Vacuum distilling vessel

Energy Technology Data Exchange (ETDEWEB)

Reik, H

1928-12-27

Vacuum distilling vessel for mineral oil and the like, characterized by the ring-form or polyconal stiffeners arranged inside, suitably eccentric to the casing, being held at a distance from the casing by connecting members of such a height that in the resulting space if necessary can be arranged vapor-distributing pipes and a complete removal of the residue is possible.

Improvement of Egyptian vacuum distillates by urea dewaxing

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Ehssan M.R. Nassef

2015-09-01

Full Text Available The dewaxing of paraffinic lube stocks is an essential step in the production of lubricants to improve the operability of machines especially in winter. The present work deals with study of the urea dewaxing process of two types of Egyptian vacuum distillates. The effect of different compositions of methanol to water saturated with urea and yield of the oil, percent of wax, pour point, refractive index, viscosity, viscosity index and specific gravity of the oil produced from the two types of distillates (I and II were evaluated. The operating conditions of the urea adduct formation with n-paraffins using methanol to water mixture achieved the best pour point at −3.88 °C from an initial temperature of 4.4 °C for distillate I at (25/75 methanol to water. At the same ratio of methanol to water the best specific gravity of oil produced changed from 0.865 to 0.867, with viscosity index of 80. Percent yield of 50% for oil and percent wax of 50% were obtained. Results for distillate II, of higher specific gravity, are comparatively higher than those for distillate I. Experiments were carried out at room temperature.

Recovery of volatile aroma compounds from black currant juice by vacuum membrane distillation

DEFF Research Database (Denmark)

Bagger-Jørgensen, Rico; Meyer, Anne S.; Warming, C.

2004-01-01

This study evaluated the recovery of seven characteristic black currant aroma compounds by vacuum membrane distillation (VMD) carried out at low temperatures (10-45 degreesC) and at varying feed flow rates (100-500 l/h) in a lab scale membrane distillation set tip. VMD at feed flow from 100 to 500...

STUDY OF THE THERMAL CRACKING DURING THE VACUUM DISTILLATION OF ATMOSPHERIC RESIDUE OF CRUDE OIL

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JAOUAD ELAYANE

2017-03-01

Full Text Available This article concerns the study of the thermal cracking as undesirable phenomenon in the vacuum distillation of atmospheric residue of crude oil. In this point, we have sought to identify and characterize the effect of the increase in the temperature of vacuum distillation on the separation and the modification of the constituents of atmospheric residue of crude oil whose origin is Arabian Light. This study has been carried out by several techniques of analysis such as the density (ASTM D4052, distillation (ASTM D1160, determination of heavy metals nickel and vanadium (IFP9422, dosing of Conradson Carbon (ASTM D189, dosing of asphaltenes (ASTM D2549 and dosage of PCI (polycyclic aromatics (ASTM D 5186. The results showed a clear idea on the decomposition of the atmospheric residue and their influence on the performance of the vacuum distillation unit.

Seawater desalination with solar-energy-integrated vacuum membrane distillation system

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Fang Wang

2017-03-01

Full Text Available This study designed and tested a novel type of solar-energy-integrated vacuum membrane distillation (VMD system for seawater desalination under actual environmental conditions in Wuhan, China. The system consists of eight parts: a seawater tank, solar collector, solar cooker, inclined VMD evaporator, circulating water vacuum pump, heat exchanger, fresh water tank, and brine tank. Natural seawater was used as feed and a hydrophobic hollow-fiber membrane module was used to improve seawater desalination. The experiment was conducted during a typical summer day. Results showed that when the highest ambient temperature was 33 °C, the maximum value of the average solar intensity was 1,080 W/m2. The system was able to generate 36 kg (per m2 membrane module distilled fresh water during 1 day (7:00 am until 6:00 pm, the retention rate was between 99.67 and 99.987%, and electrical conductivity was between 0.00276 and 0.0673 mS/cm. The average salt rejection was over 90%. The proposed VMD system shows favorable potential application in desalination of brackish waters or high-salt wastewater treatment, as well.

Fractionation of Java Citronella Oil and Citronellal Purification by Batch Vacuum Fractional Distillation

Science.gov (United States)

Eden, W. T.; Alighiri, D.; Cahyono, E.; Supardi, K. I.; Wijayati, N.

2018-04-01

The aim of this work was to assess the performance of a vacuum fractionating column for the fractionation of Java Citronella Oil (Cymbopogon winterianus) and citronellal purification during batch mode operation at vacuum -76 cmHg and reflux ratios 5:1. Based on GC-MS analysis of Java Citronella Oil is known that citronellal, citronellol, and geraniol has yielded 21,59%; 7,43%; and 34,27%, respectively. Fractional distillation under reduced pressure and continued redistilled are needed to isolate the component of Java Citronella Oil. Redistilled can improve the purity, then distillate collected while the temperature changed. In the first distillate yielded citronellal with a purity of 75.67%. The first distillate obtained residue rhodinol product will then be carried back to separation into citronellol and geraniol. The purity of citronellol reached 80,65% purity, whereas geraniol reached 76.63% purity. Citronellal Purification resulting citronellal to 95.10% purity and p-menthane-3,8-diol reached 75.95% purity.

Performance Investigation of O-Ring Vacuum Membrane Distillation Module for Water Desalination

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Adnan Alhathal Alanezi

2016-01-01

Full Text Available A new O-ring flat sheet membrane module design was used to investigate the performance of Vacuum Membrane Distillation (VMD for water desalination using two commercial polytetrafluoroethylene (PTFE and polyvinylidene fluoride (PVDF flat sheet hydrophobic membranes. The design of the membrane module proved its applicability for achieving a high heat transfer coefficient of the order of 103 (W/m2 K and a high Reynolds number (Re. VMD experiments were conducted to measure the heat and mass transfer coefficients within the membrane module. The effects of the process parameters, such as the feed temperature, feed flow rate, vacuum degree, and feed concentration, on the permeate flux have been investigated. The feed temperature, feed flow rate, and vacuum degree play an important role in enhancing the performance of the VMD process; therefore, optimizing all of these parameters is the best way to achieve a high permeate flux. The PTFE membrane showed better performance than the PVDF membrane in VMD desalination. The obtained water flux is relatively high compared to that reported in the literature, reaching 43.8 and 52.6 (kg/m2 h for PVDF and PTFE, respectively. The salt rejection of NaCl was higher than 99% for both membranes.

KINETIC MODELS STUDY OF HYDRODESULPHURIZATION VACUUM DISTILLATE REACTION

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AbdulMunem A. Karim

2013-05-01

Full Text Available    This study deals with  kinetics of hydrodesulphurization (HDS reaction of vacuum gas oil (611-833 K which was distillated from Kirkuk crude oil and which was obtained by blending the fractions, light vacuum gas oil (611 - 650 K, medium vacuum gas oil (650-690 K, heavy vacuum gas oil (690-727 K and very heavy vacuum gas oil (727-833 K.   The vacuum gas oil was hydrotreated on a commercial cobalt-molybdenum alumina catalyst presulfied at specified conditions in a laboratory trickle bed reactor. The reaction temperature range (583-643 K,liquid hourly space velocity range (1.5-3.75 h-1 and hydrogen pressure was kept constant at 3.5 MPa with hydrogen to oil ratio about 250 lt/lt.           The conversion results for desulphurization reaction appeared to obey the second order reaction. According to this model, the rate constants for desulphurization reaction were determined. Finally, the apparent activation energy (Ea, enthalpy of activation ( H* and entropy ( S* were calculated based on the values of rate constant (k2 and were equal 80.3792 KJ/mole, 75.2974 KJ/mole and 197.493 J/mole, respectively.

Pilot-Scale Removal Of Fluoride From Legacy Plutonium Materials Using Vacuum Salt Distillation

International Nuclear Information System (INIS)

Pierce, R. A.; Pak, D. J.

2012-01-01

Between September 2009 and January 2011, the Savannah River National Laboratory (SRNL) and HB-Line designed, developed, tested, and successfully deployed a system for the distillation of chloride salts. In 2011, SRNL adapted the technology for the removal of fluoride from fluoride-bearing salts. The method involved an in situ reaction between potassium hydroxide (KOH) and the fluoride salt to yield potassium fluoride (KF) and the corresponding oxide. The KF and excess KOH can be distilled below 1000°C using vacuum salt distillation (VSD). The apparatus for vacuum distillation contains a zone heated by a furnace and a zone actively cooled using either recirculated water or compressed air. During a vacuum distillation operation, a sample boat containing the feed material is placed into the apparatus while it is cool, and the system is sealed. The system is evacuated using a vacuum pump. Once a sufficient vacuum is attaned, heating begins. Volatile salts distill from the heated zone to the cooled zone where they condense, leaving behind the non-volatile material in the feed boat. Studies discussed in this report were performed involving the use of non-radioactive simulants in small-scale and pilot-scale systems as well as radioactive testing of a small-scale system with plutonium-bearing materials. Aspects of interest include removable liner design considerations, boat materials, in-line moisture absorption, and salt deposition

Low temperature destructive distillation

Energy Technology Data Exchange (ETDEWEB)

1938-07-05

A process is given and apparatus is described for the destructive distillation at low temperature of coal, oil shale, and the like by subjection to the action of a stream of hot gases or superhearted steam, flowing in a closed circuit. Subsequent treatment of the distillation residues with a gas stream containing oxygen results in combustion of the carbon-containing material therein brings to a high temperature the solid residue, in which the process comprises subsequently contacting the hot solid residue with the fluid stream effecting the distillation.

Application Of Vacuum Salt Distillation Technology For The Removal Of Fluoride And Chloride From Legacy Fissile Materials

International Nuclear Information System (INIS)

Pierce, R.; Peters, T.

2011-01-01

Between September 2009 and January 2011, the Savannah River National Laboratory (SRNL) and the Savannah River Site (SRS) HB-Line Facility designed, developed, tested, and successfully deployed a production-scale system for the distillation of sodium chloride (NaCl) and potassium chloride (KCl) from plutonium oxide (PuO 2 ). Subsequent efforts adapted the vacuum salt distillation (VSD) technology for the removal of chloride and fluoride from less-volatile halide salts at the same process temperature and vacuum. Calcium chloride (CaCl 2 ), calcium fluoride (CaF 2 ), and plutonium fluoride (PuF 3 ) were of particular concern. To enable the use of the same operating conditions for the distillation process, SRNL employed in situ exchange reactions to convert the less-volatile halide salts to compounds that facilitated the distillation of halide without removal of plutonium. SRNL demonstrated the removal of halide from CaCl 2 , CaF 2 and PuF 3 below 1000 C using VSD technology.

Study on Exploration of Azeotropic Point of Pb-Sb Alloys by Vacuum Distillation and Ab Initio Molecular Dynamic Simulation

Science.gov (United States)

Song, Bingyi; Jiang, Wenlong; Yang, Bin; Chen, Xiumin; Xu, Baoqiang; Kong, Lingxin; Liu, Dachun; Dai, Yongnian

2016-10-01

The possibility of the separation of Pb-Sb alloys by vacuum distillation was investigated theoretically. The results show that Pb and Sb can be separated by vacuum distillation. However, the experimental results show that vacuum distillation technique does not provide clear separation. According to the literature, Pb-Sb alloys belong to azeotropic compounds under some certain temperature; the experiment and computer simulation were carried out based on the exceptional condition so as to analyze the reason from the experiment and microstructure of Pb-Sb alloys perspective. The separation of Pb-Sb alloys by vacuum distillation was experimentally carried out to probe the azeotropic point. Also, the functions, such as partial radial distributions functions, the structure factor, mean square displacement, and the density of state, were calculated by ab-initio molecular dynamics for the representation of the structure and properties of Pb-Sb alloys with different composition of Sb. The experimental results indicate that there exists common volatilization for Pb-Sb alloys when Sb content is 16.5 wt pct. On the other hand, the calculation results show that there is an intense interaction between Pb and Sb when Sb content is 22 wt pct, which supports the experimental results although Sb content is slightly deviation.

High temperature high vacuum creep testing facilities

International Nuclear Information System (INIS)

Matta, M.K.

1985-01-01

Creep is the term used to describe time-dependent plastic flow of metals under conditions of constant load or stress at constant high temperature. Creep has an important considerations for materials operating under stresses at high temperatures for long time such as cladding materials, pressure vessels, steam turbines, boilers,...etc. These two creep machines measures the creep of materials and alloys at high temperature under high vacuum at constant stress. By the two chart recorders attached to the system one could register time and temperature versus strain during the test . This report consists of three chapters, chapter I is the introduction, chapter II is the technical description of the creep machines while chapter III discuss some experimental data on the creep behaviour. Of helium implanted stainless steel. 13 fig., 3 tab

Thermodynamic Behavior of Lead-Antimony Alloy in Vacuum Distillation

Institute of Scientific and Technical Information of China (English)

1989-01-01

The distribution of metals in Pb-Sb ailoy during vacuum distillation was calculated.The composition curve of vapor-liquid phases determined by this work is different from those of. other researchers.The curve intersects the diagonal at C.The compositions of vapor and liquid at C are identical.The antimony content of vapor on the left of C is less than that of liquid,and the vapor on the right-side of C contains more antimony.These characteristics can be applied to the elimination of antimony from crude lead or the elimination of lead from crude antimony.The position of C moves rightwards with temperature increment.The discrepency among the compositions of C suggested by diffrent authors was explained.

Vacuum distillation residue upgrading by an indigenous Bacillus cereus.

Science.gov (United States)

Tabatabaee, Mitra Sadat; Mazaheri Assadi, Mahnaz

2013-07-16

Biological processing of heavy fractions of crude oils offers less severe process conditions and higher selectivity for refining. Biochemical Processes are expected to be low demand energy processes and certainly ecofriendly. A strain of biosurfactant producing bacterium was isolated from an oil contaminated soil at Tehran refinery distillation unit. Based on selected phenotypic and genotypic characteristic including morphology, biochemical proprety, and 16 SrRNA sequencing identified as a novel strain of Bacillus cereus (JQ178332). This bacterium endures a wide range of pH, salinity and temperature. This specific strain utilizes both paraffin and anthracene as samples of aliphatic and polycyclic aromatic hydrocarbons. The ability of this bacterium to acquire all its energy and chemical requirements from Vacuum Distillation Residue (VR), as a net sample of problematic hydrocarbons in refineries, was studied. SARA test ASTM D4124-01 revealed 65.5% decrease in asphaltenic, 22.1% in aliphatics and 30.3% in Aromatics content of the VR in MSM medium. Further results with 0.9% saline showed 55% decrease in asphaltene content and 2.1% Aromatics respectively. Remarkable abilities of this microorganism propose its application in an ecofriendly technology to upgrade heavy crude oils.

Sodium removal of fuel elements by vacuum distillation

International Nuclear Information System (INIS)

Buescher, E.; Haubold, W.; Jansing, W.; Kirchner, G.

1978-01-01

Cleaning of sodium-wetted core components can be performed by using either lead, moist nitrogen, or alcohol. The advantages of these methods for cleaning fuel elements without causing damage are well known. The disadvantage is that large amounts of radioactive liquids are formed during handling in the latter two cases. In this paper a new method to clean components is described. The main idea is to remove all liquid metal from the core components within a comparatively short period of time. Fuel elements removed from the reactor must be cooled because of high decay heat release. To date, vacuum distillation of fuel elements has not yet been applied

Sodium distiller II

International Nuclear Information System (INIS)

Goncalves, A.C.; Castro, P.M. e; Torres, A.R.; Correa, S.M.

1990-01-01

A sodium distiller allows the evaluation of the sodium purity, contained in plants and circuits of Fast Reactors. The sodium distillers of the IEN Reactor's Department was developed initially as a prototype, for the testing of the distillation process and in a second step, as a equipment dedicated to attendance the operation of these circuits. This last one was build in stainless steel, with external heat, rotating crucible of nickel for four samples, purge system for pipe cleaning and a sight glass that permits the observation of the distillation during all the operation. The major advantage of this equipment is the short time to do a distillation operation, which permits its routine utilization. As a consequence of the development of the distillers and its auxiliary systems an important amount of new information was gathered concerning components and systems behaviour under high temperature, vacuum and sodium. (author)

EVALUATION OF A VACUUM DISTILLER FOR PERFORMING METHOD 8261 ANALYSES

Science.gov (United States)

Vacuum distillation uses a specialized apparatus. This apparatus has been developed and patented by the EPA. Through the Federal Technology Transfer Act this invention has been made available for commercialization. Available vendors for this instrumentation are being evaluated. ...

Vacuum distillation for the separation of LiCl-KCl eutectic salt and cadmium in pyro process

International Nuclear Information System (INIS)

Kwon, S. W.; Park, K. M.; Lee, S. J.; Park, S. B.; Woo, M. S.; Kim, K. R.; Kim, J. G.; Ahn, D. H.; Lee, H. S.

2010-10-01

Electrorefining is a key step in pyro processing. Electrorefining process is generally composed of two recovery steps- a deposit of uranium onto a solid cathode (electrorefining) and then the recovery of the remaining uranium and Tru (Transuranic) elements simultaneously by a liquid cadmium cathode (electrowinning). In this study, distillation experiments of a LiCl-KCl eutectic salt and cadmium metal were carried out to examine the distillation behaviors for the development of the electrorefining and the electrowinning processes. The experimental set-up was composed of a distillation tower with an evaporator and a condenser, vacuum pump, control unit, and an off gas treatment system. The solid-liquid separation prior to distillation of the LiCl-KCl eutectic salt was proposed and found to be feasible for the reduction of the burden of the distillation process. The LiCl-KCl eutectic salt was successfully distilled after the liquid salt separation. Distillation experiments for cadmium metal were also carried out. The apparent evaporation rates of LiCl-KCl eutectic salt and cadmium increased with an increasing temperature. The evaporation behaviors of cadmium metal and cadmium-cerium alloy were compared. Cadmium in the alloy was successfully distilled and separated from cerium. The evaporation rate of cadmium in the alloy was lower than that of cadmium metal. The low evaporation rate of the alloy was probably caused by the formation of an intermetallic compound and the residual salt during the preparation of the alloy. Therefore, the distillation temperature for the distillation of the liquid cathode should be higher than the distillation of cadmium metal. The measured evaporation rates of the eutectic salt and cadmium were compared with the values calculated by a relation based on the kinetics of gases. The theoretical values of the evaporation rate calculated by the Hertz-Langmuir relation were higher than the experimental values. The deviations were compensated for

Vacuum Distillation Residue Upgrading by an Indigenous Bacillus Cereus

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Mitra Sadat Tabatabaee

2013-07-01

Full Text Available Background:Biological processing of heavy fractions of crude oils offers less severe process conditions and higher selectivity for refining. Biochemical Processes are expected to be low demand energy processes and certainly ecofriendly.Results:A strain of biosurfactant producing bacterium was isolated from an oil contaminated soil at Tehran refinery distillation unit. Based on selected phenotypic and genotypic characteristic including morphology, biochemical proprety, and 16 SrRNA sequencing identified as a novel strain of Bacillus cereus (JQ178332. This bacterium endures a wide range of pH, salinity and temperature. This specific strain utilizes both paraffin and anthracene as samples of aliphatic and polycyclic aromatic hydrocarbons. The ability of this bacterium to acquire all its energy and chemical requirements from Vacuum Distillation Residue (VR, as a net sample of problematic hydrocarbons in refineries, was studied. SARA test ASTM D4124-01 revealed 65.5% decrease in asphaltenic, 22.1% in aliphatics and 30.3% in Aromatics content of the VR in MSM medium. Further results with 0.9% saline showed 55% decrease in asphaltene content and 2.1% Aromatics respectively.Conclusion:Remarkable abilities of this microorganism propose its application in an ecofriendly technology to upgrade heavy crude oils.

Modifications in the vacuum loop of the distillation system - Annex 7; Prilog 7 - Izmene u vakuumskoj grani destilacionog sistema

Energy Technology Data Exchange (ETDEWEB)

Milosevic, D [Institute of Nuclear Sciences Boris Kidric, Reaktor RA, Vinca, Beograd (Serbia and Montenegro)

1964-12-15

The heavy water distillation system is foreseen to operate in a continuous regime during reactor operation. The vacuum loop is designed to achieve absolute pressure of 70 mmHg in the evaporator. Modifications in the vacuum loop of the distillation system were necessary in order to attain good efficiency of the distillation, i.e clean heavy water coolant.

Development of a vacuum distillation process for Pu pyro-chemistry spent salts treatment

International Nuclear Information System (INIS)

Bourges, G.; Lambertin, D.; Baudrot, C.; Pescayre, L.; Thiebaut, C.

2004-01-01

The pyrochemical purification of plutonium has generated spent salts, which are disposed in nuclear facility. To reduce stored quantities, the development of a pyrochemical treatment is in progress. The feed salt, typically composed of various Pu and Am species spread into monovalent or divalent chloride matrix, is first oxidized to convert the actinides into oxides. Then the chlorides are separated from the actinide oxides by vacuum distillation. Temperatures higher than 750 deg C for mono-chloride salts mixture NaCl/KCl and higher than 1100 deg C for divalent CaCl 2 base salts, are required to produce an industrial flow of vaporization. Inactive qualification of the process for NaCl/KCl base salt has been carried with lanthanide surrogates. Then, a pilot equipment, called Distillator has been designed and built for production-scale distillation of NaCl/KCl and CaCl 2 oxidized plutonium salts. Industrial flows of vaporization have been obtained with this pilot equipment: about 4 g/cm 2 /h for NaCl/KCl at 800 - 900 deg C and 1 Pa, and more than 1.5 g/cm 2 /h for CaCl 2 base salts between 1000 - 1200 deg C at 0.1 Pa. The last step will be the integration of the Distillator into a glove box. (authors)

Decay rate of the false vacuum at high temperatures

International Nuclear Information System (INIS)

Eboli, O.J.P.; Marques, G.C.

1986-01-01

We investigate, within the semiclassical approach, the high temperature behaviour of the decay rate (Γ) of the metastable vacuum in Field Theory. We exhibit some exactly soluble (1+1) and (3+1) dimensional examples and develop a formal expression for γ in the high temperature limit. (Author) [pt

Fundamental study on the salt distillation from the mixtures of rare earth precipitates and LiCl-KCl eutectic salt

International Nuclear Information System (INIS)

Yang, H. C.; Eun, H. C.; Cho, Y. Z.; Lee, H. S.; Kim, I. T.

2008-01-01

An electrorefining process of spent nuclear fuel generates waste salt containing some radioactive metal chlorides. The most effective method to reduce salt waste volume is to separate radioactive metals from non-radioactive salts. A promising approach is to change radioactive metal chlorides into salt-insoluble oxides by an oxygen sparging. Following this, salt distillation process is available to effectively separate the precipitated particulate metal oxides from salt. This study investigated the distillation rates of LiCl-KCl eutectic salt under different vacuums at elevated temperatures. The first part study investigated distillation rates of eutectic salt under different vacuums at high temperatures by using thermo-gravimetric furnace system. In the second part, we tested the removal of eutectic salt from the RE precipitates by using the laboratory vacuum distillation furnace system. Investigated variables were the temperature of mixture, the degree of vacuum and the time

Metal–Organic Framework-Functionalized Alumina Membranes for Vacuum Membrane Distillation

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Jian Zuo

2016-12-01

Full Text Available Nature-mimetic hydrophobic membranes with high wetting resistance have been designed for seawater desalination via vacuum membrane distillation (VMD in this study. This is achieved through molecular engineering of metal–organic framework (MOF-functionalized alumina surfaces. A two-step synthetic strategy was invented to design the hydrophobic membranes: (1 to intergrow MOF crystals on the alumina tube substrate and (2 to introduce perfluoro molecules onto the MOF functionalized membrane surface. With the first step, the surface morphology, especially the hierarchical roughness, can be controlled by tuning the MOF crystal structure. After the second step, the perfluoro molecules function as an ultrathin layer of hydrophobic floss, which lowers the surface energy. Therefore, the resultant membranes do not only possess the intrinsic advantages of alumina supports such as high stability and high water permeability, but also have a hydrophobic surface formed by MOF functionalization. The membrane prepared under an optimum condition achieved a good VMD flux of 32.3 L/m2-h at 60 °C. This study may open up a totally new approach for design of next-generation high performance membrane distillation membranes for seawater desalination.

Removing lead from metallic mixture of waste printed circuit boards by vacuum distillation: factorial design and removal mechanism.

Science.gov (United States)

Li, Xingang; Gao, Yujie; Ding, Hui

2013-10-01

The lead removal from the metallic mixture of waste printed circuit boards by vacuum distillation was optimized using experimental design, and a mathematical model was established to elucidate the removal mechanism. The variables studied in lead evaporation consisted of the chamber pressure, heating temperature, heating time, particle size and initial mass. The low-level chamber pressure was fixed at 0.1 Pa as the operation pressure. The application of two-level factorial design generated a first-order polynomial that agreed well with the data for evaporation efficiency of lead. The heating temperature and heating time exhibited significant effects on the efficiency, which was validated by means of the copper-lead mixture experiments. The optimized operating conditions within the region studied were the chamber pressure of 0.1 Pa, heating temperature of 1023 K and heating time of 120 min. After the conditions were employed to remove lead from the metallic mixture of waste printed circuit boards, the efficiency was 99.97%. The mechanism of the effects was elucidated by mathematical modeling that deals with evaporation, mass transfer and condensation, and can be applied to a wider range of metal removal by vacuum distillation. Copyright © 2013 Elsevier Ltd. All rights reserved.

A Comparative study between MPC and PI controller to control vacuum distillation unit for producing LVGO, MVGO, and HVGO

Science.gov (United States)

Wahid, A.; Prasetyo, A. P.

2018-03-01

This study describes the selection of controllers in the vacuum distillation unit (VDU) between a model predictive control (MPC) and a proportional-integral (PI) controller by comparing the integral square error (ISE) values. Design of VDU in this simulation is based on modified Metso Automation Inc. scheme. Controlled variables in this study are feed flow rate, feed temperature, top stage pressure, condenser level, bottom stage temperature, LVGO (light vacuum gas oil), MVGO (medium vacuum gas oil), and HVGO (heavy vacuum gas oil) flow rate. As a result, control performance improvements occurred as using MPC compared to PI controllers, when testing a set-point change, of feed flow rate control, feed temperature, top-stage pressure, bottom-stage temperature and flow rate of LVGO, MVGO, and HVGO, respectively, 36%, 6%, 92%, 53%, 90%, 96% and 88%. Only on condenser level control PI performs much better than the MPC. So PI controller is used for level condenser control. While for the test of disturbance rejection, by changing feed flow rate by 10%, there is improvement of control performance using MPC compared to PI controller on feed temperature control, top-stage pressure, bottom-stage temperature and flow rate LVGO, MVGO and HVGO 0.3%, 0.7%, 14%, 2.7%, 10.6% and 4.3%, respectively.

Quality improvement by batch vacuum distillation and physicochemical characterization of clove leaf oil in Central Java, Indonesia

Science.gov (United States)

Alighiri, D.; Eden, W. T.; Cahyono, E.; Supardi, K. I.

2018-03-01

Clove leaf oil is one of the essential oils which have high economic value and produced in considerable amount in Indonesia. As many as 60% of clove oil produced by Indonesia has exported to many countries in the world. Musuk and Ringinlarik Village, Boyolali District, Central Java Province is one of the areas in Indonesia which became the primary supplier of Indonesian clove leaf oil. Although, the quality of the resulting yield is still low because it uses a simple distillation kettle in the form of the iron plate or used the drum. The clove leaf oil produced by steam distillation from the dry whole leaves of the clove tree. The color of the oil is brownish black and dirty with the odor are fresh distilled, spicy, warm, and terpenic. The specific gravity at 25 °C of 1.529, the refractive index at 20 °C of 1.030, and based on GC-MS analysis, eugenol levels only 68% and caryophyllene is too high, i.e., 20%. The quality of clove leaf oil produced does not meet the specifications of international market standards. This work aimed to improve the quality of Indonesian clove leaf oil. The purifications done in this research was used by batch vacuum distillation with mode operation at vacuum -76 cmHg and reflux ratios 5:1. Clove leaf oil produced by using this method has a better physicochemical characterization, i.e., the appearance that is yellow to pale color with the odor is spicy, woody, warm, and terpenic. The specific gravity at 25 °C of 1.533, the refractive index at 20 °C of 1.038, and eugenol and caryophyllene contents has yielded 80.58% and 10%, respectively. By The enhancement quality of clove leaf oil by batch vacuum distillation, these oil is already meet international standards and income of clove leaf oil grower in Musuk and Ringinlarik Village, Boyolali District, Central Java Province, Indonesia could be increased.

Separation and Recycling of Spent Carbon Cathode Blocks in the Aluminum Industry by the Vacuum Distillation Process

Science.gov (United States)

Yaowu, Wang; Jianping, Peng; Yuezhong, Di

2018-04-01

Aluminum is the second most produced metal after iron. China is the top producer of primary aluminum with a production capacity of 41,000 kt and an output in 2016 of 32,000 kt. A large amount of spent carbon cathode block (SCCB) is produced after electrolytic pot failure. SCCB consists of carbon, fluorides, alkali metals, carbides, nitrides, cyanides, and oxides, and is considered to be a hazardous material because it contains significant concentrations of toxic and soluble cyanides and fluorides. There is no economical and efficient process for the treatment of SCCB and is most commonly disposed in landfill. In this study, the vacuum distillation process (VDP) has been used to separate and recycle SCCB. The results show that Na3AlF6, NaF, and sodium metal can be effectively separated from SCCB by VDP, and the distillation ratio is above 80% at a distillation temperature of 1200°C. The carbon content in the distilled SCCB is above 91% and the impurities are mainly CaF2 and Al2O3.

VOLATILE ORGANO-METALLOIDS IN BIO-SOLID MATERIALS: ANALYSIS BY VACUUM DISTILLATION-GC/MS

Science.gov (United States)

An analytical method based on vacuum distillation-gas chromatography-mass spectrometry (VD-GC-MS)was developed for determining volatile organo-metalloid contaminants in bio-solid materials. Methodperformance was evaluated for dimethylselenide (DMSe), dimethyldisel...

Separation of tritium from heavy water by vacuum distillation

International Nuclear Information System (INIS)

Vidal, M.I.; Cabrera, C.A.

1996-01-01

In this report the feasibility of using vacuum distillation to detriate the moderator of a HWR nuclear power plant is studied. It is intended to use, for this purpose, the Atucha I nuclear power plant present facilities. The physical-chemistry of the system is described and the most appropriate range of operating conditions is examined. The availability of data to make use of the present equipment is also analyzed. (author). 20 refs., 3 figs., 1 tab

2,3-Butanediol recovery from fermentation broth by alcohol precipitation and vacuum distillation.

Science.gov (United States)

Jeon, Sangjun; Kim, Duk-Ki; Song, Hyohak; Lee, Hee Jong; Park, Sunghoon; Seung, Doyoung; Chang, Yong Keun

2014-04-01

This study presents a new and effective downstream process to recover 2,3-butanediol (2,3-BD) from fermentation broth which is produced by a recombinant Klebsiella pneumoniae strain. The ldhA-deficient K. pneumoniae strain yielded about 90 g/L of 2,3-BD, along with a number of by-products, such as organic acids and alcohols, in a 65 h fed-batch fermentation. The pH-adjusted cell-free fermentation broth was firstly concentrated until 2,3-BD reached around 500 g/L by vacuum evaporation at 50°C and 50 mbar vacuum pressure. The concentrated solution was further treated using light alcohols, including methanol, ethanol, and isopropanol, for the precipitation of organic acids and inorganic salts. Isopropanol showed the highest removal efficiency, in which 92.5% and 99.8% of organic acids and inorganic salts were precipitated, respectively. At a final step, a vacuum distillation process enabled the recovery of 76.2% of the treated 2,3-BD, with 96.1% purity, indicating that fermentatively produced 2,3-BD is effectively recovered by a simple alcohol precipitation and vacuum distillation. Copyright © 2013 The Society for Biotechnology, Japan. Published by Elsevier B.V. All rights reserved.

Structural characterization of asphaltenes from vacuum residue distillation

International Nuclear Information System (INIS)

Silva, Ronaldo C.; Seidl, Peter R.; Menezes, Sonia M.C. de; Teixeira, Marco A.G.

2001-01-01

The aim of this work was to do structural characterization of asphaltenes from different vacuum residues distillation. Several average molecular parameters using some analytical techniques were obtained and these techniques were: nuclear magnetic resonance ( 1 H and 13 C NMR), elemental analysis (C,H,N,O and S content), Fourier transform infrared (FT-IR), vapor pressure osmometry and gel permeation chromatography. Particularly from NMR, some important molecular parameters were obtained, such as aromatic carbon fraction, aliphatic carbons fraction, alkyl substituted aromatic carbons, unsubstituted aromatic carbons, etc. Molecular modeling will be employed to build the structure of asphaltenes using the experimental data. (author)

Importance of low-temperature distillation of coal for German fuel economics

Energy Technology Data Exchange (ETDEWEB)

Rosendahl, F

1942-01-01

Improved processes are available to give low-temperature distillation products economic importance. Low-temperature distillation is limited to the utilization of high-volatile nut coals and briquets. The coke formed can be used as a smokeless fuel, and the tar directly as a fuel oil. Phenols can be extracted, in order to work up the residue into fuel oil and motor fuel. Large deposits of coal in Upper Silesia and in the Saar District are suitable for low-temperature distillation.

Low temperature distillation

Energy Technology Data Exchange (ETDEWEB)

Vandegrift, J N; Postel, C

1929-04-09

To recover gas, oil tars, and coked residues by low temperature distillation from bituminous coals, lignites, oil shales, and the like, the raw material is fed from a hopper into a rotary retort which is zonally heated, the temperature being greatest at the discharge end. The material is heated first to a relatively low temperature, thereby removing the moisture and lighter volatiles which are withdrawn through a pipe by the suction of a pump, while the higher boiling point volatiles and fixed gases are withdrawn by suction through an outlet from the higher temperature zone. The vapors withdrawn from the opposite ends of the retort pass through separate vapor lines and condensers, and the suction in each end of the retort, caused by the pumps, is controlled by valves, which also control the location of the neutral point in the retort formed by said suction. Air and inert gas may be introduced into the retort from pipe and stack respectively through a pipe, and steam may be admitted into the high temperature zone through a pipe.

Development of multi-channel high power rectangular RF window for LHCD system employing high temperature vacuum brazing technique

International Nuclear Information System (INIS)

Sharma, P K; Ambulkar, K K; Parmar, P R; Virani, C G; Thakur, A L; Joshi, L M; Nangru, S C

2010-01-01

A 3.7 GHz., 120 kW (pulsed), lower hybrid current drive (LHCD) system is employed to drive non-inductive plasma current in ADITYA tokamak. The rf power is coupled to the plasma through grill antenna and is placed in vacuum environment. A vacuum break between the pressurized transmission line and the grill antenna is achieved with the help of a multi (eight) channel rectangular RF vacuum window. The phasing between adjacent channels of 8-channel window (arranged in two rows) is important for launching lower hybrid waves and each channel should have independent vacuum window so that phase information is retained. The geometrical parameter of the grill antenna, like periodicity (9mm), channel dimensions (cross sectional dimension of 76mm x 7mm), etc. is to be maintained. These design constraint demanded a development of a multi channel rectangular RF vacuum window. To handle rf losses and thermal effects, high temperature vacuum brazing techniques is desired. Based on the above requirements we have successfully developed a multi channel rectangular rf vacuum window employing high temperature vacuum brazing technique. During the development process we could optimize the chemical processing parameters, brazing process parameters, jigs and fixtures for high temperature brazing and leak testing, etc. Finally the window is tested for low power rf performance using VNA. In this paper we would present the development of the said window in detail along with its mechanical, vacuum and rf performances.

Development of multi-channel high power rectangular RF window for LHCD system employing high temperature vacuum brazing technique

Energy Technology Data Exchange (ETDEWEB)

Sharma, P K; Ambulkar, K K; Parmar, P R; Virani, C G; Thakur, A L [Institute for Plasma Research, Bhat, Gandhinagar 382428 (India); Joshi, L M; Nangru, S C, E-mail: pramod@ipr.res.i [Central Electronics Engineering Research Institute, Pilani, Rajasthan 333 031 (India)

2010-02-01

A 3.7 GHz., 120 kW (pulsed), lower hybrid current drive (LHCD) system is employed to drive non-inductive plasma current in ADITYA tokamak. The rf power is coupled to the plasma through grill antenna and is placed in vacuum environment. A vacuum break between the pressurized transmission line and the grill antenna is achieved with the help of a multi (eight) channel rectangular RF vacuum window. The phasing between adjacent channels of 8-channel window (arranged in two rows) is important for launching lower hybrid waves and each channel should have independent vacuum window so that phase information is retained. The geometrical parameter of the grill antenna, like periodicity (9mm), channel dimensions (cross sectional dimension of 76mm x 7mm), etc. is to be maintained. These design constraint demanded a development of a multi channel rectangular RF vacuum window. To handle rf losses and thermal effects, high temperature vacuum brazing techniques is desired. Based on the above requirements we have successfully developed a multi channel rectangular rf vacuum window employing high temperature vacuum brazing technique. During the development process we could optimize the chemical processing parameters, brazing process parameters, jigs and fixtures for high temperature brazing and leak testing, etc. Finally the window is tested for low power rf performance using VNA. In this paper we would present the development of the said window in detail along with its mechanical, vacuum and rf performances.

Determination of lithium in sodium by vacuum distillation-graphite furnace atomic absorption spectroscopy

International Nuclear Information System (INIS)

Xie Chun; Sun Shiping; Jia Yunteng; Wen Ximeng

1996-12-01

When sodium is used as a coolant in China Experimental Fast Reactor, the lithium content in sodium has an effect on the nuclear property of reactor. A method has been developed to determine the trace lithium in sodium metal at the level of less than ten parts per million. About 0.4 g sodium is placed into a high-purity tantalum crucible, then it is placed in a stainless-steel still to distill at 360 degree C under vacuum (0.01 Pa). After the sodium has been removed, the residue is dissolved by nitric acid (1:2) and analyzed with Graphite Furnace Atomic Absorption Spectroscopy at 671.0 nm wavelength. The distillation conditions, working conditions of the instrument and interferences from matrix sodium, acid and concomitant elements have been studied. Standard addition experiments are carried out with lithium chloride and lithium nitrate. The percentage recoveries are 96.8% and 97.4% respectively. The relative standard deviation is less than +- 5%. The method has been used to determine lithium content in high pure sodium and industrial grade sodium. (11 refs., 5 figs., 5 tabs.)

A comparison of the toluene distillation and vacuum/heat methods for extracting soil water for stable isotopic analysis

Science.gov (United States)

Ingraham, Neil L.; Shadel, Craig

1992-12-01

Hanford Loam, from Richland, Washington, was used as a test soil to determine the precision, accuracy and nature of two methods to extract soil water for stable isotopic analysis: azeotropic distillation using toluene, and simple heating under vacuum. The soil was oven dried, rehydrated with water of known stable isotopic compositions, and the introduced water was then extracted. Compared with the introduced water, initial aliquots of evolved water taken during a toluene extraction were as much as 30 ‰ more depleted in D and 2.7 ‰ more depleted in 18O, whereas final aliquots were as much as 40 ‰ more enriched in D and 14.3 ‰ more enriched in 18O. Initial aliquots collected during the vacuum/heat extraction were as much as 64 ‰ more depleted in D and 8.4 ‰ more depleted in 18O than was the introduced water, whereas the final aliquots were as much as 139 ‰ more enriched in D, and 20.8 ‰ more enriched in 18O. Neither method appears quantitative; however, the difference in stable isotopic composition between the first and last aliquots of water extracted by the toluene method is less than that from the vacuum/heat method. This is attributed to the smaller fractionation factors involved with the higher average temperatures of distillation of the toluene. The average stable isotopic compositions of the extracted water varied from that of the introduced water by up to 1.4 ‰ in δD and 4.2 ‰ in δ18O with the toluene method, and by 11.0 ‰ in δD and 1.8 ‰ in δ18O for the vacuum/heat method. The lack of accuracy of the extraction methods is thought to be due to isotopic fractionation associated with water being weakly bound (not released below 110°C) in the soil. The isotopic effect of this heat-labile water is larger at low water contents (3.6 and 5.2% water by weight) as the water bound in the soil is a commensurately larger fraction of the total. With larger soilwater contents the small volume of water bound with an associated fractionation is

Development of High Throughput Salt Separation System with Integrated Liquid Salt Separation - Salt Distillation Assembly

Energy Technology Data Exchange (ETDEWEB)

Kwon, Sangwoon; Park, K. M.; Kim, J. G.; Jeong, J. H.; Lee, S. J.; Park, S. B.; Kim, S. S.

2013-01-15

The capacity of a salt distiller should be sufficiently large to reach the throughput of uranium electro-refining process. In this study, an assembly composing a liquid separation sieve and a distillation crucible was developed for the sequential operation of a liquid salt separation and a vacuum distillation in the same tower. The feasibility of the sequential salt separation was examined by the rotation test of the sieve-crucible assembly and sequential operation of a liquid salt separation and a vacuum distillation. The adhered salt in the uranium deposits was removed successfully. The salt content in the deposits was below 0.1 wt% after the sequential operation of the liquid salt separation - salt distillation. From the results of this study, it could be concluded that efficient salt separation can be realized by the sequential operation of liquid salt separation and vacuum distillation in one distillation tower since the operation procedures are simplified and no extra operation of cooling and reheating is necessary.

Vacuumed gap membrane distillation (vagmed) module, multi-stage vagmed systems, and vagmed processes

KAUST Repository

Ghaffour, Noreddine

2016-06-30

Vacuumed gap membrane distillation (VAGMED) modules, and multi-stage VAGMED systems and processes using the modules are provided. In an embodiment, the membrane distillation modules (10) can comprise: a) a condenser (12) including a condensation surface (15); b) a first passageway (13) having an inlet for receiving a first feed stream (14) and an outlet through which the first stream can pass out of the first passageway, the first passageway configured to bring the first feed stream into thermal communication with the condensation surface; c) an evaporator (17) including a permeable evaporation surface allowing condensable gas to pass there through; d) a second passageway (18) having an inlet for receiving a second feed stream (19) and an outlet through which the second feed stream can pass out of the second passageway, the second passageway configured to bring the second feed stream into communication with the permeable evaporation surface; and e) an enclosure (24) providing a vacuum compartment within which the condenser, the evaporator and the first and second passageways of the module are contained.

Vacuumed gap membrane distillation (vagmed) module, multi-stage vagmed systems, and vagmed processes

KAUST Repository

Ghaffour, NorEddine; Alsaadi, Ahmad Salem; Francis, Lijo

2016-01-01

Vacuumed gap membrane distillation (VAGMED) modules, and multi-stage VAGMED systems and processes using the modules are provided. In an embodiment, the membrane distillation modules (10) can comprise: a) a condenser (12) including a condensation surface (15); b) a first passageway (13) having an inlet for receiving a first feed stream (14) and an outlet through which the first stream can pass out of the first passageway, the first passageway configured to bring the first feed stream into thermal communication with the condensation surface; c) an evaporator (17) including a permeable evaporation surface allowing condensable gas to pass there through; d) a second passageway (18) having an inlet for receiving a second feed stream (19) and an outlet through which the second feed stream can pass out of the second passageway, the second passageway configured to bring the second feed stream into communication with the permeable evaporation surface; and e) an enclosure (24) providing a vacuum compartment within which the condenser, the evaporator and the first and second passageways of the module are contained.

Low temperature distillation of powdered materials

Energy Technology Data Exchange (ETDEWEB)

1929-04-11

In the low temperature distillation of powdered material such as coal, brown coal, or oil shale, dust carried by the gases and vapors is precipitated by supplying liquid hydrocarbons to the effluent gases, for example, to a dust remover through which the distillates pass. The material is supplied through a hopper and moved through a retort by a worm feed, and is discharged into a sump. Scavenging gases such as steam may be introduced through a pipe. Two conveyor worms moving in opposite directions are provided in an outlet conduit which may be surrounded by a cooling jacket. Heavy hydrocarbons condense on the walls of the conduit and on the conveyor worms and serve as dust catchers for the distillates, the lighted volatiles escaping through an outlet. The high boiling point oils flow back to and are cracked in the retort. Oils such as tar oils may be sprayed into the conduit or directly adjacent the entry of the material from feeding hopper.

Advanced purification of petroleum refinery wastewater by catalytic vacuum distillation.

Science.gov (United States)

Yan, Long; Ma, Hongzhu; Wang, Bo; Mao, Wei; Chen, Yashao

2010-06-15

In our work, a new process, catalytic vacuum distillation (CVD) was utilized for purification of petroleum refinery wastewater that was characteristic of high chemical oxygen demand (COD) and salinity. Moreover, various common promoters, like FeCl(3), kaolin, H(2)SO(4) and NaOH were investigated to improve the purification efficiency of CVD. Here, the purification efficiency was estimated by COD testing, electrolytic conductivity, UV-vis spectrum, gas chromatography-mass spectrometry (GC-MS) and pH value. The results showed that NaOH promoted CVD displayed higher efficiency in purification of refinery wastewater than other systems, where the pellucid effluents with low salinity and high COD removal efficiency (99%) were obtained after treatment, and the corresponding pH values of effluents varied from 7 to 9. Furthermore, environment estimation was also tested and the results showed that the effluent had no influence on plant growth. Thus, based on satisfied removal efficiency of COD and salinity achieved simultaneously, NaOH promoted CVD process is an effective approach to purify petroleum refinery wastewater. Copyright 2010 Elsevier B.V. All rights reserved.

Fundamental Study on a Distillation Separation of a LiCl-KCl Eutectic Salt from Rare Earth Precipitates

International Nuclear Information System (INIS)

Yang, Hee Chul; Eun, Hee Chul; Kim, In Tae

2010-01-01

The distillation rate on LiCl-KCl eutectic salt under different vacuums from 0.5-50 mmHg was first investigated by using both a non-isothermal and a isothermal thermogravimetric (TG) analysis. Based on the non-isothermal TG data, distillation rate equations as a function of the temperature could be derived. Calculated flux by these model flux equations was in agreement with the distillation rate obtained from isothermal TG analysis. A distillation rate of 10 -4 -10 -5 mole cm -2 sec -1 is obtainable at temperatures less than 1300 K and vacuums of 0.5-50 mmHg. About a 99% salt distillation efficiency was obtained after an hour at a temperature above 1150 K under 50 mmHg in a small scale distillation test system. An increase in the vaporizing surface area is relatively effective for removing residual salt in the remaining particles, when compared to that for the vaporizing time. Over 99.95% of total distillation efficiency was obtained for a 1-h distillation operation by increasing the inner surface area from 4.52 cm 2 to 12.56 cm 2 .

Low temperature distillation of coal, shale, etc

Energy Technology Data Exchange (ETDEWEB)

1938-08-12

A process is disclosed for the low temperature distillation of solid carbonaceous fuels, such as coal, lignite, shale or the like, which comprises feeding or supplying the comminuted fuel in the form of a layer of shallow depth to drying and distilling zones in succession moving the fuel forward through the zones, submitting it to progressively increasing nonuniform heating therein by combustion gases supplied to the distillation zone and traveling thence to the drying zone, the gases heating the distillation zone indirectly and the drying zone both indirectly and then directly such that the fuel retains its solid discrete form during substantially the whole of its travel through the drying and distillation zones, subjecting the fuel for a portion of its travel to a zigzag ploughing and propelling movement on a heated sole, and increasing the heating so as to cause fusion of the fuel immediately prior to its discharge from the distillation zone.

Surface Effects and Challenges for Application of Piezoelectric Langasite Substrates in Surface Acoustic Wave Devices Caused by High Temperature Annealing under High Vacuum.

Science.gov (United States)

Seifert, Marietta; Rane, Gayatri K; Kirbus, Benjamin; Menzel, Siegfried B; Gemming, Thomas

2015-12-19

Substrate materials that are high-temperature stable are essential for sensor devices which are applied at high temperatures. Although langasite is suggested as such a material, severe O and Ga diffusion into an O-affine deposited film was observed during annealing at high temperatures under vacuum conditions, leading to a damage of the metallization as well as a change of the properties of the substrate and finally to a failure of the device. Therefore, annealing of bare LGS (La 3 Ga 5 SiO 14 ) substrates at 800 ∘ C under high vacuum conditions is performed to analyze whether this pretreatment improves the suitability and stability of this material for high temperature applications in vacuum. To reveal the influence of the pretreatment on the subsequently deposited metallization, RuAl thin films are used as they are known to oxidize on LGS at high temperatures. A local study of the pretreated and metallized substrates using transmission electron microscopy reveals strong modification of the substrate surface. Micro cracks are visible. The composition of the substrate is strongly altered at those regions. Severe challenges for the application of LGS substrates under high-temperature vacuum conditions arise from these substrate damages, revealing that the pretreatment does not improve the applicability.

Surface Effects and Challenges for Application of Piezoelectric Langasite Substrates in Surface Acoustic Wave Devices Caused by High Temperature Annealing under High Vacuum

Directory of Open Access Journals (Sweden)

Marietta Seifert

2015-12-01

Full Text Available Substrate materials that are high-temperature stable are essential for sensor devices which are applied at high temperatures. Although langasite is suggested as such a material, severe O and Ga diffusion into an O-affine deposited film was observed during annealing at high temperatures under vacuum conditions, leading to a damage of the metallization as well as a change of the properties of the substrate and finally to a failure of the device. Therefore, annealing of bare LGS (La 3 Ga 5 SiO 14 substrates at 800 ∘ C under high vacuum conditions is performed to analyze whether this pretreatment improves the suitability and stability of this material for high temperature applications in vacuum. To reveal the influence of the pretreatment on the subsequently deposited metallization, RuAl thin films are used as they are known to oxidize on LGS at high temperatures. A local study of the pretreated and metallized substrates using transmission electron microscopy reveals strong modification of the substrate surface. Micro cracks are visible. The composition of the substrate is strongly altered at those regions. Severe challenges for the application of LGS substrates under high-temperature vacuum conditions arise from these substrate damages, revealing that the pretreatment does not improve the applicability.

Vacuum distillation/vapor filtration water recovery, phases 1 and 2

Science.gov (United States)

Honegger, R. J.; Remus, G. A.; Krug, E. K.

1973-01-01

The research is reported on the development of an evaporator for vacuum distillation/vapor filtration VD/VF water reclamation system for use on manned space flights. The design, fabrication, and tests of a six-man evaporator are described. It is concluded that: (1) A condenser with an internal rotating impeller and coolant surfaces directly opposite the condensing surfaces is an effective condenser. (2) The VD/VF evaporator, catalyst unit and condenser function satisfactorily based on thermal, mechanical and recovery performance during a 145-hour evaluation test. (3) The quality of recovered water, as measured by analyses for total organic carbon, pH, conductivity, turbidity, and viable bacteria density was within established limits for potability.

On the catalysis of the electroweak vacuum decay by black holes at high temperature

Science.gov (United States)

Canko, D.; Gialamas, I.; Jelic-Cizmek, G.; Riotto, A.; Tetradis, N.

