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Sample records for hokokusho nippon ni

  1. Fiscal 1998 research report. Feasibility survey on offshore wind power generation in Japan; 1998 nendo chosa hokokusho. Nippon ni okeru yojo furyoku hatsuden no donyu kanosei chosa

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    NONE

    1999-03-01

    This survey studied the feasibility of large-scale offshore wind power generation in Japan. Attempt was also made on preparation of outline maps of offshore wind around Japan. The cost of future offshore wind power generation systems is roughly dependent on technical issues and environmental issues. As technical issues, 'installation site,' 'foundation,' 'system interconnection' and 'maintenance/management' were summarized based on applications in Europe. As a result, it was clarified that technical issues can be solved with existing technologies to a certain extent, however, those relate to economical problems closely. The previous environment impact assessments say that wind power generation has no problems on the environmental issues. As relatively strong wind coastal areas, the outline maps of offshore wind point out Western Hokkaido area, Japan Sea area of Tohoku district, Pacific ocean area of the central part of Honshu, Genkai Nada area, Western Kyushu area and Southwest islands area, and suggest that these areas are promising for offshore wind power generation. (NEDO)

  2. Attempts for development of new processing techniques and products by Nippon Arm aiming at creation and diversification. Development of new processing techniques and products by drawing machines aided by induction heating. Sozo to tayo wo mezasu Nippon Arm no 'atarashii kako gijutsu to shohin kaihatsu' eno torikumi. Yudo kanetsu shibori kakoki ni yoru kako gijutsu oyobi shinshohin no kaihatsu

    Energy Technology Data Exchange (ETDEWEB)

    Yamamoto, K.; Kurihara, T. (Kansai Electric Power Co. Inc., Osaka (Japan))

    1999-05-10

    Described herein are new processing techniques and products of good designs Nippon Arm has developed by introducing drawing machines aided by induction heating. The machine draws a rotating tube heated by high-frequency induction heating while pressing its outer surface by 3 rolls. It works under programmed conditions (e.g., heating temperature, speed of rotation, feed rate and drawing depth) to give an optional shape, without needing a mold. The basic modes of drawing include straight tube drawing, tapered drawing, R-drawing and convexo-concave drawing, and a combination thereof is also possible to form more complex shapes. The first product produced by the machine is N type arms for overhead cables, and has been followed by various products, e.g., illumination poles and garden illuminators of unique designs for common markets. (NEDO)

  3. Attempts for development of new processing techniques and products by Nippon Arm aiming at creation and diversification. Development of new processing techniques and products by drawing machines aided by induction heating; Sozo to tayo wo mezasu Nippon Arm no `atarashii kako gijutsu to shohin kaihatsu` eno torikumi. Yudo kanetsu shibori kakoki ni yoru kako gijutsu oyobi shinshohin no kaihatsu

    Energy Technology Data Exchange (ETDEWEB)

    Yamamoto, K.; Kurihara, T. [Kansai Electric Power Co. Inc., Osaka (Japan)

    1999-05-10

    Described herein are new processing techniques and products of good designs Nippon Arm has developed by introducing drawing machines aided by induction heating. The machine draws a rotating tube heated by high-frequency induction heating while pressing its outer surface by 3 rolls. It works under programmed conditions (e.g., heating temperature, speed of rotation, feed rate and drawing depth) to give an optional shape, without needing a mold. The basic modes of drawing include straight tube drawing, tapered drawing, R-drawing and convexo-concave drawing, and a combination thereof is also possible to form more complex shapes. The first product produced by the machine is N type arms for overhead cables, and has been followed by various products, e.g., illumination poles and garden illuminators of unique designs for common markets. (NEDO)

  4. [Behavior ethogram and PAE coding system of Cervus nippon sichuanicus].

    Science.gov (United States)

    Qi, Wen-Hua; Yue, Bi-Song; Ning, Ji-Zu; Jiang, Xue-Mei; Quan, Qiu-Mei; Guo, Yan-Shu; Mi, Jun; Zuo, Lin; Xiong, Yuan-Qing

    2010-02-01

    A monthly 5-day periodic observation at 06:00-18:00 from March to November 2007 was conducted to record the behavioral processes, contents, and results, and the surrounding habitats of Sichuan sika deer (Cervus nippon sichuanicus) in Donglie, Chonger, and Reer villages of Tiebu Natural Reserve of Sichuan Province. The behavioral ethogram, vigilance behaviors ethogram and its PAE (posture, act, and environment) coding system of the Sichuan sika deer were established, which filled the gap of the PAE coding of ungulates vigilance behaviors. A total of 11 kinds of postures, 83 acts, and 136 behaviors were recorded and distinguished, with the relative frequency of each behavior in relation to gender, age, and season described. Compared with other ungulates, the behavioral repertoire of Sichuan sika deer was mostly similar to that of other cervid animals.

  5. Complete mitochondrial genomes of two subspecies (Rhinolophus ferrumequinum nippon and Rhinolophus ferrumequinum tragatus) of the greater horseshoe bat (Chiroptera: Rhinolophidae).

    Science.gov (United States)

    Xiao, Yanhong; Sun, Keping; Feng, Jiang

    2017-01-01

    Rhinolophus ferrumequinum nippon and Rhinolophus ferrumequinum tragatus are two subspecies of Rhinolophus ferrumequinum currently recognized in China. In this study, their mitochondrial genomes were completely sequenced and annotated. Phylogenetic analyses indicated that R. f. nippon has a close relationship with two subspecies of R. ferrumequinum from Korea with 0.1% divergence, which indicated they are synonyms.

  6. Qualification of the Nippon Instrumentation for use in Measuring Mercury at the Defense Waste Processing Facility

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    Edwards, T.; Mahannah, R.

    2011-07-05

    The Nippon Mercury/RA-3000 system installed in 221-S M-14 has been qualified for use. The qualification was a side-by-side comparison of the Nippon Mercury/RA-3000 system with the currently used Bacharach Mercury Analyzer. The side-by-side testing included standards for instrument calibration verifications, spiked samples and unspiked samples. The standards were traceable back to the National Institute of Standards and Technology (NIST). The side-by-side work included the analysis of Sludge Receipt and Adjustment Tank (SRAT) Receipt, SRAT Product, and Slurry Mix Evaporator (SME) samples. With the qualification of the Nippon Mercury/RA-3000 system in M-14, the DWPF lab will be able to perform a head to head comparison of a second Nippon Mercury/RA-3000 system once the system is installed. The Defense Waste Processing Facility (DWPF) analyzes receipt and product samples from the Sludge Receipt and Adjustment Tank (SRAT) to determine the mercury (Hg) concentration in the sludge slurry. The SRAT receipt is typically sampled and analyzed for the first ten SRAT batches of a new sludge batch to obtain an average Hg concentration. This average Hg concentration is then used to determine the amount of steam stripping required during the concentration/reflux step of the SRAT cycle to achieve a less than 0.6 wt% Hg in the SRAT product solids. After processing is complete, the SRAT product is sampled and analyzed for mercury to ensure that the mercury concentration does not exceed the 0.45 wt% limit in the Slurry Mix Evaporator (SME). The DWPF Laboratory utilizes Bacharach Analyzers to support these Hg analyses at this facility. These analyzers are more than 10 years old, and they are no longer supported by the manufacturer. Due to these difficulties, the Bacharach Analyzers are to be replaced by new Nippon Mercury/RA-3000 systems. DWPF issued a Technical Task Request (TTR) for the Savannah River National Laboratory (SRNL) to assist in the qualification of the new systems. SRNL

  7. Ascaris spp. and Capillaria caudinflata infections in captive-bred crested ibis (Nipponia nippon) in China.

    Science.gov (United States)

    Zhang, Xu; Qiao, Ji Ying; Wu, Xiao Min; Ma, Qing Yi; Hu, Han; Wang, Jing; Che, Li Feng

    2015-01-01

    Crested ibis (Nipponia nippon), an endan gered native bird, was called the "precious stone" of oriental birds. N. nippon was considered a critically endangered species in the IUCN Red List of Threatened Species and a first-class national protected animal in China. The Chinese government had exerted considerable effort to protect the N. nippon population. An effective approach to increase the number of these birds was captive breeding. However, several pathogens, including parasites, could jeopardize the health of this species. The present study used the fecal flotation method to determine prevalence of intestinal parasites in fresh stool samples by wet mount smearing and iodine staining. Samples were obtained from 63 randomly selected crested ibis bred in Shaanxi Rare Wildlife Rescuing and Breeding Research Center in Zhouzhi County, Xi'an City, Shaanxi Province, China. In the 63 captive individuals, 38 were found positive for intestinal parasites (60.3%, 38/63). Of positive birds, high prevalence of Ascaris spp. (84.2%, 32/38) and Capillaria caudinflata (50.0%, 19/38) were detected. Coccidea (7.8%, 3/38), Fasciolidae (23.7%, 9/38), Blastocystis spp. (15.8%, 6/38), and Entamoeba histolytica (7.8%, 3/38) showed relatively low prevalence rates. This study focuses on the morphological identification of Ascaris spp. and C. caudinflata and their transmission in the N. nippon population. We introduce strategies to improve the breeding management of the birds, enhance their health, and stimulate population productivity. © 2014 Wiley Periodicals, Inc.

  8. FY 1998 result report. Study of a total system for the development of superconductor power application technology (Feasibility study of commercialization of superconductivity technology and study of the introductory effect. Future superconductivity technology development in Japan); 1998 nendo seika hokokusho. Chodendo denryoku oyo gijutsu kaihatsu total system nado no kenkyu chodendo gijutsu no jitsuyoka kanosei oyobi donyu kokanado no chosa (Nippon ni okeru chodendo gijutsu kaihatsu no kongo no hokosei)

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    NONE

    1996-03-01

    As a part of the New Sunshine Project, 'an R and D project on superconductor power application technology,' an examinational study was made as a mini project to clarify the developmental course for commercialization of superconductor technology. The superconductor technology is being watched with interest as a technology in the 21st century. In the application to the electric power/energy field, in particular, expected are the energy saving effect by high operation efficiency, excellent environmentality, developmental potentiality of new equipment/system by the application of ferromagnetism, etc. Accordingly, the paper analytically arranged the needs of superconductor devices in Japan and abroad and the technology seeds corresponding to the needs, and prepared the developmental subjects of superconductor technology. These developmental steps and the mutual relationship were expressed in an R and D framework. At the same time, as to the superconductivity, a survey outlined the projects carried out in each government office in Japan. The future developmental course was indicated, and proposals were made on the equipment/system as object which are the subjects for urgent development for commercialization. (NEDO)

  9. Species-specific control of acoustic gaze by echolocating bats, Rhinolophus ferrumequinum nippon and Pipistrellus abramus, during flight.

    Science.gov (United States)

    Yamada, Yasufumi; Hiryu, Shizuko; Watanabe, Yoshiaki

    2016-11-01

    Based on the characteristics of the ultrasounds they produce, echolocating bats can be categorized into two main types: broadband FM (frequency modulated) and narrowband CF (constant frequency) echolocators. In this study, we recorded the echolocation behavior of a broadband FM (Pipistrellus abramus) and a narrowband CF echolocator species (Rhinolophus ferrumequinum nippon) while they explored an unfamiliar space in a laboratory chamber. During flight, P. abramus smoothly shifted its acoustic gaze in relation to its flight direction, whereas R. ferrumequinum nippon frequently shifted its acoustic gaze from side to side. The distribution of the acoustic gazes of R. ferrumequinum nippon was twice as wide as that of P. abramus. Furthermore, R. ferrumequinum nippon produced double pulses twice as often as P. abramus. Because R. ferrumequinum nippon has a horizontal beam width (-6 dB off-axis angle) half as wide (±20.8 ± 6.0°) as that of P. abramus (±38.3 ± 6.0°), it appears to double the width of its acoustical field of view by shifting its acoustic gaze further off-axis and emitting direction-shifted double pulses. These results suggest that broadband FM and narrowband CF bats actively control their acoustic gazes in a species-specific manner based on the acoustic features of their echolocation signals.

  10. Peripheral Refraction Validity of the Shin-Nippon SRW5000 Autorefractor.

    Science.gov (United States)

    Osuagwu, Uchechukwu Levi; Suheimat, Marwan; Wolffsohn, James S; Atchison, David A

    2016-10-01

    To investigate the operation of the Shin-Nippon/Grand Seiko autorefractor and whether higher-order aberrations affect its peripheral refraction measurements. Information on instrument design, together with parameters and equations used to obtain refraction, was obtained from a patent. A model eye simulating the operating principles was tested with an optical design program. Effects of induced defocus and astigmatism on the retinal image were used to calibrate the model eye to match the patent equations. Coma and trefoil were added to assess their effects on the image. Peripheral refraction of a physical model eye was measured along four visual field meridians with the Shin-Nippon/Grand Seiko autorefractor SRW-5000 and a Hartmann-Shack aberrometer, and simulated autorefractor peripheral refraction was derived using the Zernike coefficients from the aberrometer. In simulation, the autorefractor's square image was changed in size by defocus, into rectangles or parallelograms by astigmatism, and into irregular shapes by coma and trefoil. In the presence of 1.0 D oblique astigmatism, errors in refraction were proportional to the higher-order aberrations, with up to 0.8 D sphere and 1.5 D cylinder for ±0.6 μm of coma or trefoil coefficients with a 5-mm-diameter pupil. For the physical model eye, refraction with the aberrometer was similar in all visual field meridians, but refraction with the autorefractor changed more quickly along one oblique meridian and less quickly along the other oblique meridian than along the horizontal and vertical meridians. Simulations predicted that higher-order aberrations would affect refraction in oblique meridians, and this was supported by the experimental measurements with the physical model eye. The autorefractor's peripheral refraction measurements are valid for horizontal and vertical field meridians, but not for oblique field meridians. Similar instruments must be validated before being adopted outside their design scope.

  11. Structure and polymorphism of the major histocompatibility complex class II region in the Japanese Crested Ibis, Nipponia nippon.

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    Yukio Taniguchi

    Full Text Available The major histocompatibility complex (MHC is a highly polymorphic genomic region that plays a central role in the immune system. Despite its functional consistency, the genomic structure of the MHC differs substantially among organisms. In birds, the MHC-B structures of Galliformes, including chickens, have been well characterized, but information about other avian MHCs remains sparse. The Japanese Crested Ibis (Nipponia nippon, Pelecaniformes is an internationally conserved, critically threatened species. The current Japanese population of N. nippon originates from only five founders; thus, understanding the genetic diversity among these founders is critical for effective population management. Because of its high polymorphism and importance for disease resistance and other functions, the MHC has been an important focus in the conservation of endangered species. Here, we report the structure and polymorphism of the Japanese Crested Ibis MHC class II region. Screening of genomic libraries allowed the construction of three contigs representing different haplotypes of MHC class II regions. Characterization of genomic clones revealed that the MHC class II genomic structure of N. nippon was largely different from that of chicken. A pair of MHC-IIA and -IIB genes was arranged head-to-head between the COL11A2 and BRD2 genes. Gene order in N. nippon was more similar to that in humans than to that in chicken. The three haplotypes contained one to three copies of MHC-IIA/IIB gene pairs. Genotyping of the MHC class II region detected only three haplotypes among the five founders, suggesting that the genetic diversity of the current Japanese Crested Ibis population is extremely low. The structure of the MHC class II region presented here provides valuable insight for future studies on the evolution of the avian MHC and for conservation of the Japanese Crested Ibis.

  12. Structure and polymorphism of the major histocompatibility complex class II region in the Japanese Crested Ibis, Nipponia nippon.

    Science.gov (United States)

    Taniguchi, Yukio; Matsumoto, Keisuke; Matsuda, Hirokazu; Yamada, Takahisa; Sugiyama, Toshie; Homma, Kosuke; Kaneko, Yoshinori; Yamagishi, Satoshi; Iwaisaki, Hiroaki

    2014-01-01

    The major histocompatibility complex (MHC) is a highly polymorphic genomic region that plays a central role in the immune system. Despite its functional consistency, the genomic structure of the MHC differs substantially among organisms. In birds, the MHC-B structures of Galliformes, including chickens, have been well characterized, but information about other avian MHCs remains sparse. The Japanese Crested Ibis (Nipponia nippon, Pelecaniformes) is an internationally conserved, critically threatened species. The current Japanese population of N. nippon originates from only five founders; thus, understanding the genetic diversity among these founders is critical for effective population management. Because of its high polymorphism and importance for disease resistance and other functions, the MHC has been an important focus in the conservation of endangered species. Here, we report the structure and polymorphism of the Japanese Crested Ibis MHC class II region. Screening of genomic libraries allowed the construction of three contigs representing different haplotypes of MHC class II regions. Characterization of genomic clones revealed that the MHC class II genomic structure of N. nippon was largely different from that of chicken. A pair of MHC-IIA and -IIB genes was arranged head-to-head between the COL11A2 and BRD2 genes. Gene order in N. nippon was more similar to that in humans than to that in chicken. The three haplotypes contained one to three copies of MHC-IIA/IIB gene pairs. Genotyping of the MHC class II region detected only three haplotypes among the five founders, suggesting that the genetic diversity of the current Japanese Crested Ibis population is extremely low. The structure of the MHC class II region presented here provides valuable insight for future studies on the evolution of the avian MHC and for conservation of the Japanese Crested Ibis.

  13. Sperm invasion of the oviducal mucosa, fibroblastic phagocytosis and endometrial sloughing in the Japanese greater horseshoe bat, Rhinolophus ferrumequinum nippon.

    Science.gov (United States)

    Uchida, T A; Mori, T; Oh, Y K

    1984-01-01

    In the Japanese greater horseshoe bat, Rhinolophus ferrumequinum nippon, a vast number of spermatozoa invade the oviducal epithelial cells of the caudal isthmus and become concentrated in the endometrial lamina propria of the bicornuate horns. They are subsequently phagocytised and digested by fibroblasts. Then, finally, they become deposited in the uterine lumen together with a large quantity of secretory material from the endometrial connective tissue which, prior to this event, undergoes a massive infiltration by polymorphonuclear leucocytes.

  14. Decline of traditional rice farming constrains the recovery of the endangered Asian crested ibis (Nipponia nippon).

    Science.gov (United States)

    Sun, Yiwen; Wang, Tiejun; Skidmore, Andrew K; Wang, Qi; Ding, Changqing

    2015-12-01

    Traditional agriculture benefits a rich diversity of plants and animals. The winter-flooded rice fields in the Qinling Mountains, China, are the last refuge for the endangered Asian crested ibis (Nipponia nippon), and intensive efforts have been made to protect this anthropogenic habitat. Analyses of multi-temporal satellite data indicate that winter-flooded rice fields have been continuously reduced across the current range of crested ibis during the past two decades. The rate of loss of these fields in the core-protected areas has unexpectedly increased to a higher level than that in non-protected areas in the past decade. The best fit (R (2) = 0.87) numerical response model of the crested ibis population shows that a reduction of winter-flooded rice fields decreases population growth and predicts that the population growth will be constrained by the decline of traditional winter-flooded rice fields in the coming decades. Our findings suggest that the decline of traditional rice farming is likely to continue to pose a threat to the long-term survival and recovery of the crested ibis population in China.

  15. Detection of Brucellosis in Sika Deer ( Cervus nippon ) through Loop-mediated Isothermal Amplification (LAMP).

    Science.gov (United States)

    Liu, Qianhong; Wei, Jie; Sun, Qingsong; Wang, Ben; Wang, Yuting; Hu, Ying; Wu, Wenrong

    2017-07-01

    Brucellosis (Brucella bovis) in sika deer ( Cervus nippon ) can cause enormous losses to stag breeding, especially in areas in which stag breeding has become an important industry. It also poses a threat to humans because it is a zoonotic disease. Use of the loop-mediated isothermal amplification (LAMP) assay has been poorly described in the diagnosis of brucellosis in deer. We developed a LAMP assay targeting the omp25 gene sequence to detect brucellosis in sika deer. The reaction can be completed in 60 min at 63 C and, with a detection limit of 17 pg, it was more sensitive than conventional PCR, with its detection limit of 1.7 ng. No cross-reactivity was observed with four bacteria: Escherichia coli , Salmonella enterica subsp. enterica, Clostridium pasteurianum , and Pseudomonas aeruginosa . We used 263 samples of blood to evaluate the reaction. The percentage of agreement between LAMP and PCR reached 91%; relative specificity reached 87%, and relative sensitivity reached 100%. The results indicate LAMP can be a simple and rapid diagnostic tool for detecting brucellosis in sika deer, particularly in the field, where it is essential to control brucellosis in deer with a rapid and accurate diagnosis for removal of positive animals.

  16. Biomarkers in petroleum from sedimentary basins in Northeast Japan. Tohoku Nippon no taiseki bonchi ni okeru abura no biomarker

    Energy Technology Data Exchange (ETDEWEB)

    Sakata, Susumu; Kaneko, Nobuyuki; Suzuki, Noriyuki (Geological Survey of Japan, Tsukuba, (Japan) Shimane Univ., Shimane, (Japan). Faculty of Science)

    1990-01-01

    Study by biomarker was made of oil from sedimentary basin in Northeast Japan. The oil biomarker is a proof to directly verify the biological origin of oil and becomes an index to effectively evaluate the matureness of oil, type of original organic matter, migration of oil, influence of microbiological decomposition, etc. Both matureness and original organic matter indexes of both steroid and triterpenoid hydrocarbon were applied to both crude oil and condensate, produced in Northeast Japan. Condensate is higher in matureness than crude oil. While as for crude oil, some of crude oil from Akita-Yamagata basin is lower in matureness than that from Niigata basin. It is possible that Akita-Yamagata basin was earlier in primary migration period than Niigata basin. Oil from Niigata basin trends to be larger in contribution by terrigenous organic matter than that from Akita-Yamagata basin. In oil from Niigata basin, no systematic difference was recorded in original organic matter between crude oil and condensate. 26 refs., 4 figs., 1 tab.

  17. Comparison of the National Nutritional Survey in Japan estimated individual-based nutritional data and NIPPON DATA80 food frequency questionnaires.

    Science.gov (United States)

    Nakamura, Yasuyuki; Okuda, Nagako; Turin, Tanvir Chowdhury; Fujiyoshi, Akira; Okamura, Tomonori; Hayakawa, Takehito; Matsumura, Yasuhiro; Miura, Katsuyuki; Ueshima, Hirotsugu

    2010-01-01

    The National Nutritional Survey in Japan (NNSJ) was initiated in 1946. Using the majority of the participants for NNSJ, the National Survey on Circulatory Disorders has been conducted every 10 year since 1960. We performed a comparative study of the NNSJ80 estimated individual-based nutritional data by comparing those with NIPPON DATA80 food frequency questionnaires (FFQ) data. A total of 10 546 community residents from 300 randomly selected districts participated in the both surveys in 1980. At baseline, history, physical, and blood biochemical measurement and a nutritional survey by FFQ were performed individually. From household-based NNSJ80 data, we estimated nutrient intakes of each household member by dividing household intake data proportionally using average intakes by sex and age groups calculated for NNSJ95. We re-categorized NNSJ80 estimated data to correspond to NIPPON DATA80 FFQ categories. Data were analyzed in men and women separately. Cross tables showed fairly good agreement of the two categories. The majorities of participants situated on the diagonally aligned cells or the next to them. Weighted kappa ranged from 0.152 to 0.241. Spearman's rank correlation coefficients between the two categories ranged from 0.224 to 0.338, and those between NNSJ80 continuous data and NIPPON DATA80 categorical data ranged from 0.237 to 0.354. All these values have P nutritional estimation method is applicable to, further studies.

  18. Seasonal changes of the mineral contents in the rumen of wild Yeso sika deer (Cervus nippon yesoensis).

    Science.gov (United States)

    Hayashida, Maki; Souma, Kousaku; Hanagata, Osamu; Okamoto, Masayo; Masuko, Takayoshi

    2012-03-01

    The rumen contents were collected from 36 wild Yeso sika deer (Cervus nippon yesoensis) captured by deer culling or by hunting in the spring, summer, autumn and winter in Hokkaido, Japan. Botanical classification was conducted, and the contents of mineral (calcium (Ca), phosphorus (P), potassium (K), sodium (Na), iron (Fe), copper (Cu) and zinc (Zn)) were measured. The animals were captured around pastures or fallow field areas in the Kushiro area. The rumen contents consisted of grasses and Sasa sp. leaves regardless of the season. Leaves and bark were ingested in the spring, autumn and winter. The macro-mineral contents in the rumen showed seasonal changes. In the summer, the Ca, K and P contents were high, and the Na content was low. There were no seasonal changes in the Fe content. The P, Na and Fe contents were higher than the animals' requirements. In a future survey, it is needed to determine the mineral contents of the food ingested by wild Yeso sika deer. © 2011 The Authors. Animal Science Journal © 2011 Japanese Society of Animal Science.

  19. Convergence of reference frequencies by multiple CF-FM bats (Rhinolophus ferrumequinum nippon) during paired flights evaluated with onboard microphones.

    Science.gov (United States)

    Furusawa, Yuto; Hiryu, Shizuko; Kobayasi, Kohta I; Riquimaroux, Hiroshi

    2012-09-01

    The constant frequency component of the second harmonic (CF(2)) of echolocation sounds in Rhinolophus ferrumequinum nippon were measured using onboard telemetry microphones while the bats exhibited Doppler-shift compensation during flights with conspecifics. (1) The CF(2) frequency of pulses emitted by individual bats at rest (F (rest)) showed a long-term gradual decline by 0.22 kHz on average over a period of 3 months. The mean neighboring F (rest) (interindividual differences in F (rest) between neighboring bats when the bats were arranged in ascending order according to F (rest)) ranged from 0.08 to 0.11 kHz among 18 bats in a laboratory colony. (2) The standard deviation of observed echo CF(2) (reference frequency) for bats during paired flights ranged from 50 to 90 Hz, which was not significantly different from that during single flights. This finding suggests that during paired flights, bats exhibit Doppler-shift compensation with the same accuracy as when they fly alone. (3) In 60% (n = 29) of the cases, the difference in the reference frequency between two bats during paired flights significantly decreased compared to when the bats flew alone. However, only 15% of the cases (n = 7) showed a significant increase during paired flights. The difference in frequency between two bats did not increase even when the reference frequencies of the individuals were not statistically different during single flights.

  20. The Development of Microbiota and Metabolome in Small Intestine of Sika Deer (Cervus nippon from Birth to Weaning

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    Zhipeng Li

    2018-01-01

    Full Text Available The dense and diverse community of microorganisms inhabiting the gastrointestinal tract of ruminant animals plays critical roles in the metabolism and absorption of nutrients, and gut associated immune function. Understanding microbial colonization in the small intestine of new born ruminants is a vital first step toward manipulating gut function through interventions during early life to produce long-term positive effects on host productivity and health. Yet the knowledge of microbiota colonization and its induced metabolites of small intestine during early life is still limited. In the present study, we examined the microbiota and metabolome in the jejunum and ileum of neonatal sika deer (Cervus nippon from birth to weaning at days 1, 42, and 70. The microbial data showed that diversity and richness were increased with age, but a highly individual variation was observed at day 1. Principal coordinate analysis revealed significant differences in microbial community composition across three time points in the jejunum and ileum. The abundance of Halomonas spp., Lactobacillus spp., Escherichia–Shigella, and Bacteroides spp. tended to be decreased, while the proportion of Intestinibacter spp., Cellulosilyticum spp., Turicibacter spp., Clostridium sensu stricto 1 and Romboutsia spp. was significantly increased with age. For metabolome, metabolites separated from each other across the three time points in both jejunum and ileum. Moreover, the amounts of methionine, threonine, and putrescine were increased, while the amounts of myristic acid and pentadecanoic acid were decreased with age, respectively. The present study demonstrated that microbiota colonization and the metabolome becomes more developed in the small intestine with age. This may shed new light on the microbiota-metabolome-immune interaction during development.

  1. Proceedings of RITE international workshop on valuation; Total eko balance ni kansuru kokusai workshop hokokusho

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1996-02-01

    The RITE International Workshop on Valuation was held in Tokyo and Osaka in February 1996, and eight papers on total ecobalance were reported. In The Field of Impact Assessment, described were constitution and methodology about impact assessment in a wide sense. In LCA Yesterday, Today and Tomorrow, discussed were the historical development and future outlook of LCA. In Standardization of Product Life Cycle Assessment, a survey of the present situation of LCA international standardization was made. In the Relationship between Product Life Cycle Assessment Methodology, considered was the relationship between the goal definition of the product life cycle assessment and the methodological choices. In Valuation in LCA, the present study of LCA was reviewed. Besides, reviews of the LCA study in Japan were made public.

  2. Seasonal and year-round use of the Kushiro Wetland, Hokkaido, Japan by sika deer (Cervus nippon yesoensis

    Directory of Open Access Journals (Sweden)

    Hino Takafumi

    2017-10-01

    Full Text Available The sika deer (Cervus nippon yesoensis population in the Ramsar-listed Kushiro Wetland has increased in recent years, and the Ministry of the Environment of Japan has decided to take measures to reduce the impact of deer on the ecosystem. However, seasonal movement patterns of the deer (i.e., when and where the deer inhabit the wetland remain unclear. We examined the seasonal movement patterns of sika deer in the Kushiro Wetland from 2013 to 2015 by analyzing GPS location data for 28 hinds captured at three sites in the wetland. Seasonal movement patterns were quantitatively classified as seasonal migration, mixed, dispersal, nomadic, resident, or atypical, and the degree of wetland utilization for each individual was estimated. The area of overlap for each individual among intra-capture sites and inter-capture sites was calculated for the entire year and for each season. Our results showed that the movement patterns of these deer were classified not only as resident but also as seasonal migration, dispersal, and atypical. Approximately one-third of the individuals moved into and out of the wetland during the year as either seasonal migrants or individuals with atypical movement. Some of the individuals migrated to farmland areas outside the wetland (the farthest being 69.9 km away. Half of the individuals inhabited the wetland all or most of the year, i.e., 81–100% of their annual home range was within the wetland area. Even among individuals captured at the same site, different seasonal movement patterns were identified. The overlap areas of the home ranges of individuals from the same capture sites were larger than those for individuals from different capture sites (e.g., mean of annual home range overlap with intra-capture sites: 47.7% vs. inter-sites: 1.3%. To achieve more effective ecosystem management including deer management in the wetland, management plans should cover inside and outside of the wetland and separate the population

  3. Seasonal and year-round use of the Kushiro Wetland, Hokkaido, Japan by sika deer (Cervus nippon yesoensis).

    Science.gov (United States)

    Takafumi, Hino; Kamii, Tatsuya; Murai, Takunari; Yoshida, Ryoto; Sato, Atsuki; Tachiki, Yasuyuki; Akamatsu, Rika; Yoshida, Tsuyoshi

    2017-01-01

    The sika deer (Cervus nippon yesoensis) population in the Ramsar-listed Kushiro Wetland has increased in recent years, and the Ministry of the Environment of Japan has decided to take measures to reduce the impact of deer on the ecosystem. However, seasonal movement patterns of the deer (i.e., when and where the deer inhabit the wetland) remain unclear. We examined the seasonal movement patterns of sika deer in the Kushiro Wetland from 2013 to 2015 by analyzing GPS location data for 28 hinds captured at three sites in the wetland. Seasonal movement patterns were quantitatively classified as seasonal migration, mixed, dispersal, nomadic, resident, or atypical, and the degree of wetland utilization for each individual was estimated. The area of overlap for each individual among intra-capture sites and inter-capture sites was calculated for the entire year and for each season. Our results showed that the movement patterns of these deer were classified not only as resident but also as seasonal migration, dispersal, and atypical. Approximately one-third of the individuals moved into and out of the wetland during the year as either seasonal migrants or individuals with atypical movement. Some of the individuals migrated to farmland areas outside the wetland (the farthest being 69.9 km away). Half of the individuals inhabited the wetland all or most of the year, i.e., 81-100% of their annual home range was within the wetland area. Even among individuals captured at the same site, different seasonal movement patterns were identified. The overlap areas of the home ranges of individuals from the same capture sites were larger than those for individuals from different capture sites (e.g., mean of annual home range overlap with intra-capture sites: 47.7% vs. inter-sites: 1.3%). To achieve more effective ecosystem management including deer management in the wetland, management plans should cover inside and outside of the wetland and separate the population into multiple

  4. Seismicity and volcanic activity in Japan based on crustal thermal activity . 2; Chikaku no netsukatsudo ni motozuku Nippon no Jishin kazan katsudo. 2

    Energy Technology Data Exchange (ETDEWEB)

    Hayakawa, M. [Tokai Univ., Tokyo (Japan). School of Marine Science and Technology

    1996-05-01

    This paper describes the following matters about seismic and volcanic activities in Japan. The previous paper has reported a view that energy is transported from deep portions of the earth`s crust toward outer portions, and the stored energy thrusts up collectively in a certain time period (a rising period). A fact may be accounted for as one of the endorsements thereof that earthquakes and volcanic eruptions take place successively over a wide area from Okinawa to Hokkaido in a short period of time (included in the rising period). When viewed by limiting the time period and areas, a great earthquake would not occur suddenly, but stored energy is released wholly at a certain time while it has been released little by little. Referring to the Kanto Great Earthquake (1923) and the Tokai and Nankai Earthquakes (1944 and 1946), it is found that earthquakes had been occurring successively in the surrounding areas since about 20 years before the occurrence of these great earthquakes. Similar phenomena may be seen in the great earthquakes of Ansei (1854) and An-ei (1707). 5 figs.

  5. Seismicity and volcanic activity in Japan based on crustal thermal activity. 1; Chikaku no netsukatsudo ni motozuku Nippon no jishin kazan katsudo. 1

    Energy Technology Data Exchange (ETDEWEB)

    Hayakawa, M. [Tokai Univ., Tokyo (Japan). School of Marine Science and Technology

    1996-05-01

    This paper describes the following matters about correlation between seismic and volcanic activities and thermal energy. Investigations on the status of seismic and volcanic activities in the Japanese archipelago during about 400 years in the past reveals the following matters: noticing earthquakes with magnitudes of upper M6 to about M7, flows of energy going outward from deep crust of the earth repeat ups and downs, whereas several prominent rising periods having certain time widths can be seen; volcanic activities are included in the rising period at the same rank as seismic activities; with regard to years 1900 and on, the similar fact can be seen if the Japanese archipelago is divided into a north portion, a south portion, and an extremely south portion southern than the Hiuga area; and the present time is going toward a period of rise in energy flows. In other words, it is thought that the crust and the uppermost portion of the mantle form one body like an organic body, making an action like a geyser releasing the energy outward. 3 refs., 2 figs., 1 tab.

  6. Survey of the actual state of the coal related research and development in Japan. 11; Nippon ni okeru sekitan kanren kenkyu kaihatsu jittai chosa. 11

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1998-03-01

    NEDO is surveying the actual state of the coal related research/development in Japan to supply information on the coal related research/development in Japan to IEA`s coal research project database. This book of fiscal 1997 version includes 338 subjects. The details described are name of research institute, the section in charge, address, name of country, telephone No., name of joint researcher, research theme, classification, outline of research, project No., name of researcher, sponsor, the budget appropriated, term of research, remarks, etc. The books of data collected from each country in surveys of the actual state of the coal related R and D and IEA`s coal researches which have been made so far are submitted for general viewing at NEDO Information Center. Also, a part of those can be accessible from the energy database of which NEDO Information Center is performing on-line service for user members

  7. Centre of Excellence in Observational Oceanography: Nippon Foundation and POGO Supported Programme at the Bermuda Institute of Ocean Sciences

    Science.gov (United States)

    Plumley, F. G.; Sathyendranath, S.; Frouin, R.; Knap, T.

    2008-05-01

    Building on previous experience in capacity building for ocean observations, the Nippon Foundation (NF) and the Partnership for Observations of the Global Oceans (POGO) have announced a new Centre of Excellence (C of E) at the Bermuda Institute of Ocean Sciences (BIOS). The goals of the C of E are to expand the world-wide capacity and expertise to observe the oceans and to expand capacity-building projects and promote international collaboration and networking in ocean sciences. Over the past 104 years, BIOS has built a global reputation in blue-water oceanography, coral reef ecology, and the relationships between ocean health and human health coupled with high quality education programmes that provide direct, hands-on experience with BIOS-based research. The C of E at BIOS will build upon this model to establish a new, graduate-level education and training programme in operational oceanography. The 10 month Programme will offer course modules in ocean disciplines with a focus on observatory sciences complemented by hands-on training in observational methods and techniques based on the multi-disciplinary expertise of BIOS and BIOS-affiliated scientists who direct ongoing, ocean observational programmes such as: - Hydrostation S, since 1954; - Bermuda Atlantic Time-series Study, since 1988; - Oceanic Flux Program sediment trap time-series, since 1978; - Bermuda Test-Bed and Science Mooring, since 1994; - Bermuda Microbial Observatory, since 1997; - Bermuda Bio-Optics Program, since 1992; - Atmospheric chemistry and air-sea fluxes, since 1990 Additional areas of BIOS research expertise will be incorporated in the C of E to broaden the scope of education and training. These include the nearshore observational network of the BIOS Marine Environmental Program and the environmental air-water chemistry network of the Bermuda Environmental Quality Program. A key resource of the C of E is the newly acquired 168 ft. research vessel, the RV Atlantic Explorer, which was

  8. Molecular diversity of rumen bacterial communities from tannin-rich and fiber-rich forage fed domestic Sika deer (Cervus nippon) in China

    Science.gov (United States)

    2013-01-01

    Background Sika deer (Cervus nippon) have different dietary preferences to other ruminants and are tolerant to tannin-rich plants. Because the rumen bacteria in domestic Sika deer have not been comprehensively studied, it is important to investigate its rumen bacterial population in order to understand its gut health and to improve the productivity of domestic Sika deer. Results The rumen bacterial diversity in domestic Sika deer (Cervus nippon) fed oak leaves- (OL group) and corn stalks-based diets (CS group) were elucidated using 16S rRNA gene libraries and denaturing gradient gel electrophoresis (DGGE). Overall, 239 sequences were examined from the two groups, 139 clones from the OL group were assigned to 57 operational taxonomic units (OTUs) and 100 sequences from the CS group were divided into 50 OTUs. Prevotella-like sequences belonging to the phylum Bacteroidetes were the dominant bacteria in both groups (97.2% OL and 77% CS), and sequences related to Prevotella brevis were present in both groups. However, Prevotella shahii-like, Prevotella veroralis-like, Prevotella albensis-like, and Prevotella salivae-like sequences were abundant in the OL group compared to those in the CS group, while Succinivibrio dextrinosolvens-like and Prevotella ruminicola-like sequences were prevalent in the CS group. PCR-DGGE showed that bacterial communities clustered with respect to diets and the genus Prevotella was the dominant bacteria in the rumen of domestic Sika deer. However, the distribution of genus Prevotella from two groups was apparent. In addition, other fibrolytic bacteria, such as Clostridium populeti and Eubacterium cellulosolvens were found in the rumen of domestic Sika deer. Conclusions The rumen of domestic Sika deer harbored unique bacteria which may represent novel species. The bacterial composition appeared to be affected by diet, and sequences related to Prevotella spp. may represent new species that may be related to the degradation of fiber biomass or

  9. The parasitecoenoses' influence on health status of sika-deer (Cervus nippon population in the west-Bohemia region (Czech Republic

    Directory of Open Access Journals (Sweden)

    Marie Borkovcová

    2009-01-01

    Full Text Available The aim of this study was detection of prevalence of the parasitecoenoses of sika deer (Cervus nippon living in the wild in the area of Western Bohemia (Czech Republic and to compare roundup data with results from previous investigations.All together 560 samples of excrements and 8 grallochs were examined. The research was done from March 2005 to June 2007. The samples of excrements were collected during the whole research period in periodical monthly intervals always in the amount of 20 pieces. Grallochs were examined by partial helmintological dissection, the samples of excrements by Baermann method and flotation. Parasites were detected only in 26.8 % of examined samples. The spectrum of detected parasites included: coccidia Eimeria spp. (8.6 %, lungworms (LW Dictyocaulus sp. and Bicaulus sagittatus (23.4 %, and nematode worms from the group of gastrointestinal nematodes (GIN (7.9 %. In fine we can confirm that the Sika game is quite resistant against parasitoses under our conditions, and health of Sika game in monitored localities is good.

  10. Adaptive beam-width control of echolocation sounds by CF-FM bats, Rhinolophus ferrumequinum nippon, during prey-capture flight.

    Science.gov (United States)

    Matsuta, Naohiro; Hiryu, Shizuko; Fujioka, Emyo; Yamada, Yasufumi; Riquimaroux, Hiroshi; Watanabe, Yoshiaki

    2013-04-01

    The echolocation sounds of Japanese CF-FM bats (Rhinolophus ferrumequinum nippon) were measured while the bats pursued a moth (Goniocraspidum pryeri) in a flight chamber. Using a 31-channel microphone array system, we investigated how CF-FM bats adjust pulse direction and beam width according to prey position. During the search and approach phases, the horizontal and vertical beam widths were ±22±5 and ±13±5 deg, respectively. When bats entered the terminal phase approximately 1 m from a moth, distinctive evasive flight by G. pryeri was sometimes observed. Simultaneously, the bats broadened the beam widths of some emissions in both the horizontal (44% of emitted echolocation pulses) and vertical planes (71%). The expanded beam widths were ±36±7 deg (horizontal) and ±30±9 deg (vertical). When moths began evasive flight, the tracking accuracy decreased compared with that during the approach phase. However, in 97% of emissions during the terminal phase, the beam width was wider than the misalignment (the angular difference between the pulse and target directions). These findings indicate that bats actively adjust their beam width to retain the moving target within a spatial echolocation window during the final capture stages.

  11. A relapsing fever group Borrelia sp. similar to Borrelia lonestari found among wild sika deer (Cervus nippon yesoensis) and Haemaphysalis spp. ticks in Hokkaido, Japan.

    Science.gov (United States)

    Lee, Kyunglee; Takano, Ai; Taylor, Kyle; Sashika, Mariko; Shimozuru, Michito; Konnai, Satoru; Kawabata, Hiroki; Tsubota, Toshio

    2014-10-01

    A relapsing fever Borrelia sp. similar to Borrelia lonestari (herein referred to as B. lonestari-like) was detected from wild sika deer (Cervus nippon yesoensis) and Haemaphysalis ticks in the eastern part of Hokkaido, Japan. The total prevalence of this Borrelia sp. in tested deer blood samples was 10.6% using conventional PCR and real-time PCR. The prevalence was significantly higher in deer fawns compared to adults (21.9% and 9.4%, respectively). Additionally, there was significant regional difference between our two sampling areas, Shiretoko and Shibetsu with 17% and 2.8% prevalence, respectively. Regional differences were also found in tick species collected from field and on deer. In the Shiretoko region, Haemaphysalis spp. were more abundant than Ixodes spp., while in Shibetsu, Ixodes spp. were more abundant. Using real-time PCR analysis, B. lonestari-like was detected from 2 out of 290 adult Haemaphysalis spp. ticks and 4 out of 76 pools of nymphs. This is the first report of a B. lonestari-like organism in Haemaphysalis spp. ticks, and the first phylogenetic analysis of this B. lonestari-like organism in Asia. Based on our results, Haemaphysalis spp. are the most likely candidates to act as a vector for B. lonestari-like; furthermore, regional variation of B. lonestari-like prevalence in sika deer may be dependent on the population distribution of these ticks. Copyright © 2014 Elsevier GmbH. All rights reserved.

  12. Long-term outcome of healthy participants with atrial premature complex: a 15-year follow-up of the NIPPON DATA 90 cohort.

    Directory of Open Access Journals (Sweden)

    Taku Inohara

    Full Text Available BACKGROUND: Atrial premature complexes (APC are among the most frequently encountered electrocardiographic abnormalities. However, their prognostic value among healthy individuals is unclear. This study aimed to clarify the role of APC in predicting cardiovascular events in a large Japanese community cohort using long-term follow-up data. METHODS: National Integrated Project for Prospective Observation of Non-communicable Disease And its Trends in the Aged, 1990-2005, (NIPPON DATA 90 was a large cohort study of cardiovascular disease (CVD in Japan. A total of 7692 otherwise healthy participants with no history of myocardial infarction, stroke, atrial fibrillation, or atrial flutter were enrolled (men, 41.5%; mean age, 52.5 ± 13.7 years. RESULTS: A total of 64 (0.8% participants had at least one beat of APC on screening 12-lead electrocardiogram. During the follow-up of 14.0 ± 2.9 years (total, 107,474 patient-years, 338 deaths occurred due to CVD. The association between APC and CVD outcome was assessed using Cox proportional hazard models. Cox regression analysis revealed that the presence of APC was an independent predictor for CVD deaths (HR: 2.03, 95% CI: 1.12-3.66, P = 0.019. The association of APC on CVD death was more evident in participants with hypertension (P-value for interaction, 0.03. CONCLUSIONS: APC recorded during the screening electrocardiogram are significantly associated with an increased risk of CVD deaths in a Japanese community-dwelling population and are a strong prognostic factor for hypertensive participants.

  13. Lack of Structural Variation but Extensive Length Polymorphisms and Heteroplasmic Length Variations in the Mitochondrial DNA Control Region of Highly Inbred Crested Ibis, Nipponia nippon.

    Directory of Open Access Journals (Sweden)

    Xue-Lian He

    Full Text Available The animal mitochondrial DNA (mtDNA length polymorphism and heteroplasmy are accepted to be universal. Here we report the lack of structural variation but the presence of length polymorphism as well as heteroplasmy in mtDNA control region of an endangered avian species - the Crested Ibis (Nipponia nippon. The complete control region was directly sequenced while the distribution pattern and inheritance of the length variations were examined using both direct sequencing and genotyping of the PCR fragments from captive birds with pedigrees, wild birds and a historical specimen. Our results demonstrated that there was no structural variation in the control region, however, different numbers of short tandem repeats with an identical motif of CA3CA2CA3 at the 3'-end of the control region determined the length polymorphisms among and heteroplasmy within individual birds. There were one to three predominant fragments in every bird; nevertheless multiple minor fragments coexist in all birds. These extremely high polymorphisms were suggested to have derived from the 'replication slippage' of a perfect microsatellite evolution following the step-wise mutational model. The patterns of heteroplasmy were found to be shifted between generations and among siblings but rather stable between blood and feather samples. This study provides the first evidence of a very extensive mtDNA length polymorphism and heteroplasmy in the highly inbred Crested Ibis which carries an mtDNA genome lack of structural genetic diversity. The analysis of pedigreed samples also sheds light on the transmission of mtDNA length heteroplasmy in birds following the genetic bottleneck theory. Further research focusing on the generation and transmission of particular mtDNA heteroplasmy patterns in single germ line of Crested Ibis is encouraged by this study.

  14. FY 1997 report of survey on the intellectual property in international collaboration research project; 1997 nendo chosa hokokusho (kokusai kyodo kenkyu ni okeru chiteki zaisanken ni tsuite no chosa hokokusho)

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1998-03-01

    In promoting international collaboration research project, coordination of the patent system of each country which participants to the project belong to has broad implications in concluding the contract for the project. For example, in Japan, 100% of the patent belongs to the government for contrast or collaboration project with the government. While, in the USA, the patent developed by the private company belongs to the private company even for the contrast project. In Japan, the shared patent can not be transferred to the third party or implemented without agreement with the partner. While, in the USA, the shared patent can be transferred to the third party or implemented without agreement with the partner. Due to such a difference, some projects can not be established by ill coordination of intellectual property even when the meaning of the projects is well understood. In this survey, was investigated the outline of patent systems of major countries to study about what should well balanced treatment of intellectual property in international collaboration research project be in the future. 4 figs., 8 tabs.

  15. Ni hombres ni mujeres providenciales

    OpenAIRE

    Montaño Virreira, Sonia

    2000-01-01

    Debo advertir a la y el lector de este texto que lo que a continuación se presenta no es, ni de lejos, una propuesta realista, si por ella entendemos la traducción, enclave mujer, de las actuales tendencias de liderazgo político vigentes en la región. Por el contrario, intento argumentaren favor de un liderazgo que supere el caudillismo como estilo y se aproxime al máximo hacia el respeto de las formas, entendiendo que sin ellas no es posible construir la democracia. Para hacerlo reviso rápid...

  16. Fiscal 1993 investigational report on heat pump heat storage technology; 1993 nendo heat pump chikunetsu gijutsu ni kansuru chosa hokokusho

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1994-03-01

    This project is for an investigation into the heat pump (HP) use heat storage technology, with the aim of clarifying the present status of HP heat storage technology, the utilization status, and the developmental trend of technology and of contributing to the spread of heat energy effective use using HP heat storage technology and to the promotion of the technical development. Accordingly, the evaluation of the following was made: sensible heat (SH), latent heat (LH), chemical heat storage technology (CH), and heat storage technology (HS). Investigations were made on the sensible heat use heat storage technology of water, brine, stone, soil, etc. in terms of SH; the phase change sensible heat use heat storage technology of ice, hydrate salt, paraffins, etc. in terms of LH; hydration, hydroxide, 2-propanol pyrolysis, adsorption of silica gel, zeolite and water, and heat storage technology using metal hydride, etc. in terms of CH. In terms of HS, the following were studied and evaluated from the study results of the heat storage system in which HP is applied to the sensible heat and latent heat type heat storage technology: contribution to the power load levelling and the reduction of heat source capacity, heat recovery and the use of unused energy, improvement of the system efficiency by combining HP and heat storage technology. 24 refs., 242 figs., 56 tabs.

  17. Fiscal 1995 investigation on biological fixation of carbon dioxide; 1995 nendo seibutsuteki CO2 kotei ni kansuru chosa hokokusho

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1996-03-01

    To cope with the global warming caused by CO2, an investigation was conducted into biological fixation. It is necessary to make a many-sided and comprehensive study on the mechanism of CO2 fixation, the scale (area and carbon holding density), the rate and the environmental impact of the introduction of the technology and the technical problems, and to make a quantitative evaluation of each of the methods in order to make them practical proposals. The global ecosystem is classified into the land biota and ocean biota, and each typical ecosystem was surveyed in terms of the surface area, the carbon holding amount (presently existing amount), the net primary production amount, the required nutrient salt amount, the transpiration rate, etc. Next, a discussion was made on the increasing effect of the carbon fixation amount by changing the present ecosystem from the aspect of scale and rate. At the same time, a study was carried out of energy efficiency, economical efficiency and problems. Last, elementary technology was taken up which seems to be important for implementing measures for the biological carbon fixation. As to the ocean, it is necessary to obtain information, which is not sufficient to utilize marine biota for CO2 fixation, especially on the mechanism of depth-direction transfer of organism and its quantitative grasp. As to the land, one of the measures is conversion of the ecosystem where the amount of carbon fixed is small to the ecosystem where the amount is large. 249 refs., 58 figs., 51 tabs.

  18. Fiscal 2000 study on technology and marketability concerning phytoremediation; 2000 nendo phytoremediation ni kansuru gijutsu oyobi shijosei no chosa hokokusho

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    2001-03-01

    An investigative study was conducted on phytoremediation with the purpose of correcting soil contamination caused by heavy metals and the like. In Japan, in connection with the cadmium pollution along the Jintsugawa River region in Toyama Prefecture, a growth of botanical colony such as Athyrium ykoscense was confirmed having a high capacity in absorbing/accumulating heavy metals, with a possibility suggested that they may be utilized for phytoremediation. In a technological research for restoring the environment sustainingly in a wide area, feasibility has been proven to remove polluting agricultural chemicals in farmlands and toxic substance in old industrial sites by making forest trees like poplars, lawns and herbage function. In a project for the cleanup of oil contaminated soil after Gulf War, a demonstrative test of bioremediation for one hectare was performed and, after 15 month experiment, 80 to 90% of aliphatic compounds and 50 to 60% aromatic compounds were degraded. In EU Framework Program in Europe, phytoremediation projects have been implemented across the member countries. (NEDO)

  19. Report on Asian Environment Information Network; 'Asia kankyo joho network' ni kansuru hokokusho

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1996-03-01

    The goal is the construction of Asian Environment Information Network (AEInet) in accordance with a contract signed between Indonesia's LIPI (Indonesian Institute of Science) and NEDO under NEDO's Research Cooperation Project Concerning the Development of Environment Measuring Laser Radar (LR). The network is so designed and constituted as to operate on a private line between Indonesia and Japan via IP (Internet protocol) and to enable the exchange on the Internet network of the data collected/analyzed by the Indonesian LR system and of articles of e-mail between scientists of the two countries. The AEInet will be utilized for the collection/analysis of LR-collected data; exchange of observed data and the result of processing; provision of support to environment information scientists in exchanging e-mail and information; and the search of databases for the implementation of the project. In this paper, the outline and functions of the system, network system design, WWW server construction, network operating status, joint researches with Indonesia, etc., are described. (NEDO)

  20. International Workshop on Carbon Cycling and Coral Reef Metabolism; Sangosho no tanso junkan ni kansuru kokusai workshop hokokusho

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1995-10-16

    The paper described the International Workshop on Carbon Cycling and Coral Reef Metabolism which was held at Miyako-jima, Okinawa Pref. on October 17-24, 1995. In the workshop, researchers got together which are involved in marine chemistry, marine biology, coral ecology, and environmental science, and discussed the carbon cycling and metabolism of coral reef. Discussions were made on what the coral reef ecosystem is, and what the definition of a sink or a source for CO2 is. Also discussed were scales of how much time and space should be considered to make these issues clear. Further, it was proposed that it was necessary to investigate carbon balance of both the whole system and the components of the system and to keep track of mass transfer among neighboring components of the system. Seventeen presentations were given. The workshop obtained a definite consensus on carbon balance of the coral reef system. 123 refs., 39 figs., 9 tabs.

  1. Global environmental benefits of industrial heat pumps (fiscal 1993); 1993 nendo koon heat pumping gijutsu ni yoru chikyu ondanka keigen koka ni kansuru chosa kenkyu hokokusho

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1994-03-01

    An investigational study was conducted aiming at making a quantitative grasp of effects of the spread of industrial heat pumps on energy conservation and greenhouse gas reduction and at promoting the spread. Finally, the following eight countries joined this international joint research: Canada, France, Japan, Holland, Norway, Sweden, the U.K. and the U.S. Each country share the work and expenses for the research with each other. Japan made investigational researches on the application of heat pumps to processes of the chemical industry, oil refining industry, food industry, paper/pulp industry, and dyeing/weaving industry, and on the effects of greenhouse gas reduction. As procedures taken, values up to 2010 were estimated of energy prices in each country, energy supply/demand, rates of the heat source configuration for electric power supply, etc., the heat flow of the above-mentioned process was made clear, and analyses were conducted of annual profits, energy consumption, and depreciation period in the case of adopting heat pumps. Moreover, the energy conservation amount and greenhouse effect gas reduction amount were estimated based on the result of the analyses. 69 figs., 196 tabs.

  2. FY 2000 report on the survey of geological structures overseas, etc. Volume 1. 'Tanjung Enim IV Coal Exploration Project between Japan and Indonesia'; 2000 nendo kaigai chishitsu kozo nado chosa hokokusho. 1. Nippon Indonesia sekitan kyodo tansa Tanjung Enim project

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    2001-03-01

    The paper summarized the results of the surveys in the final fiscal year (FY 2000) and in the past five years of the Tanjung Enim IV Coal Exploration Project between Japan and Indonesia. In FY 2000, conducted in the South Arahan area were the surface reconnaissance (50km+ACI-2), boring survey (11 holes, 1,847m), borehole physical logging (11 holes), reflection method seismic survey (3 traverse lines), pumping test, coal analysis (112 specimens), etc. As a result of the exploration/study made during 5 years, coal reserves in the South Arahan area were 223 million tons in north block (proved coal reserves: 213 million tons) and 332 million tons (proved coal reserves: 303 million tons) in south block. The coal in the area is in the depth of {+-}0m from surface, and the coal reserve is enough for large scale open pit mining. Further, coal reserves in the Banjarsari area were 442 million tons (proved coal reserves: 330 million tons) in the whole area and 223 million tons (proved coal reserves: 214 million tons) in the syncline part. About the syncline part promising as that for open pit mining, the overburden ratio was divided into three for calculation: 2:1, 3:1 and 4:1 or below. (NEDO)

  3. Fiscal 1998 research report. Research on the possibility of promoting CDM project through technology transfer with plant exports; 1998 nendo chosa hokokusho. Plant yushutsugata gijutsu iten wo tsujita CDM project suishin kanosei ni kansuru chosa hokokusho

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1996-03-01

    Study was made on promotion of CDM (clean development mechanism) project through technology transfer with plant exports. Although CDM system was provided in COP3 on climate change held in Kyoto in 1997, its detailed rules including project approval are yet undecided, and only the schedule to provide the detailed rules until COP6 in 2000 was decided in COP4 in 1998. The common recognition that the CDM project with plant exports produces various merits for both Japan and the partner country is increasing. However, from the viewpoint of forming concrete CDM projects, most Japanese enterprises are passive in approach to the CDM project because of no detailed design of CDM, uncertain profitability and procedures, and avoidance of additional burdens. Plant export is also difficult because of the fact that assessment of a new project is difficult. Enterprises' deeper recognition on the CDM project, and a governmental integrated support system are desirable. (NEDO)

  4. Fiscal 1998 research report on information structuring technology for advanced use of NEDO research reports; 1998 nendo NEDO seika hokokusho nado no kodo riyo ni hitsuyona joho kozoka gijutsu no chosa hokokusho

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1999-03-01

    Research was made on electronic NEDO research reports corresponding to the recent extending trend of Internet. The logical structure and electronic format of NEDO research reports as document were first studied considering document disclosure and reuse of technical information. HTML as electronic format for Internet is unfortunately insufficient to describe the logical structure of NEDO research reports because of HTML's restricted description. Thus, XML which is being watched because of its possible definition of original tags was studied in place of HTML. As a result, because at present preparation of standards on XML and a compatibility for implementation of standards are insufficient, it was concluded that construction of the electronic document system for NEDO research reports is still too early. However, since adoption of XML as document format is important from the viewpoint of a property succession on Internet, preparation of the XML format file of NEDO research reports is essential. (NEDO)

  5. Research report of fiscal 1997. Study on total energy and material control (feasibility study on circulating society); 1997 nendo chosa hokokusho. Total energy and material control ni kansuru chosa (junkangata shakai kochiku kanosei chosa) chosa hokokusho

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1998-03-01

    In order to construct real sustainable global environment and human society in the 21st century called the century of environment, not only the innovation of manufacturing processes technically supporting such the construction but also the conception including the innovation of the whole society from a wide viewpoint are essential. As a total energy and material control system (TEMCOS) concept, the view of an energy-saving circulating society is attempted which minimizes a total energy and material flow in Japan, and the role and issue of manufacturing industry, in particular, material industry are extracted. As one of the targets of such a concept, the conception of an eco-town is also described. Paying attention on some important material industries including a mass material flow and consuming a large amount of energy such as metal, plastics and automobile industries, the study result on a material flow for every industry is arranged, and some effective issues contributing to minimize a material flow and control energy consumption and CO2 emission are extracted. 80 refs., 67 figs., 30 tabs.

  6. Fiscal 1997 survey report on the trend of global warming protection measures of substituting freons; 1997 nendo chosa hokokusho (daitai freon no chikyu ondanka taisaku doko ni kansuru chosa hokokusho)

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1998-03-01

    The trend survey was conducted of global warming protection measures by participation in international conferences, scientific society meetings and lecture meetings, and by literature surveys. We participated in the international conference on ozonosphere protection measures. In the 9th meeting of the nations which concluded the Montreal Protocol, the strengthening of restrictions on methyl bromide was decided on. In the UNEP solvent technology selection conference and the OORG conference of the World Bank, reports were made on substituting solvents in Japan, activities supporting developing countries, and the developmental trend of urethane use foaming agent. In the international conference on ozonosphere protection measures, introduced were the present status of Japan`s ODA for developing countries and examples of success of the substitution in the solvent field. The paper included nine reports on CFC destruction technology related literature made public in the past one year. The paper also introduced a comparative study of de-HCFC substituting technology at U.S. Oak Ridge National Laboratory, U.S. EPA`s prediction of emission of fluorine 3 gas, the predicted value of HFC emission and trial calculation of contributing rate in all greenhouse gases by IIR, Green Peace and Elf Atochem, and NOAA`s measured data on SF6 in the atmosphere. 49 refs., 46 figs., 26 tabs.

  7. Specialty education in periodontics in Japan and the United States: comparison of programs at Nippon Dental University Hospital and the University of Texas Health Science Center at San Antonio.

    Science.gov (United States)

    Osawa, Ginko; Nakaya, Hiroshi; Mealey, Brian L; Kalkwarf, Kenneth; Cochran, David L

    2014-03-01

    Japan has institutions that train qualified postdoctoral students in the field of periodontics; however, Japan does not have comprehensive advanced periodontal programs and national standards for these specialty programs. To help Japanese programs move toward global standards in this area, this study was designed to describe overall differences in periodontics specialty education in Japan and the United States and to compare periodontics faculty members and residents' characteristics and attitudes in two specific programs, one in each country. Periodontal faculty members and residents at Nippon Dental University (NDU) and the University of Texas Health Science Center at San Antonio (UTHSCSA) Dental School participated in the survey study: four faculty members and nine residents at NDU; seven faculty members and thirteen residents at UTHSCSA. Demographic data were collected as well as respondents' attitudes toward and assessment of their programs. The results showed many differences in curriculum structure and clinical performance. In contrast to the UTHSCSA respondents, for example, the residents and faculty members at NDU reported that they did not have enough subject matter and time to learn clinical science. Although the residents at NDU reported seeing more total patients in one month than those at UTHSCSA, they were taught fewer varieties of periodontal treatments. To provide high-quality and consistent education for periodontal residents, Japan needs to establish a set of standards that will have positive consequences for those in Japan who need periodontal treatment.

  8. Bridging exchange bias effect in NiO and Ni(core)@NiO(shell) nanoparticles

    Energy Technology Data Exchange (ETDEWEB)

    Rinaldi-Montes, Natalia, E-mail: nataliarin@gmail.com [Departamento de Física, Universidad de Oviedo, E-33007 Oviedo (Spain); Gorria, Pedro [Departamento de Física & IUTA, EPI, Universidad de Oviedo, E-33203 Gijón (Spain); Martínez-Blanco, David [Servicios Científico-Técnicos, Universidad de Oviedo, E-33006 Oviedo (Spain); Fuertes, Antonio B. [Instituto Nacional del Carbón, CSIC, E-33080 Oviedo (Spain); Fernández Barquín, Luis [CITIMAC, Facultad de Ciencias, Universidad de Cantabria, E-39005 Santander (Spain); Puente-Orench, Inés [Instituto de Ciencia de Materiales de Aragón, CSIC-Universidad de Zaragoza and Institut Laue-Langevin, BP 156, F-38042 Grenoble Cedex 9 (France); Blanco, Jesús A. [Departamento de Física, Universidad de Oviedo, E-33007 Oviedo (Spain)

    2016-02-15

    Among all bi-magnetic core(transition metal)@shell(transition metal oxide) nanoparticles (NPs), Ni@NiO ones show an onset temperature for the exchange bias (EB) effect far below the Néel temperature of bulk antiferromagnetic NiO. In this framework, the role played by the magnetism of NiO at the nanoscale is investigated by comparing the microstructure and magnetic properties of NiO and Ni@NiO NPs. With the aim of bridging the two systems, the diameter of the NiO NPs (~4 nm) is chosen to be comparable to the shell thickness of Ni@NiO ones (~2 nm). The EB effect in Ni@NiO NPs is attributed to the exchange coupling between the core and the shell, with an interfacial exchange energy of ΔE~0.06 erg cm{sup −2}, thus comparable to previous reports on Ni/NiO interfaces both in thin film and NP morphologies. In contrast, the EB detected in NiO NPs is explained in a picture where uncompensated spins located on a magnetically disordered surface shell are exchange coupled to the antiferromagnetic core. In all the studied NPs, the variation of the EB field as a function of temperature is described according to a negative exponential law with a similar decay constant, yielding a vanishing EB effect around T~40–50 K. In addition, the onset temperature for the EB effect in both NiO and Ni@NiO NPs seems to follow a universal dependence with the NiO crystallite size. - Highlights: • Comparison of the exchange bias effect in NiO and Ni(core)@NiO(shell) nanoparticles. • Universal temperature dependence of the exchange bias effect. • Suggested similar physical origin of the effect in both systems. • Size and crystallinity of the NiO shell hold the key for exchange bias properties.

  9. ZnNi data

    Science.gov (United States)

    2014-11-01

    information only) BE AMERICA’S BEST STRENGTH AND HONOR Additional LHE Zn-Ni Hydrogen Re-Embrittlement Testing  The original LHE Zn-Ni test...follows:  LHE Zn-Ni tank contamination • Spring ‘09 Lab analysis showed organic contamination • The PVC tank liner had begun to break down and had...to be replaced in the Summer ‘09 with a more robust grade of PVC liner • Two years operating with new liner with no problems  Inconsistent plating

  10. OpenNI cookbook

    CERN Document Server

    Falahati, Soroush

    2013-01-01

    This is a Cookbook with plenty of practical recipes enriched with explained code and relevant screenshots to ease your learning curve. If you are a beginner or a professional in NIUI and want to write serious applications or games, then this book is for you. Even OpenNI 1 and OpenNI 1.x programmers who want to move to new versions of OpenNI can use this book as a starting point. This book uses C++ as the primary language but there are some examples in C# and Java too, so you need to have about a basic working knowledge of C or C++ for most cases.

  11. FY 2000 report on the results of the R and D of solid oxide fuel cells (SOFC); 2000 nendo kotai denkaishitsugata nenryo denchi no kenkyu kaihatsu seika hokokusho

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    2001-05-01

    Development of fuel cell power generation technology and R and D of solid oxide fuel cells were carried out, and reports of the FY 2000 results of companies were summed up. As to the R and D of the cell module, the R and D on the wet type cylinder module were made jointly by Toto Ltd., Kyushu Electric Power Co. and Nippon Steel Corp. As to the R and D of materials/basic technology, the following were conducted: evaluation of reliability of the cell module (evaluation of thermal cycle characteristics, etc.) by Chubu Electric Power Co., evaluation of reliability of the cell module (cell characteristics/stress evaluation) by Tokyo Gas Co. Ltd., cost reduction of cell materials (evaluation of chemical characteristics) by Central Research Institute of Electric Power Industry, and cost reduction of cell materials (evaluation of mechanical/thermal characteristics) by Japan Fine Ceramics Center. Concerning the system study, study of the system (adaptation fields of the small system and the optimization) was conducted by Nippon Steel Corp. (NEDO)

  12. Preprint of the 40th material study joint lecture of Science Council of Japan; Dai 40 kai Nippon gakujutsu kaigi zairyo kenkyu rengo koenkai maezurishu

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1996-09-19

    The paper stated mostly topics from special lectures. Composite materials have a lot of potentialities, and there are larger expectations in flexible and high-strength soft composites rather than the conventional high rigidity ones. As to micro-machines, the problems are on mechanical property of the element, environment/friction/fracture/life, etc. and the evaluation method of the characteristics was studied. Concerning the research and development of the intellectual structure system, the introductive study has entered the second year. Ultimately, structures have functions similar to those of the living organism had, and conduct self-diagnosis, self-repair and autonomous-response. Railroad structures receive regular inspections according to the rule, and a half of the objects for the inspection are cracks, unbonding and weathering of concrete. With the Hanshin Awaji great earthquake especially, the anti-earthquake reinforcement has been expedited. In various kinds of materials, the finer the crystal particle becomes, the greater the high temperature deforming ability becomes. When the particle size is below the critical particle size, it shows superplasticity. The study is advancing. As to high density secondary batteries, introduced especially were Ni-hydrogen batteries and Li batteries.

  13. Production of cloned NIBS (Nippon Institute for Biological Science) and α-1, 3-galactosyltransferase knockout MGH miniature pigs by somatic cell nuclear transfer using the NIBS breed as surrogates.

    Science.gov (United States)

    Shimatsu, Yoshiki; Yamada, Kazuhiko; Horii, Wataru; Hirakata, Atsushi; Sakamoto, Yuji; Waki, Shiori; Sano, Junichi; Saitoh, Toshiki; Sahara, Hisashi; Shimizu, Akira; Yazawa, Hajime; Sachs, David H; Nunoya, Tetsuo

    2013-01-01

    Nuclear transfer (NT) technologies offer a means for producing the genetically modified pigs necessary to develop swine models for mechanistic studies of disease processes as well as to serve as organ donors for xenotransplantation. Most previous studies have used commercial pigs as surrogates. In this study, we established a cloning technique for miniature pigs by somatic cell nuclear transfer (SCNT) using Nippon Institute for Biological Science (NIBS) miniature pigs as surrogates. Moreover, utilizing this technique, we have successfully produced an α-1, 3-galactosyltransferase knockout (GalT-KO) miniature swine. Fibroblasts procured from a NIBS miniature pig fetus were injected into 1312 enucleated oocytes. The cloned embryos were transferred to 11 surrogates of which five successfully delivered 13 cloned offspring; the production efficiency was 1.0% (13/1312). In a second experiment, lung fibroblasts obtained from neonatal GalT-KO MGH miniature swine were used as donor cells and 1953 cloned embryos were transferred to 12 surrogates. Six cloned offspring were born from five surrogates, a production efficiency of 0.3% (6/1953). These results demonstrate successful establishment of a miniature pig cloning technique by SCNT using NIBS miniature pigs as surrogates. To our knowledge, this is the first demonstration of successful production of GalT-KO miniature swine using miniature swine surrogates. This technique could help to ensure a stable supply of the cloned pigs through the use of miniature pig surrogates and could expand production in countries with limited space or in facilities with special regulations such as specific pathogen-free or good laboratory practice. © 2013 John Wiley & Sons A/S.

  14. Production of cloned NIBS (Nippon Institute for Biological Science) and α-1, 3-galactosyltransferase knockout MGH miniature pigs by somatic cell nuclear transfer using the NIBS breed as surrogates

    Science.gov (United States)

    Shimatsu, Yoshiki; Yamada, Kazuhiko; Horii, Wataru; Hirakata, Atsushi; Sakamoto, Yuji; Waki, Shiori; Sano, Junichi; Saitoh, Toshiki; Sahara, Hisashi; Shimizu, Akira; Yazawa, Hajime; Sachs, David H.; Nunoya, Tetsuo

    2013-01-01

    Background Nuclear transfer (NT) technologies offer a means for producing the genetically modified pigs necessary to develop swine models for mechanistic studies of disease processes as well as to serve as organ donors for xenotransplantation. Most previous studies have used commercial pigs as surrogates. Method and Results In this study, we established a cloning technique for miniature pigs by somatic cell nuclear transfer (SCNT) using Nippon Institute for Biological Science (NIBS) miniature pigs as surrogates. Moreover, utilizing this technique, we have successfully produced an α-1, 3-galactosyltransferase knockout (GalT-KO) miniature swine. Fibroblasts procured from a NIBS miniature pig fetus were injected into 1312 enucleated oocytes. The cloned embryos were transferred to 11 surrogates of which five successfully delivered 13 cloned offspring; the production efficiency was 1.0% (13/1312). In a second experiment, lung fibroblasts obtained from neonatal GalT-KO MGH miniature swine were used as donor cells and 1953 cloned embryos were transferred to 12 surrogates. Six cloned offspring were born from five surrogates, a production efficiency of 0.3% (6/1953). Conclusions These results demonstrate successful establishment of a miniature pig cloning technique by SCNT using NIBS miniature pigs as surrogates. To our knowledge, this is the first demonstration of successful production of GalT-KO miniature swine using miniature swine surrogates. This technique could help to ensure a stable supply of the cloned pigs through the use of miniature pig surrogates and could expand production in countries with limited space or in facilities with special regulations such as specific pathogen-free or good laboratory practice. PMID:23581451

  15. RESISTENCIA CHIMILA: NI ANIQUILADOS, NI VENCIDOS

    Directory of Open Access Journals (Sweden)

    Edgar Rey Sinning

    2009-08-01

    Full Text Available En este artículo se examina de forma sucinta la respuesta que los Chimilas dieron al proceso de usurpación de su territorio, mostrando cómo lograron resistir y lucharon por recuperar su espacio social, al tiempo que se señalan los efectos que tuvo sobre ellos el último proceso de ocupación territorial que, con fines capitalistas, el Estado colombiano y las economías privadas llevaron a cabo, pese al cual no fueron “ni aniquilados ni vencidos”. Finalizaremos este artículo señalando las características de las últimas fundaciones en territorio Chimila y su lucha por la supervivencia. Para su elaboración se reunió una variada información, a partir de diversos documentos históricos recolectados en archivos nacionales y regionales, diarios, cartas y crónicas de viajeros, además de las diversas reflexiones que han elaborado, antropólogos, sociólogos e historiadores sobre la temática.

