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Sample records for high-temperature high-pressure metamorphic

  1. High pressure and high temperature behaviour of ZnO

    Energy Technology Data Exchange (ETDEWEB)

    Thakar, Nilesh A. [K. K. Shah Jarodwala Maninagar Science College, Rambaug, Maninagar, Ahmedabad-380008 (India); Bhatt, Apoorva D. [Department of Physics, Gujarat University, Ahmedabad-380009 (India); Pandya, Tushar C., E-mail: pandyatc@gmail.com [St. Xavier' s College, Navrangpura, Ahmedabad-380009 (India)

    2014-04-24

    The thermodynamic properties with the wurtzite (B4) and rocksalt (B1) phases of ZnO under high pressures and high temperatures have been investigated using Tait's Equation of state (EOS). The effects of pressures and temperatures on thermodynamic properties such as bulk modulus, thermal expansivity and thermal pressure are explored for both two structures. It is found that ZnO material gradually softens with increase of temperature while it hardens with the increment of the pressure. Our predicted results of thermodynamics properties for both the phases of ZnO are in overall agreement with the available data in the literature.

  2. High-pressure-high-temperature treatment of natural diamonds

    CERN Document Server

    Royen, J V

    2002-01-01

    The results are reported of high-pressure-high-temperature (HPHT) treatment experiments on natural diamonds of different origins and with different impurity contents. The diamonds are annealed in a temperature range up to 2000 sup o C at stabilizing pressures up to 7 GPa. The evolution is studied of different defects in the diamond crystal lattice. The influence of substitutional nitrogen atoms, plastic deformation and the combination of these is discussed. Diamonds are characterized at room and liquid nitrogen temperature using UV-visible spectrophotometry, Fourier transform infrared spectrophotometry and photoluminescence spectrometry. The economic implications of diamond HPHT treatments are discussed.

  3. HIGH TEMPERATURE HIGH PRESSURE THERMODYNAMIC MEASUREMENTS FOR COAL MODEL COMPOUNDS

    Energy Technology Data Exchange (ETDEWEB)

    Vinayak N. Kabadi

    2000-05-01

    The Vapor Liquid Equilibrium measurement setup of this work was first established several years ago. It is a flow type high temperature high pressure apparatus which was designed to operate below 500 C temperature and 2000 psia pressure. Compared with the static method, this method has three major advantages: the first is that large quantity of sample can be obtained from the system without disturbing the equilibrium state which was established before; the second is that the residence time of the sample in the equilibrium cell is greatly reduced, thus decomposition or contamination of the sample can be effectively prevented; the third is that the flow system allows the sample to degas as it heats up since any non condensable gas will exit in the vapor stream, accumulate in the vapor condenser, and not be recirculated. The first few runs were made with Quinoline-Tetralin system, the results were fairly in agreement with the literature data . The former graduate student Amad used the same apparatus acquired the Benzene-Ethylbenzene system VLE data. This work used basically the same setup (several modifications had been made) to get the VLE data of Ethylbenzene-Quinoline system.

  4. Pulse Radiolysis at High Temperatures and High Pressures

    DEFF Research Database (Denmark)

    Christensen, H.; Sehested, Knud

    1981-01-01

    A set-up enabling pulse radiolysis measurements at high temperatures (up to 320°C) and high pressures (up to 140 bar) has been constructed in collaboration between Risö National Laboratory and Studsvik Energiteknik. The cell has been used for experiments with aqueous solutions with the purpose.......2 kcal.mol−1) and OH+OH (tentatively 8 kJ·mol−1, 1.9 kcal·mol−1) have been determined. The absorption spectrum of the OH radical has been determined up to temperatures of 200°C. The absorption maximum is found at 230 nm at all temperatures. The reaction between Fe2+ and OH radicals has been studied up...... to a temperature of 220°C. An activation energy of 9 kJ·mol−1 (2.2 kcal·mol−1) has been determined and the spectrum of the transient formed in the reaction has been determined at different temperatures....

  5. Research at Very High Pressures and High Temperatures

    Science.gov (United States)

    Bundy, Francis P.

    1977-01-01

    Reviews research and apparatus utilized in the study of the states and characteristics of materials at very high temperatures and pressures. Includes three examples of the research being conducted. (SL)

  6. HIGH TEMPERATURE HIGH PRESSURE THERMODYNAMIC MEASUREMENTS FOR COAL MODEL COMPOUNDS

    Energy Technology Data Exchange (ETDEWEB)

    Vinayak N. Kabadi

    1999-02-20

    It is well known that the fluid phase equilibria can be represented by a number of {gamma}-models , but unfortunately most of them do not function well under high temperature. In this calculation, we mainly investigate the performance of UNIQUAC and NRTL models under high temperature, using temperature dependent parameters rather than using the original formulas. the other feature of this calculation is that we try to relate the excess Gibbs energy G{sup E}and enthalpy of mixing H{sup E}simultaneously. In other words, we will use the high temperature and pressure G{sup E} and H{sup E}data to regress the temperature dependant parameters to find out which model and what kind of temperature dependant parameters should be used.

  7. High pressure study of high-temperature superconductors

    Energy Technology Data Exchange (ETDEWEB)

    Souliou, Sofia-Michaela

    2014-09-29

    The current thesis studies experimentally the effect of high external pressure on high-T{sub c} superconductors. The structure and lattice dynamics of several members of the high-T{sub c} cuprate and Fe-based superconductors families were investigated by means of Raman spectroscopy and X-ray diffraction under well-controlled, hydrostatic high pressure and low temperature conditions. The lattice dynamics of the high-T{sub c} superconductor YBa{sub 2}Cu{sub 3}O{sub 6+x} have been investigated systematically by Raman spectroscopy as a function of doping (x = 0.95, 0.75, 0.60, 0.55, and 0.45) and external pressure. Under ambient pressure conditions, in addition to the Raman modes expected from group theory, we observe new Raman active phonons upon cooling the underdoped samples, at temperatures well above the superconducting transition temperature. The doping dependence and the onset temperatures of the new Raman features suggest that they are associated with the incommensurate charge density wave (CDW) state recently discovered in underdoped cuprates using synchrotron X-ray scattering techniques. Under high pressure conditions (from 2 to 12 GPa), our Raman measurements on highly ordered underdoped YBa{sub 2}Cu{sub 3}O{sub 6.55} samples do not show any of the new Raman phonons seen at ambient pressure. High pressure and low temperature Raman measurements have been performed on the underdoped superconductor YBa{sub 2}Cu{sub 4}O{sub 8}. A clear renormalization of some of the Raman phonons is seen below T{sub c} as a result of the changes in the phonon self-energy upon the opening of the superconducting gap, with the most prominent one being that of the B{sub 1g}-like buckling phonon mode. The amplitude of this renormalization strongly increases with pressure, resembling the effect of hole doping in YBa{sub 2}Cu{sub 3}O{sub 6+x}. At ∝ 10 GPa, the system undergoes a reversible pressure-induced structural phase transition to a non-centrosymmmetric structure (space group

  8. Thermal evolution of high-pressure metamorphic rocks in the Alps

    NARCIS (Netherlands)

    Brouwer, F.M.

    2000-01-01

    There are two major and currently unresolved issues in Alpine geology concerning the metamorphic evolution of the rocks in the internal zones of the Alps. First, rocks showing evidence for geologically young, high-pressure to very high-pressure metamorphism are now exposed at the Earth's surface,

  9. HIGH TEMPERATURE HIGH PRESSURE THERMODYNAMIC MEASUREMENTS FOR COAL MODEL COMPOUNDS

    Energy Technology Data Exchange (ETDEWEB)

    Vinayak N. Kabadi

    2000-05-01

    The flow VLE apparatus designed and built for a previous project was upgraded and recalibrated for data measurements for this project. The modifications include better and more accurate sampling technique, addition of a digital recorder to monitor temperature and pressure inside the VLE cell, and a new technique for remote sensing of the liquid level in the cell. VLE data measurements for three binary systems, tetralin-quinoline, benzene--ethylbenzene and ethylbenzene--quinoline, have been completed. The temperature ranges of data measurements were 325 C to 370 C for the first system, 180 C to 300 C for the second system, and 225 C to 380 C for the third system. The smoothed data were found to be fairly well behaved when subjected to thermodynamic consistency tests. SETARAM C-80 calorimeter was used for incremental enthalpy and heat capacity measurements for benzene--ethylbenzene binary liquid mixtures. Data were measured from 30 C to 285 C for liquid mixtures covering the entire composition range. An apparatus has been designed for simultaneous measurement of excess volume and incremental enthalpy of liquid mixtures at temperatures from 30 C to 300 C. The apparatus has been tested and is ready for data measurements. A flow apparatus for measurement of heat of mixing of liquid mixtures at high temperatures has also been designed, and is currently being tested and calibrated.

  10. Temperature uniformity mapping in a high pressure high temperature reactor using a temperature sensitive indicator

    NARCIS (Netherlands)

    Grauwet, T.; Plancken, van der I.; Vervoort, L.; Matser, A.M.; Hendrickx, M.; Loey, van A.

    2011-01-01

    Recently, the first prototype ovomucoid-based pressure–temperature–time indicator (pTTI) for high pressure high temperature (HPHT) processing was described. However, for temperature uniformity mapping of high pressure (HP) vessels under HPHT sterilization conditions, this prototype needs to be

  11. Comparison of Diesel Spray Combustion in Different High-temperature, High-pressure Facilities

    DEFF Research Database (Denmark)

    Pickett, Lyle M.; Genzale, Caroline L.; Bruneaux, Gilles

    2010-01-01

    Diesel spray experimentation at controlled high-temperature and high-pressure conditions is intended to provide a more fundamental understanding of diesel combustion than can be achieved in engine experiments. This level of understanding is needed to develop the high-fidelity multi-scale CFD models...... boundary conditions at these unique facilities. Performing experiments at the same high-temperature, high-pressure operating conditions is an objective of the Engine Combustion Network (http://www.ca.sandia.gov/ECN/), which seeks to leverage the research capabilities and advanced diagnostics of all...... that will be used to optimize future engine designs. Several spray chamber facilities capable of high-temperature, high-pressure conditions typical of engine combustion have been developed, but because of the uniqueness of each facility, there are uncertainties about their operation. For this paper, we describe...

  12. Research of a Novel Ultra-High Pressure Sensor with High-Temperature Resistance

    Directory of Open Access Journals (Sweden)

    Guo-Dong Zhang

    2017-12-01

    Full Text Available Ultra-high pressure measurement has significant applications in various fields such as high pressure synthesis of new materials and ultra-high pressure vessel monitoring. This paper proposes a novel ultra-high pressure sensor combining a truncated-cone structure and a silicon-on-insulator (SOI piezoresistive element for measuring the pressure up to 1.6 GPa. The truncated-cone structure attenuates the measured pressure to a level that can be detected by the SOI piezoresistive element. Four piezoresistors of the SOI piezoresistive element are placed along specific crystal orientation and configured as a Wheatstone bridge to obtain voltage signals. The sensor has an advantage of high-temperature resistance, in that the structure of the piezoresistive element can avoid the leakage current at high temperature and the truncated-cone structure separates the piezoresistive element from the heat environment. Furthermore, the upper surface diameter of the truncated-cone structure is designed to be 2 mm for the application of small scale. The results of static calibration show that the sensor exhibits a good performance in hysteresis and repeatability. The temperature experiment indicates that the sensor can work steadily at high temperature. This study would provide a better insight to the research of ultra-high pressure sensors with larger range and smaller size.

  13. Phase transitions in Cd3P2 at high pressures and high temperatures

    DEFF Research Database (Denmark)

    Yel'kin, F.S.; Sidorov, V.A.; Waskowska, A.

    2008-01-01

    The high-pressure, high-temperature structural behaviour of Cd3P2 has been studied using electrical resistance measurements, differential thermal analysis, thermo baric analysis and X-ray diffraction. At room temperature, a phase transformation is observed at 4.0 GPa in compression....... The experimental zero-pressure bulk modulus of the low-pressure phase is 64.7(7) GPa, which agrees quite well with the calculated value of 66.3 GPa using the tight-binding linear muffin-tin orbital method within the local density approximation. Tentatively, the high-pressure phase has an orthorhombic crystal...

  14. Inelastic X-ray scattering experiments at extreme conditions: high temperatures and high pressures

    Directory of Open Access Journals (Sweden)

    S.Hosokawa

    2008-03-01

    Full Text Available In this article, we review the present status of experimental techniques under extreme conditions of high temperature and high pressure used for inelastic X-ray scattering (IXS experiments of liquid metals, semiconductors, molten salts, molecular liquids, and supercritical water and methanol. For high temperature experiments, some types of single-crystal sapphire cells were designed depending on the temperature of interest and the sample thickness for the X-ray transmission. Single-crystal diamond X-ray windows attached to the externally heated high-pressure vessel were used for the IXS experiment of supercritical water and methanol. Some typical experimental results are also given, and the perspective of IXS technique under extreme conditions is discussed.

  15. High Temperature, High Pressure Devices for Zonal Isolation in Geothermal Wells

    Energy Technology Data Exchange (ETDEWEB)

    Fabian, Paul [Composite Technology Development, Inc, Lafayette, CO (United States)

    2012-03-31

    The U.S. Department of Energy is leading the development of alternative energy sources that will ensure the long-term energy independence of our nation. One key renewable resource being advanced is geothermal energy which offers an environmentally benign, reliable source of energy for the nation. To utilize this resource, water will be introduced into wells 3 to 10 km deep to create a geothermal reservoir. This approach is known as an Enhanced Geothermal System (EGS). The high temperatures and pressures at these depths have become a limiting factor in the development of this energy source. For example, reliable zonal isolation for high-temperature applications at high differential pressures is needed to conduct mini-fracs and other stress state diagnostics. Zonal isolation is essential for many EGS reservoir development activities. To date, the capability has not been sufficiently demonstrated to isolate sections of the wellbore to: 1) enable stimulation; and 2) seal off unwanted flow regions in unknown EGS completion schemes and high-temperature (>200°C) environments. In addition, packers and other zonal isolation tools are required to eliminate fluid loss, to help identify and mitigate short circuiting of flow from injectors to producers, and to target individual fractures or fracture networks for testing and validating reservoir models. General-purpose open-hole packers do not exist for geothermal environments, with the primary barrier being the poor stability of elastomeric seals at high temperature above 175°C. Experimental packer systems have been developed for geothermal environments but they currently only operate at low pressure, they are not retrievable, and they are not commercially available. The development of the high-temperature, high-pressure (HTHP) zonal isolation device would provide the geothermal community with the capability to conduct mini-fracs, eliminate fluid loss, to help identify and mitigate short circuiting of flow from injectors to

  16. Standard guide for corrosion tests in high temperature or high pressure environment, or both

    CERN Document Server

    American Society for Testing and Materials. Philadelphia

    2010-01-01

    1.1 This guide covers procedures, specimens, and equipment for conducting laboratory corrosion tests on metallic materials under conditions of high pressure (HP) or the combination of high temperature and high pressure (HTHP). See for definitions of high pressure and temperature. 1.2 Tests conducted under HP or HTHP by their nature have special requirements. This guide establishes the basic considerations that are necessary when these conditions must be incorporated into laboratory corrosion tests. 1.3 The procedures and methods in this guide are applicable for conducting mass loss corrosion, localized corrosion, and electrochemical tests as well as for use in environmentally induced cracking tests that need to be conducted under HP or HTHP conditions. 1.4 The primary purpose for this guide is to promote consistency of corrosion test results. Furthermore, this guide will aid in the comparison of corrosion data between laboratories or testing organizations that utilize different equipment. 1.5 The values s...

  17. Laser-Machined Microcavities for Simultaneous Measurement of High-Temperature and High-Pressure

    Directory of Open Access Journals (Sweden)

    Zengling Ran

    2014-08-01

    Full Text Available Laser-machined microcavities for simultaneous measurement of high-temperature and high-pressure are demonstrated. These two cascaded microcavities are an air cavity and a composite cavity including a section of fiber and an air cavity. They are both placed into a pressure chamber inside a furnace to perform simultaneous pressure and high-temperature tests. The thermal and pressure coefficients of the short air cavity are ~0.0779 nm/°C and ~1.14 nm/MPa, respectively. The thermal and pressure coefficients of the composite cavity are ~32.3 nm/°C and ~24.4 nm/MPa, respectively. The sensor could be used to separate temperature and pressure due to their different thermal and pressure coefficients. The excellent feature of such a sensor head is that it can withstand high temperatures of up to 400 °C and achieve precise measurement of high-pressure under high temperature conditions.

  18. Petrological and geochemical records of short-lived, high temperature metamorphism during exhumation of the Sulu UHP metamorphic terrane

    Science.gov (United States)

    Zong, K.; Liu, Y.; Zhang, X.; Ye, Y.; Gao, C.

    2010-12-01

    The Dabie-Sulu terrane of east-central China is the largest and most well known ultrahigh-pressure (UHP) metamorphic terrane in the world, which has become one of the most important places to study continental subduction-related UHP metamorphism. In the past two decades, numerous petrological, geochemical, petrophysical and tectonophysical studies were carried out in the Dabie-Sulu UHP metamorphic terrane. However, almost all of these studies have focused on UHP metamorphic processes, while only a few studies have focused on the thermal evolution. Here we present a detailed petrological and geochemical study on the southern Sulu UHP eclogites in order to constrain the “hot” exhumation of the Sulu UHP metamorphic terrane. Eclogite-hosted garnet-spinel-corundum-quartz-bearing titanohematite veins near the main hole of the Chinese Continental Scientific Drilling Project (CCSD-MH) are described for the first time in the Sulu UHP metamorphic terrane. A vein composed of titanohematite + ilmenite + hematite + spinel + garnet + corundum + quartz + K-feldspar + albite was studied in detail. The unusual mineral assemblage of garnet + spinel + corundum + quartz implies that this vein could have experienced high temperatures (>900 oC). Although within garnets showed well-defined Mg and Mn diffusion zoning in the rim as a result of the high temperature event, slight Mg and Mn growth zoning was preserved in the core. Thus, we suggest that the Sulu UHP terrane could have experienced a short-lived, high-temperature stage during exhumation. This is consistent with trace element zoning recorded by garnet, omphacite and apatite and much higher temperatures recorded by rutiles and zircons with ages of ~200 Ma in the CCSD-MH eclogites. We speculate that slab breakoff may have caused asthenospheric upwelling, which could have provided a heat pulse for the short-lived, high-temperature metamorphism in the Sulu UHP terrane. Such high temperature stage could have contributed to the

  19. High-pressure high-temperature phase diagram of organic crystal paracetamol

    Science.gov (United States)

    Smith, Spencer J.; Montgomery, Jeffrey M.; Vohra, Yogesh K.

    2016-01-01

    High-pressure high-temperature (HPHT) Raman spectroscopy studies have been performed on the organic crystal paracetamol in a diamond anvil cell utilizing boron-doped heating diamond anvil. Isobaric measurements were conducted at pressures up to 8.5 GPa and temperature up to 520 K in five different experiments. Solid state phase transitions from monoclinic Form I  →  orthorhombic Form II were observed at various pressures and temperatures as well as transitions from Form II  →  unknown Form IV. The melting temperature for paracetamol was observed to increase with increasing pressures to 8.5 GPa. This new data is combined with previous ambient temperature high-pressure Raman and x-ray diffraction data to create the first HPHT phase diagram of paracetamol.

  20. Thermoelectric properties of PbTe prepared at high pressure and high temperature

    CERN Document Server

    Zhu, P W; Jia, X; Ma, H A; Ren, G Z; Guo, W L; Zhang, W; Zou Guang Tian

    2002-01-01

    Lead telluride (PbTe) with rock-salt structure was successfully obtained by a high-pressure and high-temperature (HPHT) method. The orientation of the PbTe samples varies with pressure increase. The results - a decrease in the Seebeck coefficient, resistivity and thermal conductivity of PbTe with pressure but an increase in the thermoelectric power figure sigma S sup 2 - indicate that the figure of merit Z of PbTe samples can be improved several times over by using HPHT.

  1. The analysis of energy efficiency in water electrolysis under high temperature and high pressure

    Science.gov (United States)

    Hourng, L. W.; Tsai, T. T.; Lin, M. Y.

    2017-11-01

    This paper aims to analyze the energy efficiency of water electrolysis under high pressure and high temperature conditions. The effects of temperature and pressure on four different kinds of reaction mechanisms, namely, reversible voltage, activation polarization, ohmic polarization, and concentration polarization, are investigated in details. Results show that the ohmic and concentration over-potentials are increased as temperature is increased, however, the reversible and activation over-potentials are decreased as temperature is increased. Therefore, the net efficiency is enhanced as temperature is increased. The efficiency of water electrolysis at 350°C/100 bars is increased about 17%, compared with that at 80°C/1bar.

  2. Design Strategies for Optically-Accessible, High-Temperature, High-Pressure Reactor

    Energy Technology Data Exchange (ETDEWEB)

    S. F. Rice; R. R. Steeper; C. A. LaJeunesse; R. G. Hanush; J. D. Aiken

    2000-02-01

    The authors have developed two optical cell designs for high-pressure and high-temperature fluid research: one for flow systems, and the other for larger batch systems. The flow system design uses spring washers to balance the unequal thermal expansions of the reactor and the window materials. A typical design calculation is presented showing the relationship between system pressure, operating temperature, and torque applied to the window-retaining nut. The second design employs a different strategy more appropriate for larger windows. This design uses two seals: one for the window that benefits from system pressure, and a second one that relies on knife-edge, metal-to-metal contact.

  3. Design strategies for optically-accessible, high-temperature, high-pressure reactor

    Energy Technology Data Exchange (ETDEWEB)

    S. F. Rice; R. R. Steeper; C. A. LaJeunesse; R. G. Hanush; J. D. Aiken

    2000-02-01

    The authors have developed two optical cell designs for high-pressure and high-temperature fluid research: one for flow systems, and the other for larger batch systems. The flow system design uses spring washers to balance the unequal thermal expansions of the reactor and the window materials. A typical design calculation is presented showing the relationship between system pressure, operating temperature, and torque applied to the window-retaining nut. The second design employs a different strategy more appropriate for larger windows. This design uses two seals: one for the window that benefits from system pressure, and a second one that relies on knife-edge, metal-to-metal contact.

  4. Different origins of garnet in high pressure to ultrahigh pressure metamorphic rocks

    Science.gov (United States)

    Xia, Qiong-Xia; Zhou, Li-Gang

    2017-09-01

    Garnet in high-pressure (HP) to ultrahigh-pressure (UHP) metamorphic rocks in subduction zone commonly shows considerable zonation in major and trace elements as well as mineral inclusions, which bears information on its growth mechanism via metamorphic or peritectic reactions in coexistence with relic minerals and metamorphic fluids or anatectic melts at subduction-zone conditions. It provides an important target to retrieve physicochemical changes in subduction-zone processes, including those not only in pressure and temperature but also in the durations of metamorphism and anatexis. Garnet from different compositions of HP to UHP metamorphic rocks may show different types of major and trace element zonation, as well as mineral inclusions. Discrimination between the different origins of garnet provides important constraints on pressure and temperature and the evolution history for the HP to UHP metamorphic rocks. Magmatic garnet may occur as relics in granitic gneisses despite metamorphic modification at subduction-zone conditions, with spessartine-increasing or flat major element profiles from inner to outer core and exceptionally higher contents of trace elements than metamorphic mantle and rim. Metamorphic garnet can grow at different metamorphic stages during prograde subduction and retrograde exhumation, with spessartine-decreasing from core to rim if the intracrystalline diffusion is not too fast. The compositional profiles of metamorphic garnet in the abundances of grossular, almandine and pyrope are variable depending on the composition of host rocks and co-existing minerals. Peritectic garnet grows through peritectic reactions during partial melting of HP to UHP rocks, with the composition of major elements to be controlled by anatectic P-T conditions and the compositions of parental rocks and anatectic melts. Trace element profiles in garnet with different origins are also variable depending on the coexisting mineral assemblages, the garnet

  5. Rheological properties of a reclaimed waste tire rubber through high-pressure high-temperature sintering

    Science.gov (United States)

    Ubaidillah, Yunus, N. A.; Aziz, S. A. A.; Wahab, N. A. A.; Mazlan, S. A.

    2017-01-01

    High-Pressure High-Temperature (HPHT) sintering method has successfully revulcanized waste tire rubber (WTR) without any additional virgin rubber. The crumb rubber cleaned from its fabric and metals was reclaimed by applying high pressure (25 MPa) and high temperature (200 °C) for an hour along with common vulcanization agents such as sulfur, zinc oxide, and stearic acid. Dynamic properties of reclaimed WTR were assessed through shear rheology test on MCR302 Rheometer, Anton Paar, Austria. The results indicated that under steady test, the yield stress occurred at 31 kPa at 5% linear viscoelastic limit. The storage modulus ranged from 0.6 to 0.7 MPa under excitation frequency of 0.1 to 100 Hz and 1% strain amplitude. Under ramp strain amplitude, the storage modulus showed Payne Effect phenomenon at 0.8 to 1 % strain amplitude and 1 Hz excitation frequency. In general, the resulted dynamic properties was comparable with non-reclaimed rubber based on a literature survey. The results confirmed that HPHT sintering method was capable of reclaiming 100% WTR without an additional virgin rubber and achieving acceptable dynamic properties.

  6. Defects of diamond single crystal grown under high temperature and high pressure

    Energy Technology Data Exchange (ETDEWEB)

    Su, Qingcai, E-mail: suqc@sdu.edu.cn [Key Laboratory of Liquid Structure and Heredity of Materials (Ministry of Education), Shandong University, Jinan, P. R. China, 250061 (China); School of Materials Science and Engineering, Shandong University, Jinan, P. R. China, 250061 (China); Shandong Engineering Research Center for Superhard Materials, Zoucheng, P. R. China 273500 (China); Zhang, Jianhua [School of Mechanical Engineering, Shandong University, Jinan, P. R. China, 250061 (China); Li, Musen [Key Laboratory of Liquid Structure and Heredity of Materials (Ministry of Education), Shandong University, Jinan, P. R. China, 250061 (China); School of Materials Science and Engineering, Shandong University, Jinan, P. R. China, 250061 (China); Shandong Engineering Research Center for Superhard Materials, Zoucheng, P. R. China 273500 (China)

    2013-11-01

    The diamond single crystal, synthesized with Fe–Ni–C–B system of catalyst under high temperature and high pressure, had been observed by field emission scanning electron microscope and transmission electron microscope. The presence of a cellular structure suggested that the diamond grew from melted catalyst solution and there existed a zone of component supercooling zone in front of the solid–liquid interface. The main impurities in the diamond crystal was (FeNi){sub 23}C{sub 6}. The triangle screw pit revealed on the (111) plane was generated by the screw dislocation meeting the diamond (111) plane at the points of emergence of dislocations. A narrow twin plane was formed between the two (111) plane. - Highlights: • High pressure, high temperature synthesis of diamond single crystal. • Fe–Ni–C–B used as catalyst, graphite as carbon source. • The main impurity in the diamond crystal was (FeNi){sub 23}C{sub 6}. • Surface defects arose from screw dislocations and stacking faults.

  7. Temperature Prediction for High Pressure High Temperature Condensate Gas Flow Through Chokes

    Directory of Open Access Journals (Sweden)

    Changjun Li

    2012-03-01

    Full Text Available This study developed a theoretical model for predicting the downstream temperatures of high pressure high temperature condensate gas flowing through chokes. The model is composed of three parts: the iso-enthalpy choke model derived from continuity equation and energy conservation equation; the liquid-vapor equilibrium model based on the SRK equation of state (EoS; and the enthalpy model based on the Lee-Kesler EoS. Pseudocritical properties of mixtures, which are obtained by mixing rules, are very important in the enthalpy model, so the Lee-Kesler, Plocker-Knapp, Wong-Sandler and Prausnitz-Gunn mixing rules were all researched, and the combination mixing rules with satisfactory accuracy for high pressure high temperature condensate gases were proposed. The temperature prediction model is valid for both the critical and subcritical flows through different kinds of choke valves. The applications show the model is reliable for predicting the downstream temperatures of condensate gases with upstream pressures up to 85.54 MPa and temperatures up to 93.23 °C. The average absolute errors between the measured and calculated temperatures are expected for less than 2 °C by using the model.

  8. High-Pressure High-Temperature Phase Diagram of the Organic Crystal Paracetamol

    Science.gov (United States)

    Smith, Spencer; Montgomery, Jeffrey; Vohra, Yogesh

    High-pressure high-temperature (HPHT) Raman spectroscopy studies have been performed on the organic crystal paracetamol in a diamond anvil cell utilizing boron-doped diamond as heating anvil. The HPHT data obtained from boron-doped diamond heater is cross-checked with data obtained using a standard block heater diamond anvil cell. Isobaric measurements were conducted at pressures up to 8.5 GPa and temperature up to 520 K in a number of different experiments. Solid state phase transitions from monoclinic Form I --> orthorhombic Form II were observed at various pressures and temperatures as well as transitions from Form II --> unknown Form IV. The melting temperature for paracetamol was observed to increase with increasing pressures to 8.5 GPa. Our previous angle dispersive x-ray diffraction studies at the Advanced Photon Source has confirmed the existence of two unknown crystal structures Form IV and Form V of paracetamol at high pressure and ambient temperature. The phase transformation from Form II to Form IV occurs at ~8.5 GPa and from Form IV to Form V occurs at ~11 GPa at ambient temperature. Our new data is combined with the previous ambient temperature high-pressure Raman and X- ray diffraction data to create the first HPHT phase diagram of paracetamol. Doe-NNSA Carnegie DOE Alliance Center (CDAC) under Grant Number DE-NA0002006.

  9. High-Pressure and High-Temperature Sorption of Methane on Black Shales

    Science.gov (United States)

    Gasparik, Matus; Ghanizadeh, Amin; Gensterblum, Yves; Weniger, Phillipp; Krooss, Bernhard

    2013-04-01

    Improved estimations of Gas-In-Place (GIP) for shale gas reservoirs require reliable experimental sorption data for high pressures and high temperatures. In the framework of European Shale Gas Research project (GASH, www.gas-shales.org) a manometric method was used to measure methane sorption isotherms on various shales from Europe and the USA. Established procedures originally developed for CBM research were modified to: (1) improve the accuracy of sorption measurements for materials with low sorption capacity (5-10% of that for coals) and (2) extend the experimental conditions to pressures and temperatures representative of shale gas reservoirs. It is generally assumed that at high temperatures (> 100°) sorption does no longer contribute significantly to the total gas storage capacity of shales. Experimental data on high-temperature / high-pressure sorption are, however, still missing. Part of our work was therefore focused on providing reliable experimental data at pressures up to 25 MPa and temperatures up to 150°C. Moisture content has a strong effect on gas sorption capacity due to competition of methane and water molecules for sorption sites and/or pore restrictions in the presence of water. However, sorption measurements on moist samples at different temperatures pose some experimental difficulties. A simple and effective method was developed allowing for measurements of multiple isotherms at constant moisture content in the system. This procedure ensures that the moisture state of the sample remains unchanged and is not affected by evacuation cycles as in conventional measurements. Uncertainties in assessing the temperature dependence of sorption isotherms on moist samples can thus be significantly reduced. The following aspects analyzed in this study will be discussed: • Variation of methane sorption capacity with Total Organic Carbon (TOC) content, mineralogy and thermal maturity • Temperature dependence of methane sorption capacity over a wide

  10. High-Pressure Minerals in RC106: Formation at Modest Shock Pressures and very High Temperatures

    Science.gov (United States)

    Sharp, T. G.; Trickey, R.; de Carli, P. S.; Xie, Z.

    2009-12-01

    The controversy concerning the pressures required to produce shock effects in meteorites began with the interpretation that shock veins in chondrites crystallize at pressures about 25 GPa (Chen et al. 1996) rather than the 50 -90 GPa inferred from “calibration” of shock effects from shock-recovery experiments (Stöffler et al. 1991). The 25 GPa estimate was based on phase equilibrium data for crystallization. The transformation of mafic silicate minerals into their high-pressure polymorphs within shock veins has been used as evidence for local excursions to extreme pressure and temperature. Here we present new data from the RC106 L6 S6 chondrite, that illustrates the importance of high temperatures and long shock durations. The shock vein consists of entrained fragments of chondrite in a matirix of quenched silicate and metal-sulfide melts. The silicate melt crystallized majorite-pyrope garnet and ferropericlase throughout the vein, with course (10-15 µm) granular garnets in the vein center and sub-µm dendritic garnets at the vein margins. All of the entrained olivine in the melt vein was transformed into ringwoodite. A distinct nanocrystalline boundary zone, composed of predominantly ringwoodite, occurs along much of the melt vein margin as a continuous blue layer. These zones contain quenched droplets of metal-sulfide melt that suggest a liquid origin. Some of the olivine in contact with the boundary zones is partially transformed to ringwoodite. The mineralogy and texture of the vein matrix indicate that the silicate liquid was quenched at approximately 23 GPa by conduction of heat into the surrounding chondrite host. We infer that boundary zones represent vein margin minerals that were melted by the influx of heat from the super heated melt vein. One explanation for the discrepancy in pressure estimates between shock recovery experiments and melt-vein crystallization has been that crystallization occurs during release from a much higher shock pressure

  11. Thermoset recycling via high-pressure high-temperature sintering: Revisiting the effect of interchange chemistry

    Science.gov (United States)

    Morin, Jeremy Edward

    In 1844 Charles Goodyear obtained U.S. Patent #3,633 for his "Gum Elastic Composition". In a published circular, which describes his patent for the sulfur vulcanization of gum elastic composition, he stated: "No degree of heat, without blaze, can melt it (rubber)... It resists the most powerful chemical reagents. Aquafortis (nitric acid), sulphuric acid, essential and common oils, turpentine and other solvents... ..." Goodyear's sulfur vulcanization of rubber fueled much of the industrial revolution and made transportation possible, as it exists today. In doing so, Goodyear created one of the most difficult materials to recycle. Rubber will not melt, dissolve, or lend itself to the usual methods of chemical decomposition. Ironically, Goodyear recognized this problem and in 1853 he patented the process of adding ground rubber to virgin material, now currently known as regrind blending. Today, scrap tires represent one of the most serious sources of pollution in the world. Studies estimate that there are roughly 2 billion scrap tires in U.S. landfills and more are being added at a rate of over 273 million tires per year. Current methods of recycling waste tires are crude, ineffective, and use rubber powder as a low cost filler instead of a new rubber. The groundwork for a very simple and effective method of producing high-quality rubber goods using 100% scrap rubber was discovered in 1944 by A. V. Tobolsky et al. This application, however, was not recognized until recently in our laboratory. The process as studied to date represents a method of creating quality, high-value added rubber goods with nothing other than heat and pressure. High pressure is required to obtain a void-free compaction of the rubber particles by forcing all of the free surfaces into intimate contact. High temperature then activates the chemical rearrangement, scission, and reformation of the chemical bonds thus providing new bridges between the once fractured interfaces. This occurs both within

  12. Design and analysis of a high pressure and high temperature sulfuric acid experimental system

    Energy Technology Data Exchange (ETDEWEB)

    Hong, Sung-Deok, E-mail: sdhong1@kaeri.re.kr [Korea Atomic Energy Research Institute, Yuseong-Gu, Daejeon 305-600 (Korea, Republic of); Kim, Chan-Soo; Kim, Yong-Wan [Korea Atomic Energy Research Institute, Yuseong-Gu, Daejeon 305-600 (Korea, Republic of); Seo, Dong-Un; Park, Goon-Cherl [Seoul National University, San56-1, Sillim-Dong, Kwanak-Gu, Seoul 151-742 (Korea, Republic of)

    2012-10-15

    We discuss the design and analysis of a small scale sulfuric acid experimental system that can simulate a part of the hydrogen production module. Because nuclear hydrogen coupled components such as a SO{sub 3} decomposer and a sulfuric acid evaporator should be tested under high pressure and high temperature operating conditions, we developed the sulfuric acid loop to satisfy design specifications of 900 Degree-Sign C in temperature and 1.0 MPa in pressure. The components for the sulfuric acid loop were specially designed using a combination of materials with good corrosion resistance; a ceramic and Hastelloy-C276. The design feature of the loop was tested for performance in a 10 h sulfuric acid experiment and optimized using Aspen+ code simulation.

  13. High-pressure metamorphism in the Chinshuichi area, Yuli belt, eastern Taiwan

    Science.gov (United States)

    Keyser, William; Tsai, Chin-Ho; Iizuka, Yoshiyuki; Oberhänsli, Roland; Ernst, W. G.

    2016-12-01

    Tectonic blocks and slabs of mafic-ultramafic rocks are distributed discontinuously in the Yuli metamorphic belt of Taiwan. The blocks include rare omphacite metagabbros and garnet-epidote blueschists in the Wanjung and Juisui (Tamayen) areas, respectively. Such high-pressure (HP) mineral assemblages have been attributed to a mid-Miocene subduction event. However, the surrounding psammitic, pelitic and chloritic schists are the dominant greenschist-facies lithologies of the Yuli belt. In the Chinshuichi area, tectonic blocks are enclosed in garnet-bearing metapelites, suggesting elevated pressures. In this area, we recently discovered meta-plagiogranite containing the assemblage glaucophane + omphacite (XJd up to 0.39) + rutile + quartz, indicating P-T conditions near 13 kbar/550 °C. New equilibrium phase modeling of a garnet-paragonite mica schist and compositional isopleths for peak assemblage minerals garnet and phengite (Si = 3.33-3.37 pfu) indicate metamorphic conditions of 15.5-17 kbar/530-550 °C. These P-T estimates are higher than previously reported in the Yuli belt and suggest that both tectonic blocks and host metapelites underwent HP metamorphism. The juxtaposition of tectonic blocks and metapelites apparently occurred during the formation of a subduction-accretionary complex, followed by exhumation facilitated by a collisional event. These new findings imply that HP metamorphism was not limited to tectonic blocks, and instead played a significant role attending orogenesis in eastern Taiwan.

  14. Matrix free fiber reinforced polymeric composites via high-temperature high-pressure sintering

    Science.gov (United States)

    Xu, Tao

    2004-11-01

    A novel manufacturing process called high-temperature high-pressure sintering was studied and explored. Solid fiber reinforced composites are produced by consolidating and compacting layers of polymeric fabrics near their melting temperature under high pressure. There is no need to use an additional matrix as a bonding material. Partial melting and recrystallization of the fibers effectively fuse the material together. The product is called a "matrix free" fiber reinforced composite and essentially a one-polymer composite in which the fiber and the matrix have the same chemical composition. Since the matrix is eliminated in the process, it is possible to achieve a high fiber volume fraction and light weight composite. Interfacial adhesion between fibers and matrix is very good due to the molecular continuity throughout the system and the material is thermally shapeable. Plain woven Spectra RTM cloth made of SpectraRTM fiber was used to comprehensively study the process. The intrinsic properties of the material demonstrate that matrix free SpectraRTM fiber reinforced composites have the potential to make ballistic shields such as body armor and helmets. The properties and structure of the original fiber and the cloth were carefully examined. Optimization of the processing conditions started with the probing of sintering temperatures by Differential Scanning Calorimetry. Coupled with the information from structural, morphological and mechanical investigations on the samples sintered at different processing conditions, the optimal processing windows were determined to ensure that the outstanding original properties of the fibers translate into high ballistic performance of the composites. Matrix free SpectraRTM composites exhibit excellent ballistic resistance in the V50 tests conducted by the US Army. In the research, process-structure-property relationship is established and correlations between various properties and structures are understood. Thorough knowledge is

  15. Eclogite-high-pressure granulite metamorphism records early collision in West Gondwana: new data from the Southern Brasilia Belt, Brazil

    DEFF Research Database (Denmark)

    Reno II, Barry Len; Brown, Michael; Kobayashi, Katsura

    2009-01-01

    constrain the age of. (1) retrograded eclogite from a block along the tectonic contact beneath the uppermost nappe in a stack of passive margin-derived nappes; (2) high-pressure granulite-facies metamorphism in the uppermost passive margin-derived nappe; (3) high-pressure granulite-facies metamorphism...... in the overlying arc-derived nappe. Rare zircons from a retrograded eclogite yield a Pb-206/U-238 age of 678 +/- 29 Ma. which we interpret as most likely to (late close-to-peak-P metamorphism and to provide a minimum age for detachment of the overlying passive margin-derived nappe from the subducting plate. Zircon...

  16. Carvacrol suppresses high pressure high temperature inactivation of Bacillus cereus spores.

    Science.gov (United States)

    Luu-Thi, Hue; Corthouts, Jorinde; Passaris, Ioannis; Grauwet, Tara; Aertsen, Abram; Hendrickx, Marc; Michiels, Chris W

    2015-03-16

    The inactivation of bacterial spores generally proceeds faster and at lower temperatures when heat treatments are conducted under high pressure, and high pressure high temperature (HPHT) processing is, therefore, receiving an increased interest from food processors. However, the mechanisms of spore inactivation by HPHT treatment are poorly understood, particularly at moderately elevated temperature. In the current work, we studied inactivation of the spores of Bacillus cereus F4430/73 by HPHT treatment for 5 min at 600MPa in the temperature range of 50-100°C, using temperature increments of 5°C. Additionally, we investigated the effect of the natural antimicrobial carvacrol on spore germination and inactivation under these conditions. Spore inactivation by HPHT was less than about 1 log unit at 50 to 70°C, but gradually increased at higher temperatures up to about 5 log units at 100°C. DPA release and loss of spore refractility in the spore population were higher at moderate (≤65°C) than at high (≥70°C) treatment temperatures, and we propose that moderate conditions induced the normal physiological pathway of spore germination resulting in fully hydrated spores, while at higher temperatures this pathway was suppressed and replaced by another mechanism of pressure-induced dipicolinic acid (DPA) release that results only in partial spore rehydration, probably because spore cortex hydrolysis is inhibited. Carvacrol strongly suppressed DPA release and spore rehydration during HPHT treatment at ≤65°C and also partly inhibited DPA release at ≥65°C. Concomitantly, HPHT spore inactivation was reduced by carvacrol at 65-90°C but unaffected at 95-100°C. Copyright © 2014 Elsevier B.V. All rights reserved.

  17. Development of Aerosol Measurement, Sampling and Generation Experimental Facilities under High Temperature and High Pressure

    Energy Technology Data Exchange (ETDEWEB)

    Lee, Jong Chan; Jung, Woo Young; Lee, Hyun Chul; Lee, Doo Yong [FNC TECH., Yongin (Korea, Republic of)

    2016-05-15

    The pressure is key factor determining Knudsen number and it affects aerosol dynamics. Hence, it is important to design experimental facilities to simulate the aerosols transport phenomena and removal mechanisms in the high temperature and high pressure (HT/HP). In case of Nuclear Power Plant, during the Light Water Reactor (LWR) severe accident, core degradation results in the release of both vapors and aerosol particles which differ in composition depending on their source terms. Vapor and aerosols generated under severe accident enter the containment atmosphere and are distributed in the containment by atmospheric flow. Temperature and pressure in the containment increase until containment spray system, fan cooler system or FCVS initiates to extract heat and avoid pressurization. The main purpose of the experimental facility is to develop not only multi-purpose test loops applying for aerosol industry but also to evaluation performance of engineered safety system including containment filtered venting system. The main experiment will be carried out in this loop and provide representative behavior of the aerosols under HT/HP conditions. The aim of the research is to be able to 1) develop the aerosol generation, mixing, sampling and measurement system and conduct tests based on various aerosol concentration, thermal-hydraulic conditions including high temperature and pressure and type of carrier gases (air, nitrogen and steam), applicable to the thermal power plant, environmental industry, automobile exhaust gas, chemical plant, HVAC system including nuclear power plant, and 2) investigate aerosol behaviors and removal mechanisms under these conditions. The tests with the main carrier gas of air will be performed on PHASEⅠ, steam will be conducted on PHASEⅡ.

  18. High-pressure high-temperature rheological studies of colloidal suspensions with carbon nanotube

    Science.gov (United States)

    Baby, Anoop; Sadr, Reza; Yarc, Rommel; Amani, Mahmood

    2017-11-01

    Selection of the drilling fluid, drilling mud, is vital in minimizing the cost and time required for the drilling in oil fields. Drilling mud aids in cooling, lubricating drilling bit, removing the debries from the drill bore and maintaining the wellbore stability. Owing to the enhanced thermo-physical properties and stable nature, suspensions of nanoparticles have been suggested for drilling fluids. High-pressure and high-temperature rheology of a nanomud suspension (nano particles suspended in a mud solution) is studied here. The nanomud is prepared by dispersing a water-based drilling mud suspension (water with 1% Bentonite and 7% Barite particles) with multi-walled carbon nanotubes, MWCNT. The effect of pressure, temperature, and shear rate are independently studied for the various particle loading of the nanoparticles. Viscosity values are measured at a maximum pressure of 170MPa with temperatures ranging from ambient to 180oC. The effect of MWCNT concentration and variation in shear rate are also investigated A shear thinning non-Newtonian behavior is observed for the basemud and the nanomud samples for all cases. The basemud showed an increase in viscosity with an increase in pressure. However, with MWCNT particle addition, this trend is observed to have reversed.

  19. Investigation of the polymerization mechanism of ferrocene doped C60 under high pressure and high temperature.

    Science.gov (United States)

    Sun, Shishuai; Cui, Wen; Wang, Shuangming; Liu, Bingbing

    2017-09-07

    In situ high pressure and high temperature (HPHT) study has been carried out on C60/ferrocene (Fc) in order to detect the process of polymerization and reveal the polymerization mechanism. Pristine C60 was also studied under same conditions for comparison. In both cases, similar types of polymers can be observed after pressure and temperature release, but with different fractions, i.e. a larger amount of 2D polymers were formed in pure C60, while more branch-like polymers were synthesized in C60/Fc, although the most fraction of the polymers is still 1D chain-like polymer in both of the materials. The polymers formed in C60 can be detected both during the "up" run (pressure and temperature increase) and the "down" run (pressure and temperature decrease), while in C60/Fc, the polymers can only be synthesized in the "down" run. The differences between the two cases were attributed to the different initial lattice structures of the two materials and the confinement effect of the dopant. The polymerization mechanism on C60/Fc under HPHT was also revealed in this work.

  20. High structural complexity of potassium uranyl borates derived from high-temperature/high-pressure reactions.

    Science.gov (United States)

    Wu, Shijun; Wang, Shuao; Polinski, Matthew; Beermann, Oliver; Kegler, Philip; Malcherek, Thomas; Holzheid, Astrid; Depmeier, Wulf; Bosbach, Dirk; Albrecht-Schmitt, Thomas E; Alekseev, Evgeny V

    2013-05-06

    Three new potassium uranyl borates, K12[(UO2)19(UO4)(B2O5)2(BO3)6(BO2OH)O10] ·nH2O (TPKBUO-1), K4[(UO2)5(BO3)2O4]·H2O (TPKBUO-2), and K15[(UO2)18(BO3)7O15] (TPKBUO-3), were synthesized under high-temperature/high-pressure conditions. In all three compounds, the U/B ratio exceeds 1. Boron exhibits BO3 coordination only, which is different from other uranyl borates prepared at room temperature or under mild hydrothermal conditions. A rare uranium(VI) tetraoxide core UO4O2, which is coordinated by two BO3 groups, is observed in the structure of TPKBUO-1. Both structures of TPKBUO-1 and TPKBUO-3 contain three different coordination environments of uranium, namely, UO4O2, UO2O4, and UO2O5 and UO2O4, UO2O5, and UO2O6 bipyramids in TPKBUO-1 and TPKBUO-3, respectively.

  1. Effects of catalyst height on diamond crystal morphology under high pressure and high temperature

    Science.gov (United States)

    Ya-Dong, Li; Xiao-Peng, Jia; Bing-Min, Yan; Ning, Chen; Chao, Fang; Yong, Li; Hong-An, Ma

    2016-04-01

    The effect of the catalyst height on the morphology of diamond crystal is investigated by means of temperature gradient growth (TGG) under high pressure and high temperature (HPHT) conditions with using a Ni-based catalyst in this article. The experimental results show that the morphology of diamond changes from an octahedral shape to a cub-octahedral shape as the catalyst height rises. Moreover, the finite element method (FEM) is used to simulate the temperature field of the melted catalyst/solvent. The results show that the temperature at the location of the seed diamond continues to decrease with the increase of catalyst height, which is conducive to changing the morphology of diamond. This work provides a new way to change the diamond crystal morphology. Project supported by the National Natural Science Foundation of China (Grant No. 51172089), the Program for New Century Excellent Talents in University, the Natural Science Foundation of Guizhou Provincial Education Department (Grant No. KY[2013]183), and the Collaborative Fund of Science and Technology Office of Guizhou Province, China (Grant No. LH[2015]7232).

  2. Filter-based Aerosol Measurement Experiments using Spherical Aerosol Particles under High Temperature and High Pressure

    Energy Technology Data Exchange (ETDEWEB)

    Lee, Jong Chan; Jung, Woo Young; Lee, Hyun Chul; Lee, Doo Young [FNC TECH., Yongin (Korea, Republic of)

    2016-05-15

    Optical Particle Counter (OPC) is used to provide real-time measurement of aerosol concentration and size distribution. Glass fiber membrane filter also be used to measure average mass concentration. Three tests (MTA-1, 2 and 3) have been conducted to study thermal-hydraulic effect, a filtering tendency at given SiO{sub 2} particles. Based on the experimental results, the experiment will be carried out further with a main carrier gas of steam and different aerosol size. The test results will provide representative behavior of the aerosols under various conditions. The aim of the tests, MTA 1, 2 and 3, are to be able to 1) establish the test manuals for aerosol generation, mixing, sampling and measurement system, which defines aerosol preparation, calibration, operating and evaluation method under high pressure and high temperature 2) develop commercial aerosol test modules applicable to the thermal power plant, environmental industry, automobile exhaust gas, chemical plant, HVAC system including nuclear power plant. Based on the test results, sampled aerosol particles in the filter indicate that important parameters affecting aerosol behavior aerosols are 1) system temperature to keep above a evaporation temperature of ethanol and 2) aerosol losses due to the settling by ethanol liquid droplet.

  3. Survey of processes for high temperature-high pressure gas purification. [52 references

    Energy Technology Data Exchange (ETDEWEB)

    Meyer, J.P.; Edwards, M.S.

    1978-11-01

    In order to ensure the optimum operating efficiency of a combined-cycle electric power generating system, it is necessary to provide gas treatment processes capable of operating at high temperatures (> 1000/sup 0/F) and high pressures (> 10 atm (absolute)). These systems will be required to condition the inlet stream to the gas turbine to suitable levels of gas purity (removal of particulate matter, sulfur, nitrogen, and alkali metal compounds) to be compatible with both environmental and machine constraints. A survey of the available and developmental processes for the removal of these various contaminant materials has been conducted. Based on the data obtained from a variety of sources, an analysis has been performed to evaluate the performance of a number of potential cleanup processes in view of the overall system needs. The results indicate that commercially available, reliable, and economically competitive hot-gas cleanup systems (for the removal of H/sub 2/S, particulate matter, alkali, and nitrogen compounds) capable of conditioning raw product gas to the levels required for turbine use will not be available for some time.

  4. Survey of industrial coal conversion equipment capabilities: high-temperature, high-pressure gas purification

    Energy Technology Data Exchange (ETDEWEB)

    Meyer, J. P.; Edwards, M. S.

    1978-06-01

    In order to ensure optimum operating efficiencies for combined-cycle electric generating systems, it is necessary to provide gas treatment equipment capable of operating at high temperatures (>1000/sup 0/F) and high pressure (>10 atmospheres absolute). This equipment, when assembled in a process train, will be required to condition the inlet stream to a gas turbine to suitable levels of gas purity (removal of particulate matter, sulfur, nitrogen, and alkali metal compounds) so that it will be compatible with both environmental and machine constraints. In this work, a survey of the available and developmental equipment for the removal of particulate matter and sulfur compounds has been conducted. In addition, an analysis has been performed to evaluate the performance of a number of alternative process configurations in light of overall system needs. Results from this study indicate that commercially available, reliable, and economically competitive hot-gas cleanup equipment capable of conditioning raw product gas to the levels required for high-temperatue turbine operation will not be available for some time.

  5. An Innovative High-Temperature High-Pressure Measurement While Drilling (MWD) Tool

    Energy Technology Data Exchange (ETDEWEB)

    Brian Boling

    2007-06-01

    Measurement while drilling (MWD) tools specified to 150 C (302 F) that provide wellbore surveys, real-time inclination, and natural gamma ray detection are a commodity item in the oilfield services industry. MWD tools specified to 175 C (347 F) that routinely demonstrate highly reliable operation are available from only a few service companies. Commercial MWD tools that reliably operate to 200 C (392 F) for extended periods of time and offer features like real-time gamma ray, retrievability, and reseatability are nonexistent. Need for these higher temperature tools will increase as wells become hotter in the search for new oil and gas resources. The goal of this project was to design a retrievable and reseatable high-pressure/high-temperature MWD tool with real-time continuous inclination, vibration detection, annular pressure, and gamma ray detection. This report describes the development of such a tool from concept, through feasibility, and into field testing and preliminary development planning. It describes the challenges encountered in the design of the tool, along with testing results and decisions about the commercial viability of the tool in the configuration in which it was developed. The decision was made not to commercialize the tool developed under this project because of a combination of battery technology problems and modulation power consumption at the required depths.

  6. On Ultra-High Temperature Metamorphism in the Mid-Lower Crust

    OpenAIRE

    Dorfler, Kristin Marie

    2014-01-01

    The Cortlandt Complex in New York is a composite intrusion of six mafic plutons and contains pelitic xenoliths that experienced extensive interaction with Mg-rich basaltic melt. The complex is an excellent natural example of ultra-high temperature (UHT) metamorphic processes and country rock-magma interaction due to mappable units of hybrid igneous rocks and the presence of large, partially melted, politic "emery" xenoliths. Previous attempts to understand the formation of the UHT xenoliths i...

  7. Permian high-temperature metamorphism in the Western Alps (NW Italy)

    Science.gov (United States)

    Kunz, Barbara E.; Manzotti, Paola; von Niederhäusern, Brigitte; Engi, Martin; Darling, James R.; Giuntoli, Francesco; Lanari, Pierre

    2018-01-01

    During the late Palaeozoic, lithospheric thinning in part of the Alpine realm caused high-temperature low-to-medium pressure metamorphism and partial melting in the lower crust. Permian metamorphism and magmatism has extensively been recorded and dated in the Central, Eastern, and Southern Alps. However, Permian metamorphic ages in the Western Alps so far are constrained by very few and sparsely distributed data. The present study fills this gap. We present U/Pb ages of metamorphic zircon from several Adria-derived continental units now situated in the Western Alps, defining a range between 286 and 266 Ma. Trace element thermometry yields temperatures of 580-890 °C from Ti-in-zircon and 630-850 °C from Zr-in-rutile for Permian metamorphic rims. These temperature estimates, together with preserved mineral assemblages (garnet-prismatic sillimanite-biotite-plagioclase-quartz-K-feldspar-rutile), define pervasive upper-amphibolite to granulite facies conditions for Permian metamorphism. U/Pb ages from this study are similar to Permian ages reported for the Ivrea Zone in the Southern Alps and Austroalpine units in the Central and Eastern Alps. Regional comparison across the former Adriatic and European margin reveals a complex pattern of ages reported from late Palaeozoic magmatic and metamorphic rocks (and relics thereof): two late Variscan age groups ( 330 and 300 Ma) are followed seamlessly by a broad range of Permian ages (300-250 Ma). The former are associated with late-orogenic collapse; in samples from this study these are weakly represented. Clearly, dominant is the Permian group, which is related to crustal thinning, hinting to a possible initiation of continental rifting along a passive margin.

  8. High-pressure, high-temperature magic angle spinning nuclear magnetic resonance devices and processes for making and using same

    Science.gov (United States)

    Hu, Jian Zhi; Hu, Mary Y.; Townsend, Mark R.; Lercher, Johannes A.; Peden, Charles H. F.

    2015-10-06

    Re-usable ceramic magic angle spinning (MAS) NMR rotors constructed of high-mechanic strength ceramics are detailed that include a sample compartment that maintains high pressures up to at least about 200 atmospheres (atm) and high temperatures up to about least about 300.degree. C. during operation. The rotor designs minimize pressure losses stemming from penetration over an extended period of time. The present invention makes possible a variety of in-situ high pressure, high temperature MAS NMR experiments not previously achieved in the prior art.

  9. Energy-Based Tetrahedron Sensor for High-Temperature, High-Pressure Environments

    Science.gov (United States)

    Gee, Kent L.; Sommerfeldt, Scott D.; Blotter, Jonathan D.

    2012-01-01

    An acoustic energy-based probe has been developed that incorporates multiple acoustic sensing elements in order to obtain the acoustic pressure and three-dimensional acoustic particle velocity. With these quantities, the user can obtain various energy-based quantities, including acoustic energy density, acoustic intensity, and acoustic impedance. In this specific development, the probe has been designed to operate in an environment characterized by high temperatures and high pressures as is found in the close vicinity of rocket plumes. Given these capabilities, the probe is designed to be used to investigate the acoustic conditions within the plume of a rocket engine or jet engine to facilitate greater understanding of the noise generation mechanisms in those plumes. The probe features sensors mounted inside a solid sphere. The associated electronics for the probe are contained within the sphere and the associated handle for the probe. More importantly, the design of the probe has desirable properties that reduce the bias errors associated with determining the acoustic pressure and velocity using finite sum and difference techniques. The diameter of the probe dictates the lower and upper operating frequencies for the probe, where accurate measurements can be acquired. The current probe design implements a sphere diameter of 1 in. (2.5 cm), which limits the upper operating frequency to about 4.5 kHz. The sensors are operational up to much higher frequencies, and could be used to acquire pressure data at higher frequencies, but the energy-based measurements are limited to that upper frequency. Larger or smaller spherical probes could be designed to go to lower or higher frequency range

  10. Monazite behaviours during high-temperature metamorphism: a case study from Dinggye region, Tibetan Himalaya

    Science.gov (United States)

    Wang, Jia-Min; Wu, Fu-Yuan; Rubatto, Daniela; Liu, Shi-Ran; Zhang, Jin-Jiang

    2017-04-01

    Monazite is a key accessory mineral for metamorphic geochronology, but its growth mechanisms during melt-bearing high-temperature metamorphism is not well understood. Therefore, the petrology, pressure-temperature and timing of metamorphism have been investigated in pelitic and psammitic granulites from the Greater Himalayan Crystalline Complex (GHC) in Dinggye, southern Tibet. These rocks underwent an isothermal decompression process from pressure conditions of >10 kbar to mineral growth by comprehensive studies on zoning patterns, trace element signatures, index mineral inclusions (melt inclusions, sillimanite and K-feldspar) in dated domains and textural correlations with coexisting minerals. The results show that inherited domains (500-400 Ma) are common in monazite even at granulite-facies conditions. Few monazites formed at the M1-stage ( 30-29 Ma) and recorded heterogeneous Th, Y, and HREE compositions, which formed by recrystallization related to muscovite dehydration melting reaction. These monazite grains were protected from dissolution or lateral overprinting mainly by the armour effect of matrix crystals (biotite and quartz). Most monazite grains formed at the M3-stage (21-19 Ma) through either dissolution-reprecipitation or recrystallization that was related to biotite dehydration melting reaction. These monazite grains record HREE and Y signatures in local equilibrium with different reactions involving either garnet breakdown or peritectic garnet growth. Another peak of monazite growth occurs during melt crystallization ( 15 Ma), and these monazites are unzoned and have homogeneous compositions. Our results documented the widespread recrystallization to account for monazite growth during high-temperature metamorphism and related melting reactions that trigger monazite recrystallization. In a regional sense, our P-T-t data along with published data indicate that the pre-M1 eclogite-facies metamorphism occurred at 39-30 Ma in the Dinggye Himalaya. Our

  11. Synthesis of Dense BC3 Phases under High-Pressure and High-Temperature

    Science.gov (United States)

    Zinin, P.; Ming, L.; Acosta, T.; Jia, R.; Hellebrand, E.; Ishii, H.

    2010-12-01

    The finding of the new diamond-like B-C phases is of fundamental importance. These phases are potential high-temperature superconductors and their development is important for understanding the nature of high-temperature superconductivity (Moussa, Cohen, Phys. Rev. B, 77, 064518 2008). They will shed light on the nature of the bonding of the boron atoms in a diamond-like structure. Recently, theoretical simulations of pressure- and temperature-induced phase transition in the B-C system demonstrated that the incorporation of B atoms into a diamond structure should not lead to a drastic distortion of the cubic cell of a diamond (Lowther, J. Phys. Condense Matter. 17, 3221, 2005). In this report we present data on the synthesis of new dense phases cubic BC3 (c-BC3) phase from graphitic BC3 phase (g-BC3) phase under high pressure and high temperature. Two graphitic polycrystalline BCx samples were compressed in a diamond-anvil cell to about 24 GPa and 45 GPa, respectively, and then were laser-heated to ~2000 K. After quenching, each sample was decompressed gradually stepwise to the atmospheric pressure. Synchrotron-based X-ray diffraction patterns were taken before and after the laser-heating, and also at each pressure step-down. The experimental data showed that two new phases were synthesized: (a) an orthorhombic phase with a0 = 3.74 Å, b0 = 3.24 Å, c0=4.25 Å; and (b) a cubic phase with a0 = 3.587Å recovered from 24 GPa and 44 GPa, respectively. The zero-pressure lattice parameter of the cubic phase obtained in this study is larger than that of diamond (i.e., a0=3.5667 Å, ASTM # 6-0675), which is consistent with theoretical prediction The micro-Raman measurements were directly performed on the new phases. The Raman spectra excited by a green (Nd-YAG, 532-nm) laser were taken with a confocal Raman system (WiTec alpha300). The Raman spectrum of the c-BC3 phase is similar to that of diamond-like BC3 phase (Zinin et al., J. Raman Spectrosc., 38, 1362, 2007) with a

  12. High-Pressure-High-Temperature Processing Reduces Maillard Reaction and Viscosity in Whey Protein-Sugar Solutions

    NARCIS (Netherlands)

    Avila Ruiz, Geraldine; Xi, Bingyan; Minor, Marcel; Sala, Guido; Boekel, van Tiny; Fogliano, Vincenzo; Stieger, Markus

    2016-01-01

    The aim of the study was to determine the influence of pressure in high-pressure-high-temperature (HPHT) processing on Maillard reactions and protein aggregation of whey protein-sugar solutions. Solutions of whey protein isolate containing either glucose or trehalose at pH 6, 7, and 9 were

  13. High Efficiency Heat Exchanger for High Temperature and High Pressure Applications

    Energy Technology Data Exchange (ETDEWEB)

    Sienicki, James J. [Argonne National Lab. (ANL), Argonne, IL (United States). Nuclear Engineering Division; Lv, Qiuping [Argonne National Lab. (ANL), Argonne, IL (United States). Nuclear Engineering Division; Moisseytsev, Anton [Argonne National Lab. (ANL), Argonne, IL (United States). Nuclear Engineering Division

    2017-09-29

    CompRex, LLC (CompRex) specializes in the design and manufacture of compact heat exchangers and heat exchange reactors for high temperature and high pressure applications. CompRex’s proprietary compact technology not only increases heat exchange efficiency by at least 25 % but also reduces footprint by at least a factor of ten compared to traditional shell-and-tube solutions of the same capacity and by 15 to 20 % compared to other currently available Printed Circuit Heat Exchanger (PCHE) solutions. As a result, CompRex’s solution is especially suitable for Brayton cycle supercritical carbon dioxide (sCO2) systems given its high efficiency and significantly lower capital and operating expenses. CompRex has already successfully demonstrated its technology and ability to deliver with a pilot-scale compact heat exchanger that was under contract by the Naval Nuclear Laboratory for sCO2 power cycle development. The performance tested unit met or exceeded the thermal and hydraulic specifications with measured heat transfer between 95 to 98 % of maximum heat transfer and temperature and pressure drop values all consistent with the modeled values. CompRex’s vision is to commercialize its compact technology and become the leading provider for compact heat exchangers and heat exchange reactors for various applications including Brayton cycle sCO2 systems. One of the limitations of the sCO2 Brayton power cycle is the design and manufacturing of efficient heat exchangers at extreme operating conditions. Current diffusion-bonded heat exchangers have limitations on the channel size through which the fluid travels, resulting in excessive solid material per heat exchanger volume. CompRex’s design allows for more open area and shorter fluid proximity for increased heat transfer efficiency while sustaining the structural integrity needed for the application. CompRex is developing a novel improvement to its current heat exchanger design where fluids are directed to alternating

  14. Tertiary plate tectonics and high-pressure metamorphism in New Caledonia

    Science.gov (United States)

    Brothers, R.N.; Blake, M.C.

    1973-01-01

    The sialic basement of New Caledonia is a Permian-Jurassic greywacke sequence which was folded and metamorphosed to prehnite-pumpellyite or low-grade greenschist facies by the Late Jurassic. Succeeding Cretaceous-Eocene sediments unconformably overlie this basement and extend outwards onto oceanic crust. Tertiary tectonism occurred in three distinct phases. 1. (1) During the Late Eocene a nappe of peridotite was obducted onto southern New Caledonia from northeast to southwest, but without causing significant metamorphism in the underlying sialic rocks. 2. (2) Oligocene compressive thrust tectonics in the northern part of the island accompanied a major east-west subduction zone, at least 30 km wide, which is identified by an imbricate system of tectonically intruded melanges and by development of lawsonite-bearing assemblages in adjacent country rocks; this high-pressure mineralogy constituted a primary metamorphism for the Cretaceous-Eocene sedimentary pile, but was overprinted on the Mesozoic prehnite-pumpellyite metagreywackes. 3. (3) Post-Oligocene transcurrent faulting along a northwest-southeast line (the sillon) parallel to the west coast caused at least 150 km of dextral offset of the southwest frontal margin of the Eocene ultramafic nappe. At the present time, the tectonics of the southwest Pacific are related to a series of opposite facing subduction (Benioff) zones connected by transform faults extending from New Britain-Solomon Islands south through the New Hebrides to New Zealand and marking the boundary between the Australian and Pacific plates. Available geologic data from this region suggest that a similar geometry existed during the Tertiary and that the microcontinents of New Guinea, New Caledonia and New Zealand all lay along the former plate boundary which has since migrated north and east by a complex process of sea-floor spreading behind the active island arcs. ?? 1973.

  15. Modeling of high temperature- and diffusion-controlled die soldering in aluminum high pressure die casting

    DEFF Research Database (Denmark)

    Domkin, Konstantin; Hattel, Jesper Henri; Thorborg, Jesper

    2009-01-01

    Soldering of cast alloys to the dies has been a continuing source of die surface damage in the aluminum die-casting industry. To reduce the repair and maintenance costs, an approach to modeling the damage and predicting the die lifetime is required. The aim of the present study is the estimation...... the die-casting industry. As an example, the model is applied to several cases of high pressure die casting (HPDC) where A380 alloy parts are cast in the H13 steel die. The predicted locations of the higher strength of soldering appear in the "hot spot" areas of the die surface in agreement...

  16. Comparison of the existing internally consistent pressure scales at high pressures and high temperatures

    Science.gov (United States)

    Cynn, Hyunchae; Baer, B. J.; MacLeod, S. G.; Evans, W. J.; Lipp, M. J.; Klepeis, J. P.; Jenei, Zs.; Chen, J. Y.; Catalli, K.; Popov, D.; Park, C. Y.

    2012-02-01

    There have been several efforts to determine internally consistent pressure scales for static diamond anvil high pressure study. We decide to extend the choice of pressure scales to include W and Cu. A recent study of Cu claims that electronic theory can constrain cold curve and possibly room temperature isotherm (Greeff et al., 2006, JPCS). We will present our comparison of 6 different pressure scales in regards with the suggested Cu EOS. We have measured angle-dispersive x-ray diffraction of Au, Pt, W, Cu, Ne, and NaCl to directly compare with the current existing EOS. We will also discuss discrepancies in the precise determination of pressure of phase transformations.