2018-04-01

We study the effect of primordial black holes on the classical rate of nucleation of AdS regions within the standard electroweak vacuum at high temperature. We base our analysis on the assumption that, at temperatures much higher than the Hawking temperature, the main effect of the black hole is to distort the Higgs configuration dominating the transition to the new vacuum. We estimate the barrier for the transition by the ADM mass of this configuration, computed through the temperature-corrected Higgs potential. We find that the exponential suppression of the nucleation rate can be reduced significantly, or even eliminated completely, in the black-hole background if the Standard Model Higgs is coupled to gravity through the renormalizable term ξ R h^2.

Characteristics analysis of salt vacuum distillation equipment

International Nuclear Information System (INIS)

Im, Hun Suk; Oh, Seung Chul; Hong, Sun Seok; Hur, Jin Mok; Lee, Hyo Jik

2016-01-01

A new technique for pyroprocessing was designed by adding an oxide reduction process to the previous one. It is regarded as a promising process to treat and recycle oxide spent fuels owing to its enhanced nuclear proliferation resistance and the simplified process equipment and the low process costing. Spent oxide fuel is reduced into a metal by an electrochemical method while using a high-temperature molten salt as the reaction medium. After being subjected to electrorefining and electrowinning processes, the reduced metal fuel can be used in sodium-cooled fast reactors. The salt vacuum distillation process termed cathode processing follows the oxide reduction stage and has been developed to remove the residual salt, allowing for clear fuel metal to be supplied to the next step, which is electrorefining. KAERI has manufactured this apparatus in several sizes and has been able to achieve a fuel recovery rate of 95%. However it is very difficult to scale up the equipment. Because all transport phenomena, including heat transfer and fluid flow, depend on the size and structure of the apparatus used. The ideal method for overcoming this issue is nondimensionalization, which allows one to determine the characteristic properties of a system. A comparison of the dimensionless variables corresponding to the M-type and P-type apparatuses performed on the basis of phase-transition phenomena as well as the results of the above-mentioned analysis elucidated the differences between the two apparatuses. It also means that the structure of the nozzle throat can be the one of the several causes for the recovery performance. First, the standard model (i.e., the M-type apparatus) was analyzed using dimensionless parameters. The characteristics of this apparatus were the following: 1) the diameter of the outlet of the nozzle throat was twice that of the inlet, 2) the ratio of the length to the diameter (L/D) was 8, and 3) the modified heat-transfer factor was 220-270. It indicates

Characteristics analysis of salt vacuum distillation equipment

Energy Technology Data Exchange (ETDEWEB)

Im, Hun Suk; Oh, Seung Chul; Hong, Sun Seok; Hur, Jin Mok; Lee, Hyo Jik [KAERI, Daejeon (Korea, Republic of)

2016-05-15

A new technique for pyroprocessing was designed by adding an oxide reduction process to the previous one. It is regarded as a promising process to treat and recycle oxide spent fuels owing to its enhanced nuclear proliferation resistance and the simplified process equipment and the low process costing. Spent oxide fuel is reduced into a metal by an electrochemical method while using a high-temperature molten salt as the reaction medium. After being subjected to electrorefining and electrowinning processes, the reduced metal fuel can be used in sodium-cooled fast reactors. The salt vacuum distillation process termed cathode processing follows the oxide reduction stage and has been developed to remove the residual salt, allowing for clear fuel metal to be supplied to the next step, which is electrorefining. KAERI has manufactured this apparatus in several sizes and has been able to achieve a fuel recovery rate of 95%. However it is very difficult to scale up the equipment. Because all transport phenomena, including heat transfer and fluid flow, depend on the size and structure of the apparatus used. The ideal method for overcoming this issue is nondimensionalization, which allows one to determine the characteristic properties of a system. A comparison of the dimensionless variables corresponding to the M-type and P-type apparatuses performed on the basis of phase-transition phenomena as well as the results of the above-mentioned analysis elucidated the differences between the two apparatuses. It also means that the structure of the nozzle throat can be the one of the several causes for the recovery performance. First, the standard model (i.e., the M-type apparatus) was analyzed using dimensionless parameters. The characteristics of this apparatus were the following: 1) the diameter of the outlet of the nozzle throat was twice that of the inlet, 2) the ratio of the length to the diameter (L/D) was 8, and 3) the modified heat-transfer factor was 220-270. It indicates

HIGH-TEMPERATURE VACUUM CEMENTATION – THE RESERVE TO REDUCE THE ENERGY INTENSITY OF MANUFACTURE AND IMPROVE THE QUALITY OF TRANSMISSIONS GEARWHEELS OF HIGH-ENERGY MACHINES

OpenAIRE

A. A. Shipko; S. P. Rudenko; A. L. Valko; A. N. Chichin

2016-01-01

Results of research of influence of high-temperature vacuum chemical heat treatment on the amount of grain structural steels are presented. The efficiency of hereditary fine-grained steel for high temperature vacuum carburizing are shown.

Design and test of a vacuum distillation method for determining carbon in sodium

International Nuclear Information System (INIS)

Irmisch, R.; Rettig, D.; Woelke, K.

1976-08-01

A method is described for determining total and carbonate carbon in sodium samples until 10 g. Sodium is removed by vacuum distillation at 300 0 C and the carbon in the residue is converted to carbon dioxide by combustion in a stream of air or thermic splitting in a stream of cover gas at 1000 0 C. The carbon dioxide is measured manometrically. It is therefore not necessary to carry out calibration. Distillation and combustion rig are combined with inertgas filled transfer box. Therefore the sodium sample does not get into touch with air. Test of this method was carried out with Na 2 CO 3 and WC. Carbon recoveries were for Na 2 CO 3 between 103 and 107% and for WC between 92 and 96%. The blank value found being 9 μg C and sensitivity 3 μg C. (author)

Process and apparatus to analyze high-boiling products by distillation

Energy Technology Data Exchange (ETDEWEB)

Goupil, J.; Mouton, M.; Fischer, W.

1982-05-19

In the described process to analyze high-boiling petroleum products by distillation, contents of these products with atmospheric boiling points above 500/sup 0/C can be isolated as distillates. For this purpose the continuous shortway distillation process is employed and at least a part of the components of the apparatus which serve to introduce the raw product are heated seperately and held at different temperatures. The raw product is distributed on the combustion surface of the shortway distiller by a roller wiping system.

Performance test of solar energy distillation system; Taiyonetsu riyo kaisui tansuika system no zosui seino shiken

Energy Technology Data Exchange (ETDEWEB)

Kawahara, T; Toyoshima, Y [Keio University, Tokyo (Japan); Narasaki, Y; Kamiya, I [Ebara Corp., Tokyo (Japan); Sato, H [Keio University, Tokyo (Japan). Faculty of Science and Technology

1997-11-25

In order to develop a seawater desalination equipment utilizing solar heat, a performance test was performed on a three-stage solar heat vacuum distiller. The equipment can evaporate and condense water at low temperatures by reducing the pressure in a distilling section. Solar heat is collected by a heat collecting plate, by which water as the working fluid is evaporated and moved to a heat conducting section in an evaporation pipe in a state of steam. The steam is condensed in a low-temperature heat conducting pipe, the heat is released outside the heat conducting pipe, and seawater is evaporated under low pressure condition. The working fluid is circulated for repetitive use. Solar cells are used as a motive power source for a vacuum pump, hence the system is self-sustainable even if installed in a desert area and the like places. The construction is simple, highly durable, and easy in maintenance. The system has high water producing performance, uses no harmful substances whatsoever such as fluorocarbons, and is a friendly system to the global environment. Because of evaporation at low temperatures, heat loss to the surroundings and sensible heat due to temperature rise are small, and the system response is quick. The solar heat can be utilized more effectively as multiple effects. When a heat collecting plate of 7.76 m {sup 2} was used, maximum yield of 105.45 kg/day was obtained. The system`s distillation efficiency is higher than other types of solar heat utilizing distillers. 7 refs., 5 figs.

HIGH-TEMPERATURE VACUUM CEMENTATION – THE RESERVE TO REDUCE THE ENERGY INTENSITY OF MANUFACTURE AND IMPROVE THE QUALITY OF TRANSMISSIONS GEARWHEELS OF HIGH-ENERGY MACHINES

Directory of Open Access Journals (Sweden)

A. A. Shipko

2016-01-01

Full Text Available Results of research of influence of high-temperature vacuum chemical heat treatment on the amount of grain structural steels are presented. The efficiency of hereditary fine-grained steel for high temperature vacuum carburizing are shown.

Aroma Stripping under various Forms of Membrane Distillation Processes: Experiments and modeling

DEFF Research Database (Denmark)

Jonsson, Gunnar Eigil

Concentration of fruit juices by membrane distillation is an interesting process as it can be done at low temperature giving a gentle concentration process with little deterioration of the juices. Since the juices contains many different aroma compounds with a wide range of chemical properties...... such as volatility, activity coefficient and vapor pressure, it is important to know how these aroma compounds will eventually pass through the membrane. Experiments have been made on an aroma model solution and on black currant juice in a lab scale membrane distillation set up which can be operated in various types...... of MD configurations: Vacuum Membrane Distillation , Sweeping Gas Membrane Distillation , Direct Contact Membrane Distillation and Osmotic Membrane Distillation. The influence of feed temperature and feed flow rate on the permeate flux and concentration factor for different types of aroma compounds have...

Distillation of oil-bearing minerals

Energy Technology Data Exchange (ETDEWEB)

1952-12-03

A process of distilling oil-bearing minerals of the type of oil shale which disintegrate during distillation consists of subjecting the subdivided minerals to a distillation temperature in the form of a highly turbulent dense mass fluidized by an upwardly flowing gasiform medium in a distillation zone and supplying the heat required for the distillation by burning solid distillation residue with a combustion-supporting gas in the form of a fluidized mass of solids in a separate combustion zone at a combustion temperature and returning solid combustion residue substantially at the combustion temperature to the distillation zone. Combustion temperature is positively maintained at a figure not exceeding 1,200/sup 0/F and at a figure which is not substantially more than 50/sup 0/F higher than the distillation temperature.

Measuring the internal temperature of a levitated nanoparticle in high vacuum

Science.gov (United States)

Hebestreit, Erik; Reimann, René; Frimmer, Martin; Novotny, Lukas

2018-04-01

The interaction of an object with its surrounding bath can lead to a coupling between the object's internal degrees of freedom and its center-of-mass motion. This coupling is especially important for nanomechanical oscillators, which are among the most promising systems for preparing macroscopic objects in quantum mechanical states. Here we exploit this coupling to derive the internal temperature of a levitated nanoparticle from measurements of its center-of-mass dynamics. For a laser-trapped silica particle in high vacuum, we find an internal temperature of 1000 (60 )K . The measurement and control of the internal temperature of nanomechanical oscillators is of fundamental importance because black-body emission sets limits to the coherence of macroscopic quantum states.

Process and apparatus to distil petroleum. Verfahren und Vorrichtung zur Erdoel-Destillation

Energy Technology Data Exchange (ETDEWEB)

Buchenau, R.; Fauser, F.; Fischer, W.

1982-12-23

In a process to distil petroleum the raw petroleum is distilled in the first instance at atmospheric pressure to separate the low-boiling components and subsequently under vacuum to separate the remaining components. The vacuum distillation is carried out as a flash distillation using a shortway distiller.

Fretting wear of Inconel 625 at high temperature and in high vacuum

International Nuclear Information System (INIS)

Iwabuchi, A.

1985-01-01

The purpose of this work was to investigate the fretting properties of Inconel 625 at high temperature and in high vacuum. Experiments were carried out under constant conditions with a normal load of 14 N and a peak-to-peak slip amplitude of 110 μm and through 6x10 4 cycles. Several environmental conditions were used. Pressure was varied between 10 -3 and 10 5 Pa at temperatures of 20 and 500 0 C. Temperatures up to 500 0 C were also used at pressures of 10 -3 and 10 5 Pa. At 10 -3 Pa and 500 0 C wear loss was negligible but wear scars showed severe damage consisting of deep cracks and accretion of transferred debris. The coefficient of friction then maintained a high value of 1.7 throughout the fretting test. The critical pressure below which oxidation rate becomes reduced is 10 Pa, a value independent of temperature. At pressures below this critical value the coefficient of friction increases steeply and the fretting mechanism changes from one of oxidative wear to one of adhesive wear. A compacted so-called 'glaze' oxide was formed at temperatures above 300 0 C in air (10 5 Pa) and at pressures above 10 3 Pa at 500 0 C. A comparison of results for Inconel 625 with those for S45C and SUS304 steels and Inconel 600 is given. (orig.)

Purification of specific structured lipids by distillation: Effects on acyl migration

DEFF Research Database (Denmark)

Xu, Xuebing; Skands, A.; Adler-Nissen, Jens

2001-01-01

The cause and effects of acyl migration during the purification of specific structured lipids by distillation were studied in a conventional batch deodorizer with stripping steam. The mixture of specific structured lipids produced by lipase-catalyzed acidolysis between rapeseed oil and capric acid...... influenced the rate of acyl migration, and their combinations made the effect more severe. However, diacylglycerols were found to be the main reason for acyl migration. In the distillation of the specific structured lipid product mixture, distillation temperature and time were the main factors to determine...... the degree of acyl migration and the extent of separation of free fatty acids. The results indicate that more efficient separation technology should be used to improve the quality of the purified structured lipids. in order to reduce the distillation temperature, vacuum should be made as low as possible...

Low temperature distillation

Energy Technology Data Exchange (ETDEWEB)

1937-07-21

To distil mineral or organic material, the material is heated by means of a hot gas entering into contact with and traversing the material in a horizontal direction. The vertical retort is charged with material from the hopper and hot gases from the furnace after traversing the boiler enter the preheating zone, pass through the slots and charge therein and are educted through connection by the blower. The charge passes downwardly to the distillation zone wherein hot gases from the heater are passed via pipe and slots through the chambers and to the pipe controlled by the dampers. These gases are recycled by the fan through the heater and chamber, that portion of the gases corresponding to the amount of vapours evolved from the distillation being evacuated via the pipe to the condensing plant not shown. Steam and/or a limited quantity of water may be admitted to the distillation zone.

Distillation of oil-bearing minerals

Energy Technology Data Exchange (ETDEWEB)

1952-05-21

In the process of distilling oil-bearing minerals such as oil shale which disintegrates during distillation, wherein the subdivided minerals are subjected to a distillation temperature in the form of a highly turbulent dense mass fluidized by an upwardly flowing gasiform medium in a distillation zone and the heat required by the distillation is supplied by burning solid distillation residue with a combustion-supporting gas in the form of a fluidized mass of solids in a separate combustion zone at a temperature substantially higher than the distillation temperature and returning solid combustion residue substantially at the higher temperature to the distillation zone. The steps of starting up the process which consists of maintaining in the distillation and combustion zones dense turbulent fluidized beds of non-disintegrating solids, circulating the non-disintegrating solids between said beds, heating the circulating solids by an auxiliary heat supply until the bed in the distillation zone has reached at least the distillation temperature, thereafter charging fresh oil-bearing minerals to the bed in the distillation zone, continuing the circulation, withdrawing solids which have passed through the combustion zone at a rate adequate to maintain a solids balance, supplying the combustion-supporting gas to the combustion zone to cause the combustion of the residue, and discontinuing the auxilary heating when sufficient heat for the distillation is being generated in the combustion zone.

The Effect of Non-condensable Gases Removal on Air Gap Membrane Distillation: Experimental and Simulation Studies

KAUST Repository

Alsaadi, Ahmad S.

2014-04-01

In the kingdom of Saudi Arabia (KSA), the current seawater desalination technologies are completely relying on burning unsustainable crude oil as their main energy driver. Saudi authorities have realized that the KSA is not going to be protected from the future global energy crisis and have started to set up a plan to diversify its energy resources. Membrane Distillation (MD) has emerged as an attractive alternative desalination process. It combines advantages from both thermal and membrane-based technologies and holds the potential of being a cost-effective separation process that can utilize low-grade waste heat or renewable energy. MD has four different configurations; among them is Air Gap Membrane Distillation (AGMD) which is the second most commonly tested and the most commercially available pilot-plant design. AGMD has a stagnant thin layer of air between the membrane and the condensation surface. This layer introduces a mass transfer resistance that makes the process require a large membrane surface area if a large quantity of fresh water is desired. This dissertation reports on experimental and theoretical work conducted to enhance the AGMD flux by removing non-condensable gases from the module and replacing it with either vacuum, liquid water or porous materials. At first, a mathematical model for AGMD was developed and validated experimentally to create a baseline for improvements that could be achieved after the removal of non-condensable gases. The mathematical model was then modified to simulate the process under vacuum where it showed a flux enhancement that reached 286%. The Water Gap Membrane Distillation (WGMD) configuration improved the flux by almost the same percentage. Since enhancing the flux is expected to increase temperature polarization effects, a theoretical study was conducted on the effect of temperature polarization in a Vacuum Membrane Distillation (VMD) configuration. The study showed that the effect of temperature polarization at

PLS models for determination of SARA analysis of Colombian vacuum residues and molecular distillation fractions using MIR-ATR

Directory of Open Access Journals (Sweden)

Jorge A. Orrego-Ruiz

2014-06-01

Full Text Available In this work, prediction models of Saturates, Aromatics, Resins and Asphaltenes fractions (SARA from thirty-seven vacuum residues of representative Colombian crudes and eighteen fractions of molecular distillation process were obtained. Mid-Infrared (MIR Attenuated Total Reflection (ATR spectroscopy in combination with partial least squares (PLS regression analysis was used to estimate accurately SARA analysis in these kind of samples. Calibration coefficients of prediction models were for saturates, aromatics, resins and asphaltenes fractions, 0.99, 0.96, 0.97 and 0.99, respectively. This methodology permits to control the molecular distillation process since small differences in chemical composition can be detected. Total time elapsed to give the SARA analysis per sample is 10 minutes.

High-temperature distillation and consolidation of U–Zr cathode product from molten salt electrorefining of simulated metallic fuel

International Nuclear Information System (INIS)

Iizuka, Masatoshi; Akagi, Masaaki; Koyama, Tadafumi

2014-01-01

High-temperature distillation experiments were performed using U–Zr cathode products of various compositions to obtain knowledge on suitable operation conditions and equipment design such as the container material. The LiCl–KCl–UCl 3 electrolyte adhering to the U–Zr cathode products was almost completely vaporized at 1273–1573 K, under pressure of 10–300 Pa. Massive ingots were obtained from the remaining cathode products by heating them at 1573–1673 K. Three different phases were identified in a distillation product of a higher Zr content. A U-rich bulk (3.9 wt% Zr) and a deposit of a relatively low Zr content (17.2 wt% Zr) were considered to be formed during the cooling process of the distillation product. Another Zr-rich deposit (64.7 wt% Zr), which might cause the inhomogeneity of product ingots, was expected to result from Zr-rich spots that originally existed in the cathode product. The Cl content in the cathode product was decreased by distillation to less than 1/200 of that after electrorefining, while it was markedly larger at a higher Zr concentration. To limit the amount of Zr-rich deposit and the Cl content, the amount of Zr in the distillation product should be controlled to a sufficiently low level by optimization of the operating procedures and conditions in the electrorefining and distillation steps. The zirconia coating material developed in this study showed superior performance in inhibiting reaction between the melted U–Zr alloy melt and the graphite crucible and also in the easy release of the U–Zr ingot from the crucible

On the evolution of morphology of zirconium sponge during reduction and distillation

International Nuclear Information System (INIS)

Kapoor, K.; Padmaprabu, C.; Nandi, D.

2008-01-01

High purity zirconium metal is produced by magnesio-thermic reduction of zirconium tetrachloride followed by vacuum distillation. The reduction process is carried out in a batch giving metal sponge and magnesium chloride in the reduced mass. The sponge is purified to using by vacuum distillation. The morphology of the sponge formed during the reduction and its influence on further processing has significant importance. In the present study, a detailed investigation involving evolution of the morphology of sponge particles and its implication during the vacuum distillation was carried out. The study of the microstructure was done using scanning electron microscopy and X-ray diffraction. It is observed that the nascent sponge formed is highly unstable which transforms to a needle-like morphology almost immediately, which further transforms to rounded and finally to a bulk shape. Faceting of the surface and needle-shape formation were observed in these particles, this is probably due to anisotropy in the surface energy. The morphology of the sponge formed during the reduction influences the distillation process. The fine needle-like shape sponge morphology leads to particle ejection, which is explained to be due to curvature effect. This is responsible for the formation of unwanted mass during distillation. XRD line broadening analysis indicates that the individual sponge particles are free from structural defects (dislocation) and are nearly single crystalline in nature

Simulation and optimization of stable isotope 18O separation by water vacuum distillation

International Nuclear Information System (INIS)

Chen Yuyan; Qin Chuanjiang; Xiao Bin; Xu Jing'an

2012-01-01

In the research, a stable isotope 18 O separation column was set up by water vacuum distillation with 20 m packing height and 0.1 m diameter of the column. The self-developed special packing named PAC- 18 O was packed inside the column. Firstly, a model was created by using the Aspen Plus software, and then the simulation results were validated by test results. Secondly, a group of simulation results were created by Aspen Plus, and the optimal operation conditions were gotten by using the artificial neural network (ANN) and Statistica software. Considering comprehensive factors drawn from column pressure and from withdrawing velocity, conclusions were reached on the study of the impact on the abundance of the isotope 18 O. The final results show that the abundance of the isotope 18 O increases as column pressure dropping and withdrawing velocity decreasing. Besides, the optimal column pressure and the incidence formula between the abundance of the isotope 18 O and withdrawing velocity were gotten. The conclusion is that the method of simulation and optimization can be applied to 18 O industrial design and will be popular in traditional distillation process to realize optimization design. (authors)

[Prediction of the side-cut product yield of atmospheric/vacuum distillation unit by NIR crude oil rapid assay].

Science.gov (United States)

Wang, Yan-Bin; Hu, Yu-Zhong; Li, Wen-Le; Zhang, Wei-Song; Zhou, Feng; Luo, Zhi

2014-10-01

In the present paper, based on the fast evaluation technique of near infrared, a method to predict the yield of atmos- pheric and vacuum line was developed, combined with H/CAMS software. Firstly, the near-infrared (NIR) spectroscopy method for rapidly determining the true boiling point of crude oil was developed. With commercially available crude oil spectroscopy da- tabase and experiments test from Guangxi Petrochemical Company, calibration model was established and a topological method was used as the calibration. The model can be employed to predict the true boiling point of crude oil. Secondly, the true boiling point based on NIR rapid assay was converted to the side-cut product yield of atmospheric/vacuum distillation unit by H/CAMS software. The predicted yield and the actual yield of distillation product for naphtha, diesel, wax and residual oil were compared in a 7-month period. The result showed that the NIR rapid crude assay can predict the side-cut product yield accurately. The near infrared analytic method for predicting yield has the advantages of fast analysis, reliable results, and being easy to online operate, and it can provide elementary data for refinery planning optimization and crude oil blending.

Process for carbonizing, distilling, and vaporizing of coal from any source

Energy Technology Data Exchange (ETDEWEB)

Limberg, T

1916-10-15

A process is described for carbonizing, distilling, and vaporizing coal from any source, especially of humid and bituminous coals as well as bituminous shale and peat for recovering an especially light tar with a large aliphatic hydrocarbon content that is characterized in that it is exposed to internal heating under vacuum at a temperature below dull-red heat. The distillation products of the material are washed away by the heating gases for the whole length of the furnace and are removed immediately and carried into separate condensers.

Characterization of selective solar absorber under high vacuum.

Science.gov (United States)

Russo, Roberto; Monti, Matteo; di Giamberardino, Francesco; Palmieri, Vittorio G

2018-05-14

Total absorption and emission coefficients of selective solar absorbers are measured under high vacuum conditions from room temperature up to stagnation temperature. The sample under investigation is illuminated under vacuum @1000W/m 2 and the sample temperature is recorded during heat up, equilibrium and cool down. During stagnation, the absorber temperature exceeds 300°C without concentration. Data analysis allows evaluating the solar absorptance and thermal emittance at different temperatures. These in turn are useful to predict evacuated solar panel performances at operating conditions.

Temperature control in vacuum

International Nuclear Information System (INIS)

Dearnaley, G.

1986-01-01

The patent concerns a method for controlling the temperature of silicon wafers (or samples), during ion beam treatment of the wafers, in a vacuum. The apparatus and method are described for irradiation and temperature control of the samples. The wafers are mounted on a drum which is rotated through the ion beam, and are additionally heated by infra-red lamps to achieve the desired temperature. (U.K.)

Materials for high vacuum technology, an overview

CERN Document Server

Sgobba, Stefano

2007-01-01

In modern accelerators stringent requirements are placed on materials of vacuum systems. Their physical and mechanical properties, machinability, weldability or brazeability are key parameters. Adequate strength, ductility, magnetic properties at room as well as low temperatures are important factors for vacuum systems of accelerators working at cryogenic temperatures, such as the Large Hadron Collider (LHC) under construction at CERN. In addition, baking or activation of Non-Evaporable Getters (NEG) at high temperatures impose specific choices of material grades of suitable tensile and creep properties in a large temperature range. Today, stainless steels are the dominant materials of vacuum constructions. Their metallurgy is extensively treated. The reasons for specific requirements in terms of metallurgical processes are detailed, in view of obtaining adequate purity, inclusion cleanliness, and fineness of the microstructure. In many cases these requirements are crucial to guarantee the final leak tightnes...

Advanced performance of small diaphragm vacuum pumps through the use of mechatronics

Science.gov (United States)

Lachenmann, R.; Dirscherl, J.

Oil-free diaphragm vacuum pumps have proven to be the best way in vacuum generation for the chemical laboratory and they also find increasing use as backing pumps for modern wide-range turbo molecular pumps. The majority of vacuum pumps in practical use pump only a rather small percentage of their lifetime at full gas load. A pump backing a turbo molecular pump does not have to pump a significant gas load when the high-vacuum pump is running at ultimate vacuum pressure. Also, for a vacuum distillation the vacuum pump has to operate at full speed only at the beginning to lower the pressure inside the system to a vacuum level where evaporation starts. In a rather leak-tight system the distillation process continues by evaporating from the hot liquid and condensing at the cold condenser without the need of a mechanical vacuum pump. Rotational speed controlled diaphragm pumps are now available through progress in mechatronics and offer high pumping speed capability for fast pump-down cycles and precise pressure control for distillations. At low gas load the rotational speed can be reduced, improving maintenance intervals, power consumption, noise, vibration and - surprisingly - also ultimate pressure. The different behaviour in pumping speed and ultimate pressure of rotational speed controlled diaphragm pumps in comparison to constant-speed pumps is related to the mechanical properties of the valves and gas dynamics .

Selecting a distillation scheme for purifying ditolymethane for a nuclear heat source

International Nuclear Information System (INIS)

Garanin, V.I.; Stychinskii, G.F.; Chukhlov, G.Z.; Smirnova, V.S.

1989-01-01

Ditolymethane can be used as a coolant in nuclear heat plants, although it needs ongoing purification from radiolytic products, including low-boiling and high-boiling components. Periodic distillation to remove radiolytic products represents world practice. The objective of this study was to develop a distillation system less laborious to service, simpler to automate, and costing less to operate. A continuous-flow plant can have those advantages if one could use the heat from the first loop in the plant (200-240C) to evaporate the ditolymethane and the low-boiling components instead of the more expensive electrical power, while the vapor could be condensed by cheaper air cooling to +30C instead of water cooling, while one could reduce the loss of ditolymethane with the wastes and almost eliminate the loss of low-boiling components in the vacuum pump. The laboratory tests were based on outgassed ditholymethane coolant from the first loop in the ARBUS nuclear heat plant, which had the following mass-fraction composition: ditolylmethane 82 ± 1, low-boiling components 2.3 ± 0.2, and high-boiling ones 16 ± 1%. The low-boiling components included benzene, toluene, xylene, and four unidentified compounds. The high-boiling ones included compounds containing three or more benzene rings and having a mean molecular weight 450. Continuous purification from these components and water was examined in two ways. In a one-stage system, the two types of organic component and the water are removed under a common vacuum by sequential partial condensation from the common vapor flow as the temperature is reduced. The two-stage scheme differed in that the low-boiling components and the water were removed at a lower vacuum (first stage) and the high-boiling ones at a higher vacuum (second stage)

High-temperature deformation and rupture behavior of internally-pressurized Zircaloy-4 cladding in vacuum and steam enivronments

International Nuclear Information System (INIS)

Chung, H.M.; Garde, A.M.; Kassner, T.F.

1977-01-01

The high-temperature diametral expansion and rupture behavior of Zircaloy-4 fuel-cladding tubes have been investigated in vacuum and steam environments under transient-heating conditions that are of interest in hypothetical loss-of-coolant accident situations in light-water reactors. The effects of internal pressure, heating rate, axial constraint, and localized temperature nonuniformities in the cladding on the maximum circumferential strain have been determined for burst temperatures between approximately 650 and 1350 0 C

Distillation modeling for a uranium refining process

International Nuclear Information System (INIS)

Westphal, B.R.

1996-01-01

As part of the spent fuel treatment program at Argonne National Laboratory, a vacuum distillation process is being employed for the recovery of uranium following an electrorefining process. Distillation of a salt electrolyte, containing a eutectic mixture of lithium and potassium chlorides, from uranium is achieved by a simple batch operation and is termed open-quotes cathode processingclose quotes. The incremental distillation of electrolyte salt will be modeled by an equilibrium expression and on a molecular basis since the operation is conducted under moderate vacuum conditions. As processing continues, the two models will be compared and analyzed for correlation with actual operating results. Possible factors that may contribute to aberrations from the models include impurities at the vapor-liquid boundary, distillate reflux, anomalous pressure gradients, and mass transport phenomena at the evaporating surface. Ultimately, the purpose of either process model is to enable the parametric optimization of the process

Distillation modeling for a uranium refining process

Energy Technology Data Exchange (ETDEWEB)

Westphal, B.R.

1996-03-01

As part of the spent fuel treatment program at Argonne National Laboratory, a vacuum distillation process is being employed for the recovery of uranium following an electrorefining process. Distillation of a salt electrolyte, containing a eutectic mixture of lithium and potassium chlorides, from uranium is achieved by a simple batch operation and is termed {open_quotes}cathode processing{close_quotes}. The incremental distillation of electrolyte salt will be modeled by an equilibrium expression and on a molecular basis since the operation is conducted under moderate vacuum conditions. As processing continues, the two models will be compared and analyzed for correlation with actual operating results. Possible factors that may contribute to aberrations from the models include impurities at the vapor-liquid boundary, distillate reflux, anomalous pressure gradients, and mass transport phenomena at the evaporating surface. Ultimately, the purpose of either process model is to enable the parametric optimization of the process.

Upgrading the lubricity of bio-oil via homogeneous catalytic esterification under vacuum distillation conditions

International Nuclear Information System (INIS)

Xu, Yufu; Zheng, Xiaojing; Peng, Yubin; Li, Bao; Hu, Xianguo; Yin, Yanguo

2015-01-01

In order to accelerate the application of bio-oil in the internal combustion engines, homogeneous catalytic esterification technology under vacuum distillation conditions was used to upgrade the crude bio-oil. The lubricities of the crude bio-oil (BO) and refined bio-oil with homogeneous catalytic esterification (RBO hce ) or refined bio-oil without catalyst but with distillation operation (RBO wc ) were evaluated by a high frequency reciprocating test rig according to the ASTM D 6079 standard. The basic physiochemical properties and components of the bio-oils were analyzed. The surface morphology, contents and chemical valence of active elements on the worn surfaces were investigated by scanning electron microscopy, energy dispersive spectroscopy and X-ray photoelectron spectroscopy, respectively. The results show that RBO hce has better lubricities than those of BO, but RBO wc has worse lubricities than those of BO. The tribological mechanisms of the bio-oils are attributed to the combined actions of lubricating films and factors that will break the film. Compared with BO, plenty of phenols in RBO wc results in corrosion of the substrate and destroys the integrity of the lubricating films, which is responsible for its corrosive wear. However, more esters and alkanes in RBO hce contribute to forming a complete boundary lubricating film on the rubbed surfaces which result in its excellent antifriction and antiwear properties. - Highlights: • Refined bio-oil was prepared through homogeneous catalytic esterification technology. • Properties of the bio-oils before and after refining were assessed by HFRR. • Refined bio-oil showed better lubricities than crude bio-oil. • More esters and alkanes in refined bio-oil contributed to forming superior boundary lubrication

High temperature vacuum furnace for the preparation of graphite targets for 14C dating by tandem accelerator mass spectrometry

International Nuclear Information System (INIS)

Lowe, D.C.; Bristow, P.; Judd, W.J.

1985-02-01

A simple and reliable furnace design capable of producing temperatures of up to 2800 deg. C is presented. The furnace has been specifically designed for the rapid and reliable production of graphite targets for 14 C dating purposes but may be used in a variety of applications requiring high temperatures under vacuum conditions

Investigation of TiN thin film oxidation depending on the substrate temperature at vacuum break

Energy Technology Data Exchange (ETDEWEB)

Piallat, Fabien, E-mail: fabien.piallat@gmail.com [STMicroelectronics, 850 rue Jean Monnet, 38920 Crolles (France); CEA, LETI, Campus Minatec, F-38054 Grenoble (France); LTM-CNRS, 17 rue des Martyrs, 38054 Grenoble (France); Gassilloud, Remy [CEA, LETI, Campus Minatec, F-38054 Grenoble (France); Caubet, Pierre [STMicroelectronics, 850 rue Jean Monnet, 38920 Crolles (France); Vallée, Christophe [LTM-CNRS, 17 rue des Martyrs, 38054 Grenoble (France)

2016-09-15

Due to the reduction of the thickness of the layers used in the advanced technology nodes, there is a growing importance of the surface phenomena in the definition of the general properties of the materials. One of the least controlled and understood phenomenon is the oxidation of metals after deposition, at the vacuum break. In this study, the influence of the sample temperature at vacuum break on the oxidation level of TiN deposited by metalorganic chemical vapor deposition is investigated. TiN resistivity appears to be lower for samples which underwent vacuum break at high temperature. Using X-ray photoelectron spectrometry analysis, this change is correlated to the higher oxidation of the TiN layer. Moreover, angle resolved XPS analysis reveals that higher is the temperature at the vacuum break, higher is the surface oxidation of the sample. This surface oxidation is in turn limiting the diffusion of oxygen in the volume of the layer. Additionally, evolution of TiN layers resistivity was monitored in time and it shows that resistivity increases until a plateau is reached after about 10 days, with the lowest temperature at vacuum break resulting in the highest increase, i.e., the resistivity of the sample released to atmosphere at high temperature increased by a factor 1.7 whereas the resistivity of the sample cooled down under vacuum temperature increased by a factor 2.7.

Distilling shale

Energy Technology Data Exchange (ETDEWEB)

Heyl, G E

1917-02-06

The yield of oil obtained by distilling shale is increased by first soaking the shale with about 10 percent of its volume of a liquid hydrocarbon for a period of 24 hours or longer. Distillation is carried on up to a temperature of about 220/sup 0/C., and a further 10 percent of hydrocarbon is then added and the distillation continued up to a temperature of about 400/sup 0/C.

Separation of tritium from heavy water by vacuum distillation; Separacion de tritio de agua pesada por destilacion al vacio

Energy Technology Data Exchange (ETDEWEB)

Vidal, M I; Cabrera, C A [Comision Nacional de Energia Atomica, San Martin (Argentina). Unidad de Actividad Reactores y Centrales Nucleares

1997-12-31

In this report the feasibility of using vacuum distillation to detriate the moderator of a HWR nuclear power plant is studied. It is intended to use, for this purpose, the Atucha I nuclear power plant present facilities. The physical-chemistry of the system is described and the most appropriate range of operating conditions is examined. The availability of data to make use of the present equipment is also analyzed. (author). 20 refs., 3 figs., 1 tab.

High vacuum tribology of polycrystalline diamond coatings

Indian Academy of Sciences (India)

Polycrystalline diamond coatings; hot filament CVD; high vacuum tribology. 1. Introduction .... is a characteristic of graphite. We mark the (diamond ... coefficient of friction due to changes in substrate temperature. The average coefficient of.

Distillation plant for tritium enrichment in metallic lithium

International Nuclear Information System (INIS)

Barnert, E.; Butzek, D.; Cordewiner, J.; Heinrichs, E.

1984-06-01

To close the external fuel cycle of fusion reactors, the tritium obtained from lithium must be separated off. One way of doing this is by high-temperature distillation and subsequent permeation. The construction of high-temperature distillation plant is described. For the time being, deuterium is processed instead of tritium. (orig.) [de

Simulation and flavor compound analysis of dealcoholized beer via one-step vacuum distillation.

Science.gov (United States)

Andrés-Iglesias, Cristina; García-Serna, Juan; Montero, Olimpio; Blanco, Carlos A

2015-10-01

The coupled operation of vacuum distillation process to produce alcohol free beer at laboratory scale and Aspen HYSYS simulation software was studied to define the chemical changes during the dealcoholization process in the aroma profiles of 2 different lager beers. At the lab-scale process, 2 different parameters were chosen to dealcoholize beer samples, 102mbar at 50°C and 200mbar at 67°C. Samples taken at different steps of the process were analyzed by HS-SPME-GC-MS focusing on the concentration of 7 flavor compounds, 5 alcohols and 2 esters. For simulation process, the EoS parameters of the Wilson-2 property package were adjusted to the experimental data and one more pressure was tested (60mbar). Simulation methods represent a viable alternative to predict results of the volatile compound composition of a final dealcoholized beer. Copyright © 2015 Elsevier Ltd. All rights reserved.

Jets with ALICE. From vacuum to QCD at high temperatures

Energy Technology Data Exchange (ETDEWEB)

Leticia, Cunqueiro [University of Muenster (Germany); Collaboration: ALICE-Collaboration

2016-07-01

The hot and dense medium created in heavy-ion collisions is expected to modify the yield and radiation pattern of jets relative to proton proton collisions. The study of medium-induced modifications in jets aims at the understanding of the detailed mechanisms of in medium energy loss of partons and of fundamental properties of QCD at high temperatures. ALICE measures jets in pp, p-Pb and Pb-Pb collisions, where pp and p-Pb are conceived primarily as a reference for vacuum and cold nuclear effects respectively. The jet program comprises measurements like yields for different resolution R, intra-jet and inter-jet modifications via jet shapes and hadron-jet correlations, path length dependence of energy loss via jet flow v{sub 2}, hadrochemistry via jet constituent identification, flavour/mass hierarchy of energy loss via heavy flavour tagging etc. Several of the latest ALICE jet physics results are presented and discussed with emphasis on new studies on jet substructure and jet shapes.

Direct Numerical Simulations of Concentration and Temperature Polarization in Direct Contact Membrane Distillation

Science.gov (United States)

Lou, Jincheng; Tilton, Nils

2017-11-01

Membrane distillation (MD) is a method of desalination with boundary layers that are challenging to simulate. MD is a thermal process in which warm feed and cool distilled water flow on opposite sides of a hydrophobic membrane. The temperature difference causes water to evaporate from the feed, travel through the membrane, and condense in the distillate. Two challenges to MD are temperature and concentration polarization. Temperature polarization represents a reduction in the transmembrane temperature difference due to heat transfer through the membrane. Concentration polarization describes the accumulation of solutes near the membrane. These phenomena reduce filtration and lead to membrane fouling. They are difficult to simulate due to the coupling between the velocity, temperature, and concentration fields on the membrane. Unsteady regimes are particularly challenging because noise at the outlets can pollute the near-membrane flow fields. We present the development of a finite-volume method for the simulation of fluid flow, heat, and mass transport in MD systems. Using the method, we perform a parametric study of the polarization boundary layers, and show that the concentration boundary layer shows self-similar behavior that satisfies power laws for the downstream growth. Funded by the U.S. Bureau of Reclamation.

Reactivity study on thermal cracking of vacuum residues

Science.gov (United States)

León, A. Y.; Díaz, S. D.; Rodríguez, R. C.; Laverde, D.

2016-02-01

This study focused on the process reactivity of thermal cracking of vacuum residues from crude oils mixtures. The thermal cracking experiments were carried out under a nitrogen atmosphere at 120psi between 430 to 500°C for 20 minutes. Temperature conditions were established considering the maximum fractional conversion reported in tests of thermogravimetry performed in the temperature range of 25 to 600°C, with a constant heating rate of 5°C/min and a nitrogen flow rate of 50ml/min. The obtained products were separated in to gases, distillates and coke. The results indicate that the behaviour of thermal reactivity over the chemical composition is most prominent for the vacuum residues with higher content of asphaltenes, aromatics, and resins. Finally some correlations were obtained in order to predict the weight percentage of products from its physical and chemical properties such as CCR, SARA (saturates, aromatics, resins, asphaltenes) and density. The results provide new knowledge of the effect of temperature and the properties of vacuum residues in thermal conversion processes.

Vacuum Radiance-Temperature Standard Facility for Infrared Remote Sensing at NIM

Science.gov (United States)

Hao, X. P.; Song, J.; Xu, M.; Sun, J. P.; Gong, L. Y.; Yuan, Z. D.; Lu, X. F.

2018-06-01

As infrared remote sensors are very important parts of Earth observation satellites, they must be calibrated based on the radiance temperature of a blackbody in a vacuum chamber prior to launch. The uncertainty of such temperature is thus an essential component of the sensors' uncertainty. This paper describes the vacuum radiance-temperature standard facility (VRTSF) at the National Institute of Metrology of China, which will serve to calibrate infrared remote sensors on Chinese meteorological satellites. The VRTSF can be used to calibrate vacuum blackbody radiance temperature, including those used to calibrate infrared remote sensors. The components of the VRTSF are described in this paper, including the VMTBB, the LNBB, the FTIR spectrometer, the reduced-background optical system, the vacuum chamber used to calibrate customers' blackbody, the vacuum-pumping system and the liquid-nitrogen-support system. The experimental methods and results are expounded. The uncertainty of the radiance temperature of VMTBB is 0.026 °C at 30 °C over 10 μm.

Performance Limits and Opportunities for Low Temperature Thermal Desalination

OpenAIRE

Nayar, Kishor Govind; Swaminathan, Jaichander; Warsinger, David Elan Martin; Lienhard, John H.

2015-01-01

Conventional low temperature thermal desalination (LTTD) uses ocean thermal temperature gradients to drive a single stage flash distillation process to produce pure water from seawater. While the temperature difference in the ocean drives distillation and provides cooling in LTTD, external electrical energy is required to pump the water streams from the ocean and to maintain a near vacuum in the flash chamber. In this work, an LTTD process from the literature is compared against, the thermody...

Distillation of combustibles at temperatures below fusion

Energy Technology Data Exchange (ETDEWEB)

Dalin, D

1946-09-26

A process is described for combustion and distillation for dry fuels, such as bituminous shales, below the temperature of fusion of the ash, for the production of heat, in which the temperature in the charge of fuel forming a vertical column is maintained beneath the temperature of fusion of the ash by a withdrawal of the heat from the combustible charge by means of a fluid absorbing this heat. This fluid being constituted, for example, by water in a suitable form, so that it can be circulated through a convenient cooling system, extending through the different parts of the charge. The fluid circulating also through the desired parts of the charge and absorbing the heat, the quantity of fluid or the surface of absorption increasing with the intensity of the combustion in the part of the combustible charge traversed by the fluid.

Microbubble Distillation for Ethanol-Water Separation

Directory of Open Access Journals (Sweden)

Atheer Al-yaqoobi

2016-01-01

Full Text Available In the current study, a novel approach for separating ethanol-water mixture by microbubble distillation technology was investigated. Traditional distillation processes require large amounts of energy to raise the liquid to its boiling point to effect removal of volatile components. The concept of microbubble distillation by comparison is to heat the gas phase rather than the liquid phase to achieve separation. The removal of ethanol from the thermally sensitive fermentation broths was taken as a case of study. Consequently the results were then compared with those which could be obtained under equilibrium conditions expected in an “ideal” distillation unit. Microbubble distillation has achieved vapour compositions higher than that which could be obtained under traditional equilibrium conditions. The separation was achieved at liquid temperature significantly less than the boiling point of the mixture. In addition, it was observed that the separation efficiency of the microbubble distillation could be increased by raising the injected air temperature, while the temperature of the liquid mixture increased only moderately. The separation efficiency of microbubble distillation was compared with that of pervaporation for the recovery of bioethanol from the thermally sensitive fermentation broths. The technology could be controlled to give high separation and energy efficiency. This could contribute to improving commercial viability of biofuel production and other coproducts of biorefinery processing.

Lanthanoid titanate film structure deposited at different temperatures in vacuum

International Nuclear Information System (INIS)

Kushkov, V.D.; Zaslavskij, A.M.; Mel'nikov, A.V.; Zverlin, A.V.; Slivinskaya, A.Eh.

1991-01-01

Influence of deposition temperature on the structure of lanthanoid titanate films, prepared by the method of high-rate vacuum condensation. It is shown that formation of crystal structure, close to equilibrium samples, proceeds at 1100-1300 deg C deposition temperatures. Increase of temperature in this range promotes formation of films with higher degree of structural perfection. Amorphous films of lanthanoid titanates form at 200-1000 deg C. Deposition temperature shouldn't exceed 1400 deg C to prevent the formation of perovskite like phases in films

Molecular Grafting of Fluorinated and Nonfluorinated Alkylsiloxanes on Various Ceramic Membrane Surfaces for the Removal of Volatile Organic Compounds Applying Vacuum Membrane Distillation.

Science.gov (United States)

Kujawa, Joanna; Al-Gharabli, Samer; Kujawski, Wojciech; Knozowska, Katarzyna

2017-02-22

Four main tasks were presented: (i) ceramic membrane functionalization (TiO 2 5 kDa and 300 kDa), (ii) extended material characterization (physicochemistry and tribology) of pristine and modified ceramic samples, (iii) evaluation of chemical and mechanical stability, and finally (iv) assessment of membrane efficiency in vacuum membrane distillation applied for volatile organic compounds (VOCs) removal from water. Highly efficient molecular grafting with four types of perfluoroalkylsilanes and one nonfluorinated agent was developed. Materials with controllable tribological and physicochemical properties were achieved. The most meaningful finding is associated with the applicability of fluorinated and nonfluorinated grafting agents. The results of contact angle, hysteresis of contact angle, sliding angle, and critical surface tension as well as Young's modulus, nanohardness, and adhesion force for grafting by these two modifiers are comparable. This provides insight into the potential applicability of environmental friendly hydrophobic and superhydrophobic surfaces. The achieved hydrophobic membranes were very effective in the removal of VOCs (butanol, methyl-tert-butyl ether, and ethyl acetate) from binary aqueous solutions in vacuum membrane distillation. The correlation between membrane effectiveness and separated solvent polarity was compared in terms of material properties and resistance to the wetting (kinetics of wetting and in-depth liquid penetration). Material properties were interpreted considering Zisman theory and using Kao diagram. The significant influence of surface chemistry on the membrane performance was noticed (5 kDa, influence of hydrophobic nanolayer and separation controlled by solution-diffusion model; 300 kDa, no impact of surface chemistry and separation controlled by liquid-vapor equilibrium).

Assessing the feasibility of a high-temperature, helium-cooled vacuum vessel and first wall for the Vulcan tokamak conceptual design

International Nuclear Information System (INIS)

Barnard, H.S.; Hartwig, Z.S.; Olynyk, G.M.; Payne, J.E.

2012-01-01

The Vulcan conceptual design (R = 1.2 m, a = 0.3 m, B 0 = 7 T), a compact, steady-state tokamak for plasma–material interaction (PMI) science, must incorporate a vacuum vessel capable of operating at 1000 K in order to replicate the temperature-dependent physical chemistry that will govern PMI in a reactor. In addition, the Vulcan divertor must be capable of handling steady-state heat fluxes up to 10 MW m −2 so that integrated materials testing can be performed under reactor-relevant conditions. A conceptual design scoping study has been performed to assess the challenges involved in achieving such a configuration. The Vulcan vacuum system comprises an inner, primary vacuum vessel that is thermally and mechanically isolated from the outer, secondary vacuum vessel by a 10 cm vacuum gap. The thermal isolation minimizes heat conduction between the high-temperature helium-cooled primary vessel and the water-cooled secondary vessel. The mechanical isolation allows for thermal expansion and enables vertical removal of the primary vessel for maintenance or replacement. Access to the primary vessel for diagnostics, lower hybrid waveguides, and helium coolant is achieved through ∼1 m long intra-vessel pipes to minimize temperature gradients and is shown to be commensurate with the available port space in Vulcan. The isolated primary vacuum vessel is shown to be mechanically feasible and robust to plasma disruptions with analytic calculations and finite element analyses. Heat removal in the first wall and divertor, coupled with the ability to perform in situ maintenance and replacement of divertor components for scientific purposes, is achieved by combining existing helium-cooled techniques with innovative mechanical attachments of plasma facing components, either in plate-type helium-cooled modules or independently bolted, helium-jet impingement-cooled tiles. The vacuum vessel and first wall design enables a wide range of potential PFC materials and configurations to

Role of vacuum in food preservation

International Nuclear Information System (INIS)

Bongirwar, D.R.

1997-01-01

Considerable progress has been made in the processing of foods using operations viz. drying, evaporation, distillation, concentration, centrifugation, filtration, irradiation, freeze drying, osmotic drying etc. to get ready to eat food, convenience food, pre cooked dried food. Vacuum technology in direct or indirect way has played a vital role in carrying out these food processing operations. The role of vacuum in getting these processes developed and its use in the development of these high quality products with respect to colour, flavour, texture and other attributes has been highlighted along with process details. (author)

Distillation of LiCl from the LiCl-Li2O molten salt of the electrolytic reduction process

International Nuclear Information System (INIS)

Kim, I.S.; Oh, S.C.; Im, H.S.; Hur, J.M.; Lee, H.S.

2013-01-01

Electrolytic reduction of the uranium oxide in LiCl-Li 2 O molten salt for the treatment of spent nuclear fuel requires the separation of the residual salt from the reduced metal product, which contains about 20 wt% salt. In order to separate the residual salt and reuse it in the electrolytic reduction, a vacuum distillation process was developed. Lab-scale distillation equipment was designed and installed in an argon atmosphere glove box. The equipment consisted of an evaporator in which the reduced metal product was contained and exposed to a high temperature and reduced pressure; a receiver; and a vertically oriented condenser that operated at a temperature below the melting point of lithium chloride. We performed experiments with LiCl-Li 2 O salt to evaluate the evaporation rate of LiCl salt and varied the operating temperature to discern its effect on the behavior of salt evaporation. Complete removal of the LiCl salt from the evaporator was accomplished by reducing the internal pressure to <100 mTorr and heating to 900 deg C. We achieved evaporation efficiency as high as 100 %. (author)

An ultra-high vacuum scanning tunneling microscope operating at sub-Kelvin temperatures and high magnetic fields for spin-resolved measurements

Science.gov (United States)

Salazar, C.; Baumann, D.; Hänke, T.; Scheffler, M.; Kühne, T.; Kaiser, M.; Voigtländer, R.; Lindackers, D.; Büchner, B.; Hess, C.

2018-06-01

We present the construction and performance of an ultra-low-temperature scanning tunneling microscope (STM), working in ultra-high vacuum (UHV) conditions and in high magnetic fields up to 9 T. The cryogenic environment of the STM is generated by a single-shot 3He magnet cryostat in combination with a 4He dewar system. At a base temperature (300 mK), the cryostat has an operation time of approximately 80 h. The special design of the microscope allows the transfer of the STM head from the cryostat to a UHV chamber system, where samples and STM tips can be easily exchanged. The UHV chambers are equipped with specific surface science treatment tools for the functionalization of samples and tips, including high-temperature treatments and thin film deposition. This, in particular, enables spin-resolved tunneling measurements. We present test measurements using well-known samples and tips based on superconductors and metallic materials such as LiFeAs, Nb, Fe, and W. The measurements demonstrate the outstanding performance of the STM with high spatial and energy resolution as well as the spin-resolved capability.