  16. and ni(ii)

    African Journals Online (AJOL)

    userpc

    with nickel(II) and cobalt(II) chloride in 2:1 mole ratio yielded Ni(II) and Co(II) complexes respectively. The synthesized compounds were characterized based on melting point/decomposition temperature, solubility, molar conductance, magnetic susceptibility and infrared spectral analyses. The complexes have low molar ...

  17. FY 1998 annual report on the research and development of superhigh-sensitivity photocurrent conversion devices; 1998 nendo chokokando koden henkan soshi ni kansuru kenkyu kaihatsu chosa hokokusho

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1999-03-01

    Described herein are research and development of superhigh-sensitivity photocurrent conversion devices. The huge photocurrent multiplication effect exhibited by a thin film of organic pigment semiconductor is expected to be applicable to various new devices, e.g., superhigh-sensitivity, intelligent optical sensor families and photocurrent devices. Photocurrent multiplier thin films of perylene is prepared by an ionized cluster beam method, to evaluate their structures and photocurrent characteristics as the basic knowledge for controlling their characteristics by the ion engineering procedures. Photocurrent multiplier thin films of new, two-layer structure are developed, and improvement and stabilization of their characteristics are studied. Increasing sensing sensitivity by, e.g., introduction of p-n junction and reducing dark current resulting from the light memory effect are found to be effective to improve the S/N ratio. An organic EL light-emitting layer capable of positive/negative feedback, as one of the elementary techniques for realizing intelligent devices, is made on a trial basis and evaluated for its characteristics, and studied for its application to photocurrent multiplier thin films. Functional devices in which the arithmetic and controlling functions of the thin films are utilized are also studied. (NEDO)

  18. FY 1996 annual report of investigation on biological fixation of carbon dioxide. 2; 1996 nendo seibutsuteki CO2 kotei ni kansuru chosa hokokusho. 2

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1997-03-01

    Various kinds of biological fixation processes of CO2 were evaluated from the various viewpoints. Afforestation of tropical and temperate areas, greening of desert, biomass energy production in these areas by energy plantation, coastal mangrove plantation, fertilization with nitrogen and phosphate to outer ocean and coastal, upwelling zone fertilization with iron, and coral reef expansion combined with OTEC (ocean thermal energy conversion) were comparatively investigated as the selected measures. As a result, the cost of CO2 fixation by cultivation of sea weed and plankton was much higher than that of afforestation. The iron fertilization method which was considered to be one of the high CO2 reduction potentials might be economical. However, its effect could not be quantitatively evaluated. The afforestation of tropical and temperate areas seemed to be most feasible in a short term from the viewpoints of economy and environment. It was suggested that the establishment of a systematic water management technology could make greening and afforestation of desert. 76 refs., 27 figs., 28 tabs.

  19. Report on the field test project for wind power development at Matsushima (wind characteristics investigation); Matsushima ni okeru furyoku kaihatsu field test jigyo (fukyo seisa) hokokusho

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1998-11-01

    The test was conducted at Matsushima, Oseto Town, Nishisonogi-gun, Nagasaki Prefecture, for a year. The annual average wind speed is 4.3m/s at 20m above ground, lower than the reference value (5.8m/s). Wind speed variation is great in the cold season and small in the warm season, which is typical of Japan's climate. A maximum instantaneous wind speed to exceed wind turbine system wind-resisting capacity is not likely to occur. At the site selected for investigation, there is no manifestly prevailing wind direction, and caution needs to be exercised relative to mutual interference in case plural wind turbine systems are built. The exponential value in the wind speed vertical distribution is 7.1. The turbulence intensity index is 0.14 (for 4.0m/s or higher), which indicates a relatively small scale. As for wind energy density, it is short of the level indicated by U.S. Department of Energy. Wind turbines of 150 kW, 300 kW, and 750 kW are assumed, and they all work beyond NEDO (New Energy and Industrial Technology Development Organization) indicated operating rates, and will also satisfy NEDO indicated capacity ratios when their wattage is higher than 300 kW. Although Matsushima is not necessarily an excellent place for wind power development in view of the annual average wind speed, it is concluded that possibilities are that Matsushima will satisfy the requisites for a wind power development site if large wind turbine systems with the hub positioned high are introduced. (NEDO)

  20. FY 1998 annual report on the surveys on high-efficiency power generation techniques of the next generation; 1998 nendo jisedai kokoritsu hatsuden gijutsu ni kansuru chosa hokokusho

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1999-03-01

    Comprehensive surveys on and assessment of seeds of the high-efficiency power generation techniques of the next generation, both domestic and overseas, are conducted to help propose preliminary national research themes. In FY 1998, the survey efforts are directed not only to the trends of those for industrial power generation under development, e.g., combined cycle, coal-gasification combined cycle and pressurized fluidized bed combined cycle, but also to the trends of newly proposed systems, e.g., humid air combined cycle, methane reforming combined cycle, fuel reforming/humid air combined cycle, fuel reforming/fuel cell combined cycle and micro gas turbine, to further enhance efficiency by integration with a gas turbine power generation system. The efforts are also directed to (new power generation techniques in the basic research stage) being studied mainly by academic and research organizations, and to development trends of new power generation techniques under development by private enterprises, mainly based on the patent survey. (NEDO)

  1. International symposium on environmental impacts of advanced alternative to CFC; CFC shinki daitai busshitsu no kankyo eikyo ni kansuru kokusai symposium hokokusho

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1996-02-07

    The international symposium on environmental effects of new CFC substitutes was held in Tsukuba City, Ibaraki Pref. on February 7-9, 1996, and 19 papers were made public. In Session 1 (Plenary lecture), reports were made on Global warming and climate change: a review of recent studies; Stratospheric ozone, CFCs, and CFC-substitutes: an update, etc. In Session 2, Measurements of OH rate constants for advanced refrigerants as well as HCFCs and HFCs; The reaction rate of CFC alternatives with OH radical; Experimental and estimated rate constants: reactions of hydroxyl radicals with several halocarbons, etc. In Session 3, Measurement of uptake coefficients of some acetyl halides and fluorinated ethers into water; Mass transfer at the air/water interface: removal processes of halocarbonyl compounds; Heterogeneous reactions of fluorinated ethers on allophane or titanium dioxide, etc. In Session 4, papers were reported on model calculations relating to the global warming.

  2. Evaluation report on research and development of a subsea petroleum production system; Kaitei sekiyu seisan system no kenkyu kaihatsu ni kansuru hyoka hokokusho

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1985-03-01

    In order to assure stable supply of oil and natural gas resources, and achieve enhancement in ocean development technologies in general, development has been made on the subsea petroleum production system (SBPPS), which is effective in ocean floor petroleum production from oil fields at great depths (300 m or deeper), and can be applicable to continental shelves and continental slopes around Japan. The SBPPS consists of four sub-systems of shafts, pipelines, manifolds, and riser and oil storage, whose basic development targets were established for the total system. The system was given a conceptual design for the total system, and the above four sub-systems were designed according to the conceptual design. The experimenting devices of each system were fabricated on a trial basis while fundamental studies are being made on component technologies, and experiments were performed to verify basic functions of the sub-systems. Developments were made on such operation technologies as the system operation technology, production control technology, safety control technology, and maintenance and repair technology required to operate the SBPPS. On-shore and general off-shore experiments were carried out to verify the functions of the experimenting devices of each system, the comprehensive functions and the operation technology. Comprehensive evaluation was given on the above achievements from the technical, economic and social viewpoints. (NEDO)

  3. Research report of fiscal 1997. Basic research on the commercialization of innovative energy technologies; 1997 nendo chosa hokokusho. Kakushinteki energy gijutsu no jitsuyoka ni kansuru kiso chosa

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1998-03-01

    This paper summarizes the research result in fiscal 1997 from the basic research results on the commercialization of innovative energy technologies. The target of a photovoltaic power generation market includes isolated power sources (several kWp) for distant places or developing countries, and those (several tens kWp) for personal residences or public facilities. Although the former is mainly promoted in the West, while the latter over the world, their profitability is unsolved. Power plants over several hundreds kWp are in demonstration test. Solar heat power generation of several tens to hundreds MWp is most profitable, however, small-scale one is poor in feasibility. Australia takes an interest in distributed photovoltaic power generation directly connected with actual lives of residents, and has a dominant opinion that desert is useless as large-scale site. This country lays emphasis on protection and maintenance rather than positive use of desert based on a basic cognition that desert is easily changed and broken. The Australian government announced power company`s obligation to use renewable energy by 2%, and a strong organization is scheduled to be newly established. 59 figs., 57 tabs.

  4. Report of 'Survey on Asian environmental information networks'; 'Asia kankyo joho network chosa' ni kansuru hokokusho

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1994-03-01

    This project is implemented to survey the current statuses and future trends of the Asian district environment-related information networks, for the (research cooperation project for development of environmental condition measuring laser radar systems), being promoted by NEDO. First, current statuses of the network names, managing organizations, user numbers, conditions of use, protocols for use, service conditions, major domestic nodes and internationally connected conditions are surveyed mainly for internet-connected networks, for surveying the current statuses and future trends of the research networks in Asian countries. Second, current statuses in Indonesia of the network names, managing organizations, user numbers, conditions of use, protocols for use, service conditions, domestic node sites and managing organizations, charge systems and institutions, types/reliability/ stability of the circuits, and conditions of restriction of use, if any, for surveying the current statuses and future trends in Indonesia. Third, conditions of and needs for network utilization by researchers for Asian district environments. (NEDO)

  5. Report on the field test project for wind power development at Kamiyaku Town (wind characteristics investigation); Kamiyakucho ni okeru furyoku kaihatsu field test jigyo (fukyo seisa) hokokusho

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1998-11-01

    Wind characteristics are observed for a year at the above town located at the northern end of the Yakushima island, Kagoshima Prefecture. The exponential index of the wind speed distribution in the vertical direction is 6.06 with all the directions averaged, and is so high as 8.4/13.6 in the wind directions (W/E). Prudence should be exercised, when to estimate the wind speed at the wind turbine hub altitude, against disjunction from the simple exponential law due to geographical peculiarities of the observation location. Turbulence intensity is low and is 0.15 when the wind speed is 2m/s or more, not exerting an ill effect on wind power development. As for the total wind direction occurrence rate on the prevalent wind axis, 78.2% is recorded, which is much higher than the reference value (60%). The average wind speed on this wind axis is high, and this shows that the location is quite suitable for wind power development. The annual average wind speed of 6.3m/s is much higher than the reference value, this again promising a success. The wind energy density of 478W/m{sup 2} is sufficiently high, as compared with the reference value (215W/m{sup 2}). Since there are possibilities of a maximum instantaneous wind speed of over 60m/s, caution is to be used in determining wind endurance for the wind turbine design. The annual capacity ratios for the 150/300/750kW wind turbine models are 33.8/36.5/36.9%, respectively, higher than the NEDO-provided reference value (17% or higher) and predicting sufficient power generation. (NEDO)

  6. Report on the field test project for wind power development at Oshima Village (wind characteristics investigation); Oshimamura ni okeru furyoku kaihatsu field test jigyo (fukyo seisa) hokokusho

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1998-11-01

    Wind characteristics are observed for a year at Oshima City, Fukuoka Prefecture. The annual average wind speed is 6.7m/s at 20m above ground, reflecting the general trend in Japan's climate that wind is strong in the cold season and weak in the warm season. The wind direction occurrence rate is the highest of 13.2% in the ENE direction. Now that the occurrence of the NE, SW, and WSW directions occupying the same wind axis is also high throughout the year, Oshima Village is suitable for wind turbine installation. Since the wind speed is high in the high-occurrence NE-ESE directions, the relation between the wind direction occurrence rate and wind speed is said to be convenient. The conditions for a success in wind power development, that the wind speed be 5.8m/s or more and energy density 215W/m{sup 2} or more at an altitude of 20m above the ground, are satisfied at this observation station. As for the operation rate and capacity ratio of each of 150kW, 300kW, and 750kW wind turbine models, they are all over the reference values. The site is highly promising as a wind power development site because all the wind turbine availability conditions, such as the annual average wind speed, annual wind energy density, operating rate, and capacity ratio are found to be better than the reference values.

  7. Fiscal 1999 survey report. Survey and research concerning development of next-generation chemical process technologies; 1999 nendo jisedai kagaku process gijutsu kaihatsu ni kansuru chosa kenkyu hokokusho

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    2000-03-01

    To further enhance resource/energy conservation and environmental impact reduction, it is necessary to develop innovative chemical reaction process technologies. It is for this reason that 'development of next-generation chemical reaction process technologies' is being carried out under the New Sunshine Program. The survey and research, for the fulfilment of the above goal, aim to select important technologies and put in a easy-to-study order the problems contained in associated technologies for picking out tasks for future studies for the purpose of suggesting some subjects to be taken up for future development. In addition, studies are made about how a comprehensive technology assessment system should be. In this fiscal year, propositions are compiled for research and development projects on five subjects. Studies of subjects other than these five will also continue to eventually build concrete propositions on them. The said five subjects involve 1) the development and application of nonaqueous biotechnologies, 2) biotechnology-aided polymeric material creation processes, 3) construction of high-efficiency energy conservation processes using innovative grain handling technologies in the high-temperature reaction field, 4) manufacture of high-performance polymeric materials for batteries and development of battery fabrication processes, and 5) the development of an energy conservation process maximally utilizing environmentally-friendly polyolefin. (NEDO)

  8. Fiscal 1998 research report. Survey on the international standardization of top technologies; 1998 nendo chosa hokokusho. Sentan gijutsu no kokusai hyojunka ni kansuru chosa

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1999-03-01

    Survey was made on the trend of the international standardization of top technologies in developed countries. With a recent progress of technology business beyond boundaries, the interrelation between technology and industry is becoming complex increasingly. For construction of industrial technology policies, the factor analysis of the international standardization of top technologies is important. Recently, public standardization (promoted by public organizations) and de- facto standardization (formed in market competition) have been promoted in a top technology field. International comparison was made on the basis of the report on international comparison of technical competitive powers by the US government or non-profit organizations. Survey was made on the trend of international unification of standards and positioning of standards in enterprise strategy, and approaches of ISO, IEC, ITU and developed countries to standards. Case study was made on digital mobile telephone, IC card, OS for PCs, electric vehicle and fine ceramics. (NEDO)

  9. Survey report on an environmental harmony type production system of chemical products; Kankyo chowagata kagaku seihin seizo system ni kansuru chosa hokokusho

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1996-03-01

    As part of establishing an environmental harmony type production system of chemical products, study and survey were made on PET bottles. Using the life cycle analysis method (LCA), a study was made for proposing a material recycle (MR) method which is environmentally and economically excellent in the stage of recycling waste PET bottles. The total cost of recycling can be reduced by 34% supported by a decrease in equipment cost and improvement in yield if there is no mixture of foreign substances such as aluminum caps and PVC bottles. However, the ratio of the amount obtained from the reduction to the total production cost is small, and it is necessary to take measures from a viewpoint of the cost in a total production process and environmental loads. In a survey in Kawaguchi city, PET bottles discharged from the business sector occupied 41% of all the discharge amount. In a survey in Yokohama city, very important data were obtained on PET bottles appointed as the second type under the recycle law. The quality of PET bottles to be brought to the recycling plant is important for effectively processing PET bottles in MR method. For achievement of MR which is low in cost and small in environmental load, needed were cooperation by citizens, the shipping management system in autonomous government, and changes in design and material quality to be made by the industrial circle. 8 refs., 64 figs., 68 tabs.

  10. Evaluation report on research and development of an ultra-advanced processing system. 3; Chosentan kako system no kenkyu kaihatsu ni kansuru hyoka hokokusho. 3

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1994-08-01

    This paper describes comprehensive evaluation on the following technologies as the ultra-advanced processing system: (1) large output excimer laser, (2) high-density ion beam, (3) an ultra-precision machining device, (4) ultra-advanced processing, (5) measurement and evaluation, and (6) comprehensive test. In the item (1), research and development was performed on such technologies as output increasing, output stabilization and beam formation, having achieved the targets. In the item (2), research and development was performed on such technologies as beam convergence, plasma control, ion transportation, high-frequency quadruple pole acceleration, and large-capacity class ion beam, having achieved the targets. In the item (3), research and development was performed on form creation and ultra-precision machining, having achieved the targets. In the item (4), research and development was performed on formation of high function thin films to apply the laser abrasion process to large area, ion surface modification, wide band area optics, high reflectance optics, ion injection, dynamic mixing, and modification of ultra high-grade metal surface, having achieved the targets. In the item (5), research and development was performed on high-accuracy roughness measurement, shape measurement, optical property evaluation, a wavelength meter, ultra advanced processing standard measurement, and environment correction technology, having achieved the targets. In the item (6), comprehensive demonstration was carried out on the component technologies. (NEDO)

  11. Research report of fiscal 1997. Study on profitability evaluation technique for waste power generation; 1997 nendo chosa hokokusho. Haikibutsu hatsuden ni kansuru keizaisei hyoka shuho no kenkyu

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1998-03-01

    For diffusion of waste power generation, cost reduction is important. As the profitability evaluation technique for conventional waste power systems, a simple recovery year method, total waste treatment cost method, generation cost method, and evaluation method by accumulated balance sheet are presented along with their principles. For the generation cost method, trial calculation results are presented based on documents reported. From methods for the study in Institute of Applied Energy, some estimation methods of construction cost are presented, and generation cost and profitability evaluation were studied by parametric accumulation method. The profitability was calculated for RDF power systems, and it was clarified that although as a whole this system is more efficient than a simple refuse incineration system, the balance sheet of local governments is dependent on a responsibility range for the facility. In a combined type (super refuse power generation), generally municipalities bear a combustor and boiler, while a prefecture bears generation facilities. Because of large scale generation, the profitability is dependent on a selling price of electricity. 37 refs., 36 figs., 24 tabs.

  12. Report on `Survey of commercialization of intellectual ownership such as patent rights`; `Tokkyoken nado chiteki shoyuken no jitsuyoka ni kansuru chosa` hokokusho

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1997-03-01

    A survey was conducted on research results in industrial circles, universities, etc. in the U.S., Europe and Japan, especially the state of how intellectual ownership such as patent rights is handled and the present situation of the commercialization of intellectual ownership, proposing problems and measures to be taken for promotion of practical use of excellent research results in Japan. The most important thing obtained from the survey is that study jointly by industrial circles and universities in the U.S. and Europe is much more advancing than that in Japan and is firmly established not only in industrial circles, universities and national research institutes, but in the whole society, actually producing a lot of favorable results. For Japan to catch up with the U.S. and Europe, needed is not only accumulation of the ideas in the past, but drastic measures to be taken from a new point of view. Concretely, it was proposed that by belonging intellectual properties such as patent rights to universities/research institutes and transferring their disposal rights to them, royalties of licenses are given back to inventors as incentives, and that as a body promoting the transfer to the industrial circle, `management organization` to which private vitality is introduced is established in universities/research institutes in order to promote interconnection between the industrial circle and universities. 15 refs., 35 figs., 36 tabs.

  13. Research report for fiscal 1998. Research into the recycling of plastic wastes into resources; 1998 nendo hai plastic no saishigenka ni kansuru chosa hokokusho

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1999-03-01

    The actualities in Japan are investigated of the types and quantities of plastic wastes, collection and recovery systems, and recycling technologies. Plastic wastes exceeded 9-million tons in 1996, of which 39% was effectively utilized while 61% was merely incinerated or used for reclamation. The 61% of the plastic wastes which are equivalent to oil resources in terms of the energy they contain is found dealt with in such ways, for which additional energy has to be consumed. Some problems are mentioned that occur in the CO2 gas reduction effort in the process of plastic waste recycling for each of its stages of production, distribution, assortment, recovery, and reuse. The problems involve the required reform into production designs and systems with the greatest importance attached to recyclability; share of the expenses between the producing and distributing parties and financial support to assortment/recovery systems; reform of consciousness of both people at large and the administrative organizations, mutual collaboration between them, and reasonable share of expenses between them; construction of a unified assortment/recovery system; expansion of the scope of use of recycled products and the building of environments that encourage their use; diversification of recycling methods and establishment of technologies therefor; and limits on the use of materials and products that generate heavy impacts on environments during their life cycles. (NEDO)

  14. FY1998 report on the surveys and studies on developing next generation chemical process technologies; 1998 nendo jisedai kagaku process gijutsu kaihatsu ni kansuru chosa kenkyu hokokusho

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1999-03-01

    For further resource and energy conservation and environmental load reduction, development is necessary on innovative chemical reaction technologies. This paper describes surveys on next generation chemical processes. As non-halogen processes subject to development of new catalysts, new processes were investigated and searching experiments and discussions were given on isocyanate, propylene oxide, and phenol. Technological progress in the C1 chemistry was investigated. Problems in hydrocarbon compound oxidation, hydroxylation, and decomposition by utilizing microorganisms were put into order as application of environmentally friendly technologies. Marine biotechnical possibilities were surveyed. The surveys were given on new processes utilizing the phase transfer catalyst forming a third phase, manufacture of biodegradable plastics, and a novel reaction system combined with self-separation process using molecular assembly. Possibilities were searched on designing a truly simple production system of highly energy saving type. Such fundamental common technologies as structure analysis, property control and reaction engineering were investigated for methods to manufacture functional micro-powder chemical materials. Development was discussed on a system for technology assessment over whole product life cycle to structure a technology assessment basis. (NEDO)

  15. Report on survey of promotion of activities implemented jointly in China in FY 1997; 1997 nendo chosa hokokusho (Chugoku ni okeru kyodo jisshi katsudo no suishin chosa)

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1998-03-01

    Rapid economy growth has been observed in Asia including Japan. On the other hand, problems of population and environment grew even worse with the economic growth. Especially, China is the second CO2 emission country in the world. Large energy demand is still forecasted with its economic growth in the future. It is well-known that the energy consumption per unit GDP is very large. Therefore, it is very significant to promote the activities implemented jointly with China for mitigating the emission of greenhouse gases including CO2, which provides a significant meaning for solving global environmental issues as well as for improving regional environmental issues. It is necessary for the above to recognize the appropriate current situations and to promote the activities implemented jointly suitable for the country. Based on the discussions and information exchanges about environmental issues with staffs concerning environmental policies and scientists as well as the field surveys, methods for the activities implemented jointly were investigated to provide some proposals. 4 figs., 8 tabs.

  16. SOVRAŽNI GOVOR

    OpenAIRE

    Ajtnik, Mojca

    2015-01-01

    Pojem sovražnega govora izhaja iz anglosaškega sveta in temelji na prepričanju o manjvrednosti nekaterih ljudi, zaradi njihove pripadnosti določeni skupini. Sovražni govor je eden ključnih trenutkov v vzbujanju sovraštva do določenih skupin ljudi. Takšen govor je neizogibno povezan s predsodki, diskriminacijo in stereotipi. Je stalni spremljevalec človeške družbe, vedno večja prisotnost sovražnega govora v današnji družbi pa je posledica potrošniško in kapitalistično naravnane družbe. Na pora...

  17. Ni landsbyer i Danmark

    DEFF Research Database (Denmark)

    Larsen, Jacob Norvig

    Denne rapport beskriver en evaluering af statsstøttede forsøg med at styrke og udvikle mindre lokalsamfund. Forsøgene er gennemført i ni kommuner. Da der i disse år er stor opmærksomhed om de små byers og samfunds udviklingsmuligheder, har erfaringerne fra forsøgsprojekterne bred interesse. Forsø...

  18. Submicron particles of Co, Ni and Co–Ni alloys

    Indian Academy of Sciences (India)

    Home; Journals; Bulletin of Materials Science; Volume 24; Issue 5 ... Magnetic Materials Volume 24 Issue 5 October 2001 pp 515-521 ... Magnetic sub-micron sized particles (with diameters in the range 100–600 nm) of Co, Ni and Co–Ni alloys, protected with polyvinylpyrrolidone have been prepared in gram quantities ...

  19. Niños investigadores

    Directory of Open Access Journals (Sweden)

    Manfred Liebel

    2007-12-01

    Full Text Available EN LA SOCIOLOGÍA INFANTIL, EL PRINCIPIO DE HACER PARTICIPAR A NIÑAS Y NIÑOS en los procesos de investigación está ampliamente reconocido. Tomando como punto de partida ese principio de participación, el presente aporte analiza la pregunta de en qué medida y de qué manera los niños mismos pueden actuar como investigadores. A fin de apreciar en lo justo la perspectiva de los niños, el presente trabajo aboga por que –con el debido acompañamiento de personas adultas– la investigación esté en manos de los niños. Por medio de varios ejemplos de países del Sur, se muestra cómo poner en práctica esta forma de investigación encabezada por niños. Tomando en cuenta la desigualdad en las relaciones entre niñas, niños y personas adultas, el trabajo hace referencia a problemas de ética y práctica investigativa que surgen en el proceso de investigación y también en el tema del uso de los resultados. Finalmente, se explican los beneficios que niñas y niños pueden obtener de sus propias investigaciones.

  20. Report on the research cooperation promoting project in fiscal 1998. Research cooperation related to the mine waste water treatment technology utilizing biomass; 1998 nendo kenkyu kyoryoku suishin jigyo hokokusho. Bio riyo ni yoru kohaisui shori gijutsu ni kansuru kyoryoku

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1999-03-01

    This paper describes the achievement in relation with the mine waste water treatment technology utilizing biomass, from among the promotion projects for research cooperation with China. Waste water is converted into ferric iron (Fe{sup 3+}), which precipitates at low pH, by utilizing iron oxidizing bacteria which use ferrous iron (Fe{sup 2+}) in the waste water as the energy source, and is precipitated and removed by using low-cost calcium carbonate as a neutralizing agent. Fiscal 1998 has performed eight site surveys with 47 persons in total. The main survey items are the study and guidance of pilot plant operation and the survey on measures to prevent occurrence of contamination by heavy metals in Wushan Mine. Additional site surveys were made at Dexing Mine and Yinshan Lead/Zinc Mine. Continued from fiscal 1997, consumables required for the pilot plant were purchased, and items of the bench-scale testing equipment used by Japan for domestic researches (an oxidation and neutralization testing equipment and a copper recovering and testing equipment) were transported to China. The operation research data of the pilot plant were put in order and analyzed. This paper summarizes the concept design of the shaft waste water treatment facilities for the north mine in Wushan Mine, and the surveys on measures for heavy metal contamination sources. (NEDO)

  1. Report on research cooperation for bio-aided treatment of waste water from mining pits, conducted in FY1996. Data edition; 1996 nendo bio riyo ni yoru kohaisui shori gijutsu ni kansuru kenkyu kyoryoku hokokusho. Shiryohen

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1997-03-01

    This report carries the results of (1) surveys on properties of waste water discharged from pits in Wushan Mine in Province of Jiangxi, China, (2) monitoring the environments around the mine, (3) monitoring the environments around the mine (photographs) and (4) surveys on properties of waste water discharged from pits in other mines, and also outlines (5) the Chinese research activities. More specifically, it carries (1) water analysis results of pH and heavy metals at -40mL and -160mL pits and raw water pit on the earth's surface, (2) analysis results of pH and heavy metals for water discharged from the mine at 15 points, 7 at the north of the mine, 4 at the south of the mine, 2 at the tailings, 1 at Chihu, and 1 at the eastern tailings, (4) the data regarding waste water discharged from pits in 5 mines in the same province, including copper, copper-sulfur and copper-zinc mines, and (5) results of the (bacteria-culturing tests for high-efficiency oxidation of iron) carried out in Wushan Mine. The tests comprised the nutrient addition, raw water load and residence time tests, and the results of each test are reported. Fe (II) is oxidized to 95 to 98% at a residence time of 0.75 hours. (NEDO)

  2. FY1998 report on a survey related to joint utilization of welfare device development data using an international network; 1998 nendo kokusai network ni yoru fukushi kiki kaihatsu data no kyodo riyo ni kansuru chosa hokokusho

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1999-03-01

    A survey was made in relation with joint utilization of welfare device development data using an international network. Developing welfare devices requires data from ergonomic and medical systems, while the cope of the objects is wide, and the kinds are various. For proliferation of welfare devices, system compatibility evaluation including that on using environment is important, including living environments that are different by countries. The present survey has identified how data for aged, handicapped and help-needing persons are accumulated and utilized in research organizations in America and Europe for both of the ergonomic and medical areas. The survey also investigated major academic societies in overseas countries, and collected database and academic network information that support the advanced research and development. At the same time, investigations were also made on organizations and corporations who are moving forward the efficient data utilization. Welfare device and service information providing systems in Japan were investigated to compare them with the trends in other countries. Conceptions and methods were compiled to utilize data internationally and jointly. Database models for device development were considered, and a proposal was made on structuring a research and development supporting database, and the operation method thereof. (NEDO)

  3. Research cooperation project in fiscal 1998. General report on research cooperation related to mine waste water treatment technology by utilizing biotechnology; 1998 nendo kenkyu kyoryoku jigyo. Bio riyo ni yoru kohaisui shori gijutsu ni kansuru kenkyu kyoryoku sokatsu hokokusho

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1999-03-01

    This paper describes cooperative development of bio-treatment technology for mine waste water generated by operating mines in China. Certain types of bacteria have capability to oxidize ferrous iron in the waste water into ferric iron ions. The bacteria cause ferric iron oxides in low pH regions to get deposited, and can remove them from sedimentation by using cheap calcium carbonate as a neutralizer. Volumetric reduction in waste sediments may also be achieved during removing heavy metals in a pretreatment process. Great advance may be expected in taking actions to prevent water quality contamination. This paper summarizes activities taken in fiscal 1998. Eight site surveys in total were carried out using 47 persons in total. Major activities included operation study guidance of a pilot plant, and surveys for measures on heavy metal generation sources in Wushan Mine. In addition, site surveys were performed at Dexing Mine and Yinshan Zinc Mine. Subsequently from fiscal 1997, a bench scale testing equipment used in Japan and consumables were transported to China. The operation study data on the pilot plant were put into order and analyzed. Concept design was also made on a waste water treatment facility for Wushan Mine. (NEDO)

  4. FY 1997 report on the modification of dental materials with Ag for improvement of antibacterial activity; 1997 nendo chosa hokokusho (gin ion ni yoru shikayo zairyo no kokinsei fuyo ni kansuru kenkyu)

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1998-03-01

    Improvement of an antibacterial activity is one of the issues in modification of artificial teeth for an aged society. Study was made on improvement technique of an antibacterial activity with Ag ion as secondary corrosion measures. Partial gaps of dental materials themselves and gaps between materials and peripheral tissues causes bad breath or bad teeth through propagation of disease germs. Ag ion is harmless and has an antibacterial activity for bio-tissues from a macro-viewpoint, however, only corrosion germ causing bad teeth in mouths should be sterilized by controlling an elution rate of Ag properly. The antibacterial activity was controlled by controlling Ag ion implantation depth and rate, and Ag elution rate for dental materials. Experiment was made on an IMZ twinplus specimen implanted with Ag ion and an Ag thin film-coated specimen using beagle dog in comparison with an unmodified specimen. As a result, the very favorable antibacterial activity was obtained. Ag ion is effective for prevention of endogenous infectious disease due to mouth germs in dental surgery. 3 refs., 47 figs., 10 tabs.

  5. Research and survey report of FY 1997 on the CO2 balance for high-temperature CO2 fixation and utilization technology; 1997 nendo chosa hokokusho (nisanka tanso koon bunri gijutsu ni okeru CO2 balance ni kansuru chosa kenkyu)

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1998-03-01

    The purpose of this research is to clarify the application condition and effectiveness of high-temperature CO2 fixation and utilization technology. To evaluate the present process, it was compared with others, such as separation using a polymer membrane, physico-chemical absorption process, adsorption process, hydrogen contact reduction process, and biological fixation. The development trends of absorption, membrane, adsorption, and cryogenic separation were investigated. The questionnaire was carried out about the separation technologies which are in the stage of performance test using actual gas, to arrange and compare the data and information. The current trends of chemical and biological CO2 fixation and utilization technology were also investigated for arranging the subjects. High-temperature CO2 disposal by the carbonation in concrete waste has been studied, to clarify its application conditions and effectiveness. In order to compare the separation technologies, treatment processes of CO2 in the exhaust gas from boilers of LNG power generation and coal fired power generation were simulated. These processes were simulated by ASPEN PLUS for the modeling. Trends of application of ASPEN PLUS and collection of information were surveyed by participating in the ASPEN WORLD. 103 refs., 51 figs., 55 tabs.

  6. Fiscal 1998 research report on the metal thin film formation by UV laser photodecomposition of adsorbed organic metal compounds; Kyuchaku yuki kinzoku kagobutsu no shigai laser ko bunkai ni yoru usumaku sakuseiho ni kansuru kenkyu 1998 nendo chosa hokokusho

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1999-03-01

    Research was made on the new thin film formation method depositing metal or metal compound thin films by excimer laser photodecomposition of organic metal compounds condensed onto substrates at lower temperature. The organic metal compound was condensed onto cooled substrates (glass, semiconductor Si) from gas-phase iron pentacarbonyl below 250K in vacuum. KrF excimer laser was used as UV laser. The thin films with electric conductivity and metallic luster were deposited onto the laser irradiation areas of both substrates below 250K. The thin films were deposited only by proper laser pulse irradiation fluence (energy/unit area), and are composed of iron or its oxide. The deposition rate is estimated to be nearly 0.5nm/s, and precise control of film thicknesses is possible. Formation of pure metal and metal oxide thin films with various film thicknesses and compositions is probably possible by controlling thin film formation conditions. The iron thin film with characteristics of magnetic thin films is applicable to various fields, and is also important as the base for forming alloy films and multi-layered films. (NEDO)

  7. Report on research results of the development of high efficient boilers in fiscal 1996. Research development of high efficient industrial furnaces, etc; Koseino boiler no kaihatsu ni kansuru kenkyu seika hokokusho. Koseino kogyoro nado ni kansuru kenkyu kaihatsu

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1997-03-01

    Out of the developments of high efficient boilers which have been continued since fiscal 1993, the paper reported the result of the development conducted in fiscal 1996. The oxygen combustion (the oxygen enrichment combustion including 100% oxygen combustion) decreases the amount of flue gas and reduces heat loss of the flue gas, and is also effective as NOx reduction measures. The experiment was conducted using testing furnace. The boiler efficiency rapidly increased with the increasing concentration of oxygen enrichment. In the pure oxygen combustion, the overall boiler efficiency of a 106% level (low heating value standard) is expected. Since the boiler wet flue gas is decreased, the NOx emission is reduced. The boiler can raise the combustion temperature with no fear of NOx and can be reduced in size. CO2 decreases in proportion to the energy saving effect. The development of a condensation flue gas heat exchanger is aimed at recovering heat down to the low temperature. Prediction of heat transfer in the steam condensation region becomes possible, and the size reduction can be expected. Dew point corrosion resistant materials were also selected. As to the high speed combustion control, a simple type using micro-processor was developed. Obtained were high speed, compactness, electric power saving, and high controllability. 14 refs., 306 figs., 88 tabs.

  8. Survey report for fiscal 1998. Evaluation by industrial circles of the COP3 outcome and their future response (America); 1998 nendo chosa hokokusho. COP3 no kekka ni taisuru sangyokai no hyoka oyobi kongo no taio ni tsuite (Beikoku)

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1999-03-01

    Response in America to COP3 (Third Session of the Conference of the Parties to the United Nations Framework Convention on Climate Change) is investigated. Office of Energy Efficiency and Renewable Energy (EE) of America's Department of Energy conducts activities designed to protect environments and supports America's economic competitiveness. The scope of EE activities is quite wide, covering efforts at energy efficiency improvement and renewal energy utilization for all energy consuming sectors involving construction work and equipment for buildings, various industries and public utility works, and transportation. EE also supports and promotes the development of advanced industrial materials, electric vehicles, hybrid vehicles, fuel cells, etc. In the field of renewable energy, it deals with the exploitation of sunlight, biomass, wind force, water power, geothermal energy, etc. It also supports efficiency improvement efforts being undertaken through studies of advanced power transmission and distribution, high-temperature superconduction, energy storage, etc. The said supports are provided not only by Federal Government but also by state governments, and include financial aids. A number of programs are under way, worked out and promoted by the respective bureaus and departments. They are evaluated, protected, and implemented through the partnership of official and civilian organizations. (NEDO)

  9. Fiscal 1993 investigational study of a model of international cooperation for an environmentally harmony type green technosystem; 1993 nendo Oshu ni okeru haikibutsu shori oyobi recycle no doko ni kansuru chosa kenkyu hokokusho

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1994-03-01

    For the natural environment preservation, effective utilization of resources, and maintenance of the ecosystem, an international cooperation model was proposed for the environmental harmony type green technosystem. A comprehensive evaluating analysis of a green forest resource, etc. as the global resource, and an intensive extraction of subjects and needs was made. The analysis was conducted of technical possibility and abstract business development effects toward the industrialization with high values added which is in harmony with the environment. As a case study, the Papua New Guinea area, Malaysia was selected and re-evaluated. For this typical tropical forest area, a new technical system was studied based on the natural environment, industry/economy, social/cultural assessment, etc., and a model for industrializing new international cooperation was proposed. For the model making for industrialization, various steps to be taken and conditions to be prepared were studied and arranged for the realization. Upon going ahead with the international technical cooperation, Japan, a large lumber consuming country, needs to always consider the fostering and effective use of lumber resource in particular. 27 refs., 28 figs., 30 tabs.

  10. Reports on 1981 result of Sunshine Project. Research on conditioning required for industrialization of new energy technology; 1981 nendo shin energy gijutsu kigyoka ni hitsuyona joken seibi ni kansuru chosa kenkyu seika hokokusho

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1982-03-01

    This research was intended to establish foundation for the coming new energy era, by clarifying all interfering elements and taking counter measures, in further spreading and promoting the new phase of new energy technology development under the Sunshine Project. With the public section as the main body, studies were made in the technological aspect as well as the legal/institutional aspects, and also an investigation was conducted of the cases of introducing new energy from overseas. In the subject research, with 1990 set as the target year, the following examinations were carried out for the purpose of concretely estimating the situation of introducing new energy into the society in Japan at such point in time. The examinations were to study the feasibility of substitution with new energy in fiscal 1990 on the present level of oil consumption; to extract problems on the basis of the results and examining a policy of introducing and promoting new energy; and, to investigate on the spot, as a case study in building a coal liquefaction plant in a coal production area overseas, a relation with the energy policy of the producing country in implementing the overseas operation and importation of liquefied oil so produced, etc. (NEDO)

  11. FY 1999 report on the results of the R and D on high performance industrial furnace, etc.; 1999 nendo koseino kogyoro no kaihatsu ni kansuru kenkyu seika hokokusho. Koseino kogyoro nado ni kansuru kenkyu kaihatsu

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    2000-03-01

    In the development of high performance industrial furnace, initial targets were achieved such as energy saving of 30%, downsizing of 20%, and a remarkable NOx reduction. To verify the achievement, the test field project is being worked on by NEDO. In FY 1998, 23 heating furnaces, 29 heat treat furnaces and 6 melting furnaces were under the project at energy saving effect of 52,000 kl converted to crude oil. In FY 1999, 18 heating furnaces, 26 heat treat furnaces and 7 melting furnaces are now under the project at energy saving effect of 57,000 kl. The project was awarded 'The 9th Nikkei Global Environmental Technology Prize.' The themes for the R and D are as follows: high efficiency exhaust heat utilization system, self-completion type high temperature/high radiation heating technology, technology to make heat transfer in steel heating suitable under non-stationary state, high efficiency heat transfer technology, technology to optimize the shape of heating furnace, high performance atmosphere heat treat furnace, high efficiency heat transfer technology by high temperature jet flame heating, technology of high efficiency aluminum melting furnace, technology to improve soaking degree in steel heating, high performance tubular heating furnace in oil refining, optimum combustion control technology of regenerative burner furnace, and laser measuring method inside industrial furnace. (NEDO)

  12. Outline of investigation on restraint of carbon dioxide generation by green chemistry. 1999.1-1999.3; 1998 nendo green chemistry ni yoru CO2 hassei yokusei ni kakawaru chosa kenkyu chosa hokokusho

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1999-03-01

    Investigations were conducted into the above in some leading OECD (Organization for Economic Cooperation and Development) member states. Green chemistry is a new concept in which clean technology, environment-friendly chemistry, and the like are combined, and is a chemical solution for reducing or stopping the use or generation of materials, products, by-products, solvents, reagents, etc., which are dangerous to health and environments, throughout the whole life cycle of chemicals covering the processes of their designing, manufacturing, dumping, and recycling. In this fiscal year, the actual state of the generation of biomass, regarded as representative of reproducible materials, and its feasibility as chemical resources were investigated. In an effort at finding out chemical reactions safer to health and causing less environmental impact, investigations were also conducted into the recent trends of catalysts, novel reactions for organic syntheses, use of supercritical fluids, photocatalysts, biomimetic processes, etc. The development of substitutes for plastic additives was also studied. Since acceptance by the citizenry is quite important for green chemistry to take effect, educating and enlightening activities in the U.S., Britain, France, and Germany were inquired into. (NEDO)

  13. Research report of fiscal 1997. Survey on creation of high-efficiency renewable resources, and bioconversion technology; 1997 nendo chosa hokokusho. Kokoritsu saisei kano shigen no sosei narabi ni bioconversion gijutsu ni kansuru chosa

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1997-03-01

    Survey was made on material production technology using creation technology of high-efficiency renewable resources (photosynthesis reaction of plants). Industrially usable plant resources in overseas countries and Japan were arranged, and plant resources unused for food were also surveyed. The present state of genetic engineering necessary for metabolic engineering of higher plants such as fit and high-expression technology of genes, plant cell cultivation, and control technology of plant cell multiplication is described, and elementary technologies required for future gene-recombined plants are predicted. Survey was also made on the trend of creation technology of industrial plants for fat and oil, biodegradable polyester, amino acid, cellulose, fiber (cotton) and forest wood. A patent list on plant biotechnology was prepared, and study on bioconversion of plant resources was also surveyed. Overseas R & D trends on conversion and effective use technologies of renewable bio- resources are reported, and process design and its profitability were evaluated through a case study. 414 refs., 87 figs., 55 tabs.

  14. Fiscal 1999 research result report. Research on improvement of boiling heat transfer characteristics by photocatalyst wall; 1999 nendo hikari shokubai hekimen ni yoru futto netsu dentatsu tokusei kaizen ni kansuru kenkyu chosa hokokusho

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    2000-03-01

    Research was made on improvement of the wettability and boiling heat transfer characteristics of a photocatalyst wall. Measurement experiment of the wettability was made for anatase type titan oxide-coated Al, SUS and Pb plates, rutil type titan oxide-flame coated SUS plate, raw plate, and oxide-plasma coated titan plate. In the ground experiment, the contact angles of distilled water and oil on specimen surfaces were measured. In the microgravity experiment, falling droplet images were recorded by using the facility of Japan Microgravity Center (JAMIC). For obtaining the effect of radioactive emission, UV irradiation, {gamma} ray and neutron beam irradiation by nuclear reactor, and {gamma} ray irradiation by Co-60 were carried out. As the experiment result, the rutil type titan oxide-flame coated SUS plate, nonconductor-coated titan plate, and zircaloy plate showed large improvement of the wettability by {gamma} ray irradiation with Co-60. It was also confirmed that in particular, titan shows the large effect of radioactive emission, and the wettability deteriorates rapidly after {gamma} ray irradiation. (NEDO)

  15. FY 1997 report on the research study for preparation of NEDO`s vision. Biomass energy; 1997 nendo chosa hokokusho (NEDO vision sakutei ni muketa chosa kenkyu). Biomass energy ni tsuite

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1998-03-01

    Research study was made on the current usage, technological development and future subjects of biomass energy. The current use of biomass energy over the world estimated to be nearly a billion t/y oil equivalent. This value is estimated to be only a part of a pure primary biomass yield of 73 billion t/y oil equivalent showing a large supply potential. The evaluation result of a biomass energy potential in the world by GLUE (Global Land Use and Energy Model) considering worldwide biomass flow and competition of land use showed that no change of land use form in advanced areas is predicted, and no production of new biomass energy from forests in advancing areas is also expected. Production of biomass energy from farm products is promising in advanced areas, while the potential of biomass residue is high in advancing areas showing the possibility of energy development. Development of new biotechnologies such as molecular control of bio-production functions is expected to increase biomass resources. 76 refs., 26 figs., 30 tabs.

  16. Fiscal 1998 research report on the development trends of natural gas conversion technologies into liquefied fuel in Russia; 1998 nendo Roshia ni okeru tennen gas no ekitai nenryoka gijutsu no kaihatsu doko nado ni kansuru chosa kenkyu seika hokokusho

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1999-03-01

    Russia having natural gas resources largest in the world is actively promoting the basic research on liquefaction technology of natural gas such as Fischer-Tropsch (FT) synthetic catalyst, and its research potential is extremely high. This 3-year research project surveys the R and D trends of catalyst technology for liquefaction of natural gas, and fabricates the prototype FT synthetic catalyst based on the idea of Russian researchers to evaluate its feasibility experimentally. This report summarizes the following to clarify the research background: (1) The technology system for liquefaction of natural gas, and its future R and D trend, (2) The R and D trends of liquefaction technology of natural gas in the world, (3) The R and D trends of liquefaction technology of natural gas in Russia, (4) The research system of catalyses in Russia, (5) The activities of Russian catalysis research institutes, (6) The fuel liquefaction technologies of Russian major research institutes, and (7) The proposals from Russian research institutes. (NEDO)

  17. Fiscal 1998 research report on development of the advanced industrial furnace (R and D on the advanced industrial furnace). Volume 3; 1998 nendo koseino kogyoro no kaihatsu ni kansuru kenkyu seika hokokusho. Koseino kogyoro nado ni kansuru kenkyu kaihatsu

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1999-03-01

    This report summarizes the research results of the chapter 4 and 5 (experimental database) from the research report on development of the advanced industrial furnace. The chapter 4 summarizes functions of the temperature performance evaluation simulator of the advanced continuous heating furnace for the database system, and various research results obtained by the simulator. This chapter also summarizes the research result on the applicability of high-temperature air combustion to other industries, the patent research result on heat storage combustion technology, the basic technology research result, and the reaction analysis result by FLUENT. The chapter 5 summarizes the combustion experiment data collection by developing self-completion high-temperature high-radiation heating technology. As for R and D on technology optimizing the profile of heating furnaces, the following data are summarized: measurement data of heat transfer in furnaces and heat flux data at right overhead furnace temperature under cold air and preheated air combustion in conventional furnaces, and heat storage combustion. (NEDO)

  18. Oxidation behavior of Ni powder and Ni powder compact; Ni fun oyobi Ni fun atsufuntai no sanka kyodo

    Energy Technology Data Exchange (ETDEWEB)

    Yamazaki, M.; Ochiai, S.; Watanabe, Y. [Teikyo Univ., Tokyo (Japan)

    1997-09-15

    With an objective to investigate reactions of metal powder and metal powder compact having open pores with gases, their oxidation behavior was elucidated by taking Ni powder and Ni powder compact as examples. Oxidation rate of the Ni powder can be expressed by the Jander equation, and activation energy for the oxidation was 0.948 times 10 {sup 5} J/mol. Oxidation rate of the Ni powder compact is equal to that of powder not made into compact in the initial stage of the oxidation, but it decreases as time elapses because of occurrence of packing of oxide. Difference in oxidation rate inside and outside the powder compact is very little. The oxidation rate of the powder compact was analyzed by using an improved Jander model. More specifically, a model was used, in which concentration difference of diffused components in the oxides decreases with progress of the oxidation, whereas 1.113 times 10 {sup 5} J/mol was derived as the activation energy of the oxidation. The cause for the activation energy for the oxidation of the powder and powder compact being about half of that for bulk Ni is because of low temperature oxidation of the powder, and tensile stress generated between metal particles and spherical shell shaped oxides, which make production of Ni {sup 2+} more difficult. 5 refs., 4 figs., 1 tab.

  19. Nitriding behavior of Ni and Ni-based binary alloys

    Energy Technology Data Exchange (ETDEWEB)

    Fonovic, Matej

    2015-01-15

    Gaseous nitriding is a prominent thermochemical surface treatment process which can improve various properties of metallic materials such as mechanical, tribological and/or corrosion properties. This process is predominantly performed by applying NH{sub 3}+H{sub 2} containing gas atmospheres serving as the nitrogen donating medium at temperatures between 673 K and 873 K (400 C and 600 C). NH{sub 3} decomposes at the surface of the metallic specimen and nitrogen diffuses into the surface adjacent region of the specimen whereas hydrogen remains in the gas atmosphere. One of the most important parameters characterizing a gaseous nitriding process is the so-called nitriding potential (r{sub N}) which determines the chemical potential of nitrogen provided by the gas phase. The nitriding potential is defined as r{sub N} = p{sub NH{sub 3}}/p{sub H{sub 2}{sup 3/2}} where p{sub NH{sub 3}} and p{sub H{sub 2}} are the partial pressures of the NH{sub 3} and H{sub 2} in the nitriding atmosphere. In contrast with nitriding of α-Fe where the nitriding potential is usually in the range between 0.01 and 1 atm{sup -1/2}, nitriding of Ni and Ni-based alloys requires employing nitriding potentials higher than 100 atm{sup -1/2} and even up to ∞ (nitriding in pure NH{sub 3} atmosphere). This behavior is compatible with decreased thermodynamic stability of the 3d-metal nitrides with increasing atomic number. Depending on the nitriding conditions (temperature, nitriding potential and treatment time), different phases are formed at the surface of the Ni-based alloys. By applying very high nitriding potential, formation of hexagonal Ni{sub 3}N at the surface of the specimen (known as external nitriding) leads to the development of a compound layer, which may improve tribological properties. Underneath the Ni{sub 3}N compound layer, two possibilities exist: (i) alloying element precipitation within the nitrided zone (known as internal nitriding) and/or (ii) development of metastable and

  20. Abnormal Intermetallic Compound Evolution in Ni/Sn/Ni and Ni/Sn-9Zn/Ni Micro Solder Joints Under Thermomigration

    Science.gov (United States)

    Zhao, N.; Deng, J. F.; Zhong, Y.; Huang, M. L.; Ma, H. T.

    2017-04-01

    Interfacial reactions in Ni/Sn/Ni and Ni/Sn-9Zn/Ni micro solder joints during thermomigration (TM) have been studied by reflowing solder joints on a hot plate. Asymmetrical growth and transformation of interfacial intermetallic compounds (IMCs) were clearly observed. The growth of the Ni3Sn4 IMC in the Ni/Sn/Ni solder joints was always fast at the cold end and relatively slow at the hot end. Only asymmetrical growth of the Ni5Zn21 IMC in the Ni/Sn-9Zn/Ni solder joints occurred at the beginning because Zn was the dominant TM species; however, asymmetrical transformation of the Ni5Zn21 IMC also occurred under the combined effect of Zn depletion and Ni dissolution and migration, resulting in formation of a thin τ-phase layer at the hot end and a thick τ-phase/Ni5Zn21/τ-phase sandwich structure at the cold end. TM of Ni and Zn atoms was identified towards the cold end, being responsible for the abnormal IMC evolution. Addition of Zn was found to slow the TM-induced IMC growth and Ni dissolution.

  1. Electronic structure of Ni/sub 3/Al and Ni/sub 3/Ga alloys

    CERN Document Server

    Pong, W F; Chang, Y K; Tsai, M H; Hsieh, H H; Pieh, J Y; Tseng, P K; Lee, J F; Hsu, L S

    1999-01-01

    This work investigates the charge transfer and Al(Ga) p-Ni d hybridization effects in the intermetallic Ni/sub 3/Al(Ni/sub 3/Ga) alloy using the NiL/sub 3.2/- and K-edge and Al(Ga)K X-ray absorption near edge structure (XANES) measurements. We find that the intensity of white-line features at the NiL/sub 3.2/-edge in the Ni/sub 3/Al(Ni /sub 3/Ga) alloy decreased in comparison with that of pure Ni, which can be attributed to the enhancement of Ni3d states filling and the depletion of the density of Ni 3d unoccupied states in the Ni/sub 3 /Al(Ni/sub 3/Ga) alloy. Two clear features are also observed in the Ni/sub 3/Al(Ni/sub 3/Ga) XANES spectrum at the Al(Ga) K-edge, which can be assigned to the Al(Ga) unoccupied 3p (4p) states and their hybridized states with the Ni 3d/4sp states above the Fermi level in Ni/sub 3/Al(Ni/sub 3/Ga). The threshold at Al K-edge XANES for Ni/sub 3/Al clearly shifts towards higher photon energies relative to that of pure Al, indicating that Al loses charges upon forming Ni/sub 3 /Al. ...

  2. Measurement of 59Ni and 63Ni by accelerator mass spectrometry at CIAE

    Science.gov (United States)

    Wang, Xiaoming; He, Ming; Ruan, Xiangdong; Xu, Yongning; Shen, Hongtao; Du, Liang; Xiao, Caijin; Dong, Kejun; Jiang, Shan; Yang, Xuran; Lan, Xiaoxi; Wu, Shaoyong; Zhao, Qingzhang; Cai, Li; Pang, Fangfang

    2015-10-01

    The long lived isotopes 59Ni and 63Ni can be used in many areas such as radioactive waste management, neutron dosimetry, cosmic radiation study, and so on. Based on the large accelerator and a big Q3D magnetic spectrometer, the measurement method for 59Ni and 63Ni is under development at the AMS facility at China Institute of Atomic Energy (CIAE). By using the ΔE-Q3D technique with the Q3D magnetic spectrometer, the isobaric interferences were greatly reduced in the measurements of 59Ni and 63Ni. A four anode gas ionization chamber was then used to further identify isobars. With these techniques, the abundance sensitivities of 59Ni and 63Ni measurements are determined as 59Ni/Ni = 1 × 10-13 and 63Ni/Ni = 2 × 10-12, respectively.

  3. ni potni list

    Directory of Open Access Journals (Sweden)

    Ana Krajnc

    1996-12-01

    Full Text Available Decembra 1994 je bila v Rimu velika mednarodna konferenca o permanentnem ali vse življenje trajajočem izobraževanju. Široki strokovni javnosti sta bila takrat prvič predstavljena tudi dva nova pojma: osebni učni načrt in učni potni list. Pri priči sta se prijela v teoriji in praksi - očitno sta bila oba predloga odsev potreb.

  4. Relation between shape of Ni-particles and Ni migration in Ni-YSZ electrodes – a hypothesis

    DEFF Research Database (Denmark)

    Mogensen, Mogens Bjerg; Hauch, Anne; Sun, Xiufu

    2016-01-01

    pressure (pH2O) gradient as previously observed [1], but in the present cases Ni seems to migrate up the pH2O gradient. However, it is also observed that there is a preceding phase in this Ni-YSZ electrode degradation, namely that the Ni-particles closest to the YSZ electrolyte loose contact to each other...

  5. Comprehensive theoretical studies on the low-lying electronic states of NiF, NiCl, NiBr, and NiI.

    Science.gov (United States)

    Zou, Wenli; Liu, Wenjian

    2006-04-21

    The low-lying electronic states of the nickel monohalides, i.e., NiF, NiCl, NiBr, and NiI, are investigated by using multireference second-order perturbation theory with relativistic effects taken into account. For the energetically lowest 11 lambda-S states and 26 omega states there into, the potential energy curves and corresponding spectroscopic constants (vertical and adiabatic excitation energies, equilibrium bond lengths, vibrational frequencies, and rotational constants) are reported. The calculated results are grossly in very good agreement with those solid experimental data. In particular, the ground state of NiI is shown to be different from those of NiF, NiCl, and NiBr, being in line with the recent experimental observation. Detailed analyses are provided on those states that either have not been assigned or have been incorrectly assigned by previous experiments.

  6. CONFIGURATION-INTERACTION IN NI METAL AND NI-ALLOYS AND HIGH-ENERGY SPECTROSCOPY

    NARCIS (Netherlands)

    TANAKA, A; JO, T; SAWATZKY, GA

    We discuss the electronic state of Ni atoms in Ni metal and of Ni impurity in Cu and Au metals from the viewpoint of 3d configuration interaction (CI) using the Anderson impurity model including atomic multiplets. On the basis of the discussion, we give an interpretation for the Ni 2p-core X-ray

  7. Laser alloyed Al-Ni-Fe coatings

    CSIR Research Space (South Africa)

    Pityana, SL

    2008-10-01

    Full Text Available The aim of this work was to produce crack-free thin surface layers consisting of binary (Al-Ni, Al-Fe) and ternary (Al-Ni-Fe) intermetallic phases by means of a high power laser beam. The laser surface alloying was carried out by melting Fe and Ni...

  8. Kinetics of Ni2Si growth from pure Ni and Ni(V) films on (111) and (100) Si

    Science.gov (United States)

    Harith, M. A.; Zhang, J. P.; Campisano, S. U.; Klaar, H.-J.

    1987-01-01

    The kinetics of Ni2Si growth from pure Ni and from Ni0.93V0.07 films on (111) and (100) silicon has been studied by the combination of He+ backscattering, x-ray diffraction, Auger electron spectroscopy (AES) and transmission electron microscopy (TEM) techniques. The activation energies are 1.5 and 1.0 eV for pure Ni and Ni(V) films, respectively while the pre-exponential factors in Ni(V) are 4 5 orders of magnitude smaller than in the pure Ni case. The variations in the measured rates are related to the different grain size of the growing suicide layers. The vanadium is rejected from the silicide layer and piles up at the metalsilicide interface.

  9. Synthesis and catalytic performance of SiO2@Ni and hollow Ni microspheres

    Science.gov (United States)

    Liu, Xin; Liu, Yanhua; Shi, Xueting; Yu, Zhengyang; Feng, Libang

    2016-11-01

    Nickel (Ni) catalyst has been widely used in catalytic reducing reactions such as catalytic hydrogenation of organic compounds and catalytic reduction of organic dyes. However, the catalytic efficiency of pure Ni is low. In order to improve the catalytic performance, Ni nanoparticle-loaded microspheres can be developed. In this study, we have prepared Ni nanoparticle-loaded microspheres (SiO2@Ni) and hollow Ni microspheres using two-step method. SiO2@Ni microspheres with raspberry-like morphology and core-shell structure are synthesized successfully using SiO2 microsphere as a template and Ni2+ ions are adsorbed onto SiO2 surfaces via electrostatic interaction and then reduced and deposited on surfaces of SiO2 microspheres. Next, the SiO2 cores are removed by NaOH etching and the hollow Ni microspheres are prepared. The NaOH etching time does no have much influence on the crystal structure, shape, and surface morphology of SiO2@Ni; however, it can change the phase composition evidently. The hollow Ni microspheres are obtained when the NaOH etching time reaches 10 h and above. The as-synthesized SiO2@Ni microspheres exhibit much higher catalytic performance than the hollow Ni microspheres and pure Ni nanoparticles in the catalytic reduction of methylene blue. Meanwhile, the SiO2@Ni catalyst has high stability and hence it can be recycled for reuse.

  10. Fiscal 2000 survey of geological structures overseas. Exchange of engineers with Vietnam (Coal mining technology); 2000 nendo kaigai chishitsu kozo nado chosa hokokusho. Gijutsusha koryu jigyo (tanko gijutsu bun'ya) Vietnam

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    2001-03-01

    A coal mining engineer exchange project was implemented by Japan and Vietnam for improving on coal mining engineers' production and management technologies in the Asia-Pacific region. Six engineers were dispatched to Hon Cam Training School for mine workers, Hon Gai, where they taught in the period November 12 through December 2, 2000. There were 18 trainees, to whom lectures were given on 16 subjects including the steep slope mining method, excavation technology, transportation technology, ventilation control technology, production control technology, quality control technology, cost and material control, risk control, and centralized monitoring technology. Discussion was also held on the subjects. Ten trainees were invited and received mainly by Taiheiyo Coal Mining Corporation for the period August 24 through September 9, 2000, where they were given lectures and underwent training in the mine. The trainees also visited Isoko Power Station, Coal Research Institute of Idemitsu Kosan Co., Ltd., and Kushiro Plant of Nippon Paper Industries Co., Ltd. (NEDO)

  11. Formation of NiCrAlY/NiAl multi-layered coating by low pressure plasma spraying; Genatsu plasma yosha ni yoru NiCrAlY/NiAl tasomaku no seisei

    Energy Technology Data Exchange (ETDEWEB)

    Takizawa, H. [Industrial Res. Inst. of Nagano Pref., Nagano (Japan).; Yonehama, K.; Sugimoto, K.; Kobayashi, M. [Shinshu Univ., Nagano (Japan). Faculty of Education

    1997-12-15

    NiCrAlY/NiAl multi-layered coating was produced on SUS310S steel by means of mutual low pressure plasma spraying of NiCrAlY and Al powders which was accompanied with self-propagating high-temperature synthesis (SHS) reaction of metal deposits. The NiAl layer contained Ni3Al particles and Cr2Al phase along the fine grain boundary. Also, Ni3Al was detected in the NiCrAlY layer with a small amount of NiAl particles. As the result, high hardness was obtained in both the layers, i.e., 650HV in NiAl layer and 450HV in NiCrAlY one at 673K. The structure of the multilayered coating changed hardly during annealing lower than 973K because enriched Cr at NiCrAlY/NiAl interface suppressed NiAl + Ni3Al{yields}Ni5Al3 peritectoid reaction. The SHS reaction time of an compressed Al droplet in diameter of 50{mu}m was calculated as 4.17times10{sup -3} second. 20 refs., 9 figs., 3 tabs.

  12. niños preescolares

    Directory of Open Access Journals (Sweden)

    Claudia Rosario Portilla Ramírez

    2007-01-01

    Full Text Available Este estudio explora la relación entre la escritura y la comprensión de la referencia a través de una tarea de sinonimia en niños entre 5 y 6 años de edad, de origen latinoamericano, escolarizados en Barcelona (España. Las variables relacionadas con la tarea de sinonimia fueron (a la comprensión de la entidad lingüística nombre y (b el nivel de conceptualización de la escritura de los niños y la presencia de etiquetas escritas durante la tarea. Para la tarea de sinonimia se utilizaron pares de sinónimos dialectales del español (de Latinoamérica y de la Península Ibérica. Los resultados mostraron una diferenciación en el razonamiento de los niños, la cual dependía de la comparación entre lenguaje oral y lenguaje escrito en el desarrollo de la tarea, evidenciando una mayor aceptación de la sinonimia en la modalidad de lenguaje oral que en la modalidad de lenguaje escrito.

  13. Exclusive study of Ni+Ni and Ni+Au central collisions: phase coexistence and spinodal decomposition; Etude exclusive des collisions centrales Ni+Ni et Ni+Au: coexistence de phase et decomposition spinodale

    Energy Technology Data Exchange (ETDEWEB)

    Guiot, B

    2002-12-01

    The INDRA multidetector allowed us to study the Ni+Ni collisions at 32A MeV and the Ni+Au collisions at 52,4 MeV. Central collisions leading to 'quasi-fused' systems were isolated using multidimensional analysis techniques: the Discriminant Analysis and the Principal Component Analysis. Comparison with a statistical model shows that the selected events are compatible with thermodynamical equilibrium. The average thermal excitation energy is 5A MeV for both systems. Calculations of heat capacities show that the deexcitation of the hot sources are akin to a liquid-gas phase transition of nuclear matter. Indeed heat capacities exhibit a negative branch as expected for a phase transition of a finite system. The dynamics of this phase transition has been investigated by applying the charge correlation method. An enhanced production of events with equal-sized fragments has been evidenced for Ni+Au at 52A MeV. No signal was found for Ni+Ni at 32A MeV. Finally this method was improved by taking into account the total charge conservation. The signal is seen more clearly for Ni+Au at 52A MeV, but is ambiguous for Ni+Ni at 32A MeV. The path followed in the state diagram, or the involved time scales, seem to be different for these systems. (authors)

  14. Effect of air annealing on structural and magnetic properties of Ni/NiO nanoparticles

    Energy Technology Data Exchange (ETDEWEB)

    Nadeem, K., E-mail: kashif.nadeem@iiu.edu.pk [Nanomagnetism and Nanotechnology Laboratory, International Islamic University, Islamabad (Pakistan); Ullah, Asmat; Mushtaq, M.; Kamran, M.; Hussain, S.S. [Nanomagnetism and Nanotechnology Laboratory, International Islamic University, Islamabad (Pakistan); Mumtaz, M. [Materials Research Laboratory, Department of Physics, International Islamic University, Islamabad (Pakistan)

    2016-11-01

    We reported systematic study on structural and magnetic properties of nickel/nickel oxide (Ni/NiO) nanoparticles annealed under air atmosphere at different temperatures in the range 400–800 °C. The XRD spectra revealed two phases such as Ni and NiO. The average crystallite size increases with increasing annealing temperature. A phase diagram was developed between two phases versus annealing temperature using XRD analysis. At lower annealing temperatures, Ni phase is dominant which does not easily undergo oxidation to form NiO. The NiO phase increases with increasing annealing temperature. FTIR spectroscopy revealed an increase in the NiO phase content at higher annealing temperature, which is in agreement with the XRD analysis. SEM images showed that nanoparticles are well separated at lower annealing temperatures but get agglomerated at higher annealing temperatures. The ferromagnetic (FM) Ni phase content and saturation magnetization (M{sub s}) showed nearly the same trend with increasing annealing temperature. The nanoparticles annealed at 500 °C and 800 °C revealed highest and lowest M{sub s} values, respectively, which is in accordance with the XRD phase diagram. Coercivity showed an overall decreasing trend with increasing annealing temperature due to decreased concentration of FM Ni phase and increasing average crystallite size. All these measurements indicate that the structural and magnetic properties of Ni/NiO nanoparticles are strongly influenced by the annealing temperature. - Highlights: • Air annealing effects on structural and magnetic properties of Ni/NiO nanoparticles have been studied. • The XRD spectra revealed two phases such as Ni and NiO. • A phase diagram was developed between two phases versus annealing temperature using XRD analysis. • The magnetic properties are well governed by ferromagnetic Ni phase.

  15. A threonine stabilizes the NiC and NiR catalytic intermediates of [NiFe]-hydrogenase.

    Science.gov (United States)

    Abou-Hamdan, Abbas; Ceccaldi, Pierre; Lebrette, Hugo; Gutiérrez-Sanz, Oscar; Richaud, Pierre; Cournac, Laurent; Guigliarelli, Bruno; De Lacey, Antonio L; Léger, Christophe; Volbeda, Anne; Burlat, Bénédicte; Dementin, Sébastien

    2015-03-27

    The heterodimeric [NiFe] hydrogenase from Desulfovibrio fructosovorans catalyzes the reversible oxidation of H2 into protons and electrons. The catalytic intermediates have been attributed to forms of the active site (NiSI, NiR, and NiC) detected using spectroscopic methods under potentiometric but non-catalytic conditions. Here, we produced variants by replacing the conserved Thr-18 residue in the small subunit with Ser, Val, Gln, Gly, or Asp, and we analyzed the effects of these mutations on the kinetic (H2 oxidation, H2 production, and H/D exchange), spectroscopic (IR, EPR), and structural properties of the enzyme. The mutations disrupt the H-bond network in the crystals and have a strong effect on H2 oxidation and H2 production turnover rates. However, the absence of correlation between activity and rate of H/D exchange in the series of variants suggests that the alcoholic group of Thr-18 is not necessarily a proton relay. Instead, the correlation between H2 oxidation and production activity and the detection of the NiC species in reduced samples confirms that NiC is a catalytic intermediate and suggests that Thr-18 is important to stabilize the local protein structure of the active site ensuring fast NiSI-NiC-NiR interconversions during H2 oxidation/production. © 2015 by The American Society for Biochemistry and Molecular Biology, Inc.

  16. Microstructural investigations of Ni and Ni2Al3 coatings exposed in biomass power plants

    DEFF Research Database (Denmark)

    Wu, D. L.; Dahl, K. V.; Christiansen, T. L.

    2017-01-01

    temperature pack cementation. After exposure, microstructural investigations were performed by light optical and electron microscopy (SEM-EDS). Electroplated Ni coatings were not protective in straw firing power plants and exhibited similar corrosion morphology as uncoated tubes. For Ni2Al3 coatings......The present work investigates the corrosion resistance of Ni and Ni2Al3 coated austenitic stainless steel (TP347H) tubes, which were exposed in a biomass-fired boiler with an outlet steam temperature of 540 °C for 6757 h. The Ni2Al3 coating was produced by electroplating Ni followed by low......, the nickel aluminide layer was no longer adherent to the tube and was only found within the deposit. However, Ni2Al3 coatings had provided some protection compared to uncoated and Ni coated tubes. The formation of nickel chloride binds aggressive chlorine and slows down the active oxidation mechanism...

  17. Adherencia al tratamiento en niñas y niños con VIH

    OpenAIRE

    Ana María Ruiz Navia; Sandra Liliana Enríquez Lara; Paula Andrea Hoyos Hernández

    2009-01-01

    Este artículo describe y determina el grado de adherencia al tratamiento en niños y niñas con VIH/ SIDA teniendo en cuenta los comportamientos y las variables asociadas a ésta. La muestra estuvo conformada por 1 niño y 5 niñas, diagnosticados con VIH, y su respectivo cuidador primario, quienes respondieron a la entrevista semiestructurada de evaluación de adherencia para niños y niñas con VIH/ SIDA ad hoc y a la entrevista semiestructurada de evaluación de adherencia para niños y niñas con VI...

  18. The Ni-Al-Hf Multiphase Diffusion

    Directory of Open Access Journals (Sweden)

    Romanowska J.

    2016-06-01

    Full Text Available The generalized Darken method was applied to simulate the diffusion between γ-Ni| γ’-Ni3Al and γ’-Ni3Al|β-NiAl interfaces. The results of calculations were compared with the experimental concentration’s profiles of nickel, aluminum and hafnium in aluminide and hafnium doped aluminide coatings deposited by the CVD and PVD methods on pure nickel. The method deals with the Wagner’s integral diffusion coefficients and thermodynamic data - activities of components. The experimental results agree with the simulated ones.

  19. Laser welding of NiTi wires

    Energy Technology Data Exchange (ETDEWEB)

    Gugel, H. [Institute for Materials, Materials Technology, Ruhr-University Bochum, Bochum (Germany)], E-mail: hajo.gugel@rub.de; Schuermann, A.; Theisen, W. [Institute for Materials, Materials Technology, Ruhr-University Bochum, Bochum (Germany)

    2008-05-25

    The special properties of nickel-titanium shape memory alloys are currently used in micro-engineering and medical technology. In order to integrate NiTi components into existing parts and modules, they often need to be joined to other materials. For this reason, the present contribution deals with the laser welding of thin pseudoelastic NiTi wires (100 {mu}m) with an Nd:YAG laser. Based on extensive parameter studies, faultless joints were produced. This study deals with the structural changes occurring in the fusion and heat-affected zones, the performance of the joints in static tensile tests and their functional fatigue. It can be shown that NiTi/NiTi joints reach about 75% of the ultimate tensile strength of pure NiTi wires. For welding NiTi to steel, no interlayer was used. The dissimilar NiTi/steel joints provide a bonding strength in the fusion and heat-affected zones higher than the plateau stress level. NiTi/steel joints of thin wires, as a new aspect, enable the possibility to benefit from the pseudoelastic properties of the NiTi component.