  17. Feasibility study of underground energy storage using high-pressure, high-temperature water. Final report

    Energy Technology Data Exchange (ETDEWEB)

    Dooley, J.L.; Frost, G.P.; Gore, L.A.; Hammond, R.P.; Rawson, D.L.; Ridgway, S.L.

    1977-01-01

    A technical, operational and economic feasibility study on the storage of energy as heated high pressure water in underground cavities that utilize the rock overburden for containment is presented. Handling peak load requirements of electric utility power networks is examined in some detail. The cavity is charged by heating water with surplus steaming capacity during periods of low power requirement. Later this hot water supplies steam to peaking turbines when high load demands must be met. This system can be applied to either new or existing power plants of nuclear or fossil fuel type. The round trip efficiency (into storage and back) is higher than any other system - over 90%. Capital costs are competitive and the environmental impact is quite benign. Detailed installation and design problems are studied and costs are estimated. The continental United States is examined for the most applicable geology. Formations favorable for these large cavities exist in widespread areas.

  18. Solubility Measurements and Modeling of Zinc, Lead and Iron Sulfides at High Temperatures and High Pressures

    DEFF Research Database (Denmark)

    Carolina Figueroa Murcia, Diana; Fosbøl, Philip Loldrup; Thomsen, Kaj

    task. Consequently existing data are rare and scattered. The aim of this work is to develop a reliable experimental procedure and to measure solubility of sulfides at high temperature and pressures. Additionally the experimental data are used for estimation of the solid-liquid equilibrium using...... the Extended UNIQUAC model. The experimental determination of the solubility of ZnS, PbS and FeS is carried out at temperatures up to 200°C and pressures up to 60 bars. The minerals in their pure form are added to ultra-pure water previously degassed with nitrogen. The aqueous solution is prepared in a reduced...... oxygen atmosphere to avoid the risk of oxidation of sulfide minerals. The solution is kept in an equilibrium cell at constant temperature and pressure with continuous stirring. The concentration of Zn2+, Pb2+, Fe2+ and S2- are measured using Inductively Coupled Plasma Optical Emission spectrometry (ICP...

  19. High-temperature high-pressure gas cleanup with ceramic bag filters. Draft final report

    Energy Technology Data Exchange (ETDEWEB)

    Shackleton, M.; Chang, R.; Sawyer, J.; Kuby, W.; Turner-Tamiyasu, E.

    1982-12-06

    Advanced processes designed for the efficient use of coal in the production of energy will benefit from, or even depend upon, highly efficient, economical, high-temperature removal systems for fine particulates. In the case of pressurized fluidized-bed combustion (PFBC), the hot gas cleanup device must operate at approximately 1600/sup 0/F. Existing commercial filter systems are temperature limited due to the filter material, but ceramic fibers intended for refractory insulation offer the promise of a practical high-temperature filter media if they can be incorporated into a design which combines filter performance with acceptable durability. The current work was initiated to further develop and demonstrate on a larger-scale basis, a ceramic fiber filtration system for application to coal-fired PFBC's. The development effort centered around the need to replace the knit metal wire scrim, used in earlier designs as support for the fine fiber ceramic mat filtration medium, with a corrosion-resistant material. This led to the selection of woven ceramic cloth for support of the mat layer. Because of the substantial difference in strength and other material properties between the metal and ceramic cloth, tests were necessary to optimize the filter; pulse parameters such as pulse duration, pulse pressure, and pulse injection orifice size; woven cloth mesh configuration; the technique for clamping the bag to the support; and similar structural, fluid, and control parameters. The demonstration effort included both tests to prove this concept in a real application and a systems analysis to show commercial feasibility of the ceramic filtration approach for hot gas cleanup in PFBC's. 12 references, 57 figures, 23 tables.

  20. Spin crossover and Mott—Hubbard transition under high pressure and high temperature in the low mantle of the Earth

    Science.gov (United States)

    Ovchinnikov, S. G.; Ovchinnikova, T. M.; Plotkin, V. V.; Dyad'kov, P. G.

    2015-11-01

    Effect of high pressure induced spin crossover on the magnetic, electronic and structural properties of the minerals forming the Earth's low mantle is discussed. The low temperature P, T phase diagram of ferropericlase has the quantum phase transition point Pc = 56 GPa at T = 0 confirmed recently by the synchrotron Mössbauer spectroscopy. The LDA+GTB calculated phase diagram describes the experimental data. Its extension to the high temperature resulted earlier in prediction of the metallic properties of the Earth's mantle at the depth 1400 km insulator transition and compare them with the experimental seismic and geomagnetic field data.

  1. Vaporization and configuration effects in a high-pressure/high-temperature combustor equipped with multiple Venturi-type fuel injectors

    Science.gov (United States)

    Locke, Randy J.; Chun, K. S.; Lee, C. M.; Ratvasky, William J.

    1994-03-01

    The flow field and fuel/air mixing patterns produced in an optically accessible, premixing/prevaporization section of a high pressure/high temperature combustor were examined via focused Schlieren high-speed photography. A focal plane, approximately 8 mm thick and centered within this section downstream of the fuel injectors, was imaged at a framing rate of 8,000 frames/second. High-speed focused Schlieren images were obtained for three different Venturi-type fuel injector configurations under identical experimental parameters. The results demonstrate the efficacy of this technique to discern fuel spray patternization, fuel-air mixing efficiencies, and mixing times of various fuel injector arrangements.

  2. Synthesis of Fused Pyrimidinone and Quinolone Derivatives in an Automated High-Temperature and High-Pressure Flow Reactor.

    Science.gov (United States)

    Tsoung, Jennifer; Bogdan, Andrew R; Kantor, Stanislaw; Wang, Ying; Charaschanya, Manwika; Djuric, Stevan W

    2017-01-20

    Fused pyrimidinone and quinolone derivatives that are of potential interest to pharmaceutical research were synthesized within minutes in up to 96% yield in an automated Phoenix high-temperature and high-pressure continuous flow reactor. Heterocyclic scaffolds that are either hard to synthesize or require multisteps are readily accessible using a common set of reaction conditions. The use of low-boiling solvents along with the high conversions of these reactions allowed for facile workup and isolation. The methods reported herein are highly amenable for fast and efficient heterocycle synthesis as well as compound scale-ups.

  3. Exploring silicon allotropy and chemistry by high pressurehigh temperature conditions

    Science.gov (United States)

    Kurakevych, O. O.; Le Godec, Y.; Strobel, T. A.; Kim, D. Y.; Crichton, W. A.; Guignard, J.

    2017-10-01

    Silicon is the second abundant element, after oxygen, in the earth crust. It is essential for today’s electronics because of its ability to show various electronic behaviors that allow covering the numerous fields of cutting-edge applications. Moreover, silicon is not a pollutant and, therefore, is an ideal candidate to replace the actual materials in photovoltaics, like compounds based on the arsenic and heavy metals. It has not replaced them so far because Si is an indirect gap semiconductor and cannot absorb directly the solar photons without thermal agitations of crystal lattice (phonons). This puts it apart from the next-generation applications (light diode, high-performance transistor). That justifies the attempts to create silicon materials with direct gap that can absorb and emit light. Our recent high-pressure studies of the chemical interaction and phase transformations in the Na-Si system, revealed a number of interesting routes to new and known silicon compounds and allotropes. The pressure-temperature range of their formation is suitable for large-volume synthesis and future industrial scaling. The variety of properties observed (e.g. quasi-direct bandgap of open-framework allotrope Si24) allows us to suggest future industrial applications.

  4. Picosecond ballistic imaging of diesel injection in high-temperature and high-pressure air

    Science.gov (United States)

    Duran, Sean P.; Porter, Jason M.; Parker, Terence E.

    2015-04-01

    The first successful demonstration of picosecond ballistic imaging using a 15-ps-pulse-duration laser in diesel sprays at temperature and pressure is reported. This technique uses an optical Kerr effect shutter constructed from a CS2 liquid cell and a 15-ps pulse at 532 nm. The optical shutter can be adjusted to produce effective imaging pulses between 7 and 16 ps. This technique is used to image the near-orifice region (first 3 mm) of diesel sprays from a high-pressure single-hole fuel injector. Ballistic imaging of dodecane and methyl oleate sprays injected into ambient air and diesel injection at preignition engine-like conditions are reported. Dodecane was injected into air heated to 600 °C and pressurized to 20 atm. The resulting images of the near-orifice region at these conditions reveal dramatic shedding of the liquid near the nozzle, an effect that has been predicted, but to our knowledge never before imaged. These shedding structures have an approximate spatial frequency of 10 mm-1 with lengths from 50 to 200 μm. Several parameters are explored including injection pressure, liquid fuel temperature, air temperature and pressure, and fuel type. Resulting trends are summarized with accompanying images.

  5. Development of high temperature, high pressure rotating shaft seals: Final report

    Energy Technology Data Exchange (ETDEWEB)

    Heshmat, H.; Shapiro, W.

    1987-06-01

    Rotating shaft seals used in coal gasification equipment are exposed to difficult environmental conditions including temperature from 430/sup 0/C to 816/sup 0/C (800/sup 0/F to 1500/sup 0/F), high pressure (to 10 MPa or 1500 psig), and high levels of particulate contamination (50,000 to 100,000 ppM). The program reported upon was designed to develop long-life seals that would not require external flushing or cooling. The approach taken was to develop unbalanced face that would remain closed and prevent particulate entry into the interface. Wear resistant materials and coatings with low friction coefficients are required. Significant results of the program are enumerated: The selected material combination was a rotating runner of Kentanium K162B mating against a non-rotating seal ring of Kentanium K162B. Kentanium is the trade name of a series of hard carbide alloys with pure titanium carbide as the principal ingredient. Nickel and nickel molybdenum are used as binder materials. Kentanium retains most of its strength at temperatures ..mu..p to 1100/sup 0/C (2000/sup 0/F). Since hard materials are required to resist wear and withstand the temperatures, mechanical compliance must be built into the seal configuration for the opposed faces to follow runner nutations and remain closed. Environmental and frictional heating caused the formation of very small particles of titanium oxide which lodged in the face wave formations and acted as an interfacial lubricant. The results of this program provide encouragement and optimism that dry contact face seals can be developed for long unattended operation in the hostile environment of a coal gasification plant. 40 refs., 98 figs., 20 tabs.

  6. Highly Coordinated Iron and Cobalt Nitrides Synthesized at High Pressures and High Temperatures.

    Science.gov (United States)

    Niwa, Ken; Terabe, Toshiki; Kato, Daiki; Takayama, Shin; Kato, Masahiko; Soda, Kazuo; Hasegawa, Masashi

    2017-06-05

    Highly coordinated iron and cobalt nitrides were successfully synthesized via direct chemical reaction between a transition metal and molecular nitrogen at pressures above approximately 30 GPa using a laser-heated diamond anvil cell. The synthesized novel transition metal nitrides were found to crystallize into the NiAs-type or marcasite-type structure. NiAs-type FeN could be quenched at ambient pressure, although it was gradually converted to the ZnS-type structure after the pressure was released. On the other hand, CoN was recovered with ZnS-type structure through a phase transition from NiAs-type structure at approximately a few gigapascals during decompression. Marcasite-type CoN2 was also synthesized at pressures above approximately 30 GPa. High-pressure in situ X-ray diffraction measurement showed that the zero-pressure bulk modulus of marcasite-type CoN2 is 216(18) GPa, which is comparable to that of RhN2. This indicates that the interatomic distance of the N-N dimer in marcasite-type CoN2 is short because of weak orbital interaction between cobalt and nitrogen atoms, as in RhN2. Surprisingly, a first-principles electronic band calculation suggests that the NiAs-type FeN and CoN and marcasite-type CoN2 exhibit metallic characteristics with magnetic moments of 3.4, 0.6, and 1.2 μB, respectively. The ferromagnetic NiAs-type structure originates from the anisotropic arrangement of transition atoms stacked along the c axis.

  7. Tectonic origin and deformation process of the Mayer Kangri medium-high pressure metamorphic dome in Central Qiangtang of Tibet

    Science.gov (United States)

    Wang, Y.; Liang, X.

    2016-12-01

    The metamorphic characteristics, deformation process, geochronology of the medium-high pressure metamorphic rocks in blueschist bearing Central Qiangtang Metamorphic belt (CQMB) of Tibet were less well constrained. It is, however, commonly assumed that these rock slices in the margin also contain important implications on the evolution of the entire metamorphic belt. The well-exposed Mayer Kangri medium-high pressure metamorphic dome in north flank of the CQMB provides an unique opportunity to investigate the outer part of the CQMB, which could facilitate the study on the subduction-exhumation-post orogenic scenarios of the Triassic accretionary orogeny in Central Qiangtang. Field structural analyses indicate the Mayer Kangri metamorphic dome are bounded by low-angle normal faults (LANF) within the hanging wall of low-green schist facies mélange. It majorly consists of epidote-amphibolites, quartz-phengite schist, epidote-albite schist. The outcrop and micro structural observations of footwall metamorphic rocks show an open anticline with multiple foliation replacement, which largely differentiate themselves from the dextral strike-slip shearing of the hanging wall. Well-zoned amphiboles were found within the epidote-amphibolite after micro-structural observations and electron probe microanalyses (EPMA), which indicate that the amphibole zonation demonstrates a Hastingsite core, a Ferro-actinolite mantle and a Ferro-winchite rim in most cases. The mean temperature and pressure estimates of the zoned amphibolites change from 544 °, 0.98Gpa in the core, to 426°, 0.34Gpa in the mantle, and to ca.364° and 0.70 GPa in the rim. The detailed analyses on the stepwise-heating Ar-Ar results of the zoned amphiboles provide good constrains on the episodic deformation process of the CQMB. For Hast-cores, we obtained near plateau ages of 242.4-241.2 Ma, indicating the onset of the oceanic subduction is earlier than the Anisian stage of Middle Triassic. The subsequent

  8. Impact of different water activities (aw adjusted by solutes on high pressure high temperature inactivation of Bacillus amyloliquefaciens spores

    Directory of Open Access Journals (Sweden)

    Robert eSevenich

    2015-07-01

    Full Text Available Much research has been conducted to comprehend the mechanisms of high pressure (HP inactivation of spores in aqueous systems but for food model systems these information are scarce. In these systems spores can interact with ingredients which could lead to retarded inactivation, which can cause a problem for the sterilization process. The protective mechanism of a reduced a_W-value is still unclear. HP processing might prove valuable to overcome protective effects of solutes and achieve shorter process times for sterilization under HP. To gain insight into the underlying mechanisms five a_W-values (0.9, 0.92, 0.94, 0.96, 1 were adjusted with 2 different solutes (NaCl, sucrose. Solutions were inoculated with spores of Bacillus amyloliquefaciens and treated at 105,110°C and115°C at 600 MPa. A thermal inactivation was conducted at the same temperatures for a compraison with the high pressure data. The influence of high pressure high temperature treatment on the inactivation, the DPA-release and membrane constitution was assessed by plate count, HPLC and flow cytometry. The results show that during HP treatments sucrose and salt both have a protective effect, in which the influence of sucrose on the retarded inactivation is higher. The threshold aw, which is 0.94, here salt and sucrose have a significant influence on the inactivation. The comparison of thermal (105-115°C and high pressure and high temperature (600 MPa, 105-115°C treated samples showed that the time needed to achieve a 4-5 log inactivation can be reduced at 600 MPa.The release of dipicolinic acid (DPA is the rate limiting step of the inactivation and therefore monitoring the release is of great interest. The DPA-release is slowed is slowed down in high concentrated solutions (e.g. sucrose, salt in comparison to aw 1. Maybe as shown for vegetative microorganism the solutes can interact with membranes, e.g. inner spore membrane. FCM (flow cytometry measurement data show a similar

  9. High-pressure high-temperature crystal growth of equiatomic rare earth stannides RENiSn and REPdSn

    Energy Technology Data Exchange (ETDEWEB)

    Heymann, Gunter [Institut für Allgemeine, Anorganische und Theoretische Chemie, Leopold-Franzens-Universität Innsbruck, Innrain 80-82, A-6020 Innsbruck (Austria); Heying, Birgit; Rodewald, Ute Ch.; Janka, Oliver [Institut für Anorganische und Analytische Chemie, Universität Münster, Corrensstraße 30, 48149 Münster (Germany); Huppertz, Hubert, E-mail: Hubert.Huppertz@uibk.ac.at [Institut für Allgemeine, Anorganische und Theoretische Chemie, Leopold-Franzens-Universität Innsbruck, Innrain 80-82, A-6020 Innsbruck (Austria); Pöttgen, Rainer, E-mail: pottgen@uni-muenster.de [Institut für Anorganische und Analytische Chemie, Universität Münster, Corrensstraße 30, 48149 Münster (Germany)

    2016-04-15

    The two series of equiatomic rare earth (RE) stannides RENiSn and REPdSn were systematically studied with respect to high-pressure modifications. The normal-pressure (NP) low-temperature (LT) modifications were synthesized by arc-melting and subsequently treated under high-pressure (P{sub max}=11.5 GPa) and high-temperature (T{sub max}=1570 K) conditions in a Walker-type multi-anvil press. The pressure and temperature conditions were systematically varied in order to improve the crystallization conditions. The new ZrNiAl-type high-pressure modifications HP-RENiSn (RE=Sc, Y, La, Gd–Lu) and HP-REPdSn (RE=Y, Sm–Dy) were obtained in 80 mg quantities, several of them in X-ray pure form. Some of the REPdSn stannides with the heavy rare earth elements show high-temperature (HT) modifications. The structures of HP-ScNiSn, HP-GdNiSn, HP-DyNiSn (both ZrNiAl-type), NP-YbNiSn, and HT-ErPdSn (both TiNiSi-type) were refined from single crystal diffractometer data, indicating full ordering of the transition metal and tin sites. TiNiSi-type NP-EuPdSn transforms to MgZn{sub 2}-type HP-EuPdSn: P6{sub 3}/mmc, a=588.5(2), c=917.0(3) pm, wR2=0.0769, 211 F{sup 2} values, 11 variables. The structure refinement indicated statistical occupancy of the palladium and tin sites on the tetrahedral network. The X-ray pure high-pressure phases were studied with respect to their magnetic properties. HP-YPdSn is a Pauli paramagnet. The susceptibility data of HP-TbNiSn, HP-DyNiSn, HP-GdPdSn, and HP-TbPdSn show experimental magnetic moments close to the free ion values of RE{sup 3+} and antiferromagnetic ordering at low temperature with the highest Néel temperature of 15.8 K for HP-TbPdSn. HP-SmPdSn shows the typical Van Vleck type behavior along with antiferromagnetic ordering at T{sub N}=5.1 K. HP-EuPdSn shows divalent europium and antiferromagnetic ordering at 8.9 K followed by a spin reorientation at 5.7 K. - Graphical abstract: Packing of the polyhedra in the high-pressure phase of Eu

  10. High-pressure high-temperature equations of state of UO2 and ThO2

    Science.gov (United States)

    Chidester, B.; Campbell, A. J.; Fischer, R. A.; Reaman, D. M.; Heinz, D. L.; Prakapenka, V.

    2013-12-01

    The actinide elements uranium and thorium are important from the standpoint of heat production in the deep Earth. However, the host mineral phases and distribution of these elements in the mantle are not well constrained. Here we investigate the crystal chemistry and coordination preferences of these elements in simple oxides. Room-temperature high-pressure equations of state of uranium dioxide (UO2) and thorium dioxide (ThO2) have been reported [1-5], but no in situ high-pressure, high-temperature (high P-T) data are available for these compounds. We present results from a high P-T synchrotron x-ray diffraction study of the equations of state and observed phase relations of UO2 and ThO2. High-pressure, high-temperature in situ X-ray diffraction data were obtained at beamline 13-ID-D of the Advanced Photon Source, and room temperature compression data were obtained at beamline 12.2.2 of the Advanced Light Source. We observed that UO2 exists only in the cubic fluorite structure (space group Fm3m) up to 32 GPa and 2300 K. By fitting these P-V-T data to a Birch-Murnaghan equation of state (EOS), we obtain the thermodynamic parameters K0 = 222 × 3.9 GPa and the thermal contribution to pressure, αK = 0.00254 × 0.00044 GPa/K (V0 = 24.51 cm3/mol and K0' = 5, fixed). At ~46 GPa and up to 2400 K, the cubic structure was found to coexist with a high-pressure phase, which we indexed as the orthorhombic Pnma space group (Z=8). Above this pressure, only the orthorhombic structure was observed up to 61 GPa and 2400 K. The EOS parameters for this phase are V0 = 23.84 × 0.20 cm3/mol, K0 = 187 × 10 GPa and αK = 0.00308 × 0.00042 GPa/K (K0' = 4, fixed). Similarly, ThO2 has the fluorite (Fm3m) structure up to ~23 GPa. The EOS parameters for this phase are K0 = 199 × 10 GPa, K0' = 7.1 × 2.0 and αK = 0.00656 × 0.00092 GPa/K (V0 = 26.38 cm3/mol, fixed). The cubic phase was observed to coexist with an orthorhombic phase (Pnma, Z=4) between 27 and 31 GPa and up to 1900 K. Above

  11. Stepwise exhumation of the Triassic Lanling high-pressure metamorphic belt in Central Qiangtang, Tibet: Insights from a coupled study of metamorphism, deformation, and geochronology

    Science.gov (United States)

    Liang, Xiao; Wang, Genhou; Yang, Bo; Ran, Hao; Zheng, Yilong; Du, Jinxue; Li, Lingui

    2017-04-01

    The E-W trending Central Qiangtang metamorphic belt (CQMB) is correlated to the Triassic orogeny of the Paleo-Tethys Ocean prior to Cenozoic growth of the Tibetan Plateau. The well-exposed Lanling high-pressure, low-temperature (HP-LT) metamorphic complex was chosen to decipher the process by which it was exhumed, which thereby provides insights into the origin of the CQMB and Qiangtang terrane. After a detailed petrological and structural mapping, three distinct N-S-trending metamorphic domains were distinguished. Microscopic observations show that core domain garnet (Grt)-bearing blueschist was exhumed in a heating plus depressurization trajectory after peak eclogitic conditions, which is more evident in syntectonic vein form porphyroblastic garnets with zoning typical of a prograde path. Grt-free blueschist of the mantle domain probably underwent an exhumation path of temperature increasing and dehydration, as evidenced by pervasive epidote veins. The compilation of radiometric results of high-pressure mineral separates in Lanling and Central Qiantang, and reassessments on the published phengite data sets of Lanling using Arrhenius plots allow a two-step exhumation model to be formulated. It is suggested that core domain eclogitic rocks were brought onto mantle domain blueschist facies level starting at 244-230 Ma, with exhumation continuing to 227-223.4 Ma, and subsequently were exhumed together starting at 223-220 Ma, reaching lower greenschist facies conditions generally after 222-217 Ma. These new observations indicate that the CQMB formed as a Triassic autochthonous accretionary complex resulting from the northward subdcution of the Paleo-Tethys Ocean and that HP-LT rocks therein were very probably exhumed in an extensional regime.

  12. Six-axis multi-anvil press for high-pressure, high-temperature neutron diffraction experiments

    Energy Technology Data Exchange (ETDEWEB)

    Sano-Furukawa, A., E-mail: sano.asami@jaea.go.jp; Hattori, T. [Quantum Beam Science Center, Japan Atomic Energy Agency, Ibaraki 319-1195 (Japan); J-PARC Center, Japan Atomic Energy Agency, Ibaraki 319-1195 (Japan); Arima, H. [Institute for Materials Research, Tohoku University, Sendai 980-8577 (Japan); Yamada, A. [The University of Shiga Prefecture, Shiga 522-8533 (Japan); Tabata, S.; Kondo, M.; Nakamura, A. [Sumitomo Heavy Industries Co., Ltd., Ehime 792-0001 (Japan); Kagi, H.; Yagi, T. [Geochemical Research Center, Graduate School of Science, The University of Tokyo, Tokyo 113-0033 (Japan)

    2014-11-15

    We developed a six-axis multi-anvil press, ATSUHIME, for high-pressure and high-temperature in situ time-of-flight neutron powder diffraction experiments. The press has six orthogonally oriented hydraulic rams that operate individually to compress a cubic sample assembly. Experiments indicate that the press can generate pressures up to 9.3 GPa and temperatures up to 2000 K using a 6-6-type cell assembly, with available sample volume of about 50 mm{sup 3}. Using a 6-8-type cell assembly, the available conditions expand to 16 GPa and 1273 K. Because the six-axis press has no guide blocks, there is sufficient space around the sample to use the aperture for diffraction and place an incident slit, radial collimators, and a neutron imaging camera close to the sample. Combination of the six-axis press and the collimation devices realized high-quality diffraction pattern with no contamination from the heater or the sample container surrounding the sample. This press constitutes a new tool for using neutron diffraction to study the structures of crystals and liquids under high pressures and temperatures.

  13. Six-axis multi-anvil press for high-pressure, high-temperature neutron diffraction experiments.

    Science.gov (United States)

    Sano-Furukawa, A; Hattori, T; Arima, H; Yamada, A; Tabata, S; Kondo, M; Nakamura, A; Kagi, H; Yagi, T

    2014-11-01

    We developed a six-axis multi-anvil press, ATSUHIME, for high-pressure and high-temperature in situ time-of-flight neutron powder diffraction experiments. The press has six orthogonally oriented hydraulic rams that operate individually to compress a cubic sample assembly. Experiments indicate that the press can generate pressures up to 9.3 GPa and temperatures up to 2000 K using a 6-6-type cell assembly, with available sample volume of about 50 mm(3). Using a 6-8-type cell assembly, the available conditions expand to 16 GPa and 1273 K. Because the six-axis press has no guide blocks, there is sufficient space around the sample to use the aperture for diffraction and place an incident slit, radial collimators, and a neutron imaging camera close to the sample. Combination of the six-axis press and the collimation devices realized high-quality diffraction pattern with no contamination from the heater or the sample container surrounding the sample. This press constitutes a new tool for using neutron diffraction to study the structures of crystals and liquids under high pressures and temperatures.

  14. Effect of oxidation on base liquids of oil and synthetic-based drilling fluids at high pressure and high temperatures

    Energy Technology Data Exchange (ETDEWEB)

    Shahbazi, K.; Mehta, S.A.; Moore, R.G.; Ursenbach, M.G. [Calgary Univ., AB (Canada)

    2005-07-01

    Diesels and distillates are used as a base liquid for most oil-based drilling fluids in conventional drilling and as the liquid phase in gasified liquids in some underbalanced drilling operations. They are also used as friction reducing agents to free stuck pipes. It is important to understand the true downhole rheological properties because they affect equivalent circulating density, hole cleaning, barite sag, surge/swab pressures during tripping, pump pressure and bit hydraulics. Also, gelation and high viscosity are major concerns, particularly at high temperatures. An experimental study was conducted to evaluate the effect of oxidation on some base liquids for oil-based and synthetic-based drilling fluids at high pressures and high temperatures. Gas and liquid phases were characterized and the solid phase was measured along with viscosity measurements at temperatures and pressures ranging from 20 to 152 degrees C at atmospheric pressures to 103.4 MPa. The viscosity of the liquid samples after aging was compared with that of corresponding fresh samples. The results indicate that the degree of oxidation plays an important role in increasing the sample viscosity. The increase in viscosity depends on temperature, and is more significant at low temperatures. Agitation of samples during aging with air resulted in increased amounts of solid precipitation while lowering the viscosity of the liquid phase. This study demonstrated that oxidation has an important influence on rheological properties of the oil, because it affects the mobility of the oil and therefore the recovery factor. 11 refs., 7 tabs., 22 figs.

  15. Study of Raman Spectroscopy on Phase Relations of CaCO3 at High Temperature and High Pressure

    Science.gov (United States)

    Li, M.; Zheng, H.; Duan, T.

    2006-05-01

    Laser Raman Spectroscopy was used to study phase relations between calcite I, calcite II and aragonite at high pressure and high temperature. The experiment was performed in an externally heated Basselt type diamond anvil cell (DAC). Natural calcite (calcite I) was used as starting mineral. The sample and a small chip of quartz were loaded in a cavity (300 μm in diameter and 250 μm in depth) in a rhenium gasket. The Na2CO3 aqueous solution of 1mol/L was also loaded as a pressure medium to yield hydrostatic pressure. The whole assembly was pressurized first and then heated stepwise to 400°C. Pressure and temperature in the chamber were determined by the shift of Raman band at 464 cm-1 of quartz and by NiCr-NiSi thermocouple, respectively. The Raman spectra were measured by a Renishaw 1000 spetrometer with 50 mW of 514.5nm argon-ion laser as the excitation light source. The slit width was 50 μm and the corresponding resolution was ±1 cm-1. From the experiments, we observed the phase transitions between calcite I and calcite II, calcite I and aragonite, calcite II and aragonite, respectively. Our data showed a negative slope for the boundary between calcite I and calcite II, which was similar to Bridgman's result, although Hess et al. gave a positive slope. The boundary with a negative slope for calcite II and aragonite was also defined, which had never been done before. And all these data can yield a more complete phase diagram of CaCO3 than the studies of Hess et al. and Suito et al.Reference:Bridgeman P. W.(1939) Journal: American Journal of Science, Vol. 237, p. 7-18Bassett W. A. et al. (1993) Journal: Review of Scientific Instruments, Vol. 64, p. 2340-2345Suito K. et al. (2001) Journal: American Mineralogist, Vol. 86, p. 997- 1002Hess N. J. et al. (1991) In A. K. Singh, Ed., Recent Trends in High Pressure Research; Proc. X IIIth AIRAPT International Conference on High Pressure Science and Technology, p. 236-241. Oxford & IBH Publishing Co. Pvt, Ltd., New

  16. Pre-drilling prediction techniques on the high-temperature high-pressure hydrocarbon reservoirs offshore Hainan Island, China

    Science.gov (United States)

    Zhang, Hanyu; Liu, Huaishan; Wu, Shiguo; Sun, Jin; Yang, Chaoqun; Xie, Yangbing; Chen, Chuanxu; Gao, Jinwei; Wang, Jiliang

    2018-02-01

    Decreasing the risks and geohazards associated with drilling engineering in high-temperature high-pressure (HTHP) geologic settings begins with the implementation of pre-drilling prediction techniques (PPTs). To improve the accuracy of geopressure prediction in HTHP hydrocarbon reservoirs offshore Hainan Island, we made a comprehensive summary of current PPTs to identify existing problems and challenges by analyzing the global distribution of HTHP hydrocarbon reservoirs, the research status of PPTs, and the geologic setting and its HTHP formation mechanism. Our research results indicate that the HTHP formation mechanism in the study area is caused by multiple factors, including rapid loading, diapir intrusions, hydrocarbon generation, and the thermal expansion of pore fluids. Due to this multi-factor interaction, a cloud of HTHP hydrocarbon reservoirs has developed in the Ying-Qiong Basin, but only traditional PPTs have been implemented, based on the assumption of conditions that do not conform to the actual geologic environment, e.g., Bellotti's law and Eaton's law. In this paper, we focus on these issues, identify some challenges and solutions, and call for further PPT research to address the drawbacks of previous works and meet the challenges associated with the deepwater technology gap. In this way, we hope to contribute to the improved accuracy of geopressure prediction prior to drilling and provide support for future HTHP drilling offshore Hainan Island.

  17. Impact of different water activities (a w) adjusted by solutes on high pressure high temperature inactivation of Bacillus amyloliquefaciens spores.

    Science.gov (United States)

    Sevenich, Robert; Reineke, Kai; Hecht, Philipp; Fröhling, Antje; Rauh, Cornelia; Schlüter, Oliver; Knorr, Dietrich

    2015-01-01

    Much research has been conducted to comprehend the mechanisms of high pressure (HP) inactivation of spores in aqueous systems but for food model systems these information are scarce. In these systems spores can interact with ingredients which then could possibly lead to retarded or reduced inactivation, which can cause a problem for the sterilization process. The protective mechanism of a reduced a w-value is still unclear. HP processing might prove valuable to overcome protective effects of solutes and achieve shorter process times for sterilization under HP. To gain insight into the underlying mechanisms five a w-values (0.9, 0.92, 0.94, 0.96, 1) were adjusted with two different solutes (NaCl, sucrose). Solutions were inoculated with spores of Bacillus amyloliquefaciens and treated at 105, 110, and 115°C at 600 MPa. Further a thermal inactivation was conducted at the same temperatures for a comparison with the HP data. Afterward, the influence of HP high temperature treatment on the inactivation, the dipicolinic acid (DPA)-release and membrane constitution was assessed by plate count, HPLC and flow cytometry (FCM). The results show that during HP treatments sucrose and salt both have a protective effect, in which the influence of sucrose on the retarded inactivation is higher. The threshold water activities (a w), which is 0.94, here salt and sucrose have a significant influence on the inactivation. The comparison of thermal (105-115°C) and HP and high temperature (600 MPa, 105-115°C) treated samples showed that the time needed to achieve a 4-5 log10 inactivation is reduced from 45 (a w = 1) to 75 (a w = 0.9) min at 105°C to 3 (a w = 1) to 15 (a w = 0.9) minutes at 600 MPa and 105°C. The release of DPA is the rate limiting step of the inactivation and therefore monitoring the release is of great interest. The DPA-release is slowed down in high concentrated solutions (e.g., sucrose, salt) in comparison to a w 1. Since there is a difference in the way the

  18. Rapid high-temperature metamorphism of East Pacific Rise gabbros from Hess Deep

    Science.gov (United States)

    Manning, Craig E.; Weston, Patricia E.; Mahon, Keith I.

    1996-10-01

    Metamorphosed oceanic gabbros provide a record of the cooling history of the lower crust near mid-ocean ridges, but the temperature range, rate, and location of subsolidus events are poorly known. We combine hornblende-plagioclase thermometry, statistical analysis, and thermal models to estimate precisely the temperature, time, distance from axis, and duration of metamorphism in East Pacific Rise gabbros from Hess Deep, ODP Hole 894G. Metamorphic hornblende and plagioclase, which formed during microfracturing and sea water penetration, equilibrated at a mean temperature of 716 ± 8°C (90% confidence level). Comparison of the properties of the observed temperature distribution with those of model events indicates that metamorphism spanned ≤ 60°C. When combined with thermal models of fast-spreading centers, this implies that metamorphism was rapid (≤ 6000 yr) and occurred 1-4 km off axis. Application of this approach to other gabbros will allow comparison of spatial and temporal characteristics of deformation and fluid flow in the lower oceanic crust as a function of ridge setting.

  19. Deformation of Lawsonite at High Pressure and High Temperature - Implications for Low Velocity Layers in Subduction Zones

    Science.gov (United States)

    Amiguet, E.; Hilairet, N.; Wang, Y.; Gillet, P.

    2014-12-01

    During subduction, the hydrated oceanic crust undergoes a series of metamorphic reactions and transform gradually to blueschists and eclogite at depths of 20-50 km. Detailed seismic observations of subduction zones suggest a complex layered structure with the presence of a Low Velocity Layer (LVL) related to the oceanic crust [1] persisting to considerable depths (100- 250 km).While the transformation from blueschist to eclogite [2] and the presence of glaucophane up to 90-100 km [3] could explain some of these observations, the presence of LVL at greater depths could be related to the presence of the hydrous mineral lawsonite (CaAl2(Si2O7)(OH)2 H2O). Its stability field extends to 8.5 GPa and 1100K corresponding to depths up to 250 km in cold hydrous part of subducting slabs [4]. Because these regions undergo large and heterogeneous deformation, lawsonite plasticity and crystal preferred orientation (CPOs) may strongly influence the dynamic of subduction zones and the seismic properties. We present a deformation study at high presssure and high temperature on lawsonite. Six samples were deformed at 4-10 GPa and 600K to 1000K using a D-DIA apparatus [5] at 13-BMD at GSECARS beamline, APS, in axial compression up to 30% deformation with strain rates of 3.10-4s-1 to 6.10-6s-1. We measured in-situ lattice strains (a proxy for macroscopic stress), texture and strain using synchrotron radiations and calculated the macroscopic stress using lawsonite elastic properties [6]. Results from lattice strain analysis show a dependence of flow stress with temperature and strain rate. Texture analysis coupled with transmission electron microscopy showed that dislocation creep is the dominant deformation mechanism under our deformation conditions. [1] Abers, Earth and Planetary Science Letters, 176, 323-330, 2000 [2] Helffrich et al., Journal of Geophysical Research, 94, 753-763, 1989 [3] Bezacier et al., Tectonophysics, 494, 201-210, 2010 [4] Schmidt & Poli, Earth and Planetary

  20. Investigation of the rate-controlling mechanism(s) for high temperature creep and the relationship between creep and melting by use of high pressure as a variable

    Energy Technology Data Exchange (ETDEWEB)

    1991-01-01

    Using high pressure as a variable, the rate-controlling mechanism for high temperature creep and the relationship between creep and melting is investigated for silicon and nickel. An apparatus is used in which the samples are heated to melting point and subjected to 1 to 3 GigaPascal pressure. The stress behavior of the materials are then studied.

  1. Combined high-pressure and high-temperature vibrational studies of dolomite: phase diagram and evidence of a new distorted modification

    Science.gov (United States)

    Efthimiopoulos, I.; Jahn, S.; Kuras, A.; Schade, U.; Koch-Müller, M.

    2017-07-01

    A combined high-pressure mid-infrared absorption and Raman spectroscopy study on a natural CaMg0.98Fe0.02(CO3)2 dolomite sample was performed both at ambient and high temperatures. A pressure-temperature phase diagram was constructed for all the reported dolomite ambient- and high-pressure polymorphs. In addition, a local distortion of the ambient-pressure dolomite structure was identified close to 11 GPa, just before the transition toward the first known high-pressure phase. All the Clausius-Clapeyron slopes are found to be positive with similar magnitudes. Complementary first-principles calculations suggest a metastable nature of the high-pressure dolomite polymorphs. Finally, theoretical spectroscopy is used to interpret and discuss the observed changes in the measured vibrational spectra.

  2. Enhancement of yield point at high pressure high temperature wells by using polymer nanocomposites based on ZnO & CaCO3 nanoparticles

    Directory of Open Access Journals (Sweden)

    A.Z. Noah

    2017-03-01

    Full Text Available Zinc oxide nanoparticles (ZnO-NPs and modified calcium carbonate (nano-CaCO3 nanoparticles were successfully prepared and added to polystyrene-butadiene rubber copolymer (PSBR matrix to prepare PSBR nanocomposites. The prepared nanomaterials (ZnO-NPs & nano-CaCO3 were characterized using scanning electron microscope (SEM, transmission electron microscope (TEM and X-ray diffraction (XRD. Furthermore, the prepared polymer nanocomposites and oil base mud were used for drilling in high pressure high temperature (HPHT wells. The consequence of using polymer nanocomposites based on different loading of ZnO-NPs and nano-CaCO3 on the rheological properties of oil base mud was evaluated and enhanced the yield point at high pressure high temperature wells (HPHT. The using of the polymer with different percentage from (0.5 in all percent the obtained results is very promising; this means that the increase of polymer is reasonable for the increase of apparent viscosity, plastic viscosity and yield point at high temperature. Correspondingly, polymer nanocomposites displayed rise of apparent viscosity, plastic viscosity, and yield point, decreased in fluid loss and increased in electrical stability at high pressure high temperature wells.

  3. Silicate darkening in the Kobe CK Chondrite: Evidence for shock metamorphism at high temperature

    Science.gov (United States)

    Tomeoka, Kazushige; Ohnishi, Ichiro; Nakamura, Noboru

    2001-11-01

    The Kobe CK4 chondrite, like most metamorphosed CK chondrites, exhibits pronounced silicate darkening of matrix and chondrule mesostases. Our petrographic and scanning electron microscopic study reveals that the matrix of Kobe consists mostly of intermixtures of two types of fine-grained olivine. One forms subhedral to anhedral normal crystals. The other fills interstices of the subhedral to anhedral olivine crystals, exhibiting a complex network of veinlets. The latter type of olivine contains high densities of small spherical vesicles (chlorapatite. The vesicular olivine is particularly abundant in regions of matrix that exhibit a relatively high degree of darkening and commonly fills chondrule mesostases. The vesicular olivine is clearly the principal cause of the silicate darkening in Kobe. The internal texture of the vesicular olivine closely resembles those of local melts produced from the matrices of experimentally and naturally shocked carbonaceous chondrites. The occurrence and texture of the vesicular olivine suggest that it resulted from recrystallization of partially melted matrix olivine by shock. Kobe exhibits light shock effects in olivine that are consistent with shock stage S2 that is too low to explain the occurrence of olivine melting. We suggest that the vesicular olivine in Kobe was produced by shock metamorphism at a relatively mild shock pressure (600 °C). Thus, it is probable that the shock effects in olivine, manifest as fracturing and deformation, were relatively minor, but heating was strong enough to cause partial melting of matrix olivine.

  4. High-pressure high-temperature experiments: Windows to the Universe; Experimentos a alta presion y alta temperatura: Ventanas al universo

    Energy Technology Data Exchange (ETDEWEB)

    Santaria-Perez, D.

    2011-07-01

    From Earth compositional arguments suggested by indirect methods, such as the propagation of seismic waves, is possible to generate in the laboratory pressure and temperature conditions similar to those of the Earth or other planet interiors and to study how these conditions affect to a certain metal or mineral. These experiments are, therefore, windows to the Universe. The aim of this chapter is to illustrate the huge power of the experimental high-pressure high-temperature techniques and give a global overview of their application to different geophysical fields. Finally, we will introduce the MALTA Consolider Team, which gather most of the Spanish high-pressure community, and present their available high-pressure facilities. (Author) 28 refs.

  5. Protolith ages and timing of peak and retrograde metamorphism of the high-pressure granulites in the Shandong Peninsula, eastern North China Craton

    Directory of Open Access Journals (Sweden)

    Pinghua Liu

    2012-11-01

    Full Text Available High-pressure (HP granulites widely occur as enclaves within tonalite-trondhjemite-granodiorite (TTG gneisses of the Early Precambrian metamorphic basement in the Shandong Peninsula, southeast part of the North China Craton (NCC. Based on cathodoluminescence (CL, laser Raman spectroscopy and in-situ U-Pb dating, we characterize the zircons from the HP granulites and group them into three main types: inherited (magmatic zircon, HP metamorphic zircon and retrograde zircon. The inherited zircons with clear or weakly defined magmatic zoning contain inclusions of apatites, and 207Pb/206Pb ages of 2915–2890 Ma and 2763–2510 Ma, correlating with two magmatic events in the Archaean basement. The homogeneous HP metamorphic zircons contain index minerals of high-pressure metamorphism including garnet, clinopyroxene, plagioclase, quartz, rutile and apatite, and yield 207Pb/206Pb ages between 1900 and 1850 Ma, marking the timing of peak HP granulite facies metamorphism. The retrograde zircons contain inclusions of orthopyroxene, plagioclase, quartz, apatite and amphibole, and yield the youngest 207Pb/206Pb ages of 1840–1820 Ma among the three groups, which we correlate to the medium to low-pressure granulite facies retrograde metamorphism. The data presented in this study suggest subduction of Meso- and Neoarchean magmatic protoliths to lower crust depths where they were subjected to HP granulite facies metamorphism during Palaeoproterozoic (1900–1850 Ma. Subsequently, the HP granulites were exhumated to upper crust levels, and were overprinted by medium to low-pressure granulite and amphibolite facies retrograde event at ca. 1840–820 Ma.

  6. Petrographical Evidence for Ultra High Temperature Metamorphism from Sapphirine-bearing Granulites; the Central Highland Complex Sri Lanka

    Science.gov (United States)

    Dharmapriya, P. L.; Malaviarachchi, S.

    2013-05-01

    Extreme crustal metamorphism at temperatures of 900-1150 0C generates rocks with specific mineralogical characteristics termed as ultra high temperature (UHT) granulites. UHT conditions have been derived and inferred from Sapphirine-bearing granulites throughout the world including Sri Lanka. In this study we put forward petrographical evidence for UHT metamorphism observed in thin sections of four types of sapphirine-bearing granulites. Sapphirine (Spr), Kayanite (Ky) (?) and Spinel (Spl) bearing Garnet (Grt)- Orthopyroxene (Opx)-Sillimanite (Sil)-Cordiarite (Cord)-Biotite (Bt) gneiss (Rock A) collected from quarry close to Gampola where the rock is occurred as a layer within Sapphirine bearing Grt-Opx-Sil- Bt gneiss (Rock B). In Rock A, anhedral Spr grains are founded in two phases; as inclusion with in core area of porphyroblastic Grt and within the Quartz (Qtz) saturated matrix. Former type is coexisting with Ky (?) while later types where Spr grain close to Grt porpyroblasts associated with Plagioclase (Plag)-Opx and Spr grain away from garnets are coexisting with K-feldspar and Plag. There are plenty of retrograde Opx+Sil+Cord intergrowth in the matrix of Rock A could be the Spr+Qtz brake down product after the peak metamorphism via the reaction Spr+Qtz=Opx+Sil+Qtz. In Rock B, Spr comprise as inclusion within Grt as mono-phase. Multiple modes of occurrences of Opx-Sil-Qtz assemblage can also be observed in both Rocks A and B enhance that the rocks have been evolved through UHT conditions. Spr, Spl and Sil bearing Grt-Opx-Bt gneiss (Rock C) was collected from a quarry close Kotmale where the rock is occur as a thin layer within a massive charnockite. The Rock C contains medium grained Grt porphyroblasts in which Spr, Spl, Sil, Rutile, Qtz and Bt occur as rare inclusions as either monophase or multiphase assemblages. Spr and Spl have coexisted with tiny mineral which shows inclined extinction and low order birefringence it is very difficult to identify. Based

  7. Stability of rhombohedral phases in vanadium at high-pressure and high-temperature: first-principles investigations

    CERN Document Server

    Wang, Yi X; Chen, Xiang R; Geng, Hua Y

    2016-01-01

    The pressure-induced transition of vanadium from BCC to rhombohedral structures is unique and intriguing among transition metals. In this work, the stability of these phases is revisited by using density functional theory. At finite temperatures, a novel transition of rhombohedral phases back to BCC phase induced by thermal electrons is discovered. This reentrant transition is found not driven by phonons, instead it is the electronic entropy that stabilizes the latter phase, which is totally out of expectation. Parallel to this transition, we find a peculiar and strong increase of the shear modulus C44 with increasing temperature. It is counter-intuitive in the sense that it suggests an unusual harding mechanism of vanadium by temperature. With these stability analyses, the high-pressure and finite-temperature phase diagram of vanadium is proposed. Furthermore, the dependence of the stability of RH phases on the Fermi energy and chemical environment is investigated. The results demonstrate that the position o...

  8. Boron isotope study of high-pressure metamorphic rocks from Syros (Greece) by secondary ion mass spectrometry (SIMS)

    Science.gov (United States)

    Marschall, H.; Altherr, R.; Ludwig, T.; Kalt, A.

    2003-04-01

    The Heidelberg Cameca ims-3f ion probe has been modified in order to measure δ11B values with a precision of ±1 ppm (2σ) in tourmaline, ±2 ppm in phengite (≈100 μg/g B), and ±4 ppm in other minerals (2--10 μg/g B). Three tourmaline standards (98144 elbaite, 112566 schorl and 108796 dravite; [1]) of different chemical compositions were used to correct for instrumental mass fractionation. This newly established equipment has been used to determine the isotopic ratios of boron (11B/10B) in minerals of Eocene high-pressure rocks from the island of Syros, Greece, for which metamorphic peak conditions of ˜470^oC and 1.5 GPa have been estimated [e.g. 2]. The rocks examined represent different parts of former oceanic crust and occur as eclogites, mafic blueschists, metagabbros, talc-chlorite-actinolite schists or serpentinites. Two types of tourmaline were recognized within the rocks [3]. Type I are small grains (100 μm) with dravite cores and schorl rims, forming inclusions in garnet, glaucophane or phengite. Type II are large grains (10 mm) with very weak zonations occurring within reaction zones between eclogites and serpentinites. Type I shows strong isotopic zonations with light cores of δ11B = -4 ppm and heavy rims of δ11B = +8 ppm. Despite their large grain size, Type II tourmalines show very homogenous isotopic compositions, varying randomly by ±1 ppm over whole grains. Isotopic composition of type II tourmalines were found to be extremely heavy and range from +19 ppm to +22 ppm among different samples. Preliminary results on coexisting phengite, chlorite and glaucophane show significant fractionation between tourmaline and other silicates, with the latter being more than 10 ppm lighter. The heavy isotopic composition of type II tourmaline, formed at depth of approx. 50 km, reflects boron-rich fluids that migrated through the rocks during subduction and early exhumation. They are direct evidence for very high d11B values (>+20 ppm) of subduction

  9. High temperatures and high pressures Brillouin scattering studies of liquid H(2)O+CO(2) mixtures.

    Science.gov (United States)

    Qin, Junfeng; Li, Min; Li, Jun; Chen, Rongyan; Duan, Zhenhao; Zhou, Qiang; Li, Fangfei; Cui, Qiliang

    2010-10-21

    The Brillouin scattering spectroscopy studies have been conducted in a diamond anvil cell for a liquid mixtures composed of 95 mol % H(2)O and 5 mol % CO(2) under high temperatures and pressures. The sound velocity, refractive index, density, and adiabatic bulk modulus of the H(2)O+CO(2) mixtures were determined under pressures up to the freezing point at 293, 453, and 575 K. It is found from the experiment that sound velocities of the liquid mixture are substantially lower than those of pure water at 575 K, but not at lower temperatures. We presented an empirical relation of the density in terms of pressure and temperature. Our results show that liquid H(2)O+CO(2) mixtures are more compressible than water obtained from an existing equation of state of at 453 and 575 K.

  10. Polytypes and twins in the diamond-lonsdaleite system formed by high-pressure and high-temperature treatment of graphite.

    Science.gov (United States)

    Kulnitskiy, Boris; Perezhogin, Igor; Dubitsky, Gennady; Blank, Vladimir

    2013-10-01

    As a result of the high-temperature and high-pressure treatment of graphite we obtained a powder containing diamond and lonsdaleite. The structure and properties of the powder were studied by transmission electron microscopy (TEM) and electron energy-loss spectroscopy (EELS). It was found that the synthesized material contains not only diamond nanoparticles, but also some relatively large (up to several nanometers) fragments of lonsdaleite. 4H and 6H polytypes were found in some of the diamond particles. Incoherent twin boundaries were observed in the diamond particle containing fragments of lonsdaleite.

  11. Evaluation of Fungal Growth on Olive-Mill Wastewaters Treated at High Temperature and by High-Pressure Homogenization

    Directory of Open Access Journals (Sweden)

    Francesca Cibelli

    2017-12-01

    Full Text Available Reuse of olive mill wastewaters (OMWWs in agriculture represents a significant challenge for health and safety of our planet. Phytotoxic compounds in OMWW generally prohibit use of untreated OMWWs for agricultural irrigation or direct discharge into surface waters. However, pretreated OMWW can have positive effects on chemical and microbiological soil characteristics, to fight against fungal soil-borne pathogens. Low amounts of OMWW following thermal (TT-OMWW and high-pressure homogenization (HPH-OMWW pretreatments counteracted growth of some of 12 soil-borne and/or pathogenic fungi examined. With fungal growth measured as standardized change in time to half maximum colony diameter, Δτ, overall, HPH-OMWW showed increased bioactivity, as increased mean Δτ from 3.0 to 4.8 days. Principal component analysis highlighted two fungal groups: Colletotrichum gloeosporioides, Alternaria alternata, Sclerotium rolfsii, and Rosellinia necatrix, with growth strongly inhibited by the treated OMWWs; and Aspergillus ochraceus and Phaeoacremonium parasiticum, with stimulated growth by the treated OMWWs. As a non-thermal treatment, HPH-OMWW generally shows improved positive effects, which potentially arise from preservation of the phenols.

  12. Computational Mechanics of Bridgmanite at High-Pressure, High-temperature and as a Function of Strain-Rate

    Science.gov (United States)

    Carrez, P.; Kraych, A.; Hirel, P.; Cordier, P.

    2015-12-01

    It is widely accepted that bridgmanite is the most abundant mineral of the Earth's mantle. Therefore, the convective flow and the seismic properties of the Earth's deep mantle should depend strongly on the mechanical and physical properties of this mineral. Nowadays, atomic scale modelling of dislocation properties appears as one of the possible route to accurately infer the plastic behaviour of high pressure minerals. In this study, we propose a theoretical modelling of dislocation glide in the easiest slip systems in MgSiO3 perovskite taking into account the influence of pressure and the effect of temperature. We focus on [100](010) and [010](100) slip systems and develop a multi scale model based on atomistic calculations to evaluate the mobility of dislocation under the conjugate action of stress and temperature and at various strain-rates. In particular, we show how numerical techniques such as Nudged Elastic Band are useful to evaluate the intermediate atomistic configurations which control lattice friction. Finally, we show that our model enables to calculate the strength of MgSiO3, either under laboratory conditions to compare with experimental data or under mantle strain rates.

  13. Optimized High Temperature PEM Fuel Cell & High Pressure PEM Electrolyser for Regenerative Fuel Cell Systems in GEO Telecommunication Satellites

    Directory of Open Access Journals (Sweden)

    Farnes Jarle

    2017-01-01

    Full Text Available Next generation telecommunication satellites will demand increasingly more power. Power levels up to 50 kW are foreseen for the next decades. Battery technology that can sustain up to 50 kW for eclipse lengths of up to 72 minutes will represent a major impact on the total mass of the satellite, even with new Li-ion battery technologies. Regenerative fuel cell systems (RFCS were identified years ago as a possible alternative to rechargeable batteries. CMR Prototech has investigated this technology in a series of projects initiated by ESA focusing on both the essential fuel cell technology, demonstration of cycle performance of a RFCS, corresponding to 15 years in orbit, as well as the very important reactants storage systems. In the last two years the development has been focused towards optimising the key elements of the RFCS; the HTPEM fuel cell and the High Pressure PEM electrolyser. In these ESA activities the main target has been to optimise the design by reducing the mass and at the same time improve the performance, thus increasing the specific energy. This paper will present the latest development, including the main results, showing that significant steps have been taken to increase TRL on these key components.

  14. High-pressure, high-temperature deformation of dunite, eclogite, clinopyroxenite and garnetite using in situ X-ray diffraction

    Science.gov (United States)

    Farla, R.; Rosenthal, A.; Bollinger, C.; Petitgirard, S.; Guignard, J.; Miyajima, N.; Kawazoe, T.; Crichton, W. A.; Frost, D. J.

    2017-09-01

    The rheology of eclogite, garnetite and clinopyroxenite in the peridotitic upper mantle was experimentally investigated in a large volume press combined with in situ synchrotron X-ray diffraction techniques to study the impact on mantle convection resulting from the subduction of oceanic lithosphere. Experiments were carried out over a range of constant strain rates (2 ×10-6- 3 ×10-5 s-1), pressures (4.3 to 6.7 GPa) and temperatures (1050 to 1470 K). Results show substantial strength variations among eclogitic garnet and clinopyroxene and peridotitic olivine. At low temperatures (1400 K) eclogite is weaker than dunite by 0.2 GPa or more. Garnetite and clinopyroxenite exhibit higher strength than dunite at approximately 1200 K. However, at higher temperature (1370 K), clinopyroxenite is significantly weaker than garnetite (and dunite) by more than a factor of five. We explain these observations by transitions in deformation mechanisms among the mineral phases. In clinopyroxene, high temperature dislocation creep resulting in a strength reduction replaces low temperature twinning. Whereas garnet remains very rigid at all experimental conditions when nominally anhydrous ('dry'). Microstructural observations show phase segregation of clinopyroxene and garnet, development of a crystallographic and shape preferred orientation in the former but not in the latter, suggesting an overall weak seismic anisotropy. Detection of eclogite bodies in the peridotite-dominated mantle may only be possible via observation of high VP /VS1 ratios. A comparable or weaker rheology of eclogite to dunite suggests effective stirring and mixing of eclogite in the convecting mantle.

  15. High-pressure and high-temperature synthesis of rhenium carbide using rhenium and nanoscale amorphous two-dimensional carbon nitride

    Directory of Open Access Journals (Sweden)

    Nozomu Yasui

    2015-12-01

    Full Text Available Both Re2C and Re2N are ultra incompressible and have a bulk modulus of about 400 GPa. These materials are synthesized under high pressure and high temperature. The synthesis pressures are about 10 GPa or below for Re2C and 20–30 GPa for Re2N. If the synthesis pressure of Re2N was about 10 GPa or below, a large volume high-pressure cell like a multi-anvil apparatus can be used to synthesize Re2N. To realize this, a proper solid nitrogen source is needed instead of liquid or gas nitrogen. We used a precursor of a mixture of rhenium and home-made nanoscale amorphous two-dimensional carbon nitride as a solid nitrogen source. Consequently, the synthesis reaction produced Re2C but not Re2N. We characterized the synthesized Re2C by various techniques including high-pressure x-ray diffraction (XRD. The bulk modulus B0 of the synthesized Re2C under hydrostatic conditions was estimated to be 385.7 ± 18.0 GPa. This value is a little smaller than the previous data. When the pressure medium became non-hydrostatic, the peculiar compression behaviour occurred; the rate of broadening of XRD lines increased and the compression became negligible in the range of a few GPa. The reason for this peculiar behaviour is not known.

  16. Simultaneous high-pressure high-temperature elastic velocity measurement system up to 27 GPa and 1873 K using ultrasonic and synchrotron X-ray techniques

    Science.gov (United States)

    Higo, Yuji; Irifune, Tetsuo; Funakoshi, Ken-ichi

    2018-01-01

    A new pulse-echo interferometry system has been developed for measurements of sound velocity at simultaneous high pressure and temperature corresponding to those of the Earth's lower mantle, using synchrotron X-ray techniques at SPring-8. A combination of a low-noise high-frequency amplifier and a high-speed solid-state relay system allowed us to clearly detect the ultrasonic echoes of a small sample (<1.0 mm in diameter and length) in multi-anvil apparatus. A new high-pressure cell has also been introduced for precise measurement of the length of the tiny sample by X-ray radiography imaging under very high pressure and temperature. The new system was tested by measuring elastic velocities of α-Al2O3 over wide pressure and temperature ranges of up to 27 GPa and 1873 K, respectively. The resultant adiabatic bulk modulus, shear modulus, and pressure and temperature derivatives of α-Al2O3 are K0S = 251.2 (18) GPa, ∂ KS/∂ P = 4.21 (10), ∂ KS/∂ T = -0.025 (1), G = 164.1 (7), ∂ G/∂ P = 1.59 (3), ∂ G/∂ T = -0.021 (1). These values are consistent with those previously reported based on experiments at high temperatures at ambient pressure and high pressures at room temperature. The present system allows precise measurements of the elastic velocities of minerals under the pressures and temperatures corresponding to the lower mantle for the first time, which should greatly contribute to our understanding of mineralogy of the whole mantle.

  17. New high-pressure and high-temperature metal/silicate partitioning of U and Pb: Implications for the cores of the Earth and Mars

    Energy Technology Data Exchange (ETDEWEB)

    Malavergne, V. [Lunar and Planetary Inst, Houston, TX (United States); Malavergne, V.; Tarrida, M.; Combes, R. [Univ Marne La Vallee, Lab Geomat, F-77454 Marne La Vallee, (France); Bureau, H. [CEA Saclay, LPS, CEA-CNRS, F-91191 Gif Sur Yvette, (France); Jones, J. [NASA, Lyndon B Johnson Space Ctr, Houston, TX 77058 (United States); Schwandt, C. [Jacobs Sverdrup, ESCG, Houston, TX (United States)

    2007-07-01

    In order to quantify possible fractionation of U and Pb into a metallic core, we have performed piston cylinder and multi-anvil press experiments at high pressure (up to 20 GPa) and high temperature (up to 2400 degrees C) and obtained the distribution coefficient D(metal-silicate) and the exchange partition coefficient K(metal-silicate) for these elements between metal and silicates (mineral or liquid). D{sup Pb}(metal-silicate) and D{sup U}(metal-silicate) depend strongly on the S content of the metallic phase, and also on the oxygen fugacity, in agreement with an effective valence state of 4 for U in silicates and 2 for Pb in silicates. Kd{sup Pb}( metal-silicate) and Kd{sup U}(metal-silicate) show no discernable pressure and temperature trend. U remains lithophile even at high pressure and high temperature but its lithophile nature decreases at very low oxygen fugacity. From our experimental data, it was possible to calculate the U and Pb contents of the cores of Mars and Earth under core-mantle equilibrium conditions at high pressure and high temperature. From the D(metal-silicate) of the present study, we obtained that: 0.008 ppm {<=} Pb (in the core) {<=} 4.4 ppm, and 0.0003 ppb {<=} U (in the core) {<=} 0.63 ppb, depending on whether the metal is S-free or S-saturated respectively, and if the mantle was molten or solid during the segregation process of the Earth's core around {delta}IW-2. For Mars, based on a core segregation process around {delta}IW-1, we obtained that: 0.005 ppm {<=} Pb (in the core) {<=} 3 ppm, and 0.00002 ppb {<=} U (in the core) < 0.05 ppb, depending on the metallic composition: S-free or S-saturated respectively. Our results suggest that the low concentration of Pb in the terrestrial mantle could not be explained by an early Pb sequestration in the Earth's core even if S is the dominant light element of the core. If we assume a magma ocean scenario, U might produced a maximum value of 1.5% of the total heat budget of the core

  18. Raman scattering of 2H-MoS2 at simultaneous high temperature and high pressure (up to 600 K and 18.5 GPa

    Directory of Open Access Journals (Sweden)

    JianJun Jiang

    2016-03-01

    Full Text Available The Raman spectroscopy of natural molybdenite powder was investigated at simultaneous conditions of high temperature and high pressure in a heatable diamond anvil cell (DAC, to obtain the temperature and pressure dependence of the main Raman vibrational modes (E1g, E 2 g 1 ,A1g, and 2LA(M. Over our experimental temperature and pressure range (300–600 K and 1 atm−18.5 GPa, the Raman modes follow a systematic blue shift with increasing pressure, and red shift with increasing temperature. The results were calculated by three-variable linear fitting. The mutual correlation index of temperature and pressure indicates that the pressure may reduce the temperature dependence of Raman modes. New Raman bands due to structural changes emerged at about 3–4 GPa lower than seen in previous studies; this may be caused by differences in the pressure hydrostaticity and shear stress in the sample cell that promote the interlayer sliding.

  19. Thermodynamic Analysis about Nucleation and Growth of Cubic Boron Nitride Crystals in the hBN-Li3N System under High Pressure and High Temperature

    Directory of Open Access Journals (Sweden)

    Xiao-Fei Guo

    2015-02-01

    Full Text Available The nucleation of cubic boron nitride (cBN single crystals synthesized with lithium nitride (Li3N as a catalyst under high pressure and high temperature (HPHT was analyzed. Many nanometer-sized cubic boron nitride nuclei formed in the near surface layer, as detected by high resolution transmission electron microscopy. Based on the experiment results, the transformation kinetics is described by a nucleation and growth process in the thermodynamic stability region of cBN. A theoretical description is developed based on the heterogeneous nucleation and layer growth mechanism, and the relevant parameters are estimated and discussed. The critical crystal radius, r*, increases with the temperature under constant pressure; the change with temperature more pronounced at lower pressure (such as 4.5 GPa. The crystal growth velocity increased with the temperature, and it is parabolic with temperature under certain pressure. These results are consistent with experimental data.

  20. Fabrication of intermetallic NiAl by self-propagating high-temperature synthesis reaction using aluminium nanopowder under high pressure

    CERN Document Server

    Dong Shu Shan; Cheng Hai Yong; Yang Hai Bin; Zou Guang Tian

    2002-01-01

    By using aluminium nanopowder prepared by wire electrical explosion, pure monophase NiAl compound with fine crystallites (<=10 mu m) and good densification (98% of the theoretical green density) was successfully fabricated by means of self-propagating high-temperature synthesis (SHS) under a high pressure of 50 MPa. Investigation shows that, due to the physical and chemical characteristics of the nanoparticles, the SHS reaction mode and mechanism are distinct from those when using conventional coarse-grained reactants. The SHS reaction process depends on the thermal conditions related to pressure and can occur at a dramatically low temperature of 308 sup o C, which cannot be expected in conventional SHS reaction. With increasing pressure, the SHS explosive ignition temperature (T sub i sub g) of forming NiAl decreases due to thermal and kinetic effects.

  1. Apparatus for the investigation of high-temperature, high-pressure gas-phase heterogeneous catalytic and photo-catalytic materials

    Science.gov (United States)

    Alvino, Jason F.; Bennett, Trystan; Kler, Rantej; Hudson, Rohan J.; Aupoil, Julien; Nann, Thomas; Golovko, Vladimir B.; Andersson, Gunther G.; Metha, Gregory F.

    2017-05-01

    A high-temperature, high-pressure, pulsed-gas sampling and detection system has been developed for testing new catalytic and photocatalytic materials for the production of solar fuels. The reactor is fitted with a sapphire window to allow the irradiation of photocatalytic samples from a lamp or solar simulator light source. The reactor has a volume of only 3.80 ml allowing for the investigation of very small quantities of a catalytic material, down to 1 mg. The stainless steel construction allows the cell to be heated to 350 °C and can withstand pressures up to 27 bar, limited only by the sapphire window. High-pressure sampling is made possible by a computer controlled pulsed valve that delivers precise gas flow, enabling catalytic reactions to be monitored across a wide range of pressures. A residual gas analyser mass spectrometer forms a part of the detection system, which is able to provide a rapid, real-time analysis of the gas composition within the photocatalytic reaction chamber. This apparatus is ideal for investigating a number of industrially relevant reactions including photocatalytic water splitting and CO2 reduction. Initial catalytic results using Pt-doped and Ru nanoparticle-doped TiO2 as benchmark experiments are presented.

  2. Stable solid and aqueous H2CO3 from CO2 and H2O at high pressure and high temperature

    Science.gov (United States)

    Wang, Hongbo; Zeuschner, Janek; Eremets, Mikhail; Troyan, Ivan; Willams, Jonathan

    2016-01-01

    Carbonic acid (H2CO3) forms in small amounts when CO2 dissolves in H2O, yet decomposes rapidly under ambient conditions of temperature and pressure. Despite its fleeting existence, H2CO3 plays an important role in the global carbon cycle and in biological carbonate-containing systems. The short lifetime in water and presumed low concentration under all terrestrial conditions has stifled study of this fundamental species. Here, we have examined CO2/H2O mixtures under conditions of high pressure and high temperature to explore the potential for reaction to H2CO3 inside celestial bodies. We present a novel method to prepare solid H2CO3 by heating CO2/H2O mixtures at high pressure with a CO2 laser. Furthermore, we found that, contrary to present understanding, neutral H2CO3 is a significant component in aqueous CO2 solutions above 2.4 GPa and 110 °C as identified by IR-absorption and Raman spectroscopy. This is highly significant for speciation of deep C-O-H fluids with potential consequences for fluid-carbonate-bearing rock interactions. As conditions inside subduction zones on Earth appear to be most favorable for production of aqueous H2CO3, a role in subduction related phenomena is inferred.

  3. Apparatus for the investigation of high-temperature, high-pressure gas-phase heterogeneous catalytic and photo-catalytic materials.