Study of distillation and degradation of perfluoro polyether

International Nuclear Information System (INIS)

Lopergolo, Lilian Cristine

1997-01-01

Perfluoro-polyethers, PFPE, were first synthesised by Sianesi and collaborators giving rise to a new lubricant oils and greases classes with several applications. Perfluoro polyethers have excellent properties, for instance: high chemical stability and thermal stability, high density, high radiation resistance and excellent lubricating properties. FOMBLIN-Y oil is one of the perfluoro polyethers used as a lubricant in vacuum systems applied in the UF 6 enrichment installations. Due to its excellent properties and for its applications in the nuclear field, IPEN-CNEN/S P had the interest to dominate its production technology with the aim to substitute the commercial FOMBLIN-Y oil used in the national consumption. The FOMBLIN-Y oil synthesis method, adopted in IPEN-CNEN/S P, made by the photooxidation of the hexa fluoro propylene. In this work we study the fraction separation of the national available production with restricted an increased molecular weights which was obtained by fraction distillation in a vacuum according to the ASTM D-1160 norm. We also study the catalytic effect of metals on the thermal stability of perfluoro polyethers. The inertness of perfluoro polyethers at temperatures higher than 300 deg C is strongly affected by presence of some metals. Al and Ti alloys cause fluid degradation at 250 deg C. This degradation is very important because it has a yield increase of the perfluoro polyethers production. (author)

Refining of Cd and Zn from interstitial impurities using distillation with a ZrFe getter filter

Directory of Open Access Journals (Sweden)

Scherban’ A. P.

2013-10-01

Full Text Available Behavior of interstitial impurities in Cd and Zn is analysed in terms of thermodynamics. The authors consider reduction reactions of cadmium, zinc and carbon oxides, as well as zinc nitride with the getter material from the Zr-Fe alloy, depending on temperature and vacuum. Optimum initial temperature and vacuum conditions for the processes of deep refining of Cd and Zn from interstitial impurities has been developed. It has been shown experimentally that the proposed refining method provides a more effective cleaning of cadmium and zinc from the interstitial impurities than the distillation without a filter: the impurity content is reduced more than tenfold compared to the concentration in the input metal.

Characterization of magnetic Ni clusters on graphene scaffold after high vacuum annealing

Energy Technology Data Exchange (ETDEWEB)

Zhang, Zhenjun, E-mail: zzhang1@albany.edu; Matsubayashi, Akitomo, E-mail: norwegianwood.1984@gmail.com; Grisafe, Benjamin, E-mail: bgrisafe@albany.edu; Lee, Ji Ung, E-mail: jlee1@albany.edu; Lloyd, James R., E-mail: JLloyd@sunycnse.com

2016-02-15

Magnetic Ni nanoclusters were synthesized by electron beam deposition utilizing CVD graphene as a scaffold. The subsequent clusters were subjected to high vacuum (5−8 x10{sup −7} torr) annealing between 300 and 600 °C. The chemical stability, optical and morphological changes were characterized by X-ray photoemission microscopy, Raman spectroscopy, atomic force microscopy and magnetic measurement. Under ambient exposure, nickel nanoparticles were observed to be oxidized quickly, forming antiferromagnetic nickel oxide. Here, we report that the majority of the oxidized nickel is in non-stoichiometric form and can be reduced under high vacuum at temperature as low as 300 °C. Importantly, the resulting annealed clusters were relatively stable and no further oxidation was detectable after three weeks of air exposure at room temperature. - Highlights: • Random oriented nickel clusters were assembled on monolayer graphene scaffold. • Nickel oxide shell was effectively reduced at moderate temperature. • Coercivity of nickel clusters are greatly improved after high vacuum annealing.

In-situcross-linked PVDF membranes with enhanced mechanical durability for vacuum membrane distillation

KAUST Repository

Zuo, Jian; Chung, Neal Tai-Shung

2016-01-01

A novel and effective one-step method has been demonstrated to fabricate cross-linked polyvinylidene fluoride (PVDF) membranes with better mechanical properties and flux for seawater desalination via vacuum membrane distillation (VMD). This method involves the addition of two functional nonsolvent additives; namely, water and ethylenediamine (EDA), into the polymer casting solution. The former acts as a pore forming agent, while the latter performs as a cross-linking inducer. The incorporation of water tends to increase membrane flux via increasing porosity and pore size but sacrifices membrane mechanical properties. Conversely, the presence of EDA enhances membrane mechanical properties through in-situ cross-linking reaction. Therefore, by synergistically combining the effects of both functional additives, the resultant PVDF membranes have shown good MD performance and mechanical properties simultaneously. The parameters that affect the cross-link reaction and membrane mechanical properties such as reaction duration and EDA concentration have been systematically studied. The membranes cast from an optimal reaction condition comprising 0.8 wt % EDA and 3-hour reaction not only shows a 40% enhancement in membrane Young's Modulus compared to the one without EDA but also achieves a good VMD flux of 43.6 L/m2-h at 60°C. This study may open up a totally new approach to design next-generation high performance MD membranes. © 2016 American Institute of Chemical Engineers AIChE J, 62: 4013–4022, 2016

In-situcross-linked PVDF membranes with enhanced mechanical durability for vacuum membrane distillation

KAUST Repository

Zuo, Jian

2016-05-12

A novel and effective one-step method has been demonstrated to fabricate cross-linked polyvinylidene fluoride (PVDF) membranes with better mechanical properties and flux for seawater desalination via vacuum membrane distillation (VMD). This method involves the addition of two functional nonsolvent additives; namely, water and ethylenediamine (EDA), into the polymer casting solution. The former acts as a pore forming agent, while the latter performs as a cross-linking inducer. The incorporation of water tends to increase membrane flux via increasing porosity and pore size but sacrifices membrane mechanical properties. Conversely, the presence of EDA enhances membrane mechanical properties through in-situ cross-linking reaction. Therefore, by synergistically combining the effects of both functional additives, the resultant PVDF membranes have shown good MD performance and mechanical properties simultaneously. The parameters that affect the cross-link reaction and membrane mechanical properties such as reaction duration and EDA concentration have been systematically studied. The membranes cast from an optimal reaction condition comprising 0.8 wt % EDA and 3-hour reaction not only shows a 40% enhancement in membrane Young\\'s Modulus compared to the one without EDA but also achieves a good VMD flux of 43.6 L/m2-h at 60°C. This study may open up a totally new approach to design next-generation high performance MD membranes. © 2016 American Institute of Chemical Engineers AIChE J, 62: 4013–4022, 2016

Destructive distillation: oils

Energy Technology Data Exchange (ETDEWEB)

West, J; Glover, S

1918-01-31

Canned and other coals are destructively distilled in continuously operated vertical retorts which at their upper portions are maintained at temperatures suitable for low temperature oil distillation such as about 700/sup 0/C, and at their lower portions the temperature is higher and such as to be suitable for the production of gas, e.g., about 1400/sup 0/C. Superheated steam is introduced into the lower portion of the retort, preferably by means of the arrangement described in Specification 120,458, and this is converted into blue water gas which assists the distillation in the center of the coal charge. The retorts are preferably such as are described in Specifications 2663/07 and 7757/14.

Design and performance of an ultra-high vacuum scanning tunneling microscope operating at dilution refrigerator temperatures and high magnetic fields.

Science.gov (United States)

Misra, S; Zhou, B B; Drozdov, I K; Seo, J; Urban, L; Gyenis, A; Kingsley, S C J; Jones, H; Yazdani, A

2013-10-01

We describe the construction and performance of a scanning tunneling microscope capable of taking maps of the tunneling density of states with sub-atomic spatial resolution at dilution refrigerator temperatures and high (14 T) magnetic fields. The fully ultra-high vacuum system features visual access to a two-sample microscope stage at the end of a bottom-loading dilution refrigerator, which facilitates the transfer of in situ prepared tips and samples. The two-sample stage enables location of the best area of the sample under study and extends the experiment lifetime. The successful thermal anchoring of the microscope, described in detail, is confirmed through a base temperature reading of 20 mK, along with a measured electron temperature of 250 mK. Atomically resolved images, along with complementary vibration measurements, are presented to confirm the effectiveness of the vibration isolation scheme in this instrument. Finally, we demonstrate that the microscope is capable of the same level of performance as typical machines with more modest refrigeration by measuring spectroscopic maps at base temperature both at zero field and in an applied magnetic field.

Large scale use of brazing and high temperature brazing for the fabrication of the 6.4 km long vacuum system of the HERA electron storage ring

International Nuclear Information System (INIS)

Ballion, R.; Boster, J.; Giesske, W.; Hartwig, H.; Jagnow, D.; Kouptsidis, J.; Pape, R.; Prohl, W.; Schumann, G.; Schwartz, M.; Iversen, K.; Mucklenbeck, J.

1989-01-01

The 6.4 km long vacuum system for electrons in the large storage ring HERA at Hamburg consists of about 1,400 components having lengths between .14 and 12 m. The vacuum components are mainly made from variously shaped tubes of the copper alloy CuSn2. This alloy combines sufficient mechanical strength with the high thermal conductivity needed to remove the 6 MW dissipated power of the synchrotron-light. The vacuum components consist additionally of parts made from stainless steel such as flanges, chambers for pumps, beam monitors, etc. All of these parts are connected in a vacuum tight manner and on a large scale by using brazing and high temperature brazing both in a vacuum or in a reducing gas atmosphere. (orig.)

Distributed remote temperature monitoring system for INDUS-2 vacuum chambers

International Nuclear Information System (INIS)

Bhange, N.J.; Gothwal, P.; Fatnani, P.; Shukla, S.K.

2011-01-01

Indus-2, a 2.5 GeV Synchrotron Radiation Source (SRS) at Indore has a large vacuum system. The vacuum envelope of Indus-2 ring comprises of 16 dipole chambers as vital parts. Each chamber has 4 photon absorbers and three beam line ports blanked with end flanges. Temperature monitoring of critical vacuum components during operation of Indus-2 ring is an important requirement. The paper discusses a distributed, 160 channel remote temperature monitoring system developed and deployed for this purpose using microcontroller based, modular Temperature Monitoring Units (TMU). The cabling has been extensively minimized using RS485 system and keeping trip relay contacts of all units in series. For ensuring proper signal conditioning of thermocouple outputs (K-type) and successful operation over RS485 bus, many precautions were taken considering the close proximity to the storage ring. We also discuss the software for vacuum chamber temperature monitoring and safety system. The software developed using LabVIEW, has important features like modularity, client-server architecture, local and global database logging, alarms and trips, event and error logging, provision of various important configurations, communications handling etc. (author)

Destructive distillation

Energy Technology Data Exchange (ETDEWEB)

1938-07-05

A process and apparatus for the destructive distillation at low temperature of mineral or organic material particularly oil shale, is given in which the process comprises distilling the material in a horizontal gaseous stream, subjecting the hot residues to the action of a gaseous stream containing a predetermined amount of oxygen so as to burn, at least partly, the carbon-containing substances, and the process uses the gases from this combustion for the indirect heating of the gases serving for the distillation.

Aerobic stability of distillers wet grains as influenced by temperature.

Science.gov (United States)

Lehman, R Michael; Rosentrater, Kurt A

2013-02-01

The storability of distillers wet grains (DWG) influences the economic, energetic, and carbon balances of fuel ethanol production, yet there are limited published data on the deterioration of DWG following its production. We used biogenic CO(2) production to assess the aerobic stability of DWG incubated at three temperatures (12 °C, 22 °C, 32 °C) and compared CO(2) production over time to the appearance of mold and changes in DWG color parameters. CO(2) production and mold colonization indicate that at temperatures near 12 °C, the aerobic stability of DWG was high and that it can be stored for at least a 10-day period. At temperatures close to 22 °C, the onset of increased microbial activity and visible mold colonization occurred between 4 and 7 days and both activity and mold ratings were very high by the ninth day in all three experiments. At 32 °C, 2 days may be a more appropriate limit for storage. Temperature and time interact in a nonlinear fashion that permits the prediction of DWG stability boundaries. The simple visual appearance of mold appears to be a reasonable indicator that correlates well (r = 0.694) with CO(2) production, a measure of the aerobic stability of DWG. Published 2012 by John Wiley & Sons, Ltd.

Improving distillation method and device of tritiated water analysis for ultra high decontamination efficiency

International Nuclear Information System (INIS)

Fang, Hsin-Fa; Wang, Chu-Fang; Lin, Chien-Kung

2015-01-01

It is important that monitoring environmental tritiated water for understanding the contamination dispersion of the nuclear facilities. Tritium is a pure beta radionuclide which is usually measured by Liquid Scintillation Counting (LSC). The average energy of tritum beta is only 5.658 keV that makes the LSC counting of tritium easily be interfered by the beta emitted by other radionuclides. Environmental tritiated water samples usually need to be decontaminated by distillation for reducing the interference. After Fukushima Nucleaer Accident, the highest gross beta concentration of groundwater samples obtained around Fukushima Daiichi Nuclear Power Station is over 1,000,000 Bq/l. There is a need for a distillation with ultra-high decontamination efficiency for environmental tritiated water analysis. This study is intended to improve the heating temperature control for better sub-boiling distillation control and modify the height of the container of the air cooling distillation device for better fractional distillation effect. The DF of Cs-137 of the distillation may reach 450,000 which is far better than the prior study. The average loss rate of the improved method and device is about 2.6% which is better than the bias value listed in the ASTM D4107-08. It is proven that the modified air cooling distillation device can provide an easy-handling, water-saving, low cost and effective way of purifying water samples for higher beta radionuclides contaminated water samples which need ultra-high decontamination treatment. - Highlights: • The improvements of method and device make the decontaminatin factor (DF) of Cs-137 of distillation reach over 450,000. • The decontamination factor ( DF) value may be increased about 20 times by increasing the height of the container from 7 cm to 20 cm. • The device provides an easy-handling, water-saving, low cost, stable and effective way for the distillation of triated water analysis.

Development of high pressure-high vacuum-high conductance piston valve for gas-filled radiation detectors

International Nuclear Information System (INIS)

Prasad, D N; Ayyappan, R; Kamble, L P; Singh, J P; Muralikrishna, L V; Alex, M; Balagi, V; Mukhopadhyay, P K

2008-01-01

Gas-filled radiation detectors need gas filling at pressures that range from few cms of mercury to as high as 25kg/cm 2 at room temperature. Before gas-filling these detectors require evacuation to a vacuum of the order of ∼1 x 10 -5 mbar. For these operations of evacuation and gas filling a system consisting of a vacuum pump with a high vacuum gauge, gas cylinder with a pressure gauge and a valve is used. The valve has to meet the three requirements of compatibility with high-pressure and high vacuum and high conductance. A piston valve suitable for the evacuation and gas filling of radiation detectors has been designed and fabricated to meet the above requirements. The stainless steel body (80mmx160mm overall dimensions) valve with a piston arrangement has a 1/2 inch inlet/outlet opening, neoprene/viton O-ring at piston face and diameter for sealing and a knob for opening and closing the valve. The piston movement mechanism is designed to have minimum wear of sealing O-rings. The valve has been hydrostatic pressure tested up to 75bars and has Helium leak rate of less than 9.6x10 -9 m bar ltr/sec in vacuum mode and 2x10 -7 mbar ltr/sec in pressure mode. As compared to a commercial diaphragm valve, which needed 3 hours to evacuate a 7 litre chamber to 2.5x10 -5 mbar, the new valve achieved vacuum 7.4x10 -6 mbar in the same time under the same conditions

Desalination by very low temperature nuclear heat

International Nuclear Information System (INIS)

Saari, Risto

1977-01-01

A new sea water desalination method has been developed: Nord-Aqua Vacuum Evaporation, which utilizes waste heat at a very low temperature. The requisite vacuum is obtained by the aid of a barometric column and siphon, and the dissolved air is removed from the vacuum by means of water flows. According to test results from a pilot plant, the process is operable if the waste heat exists at a temperature 7degC higher than ambient. The pumping energy which is then required is 9 kcal/kg, or 1.5% of the heat of vaporization of water. Calculations reveal that the method is economically considerably superior to conventional distilling methods. (author)

Sensor locations and noise reduction in high-purity batch distillation control loops

Directory of Open Access Journals (Sweden)

Oisiovici R.M.

2000-01-01

Full Text Available The influence of the sensor locations on the composition control of high-purity batch distillation columns has been investigated. Using concepts of the nonlinear control theory, an input-output linearizing controller was implemented to keep the distillate composition constant at a desired value by varying the reflux ratio. An Extended Kalman Filter was developed to estimate the compositions required in the control algorithm using temperature measurements. In the presence of measurement noise, the control performance depended greatly on the sensor locations. Placing the sensors further from the top stages reduced the detrimental effects of noise but increased the inference error. To achieve accurate composition control, both noise reduction and composition estimate accuracy should be considered in the selection of the sensor locations.

Field installed brazed thermocouple feedthroughs for high vacuum experiments

International Nuclear Information System (INIS)

Anderson, P.; Messick, C.

1983-01-01

In order to reduce the occurrence of vacuum leaks and to increase the availability of the DIII vacuum vessel for experimental operation, effort was applied to developing a vacuum-tight brazed feedthrough system for sheathed thermocouples, stainless steel sheathed conductor cables and tubes for cooling fluids. This brazed technique is a replacement for elastomer ''O'' ring sealed feedthroughs that have proven vulnerable to leaks caused by thermal cycling, etc. To date, about 200 feedthroughs have been used. Up to 91 were grouped on a single conflat flange mounted in a bulkhead connector configuration which facilitates installation and removal. Investigation was required to select a suitable braze alloy, flux and installation procedure. Braze alloy selection was challenging since the alloy was required to have: 1) Melting temperature in excess of the 250 0 C (482 0 F) bakeout temperature. 2) No high vapor pressure elements. 3) Good wetting properties when used in air with acceptable flux. 4) Good wettability to 300 series stainless steel and inconel

A new-generation asymmetric multi-bore hollow fiber membrane for sustainable water production via vacuum membrane distillation.

Science.gov (United States)

Wang, Peng; Chung, Tai-Shung

2013-06-18

Due to the growing demand for potable water, the capacities for wastewater reclamation and saline water desalination have been increasing. More concerns are raised on the poor efficiency of removing certain contaminants by the current water purification technologies. Recent studies demonstrated superior separation performance of the vacuum membrane distillation (VMD) technology for the rejection of trace contaminants such as boron, dye, endocrine-disruptive chemical, and chloro-compound. However, the absence of suitable membranes with excellent wetting resistance and high permeation flux has severely hindered the VMD application as an effective water production process. This work presents a new generation multibore hollow fiber (MBF) membrane with excellent mechanical durability developed for VMD. Its micromorphology was uniquely designed with a tight surface and a fully porous matrix to maximize both high wetting resistance and permeation flux. Credit to the multibore configuration, a 65% improvement was obtained on the antiwetting property. Using a synthetic seawater feed, the new membrane with optimized fabrication condition exhibits a high flux and the salt rejection is consistently greater than 99.99%. In addition, a comparison of 7-bore and 6-bore MBF membranes was performed to investigate the optimum geometry design. The newly designed MBF membrane not only demonstrates its suitability for VMD but also makes VMD come true as an efficient process for water production.

The application of vacuum redistillation of patchouli oil to improve patchouli alcohol compound

Science.gov (United States)

Asnawi, T. M.; Alam, P. N.; Husin, H.; Zaki, M.

2018-04-01

Patchouli oil produced by traditional distillation of patchouli leaves and stems by farmers in Aceh still has low patchouli alcohol compound. In order to increase patchouli alcohol concentration, vacuum redistillation process using packed column was introduced. This research was conducted to fractionate terpene (alpha-copinene) from oxygenated hydrocarbon (patchouli alcohol) compound. The operation condition was conducted at two variables that was dependent variable and independent variable. The dependent variable was the 30 cm height distillation packed column, by using raschig ring with 8 mm x 8 mm dimension. And the independent variable was operating temperature 130 °C and 140 °C., vacuum pressure 143,61 mbar, 121,60 mbar and 88,59 mbar and operation time 2 hours, 3 hours and 5 hours. Total of treatments applied in this works were 3 x 3 x 3 or equal to 27 treatments. Patchouli oil used in this research was obtained from Desa Teladan-Lembah Seulawah, Aceh Province. The initial patchouli alcohol compound which analyzed with GC-MS contained 16,02% before treatment applied. After vacuum redistillation process treatment applied patchouli oil concentration increase up to 34,67%. Physico-chemical test of patchouli oil after vacuum redistillation is in accordance with SNI 06-23852006 standard.

Distilling shale and coal

Energy Technology Data Exchange (ETDEWEB)

Edwards, H; Young, G

1923-01-09

In a process of recovering oil from shale or coal the material is ground and may be subjected to a cleaning or concentrating process of the kind described in Specification 153,663 after which it is distilled in a furnace as described in Specification 13,625/09 the sections of the furnace forming different temperature zones, and the rate of the passage of the material is regulated so that distillation is complete with respect to the temperature of each zone, the whole distillation being accomplished in successive stages. The vapors are taken off at each zone and superheated steam may be passed into the furnace at suitable points and the distillation terminated at any stage of the process.

High temperature x-ray diffraction of zr-2.5nb during thermal cycling in vacuum

Directory of Open Access Journals (Sweden)

Tumanov Mikhail

2017-01-01

Full Text Available The cyclic thermal tests in vacuum of zirconium alloy Zr-2.5Nb in the temperature range 250-350°C is established the presence of anomalies of thermal deformation of the crystal lattice, reducing the efficiency of the fuel rods.

Optimization model of a system of crude oil distillation units with heat integration and metamodeling

International Nuclear Information System (INIS)

Lopez, Diana C; Mahecha, Cesar A; Hoyos, Luis J; Acevedo, Leonardo; Villamizar Jaime F

2010-01-01

The process of crude distillation impacts the economy of any refinery in a considerable manner. Therefore, it is necessary to improve it taking good advantage of the available infrastructure, generating products that conform to the specifications without violating the equipment operating constraints or plant restrictions at industrial units. The objective of this paper is to present the development of an optimization model for a Crude Distillation Unit (CDU) system at a ECOPETROL S.A. refinery in Barrancabermeja, involving the typical restrictions (flow according to pipeline capacity, pumps, distillation columns, etc) and a restriction that has not been included in bibliographic reports for this type of models: the heat integration of streams from Atmospheric Distillation Towers (ADTs) and Vacuum Distillation Towers (VDT) with the heat exchanger networks for crude pre-heating. On the other hand, ADTs were modeled with Metamodels in function of column temperatures and pressures, pump a rounds flows and return temperatures, stripping steam flows, Jet EBP ASTM D-86 and Diesel EBP ASTM D-86. Pre-heating trains were modeled with mass and energy balances, and design equation of each heat exchanger. The optimization model is NLP, maximizing the system profit. This model was implemented in GAMSide 22,2 using the CONOPT solver and it found new operating points with better economic results than those obtained with the normal operation in the real plants. It predicted optimum operation conditions of 3 ADTs for constant composition crude and calculated the yields and properties of atmospheric products, additional to temperatures and duties of 27 Crude Oil exchangers.

Decay rate of the false vacuum at high tempratures

International Nuclear Information System (INIS)

Eboli, O.J.P.; Marques, G.C.

1984-01-01

Within the semiclassical approach, the high temperaure behaviour of the decay rate of the metastable vacuum in Field Theory is investigated. It is shown that, contrarily to what has been proposed in the literature, the pre-exponential factor exhibits a nontrivial dependence on the temperature. Furthermore, this dependence is such that at very high temperatures it is as important as the exponential factor and consequently it spoils many conclusions drawn up to now on Cosmological Phase Transitions. (Author) [pt

A feasibility study for high-temperature titanium reduction from TiCl4 using a magnesiothermic process

Science.gov (United States)

Ivanov, S. L.; Zablotsky, D.

2018-05-01

The current industrial practice for titanium extraction is a complex procedure, which produces a porous reaction mass of sintered titanium particulates fused to a steel retort wall with magnesium and MgCl2 trapped in the interstices. The reactor temperature is limited to approx. 900 °C due to the formation of fusible TiFe eutectic, which corrodes the retort and degrades the quality of titanium sponge. Here we examine the theoretical foundations and technological possibilities to design a shielded retort of niobium-zirconium alloy NbZr(1%), which is resistant to corrosion by titanium at high temperature. We consider the reactor at a temperature of approx. 1150 °C. Supplying stoichiometric quantities of reagents enables the reaction in the gas phase, whereas the exothermic process sustains the combustion of the reaction zone. When the pathway to the condenser is open, vacuum separation and evacuation of vaporized magnesium dichloride and excess magnesium into the water-cooled condenser take place. As both the reaction and the evacuation occur within seconds, the yield of the extraction is improved. We anticipate new possibilities for designing a device combining the retort function to conduct the reduction in the gas phase with fast vacuum separation of the reaction products and distillation of magnesium dichloride.

Apparatus for distilling dry solids. [high temperature

Energy Technology Data Exchange (ETDEWEB)

Constant, M

1873-09-09

In the proposed system under the action of high temperature, the vapors commence to form, and on account of their density go toward the lower part of the retort, where they take the place of air; then they find the exit prepared for them and run out literally by their weight as they are formed and enter the coil where all that can are completely condensed into oil.

Dynamical Model of QCD Vacuum and Color Thaw at Finite Temperatures

Institute of Scientific and Technical Information of China (English)

WANG Dian-Fu; SONG He-Shan; MI Dong

2004-01-01

In terms of the Nambu-Jona-Lasinio (NJL) mechanism, the dynamical symmetry breaking of a simple localgauge model is investigated. An important relation between the vacuum expectation value of gauge fields and scalarfields is derived by solving the Euler equation for the gauge fields. Based on this relation the SU(3) gauge potential isgiven which can be used to explain the asymptotic freedom and confinement of quarks in a hadron. The confinementbehavior at finite temperatures is also investigated and it is shown that color confinement at zero temperature can bemelted away under high temperatures.

A highly miniaturized vacuum package for a trapped ion atomic clock

Energy Technology Data Exchange (ETDEWEB)

Schwindt, Peter D. D., E-mail: pschwin@sandia.gov; Jau, Yuan-Yu; Partner, Heather; Casias, Adrian; Wagner, Adrian R.; Moorman, Matthew; Manginell, Ronald P. [Sandia National Laboratories, Albuquerque, New Mexico 87185 (United States); Kellogg, James R.; Prestage, John D. [Jet Propulsion Laboratory, Pasadena, California 91109 (United States)

2016-05-15

We report on the development of a highly miniaturized vacuum package for use in an atomic clock utilizing trapped ytterbium-171 ions. The vacuum package is approximately 1 cm{sup 3} in size and contains a linear quadrupole RF Paul ion trap, miniature neutral Yb sources, and a non-evaporable getter pump. We describe the fabrication process for making the Yb sources and assembling the vacuum package. To prepare the vacuum package for ion trapping, it was evacuated, baked at a high temperature, and then back filled with a helium buffer gas. Once appropriate vacuum conditions were achieved in the package, it was sealed with a copper pinch-off and was subsequently pumped only by the non-evaporable getter. We demonstrated ion trapping in this vacuum package and the operation of an atomic clock, stabilizing a local oscillator to the 12.6 GHz hyperfine transition of {sup 171}Y b{sup +}. The fractional frequency stability of the clock was measured to be 2 × 10{sup −11}/τ{sup 1/2}.

Evaluation of air gap membrane distillation process running under sub-atmospheric conditions: Experimental and simulation studies

KAUST Repository

Alsaadi, Ahmad S.; Francis, Lijo; Maab, Husnul; Amy, Gary L.; Ghaffour, NorEddine

2015-01-01

The importance of removing non-condensable gases from air gap membrane distillation (AGMD) modules in improving the water vapor flux is presented in this paper. Additionally, a previously developed AGMD mathematical model is used to predict to the degree of flux enhancement under sub-atmospheric pressure conditions. Since the mathematical model prediction is expected to be very sensitive to membrane distillation (MD) membrane resistance when the mass diffusion resistance is eliminated, the permeability of the membrane was carefully measured with two different methods (gas permeance test and vacuum MD permeability test). The mathematical model prediction was found to highly agree with the experimental data, which showed that the removal of non-condensable gases increased the flux by more than three-fold when the gap pressure was maintained at the saturation pressure of the feed temperature. The importance of staging the sub-atmospheric AGMD process and how this could give better control over the gap pressure as the feed temperature decreases are also highlighted in this paper. The effect of staging on the sub-atmospheric AGMD flux and its relation to membrane capital cost are briefly discussed.

Evaluation of air gap membrane distillation process running under sub-atmospheric conditions: Experimental and simulation studies

KAUST Repository

Alsaadi, Ahmad S.

2015-04-16

The importance of removing non-condensable gases from air gap membrane distillation (AGMD) modules in improving the water vapor flux is presented in this paper. Additionally, a previously developed AGMD mathematical model is used to predict to the degree of flux enhancement under sub-atmospheric pressure conditions. Since the mathematical model prediction is expected to be very sensitive to membrane distillation (MD) membrane resistance when the mass diffusion resistance is eliminated, the permeability of the membrane was carefully measured with two different methods (gas permeance test and vacuum MD permeability test). The mathematical model prediction was found to highly agree with the experimental data, which showed that the removal of non-condensable gases increased the flux by more than three-fold when the gap pressure was maintained at the saturation pressure of the feed temperature. The importance of staging the sub-atmospheric AGMD process and how this could give better control over the gap pressure as the feed temperature decreases are also highlighted in this paper. The effect of staging on the sub-atmospheric AGMD flux and its relation to membrane capital cost are briefly discussed.

Destructive distillation under pressure

Energy Technology Data Exchange (ETDEWEB)

1932-09-08

A process of destructive distillation of distillable carbonaceous material under pressure is described, consisting of regulating the temperature by introducing the carbonaceous materials to a point where the reaction of hydrogenation has begun but has not stopped, by placing it in indirect heat-exchange with a cooling agent at a critical temperature below the reaction temperature, the agent being under pressure and introduced in the liquid state. Water is used as the cooling agent.

Effect of Recycled Waste Polymers, Natural Bitumen and HVS Cut on the Properties of Vacuum Bottom

Directory of Open Access Journals (Sweden)

Y. Rasoulzadeh

2013-01-01

Full Text Available The neat bitumen, an oil refining by-product, has its own inherent weakness under long-time loading at low and high temperatures. These performance limitations of neat bitumen have led researchers to modify its physical andmechanical properties. According to several studies, polymers can be used to modify the properties of bitumen. Due to much lower production costs and aiming to reduce environmental impacts, recycled waste polymers are preferred as compared with virgin polymers. In this study, the effect of recycled waste polymers including crumb rubber modifier (CRM, polyethylene and latex and non-polymeric materials such as natural bitumen (NB and heavy vacuum slops (HVS cut on physical and mechanical properties of vacuum bottom residue (VB of crude oil distillation was investigat-ed. Based on the results, recycled waste polyethylene and NB can improve the performance grade of VB at high temperatures and CRM, latex and HVS can improve the performance grade of VB at low temperatures. Thus, by designing various blends of these additives with VB, different modified bitumens can be directly obtained from VB without any need to air-blowing process.

Method and apparatus for scientific analysis under low temperature vacuum conditions

Science.gov (United States)

Winefordner, James D.; Jones, Bradley T.

1990-01-01

A method and apparatus for scientific analysis of a sample under low temperature vacuum conditions uses a vacuum chamber with a conveyor belt disposed therein. One end of the conveyor belt is a cool end in thermal contact with the cold stage of a refrigerator, whereas the other end of the conveyor belt is a warm end spaced from the refrigerator. A septum allows injection of a sample into the vacuum chamber on top of the conveyor belt for spectroscopic or other analysis. The sample freezes on the conveyor belt at the cold end. One or more windows in the vacuum chamber housing allow spectroscopic analysis of the sample. Following the spectroscopic analysis, the conveyor belt may be moved such that the sample moves toward the warm end of the conveyor belt where upon it evaporates, thereby cleaning the conveyor belt. Instead of injecting the sample by way of a septum and use of a syringe and needle, the present device may be used in series with capillary-column gas chromatography or micro-bore high performance liquid chromatography.

Optimization model of a system of crude oil distillation units whit heat integration and meta modeling

International Nuclear Information System (INIS)

Lopez, Diana C; Mahecha, Cesar A; Hoyos, Luis J; Acevedo, Leonardo; Villamizar Jaime F

2009-01-01

The process of crude distillation impacts the economy of any refinery in a considerable manner. Therefore, it is necessary to improve it taking good advantage of the available infrastructure, generating products that conform to the specifications without violating the equipment operating constraints or plant restrictions at industrial units. The objective of this paper is to present the development of an optimization model for a Crude Distillation Unit (CDU) system at a ECOPETROL S.A. refinery in Barrancabermeja, involving the typical restrictions (flow according to pipeline capacity, pumps, distillation columns, etc) and a restriction that has not been included in bibliographic reports for this type of models: the heat integration of streams from Atmospheric Distillation Towers (ADTs) and Vacuum Distillation Towers (VDT) with the heat exchanger networks for crude pre-heating. On the other hand, ADTs were modeled with Meta models in function of column temperatures and pressures, pumparounds flows and return temperatures, stripping steam flows, Jet EBP ASTM D-86 and Diesel EBP ASTM D-86. Pre-heating trains were modeled with mass and energy balances, and design equation of each heat exchanger. The optimization model is NLP, maximizing the system profit. This model was implemented in GAMSide 22,2 using the CONOPT solver and it found new operating points with better economic results than those obtained with the normal operation in the real plants. It predicted optimum operation conditions of 3 ADTs for constant composition crude and calculated the yields and properties of atmospheric products, additional to temperatures and duties of 27 Crude Oil exchangers.

Solar power water distillation unit

International Nuclear Information System (INIS)

Hameed, Kamran; Khan, Muhammad Muzammil; Ateeq, Ijlal Shahrukh; Omair, Syed Muhammad; Ahmer, Muhammad; Wajid, Abdul

2013-01-01

Clean drinking water is the basic necessity for every human being, but about 1.1 billion people in the world lacked proper drinking water. There are many different types of water purification processes such as filtration, reverse osmosis, ultraviolet radiation, carbon absorption, but the most reliable processes are distillation and boiling. Water purification, such as distillation, is especially important in regions where water resources or tap water is not suitable for ingesting without boiling or chemical treatment. In design project It treats the water by combining different methods such as Filtration, Distillation and a technique called concentrated solar power (CSP). Distillation is literally the method seen in nature, whereby: the sun heats the water on the earth's surface, the water is turned into a vapor (evaporation) and rises, leaving contaminants behind, to form clouds. As the upper atmosphere drops in temperature the vapors cool and convert back to water to form water. In this project distillation is achieved by using a parabolic mirror which boils water at high temperature. Filtration is done by sand filter and carbon filter. First sand filter catches the sand particles and the carbon filter which has granules of active carbon is used to remove odor dissolved gases from water. This is the Pre-treatment of water. The filtered water is then collected in a water container at a focus of parabolic mirror where distillation process is done. Another important feature of designed project is the solar tracking of a parabolic mirror which increases the efficiency of a parabolic mirror [1],[2].

Behavior of pressure rise and condensation caused by water evaporation under vacuum at high temperature

International Nuclear Information System (INIS)

Takase, Kazuyuki; Kunugi, Tomoaki; Yamazaki, Seiichiro; Fujii, Sadao

1998-01-01

Pressure rise and condensation characteristics during the ingress-of-coolant event (ICE) in fusion reactors were investigated using the preliminary ICE apparatus with a vacuum vessel (VV), an additional tank (AT) and an isolation valve (IV). A surface of the AT was cooled by water at RT. The high temperature and pressure water was injected into the VV which was heated up to 250degC and pressure and temperature transients in the VV were measured. The pressure increased rapidly with an injection time of the water because of the water evaporation. After the IV was opened and the VV was connected with the AT, the pressure in the VV decreased suddenly. From a series of the experiments, it was confirmed that control factors on the pressure rise were the flushing evaporation and boiling heat transfer in the VV, and then, condensation of the vapor after was effective to the depressurization in the VV. (author)

High-voltage high-current triggering vacuum switch

International Nuclear Information System (INIS)

Alferov, D.F.; Bunin, R.A.; Evsin, D.V.; Sidorov, V.A.

2012-01-01

Experimental investigations of switching and breaking capacities of the new high current triggered vacuum switch (TVS) are carried out at various parameters of discharge current. It has been shown that the high current triggered vacuum switch TVS can switch repeatedly a current from units up to ten kiloampers with duration up to ten millisecond [ru

Effect of dope solution temperature on the membrane structure and membrane distillation performance

Science.gov (United States)

Nawi, N. I. M.; Bilad, M. R.; Nordin, N. A. H. M.

2018-04-01

Membrane distillation (MD) is a non-isothermal process applicable to purify water using hydrophobic membrane. Membrane in MD is hydrophobic, permeable to water vapor but repels liquid water. MD membrane is expected to pose high flux, high fouling and scaling resistances and most importantly high wetting resistance. This study develops flat-sheet polyvinylidene fluoride (PVDF) membrane by exploring both liquid-liquid and liquid-solid phase inversion technique largely to improve its wetting resistance and flux performance. We hypothesize that temperature of dope solution play roles in solid-liquid separation during membrane formation and an optimum balance between liquid-liquid and liquid-solid (crystallization) separation leads to highly performance PVDF membrane. Findings obtained from differential scanning calorimeter test show that increasing dope solution temperature reduces degree of PVDF crystallinity and suppresses formation of crystalline structure. The morphological images of the resulting membranes show that at elevated dope solution temperature (40, 60, 80 and 100°C), the spherulite-like structures are formed across the thickness of membranes ascribed from due to different type of crystals. The performance of direct-contact MD shows that the obtained flux of the optimum dope temperature (60°C) of 10.8 L/m2h is comparable to commercial PTFE-based MD membrane.

THE THERMOELECTRIC VACUUM CROCK-POT AND THE AUTOMATED WORKPLACE FOR ITS RESEARCH AS A CONTROL OBJECT

Directory of Open Access Journals (Sweden)

S. Hudz

2017-08-01

Full Text Available The technologies of thermal treatment in vacuum are widely used in various fields of production, in particular in the food industry, but their application at farms, hotels or a for domestic purposes is limited because of the big sizes, high cost of processing equipment and complexity of its management at realization of foodstuff processing. Products, made with use of vacuum technologies, keep much more useful substances because they aren't exposed to high-temperature processing and oxidation while preparation. Development and production of the small-sized equipment for realization of heat treatment processes of foodstuff in vacuum would create technical and economic conditions for implementation of temperature processing processes of foodstuff at farms, hotels and even at home that would promote creation of new food, development of new recipes and, in general, development of the new direction in cookery. So the article describes the problem of equipment construction for the process of thermal processing of food in vacuum such as cooking jam, concentration of juices and dairy products, distillation, drying, pickling, and the possibility of building inexpensive compact vacuum unit for the implementation of these processes (crock-pot for use at hotels, farms and even for domestic purposes. The analysis of technological schemes for energy efficient evaporation process in vacuum crock-pot is provided. The developed technological scheme of vacuum crock-pot with thermoelectric converters and principle of its operation are considered. Microprocessor block diagram of a multichannel data acquisition system consisting workstation for investigation of thermoelectric vacuum crock-pot as a control object is presented and control algorithms helping to reduce energy consumption and to increase operational reliability in implementing processes and the quality of ready-made products are provided.

Dynamical Model of QCD Vacuum and Color Thaw at Finite Temperatures

Institute of Scientific and Technical Information of China (English)

WANGDian-Fu; SONGHe-Shan; MIDong

2004-01-01

In terms of the Nambu Jona-Lasinio (NJL) mechanism, the dynamical symmetry breaking of a simple local gauge model is investigated. An important relation between the vacuum expectation value of gauge fields and scalar fields is derived by solving the Euler equation for the gauge fields. Based on this relation the SU(3) gauge potential is given which can be used to explain the asymptotic freedom and confinement of quarks in a hadron. The confinement behavior at finite temperatures is also investigated and it is shown that color confinement at zero temperature can be melted away under high temperatures.

Multilayer Porous Crucibles for the High Throughput Salt Separation from Uranium Deposits

International Nuclear Information System (INIS)

Kwon, S. W.; Park, K. M.; Kim, J. G.; Kim, I. T.; Seo, B. K.; Moon, J. G.

2013-01-01

Solid cathode processing is necessary to separate the salt from the cathode since the uranium deposit in a solid cathode contains electrolyte salt. A physical separation process, such as a distillation separation, is more attractive than a chemical or dissolution process because physical processes generate much less secondary process. Distillation process was employed for the cathode processsing due to the advantages of minimal generation of secondary waste, compact unit process, simple and low cost equipment. The basis for vacuum distillation separation is the difference in vapor pressures between salt and uranium. A solid cathode deposit is heated in a heating region and salt vaporizes, while nonvolatile uranium remains behind. It is very important to increase the throughput of the salt separation system owing to the high uranium content of spent nuclear fuel and high salt fraction of uranium dendrites. The evaporation rate of the LiCl-KCl eutectic salt in vacuum distiller is not so high to come up with the generation capacity of uranium dendrites in an electro-refiner. Therefore, a wide evaporation area or high distillation temperature is necessary for the successful salt separation. In this study, it was attempted to enlarge a throughput of the salt distiller with a multilayer porous crucibles for the separation of adhered salt in the uranium deposits generated from the electrorefiner. The feasibility of the porous crucibles was tested by the salt distillation experiments. In this study, the salt distiller with multilayer porous crucibles was proposed and the feasibility of liquid salt separation was examined to increase a throughput. It was found that the effective separation of salt from uranium deposits was possible by the multilayer porous crucibles

Multilayer Porous Crucibles for the High Throughput Salt Separation from Uranium Deposits

Energy Technology Data Exchange (ETDEWEB)

Kwon, S. W.; Park, K. M.; Kim, J. G.; Kim, I. T.; Seo, B. K.; Moon, J. G. [Korea Atomic Energy Research Institute, Daejeon (Korea, Republic of)

2013-05-15

Solid cathode processing is necessary to separate the salt from the cathode since the uranium deposit in a solid cathode contains electrolyte salt. A physical separation process, such as a distillation separation, is more attractive than a chemical or dissolution process because physical processes generate much less secondary process. Distillation process was employed for the cathode processsing due to the advantages of minimal generation of secondary waste, compact unit process, simple and low cost equipment. The basis for vacuum distillation separation is the difference in vapor pressures between salt and uranium. A solid cathode deposit is heated in a heating region and salt vaporizes, while nonvolatile uranium remains behind. It is very important to increase the throughput of the salt separation system owing to the high uranium content of spent nuclear fuel and high salt fraction of uranium dendrites. The evaporation rate of the LiCl-KCl eutectic salt in vacuum distiller is not so high to come up with the generation capacity of uranium dendrites in an electro-refiner. Therefore, a wide evaporation area or high distillation temperature is necessary for the successful salt separation. In this study, it was attempted to enlarge a throughput of the salt distiller with a multilayer porous crucibles for the separation of adhered salt in the uranium deposits generated from the electrorefiner. The feasibility of the porous crucibles was tested by the salt distillation experiments. In this study, the salt distiller with multilayer porous crucibles was proposed and the feasibility of liquid salt separation was examined to increase a throughput. It was found that the effective separation of salt from uranium deposits was possible by the multilayer porous crucibles.

Effect of osmotic dehydration and vacuum-frying parameters to produce high-quality mango chips.

Science.gov (United States)

Nunes, Yolanda; Moreira, Rosana G

2009-09-01

Mango (Mangifera indica L.) is a fruit rich in flavor and nutritional values, which is an excellent candidate for producing chips. The objective of this study was to develop high-quality mango chips using vacuum frying. Mango ("Tommy Atkins") slices were pretreated with different maltodextrin concentrations (40, 50, and 65, w/v), osmotic dehydration times (45, 60, and 70 min), and solution temperatures (22 and 40 degrees C). Pretreated slices were vacuum fried at 120, 130, and 138 degrees C and product quality attributes (oil content, texture, color, carotenoid content) determined. The effect of frying temperatures at optimum osmotic dehydration times (65 [w/v] at 40 degrees C) was assessed. All samples were acceptable (scores > 5) to consumer panelists. The best mango chips were those pretreated with 65 (w/v) concentration for 60 min and vacuum fried at 120 degrees C. Mango chips under atmospheric frying had less carotenoid retention (32%) than those under vacuum frying (up to 65%). These results may help further optimize vacuum-frying processing of high-quality fruit-based snacks.

Method of distillation of bituminous material

Energy Technology Data Exchange (ETDEWEB)

Gustafsson, E G.T.

1919-11-12

A method is described of dry distillation of bituminous materials by leading warm combustible gases, mixed or not mixed with steam, through the distillation chamber in direct contact with the materials, during which process the distillation chamber may be heated by other means. It is characterized by the mixture of distillation products (formed by the vapors produced by heating the raw materials) and the gas (circulating gas) used for heating in the process, being led through coolers or similar contrivances, in order to separate through condensation the greater part of the content of the products or materials condensable at ordinary temperatures, and also to recover as much as possible of the highly volatile oils in the gas. Thereafter the gas is split, one part is, without further cleaning, and led through the distillation chamber, after this gas has been reheated in suitable apparatus. The other part (surplus gas), which in volume corresponds approximately to the new-formed distillation gases, is treated according to known methods for the extraction of the remaining products of the distillation, such as volatile oils, ammonia, methyl alcohol, sulfuretted hydrogen, and others. The patent contains three other claims.

Onset temperature for Si nanostructure growth on Si substrate during high vacuum electron beam annealing.

Science.gov (United States)

Fang, F; Markwitz, A

2009-05-01

Silicon nanostructures, called Si nanowhiskers, are successfully synthesized on Si(100) substrate by high vacuum electron beam annealing. The onset temperature and duration needed for the Si nanowhiskers to grow was investigated. It was found that the onset and growth morphology of Si nanowhiskers strongly depend on the annealing temperature and duration applied in the annealing cycle. The onset temperature for nanowhisker growth was determined as 680 degrees C using an annealing duration of 90 min and temperature ramps of +5 degrees C s(-1) for heating and -100 degrees C s(-1) for cooling. Decreasing the annealing time at peak temperature to 5 min required an increase in peak temperature to 800 degrees C to initiate the nanowhisker growth. At 900 degrees C the duration for annealing at peak temperature can be set to 0 s to grow silicon nanowhiskers. A correlation was found between the variation in annealing temperature and duration and the nanowhisker height and density. Annealing at 900 degrees C for 0 s, only 2-3 nanowhiskers (average height 2.4 nm) grow on a surface area of 5 x 5 microm, whereas more than 500 nanowhiskers with an important average height of 4.6 nm for field emission applications grow on the same surface area for a sample annealed at 970 degrees C for 0 s. Selected results are presented showing the possibility of controlling the density and height of Si nanowhisker growth for field emission applications by applying different annealing temperature and duration.

Carbon-13 isotopic composition of distillation fractions of some Egyptian crude oils

International Nuclear Information System (INIS)

Aly, A.I.M.; Hamza, M.S.; Abd Elsamie, S.G.

1991-01-01

13 C/ 13 C ratios were determined for some crude oil fields in the Gulf of Suez and Western Desert provinces. The crude oil was subjected to distillation at atmospheric pressure and subsequently under vacuum. Distillation fractions were collected at 25 degree C intervals. Carbon-13 content of these distillation fractions showed some differences in the degree of isotopic fractionation. The results were interpreted in view of the age of the source rocks and the degree of maturation process. The carbon-13 content of distillation fractions may be helpful in revealing petroleum mechanisms which can be exploited in exploration.4 fig

Tribological properties of magnet structural materials at cryogenic temperatures in vacuum

International Nuclear Information System (INIS)

Iwabuchi, Akira; Shimizu, Tomoharu; Yoshino, Yasuhiro; Iida, Shin-ichiro; Sugimoto, Makoto; Yoshida, Kiyoshi.

1994-01-01

Tribological properties of structural materials of a superconducting magnet for a nuclear fusion reactor were investigated at temperatures of 293 K, 77 K and about 5 K in vacuum. Specimen materials were JN1, JN2 and SUS316L steels, copper and its alloys, and GFRP. The properties of the coefficient of friction against the number of cycles were classified into two groups; smooth friction and fluctuating friction. The latter was caused by the strong adhesion dependent on the material combination and temperature. The coefficient of friction of the smooth friction was low less than 0.6. The upper coefficient of friction of fluctuating friction reaches more than 3. The temperature dependence of the coefficient of friction was also examined from 5 K to 130 K. Combinations of Cu-Cu and JN2-cupronickel showed high friction over the temperature, but JN1-Cu and JN2-Cu showed clear temperature dependence where the friction was high at temperatures between 45 K and 90 K. (author)

High current vacuum closing switch

International Nuclear Information System (INIS)

Dolgachev, G.I.; Maslennikov, D.D.; Romanov, A.S.; Ushakov, A.G.

2005-01-01

The paper proposes a powerful pulsed closing vacuum switch for high current commutation consisting of series of the vacuum diodes with near 1 mm gaps having closing time determined by the gaps shortening with the near-electrode plasmas [ru

Photoionization capable, extreme and vacuum ultraviolet emission in developing low temperature plasmas in air

NARCIS (Netherlands)

Stephens, J.; Fierro, A.; Beeson, S.; Laity, G.; Trienekens, D.; Joshi, R.P.; Dickens, J.; Neuber, A.

2016-01-01

Experimental observation of photoionization capable extreme ultraviolet and vacuum ultraviolet emission from nanosecond timescale, developing low temperature plasmas (i.e. streamer discharges) in atmospheric air is presented. Applying short high voltage pulses enabled the observation of the onset of

Anaesthetic effects of Adenia gummifera distillates on Apis mellifera (Honeybee).

Science.gov (United States)

Ngarivhume, T; Dzomba, P; Gwizangwe, I; Zendera, C H; Katsvanga, C A T; Jimu, L; Moyo, M; Chagonda, T

2008-01-01

The anaesthetic activities of steam distillates of Adenia gummifera stem on Apis mellifera were evaluated by a diffusion method. Live, direct and fractional (61-80 degrees C fraction) distillates had greater anaesthetic effect while vacuum distillates were mild. The anaesthetic activity significantly increased with concentration up to 6% (v/v), and then it levelled off, while excessive exposure was lethal. The number of bees in a given volume had no significant effect on anaesthetic activity but container volume (F(cal) = 66.4; F(3,8) = 4.07) and bee-distillate distance (F(cal) = 31.0; F(2,6) = 5.14) did, suggesting the rate of diffusion of active component could be the determining factor. The active component is likely to contain amines and the rest halogenated alkane.

Towards energy efficient distillation technologies – Making the right choice

International Nuclear Information System (INIS)

Kiss, Anton A.; Flores Landaeta, Servando J.; Infante Ferreira, Carlos A.