  20. Effects of Ni vacancy, Ni antisite, Cr and Pt on the third-order elastic constants and mechanical properties of NiAl

    KAUST Repository

    Wu, Shaohua

    2014-12-01

    Effects of Ni vacancy, Ni antisite in Al sublattice, Cr in Al sublattice, Pt in Ni sublattice on the second-order elastic constants (SOECs) and third-order elastic constants (TOECs) of the B2 NiAl have been investigated using the first-principles methods. Lattice constant and the SOECs of NiAl are in good agreement with the previous results. The brittle/ductile transition map based on Pugh ratio G/B and Cauchy pressure Pc shows that Ni antisite, Cr, Pt and pressure can improve the ductility of NiAl, respectively. Ni vacancy and lower pressure can enhance the Vickers hardness Hv of NiAl. The density of states (DOS) and the charge density difference are also used to analysis the effects of vacancy, Ni antisite, Cr and Pt on the mechanical properties of NiAl, and the results are in consistent with the transition map. © 2014 Elsevier Ltd. All rights reserved.

  1. Continuum mechanics simulations of NiO/Ni-YSZ composites during reduction and re-oxidation

    DEFF Research Database (Denmark)

    Pihlatie, Mikko; Frandsen, Henrik Lund; Kaiser, Andreas

    2010-01-01

    expansion, diffusional creep, grain boundary sliding (GBS) and microcracking due to excessive stress. In the Ni/NiO phase, nonelastic strains in terms of diffusional and power law creep were implemented, and additionally for NiO deformation due to microcracking and/or pseudoplasticity. Semi...

  2. Preparation and characterization of Cu(111)-Ni and Cu(110)-Ni surface alloys

    NARCIS (Netherlands)

    Geus, John W.; Mesters, C.M.A.M.; Wermer, G.; Gijzeman, O.L.J.

    1984-01-01

    The interaction of Ni(CO)4/CO gas mixtures with Cu(111) and Cu(110) single crystal surfaces has been studied with ellipsometry. Auger electron spectroscopy, LEED and argon ion depth profiling. At room temperature Ni atoms with some CO ligands remain at the surface. The amount of Ni that can be

  3. Contexto Familiar: Diferencias Conductuales entre Niños y Niñas

    Directory of Open Access Journals (Sweden)

    María Aurelia Ramírez Castillo

    2005-01-01

    Full Text Available En este trabajo se investigan las diferencias por género en problemas de conducta. En una muestra de 200 sujetos (niños y niñas en tre 5 y 18 años de Granada (España, los resultados concluyen que los niños tienen más problemas de conducta delictiva que las niñas. Cuando existen conflictos matrimoniales y prácticas de crianza negativas, de nuevo los niños tienen más problemas externos que las niñas. En este trabajo se investigan las diferencias por género en problemas de conducta. En una muestra de 200 sujetos (niños y niñas en tre 5 y 18 años de Granada (España, los resultados concluyen que los niños tienen más problemas de conducta delictiva que las niñas. Cuando existen conflictos matrimoniales y prácticas de crianza negativas, de nuevo los niños tienen más problemas externos que las niñas.

  4. Structure-activity relations for Ni-containing zeolites during NO reduction. II. Role of the chemical state of Ni

    NARCIS (Netherlands)

    Mosqueda Jimenez, B.I.; Jentys, A.; Seshan, Kulathuiyer; Lercher, J.A.

    2003-01-01

    The influence of the metal in Ni-containing zeolites used as catalysts for the reduction of NO with propane and propene was studied. In the fresh catalysts, Ni is located in ion exchange positions for Ni/MOR, Ni/ZSM-5, and Ni/MCM-22. The formation of carbonaceous deposits, the removal of Al from

  5. Morphological control of Ni/NiO core/shell nanoparticles and production of hollow NiO nanostructures

    Energy Technology Data Exchange (ETDEWEB)

    Chopra, Nitin [University of Alabama, Department of Metallurgical and Materials Engineering, Center for Materials for Information Technology (MINT) (United States); Claypoole, Leslie [Fairmont State University (United States); Bachas, Leonidas G., E-mail: bachas@uky.ed [University of Kentucky, Department of Chemistry (United States)

    2010-10-15

    Chemical synthesis coupled with a microwave irradiation process allowed for the control of size (6-40 nm), shape, and shell thickness of Ni/NiO core/shell nanoparticles. In this unique synthetic route, the size of Ni nanoparticles (NiNPs) was strongly influenced by the nickel salt-to-stabilizer ratio and the amount of the stabilizer. Interestingly, it was observed that the shape of the nanoparticles was altered by varying the reaction time, where longer reaction times resulted in annealing effects and rupture of the stabilizer micelle leading to distinct shapes of Ni/NiO core/shell nanostructures. Product cooling rate was another important parameter identified in this study that not only affected the shape, but also the crystal structure of the core/shell nanoparticles. In addition, a simple and cost-effective method of microwave irradiation of NiNPs led to the formation of distinctly shaped hollow NiO nanoparticles. These high surface area core/shell nanoparticles with well-controlled morphologies are important and can lead to significant advancement in the design of improved fuel cells, electrochromic display devices, and catalysis systems.

  6. .';.:NI~

    African Journals Online (AJOL)

    nag was die terugtog van die Skotte, oor die woestyn, vir myle sigbaar soos die een ou krok na die ander opgegaan het in ligte laaie. Geen wonder dat luisteraars die volgende aand oor. Zeesenradio gehoor het hoe 8 Leer verslaan is dat hulle, in hulle dolIe vaart na die Delta, besig was om hulle voertuie te verband.

  7. Fiscal 1998 research report. Study on the possibility of international cooperation for high- efficiency urban heat use systems for CO{sub 2} reduction; 1998 nendo chosa hokokusho. CO{sub 2} sakugen no tame no toshi netsu riyo system kokoritsuka ni kakawaru kokusai kyoryoku kanosei chosa hokokusho

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1999-03-01

    This research aims at study on the possibility of international cooperation such as technology transfer and technical cooperation between developed countries for introduction of high-efficiency urban heat use systems into developing countries from the viewpoint of global warming control. On the case of a city in the south-eastern district in China, this research studies the principle of international cooperation such as technology transfer and research cooperation through survey on social and economical restrictions to their introduction into developing countries and study on a CO{sub 2} reduction effect by the introduction. This report describes the current technology for high-efficiency urban heat use systems in developed countries, the current energy use in Chinese cities and some issues, current heat use technologies, the case study on the potential and constraint of high- efficiency urban heat use systems, and the case study on the CO{sub 2} reduction effect of the high-efficiency urban heat use system. Expectation for Japanese technical cooperation as such international cooperation is described. (NEDO)

  8. FY 1998 result report. Report on the results of the examinational research on the trend of technology development in the iron/steel industry; 1998 nendo seika hokokusho. Tekko sangyo no gijutsu kaihatsu doko nado ni kansuru chosa kenkyu seika hokokusho

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1999-03-01

    The trend of the technology development in the Japanese iron/steel industry was compared with those in foreign countries and surveyed to increase the international competitive strength. From the viewpoints of technology, industry and goods, the iron/steel field was characterized based on the statistic data, and especially automobile use steel materials were selected such as cold rolling high tension steel sheet, surface treated steel sheet, and bearing sheet. The analysis of factors of competitive superiority was conducted, and the following were presented: measures for process continuation, and measures taken from the age of equipment and cost indexes. The paper also surveyed the trend of pig iron making/steel making technology in Asia. The present international technical competitiveness in the iron/steel industry in Japan, especially of automobile use steel sheet, is very high. This is because of the well-functioned demand-oriented development, and also as a result of the mutually influentially conducted equipment development such as process continuation and development of new goods, supposing the iron/steel continuous process and reduction in impurities. However, fears are the stagnation in the recent technical development strength and the saturation of new equipment. Moreover, the further heightening is needed of the international cost competitive strength of general-purpose products. (NEDO)

  9. Fiscal 1997 report on the results of the R and D on the invention of high-level combustion technology using the microgravity environment; 1997 nendo seika hokokusho (bisho juryoku kankyo wo riyoshita kodo nensho gijutsu soshutsu ni kansuru kenkyu kaihatsu) seika hokokusho

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1998-03-01

    For the purpose of achieving both the diversification of energy resources and the reduction in environmental pollutants in fuel exhaust gases, the paper conducted elucidation of combustion phenomena using microgravity facilities and research on combustors which make high-level combustion possible. In the experimental study using microgravity experimental facilities, conducted were evaluation experiments on combustion/evaporation of fuel droplets and droplet groups, elucidation/evaluation experiments of combustion characteristics of high-density fuels, evaluation experiments of flammability limit, and elucidation/evaluation experiments of emission mechanisms of NOx, etc. Analysis/evaluation of the data obtained and elucidation of the combustion mechanism were conducted. Further, by applying the results of the microgravity experiment, the high-level combustor experimental facilities were fabricated, and validation tests were started. In the international joint research with US`s NASA, the following were conducted using JAMIC`s facilities and NASA`s 2.2 second drop tower: study of mutual interference of droplet series combustion, study of binary system fuel droplet series combustion, study of combustion characteristics of solid fuels, study of behavior of flames around the lean flammable limit, etc. 151 refs., 253 figs., 7 tabs.

  10. Thermal neutron capture γ-ray spectroscopy of59Ni and61Ni

    Science.gov (United States)

    Harder, A.; Michaelsen, S.; Lieb, K. P.; Williams, A. P.

    1993-06-01

    The γ-radiation emitted after thermal neutron capture in isotopically enriched58Ni and60Ni was measured at the ILL high flux reactor by means of Ge/NaI detectors operated in Compton suppression and pair spectrometer mode. The neutron binding energies were determined as B n (59Ni)=8999.15(23) keV and Bn(61Ni)=7820.07(20) keV; some 95% of the total γ-ray fluxes through59,61Ni were assigned. The γ-ray strength functions of the primary transitions and the level densities are discussed.

  11. Who is El Niño?

    Science.gov (United States)

    Philander, S. George

    It is a curious story, about a phenomenon we first welcomed as a blessing but now view with dismay, if not horror [Philander, 1998]. We named it El Niño for the child Jesus, provided it with relatives—La Niña and ENSO—and are devoting innumerable studies to the description and idealization of this family. These scriptures provide such a broad spectrum of historical, cultural, and scientific perspectives that there is now confusion about the identity of El Niño. Trenberth [1997] summarizes the situation as follows.The atmospheric component tied to El Niño is termed the “Southern Oscillation.” Scientists often call the phenomenon where the atmosphere and ocean collaborate ENSO, short for El Niño-Southern Oscillation. El Niño then corresponds to the warm phase of ENSO. The opposite “La Niña” (“the girl” in Spanish) phase consists of a basinwide cooling of the tropical Pacific and thus the cold phase of ENSO. However, for the public, the term for the whole phenomenon is “El Niño.”

  12. nière's Disease

    Science.gov (United States)

    ... disease. Why do people get Ménière’s disease? Many theories exist about what happens to cause Ménière’s disease, ... changes. Some people claim that caffeine, chocolate, and alcohol make their symptoms worse and either avoid or ...

  13. Capture of Hydrogen Using ZrNi

    Science.gov (United States)

    Patton, Lisa; Wales, Joshua; Lynch, David; Parrish, Clyde

    2005-01-01

    Water, as ice, is thought to reside in craters at the lunar poles along with CH4 and H2 . A proposed robotic mission for 2012 will utilize metal/metal hydrides for H2 recovery. Specifications are 99% capture of H2 initially at 5 bar and 100C (or greater), and degassing completely at 300C. Of 47-systems examined using the van't Hoff equation, 4 systems, Mg/MgH2, Mg2Ni/Mg2NiH4, ZrNi/ZrNiH2.8, and Pd/PdH0.77, were considered likely candidates for further examination. It is essential, when selecting a system, to also examine questions regarding activation, kinetics, cyclic stability, and gas impurity effects. After considering those issues, ZrN1 was selected as the most promising candidate, as it is easily activated and rapidly forms ZrNiH 2.8 . In addition, it resists oxide poisoning by CO2, and H2O, while some oxidation by O2 is recommended for improved activation . The presence of hydrogen in the as received Zr-Ni alloy from Alfa Aesar posed additional technical problems. X-ray diffraction of the Zr-Ni powder (-325 mesh), with a Zr:Ni wt% ratio of 70:30, was found to consist of ZrH2, ZrNiH2.8, and ZrNi. ZrH2 in the alloy presented the risk that after degassing that both Zr and ZrNi would be present, and thus lead to erroneous results regarding the reactivity of ZrNi with H2 . Fortunately, ZrH2 is a highly stable hydride that does not degas H2 to any significant extent at temperatures below 300C. Based on equilibrium calculations for the decomposition of ZrH2, only 1 millionth of the hydride decomposed at 300C under a N2 atmosphere flowing at 25 ccm for 64 hours, the longest time for pretreatment employed in the investigation. It was possible, from the X-ray results and knowledge of the Zr:Ni ratio, to compute the composition of a pretreated specimen as being 76 wt% ZrNi and the balance ZrH2.

  14. Water dissociation on Ni(100), Ni(110), and Ni(111) surfaces: Reaction path approach to mode selectivity.

    Science.gov (United States)

    Seenivasan, H; Jackson, Bret; Tiwari, Ashwani K

    2017-02-21

    A comparative study of mode-selectivity of water dissociation on Ni(100), Ni(110), and Ni(111) surfaces is performed at the same level of theory using a fully quantum approach based on the reaction path Hamiltonian. Calculations show that the barrier to water dissociation on the Ni(110) surface is significantly lower compared to its close-packed counterparts. Transition states for this reaction on all three surfaces involve the elongation of one of the O-H bonds. A significant decrease in the symmetric stretching and bending mode frequencies near the transition state is observed in all three cases and in the vibrational adiabatic approximation, excitation of these softened modes results in a significant enhancement in reactivity. Inclusion of non-adiabatic couplings between modes results in the asymmetric stretching mode showing a similar enhancement of reactivity as the symmetric stretching mode. Dissociation probabilities calculated at a surface temperature of 300 K showed higher reactivity at lower collision energies compared to that of the static surface case, underlining the importance of lattice motion in enhancing reactivity. Mode selective behavior is similar on all the surfaces. Molecules with one-quantum of vibrational excitation in the symmetric stretch, at lower energies (up to ∼0.45 eV), are more reactive on Ni(110) than the Ni(100) and Ni(111) surfaces. However, the dissociation probabilities approach saturation on all the surfaces at higher incident energy values. Overall, Ni(110) is found to be highly reactive toward water dissociation among the low-index nickel surfaces owing to a low reaction barrier resulting from the openness and corrugation of the surface. These results show that the mode-selective behavior does not vary with different crystal facets of Ni qualitatively, but there is a significant quantitative effect.

  15. The Ni-YSZ interface

    DEFF Research Database (Denmark)

    Jensen, Karin Vels

    the samples with impure nickel electrodes showed an initial increase toward a high constant polarisation resistance, whereas the samples with pure nickel electrodes showed a considerable decrease to a low constant polarisation resistance with time. For both types of nickel the polarisation resistance dropped......The anode/electrolyte interface in solid oxide fuel cells (SOFC) is known to cause electrical losses. Geometrically simple Ni/yttria-stabilised zirconia (YSZ) interfaces were examined to gain information on the structural and chemical changes occurring during experiments at 1000°C in an atmosphere...... of 97% H2/3% H2O. Electrochemical impedance spectroscopy at open circuit voltage (OCV) and at anodic and cathodic polarisations (100 mV) was performed. A correlation of the electrical data with the structure development and the chemical composition was attempted. Nickel wires with different impurity...

  16. Niño maltratado

    Directory of Open Access Journals (Sweden)

    Ana Ivis Crespo Barrios

    1996-12-01

    Full Text Available Se presentan 200 niños maltratados que acuden al Hospital Pediátrico Docente "Juan Manuel Márquez" en el período comprendido de diciembre de 1990 a enero de 1992; éstos fueron seleccionados teniendo en cuenta los criterios de maltrato, y era el objetivo fundamental del estudio conocer cómo se comporta en nuestro medio. En los resultados se muestra que la forma más frecuente fue el tipo no intencional; la ingestión de tóxicos fue la forma de negligencia física más frecuente dentro del maltrato no intencional, ésta es más usual en los niños menores de 5 años; los trastornos psiquiátricos y el alcoholismo son favorecedores del maltrato intencional, la madre es la que más maltrata; la mortalidad por esta causa no fue elevada (5 fallecidos y los criterios de riesgo de maltrato tienen utilidad para su identificación.200 mistreated children who were seen at the "Juan Manual Márquez" Pediatric Teaching Hospital from December, 1990 to January, 1992, are presented. These patients were selected taking into consideration the abuse criteria. The main objective of this paper was to know how these criteria behave in our enviroment. According to the results, the most common form was the non-intentional type. The ingestion of toxic agents was the most frequent form of physical neglect within the non-intentional mistreatment, and it is the most usual among children under 5. Psychiatric disorders and alcoholism favor the intentional mistreatment, and the mother mistreats the most. Mortality due to this cause was not high (5 deaths, and the abuse risk criteria are useful for its identification.

  17. Nonenzymatic Glucose Sensor Based on In Situ Reduction of Ni/NiO-Graphene Nanocomposite

    Directory of Open Access Journals (Sweden)

    Xiaohui Zhang

    2016-10-01

    Full Text Available Ni/NiO nanoflower modified reduced graphene oxide (rGO nanocomposite (Ni/NiO-rGO was introduced to screen printed electrode (SPE for the construction of a nonenzymatic electrochemical glucose biosensor. The Ni/NiO-rGO nanocomposite was synthesized by an in situ reduction process. Graphene oxide (GO hybrid Nafion sheets first chemical adsorbed Ni ions and assembled on the SPE. Subsequently, GO and Ni ions were reduced by hydrazine hydrate. The electrochemical properties of such a Ni/NiO-rGO modified SPE were carefully investigated. It showed a high activity for electrocatalytic oxidation of glucose in alkaline medium. The proposed nonenzymatic sensor can be utilized for quantification of glucose with a wide linear range from 29.9 μM to 6.44 mM (R = 0.9937 with a low detection limit of 1.8 μM (S/N = 3 and a high sensitivity of 1997 μA/mM∙cm−2. It also exhibited good reproducibility as well as high selectivity.

  18. Asymmetry of inter-El Niño and -La Niña diversity

    Science.gov (United States)

    Kim, S.; Kug, J. S.

    2016-12-01

    Over the North Pacific, there is a distinctive asymmetry of inter-El Niño and -La Niña diversity in atmospheric teleconnection patterns, indicating a strong diversity during La Niña events. Recent studies suggested that the typical patterns of the extratopical teleconnections associated with El Niño-Southern Oscillation (ENSO) are predominantly explained by the relative roles of the equatorial central Pacific (CP) and western North Pacific (WNP) precipitation anomalies. We find that the diversity of WNP precipitation anomalies is greater during La Niña events than during El Niño events. It also implies that the diversity of WNP precipitation anomalies during La Niña events is responsible for the diversity in the extratropical teleconnection. Since the relationship of anomalous sea surface temperature (SST) to precipitation is quite sensitive for SST in the range of 27-28°C, the WNP precipitation differences located over the warm pool among La Niña events lead to considerable teleconnection changes. In addition, we find here that the CMIP5 models well simulate the overall diversity in the tropical precipitation and extratropical teleconnection patterns during La Niña events, but it fails to reproduce a detailed pattern difference of atmospheric teleconnection in inter-La Niña events.

  19. Engineering NiS/Ni2P Heterostructures for Efficient Electrocatalytic Water Splitting.

    Science.gov (United States)

    Xiao, Xin; Huang, Dekang; Fu, Yongqing; Wen, Ming; Jiang, Xingxing; Lv, Xiaowei; Li, Man; Gao, Lin; Liu, Shuangshuang; Wang, Mingkui; Zhao, Chuan; Shen, Yan

    2018-01-23

    Developing high-active and low-cost bifunctional materials for catalyzing the hydrogen evolution reaction (HER) and oxygen evolution reaction (OER) holds a pivotal role in water splitting. Therefore, we present a new strategy to form NiS/Ni2P heterostructures. The as-obtained NiS/Ni2P/carbon cloth (CC) requires overpotentials of 111 mV for the HER and 265 mV for the OER to reach a current density of 20 mA cm-2, outperforming their counterparts such as NiS and Ni2P under the same conditions. Additionally, the NiS/Ni2P/CC electrode requires a 1.67 V cell voltage to deliver 10 mA cm-2 in a two-electrode electrolysis system, which is comparable to the cell using the benchmark Pt/C||RuO2 electrode. Detailed characterizations reveal that strong electronic interactions between NiS and Ni2P, abundant active sites, and smaller charge-transfer resistance contribute to the improved HER and OER activity.

  20. Study of the central collisions in the reactions Ni + Al and Ni + Ni at 28 A.MeV; Etude des collisions centrales dans les reactions Ni + Al et Ni + Ni a 28 A.MeV

    Energy Technology Data Exchange (ETDEWEB)

    Lebreton, L.

    1995-12-01

    The work is in characterisation of mechanisms in the energy range of onset of multifragmentation (excitation energy of composed nucleus around 4 - 5 AMeV). This work focused on an experiment performed at the SARA facility, in Grenoble, using the AMPHORA multi detection array. I have been particularly interested in central collisions in the Ni + Al and Ni + Ni systems. The possibility to detect complete events for Ni + Al, and quasi-complete events for the Ni + Ni case, is the reason of this choice. Furthermore Ni + Ni presents the interest of a symmetrical system, for which the excitation energy per nucleon is maximum. The study of these reactions has been focused on the quasi-complete events (events for which at least 80 % of the total charge has been detected). Heavy ions produced in peripheral collisions are very likely emitted along the beam line or stopped in the plastic detectors, energy thresholds are too high for the quasi-target products detection, consequently by requiring complete or quasi-complete measurement of the total charge, we are able to detect mostly central events. The knowledge of informations like charge, energy or detection angles allows to isolate the source(s) and to reconstruct the size and the excitation energy of the source(s). Comparisons with simulations like sequential emission (GEMINI code), very deep inelastic collision or instantaneous emission (Berliner code) allows to characterise the first stage of the collision (binary collisions or central collisions) and the type of deexcitation of the source(s). Some calculations was also performed with the statistical model code MODGAN. Indeed azimuthal correlations seem to be a good tool in getting more information about involved reaction mechanisms. Comparisons with MODGAN provide information about angular momentum of the source and time delay between emissions of the two particles (separation between sequential or instantaneous process). (author). 69 refs.

  1. Ääniä tiloissa

    OpenAIRE

    Rehn, Nicolas

    2014-01-01

    Opinnäytetyössäni esittelen keväällä 2013 Pop & Jazz Konservatorion lounasravintolan WC:ssä toteuttamani liveinstallaation Ääniä tiloissa. Analysoin teokseni kautta taiteen ja musiikin tekemisen motiiveja ja symboliikkaa, sekä tilan funktiota paikkana jossa toteuttaa musiikkia ja taidetta. Tavoitteenani opinnäytetyössäni oli toteuttaa performatiivinen esitys joka on vahvasti sidoksissa tiettyyn paikkaan, tilaan ja aikaan, ja jonka äänimateriaali saa muotonsa tässä nimenomaisessa tilassa ...

  2. Ni{sub 3}Al aluminide alloys

    Energy Technology Data Exchange (ETDEWEB)

    Liu, C.T.

    1993-10-01

    This paper provides a brief review of the recent progress in research and development of Ni{sub 3}Al and its alloys. Emphasis has been placed on understanding low ductility and brittle fracture of Ni{sub 3}Al alloys at ambient and elevated temperatures. Recent studies have resulted in identifying both intrinsic and extrinsic factors governing the fracture behavior of Ni{sub 3}Al alloys. Parallel efforts on alloy design using physical metallurgy principles have led to properties for structural use. Industrial interest in these alloys is high, and examples of industrial involvement in processing and utilization of these alloys are briefly mentioned.

  3. New developments in Ni/Ti multilayers

    Energy Technology Data Exchange (ETDEWEB)

    Anderson, I.; Hoghoj, P. [Institut Max von Laue - Paul Langevin (ILL), 38 - Grenoble (France)

    1997-04-01

    It is now 20 years since super-mirrors were first used as a neutron optical element. Since then the field of multilayer neutron-optics has matured with multilayers finding their way to application in many neutron scattering instruments. However, there is still room for progress in terms of multilayer quality, performance and application. Along with work on multilayers for neutron polarisation Ni/Ti super-mirrors have been optimised. The state-of-the-art Ni/Ti super-mirror performance and the results obtained in two neutron-optics applications of Ni/Ti multilayers are presented. (author).

  4. Binary Ni-Nb bulk metallic glasses

    Science.gov (United States)

    Xia, L.; Li, W. H.; Fang, S. S.; Wei, B. C.; Dong, Y. D.

    2006-01-01

    We studied the glass forming ability of Ni-Nb binary alloys and found that some of the alloys can be prepared into bulk metallic glasses by a conventional Cu-mold casting. The best glass former within the compositional range studied is off-eutectic Ni62Nb38 alloy, which is markedly different from those predicted by the multicomponent and deep eutectic rules. The glass formation mechanism for binary Ni-Nb alloys was studied from the thermodynamic point of view and a parameter γ* was proposed to approach the ability of glass formation against crystallization.

  5. Nickel Release, ROS Generation and Toxicity of Ni and NiO Micro- and Nanoparticles.

    Directory of Open Access Journals (Sweden)

    Siiri Latvala

    Full Text Available Occupational exposure to airborne nickel is associated with an elevated risk for respiratory tract diseases including lung cancer. Therefore, the increased production of Ni-containing nanoparticles necessitates a thorough assessment of their physical, chemical, as well as toxicological properties. The aim of this study was to investigate and compare the characteristics of nickel metal (Ni and nickel oxide (NiO particles with a focus on Ni release, reactive oxygen species (ROS generation, cellular uptake, cytotoxicity and genotoxicity. Four Ni-containing particles of both nano-size (Ni-n and NiO-n and micron-size (Ni-m1 and Ni-m2 were tested. The released amount of Ni in solution was notably higher in artificial lysosomal fluid (e.g. 80-100 wt% for metallic Ni than in cell medium after 24h (ca. 1-3 wt% for all particles. Each of the particles was taken up by the cells within 4 h and they remained in the cells to a high extent after 24 h post-incubation. Thus, the high dissolution in ALF appeared not to reflect the particle dissolution in the cells. Ni-m1 showed the most pronounced effect on cell viability after 48 h (alamar blue assay whereas all particles showed increased cytotoxicity in the highest doses (20-40 μg cm2 when assessed by colony forming efficiency (CFE. Interestingly an increased CFE, suggesting higher proliferation, was observed for all particles in low doses (0.1 or 1 μg cm-2. Ni-m1 and NiO-n were the most potent in causing acellular ROS and DNA damage. However, no intracellular ROS was detected for any of the particles. Taken together, micron-sized Ni (Ni-m1 was more reactive and toxic compared to the nano-sized Ni. Furthermore, this study underlines that the low dose effect in terms of increased proliferation observed for all particles should be further investigated in future studies.

  6. Ni nanoparticles prepared by simple chemical method for the synthesis of Ni/NiO-multi-layered graphene by chemical vapor deposition

    Science.gov (United States)

    Ali, Mokhtar; Remalli, Nagarjuna; Gedela, Venkataramana; Padya, Balaji; Jain, Pawan Kumar; Al-Fatesh, Ahmed; Rana, Usman Ali; Srikanth, Vadali V. S. S.

    2017-02-01

    A new chemical method was used to obtain a high yield of nickel nanoparticles (Ni-NPs). The effect of solvent (distilled water, ethylene glycol, and ethanol) and surfactant (oleic acid and polyvinyl pyrrolidinone) on the morphology and crystallinity of the synthesized Ni-NPs has been investigated. The experimental results revealed that among the solvents mentioned above, ethanol gives the best results in terms of complete reduction, controlled morphology and size distribution of Ni-NPs. The surfactants played an important role in impeding the agglomeration and surface oxidation of Ni-NPs. The surfactants also affected the morphology of the Ni-NPs. The synthesized Ni-NPs are found to be quite stable in air. The best of the synthesized Ni-NPs were effectively used as catalysts for the synthesis of Ni/NiO-multi-layered graphene using catalytic chemical vapor deposition technique.

  7. Synthesis of Supported NiPt Bimetallic Nanoparticles, Methods for Controlling the Surface Coverage of Ni Nanoparticles With Pt, Methods Of Making NiPt Multilayer Core-Shell Structures and Application of the Supported Catalysts for CO2 Reforming

    KAUST Repository

    Li, Lidong

    2015-06-25

    Embodiments of the present disclosure provide for supported Ni/Pt bimetallic nanoparticles, compositions including supported NiPt nanoparticles, methods of making supported NiPt nanoparticles, methods of using supported NiPt nanoparticles, and the like.

  8. Fiscal 1997 survey report. Feasibility study of the environmentally friendly type coal utilization system (survey of the coal utilization in Pakistan); 1997 nendo chosa hokokusho. Kankyo chowagata sekitan riyo system kanosei chosa (Pakistan ni okeru sekitan riyo gaikyo chosa)

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1998-03-01

    This paper made a literature survey, hearing survey, site survey/study on the coal in Pakistan such as the coal utilization system and the environmental situation, etc., and aimed at pre-examination for the survey of the introduction of the environmentally friendly type coal utilization system to be planned in Pakistan in the future. The examination, data collection and preparation were conducted in terms of the following items: the structure of coal consumption in energy supply, structure of coal consumption, mainly of domestic brown coal consumption, the situation of coal utilization by industry and by region, environmental problems caused by coal utilization such as air pollution, the trend of policies of environmental regulation, etc. The literature on the following was obtained and surveyed: the situation of economy/energy in Pakistan, coal utilization technology by industrial field, and environmental protection technology. The hearing survey was made to institutions concerned, corporation groups and men of learning and experience. Site surveys were conducted for the typically selected coal utilization equipment and existing environmental protection equipment. 66 figs., 56 tabs.

  9. Interim report on the research development of high combustion technology using the microgravity environment; Bisho juryoku kankyo wo riyoshita kodo nensho gijutsu soshutsu ni kansuru kenkyu kaihatsu chukan hokokusho

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1997-03-01

    There are problems on diversification of energy from a viewpoint of energy stabilized supply and reduction of environmental pollutant in fuel exhaust gas. For the solution, combustion phenomena are elucidated using microgravity equipment, and a combustor which enables high combustion technology is studied. For it, a field survey is conducted on implementation of international joint research with the U.S.` NASA, and at the same time experiments and analyses of the experimental data are carried out using microgravity experimental equipment. For experiments using microgravity experimental equipment and analysis/evaluation of experimental data, the following were conducted: (1) evaluation of combustion properties of various fuels, (2) fabrication of equipment needed for experiments for analysis/evaluation of combustion parameters, and combustion/evaporation evaluation experiments of fuel droplet/droplet group using microgravity experimental equipment, evaluation experiment to elucidate combustion property of solid particle mixed fuel, evaluation experiment of combustion limit, etc. In fiscal 1993, experimental data are being acquired for establishing a target experimental method. 42 refs., 151 figs., 1 tab.

  10. Fiscal 1998 research report on the basic research on the practical application of innovative technologies. 2; 1998 nendo kakushinteki energy gijutsu no jitsuyoka ni kansuru kiso chosa hokokusho. 2

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1999-03-01

    This report is composed of the part 1 'Estimation of fossil energy resources and preliminary preparation of the super- long-term view of energy supply and demand', and the part 2 'Research on concrete conditions for introducing renewable energy (RES)'. In the part 1, estimation was made on the amount of non-conventional fossil energy resources such as oil sand, oil shale, coal bed methane and methane hydrate. Study was also made on the role of nuclear power, fast breeder reactor and nuclear fusion in the world energy supply and demand in the 21st century. In addition, as preliminary study on the super-long-term view of energy supply and demand in the next fiscal year, study was made on a scenario and measuring model considering energy supply restriction and CO{sub 2} problem. In the part 2, research was made on the amount of resources, applicable fields and cost estimation for various RESs such as solar energy, wind power, biomass, oceanic energy, geothermal energy and hydraulic power. Several technical issues on transport, storage, conversion and use for every energy were arranged toward real introduction, efficient use and stable supply of such RESs. (NEDO)

  11. Achievement report for fiscal 1997 on investigative research on society compatibility of development of coal hydrogasification technology; 1997 nendo sekitan suiso tenka gas ka gijutsu kaihatsu shakai tekigosei ni kansuru chosa kenkyu seika hokokusho

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1998-03-01

    In view of possibility of the future tightness in natural gas supply, establishment of coal gasification technology was set as the final objective, which can supply cheaply and stably the substitution natural gas of high quality by using coal existing affluently over the world as the raw material. An investigative research is carried out under a five-year plan on society compatibility required to assess the possibility of the practical application thereof. Fiscal 1997 has performed in continuation from the previous year the 'survey on process level elevation' and 'survey on the society compatibility'. This report summarizes the achievements thereon. In the investigative research on the process level elevation, the Shell's methane synthesis process based on an oxygen blown and dry feed coal gasifier was evaluated, and the calculation process was pursued on material balance in a hydrogasification reactor as having been performed in the 'survey on developing the coal hydrogasification technology' in which its reasonability was verified. In the survey on the society compatibility of the process, a survey was carried out on natural gas (including non-conventional methane hydrate and coal bed methane) and coals as raw materials for hydrogasification. (NEDO)

  12. Fiscal 2000 technical trend survey report on the surveys of technical trends regarding development of microminiature high-density power source technology; 2000 nendo chokogata komitsudo power gen gijutsu no kaihatsu ni kansuru gijutsu doko chosa hokokusho

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    2001-03-01

    Surveys are conducted of technical trends of, and needs for, versatile microminiature high-density power sources, and research and development projects are proposed for micro fuel cells, combustion type micro power generation, environmental micro power generation, and micro rockets. Assumed in the research and development of micro fuel cells are a direct methanol method, chemical hydride method, micro combustion reformer method, and a hydrogen method using advanced hydrogen absorbing materials. Assumed in the research and development of combustion type micro power generators are a micro engine power generator (gas turbine power generation, steam cycle power generation), thermophotovoltaic micro power generator, catalyst-aided combustion thermophotovoltaic micro power generator, and so forth. Assumed in the research and development of environmental micro power generators are an environmental micro vibration power generator, environmental micro thermal power generator, environmental electromagnetic power generator, non-contact power feeding system, and so forth. Assumed in the research and development of micro rockets are a solid micro rocket array, micro PPT (pulsed plasma thruster), card type electric propulsion system, and so forth. (NEDO)

  13. Report on survey of international cooperation possibility on chemical CO2 fixation and utilization technology in FY 1997; 1997 nendo chosa hokokusho (kagakuteki CO2 koteika yuko riyo gijutsu ni kakawaru kokusai kyoryoku kanosei chosa)

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1998-03-01

    This survey focused on the end of the more promising companion and promoting the international cooperation on chemical CO2 fixation and utilization technology. As a result, the way of the carrying-forward of the international cooperation with more than one companion could be arranged beforehand. It led to getting an arrangement about a secrecy agreement respectively with Lurgi company and ABB company in Europe, and to providing a catalyst sample developed by RITE to implement an examination by the other party and to show related technical information. In addition, it concluded a cooperation agreement about a total system of the chemical CO2 fixation and utilization technology and methanol synthesis with ZSW. In Australia, negotiation about international cooperation with CSIRO which is a federal research organization and CRC (Cooperative Research Centre) for renewable energy has been started. The ideal circumstances are being ready for the chemical CO2 fixation project for which the international cooperation with the country where the natural energy is rich like Australia is essential when coming to practical use. To do alternating current with further high density in the following year it is desired to build a concrete study cooperation system. 1 fig., 4 tabs.

  14. Fiscal 1999 basic survey report for promotion of joint implementation. Survey of diffusion of fluidized bed cement kilns in Vietnam; 1999 nendo Vietnam koku ni okeru ryudosho cement kiln fukyu chosa hokokusho

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    2000-03-01

    Possibility is assessed of energy saving and CO2 reduction through replacing shaft kilns with fluidized bed kilns at four cement plants in Vietnam. The effort will be associated with the clean development mechanism (CDM) ultimately. The fluidized bed kiln is one of the state-of-the-art technologies developed to meet social, economic, and technical demands involving global environments, enhancement of energy efficiency, effective use of resources, improvement in cost performance, increasingly diversified needs for cement, etc. Use of the technology will lead to an extensive reduction in greenhouse gas emissions, solution of the problem of dust flying from calcinating facilities, production of clinkers high in stability and quality, utilization of inexpensive fuels such as low-grade coal, and production cost reduced thanks to the new equipment occupying less installation space. The conclusion of the study is that the energy to be consumed by the four plants will decrease by 6101-9551 tons/year in terms of oil and that energy saving rate will be 37-44%. The decrease in fuel and electricity for calcinating furnaces in turn decreases CO2 emissions, with the amount of reduction estimated at 24,393-38,794 tons/year in terms of CO2 and the rate of reduction estimated at 36-44%. As for payout in case environmental special yen credit is granted, it will realize in the 10-12th year, which means such financing will achieve a sufficient investment effect. Effect is also tentatively calculated in case of fluidized bed kilns diffused across the country. (NEDO)

  15. Fiscal 1975 Sunshine Project research report. R and D on hydrogen production technology by high-temperature high- pressure water electrolysis; 1975 nendo koon koatsusui denkaiho ni yoru suiso seizo gijutsu no kenkyu kaihatsu seika hokokusho

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1976-05-29

    This report details the research result in fiscal 1975. Part 1 'Outlines' includes the research target, the summary of fiscal 1974 research results, the summary of fiscal 1975 research results, and responsible researchers. Part 2 'Details of the research' includes the fiscal 1975 research results. Chapter 1 reports 'Study on constant-load high- temperature high-pressure (multi-electrode type) diaphragm water electrolysis tank' promoted by Mitsubishi Kakoki Kaisha. Chapter 2 reports 'Study on Teflon system diaphragm for high-temperature high-pressure water electrolysis tanks' promoted by Yuasa Battery Co. through Mitsubishi Kakoki Kaisha. Chapter 3 reports 'Study on variable-load high- temperature high-pressure diaphragm water electrolysis tank' promoted by Showa Denko K.K. Chapter 4 reports 'The first detailed design of the electrolysis tank for a small test plant' promoted by Hitachi Zosen Corp. through Showa Denko K.K. Chapter 5 reports 'Research on the applicability of water electrolysis systems to various fields' promoted by Mitsubishi Research Institute, Inc. through Showa Denko K.K. (NEDO)

  16. Basic research on energy conservation in developing countries. Report of the International Conference on Adaptation and Mitigation Technologies for Climate Change; Hatten tojokoku energy shohi koritsuka kiso chosanado jigyo. Kiko hendo ni kansuru tekio kanwa gijutsu kokusai kaigi hokokusho

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1996-03-01

    The International Conference on Adaptation and Mitigation Technologies for Climate Change was held based on the 1st Conference of the Parties in 1995 of the United Nations Framework Convention on Climate Change, and the 2nd evaluation report of the Intergovernmental Panel on Climate Change (IPCC). This report carries the outline of this conference and minutes. Japanese government had studied the framework of activities implemented jointly (AIJ) for emission control of greenhouse gases by voluntary workers jointly with developing countries. The government decided the basis of the AIJ Japan program in 1995, and approved the evaluation guidelines of this program including confirmed and considered matters which are necessary for government offices related to this program to evaluate and approve each project. IPCC approved the 2nd evaluation report in its general meeting in 1995. This conference was thus held to discuss strategic technology and international cooperation with participation of writers of the 2nd IPCC report, policy planners of Asian countries, Japanese industries, governmental offices and NGO.

  17. FY 1997 report on the research for construction of NEDO`s vision. Regional environment and international collaboration; 1997 nendo chosa hokokusho (NEDO vision sakutei ni muketa chosa kenkyu). Chiiki kankyo to kokusai kyoryoku

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1998-03-01

    It is necessary for NEDO to transfer the energy technology to developing countries and conduct collaborations with them efficiently. First of all, environments of the community were analyzed from a viewpoint of natural environment, social and cultural environment, and industrial and economic environment. Then, this report outlines the organizations of domestic and international aid agencies which have potentials to conduct alliance and collaboration with NEDO, and also illustrates their activities including financing and technology exchange, regional activities, and progress of activities. Alliances and collaborations with NGOs of each international organization were analyzed on the aspect of the fields and know-how of alliance with NGOs, selection standards of NGOs and necessary systems and organizations to make effective alliance and collaboration with NGOs, and some case studies were taken. Organization, purposes and activities of NGOs in Asian countries are introduced, and their current situations are illustrated. Finally, some proposals were offered to make alliances and collaborations with aid agencies and NGOs. They are concerned about the fields and know-how of alliance with NGOs, selection standards of NGOs and necessary systems and organizations to make effective alliance and collaboration with NGOs. 44 figs., 8 tabs.

  18. FY1998 Report of surveys on network possibility involved with proliferation and transfer of environmental technologies (Europe, Australia and New Zealand); 1998 nendo kankyo gijutsu no fukyu iten ni kakawaru network kanosei chosa hokokusho . Oshu Goshu New Zealand

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1999-03-01

    At the third Conference of the Parties to the United Nations Framework Convention for Climate Change (COP3) held in December 1997, the industrialized nations have agreed on development and proliferation of innovative technologies under international cooperation and transfer of environmental technologies to developing countries by expanding and strengthening CTI being the framework to be progressed spontaneously. Under the international strategic research project for global environment, NEDO has been promoting positively the research and development, whose support is urged to be expanded further in the future upon receiving the present agreement. Therefore, NEDO has performed the present survey in order to propose frameworks and measures for strengthening and expanding CTI. From among the policies and measures to be taken by the related countries based on the COP3 protocol, fiscal 1997 has performed review and new establishment of plans involved with execution of the items related to technology development, and surveys on action movements such as review and expansion of the measures, as the first stage. Fiscal 1998 has executed surveys focusing on the network for technology proliferation and transfer to developing countries as the second stage. (NEDO)

  19. Introduction of report of the investigation into deflagration and fire accident (1992) at a British Corporation, Hickson and Welch Co. Ltd.; Eikoku HICKSON and WELCH sha no bakunen kasai jiko (1992 nen) ni kansuru chosa hokokusho no shokai

    Energy Technology Data Exchange (ETDEWEB)

    Sato, K. [The High Pressure Gas Safefy Institute of Japan, Tokyo (Japan)

    1995-09-01

    A deflagration and fire accident broke out at Hickson and Welch Co., Ltd., Castleford, West Yorkshire, England at two p.m. September 21, 1992, and five persons were killed, 14 persons were injured, and the factory facilities were also seriously damaged. This article summarizes the accident based on the final report recently issued by the Health and Safety Executive (HSE) of Britain. This accident broke out during operation for removing sludge accumulating in a still for separating and purifying process positioned on the downstream side of a nitrotoluene production plant in the Hickson Co., Ltd.`s factory. Ignoring manager`s individual responsibility, the HSE used the company for its general management mistake. In regard to this, the court judged that Hickson Co., Ltd. must pay a penalty of 250 thousand pounds for violating general duty items for protection of the health and safety of the employees and also pay for the investigating costs of 150 thousand pounds incurred by the HSE. 2 refs., 2 figs.

  20. Fiscal 1997 report on a feasibility survey of cooperation in relation to the joint implementation activities in Southeast Asian countries (6 nations); 1997 nendo chosa hokokusho (Tonan Asia chiikikoku (rokkakoku) ni okeru kyodo jisshi katsudo kanren no kyoryoku kanosei chosa)

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1998-03-01

    In the COP3 Conference on Global Warming held in Kyoto in December 1997, the framework on greenhouse gases was agreed in discussions comprehensively made among Japan, the U.S. and the E.U. As a result, it is for 6 gases including CO2 and methane, and total emissions in developed countries are to be reduced 5% at least during 2008-2012 from the 1990 level. Target of each country is determined by gaps, and Japan`s reduction target is 6%. Therefore, to pass the numerical target agreed, it is necessary to take measures such as rationalization of the energy use by energy saving, etc. in the country and also measures such as promotion of the greenhouse gas emission control in developing countries. Accordingly, for the future development of NEDO`s AIJ project, a possibility of cooperation in the joint implementation was surveyed such as the state of greenhouse gas emissions of countries which are objects of GAP in Southeast Asian countries and neighboring countries, policies of the countries after the COP3 agreement, technological transfer for the emission control, etc. Countries for survey are Thailand, Indonesia, the Philippines, Malaysia, Vietnam and Myanmar. 21 figs., 15 tabs.

  1. Fiscal 1997 research report on the survey on public test and evaluation organizations for development of welfare equipment; 1997 nendo fukushi kiki kaihatsu ni kakawaru koteki shiken hyoka kikan chosa hokokusho

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1998-03-01

    This research studies the construction policy of public test and evaluation systems for future development and practical use of welfare equipment, through survey on the current methods for development, practical test and evaluation of welfare equipment in countries advanced in welfare, and preparation of basic data for promoting establishment of public test and evaluation functions in Japan. Infrastructure preparation for standards and public test and evaluation organizations for developing welfare equipment is being promoted by Technical Laboratory of Bicycle Industry Promotion Association and some national organizations such as Product Evaluation Technical Center, Mechanical Engineering Laboratory, National Institute of Bioscience and Human Technology, and Living and JIS Center. However, preparation of objective and across test and evaluation systems for developing welfare equipment is still insufficient. Product Evaluation Technical Center is now approaching to evaluation and standardization of welfare equipment. Public test and evaluation organizations of the UK, Sweden and Denmark are presented. (NEDO)

  2. Fiscal 2000 research report on the energy consumption survey for popularizing stationary fuel cell systems; 2000 nendo teichiyo nenryo denchi no fukyu wo mokutekito shita energy no shohi ni kansuru chosa hokokusho

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    2001-03-01

    A survey was conducted about the current state of domestic energy consumption for studying the feasibility of a stationary energy system using the polymer electrolyte fuel cell. A study relative to domestic energy consumption dealt with transition in the energy consumption rate, dependence on locality, and the effect of the makeup of residences. The monthly and hourly patterns of demand for heat for hot-water supply were referred to power consumption data broken down by time zone, and it was found that approximately 1kW output would be suitable for this purpose. A study was made about the pattern of operation that such a fuel cell system should follow, and it was learned that a pattern in which 'the system operates according to the imposed load starting at seven o'clock in the morning when the electricity rate switches to the higher and the output does not exceed what is necessary to meet the daily demand for heat.' This method was found to assure the most efficient way of operation covering more than 80% of the need for hot water and electricity. In a study of consumption of energy for business, feasibility was suggested to exist in the installation of systems of 30kW or less at small hotels, barber shops and beauty parlors, restaurants, schools equipped with minor-scale food service, small hospitals, clinics, and the like. (NEDO)

  3. Fiscal 1997 report on the survey project on planning to execute `The New Earth 21`; 1997 nendo chosa hokokusho (`chikyu saisei keikaku` no jisshi keikaku sakusei ni kansuru chosa jigyo)

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1998-03-01

    Japan proposed in the Houston Summit the New Earth 21 to be carried out with technology development and technology transfer, and to make a concrete development of the project, Japan also proposed in the Tokyo Summit a TREE Plan for working out comprehensive strategies of the innovative technology development. In the CO3 Kyoto Conference in 1997, numerical targets for developed countries were determined which have legal binding force for control/reduction of greenhouse gas emissions in the term of 2008-2012. It was agreed to urge developing countries also to play a certain part in the project through the clean development. Therefore, the paper made quantitative analysis of important CO2 prevention technologies, technology transfer costs, and economical assessment by energy conservation. As a model, the DNE 21 model was upgraded and used into which CO2 prevention technologies, energy, economy and climate changes were integrated. In fiscal 1997, the following were carried out: collection of data on important CO2 prevention technologies and systems and analytical assessment using the DNE 21 model, CO2 reduction and selection of energy technology, assessment of energy system costs, construction of the unified DNE 21 model, and opening of the international workshop. 62 refs., 98 figs., 34 tabs.

  4. Fiscal 1997 international cooperation project. Report on the results of the research on environmental harmony type combustion technology; 1997 nendo kokusai kenkyu kyoryoku jigyo. Kankyo chowagata nensho gijutsu ni kansuru kenkyu kaihatsu seika hokokusho

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1998-03-01

    Out of the R and D on the environmental harmony type combustion technology, the results of the project carried out in fiscal 1997 were summed up. In the site survey, etc., visits were paid to France, Spain, Greek, Germany, the U.K. and the U.S. to have discussions and examine the trend of research on the NOx removal catalyst and catalyst combustion. In the actual R and D, the R and D were conducted on zeolite base NOx removal catalyst, oxide composite base NOx removal catalyst, alumina base NOx removal catalyst, direct decomposition type NOx removal catalyst, catalyst combustion, etc. In the R and D of the catalyst combustion, durability under high gas flow flux was examined of PdO-Pt/Ba-Al203 catalyst developed for low temperature use, which indicated that durability and low temperature activity were heightened. As high temperature use catalyst, high temperature durability was examined of the developed Pd0-La/Gd-ZrO2 catalyst, which showed that the durability was favorable. 322 refs., 261 figs., 55 tabs.

  5. Fiscal 1996 report on the investigational research on the construction of a database of physical functions; 1996 nendo chosa hokokusho (shintai kino database no kochiku ni kansuru chosa kenkyu)

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1997-03-01

    For the purpose of realizing `the affluence` sought in the Japanese economic society, the supply and preparation of products, service and environments friendly to human beings seem to be important. In the future, the development of products which are fully considered also of aged and handicapped people is more expected than the conventional manufacturing of products added with value. Especially in accordance with the rapid aging, from a viewpoint that the lowering of physical functions caused by aging has an exactly close relation with the response to products and the environment, development of the database of physical functions for the aged which is useful for the design is urgently promoted. First, the data to be supplied for database were selected. As to the selection method, the data required for database were defined by collection/analysis of the existing data, examination of the needs of enterprise designers, and analysis of daily activities. In the study of the database, the structure by which data can be effectively supplied was studied and verified by pilot database for extraction of the subjects and solution to the problems. 6 refs., 57 figs., 26 tabs.

  6. Fiscal 1996 survey report. Data collection and evaluation analysis in the project on field tests on the fuel cell generation; 1996 nendo kenkyu hokokusho. Nenryo denchi hatsuden field test jigyo ni okeru data shuyaku oyobi hyoka kaiseki

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1997-03-01

    The paper installed fuel cell power generation equipment experimentally at various facilities which are the final diffusion form of the new energy power generation, conducted long-term operation under the actual load, collected/analyzed various data, arranged them as data useful for full scale introduction/diffusion, aiming at forming the base for general diffusion of the fuel cell power generation. The number of the systems installed for field test execution has been 24 places/28 units since the start of the project, and the system capacity totaled 4,250kW. The actual operation hours in five years are 6,000-28,000. In fiscal 1996, the average cumulative accumulated operational rate was approximately 68%, a little over that in fiscal 1995, 65%. The average load factor was 69% in fiscal 1995 and 70% in fiscal 1996. The utilization rate increased as a whole to about 57% on average if seeing only fiscal 1996, as compared with that in fiscal 1995, about 48%. The power generating efficiency was approximately 34% on average. As to the status of shutdown of the fuel cell power generation, the paper surveyed the average interval of failure, the rate of frequency of shutdown, the analysis of shutdown, etc. 250 figs., 29 tabs.

  7. Research cooperation project on the development of easy injection molding control technology for engineering plastics; Engineering plastic no seikei joken kan`i settei gijutsu ni kansuru kenkyu kyoryoku jigyo seika hokokusho

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1997-03-01

    In order to enhance the industries which supply assembly parts to Japan`s assembly industries in Thailand, research cooperation project on the plastic parts production technology has started. For the research cooperation, the mold design is effectively conducted using simulation technique of CAE (computer aided engineering), and an international easy injection molding control system is made using the molding support software for injection molding machines. In FY 1996, actual situations of plastic parts and assembly industries in Thailand have been investigated through the cooperation with the counterpart of Thailand. Demand and supply of engineering plastics, receive and inspection of parts, and current circumstances of molding processing makers in Thailand have been grasped. Based on the results of this investigation, proposal of basic plan, time schedule, and delivery plan of molding machines and testing equipment have been discussed, to make the basic plan. 18 refs., 4 figs., 23 tabs.

  8. Research report for fiscal 1998. Basic research for promoting joint implementation (rehabilitation of 300MW coal-fired thermoelectric power plants in China); 1998 nendo chosa hokokusho. Chugoku ni okeru 300MW sekitan karyoku hatsudensho rihabiri

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1999-03-01

    Studies are made on the feasibility of the above project which aims at energy efficiency improvement and CO2 reduction at thermoelectric power plants. Opinions and comments are collected by hearing, and on-site surveys are conducted at Shandong Province Zouxian Power Plant, Anhui Province Luohe Power Plant, and Henan Province Yaomeng Power Plant. The conclusion reached is outlined below. In view of the current and future demand for electricity in China and of the network to be constructed, it is believed that the rehabilitation is a pressing task for improvement on efficiency and reliability at 300MW coal-fired power plants. As for air pollution, NOx and dust in addition to greenhouse gas will be reduced under the project. There will be 3-4% improvement in boiler efficiency and approximately 4% improvement in turbine efficiency, and, in this connection, there will be CO2 emission reduction of 140,400-154,900 tons/year per unit in case of 300MW coal-fired power plants. As for cost efficiency, it is inferred that investment will achieve an adequate result, with the number of years required for investment retrieval taken into consideration. (NEDO)

  9. Evaluation report on research and development of an ultra-advanced processing system. Sections 1 and 2; Chosentan kako system no kenkyu kaihatsu ni kansuru hyoka hokokusho. 1 and 2

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1994-08-01

    The ultra-advanced processing system is intended to develop an ultra-advanced processing device technology and an ultra-advanced processing technology. These technologies are indispensable to create such new processing technologies as ultra-precision and ultra-micro processing, and ultra high-grade surface modification processing, which have been impossible by the processing technologies having been available to date. It is also intended to develop a measuring and evaluating technology to support the above technologies. The intended system makes it possible to produce 21st century electronic components and ultra-high grade environment resistant materials. In order to achieve these goals, research and development has been performed on the excited beam technologies such as large output excimer laser and high-density ion beams, the ultra-precision machining device technology, the ultra-advanced processing technology using the above technologies, and the measuring and evaluating technology to assure the reliability of these technologies as the fundamental technologies. This project has begun in fiscal 1986, where fiscal 1987 has achieved development of component technologies related to the large output excimer laser and high-density ion beams, the ultra-precision machining device technology, the ultra-advanced processing technology using the above technologies, and the measuring and evaluating technology, and completed the device technology, having achieved the final target. (NEDO)

  10. Report on achievements in fiscal 1998. Demonstrative research of an alkali recovery process in the non-wood pulp paper manufacturing industry; 1998 nendo himokuzai pulp seishi sangyo arukari kaishu process ni kakawaru jissho kenkyu seika hokokusho

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1999-09-01

    This project is intended of performing demonstrative research jointly with China on a system to efficiently extract, condense, and combust black liquor in a non-wood pulp paper manufacturing plant in China to recover alkaline solution and heat energy, and to contribute to proliferation of the system. Specifically, an alkali recovery plant is built in Cangshan Paper Making Plant in Shandong Province to verify conservation in energy and reduction environmental load. This fiscal year has performed (1) component researches and related technology investigations, and (2) device design and fabrication. For Item 1, the extractor adopted the spiral net type, and the condensation device adopted the falling film evaporator of full-can plate type. For the silica removing agent, data were acquired on reduction of silica in the black liquor and effect of reducing the black liquor viscosity. Basic design requirements were established for an alkali recovery process for a pulp production plant of 75 t/d. Regarding Item 2, prepared were the material and heat balance tables for the black liquor extractor and the black liquor condenser, process flow diagrams (PFD), device specifications, a meter list, and a summary utility consumption list, and confirmed them with the Chinese side. For the black liquor combustion device and the caustification device, PFD and device list prepared by the Chinese side were acquired to start the basic design. (NEDO)

  11. International research cooperation in fiscal 1997. Report on the development of novel magnesium alloy-base ultralight materials; 1997 nendo kokusai kenkyu kyoryoku jigyo. Magnesium gokin ni yoru chokeiryo shinzairyo no kaihatsu seika hokokusho

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1998-03-01

    Research and development are conducted for the improvement of magnesium alloy characteristics and for the realization of energy and cost saving in the manufacturing process of the said alloys. Concerning manufacturing techniques for high-performance magnesium materials which are among the existing alloys, researches are conducted about the development of superplastic magnesium alloys, development of heat-resistant magnesium alloys, pulverizing techniques and the experimental construction of equipment therefor, safety of magnesium powder, high-precision strain control, processing for enhanced strength and superplasticity, and heat treatment and surface treatment technologies. In the efforts for developing technologies for manufacturing ultrahigh-performance magnesium materials which are novel alloys, researches are conducted concerning the manufacture of amorphous magnesium alloys and methods for evaluating the characteristics thereof, manufacture of amorphous magnesium alloys by a liquid-aided rapid cooling method and the characteristics of the products, and methods for forming the alloys into wires. The developed magnesium materials are tested for strength, resistance to corrosion, etc., and environmental impacts and friendliness toward environments that will eventually affect the life cycle of the new materials are discussed. 45 refs., 91 figs., 21 tabs.

  12. Fiscal 1995 international research cooperation project. Report on the R and D result of the environmental harmony type combustion technology; 1995 nendo kokusai kenkyu kyoryoku jigyo. Kankyo chowagata nensho gijutsu ni kansuru kenkyu kaihatsu seika hokokusho

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1996-03-01

    The research and development were conducted jointly with Europe of an environmental harmony type high efficient catalyst which enables clean combustion and NOx removal in polluted gas in combustion flue gas, etc. In the research and development of NOx removal catalyst such as zeolite base, reformation of mostly mordenite was done by ion exchange, ion implantation, skeleton element substitution, etc. A possibility was found out of applying the membrane formation method except ion implantation as reforming means. In the R and D of the complex oxide base NOx removal catalyst, it was found that the catalyst carrying copper and silver on silica and layer clay compound under optimum conditions shows peculiarly high activity, and there is little decrease in the activity, but rather increase in it even under vapor existence. An evaluation was made of NO resolution of direct resolution element carrying noble metal electrolyte on solid electrolyte, finding out that the highest NO selectivity is shown with Pd as electrolyte and at a baking temperature of about 1300degC. Development of high- and low-temperature catalysts was also made. 417 refs., 286 figs., 63 tabs.

  13. FY1998 report on the survey on total energy and material control. Pt. 2. Survey on feasibility to structure a circulation type society; 1998 nendo total energy and material control ni kansuru chosa hokokusho. 2. Junkangata shakai kochiku kanosei chosa

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1999-03-01

    This paper describes a survey on feasibility to structure a circulation type society. The TEMCOS is a technology to contribute to structuring a circulation type society by controlling energy and materials totally. In order for the technology to develop into one that fuses with districts, survey and research were made on specific possibility of inter-process linking. Particularly discussions were given on zero emission of wastes (by-products) by means of inter-process linking of the metal industries with the chemical and petroleum industries. Therefore, the actual status of by-products was investigated and narrowed down, utilization possibilities were proposed, and the future possibilities and development themes were put into order. In order to structure a sustainable circulation type society, it is indispensable to perform step-wise cascade utilization considering quality of the energy, not only recycling energies and resources. Focusing on recovery of waste heat of low-middle temperatures which is difficult to recover latent heat, plans were established on research themes. The plans include chemical utilization of low-middle temperature heat utilizing ammonia gas, storage of heat in cryogenic temperature waste gas to iron particles, and transfer and utilization thereof. (NEDO)

  14. Report on the investigative study for enregy-saving measure in hydraulic/pneumatic system in 1990 fiscal year; 1990 nendo yukuatsu system ni okeru sho energy taisaku no chosa kenkyu hokokusho

    Energy Technology Data Exchange (ETDEWEB)

    1991-05-01

    In hydraulic systems, material problems were investigated in addition to the problem of providing microelectronic instruments and that of working fluids. In pneumatic systems, air leakage and sealing were investigated in response to the resource-saving problem and high-pressurization for miniaturization of systems. The demonstration tests of hydraulic/pneumatic cylinders showed that the piston rod surface-treated by 20um hard chromium plating is more stable than that treated by other methods. There, however, remains the possibility of using SQP even now in hydraulic cylinders in which lubrication is assured. Stabilization of hardness and finishing precision in the SQP treatment of pneumatic cylinders must still be investigated. Concerning the quality of packings for hydraulic systems which use lubricating oil, urethane and other materials are not much different from each other in oil-resistant and wear-resistant properties. Superiority of urethane and XNBR was not apparently shown for non-lubricative pneumatic use. Totalized cost estimation in relation to durability must be regarded as important over the whole field of material, processing, transportation and use. 36 figs., 29 tabs.

  15. Evaluation report on research and development of 'seawater purification and byproduct utilization'; 'Kaisui Tansuika to fukusanbutsu riyo' no kenkyu kaihatsu ni kansuru hyoka hokokusho

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1978-03-01

    Research, development, and evaluation were made on seawater purification for the purpose of supplying inexpensive city water stably in the future. In the research of the high flow rate long-tube type multi-stage flash process, basic characteristics were identified by studying fluidity, heat transfer, deaeration, and decarburization by using a test plant with a capacity of 3,000 m{sup 3}/d. A number of findings were derived in carrying out demonstration studies by using a test module with a capacity of 100,000 m{sup 3}/d. Research on heat transfer pipe materials covered a wide area including copper alloys, titanium and aluminum alloys, and ferrous materials, where a prospect was obtained on materials which may be practically usable in the future as transfer pipes in large seawater purifying equipment. Research on a concrete evaporator body proved that it is more economical than steel evaporators, and has sufficient corrosion resistance even against high-temperature brine. Other activities included researches on effects of contaminated seawater, brine diffusion, byproduct utilization, and total systems. Social and economic evaluations were also performed. (NEDO)

  16. Research report for fiscal 1998 on the analysis of spread effect of technologies approved as international standards. Value web analysis and research; 1998 nendo kokusai hyojun ni ninteisareta gijutsu no hakyu koka bunseki chosa hokokusho. Value wave bunseki chosa

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1999-03-01

    For contributing to the formulation of technology development programs, an analysis is conducted based on the concept of value web into which the economic spread effect is incorporated. As information technology plays an important role in the fields of automobiles and chemical materials, there are various fields the research and development efforts exerted in which are common to many others. As to what additional values are created when such separately developed technologies cross each other, a discussion is conducted using techniques of industry-oriented analyses. Findings obtained are mentioned below. When the numbers of essays relative to the respective industries are compared, it is found that 63% of the total number of biotechnological essays fall on agriculture, the drug industry, and the food industry. On the other hand, when it comes to the produce, related industries larger in marketing scale is more strongly influenced by the spread effect. The spread effect of biotechnology is distinguished in the drug industry, and that of information/communication technology in the information industry, electric and electronic industries, and in the semiconductor industry. (NEDO)

  17. Achievement report for fiscal 2000 on the fundamental research on functional sectional imaging system using optical interference; 2000 nendo hikari kansho riyo kokino danso gazo sokutei sytsem ni kansuru kiban kenkyu seika hokokusho

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    2001-05-16

    This project promotes the fundamental research on the conventional OCT technology to make it applicable to wider clinical applications of diagnoses and therapies by greatly improving the technology in view of higher spatial resolution, smaller size, and functional diversification. The research is supported by the medical and engineering cooperative research that utilizes the medical and engineering knowledge. Furthermore, as the fundamental technologies for the next generation, the sectional image measuring technology is established that makes possible to measure the three-dimensional flow and movement such as blood flow distribution in very small blood vessels, and performs the basic research on high-speed sectional image measurement to measure moving images of sectional images. The research contents for the current fiscal year may be summarized as follows: in the research on a small integrated optical element to make diagnostic application possible for skin cancers, retinal detachment, and cataract, research on trial production of a small OCT has been performed, and research on high spatial resolution has been implemented; furthermore, research was carried out on an endoscope integrated type OCT system intended of textural diagnoses of gastric cancer, hemorrhoidal cancer, and colic cancer, and on a sectional image measuring system intended of extracting biochemical information, and on a high-precision absorptive spectrum measuring technology for biogenic structures. (NEDO)

  18. FY 1998 annual report on the survey on development, introduction and promotion of urban type multipurpose geothermal utilization techniques; 1998 nendo toshigata tamokuteki chinetsu riyo gijutsu no kaihatsu, donyu, sokushin ni kansuru chosa hokokusho

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1999-03-01

    Introduction of geothermal heat pump systems, which depend on temperature differential, is investigated for urban areas, which have large energy demands. Results of the surveys on the current situations of geothermal heat pump (GHP) systems indicate that they have already numbered 300,000 units in USA and totaled more than 50,000 units in Switzerland and Northern European countries, and that they are increasing at an annual rate of higher than 10%. The results also indicate that introduction of these systems are well feasible in Japan, which generally has better topographical conditions than American and European countries, and the GHP system with vertical ground heat exchanger is investigated for its topographical and environmental considerations. These systems could annually abate approximately 52 million tons of CO2 (4.3% decrease), if disseminated to all households. They are also expected to help control the heat island phenomenon, and reduce peak power consumption. The technological problems to be solved before these systems are massively disseminated including development of small scale drilling rigs and preparation of drilling manuals. System standardization and introduction of subsidy systems are also needed to massively disseminate these systems. (NEDO)

  19. Report on the FY 1995 basic survey for industrialization related to the survey of overseas geological structure (Pondok Labu East area, Indonesia); 1995 nendo kaigai chishitsu kozo nado chosa ni kakawaru kigyoka kiso chosa (Indonesia Pondok Labu higashi chiku) hokokusho

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1996-03-01

    The survey was conducted based on 'Scope of work for detailed coal exploration in the Pondok Labu East area of East Kalimantan Province, Kalimantan, Indonesia' concluded on June 16, 1995 between NEDO and P.T. Tanito Harum which owns the mining right. The area for survey is approximately 10km west of Tenggarong city, the capital of Kabupaten Kutai, East Kalimantan Province which is northeast part of Kalimantan island of Indonesia. The field survey was divided into the geological/boring survey and the survey of conditions for underground mining development and the infrastructure. This survey made it clear that in the underground mining of PDL7A seam, assuming the minable coal reserve to be 6.81 million tons, it is possible to produce raw coal of 0.5 million tons/year by adopting the longwall pick mining. The raw coal is all prepared, and the yield is 80%. Accordingly, the production of product coal is 0.4 million tons/year. Attached were the boring log (JN9-94-0855), physical log (JN9940856), and BIP survey report (JN9940857). (NEDO)

  20. Fiscal 1997 report on the feasibility survey of Japan`s cooperation into energy/environment related fields in Asian countries; 1997 nendo chosa hokokusho (Asia shokoku ni okeru energy kankyo kanren bun`ya eno kyoryoku kanosei chosa)

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1998-03-01

    A survey was made to study possibilities of Japan`s cooperation in tackling energy/environment problems in Asian countries. In 1995 the GNP growth rate was 2.6% in the world, while it was 7.9% in Asia showing a rapid growth. With the accelerating industrialization and urbanization, energy demand is now over three times as much as that in the 1980s. This means increases in waste and environmental pollution. Especially, the use of firewood in non-electrified areas is a serious problem the same as the slash-and-burn farming and deforestation. Also relating to the production of electric power, it is inevitable to choose hydroelectric power and renewable energy in addition to fossil fuels. Therefore, the necessity is heightening of various technologies for it and environmental protection technologies such as coal cleaning. Local areas, where the population density is extremely low and the electrification cost is high, became victims of elecrification. There the power system should be shifted from the central supply system to the local distributed one. For it, it is necessary to recognize an importance of the distributed type renewable energy which is friendly to the environment. The paper outlined the state of each country and energy by policy and environment. 10 figs., 83 tabs.

  1. FY 2000 study report on the study on technological development of the chemical processes of the next generation; 2000 nendo jisedai kagaku process gijutsu kaihatsu ni kansuru chosa kenkyu hokokusho

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    2001-03-01

    The technological development of the innovative chemical reaction processes is studied, in order to accomplish further energy saving, and reduction of resource consumption and environmental loads. Described herein are the FY 2000 study results. The program for systematization of the next-generation chemical processes systematically pigeonholes the undergoing projects and subjects to be studied, based on the principles of simplification, and sets the study fields of organic bulk chemicals, organic fine chemicals, highpolymer materials and inorganic materials. The program for investigation on next-generation chemical processes reviews creation and technological use of tailor-made biocatalysts, polymer materials which utilize wood resources, tailor-made reaction process engineering for handling fine particles in high-temperature reaction fields, production and processing of materials for high-performance polymer batteries, and extreme energy saving process for polyolefins, and proposes the revisions. The newly proposed study themes include novel C1 catalytic processes toward minimal wastes, and high utilization of biotechnology for novel processes to create materials. (NEDO)

  2. Report on a wind power development field test project (detailed wind condition investigation) in the city of Choshi; Choshishi ni okeru furyoku kaihatsu field test jigyo (fukyo seisa) hokokusho

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1998-11-01

    This paper describes observation on the annual wind condition at the Yokka-ichibadai in the city of Choshi. The average wind velocities were 4.7 and 3.8 m/s at the ground height of 20 and 10 meters, respectively, not having reached the NEDO's criterion values 5.6 and 5.0 m/s. The annual wind direction emergence rate on the wind axis was 70%, meeting the criterion value of 60% or higher, and the wind direction is stable. The exponent for the vertical wind velocity distribution was 3.3, which is similar to that in the urban area. Disturbance in the wind condition was 0.18, meeting the criterion value of 0.30 or lower. The maximum momentary wind velocity was 31.9 m/s, which is well below the criterion of 60 m/s presenting no problem as a wind mill construction site. The wind energy density was 94 W/m{sup 2}, being only 63% of the criterion value, when all the azimuths were used as the object. The result of the investigation is that the average wind velocity is low and the wind energy density is also low. However, if the size of wind mill to be introduced is set to the class B (300 kW), it is possible to attain an annual operation rate of 58%, an annual energy acquisition amount of 515 MWh, and a facility utilization rate of 19.6%. If set to the class C (750 kW), an operation rate of 78%, an annual energy acquisition of 1296 MWh, and a facility utilization rate of 19.7% can be obtained, meeting the criterion value. (NEDO)

  3. Report on follow-up for joint research of valuable resources recovery techniques from brackish water; Kansuichu no yuka shigen kaishu gijutsu ni kansuru kenkyu kyoryoku follow up hokokusho

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1996-03-01

    This report describes follow-up for research and development on the recovery of valuable resources, such as magnesium, bromine and boron, contained in the brackish water for manufacture of common salt in the coastal region of Mexico. For the field survey, salt garden, irrigation plant and manufacturing plant of dinning salt were inspected. The optimum site was examined by assuming desalination plant and solar pond. The groundwater in coastal regions is progressively salified. Since the coastal region is a tourist resort with an round-trip area of whales, environmental protection is indispensable. For the joint research with invited researchers, the solar pond system and fresh water generation were studied. As a result, it was found that the solar pond system is an excellent method for keeping thermal energy in a low cost at the salt garden with abundant solar energy, and that the desalination system combined with distilling is the most suitable method. 7 refs., 8 figs., 1 tab.