    Science.gov (United States)

    Alvino, Jason F; Bennett, Trystan; Kler, Rantej; Hudson, Rohan J; Aupoil, Julien; Nann, Thomas; Golovko, Vladimir B; Andersson, Gunther G; Metha, Gregory F

    2017-05-01

    A high-temperature, high-pressure, pulsed-gas sampling and detection system has been developed for testing new catalytic and photocatalytic materials for the production of solar fuels. The reactor is fitted with a sapphire window to allow the irradiation of photocatalytic samples from a lamp or solar simulator light source. The reactor has a volume of only 3.80 ml allowing for the investigation of very small quantities of a catalytic material, down to 1 mg. The stainless steel construction allows the cell to be heated to 350 °C and can withstand pressures up to 27 bar, limited only by the sapphire window. High-pressure sampling is made possible by a computer controlled pulsed valve that delivers precise gas flow, enabling catalytic reactions to be monitored across a wide range of pressures. A residual gas analyser mass spectrometer forms a part of the detection system, which is able to provide a rapid, real-time analysis of the gas composition within the photocatalytic reaction chamber. This apparatus is ideal for investigating a number of industrially relevant reactions including photocatalytic water splitting and CO2 reduction. Initial catalytic results using Pt-doped and Ru nanoparticle-doped TiO2 as benchmark experiments are presented.

  4. Self-diffusion in supercritical water and benzene in high-temperature high-pressure conditions studied by NMR and dynamic solvation-shell model

    Science.gov (United States)

    Yoshida, Ken; Matubayasi, Nobuyuki; Uosaki, Yasuhiro; Nakahara, Masaru

    2010-03-01

    The self-diffusion coefficients of water and organic solvents in the high-temperature high-pressure conditions are studied by using high-temperature NMR and MD simulation methods. The experimental results are analyzed using a scheme based on the solvation shell relaxation time obtained by MD simulation. The dynamic effect of hydrogen bonding is discussed through the comparison between water and a nonpolar organic solvent, benzene, over a wide range of density and temperature. The hydrogen-bonding effects are as follows: (1) the self-diffusion coefficient of water depends on density more weakly than that of benzene, (2) the self-diffusion coefficient of water at the ambient density depends on temperature more strongly than that of benzene at the density, (3) the turnover from the mobile-shell type to the in-shell type with increasing density does not occur in supercritical water up to the ambient density, whereas such turnover is observed in benzene. These contrasts are reflecting the dynamic effect of the anisotropic attractive interactions.

  5. High Temperature, High Pressure Equation of State: Solidification of Hydrocarbons and Measurement of Krytox Oil Using Rolling-Ball Viscometer Validation

    Energy Technology Data Exchange (ETDEWEB)

    Gamwo, Isaac K. [National Energy Technology Lab. (NETL), Pittsburgh, PA, (United States); Burgess, Ward [National Energy Technology Lab. (NETL), Pittsburgh, PA, (United States); Tapriyal, Deepak [National Energy Technology Lab. (NETL), Pittsburgh, PA, (United States)

    2014-10-03

    The global consumption of oil and gas continues to rise and has led to the search and recovery of petroleum sources from reservoirs exhibiting increasingly high-temperature, high-pressure conditions. For example, ultra-deep petroleum formations found at depths of approximately 5 km or more, can exhibit pressure and temperature values as high as 240 MPa (35,000 psi) and 533 K (260°C). The hydrocarbons produced from these ultra-deep formations experience significant decreases in temperature and pressure from reservoir to platform conditions. Hence, it is highly desirable to develop accurate equation of state models (EOS) and fluid properties databases that covers the entire temperature and pressure ranges associated with this process to promote the efficient, safe, and environmentally responsible production from these reservoirs at extreme conditions. Currently available databases and EOS models are generally limited to approximately 69 MPa and do not correlate accurately when extrapolated to the extreme environments associated with ultra-deep reservoirs where temperatures can reach as high as 533 K and pressures up to 240 MPa. Despite recent exploration and production of petroleum from ultra-deep formations, there are major gaps in the databases for pure and mixture density and viscosity of hydrocarbons. These are the most important fluid properties that enable accurate booking of reserves as well as the design of size and equipment to safely bring these fluids to the platform. The overall objective of this project is to develop methodologies to provide crude oil thermodynamic and transport properties—including density, viscosity, and phase composition— at extreme temperature and pressure conditions. The knowledge of these crude oil properties reduces uncertainties associated with deep drilling and promotes safer and reliable access to domestic energy resources. This report is an extension of work reported in our first Technical Report Series (TRS) released

  6. Standard practice for evaluation of disbonding of bimetallic stainless alloy/steel plate for use in high-pressure, high-temperature refinery hydrogen service

    CERN Document Server

    American Society for Testing and Materials. Philadelphia

    2001-01-01

    1.1 This practice covers a procedure for the evaluation of disbonding of bimetallic stainless alloy/steel plate for use in refinery high-pressure/high-temperature (HP/HT) gaseous hydrogen service. It includes procedures to (1) produce suitable laboratory test specimens, (2) obtain hydrogen charging conditions in the laboratory that are similar to those found in refinery HP/HT hydrogen gas service for evaluation of bimetallic specimens exposed to these environments, and (3) perform analysis of the test data. The purpose of this practice is to allow for comparison of data among test laboratories on the resistance of bimetallic stainless alloy/steels to hydrogen-induced disbonding (HID). 1.2 This practice applies primarily to bimetallic products fabricated by weld overlay of stainless alloy onto a steel substrate. Most of the information developed using this practice has been obtained for such materials. The procedures described herein, may also be appropriate for evaluation of hot roll bonded, explosive bonded...

  7. High-pressure and high-temperature synthesis and study of the thermal properties of ZrW2O8/Cu composites

    Science.gov (United States)

    Li, Xin; Fang, Leiming; Chen, Bo; He, Duanwei

    2016-04-01

    ZrW2O8/Cu composites with high thermal conductivity and low coefficients of thermal expansion (CTE) are desired to be utilized in thermal management applications. The ZrW2O8/Cu composites were synthesized under high-pressure and high-temperature (HPHT) conditions and annealing method. We found that the thermal conductivity and CTE of the ZrW2O8/Cu composites could be controlled through suitable HPHT sintering. In addition, cyclic heating-cooling is crucial to recrystallize the composite and reduce the thermal mismatch stress to produce a composite with high thermal conductivity and a low CTE. Under HPHT (3 GPa, 500 °C) conditions and annealing at 700 °C, the thermal conductivity and CTE of the ZrW2O8/Cu composites have been determined directly to 165 W/(m k) and 6.8×10-6 K-1. Our results help to understand the structural origins of the high thermal conductivity and low CTE, and aid in designing ZrW2O8/Cu composites with improved performance.

  8. High-pressure mafic oceanic rocks from the Makbal Complex, Tianshan Mountains (Kazakhstan & Kyrgyzstan): Implications for the metamorphic evolution of a fossil subduction zone

    Science.gov (United States)

    Meyer, Melanie; Klemd, Reiner; Konopelko, Dmitry

    2013-09-01

    omphacite) due to an unfavorable alkali-poor bulk composition (Na2O < 1 wt.%). The four high-pressure mafic samples investigated in this study originated from oceanic crust (Zr/Hf ratio of 33 to 35) which contradicts all previous studies suggesting a continental protolith for all mafic HP/UHP rocks at Makbal. The present study indicates that the mafic high-pressure rocks represent incoherent segments of exhumed oceanic crust. Juxtaposition of different mafic oceanic (this study) and continental rocks is suggested to be due to buoyancy-driven exhumation of the metasedimentary host rock in the subduction channel where dismembered fragments of the subducted oceanic crust were captured in different depths.

  9. Effect of Chromium on Corrosion Behavior of P110 Steels in CO2-H2S Environment with High Pressure and High Temperature

    Science.gov (United States)

    Sun, Jianbo; Sun, Chong; Lin, Xueqiang; Cheng, Xiangkun; Liu, Huifeng

    2016-01-01

    The novel Cr-containing low alloy steels have exhibited good corrosion resistance in CO2 environment, mainly owing to the formation of Cr-enriched corrosion film. In order to evaluate whether it is applicable to the CO2 and H2S coexistence conditions, the corrosion behavior of low-chromium steels in CO2-H2S environment with high pressure and high temperature was investigated using weight loss measurement and surface characterization. The results showed that P110 steel suffered localized corrosion and both 3Cr-P110 and 5Cr-P110 steels exhibited general corrosion. However, the corrosion rate of 5Cr-P110 was the highest among them. The corrosion process of the steels was simultaneously governed by CO2 and H2S. The outer scales on the three steels mainly consisted of FeS1−x crystals, whereas the inner scales on Cr-containing steels comprised of amorphous FeS1−x, Cr(OH)3 and FeCO3, in contrast with the amorphous FeS1−x and FeCO3 mixture film of P110 steel. The more chromium the steel contains, the more chromium compounds the corrosion products contain. The addition of chromium in steels increases the uniformity of the Cr-enriched corrosion scales, eliminates the localized corrosion, but cannot decrease the general corrosion rates. The formation of FeS1−x may interfere with Cr-enriched corrosion scales and lowering the corrosion performance of 3Cr-P110 and 5Cr-P110 steels. PMID:28773328

  10. Effect of Chromium on Corrosion Behavior of P110 Steels in CO2-H2S Environment with High Pressure and High Temperature

    Directory of Open Access Journals (Sweden)

    Jianbo Sun

    2016-03-01

    Full Text Available The novel Cr-containing low alloy steels have exhibited good corrosion resistance in CO2 environment, mainly owing to the formation of Cr-enriched corrosion film. In order to evaluate whether it is applicable to the CO2 and H2S coexistence conditions, the corrosion behavior of low-chromium steels in CO2-H2S environment with high pressure and high temperature was investigated using weight loss measurement and surface characterization. The results showed that P110 steel suffered localized corrosion and both 3Cr-P110 and 5Cr-P110 steels exhibited general corrosion. However, the corrosion rate of 5Cr-P110 was the highest among them. The corrosion process of the steels was simultaneously governed by CO2 and H2S. The outer scales on the three steels mainly consisted of FeS1−x crystals, whereas the inner scales on Cr-containing steels comprised of amorphous FeS1−x, Cr(OH3 and FeCO3, in contrast with the amorphous FeS1−x and FeCO3 mixture film of P110 steel. The more chromium the steel contains, the more chromium compounds the corrosion products contain. The addition of chromium in steels increases the uniformity of the Cr-enriched corrosion scales, eliminates the localized corrosion, but cannot decrease the general corrosion rates. The formation of FeS1−x may interfere with Cr-enriched corrosion scales and lowering the corrosion performance of 3Cr-P110 and 5Cr-P110 steels.

  11. Cretaceous high-pressure metamorphic belts of the Central Pontides (northern Turkey): pre-collisional Pacific-type accretionary continental growth of Laurasian Margin

    Science.gov (United States)

    Aygul, Mesut; Okay, Aral I.; Oberhaensli, Roland; Sudo, Masafumi

    2014-05-01

    Cretaceous blueschist-facies metamorphic rocks crop out widely in the central part of the Pontides, an east-west trending mountain belt in northern Turkey. They comprise an accretionary wedge along to the southern Laurasian active continental margin and predate the opening of Black Sea basin. From North to South, the wedge consists of a low grade metaflysch unit with marble, Na-amphibole-bearing metabasite and serpentinite blocks. An extensional shear zone separates the accreted distal terrigenous sediments from HP/LT micaschists and metabasites of oceanic origin, known as Domuzdaǧ Complex. The shear zone reaches up to one km in thickness and consists of tectonic slices of serpentinite, metabasite, marble, phyllite and micaschist with top to the NW sense of shear. The Domuzdaǧ Complex predominantly consists of carbonaceous micaschist and metabasite with serpentinite, and minor metachert, marble and metagabbro. Metabasites consist mainly of epidote-blueschists sometimes with garnet. Fresh lawsonite-blueschists are found as blocks within the shear zone. Peak metamorphic assemblages in the micaschists are chloritoid-glaucophane and garnet-chloritoid-glaucophane-lawsonite in addition to phengite, paragonite, quartz, chlorite and rutile (P: 17 ± 1 Kbar, T: 390-450 °C). To the south, lithologies change slightly, with metabasite and thick, pale marble with few metachert and metapelitic horizons. The degree of metamorphism also changes. The metabasites range from high-pressure upper-greenschist facies with growth of sodic-amphibole to lower greenschist without any HP index mineral, suggesting a general decrease in pressure toward south within the prism. While Domuzdaǧ Complex represents deep-seated underplated oceanic sediments and basalts, the carbonate-rich southern parts can be interpreted as seamounts integrated into the accretionary prism. Ar/Ar dating on phengite separates both from terrigenous and oceanic metasediments give consistent plateau ages of 100 ± 2

  12. High-temperature granulites and supercontinents

    Directory of Open Access Journals (Sweden)

    J.L.R. Touret

    2016-01-01

    Full Text Available The formation of continents involves a combination of magmatic and metamorphic processes. These processes become indistinguishable at the crust-mantle interface, where the pressure-temperature (P-T conditions of (ultra high-temperature granulites and magmatic rocks are similar. Continents grow laterally, by magmatic activity above oceanic subduction zones (high-pressure metamorphic setting, and vertically by accumulation of mantle-derived magmas at the base of the crust (high-temperature metamorphic setting. Both events are separated from each other in time; the vertical accretion postdating lateral growth by several tens of millions of years. Fluid inclusion data indicate that during the high-temperature metamorphic episode the granulite lower crust is invaded by large amounts of low H2O-activity fluids including high-density CO2 and concentrated saline solutions (brines. These fluids are expelled from the lower crust to higher crustal levels at the end of the high-grade metamorphic event. The final amalgamation of supercontinents corresponds to episodes of ultra-high temperature metamorphism involving large-scale accumulation of these low-water activity fluids in the lower crust. This accumulation causes tectonic instability, which together with the heat input from the sub-continental lithospheric mantle, leads to the disruption of supercontinents. Thus, the fragmentation of a supercontinent is already programmed at the time of its amalgamation.

  13. Achievement report for fiscal 1974 on Sunshine Program. Research and development of hydrogen production technology using high-temperature and high-pressure water electrolysis; 1974 nendo koon koatsusui denkaiho ni yoru suiso seizo gijutsu no kenkyu kaihatsu

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1975-05-30

    The goals at present are to clarify conditions for the realization of the water electrolysis process relative to various primary energy sources and to experimentally construct a small practical electrobath to operate at high temperature and high pressure for the attainment of high economic efficiency. Efforts in this fiscal year are mentioned below. Surveys and studies are conducted about hydrogen production by water electrolysis and about achievements in the past and problems at present concerning hydrogen production by water electrolysis in Japan and overseas. The expected role of water electrolysis in various primary energy sources is also studied and evaluated. For a high-temperature high-pressure water electrolysis bath conceptual design (small test plant, bathing temperature 120 degrees C, pressure 20atm, hydrogen production rate 2Nm{sup 3}/h), studies are conducted about a constant-load type high-temperature high-pressure (bipolar) diaphragm-assisted water electrolysis bath and a variable-load type high-temperature high-pressure diaphragm-assisted water electrolysis bath. Surveys and studies are also conducted about the expected role of water electrolysis in various primary energy sources, and the role is evaluated. (NEDO)

  14. Investigation of the rate-controlling mechanism(s) for high temperature creep and the relationship between creep and melting by use of high pressure as a variable. Progress report

    Energy Technology Data Exchange (ETDEWEB)

    1991-12-31

    Using high pressure as a variable, the rate-controlling mechanism for high temperature creep and the relationship between creep and melting is investigated for silicon and nickel. An apparatus is used in which the samples are heated to melting point and subjected to 1 to 3 GigaPascal pressure. The stress behavior of the materials are then studied.

  15. Investigation of reactivity and structure formation in a K-Te-U oxo-system under high-temperature/high-pressure conditions.

    Science.gov (United States)

    Xiao, Bin; Kegler, Philip; Bosbach, Dirk; Alekseev, Evgeny V

    2016-09-27

    The high-temperature/high-pressure treatment of the K-Te-U oxo-family at 1100 °C and 3.5 GPa results in the crystallization of a series of novel uranyl tellurium compounds, K2[(UO2)3(TeIVO3)4], K2[(UO2)TeO14], α-K2[(UO2)TeVIO5] and β-K2[(UO2)TeVIO5]. In contrast to most of the reported uranyl compounds which are favorable in layered structures, we found that under extreme conditions, the potassium uranyl oxo-tellurium compounds preferably crystallized in three-dimensional (3D) framework structures with complex topologies. Anion topology analysis indicates that the 3D uranyl tellurite anionic framework observed in K2[(UO2)3(TeIVO3)4] is attributable to the additional linkages of TeO3 polyhedra connecting with TeO4 disphenoids from the neighboring U-Te layers. The structure of K2[(UO2)TeO14] can be described based on [UTe6O26]22- clusters, where six TeO5 polyhedra enclose a hexagonal cavity in which a UO8 polyhedron is located. The [UTe6O26]22- clusters are further linked by TeO5 square pyramids to form the 3D network. Similar to uranyl tellurates, both α-K2[(UO2)TeVIO5] and β-K2[(UO2)TeVIO5] contain TeO6 octahedra which share a common face to form a dimeric Te2O10 unit. However, in α-K2[(UO2)TeVIO5], these Te2O10 units connect with UO6 tetragonal bipyramids to form a 3D structural framework, while in β-K2[(UO2)TeVIO5], the same Te2O10 dimers are observed to link with UO7 pentagonal bipyramids, forming 2D layers. Raman measurements were carried out and the vibration bands related to TeIV-O, TeVI-O and UVI-O bonds are discussed.

  16. Using TOUGH2/ECO2H for modeling high-pressure and high-temperature CO2-enhanced geothermal energy extraction from saline systems

    Science.gov (United States)

    Borgia, A.; Pruess, K.; Kneafsey, T. J.; Oldenburg, C. M.

    2011-12-01

    Conventional geothermal energy uses water as the fluid to transport heat to the surface. This has a number of drawbacks principally related to strong water-rock chemical reactions, but also in terms of environmental impacts through overdraft of shallow aquifers with valuable water resources. Various authors have proposed the use of CO2 instead of water to transfer heat because such use may result in better rate of heat extraction, less fluid-rock reactivity, and less demand for scarce ground or surface water resources. TOUGH2/ECO2H was developed to study the behavior of high-pressure high-temperature H2O-CO2-NaCl geothermal systems. To demonstrate and test the code, we have modeled an idealized fractured geothermal system. Based on a five-spot well pattern and its inherent symmetry, we use a model grid of 1/8 of a square with sides of 1 km. In the model, CO2 is injected at the four corner-wells at 20 °C and constant pressure of 2.1*10^7 Pa into a variable salinity reservoir which is initially at 200 °C. The center well produces fluid at a constant pressure of 1.9*10^7 Pa. Initially, H2O + NaCl are produced, followed by a mixture of H2O + CO2 + NaCl and, finally only CO2. As soon as the injected CO2 reaches the production well, usually less than 2 months after injection begins, there is a drastic drop in heat production. This decrease occurs because of a reduced flow rate induced by reduction in effective permeability associated with two-phase flow (liquid + gas) in the reservoir. As the liquid phase dries out, the CO2 flow rate increases slowly over about 2-3 years and the heat production reaches a maximum rate that is about 40% larger than the initial rate of production with just water. Our modeling suggests that this same behavior occurs for highly saline geothermal reservoirs, even though the absolute rate of heat production is about 30% lower than the non-saline models. The decrease in production for saline systems is due to a marked reduction in permeability

  17. The influence of boron on the crystal structure and properties of mullite. Investigations at ambient, high-pressure, and high-temperature conditions

    Energy Technology Data Exchange (ETDEWEB)

    Luehrs, Hanna

    2013-11-21

    Mullite is one of the most important synthetic compounds for advanced structural and functional ceramic materials. The crystal structure of mullite with the composition Al{sub 2}[Al{sub 2+2x}Si{sub 2-2x}]O{sub 10-x} can incorporate a large variety of foreign cations, including (amongst others) significant amounts of boron. However, no chemical or crystal structure analyses of boron-mullites (B-mullites) were available prior to this work, thus representing the key aspects of this thesis. Furthermore, the influence of boron on selected properties of mullite under ambient, high-temperature, and high-pressure conditions are addressed. Starting from a 3:2 mullite composition (Al{sub 4.5}Si{sub 1.5}O{sub 9.75}), the initial hypothesis for this study was a 1:1 isomorphous replacement of silicon by boron according to the coupled substitution mechanism: 2 Si{sup 4+} + O{sup 2-} → 2 B{sup 3+} + □. Based on a series of compounds synthesized from sol-gel derived precursors at ambient pressure and 1200 C, the formation conditions and physical properties of B-mullites were investigated. The formation temperature for B-mullites decreases with increasing boron-content, as revealed by thermal analyses. An anisotropic development of lattice parameters is observed: Whereas lattice parameters a and b only exhibit minor changes, a linear relationship between lattice parameter c and the amount of boron in the crystal structure was established, on the basis of prompt gamma activation analyses (PGAA) and Rietveld refinements. According to this relationship about 15% of the silicon in mullite can be replaced by boron yielding single-phase B-mullite. B-mullites with significantly higher (∝ factor 3) boron-contents in the mullite structure were also observed but the respective samples contain alumina impurities. Fundamental new details regarding the response of B-mullite to high-temperature and highpressure are presented in this thesis. On the one hand, long-term thermal stability at

  18. Determination of the relative resistance to ignition of selected turbopump materials in high-pressure, high-temperature, oxygen environments, volume 1

    Science.gov (United States)

    Stoltzfus, Joel M.; Benz, Frank J.

    1986-01-01

    Advances in the design of the liquid oxygen, liquid hydrogen engines for the Space Transportation System call for the use of warm, high-pressure oxygen as the driving gas in the liquid oxygen turbopump. The NASA Lewis Research Center requested the NASA White Sands Test Facility (WSTF) to design a test program to determine the relative resistance to ignition of nine selected turbopump materials: Hastelloy X, Inconel 600, Invar 36, Monel K-500, nickel 200, silicon carbide, stainless steel 316, and zirconium copper. The materials were subjected to particle impact and to frictional heating in high-pressure oxygen.

  19. High Pressure Scanning Tunneling Microscopy Studies of AdsorbateStructure and Mobility during Catalytic Reactions: Novel Design of anUltra High Pressure, High Temperature Scanning Tunneling MicroscopeSystem for Probing Catalytic Conversions

    Energy Technology Data Exchange (ETDEWEB)

    Tang, David Chi-Wai [Univ. of California, Berkeley, CA (United States)

    2005-05-16

    The aim of the work presented therein is to take advantage of scanning tunneling microscope’s (STM) capability for operation under a variety of environments under real time and at atomic resolution to monitor adsorbate structures and mobility under high pressures, as well as to design a new generation of STM systems that allow imaging in situ at both higher pressures (35 atm) and temperatures (350 °C).

  20. Fiscal 1975 Sunshine Project research report. R and D on hydrogen production technology by high-temperature high- pressure water electrolysis; 1975 nendo koon koatsusui denkaiho ni yoru suiso seizo gijutsu no kenkyu kaihatsu seika hokokusho

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1976-05-29

    This report details the research result in fiscal 1975. Part 1 'Outlines' includes the research target, the summary of fiscal 1974 research results, the summary of fiscal 1975 research results, and responsible researchers. Part 2 'Details of the research' includes the fiscal 1975 research results. Chapter 1 reports 'Study on constant-load high- temperature high-pressure (multi-electrode type) diaphragm water electrolysis tank' promoted by Mitsubishi Kakoki Kaisha. Chapter 2 reports 'Study on Teflon system diaphragm for high-temperature high-pressure water electrolysis tanks' promoted by Yuasa Battery Co. through Mitsubishi Kakoki Kaisha. Chapter 3 reports 'Study on variable-load high- temperature high-pressure diaphragm water electrolysis tank' promoted by Showa Denko K.K. Chapter 4 reports 'The first detailed design of the electrolysis tank for a small test plant' promoted by Hitachi Zosen Corp. through Showa Denko K.K. Chapter 5 reports 'Research on the applicability of water electrolysis systems to various fields' promoted by Mitsubishi Research Institute, Inc. through Showa Denko K.K. (NEDO)

  1. Preliminary Investigation on the Useful Chemicals obtained from High-Temperature and High-Pressure Water Treatment of Hinoki (Chamaecyparis Obutus Bark

    Directory of Open Access Journals (Sweden)

    Hiroyuki Daimon

    2010-12-01

    Full Text Available The possibility of utilizing residual forest biomass to produce valuable chemicals was investigated. An outer layer of a bark of Hinoki (Chamaecyparis obutusa tree, a Japanese cypress, was used as a sample material. Experiments were carried out in a semibatch reactor apparatus that allows the study of the effect of reaction temperatures in a single run. Analysis of the products by GC-MS reveals formation of useful compounds such as furfural, some aromatic compounds (1,3-di-tert-butyl benzene and 2,4-di-tert-butyl phenol, and fatty acids (myristic acid, palmitic acid and stearic acid. Keywords: fatty acids, furfural, high temperature water treatment, hinoki, residual biomass

  2. Solubility study of nickel ferrite in boric acid using a flow-through autoclave system under high temperature and high pressure

    Energy Technology Data Exchange (ETDEWEB)

    Park, Yong Joon; Choi, Ke Chon; Ha, Yeong Keong [Nuclear Chemistry Research Division, Korea Atomic Energy Research Institute, Daejeon (Korea, Republic of)

    2016-04-15

    The solubility of nickel ferrite in an aqueous solution of boric acid was studied by varying the pH at the temperatures ranging from 25 .deg. C to 320 .deg. C. A flow-through autoclave system was specially designed and fabricated to measure the solubility of Fe in hydrothermal solutions under high temperature and pressure. The performance of this flow-through system was directly compared with the conventional static state technique using a batch-type autoclave system. The stability of fluid velocity for the flow-through autoclave system was verified prior to the solubility measurement. The influence of chemical additives, such as boric acid and H2, on the solubility of nickel ferrite was also evaluated.

  3. H + CH{sub 2}CO {yields} CH{sub 3} + CO at high temperature : a high pressure chemical activation reaction with positive barrier.

    Energy Technology Data Exchange (ETDEWEB)

    Hranisavljevic, J.; Kumaran, S. S.; Michael, J. V.

    1997-12-08

    The Laser Photolysis-Shock Tube (LP-ST) technique coupled with H-atom atomic resonance absorption spectrometry (ARAS) has been used to study reaction, H + CH{sub 2}CO {r_arrow} CH{sub 3} + CO, over the temperature range, 863-1400 K. The results can be represented by the Arrhenius expression, k = (4.85 {+-} 0.70) x 10{sup {minus}11} exp({minus}2328 {+-} 155 K/T) cm{sup 3} molecule{sup {minus}1} s{sup {minus}1}. The present data have been combined with the earlier low temperature flash photolysis-resonance fluorescence measurements to yield a joint three parameter expression, k = 5.44 x 10{sup {minus}14} T{sup 0.8513} exp({minus}1429 K/T) cm{sup 3} molecule{sup {minus}1} s{sup {minus}1}. This is a chemical activation process that proceeds through vibrationally excited acetyl radicals. However, due to the presence of a low lying forward dissociation channel to CH{sub 3} + CO, the present results refer to the high pressure limiting rate constants. Hence, transition state theory with Eckart tunneling is used to explain the data.

  4. Accurate high-pressure and high-temperature effective pair potentials for the systems N2-N and O2-O

    Science.gov (United States)

    van Thiel, M.; Ree, F. H.

    1996-04-01

    Statistical mechanical chemical equilibrium calculations of N2 and O2 show that these molecules dissociate behind strong shock waves. Our determination of accurate intermolecular potentials has required the consideration of the dissociation products N and O. Our previous theoretical efforts to predict the thermodynamic properties of these molecules relied in part on corresponding states theory and shock wave data of argon, without consideration of the dissociation products. Recent high-pressure Hugoniot measurements, however, allowed a more accurate determination of the potentials and the explicit inclusion of the dissociation products. The best fit to the data is obtained with the exponential-6 coefficients, for O2-O2: ɛ/k=125 K, r*=3.86 Å, α=13.2; for O-O: ɛ/k=700 K, r*=2.40 Å, α=11.0; for N2-N2: ɛ/k=293 K, r*=3.91 Å, α=11.5; and for N-N: ɛ/k=600 K, r*=2.47 Å, α=10.0. The unlike pair interactions are obtained from these like interactions with a modified Lorentz-Berthelot rule. The coefficients in the modified Lorentz-Berthelot equations are k/l/m=1/1/0.93 for O2-O- and k/l/m=1/1/0.90 for N2-N interactions.

  5. Experimental Measurement of Speeds of Sound in Liquid Carbon Monoxide and Development of High-Pressure, High-Temperature Equations of State

    Science.gov (United States)

    Zaug, Joseph; Carter, Jeffrey; Bastea, Sorin; Armstrong, Michael; Laurence, Fried

    2013-06-01

    We report the adiabatic sound speeds for supercritical fluid carbon monoxide along two isotherms, from 0.17 to 2.13 GPa at 297 K and from 0.31 to 3.2 GPa at 600 K. The carbon monoxide was confined in a resistively heated diamond-anvil cell and the sound speed measurements were conducted in situ using a recently reported variant of the photoacoustic light scattering effect. The measured sound speeds were then used to parameterize a single site dipolar exponential-6 intermolecular potential for carbon monoxide. PT thermodynamic states, sound speeds, and shock Hugoniots were calculated using the newly parameterized intermolecular potential and compared to previously reported experimental results. Additionally, we generated an analytical equation of state for carbon monoxide by fitting to a grid of calculated PT states over a range of 0.1-10 GPa and 150-2000 K. A 2 percent mean variation was found between computed high-pressure solid-phase densities and measured data -a surprising result for a spherical interaction potential. We further computed a rotationally dependent fluid to beta-solid phase boundary; results signal the relative magnitude of short-range rotational disorder under conditions that span existing phase boundary measurements. This research was partly funded by the Joint D0D/DOE Munitions Program, and was performed under the auspices of the U.S. Department of Energy by Lawrence Livermore National Laboratory under Contract No. DE-AC52-07NA27344.

  6. Synthesis of a new high-pressure and high-temperature iron oxide, Fe4O5, a plausible key player in deep subduction processes

    Science.gov (United States)

    Lavina, B.; Dera, P. K.; Kim, E.; Dobrzhinetskaya, L.; Meng, Y.; Downs, R. T.; Weck, P. F.; Sutton, S. R.; Zhao, Y.; Alp, E.

    2012-12-01

    Iron oxides have broad geophysical and geochemical relevance due to their abundance, electronic properties and role in redox equilibria. While investigating the stability and decomposition products of siderite (FeCO3) at conditions of the Earth's mantle we obtained, at 10 GPa and about 1800 K, a single crystal of unknown phase. High pressure and temperatures were achieved using a laser heated diamond anvil cell. Diffraction data were obtained using highly focused synchrotron x-rays. Structural solution and refinement of the single crystal diffraction pattern indicate that the phase is a new compound with formula Fe4O5 [1]. The phase has orthorhombic symmetry where iron is 6-coordinated in layers of trigonal prisms and edge-sharing octahedra. First-principle calculations show that Fe4O5 is stable at high pressure with respect to its possible breakdown products (FeO and Fe3O4 in the cubic and orthorhombic structures). We performed several HP-HT syntheses starting from mixtures of pure Fe+Fe3O4 and Fe+Fe2O3 in appropriate proportions. Fe4O5 was synthesized in the range 10-20 GPa readily upon heating at temperature in the range 1500-2500 K. Upon decompression and further heating we observed the decomposition of Fe4O5 at ~ 5GPa and 1800K, to wüstite and magnetite; whereas cold decompression shows that orthorhombic Fe4O5 is a phase retrievable to ambient conditions. The new Fe-O compound has a broad fundamental and applicative significance, spanning planetary science, physics, chemistry and materials science. Also, the new iron oxide is a plausible phase of deep Earth, considering that it is rather reduced and taking into account the high heterogeneity of the upper mantle. Many peridotite from deep (>200-300km) subduction zones contain olivine and garnet rich in Fe3O4 lamellae exsolution which attest to the decompression of precursor phases that had formed at profound depths preceding mantle upwelling[2]. Microdiamonds from UHP gneisses also contain abundant Fex

  7. Study of cements silicate phases hydrated under high pressure and high temperature; Etude des phases silicatees du ciment hydrate sous haute pression et haute temperature

    Energy Technology Data Exchange (ETDEWEB)

    Meducin, F.

    2001-10-01

    This study concerns the durability of oil-well cementing. Indeed, in oil well cementing a cement slurry is pumped down the steel casing of the well up the annular space between it and the surrounding rock to support and protect the casing. The setting conditions of pressure and temperature may be very high (up to 1000 bar and 250 deg C at the bottom of the oil-well). In this research, the hydration of the main constituent of cement, synthetic tri-calcium silicate Ca{sub 3}SiO{sub 2}, often called C{sub 3}S (C = CaO; S = SiO{sub 2} and H H{sub 2}O), is studied. Calcium Silicate hydrates are prepared in high-pressure cells to complete their phase diagram (P,T) and obtain the stability conditions for each species. Indeed, the phases formed in these conditions are unknown and the study consists in the hydration of C{sub 3}S at different temperatures, pressures, and during different times to simulate the oil-well conditions. In a first step (until 120 deg C at ambient pressure) the C-S-H, a not well crystallized and non-stoichiometric phase, is synthesized: it brings adhesion and mechanical properties., Then, when pressure and temperature increase, crystallized phases appear such as jaffeite (Ca{sub 6}(Si{sub 2}O{sub 7})(OH){sub 6}) and hillebrandite (Ca{sub 2}(SiO{sub 3})(OH){sub 2}). Silicon {sup 29}Si Nuclear Magnetic Resonance (using standard sequences MAS, CPMAS) allow us to identify all the silicates hydrates formed. Indeed, {sup 29}Si NMR is a valuable tool to determine the structure of crystallized or not-well crystallized phases of cement. The characterization of the hydrated samples is completed by other techniques: X- Ray Diffraction and Scanning Electron Microscopy. The following results are found: jaffeite is the most stable phase at C/S=3. To simulate the hydration of real cement, hydration of C{sub 3}S with ground quartz and with or without super-plasticizers is done. In those cases, new phases appear: kilchoanite mainly, and xonotlite. A large amount of

  8. High-pressure high-temperature phase relations in FeTiO3 up to 35 GPa and 1600 °C

    Science.gov (United States)

    Akaogi, M.; Abe, K.; Yusa, H.; Ishii, T.; Tajima, T.; Kojitani, H.; Mori, D.; Inaguma, Y.

    2017-01-01

    Phase relations in FeTiO3 were precisely determined at 25-35 GPa and 600-1600 °C using multianvil high-pressure experiments with tungsten carbide anvils. Pressure generation up to about 36 GPa at 1600 °C was evaluated using Al2O3 solubility in MgSiO3 perovskite (Pv) in the system MgSiO3-Al2O3. At about 28 GPa, FeTiO3 Pv dissociates into an assemblage of calcium titanate (CT)-type Fe2TiO4 + orthorhombic-I (OI)-type TiO2 below 1200 °C. However, above 1200 °C at 28 GPa, FeTiO3 Pv decomposes into a new, denser phase assemblage of CT-type Fe2TiO4 + a new compound of FeTi2O5. The new phase FeTi2O5 was recovered as an amorphous phase at 1 atm. In situ X-ray diffraction experiments at 35.1 GPa indicated that the new phase (N-p) FeTi2O5 has orthorhombic symmetry with cell parameters a = 8.567(2) Å, b = 5.753(1) Å and c = 5.257(1) Å. In addition, the assemblage of CT-type Fe2TiO4 + OI-type TiO2 changes to FeO wüstite (Wu) + OI-type TiO2 at about 33 GPa below 1000 °C. The phase assemblages in FeTiO3 are denser in the order: FeTiO3 (Pv) → 1/2Fe2TiO4 (CT) + 1/2TiO2 (OI) → 1/3Fe2TiO4 (CT) + 1/3FeTi2O5 (N-p) → FeO (Wu) + TiO2 (OI). Our results indicate that the upper stability limit of FeTiO3 Pv is about 28 GPa at 600-1600 °C. This puts a constraint on peak shock pressure for formation of naturally discovered lithium niobate-type FeTiO3 which was interpreted to be retrograde transition product of FeTiO3 Pv on release of shock pressure.

  9. High-pressure high-temperature stability of hcp-IrxOs1-x (x = 0.50 and 0.55) alloys

    Energy Technology Data Exchange (ETDEWEB)

    Yusenko, Kirill V.; Bykova, Elena; Bykov, Maxim; Gromilov, Sergey A.; Kurnosov, Alexander V.; Prescher, Clemens; Prakapenka, Vitali B.; Crichton, Wilson A.; Hanfland, Michael; Margadonna, Serena; Dubrovinsky, Leonid S.

    2016-12-23

    Hcp-Ir0.55Os0.45 and hcp-Ir0.50Os0.50 alloys were synthesised by thermal decomposition of single-source precursors in hydrogen atmosphere. Both alloys correspond to a miscibility gap in the Ir–Os binary phase diagram and therefore are metastable at ambient conditions. An in situ powder X-ray diffraction has been used for a monitoring a formation of hcp-Ir0.55Os0.45 alloy from (NH4)2[Ir0.55Os0.45Cl6] precursor. A crystalline intermediate compound and nanodimentional metallic particles with a large concentration of defects has been found as key intermediates in the thermal decomposition process in hydrogen flow. High-temperature stability of titled hcp-structured alloys has been investigated upon compression up to 11 GPa using a multi-anvil press and up to 80 GPa using laser-heated diamond-anvil cells to obtain a phase separation into fcc + hcp mixture. Compressibility curves at room temperature as well as thermal expansion at ambient pressure and under compression up to 80 GPa were collected to obtain thermal expansion coefficients and bulk moduli. hcp-Ir0.55Os0.45 alloy shows bulk moduli B0 = 395 GPa. Thermal expansion coefficients were estimated as α = 1.6·10-5 K-1 at ambient pressure and α = 0.3·10-5 K-1 at 80 GPa. Obtained high-pressure high-temperature data allowed us to construct the first model for pressure-dependent Ir–Os phase diagram.

  10. X-ray diffraction and Raman spectroscopy on Gd{sub 2}(Ti{sub 2-y}Te{sub y})O{sub 7} prepared at high pressure and high temperature

    Energy Technology Data Exchange (ETDEWEB)

    Heredia, A.R. [Instituto de Investigaciones en Materiales, Universidad Nacional Autonoma de Mexico, A. Postal 70-360, Mexico D.F. 04510 (Mexico); Garcia, M. Quintana; Mazariego, J.L. Perez [Facultad de Ciencias, Universidad Nacional Autonoma de Mexico, A. Postal 70-360, Mexico D.F. 04510 (Mexico); Escamilla, R., E-mail: rauleg@servidor.unam.m [Instituto de Investigaciones en Materiales, Universidad Nacional Autonoma de Mexico, A. Postal 70-360, Mexico D.F. 04510 (Mexico)

    2010-08-20

    A series of Te-substituted pyrochlores of stoichiometry Gd{sub 2}(Ti{sub 2-y}Te{sub y})O{sub 7} (y {<=} 0.2) were prepared under high-pressure and high-temperature conditions and characterized by X-ray diffraction, X-ray photoelectron spectroscopy and Raman spectroscopy. X-ray diffraction and X-ray photoelectron spectroscopy studies revealed that the Te{sup 4+} and Te{sup 6+} ions occupy the Ti{sup 4+}sites; the percentage of the contribution of Te{sup 6+} increases as tellurium content. These substitutions induce an increase of the volume of the TiO{sub 6} octahedron due to the increase in the Ti-O(2) bond length, which preserves the oxygen positional parameter (x{sub 48f}) and the Gd-O(1) bond length. Results of Raman spectroscopy showed a significant shift to higher frequencies of the E{sub g} mode associated to the O(2) sublattice, as well an increase in the full-width-at-half-maximum intensity (FWHM) of the F{sub 2g} mode (O-Gd-O bending) as the level of Te substitution for Ti increases. These results are discussed and compared with those reported in the literature.

  11. Evolution of spin and valence states of (Pr0.7Sm0.3)0.7Ca0.3CoO3 at high temperature and high pressure

    Science.gov (United States)

    Chen, J. M.; Lee, J. M.; Haw, S. C.; Chen, S. A.; Hardy, V.; Guillou, F.; Chen, S. W.; Kuo, C. Y.; Pao, C. W.; Lee, J. F.; Hiraoka, N.; Ishii, H.; Tsuei, K. D.; Hu, Z.

    2014-07-01

    The changes of physical properties occurring at a first-order-like transition among a wide family of (Pr1-yLny)1-xCaxCoO3 compounds (Ln being a lanthanide) are controversially discussed as a transition of Co3+ ions from states of low spin (LS) to intermediate spin (IS), or from LS to a mixture of LS and high spin (HS). The debate also includes the nature of the spin state of Co4+, as well as the degree of valence shift between Pr3+ and Pr4+ which accompanies this transition. In the present paper, we investigated the evolution of spin and valence states of Co ions and the valence state of Pr ions in (Pr0.7Sm0.3)0.7Ca0.3CoO3, at high temperature up to 750 K and under pressure up to 36.5 GPa. For this purpose, the data of three spectroscopic techniques were combined: high-resolution Co K-edge partial-fluorescence-yield x-ray absorption spectra, Pr L2-edge x-ray absorption spectra, and Co Kβ x-ray emission spectra. The spectral weight transfer of the pre-edge peaks of the Co K-edge spectra reveals a continuous redistribution of 3d electrons between the t2g and eg levels of Co ions, reflecting a gradual increase of the average Co spin state upon heating. This is further confirmed by Co Kβ x-ray emission spectra, which show an increase of HS Co3+ population when increasing temperature from 300 to 750 K. Applying high pressure at 300 K, the Co Kβ x-ray emission spectra indicate a relatively sharp increase of LS Co3+ population below 4 GPa. Pr L2-edge x-ray absorption spectra of (Pr0.7Sm0.3)0.7Ca0.3CoO3 exhibit a valence-state transition from Pr3+ to Pr3.26+, occurring predominantly upon applying pressure in the range ˜4 to ˜12 GPa. Owing to the charge balance, increasing pressure in this regime induces complex valence and spin-state transitions within the Co ions. Moreover, at high enough pressure, it is found that the Co4+ can also undergo a spin-state transition (from IS to LS), in addition to that affecting the Co3+ (HS to LS).

  12. High-pressure microfluidics

    Science.gov (United States)

    Hjort, K.

    2015-03-01

    When using appropriate materials and microfabrication techniques, with the small dimensions the mechanical stability of microstructured devices allows for processes at high pressures without loss in safety. The largest area of applications has been demonstrated in green chemistry and bioprocesses, where extraction, synthesis and analyses often excel at high densities and high temperatures. This is accessible through high pressures. Capillary chemistry has been used since long but, just like in low-pressure applications, there are several potential advantages in using microfluidic platforms, e.g., planar isothermal set-ups, large local variations in geometries, dense form factors, small dead volumes and precisely positioned microstructures for control of reactions, catalysis, mixing and separation. Other potential applications are in, e.g., microhydraulics, exploration, gas driven vehicles, and high-pressure science. From a review of the state-of-art and frontiers of high pressure microfluidics, the focus will be on different solutions demonstrated for microfluidic handling at high pressures and challenges that remain.

  13. Examining the microhardness evolution and thermal stability of an Al–Mg–Sc alloy processed by high-pressure torsion at a high temperature

    Directory of Open Access Journals (Sweden)

    Pedro Henrique R. Pereira

    2017-10-01

    Full Text Available An Al–3% Mg–0.2% Sc alloy was solution treated and processed through 10 turns of high-pressure torsion (HPT at 450 K. Afterwards, the HPT-processed alloy was annealed for 1 h at temperatures ranging from 423 to 773 K and its mechanical properties and microstructural evolution were examined using microhardness measurements and electron backscattered diffraction (EBSD analysis. The results demonstrate that HPT processing at an elevated temperature leads to a more uniform microhardness distribution and to an early saturation in the hardness values in the Al alloy compared with high-pressure torsion at room temperature. In addition, detailed EBSD analysis conducted on the HPT-processed samples immediately after annealing revealed that the Al–Mg–Sc alloy subjected to HPT processing at 450 K exhibits superior thermal stability by comparison with the same material subjected to HPT at 300 K. Keywords: Aluminium alloys, Hall–Petch relationship, Hardness, High-pressure torsion, Severe plastic deformation, Thermal stability

  14. High Pressure Biomass Gasification

    Energy Technology Data Exchange (ETDEWEB)

    Agrawal, Pradeep K [Georgia Tech Research Corporation, Atlanta, GA (United States)

    2016-07-29

    According to the Billion Ton Report, the U.S. has a large supply of biomass available that can supplement fossil fuels for producing chemicals and transportation fuels. Agricultural waste, forest residue, and energy crops offer potential benefits: renewable feedstock, zero to low CO2 emissions depending on the specific source, and domestic supply availability. Biomass can be converted into chemicals and fuels using one of several approaches: (i) biological platform converts corn into ethanol by using depolymerization of cellulose to form sugars followed by fermentation, (ii) low-temperature pyrolysis to obtain bio-oils which must be treated to reduce oxygen content via HDO hydrodeoxygenation), and (iii) high temperature pyrolysis to produce syngas (CO + H2). This last approach consists of producing syngas using the thermal platform which can be used to produce a variety of chemicals and fuels. The goal of this project was to develop an improved understanding of the gasification of biomass at high pressure conditions and how various gasification parameters might affect the gasification behavior. Since most downstream applications of synags conversion (e.g., alcohol synthesis, Fischer-Tropsch synthesis etc) involve utilizing high pressure catalytic processes, there is an interest in carrying out the biomass gasification at high pressure which can potentially reduce the gasifier size and subsequent downstream cleaning processes. It is traditionally accepted that high pressure should increase the gasification rates (kinetic effect). There is also precedence from coal gasification literature from the 1970s that high pressure gasification would be a beneficial route to consider. Traditional approach of using thermogravimetric analyzer (TGA) or high-pressure themogravimetric analyzer (PTGA) worked well in understanding the gasification kinetics of coal gasification which was useful in designing high pressure coal gasification processes. However

  15. Sensitivity of Fischer-Tropsch Synthesis and Water-Gas Shift Catalysts to Poisons from High-Temperature High-Pressure Entrained-Flow (EF) Oxygen-Blown Gasifier Gasification of Coal/Biomass Mixtures

    Energy Technology Data Exchange (ETDEWEB)

    Burton Davis; Gary Jacobs; Wenping Ma; Dennis Sparks; Khalid Azzam; Janet Chakkamadathil Mohandas; Wilson Shafer; Venkat Ramana Rao Pendyala

    2011-09-30

    There has been a recent shift in interest in converting not only natural gas and coal derived syngas to Fischer-Tropsch synthesis products, but also converting biomass-derived syngas, as well as syngas derived from coal and biomass mixtures. As such, conventional catalysts based on iron and cobalt may not be suitable without proper development. This is because, while ash, sulfur compounds, traces of metals, halide compounds, and nitrogen-containing chemicals will likely be lower in concentration in syngas derived from mixtures of coal and biomass (i.e., using entrained-flow oxygen-blown gasifier gasification gasification) than solely from coal, other compounds may actually be increased. Of particular concern are compounds containing alkali chemicals like the chlorides of sodium and potassium. In the first year, University of Kentucky Center for Applied Energy Research (UK-CAER) researchers completed a number of tasks aimed at evaluating the sensitivity of cobalt and iron-based Fischer-Tropsch synthesis (FT) catalysts and a commercial iron-chromia high temperature water-gas shift catalyst (WGS) to alkali halides. This included the preparation of large batches of 0.5%Pt-25%Co/Al{sub 2}O{sub 3} and 100Fe: 5.1Si: 3.0K: 2.0Cu (high alpha) catalysts that were split up among the four different entities participating in the overall project; the testing of the catalysts under clean FT and WGS conditions; the testing of the Fe-Cr WGS catalyst under conditions of co-feeding NaCl and KCl; and the construction and start-up of the continuously stirred tank reactors (CSTRs) for poisoning investigations. In the second and third years, researchers from the University of Kentucky Center for Applied Energy Research (UK-CAER) continued the project by evaluating the sensitivity of a commercial iron-chromia high temperature water-gas shift catalyst (WGS) to a number of different compounds, including KHCO{sub 3}, NaHCO{sub 3}, HCl, HBr, HF, H{sub 2}S, NH{sub 3}, and a combination of H

  16. Sensitivity of Fischer-Tropsch Synthesis and Water-Gas Shift Catalysts to Poisons from High-Temperature High-Pressure Entrained-Flow (EF) Oxygen-Blown Gasifier Gasification of Coal/Biomass Mixtures

    Energy Technology Data Exchange (ETDEWEB)

    Burtron Davis; Gary Jacobs; Wenping Ma; Khalid Azzam; Dennis Sparks; Wilson Shafer

    2010-09-30

    The successful adaptation of conventional cobalt and iron-based Fischer-Tropsch synthesis catalysts for use in converting biomass-derived syngas hinges in part on understanding their susceptibility to byproducts produced during the biomass gasification process. With the possibility that oil production will peak in the near future, and due to concerns in maintaining energy security, the conversion of biomass-derived syngas and syngas derived from coal/biomass blends to Fischer-Tropsch synthesis products to liquid fuels may provide a sustainable path forward, especially considering if carbon sequestration can be successfully demonstrated. However, one current drawback is that it is unknown whether conventional catalysts based on iron and cobalt will be suitable without proper development because, while ash, sulfur compounds, traces of metals, halide compounds, and nitrogen-containing chemicals will likely be lower in concentration in syngas derived from mixtures of coal and biomass (i.e., using an entrained-flow oxygen-blown gasifier) than solely from coal, other byproducts may be present in higher concentrations. The current project examines the impact of a number of potential byproducts of concern from the gasification of biomass process, including compounds containing alkali chemicals like the chlorides of sodium and potassium. In the second year, researchers from the University of Kentucky Center for Applied Energy Research (UK-CAER) continued the project by evaluating the sensitivity of a commercial iron-chromia high temperature water-gas shift catalyst (WGS) to a number of different compounds, including KHCO{sub 3}, NaHCO{sub 3}, HCl, HBr, HF, H{sub 2}S, NH{sub 3}, and a combination of H{sub 2}S and NH{sub 3}. Cobalt and iron-based Fischer-Tropsch synthesis (FT) catalysts were also subjected to a number of the same compounds in order to evaluate their sensitivities.

  17. Cretaceous high-pressure metamorphism and low pressure overprint in the Sistan Suture Zone, eastern Iran: Additional temperature estimates for eclogites, geological significance of U-Pb zircon ages and Rb-Sr constraints on the timing of exhumation

    Science.gov (United States)

    Kurzawa, Timon; Bröcker, Michael; Fotoohi Rad, Gholamreza; Berndt, Jasper; Lisker, Frank

    2017-10-01

    The Sistan Suture Zone, eastern Iran, includes blocks and lenses of eclogite-, blueschist- and/or epidote amphibolite-facies rocks that provide an excellent opportunity to examine the exhumation history of oceanic HP/LT rocks and their retrograde derivatives. Zr-in-rutile thermometry of eclogites corroborates previous interpretations suggesting metamorphic temperatures of ca. 550-600 °C during the HP stage in the Sistan area. Flat HREE distribution patterns and Ti-in-zircon temperatures of ca. 500-600 °C document that zircon in eclogite is of metamorphic origin. REE patterns of zircon from felsic meta-igneous rocks do not allow to distinguish between a magmatic or metamorphic origin, but relatively low temperatures indicated by Ti-in-zircon thermometry (ca. 500-600 °C) and the close similarity of zircon (U-Pb) and white mica (Rb-Sr, Ar-Ar) ages favor a metamorphic zircon origin. Previously published isotopic ages of the felsic rocks cannot unambiguously be linked to the eclogite- and/or blueschist-facies P-T conditions due to the absence of unequivocal mineralogical and petrological evidence. Instead, these rocks may record contemporaneous metamorphic processes that took place at a different depth within the subduction complex, or may indicate active ridge subduction and/or melt formation in the subduction zone at relatively low pressures. Biotite-based internal Rb-Sr isochrons of newly dated epidote amphibolite and biotite-albite gneisses indicate ages of ca. 74-80 Ma, either dating fluid-infiltration-induced formation of biotite during relatively fast uplift, or the time of final passage through the effective biotite closure temperature. Rb-Sr ages of phengite from both an epidote amphibolite and a biotite-albite gneiss yield ages that correspond to the HP/LT stage. This outcome, combined with textural evidence for derivation from eclogitic precursors documents that white mica ages of some strongly overprinted Sistan rocks are compromised by inheritance and do

  18. Structural variations of feldspars at high pressure and high temperature

    OpenAIRE

    Kolbus, Lindsay Marie

    2012-01-01

    Feldspar minerals are framework aluminosilicates that comprise approximately 60 percent of the Earth's crust. The elastic and thermodynamic properties of this important mineral group are needed for the interpretation of seismic wave velocities, for understanding cation partioning patterns and for the determination of phase boundaries and reactions involving feldspars in the Earth's crust. Until recently, no systematic approach has been applied to describe the structural behavior of feldspars ...

  19. Advanced High-Temperature, High-Pressure Transport Reactor Gasification

    Energy Technology Data Exchange (ETDEWEB)

    Michael Swanson; Daniel Laudal

    2008-03-31

    The U.S. Department of Energy (DOE) National Energy Technology Laboratory Office of Coal and Environmental Systems has as its mission to develop advanced gasification-based technologies for affordable, efficient, zero-emission power generation. These advanced power systems, which are expected to produce near-zero pollutants, are an integral part of DOE's Vision 21 Program. DOE has also been developing advanced gasification systems that lower the capital and operating costs of producing syngas for chemical production. A transport reactor has shown potential to be a low-cost syngas producer compared to other gasification systems since its high-throughput-per-unit cross-sectional area reduces capital costs. This work directly supports the Power Systems Development Facility utilizing the KBR transport reactor located at the Southern Company Services Wilsonville, Alabama, site. Over 2800 hours of operation on 11 different coals ranging from bituminous to lignite along with a petroleum coke has been completed to date in the pilot-scale transport reactor development unit (TRDU) at the Energy & Environmental Research Center (EERC). The EERC has established an extensive database on the operation of these various fuels in both air-blown and oxygen-blown modes utilizing a pilot-scale transport reactor gasifier. This database has been useful in determining the effectiveness of design changes on an advanced transport reactor gasifier and for determining the performance of various feedstocks in a transport reactor. The effects of different fuel types on both gasifier performance and the operation of the hot-gas filter system have been determined. It has been demonstrated that corrected fuel gas heating values ranging from 90 to 130 Btu/scf have been achieved in air-blown mode, while heating values up to 230 Btu/scf on a dry basis have been achieved in oxygen-blown mode. Carbon conversions up to 95% have also been obtained and are highly dependent on the oxygen-coal ratio. Higher-reactivity (low-rank) coals appear to perform better in a transport reactor than the less reactive bituminous coals. Factors that affect TRDU product gas quality appear to be coal type, temperature, and air/coal ratios. Testing with a higher-ash, high-moisture, low-rank coal from the Red Hills Mine of the Mississippi Lignite Mining Company has recently been completed. Testing with the lignite coal generated a fuel gas with acceptable heating value and a high carbon conversion, although some drying of the high-moisture lignite was required before coal-feeding problems were resolved. No ash deposition or bed material agglomeration issues were encountered with this fuel. In order to better understand the coal devolatilization and cracking chemistry occurring in the riser of the transport reactor, gas and solid sampling directly from the riser and the filter outlet has been accomplished. This was done using a baseline Powder River Basin subbituminous coal from the Peabody Energy North Antelope Rochelle Mine near Gillette, Wyoming.

  20. High Temperature High Pressure Thermodynamic Measurements for Coal Model Compounds

    Energy Technology Data Exchange (ETDEWEB)

    John C. Chen; Vinayak N. Kabadi

    1998-11-12

    The overall objective of this project is to develop a better thermodynamic model for predicting properties of high-boiling coal derived liquids, especially the phase equilibria of different fractions at elevated temperatures and pressures. The development of such a model requires data on vapor-liquid equilibria (VLE), enthalpy, and heat capacity which would be experimentally determined for binary systems of coal model compounds and compiled into a database. The data will be used to refine existing models such as UNIQUAC and UNIFAC. The flow VLE apparatus designed and built for a previous project was upgraded and recalibrated for data measurements for thk project. The modifications include better and more accurate sampling technique and addition of a digital recorder to monitor temperature, pressure and liquid level inside the VLE cell. VLE data measurements for system benzene-ethylbenzene have been completed. The vapor and liquid samples were analysed using the Perkin-Elmer Autosystem gas chromatography.

  1. Aqueous Geochemistry at High Pressures and High Temperatures

    Energy Technology Data Exchange (ETDEWEB)

    Bass, Jay D. [Univ. of Illinois, Urbana-Champaign, IL (United States)

    2015-05-21

    This project is aimed at experimental characterization of the sound velocities, equations of state (EOS), and derived physical and chemical properties of aqueous solutions and carbon dioxide at extreme pressure and temperature conditions relevant to processes occurring in the interior of the Earth. Chemical transport, phase changes (including melting), fluid-solid reactions, and formation of magmatic liquids at convergent plat boundaries are a key motivation for this project. Research in this area has long been limited by the extreme experimental challenges and lack of data under the appropriate pressure-temperature (P-T) conditions. The vast majority of studies of aqueous geochemistry relevant to terrestrial problems of fluid-rock interactions have been conducted at 0.3 GPa or less, and the widely used Helgeson-Kirkham-Flowers equation of state for aqueous species is applicable only at ~ < 0.5 GPa. These limits are unfortunate because fluid flow and reactions plays a central role in many deeper environments. Recent efforts including our own, have resulted in new experimental techniques that now make it possible to investigate properties of homogeneous and heterogeneous equilibria involving aqueous species and minerals over a much broader range of pressure and temperature appropriate for deep crustal and upper mantle processes involving water-rich fluids. We carried out 1) Brillouin scattering measurements of the equations of state and molar volume of water and carbon dioxide to over 10 GPa and 870K using precise resistance heating of samples under pressure in the diamond anvil cell, and 2) the phase diagrams of the water and CO2, and 3) Exploring new experimental approaches, including CO2 laser heating of samples in a diamond cell, to measurements of sound velocities, EOS, and phase relations by Brillouin scattering to far greater pressures and temperatures.

  2. Modeling Study of High Pressure and High Temperature Reservoir Fluids

    DEFF Research Database (Denmark)

    Varzandeh, Farhad

    With dwindling easily accessible oil and gas resources, more and more exploration and production activities in the oil industry are driven to technically challenging environments such as unconventional resources and deeper formations. The temperature and pressure can become extremely high, e.g., up...

  3. Advanced High-Temperature, High-Pressure Transport Reactor Gasification

    Energy Technology Data Exchange (ETDEWEB)

    Michael L. Swanson

    2005-08-30

    The transport reactor development unit (TRDU) was modified to accommodate oxygen-blown operation in support of a Vision 21-type energy plex that could produce power, chemicals, and fuel. These modifications consisted of changing the loop seal design from a J-leg to an L-valve configuration, thereby increasing the mixing zone length and residence time. In addition, the standpipe, dipleg, and L-valve diameters were increased to reduce slugging caused by bubble formation in the lightly fluidized sections of the solid return legs. A seal pot was added to the bottom of the dipleg so that the level of solids in the standpipe could be operated independently of the dipleg return leg. A separate coal feed nozzle was added that could inject the coal upward into the outlet of the mixing zone, thereby precluding any chance of the fresh coal feed back-mixing into the oxidizing zone of the mixing zone; however, difficulties with this coal feed configuration led to a switch back to the original downward configuration. Instrumentation to measure and control the flow of oxygen and steam to the burner and mix zone ports was added to allow the TRDU to be operated under full oxygen-blown conditions. In total, ten test campaigns have been conducted under enriched-air or full oxygen-blown conditions. During these tests, 1515 hours of coal feed with 660 hours of air-blown gasification and 720 hours of enriched-air or oxygen-blown coal gasification were completed under this particular contract. During these tests, approximately 366 hours of operation with Wyodak, 123 hours with Navajo sub-bituminous coal, 143 hours with Illinois No. 6, 106 hours with SUFCo, 110 hours with Prater Creek, 48 hours with Calumet, and 134 hours with a Pittsburgh No. 8 bituminous coal were completed. In addition, 331 hours of operation on low-rank coals such as North Dakota lignite, Australian brown coal, and a 90:10 wt% mixture of lignite and wood waste were completed. Also included in these test campaigns was 50 hours of gasification on a petroleum coke from the Hunt Oil Refinery and an additional 73 hours of operation on a high-ash coal from India. Data from these tests indicate that while acceptable fuel gas heating value was achieved with these fuels, the transport gasifier performs better on the lower-rank feedstocks because of their higher char reactivity. Comparable carbon conversions have been achieved at similar oxygen/coal ratios for both air-blown and oxygen-blown operation for each fuel; however, carbon conversion was lower for the less reactive feedstocks. While separation of fines from the feed coals is not needed with this technology, some testing has suggested that feedstocks with higher levels of fines have resulted in reduced carbon conversion, presumably due to the inability of the finer carbon particles to be captured by the cyclones. These data show that these low-rank feedstocks provided similar fuel gas heating values; however, even among the high-reactivity low-rank coals, the carbon conversion did appear to be lower for the fuels (brown coal in particular) that contained a significant amount of fines. The fuel gas under oxygen-blown operation has been higher in hydrogen and carbon dioxide concentration since the higher steam injection rate promotes the water-gas shift reaction to produce more CO{sub 2} and H{sub 2} at the expense of the CO and water vapor. However, the high water and CO{sub 2} partial pressures have also significantly reduced the reaction of (Abstract truncated)

  4. Pulse Radiolysis at High Temperatures and High Pressures

    DEFF Research Database (Denmark)

    Christensen, H.; Sehested, Knud

    1980-01-01

    A cell for pulse radiolytic measurements up to temperatures of 320°C and pressures of 14 MPa is constructed. The activation energy of the reaction OH + Cu2+ is determined to 13.3 kJ × mol−1 (3.2 kcal × mol−1). A preliminary study of the reaction e−aq + e−aq yields an activation energy of 22 k...

  5. Fundamentals of high-pressure, high-temperature combustion of solid fuels. Final report (01.01.1994 - 31.12.1996); Grundlagen der Umwandlung fester Brennstoffe unter hohen Temperaturen und Druecken. Abschlussbericht (01.01.1994 - 31.12.1996)

    Energy Technology Data Exchange (ETDEWEB)

    Kremer, H.; Hackert, G.

    1997-06-01

    Drop tube investigations of coal particle combustion were done in a newly designed high temperature, high pressure drop tube furnace (KOALA) at temperatures up to 1500 C and pressures up to 20 bar. New methods of in situ particle observation like phase shift Doppler anemometry (PDA) and high-resolution video (HR-CCD) techniques were developed. Velocity distributions size, shape and surface temperatures of burning particles were determined. It is the aim of this work, both, to produce data for the mathematical modelling and simulation of full scale pressurised combustors, and to improve the understanding of the elementary reactions involved in pulverised coal combustion at such conditions. The measurements show that velocity and extent of devolatilisation are strongly reduced at high pressures. The apparent reaction rate coefficients showed significant pressure dependence. (orig.) [Deutsch] Gegenstand des Vorhabens sind Untersuchungen im Laboratoriums- und im kleintechnischen Massstab zur Erarbeitung von Grundlagen fuer die Kohleumwandlung bei Temperaturen bis zu 2000 Grad Celsius und Druecken bis zu 20 bar durch Druckstaufeuerung und Hochtemperatur-Vergasung. Das Programm wird sich vorwiegend zwei Bereichen widmen: Den Vorgaengen in den eigentlichen Umwandlungsreaktoren und den Vorgaengen in nachgeschalteten Anlagen. Zu den ersteren gehoeren die Untersuchung der Teilchentemperaturen, -groessen und -geschwindigkeiten, der Kinetik, des Verhaltens der Minerale und der Schadstoffentwicklung. Zu den Vorgaengen in nachgeschalteten Anlagen sollen untersucht werden: Abscheidung der im Rohrgas enthaltenen Partikeln, Ablagerungsmechanismen der mineralischen Bestandteile, Entfernung von Alkalien und Spurenelementen. (orig.)

  6. Collision condition indicted by High Pressure Phases in a Chondrite

    Science.gov (United States)

    Kato, Y.; Sekine, T.; Kayama, M.; Miyahara, M.; Yamaguchi, A.

    2012-12-01

    It has been generally recognized that there were many collisions during planetary accretion. Chondrites include the materials at the time of formation of the solar system. It is essential to unravel the shock history in meteorites and the parent planet in order to understand such collisional processes. In this study, we investigate a thin section of ordinary chondrite Y-790729 classified as L6 in which high-pressure minerals are found in the about 620-μm-wide shock vein. The mineralogical and chemical features give us detailed information to constrain the shock conditions. We have tried to constrain the P-T condition from the viewpoints of the mineral assemblage and cathodoluminescense (CL) spectroscopy. Y-790729 consists mostly of olivine and pyroxene and has shock veins. To identify high pressure phases, we used an optical microscope, a scanning electron microscope (SEM), micro Raman spectroscopy, and electron probe micro analyzer (EPMA). In addition, scanning electron microscopy-cathodoluminescence (SEM-CL) analysis, detectable shock-induced defect centers, was used to characterize the shock metamorphism in feldspar minerals. The presence of shock vein, maskelynite, and high pressure phases confirms shock record. 7 high pressure phases of ringwoodite, high-pressure clinoenstatite (HPC), majorite, merrillite, lingunite, high-pressure chromite and akimotoite were found in this section. All of them exist only in a shock vein, but maskelynite occurs everywhere in the section. From these observations, it is obvious that the shock vein experienced the high pressure and high temperature generated by shock wave. If some of the high pressure minerals are equilibrated, the P-T condition can be estimated. Based on the equilibrium phase diagram of MgSiO3 polymorphs (Presnall. 1995), the P-T conditions for crystallization of majorite, HPC and akimotoite is about 17 GPa and 1600 oC, because the compositions of the three phases are close to MgSiO3. It is consistent with the

  7. Tunable high pressure lasers

    Science.gov (United States)

    Hess, R. V.

    1976-01-01

    Atmospheric transmission of high energy CO2 lasers is considerably improved by high pressure operation which, due to pressure broadening, permits tuning the laser lines off atmospheric absorption lines. Pronounced improvement is shown for horizontal transmission at altitudes above several kilometers and for vertical transmission through the entire atmosphere. Applications of tunable high pressure CO2 lasers to energy transmission and to remote sensing are discussed along with initial efforts in tuning high pressure CO2 lasers.

  8. High pressure synthesis of bismuth disulfide

    DEFF Research Database (Denmark)

    Søndergaard-Pedersen, Simone; Nielsen, Morten Bormann; Bremholm, Martin

    In this research the BiS2 compound was synthesized by a high pressure and high temperature method using a multi-anvil large volume press and the structure was solved by single crystal diffraction. The structure contains Bi atoms in distorted square-based pyramidal coordination to five surrounding...