2012-01-01

In spite of claiming around half of the operational costs of chemical plants, distillation is still the most popular separation technology. Distillation has low thermodynamic efficiency, requiring the input of high quality energy in the reboiler – while rejecting a similar amount of heat at lower temperature, in the condenser. Several heat pump concepts have been proposed to upgrade that thermal energy and reduce the consumption of valuable utilities. Under certain conditions, the energy savings of heat pump assisted distillation is usually around 20–50%. This study proposes a novel selection scheme of energy efficient distillation technologies, with a special focus on heat pumps. The most promising technologies selected are vapor compression, mechanical or thermal vapor recompression, absorption, compression–resorption and thermo-acoustic heat pumps, multi-effect distillation, heat integrated distillation column, cyclic distillation, Kaibel and dividing-wall column. The scheme considers as the main selection criteria the type of separation tasks, product flow and specifications, operating pressure, difference in boiling points, reboiler duty and its temperature level. Moreover, this scheme is very practical, allowing major time and resources savings in the design of eco-efficient processes. -- Highlights: ► Heat pump assisted distillation with energy savings of 20–50%. ► Novel and practical selection scheme of energy efficient distillation technologies. ► Evaluation of promising technologies: VC, MVR, TVR, AHP, CHRP, TAHP, HIDiC, DWC, CyDist. ► Selection criteria include: ΔT b , ΔT lift , P, T reb , Q reb , volatility. ► Design of eco-efficient processes with high COP, and lower TIC and TAC.

Distilling shale and the like

Energy Technology Data Exchange (ETDEWEB)

Gee, H T.P.

1922-02-23

In distilling shale or like bituminous fuels by internal heating with hot gas obtained by the gasifying of the shale residues with air or steam or a mixture of these, the amount and temperature of the gaseous distilling medium is regulated between the gasifying and the distilling chambers, by the introduction of cold gas or air.

Vacuum-arc chromium coatings for Zr-1%Nb alloy protection against high-temperature oxidation in air

International Nuclear Information System (INIS)

Kuprin, A.S.; Belous, V.A.; Bryk, V.V.; Vasilenko, R.L.; Voevodin, V.N.; Ovcharenko, V.D.; Tolmacheva, G.N.; Kolodij, I.V.; Lunev, V.M.; Klimenko, I.O.

2015-01-01

The effect of vacuum-arc Cr coatings on the alloy E110 resistance to the oxidation in air at temperatures 1020 and 1100 deg C for 3600 s has been investigated. The methods of scanning electron microscope, X-ray analysis and nanoindentation were used to determine the thickness, phase, mechanical properties of coatings and oxide layers. The results show that the chromium coating can effectively protect fuel tubes against high-temperature oxidation in air for one hour. In the coating during oxidation at T = 1100 deg C a Cr 2 O 3 oxide layer of 5 μm thickness is formed preventing further oxygen penetration into the coating, and thus the tube shape is conserved. Under similar test conditions the oxidation of uncoated tubes with formation of a porous monocline oxide of ZrO 2 of a thickness more than ≥ 250 μm is observed, then the deformation and cracking of samples occur and the oxide layer breaks away

Improved simulation design factors for unconventional crude vacuum units : cracked gas make and stripping section performance

Energy Technology Data Exchange (ETDEWEB)

Remesat, D. [Koch-Glitsch Canada LP, Calgary, AB (Canada)

2008-10-15

Operating data for unconventional heavy oil vacuum crude units were reviewed in order to optimize the design of vacuum columns. Operational data from heavy crude vacuum units operating with stripping and velocity were used to investigate the application of a proven vacuum distillation tower simulation topology designed for use with heavy oil and bitumen upgrader feeds. Design factors included a characterization of the crude oils or bitumens processed in the facility; the selection of thermodynamic models; and the non-equilibrium simulation topology. Amounts of generated cracked gas were calculated, and entrainment and stripping section performance was evaluated. Heater designs for ensuring the even distribution of heat flux were discussed. Data sets from vacuum units processing crude oils demonstrated that the amount of offgas flow increased as the transfer line temperature increased. The resulting instability caused increased coke generation and light hydrocarbon formation. Results also indicated that overhead vacuum ejector design and size as well as heat transfer capabilities of quench and pumparound zones must be considered when designing vacuum column units. Steam stripping lowered hydrocarbon partial pressure to allow materials to boil at lower temperatures. It was concluded that setting appropriate entrainment values will ensure the accuracy of sensitivity analyses for transfer line designs, inlet feed devices, and wash bed configurations. 9 refs., figs.

High-temperature performance of the brazement of molybdenum single crystals

International Nuclear Information System (INIS)

Hirakoa, Y.

1992-01-01

Molybdenum is utilized in the fields of high-temperature vacuum industry, electrical and electronic industry, and chemical industries. For the wider application of this material, however, it is necessary to obtain a joining with good quality. In this investigation, high-temperature brazing of a single-crystalline molybdenum was performed. Then the bend properties of the brazement after a high-temperature annealing were evaluated. The single-crystalline molybdenum had been produced by the secondary recrystallization method. Brazing was performed in vacuum at 2273K using Mo-40Ru alloy powder as a brazing material. The brazement was investigated via optical microscopy, EPMA, Knoop hardness, and three point bending. In this paper the effects of annealing in hydrogen and vacuum are discussed

Steam Distillation with Induction Heating System: Analysis of Kaffir Lime Oil Compound and Production Yield at Various Temperatures

International Nuclear Information System (INIS)

Zuraida Muhammad; Zakiah Mohd Yusoff; Mohd Noor Nasriq Nordin

2013-01-01

The steam temperature during the extraction process has a great influence on the essential oil quality. .This study was conducted to analyze the compound of kaffir-lime oil during extracting at different steam temperature using GC-MS analysis. The extraction was carried out by using steam distillation based on induction heating system at different extraction temperature such as 90, 95 and 100 degree Celsius, the power of the induction heating system is fixed at 1.6 kW. Increment of the steam temperature will increase the oil yield. In terms of oil composition, extraction at lower temperature resulted high concentration for four marker compounds of kaffir-lime oil which are α-pinene, sabinene, limonene, β-pinene. (author)

Optimizing design parameter for light isotopes separation by distillation method

International Nuclear Information System (INIS)

Ahmadi, M.

1999-01-01

mentioned rules, pressure decrease, results in separation factor increase, and higher is separation factor in distillation process, lower is theoretical trays needed to do the separation. Therefore choice of optimum pressure (proper vacuum) and method of computing number of theoretical trays needed is very important. Required vacuum in the condenser of distillation apparat ous(including: condenser, tower and re boiler), is determined in such a way that outlet vapour from the tower could be condensed. In the other hand, proper vacuum is set by the temperature of coolant used. Common calculation methods to compute number of theoretical trays needed to separate constituent components of a solution, may be used by doing some modifications for isotopic separation via distillation process. Therefore to generalize common calculation methods for distillation to compute number of theoretical trays needed in a isotopic enrichment process, enrichment in ideal tray and other hydrodynamic specifications, it is first of all necessary to define isotopes as components. For obtaining equilibrium equations between hydrogen isotopes to apply for comp ting number of theoretical trays for isotopic enrichment through distillation process, firstly equilibrium equations between hydrogen isotopes in liquid phase is obtained base on reaction constant coefficient for these isotopes and then equilibrium equations in vapour phase are analysed base on ideal gas laws. By taking into consideration the separation factor, equations obtained for both phases are combined and finally the amount of hydrogen isotopes and separation factor are defined independently considering equilibrium equations in liquid and vapour phases. Therefore using mathematical method for both liquid and vapour phases of isotopes and common distillation method, number of theoretical trays are calculated and then profiting return equations presented, enrichment of isotopes for each theoretical tray may be calculated. To achieve know

Low Temperature Geothermal Resource Assessment for Membrane Distillation Desalination in the United States

Energy Technology Data Exchange (ETDEWEB)

Akar, Sertac; Turchi, Craig

2017-05-01

Substantial drought and declines in potable groundwater in the United States over the last decade has increased the demand for fresh water. Desalination of saline water such as brackish surface or groundwater, seawater, brines co-produced from oil and gas operations, industrial wastewater, blow-down water from power plant cooling towers, and agriculture drainage water can reduce the volume of water that requires disposal while providing a source of high-quality fresh water for industrial or commercial use. Membrane distillation (MD) is a developing technology that uses low-temperature thermal energy for desalination. Geothermal heat can be an ideal thermal-energy source for MD desalination technology, with a target range of $1/m3 to $2/m3 for desalinated water depending on the cost of heat. Three different cases were analyzed to estimate levelized cost of heat (LCOH) for integration of MD desalination technology with low-grade geothermal heat: (1) residual heat from injection brine at a geothermal power plant, (2) heat from existing underutilized low-temperature wells, and (3) drilling new wells for low-temperature resources. The Central and Western United States have important low-temperature (<90 degrees C) geothermal resource potential with wide geographic distribution, but these resources are highly underutilized because they are inefficient for power production. According to the USGS, there are 1,075 identified low temperature hydrothermal systems, 55 low temperature sedimentary systems and 248 identified medium to high temperature geothermal systems in the United States. The estimated total beneficial heat potential from identified low temperature hydrothermal geothermal systems and residual beneficial heat from medium to high temperature systems is estimated as 36,300 MWth, which could theoretically produce 1.4 to 7 million m3/day of potable water, depending on desalination efficiency.

Study of the Formation of Eutectic Melt of Uranium and Thermal Analysis for the Salt Distillation of Uranium Deposits

International Nuclear Information System (INIS)

Park, Sung Bin; Hwang, Sung Chan; Kang, Young Ho; Park, Ki Min; Jun, Wan Gi; Lee, Han Soo; Cho, Dong Wook

2010-01-01

Uranium deposits from an electrorefining process contain about 30% salt. In order to recover pure uranium and transform it into an ingot, the salts have to be removed from the uranium deposits. Major process variables for the salt distillation process of the uranium deposits are hold temperature and vacuum pressure. Effects of the variables on the salt removal efficiency were studied in the previous study 1. By applying the Hertz-Langmuir relation to the salt evaporation of the uranium deposits, the evaporation coefficients were obtained at the various conditions. The operational conditions for achieving above 99% salt removal were deduced. The salt distilled uranium deposits tend to form the eutectic melt with iron, nickel, chromium for structural material of salt evaporator. In this study, we investigated the hold temperature limitation in order to prevent the formation of the eutectic melt between uranium and other metals. The reactions between the uranium metal and stainless steel were tested at various conditions. And for enhancing the evaporation rate of the salt and the efficient recovery of the distilled salt, the thermal analysis of the salt distiller was conducted by using commercial CFX software. From the thermal analysis, the effect of Ar gas flow on the evaporation of the salt was studied.

Vacuum-sintered body of a novel apatite for artificial bone

Science.gov (United States)

Tamura, Kenichi; Fujita, Tatsushi; Morisaki, Yuriko

2013-12-01

We produced regenerative artificial bone material and bone parts using vacuum-sintered bodies of a novel apatite called "Titanium medical apatite (TMA®)" for biomedical applications. TMA was formed by chemically connecting a Ti oxide molecule with the reactive [Ca10(PO4)6] group of Hydroxyapatite (HAp). The TMA powders were kneaded with distilled water, and solid cylinders of compacted TMA were made by compression molding at 10 MPa using a stainless-steel vessel. The TMA compacts were dried and then sintered in vacuum (about 10-3 Pa) or in air using a resistance heating furnace in the temperature range 1073-1773 K. TMA compacts were sintered at temperatures greater than 1073 K, thus resulting in recrystallization. The TMA compact bodies sintered in the range 1273-1773 K were converted into mixtures composed of three crystalline materials: α-TCP (tricalcium phosphate), β-TCP, and Perovskite-CaTiO3. The Perovskite crystals were stable and hard. In vacuum-sintering, the Perovskite crystals were transformed into fibers (approximately 1 µm in diameter × 8 µm in length), and the fiber distribution was uniform in various directions. We refer to the TMA vacuum-sintered bodies as a "reinforced composite material with Perovskite crystal fibers." However, in atmospheric sintering, the Perovskite crystals were of various sizes and were irregularly distributed as a result of the effect of oxygen. After sintering temperature at 1573 K, the following results were obtained: the obtained TMA vacuum-sintered bodies (1) were white, (2) had a density of approximately 2300 kg/m3 (corresponding to that of a compact bone or a tooth), and had a thermal conductivity of approximately 31.3 W/(m·K) (corresponding to those of metal or ceramic implants). Further, it was possible to cut the TMA bodies into various forms with a cutting machine. An implant made of TMA and inserted into a rabbit jaw bone was covered by new bone tissues after just one month because of the high

Development of a vacuum superinsulation panel

Energy Technology Data Exchange (ETDEWEB)

Timm, H; Seefeldt, D; Nitze, C

1983-05-01

After completion of the investigations the vacuum-insulated panel is available as prototype. The aim of the investigations was to optimize and to finalize the vacuum superinsulation system with regard to a pressure-resistant, temperature-resistant thermal insulation of high efficiency. In this connection, particularly investigations with regard to vacuum-tight sealing, compression and evacuation of powder filling as well as special material investigations were performed. The application-specific utilization of the vacuum-insulated panel and the adjustment to special operational conditions can now be started. Application possibilities are at present seen in coverings or linings with high temperature and/or pressure requirements.

Development of fast heating electron beam annealing setup for ultra high vacuum chamber

Energy Technology Data Exchange (ETDEWEB)

Das, Sadhan Chandra [UGC-DAE Consortium For Scientific Research, University Campus, Khandwa Road, Indore 452 001, MP (India); School of Electronics, Devi Ahilya University, Indore 452001, MP (India); Institute of Physics, University of Greifswald, Felix Hausdroff Str. 6 (Germany); Majumdar, Abhijit, E-mail: majuabhijit@gmail.com, E-mail: majumdar@uni-greifswald.de; Hippler, R. [Institute of Physics, University of Greifswald, Felix Hausdroff Str. 6 (Germany); Katiyal, Sumant [School of Electronics, Devi Ahilya University, Indore 452001, MP (India); Shripathi, T. [UGC-DAE Consortium For Scientific Research, University Campus, Khandwa Road, Indore 452 001, MP (India)

2014-02-15

We report the design and development of a simple, electrically low powered and fast heating versatile electron beam annealing setup (up to 1000 °C) working with ultra high vacuum (UHV) chamber for annealing thin films and multilayer structures. The important features of the system are constant temperature control in UHV conditions for the temperature range from room temperature to 1000 ºC with sufficient power of 330 W, at constant vacuum during annealing treatment. It takes approximately 6 min to reach 1000 °C from room temperature (∼10{sup −6} mbar) and 45 min to cool down without any extra cooling. The annealing setup consists of a UHV chamber, sample holder, heating arrangement mounted on suitable UHV electrical feed-through and electronic control and feedback systems to control the temperature within ±1 ºC of set value. The outside of the vacuum chamber is cooled by cold air of 20 °C of air conditioning machine used for the laboratory, so that chamber temperature does not go beyond 50 °C when target temperature is maximum. The probability of surface oxidation or surface contamination during annealing is examined by means of x-ray photoelectron spectroscopy of virgin Cu sample annealed at 1000 °C.

Development of fast heating electron beam annealing setup for ultra high vacuum chamber

International Nuclear Information System (INIS)

Das, Sadhan Chandra; Majumdar, Abhijit; Hippler, R.; Katiyal, Sumant; Shripathi, T.

2014-01-01

We report the design and development of a simple, electrically low powered and fast heating versatile electron beam annealing setup (up to 1000 °C) working with ultra high vacuum (UHV) chamber for annealing thin films and multilayer structures. The important features of the system are constant temperature control in UHV conditions for the temperature range from room temperature to 1000 ºC with sufficient power of 330 W, at constant vacuum during annealing treatment. It takes approximately 6 min to reach 1000 °C from room temperature (∼10 −6 mbar) and 45 min to cool down without any extra cooling. The annealing setup consists of a UHV chamber, sample holder, heating arrangement mounted on suitable UHV electrical feed-through and electronic control and feedback systems to control the temperature within ±1 ºC of set value. The outside of the vacuum chamber is cooled by cold air of 20 °C of air conditioning machine used for the laboratory, so that chamber temperature does not go beyond 50 °C when target temperature is maximum. The probability of surface oxidation or surface contamination during annealing is examined by means of x-ray photoelectron spectroscopy of virgin Cu sample annealed at 1000 °C

Influence of essential oil fractionation by vacuum distillation on acaricidal activity against the cattle tick

Directory of Open Access Journals (Sweden)

Fernando Cidade Torres

2012-08-01

Full Text Available The aim of this work was to study the influence of essential oil fractionation on acaricidal activity against the cattle tick Rhipicephalus (Boophilus microplus. The citronella (Cymbopogon winterianus J. and pepper tree (Schinus molle L. essential oils were fractionated by vacuum distillation yielding fractions that were analyzed by the GC/MS. Laboratory tests were carried out to determine the effect of the total essential oil and fractions on larvae of the cattle tick R. (B. microplus. The fractions 04 and 05 of the C. winterianus essential oil were the most active showing LC50 values of 1.20 and 1.34 μL/mL, respectively. The LC50 of the total oil was 3.30 μL/mL while the effect of the fractions 01, 02 and 03 was less pronounced, with LC50 values of 4.37, 4.24 and 3.49 μL/mL, respectively. The fraction 03 of the S. molle essential oil was the most active showing LC50 value of 8.80 μL/mL while the fractions 01 and 02 did not show toxic effects on the larvae.

Batch extractive distillation for high purity methanol

International Nuclear Information System (INIS)

Zhang Weijiang; Ma Sisi

2006-01-01

In this paper, the application in chemical industry and microelectronic industry, market status and the present situation of production of high purity methanol at home and abroad were introduced firstly. Purification of industrial methanol for high purity methanol is feasible in china. Batch extractive distillation is the best separation technique for purification of industrial methanol. Dimethyl sulfoxide was better as an extractant. (authors)

Innovative Design of Solar-Powered Desalination (SPD System using Vacuum-Multi Effect Membrane Distillation (V-MEMD Process

Directory of Open Access Journals (Sweden)

Chafidz Achmad

2018-01-01

Full Text Available This research focused on the development of an innovative design of solar-powered desalination (SPD system which was expected to solve the water and energy problem simultaneously. We have developed a portable and hybrid solar-powered desalination (SPD system for producing potable water from saline water. It is a self-contained and integrated system which combines solar-thermal collector and solar-photovoltaic for its operation, and thus the system can operate to produce water by only using solar energy. Therefore, the system is highly suitable to be implemented in remote arid and coastal areas without infrastructures or connection to the grid (water and power, but blessed with abundant solar irradiation, like in Saudi Arabia. A Memsys Vacuum Multi-Effect Membrane Distillation (V-MEMD unit was used as the core of the SPD system. A heat pump was also integrated into the SPD system for energy recovery and to improve the performance of the system. The system could be considered as sustainable and “green” desalination technology, which will be very useful for the Kingdom of Saudi Arabia. To study the performance of the system, small-scale tests have been carried out at the Engineering College - King Saud University, Saudi Arabia. Based on the experimental results, the system has run successfully by only utilizing solar energy.

The features of ultrapurification of cadium by distillation method

International Nuclear Information System (INIS)

Kozin, L.F.; Berezhnoj, E.O.; Kozin, K.L.

1996-01-01

The linear dependence of the coefficients of interphase distribution of liquid-vapour is found in the systems cadmium-accompanying impurities upon the evaporation enthalpy. The values of α are calculated for 52 accompanying impurities. The vacuum distillation of cadmium at different experimental conditions. It is shown that during distillation of cadmium at the optimum conditions the content of 14 accompanying impurities is 1.78x10 -7 mass. %, and the assumed content of the main metal is 8N8 of cadmium. The total separation coefficient is 2.1x10 4

Determination of 129I using distillation method and liquid scintillation spectrometry

International Nuclear Information System (INIS)

Horvathova, B.; Dulanska, S.; Remenec, B.; Matel, L.; Gardonova, V.

2014-01-01

The conditions for effective distillation of iodine as a screening method for the determination of 129 I by liquid scintillation spectrometry were optimized. By distillation of iodine it is possible to achieve high-purity fraction without interferences needed for measuring 129 I for liquid scintillation spectrometer. Yields of separation were determined gravimetrically using PdI 2 ·H 2 O. The environment that was found to be effective for distillation of iodine is made up of 1 - 2 mol dm -3 HNO 3 together with 0.4 g of NaNO 2 as an oxidizing agent (I . →I 2 ). For testing of distillation, suitable apparatus for distillation of iodine was designed. The apparatus was connected to a vacuum box, which sucks iodine of the distilled solution. Then the iodine was captured in a solution of NaOH at a concentration of 1.5 mol dm -3 . As part of the optimization methodology, it was found that the concentration of NaOH solution for adsorption I 2 (g) does not have any influence on the yields, as opposed to its volume, where it is necessary to use a maximum amount of NaOH in the holding flask for maximum adsorption of iodine. It was determined, that time needed for coagulation PdI 2 ·H 2 O is 24 hours and suitable time for distillation was 20 minutes. Optimized method for the determination of 129 I was applied for various matrices from NPPs in Slovak Republic. Values of 129 I for all analyzed samples were less than the minimum detectable activity (0.043 Bq). The separation yields were in the range (73.14 to 82.04)% and 129 I was measured on a liquid scintillation spectrometer TRI CARB 2900TR with high detection efficiency of 95%. (authors)

Stability time of a DT-filled cryogenic ICF target in a high vacuum environment

International Nuclear Information System (INIS)

Ebey, P.S.; Hoffer, J.K.

1998-01-01

Following the successful pressure loading with DT of a thin-walled plastic inertial fusion target shell (such as those designed for use at the OMEGA facility at the University of Rochester's Laboratory for Laser Energetics (UR/LLE)), continual care must be taken to safeguard the shell from being exposed to unacceptable pressure differentials across its wall. In particular, once the DT has been condensed into a liquid or solid phase and the outside pressure has been reduced, the target must be maintained below some upper cutoff temperature such that the vapor pressure of the DT is below the bursting pressure for the shell. Through the process of β-decay the DT self-heats, but while the shell is in a high vacuum environment (P much-lt 0.8 Pa (6 mtorr) for the OMEGA layering sphere) there is only a negligible heat loss mechanism. This will cause the temperature to increase. A calculation has been done to estimate the rate of temperature increase of the loaded target under high vacuum conditions. A functional form for calculating the target's temperature increase given its starting temperature is presented. An overall result is that under high vacuum conditions the DT changes from a solid at 10 K to a liquid at 37 K (T c = 39.4 K) in about 19 minutes. This holding time is significantly less if the initial temperature is higher, the initial state is liquid, or the upper allowed temperature is lower. Simplifying assumptions which were made and their impact on interpreting the results of this calculation are discussed

Fracture peculiarities in ceramic tungsten at different temperatures in vacuum

International Nuclear Information System (INIS)

Uskov, E.I.; Babak, A.V.

1981-01-01

Stress-strain diagrams and results of metallographic analyses are presented for the ceramic tungsten samples tested for fracture toughness under conditions of eccentric tension at different temperatures (20...1600 deg C) in vacuum. The tungsten fracture is shown to be of brittle nature within the whole temperature range studied, but the fracture process has its own peculiarities at different test temperatures

High temperature electronic gain device

International Nuclear Information System (INIS)

McCormick, J.B.; Depp, S.W.; Hamilton, D.J.; Kerwin, W.J.

1979-01-01

An integrated thermionic device suitable for use in high temperature, high radiation environments is described. Cathode and control electrodes are deposited on a first substrate facing an anode on a second substrate. The substrates are sealed to a refractory wall and evacuated to form an integrated triode vacuum tube

Commissioning and operation of distillation column at Madras Atomic Power Station (Paper No. 1.10)

International Nuclear Information System (INIS)

Neelakrishnan, G.; Subramanian, N.

1992-01-01

In Madras Atomic Power Station (MAPS), an upgrading plant based on vacuum distillation was constructed to upgrade the downgraded heavy water collected in vapor recovery dryers. There are two distillation columns and each having a capacity of 77.5 tonne per annum of reactor grade heavy water with average feed concentration of 30% IP. The performance of the distillation columns has been very good. The column I and column II have achieved an operating factor of 92% and 90% respectively. The commissioning activities, and subsequent improvements carried out in the distillation columns are described. (author)

Hydrothermal Liquefaction of Dried Distillers Grains with solubles: A reaction temperature study

DEFF Research Database (Denmark)

Mørup, Anders; Christensen, Per Runge; Aarup, David Friis

2012-01-01

provides rapid heating of biomass feeds and the option of performing multiple sequential repetitions. This bypasses long, uncontrollable temperature gradients and unintended changes in the reaction chemistry. The product, a crude bio-oil, was characterized in terms of yield, elemental composition......The effect of the reaction temperature on hydrothermal liquefaction of dried distillers grains with solubles (DDGS) was investigated using a novel stop-flow reactor system at varying temperatures (300–400 °C), fixed pressure (250 bar), and fixed reaction time (15 min). The stop-flow reactor......, and chemical composition. Higher reaction temperatures resulted in improved bio-oil yields, less char formation, and higher heating values of the bio-oil. A supercritical reaction temperature of 400 °C was found to produce bio-oil in the highest yields and of the best quality....

Jets with ALICE: from vacuum to high-temperature QCD

CERN Multimedia

CERN. Geneva

2014-01-01

ALICE measures jets in pp, p-Pb and Pb-Pb collisions to study modifications of the jet fragmentation due to cold nuclear and hot QCD matter. In pp collisions ALICE has measured inclusive jet yields, the ratio of yields with different resolution R, a variety of jet shapes and the semi-inclusive rate of jets recoiling against a high transverse momentum hadron trigger. These measurements are compared to NLO calculations including hadronization corrections and to MC models. Jets in pp are primarily conceived as a vacuum reference for jet observables in p-Pb and Pb-Pb collisions. In p-Pb collisions ALICE explores cold nuclear matter effects on jet yields, jet fragmentation and dijet acoplanarity. The hot and dense medium created in heavy-ion collisions is expected to modify the fragmentation of high energy partonic projectiles leading to changes in the energy and structure of the reconstructed jets with respect to pp jets. The study of modified jets aims at understanding the detailed mechanisms of in-medium energy...

Fusion blanket high-temperature heat transfer

International Nuclear Information System (INIS)

Fillo, J.A.

1983-01-01

Deep penetration of 14 MeV neutrons makes two-temperature region blankets feasible. A relatively low-temperature (approx. 300 0 C) metallic structure is the vacuum/coolant pressure boundary, while the interior of the blanket, which is a simple packed bed of nonstructural material, operates at very high temperatures (>1000 0 C). The water-cooled shell structure is thermally insulated from the steam-cooled interior. High-temperature steam can dramatically increase the efficiency of electric power generation, as well as produce hydrogen and oxygen-based synthetic fuels at high-efficiency

ITER articulated inspection arm (AIA): R and D progress on vacuum and temperature technology for remote handling

Energy Technology Data Exchange (ETDEWEB)

Perrot, Y.; Friconneau, J.P. [Robotics and Interactive Systems Unit - CEA/LIST, 92 - Fontenay aux Roses (France); Cordier, J.J.; Gargiulo, L. [Association Euratom-CEA, Centre d' Etudes de Cadarache, 13 - Saint-Paul-lez-Durance (France). Dept. de Recherches sur la Fusion Controlee; Palmer, J.D. [EFDA CSU Garching (Germany); Martin, E. [ITER International Team, Garching (Germany); Tesini, A. [ITER International Team, ITER Naka Joint Work Site, Iberaki-ken (Japan)

2004-07-01

To perform an intervention a short time after plasma shutdown, the operation of the robot will have to be under ITER conditions which means: under high vacuum, pollution avoidance and a temperature ambience around 120 C. The feasibility studies have led to the design of a robot in the shape of a 8.2 meter long articulated arm made up of 5 modules with 11 articulated joints. A single module prototype has been manufactured to be tested. The prototype was set up in a specific vacuum vessel at Tore-Supra facility that can be baked up to 230 C under high-vacuum conditions. The first tests have shown that: -) the efficiency of the actuators at 120 C was the same than in air at room temperature, the speed was slightly lower, -) the monitoring of the temperature of the motor and of the power electronics components showed an increasing of only 40 C during 3 full pitch movements, and -) most of the greases was degassed during the 1 week long baking at 200 C except one which comes from an organic material in a component that has to be identified.

ITER articulated inspection arm (AIA): R and D progress on vacuum and temperature technology for remote handling

International Nuclear Information System (INIS)

Perrot, Y.; Friconneau, J.P.; Cordier, J.J.; Gargiulo, L.; Martin, E.; Tesini, A.

2004-01-01

To perform an intervention a short time after plasma shutdown, the operation of the robot will have to be under ITER conditions which means: under high vacuum, pollution avoidance and a temperature ambience around 120 C. The feasibility studies have led to the design of a robot in the shape of a 8.2 meter long articulated arm made up of 5 modules with 11 articulated joints. A single module prototype has been manufactured to be tested. The prototype was set up in a specific vacuum vessel at Tore-Supra facility that can be baked up to 230 C under high-vacuum conditions. The first tests have shown that: -) the efficiency of the actuators at 120 C was the same than in air at room temperature, the speed was slightly lower, -) the monitoring of the temperature of the motor and of the power electronics components showed an increasing of only 40 C during 3 full pitch movements, and -) most of the greases was degassed during the 1 week long baking at 200 C except one which comes from an organic material in a component that has to be identified

Distillation, destructive

Energy Technology Data Exchange (ETDEWEB)

Newton, A V

1856-04-22

In order to obtain, at the first distillation, from coal, shale, and bituminous substances an oil sufficiently pure for illuminating and other purposes, the material broken into very small pieces and placed on the bottom of the retort, is evenly covered with common sand, about four times greater in weight than the weight of the coal. The coal and sand are then gradually raised to a temperature of 212/sup 0/F. Steam containing carbonaceous impurities first passes to the condenser, and subsequently oil, which rises to the surface of the water in the receiving-vessel. When some bituminous substances are employed, the temperature, after oil ceases to come over, may be gradually raised until the oil produced ceases to be pure. Most kinds of clay and earth, chalk, gypsum, black oxide of manganese, plumbago, or charcoal may be used separately, in combination, or with added chemicals, instead of sand as the medium for filtering the gas or vapor from which the oil is formed. Either the oil obtained by the first distillation or oils obtained by other means may be rectified by distilling with sand.

Destructive distillation

Energy Technology Data Exchange (ETDEWEB)

Nielsen, H; Laing, B

1927-12-23

Oil bearing solids such as coal, tar sands, oil shales, or the like, are distilled in a current of hot gas and are first preheated to a temperature above that at which the heaviest oil fractions in the vapors are liable to condense, for example 100 to 250/sup 0/C, according to the volume of gas passing through the retort, temperature being in inverse proportion to the quantity of oxygen containing constituents in the charge. When the distillation takes place in a controlled volume of hot inert gas of 45,000 cubic feet per ton and the volume of oil recovered is about 20 gallons per ton, the material is preheated to 200 to 250/sup 0/C, when the volume of gas used is 100,000 cubic feet the preheating temperature is 150/sup 0/C. The temperatures of the retort dust extractor etc. do not fall below 100 to 150/sup 0/C until actual condensation of the oil vapor is desired. Specification 287,381 is referred to, and Specification 287,037 also is referred to in the Provisional Specification.

THE EFFECT OF DISTILLATE STORING DISTILLED FROM FRUCTOSE SYRUPS TOWARD ITS ACETALDEHYDE CONCENTRATION MEASURED BY GAS CHROMATOGRAPHY

Directory of Open Access Journals (Sweden)

Maria Monica Sianita Basukiwardojo

2010-06-01

Full Text Available Acetaldehyde is a compound of aldehyde group that is very volatile and toxic. This compound can be found in fructose syrups used in carbonate beverages. The syrups had been distilled then analysed using gas chromatography. The concentration of acetaldehyde was 289.78 g/g in the distillates kept for one week, 295.30 g/g in those kept for two weeks, 429.45 g/g in those kept for three weeks, and 449.38 g/g in those kept for four weeks. The optimum column temperature was programmed with initial temperature of 40 oC held on for four minutes, then increasing by 40 oC/minute to 200 oC. It can be concluded that the longer the distillates have been kept, the greater the concentration of acetaldehyde in the distillates. A further research to investigate the present of microbe in the distillates and the effect of pH should be conducted   Keywords: acetaldehyde, fructose syrup, distillates, gas chromatography.

Bubble point measurement and high pressure distillation column design for the environmentally benign separation of zirconium from hafnium for nuclear power reactor

International Nuclear Information System (INIS)

Minh, Le Quang; Kim, Gyeongmin; Lee, Moonyong; Park, Jongki

2015-01-01

We examined the feasible separation of ZrCl 4 and HfCl 4 through high pressure distillation as environmentally benign separation for structural material of nuclear power reactor. The bubble point pressures of ZrCl 4 and HfCl 4 mixtures were determined experimentally by using an invariable volume equilibrium cell at high pressure and temperature condition range of 2.3-5..6MPa and 440-490 .deg. C. The experimental bubble point pressure data were correlated with Peng-Robinson equation of state with a good agreement. Based on the vapor-liquid equilibrium properties evaluated from the experimental data, the feasibility of high pressure distillation process for the separation of ZrCl 4 and HfCl 4 was investigated with its main design condition through rigorous simulation using a commercial process simulator, ASPEN Hysys. An enhanced distillation configuration was also proposed to improve energy efficiency in the distillation process. The result showed that a heat-pump assisted distillation with a partial bottom flash could be a promising option for commercial separation of ZrCl 4 and HfCl 4 by taking into account of both energy and environmental advantages

Electron beam gun with kinematic coupling for high power RF vacuum devices

Science.gov (United States)

Borchard, Philipp

2016-11-22

An electron beam gun for a high power RF vacuum device has components joined by a fixed kinematic coupling to provide both precise alignment and high voltage electrical insulation of the components. The kinematic coupling has high strength ceramic elements directly bonded to one or more non-ductile rigid metal components using a high temperature active metal brazing alloy. The ceramic elements have a convex surface that mates with concave grooves in another one of the components. The kinematic coupling, for example, may join a cathode assembly and/or a beam shaping focus electrode to a gun stem, which is preferably composed of ceramic. The electron beam gun may be part of a high power RF vacuum device such as, for example, a gyrotron, klystron, or magnetron.

Process of treating carbonaceous materials. [400 to 700/sup 0/C, high vacuum

Energy Technology Data Exchange (ETDEWEB)

Parker, O J

1913-11-24

A process is given of treating carbonaceous materials, characterized by the material being submitted simultaneously to a temperature of 400 to 700/sup 0/C, a pressure between 5.0 mm of mercury under atmospheric and a practically perfect vacuum, and by the volatile material able to condense under the vacuum used being condensed practically under the same pressure for the production of a high proportion of condensable products and a superior fuel.

Influence of high temperature and ethanol on thermostable lignocellulolytic enzymes

DEFF Research Database (Denmark)

Skovgaard, Pernille Anastasia; Jørgensen, Henning

2013-01-01

the influence of temperature and ethanol on enzyme activity and stability in the distillation step, where most enzymes are inactivated due to high temperatures. Two enzyme mixtures, a mesophilic and a thermostable mixture, were exposed to typical process conditions [temperatures from 55 to 65 °C and up to 5...... % ethanol (w/v)] followed by specific enzyme activity analyses and SDS-PAGE. The thermostable and mesophilic mixture remained active at up to 65 and 55 °C, respectively. When the enzyme mixtures reached their maximum temperature limit, ethanol had a remarkable influence on enzyme activity, e.g., the more...... ethanol, the faster the inactivation. The reason could be the hydrophobic interaction of ethanol on the tertiary structure of the enzyme protein. The thermostable mixture was more tolerant to temperature and ethanol and could therefore be a potential candidate for recycling after distillation....

Silicates materials of high vacuum technology

CERN Document Server

Espe, Werner

2013-01-01

Materials of High Vacuum Technology, Volume 2: Silicates covers silicate insulators of special importance to vacuum technology. The book discusses the manufacture, composition, and physical and chemical properties of technical glasses, quartz glass, quartzware, vycor glass, ceramic materials, mica, and asbestos.

Fundamentals of a moderate thermocracking-deep deasphalting combined process of Karamay vacuum residue

Energy Technology Data Exchange (ETDEWEB)

Zhiming, X; Tonghua, L.; Suogi, Z.; Renan, W. [University of Petroleum, State Key Laboratory of Heavy Oil Processing, Beijing (China); Lailong, L.; Zhen, L. [Karamay Petrochemical Company, Petrochemical Research Institute, Karamay (China)

2004-07-01

Thermocracking of heavy oil vacuum residue was carried out to determine the optimum conditions for the thermal cracking of Karamay vacuum residue prior to coke formation. The vacuum residue and the cracked residue after distillation were separated using supercritical fluid extraction and fractionation techniques. Sixteen and thirteen fractions and non-extractable end cuts respectively were separated, and their properties, compositions and average structures determined. Solubility parameters of the end cuts were measured, and those of the fractions calculated. The solubility parameter of the end cut of distilled residue was found to have greatly increased. It was determined that when the difference of the end cut and the extractable fractions amounts to 6.37MPa1/2, in the case of Karamay vacuum residue coke will deposit under thermocracking conditions. Based on the results of a series of solvent deep deasphalting experiments, a scheme for vacuum residue thermocracking and deasphalting of the cracked residue was proposed.

A High Rated Solar Water Distillation Unit for Solar Homes

Directory of Open Access Journals (Sweden)

Abhishek Saxena

2016-01-01

Full Text Available India is presently focusing on complete utilization of solar energy and saving fossil fuels, which are limited. Various solar energy systems like solar cookers, solar water heaters, solar lanterns, solar PV lights, and solar lamps are continuously availing by the people of India at a low cost and on good subsidies. Apart from this, India is a solar energy promising country with a good number of solar homes (carrying solar energy systems in its various locations. The present paper focuses on a unique combination of solar dish cooker (SDC and solar water heater (SWH to produce distilled water with a high distillate and a high daily productivity. The procedure has been discussed on the basis of experimental testing to produce distilled water by combining an evacuated type SWH and a SDC. Experimentation has been carried out in MIT, Moradabad (longitude, 28.83°N, and latitude, 78.78°E by developing the same experimental setup on behalf of solar homes. The daily productivity of distilled water was found around 3.66 litres per day in full sunshine hours for an approximated pH value of 7.7 and a ppm value of 21. The payback period (PBP has been estimated around 1.16 years of the present system.

Low Temperature Geothermal Resource Assessment for Membrane Distillation Desalination in the United States: Preprint

Energy Technology Data Exchange (ETDEWEB)

Akar, Sertac; Turchi, Craig

2016-10-01

Substantial drought and declines in potable groundwater in the United States over the last decade has increased the demand for fresh water. Desalination of saline water such as brackish surface or groundwater, seawater, brines co-produced from oil and gas operations, industrial wastewater, blow-down water from power plant cooling towers, and agriculture drainage water can reduce the volume of water that requires disposal while providing a source of high-quality fresh water for industrial or commercial use. Membrane distillation (MD) is a developing technology that uses low-temperature thermal energy for desalination. Geothermal heat can be an ideal thermal-energy source for MD desalination technology, with a target range of $1/m3 to $2/m3 for desalinated water depending on the cost of heat. Three different cases were analyzed to estimate levelized cost of heat (LCOH) for integration of MD desalination technology with low-grade geothermal heat: (1) residual heat from injection brine at a geothermal power plant, (2) heat from existing underutilized low-temperature wells, and (3) drilling new wells for low-temperature resources. The Central and Western United States have important low-temperature (<90 degrees C) geothermal resource potential with wide geographic distribution, but these resources are highly underutilized because they are inefficient for power production. According to the USGS, there are 1,075 identified low temperature hydrothermal systems, 55 low temperature sedimentary systems and 248 identified medium to high temperature geothermal systems in the United States. The estimated total beneficial heat potential from identified low temperature hydrothermal geothermal systems and residual beneficial heat from medium to high temperature systems is estimated as 36,300 MWth, which could theoretically produce 1.4 to 7 million m3/day of potable water, depending on desalination efficiency.

Development of an inspection robot under iter relevant vacuum and temperature conditions

Energy Technology Data Exchange (ETDEWEB)

Hatchressian, J-C; Bruno, V; Gargiulo, L; Bayetti, P; Cordier, J-J; Samaille, F [Association Euratom-CEA, DSM/Departement de Recherche sur la Fusion Controlee, CEA Cadarache, F-13108 Saint Paul-Lez-Durance Cedex (France); Keller, D; Perrot, Y; Friconneau, J-P [CEA, LIST, Service de Robotique Interactive, 18 route du Panorama, BP6, Fontenay aux Roses F-92265 France (France); Palmer, J D [EFDA-CSU Max-Planck-Institut fuer Plasma Physik Boltzmannstr.2, D-85748 Garching Germany (Germany)

2008-03-15

Robotic operations are one of the major maintenance challenges for ITER and future fusion reactors. In vessel inspection operations without loss of conditioning could be very mandatory. Within this framework, the aim of the Articulated Inspection Arm (AIA) project is to demonstrate the feasibility of a multi-purpose in-vessel Remote Handling inspection system. It is a long reach, composed of 5 segments with in all 8 degrees of freedom, limited payload carrier (up to 10kg) and a total range of 8m. The project is currently developed by the CEA within the European work program. Some tests will validate chosen concepts for operations under ITER relevant vacuum and temperature conditions. The presence of magnetic fields, radiation and neutron beams will not be considered. This paper deals with the choices of the materials to minimize the out-gassing under vacuum and high temperature during conditioning, the implantation of the electronics which are enclosed in boxes with special gaskets, the design of the first embedded process which is a viewing system.

Distilling coal

Energy Technology Data Exchange (ETDEWEB)

Blythe, F C

1914-09-14

In the destructive distillation of bituminous coal, heavy hydrocarbon oil, such as petroleum, kerosine, shale oil, and heavy tar oil, obtained in some cases during the process, is added to the coal, which is then distilled under pressure and at a comparatively low temperature regulated so as to produce a large proportion of hydrocarbon oils and a small proportion of permanent gas. In one method, about 5 to 10 parts of hydrocarbon oil are mixed with 100 parts of crushed or ground coal, and the mixture is heated in a closed vessel, provided in some cases with an agitator, under a pressure of about 60 lb/in/sup 2/, and the temperature may be gradually raised to 350/sup 0/C and then to about 500/sup 0/C. The heating may be by means of superheated steam with or without external heat.

TNO experience on sodium cleaning of large plant components by vacuum distillation

Energy Technology Data Exchange (ETDEWEB)

Smit, C Ch [MT-TNO Dept. 50-MW Sodium Component Test Facility, Hengelo (Netherlands)

1978-08-01

The Intermediate Heat Exchanger and Steam generators developed within the framework of the SNR-programme are being tested in the 50 MW Test facility at Hengelo - The Netherlands. The facility was designed and built by Neratoom, and is operated by TNO, the Dutch Organisation for Applied Scientific Research. Sodium technology work, such as reported in this paper, is done in close cooperation with Neratoom and with TNO-laboratories at Apeldoorn, where several smaller sodium rigs and other facilities are available. The operation and maintenance of a large sodium test facility and sodium rigs lead to frequent cleaning of small plant components, test sections and sampling devices. The choice of method usually depends on the size of the component and the cleaning quality needed. The results are predictable and satisfactory. For large components, however, the situation is different. Although the basic cleaning methods using alcohol and moist gas are well-known, and procedures for the cleaning of small components are available, complete cleaning of tight crevices and threaded bolds cannot be guaranteed, and consequently the requalification procedure needs to include a complete disassembly and inspection of the cleaned component. For large components this policy cannot always be followed. In those cases for instance where an in-between internal inspection is required, or where only small modifications of the test object are necessary, other possibilities have to be considered. For this reason some work has been done to develop reliable vacuum distillation procedures for large components, based on the cleaning experience with small plant components. The results of these procedures applied to large plant components are reported in this paper.

TNO experience on sodium cleaning of large plant components by vacuum distillation

International Nuclear Information System (INIS)

Smit, C.Ch.

1978-01-01

The Intermediate Heat Exchanger and Steam generators developed within the framework of the SNR-programme are being tested in the 50 MW Test facility at Hengelo - The Netherlands. The facility was designed and built by Neratoom, and is operated by TNO, the Dutch Organisation for Applied Scientific Research. Sodium technology work, such as reported in this paper, is done in close cooperation with Neratoom and with TNO-laboratories at Apeldoorn, where several smaller sodium rigs and other facilities are available. The operation and maintenance of a large sodium test facility and sodium rigs lead to frequent cleaning of small plant components, test sections and sampling devices. The choice of method usually depends on the size of the component and the cleaning quality needed. The results are predictable and satisfactory. For large components, however, the situation is different. Although the basic cleaning methods using alcohol and moist gas are well-known, and procedures for the cleaning of small components are available, complete cleaning of tight crevices and threaded bolds cannot be guaranteed, and consequently the requalification procedure needs to include a complete disassembly and inspection of the cleaned component. For large components this policy cannot always be followed. In those cases for instance where an in-between internal inspection is required, or where only small modifications of the test object are necessary, other possibilities have to be considered. For this reason some work has been done to develop reliable vacuum distillation procedures for large components, based on the cleaning experience with small plant components. The results of these procedures applied to large plant components are reported in this paper

Automatic torque magnetometer for vacuum-to-high-pressure hydrogen environments

International Nuclear Information System (INIS)

Larsen, J.W.; Livesay, B.R.

1979-01-01

An automatic torque magnetometer has been developed for use in high-pressure hydrogen. It will contain pressures ranging from vacuum to 200 atm of hydrogen gas at sample temperatures greater than 400 0 C. This magnetometer, which uses an optical lever postion sensor and a restoring force technique has an operating range of 2.0 x 10 3 dyn cm to l.6 x 10 -4 dyn cm. An accompanying digital data collection system extends the sensitivity to 1 x 10 -5 dyn cm as well as increasing the data handling capacity of the system. The magnetic properties of thin films in high-temperature and high-pressure hydrogen environments can be studied using this instruments

Baking results of KSTAR vacuum vessel

International Nuclear Information System (INIS)

Kim, S. T.; Kim, Y. J.; Kim, K. M.; Im, D. S.; Joung, N. Y.; Yang, H. L.; Kim, Y. S.; Kwon, M.

2009-01-01

The Korea Superconducting Tokamak Advanced Research (KSTAR) is an advanced superconducting tokamak designed to establish a scientific and technological basis for an attractive fusion reactor. The fusion energy in the tokamak device is released through fusion reactions of light atoms such as deuterium or helium in hot plasma state, of which temperature reaches several hundreds of millions Celsius. The high temperature plasma is created in the vacuum vessel that provides ultra high vacuum status. Accordingly, it is most important for the vacuum condition to keep clean not only inner space but also surface of the vacuum vessel to make high quality plasma. There are two methods planned to clean the wall surface of the KSTAR vacuum vessel. One is surface baking and the other is glow discharge cleaning (GDC). To bake the vacuum vessel, De-Ionized (DI) water is heated to 130 .deg. C and circulated in the passage between double walls of the vacuum vessel (VV) in order to bake the surface. The GDC operation uses hydrogen and inert gas discharges. In this paper, general configuration and brief introduction of the baking result will be reported

Baking results of KSTAR vacuum vessel

Energy Technology Data Exchange (ETDEWEB)

Kim, S. T.; Kim, Y. J.; Kim, K. M.; Im, D. S.; Joung, N. Y.; Yang, H. L.; Kim, Y. S.; Kwon, M. [National Fusion Research Institute, Daejeon (Korea, Republic of)

2009-05-15

The Korea Superconducting Tokamak Advanced Research (KSTAR) is an advanced superconducting tokamak designed to establish a scientific and technological basis for an attractive fusion reactor. The fusion energy in the tokamak device is released through fusion reactions of light atoms such as deuterium or helium in hot plasma state, of which temperature reaches several hundreds of millions Celsius. The high temperature plasma is created in the vacuum vessel that provides ultra high vacuum status. Accordingly, it is most important for the vacuum condition to keep clean not only inner space but also surface of the vacuum vessel to make high quality plasma. There are two methods planned to clean the wall surface of the KSTAR vacuum vessel. One is surface baking and the other is glow discharge cleaning (GDC). To bake the vacuum vessel, De-Ionized (DI) water is heated to 130 .deg. C and circulated in the passage between double walls of the vacuum vessel (VV) in order to bake the surface. The GDC operation uses hydrogen and inert gas discharges. In this paper, general configuration and brief introduction of the baking result will be reported.

Waste acid/metal solution reduction and recovery by vacuum distillation

International Nuclear Information System (INIS)

Jones, E.O.; Wilcox, W.A.; Johnson, N.T.; Bowdish, F.W.

1995-01-01

Processes involving distillation under reduced pressure were developed at the Pacific Northwest Laboratory several years ago to recover spent acid solutions generated during the manufacture of nuclear fuel for the N-Reactor at the Hanford site. Following construction and testing of a pilot-plant, the technology was licensed to Viatec Recovery Systems, Inc. for commercialization. The technology developed included specialized distillation and rectification of volatile acids, removal of water and/or volatile acid from sulfuric acid, and precipitation of salts. A key feature of the Waste Acid Detoxification and Reclamation (WADR) technology is the development and use of advanced thermoplastic and fluoropolymer materials of construction in all critical process equipment. The technology was then expanded to include crystallization to recover metal salts for possible reuse. Economic and environmental advantages of the procedures include recovery of acids for reuse, simplification or elimination of the disposal of waste solutions, and possible recovery of metals. Industries expected to benefit from such applications include galvanizing, electroplating, sand leaching and any where metals are cleaned in acid solutions. Currently a modular system has been assembled for recovery of several different spent acid solutions

Production of Bioethanol from Agricultural Wastes Using Residual Thermal Energy of a Cogeneration Plant in the Distillation Phase

Directory of Open Access Journals (Sweden)

Raffaela Cutzu

2017-05-01

Full Text Available Alcoholic fermentations were performed, adapting the technology to exploit the residual thermal energy (hot water at 83–85 °C of a cogeneration plant and to valorize agricultural wastes. Substrates were apple, kiwifruit, and peaches wastes; and corn threshing residue (CTR. Saccharomyces bayanus was chosen as starter yeast. The fruits, fresh or blanched, were mashed; CTR was gelatinized and liquefied by adding Liquozyme® SC DS (Novozymes, Dittingen, Switzerland; saccharification simultaneous to fermentation was carried out using the enzyme Spirizyme® Ultra (Novozymes, Dittingen, Switzerland. Lab-scale static fermentations were carried out at 28 °C and 35 °C, using raw fruits, blanched fruits and CTR, monitoring the ethanol production. The highest ethanol production was reached with CTR (10.22% (v/v and among fruits with apple (8.71% (v/v. Distillations at low temperatures and under vacuum, to exploit warm water from a cogeneration plant, were tested. Vacuum simple batch distillation by rotary evaporation at lab scale at 80 °C (heating bath and 200 mbar or 400 mbar allowed to recover 93.35% (v/v and 89.59% (v/v of ethanol, respectively. These results support a fermentation process coupled to a cogeneration plant, fed with apple wastes and with CTR when apple wastes are not available, where hot water from cogeneration plant is used in blanching and distillation phases. The scale up in a pilot plant was also carried out.

Cascade Distillation Subsystem Development: Progress Toward a Distillation Comparison Test

Science.gov (United States)

Callahan, M. R.; Lubman, A.; Pickering, Karen D.