  4. Research report for fiscal 1998. Research for 'New Earth 21' project implementation program preparation; 1998 nendo chosa hokokusho. 'Chikyu saisei keikaku' no jisshi keikaku sakusei ni kansuru chosa jigyo

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1999-03-01

    For the establishment of a CO2 measures introduction scenario which the world would accept, the latest information was collected, the DNE21 (Dynamic New Earth 21) model was improved, and simulation was reviewed. In fiscal 1998, simulation was performed for each district using an LDNE21 (Linear Dynamic New Earth 21) model, and an energy flow chart, energy balance table, and trade table were prepared and subjected to detailed deliberation. Studied were also conducted about the changes to occur in methanol production when the natural gas reserves and plant cost data were given different values. In the DNE21 model, the 'macro economy model' and 'warming damage function' were integrated, and simulation was performed for verification. Using a standard model compatible with COP3 (Third Session of the Conference of the Parties to the United Nations Framework Convention on Climate Change), comparison was made between a case in which different CO2 emission constraints were imposed on the advanced area and developing area separately and a case in which one and the same constraint was imposed on the world as a whole, and calculations were made about CDM (Clean Development Mechanism). (NEDO)

  5. Fiscal 2000 survey report. Research on bone-forming dental material capable of reducing plaque adhesion; 2000 nendo shiko fuchaku boshigata hone keisei shika zairyo ni kansuru chosa kenkyu hokokusho

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    2001-03-01

    Research and development efforts are exerted to produce advanced dental materials equipped with such functions as plaque reduction, bactericidal effect, and early formation of hydroxyapatite (HAP). In the study of fluorine ion implantation for plaque reduction, it is found that in a specimen implanted with fluorine ions the adhesion of carius streptococci is reduced to 1/3-1/10 for the achievement of remarkable improvement. In particular, carious streptococcus multiplication is suppressed when the metal shield layer is replaced with a titanium mesh. For the realization of a thin film formation method for osteoblast multiplication through reforming the material surface in the study of bone-forming dental materials, film formation conditions under which a P/Ca rate which is quite near that of ameloblast are achieved by use of a high frequency magnetron sputtering device. A titanium plate coated with a thus-formed film is annealed for a great increase in its wet contact angle, and then adhesion of bacteria is reduced and an osteoblast multiplication rate is increased by 20% or more, as compared with the case of no treatment in a petri dish. (NEDO)

  6. FY 1998 annual report on the improvement of toughness of silicide-based intermetallic compounds by controlling their composite structures; 1998 nendo fukugo soshikika ni yoru shirisaidokei kinzokukan kagobutsu no kyojinsei kaizen chosa hokokusho

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1999-03-01

    Intermetallic compounds, although attracting much attention as most promising materials serviceable at superhigh temperature, are very fragile at normal temperature, which is one of their major disadvantages. Structures of these compounds prepared by the melting method are controlled to improve their toughness by, e.g., changing phase ratio of the initial crystal for the Mo-Si-Nb system to prevent cracking during the melting and casting stages, addition of a third element (e.g., Zr, Ti or Hf) or a mixed component of Nb and Zr to control the structure of Mo{sub 5}Si{sub 3} considered to be a cause for the cracking, and controlling melting and solidification rates for the FZ melting method. The three-phase microstructures with added Hf or Zr show improved toughness, but need additional procedures for controlling solidification and cooling conditions. For the powder method, the MA conditions are investigated with a two-element system, and the effects of Al or Zr as the third element added to the base composition on the composite microstructures and constituent phases are also investigated. Unlike the melting method, the powder method causes no cracking problems during the stock preparation stage and hence is expected to be applicable to production of larger stocks. However, the products by this method are found to be insufficient both in toughness and high-temperature strength. It is necessary to develop methods for cutting down and controlling oxides in the grain boundaries, in order to prevent deterioration of their strength at high temperature. (NEDO)

  7. Fiscal 1997 report on the survey of biological CO2 fixation using arid land and oligotrophic waters; 1997 nendo chosa hokokusho (kansochi, hin`eiyo kaiiki wo riyoshita seibutsuteki CO2 kotei ni kansuru chosa)

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1998-03-01

    This survey is aimed to investigate various measures to be taken for biological CO2 fixation, to synthetically study feasibilities of the measures from various aspects of CO2 fixation mechanism, scale, speed, and environmental effects and technical problems in case of introducing those, and to assess the measures quantitatively. In this fiscal year, a study was proceeded with of possibilities of carbon fixation by afforestation and that by fertilization into ocean. The paper defined significance of afforestation in arid land, and especially advantages in conducting researches in West Australia. Relationships were examined among afforestation, precipitation and topography. The result of the survey was described of water- and salt-transfer simulation methods. Studies of arid land were made in terms of photosynthetic speed, transpiration speed, soil characteristics, measuring methods for precipitation and vaporization amount, and the examples. Seven places of Leonora where water source and water quality were examined were selected, and the measuring results were described. The paper summed up the state of utilization of biomass energy obtained from forest and commented on a scenario on tree-planting. Finally, a possibility was stated of the carbon fixation by fermentation into ocean. 178 refs., 121 figs., 53 tabs.

  8. Research report for fiscal 1998 on the basic research on the promotion of joint implementation and so forth. Coalbed methane collection and utilization project in China; 1998 nendo Chugoku ni okeru tanko methane gas kaishu riyo project chosa hokokusho

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1999-03-01

    China is surveyed for promotion of joint implementation, which is one of the flexibility measures in the Kyoto Protocol, the Third Session of the Conference of the Parties to the United Nations Framework Convention on Climate Change. The project aims to collect methane for global warming suppression and to use it as town gas and for power generation as well. The survey covers the 2 coalfields of Yangquan and Panjiang. The Yangquan coalfield is the largest anthracite yielding base in China, with 6 mines in operation. Power generation centering on a 100MW plant is discussed, and generation fired by a mixture of debris out of the coal preparation facility and gas is compared with another fired by town gas, on the assumption that 130-million m{sup 3} is available under the current circumstances. In the case of the Panjiang coalfield, which is expected to develop into a large coal base in the southern part of China, power generation centering on a 50MW plant fired by a mixture of debris and gas is discussed, on the assumption that 63-million m{sup 3} is collectable from the existing 5 mines. Use of town gas is also studied. When Japan's coalbed methane collection technology is applied, the gas drainage rate will be elevated to 40-35% or higher. It is desired that the use of gas drainage will be further diffused for the prevention of disasters of coal mine gas explosion. It is hoped that the use of environmentally friendly energies will be enhanced. (NEDO)

  9. FY 1997 report on the study on the formation condition of hetero-structure of single-crystalline semiconductor thin films; 1997 nendo chosa hokokusho (tankessho no handotai usumaku hetero kozo no keisei joken ni kansuru kenkyu)

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1998-03-01

    Since ion implantation causes material degradation by formation of crystalline defects, and hydrogen embrittlement deteriorates material strength, reduction of such defects has been positively studied. Study was made on a new active application of hydrogen separation into ion implantation defects. After H ion implantation of a proper depth into single-crystalline Si and SiC and successive annealing, single-crystalline films of sub-micron to several micron thick were obtained by hydrogen-induced delamination at the implantation depth due to hydrogen embrittlement in crystalline defects. The implantation depth is dependent on implantation energy. H atom forms (111) face defect through connection with dangling bond of crystalline defects. This crystal face defect forms a delamination plane through (100) face cleavage. This hydrogen embrittlement delamination by ion implantation is applicable to production of light-weight high-efficiency single-crystalline Si solar cells, and large single-crystalline SiC wafers as new resource saving process. 33 refs., 19 figs., 2 tabs.

  10. Fiscal 1998 research report. Study on the feasibility of microorganism biotechnology for effective use of environmental pollutants. Pt. 2; 1998 nendochosa hokokusho. Kankyo osen busshitsu no shigenka no tame no biseibutsu bio technology riyo kanosei ni kansuru chosa. 2

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1996-03-01

    Study was made on the feasibility of microorganism biotechnology for effective use of environmental pollutants and unused resources. Microorganisms and microorganism enzymes for decomposing lignocellulose were viewed, and uses of hydrolysis products were summarized. Production of microorganisms applicable to fodder, composting, and production of energy sources (methane, hydrogen, ethanol) were studied. Use of vegetable fiber residues such as beer lees as fungus cultivation medium and conversion to valuable substances were also studied. Microorganisms treatment (MT) of wastes in fats and oils industry was summarized. Effective use of MT of protein waste from marine products was studied. MT of manures with the greatest impact on environment as livestock waste was summarized. The necessity of separate collection of domestic wastes, and composting and methane fermentation of kitchen garbage were reported. The feasibility of MT of plastic wastes, and decomposition of halogenated methane with high toxicity were also studied. (NEDO)

  11. Fiscal 2000 report on investigation. Investigation of demonstrative test for harmonizing system interconnection (demonstrative test by simulation); 2000 nendo keito renkei enkatsuka jissho shiken chosa hokokusho. Simulation ni yoru jissho shiken

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    2001-03-01

    With the purpose of promoting the spread of dispersed power generating facilities, study was conducted on technical problems concerning system interconnection of dispersed generating facilities using a simulation, with fiscal 2000 results compiled. In the validity verification of an active type islanding detection equipment in a low voltage system interconnection, the simulations were made for the duration of ten seconds after the start of the islanding, with the detection time examined. In the case of the interconnection with a single unit, islanding was generally detected within ten seconds of the simulation time; in the case of the interconnection with multiple units, however, a trend was observed in which a frequency shift method was liable to receive interference from other methods. In the validity verification of the active type islanding detection equipment in a high voltage system interconnection, islanding was detected within ten seconds in the case of the single unit interconnection; in the case of the two unit interconnection, however, it revealed difficult conditions for islanding detection in the event of interconnection with a large capacity synchronous generator and in the presence of interference of variable signals. Additionally, examination was made on such subjects as countermeasures against high/low voltage short-circuit accident in low voltage systems and limitation in introducing photovoltaic power generation on account of rise in voltage of a system line. (NEDO)

  12. Fiscal 1997 report on the cooperative research on the preservation and sustainable utilization of biological diversification; Seibutsu tayosei hozen to jizokuteki riyo nado ni kansuru kenkyu kyoryoku (1997 nendo hokokusho)

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1998-03-01

    Cooperative researches were conducted between Japan and Thailand, Indonesia and Malaysia for the purpose of the technology development to make developing countries themselves preserve bioresources existing in tropical forests and use those sustainably. The research subjects for Thailand are a strategical study on eating of the primates, improvement of a microorganism culture collection system, preservation of biological diversification using an artificial ecosystem, bioresource utilization, etc. The subjects for Indonesia are a study of a microorganism culture collection system, study of plant preservation technology, study of microorganism utilization technology, study of plant utilization technology, promotion of the founding of the Indonesia tropical bioresource information center, etc. The subjects for Malaysia are biological diversification database and gene bank, assessment/monitoring of the ocean ecosystem, assessment and inventory of the ecosystem using hi-tech technology, search/separation of bioactive substances originated from microorganism/plant, etc. 26 refs., 24 figs., 81 tabs.

  13. FY 1997 report on the investigation on the actual status of international research information exchange in research organizations in Japan and U.S.A; 1997 nendo chosa hokokusho (Nichibei kenkyu kikan ni okeru kokusai kenkyu koryu jittai chosa)

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1998-03-01

    An investigation was made on the actual status of utilizing researchers from foreign countries and internationally exchanging researchers with views on technological researchers in universities and public institutes in Japan and the U.S.A. Foreign researchers at 39 research institutes in the Tsukuba area are from Asian region at 43%, and European and North American regions at 43%. Asian researchers are dominated overwhelmingly by Chinese and Korean people. Researchers from Europe and North America have a high ratio of working at institutes belonging to the Ministry of International Trade and Industry, and many of them are of short period staying type. On the other hand, many of those from African regions intend to study diplomatic and cultural exchange, and those from Middle and South American regions to study agricultural and fishery industries. About 8.4% of the scientists and engineers who obtained doctorates in America in 1995 is foreign nationals, and about 83.3% of them is of long period staying type. Foreign students in the U.S.A. account for 3.1% of students in institutions of higher education. The higher the education level, the higher the foreign student ratio, whereas the ratio reaches 33.0% in doctoral courses. Persons who obtained doctorates in the department of science and engineering are, in decreasing order, Chinese, Taiwanese, Indian and Korean. 32 figs., 47 tabs.

  14. Fiscal 1996 report on the survey of making models for introducing petroleum substituting energy systems. 3; 1996 nendo chosa hokokusho (sekiyu daitai energy system donyu model sakusei ni kansuru chosa). 3

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1997-03-01

    In the introduction of new energy and promotion of measures taken for energy conservation, it is necessary to give local governments, entrepreneurs, etc. guidance for introducing energy systems which meet with courses for how to construct infrastructures of towns or cities and features of facilities in case of regional development, arrangement of facilities, etc. In fiscal 1996, each of the petroleum substituting energy systems which were invented in fiscal 1996 was arranged, and the main systems were shown in image in pamphlets. Namely, those are related to photovoltaic power generation, use of solar energy, use of wind energy, use of geothermal energy, use of biomass energy, use of waste, use of unused energy, cogeneration, load levelling, wide-area energy supply, etc. Characteristics of each of the petroleum substituting energy systems were arranged from viewpoints of introducibility, scale, features of supply power/heat, economical efficiency and environmental characteristics, and subjects. Typical examples of the introduction in the country were outlined in terms of introduction sites, actual operational results, and effects. 7 figs., 4 tabs.

  15. Report for fiscal 1998. Joint research of environment-friendly system for effectively utilizing water resources; 1998 nendo hokokusho. Kankyo taiogata mizushigen yuko riyo system ni kansuru kenkyu kyoryoku

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1999-03-01

    The research is conducted in cooperation with Industrial Technology Development Institute of the Philippines, and aims to solve water related problems such as unstable water supply and water quality pollution though developing a waste water treatment and recycling system which is easy to operate and maintain, low in cost, and usable in the Philippines. Fiscal 1998 is the second year of the project. Statistics are studied about the load that each industrial branch imposes on water for its pollution, and it is found that food manufacturers, paper pulp mills, and fiber dyeing plants are heavily responsible for water pollution. A method consisting of single-tower UASB anaerobic treatment and activated sludge treatment is applied as a water treatment process to Ram Food Products Corporation, and its optimization is studied. A removal rate 60% is achieved after a 12-hour treatment period at a COD (chemical oxygen demand) rate of 8g/liter/day. A method consisting of coagulating sedimentation and activated sludge treatment is applied to the waste water from a Solid Mill Corporation dyeing plant, when it is found that the water after ultimate treatment is almost colorless and that COD is 76mg/liter and BOD (biological oxygen demand) 13mg/liter, and these suggest that the waste water is recyclable. Since it is low in COD removing rate, the application of anaerobic treatment to high-concentration water after washing is not appropriate. (NEDO)

  16. Fiscal 1998 research report on the basic study on the effect of microgravity on living individuals; Bisho juryoku no seibutsu kotai ni taisuru eikyo no kiso kenkyu 1998 nendo chosa hokokusho

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1999-03-01

    In order to clarify the effect of microgravity on vital functions and organisms at a cell level, this research studies the molecular biological response function of higher animals, the gravity acceptable mechanism of single-cell organisms, the effect of gravity on geotaxis of insects, measurement of monoamine system neurotransmitters of rat hippocampus by dialysis in a brain and the effect of microgravity on it, the effect of microgravity on water and bone metabolism functions and immunity function, and the analysis of BZ reaction as a simple model of vital reaction. The themes of the research are as follows: the effect of microgravity environment on cell fusion, the analysis of gravity acceptable mechanisms of single-cell organisms, the effect of oriental medical treatment on bone metabolism anomaly of mouses under microgravity environment, the effect of oriental medical treatment on change in physiological function under microgravity environment, the effect of microgravity environment on immunity systems, the effect of gravity on cell activities, the effect of a gravity field on chemical oscillation reaction, and the effect of gravity on geotaxis of insects. (NEDO)

  17. FY 1998 annual report on the CO{sub 2} reduction by 30 manufacturing companies (plants) through energy conservation. Thailand; Seizogyo 30 sha (kojo) no sho energy ni yoru CO{sub 2} haishutsuryo sakugen 1998 nendo chosa hokokusho. Taikoku

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1999-03-01

    This project is aimed at energy-saving diagnosis of 30 energy-intensive manufacturing plants in Thailand, to draw the project plans and clarify, e.g., greenhouse effect gas reduction and cost-effectiveness effects, on the basis of transferring and applying the energy management and energy-saving equipment technologies now being used by the manufacturing sector in Japan. The 30 plants analyzed are 6 metal-related plants, 3 non-ferrous plants, 5 chemical plants, 6 ceramics plant, 4 textile plants, 4 food processing plants and 2 pulp plants. Two or more feasible energy-saving measures are studied for each plant. A total of 178 improvement measures (approximately 6 on the average for each plant) are identified as the ones related to energy-saving and operation controlling techniques. These measures could reduce CO2 emissions by 145,000 t/y from 1,370,000 t/y released from the 30 plants. The measures of high cost-effectiveness are (use of an appropriate pressure for air compressors) and (resting of transformers on non-working days). (NEDO)

  18. Research report of FY 1997 on the technology trend survey meetings for highly creative and functional material creation technology; 1997 nendo `dokusoteki kokino zairyo sosei gijutsu` gijutsu doko chosa kenkyukai ni kakawaru chosa kenkyu hokokusho

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1998-02-01

    Survey and research have been conducted to plan and investigate the direction of creative material development. The survey and research were carried out through discussions in the symposium and meetings. For the symposium, were presented the activities of Asahi Research Center for reducing the environmental loads, environmentally acceptable industries and materials, needs and research/development trends related to ceramics including artificial lattice, processes and composites, no needs is good needs, needs and future research/development in chemical companies, and the display material development. For the results of national institutes of the Agency of Industrial Science and Technology, 17 papers were presented which include the neuro-computer for distinguishing plastic wastes, development and assessment of biodegradable plastics, recycling of high molecular wastes, super plastic silicon nitride with an ultra-long life through the formation of orientated texture, reaction hot-press of carbonized chaff by adding metal oxides, etc. 14 tabs.

  19. Reports on research achievements in developing high-performance industrial furnaces in fiscal 1998 (Research and development of high-performance industrial furnaces). Volume 1; 1998 nendo koseino kogyoro nado ni kansuru kenkyu kaihatsu seika hokokusho. 1

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1999-03-01

    From the reports on research achievements in developing high-performance industrial furnaces in fiscal 1998, the report volume 1 was prepared as a research achievement report of each working group, detailing fundamental researches, heating furnaces, and heat treatment furnaces. The fundamental researches have researched combustion evaluating technology, characteristics of the area in the vicinity of a combustor, characteristics of combustion of high-temperature air, heating characteristics of a furnace to investigate effect of local heat absorption, and combustion evaluation. For the heating furnaces, the following subjects were studied: development of an in-furnace combustion model, summary of an experiment for evaluating high-temperature air combustion, furnace height relative to combustion heat transfer characteristics, heat loss minimizing technology, combustion heat transfer characteristics of liquid fuels, optimal operation of the high-temperature air combustion, basic control in heating control, and steel piece heating control. Studies were performed for the heat treatment furnaces on the case of a direct firing furnace in evaluating the heat transfer characteristics, the case of a radiant tube furnace, application of thermal fluid simulation technology, furnace averaging technology, soot reducing technology, control technology, and trial design on a high-performance heat treatment furnace. (NEDO)

  20. Report on the invitation program for developing countries concerning technology promotion project of global environmental industry in FY 1997; 1997 nendo chikyu kankyo sangyo gijutsu suishin jigyo ni kakawaru chikyu kankyo kanren gijutsu kaigai kenkyusha shohei jigyo hokokusho

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1998-03-01

    In an effort to help preserve the global environment, International Center for Environmental Technology Transfer (ICETT) contributes to the solution of global environmental problems by promoting research exchanges with developing countries. As a part of this effort, ICETT hosted an environmental development researcher who visited Japan from the Institute of Environmental Research of Chulalongkorn University in Bangkok, Thailand. The invitation was extended at the request of NEDO. During the period of this investigation between September 16 and December 14, 1997, a photocatalyst was prepared and its performance was evaluated under the theme ``Application of photocatalysis to purification of atmospheric environment.`` At the same time, roadside test spots were inspected to study the practical application of optical photocatalysis. The visiting researcher also visited the National Institute for Resources and Environment to discuss with the staff of institute. This helped to deepen understandings of the state of air pollution problems confronting Japan, Europe, and North America, as well as issues related to the technologies that have been developed to solve these problems. The visiting researcher toured the RITE and examined Japan`s progress in the development of environmental control technology through joint research involving government, industry, and academia. At ICETT, the visiting researcher received training in Japan`s approaches to environmental problems in developing countries

  1. Fiscal 1997 report on the results of the international standardization R and D. International standards for computers/manikins; 1997 nendo seika hokokusho kokusai hyojun soseigata kenkyu kaihatsu. Computer manikin ni kansuru kokusai hyojun kikaku

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1998-03-01

    Through the development of computer manikins (CM) which assess human adaptability to products and environments, a draft for international standardization was worked out to propose to ISO. A draft for the international standardization was presented to ISO through a development of `a structure model` changing based on human attributes, a study of `a motion model` enabling changes in posture and movement, a study of `an evaluation model` evaluating attainment ranges and ecodynamic loads, and a development of `computer functions` realizing the above-mentioned functions. The development of CM having the following characteristics: a function to reproduce `the structure model` based on the ISO7250 human body dimensional measuring values which were regulated in items for the human body dimensional measuring, a function to change posture/movement based on the joint movable range data, a function to evaluate geometrical human adaptability such as attainment ranges. As a plug-in to Autodesk Mechanical Desktop 2.0, the above-mentioned functions were realized, and the modular structure platform was constructed which enables the wide-range cross-industry option and functional expansion by the advance of CM. 7 refs., 41 figs., 18 tabs.

  2. Report on evaluation on endocrine disturbing effect of chemicals and development of test methods; 1999 nendo kagaku busshitsu no naibunpi kakuran koka ni kansuru hyoka oyobi shikenho no kaihatsu hokokusho

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    2001-03-01

    With regard to endocrine disturbing effect being the new deleteriousness of chemicals, data were collected and evaluated by using the existing testing methods, data were collected by using the screening test, the testing methods were developed, and international investigation was carried out to establish the risk evaluation methods. In the evaluation by using the existing test methods, seven substance groups deficient in deleteriousness data qualitatively and quantitatively were given reproduction toxicity tests to evaluate availability of the endocrine activity. Development of the screening test method has been carried out by participating the validation test by OECD to make the uterotrophic assay method and the Hershberger assay method a test guideline having international matching property. International investigations to establish the risk evaluation were executed on the molecular mechanism of nuclear receptors, the chemical, metabolic and environmental behaviors of endocrine active substances, the effects of the endocrine active substances on experimental animals and human, the utilization thereof for risk assessment in human, and the effects of endocrine disturbance acting substances in wildlife species. (NEDO)

  3. Fiscal 1997 survey report on a feasibility of international collaboration on bio-hydrogen R and D; 1997 nendo chosa hokokusho (bio suiso seizo gijutsu ni kakawaru kokusai kyoryoku kanosei chosa)

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1998-03-01

    R and D of the production technology of biohydrogen is an option effective for the world energy supply technology and the world environmental preservation technology in the 21st century. At present, a project named `R and D of the environment harmony type hydrogen production technology` tackles the R and D of the hydrogen production technology using photosynthetic microorganisms, and promotes the R and D in this field from both aspects of a basis and application as seen in a workshop held including interchanges with researchers and research institutes overseas. With the recently increasing interest in bio-hydrogen production technology also overseas, search and bleeding/improvement of microorganisms related to the hydrogen production and utilization technology of biomass have been advancing. For development in this field, it is necessary to construct a widespread research network and promote the comprehensive research and development. In this survey, most of the research institutes visited recognized an importance of international cooperation in this field and agreed to make future research interchanges in a wide range. Based on the survey, a feasibility of concrete international collaboration is searched. 146 refs., 2 figs., 11 tabs.

  4. FY 1998 annual report on the exploration and production of functional peptide from unutilized protein resources; 1998 nendo miriyo tanpakushitsugen kara no kinosei pepuchido no tansaku to seisan ni kansuru kenkyu hokokusho

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1999-03-01

    This project is aimed at promotion of effective utilization of unutilized resources by transforming histidine-containing peptide (anserine), enzymatically hydrolyzed muscle protein present in lean salmon swimming off the Sanriku District in the spawning season, into functional peptide. A reactor system, comprising an enzyme-immobilized column and rotary bioreactor, is investigated to efficiently produce peptide by enzymatically hydrolyzing the water-insoluble muscle protein. Anserine is isolated by ethanol extraction, ion-exchanging and partition chromatography. The TPTZ and ABTS methods are developed for speeding up measurement of the antioxidant activity. The salmon muscle protein is hydrolyzed by 3 types of enzymes, to measure the free radical erasing activity by the ABTS method. The enzymatically hydrolyzed protein is fractionated by gel permeation chromatography. The fractions having a molecular weight of 10,000 or less show strong antioxidant activity. The hydrolyzed protein shows improved activity by the iron rhodanide method when it has histidine at the center of tripeptide, and strong radical erasing function when it has thyrosine or tryptophan at the carboxyl terminal. (NEDO)

  5. FY 1998 annual summary report on development of powder metallurgy techniques of the next generation by CNC multi-axis forming; 1998 nendo CNC tajiku seikei ni yoru jisedai funmatsu yakin gijutsu no kaihatsu seika hokokusho

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1999-03-01

    This R and D program is aimed at development of a new press, based on the new pressing concept of right-and-left press cycles in addition to the conventional up-and-down press cycles, development of the die suitable for the press, optimization of the pressing conditions, and establishment of the automatic forming techniques for undercut shapes, which are very difficult for the compacts at present, because of the problems associated with, e.g., reproducibility and uniformity of density distribution, as the hardware-related themes. The conventional 5-axis, up-and-down CNC press is provided with the right-and-left pressing mechanism, to enable it to form compacts having an undercut shape. The die and punch of structure and shape suitable for the newly developed press were designed and made. Two mold types by shape are developed, one is for the chip as a cutting tool and the other for the machine part having an undercut. The conditions to control and improve compressive fluidity of the stock powder have been established. The new press forming techniques for the products of high precision and reproducibility have been developed, based on the analysis of the compacts and their sinters. (NEDO)

  6. Research cooperation report for fiscal 1997 on the environment-friendly system for effectively utilizing water resources; 1997 nendo kankyo taiogata mizushigen yuko riyo system ni kansuru kenkyu kyoryoku itaku gyomu hokokusho

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1998-03-01

    This effort exerted in cooperation with the Philippines aims to solve problems related to water resources such as stable supply and pollution of water through developing a waste water treatment/water reuse system which is easy to operate and maintain, and low in price. The ultimate goal includes (1) the construction of a waste water treatment/water reuse system comprising an anaerobic reaction tank and activated charcoal absorption tower, easy to operate and maintain, and low in price, (2) the employment of goods procurable in the Philippines, the goods including carriers for use in the anaerobic reaction tank, microbes for use in both aerobic and anaerobic reaction tanks, and activated charcoal for use in waste water reutilization, and (3) the establishment of optimum operating conditions for the waste water treatment/water reuse system by use of a pilot plant and the transfer of operating and managing techniques to the Filipino counterpart. In this fiscal year, investigations are conducted to disclose the actualities of waste water treatment and water consumption by primary industries in the vicinity of Laguna de Bay, and the waste water to be the object of study and the place of pilot plant installation have been selected. Also conducted are investigations into the carrier, microbe, activated charcoal, etc., for use in the anaerobic reaction tank. (NEDO)

  7. Fiscal 1997 report on the results of the research on the development of high-performance industrial furnaces. Volume 3; 1997 nendo seika hokokusho (koseino kogyoro no kaihatsu ni kansuru kenkyu seika hokokusto)

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1998-03-01

    A R and D was conducted for the purpose of developing remarkable energy conservation/CO2 reduction technologies. In fiscal 1997, the five working groups about the following were formed to have animated discussions: the basic research, heating furnace, heat treatment furnace, melting furnace, and tubular heating furnace. The research subjects are the pursuit/deepening of the base study on flame structures in high temperature air combustion, critical heat recovery of the system in high temperature air combustion, examination of the basic common technology on the ultimate optimization of the material heat transfer, construction of general-purpose experimental database, setting-up of design standards for general-purpose high-performance industrial furnaces, presentation of examples of the actual trial design based on the design standards and feasibility study of the practical application, preparatory support of the field test project on high-performance industrial furnaces for commercialization/diffusion/spread, etc. Further, how to arrange the developmental results was studied to make the results of the project useful for study of the prompt commercialization. 442 refs., 1444 figs., 311 tabs.

  8. FY 1998 survey report on the feasibility study of environmental cooperation in environmental protection technology, system, etc. for spread to developing countries; 1998 nendo kankyo taisaku gijutsu seidonado no tojokoku fukyu ni kakawaru kankyo kyoryoku kanosei chosa hokokusho

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1999-03-01

    The paper arranged the present situation and the problems of environmental cooperation for developing countries, and studied based thereon how to cooperate in environmental protection for developing countries in the future. At the same time, it arranged the problems/subjects posed when environment-related companies in Japan try to transfer environmental technology to developing countries, for the purpose of using them as data in studying possibility of reviewing the environmental cooperation presently conducted. A view on environmental cooperation is that as security of mankind, it is necessary to help developing countries in technology/knowledge/fund. However, a trial calculation indicated that the initial investment of 11.1 trillion yen is needed only for desulfurization and water treatment in China and ASEAN countries. Such a huge amount of money cannot be paid at all even by developed countries. As the support of environmental protection measures, the one also including energy and resource is needed. Further, the support of environmental protection measures should be the one that has the exhibition effect and influential effect, promotes efforts of developing countries' own, and pushes independent environmental measures forward. From this point of view, a study was made on what the details of the environmental cooperation should be like. (NEDO)

  9. Fine Structure in Multi-Phase Zr8Ni21-Zr7Ni10-Zr2Ni7 Alloy Revealed by Transmission Electron Microscope

    Directory of Open Access Journals (Sweden)

    Haoting Shen

    2015-07-01

    Full Text Available The microstructure of an annealed alloy with a Zr8Ni21 composition was studied by both scanning electron microscopy (SEM and transmission electron microscopy (TEM. The presence of three phases, Zr8Ni21, Zr2Ni7, and Zr7Ni10, was confirmed by SEM/X-ray energy dispersive spectroscopy compositional mapping and TEM electron diffraction. Distribution of the phases and their morphology can be linked to a multi-phase structure formed by a sequence of reactions: (1 L → Zr2Ni7 + L’; (2 peritectic Zr2Ni7 + L’ → Zr2Ni7 + Zr8Ni21 + L”; (3 eutectic L” → Zr8Ni21 + Zr7Ni10. The effect of annealing at 960 °C, which was intended to convert a cast structure into a single-phase Zr8Ni21 structure, was only moderate and the resulting alloy was still multi-phased. TEM and crystallographic analysis of the Zr2Ni7 phase show a high density of planar (001 defects that were explained as low-energy boundaries between rotational variants and stacking faults. The crystallographic features arise from the pseudo-hexagonal structure of Zr2Ni7. This highly defective Zr2Ni7 phase was identified as the source of the broad X-ray diffraction peaks at around 38.4° and 44.6° when a Cu-K was used as the radiation source.

  10. Incorporation of alumina particles into reactively sintered Ni{sub 3}Al; Hanno shoketsu ni yoru Ni{sub 3}Al eno alumina no fukugoka

    Energy Technology Data Exchange (ETDEWEB)

    Yamazaki, M.; Ochiai, S.; Arai, T. [Teikyo Univ. of Science and Tech., Yamanashi (Japan); Sakamoto, Y. [Teikyo Univ. of Science and Tech., Yamanashi (Japan)]|[NIKKOSHI Co. Ltd., Tokyo (Japan); Koyama, M. [Japan Space Utilization Promotion Center, Tokyo (Japan)

    1998-08-15

    The Ni3Al having the structure of L1{sub 2} is attracting the attention of the people. As methods for preparing it, the reactive sintering method according to which Ni powders and Al powders are mixed first and then reacted at 700 degC to prepare the Ni2Al, and the combustion composition method are expected as the hopeful method. In this study, several processes for composing alumina while preparing the Ni3Al by reactively sintering Ni powders and Al powders, are compared. While dispersing alumina powders into Ni powders beforehand by mechanical dispersing (MD), the Ni3Al can be produced under the conditions as they are. As another method for producing the Ni3Al according to which NiO powders are mixed into Ni powders to oxidize surfaces of the Ni powders and then they react with the Al powders, the reactive sintering of the Ni3Al and the alumina generation by the thermit reaction progress simultaneously, but dispersion of the alumina is the worst and the void is too much. As for the method according to which the NiO powders in the Ni powders are mechanically dispersed and then reacted with Al powders, the resultant reactions hardly occur. 9 refs., 4 figs.

  11. An Ultrastable and High-Performance Flexible Fiber-Shaped Ni-Zn Battery based on a Ni-NiO Heterostructured Nanosheet Cathode.

    Science.gov (United States)

    Zeng, Yinxiang; Meng, Yue; Lai, Zhengzhe; Zhang, Xiyue; Yu, Minghao; Fang, Pingping; Wu, Mingmei; Tong, Yexiang; Lu, Xihong

    2017-11-01

    Currently, the main bottleneck for the widespread application of Ni-Zn batteries is their poor cycling stability as a result of the irreversibility of the Ni-based cathode and dendrite formation of the Zn anode during the charging-discharging processes. Herein, a highly rechargeable, flexible, fiber-shaped Ni-Zn battery with impressive electrochemical performance is rationally demonstrated by employing Ni-NiO heterostructured nanosheets as the cathode. Benefiting from the improved conductivity and enhanced electroactivity of the Ni-NiO heterojunction nanosheet cathode, the as-fabricated fiber-shaped Ni-NiO//Zn battery displays high capacity and admirable rate capability. More importantly, this Ni-NiO//Zn battery shows unprecedented cyclic durability both in aqueous (96.6% capacity retention after 10 000 cycles) and polymer (almost no capacity attenuation after 10 000 cycles at 22.2 A g-1 ) electrolytes. Moreover, a peak energy density of 6.6 µWh cm-2 , together with a remarkable power density of 20.2 mW cm-2 , is achieved by the flexible quasi-solid-state fiber-shaped Ni-NiO//Zn battery, outperforming most reported fiber-shaped energy-storage devices. Such a novel concept of a fiber-shaped Ni-Zn battery with impressive stability will greatly enrich the flexible energy-storage technologies for future portable/wearable electronic applications. © 2017 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

  12. Investigation of Characteristics of Sprayed Ni-Cr and Ni-Cr-Wc Coatings

    Directory of Open Access Journals (Sweden)

    Ovidijus Jarašūnas

    2017-01-01

    Full Text Available The article deals with the flame sprayed Ni-Cr and Ni-Cr-WC coatings on construction S235 steel substrates. Before spraying, the surfaces of substrates were treated mechanically. Using the different chemical composition of Ni-Cr and Ni-Cr-WC spraying powder and additional substrate heating till 250–290 °C, were sprayed coatings. The microstructure, porosity, hardness, elastic modulus, wear resistance of the Ni-Cr and Ni-Cr-WC coatings were investigated in the work. The influence of the chemical composition and WC content of the coatings on the various physical and tribological properties of the coatings were evaluated. Also the dependence of these coatings characteristics was investigated.

  13. Structural analysis of Ni/NiO-water interface using X-ray reflectivity

    Energy Technology Data Exchange (ETDEWEB)

    Kim, Jong Jin; Kim, Seung Hyun; Kim, Ji Hyun [Ulsan National Institute of Science and technology, Ulsan (Korea, Republic of); Bahn, Chi Bum [Argonne National Laboratory, Illinois (United States)

    2013-10-15

    These test revealed the epitaxial relationship between Ni substrate and the oxide layer as well as those structures. However, still the resolution of the initial structural data of interface between water and pre oxidized Ni(110) surface is not clear. Therefore, the objective in this study was to obtain detailed structural data between pre-oxidized Ni(110) and water interfaces to investigate the mechanism of growth the passive film formed on Ni(110) by In-situ high energy X-ray reflectivity study and simulated atomistic model. The surface treatment procedure to increase the surface crystallinity was developed to surface x-ray reflectivity measurement. The CTR data shows the surface pre-treatment procedure developed for Ni(110) was suitable for the surface X-ray study. Synchrotron X-ray experiments and analyses will be continued to identify the surface interface between Ni(110), water, and solution contained lead.

  14. Contexto Familiar: Diferencias Conductuales entre Niños y Niñas

    OpenAIRE

    María Aurelia Ramírez Castillo

    2005-01-01

    En este trabajo se investigan las diferencias por género en problemas de conducta. En una muestra de 200 sujetos (niños y niñas) en tre 5 y 18 años de Granada (España), los resultados concluyen que los niños tienen más problemas de conducta delictiva que las niñas. Cuando existen conflictos matrimoniales y prácticas de crianza negativas, de nuevo los niños tienen más problemas externos que las niñas. En este trabajo se investigan las diferencias por género en problemas de condu...

  15. Ni Mineralization and PGE Characterization in the Kabanga and ...

    African Journals Online (AJOL)

    ... indicate that the Luhuma is also potential for Ni-Cu sulfide deposits particularly on drill holes LUH05 and LUH13 where these samples were taken. In other words, if TiO2 increases then Ni-Cu sulfide increases and hence the potential for Ni-Cu mineralization. Key words: Tanzania, Kabanga, Luhuma, PGE, Ni-Cu sulfides ...

  16. Crystallographic Orientation Effect on Electromigration in Ni-Sn Microbump

    Science.gov (United States)

    Huang, Yi-Ting; Chen, Chih-Hao; Chakroborty, Subhendu; Wu, Albert T.

    2017-09-01

    This article addresses the reliability challenges regarding electromigration in developing three-dimensional integrated circuits (3D-ICs). The line-type sandwich structure of Ni/Sn3.5Ag(15 μm)/Ni was used to simulate microbumps to examine the reliability of electromigration in 3D-IC technology. The solder strip of Ni/Sn3.5Ag(15 μm)/Ni was stressed with a current density of 1.0 × 104 A/cm2 at 150°C. The current stressing enhanced the reaction between the solder and Ni to form Ni3Sn4, which occupied the entire joint and transformed into a Ni/Ni3Sn4/Ni structure when the solder was completely consumed. Electron backscatter diffraction was used to analyze the crystallographic characteristics of Sn and Ni3Sn4 as related to the electromigration effect. The results indicated that the crystallographic orientation of Sn plays a significant role in the Ni/Sn3.5Ag/Ni, whereas the orientation of Ni3Sn4 is the dominant factor of diffusion behavior in the Ni/Ni3Sn4/Ni.

  17. Site occupancy of Fe in ternary Ni 75-x

    Indian Academy of Sciences (India)

    The results of a detailed structural and magnetic study clearly indicate that regardless of the thermal history of the samples, Fe has a strong preference for the Ni sites in Ni-poor (non-stoichiometric) Ni75Al25 alloys. Fe substitution has a profound effect on the nature of magnetism in Ni75Al25.

  18. Synthesis of stochastic open cell Ni-based foams

    Energy Technology Data Exchange (ETDEWEB)

    Queheillalt, Douglas T.; Katsumura, Yasushi; Wadley, Haydn N.G

    2004-02-15

    Open cell, stochastic Ni-based foams have been synthesized on carbon foam templates by transient liquid phase bonding nickel based superalloy (Ni-21Cr-9Mo-4Nb) and Ni-25Cr-10P powders. The mechanical properties of these Ni-based foams were similar to those of other lower temperature metal foams of similar topology.

  19. Studies on the valence electronic structure of Fe and Ni in Fe Ni ...

    Indian Academy of Sciences (India)

    -to- X-ray intensity ratios of Fe and Ni in pure metals and in FeNi1- alloys ( = 0.20, 0.50, 0.58) exhibiting similar crystalline structure have been measured following excitation by 59.54 keV -rays from a 241Am point source, to understand as to why the properties of permalloy Fe0.2Ni0.8 is distinct from other alloy ...

  20. Directional Solidification and Mechanical Properties of NiAl-NiAlTa Alloys

    Science.gov (United States)

    Johnson, D. R.; Chen, X. F.; Oliver, B. F.; Noebe, R. D.; Whittenberger, J. D.

    1995-01-01

    Directional solidification of eutectic alloys is a promising technique for producing in-situ composite materials exhibiting a balance of properties. Consequently, the microstructure, creep strength and fracture toughness of directionally solidified NiAl-NiAlTa alloys were investigated. Directional solidification was performed by containerless processing techniques to minimize alloy contamination. The eutectic composition was found to be NiAl-15.5 at% Ta and well-aligned microstructures were produced at this composition. A near-eutectic alloy of NiAl-14.5Ta was also investigated. Directional solidification of the near-eutectic composition resulted in microstructures consisting of NiAl dendrites surrounded by aligned eutectic regions. The off-eutectic alloy exhibited promising compressive creep strengths compared to other NiAl-based intermetallics, while preliminary testing indicated that the eutectic alloy was competitive with Ni-base single crystal superalloys. The room temperature toughness of these two-phase alloys was similar to that of polycrystalline NiAl even with the presence of the brittle Laves phase NiAlTa.

  1. Modeling and simulation of NiO dissolution and Ni deposition in molten carbonate fuel cells

    Energy Technology Data Exchange (ETDEWEB)

    Nam, Suk Woo; Choi, Hyung-Joon; Lim, Tae Hoon [Korea Institute of Science & Technology, Seoul (Korea, Republic of)] [and others

    1996-12-31

    Dissolution of NiO cathode into the electrolyte matrix is an important phenomena limiting the lifetime of molten carbonate fuel cell (MCFC). The dissolved nickel diffuses into the matrix and is reduced by dissolved hydrogen leading to the formation of metallic nickel films in the pores of the matrix. The growth of Ni films in the electrolyte matrix during the continuous cell operation results eventually in shorting between cathode and anode. Various mathematical and empirical models have been developed to describe the NiO dissolution and Ni deposition processes, and these models have some success in estimating the lifetime of MCFC by correlating the amount of Ni deposited in the matrix with shorting time. Since the exact mechanism of Ni deposition was not well understood, deposition reaction was assumed to be very fast in most of the models and the Ni deposition region was limited around a point in the matrix. In fact, formation of Ni films takes place in a rather broad region in the matrix, the location and thickness of the film depending on operating conditions as well as matrix properties. In this study, we assumed simple reaction kinetics for Ni deposition and developed a mathematical model to get the distribution of nickel in the matrix.

  2. Metallic Ni3 P/Ni Co-Catalyst To Enhance Photocatalytic Hydrogen Evolution.

    Science.gov (United States)

    Zhao, Jun Jie; Liu, Peng Fei; Wang, Yu Lei; Li, Yu Hang; Zu, Meng Yang; Wang, Chong Wu; Wang, Xue Lu; Fang, Li Jun; Zeng, Hui Dan; Yang, Hua Gui

    2017-11-27

    Metallic Ni3 P/Ni can be used as a co-catalyst to replace noble metal Pt for efficient photocatalytic hydrogen evolution, due to its excellent trapping-electron ability. The applications of metallic Ni3 P/Ni co-catalyst on CdS, Zn0.5 Cd0.5 S, TiO2 (Degussa P25) and g-C3 N4 are further confirmed, indicating its versatile applicability nature like Pt. © 2017 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim.

  3. Actitudes afectivas hacia niños y niñas con necesidades educativas especiales

    OpenAIRE

    Cárdenas Leitón, Helvetia

    2013-01-01

    En este artículo se analizan las actitudes afectivas de los compañeros de clase hacia niños y niñas con necesidades educativas especiales, integrados en el sistema de educación regular. Se parte de una investigación cualitativa realizada en cuatro secciones de I y II Ciclos de la Enseñanza General Básica, en Escuelas Urbano Marginales, donde se encontraban niños con necesidades educativas especiales. Se encontró que el tipo de relaciones que se suscitan con los niños integrados, están marcada...

  4. Niños y Violencia

    OpenAIRE

    International Child Development Centre

    1997-01-01

    Este Innocenti Digest explora la violencia de los niños y hacia los niños, usando el marco de la Convención de los Derechos del Niño de las Naciones Unidas. Se centra en la violencia interpersonal, tanto intrafamiliar como extrafamiliar. Se incluye el abuso sexual y la explotación ya que a pesar de no implicar obligatoriamente violencia o coerción, la mayor parte de la evidencia demuestra su efectos dañinos tanto físicos como psicológicos. También se discute la implicación de los niños en los...

  5. Ni adsorption and Ni-Al LDH precipitation in a sandy aquifer: An experimental and mechanistic modeling study

    NARCIS (Netherlands)

    Regelink, I.C.; Temminghoff, E.J.M.

    2011-01-01

    Mining activities and industries have created nickel (Ni) contaminations in many parts of the world. The objective of this study is to increase our understanding of Ni adsorption and Nickel-Aluminium Layered Double Hydroxide (Ni-Al LDH) precipitation to reduce Ni mobility in a sandy soil aquifer. At

  6. FY 1999 report on the results of the introductory study on the global environmental industry technology. Investigational study on the environmental creation technology by the application of ecosystem information functions; 1999 nendo chikyu kankyo sangyo gijutsu ni kakawaru sendo kenkyu seika hokokusho. Seitaikei joho kino oyo ni yoru kankyo sozo gijutsu ni kansuru chosa kenkyu

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    2000-03-01

    To know the state of environmental pollution before it clearly exists, an investigational study was made on the technology to measure environmental stress at high sensitivity, in wide range and at high speed using functions to respond chemical substances, etc. which living organisms have. The FY 1999 results were outlined. As to the application of ecosystem information functions, survey was conduced paying attention to the environmental stress response of each of the bacteria, algae, plants and animals, responses viewed from the manifestation of immunity antibodies which occurs inside living organisms and changes at genetic level, and responses of algae and plants in case of specifying environmental pollutants. In relation to the application of the biological amplification mechanism, survey was carried out on environmental stress signals sent from plants, selection of environmental stress index plants, detection of environmental pollutants using bacteria, high sensitivity detection using animal (nematode), etc. Concerning the standardization of the environmental measuring technology by the application of ecosystem information functions, survey was conducted on artificial molecular recognition sensor, antibody device sensor, biochips, system construction, etc. (NEDO)

  7. Consequences of Surface Oxophilicity of Ni, Ni-Co, and Co Clusters on Methane Activation.

    Science.gov (United States)

    Tu, Weifeng; Ghoussoub, Mireille; Singh, Chandra Veer; Chin, Ya-Huei Cathy

    2017-05-24

    This study describes a new C-H bond activation pathway during CH4-CO2 reactions on oxophilic Ni-Co and Co clusters, unlike those established previously on Ni clusters. The initial C-H bond activation remains as the sole kinetically relevant step on Ni-Co, Ni, and Co clusters, but their specific reaction paths vary. On Ni clusters, C-H bond activation occurs via an oxidative addition step that involves a three-center (H3C···*···H)⧧ transition state, during which a Ni-atom inserts into the C-H bond and donates its electron density into the C-H bond's antibonding orbital. Ni-Co clusters are more oxophilic than Ni; thus, their surfaces are covered with oxygen adatoms. An oxygen adatom and a vicinal Co-atom form a metal-oxygen site-pair that cleaves the C-H bond via a σ bond metathesis reaction, during which the Co inserts into the C-H bond while the oxygen abstracts the leaving H-atom in a concerted, four-center (H3C···*···H···O*)⧧ transition state. Similarly, Co clusters also catalyze the σ bond metathesis step, but much less effectively because of their higher oxophilicities, much stronger binding to oxygen, and less effective hydrogen abstraction than Ni-Co clusters. On Ni-Co and Co clusters, the pseudo-first-order rate coefficients are single-valued functions of the CO2-to-CO ratio (or H2O-to-H2 ratio), because this ratio prescribes the oxygen chemical potentials and the relative abundances of metal-oxygen site-pairs through the water-gas shift equilibrium. The direct involvement of reactive oxygen in the kinetically relevant step leads to more effective CH4 turnovers and complete elimination of coke deposition on Ni-Co bimetallic clusters.

  8. Microstructure and mechanical properties of sputter deposited Ni/Ni{sub 3}Al multilayer films at elevated temperature

    Energy Technology Data Exchange (ETDEWEB)

    Zhang, Chao [Shanghai Key Laboratory of Materials Laser Processing and Modification, School of Materials Science and Engineering, Shanghai Jiao Tong University, Shanghai 200240 (China); Collaborative Innovation Center for Advanced Ship and Deep-Sea Exploration, Shanghai 200240 (China); Feng, Kai, E-mail: fengkai@sjtu.edu.cn [Shanghai Key Laboratory of Materials Laser Processing and Modification, School of Materials Science and Engineering, Shanghai Jiao Tong University, Shanghai 200240 (China); Collaborative Innovation Center for Advanced Ship and Deep-Sea Exploration, Shanghai 200240 (China); Li, Zhuguo, E-mail: lizg@sjtu.edu.cn [Shanghai Key Laboratory of Materials Laser Processing and Modification, School of Materials Science and Engineering, Shanghai Jiao Tong University, Shanghai 200240 (China); Collaborative Innovation Center for Advanced Ship and Deep-Sea Exploration, Shanghai 200240 (China); Lu, Fenggui; Huang, Jian; Wu, Yixiong [Shanghai Key Laboratory of Materials Laser Processing and Modification, School of Materials Science and Engineering, Shanghai Jiao Tong University, Shanghai 200240 (China); Collaborative Innovation Center for Advanced Ship and Deep-Sea Exploration, Shanghai 200240 (China)

    2016-08-15

    Highlights: • Ni/Ni{sub 3}Al multilayers are prepared by magnetron sputtering. • Both grain size and phase constitution of annealed Ni/Ni{sub 3}Al multilayers are dependent on individual layer thickness. • The hardness of annealed Ni/Ni{sub 3}Al multilayers varies with individual layer thickness and annealing temperature. • 40 nm Ni/Ni{sub 3}Al multilayer exhibits excellent hardness at elevated temperature. - Abstract: Nano-structured Ni/Ni{sub 3}Al multilayer was prepared by magnetron sputtering, with individual layer thicknesses h varying from 10 to 160 nm. The microstructure and hardness of Ni/Ni{sub 3}Al multilayer were investigated by X-ray diffraction, transmission electron microscopy and nanoindentation. The results show that the hardness increases with decreasing h for as-deposited and 500 °C annealed multilayers. When annealed at 700 °C, the hardness approach a peak value at h = 40 nm with followed by softening at smaller h. The influence of individual layer thickness, grain size as well as formation of ordered Ni{sub 3}Al on strengthening mechanisms of Ni/Ni{sub 3}Al multilayers at elevated temperature are discussed.

  9. Direct versus hydrogen-assisted CO dissociation over stepped Ni and Ni3Fe surfaces: a computational investigation.

    Science.gov (United States)

    Yang, Kuiwei; Zhang, Minhua; Yu, Yingzhe

    2015-11-28

    The adsorption and dissociation of CO over stepped Ni and Ni3Fe surfaces were systematically studied using density functional theory slab calculations. Both (211)-like surface structure terminations (NiNi step and NiFe step, denoted as Ni3Fe(211)-AA and Ni3Fe(211)-AB) are considered for Ni3Fe. Direct scission of the C-O bond in CO is identified as the least likely one among the three proposed dissociation pathways and CO dissociation via a CHO intermediate appears to be most feasible at low CO coverage on pure and alloyed Ni(211) surfaces. The priority of H-assisted CO dissociation might originate from the more activated C-O bond in COH and CHO. Compared to Ni(211), the Ni3Fe(211)-AB surface could facilitate CO activation especially for the most possible CHO intermediate mechanism, whose rate-limiting step is found to be altered. The d-band center theory and Mulliken charge analysis are also employed to explain the activity difference between Ni3Fe(211)-AB and Ni3Fe(211)-AA. The significant structural sensitivity of CO dissociation highlights the importance of Fe locating in the step edge and the high reactivity of Ni3Fe(211)-AB is largely ascribed to the synergistic effect between Ni and Fe at the step edge.

  10. Single-crystalline Ni2Ge/Ge/Ni2Ge nanowire heterostructure transistors.

    Science.gov (United States)

    Tang, Jianshi; Wang, Chiu-Yen; Xiu, Faxian; Hong, Augustin J; Chen, Shengyu; Wang, Minsheng; Zeng, Caifu; Yang, Hong-Jie; Tuan, Hsing-Yu; Tsai, Cho-Jen; Chen, Lih Juann; Wang, Kang L

    2010-12-17

    In this study, we report on the formation of a single-crystalline Ni(2)Ge/Ge/Ni(2)Ge nanowire heterostructure and its field effect characteristics by controlled reaction between a supercritical fluid-liquid-solid (SFLS) synthesized Ge nanowire and Ni metal contacts. Scanning electron microscopy (SEM) and transmission electron microscopy (TEM) studies reveal a wide temperature range to convert the Ge nanowire to single-crystalline Ni(2)Ge by a thermal diffusion process. The maximum current density of the fully germanide Ni(2)Ge nanowires exceeds 3.5 × 10(7) A cm(-2), and the resistivity is about 88 μΩ cm. The in situ reaction examined by TEM shows atomically sharp interfaces for the Ni(2)Ge/Ge/Ni(2)Ge heterostructure. The interface epitaxial relationships are determined to be [Formula: see text] and [Formula: see text]. Back-gate field effect transistors (FETs) were also fabricated using this low resistivity Ni(2)Ge as source/drain contacts. Electrical measurements show a good p-type FET behavior with an on/off ratio over 10(3) and a one order of magnitude improvement in hole mobility from that of SFLS-synthesized Ge nanowire.

  11. Eutectic superalloys strengthened by delta Ni3Cb lamellae, and gamma prime, Ni3Al precipitates.

    Science.gov (United States)

    Lemkey, F. D.; Thompson, E. R.

    1972-01-01

    Bivariant eutectic alloys, located on a liquidus surface within the Ni-Cb-Cr-Al quaternary, were identified which permitted the production of aligned delta Ni3Cb lamellae within a nichrome matrix containing the fcc precipitate gamma prime Ni3Al. The volume fraction of delta and gamma prime could be varied significantly by compositional changes. After directional solidification certain alloys possessed improved ductility and corrosion resistance with respect to the Ni3Al-Ni3Cb eutectic, while their values of tensile and creep strength approached or exceeded those for the Ni3Al-Ni3Cb pseudobinary system. The mechanical properties of the directionally solidified alloy, Ni-19.7 wt % Cb-6.0 wt % Cr-2.5 wt % Al, were evaluated. Its longitudinal strength in tension and creep was found to be superior to all advanced nickel base superalloys. It is thus demonstrated that useful properties for gas turbine airfoil applications can be achieved by reinforcing a strong and tough gamma nichrome matrix containing precipitated gamma prime by a strong lamellar intermetallic compound having greater strength at elevated temperature.

  12. Ni(salen): a system that forms many solvates with interacting Ni atoms

    NARCIS (Netherlands)

    Siegler, M.A.M.|info:eu-repo/dai/nl/31411744X; Lutz, M.|info:eu-repo/dai/nl/304828971

    2009-01-01

    Recrystallization of [N,N’-Ethylene-bis(salicylideneiminato)]-nickel(II) [Ni(salen)] has been carried out from a large selection of solvents. Crystals can be either solvent free or solvates. This study is based on X-ray crystal structure determinations, which include the redetermination of Ni(salen)

  13. Enhanced Electrocatalytic Activity for Water Splitting on NiO/Ni/Carbon Fiber Paper

    Directory of Open Access Journals (Sweden)

    Ruoyu Zhang

    2016-12-01

    Full Text Available Large-scale growth of low-cost, efficient, and durable non-noble metal-based electrocatalysts for water splitting is crucial for future renewable energy systems. Atomic layer deposition (ALD provides a promising route for depositing uniform thin coatings of electrocatalysts, which are useful in many technologies, including the splitting of water. In this communication, we report the growth of a NiO/Ni catalyst directly on carbon fiber paper by atomic layer deposition and report subsequent reduction and oxidation annealing treatments. The 10–20 nm NiO/Ni nanoparticle catalysts can reach a current density of 10 mA·cm−2 at an overpotential of 189 mV for hydrogen evolution reactions and 257 mV for oxygen evolution reactions with high stability. We further successfully achieved a water splitting current density of 10 mA·cm−2 at 1.78 V using a typical NiO/Ni coated carbon fiber paper two-electrode setup. The results suggest that nanoparticulate NiO/Ni is an active, stable, and noble-metal-free electrocatalyst, which facilitates a method for future water splitting applications.

  14. Adherencia al tratamiento en niñas y niños con VIH

    Directory of Open Access Journals (Sweden)

    Ana María Ruiz Navia

    2009-01-01

    Full Text Available Este artículo describe y determina el grado de adherencia al tratamiento en niños y niñas con VIH/ SIDA teniendo en cuenta los comportamientos y las variables asociadas a ésta. La muestra estuvo conformada por 1 niño y 5 niñas, diagnosticados con VIH, y su respectivo cuidador primario, quienes respondieron a la entrevista semiestructurada de evaluación de adherencia para niños y niñas con VIH/ SIDA ad hoc y a la entrevista semiestructurada de evaluación de adherencia para niños y niñas con VIH/SIDA versión cuidador primario ad hoc, respectivamente. Los resultados muestran la presencia de conductas de adherencia en los participantes del estudio, evidenciando la influencia de una serie de variables determinantes para este comportamiento. Cinco de los participantes cumplieron más del 95% de adherencia, mientras que uno se ubicó por debajo de este porcentaje. Como aspectos centrales se destacan la influencia de los estados emocionales en la toma del medicamento y la importancia del rol del cuidador primario en la adherencia.

  15. Magnetic properties of monodispersed Ni/NiO core-shell nanoparticles.

    Science.gov (United States)

    Seto, Takafumi; Akinaga, Hiroyuki; Takano, Fumiyoshi; Koga, Kenji; Orii, Takaaki; Hirasawa, Makoto

    2005-07-21

    We have recently developed a method to fabricate monodispersed Ni/NiO core-shell nanoparticles by pulsed laser ablation. In this report, the size-dependent magnetic properties of monodispersed Ni/NiO core-shell nanoparticles were investigated. These nanoparticles were formed in two steps. The first was to fabricate a series of monodispersed Ni nanoparticles of 5 to 20 nm in diameter using a combination of laser ablation and size classification by a low-pressure differential mobility analyzer (DMA). The second step was to oxidize the surfaces of the Ni particles in situ to form core-shell structures. A superconducting quantum interference device (SQUID) magnetometer was used to measure the magnetic properties of nanostructured films prepared by depositing the nanoparticles at room temperature. Ferromagnetism was observed in the magnetic hysteresis loop of the nanostructured films composed of core-shell nanoparticles with core diameters smaller than the superparamagnetic limit, which suggests the spin of Ni core was weakly exchange coupled with antiferromagnetic NiO shell. In contrast, smaller nanoparticles with core diameters of 3.0 nm exhibited superparamagnetism. The drastic change in the hysteresis loops between field-deposited and zero-field-deposited samples was attributable to the strong anisotropy that developed during the magnetic-field-assisted nanostructuring process.

  16. Ab initio phonon calculations for Ll(2) Ni3Al and B2NiAl

    NARCIS (Netherlands)

    Isaeva, E.I.; Lichtenstein, A.I.; Vekilov, Y.K.; Smirnova, E.A.; Abrikosov, I.A.; Simak, S.I.; Ahuja, R.; Johansson, B.

    2004-01-01

    The phonon spectra and phonon density of states of the Ni3Al and NiAl intermetallic compounds are calculated from first principles using the linear response method in conjunction with ultrasoft pseudopotentials. The calculated phonon dispersion curves are in good agreement with available

  17. Reactivity and wettability of SiC by Ni and Ni-Si alloys

    Energy Technology Data Exchange (ETDEWEB)

    Rado, C. [INPG, 38 - Saint Martin d`Heres (France). LTPCM; Kalogeropoulou, S. [INPG, 38 - Saint Martin d`Heres (France). LTPCM; Eustathopoulos, N. [INPG, 38 - Saint Martin d`Heres (France). LTPCM

    1996-08-01

    Wettability of SiC by Ni and Ni-Si alloys was studied at 1633K by the sessile drop technique under high vacuum or pure He. It is shown that reactivity in this system can be controlled and even nearly suppressed while obtaining good wetting and strong interface. (orig.)

  18. Probing the semi-magicity of $^{68}$Ni via the $^{3}$H($^{66}$Ni,$^{68}$Ni)p two-neutron transfer reaction in inverse kinematics

    CERN Multimedia

    Reiter, P; Blazhev, A A; Kruecken, R; Franchoo, S; Mertzimekis, T; Darby, I G; Van de walle, J; Raabe, R; Elseviers, J; Gernhaeuser, R A; Sorlin, O H; Georgiev, G P; Bree, N C F; Habs, D; Chapman, R; Gaudefroy, L; Diriken, J V J; Jenkins, D G; Kroell, T; Axiotis, M; Huyse, M L; Patronis, N

    We propose to perform the two-neutron transfer reaction $^{3}$H($^{66}$Ni, $^{68}$Ni)$p$ using the ISOLDE radioactive ion beam at 2.7 $A$ MeV and the MINIBALL + T-REX setup to characterize the 0$^{+}$ and 2$^{+}$ states in $^{68}$Ni.

  19. Ni(OH){sub 2} and NiO nano structures: Synthesis, characterization and electrochemical performance

    Energy Technology Data Exchange (ETDEWEB)

    Saghatforoush, Lotf Ali; Sanati, Soheila; Mehdizadeh, Robabeh [Payam Noor Univ., Tehran (Iran, Islamic Republic of); Hasanzadeh, Mohammad [Tabriz Univ. of Medical Sciences, Tabriz (Iran, Islamic Republic of)

    2012-04-15

    Hydrothermal route have been used in different conditions for preparation of Ni(OH){sub 2} nano structures. The NiO nanoparticles were obtained by calcining the Ni(OH){sub 2} precursor at 450 .deg. C for 2 h. The effect of sodium dodecyl sulfonate (SDS) as surfactant on the morphology and size of Ni(OH){sub 2} nanoparticles were discussed in detail. X-ray diffraction (XRD), Scanning electron microscopy (SEM), Transmission electron microscopy (TEM) and Fourier transform infrared (FT-IR) spectroscopy were used to characterize the products. The growth mechanism of the as-synthesized nano structures was also discussed in detail based on the experimental results. Coming up, the NiO nanoparticle modified carbon paste electrode was applied to the determination of captopril in aqueous solution.

  20. NiO Nanoparticles: Synthesis and Characterization

    Directory of Open Access Journals (Sweden)

    A. Rahdar

    2015-04-01

    Full Text Available In the current paper,Nanostructured Nickel oxide (NiO were synthesized by co-precipitation method using Nickel(II Chloride Hexahydrate (NiCl2.6H2O and sodium hydroxide (NaOH as starting material. Structural, optical and magnetic properties of nanostructures were characterized by X-ray diffraction (XRD, scanning electron microscopy (SEM, Atomic force microscope (AFM, UV–Vis absorption; Fourier transformed infrared (FTIR and vibrating sample magnetometer (VSM technique. The X-ray diffraction pattern studies revealed the NiO have a  face-centered cubic (FCC structure and confirmed the presence of high degree of crystallinity nature NiO nanoparticles that their average size is found to be 26 nm. The composition of nanostructures confirmed by analysis of FTIR spectra. The average size of the NiO nanoparticle observed from scanning electron microscopy images is found to be dimensions about 24 nm. Magnetic measurement confirmed the Nickel Oxide nanostructures superparamagnetic behavior at room temperature (RT after calcinations.

  1. Hydrothermal synthesis of α-Ni(OH){sub 2} and its conversion to NiO with electrochemical properties

    Energy Technology Data Exchange (ETDEWEB)

    Cai, Yong; Ma, Jianmin, E-mail: nanoelechem@hnu.edu.cn; Wang, Taihong, E-mail: thwang@hnu.edu.cn

    2014-01-05

    Highlights: • α-Ni(OH){sub 2} microspheres have been synthesized with triethanolamine. • The formation mechanism of α-Ni(OH){sub 2} microspheres is suggested. • NiO deriving from α-Ni(OH){sub 2} microspheres exhibits better electrochemical performances. -- Abstract: The paper reports the fabrication of microscale NiO matrixes with enhanced electrochemical properties through annealing the corresponding chrysanthemum-like α-Ni(OH){sub 2} microspheres. The precursor α-Ni(OH){sub 2} can be synthesized by a hydrothermal method using triethanolamine as the alkaline source. The formation mechanism of chrysanthemum-like α-Ni(OH){sub 2} microspheres is properly discussed. Furthermore, the electrochemical experiments demonstrate that the microscale NiO matrixes show superior electrochemical behavior in lithium-ion batteries due to their unique structures.

  2. Exchange bias effect in polycrystalline NiO/NiMn{sub 2}O{sub 4} composite

    Energy Technology Data Exchange (ETDEWEB)

    Freitas Cabral, A.J. [Instituto de Ciências Exatas e Naturais, Universidade Federal do Pará (UFPA), Belém, PA (Brazil); Peña Serna, J.; Rache Salles, B.; Novak, M.A. [Instituto de Física, Universidade Federal do Rio de janeiro (UFRJ), Rio de Janeiro, RJ (Brazil); Pinto, A.L. [Centro Brasileiro de Pesquisas Físicas (CBPF), Rio de Janeiro, RJ (Brazil); Rocha Remédios, C.M. [Instituto de Ciências Exatas e Naturais, Universidade Federal do Pará (UFPA), Belém, PA (Brazil)

    2015-05-05

    Highlights: • Antiferromagnetic NiO/ferrimagnetic NiMn{sub 2}O{sub 4} oxide composites. • Grains are well faceted, indicating that the specimen was well crystallized. • The micrographs suggests that NiO and NiMn{sub 2}O{sub 4} may be stuck to each other. • EB effect in NiO/NiMn{sub 2}O{sub 4} oxide composites. • EB effect increases with the amount of NiO. - Abstract: Calcination of aqueous solutions formed by different molar ratios between the nickel and manganese chlorides led to the formation of antiferromagnetic NiO/ferrimagnetic NiMn{sub 2}O{sub 4} oxide composites, as determined by X-ray powder diffraction technique and Rietveld refinement. Low temperature zero field cooled and field cooled magnetic hysteresis cycles show an exchange bias effect, presumably due to interaction at the interfaces between the antiferromagnetic and ferrimagnetic materials.

  3. Hydrogenation of Amorphous and Crystalline RE-Ni Alloys

    OpenAIRE

    AOKI, Kiyoshi; Shirakawa, Kiwamu; MASUMOTO, Tsuyoshi

    1985-01-01

    Amorphous alloys with the combination of a rare earth metal(RE=Y, La, Ce, Pr and Sm) and nickel were prepared around the composition at an eutectic point by the melt-quenching technique. Amorphous Y-Ni and Sm-Ni alloys absorbed a large amount of hydrogen even in the amorphous state, while the the other alloys in La-Ni, Ce-Ni and Pr-Ni systems were decomposed to a mixture of crystalline phase and hydride during hydrogenation at 323 K. An amorphous SmNi_2 phase was also synthesized by reaction ...

  4. Reduction of a Ni/Spinel Catalyst for Methane Reforming

    DEFF Research Database (Denmark)

    Kehres, Jan; Andreasen, Jens Wenzel; Fløystad, Jostein Bø

    2015-01-01

    A nickel/spinel (Ni/MgAl2O4) catalyst, w(Ni) = 22 wt%, was investigated in situ during reduction with wide angle X-ray scattering (WAXS) in a laboratory setup and with anomalous small angle X-ray scattering (ASAXS) at a synchrotron source. Complementary high resolution transmission electron...... microscopy (HRTEM) was performed on the fresh catalyst sample. The Ni particles in the fresh catalyst sample were observed to exhibit a Ni/NiO core/shell structure. A decrease of the Ni lattice parameter is observed during the reduction in a temperature interval from 413 – 453 K, which can be related...

  5. Achievement report for fiscal 2000 on development of technologies to reduce pollutants in oil refining; 2000 nendo sekiyu seisei osen busshitsu teigen nado gijutsu kaihatsu seika hokokusho

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    2001-03-01

    Research and development has been made on technologies to reduce sulfur content in light oil and on optimization of light oil quality. This paper summarizes the achievements in fiscal 2000. In the study of enhancing the desulfurization rate in gas oil deep hydrodesulfurization process, it was found that NiHY zeolite having Ni introduced by using the ion exchange method shows stable activity, whereas the target of sulfur content of 50 ppm or lower was achieved by adding the third constituent and by optimizing the impregnation solution to pH3. In the study of the Ni, Mo/alumina catalyst, the desulfurization activity was enhanced by optimization of carrier pore size to 120 to 140 angstroms and by addition of phosphorus and silica, having the target of sulfur content of 50 ppm or lower achieved. In the research of manufacturing low-sulfur light oil using heavy oil desulfurization and hydrocracking, optimization was performed on the catalyst used in the latter stage of heavy oil desulfurization, and evaluation was given on the performance in combination of commercially available hydrometallation catalyst/middle part HDS catalyst/bottom part HDS catalyst. As a result, achievement of the target of sulfur content in the desulfurized light oil of 300 ppm or lower was verified. Life evaluation test is in continuation on the heavy oil hydrocracking catalyst. (NEDO)

  6. Evolution of Ni nanofilaments and electromagnetic coupling in the resistive switching of NiO

    Science.gov (United States)

    Luo, Yuxiang; Zhao, Diyang; Zhao, Yonggang; Chiang, Fu-Kuo; Chen, Pengcheng; Guo, Minghua; Luo, Nannan; Jiang, Xingli; Miao, Peixian; Sun, Ying; Chen, Aitian; Lin, Zhu; Li, Jianqi; Duan, Wenhui; Cai, Jianwang; Wang, Yayu

    2014-12-01

    Resistive switching effect in conductor/insulator/conductor thin-film stacks is promising for resistance random access memory with high-density, fast speed, low power dissipation and high endurance, as well as novel computer logic architectures. NiO is a model system for the resistive switching effect and the formation/rupture of Ni nanofilaments is considered to be essential. However, it is not clear how the nanofilaments evolve in the switching process. Moreover, since Ni nanofilaments should be ferromagnetic, it provides an opportunity to explore the electromagnetic coupling in this system. Here, we report a direct observation of Ni nanofilaments and their specific evolution process for the first time by a combination of various measurements and theoretical calculations. We found that multi-nanofilaments are involved in the low resistance state and the nanofilaments become thin and rupture separately in the RESET process with subsequent increase of the rupture gaps. Theoretical calculations reveal the role of oxygen vacancy amount in the evolution of Ni nanofilaments. We also demonstrate electromagnetic coupling in this system, which opens a new avenue for multifunctional devices.Resistive switching effect in conductor/insulator/conductor thin-film stacks is promising for resistance random access memory with high-density, fast speed, low power dissipation and high endurance, as well as novel computer logic architectures. NiO is a model system for the resistive switching effect and the formation/rupture of Ni nanofilaments is considered to be essential. However, it is not clear how the nanofilaments evolve in the switching process. Moreover, since Ni nanofilaments should be ferromagnetic, it provides an opportunity to explore the electromagnetic coupling in this system. Here, we report a direct observation of Ni nanofilaments and their specific evolution process for the first time by a combination of various measurements and theoretical calculations. We found

  7. La niña proletaria

    Directory of Open Access Journals (Sweden)

    Cartabia, Sabrina A.

    2011-12-01

    Full Text Available El presente trabajo se propone trazar un paralelo entre el cuento de Osvaldo Lamborghini “El niño proletario”, el cual, según la autora del ensayo, introduce al lector en la lucha de clases y el sometimiento de los/as proletarios/as, que sufren las mujeres, en particular a través de la violencia sexual. De esa forma la autora se pregunta si el poder que ciertas clases detentan sobre otras no influye también sobre el sometimiento de la mujer. El ensayo analiza además cómo la violencia sexual es una herramienta que constituye la base de la desigualdad, el sometimiento y la degradación de la mujer, al igual que constituye una herramienta de opresión de otros grupos vulnerables como los niños y niñas.

  8. [NiFeSe]-hydrogenase chemistry.