  9. High-pressure high-temperature decomposition of CeCoGa to the Laves phases CeCo{sub 0.58}Ga{sub 1.42}, CeCo{sub 0.72}Ga{sub 1.28}, and CeCo{sub 2}

    Energy Technology Data Exchange (ETDEWEB)

    Niehaus, Oliver; Rodewald, Ute C.; Heying, Birgit; Poettgen, Rainer [Muenster Univ. (Germany). Inst. fuer Anorganische und Analytische Chemie; Heymann, Gunter; Huppertz, Hubert [Innsbruck Univ. (Austria). Inst. fuer Allgemeine, Anorganische und Theoretische Chemie

    2016-07-01

    The monoclinic intermediate-valent gallide CeCoGa decomposes under high-pressure (HP) (9.5 GPa) high-temperature (HT) (1470 K) conditions into the Laves phases CeCo{sub 0.58}Ga{sub 1.42} (MgCu{sub 2} type), CeCo{sub 0.72}Ga{sub 1.28} (MgZn{sub 2} type; major product phase), and CeCo{sub 2} (MgCu{sub 2} type). The structures of the ternary Laves phases were refined from single crystal X-ray diffractometer data: Fd anti 3m, a=778.3(1) pm, wR2=0.0310, 63 F{sup 2} values, five variables for CeCo{sub 0.58(3)}Ga{sub 1.42(3)} and P6{sub 3}/mmc, a=547.24(5), c=858.76(7) pm, wR2=0.1009, 195 F{sup 2} values, 13 variables for CeCo{sub 0.72(1)}Ga{sub 1.28(1)}. Partial substitution of cobalt by gallium leads to a significant increase of the distances within the tetrahedral network: 253 pm Co-Co in CeCo{sub 2} as compared to 275 pm in CeCo{sub 0.58(3)}Ga{sub 1.42(3)} and 265-277 pm in CeCo{sub 0.72(1)}Ga{sub 1.28(1)}. The crystal chemical consequences are briefly discussed.

  10. Back-transformation of high-pressure minerals in shocked chondrites: Low-pressure mineral evidence for strong shock

    Science.gov (United States)

    Hu, Jinping; Sharp, Thomas G.

    2017-10-01

    Post-shock annealing of meteorites can destroy their shock-induced features, particularly high-pressure minerals, and complicate the estimation of impact pressure-temperature conditions. However, distinguishing post-shock annealing features from thermal metamorphism effects can be practically difficult. Here we report results from Mbale, a highly shocked L chondrite, to investigate the mechanisms, kinetics and identification criteria for post-shock annealing of high-pressure signatures. Olivine fragments within shock-melt veins in Mbale occur as chemically heterogeneous nanocrystalline aggregates that contain trace wadsleyite and ringwoodite. Their strong variation in fayalite content provides evidence of iron partitioning during transformation of olivine to wadsleyite, followed by back-transformation to olivine after decompression. Experimental studies of transformation kinetics show that wadsleyite transforms to olivine in seconds at temperatures above ∼1200 K and in hours at temperatures between 900 and 1200 K. Thermal models of shock-melt cooling show that shock veins in Mbale cooled to 1200 K in 1 s. The shock pulse must have been shorter than ∼1 s to provide the high temperature conditions for post-shock back-transformation of wadsleyite. Many highly shocked L chondrites, which have abundant high-pressure minerals, must have experienced relatively long shock durations combined with rapid cooling of shock-melt regions to preserve high-pressure phases. The most highly shocked samples, such as impact melt breccias, lack high-pressure phases because of post-shock back-transformations.

  11. Metamorphic belts of Anatolia

    Science.gov (United States)

    Oberhänsli, Roland; Prouteau, Amaury; Candan, Osman; Bousquet, Romain

    2015-04-01

    Investigating metamorphic rocks from high-pressure/low-temperature (HP/LT) belts that formed during the closure of several oceanic branches, building up the present Anatolia continental micro-plate gives insight to the palaeogeography of the Neotethys Ocean in Anatolia. Two coherent HP/LT metamorphic belts, the Tavşanlı Zone (distal Gondwana margin) and the Ören-Afyon-Bolkardağ Zone (proximal Gondwana margin), parallel their non-metamorphosed equivalent (the Tauride Carbonate Platform) from the Aegean coast in NW Anatolia to southern Central Anatolia. P-T conditions and timing of metamorphism in the Ören-Afyon-Bolkardağ Zone (>70?-65 Ma; 0.8-1.2 GPa/330-420°C) contrast those published for the overlying Tavşanlı Zone (88-78 Ma; 2.4 GPa/500 °C). These belts trace the southern Neotethys suture connecting the Vardar suture in the Hellenides to the Inner Tauride suture along the southern border of the Kirşehir Complex in Central Anatolia. Eastwards, these belts are capped by the Oligo-Miocene Sivas Basin. Another HP/LT metamorphic belt, in the Alanya and Bitlis regions, outlines the southern flank of the Tauride Carbonate Platform. In the Alanya Nappes, south of the Taurides, eclogites and blueschists yielded metamorphic ages around 82-80 Ma (zircon U-Pb and phengite Ar-Ar data). The Alanya-Bitlis HP belt testifies an additional suture not comparable to the northerly Tavşanlı and Ören-Afyon belts, thus implying an additional oceanic branch of the Neotethys. The most likely eastern lateral continuation of this HP belt is the Bitlis Massif, in SE Turkey. There, eclogites (1.9-2.4 GPa/480-540°C) occur within calc-arenitic meta-sediments and in gneisses of the metamorphic (Barrovian-type) basement. Zircon U-Pb ages revealed 84.4-82.4 Ma for peak metamorphism. Carpholite-bearing HP/LT metasediments representing the stratigraphic cover of the Bitlis Massif underwent 0.8-1.2 GPa/340-400°C at 79-74 Ma (Ar-Ar on white mica). These conditions compares to the Tav

  12. Superconductivity under high pressure

    Energy Technology Data Exchange (ETDEWEB)

    Amaya, K.; Shimizu, K.; Takeda, K.; Tateiwa, N.; Muramatsu, T.; Ishizuka, M.; Kobayashi, T.C

    2003-05-01

    In part 1, we review techniques developed in our laboratory for producing the complex extreme condition of very low temperature and ultra-high pressure and those for measuring electrical resistance and magnetization of the sample confined in the extremely small space of the used pressure cell. In part 2, we review our experimental results in search for pressure-induced superconductivity, which have been obtained by the use of developed techniques. Typical examples are shown in the case of simple inorganic and organic molecular crystals, ionic crystals, and magnetic metals.

  13. High pressure induced superconductivity

    Energy Technology Data Exchange (ETDEWEB)

    Amaya, K.; Shimizu, K

    2003-10-15

    We have developed complex extreme condition of very low temperature down to 30 mK and ultra high pressure exceeding 200 GPa by assembling compact diamond anvil cell (DAC) on a powerful {sup 3}He/{sup 4}He dilution refrigerator. We have also developed measuring techniques of electrical resistance, magnetization and optical measurement for the sample confined in the sample space of the DAC. Using the newly developed apparatus and techniques, we have searched for superconductivity in various materials under pressure. In this paper, we will shortly review our newly developed experimental apparatus and techniques and discuss a few examples of pressure induced superconductivity which were observed recently.

  14. Oxygen and hydrogen isotope study of high-pressure metagabbros and metabasalts (Cyclades, Greece): implications for the subduction of oceanic crust

    Science.gov (United States)

    Putlitz, Benita; Matthews, Alan; Valley, John W.

    Oxygen and hydrogen stable isotope ratios of eclogite-facies metagabbros and metabasalts from the Cycladic archipelago (Greece) document the scale and timing of fluid-rock interaction in subducted oceanic crust. Close similarities are found between the isotopic compositions of the high-pressure rocks and their ocean-floor equivalents. High-pressure minerals in metagabbros have low δ18O values: garnet 2.6 to 5.9‰, glaucophane 4.3 to 7.1‰ omphacite 3.5 to 6.2‰. Precursor actinolite that was formed during the hydrothermal alteration of the oceanic crust by seawater analyses at 3.7 to 6.3‰. These compositions are in the range of the δ18O values of unaltered igneous oceanic crust and high-temperature hydrothermally altered oceanic crust. In contrast, high-pressure metabasalts are characterised by 18O-enriched isotopic compositions (garnet 9.2 to 11.5‰, glaucophane 10.6 to 12.5‰, omphacite 10.2 to 12.8‰), which are consistent with the precursor basalts having undergone low-temperature alteration by seawater. D/H ratios of glaucophane and actinolite are also consistent with alteration by seawater. Remarkably constant oxygen isotope fractionations, compatible with isotopic equilibrium, are observed among high-pressure minerals, with Δglaucophane-garnet= 1.37+/-0.24‰ and Δomphacite-garnet=0.72+/-0.24‰. For the estimated metamorphic temperature of 500°C, these fractionations yield coefficients in the equation Δ=A*106/T2 (in Kelvin) of Aglaucophane-garnet= 0.87+/-0.15 and Aomphacite-garnet=0.72+/-0.24. A fractionation of Δglaucophane-actinolite=0.94+/-0.21‰ is measured in metagabbros, and indicates that isotopic equilibrium was established during the metamorphic reaction in which glaucophane formed at the expense of actinolite. The preservation of the isotopic compositions of gabbroic and basaltic oceanic crust and the equilibrium fractionations among minerals shows that high-pressure metamorphism occurred at low water/rock ratios. The isotopic

  15. Tectono-metamorphic evolution of the Jomolhari massif: Variations in timing of syn-collisional metamorphism across western Bhutan

    Science.gov (United States)

    Regis, Daniele; Warren, Clare J.; Young, David; Roberts, Nick M. W.

    2014-03-01

    Our current understanding of the rates and timescales of mountain-building processes is largely based on information recorded in U-bearing accessory minerals such as monazite, which is found in low abundance but which hosts the majority of the trace element budget. Monazite petrochronology was used to investigate the timing of crustal melting in migmatitic metasedimentary rocks from the Jomolhari massif (NW Bhutan). The samples were metamorphosed at upper amphibolite to granulite facies conditions (~ 0.85 GPa, ~ 800 °C), after an earlier High-Pressure stage (P > 1.4 GPa), and underwent partial melting through dehydration melting reactions involving muscovite and biotite. In order to link the timing of monazite growth/dissolution to the pressure-temperature (P-T) evolution of the samples, we identified 'chemical fingerprints' in major and accessory phases that were used to back-trace specific metamorphic reactions. Variations in Eu anomaly and Ti in garnet were linked to the growth and dissolution of major phases (e.g. growth of K-feldspar and dehydration melting of muscovite/biotite). Differences in M/HREE and Y from garnet core to rim were instead related to apatite breakdown and monazite-forming reactions. Chemically zoned monazite crystals reacted multiple times during the metamorphic evolution suggesting that the Jomolhari massif experienced a prolonged high-temperature metamorphic evolution from 36 Ma to 18 Ma, significantly different from the P-T-time path recorded in other portions of the Greater Himalayan Sequence (GHS) in Bhutan. Our data demonstrate unequivocally that the GHS in Bhutan consists of units that experienced independent high-grade histories and that were juxtaposed across different tectonic structures during exhumation. The GHS may have been exhumed in response to (pulsed) mid-crustal flow but cannot be considered a coherent block.

  16. High temperature battery. Hochtemperaturbatterie

    Energy Technology Data Exchange (ETDEWEB)

    Bulling, M.

    1992-06-04

    To prevent heat losses of a high temperature battery, it is proposed to make the incoming current leads in the area of their penetration through the double-walled insulating housing as thermal throttle, particularly spiral ones.

  17. High pressure direct injection

    Energy Technology Data Exchange (ETDEWEB)

    Johnson, J. [Cummins Westport Inc., Vancouver, BC (Canada)

    2002-07-01

    A brief overview of Cummins Westport was provided, indicating that Westport originated in the 1980s through a research team at the University of British Columbia, and the hiring of the first employees began in 1996. The joint venture between Cummins and Westport was formed in March 2001. Cummins is the largest builder of commercial diesels in the world, and Westport is a small incubation technology company with emphasis on natural gas. The contribution of each company benefits the joint venture. Cummins brings traditional expertise in product and process development and distribution system, while Westport contributes new high pressure direct injection (HPDI) technology, funding and enthusiasm. The same base engine is kept and only the fuel system is changed. HPDI uses diesel cycle combustion and diesel pilot ignites natural gas. It allows for low emissions, high performance, high efficiency and economic payback. The pilot-ignited HPDI technology was explained, and its application to large class-8 trucks was discussed. The efficiency and performance of diesel engines is maintained by HPDI technology, there are 40 per cent reductions in nitrous oxide emissions, particulate matter emissions are reduced by 60 per cent, and carbon dioxide emissions are reduced by 20 per cent. A field demonstration was reviewed, and the major test at Norcal in San Francisco was discussed. The key success factors were found to be: formalized customer support plan, on-site technical support, parts availability, driver support and interaction, and training. Liquid natural gas fuel contamination was found to cause component wear. The emphasis has now been placed on three issues: injector life improvements, fuel debris and liquid natural gas pump/dome regulator life, and fuel economy improvements. The accomplishments for 2001 were identified, such as rapidly improving reliability, 17 HPDI trucks are upfit and in-service to name a few. The goals for 2002 include the placement of permanent fuel

  18. High Temperature QCD

    CERN Document Server

    Lombardo, M P

    2012-01-01

    I review recent results on QCD at high temperature on a lattice. Steady progress with staggered fermions and Wilson type fermions allow a quantitative description of hot QCD whose accuracy in many cases parallels that of zero temperature studies. Simulations with chiral quarks are coming of age, and togheter with theoretical developments trigger interesting developments in the analysis of the critical region. Issues related with the universality class of the chiral transition and the fate of the axial symmetry are discussed in the light of new numerical and analytical results. Transport coefficients and analysis of bottomonium spectra compare well with results of heavy ion collisions at RHIC and LHC. Model field theories, lattice simulations and high temperature systematic expansions help building a coherent picture of the high temperature phase of QCD. The (strongly coupled) Quark Gluon Plasma is heavily investigated, and asserts its role as an inspiring theoretical laboratory.

  19. High Temperature Electrolysis

    DEFF Research Database (Denmark)

    Elder, Rachael; Cumming, Denis; Mogensen, Mogens Bjerg

    2015-01-01

    High temperature electrolysis of carbon dioxide, or co-electrolysis of carbon dioxide and steam, has a great potential for carbon dioxide utilisation. A solid oxide electrolysis cell (SOEC), operating between 500 and 900. °C, is used to reduce carbon dioxide to carbon monoxide. If steam is also...... input to the cell then hydrogen is produced giving syngas. This syngas can then be further reacted to form hydrocarbon fuels and chemicals. Operating at high temperature gives much higher efficiencies than can be achieved with low temperature electrolysis. Current state of the art SOECs utilise a dense...

  20. High Pressure Research on Materials

    Indian Academy of Sciences (India)

    Home; Journals; Resonance – Journal of Science Education; Volume 12; Issue 6. High Pressure Research on Materials - Production and Measurement of High Pressures in the Laboratory. P Ch Sahu N V Chandra Shekar. General Article Volume 12 Issue 6 June 2007 pp 10-23 ...

  1. High-Pressure Lightweight Thrusters

    Science.gov (United States)

    Holmes, Richard; McKechnie, Timothy; Shchetkovskiy, Anatoliy; Smirnov, Alexander

    2013-01-01

    Returning samples of Martian soil and rock to Earth is of great interest to scientists. There were numerous studies to evaluate Mars Sample Return (MSR) mission architectures, technology needs, development plans, and requirements. The largest propulsion risk element of the MSR mission is the Mars Ascent Vehicle (MAV). Along with the baseline solid-propellant vehicle, liquid propellants have been considered. Similar requirements apply to other lander ascent engines and reaction control systems. The performance of current state-ofthe- art liquid propellant engines can be significantly improved by increasing both combustion temperature and pressure. Pump-fed propulsion is suggested for a single-stage bipropellant MAV. Achieving a 90-percent stage propellant fraction is thought to be possible on a 100-kg scale, including sufficient thrust for lifting off Mars. To increase the performance of storable bipropellant rocket engines, a high-pressure, lightweight combustion chamber was designed. Iridium liner electrodeposition was investigated on complex-shaped thrust chamber mandrels. Dense, uniform iridium liners were produced on chamber and cylindrical mandrels. Carbon/carbon composite (C/C) structures were braided over iridium-lined mandrels and densified by chemical vapor infiltration. Niobium deposition was evaluated for forming a metallic attachment flange on the carbon/ carbon structure. The new thrust chamber was designed to exceed state-of-the-art performance, and was manufactured with an 83-percent weight savings. High-performance C/Cs possess a unique set of properties that make them desirable materials for high-temperature structures used in rocket propulsion components, hypersonic vehicles, and aircraft brakes. In particular, more attention is focused on 3D braided C/Cs due to their mesh-work structure. Research on the properties of C/Cs has shown that the strength of composites is strongly affected by the fiber-matrix interfacial bonding, and that weakening

  2. High temperature superconducting materials

    Energy Technology Data Exchange (ETDEWEB)

    Alario-Franco, M.A. [Universidad Complutense de Madrid (Spain). Facultad de Ciencias Quimicas

    1995-02-01

    The perovskite structure is the basis of all known high-temperature superconducting materials. Many of the most successful (highest T{sub c}) materials are based on mercury and thallium phases but, due to the high toxicity of the component compounds effort has been invested in the substitution of these elements with silver. Progress is reviewed. (orig.)

  3. High-temperature superconductors

    CERN Document Server

    Saxena, Ajay Kumar

    2010-01-01

    The present book aims at describing the phenomenon of superconductivity and high-temperature superconductors discovered by Bednorz and Muller in 1986. The book covers the superconductivity phenomenon, structure of high-Tc superconductors, critical currents, synthesis routes for high Tc materials, superconductivity in cuprates, the proximity effect and SQUIDs, theories of superconductivity and applications of superconductors.

  4. High temperature superconductivity: Proceedings

    Energy Technology Data Exchange (ETDEWEB)

    Bedell, K.S.; Coffey, D. (Los Alamos National Lab., NM (USA)); Meltzer, D.E. (Florida Univ., Gainesville, FL (USA)); Pines, D. (Illinois Univ., Urbana, IL (USA)); Schrieffer, J.R. (California Univ., Santa Barbara, CA (USA)) (eds.)

    1990-01-01

    This book is the result of a symposium at Los Alamos in 1989 on High Temperature Superconductivity. The topics covered include: phenomenology, quantum spin liquids, spin space fluctuations in the insulating and metallic phases, normal state properties, and numerical studies and simulations. (JF)

  5. Life at High Temperatures

    Indian Academy of Sciences (India)

    Home; Journals; Resonance – Journal of Science Education; Volume 10; Issue 9. Life at High Temperatures. Ramesh Maheshwari. General Article Volume 10 Issue 9 September 2005 pp 23-36. Fulltext. Click here to view fulltext PDF. Permanent link: http://www.ias.ac.in/article/fulltext/reso/010/09/0023-0036. Keywords.

  6. High temperature storage loop :

    Energy Technology Data Exchange (ETDEWEB)

    Gill, David Dennis; Kolb, William J.

    2013-07-01

    A three year plan for thermal energy storage (TES) research was created at Sandia National Laboratories in the spring of 2012. This plan included a strategic goal of providing test capability for Sandia and for the nation in which to evaluate high temperature storage (>650ÀC) technology. The plan was to scope, design, and build a flow loop that would be compatible with a multitude of high temperature heat transfer/storage fluids. The High Temperature Storage Loop (HTSL) would be reconfigurable so that it was useful for not only storage testing, but also for high temperature receiver testing and high efficiency power cycle testing as well. In that way, HTSL was part of a much larger strategy for Sandia to provide a research and testing platform that would be integral for the evaluation of individual technologies funded under the SunShot program. DOEs SunShot program seeks to reduce the price of solar technologies to 6/kWhr to be cost competitive with carbon-based fuels. The HTSL project sought to provide evaluation capability for these SunShot supported technologies. This report includes the scoping, design, and budgetary costing aspects of this effort

  7. Screening of hydrogen storage media applying high pressure thermogravimetry

    DEFF Research Database (Denmark)

    Bentzen, J.J.; Pedersen, Allan Schrøder; Kjøller, J.

    2001-01-01

    A number of commercially available hydride-forming alloys of the MmNi5–xSnx (Mm=mischmetal, a mixture of lanthanides) type were examined using a high pressure, high temperature microbalance,scanning electron microscopy and X-ray diffraction. Activation conditions, reversible storage capacity, wor...

  8. Magnetic and Superconducting Materials at High Pressures

    Energy Technology Data Exchange (ETDEWEB)

    Struzhkin, Viktor V. [Carnegie Inst. of Washington, Washington, DC (United States)

    2015-03-24

    The work concentrates on few important tasks in enabling techniques for search of superconducting compressed hydrogen compounds and pure hydrogen, investigation of mechanisms of high-Tc superconductivity, and exploring new superconducting materials. Along that route we performed several challenging tasks, including discovery of new forms of polyhydrides of alkali metal Na at very high pressures. These experiments help us to establish the experimental environment that will provide important information on the high-pressure properties of hydrogen-rich compounds. Our recent progress in RIXS measurements opens a whole field of strongly correlated 3d materials. We have developed a systematic approach to measure major electronic parameters, like Hubbard energy U, and charge transfer energy Δ, as function of pressure. This technique will enable also RIXS studies of magnetic excitations in iridates and other 5d materials at the L edge, which attract a lot of interest recently. We have developed new magnetic sensing technique based on optically detected magnetic resonance from NV centers in diamond. The technique can be applied to study superconductivity in high-TC materials, to search for magnetic transitions in strongly correlated and itinerant magnetic materials under pressure. Summary of Project Activities; development of high-pressure experimentation platform for exploration of new potential superconductors, metal polyhydrides (including newly discovered alkali metal polyhydrides), and already known superconductors at the limit of static high-pressure techniques; investigation of special classes of superconducting compounds (high-Tc superconductors, new superconducting materials), that may provide new fundamental knowledge and may prove important for application as high-temperature/high-critical parameter superconductors; investigation of the pressure dependence of superconductivity and magnetic/phase transformations in 3d transition metal compounds, including

  9. Phase Evolution of Hydrous Enstatite at High Pressures and Temperatures

    Science.gov (United States)

    Xu, J.; Zhang, D.; Dera, P.; Zhang, J.; Fan, D.

    2016-12-01

    Pyroxenes, including Mg-rich orthopyroxene and Ca-rich clinopyroxene, are among the most important minerals in the Earth's upper mantle (account for 20% by volume). Pyroxenes are major phases of harzburgite and lherzolite, which are important components of subducting slabs, so the high pressure behavior of pyroxenes should influence the physical properties of the subducted slabs. Therefore, understanding the phase evolution and thermal equations of state and of pyroxenes at elevated pressure and temperature is crucial to model theupper mantle and subduction zones. On the other hand, water is expected to be incorporated into pyroxene minerals in the upper mantle environments, yet the effect of water on the high pressure behavior of pyroxene has not been fully explored. In this study, we conducted high-pressure single-crystal X-ray diffraction study on hydrous enstatite sample (Mg2Si2O6) at ambient and high temperatures. High-pressure single-crystal diffraction experiments at ambient temperature were performed to 30 GPa at the experimental station 13BMC of the Advanced Photon Source. Two phase transformations were detected within the pressure range. High-pressure and high-temperature single crystal diffraction experiments were conducted to 27 GPa and 700 K also at 13BMC. From the experimental data, we derived the thermoelastic parameters of enstatite and performed structural refinements of enstatite at high pressures and temperatures, which is of implication for understanding of geophysics and geochemistry of subducting slabs.

  10. High temperature future

    Energy Technology Data Exchange (ETDEWEB)

    Sheinkopf, K. [Solar Energy Research and Education Foundation, Washington, DC (United States)

    1994-09-01

    During the past few years, there have been dramatic accomplishments and success of high temperature solar thermal systems and significant development of these systems. High temperature technologies, about 500 F and higher, such as dish engines, troughs, central receiver power towers and solar process heat systems, have been tested, demonstrated and used in an array of applications, including many cost-effective utility bulk power production and demand side supply projects in the United States. Large systems provide power and hot water to prisons, schools, nursing homes and other institutions. Joint ventures with industry, utility projects, laboratory design assistance and other activities are building a solid industry of US solar thermal systems ready for use today.

  11. High temperature superconductors

    CERN Document Server

    Paranthaman, Parans

    2010-01-01

    This essential reference provides the most comprehensive presentation of the state of the art in the field of high temperature superconductors. This growing field of research and applications is currently being supported by numerous governmental and industrial initiatives in the United States, Asia and Europe to overcome grid energy distribution issues. The technology is particularly intended for densely populated areas. It is now being commercialized for power-delivery devices, such as power transmission lines and cables, motors and generators. Applications in electric utilities include current limiters, long transmission lines and energy-storage devices that will help industries avoid dips in electric power.

  12. Decomposition of silicon carbide at high pressures and temperatures

    Energy Technology Data Exchange (ETDEWEB)

    Daviau, Kierstin; Lee, Kanani K. M.

    2017-11-01

    We measure the onset of decomposition of silicon carbide, SiC, to silicon and carbon (e.g., diamond) at high pressures and high temperatures in a laser-heated diamond-anvil cell. We identify decomposition through x-ray diffraction and multiwavelength imaging radiometry coupled with electron microscopy analyses on quenched samples. We find that B3 SiC (also known as 3C or zinc blende SiC) decomposes at high pressures and high temperatures, following a phase boundary with a negative slope. The high-pressure decomposition temperatures measured are considerably lower than those at ambient, with our measurements indicating that SiC begins to decompose at ~ 2000 K at 60 GPa as compared to ~ 2800 K at ambient pressure. Once B3 SiC transitions to the high-pressure B1 (rocksalt) structure, we no longer observe decomposition, despite heating to temperatures in excess of ~ 3200 K. The temperature of decomposition and the nature of the decomposition phase boundary appear to be strongly influenced by the pressure-induced phase transitions to higher-density structures in SiC, silicon, and carbon. The decomposition of SiC at high pressure and temperature has implications for the stability of naturally forming moissanite on Earth and in carbon-rich exoplanets.

  13. Electrokinetic high pressure hydraulic system

    Science.gov (United States)

    Paul, Phillip H.; Rakestraw, David J.; Arnold, Don W.; Hencken, Kenneth R.; Schoeniger, Joseph S.; Neyer, David W.

    2001-01-01

    An electrokinetic high pressure hydraulic pump for manipulating fluids in capillary-based systems. The pump uses electro-osmotic flow to provide a high pressure hydraulic system, having no moving mechanical parts, for pumping and/or compressing fluids, for providing valve means and means for opening and closing valves, for controlling fluid flow rate, and manipulating fluid flow generally and in capillary-based systems (Microsystems), in particular. The compact nature of the inventive high pressure hydraulic pump provides the ability to construct a micro-scale or capillary-based HPLC system that fulfills the desire for small sample quantity, low solvent consumption, improved efficiency, the ability to run samples in parallel, and field portability. Control of pressure and solvent flow rate is achieved by controlling the voltage applied to an electrokinetic pump.

  14. Electrokinetic high pressure hydraulic system

    Science.gov (United States)

    Paul, Phillip H.; Rakestraw, David J.

    2000-01-01

    A compact high pressure hydraulic pump having no moving mechanical parts for converting electric potential to hydraulic force. The electrokinetic pump, which can generate hydraulic pressures greater than 2500 psi, can be employed to compress a fluid, either liquid or gas, and manipulate fluid flow. The pump is particularly useful for capillary-base systems. By combining the electrokinetic pump with a housing having chambers separated by a flexible member, fluid flow, including high pressure fluids, is controlled by the application of an electric potential, that can vary with time.

  15. High temperature structural silicides

    Energy Technology Data Exchange (ETDEWEB)

    Petrovic, J.J.

    1997-03-01

    Structural silicides have important high temperature applications in oxidizing and aggressive environments. Most prominent are MoSi{sub 2}-based materials, which are borderline ceramic-intermetallic compounds. MoSi{sub 2} single crystals exhibit macroscopic compressive ductility at temperatures below room temperature in some orientations. Polycrystalline MoSi{sub 2} possesses elevated temperature creep behavior which is highly sensitive to grain size. MoSi{sub 2}-Si{sub 3}N{sub 4} composites show an important combination of oxidation resistance, creep resistance, and low temperature fracture toughness. Current potential applications of MoSi{sub 2}-based materials include furnace heating elements, molten metal lances, industrial gas burners, aerospace turbine engine components, diesel engine glow plugs, and materials for glass processing.

  16. High temperature measuring device

    Science.gov (United States)

    Tokarz, Richard D.

    1983-01-01

    A temperature measuring device for very high design temperatures (to 2,000.degree. C.). The device comprises a homogenous base structure preferably in the form of a sphere or cylinder. The base structure contains a large number of individual walled cells. The base structure has a decreasing coefficient of elasticity within the temperature range being monitored. A predetermined quantity of inert gas is confined within each cell. The cells are dimensionally stable at the normal working temperature of the device. Increases in gaseous pressure within the cells will permanently deform the cell walls at temperatures within the high temperature range to be measured. Such deformation can be correlated to temperature by calibrating similarly constructed devices under known time and temperature conditions.

  17. High temperature materials and mechanisms

    CERN Document Server

    2014-01-01

    The use of high-temperature materials in current and future applications, including silicone materials for handling hot foods and metal alloys for developing high-speed aircraft and spacecraft systems, has generated a growing interest in high-temperature technologies. High Temperature Materials and Mechanisms explores a broad range of issues related to high-temperature materials and mechanisms that operate in harsh conditions. While some applications involve the use of materials at high temperatures, others require materials processed at high temperatures for use at room temperature. High-temperature materials must also be resistant to related causes of damage, such as oxidation and corrosion, which are accelerated with increased temperatures. This book examines high-temperature materials and mechanisms from many angles. It covers the topics of processes, materials characterization methods, and the nondestructive evaluation and health monitoring of high-temperature materials and structures. It describes the ...

  18. High pressure neon arc lamp

    Science.gov (United States)

    Sze, Robert C.; Bigio, Irving J.

    2003-07-15

    A high pressure neon arc lamp and method of using the same for photodynamic therapies is provided. The high pressure neon arc lamp includes a housing that encloses a quantity of neon gas pressurized to about 500 Torr to about 22,000 Torr. At each end of the housing the lamp is connected by electrodes and wires to a pulse generator. The pulse generator generates an initial pulse voltage to breakdown the impedance of the neon gas. Then the pulse generator delivers a current through the neon gas to create an electrical arc that emits light having wavelengths from about 620 nanometers to about 645 nanometers. A method for activating a photosensitizer is provided. Initially, a photosensitizer is administered to a patient and allowed time to be absorbed into target cells. Then the high pressure neon arc lamp is used to illuminate the target cells with red light having wavelengths from about 620 nanometers to about 645 nanometers. The red light activates the photosensitizers to start a chain reaction that may involve oxygen free radicals to destroy the target cells. In this manner, a high pressure neon arc lamp that is inexpensive and efficiently generates red light useful in photodynamic therapy is provided.

  19. High Pressure Research on Materials

    Indian Academy of Sciences (India)

    basic types of apparatus that are now being used throughout the world. He was awarded the Nobel Prize in Physics in 1946. The static high pressure generating devices can be divided into two categories: piston-cylinder and opposed anvil devices. These devices with their pressure capabilities are listed in Figure 4.

  20. Intermolecular Interactions at high pressure

    DEFF Research Database (Denmark)

    Eikeland, Espen Zink

    2016-01-01

    In this project high-pressure single crystal X-ray diffraction has been combined with quantitative energy calculations to probe the energy landscape of three hydroquinone clathrates enclosing different guest molecules. The simplicity of the hydroquinone clathrate structures together with their st......In this project high-pressure single crystal X-ray diffraction has been combined with quantitative energy calculations to probe the energy landscape of three hydroquinone clathrates enclosing different guest molecules. The simplicity of the hydroquinone clathrate structures together....... High-pressure crystallography is the perfect method for studying intermolecular interactions, by forcing the molecules closer together. In all three studied hydroquinone clathrates, new pressure induced phase transitions have been discovered using a mixture of pentane and isopentane as the pressure...... transmitting medium. Through careful structural analysis combined with theoretical calculations, the structures of all the new high-pressure phases identified herein were determined. In the hydroquinone - methanol and hydroquinone - acetonitrile clathrate structures the phase transitions break the host...

  1. High Temperature Hybrid Elastomers

    Science.gov (United States)

    Drake, Kerry Anthony

    Conventional high temperature elastomers are produced by chain polymerization of olefinic or fluorinated olefinic monomers. Ultimate thermal stabilities are limited by backbone bond strengths, lower thermal stability of cross-link sites relative to backbone bonds, and depolymerization or "unzipping" at high temperatures. In order to develop elastomers with enhanced thermal stability, hybrid thermally cross-linkable polymers that consisted only of organic-inorganic and aromatic bonds were synthesized and evaluated. The addition of phenylethynyl or phenylacetylinic functional groups to these polymers resulted in conversion of the polymers into high temperature elastomers when cross-linked by thermal curing. Polyphenyoxydiphenylsilanes were synthesized via several different condensation reactions. Results of these synthetic reactions, which utilized both hydroquinone and biphenol as monomers, were systematically evaluated to determine the optimal synthetic conditions for subsequent endcapping reactions. It was determined that dichlorodiphenylsilane condensations with biphenol in toluene or THF were best suited for this work. Use of excess dichlorodiphenylsilane yielded polymers of appropriate molecular weights with terminal reactive chlorosilane groups that could be utilized for coupling with phenylethynyl reagents in a subsequent reaction. Two new synthetic routes were developed to endcap biphenoxysilanes with ethynyl containing substituents, to yield polymers with cross-linkable end groups. Endcapping by lithiumphenylacetylide and 4[(4-fluorophenylethynyl))phenol yielded two new polymers that could be thermally cross-linked on heating above 300 °C. Successful endcapping was verified chemically by 13C NMR, FTIR and Raman analysis. Exothermic peaks consistent with ethynyl curing reactions were observed in endcapped polymers by DSC. A new diacetylinic polymer was prepared through reaction of 4,4'-buta-1,3-diyne-1,4-diyldiphenol and dichlorodiphenylsilane. This

  2. Retrograde mineral and fluid evolution in high-pressure metapelites (Schistes Lustres unit, Western Alps).

    NARCIS (Netherlands)

    Agard, Ph.; Goffe, B.; Touret, J.L.R.; Vidal, O.

    2000-01-01

    Fluid inclusions have been analysed in successive generations of syn-metamorphic segregations within low-grade, high-pressure, low-temperature (HP-LT) metapelites from the Western Alps. Fluid composition was then compared to mass transfer deduced from outcrop-scale retrograde mineral reactions. Two

  3. Analysis of the high-temperature particulate collection problem

    Energy Technology Data Exchange (ETDEWEB)

    Razgaitis, R.

    1977-10-01

    Particulate agglomeration and separation at high temperatures and pressures are examined, with particular emphasis on the unique features of the direct-cycle application of fluidized-bed combustion. The basic long-range mechanisms of aerosol separation are examined, and the effects of high temperature and high pressure on usable collection techniques are assessed. Primary emphasis is placed on those avenues that are not currently attracting widespread research. The high-temperature, particulate-collection problem is surveyed, together with the peculiar requirements associated with operation of turbines with particulate-bearing gas streams. 238 references.

  4. HIGH TEMPERATURE VACUUM MIXER

    Directory of Open Access Journals (Sweden)

    E. D. Chertov

    2015-01-01

    Full Text Available The work is devoted to the creation of a new type of mixer to produce homogeneous mixtures of dissimilar materials applied to recycling of housing and communal services waste. The article describes the design of a dual-chamber device of the original high-temperature vacuum mixer, there investigated the processes occurring in the chambers of such devices. The results of theoretical and experimental research of the process of mixing recycled polyethylene with a mixture of "grinded food waste – Eco wool” are presented. The problem of the optimum choice of bending the curvilinear blades in the working volume of the seal, which is achieved by setting their profile in the form of involute arc of several circles of different radii, is examined . The dependences, allowing to define the limits of the changes of the main mode parameters the angular velocity of rotation of the working body of the mixer using two ways of setting the profile of the curvilinear blade mixer are obtained. Represented design of the mixer is proposed to use for a wide range of tasks associated with the mixing of the components with a strongly pronounced difference of physic al chemical properties and, in particular, in the production of composites out of housing and communal services waste.

  5. In-situ Nd isotope measurements on accessory minerals: Insights into isotope equilibration during metamorphism

    Science.gov (United States)

    Hammerli, Johannes; Spandler, Carl; Kemp, Tony; Pirard, Cassian

    2015-04-01

    Understanding isotope equilibration processes during metamorphism has huge implications for a range of geoscience applications, ranging from provenance studies of sedimentary units to the origin of magmas and ore bodies. Furthermore, recent claims of isotope disequilibrium situations during the melting of continental crust have questioned the reliability of using certain isotope systems to track magma sources. Our recent work investigated a prograde sequence of high-temperature, low-pressure (350-650 ˚C, ~3-5 kbar) metasedimentary rocks from the Mt. Lofty Ranges, South Australia that underwent widespread pervasive fluid flow at peak metamorphism. In situ Nd-isotope analyses by LA-MC-ICP-MS found that the detrital signature of apatite survives temperatures of 500 °C. However, the observed isotope equilibration of REE-bearing accessory minerals at ~600 °C, before the onset of partial melting, suggests that isotope disequilibrium is unlikely during high-grade metamorphism of upper crustal rocks where fluid induced melting takes place. Here, we extend our research to metasedimentary rocks from (ultra)-high pressure metamorphic terrains from northern New Caledonia, and Dabieshan, China that represent pressure and temperature conditions found in subduction zones. Our study helps to understand isotope equilibration processes from heterogeneous protoliths as well as the impact of retrogression and the resetting of isotope systems over a pressure-temperature range from ~350 °C to 700 °C and ~15 kbar to 40 kbar. Nd isotope analyses of apatite, allanite, titanite, xenotime, monazite, lawsonite and epidote in pelitic and psammitic samples allow the investigation of isotope equilibration on a mineral and sub-mineral scale, as well as comparison with traditional bulk rock isotope analyses. Our preliminary results show that under high-pressure conditions (~20 to 30 kbar) and temperatures to ~650 °C, REE-bearing phases show variable ɛNd values in some cases. These

  6. High-Pressure Design of Advanced BN-Based Materials

    Directory of Open Access Journals (Sweden)

    Oleksandr O. Kurakevych

    2016-10-01

    Full Text Available The aim of the present review is to highlight the state of the art in high-pressure design of new advanced materials based on boron nitride. Recent experimental achievements on the governing phase transformation, nanostructuring and chemical synthesis in the systems containing boron nitride at high pressures and high temperatures are presented. All these developments allowed discovering new materials, e.g., ultrahard nanocrystalline cubic boron nitride (nano-cBN with hardness comparable to diamond, and superhard boron subnitride B13N2. Thermodynamic and kinetic aspects of high-pressure synthesis are described based on the data obtained by in situ and ex situ methods. Mechanical and thermal properties (hardness, thermoelastic equations of state, etc. are discussed. New synthetic perspectives, combining both soft chemistry and extreme pressure–temperature conditions are considered.

  7. Advances in high temperature chemistry

    CERN Document Server

    Eyring, Leroy

    1969-01-01

    Advances in High Temperature Chemistry, Volume 2 covers the advances in the knowledge of the high temperature behavior of materials and the complex and unfamiliar characteristics of matter at high temperature. The book discusses the dissociation energies and free energy functions of gaseous monoxides; the matrix-isolation technique applied to high temperature molecules; and the main features, the techniques for the production, detection, and diagnosis, and the applications of molecular beams in high temperatures. The text also describes the chemical research in streaming thermal plasmas, as w

  8. Development and Application of Insulated Drill Pipe for High Temperature, High Pressure Drilling

    Energy Technology Data Exchange (ETDEWEB)

    Tom Champness; Tony Worthen; John Finger

    2008-12-31

    This project aimed to extend the insulated drill pipe (IDP) technology already demonstrated for geothermal drilling to HTHP drilling in deep gas reservoirs where temperatures are high enough to pose a threat to downhole equipment such as motors and electronics. The major components of the project were: a preliminary design; a market survey to assess industry needs and performance criteria; mechanical testing to verify strength and durability of IDP; and development of an inspection plan that would quantify the ability of various inspection techniques to detect flaws in assembled IDP. This report is a detailed description of those activities.

  9. Risk Associated With The Decompression Of High Pressure High Temperature Fluids - Study On Black Oil

    DEFF Research Database (Denmark)

    Figueroa, D. C.; Fosbøl, P. L.; Thomsen, K.

    2015-01-01

    that the final temperature of black oil increases upon adiabatic decompression. In the case of the isenthalpic process at initial conditions of the reservoir, e.g. 150°C and 1000 bars, it is found that the final temperature can increase to 173.7°C. At non-isenthalpic conditions the final temperature increases......Fluids produced from deep underground reservoirs may result in exponential increase in temperature. It is a consequence of adiabatic fluid decompression from the inverse Joule Thomson Effect (JTE). The phenomenon requires analysis in order to avoid any operational risks. This study evaluates...

  10. High-pressure high-temperature synthesis and structure of α-tetragonal boron

    Directory of Open Access Journals (Sweden)

    Evgeny A Ekimov and Igor P Zibrov

    2011-01-01

    Full Text Available ERRATUMThis is an Erratum for the article 2011 Sci. Technol. Adv. Mater. 12 055009The publisher regrets that there is a typographical error on page 2 of this article. The fourth sentence of section 3 should read as follows:The lines characteristic of B–H–B (1700–2000 cm-1 and B–H (2550–2650 cm-1 bonds of decaborane were not found in the Raman spectra of the crystals (figure 3 that confirms the complete decomposition of decaborane [19, 20].

  11. High Temperature, high pressure equation of state density correlations and viscosity correlations

    Energy Technology Data Exchange (ETDEWEB)

    Tapriyal, D.; Enick, R.; McHugh, M.; Gamwo, I.; Morreale, B.

    2012-07-31

    Global increase in oil demand and depleting reserves has derived a need to find new oil resources. To find these untapped reservoirs, oil companies are exploring various remote and harsh locations such as deep waters in Gulf of Mexico, remote arctic regions, unexplored deep deserts, etc. Further, the depth of new oil/gas wells being drilled has increased considerably to tap these new resources. With the increase in the well depth, the bottomhole temperature and pressure are also increasing to extreme values (i.e. up to 500 F and 35,000 psi). The density and viscosity of natural gas and crude oil at reservoir conditions are critical fundamental properties required for accurate assessment of the amount of recoverable petroleum within a reservoir and the modeling of the flow of these fluids within the porous media. These properties are also used to design appropriate drilling and production equipment such as blow out preventers, risers, etc. With the present state of art, there is no accurate database for these fluid properties at extreme conditions. As we have begun to expand this experimental database it has become apparent that there are neither equations of state for density or transport models for viscosity that can be used to predict these fundamental properties of multi-component hydrocarbon mixtures over a wide range of temperature and pressure. Presently, oil companies are using correlations based on lower temperature and pressure databases that exhibit an unsatisfactory predictive capability at extreme conditions (e.g. as great as {+-} 50%). From the perspective of these oil companies that are committed to safely producing these resources, accurately predicting flow rates, and assuring the integrity of the flow, the absence of an extensive experimental database at extreme conditions and models capable of predicting these properties over an extremely wide range of temperature and pressure (including extreme conditions) makes their task even more daunting.

  12. First-principles calculation of thermal conductivity of silicate perovskite at high pressures and high temperatures

    Science.gov (United States)

    Dong, Jianjun; Tang, Xiaoli; Kavner, Abby; Ntam, Moses

    2011-03-01

    The lattice thermal conductivity of silicate perovskite, the most abundant mineral in the Earth's lower mantle, is calculated by combining the first-principles electronic structure theory and Peierls-Boltzmann transport theory. The phonon scattering rate due to lattice anharmonicity and Mg/Fe mass disorder is evaluated for each mode at the extreme P-T conditions of the lower mantle. The predicted thermal conductivity of single crystal MgSiO3 perovskite at ambient condition, about 5.7 W/m/K, is in excellent agreement with experiment. Adding about 6% Fe will lower the thermal conductivity by nearly 40%. Our calculation also reveals an unique pressure dependence for the thermal conductivity of perovskite, and the calculated thermal conductivity of iron bearing perovskite is almost an order of magnitude lower than the previously estimates based on long extrapolation of single crystal data. Including a re-evaluation of radiative contribution, we discuss the implications of our results for the heat flow in deep Earth. Funded by NSF (EAR-0757847).

  13. High-pressure high-temperature equation of state of graphite from Monte Carlo simulations

    NARCIS (Netherlands)

    Colonna, F.; Fasolino, A.; Meijer, E.J.

    2011-01-01

    The thermoelastic behavior of graphite is experimentally accessible in a limited range of pressures and temperatures. Here we perform Monte Carlo simulations based on the accurate long range carbon bond-order potential (LCBOPII) in order to study graphite in a wider range of thermodynamic

  14. Metamorphic zirconology of continental subduction zones

    Science.gov (United States)

    Chen, Ren-Xu; Zheng, Yong-Fei

    2017-09-01

    Zircon is widely used to date geological events and trace geochemical sources in high-pressure (HP) to ultrahigh-pressure (UHP) metamorphic rocks of continental subduction zones. However, protolith zircons may be modified by three different types of metamorphic recrystallization via mechanisms of solid-state transformation, metasomatic alteration and dissolution reprecipitation; new zircon growth may be induced by dehydration reactions below the wet solidus of crustal rocks (metamorphic zircon) or peritectic reactions above the wet solidus (peritectic zircon). As a consequence, there are different origins of zircon domains in high-grade metamorphic rocks from collisional orogens. Thus, determining the nature of individual zircon domains is substantial to correct interpretation of their origin in studies of isotopic geochronology and geochemical tracing. We advocate an integrated study of zircon mineragraphy (internal structure and external morphology), U-Pb ages, mineral inclusions, trace elements, and Lu-Hf and O isotope compositions. Only in this way we are in a position to advance the simple zircon applications to metamorphic zirconology, enabling discrimination between the different origins of zircon and providing constraints on the property of fluid activity at subduction-zone conditions. The metamorphic recrystallization of protolith zircons and the new growth of metamorphic and peritectic zircons are prominent in HP to UHP metamorphic rocks of collisional orogens. These different types of recrystallized and grown zircons can be distinguished by their differences in element and isotope compositions. While the protolith nature of metamorphosed rocks dictates water availability, the P-T conditions of subduction zones dictate the property of subduction-zone fluids. The fluids of different properties may be produced at different positions of subducting and exhuming crustal slices, and they may physically and chemically mix with each other in continental

  15. High Temperature Aquifer Storage

    Science.gov (United States)

    Ueckert, Martina; Niessner, Reinhard; Baumann, Thomas

    2016-04-01

    Combined heat and power generation (CHP) is highly efficient because excess heat is used for heating and/or process energy. However, the demand of heat energy varies considerably throughout the year while the demand for electrical energy is rather constant. It seems economically and ecologically highly beneficial for municipalities and large power consumers such as manufacturing plants to store excess heat in groundwater aquifers and to recuperate this energy at times of higher demand. Within the project High Temperature Aquifer Storage, scientists investigate storage and recuperation of excess heat energy into the bavarian Malm aquifer. Apart from high transmissivity and favorable pressure gradients, the hydrochemical conditions are crucial for long-term operation. An enormous technical challenge is the disruption of the carbonate equilibrium - modeling results indicated a carbonate precipitation of 10 - 50 kg/d in the heat exchangers. The test included five injection pulses of hot water (60 °C up to 110 °C) and four tracer pulses, each consisting of a reactive and a conservative fluorescent dye, into a depth of about 300 m b.s.l. resp. 470 m b.s.l. Injection and production rates were 15 L/s. To achieve the desired water temperatures, about 4 TJ of heat energy were necessary. Electrical conductivity, pH and temperature were recorded at a bypass where also samples were taken. A laboratory container at the drilling site was equipped for analysing the concentration of the dyes and the major cations at sampling intervals of down to 15 minutes. Additional water samples were taken and analysed in the laboratory. The disassembled heat exchanger prooved that precipitation was successfully prevented by adding CO2 to the water before heating. Nevertheless, hydrochemical data proved both, dissolution and precipitation processes in the aquifer. This was also suggested by the hydrochemical modelling with PhreeqC and is traced back to mixture dissolution and changing

  16. Carbon nanostructures under high pressure

    CERN Document Server

    Sundqvist, B

    2002-01-01

    Results from recent high-pressure experiments in the field of fullerenes are briefly reviewed. In particular, new results on one-, two- and three-dimensional polymerized C sub 6 sub 0 and C sub 7 sub 0 are discussed. Results discussed include the first synthesis of a well defined, one-dimensional polymer based on C sub 7 sub 0 , transformations from two-dimensional (2D) to three-dimensional phases in C sub 6 sub 0 , and doping of 2D C sub 6 sub 0 polymers.

  17. High-Temperature Piezoelectric Sensing

    Directory of Open Access Journals (Sweden)

    Xiaoning Jiang

    2013-12-01

    Full Text Available Piezoelectric sensing is of increasing interest for high-temperature applications in aerospace, automotive, power plants and material processing due to its low cost, compact sensor size and simple signal conditioning, in comparison with other high-temperature sensing techniques. This paper presented an overview of high-temperature piezoelectric sensing techniques. Firstly, different types of high-temperature piezoelectric single crystals, electrode materials, and their pros and cons are discussed. Secondly, recent work on high-temperature piezoelectric sensors including accelerometer, surface acoustic wave sensor, ultrasound transducer, acoustic emission sensor, gas sensor, and pressure sensor for temperatures up to 1,250 °C were reviewed. Finally, discussions of existing challenges and future work for high-temperature piezoelectric sensing are presented.

  18. Charnockite microstructures: From magmatic to metamorphic

    Directory of Open Access Journals (Sweden)

    Jacques L.R. Touret

    2012-11-01

    Full Text Available Charnockites sensu lato (charnockite-enderbite series are lower crustal felsic rocks typically characterised by the presence of anhydrous minerals including orthopyroxene and garnet. They either represent dry (H2O-poor felsic magmas that are emplaced in the lower crust or granitic intrusions that have been dehydrated during a subsequent granulite facies metamorphic event. In the first case, post-magmatic high-temperature recrystallisation may result in widespread metamorphic granulite microstructures, superimposed or replacing the magmatic microstructures. Despite recrystallisation, magmatic remnants may still be found, notably in the form of melt-related microstructures such as melt inclusions. For both magmatic charnockites and dehydrated granites, subsequent fluid-mineral interaction at intergrain boundaries during retrogradation are documented by microstructures including K-feldspar microveins and myrmekites. They indicate that a large quantity of low-H2O activity salt-rich brines, were present (together with CO2 under immiscible conditions in the lower crust.

  19. Shock melt veins of Tenham chondrite as a possible paleomagnetic recorder: Rock magnetism and high-pressure minerals

    Science.gov (United States)

    Sato, Yugo; Nakamura, Norihiro

    2010-04-01

    Heavily shocked meteorites of shock stages S5 and S6 contain shock-induced melt veins (SMVs). SMVs might have reset the remanence of an asteroidal metamorphism at the time of giant collisions against a chondrite parent body. Here we present micropaleomagnetic and petrologic studies of SMVs in L6S5 Tenham chondrite with ˜500 μm thick black veins enclosing high-pressure minerals such as ringwoodite. Paleomagnetic data show that the high-temperature (HT, 200°C-650°C) and high-coercivity (HC, 20-100 mT) stable components of SMVs formed a cluster even from different portions of SMV, whereas the stable HT component of surrounding host rock showed a scattered orientation under stereonet projection. The host rock HC components form a girdle between the mixing of SMVs and unknown overprints, tracing the magnetic susceptibility foliation. Magnetic force microscopy and backscattered electron images confirmed kamacite and taenite assemblages in iron sulfides as remanence-carrying minerals in SMVs. Hysteresis data of SMVs revealed the presence of single-domain (SD) FeNi metals with Mrs/Ms = ˜0.1 and Hrc/Hc = ˜2, although these parameters are only applicable to magnetite. Because the metastable ringwoodite in SMVs transforms back to olivine at 188°C for 1000 Myr (metamorphism) or at 900°C for 1 h (postshock heating), the preservation of ringwoodite suggests that SMVs have not experienced either thermal condition. The magnetic time-temperature relation for SD FeNi metals suggested that 200°C unblocking temperature corresponds to the storage time of 100 years for kamacite and 4500 Myr for taenite at room temperature. The difference of HT components discards the possibility of postshock heating. Therefore, the SMV's remanence is a characteristic shock-induced thermal remanence that has newly been acquired during hypervelocity collision under a cryptic magnetic field.

  20. High pressure processing of meat

    DEFF Research Database (Denmark)

    Grossi, Alberto; Christensen, Mette; Ertbjerg, Per

    Abstract Background: The research of high pressure (HP) processing of meat based foods needs to address how pressure affects protein interactions, aggregation and/or gelation. The understanding of the gel forming properties of myofibrillar components is fundamental for the development of muscle...... based products (Chapleau et al., 2004;Colmenero, 2002). Object: The aim was to study the rheological properties of pork meat emulsion exposed to HP and the effect of HP on the aggregation state of myofibrillar proteins. To address the role of cathepsin in myofibrillar protein degradation the changes...... in the myofibrillar protein pattern and HP-induced change in activity of cathepsin B and L were investigated. Results: In this study we showed that HP treatment of pork meat emulsion, ranging from 0.1 to 800 MPa, induced protein gel formation as shown by the increased Young’s modulus (Fig.1). Analysis of SDS...

  1. Synthesis and stability of hydrogen selenide compounds at high pressure

    Energy Technology Data Exchange (ETDEWEB)

    Pace, Edward J.; Binns, Jack; Alvarez, Miriam Pena; Dalladay-Simpson, Philip; Gregoryanz, Eugene; Howie, Ross T. (Edinburgh); (CHPSTAR- China)

    2017-11-14

    The observation of high-temperature superconductivity in hydride sulfide (H2S) at high pressures has generated considerable interest in compressed hydrogen-rich compounds. High-pressure hydrogen selenide (H2Se) has also been predicted to be superconducting at high temperatures; however, its behaviour and stability upon compression remains unknown. In this study, we synthesize H2Se in situ from elemental Se and molecular H2 at pressures of 0.4 GPa and temperatures of 473 K. On compression at 300 K, we observe the high-pressure solid phase sequence (I-I'-IV) of H2Se through Raman spectroscopy and x-ray diffraction measurements, before dissociation into its constituent elements. Through the compression of H2Se in H2 media, we also observe the formation of a host-guest structure, (H2Se)2H2, which is stable at the same conditions as H2Se, with respect to decomposition. These measurements show that the behaviour of H2Se is remarkably similar to that of H2S and provides further understanding of the hydrogen chalcogenides under pressure.

  2. Fluids in metamorphic rocks

    NARCIS (Netherlands)

    Touret, J.L.R.

    2001-01-01

    Basic principles for the study of fluid inclusions in metamorphic rocks are reviewed and illustrated. A major problem relates to the number of inclusions, possibly formed on a wide range of P-T conditions, having also suffered, in most cases, extensive changes after initial trapping. The

  3. Back-transformation of high-pressure minerals in shocked chondrites: Low-pressure mineral evidence for strong shock

    OpenAIRE

    Hu, Jinping; Sharp, Thomas G.

    2017-01-01

    Post-shock annealing of meteorites can destroy their shock-induced features, particularly high-pressure minerals, and complicate the estimation of impact pressure–temperature conditions. However, distinguishing post-shock annealing features from thermal metamorphism effects can be practically difficult. Here we report results from Mbale, a highly shocked L chondrite, to investigate the mechanisms, kinetics and identification criteria for post-shock annealing of high-pressure signatures. Olivi...

  4. High temperature superconductor accelerator magnets

    NARCIS (Netherlands)

    van Nugteren, J.

    2016-01-01

    For future particle accelerators bending dipoles are considered with magnetic fields exceeding 20T. This can only be achieved using high temperature superconductors (HTS). These exhibit different properties from classical low temperature superconductors and still require significant research and

  5. High Temperature Electrostrictive Ceramics Project

    Data.gov (United States)

    National Aeronautics and Space Administration — TRS Technologies proposes to develop high temperature electrostrictors from bismuth-based ferroelectrics. These materials will exhibit high strain and low loss in...

  6. High Temperature Materials Laboratory (HTML)

    Data.gov (United States)

    Federal Laboratory Consortium — The six user centers in the High Temperature Materials Laboratory (HTML), a DOE User Facility, are dedicated to solving materials problems that limit the efficiency...

  7. Equation of state of liquid Indium under high pressure

    Directory of Open Access Journals (Sweden)

    Huaming Li

    2015-09-01

    Full Text Available We apply an equation of state of a power law form to liquid Indium to study its thermodynamic properties under high temperature and high pressure. Molar volume of molten indium is calculated along the isothermal line at 710K within good precision as compared with the experimental data in an externally heated diamond anvil cell. Bulk modulus, thermal expansion and internal pressure are obtained for isothermal compression. Other thermodynamic properties are also calculated along the fitted high pressure melting line. While our results suggest that the power law form may be a better choice for the equation of state of liquids, these detailed predictions are yet to be confirmed by further experiment.

  8. Leak Detection of High Pressure Feedwater Heater Using Empirical Models

    Energy Technology Data Exchange (ETDEWEB)

    Lee, Song Kyu; Kim, Eun Kee [Korea Power Engineering Company, Daejeon (Korea, Republic of); Heo, Gyun Young [Kyung Hee University, Yongin (Korea, Republic of); An, Sang Ha [Korea Advanced Institute of Science and Technology, Daejeon (Korea, Republic of)

    2009-10-15

    Even small leak from tube side or pass partition within the high pressure feedwater heater (HPFWH) causes a significant deficiency in its performance. Plant operation under the HPFWH leak condition for long time will result in cost increase. Tube side leak within HPFWH can produce the high velocity jet of water and it can cause neighboring tube failures. However, most of plants are being operated without any information for internal leaks of HPFWH, even though it is prone to be damaged under high temperature and high pressure operating conditions. Leaks from tubes and/or pass partition of HPFWH occurred in many nuclear power plants, for example, Mihama PS-2, Takahama PS-2 and Point Beach Nuclear Plant Unit 1. If the internal leaks of HPFWH are monitored, the cost can be reduced by inexpensive repairs relative to loss in performance and moreover plant shutdown as well as further tube damages can be prevented.

  9. K-Ar ages of the rocks of two kinds existed in the Kamuikotan metamorphic rocks located in the Horokanai district, Hokkaido

    Energy Technology Data Exchange (ETDEWEB)

    Imaizumi, M. (Chiba Univ. (Japan). Faculty of Science); Ueda, Y.

    1981-03-01

    In the Fransiscan metamorphic rocks known as the typical high-pressure type metamorphic belts, existence of the blocks of high grade metamorphic rocks of older age in the widely distributed low grade ones of younger age is commonly noticed. This feature has been explained as a phenomenon that the blocks had been tectonically mixed with the surroundings - so-called tectonic blocks - based on the absolute age determination of the component minerals. The Kamuikotan tectonic belt is a melange zone in which occur various kinds of metamorphic rocks of high-pressure and low-pressure types. The high-pressure Kamuikotan metamorphic rocks can be classified into two kinds based upon the modes of occurrence and mineral paragenesis. One is the low grade metamorphic rocks of greenschist and glaucophane schist and the other, the high grade metamorphic rocks of epidote glaucophane schist and epidote amphibolite. The high grade metamorphic rocks always occur as isolated blocks in the low grade metamorphics and associated serpentinite. The report discusses the age of muscovites separated from the two types of high-pressure Kamuikotan metamorphic rocks in the Horokanai district, central Hokkaido. The muscovites separated from the low grade metamorphics of the district give the age of 72 - 116 m.y., while those separated from the high grade metamorphics give the age of 132 - 145 m.y. These ages seem to agree with the idea that the blocks of high grade metamorphics (epidote glaucophane schist and epidote amphibolite) would be the ''tectonic blocks'' - namely the fragments tectonically mixed into the low grade metamorphics of younger age.

  10. High Temperature Fluoride Salt Test Loop

    Energy Technology Data Exchange (ETDEWEB)

    Aaron, Adam M. [Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States); Cunningham, Richard Burns [Univ. of Tennessee, Knoxville, TN (United States); Fugate, David L. [Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States); Holcomb, David Eugene [Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States); Kisner, Roger A. [Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States); Peretz, Fred J. [Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States); Robb, Kevin R. [Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States); Wilson, Dane F. [Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States); Yoder, Jr, Graydon L. [Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States)

    2015-12-01

    Effective high-temperature thermal energy exchange and delivery at temperatures over 600°C has the potential of significant impact by reducing both the capital and operating cost of energy conversion and transport systems. It is one of the key technologies necessary for efficient hydrogen production and could potentially enhance efficiencies of high-temperature solar systems. Today, there are no standard commercially available high-performance heat transfer fluids above 600°C. High pressures associated with water and gaseous coolants (such as helium) at elevated temperatures impose limiting design conditions for the materials in most energy systems. Liquid salts offer high-temperature capabilities at low vapor pressures, good heat transport properties, and reasonable costs and are therefore leading candidate fluids for next-generation energy production. Liquid-fluoride-salt-cooled, graphite-moderated reactors, referred to as Fluoride Salt Reactors (FHRs), are specifically designed to exploit the excellent heat transfer properties of liquid fluoride salts while maximizing their thermal efficiency and minimizing cost. The FHR s outstanding heat transfer properties, combined with its fully passive safety, make this reactor the most technologically desirable nuclear power reactor class for next-generation energy production. Multiple FHR designs are presently being considered. These range from the Pebble Bed Advanced High Temperature Reactor (PB-AHTR) [1] design originally developed by UC-Berkeley to the Small Advanced High-Temperature Reactor (SmAHTR) and the large scale FHR both being developed at ORNL [2]. The value of high-temperature, molten-salt-cooled reactors is also recognized internationally, and Czechoslovakia, France, India, and China all have salt-cooled reactor development under way. The liquid salt experiment presently being developed uses the PB-AHTR as its focus. One core design of the PB-AHTR features multiple 20 cm diameter, 3.2 m long fuel channels

  11. Moire interferometry at high temperatures

    Science.gov (United States)

    Wu, Jau-Je

    1992-01-01

    The objective of this study was to provide an optical technique allowing full-field in-plane deformation measurements at high temperature by using high-sensitivity moire interferometry. This was achieved by a new approach of performing deformation measurements at high temperatures in a vacuum oven using an achromatic interferometer. The moire system setup was designed with particular consideration for the stability, compactness, flexibility, and ease of control. A vacuum testing environment was provided to minimize the instability of the patterns by protecting the optical instruments from the thermal convection currents. Also, a preparation procedure for the high-temperature specimen grating was developed with the use of the plasma-etched technique. Gold was used as a metallic layer in this procedure. This method was demonstrated on a ceramic block, metal/matrix composite, and quartz. Thermal deformation of a quartz specimen was successfully measured in vacuum at 980 degrees Celsius, with the sensitivity of 417 nm per fringe. The stable and well-defined interference patterns confirmed the feasibility of the developments, including the high-temperature moire system and high-temperature specimen grating. The moire system was demonstrated to be vibration-insensitive. Also, the contrast of interference fringes at high temperature was enhanced by means of a spatial filter and a narrow band interference filter to minimize the background noise from the flow of the specimen and heater. The system was verified by a free thermal expansion test of an aluminum block. Good agreement demonstrated the validity of the optical design. The measurements of thermal deformation mismatch were performed on a graphite/epoxy composite, a metal/matrix composite equipped with an optical fiber, and a cutting tool bit. A high-resolution data-reduction technique was used to measure the strain distribution of the cutting tool bit.

  12. High temperature superconductor current leads

    Science.gov (United States)

    Hull, John R.; Poeppel, Roger B.

    1995-01-01

    An electrical lead having one end for connection to an apparatus in a cryogenic environment and the other end for connection to an apparatus outside the cryogenic environment. The electrical lead includes a high temperature superconductor wire and an electrically conductive material distributed therein, where the conductive material is present at the one end of the lead at a concentration in the range of from 0 to about 3% by volume, and at the other end of the lead at a concentration of less than about 20% by volume. Various embodiments are shown for groups of high temperature superconductor wires and sheaths.

  13. High temperature corrosion in gasifiers

    Directory of Open Access Journals (Sweden)

    Wate Bakker

    2004-03-01

    Full Text Available Several commercial scale coal gasification combined cycle power plants have been built and successfully operated during the last 5-10 years. Supporting research on materials of construction has been carried out for the last 20 years by EPRI and others. Emphasis was on metallic alloys for heat exchangers and other components in contact with hot corrosive gases at high temperatures. In this paper major high temperature corrosion mechanisms, materials performance in presently operating gasifiers and future research needs will be discussed.

  14. The High-Pressure Assemblage Majorite-Pyrope Solid Solution + Magnesiowustite: A New Constraint on the High Pressure and Temperature History of Shock Melt Veins in Chondrites

    Science.gov (United States)

    Chen, M.; Sharp, T. G.; El Goresy, A.; Wopenka, B.; Xie, X.

    1996-03-01

    Two coexisting distinct high pressure assemblages were discovered in shock melt veins of the Sixiangkou (L6) chondrite: (1) majorite-pyrope(sub)ss + magnesiowustite and (2) ringwoodite + low-Ca majorite. The majorite-pyrope(sub)ss + magnesiowustite evidently crystallized from a dense melt of bulk Sixiangkou composition that was produced by shock-fusion under high pressures and temperatures, whereas ringwoodite and low-Ca majorite in the second assemblage were formed by solid state transformation of olivine and low-Ca pyroxene originally present in the meteorite. The two high pressure assemblages indicate a duration over a time on the order of seconds under a high pressure (20-24 GPa) and high temperature (2050-2300 degrees C) regime.

  15. (Krauss) at constant high temperatures

    African Journals Online (AJOL)

    Snail Research Unit of the SAMRC and Department of Zoology, Potchefstroom University for CHE,. Potchefstroom. The survival of the freshwater snail species Bulinus africanus, Bulinus g/obosus and Biompha/aria pfeifferi at extreme high temperatures was experimentally investigated. Snails were exposed to temperatures ...

  16. High Temperature Superconductor Machine Prototype

    DEFF Research Database (Denmark)

    Mijatovic, Nenad; Jensen, Bogi Bech; Træholt, Chresten

    2011-01-01

    A versatile testing platform for a High Temperature Superconductor (HTS) machine has been constructed. The stationary HTS field winding can carry up to 10 coils and it is operated at a temperature of 77K. The rotating armature is at room temperature. Test results and performance for the HTS field...

  17. High-Temperature Optical Sensor

    Science.gov (United States)

    Adamovsky, Grigory; Juergens, Jeffrey R.; Varga, Donald J.; Floyd, Bertram M.

    2010-01-01

    A high-temperature optical sensor (see Figure 1) has been developed that can operate at temperatures up to 1,000 C. The sensor development process consists of two parts: packaging of a fiber Bragg grating into a housing that allows a more sturdy thermally stable device, and a technological process to which the device is subjected to in order to meet environmental requirements of several hundred C. This technology uses a newly discovered phenomenon of the formation of thermally stable secondary Bragg gratings in communication-grade fibers at high temperatures to construct robust, optical, high-temperature sensors. Testing and performance evaluation (see Figure 2) of packaged sensors demonstrated operability of the devices at 1,000 C for several hundred hours, and during numerous thermal cycling from 400 to 800 C with different heating rates. The technology significantly extends applicability of optical sensors to high-temperature environments including ground testing of engines, flight propulsion control, thermal protection monitoring of launch vehicles, etc. It may also find applications in such non-aerospace arenas as monitoring of nuclear reactors, furnaces, chemical processes, and other hightemperature environments where other measurement techniques are either unreliable, dangerous, undesirable, or unavailable.

  18. Chemistry of high temperature superconductors

    CERN Document Server

    1991-01-01

    This review volume contains the most up-to-date articles on the chemical aspects of high temperature oxide superconductors. These articles are written by some of the leading scientists in the field and includes a comprehensive list of references. This is an essential volume for researchers working in the fields of ceramics, materials science and chemistry.

  19. High temperature component life assessment

    CERN Document Server

    Webster, G A

    1994-01-01

    The aim of this book is to investigate and explain the rapid advances in the characterization of high temperature crack growth behaviour which have been made in recent years, with reference to industrial applications. Complicated mathematics has been minimized with the emphasis placed instead on finding solutions using simplified procedures without the need for complex numerical analysis.