2009-01-01

Recovery of potable water from wastewater is essential for the success of long-duration manned missions to the Moon and Mars. Honeywell International and a team from NASA Johnson Space Center (JSC) are developing a wastewater processing subsystem that is based on centrifugal vacuum distillation. The wastewater processor, referred to as the Cascade Distillation Subsystem (CDS), utilizes an innovative and efficient multistage thermodynamic process to produce purified water. The rotary centrifugal design of the system also provides gas/liquid phase separation and liquid transport under microgravity conditions. A five-stage subsystem unit has been designed, built, delivered and integrated into the NASA JSC Advanced Water Recovery Systems Development Facility for performance testing. A major test objective of the project is to demonstrate the advancement of the CDS technology from the breadboard level to a subsystem level unit. An initial round of CDS performance testing was completed in fiscal year (FY) 2008. Based on FY08 testing, the system is now in development to support an Exploration Life Support (ELS) Project distillation comparison test expected to begin in early 2009. As part of the project objectives planned for FY09, the system will be reconfigured to support the ELS comparison test. The CDS will then be challenged with a series of human-gene-rated waste streams representative of those anticipated for a lunar outpost. This paper provides a description of the CDS technology, a status of the current project activities, and data on the system s performance to date.

Evolution of Volatile Compounds during the Distillation of Cognac Spirit.

Science.gov (United States)

Awad, Pierre; Athès, Violaine; Decloux, Martine Esteban; Ferrari, Gérald; Snakkers, Guillaume; Raguenaud, Patrick; Giampaoli, Pierre

2017-09-06

Cognac wine spirit has a complex composition in volatile compounds which contributes to its organoleptic profile. This work focused on the batch distillation process and, in particular, on volatile compounds specifically produced by chemical reactions during the distillation of Cognac wine spirit, traditionally conducted in two steps with charentais pot stills. The aim of this study was to characterize these volatile compounds formed during distillation. Sampling has been performed on the distillates and inside the boiler during a typical Cognac distillation. The analysis of these samples allowed us to perform a mass balance and to point out several types of volatile compounds whose quantities strongly increased during the distillation process. These compounds were distinguished by their chemical family. It has been found that the first distillation step was decisive for the formation of volatile compounds. Moreover, 2 esters, 3 aldehydes, 12 norisoprenoids, and 3 terpenes were shown to be generated during the process. These results suggest that some volatile compounds found in Cognac spirit are formed during distillation due to chemical reactions induced by high temperature. These findings give important indications to professional distillers in order to enhance the product's quality.

Application of high power microwave vacuum electron devices

International Nuclear Information System (INIS)

Ding Yaogen; Liu Pukun; Zhang Zhaochuan; Wang Yong; Shen Bin

2011-01-01

High power microwave vacuum electron devices can work at high frequency, high peak and average power. They have been widely used in military and civil microwave electron systems, such as radar, communication,countermeasure, TV broadcast, particle accelerators, plasma heating devices of fusion, microwave sensing and microwave heating. In scientific research, high power microwave vacuum electron devices are used mainly on high energy particle accelerator and fusion research. The devices include high peak power klystron, CW and long pulse high power klystron, multi-beam klystron,and high power gyrotron. In national economy, high power microwave vacuum electron devices are used mainly on weather and navigation radar, medical and radiation accelerator, TV broadcast and communication system. The devices include high power pulse and CW klystron, extended interaction klystron, traveling wave tube (TWT), magnetron and induced output tube (IOT). The state of art, common technology problems and trends of high power microwave vacuum electron devices are introduced in this paper. (authors)

Application of vacuum metallurgy to separate pure metal from mixed metallic particles of crushed waste printed circuit board scraps.

Science.gov (United States)

Zhan, Lu; Xu, Zhenming

2008-10-15

The principle of separating pure metal from mixed metallic particles (MMPs) byvacuum metallurgy is that the vapor pressures of various metals at the same temperature are different As a result, the metal with high vapor pressure and low boiling point can be separated from the mixed metals through distillation or sublimation, and then it can be recycled through condensation under a certain condition. The vacuum metallurgy separation (VMS) of MMPs of crushed waste printed circuit boards (WPCBs) has been studied in this paper. Theoretical analyses show that the MMPs (copper, zinc, bismuth, lead, and indium, for example) can be separated by vacuum metallurgy. The copper particles (0.15-0.20 mm) and zinc particles (<0.30 mm) were chosen to simulate the MMPs of crushed WPCBs. Experimental results show that the separated efficiency of zinc in the copper-rich particles achieves 96.19 wt % when the vacuum pressure is 0.01-0.10 Pa, the heating temperature is 1123 K, and the heating time is 105 min. Under this operation condition, the separated efficiency of zinc in the copper-rich particles from crushed WPCBs achieves 97.00 wt % and the copper purity increases from 90.68 to 99.84 wt %.

Fundamental studies on the switching in liquid nitrogen environment using vacuum switches for application in future high-temperature superconducting medium-voltage power grids

International Nuclear Information System (INIS)

Golde, Karsten

2016-01-01

By means of superconducting equipment it is possible to reduce the transmission losses in distribution networks while increasing the transmission capacity. As a result even saving a superimposed voltage level would be possible, which can put higher investment costs compared to conventional equipment into perspective. For operation of superconducting systems it is necessary to integrate all equipment in the cooling circuit. This also includes switchgears. Due to cooling with liquid nitrogen, however, only vacuum switching technology comes into question. Thus, the suitability of vacuum switches is investigated in this work. For this purpose the mechanics of the interrupters is considered first. Material investigations and switching experiments at ambient temperature and in liquid nitrogen supply information on potential issues. For this purpose, a special pneumatic construction is designed, which allows tens of thousands of switching cycles. Furthermore, the electrical resistance of the interrupters is considered. Since the contact system consists almost exclusively of copper, a remaining residual resistance and appropriate thermal losses must be considered. Since they have to be cooled back, an appropriate evaluation is given taking environmental parameters into account. The dielectric strength of vacuum interrupters is considered both at ambient temperature as well as directly in liquid nitrogen. For this purpose different contact distances are set at different interrupter types. A distinction is made between internal and external dielectric strength. Conditioning and deconditioning effects are minimized by an appropriate choice of the test circuit. The current chopping and resulting overvoltages are considered to be one of the few drawbacks of vacuum switching technology. Using a practical test circuit the height of chopping current is determined and compared for different temperatures. Due to strong scattering the evaluation is done using statistical methods. At

Study of distillation and degradation of perfluoro polyether; Estudo da destilacao e degradacao do perfluoropolieter

Energy Technology Data Exchange (ETDEWEB)

Lopergolo, Lilian Cristine

1997-07-01

Perfluoro-polyethers, PFPE, were first synthesised by Sianesi and collaborators giving rise to a new lubricant oils and greases classes with several applications. Perfluoro polyethers have excellent properties, for instance: high chemical stability and thermal stability, high density, high radiation resistance and excellent lubricating properties. FOMBLIN-Y oil is one of the perfluoro polyethers used as a lubricant in vacuum systems applied in the UF{sub 6} enrichment installations. Due to its excellent properties and for its applications in the nuclear field, IPEN-CNEN/S P had the interest to dominate its production technology with the aim to substitute the commercial FOMBLIN-Y oil used in the national consumption. The FOMBLIN-Y oil synthesis method, adopted in IPEN-CNEN/S P, made by the photooxidation of the hexa fluoro propylene. In this work we study the fraction separation of the national available production with restricted an increased molecular weights which was obtained by fraction distillation in a vacuum according to the ASTM D-1160 norm. We also study the catalytic effect of metals on the thermal stability of perfluoro polyethers. The inertness of perfluoro polyethers at temperatures higher than 300 deg C is strongly affected by presence of some metals. Al and Ti alloys cause fluid degradation at 250 deg C. This degradation is very important because it has a yield increase of the perfluoro polyethers production. (author)

Distillation of shale in situ

Energy Technology Data Exchange (ETDEWEB)

de Ganahl, C F

1922-07-04

To distill buried shale or other carbon containing compounds in situ, a portion of the shale bed is rendered permeable to gases, and the temperature is raised to the point of distillation. An area in a shale bed is shattered by explosives, so that it is in a relatively finely divided form, and the tunnel is then blocked by a wall, and fuel and air are admitted through pipes until the temperature of the shale is raised to such a point that a portion of the released hydrocarbons will burn. When distillation of the shattered area takes place and the lighter products pass upwardly through uptakes to condensers and scrubbers, liquid oil passes to a tank and gas to a gasometer while heavy unvaporized products in the distillation zone collect in a drain, flow into a sump, and are drawn off through a pipe to a storage tank. In two modifications, methods of working are set out in cases where the shale lies beneath a substantially level surface.

Pyrocatechol from low-temperature tar

Energy Technology Data Exchange (ETDEWEB)

Lowenstein-Lom, W

1950-01-01

A method for production and purification of pyrocatechol (I) from low-temperature carbonization effluents was described. Phenosolvan, a mixture of isobutyl, butyl, and amyl acetates, was used for extraction of I from the effluent. After removing most of the solvent by distillation, the separation was completed by batch vacuum distillation at 25 to 50 millimeter Hg. The 4th fraction, containing I 49.2, I homologues 31.1, o-cresol 6.8, xylenols 7.3, and higher boiling material and residue 5.6 percent, was treated in a purification pilot plant, which was described. This fraction was dissolved in an equal weight of C/sub 6/H/sub 6/, then cooled. I was crystallized out in a vacuum crystallizer, centrifuged, and washed with C/sub 6/H/sub 6/, dried in a rotating-plate drier and taken to storage. The purified I melted 100/sup 0/ to 102/sup 0/ and contained 4 to 8 percent homologues or other impurities. A further recrystallization raised its purity to 99.2 percent. Plant capacities and production costs are given.

Design data, liquid distributors and condenser for a distillation column to enrich tritium in metallic lithium

International Nuclear Information System (INIS)

Barnert, E.

1984-01-01

Tritium, one fuel component of the fusion reactor is bred from the reactors blanket material lithium. Before extracting the tritium from, for instance, metallic lithium by permeation it has to be enriched in the lithium by high temperature distillation. In this report design data for a column for high temperature distillation are given. About the testing of two distributors for small liquid quantities and of a condenser is reported. (orig.) [de

High-vacuum pumping out of hydrogen isotopes by compressed and electrophysical pumps

International Nuclear Information System (INIS)

Bychkova, A.D.; Ershova, Z.V.; Saksaganskij, G.L.; Serebrennikov, D.V.

1982-01-01

To explain the selection of parameters of vacuum systems of projected thermonuclear devices, experiments are performed on the pumping-out of deuterium and tritium by high-vacuum pumps of different types. The values of the fast response of turbomolecular, diffusion vapour-mercury, magneto-discharge and titanium getter pumps in the operation pressure range are determined. The rate of sorption of hydrogen isotopes by non-spraying gas absorber of cial alloy depending on the amount of the gas absorbed and temperature, is measured. Gas current is determined by the pressure drop on the diagram of the known conductivity. Individual calibration of manometric converters for different gases using a mercury burette is performed preliminarily. The means of high-vacuum pumping-out that have been studied have the following values of fast response for tritium (relatively to protium): turbomolecular pump-0.95; evaporation getter pump-0.25; magneto-discharge pumps-0.65-0.9; cial alloy-0.1...0.5

Pressure measurements in the AGS Booster ultra-high vacuum system

International Nuclear Information System (INIS)

Gabusi, J.; Geller, J.; Hseuh, H.C.; Mapes, M.; Stattel, P.

1992-01-01

An average pressure of mid 10 -11 Torr has been achieved and maintained in the AGS Booster ring vacuum system during its first year of operation. This ultra-high vacuum system is monitored through remote controlled Bayard-Alpert Gauges (BAGs). The characteristics of the pressure measurements with BAGs over the long cable lengths (up to 200 m) and under various accelerator operating conditions will be described. Two types of noise in the pressure readouts have been identified; the electromagnetic interference (EMI) associated with the acceleration cycles of the Booster and the environment noise associated with the temperature of the collector cables. The magnitude of the noise pickup depends on the routing of the collector cables and reaches the equivalent pressure of low 10 -9 Torr

Micro-damage propagation in ultra-high vacuum seals

CERN Document Server

Lutkiewicz, P; Garion, C

2010-01-01

The paper addresses a fundamental problem of tightness of ultra-high vacuum systems (UHV) at cryogenic temperatures in the light of continuum damage mechanics (CDM). The problem of indentation of a rigid punch into an elastic-plastic half-space is investigated based on rate independent plasticity with mixed kinematic and isotropic hardening. The micro-damage fields are modeled by using an anisotropic approach with a kinetic law of damage evolution suitable for ductile materials and cryogenic temperatures. The model has been experimentally validated and the results are used to predict the onset of macro-cracking (loss of tightness) and the corresponding load (contact pressure). The algorithm is applied in the design of UHV systems for particle accelerators. (C) 2009 Published by Elsevier Ltd.

Experimental Verification of Dynamic Operation of Continuous and Multivessel Batch Distillation

Energy Technology Data Exchange (ETDEWEB)

Wittgens, Bernd

1999-07-01

This thesis presents a rigorous model based on first principles for dynamic simulation of the composition dynamics of a staged high-purity continuous distillation columns and experiments performed to verify it. The thesis also demonstrates the importance of tray hydraulics to obtain good agreement between simulation and experiment and derives analytic expressions for dynamic time constants for use in simplified and vapour dynamics. A newly developed multivessel batch distillation column consisting of a reboiler, intermediate vessels and a condenser vessel provides a generalization of previously proposed batch distillation schemes. The total reflux operation of this column was presented previously and the present thesis proposes a simple feedback control strategy for its operation based on temperature measurements. The feasibility of this strategy is demonstrated by simulations and verified by laboratory experiments. It is concluded that the multivessel column can be easily operated with simple temperature controllers, where the holdups are only controlled indirectly. For a given set of temperature setpoints, the final product compositions are independent of the initial feed composition. When the multivessel batch distillation column is compared to a conventional batch column, both operated under feedback control, it is found that the energy required to separate a multicomponent mixture into highly pure products is much less for the multivessel system. This system is also the simplest one to operate.

VARTM Processing of High Temperature Polymer Matrix Composites

National Research Council Canada - National Science Library

Criss, Jr, Jim M

2008-01-01

The overall technical objective of the Phase 1 effort was to extend and advance the state the-art in high temperature composite fabrication techniques by developing a High Tempera Vacuum Assisted Resin Transfer Molding (VARTM...

Reoxidation of uranium in electrolytically reduced simulated oxide fuel during residual salt distillation

International Nuclear Information System (INIS)

Eun-Young Choi; Jin-Mok Hur; Min Ku Jeon; University of Science and Technology, Yuseong-gu, Daejeon

2017-01-01

We report that residual salt removal by high-temperature distillation causes partial reoxidation of uranium metal to uranium oxide in electrolytically reduced simulated oxide fuel. Specifically, the content of uranium metal in the above product decreases with increasing distillation temperatures, which can be attributed to reoxidation by Li 2 O contained in residual salt (LiCl). Additionally, we estimate the fractions of Li 2 O reacted with uranium metal under these conditions, showing that they decrease with decreasing temperature, and calculate some thermodynamic parameters of the above reoxidation. (author)

Method of dry distillation of solid and liquid fuels. [below 500/sup 0/C

Energy Technology Data Exchange (ETDEWEB)

Michot-Dupont, G F

1932-07-29

A method of manufacture is given of liquid fuels with a low boiling temperature by means of dry distillation of coals, lignites, peat, and similar materials at temperatures below 500/sup 0/C in the presence of fatty acids (such as acetates). It is characterized by carrying out the distillation after adding at least one more basic reacting salt in such quantity that the reaction takes place under highly basic conditions.

New alternatives for the fermentation process in the ethanol production from sugarcane: Extractive and low temperature fermentation

International Nuclear Information System (INIS)

Palacios-Bereche, Reynaldo; Ensinas, Adriano; Modesto, Marcelo; Nebra, Silvia A.

2014-01-01

Ethanol is produced in large scale from sugarcane in Brazil by fermentation of sugars and distillation. This is currently considered as an efficient biofuel technology, leading to significant reduction on greenhouse gases emissions. However, some improvements in the process can be introduced in order to improve the use of energy. In current distilleries, a significant fraction of the energy consumption occurs in the purification step – distillation and dehydration – since conventional fermentation systems employed in the industry require low substrate concentration, which must be distilled, consequently with high energy consumption. In this study, alternatives to the conventional fermentation processes are assessed, through computer simulation: low temperature fermentation and vacuum extractive fermentation. The aim of this study is to assess the incorporation of these alternative fermentation processes in ethanol production, energy consumption and electricity surplus produced in the cogeneration system. Several cases were evaluated. Thermal integration technique was applied. Results shown that the ethanol production increases between 3.3% and 4.8% and a reduction in steam consumption happens of up to 36%. About the electricity surplus, a value of 85 kWh/t of cane can be achieved when condensing – extracting steam turbines are used. - Highlights: • Increasing the wine concentration in the ethanol production from sugarcane. • Alternatives to the conventional fermentation process. • Low temperature fermentation and vacuum extractive fermentation. • Reduction of steam consumption through the thermal integration of the processes. • Different configurations of cogeneration system maximizing the electricity surplus

Process for distilling shales, peats, etc

Energy Technology Data Exchange (ETDEWEB)

Felizat, G

1922-01-09

The invention has for its object: a process for the distillation of shales, peats, and analogous products characterized by injecting across the substance a very rapid stream of superheated steam under pressure in order to effect a rapid removal of the products of distillation, to lower also the temperature at which it distills, to equalize the temperature throughout the mass, to hydrogenate the heavy hydrocarbons. An apparatus is put into operation characterized by the combination of a retort receiving the material to be distilled with a superheater for the steam, the combustion products which escape from the hearth of the superheater going to encircle the retort while the steam which comes off the superheater traverses this retort, the pressure of the steam being regulated by a convenient regulator; the products of the distillation result from the simultaneous action of the hot gases and steam on the contents of the retort being, on the other hand, separated at the outlet of this retort by means of cooling in a gas separator, a condenser, and part of the gas after being separated serving to heat the mentioned superheater.

Process of distilling heavy hydrocarbons

Energy Technology Data Exchange (ETDEWEB)

1929-12-03

This invention has for its object the distillation of heavy liquid hydrocarbons for the purpose of obtaining lighter hydrocarbons stable and immediately salable for fuels in combustion motors. The process is distinguished by the fact that the heavy hydrocarbon is distilled by means of heating to a temperature in keeping with the nature of the material to be treated up to 350/sup 0/C under pressure or without pressure the distillation being carried out on catalysts containing successively nickel, copper, and iron (3 parts of nickel, 1 part of copper, and 1 part of iron), the vapors produced by this distillation being exposed in turn to the action of catalysts of the same nature and in the same proportion.

Ultra-high vacuum technology for accelerators

CERN Multimedia

CERN. Geneva. Audiovisual Unit; Hilleret, Noël; Strubin, Pierre M

2002-01-01

The lectures will start with a review of the basics of vacuum physics required to build Ultra High Vacuum (UHV) systems, such as static and dynamic outgassing. Before reviewing the various pumping and measurement devices, including the most modern one like Non Evaporable Getter (NEG) coatings, an overview of adequate materials to be used in UHV systems will be given together with their treatment (e.g. cleaning procedures and bake out). Practical examples based on existing or future accelerators will be used to illustrate the topics. Finally, a short overview of modern vacuum controls and interlocks will be given.

Destructive distillation

Energy Technology Data Exchange (ETDEWEB)

Allison, C A

1906-05-22

The invention relates to an apparatus in which the destructive distillation or coking of coal, peat, shale, etc., is carried out by means of a current of hot gases at a temperature of 700--800/sup 0/F., as described in Specification No. 11,925, A.D. 1906.

Multiscale Thermo-Mechanical Design and Analysis of High Frequency and High Power Vacuum Electron Devices

Science.gov (United States)

Gamzina, Diana

Diana Gamzina March 2016 Mechanical and Aerospace Engineering Multiscale Thermo-Mechanical Design and Analysis of High Frequency and High Power Vacuum Electron Devices Abstract A methodology for performing thermo-mechanical design and analysis of high frequency and high average power vacuum electron devices is presented. This methodology results in a "first-pass" engineering design directly ready for manufacturing. The methodology includes establishment of thermal and mechanical boundary conditions, evaluation of convective film heat transfer coefficients, identification of material options, evaluation of temperature and stress field distributions, assessment of microscale effects on the stress state of the material, and fatigue analysis. The feature size of vacuum electron devices operating in the high frequency regime of 100 GHz to 1 THz is comparable to the microstructure of the materials employed for their fabrication. As a result, the thermo-mechanical performance of a device is affected by the local material microstructure. Such multiscale effects on the stress state are considered in the range of scales from about 10 microns up to a few millimeters. The design and analysis methodology is demonstrated on three separate microwave devices: a 95 GHz 10 kW cw sheet beam klystron, a 263 GHz 50 W long pulse wide-bandwidth sheet beam travelling wave tube, and a 346 GHz 1 W cw backward wave oscillator.

Distillation, destructive

Energy Technology Data Exchange (ETDEWEB)

Medlrum, E

1869-02-06

The invention relates to the decomposition of the liquids with high boiling points, and the solids with low melting points, left in the purification of paraffin oil obtained from coal or shale. The liquids or melted solids, or their vapors, are passed through a heated iron tube or retort and c., which may be packed with broken stones, spent shale, and c. The temperature is regulated between 700/sup 0/F and a low red heat. The condensed products consist of a mixture of light and heavy oils, which may be separated by distillation. The heavier residues may be again passed through the decomposing apparatus.

Distilling hydrocarbons

Energy Technology Data Exchange (ETDEWEB)

Bataafsche, N V; de Brey, J H.C.

1918-10-30

Hydrocarbons containing a very volatile constituent and less volatile constituents, such as casing-head gases, still gases from the distillation of crude petroleum and bituminous shale are separated into their constituents by rectification under pressure; a pressure of 20 atmospheres and limiting temperatures of 150/sup 0/C and 40/sup 0/C are mentioned as suitable. The mixture may be subjected to a preliminary treatment consisting in heating to a temperature below the maximum rectification temperature at a pressure greater than that proposed to be used in the rectification.

Batch pervaporative fermentation with coupled membrane and its influence on energy consumption in permeate recovery and distillation stage

International Nuclear Information System (INIS)

Leon, Juan A.; Palacios-Bereche, Reynaldo; Nebra, Silvia A.

2016-01-01

In the ethanol production process from sugarcane molasses, the distillation process is a high-energy demand stage. The distillation energy efficiency is strongly associated with the alcoholic fermentation performance in the process. The final ethanol concentration in the alcoholic wines has a direct impact on consumption of thermal energy in ethanol separation. In this paper, ethanol production with a H-SBMF (Hybrid-Simple Batch Membrane Fermenter) using PDMS (polydimethylsiloxane) pervaporation membrane was modelled and simulated, in order to determine its influence on energy consumption in distillation. Steam in distillation and electrical energy needs in permeate recovery were mainly influenced by membrane adaptation. The H-SBMF achieved a higher ethanol production in the range of 10–13% compared to the conventional batch fermenter, and an increase in productivity of 150%. The distillation system consisted of two sets of columns: the ethanol recovery column and the rectification column. The permeate recovery system (i.e. vacuum and compression) was regarded in order to evaluate the electrical energy requirement, and the thermal energy demand was evaluated. A decrease in steam consumption was evidenced by the adaptation of the membrane to the fermenter. Higher energy efficiencies were achieved in distillation with larger membrane areas, achieving almost 17% steam reduction. - Highlights: • Higher and faster ethanol productions were achieved by fermenter hybridization. • Multi-stage permeate compression and inter-stage heat recovery were assumed. • Energy demand was studied based on an integrated fermentation and distillation scheme. • High-energy efficiency was attained in the distillation to produce hydrated alcohol.

Nanophotonics-enabled solar membrane distillation for off-grid water purification.

Science.gov (United States)

Dongare, Pratiksha D; Alabastri, Alessandro; Pedersen, Seth; Zodrow, Katherine R; Hogan, Nathaniel J; Neumann, Oara; Wu, Jinjian; Wang, Tianxiao; Deshmukh, Akshay; Elimelech, Menachem; Li, Qilin; Nordlander, Peter; Halas, Naomi J

2017-07-03

With more than a billion people lacking accessible drinking water, there is a critical need to convert nonpotable sources such as seawater to water suitable for human use. However, energy requirements of desalination plants account for half their operating costs, so alternative, lower energy approaches are equally critical. Membrane distillation (MD) has shown potential due to its low operating temperature and pressure requirements, but the requirement of heating the input water makes it energy intensive. Here, we demonstrate nanophotonics-enabled solar membrane distillation (NESMD), where highly localized photothermal heating induced by solar illumination alone drives the distillation process, entirely eliminating the requirement of heating the input water. Unlike MD, NESMD can be scaled to larger systems and shows increased efficiencies with decreased input flow velocities. Along with its increased efficiency at higher ambient temperatures, these properties all point to NESMD as a promising solution for household- or community-scale desalination.

Some remarks on the carrier distillation method; Quelques remarques sur la methode 'carrier distillation'

Energy Technology Data Exchange (ETDEWEB)

Avni, R; Chaput, M [Commissariat a l' Energie Atomique, Saclay (France). Centre d' Etudes Nucleaires

1961-07-01

The method described by SCRIBNER and MULLIN makes possible the spectrographic analysis of the refractory oxides of uranium and plutonium. It uses a distillation of the elements which is more or less selective. The influence of the carrier is the subject of as many hypotheses as there are parameters involved in the process. The measurements of the arc temperature carried out on the leading edges of the vibration bands and of certain copper lines have made it possible to show the influence of the nature of the carrier and to establish a relationship between the values of the excitation potentials of the atoms and the temperatures produced. Further, this result makes it possible to explain certain contradictions between the principle of a fractional distillation in the arc which is incompatible with the refractory properties of certain elements and their spectrographic sensitivity. (author) [French] La methode decrite par SCRIBNER et MULLIN permet l'analyse spectrographique des oxydes refractaires d'uranium et de plutonium. Elle fait appel a une distillation plus ou moins selective des elements. L'influence de l'entraineur est l'objet d'aussi nombreuses hypotheses que les parametres lies au phenomene. Les mesures de la temperature de l'arc, effectuees sur les tetes de bandes de vibration du cyanogene et certaines raies du cuivre ont permis de montrer l'influence de la nature de l'entraineur et de trouver une relation entre les valeurs des potentiels d'excitation des atomes et les temperatures produites. En outre, ce resultat permet d'expliquer certaines contradictions entre le principe d'une distillation fractionnee dans l'arc incompatible avec les proprietes refractaires de certains elements et leur sensibilite spectrographique. (auteur)

Separation of free fatty acids from high free fatty acid crude palm oil using short-path distillation

Science.gov (United States)

Japir, Abd Al-Wali; Salimon, Jumat; Derawi, Darfizzi; Bahadi, Murad; Yusop, Muhammad Rahimi

2016-11-01

The separation of free fatty acids (FFAs) was done by using short-path distillation (SPD). The separation parameters was at their boiling points, a feed amount of 2.3 mL/min, an operating pressure of 10 Torr, a condenser temperature of 60°C, and a rotor speed of 300 rpm. The physicochemical characteristics of oil before and after SPD were determined. The results showed that FFA % of 8.7 ± 0.3 and 0.9 ± 0.1 %, iodine value of 53.1 ± 0.4 and 52.7 ± 0.5 g I2/100 g, hydroxyl value of 32.5 ± 0.6 and 13.9 ± 1.1 mg KOH/g, unsaponifiable value of 0.31 ± 0.01 and 0.20 ± 0.15%, moisture content of 0.31 ± 0.01 and 0.24 ± 0.01 % for high free fatty acid crude palm oil before and after distillation, respectively. Gas chromatography (GC) results showed that the major fatty acids in crude palm oil (CPO) were palmitic acid (44.4% - 45%) followed by oleic acid (39.6% - 39.8%). In general, high free fatty acid crude palm oil after molecular distillation (HFFA-CPOAM) showed admirably physicochemical properties.

Grain growth behavior and high-temperature high-strain-rate tensile ductility of iridium alloy DOP-26

International Nuclear Information System (INIS)

McKamey, C.G.; Gubbi, A.N.; Lin, Y.; Cohron, J.W.; Lee, E.H.; George, E.P.

1998-04-01

This report summarizes results of studies conducted to date under the Iridium Alloy Characterization and Development subtask of the Radioisotope Power System Materials Production and Technology Program to characterize the properties of the new-process iridium-based DOP-26 alloy used for the Cassini space mission. This alloy was developed at Oak Ridge National Laboratory (ORNL) in the early 1980's and is currently used by NASA for cladding and post-impact containment of the radioactive fuel in radioisotope thermoelectric generator (RTG) heat sources which provide electric power for interplanetary spacecraft. Included within this report are data generated on grain growth in vacuum or low-pressure oxygen environments; a comparison of grain growth in vacuum of the clad vent set cup material with sheet material; effect of grain size, test temperature, and oxygen exposure on high-temperature high-strain-rate tensile ductility; and grain growth in vacuum and high-temperature high-strain-rate tensile ductility of welded DOP-26. The data for the new-process material is compared to available old-process data

High-vacuum plasma pump

International Nuclear Information System (INIS)

Dorodnov, A.M.; Minajchev, V.E.; Miroshkin, S.I.

1980-01-01

The action of an electric-arc high-vacuum pump intended for evacuating the volumes in which the operation processes are followed by a high gas evolution is considered. The operation of the pump is based on the principle of controlling the getter feed according to the gas load and effect of plasma sorbtion pumping. The pump performances are given. The starting pressure is about 5 Pa, the limiting residual pressure is about 5x10 -6 Pa, the pumping out rate of nitrogen in the pressure range 5x10 -5 -5x10 -3 Pa accounts for about 4000 l/s, the power consumption comes to 6 kW. Analyzing the results of the test operation of the pump, it has been concluded that its principal advantages are the high starting pressure, controlled getter feed rate and possibility of pumping out the gases which are usually pumped out with difficulty. The operation reliability of the pump is defined mainly by reliable operation of the ignition system of the vacuum arc [ru

Model predictive control of a crude oil distillation column

Directory of Open Access Journals (Sweden)

Morten Hovd

1999-04-01

Full Text Available The project of designing and implementing model based predictive control on the vacuum distillation column at the Nynäshamn Refinery of Nynäs AB is described in this paper. The paper describes in detail the modeling for the model based control, covers the controller implementation, and documents the benefits gained from the model based controller.

Economic Analysis in Series-Distillation Desalination

Directory of Open Access Journals (Sweden)

Mirna Rahmah Lubis

2010-06-01

Full Text Available The ability to produce potable water economically is the primary purpose of seawater desalination research. Reverse osmosis (RO and multi-stage flash (MSF cost more than potable water produced from fresh water resources. Therefore, this research investigates a high-efficiency mechanical vapor-compression distillation system that employs an improved water flow arrangement. The incoming salt concentration was 0.15% salt for brackish water and 3.5% salt for seawater, whereas the outgoing salt concentration was 1.5% and 7%, respectively. Distillation was performed at 439 K and 722 kPa for both brackish water feed and seawater feed. Water costs of the various conditions were calculated for brackish water and seawater feeds using optimum conditions considered as 25 and 20 stages, respectively. For brackish water at a temperature difference of 0.96 K, the energy requirement is 2.0 kWh/m3. At this condition, the estimated water cost is $0.39/m3 achieved with 10,000,000 gal/day distillate, 30-year bond, 5% interest rate, and $0.05/kWh electricity. For seawater at a temperature difference of 0.44 K, the energy requirement is 3.97 kWh/m3 and the estimated water cost is $0.61/m3. Greater efficiency of the vapor compression system is achieved by connecting multiple evaporators in series, rather than the traditional parallel arrangement. The efficiency results from the gradual increase of salinity in each stage of the series arrangement in comparison to parallel. Calculations using various temperature differences between boiling brine and condensing steam show the series arrangement has the greatest improvement at lower temperature differences. Keywords: desalination, dropwise condensation, mechanical-vapor compression

Single-laboratory validation of a method for the determination of select volatile organic compounds in foods by using vacuum distillation with gas chromatography/mass spectrometry.

Science.gov (United States)

Nyman, Patricia J; Limm, William; Begley, Timothy H; Chirtel, Stuart J

2014-01-01

Recent studies showed that headspace and purge and trap methods have limitations when used to determine volatile organic compounds (VOCs) in foods, including matrix effects and artifact formation from precursors present in the sample matrix or from thermal decomposition. U.S. Environmental Protection Agency Method 8261A liberates VOCs from the sample matrix by using vacuum distillation at room temperature. The method was modified and validated for the determination of furan, chloroform, benzene, trichloroethene, toluene, and sytrene in infant formula, canned tuna (in water), peanut butter, and an orange beverage (orange-flavored noncarbonated beverage). The validation studies showed that the LOQ values ranged from 0.05 ng/g toluene in infant formula to 5.10 ng/g toluene in peanut butter. Fortified recoveries were determined at the first, second, and third standard additions, and concentrations ranged from 0.07 to 6.9 ng/g. When quantified by the method of standard additions, the recoveries ranged from 56 to 218% at the first standard addition and 89 to 117% at the third. The validated method was used to conduct a survey of the targeted VOCs in 18 foods. The amounts found ranged from none detected to 73.8 ng/g furan in sweet potato baby food.

Dry-distillation of experimental animal wastes containing radioisotopes

International Nuclear Information System (INIS)

Miyatake, Hideo; Saito, Kazumi; Kurihara, Norio

1988-01-01

Mice were dry-distilled at 800deg C for 10 min, after [ 32 P]orthophosphate or L-[4,5- 3 H]leucine was intraperitoneally administered. Phosphorus-32 was quantitatively recovered in the residual solid, whereas 95% of 3 H was found in the distillate (condensed water). When 14 C (L-[U- 14 C]malic acid or L-[U- 14 C]leucine) was administered to mice and they were dry-distilled, 14 C-radioactivity was distributed into two fractions; residual solid and exhaust gas. In these cases, the recovery percentage of 14 C in residual solid was not very high but increased as the treating temperature decreased. It reached about 40% of the administered 14 C at 400deg C for 120 min. By the dry-distillation of animals, their weight was reduced to about 10% in every animal tested (mice, rats and rabbits). The volume was reduced to about 20% in cases of mice and rats, and about 30% in case of rabbits. It was concluded that the dry-distillation can be useful as a pre-treatment for disposal of animal wastes containing radioisotopes. (author)

Characterization of petroleum distillates by GC-AED (coupling with gas chromatography and atomic emission detection); Caracterisation des distillats petroliers par couplage chromatographie en phase gazeuse et detection par emission atomique

Energy Technology Data Exchange (ETDEWEB)

Baco, F.

1997-05-21

This thesis describes the characterization of atmospheric petroleum distillates (kerosenes and gas-oils) and vacuum distillates by hyphenated technic of Gas Chromatography and Atomic Emission Detector (GC-AED). A gas chromatographic simulated distillation, which gives the weight % of sample as a function of the petroleum cut temperature, was adapted to the GC-AED to obtain an original information about the elemental composition profile. After generalities, historic of the development of the instrument and the first petroleum applications are described. In the experimental part, analytical conditions used, different technics of characterisation of distillates and the base of samples analyzed are exposed. After a study of the GC-AED`s performances for the target elements (C, H, S, N), a quantitative method for the elemental analysis of distillates was developed and validated at three levels: total elemental analysis, simulated distillation and elemental composition as a function of the distillation profile. Finally, different ways for the applications of the GC-AED in order to characterize the distillates were explored, in particular to classify products and predict some petroleum properties (cetane number, density,...). The more interesting outlook seems to be the prediction of some properties as a function of the distillation profile. (author) 155 refs.

Honeywell Cascade Distiller System Performance Testing Interim Results

Science.gov (United States)

Callahan, Michael R.; Sargusingh, Miriam

2014-01-01

The ability to recover and purify water through physiochemical processes is crucial for realizing long-term human space missions, including both planetary habitation and space travel. Because of their robust nature, distillation systems have been actively pursued as one of the technologies for water recovery. The Cascade Distillation System (CDS) is a vacuum rotary distillation system with potential for greater reliability and lower energy costs than existing distillation systems. The CDS was previously under development through Honeywell and NASA. In 2009, an assessment was performed to collect data to support down-selection and development of a primary distillation technology for application in a lunar outpost water recovery system. Based on the results of this testing, an expert panel concluded that the CDS showed adequate development maturity, TRL-4, together with the best product water quality and competitive weight and power estimates to warrant further development. The Advanced Exploration Systems (AES) Water Recovery Project (WRP) worked to address weaknesses identified by The Panel; namely bearing design and heat pump power efficiency. Testing at the NASA-JSC Advanced Exploration System Water Laboratory (AES Water Lab) using a prototype Cascade Distillation Subsystem (CDS) wastewater processor (Honeywell International, Torrance, Calif.) with test support equipment and control system developed by Johnson Space Center was performed to evaluate performance of the system with the upgrades. The CDS will also have been challenged with ISS analog waste streams and a subset of those being considered for Exploration architectures. This paper details interim results of the AES WRP CDS performance testing.

Procurement specification high vacuum test chamber and pumping system

International Nuclear Information System (INIS)

1976-01-01

The specification establishes requirements for a high-vacuum test chamber, associated vacuum pumps, valves, controls, and instrumentation that shall be designed and fabricated for use as a test chamber for testing a closed loop Brayton Isotope Power System (BIPS) Ground Demonstration System (GDS). The vacuum system shall include all instrumentation required for pressure measurement and control of the vacuum pumping system. A general outline of the BIPS-GDS in the vacuum chamber and the preliminary piping and instrumentation interface to the vacuum chamber are shown

Distilling oils

Energy Technology Data Exchange (ETDEWEB)

Leffer, L G

1912-01-29

In a process for converting heavy hydrocarbons, such as petroleum or shale oil, into light hydrocarbons by distilling under the pressure of an inert gas, the operation is conducted at a temperature not exceeding 410/sup 0/C and under an accurately regulated pressure, the gas being circulated through the still and the condenser by means of a pump. The oil in the still may be agitated by stirring vanes or by blowing the gas through it. Hydrogen, nitrogen, carbon dioxide, methane, or gases generated in the distillation may be used as pressure media; the gas is heated before its admission to the still. A pressure of from 11 to 12 atmospheres is used in treating gas oil. Specification 10,277/89 is referred to.

Temperature distributions in a Tokamak vacuum vessel of fusion reactor after the loss-of-vacuum-events occurred

International Nuclear Information System (INIS)

Takase, K.; Kunugi, T.; Shibata, M.; Seki, Y.

1998-01-01

If a loss-of-vacuum-event (LOVA) occurred in a fusion reactor, buoyancy-driven exchange flows would occur at breaches of a vacuum vessel (VV) due to the temperature difference between the inside and outside of the VV. The exchange flows may bring mixtures of activated materials and tritium in the VV to the outside through the breaches, and remove decay heat from the plasma-facing components of the VV. Therefore, the LOVA experiments were carried out under the condition that one or two breaches was opened and that the VV was heated to a maximum 200 C, using a small-scaled LOVA experimental apparatus. Air and helium gas were provided as working fluids. Fluid and wall temperature distributions in the VV were measured and the flow patterns in the VV were estimated by using these temperature distributions. It was found that: (1) the exchange mass in the VV depended on the breach positions; (2) the exchange flow at the single breach case became a counter-current flow when the breach was at the roof of the VV and a stratified flow when it was at the side wall; (3) and that at the double breach case, a one-way flow between two breaches was formed. (orig.)

Isolation of high purity americium metal via distillation

Science.gov (United States)

Squires, Leah N.; King, James A.; Fielding, Randall S.; Lessing, Paul

2018-03-01

Pure americium metal is a crucial component for the fabrication of transmutation fuels. Unfortunately, americium in pure metal form is not available; however, a number of mixed metals and mixed oxides that include americium are available. In this manuscript a method is described to obtain high purity americium metal from a mixture of americium and neptunium metals with lead impurity via distillation.

Development of an Exploration-Class Cascade Distillation System: Flight Like Prototype Preliminary Design

Science.gov (United States)

Callahan, Michael R.; Sargusingh, Miriam J.

2015-01-01

The ability to recover and purify water through physiochemical processes is crucial for realizing long-term human space missions, including both planetary habitation and space travel. Because of their robust nature, distillation systems have been actively pursued as one of the technologies for water recovery. One such technology is the Cascade Distillation System (CDS) a multi-stage vacuum rotary distiller system designed to recover water in a microgravity environment. Its rotating cascading distiller operates similarly to the state of the art (SOA) vapor compressor distiller (VCD), but its control scheme and ancillary components are judged to be straightforward and simpler to implement into a successful design. Through the Advanced Exploration Systems (AES) Life Support Systems (LSS) Project, the NASA Johnson Space Center (JSC) in collaboration with Honeywell International is developing a second generation flight forward prototype (CDS 2.0). The key objectives for the CDS 2.0 design task is to provide a flight forward ground prototype that demonstrates improvements over the SOA system in the areas of increased reliability and robustness, and reduced mass, power and volume. It will also incorporate exploration-class automation. The products of this task are a preliminary flight system design and a high fidelity prototype of an exploration class CDS. These products will inform the design and development of the third generation CDS which is targeted for on-orbit DTO. This paper details the preliminary design of the CDS 2.0.

Improving the performance of solar still by using nanofluids and providing vacuum

International Nuclear Information System (INIS)

Kabeel, A.E.; Omara, Z.M.; Essa, F.A.

2014-01-01

Highlights: • Modified solar still integrated with an external condenser and used nanofluids were studied. • The results obtained that using cuprous oxide increased the distilled productivity by 133.64%. • Using the aluminum oxide–water nanofluid increased the distillate productivity of the modified still by 125.0%. - Abstract: The experimental modifications were carried out into the conventional solar still, considerably increasing the distillate water productivity. The effects of using different types of nanomaterials on the performance of solar still were studied. The investigated solid nanoparticles are the cuprous and aluminum oxides. The performance was investigated at different weight fraction concentrations of nanoparticles in the basin water with and without providing vacuum. These additions and modifications greatly improve the evaporation and condensation rates and hence the distillate yield was augmented. The research was conducted for range of concentrations starting from 0.02% to 0.2% with a step of 0.02%. The maxima productivity was obtained for using the cuprous oxide nanoparticles with a concentration of 0.2% with operating the vacuum fan. The results obtained that using cuprous oxide nanoparticles increased the distilled productivity by 133.64% and 93.87% with and without the fan respectively. On the other hand, using aluminum oxide nanoparticles enhanced the distillate by 125.0% and 88.97% with and without the fan respectively as compared to the conventional still. The estimated cost of 1.0 l of distillate are approximately 0.035$, 0.045$ when using the cuprous oxide nanomaterial with and without the fan and, as well as the aluminum oxide nanoparticles, 0.038$ and 0.051$ respectively, and for the conventional still is 0.048$

Progress in vacuum metal extraction, refining and consolidation

International Nuclear Information System (INIS)

Sundaram, C.V.; Mukherjee, T.K.; Sharma, B.P.

1973-01-01

The unique achievements in the process metallurgy of rare metals in the past quarter century should largely be attributed to advances in vacuum technology. New standards for high purity, increasing demand for pure metals and alloys for established applications, and steady improvement in sophistication and capacity of vacuum furnaces have provided the stimulus for developing and expanding vacuum metal extraction processes, and also exploring totally new processes. The paper discusses the thermochemistry of vacuum metallurgy, carbothermic and metallothermic reduction reactions, consolidation and refining by vacuum arc melting, electron beam melting and high temperature high vacuum sintering, and ultrapurification, with special reference to the reactive and refractory metals of Group IV to VI. (author)

Multivariable model predictive control design of reactive distillation column for Dimethyl Ether production

Science.gov (United States)

Wahid, A.; Putra, I. G. E. P.

2018-03-01

Dimethyl ether (DME) as an alternative clean energy has attracted a growing attention in the recent years. DME production via reactive distillation has potential for capital cost and energy requirement savings. However, combination of reaction and distillation on a single column makes reactive distillation process a very complex multivariable system with high non-linearity of process and strong interaction between process variables. This study investigates a multivariable model predictive control (MPC) based on two-point temperature control strategy for the DME reactive distillation column to maintain the purities of both product streams. The process model is estimated by a first order plus dead time model. The DME and water purity is maintained by controlling a stage temperature in rectifying and stripping section, respectively. The result shows that the model predictive controller performed faster responses compared to conventional PI controller that are showed by the smaller ISE values. In addition, the MPC controller is able to handle the loop interactions well.

A transparent vacuum window for high-intensity pulsed beams

CERN Document Server

Monteil, M; Veness, R

2011-01-01

The HiRadMat (High-Radiation to Materials) facility Ill will allow testing of accelerator components, in particular those of the Large Hadron Collider (LHC) at CERN, under the impact of high-intensity pulsed beams. To reach this intensity range, the beam will be focused on a focal point where the target to be tested is located. A 60 mm aperture vacuum window will separate the vacuum of the beam line which is kept under high vacuum 10(-8) mbar, from the test area which is at atmospheric pressure. This window has to resist collapse due to beam passage. The high-intensity of the beam means that typical materials used for standard vacuum windows (such as stainless steel, aluminium and titanium alloy) cannot endure the energy deposition induced by the beam passage. Therefore, a vacuum window has been designed to maintain the differential pressure whilst resisting collapse due to the beam impact on the window. In this paper, we will present calculations of the energy transfer from beam to window, the design of the ...

Reference test methods for total water in lint cotton by Karl Fischer Titration and low temperature distillation

Science.gov (United States)

In a study of comparability of total water contents (%) of conditioned cottons by Karl Fischer Titration (KFT) and Low Temperature Distillation (LTD) reference methods, we demonstrated a match of averaged results based on a large number of replications and weighing the test specimens at the same tim...

Modification of Ultra-High Vacuum Surfaces Using Free Radicals

CERN Document Server

Vorlaufer, G

2002-01-01

In ultra-high vacuum systems outgassing from vacuum chamber walls and desorption of surface adsorbates are usually the factors which determine pressure and residual gas composition. In particular in beam vacuum systems of accelerators like the LHC, where surfaces are exposed to intense synchrotron radiation and bombardment by energetic ions and electrons, surface properties like the molecular desorption yield or secondary electron yield can strongly influence the performance of the accelerator. Well-established treatment methods like vacuum bake-out or glow-discharge cleaning have been successfully applied in the past to condition ultra-high vacuum surfaces, but these methods are sometimes difficult to carry out, for example if the vacuum chambers are not accessible. In this work, an alternative treatment method is investigated. This method is based on the strong chemical reactivity of free radicals, electrically neutral fragments of molecules. Free radicals (in the case of this work, nitrogen and oxygen radi...

RF HEATING AND TEMPERATURE OSCILLATIONS DUE TO A SMALL GAP IN A PEP-II VACUUM CHAMBER

International Nuclear Information System (INIS)

Novokhatski, Alexander

2003-01-01

Wake fields excited in a small gap of a vacuum chamber by ampere beams can have enough amplitude to heat the chamber. The electric component of these fields can be above the arcing limit. Usually flange connections in a vacuum chamber contain a vacuum gasket and an inner RF gasket. If a small gap occurs between the RF gasket and flange surface, wake fields can heat the flanges. The flanges are usually made of stainless steel, which efficiently absorbs RF power. Some flanges consist of two parts (like a vacuum valve flange) and are mechanically connected but have poor thermal contact. A temperature rise can lengthen the inner part of the flange and make firmer the thermal contact to the outer part of the flange. The heat will then flow to the outer part of the flange, which is air and water-cooled. This cooling lowers the flange temperature and the thermal contact becomes poor again. This ''quasi'' periodic mechanism can explain the nature of temperature oscillations observed at several locations in PEP-II, the SLAC B-factory

Method of distilling organic materials

Energy Technology Data Exchange (ETDEWEB)

Gustafsson, E G.T.

1921-11-11

In the distillation of organic materials, by means of coursing heated gases through the distillation chamber, that can be heated by other means also, a method is given by which the hot gases coming from the distillation chamber are cooled in one or more heat-absorbent devices (for example, in spray coolers, condensers and/or water). The greater part of the products or constituents condensable at ordinary temperature are separated from the vapors and gases, and thereafter the gases should be passed through the distillation chamber after the necessary additional heating in special heaters, as one or more heat producers, suitably of the same construction as the heat absorbers, for heating and saturation with steam by means of warm condensate and/or water obtained fully or partly from the heat absorbers, possibly after separation of tar or oil from them. The patent has 11 other claims.

Catalytic distillation process

Science.gov (United States)

Smith, L.A. Jr.

1982-06-22

A method is described for conducting chemical reactions and fractionation of the reaction mixture comprising feeding reactants to a distillation column reactor into a feed zone and concurrently contacting the reactants with a fixed bed catalytic packing to concurrently carry out the reaction and fractionate the reaction mixture. For example, a method for preparing methyl tertiary butyl ether in high purity from a mixed feed stream of isobutene and normal butene comprising feeding the mixed feed stream to a distillation column reactor into a feed zone at the lower end of a distillation reaction zone, and methanol into the upper end of said distillation reaction zone, which is packed with a properly supported cationic ion exchange resin, contacting the C[sub 4] feed and methanol with the catalytic distillation packing to react methanol and isobutene, and concurrently fractionating the ether from the column below the catalytic zone and removing normal butene overhead above the catalytic zone.

Solar Aluminum Production by Vacuum Carbothermal Reduction of Alumina—Thermodynamic and Experimental Analyses

Science.gov (United States)

Kruesi, M.; Galvez, M. E.; Halmann, M.; Steinfeld, A.

2011-02-01

Thermochemical equilibrium calculations indicate the possibility of significantly lowering the onset temperature of aluminum vapor formation via carbothermal reduction of Al2O3 by decreasing the total pressure, enabling its vacuum distillation while bypassing the formation of undesired by-products Al2O, Al4C3, and Al-oxycarbides. Furthermore, the use of concentrated solar energy as the source of high-temperature process heat offers considerable energy savings and reduced concomitant CO2 emissions. When the reducing agent is derived from a biomass source, the solar-driven carbothermal reduction is CO2 neutral. Exploratory experimental runs using a solar reactor were carried out at temperatures in the range 1300 K to 2000 K (1027 °C to 1727 °C) and with total pressures in the range 3.5 to 12 millibar, with reactants Al2O3 and biocharcoal directly exposed to simulated high-flux solar irradiation, yielding up to 19 pct Al by the condensation of product gases, accompanied by the formation of Al4C3 and Al4O4C within the crucible. Based on the measured CO generation, integrated over the duration of the experimental run, the reaction extent reached 55 pct at 2000 K (1727 °C).

Preparation of High-Grade Powders from Tomato Paste Using a Vacuum Foam Drying Method.