    Science.gov (United States)

    Wombwell, Claire; Caputo, Christine A; Reisner, Erwin

    2015-11-17

    The development of technology for the inexpensive generation of the renewable energy vector H2 through water splitting is of immediate economic, ecological, and humanitarian interest. Recent interest in hydrogenases has been fueled by their exceptionally high catalytic rates for H2 production at a marginal overpotential, which is presently only matched by the nonscalable noble metal platinum. The mechanistic understanding of hydrogenase function guides the design of synthetic catalysts, and selection of a suitable hydrogenase enables direct applications in electro- and photocatalysis. [FeFe]-hydrogenases display excellent H2 evolution activity, but they are irreversibly damaged upon exposure to O2, which currently prevents their use in full water splitting systems. O2-tolerant [NiFe]-hydrogenases are known, but they are typically strongly biased toward H2 oxidation, while H2 production by [NiFe]-hydrogenases is often product (H2) inhibited. [NiFeSe]-hydrogenases are a subclass of [NiFe]-hydrogenases with a selenocysteine residue coordinated to the active site nickel center in place of a cysteine. They exhibit a combination of unique properties that are highly advantageous for applications in water splitting compared with other hydrogenases. They display a high H2 evolution rate with marginal inhibition by H2 and tolerance to O2. [NiFeSe]-hydrogenases are therefore one of the most active molecular H2 evolution catalysts applicable in water splitting. Herein, we summarize our recent progress in exploring the unique chemistry of [NiFeSe]-hydrogenases through biomimetic model chemistry and the chemistry with [NiFeSe]-hydrogenases in semiartificial photosynthetic systems. We gain perspective from the structural, spectroscopic, and electrochemical properties of the [NiFeSe]-hydrogenases and compare them with the chemistry of synthetic models of this hydrogenase active site. Our synthetic models give insight into the effects on the electronic properties and reactivity of

  9. Two-proton radioactivity of 48Ni

    Science.gov (United States)

    Miernik, Krzysztof

    2011-10-01

    In experiment performed at NSCL facility we studied the decay of extremely neutron deficient isotope of 48Ni. Ions were implanted into a gaseuos detector, the Optical Time Projection Chamber which allows to record tracks of charged particles. Six events of 48Ni were observed, the two-proton radioactivity (four events) and the β-decay (two events) channels were clearly indentified. The half-life of 48Ni is determined to be T1 / 2 = 2.1-0. 4 + 1 . 4 ms. The results of three-dimensional events reconstruction as well as comparison of results with theoretical models will be presented. Research performed as a Eugene P. Wigner Fellow and staff member at the Oak Ridge National Laboratory, managed by UT-Battelle, LLC, for the U.S. Department of Energy under Contract DE-AC05-00OR22725.

  10. Voz del niño

    OpenAIRE

    Urra-Barandiarán, A. (Ainhoa); Vázquez-de-la-Iglesia, F. (Francisco); Fernandez-Gonzalez, S. (Secundino); Molina, M.T.

    2006-01-01

    En el curso de la vida la voz sufre diferentes cambios que obedecen a factores de desarrollo y en los que intervienen de manera decisiva el sistema nervioso y el sistema hormonal. La voz del niño y, por tanto la disfonía en el niño requiere una evaluación precisa y específica, no sólo desde el punto de vista instrumental sino también perceptual y en evaluación logopédica. Se insiste en la protocolización de elaboración de trastornos de voz en el niño, la revisión de los f...

  11. Melatonin Promotes Superovulation in Sika Deer (Cervus nippon

    Directory of Open Access Journals (Sweden)

    Liang Wang

    2014-07-01

    Full Text Available In this study, the effects of melatonin (MT on superovulation and reproductive hormones (melatonin, follicle-stimulating hormone (FSH, luteinizing hormone (LH and PRL were investigated in female sika deer. Different doses (40 or 80 mg/animal of melatonin were subcutaneously implanted into deer before the breeding season. Exogenous melatonin administration significantly elevated the serum FSH levels at the time of insemination compared with levels in control animals. During superovulation, the serum LH levels in donor sika deer reached their highest values (7.1 ± 2.04 ng/mL at the point of insemination, compared with the baseline levels (4.98 ± 0.07 ng/mL in control animals. This high level of LH was sustained until the day of embryo recovery. In contrast, the serum levels of PRL in the 80 mg of melatonin-treated group were significantly lower than those of control deer. The average number of corpora lutea in melatonin-treated deer was significantly higher than that of the control (p < 0.05. The average number of embryos in the deer treated with 40 mg of melatonin was higher than that of the control; however, this increase did not reach significant difference (p > 0.05, which may be related to the relatively small sample size. In addition, embryonic development in melatonin-treated groups was delayed.

  12. Microstructure evolution of electroless Ni P and Ni Cu P deposits on Cu in the presence of additives

    Science.gov (United States)

    Lin, Kwang-Lung; Chang, Yu-Lan; Huang, Chiao-Chan; Li, Fang-I.; Hsu, Jen-Che

    2001-09-01

    The microstructures of electroless Ni-P and Ni-Cu-P deposits were investigated in the presence of thiourea and saccharin with AFM. The phosphorus contents and crystallinity of the deposits were investigated. Saccharin was found to refine the nodular structure of the Ni-Cu-P deposit, while not affecting the P% of the Ni-P and Ni-Cu-P deposits. On the other hand, thiourea was found to affect the P% and surface roughness of the Ni-P deposit. Thiourea does not exhibit nodular refining effect on the deposit.

  13. The acceleration intermediate phase (NiS and Ni3S2) evolution by nanocrystallization in Li/NiS2 thermal batteries with high specific capacity

    Science.gov (United States)

    Jin, Chuanyu; Zhou, Lingping; Fu, Licai; Zhu, Jiajun; Li, Deyi; Yang, Wulin

    2017-06-01

    The intermediate phase of NiS2 is thought to be a bottleneck currently to improve the overall performance of Li/NiS2 thermal batteries because of its low conductivity and close formation enthalpy between NiS2 and the intermediate phase (NiS, Ni3S2, etc). For improving the discharge performances of Li/NiS2 thermal batteries, the nano NiS2 with an average size of 85 ± 5 nm is designated as a cathode material. The electrochemical measurements show that the specific capacity of nano NiS2 cathode is higher than micro NiS2. The nano NiS2 cathode exhibits excellent electrochemical performances with high specific capacities of 794 and 654 mAh g-1 at current density of 0.1 and 0.5 A cm-2 under a cut-off voltage of 0.5 V, respectively. These results show that the rapid intermediate phase evolution from the nanocrystallization can obviously enhance use efficiency of NiS2 and improve discharge performances of thermal batteries.

  14. Hierarchical NiCo2 S4 Nanotube@NiCo2 S4 Nanosheet Arrays on Ni Foam for High-Performance Supercapacitors.

    Science.gov (United States)

    Chen, Haichao; Chen, Si; Shao, Hongyan; Li, Chao; Fan, Meiqiang; Chen, Da; Tian, Guanglei; Shu, Kangying

    2016-01-01

    Hierarchical NiCo2 S4 nanotube@NiCo2 S4 nanosheet arrays on Ni foam have been successfully synthesized. Owing to the unique hierarchical structure, enhanced capacitive performance can be attained. A specific capacitance up to 4.38 F cm(-2) is attained at 5 mA cm(-2) , which is much higher than the specific capacitance values of NiCo2 O4 nanosheet arrays, NiCo2 S4 nanosheet arrays and NiCo2 S4 nanotube arrays on Ni foam. The hierarchical NiCo2 S4 nanostructure shows superior cycling stability; after 5000 cycles, the specific capacitance still maintains 3.5 F cm(-2) . In addition, through the morphology and crystal structure measurement after cycling stability test, it is found that the NiCo2 S4 electroactive materials are gradually corroded; however, the NiCo2 S4 phase can still be well-maintained. Our results show that hierarchical NiCo2 S4 nanostructures are suitable electroactive materials for high performance supercapacitors. © 2016 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

  15. Radiation damage buildup and dislocation evolution in Ni and equiatomic multicomponent Ni-based alloys

    Science.gov (United States)

    Levo, E.; Granberg, F.; Fridlund, C.; Nordlund, K.; Djurabekova, F.

    2017-07-01

    Single-phase multicomponent alloys of equal atomic concentrations (;equiatomic;) have proven to exhibit promising mechanical and corrosion resistance properties, that are sought after in materials intended for use in hazardous environments like next-generation nuclear reactors. In this article, we investigate the damage production and dislocation mobility by simulating irradiation of elemental Ni and the alloys NiCo, NiCoCr, NiCoFe and NiFe, to assess the effect of elemental composition. We compare the defect production and the evolution of dislocation networks in the simulation cells of two different sizes, for all five studied materials. We find that the trends in defect evolution are in good agreement between the different cell sizes. The damage is generally reduced with increased alloy complexity, and the dislocation evolution is specific to each material, depending on its complexity. We show that increasing complexity of the alloys does not always lead to decreased susceptibility to damage accumulation under irradiation. We show that, for instance, the NiCo alloy behaves very similarly to Ni, while presence of Fe or Cr in the alloy even as a third component reduces the saturated level of damage substantially. Moreover, we linked the defect evolution with the dislocation transformations in the alloys. Sudden drops in defect number and large defect fluctuations from the continuous irradiation can be explained from the dislocation activity.

  16. Tipos especiales de niños

    Directory of Open Access Journals (Sweden)

    Mercedes Rodrigo Bellido

    1946-09-01

    Full Text Available En las tres últimas lecciones han sido expuestas algunas consideraciones referentes a niños y adolescentes desde el nacimiento hasta el dintel de la juventud. En todas ellas hemos procurado poner de relieve la necesidad de individualizar el conocimiento de cada niño para obtener mejores resultados en su adaptación a su futura vida de adultos, En todas ellas  nos hemos referido al llamado niño normal. Nos corresponde en la lección de hoy ocuparnos can la superficialidad característica de estas charlas tipo-muestrario, de otras categorías de niños muy dignos de interés.. quienes unas por exceso, otros por defecto, otros por dificultades de adaptación por diferentes causas, se desvían de la línea media de la normalidad. Consideramos que no está fuera del lugar, aquí, el tema de los niños excepcionales y por el contrario que es necesario intensificar el estudio de los trastornos de la vida mental y emocional de los niños en la preparación de los estudiantes de Medicina. Y no es nuestra solo esta opinión; no hace mucho tiempo en la Medical School de Ia Universidad de Minnessota hemos sabido que se ha hecho un intento de considerar y evaluar factores emocionales ambientales sobre las mismas bases que los descubrimientos fisiológicos.

  17. Ni Foam-Ni3 S2 @Ni(OH)2 -Graphene Sandwich Structure Electrode Materials: Facile Synthesis and High Supercapacitor Performance.

    Science.gov (United States)

    Wang, Xiaobing; Hu, Jiangjiang; Su, Yichang; Hao, Jin; Liu, Fanggang; Han, Shuang; An, Jian; Lian, Jianshe

    2017-03-23

    A novel Ni foam-Ni3 S2 @Ni(OH)2 -graphene sandwich-structured electrode (NF-NN-G) with high areal mass loading (8.33 mg cm(-2) ) has been developed by sulfidation and hydrolysis reactions. The conductivity of Ni3 S2 and Ni(OH)2 were both improved. The upper layer of Ni(OH)2 , covered with a thin graphene film, is formed in situ from the surface of the lower layer of Ni3 S2 , whereas the Ni3 S2 grown on Ni foam substrate mainly acts as a rough support bridging the Ni(OH)2 and Ni foam. The graphene stabilized the Ni(OH)2 and the electrochemical properties were effectively enhanced. The as-synthesized NF-NN-G-5mg electrode shows a high specific capacitance (2258 F g(-1) at 1 A g(-1) or 18.81 F cm(-2) at 8.33 mA cm(-2) ) and an outstanding rate property (1010 F g(-1) at 20 Ag(-1) or 8.413 F cm(-2) at 166.6 mA cm(-2) ). This result is around double the capacitance achieved in previous research on Ni3 S2 @Ni(OH)2 /3DGN composites (3DGN=three-dimensional graphene network). In addition, the as-fabricated NF-NN-G-5mg composite electrode has an excellent cycle life with no capacitance loss after 3000 cycles, indicating a potential application as an efficient electrode. © 2017 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim.

  18. NiTi Expansion in Operated Unilateral Cleft Palate Patients

    Directory of Open Access Journals (Sweden)

    K Y Poornima

    2011-01-01

    Conclusion : NiTi expansion in operated cleft patients, showed mainly orthodontic expansion. The significant change in the maxillary inter- molar region is due to the direct placement of NiTi palatal expander to 16, 26.

  19. Funciones cognoscitivas en niños y niñas con trastorno disocial comparados con niños y niñas sin el trastorno

    OpenAIRE

    Urazán Torres, Gina Rocio

    2011-01-01

    Este proyecto de investigación tuvo como objetivo evaluar y caracterizar las funciones cognoscitivas de un grupo de niños y niñas con Trastorno Disocial (TD), comparándolas con las de un grupo de niños y niñas normales. Se utilizó un diseño de casos y controles con una muestra de 39 niños y niñas entre 6 y 12 años de edad con TD y 39 niños y niñas del mismo rango de edades y los mismos estratos socioeconómicos. Los participantes fueron seleccionados de diferentes instituciones educativas de B...

  20. Enhancement of porous silicon photoluminescence using (Ni) treatment

    Science.gov (United States)

    Nabil, M.; Elnouby, M.; Gayeh, N.; Sakr, A. H.; Motaweh, H. A.

    2017-10-01

    A new method has been developed to improve the photoluminescence intensity of porous silicon (PS). Self-organized (PS) can be used in various fields. The deposition of metal nanoparticles (Ni) allows utilizing the obtained nano-composite for numerous applications such as sensor technology, biomedicine, and many more. (Ni/PS) nano-composite powders are prepared using Ni deposition on the PS powder surface. The (Ni/PS) powders became hydrophilic by the deposited Ni nanoparticles. At the different percentages of (Ni: PS), at a higher percentage than (3:1) the values of the crystallite size of Ni and PS are nearly equivalent which suggests the saturation case of PS surface by Ni particles. It also depends on the deposition time value. In this study, that is the commercialization of nanostructured materials, it is important that the manufacturing costs are appropriate and inexpensive for large scale production, in addition, the enhancement of the photoluminescence intensity of (PS).

  1. Hydrogenation of Ethyl Acetate to Ethanol over Ni-Based Catalysts Obtained from Ni/Al Hydrotalcite-Like Compounds

    Directory of Open Access Journals (Sweden)

    Longfei Jiang

    2010-07-01

    Full Text Available A series of Ni-based catalysts were prepared using hydrogen reduction of Ni/Al hydrotalcite-like compounds (Ni/Al HTlcs synthesized by coprecipitation. The physico-chemical properties of Ni/Al hydrotalcite-like compounds and the corresponding Ni-based catalysts were characterized using inductively coupled plasma (ICP, BET surface areas, X-ray diffraction (XRD, Fourier transform infrared (FTIR spectroscopy and scanning electron microscopy (SEM techniques. The results indicated that Ni/Al HTlcs with layered structures could be successfully prepared by the coprecipitation method, and the characteristic HTlcs reflections were also observed in the XRD analysis. The NiO and Ni0 phases were identified in all Ni-based catalysts, which displayed randomly interconnected pores and no layer structures. In addition, the studies also found the Ni/Al HTlcs and Ni-based catalysts had high specific surface areas, low pore volumes and low pore diameters. The catalytic hydrogenation of ethyl acetate to ethanol with Ni-based catalysts was also investigated. Among the studied catalysts, RE1NASH-110-3 showed the highest selectivity and yield of ethyl acetate to ethanol, which were 68.2% and 61.7%, respectively. At the same time, a major by-product, butyl acetate, was formed due to an ester-exchange reaction. A proposed hydrogenation pathway for ethyl acetate over Ni-based catalysts was suggested.

  2. Structural study of radiolytic catalysts Ni-Ce/Al2O3 and Ni-Pt/Al2O3

    Science.gov (United States)

    Seridi, F.; Chettibi, S.; Keghouche, N.; Beaunier, P.; Belloni, J.

    2017-01-01

    Ni-Ce and Ni-Pt bimetallic catalysts supported over α-Al2O3 are synthesized by using co-impregnation method, and then reduced, each via radiolytic process or thermal H2-treatment. For Ni-Ce/Al2O3, the structural study reveals that Ce is alloyed with Ni as Ce2Ni7 nanoparticles in the radiation-reduced catalysts, while it segregates to the surface in the form of CeO2 in the H2-reduced catalysts. For Ni-Pt/Al2O3 radiolytic catalysts, Ni, Pt, NiPt and Ni3Pt nanoparticles, which size is 3.5 nm, are observed. When the radiation-reduced samples are tested in the benzene hydrogenation, they both display high conversion rate. However, the Ni-Pt/Al2O3 is more efficient than Ni-Ce/Al2O3. The performance of the catalysts is correlated with the high dispersion of the metal and the presence of intermetallic Ni-Pt and Ni-Ce phases. It is compared to that of other radiolytic monometallic/oxide catalysts of the literature.

  3. Melting in the Fe-Ni system

    Science.gov (United States)

    Lord, O. T.; Walter, M. J.; Vocadlo, L.; Wood, I. G.; Dobson, D. P.

    2012-12-01

    The melting temperature of the Fe-rich core alloy at the inner core boundary (ICB) condition of 330 GPa is a key geophysical parameter because it represents an anchor point on the geotherm. An accurate knowledge of the melting curves of candidate alloys is therefore highly desirable. In spite of this, there is still considerable uncertainty in the melting point even of pure Fe at these conditions; estimates range from as low as 4850K based on one laser heated diamond anvil cell (LHDAC) study [1] to as high as 6900K based on recent quantum Monte Carlo calculations [2]. In reality we expect that the bulk core alloy may contain 5-10 wt% Ni (based on cosmochemical and meteoritic arguments) and up to 10 wt% of an as yet undetermined mix of light elements (with Si, S, C and O being the most likely candidates). While some recent studies have looked at the effects of light elements on the melting curve of Fe [e.g.: 3,4] with some of these studies including a small amount of Ni in their starting material, to date there has been no systematic study of melting temperatures in the Fe-Ni system. To address this issue, we have embarked upon just such a study. Using the LHDAC we have determined the melting curve of the pure Ni end-member to 180 GPa, and that of pure Fe to 50 GPa, using perturbations in the power vs. temperature function as the melting criterion [5]. Ar or NaCl were employed as pressure media while temperature was measured using standard spectroradiometric techniques [6]. In the case of Ni, perturbations were observed for both the sample and the Ar medium, allowing us to determine the melting curve of Ar and Ni simultaneously. Our results thus far for Ni and Ar agree closely with all of the available data, while extending the melting curves by a factor of two in pressure. In the case of Fe, our current dataset is also in good agreement with previous studies [2,7]. The agreement of all three melting curves with the literature data as well as other materials

  4. NiO Nanofibers as a Candidate for a Nanophotocathode

    Directory of Open Access Journals (Sweden)

    Thomas J. Macdonald

    2014-04-01

    Full Text Available p-type NiO nanofibers have been synthesized from a simple electrospinning and sintering procedure. For the first time, p-type nanofibers have been electrospun onto a conductive fluorine doped tin oxide (FTO surface. The properties of the NiO nanofibers have been directly compared to that of bulk NiO nanopowder. We have observed a p-type photocurrent for a NiO photocathode fabricated on an FTO substrate.

  5. Facile synthesis of monodisperse thermally immiscible Ag–Ni alloy ...

    Indian Academy of Sciences (India)

    Administrator

    to their synergistic effects. Using Ag–Ni ANPs, at the same time, is more economical than pure silver ANPs. According to the literature, metal-catalyst decoration can .... 1451. Figure 7. Schematic representation of the Ag–Ni ANP forma- tion. M stands for a metal element. Schematic representation of the Ag–Ni ANP formation.

  6. Fabrication of micro-Ni arrays by electroless and electrochemical ...

    Indian Academy of Sciences (India)

    Nickel micro-arrays were fabricated by electroless and electrochemical deposition in an etched porous aluminum membrane. The aluminum membrane with metal characteristic could be fabricated from high-purity aluminium by electrochemical method. The aluminum reduced Ni2+ into Ni and the formed Ni nuclei served as ...

  7. Optimization of process parameters for synthesis of silica–Ni ...

    Indian Academy of Sciences (India)

    The optimumcombination of experimental variable, temperature, time of heat treatment under nitrogen atmosphere and amount of Ni-salt was delineated to find out the maximum yield of nanophase Ni in the silica gel matrix. The size of Ni in the silica gel was found to be 34 and 45 nm for the two chosen compositions, ...

  8. Energetic Mapping of Ni Catalysts by Detailed Kinetic Modeling

    DEFF Research Database (Denmark)

    Bjørgum, Erlend; Chen, De; Bakken, Mari G.

    2005-01-01

    Temperature-programmed desorption (TPD) of CO has been performed on supported and unsupported nickel catalysts. The unsupported Ni catalyst consists of a Ni(14 13 13) single crystal which has been studied under ultrahigh vacuum conditions. The desorption energy for CO at low CO surface coverage w...... nicely with literature values, providing useful information for identifying active sites on supported Ni catalysts....

  9. New route for synthesis of electrocatalytic Ni (OH) 2 modified ...

    Indian Academy of Sciences (India)

    Immobilization of redox species like Ni(OH)2 onto the electrode surface is important in the application areas such as super capacitor, electrochromic displays and electrocatalysis. Nickel hexacyanoferrate (NiHCF) modified glassy carbon could be further derivatized with Ni(OH)2 by electrochemical cycling in alkali.

  10. Synthesis and characterization of Co–Ni and Fe–Ni alloy nanoparticles

    Energy Technology Data Exchange (ETDEWEB)

    Solanki, Vandana [Discipline of Natural Sciences, Indian Institute of Information Technology, Design & Manufacturing Jabalpur, Dumna Airport Road, Madhya Pradesh 482005 (India); Lebedev, Oleg I. [Laboratoire CRISMAT, ENSICAEN UMR6508, 6 Bd Maréchal Juin, Cedex 4, Caen 14050 (France); ITMO University, 49 Kronverksky Pr., St. Petersburg 197101 (Russian Federation); Seikh, Md. Motin [Department of Chemistry, Visva-Bharati University, Santiniketan, West Bengal 731235 (India); Mahato, Nihar K. [Discipline of Natural Sciences, Indian Institute of Information Technology, Design & Manufacturing Jabalpur, Dumna Airport Road, Madhya Pradesh 482005 (India); Raveau, Bernard [Laboratoire CRISMAT, ENSICAEN UMR6508, 6 Bd Maréchal Juin, Cedex 4, Caen 14050 (France); Kundu, Asish K., E-mail: asish.k@gmail.com [Discipline of Natural Sciences, Indian Institute of Information Technology, Design & Manufacturing Jabalpur, Dumna Airport Road, Madhya Pradesh 482005 (India)

    2016-12-15

    The magnetic alloy nanoparticles have been synthesized by sol-gel method with a stable Pm-3m cubic structure. The Co–Ni and Fe–Ni alloy nanoparticles are highly crystalline and exhibit preferential low index <111> faceting as determined from HRTEM investigation. TEM images and EDX elemental mapping also confirm the nano-dimensional structure with core-shell structure, where the alloy forms the core and the shell is formed by amorphous carbon. The magnetization results of the alloy nanoparticles confirm the ferromagnetic nature at room temperature akin to their bulk metals with a significant value of field dependent isothermal magnetization at high temperature (390 K). - Highlights: • Synthesis of Co–Ni and Fe–Ni alloy nanoparticles by exploiting low temperature sol–gel process. • The nanoparticles are core–shell type with core ferromagnetic alloys and graphitic carbon shell. • Electron microscope study explains the higher stability at ambient conditions of the nanoparticles.

  11. Thermal stability of electrodeposited Ni and Ni-Co layers; an EBSD-study

    DEFF Research Database (Denmark)

    Rasmussen, Anette Alsted; Gholinia, A.; Trimby, P.W.

    2004-01-01

    The influence of heat treatment on the microstructure and the microtexture of electrodeposited Ni and Ni-Co layers was investigated with Electron Backscatter Diffraction (EBSD) with high resolution. Samples were annealed for 1 hour at 523 K and 673 K, the temperature region wherein recrystallisat......The influence of heat treatment on the microstructure and the microtexture of electrodeposited Ni and Ni-Co layers was investigated with Electron Backscatter Diffraction (EBSD) with high resolution. Samples were annealed for 1 hour at 523 K and 673 K, the temperature region wherein...... recrystallisation occurs. The results are discussed in relation to the resolution of EBSD for the very fine grained electrodeposits and previous X-ray diffracton investigations....

  12. Modelling of rechargeable NiMH batteries

    NARCIS (Netherlands)

    Ledovskikh, A.; Verbitskiy, E.; Ayeb, A.; Notten, P.H.L.

    2003-01-01

    A new mathematical model has been developed for rechargeable NiMH batteries, which is based on the occurring physical–chemical processes inside. This model enables one to simultaneously simulate the battery voltage, internal gas pressures (both PO2 and PH2) and temperature during battery operation.

  13. Ni (II) decorated nano silicoaluminophosphate molecular sieves ...

    Indian Academy of Sciences (India)

    Ni(II) decorated nano silicoaluminophosphate molecular sieves-modified carbon paste electrode as an electrocatalyst for electrooxidation of methanol ... of Science, Babol University of Technology, Babol 47148-71167, Iran; Biofuel & Renewable Energy Research Center, Faculty of Chemical Engineering, Babol University ...

  14. Cancer en los niños

    OpenAIRE

    Pereira, Fabio; Ramírez Wurttenberger, Óscar; Lotero, Viviana; Fundación Valle de Lili

    2004-01-01

    Epidemiología/ ¿Por qué se presenta el cáncer en los niños?/ ¿Cómo se realiza el diagnóstico?/ ¿Cómo es el tratamiento?/ ¿Resultados del tratamiento?/Recomendaciones/Otras formas de tratamiento: El trasplante de médula ósea.

  15. (ii) and ni (ii) complexes with n

    African Journals Online (AJOL)

    DR. AMINU

    II) complexes with a. Schiff base derived from. 4-dimetylamino benzaldehyde and primary amines. The chemical analysis data showed the formation of (1:1) metal - ligand ratio and a square planar geometry was suggested for Co(II) and Ni(II) ...

  16. Dissociative chemisorption of methane on Ni(111)

    NARCIS (Netherlands)

    Krishna Mohan, Gangadharan Prasanna

    2010-01-01

    In this thesis we attempt to understand several aspects of the gas-surface physics/chemistry of (a) the dissociative chemisorption of CH4 on the Ni(111) surface and (b) N2 dissociation over the Ru(0001) surface. Apart from their industrial importance, these systems are regarded as prototypes for

  17. Preparing of Ni-Cu-P Coating

    Science.gov (United States)

    Shumei, Kang

    Ni-Cu-P coating by chemical plating has excellent corrosion resistance,wear resistance, thermal stability and electrical conductivity. In this paper, Ni-Cu-P was prepared by chemical deposition methods, the optimum process of chemical plating Ni-Cu-P. By using scanning electron microscopy(SEM), spectrum analyzer, Autolab workstation on the corrosion resistance of the coating. The results showed that: (1)after the specimen surface chemical plating nickelcopper phosphorus treatment, in the same corrosion potential, the corrosion current density was lower than that of Ni-P coating and substrate materials; (2)had a significant effect on corrosion resistance of quantity of citric acid sodium on nickel copper phosphorus alloy plating, coating corrosion resistance with increasing citric acid sodium content first increased and then decreased, and inaddition level of sodium citrate is 40g/L, the corrosion current density reaches a minimum, 14.51×10-6A/cm2; (3)under the same conditions, the Ni-Cu-P alloy coating pH impact is the biggest,the maximum impedance 1268.05Ω; (4)in the 3.5%NaCl solution, with the change of copper content, the main trend of the corrosion current is decreased first and then increased, and the content of copper in Energy spectrum analysis within 5.18Wt% corrosion current density of a minimum of 14.51×10-6A/cm2, the corrosion resistance. With the increase of Cu content in the coatings, the P content first increased and then decreased in the coating, the content of Ni decreased first and then increased; (5)the best technology:NiSO46H2O, CuSO4 25g/L, 5H2O 0.15g/L, C6H5Na3O7•2H2O 40g/L, NaH2PO2H2O 25g/L, CH3COONa 15g/L, KIO3 0.03g/L, C12H25NaO4SO3 0.01g/L, pH4.75 ± 0.01,temperature 80 ± 1 °C, deposition time of 2h.

  18. Elastic scattering of sup 58 Ni+ sup 64 Ni near the Coulomb barrier

    Energy Technology Data Exchange (ETDEWEB)

    Stefanini, A.M.; Xu Jincheng; Corradi, L.; Montagnoli, G.; Moreno, H.; Nagashima, Y.; Mueller, L.; Narayanasamy, M.; Napoli, D.R.; Spolaore, P. (Istituto Nazionale di Fisica Nucleare, Padua (Italy). Lab. di Legnaro); Beghini, S.; Scarlassara, F.; Segato, G.F.; Soramel, F. (Padua Univ. (Italy). Dipt. di Fisica Istituto Nazionale di Fisica Nucleare, Padua (Italy)); Signorini, C. (Salerno Univ. (Italy). Dipt. di Fisica Istituto Nazionale di Fisica Nucleare, Padua (Italy)); Esbensen, H.; Landowne, S. (Argonne National Lab., IL (USA). Physics Div.); Pollarolo, G. (Turin Univ. (Italy). Dipt. di Fisica Istituto Nazionale di Fisica Nucleare, Turin (Italy))

    1990-04-26

    Elastic scattering angular distributions have been measured for {sup 58}Ni+{sup 64}Ni at three energies around the Coulomb barrier employing a new kinematic coincidence technique. The data are compared with the results of coupled-channels calculations including inelastic excitations as well as one- and two-neutron transfer reactions. The agreement is good and the calculations also agree well with the available transfer and fusion reaction data. (orig.).

  19. Geometric structures of thin film: Pt on Pd(110) and NiO on Ni(100)

    Energy Technology Data Exchange (ETDEWEB)

    Warren, Oden L. [Iowa State Univ., Ames, IA (United States)

    1993-07-01

    This thesis is divided into 3 papers: dynamical low-energy electron- diffraction investigation of lateral displacements in topmost layer of Pd(110); determination of (1x1) and (1x2) structures of Pt thin films on Pd(110) by dynamical low-energy electron-diffraction analysis; and structural determination of a NiO(111) film on Ni(100) by dynamical low-energy electron-diffraction analysis.

  20. Effect of deposition technique of Ni on the perpendicular magnetic anisotropy in Co/Ni multilayers

    Energy Technology Data Exchange (ETDEWEB)

    Akbulut, S., E-mail: sakbulut@gtu.edu.tr [Gebze Technical University, Physics Department, Istanbul Cad, PK 41400 Gebze/Kocaeli (Turkey); Akbulut, A. [Gebze Technical University, Physics Department, Istanbul Cad, PK 41400 Gebze/Kocaeli (Turkey); Özdemir, M. [Marmara University, Physics Department, Göztepe, Istanbul (Turkey); Yildiz, F., E-mail: fyildiz@gtu.edu.tr [Gebze Technical University, Physics Department, Istanbul Cad, PK 41400 Gebze/Kocaeli (Turkey)

    2015-09-15

    The perpendicular magnetic anisotropy (PMA) of Si/Pt 3.5/(Co 0.3/Ni 0.6){sub n} /Co 0.3/ Pt 3 (all thicknesses are nm) multilayers were investigated for two different sample sets by using ferromagnetic resonance (FMR) and magnetooptic Kerr effect (MOKE) techniques. In the first sample set all layers (buffer, cap, Co and Ni) were grown by magnetron sputtering technique while in the second sample set Ni sub-layers were grown by molecular beam epitaxy (MBE) at high vacuum. Apart from deposition technique of Ni, all other parameters like thicknesses and growth rates of each layers are same for both sample sets. Multilayers in these two sample sets display PMA in the as grown state until a certain value of bilayer repetition (n) and the strength of PMA decreases with increasing n. Magnetic easy axis's of the multilayered samples switched from film normal to the film plane when n is 9 and 5 for the first and second sample sets, respectively. The reason for that, PMA was decreased due to increasing roughness with increasing n. This was confirmed by X Ray Reflectivity (XRR) measurements for both sample sets. Moreover, in the first sample set coercive field values are smaller than the second sample set, which means magnetic anisotropy is lower than the latter one. This stronger PMA is arising due to existence of stronger Pt (111) and Co/Ni (111) textures in the second sample set. - Highlights: • Effect of deposition techniques for Ni sub-layers on magnetic properties in [Co/Ni]{sub n} multilayered films was studied. • Ni sub-layers were deposited by two different techniques, molecular beam epitaxy (MBE) and magnetron sputtering. • Spin reorientation thickness and magnitude of the anisotropy are strongly depending on growing techniques.

  1. Epitaxial NiWO4 films on Ni(110): Experimental and theoretical study of surface stability

    Science.gov (United States)

    Doudin, N.; Pomp, S.; Blatnik, M.; Resel, R.; Vorokhta, M.; Goniakowski, J.; Noguera, C.; Netzer, F. P.; Surnev, S.

    2017-05-01

    Despite the application potential of nickel tungstate (NiWO4) in heterogeneous catalysis, humidity and gas sensing, etc, its surfaces have essentially remained unexplored. In this work, NiWO4 nanoparticles and films with the wolframite structure have been grown via a solid-state reaction of (WO3)3 clusters and a NiO(100) film on a Ni(110) crystal surface and characterized by a variety of experimental techniques, including x-ray photoelectron spectroscopy (XPS), scanning tunneling microscopy (STM) and x-ray diffraction (XRD), combined with ab-initio density functional theory (DFT) calculations. NiWO4 grows initially as three-dimensional (3D) crystalline nanoparticles displaying mainly two crystalline facets vicinal to the (100) surface, which merge with increasing the (WO3)3 coverage into a quasi-continuous epitaxial film. The DFT results provide an account of the energetics of NiWO4 low index surfaces and highlight the role of faceting in the stabilization of extended polar (100) terraces. These combined experimental and theoretical results show that interaction with a metal substrate and vertical confinement may stabilize oxide nano-objects with high energy facets, able to enhance their reactivity.

  2. Weldability of spheroidal graphite ductile cast iron using Ni / Ni-Fe electrodes

    Directory of Open Access Journals (Sweden)

    Pascual, M.

    2009-10-01

    Full Text Available Weldability of spheroidal graphite ductile cast iron was established using a cheap Ni-Fe and a high purity Ni electrode. A preheating treatment at 350 °C and an annealing treatment at 850 °C were carried out to improve mechanical properties of welded pieces. The pure Ni electrode showed graphite diffusion in the bead with a uniform distribution of phases, improving weldability and decreasing fragility. Preheating and annealing treatments increased ductility and improved weldability.

    Se establece la soldabilidad de funciones dúctiles de grafito según las características mecánicas alcanzadas, utilizando un electrodo puro de Ni mientras se compara con uno más económico de Ni-Fe. Diferentes tratamientos t��rmicos son propuestos y analizados. El electrodo de Ni puro mostró difusión de grafito desde el material original al cordón de soldadura, dando como resultado una fase homogénea que mejoró la soldabilidad y redujo la fragilidad. Un pre tratamiento a 350 °C y un recocido a 850 °C incrementaron la ductilidad y mejoró la soldabilidad.

  3. Cold Spray Deposition of Ni and WC-Reinforced Ni Matrix Composite Coatings

    Science.gov (United States)

    Alidokht, S. A.; Vo, P.; Yue, S.; Chromik, R. R.

    2017-09-01

    Ni-WC composites are ideal protective coatings against wear and are often fabricated using laser cladding and thermal spray processes, but the high temperatures of these processes result in decarburization, which deteriorates the performance of the coating. Cold spray has the potential to deposit Ni-WC composite coatings and retain the composition of the initial WC feedstock. However, the insignificant plastic deformation of hard WC particles makes it difficult to build up a high WC content coating by cold spray. By using three different WC powder sizes, the effect of feedstock powder size on WC retention was tested. To improve WC retention, a WC/Ni composite powder in mixture with Ni was also sprayed. Microstructural characterization, including the deformed structure of Ni splats, retention, distribution, and fragmentation of WC, was performed by scanning electron microscopy. An improvement in WC retention was achieved using finer WC particles. Significant improvement in WC particles retention was achieved using WC/Ni composite powder, with the WC content in the coating being close to that of the feedstock.

  4. Interfacial reaction of Ni{sub 3}Sn{sub 4} intermetallic compound in Ni/SnAg solder/Ni system under thermomigration

    Energy Technology Data Exchange (ETDEWEB)

    Yang, Yi-Shan; Yang, Chia-Jung; Ouyang, Fan-Yi, E-mail: fyouyang@ess.nthu.edu.tw

    2016-07-25

    The growth of Ni{sub 3}Sn{sub 4} intermetallic compound (IMC) between liquid–solid interface in micro-scale Ni/SnAg/Ni system was investigated under a temperature gradient of 160 °C/cm at 260 °C on a hot plate. In contrast to a symmetrical growth of Ni{sub 3}Sn{sub 4} on both interfaces under isothermally annealed at 260 °C, the interfacial Ni{sub 3}Sn{sub 4} IMC exhibited asymmetric growth under a temperature gradient; the growth of Ni{sub 3}Sn{sub 4} at cold interface was faster than that at hot side because of temperature gradient induced mass migration of Ni atoms from the hot end toward the cold end. It was found that two-stage growth behavior of Ni{sub 3}Sn{sub 4} IMC under a temperature gradient. A growth model was established and growth kinetic analysis suggested that the chemical potential gradient controlled the growth of Ni{sub 3}Sn{sub 4} at stage I (0–120 min) whereas the dynamic equilibrium between chemical potential gradient and temperature gradient forces was attained at the hot end at stage II (120–210 min). When dynamic equilibrium was achieved at 260 °C, the critical length-temperature gradient product at the hot end was experimentally estimated to be 489.18 μm × °C/cm and the moving velocity of Ni{sub 3}Sn{sub 4} interface due to Ni consumption was calculated to be 0.134 μm/h. The molar heat of transport (Q*) of Ni atoms in molten SnAg solder was calculated to be +0.76 kJ/mol. - Highlights: • Interfacial reaction in Ni/SnAg solder/Ni system under thermal gradient. • Growth rate of Ni{sub 3}Sn{sub 4} at cold end is faster than that at hot end. • Critical length-temperature gradient product at hot end is 489.2 μm°C/cm at 260 °C. • Velocity of Ni{sub 3}Sn{sub 4} moving interface is 0.134 μm/h during dynamic equilibrium. • Molar heat of transport (Q*) of Ni in molten SnAg was +0.76 kJ/mol.

  5. Microstructure, Mechanical Property, and Phase Transformation of Quaternary NiTiFeNb and NiTiFeTa Shape Memory Alloys

    National Research Council Canada - National Science Library

    Yulong Liang; Shuyong Jiang; Yanqiu Zhang; Junbo Yu

    2017-01-01

    Based on ternary Ni45Ti51.8Fe3.2 (at %) shape memory alloy (SMA), Nb and Ta elements are added to an NiTiFe SMA by replacing Ni element, and consequently quaternary Ni44Ti51.8Fe3.2Nb1 and Ni44Ti51.8Fe3.2Ta1...

  6. Evaluation of the Antitumor Activity by Ni Nanoparticles with Verbascoside

    Directory of Open Access Journals (Sweden)

    Mingyue Chen

    2013-01-01

    Full Text Available Verbascoside (VB has attracted a great deal of attention due to ITS pharmacological properties. In our study, we synthesized a multifunctional verbascoside coated Ni nanoparticles (VB-Ni. Transmission electron microscopy (TEM and high performance liquid chromatography (HPLC display the characteristics of VB-Ni nanoparticles. Compared with VB, VB-Ni has been proven to induce apoptosis and resist the growth of doxorubicin-resistant K562 cells in vitro and in vivo. Thus, VB-Ni nanoparticles can be thought of as an ideal mode of cancer treatment.

  7. Atomistic modeling of ternary additions to NiTi and quaternary additions to Ni-Ti-Pd, Ni-Ti-Pt and Ni-Ti-Hf shape memory alloys

    Energy Technology Data Exchange (ETDEWEB)

    Mosca, H.O., E-mail: hmosca@cnea.gov.ar [Gcia. Investigacion y Aplicaciones, CNEA, Av. Gral Paz 1499, B1650KNA San Martin (Argentina); GCMM, UTN, FRG Pacheco, Av. H. Yrigoyen 288, Gral. Pacheco (Argentina); Bozzolo, G. [Loyola University Maryland, 4501 N. Charles St., Baltimore, MD 21210 (United States); Grosso, M.F. del [Gcia. Investigacion y Aplicaciones, CNEA, Av. Gral Paz 1499, B1650KNA San Martin (Argentina); GCMM, UTN, FRG Pacheco, Av. H. Yrigoyen 288, Gral. Pacheco (Argentina); Consejo Nacional de Investigaciones Cientificas y Tecnicas, CONICET (Argentina)

    2012-08-15

    The behavior of ternary and quaternary additions to NiTi shape memory alloys is investigated using a quantum approximate method for the energetics. Ternary additions X to NiTi and quaternary additions to Ni-Ti-Pd, Ni-Ti-Pt, and Ni-Ti-Hf alloys, for X=Au, Pt, Ir, Os, Re, W, Ta,Ag, Pd, Rh, Ru, Tc, Mo, Nb, Zr, Zn, Cu, Co, Fe, Mn, V, Sc, Si, Al and Mg are considered. Bulk properties such as lattice parameter, energy of formation, and bulk modulus of the B2 alloys are studied for variations due to the presence of one or two simultaneous additives.

  8. Nanoporous PdNi/C electrocatalyst prepared by dealloying high-Ni-content PdNi alloy for formic acid oxidation

    Energy Technology Data Exchange (ETDEWEB)

    Wang, Wei; Wang, Hui; Wang, Rongfang [Key Laboratory of Eco-Environment-Related Polymer Materials, Ministry of Education of China, Key Laboratory of Gansu Polymer Materials, College of Chemistry and Chemical Engineering, Northwest Normal University, Lanzhou 730070 (China); Ji, Shan [South African Institute for Advanced Materials Chemistry, University of the Western Cape, Cape Town 7535 (South Africa)

    2012-12-15

    To improve the electrochemical performance of Pd-based catalysts for formic acid oxidation, a carbon supported nanoporous PdNi catalyst is prepared by dealloying high-Ni-content PdNi alloy nanoparticles in acid solution. The structure of nanoporous PdNi/C catalyst is characterized by X-ray diffraction, transmission electron microscopy and X-ray photoelectron spectroscopy. The electrocatalytic results show that the activity of the nanoporous PdNi/C catalyst is higher than that of nonporous Pd/C catalyst. The results demonstrate that the carbon-supported nanoporous PdNi catalyst has a potential for application in direct formic acid fuel cells. (Copyright copyright 2012 WILEY-VCH Verlag GmbH and Co. KGaA, Weinheim)

  9. State of Supported Nanoparticle Ni during Catalysis in Aqueous Media

    Energy Technology Data Exchange (ETDEWEB)

    Chase, Zizwe; Vjunov, Aleksei; Fulton, John; Camaioni, Donald; Balasubramanian, Mahalingam; Lercher, Johannes

    2015-11-09

    The state of Ni supported on HZSM-5 zeolite, silica, and sulfonated carbon was studied during aqueous-phase catalysis of phenol hydrodeoxygenation using in situ extended X-ray absorption fine structure spectroscopy. On sulfonated carbon and HZSM-5 supports, NiO and Ni(OH)(2) were readily reduced to Ni-0 under reaction conditions (approximate to 35bar H-2 in aqueous phenol solutions containing up to 0.5wt.% phosphoric acid at 473K). In contrast, Ni supported on SiO2 was not stable in a fully reduced Ni-0 state. Water enables the formation of Ni-II phyllosilicate, which is more stable, that is, difficult to reduce, than either -Ni(OH)(2) or NiO. Leaching of Ni from the supports was not observed over a broad range of reaction conditions. Ni-0 particles on HZSM-5 were stable even in presence of 15wt.% acetic acid at 473K and 35bar H-2.

  10. Intra-specific variation in Ni tolerance, accumulation and translocation patterns in the Ni-hyperaccumulator Alyssum lesbiacum.

    Science.gov (United States)

    Adamidis, G C; Aloupi, M; Kazakou, E; Dimitrakopoulos, P G

    2014-01-01

    A hydroponic experiment was conducted to investigate inter-population variation in Ni tolerance, accumulation and translocation patterns in Alyssum lesbiacum. The in vitro results were compared to field data (soil bioavailable and leaf Ni concentrations) so as to examine any potential relationship between hydroponic and natural conditions. Seeds from the four major existing populations of A. lesbiacum were used for the cultivation of plantlets in solution cultures with incrementally increasing Ni concentrations (ranging from 0 to 250 μmol L(-1) NiSO4). Ni accumulation and tolerance of shoots and roots, along with initial seed Ni concentration for each population were measured. The ratio of root or shoot length of plantlets grown in NiSO4 solutions to root or shoot lengths of plantlets grown in the control solution was used as tolerance index. For the range of metal concentrations used, A. lesbiacum presented significant inter-population variation in Ni tolerance, accumulation and translocation patterns. Initial seed Ni concentration was positively correlated to shoot Ni accumulation. A significant positive relationship between tolerance and accumulation was demonstrated. Initial seed Ni concentration along with physiological differences in xylem loading and Ni translocation of each population, appear to be the determining factors of the significant inter-population variation in Ni tolerance and accumulation. Our results highlight the inter-population variation in Ni tolerance and accumulation patterns in the Ni-hyperaccumulator A. lesbiacum and give support to the suggestion that the selection of metal hyperaccumulator species with enhanced phytoremediation efficiency should be considered at the population level. Copyright © 2013 Elsevier Ltd. All rights reserved.

  11. NiCo2S4 nanosheet-decorated 3D, porous Ni film@Ni wire electrode materials for all solid-state asymmetric supercapacitor applications.

    Science.gov (United States)

    Saravanakumar, Balasubramaniam; Jayaseelan, Santhana Sivabalan; Seo, Min-Kang; Kim, Hak-Yong; Kim, Byoung-Suhk

    2017-12-07

    Wire type supercapacitors with high energy and power densities have generated considerable interest in wearable applications. Herein, we report a novel NiCo2S4-decorated 3D, porous Ni film@Ni wire electrode for high performance supercapacitor application. In this work, a facile method is introduced to fabricate a 3D, porous Ni film deposited on a Ni wire as a flexible electrode, followed by decoration with NiCo2S4 as an electroactive material. The fabricated NiCo2S4-decorated 3D, porous Ni film@Ni wire electrode displays a superior performance with an areal and volumetric capacitance of 1.228 F cm-2 and 199.74 F cm-3, respectively, at a current density of 0.2 mA cm-1 with a maximum volumetric energy and power density (EV: 6.935 mW h cm-3; PV: 1.019 W cm-3). Finally, the solid state asymmetric wire type supercapacitor is fabricated using the fabricated NiCo2S4-decorated 3D, porous Ni film@Ni wire as a positive electrode and N-doped reduced graphene oxide (N-rGO) as a negative electrode and this exhibits good areal and volumetric capacitances of CA: 0.12 F cm-2 and CV: 19.57 F cm-2 with a higher rate capability (92%). This asymmetric wire type supercapacitor demonstrates a low leakage current and self-discharge with a maximum volumetric energy (EV: 5.33 mW h cm-3) and power (PV: 855.69 mW cm-3) density.

  12. Martensitic Transformation in Ni-Mn-Sn-Co Heusler Alloys

    Directory of Open Access Journals (Sweden)

    Alexandre Deltell

    2015-04-01

    Full Text Available Thermal and structural austenite to martensite reversible transition was studied in melt spun ribbons of Ni50Mn40Sn5Co5, Ni50Mn37.5Sn7.5Co5 and Ni50Mn35Sn10Co5 (at. % alloys. Analysis of X-ray diffraction patterns confirms that all alloys have martensitic structure at room temperature: four layered orthorhombic 4O for Ni50Mn40Sn5Co5, four layered orthorhombic 4O and seven-layered monoclinic 14M for Ni50Mn37.5Sn7.5Co5 and seven-layered monoclinic 14M for Ni50Mn35Sn5Co5. Analysis of differential scanning calorimetry scans shows that higher enthalpy and entropy changes are obtained for alloy Ni50Mn37.5Sn7.5Co5, whereas transition temperatures increases as increasing valence electron density.

  13. Structural and magnetic properties of Ni-Zn and Ni-Zn-Co ferrites

    Energy Technology Data Exchange (ETDEWEB)

    Knyazev, A.V., E-mail: knyazevav@gmail.com [N.I. Lobachevsky State University of Nizhni Novgorod, Gagarin Prospekt 23/2, 603950 Nizhni Novgorod (Russian Federation); Zakharchuk, I.; Lähderanta, E. [Lappeenranta University of Technology, P.O. Box 20, FI-53851 Lappeenranta (Finland); Baidakov, K.V.; Knyazeva, S.S. [N.I. Lobachevsky State University of Nizhni Novgorod, Gagarin Prospekt 23/2, 603950 Nizhni Novgorod (Russian Federation); Ladenkov, I.V. [Joint-stock Company “Research and Production Company “Salut”, Nizhni Novgorod (Russian Federation)

    2017-08-01

    Highlights: • Ni-Zn and Ni-Zn-Co ferrite powders were prepared by the solid-state reaction at 1073 K. • The room temperature saturation magnetizations are 59.7 emu/g for Ni{sub 0.5}Zn{sub 0.5}Fe{sub 2}O{sub 4} and 57.1 emu/g for Ni{sub 0.5}Zn{sub 0.3}Co{sub 0.2}Fe{sub 2}O{sub 4}. • The coercivity of the samples is found to be much larger than that of bulk ferrites and increases with Co introduction. • The temperature dependences of magnetization exhibit large spin frustration and spin-glass-like behavior. - Abstract: Ni-Zn and Ni-Zn-Co ferrite powders with nominal compositions Ni{sub 0.5}Zn{sub 0.5}Fe{sub 2}O{sub 4} and Ni{sub 0.5}Zn{sub 0.3}Co{sub 0.2}Fe{sub 2}O{sub 4} were prepared by the solid-state reaction synthesis with periodic regrinding during the calcination at 1073 K. The structure of Ni{sub 0.5}Zn{sub 0.5}Fe{sub 2}O{sub 4} and Ni{sub 0.5}Zn{sub 0.3}Co{sub 0.2}Fe{sub 2}O{sub 4} was refined assuming space group F d-3m. Scanning electron microscopy revealed the average sizes of the crystalline ferrite particles are 130–630 nm for Ni{sub 0.5}Zn{sub 0.5}Fe{sub 2}O{sub 4} and 140–350 nm for Ni{sub 0.5}Zn{sub 0.3}Co{sub 0.2}Fe{sub 2}O{sub 4}. The room temperature saturation magnetizations are 59.7 emu/g for Ni{sub 0.5}Zn{sub 0.5}Fe{sub 2}O{sub 4} and 57.1 emu/g for Ni{sub 0.5}Zn{sub 0.3}Co{sub 0.2}Fe{sub 2}O{sub 4}. The coercivity of the samples is found to be much larger than that of bulk ferrites and increases with Co introduction. The Curie temperature tends to increase upon Zn substitution by Co, as well. The temperature dependences of magnetization measured using zero-field cooled and field cooled protocols exhibit large spin frustration and spin-glass-like behavior.

  14. Peculiarities of thermoelectric half-Heusler phase formation in Gd-Ni-Sb and Lu-Ni-Sb ternary systems

    Energy Technology Data Exchange (ETDEWEB)

    Romaka, V.V., E-mail: romakav@lp.edu.ua [Department of Applied Material Science and Materials Engineering, Lviv Polytechnic National University, Ustyyanovycha Str. 5, 79013 Lviv (Ukraine); Romaka, L.; Horyn, A. [Inorganic Chemistry Department, Ivan Franko Lviv National University, Kyryla and Mefodiya str. 6, 79005 Lviv (Ukraine); Rogl, P. [Institute of Materials Chemistry and Research, University of Vienna, Währingerstrasse 42, A-1090 Wien (Austria); Stadnyk, Yu; Melnychenko, N. [Inorganic Chemistry Department, Ivan Franko Lviv National University, Kyryla and Mefodiya str. 6, 79005 Lviv (Ukraine); Orlovskyy, M.; Krayovskyy, V. [Department of Applied Material Science and Materials Engineering, Lviv Polytechnic National University, Ustyyanovycha Str. 5, 79013 Lviv (Ukraine)

    2016-07-15

    The phase equilibria in the Gd–Ni–Sb and Lu-Ni-Sb ternary systems were studied at 873 K by X-ray and metallographic analyses in the whole concentration range. The interaction of the elements in the Gd–Ni–Sb system results the formation of five ternary compounds at investigated temperature: Gd{sub 5}Ni{sub 2}Sb (Mo{sub 5}SiB{sub 2}-type), Gd{sub 5}NiSb{sub 2} (Yb{sub 5}Sb{sub 3}-type), GdNiSb (MgAgAs-type), Gd{sub 3}Ni{sub 6}Sb{sub 5} (Y{sub 3}Ni{sub 6}Sb{sub 5}-type), and GdNi{sub 0.72}Sb{sub 2} (HfCuSi{sub 2}-type). At investigated temperature the Lu-Ni-Sb system is characterized by formation of the LuNiSb (MgAgAs-type), Lu{sub 5}Ni{sub 2}Sb (Mo{sub 5}SiB{sub 2}-type), and Lu{sub 5}Ni{sub 0.56}Sb{sub 2.44} (Yb{sub 5}Sb{sub 3}-type) compounds. The disordering in the crystal structure of half-Heusler GdNiSb and LuNiSb was revealed by EPMA and studied by means of Rietveld refinement and DFT modeling. The performed electronic structure calculations are in good agreement with electrical transport property studies. - Graphical abstract: Crystal structure model and electron localization function of Lu{sub 5}Ni{sub 2}Sb. Display Omitted - Highlights: • Gd-Ni-Sb and Lu-Ni-Sb phase diagrams were constructed at 873 K. • GdNiSb and LuNiSb are characterized by disordered crystal structure. • Crystal structure optimization with DFT calculations confirmed crystal structure disorder in GdNiSb and LuNiSb.

  15. Structural characterization of Ni and Ni/Ti ohmic contact on n-type 4H-SiC

    Energy Technology Data Exchange (ETDEWEB)

    Siad, M., E-mail: siadmenouar@yahoo.fr [Centre de Recherche Nucleaire d' Alger, 02 Bd Frantz Fanon (Algeria); Abdesselam, M. [USTHB, Faculte de Physique, BP 32, El Alia, Bab Ezzouar (Algeria); Souami, N. [Centre de Recherche Nucleaire d' Alger, 02 Bd Frantz Fanon (Algeria); Chami, A.C. [USTHB, Faculte de Physique, BP 32, El Alia, Bab Ezzouar (Algeria)

    2011-10-01

    In this study, we report on the structural characterization of Ni layer and Ni/Ti bilayer contacts on n-type 4H-SiC. The resulting Ni-silicides and the redistribution of carbon, after annealing at 950 deg. C, in the Ni/SiC and the Ni/Ti/SiC contacts are particularly studied by Rutherford Backscattering Spectrometry (RBS) at E{sub {alpha}} = 3.2 MeV, nuclear reaction analysis (NRA) at E{sub d} = 1 MeV, scanning electron microscopy (SEM) and Energy Dispersive X-ray Spectrometry (EDS) techniques.

  16. Evaluation of structure and mechanical properties of Ni-rich NiTi/Kapton composite film

    Energy Technology Data Exchange (ETDEWEB)

    Mohri, Maryam [Institute of Nanotechnology (INT), Karlsruhe Institute of Technology (KIT), Karlsruhe (Germany); School of Metallurgy and Materials Engineering, College of Engineering, University of Tehran, Tehran (Iran, Islamic Republic of); Nili-Ahmadabadi, Mahmoud [School of Metallurgy and Materials Engineering, College of Engineering, University of Tehran, Tehran (Iran, Islamic Republic of); PouryazdanPanah, Mohsen; Hahn, Horst [Institute of Nanotechnology (INT), Karlsruhe Institute of Technology (KIT), Karlsruhe (Germany); Joint Research Labaratory Nanomaterials, Technische Universität Darmstadt, Darmstadt (Germany)

    2016-06-21

    NiTi thin films are usually sputtered on silicon wafers by magnetron sputtering. But the systems composed of thin film on flexible polymeric substrate are used in many applications such as micro electro-mechanical systems (MEMS). Investigation on mechanical properties of thin films has attracted much attention due to their widespread applications. In this paper, the mechanical properties of 1 µm-thick crystallized Ni-49.2 at%Ti thin film alloy deposited by DC magnetron sputtering on Kapton substrate are investigated by using tensile test. The as-deposited thin films are in amorphous state, then for crystallization, the thin film was annealed at 450 °C for 30 min. Formation of the austenite phase after annealing was confirmed by X-ray diffractometry (XRD) and differential scanning calorimetry (DSC). The surface morphology of as deposited and crystallized thin films were examined by scanning electron microscopy (SEM). Stress-strain curves of the NiTi alloy thin film were obtained by subtracting of the stress-strain Kapton curves from the corresponding curves of the NiTi/Kapton composite. The XRD results revealed that the NiTi thin film deposited on the Kapton is austenitic and presents super-elastic effect at room temperature. This pseudo elastic effect leads to more recoverable strain in NiTi/Kapton composite film compared with Kapton foils on loading/unloading test. Furthermore, it was concluded that nanostructure of the NiTi thin film is responsible for remarkable improvement of ultimate tensile strength (1.4 GPa) at a strain of 30% compared with the bulk material.

  17. Mechanical alloying of Ni{sub 3}Fe in the presence of Ni{sub 3}Fe nanocrystalline germs

    Energy Technology Data Exchange (ETDEWEB)

    Sparchez, Z. [Materials Sciences and Technology Department, Technical University of Cluj-Napoca, 103-105 Muncii Avenue, 400641 Cluj-Napoca (Romania); Chicinas, I. [Materials Sciences and Technology Department, Technical University of Cluj-Napoca, 103-105 Muncii Avenue, 400641 Cluj-Napoca (Romania) and Laboratoire de Cristallographie, CNRS, associe a l' Universite J. Fourier, BP 166, F-38042 Grenoble Cedex 9 (France)]. E-mail: Ionel.Chicinas@stm.utcluj.ro; Isnard, O. [Laboratoire de Cristallographie, CNRS, associe a l' Universite J. Fourier, BP 166, F-38042 Grenoble Cedex 9 (France); Pop, V. [Faculty of Physics, Babes-Bolyai University, 400084 Cluj-Napoca (Romania); Popa, F. [Materials Sciences and Technology Department, Technical University of Cluj-Napoca, 103-105 Muncii Avenue, 400641 Cluj-Napoca (Romania); Laboratoire de Cristallographie, CNRS, associe a l' Universite J. Fourier, BP 166, F-38042 Grenoble Cedex 9 (France)

    2007-05-31

    The influence of nanocrystalline germs on the production of the Ni{sub 3}Fe intermetallic compound by mechanical alloying is reported. These germs consist in Ni{sub 3}Fe nanocrystalline particles previously obtained by mechanical alloying which have been added to the Ni-Fe mixture: 0.8(3Ni + Fe) + 0.2Ni{sub 3}Fe = Ni{sub 3}Fe. The powder mixture was milled in a planetary mill in argon atmosphere. Several milling times have been used ranging from 2 to 8 h. A Ni-Fe mixture at nominal composition of Ni{sub 3}Fe compound was milled in the same conditions, as blind samples. A heat treatment at 350 {sup o}C for 0.5, 1, 2 and 4 h has been performed in order to remove the internal stresses induced by milling and to improve the solid-state reaction. The formation of the Ni{sub 3}Fe phase was checked by X-ray diffraction and magnetic measurements. The germs inoculation improves the synthesis of the Ni{sub 3}Fe phase by combined mechanical alloying and annealing technique. This influence is more effective for short milling times (typically lower than 4 h). For samples milled more than 4 h the influence of the germs inoculation is more reduced, due to the Ni{sub 3}Fe germs self-formation by milling.

  18. Preparation of Ni-YSZ Cermet through Reduction of NiO-YSZ Ceramic for SOFC Anode

    Science.gov (United States)

    Baity, P. S. N.; Budiana, B.; Suasmoro, S.

    2017-07-01

    Research on the synthesis of Nickel-Yttria Stabilized Zirconia (Ni-YSZ) cermet for Solid Oxide Fuel Cell (SOFC) anode has been performed. The preparation was carried out through the reduction process of the Nickel Oxide-Yttria stabilized Zirconia (NiO-YSZ) ceramic. NiO and YSZ were prepared separately, the NiO powder was prepared by calcination of CH4Ni3O7.xH2O at 500°C for 3 hours, while YSZ powder was prepared by calcination of 7mol% Y2O3 and 93mol% ZrO2 mixture at 1350°C for an hour. The NiO-YSZ ceramic preparation was carried outby mixing of YSZ and NiO powder with natural white starch by weight ratio NiO: YSZ: natural white starch = 4:6:1 followed by sintering at 1200°C for 4 hours. The completion of reduction process of NiO-YSZ ceramic was performed at 1000°C in flowing Argon (Ar) containing 10% Hydrogen (H2) up to 4 hours. The characterisations include thermogravimetric analysis (TGA), XRD, SEM-EDX and Impedance Analyzer meter. The synthesised Ni-YSZ cermet at composition 33wt% Ni and 67wt% YSZ, shows relative density 70% and electrical conductivity 10-2 S/cm at 700°C, it qualifies as anode for SOFC.

  19. Microwave assisted synthesis and characterization of Ni/NiO nanoparticles as electrocatalyst for methanol oxidation in alkaline solution

    Science.gov (United States)

    Arunachalam, Prabhakarn; Ghanem, Mohamed A.; Al-Mayouf, Abdullah M.; Al-shalwi, Matar; Hamed Abd-Elkader, Omar

    2017-02-01

    Nickel/Nickel oxide (Ni/NiO) nanoparticles catalyst is prepared by microwave-assisted liquid-phase deposition using ethylene glycol (EG) and water mixture under atmospheric conditions. The physicochemical characterizations of the catalyst carried out by surface area analyzer, x-ray diffraction (XRD), x-ray photoelectron spectroscopy (XPS), electron microscopes measurements suggest the formation of crystalline nanoparticles structure of NiO. The surface area of Ni/NiO prepared using EG/water mixture reaches 70 m2 g-1 which is 2-fold enhsancement in surface area in comparison with NiO prepared in pure EG and an order of magnitude higher than that of bulk nickel prepared in pure water. The methanol electro-oxidation activity of the Ni/NiO nanoparticles obtained in EG/water mixture displayed more than 4-fold increase in oxidation current at 1.7 V versus RHE in comparison with NiO nanoparticles obtained in EG and 20-fold increase compared to bulk nickel catalyst concord with the enhancement of electro-active surface area. The results show the Ni/NiO nanoparticles produced by microwave assisted synthesis has superior activity for methanol oxidation in alkaline solution over the other nickel based catalysts and has potential for mass production.

  20. Role of Ni-tolerant Bacillus spp. and Althea rosea L. in the phytoremediation of Ni-contaminated soils.

    Science.gov (United States)

    Khan, Waheed Ullah; Yasin, Nasim Ahmad; Ahmad, Sajid Rashid; Ali, Aamir; Ahmed, Shakil; Ahmad, Aqeel

    2017-05-04

    In our current study, four nickel-tolerant (Ni-tolerant) bacterial species viz, Bacillus thuringiensis 002, Bacillus fortis 162, Bacillus subtilis 174, and Bacillus farraginis 354, were screened using Ni-contaminated media. The screened microbes exhibited positive results for synthesis of indole acetic acid (IAA), siderophore production, and phosphate solubilization. The effects of these screened microbes on Ni mobility in the soil, root elongation, plant biomass, and Ni uptake in Althea rosea plants grown in Ni-contaminated soil (200 mg Ni kg(-1)) were evaluated. Significantly higher value for water-extractable Ni (38 mg kg(-1)) was observed in case of Ni-amended soils inoculated with B. subtilis 174. Similarly, B. thuringiensis 002, B. fortis 162, and B. subtilis 174 significantly enhanced growth and Ni uptake in A. rosea. The Ni uptake in the shoots and roots of B. subtilis 174-inoculated plants enhanced up to 1.7 and 1.6-fold, respectively, as compared to that in the un-inoculated control. Bacterial inoculation also significantly improved the root and shoot biomass of treated plants. The current study presents a novel approach for bacteria-assisted phytoremediation of Ni-contaminated areas.

  1. High Damping of Lightweight TiNi-Ti2Ni Shape Memory Composites for Wide Temperature Range Usage

    Science.gov (United States)

    Yang, Bing; Luo, Zheng; Yuan, Bin; Liu, Jiangwen; Gao, Yan

    2017-10-01

    A bimodal porous TiNi-Ti2Ni shape memory alloy composite (SMAC) with 59% porosity was fabricated by sintering Ti-46at.%Ni elemental powders with pore-forming agent. The porous TiNi-Ti2Ni SMAC contains two irregular pores of about 400 and 120 μm. We investigated the microstructure and pore morphology correlated with the mechanical properties and damping capacities of the SMAC. Ti2Ni intermetallic phases with size of 1-3 μm were homogeneously distributed in the TiNi matrix. The porous TiNi-Ti2Ni SMAC exhibits exceptionally high inverse mechanical quality factor ( Q -1) of 0.25 at < 40 °C, which is among the highest value reported for porous/dense shape memory alloys or composites to best of our knowledge, and it shows very high compressive fracture strain of about 25%. Moreover, the fabricated porous SMAC at relatively low strain amplitude can exhibit considerable high Q -1 of 0.06 0.11 for a wide range of temperature between - 90 and 200 °C, which is attributed to the stress concentration distribution provided by the bimodal structure of pores and the massive interfaces between pore/matrix and TiNi/Ti2Ni. These porous SMACs can be an ideal candidate for using as a lightweight damping material in the energy-saving applications.

  2. Anti-corrosive and anti-microbial properties of nanocrystalline Ni-Ag coatings

    Energy Technology Data Exchange (ETDEWEB)

    Raghupathy, Y.; Natarajan, K.A.; Srivastava, Chandan, E-mail: csrivastava@materials.iisc.ernet.in

    2016-04-15

    Graphical abstract: - Highlights: • Electrodeposition yielded phase-segregated, nanocrystalline Ni-Ag coatings. • Ni-Ag alloys exhibited smaller Ni crystals compared to pure Ni. • Ultra fine Ni grains of size 12–14 nm favoured Ni-Ag solid solution. • Nanocrystalline Ag resisted bio-fouling by Sulphate Reducing bacteria. • Ni-Ag outperformed pure Ni in corrosion and bio-corrosion tests. - Abstract: Anti-corrosive and anti-bacterial properties of electrodeposited nanocrystalline Ni-Ag coatings are illustrated. Pure Ni, Ni-7 at.% Ag, & Ni-14 at.% Ag coatings were electrodeposited on Cu substrate. Coating consisted of Ni-rich and Ag-rich solid solution phases. With increase in the Ag content, the corrosion resistance of the Ni-Ag coating initially increased and then decreased. The initial increase was due to the Ni-Ag solid solution. The subsequent decrease was due to the increased galvanic coupling between the Ag-rich and Ni-rich phases. For all Ag contents, the corrosion resistance of the Ni-Ag coating was higher than the pure Ni coating. Exposure to Sulphate Reducing Bacteria (SRB) revealed that the extent of bio-fouling decreased with increase in the Ag content. After 2 month exposure to SRB, the Ni-Ag coatings demonstrated less loss in corrosion resistance (58% for Ni-7 at.% Ag and 20% for Ni-14 at.% Ag) when compared pure Ni coating (115%).

  3. Effect of Ni Core Structure on the Electrocatalytic Activity of Pt-Ni/C in Methanol Oxidation

    Science.gov (United States)

    Kang, Jian; Wang, Rongfang; Wang, Hui; Liao, Shijun; Key, Julian; Linkov, Vladimir; Ji, Shan

    2013-01-01

    Methanol oxidation catalysts comprising an outer Pt-shell with an inner Ni-core supported on carbon, (Pt-Ni/C), were prepared with either crystalline or amorphous Ni core structures. Structural comparisons of the two forms of catalyst were made using transmission electron microscopy (TEM), X-ray diffraction (XRD) and X-ray photoelectron spectroscopy (XPS), and methanol oxidation activity compared using CV and chronoamperometry (CA). While both the amorphous Ni core and crystalline Ni core structures were covered by similar Pt shell thickness and structure, the Pt-Ni(amorphous)/C catalyst had higher methanol oxidation activity. The amorphous Ni core thus offers improved Pt usage efficiency in direct methanol fuel cells. PMID:28811402

  4. Effect of Ni Core Structure on the Electrocatalytic Activity of Pt-Ni/C in Methanol Oxidation

    Directory of Open Access Journals (Sweden)

    Vladimir Linkov

    2013-07-01

    Full Text Available Methanol oxidation catalysts comprising an outer Pt-shell with an inner Ni-core supported on carbon, (Pt-Ni/C, were prepared with either crystalline or amorphous Ni core structures. Structural comparisons of the two forms of catalyst were made using transmission electron microscopy (TEM, X-ray diffraction (XRD and X-ray photoelectron spectroscopy (XPS, and methanol oxidation activity compared using CV and chronoamperometry (CA. While both the amorphous Ni core and crystalline Ni core structures were covered by similar Pt shell thickness and structure, the Pt-Ni(amorphous/C catalyst had higher methanol oxidation activity. The amorphous Ni core thus offers improved Pt usage efficiency in direct methanol fuel cells.

  5. Hard X-ray MCD in GdNi/sub 5/ and TbNi/sub 5/ single crystals

    CERN Document Server

    Galera, R M

    1999-01-01

    XMCD experiments have been performed at the R L/sub 2,3/ and Ni K- edges on magnetically saturated single crystals of GdNi/sub 5/ and Tb Ni/sub 5/ ferromagnetic compounds. The spectra present huge and well structured dichroic $9 signals at both the R L/sub 2,3/ and the Ni K- edges. Structures from the quadrupolar (2p to 4f) transitions are clearly observed at the R L/sub 2,3/-edges. Though Ni is not magnetic, large intensities, up to 0.4, are measured at the $9 Ni K- edge. The Ni K-edge XMCD shows a three-peak structure which intensities dependent on the rare earth. (7 refs).

  6. Shell-ferromagnetism in Ni-Mn-based Heuslers in view of ductile Ni-Mn-Al

    Directory of Open Access Journals (Sweden)

    A. Çakır

    2017-05-01

    Full Text Available The present work deals with magnetic and structural phase instabilities in Ni-Mn-based Heusler alloys especially Ni-Mn-Al. The temper-annealed Ni50Mn45Al5 Heusler alloy decomposes into the full stoichiometric Ni2MnAl and NiMn phases. The decomposed stoichiometric Heusler forms precipitates in an anti-ferromagnetic NiMn matrix and exhibits shell-ferromagnetic properties when the temper-annealing is performed under magnetic field. The shell-ferromagnetism results from the magnetic proximity effect and is observed as vertically shifted magnetization loops. The presence of this property in Ni50Mn45Al5 adds the possibility of having a ductile material while preserving the shell-ferromagnetic properties.

  7. Ni{sub 3}Al technology transfer

    Energy Technology Data Exchange (ETDEWEB)

    Sikka, V.K.; Viswanathan, S.; Santella, M.L. [Oak Ridge National Lab., TN (United States)] [and others

    1997-04-01

    Ductile Ni{sub 3}Al and Ni{sub 3}Al-based alloys have been identified for a range of applications. These applications require the use of material in a variety of product forms such as sheet, plate, bar, wire, tubing, piping, and castings. Although significant progress has been made in the melting, casting, and near-net-shape forming of nickel aluminides, some issues still remain. These include the need for: (1) high-strength castable composition for many applications that have been identified; (2) castability (mold type, fluidity, hot-shortness, porosity, etc.); (3) weld reparability of castings; and (4) workability of cast or powder metallurgy product to sheet, bar, and wire. The four issues listed above can be {open_quotes}show stoppers{close_quotes} for the commercial application of nickel aluminides. This report describes the work completed to address some of these issues during FY 1996.

  8. Niño, inteligencia, devenir

    OpenAIRE

    Galindo Olaya, Juan Diego

    2016-01-01

    En este artículo nos proponemos mostrar cómo actúan en conjunto el plano de organización y el plano de consistencia que conforman el mapa del pensamiento en la escuela, según el cual, se puede afirmar que el pensamiento se escapa a la inhibición, la interpretación y la sujeción que provoca su traducción en términos de inteligencia, cuando, como resultado de la experimentación, se gesta un encuentro indeterminado con fuerzas que pueden conducir al devenir-niño del niño en la escuela. En este s...