  20. Properties of high temperature SQUIDS

    Energy Technology Data Exchange (ETDEWEB)

    Falco, C. M.; Wu, C. T.

    1978-01-01

    A review is given of the present status of weak links and dc and rf biased SQUIDs made with high temperature superconductors. A method for producing reliable, reproducible devices using Nb/sub 3/Sn is outlined, and comments are made on directions future work should take.

  1. High-temperature flooding injury

    Science.gov (United States)

    This problem, also called scald, is most serious in the hot desert valleys of the southwestern United States, subtropical regions in eastern Australia, and western Asia and northern Africa (Middle East) where fields are established and irrigated under high temperatures. The disorder also occurs to...

  2. Modelling Metamorphism by Abstract Interpretation

    Science.gov (United States)

    Dalla Preda, Mila; Giacobazzi, Roberto; Debray, Saumya; Coogan, Kevin; Townsend, Gregg M.

    Metamorphic malware apply semantics-preserving transformations to their own code in order to foil detection systems based on signature matching. In this paper we consider the problem of automatically extract metamorphic signatures from these malware. We introduce a semantics for self-modifying code, later called phase semantics, and prove its correctness by showing that it is an abstract interpretation of the standard trace semantics. Phase semantics precisely models the metamorphic code behavior by providing a set of traces of programs which correspond to the possible evolutions of the metamorphic code during execution. We show that metamorphic signatures can be automatically extracted by abstract interpretation of the phase semantics, and that regular metamorphism can be modelled as finite state automata abstraction of the phase semantics.

  3. Pargasite at high pressure and temperature

    Science.gov (United States)

    Comboni, Davide; Lotti, Paolo; Gatta, G. Diego; Merlini, Marco; Liermann, Hanns-Peter; Frost, Daniel J.

    2017-08-01

    The P-T phase stability field, the thermoelastic behavior and the P-induced deformation mechanisms at the atomic scale of pargasite crystals, from the "phlogopite peridotite unit" of the Finero mafic-ultramafic complex (Ivrea-Verbano Formation, Italy), have been investigated by a series of in situ experiments: (a) at high pressure (up to 20.1 GPa), by single-crystal synchrotron X-ray diffraction with a diamond anvil cell, (b) at high temperature (up to 823 K), by powder synchrotron X-ray diffraction using a hot air blower device, and (c) at simultaneous HP-HT conditions, by single-crystal synchrotron X-ray diffraction with a resistive-heated diamond anvil cell (P max = 16.5 GPa, T max = 1200 K). No phase transition has been observed within the P-T range investigated. At ambient T, the refined compressional parameters, calculated by fitting a second-order Birch-Murnaghan Equation of State (BM-EoS), are: V 0 = 915.2(8) Å3 and K P0,T0 = 95(2) GPa (β P0,T0 = 0.0121(2) GPa-1) for the unit-cell volume; a 0 = 9.909(4) Å and K(a) P0,T0 = 76(2) GPa for the a-axis; b 0 = 18.066(7) Å and K(b) P0,T0 = 111(2) GPa for the b-axis; c 0 = 5.299(5) Å and K(c) P0,T0 = 122(12) GPa for the c-axis [K(c) P0,T0 K(b) P0,T0 > K(a) P0,T0]. The high-pressure structure refinements (at ambient T) show a moderate contraction of the TO4 double chain and a decrease of its bending in response to the hydrostatic compression, along with a pronounced compressibility of the A- and M(4)-polyhedra [K P0, T0(A) = 38(2) GPa, K P0, T0(M4) = 79(5) GPa] if compared to the M(1)-, M(2)-, M(3)-octahedra [K P0, T0(M1,2,3) ≤ 120 GPa] and to the rigid tetrahedra [K P0, T0(T1,T2) 300 GPa]. The thermal behavior, at ambient pressure up to 823 K, was modelled with Berman's formalism, which gives: V 0 = 909.1(2) Å3, α0 = 2.7(2)·10-5 K-1 and α1 = 1.4(6)·10-9 K-2 [with α0(a) = 0.47(6)·10-5 K-1, α0(b) = 1.07(4)·10-5 K-1, and α0(c) = 0.97(7)·10-5 K-1]. The petrological implications for the experimental

  4. World of high pressure. Koatsuryoku no sekai

    Energy Technology Data Exchange (ETDEWEB)

    Moritoki, M.; Kanda, T. (Kobe Steel, Ltd., Kobe (Japan))

    1993-05-01

    The present article describes development and current status of high pressure technology. It introduces applications of high pressure technology to chemical reactions and processings, utilizations of phase changes and supercritical fluids, and applications of high pressure to food processings. Contributions of high pressure technology to synthetic chemistry are mentioned as for industrialization of syntheses of ammonia, urea and methanol, and invention of synthesis of polyethylene. Processing technologies utilizing high pressure are also mentioned as for cold isostatic pressing, hot isostatic pressing, hydrostatic extrusion technique, water jet working technique, and explosive forming technique. Introduced are application of phase changes under high pressure, such as high pressure synthesis of diamond and pressurized crystallization technology, and supercritical extraction technology using water and carbon dioxide. Pressurized food processings of mandarin orange, jam, and grapefruit are described. Furthermore, current status of fundamental technologies of high pressure installations is provided as for pressure vessel technology, pressure generation and control technology, and pressure sealing technology. 12 refs., 15 figs., 1 tab.

  5. High pressure studies of molecular lumenescence

    Energy Technology Data Exchange (ETDEWEB)

    Drickamer, H.G.

    1982-01-01

    The studies of high pressure molecular luminescence reviewed, along with results for inorganic systems discussed elsewhere, provide evidence about the versatility and power of high pressure as a tool for characterizing electronic states, testing theories concerning electronic phenomena, and generally obtaining a better understanding of electronic behavior in condensed systems. 16 figures.

  6. High pressure effects on fruits and vegetables

    NARCIS (Netherlands)

    Timmermans, R.A.H.; Matser, A.M.

    2016-01-01

    The chapter provides an overview on different high pressure based treatments (high pressure pasteurization, blanching, pressure-assisted thermal processing, pressure-shift freezing and thawing) available for the preservation of fruits and vegetable products and extending their shelf life. Pressure

  7. Coal swelling and thermoplasticity under high pressure

    Energy Technology Data Exchange (ETDEWEB)

    Ndaji, F.E.; Butterfield, I.M.; Thomas, K.M. (Newcastle upon Tyne University, Newcastle upon Tyne (United Kingdom). Northern Carbon Research Labs., Dept. of Chemistry)

    1992-01-01

    The literature on the following topics is reviewed: swelling and agglomeration of coal; measurements of swelling index and dilatometric and plastometric properties at high pressures; and the effects of oxidation, tar addition and minerals on high-pressure thermoplastic properties. 34 refs., 6 figs.

  8. Depth Gauge for Liquids Under High Pressure

    Science.gov (United States)

    Zuckerwar, A. J.; Mazel, D. S.

    1987-01-01

    Piezoelectric element mounted in hole drilled in high-pressure plug. Transducer used to measure depth of liquid when pressure in vessel high. New configuration transmits ultrasonic vibration directly into liquid, enhancing signal strength, accuracy, and range, yet piezoelectric element protected from high-pressure liquid.

  9. Metamorphic Testing for Cybersecurity.

    Science.gov (United States)

    Chen, Tsong Yueh; Kuo, Fei-Ching; Ma, Wenjuan; Susilo, Willy; Towey, Dave; Voas, Jeffrey; Zhou, Zhi Quan

    2016-06-01

    Testing is a major approach for the detection of software defects, including vulnerabilities in security features. This article introduces metamorphic testing (MT), a relatively new testing method, and discusses how the new perspective of MT can help to conduct negative testing as well as to alleviate the oracle problem in the testing of security-related functionality and behavior. As demonstrated by the effectiveness of MT in detecting previously unknown bugs in real-world critical applications such as compilers and code obfuscators, we conclude that software testing of security-related features should be conducted from diverse perspectives in order to achieve greater cybersecurity.

  10. Highly efficient high temperature electrolysis

    DEFF Research Database (Denmark)

    Hauch, Anne; Ebbesen, Sune; Jensen, Søren Højgaard

    2008-01-01

    High temperature electrolysis of water and steam may provide an efficient, cost effective and environmentally friendly production of H-2 Using electricity produced from sustainable, non-fossil energy sources. To achieve cost competitive electrolysis cells that are both high performing i.e. minimum...... electrolysis is favourable from a thermodynamic point of view, because a part of the required energy can be supplied as thermal heat, and the activation barrier is lowered increasing the H-2 production rate. Only two types of cells operating at high temperature (above 200 degrees C) have been described...... electrolysis using SOECs is competitive to H-2 production from fossil fuels at electricity prices below 0.02-0.03 is an element of per kWh. Though promising SOEC results on H-2 production have been reported a substantial R&D is still required to obtain inexpensive, high performing and long-term stable...

  11. High Temperature Heat Exchanger Project

    Energy Technology Data Exchange (ETDEWEB)

    Anthony E. Hechanova, Ph.D.

    2008-09-30

    The UNLV Research Foundation assembled a research consortium for high temperature heat exchanger design and materials compatibility and performance comprised of university and private industry partners under the auspices of the US DOE-NE Nuclear Hydrogen Initiative in October 2003. The objectives of the consortium were to conduct investigations of candidate materials for high temperature heat exchanger componets in hydrogen production processes and design and perform prototypical testing of heat exchangers. The initial research of the consortium focused on the intermediate heat exchanger (located between the nuclear reactor and hydrogen production plan) and the components for the hydrogen iodine decomposition process and sulfuric acid decomposition process. These heat exchanger components were deemed the most challenging from a materials performance and compatibility perspective

  12. Motor for High Temperature Applications

    Science.gov (United States)

    Roopnarine (Inventor)

    2013-01-01

    A high temperature motor has a stator with poles formed by wire windings, and a rotor with magnetic poles on a rotor shaft positioned coaxially within the stator. The stator and rotor are built up from stacks of magnetic-alloy laminations. The stator windings are made of high temperature magnet wire insulated with a vitreous enamel film, and the wire windings are bonded together with ceramic binder. A thin-walled cylinder is positioned coaxially between the rotor and the stator to prevent debris from the stator windings from reaching the rotor. The stator windings are wound on wire spools made of ceramic, thereby avoiding need for mica insulation and epoxy/adhesive. The stator and rotor are encased in a stator housing with rear and front end caps, and rear and front bearings for the rotor shaft are mounted on external sides of the end caps to keep debris from the motor migrating into the bearings' races.

  13. Rapid sulfur capture studies at high temperatures

    Energy Technology Data Exchange (ETDEWEB)

    Richards, G.A.; Lawson, W.F.; Maloney, D.J.; Shaw, D.W.

    1990-12-01

    Determine conditions that would reproduce optimum sulfur capture ( super-equilibrium'') behavior. No attempt was made to extract kinetic data for calcination or sulfur capture, as might be done in a comprehensive study of sorbent behavior. While some interesting anomalies are present in the calcination data and in the limited surface area data, no attempt was made to pursue those issues. Since little sulfur capture was observed at operating conditions where super-equilibrium'' might be expected to occur, tests were stopped when the wide range of parameters that were studied failed to produce significant sulfur capture via the super-equilibrium mechanism. Considerable space in this report is devoted to a description of the experiment, including details of the GTRC construction. This description is included because we have received requests for a detailed description of the GTRC itself, as well as the pressurized dry powder feed system. In addition, many questions about accurately sampling the sulfur species from a high-temperature, high-pressure reactor were raised during the course of this investigation. A full account of the development of the gas and particulate sampling train in thus provided. 8 refs., 17 figs., 2 tabs.

  14. Assessment of high-temperature filtering elements

    Energy Technology Data Exchange (ETDEWEB)

    Monica Lupion; Francisco J. Gutierrez Ortiz; Benito Navarrete; Vicente J. Cortes [University of Seville, Seville (Spain). E.T.S. Ingenieros

    2008-07-01

    A complete experimental campaign has been carried out in a hot gas filtration test facility so as to test several filtering elements and configurations, particularly, three different types of bag filters and one ceramic candle. The facility was designed to operate under a wide range of conditions, thus providing an excellent tool for the investigation of hot gas filtration applications for the advanced electrical power generation industry such as IGCC, PFBC or fuel cell technologies. Relevant parameters for the characterization and optimization of the performance of the filters have been studied for a variety of operation conditions such as filtration velocity, particle concentration, pressure and temperature among others. Pressure drop across the filter, cleaning pulse interval, baseline pressure drop, filtration efficiency and durability of the filter have been investigated for each type considered and dependences on parameters have been established. On top of that, optimal operating conditions and cleaning strategies were determined. The tests results show that bag filters are a suitable alternative for the hot gas filtration due to the better performance and the high efficiency observed, which makes them suitable for industrial applications operating under high temperature high pressure conditions considered within the study (200-370{degree}C and 4-7.5 barg respectively). 7 refs., 7 figs., 10 tabs.

  15. Fabrication and mechanical testing of glass chips for high-pressure synthetic or analytical chemistry

    NARCIS (Netherlands)

    Oosterbroek, R.E.; Hermes, D.C.; Kakuta, M.; Benito-Lopez, F.; Verboom, Willem; Gardeniers, Johannes G.E.; van den Berg, Albert; Reinhoudt, David

    The pressure strength of microfluidics glass chips for high-pressure chemistry has been examined. Internal pressures up to 320 bar have been measured, although variations are substantial. Long annealing steps at high temperatures did not show any improvement, but smoothening the powder blasted

  16. High temperature superconductor accelerator magnets

    OpenAIRE

    van Nugteren, J.

    2016-01-01

    For future particle accelerators bending dipoles are considered with magnetic fields exceeding 20T. This can only be achieved using high temperature superconductors (HTS). These exhibit different properties from classical low temperature superconductors and still require significant research and development before they can be applied in a practical accelerator magnet. In order to study HTS in detail, a five tesla demonstrator magnet named Feather-M2 is designed and constructed. The magnet is ...

  17. High Temperature Superconductor Accelerator Magnets

    OpenAIRE

    Van Nugteren, Jeroen; ten Kate, Herman; de Rijk, Gijs; Dhalle, Marc

    2016-01-01

    For future particle accelerators bending dipoles are considered with magnetic fields exceeding $20T$. This can only be achieved using high temperature superconductors (HTS). These exhibit different properties from classical low temperature superconductors and still require significant research and development before they can be applied in a practical accelerator magnet. In order to study HTS in detail, a five tesla demonstrator magnet named Feather-M2 is designed and constructed. The magnet ...

  18. Nanoscale high-temperature superconductivity

    Energy Technology Data Exchange (ETDEWEB)

    Mohanty, P.; Wei, J.Y.T.; Ananth, V.; Morales, P.; Skocpol, W

    2004-08-01

    We discuss the exciting prospects of studying high-temperature superconductivity in the nanometer scale from the perspective of experiments, theory and simulation. In addition to enabling studies of novel quantum phases in an unexplored regime of system dimensions and parameters, nanoscale high-temperature superconducting structures will allow exploration of fundamental mechanisms with unprecedented insight. The prospects include, spin-charge separation, detection of electron fractionalization via novel excitations such as vison, stripe states and their dynamics, preformed cooper pairs or bose-condensation in the underdoped regime, and other quantum-ordered states. Towards this initiative, we present the successful development of a novel nanofabrication technique for the epitaxial growth of nanoscale cuprates. Combining the techniques of e-beam lithography and nanomachining, we have been able to fabricate the first generation of high-temperature superconducting nanoscale devices, including Y-junctions, four-probe wires and rings. Their initial transport characterization and scanning tunneling microscopy reveal the integrity of the crystal structure, grown on nanometer scale lateral dimensions. Here, we present atomic force micrographs and electrical characterization of a few nanoscale YBa{sub 2}Cu{sub 3}O{sub 7} (YBCO) samples.

  19. High temperature thermoelectric energy conversion

    Science.gov (United States)

    Wood, Charles

    1987-01-01

    The theory and current status of materials research for high-temperature thermoelectric energy conversion are reviewed. Semiconductors are shown to be the preferred class of materials for this application. Optimization of the figure of merit of both broadband and narrow-band semiconductors is discussed as a function of temperature. Phonon scattering mechanisms are discussed, and basic material guidelines are given for reduction of thermal conductivity. Two general classes of materials show promise for high temperature figure of merit (Z) values, namely the rare earth chalcogenides and the boron-rich borides. The electronic transport properties of the rare earth chalcogenides are explicable on the basis of degenerate or partially degenerate n-type semiconductors. Boron and boron-rich borides exhibit p-type hopping conductivity, with detailed explanations proposed for the transport differing from compound to compound. Some discussion is presented on the reasons for the low thermal conductivities in these materials. Also, ZTs greater than one appear to have been realized at high temperature in many of these compounds.

  20. Summary: High Temperature Downhole Motor

    Energy Technology Data Exchange (ETDEWEB)

    Raymond, David W. [Sandia National Lab. (SNL-NM), Albuquerque, NM (United States)

    2017-10-01

    Directional drilling can be used to enable multi-lateral completions from a single well pad to improve well productivity and decrease environmental impact. Downhole rotation is typically developed with a motor in the Bottom Hole Assembly (BHA) that develops drilling power (speed and torque) necessary to drive rock reduction mechanisms (i.e., the bit) apart from the rotation developed by the surface rig. Historically, wellbore deviation has been introduced by a “bent-sub,” located in the BHA, that introduces a small angular deviation, typically less than 3 degrees, to allow the bit to drill off-axis with orientation of the BHA controlled at the surface. The development of a high temperature downhole motor would allow reliable use of bent subs for geothermal directional drilling. Sandia National Laboratories is pursuing the development of a high temperature motor that will operate on either drilling fluid (water-based mud) or compressed air to enable drilling high temperature, high strength, fractured rock. The project consists of designing a power section based upon geothermal drilling requirements; modeling and analysis of potential solutions; and design, development and testing of prototype hardware to validate the concept. Drilling costs contribute substantially to geothermal electricity production costs. The present development will result in more reliable access to deep, hot geothermal resources and allow preferential wellbore trajectories to be achieved. This will enable development of geothermal wells with multi-lateral completions resulting in improved geothermal resource recovery, decreased environmental impact and enhanced well construction economics.

  1. Very High Temperature Sound Absorption Coating Project

    Data.gov (United States)

    National Aeronautics and Space Administration — Phase I demonstrated experimentally a very high temperature acoustically absorbing coating for ducted acoustics applications. High temperature survivability at 3500...

  2. High Temperature Radio Frequency Loads

    CERN Document Server

    Federmann, S; Grudiev, A; Montesinos, E; Syratchev, I

    2011-01-01

    In the context of energy saving and recovery requirements the design of reliable and robust RF power loads which permit a high outlet temperature and high pressure of the cooling water is desirable. Cooling water arriving at the outlet withmore than 150 ◦C and high pressure has a higher value than water with 50 ◦C under low pressure. Conventional RF power loads containing dielectric and magnetic materials as well as sensitive ceramic windows usually do not permit going much higher than 90 ◦C. Here we present and discuss several design concepts for "metal only" RF high power loads. One concept is the application of magnetic steel corrugated waveguides near cutoff – this concept could find practical use above several GHz. Another solution are resonant structures made of steel to be installed in large waveguides for frequencies of 500 MHz or lower. Similar resonant structures above 100 MHz taking advantage of the rather high losses of normal steel may also be used in coaxial line geometries with large di...

  3. Application of High Pressure in Food Processing

    Directory of Open Access Journals (Sweden)

    Herceg, Z.

    2011-01-01

    Full Text Available In high pressure processing, foods are subjected to pressures generally in the range of 100 – 800 (1200 MPa. The processing temperature during pressure treatments can be adjusted from below 0 °C to above 100 °C, with exposure times ranging from a few seconds to 20 minutes and even longer, depending on process conditions. The effects of high pressure are system volume reduction and acceleration of reactions that lead to volume reduction. The main areas of interest regarding high-pressure processing of food include: inactivation of microorganisms, modification of biopolymers, quality retention (especially in terms of flavour and colour, and changes in product functionality. Food components responsible for the nutritive value and sensory properties of food remain unaffected by high pressure. Based on the theoretical background of high-pressure processing and taking into account its advantages and limitations, this paper aims to show its possible application in food processing. The paper gives an outline of the special equipment used in highpressure processing. Typical high pressure equipment in which pressure can be generated either by direct or indirect compression are presented together with three major types of high pressure food processing: the conventional (batch system, semicontinuous and continuous systems. In addition to looking at this technology’s ability to inactivate microorganisms at room temperature, which makes it the ultimate alternative to thermal treatments, this paper also explores its application in dairy, meat, fruit and vegetable processing. Here presented are the effects of high-pressure treatment in milk and dairy processing on the inactivation of microorganisms and the modification of milk protein, which has a major impact on rennet coagulation and curd formation properties of treated milk. The possible application of this treatment in controlling cheese manufacture, ripening and safety is discussed. The opportunities

  4. Packaging Technologies for High Temperature Electronics and Sensors

    Science.gov (United States)

    Chen, Liangyu; Hunter, Gary W.; Neudeck, Philip G.; Beheim, Glenn M.; Spry, David J.; Meredith, Roger D.

    2013-01-01

    This paper reviews ceramic substrates and thick-film metallization based packaging technologies in development for 500degC silicon carbide (SiC) electronics and sensors. Prototype high temperature ceramic chip-level packages and printed circuit boards (PCBs) based on ceramic substrates of aluminum oxide (Al2O3) and aluminum nitride (AlN) have been designed and fabricated. These ceramic substrate-based chiplevel packages with gold (Au) thick-film metallization have been electrically characterized at temperatures up to 550degC. A 96% alumina based edge connector for a PCB level subsystem interconnection has also been demonstrated recently. The 96% alumina packaging system composed of chip-level packages and PCBs has been tested with high temperature SiC devices at 500degC for over 10,000 hours. In addition to tests in a laboratory environment, a SiC JFET with a packaging system composed of a 96% alumina chip-level package and an alumina printed circuit board mounted on a data acquisition circuit board was launched as a part of the MISSE-7 suite to the International Space Station via a Shuttle mission. This packaged SiC transistor was successfully tested in orbit for eighteen months. A spark-plug type sensor package designed for high temperature SiC capacitive pressure sensors was developed. This sensor package combines the high temperature interconnection system with a commercial high temperature high pressure stainless steel seal gland (electrical feed-through). Test results of a packaged high temperature capacitive pressure sensor at 500degC are also discussed. In addition to the pressure sensor package, efforts for packaging high temperature SiC diode-based gas chemical sensors are in process.

  5. High-pressure study on some superconductors

    CERN Document Server

    Li, K Q; Yao, Y S; Che, G C; Zhao, Z X

    2002-01-01

    High-pressure study has played an important role in the investigation of conventional superconductors. Since the discovery of cuprate superconductors, high-pressure study has become even more important, especially as regards high-pressure synthesis and the effect of pressure. In this report, the new materials Ca-doped Pr-123, (Fe, Cu)-1212, and MgB sub 2 - a very new and interesting system synthesized under high pressure with good quality - will be discussed. Chemical inner pressure has been thought to explain the high T sub c of Ca-doped Pr-123. As another possibility, the replacement of the physical pressure effect by a chemical effect will be discussed.

  6. High temperature structural sandwich panels

    Science.gov (United States)

    Papakonstantinou, Christos G.

    High strength composites are being used for making lightweight structural panels that are being employed in aerospace, naval and automotive structures. Recently, there is renewed interest in use of these panels. The major problem of most commercial available sandwich panels is the fire resistance. A recently developed inorganic matrix is investigated for use in cases where fire and high temperature resistance are necessary. The focus of this dissertation is the development of a fireproof composite structural system. Sandwich panels made with polysialate matrices have an excellent potential for use in applications where exposure to high temperatures or fire is a concern. Commercial available sandwich panels will soften and lose nearly all of their compressive strength temperatures lower than 400°C. This dissertation consists of the state of the art, the experimental investigation and the analytical modeling. The state of the art covers the performance of existing high temperature composites, sandwich panels and reinforced concrete beams strengthened with Fiber Reinforced Polymers (FRP). The experimental part consists of four major components: (i) Development of a fireproof syntactic foam with maximum specific strength, (ii) Development of a lightweight syntactic foam based on polystyrene spheres, (iii) Development of the composite system for the skins. The variables are the skin thickness, modulus of elasticity of skin and high temperature resistance, and (iv) Experimental evaluation of the flexural behavior of sandwich panels. Analytical modeling consists of a model for the flexural behavior of lightweight sandwich panels, and a model for deflection calculations of reinforced concrete beams strengthened with FRP subjected to fatigue loading. The experimental and analytical results show that sandwich panels made with polysialate matrices and ceramic spheres do not lose their load bearing capability during severe fire exposure, where temperatures reach several

  7. High pressure structural studies of conjugated molecules

    DEFF Research Database (Denmark)

    Knaapila, Matti; Torkkeli, Mika; Scherf, Ullrich

    2018-01-01

    This chapter highlights high pressure GPa level structural studies of conjugated polymers and their analogues: conjugated oligomers and molecules, and rigid rod polymers. Attention is placed on our recent studies of polyfluorenes.......This chapter highlights high pressure GPa level structural studies of conjugated polymers and their analogues: conjugated oligomers and molecules, and rigid rod polymers. Attention is placed on our recent studies of polyfluorenes....

  8. High-pressure minerals in shocked meteorites

    Science.gov (United States)

    Tomioka, Naotaka; Miyahara, Masaaki

    2017-09-01

    Heavily shocked meteorites contain various types of high-pressure polymorphs of major minerals (olivine, pyroxene, feldspar, and quartz) and accessory minerals (chromite and Ca phosphate). These high-pressure minerals are micron to submicron sized and occur within and in the vicinity of shock-induced melt veins and melt pockets in chondrites and lunar, howardite-eucrite-diogenite (HED), and Martian meteorites. Their occurrence suggests two types of formation mechanisms (1) solid-state high-pressure transformation of the host-rock minerals into monomineralic polycrystalline aggregates, and (2) crystallization of chondritic or monomineralic melts under high pressure. Based on experimentally determined phase relations, their formation pressures are limited to the pressure range up to 25 GPa. Textural, crystallographic, and chemical characteristics of high-pressure minerals provide clues about the impact events of meteorite parent bodies, including their size and mutual collision velocities and about the mineralogy of deep planetary interiors. The aim of this article is to review and summarize the findings on natural high-pressure minerals in shocked meteorites that have been reported over the past 50 years.

  9. Directs measurement of high temperature/high pressure solubility of methane and carbon dioxide in polyamide (PA-11) using a high-pressure microbalance

    DEFF Research Database (Denmark)

    von Solms, Nicolas; Rubin, A; Andersen, Simon Ivar

    2005-01-01

    Experiments to determine the Solubility of methane and carbon dioxide in PA-11 have been performed in the temperature range 50-90&DEG; C and the pressure ranges 50-150 bar for methane and 20-40 bar for carbon dioxide. In general, the results agree fairly well with previous experiments for similar...

  10. The Effect of High Pressure Techniques on the Stability of Anthocyanins in Fruit and Vegetables

    Directory of Open Access Journals (Sweden)

    Krystian Marszałek

    2017-01-01

    Full Text Available Anthocyanins are a group of phenolic compounds responsible for red, blue and violet colouration of many fruits, vegetables and flowers. The high content of these pigments is important as it influences directly their health promoting properties as well as the sensory quality of the product; however they are prone to degradation by, inter alia, elevated temperature and tissue enzymes. The traditional thermal methods of food preservation cause significant losses of these pigments. Thus, novel non-thermal techniques such as high pressure processing, high pressure carbon dioxide and high pressure homogenization are under consideration. In this review, the authors attempted to summarize the current knowledge of the impact of high pressure techniques on the stability of anthocyanins during processing and storage of fruit and vegetable products. Furthermore, the effect of the activity of enzymes involved in the degradation of these compounds has been described. The conclusions including comparisons of pressure-based methods with high temperature preservation techniques were presented.

  11. The Effect of High Pressure Techniques on the Stability of Anthocyanins in Fruit and Vegetables.

    Science.gov (United States)

    Marszałek, Krystian; Woźniak, Łukasz; Kruszewski, Bartosz; Skąpska, Sylwia

    2017-01-27

    Anthocyanins are a group of phenolic compounds responsible for red, blue and violet colouration of many fruits, vegetables and flowers. The high content of these pigments is important as it influences directly their health promoting properties as well as the sensory quality of the product; however they are prone to degradation by, inter alia, elevated temperature and tissue enzymes. The traditional thermal methods of food preservation cause significant losses of these pigments. Thus, novel non-thermal techniques such as high pressure processing, high pressure carbon dioxide and high pressure homogenization are under consideration. In this review, the authors attempted to summarize the current knowledge of the impact of high pressure techniques on the stability of anthocyanins during processing and storage of fruit and vegetable products. Furthermore, the effect of the activity of enzymes involved in the degradation of these compounds has been described. The conclusions including comparisons of pressure-based methods with high temperature preservation techniques were presented.

  12. Solute strengthening at high temperatures

    Science.gov (United States)

    Leyson, G. P. M.; Curtin, W. A.

    2016-08-01

    The high temperature behavior of solute strengthening has previously been treated approximately using various scaling arguments, resulting in logarithmic and power-law scalings for the stress-dependent energy barrier Δ E(τ ) versus stress τ. Here, a parameter-free solute strengthening model is extended to high temperatures/low stresses without any a priori assumptions on the functional form of Δ E(τ ) . The new model predicts that the well-established low-temperature, with energy barrier Δ {{E}\\text{b}} and zero temperature flow stress {τy0} , transitions to a near-logarithmic form for stresses in the regime 0.2intermediate-temperature and the associated transition for the activation volume. Overall, the present analysis unifies the different qualitative models in the literature and, when coupled with the previous parameter-free solute strengthening model, provides a single predictive model for solute strengthening as a function of composition, temperature, and strain rate over the full range of practical utility.

  13. High temperature PEM fuel cells

    Science.gov (United States)

    Zhang, Jianlu; Xie, Zhong; Zhang, Jiujun; Tang, Yanghua; Song, Chaojie; Navessin, Titichai; Shi, Zhiqing; Song, Datong; Wang, Haijiang; Wilkinson, David P.; Liu, Zhong-Sheng; Holdcroft, Steven

    There are several compelling technological and commercial reasons for operating H 2/air PEM fuel cells at temperatures above 100 °C. Rates of electrochemical kinetics are enhanced, water management and cooling is simplified, useful waste heat can be recovered, and lower quality reformed hydrogen may be used as the fuel. This review paper provides a concise review of high temperature PEM fuel cells (HT-PEMFCs) from the perspective of HT-specific materials, designs, and testing/diagnostics. The review describes the motivation for HT-PEMFC development, the technology gaps, and recent advances. HT-membrane development accounts for ∼90% of the published research in the field of HT-PEMFCs. Despite this, the status of membrane development for high temperature/low humidity operation is less than satisfactory. A weakness in the development of HT-PEMFC technology is the deficiency in HT-specific fuel cell architectures, test station designs, and testing protocols, and an understanding of the underlying fundamental principles behind these areas. The development of HT-specific PEMFC designs is of key importance that may help mitigate issues of membrane dehydration and MEA degradation.

  14. High pressure processing for food safety.

    Science.gov (United States)

    Fonberg-Broczek, Monika; Windyga, B; Szczawiński, J; Szczawińska, M; Pietrzak, D; Prestamo, G

    2005-01-01

    Food preservation using high pressure is a promising technique in food industry as it offers numerous opportunities for developing new foods with extended shelf-life, high nutritional value and excellent organoleptic characteristics. High pressure is an alternative to thermal processing. The resistance of microorganisms to pressure varies considerably depending on the pressure range applied, temperature and treatment duration, and type of microorganism. Generally, Gram-positive bacteria are more resistant to pressure than Gram-negative bacteria, moulds and yeasts; the most resistant are bacterial spores. The nature of the food is also important, as it may contain substances which protect the microorganism from high pressure. This article presents results of our studies involving the effect of high pressure on survival of some pathogenic bacteria -- Listeria monocytogenes, Aeromonas hydrophila and Enterococcus hirae -- in artificially contaminated cooked ham, ripening hard cheese and fruit juices. The results indicate that in samples of investigated foods the number of these microorganisms decreased proportionally to the pressure used and the duration of treatment, and the effect of these two factors was statistically significant (level of probability, P monocytogenes and A. hydrophila. Mathematical methods were applied, for accurate prediction of the effects of high pressure on microorganisms. The usefulness of high pressure treatment for inactivation of microorganisms and shelf-life extention of meat products was also evaluated. The results obtained show that high pressure treatment extends the shelf-life of cooked pork ham and raw smoked pork loin up to 8 weeks, ensuring good micro-biological and sensory quality of the products.

  15. HIgh Temperature Photocatalysis over Semiconductors

    Science.gov (United States)

    Westrich, Thomas A.

    Due in large part to in prevalence of solar energy, increasing demand of energy production (from all sources), and the uncertain future of petroleum energy feedstocks, solar energy harvesting and other photochemical systems will play a major role in the developing energy market. This dissertation focuses on a novel photochemical reaction process: high temperature photocatalysis (i.e., photocatalysis conducted above ambient temperatures, T ≥ 100°C). The overarching hypothesis of this process is that photo-generated charge carriers are able to constructively participate in thermo-catalytic chemical reactions, thereby increasing catalytic rates at one temperature, or maintaining catalytic rates at lower temperatures. The photocatalytic oxidation of carbon deposits in an operational hydrocarbon reformer is one envisioned application of high temperature photocatalysis. Carbon build-up during hydrocarbon reforming results in catalyst deactivation, in the worst cases, this was shown to happen in a period of minutes with a liquid hydrocarbon. In the presence of steam, oxygen, and above-ambient temperatures, carbonaceous deposits were photocatalytically oxidized over very long periods (t ≥ 24 hours). This initial experiment exemplified the necessity of a fundamental assessment of high temperature photocatalytic activity. Fundamental understanding of the mechanisms that affect photocatalytic activity as a function of temperatures was achieved using an ethylene photocatalytic oxidation probe reaction. Maximum ethylene photocatalytic oxidation rates were observed between 100 °C and 200 °C; the maximum photocatalytic rates were approximately a factor of 2 larger than photocatalytic rates at ambient temperatures. The loss of photocatalytic activity at temperatures above 200 °C is due to a non-radiative multi-phonon recombination mechanism. Further, it was shown that the fundamental rate of recombination (as a function of temperature) can be effectively modeled as a

  16. The high-pressure phase of CePtAl

    Energy Technology Data Exchange (ETDEWEB)

    Heymann, Gunter [Univ. Innsbruck (Austria). Inst. fuer Allgemeine, Anorganische und Theoretische Chemie; Heying, Birgit; Rodewald, Ute C. [Univ. Muenster (Germany). Inst. fuer Anorganische und Analytische Chemie; Janka, Oliver [Univ. Muenster (Germany). Inst. fuer Anorganische und Analytische Chemie; Univ. Oldenburg (Germany). Inst. fuer Chemie

    2017-03-01

    The intermetallic aluminum compound HP-CePtAl was synthesized by arc melting of the elements with subsequent high-pressure/high-temperature treatment at 1620 K and 10.5 GPa in a multianvil press. The compound crystallizes in the hexagonal MgZn{sub 2}-type structure (P6{sub 3}/mmc) with lattice parameters of a=552.7(1) and c=898.8(2) pm refined from powder X-ray diffraction data. With the help of single crystal investigations (wR=0.0527, 187 F{sup 2} values, 13 variables), the proposed structure type was confirmed and the mixed Pt/Al site occupations could be refined. Magnetic susceptibility measurements showed a disappearance of the complex magnetic ordering phenomena, which are observed in NP-CePtAl.

  17. Nonlinear plasmonics at high temperatures

    Science.gov (United States)

    Sivan, Yonatan; Chu, Shi-Wei

    2017-01-01

    We solve the Maxwell and heat equations self-consistently for metal nanoparticles under intense continuous wave (CW) illumination. Unlike previous studies, we rely on experimentally-measured data for metal permittivity for increasing temperature and for the visible spectral range. We show that the thermal nonlinearity of the metal can lead to substantial deviations from the predictions of the linear model for the temperature and field distribution and, thus, can explain qualitatively the strong nonlinear scattering from such configurations observed experimentally. We also show that the incompleteness of existing data of the temperature dependence of the thermal properties of the system prevents reaching a quantitative agreement between the measured and calculated scattering data. This modeling approach is essential for the identification of the underlying physical mechanism responsible for the thermo-optical nonlinearity of the metal and should be adopted in all applications of high-temperature nonlinear plasmonics, especially for refractory metals, for both CW and pulsed illumination.

  18. Nonlinear plasmonics at high temperatures

    Directory of Open Access Journals (Sweden)

    Sivan Yonatan

    2016-10-01

    Full Text Available We solve the Maxwell and heat equations self-consistently for metal nanoparticles under intense continuous wave (CW illumination. Unlike previous studies, we rely on experimentally-measured data for metal permittivity for increasing temperature and for the visible spectral range. We show that the thermal nonlinearity of the metal can lead to substantial deviations from the predictions of the linear model for the temperature and field distribution and, thus, can explain qualitatively the strong nonlinear scattering from such configurations observed experimentally. We also show that the incompleteness of existing data of the temperature dependence of the thermal properties of the system prevents reaching a quantitative agreement between the measured and calculated scattering data. This modeling approach is essential for the identification of the underlying physical mechanism responsible for the thermo-optical nonlinearity of the metal and should be adopted in all applications of high-temperature nonlinear plasmonics, especially for refractory metals, for both CW and pulsed illumination.

  19. High Temperature Composite Heat Exchangers

    Science.gov (United States)

    Eckel, Andrew J.; Jaskowiak, Martha H.

    2002-01-01

    High temperature composite heat exchangers are an enabling technology for a number of aeropropulsion applications. They offer the potential for mass reductions of greater than fifty percent over traditional metallics designs and enable vehicle and engine designs. Since they offer the ability to operate at significantly higher operating temperatures, they facilitate operation at reduced coolant flows and make possible temporary uncooled operation in temperature regimes, such as experienced during vehicle reentry, where traditional heat exchangers require coolant flow. This reduction in coolant requirements can translate into enhanced range or system payload. A brief review of the approaches and challengers to exploiting this important technology are presented, along with a status of recent government-funded projects.

  20. Faraday imaging at high temperatures

    Science.gov (United States)

    Hackel, Lloyd A.; Reichert, Patrick

    1997-01-01

    A Faraday filter rejects background light from self-luminous thermal objects, but transmits laser light at the passband wavelength, thus providing an ultra-narrow optical bandpass filter. The filter preserves images so a camera looking through a Faraday filter at a hot target illuminated by a laser will not see the thermal radiation but will see the laser radiation. Faraday filters are useful for monitoring or inspecting the uranium separator chamber in an atomic vapor laser isotope separation process. Other uses include viewing welds, furnaces, plasma jets, combustion chambers, and other high temperature objects. These filters are can be produced at many discrete wavelengths. A Faraday filter consists of a pair of crossed polarizers on either side of a heated vapor cell mounted inside a solenoid.

  1. Thermodynamic properties of liquid sodium under high pressure

    Science.gov (United States)

    Li, Huaming; Zhang, Xiaoxiao; Sun, Yongli; Li, Mo

    2017-04-01

    Acquiring reliable thermodynamic properties in liquid metals at high pressure and temperature is still a challenge in both experiment and theory. Equation of state (EoS) offers an alternative approach free of many of the difficulties. Here using the EoS of a power law form we obtained the thermodynamic properties of liquid sodium under pressure along the isothermal lines, including isothermal buck modulus, thermal expansion coefficient, Grüneisen parameter, and Anderson-Grüneisen parameter. The results are in excellent agreement with available experimental data measured by a piezometer at high temperature and high pressure and sound velocity measurement with pulse-echo technique. We found that the pressure derivative of the isothermal bulk modulus at zero pressure is a monotonic function of temperature and has a value around 4. In addition, unexpected crossing points were found in the isobaric thermal expansion coefficient and Grüneisen parameter; and a minimum in the isobaric heat under isothermal compression was also observed. While some of these detailed predictions are yet to be confirmed by further experiment, our results suggest that the power law form may be a more suitable choice for the EoS of liquids metals.

  2. High Pressure Scanning Tunneling Microscopy and High PressureX-ray Photoemission Spectroscopy Studies of Adsorbate Structure,Composition and Mobility during Catalytic Reactions on A Model SingleCrystal

    Energy Technology Data Exchange (ETDEWEB)

    Montano, Max O. [Univ. of California, Berkeley, CA (United States)

    2006-01-01

    Our research focuses on taking advantage of the ability of scanning tunneling microscopy (STM) to operate at high-temperatures and high-pressures while still providing real-time atomic resolution images. We also utilize high-pressure x-ray photoelectron spectroscopy (HPXPS) to monitor systems under identical conditions thus giving us chemical information to compare and contrast with the structural and dynamic data provided by STM.

  3. Techniques in high pressure neutron scattering

    CERN Document Server

    Klotz, Stefan

    2013-01-01

    Drawing on the author's practical work from the last 20 years, Techniques in High Pressure Neutron Scattering is one of the first books to gather recent methods that allow neutron scattering well beyond 10 GPa. The author shows how neutron scattering has to be adapted to the pressure range and type of measurement.Suitable for both newcomers and experienced high pressure scientists and engineers, the book describes various solutions spanning two to three orders of magnitude in pressure that have emerged in the past three decades. Many engineering concepts are illustrated through examples of rea

  4. High pressure water jet mining machine

    Science.gov (United States)

    Barker, Clark R.

    1981-05-05

    A high pressure water jet mining machine for the longwall mining of coal is described. The machine is generally in the shape of a plowshare and is advanced in the direction in which the coal is cut. The machine has mounted thereon a plurality of nozzle modules each containing a high pressure water jet nozzle disposed to oscillate in a particular plane. The nozzle modules are oriented to cut in vertical and horizontal planes on the leading edge of the machine and the coal so cut is cleaved off by the wedge-shaped body.

  5. High Temperature Superconducting Underground Cable

    Energy Technology Data Exchange (ETDEWEB)

    Farrell, Roger, A.

    2010-02-28

    The purpose of this Project was to design, build, install and demonstrate the technical feasibility of an underground high temperature superconducting (HTS) power cable installed between two utility substations. In the first phase two HTS cables, 320 m and 30 m in length, were constructed using 1st generation BSCCO wire. The two 34.5 kV, 800 Arms, 48 MVA sections were connected together using a superconducting joint in an underground vault. In the second phase the 30 m BSCCO cable was replaced by one constructed with 2nd generation YBCO wire. 2nd generation wire is needed for commercialization because of inherent cost and performance benefits. Primary objectives of the Project were to build and operate an HTS cable system which demonstrates significant progress towards commercial progress and addresses real world utility concerns such as installation, maintenance, reliability and compatibility with the existing grid. Four key technical areas addressed were the HTS cable and terminations (where the cable connects to the grid), cryogenic refrigeration system, underground cable-to-cable joint (needed for replacement of cable sections) and cost-effective 2nd generation HTS wire. This was the world’s first installation and operation of an HTS cable underground, between two utility substations as well as the first to demonstrate a cable-to-cable joint, remote monitoring system and 2nd generation HTS.

  6. High temperature two component explosive

    Science.gov (United States)

    Mars, James E.; Poole, Donald R.; Schmidt, Eckart W.; Wang, Charles

    1981-01-01

    A two component, high temperature, thermally stable explosive composition comprises a liquid or low melting oxidizer and a liquid or low melting organic fuel. The oxidizer and fuel in admixture are incapable of substantial spontaneous exothermic reaction at temperatures on the order of 475.degree. K. At temperatures on the order of 475.degree. K., the oxidizer and fuel in admixture have an activation energy of at least about 40 kcal/mol. As a result of the high activation energy, the preferred explosive compositions are nondetonable as solids at ambient temperature, and become detonable only when heated beyond the melting point. Preferable oxidizers are selected from alkali or alkaline earth metal nitrates, nitrites, perchlorates, and/or mixtures thereof. Preferred fuels are organic compounds having polar hydrophilic groups. The most preferred fuels are guanidinium nitrate, acetamide and mixtures of the two. Most preferred oxidizers are eutectic mixtures of lithium nitrate, potassium nitrate and sodium nitrate, of sodium nitrite, sodium nitrate and potassium nitrate, and of potassium nitrate, calcium nitrate and sodium nitrate.

  7. High Temperature Superconductor Accelerator Magnets

    CERN Document Server

    AUTHOR|(CDS)2079328; de Rijk, Gijs; Dhalle, Marc

    2016-11-10

    For future particle accelerators bending dipoles are considered with magnetic fields exceeding $20T$. This can only be achieved using high temperature superconductors (HTS). These exhibit different properties from classical low temperature superconductors and still require significant research and development before they can be applied in a practical accelerator magnet. In order to study HTS in detail, a five tesla demonstrator magnet named Feather-M2 is designed and constructed. The magnet is based on ReBCO coated conductor, which is assembled into a $10kA$ class Roebel cable. A new and optimized Aligned Block layout is used, which takes advantage of the anisotropy of the conductor. This is achieved by providing local alignment of the Roebel cable in the coil windings with the magnetic field lines. A new Network Model capable of analyzing transient electro-magnetic and thermal phenomena in coated conductor cables and coils is developed. This model is necessary to solve critical issues in coated conductor ac...

  8. Development of high pressure proportional counters

    Energy Technology Data Exchange (ETDEWEB)

    Oddone, P.; Smith, G.; Green, A.; Nemethy, P.; Baksay, L.; Schick, L.; Heflin, E.G.

    1986-12-01

    We have begun to investigate the possibility of operating gas counters at high pressures. In a first step we were able to operate cylindrical chambers up to 430 atm with a gas gain of about 300 using a mixture of 92% Ar and 8% CH/sub 4/.

  9. High-field/high-pressure ESR.

    Science.gov (United States)

    Sakurai, T; Okubo, S; Ohta, H

    2017-07-01

    We present a historical review of high-pressure ESR systems with emphasis on our recent development of a high-pressure, high-field, multi-frequency ESR system. Until 2000, the X-band system was almost established using a resonator filled with dielectric materials or a combination of the anvil cell and dielectric resonators. Recent developments have shifted from that in the low-frequency region, such as X-band, to that in multi-frequency region. High-pressure, high-field, multi-frequency ESR systems are classified into two types. First are the systems that use a vector network analyzer or a quasi-optical bridge, which have high sensitivity but a limited frequency region; the second are like our system, which has a very broad frequency region covering the THz region, but lower sensitivity. We will demonstrate the usefulness of our high-pressure ESR system, in addition to its experimental limitations. We also discuss the recent progress of our system and future plans. Copyright © 2017 Elsevier Inc. All rights reserved.

  10. High pressure and synchrotron radiation satellite workshop

    Energy Technology Data Exchange (ETDEWEB)

    Bass, J.; Guignot, N.; Morard, G.; Mezouar, M.; Andrault, D.; Bolfan-Casanova, N.; Sturhahn, W.; Daniel, I.; Reynard, B.; Simionovici, A.; Sanchez Valle, C.; Martinez, I.; Kantor, I.; Dubrovinsky, I.; Mccammon, C.; Dubrovinskaia, N.; Kurnosiv, A.; Kuznetsov, A.; Goncharenko, I.; Loubeyre, P.; Desgreniers, S.; Weck, G.; Yoo, C.S.; Iota, V.; Park, J.; Cynn, H.; Gorelli, F.; Toulemonde, P.; Machon, D.; Merlen, A.; San Miguel, A.; Amboage, M.; Aquilanti, G.; Mathon, O.; Pascarelli, S.; Itie, J.P.; Mcmillan, P.F.; Trapananti, A.; Di Cicco, A.; Panfilis, S. de; Filipponi, A.; Kreisel, J.; Bouvier, P.; Dkhil, B.; Chaabane, B.; Rosner, H.; Koudela, D.; Schwarz, U.; Handestein, A.; Hanfland, M.; Opahle, I.; Koepernik, K.; Kuzmin, M.; Mueller, K.H.; Mydosh, J.; Richter, M.; Hejny, C.; Falconi, S.; Lundegaard, L.F.; Mcmahon, M.I; Loa, I.; Syassen, K.; Wang, X.; Roth, H.; Lorenz, T.; Farber Daniel, I.; Antonangeli Daniele, I.; Krisch, M.; Badro, J.; Fiquet, G.; Occelli, F.; Mao, W.L.; Mao, H.K.; Eng, P.; Kao, C.C.; Shu, J.F.; Hemley, R.J.; Tse, J.S.; Yao, Y.; Deen, P.P.; Paolasini, I.; Braithwaite, D.; Kernavanois, N.; Lapertot, G.; Rupprecht, K.; Leupold, O.; Ponkratz, U.; Wortmann, G.; Beraud, A.; Krisch, M.; Farber, D.; Antonangeli, D.; Aracne, C.; Zarestky, J.L.; Mcqueeney, R.; Mathon, O.; Baudelet, F.; Decremps, F.; Itie, J.P.; Nataf, I.; Pascarelli, S.; Polian, A

    2006-07-01

    The workshop is dedicated to recent advances on science at high pressure at third generation synchrotron sources. A variety of experiments using synchrotron radiation techniques including X-ray diffraction, EXAFS (extended X-ray absorption fine structure), inelastic X-ray scattering, Compton scattering and Moessbauer spectroscopy of crystalline, liquid or amorphous samples, are reported. This document gathers the abstracts of the presentations.

  11. High-pressure oxidation of methane

    NARCIS (Netherlands)

    Hashemi, Hamid; Christensen, Jakob M.; Gersen, Sander; Levinsky, Howard; Klippenstein, Stephen J.; Glarborg, Peter

    2016-01-01

    Methane oxidation at high pressures and intermediate temperatures was investigated in a laminar flow reactor and in a rapid compression machine (RCM). The flow-reactor experiments were conducted at 700–900 K and 100 bar for fuel-air equivalence ratios (Φ) ranging from 0.06 to 19.7, all highly

  12. High pressure metrology for industrial applications

    Science.gov (United States)

    Sabuga, Wladimir; Rabault, Thierry; Wüthrich, Christian; Pražák, Dominik; Chytil, Miroslav; Brouwer, Ludwig; Ahmed, Ahmed D. S.

    2017-12-01

    To meet the needs of industries using high pressure technologies, in traceable, reliable and accurate pressure measurements, a joint research project of the five national metrology institutes and the university was carried out within the European Metrology Research Programme. In particular, finite element methods were established for stress–strain analysis of elastic and nonlinear elastic–plastic deformation, as well as of contact processes in pressure-measuring piston-cylinder assemblies, and high-pressure components at pressures above 1 GPa. New pressure measuring multipliers were developed and characterised, which allow realisation of the pressure scale up to 1.6 GPa. This characterisation is based on research including measurements of material elastic constants by the resonant ultrasound spectroscopy, hardness of materials of high pressure components, density and viscosity of pressure transmitting liquids at pressures up to 1.4 GPa and dimensional measurements on piston-cylinders. A 1.6 GPa pressure system was created for operation of the 1.6 GPa multipliers and calibration of high pressure transducers. A transfer standard for 1.5 GPa pressure range, based on pressure transducers, was built and tested. Herewith, the project developed the capability of measuring pressures up to 1.6 GPa, from which industrial users can calibrate their pressure measurement devices for accurate measurements up to 1.5 GPa.

  13. High Temperature Chemistry at NASA: Hot Topics

    Science.gov (United States)

    Jacobson, Nathan S.

    2014-01-01

    High Temperature issues in aircraft engines Hot section: Ni and Co based Superalloys Oxidation and Corrosion (Durability) at high temperatures. Thermal protection system (TPS) and RCC (Reinforced Carbon-Carbon) on the Space Shuttle Orbiter. High temperatures in other worlds: Planets close to their stars.

  14. Development of a method for measuring the density of liquid sulfur at high pressures using the falling-sphere technique.

    Science.gov (United States)

    Funakoshi, Ken-ichi; Nozawa, Akifumi

    2012-10-01

    We describe a new method for the in situ measurement of the density of a liquid at high pressure and high temperature using the falling-sphere technique. Combining synchrotron radiation X-ray radiography with a large-volume press, the newly developed falling-sphere method enables the determination of the density of a liquid at high pressure and high temperature based on Stokes' flow law. We applied this method to liquid sulfur and successfully obtained the density at pressures up to 9 GPa. Our method could be used for the determination of the densities of other liquid materials at higher static pressures than are currently possible.

  15. Advanced Diagnostics for High Pressure Spray Combustion.

    Energy Technology Data Exchange (ETDEWEB)

    Skeen, Scott A.; Manin, Julien Luc; Pickett, Lyle M.

    2014-06-01

    The development of accurate predictive engine simulations requires experimental data to both inform and validate the models, but very limited information is presently available about the chemical structure of high pressure spray flames under engine- relevant conditions. Probing such flames for chemical information using non- intrusive optical methods or intrusive sampling techniques, however, is challenging because of the physical and optical harshness of the environment. This work details two new diagnostics that have been developed and deployed to obtain quantitative species concentrations and soot volume fractions from a high-pressure combusting spray. A high-speed, high-pressure sampling system was developed to extract gaseous species (including soot precursor species) from within the flame for offline analysis by time-of-flight mass spectrometry. A high-speed multi-wavelength optical extinction diagnostic was also developed to quantify transient and quasi-steady soot processes. High-pressure sampling and offline characterization of gas-phase species formed following the pre-burn event was accomplished as well as characterization of gas-phase species present in the lift-off region of a high-pressure n-dodecane spray flame. For the initial samples discussed in this work several species were identified, including polycyclic aromatic hydrocarbons (PAH); however, quantitative mole fractions were not determined. Nevertheless, the diagnostic developed here does have this capability. Quantitative, time-resolved measurements of soot extinction were also accomplished and the novel use of multiple incident wavelengths proved valuable toward characterizing changes in soot optical properties within different regions of the spray flame.

  16. High temperature vapors science and technology

    CERN Document Server

    Hastie, John

    2012-01-01

    High Temperature Vapors: Science and Technology focuses on the relationship of the basic science of high-temperature vapors to some areas of discernible practical importance in modern science and technology. The major high-temperature problem areas selected for discussion include chemical vapor transport and deposition; the vapor phase aspects of corrosion, combustion, and energy systems; and extraterrestrial high-temperature species. This book is comprised of seven chapters and begins with an introduction to the nature of the high-temperature vapor state, the scope and literature of high-temp

  17. High-pressure Synthesis and Physical Properties of New Filled Skutterudite Compound BaOs4P12

    Science.gov (United States)

    Deminami, S.; Kawamura, Y.; Chen, Y. Q.; Kanazawa, M.; Hayashi, J.; Kuzuya, T.; Takeda, K.; Matsuda, M.; Sekine, C.

    2017-10-01

    We have succeeded in synthesizing samples of new filled skutterudite compound BaOs4P12 using the high-pressure synthesis technique. The physical properties of the compound are reported for the first time. The electrical resistivity decreases with decreasing temperature, and drop sharply around 1.8K. This indicates that BaOs4P12 is a new superconductor. Before the high-pressure synthesis, using synchrotron radiation x-ray, we tried to observe synthesizing processes of BaOs4P12 in-situ at high temperature and high pressure to obtain the optimum condition for synthesis.

  18. Influence of High Pressure and High Temperature Hydrogen on Fracture Toughness of Ni-Containing Steels and Alloys

    Directory of Open Access Journals (Sweden)

    Balitskii Alexander

    2014-03-01

    Full Text Available W ramach przeprowadzonych badan okreslono wpływ wodoru na krótkotrwała wytrzymałosc i płasko-naprezeniowa ciagliwosc stali 10Cr15Ni27 oraz stopów niklu 04Cr16Ni56, 05Cr19Ni55 przy wielkosciach cisnienia do 35 MPa i zakresie temperatury od 293 do 773 K. Wpływ wodoru wysokiego cisnienia powoduje, ze wydłuzenie, plastycznosc, wytrzymałosc nisko cyklowa N i parametr odpornosci na pekanie Kc przyjmuja minimalne wartosci dla próbek stopu 04Cr16Ni56 przy cisnieniu wynoszacym 10 MPa, natomiast dla nasyconych wodorem próbek stali 10Cr15Ni27 i stopu 05Cr19Ni55 minimum wartosci tych parametrów wystepuje przy cisnieniu 15 MPa, dla koncentracji wodoru wynoszacej odpowiednio 15 i 19 wppm.

  19. Macroscopic Expressions of Molecular Adiabatic Compressibility of Methyl and Ethyl Caprate under High Pressure and High Temperature

    Directory of Open Access Journals (Sweden)

    Fuxi Shi

    2014-01-01

    Full Text Available The molecular compressibility, which is a macroscopic quantity to reveal the microcompressibility by additivity of molecular constitutions, is considered as a fixed value for specific organic liquids. In this study, we introduced two calculated expressions of molecular adiabatic compressibility to demonstrate its pressure and temperature dependency. The first one was developed from Wada’s constant expression based on experimental data of density and sound velocity. Secondly, by introducing the 2D fitting expressions and their partial derivative of pressure and temperature, molecular compressibility dependency was analyzed further, and a 3D fitting expression was obtained from the calculated data of the first one. The third was derived with introducing the pressure and temperature correction factors based on analogy to Lennard-Jones potential function and energy equipartition theorem. In wide range of temperatures (293

  20. High-pressure and high-temperature powder diffraction on molybdenum diphosphide, MoP{sub 2}

    Energy Technology Data Exchange (ETDEWEB)

    Soto, V. [Centro de Investigacion Cientifica y de Educacion Superior de Ensenada, Esenada (Mexico); Knorr, K.; Ehm, L. [Christian-Albrechts-Univ. zu Kiel, Inst. fuer Geowissenschaften, Mineralogie/Kristallographie, Kiel (Germany); Baehtz, C. [HASYLAB Hamburg and TU Darmstadt, Materialwissenschaften, Darmstadt (Germany); Winkler, B. [Johann-Wolfgang-Goethe Univ. Frankfurt-Main, Mineralogie, Frankfurt/M. (Germany); Avalos-Borja, M. [Centro de Ciencias de la Materia Condensada, Univ. Nacional Autonoma de Mexico, Ensenada, BC (Mexico)

    2004-07-01

    The isothermal compressibility and bulk thermal expansion of molybdenum diphosphide, MoP{sub 2}, were measured by in-situ X-ray powder diffraction from ambient conditions to 6.8 GPa and 839 K, respectively. A small anisotropy of the compressibilities in MoP{sub 2} appears to be governed by non-bonding interactions in this layer-like material. The thermal expansion data are compared to molybdenum phosphide, MoP, which was measured to 1262 K. (orig.)

  1. High-pressure powder x-ray diffraction experiments on Zn at low temperature

    CERN Document Server

    Takemura, K; Fujihisa, H; Kikegawa, T

    2002-01-01

    High-pressure powder x-ray diffraction experiments have been performed on Zn with a He-pressure medium at low temperature. When the sample was compressed in the He medium at low temperature, large nonhydrostaticity developed, yielding erroneous lattice parameters. On the other hand, when the pressure was changed at high temperatures, good hydrostaticity was maintained. No anomaly in the volume dependence of the c/a axial ratio has been found.

  2. Cementing liners through deep high pressure ones

    Energy Technology Data Exchange (ETDEWEB)

    Mahony, B.J.; Barrios, J.R.

    1974-03-01

    Entry of gas into the liner-hole annulus during and after cementing liners though deep high pressure zones, generally results in a gas cut cement column from depth of gas entry to top of liner. Prior to undertaking design of liner cementation, it is necessary to know fracture pressure limits of the formations. It is also necessary to know the formation pore pressure or the pressure required to hold gas in the formation and precisely the depth of formation from which gas emerges. This knowledge may be gained from a study of formation pressure gradients of nearby wells or from sonic log analysis of the interval being readied for cementation. Both single-stage and 2-stage techniques are used to solve liner cementing problems in these high pressure zones. An example sets out conditions which are more or less typical and demonstrates how the problem may be considered and solved.

  3. Inspection technology for high pressure pipes

    Energy Technology Data Exchange (ETDEWEB)

    Kim, Jae H.; Lee, Jae C.; Eum, Heung S.; Choi, Yu R.; Moon, Soon S.; Jang, Jong H

    2000-02-01

    Various kinds of defects are likely to be occurred in the welds of high pressure pipes in nuclear power plants. Considering the recent accident of Zuruga nuclear power plant in Japan, reasonable policy is strongly requested for the high pressure pipe integrity. In this study, we developed the technologies to inspect pipe welds automatically. After development of scanning robot prototype in the first research year, we developed and implemented the algorithm of automatic tracking of the scanning robot along the weld line of the pipes. We use laser slit beam on weld area and capture the image using digital camera. Through processing of the captures image, we finally determine the weld line automatically. In addition, we investigated a new technology on micro systems for developing micro scanning robotic inspection of the pipe welds. The technology developed in this study is being transferred to the industry. (author)

  4. High-pressure oxidation of methane

    DEFF Research Database (Denmark)

    Hashemi, Hamid; Christensen, Jakob Munkholt; Gersen, Sander

    2016-01-01

    Methane oxidation at high pressures and intermediate temperatures was investigated in a laminar flow reactor and in a rapid compression machine (RCM). The flow-reactor experiments were conducted at 700–900 K and 100 bar for fuel-air equivalence ratios (Φ) ranging from 0.06 to 19.7, all highly...... diluted in nitrogen. It was found that under the investigated conditions, the onset temperature for methane oxidation ranged from 723 K under reducing conditions to 750 K under stoichiometric and oxidizing conditions. The RCM experiments were carried out at pressures of 15–80 bar and temperatures of 800......–1250 K under stoichiometric and fuel-lean (Φ=0.5) conditions. Ignition delays, in the range of 1–100 ms, decreased monotonically with increasing pressure and temperature. A chemical kinetic model for high-pressure methane oxidation was established, with particular emphasis on the peroxide chemistry...

  5. Inelastic neutron scattering to very high pressures

    Science.gov (United States)

    Klotz, S.; Braden, M.; Besson, J. M.

    2000-11-01

    Progress in high-pressure and neutron scattering methods has recently allowed measurements of phonon dispersion curves of simple solids at high pressures to 10 GPa. In this technique single crystals of 10 25 mm3 volume are compressed by the Paris-Edinburgh cell and the phonon frequencies are measured on high-flux triple axis spectrometers. Detailed studies of the lattice dynamics of low-compressible systems are feasible, including measurements of mode Grüneisen parameters, elastic constants, and precursor effects of phase transitions. We describe the experimental set-up and illustrate its potential by results on semiconductors (Ge and GaSb) and metals (Fe and Zn) obtained at the LLB (Saclay) and ILL (Grenoble) reactor sources.

  6. Melting point of polymers under high pressure

    Energy Technology Data Exchange (ETDEWEB)

    Seeger, Andreas [Technische Universitaet Darmstadt, Ernst Berl-Institut fuer Technische und Makromolekulare Chemie, Petersenstr. 20, D-64287 Darmstadt (Germany)], E-mail: seeger@chemie.tu-darmstadt.de; Freitag, Detlef [Friedrich-Alexander-Universitaet, Erlangen-Nuernberg (Germany); Freidel, Frank [Technische Universitaet Darmstadt, Ernst Berl-Institut fuer Technische und Makromolekulare Chemie, Petersenstr. 20, D-64287 Darmstadt (Germany); Luft, Gerhard [Technische Universitaet Darmstadt, Ernst Berl-Institut fuer Technische und Makromolekulare Chemie, Petersenstr. 20, D-64287 Darmstadt (Germany)], E-mail: luft@bodo.ct.chemie.tu-darmstadt.de

    2009-03-20

    The influence of highly compressed gases on the melting of polyethylene was investigated for nitrogen, helium and ethylene. The impact of the particle size of the polymer and the heating rate on the melting point were also analysed. The melting points were determined with a high pressure differential thermal analysis (HPDTA) apparatus. These measurements were compared with independent measurements, done by high pressure differential scanning calorimetry (HPDSC), without gas. From this experimental data it was possible to calculate the concentration of the gas in the molten polymer phase based on equilibrium thermodynamics. For high density polyethylene (HDPE), a concentration of nitrogen at the polymer melting point of 10.4-35.7 mL(SATP) g(polymer){sup -1}, in the pressure interval of 65-315 MPa, was calculated.

  7. Stability of xenon oxides at high pressures.

    Science.gov (United States)

    Zhu, Qiang; Jung, Daniel Y; Oganov, Artem R; Glass, Colin W; Gatti, Carlo; Lyakhov, Andriy O

    2013-01-01

    Xenon, which is quite inert under ambient conditions, may become reactive under pressure. The possibility of the formation of stable xenon oxides and silicates in the interior of the Earth could explain the atmospheric missing xenon paradox. Using an ab initio evolutionary algorithm, we predict the existence of thermodynamically stable Xe-O compounds at high pressures (XeO, XeO(2) and XeO(3) become stable at pressures above 83, 102 and 114 GPa, respectively). Our calculations indicate large charge transfer in these oxides, suggesting that large electronegativity difference and high pressure are the key factors favouring the formation of xenon compounds. However, xenon compounds cannot exist in the Earth's mantle: xenon oxides are unstable in equilibrium with the metallic iron occurring in the lower mantle, and xenon silicates are predicted to decompose spontaneously at all mantle pressures (xenon atoms may be retained at defects in mantle silicates and oxides.

  8. High pressure layered structure of carbon disulfide

    OpenAIRE

    Naghavi, S. Shahab; Crespo, Yanier; Martonak, Roman; Tosatti, Erio

    2015-01-01

    Solid CS$_{2}$ is superficially similar to CO$_{2}$, with the same $Cmca$ molecular crystal structure at low pressures, which has suggested similar phases also at high pressures. We carried out an extensive first principles evolutionary search in order to identify the zero temperature lowest enthalpy structures of CS$_{2}$ for increasing pressure up to 200\\,GPa. Surprisingly, the molecular $Cmca$ phase does not evolve into $\\beta$-cristobalite as in CO$_{2}$, but transforms instead into phase...

  9. The high-pressure behavior of bloedite

    DEFF Research Database (Denmark)

    Comodi, Paola; Nazzareni, Sabrina; Balic Zunic, Tonci

    2014-01-01

    High-pressure single-crystal synchrotron X‑ray diffraction was carried out on a single crystal of bloedite [Na2Mg(SO4)24H2O] compressed in a diamond-anvil cell. The volume-pressure data, collected up to 11.2 GPa, were fitted by a second- and a third-order Birch-Murnaghan equation of state (EOS), ...

  10. High Pressure Multicomponent Adsorption in Porous Media

    DEFF Research Database (Denmark)

    Shapiro, Alexander; Stenby, Erling Halfdan

    1999-01-01

    We analyse adsorption of a multicomponent mixture at high pressure on the basis of the potential theory of adsorption. The adsorbate is considered as a segregated mixture in the external field produced by a solid adsorbent. we derive an analytical equation for the thickness of a multicomponent film...... close to a dew point. This equation (asymptotic adsorption equation, AAE) is a first order approximation with regard to the distance from a phase envelope....

  11. observed by high pressure NMR and NQR

    Indian Academy of Sciences (India)

    Abstract. NMR and NQR studies on two interesting systems (URu2Si2, CeTIn5) were performed under high pressure. (1) URu2Si2: In the pressure range 3.0 to 8.3 kbar, we have observed new 29Si. NMR signals arising from the antiferromagnetic (AF) region besides the previously observed 29Si. NMR signals which come ...