Science.gov (United States)

Sramek, Martin; Schweiggert, Ralf Martin; van Kampen, Andreas; Carle, Reinhold; Kohlus, Reinhard

2015-08-01

We present a rapid and gentle drying method for the production of high-grade tomato powders from double concentrated tomato paste, comparing results with powders obtained by foam mat air drying and freeze dried powders. The principle of this method consists of drying tomato paste in foamed state at low temperatures in vacuum. The formulations were dried at temperatures of 50, 60, and 70 °C and vacuum of 200 mbar. Foam stability was affected by low serum viscosity and the presence of solid particles in tomato paste. Consequently, serum viscosity was increased by maltodextrin addition, yielding optimum stability at tomato paste:maltodextrin ratio of 2.4:1 (w/w) in dry matter. Material foamability was improved by addition of 0.5% (w/w, fresh weight) egg white. Because of solid particles in tomato paste, foam air filling had to be limited to critical air volume fraction of Φ = 0.7. The paste was first pre-foamed to Φ = 0.2 and subsequently expanded in vacuo. After drying to a moisture content of 5.6% to 7.5% wet base (w.b.), the materials obtained were in glassy state. Qualities of the resulting powders were compared with those produced by freeze and air drying. Total color changes were the least after vacuum drying, whereas air drying resulted in noticeable color changes. Vacuum foam drying at 50 °C led to insignificant carotenoid losses, being equivalent to the time-consuming freeze drying method. In contrast, air drying caused lycopene and β-carotene losses of 18% to 33% and 14% to 19% respectively. Thus, vacuum foam drying enables production of high-grade tomato powders being qualitatively similar to powders obtained by freeze drying. © 2015 Institute of Food Technologists®

Ceramics for high temperature applications

International Nuclear Information System (INIS)

Mocellin, A.

1977-01-01

Problems related to materials, their fabrication, properties, handling, improvements are examined. Silicium nitride and silicium carbide are obtained by vacuum hot-pressing, reaction sintering and chemical vapour deposition. Micrographs are shown. Mechanical properties i.e. room and high temperature strength, creep resistance fracture mechanics and fatigue resistance. Recent developments of pressureless sintered Si C and the Si-Al-O-N quaternary system are mentioned

Gamma ray scanning as troubleshooting tool for unusual and large diameter refinery vacuum columns

International Nuclear Information System (INIS)

Sarkar, T.K.; Chawla, R.; Banik, S.; Chopra, S.J.; Singh, G.; Pant, H.J.; Sreeramakrishnan, P.; Dhar, D.C.; Pushpangathan, P.N.; Sharma, V.K.

1997-01-01

Gamma scanning of trayed and packed columns is widely used to obtain density profiles and identify on-line problems such as: damaged tray or packing, foaming, flooding, maldistribution, weeping and entrainment, etc. However, scanning of large diameter tray or packed columns requires expertise in handling high intensity gamma sources along with thorough understanding of distillation engineering. Engineers India Limited and the Bhabha Atomic Research Centre undertook scanning of two such large diameter (8.4 m and 7.4 m) trayed and packed refinery vacuum distillation columns and successfully diagnosed the problems and suggested remedial actions. Radiography testing of small diameter columns can be used to confirm gamma scanning results. One such example for ammonia separator column is given

New design of a variable-temperature ultrahigh vacuum scanning tunneling microscope

NARCIS (Netherlands)

Mugele, Friedrich Gunther; Rettenberger, A.; Boneberg, J.; Leiderer, P.

1998-01-01

We present the design of a variable-temperature ultrahigh vacuum (UHV) scanning tunneling microscope which can be operated between 20 and 400 K. The microscope is mounted directly onto the heat exchanger of a He continuous flow cryostat without vibration isolation inside the UHV chamber. The coarse

Design and construction of a Fresnel linear distiller

International Nuclear Information System (INIS)

Saettone, E.

2014-01-01

It was designed a Fresnel linear distiller based on optical calculations obtained from taking into account Lima's latitude value, Earth inclination angle and heat absorber cavity's dimensions. The 5.6 m 2 reflective surface concentrator of the distiller was constructed with 32 plane rectangular mirrors; the heat absorber cavity was made with a rectangular blackened aluminum tube 1 m long and installed 2.5 m over the plane of mirrors. The Fresnel linear distiller was installed at the University of Lima and experimental tests were performed during no cloudy summer days. There were measured ambient temperature, heat absorber cavity temperature, radiant flux and fresh water volume. From this, it was obtained a production of 0.89 liters/hour and 0.79 L/m 2 , and it was calculated a total performance of 34.5% in desalting sea water. Finally, it is presented a comparison between Fresnel linear distiller (FLD) and parabolic trough distiller (PTD) with similar dimensions and characteristics. It is obtained that the last one produced almost 32% more fresh water than the former, but at the same time, the FLD is almost 20% cheaper than PTD. However, water cost production with both distillers using is almost the same. (author)

Time, Temperature and Amount of Distilled Water Effects on the Purity and Yield of Bis(2-hydroxyethyl Terephthalate Purification System

Directory of Open Access Journals (Sweden)

H.W. Goh

2015-07-01

Full Text Available Polyethylene terephthalate (PET bottle is one of the common plastic wastes existed in the municipal solid waste in Malaysia. One alternative to solve the abundant of PET wastes is chemical recycling of the wastes to produce a value added product. This technology not only can decrease the PET wastes in landfill sites but also can produce many useful recycled PET products. Bis(2-hydroxyethyl terephthalate (BHET obtained from glycolysis reaction of PET waste was purified using crystallization process. The hot distilled water was added to glycolysis product followed by cooling and filtration to extract BHET in white solid form from the product. The effect of three operating conditions namely crystallization time, crystallization temperatures and amount of distilled water used to the yield of crystallization process were investigated. The purity of crystallization products were analyzed using HPLC and DSC. The optimum conditions of 3 hours crystallization time, 2 °C crystallization temperature and 5:1 mass ratio of distilled water used to glycolize solid gave the highest yield and purity of the crystallization process. © 2015 BCREC UNDIP. All rights reservedReceived: 12nd August 2014; Revised: 4th February 2015; Accepted: 5th February 2015How to Cite: Goh, H.W., Salmiaton, A., Abdullah, N., Idris, A. (2015. Time, Temperature and Amount of Distilled Water Effects on the Purity and Yield of Bis(2-hydroxyethyl Terephthalate Purification System. Bulletin of Chemical Reaction Engineering & Catalysis, 10 (2: 143-154. (doi:10.9767/bcrec.10.2.7195.143-154 Permalink/DOI: http://dx.doi.org/10.9767/bcrec.10.2.7195.143-154  

Temperature field and thermal stress analysis of the HT-7U vacuum vessel

International Nuclear Information System (INIS)

Song Yuntao; Yao Damao; Wu Songtao; Weng Peide

2000-01-01

The HT-7U vacuum vessel is an all-metal-welded double-wall interconnected with toroidal and poloidal stiffening ribs. The channels formed between the ribs and walls are filled with boride water as a nuclear shielding. On the vessel surface facing the plasma are installed cable-based Ohmic heaters. Prior to plasma operation the vessel is to be baked out and discharge cleaned at about 250 degree C. During baking out the non-uniformity of temperature distribution on the vacuum vessel will bring about serious thermal stress that can damage the vessel. In order to determine and optimize the design of the HT-7U vacuum vessel, a three-dimensional finite element model was performed to analyse its temperature field and thermal stress. the maximal thermal stress appeared on the round of lower vertical port and maximal deformation located just on the region between the upper vertical port and the horizontal port. The results show that the reinforced structure has a good capability of withstanding the thermal loads

Study on Gas-liquid Falling Film Flow in Internal Heat Integrated Distillation Column

Science.gov (United States)

Liu, Chong

2017-10-01

Gas-liquid internally heat integrated distillation column falling film flow with nonlinear characteristics, study on gas liquid falling film flow regulation control law, can reduce emissions of the distillation column, and it can improve the quality of products. According to the distribution of gas-liquid mass balance internally heat integrated distillation column independent region, distribution model of heat transfer coefficient of building internal heat integrated distillation tower is obtained liquid distillation falling film flow in the saturated vapour pressure of liquid water balance, using heat transfer equation and energy equation to balance the relationship between the circulating iterative gas-liquid falling film flow area, flow parameter information, at a given temperature, pressure conditions, gas-liquid flow falling film theory makes the optimal parameters to achieve the best fitting value with the measured values. The results show that the geometric gas-liquid internally heat integrated distillation column falling film flow heat exchange area and import column thermostat, the average temperature has significant. The positive correlation between the heat exchanger tube entrance due to temperature difference between inside and outside, the heat flux is larger, with the increase of internal heat integrated distillation column temperature, the slope decreases its temperature rise, which accurately describes the internal gas-liquid heat integrated distillation tower falling film flow regularity, take appropriate measures to promote the enhancement of heat transfer. It can enhance the overall efficiency of the heat exchanger.

HIGH PRODUCTIVITY VACUUM BLASTING SYSTEM

International Nuclear Information System (INIS)

McPhee, William S.

2001-01-01

The Department of Energy (DOE) needs improved technologies to decontaminate large areas of both concrete and steel surfaces. The technology should have high operational efficiency, minimize exposures to workers, and produce low levels of secondary waste. In order to meet the DOE's needs, an applied research and development project for the improvement of a current decontamination technology, Vacuum Blasting, is proposed. The objective of this project is to improve the productivity and lower the expense of the existing vacuum blasting technology which has been widely used in DOE sites for removing radioactive contamination, PCBs, and lead-based paint. The proposed work would increase the productivity rate and provide safe and cost-effective decontamination of the DOE sites

Comprehending the structure of a vacuum vessel and in-vessel components of fusion machines. 1. Comprehending the vacuum vessel structure

International Nuclear Information System (INIS)

Onozuka, Masanori; Nakahira, Masataka

2006-01-01

The functions, conditions and structure of vacuum vessel using tokamak fusion machines are explained. The structural standard and code of vacuum vessel, process of vacuum vessel design, and design of ITER vacuum vessel are described. Production and maintenance of ultra high vacuum, confinement of radioactive materials, support of machines in vessel and electromagnetic force, radiation shield, plasma vertical stability, one-turn electric resistance, high temperature baking heat and remove of nuclear heat, reduce of troidal ripple, structural standard, features of safety of nuclear fusion machines, subjects of structural standard of fusion vacuum vessel, design flow of vacuum vessel, establishment of radial build, selections of materials, baking and cooling method, basic structure, structure of special parts, shield structure, and of support structure, and example of design of structure, ITER, are stated. (S.Y.)

An improvement study on the closed chamber distillation system for recovery of renewable salts from salt wastes containing radioactive rare earth compounds

International Nuclear Information System (INIS)

Eun, H.C.; Cho, Y.Z.; Lee, T.K.; Kim, I.T.; Park, G.I.; Lee, H.S.

2013-01-01

In this paper, an improvement study on the closed chamber distillation system for recovery of renewable salts from salt wastes containing radioactive rare earth compounds was performed to determine optimum operating conditions. It was very important to maintain the pressure in the distillation chamber below 10 Torr for a high efficiency (salt recovery >99 %) of the salt distillation. This required increasing the salt vaporization and condensation rates in the distillation system. It was confirmed that vaporization and condensation rates could be improved controlling the given temperature of top of the condensation chamber. In the distillation tests of the salt wastes containing rare earth compounds, the operation time at a given temperature was greatly reduced changing the given temperature of top of the condensation chamber from 780 to 700 deg C. (author)

Investigations into the high temperature brazing of type NiCr20Ti nickel alloy under vacuum conditions

International Nuclear Information System (INIS)

Zaremba, P.

1977-01-01

Joints made from NiCr20Ti material brazed in a vacuum furnace (brazing gap width 10, 30 and 50 μm, brazing temperature 1,040 0 C and 1,100 0 C) were tensile tested and subjected to metallographic investigation. Furthermore, the angle of wetting and the pattern of hardness across the brazed joint was established. The results obtained showed that, amongst other things, a relationship existed between the micro-hardness at the centre of the joint and the tensile strength of the brazed joint itself. (orig.) [de

Production of high quality distillate to meet a fit-for-purpose boiler feedwater specification

Energy Technology Data Exchange (ETDEWEB)

Minnich, K. [Veolia Water Solutions Oil and Gas, Calgary, AB (Canada); Neu, D. [Veolia Water Solutions and Technologies/HPD, Pewaukee, WI (United States); Drone, J.L. [Veolia Water Solutions and Technologies/HPD, Plainfield, IL (United States)

2009-07-01

Veolia Water Solutions and Technologies has significant experience managing boiler water chemistry and is the world's largest manufacturer of evaporation systems. The company has conducted extensive testing and analysis for produced water evaporation distillate from multiple facilities. In order to produce boiler feed water, evaporation of produced water is used at several steam assisted gravity drainage (SAGD) facilities. There are no official guidelines for the required quality of evaporator distillate to feed a once through steam generator (OTSG) or high pressure industrial watertube boiler (IWT) that will produce injection steam. This paper presented a basis for a fit-for-purpose specification for IWT boilers as well as data on the performance of a Vapor Washer, which produces high quality distilled water that meets fit-for-purpose specifications even during normal variations in feed conditions. Specifically, the paper discussed boiler water requirements for steam injection IWTs; the quality of distillate from a produced water evaporator; the benefits of vapour washing to maintain distillate quality; and suggested boiler chemistry limits for a fit-for-purpose specification. Oxygen, iron, and copper were discussed as being implicated with corrosion and reaction in boilers. Hardness contaminants such as calcium and magnesium were also presented. Suggested limits for boiler water in the fit-for-purpose specification were also presented for silica, total alkalinity, free OH alkalinity, and total dissolved solids in steam. It was concluded that foaming episodes can occur in produced water evaporators due to normal variations, and the distillate can fail to meet the fit-for-purpose specification during foam upsets. 3 refs., 9 figs.

Removing antimony from waste lead storage batteries alloy by vacuum displacement reaction technology.

Science.gov (United States)

Liu, Tiantian; Qiu, Keqiang

2018-04-05

With the wide application of lead acid battery, spent lead acid battery has become a serious problem to environmental protection and human health. Though spent battery can be a contaminant if not handled properly, it is also an important resource to obtain refined lead. Nowadays, the Sb-content in lead storage batteries is about 0.5-3 wt%, which is higher than the Sb-content in the crude lead. However, there are few reports about the process of removing antimony from high-antimony lead bullion. In this study, vacuum displacement reaction technology, a new process for removing antimony from high-antimony lead melts, was investigated. During this process, lead oxide was added to the system and antimony from lead melts was converted into antimony trioxide, which easily was evaporated under vacuum so that antimony was removed from lead melts. The experimental results demonstrated that Sb-content in lead melts decreased from 2.5% to 23 ppm under following conditions: mass ratio of PbO/lead bullion of 0.33, residual gas pressure of 30 Pa, melt temperature of 840 °C, reaction time of 60 min. The distillate gotten can be used as by-product to produce antimony white. Moreover, this study is of importance to recycling of waste lead storage batteries alloy. Copyright © 2018 Elsevier B.V. All rights reserved.

Testing of improved polyimide actuator rod seals at high temperature and under vacuum conditions for use in advanced aircraft hydraulic systems

Science.gov (United States)

Sellereite, B. K.; Waterman, A. W.; Nelson, W. G.

1974-01-01

Polyimide second-stage rod seals were evaluated to determine their suitability for applications in space station environments. The 6.35-cm (2.5-in.)K-section seal was verified for thermal cycling operation between room temperature and 478 K (400 F) and for operation in a 133 micron PA(0.000001 mm Hg) vacuum environment. The test seal completed the scheduled 96 thermal cycles and 1438 hr in vacuum with external rod seal leakage well within the maximum allowable of two drops per 25 actuation cycles. At program completion, the seals showed no signs of structural degradation. Posttest inspection showed the seals retained a snug fit against the shaft and housing walls, indicating additional wear life capability. Evaluation of a molecular flow section during vacuum testing, to inhibit fluid loss through vaporization, showed it to be beneficial with MIL-H-5606, a petroleum-base fluid, in comparison with MIL-H-83282, a synthetic hydrocarbon-base fluid.

Vacuum-integrated electrospray deposition for highly reliable polymer thin film.

Science.gov (United States)

Park, Soohyung; Lee, Younjoo; Yi, Yeonjin

2012-10-01

Vacuum electrospray deposition (ESD) equipment was designed to prepare polymer thin films. The polymer solution can be injected directly into vacuum system through multi-stage pumping line, so that the solvent residues and ambient contaminants are highly reduced. To test the performance of ESD system, we fabricated organic photovoltaic cells (OPVCs) by injecting polymer solution directly onto the substrate inside a high vacuum chamber. The OPVC fabricated has the structure of Al∕P3HT:PCBM∕PEDOT:PSS∕ITO and was optimized by varying the speed of solution injection and concentration of the solution. The power conversion efficiency (PCE) of the optimized OPVC is 3.14% under AM 1.5G irradiation without any buffer layer at the cathode side. To test the advantages of the vacuum ESD, we exposed the device to atmosphere between the deposition steps of the active layer and cathode. This showed that the PCE of the vacuum processed device is 24% higher than that of the air exposed device and confirms the advantages of the vacuum prepared polymer film for high performance devices.

Treatment of Simulated Coalbed Methane Produced Water Using Direct Contact Membrane Distillation

Directory of Open Access Journals (Sweden)

Dong-Wan Cho

2016-05-01

Full Text Available Expolitation of coalbed methane (CBM involves production of a massive amount saline water that needs to be properly managed for environmental protection. In this study, direct contact membrane distillation (DCMD was utilized for treatment of CBM-produced water to remove saline components in the water. Simulated CBM waters containing varying concentrations of NaCl (1, 20, and 500 mM and NaHCO3 (1 and 25 mM were used as feed solutions under two transmembrane temperatures (Δ40 and 60 °C. In short-term distillation (~360 min, DCMD systems showed good performance with nearly 100% removal of salts for all solutes concentrations at both temperatures. The permeate flux increased with the feed temperature, but at a given temperature, it remained fairly stable throughout the whole operation. A gradual decline in permeate flux was observed at Δ60 °C at high NaHCO3 concentration (25 mM. In long-term distillation (5400 min, the presence of 25 mM NaHCO3 further decreased the flux to 25%–35% of the initial value toward the end of the operation, likely due to membrane fouling by deposition of Ca-carbonate minerals on the pore openings. Furthermore, pore wetting by the scalants occurred at the end of the experiment, and it increased the distillate conducitivity to 110 µS·cm−1. The precipitates formed on the surface were dominantly CaCO3 crystals, identified as aragonite.

Development on the cryogenic hydrogen isotopes distillation process technology for tritium removal (Final report)

International Nuclear Information System (INIS)

Sung, Ki Woung; Kim, Yong Ik; Na, Jeong Won; Ku, Jae Hyu; Kim, Kwang Rak; Jeong, Yong Won; Lee, Han Soo; Cho, Young Hyun; Ahn, Do Hee; Baek, Seung Woo; Kang, Hee Seok; Kim, You Sun

1995-12-01

While tritium exposure to the site-workers in Wolsung NPP is up to about 40% of the total personnel exposure, Ministry of Science and Technology has asked tritium removal facility for requirement of post heavy-water reactor construction. For the purpose of essential removal of tritium from the Wolsung heavy-water reactor system, a preliminary study on the cryogenic Ar-N 2 and H 2 -D 2 distillation process for development of liquid-phase catalytic exchange cryogenic hydrogen distillation process technology. The Ar-N 2 distillation column showed good performance with approximately 97% of final Ar concentration, and a computer simulation code was modified using these data. A simulation code developed for cryogenic hydrogen isotopes (H 2 , HD, D 2 , HT, DT, T 2 ) distillation column showed good performance after comparison with the result of a JAERI code, and a H 2 -D 2 distillation column was made. Gas chromatography for hydrogen isotopes analysis was established using a vacuum sampling loop, and a schematic diagram of H 2 -D 2 distillation process was suggested. A feasibility on modification of H 2 -D 2 distillation process control system using Laser Raman Spectroscopy was studied, and the consideration points for tritium storage system for Wolsung tritium removal facility was suggested. 31 tabs., 79 figs., 68 refs. (Author)

Height determination at the transfer unit in isotopic distillation of hydrogen on type B7 ordered column packing

International Nuclear Information System (INIS)

Pop, F.; Croitoru, C.; Peculea, M.

2001-01-01

Owing to the low pressure drop implied by ordered column packings these are often utilized for vacuum distillations and separation of mixtures in which the important component occurs at a very low concentration, as for instance is the case of water, deuterium or oxygen isotopic distillation. The paper presents a model for determination of the height of transfer unit (HTU) in the hydrogen isotopic distillation installation, equipped with ordered column packing of B7 type. The computed values for HUT based on the analogy between heat, moment and mass transfer, were compared with the experimental data

Plant-wide control of coupled distillation columns with partial condensers

International Nuclear Information System (INIS)

Ebrahimzadeh, Edris; Baxter, Larry L.

2016-01-01

Highlights: • Extractive distillation system for CO_2–ethane azeotrope separation. • Control of distillation column systems that have interconnected partial condenser and total condenser columns. • Single-end temperature control of distillation columns. • Aspen Dynamics tools applied for rigorous steady-state and dynamic simulations. - Abstract: Conventional distillation control processes use vapor distillate flowrate to control column pressure and condenser heat removal to control the reflux drum level. These intuitive control systems work well for isolated columns or columns with total condensers. However, these controls are not effective when columns with partial condensers occur in series. The pressure and reflux drum level interact in such systems in ways that defeat conventional control systems, rendering them unable to maintain product purities in the presence of large feed flowrate and composition disturbances. This investigation documents a plant-wide control structure that can address this issue by controlling pressure through reflux heat removal rate and reflux drum level by reflux flow rate. This control system demonstrates its capability to handle large disturbances in throughput and feed composition through a series of Aspen simulations. This alternative system is no more complicated than the conventional system and should work on distillation columns of nearly all designs, not just the coupled partial condenser designs for which it is essential. Common natural gas processing provides a specific example of this alternative control system. Natural gas commonly includes high concentrations of CO_2 that must be removed prior to pipeline or LNG distribution. The existence of a minimum-boiling temperature azeotrope between ethane, virtually always present in natural gas, and carbon dioxide complicates the separation of CO_2 from the hydrocarbons. This separation commonly employs extractive distillation with high-molecular-weight hydrocarbons. Our

Mass and heat transfer on B7 structured packing in the separation of hydrogen isotopes by distillation

International Nuclear Information System (INIS)

Croitoru, C.; Pop, F.; Titescu, Gh.; Culcer, M.; Iliescu, M.; Stefanescu, I.; Trancota, D.; Peculea, M.

2002-01-01

The paper presents theoretical and experimental data concerning mass and heat transfer on B7 ordered packing, at deuterium separation by distillation. The first section of the paper is dedicated to the mass transfer study of hydrogen distillation, while the second section deals with mass and heat transfer in water distillation. A mathematical model was worked out and compared with experimental data, obtained from two laboratory distillation plants for deuterium separation. From the first plant experimental data concerning B7 ordered packing efficiency of hydrogen cryogenic distillation at 250 deg. C level were obtained. Data concerning mass and heat transfer on the same packing in deuterium separation by water vacuum distillation at 60 deg. C level were obtained in the second plant. HUT values, mass and heat transfer coefficients both theoretically evaluated and experimentally determined were found to be comparable with those obtained from chemical industry separation processes. The fact justifies the use of multi-tubular column model for description of transfer processes in distillation columns equipped with B7 structured packing. (authors)

Control of distributed heat transfer mechanisms in membrane distillation plants

KAUST Repository

Laleg-Kirati, Taous-Meriem

2017-01-05

Various examples are provided that are related to boundary control in membrane distillation (MD) processes. In one example, a system includes a membrane distillation (MD) process comprising a feed side and a permeate side separated by a membrane boundary layer; and processing circuitry configured to control a water production rate of the MD process based at least in part upon a distributed heat transfer across the membrane boundary layer. In another example, a method includes determining a plurality of estimated temperature states of a membrane boundary layer separating a feed side and a permeate side of a membrane distillation (MD) process; and adjusting inlet flow rate or inlet temperature of at least one of the feed side or the permeate side to maintain a difference temperature along the membrane boundary layer about a defined reference temperature based at least in part upon the plurality of estimated temperature states.

High Vacuum Techniques for Anionic Polymerization

KAUST Repository

Ratkanthwar, Kedar; Hadjichristidis, Nikolaos; Mays, Jimmy

2015-01-01

Anionic polymerization high vacuum techniques (HVTs) are the most suitable for the preparation of polymer samples with well-defined complex macromolecular architectures. Though HVTs require glassblowing skill for designing and making polymerization

Multistage charged particle accelerator, with high-vacuum insulation

International Nuclear Information System (INIS)

Holl, P.

1976-01-01

A multistage charged-particle accelerator for operating with accelerating voltages higher than 150 kV is described. The device consists essentially of a high-voltage insulator, a source for producing charged particles, a Wehnelt cylinder, an anode, and a post-accelerating tube containing stack-wise positioned post-accelerating electrodes. A high vacuum is used for insulating the parts carrying the high voltages, and at least one cylindrical screen surrounding these parts is interposed between them and the vacuum vessel, which can itself also function as a cylindrical screen

Extremely-high vacuum pressure measurement by laser ionization

International Nuclear Information System (INIS)

Kokubun, Kiyohide

1991-01-01

Laser ionization method has the very high sensitivity for detecting atoms and molecules. Hurst et al. successfully detected a single Cs atom by means of resonance ionization spectroscopy developed by them. Noting this high sensitivity, the authors have attempted to apply the laser ionization method to measure gas pressure, particularly in the range down to extremely high vacuum. At present, hot cathode ionization gauges are used for measuring gas pressure down to ultrahigh vacuum, however, those have a number of disadvantages. The pressure measurement using lasers does not have such disadvantages. The pressure measurement utilizing the laser ionization method is based on the principle that when laser beam is focused through a lens, the amount of atom or molecule ions generated in the focused space region is proportional to gas pressure. In this paper, the experimental results are presented on the nonresonant multiphoton ionization characteristics of various kinds of gases, the ion detection system with high sensitivity and an extremely high vacuum system prepared for the laser ionization experiment. (K.I.)

A 10 mK scanning tunneling microscope operating in ultra high vacuum and high magnetic fields.

Science.gov (United States)

Assig, Maximilian; Etzkorn, Markus; Enders, Axel; Stiepany, Wolfgang; Ast, Christian R; Kern, Klaus

2013-03-01

We present design and performance of a scanning tunneling microscope (STM) that operates at temperatures down to 10 mK providing ultimate energy resolution on the atomic scale. The STM is attached to a dilution refrigerator with direct access to an ultra high vacuum chamber allowing in situ sample preparation. High magnetic fields of up to 14 T perpendicular and up to 0.5 T parallel to the sample surface can be applied. Temperature sensors mounted directly at the tip and sample position verified the base temperature within a small error margin. Using a superconducting Al tip and a metallic Cu(111) sample, we determined an effective temperature of 38 ± 1 mK from the thermal broadening observed in the tunneling spectra. This results in an upper limit for the energy resolution of ΔE = 3.5 kBT = 11.4 ± 0.3 μeV. The stability between tip and sample is 4 pm at a temperature of 15 mK as demonstrated by topography measurements on a Cu(111) surface.

Destructive distillation

Energy Technology Data Exchange (ETDEWEB)

Mitting, E K

1882-08-09

The broken-up shale is placed in cast-iron retorts, heated externally, having exit tubes placed at a low level. Each retort is provided with a steam-pipe with a regulating-cock outside, the pipe being carried around the walls of the retort in a spiral or zig-zag way to ensure superheating of the steam, perforations being made in the pipe to allow exit for the steam into the retort. The steam, which may if desired be superheated before entrance, is passed into the retort when the latter has attained a temperature of from 210 to 250/sup 0/C and the passage is continued while the temperature rises, as long as distillation goes on. The exit pipe to the retort leads to a condenser of much condensing-surface, provided with a drag obtained by an exhausting steam jet or otherwise. The distilled products consist of tar, oils, wax, ammoniacal water (stated to be in greater proportion through the use of the process), and lighting and heating gas. The latter gas goes through a scrubber to a gasholder. The carbonaceous residue in the retort is discharged when cooled below a red heat, into sheet-iron cylinders, with tightly fitting lids, to avoid as far as possible contact with the atmosphere.

Use of solar distillation for olive mill wastewater drying and recovery of polyphenolic compounds.

Science.gov (United States)

Sklavos, Sotirios; Gatidou, Georgia; Stasinakis, Athanasios S; Haralambopoulos, Dias

2015-10-01

Olive mill wastewater (OMW) is characterized by its high organic load and the presence of phenolic compounds. For first time, a solar distillator was used to investigate the simultaneous solar drying of OMW and the recovery of phenolic compounds with antioxidant properties in the distillate. Two experiments were conducted and the role of thermal insulation on the performance of the distiller was studied. The use of insulation resulted to higher temperatures in the distillator (up to 84.3 °C and 78.5 °C at the air and sludge, respectively), shorter period for OMW dewatering (14 days), while it increased the performance of distillator by 26.1%. Chemical characterization of the distillate showed that pH and COD concentration gradually decreased during the experiments, whereas an opposite trend was noticed for conductivity and total phenols concentration. Almost 4% of the total phenols found initially in OMW were transferred to the distillate when an insulated solar distillator was used. Gas chromatographic analysis of collected distillates confirmed the presence of tyrosol in all samples; whereas hydroxytyrosol was found only in fresh collected distillate samples. Further experiments should be conducted to optimize the process and quantify the concentrations of recovered phenolic compounds. Copyright © 2015 Elsevier Ltd. All rights reserved.

Simultaneous production of high-quality water and electrical power from aqueous feedstock’s and waste heat by high-pressure membrane distillation

NARCIS (Netherlands)

Kuipers, N.J.M.; Hanemaaijer, J.H.; Brouwer, H.; Medevoort, J. van; Jansen, A.; Altena, F.; Vleuten, P. van der; Bak, H.

2015-01-01

A new membrane distillation (MD) concept (MemPower) has been developed for the simultaneous production of high-quality water from various aqueous feedstocks with cogeneration of mechanical power (electricity). Driven by low-grade heat (waste, solar, geothermal, etc.) a pressurized distillate can be

Interferometric study on the mass transfer in cryogenic distillation under magnetic field

Science.gov (United States)

Bao, S. R.; Zhang, R. P.; Y Rong, Y.; Zhi, X. Q.; Qiu, L. M.

2017-12-01

Cryogenic distillation has long been used for the mass production of industrial gases because of its features of high efficiency, high purity, and capability to produce noble gases. It is of great theoretical and practical significance to explore methods to improve the mass transfer efficiency in cryogenic distillation. The negative correlation between the susceptibility of paramagnetic oxygen and temperature provides a new possibility of comprehensive utilization of boiling point and susceptibility differences in cryogenic distillation. Starting from this concept, we proposed a novel distillation intensifying method by using gradient magnetic field, in which the magnetic forces enhance the transport of the oxygen molecules to the liquid phase in the distillation. In this study, a cryogenic testbed was designed and fabricated to study the diffusion between oxygen and nitrogen under magnetic field. A Mach-Zehnder interferometer was used to visualize the concentration distribution during the diffusion process. The mass transfer characteristics with and without magnetic field, in the chamber filled with the magnetized medium, were systematically studied. The concentration redistribution of oxygen was observed, and the stable stratified diffusion between liquid oxygen and nitrogen was prolonged by the non-uniform magnetic field. The experimental results show that the magnetic field can efficiently influence the mass transfer in cryogenic distillation, which can provide a new mechanism for the optimization of air separation process.

Method of controlling a distillatory coulumn in a liquefaction and distillation device for radioactive rare gases

International Nuclear Information System (INIS)

Kimura, Shigeru; Awata, Yoshihisa.

1975-01-01

Object: To automatically and securely perform controlling purity of column bottom liquid, which is most difficult in the liquefaction and distillation device. Structure: In a liquefaction and distillation device for liquefying and separating rare gas krypton in fuel reprocessing gases, a difference in temperature between the column bottom liquid (column top) and the distillation portion is detected so as to maintain temperature in the distillation portion of the distilling column constant, and the vaporization amount of column bottom liquid is varied with the difference in temperature to control purity of the column bottom liquid. (Kamimura, M.)

Distilling solid carbonaceous materials

Energy Technology Data Exchange (ETDEWEB)

Nielsen, H; Laing, B

1926-12-04

In the distillation of solid carbonaceous materials with by-product recovery by direct heating with a gas such as water gas, producer gas, or combustion gas which is passed in counter-flow to the materials, the volume of the gas used is such as to lower the vapor tension of the volatiles to enable the oil vapor to be liberated at temperatures not exceeding 450 to 500/sup 0/C and so that the gaseous mixture may be cooled to from 80 to 100/sup 0/C without causing the highest boiling oil fraction to condense. Coking coals may be subjected to a preliminary heat treatment with gases containing an oxygen content of from 2 to 8 percent to reduce their coking properties, and oxygen may be added to the heating gases to assist the polymerization of resinous bodies. Lubricating oil may be obtained by treating the primary oil with caustic soda to remove tar acids, refining the residue with sulfuric acid, distilling off 25 percent of the refined oil and passing the remainder through a filter press at -5/sup 0/C to extract the paraffin wax. The residue of wax-free oil is distilled to yield a lubricating oil which at normal temperatures has a static coefficient of friction of from .1 to .185. Other specifications are referred to.

HIGH PRODUCTIVITY VACUUM BLASTING SYSTEM

International Nuclear Information System (INIS)

McPhee, William S.

1999-01-01

construct a pre-prototype of the nozzle, blast head with wind curtain, sensors, and dust separator and test this system to assess the performance of the new design under controlled conditions at the contractor's facility. In phase III, the Contractor shall design and construct a prototype of the High Productivity Vacuum Blasting System, based on the results of the pre-prototype design and testing performed. This unit will be a full-scale prototype and will be tested at a designated Department of Energy (DOE) facility. Based on the results, the system performance, the productivity, and the economy of the improved vacuum blasting system will be evaluated

Vacuum amplification of the high-frequency electromagnetic radiation

OpenAIRE

Vilkovisky, G. A.

1998-01-01

When an electrically charged source is capable of both emitting the electromagnetic waves and creating charged particles from the vacuum, its radiation gets so much amplified that only the backreaction of the vacuum makes it finite. The released energy and charge are calculated in the high-frequency approximation. The technique of expectation values is advanced and employed.

Removal of arsenic from contaminated groundwater by solar-driven membrane distillation

International Nuclear Information System (INIS)

Manna, Ajay K.; Sen, Mou; Martin, Andrew R.; Pal, Parimal

2010-01-01

Experimental investigations were carried out on removal of arsenic from contaminated groundwater by employing a new flat-sheet cross flow membrane module fitted with a hydrophobic polyvinylidenefluoride (PVDF) microfiltration membrane. The new design of the solar-driven membrane module in direct contact membrane distillation (DCMD) configuration successfully produced almost 100 per cent arsenic-free water from contaminated groundwater in a largely fouling-free operation while permitting high fluxes under reduced temperature polarization. For a feed flow rate of 0.120 m 3 /h, the 0.13 μm PVDF membrane yielded a high flux of 74 kg/(m 2 h) at a feed water temperature of 40 deg. C and, 95 kg/m 2 h at a feed water temperature of 60 deg. C. The encouraging results show that the design could be effectively exploited in the vast arsenic-affected rural areas of South-East Asian countries blessed with abundant sunlight particularly during the critical dry season. - Solar-driven membrane distillation has the potential of removing arsenic from contaminated groundwater.

Design of the ZTH vacuum liner

International Nuclear Information System (INIS)

Prince, P.P.; Dike, R.S.

1987-01-01

The current status of the ZTh vacuum liner design is covered by this report. ZTH will be the first experiment to be installed in the CPRF (Confinement Physics Research Facility) at the Los Alamos National Laboratory and is scheduled to be operational at the rated current of 4 MA in 1992. The vacuum vessel has a 2.4m major radius and a 40 cm minor radius. Operating parameters which drive the vacuum vessel mechanical design include a 300 C bakeout temperature, an armour support system capable of withstanding 25 kV, a high toroidal resistance, 1250 kPa magnetic loading, a 10 minute cycle time, and high positional accuracy with respect to the conducting shell. The vacuum vessel design features which satisfy the operating parameters are defined

Vacuum system design for the PEP-II B Factory High-Energy Ring

International Nuclear Information System (INIS)

Perkins, C.; Bostic, D.; Daly, E.

1994-06-01

The design of the vacuum system for the PEP-II B Factory High-Energy Ring is reviewed. The thermal design and vacuum requirements are particularly challenging in PEP-II due to high stored beam currents up to 3.0 amps in 1658 bunches. The vacuum chambers for the HER arcs are fabricated by electron beam welding extruded copper sections up to 6 m long. Design of these chambers and the vacuum PumPing configuration is described with results from vacuum and thermal analyses

Tetrasilane and digermane for the ultra-high vacuum chemical vapor deposition of SiGe alloys

International Nuclear Information System (INIS)

Hart, John; Hazbun, Ramsey; Eldridge, David; Hickey, Ryan; Fernando, Nalin; Adam, Thomas; Zollner, Stefan; Kolodzey, James

2016-01-01

Tetrasilane and digermane were used to grow epitaxial silicon germanium layers on silicon substrates in a commercial ultra-high vacuum chemical vapor deposition tool. Films with concentrations up to 19% germanium were grown at temperatures from 400 °C to 550 °C. For all alloy compositions, the growth rates were much higher compared to using mono-silane and mono-germane. The quality of the material was assessed using X-ray diffraction, atomic force microscopy, and spectroscopic ellipsometry; all indicating high quality epitaxial films with low surface roughness suitable for commercial applications. Studies of the decomposition kinetics with regard to temperature were performed, revealing an unusual growth rate maximum between the high and low temperature deposition regimes. - Highlights: • Higher order precursors tetrasilane and digermane • Low temperature deposition • Thorough film characterization with temperature • Arrhenius growth rate peak

Perspectives of data-driven LPV modeling of high-purity distillation columns

NARCIS (Netherlands)

Bachnas, A.A.; Toth, R.; Mesbah, A.; Ludlage, J.H.A.

2013-01-01

Abstract—This paper investigates data-driven, Linear- Parameter-Varying (LPV) modeling of a high-purity distillation column. Two LPV modeling approaches are studied: a local approach, corresponding to the interpolation of Linear Time- Invariant (LTI) models identified at steady-state purity levels,

27 CFR 30.1 - Gauging of distilled spirits.

Science.gov (United States)

2010-04-01

... correcting hydrometer indications at temperatures between 0 and 100 degrees Fahrenheit to true proof. If distilled spirits contain dissolved solids, temperature correction of the hydrometer reading by the use of...

NSTX High Temperature Sensor Systems

International Nuclear Information System (INIS)

McCormack, B.; Kugel, H.W.; Goranson, P.; Kaita, R.

1999-01-01

The design of the more than 300 in-vessel sensor systems for the National Spherical Torus Experiment (NSTX) has encountered several challenging fusion reactor diagnostic issues involving high temperatures and space constraints. This has resulted in unique miniature, high temperature in-vessel sensor systems mounted in small spaces behind plasma facing armor tiles, and they are prototypical of possible high power reactor first-wall applications. In the Center Stack, Divertor, Passive Plate, and vessel wall regions, the small magnetic sensors, large magnetic sensors, flux loops, Rogowski Coils, thermocouples, and Langmuir Probes are qualified for 600 degrees C operation. This rating will accommodate both peak rear-face graphite tile temperatures during operations and the 350 degrees C bake-out conditions. Similar sensor systems including flux loops, on other vacuum vessel regions are qualified for 350 degrees C operation. Cabling from the sensors embedded in the graphite tiles follows narrow routes to exit the vessel. The detailed sensor design and installation methods of these diagnostic systems developed for high-powered ST operation are discussed

Development on the cryogenic hydrogen isotopes distillation process technology for tritium removal (Final report)

Energy Technology Data Exchange (ETDEWEB)

Sung, Ki Woung; Kim, Yong Ik; Na, Jeong Won; Ku, Jae Hyu; Kim, Kwang Rak; Jeong, Yong Won; Lee, Han Soo; Cho, Young Hyun; Ahn, Do Hee; Baek, Seung Woo; Kang, Hee Seok; Kim, You Sun [Korea Atomic Energy Research Institute, Taejon (Korea, Republic of)

1995-12-01

While tritium exposure to the site-workers in Wolsung NPP is up to about 40% of the total personnel exposure, Ministry of Science and Technology has asked tritium removal facility for requirement of post heavy-water reactor construction. For the purpose of essential removal of tritium from the Wolsung heavy-water reactor system, a preliminary study on the cryogenic Ar-N{sub 2} and H{sub 2}-D{sub 2} distillation process for development of liquid-phase catalytic exchange cryogenic hydrogen distillation process technology. The Ar-N{sub 2} distillation column showed good performance with approximately 97% of final Ar concentration, and a computer simulation code was modified using these data. A simulation code developed for cryogenic hydrogen isotopes (H{sub 2}, HD, D{sub 2}, HT, DT, T{sub 2}) distillation column showed good performance after comparison with the result of a JAERI code, and a H{sub 2}-D{sub 2} distillation column was made. Gas chromatography for hydrogen isotopes analysis was established using a vacuum sampling loop, and a schematic diagram of H{sub 2}-D{sub 2} distillation process was suggested. A feasibility on modification of H{sub 2}-D{sub 2} distillation process control system using Laser Raman Spectroscopy was studied, and the consideration points for tritium storage system for Wolsung tritium removal facility was suggested. 31 tabs., 79 figs., 68 refs. (Author).

Distilling solid carbonaceous materials

Energy Technology Data Exchange (ETDEWEB)

Nielsen, H; Laing, B

1926-12-04

In a process of distilling solid carbonaceous materials with by-product recovery, the time factor and the temperature gradient during the distillation period are so controlled that a temperature difference exceeding 150/sup 0/C is avoided between the temperatures at the center and periphery of any suitable size of material or thickness of fuel bed. The material is heated by direct contact with an inert gas, such as water gas, producer gas, or combustion gases, which is passed in counterflow to the material and whose volume is such as to lower the vapor tension or partial pressure of the volatilizable oils and to withdraw the oils without cracking of the oil vapors. The material may be subjected to a preliminary heat treatment by gases containing 2 to 3 percent of free oxygen to reduce its coking properties, and free oxygen may be added either to the heating gases during the heat treatment, or to the retort and heating gases and vapors to polymerize resinous bodies prior to condensation or during condensation and while the oils are still wholly or partially in the vapor state.

Stability of the lamellar structure in Mo-TiC eutectic composite under a low vacuum at high temperatures

International Nuclear Information System (INIS)

Goto, Shoji; Nishijima, Yuzo; Yoshinaga, Hideo

1986-01-01

Thermal stability of the lamellar structure in a Mo-TiC eutectic composite has been investigated through the heat-treatment at 1523 - 2223 K for 5.76 x 10 4 - 3.6 x 10 5 s under a low vacuum pressure of 13 mPa. It was found that the TiC phase in the eutectic lamellar disappeared above the critical temperature of about 1750 K, but below the critical temperature the disappearance of TiC phase was hardly observed and TiO film was formed on the surface. The Mo matrix phase was not oxidized and was stable at all test temperatures, since its affinity for oxygen is lower than that for carbon and titanium. It is presumed that at higer temperatures the disappearance process of TiC phase is controlled by the diffusion of carbon atoms through the matrix to the surface, and carbon and titanium atoms on the surface are removed by CO gas formation and TiO evaporation, respectively, but at lower temperatures the evaporation of TiO is so slow that the TiO film is formed on the surface. (author)

Membrane distillation for milk concentration

NARCIS (Netherlands)

Moejes, S.N.; Romero Guzman, Maria; Hanemaaijer, J.H.; Barrera, K.H.; Feenstra, L.; Boxtel, van A.J.B.

2015-01-01

Membrane distillation is an emerging technology to concentrate liquid products while producing high quality water as permeate. Application for desalination has been studied extensively the past years, but membrane distillation has also potential to produce concentrated food products like

Energy conversion assessment of vacuum, slow and fast pyrolysis processes for low and high ash paper waste sludge

International Nuclear Information System (INIS)

Ridout, Angelo J.; Carrier, Marion; Collard, François-Xavier; Görgens, Johann

2016-01-01

Highlights: • Vacuum, slow and fast pyrolysis of low and high ash paper waste sludge (PWS) is compared. • Reactor temperature and pellet size optimised to maximise liquid and solid product yields. • Gross energy recovery from solid and liquid was assessed. • Fast pyrolysis of low and high ash PWS offers higher energy conversions. - Abstract: The performance of vacuum, slow and fast pyrolysis processes to transfer energy from the paper waste sludge (PWS) to liquid and solid products was compared. Paper waste sludges with low and high ash content (8.5 and 46.7 wt.%) were converted under optimised conditions for temperature and pellet size to maximise both product yields and energy content. Comparison of the gross energy conversions, as a combination of the bio-oil/tarry phase and char (EC_s_u_m), revealed that the fast pyrolysis performance was between 18.5% and 20.1% higher for the low ash PWS, and 18.4% and 36.5% higher for high ash PWS, when compared to the slow and vacuum pyrolysis processes respectively. For both PWSs, this finding was mainly attributed to higher production of condensable organic compounds and lower water yields during FP. The low ash PWS chars, fast pyrolysis bio-oils and vacuum pyrolysis tarry phase products had high calorific values (∼18–23 MJ kg"−"1) making them promising for energy applications. Considering the low calorific values of the chars from alternative pyrolysis processes (∼4–7 MJ kg"−"1), the high ash PWS should rather be converted to fast pyrolysis bio-oil to maximise the recovery of usable energy products.

Vacuuming and drying during refurbishment, Task 3.08/04-11; Podzadatak 3.08/04-11 Vakuumiranje i susenje u toku remonta

Energy Technology Data Exchange (ETDEWEB)

Nikolic, M; Crnilovic, M [Institute of Nuclear Sciences Boris Kidric, Reaktor RA, Vinca, Beograd (Serbia and Montenegro)

1963-12-15

The following tasks were completed during RA reactor refurbishment: vacuuming the gas system; vacuuming of the heavy water system for collecting the leftover heavy water; drying the heavy water system to remove the demineralized water; drying the distillation system; vacuuming the heavy water system before filling with heavy water; leak testing of the complete reactor system.

Simultaneous valorization and biocatalytic upgrading of heavy vacuum gas oil by the biosurfactant-producing Pseudomonas aeruginosa AK6U.

Science.gov (United States)

Ismail, Wael Ahmed; Mohamed, Magdy El-Said; Awadh, Maysoon N; Obuekwe, Christian; El Nayal, Ashraf M

2017-11-01

Heavy vacuum gas oil (HVGO) is a complex and viscous hydrocarbon stream that is produced as the bottom side product from the vacuum distillation units in petroleum refineries. HVGO is conventionally treated with thermochemical process, which is costly and environmentally polluting. Here, we investigate two petroleum biotechnology applications, namely valorization and bioupgrading, as green approaches for valorization and upgrading of HVGO. The Pseudomonas aeruginosa AK6U strain grew on 20% v/v of HVGO as a sole carbon and sulfur source. It produced rhamnolipid biosurfactants in a growth-associated mode with a maximum crude biosurfactants yield of 10.1 g l -1 , which reduced the surface tension of the cell-free culture supernatant to 30.6 mN m -1 within 1 week of incubation. The rarely occurring dirhamnolipid Rha-Rha-C 12 -C 12 dominated the congeners' profile of the biosurfactants produced from HVGO. Heavy vacuum gas oil was recovered from the cultures and abiotic controls and the maltene fraction was extracted for further analysis. Fractional distillation (SimDist) of the biotreated maltene fraction showed a relative decrease in the high-boiling heavy fuel fraction (BP 426-565 °C) concomitant with increase in the lighter distillate diesel fraction (BP 315-426 °C). Analysis of the maltene fraction revealed compositional changes. The number-average (Mn) and weight-average (Mw) molecular weights, as well as the absolute number of hydrocarbons and sulfur heterocycles were higher in the biotreated maltene fraction of HVGO. These findings suggest that HVGO can be potentially exploited as a carbon-rich substrate for production of the high-value biosurfactants by P. aeruginosa AK6U and to concomitantly improve/upgrade its chemical composition. © 2017 The Authors. Microbial Biotechnology published by John Wiley & Sons Ltd and Society for Applied Microbiology.

Cryocooler applications for high-temperature superconductor magnetic bearings

International Nuclear Information System (INIS)

Niemann, R. C.

1998-01-01

The efficiency and stability of rotational magnetic suspension systems are enhanced by the use of high-temperature superconductor (HTS) magnetic bearings. Fundamental aspects of the HTS magnetic bearings and rotational magnetic suspension are presented. HTS cooling can be by liquid cryogen bath immersion or by direct conduction, and thus there are various applications and integration issues for cryocoolers. Among the numerous cryocooler aspects to be considered are installation; operating temperature; losses; and vacuum pumping

High vacuum tip-enhanced Raman spectroscope based on a scanning tunneling microscope.

Science.gov (United States)

Fang, Yurui; Zhang, Zhenglong; Sun, Mengtao

2016-03-01

In this paper, we present the construction of a high-vacuum tip-enhanced Raman spectroscopy (HV-TERS) system that allows in situ sample preparation and measurement. A detailed description of the prototype instrument is presented with experimental validation of its use and novel ex situ experimental results using the HV-TERS system. The HV-TERS system includes three chambers held under a 10(-7) Pa vacuum. The three chambers are an analysis chamber, a sample preparation chamber, and a fast loading chamber. The analysis chamber is the core chamber and contains a scanning tunneling microscope (STM) and a Raman detector coupled with a 50 × 0.5 numerical aperture objective. The sample preparation chamber is used to produce single-crystalline metal and sub-monolayer molecular films by molecular beam epitaxy. The fast loading chamber allows ex situ preparation of samples for HV-TERS analysis. Atomic resolution can be achieved by the STM on highly ordered pyrolytic graphite. We demonstrate the measurement of localized temperature using the Stokes and anti-Stokes TERS signals from a monolayer of 1,2-benzenedithiol on a gold film using a gold tip. Additionally, plasmonic catalysis can be monitored label-free at the nanoscale using our device. Moreover, the HV-TERS experiments show simultaneously activated infrared and Raman vibrational modes, Fermi resonance, and some other non-linear effects that are not observed in atmospheric TERS experiments. The high spatial and spectral resolution and pure environment of high vacuum are beneficial for basic surface studies.

High vacuum tip-enhanced Raman spectroscope based on a scanning tunneling microscope

Energy Technology Data Exchange (ETDEWEB)

Fang, Yurui [Beijing National Laboratory for Condensed Matter Physics, Institute of Physics, Chinese Academy of Sciences, P. O. Box 603-146, Beijing 100190 (China); Bionanophotonics, Department of Applied Physics, Chalmers University of Technology, Göteborg, SE 41296 (Sweden); Zhang, Zhenglong [Beijing National Laboratory for Condensed Matter Physics, Institute of Physics, Chinese Academy of Sciences, P. O. Box 603-146, Beijing 100190 (China); School of Physics and Information Technology, Shaanxi Normal University, 710062 Xi’an (China); Leibniz Institute of Photonic Technology, Albert-Einstein-Str. 9, 07745 Jena (Germany); Sun, Mengtao, E-mail: mtsun@iphy.ac.cn [Beijing National Laboratory for Condensed Matter Physics, Institute of Physics, Chinese Academy of Sciences, P. O. Box 603-146, Beijing 100190 (China)

2016-03-15

In this paper, we present the construction of a high-vacuum tip-enhanced Raman spectroscopy (HV-TERS) system that allows in situ sample preparation and measurement. A detailed description of the prototype instrument is presented with experimental validation of its use and novel ex situ experimental results using the HV-TERS system. The HV-TERS system includes three chambers held under a 10{sup −7} Pa vacuum. The three chambers are an analysis chamber, a sample preparation chamber, and a fast loading chamber. The analysis chamber is the core chamber and contains a scanning tunneling microscope (STM) and a Raman detector coupled with a 50 × 0.5 numerical aperture objective. The sample preparation chamber is used to produce single-crystalline metal and sub-monolayer molecular films by molecular beam epitaxy. The fast loading chamber allows ex situ preparation of samples for HV-TERS analysis. Atomic resolution can be achieved by the STM on highly ordered pyrolytic graphite. We demonstrate the measurement of localized temperature using the Stokes and anti-Stokes TERS signals from a monolayer of 1,2-benzenedithiol on a gold film using a gold tip. Additionally, plasmonic catalysis can be monitored label-free at the nanoscale using our device. Moreover, the HV-TERS experiments show simultaneously activated infrared and Raman vibrational modes, Fermi resonance, and some other non-linear effects that are not observed in atmospheric TERS experiments. The high spatial and spectral resolution and pure environment of high vacuum are beneficial for basic surface studies.