  9. Internal chlorination of Ni-Cr alloys

    Energy Technology Data Exchange (ETDEWEB)

    Berztiss, D.; Hennesen, K.; Grabke, H.J. [Max-Planck-Institut fuer Eisenforschung GmbH, Duesseldorf (Germany)

    1998-12-31

    In contrast to internal oxidation, sulfidation and carburization, very little information is available regarding internal chlorination, especially diffusion of chlorine in metallic alloys. This paper describes results of experiments on Ni-Cr alloys (<10 wt% Cr) exposed in an atmosphere containing radioactive HCl. The diffusion of chlorine in the alloy can be determined by measurement of residual {beta}-activity from the sample surface. Successively thin layers (0.5-10 {mu}m) of the alloy were removed by lapping and the surface activity was measured to obtain a depth profile. Both single and polycrystalline materials were tested. Through this work it should be determined if there is in fact solubility and diffusion of chlorine in Ni-based alloys as some authors have proposed or if the ingress of chlorine is mainly a grain boundary phenomenon. (orig.)

  10. Fe-Ni-bearing serpentines from the saprolite horizon of Caribbean Ni-laterite deposits: new insights from thermodynamic calculations

    Science.gov (United States)

    Villanova-de-Benavent, Cristina; Domènech, Cristina; Tauler, Esperança; Galí, Salvador; Tassara, Santiago; Proenza, Joaquín A.

    2017-10-01

    Fe-Ni-bearing serpentine from the saprolite horizon is the main Ni ores in hydrous silicate-type Ni laterites and formed by chemical weathering of partially serpentinized ultramafic rocks under tropical conditions. During lateritization, Mg, Si, and Ni are leached from the surface and transported downwards. Fe2+ is oxidized to Fe3+ and fixed as insoluble Fe-oxyhydroxides (mostly goethite) that incorporate Ni. This Ni is later leached from goethite and incorporated in secondary serpentine and garnierite. As a result, a serpentine-dominated saprolite horizon forms over the ultramafic protolith, overlapped by a Fe-oxyhydroxide-dominated limonite horizon. The serpentine from the protolith (serpentine I) is of hydrothermal origin and yields similar Ni (0.10-0.62 wt.% NiO) and lower Fe (mostly 1.37-5.81 wt.% FeO) concentrations than the primary olivine. In contrast, Fe-Ni-bearing serpentine from the saprolite (serpentine II) shows significantly higher and variable Fe and Ni contents, typically ranging from 2.23 to 15.59 wt.% Fe2O3 and from 1.30 to 7.67 wt.% NiO, suggesting that serpentine get enriched in Fe and Ni under supergene conditions. This study presents detailed mineralogical, textural, and chemical data on this serpentine II, as well as new insights by thermodynamic calculations assuming ideal solution between Fe-, Ni- and Mg-pure serpentines. The aim is to assess if at atmospheric pressure and temperature Fe-Ni-bearing serpentine can be formed by precipitation. Results indicate that the formation of serpentine II under atmospheric pressure and temperature is thermodynamically supported, and pH, Eh, and the equilibrium constant of the reaction are the parameters that affect the results more significantly.

  11. Tungsten inert gas (TIG) welding of Ni-rich NiTi plates: functional behavior

    Science.gov (United States)

    Oliveira, J. P.; Barbosa, D.; Braz Fernandes, F. M.; Miranda, R. M.

    2016-03-01

    It is often reported that, to successfully join NiTi shape memory alloys, fusion-based processes with reduced thermal affected regions (as in laser welding) are required. This paper describes an experimental study performed on the tungsten inert gas (TIG) welding of 1.5 mm thick plates of Ni-rich NiTi. The functional behavior of the joints was assessed. The superelasticity was analyzed by cycling tests at maximum imposed strains of 4, 8 and 12% and for a total of 600 cycles, without rupture. The superelastic plateau was observed, in the stress-strain curves, 30 MPa below that of the base material. Shape-memory effect was evidenced by bending tests with full recovery of the initial shape of the welded joints. In parallel, uniaxial tensile tests of the joints showed a tensile strength of 700 MPa and an elongation to rupture of 20%. The elongation is the highest reported for fusion-welding of NiTi, including laser welding. These results can be of great interest for the wide-spread inclusion of NiTi in complex shaped components requiring welding, since TIG is not an expensive process and is simple to operate and implement in industrial environments.

  12. Distinct demagnetization dynamics of Ni and Fe magnetic moments in a NiFe alloy

    Energy Technology Data Exchange (ETDEWEB)

    Eschenlohr, Andrea; Stamm, Christian; Pontius, Niko; Kachel, Torsten; Radu, Florin [Helmholtz Zentrum Berlin fuer Materialien und Energie, Elektronenspeicherring BESSY II, Albert-Einstein-Str. 15, 12489 Berlin (Germany); Radu, Ilie [Helmholtz Zentrum Berlin fuer Materialien und Energie, Elektronenspeicherring BESSY II, Albert-Einstein-Str. 15, 12489 Berlin (Germany); Radboud University Nijmegen, Heijendaalseweg 135, 6525 AJ Nijmegen (Netherlands); Rasing, Theo; Kimel, Alexey V. [Radboud University Nijmegen, Heijendaalseweg 135, 6525 AJ Nijmegen (Netherlands)

    2011-07-01

    Ultrafast demagnetization has been approached from a variety of experimental and theoretical angles since the first observation of a sub-picosecond quenching of magnetization in Ni. Time constants of demagnetization have been established for elementary transition metals and rare earths. Their compounds and alloys, which are highly relevant for technological applications and for research into the microscopic origins of ultrafast demagnetization, are increasingly investigated with methods like TR-MOKE. Yet experimental methods which combine femtosecond time resolution with an element-sensitive measurement of the magnetization have so far been sparse. We bridge this gap by probing magnetization dynamics in ferromagnetic NiFe alloys in an element-resolved way with 100 fs x-ray pulses generated by the Femtoslicing facility at BESSY II via XMCD. We find different demagnetization time constants for Ni (80 +/- 30 fs) and Fe (240 +/- 30 fs) in Ni50Fe50, evidence of a decoupling of the Ni and Fe dynamics on ultrafast timescales despite the exchange interaction between the two elements.

  13. Participar como niña o niño en el mundo social

    Directory of Open Access Journals (Sweden)

    Silvia Paulina Díaz

    2010-10-01

    Full Text Available En este artículo presento la participación como resultado de un trabajo investigativo realizado durante el año 2007, con niños y niñas escolarizados habitantes de la ciudad de Medellín, Colombia, cuyo objetivo fue analizar las representaciones sociales que ellos y ellas comparten sobre el ejercicio ciudadano. El análisis de la información tiene como ejes fundamentales, la salud colectiva, la sociología de la infancia y la participación en la niñez, en una aproximación que se realiza desde un enfoque cualitativo y etnográfico. En los hallazgos, sobresale cómo las niñas y niños se muestran preparados para ejercer su derecho a la participación como aspecto de sus vidas que se haría posible dentro del marco normativo existente, pero que aún no es asumido en prácticas sociales que los incluyan.

  14. NiTi superelasticity via atomistic simulations

    Science.gov (United States)

    Chowdhury, Piyas; Ren, Guowu; Sehitoglu, Huseyin

    2015-12-01

    The NiTi shape memory alloys (SMAs) are promising candidates for the next-generation multifunctional materials. These materials are superelastic i.e. they can fully recover their original shape even after fairly large inelastic deformations once the mechanical forces are removed. The superelasticity reportedly stems from atomic scale crystal transformations. However, very few computer simulations have emerged, elucidating the transformation mechanisms at the discrete lattice level, which underlie the extraordinary strain recoverability. Here, we conduct breakthrough molecular dynamics modelling on the superelastic behaviour of the NiTi single crystals, and unravel the atomistic genesis thereof. The deformation recovery is clearly traced to the reversible transformation between austenite and martensite crystals through simulations. We examine the mechanistic origin of the tension-compression asymmetries and the effects of pressure/temperature/strain rate variation isolatedly. Hence, this work essentially brings a new dimension to probing the NiTi performance based on the mesoscale physics under more complicated thermo-mechanical loading scenarios.

  15. Multifunction of Ni/Ag Nanocompound Fluid

    Directory of Open Access Journals (Sweden)

    Mu-Jung Kao

    2013-01-01

    Full Text Available An arc-submerged nanoparticle synthesis system (ASNSS is proposed and developed for fabricating Ni/Ag nanocompound fluid. In the development process, the positive and negative electrodes in the system are Ni and Ag, respectively. Applied electrical energy then produces heating source by generating an adequate arc with a high temperature that can melt and vaporize the two electrodes. The nanocompound fluid that is generated by the synthesis system is analyzed by morphological analysis, Zeta potential analysis, heat conductivity analysis, magnetic characteristic analysis, and UV-Vis absorption spectra analysis. Experimental results show that increasing the concentration of added particles and the higher temperature can be helpful to the enhancement of thermal conductivity. The Ni/Ag nanofluid not only preserves the magnetic character of the nickel and the ability of silver to absorb visible light but also enhances the thermal conductivity. The absorption occurs at 406 nm wavelength (redshift from 396 nm to 406 nm, which means that, under the excitement of visible light range (400~700 nm, it can let more easy electrons jump to the conductivity zone from the valence electron zone.

  16. Combining Ru, Ni and Ni(OH){sub 2} active sites for improving catalytic performance in benzene hydrogenation

    Energy Technology Data Exchange (ETDEWEB)

    Zhu, Lihua, E-mail: lihuazhu@stu.xmu.edu.cn [School of Metallurgy and Chemical Engineering, Jiangxi University of Science and Technology, Ganzhou 341000, Jiang Xi (China); Department of Chemical and Biochemical Engineering, National Engineering Laboratory for Green Productions of Alcohols-Ethers-Esters, College of Chemistry and Chemical Engineering, Xiamen University, Xiamen 361005 (China); Sun, Hanlei; Zheng, Jinbao [Department of Chemical and Biochemical Engineering, National Engineering Laboratory for Green Productions of Alcohols-Ethers-Esters, College of Chemistry and Chemical Engineering, Xiamen University, Xiamen 361005 (China); Yu, Changlin, E-mail: yuchanglinjx@163.com [School of Metallurgy and Chemical Engineering, Jiangxi University of Science and Technology, Ganzhou 341000, Jiang Xi (China); Zhang, Nuowei [Department of Chemical and Biochemical Engineering, National Engineering Laboratory for Green Productions of Alcohols-Ethers-Esters, College of Chemistry and Chemical Engineering, Xiamen University, Xiamen 361005 (China); Shu, Qing [School of Metallurgy and Chemical Engineering, Jiangxi University of Science and Technology, Ganzhou 341000, Jiang Xi (China); Chen, Bing H., E-mail: chenbh@xmu.edu.cn [Department of Chemical and Biochemical Engineering, National Engineering Laboratory for Green Productions of Alcohols-Ethers-Esters, College of Chemistry and Chemical Engineering, Xiamen University, Xiamen 361005 (China)

    2017-05-01

    In this study, the Ru{sub 0.04}Ni{sub 0.96}/C(T) catalysts were successfully prepared by the simple methods of hydrazine-reduction and galvanic replacement, where 0.04/0.96 and T represented the Ru/Ni atomic ratio and reducing temperature of the catalyst in N{sub 2}+10%H{sub 2}, respectively. The nanostructures of the Ru{sub 0.04}Ni{sub 0.96} nanoparticles in the Ru{sub 0.04}Ni{sub 0.96}/C(T) catalysts were controlled by modulating their annealing temperature in N{sub 2}+10%H{sub 2} and characterized by an array of techniques, including X-ray diffraction (XRD), X-ray photoelectron spectroscopy (XPS), transmission electron microscopy (TEM), high resolution transmission electron microscopy (HRTEM), scanning transmission electron microscopy energy dispersive X-ray spectroscopy (STEM-EDS) mapping and high-sensitivity low-energy ion scattering (HS-LEIS). The Ru{sub 0.04}Ni{sub 0.96}/C(30) catalyst, which was composed of Ru clusters or single atoms supported on Ni/Ni(OH){sub 2} nanoparticles, exhibited much better catalytic performance for benzene hydrogenation than the Ru{sub 0.04}Ni{sub 0.96}/C(T) catalysts reduced at above 30 °C, such as Ru{sub 0.04}Ni{sub 0.96}/C(160) with the nanostructure of partial Ru{sub 0.04}Ni{sub 0.9} alloy and Ru{sub 0.04}Ni{sub 0.96}/C(280) with the nanostructure of complete Ru{sub 0.04}Ni{sub 0.9} alloy. The reason was that the synergistic effect of multiple active sites – Ru, Ni and Ni(OH){sub 2} sites was present in the Ru{sub 0.04}Ni{sub 0.96}/C(30) catalyst, where hydrogen was preferentially activated at Ru sites, benzene was probably activated at Ni(OH){sub 2} surface and Ni acted as a “bridge” for transferring activated H{sup ∗} species to activated benzene by hydrogen spillover effect, hydrogenating and forming product – cyclohexane. This study also provided a typical example to illustrate that the synergy effect of multiple active sites can largely improve the catalytic hydrogenation performance. - Highlights: • The Ru

  17. Fabrications of High-Capacity Alpha-Ni(OH2

    Directory of Open Access Journals (Sweden)

    Kwo-Hsiung Young

    2017-03-01

    Full Text Available Three different methods were used to produce α-Ni(OH2 with higher discharge capacities than the conventional β-Ni(OH2, specifically a batch process of co-precipitation, a continuous process of co-precipitation with a phase transformation step (initial cycling, and an overcharge at low temperature. All three methods can produce α-Ni(OH2 or α/β mixed-Ni(OH2 with capacities higher than that of conventional β-Ni(OH2 and a stable cycle performance. The second method produces a special core–shell β-Ni(OH2/α-Ni(OH2 structure with an excellent cycle stability in the flooded half-cell configuration, is innovative and also already mass-production ready. The core–shell structure has been investigated by both scanning and transmission electron microscopies. The shell portion of the particle is composed of α-Ni(OH2 nano-crystals embedded in a β-Ni(OH2 matrix, which helps to reduce the stress originating from the lattice expansion in the β-α transformation. A review on the research regarding α-Ni(OH2 is also included in the paper.

  18. Ferromagnetic (Ni) nanoparticles–CuTl-1223 superconductor composites

    Energy Technology Data Exchange (ETDEWEB)

    Qasim, Irfan; Waqee-ur-Rehman, M. [Materials Research Laboratory, Department of Physics, Faculty of Basic and Applied Sciences (FBAS), International Islamic University (IIU), Islamabad 44000 (Pakistan); Mumtaz, M., E-mail: mmumtaz75@yahoo.com [Materials Research Laboratory, Department of Physics, Faculty of Basic and Applied Sciences (FBAS), International Islamic University (IIU), Islamabad 44000 (Pakistan); Hussain, Ghulam; Nadeem, K. [Materials Research Laboratory, Department of Physics, Faculty of Basic and Applied Sciences (FBAS), International Islamic University (IIU), Islamabad 44000 (Pakistan); Shehzad, Khurram [Department of Information Science and Electronic Engineering, Zhejiang University, Hangzhou 310027 (China)

    2016-04-01

    (Ni){sub x}/CuTl-1223 (x=0, 0.25, 0.75, and 1.0 wt%) nanoparticles–superconductor composites were synthesized by the addition of ferromagnetic nickel (Ni) nanoparticles in appropriate ratio to Cu{sub 0.5}Tl{sub 0.5}Ba{sub 2}Ca{sub 2}Cu{sub 3}O{sub 10−δ} (CuTl-1223) superconducting matrix. Structural, morphological, compositional and superconducting transport properties of these composites were studied by different experimental techniques. It was observed that the addition of Ni nanoparticles had not altered the crystal structure of host CuTl-1223 phase, which is somehow an evidence of the occupancy of these nanoparticles at the grain-boundaries. Suppression of superconducting properties was attributed to pair-breaking due to spin scattering across these ferromagnetic Ni nanoparticles. The enhanced magnetization of ferromagnetic Ni nanoparticles at reduced temperatures plays a significant role to reduce the diamagnetism of (Ni){sub x}/CuTl-1223 composites. Fluctuation induced conductivity (FIC) analysis of resistivity versus temperature data has explained very well the effects of Ni nanoparticles on superconductivity of CuTl-1223 phase. - Highlights: • (Ni){sub x}/CuTl-1223 composites were synthesized. • Crystal structure of CuTl-1223 phase was not affected by Ni nanoparticles. • Superconductivity of CuTl-1223 phase was suppressed by Ni nanoparticles addition. • Suppression of superconductivity was explained theoretically.

  19. Morphological instability of lamellar structures in directionally solidified Ni-Ni3Si alloys

    Science.gov (United States)

    Wei, Lufeng; Zhao, Zhilong; Gao, Jianjun; Cui, Kai; Guo, Jingying; Chen, Sen; Liu, Lin

    2018-02-01

    The morphological instability of lamellar structures in Ni-Ni3Si eutectic and hypereutectic alloys directionally solidified at low growth rates was investigated. The first instability in large lamellar structures was zigzag instability, which formed curved lamellae. A zigzag pattern was first displayed in three dimensions. The diffusion-limited growth of the Ni3Si phase decreased phase width and spacing, consequently causing zigzag instability. The reduced spacing was observed at λ/λave = 0.9. After zigzag instability, the microstructure of the eutectic alloy turned into a labyrinth structure and lamellar fragmentation. However, in hypereutectic alloys, shape transition from lamellae to rods occurred, in turn, by the broken lamellae or elongated rods to dumbbell-shaped rods, peanut-shaped rods, and circular rods.

  20. Spray Forming of NiTi and NiTiPd Shape-Memory Alloys

    Science.gov (United States)

    Mabe, James; Ruggeri, Robert; Noebe, Ronald

    2008-01-01

    In the work to be presented, vacuum plasma spray forming has been used as a process to deposit and consolidate prealloyed NiTi and NiTiPd powders into near net shape actuators. Testing showed that excellent shape memory behavior could be developed in the deposited materials and the investigation proved that VPS forming could be a means to directly form a wide range of shape memory alloy components. The results of DSC characterization and actual actuation test results will be presented demonstrating the behavior of a Nitinol 55 alloy and a higher transition temperature NiTiPd alloy in the form of torque tube actuators that could be used in aircraft and aerospace controls.

  1. Catalytic properties of amorphous NiZr alloys. Amorufasu NiZr gokin no shokubai tokusei

    Energy Technology Data Exchange (ETDEWEB)

    Komiyama, H.; Shimogaki, Y.; Egashira, Y.; Sumiya, S. (The Univ. of Tokyo, Tokyo, (Japan). Faculty of Engineering)

    1990-03-01

    This paper investigated the catalytic properties of amorphous NiZr alloys. Amorphous alloys were used as ribbon, powder and ultra-fine powder (a-UFP) prepared by different processes as they are, or after chemically cleaved process. Catalytic reactions were measured by the gas chromatography for gas composition at the reactor outlet. The applied reactions were the hydrogenation of CO, acethylene and butadiene, and the hydrogenolysis of ethane. All amorphous alloys indicated similar reacting characteristics, independent of the preparation methods. It should reflect any common substance that amorphous alloy of nonequilibrium which can be different states by manufacturing process, show similar characteristics like this. The surface of amprphous alloys has strong affinity to Zr and O and Ni, Zr and O is thought to be highly dispersed, presumably at an atomic level, maintaining Ni as the stable oxidized condition. These catalysts are very interesting because such the characteristics cannot be realized in crystaline catalysts. 5 refs., 9 figs., 2 tabs.

  2. Internal reforming of methane at Ni/YSZ and Ni/CGO SOFC cermet anodes

    Energy Technology Data Exchange (ETDEWEB)

    Timmermann, H.; Fouquet, D.; Weber, A.; Ivers-Tiffee, E. [Karlsruhe Univ. (Germany). Inst. fuer Werkstoffe der Elektrotechnik; Hennings, U.; Reimert, R. [Karlsruhe Univ. (Germany). Engler-Bunte-Institut, Bereich Gas, Erdoel und Kohle

    2006-07-15

    The internal reforming of methane on Ni/CGO and Ni/YSZ anodes was investigated with single cells operated at steam to carbon ratios from 0 to 3 and at temperatures of 800 C and 950 C. The incorporation of gas extraction ports allowed the measurement of the local gas composition in the anode gas compartment by gas chromatography. The methane conversion is presented as a function of feed gas composition, temperature, gas flow velocity, and electrical load. The impact of the anode material on the reforming reaction and on cell performance is shown. Methane conversion along the Ni/CGO anode was calculated with a one-dimensional model; the required kinetic parameters were obtained by data fitting. (Abstract Copyright [2006], Wiley Periodicals, Inc.)

  3. Measurement of {sup 63}Ni and {sup 59}Ni by accelerator mass spectrometry using characteristic projectile x-rays

    Energy Technology Data Exchange (ETDEWEB)

    McAninch, J.E.; Hainsworth, L.J.; Marchetti, A.A. [and others

    1996-05-01

    The long-lived isotopes of nickel ({sup 59}Ni, {sup 63}Ni) have current and potential use in a number of applications including cosmic radiation studies, biomedical tracing, characterization of low-level radioactive wastes, and neutron dosimetry. Methods are being developed at LLNL for the routine detection of these isotopes by AMS. One intended application is in Hiroshima dosimetry. The reaction {sup 63}Cu(n,p){sup 63}Ni has been identified as one of a small number of reactions which might be used for the direct determination of the fast neutron fluence emitted by the Hiroshima bomb. AMS measurement of {sup 63}Ni(t{sub 1/2} = 100 y) requires the chemical removal of {sup 63}Cu, which is a stable isobar of {sup 63}Ni. Following the electrochemical separation of Ni from gram-sized copper samples, the Cu concentration is further lowered to < 2 x 10{sup -8} (Cu/Ni) using the reaction of Ni with carbon monoxide to form the gas Ni(CO){sub 4}. The Ni(CO){sub 4} is thermally decomposed directly in sample holders for measurement by AMS. After analysis in the AMS spectrometer, the ions are identified using characteristic projectile x-rays, allowing further rejection of remaining {sup 63}Cu. In a demonstration experiment, {sup 63}Ni was measured in Cu wires (2-20 g) which had been exposed to neutrons from a {sup 252}Cf source. We successfully measured {sup 63}Ni at levels necessary for the measurement of Cu samples exposed near the Hiroshima hypocenter. For the demonstration samples, the Cu content was chemically reduced by a factor of 10{sup 12} with quantitative retention of {sup 63}Ni. Detection sensitivity (3{sigma}) was {approximately}20 fg {sup 63}Ni in 1 mg Ni carrier ({sup 63}Ni/Ni {approx} 2 x 10{sup -11}). Significant improvements in sensitivity are expected with planned incremental changes in the methods. Preliminary results indicate that a similar sensitivity is achievable for {sup 59}Ni (t{sub 1/2} = 10{sup 5} y).

  4. Observation of Ni{sup 3+} acceptor in P-type Ni(P):SnO{sub 2}

    Energy Technology Data Exchange (ETDEWEB)

    Lee, Po-Ming, E-mail: 101324061@cc.ncu.edu.tw; Wu, Yen-Ju; Hsieh, Chih-Yi; Liao, Ching-Han; Liu, Yen-Shuo; Liu, Cheng-Yi

    2015-05-15

    Highlights: • In this work, Ni and Ni(P) was doped into the SnO{sub 2} oxide to form p-type SnO{sub 2} thin film. • The Ni{sup 3+}-Sn{sup 4+} substitution reaction produces electrical holes overwhelming the free electrons generated by oxygen vacancies. • We report that Ni{sup 3+}-Sn{sup 4+} substitution reaction only occurs, as P is co-doped with Ni in SnO{sub 2} thin film, which converts n-type SnO{sub 2} thin film to p-type conduction. • With the developed p-Ni(P):SnO{sub 2}, transparent p-Ni(P):SnO{sub 2}/i-SnO{sub 2}/n-ITO p-i-n structure was fabricated and characterized: low leakage-current (8.41 × 10{sup −5} A at −5 V), turn-on voltage (4.68 eV), good transmittance (85%), and small ideality-factor (1.73). - Abstract: Ni dopants typically exist as Ni{sup 2+} oxidation state in metal oxides. We report that as Ni is co-doped with P in Ni(P):SnO{sub 2}, P promotes Ni{sup 2+} into Ni{sup 3+}, which acts as acceptor and coverts n-type SnO{sub 2} to p-type conduction. Significant hole concentration (4.5 × 10{sup 18} cm{sup −3}) of p-type Ni(P):SnO{sub 2} can be obtained. The chemical state of Ni{sup 3+} in Ni(P):SnO{sub 2} is verified by ultra-violet and x-ray photoelectron spectroscopy. With the developed p-Ni(P):SnO{sub 2}, transparent p-Ni(P):SnO{sub 2}/i-SnO{sub 2}/n-ITO p-i-n structure was fabricated and characterized: low leakage-current (8.41 × 10{sup −5} A at −5 V), turn-on voltage (4.68 eV), good transmittance (85%), and small ideality-factor (1.73)

  5. NiO-Microflower Formed by Nanowire-weaving Nanosheets with Interconnected Ni-network Decoration as Supercapacitor Electrode

    Science.gov (United States)

    Ci, Suqing; Wen, Zhenhai; Qian, Yuanyuan; Mao, Shun; Cui, Shumao; Chen, Junhong

    2015-01-01

    We propose a ‘weaving’ evolution mechanism, by systematically investigating the products obtained in controlled experiments, to demonstrate the formation of Ni-based ‘microflowers’ which consists of multiple characteristic dimensions, in which the three dimensional (3D) NiO ‘microflower’ is constructed by a two-dimensional (2D) nanosheet framework that is derived from weaving one-dimensional (1D) nanowires. We found such unique nanostructures are conducive for the generation of an electrically conductive Ni-network on the nanosheet surface after being exposed to a reducing atmosphere. Our study offers a promising strategy to address the intrinsic issue of poor electrical conductivity for NiO-based materials with significant enhancement of utilization of NiO active materials, leading to a remarkable improvement in the performance of the Ni-NiO microflower based supercapacitor. The optimized Ni-NiO microflower material showed a mass specific capacitance of 1,828 F g−1, and an energy density of 15.9 Wh kg−1 at a current density of 0.5 A g−1. This research not only contributes to understanding the formation mechanism of such ‘microflower’ structures but also offers a promising route to advance NiO based supercapacitor given their ease of synthesis, low cost, and long-term stability. PMID:26165386

  6. High Density Arrayed Ni/NiO Core-shell Nanospheres Evenly Distributed on Graphene for Ultrahigh Performance Supercapacitor.

    Science.gov (United States)

    Liu, Fanggang; Wang, Xiaobing; Hao, Jin; Han, Shuang; Lian, Jianshe; Jiang, Qing

    2017-12-18

    A novel NiO/Ni/RGO three-dimensional core-shell architecture consisting of Ni nanoparticles as core, NiO as shell and reduced graphene oxide (RGO) as conductivity layer, has been constructed by redox reactions with hydrothermal method and heat treatment. High density arrayed nickel nanoparticles (20 nm diameter) semi-coated by a 3 nm thick layer of NiO are evenly distributed on the surface of graphene. This elaborate design not only uses abundant NiO surfaces to provide a wealth of active sites, but also bridges electrochemical active NiO shell and graphene by Ni core to construct an interconnected 3D conductive network. Since both electrochemical activity and excellent conductivity are reserved in this Ni/NiO core-shell/graphene layer 3D structure, the as-prepared electrode material exhibits an extremely high specific capacitance (2048.3 F g-1 at current density of 1 A g-1) and excellent cycle stability (77.8% capacitance retention after 10000 cycles at current density of 50 A g-1). The novel method presented here is easy and effective and would provide reference for the preparation of other high performance supercapacitor electrodes.

  7. On the Ni-Ion release rate from surfaces of binary NiTi shape memory alloys

    Science.gov (United States)

    Ševčíková, Jana; Bártková, Denisa; Goldbergová, Monika; Kuběnová, Monika; Čermák, Jiří; Frenzel, Jan; Weiser, Adam; Dlouhý, Antonín

    2018-01-01

    The study is focused on Ni-ion release rates from NiTi surfaces exposed in the cell culture media and human vascular endothelial cell (HUVEC) culture environments. The NiTi surface layers situated in the depth of 70 μm below a NiTi oxide scale are affected by interactions between the NiTi alloys and the bio-environments. The finding was proved with use of inductively coupled plasma mass spectrometry and electron microscopy experiments. As the exclusive factor controlling the Ni-ion release rates was not only thicknesses of the oxide scale, but also the passivation depth, which was two-fold larger. Our experimental data strongly suggested that some other factors, in addition to the Ni concentration in the oxide scale, admittedly hydrogen soaking deep below the oxide scale, must be taken into account in order to rationalize the concentrations of Ni-ions released into the bio-environments. The suggested role of hydrogen as the surface passivation agent is also in line with the fact that the Ni-ion release rates considerably decrease in NiTi samples that were annealed in controlled hydrogen atmospheres prior to bio-environmental exposures.

  8. Magnetic Excitations in the Stacked Quantum Magnets NaNiO2 and LiNiO2

    Science.gov (United States)

    Clancy, J. P.; Gaulin, B. D.; Ruff, J. P. C.; Ross, K. A.; van Gastel, G. J.; Abernathy, D. L.; Stone, M. B.

    2009-03-01

    NaNiO2 and LiNiO2 are isostructural stacked triangular lattice quantum magnets, in which magnetism is conventionally thought to arise due to spin 1/2 moments carried by Ni^3+ ions. Surprisingly, while NaNiO2 undergoes a cooperative Jahn-Teller transition at 480K and magnetically orders below TN ˜ 23K, LiNiO2 undergoes a glass transition at Tg ˜ 9K and remains disordered down to the lowest measured temperatures. The absence of long-range magnetic order in LiNiO2 has been attributed to either geometric frustration caused by mixing of the Li and Ni sublattices, or orbital degeneracy due to the absence of a coherent Jahn-Teller distortion. We have performed time of flight neutron scattering measurements on polycrystalline samples of NaNiO2 and LiNiO2 using the wide Angular-Range Chopper Spectrometer (ARCS) at the SNS. Our measurements reveal previously unobserved magnetic excitations at relatively high energy transfers, which we associate with ferromagnetic spin waves mediated by in-plane interactions. We also find evidence of critical scattering in NaNiO2 near the magnetic phase transition at TN. These results will be compared with previous measurements collected using the DCS at NIST.

  9. NiO-Microflower Formed by Nanowire-weaving Nanosheets with Interconnected Ni-network Decoration as Supercapacitor Electrode

    Science.gov (United States)

    Ci, Suqing; Wen, Zhenhai; Qian, Yuanyuan; Mao, Shun; Cui, Shumao; Chen, Junhong

    2015-07-01

    We propose a ‘weaving’ evolution mechanism, by systematically investigating the products obtained in controlled experiments, to demonstrate the formation of Ni-based ‘microflowers’ which consists of multiple characteristic dimensions, in which the three dimensional (3D) NiO ‘microflower’ is constructed by a two-dimensional (2D) nanosheet framework that is derived from weaving one-dimensional (1D) nanowires. We found such unique nanostructures are conducive for the generation of an electrically conductive Ni-network on the nanosheet surface after being exposed to a reducing atmosphere. Our study offers a promising strategy to address the intrinsic issue of poor electrical conductivity for NiO-based materials with significant enhancement of utilization of NiO active materials, leading to a remarkable improvement in the performance of the Ni-NiO microflower based supercapacitor. The optimized Ni-NiO microflower material showed a mass specific capacitance of 1,828 F g-1, and an energy density of 15.9 Wh kg-1 at a current density of 0.5 A g-1. This research not only contributes to understanding the formation mechanism of such ‘microflower’ structures but also offers a promising route to advance NiO based supercapacitor given their ease of synthesis, low cost, and long-term stability.

  10. Ni-based composite microstructures fabricated by femtosecond laser reductive sintering of NiO/Cr mixed nanoparticles

    Science.gov (United States)

    Tamura, Kenki; Mizoshiri, Mizue; Sakurai, Junpei; Hata, Seiichi

    2017-06-01

    Ni-based composite micropatterns were fabricated by the femtosecond laser reductive sintering of NiO/Cr mixed nanoparticles. A NiO/Cr mixed nanoparticle solution including ethylene glycol and polyvinylpyrrolidone was irradiated with focused femtosecond laser pulses. The X-ray diffraction spectra of the fabricated micropatterns indicated that NiO nanoparticles were well reduced under atmospheric conditions in the laser scanning speed range of 5-15 mm/s. In contrast, micropatterns including NiO were formed at a laser scanning speed of 1 mm/s, indicating that the reduced Ni was reoxidized by overheating. These results were supported by those of energy-dispersive X-ray spectrometry analysis and the electrical resistivity of the micropatterns. The compositions such as Ni, NiO, Cr2O3, and Ni-Cr in the fabricated micropatterns depended on laser scanning speed. The selective fabrication of a ferromagnetic free microgear from the substrate and an axis fixed on the substrate was demonstrated by controlling the laser scanning speed. The fabrication process for Ni-based composite microstructures is useful for the fabrication of ferromagnetic microdevices.

  11. Influence of Ni doping on PtNi nanoparticles: Synthesis, electronic/atomic structure and photocatalyst investigations

    Science.gov (United States)

    Varshney, Mayora; Sharma, Aditya; Shin, Hyun-Joon; Lee, Hyun Hwi; Jeon, Tae-Yeol; Lee, Byeong-Hyeon; Chae, Keun-Hwa; Won, Sung Ok

    2017-11-01

    Carbon-supported Pt and PtNi nanoparticles (NPs) were synthesized using a borohydride reduction method. Structural properties were studied by synchrotron X-ray diffraction (XRD) and the size/shape of the NPs was determined by transmission electron microscope (TEM). X-ray absorption spectroscopy with its two amendments; X-ray absorption near edge structure (XANES) and extended X-ray absorption fine structure (EXAFS), has been employed to investigate the local electronic/atomic structure surrounding the Pt and Ni atoms. XANES results, at Pt L3-edge and Ni K-edge, have shown fractional oxidation of Pt and Ni atoms. The Pt3Ni1NPs have exhibited a lower bond distance of Pt-Ni shell and higher coordination number of Pt-Ni shells, indicating the alloy formation between Pt and Ni. We further have demonstrated that the Pt and PtNi NPs can serve as effective photocatalysts towards the degradation of water pollutant dye (methyl orange (MO)). By considering the interband charge-transfer of Pt (5d →6sp), a tentative mechanism is proposed to understand the photocatalytic degradation of MO dye molecules by Pt/PtNi NPs under the light irradiation.

  12. Validez judicial del testimonio del niño, niña o adolescente

    OpenAIRE

    Quiñónez Franky, Franciny Orlando; Cuellar Pineda, Mónica Alexandra; López Andrade, Sandra Eugenia

    2015-01-01

    Este trabajo está encaminado a realizar un aporte a la investigación de delitos sexuales en los cuales resultan víctimas los niños, niñas y adolescentes - NNA, en orden a que el enjuiciamiento de estos casos responda a parámetros y a bases que metodológica y epistemológicamente conduzcan a conclusiones científicamente procuradas. Es evidente que la validez del testimonio proveniente de sujetos calificados como los menores de edad, sobre quienes recaen los poderosos efectos del int...

  13. Transmutation-induced embrittlement of V-Ti-Ni and V-Ni alloys in HFIR

    Energy Technology Data Exchange (ETDEWEB)

    Ohnuki, S.; Takahashi, H. [Hokkaido Univ., Sapparo (Japan); Garner, F.A. [Pacific Northwest National Laboratory, Richland, WA (United States); Pawel, J.E. [Oak Ridge National Laboratory, TN (United States)] [and others

    1996-04-01

    Vanadium, V-1Ni, V-10Ti and V-10Ti-1Ni (at %) were irradiated in HFIR to doses ranging from 18 to 30 dpa and temperatures between 300 and 600C. Since the irradiation was conducted in a highly thermalized neutron spectrum without shielding against thermal neutrons, significant levels of chromium (15-22%) were formed by transmutation. The addition of such large chromium levels strongly elevated the ductile to brittle transition temperature. At higher irradiation temperatures radiation-induced segregation of transmutant Cr and solute Ti at specimen surfaces leads to strong increases in the density of the alloy.

  14. Raman active modes of NiSi crystal

    Energy Technology Data Exchange (ETDEWEB)

    Wan Li, E-mail: liwan_china@yahoo.com.c [Department of Physics, Wenzhou University (China); Tang Bo; Cheng Xinhong; Ren Yiming; Zhang Xuefei; Xu Dapeng; Luo Haijun; Huang Yunmi [Department of Physics, Wenzhou University (China)

    2009-08-01

    Raman scattering intensities of the NiSi Raman-active modes have been calculated with three Raman measurement configurations, which can be used for the symmetry assignment of the NiSi Raman peaks. Raman-active vibrations of the NiSi crystal have also been theoretically studied. Results show that the lattices with A{sub g} and B{sub 2g} modes vibrate only in the plane normal to the NiSi[0 1 0] direction while the lattices with B{sub 1g} and B{sub 3g} modes vibrate only along the NiSi[0 1 0] axis. Based on such study, the relationship between the anisotropic strain distribution in the NiSi thin film and the Raman peak shifts has been briefly discussed.

  15. Microstructure and martensitic transformation of Ni-Ti-Pr alloys

    Energy Technology Data Exchange (ETDEWEB)

    Zhao, Chunwang [Inner Mongolia University of Technology, College of Science, Hohhot (China); Shanghai Maritime University, College of Arts and Sciences, Shanghai (China); Zhao, Shilei; Jin, Yongjun; Hou, Qingyu [Inner Mongolia University of Technology, College of Science, Hohhot (China); Guo, Shaoqiang [Beihang University, Key Laboratory of Micro-nano Measurement, Manipulation and Physics (Ministry of Education), Department of Physics, Beijing (China)

    2017-09-15

    The effect of Pr addition on the microstructure and martensitic transformation behavior of Ni{sub 50}Ti{sub 50-x}Pr{sub x} (x = 0, 0.1, 0.3, 0.5, 0.7, 0.9) alloys were investigated experimentally. Results show that the microstructures of Ni-Ti-Pr alloys consist of the NiTi matrix and the NiPr precipitate with the Ti solute. The martensitic transformation start temperature decreases gradually with the increase in Pr fraction. The stress around NiPr precipitates is responsible for the decrease in martensitic transformation temperature with the increase in Pr fraction in Ni-Ti-Pr alloys. (orig.)

  16. Effect of Polyethylene Glycol on the NiO Photocathode.

    Science.gov (United States)

    Li, Shengjun; Chen, Zeng; Kong, Wenping; Jia, Xiyang; Cai, Junhao; Dong, Shaokang

    2017-08-17

    In this study, a uniform nanoporous NiO film, with a thickness of up to 2.6 μm, was prepared using polyethylene glycol (PEG). The addition of PEG significantly decreased the cracks in the NiO film and prevented the peeling of the NiO film from a fluorine-doped tin oxide substrate. The NiO cathode was prepared using CdSeS quantum dots (QDs) as the sensitizer, with an optimized photoelectric conversion of 0.80%. The optimized QD-sensitized NiO films were first assembled with the TiO2 anode to prepared QD-sensitized p-n-type tandem solar cells. The open circuit voltage was greater than that obtained using the separated NiO cathode or TiO2 anode.

  17. Effect of Polyethylene Glycol on the NiO Photocathode

    Science.gov (United States)

    Li, Shengjun; Chen, Zeng; Kong, Wenping; Jia, Xiyang; Cai, Junhao; Dong, Shaokang

    2017-08-01

    In this study, a uniform nanoporous NiO film, with a thickness of up to 2.6 μm, was prepared using polyethylene glycol (PEG). The addition of PEG significantly decreased the cracks in the NiO film and prevented the peeling of the NiO film from a fluorine-doped tin oxide substrate. The NiO cathode was prepared using CdSeS quantum dots (QDs) as the sensitizer, with an optimized photoelectric conversion of 0.80%. The optimized QD-sensitized NiO films were first assembled with the TiO2 anode to prepared QD-sensitized p-n-type tandem solar cells. The open circuit voltage was greater than that obtained using the separated NiO cathode or TiO2 anode.

  18. Euhedral metallic-Fe-Ni grains in extraterrestrial samples

    Science.gov (United States)

    Rubin, Alan E.

    1993-01-01

    Metallic Fe-Ni is rare in terrestrial rocks, being largely restricted to serpentinized peridotites and volcanic rocks that assimilated carbonaceous material. In contrast, metallic Fe-Ni is nearly ubiquitous among extraterrestrial samples (i.e., meteorites, lunar rocks, and interplanetary dust particles). Anhedral grains are common. For example, in eucrites and lunar basalts, most of the metallic Fe-Ni occurs interstitially between silicate grains and thus tends to have irregular morphologies. In many porphyritic chondrules, metallic Fe-Ni and troilite form rounded blebs in the mesostasis because their precursors were immiscible droplets. In metamorphosed ordinary chondrites, metallic Fe-Ni and troilite form coarse anhedral grains. Some of the metallic Fe-Ni and troilite grains has also been mobilized and injected into fractures in adjacent silicate grains where local shock-reheating temperatures reached the Fe-FeS eutectic (988 C). In interplanetary dust particles metallic Fe-Ni most commonly occurs along with sulfide as spheroids and fragments. Euhedral metallic Fe-Ni grains are extremely rare. Several conditions must be met before such grains can form: (1) grain growth must occur at free surfaces, restricting euhedral metallic Fe-Ni grains to systems that are igneous or undergoing vapor-deposition; (2) the metal (+/-) sulfide assemblage must have an appropriate bulk composition so that taenite is the liquidus phase in igneous systems or the stable condensate phase in vapor-deposition systems; and (3) metallic Fe-Ni grains must remain underformed during subsequent compaction, thermal metamorphism, and shock. Because of these restrictions, the occurrence of euhedral metallic Fe-Ni grains in an object can potentially provide important petrogenetic information. Despite its rarity, euhedral metallic Fe-Ni occurs in a wide variety of extraterrestrial materials. Some of these materials formed in the solar nebula; others formed on parent body surfaces by meteoroid

  19. Los niños y los videojuegos

    OpenAIRE

    Orrego Gaviria, Jaime; Fundación Valle de Lili

    2007-01-01

    Los niños y los videojuegos / Efectos perjudiciales de la utilización de los videojuegos por los niños y adolescentes/ Efectos benéficos de la de la utilización de los videojuegos por los niños y adolescentes/ Recomendaciones para favorecer el uso adecuado/ Sistema de clasificación de los videojuegos

  20. Microstructures in rapidly solidified Ni-Mo alloys

    Science.gov (United States)

    Jayaraman, N.; Tewari, S. N.; Hemker, K. J.; Glasgow, T. K.

    1986-01-01

    Ni-Mo alloys of compositions ranging from pure Ni to Ni-40 at. percent Mo were rapidly solidified by Chill Block Melt Spinning in vacuum and were examined by optical metallography, X-ray diffraction and transmission electron microscopy. Rapid solidification resulted in an extension of molybdenum solubility in nickel from 28 to 37.5 at. percent. A number of different phases and microstructures were seen at different depths (solidification conditions) from the quenched surface of the melt spun ribbons.

  1. Multicoloured electrochromic thin films of NiO/PANI

    Energy Technology Data Exchange (ETDEWEB)

    Sonavane, A C; Patil, P S [Thin Film Materials Laboratory, Department of Physics, Shivaji University, Kolhapur-416 004 (India); Inamdar, A I [Department of Semiconductor Science, Dongguk University, Seoul 100-715 (Korea, Republic of); Deshmukh, H P, E-mail: patilps_2000@yahoo.co [Department of Physics, Y. M. College, Bharati Vidyapeeth, Erandwane, Pune (India)

    2010-08-11

    NiO/polyaniline (PANI) thin films have been prepared by a two-step process. NiO thin films were electrodeposited from an aqueous solution of NiCl{sub 2} {center_dot} 6H{sub 2}O at pH 7.5 on fluorine-doped tin oxide coated glass substrates and a layer of PANI was formed on NiO thin films by chemical bath deposition. The films were characterized for their structural, optical, morphological and electrochromic properties. X-ray diffraction and Fourier-transform infrared spectroscopy indicated the formation of NiO and PANI, in which NiO is of cubic structure. Scanning electron micrographs represent porous granular NiO, which get uniformly carpeted with PANI, leading to a matty morphology of NiO/PANI samples. The electrochromic performance of NiO/PANI films has been studied using cyclic voltammetry and chronoamperometry over the -1.2 to +2.2 V (versus saturated calomel electrode (SCE)) potential window in 1M LiClO{sub 4} + propylene carbonate. The NiO/PANI films exhibit electrochromism with colour that changes from pale yellow (leucoemeraldine base at -0.7 V versus SCE) to dark green (emeraldine salt at 0.4 V versus SCE) to purple (pernigraniline at 0.8 V versus SCE) in the reduced states and dark blue (nigraniline at 0.5 V versus SCE) to dark green (emeraldine salt at 0.1 V versus SCE) to light green (photoemeraldine at -0.3 V versus SCE) in its oxidized states. These colours, though akin to pure PANI, have higher contrast, high speed of operation and high stability, owing to the properties of NiO. The colouration efficiency of the NiO/PANI film was estimated to be 85 cm{sup 2} C{sup -1}.

  2. NiAl-based Polyphase in situ Composites in the NiAl-Ta-X (X = Cr, Mo, or V) Systems

    Science.gov (United States)

    Johnson, D. R.; Oliver, B. F.; Noebe, R. D.; Whittenberger, J. D.

    1995-01-01

    Polyphase in situ composites were generated by directional solidification of ternary eutectics. This work was performed to discover if a balance of properties could be produced by combining the NiAl-Laves phase and the NiAl-refractory metal phase eutectics. The systems investigated were the Ni-Al-Ta-X (X = Cr, Mo, or V) alloys. Ternary eutectics were found in each of these systems and the eutectic composition, temperature, and morphology were determined. The ternary eutectic systems examined were the NiAl-NiAlTa-(Mo, Ta), NiAl-(Cr, Al) NiTa-Cr, and the NiAl-NiAlTa-V systems. Each eutectic consists of NiAl, a C14 Laves phase, and a refractory metal phase. Directional solidification was performed by containerless processing techniques in a levitation zone refiner to minimize alloy contamination. Room temperature fracture toughness of these materials was determined by a four-point bend test. Preliminary creep behavior was determined by compression tests at elevated temperatures, 1100-l400 K. Of the ternary eutectics, the one in the NiAl-Ta-Cr system was found to be the most promising. The fracture toughness of the NiAl-(Cr, Al)NiTa-Cr eutectic was intermediate between the values of the NiAl-NiAlTa eutectic and the NiAl-Cr eutectic. The creep strength of this ternary eutectic was similar to or greater than that of the NiAl-Cr eutectic.

  3. Stress corrosion cracking of NiTi in artificial saliva.

    Science.gov (United States)

    Wang, Jianqiu; Li, Nianxing; Rao, Guangbin; Han, En-Hou; Ke, Wei

    2007-02-01

    This paper aimed to study the mechanism of the cracking of orthodontic NiTi wire. Two orthodontic NiTi wires were subjected: (1) optical and scanning electron microscopy (SEM) to observe the fracture surface; (2) energy dispersive X-ray spectroscopy to determine the composition of the surface product; (3) anodic polarization to remove the surface product. Samples of NiTi alloy were subjected to the constant loading test to study the stress corrosion cracking (SCC) behavior of NiTi shape memory alloy in artificial saliva. The results showed that there were three typical areas at the fracture surface of NiTi orthodontic wire. Area '1' was a tool-made notch. Crack initiated from the root of this notch and propagated to form Area '2', which was perpendicular to the wire axis and covered by surface film. This film consisted of Na, K, Cl, P, S and O except Ni and Ti. The cracking process of NiTi alloy under the constant loading test depended on the pH of saliva and applied stress. The crack length was about 262microm, the longest at 300MPa and pH 3.0. A tool-made notch in orthodontic NiTi wires can cause SCC. At high stress and low pH, this NiTi alloy was most sensitive to cracking.

  4. Structural and magnetic studies in Ni/Ti multilayers

    Science.gov (United States)

    Porte, M.; Lassri, H.; Krishnan, R.; Kâabouchi, M.; Mâaza, M.; Sella, C.

    1993-03-01

    Structural and magnetic studies have been carried out on Ni/Ti multilayers prepared by DC triode sputtering. Both metal layers are crystalline with a (111) fibre structure when they are thicker than 20 Å. But for thinner layers one observes a solid solution with an amorphous-like structure. The magnetization decreases with t(Ni) and the analysis of the results at 5 K indicates the presence of a dead Ni layer about 12 Å thick. The t(Ni) dependence of the effective anisotropy shows the absence of surface anisotropy contribution.

  5. Design and fabrication of Ni nanowires having periodically hollow nanostructures

    Science.gov (United States)

    Sada, Takao; Fujigaya, Tsuyohiko; Nakashima, Naotoshi

    2014-09-01

    We propose a concept for the design and fabrication of metal nanowires having periodically hollow nanostructures inside the pores of an anodic aluminum oxide (AAO) membrane using a sacrificial metal. In this study, nickel (Ni) and silver (Ag) were used as the base metal and the sacrificial metal, respectively. Alternating an applied potential between -0.4 and -1.0 V provided alternatively deposited Ni and Ag segments in a Ni-Ag `barcode' nanowire with a diameter of 18 or 35 nm. After etching away the Ag segments, we fabricated Ni nanowires with nanopores of 12 +/- 5.3 nm. Such nanostructure formation is explained by the formation of a Ni shell layer over the surface of the Ag segments due to the strong affinity of Ni2+ for the interior surfaces of AAO. The Ni shell layer allows the Ni segments to remain even after dissolution of the Ag segments. Because the electroplating conditions can be easily controlled, we could carefully adjust the size and pitch of the periodically hollow nanospaces. We also describe a method for the fabrication of Ni nanorods by forming an Ag shell instead of a Ni shell on the Ni-Ag barcode nanowire, in which the interior of the AAO surfaces was modified with a compound bearing a thiol group prior to electroplating.We propose a concept for the design and fabrication of metal nanowires having periodically hollow nanostructures inside the pores of an anodic aluminum oxide (AAO) membrane using a sacrificial metal. In this study, nickel (Ni) and silver (Ag) were used as the base metal and the sacrificial metal, respectively. Alternating an applied potential between -0.4 and -1.0 V provided alternatively deposited Ni and Ag segments in a Ni-Ag `barcode' nanowire with a diameter of 18 or 35 nm. After etching away the Ag segments, we fabricated Ni nanowires with nanopores of 12 +/- 5.3 nm. Such nanostructure formation is explained by the formation of a Ni shell layer over the surface of the Ag segments due to the strong affinity of Ni2+ for the

  6. Fiscal 1998 achievement report. Coal liquefaction technology development - Bituminous coal liquefaction technology development - Study for supporting pilot plant - Study using 1t/d PSU (Study of operation using PSU); 1998 nendo seika hokokusho. Sekitan ekika gijutsu kaihatsu - Rekiseitan ekika gijutsu no kaihatsu - Pilot plant no shien kenkyu - 1t/d process support unit (PSU) ni yoru kenkyu (PSU ni yoru unten kenkyu)

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1999-06-01

    The operation of a 1t/d PSU (process support unit) was studied for the NEDOL coal liquefaction process. For the modification of facilities, product oil reforming facilities were installed. In the coal injection operation, a 59-day slurry operation was carried out using Tanito Harum coal, which was for the evaluation of the reforming effect under the product reforming conditions, operationality, and liquefaction characteristics. A 37-day slurry operation was also performed using Chinese coal, which was intended to pursue improved cost performance and to collect the light oil fraction in the flow of reforming operation. In the operation for maintenance, investigations were conducted into conditions for hydrogenation in a 1-through operation involving the solvent hydrogenation process and the normal pressure distillation facilities and into the effect of pre-hydrogenation solvent properties, which aimed at grasping the effect of product oil reforming measures and their influence on operationality. In the survey of environments, the properties of wastewater from the liquefaction process using Tanito Harum coal were studied and toxicity evaluation tests were conducted for activated sludge. (NEDO)

  7. Fiscal 1997 achievement report. Coal liquefaction technology development - Bituminous coal liquefaction technology development - Study for supporting pilot plant - Study using 1t/d PSU (Study of operation using PSU); 1997 nendo seika hokokusho. Sekitan ekika gijutsu kaihatsu - Rekiseitan ekika gijutsu no kaihatsu - Pilot plant no shien kenkyu - 1t/d process support unit (PSU) ni yoru kenkyu (PSU ni yoru unten kenkyu)

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1998-03-01

    The operation of a 1t/d PSU (process support unit) was studied for the NEDOL coal liquefaction process. In the modification of facilities, equipment and devices were procured for the product oil reforming facilities and their installation was partly accomplished. In the coal injection operation, a 60-day slurry operation was conducted, using coal types of the upper limit and lower limit qualities, for expanding the scope of coal types applicable to the NEDOL process and for exploring optimum conditions, and another operation of 37 days was conducted using Chinese coal and Chinese-prepared liquefaction catalysts, and the two operations were studied for difference in yields and in operationality. Characteristics of the liquefaction reactors were investigated and basic studies were made relative to the physical property of the yielded coal oil. In the operation for maintenance, the 1st liquefaction reactor was singly operated for an 8-day slurry operation, which was to check the progress of liquefaction in a 1-reactor setup. Concerning the reforming of the product oil, the hydrogenation reactors were checked for their response to temperature control. Moreover, hydrogenation solvents were produced for the PSU and for China. (NEDO)

  8. Report on simple operation type CAD/CAM system development through international cooperation. Current statuses of Asian countries; 'Kan'i sosagata denshi sekkei seisan shien system no kaihatsu ni kansuru kenkyu kyoryoku' ni kansuru hokokusho. Asia shokoku no jokyo

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1995-03-01

    Information systems, mainly aided by computers, are becoming increasingly important, contributing to development of wide areas of societies and economics, to begin with. However, few developing countries have established sufficient information systems, in spite of their strong desires to do so, which will further widen the gap between them and advanced countries, where these systems are acceleratedly advancing. Given these situations, Center of International Cooperation for Computerization (CICC) has been implementing various projects for providing assistance to and cooperation with oversea countries which are trying to develop information systems. This report summarizes the project, which CICC has been commissioned by NEDO as part of the cooperation programs, for manufacturing technology supported by advanced and integrated information system through international cooperation. It outlines the research cooperation memoranda NEDO has concluded with Indonesia, Malaysia, Singapore and Thailand, and the authorities of China, Indonesia, Malaysia, Singapore and Thailand. (NEDO)

  9. Survey report for fiscal 1997 on the survey report on the actual state of technical cooperation on industrial technologies by European countries in the South-eastern Asian region; 1997 nendo Tonan Asia chiiki ni okeru Obei shokoku no sangyo gijutsu ni kansuru gijutsu kyoryoku jittai chosa hokokusho

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1998-03-01

    The actual state was surveyed on the technical cooperation by European countries in the South-eastern Asian region. The U.S.A. is making research cooperation with Thailand on ethylene molecule structures to enhance productivity in rubber production, France on molecule markers for high production rubber clone selection, and Australia on grain storing and drying methods. For the Philippines, America is giving assistance on management of reproducible resources, France on climate information communications systems for local areas, Australia on grain storing and drying methods, and Germany on waste oil recovery and reutilization, and development of pollution-free energy resources. For Malaysia, the Great Britain is cooperating on building engineering research centers, Australia on search for plant patheology genetic organics available in the Pacific region, and Germany on investigative researches on pollution prevention for tin mines and processing areas, and forestry and plant information systems. With respect to the ASEAN, this paper reports its activities placing importance on biology and electronics engineering, while the organization is taking actions in the areas of foodstuffs, animals, electronics, information and material science, energy exploration, marine and earth physics, and resource development. (NEDO)

  10. Fiscal 1997 survey report. Investigational study on the cascade utilization of thermal energy (cold heat and hot heat) (feasibility study by the off-line system); 1997 nendo chosa hokokusho. Netsu energy (reinetsu to onnetsu) no cascade riyo ni kansuru chosa kenkyu (off-line hoshiki ni yoru feasibility study)

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1998-03-01

    The paper studied a system to effectively use unused and low-grade thermal energy (cold heat and hot heat) in the Tokyo-Yokohama seaside area. For transportation of thermal energy, the batch transportation, that is, off-line system was discussed which uses insulated tank loaded barges and railroad freight trains. Thermal energy supply sources are 1) 0.3 million kW class thermal power plant, and 2) LNG storage base of 3 million ton/year class. Thermal energy users are Tokyo (Haneda) Airport D.H.C. (District Heating/Cooling Co.), MM 21 D.H.C. and Shin-Kawasaki D.H.C. The cold heat energy supplied to these three is about 1.5 million Mcal/daytimes300 days/year, and the hot heat energy supplied is about 1.33 million Mcal/daytimes150 days/year. Cold heat is obtained from seawater after the LNG vaporization, and hot heat from heat extracted from thermal turbine. Subcooled ice was selected for cold heat medium, and PCM-120A for hot heat medium. For batch transportation, an STL heat storage system is used which transports plastic capsules sealed with heat medium. Oil saving of 62,000 tons/year and CO2 reduction of about 53,000 tons/year can be expected. 85 figs., 98 tabs.

  11. Research report for fiscal 1998. Industrial circles' evaluation of the outcome of COP3 and their response thereto (France); 1998 nendo chosa hokokusho. COP3 no kekka ni taisuru sangyokai no hyoka oyobi kongo no taio ni tsuite (France)

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1999-03-01

    Since the CO{sub 2} emission reduction cost is high under the COP3 (Third Session of the Conference of the Parties to the United Nations Framework Convention on Climate Change) rulings, they have made it clear that they will positively resort to the flexibility mechanism. This is to reserve a room for freely selecting power generation methods other than nuclear technologies with their nuclear power plants scheduled for renovation in the neighborhood of 2010. But the industrial circles are slow in responding, failing to accept the carbon fund concept. As for measures for greenhouse gas emissions reduction, since they depend on energy saving for their success, the response specially of the transportation division will be the key. In the industrial division, success depends on a voluntary consensus among industries that consume much energy. As steps to economize the trend of people's energy consumption, an energy tax and environmental tax are scheduled to be imposed. An overall program for greenhouse gas emission reduction is being drafted by a government committee, with the outline to be made known in May 1999 for finalization in autumn the same year. A power market liberalization bill has already been prepared, and a decision will soon be made on a plan for the second phase targets. France with take part in COP5, Bonn, Germany, with a general proposal carrying what are stated above. (NEDO)

  12. Report on the survey in fiscal 1998. Evaluation by the industry on the result of COP3 and the future activities (Germany); 1998 nendo chosa hokokusho. COP3 no kekka ni taisuru sangyokai no hyoka oyobi kongo no taio ni tsuite (Doitsu)

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1999-03-01

    A survey was carried out on activities taken in Germany. The industry has a strong opinion to take voluntary regulations rather than those by laws. The nation's activities are being moved forward centrally with the suppression policies that follow the declaration on the voluntary regulation by the German industry to prevent global warming, which had been submitted by the German Industry Federation to the federal government in 1996. The participation to the declaration, which is optional, covers 71% of the energy consumption by manufacturing industries and 99% of the public electric power consumption, but large-scale industrial departments such as machine and electric power sectors who have not participated can also been found. The plan calls for reduction of inherent CO2 and energy per added value production amount in the entire industry by as much as 20% of the result in 1990 by 2005. According to the third party monitoring system employed by the federal government, the industry submits results of periodical analyses to the government. According to the result, the industries participated in the voluntary regulation have achieved annual exhaust suppression of 42 million tons during the period of 1990 to 1996. The public electric power industrial department whose CO2 emission accounts for a little less than 30% of the nation's total emission amount has a great effect. The industry is making efforts to improve the power generation efficiency aiming at reduction of CO2 emission of 12% of the 1990 result by 2015. (NEDO)

  13. Survey report for fiscal 1998. Survey of the current state and tasks of research and development of technologies for effectively utilizing CO{sub 2} fixation by higher vegetation; 1998 nendo chosa hokokusho. Koto shokubutsu ni okeru nisanka tanso koteika yuko riyo gijutsu no kenkyu kaihatsu no genjo to kadai ni kansuru chosa

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1999-03-01

    Investigations and studies are conducted seeking for a CO2 fixation method improved by utilizing the photosynthesizing function of higher vegetation. Details of higher vegetation genes are being disclosed thanks to the rapid progress of studies making use of molecular biological techniques, and the application of the genetic mechanism to scientific and technological fields is becoming increasingly feasible. In particular, the role of the CO2 fixation enzyme RuBisCO has been elucidated almost completely. It has been learned that, in terms of photosynthesizing capability, the C{sub 4} plants (corn etc.) are 2-3 times higher than the C{sub 3} plants (rice, wheat, etc.), and 5-10 times higher than the CAM plants (cactuses etc.). Studies are also under way about the rice genome so that a photosynthesizing capability so high as that of the C{sub 4} plants may be endowed the rice plant. The metabolism and control of useful substances produced in the CO2 fixation process etc. in the higher vegetation are being investigated, and it is now expected that some day such useful substances will be produced and utilized efficiently. Researches are under way into the relationship between the green leaf that is the organ that performs photosynthesis and the organ (sink) that stores and utilizes starch and sugar is in progress, and now a new field is going to open where vegetables will be fully utilized. (NEDO)

  14. Report for fiscal 1997 on simple operation type CAD/CAM system development through international cooperation. Committee activity record; 1997 nendo 'kan'i sosagata denshi sekkei seisan shien system no kaihatsu ni kansuru kenkyu kyoryoku' ni kansuru hokokusho. Iinkai katsudo kiroku

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1998-03-01

    This paper reports the research and development project for an electronics design and production aid system of simple operation type. The project (MATIC) has been executed to support works of Asian countries on the information society, and enhance levels of the manufacturing industries and supportive industries by utilizing the information technologies. Fiscal 1997 has entered full-fledged demonstration experiments, and decided the project directionality as a result of different committee activities as to policies, contents and promotion methods for research, development and demonstration experiments. The working group (WG) 1, composed of members having professional knowledge on automobiles and components thereof, has deliberated specific research and development items, promotion of the research and development, technical problems, promotion of joint researches with overseas countries. The WG II, composed of members having professional knowledge on household electric appliances and their parts, discussed promotion of research and development of household electric appliances and their parts. The WG III, composed of textile and apparel expertise members, made attempts in promoting the research and development of household electrid appliances and their parts. This paper describes other committee activities including promotion of operation and cooperation on production-based futuristic type integrated information system and MATIC technologies. (NEDO)

  15. Research achievement report for fiscal 1998 on the development of high-performance industrial furnaces. Research and development of high-performance industrial furnaces and the like (2); 1998 nendo koseino kogyoro no kaihatsu ni kansuru kenkyu seika hokokusho. Koseino kogyoro nado ni kansuru kenkyu kaihatsu (2)

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1999-03-01

    Volume 2 named above contains part of research achievement reports and individual research achievement reports. The aluminum melting furnace working group research achievement report covers aluminum melting furnace operating patterns, concentrated impinging flame mode and dispersed impinging flame mode, and honeycomb and ball structures in heat storing bodies. The tubular heater working group report mentions the application of this facility to oil heating furnaces, studies and investigations for the embodiment of real systems using the tubular heater, and tests conducted in a furnace with plural heating tube lines. The individual research achievement reports elaborate on the development of technologies of heat transfer optimization under unsteady conditions in the steel material heating process, research and development of high-efficiency heat transfer technologies, development of heating furnace geometry optimization technologies, research and development of a high-performance controlled atmosphere heat treatment furnace, development of high-efficiency heat transfer technologies in high-temperature jet flame heating, development of heat uniformity improvement technologies for example for the steel material heating process, construction of optimum combustion control technologies for the regenerative burner furnace, research concerning laser-aided measurement in industrial furnaces, etc. (NEDO)

  16. Achievement report for fiscal 1998 on the preceding research related to global environment industry technologies. Survey and research on reduction of nitrogen monoxide; 1998 nendo chikyu sangyo gijutsu ni kakawaru sendo kenkyu asanka chisso no haishutsu teigen ni kansuru chosa kenkyu seika hokokusho

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1999-03-01

    Nitrogen monoxide is a strong greenhouse effect gas having warming up index per molecule 300 times greater than that of CO2, and is designated as the object of reduction in the Kyoto Conference. The present preceding research discusses necessity of performing research and development works related to reducing the emission of nitrogen monoxide, and if it is necessary, places the final objective on proposition of what researches should be planned. Fiscal 1997 being the first fiscal year of the preceding research has surveyed emission amount from different emission sources, and enumerated the research and development assignments. Fiscal 1998 falling under the final fiscal year summarizes the emission amount including the future trends, surveys the feasibility of the promising technological measures through experiments, and proposed finally a research and development plan desired of implementation in the future. The proposal contains a research plan placing development of nitrogen monoxide decomposing catalysts and automobile catalysts as the main objectives. Among the domestic nitrogen monoxide generating sources, about 2/3 is the man-made generation sources, hence catalysts, if developed, may be applied to such facilities as combustion furnaces. (NEDO)

  17. Fiscal 1998 report on the research cooperation on development of the easy-to-operate electronic design and production support system (Joint research cooperation); 1998 nendo 'kan'i sosagata denshi sekkei seisan shien system no kaihatsu ni kansuru kenkyu kyoryoku' ni kansuru hokokusho (kyodo kenkyu kyoryoku)

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1999-03-01

    Asian countries are constructing information infrastructures actively in spite of severe financial and economic conditions in every country. For promoting advanced manufacturing industries and supporting industries of Asian countries by information technology, the research cooperation promotion project (MATIC) on the electronic design and production support system has been carried out as the joint research project of Japan, China, Indonesia, Malaysia, Singapore and Thailand. This project started as the 5-year project in 1994, and has developed and demonstrated the prototype electronic design and production support system in 3 fields of automobile, home appliance and fiber/apparel. In the final 1998, the R and D and demonstration test were carried out, and the project results were summarized. For discussing the research cooperation concretely with overseas countries, the overseas researchers were invited to Japan for explaining the research state in Japan, confirming the promotion states of each country, and discussing the research report, while Japanese researchers visited the concerned organizations in every country. (NEDO)

  18. FY 1997 report on the study on cryogenic aggregate target PLD process by multi-laser excitation for using gaseous materials; 1997 nendo chosa hokokusho (kitai genryo riyo no tame no taju laser reiki ni yoru gokuteion gyoshutai target PLD process ni kansuru kenkyu)

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1998-03-01

    This paper reports the result in fiscal 1995 of the study on PLD (pulse laser deposition) thin film formation process having been made since 1993. In fiscal 1995, the effect of irradiation of excimer laser and YGA(SHG) on ablation of aggregates of N2, CH4, Ar, Kr and Xe, and the effect of time-delayed irradiation of YGA(SHG) and KrF excimer laser on ablation of N2 aggregate were studied aiming at exciting ablation by cryogenic aggregate alone. Experimental results by a newly developed multi-laser excitation experiment equipment are as follows. Ablation was not caused by KrF excimer laser irradiation, while caused by YGA(SHG) irradiation. Ablation was caused by 1mm thick N2 or CH4 aggregate alone. Kr target was the most promising among rare gas solid targets expected as seed of ablation occurrence. Multi-irradiation showed a different ablation behavior as compared with single YGA(SHG) irradiation, and in some cases, multi-irradiation not increased scattering of particles. Time-delayed multi- irradiation (YGA(SHG) excitation after excimer excitation) was effective. 23 figs., 4 tabs.

  19. Fiscal 1998 research report. Survey on development and application of membranes with pores of micron to nano-meter sizes; 1998 nendo chosa kenkyu hokokusho. Makuro kara mikuro (nano mezo dai) size wo motsu, menburenmaku no kaihatsu narabi ni oyo ni kansuru chosa kenkyu

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1999-03-01

    Researches on preparation of membranes of various materials have been promoted by not systematic technique but separate techniques according to needs of concerned fields. To establish the efficient technique for membranes with pores of required uniform size according to needs of various industries, survey and study were made on process optimization and low-cost production method. Porous membrane is the leading candidate for new separation systems as separation medium in chemical industry, hot gas filtration for energy production and environmental purification engineering. The electrode, separator and gas storage medium of fuel cell vehicles and next-generation batteries require effective porous materials. The workshop on engineering porous materials held in May 1993 confirmed the time of following materials: High-efficiency gas separation membrane, chemical catalytic membrane, fuel cell electrode and absorbent for environmental purification. Development of inorganic membranes more excellent in high-temperature stability, strength, catalytic activity and corrosion resistance than previous polymer membranes is important. (NEDO)

  20. Report for fiscal 1997 on simple operation type CAD/CAM system development through international cooperation. Joint research cooperation; 1997 nendo 'kan'i sosagata denshi sekkei seisan shien system no kaihatsu ni kansuru kenkyu kyoryoku' ni kansuru hokokusho. Kyodo kenkyu kyoryoku

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1998-03-01

    This report describes Japan's joint researches with China, Indonesia, Malaysia, Singapore, and Thailand under the above-named project (MATIC) which were carried out in fiscal 1997. Scientists are invited to Japan from the above-named countries, to whom Japan's status of researches is explained and with whom discussion is conducted about progress in general and system development in those countries, and about verification tests. Japanese scientists visit research institutes of those countries so as to appraise the progress of researches and technological levels and to install computers for verification tests. Scientists visiting this country upon Japan's invitation and workshop held in Japan are enumerated below. Accepted by Working Group I (automobile and parts) are scientists from Indonesia and China and workshops from two countries; accepted by Working Group II (electrical home appliance) are scientists from Malaysia and workshops from five countries and then from four countries; and accepted by Working Group III (fiber and apparel) are scientists from China. Visits are made by the Working Groups to Thailand, Indonesia, Malaysia, Singapore, and China. (NEDO)

  1. Fiscal 1999 achievement report on regional consortium research and development project. Regional consortium research on energy (Research and development of biofuel production using highly functional bioreactor - 2nd year); 1999 nendo kokino bio reactor ni yoru bio nenryo seisan ni kansuru kenkyu kaihatsu seika hokokusho (dai 2 nendo)

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    2000-03-01

    Microbes capable of a high biodiesel fuel (BDF) yield from moisture-containing oils assumedly waste oil are investigated. Lipase attributed to Rhizopus oryzae exhibits a high reaction rate of not lower than 90%. The process functions even when microbes are immobilized by BSPs. BDF does not affect driving performance, and black smoke is reduced. A process basic to industrial production is developed by use of a fixed bed reactor. In the production of ethanol from starch thanks to plural kinds of glucoamylase producing yeast, ethanol is produced at a rate of 7-8% under microaerophilic conditions in both proliferation and fermentation periods, which means a success achieved in growing arming yeast equipped with enhanced functions. A 20-liter class bench plant is installed and immobilization by BSPs is tested, when no problem is detected. In a reaction involving these immobilized microbes, a reaction rate near 16% is achieved. In the production of ethanol by yeast immobilized by BSPs, use of a fuzzy control system is studied, and it is found that prolonged stability is available when glucose concentration is sustained at 10-20g/liter. (NEDO)

  2. Report for fiscal 1995 on simple operation type CAD/CAM system development through international cooperation. Cooperation for joint researches; 1995 nendo 'kan'i sosagata denshi sekkei seisan shien system no kaihatsu ni kansuru kenkyu kyoryoku' ni kansuru hokokusho. Kyodo kenkyu kyoryoku

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1996-03-01

    Reported herein are the joint research results of the project (manufacturing technology supported by advanced and integrated information system through international cooperation (MATIC)), implemented in China, Indonesia, Malaysia, Singapore and Thailand by Center of International Cooperation for Computerization, commissioned by NEDO. Japan invited researchers from each country to explain the research themes, and discussed construction of the systems in each country. Japanese experts visited the research institutes and cooperative works in these countries, to discuss the research cooperation themes, and survey the conditions and technical levels of these research institutes, and information infrastructures. The oversea researchers were invited to Japan for the MATIC international seminar, discussions for research cooperation themes, and MATIC cooperation promotion committee. Textile and apparel researchers were also invited from China. Japanese experts visited China, Indonesia, Malaysia, Singapore and Thailand for the on-the-spot surveys for each working group. (NEDO)

  3. Fiscal 1997 report on the results of the international standardization R and D. Study on optimizing design/evaluation technology using quality engineering; 1997 nendo seika hokokusho kokusai hyojun soseigata kenkyu kaihatsu. Hinshitsu kogaku ni yoru saitekika sekkei hyoka gijutsu ni kansuru kenkyu

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1998-03-01

    To take up methodology of quality engineering as ISO standards, the basic document was worked out which regulates general items for the method to evaluate the operation of various systems as function for proposal to ISO. A method is developed for evaluating the design quality by function and predicting/optimizing the quality of finished products. For the evaluation of slippage from ideal function, the SN ratio and Maharanobis`s distance are used. In the two basic working groups (WG), a document on general methods to evaluate function was made. To reinforce the basic document, WGs divided into five by content/business were set up. Each WG collected examples from the past, studied methods to evaluate function in each field, and recorded them in the document. Five experiments for each WG were conducted to verify effectiveness of the above-mentioned method to evaluate function recorded in the document. As a result, the draft to present to ISO was worked out since the experimental WGs proved the effectiveness of the method to evaluate function in each field. 85 refs., 147 figs., 185 tabs.