  12. CRRT Connected to ECMO: Managing High Pressures.

    Science.gov (United States)

    de Tymowski, Christian; Augustin, Pascal; Houissa, Hamda; Allou, Nicolas; Montravers, Philippe; Delzongle, Alienor; Pellenc, Quentin; Desmard, Mathieu

    Metabolic disorders and fluid overload are indications of continuous renal replacement therapy (CRRT) including continuous venovenous hemofiltration in patients on extracorporeal membrane oxygenation (ECMO). Direct connection of CRRT machine to the ECMO circuit provides many advantages. Nevertheless, because pressures in CRRT lines relate to ECMO blood flow, high ECMO blood flow may be associated with high pressures in CRRT lines. Thus, management of CRRT pressure lines becomes challenging. We evaluated a protocol for managing high CRRT pressures. Connections were performed according to a standardized protocol to maintain CRRT lines in the correct pressure ranges without modifying ECMO settings or inhibiting pressure alarms. To achieve this goal, the way of connecting of CRRT lines was adapted following a standardized protocol. Connection was first attempted between pump and oxygenator in the 12 patients. In five cases, high pressures in CRRT lines were successfully managed by changing the connection segment. Continuous renal replacement therapy parameters were within target levels and reduction of serum creatinine was 37%. In conclusion, management of high pressures in CRRT lines induced by ECMO could be achieved without modifying ECMO blood flow or inhibiting CRRT alarms. Iterative stops were avoided allowing efficient procedures.

  13. Path Dependency of High Pressure Phase Transformations

    Science.gov (United States)

    Cerreta, Ellen

    2017-06-01

    At high pressures titanium and zirconium are known to undergo a phase transformation from the hexagonal close packed (HCP), alpha-phase to the simple-hexagonal, omega-phase. Under conditions of shock loading, the high-pressure omega-phase can be retained upon release. It has been shown that temperature, peak shock stress, and texture can influence the transformation. Moreover, under these same loading conditions, plastic processes of slip and twinning are also affected by similar differences in the loading path. To understand this path dependency, in-situ velocimetry measurements along with post-mortem metallographic and neutron diffraction characterization of soft recovered specimens have been utilized to qualitatively understand the kinetics of transformation, quantify volume fraction of retained omega-phase and characterize the shocked alpha and omega-phases. Together the work described here can be utilized to map the non-equilibrium phase diagram for these metals and lend insight into the partitioning of plastic processes between phases during high pressure transformation. In collaboration with: Frank Addesssio, Curt Bronkhorst, Donald Brown, David Jones, Turab Lookman, Benjamin Morrow, Carl Trujillo, Los Alamos National Lab.; Juan Pablo Escobedo-Diaz, University of New South Wales; Paulo Rigg, Washington State University.

  14. High pressure synthesis gas conversion. Final report

    Energy Technology Data Exchange (ETDEWEB)

    1993-05-01

    The purpose of this research project is to build and test a high pressure fermentation system for the production of ethanol from synthesis gas. The fermenters, pumps, controls, and analytical system were procured or fabricated and assembled in our laboratory. This system was then used to determine the effects of high pressure on growth and ethanol production by Clostridium ljungdahlii. The limits of cell concentration and mass transport relationships were found in CSTR and immobilized cell reactors (ICR). The minimum retention times and reactor volumes were found for ethanol production in these reactors. A maximum operating pressure of 150 psig has been shown to be possible for C. ljungdahlli with the medium of Phillips et al. This medium was developed for atmospheric pressure operation in the CSTR to yield maximum ethanol concentrations and thus is not best for operation at elevated pressures. It is recommended that a medium development study be performed for C. ljungdahlii at increased pressure. Cell concentration, gas conversion and product concentration profiles were presented for C. ljungdahlii as a function of gas flow rate, the variable which affects bacterium performance the most. This pressure was chosen as a representative pressure over the 0--150 psig operating pressure range for the bacterium. Increased pressure negatively affected ethanol productivity probably due to the fact that medium composition was designed for atmospheric pressure operation. Medium development at increased pressure is necessary for high pressure development of the system.

  15. Regional metamorphism at extreme conditions: Implications for orogeny at convergent plate margins

    Science.gov (United States)

    Zheng, Yong-Fei; Chen, Ren-Xu

    2017-09-01

    Regional metamorphism at extreme conditions refers either to Alpine-type metamorphism at low geothermal gradients of 30 °C/km. Extreme pressures refer to those above the polymorphic transition of quartz to coesite, so that ultrahigh-pressure (UHP) eclogite-facies metamorphism occurs at mantle depths of >80 km. Extreme temperatures refer to those higher than 900 °C at crustal depths of ≤80 km, so that ultrahigh-temperature (UHT) granulite-facies metamorphism occurs at medium to high pressures. While crustal subduction at the low geothermal gradients results in blueschist-eclogite facies series without arc volcanism, heating of the thinned orogenic lithosphere brings about the high geothermal gradients for amphibolite-granulite facies series with abundant magmatism. Therefore, UHP metamorphic rocks result from cold lithospheric subduction to the mantle depths, whereas UHT metamorphic rocks are produced by hot underplating of the asthenospheric mantle at the crustal depths. Active continental rifting is developed on the thinned lithosphere in response to asthenospheric upwelling, and this tectonism is suggested as a feasible mechanism for regional granulite-facies metamorphism, with the maximum temperature depending on the extent to which the mantle lithosphere is thinned prior to the rifting. While lithospheric compression is associated with subduction metamorphism in accretionary and collisional orogens, the thinned orogenic lithosphere undergoes extension due to the asthenospheric upwelling to result in orogen-parallel rifting metamorphism and magmatism. Thus, the rifting metamorphism provides a complement to the subduction metamorphism and its operation marks the asthenospheric heating of the orogenic lithosphere. Because of the partial melting and melt extraction of the lower continental crust, contemporaneous granite-migmatite-granulite associations may serve as a petrological indicator of rifting orogeny that is superimposed on precedingly accretionary and

  16. Thermal and shock metamorphism of the sixiangkou ordinary chondrite

    Science.gov (United States)

    Ding, M. W.; Zhang, A. C.; Hsu, W. B.

    2008-01-01

    The Sixiangkou meteorite is a heavily shocked chondrite that contains numerous shock-induced melt veins of various widths. This paper focuses on the petrography and mineralogy of the host portion and shock veins of Sixiangkou. This meteorite contains relict chondrules with obscure structures and shapes. We calculate the peak equilibration temperature (891±36°C) recorded in the Sixiangkou L6 chondrite using the two-pyroxene geothermometer. The thermal metamorphic features of Sixiangkou are in accordance with the petrologic type 6. Olivine in the host portion of the chondrite shows obvious undulatory extinction and planar deformation features. Abundant maskelynite occurs in the chondrite. The shock veins contain numerous coarse-grained ringwoodite, majorite, and fine-grained high-pressure mineral assemblages. On the basis of these observations, Sixiangkou can be graded as S6 on the shock metamorphism scale. And it can also be inferred that the peak pressure which melt veins experienced is about 20GPa---24GPa and the temperature is higher than 2000°C. Merrilite and chromite in the shock veins are possibly transformed back from their high-pressure to low-pressure phases during the prolonged shock event Sixiangkou experienced.

  17. Deep Trek High Temperature Electronics Project

    Energy Technology Data Exchange (ETDEWEB)

    Bruce Ohme

    2007-07-31

    This report summarizes technical progress achieved during the cooperative research agreement between Honeywell and U.S. Department of Energy to develop high-temperature electronics. Objects of this development included Silicon-on-Insulator (SOI) wafer process development for high temperature, supporting design tools and libraries, and high temperature integrated circuit component development including FPGA, EEPROM, high-resolution A-to-D converter, and a precision amplifier.

  18. High Temperature Capacitors for Venus Exploration Project

    Data.gov (United States)

    National Aeronautics and Space Administration — In this SBIR program, TRS Technologies has developed several new dielectrics for high temperature applications including signal conditioning, filtering and energy...

  19. Advances in high temperature chemistry 1

    CERN Document Server

    Eyring, Leroy

    2013-01-01

    Advances in High Temperature Chemistry, Volume 1 describes the complexities and special and changing characteristics of high temperature chemistry. After providing a brief definition of high temperature chemistry, this nine-chapter book goes on describing the experiments and calculations of diatomic transition metal molecules, as well as the advances in applied wave mechanics that may contribute to an understanding of the bonding, structure, and spectra of the molecules of high temperature interest. The next chapter provides a summary of gaseous ternary compounds of the alkali metals used in

  20. High temperature phase equilibria and phase diagrams

    CERN Document Server

    Kuo, Chu-Kun; Yan, Dong-Sheng

    2013-01-01

    High temperature phase equilibria studies play an increasingly important role in materials science and engineering. It is especially significant in the research into the properties of the material and the ways in which they can be improved. This is achieved by observing equilibrium and by examining the phase relationships at high temperature. The study of high temperature phase diagrams of nonmetallic systems began in the early 1900s when silica and mineral systems containing silica were focussed upon. Since then technical ceramics emerged and more emphasis has been placed on high temperature

  1. Metamorphic Rocks in West Irian

    NARCIS (Netherlands)

    Wegen, van der G.

    1971-01-01

    Low-grade metamorphics of West Irian occur to the east of Geelvink Bay associated with two narrow belts of basic and ultrabasic igneous rocks which represent ophiolitic suites of an eugeosynclinical development beginning in Early Mesozoic time. In both of these belts there are indications of

  2. Tectonic evolution of the Mogok metamorphic belt, Burma (Myanmar) constrained by U-Th-Pb dating of metamorphic and magmatic rocks

    Science.gov (United States)

    Searle, M. P.; Noble, S. R.; Cottle, J. M.; Waters, D. J.; Mitchell, A. H. G.; Hlaing, Tin; Horstwood, M. S. A.

    2007-06-01

    The Mogok metamorphic belt (MMB) extends for over 1500 km along the western margin of the Shan-Thai block, from the Andaman Sea north to the eastern Himalayan syntaxis. Previous geochronology has suggested that a long-lasting Jurassic-early Cretaceous subduction-related event resulted in emplacement of granodiorites and orthogneisses (171-120 Ma) and a poorly constrained Tertiary metamorphic event. On the basis of new U-Pb isotope dilution thermal ionization mass spectrometry and U-Th-Pb laser ablation-multicollector-inductively coupled plasma mass spectrometer geochronology presented here, we propose two Tertiary metamorphic events affected the MMB in Burma. The first was a Paleocene event that ended with intrusion of crosscutting postkinematic biotite granite dikes at ˜59 Ma. A second metamorphic event spanned late Eocene to Oligocene (at least from 37, possibly 47, to 29 Ma). This resulted in the growth of metamorphic monazite at sillimanite grade, growth of zircon rims at 47-43 Ma, sillimanite + muscovite replacing older andalusite, and synmetamorphic melting producing garnet and tourmaline bearing leucogranites at 45.5 ± 0.6 Ma and 24.5 ± 0.7 Ma. These data imply high-temperature sillimanite + muscovite metamorphism peaking at 680°C and 4.9 kbar between 45 and 33 Ma, to around 606-656°C and 4.4-4.8 kbar at 29.3 ± 0.5 Ma. The later metamorphic event is older than 24.5 ± 0.3 Ma, the age of leucogranites that crosscut all earlier fabrics. Our structural and geochronological data suggest that the MMB links north to the unexposed middle or lower crust rocks of the Lhasa terrane, south Tibet, and east to high-grade metamorphic core complexes in northwest Thailand.

  3. The compositions of minerals within high pressure tectonic blocks from Horse Mountain, Northern California

    Energy Technology Data Exchange (ETDEWEB)

    Gilliam, C.E. (Mount Holyoke College, South Hadley, MA (United States). Geology Dept.)

    1993-03-01

    High pressure metamorphic blocks occur within serpentinite between the South Fork Mountain Schist and the Coast Range Fault, Humboldt Co., Northern California. Samples from three of these blocks were studied by petrographic techniques and quantitatively analyzed using the energy dispersive spectrometer on out scanning electron microscope. The mineral assemblages for three samples are as follows: WC86-7-3 contains omphacite (jd53, di36, hd11), pumpellyite, and relic igneous clinopyroxene. WC86-9-3 contains titanite, epidote chlorite, pumpellyite, and relic clinopyroxene. WC86-18-3 contains garnet, lawsonite, glaucophane, albite, chlorite, pumpellyite, minor quartz, and relic clinopyroxene. All samples contain relic clinopyroxene that, in the case of SC86-7-3, acts as a nucleus for omphacite growth. When present in cross cutting veins, omphacite has both radiating fibrous and blocky textures. Some epidote, titanite, clinopyroxene and pumpellyite were too fine to identify optically as well, but occur in the ground mass. Large grains of euhedral glaucophane, (Na[sub 2.0] Ca[sub .2])(Mg[sub 1.3] Fe[sub 2.0] Al[sub 1.7])Si[sub 8.0] O[sub 22] (OH)[sub 2], and garnet, (alm 33, pyO, sp30, gr37), containing relic ( ) clinopyroxene, glaucophane, and albite inclusions, were present in WC86-18-3. The high SiO[sub 2] and low TiO[sub 2] relative to Al[sub 2]O[sub 3] in relic clinopyroxene indicates a non-alkaline tholeiitic protolith. Omphacite compositions correspond to the type IV blueschist typical of the Franciscan Complex and constrain the pressures of metamorphism to be approximately 9 kb while lawsonite in WC86-18-3 implies a temperature below 450C. These observations indicate that the blocks are derived from subducted material that underwent metamorphism in a low temperature, high pressure setting. The process of their exhumation remains a mystery.

  4. HIGH PRESSURE COAL COMBUSTON KINETICS PROJECT

    Energy Technology Data Exchange (ETDEWEB)

    Stefano Orsino

    2005-03-30

    As part of the U.S. Department of Energy (DoE) initiative to improve the efficiency of coal-fired power plants and reduce the pollution generated by these facilities, DOE has funded the High-Pressure Coal Combustion Kinetics (HPCCK) Projects. A series of laboratory experiments were conducted on selected pulverized coals at elevated pressures with the specific goals to provide new data for pressurized coal combustion that will help extend to high pressure and validate models for burnout, pollutant formation, and generate samples of solid combustion products for analyses to fill crucial gaps in knowledge of char morphology and fly ash formation. Two series of high-pressure coal combustion experiments were performed using SRI's pressurized radiant coal flow reactor. The first series of tests characterized the near burner flame zone (NBFZ). Three coals were tested, two high volatile bituminous (Pittsburgh No.8 and Illinois No.6), and one sub-bituminous (Powder River Basin), at pressures of 1, 2, and 3 MPa (10, 20, and 30 atm). The second series of experiments, which covered high-pressure burnout (HPBO) conditions, utilized a range of substantially longer combustion residence times to produce char burnout levels from 50% to 100%. The same three coals were tested at 1, 2, and 3 MPa, as well as at 0.2 MPa. Tests were also conducted on Pittsburgh No.8 coal in CO2 entrainment gas at 0.2, 1, and 2 MPa to begin establishing a database of experiments relevant to carbon sequestration techniques. The HPBO test series included use of an impactor-type particle sampler to measure the particle size distribution of fly ash produced under complete burnout conditions. The collected data have been interpreted with the help of CFD and detailed kinetics simulation to extend and validate devolatilization, char combustion and pollutant model at elevated pressure. A global NOX production sub-model has been proposed. The submodel reproduces the performance of the detailed chemical

  5. Heterogeneous flow during high-pressure torsion

    Directory of Open Access Journals (Sweden)

    Roberto B. Figueiredo

    2013-06-01

    Full Text Available High-Pressure Torsion (HPT has attracted significant attention in recent years as an effective technique to process ultrafine and nanostructured materials. The hydrostatic pressure developed during processing prevents the occurrence of cracks and the low thickness to diameter ratio provides the opportunity for developing high strains at low numbers of rotations. The present work analyses the plastic flow during HPT. Experimental results and computer modeling are used to describe heterogeneous plastic flow. It is shown that variations in structure, hardness and in the distribution of strain are observed along the disc thickness. The sources of these heterogeneities are discussed.

  6. Foaming Glass Using High Pressure Sintering

    DEFF Research Database (Denmark)

    Østergaard, Martin Bonderup; Petersen, Rasmus Rosenlund; König, Jakob

    Foam glass is a high added value product which contributes to waste recycling and energy efficiency through heat insulation. The foaming can be initiated by a chemical or physical process. Chemical foaming with aid of a foaming agent is the dominant industrial process. Physical foaming has two...... variations. One way is by saturation of glass melts with gas. The other involves sintering of powdered glass under a high gas pressure resulting in glass pellets with high pressure bubbles entrapped. Reheating the glass pellets above the glass transition temperature under ambient pressure allows the bubbles...

  7. High pressure hydroformylation in the chemical industry

    Energy Technology Data Exchange (ETDEWEB)

    Paciello, R. [BASF Aktiengesellschaft, Ludwigshafen (Germany)

    2006-07-01

    Higher oxo alcohols are intermediates for large-scale applications, such as plasticizers, detergents and fuel additives, as well as being useful in the synthesis of fine chemicals such as vitamins or flavors and fragrances. Many of these alcohols are still made using high pressure technologies. Advantages and disadvantages of different technologies presently in use or being developed are discussed. In particular, efforts to decrease raw material costs, e.g. by increasing yield, or investment, e.g. by decreasing pressure, will be highlighted. (orig.)

  8. High temperature superconducting fault current limiter

    Science.gov (United States)

    Hull, John R.

    1997-01-01

    A fault current limiter (10) for an electrical circuit (14). The fault current limiter (10) includes a high temperature superconductor (12) in the electrical circuit (14). The high temperature superconductor (12) is cooled below its critical temperature to maintain the superconducting electrical properties during operation as the fault current limiter (10).

  9. Technological Evolution of High Temperature Superconductors

    Science.gov (United States)

    2015-12-01

    TEMPERATURE SUPERCONDUCTORS by Jordan R. White December 2015 Thesis Advisor: Clifford Whitcomb Co-Advisor: Fotis Papoulias THIS PAGE INTENTIONALLY...AND SUBTITLE TECHNOLOGICAL EVOLUTION OF HIGH TEMPERATURE SUPERCONDUCTORS 5. FUNDING NUMBERS 6. AUTHOR(S) Jordan R. White 7. PERFORMING ORGANIZATION...trends. 14. SUBJECT TERMS electric ships, high temperature superconductor , HTS 15. NUMBER OF PAGES 111 16. PRICE CODE 17. SECURITY CLASSIFICATION

  10. High Pressure and Temperature Effects in Polymers

    Science.gov (United States)

    Bucknall, David; Arrighi, Valeria; Johnston, Kim; Condie, Iain

    Elastomers are widely exploited as the basis for seals in gas and fluid pipelines. The underlying behaviour of these elastomer at the high pressure, elevated temperatures they experience in operation is poorly understood. Consequently, the duty cycle of these materials is often deliberately limited to a few hours, and in order to prevent failure, production is stopped in order to change the seals in critical joints. The result is significant time lost due to bringing down production to change the seals as well as knock on financial costs. In order to address the fundamental nature of the elastomers at their intended operating conditions, we are studying the gas permeation behaviour of hydrogenated natural butyl rubber (HNBR) and fluorinated elastomers (FKM) at a high pressure and elevated temperature. We have developed a pressure system that permits gas permeation studies at gas pressures of up to 5000 psi and operating temperatures up to 150° C. In this paper, we will discuss the nature of the permeation behaviour at these extreme operating conditions, and how this relates to the changes in the polymer structure. We will also discuss the use of graphene-polymer thin layer coatings to modify the gas permeation behaviour of the elastomers.

  11. High Pressure Hydrogen from First Principles

    Science.gov (United States)

    Morales, M. A.

    2014-12-01

    Typical approximations employed in first-principles simulations of high-pressure hydrogen involve the neglect of nuclear quantum effects (NQE) and the approximate treatment of electronic exchange and correlation, typically through a density functional theory (DFT) formulation. In this talk I'll present a detailed analysis of the influence of these approximations on the phase diagram of high-pressure hydrogen, with the goal of identifying the predictive capabilities of current methods and, at the same time, making accurate predictions in this important regime. We use a path integral formulation combined with density functional theory, which allows us to incorporate NQEs in a direct and controllable way. In addition, we use state-of-the-art quantum Monte Carlo calculations to benchmark the accuracy of more approximate mean-field electronic structure calculations based on DFT, and we use GW and hybrid DFT to calculate the optical properties of the solid and liquid phases near metallization. We present accurate predictions of the metal-insulator transition on the solid, including structural and optical properties of the molecular phase. This work was supported by the U.S. Department of Energy at the Lawrence Livermore National Laboratory under Contract DE-AC52-07NA27344 and by LDRD Grant No. 13-LW-004.

  12. Is sodium a superconductor under high pressure?

    Science.gov (United States)

    Tutchton, Roxanne; Chen, Xiaojia; Wu, Zhigang

    2017-01-07

    Superconductivity has been predicted or measured for most alkali metals under high pressure, but the computed critical temperature (T c ) of sodium (Na) at the face-centered cubic (fcc) phase is vanishingly low. Here we report a thorough, first-principles investigation of superconductivity in Na under pressures up to 260 GPa, where the metal-to-insulator transition occurs. Linear-response calculations and density functional perturbation theory were employed to evaluate phonon distributions and the electron-phonon coupling for bcc, fcc, cI16, and tI19 Na. Our results indicate that the maximum electron-phonon coupling parameter, λ, is 0.5 for the cI16 phase, corresponding to a theoretical peak in the critical temperature at T c ≈1.2 K. When pressure decreases or increases from 130 GPa, T c drops quickly. This is mainly due to the lack of p-d hybridization in Na even at 260 GPa. Since current methods based on the Eliashberg and McMillian formalisms tend to overestimate the T c (especially the peak values) of alkali metals, we conclude that under high pressure-before the metal-to-insulator transition at 260 GPa-superconductivity in Na is very weak, if it is measurable at all.

  13. Comparison of the high-pressure schist belts of New Caledonia and Sanbagawa, Japan

    Science.gov (United States)

    Brothers, R. N.; Yokoyama, K.

    1982-06-01

    The high-pressure schist terranes of New Caledonia and Sanbagawa were developed along the oceanic sides of sialic forelands by tectonic burial metamorphism. The parent rocks were chemically similar, as volcanic-sedimentary trough or trench sequences, and metamorphic temperatures in both belts were 250° to 600° C. From phase equilibria curves, total pressures were higher for New Caledonia (6 15 kb) than for Sanbagawa (5 11 kb) and the estimated thermal gradients were 7 10° C/km and 15° C/km respectively. PT paths identify the higher pressure in New Caledonia ( P differences 2 kb at 300° C and 4 kb at 550° C) with consequent contrast in progressive regional metamorphic zonation for pelites in the two areas: lawsonite-epidote-omphacite (New Caledonia) and chlorite-garnet-biotite (Sanbagawa). In New Caledonia the Na-amphibole is dominantly glaucophane and Na-pyroxenes associated with quartz are Jadeite (Jd95 100) and omphacite; in Sanbagawa the amphibole is crossite or riebeckite and the pyroxene is omphacite (Jd50). For both areas, garnet rims show increase in pyrope content with advancing grade, but Sanbagawa garnets are richer in almandine. Progressive assemblages within the two belts can be equated by such reactions as: New Caledonia Sanbagawa glaucophane+paragonite+H2O⇌albite+chlorite+quartz glaucophane+epidote+H2O⇌albite+chlorite+actinolite and the lower pressure Japanese associations appear as retrogressive phases in the New Caledonia epidote and omphacite zones. The contrasts in PT gradient, regional zonation and mineralogy are believed due to differences in the tectonic control of metamorphic burial: for New Caledonia, rapid obduction of an upper sialic plate over an inert oceanic plate and sedimentary trough; and for Sanbagawa, slower subduction of trench sediments beneath a relatively immobile upper plate.

  14. High-Pressure Minerals in Meteorites: Constraints on Shock Conditions and Duration

    Science.gov (United States)

    Sharp, Thomas G.

    2004-01-01

    The objective of this research was to better understand the conditions and duration of shock metamorphism in meteorites through microstructural and microanalytical characterization of high-pressure minerals. A) Continue to investigate the mineralogy and microstructures of melt-veins in a suite of chondritic samples ranging from shock grades S3 through S6 to determine how the mineral assemblages that crystallize at high-pressure and are related to shock grade. B) Investigate the chemical, mineralogical, and microstructural heterogeneities that occur across melt veins to interpret crystallization histories. C) Use static high-pressure experiments to simulate crystallization of melt veins for mineralogical and textural comparisons with the melt veins of naturally shocked samples. D) Characterize the compositions and defect microstructures of polycrystalline ringwoodite, wadsleyite, majorite, (Mg,Fe)Si03-ilmenite and (Mg,Fe)SiO3-perovskite in S6 samples to understand the mechanisms of phase transformations that occur during shock. These results will combined with kinetic data to constrain the time scales of kinetic processes. E) Investigate the transformations of metastable high-pressure minerals back to low- pressure forms to constrain post-shock temperatures and estimates of the peak shock pressure. Of these objectives, we have obtained publishable data on A, B and D. I am currently doing difficult high-pressure melting and quench experiments on an L chondrite known as Mbale. These experiments will provide additional constraints on the mineral assemblages that are produced during rapid quench of an L chondrite at pressures of 16 to 25 GPa. Results from published or nearly published research is presented below. Lists of theses, dissertations and publications are given below.

  15. Production of nanograined intermetallics using high-pressure torsion

    Energy Technology Data Exchange (ETDEWEB)

    Alhamidi, Ali; Edalati, Kaveh; Horita, Zenji, E-mail: horita@zaiko.kyushu-u.ac.jp [Department of Materials Science and Engineering, Faculty of Engineering, Kyushu University, Fukuoka (Japan)

    2013-11-01

    Formation of intermetallics is generally feasible at high temperatures when the lattice diffusion is fast enough to form the ordered phases. This study shows that nanograined intermetallics are formed at a low temperature as 573 K in Al- 25 mol% Ni, Al- 50 mol.% Ni and Al- 50 mol% Ti powder mixtures through powder consolidation using high-pressure torsion (HPT). For the three compositions, the hardness gradually increases with straining but saturates to the levels as high as 550-920 Hv. In addition to the high hardness, the TiAl material exhibits high yield strength as {approx}3 GPa with good ductility as {approx}23%, when they are examined by micropillar compression tests. X-ray diffraction analysis and high-resolution transmission electron microscopy reveal that the significant increase in hardness and strength is due to the formation of nanograined intermetallics such as Al{sub 3}Ni, Al{sub 3}Ni{sub 2}, TiAl{sub 3}, TiAl{sub 2} and TiAl with average grain sizes of 20-40 nm (author)

  16. Plastic deformation of silicate garnets. I. High-pressure experiments

    Science.gov (United States)

    Voegelé, V.; Ando, J. I.; Cordier, P.; Liebermann, R. C.

    Deformation experiments have been carried out on garnet single crystals (Py20 Al73 Sp2 Gr5) under high confining pressure (6.5 GPa) and temperatures in the range 700-1440°C. The high-pressure sample assembly was designed to generate high differential stress. Below 1000°C, the specimens show only evidence of microplasticity associated with microcracking. Above 1000°C, garnet become ductile and the microstructure is characteristic of dislocation creep with significant recovery. The observed glide systems are 1/2{11¯0}, 1/2{112¯}, 1/2{123¯}, {010} and {011} in the whole temperature range. The most stable (and hence less mobile) dislocation lines appear to be the 70° 1/2 (i.e., with a large edge component) and edge . Except for some rare dislocations generated at low temperature, most of the dislocations exhibit no visible dissociation. The detailed characterization of the dislocations suggests that they have an extended, non-planar core. This core structure induces a high Peierls friction and is responsible for the brittle behavior of garnets at low temperature. The Peierls regime extends up to high temperature until diffusion takes place and enhances dislocation climb superimposed to glide.

  17. High pressure die casting of Fe-based metallic glass.

    Science.gov (United States)

    Ramasamy, Parthiban; Szabo, Attila; Borzel, Stefan; Eckert, Jürgen; Stoica, Mihai; Bárdos, András

    2016-10-11

    Soft ferromagnetic Fe-based bulk metallic glass key-shaped specimens with a maximum and minimum width of 25.4 and 5 mm, respectively, were successfully produced using a high pressure die casting (HPDC) method, The influence of die material, alloy temperature and flow rate on the microstructure, thermal stability and soft ferromagnetic properties has been studied. The results suggest that a steel die in which the molten metal flows at low rate and high temperature can be used to produce completely glassy samples. This can be attributed to the laminar filling of the mold and to a lower heat transfer coefficient, which avoids the skin effect in the steel mold. In addition, magnetic measurements reveal that the amorphous structure of the material is maintained throughout the key-shaped samples. Although it is difficult to control the flow and cooling rate of the molten metal in the corners of the key due to different cross sections, this can be overcome by proper tool geometry. The present results confirm that HPDC is a suitable method for the casting of Fe-based bulk glassy alloys even with complex geometries for a broad range of applications.

  18. High pressure die casting of Fe-based metallic glass

    Science.gov (United States)

    Ramasamy, Parthiban; Szabo, Attila; Borzel, Stefan; Eckert, Jürgen; Stoica, Mihai; Bárdos, András

    2016-10-01

    Soft ferromagnetic Fe-based bulk metallic glass key-shaped specimens with a maximum and minimum width of 25.4 and 5 mm, respectively, were successfully produced using a high pressure die casting (HPDC) method, The influence of die material, alloy temperature and flow rate on the microstructure, thermal stability and soft ferromagnetic properties has been studied. The results suggest that a steel die in which the molten metal flows at low rate and high temperature can be used to produce completely glassy samples. This can be attributed to the laminar filling of the mold and to a lower heat transfer coefficient, which avoids the skin effect in the steel mold. In addition, magnetic measurements reveal that the amorphous structure of the material is maintained throughout the key-shaped samples. Although it is difficult to control the flow and cooling rate of the molten metal in the corners of the key due to different cross sections, this can be overcome by proper tool geometry. The present results confirm that HPDC is a suitable method for the casting of Fe-based bulk glassy alloys even with complex geometries for a broad range of applications.

  19. Metamorphic evolution of aluminous granulites from Labwor Hills, Uganda

    Science.gov (United States)

    Sandiford, Michael; Neall, Fiona B.; Powell, Roger

    1987-02-01

    Sapphirine-cordierite-quartz and spinel-cordierite-quartz form relic assemblages of probable Archaean age in Fe-rich aluminous metapelites from Labwor Hills, Uganda, and reflect an unusually high temperature metamorphism (˜1,000° C) at pressures in the vicinity of 7 9 kbars and a(O2) near the magnetite-hematite buffer. Subsequent reaction textures include the replacement of spinel and cordierite by sillimanite and hypersthene and formation of sapphirine-hypersthene-K-feldspar-quartz symplectites which are interpreted as pseudomorphs after osumilite. A petrogenetic grid appropriate to these assemblages suggests these reaction textures may be due to cooling at constant or increasing pressure and constant a(O2), or decreasing a(O2) at constant temperature and pressure. The former interpretation is supported by the coexistence of ilmenohematite and magnetite during the development of the reaction textures, and by the comparatively low Al2O3-contents of secondary hypersthene. This pressure-temperature path implies that: (1) metamorphism occurred at deep levels within normal thickness crust, probably less than 40 45 km thick, due to an extreme thermal perturbation induced either by emplacement of mantle-derived magmas or by thinning of the subcontinental lithosphere in an extensional tectonic regime, (2) the excavation and surface exposure of the granulites is due to a subsequent, postgranulite facies metamorphism, crustal thickening most probably involving their incorporation into an allochthonous upper crustal thrust sheet during the formation of the Mozambique foldbelt.

  20. High temperature triaxial tests on Rochester shale

    Science.gov (United States)

    Bruijn, Rolf; Burlini, Luigi; Misra, Santanu

    2010-05-01

    Phyllosilicates are one of the major components of the crust, responsible for strength weakening during deformation. High pressure and temperature experiments of natural samples rich in phyllosilicates are needed to test the relevance of proposed weakening mechanisms induced by phyllosilicates, derived from lab experiments on single phase and synthetic polyphase rocks and single crystals. Here, we present the preliminary results of a series of high temperature triaxial tests performed on the illite-rich Rochester Shale (USA - New York) using a Paterson type gas-medium HPT testing machine. Cylindrical samples with homogeneous microstructure and 12-14% porosity were fabricated by cold and hot-isostatically pressing, hot-pressed samples were deformed up to a total shortening of 7.5 to 13%. To study the significance of mica dehydration, iron or copper jackets were used in combination with non-porous or porous spacers. Water content was measured before and after experiments using Karl Fischer Titration (KFT). All experiments show, after yielding at 0.6% strain, rapid hardening in nearly linear fashion until about 4-5% strain, from where stress increases at reducing rates to values at 10% strain, between 400 and 675 MPa, depending on experimental conditions. Neither failure nor steady state however, is achieved within the maximum strain of 13%. Experiments performed under 500 °C and 300 MPa confining pressure show weak strain rate dependence. In addition, iron-jacketed samples appear harder than copper-jacketed ones. At 700 °C samples are 17 to 37% weaker and more sensitive to strain rate than during 500 °C experiments. Although, iron-jacketed samples behave stronger than copper-jacketed ones. By visual inspection, samples appear homogeneously shortened. Preliminary analysis suggests that deformation is mostly accommodated by pore collapse. Although, with finite strain, pore collapse becomes less significant. A temperature, strain rate and jacket material dependent

  1. New developments in high pressure x-ray spectroscopy beamline at High Pressure Collaborative Access Team.

    Science.gov (United States)

    Xiao, Y M; Chow, P; Boman, G; Bai, L G; Rod, E; Bommannavar, A; Kenney-Benson, C; Sinogeikin, S; Shen, G Y

    2015-07-01

    The 16 ID-D (Insertion Device - D station) beamline of the High Pressure Collaborative Access Team at the Advanced Photon Source is dedicated to high pressure research using X-ray spectroscopy techniques typically integrated with diamond anvil cells. The beamline provides X-rays of 4.5-37 keV, and current available techniques include X-ray emission spectroscopy, inelastic X-ray scattering, and nuclear resonant scattering. The recent developments include a canted undulator upgrade, 17-element analyzer array for inelastic X-ray scattering, and an emission spectrometer using a polycapillary half-lens. Recent development projects and future prospects are also discussed.

  2. Blue emitting organic semiconductors under high pressure

    DEFF Research Database (Denmark)

    Knaapila, Matti; Guha, Suchismita

    2016-01-01

    highlighted by high pressure optical spectroscopy whilst analogous x-ray diffraction experiments remain less frequent. By focusing on a class of blue-emitting π-conjugated polymers, polyfluorenes, this article reviews optical spectroscopic studies under hydrostatic pressure, addressing the impact of molecular......This review describes essential optical and emerging structural experiments that use high GPa range hydrostatic pressure to probe physical phenomena in blue-emitting organic semiconductors including π-conjugated polyfluorene and related compounds. The work emphasizes molecular structure...... and intermolecular self-organization that typically determine transport and optical emission in π-conjugated oligomers and polymers. In this context, hydrostatic pressure through diamond anvil cells has proven to be an elegant tool to control structure and interactions without chemical intervention. This has been...

  3. High pressure chemistry of substituted acetylenes

    Energy Technology Data Exchange (ETDEWEB)

    Chellappa, Raja [Los Alamos National Laboratory; Dattelbaum, Dana [Los Alamos National Laboratory; Sheffield, Stephen [Los Alamos National Laboratory; Robbins, David [Los Alamos National Laboratory

    2011-01-25

    High pressure in situ synchrotron x-ray diffraction experiments were performed on substituted polyacetylenes: tert-butyl acetylene [TBA: (CH{sub 3}){sub 3}-C{triple_bond}CH] and ethynyl trimethylsilane [ETMS: (CH{sub 3}){sub 3}-Si{triple_bond}CH] to investigate pressure-induced chemical reactions. The starting samples were the low temperature crystalline phases which persisted metastably at room temperature and polymerized beyond 11 GPa and 26 GPa for TBA and ETMS respectively. These reaction onset pressures are considerably higher than what we observed in the shockwave studies (6.1 GPa for TBA and 6.6 GPa for ETMS). Interestingly, in the case of ETMS, it was observed with fluid ETMS as starting sample, reacts to form a semi-crystalline polymer (crystalline domains corresponding to the low-T phase) at pressures less than {approx}2 GPa. Further characterization using vibrational spectroscopy is in progress.

  4. High pressure photophysics of organic molecules

    Energy Technology Data Exchange (ETDEWEB)

    Brey, L. A.

    1979-01-01

    High pressure spectroscopic studies on several classes of organic compounds were made both in fluid solution (to 10 kbar) and in polymeric media (to 40 kbar). The first three studies were conducted in fluid solution and concern the effect of solvent viscosity on the nonradiative deactivation rates from electronically excited states. Pressure was utilized to attain high viscosities in organic solvents at room temperature. The primary experimental technique used was fluorescence emission spectroscopy. In the fourth and last study observations were made both in fluid solution and in plastic films. The focus of this study was the effect of pressure on the solvent-chromophore dispersion interaction in several polyenes and the concomitant changes in both the radiative and non-radiative rates from the excited states. Extensive use was made of fluorescence lifetime measurements and excitation spectra. 105 references.

  5. Superconductivity from magnetic elements under high pressure

    Energy Technology Data Exchange (ETDEWEB)

    Shimizu, Katsuya [KYOKUGEN, Research Center for Materials Science at Extreme Conditions, Osaka University, Osaka 560-8531 (Japan)]. E-mail: shimizu@rcem.osaka-u.ac.jp; Amaya, Kiichi [Toyota Physical and Chemical Research Institute, Aichi 480-1192 (Japan); Suzuki, Naoshi [Graduate School of Engineering Science, Osaka University, Osaka 560-8531 (Japan); Onuki, Yoshichika [Graduate School of Science, Osaka University, Osaka 560-0043 (Japan)

    2006-05-01

    Can we expect the appearance of superconductivity from magnetic elements? In general, superconductivity occurs in nonmagnetic metal at low temperature and magnetic impurities destroy superconductivity; magnetism and superconductivity are as incompatible as oil and water. Here, we present our experimental example of superconducting elements, iron and oxygen. They are magnetic at ambient pressure, however, they become nonmagnetic under high pressure, then superconductor at low temperature. What is the driving force of the superconductivity? Our understanding in the early stages was a simple scenario that the superconductive state was obtained as a consequence of an emergence of the nonmagnetic states. In both cases, we may consider another scenario for the appearance of superconductivity; the magnetic fluctuation mechanism in the same way as unconventional superconductors.

  6. Polymerization of Formic Acid under High Pressure

    Energy Technology Data Exchange (ETDEWEB)

    Goncharov, A F; Manaa, M R; Zaug, J M; Fried, L E; Montgomery, W B

    2004-08-23

    We report combined Raman, infrared (IR) and x-ray diffraction (XRD) measurements, along with ab initio calculations on formic acid under pressure up to 50 GPa. Contrary to the report of Allan and Clark (PRL 82, 3464 (1999)), we find an infinite chain low-temperature Pna2{sub 1} structure consisting of trans molecules to be a high-pressure phase at room temperature. Our data indicate the symmetrization and a partially covalent character of the intra-chain hydrogen bonds above approximately 20 GPa. Raman spectra and XRD patterns indicate a loss of the long-range order at pressures above 40 GPa with a large hysteresis at decompression. We attribute this behavior to a three-dimensional polymerization of formic acid.

  7. High pressure Raman scattering of silicon nanowires

    Energy Technology Data Exchange (ETDEWEB)

    Khachadorian, Sevak; Scheel, Harald; Thomsen, Christian [Institut fuer Festkoerperphysik, Technische Universitaet Berlin, 10623 Berlin (Germany); Papagelis, Konstantinos [Materials Science Department, University of Patras, 26504 Patras (Greece); Colli, Alan [Nokia Research Centre, 21 J J Thomson Avenue, Cambridge CB3 0FA (United Kingdom); Ferrari, Andrea C, E-mail: khachadorian@physik.tu-berlin.de [Department of Engineering, University of Cambridge, Cambridge CB3 0FA (United Kingdom)

    2011-05-13

    We study the high pressure response, up to 8 GPa, of silicon nanowires (SiNWs) with {approx} 15 nm diameter, by Raman spectroscopy. The first order Raman peak shows a superlinear trend, more pronounced compared to bulk Si. Combining transmission electron microscopy and Raman measurements we estimate the SiNWs' bulk modulus and the Grueneisen parameters. We detect an increase of Raman linewidth at {approx} 4 GPa, and assign it to pressure induced activation of a decay process into LO and TA phonons. This pressure is smaller compared to the {approx} 7 GPa reported for bulk Si. We do not observe evidence of phase transitions, such as discontinuities or change in the pressure slopes, in the investigated pressure range.

  8. Urea and deuterium mixtures at high pressures

    Energy Technology Data Exchange (ETDEWEB)

    Donnelly, M., E-mail: m.donnelly-2@sms.ed.ac.uk; Husband, R. J.; Frantzana, A. D.; Loveday, J. S. [Centre for Science at Extreme Conditions and School of Physics and Astronomy, The University of Edinburgh, Erskine Williamson Building, Peter Guthrie Tait Road, The King’s Buildings, Edinburgh EH9 3FD (United Kingdom); Bull, C. L. [ISIS, Rutherford Appleton Laboratory, Oxford Harwell, Didcot OX11 0QX (United Kingdom); Klotz, S. [IMPMC, CNRS UMR 7590, Université P and M Curie, 4 Place Jussieu, 75252 Paris (France)

    2015-03-28

    Urea, like many network forming compounds, has long been known to form inclusion (guest-host) compounds. Unlike other network formers like water, urea is not known to form such inclusion compounds with simple molecules like hydrogen. Such compounds if they existed would be of interest both for the fundamental insight they provide into molecular bonding and as potential gas storage systems. Urea has been proposed as a potential hydrogen storage material [T. A. Strobel et al., Chem. Phys. Lett. 478, 97 (2009)]. Here, we report the results of high-pressure neutron diffraction studies of urea and D{sub 2} mixtures that indicate no inclusion compound forms up to 3.7 GPa.

  9. High-pressure structures of methane hydrate

    CERN Document Server

    Hirai, H; Fujihisa, H; Sakashita, M; Katoh, E; Aoki, K; Yamamoto, Y; Nagashima, K; Yagi, T

    2002-01-01

    Three high-pressure structures of methane hydrate, a hexagonal structure (str. A) and two orthorhombic structures (str. B and str. C), were found by in situ x-ray diffractometry and Raman spectroscopy. The well-known structure I (str. I) decomposed into str. A and fluid at 0.8 GPa. Str. A transformed into str. B at 1.6 GPa, and str. B further transformed into str. C at 2.1 GPa which survived above 7.8 GPa. The fluid solidified as ice VI at 1.4 GPa, and the ice VI transformed to ice VII at 2.1 GPa. The bulk moduli, K sub 0 , for str. I, str. A, and str. C were calculated to be 7.4, 9.8, and 25.0 GPa, respectively.

  10. Aeronautical applications of high-temperature superconductors

    Science.gov (United States)

    Turney, George E.; Luidens, Roger W.; Uherka, Kenneth; Hull, John

    1989-01-01

    The successful development of high-temperature superconductors (HTS) could have a major impact on future aeronautical propulsion and aeronautical flight vehicle systems. A preliminary examination of the potential application of HTS for aeronautics indicates that significant benefits may be realized through the development and implementation of these newly discovered materials. Applications of high-temperature superconductors (currently substantiated at 95 k) were envisioned for several classes of aeronautical systems, including subsonic and supersonic transports, hypersonic aircraft, V/STOL aircraft, rotorcraft, and solar, microwave and laser powered aircraft. Introduced and described are the particular applications and potential benefits of high-temperature superconductors as related to aeronautics and/or aeronautical systems.

  11. Symposium on high temperature and materials chemistry

    Energy Technology Data Exchange (ETDEWEB)

    1989-10-01

    This volume contains the written proceedings of the Symposium on High Temperature and Materials Chemistry held in Berkeley, California on October 24--25, 1989. The Symposium was sponsored by the Materials and Chemical Sciences Division of Lawrence Berkeley Laboratory and by the College of Chemistry of the University of California at Berkeley to discuss directions, trends, and accomplishments in the field of high temperature and materials chemistry. Its purpose was to provide a snapshot of high temperature and materials chemistry and, in so doing, to define status and directions.

  12. High Temperature Permeability of Carbon Cloth Phenolic Composite

    Science.gov (United States)

    Park, O. Y.; Lawrence, T. W.

    2003-01-01

    The carbon fiber phenolic resin composite material used for the RSRM nozzle insulator occasionally experiences problems during operation from pocketing or spalling-like erosion and lifting of plies into the char layer. This phenomenon can be better understood if the permeability of the material at elevated temperatures is well defined. This paper describes an experimental approach to determining high temperature permeability of the carbon phenolic material used as the RSRM nozzle liner material. Two different approaches were conducted independently using disk and bar type specimens with the designed permeability apparatus. The principle of the apparatus was to subject a test specimen to a high pressure differential and a heat supply and to monitor both the pressure and temperature variations resulting from gas penetration through the permeable wall between the two chambers. The bar types, especially designed to eliminate sealing difficulties at a high temperature environment, were directly exposed to real time temperature elevation from 22 C to 260 C during the test period. The disk types were pre-heat treated up to 300 C for 8 hours and cooled to room temperature before testing. Nonlinear variation of downstream pressure at a certain temperature range implied moisture release and matrix pyrolysis. Permeability was calculated using a semi-numerical model of quasi-steady state. The test results and the numerical model are discussed in the paper.

  13. High-Temperature-High-Volume Lifting for Enhanced Geothermal Systems

    Energy Technology Data Exchange (ETDEWEB)

    Turnquist, Norman [GE Global Research, Munchen (Germany); Qi, Xuele [GE Global Research, Munchen (Germany); Raminosoa, Tsarafidy [GE Global Research, Munchen (Germany); Salas, Ken [GE Global Research, Munchen (Germany); Samudrala, Omprakash [GE Global Research, Munchen (Germany); Shah, Manoj [GE Global Research, Munchen (Germany); Van Dam, Jeremy [GE Global Research, Munchen (Germany); Yin, Weijun [GE Global Research, Munchen (Germany); Zia, Jalal [GE Global Research, Munchen (Germany)

    2013-12-20

    for high-temperature operation. In parallel with the design and fabrication of the subscale prototype ESP system, a subscale test facility consisting of a high-temperature-high-pressure flow loop was designed, fabricated, and installed at GE Global Research in Niskayuna, NY. A test plan for the prototype system was also established. The original plan of testing the prototype hardware in the flow loop was delayed until a future date.

  14. High-temperature sapphire optical sensor fiber coatings

    Science.gov (United States)

    Desu, Seshu B.; Claus, Richard O.; Raheem, Ruby; Murphy, Kent A.

    1990-10-01

    Advanced coal-fired power generation systems, such as pressurized fluidized-bed combustors and integrated gasifier-combined cycles, may provide cost effective future alternatives for power generation, improve our utilization of coal resources, and decrease our dependence upon oil and gas. When coal is burned or converted to combustible gas to produce energy, mineral matter and chemical compounds are released as solid and gaseous contaminants. The control of contaminants is mandatory to prevent pollution as well as degradation of equipment in advanced power generation. To eliminate the need for expensive heat recovery equipment and to avoid efficiency losses it is desirable to develop a technology capable of cleaning the hot gas. For this technology the removal of particle contaminants is of major concern. Several prototype high temperature particle filters have been developed, including ceramic candle filters, ceramic bag filters, and ceramic cross-flow (CXF) filters. Ceramic candle filters are rigid, tubular filters typically made by bonding silicon carbide or alumina-silica grains with clay bonding materials and perhaps including alumina-silica fibers. Ceramic bag filters are flexible and are made from long ceramic fibers such as alumina-silica. CXF filters are rigid filters made of stacks of individual lamina through which the dirty and clean gases flow in cross-wise directions. CXF filters are advantageous for hot gas cleanup applications since they offer a large effective filter surface per unit volume. The relatively small size of the filters allows the pressurized vessel containing them to be small, thus reducing potential equipment costs. CXF filters have shown promise but have experienced degradation at normal operational high temperatures (close to 1173K) and high pressures (up to 24 bars). Observed degradation modes include delamination of the individual tile layers, cracking at either the tile-torid interface or at the mounting flange, or plugging of

  15. Systems and methods for enhancing isolation of high-temperature reactor containments

    Energy Technology Data Exchange (ETDEWEB)

    Peterson, Per F.

    2017-09-26

    A high-temperature containment-isolation system for transferring heat from a nuclear reactor containment to a high-pressure heat exchanger is presented. The system uses a high-temperature, low-volatility liquid coolant such as a molten salt or a liquid metal, where the coolant flow path provides liquid free surfaces a short distance from the containment penetrations for the reactor hot-leg and the cold-leg, where these liquid free surfaces have a cover gas maintained at a nearly constant pressure and thus prevent high-pressures from being transmitted into the reactor containment, and where the reactor vessel is suspended within a reactor cavity with a plurality of refractory insulator blocks disposed between an actively cooled inner cavity liner and the reactor vessel.

  16. Novel High Pressure Pump-on-a-Chip Technology Project

    Data.gov (United States)

    National Aeronautics and Space Administration — HJ Science & Technology, Inc. proposes to develop a novel high pressure "pump-on-a-chip" (HPPOC) technology capable of generating high pressure and flow rate on...

  17. High Temperature Solid State Lithium Battery Project

    Data.gov (United States)

    National Aeronautics and Space Administration — Reliable energy systems with high energy density capable of operating at high temperatures, pressures and radiation levels are needed for certain NASA missions....

  18. Novel High Temperature Strain Gauge Project

    Data.gov (United States)

    National Aeronautics and Space Administration — Advanced high-temperature sensor technology and bonding methods are of great interests in designing and developing advanced future aircraft. Current state-of-the-art...

  19. High Temperature Fiberoptic Thermal Imaging System Project

    Data.gov (United States)

    National Aeronautics and Space Administration — The proposed Phase 1 program will fabricate and demonstrate a small diameter single fiber endoscope that can perform high temperature thermal imaging in a jet engine...

  20. High Temperature Capacitors for Venus Exploration Project

    Data.gov (United States)

    National Aeronautics and Space Administration — High temperature power electronics have become a vital aspect of future designs for power converters in spacecraft, battle zone electric power, satellite power...

  1. Ion Based High-Temperature Pressure Sensor

    National Research Council Canada - National Science Library

    Zdenek, Jeffrey S; Anthenien, Ralph A

    2004-01-01

    .... The environment encountered in such engines necessitates high temperature and durable (vibration resistant) devices. Traditional pressure sensors can be used, however thermal insulating materials must be used to protect the diaphragm...

  2. Lightweight, High-Temperature Radiator Panels Project

    Data.gov (United States)

    National Aeronautics and Space Administration — Lightweight, high-temperature radiators are needed for future, high-efficiency power conversion systems for Nuclear Electric Propulsion (NEP). Creare has developed...

  3. Panel report on high temperature ceramics

    Energy Technology Data Exchange (ETDEWEB)

    Nolet, T C [ed.

    1979-01-01

    Fundamental research is reported concerning high temperature ceramics for application in turbines, engines, batteries, gasifiers, MHD, fuel cells, heat exchangers, and hot wall combustors. Ceramics microstructure and behavior are included. (FS)

  4. High Temperature Rechargeable Battery Development Project

    Data.gov (United States)

    National Aeronautics and Space Administration — This small business innovation research is intended to develop and proof the concept of a highly efficient, high temperature rechargeable battery for supporting...

  5. Mechanical Proprieties of Steel at High Temperatures

    Directory of Open Access Journals (Sweden)

    Ana-Diana Ancaş

    2005-01-01

    Full Text Available The experimental test results obtained in the study of steel mechanical proprieties variation in case of high temperatures (fire are presented. The proprieties are referring to: Young’s modulus, E, the elastic limit, σe, and the characteristic diagram of the material (the rotation stress-strain. Theoretical laws that the model the steel behaviour at high temperature have been elaborated based on the most significant studies presented in the literature.

  6. High temperature superconductors and other superfluids

    CERN Document Server

    Alexandrov, A S

    2017-01-01

    Written by eminent researchers in the field, this text describes the theory of superconductivity and superfluidity starting from liquid helium and a charged Bose-gas. It also discusses the modern bipolaron theory of strongly coupled superconductors, which explains the basic physical properties of high-temperature superconductors. This book will be of interest to fourth year graduate and postgraduate students, specialist libraries, information centres and chemists working in high-temperature superconductivity.

  7. Development and Operation of the AEDC High Temperature Wall Laboratory (HTWL)

    Science.gov (United States)

    1995-04-01

    AEDC-TMR-95-P1 III it" DEVELOPMENT AND OPERATION OF THE AEDC HIGH TEMPERATURE WALL LABORATORY (HTWL) G. R. Beitel Micro Craft Technology/AEDC...PROJECT NUMBER 5e. TASK NUMBER 5f. WORK UNIT NUMBER 7. PERFORMING ORGANIZATION NAME(S) AND ADDRESS(ES) Micro Craft Technology/AEDC Operations...29 5. HTWL Equipment Layout 32 6. Ballast Resistor Bank and Water Flow System Details 33 7. HTL High Pressure Demineralized Water Pump 34 8. Blowdown

  8. High-Pressure Phases in Shock-Induced Melt Veins from the Umbarger L6 Chondrite: Constraints on Shock Conditions

    Science.gov (United States)

    Xie, Z.; Tomioka, N.; Sharp, T. G.

    2000-01-01

    Shock-induced melt veins in the Umbarger L6 (S6) chondrite contain a previously unknown set of high-pressure phases consisting of ringwoodite ((Mg, Fe)2SiO4), akimotoite ((Mg, Fe)SiO3-ilmenite), augite ((Ca, Na)(Mg, Fe, Al)(Si, Al)2O6), and hollandite-structured plagioclase ((Na, K, Ca)(Al, Si)4O8). Crystallization of akimotoite suggests supercooling of the melt vein during adiabatic decompression. High-pressure minerals are common in highly shocked (S6) L6 chondrites. These minerals, which occur within or adjacent to shock-induced melt veins, provide evidence of very high pressure and temperature conditions during impact events. The goal of this study is to characterize the high-pressure mineral assemblages of the melt veins in the L6 chondrite Umbarger to better understand crystallization conditions, and the shock history of meteorite parent body. Mineral assemblages in shock-induced melt veins have been used to estimate crystallization conditions during shock metamorphism. based on phase equilibrium data. Umbarger was previously classified as shock stage S4, based on deformation features not associated with melt veins. Based on previously unrecognized ringwoodite in the melt veins of Umbarger, we classified the shock stage as S6. Further transmission electron microscopy (TEM) study reveals several other high-pressure phases in melt veins that can be used to infer crystallization and shock conditions.

  9. Investigations into High Temperature Components and Packaging

    Energy Technology Data Exchange (ETDEWEB)

    Marlino, L.D.; Seiber, L.E.; Scudiere, M.B.; M.S. Chinthavali, M.S.; McCluskey, F.P.

    2007-12-31

    The purpose of this report is to document the work that was performed at the Oak Ridge National Laboratory (ORNL) in support of the development of high temperature power electronics and components with monies remaining from the Semikron High Temperature Inverter Project managed by the National Energy Technology Laboratory (NETL). High temperature electronic components are needed to allow inverters to operate in more extreme operating conditions as required in advanced traction drive applications. The trend to try to eliminate secondary cooling loops and utilize the internal combustion (IC) cooling system, which operates with approximately 105 C water/ethylene glycol coolant at the output of the radiator, is necessary to further reduce vehicle costs and weight. The activity documented in this report includes development and testing of high temperature components, activities in support of high temperature testing, an assessment of several component packaging methods, and how elevated operating temperatures would impact their reliability. This report is organized with testing of new high temperature capacitors in Section 2 and testing of new 150 C junction temperature trench insulated gate bipolar transistor (IGBTs) in Section 3. Section 4 addresses some operational OPAL-GT information, which was necessary for developing module level tests. Section 5 summarizes calibration of equipment needed for the high temperature testing. Section 6 details some additional work that was funded on silicon carbide (SiC) device testing for high temperature use, and Section 7 is the complete text of a report funded from this effort summarizing packaging methods and their reliability issues for use in high temperature power electronics. Components were tested to evaluate the performance characteristics of the component at different operating temperatures. The temperature of the component is determined by the ambient temperature (i.e., temperature surrounding the device) plus the

  10. Kinetics of passivation of a nickel-base alloy in high temperature water

    Energy Technology Data Exchange (ETDEWEB)

    Machet, A. [Laboratoire de Physico-Chimie des Surfaces, CNRS-ENSCP (UMR 7045), Ecole Nationale Superieure de Chimie de Paris, Universite Pierre et Marie Curie, F-75231 Paris cedex 05 (France)]|[Framatome ANP, Tour AREVA, F-92084 Paris-la-Defense (France); Galtayries, A.; Zanna, S.; Marcus, P. [Laboratoire de Physico-Chimie des Surfaces, CNRS-ENSCP (UMR 7045), Ecole Nationale Superieure de Chimie de Paris, Universite Pierre et Marie Curie, F-75231 Paris cedex 05 (France); Jolivet, P.; Scott, P. [Framatome ANP, Tour AREVA, F-92084 Paris-la-Defense (France); Foucault, M.; Combrade, P. [Framatome ANP, Centre Technique, F-71205 Le Creusot (France)

    2004-07-01

    The kinetics of passivation and the composition of the surface oxide layer, in high temperature and high pressure water, of a nickel-chromium-iron alloy (Alloy 600) have been investigated by X-ray Photoelectron Spectroscopy (XPS). The samples have been exposed for short (0.4 - 8.2 min) and longer (0 - 400 hours) time periods to high temperature (325 deg. C) and high pressure water (containing boron and lithium) under controlled hydrogen pressure. The experiments were performed in two types of autoclaves: a novel autoclave dedicated to short time periods and a classic static autoclave for the longer exposures. In the initial stage of passivation, a continuous ultra-thin layer of chromium oxide (Cr{sub 2}O{sub 3}) is rapidly formed on the surface with an external layer of chromium hydroxide. For longer times of passivation, the oxide layer is in a duplex form with an internal chromium oxide layer and an external layer of nickel hydroxide. The growth of the internal Cr{sub 2}O{sub 3} oxide layer has been fitted by three classical models (parabolic, logarithmic and inverse logarithmic laws) for the short passivation times, and the growth curves have been extrapolated to longer passivation periods. The comparison with the experimental results reveals that the kinetics of passivation of Alloy 600 in high temperature and high pressure water, for passivation times up to 400 hours, is well fitted by a logarithmic growth law. (authors)

  11. Exhumation of (ultra-high-pressure terranes: concepts and mechanisms

    Directory of Open Access Journals (Sweden)

    C. J. Warren

    2013-02-01

    Full Text Available The formation and exhumation of high and ultra-high-pressure, (UHP, rocks of crustal origin appears to be ubiquitous during Phanerozoic plate subduction and continental collision events. Exhumation of (UHP material has been shown in some orogens to have occurred only once, during a single short-lived event; in other cases exhumation appears to have occurred multiple discrete times or during a single, long-lived, protracted event. It is becoming increasingly clear that no single exhumation mechanism dominates in any particular tectonic environment, and the mechanism may change in time and space within the same subduction zone. Subduction zone style and internal force balance change in both time and space, responding to changes in width, steepness, composition of subducting material and velocity of subduction. In order for continental crust, which is relatively buoyant compared to the mantle even when metamorphosed to (UHP assemblages, to be subducted to (UHP conditions, it must remain attached to a stronger and denser substrate. Buoyancy and external tectonic forces drive exhumation, although the changing spatial and temporal dominance of different driving forces still remains unclear. Exhumation may involve whole-scale detachment of the terrane from the subducting slab followed by exhumation within a subduction channel (perhaps during continued subduction or a reversal in motion of the entire plate (eduction following the removal of a lower part of the subducting slab. Weakening mechanisms that may be responsible for the detachment of deeply subducted crust from its stronger, denser substrate include strain weakening, hydration, melting, grain size reduction and the development of foliation. These may act locally to form narrow high-strain shear zones separating stronger, less-strained crust or may act on the bulk of the subducted material, allowing whole-scale flow. Metamorphic reactions, metastability and the composition of the subducted crust

  12. Short review of high-pressure crystal growth and magnetic and electrical properties of solid-state osmium oxides

    Energy Technology Data Exchange (ETDEWEB)

    Yamaura, Kazunari, E-mail: YAMAURA.Kazunari@nims.go.jp [Superconducting Properties Unit, National Institute for Materials Science, 1-1 Namiki, Tsukuba, Ibaraki 305-0044 (Japan); Graduate School of Chemical Sciences and Engineering, Hokkaido University, North 10 West 8, Kita-ku, Sapporo, Hokkaido 060-0810 (Japan)

    2016-04-15

    High-pressure crystal growth and synthesis of selected solid-state osmium oxides, many of which are perovskite-related types, are briefly reviewed, and their magnetic and electrical properties are introduced. Crystals of the osmium oxides, including NaOsO{sub 3}, LiOsO{sub 3}, and Na{sub 2}OsO{sub 4}, were successfully grown under high-pressure and high-temperature conditions at 6 GPa in the presence of an appropriate amount of flux in a belt-type apparatus. The unexpected discovery of a magnetic metal–insulator transition in NaOsO{sub 3}, a ferroelectric-like transition in LiOsO{sub 3}, and high-temperature ferrimagnetism driven by a local structural distortion in Ca{sub 2}FeOsO{sub 6} may represent unique features of the osmium oxides. The high-pressure and high-temperature synthesis and crystal growth has played a central role in the development of solid-state osmium oxides and the elucidation of their magnetic and electronic properties toward possible use in multifunctional devices. - Graphical Abstract: Flux-grown crystals of NaOsO{sub 3} under high-pressure and high-temperature conditions in a belt-type apparatus. The crystal shows a magnetically driven metal–insulator transition at a temperature of 410 K. - Highlights: • Short review of high-pressure crystal growth of solid-state osmium oxides. • Wide variety of magnetic properties of solid-state osmium oxides. • Perovskite and related dense structures stabilized at 3–17 GPa.

  13. High-pressure synthesis of tantalum dihydride

    Science.gov (United States)

    Kuzovnikov, Mikhail A.; Tkacz, Marek; Meng, Haijing; Kapustin, Dmitry I.; Kulakov, Valery I.

    2017-10-01

    The reaction of tantalum with molecular hydrogen was studied by x-ray diffraction in a diamond-anvil cell at room temperature and pressures from 1 to 41 GPa. At pressures up to 5.5 GPa, a substoichiometric tantalum monohydride with a distorted bcc structure was shown to be stable. Its hydrogen content gradually increased with the pressure increase, reaching H /Ta =0.92 (5 ) at 5 GPa. At higher pressures, a new dihydride phase of tantalum was formed. This phase had an hcp metal lattice, and its hydrogen content was virtually independent of pressure. When the pressure was decreased, the tantalum dihydride thus obtained transformed back to the monohydride at P =2.2 GPa . Single-phase samples of tantalum dihydride also were synthesized at a hydrogen pressure of 9 GPa in a toroid-type high-pressure apparatus, quenched to the liquid-N2 temperature, and studied at ambient pressure. X-ray diffraction showed them to have an hcp metal lattice with a =3.224 (3 ) and c =5.140 (5 )Å at T =85 K . The hydrogen content determined by thermal desorption was H /Ta =2.2 (1 ) .

  14. Engineering Model of High Pressure Moist Air

    Directory of Open Access Journals (Sweden)

    Hyhlík Tomáš

    2017-01-01

    Full Text Available The article deals with the moist air equation of state. There are equations of state discussed in the article, i.e. the model of an ideal mixture of ideal gases, the model of an ideal mixture of real gases and the model based on the virial equation of state. The evaluation of sound speed based on the ideal mixture concept is mentioned. The sound speed calculated by the model of an ideal mixture of ideal gases is compared with the sound speed calculated by using the model based on the concept of an ideal mixture of real gases. The comparison of enthalpy end entropy based on the model of an ideal mixture of ideal gases and the model of an ideal mixture of real gases is performed. It is shown that the model of an ideal mixture of real gases deviates from the model of an ideal mixture of ideal gases only in the case of high pressure. An impossibility of the definition of partial pressure in the mixture of real gases is discussed, where the virial equation of state is used.

  15. High-pressure structures of yttrium hydrides

    Science.gov (United States)

    Liu, Lu-Lu; Sun, Hui-Juan; Wang, C. Z.; Lu, Wen-Cai

    2017-08-01

    In this work, the crystal structures of YH3 and YH4 at high pressure (100-250 GPa) have been explored using a genetic algorithm combined with first-principles calculations. New structures of YH3 with space group symmetries of P21/m and I4/mmm were predicted. The electronic structures and the phonon dispersion properties of various YH3 and YH4 structures at different temperatures and pressures were investigated. Among YH3 phases, the P21/m structure of YH3 was found to have a relatively high superconducting transformation temperature T c of 19 K at 120 GPa, which is reduced to 9 K at 200 GPa. Other YH3 structures have much lower T cs. Compared with YH3, the T c of the YH4 compound is much higher, i.e. 94 K at 120 GPa and 55 K at 200 GPa.

  16. Partitioning of siderophile elements between metallic liquids and silicate liquids under high-pressure and temperature

    Science.gov (United States)

    Nakatsuka, A.; Urakawa, S.

    2010-12-01

    High-pressure metal-silicate element partitioning studies have shown the possibility that the mantle abundance of siderophile elements is consistent with core-mantle equilibration at high pressures and high temperatures. Equilibrium conditions are, however, still under debates partly due to the uncertainty of partition coefficients, which vary not only with pressure, temperature and oxygen fugacity but also with composition. We have carried out partitioning experiments of siderophile elements between liquid metal and ultramafic silicate liquid at high pressure to evaluate the effects of composition on the partition coefficients. Partitioning experiments were conducted by KAWAI-type high pressure apparatus. We used natural peridotite and Fe alloy as starting materials and they were contained in graphite capsule. The quenched samples were examined by electron microprobe. Quenched textures indicate that metallic melts coexisted with silicate melts during experiment. The metallic melt contained 7-9 wt% of C. Oxygen fugacity varied from IW-3 to IW-1 in associated with the composition of the starting material. At the reduced condition, silicate melt was enriched in SiO2 compared to peridotite because of the oxidation of Si in metallic melts. When oxygen fugacity is close to IW buffur, silicate melt was enriched in FeO due to the oxidation of metallic Fe and it had high NBO/T = 3.5-4. The partition coefficients D for Co, Ni and Fe were dependent on oxygen fugacity as well as the chemical compositions.

  17. Recent progress in high-pressure studies on organic conductors

    Directory of Open Access Journals (Sweden)

    Syuma Yasuzuka and Keizo Murata

    2009-01-01

    Full Text Available Recent high-pressure studies of organic conductors and superconductors are reviewed. The discovery of the highest Tc superconductivity among organics under high pressure has triggered the further progress of the high-pressure research. Owing to this finding, various organic conductors with the strong electron correlation were investigated under high pressures. This review includes the pressure techniques using the cubic anvil apparatus, as well as high-pressure studies of the organic conductors up to 10 GPa showing extraordinary temperature and pressure dependent transport phenomena.

  18. Trace elements in migrating high-temperature fluids: Effects of diffusive exchange with the adjoining solid

    Science.gov (United States)

    Kenyon, Patricia M.

    1993-01-01

    Trace element concentrations and isotopic ratios are frequently used to study the behavior of high-temperature fluids in both metamorphic and igneous systems. Many theoretical formulations of the effects of fluid migration on trace elements have assumed instantaneous reequilibration between the migrating fluid and the solid material through which it is passing. This paper investigates the additional effects which arise when equilibration is not instantaneous due to a limited rate of diffusion in the solid, using an analytical steady state solution to a set of partial differential equations describing the exchange of trace elements between the fluid and the solid during the migration of the fluid.