Device for supporting the vacuum vessel of a thermonuclear device

International Nuclear Information System (INIS)

Sato, Hiroshi.

1980-01-01

Purpose: To hold a vacuum vessel securely at a predetermined position. Constitution: A vacuum vessel is supported on its one side to the standard mounting location of a support frame by way of a pin junction. The vacuum vessel is provided at its upper and lower positions with movable mounting portions, which are connected by way of connecting rods to fixed mounting locations on the upper and lower frames. The fixed mounting locations are disposed on a vertical plane including the axis of the torus center. This arrangement enables to hold even a large vacuum vessel at an exact predetermined position even under high temperature conditions without limiting the container's thermal expansion relative to the changes in temperature, thereby providing an extremely high rigidity against electromagnetic forces, earthquakes, etc. (Furukawa, Y.)

In-Situ Microprobe Observations of Dispersed Oil with Low-Temperature Low-Vacuum Scanning Electron Microscope

International Nuclear Information System (INIS)

Mohsen, H.T.

2010-01-01

A low cost cryostat stage from high heat capacity material is designed and constructed, in attempt to apply size distribution techniques for examination of oil dispersions. Different materials were tested according to their heat capacity to keep the liquid under investigation in frozen state as long as possible during the introduction of the cryostat stage to the low-vacuum scanning electron microscope. Different concentrations of non ionic surfactant were added to artificially contaminated with 10000 ppm Balayeam base oil in 3.5 % saline water, where oil and dispersing liquid have been added and shacked well to be investigated under the microscope as fine frozen droplets. The efficiency of dispersion was examined using low temperature low-vacuum scanning electron microscope. The shape and size distributions of freeze oil droplets were studied by digital imaging processing technique in conjunction with scanning electron microscope counting method. Also elemental concentration of oil droplets was analyzed.

Simulations and Vacuum Tests of a CLIC Accelerating Structure

CERN Document Server

Garion, C

2011-01-01

The Compact LInear Collider, under study, is based on room temperature high gradient structures. The vacuum specificities of these cavities are low conductance, large surface areas and a non-baked system. The main issue is to reach UHV conditions (typically 10-7 Pa) in a system where the residual vacuum is driven by water outgassing. A finite element model based on an analogy thermal/vacuum has been built to estimate the vacuum profile in an accelerating structure. Vacuum tests are carried out in a dedicated set-up, the vacuum performances of different configurations are presented and compared with the predictions.

Distillation methods

International Nuclear Information System (INIS)

Konecny, C.

1975-01-01

Two main methods of separation using the distillation method are given and evaluated, namely evaporation and distillation in carrier gas flow. Two basic apparatus are described for illustrating the methods used. The use of the distillation method in radiochemistry is documented by a number of examples of the separation of elements in elemental state, volatile halogenides and oxides. Tables give a survey of distillation methods used for the separation of the individual elements and give conditions under which this separation takes place. The suitability of the use of distillation methods in radiochemistry is discussed with regard to other separation methods. (L.K.)

Advances in high voltage insulation and arc interruption in SF6 and vacuum

CERN Document Server

Maller, V N

1982-01-01

Advances in High Voltage Insulation and Arc Interruption in SF6 and Vacuum deals with high voltage breakdown and arc extinction in sulfur hexafluoride (SF6) and high vacuum, with special emphasis on the application of these insulating media in high voltage power apparatus and devices. The design and developmental aspects of various high voltage power apparatus using SF6 and high vacuum are highlighted. This book is comprised of eight chapters and opens with a discussion on electrical discharges in SF6 and high vacuum, along with the properties and handling of SF6 gas. The following chapters fo

Optimal design of advanced distillation configuration for enhanced energy efficiency of waste solvent recovery process in semiconductor industry

International Nuclear Information System (INIS)

Chaniago, Yus Donald; Minh, Le Quang; Khan, Mohd Shariq; Koo, Kee-Kahb; Bahadori, Alireza; Lee, Moonyong

2015-01-01

Highlights: • Thermally coupled distillation process is proposed for waste solvent recovery. • A systematic optimization procedure is used to optimize distillation columns. • Response surface methodology is applied to optimal design of distillation column. • Proposed advanced distillation allows energy efficient waste solvent recovery. - Abstract: The semiconductor industry is one of the largest industries in the world. On the other hand, the huge amount of solvent used in the industry results in high production cost and potential environmental damage because most of the valuable chemicals discharged from the process are incinerated at high temperatures. A distillation process is used to recover waste solvent, reduce the production-related costs and protect the environment from the semiconductor industrial waste. Therefore, in this study, a distillation process was used to recover the valuable chemicals from semiconductor industry discharge, which otherwise would have been lost to the environment. The conventional sequence of distillation columns, which was optimized using the Box and sequential quadratic programming method for minimum energy objectives, was used. The energy demands of a distillation problem may have a substantial influence on the profitability of a process. A thermally coupled distillation and heat pump-assisted distillation sequence was implemented to further improve the distillation performance. Finally, a comparison was made between the conventional and advanced distillation sequences, and the optimal conditions for enhancing recovery were determined. The proposed advanced distillation configuration achieved a significant energy saving of 40.5% compared to the conventional column sequence

3D thermography for improving temperature measurements in thermal vacuum testing

Science.gov (United States)

Robinson, D. W.; Simpson, R.; Parian, J. A.; Cozzani, A.; Casarosa, G.; Sablerolle, S.; Ertel, H.

2017-09-01

The application of thermography to thermal vacuum (TV) testing of spacecrafts is becoming a vital additional tool in the mapping of structures during thermal cycles and thermal balance (TB) testing. Many of the customers at the European Space Agency (ESA) test centre, European Space Research and Technology Centre (ESTEC), The Netherlands, now make use of a thermal camera during TB-TV campaigns. This complements the use of embedded thermocouples on the structure, providing the prospect of monitoring temperatures at high resolution and high frequency. For simple flat structures with a well-defined emissivity, it is possible to determine the surface temperatures with reasonable confidence. However, for most real spacecraft and sub-systems, the complexity of the structure's shape and its test environment creates inter-reflections from external structures. This and the additional complication of angular and spectral variations of the spacecraft surface emissivity make the interpretation of the radiation detected by a thermal camera more difficult in terms of determining a validated temperature with high confidence and well-defined uncertainty. One solution to this problem is: to map the geometry of the test specimen and thermal test environment; to model the surface temperatures and emissivity variations of the structures and materials; and to use this model to correct the apparent temperatures recorded by the thermal camera. This approach has been used by a team from NPL (National Physical Laboratory), Psi-tran, and PhotoCore, working with ESA, to develop a 3D thermography system to provide a means to validate thermal camera temperatures, based on a combination of thermal imaging photogrammetry and ray-tracing scene modeling. The system has been tested at ESTEC in ambient conditions with a dummy spacecraft structure containing a representative set of surface temperatures, shapes, and spacecraft materials, and with hot external sources and a high power lamp as a sun

Refreshment topics II: Design of distillation columns

Directory of Open Access Journals (Sweden)

Milojević Svetomir

2006-01-01

Full Text Available For distillation column design it is necessary to define all the variable parameters such as component concentrations in different streams temperatures, pressures, mass and energy flow, which are used to represent the separation process of some specific system. They are related to each other according to specific laws, and if the number of such parameters exceeds the number of their relationships, in order to solve a problem some of them must be specified in advance or some constraints assumed for the mass balance, the balance of energy, phase equilibria or chemical equilibria. Knowledge of specific elements which are the constituents of a distillation unit must be known to define the number of design parameters as well as some additional apparati also necessary to realize the distilation. Each separate apparatus might be designed and constructed only if all the necessary and variable parameters for such a unit are defined. This is the right route to solve a distilation unit in many different cases. The construction of some distillation unit requires very good knowledge of mass, heat and momentum transfer phenomena. Moreover, the designer needs to know which kind of apparatus will be used in the distillation unit to realize a specific production process. The most complicated apparatus in a rectification unit is the distillation column. Depending on the complexity of the separation process one, two or more columns are often used. Additional equipment are heat exchangers (reboilers, condensers, cooling systems, heaters, separators, tanks for reflux distribution, tanks and pumps for feed transportation, etc. Such equipment is connected by pipes and valves, and for the normal operation of a distillation unit other instruments for measuring the flow rate, temperature and pressure are also required. Problems which might arise during the determination and selection of such apparati and their number requires knowledge of the specific systems which must

Combined electron beam and vacuum ARC melting for barrier tube shell material

International Nuclear Information System (INIS)

Worcester, S.A.; Woods, C.R.

1989-01-01

This patent describes a process of the type wherein zirconium tetrachloride is reduced to produce a metallic zirconium sponge. The sponge is distilled to generally remove residual magnesium and magnesium chloride, and the distilled sponge is melted to produce an ingot, the improvement for making a non-crystal bar material for use in lining the interior of zirconium alloy fuel element cladding which comprises: a. forming the distilled sponge into a consumable electrode; b. melting the consumable electrode in a multiple swept beam electron furnace with a feed rate between 1 and 20 inches per hour to form an intermediate ingot; and c. vacuum arc melting the intermediate ingot to produce a homogeneous final ingot, having 50-500 ppm iron

Distilling hydrocarbon oils

Energy Technology Data Exchange (ETDEWEB)

Tausz, J

1924-07-16

Hydrocarbon oils such as petroleum, shale oils, lignite or coal tar oils are purified by distilling them and collecting the distillate in fractions within narrow limits so that all the impurities are contained in one or more of the narrow fractions. In distilling ligroin obtained by destructive distillation of brown coal, it is found that the coloring and resin-forming constituents are contained in the fractions distilling over at 62 to 86/sup 0/C and 108/sup 0/C. The ligroin is purified, therefore, by distillating in an apparatus provided with an efficient dephlegmotor and removing these two fractions. The distillation may be carried out wholly or in part under reduced pressure, and fractions separated under ordinary pressure may be subsequently distilled under reduced pressure. The hydrocarbons may be first separated into fractions over wider limits and the separate fractions be subjected to a further fractional distillation.

Effect of vacuum and temperature on the mechanical properties of an aramid/epoxy composite

International Nuclear Information System (INIS)

Hahn, H.T.; Chin, W.K.

1981-01-01

The mechanical properties of a Kevlar 49/epoxy composite intended for flywheel applications are investigated in the laboratory and simulated service environments. The filament-wound composites were preconditioned in the test environment for 1-5 months, during which weight change was monitored, then subjected to tensile and fatigue tests at room temperature or 75 deg in vacuum. A weight loss of only 1.63% is observed after 11 months in the simulated service environment, most of which is attributed to moisture desorbed in vacuum. In contrast to air at 75 C, the simulated service environment is also found to produce no deleterious effects on static and fatigue strengths, probably to moisture desorption and a lack of oxidation. A fatigue life of about 100,000 cycles for 95% survival proability is obtained at 70% of the average static strength, and the macroscopic failure mode, which results in a brush-like formation, is observed to be independent of the type of loading and preconditioning. It is concluded that an environment of 75 C in vacuum is no deterrent to the application of the composite in flywheels, however the possibility of increasing service temperature to 150 C should be investigated

Effect of Vacuum Frying on Quality Attributes of Fruits

NARCIS (Netherlands)

Ayustaningwarno, Fitriyono; Dekker, Matthijs; Fogliano, Vincenzo; Verkerk, Ruud

2018-01-01

Vacuum frying of fruits enables frying at lower temperatures compared to atmospheric frying, thereby improving quality attributes of the fried product, such as oil content, texture, retention of nutrients, and color. Producing high-quality vacuum-fried fruit is a challenge, especially because of the

High temperature stability of surfactant capped CoFe2O4 nanoparticles

International Nuclear Information System (INIS)

Ayyappan, S.; Panneerselvam, G.; Antony, M.P.; Philip, John

2011-01-01

Highlights: → Self-assembled molecular layers of surfactant on nanoparticles are often used to modify surface properties. → We demonstrate that a surfactant nanolayer on CoFe 2 O 4 nanoparticles can act as a strong reducing agent under high temperature vacuum annealing. → We propose a possible reduction mechanism of CoFe 2 O 4 nanoparticles under air and vacuum annealing. → Our results are important in the understanding of the stability of nanoparticles at high temperatures. - Abstract: We investigate the effect of adsorbed surfactant on the structural stability of CoFe 2 O 4 nanoparticles during vacuum thermal annealing. In-situ high temperature X-ray diffraction studies show a reduction of oleic acid coated CoFe 2 O 4 nanoparticles into α-Fe and CoO under annealing at 800 deg. C. On the contrary, the uncoated CoFe 2 O 4 nanoparticles remains stable, with its cubic phase intact, even at 1000 deg. C. Thermo-gravimetric analysis coupled mass spectra reveals that the evolved carbon from the surfactant aids the removal of oxygen atom from CoFe 2 O 4 lattice thereby reducing it to α-Fe and CoO phases. These results are important in tailoring stable CoFe 2 O 4 nanostructures for various applications.

Multi-saline sample distillation apparatus for hydrogen isotope analyses : design and accuracy

Science.gov (United States)

Hassan, Afifa Afifi

1981-01-01

A distillation apparatus for saline water samples was designed and tested. Six samples may be distilled simultaneously. The temperature was maintained at 400 C to ensure complete dehydration of the precipitating salts. Consequently, the error in the measured ratio of stable hydrogen isotopes resulting from incomplete dehydration of hydrated salts during distillation was eliminated. (USGS)

A Study on the Fabrication of Uranium-Cadmium Alloy and its Distillation Behavior

International Nuclear Information System (INIS)

Kim, Ji Yong; Ahn, Do Hee; Kim, Kwang Rag; Paek, Seung Woo; Kim, Si Hyung

2010-01-01

The pyrometallurgical nuclear fuel recycle process, called pyroprocessing, has been known as a promising nuclear fuel recycling technology. Pyroprocessing technology is crucial to advanced nuclear systems due to increased nuclear proliferation resistance and economic efficiency. The basic concept of pyroprocessing is group actinide recovery, which enhances the nuclear proliferation resistance significantly. One of the key steps in pyroprocessing is 'electrowinning' which recovers group actinides with lanthanide from the spent nuclear fuels. In this study, a vertical cadmium distiller was manufactured. The evaporation rate of pure cadmium in vertical cadmium distiller varied from 12.3 to 40.8 g/cm 2 /h within a temperature range of 773 ∼ 923 K and pressure below 0.01 torr. Uranium - cadmium alloy was fabricated by electrolysis using liquid cadmium cathode in a high purity argon atmosphere glove box. The distillation behavior of pure cadmium and cadmium in uranium - cadmium alloy was investigated. The distillation behavior of cadmium from this study could be used to develop an actinide recovery process from a liquid cadmium cathode in a cadmium distiller

A Study on the Fabrication of Uranium-Cadmium Alloy and its Distillation Behavior

Energy Technology Data Exchange (ETDEWEB)

Kim, Ji Yong [University of Science and Technology, Daejeon (Korea, Republic of); Ahn, Do Hee; Kim, Kwang Rag; Paek, Seung Woo; Kim, Si Hyung [Korea Atomic Energy Research Institute, Daejeon (Korea, Republic of)

2010-12-15

The pyrometallurgical nuclear fuel recycle process, called pyroprocessing, has been known as a promising nuclear fuel recycling technology. Pyroprocessing technology is crucial to advanced nuclear systems due to increased nuclear proliferation resistance and economic efficiency. The basic concept of pyroprocessing is group actinide recovery, which enhances the nuclear proliferation resistance significantly. One of the key steps in pyroprocessing is 'electrowinning' which recovers group actinides with lanthanide from the spent nuclear fuels. In this study, a vertical cadmium distiller was manufactured. The evaporation rate of pure cadmium in vertical cadmium distiller varied from 12.3 to 40.8 g/cm{sup 2}/h within a temperature range of 773 {approx} 923 K and pressure below 0.01 torr. Uranium - cadmium alloy was fabricated by electrolysis using liquid cadmium cathode in a high purity argon atmosphere glove box. The distillation behavior of pure cadmium and cadmium in uranium - cadmium alloy was investigated. The distillation behavior of cadmium from this study could be used to develop an actinide recovery process from a liquid cadmium cathode in a cadmium distiller.

Effect of Operating Conditions on Sulfur and Metal Content of Basrah Crude Oil

Directory of Open Access Journals (Sweden)

Muzher M. Ibrahim

2013-05-01

Full Text Available       In the present work, Basrah crude oil, atmospheric distillate of 305-623 K boiling range, vacuum distillate of 623-823 K boiling range, and wide petroleum distillate of boiling range 305-823 K are hydrotreated in trickle bed reactor using Cobalt-Molybdenum alumina as a catalyst. Hydrotreating temperatures are 598-648K, 598-673K, 648-673K and 648K respectively while LHSV are 0.7-2 hr-1, 1 hr-1, 0.7-2 hr-1 respectively. The operating pressure  and H2/Oil ratio for all experiments are kept constant at 3 Mpa and 300 liter/liter.    The results show that Sulphur and metal content decreased with increasing temperature and decreasing LHSV.     Vacuum residue of boiling range above 823K is mixed with hydrotreated atmospheric distillate, vacuum distillate and with the hydrotreated wide petroleum distillate. The temperature for hydrotreating the mixed sample is 648K and LHSV is 1 hr-1. It was found that hydrotreating crude oil is the best choice since it gives the highest removal of sulphur, vanadium and cobalt removal.

Separation of isotopes of nitrogen and oxygen by low temperature distillation of nitrogen oxide

Energy Technology Data Exchange (ETDEWEB)

Isomura, Shohei; Tonooka, Yasuhiko; Kaetsu, Hayato

1987-02-01

In general, the distillation parameters, such as the number of theoretical plate (NTP) and the height equivalent to a theoretical plate (HETP), can be obtained from the operation at the steady state. However, it is time-consuming to achieve the steady state especially in the case of isotope separation. In this paper, with the purpose of simultaneous separation of isotopes of nitrogen and oxygen by NO distillation, we tried to determine the distillation parameters by an analytical method through the transient-state operation. It was confirmed that the results from the analysis were in good agreement with those observed for the operation at the steady state. Enrichment of the isotopes was carried out using a distillation column with a height of 1 m and inside diameter of 12 mm. The dependence of HETP on liquid flow rate was measured by the proposed method. The obtained HETP values were from 2 to 4 cm. The operation time of about 5 h was found to be long enough to determine the distillation parameters.

Separation of isotopes of nitrogen and oxygen by low temperature distillation of nitrogen oxide

International Nuclear Information System (INIS)

Isomura, Shohei; Tonooka, Yasuhiko; Kaetsu, Hayato

1987-01-01

In general, the distillation parameters, such as the number of theoretical plate (NTP) and the height equivalent to a theoretical plate (HETP), can be obtained from the operation at the steady state. However, it is time-consuming to achieve the steady state especially in the case of isotope separation. In this paper, with the purpose of simultaneous separation of isotopes of nitrogen and oxygen by NO distillation, we tried to determine the distillation parameters by an analytical method through the transient-state operation. It was confirmed that the results from the analysis were in good agreement with those observed for the operation at the steady state. Enrichment of the isotopes was carried out using a distillation column with a height of 1 m and inside diameter of 12 mm. The dependence of HETP on liquid flow rate was measured by the proposed method. The obtained HETP values were from 2 to 4 cm. The operation time of about 5 h was found to be long enough to determine the distillation parameters. (author)

Vacuum-ultraviolet circular dichroism spectrophotometer using synchrotron radiation

International Nuclear Information System (INIS)

Matsuo, K.; Fukuyama, T.; Yonehara, R.; Namatame, H.; Taniguchi, M.; Gekko, K.

2005-01-01

We have constructed a vacuum-ultraviolet circular dichroism (VUVCD) spectrophotometer using a synchrotron radiation and an assembled-type MgF 2 cell endurable under a high vacuum, to measure the CD spectra of biomaterials in aqueous solutions from 310 to 140 nm. To avoid the absorption of light by air and water vapor, all optical devices of the spectrophotometer were set up under a high vacuum (10 -4 Pa). A path length of the optical cell can be adjusted by various Teflon spacers in the range from 1.3 to 50 μm and its temperature can be controlled to an accuracy of ±1 deg. C over the range from -30 to 70 deg. C by a temperature-control unit using a Peltier thermoelectric element. The performance of the spectrophotometer and the optical cell constructed was tested by measuring the CD spectra of ammonium d-camphor-10-sulfonate, D- and L-isomers of amino acids, and myoglobin in aqueous solutions. The spectra obtained demonstrate that the optical system and the sample cell constructed operate normally under a high vacuum and provide useful information on the structure of biomolecules based on the higher energy chromophores

Distillation, destructive

Energy Technology Data Exchange (ETDEWEB)

Byrom, W A; Bennett, J A.B.

1884-02-22

Effecting the separation of the various products of the distillation of coal, shale, etc., by taking advantage of the graduated temperature of successive portions of the length of mechanical retorts is described. The substances entering from the hopper are gradually heated in their progress and give off a series of products in their order of volatilization, which pass from openings in the retort through a series of ascension pipes into collecting-vessels. The vessels are designed to contain different portions of the distillate and are sealed against the escape of uncondensed vapor or gas by the condensed liquid. Each of the ascension pipes communicates above its vessel with a common pipe to convey away permanent gases. The flues for heating the retort may be so arranged as to give the greatest heat at the end farthest from the point of entrance, or the stages of heat may be self-regulated by the time necessary for the material to acquire heat as it travels. If necessary the pipes may be fitted with refrigerating-appliances.

Vacuum and ultravacuum physics and technology

CERN Document Server

Bello, Igor

2018-01-01

Vacuum technology has enormous impact on human life in many aspects and fields, such as metallurgy, material development and production, food and electronic industry, microelectronics, device fabrication, physics, materials science, space science, engineering, chemistry, technology of low temperature, pharmaceutical industry, and biology. All decorative coatings used in jewelries and various daily products—including shiny decorative papers, the surface finish of watches, and light fixtures—are made using vacuum technological processes. Vacuum analytical techniques and vacuum technologies are pillars of the technological processes, material synthesis, deposition, and material analyses—all of which are used in the development of novel materials, increasing the value of industrial products, controlling the technological processes, and ensuring the high product quality. Based on physical models and calculated examples, the book provides a deeper look inside the vacuum physics and technology.

Ultra high vacuum systems for accelerators

International Nuclear Information System (INIS)

Loefgren, P.

2001-01-01

Full text: In order to perform controlled, stable, and reproducible experiments, several research areas today require very low pressures. Maybe the most important example is the research that is performed in storage rings and accelerators where the lifetime and stability of particle beams depends critically on the vacuum conditions. Although the vacuum requirements ultimately depend on the kind of experiments that is performed, the studies of more and more rare and exotic species in storage rings and accelerators today pushes the demands on the vacuum conditions towards lower and lower pressures. The final pressure obtained in the vacuum system can often be the key factor for the outcome of an experiment. Pioneering work in vacuum technology has therefore often been performed at storage rings and accelerator facilities around the world. In order to reach pressures in the low UHV regime and lower (below 10 -11 mbar), several aspects have to be considered which implies choosing the proper materials, pumps and vacuum gauges. In the absence of gases inleaking from the outside, the rate of gas entering a vacuum system is determined by the release of molecules adsorbed on the surfaces and the outgassing from the bulk of the vacuum chamber walls. This means that the choice of material and, equally important, the pre treatment of the material, must be such that these rates are minimised. Today the most widely used material for vacuum applications are stainless steel. Besides its many mechanical advantages, it is resistant to corrosion and oxidation. If treated correctly the major gas source in a stainless steel chamber is hydrogen outgassing from the chamber walls. The hydrogen outgassing can be decreased by vacuum firing at 950 deg. C under vacuum. In addition to choosing the right materials the choice of vacuum pumps is important for the final pressure. Since no vacuum pump is capable of taking care of all kinds of gases found in the rest gas at pressures below 10 -11

Experimental confirmation of the ITER cryopump high temperature regeneration scheme

International Nuclear Information System (INIS)

Day, C.; Haas, H.

2007-01-01

Forschungszentrum Karlsruhe (FZK) is developing the ITER high vacuum pumping systems for evacuation and maintenance of the required pressure levels in the torus (during burn and dwell, conditioning and leak detection), the neutral beam injectors and the cryostat vessel. All ITER high vacuum systems share the same concept of accumulative cryosorption pumping. The pumping surfaces, forced-cooled by 4.5 K supercritical helium, are coated with activated charcoal so as to be able to adsorb helium and hydrogens. All other gases are cryopumped by cryogenic phase transition from gaseous into the liquid/solid state. For the hydrogen processing pumps in the torus and the NBI, the maximum pumping time is given by the limitation of the maximum hydrogen inventory such that the resulting pressure in case of a loss of vacuum event and a corresponding oxy-hydrogen explosion is compatible to the design criteria of the vacuum vessel. To limit the gas accumulation, a staggered regeneration philosophy has been adopted, which involves three different temperature levels in order to achieve high regeneration efficiencies at best availability of the pumping system. The regular regeneration step is performed at a charcoal temperature of 90 K to release all hydrogen isotopomers (and helium), which are subsequently pumped out by the forevacuum pumping system. The second step at ambient temperature leads to the release of all air-like species. It has to be performed less frequently, probably over-night. Any water-like species with strong sorption bonding forces need still higher temperatures for effective desorption from the charcoal. These species comprise not only water itself but also high molecular tracers added to the water circuits in case of leak localisation and any pumped higher hydrocarbons from the plasma exhaust or. The latter in their tritiated forms may contribute significantly to the semi-permanent tritium inventory; a good knowledge of their regeneration characteristics is

Dry distillation

Energy Technology Data Exchange (ETDEWEB)

1939-11-30

To heat rapidly, and prevent agglutination of carbonaceous material duriing distillation of shale, a furnace of the tunnel type has four compartments (the preheating chamber, the distillation chamber proper, and two cooling chambers). Waggons, which convey the material through the distilling chamber, have perforated bottoms. Above the waggons in the distilling chamber are three heating sections having pipes which pass through the sections and communicate with the distilling chamber. Fans cause the distillation gases to circulate through the material and the pipes. The heating gases from three fire boxes are introduced into the oven, and circulate around pipes and are drawn to the discharge apertures by the fans. The heating gases introduced at two points travel in the direction of the material being treated, while the gases introduced at a third point travel in counter flow thereto. Gas is discharged by two pipes. Trucks carrying treated material are passed to two cooling chambers.

PETIs as High-Temperature Resin-Transfer-Molding Materials

Science.gov (United States)

Connell, John N.; Smith, Joseph G., Jr.; Hergenrother, Paul M.

2005-01-01

Compositions of, and processes for fabricating, high-temperature composite materials from phenylethynyl-terminated imide (PETI) oligomers by resin-transfer molding (RTM) and resin infusion have been developed. Composites having a combination of excellent mechanical properties and long-term high-temperature stability have been readily fabricated. These materials are particularly useful for the fabrication of high-temperature structures for jet-engine components, structural components on highspeed aircraft, spacecraft, and missiles. Phenylethynyl-terminated amide acid oligomers that are precursors of PETI oligomers are easily made through the reaction of a mixture of aromatic diamines with aromatic dianhydrides at high stoichiometric offsets and 4-phenylethynylphthalic anhydride (PEPA) as an end-capper in a polar solvent such as N-methylpyrrolidinone (NMP). These oligomers are subsequently cyclodehydrated -- for example, by heating the solution in the presence of toluene to remove the water by azeotropic distillation to form low-molecular-weight imide oligomers. More precisely, what is obtained is a mixture of PETI oligomeric species, spanning a range of molecular weights, that exhibits a stable melt viscosity of less than approximately 60 poise (and generally less than 10 poise) at a temperature below 300 deg C. After curing of the oligomers at a temperature of 371 deg C, the resulting polymer can have a glass-transition temperature (Tg) as high as 375 C, the exact value depending on the compositions.

Research on temperature control and influence of the vacuum tubes with inserted tubes solar heater

Science.gov (United States)

Xiao, L. X.; He, Y. T.; Hua, J. Q.

2017-11-01

A novel snake-shape vacuum tube with inserted tubes solar collector is designed in this paper, the heat transfer characteristics of the collector are analyzed according to its structural characteristics, and the influence of different working temperature on thermal characteristics of the collector is studied. The solar water heater prototype consisting of 14 vacuum tubes with inserted tubes is prepared, and the hot water storage control subsystem is designed by hysteresis comparison algorithm. The heat characteristic of the prototype was experimentally studied under hot water output temperature of 40-45°C, 50-55°C and 60-65°C. The daily thermal efficiency was 64%, 50% and 46%, respectively. The experimental results are basically consistent with the theoretical analysis.

Ultra high vacuum technology

CERN Multimedia

CERN. Geneva

2001-01-01

A short introduction for some basic facts and equations. Subsquently, discussion about: Building blocks of an ultrahigh vacuum system - Various types of pumps required to reach uhv and methods to reduce these effects - Outgassing phenomena induced by the presence of a particle beam and the most common methods to reduce these effects It will be given some practical examples from existing CERN accelerators and discuss the novel features of the future LHC vacuum system.

An ultrahigh vacuum fast-scanning and variable temperature scanning tunneling microscope for large scale imaging.

Science.gov (United States)

Diaconescu, Bogdan; Nenchev, Georgi; de la Figuera, Juan; Pohl, Karsten

2007-10-01

We describe the design and performance of a fast-scanning, variable temperature scanning tunneling microscope (STM) operating from 80 to 700 K in ultrahigh vacuum (UHV), which routinely achieves large scale atomically resolved imaging of compact metallic surfaces. An efficient in-vacuum vibration isolation and cryogenic system allows for no external vibration isolation of the UHV chamber. The design of the sample holder and STM head permits imaging of the same nanometer-size area of the sample before and after sample preparation outside the STM base. Refractory metal samples are frequently annealed up to 2000 K and their cooldown time from room temperature to 80 K is 15 min. The vertical resolution of the instrument was found to be about 2 pm at room temperature. The coarse motor design allows both translation and rotation of the scanner tube. The total scanning area is about 8 x 8 microm(2). The sample temperature can be adjusted by a few tens of degrees while scanning over the same sample area.

ITER articulated inspection arm (AIA): R and d progress on vacuum and temperature technology for remote handling

International Nuclear Information System (INIS)

Perrot, Y.; Cordier, J.J.; Friconneau, J.P.; Gargiulo, L.; Martin, E.; Palmer, J.D.; Tesini, A.

2005-01-01

This paper is part of the remote handling (RH) activities for the future fusion reactor ITER. The aim of the R and D program performed under the European Fusion Development Agreement (EFDA) work program is to demonstrate the feasibility of close inspection tasks such as viewing or leak testing of the Divertor cassettes and the Vacuum Vessel (VV) first wall of ITER. It is assumed that a long reach, limited payload carrier penetrates the ITER chamber through the openings evenly distributed around the machine such as In-Vessel Viewing System (IVVS) access or through upper port plugs. To perform an intervention a short time after plasma shut down, the operation of the robot should be realised under ITER conditioning i.e. under high vacuum and temperature conditions (120 o C). The feasibility analysis drove the design of the so-called articulated inspection arm (AIA) which is a 8.2 m long robot made of five modules with a 11 actuated joints kinematics. A single module prototype was designed in detail and manufactured to be tested under ITER realistic conditions at CEA-Cadarache test facility. As well as demonstrating the potential for the application of an AIA type device in ITER, this program is also dedicated to explore the necessary robotic technologies required to ITER's IVVS deployment system. This paper presents the whole AIA robot concept, the first results of the test campaign on the prototype vacuum and temperature demonstrator module

ITER articulated inspection arm (AIA): R and d progress on vacuum and temperature technology for remote handling

Energy Technology Data Exchange (ETDEWEB)

Perrot, Y. [Robotics and Interactive Systems Unit-CEA/LIST, BP6 F-92265 Fontenay aux Roses Cedex (France)]. E-mail: yann.perrot@cea.fr; Cordier, J.J. [DRFC-CEA Cadarache, 13108 Saint Paul Lez Durance Cedex (France); Friconneau, J.P. [Robotics and Interactive Systems Unit-CEA/LIST, BP6 F-92265 Fontenay aux Roses Cedex (France); Gargiulo, L. [DRFC-CEA Cadarache, 13108 Saint Paul Lez Durance Cedex (France); Martin, E. [ITER International Team, Boltzmannstrasse 2, 85748 Garching (Germany); Palmer, J.D. [EFDA CSU Garching, Boltzmannstrasse 2, 85748 Garching (Germany); Tesini, A. [ITER International Team, ITER Naka Joint Work Site, 801-1, Muouyama, Naka-machi, Naka-gun, Iberaki-ken 311-0193 (Japan)

2005-11-15

This paper is part of the remote handling (RH) activities for the future fusion reactor ITER. The aim of the R and D program performed under the European Fusion Development Agreement (EFDA) work program is to demonstrate the feasibility of close inspection tasks such as viewing or leak testing of the Divertor cassettes and the Vacuum Vessel (VV) first wall of ITER. It is assumed that a long reach, limited payload carrier penetrates the ITER chamber through the openings evenly distributed around the machine such as In-Vessel Viewing System (IVVS) access or through upper port plugs. To perform an intervention a short time after plasma shut down, the operation of the robot should be realised under ITER conditioning i.e. under high vacuum and temperature conditions (120 {sup o}C). The feasibility analysis drove the design of the so-called articulated inspection arm (AIA) which is a 8.2 m long robot made of five modules with a 11 actuated joints kinematics. A single module prototype was designed in detail and manufactured to be tested under ITER realistic conditions at CEA-Cadarache test facility. As well as demonstrating the potential for the application of an AIA type device in ITER, this program is also dedicated to explore the necessary robotic technologies required to ITER's IVVS deployment system. This paper presents the whole AIA robot concept, the first results of the test campaign on the prototype vacuum and temperature demonstrator module.

Second Generation Novel High Temperature Commercial Receiver & Low Cost High Performance Mirror Collector for Parabolic Solar Trough

Energy Technology Data Exchange (ETDEWEB)

Stettenheim, Joel [Norwich Technologies, White River Junction, VT (United States)

2016-02-29

Norwich Technologies (NT) is developing a disruptively superior solar field for trough concentrating solar power (CSP). Troughs are the leading CSP technology (85% of installed capacity), being highly deployable and similar to photovoltaic (PV) systems for siting. NT has developed the SunTrap receiver, a disruptive alternative to vacuum-tube concentrating solar power (CSP) receivers, a market currently dominated by the Schott PTR-70. The SunTrap receiver will (1) operate at higher temperature (T) by using an insulated, recessed radiation-collection system to overcome the energy losses that plague vacuum-tube receivers at high T, (2) decrease acquisition costs via simpler structure, and (3) dramatically increase reliability by eliminating vacuum. It offers comparable optical efficiency with thermal loss reduction from ≥ 26% (at presently standard T) to ≥ 55% (at high T), lower acquisition costs, and near-zero O&M costs.

Modeling Of A Reactive Distillation Column: Methyl Tertiary Butyl Ether (Mtbe Simulation Studies

Directory of Open Access Journals (Sweden)

Ismail Mohd Saaid Abdul Rahman Mohamed and Subhash Bhatia

2012-10-01

Full Text Available A process simulation stage-wise reactive distillation column model formulated from equilibrium stage theory was developed. The algorithm for solving mathematical model represented by sets of differential-algebraic equations was based on relaxation method. Numerical integration scheme based on backward differentiation formula was selected for solving the stiffness of differential-algebraic equations. Simulations were performed on a personal computer (PC Pentium processor through a developed computer program using FORTRAN90 programming language. The proposed model was validated by comparing the simulated results with the published simulation results and with the pilot plant data from the literature. The model was capable of predicting high isobutene conversion for heterogeneous system, as desirable in industrial MTBE production process. The comparisons on temperature profiles, liquid composition profile and operating conditions of reactive distillation column also showed promising results. Therefore the proposed model can be used as a tool for the development and simulation of reactive distillation column.Keywords: Modeling, simulation, reactive distillation, relaxation method, equilibrium stage, heterogeneous, MTBE

Vacuum system of SST-1 Tokamak

International Nuclear Information System (INIS)

Khan, Ziauddin; Pathan, Firozkhan; George, Siju; Semwal, Pratibha; Dhanani, Kalpesh; Paravastu, Yuvakiran; Thankey, Prashant; Ramesh, Gattu; Himabindu, Manthena; Pradhan, Subrata

2013-01-01

Highlights: ► Air leaks developed during ongoing SST-1 cooldown campaign were detected online using RGA. ► The presence of N 2 and O 2 gases with the ratio of their partial pressures with ∼3.81:1 confirmed the air leaks. ► Baking of SST-1 was done efficiently by flowing hot N 2 gas in C-channels welded on inner surfaces without any problem. ► In-house fabricated demountable bull nose couplers were demonstrated for high temperature and pressure applications. ► Cryopumping effect was observed when liquid helium cooled superconducting magnets reached below 63 K. -- Abstract: Vacuum chambers of Steady State Superconducting (SST-1) Tokamak comprises of the vacuum vessel and the cryostat. The plasma will be confined inside the vacuum vessel while the cryostat houses the superconducting magnet systems (TF and PF coils), LN 2 cooled thermal shields and hydraulics for these circuits. The vacuum vessel is an ultra-high (UHV) vacuum chamber while the cryostat is a high-vacuum (HV) chamber. In order to achieve UHV inside the vacuum vessel, it would be baked at 150 °C for longer duration. For this purpose, U-shaped baking channels are welded inside the vacuum vessel. The baking will be carried out by flowing hot nitrogen gas through these channels at 250 °C at 4.5 bar gauge pressure. During plasma operation, the pressure inside the vacuum vessel will be raised between 1.0 × 10 −4 mbar and 1.0 × 10 −5 mbar using piezoelectric valves and control system. An ultimate pressure of 4.78 × 10 −6 mbar is achieved inside the vacuum vessel after 100 h of pumping. The limitation is due to the development of few leaks of the order of 10 −5 mbar l/s at the critical locations of the vacuum vessel during baking which was confirmed with the presence of nitrogen gas and oxygen gas with the ratio of ∼3.81:1 indicating air leak. Similarly an ultimate vacuum of 2.24 × 10 −5 mbar is achieved inside the cryostat. Baking of the vacuum vessel up to 110 °C with ±10 �

Vacuum system for the tokamak fusion test reactor (TFTR)

International Nuclear Information System (INIS)

Lange, W.J.; Green, D.; Sink, D.A.

1976-01-01

The vacuum system for TFTR is described. Insofar as possible, conventional and ultrahigh vacuum (UHV) components and technology will be employed. Subassemblies will be prebaked in vacuum to reduce subsequent outgassing, and assembly will employ TIG welding and metal gaskets. It is not anticipated that the totally assembled torus with its numerous diagnostic appendages will be baked in situ to a high temperature, however a lower bakeout temperature (approximately 250 0 C) is under consideration. Final vacuum conditioning will be performed using discharge cleaning to obtain a specific outgassing rate of less than or = to 10 -10 Torr liter/sec cm 2 hydrogen isotopes and less than or = to 10 -12 Torr liter/sec cm 2 of other gases, and a base pressure of less than or = to 5 x 10 -8 Torr

Enhanced Freshwater Production Using Finned-Plate Air Gap Membrane Distillation (AGMD

Directory of Open Access Journals (Sweden)

Perves Bappy Mohammad Jabed

2017-01-01

Full Text Available Air Gap membrane distillation (AGMD, a special type of energy efficient membrane distillation process, is a technology for producing freshwater from waste water. Having some benefits over other traditional processes, this method has been able to draw attention of researchers working in the field of freshwater production technologies. In this study, a basic AGMD system with flat coolant plate has been modified using a specially designed channelled coolant plate of portable size to observe its effect over the production rate and performance of the system. Attempt has been made to increase the amount of distillate flux by using the “fin effect” of the channelled coolant plate. A finned plate have been used instead of a flat coolant plate and experiments were conducted to compare the effect. Coolant temperature and feed temperature of the system have been varied from 10°C to 25°C and 40°C to 70°C respectively. Comparing the data, around 50% to 58% distillate enhancement has been observed for channelled coolant plate. Also, it was seen that the enhancement was higher for higher feed temperatures and coolant temperatures. With these findings, a better performing AGMD module has been introduced to mitigate the scarcity of freshwater.

Thermoeconomic and environmental assessment of a crude oil distillation unit of a Nigerian refinery

International Nuclear Information System (INIS)

Waheed, M.A.; Oni, A.O.; Adejuyigbe, S.B.; Adewumi, B.A.

2014-01-01

The renovation of refineries should be aimed at achieving the highest possible technical efficiencies at a considerable investment cost and not only at replacing damaged components to attain full capacity utilisation. This study examined a crude distillation unit (CDU) of a Nigerian refinery plant comprising the atmospheric distillation unit (ADU), vacuum distillation unit (VDU), preflash unit (PFU), splitter unit (SPU), stabiliser unit (SBU) and heat exchanger network (HEN) to determine critical areas of inefficiencies as the plant managements plan renovation. Using real plant data, the CDU was simulated with Aspen Hysys ® and the thermoeconomic and environmental analyses were carried out. The results show that the energy and exergy efficiencies of the CDU were 9.0 and 4.0% respectively. The specific CO 2 emission was 3.67 kg CO 2 /bbl. The highly inefficient subunits accounting for 77.4 and 90.0% of the overall energy and exergy losses respectively and 60.3% of the emission released were the PFU, ADU and HEN. The highly inefficient components are the furnaces which accounted for 51.6% of the overall exergy losses. The environmental and economic analysis also indicated that these components are the most potent for improvement. The columns of the PFU and ADU should be revamped to reduce their energy demands and the HEN should be modified to minimise effluent losses. - Highlights: •The assessment of a crude distillation unit (CDU) in Nigeria was carried out. •The assessment considered thermodynamic, thermoeconomic and environment analysis. •The assessment revealed areas with poor performance in the CDU. •Large thermodynamic and economic losses are responsible for the poor performance. •Areas with large losses and emission rate should be targeted for improvement

Thermoeconomic and environmental assessment of a crude oil distillation unit of a Nigerian refinery

Energy Technology Data Exchange (ETDEWEB)

Waheed, M. A. [Department of Mechanical Engineering, Federal University of Agriculture, Abeokuta, P.M.B. 2240, Abeokuta, Ogun State (Nigeria); Oni, A.O., E-mail: fem2day@yahoo.com [Department of Mechanical Engineering, Federal University of Agriculture, Abeokuta, P.M.B. 2240, Abeokuta, Ogun State (Nigeria); Adejuyigbe, S. B. [Department of Mechanical Engineering, Federal University of Agriculture, Abeokuta, P.M.B. 2240, Abeokuta, Ogun State (Nigeria); Adewumi, B. A. [Department of Agricultural Engineering, Federal University of Agriculture, Abeokuta, P.M.B. 2240, Abeokuta, Ogun State (Nigeria)

2014-05-01

The renovation of refineries should be aimed at achieving the highest possible technical efficiencies at a considerable investment cost and not only at replacing damaged components to attain full capacity utilisation. This study examined a crude distillation unit (CDU) of a Nigerian refinery plant comprising the atmospheric distillation unit (ADU), vacuum distillation unit (VDU), preflash unit (PFU), splitter unit (SPU), stabiliser unit (SBU) and heat exchanger network (HEN) to determine critical areas of inefficiencies as the plant managements plan renovation. Using real plant data, the CDU was simulated with Aspen Hysys{sup ®} and the thermoeconomic and environmental analyses were carried out. The results show that the energy and exergy efficiencies of the CDU were 9.0 and 4.0% respectively. The specific CO{sub 2} emission was 3.67 kg CO{sub 2}/bbl. The highly inefficient subunits accounting for 77.4 and 90.0% of the overall energy and exergy losses respectively and 60.3% of the emission released were the PFU, ADU and HEN. The highly inefficient components are the furnaces which accounted for 51.6% of the overall exergy losses. The environmental and economic analysis also indicated that these components are the most potent for improvement. The columns of the PFU and ADU should be revamped to reduce their energy demands and the HEN should be modified to minimise effluent losses. - Highlights: •The assessment of a crude distillation unit (CDU) in Nigeria was carried out. •The assessment considered thermodynamic, thermoeconomic and environment analysis. •The assessment revealed areas with poor performance in the CDU. •Large thermodynamic and economic losses are responsible for the poor performance. •Areas with large losses and emission rate should be targeted for improvement.

Vacuum pumping for controlled thermonuclear reactors

International Nuclear Information System (INIS)

Watson, J.S.; Fisher, P.W.

1976-01-01

Thermonuclear reactors impose unique vacuum pumping problems involving very high pumping speeds, handling of hazardous materials (tritium), extreme cleanliness requirements, and quantitative recovery of pumped materials. Two principal pumping systems are required for a fusion reactor, a main vacuum system for evacuating the torus and a vacuum system for removing unaccelerated deuterium from neutral beam injectors. The first system must pump hydrogen isotopes and helium while the neutral beam system can operate by pumping only hydrogen isotopes (perhaps only deuterium). The most promising pumping techniques for both systems appear to be cryopumps, but different cryopumping techniques can be considered for each system. The main vacuum system will have to include cryosorption pumps cooled to 4.2 0 K to pump helium, but the unburned deuterium-tritium and other impurities could be pumped with cryocondensation panels (4.2 0 K) or cryosorption panels at higher temperatures. Since pumping speeds will be limited by conductance through the ducts and thermal shields, the pumping performance for both systems will be similar, and other factors such as refrigeration costs are likely to determine the choice. The vacuum pumping system for neutral beam injectors probably will not need to pump helium, and either condensation or higher temperature sorption pumps can be used

Recovery of Residual LiCl-KCl Eutectic Salts in Radioactive Rare Earth Precipitates

International Nuclear Information System (INIS)

Eun, Hee Chul; Yang, Hee Chul; Kim, In Tae; Lee, Han Soo; Cho, Yung Zun

2010-01-01

For the pyrochemical process of spent nuclear fuels, recovery of LiCl-KCl eutectic salts is needed to reduce radioactive waste volume and to recycle resource materials. This paper is about recovery of residual LiCl-KCl eutectic salts in radioactive rare earth precipitates (rare earth oxychlorides or oxides) by using a vacuum distillation process. In the vacuum distillation test apparatus, the salts in the rare earth precipitates were vaporized and were separated effectively. The separated salts were deposited in three positions of the vacuum distillation test apparatus or were collected in the filter and it is difficult to recover them. To resolve the problem, a vacuum distillation and condensation system, which is subjected to the force of a temperature gradient at a reduced pressure, was developed. In a preliminary test of the vacuum distillation/condensation recovery system, it was confirmed that it was possible to condense the vaporized salts only in the salt collector and to recover the condensed salts from the salt collector easily

A simple, high-yield, apparatus for NEG coating of vacuum beamline elements

International Nuclear Information System (INIS)

Ron, G; Oort, R; Lee, D

2010-01-01

Non-Evaporable Getter (NEG) materials are extremely useful in vacuum systems for achieving Ultra High Vacuum. Recently, these materials have been used to coat the inner surfaces of vacuum components, acting as an internal, passive, vacuum pump. We have constructed a low cost apparatus, which allows coating of very small diameter vacuum tubes, used as differential pumping stages. Despite the relative ease of construction, we are routinely able to achieve high coating yields. We further describe an improvement to our system, which is able to achieve the same yield, at an even lower complexity by using an easily manufactured permanent magnet arrangement. The designs described are extendible to virtually any combination of length and diameter of the components to be coated.

Tribological properties of polymers PI, PTFE and PEEK at cryogenic temperature in vacuum

Science.gov (United States)

Wang, Qihua; Zheng, Fei; Wang, Tingmei

2016-04-01

The effects of temperature, sliding speed and load on the tribological properties of polyimide (PI), polytetrafluoroethylene (PTFE) and polyetheretherketone (PEEK) at cryogenic temperature in vacuum were investigated using a ball-on-disk tribometer. At cryogenic temperature, polymers show higher hardness which results in decreasing contact area between the friction pairs. Moreover, the real surface area in contact between steel ball and polymer disk determines the friction coefficient instead of the formation and adhesion of the transfer film. Thus, the friction coefficients at cryogenic temperatures are lower than at room temperature. On the other hand, wear rates of the three polymers decrease as temperature decreases since molecular mobility and migration are limited at cryogenic temperatures. For the visco-elasticity of PI, PTFE and PEEK, the friction coefficients fall as the load increases.

High temperature blankets for the production of synthetic fuels

International Nuclear Information System (INIS)

Powell, J.R.; Steinberg, M.; Fillo, J.; Makowitz, H.

1977-01-01

The application of very high temperature blankets to improved efficiency of electric power generation and production of H 2 and H 2 based synthetic fuels is described. The blanket modules have a low temperature (300 to 400 0 C) structure (SS, V, Al, etc.) which serves as the vacuum/coolant pressure boundary, and a hot (>1000 0 C) thermally insulated interior. Approximately 50 to 70% of the fusion energy is deposited in the hot interior because of deep penetration by high energy neutrons. Separate coolant circuits are used for the two temperature zones: water for the low temperature structure, and steam or He for the hot interior. Electric generation efficiencies of approximately 60% and H 2 production efficiencies of approximately 50 to 70%, depending on design, are projected for fusion reactors using these high temperature blankets

Process and apparatus for distilling bituminous minerals

Energy Technology Data Exchange (ETDEWEB)

Veyrier, J A

1922-03-27

This process of distillation of bituminous minerals and particularly bituminous limestone is characterized by the fact that the minerals are introduced into the retort where they stand only the temperature necessary to distill the water and lighter oils that they contain and then are drawn out into the hearth and serve for heating the retort. The apparatus is characterized by the fact that the retort has a screw conveyor, placed in the flue of the hearth, supplied with a chamber for evacuation below this hearth.

Distilling carbonaceous materials

Energy Technology Data Exchange (ETDEWEB)

Garrow, J R

1921-04-16

To obtain an increased yield of by-products such as oils, ammonia, and gas from coal, oil shale, wood, peat, and the like by low and medium temperature processes, the requisite quantity of hot producer gas from a gas producer, is caused to travel, without ignition, through the material as it passes in a continuous manner through the retort so that the sensible heat of the producer gas is utilized to produce distillation of the carbonaceous material, the gases passing to a condenser, absorption apparatus, and an ammonia absorber respectively. In a two-stage method of treatment of materials such as peat or the like, separate supplies of producer gas are utilized for a preliminary drying operation and for the distillation of the material, the drying receptacle and the retort being joined together to render the process continuous. The gas from the drying receptacle may be mixed with the combined producer and retort gas from the retort, after the hydrocarbon oils have deen removed therefrom.