  4. Report for fiscal 1995 on simple operation type CAD/CAM system development through international cooperation. Committee activity record; 1995 nendo 'kan'i sosagata denshi sekkei seisan shien system no kaihatsu ni kansuru kenkyu kyoryoku' ni kansuru hokokusho. Iinkai katsudo kiroku

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1996-03-01

    This paper reports the committee activities in fiscal 1995 on research cooperation for developing an electronics design and production aid system of simple operation type (MATIC). This fiscal year has decided the directionality of MATIC promotion by activities carried out by the different committees. These activities relate to research and development themes, the basic policies of the research and development along with the themes, research and development themes linked with overseas countries, and promotion methods. The working group (WG)I has discussed and deliberated specific research and development items to promote research and development of automobiles and components thereof as the promotion theme, promotion of the research and development, and technical problems. The committee consists of researchers at the related corporations participated in MATIC. The WGII has taken up household appliances and parts thereof, and the WGIII textiles and apparels as the research and development themes, and given specific discussions for promoting the research and development. The paper also reports the activities taken by different committees for promotion of the production-based futuristic type integrated information system, and promotion of the MATIC technologies, operation and cooperation. (NEDO)

  5. Achievement report for fiscal 1998 on Simple Operation Type CAD/CAM System Development through International Cooperation; 1998 nendo 'kan'i sosagata denshi sekkei seian shien system no kaihatsu ni kansru kenkyu kyoryoku' ni kansuru hokokusho

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1999-03-01

    The subject project is implemented in the fields of automobiles and their parts, electrical home appliances and their parts, and textile and apparel. In the field of automobiles and their parts, a prototype is developed of an integrated information management system which is to serve between corporation head offices and assembling businesses overseas, and another prototype is developed of an inter-business technical data serving system which is to serve between overseas assembling businesses and supporting businesses, both involving Japan, Indonesia, and Thailand. In the field of electrical home appliances and their parts, a prototype is developed of an electronic catalog system in a joint endeavor with research institutes of Indonesia, Malaysia, Singapore, and Thailand, and a demonstration test is conducted. A design concurrent engineering system is developed by Japan and Malaysian research institutes. In the field of textile and apparel, prototypes are developed, by Japanese, Chinese, and Indonesian apparel manufactures, of an apparel manufacturing specification system, international EDI (electronic data interchange) system, translation system, and a CAD (computer-aided design)/CAM (computer-aided manufacturing) data interchange system. (NEDO)

  6. Hydride Reactivity of Ni-II-X-Ni-II Entities : Mixed-Valent Hydrido Complexes and Reversible Metal Reduction

    NARCIS (Netherlands)

    Gehring, Henrike; Metzinger, Ramona; Herwig, Christian; Intemann, Julia; Harder, Sjoerd; Limberg, Christian

    After the lithiation of PYR-H2 (PYR2-=[{NC(Me)C(H)C(Me)NC6H3(iPr)2}2(C5H3N)]2-), which is the precursor of an expanded beta-diketiminato ligand system with two binding pockets, its reaction with [NiBr2(dme)] led to a dinuclear nickel(II)bromide complex, [(PYR)Ni(mu-Br)NiBr] (1). The bridging bromide

  7. Viviendo con VIH/SIDA: Las voces ocultas de los niños y niñas afectados

    Directory of Open Access Journals (Sweden)

    Luz Adriana Aristizábal Becerra

    2012-01-01

    Full Text Available El VIH/SIDA no es solamente un problema de salud, sino también un problema social. Los primeros casos de VIH/SIDA en niños se describen en 1982 en Estados Unidos, y desde entonces el número de niños infectados y afectados continúa incrementándose, hasta convertirse en lo que en la actualidad se denota como una pandemia. Objetivo. Posibilitar un espacio para que los niños y niñas afectados por el VIH/SIDA, puedan expresar sus vivencias en torno al padecimiento propio y/o de sus padres. Metodología. Estudio de enfoque cualitativo con una orientación fenomenológica. Participaron 29 niños (68 % y 13 niñas (32 % de 4 a 17 años, quienes fueron visitados en sus entornos hogareños. Para evitar la revictimización se utilizaron estrategias lúdicas y juegos para conocer las voces ocultas de estos infantes. Resultados: los hallazgos se agruparon en tres categorías: 1. La orfandad, 2. Rechazo social, estigma y discriminación y 3. Servicios de Salud, donde en cada una se percibe la vivencia subjetiva de cada niño y niña entrevistado(a. Conclusiones: el estigma que ha revestido al VIH/SIDA dificulta considerablemente el desarrollo pleno de los niños y niñas, obstaculizando su libre expresión y crecimiento. Sus voces siguen estando ausentes en las políticas públicas, es por ello que este estudio resaltó las vivencias de los niños y niñas expresadas desde sus propias voces.

  8. Experimental study of the $^{66}$Ni$(d,p)^{67}$Ni one-neutron transfer reaction

    CERN Document Server

    Diriken, J.; Andreyev, A.N.; Antalic, S.; Bildstein, V.; Blazhev, A.; Darby, I.G.; De Witte, H.; Eberth, J.; Elseviers, J.; Fedosseev, V.N.; Flavigny, F.; Fransen, Ch.; Georgiev, G.; Gernhauser, R.; Hess, H.; Huyse, M.; Jolie, J.; Kröll, Th.; Krücken, R.; Lutter, R.; Marsh, B.A.; Mertzimekis, T.; Muecher, D.; Orlandi, R.; Pakou, A.; Raabe, R.; Randisi, G.; Reiter, P.; Roger, T.; Seidlitz, M.; Seliverstov, M.; Sotty, C.; Tornqvist, H.; Van De Walle, J.; Van Duppen, P.; Voulot, D.; Warr, N.; Wenander, F.; Wimmer, K.

    2015-01-01

    The quasi-SU(3) sequence of the positive parity $νg_{9/2}, d_{5/2}, s_{1/2}$ orbitals above the N=40 shell gap are assumed to induce strong quadrupole collectivity in the neutron-rich Fe (Z=26) and Cr (Z=24) isotopes below the nickel region. In this paper the position and strength of these single-particle orbitals are characterized in the neighborhood of $^{68}$Ni (Z=28,N=40) through the $^{66}$Ni($d,p$)$^{67}$Ni one-neutron transfer reaction at 2.95 MeV/nucleon in inverse kinematics, performed at the REX-ISOLDE facility in CERN. A combination of the Miniball $\\gamma$-array and T-REX particle-detection setup was used and a delayed coincidence technique was employed to investigate the 13.3-$\\mu$s isomer at 1007 keV in $^{67}$Ni. Excited states up to an excitation energy of 5.8 MeV have been populated. Feeding of the $νg_{9/2}$ (1007 keV) and $νd_{5/2}$ (2207 keV and 3277 keV) positive-parity neutron states and negative parity ($νpf$) states have been observed at low excitation energy. The extracted relativ...

  9. Transformation dynamics of Ni clusters into NiO rings under electron beam irradiation

    Energy Technology Data Exchange (ETDEWEB)

    Knez, Daniel, E-mail: daniel.knez@felmi-zfe.at [Institute of Electron Microscopy and Nanoanalysis, Graz University of Technology, Steyrergasse 17, 8010 Graz (Austria); Graz Centre for Electron Microscopy, Steyrergasse 17, 8010 Graz (Austria); Thaler, Philipp; Volk, Alexander [Institute of Experimental Physics, Graz University of Technology, Petersgasse 16, 8010 Graz (Austria); Kothleitner, Gerald [Institute of Electron Microscopy and Nanoanalysis, Graz University of Technology, Steyrergasse 17, 8010 Graz (Austria); Graz Centre for Electron Microscopy, Steyrergasse 17, 8010 Graz (Austria); Ernst, Wolfgang E. [Institute of Experimental Physics, Graz University of Technology, Petersgasse 16, 8010 Graz (Austria); Hofer, Ferdinand [Institute of Electron Microscopy and Nanoanalysis, Graz University of Technology, Steyrergasse 17, 8010 Graz (Austria); Graz Centre for Electron Microscopy, Steyrergasse 17, 8010 Graz (Austria)

    2017-05-15

    We report the transformation of nickel clusters into NiO rings by an electron beam induced nanoscale Kirkendall effect. High-purity nickel clusters consisting of a few thousand atoms have been used as precursors and were synthesized with the superfluid helium droplet technique. Aberration-corrected, analytical scanning transmission electron microscopy was applied to oxidise and simultaneously analyse the nanostructures. The transient dynamics of the oxidation could be documented by time lapse series using high-angle annular dark-field imaging and electron energy-loss spectroscopy. A two-step Cabrera-Mott oxidation mechanism was identified. It was found that water adsorbed adjacent to the clusters acts as oxygen source for the electron beam induced oxidation. The size-dependent oxidation rate was estimated by quantitative EELS measurements combined with molecular dynamics simulations. Our findings could serve to better control sample changes during examination in an electron microscope, and might provide a methodology to generate other metal oxide nanostructures. - Highlights: • Beam induced conversion of Ni clusters into crystalline NiO rings has been observed. • Ni clusters were grown with the superfluid He-droplet technique. • oxidizeSTEM was utilized to investigate and simultaneously oxidize these clusters. • Oxidation dynamics was captured in real-time. • Cluster sizes and the oxidation rate were estimated via EELS and molecular dynamics.

  10. Manejo del Niño Quemado

    OpenAIRE

    José Edmundo Sánchez-López

    2011-01-01

    Las quemaduras en la población infantil constituyen un serio problema debido al alto riesgo de mortalidad, presencia delesiones invalidantes, funcionales y estéticas; siendo una causa importante de muerte accidental en los niños. Los pediatrasdesempeñan un papel importante, instruyendo a los padres para la prevención de las quemaduras más comunes en losniños.Las quemaduras pueden producirse por agentes químicos, biológicos y físicos; los últimos constituyen la causa más frecuentede quemaduras...

  11. Recipročni model izgorelosti (RMI)

    OpenAIRE

    Pšeničny, Andreja

    2015-01-01

    Izgorelost bi najkrajše definirali kot kronično stanje skrajne psihofizične inčustvene izčrpanosti. Izgorevanje poteka v zaporednih fazah od stanja izčrpanosti preko stanja ujetosti do stanja adrenalne izgorelosti. Sindrom adrenalne izgorelosti je zadnja stopnja procesa izgorevanja, ko v telesu zaradi funkcionalne blokade hipotalamus-hipofizno-adrenalne osi nastopi sekundarna insuficienca kortizola. Izgorelost in depresija sta dve različni motnji, ki imata nekaj sorodnih simptomov, vendar obs...

  12. GOSPODARSKE KRIZE IN FINANČNI TRG

    OpenAIRE

    Žigon, Mihela

    2010-01-01

    Diplomsko delo zajema finančni trg, finančno krizo 2007-2009 in veliko depresijo, ki je sledila borznemu zlomu 1929. Zzajema delitev finančnega trga na trg kapitala in trg denarja, finančne instrumente, ki jih denarne in nedenarne inštitucije uporabljajo na finančnem trgu ter centralna banka, ki vodi denarno politiko in bi naj imela nadzor nad vsemi institucijami. Opisali smo obe krizi, njune začetke, kako sta se širili in razvijali ter kakšno vlogo so imele ZDA in politika njene centralne ba...

  13. Anomalous Hall effect in polycrystalline Ni films

    KAUST Repository

    Guo, Zaibing

    2012-02-01

    We systematically studied the anomalous Hall effect in a series of polycrystalline Ni films with thickness ranging from 4 to 200 nm. It is found that both the longitudinal and anomalous Hall resistivity increased greatly as film thickness decreased. This enhancement should be related to the surface scattering. In the ultrathin films (46 nm thick), weak localization corrections to anomalous Hall conductivity were studied. The granular model, taking into account the dominated intergranular tunneling, has been employed to explain this phenomenon, which can explain the weak dependence of anomalous Hall resistivity on longitudinal resistivity as well. © 2011 Elsevier Ltd. All rights reserved.

  14. PRAVNI IN ETIČNI VIDIK EVTANAZIJE

    OpenAIRE

    Šibila, Nina

    2010-01-01

    Diplomska naloga predstavlja pravni in etični vidik evtanazije ter kratek pregled stališč v današnjem času in skozi zgodovino. Sama beseda evtanazija je grškega izvora in v dobesednem prevodu pomeni lahko oziroma dobro smrt (eu - dobro, thanatos - smrt). V resnici gre za olajšanje trpljenja ali smrtnega boja umirajočega ali neozdravljivo bolnega na tak način, da umirajoči oziroma neozdravljivo bolni umre. To olajšanje trpljenja ali smrtnega boja je mogoče doseči tako, da bodisi nekaj stori...

  15. Dynamic properties of liquid Ni revisited

    Directory of Open Access Journals (Sweden)

    del Rio B. G.

    2017-01-01

    Full Text Available Liquid Ni has previously been studied by different approaches such as molecular dynamics simulations and experimental techniques including inelastic neutron and X-ray scattering. Although some puzzling results, such as the shape of the sound dispersion curve for q ≤ 1.0 Å−1, have already been sorted out, there still persist some discrepancies, among different studies, for greater q-values. We have performed ab initio simulation calculations which show how those differences can be reconciled. Moreover, we have found that the transverse current spectral functions have some features which, so far, had previously been shown by high pressure liquid metals.

  16. Suicidio en niños

    OpenAIRE

    Alma Reyes G; José Lempira Escobar Y; Mayela Valerio H

    1998-01-01

    Trata de un estudio estadístico realizado en Costa Rica por los doctores Alma Reyes, Lempira Escobar y Mayela Valerio, quienes revisaron 16 años de autopsias (1980-1996), encontrando que de 28.584 autopsias, 26 correspondieron a suicidios de niños menores de 13 años de edad. De los 26 casos, el mayor número se presentó entre 1988 y 1991 con 11 casos (42%)de estos 5 casos (19%) se presentaron en 1990. Predominó el sexo masculino con 20 casos y 6 casos fueron del sexo femenino. El mayor grupo d...

  17. The design of underwater superoleophobic Ni/NiO microstructures with tunable oil adhesion

    Science.gov (United States)

    Zhang, Enshuang; Cheng, Zhongjun; Lv, Tong; Li, Li; Liu, Yuyan

    2015-11-01

    Controlling oil adhesion in water is a fundamental issue in many practical applications for surfaces. Currently, almost all studies on underwater oil adhesion control are concentrated on regulating surface chemistry on polymer surfaces, and structure-dependent underwater oil adhesion is still rare, especially on inorganic materials. Herein, we report a series of underwater superoleophobic Ni/NiO surfaces with controlled oil adhesions by combining electro-deposition and heating techniques. The adhesive forces between an oil droplet and the surfaces can be adjusted from an extremely low (less than 1 μN) to a very high value (about 60 μN), and the tunable effect can be attributed to different wetting states that result from different microstructures on the surfaces. Moreover, the oil-adhesion controllability for different types of oils was also analyzed and the applications of the surface including oil droplet transportation and self-cleaning were discussed. The results reported herein provide a new feasible method for fabrication of underwater superoleophobic surfaces with controlled adhesion, and improve the understanding of the relationship between surface microstructures, adhesion, and the fabrication principle of tunable oil adhesive surfaces.Controlling oil adhesion in water is a fundamental issue in many practical applications for surfaces. Currently, almost all studies on underwater oil adhesion control are concentrated on regulating surface chemistry on polymer surfaces, and structure-dependent underwater oil adhesion is still rare, especially on inorganic materials. Herein, we report a series of underwater superoleophobic Ni/NiO surfaces with controlled oil adhesions by combining electro-deposition and heating techniques. The adhesive forces between an oil droplet and the surfaces can be adjusted from an extremely low (less than 1 μN) to a very high value (about 60 μN), and the tunable effect can be attributed to different wetting states that result from

  18. Achievement report for fiscal 1997 on research and development of solid electrolyte fuel cells; Kotai denkaishitsugata nenryo denchi no kenkyu kaihatsu 1997 nendo seika hokokusho

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1998-07-01

    This paper describes the achievements in fiscal 1997 on research and development of solid electrolyte fuel cells. Fuji Electric has demonstrated possibilities of film type cells of predominantly metallic flat plate supporting type of a large-area cell lamination system, and seal-less stack structure. Sanyo Electric has discussed making thinner the composite cell lamination type anode, optimization in sintering temperature, and sealing materials. The Fine Ceramic Center has performed a 1,000-hour test on an La(Sr) MnO{sub 3}-YSZ electrode, in which A-site defect amount was decreased to 0.1-0.02 to stabilize micro-structure air electrodes for an extended period of time. Fujikura has discussed functional materials for high dispersion and slanting in a fuel electrode Ni/YSZ. Mitsubishi Heavy Industries has fabricated MgO-based fuel electrodes on a trial basis, and performed internal reformation and power generation tests by using full-size stacks. Murata Manufacturing Company has verified long-term power generation properties and stability of a three-layered co-sintered film of flat plate type. Mitsui Shipbuilding has reached a near final conclusion on the basic structure of gas separator cells. The Central Electric Power Research Institute has completed a conceptual design on a 300-MW class composite power generation system in which SOFC and gas turbines are combined. The Electric Power Development Company has discussed problems in SOFC composite power generation development using coal gasified fuel. (NEDO)

  19. Low temperature diffusion coefficients in the Fe-Ni and FeNiP systems: Application to meteorite cooling rates

    Science.gov (United States)

    Dean, D. C.; Goldstein, J. I.

    1984-01-01

    The interdiffusion coefficient of FeNi in fcc taenite (gamma) of Fe-Ni and Fe-Ni-0.2 P alloys was measured as a function of temperature between 600 and 900 C. This temperature range is directly applicable to the nucleation and growth of the Widmanstatten pattern in iron meteorites and metal regions of stony and stony-iron meteorites. Diffusion couples were made from FeNi or FeNiP alloys which ensured that the couples were in the taenite phase at the diffusion temperature. The presence or absence of grain boundary diffusion was determined by measuring the Ni profile normal to the existing grain boundaries with the AEM. Ignoring any variation of interdiffusion coefficient with composition, the measured data was plotted versus the reciprocal of the diffusion temperature. The FeNi data generally follow the extrapolated Goldstein, et al. (1965) data from high temperatures. The FeNiP data indicates that small additions of P (0.2 wt%) cause a 3 to 10 fold increase in the FeNi interdifussion coefficient increasing with decreasing temperature. This increase is about the same as that predicted by Narayan and Goldstein (1983) at the Widmanstatten growth temperature.

  20. Ni ion release, osteoblast-material interactions, and hemocompatibility of hafnium-implanted NiTi alloy.

    Science.gov (United States)

    Zhao, Tingting; Li, Yan; Zhao, Xinqing; Chen, Hong; Zhang, Tao

    2012-04-01

    Hafnium ion implantation was applied to NiTi alloy to suppress Ni ion release and enhance osteoblast-material interactions and hemocompatibility. The auger electron spectroscopy, x-ray photoelectron spectroscopy, and atomic force microscope results showed that a composite TiO(2)/HfO(2) nanofilm with increased surface roughness was formed on the surface of NiTi, and Ni concentration was reduced in the superficial surface layer. Potentiodynamic polarization tests displayed that 4 mA NiTi sample possessed the highest E(br) - E(corr), 470 mV higher than that of untreated NiTi, suggesting a significant improvement on pitting corrosion resistance. Inductively coupled plasma mass spectrometry tests during 60 days immersion demonstrated that Ni ion release rate was remarkably decreased, for example, a reduction of 67% in the first day. The water contact angle increased and surface energy decreased after Hf implantation. Cell culture and methyl-thiazol-tetrazolium indicated that Hf-implanted NiTi expressed enhanced osteoblasts adhesion and proliferation, especially after 7 days culture. Hf implantation decreased fibrinogen adsorption, but had almost no effect on albumin adsorption. Platelets adhesion and activation were suppressed significantly (97% for 4 mA NiTi) and hemolysis rate was decreased by at least 57% after Hf implantation. Modified surface composition and morphology and decreased surface energy should be responsible for the improvement of cytocompatibility and hemocompatibility. Copyright © 2011 Wiley Periodicals, Inc.

  1. Pautas para fomentar la autoestima en niños y niñas con discapacidad motora

    OpenAIRE

    Yagüe Lobo, Delia

    2014-01-01

    El informe aborda las pautas de actuación necesarias para trabajar la autoestima en niños y niñas con discapacidad motora y, por ello, se proponen pautas a desarrollar en distintos ámbitos, tanto en el aula como en el hogar. Se facilitan diferentes propuestas de actuación para la intervención individualiza-da en un aula ordinaria. Las pautas de actuación se han organizado a partir de los com-ponentes de la autoestima. Las mismas van dirigidas a cualquier niño o niña con disca-pacidad motor...

  2. Photoelectrochemical Water Splitting Properties of Ti-Ni-Si-O Nanostructures on Ti-Ni-Si Alloy

    Directory of Open Access Journals (Sweden)

    Ting Li

    2017-10-01

    Full Text Available Ti-Ni-Si-O nanostructures were successfully prepared on Ti-1Ni-5Si alloy foils via electrochemical anodization in ethylene glycol/glycerol solutions containing a small amount of water. The Ti-Ni-Si-O nanostructures were characterized by field-emission scanning electron microscopy (FE-SEM, energy dispersive spectroscopy (EDS, X-ray diffraction (XRD, and diffuse reflectance absorption spectra. Furthermore, the photoelectrochemical water splitting properties of the Ti-Ni-Si-O nanostructure films were investigated. It was found that, after anodization, three different kinds of Ti-Ni-Si-O nanostructures formed in the α-Ti phase region, Ti2Ni phase region, and Ti5Si3 phase region of the alloy surface. Both the anatase and rutile phases of Ti-Ni-Si-O oxide appeared after annealing at 500 °C for 2 h. The photocurrent density obtained from the Ti-Ni-Si-O nanostructure photoanodes was 0.45 mA/cm2 at 0 V (vs. Ag/AgCl in 1 M KOH solution. The above findings make it feasible to further explore excellent photoelectrochemical properties of the nanostructure-modified surface of Ti-Ni-Si ternary alloys.

  3. Amorphous NiFe-OH/NiFeP Electrocatalyst Fabricated at Low Temperature for Water Oxidation Applications

    KAUST Repository

    Liang, Hanfeng

    2017-04-11

    Water splitting driven by electricity or sunlight is one of the most promising ways to address the global terawatt energy needs of future societies; however, its large-scale application is limited by the sluggish kinetics of the oxygen evolution reaction (OER). NiFe-based compounds, mainly oxides and hydroxides, are well-known OER catalysts and have been intensively studied; however, the utilization of the synergistic effect between two different NiFe-based materials to further boost the OER performance has not been achieved to date. Here, we report the rapid conversion of NiFe double hydroxide into metallic NiFeP using PH3 plasma treatment and further construction of amorphous NiFe hydroxide/NiFeP/Ni foam as efficient and stable oxygen-evolving anodes. The strong electronic interactions between NiFe hydroxide and NiFeP significantly lower the adsorption energy of H2O on the hybrid and thus lead to enhanced OER performance. As a result, the hybrid catalyst can deliver a geometrical current density of 300 mA cm–2 at an extremely low overpotential (258 mV, after ohmic-drop correction), along with a small Tafel slope of 39 mV decade–1 and outstanding long-term durability in alkaline media.

  4. Imaginarios sociales sobre el maltrato: Una mirada desde los niños y niñas

    OpenAIRE

    Ayala Zúñiga, Paola Andrea

    2006-01-01

    Tesis (Maestría en Educación y Desarrollo Humano). Universidad de Manizales.CINDE, 2006 En Colombia, un país de sinsabores y violencias, el fenómeno social del maltrato infantil no es un asunto “menor”, sino un factor desequilibrante en el futuro de su tejido social. La investigación “Imaginarios sobre el maltrato: Una mirada desde los niños y niñas” parte de la pertinencia de observar y escuchar a nuestros niños y niñas, desde los modos como estos perciben, entienden y sufren la cotidia...

  5. Formation of nickel germanides from Ni layers with thickness below 10 nm

    Energy Technology Data Exchange (ETDEWEB)

    Jablonka, Lukas; Kubart, Tomas; Primetzhofer, Daniel; Abedin, Ahmad; Hellström, Per-Erik; Östling, Mikael; Jordan-Sweet, Jean; Lavoie, Christian; Zhang, Shi-Li; Zhang, Zhen

    2017-03-01

    The authors have studied the reaction between a Ge (100) substrate and thin layers of Ni ranging from 2 to 10 nm in thickness. The formation of metal-rich Ni5Ge3Ni5Ge3 was found to precede that of the monogermanide NiGe by means of real-time in situ x-ray diffraction during ramp-annealing and ex situ x-ray pole figure analyses for phase identification. The observed sequential growth of Ni5Ge3Ni5Ge3 and NiGe with such thin Ni layers is different from the previously reported simultaneous growth with thicker Ni layers. The phase transformation from Ni5Ge3Ni5Ge3 to NiGe was found to be nucleation-controlled for Ni thicknesses <5 nm<5 nm, which is well supported by thermodynamic considerations. Specifically, the temperature for the NiGe formation increased with decreasing Ni (rather Ni5Ge3Ni5Ge3) thickness below 5 nm. In combination with sheet resistance measurement and microscopic surface inspection of samples annealed with a standard rapid thermal processing, the temperature range for achieving morphologically stable NiGe layers was identified for this standard annealing process. As expected, it was found to be strongly dependent on the initial Ni thickness

  6. Ternary Pd-Ni-P hybrid electrocatalysts derived from Pd-Ni core-shell nanoparticles with enhanced formic acid oxidation activity.

    Science.gov (United States)

    Liang, Xin; Liu, Bo; Zhang, Juntao; Lu, Siqi; Zhuang, Zhongbin

    2016-09-25

    Ternary Pd-Ni-P hybrid electrocatalysts were synthesized through low temperature phosphidation of Pd-Ni core-shell nanoparticles. They show enhanced formic acid electro-oxidation activity compared to Pd, Pd-Ni and Pd-P nanoparticles, which is ascribed to the synergistic effect of the Ni and P components with Pd.

  7. FY 1999 report on the results of the superconductive energy application technology development/research on a total system, etc. Survey of potentiality of the commercialization of superconductive technology, effects of the introduction, etc. (Future course of the superconductive technology development in Japan); 1999 nendo chodendo denryoku oryokuyo gijutsu kaihatsu total system nado no kenkyu. Chodendo gijutsu no jitsuyoka kanosei oyobi donyu koka nado no chosa (Nippon ni okeru chodendo gijutsu kaihatsu no kongo no hokosei)

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    2000-03-01

    By the use of superconductive technology, the following are aimed at: marked reduction in power loss of electrical equipment and power transmission path, and size/weight reduction in electrical devices by high current/magnetic flux density. The superconductive technology has advantages such as great energy saving effect, CO2 reduction and global environmental preservation. As an example, concerning the superconductive generator now being developed under the New Sunshine Project, power loss can be reduced by half, and by the use of high magnetic field, size/weight can be reduced such as reduction in rotor diameter and reduction in weight by half. Further, as an innovative system, cited are the superconducting magnetic energy storage system (SMES) and flywheel energy storage system. The superconducting magnetic levitation railway, medical use MRI, etc. have also innovativity which is difficult to get in the conventional technology. Effects are also expected of introducing the process development using superconducting magnet such as magnetic separation, electromagnetic metallurgy, electromagnetic agitation and monocrytal growth convection control. Also cited is Josephson electronic device. High performance SQUID in bio-magnetic/non-destructive inspection is also expected to be developed. (NEDO)

  8. In situ synchrotron X-ray diffraction study of deformation behavior and load transfer in a Ti2Ni-NiTi composite

    Science.gov (United States)

    Zhang, Junsong; Liu, Yinong; Ren, Yang; Huan, Yong; Hao, Shijie; Yu, Cun; Shao, Yang; Ru, Yadong; Jiang, Daqiang; Cui, Lishan

    2014-07-01

    The deformation behavior and load transfer of a dual-phase composite composed of martensite NiTi embedded in brittle Ti2Ni matrices were investigated by using in situ synchrotron x-ray diffraction during compression. The composite exhibits a stage-wise deformation feature and a double-yielding phenomenon, which were caused by the interaction between Ti2Ni and NiTi with alternative microscopic deformation mechanism. No load transfer occurs from the soft NiTi dendrites to the hard Ti2Ni matrices during the pseudoplastic deformation (detwinning) of NiTi, which is significantly different from that previously reported in bulk metallic glasses matrices composites.

  9. Fabrication and Gas-Sensing Properties of Ni-Silicide/Si Nanowires

    OpenAIRE

    Hsu, Hsun-Feng; Chen, Chun-An; Liu, Shang-Wu; Tang, Chun-Kai

    2017-01-01

    Ni-silicide/Si nanowires were fabricated by atomic force microscope nano-oxidation on silicon-on-insulator substrates, selective wet etching, and reactive deposition epitaxy. Ni-silicide nanocrystal-modified Si nanowire and Ni-silicide/Si heterostructure multi-stacked nanowire were formed by low- and high-coverage depositions of Ni, respectively. The Ni-silicide/Si Schottky junction and Ni-silicide region were attributed high- and low-resistance parts of nanowire, respectively, causing the re...

  10. NiO/LaNiO{sub 3} film electrode with binder-free for high performance supercapacitor

    Energy Technology Data Exchange (ETDEWEB)

    Liu, Xi; Du, Guo; Zhu, Jiliang, E-mail: jlzhu167@scu.edu.cn; Zeng, Zifan; Zhu, Xiaohong

    2016-10-30

    Graphical abstract: This figure shows the charge-discharge curves of the P{sub 0}, P{sub 5}, P{sub 10} and P{sub 15} electrodes at the current density of 0.5 A/g in 2 M KOH electrolyte, respectively. From the figure, the specific capacitance of P{sub 10} electrode is as high as 2030 F/g. - Highlights: • Novel NiO/LaNiO{sub 3} film electrode with binder-free was prepared by spin-coating technique. • The NiO/LaNiO{sub 3} electrode with appropriate LNO content exhibited a high specific capacitance of 2030 F/g at 0.5A/g and superior cycling stability (83% retention of the initial capacitance after 1000 cycles) in 2 M KOH aqueous solution. • The NiO is directly anchored on the Pt/Ti/SiO{sub 2}/Si(100) substratewith binder-free, which is favorable for obtaining a larger specific surface. - Abstract: NiO/LaNiO{sub 3} (NiO/LNO) film electrode was prepared by spin-coating technique on Pt/Ti/SiO{sub 2}/Si(100) substrates. The crystal structure and surface morphology were characterized by X-ray diffraction (XRD) and scanning electron microscopy (SEM), respectively. Cyclic voltammetry (CV), galvanostatic charge/discharge, electrochemical impedance spectroscopy (EIS) and cyclic charge-discharge measurements were employed to evaluate the electrochemical performance of the electrode. The effect of LNO layer on the performance of the NiO/LNO electrode was also investigated. The NiO/LNO electrode with appropriate LNO content possesses high specific capacitance (2030 F/g at 0.5 A/g) and good cyclability (specific capacitance retention of 83% after 1000 cycles). The present study suggests that NiO/LNO film is a promising electrode material for supercapacitor.

  11. Realizing NiO nanocrystals from a simple chemical method

    Indian Academy of Sciences (India)

    Department of Physics, Banaras Hindu University, Varanasi 221 005, India. MS received 25 June 2009; revised 28 August 2010. Abstract. Nanocrystalline NiO has been prepared successfully by a simple chemical route using NiCl2·6H2O and. NaOH aqueous solution at a temperature of 70°C. The prepared material has ...

  12. Large scale synthesis and characterization of Ni nanoparticles by ...

    Indian Academy of Sciences (India)

    WINTEC

    of the parameters on the particle size of Ni nanoparticles were studied and the referential process parameters were obtained. The morphology and structure of the ... analysis and infrared spectroscopy (IR). The results show that Ni ... such uses, nanoparticles with different purity, size, shape and structure will greatly influence ...

  13. Violencia sexual contra hombres y niños

    OpenAIRE

    Russell, Wynne

    2007-01-01

    Es bien sabido que los conflictos armados y la violencia sexual contra las mujeres y las niñas suelen ir de la mano. Lo que no se conoce tanto es que los conflictos armados y sus secuelas también suponen un peligro sexual para los hombres y los niños.

  14. Lanthanide Al-Ni base Ericsson cycle magnetic refrigerants

    Science.gov (United States)

    Gschneidner, Jr., Karl A.; Takeya, Hiroyuki

    1995-10-31

    A magnetic refrigerant for a magnetic refrigerator using the Ericsson thermodynamic cycle comprises DyAlNi and (Gd.sub.0.54 Er.sub.0.46)AlNi alloys having a relatively constant .DELTA.Tmc over a wide temperature range.

  15. Structural study of Novel (superhard) material: NiO

    Indian Academy of Sciences (India)

    Abstract. We have investigated the pressure-induced phase transition of NiO and other structural properties using three-body potential approach. NiO undergoes phase transition from B1 (rocksalt) to B2 (CsCl) structure associated with a sudden collapse in volume showing first-order phase transition. A theoretical study of ...

  16. Cd, Zn, Ni and Cu in the Indian Ocean

    NARCIS (Netherlands)

    Saager, Paul M.; Baar, Hein J.W. de; Howland, Robin J.

    1992-01-01

    Vertical profiles of dissolved Cd, Zn, Ni and Cu in the Northwest Indian Ocean (Arabian Sea) exhibit a nutrient type distribution also observed in other oceans. The area is characterized by strong seasonal upwelling and a broad oxygen minimum zone in intermediate waters. However, neither Cd, Zn, Ni

  17. "Dealloying" Phase Separation during Growth of Au on Ni(110)

    DEFF Research Database (Denmark)

    Nielsen, L. Pleth; Besenbacher, Flemming; Stensgaard, I.

    1995-01-01

    Combined scanning tunneling microscopy and ion-scattering studies have revealed a new "dealloying" phase transition during the growth of Au on Ni(110). The Au atoms, which initially alloy into the Ni(110) surface, phase separate into a vacancy-stabilized Au dimer-trimer chain structure at Au...

  18. Sodium-dodecyl-sulphate-assisted synthesis of Ni nanoparticles ...

    Indian Academy of Sciences (India)

    Stabilized nickel nanoparticles (SNNPs) were prepared using Ni(acac) 2 (acac = acetylacetonate) via a simplesolvothermal method. The synthesis of the nickel nanoparticles was performed in the presence of sodium dodecyl sulphate(SDS) of different concentrations (mole ratios of SDS:Ni(acac) 2 = 1:1, 2:1 and 4:1), as the ...

  19. Water dissociate on faceted NiO(111)

    Science.gov (United States)

    Liu, Lixia; Wang, Shuai; Liu, Shuming; Guo, Qinlin; Guo, Jiandong

    The interaction of water with metal oxide surface is important in heterogeneous catalysis, geochemistry, electrochemistry and corrosion science. It has been reported that water molecules physically absorb on NiO(100) surface while they dissociate as OH on NiO(111) surface. As a typical polar surface, NiO(111) is instable, and the polar compensation may lead to surface reconstruction, segregation of oxygen vacancies, or formation of facets. Faceted NiO(111) surface, consisting of Ni(100) or NiO(110) facets, introduces new surface states and provides complex chemical environment for water adsorption and dissociation. We prepare faceted NiO(111) films with different thickness and observe water dissociation on the surface. The dissociated OH can be detected at high temperature up to 700K on the thin film surface, while on the surface of relative thick film, the OH amount is significantly reduced and the thermo stability lowered. The morphology characterization of the film shows that the size and number density of the facets are thickness dependent - the thinner the films is, the smaller the facets are, and the higher the density of facets is. We conclude that the boundary sites on NiO(111) facilitate the dissociative adsorption of water. Chinese NSFC (11474334 & 11274237). This work is supported by Chinese NSFC (11474334 & 11274237).

  20. Giant magnetoresistance of electrodeposited Cu–Co–Ni alloy films

    Indian Academy of Sciences (India)

    Electrodeposition of CuCoNi alloys was performed in an acid–citrate medium. Nickel density parameter was varied in order to analyse its influence on the magnetoresistance. The structure and giant magneto- resistance (GMR) effect of CuCoNi alloys have been investigated. The maximum value for GMR ratio, at room ...

  1. Phytoremediation technologies for Ni ++ by water hyacinth | Hussain ...

    African Journals Online (AJOL)

    (desorption) of Ni++, 3 M HNO3 was used. Desorption capacity was 3.71 μg/g of ash. The results of comparative study show order of nickel phytoremediation from soil to be greater than that from water by adsorption which was greater than that from water by hydroponic study. For phytoremoval of Ni++ from soil and water, ...

  2. PtNi nanoparticles embedded in porous silica microspheres as ...

    Indian Academy of Sciences (India)

    Supported Pt-based alloy nanoparticles have attracted greater attention in catalysis due to their high activity, reduced cost, and easy recycling in chemical reactions. In this work, mesoporous SiO₂ microspheres were employed as support to immobilize PtNi alloy nanocatalysts with different mass ratios of Pt and Ni (1:0, 3:1, ...

  3. Microemulsion prepared Ni88Pt12 for methane cracking

    KAUST Repository

    Zhou, Lu

    2017-01-16

    Monodispersed NiPt nanoparticles of 10 nm were synthesized by water-in-oil microemulsion. The Ni-Pt alloy structure was stable during the thermal treatment between 330 and 1037 °C, whereas the relatively low temperature range of 600-700 °C was favorable for methane cracking to produce hydrogen and carbon nanotubes.

  4. Electrolytic deposition and corrosion resistance of Zn–Ni coatings ...

    Indian Academy of Sciences (India)

    Zn–Ni coatings were deposited under galvanostatic conditions on steel substrate (OH18N9). The influence of current density of deposition on the surface morphology, chemical and phase composition was investigated. The corrosion resistance of Zn–Ni coatings obtained at current density 10–25 mA cm-2 are measured, ...

  5. Sodium dodecyl sulfate-assisted synthesis of Ni nanoparticles ...

    Indian Academy of Sciences (India)

    31

    Sodium dodecyl sulfate-assisted synthesis of Ni nanoparticles: Electrochemical. 1 properties. 2. 3 ... presence of different concentrations of sodium dodecyl sulfate (SDS) (mole ratios of. 4. SDS:Ni(acac)2 = 1:1, ..... In our previous work, we presented that DMF could be act as a unique reducing agent for the. 12 reduction of ...

  6. Mechanical alloying of Fe?Ni based nanostructured magnetic materials

    Science.gov (United States)

    Du, S. W.; Ramanujan, R. V.

    2005-04-01

    Alloys with the composition Fe 40Ni 38B 18Mo 4, Fe 49Ni 46Mo 5 and Fe 42Ni 40B 18 were processed from elemental powders by mechanical alloying and the microstructure was studied by differential scanning calorimetry (DSC), X-ray diffractometer (XRD), scanning electron microscopy (SEM) and transmission electron microscopy (TEM) techniques. Nanocrystalline fcc solid solution was achieved as a result of mechanical alloying in all three alloy compositions and the grain size reduced to nanoscale but lattice strain was introduced. Molybdenum was found to affect the products of mechanical alloying, specifically, the Fe 3B phase formed in the Fe 42Ni 40B 18 alloy while no boride phase formed in the Fe 40Ni 38B 18Mo 4 alloy. SEM studies indicated that the presence of boron was found to make the milling process easier. Elemental mapping by SEM as well as XRD results showed that molybdenum does not dissolve easily in the Fe-Ni solid solution produced by milling. The DSC results suggested that an amorphous structure together with nanocrystals was obtained in the Fe 40Ni 38B 18Mo 4 and Fe 42Ni 40B 18 alloys. A two-stage crystallization process was found in the Fe 40Ni 38B 18Mo 4 and Fe 42Ni 40B 18 alloys, the presence of boron was found to make amorphization easier. TEM investigations were consistent with these XRD and DSC results. Heat-treated samples of the Fe 40Ni 38B 18Mo 4 and Fe 42Ni 40B 18 alloys milled for 100 h showed that molybdenum inhibited the grain growth. The saturation magnetization of the heat-treated Fe 40Ni 38B 18Mo 4 alloy milled for 100 h was stable, coercivity was reduced; on the other hand, the Ms of heat-treated Fe 42Ni 40B 18 alloy milled for 100 h decreased and the Hc increased. This difference in magnetic behavior is due to the alloying addition of molybdenum which affected the microstructural evolution during heat treatment, specifically by inhibition of the increase in grain size.

  7. Physical and mechanical metallurgy of NiAl

    Science.gov (United States)

    Noebe, Ronald D.; Bowman, Randy R.; Nathal, Michael V.

    1994-01-01

    Considerable research has been performed on NiAl over the last decade, with an exponential increase in effort occurring over the last few years. This is due to interest in this material for electronic, catalytic, coating and especially high-temperature structural applications. This report uses this wealth of new information to develop a complete description of the properties and processing of NiAl and NiAl-based materials. Emphasis is placed on the controlling fracture and deformation mechanisms of single and polycrystalline NiAl and its alloys over the entire range of temperatures for which data are available. Creep, fatigue, and environmental resistance of this material are discussed. In addition, issues surrounding alloy design, development of NiAl-based composites, and materials processing are addressed.

  8. Estudo da eletrocristalização de Ni e Ni-P sobre ultramicroeletrodo de platina Study of electrocrystallization of Ni and Ni-P on platinum ultramicroelectrode

    Directory of Open Access Journals (Sweden)

    Katlin Ivon Barrios Eguiluz

    2008-01-01

    Full Text Available This work describes a comparative study of the electrocrystallization of Ni and Ni-P on Pt ultramicroelectrodes using chronoamperometric measurements. It was possible to confirm that in all cases a progressive nucleation was the predominant mechanism. Moreover, the application of the Atomistic Theory to the experimental rate of nuclei formation showed that the number of atoms in the critical nucleus was zero, except for Ni-P on Pt at low overpotentials were a value of one was observed. Furthermore, the physical characterisation of the different deposits on Pt by atomic force microscopy allowed observing the coalescence of the hemispherical nuclei of Ni and Ni-P at t max thus confirming the results obtained from the current-time analysis.

  9. Functional textiles driven by transforming NiTi wires

    Directory of Open Access Journals (Sweden)

    Heller Luděk

    2015-01-01

    Full Text Available Over last ten years, we have carried out extensive research on the use of thin NiTi wires for advanced functional textiles. In this work we discuss general challenges and opportunities in the design, production and processing of NiTi textiles stemming from the fact that NiTi is martensitically transforming metal. As a case example, application of weft knitting technology to NiTi wires is discussed in detail covering technological aspects related to textile processing, shape setting as well as multiaxial thermomechanical properties of final products. Finally, two weft knitted NiTi textile proof-of-concepts with a promising application potential are presented. First, a textile based actuator with large strokes and low forces characteristics is introduced. Second, 3D textiles with temperature-adaptive cross-section height for applications in technical or protective textiles are described.

  10. Permeability studies on 3D Ni foam/graphene composites

    Science.gov (United States)

    Yang, Zhuxian; Chen, Hongmei; Wang, Nannan; Xia, Yongde; Zhu, Yanqiu

    2017-09-01

    This study investigates the permeability of new 3D Ni foam/graphene composites (Ni foam covered with graphene) using compressed air, Ar and N2 as the probe gases. The results show that the introduction of graphene on the surface of Ni foam via in situ chemical vapour deposition is not detrimental to the permeability of the composites; on the contrary, in some cases it improves permeability. A modified Ergun-type correlation has been proposed, which represents very well the permeability of the Ni foam/graphene composites, especially at flow rates higher than 0.3 m s-1. Further studies show that graphene also helps to improve the thermal conductivity of the composite. These results suggest that the graphene involvement will make the Ni foam/graphene composite a good candidate for potential applications such as filters or heat exchangers suitable for working under harsh conditions such as at high temperatures, in corrosive environments, etc.

  11. Effect of amount of glycine as fuel in obtaining nanocomposite Ni/NiO; Efeito da quantidade de glicina como combustivel na obtencao de nanocompositos Ni/NiO

    Energy Technology Data Exchange (ETDEWEB)

    Simoes, A.N.; Simoes, V.N.; Neiva, L.S.; Quirino, M.R.; Vieira, D.A.; Gama, L., E-mail: alluskynha@hotmail.co [Universidade Federal de Campina Grande (UFCG), PB (Brazil). Unidade Academica de Engenharia de Materiais

    2010-07-01

    This paper proposes to investigate the effect of the amount of glycine in obtaining nanocomposite Ni/NiO synthesized by combustion reaction technique. The amount of glycine used was calculated on the stoichiometric composition of 50% and 100%. Characterizations by X-ray diffraction (XRD), N2 adsorption by the BET method and scanning electron microscopy (SEM) were performed with powder of Ni/NiO result. The analysis of X-ray diffraction showed the presence of crystalline NiO phase in the presence of nickel as a secondary phase, whose amount increased with the amount of glycine. Increasing the concentration of glycine also caused an increase in surface area, which ranged from 1.1 to 1.4 m{sup 2}/g. The micrographs revealed the formation of soft agglomerates with porous appearance and easy dispersions. It can be concluded that the synthesis is effective to obtain nanosized powders. (author)

  12. Hydrides of CeNi/sub 5/, MmNi/sub 5/, Ca/sub 0/ /sub 2/(Ce/sub 0/ /sub 65/Mm/sub 0/ /sub 35/)/sub 0/ /sub 8/Ni/sub 5/, Ca/sub 0/ /sub 2/Ce/sub 0/ /sub 8/Ni/sub 5/, Ca/sub 0/ /sub 2/Mm/sub 0/ /sub 8/Ni/sub 5/, and mixed CeNi/sub 5//MmNi/sub 5/

    Energy Technology Data Exchange (ETDEWEB)

    Lakner, J.F.; Chow, T.S.

    1982-09-01

    Six intermetallic alloys (CeNi/sub 5/, MmNi/sub 5/, Ca/sub 0/ /sub 2/(Ce/sub 0/ /sub 65/Mm/sub 0/ /sub 35/)/sub 0/ /sub 8/Ni/sub 5/, Ca/sub 0/ /sub 2/Ce/sub 0/ /sub 8/Ni/sub 5/, Ca/sub 0/ /sub 2/Mm/sub 0/ /sub 8/Ni/sub 5/, and a mixed alloy, CeNi/sub 5//MmNi/sub 5/) were investigated with respect to their suitability to provide high hydrogen capacity and their potential for use in providing substantial hydrogen pressure at both low and high temperatures. A second phase of our investigation dealt with ball-milling and hydriding and dehydriding cycles to produce fine particles for use in hydride powder transfer studies. A summary of several Van't Hoff plots is also included for hydride-forming alloys.

  13. Absence of Ni on the outer surface of Sr doped La 2 NiO 4 single crystals

    KAUST Repository

    Burriel, Mónica

    2014-01-01

    A combination of surface sensitive techniques was used to determine the surface structure and chemistry of La2-xSrxNiO 4+δ. These measurements unequivocally showed that Ni is not present in the outermost atomic layer, suggesting that the accepted model with the B-site cations exposed to the environment is incorrect. © 2014 The Royal Society of Chemistry.

  14. Semitransparent Ni/Ag/Ni electrode for use as anode in flexible red phosphorescent organic light-emitting diodes.

    Science.gov (United States)

    Lee, Ho Won; Yang, Hyung Jin; Lee, Seok Jae; Lee, Song Eun; Koo, Ja Ryong; Yoon, Seung Soo; Park, Jaehoon; Kim, Young Kwan

    2014-11-01

    We suggested that Ni/Ag/Ni semitransparent electrodes for the exchange of indium-tin-oxide (ITO) electrode, which is the most commonly used as a transparent electrode in spite of the structural defects, limited supply of indium, and toxic, could be apply on flexible Organic Light-Emitting Diodes (OLEDs). Red phosphorescent OLEDs (PHOLEDs) using different types of electrodes as ITO and various conditions of Ni/Ag/Ni electrode were fabricated and analyzed. The electrical and optical properties of device using Ni/Ag/Ni electrode were improved than that of devices on ITO glass substrate at the 10,000 cd/m2 criterion due to the micro-cavity effect even though their transmittance has lower than ITO glass. In addition, we also fabricated red PHOLEDs of same structure on Ni/Ag/Ni flexible substrate of various conditions. As a result, flexible red PHOLED showed competitive characteristics compared to the device on a glass substrate. Therefore, this study could be suggested to additional research on flexible OLEDs display and light applications for ITO-free fabrication.

  15. Multilevel programming in Cu/NiO y /NiO x /Pt unipolar resistive switching devices

    Science.gov (United States)

    Sarkar, P. K.; Bhattacharjee, S.; Barman, A.; Kanjilal, A.; Roy, A.

    2016-10-01

    The application of a NiO y /NiO x bilayer in resistive switching (RS) devices with x > y was studied for its ability to achieve reliable multilevel cell (MLC) characteristics. A sharp change in resistance brought about by sweeping the voltage, along with an improved on/off ratio (>103) and endurance (104) were achieved in the bilayer structure as compared to the single NiO x layer devices. Moreover, it was found that nonvolatile and stable resistance levels, especially the multiple low-resistance states of Cu/NiO y /NiO x /Pt memory devices, could be controlled by varying the compliance current. All the multilevel resistance states of the Cu/NiO y /NiO x /Pt bilayer devices were stable for up to 500 consecutive dc switching cycles, as compared to the Cu/NiO x /Pt single layer devices. The temperature-dependent variation of the high and low resistance states of both the bilayer and single layer devices was further investigated to elucidate the charge conduction mechanism. Finally, based on a detailed analysis of the experimental results, comparisons of the possible models for RS in bilayer and single layer memory devices have also been discussed.

  16. Carbon supported Pd-Ni and Pd-Ru-Ni nanocatalysts for the alkaline direct ethanol fuel cell (DEFC)

    CSIR Research Space (South Africa)

    Mathe, MK

    2011-08-01

    Full Text Available Carbon supported Pd-Ni and Pd-Ru-Ni nanocatalysts were prepared by the chemical reduction method, using sodium borohydride and ethylene glycol mixture as the reducing agent. The catalytic activity towards ethanol electro-oxidation in alkaline medium...

  17. Derechos de niños y niñas: del discurso a la política local

    National Research Council Canada - National Science Library

    Ernesto Durán-Strauch

    2017-01-01

    ... cómo se han interpretado e incorporado los derechos de los niños y niñas en el diseño e implementación de la política, contrastando los hallazgos con lo planteado en la literatura como perspectiva de derechos...

  18. Studies on the valence electronic structure of Fe and Ni in FexNi1−x ...

    Indian Academy of Sciences (India)

    Studies on the valence electronic structure of Fe and Ni in FexNi1−x alloys. D K BASA1,∗. , S RAJ2, H C PADHI2, M POLASIK3 and F PAWLOWSKI3. 1Department of Physics, Utkal University, Bhubaneswar 751 004, India. 2Institute of Physics, Bhubaneswar 751 005, India. 3Faculty of Chemistry, Nicholas Copernicus ...

  19. Exchange bias coupling in NiO/Ni bilayer tubular nanostructures synthetized by electrodeposition and thermal oxidation

    Energy Technology Data Exchange (ETDEWEB)

    Yu, T., E-mail: work_tian@scu.edu.cn [College of Physical Science and Technology, Sichuan University, Chengdu 610064 (China); Zhang, Z.W.; Xu, Y.H. [College of Physical Science and Technology, Sichuan University, Chengdu 610064 (China); Liu, Y. [Analytical & Testing Center, Sichuan University, Chengdu 610064 (China); Li, W.J. [Beijing National Laboratory for Condensed Matter Physics, Institute of Physics, University of Chinese Academy of Sciences, Chinese Academy of Sciences, Beijing 100190 (China); Nie, Y.; Zhang, X. [College of Physical Science and Technology, Sichuan University, Chengdu 610064 (China); Xiang, G., E-mail: gxiang@scu.edu.cn [College of Physical Science and Technology, Sichuan University, Chengdu 610064 (China)

    2017-05-01

    In this paper, we reported the synthesis of NiO/Ni bilayer nanotubes by electrodeposition and thermal oxidation using anodic aluminum oxide templates. The morphology, structure, chemical composition and magnetic properties, especially magnetic exchange bias induced by subsequent magnetic field cooling, in this one-dimensional antiferromagnetic/ferromagnetic hybrid system were investigated. It was found that the effect of the annealing temperature, which mainly dominated the thickness of the NiO layer, and the annealing time, which mainly dominated the grain size of the NiO, on the exchange bias field showed competitive relationship. The optimized exchange bias field was achieved by the combination of the shorter annealing time and higher annealing temperature. - Highlights: • NiO-Ni bilayer tubular nanotubes were fabricated by electrodeposition and thermal oxidation. • The exchange bias effect in NiO-Ni nanotubes was induced by magnetic field cooling. • The competitive effect of annealing temperature and annealing time on the exchange bias coupling was analyzed.

  20. Moderated surface defects of Ni particles encapsulated with NiO nanofibers as supercapacitor with high capacitance and energy density.

    Science.gov (United States)

    Zhang, Yifan; Park, Mira; Kim, Hak Yong; Park, Soo-Jin

    2017-08-15

    Nickel oxide is a promising material for supercapacitors owing to its high theoretical specific capacitance; however, its practical capacitance is far below the theoretical limit. In this work, we report a novel Ni/NiO composite supported by carbon nanofibers as a pseudocapacitor electrode. Characterization of this sample by X-ray diffraction, transmission electron microscopy, scanning electron microscopy, X-ray photoelectron spectroscopy, Brunauer-Emmett-Teller analysis, and contact angle measurements revealed that Ni nanoparticles were uniformly dispersed on the surface of the nanofibers, leading to strong metal-metal oxide interactions and the formation of oxygen vacancies. Such three dimensional hetero-Ni/NiO components afford high conductivity owing to efficient electron transport and abundant surface defects (oxygen vacancies), which result in enhanced supercapacitor performance and energy density (ED). A moderate concentration of oxygen vacancies is crucial for achieving optimized electrochemical activity. As-prepared Ni/NiO-3 nanofibers generated high capacitances of 526 and 400F/g at current densities of 1 and 10A/g, respectively, with good stability (80% of the initial capacitance retained after 1000 cycles). Moreover, an ED as high as 65.8Wh/kg was achieved at a power density of 900W/kg, which is higher than those of NiO-based supercapacitors. This work provides a strategy for improving the potential of metal oxides for energy storage applications. Copyright © 2017 Elsevier Inc. All rights reserved.

  1. Nucleation and Growth of Tetrataenite (FeNi) in Meteorites

    Science.gov (United States)

    Goldstein, J. I.; Williams, D. B.; Zhang, J.

    1992-07-01

    The mineral tetrataenite (ordered FeNi) has been observed in chondrites, stony irons, and iron meteorites (1). FeNi is an equilibrium phase in the Fe-Ni phase diagram (Figure 1) and orders to tetrataenite at ~320 degrees C (2). The phase forms at temperatures at or below the eutectoid temperature (~400 degrees C) where taenite (gamma) transforms to kamacite (alpha) plus FeNi (gamma"). An understanding of the formation of tetrataenite can lead to a new method for determining cooling rates at low temperatures (transformation sequences for the formation of tetrataenite were observed. In either sequence, during the cooling process, the taenite (gamma) phase initially undergoes a diffusionless transformation to a martensite (alpha, bcc) phase without a composition change. The martensite then decomposes either above or below the eutectoid temperature (~400 degrees C) during cooling or upon subsequent reheating. During martensite decomposition above the eutectoid, the taenite (gamma) phase nucleates by the reaction alpha(sub)2 ---> alpha + gamma and grows under volume diffusion control. The Ni composition of the taenite increases continuously following the equilibrium gamma/alpha + gamma boundary while the Ni composition of the kamacite matrix decreases following the alpha/alpha + gamma phase boundary (2), see Figure 1. Below the eutectoid temperature, the precipitate composition follows the equilibrium gamma"/alpha + gamma" boundary and reaches ~52 wt% Ni, the composition of FeNi, gamma". The kamacite (alpha) matrix composition approaches ~4 to 5 wt% Ni. The ordering transformation starts at ~320 degrees C forming the tetrataenite phase. During martensite decomposition below the eutectoid temperature, FeNi should form directly by the reaction alpha2 --> alpha + gamma" (FeNi). If this transformation sequence occurs, then the composition of kamacite and tetrataenite should also be given by the alpha/alpha + gamma" and gamma"/alpha + gamma" boundaries of the Fe-Ni phase

  2. Pt content of Cu-Ni deposits and ore occurrences in the Stanovoi Ni-bearing province (Far East, Russia)

    Science.gov (United States)

    Melnikov, A. V.; Strikha, V. E.; Moiseenko, V. G.

    2017-12-01

    Data on the Pt content in Cu-Ni deposits and ore occurrences of the Stanovoi Ni-bearing province of the Upper Amur Region are reported. Description and comparative analysis of the deposits and ore occurrences of the Pt-bearing Cu-Ni ores have been carried out taking into account new data on the ore geology, geochemistry, and material composition. We have described the formation prerequisites, forecast, and search criteria for large deposits of Pt-bearing Cu-Ni ores in the Upper Amur Region: the geotectonic and structural position, deep structure, formational features, magmatism of the mineralization period, hydrothermal alterations of the rocks, mineral and geochemical assemblages, PGM typomorphism, etc. This paper emphasizes the considerable potential of the Upper Amur Cu-Ni ores in relation to the complex of useful mineral resources such as gold, PGEs, sulfur, and cobalt.

  3. Characterization and leaching of NiCd and NiMH spent batteries for the recovery of metals.

    Science.gov (United States)

    Pietrelli, L; Bellomo, B; Fontana, D; Montereali, M

    2005-01-01

    Since NiMH and NiCd batteries are still used in the electronic devices market, a treatment and recycling plant has many advantages both from the environmental and the economic points of view. Unfortunately, there is no relationship between shape, size and chemical composition of spent batteries, consequently the characterization and the leaching method of the starting material becomes an important step of the overall treatment process in choosing the best conditions for the selective separation of the metals by hydrometallurgy. Leaching at 20 degrees C with H(2)SO(4) 2M for about 2h seems to be a good solution in terms of cost and efficiency for both battery types. The hydroxide compounds can be readily leached while Ni present as metallic form requires more aggressive conditions due to kinetic constraints. In this paper, the characterization of NiMH and NiCd spent batteries and the results of leaching tests in different conditions are reported.

  4. Shape memory behavior of single crystal and polycrystalline Ni-rich NiTiHf high temperature shape memory alloys

    Science.gov (United States)

    Saghaian, Sayed M.

    NiTiHf shape memory alloys have been receiving considerable attention for high temperature and high strength applications since they could have transformation temperatures above 100 °C, shape memory effect under high stress (above 500 MPa) and superelasticity at high temperatures. Moreover, their shape memory properties can be tailored by microstructural engineering. However, NiTiHf alloys have some drawbacks such as low ductility and high work hardening in stress induced martensite transformation region. In order to overcome these limitations, studies have been focused on microstructural engineering by aging, alloying and processing. Shape memory properties and microstructure of four Ni-rich NiTiHf alloys (Ni50.3Ti29.7Hf20, Ni50.7Ti 29.3Hf20, Ni51.2Ti28.8Hf20, and Ni52Ti28Hf20 (at. %)) were systematically characterized in the furnace cooled condition. H-phase precipitates were formed during furnace cooling in compositions with greater than 50.3Ni and the driving force for nucleation increased with Ni content. Alloy strength increased while recoverable strain decreased with increasing Ni content due to changes in precipitate characteristics. The effects of the heat treatments on the transformation characteristics and microstructure of the Ni-rich NiTiHf shape memory alloys have been investigated. Transformation temperatures are found to be highly annealing temperature dependent. Generation of nanosize precipitates (˜20 nm in size) after three hours aging at 450 °C and 550 °C improved the strength of the material, resulting in a near perfect dimensional stability under high stress levels (> 1500 MPa) with a work output of 20-30 J cm- 3. Superelastic behavior with 4% recoverable strain was demonstrated at low and high temperatures where stress could reach to a maximum value of more than 2 GPa after three hours aging at 450 and 550 °C for alloys with Ni great than 50.3 at. %. Shape memory properties of polycrystalline Ni50.3Ti29.7 Hf20 alloys were studied via

  5. Neutron enrichment at midrapidity in {sup 58}Ni + {sup 58}Ni at 52 MeV/u

    Energy Technology Data Exchange (ETDEWEB)

    Theriault, D.; Vallee, A.; Gingras, L.; Larochelle, Y.; Roy, R.; April, A.; Beaulieu, L.; Grenier, F.; Lemieux, F.; Moisan, J.; Samri, M.; Saint-Pierre, C.; Turbide, S. [Laval Univ., Lab. de Physique Nucleaire, Dept. de Physique, Quebec City, PQ (Canada); Yennello, S.J.; Martin, E.; Winchester, E. [Texas A and M Univ., College Station, TX (United States). Cyclotron Inst.

    2003-07-01

    By combining data from a charged particle {sup 58}Ni + {sup 58}Ni experiment at 52 MeV/u with an {sup 36}Ar + {sup 58}Ni experiment at 50 MeV/u for which free neutrons have been detected, an increase in the neutron to proton ratio of the whole nuclear material at midrapidity has been experimentally observed in the reaction {sup 58}Ni + {sup 58}Ni at 52 MeV/u. The neutron to proton ratio is measured above the initial neutron to proton ratio of the system. Neutron to proton ratio of the quasi-projectile emission is analysed for the same reactions and is seen to decrease below the ratio of the initial system. (authors)

  6. Migración con rostro de niños, niñas y adolescentes

    National Research Council Canada - National Science Library

    Álvaro Caballeros

    2011-01-01

    ... un panorama de la experiencia de la niñez migrante, las circunstancias del viaje, el proceso de deportación y de reinserción en sus países de origen. El autor señala que la atención y protección que reciben los niños, niñas y adolescentes por parte de autoridades migratorias y sociales ha mejorado considerablemente, sin embargo, no se adecúa al enfoque de derechos humanos. Palabras clave: Niñez migrante / deportación / Derechos Humanos 1. Introducción: la historia de Pablo Pablo1 es un niño migr...

  7. Influence of complex surface vibrations on the fusion of [sup 58]Ni+[sup 60]Ni

    Energy Technology Data Exchange (ETDEWEB)

    Stefanini, A.M.; Ackermann, D.; Corradi, L.; Napoli, D.R.; Petrache, C.; Spolaore, P.; Bednarczyk, P.; Zhang, H.Q. (Istituto Nazionale di Fisica Nucleare, Laboratori Nazionali di Legnaro, I-35020 Legnaro, Padova (Italy)); Beghini, S.; Montagnoli, G.; Mueller, L.; Scarlassara, F.; Segato, G.F.; Soramel, F. (Dipartimento di Fisica, Universita di Padova and Istituto Nazionle di Fisica Nucleare Sezione di Padova, I-35131, Padova (Italy)); Rowley, N. (Department of Physics and Astronomy, University of Manchester, Manchester M13 9PL (United Kingdom) Department of Physics, University of Surrey, Guildford GU2 5XH (United Kingdom))

    1995-02-06

    Fusion-evaporation cross sections for [sup 58]Ni+[sup 60]Ni have been measured with high accuracy in the energy range around the Coulomb barrier. The data yield an experimental distribution of fusion barriers'' around 13 MeV wide, which displays structure characteristic of strong phonon couplings with two large well resolved'' peaks, and a smaller peak at lower energies, which is essential for fitting the low-energy cross section. This is obtained only when the target and projectile double-phonon excitations are taken into account. This is the first time that such complex surface vibrations have been identified in a fusion experiment.

  8. Edge geometry effects on resonance response of electroplated cylindrical Ni/PZT/Ni magnetoelectric composites

    Directory of Open Access Journals (Sweden)

    Vladislav Yakubov

    2017-08-01

    Full Text Available Trilayer Ni/PZT/Ni cylindrical magnetoelectric (ME composites were prepared by electrodeposition, a process, which creates sub-millimeter raised edges due to current concentration near sharp points. The ME response in both axial and vertical modes was measured with the edges, with only outer edges removed, and with both outer and inner edges removed. The ME voltage coefficient improved at resonance by 40% and 147% without the edges in the vertical and axial modes, respectively. The observed improvements in three different samples were only present at the ME resonance and no changes were detected outside of the ME resonance. Mechanical quality factor at resonance also improved with no effect on the resonant frequency. Experimentally demonstrated minor geometry changes resulted in substantial ME improvement at resonant frequency. This study demonstrates device performance optimization. The observed effects have been attributed to improved vibrations in terms of decreased damping coefficient and enhanced vibration amplitude at resonance.

  9. Electrical permittivity of Ni and NiZn ferrite-polymer composites

    Energy Technology Data Exchange (ETDEWEB)

    Razzitte, A.C. [Laboratorio de Fisicoquimica de Materiales Ceramicos Electronicos (LAFMACEL), Departamento de Quimica, Universidad de Buenos Aires, Paseo Colon 850, Capital Fedcral 1063, Buenos Aires (Argentina)]. E-mail: arazzit@fi.uba.ar; Fano, W.G. [Departamento de Electronica, Facultad.de Ingenieria, Universidad de Buenos Aires, Paseo Colon 850, Capital Fedcral 1063, Buenos Aires (Argentina); Jacobo, S.E. [Laboratorio de Fisicoquimica de Materiales Ceramicos Electronicos (LAFMACEL), Departamento de Quimica, Universidad de Buenos Aires, Paseo Colon 850, Capital Fedcral 1063, Buenos Aires (Argentina)

    2004-12-31

    Electrical properties of polymers, well known for their insulating properties, may be improved by adding various functional fillers. Polymer-ferrite composites have been a subject of recent extensive research. Electric properties of such composites depend on the size, shape and amount of added filler in general. When polymer-ferrite composites are particularly used as electromagnetic wave absorbers and EMI shielding materials, it is very important to explain the variation of permeability and permittivity in the measured frequency ranges. In this paper, acrylic-Ni ferrite composites and acrylic-NiZn ferrite composites were used. The effects of the weight fraction of ferrite on the frequency dispersion characteristics of the complex permittivity are studied.

  10. Magnetoresistance Effect in NiFe/BP/NiFe Vertical Spin Valve Devices

    Directory of Open Access Journals (Sweden)

    Leilei Xu

    2017-01-01

    Full Text Available Two-dimensional (2D layered materials such as graphene and transition metal dichalcogenides are emerging candidates for spintronic applications. Here, we report magnetoresistance (MR properties of a black phosphorus (BP spin valve devices consisting of thin BP flakes contacted by NiFe ferromagnetic (FM electrodes. The spin valve effect has been observed from room temperature to 4 K, with MR magnitudes of 0.57% at 4 K and 0.23% at 300 K. In addition, the spin valve resistance is found to decrease monotonically as temperature is decreased, indicating that the BP thin film works as a conductive interlayer between the NiFe electrodes.

  11. Active Pt3Ni (111) Surface of Pt3Ni Icosahedron for Oxygen Reduction.

    Science.gov (United States)

    Zhu, Jianbing; Xiao, Meiling; Li, Kui; Liu, Changpeng; Zhao, Xiao; Xing, Wei

    2016-11-09

    Highly active, durable oxygen reduction reaction (ORR) electrocatalysts are extremely important for fuel cell applications. Herein, we provide an efficient way to synthesis of activity Pt 3 M icosahedra by the one-pot hydrothermal method in the presence of glucosamine which can well adjust the reduction rate of Pt 4+ and efficiently control the morphology of final catalysts. Compared to Pt/C, the Pt 3 Ni icosahedra show 32-fold and 12-fold enhancement in specific and mass activity, respectively. Furthermore, robust durability was also observed in the accelerated durability test. Thus, this Pt 3 Ni icosahedron is found among the best Pt-based ORR catalysts, moreover, the findings also demonstrate how to mimic active extended surfaces in nanoscale.

  12. Percepciones en salud bucal de los niños y niñas

    OpenAIRE

    Catalina González-Penagos, Colombia.; Melissa Cano-Gómez, Colombia.; Edwin J. Meneses-Gómez, Colombia.; Annie M. Viva res-Builes, Colombia.

    2015-01-01

    (analítico): Identificamos las necesidades de salud bucal de los niños y niñas de 2 a 5 años del programa Buen Comienzo-Fantasías de las Américas, desde la percepción de las agentes educativas en la ciudad de Medellín, en el año 2013. Realizamos un estudio cualitativo, con enfoque histórico hermenéutico; la población de estudio correspondió a 65 agentes educativas. Los resultados preliminares reflejan necesidades relacionadas con el acceso y oportunidad de atención odontológica, la deficienci...

  13. Equidad entre niñas y niños: situaciones didácticas

    Directory of Open Access Journals (Sweden)

    Antonio Paoli

    2010-01-01

    Full Text Available Este artículo presenta cuatro situaciones didácticas para la educación primaria, de cuarto y quinto grado en especial, y un conjunto de principios educativos; su finalidad es esclarecer y ejemplificar claves del programa educativo Jugar y vivir los valores (jvlv, orientadas a propiciar la equidad y la armonía entre los géneros. En este trabajo se muestran actividades prácticas que buscan explícitamente favorecer en las aulas la equidad de género: cuentos, canciones, preguntas a los niños para propiciar diálogos y conceptualizaciones surgidas de ellos, tareas familiares y reflexiones sobre la didáctica aplicada en la comunidad educativa, comunidad que incluye a maestros, padres de familia, niños y a todo el personal de la escuela. El Programa jvlv se creó en el Departamento de Educación y Comunicación de la uam-x, y hoy se aplica en más de 1000 primarias oficiales del estado de Chiapas. El programa se experimentó como programa piloto primero en diez jardines de niñas y niños en el año escolar 2001-2002, posteriormente en seis primarias oficiales en 2003-2004 y hoy se desarrolla un nuevo programa piloto en 52 primarias en los municipios de Tuxtla Gutiérrez y Suchiapa. La concepción de equidad se tiende a identificar con la de justicia, entendida como dar beneficio a los demás, al medio ambiente y a uno mismo. La equidad de género supone centrar la atención en hacer bien tanto a hombres como a mujeres, sistemáticamente.

  14. Electronic ground state of Ni$_2^+$

    CERN Document Server

    Zamudio-Bayer, V; Bülow, C; Leistner, G; Terasaki, A; Issendorff, B v; Lau, J T

    2016-01-01

    The $^{4}\\Phi_{9/2}$ ground state of the Ni$_2^+$ diatomic molecular cation is determined experimentally from temperature and magnetic-field-dependent x-ray magnetic circular dichroism spectroscopy in a cryogenic ion trap, where an electronic and rotational temperature of $7.4 \\pm 0.2$ K was achieved by buffer gas cooling of the molecular ion. The contribution of the magnetic dipole term to the x-ray magnetic circular dichroism spin sum rule amounts to $7\\, T_z = 0.17 \\pm 0.06$ $\\mu_B$ per atom, approximately 11 \\% of the spin magnetic moment. We find that, in general, homonuclear diatomic molecular cations of $3d$ transition metals seem to adopt maximum spin magnetic moments in their electronic ground states.