  19. Sandia_HighTemperatureComponentEvaluation_2015

    Energy Technology Data Exchange (ETDEWEB)

    Cashion, Avery T. [Sandia National Lab. (SNL-NM), Albuquerque, NM (United States)

    2015-03-01

    The objective of this project is to perform independent evaluation of high temperature components to determine their suitability for use in high temperature geothermal tools. Development of high temperature components has been increasing rapidly due to demand from the high temperature oil and gas exploration and aerospace industries. Many of these new components are at the late prototype or first production stage of development and could benefit from third party evaluation of functionality and lifetime at elevated temperatures. In addition to independent testing of new components, this project recognizes that there is a paucity of commercial-off-the-shelf COTS components rated for geothermal temperatures. As such, high-temperature circuit designers often must dedicate considerable time and resources to determine if a component exists that they may be able to knead performance out of to meet their requirements. This project aids tool developers by characterization of select COTS component performances beyond published temperature specifications. The process for selecting components includes public announcements of project intent (e.g., FedBizOps), direct discussions with candidate manufacturers,and coordination with other DOE funded programs.

  20. Diffusion Creep of Enstatite at High Pressures Under Hydrous Conditions

    Science.gov (United States)

    Zhang, Guinan; Mei, Shenghua; Song, Maoshuang; Kohlstedt, David L.

    2017-10-01

    Mantle convection and large-scale plate motion depend critically on the nature of the lithosphere-asthenosphere boundary and thus on the viscosity structure of Earth's upper mantle, which is determined by the rheological properties of its constituent minerals. To constrain the flow behavior of orthopyroxene, the second most abundant constituent of the upper mantle, deformation experiments were carried out in triaxial compressive creep on fine-grained ( 6 μm) samples of enstatite at high pressures (3.8-6.3 GPa) and high temperatures (1323-1573 K) using a deformation-DIA apparatus. Based on results from this study, the deformation behavior of enstatite is quantitatively presented in the form of a flow law that describes the dependence of deformation rate on differential stress, water fugacity, temperature, and pressure. Specifically, the creep rate depends approximately linearly on stress, indicating deformation in the diffusion creep regime. A least squares regression fit to our data yielded a flow law for diffusion creep with an activation energy of 200 kJ/mol and an activation volume of 14 × 10-6 m3/mol. The magnitude of the water-weakening effect is similar to that for olivine with a water fugacity exponent of r ≈ 0.7. This strong dependence of viscosity on water fugacity (concentration) indicates that the viscosity of an orthopyroxene-bearing mantle varies from one geological setting to another, depending on the large-scale water distribution. Based on the rheology contrast between olivine and enstatite, we conclude that olivine is weaker than enstatite throughout most of the upper mantle except in some shallow regions in the diffusion creep regime.

  1. Pressure Dome for High-Pressure Electrolyzer

    Science.gov (United States)

    Norman, Timothy; Schmitt, Edwin

    2012-01-01

    A high-strength, low-weight pressure vessel dome was designed specifically to house a high-pressure [2,000 psi (approx. = 13.8 MPa)] electrolyzer. In operation, the dome is filled with an inert gas pressurized to roughly 100 psi (approx. = 690 kPa) above the high, balanced pressure product oxygen and hydrogen gas streams. The inert gas acts to reduce the clamping load on electrolyzer stack tie bolts since the dome pressure acting axially inward helps offset the outward axial forces from the stack gas pressure. Likewise, radial and circumferential stresses on electrolyzer frames are minimized. Because the dome is operated at a higher pressure than the electrolyzer product gas, any external electrolyzer leak prevents oxygen or hydrogen from leaking into the dome. Instead the affected stack gas stream pressure rises detectably, thereby enabling a system shutdown. All electrical and fluid connections to the stack are made inside the pressure dome and require special plumbing and electrical dome interfaces for this to be accomplished. Further benefits of the dome are that it can act as a containment shield in the unlikely event of a catastrophic failure. Studies indicate that, for a given active area (and hence, cell ID), frame outside diameter must become ever larger to support stresses at higher operating pressures. This can lead to a large footprint and increased costs associated with thicker and/or larger diameter end-plates, tie-rods, and the frames themselves. One solution is to employ rings that fit snugly around the frame. This complicates stack assembly and is sometimes difficult to achieve in practice, as its success is strongly dependent on frame and ring tolerances, gas pressure, and operating temperature. A pressure dome permits an otherwise low-pressure stack to operate at higher pressures without growing the electrolyzer hardware. The pressure dome consists of two machined segments. An O-ring is placed in an O-ring groove in the flange of the bottom

  2. High Pressure Microwave Powered UV Light Sources

    Science.gov (United States)

    Cekic, M.; Frank, J. D.; Popovic, S.; Wood, C. H.

    1997-10-01

    Industrial microwave powered (*electrodeless*) light sources have been limited to quiescent pressures of 300 Torr of buffer gas and metal- halide fills. Recently developed multi-atmospheric electronegative bu lb fills (noble gas-halide excimers, metal halide) require electric field s for ionization that are often large multiples of the breakdown voltage for air. For these fills an auxiliary ignition system is necessary. The most successful scheme utilizes a high voltage pulse power supply and a novel field emission source. Acting together they create localized condition of pressure reduction and high free electron density. This allows the normal microwave fields to drive this small region into avalanche, ignite the bulb, and heat the plasma to it's operating poin t Standard diagnostic techniques of high density discharges are inapplicable to the excimer bulbs, because of the ionic molecular exci ted state structure and absence of self-absorption. The method for temperature determination is based on the equilibrium population of certain vibrational levels of excimer ionic excited states. Electron d ensity was determined from the measurements of Stark profiles of H_β radiation from a small amount of hydrogen mixed with noble gas and halogens. At the present time, high pressure (Te 0.5eV, ne 3 x 10^17 cm-3) production bulbs produce over 900W of radiation in a 30nm band, centered at 30nm. Similarly, these prototypes when loaded with metal-halide bulb fills produce 1 kW of radiation in 30nm wide bands, centered about the wavelength of interest.

  3. Cobalt ferrite nanoparticles under high pressure

    Energy Technology Data Exchange (ETDEWEB)

    Saccone, F. D.; Ferrari, S.; Grinblat, F.; Bilovol, V. [Instituto de Tecnologías y Ciencias de la Ingeniería, “Ing. H. Fernández Long,” Av. Paseo Colón 850 (1063), Buenos Aires (Argentina); Errandonea, D., E-mail: daniel.errandonea@uv.es [Departamento de Fisica Aplicada, Institut Universitari de Ciència dels Materials, Universitat de Valencia, c/ Doctor Moliner 50, E-46100 Burjassot, Valencia (Spain); Agouram, S. [Departamento de Física Aplicada y Electromagnetismo, Universitat de València, 46100 Burjassot, Valencia (Spain)

    2015-08-21

    We report by the first time a high pressure X-ray diffraction and Raman spectroscopy study of cobalt ferrite (CoFe{sub 2}O{sub 4}) nanoparticles carried out at room temperature up to 17 GPa. In contrast with previous studies of nanoparticles, which proposed the transition pressure to be reduced from 20–27 GPa to 7.5–12.5 GPa (depending on particle size), we found that cobalt ferrite nanoparticles remain in the spinel structure up to the highest pressure covered by our experiments. In addition, we report the pressure dependence of the unit-cell parameter and Raman modes of the studied sample. We found that under quasi-hydrostatic conditions, the bulk modulus of the nanoparticles (B{sub 0} = 204 GPa) is considerably larger than the value previously reported for bulk CoFe{sub 2}O{sub 4} (B{sub 0} = 172 GPa). In addition, when the pressure medium becomes non-hydrostatic and deviatoric stresses affect the experiments, there is a noticeable decrease of the compressibility of the studied sample (B{sub 0} = 284 GPa). After decompression, the cobalt ferrite lattice parameter does not revert to its initial value, evidencing a unit cell contraction after pressure was removed. Finally, Raman spectroscopy provides information on the pressure dependence of all Raman-active modes and evidences that cation inversion is enhanced by pressure under non-hydrostatic conditions, being this effect not fully reversible.

  4. High pressure and microwave based synthesis of transition metal pnictides

    Energy Technology Data Exchange (ETDEWEB)

    Pobel, Roman Rupert

    2016-04-11

    The goal of this thesis was to explore the possibilities of synthetic methods that are not very common in current transition metal pnictide research. The substitution of the Ca-site in CaFe{sub 2}As{sub 2} with rare earth elements such as Pr the has been reported to induce superconductivity. However, some inconsistencies in the data suggested a non-intrinsic origin of the observed diamagnetic signal. Furthermore a solubility limit of 13% was found when prepared in an electrical furnace thus leaving a huge part of the physical phase diagram inaccessible. A high pressure/high temperature synthesis was developed to allow access to the whole doping range and an in-depth characterization of this compound was carried out. During the experiments concerning the high pressure synthesis of Ca{sub 1-x}Pr{sub x}Fe{sub 2}As{sub 2} the new ternary iron arsenide CaFe{sub 5}As{sub 3} was identified and classified as a member of the Ca{sub n(n+1)/2}(Fe{sub 1-x}M{sub x}){sub (2+3n)}M'{sub n(n-1)/2}As{sub (n+1)(n+2)/2} (n = 1-3; M =Nb, Pd, Pt; M' = □, Pd, Pt) family. The complete solid solution Ca{sub 1-x}Pr{sub x}Fe{sub 5}As{sub 3} (O ≤ x ≤ 1) was prepared and physically characterized. Furthermore, several useful techniques were developed to aid in future high pressure based investigations of transition metal pnictides. The second part of this thesis concerns a completely different, but equally promising synthetic approach. Microwave based synthesis is a well-established technique in many solution based fields, such as organic, medicinal or nano chemistry. For solid state and materials research several parameters and particularities have to be considered. But when successful, it allows for the reduction of reaction time by several orders of magnitude. It has very rarely been applied in the preparation of pnictides and on1y once in the context of pnictide superconductor research. The possibilities of this method were explored and employed in the preparation of several

  5. Copper Alloy For High-Temperature Uses

    Science.gov (United States)

    Dreshfield, Robert L.; Ellis, David L.; Michal, Gary

    1994-01-01

    Alloy of Cu/8Cr/4Nb (numbers indicate parts by atom percent) improved over older high-temperature copper-based alloys in that it offers enhanced high temperature strength, resistance to creep, and ductility while retaining most of thermal conductivity of pure copper; in addition, alloy does not become embrittled upon exposure to hydrogen at temperatures as high as 705 degrees C. Designed for use in presence of high heat fluxes and active cooling; for example, in heat exchangers in advanced aircraft and spacecraft engines, and other high-temperature applications in which there is need for such material. High conductivity and hardness of alloy exploited in welding electrodes and in high-voltage and high-current switches and other applications in which wear poses design problem.

  6. High temperature thrust chamber for spacecraft

    Science.gov (United States)

    Chazen, Melvin L. (Inventor); Mueller, Thomas J. (Inventor); Kruse, William D. (Inventor)

    1998-01-01

    A high temperature thrust chamber for spacecraft (20) is provided herein. The high temperature thrust chamber comprises a hollow body member (12) having an outer surface and an internal surface (16) defining the high temperature chamber (10). The body member (12) is made substantially of rhenium. An alloy (18) consisting of iridium and at least alloying metal selected of the group consisting of rhodium, platinum and palladium is deposited on at least a portion of the internal surface (16) of the body member (12). The iridium and the alloying metal are electrodeposited onto the body member (12). A HIP cycle is performed upon the body member (12) to cause the coating of iridium and the alloying metal to form the alloy (18) which protects the body member (12) from oxidation.

  7. The flavoured BFSS model at high temperature

    Energy Technology Data Exchange (ETDEWEB)

    Asano, Yuhma; Filev, Veselin G. [School of Theoretical Physics, Dublin Institute for Advanced Studies,10 Burlington Road, Dublin 4 (Ireland); Kováčik, Samuel [School of Theoretical Physics, Dublin Institute for Advanced Studies,10 Burlington Road, Dublin 4 (Ireland); Faculty of Mathematics, Physics and Informatics,Comenius University Bratislava, Mlynská dolina, Bratislava, 842 48 (Slovakia); O’Connor, Denjoe [School of Theoretical Physics, Dublin Institute for Advanced Studies,10 Burlington Road, Dublin 4 (Ireland)

    2017-01-25

    We study the high-temperature series expansion of the Berkooz-Douglas matrix model, which describes the D0/D4-brane system. At high temperature the model is weakly coupled and we develop the series to second order. We check our results against the high-temperature regime of the bosonic model (without fermions) and find excellent agreement. We track the temperature dependence of the bosonic model and find backreaction of the fundamental fields lifts the zero-temperature adjoint mass degeneracy. In the low-temperature phase the system is well described by a gaussian model with three masses m{sub A}{sup t}=1.964±0.003, m{sub A}{sup l}=2.001±0.003 and m{sub f}=1.463±0.001, the adjoint longitudinal and transverse masses and the mass of the fundamental fields respectively.

  8. Application of High Temperature Superconductors to Accelerators

    CERN Document Server

    Ballarino, A

    2000-01-01

    Since the discovery of high temperature superconductivity, a large effort has been made by the scientific community to investigate this field towards a possible application of the new oxide superconductors to different devices like SMES, magnetic bearings, flywheels energy storage, magnetic shielding, transmission cables, fault current limiters, etc. However, all present day large scale applications using superconductivity in accelerator technology are based on conventional materials operating at liquid helium temperatures. Poor mechanical properties, low critical current density and sensitivity to the magnetic field at high temperature are the key parameters whose improvement is essential for a large scale application of high temperature superconductors to such devices. Current leads, used for transferring currents from the power converters, working at room temperature, into the liquid helium environment, where the magnets are operating, represent an immediate application of the emerging technology of high t...

  9. High-temperature heat-pump fluids

    Science.gov (United States)

    Bertinat, M. P.

    1988-05-01

    Heat pumps could be immensely useful in many industrial processes, but standard working fluids are unsuitable for the high temperatures involved. The ideal high-temperature heat-pump fluid should have a high (but not too high) critical temperature, a moderate critical pressure ( approximately=5.0 MPa) and a low (but not too low) boiling point. There are many organic fluids that do meet the above thermodynamic criteria The author's list of 250 contained dozens of them including many of the common laboratory solvents such as ethanol, ether and especially acetone. Unfortunately most of them are highly flammable. The ideal work fluid for high-temperature heat pumps will probably always remain elusive and water, despite its drawbacks will continue to be the best choice in most applications

  10. High Temperature, Wireless Seismometer Sensor for Venus

    Science.gov (United States)

    Ponchak, George E.; Scardelletti, Maximilian C.; Taylor, Brandt; Beard, Steve; Meredith, Roger D.; Beheim, Glenn M.; Hunter Gary W.; Kiefer, Walter S.

    2012-01-01

    Space agency mission plans state the need to measure the seismic activity on Venus. Because of the high temperature on Venus (462? C average surface temperature) and the difficulty in placing and wiring multiple sensors using robots, a high temperature, wireless sensor using a wide bandgap semiconductor is an attractive option. This paper presents the description and proof of concept measurements of a high temperature, wireless seismometer sensor for Venus. A variation in inductance of a coil caused by the movement of an aluminum probe held in the coil and attached to a balanced leaf-spring seismometer causes a variation of 700 Hz in the transmitted signal from the oscillator/sensor system at 426? C. This result indicates that the concept may be used on Venus.

  11. Electrical resistance of SrFeO2 at ultra high pressure

    Science.gov (United States)

    Kikuchi, Masayoshi; Kagayama, Tomoko; Shimizu, Katsuya; Kageyama, Hiroshi

    2015-03-01

    SrFeO2 shows antiferromagnetic and insulating order at ambient pressure. The crystal structure of SrFeO2 has 2-dementional FeO2 plate and is interested in because this is common structure of high temperature superconductor. SrFeO2 has M-I, magnetic and spin transition with applying pressure. If magnetism disappears and metallization occurs with applying pressure, SrFeO2 may show superconductivity because of the crystal structure, so we measured electrical resistance at high pressure up to 150 GPa and low temperature down to 100 mK.

  12. Development of Instrument Transmitter Protecting Device against High-Temperature Condition during Severe Accidents

    Directory of Open Access Journals (Sweden)

    Min Yoo

    2014-01-01

    Full Text Available Reliable information through instrumentation systems is essential in mitigating severe accidents such as the one that occurred at the Fukushima Daiichi nuclear power plant. There are five elements which might pose a potential threat to the reliability of parameter detection at nuclear power plants during a severe accident: high temperature, high pressure, high humidity, high radiation, and missiles generated during the evolution of a severe accident. Of these, high temperature apparently poses the most serious threat, since thin shielding can get rid of pressure, humidity, radiation (specifically, alpha and beta radiations, and missile effects. In view of this fact, our study focused on designing an instrument transmitter protecting device that can eliminate the high-temperature effect on transmitters to maintain their functional integrity. We present herein a novel concept for designing such a device in terms of heat transfer model that takes into account various heat transfer mechanisms associated with the device.

  13. Materials for high-temperature fuel cells

    CERN Document Server

    Jiang, San Ping; Lu, Max

    2013-01-01

    There are a large number of books available on fuel cells; however, the majority are on specific types of fuel cells such as solid oxide fuel cells, proton exchange membrane fuel cells, or on specific technical aspects of fuel cells, e.g., the system or stack engineering. Thus, there is a need for a book focused on materials requirements in fuel cells. Key Materials in High-Temperature Fuel Cells is a concise source of the most important and key materials and catalysts in high-temperature fuel cells with emphasis on the most important solid oxide fuel cells. A related book will cover key mater

  14. Melt processed high-temperature superconductors

    CERN Document Server

    1993-01-01

    The achievement of large critical currents is critical to the applications of high-temperature superconductors. Recent developments have shown that melt processing is suitable for producing high J c oxide superconductors. Using magnetic forces between such high J c oxide superconductors and magnets, a person could be levitated.This book has grown largely out of research works on melt processing of high-temperature superconductors conducted at ISTEC Superconductivity Research Laboratory. The chapters build on melt processing, microstructural characterization, fundamentals of flux pinning, criti

  15. Electrons and Phonons in High Temperature Superconductors

    Directory of Open Access Journals (Sweden)

    Anu Singh

    2013-01-01

    Full Text Available The defect-induced anharmonic phonon-electron problem in high-temperature superconductors has been investigated with the help of double time thermodynamic electron and phonon Green’s function theory using a comprehensive Hamiltonian which includes the contribution due to unperturbed electrons and phonons, anharmonic phonons, impurities, and interactions of electrons and phonons. This formulation enables one to resolve the problem of electronic heat transport and equilibrium phenomenon in high-temperature superconductors in an amicable way. The problem of electronic heat capacity and electron-phonon problem has been taken up with special reference to the anharmonicity, defect concentration electron-phonon coupling, and temperature dependence.

  16. Neutron experiments on high-temperature superconductors

    Science.gov (United States)

    Mook, H. A., Jr.

    1989-12-01

    This report details the trip to the ILL to perform neutron scattering research on high-temperature superconductivity. The trip was very successful because of the excellent users' facilities available at the ILL. The data we accumulated were of high quality and will make an impact on our understanding of high-temperature superconductivity. However, we cannot continue to run a research program in this field with the limited beam time available at the ILL. To make substantial progress in this field, we must restart the High Flux Isotope Reactor.

  17. Accessory Mineral Geochronology and Trace Element Fingerprinting of Metamorphic Processes

    Science.gov (United States)

    Moller, A.

    2009-05-01

    Zircon and monazite are the most versatile tools for geochronological studies in magmatic, metamorphic and sedimentary rocks. New trace element techniques are now used to link growth and modification to pressure and temperature evolution of magmatic and metamorphic rocks and to coexisting minerals. Studies on the distribution of rare earth elements (REE) have mainly focused on garnet and zircon relationships and which distribution patterns constitute equilibrium under different metamorphic conditions. But a more detailed understanding of the growth and modification processes of accessory phases is needed to provide better constraints for genetic models and multiple method datasets (U-Pb, REE, trace element thermometry, imaging) is essential. We use this approach on examples from high-temperature low-pressure granulites of Rogaland (SW Norway) and UHT medium pressure granulites from the Labwor Hills (Uganda) to illustrate the influence of major and accessory mineral reactions on the trace element signature of zircon and monazite. Relatively flat zircon HREE patterns, often associated with coexisting garnet, can also be found in orthopyroxene-bearing, garnet free assemblages. The zircon-opx distribution patterns are similar to zircon-garnet pairs from UHT leucosomes and granulites. Some garnet-bearing granulites are characterized by zircon overgrowths with xenotime inclusions and elevated Y- and HREE-contents, interpreted to reflect garnet breakdown at high T. Zircon and monazite in Labwor Hills metasedimentary granulites both have modified domains. Monazite has low Th rims that yield erroneous high chemical ages, interpreted to be due to loss of Th, while remnants of radiogenic Pb remain during the recrystallization process. Zircon in contrast has high Th rims and domains along sealed cracks that are characterized by anomalously high Th/U ratios (not previously associated with metamorphic growth or modification) and unusual REE patterns. These features are

  18. Lightweight High-Temperature Thermal Insulation

    Science.gov (United States)

    Wagner, W. R.; Fasheh, J. I.

    1985-01-01

    Fine Ni/Cr fibers sintered into corrosion-resistant, fireproof batt. Possible applications include stoves, furnaces, safes, fire clothing, draperies in public buildings, wall firebreaks, airplane walls, and jetengine components. New insulation takes advantage of some of same properties of nickel/chromium alloy useful in heating elements in toasters, namely, corrosion and oxidation resistance even at high temperatures.

  19. High temperatures influence sexual development differentially in ...

    Indian Academy of Sciences (India)

    Although sex determination in amphibians is believed to be a genetic process, environmental factors such as temperatureare known to influence the sex differentiation and development. Extremely low and high temperatures influence gonadaldevelopment and sex ratio in amphibians but the mechanism of action is not ...

  20. High Temperature Corrosion in Biomass Incineration Plants

    DEFF Research Database (Denmark)

    Montgomery, Melanie; Maahn, Ernst emanuel; Gotthjælp, K.

    1997-01-01

    The aim of the project is to study the role of ash deposits in high temperature corrosion of superheater materials in biomass and refuse fire combined heat and power plants. The project has included the two main activities: a) A chemical characterisation of ash deposits collected from a major...

  1. High Temperature Resistant Exhaust Valve Spindle

    DEFF Research Database (Denmark)

    Bihlet, Uffe Ditlev

    of the engine, new high temperature alloys are required for a specific engine component, the exhaust valve spindle. Two alloys are used for an exhaust valve spindle; one for the bottom of the spindle, and one for the spindle seat. Being placed in the exhaust gas stream, combustion products such as V2O5 and Na2...

  2. Helium-cooled high temperature reactors

    Energy Technology Data Exchange (ETDEWEB)

    Trauger, D.B.

    1985-01-01

    Experience with several helium cooled reactors has been favorable, and two commercial plants are now operating. Both of these units are of the High Temperature Graphite Gas Cooled concept, one in the United States and the other in the Federal Republic of Germany. The initial helium charge for a reactor of the 1000 MW(e) size is modest, approx.15,000 kg.

  3. Thermoelastic properties of minerals at high temperature

    Indian Academy of Sciences (India)

    under high temperatures and calculated the second-order elastic constant (Cij ) and bulk modulus. (KT) of the above minerals, in two cases first by taking Anderson–Gruneisen parameter (δT) as temperature-independent and then by treating δT as temperature-dependent parameter. The results obtained when δT is ...

  4. High temperature spectral gamma well logging

    Energy Technology Data Exchange (ETDEWEB)

    Normann, R.A.; Henfling, J.A.

    1997-01-01

    A high temperature spectral gamma tool has been designed and built for use in small-diameter geothermal exploration wells. Several engineering judgments are discussed regarding operating parameters, well model selection, and signal processing. An actual well log at elevated temperatures is given with spectral gamma reading showing repeatability.

  5. Complex performance during exposure to high temperatures.

    Science.gov (United States)

    1969-06-01

    The effects of high temperature on psychomotor performance and physiological function were studied on male pilots (age 30-51) holding a current medical certificate. A total of 41 runs were made at neutral (23.8C (75F), or hot (60.0C (140F), 71.1C (16...

  6. Thermoelastic properties of minerals at high temperature

    Indian Academy of Sciences (India)

    The knowledge of elasticity of the minerals is useful for interpreting the structure and composition of the lower mantle and also in seismic studies. The purpose of the present study is to discuss a simple and straightforward method for evaluating thermoelastic properties of minerals at high temperatures. We have extended ...

  7. Structural and Metamorphic Evolution of the Archaean High-pressure Granulite in Datong-Huaian Area, North China

    NARCIS (Netherlands)

    Zhang, J.

    2001-01-01

    The Archaean granulite terrain in the Datong-Huaian area, north China, comprises a basement complex of fe lsic and mafic granulite (TTG gneiss), overlain by a sedimentary sequence dominated by metapelite and metapsammite (khondalite series). Both lithological associations are separated by

  8. Controllable synthesis of fullerene nano/microcrystals and their structural transformation induced by high pressure

    Science.gov (United States)

    Yao, Ming-Guang; Du, Ming-Run; Liu, Bing-Bing

    2013-09-01

    Fullerene molecules are interesting materials because of their unique structures and properties in mechanical, electrical, magnetic, and optical aspects. Current research is focusing on the construction of well-defined fullerene nano/microcrystals that possess desirable structures and morphologies. Further tuning the intermolecular interaction of the fullerene nano/microcrystals by use of pressure is an efficient way to modify their structures and properties, such as creation of nanoscale polymer structures and new hybrid materials, which expands the potential of such nanoscale materials for direct device components. In this paper, we review our recent progress in the construction of fullerene nanostructures and their structural transformation induced by high pressure. Fullerene nano/microcrystals with controllable size, morphology and structure have been synthesized through the self-assembly of fullerene molecules by a solvent-assisted method. By virtue of high pressure, the structures, components, and intermolecular interactions of the assemblied fullerene nano/microcrystals can be finely tuned, thereby modifying the optical and electronic properties of the nanostructures. Several examples on high pressure induced novel structural phase transition in typical fullerene nanocrystals with C60 or C70 cage serving as building blocks are presented, including high pressure induced amorphization of the nanocrystals and their bulk moduli, high pressure and high temperature (HPHT) induced polymerization in C60 nanocrystals, pressure tuned reversible polymerization in ferrocene-doped C60/C70 single crystal, as well as unique long-range ordered crystal with amorphous nanoclusters serving as building blocks in solvated C60 crystals, which brings new physical insight into the understanding of order and disorder concept and new approaches to the design of superhard carbon materials. The nanosize and morphology effects on the transformations of fullerene nanocrystals have also

  9. Nanocomposite Thermolectric Materials by High Pressure Powder Consolidation Manufacturing Project

    Data.gov (United States)

    National Aeronautics and Space Administration — In response to NASA's need to develop advanced nanostructured thermolectric materials, UTRON is proposing an innovative high pressure powder consolidation...

  10. Shock metamorphism of carbonaceous chondrites

    Science.gov (United States)

    Scott, Edward R. D.; Keil, Klaus; Stoeffler, Dieter

    1992-01-01

    Shock effects were studied in 69 carbonaceous chondrites, including CM2, CO3, CV3, ungrouped C2-C4, and CK4-6 chondrites, using optical microscopy of thin sections. It is shown that the classification scheme of Stoeffler et al. (1991) for the progressive stages of shock metamorphism in ordinary chondrites is also applicable to carbonaceous chondrites. On the basis of shock effects in olivine, the 69 carbonaceous chondrites could be assigned to four shock stage, S1 to S4. The CM2 and CO3 groups were found to be the least shocked chondrite groups, whereas the CK4-6 and CV3 were the most strongly shocked groups.

  11. A high-pressure vessel for X-ray diffraction experiments for liquids in a wide temperature range

    CERN Document Server

    Hosokawa, S

    2001-01-01

    An internally heated high-pressure vessel was developed for angle-dispersive X-ray scattering experiments on liquids at high-temperatures and high-pressures. It consists of a closed-end Al cylinder and a steel flange. Continuous windows made of Be cover a scattering angle range up to 55 deg. In combination with a single-crystal sapphire cell and a small heating system inside the vessel, we were able to carry out diffraction measurements for liquids in a wide temperature range up to 2000 K at high pressures up to 150 bars. Some of our recent X-ray scattering experiments using synchrotron radiation, such as inelastic scattering, high-energy elastic scattering, and anomalous scattering, are also reported.

  12. The timing of eclogite facies metamorphism and migmatization in the Orlica–Śnieżnik complex, Bohemian Massif: Constraints from a multimethod geochronological study

    Science.gov (United States)

    Brocker, M.; Klemd, R.; Cosca, M.; Brock, W.; Larionov, A.N.; Rodionov, N.

    2009-01-01

    The Orlica–Śnieżnik complex (OSC) is a key geological element of the eastern Variscides and mainly consists of amphibolite facies orthogneisses and metasedimentary rocks. Sporadic occurrences of eclogites and granulites record high-pressure (HP) to ultrahigh-pressure (UHP) metamorphic conditions. A multimethod geochronological approach (40Ar–39Ar, Rb–Sr, Sm–Nd, U–Pb) has been used to gain further insights into the polymetamorphic evolution of eclogites and associated country rocks. Special attention was given to the unresolved significance of a 370- to 360 Ma age group that was repeatedly described in previous studies. Efforts to verify the accuracy of c.370 Ma K–Ar phengite and biotite dates reported for an eclogite and associated country-rock gneiss from the location Nowa Wieś suggest that these dates are meaningless, due to contamination with extraneous Ar. Extraneous Ar is also considered to be responsible for a significantly older 40Ar–39Ar phengite date of c. 455 Ma for an eclogite from the location Wojtowka. Attempts to further substantiate the importance of 370–360 Ma zircon dates as an indicator for a melt-forming high-temperature (HT) episode did not provide evidence in support of anatectic processes at this time. Instead, SHRIMP U–Pb zircon dating of leucosomes and leucocratic veins within both orthogneisses and (U)HP granulites revealed two age populations (490–450 and 345–330 Ma respectively) that correspond to protolith ages of the magmatic precursors and late Variscan anatexis. The results of this study further underline the importance of Late Carboniferous metamorphic processes for the evolution of the OSC that comprise the waning stages of HP metamorphism and lower pressure HT overprinting with partial melting. Eclogites and their country rocks provided no chronometric evidence for an UHP and ultrahigh-temperature episode at 387–360 Ma, as recently suggested for granulites from the OSC, based on Lu–Hf garnet

  13. Divergent synthesis routes and superconductivity of ternary hydride MgSiH6 at high pressure

    Science.gov (United States)

    Ma, Yanbin; Duan, Defang; Shao, Ziji; Yu, Hongyu; Liu, Hanyu; Tian, Fubo; Huang, Xiaoli; Li, Da; Liu, Bingbing; Cui, Tian

    2017-10-01

    We predict a new ternary hydride MgSiH6 under high pressures, which is a metal with an ionic feature and takes on a simple cubic structure with space group P m -3 above 250 GPa. Our first-principles calculations show that the cubic MgSiH6 is a potential high-temperature superconductor with a superconducting transition temperature Tc of ˜63 K at 250 GPa. Further analysis suggests that phonon softening along mainly Γ -X and Γ -M directions induced by Fermi surface nesting plays a crucial role in the high-temperature superconductivity. Herein we propose the "triangle straight-line method" which provides a clear guide to determine the specific A + B → D type formation routes for ternary hydrides of the Mg-Si-H system and it effectively reveals two divergent paths to obtain MgSiH6 under high pressures: MgH2+SiH4→MgSiH6 and MgSi + 3 H2→MgSiH6 . This method might be applicable to all ternary compounds, which will be very significant for further experimental synthesis.

  14. High Temperature Mechanisms for Venus Exploration

    Science.gov (United States)

    Ji, Jerri; Narine, Roop; Kumar, Nishant; Singh, Sase; Gorevan, Steven

    Future Venus missions, including New Frontiers Venus In-Situ Explorer and three Flagship Missions - Venus Geophysical Network, Venus Mobile Explorer and Venus Surface Sample Return all focus on searching for evidence of past climate change both on the surface and in the atmospheric composition as well as in the interior dynamics of the planet. In order to achieve these goals and objectives, many key technologies need to be developed for the Venus extreme environment. These key technologies include sample acquisition systems and other high-temperature mechanisms and mobility systems capable of extended operation when directly exposed to the Venus surface or lower atmosphere environment. Honeybee Robotics has developed two types of high temperature motors, the materials and components in both motors were selected based on the requirement to survive temperatures above a minimum of 460° C, at earth atmosphere. The prototype Switched Reluctance Motor (SRM) has been operated non-continuously for over 20 hours at Venus-like conditions (460° C temperature, mostly CO2 gas environment) and it remains functional. A drilling system, actuated by two SRMs was tested in Venus-like conditions, 460° C temperature and mostly CO2 gas environment, for more than 15 hours. The drill successfully completed three tests by drilling into chalk up to 6 inches deep in each test. A first generation Brushless DC (BLDC) Motor and high temperature resolver were also tested and the feasibility of the designs was demonstrated by the extended operation of both devices under Venus-like condition. Further development of the BLDC motor and resolver continues and these devices will, ultimately, be integrated into the development of a high temperature sample acquisition scoop and high temperature joint (awarded SBIR Phase II in October, 2007). Both the SR and BLDC motors will undergo extensive testing at Venus temperature and pressure (TRL6) and are expected to be mission ready before the next New

  15. Stability projections for high temperature superconductors

    Energy Technology Data Exchange (ETDEWEB)

    Laquer, H.L.; Edeskuty, F.J.; Hassenzahl, W.V.; Wipf, S.L.

    1989-03-01

    The stability of the new high temperature superconducting oxides has been analyzed, using the methodology developed over the last 25 years for conventional Type II superconductors. The results are presented in graphical form for the temperature range from 4 to 100 K. For a 90 K superconductor the first flux jump field peaks above 7 T at 60 K, ( and for a 120 k superconductor it peaks above 12 T at 75 K). The maximum adiabatically stable thickness increases dramatically. The linear dimension of the minimum propagating zone increases by a factor of 3 to 5, and the quench propagation velocity drops by 4 orders of magnitude. The high temperature superconducting materials will, therefore, have much higher stability than conventional Type II superconductors; their high flux jump fields will make ultra-fine multifilamentary conductors unnecessary and improve the outlook for tape conductors; the energy to create a propagating zone is increased; however, methods of coil protection will have to be modified.

  16. Metallic Membranes for High Temperature Hydrogen Separation

    DEFF Research Database (Denmark)

    Ma, Y.H.; Catalano, Jacopo; Guazzone, Federico

    2013-01-01

    Composite palladium membranes have extensively been studied in laboratories and, more recently, in small pilot industrial applications for the high temperature separation of hydrogen from reactant mixtures such as water-gas shift (WGS) reaction or methane steam reforming (MSR). Composite Pd...... membrane fabrication methods have matured over the last decades, and the deposition of very thin films (1–5 µm) of Pd over porous ceramics or modified porous metal supports is quite common. The H2 permeances and the selectivities achieved at 400–500 °C were in the order of 50–100 Nm3/m/h/bar0.5 and greater...... than 1000, respectively. This chapter describes in detail composite Pd-based membrane preparation methods, which consist of the grading of the support and the deposition of the dense metal layer, their performances, and their applications in catalytic membrane reactors (CMRs) at high temperatures (400...

  17. High temperature aircraft research furnace facilities

    Science.gov (United States)

    Smith, James E., Jr.; Cashon, John L.

    1992-01-01

    Focus is on the design, fabrication, and development of the High Temperature Aircraft Research Furnace Facilities (HTARFF). The HTARFF was developed to process electrically conductive materials with high melting points in a low gravity environment. The basic principle of operation is to accurately translate a high temperature arc-plasma gas front as it orbits around a cylindrical sample, thereby making it possible to precisely traverse the entire surface of a sample. The furnace utilizes the gas-tungsten-arc-welding (GTAW) process, also commonly referred to as Tungsten-Inert-Gas (TIG). The HTARFF was developed to further research efforts in the areas of directional solidification, float-zone processing, welding in a low-gravity environment, and segregation effects in metals. The furnace is intended for use aboard the NASA-JSC Reduced Gravity Program KC-135A Aircraft.

  18. High Temperature Phenomena in Shock Waves

    CERN Document Server

    2012-01-01

    The high temperatures generated in gases by shock waves give rise to physical and chemical phenomena such as molecular vibrational excitation, dissociation, ionization, chemical reactions and inherently related radiation. In continuum regime, these processes start from the wave front, so that generally the gaseous media behind shock waves may be in a thermodynamic and chemical non-equilibrium state. This book presents the state of knowledge of these phenomena. Thus, the thermodynamic properties of high temperature gases, including the plasma state are described, as well as the kinetics of the various chemical phenomena cited above. Numerous results of measurement and computation of vibrational relaxation times, dissociation and reaction rate constants are given, and various ionization and radiative mechanisms and processes are presented. The coupling between these different phenomena is taken into account as well as their interaction with the flow-field. Particular points such as the case of rarefied flows an...

  19. Silicon Carbide Nanotube Oxidation at High Temperatures

    Science.gov (United States)

    Ahlborg, Nadia; Zhu, Dongming

    2012-01-01

    Silicon Carbide Nanotubes (SiCNTs) have high mechanical strength and also have many potential functional applications. In this study, SiCNTs were investigated for use in strengthening high temperature silicate and oxide materials for high performance ceramic nanocomposites and environmental barrier coating bond coats. The high · temperature oxidation behavior of the nanotubes was of particular interest. The SiCNTs were synthesized by a direct reactive conversion process of multiwall carbon nanotubes and silicon at high temperature. Thermogravimetric analysis (TGA) was used to study the oxidation kinetics of SiCNTs at temperatures ranging from 800degC to1300degC. The specific oxidation mechanisms were also investigated.

  20. Application of displacement monitoring system on high temperature steam pipe

    Science.gov (United States)

    Ghaffar, M. H. A.; Husin, S.; Baek, J. E.

    2017-10-01

    High-energy piping systems of power plants such as Main Steam (MS) pipe or Hot Reheat (HR) pipe are operating at high temperature and high pressure at base and cyclic loads. In the event of transient condition, a pipe can be deflected dramatically and caused high stress in the pipe, yielding to failure of the piping system. Periodic monitoring and walk down can identify abnormalities but limitations exist in the standard walk down practice. This paper provides a study of pipe displacement monitoring on MS pipe of coal-fired power plant to continuously capture the pipe movement behaviour at different load using 3-Dimensional Displacement Measuring System (3DDMS). The displacement trending at Location 5 and 6 (north and south) demonstrated pipes displace less than 25% to that of design movement. It was determined from synchronisation analysis that Location 7 (north) and Location 8 (south) pipe actual movement difference has exceeded the design movement difference. Visual survey at specified locations with significant displacement trending reveals issues of hydraulic snubber and piping interferences. The study demonstrated that the displacement monitoring is able to capture pipe movement at all time and allows engineer to monitor pipe movement behaviour, aids in identifying issue early for remedy action.

  1. Assessment performance of high-temperature filtering elements

    Energy Technology Data Exchange (ETDEWEB)

    Monica Lupion; Francisco J. Gutierrez Ortiz; Benito Navarrete; Vicente J. Cortes [University of Seville, Seville (Spain). E.T.S. Ingenieros

    2010-04-15

    An extensive experimental campaign has been carried out in a hot gas filtration test facility so as to test several filtering elements and configurations, particularly, three different types of bag filters and one ceramic candle. The facility was designed to operate under a wide range of conditions, thus providing an excellent tool for the investigation of hot gas filtration applications for the advanced electrical power generation industry such as IGCC, PFBC or fuel cell technologies. Relevant parameters for the characterisation and optimization of the performance of the filters have been studied for a variety of operating conditions such as filtration velocity, particle concentration, pressure and temperature among others. Pressure drop across the filter, cleaning pulse interval, baseline pressure drop, filtration efficiency and durability of the filter have been investigated for each type considered and dependences on parameters have been established. On top of that, optimal operating conditions and cleaning strategies were determined. The tests results show that bag filters are a suitable alternative for the hot gas filtration due to the better performance and the high efficiency observed, which makes them suitable for industrial applications operating under high temperature high pressure conditions considered within the study (200-370{sup o}C and 4-7.5 barg, respectively). 8 refs., 7 figs., 10 tabs.

  2. Conceptual design of a helium heater for high temperature applications

    Energy Technology Data Exchange (ETDEWEB)

    Jin, Xue Zhou, E-mail: jin@kit.edu; Chen, Yuming; Ghidersa, Bradut-Eugen

    2014-10-15

    Highlights: •A special design of heater with two vessels is introduced for the operation at 10 MPa and 800 °C. •The additional coupling between the cold leg and the hot leg of the loop due to the heater design has an impact on the loop energy budget. •Reducing the heat transfer between the two flow channels inside the heater by means of a helium gap in the inlet nozzle is proven to be effective. -- Abstract: The Karlsruhe Advanced Technologies Helium Loop (KATHELO) has been designed for testing divertor modules as well as qualifying materials for high heat flux, high temperature (up to 800 °C) and high pressure (10 MPa) applications. The test section inlet temperature level is controlled using a process electrical heater. To cope with the extreme operating conditions, a special design of this unit has been proposed. In this paper the conceptual design of the unit will be presented and the impact of the coupling between the cold and hot helium gas on the overall efficiency of the loop will be investigated. The detailed thermal-hydraulic analysis of the feed through of the hot helium into the low temperature pressure vessel using ANSYS CFX will be presented. The impact of the design choices on the overall energy budget of the loop will be analyzed using RELAP5-3D.

  3. High temperature impedance spectroscopy of barium stannate ...

    Indian Academy of Sciences (India)

    Abstract. Polycrystalline powder of BaSnO3 was prepared at 1300 ◦C using a high-temperature solid-state reac- tion technique. X-ray diffraction analysis indicated the formation of a single-phase cubic structure with lattice parameter: a = (4·1158 ± 0·0003) Å. The synthesized powder was characterized using X-ray diffraction ...

  4. High temperature materials; Materiaux a hautes temperatures

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    2003-07-01

    The aim of this workshop is to share the needs of high temperature and nuclear fuel materials for future nuclear systems, to take stock of the status of researches in this domain and to propose some cooperation works between the different research organisations. The future nuclear systems are the very high temperature (850 to 1200 deg. C) gas cooled reactors (GCR) and the molten salt reactors (MSR). These systems include not only the reactor but also the fabrication and reprocessing of the spent fuel. This document brings together the transparencies of 13 communications among the 25 given at the workshop: 1) characteristics and needs of future systems: specifications, materials and fuel needs for fast spectrum GCR and very high temperature GCR; 2) high temperature materials out of neutron flux: thermal barriers: materials, resistance, lifetimes; nickel-base metal alloys: status of knowledge, mechanical behaviour, possible applications; corrosion linked with the gas coolant: knowledge and problems to be solved; super-alloys for turbines: alloys for blades and discs; corrosion linked with MSR: knowledge and problems to be solved; 3) materials for reactor core structure: nuclear graphite and carbon; fuel assembly structure materials of the GCR with fast neutron spectrum: status of knowledge and ceramics and cermets needs; silicon carbide as fuel confinement material, study of irradiation induced defects; migration of fission products, I and Cs in SiC; 4) materials for hydrogen production: status of the knowledge and needs for the thermochemical cycle; 5) technologies: GCR components and the associated material needs: compact exchangers, pumps, turbines; MSR components: valves, exchangers, pumps. (J.S.)

  5. High temperature mechanical properties of iron aluminides

    Directory of Open Access Journals (Sweden)

    Morris, D. G.

    2001-04-01

    Full Text Available Considerable attention has been given to the iron aluminide family of intermetallics over the past years since they offer considerable potential as engineering materials for intermediate to high temperature applications, particularly in cases where extreme oxidation or corrosion resistance is required. Despite efforts at alloy development, however, high temperature strength remains low and creep resistance poor. Reasons for the poor high-temperature strength of iron aluminides will be discussed, based on the ordered crystal structure, the dislocation structure found in the material, and the mechanisms of dislocation pinning operating. Alternative ways of improving high temperature strength by microstructural modification and the inclusion of second phase particles will also be considered.

    Durante los últimos años se ha prestado mucha atención a la familia de intermetálicos Fe-Al, puesto que estos constituyen un considerable potencial como materiales de ingeniería en aplicaciones a temperaturas intermedias o altas, sobre todo en casos donde se necesita alta resistencia a la oxidación o corrosión. A pesar del considerable esfuerzo desarrollado para obtener aleaciones con mejores propiedades, su resistencia mecánica a alta temperatura no es muy elevada. Se discutirán los aspectos que contribuyen a la baja resistencia mecánica a temperatura elevada en función de la estructura de dislocaciones y los mecanismos de anclaje que operan en este intermetálico. Se considerarán, también, maneras alternativas para mejorar la resistencia a temperatura elevada mediante la modificación de la microestructura y la incorporación de partículas de segunda fase.

  6. Fundamental aspects of high-temperature corrosion

    OpenAIRE

    Rapp, Robert

    1993-01-01

    Some recent considerations in three widely different aspects of high-temperature corrosion are summarized: 1) reactions at the metal/scale interface in support of scale growth; 2) mass transfer effects in the control of evaporation of volatile reaction products; and 3) the codeposition of multiple elements for diffusion coatings using halide-activated cementation packs. The climb of misfit edge dislocations from the metal/scale interface can achieve the annihilation of vacancies associated wi...

  7. Thermal fuse for high-temperature batteries

    Science.gov (United States)

    Jungst, Rudolph G.; Armijo, James R.; Frear, Darrel R.

    2000-01-01

    A thermal fuse, preferably for a high-temperature battery, comprising leads and a body therebetween having a melting point between approximately 400.degree. C. and 500.degree. C. The body is preferably an alloy of Ag--Mg, Ag--Sb, Al--Ge, Au--In, Bi--Te, Cd--Sb, Cu--Mg, In--Sb, Mg--Pb, Pb--Pd, Sb--Zn, Sn--Te, or Mg--Al.

  8. High-Temperature Thermoelectric Energy Conversion

    Science.gov (United States)

    Wood, C.

    1987-01-01

    Theory of thermoelectric energy conversion at high temperatures and status of research on conversion materials reviewed in report. Shows highest values of thermoelectric figure of merit, Z, found in semiconductor materials. Semiconductors keep wide choice of elements and compounds. Electrical properties tailored to particular application by impurity doping and control of stoichiometry. Report develops definition of Z useful for comparing materials and uses it to evaluate potentials of different classes of materialsmetals, semiconductors, and insulators.

  9. High Temperature Perforating System for Geothermal Applications

    Energy Technology Data Exchange (ETDEWEB)

    Smart, Moises E. [Schlumberger Technology Corporation, Sugar Land, TX (United States)

    2017-02-28

    The objective of this project is to develop a perforating system consisting of all the explosive components and hardware, capable of reliable performance in high temperatures geothermal wells (>200 ºC). In this light we will focused on engineering development of these components, characterization of the explosive raw powder and developing the internal infrastructure to increase the production of the explosive from laboratory scale to industrial scale.

  10. High-temperature technological processes: Thermophysical principles

    Science.gov (United States)

    Rykalin, N. N.; Uglov, A. A.; Anishchenko, L. M.

    The book is concerned with the principles of thermodynamics and heat transfer theory underlying high-temperature technological processes. Some characteristics of electromagnetic radiation and heat transfer in solids, liquids, and gases are reviewed, and boundary layer theory, surface phenomena, and phase transitions are examined. The discussion includes an analysis of a number of specific processes, such as treatment by concentrated energy fluxes (electron-beam and laser processing) and plasma machining.

  11. High temperature, high power piezoelectric composite transducers.

    Science.gov (United States)

    Lee, Hyeong Jae; Zhang, Shujun; Bar-Cohen, Yoseph; Sherrit, Stewart

    2014-08-08

    Piezoelectric composites are a class of functional materials consisting of piezoelectric active materials and non-piezoelectric passive polymers, mechanically attached together to form different connectivities. These composites have several advantages compared to conventional piezoelectric ceramics and polymers, including improved electromechanical properties, mechanical flexibility and the ability to tailor properties by using several different connectivity patterns. These advantages have led to the improvement of overall transducer performance, such as transducer sensitivity and bandwidth, resulting in rapid implementation of piezoelectric composites in medical imaging ultrasounds and other acoustic transducers. Recently, new piezoelectric composite transducers have been developed with optimized composite components that have improved thermal stability and mechanical quality factors, making them promising candidates for high temperature, high power transducer applications, such as therapeutic ultrasound, high power ultrasonic wirebonding, high temperature non-destructive testing, and downhole energy harvesting. This paper will present recent developments of piezoelectric composite technology for high temperature and high power applications. The concerns and limitations of using piezoelectric composites will also be discussed, and the expected future research directions will be outlined.

  12. High temperature dynamic engine seal technology development

    Science.gov (United States)

    Steinetz, Bruce M.; Dellacorte, Christopher; Machinchick, Michael; Mutharasan, Rajakkannu; Du, Guang-Wu; Ko, Frank; Sirocky, Paul J.; Miller, Jeffrey H.

    1992-01-01

    Combined cycle ramjet/scramjet engines being designed for advanced hypersonic vehicles, including the National Aerospace Plane (NASP), require innovative high temperature dynamic seals to seal the sliding interfaces of the articulated engine panels. New seals are required that will operate hot (1200 to 2000 F), seal pressures ranging from 0 to 100 psi, remain flexible to accommodate significant sidewall distortions, and resist abrasion over the engine's operational life. This report reviews the recent high temperature durability screening assessments of a new braided rope seal concept, braided of emerging high temperature materials, that shows promise of meeting many of the seal demands of hypersonic engines. The paper presents durability data for: (1) the fundamental seal building blocks, a range of candidate ceramic fiber tows; and for (2) braided rope seal subelements scrubbed under engine simulated sliding, temperature, and preload conditions. Seal material/architecture attributes and limitations are identified through the investigations performed. The paper summarizes the current seal technology development status and presents areas in which future work will be performed.

  13. New fluid for high temperature applications

    Energy Technology Data Exchange (ETDEWEB)

    Riva, M.; Flohr, F. [Solvay Fluor GmbH, Hannover (Germany); Froeba, A.P. [Lehrstuhl fuer Technische Thermodynamik (LTT), Univ. Erlangen (Germany)

    2006-12-15

    As a result of the worldwide increased consumption of energy, energy saving measures come more and more in the focus of commercial acting. Besides the efficiency enhancement of energy consuming systems the utilization of waste heat is an additional possibility of saving energy. Areas where this might be feasible are geothermal power plants, local combined heat and power plants, solar-thermal-systems and high temperature heat pumps (HTHP). All these applications need a transfer fluid which secures the transport of the energy from it's source to the place where it is needed at high temperatures. The paper will start with a description or overview of promising energy sources and their utilization. The thermophysical properties of an azeotropic binary mixture of HFC-365mfc and a per-fluoro-poly-ether (PFPE) which fulfils the requirements on a high temperature working fluid are introduced in the second part of the paper. First results and practical experiences in an ORC process are shown in this context followed by an estimation regarding the saved energy or the improved efficiency respectively for other applications The paper will end with a brief outlook on possible new applications e.g. autarkic systems or immersion cooling of electrical parts. (orig.)

  14. Laser Plasma Coupling for High Temperature Hohlraums

    Energy Technology Data Exchange (ETDEWEB)

    Kruer, W.

    1999-11-04

    Simple scaling models indicate that quite high radiation temperatures can be achieved in hohlraums driven with the National Ignition Facility. A scaling estimate for the radiation temperature versus pulse duration for different size NIF hohlraums is shown in Figure 1. Note that a radiation temperature of about 650 ev is projected for a so-called scale 1 hohlraum (length 2.6mm, diameter 1.6mm). With such high temperature hohlraums, for example, opacity experiments could be carried out using more relevant high Z materials rather than low Z surrogates. These projections of high temperature hohlraums are uncertain, since the scaling model does not allow for the very strongly-driven laser plasma coupling physics. Lasnex calculations have been carried out to estimate the plasma and irradiation conditions in a scale 1 hohlraum driven by NIF. Linear instability gains as high as exp(100) have been found for stimulated Brillouin scattering, and other laser-driven instabilities are also far above their thresholds. More understanding of the very strongly-driven coupling physics is clearly needed in order to more realistically assess and improve the prospects for high temperature hohlraums. Not surprisingly, this regime has been avoided for inertial fusion applications and so is relatively unexplored.

  15. Vapor phase lubrication of high temperature alloys

    Energy Technology Data Exchange (ETDEWEB)

    Hanyaloglu, B.F.; Graham, E.E.; Oreskovic, T.; Hajj, C.G. [Cleveland State Univ., OH (United States)

    1995-06-01

    In a previous study, it was found that when a nickel-based superalloy IN750 was heated to high temperatures, a passive layer of aluminum oxide formed on the surface, preventing vapor phase lubrication. In this study, two nickel-chrome-iron alloys and a nickel-copper alloy were studied for high temperature lubrication to see if these alloys, which contained small amounts of aluminum, would exhibit similar behavior. It was found that under static conditions, all three alloys formed a lubricious nodular coating when exposed to a vapor of aryl phosphate. Under dynamic sliding conditions at 500{degrees}C, these alloys were successfully lubricated with a coefficient of friction of 0.1 and no detectable wear. In order to explain these results, a direct correlation between successful vapor phase lubrication and the composition of the alloys containing aluminum has been proposed. If the ratio of copper/aluminum or iron/aluminum is greater that 100 vapor phase, lubrication will be successful. If the ratio is less than 10, a passive aluminum oxide layer will prevent vapor phase lubrication. By selecting alloys with a high iron or copper content, vapor phase lubrication can provide excellent lubrication at high temperatures. 14 refs., 11 figs., 1 tab.

  16. Solubility of silicon in hcp-iron at high pressure

    Science.gov (United States)

    Kuwayama, Y.

    2012-12-01

    The Earth's outer core is believed to be composed of liquid iron alloy with one or more light elements (e.g., Birch 1952; Poirier 1994). Although a number of elements lighter than iron, including hydrogen, carbon, oxygen, silicon, and sulfur, have been considered by various researchers as potential light elements in the Earth's core, silicon is one of the most attractive candidates for the light element in the core (e.g., Takafuji et al. 2005; Sakai et al. 2006; Ozawa et al. 2008, 2009, Wood et al., 2008). The Earth's inner core is considered to consist mainly of a solid iron-nickel alloy. However, multiple experimental studies revealed that the inner core is also less dense than pure iron, indicating the presence of light components in the inner core (e.g., Jephcoat and Olson 1987; Mao et al. 1998; Lin et al. 2005; Badro et al. 2007). If silicon is indeed a major light element in the liquid outer core, the maximum amount of silicon that can be incorporated in the solid inner core during inner-core solidification is limited by the solubility of silicon in solid iron at the pressure of the inner core boundary. Therefore the phase relations of iron-silicon alloys, especially the solubility of silicon in solid iron at high pressure and temperature, are the key to understanding the composition, structure, and crystallization of the inner core. The phase relations of iron-silicon alloys at high pressure have been extensively studied using a multi-anvil apparatus (Zhang and Guyot 1999; Dobson et al. 2002; Kuwayama and Hirose 2004) and a diamond-anvil cell with in-situ x-ray diffraction measurements (Lin et al. 2002; Lin et al. 2003; Dubrovinsky et al. 2003; Hirao et al. 2004; Asanuma et al. 2008, Lin et al 2009, Kuwayama et al. 2009). Below 200 GPa, the solubility of silicon in solid hcp-iron has been well studied. Solid hcp-iron can contain at least ~10 wt% Si at low temperature, but it decomposed to iron-rich hcp phase and silicon-rich bcc phase at high temperature

  17. Effects of high-pressure processing (HPP) on the microbiological ...

    African Journals Online (AJOL)

    STORAGESEVER

    2009-12-29

    Dec 29, 2009 ... High pressure processing (HPP) is an increasingly popular food processing method that offers great potential within the food industry. ... Key words: High pressure processing, fresh cheese, dairy, spoilage. INTRODUCTION. Food ..... chemical reactions and genetic mechanisms. Primarily,. HP treatment ...

  18. High Pressure Research on Materials-Experimental Techniques to ...

    Indian Academy of Sciences (India)

    Home; Journals; Resonance – Journal of Science Education; Volume 12; Issue 8. High Pressure Research on Materials - Experimental Techniques to Study the Behaviour of Materials Under High Pressure. P Ch Sahu N V Chandra Shekar. General Article Volume 12 Issue 8 August 2007 pp 49-64 ...

  19. Quantum effects in condensed matter at high pressure

    CERN Document Server

    Stishov, S M

    2001-01-01

    Experimental data on the influence of quantum effects on the equation of state and melting at high pressure are reviewed. It is shown that quantum isotopic effects tend to increase upon compression of substances with predominately Coulomb interaction, whereas compression of the van der Waals substances reveals the opposite trend. The cold melting of Coulomb substances at high pressure is discussed

  20. Novel High Temperature Magnetic Bearings for Space Vehicle Systems Project

    Data.gov (United States)

    National Aeronautics and Space Administration — Previous high temperature magnetic bearings employed only electromagnets. The work proposed in this SBIR program seeks to utilize High Temperature Permanent Magnets...

  1. Novel High Temperature Magnetic Bearings for Space Vehicle Systems Project

    Data.gov (United States)

    National Aeronautics and Space Administration — Previous high temperature magnetic bearings employed electromagnets only. The work proposed in this SBIR program seeks to utilize High Temperature Permanent Magnets...

  2. Melting in the Fe-Si System at High Pressures

    Science.gov (United States)

    Campbell, A. J.; Fischer, R. A.; Reaman, D. M.; Prakapenka, V.; Dera, P. K.

    2011-12-01

    The density of Earth's core is less dense than that of pure iron, indicating the presence of a light element component that not only reduces the density of the outer core but lowers its melting point as well. Among the most likely candidates for this light element component are Si, S, C, and O; it is important to know the high-pressure, high-temperature properties of iron alloyed with these elements to understand the nature of Earth's core. Here we report on melting experiments in the Fe-Si system to pressures reaching those in the outermost core. Synchrotron X-ray diffraction experiments were performed on laser-heated diamond anvil cell samples at beamline 13-ID-D of the Advanced Photon Source. Temperatures were measured spectroradiometrically, and melting was determined by the appearance and disappearance of diffuse scattering from the melt during heating and cooling cycles. Two compositions, Fe-9Si and Fe-16Si, were studied. Our results are compatible with recent studies [1,2] on similar compositions but lower pressures. At 137 GPa we bracket the melting temperature of Fe-16Si between 3530 and 3800 K; accordingly, 3520 K is a minimum temperature for the outermost core if it were to consist exclusively of Fe-Si alloy. At these pressures the stable solid phase assemblage for Fe-16Si is a mixture of Fe-rich hcp alloy and a more Si-rich alloy with the B2 structure (Fischer et al., this volume [3]). We observe that the hcp phase disappears while the B2 phase persists at the 138 GPa melting point, implying that the Fe-Si eutectic composition at that pressure lies below 16 wt% Si. By comparison, the maximum Si content of a Fe-Si core is 12 wt%, based on comparison of recent equation of state measurements of Fe-Si alloy [3] with a seismological model of the Earth. [1] Morard et al., PCM 2011. [2] Asanuma et al., PCM 2010. [3] Fischer et al., Fall AGU 2011.

  3. Microstructural Evolution and Mechanical Behavior of High Temperature Solders: Effects of High Temperature Aging

    Science.gov (United States)

    Hasnine, M.; Tolla, B.; Vahora, N.

    2017-12-01

    This paper explores the effects of aging on the mechanical behavior, microstructure evolution and IMC formation on different surface finishes of two high temperature solders, Sn-5 wt.% Ag and Sn-5 wt.% Sb. High temperature aging showed significant degradation of Sn-5 wt.% Ag solder hardness (34%) while aging has little effect on Sn-5 wt.% Sb solder. Sn-5 wt.% Ag experienced rapid grain growth as well as the coarsening of particles during aging. Sn-5 wt.% Sb showed a stable microstructure due to solid solution strengthening and the stable nature of SnSb precipitates. The increase of intermetallic compound (IMC) thickness during aging follows a parabolic relationship with time. Regression analysis (time exponent, n) indicated that IMC growth kinetics is controlled by a diffusion mechanism. The results have important implications in the selection of high temperature solders used in high temperature applications.

  4. Post-peak metamorphic evolution of the Sumdo eclogite from the Lhasa terrane of southeast Tibet

    Science.gov (United States)

    Cao, Dadi; Cheng, Hao; Zhang, Lingmin; Wang, Ke

    2017-08-01

    A reconstruction of the pressure-temperature-time (P-T-t) path of high-pressure eclogite-facies rocks in subduction zones may reveal important information about the tectono-metamorphic processes that occur at great depths along the plate interface. The majority of studies have focused on prograde to peak metamorphism of these rocks, whereas after-peak metamorphism has received less attention. Herein, we present a detailed petrological, pseudosection modeling and radiometric dating study of a retrograded eclogite sample from the Sumdo ultrahigh pressure belt of the Lhasa terrane, Tibet. Mineral chemical variations, textural discontinuities and thermodynamic modeling suggest that the eclogite underwent an exhumation-heating period. Petrographic observations and phase equilibria modeling suggest that the garnet cores formed at the pressure peak (∼2.5 GPa and ∼520 °C) within the lawsonite eclogite-facies and garnet rims (∼1.5 GPa and spans an interval of ∼7 million years, which is a minimum estimate of the duration of the eclogite-facies metamorphism of the Sumdo eclogite.

  5. The Cedrolina Chromitite, Goiás State, Brazil: A Metamorphic Puzzle

    Directory of Open Access Journals (Sweden)

    Yuri de Melo Portella

    2016-09-01

    Full Text Available The Cedrolina chromitite body (Goiás-Brazil is concordantly emplaced within talc-chlorite schists that correspond to the poly-metamorphic product of ultramafic rocks inserted in the Pilar de Goiás Greenstone Belt (Central Brazil. The chromite ore displays a nodular structure consisting of rounded and ellipsoidal orbs (up to 1.5 cm in size, often strongly deformed and fractured, immersed in a matrix of silicates (mainly chlorite and talc. Chromite is characterized by high Cr# (0.80–0.86, high Fe2+# (0.70–0.94, and low TiO2 (av. = 0.18 wt % consistent with variation trends of spinels from metamorphic rocks. The chromitite contains a large suite of accessory phases, but only irarsite and laurite are believed to be relicts of the original igneous assemblage, whereas most accessory minerals are thought to be related to hydrothermal fluids that emanated from a nearby felsic intrusion, metamorphism and weathering. Rutile is one of the most abundant accessory minerals described, showing an unusually high Cr2O3 content (up to 39,200 ppm of Cr and commonly forming large anhedral grains (>100 µm that fill fractures (within chromite nodules and in the matrix or contain micro-inclusions of chromite. Using a trace element geothermometer, the rutile crystallization temperature is estimated at 550–600 °C (at 0.4–0.6 GPa, which is in agreement with P and T conditions proposed for the regional greenschist to low amphibolite facies metamorphic peak of the area. Textural, morphological, and compositional evidence confirm that rutile did not crystallize at high temperatures simultaneously with the host chromitite, but as a secondary metamorphic mineral. Rutile may have been formed as a metamorphic overgrowth product following deformation and regional metamorphic events, filling fractures and incorporating chromite fragments. High Cr contents in rutile very likely are due to Cr remobilization from Cr-spinel during metamorphism and suggest that Ti was

  6. High temperature superconductors applications in telecommunications

    Energy Technology Data Exchange (ETDEWEB)

    Kumar, A.A.; Li, J.; Zhang, M.F. [Prairie View A& M Univ., Texas (United States)

    1994-12-31

    The purpose of this paper is twofold: to discuss high temperature superconductors with specific reference to their employment in telecommunications applications; and to discuss a few of the limitations of the normally employed two-fluid model. While the debate on the actual usage of high temperature superconductors in the design of electronic and telecommunications devices-obvious advantages versus practical difficulties-needs to be settled in the near future, it is of great interest to investigate the parameters and the assumptions that will be employed in such designs. This paper deals with the issue of providing the microwave design engineer with performance data for such superconducting waveguides. The values of conductivity and surface resistance, which are the primary determining factors of a waveguide performance, are computed based on the two-fluid model. A comparison between two models-a theoretical one in terms of microscopic parameters (termed Model A) and an experimental fit in terms of macroscopic parameters (termed Model B)-shows the limitations and the resulting ambiguities of the two-fluid model at high frequencies and at temperatures close to the transition temperature. The validity of the two-fluid model is then discussed. Our preliminary results show that the electrical transport description in the normal and superconducting phases as they are formulated in the two-fluid model needs to be modified to incorporate the new and special features of high temperature superconductors. Parameters describing the waveguide performance-conductivity, surface resistance and attenuation constant-will be computed. Potential applications in communications networks and large scale integrated circuits will be discussed. Some of the ongoing work will be reported. In particular, a brief proposal is made to investigate of the effects of electromagnetic interference and the concomitant notion of electromagnetic compatibility (EMI/EMC) of high T{sub c} superconductors.

  7. High temperature sensors for exhaust diagnosis

    Energy Technology Data Exchange (ETDEWEB)

    Svenningstorp, Henrik

    2000-07-01

    One of the largest problems that we will have to deal with on this planet this millennium is to stop the pollution of our environment. In many of the ongoing works to reduce toxic emissions, gas sensors capable of enduring rough environments and high temperatures, would be a great tool. The different applications where sensors like this would be useful vary between everything from online measurement in the paper industry and food industry to measurement in the exhaust pipe of a car. In my project we have tested Schottky diodes and MlSiCFET sensor as gas sensors operating at high temperatures. The measurement condition in the exhaust pipe of a car is extremely tough, not only is the temperature high and the different gases quite harmful, there are also a lot of particles that can affect the sensors in an undesirable way. In my project we have been testing Schottky diodes and MlSiCFET sensors based on SiC as high temperature sensors, both in the laboratory with simulated exhaust and after a real engine. In this thesis we conclude that these sensors can work in the hostile environment of an engines exhaust. It is shown that when measuring in a gas mixture with a fixed I below one, where the I-value is controlled by the O{sub 2} concentration, a sensor with a catalytic gate metal as sensitive material respond more to the increased O{sub 2} concentration than the increased HC concentration when varying the two correspondingly. A number of different sensors have been tested in simulated exhaust towards NO{sub x}. It was shown that resistivity changes in the thin gate metal influenced the gas response. Tests have been performed where sensors were a part of a SCR system with promising results concerning NH{sub 3} sensitivity. With a working temperature of 300 deg C there is no contamination of the metal surface.

  8. Shock metamorphism of ordinary chondrites

    Science.gov (United States)

    Stoeffler, Dieter; Keil, Klaus; Scott, Edward R. D.

    1991-01-01

    This study proposes a revised petrographic classification of progressive stages of shock metamorphism of 26 ordinary chondrites. Six stages of shock (S1 to S6) are defined on the basis of shock effects in olivine and plagioclase as recognized by thin section microscopy, and the characteristic shock effects of each shock stage are described. It is concluded that shock effects and the sequence of progressively increasing degrees of shock metamorphosis are very similar in H, L, and LL groups. Differences in the frequency distribution of shock stages are relatively minor. It is suggested that the collisional histories of the H, L, and LL parent bodies were similar. Petrologic type-3 chondrites are deficient in stages S4 and S6 and, with increasing petrologic type, the frequency of stages S4 to S6 increases. It is suggested that the more porous and volatile-rich Type-3 chondrites are subject to melting at a lower shock pressure than the nonporous chondrites of higher petrologic type. Stage S3 is the most abundant in nearly all petrologic types.