Evaluating strength at ultra-high temperatures-Methods and results

International Nuclear Information System (INIS)

Voelkl, Rainer; Fischer, Bernd; Beschliesser, Manuel; Glatzel, Uwe

2008-01-01

Proprietary equipment for mechanical testing at ultra-high temperatures by ohmic heating is outlined. Strain is measured with a video extensometer with an accuracy of up to Δε-bar∼±0.00025%. Stability and accuracy of the test system are evaluated on Pt- and refractory alloys. These specially designed and built test facilities are compared to commercially available high-vacuum test chambers with tungsten heater

Analysis of Thermal Properties on Backward Feed Multi effect Distillation Dealing with High-Salinity Wastewater

International Nuclear Information System (INIS)

Xue, J.; Ming, J.; Li, L.; Cui, Q.; Bai, Y.

2015-01-01

Theoretical investigations on thermal properties of multi effect distillation (MED) are presented to approach lower capital costs and more distillated products. A mathematical model, based on the energy and mass balance, is developed to (i) evaluate the influences of variations in key parameters (effect numbers, evaporation temperature in last effect, and feed salinity) on steam consumption, gained output ratio (GOR), and total heat transfer areas of MED and (II) compare two operation modes (backward feed (BF) and forward feed (FF) systems). The result in the first part indicated that GOR and total heat transfer areas increased with the effect numbers. Also, higher effect numbers result in the fact that the evaporation temperature in last effect has slight influence on GOR, while it influences the total heat transfer areas remarkably. In addition, an increase of feed salinity promotes the total heat transfer areas but reduces GOR. The analyses in the second part indicate that GOR and total heat transfer areas of BF system are higher than those in FF system. One thing to be aware of is that the changes of steam consumption can be omitted, considering that it shows an opposite trend to GOR.

Cermet insert high voltage holdoff for ceramic/metal vacuum devices

Science.gov (United States)

Ierna, William F.

1987-01-01

An improved metal-to-ceramic seal is provided wherein the ceramic body of the seal contains an integral region of cermet material in electrical contact with the metallic member, e.g., an electrode, of the seal. The seal is useful in high voltage vacuum devices, e.g., vacuum switches, and increases the high-voltage holdoff capabilities of such devices. A method of fabricating such seals is also provided.

Multipartite nonlocality distillation

International Nuclear Information System (INIS)

Hsu, Li-Yi; Wu, Keng-Shuo

2010-01-01

The stronger nonlocality than that allowed in quantum theory can provide an advantage in information processing and computation. Since quantum entanglement is distillable, can nonlocality be distilled in the nonsignalling condition? The answer is positive in the bipartite case. In this article the distillability of the multipartite nonlocality is investigated. We propose a distillation protocol solely exploiting xor operations on output bits. The probability-distribution vectors and matrix are introduced to tackle the correlators. It is shown that only the correlators with extreme values can survive the distillation process. As the main result, the amplified nonlocality cannot maximally violate any Bell-type inequality. Accordingly, a distillability criterion in the postquantum region is proposed.

Distillation of hydrogen isotopes for polarized HD targets

Energy Technology Data Exchange (ETDEWEB)

Ohta, T., E-mail: takeshi@rcnp.osaka-u.ac.jp [Research Center for Nuclear Physics, Osaka University, Mihogaoka 10-1, Ibaraki, Osaka 567-0047 (Japan); Bouchigny, S. [IN2P3, Institut de Physique Nucleaire, F-91406 Orsay (France); CEA LIST, BP6-92265 Fontenay-aux-Roses, CEDEX (France); Didelez, J.-P. [IN2P3, Institut de Physique Nucleaire, F-91406 Orsay (France); Fujiwara, M. [Research Center for Nuclear Physics, Osaka University, Mihogaoka 10-1, Ibaraki, Osaka 567-0047 (Japan); Fukuda, K. [Kansai University of Nursing and Health Sciences, Shizuki Awaji 656-2131 (Japan); Kohri, H.; Kunimatsu, T.; Morisaki, C.; Ono, S. [Research Center for Nuclear Physics, Osaka University, Mihogaoka 10-1, Ibaraki, Osaka 567-0047 (Japan); Rouille, G. [IN2P3, Institut de Physique Nucleaire, F-91406 Orsay (France); Tanaka, M. [Kobe Tokiwa University, Ohtani-cho 2-6-2, Nagata, Kobe 653-0838 (Japan); Ueda, K.; Uraki, M.; Utsuro, M. [Research Center for Nuclear Physics, Osaka University, Mihogaoka 10-1, Ibaraki, Osaka 567-0047 (Japan); Wang, S.Y. [Institute of Physics, Academia Sinica, Taipei 11529, Taiwan (China); Department of Physics, National Kaohsiung Normal University, Kaohsiung 824, Taiwan (China); Yosoi, M. [Research Center for Nuclear Physics, Osaka University, Mihogaoka 10-1, Ibaraki, Osaka 567-0047 (Japan)

2012-02-01

We have developed a new cryogenic distillation system to purify Hydrogen-Deuteride (HD) gas for polarized HD targets in LEPS experiments at SPring-8. A small amount of ortho-H{sub 2} ({approx}0.01%) in the HD gas plays an important role in efficiently polarizing the HD target. Since there are 1-5% impurities of H{sub 2} and D{sub 2} in commercially available HD gases, it is necessary to purify the HD gas up to {approx}99.99%. The distillation system is equipped with a cryogenic distillation unit filled with many small stainless steel cells called 'Heli-pack'. The distillation unit consists of a condenser part, a rectification part, and a reboiler part. The unit is kept at the temperature of 17-21 K. The Heli-pack has a large surface area that makes a good contact between gases and liquids. An amount of 5.2 mol of commercial HD gas is fed into the distillation unit. Three trials were carried out to purify the HD gas by changing temperatures (17.5 K and 20.5 K) and gas extraction speeds (1.3 ml/min and 5.2 ml/min). The extracted gas was analyzed using a gas analyzer system combining a quadrupole mass spectrometer with a gas chromatograph. One mol of HD gas with a purity better than 99.99% has been successfully obtained for the first time. The effective NTP (Number of Theoretical Plates), which is an indication of the distillation performances, is obtained to be 37.2{+-}0.6. This value is in good agreement with a designed value of 37.9. The HD target is expected to be efficiently polarized under a well-controlled condition by adding an optimal amount of ortho-H{sub 2} to the purified HD gas.

Continuous distillation of bituminous shale. [hot gas in chamber and chamber heated externally

Energy Technology Data Exchange (ETDEWEB)

1921-04-27

A process of continuous distillation of bituminous shale is given in which the heat necessary is produced not only on the exterior but also in the interior of the distillation apparatus in the form of hot gas directly bathing the shale. The residual carbon in the shale after distillation, or maybe with other fuel added to it, can be utilized; the fuel may be utilized not only for the heat it furnishes but also for the gas it gives and which adds itself to the incondensable gas from the distillation. The temperature of the zone of distillation of the shale is regulated by the quantity of gas, the temperature of this gas (which can be lowered voluntarily by injecting into the air a certain quantity of water vapor), the length of the zone comprised between the zone of gasification and distillation; the injection of water vapor permits the recovery of part of the nitrogen of the shale in the form of ammonia; the materials are withdrawn continuously in a mechanical way.

High Charge State Ions Extracted from Metal Plasmas in the Transition Regime from Vacuum Spark to High Current Vacuum Arc

International Nuclear Information System (INIS)

Yushkov, Georgy Yu.; Anders, A.

2008-01-01

Metal ions were extracted from pulsed discharge plasmas operating in the transition region between vacuum spark (transient high voltage of kV) and vacuum arc (arc voltage ∼ 20 V). At a peak current of about 4 kA, and with a pulse duration of 8 (micro)s, we observed mean ion charges states of about 6 for several cathode materials. In the case of platinum, the highest average charge state was 6.74 with ions of charge states as high as 10 present. For gold we found traces of charge state 11, with the highest average charge state of 7.25. At currents higher than 5 kA, non-metallic contaminations started to dominate the ion beam, preventing further enhancement of the metal charge states

Production of uranium metal via electrolytic reduction of uranium oxide in molten LiCl and salt distillation

International Nuclear Information System (INIS)

Eun-Young Choi; Chan Yeon Won; Dae-Seung Kang; Sung-Wook Kim; Ju-Sun Cha; Sung-Jai Lee; Wooshin Park; Hun Suk Im; Jin-Mok Hur

2015-01-01

Recovery of metallic uranium has been achieved by electrolytic reduction of uranium oxide in a molten LiCl-Li 2 O electrolyte at 650 deg C, followed by the removal of the residual salt by vacuum distillation at 850 deg C. Four types of stainless steel mesh baskets, with various mesh sizes (325, 1,400 and 2,300 meshes) and either three or five ply layers, were used both as cathodes and to contain the reduced product in the distillation stage. The recovered uranium had a metal fraction greater than 98.8 % and contained no residual salt. (author)

Baking of SST-1 vacuum vessel modules and sectors

International Nuclear Information System (INIS)

Pathan, Firozkhan S; Khan, Ziauddin; Yuvakiran, Paravastu; George, Siju; Ramesh, Gattu; Manthena, Himabindu; Shah, Virendrakumar; Raval, Dilip C; Thankey, Prashant L; Dhanani, Kalpesh R; Pradhan, Subrata

2012-01-01

SST-1 Tokamak is a steady state super-conducting tokamak for plasma discharge of 1000 sec duration. The plasma discharge of such long time duration can be obtained by reducing the impurities level, which will be possible only when SST-1 vacuum chamber is pumped to ultra high vacuum. In order to achieve UHV inside the chamber, the baking of complete vacuum chamber has to be carried out during pumping. For this purpose the C-channels are welded inside the vacuum vessel. During baking of vacuum vessel, these welded channels should be helium leak tight. Further, these U-channels will be in accessible under operational condition of SST-1. So, it will not possible to repair if any leak is developed during experiment. To avoid such circumstances, a dedicated high vacuum chamber is used for baking of the individual vacuum modules and sectors before assembly so that any fault during welding of the channels will be obtained and repaired. This paper represents the baking of vacuum vessel modules and sectors and their temperature distribution along the entire surface before assembly.

Electronic ceramics in high-temperature environments

International Nuclear Information System (INIS)

Searcy, A.W.; Meschi, D.J.

1982-01-01

Simple thermodynamic means are described for understanding and predicting the influence of temperature changes, in various environments, on electronic properties of ceramics. Thermal gradients, thermal cycling, and vacuum annealing are discussed, as well as the variations of ctivities and solubilities with temperature. 7 refs

Entropy Generation of Desalination Powered by Variable Temperature Waste Heat

Directory of Open Access Journals (Sweden)

David M. Warsinger

2015-10-01

Full Text Available Powering desalination by waste heat is often proposed to mitigate energy consumption and environmental impact; however, thorough technology comparisons are lacking in the literature. This work numerically models the efficiency of six representative desalination technologies powered by waste heat at 50, 70, 90, and 120 °C, where applicable. Entropy generation and Second Law efficiency analysis are applied for the systems and their components. The technologies considered are thermal desalination by multistage flash (MSF, multiple effect distillation (MED, multistage vacuum membrane distillation (MSVMD, humidification-dehumidification (HDH, and organic Rankine cycles (ORCs paired with mechanical technologies of reverse osmosis (RO and mechanical vapor compression (MVC. The most efficient technology was RO, followed by MED. Performances among MSF, MSVMD, and MVC were similar but the relative performance varied with waste heat temperature or system size. Entropy generation in thermal technologies increases at lower waste heat temperatures largely in the feed or brine portions of the various heat exchangers used. This occurs largely because lower temperatures reduce recovery, increasing the relative flow rates of feed and brine. However, HDH (without extractions had the reverse trend, only being competitive at lower temperatures. For the mechanical technologies, the energy efficiency only varies with temperature because of the significant losses from the ORC.

Vacuum die attach for integrated circuits

Science.gov (United States)

Schmitt, E.H.; Tuckerman, D.B.

1991-09-10

A thin film eutectic bond for attaching an integrated circuit die to a circuit substrate is formed by coating at least one bonding surface on the die and substrate with an alloying metal, assembling the die and substrate under compression loading, and heating the assembly to an alloying temperature in a vacuum. A very thin bond, 10 microns or less, which is substantially void free, is produced. These bonds have high reliability, good heat and electrical conduction, and high temperature tolerance. The bonds are formed in a vacuum chamber, using a positioning and loading fixture to compression load the die, and an IR lamp or other heat source. For bonding a silicon die to a silicon substrate, a gold silicon alloy bond is used. Multiple dies can be bonded simultaneously. No scrubbing is required. 1 figure.

Preparation of high-purity tellurium by the combination method

International Nuclear Information System (INIS)

Kogtev, P.M.; Khachishvili, V.I.; Mozdokeli, T.G.

1978-01-01

Vacuum distillation followed by condensation in hydrogen flow has been studied as a means of T-1 brand Te purification (particularly from Se). The distillation lasted for 4-5 hours at 530-550 deg C under residual pressure of 10 -3 Torr. A schematic of the apparatus for the purification is given. Condensation under hydrogen flow decreases the amount of impurities in Te; double condensation reduces the Se content by 2 orders of magnitude. The product obtained after vacuum distillation and double condensation under pure H sub(2) is 99.999 % Te

Influence of a high vacuum on the precise positioning using an ultrasonic linear motor.

Science.gov (United States)

Kim, Wan-Soo; Lee, Dong-Jin; Lee, Sun-Kyu

2011-01-01

This paper presents an investigation of the ultrasonic linear motor stage for use in a high vacuum environment. The slider table is driven by the hybrid bolt-clamped Langevin-type ultrasonic linear motor, which is excited with its different modes of natural frequencies in both lateral and longitudinal directions. In general, the friction behavior in a vacuum environment becomes different from that in an environment of atmospheric pressure and this difference significantly affects the performance of the ultrasonic linear motor. In this paper, to consistently provide stable and high power of output in a high vacuum, frequency matching was conducted. Moreover, to achieve the fine control performance in the vacuum environment, a modified nominal characteristic trajectory following control method was adopted. Finally, the stage was operated under high vacuum condition, and the operating performances were investigated compared with that of a conventional PI compensator. As a result, robustness of positioning was accomplished in a high vacuum condition with nanometer-level accuracy.

Influence of a high vacuum on the precise positioning using an ultrasonic linear motor

International Nuclear Information System (INIS)

Kim, Wan-Soo; Lee, Dong-Jin; Lee, Sun-Kyu

2011-01-01

This paper presents an investigation of the ultrasonic linear motor stage for use in a high vacuum environment. The slider table is driven by the hybrid bolt-clamped Langevin-type ultrasonic linear motor, which is excited with its different modes of natural frequencies in both lateral and longitudinal directions. In general, the friction behavior in a vacuum environment becomes different from that in an environment of atmospheric pressure and this difference significantly affects the performance of the ultrasonic linear motor. In this paper, to consistently provide stable and high power of output in a high vacuum, frequency matching was conducted. Moreover, to achieve the fine control performance in the vacuum environment, a modified nominal characteristic trajectory following control method was adopted. Finally, the stage was operated under high vacuum condition, and the operating performances were investigated compared with that of a conventional PI compensator. As a result, robustness of positioning was accomplished in a high vacuum condition with nanometer-level accuracy.

Development of vacuum brazing furnace

International Nuclear Information System (INIS)

Singh, Rajvir; Yedle, Kamlesh; Jain, A.K.

2005-01-01

In joining of components where welding process is not possible brazing processes are employed. Value added components, high quality RF systems, UHV components of high energy accelerators, carbide tools etc. are produced using different types of brazing methods. Furnace brazing under vacuum atmosphere is the most popular and well accepted method for production of the above mentioned components and systems. For carrying out vacuum brazing successfully it is essential to have a vacuum brazing furnace with latest features of modern vacuum brazing technology. A vacuum brazing furnace has been developed and installed for carrying out brazing of components of copper, stainless steel and components made of dissimilar metals/materials. The above furnace has been designed to accommodate jobs of 700mm diameter x 2000mm long sizes with job weight of 500kgs up to a maximum temperature of 1250 degC at a vacuum of 5 x 10 -5 Torr. Oil diffusion pumping system with a combination of rotary and mechanical booster pump have been employed for obtaining vacuum. Molybdenum heating elements, radiation shield of molybdenum and Stainless Steel Grade 304 have been used. The above furnace is computer controlled with manual over ride facility. PLC and Pentium PC are integrated together to maneuver steps of operation and safety interlocks of the system. Closed loop water supply provides cooling to the system. The installation of the above system is in final stage of completion and it will be ready for use in next few months time. This paper presents insights of design and fabrication of a modern vacuum brazing furnace and its sub-system. (author)

Development of a pilot molecular distillation unit; Desenvolvimento de unidade de destilacao molecular nacional e aplicacao na avaliacao de petroleos extrapesados

Energy Technology Data Exchange (ETDEWEB)

Rocha, Erica Roberta Lovo da; Maciel, Maria Regina Wolf; Maciel Filho, Rubens; Batistella, Cesar Benedito [Universidade Estadual de Campinas (UNICAMP), SP (Brazil); Medina, Lilian Carmem [PETROBRAS S.A., Rio de Janeiro, RJ (Brazil). Centro de Pesquisas (CENPES)

2008-07-01

Due to the importance and the need in studies with heavy and extra heavy petroleums and their residues, it was designed and built up by the oil research group of LOPCA/LDPS/FEQ/UNICAMP, in partnership with the Laboratory of Valuation Processes of CENPES / PETROBRAS, a pilot plant of falling film molecular distiller (national prototype), where some specific operational facilities were introduced. This project resulted in a suitable system for distillation of products of high molecular weight and thermally sensitive, without degradation of them. This work aims the achievement of distillate fractions of atmospheric residue 400 deg C+, using the new molecular distillation equipment. The experiments were carried out according to factorial design to assess the significant process variables in the molecular distillation prototype. The results showed that the evaporator temperature has high influence on the process and the feed flow rate has minimum influence, as it is desired. Additionally, the equipment showed easy handing operation, high operational stability and results varying around 1%. (author)

Modelling of solar distillation system with phase change material (PCM storage medium

Directory of Open Access Journals (Sweden)

Al-Hamadani Ali A.F.

2014-01-01

Full Text Available An experimental investigation on a passive solar still with myristic acid as phase change material (PCM is carried out to examine the effect of both the mass of PCM and basin water on the daily distillate output and efficiency of the system under indoor simulated condition. Basic energy balance equations are written to predict the water and glass temperatures, daily distillate output and instantaneous efficiency of the single slope solar distillation system with PCM. It is found that the higher mass of PCM with lower mass of water in the solar still basin significantly increases the daily yield and efficiency, but when the amount of PCM exceeds 20 kg productivity reduces. Therefore, a novel and simple of solar stills with PCM is proposed to enhance the overall productivity of the distillation system. The new solar still has increased the distillate output by 35-40%. The use of inner glass cover temperature for productivity prediction has also been investigated, and the prediction shows relatively better agreement with the experimental data.

Catalytic distillation structure

Science.gov (United States)

Smith, L.A. Jr.

1984-04-17

Catalytic distillation structure is described for use in reaction distillation columns, and provides reaction sites and distillation structure consisting of a catalyst component and a resilient component intimately associated therewith. The resilient component has at least about 70 volume % open space and is present with the catalyst component in an amount such that the catalytic distillation structure consists of at least 10 volume % open space. 10 figs.

Use of azeotropic distillation for isotopic analysis of deuterium in soil water and saturate saline solution

International Nuclear Information System (INIS)

Santos, Antonio Vieira dos.

1995-05-01

The azeotropic distillation technique was adapted to extract soil water and saturate saline solution, which is similar to the sea water for the Isotopic Determination of Deuterium (D). A soil test was used to determine the precision and the nature of the methodology to extract soil water for stable isotopic analysis, using the azeotropic distillation and comparing with traditional methodology of heating under vacuum. This methodology has been very useful for several kinds of soil or saturate saline solution. The apparatus does not have a memory effect, and the chemical reagents do not affect the isotopic composition of soil water. (author). 43 refs., 10 figs., 12 tabs

Production of ceramic-metal joints for high-vacuum applications and development of simulation program for discharge tube

Energy Technology Data Exchange (ETDEWEB)

Kang, S. H.; Chung, K. H. [Seoul National University, Seoul (Korea)

2000-04-01

To develop a ceramic-metal jointed tube for high-vacuum applications, metalizing process and active metal brazing were investigated. Active metal brazing was adopted as a joining process to produce a high-vacuum tube which had high joint strength and reliability. A possibility for the development of new composition of Mo-Mn paste was studied. Also, to improve the strength and reliability of active metal brazed joint, TiN coating was introduced as a diffusion barrier. It was revealed that TiN coating could improve the joint strength and reliability. 100mm {phi} tube joint was produced using incusil ABA brazing alloy. The strength and reliability of manufactured tube showed higher value than commercial one. The electric field distribution in ceramic tube under high voltage was analyzed. Two dimensional electric field distribution was investigated under the existence of charged particles. From this result, electric field distribution at the surface of ceramic tube and the location of high electric field was predicted. Finally, Arc discharge was simulated to analyze the effect of arc discharge on the discharge tube wall. The maximum temperature of arc was 12000-13000K. The wall temperature was increased 100-170K by the arc discharge. 45 refs., 57 figs., 4 tabs. (Author)

Hydrocracking of atmospheric distillable residue of Mongolian oil

Directory of Open Access Journals (Sweden)

Ts Tugsuu

2014-09-01

Full Text Available Many catalytic processes to refine heavy part of crude oil have attracted much interest due to declining reserves of light crude oils. This study focused on hydrocracking process of atmospheric distillable residue of Mongolian crude oil in the first time compared to those of other countries. Residue samples were hydrocracked with a commercial catalyst at 450°C, 460°C, 470°C for 2 h under hydrogen pressure of 10 MPa. The amount of residual fraction (350°Cdistillable residue from Tamsagbulag crude oil. When the ME-AR was hydrocracked, the high consumption of hydrogen was related to the lowest H/C atomic ratio of feed atmospheric residue. The amount of liquid fractions (BP<350°C including gaseous products increased from 45.4wt% to 89.2wt%, when the reaction temperature increased from 450°C to 470°C. The highest yield of the middle fraction for each sample was observed at temperature of 460°C. On the other hand, the effect of temperature on the yield of middle fraction was not so high as compared with the yields of other fractions. The contents of n-paraffins on midlle and heavy fractions of TB-AR, DQ-AR were similar, but ME-AR’s was around 2 times lower than other after hydrocracking runs.DOI: http://dx.doi.org/10.5564/mjc.v12i0.166 Mongolian Journal of Chemistry Vol.12 2011: 24-28 

Vacuum system of SST-1 Tokamak

Energy Technology Data Exchange (ETDEWEB)

Khan, Ziauddin, E-mail: ziauddin@ipr.res.in [Institute for Plasma Research, Near Indira Bridge, Bhat, Gandhinagar 382 428 (India); Pathan, Firozkhan; George, Siju; Semwal, Pratibha; Dhanani, Kalpesh; Paravastu, Yuvakiran; Thankey, Prashant; Ramesh, Gattu; Himabindu, Manthena; Pradhan, Subrata [Institute for Plasma Research, Near Indira Bridge, Bhat, Gandhinagar 382 428 (India)

2013-10-15

Highlights: ► Air leaks developed during ongoing SST-1 cooldown campaign were detected online using RGA. ► The presence of N{sub 2} and O{sub 2} gases with the ratio of their partial pressures with ∼3.81:1 confirmed the air leaks. ► Baking of SST-1 was done efficiently by flowing hot N{sub 2} gas in C-channels welded on inner surfaces without any problem. ► In-house fabricated demountable bull nose couplers were demonstrated for high temperature and pressure applications. ► Cryopumping effect was observed when liquid helium cooled superconducting magnets reached below 63 K. -- Abstract: Vacuum chambers of Steady State Superconducting (SST-1) Tokamak comprises of the vacuum vessel and the cryostat. The plasma will be confined inside the vacuum vessel while the cryostat houses the superconducting magnet systems (TF and PF coils), LN{sub 2} cooled thermal shields and hydraulics for these circuits. The vacuum vessel is an ultra-high (UHV) vacuum chamber while the cryostat is a high-vacuum (HV) chamber. In order to achieve UHV inside the vacuum vessel, it would be baked at 150 °C for longer duration. For this purpose, U-shaped baking channels are welded inside the vacuum vessel. The baking will be carried out by flowing hot nitrogen gas through these channels at 250 °C at 4.5 bar gauge pressure. During plasma operation, the pressure inside the vacuum vessel will be raised between 1.0 × 10{sup −4} mbar and 1.0 × 10{sup −5} mbar using piezoelectric valves and control system. An ultimate pressure of 4.78 × 10{sup −6} mbar is achieved inside the vacuum vessel after 100 h of pumping. The limitation is due to the development of few leaks of the order of 10{sup −5} mbar l/s at the critical locations of the vacuum vessel during baking which was confirmed with the presence of nitrogen gas and oxygen gas with the ratio of ∼3.81:1 indicating air leak. Similarly an ultimate vacuum of 2.24 × 10{sup −5} mbar is achieved inside the cryostat. Baking of the

Process and apparatus for destructive distillation

Energy Technology Data Exchange (ETDEWEB)

Dalin, D; Hedbaeck, T J

1951-01-10

A process of distilling wood, coal, shale, and like materials in an externally heated retort, consists of heating the retort by burning fuel in a combustion chamber completely or partly surrounding the retort and passing a heat-absorbing medium through ducts which are mounted in or adjacent the greater part of the length of the retort walls which are so arranged as to effect a greater degree of heat extraction at one part of the retort than at another part of the retort. The zones of different heat extraction being related to the heat developed in the combustion chamber maintains the most favourable distillation temperature in all parts of the retort.

Three-phase fluidized distillation

International Nuclear Information System (INIS)

Ravagnani, T.M.K.; Pereira, J.A.F.R.

2001-01-01

Separation efficiency in distillation operations can be improved by modifying the characteristics of the dispersions formed on the trays. The present work reports on the hydrodynamic and mass transfer characteristics of liquid-solid-vapour dispersions formed on sieve trays without downcomers of a distillation column operating under total reflux conditions. Murphree efficiency and the operating limits of distillation using the ethanol-n-butanol system are analyzed for a large range of vapour velocities and liquid mixture compositions, utilising wettable PVC particles and non-wettable silicone, PE, and Teflon((R)) particles. It was verified that wettable particles show a drastic reduction in the upper operating limit of vapour velocity, but this does not occur for non-wettable particles. Tray efficiency can be increased when non-wettable particles are used, mainly for high vapour velocity operations. (author)

Quality Evaluation of Agricultural Distillates Using an Electronic Nose

Directory of Open Access Journals (Sweden)

Tomasz Dymerski

2013-11-01

Full Text Available The paper presents the application of an electronic nose instrument to fast evaluation of agricultural distillates differing in quality. The investigations were carried out using a prototype of electronic nose equipped with a set of six semiconductor sensors by FIGARO Co., an electronic circuit converting signal into digital form and a set of thermostats able to provide gradient temperature characteristics to a gas mixture. A volatile fraction of the agricultural distillate samples differing in quality was obtained by barbotage. Interpretation of the results involved three data analysis techniques: principal component analysis, single-linkage cluster analysis and cluster analysis with spheres method. The investigations prove the usefulness of the presented technique in the quality control of agricultural distillates. Optimum measurements conditions were also defined, including volumetric flow rate of carrier gas (15 L/h, thermostat temperature during the barbotage process (15 °C and time of sensor signal acquisition from the onset of the barbotage process (60 s.

Quality evaluation of agricultural distillates using an electronic nose.

Science.gov (United States)

Dymerski, Tomasz; Gębicki, Jacek; Wardencki, Waldemar; Namieśnik, Jacek

2013-11-25

The paper presents the application of an electronic nose instrument to fast evaluation of agricultural distillates differing in quality. The investigations were carried out using a prototype of electronic nose equipped with a set of six semiconductor sensors by FIGARO Co., an electronic circuit converting signal into digital form and a set of thermostats able to provide gradient temperature characteristics to a gas mixture. A volatile fraction of the agricultural distillate samples differing in quality was obtained by barbotage. Interpretation of the results involved three data analysis techniques: principal component analysis, single-linkage cluster analysis and cluster analysis with spheres method. The investigations prove the usefulness of the presented technique in the quality control of agricultural distillates. Optimum measurements conditions were also defined, including volumetric flow rate of carrier gas (15 L/h), thermostat temperature during the barbotage process (15 °C) and time of sensor signal acquisition from the onset of the barbotage process (60 s).

Fouling in Membrane Distillation, Osmotic Distillation and Osmotic Membrane Distillation

Directory of Open Access Journals (Sweden)

Mourad Laqbaqbi

2017-03-01

Full Text Available Various membrane separation processes are being used for seawater desalination and treatment of wastewaters in order to deal with the worldwide water shortage problem. Different types of membranes of distinct morphologies, structures and physico-chemical characteristics are employed. Among the considered membrane technologies, membrane distillation (MD, osmotic distillation (OD and osmotic membrane distillation (OMD use porous and hydrophobic membranes for production of distilled water and/or concentration of wastewaters for recovery and recycling of valuable compounds. However, the efficiency of these technologies is hampered by fouling phenomena. This refers to the accumulation of organic/inorganic deposits including biological matter on the membrane surface and/or in the membrane pores. Fouling in MD, OD and OMD differs from that observed in electric and pressure-driven membrane processes such electrodialysis (ED, membrane capacitive deionization (MCD, reverse osmosis (RO, nanofiltration (NF, ultrafiltration (UF, microfiltration (MF, etc. Other than pore blockage, fouling in MD, OD and OMD increases the risk of membrane pores wetting and reduces therefore the quantity and quality of the produced water or the concentration efficiency of the process. This review deals with the observed fouling phenomena in MD, OD and OMD. It highlights different detected fouling types (organic fouling, inorganic fouling and biofouling, fouling characterization techniques as well as various methods of fouling reduction including pretreatment, membrane modification, membrane cleaning and antiscalants application.

Electrical Thermal Network for Direct Contact Membrane Distillation Modeling and Analysis

KAUST Repository

Karam, Ayman M.

2015-02-04

Membrane distillation is an emerging water distillation technology that offers several advantages compared to conventional water desalination processes. Although progress has been made to model and understand the physics of the process, many studies are based on steady-state assumptions or are computationally not appropriate for real time control. This paper presents the derivation of a novel dynamical model, based on analogy between electrical and thermal systems, for direct contact membrane distillation (DCMD). The proposed model captures the dynamics of temperature distribution and distilled water flux. To demonstrate the adequacy of the proposed model, validation with transient and steady-state experimental data is presented.

Effects of vacuum annealing on the optical and electrical properties of p-type copper-oxide thin-film transistors

International Nuclear Information System (INIS)

Sohn, Joonsung; Song, Sang-Hun; Kwon, Hyuck-In; Nam, Dong-Woo; Cho, In-Tak; Lee, Jong-Ho; Cho, Eou-Sik

2013-01-01

We have investigated the effects of vacuum annealing on the optical and electrical properties of the p-type copper-oxide thin-film transistors (TFTs). The vacuum annealing of the copper-oxide thin-film was performed using the RF magnetron sputter at various temperatures. From the x-ray diffraction and UV-vis spectroscopy, it is demonstrated that the high-temperature vacuum annealing reduces the copper-oxide phase from CuO to Cu 2 O, and increases the optical transmittance in the visible part of the spectrum. The fabricated copper-oxide TFT does not exhibit the switching behavior under low-temperature vacuum annealing conditions. However, as the annealing temperature increases, the drain current begins to be modulated by a gate voltage, and the TFT exhibits a high current on–off ratio over 10 4 as the vacuum annealing temperature increases over 450 °C. These results show that the vacuum annealing process can be an effective method of simultaneously improving the optical and electrical performances in p-type copper-oxide TFTs. (paper)

Distilling hydrocarbon oils

Energy Technology Data Exchange (ETDEWEB)

Schulze, J E

1923-03-19

In distilling mineral oils such as petroleum, shale oil, distillates and topped or residual oils, particularly to obtain lubricating oils, the distillation is carried out under reduced pressures below an absolute pressure of 25 mm. of mercury and preferably below about 5 mm. of mercury, and the distillate is collected in fractions determined by the physical characteristics, such as viscosity, flash point, fire point, etc. Superheated steam may be passed through the liquid during distillation. A horizontal cylindrical still provided with cross braces and peripheral ribs interrupted at the base is connected through a condensing coil immersed in a steam chest and a baffled chamber with distillate receiver and is evacuated by a pump. Steam from a boiler and superheater is injected into the still through a perforated pipe. Steam and light oil vapors passing from the chamber are condensed in a coil.

HIGH PRESSURE VAPOR-LIQUID EQUILIBRIA OF PALM FATTY ACIDS DISTILLATES-CARBON DIOXIDE SYSTEM

Directory of Open Access Journals (Sweden)

Nélio T. MACHADO

1997-12-01

Full Text Available Vapor-Liquid equilibria of palm fatty acids distillates/carbon dioxide system has been investigated experimentally at temperatures of 333, 353, and 373 K and pressures of 20, 23, 26, and 29 MPa using the static method. Experimental data for the quasi-binary system palm fatty acids distillates/carbon dioxide has been correlated with Redlich-Kwong-Aspen equation of state. Modeling shows good agreement with experimental data. Selectivity obtained indicates that supercritical carbon dioxide is a reasonable solvent for separating saturated (palmitic acid and unsaturated (oleic+linoleic acids fatty acids from palm fatty acids distillates in a continuous multistage countercurrent column.Foi investigado experimentalmente o equilíbrio líquido-vapor para o sistema Destilado Ácido de Óleo de Palma (PFAD/Dióxido de Carbono, nas temperaturas de 333, 353 e 373 K e pressões de 20, 23, 26 e 29 MPa, usando-se o método estático. Os dados experimentais do sistema pseudo-binário PFAD/CO2 foram correlacionados com a equação de estado de Redlich-Kwong do pacote computacional ASPEN. O modelo reproduz bem os resultados experimentais. A seletividade obtida indica que o CO2 supercrítico é um solvente razoável para a separação em coluna multi-estágio e contínua, do ácido graxo saturado (ácido palmítico daqueles insaturados (ácido oleico e ácido linoleico contidos no PFAD.

Low temperature carbonization

Energy Technology Data Exchange (ETDEWEB)

Abbott, A A

1934-01-10

A process is described in which coal is passed through a distillation chamber in one retort at a comparatively low temperature, then passing the coal through a distillation chamber of a second retort subjected to a higher temperature, thence passing the coal through the distillation chamber of a third retort at a still higher temperature and separately collecting the liquid and vapors produced from each retort.

Modelling of crater formation on anode surface by high-current vacuum arcs

Science.gov (United States)

Tian, Yunbo; Wang, Zhenxing; Jiang, Yanjun; Ma, Hui; Liu, Zhiyuan; Geng, Yingsan; Wang, Jianhua; Nordlund, Kai; Djurabekova, Flyura

2016-11-01

Anode melting and crater formation significantly affect interruption of high-current vacuum arcs. The primary objective of this paper is to theoretically investigate the mechanism of anode surface crater formation, caused by the combined effect of surface heating during the vacuum arc and pressure exerted on the molten surface by ions and electrons from the arc plasma. A model of fluid flow and heat transfer in the arc anode is developed and combined with a magnetohydrodynamics model of the vacuum arc plasma. Crater formation is observed in simulation for a peak arcing current higher than 15 kA on 40 mm diam. Cu electrodes spaced 10 mm apart. The flow of liquid metal starts after 4 or 5 ms of arcing, and the maximum velocities are 0.95 m/s and 1.39 m/s for 20 kA and 25 kA arcs, respectively. This flow redistributes thermal energy, and the maximum temperature of the anode surface does not remain in the center. Moreover, the condition for the liquid droplet formation on the anode surfaces is developed. The solidification process after current zero is also analyzed. The solidification time has been found to be more than 3 ms after 25 kA arcing. The long solidification time and sharp features on crater rims induce Taylor cone formation.

Mass and heat transfer on B7 ordered packing in hydrogen isotope separation by distillation

International Nuclear Information System (INIS)

Croitoru, Cornelia; Pop, Floarea; Titescu, Gheorghe; Stefanescu, Ioan; Trancota, Dan; Peculea, Marius

2002-01-01

This work presents theoretical and experimental data referring to mass and heat transfer on B7 ordered packing in deuterium isotope separation by distillation. The first part is devoted to the study of mass transfer in hydrogen isotopic distillation while the second one treats the mass and heat transfer in water isotopic distillation. A stationary mathematical model for the mass and heat transfer was developed based on multitubular column model with wet wall. This model allowed the calculation starting from theoretical data of the ordered packing efficiency, expressed by the transfer unit height, TUH. Also, from theoretical data the mass and heat transfer coefficients were determined. A test of the mathematical model was performed with the experimental data obtained from two laboratory installations for hydrogen isotope separation by distillation. From the first installation, experimental data concerning the B7 ordered packing efficiency were obtained for the deuterium separation by cryogenic distillation at the - 250 deg C level. With the second one data referring to the mass and heat transfer on the same packing were obtained for the deuterium separation by water distillation under vacuum at the 60 deg C level. The values of TUH, mass and heat transfer coefficients as theoretically evaluate and experimentally checked are in agreement with the respective values obtained in separation processes in chemical industry. This is the fact which endorses utilization of the model of multitubular column with wet wall for describing the transfer processes in distillation columns equipped with B7 ordered packing

Destructive distillation

Energy Technology Data Exchange (ETDEWEB)

1915-07-03

Oils are extracted from coal, lignite, shale, boghead, butumen, asphalt, tar, pitch, etc., by distillation at a low temperature, which may be 300 to 425/sup 0/CC, solvent oils or vapors being circulated during the heating which may be conducted with or without increased or reduced pressure. The solvent oils and the extracted oils are recovered in condensers, etc., last traces being expelled from the material by a current of water vapor. The uncondensed gases may be used for heating, and the solid residue may be used for the production of gas and coke, or may be briquetted.

Shale distillation

Energy Technology Data Exchange (ETDEWEB)

Blanding, F H

1946-08-29

A continuous method of distilling shale to produce valuable hydrocarbon oils is described which comprises providing a fluidized mass of the shale in a distillation zone, withdrawing hydrocarbon vapors from the zone, mixing fresh cold shale with the hydrocarbon vapors to quench the same, whereby the fresh shale is preheated, recovering hydrocarbon vapors and product vapors from the mixture and withdrawing preheated shale from the mixture and charging it to a shale distillation zone.

Vacuum surface flashover and high pressure gas streamers

International Nuclear Information System (INIS)

Elizondo, J.M.; Krogh, M.L.; Smith, D.; Stolz, D.; Wright, S.N.

1997-07-01

Pre-breakdown current traces obtained during high pressure gas breakdown and vacuum surface flashover show similar signatures. The initial pre-breakdown current spike, a flat constant current phase, and the breakdown phase with voltage collapse and current surge differ mostly in magnitude. Given these similarities, a model, consisting of the initial current spike corresponding to a fast precursor streamer (ionization wave led by a photoionizing front), the flat current stage as the heating or glow phase, and the terminal avalanche and gap closure, is applied to vacuum surface flashover. A simple analytical approximation based on the resistivity changes induced in the vacuum and dielectric surface is presented. The approximation yields an excellent fit to pre-breakdown time delay vs applied field for previously published experimental data. A detailed kinetics model that includes surface and gas contributions is being developed based in the initial approximation

Fast-opening vacuum switches for high-power inductive energy storage

International Nuclear Information System (INIS)

Cooperstein, G.

1988-01-01

The subject of fast-opening vacuum switches for high-power inductive energy storage is emerging as an exciting new area of plasma science research. This opening switch technology, which generally involves the use of plasmas as the switching medium, is key to the development of inductive energy storage techniques for pulsed power which have a number of advantages over conventional capacitive techniques with regard to cost and size. This paper reviews the state of the art in this area with emphasis on applications to inductive storage pulsed power generators. Discussion focuses on fast-opening vacuum switches capable of operating at high power (≥10 12 W). These include plasma erosion opening switches, ion beam opening switches, plasma filled diodes, reflex diodes, plasma flow switches, and other novel vacuum opening switches

Experiment on the Influence Factors of Steam Distillation Rate of Crude Oil in Porous Media

Directory of Open Access Journals (Sweden)

Tian Guoqing

2017-01-01

Full Text Available To explore the influence of complexity of reservoir properties in porous media and the diversity of operating conditions on the steam distillation rate of crude oil in the process of heavy oil exploitation with steam injection, steam distillation simulation devices are used to study steam distillation rate of crude oil in porous media. Then steam distillation ratio is obtained under the condition of different core permeability, oil saturation, steam temperatures, system pressure, steam injection rates and steam distillation rates with different viscosities of crude oil. The results show that the steam distillation rate of crude oil in porous media depends mainly on the nature of the crude oil itself, for temperature and pressure are the key factors compared with the pore structure, the initial oil saturation and steam injection rate. The experimental results help estimate the amount of crude oil and the required steam in the reservoir in the steam drive process, aiming to facilitate the optimization design and operation of steam drive.

Vacuum Acceptance Tests for the UHV Room Temperature Vacuum System of the LHC during LS1

CERN Document Server

Cattenoz, G; Bregliozzi, G; Calegari, D; Gallagher, J; Marraffa, A; Chiggiato, P

2014-01-01

During the CERN Large Hadron Collider (LHC) first long shut down (LS1), a large number of vacuum tests are carried out on consolidated or newly fabricated devices. In such a way, the vacuum compatibility is assessed before installation in the UHV system of the LHC. According to the equipment’s nature, the vacuum acceptance tests consist in functional checks, leak test, outgassing rate measurements, evaluation of contaminants by Residual Gas Analysis (RGA), pumping speed measurements and qualification of the H2 sticking probability of Non-Evaporable-Getter (NEG) coating. In this paper, the methods used for the tests and the acceptance criteria are described. A summary of the measured vacuum characteristics for the tested components is also given.

The Properties of Polymer-Modified Asphalt Drived from Vacuum Bottom and Wastes of PE and SBR Plants

Directory of Open Access Journals (Sweden)

A. Yousefi

2008-12-01

Full Text Available The polymeric and non-polymeric petrochemical wastes are environmentally unfavorable materials. We have to found a way to reuse these wastes in a safe manner. In styrene-butadiene rubber (SBR production plant two major wastes are produced one is a fine rubber powder and the other is recycled N-methyl pyrrolidone (NMP. In high-density polyethylene (HDPE production plant also a low molecular weight polymer waste is produced which does not degrade in environment easily. On the other hand, bitumen is usually blended with thermoplastics, rubbers and an oil to produce polymermodified bitumens. Effect of SBR, PE and NMP wastes on vacuum bottom residue of crude oil distillation was investigated. The results of penetration, softening point and Frass tests revealed the advantages of SBR and PE wastes at high temperatures and suggest NMP waste as a good bitumen extender. The results of the Marshal test on the prepared polymer-modified hot-mix asphalt of the optimum formulation highlight the superiority of its strength and its lower flow as compared with those of standard 60/70 penetration grade bitumen.

High resolution, high speed ultrahigh vacuum microscopy

International Nuclear Information System (INIS)

Poppa, Helmut

2004-01-01

The history and future of transmission electron microscopy (TEM) is discussed as it refers to the eventual development of instruments and techniques applicable to the real time in situ investigation of surface processes with high resolution. To reach this objective, it was necessary to transform conventional high resolution instruments so that an ultrahigh vacuum (UHV) environment at the sample site was created, that access to the sample by various in situ sample modification procedures was provided, and that in situ sample exchanges with other integrated surface analytical systems became possible. Furthermore, high resolution image acquisition systems had to be developed to take advantage of the high speed imaging capabilities of projection imaging microscopes. These changes to conventional electron microscopy and its uses were slowly realized in a few international laboratories over a period of almost 40 years by a relatively small number of researchers crucially interested in advancing the state of the art of electron microscopy and its applications to diverse areas of interest; often concentrating on the nucleation, growth, and properties of thin films on well defined material surfaces. A part of this review is dedicated to the recognition of the major contributions to surface and thin film science by these pioneers. Finally, some of the important current developments in aberration corrected electron optics and eventual adaptations to in situ UHV microscopy are discussed. As a result of all the path breaking developments that have led to today's highly sophisticated UHV-TEM systems, integrated fundamental studies are now possible that combine many traditional surface science approaches. Combined investigations to date have involved in situ and ex situ surface microscopies such as scanning tunneling microscopy/atomic force microscopy, scanning Auger microscopy, and photoemission electron microscopy, and area-integrating techniques such as x-ray photoelectron

Investigations by the surface photo-E. M. F. method of the effect of low temperature vacuum baking of an Si(111) surface

Energy Technology Data Exchange (ETDEWEB)

Dlugosz, B.; Kochowski, S.

1982-02-26

Investigations of the effect of low temperature vacuum baking on the surface potential of silicon are reported. The surface potential Vsub(s0) was measured by the surface photo-e.m.f. method. No noticeable changes in Vsub(s0) occurred after baking of samples which had been freshly etched in HF for 2 h in a vacuum of 6.6 x 10/sup -3/ Pa (5 x 10/sup -5/ Torr) at temperatures of 573, 623 and 723 K. Radical changes were observed when the samples had been aged in air for 2 months before vacuum baking. These results suggest that the direction and the value of the surface potential changes during vacuum baking are determined by the initial surface state.

Distilling tar; distillation, destructive

Energy Technology Data Exchange (ETDEWEB)

Brash, P; Young, W

1866-09-17

The tarry residue, which separates on treating crude shale oil with sulfuric acid, is redistilled, in the manner described in Specification No. 1278, A.D. 1866, together with shale. Previous to the distillation, the acid is neutralized with lime, or may be separated by blowing steam into the tar and adding salt. The purified tar thus obtained is absorbed by ashes, or is mixed with lime or other alkaline matter, or the shale may be mixed with lime and distilled with the tar, which is allowed to flow over and through the shale during the process. The tar obtained in the purification of natural paraffin may be similarly utilized.

Determining the mode of high voltage breakdowns in vacuum devices

International Nuclear Information System (INIS)

Miller, H.C.; Furno, E.J.; Sturtz, J.P.

1980-01-01

Devices were constructed which were essentially vacuum diodes equipped with windows allowing observation of high voltage breakdowns. The waveform of the applied voltage was photographed, and the x-ray output was monitored to investigate electrical breakdown in these vacuum diodes. Results indicate that breakdowns may be divided into two types: (1) vacuum (interelectrode) breakdown - characterized by a diffuse moderately bright discharge, a relative slow and smooth voltage collapse, and a large burst of x-rays, and (2) surface (insulator) flashover - characterized by a bright discharge with a very bright filamentary core, a relatively fast and noisy voltage collapse and no x-ray burst. Useful information concerning the type of breakdown in a vacuum device can be obtained by monitoring the voltage (current) waveform and the x-ray output

Investigation of gadolinium monophosphide at high temperatures

International Nuclear Information System (INIS)

Gordienko, S.P.; Gol'nik, V.F.; Mironov, K.E.

1982-01-01

Gadolinium monophosphide has been studied in vacuum at high temperatures using mass-spectrometric, chemical, X-ray phase and derivatographical analyses. It is established that gadolinium monophosphide at 2080-2465 K dissociates into atomic gadolinium, phosphorus and, P 2 molecules. According to Vant-Hoff and Gibbs-Helmholtz equations standard enthalpy of atomization ΔHsub(at) deg (298)=1027.3 kJ/mol and of formation ΔHsub(f) deg (298)=313.8 kJ/mol of gadolinium monophosphide are determined

DESIGN AND CONSTRUCTION OF A REFLUX COLUMN DISTILLATION UNIT FOR BIO-ETHANOL PRODUCTION FROM SUGARCANE SUBSTRATE

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J. O. Olaoye

2011-06-01

Full Text Available A bio-ethanol distilling tank was designed and constructed to distil ethanol from sugarcane substrate. The machine has a capacity to process 200 litres of substrate at full load of the boiler. The distiller has mlntemalReflux Still Condenser (IRSC that controls the internal re-distillation process and the separation of the final output. The column diameter was 40 mm. An anaerobic fermentation of substrate was adopted before distillation could be carried out. The fermented substrate was adjusted to an optimum pH level value of 4-5 by addition of 0.1 M HjSQ, and the optimum temperature was within the temperature range of 29-38°C. A charcoal pot was used as heat source. The results of the machine evaluation showed that optimum yield occurred at 0.0325 ratio of substrate to ethanol yield. An average distilled product of 2.1 litres was obtained at highest ratio of substrate to ethanol yield of 0.033 when the distillation time was 45 minutes. The total distilled products after 1XA hours of distillation was estimated at 4.25 litres. It was observed that the fermentation and distillation processes were done in situ, and could definitely affect clear separation of the fermentable portion of the fermented sugar solution.

Some remarks on the carrier distillation method

International Nuclear Information System (INIS)

Avni, R.; Chaput, M.

1961-01-01

The method described by SCRIBNER and MULLIN makes possible the spectrographic analysis of the refractory oxides of uranium and plutonium. It uses a distillation of the elements which is more or less selective. The influence of the carrier is the subject of as many hypotheses as there are parameters involved in the process. The measurements of the arc temperature carried out on the leading edges of the vibration bands and of certain copper lines have made it possible to show the influence of the nature of the carrier and to establish a relationship between the values of the excitation potentials of the atoms and the temperatures produced. Further, this result makes it possible to explain certain contradictions between the principle of a fractional distillation in the arc which is incompatible with the refractory properties of certain elements and their spectrographic sensitivity. (author) [fr

Next generation non-vacuum, maskless, low temperature nanoparticle ink laser digital direct metal patterning for a large area flexible electronics.

Science.gov (United States)

Yeo, Junyeob; Hong, Sukjoon; Lee, Daehoo; Hotz, Nico; Lee, Ming-Tsang; Grigoropoulos, Costas P; Ko, Seung Hwan

2012-01-01

Flexible electronics opened a new class of future electronics. The foldable, light and durable nature of flexible electronics allows vast flexibility in applications such as display, energy devices and mobile electronics. Even though conventional electronics fabrication methods are well developed for rigid substrates, direct application or slight modification of conventional processes for flexible electronics fabrication cannot work. The future flexible electronics fabrication requires totally new low-temperature process development optimized for flexible substrate and it should be based on new material too. Here we present a simple approach to developing a flexible electronics fabrication without using conventional vacuum deposition and photolithography. We found that direct metal patterning based on laser-induced local melting of metal nanoparticle ink is a promising low-temperature alternative to vacuum deposition- and photolithography-based conventional metal patterning processes. The "digital" nature of the proposed direct metal patterning process removes the need for expensive photomask and allows easy design modification and short turnaround time. This new process can be extremely useful for current small-volume, large-variety manufacturing paradigms. Besides, simple, scalable, fast and low-temperature processes can lead to cost-effective fabrication methods on a large-area polymer substrate. The developed process was successfully applied to demonstrate high-quality Ag patterning (2.1 µΩ·cm) and high-performance flexible organic field effect transistor arrays.

Next generation non-vacuum, maskless, low temperature nanoparticle ink laser digital direct metal patterning for a large area flexible electronics.