  15. Interface stress in Au/Ni multilayers

    DEFF Research Database (Denmark)

    Schweitz, K.O.; Böttiger, J.; Chevallier, J.

    2000-01-01

    The effect of intermixing on the apparent interface stress is studied in -textured dc-magnetron sputtered Au/Ni multilayers by use of two methods commonly used for determining interface stress. The method using profilometry and in-plane x-ray diffraction does not take intermixing...... into account and yields an apparent interface stress of -8.46 +/- 0.99 J m(-2). However, observed discrepancies between model calculations and measured high-angle x-ray diffractograms indicate intermixing, and by use of the profilometry and sin(2) psi method the real interface stress value of -2.69 +/- 0.43 J...... m(-2) is found. This method also reveals a significant and systematic change of the stress-free lattice parameter of both constituents as a function of modulation period which is shown to account for the difference between the two findings. The method using in-plane diffraction is thus shown...

  16. Residual stress in Ni-W electrodeposits

    DEFF Research Database (Denmark)

    Mizushima, Io; Tang, Peter Torben; Hansen, Hans Nørgaard

    2006-01-01

    In the present work, the residual stress in Ni–W layers electrodeposited from electrolytes based on NiSO4 and Na2WO4, is investigated. Citrate, glycine and triethanolamine were used as complexing agents, enabling complex formation between the nickel ion and tungstate. The results show that the type...... of complexing agent and the current efficiency have an influence on the residual stress. In all cases, an increase in tensile stress in the deposit with time after deposition was observed. Pulse plating could improve the stress level for the electrolyte containing equal amounts of citrate......,glycine and triethanolamine (TEA) as complexing agent. An additive as 1,3,6 naphthalene trisulphonic acid which has a grain refining effect, and chloride, which enables dissolution of metal during the anodic cycle, reduced crack occurrence in the electrodeposits....

  17. Ni/metal hydride secondary element

    Science.gov (United States)

    Bauerlein, Peter

    2005-04-19

    A Ni/metal hydride secondary element having a positive nickel hydroxide electrode, a negative electrode having a hydrogen storage alloy, and an alkaline electrolyte, the positive electrode, provided with a three-dimensional metallic conductive structure, also contains an aluminum compound which is soluble in the electrolyte, in addition to nickel hydroxide and cobalt oxide. The aluminum compound is aluminum hydroxide and/or aluminum oxide, and the mass of the aluminum compound which is present in the positive bulk material mixture is 0.1 to 2% by weight relative to the mass of the nickel hydroxide which is present. In combination with aluminum hydroxide or aluminum oxide, the positive electrode further contains lanthanoid oxidic compounds Y.sub.2 O.sub.3, La.sub.2 O.sub.3 and Ca(OH).sub.2, as well as mixtures of these compounds.

  18. Ignacio -Un niño especial-

    OpenAIRE

    Barzi, Silvia; Puyen, Paola; Mertehikian, Alida

    2009-01-01

    Paciente de 17 años de edad con diagnóstico de Síndrome de Alagille y Rubeola congénita. Derivado del Hospital de Niños “Sor María Ludovica” de La Plata al consultorio de Hepatología del HIGA “Prof. Dr. R. Rossi” de la misma ciudad por cirrosis descompensada. El síndrome de Alagille, diagnosticado a los dos años de edad, es un trastorno genético caracterizado por colestasis crónica por hipoplasia de las vías biliares intrahepáticas asociada a otras alteraciones como facie caracterís...

  19. Microstructure and property of directionally solidified Ni-Si hypereutectic alloy

    Science.gov (United States)

    Cui, Chunjuan; Tian, Lulu; Zhang, Jun; Yu, Shengnan; Liu, Lin; Fu, Hengzhi

    2016-03-01

    This paper investigates the influence of the solidification rate on the microstructure, solid/liquid interface, and micro-hardness of the directionally solidified Ni-Si hypereutectic alloy. Microstructure of the Ni-Si hypereutectic alloy is refined with the increase of the solidification rate. The Ni-Si hypereutectic composite is mainly composed of α-Ni matrix, Ni-Ni3Si eutectic phase, and metastable Ni31Si12 phase. The solid/liquid interface always keeps planar interface no matter how high the solidification rate is increased. This is proved by the calculation in terms of M-S interface stability criterion. Moreover, the Ni-Si hypereutectic composites present higher micro-hardness as compared with that of the pure Ni3Si compound. This is caused by the formation of the metastable Ni31Si12 phase and NiSi phase during the directional solidification process.

  20. Stoichiometry of LiNiO{sub 2} Studied by Moessbauer Spectroscopy

    Energy Technology Data Exchange (ETDEWEB)

    Ksenofontov, V.; Reiman, S.; Walcher, D.; Garcia, Y. [Johannes Gutenberg Universitaet, Institut fuer Anorganische Chemie und Analytische Chemie (Germany); Doroshenko, N. [A. A. Galkin Donetsk Physico-Technical Institute NAS of Ukraine (Ukraine); Guetlich, P. [Johannes Gutenberg Universitaet, Institut fuer Anorganische Chemie und Analytische Chemie (Germany)

    2002-03-15

    From the {sup 61}Ni and {sup 57}Fe Moessbauer spectroscopy data follows the cationic site assignment in Li{sub 1-x}Ni{sub 1+x}O{sub 2}. Our data explain the ferromagnetic properties of this material because of the appearance of Ni{sup 2+} (S=1) among Ni{sup 3+} (S=1/2) in Ni{sup 3+}O{sub 2} hexagonal planes. We have no evidence for the ferromagnetic interaction between the NiO{sub 2} layers through the excess Ni{sup 2+} ions substituting the Li{sup +} ions. The presence of Ni{sup 2+} found in the Ni{sup 3+}O{sub 2} planes explains the absence of the Jahn-Teller distortions probably because of the electronic transfer between the Ni{sup 3+} and Ni{sup 2+} ions.

  1. Study of the 66Ni(t,d)67Ni Transfer Reaction in Inverse Kinematics

    CERN Document Server

    Callens, Maarten

    The nickel isotopes with 28 protons are an interesting series in the study of nuclear structure. In the framework of the shell model nickel has a closed proton shell and the number of neutrons ranges from the magic numbers 20 to 50. The neutron-rich isotope $^{78}$Ni, is a waiting point in the nucleosynthesis r-process. In this process an intense neutron flux such as in supernovae results in the rapid capture of neutrons. The reaction sequence halts at $^{78}$Ni and waits for this nucleus to decay [Hea05]. For several decades the nickel isotopes have been studied extensively, particularly how the nuclear structure evolves when moving to the exotic boundaries of the nuclear chart. A remarkable feature was observed in $^{68}$Ni. This nucleus with 40 neutrons exhibits properties that are characteristic for doubly magic nuclei. Such as the energy of the first 2$^+$ state lies significantly higher than in neighbouring even-A isotopes, and is also higher than the energy of the second 0$^+$ state. Moreover also the ...

  2. Estilos parentales en niños y niñas con TDAH

    Directory of Open Access Journals (Sweden)

    Rocío González

    2014-01-01

    Full Text Available Introducción: el Trastorno por Déficit de Atención e Hiperactividad (TDAH es una de las alteraciones neuroconductuales más frecuentes en la infancia. La disfuncionalidad familiar es una variable de riesgo sobre la evolución de los síntomas. El objetivo fue analizar y comparar los estilos parentales en niños con y sin TDAH. Metodología: diseño expo facto con dos grupos, uno cuasi control. Se aplicaron dos escalas que evalúan estilos parentales. Resultados: tanto los niños con TDAH como sus padres perciben al estilo parental más rígido e indulgente y menos inductivo, caracterizado por una tendencia a manifestar mayor crítica y menor aceptación y afectuosidad por parte de los padres. Conclusiones: los hallazgos permiten el desarrollo de técnicas efectivas de disciplina y comunicación en la intervención clínica con familias de niños con TDAH.

  3. High-performance NiO/Ag/NiO transparent electrodes for flexible organic photovoltaic cells.

    Science.gov (United States)

    Xue, Zhichao; Liu, Xingyuan; Zhang, Nan; Chen, Hong; Zheng, Xuanming; Wang, Haiyu; Guo, Xiaoyang

    2014-09-24

    Transparent electrodes with a dielectric-metal-dielectric (DMD) structure can be implemented in a simple manufacturing process and have good optical and electrical properties. In this study, nickel oxide (NiO) is introduced into the DMD structure as a more appropriate dielectric material that has a high conduction band for electron blocking and a low valence band for efficient hole transport. The indium-free NiO/Ag/NiO (NAN) transparent electrode exhibits an adjustable high transmittance of ∼82% combined with a low sheet resistance of ∼7.6 Ω·s·q(-1) and a work function of 5.3 eV after UVO treatment. The NAN electrode shows excellent surface morphology and good thermal, humidity, and environmental stabilities. Only a small change in sheet resistance can be found after NAN electrode is preserved in air for 1 year. The power conversion efficiencies of organic photovoltaic cells with NAN electrodes deposited on glass and polyethylene terephthalate (PET) substrates are 6.07 and 5.55%, respectively, which are competitive with those of indium tin oxide (ITO)-based devices. Good photoelectric properties, the low-cost material, and the room-temperature deposition process imply that NAN electrode is a striking candidate for low-cost and flexible transparent electrode for efficient flexible optoelectronic devices.

  4. Alloy composition dependence of formation of porous Ni prepared by rapid solidification and chemical dealloying

    Energy Technology Data Exchange (ETDEWEB)

    Qi Zhen [Key Laboratory of Liquid Structure and Heredity of Materials, Shandong University, Jingshi Road 73, Jinan 250061 (China); Zhang Zhonghua [Key Laboratory of Liquid Structure and Heredity of Materials, Shandong University, Jingshi Road 73, Jinan 250061 (China)], E-mail: zh_zhang@sdu.edu.cn; Jia Haoling [Key Laboratory of Liquid Structure and Heredity of Materials, Shandong University, Jingshi Road 73, Jinan 250061 (China); Qu Yingjie [Shandong Labor Occupational Technology College, Jingshi Road 388, Jinan 250022 (China); Liu Guodong; Bian Xiufang [Key Laboratory of Liquid Structure and Heredity of Materials, Shandong University, Jingshi Road 73, Jinan 250061 (China)

    2009-03-20

    In this paper, the effect of alloy composition on the formation of porous Ni catalysts prepared by chemical dealloying of rapidly solidified Al-Ni alloys has been investigated using X-ray diffraction (XRD), scanning electron microscopy (SEM) with energy dispersive X-ray (EDX) analysis and N{sub 2} adsorption experiments. The experimental results show that rapid solidification and alloy composition have a significant effect on the phase constituent and microstructure of Al-Ni alloys. The melt spun Al-20 at.% Ni alloy consists of {alpha}-Al, NiAl{sub 3} and Ni{sub 2}Al{sub 3}, while the melt spun Al-25 and 31.5 at.% Ni alloys comprise NiAl{sub 3} and Ni{sub 2}Al{sub 3}. Moreover, the formation and microstructure of the porous Ni catalysts are dependent upon the composition of the melt spun Al-Ni alloys. The morphology and size of Ni particles in the Ni catalysts inherit from those of grains in the melt spun Al-Ni alloys. Rapid solidification can extend the alloy composition of Al-Ni alloys suitable for preparation of the Ni catalysts, and obviously accelerate the dealloying process of the Al-Ni alloys.

  5. Diffusion couple studies of the Ni-Bi-Sn system

    Directory of Open Access Journals (Sweden)

    Vassilev G.

    2012-01-01

    Full Text Available Investigations of Ni-Bi-Sn system were performed in order to inquire the phase diagram and to assess some diffusion kinetic parameters. For this purpose diffusion couples consisting of solid nickel (preliminary electroplated with tin and liquid Bi-Sn phase were annealed at 370 °C. Three compositions (0.8, 0.6 and 0.4 mole fractions Sn of the Bi-Sn melts were chosen. Annealing times from 24 to 216 h were applied. The phase and chemical compositions of the contact zone were determined by means of electron scanning microscope. It was confirmed that the diffusion layers consist mainly of Ni3Sn4 but other intermetallic phases grow as well. For the first time metastable Ni-Sn phases as NiSn and NiSn8 (NiSn9 were observed in metallurgical alloys (i.e. not in electroplated samples. The existence of a ternary compound previously reported in the literature was confirmed. More than one ternary Ni-Bi-Sn compounds might possibly be admitted. A growth coefficient of (2.29 ± 0.02 x 10-15 m2 s-1 was obtained. It was found that the apparent activation energy for diffusion layers growth (18 ± 8 kJ mol-1 is inferior to that one assessed at growth from solid state Bi-Sn mixtures (88 ± 12 kJ mol-1.

  6. LaBaNiO{sub 4}: a Fermi glass

    Energy Technology Data Exchange (ETDEWEB)

    Schilling, A; Dell' Amore, R; Mueller, K A [Physics Institute of the Universitaet of Zuerich, Winterthurerstrasse 190, CH-8057 Zuerich (Switzerland); Karpinski, J; Bukowski, Z [Laboratory for Solid-State Physics, ETH Zuerich HPF F-7, CH-8093 Zuerich (Switzerland); Medarde, M; Pomjakushina, E [Laboratory for Neutron Scattering, ETHZ and PSI, CH-5232 Villigen PSI (Switzerland)], E-mail: schilling@physik.uzh.ch

    2009-01-07

    Polycrystalline samples of LaSr{sub 1-x}Ba{sub x}NiO{sub 4} show a crossover from a state with metallic transport properties for x = 0 to an insulating state as x{yields}1. The end member LaBaNiO{sub 4} with a nominal nickel Ni 3d{sup 7} configuration might therefore be regarded as a candidate for an antiferromagnetic insulator. However, we do not observe any magnetic ordering in LaBaNiO{sub 4} down to 1.5 K, and despite its insulating transport properties several other physical properties of LaBaNiO{sub 4} resemble those of metallic LaSrNiO{sub 4}. Based on an analysis of electrical and thermal-conductivity data as well as magnetic-susceptibility and low-temperature specific-heat measurements, we suggest that LaBaNiO{sub 4} is a Fermi glass with a finite electron density of states at the Fermi level but these states are localized.

  7. Synthesis of FeCoNi nanoparticles by galvanostatic technique

    Energy Technology Data Exchange (ETDEWEB)

    Budi, Setia, E-mail: setiabudi@unj.ac.id [Potgraduate Program of Materials Science Study, Department of Physics, Faculty of Mathematics and Natural Sciences, Universitas Indonesia, Depok 16424 (Indonesia); Department of Chemistry, Faculty of Mathematics and Sciences, Universitas Negeri Jakarta, Jl. Pemuda No.10, Rawamangun, Jakarta 13220 (Indonesia); Hafizah, Masayu Elita; Manaf, Azwar, E-mail: azwar@ui.ac.id [Potgraduate Program of Materials Science Study, Department of Physics, Faculty of Mathematics and Natural Sciences, Universitas Indonesia, Depok 16424 (Indonesia)

    2016-06-17

    Soft magnetic nanoparticles of FeCoNi have been becoming interesting objects for many researchers due to its potential application in electronic devices. One of the most promising methods for material preparation is the electrodeposition which capable of growing nanoparticles alloy directly onto the substrate. In this paper, we report our electrodeposition studies on nanoparticles synthesis using galvanostatic electrodeposition technique. Chemical composition of the synthesized FeCoNi was successfully controlled through the adjustment of the applied currents. It is revealed that the content of each element, obtained from quantitative analysis using atomic absorption spectrometer (AAS), could be modified by the adjustment of current in which Fe and Co content decreased at larger applied currents, while Ni content increased. The nanoparticles of Co-rich FeCoNi and Ni-rich FeCoNi were obtained from sulphate electrolyte at the range of applied current investigated in this work. Broad diffracted peaks in the X-ray diffractograms indicated typical nanostructures of the solid solution of FeCoNi.

  8. Nano-sized Ni-doped carbon aerogel for supercapacitor.

    Science.gov (United States)

    Lee, Yoon Jae; Jung, Ji Chul; Park, Sunyoung; Seo, Jeong Gil; Baeck, Sung-Hyeon; Yoon, Jung Rag; Yi, Jongheop; Song, In Kyu

    2011-07-01

    Carbon aerogel was prepared by polycondensation of resorcinol with formaldehyde using sodium carbonate as a catalyst in ambient conditions. Nano-sized Ni-doped carbon aerogel was then prepared by a precipitation method in an ethanol solvent. In order to elucidate the effect of nickel content on electrochemical properties, Ni-doped carbon aerogels (21, 35, 60, and 82 wt%) were prepared and their performance for supercapacitor electrode was investigated. Electrochemical properties of Ni-doped carbon aerogel electrodes were measured by cyclic voltammetry at a scan rate of 10 mV/sec and charge/discharge test at constant current of 1 A/g in 6 M KOH electrolyte. Among the samples prepared, 35 wt% Ni-doped carbon aerogel (Ni/CA-35) showed the highest capacitance (110 F/g) and excellent charge/discharge behavior. The enhanced capacitance of Ni-doped carbon aerogel was attributed to the faradaic redox reactions of nano-sized nickel oxide. Moreover, Ni-doped carbon aerogel exhibited quite stable cyclability, indicating long-term electrochemical stability.

  9. Kinetics of Oxidation and Reduction of Ni/YSZ Cermet

    Energy Technology Data Exchange (ETDEWEB)

    Fouquet, D.; Mueller, A.; Weber, A.; Ivers-Tiffee, E.

    2002-06-01

    A cyclic reduction and oxidation of Ni/YSZ-cermet anodes for Solid Oxide Fuel Cells (SOFC) resulted in an increase of the polarization resistance. Therefore, investigations concerning kinetics of oxidation/reduction and the impact of redox cycles on the microstructure of Ni/YSZ bulk ceramics were made. The reaction process of the basic system Ni/NiO was compared with cermet bulk samples and the influence of NiO and YSZ particle sizes and sintering temperatures on kinetics and microstructure was studied using thermogravimetry and dilatometry. The investigations on bulk ceramics indicated that no length change occurred during reduction, whereas reoxidation led to an increase in the length of the samples which strongly depended on the microstructure. It was shown that bulk samples sintered at temperatures below 1300{sup o}C can withstand redox cycles much better than those sintered at higher temperatures. Furthermore, it was found that by decreasing the NiO particle size and using a NiO/YSZ particle size ratio of approximately 3:2, a smaller length increase after reoxidation was achieved. An increase of the polarization resistance could be ascribed to the formation of cracks within the bulk sample which interrupt current paths and therefore reduce the amount of the active triple phase boundary. (author)

  10. Detection of {sup 59}Ni by accelerator mass spectrometry

    Energy Technology Data Exchange (ETDEWEB)

    Persson, Per; Erlandsson, Bengt; Freimann, K.; Hellborg, R.; Stenstroem, K. [Lund Univ. (Sweden). Dept. of Nuclear Physics; Larsson, Ragnar [Lund Univ. (Sweden). Chemical Engineering II; Skog, G. [Lund Univ. (Sweden). Dept. of Quaternary Geology

    1999-02-01

    The aims of this project were to develop a method to measure the amount of {sup 59}Ni in stainless steel and to determine the detection limit for this method. {sup 59}Ni is produced by neutron activation in the construction material close to the core in a nuclear reactor and it is important to know the amount of {sup 59}Ni present as it governs the classification of the waste. If the amount of {sup 59}Ni is known at different locations in relation to the core, it is also possible to refine the calculation models of the neutron flux in the reactor. Accelerator mass spectrometry, an ultra-sensitive method for measuring small concentrations of radionuclides as well as stable nuclides, has been used in this investigation to determine the concentration of {sup 59}Ni (and thereby the activity) in stainless steel. As the cobalt content in stainless steel is the main contributor to the background in a measurement of {sup 59}Ni, a method for the chemical extraction of nickel from stainless steel, including a purification step to reduce the cobalt content in the sample, has been developed. The detection limit for {sup 59}Ni has been determined to 100{+-}30 Bq per gram nickel (100{+-}30 Bq/g) with the present status of the system 14 refs, 6 figs, 3 tabs

  11. Magnetic studies in evaporated Ni/Pd multilayers

    Energy Technology Data Exchange (ETDEWEB)

    Chafai, K. [Laboratoire de Physique des Materiaux, Micro-electronique, Automatique et Thermique (LPMMAT), Faculte des Sciences Ain Chock, Universite Hassan II, B.P. 5366 Maarif, Casablanca (Morocco); Salhi, H. [Laboratoire de Physique des Materiaux, Micro-electronique, Automatique et Thermique (LPMMAT), Faculte des Sciences Ain Chock, Universite Hassan II, B.P. 5366 Maarif, Casablanca (Morocco); Laboratoire de Mecanique, Productique et Genie industriel (LMPG), Ecole superieure de technologie, Universite Hassan II, B.P. 5366 Maarif, Casablanca (Morocco); Lassri, H., E-mail: lassrih@hotmail.co [Laboratoire de Physique des Materiaux, Micro-electronique, Automatique et Thermique (LPMMAT), Faculte des Sciences Ain Chock, Universite Hassan II, B.P. 5366 Maarif, Casablanca (Morocco); Yamkane, Z.; Lassri, M. [Laboratoire de Physique des Materiaux, Micro-electronique, Automatique et Thermique (LPMMAT), Faculte des Sciences Ain Chock, Universite Hassan II, B.P. 5366 Maarif, Casablanca (Morocco); Abid, M. [Laboratoire de Physique Fondamentale et Appliquee (LPFA), Faculte des Sciences Ain Chock, Universite Hassan II, B.P. 5366 Maarif, Casablanca (Morocco); Hlil, E.K. [Institut Neel, CNRS-Universite J. Fourier, BP 166, 38042 Grenoble (France); Krishnan, R. [Laboratoire de Magnetisme et d' Optique, URA 1531, 45 Avenue des Etats Unis, 78035 Versailles Cedex (France)

    2011-03-15

    The magnetic properties of Ni/Pd multilayers, prepared by sequential evaporation in ultrahigh vacuum, have been studied. The Ni thickness dependence of the magnetization and magnetic anisotropy is discussed. The temperature dependence of the spontaneous magnetization is well described by a T{sup 3/2} law in all multilayers. A spin-wave theory has been used to explain the temperature dependence of the spontaneous magnetization, and the approximate values for the exchange interactions for various Ni layer thicknesses have been obtained. - Research highlights: The magnetic properties of Ni/Pd multilayers, prepared by sequential evaporation in ultrahigh vacuum, have been studied. The temperature dependence of the spontaneous magnetization is well described by a T{sup 3/2} law in Ni/Pd multilayers. The spin-wave constant B was observed to depend on t{sub Ni} nonmonotonically. A spin-wave theory has been used to explain the temperature dependence of the spontaneous magnetization. The approximate values for the exchange interactions for various Ni layer thicknesses have been obtained.

  12. Study of hyperfine interactions in intermetallic compounds Gd(Ni,Pd,Cu)In, Tb(Ni,Pd)In, Dy(Ni,Pd)In and Ho(Ni,Pd)In; Estudo de interacoes hiperfinas em compostos intermetalicos Gd(Ni,Pd,Cu)In, Tb(Ni,Pd)In, Dy(Ni,Pd)In e Ho(Ni,Pd)In

    Energy Technology Data Exchange (ETDEWEB)

    Lapolli, Andre Luis

    2006-07-01

    Systematic behavior of magnetic hyperfine field (B{sub hf}) in the intermetallic compounds Gd(Ni,Pd,Cu)In Tb(Ni,Pd)In, Dy(Ni,Pd)In and Ho(Ni,Pd)In was studied by Perturbed Gamma-Gamma Angular Correlation spectroscopy. The measurements of B{sub hf} were carried out at the rare earth atom and in sites using the nuclear probes {sup 140}Ce and {sup 11}'1Cd respectively. The variation of hyperfine field with temperature, in most cases, follows the Brillouin function predicted from the molecular field theory. The hyperfine field values at rare earth atom sites obtained from {sup 140}Ce probe as well as at in sites obtained from {sup 111}Cd probe for each series of compounds were extrapolated to zero Kelvin B{sub hf}(T=0) from these curves. These values were compared with the values of the literature for other compounds containing the same rare earth element and all of them show a linear relationship with the ordering temperature. This indicates that the main contribution to B{sub hf} comes from the conduction electron polarization (CEP) through Fermi contact interaction and the principal mechanism of magnetic interaction in these compounds can be described by the RKKY type interaction. The values of B{sub hf}(T=0) for each family of intermetallic compounds RNiIn and RPdIn when plotted as a function of 4f spin projection of rare earth element also shows a linear relationship. Exceptions are the results for the compounds RNiIn obtained with {sup 111}Cd probe where a small deviation from linearity is observed. The results of the measurements carried out with the {sup 111}Cd probe were also analyzed to obtain the hyperfine parameters of the quadrupole interaction as a function of temperature for RPdln and GdNiIn compounds. The results show that for the compound GdPdIn there might be some Gd-In disorder at high temperature. (author)

  13. In vitro bioactivity and osteoblast response of porous NiTi synthesized by SHS using nanocrystalline Ni-Ti reaction agent.

    Science.gov (United States)

    Gu, Y W; Li, H; Tay, B Y; Lim, C S; Yong, M S; Khor, K A

    2006-08-01

    Porous NiTi with an average porosity of 55 vol % and a general pore size of 100-600 microm was synthesized by self-propagating high temperature synthesis (SHS) with the addition of mechanically alloyed nanocrystalline Ni-Ti as the reaction agent. The SHS of porous NiTi using elemental powders was also performed for comparison. To enhance the bioactivity of the metal surface, porous NiTi synthesized by nanocrystalline Ni-Ti was subjected to chemical treatment to form a layer of TiO(2) coating. The porous NiTi with TiO(2) coating was subsequently immersed in a simulated body fluid (SBF) to investigate its apatite forming ability. The effects of the addition of nanocrystalline Ni-Ti as reaction agent and the application of apatite coating on osteoblastic behavior were studied in primary cultures of human osteoblast cells. Results showed that the main phases in porous NiTi synthesized by elemental powders were NiTi, Ti(2)Ni, and unreacted free Ni. By using nanocrystalline Ni-Ti as reaction agent, the secondary intermetallic phase of Ti(2)Ni was significantly reduced and the free Ni was eliminated. TiO(2) coating with anatase phase was formed on the surface of porous NiTi after the chemical treatment. A layer consisting of nanocrystalline carbonate-containing apatite was formed on the surface of TiO(2) coating after soaking in SBF. The preliminary cell culture studies showed that the porous NiTi synthesized with the addition of nanocrystalline Ni-Ti attracted marked attachment and proliferation of the osteoblast cells. This gives the evidence of the potential biomedical applications of the porous NiTi.

  14. Nickel hexayttrium decaiodide, [NiY6]I10

    Directory of Open Access Journals (Sweden)

    Simon Steinberg

    2014-06-01

    Full Text Available Comproportionation reactions of yttrium triiodide, yttrium and nickel led to the formation of the compound [NiY6]I10, which is isostructural with the prototypical [RuY6]I10. In particular, [NiY6]I10 is composed of isolated nickel centered yttrium octahedra (site symmetry -1 that are further surrounded by iodide ligands to construct a three-dimensional cluster complex framework. Although this compound has been previously detected by powder X-ray diffraction techniques [Payne & Corbett (1990. Inorg. Chem. 29, 2246–2251], details of the crystal structure for triclinic [NiY6]I10 were not provided.

  15. Abuso sexual en la niñez

    OpenAIRE

    Ricardo García-Jaime

    2013-01-01

    El abuso sexual en la niñez se presenta en dos grandes modalidades: el abuso sexual familiar (también conocido como incesto), y la explotación sexual comercial de niños/as y adolescentes (conocida como trata de personas con fines sexuales). Ambas modalidades afectan a millones de niños/as en todo el mundo. El objetivo de este artículo es ofrecer una panorámica en torno al abuso sexual que ocurre al interior de las fami-lias. Para ello se revisan algunos conceptos en torno al abuso, sus princi...

  16. El niño preescolar como telespectador

    OpenAIRE

    Domínguez Aguila, Carmen Lucía; Schade Yankovic, Nieves Irma

    2005-01-01

    Los medios de comunicación social y en especial la televisión, constituyen parte importante en la vida cotidiana de los niños. En Chile el 95% de los hogares posee televisión y un 97% de los menores señalan saber utilizar el televisor. El acceso a este medio de comunicación social ha posibilitado que ver televisión sea la principal actividad que realizan los niños chilenos en su tiempo libre. Si se considera que los discursos audiovisuales inciden en la construcción que los niños hac...

  17. Brasil: Favela, niños y video

    Directory of Open Access Journals (Sweden)

    Denise María Cogo

    2015-01-01

    Full Text Available La experiencia Video-Niños surgió en 1990 con un grupo de niños afro-brasileños de 8 a 14 años que mantienen vivos elementos de su cultura en la música y la religión. El trabajo abarcó la producción de una telenovela (Gente rica, un telediario (Niño-reportero y un show de variedades donde la creatividad y participación fueron evidentes.

  18. Varying the exchange interaction between NiO nanoparticles

    DEFF Research Database (Denmark)

    Bahl, Christian Robert Haffenden; Mørup, Steen

    2006-01-01

    We demonstrate that exchange interactions between antiferromagnetic nanoparticles of 57Fe-doped NiO can be varied by simple macroscopic treatments. Mössbauer spectroscopy studies of the superparamagnetic relaxation behaviour show that grinding or suspension in water of nanoparticles of NiO can si...... significantly reduce interparticle interactions. Slow drying of aqueous suspensions of NiO nanoparticles did not lead to enhanced interparticle interactions. This is opposite to the behaviour of α-Fe2O3 (hematite) nanoparticles....

  19. Interaction of NiO with yttria-stabilized zirconia

    DEFF Research Database (Denmark)

    Kuzjukevics, A.; Linderoth, Søren

    1997-01-01

    As-prepared and heat treated plasma-produced 8 and 10 mol% yttria-stabilized zirconia (YSZ) powders doped with 0, 5, 10 and 75 mol% NiO have been investigated by XRD. The as-prepared powders are mixtures of metastable tetragonal and cubic phases but they transform to a single YSZ phase upon heat...... treatment above 1200 degrees C. The solubility of NiO in yttria-stabilized zirconia is less than 2 mol% at 1600 degrees C and varies little within the investigated yttria concentration range. The solubility increases with increasing temperature and the total NiO concentration. The activation energy...

  20. Mechanical and structural properties of sputtered Ni/Ti multilayers

    Energy Technology Data Exchange (ETDEWEB)

    Senthil Kumar, M.; Boeni, P.; Tixier, S.; Clemens, D.; Horisberger, M. [Paul Scherrer Inst. (PSI), Villigen (Switzerland)

    1997-09-01

    Ni/Ti bilayers have been prepared by dc-magnetron sputtering in order to study their mechanical and structural properties. A remarkable reduction of stress is observed when the Ni layers are sputtered reactively in argon with a high partial pressure of air. The high angle x-ray diffraction studies show a tendency towards amorphisation of the Ni layers with increasing air flow. The low angle measurements indicate a substantial reduction of interdiffusion resulting in smoother interfaces with increasing air content. (author) 2 figs., 2 refs.

  1. Synthesis and Growth Mechanism of Ni Nanotubes and Nanowires

    Directory of Open Access Journals (Sweden)

    Wang Yiqian

    2009-01-01

    Full Text Available Abstract Highly ordered Ni nanotube and nanowire arrays were fabricated via electrodeposition. The Ni microstructures and the process of the formation were investigated using conventional and high-resolution transmission electron microscope. Herein, we demonstrated the systematic fabrication of Ni nanotube and nanowire arrays and proposed an original growth mechanism. With the different deposition time, nanotubes or nanowires can be obtained. Tubular nanostructures can be obtained at short time, while nanowires take longer time to form. This formation mechanism is applicable to design and synthesize other metal nanostructures and even compound nanostuctures via template-based electrodeposition.

  2. 25 years in a nutshell--IMIA-NI, 1982 - 2007.

    Science.gov (United States)

    Tallberg, M

    2008-01-01

    When invited to give an overview of nursing informatics I found it natural to celebrate the 25th anniversary of the International Medical Informatics Special Interests Group on Nursing Informatics (IMIA SIG NI) with a "mini history" from my own perspective The method is historical. Sources are from the IMIA-NI web site, conference proceedings and programs, my private archive and reminiscences. IMIA-NI has l "left its cradle" quite a while ago, and is now leading the nursing informatics world, thanks to its voluntary, enthusiastic and devoted leaders, WG chair persons, and national members. The newly reinforced executive also works hard to disseminate nursing informatics to the third world.

  3. Metal (Ni, Au)-vacancy complexes in GaN

    Science.gov (United States)

    von Pezold, J.; Bristowe, P. D.

    2006-06-01

    The stability and electronic properties of metal (Ni, Au)-vacancy complexes in GaN were studied using density functional calculations. Two complexes (NiGa-VN and VGa-Aui-VN) were found to exhibit relatively low formation energies in their neutral charge state under p-type conditions and are predicted to act as deep acceptors in GaN. As such they are unlikely to contribute to the hole carrier concentration in p-GaN and are probably not responsible for the low electrical resistance of Au/Ni contacts. They may, however, act as compensation centres in n-GaN.

  4. Physicochemical investigation of NiAl with small molybdenum additions

    Science.gov (United States)

    Troshkina, V. A.; Kucherenko, L. A.; Fadeeva, V. I.; Aristova, N. M.

    1982-01-01

    Specimens of four cast NiAl alloys, three of them containing 0.5, 1.0 and 1.5 at. % Mo., were homogenized for 10, 10, and 140 hr at 1373, 1523 and 1273 K, respectively, then kept at 1073, 1173 and 1323 K for 60, 120 and 3 hr, respectively, and quenched in icy water. The precipitation of a metastable Ni3Mo phase was observed at temperatures between 1073 and 1523 K. Molybdenum substituted for nickel was found to inhibit the lattice disordering in NiAl at 1073 and 1523 K.

  5. Minority anion substitution by Ni in ZnO

    CERN Document Server

    Pereira, Lino Miguel da Costa; Correia, João Guilherme; Amorim, Lígia Marina; Silva, Daniel José; David-Bosne, Eric; Decoster, Stefan; da Silva, Manuel Ribeiro; Temst, Kristiaan; Vantomme, André

    2013-01-01

    We report on the lattice location of implanted Ni in ZnO using the $\\beta$− emission channeling technique. In addition to the majority substituting for the cation (Zn), a significant fraction of the Ni atoms occupy anion (O) sites. Since Ni is chemically more similar to Zn than it is to O, the observed O substitution is rather puzzling. We discuss these findings with respect to the general understanding of lattice location of dopants in compound semiconductors. In particular, we discuss potential implications on the magnetic behavior of transition metal doped dilute magnetic semiconductors.

  6. Wetting - Dewetting Transitions of Au/Ni Bilayer Films

    Science.gov (United States)

    Cen, Xi

    Thin films deposited at low temperatures are often kinetically constrained and will dewet the underlying substrate when annealed. Solid state dewetting is driven by the minimization of the total free energy of thin film-substrate interface and free surface, and mostly occurs through surface diffusion. Dewetting is a serious concern in microelectronics reliability. However, it can also be utilized for the self-assembly of nanostructures with potentials in storage, catalysis, or transistors. Therefore, a fundamental understanding of the dewetting behavior of thin metal films is critical for improving the thermal stability of microelectronics and controlling the order of self-assembled nanostructures. Mechanisms for dewetting of single layer films have been studied extensively. However little work has been reported on multilayer or alloyed thin films. In the thesis, the solid state dewetting of Au/Ni bilayer films deposited on SiO2/Si substrates was investigated by scanning electron microscopy (SEM), transmission electron microscopy (TEM) and aberration corrected scanning TEM (STEM). Ex-situ SEM and TEM studies were performed with in-situ TEM heating characterization to identify the mechanisms during the dewetting process of Au/Ni bilayer films. The solid state dewetting of Au/Ni bilayer films from SiO2/Si substrates exhibits both homogeneous and localized dewetting of Ni and long-edge retraction for Au under isothermal annealing condition. The top Au layer retracts up to 1 mm from the edge of the substrate wafer to reduce the energetically unfavored Au/Ni interface. In contrast, Ni dewets and agglomerates locally due to its limited diffusivity compared to Au. Film morphology and local chemical composition varies significantly across hundreds of microns along the direction normal to the retracting edge. Besides long range edge receding, localized dewetting shows significant changes in film morphology and chemical distribution. Both Au and Ni shows texturing. Despite

  7. Determination of 63Ni and 59Ni in spent ion-exchange resin and activated charcoal from the IEA-R1 nuclear research reactor.

    Science.gov (United States)

    Taddei, M H T; Macacini, J F; Vicente, R; Marumo, J T; Sakata, S K; Terremoto, L A A

    2013-07-01

    A radiochemical method has been adapted to determine (59)Ni and (63)Ni in samples of radioactive wastes from the water cleanup system of the IEA-R1 nuclear research reactor. The process includes extraction chromatographic resin with dimethylglyoxime (DMG) as a functional group. Activity concentrations of (59)Ni and (63)Ni were measured, respectively, by X-ray spectrometry and liquid scintillation counting, whereas the chemical yield was determined by ICP-OES. The average ratio of measured activity concentrations of (63)Ni and (59)Ni agree well with theory. Copyright © 2013 Elsevier Ltd. All rights reserved.

  8. Dechlorination of pentachlorophenol using nanoscale Fe/Ni particles: role of nano-Ni and its size effect.

    Science.gov (United States)

    Cheng, Rong; Zhou, Wei; Wang, Jian-Long; Qi, Daoduo; Guo, Lin; Zhang, Wei-Xian; Qian, Yi

    2010-08-15

    The dechlorination of pentachlorophenol (PCP) using nano-Fe together with different size of nano-Ni particles (30, 50, 80, and 100nm) was investigated. The results indicated that nano-Ni particles could improve the dechlorination of PCP. The X-ray powder diffraction (XRD) analysis suggested that nano-Ni particles might serve as catalyst for dechlorination. The decrease of nano-Ni particle size resulted in the increase of PCP transformation and chloride release. The accumulation of several intermediates, such as phenol, 2-chlorophenol, 3-chlorophenol and 4-chlorophenol indicated the probable changes of the reaction pathway for PCP dechlorination. The corrosion products of Fe were detected using XRD analysis. In the system without nano-Ni particles, they were lepidocrocite (gamma-FeOOH) and magnetite (Fe(3)O(4)) and/or maghemite (Fe(2)O(3)), however, in the systems with nano-Ni particles, they were still magnetite/maghemite but no lepidocrocite existed. The size of nano-Ni particles might affect the crystallization of corrosion products of Fe, but did not affect the species distribution of corrosion products. Copyright 2010 Elsevier B.V. All rights reserved.

  9. Structural and magnetic properties of yttrium and lanthanum-doped Ni-Co and Ni-Co-Zn spinel ferrites

    Energy Technology Data Exchange (ETDEWEB)

    Stergiou, Charalampos, E-mail: stergiou@cperi.certh.gr [Laboratory of Inorganic Materials, Centre for Research and Technology-Hellas, 57001, Thermi (Greece); Litsardakis, George, E-mail: lits@eng.auth.gr [Laboratory of Materials for Electrotechnics, Aristotle University of Thessaloniki, 54124, Thessaloniki (Greece)

    2014-11-05

    Rare earth doping of Co-rich spinel ferrites is investigated through the preparation of two groups of polycrystalline Ni-Co and Ni-Co-Zn ferrites, where Fe is partly substituted by Y and La. The characterization of the sintered ferrites by means of X-ray powder diffraction and Rietveld profile analysis, indicates the subtle expansion of the spinel unit cell and the cation redistribution in the doped ferrites in order to accommodate the incorporation of Y and La in the lattice. The impurity traces, detected only in the Ni-Co-Zn group, is ascribed to the Zn population in the tetrahedral A-sites impeding the cation transfer. Moreover, the examined microstructure of the doped Ni-Co samples comprises enlarged and more homogeneous grains, whereas grain growth is moderated in the doped Ni-Co-Zn ferrites. The discussed characteristics of the crystal and magnetic structure along with the morphological aspects define the impact of Y and La doping on the static magnetic properties of Ni-Co and Ni-Co-Zn ferrites, saturation magnetization MS and coercivity HC, which were extracted from the respective hysteresis loops.

  10. In Situ Synthesis and Electrophoretic Deposition of NiO/Ni Core-Shell Nanoparticles and Its Application as Pseudocapacitor

    Directory of Open Access Journals (Sweden)

    Joaquin Yus

    2017-11-01

    Full Text Available A simple, low cost and transferable colloidal processing method and the subsequent heat treatment has been optimized to prepare binder-free electrodes for their application in supercapacitors. NiO/Ni core–shell hybrid nanostructures have been synthetized by heterogeneous precipitation of metallic Ni nanospheres onto NiO nanoplatelets as seed surfaces. The electrophoretic deposition (EPD has been used to shape the electroactive material onto 3D substrates such as Ni foams. The method has allowed us to control the growth and the homogeneity of the NiO/Ni coatings. The presence of metallic Nickel in the microstructure and the optimization of the thermal treatment have brought several improvements in the electrochemical response due to the connectivity of the final microstructure. The highest specific capacitance value has been obtained using a thermal treatment of 325 °C during 1 h in Argon. At this temperature, necks formed among ceramic-metallic nanoparticles preserve the structural integrity of the microstructure avoiding the employment of binders to enhance their connectivity. Thus, a compromise between porosity and connectivity should be established to improve electrochemical performance.

  11. Crystalline NiCo2S4 nanotube array coated with amorphous NiCoxSy for supercapacitor electrodes.

    Science.gov (United States)

    Ding, Rui; Zhang, Mingyi; Yao, Yunhe; Gao, Hong

    2016-04-01

    Hierarchical NiCo2S4@NiCoxSy core/shell nanoarrays grown on carbon cloth were successfully synthesized via a two-step hydrothermal route and following an electrodeposition process. Compared with bare NiCo2S4, the electrochemical performance of NiCo2S4@NiCoxSy nanoarrays have been apparently improved, which shows areal capacitance as high as 3.9F/cm(2) at a constant current density of 1mA/cm(2). And the composite material exhibits excellent rate capability that a high areal capacitance of 2.9F/cm(2) is still retaining as the current density increase to 50mA/cm(2). The superior electrochemical performance can be attributed to the reasonably designed core/shell hierarchical structure of NiCo2S4@NiCoxSy nanoarrays, which would be promising for high-performance supercapacitor materials. Copyright © 2015 Elsevier Inc. All rights reserved.

  12. Effects of Ni-5%RExOy Composite Additives on Electrochemical Hydrogen Storage Performances of Mg2Ni

    Directory of Open Access Journals (Sweden)

    ZHANG Guo-fang

    2017-11-01

    Full Text Available The Ni-5%RExOy (CeO2, La2O3, Eu2O3 as composite additives, Mg2Ni-Ni-5%RExOy composites were prepared by the ball milling method. The effects of different additives on the structure, morphology, electrochemistry and kinetic properties of Mg2Ni alloy were studied systematically. The results show that composite additives can improve the proportion of amorphous and nanocrystalline structure of Mg2Ni alloy. The particle size is homogeneous but the agglomeration is observed in the sample with Ni-5%CeO2 additives. The composites with additives show higher maximum discharge capacity and better cycle stabilities. All of these three kinds of composite additives can improve the kinetic properties of the composites effectively, including optimizing the charge-transfer ability, the reversibility of the electrochemical reaction on the alloy surface, and enhancing the diffusion coefficients of H atoms in the bulk of alloy. Among these three kinds of additives, Ni-5%CeO2 additive shows the best catalysis effect on promoting the kinetic properties of the composites.

  13. Pressure-induced development of bonding in NiAs type compounds and polymorphism of NiP

    Energy Technology Data Exchange (ETDEWEB)

    Dera, Przemyslaw; Lazarz, John D.; Lavina, Barbara (UC); (UNLV)

    2016-07-29

    A reversible, displacive, pressure-induced structural phase transition has been found to occur in nickel monophosphide NiP at approximately 3.5 GPa by means of in situ synchrotron single-crystal X-ray diffraction. The new phase, with Pearson symbol oC56, assumes an orthorhombic structure with Cmc2{sub 1} space group and unit cell parameters a=23.801(2) {angstrom}, b=5.9238(6) {angstrom}, and c=4.8479(4) {angstrom} at 5.79 GPa. The high-pressure phase is a superstructure of the ambient, oP16 phase with multiplicity of 3.5. The phosphorous sublattice gradually converts from the net of isolated P{sub 2} dimers found in the ambient NiP, towards zig-zag polymeric P{infinity} chains found in MnP-type structures. The transformation involves development of triatomic phosphorous clusters and interconnected Ni slabs with diamondoid topology. The high-pressure phase, which represents intermediate polymerization step, is a commensurately modulated superstructure of the NiAs aristotype. The phase transformation in NiP bears resemblance to the effect of successive substitution of Si or Ge in place of P found in the series of stoichiometric inhomogeneous linear structures in ternary NiP{sub 1-x}Si{sub x} and NiP{sub 1-x}Ge{sub x} systems.

  14. Mechanochemical synthesis of Ni(OH){sub 2} and the decomposition to NiO nanoparticles: Thermodynamic and optical spectra

    Energy Technology Data Exchange (ETDEWEB)

    Tang, Aidong [School of Chemistry and Chemical Engineering, Central South University, Changsha 410083 (China); Li, Xiaoyu; Zhou, Zheng [Department of Inorganic Materials, School of Minerals Processing and Bioengineering, Central South University, Changsha 410083 (China); Ouyang, Jing, E-mail: jingouyang@csu.edu.cn [Department of Inorganic Materials, School of Minerals Processing and Bioengineering, Central South University, Changsha 410083 (China); Yang, Huaming, E-mail: hmyang@csu.edu.cn [Department of Inorganic Materials, School of Minerals Processing and Bioengineering, Central South University, Changsha 410083 (China)

    2014-07-05

    Highlights: • Mechanochemical route is efficient to prepare NiO nanoparticles. • Thermodynamic in the formation procedure is carefully investigated. • Size of the NiO nanoparticles can be easily controlled by changing heat temperature. - Abstract: Nickel hydroxide (Ni(OH){sub 2}) was prepared through a mechanochemical route using simple manual milling. NiO nanoparticles were obtained through subsequent calcinations. X-ray diffraction (XRD), differential thermal analysis and thermal gravimetric (DTA/TG), transmission electronic microscopy (TEM), Fourier transforming infrared spectroscopy (FTIR) and ultraviolet to visible spectroscopy (UV–vis) were adopted to characterize the structural, morphological, and optical properties of the obtained NiO products. Intensive study to the DTA curves of the Ni(OH){sub 2} precursor was conducted to understand the thermal behavior and derive the activation energy, for which the Flynn–Wall–Ozawa and Kissinger–Akahira–Sunose methods were introduced and were applied respectively. The average activation energy required to de-composite the Ni(OH){sub 2} precursor in ambient condition was 117.8 kJ/mol, which determined that the decomposition is controlled by the chemical reaction. NiO with cubic shape was obtained. Size of the products increased from 8.3 nm at 350 °C to 43.4 nm at 600 °C. Carbonates were found to co-exist with the product, which were generated in the preparing procedures. Band gap energy of the NiO was in the range of 3.30 ± 0.11 eV, which have no obvious relationship with the preparing conditions.

  15. Magnetoimpedance of thin film meander with composite coating layer containing Ni nanoparticles

    NARCIS (Netherlands)

    Lodewijk, K. J.; Fernandez, E.; Garcia-Arribas, A.; Kurlyandskaya, G. V.; Lepalovskij, V. N.; Safronov, A. P.; Kooi, B. J.

    2014-01-01

    Giant magnetoimpedance (GMI) [FeNi/Cu](4)/FeNi/Cu/[FeNi/Cu](4)/FeNi sensing meander elements were designed and tested aiming to develop a new instrumentation for characterization of polymer/magnetic nanoparticles composites. Acrylic copolymer of 95% of butyl methacrylate and 5% of methacrylic acid

  16. Optimal synthesis of a Ni(II)-dimethylglyoxime ion-imprinted polymer ...

    African Journals Online (AJOL)

    A Ni(II)-dimethylglyoxime ion-imprinted polymer {Ni(II)-DMG IIP} was optimised by the uniform design experimental method and used to adsorb Ni(II) ions from water, soil and mine tailing samples. This aimed to improve the performance of this ion-imprinted polymer in trapping Ni(II) ions from soil and mine tailing samples ...

  17. Relation Between Ni Particle Shape Change and Ni Migration in Ni–YSZ Electrodes – a Hypothesis

    DEFF Research Database (Denmark)

    Mogensen, Mogens Bjerg; Hauch, Anne; Sun, Xiufu

    2017-01-01

    This paper deals with degradation mechanisms of Ni–YSZ electrodes for solid oxide cells, mainly solid oxide electrolysis cells (SOECs), but also to some extent solid oxide fuel cells (SOFCs). Analysis of literature data reveals that several apparently different and even in one case apparently...... contradicting degradation phenomena are a consequence of interplay between loss of contact between the Ni–YSZ (and Ni–Ni particles) in the active fine-structured composite fuel electrode layer and migration of Ni via weakly oxidized Ni hydroxide species. A hypothesis that unravels the apparent contradiction...

  18. Hierarchically porous Ni monolith@branch-structured NiCo2O4 for high energy density supercapacitors

    Directory of Open Access Journals (Sweden)

    Mengjie Xu

    2016-06-01

    Full Text Available A variety of NiCo2O4 nanostrucutures ranging from nanowire to nanoplate and branched structures were successfully prepared via a simple hydrothermal process. The experimental results show that NiCo2O4 with branched structures possesses the best overall electrochemical performance. The improvement of energy density was explored in terms of hierarchically three-dimensional (3D metal substrates and a high specific area capacitance, and area energy density is obtained with hierarchically porous Ni monolith synthesized through a controlled combustion procedure.

  19. Probing the semi-magicity of $^{68}$Ni via the $^{66}$Ni(t,p)$^{68}$Ni two-neutron transfer reaction in inverse kinematics

    CERN Document Server

    AUTHOR|(CDS)2079390; Van Duppen, Piet

    The region around the nucleus $^{68}$Ni, with a shell closure for its protons at Z=28 and a harmonic oscillator shell gap for its neutrons at N=40, has drawn considerable interest over the past decades. $^{68}$Ni has properties that are typical for a doubly-magic nucleus, such as a high excitation energy and low B($E2:2^{+} \\rightarrow 0^{+}$) transition probability for the first excited 2$^{+}$ level and a 0$^{+}$ level as the first excited state. However, it has been suggested that the magic properties of $^{68}$Ni arise due to the fact that the N=40 separates the negative parity $pf$-shell from the positive parity 1$g_{9/2}$ orbital, and indeed, recent mass measurements have not revealed a clear N = 40 energy gap. Despite all additional information that was acquired over the last decade the specific role of the N=40 is not yet understood and a new experimental approach to study $^{68}$Ni was proposed. Namely, a two-neutron transfer reaction on $^{66}$Ni to characterize and disentangle the structure of the ...

  20. Corrosion resistance of amorphous and crystalline Pd40Ni40P20 alloys in aqueous solutions

    DEFF Research Database (Denmark)

    Wu, Y.F.; Chiang, Wen-Chi; Chu, J.

    2006-01-01

    The corrosion behaviors of amorphous and crystalline Pd40Ni40P20 alloys in various aqueous solutions are reported in this paper. The corrosion resistance of crystalline (annealed) Pd40Ni40P20 is better than that of amorphous Pd40Ni40P20 in various corrosive solutions, due to crystalline Pd40Ni40P20...... and mainly consists of inert Pd5P2, NI3P, Ni2Pd2P and noble Pd phases. These inert and noble properties result in a higher corrosion resistance in crystalline Pd40Ni40P20....

  1. The phase system Fe-Ni-S at 900 degree C

    DEFF Research Database (Denmark)

    Karup-Møller, Sven; Makovicky, E.

    1998-01-01

    analyses on 32 binary runs. There are two important three-phase associations in the system: mss Fe48.6Ni1.1S50.3 - gamma Fe65.0Ni35.0 - melt similar to Fe42.0Ni15.0S43.0 and vaesite Ni0.91Fe0.09S2 - mss Ni0.54Fe0.33S - S Partition coefficient D-Ni (mss/melt) was determined to be equal to (at.% Ni(mss)(0...

  2. Laboratory Investigations of Ni-Al Coatings Exposed to Conditions Simulating Biomass Firing

    DEFF Research Database (Denmark)

    Wu, Duoli; Okoro, Sunday Chukwudi; Dahl, Kristian Vinter

    2016-01-01

    Fireside corrosion is a key problem when using biomass fuels in power plants. A possible solution is to apply corrosion resistant coatings. The present paper studies the corrosion and interdiffusion behaviour of a Ni-Al diffusion coating on austenitic stainless steel (TP347H). Ni-Al coatings were...... corrosion attack. Interdiffusion was studied by isothermal heat treatment in static air at 650˚C or 700˚C for up to 3000h. The Ni2Al3 gradually transformed into NiAl and Ni3Al during the interdiffusion process. Porosity developed at the interface between the Ni-Al coating and the Ni layer and expanded...

  3. Effect of Ti seed and spacer layers on structure and magnetic properties of FeNi thin films and FeNi-based multilayers

    Energy Technology Data Exchange (ETDEWEB)

    Svalov, A.V., E-mail: andrey.svalov@ehu.es [Departamento de Electricidad y Electrónica, Universidad del País Vasco (UPV/EHU), 48080 Bilbao (Spain); Department of Magnetism and Magnetic Nanomaterials, Ural Federal University, 620002 Ekaterinburg (Russian Federation); Larrañaga, A. [SGIker, Servicios Generales de Investigación, Universidad del País Vasco (UPV/EHU), 48080 Bilbao (Spain); Kurlyandskaya, G.V. [Departamento de Electricidad y Electrónica, Universidad del País Vasco (UPV/EHU), 48080 Bilbao (Spain); Department of Magnetism and Magnetic Nanomaterials, Ural Federal University, 620002 Ekaterinburg (Russian Federation)

    2014-10-15

    Highlights: • Fe{sub 19}Ni{sub 81} films and FeNi-based multilayers were prepared by magnetron sputtering. • The samples were deposited onto glass substrates at room temperature. • Ti/FeNi films exhibit good (1 1 1) texture and crystallinity. • The thick Cu seed increases the coercive force of the magnetic layer. • The thin Ti spacer restores the magnetic softness of the Cu/Ti/FeNi multilayers. - Abstract: The microstructure and magnetic properties of sputtered permalloy films and FeNi-based multilayers prepared by magnetron sputtering have been studied. X-ray diffraction measurements indicate that Ti/FeNi films exhibit good (1 1 1) texture and crystallinity. Ti/FeNi bilayers with high crystallographic quality have relatively low resistivity. The Ti seed layer does not influence the magnetic properties of FeNi film in Ti/FeNi bilayers, but the thick Cu seed layer leads to an increase of the coercive force of the magnetic layer. For the FeNi films deposited on thick Cu seed layer, the (0 1 0) and (0 0 2) diffraction peaks of hcp nickel were clearly observed. The thin Ti spacer between Cu and FeNi layers prevents the formation of the nickel phase and restores the magnetic softness of the FeNi layer in the Cu/Ti/FeNi sample. Obtained results can be important for the development of multilayer sensitive elements for giant magnetoimpedance or magnetoresistance detectors.

  4. Catalytic properties of Ni-Zn alloy prepared by mechanical alloying for steam reforming from methanol

    Science.gov (United States)

    Park, Jeshin; Kim, Wonbaek; Suh, Changyoul; Kim, Sangbae

    2012-04-01

    Amorphous Zn65Ni35 alloy, the composition of which lies between β1-NiZn and γ-NiZn phases, was prepared by mechanical alloying for 200 hours. The alloy was heat treated at various temperatures and leached in NaOH solution in an effort to enhance the catalytic properties for hydrogen production from methanol. X-ray diffraction study revealed that the amorphous phase crystallized during the heat treatment to the equilibrium β1-NiZn and γ-NiZn phases. It was found that Zn65Ni35 alloy leached after heat treatment at 928 K showed the highest catalytic activity for steam reforming of methanol. It is believed that the enhanced catalytic activity of the Zn65Ni35 alloy heat treated at 928 K is due to the dispersed Ni particles on β1-ZnNi matrix which was formed during leaching of the γ-Zn21Ni5 phase.

  5. Report on the achievements in fiscal 1999. Technology to use gas hydrate as a resource (Research and development for exploration, research and development on drilling technologies, investigative research on an environment influence evaluation method, and investigative research on a utilization system); 1999 nendo gas hydrate shigenka gijutsu sendo kenkyu kaihatsu seika hokokusho. Tansa nado ni kansuru kenkyu kaihatsu, kussaku gijutsu nado ni kansuru kenkyu kaihatsu, kankyo eikyo hyokaho no chosa kenkyu, riyo system ni kansuru chosa kenkyu

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    2000-03-01

    The contents of the research and development performed in the current fiscal year are as follows: (1) research and development for exploration, (2) research and development on drilling technologies, (3) investigative research on an environment influence evaluation method, and (4) investigative research on a utilization system. In Item (1), element analysis data are used to study a method to estimate production environment of hydrate ore beds by using an inorganic ion analyzer and a trace amount element analyzer, the crust thermal flow measuring method is used to discuss a method to analyze the hydrate stability zones together with the data of sea area exploration records, and conceptual design is made on a resource potential evaluation system. In Item (2), experiments and analytical discussions are performed on decomposition control of the gas hydrate solid-liquid interface according to such conditions for the drilling fluid as temperatures and flow rates. Elucidation is given on the initial process of bubble generation for behavior of decomposed gas bubbles. Observation and elucidation are made on two-phase flow behavior of non-Newtonian fluid. In Item (3), conceptual design is carried out on a system to detect elements of shape change in each bed due to fluid movement in a gas hydrate bed and an upper bed. In Item (4), discussions are given on the optimizing conditions for generation and dissociation of gas hydrates. Investigation is made also on a possibility of the transportation and storage system. (NEDO)

  6. FY 1998 annual report on the preliminary research and development of techniques for developing resources from gas-hydrate. Studies on gas-hydrate exploration, excavation techniques, methods for assessing environmental impacts, and gas hydrate handling systems; 1998 nendo gas hydrate shigenka gijutsu sendoken kaihatsu seika hokokusho. Tansanado ni kansuru kenkyu kaihatsu, kussaku gijutsu nado ni kansuru kenkyu kaihatsu, kankyo eikyo hyokaho no kenkyu kaihatsu, riyo system ni kansuru chosa kenkyu

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1999-03-01

    This R and D project is for the preliminary studies on development of the following 4 types of techniques for developing resources from gas-hydrates (GH): (1) gas-hydrate exploration, (2) excavation techniques, (3) methods for assessing environmental impacts, and (4) gas hydrate handling systems. The FY 1988 R and D results are described. For gas-hydrate exploration, the methods for analyzing inorganic ions and trace quantities of elements, which are necessary for accurately estimating the offshore GH around Japan, are established; and case studies are conducted for methods of predicting GH deposit forming mechanisms, and stability fields of GH, based on terrestrial heat flow and seismic data. For excavation techniques, GH decomposition rate is analyzed using a laboratory system which reproduces conditions of excavation of GH layers. For methods for assessing environmental impacts, a geo-hazard predicting model is established, to study ground displacement and gas leakage sensing systems and data transmission systems to cope with the hazards. For gas hydrate handling systems, an overall system is studied, and storage and transportation systems are outlined. (NEDO)

  7. Achievement report for fiscal 1997 on the research and development to lead to gas hydrate using technology. Research and development on exploration, research and development on drilling technologies, survey and research on a method to evaluate environmental impact, and survey and research on a utilization system; 1997 nendo gas haidoreto shigenka gijutsu sendo kenkyu kaihatsu seika hokokusho. Tansanado ni kansuru kenkyu kaihatsu, kussaku gijutsu ni kansuru kenkyu kaihatsu, kankyo eikyo hyokaho no chosa kenkyu, riyo system ni kansuru chosa kenkyu

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1998-09-01

    The present study is intended to analyze comprehensively geophysical, geological and geochemical data, and establish a technology to estimate distribution of gas hydrate (GH) in sea areas around Japan. It is also intended to develop a high-accuracy resource amount calculating method utilizing the result of excavation of GH planned in the future. In order to achieve these goals, the following activities are performed: (1) study on a method to estimate production environment of GH deposits, (2) development of a method to estimate GH stability areas by using the crust thermal flow measuring method, and (3) study on estimation of GH distribution and wide-area potential. For the study (1), an inorganic element analyzer was introduced, and calibration of devices was performed in fiscal 1997. A survey was carried out on literatures related to distribution of inorganic elements and process of GH deposit production. In the study (2), design and trial fabrication were executed on a high-accuracy crust thermal flow measuring device, capable of long-term continuous observation. In the study (3), re-processing focusing on BSR was implemented by using the latest computer and analysis software on the data in which BSR has been confirmed in the surveys done in the past on sea areas around Japan. (NEDO)

  8. Magnetic exchange at realistic CoO/Ni interfaces

    Science.gov (United States)

    Grytsyuk, S.; Cossu, F.; Schwingenschlögl, U.

    2012-08-01

    We study the CoO/Ni interface by first principles calculations. Because the lattice mismatch is large, a realistic description requires a huge supercell. We investigate two interface configurations: in interface 1 the coupling between the Ni and Co atoms is mediated by O, whereas in interface 2 the Ni and Co atoms are in direct contact. We find that the magnetization (including the orbital moment) in interface 1 has a similar value as in bulk Ni but opposite sign, while in interface 2 it grows by 164%. The obtained magnetic moments can be explained by the local atomic environments. In addition, we find effects of charge transfer between the interface atoms. The Co 3 d local density of states of interface 2 exhibits surprisingly small deviations from the corresponding bulk result, although the first coordination sphere is no longer octahedral.

  9. El Niño causes coral bleaching

    National Research Council Canada - National Science Library

    Showstack, Randy

    1998-01-01

    El Niño's extremely warm waters in the Pacific Ocean have caused coral “bleaching” in the waters around the Galapagos Islands, Baja California, and Pacific coast of Panama, according to the National Oceanic and Atmospheric Administration...

  10. Physical characterisation of endodontic instruments in NiTi alloy

    Energy Technology Data Exchange (ETDEWEB)

    Torrisi, L. [Messina Univ. (Italy). Dipartimento di Fisica; Marco, G. di [Ist. di Tecniche Spettroscopiche del CNR, Messina (Italy)

    2000-07-01

    NiTi based endodontic instruments are investigated in functionality and wear. The instrument surfaces have been studied applying Auger electron spectroscopy, mechanical analysis, differential-scanning calorimetry, wear tests, and scanning electron microscopy. (orig.)

  11. Martensitic transformation in nanostructured Fe-Ni alloys

    Science.gov (United States)

    Meng, Q.; Rong, Y.; Hsu, T. Y. Xu Zuyao

    2003-10-01

    In Fe-Ni thin films prepared by magnetron sputtering at room temperature, the bcc structure can exist stably in a larger range of Ni-content than that in Fe-Ni equilibrium diagram. Furthermore, the experiment verified that the bcc structure forms directly from collision of atoms during the sputtering process, rather than the product of fcctobcc martensitic transformation. The starting temperature for bcctofcc transformation in thin films is near to that of bulk Fe-Ni alloys. Theoretical calculations show that the nucleation barrier of martensitic transformation and the critical size of the martensitic embryo increase with decreasing grain size within the nanometer scale, implying that the martensitic transformation in nano-sized grains would be suppressed. Moreover, the autocatalytic tendency of martensitic transformation is significantly weakened within a transformed grain or within its neighboring grain due to the reduction of probability of martensite nucleation or the drop of the stress field at grain boundary produced by martensitic transformation.

  12. Growth mechanism and magnon excitation in NiO nanowalls

    Directory of Open Access Journals (Sweden)

    Yang Chun

    2011-01-01

    Full Text Available Abstract The nanosized effects of short-range multimagnon excitation behavior and short-circuit diffusion in NiO nanowalls synthesized using the Ni grid thermal treatment method were observed. The energy dispersive spectroscopy mapping technique was used to characterize the growth mechanism, and confocal Raman scattering was used to probe the antiferromagnetic exchange energy J 2 between next-nearest-neighboring Ni ions in NiO nanowalls at various growth temperatures below the Neel temperature. This study shows that short spin correlation leads to an exponential dependence of the growth temperatures and the existence of nickel vacancies during the magnon excitation. Four-magnon configurations were determined from the scattering factor, revealing a lowest state and monotonic change with the growth temperature. PACS: 75.47.Lx; 61.82.Rx; 75.50.Tt; 74.25.nd; 72.10.Di

  13. Magnetic exchange at realistic CoO/Ni interfaces

    KAUST Repository

    Grytsiuk, Sergii

    2012-07-30

    We study the CoO/Ni interface by first principles calculations. Because the lattice mismatch is large, a realistic description requires a huge supercell. We investigate two interface configurations: in interface 1 the coupling between the Ni and Co atoms is mediated by O, whereas in interface 2 the Ni and Co atoms are in direct contact. We find that the magnetization (including the orbital moment) in interface 1 has a similar value as in bulk Ni but opposite sign, while in interface 2 it grows by 164%. The obtained magnetic moments can be explained by the local atomic environments. In addition, we find effects of charge transfer between the interface atoms. The Co 3d local density of states of interface 2 exhibits surprisingly small deviations from the corresponding bulk result, although the first coordination sphere is no longer octahedral. © Springer-Verlag 2012.

  14. NiAl-based approach for rocket combustion chambers

    Science.gov (United States)

    Nathal, Michael V. (Inventor); Gayda, John (Inventor); Noebe, Ronald D. (Inventor)

    2005-01-01

    A multi-layered component, such as a rocket engine combustion chamber, includes NiAl or NiAl-based alloy as a structural layer on the hot side of the component. A second structural layer is formed of material selected from Ni-based superalloys, Co-based alloys, Fe-based alloys, Cu, and Cu-based alloys. The second material is more ductile than the NiAl and imparts increased toughness to the component. The second material is selected to enhance one or more predetermined physical properties of the component. Additional structural layers may be included with the additional material(s) being selected for their impact on physical properties of the component.

  15. Magnetoimpedance of FeNi-based asymmetric sensitive elements

    Energy Technology Data Exchange (ETDEWEB)

    Chlenova, A.A., E-mail: chlenova.anna@gmail.com [Ural Federal University, Laboratory of Magnetic Sensorics, Lenin Ave. 51, 620083 Ekaterinburg, Russian Ferderation (Russian Federation); Immanuel Kant Baltic Federal University, Science and Technology Park “Fabrica”, Gaidara str. 6, Kaliningrad (Russian Federation); Svalov, A.V.; Kurlyandskaya, G.V. [Ural Federal University, Laboratory of Magnetic Sensorics, Lenin Ave. 51, 620083 Ekaterinburg, Russian Ferderation (Russian Federation); Universidad del País Vasco, UPV/EHU, Departamento de Electricidad y Electrónica, P.O. Box 644, Bilbao 48080 (Spain); Volchkov, S.O. [Ural Federal University, Laboratory of Magnetic Sensorics, Lenin Ave. 51, 620083 Ekaterinburg, Russian Ferderation (Russian Federation)

    2016-10-01

    [Ti/FeNi]{sub 5}/Ti/Cu/Ti/[FeNi/Ti]{sub x} (x=0–5) multilayers were prepared by sputtering. Their magnetic properties and magnetoimpedance were studied focusing on future technological applications. Both (ΔZ/Z){sub max} and (ΔR/R){sub max} values showed a tendency to decrease with a decrease of the number of magnetic layers of the top multilayer. Such a parameter as an even or odd number of layers is important for the MI value. In the field interval of technological interest all [Ti/FeNi]{sub 5}/Ti/Cu/Ti/[FeNi/Ti]{sub x} structures show similar sensitivities of about 70%/Oe for ΔR/R ratios but the lower the number of magnetic layers in the top multilayer, the higher the operating frequency. - Highlights: • Giant magnetoimpedance effect. • Non-symmetric multilayers sructure. • Biosensing.

  16. Single chamber microbial fuel cell with Ni-Co cathode

    Science.gov (United States)

    Włodarczyk, Barbara; Włodarczyk, Paweł P.; Kalinichenko, Antonina

    2017-10-01

    The possibility of wastewater treatment and the parallel energy production using the Ni-Co alloy as cathode catalyst for single chamber microbial fuel cells is presented in this research. The research included a preparation of catalyst and comparison of COD, NH4+ and NO3- reduction in the reactor without aeration, with aeration and with using a single chamber microbial fuel cell with Ni-Co cathode. The reduction time for COD with the use of microbial fuel cell with the Ni-Co catalyst is similar to the reduction time with aeration. The current density (2.4 A·m-2) and amount of energy (0.48 Wh) obtained in MFC is low, but the obtained amount of energy allows elimination of the energy needed for reactor aeration. It has been shown that the Ni-Co can be used as cathode catalyst in single chamber microbial fuel cells.

  17. NiCo2S4@NiMoO4 Core-Shell Heterostructure Nanotube Arrays Grown on Ni Foam as a Binder-Free Electrode Displayed High Electrochemical Performance with High Capacity

    Science.gov (United States)

    Zhang, Yan; Xu, Jie; Zheng, Yayun; Zhang, Yingjiu; Hu, Xing; Xu, Tingting

    2017-06-01

    Core-shell-structured system has been proved as one of the best architecture for clean energy products owing to its inherited superiorities from both the core and the shell part, which can provide better conductivity and high surface area. Herein, a hierarchical core-shell NiCo2S4@NiMoO4 heterostructure nanotube array on Ni foam (NF) (NiCo2S4@NiMoO4/NF) has been successfully fabricated. Because of its novel heterostructure, the capacitive performance has been enhanced. A specific capacitance up to 2006 F g-1 was obtained at a current density of 5 mA cm-2, which was far higher than that of pristine NiCo2S4 nanotube arrays (about 1264 F g-1). More importantly, NiCo2S4@NiMoO4/NF and active carbon (AC) were congregated as positive electrode and negative electrode in an asymmetric supercapacitor. As-fabricated NiCo2S4@NiMoO4/NF//AC device has a good cyclic behavior with 78% capacitance retention over 2000 cycles, and exhibits a high energy density of 21.4 Wh kg-1 and power density of 58 W kg-1 at 2 mA cm-2. As displayed, the NiCo2S4@NiMoO4/NF core-shell herterostructure holds great promise for supercapacitors in energy storage.

  18. Fracturas de cadera en niños

    Directory of Open Access Journals (Sweden)

    Alvaro A. Vanegas

    1990-03-01

    Full Text Available Se hizo una evaluación retrospectiva de los resultados finales obtenidos en 37 niñas y 34 niños, de 2 a 16 años, con fractura de cadera, tratados por el grupo de Ortopedia Infantil de la Facultad de Medicina de la Universidad de Antioquia y el Hospital Universitario San Vicente de
    Paúl, entre 1976 y 1986.

  19. Cu–Ni nanoalloy phase diagram – Prediction and experiment

    OpenAIRE

    Sopoušek Jiří; Vřešťál Jan; Pinkas Jiří; Brož Pavel; Buršík Jiří; Stýskalík Aleš; Škoda David; Zobač Ondřej; Lee Joonho

    2014-01-01

    The Cu-Ni nanoalloy phase diagram respecting the nanoparticle size as an extra variable was calculated by the CALPHAD method. The samples of the Cu-Ni nanoalloys were prepared by the solvothermal synthesis from metal precursors. The samples were characterized by means of dynamic light scattering (DLS), infrared spectroscopy (IR), inductively coupled plasma optical emission spectroscopy (ICP/OES), transmission electron microscopy (TEM, HRTEM), and differential scanning calorimetry (DSC). The n...

  20. Négation et coordination: la conjonction ni

    NARCIS (Netherlands)

    Swart, Henriëtte de

    2001-01-01

    Dans cet article, nous étudions la position de ni dans le système de la négation en français moderne. Notre point de départ réside dans l'observation que ni est une conjonction de coordination (section 1), qui sert à unir deux phrases ou syntagmes négatifs (section 2). Sur la base de la