  9. High temperature behaviour of a zircon ceramic

    Energy Technology Data Exchange (ETDEWEB)

    Carbonneau, X.; Olagnon, C.; Fantozzi, G. [INSA, Villeurbanne (France). GEMMPM; Hamidouche, M. [Lab. Science des Materiaux, Univ. de Setif (Algeria); Torrecillas, R. [Inst. Nacional del Carbon, Oviedo (Spain)

    1997-12-31

    The high temperature properties of a sintered zircon material has been tested up to 1200 C. A significant creep rate is observed, mainly attributed to the presence of glassy phase. The sub-critical crack growth measured in double torsion showed that above 1000 C, the crack velocity is reduced either by stress relaxation or by crack healing. The thermal shock analysis under a heat exchange coefficient of 600 W/m{sup 2}/K showed a regular decrease rather that a sudden fall off of properties. (orig.) 3 refs.

  10. High temperature and pressure electrochemical test station

    DEFF Research Database (Denmark)

    Chatzichristodoulou, Christodoulos; Allebrod, Frank; Mogensen, Mogens Bjerg

    2013-01-01

    An electrochemical test station capable of operating at pressures up to 100 bars and temperatures up to 400 ◦C has been established. It enables control of the partial pressures and mass flow of O2, N2, H2, CO2, and H2O in a single or dual environment arrangement, measurements with highly corrosive......, to the electrochemical characterization of high temperature and pressure alkaline electrolysis cells and the use of pseudo-reference electrodes for the separation of each electrode contribution. A future perspective of various electrochemical processes and devices that can be developed with the use of the established...

  11. High temperature superconducting digital circuits and subsystems

    Energy Technology Data Exchange (ETDEWEB)

    Martens, J.S.; Pance, A.; Whiteley, S.R.; Char, K.; Johansson, M.F.; Lee, L. [Conductus, Sunnyvale, CA (United States); Hietala, V.M.; Wendt, J.R. [Sandia National Labs., Albuquerque, NM (United States); Hou, S.Y.; Phillips, J. [AT and T Bell Labs., Murray Hill, NJ (United States)

    1993-10-01

    The advances in the fabrication of high temperature superconducting devices have enabled the demonstration of high performance and useful digital circuits and subsystems. The yield and uniformity of the devices is sufficient for circuit fabrication at the medium scale integration (MSI) level with performance not seen before at 77 K. The circuits demonstrated to date include simple gates, counters, analog to digital converters, and shift registers. All of these are mid-sized building blocks for potential applications in commercial and military systems. The processes used for these circuits and blocks will be discussed along with observed performance data.

  12. Encapsulation of high temperature molten salts

    Energy Technology Data Exchange (ETDEWEB)

    Oxley, James D.; Mathur, Anoop Kumar

    2017-05-16

    The present disclosure relates to a method of encapsulating microcapsules containing relatively high temperature phase change materials and the microcapsules so produced. The microcapsules are coated with an inorganic binder, film former and an inorganic filler. The microcapsules may include a sacrificial layer that is disposed between the particle and the coating. The microcapsules may also include an inner coating layer, sacrificial layer and outer coating layer. The microcapsules are particularly useful for thermal energy storage in connection with, e.g., heat collected from concentrating solar collectors.

  13. Quench in high temperature superconductor magnets

    CERN Document Server

    Schwartz, J.

    2013-01-01

    High field superconducting magnets using high temperature superconductors are being developed for high energy physics, nuclear magnetic resonance and energy storage applications. Although the conductor technology has progressed to the point where such large magnets can be readily envisioned, quench protection remains a key challenge. It is well-established that quench propagation in HTS magnets is very slow and this brings new challenges that must be addressed. In this paper, these challenges are discussed and potential solutions, driven by new technologies such as optical fiber based sensors and thermally conducting electrical insulators, are reviewed.

  14. Sorbents Remove Oxygen At High Temperatures

    Science.gov (United States)

    Sharma, Pramod K.

    1995-01-01

    Cobalt-exchanged, platinized zeolites 13X and L found conveniently reducible in hot gaseous mixture of hydrogen and nitrogen and thereafter useful as sorbents of trace amounts of oxygen at high temperatures. Aided by catalytic action of platinum, sorbents exhibit rapid oxygen-sorption kinetics and, according to thermodynamic properties of O2/CoO system, capable of lowering level of oxygen in otherwise inert gaseous atmosphere to less than 1 part per trillion in temperature range of 400 to 800 degrees C. Inert atmospheres with these oxygen levels required for processing of certain materials in semiconductor industry.

  15. A review of high-temperature adhesives

    Science.gov (United States)

    St.clair, A. K.; St.clair, T. L.

    1981-01-01

    The development of high temperature adhesives and polyphenylquinoxalines (PPQ) is reported. Thermoplastic polyimides and linear PPQ adhesive are shown to have potential for bonding both metals and composite structures. A nadic terminated addition polyimide adhesive, LARC-13, and an acetylene terminated phenylquinoxaline (ATPQ) were developed. Both of the addition type adhesives are shown to be more readily processable than linear materials but less thermooxidatively stable and more brittle. It is found that the addition type adhesives are able to perform, at elevated temperatures up to 595 C where linear systems fail thermoplastically.

  16. High Temperature Materials Laboratory third annual report

    Energy Technology Data Exchange (ETDEWEB)

    Tennery, V.J.; Foust, F.M.

    1990-12-01

    The High Temperature Materials Laboratory has completed its third year of operation as a designated DOE User Facility at the Oak Ridge National Laboratory. Growth of the user program is evidenced by the number of outside institutions who have executed user agreements since the facility began operation in 1987. A total of 88 nonproprietary agreements (40 university and 48 industry) and 20 proprietary agreements (1 university, 19 industry) are now in effect. Sixty-eight nonproprietary research proposals (39 from university, 28 from industry, and 1 other government facility) and 8 proprietary proposals were considered during this reporting period. Research projects active in FY 1990 are summarized.

  17. Ultrasonic depth gauge for liquids under high pressure

    Science.gov (United States)

    Zuckerwar, Allan J. (Inventor); Mazel, David S. (Inventor)

    1988-01-01

    The invention relates to an ultrasonic depth gauge for liquids under high pressure and is particularly useful in the space industry where it is necessary to use a pressurized gas to transfer a liquid from one location to another. Conventional liquid depth gauges do not have the capability to operate under extreme high pressure (i.e., exceeding 300 psi). An ultrasonic depth gauge capable of withstanding high pressure according to the present invention is comprised of a transducer assembly and a supporting electronics unit. The former is mounted in to the bottom wall of a storage vessel with its resonating surface directly exposed to the highly pressurized liquid in the vessel. In operation, the ultrasonic pulse propagates upward through the liquid to the liquid-gas interface in the storage vessel. When the ultrasonic echo returns from the liquid-gas interface, it re-excites the composite resonator into vibration. The supporting electronics unit measures the round-trip transmit time for the ultrasonic pulse and its return echo to traverse the depth of the highly pressurized liquid. The novelty of the invention resides in the use of a conventional transducer rigidly bonded to the inside wall of a bored out conventional high-pressure plug to form a composite resonator capable of withstanding extremely high pressure.

  18. Amphibole zonation as a tool for tracing metamorphic histories: examples from Lavrion and Penteli metamorphic core complexes

    Science.gov (United States)

    Baziotis, Ioannis; Proyer, Alexander; Mposkos, Evripides; Marsellos, Antonios; Leontakianakos, George

    2014-05-01

    The amphiboles represent the predominant minerals in high pressure/low temperature metamafic rocks. Amphibole composition (e.g. cations Si, Al, Na) depends on the bulk composition, the solid solution's gaps and the P-T conditions during metamorphism. The AlIV , NaA and Ti increase with temperature, whereas AlV I and NaB with pressure (Triboulet, 1992). Increase of Si+4 and decrease of AlV I and (NaA+NaB) in clinoamphibole is concurrent with pressure decrease. We focus on Na- and Ca-amphiboles from greenschists and blueschists from Lavrion (upper tectonic unit-UTU) and Penteli (lower tectonic unit-LTU) metamorphic complexes (Baziotis et al. 2009; Baziotis & Mposkos, 2011) in order to unravel the relation of zonation with: (1) the physicochemical conditions and (2) the P-T stages during metamorphic evolution. Amphiboles in Lavrion metabasites are the dominant rock constituents: (ferro)-glaucophane in the blueschists and actinolite in the greenschists. Blue-amphiboles occur in various textural modes: parallel to the foliation, replacing omphacite, rimmed by Ca-amphibole, as inclusions in albite and epidote or in calcitic veinlets. The blue-amphibole composition varies from glaucophane to ferro-glaucophane with the NaB ranging from 1.617 to 1.979 a.p.f.u., whereas the green-amphiboles are actinolites. In the blueschists, actinolite has higher R3+ at a given NaB compared to the greenschists, attributed to Fe+3-rich bulk composition of the blueschists. Three types of zoning were observed in these amphiboles: glaucophane rimming actinolite, glaucophane with increasing AlIV , AlV I and NaB values towards the rim, and actinolite mantling glaucophane. The zoning patterns in the blue-amphiboles are characterized by increasing Tschermak and glaucophane components towards the rim, consistent with increasing temperature and pressure during prograde metamorphism. Two different modes of actinolite represent different stages of the metamorphic history. The actinolite inclusions

  19. Apparatus for accurately measuring high temperatures

    Science.gov (United States)

    Smith, D.D.

    The present invention is a thermometer used for measuring furnace temperatures in the range of about 1800/sup 0/ to 2700/sup 0/C. The thermometer comprises a broadband multicolor thermal radiation sensor positioned to be in optical alignment with the end of a blackbody sight tube extending into the furnace. A valve-shutter arrangement is positioned between the radiation sensor and the sight tube and a chamber for containing a charge of high pressure gas is positioned between the valve-shutter arrangement and the radiation sensor. A momentary opening of the valve shutter arrangement allows a pulse of the high gas to purge the sight tube of air-borne thermal radiation contaminants which permits the radiation sensor to accurately measure the thermal radiation emanating from the end of the sight tube.

  20. Safety analysis of high pressure gasous fuel container punctures

    Energy Technology Data Exchange (ETDEWEB)

    Swain, M.R. [Univ. of Miami, Coral Gables, FL (United States)

    1995-09-01

    The following report is divided into two sections. The first section describes the results of ignitability tests of high pressure hydrogen and natural gas leaks. The volume of ignitable gases formed by leaking hydrogen or natural gas were measured. Leaking high pressure hydrogen produced a cone of ignitable gases with 28{degrees} included angle. Leaking high pressure methane produced a cone of ignitable gases with 20{degrees} included angle. Ignition of hydrogen produced larger overpressures than did natural gas. The largest overpressures produced by hydrogen were the same as overpressures produced by inflating a 11 inch child`s balloon until it burst.

  1. Implement and application of ultra-high pressures environment

    Science.gov (United States)

    Xian Zhang, Yu; Li, Nan; Liu, Bin Bin; Wang, Hong

    2017-09-01

    A hydraulic system was designed which was used to generate hydrostatic ultra-high pressure environment. The functions and roles of the main elements in the hydraulic system were introduced. Deformation theory based on ultrahigh pressure cylinder was analyzed. The principle and method about measuring ultra-high pressure cylinder radial and circumferential elastic line-strain by a dial indicator were illustrated. A practical example was given to illustrate the practicability and validity of this method. The measures to decrease the measurement error were pointed out. The described priciples and methods have a certain theoretical and practical significance in engineering research and application of ultra-high pressure.

  2. Public debate on metallic hydrogen to boost high pressure research

    Directory of Open Access Journals (Sweden)

    Hua Y. Geng

    2017-11-01

    Full Text Available Instead of praises from colleagues, the claim of observation of metallic hydrogen at 495 GPa by Dias and Silvera met much skepticism, and grew into a public debate at the International Conference on High-Pressure Science and Technology, AIRAPT26. We briefly review this debate, and extend the topic to show that this disputation could be an opportunity to benefit the whole high pressure community. Keywords: High pressure, Metallic hydrogen, Quantum solid and liquid, Phase stability, Superconductivity, PACS codes: 61.50.Ks, 67.63.-r, 67.80.-s, 71.30.+h, 74.62.Fj

  3. Medium Deep High Temperature Heat Storage

    Science.gov (United States)

    Bär, Kristian; Rühaak, Wolfram; Schulte, Daniel; Welsch, Bastian; Chauhan, Swarup; Homuth, Sebastian; Sass, Ingo

    2015-04-01

    Heating of buildings requires more than 25 % of the total end energy consumption in Germany. Shallow geothermal systems for indirect use as well as shallow geothermal heat storage systems like aquifer thermal energy storage (ATES) or borehole thermal energy storage (BTES) typically provide low exergy heat. The temperature levels and ranges typically require a coupling with heat pumps. By storing hot water from solar panels or thermal power stations with temperatures of up to 110 °C a medium deep high temperature heat storage (MDHTS) can be operated on relatively high temperature levels of more than 45 °C. Storage depths of 500 m to 1,500 m below surface avoid conflicts with groundwater use for drinking water or other purposes. Permeability is typically also decreasing with greater depth; especially in the crystalline basement therefore conduction becomes the dominant heat transport process. Solar-thermal charging of a MDHTS is a very beneficial option for supplying heat in urban and rural systems. Feasibility and design criteria of different system configurations (depth, distance and number of BHE) are discussed. One system is designed to store and supply heat (300 kW) for an office building. The required boreholes are located in granodioritic bedrock. Resulting from this setup several challenges have to be addressed. The drilling and completion has to be planned carefully under consideration of the geological and tectonical situation at the specific site.

  4. Development of High Temperature Gas Sensor Technology

    Science.gov (United States)

    Hunter, Gary W.; Chen, Liang-Yu; Neudeck, Philip G.; Knight, Dak; Liu, Chung-Chiun; Wu, Quing-Hai; Zhou, Huan-Jun

    1997-01-01

    The measurement of engine emissions is important for their monitoring and control. However, the ability to measure these emissions in-situ is limited. We are developing a family of high temperature gas sensors which are intended to operate in harsh environments such as those in an engine. The development of these sensors is based on progress in two types of technology: (1) The development of SiC-based semiconductor technology; and (2) Improvements in micromachining and microfabrication technology. These technologies are being used to develop point-contact sensors to measure gases which are important in emission control especially hydrogen, hydrocarbons, nitrogen oxides, and oxygen. The purpose of this paper is to discuss the development of this point-contact sensor technology. The detection of each type of gas involves its own challenges in the fields of materials science and fabrication technology. Of particular importance is sensor sensitivity, selectivity, and stability in long-term, high temperature operation. An overview is presented of each sensor type with an evaluation of its stage of development. It is concluded that this technology has significant potential for use in engine applications but further development is necessary.

  5. High-temperature superconductors make major progress

    CERN Multimedia

    CERN Bulletin

    2014-01-01

    This month's Nature Materials featured an important breakthrough for high-temperature superconductors. A new method has been found for processing Bi-2212 high-temperature superconducting round wire in order to drastically increase its critical current density. The result confirms that this conductor is a serious candidate for future very-high-field magnets.   This image shows the cross-section of two Bi-2212 wires. The bottom wire has less leakage and void porosity due to a heat treatment done at an overpressure of 100 bar - about 100 times the pressure used to produce the top wire (image from [Nature Materials, Vol. 13 (2014), 10.1038/nmat3887]). The workhorse for building superconducting accelerator magnets has been, so far, the Niobium-Titanium (Nb-Ti) alloy superconductor. But with Nb-Ti having reached its full potential, other conductors must be used to operate in higher magnetic fields beyond those reached with the LHC magnets. Today, the intermetallic Niobium-Tin (Nb3Sn) is th...

  6. Conformal Properties in High Temperature QCD

    CERN Document Server

    Ishikawa, K -I; Nakayama, Yu; Yoshie, T

    2015-01-01

    We investigate the properties of quarks and gluons above the chiral phase transition temperature $T_c,$ using the RG improved gauge action and the Wilson quark action with two degenerate quarks mainly on a $32^3\\times 16$ lattice. In the one-loop perturbation theory, the thermal ensemble is dominated by the gauge configurations with effectively $Z(3)$ center twisted boundary conditions, making the thermal expectation value of the spatial Polyakov loop take a non-trivial $Z(3)$ center. This is in agreement with our lattice simulation of high temperature QCD. We further observe that the temporal propagator of massless quarks at extremely high temperature $\\beta=100.0 \\, (T \\simeq10^{58} T_c)$ remarkably agrees with the temporal propagator of free quarks with the $Z(3)$ twisted boundary condition for $t/L_t \\geq 0.2$, but differs from that with the $Z(3)$ trivial boundary condition. As we increase the mass of quarks $m_q$, we find that the thermal ensemble continues to be dominated by the $Z(3)$ twisted gauge fi...

  7. Hole-doped cuprate high temperature superconductors

    Energy Technology Data Exchange (ETDEWEB)

    Chu, C.W.; Deng, L.Z.; Lv, B.

    2015-07-15

    Highlights: • Historical discoveries of hole-doped cuprates and representative milestone work. • Several simple and universal scaling laws of the hole-doped cuprates. • A comprehensive classification list with references for hole-doped cuprates. • Representative physical parameters for selected hole-doped cuprates. - Abstract: Hole-doped cuprate high temperature superconductors have ushered in the modern era of high temperature superconductivity (HTS) and have continued to be at center stage in the field. Extensive studies have been made, many compounds discovered, voluminous data compiled, numerous models proposed, many review articles written, and various prototype devices made and tested with better performance than their nonsuperconducting counterparts. The field is indeed vast. We have therefore decided to focus on the major cuprate materials systems that have laid the foundation of HTS science and technology and present several simple scaling laws that show the systematic and universal simplicity amid the complexity of these material systems, while referring readers interested in the HTS physics and devices to the review articles. Developments in the field are mostly presented in chronological order, sometimes with anecdotes, in an attempt to share some of the moments of excitement and despair in the history of HTS with readers, especially the younger ones.

  8. Cooling Effect of Water Injection on a High-Temperature Supersonic Jet

    Directory of Open Access Journals (Sweden)

    Jing Li

    2015-11-01

    Full Text Available The high temperature and high pressure supersonic jet is one of the key problems in the design of solid rocket motors. To reduce the jet temperature and noise, cooling water is typically injected into the exhaust plume. Numerical simulations for the gas-liquid multiphase flow field with mixture multiphase model were developed and a series of experiments were carried out. By introducing the energy source terms caused by the vaporization of liquid water into the energy equation, a coupling solution was developed to calculate the multiphase flow field. The temperature data predictions agreed well with the experimental results. When water was injected into the plume, the high temperature core region area was reduced, and the temperature on the head face was much lower than that without water. The relationship between the reduction of temperature on the bottom plate and the momentum ratio is developed, which can be used to predict the cooling effect of water injection in many cases.

  9. Fuel properties effect on the performance of a small high temperature rise combustor

    Science.gov (United States)

    Acosta, Waldo A.; Beckel, Stephen A.

    1989-01-01

    The performance of an advanced small high temperature rise combustor was experimentally determined at NASA-Lewis. The combustor was designed to meet the requirements of advanced high temperature, high pressure ratio turboshaft engines. The combustor featured an advanced fuel injector and an advanced segmented liner design. The full size combustor was evaluated at power conditions ranging from idle to maximum power. The effect of broad fuel properties was studied by evaluating the combustor with three different fuels. The fuels used were JP-5, a blend of Diesel Fuel Marine/Home Heating Oil, and a blend of Suntec C/Home Heating Oil. The fuel properties effect on the performance of the combustion in terms of pattern factor, liner temperatures, and exhaust emissions are documented.

  10. The high pressure gas Cerenkov counter at the Omega Facility.

    CERN Multimedia

    1975-01-01

    The high-pressure gas Cerenkov was used to measure reactions as pion (or kaon)- hydrogen --> forward proton - X. It was built by the Ecole Polytechnique (Palaiseu). Here Peter Sonderegger and Patrick Fleury,

  11. Beam steering effects in turbulent high pressure flames

    Energy Technology Data Exchange (ETDEWEB)

    Hemmerling, B.; Kaeppeli, B. [Paul Scherrer Inst. (PSI), Villigen (Switzerland)

    1997-06-01

    The propagation of a laser beam through a flame is influenced by variations of the optical density. Especially in turbulent high pressure flames this may seriously limit the use of laser diagnostic methods. (author) 1 fig., 2 refs.

  12. Novel High Pressure Pump-on-a-Chip Technology Project

    Data.gov (United States)

    National Aeronautics and Space Administration — HJ Science & Technology, Inc proposes to develop a novel high pressure "pump-on-a-chip" and "valve-on-a-chip" microfluidic technology for NASA planetary science...

  13. Monitoring protein folding through high pressure NMR spectroscopy.

    Science.gov (United States)

    Roche, Julien; Royer, Catherine A; Roumestand, Christian

    2017-11-01

    High-pressure is a well-known perturbation method used to destabilize globular proteins. It is perfectly reversible, which is essential for a proper thermodynamic characterization of a protein equilibrium. In contrast to other perturbation methods such as heat or chemical denaturant that destabilize protein structures uniformly, pressure exerts local effects on regions or domains of a protein containing internal cavities. When combined with NMR spectroscopy, hydrostatic pressure offers the possibility to monitor at a residue level the structural transitions occurring upon unfolding and to determine the kinetic properties of the process. High-pressure NMR experiments can now be routinely performed, owing to the recent development of commercially available high-pressure sample cells. This review summarizes recent advances and some future directions of high-pressure NMR techniques for the characterization at atomic resolution of the energy landscape of protein folding. Copyright © 2017 Elsevier B.V. All rights reserved.

  14. A high-pressure MWPC detector for crystallography

    DEFF Research Database (Denmark)

    Ortuno-Prados, F.; Bazzano, A.; Berry, A.

    1999-01-01

    The application of the Multi-Wire Proportional Counter (MWPC) as a potential detector for protein crystallography and other wide-angle diffraction experiments is presented. Electrostatic problems found with our large area MWPC when operated at high pressure are discussed. We suggest that a soluti...... to these problems is to use a glass micro-strip detector in place of the wire frames. The characteristics of a high-pressure Micro-Strip Gas Chamber (MSGC) tested in the laboratory are presented....

  15. High-pressure crystallography of periodic and aperiodic crystals

    Directory of Open Access Journals (Sweden)

    Clivia Hejny

    2015-03-01

    Full Text Available More than five decades have passed since the first single-crystal X-ray diffraction experiments at high pressure were performed. These studies were applied historically to geochemical processes occurring in the Earth and other planets, but high-pressure crystallography has spread across different fields of science including chemistry, physics, biology, materials science and pharmacy. With each passing year, high-pressure studies have become more precise and comprehensive because of the development of instrumentation and software, and the systems investigated have also become more complicated. Starting with crystals of simple minerals and inorganic compounds, the interests of researchers have shifted to complicated metal–organic frameworks, aperiodic crystals and quasicrystals, molecular crystals, and even proteins and viruses. Inspired by contributions to the microsymposium `High-Pressure Crystallography of Periodic and Aperiodic Crystals' presented at the 23rd IUCr Congress and General Assembly, the authors have tried to summarize certain recent results of single-crystal studies of molecular and aperiodic structures under high pressure. While the selected contributions do not cover the whole spectrum of high-pressure research, they demonstrate the broad diversity of novel and fascinating results and may awaken the reader's interest in this topic.

  16. Fast pyrolysis of biomass at high temperatures

    DEFF Research Database (Denmark)

    Trubetskaya, Anna

    . Different particle shapes of beechwood and leached wheat straw chars produced in the drop tube reactor which have similar potassium content suggested a stronger influence of the major biomass cell wall compounds (cellulose, hemicellulose, lignin and extractives) and silicates on the char morphology than...... multi core structures compared to pinewood soot generated at 1400°C, combining both single and multi core particles.Beechwood and wheat straw soot samples had multi and single core particles at both temperatures.In thermogravimetric analysis, the maximal reaction rate of pinewood soot was shifted...... pyrolysis at high temperatures plays a significant role in the overall combustion process since the biomass type, the reaction kinetics and heat transfer rates during pyrolysis influence the volatile gas release. The solid residue yield and its properties in suspension firing, including particle size...

  17. High Temperature Battery for Drilling Applications

    Energy Technology Data Exchange (ETDEWEB)

    Josip Caja

    2009-12-31

    In this project rechargeable cells based on the high temperature electrochemical system Na/beta''-alumina/S(IV) in AlCl3/NaCl were developed for application as an autonomous power source in oil/gas deep drilling wells. The cells operate in the temperature range from 150 C to 250 C. A prototype DD size cell was designed and built based on the results of finite element analysis and vibration testing. The cell consisted of stainless steel case serving as anode compartment with cathode compartment installed in it and a seal closing the cell. Critical element in cell design and fabrication was hermetically sealing the cell. The seal had to be leak tight, thermally and vibration stable and compatible with electrode materials. Cathode compartment was built of beta''-alumina tube which served as an electrolyte, separator and cathode compartment.

  18. High Temperature Polymer Electrolyte Fuel Cells

    DEFF Research Database (Denmark)

    Fleige, Michael

    This thesis presents the development and application of electrochemical half-cell setups to study the catalytic reactions taking place in High Temperature Polymer Electrolyte Fuel Cells (HTPEM-FCs): (i) a pressurized electrochemical cell with integrated magnetically coupled rotating disk electrode...... to 140 ºC and oxygen pressures up to ~100 bar at room temperature. The GDE cell is successfully tested at 130 ºC by means of direct oxidation of methanol and ethanol, respectively. In the second part of the thesis, the emphasis is put on the ORR in H3PO4 with particular focus on the mass transport...... oxidation of ethanol is in principle a promising concept to supply HTPEM-FCs with a sustainable and on large scale available fuel (ethanol from biomass). However, the intermediate temperature tests in the GDE setup show that even on Pt-based catalysts the reaction rates become first significant...

  19. Creep resistant high temperature martensitic steel

    Energy Technology Data Exchange (ETDEWEB)

    Hawk, Jeffrey A.; Jablonski, Paul D.; Cowen, Christopher J.

    2015-11-13

    The disclosure provides a creep resistant alloy having an overall composition comprised of iron, chromium, molybdenum, carbon, manganese, silicon, nickel, vanadium, niobium, nitrogen, tungsten, cobalt, tantalum, boron, and potentially additional elements. In an embodiment, the creep resistant alloy has a molybdenum equivalent Mo(eq) from 1.475 to 1.700 wt. % and a quantity (C+N) from 0.145 to 0.205. The overall composition ameliorates sources of microstructural instability such as coarsening of M.sub.23C.sub.6 carbides and MX precipitates, and mitigates or eliminates Laves and Z-phase formation. A creep resistant martensitic steel may be fabricated by preparing a melt comprised of the overall composition followed by at least austenizing and tempering. The creep resistant alloy exhibits improved high-temperature creep strength in the temperature environment of around 650.degree. C.

  20. Creep resistant high temperature martensitic steel

    Energy Technology Data Exchange (ETDEWEB)

    Hawk, Jeffrey A.; Jablonski, Paul D.; Cowen, Christopher J.

    2017-01-31

    The disclosure provides a creep resistant alloy having an overall composition comprised of iron, chromium, molybdenum, carbon, manganese, silicon, nickel, vanadium, niobium, nitrogen, tungsten, cobalt, tantalum, boron, copper, and potentially additional elements. In an embodiment, the creep resistant alloy has a molybdenum equivalent Mo(eq) from 1.475 to 1.700 wt. % and a quantity (C+N) from 0.145 to 0.205. The overall composition ameliorates sources of microstructural instability such as coarsening of M.sub.23C.sub.6carbides and MX precipitates, and mitigates or eliminates Laves and Z-phase formation. A creep resistant martensitic steel may be fabricated by preparing a melt comprised of the overall composition followed by at least austenizing and tempering. The creep resistant alloy exhibits improved high-temperature creep strength in the temperature environment of around 650.degree. C.

  1. High temperature superconductors for magnetic suspension applications

    Science.gov (United States)

    Mcmichael, C. K.; Cooley, R. S.; Chen, Q. Y.; Ma, K. B.; Lamb, M. A.; Meng, R. L.; Chu, C. W.; Chu, W. K.

    1994-01-01

    High temperature superconductors (HTS) hold the promise for applications in magnetic levitation bearings, vibration damping, and torque coupling. Traditional magnetic suspension systems require active feedback and vibration controls in which power consumption and low frequency vibration are among the major engineering concerns. HTS materials have been demonstrated to be an enabling approach towards such problems due to their flux trapping properties. In our laboratory at TCSUH, we have been conducting a series of experiments to explore various mechanical applications using HTS. We have constructed a 30 lb. model flywheel levitated by a hybrid superconducting magnetic bearing (HSMB). We are also developing a levitated and vibration-dampled platform for high precision instrumentation. These applications would be ideal for space usages where ambient temperature is adequate for HTS to operate properly under greatly reduced cryogenic requirements. We will give a general overview of these potential applications and discuss the operating principles of the HTS devices we have developed.

  2. High-temperature ordered intermetallic alloys V

    Energy Technology Data Exchange (ETDEWEB)

    Baker, I. (ed.) (Dartmouth Coll., Hanover, NH (United States). Thayer School of Engineering); Darolia, R. (ed.) (GE Aircraft Engines, Cincinnati, OH (United States)); Whittenberger, J.D. (ed.) (NASA, Cleveland, OH (United States). Lewis Research Center); Yoo, M.H. (ed.) (Oak Ridge National Lab., TN (United States))

    1993-01-01

    These proceedings represent the written record of the High-Temperature Ordered Intermetallic Alloys 5 Symposium which was held in conjunction with the 1992 Fall Materials Research Society meeting in Boston, Massachusetts. This symposium, which was the fifth in the series originated by C.C Koch, C.T. Liu and N.S. Stoloff in 1984, was very successful with 86 oral presentations over four days, and approximately 140 posters given during two lively evening sessions. Such a response, in view of the increasing number of conferences being held on intermetallics each year, reveals the continued high regard for this series of symposia. Individual papers have been processed separately for inclusion in the appropriate data bases.

  3. High temperature chemically resistant polymer concrete

    Science.gov (United States)

    Sugama, T.; Kukacka, L.E.

    High temperature chemically resistant, non-aqueous polymer concrete composites consist of about 12 to 20% by weight of a water-insoluble polymer binder. The binder is polymerized in situ from a liquid vinyl-type monomer or mixture of vinyl containing monomers such as triallylcyanurate, styrene, acrylonitrile, acrylamide, methacrylamide, methyl-methacrylate, trimethylolpropane trimethacrylate and divinyl benzene. About 5 to 40% by weight of a reactive inorganic filler selected from the group consisting of tricalcium silicate and dicalcium silicate and mixtures containing less than 2% free lime, and about 48 to 83% by weight of silica sand/ and a free radical initiator such as di-tert-butyl peroxide, azobisisobutyronitrile, benzoyl peroxide, lauryl peroxide, other orgaic peroxides and combinations to initiate polymerization of the monomer in the presence of the inorganic filers are used.

  4. FY16 ASME High Temperature Code Activities

    Energy Technology Data Exchange (ETDEWEB)

    Swindeman, M. J. [Chromtech Inc., Oak Ridge, TN (United States); Jetter, R. I. [R. I Jetter Consulting, Pebble Beach, CA (United States); Sham, T. -L. [Argonne National Lab. (ANL), Argonne, IL (United States)

    2016-09-01

    One of the objectives of the ASME high temperature Code activities is to develop and validate both improvements and the basic features of Section III, Division 5, Subsection HB, Subpart B (HBB). The overall scope of this task is to develop a computer program to be used to assess whether or not a specific component under specified loading conditions will satisfy the elevated temperature design requirements for Class A components in Section III, Division 5, Subsection HB, Subpart B (HBB). There are many features and alternative paths of varying complexity in HBB. The initial focus of this task is a basic path through the various options for a single reference material, 316H stainless steel. However, the program will be structured for eventual incorporation all the features and permitted materials of HBB. Since this task has recently been initiated, this report focuses on the description of the initial path forward and an overall description of the approach to computer program development.

  5. Gravimeter using high-temperature superconductor bearing.

    Energy Technology Data Exchange (ETDEWEB)

    Hull, J. R.

    1998-09-11

    We have developed a sensitive gravimeter concept that uses an extremely low-friction bearing based on a permanent magnet (PM) levitated over a high-temperature superconductor (HTS). A mass is attached to the PM by means of a cantilevered beam, and the combination of PM and HTS forms a bearing platform that has low resistance to rotational motion but high resistance to horizontal, vertical, or tilting motion. The combination acts as a low-loss torsional pendulum that can be operated in any orientation. Gravity acts on the cantilevered beam and attached mass, accelerating them. Variations in gravity can be detected by time-of-flight acceleration, or by a control coil or electrode that would keep the mass stationary. Calculations suggest that the HTS gravimeter would be as sensitive as present-day superconducting gravimeters that need cooling to liquid helium temperatures, but the HTS gravimeter needs cooling only to liquid nitrogen temperatures.

  6. Thermomechanics of composite structures under high temperatures

    CERN Document Server

    Dimitrienko, Yu I

    2016-01-01

    This pioneering book presents new models for the thermomechanical behavior of composite materials and structures taking into account internal physico-chemical transformations such as thermodecomposition, sublimation and melting at high temperatures (up to 3000 K). It is of great importance for the design of new thermostable materials and for the investigation of reliability and fire safety of composite structures. It also supports the investigation of interaction of composites with laser irradiation and the design of heat-shield systems. Structural methods are presented for calculating the effective mechanical and thermal properties of matrices, fibres and unidirectional, reinforced by dispersed particles and textile composites, in terms of properties of their constituent phases. Useful calculation methods are developed for characteristics such as the rate of thermomechanical erosion of composites under high-speed flow and the heat deformation of composites with account of chemical shrinkage. The author expan...

  7. Diamond switches for high temperature electronics

    Energy Technology Data Exchange (ETDEWEB)

    Prasad, R.R.; Rondeau, G.; Qi, Niansheng [Alameda Applied Sciences Corp., San Leandro, CA (United States)] [and others

    1996-04-25

    Diamond switches are well suited for use in high temperature electronics. Laboratory feasibility of diamond switching at 1 kV and 18 A was demonstrated. DC blocking voltages up to 1 kV were demonstrated. A 50 {Omega} load line was switched using a diamond switch, with switch on-state resistivity {approx}7 {Omega}-cm. An electron beam, {approx}150 keV energy, {approx}2 {mu}s full width at half maximum was used to control the 5 mm x 5 mm x 100 {mu}m thick diamond switch. The conduction current temporal history mimics that of the electron beam. These data were taken at room temperature.

  8. Robust high temperature oxygen sensor electrodes

    DEFF Research Database (Denmark)

    Lund, Anders

    reaction kinetics. At oxygen partial pressures below 10-6 bar at 700 C, the mass transport processes dominated the response time. The response time increased with decreasing oxygen partial pressure and inlet gas flow rate. A series of porous platinum electrodes were impregnated with the ionically...... conducting gadolinium-doped cerium oxide (CGO). The addition of CGO was found to decrease the polarisation resistance of the oxygen reaction by up to an order of magnitude compared with a single phase platinum electrode by increasing the effective triple phase boundary (TPB) length. It did not have any......Platinum is the most widely used material in high temperature oxygen sensor electrodes. However, platinum is expensive and the platinum electrode may, under certain conditions, suffer from poisoning, which is detrimental for an oxygen sensor. The objective of this thesis is to evaluate electrode...

  9. High-temperature brushless DC motor controller

    Energy Technology Data Exchange (ETDEWEB)

    Cieslewski, Crzegorz; Lindblom, Scott C.; Maldonado, Frank J.; Eckert, Michael Nathan

    2017-05-16

    A motor control system for deployment in high temperature environments includes a controller; a first half-bridge circuit that includes a first high-side switching element and a first low-side switching element; a second half-bridge circuit that includes a second high-side switching element and a second low-side switching element; and a third half-bridge circuit that includes a third high-side switching element and a third; low-side switching element. The motor controller is arranged to apply a pulse width modulation (PWM) scheme to switch the first half-bridge circuit, second half-bridge circuit, and third half-bridge circuit to power a motor.

  10. On-wafer high temperature characterization system

    Science.gov (United States)

    Teodorescu, L.; ǎghici, F., Dr; Rusu, I.; Brezeanu, G.

    2016-12-01

    In this work a on-wafer high temperature characterization system for wide bandgap semiconductor devices and circuits has been designed, implemented and tested. The proposed system can perform the wafer temperature adjustment in a large domain, from the room temperature up to 3000C with a resolution better than +/-0.50C. In order to obtain both low-noise measurements and low EMI, the heating element of the wafer chuck is supplied in two ways: one is from a DC linear power supply connected to the mains electricity, another one is from a second DC unit powered by batteries. An original temperature control algorithm, different from classical PID, is used to modify the power applied to the chuck.

  11. Filter unit for use at high temperatures

    Science.gov (United States)

    Ciliberti, David F.; Lippert, Thomas E.

    1988-01-01

    A filtering unit for filtering particulates from high temperature gases uses a spiral ceramic spring to bias a ceramic, tubular filter element into sealing contact with a flange about an aperture of a metallic tube sheet. The ceramic spiral spring may contact the upper edge of the filter element and be restrained by a stop member spaced from one end of the tube sheet, or the spring may contact the bottom of the filter element and be restrained by a support member spaced from the opposite end of the tube sheet. The stop member and support member are adjustably secured to the tube sheet. A filtering system uses the ceramic spiral spring to bias a plurality of ceramic, tubular filter elements in a respective plurality of apertures in a tube sheet which divides a vessel into upper and lower enclosed sections.

  12. Toroidal high temperature superconducting coils for ISTTOK

    Energy Technology Data Exchange (ETDEWEB)

    Fernandes, H., E-mail: hf@ipfn.ist.utl.pt [Associacao Euratom/IST, Instituto de Plasmas e Fusao Nuclear, Laboratorio Associado, Instituto Superior Tecnico, 1049-001 Lisboa (Portugal); Goemoery, F. [Institute of Electrical Engineering, Slovak Academy of Sciences, Dubravska cesta 9, 84104 Bratislava (Slovakia); Corte, A. della; Celentano, G. [ENEA C.R. Frascati, Via E. Fermi 45, 00044 Frascati (Italy); Souc, J. [Institute of Electrical Engineering, Slovak Academy of Sciences, Dubravska cesta 9, 84104 Bratislava (Slovakia); Silva, C.; Carvalho, I.; Gomes, R. [Associacao Euratom/IST, Instituto de Plasmas e Fusao Nuclear, Laboratorio Associado, Instituto Superior Tecnico, 1049-001 Lisboa (Portugal); Di Zenobio, A.; Messina, G. [ENEA C.R. Frascati, Via E. Fermi 45, 00044 Frascati (Italy)

    2011-10-15

    High temperature superconductors (HTS) are very attractive to be used in fusion devices mainly due to lower operations costs. The HTS technology has reached a point where the construction of toroidal field coils for a tokamak is possible. The feasibility of a tokamak operating with HTS is extremely relevant and ISTTOK is the ideal candidate for a meaningful test due to its small size (and consequently lower cost) and the possibility to operate in a steady-state inductive regime. In this paper, a conceptual study of the ISTTOK upgrade to a superconducting device is presented, along with the relevant boundary conditions to achieve a permanent toroidal field with HTS. It is shown that the actual state of the art in HTS allows the design of a toroidal field coil capable of generating the appropriate field on plasma axis while respecting the structural specification of the machine.

  13. Measuring nanowire thermal conductivity at high temperatures

    Science.gov (United States)

    Wang, Xiaomeng; Yang, Juekuan; Xiong, Yucheng; Huang, Baoling; Xu, Terry T.; Li, Deyu; Xu, Dongyan

    2018-02-01

    This work extends the micro-thermal-bridge method for thermal conductivity measurements of nanowires to high temperatures. The thermal-bridge method, based on a microfabricated device with two side-by-side suspended membranes with integrated platinum resistance heaters/thermometers, has been used to determine thermal conductivity of various nanowires/nanotubes/nanoribbons at relatively low temperatures. However, to date, thermal conductivity characterization of nanowires at temperatures above 600 K has seldom been reported presumably due to several technical difficulties including the instability of the microfabricated thermometers, radiation heat loss, and the effect of the background conductance on the measurement. Here we report on our attempt to address the aforementioned challenges and demonstrate thermal conductivity measurement of boron nanoribbons up to 740 K. To eliminate high temperature resistance instability, the device is first annealed at 1023 K for 5 min in an argon atmosphere. Two radiation shields are installed in the measurement chamber to minimize radiation heat loss from the measurement device to the surroundings; and the temperature of the device at each set point is calibrated by an additional thermocouple directly mounted on the chip carrier. The effect of the background conductance is eliminated by adopting a differential measurement scheme. With all these modifications, we successfully measured the thermal conductivity of boron nanoribbons over a wide temperature range from 27 K to 740 K. The measured thermal conductivity increases monotonically with temperature and reaches a plateau of ~2.5 W m‑1 K‑1 at approximately 400 K, with no clear signature of Umklapp scattering observed in the whole measurement temperature range.

  14. Timing and conditions of regional metamorphism and crustal shearing in the granulite facies basement of south Namibia: Implications for the crustal evolution of the Namaqualand metamorphic basement in the Mesoproterozoic

    Science.gov (United States)

    Bial, Julia; Büttner, Steffen; Appel, Peter

    2016-11-01

    Granulite facies basement gneisses from the Grünau area in the Kakamas Domain of the Namaqua-Natal Metamorphic Province in south Namibia show high-grade mineral assemblages, most commonly consisting of garnet, cordierite, sillimanite, alkali feldspar and quartz. Cordierite + hercynitic spinel, and in some places quartz + hercynitic spinel, indicate granulite facies P-T conditions. The peak assemblage equilibrated at 800-850 °C at 4.0-4.5 kbar. Sillimanite pseudomorphs after kyanite1 and late-stage staurolite and kyanite2 indicate that the metamorphic record started and ended within the stability field of kyanite. Monazite in the metamorphic basement gneisses shows a single-phase growth history dated as 1210-1180 Ma, which we interpret as the most likely age of the regional metamorphic peak. This time coincides with the emplacement of granitic plutons in the Grünau region. The ∼10 km wide, NW-SE striking Grünau shear zone crosscuts the metamorphic basement and overprints high-temperature fabrics. In sheared metapelites, the regional metamorphic peak assemblage is largely obliterated, and is replaced by synkinematic biotite2, quartz, alkali feldspar, sillimanite and cordierite or muscovite. In places, gedrite, staurolite, sillimanite and green biotite3 may have formed late- or post-kinematically. The mylonitic mineral assemblage equilibrated at 590-650 °C at 3.5-5.0 kbar, which is similar to a retrograde metamorphic stage in the basement away from the shear zone. Monazite cores in two mylonite samples are similar in texture and age (∼1200 Ma) to monazite in metapelites away from the shear zone. Chemically distinct monazite rims indicate a second growth episode at ∼1130-1120 Ma. This age is interpreted to date the main deformation episode along the Grünau shear zone and the retrograde metamorphic stage seen in the basement. The main episode of ductile shearing along the Grünau shear zone took place 70-80 million years after the thermal peak metamorphism

  15. New geochemical and geochronological data constraining metamorphism of the Tavşanlı Zone, NW Turkey

    Science.gov (United States)

    Aydın, Halil Can; Özdamar, Şenel

    2016-04-01

    The Tavşanlı Zone is a high-grade metamorphic belt, representing subduction and exhumation between the Sakarya Zone and the Afyon-Bolkardaǧ Zone in Western Anatolia. The Sivrihisar area of the Tavşanlı Zone comprises Paleozoic metamorphic rocks including sedimentary and magmatic origanated; Eocene granites; Neogene sedimentary rocks and alluvium. Metasedimantary rocks are composed of marble, schist and quartzite. Metamagmatics are gneiss and metabazites. This study presents new and precise, whole-rock chemistry; phengite-40Ar/39Ar age data from this area to constrain the high pressure (HP)-low temperature (LT) metamorphism of the Tavşanlı Zone. 40Ar/39Ar dating of two phengite samples from schists gave plateau ages between 82,5 ± 0,14 and 83,29 ± 0,22 Ma, which are interpreted as the metamorphic age of these schists, and as the age of metamorphism affected the Tavşanlı Zone. Also these ages constrain the timing of the closure of the Neo-Tethys.

  16. Metamorphic and tectonic evolution of Ceuta peninsula (Internal Rif): new interpretation in the framework of arc and back arc evolution

    Science.gov (United States)

    Homonnay, Emmanuelle; Lardeaux, Jean-Marc; Corsini, Michel; Cenki-Tok, Bénédicte; Bosch, Delphine; Munch, Philippe; Romagny, Adrien; Ouazzani-Touhami, Mohamed

    2016-04-01

    In the last twenty years, various geophysical investigations have established that the Western Mediterranean opened in a subduction context as a back arc domain. In the Alboran basin the dip of the subduction plane is eastwards or southeastwards depending of considered models. If the geological records of back-arc opening are well-known, the arc-related tectonic and petrologic evolutions are still poorly documented. In order to decipher these markers, we focalised structural, petrological and thermo-chronological studies on the Ceuta peninsula located in the Rif belt, on the western part of the Gibraltar arc to the North of Morocco. The present-day tectonic pile is constituted by: (1) the upper Ceuta unit, composed of High Pressure and High Temperature metapelites retromorphosed under Amphibolite-facies condition, with Ultra-High Pressure relicts, and pyrigarnite and spinel bearing peridotites boudins at its base, (2) the lower Monte Hacho unit, with orthogneisses metamorphosed under Amphibolite-facies conditions. Structural analysis indicates a polyphase tectonic evolution: (1) an earlier deformation phase only observed in the UHP metapelites and characterized by a steep S1 foliation plane, (2) a main deformation phase associated to a pervasive gently dipping S2 foliation plane bearing a L2 stretching lineation and synschistose folds whose axes are parallel to L2 and (3) a late deformation phase which developed S3 foliation plane and L3 stretching lineation coeval with development of narrow normal ductile shear zones. A zone of increasing deformation, several dozen meters wide, is identified as a major ductile shear zone involving the peridotitic lenses at the base of the metapelites of the Ceuta unit and overlaying this upper unit on top of the orthogneisses of the Monte Hacho lower unit. The attitude of mylonitic foliation and stretching and mineral lineations as well as the numerous shear sense indicators observed in the shear zone are consistent with a

  17. Metamorphic Evolution of Garnet-bearing Epidote-Barroisite Schist from the Meratus Complex in South Kalimantan, Indonesia

    Directory of Open Access Journals (Sweden)

    Nugroho Imam Setiawan

    2015-09-01

    Full Text Available DOI:10.17014/ijog.2.3.139-156This paper presents metamorphic evolution of metamorphic rocks from the Meratus Complex in South Kalimantan, Indonesia. Eight varieties of metamorphic rocks samples from this location, which are garnet-bearing epidote-barroisite schist, epidote-barroisite schist, glaucophane-quartz schist, garnet-muscovite schist, actinolite-talc schist, epidote schist, muscovite schist, and serpentinite, were investigated in detail its petrological and mineralogical characteristics by using polarization microscope and electron probe micro analyzer (EPMA. Furthermore, the pressure-temperature path of garnet-bearing epidote-barroisite schist was estimated by using mineral parageneses, reaction textures, and mineral chemistries to assess the metamorphic history. The primary stage of this rock might be represented by the assemblage of glaucophane + epidote + titanite ± paragonite. The assemblage yields 1.7 - 1.0 GPa in assumed temperature of 300 - 550 °C, which is interpreted as maximum pressure limit of prograde stage. The peak P-T condition estimated on the basis of the equilibrium of garnet rim, barroisite, phengite, epidote, and quartz, yields 547 - 690 °C and 1.1 - 1.5 GPa on the albite epidote amphibolite-facies that correspond to the depth of 38 - 50 km. The retrograde stage was presented by changing mineral compositions of amphiboles from the Si-rich barroisite to the actinolite, which lies near 0.5 GPa at 350 °C. It could be concluded that metamorphic rocks from the Meratus Complex experienced low-temperature and high-pressure conditions (blueschist-facies prior to the peak metamorphism of the epidote amphibolite-facies. The subduction environments in Meratus Complex during Cretaceous should be responsible for this metamorphic condition.

  18. Metamorphic evolution of ultrahigh-pressure rocks from Chinese southwestern Tianshan and a possible indicator of UHP metamorphism using garnet composition in low-T eclogites

    Science.gov (United States)

    Du, Jin-Xue; Zhang, Li-Fei; Bader, Thomas; Shen, Ting-Ting

    2014-09-01

    How to identify ultrahigh-pressure (UHP) metamorphism in the absence of coesite is a key problem to gain the correct P-T history for an orogenic belt. In this study, garnet composition combined with the pseudosection approach was used to identify ultrahigh-pressure metamorphism and to determine P-T paths for eclogites and metapelites from Chinese southwestern Tianshan. Porphyroblastic garnets from both eclogites and metapelites develop pronounced chemical core-rim textures: the relatively homogeneous core with low pyrope [Prp; Mg/(Ca + Mn + Mg + Fe2+) × 100] and grossular [Grs; Ca/(Ca + Mn + Mg + Fe2+) × 100] content is overgrown by a thin rim with sharply increased Prp and Grs. Phase equilibria modeling indicates that the ultrahigh-pressure rocks have undergone a clockwise P-T path characterized by heating during early exhumation with peak P-T at 31-33 kbar and 490-520 °C. The P-T pseudosections for eclogites show that isopleths of Prp and Grs strongly depend on temperature and pressure, respectively, especially in the stability fields of glaucophane-lawsonite-bearing eclogite facies assemblages. This indicates that garnet composition provides robust thermobarometric constraints. Consequently, we propose a Prp-Grs diagram which is subdivided into a high-pressure region and an ultrahigh-pressure region by the quartz-coesite-transition curve. Those garnet compositions which fall into the ultrahigh-pressure region are regarded to have experienced ultrahigh-pressure metamorphism. This approach is expected to be a useful tool to qualitatively identify ultrahigh-pressure metamorphism for glaucophane-lawsonite-bearing eclogites and its particular strength is the quick examination of large datasets comprising samples with similar bulk composition. Using this method, garnet compositions of eclogites and mafic blueschists from Chinese southwestern Tianshan and lawsonite eclogites worldwide are plotted in the Prp-Grs diagram and several possible ultrahigh

  19. High Temperature Integrated Thermoelectric Ststem and Materials

    Energy Technology Data Exchange (ETDEWEB)

    Mike S. H. Chu

    2011-06-06

    The final goal of this project is to produce, by the end of Phase II, an all ceramic high temperature thermoelectric module. Such a module design integrates oxide ceramic n-type, oxide ceramic p-type materials as thermoelectric legs and oxide ceramic conductive material as metalizing connection between n-type and p-type legs. The benefits of this all ceramic module are that it can function at higher temperatures (> 700 C), it is mechanically and functionally more reliable and it can be scaled up to production at lower cost. With this all ceramic module, millions of dollars in savings or in new opportunities recovering waste heat from high temperature processes could be made available. A very attractive application will be to convert exhaust heat from a vehicle to reusable electric energy by a thermoelectric generator (TEG). Phase I activities were focused on evaluating potential n-type and p-type oxide compositions as the thermoelectric legs. More than 40 oxide ceramic powder compositions were made and studied in the laboratory. The compositions were divided into 6 groups representing different material systems. Basic ceramic properties and thermoelectric properties of discs sintered from these powders were measured. Powders with different particles sizes were made to evaluate the effects of particle size reduction on thermoelectric properties. Several powders were submitted to a leading thermoelectric company for complete thermoelectric evaluation. Initial evaluation showed that when samples were sintered by conventional method, they had reasonable values of Seebeck coefficient but very low values of electrical conductivity. Therefore, their power factors (PF) and figure of merits (ZT) were too low to be useful for high temperature thermoelectric applications. An unconventional sintering method, Spark Plasma Sintering (SPS) was determined to produce better thermoelectric properties. Particle size reduction of powders also was found to have some positive benefits

  20. Evidence for photo-induced monoclinic metallic VO{sub 2} under high pressure

    Energy Technology Data Exchange (ETDEWEB)

    Hsieh, Wen-Pin, E-mail: wphsieh@stanford.edu; Mao, Wendy L. [Stanford Institute for Materials and Energy Sciences, SLAC National Accelerator Laboratory, Menlo Park, California 94025 (United States); Department of Geological and Environmental Sciences, Stanford University, Stanford, California 94305 (United States); Trigo, Mariano [Stanford Institute for Materials and Energy Sciences, SLAC National Accelerator Laboratory, Menlo Park, California 94025 (United States); Stanford PULSE Institute, SLAC National Accelerator Laboratory, Menlo Park, California 94025 (United States); Reis, David A. [Stanford Institute for Materials and Energy Sciences, SLAC National Accelerator Laboratory, Menlo Park, California 94025 (United States); Stanford PULSE Institute, SLAC National Accelerator Laboratory, Menlo Park, California 94025 (United States); Department of Photon Science and Applied Physics, Stanford University, Stanford, California 94305 (United States); Andrea Artioli, Gianluca; Malavasi, Lorenzo [Dipartimento di Chimica, Sezione di Chimica Fisica, INSTM (UdR Pavia), Università di Pavia, Viale Taramelli 16, 27100 Pavia (Italy)

    2014-01-13

    We combine ultrafast pump-probe spectroscopy with a diamond-anvil cell to decouple the insulator-metal electronic transition from the lattice symmetry changing structural transition in the archetypal strongly correlated material vanadium dioxide. Coherent phonon spectroscopy enables tracking of the photo-excited phonon vibrational frequencies of the low temperature, monoclinic (M{sub 1})-insulating phase that transforms into the metallic, tetragonal rutile structured phase at high temperature or via non-thermal photo-excitations. We find that in contrast with ambient pressure experiments where strong photo-excitation promptly induces the electronic transition along with changes in the lattice symmetry, at high pressure, the coherent phonons of the monoclinic (M{sub 1}) phase are still clearly observed upon the photo-driven phase transition to a metallic state. These results demonstrate the possibility of synthesizing and studying transient phases under extreme conditions.

  1. Appraisal of the realistic accuracy of molecular dynamics of high-pressure hydrogen

    Directory of Open Access Journals (Sweden)

    Graeme J. Ackland

    2015-12-01

    Full Text Available Molecular dynamics (MD is a powerful method for studying the behaviour of materials at high temperature. In practice, however, its effectiveness in representing real systems is limited by the accuracy of the forces, finite size effects, quantization and equilibration methods. In this paper, we report and discuss some calculations carried out using MD on high-pressure hydrogen, reviewing a number of sources of error, of which the neglect of zero-point vibrations is quantitatively the largest. We show that simulations using ab initio MD with the PBE functional predict a large stability field for the molecular Cmca4 structure at pressures just above those achieved in current experiments above the stability range of the mixed molecular layered Phase IV. However, the various errors in the simulation all point towards a much smaller stability range, and the likelihood of a non-molecular phase based on low-coordination networks or chains of atoms.

  2. High-Temperature Shape Memory Polymers

    Science.gov (United States)

    Yoonessi, Mitra; Weiss, Robert A.

    2012-01-01

    physical conformation changes when exposed to an external stimulus, such as a change in temperature. Such materials have a permanent shape, but can be reshaped above a critical temperature and fixed into a temporary shape when cooled under stress to below the critical temperature. When reheated above the critical temperature (Tc, also sometimes called the triggering or switching temperature), the materials revert to the permanent shape. The current innovation involves a chemically treated (sulfonated, carboxylated, phosphonated, or other polar function group), high-temperature, semicrystalline thermoplastic poly(ether ether ketone) (Tg .140 C, Tm = 340 C) mix containing organometallic complexes (Zn++, Li+, or other metal, ammonium, or phosphonium salts), or high-temperature ionic liquids (e.g. hexafluorosilicate salt with 1-propyl-3- methyl imidazolium, Tm = 210 C) to form a network where dipolar or ionic interactions between the polymer and the low-molecular-weight or inorganic compound forms a complex that provides a physical crosslink. Hereafter, these compounds will be referred to as "additives". The polymer is semicrystalline, and the high-melt-point crystals provide a temporary crosslink that acts as a permanent crosslink just so long as the melting temperature is not exceeded. In this example case, the melting point is .340 C, and the shape memory critical temperature is between 150 and 250 C. PEEK is an engineering thermoplastic with a high Young fs modulus, nominally 3.6 GPa. An important aspect of the invention is the control of the PEEK functionalization (in this example, the sulfonation degree), and the thermal properties (i.e. melting point) of the additive, which determines the switching temperature. Because the compound is thermoplastic, it can be formed into the "permanent" shape by conventional plastics processing operations. In addition, the compound may be covalently cross - linked after forming the permanent shape by S-PEEK by applying ionizing

  3. Electrochemical high-temperature gas sensors

    Science.gov (United States)

    Saruhan, B.; Stranzenbach, M.; Yüce, A.; Gönüllü, Y.

    2012-06-01

    Combustion produced common air pollutant, NOx associates with greenhouse effects. Its high temperature detection is essential for protection of nature. Component-integration capable high-temperature sensors enable the control of combustion products. The requirements are quantitative detection of total NOx and high selectivity at temperatures above 500°C. This study reports various approaches to detect NO and NO2 selectively under lean and humid conditions at temperatures from 300°C to 800°C. All tested electrochemical sensors were fabricated in planar design to enable componentintegration. We suggest first an impedance-metric gas sensor for total NOx-detection consisting of NiO- or NiCr2O4-SE and PYSZ-electrolyte. The electrolyte-layer is about 200μm thickness and constructed of quasi-single crystalline columns. The sensing-electrode (SE) is magnetron sputtered thin-layers of NiO or NiCr2O4. Sensor sensitivity for detection of total NOx has been measured by applying impedance analysis. The cross-sensitivity to other emission gases such as CO, CO2, CH4 and oxygen (5 vol.%) has been determined under 0-1000ppm NO. Sensor maintains its high sensitivity at temperatures up to 550°C and 600°C, depending on the sensing-electrode. NiO-SE yields better selectivity to NO in the presence of oxygen and have shorter response times comparing to NiCr2O4-SE. For higher temperature NO2-sensing capability, a resistive DC-sensor having Al-doped TiO2-sensing layers has been employed. Sensor-sensitivity towards NO2 and cross-sensitivity to CO has been determined in the presence of H2O at temperatures 600°C and 800°C. NO2 concentrations varying from 25 to 100ppm and CO concentrations from 25 to 75ppm can be detected. By nano-tubular structuring of TiO2, NO2 sensitivity of the sensor was increased.

  4. High temperature deformation mechanisms of L12-containing Co-based superalloys

    Science.gov (United States)

    Titus, Michael Shaw

    Ni-based superalloys have been used as the structural material of choice for high temperature applications in gas turbine engines since the 1940s, but their operating temperature is becoming limited by their melting temperature (Tm =1300degrees C). Despite decades of research, no viable alternatives to Ni-based superalloys have been discovered and developed. However, in 2006, a ternary gamma' phase was discovered in the Co-Al-W system that enabled a new class of Co-based superalloys to be developed. These new Co-based superalloys possess a gamma-gamma' microstructure that is nearly identical to Ni-based superalloys, which enables these superalloys to achieve extraordinary high temperature mechanical properties. Furthermore, Co-based alloys possess the added benefit of exhibiting a melting temperature of at least 100degrees C higher than commercial Ni-based superalloys. Superalloys used as the structural materials in high pressure turbine blades must withstand large thermomechanical stresses imparted from the rotating disk and hot, corrosive gases present. These stresses induce time-dependent plastic deformation, which is commonly known as creep, and new superalloys must possess adequate creep resistance over a broad range of temperature in order to be used as the structural materials for high pressure turbine blades. For these reasons, this research focuses on quantifying high temperature creep properties of new gamma'-containing Co-based superalloys and identifying the high temperature creep deformation mechanisms. The high temperature creep properties of new Co- and CoNi-based alloys were found to be comparable to Ni-based superalloys with respect to minimum creep rates and creep-rupture lives at 900degrees C up to the solvus temperature of the gamma' phase. Co-based alloys exhibited a propensity for extended superlattice stacking fault formation in the gamma' precipitates resulting from dislocation shearing events. When Ni was added to the Co-based compositions

  5. Impact of high-pressure coolant supply on chip formation in milling

    Science.gov (United States)

    Klocke, F.; Döbbeler, B.; Lakner, T.

    2017-10-01

    Machining of titanium alloys is considered as difficult, because of their high temperature strength, low thermal conductivity and low E-modulus, which contributes to high mechanical loads and high temperatures in the contact zone between tool and workpiece. The generated heat in the cutting zone can be dissipated only in a low extent. When cutting steel materials, up to 75% of the process heat is transported away by the chips, contrary to only 25% when machining titanium alloys. As a result, the cutting tool heats up, which leads to high tool wear. Therefore, machining of titanium alloys is only possible with relatively low cutting speeds. This leads to low levels of productivity for milling processes with titanium alloys. One way to increase productivity is to use more cutting edges in tools with the same diameter. However, the limiting factor of adding more cutting edges to a milling tool is the minimum size of the chip spaces, which are sufficient for a stable chip evacuation. This paper presents experimental results on the chip formation and chip size influenced by high-pressure coolant supply, which can lead to smaller chips and to smaller sizes of the chip spaces, respectively. Both influences, the pressure of the supplied coolant and the volumetric flow rate were individually examined. Alpha-beta annealed titanium TiAl6V4 was examined in relation to the reference material quenched and tempered steel 42CrMo4+QT (AISI 4140+QT). The work shows that with proper chip control due to high-pressure coolant supply in milling, the number of cutting edges on the same diameter tool can be increased, which leads to improved productivity.

  6. High-temperature archeointensity measurements from Mesopotamia

    Science.gov (United States)

    Gallet, Yves; Le Goff, Maxime

    2006-01-01

    We present new archeointensity results obtained from 127 potsherds and baked brick fragments dated from the last four millennia BC which were collected from different Syrian archeological excavations. High temperature magnetization measurements were carried out using a laboratory-built triaxial vibrating sample magnetometer (Triaxe), and ancient field intensity determinations were derived from the experimental procedure described by Le Goff and Gallet [Le Goff and Gallet. Earth Planet. Sci. Lett. 229 (2004) 31-43]. As some of the studied samples were previously analyzed using the classical Thellier and Thellier [Thellier and Thellier . Ann. Geophys. 15 (1959) 285-376] method revised by Coe [Coe. J. Geophys. Res. 72 (1967) 3247-3262], a comparison of the results is made from the two methods. The differences both at the fragment and site levels are mostly within ± 5%, which strengthens the validity of the experimental procedure developed for the Triaxe. The new data help to better constrain the geomagnetic field intensity variations in Mesopotamia during archeological times, with the probable occurrence of an archeomagnetic jerk around 2800-2600 BC.

  7. Energy storage via high temperature superconductivity (SMES)

    Energy Technology Data Exchange (ETDEWEB)

    Mikkonen, R. [Tampere Univ. of Technology (Finland)

    1998-10-01

    The technology concerning high temperature superconductors (HTS) is matured to enabling different kind of prototype applications including SMES. Nowadays when speaking about HTS systems, attention is focused on the operating temperature of 20-30 K, where the critical current and flux density are fairly close to 4.2 K values. In addition by defining the ratio of the energy content of a novel HTS magnetic system and the required power to keep the system at the desired temperature, the optimum settles to the above mentioned temperature range. In the frame of these viewpoints a 5 kJ HTS SMES system has been designed and tested at Tampere University of Technology with a coil manufactured by American Superconductor (AMSC). The HTS magnet has inside and outside diameters of 252 mm and 317 mm, respectively and axial length of 66 mm. It operates at 160 A and carries a total of 160 kA-turns to store the required amount of energy. The effective magnetic inductance is 0.4 H and the peak axial field is 1.7 T. The magnet is cooled to the operating temperature of 20 K with a two stage Gifford-McMahon type cryocooler with a cooling power of 60 W at 77 K and 8 W at 20 K. The magnetic system has been demonstrated to compensate a short term loss of power of a sensitive consumer

  8. High-temperature enzymatic breakdown of cellulose.

    Science.gov (United States)

    Wang, Hongliang; Squina, Fabio; Segato, Fernando; Mort, Andrew; Lee, David; Pappan, Kirk; Prade, Rolf

    2011-08-01

    Cellulose is an abundant and renewable biopolymer that can be used for biofuel generation; however, structural entrapment with other cell wall components hinders enzyme-substrate interactions, a key bottleneck for ethanol production. Biomass is routinely subjected to treatments that facilitate cellulase-cellulose contacts. Cellulases and glucosidases act by hydrolyzing glycosidic bonds of linear glucose β-1,4-linked polymers, producing glucose. Here we describe eight high-temperature-operating cellulases (TCel enzymes) identified from a survey of thermobacterial and archaeal genomes. Three TCel enzymes preferentially hydrolyzed soluble cellulose, while two preferred insoluble cellulose such as cotton linters and filter paper. TCel enzymes had temperature optima ranging from 85°C to 102°C. TCel enzymes were stable, retaining 80% of initial activity after 120 h at 85°C. Two modes of cellulose breakdown, i.e., with endo- and exo-acting glucanases, were detected, and with two-enzyme combinations at 85°C, synergistic cellulase activity was observed for some enzyme combinations.

  9. High temperature deformation of silicon steel

    Energy Technology Data Exchange (ETDEWEB)

    Rodriguez-Calvillo, Pablo, E-mail: pablo.rodriguez@ctm.com.es [CTM - Technologic Centre, Materials Technology Area, Manresa, Cataluna (Spain); Department of Materials Science and Metallurgical Engineering, Universidad Politecnica de Cataluna, Barcelona (Spain); Houbaert, Yvan, E-mail: Yvan.Houbaert@UGent.be [Department of Materials Science and Engineering, University of Ghent (Belgium); Petrov, Roumen, E-mail: Roumen.Petrov@ugent.be [Department of Materials Science and Engineering, University of Ghent (Belgium); Kestens, Leo, E-mail: Leo.kestens@ugent.be [Department of Materials Science and Engineering, University of Ghent (Belgium); Colas, Rafael, E-mail: rafael.colas@uanl.edu.mx [Facultad de Ingenieria Mecanica y Electrica, Universidad Autonoma de Nuevo Leon (Mexico); Centro de Innovacion, Investigacion y Desarrollo en Ingenieria y Tecnologia, Universidad Autonoma de Nuevo Leon (Mexico)

    2012-10-15

    The microstructure and texture development during high temperature plane strain compression of 2% in weight silicon steel was studied. The tests were carried out at a constant strain rate of 5 s{sup -1} with reductions of 25, 35 and 75% at temperatures varying from 800 to 1100 Degree-Sign C. The changes in microstructure and texture were studied by means of scanning electron microscopy and electron backscattered diffraction. The microstructure close to the surface of the samples was equiaxed, which is attributed to the shear caused by friction, whereas that at the centre of the specimens was made of a mixture of elongated and fine equiaxed grains, the last ones attributed to the action of dynamic recovery followed by recrystallization. It was found that the volume fraction of these equiaxed grains augmented as reduction and temperature increased; a 0.7 volume fraction was accomplished with a 75% reduction at 1100 Degree-Sign C. The texture of the equiaxed and elongated grains was found to vary with the increase of deformation and temperature, as the {gamma}-fibre tends to disappear and the {alpha}-fibre to increase towards the higher temperature range. -- Highlights: Black-Right-Pointing-Pointer The plastic deformation of a silicon containing steel is studied by plane strain compression. Black-Right-Pointing-Pointer Equiaxed and elongated grains develop in different regions of the sample due to recrystallization. Black-Right-Pointing-Pointer Texture, by EBSD, is revealed to be similar in either type of grains.

  10. Fiber Bragg Grating Filter High Temperature Sensors

    Science.gov (United States)

    Lyons, Donald R.; Brass, Eric D.; Pencil, Eric (Technical Monitor)

    2001-01-01

    We present a scaled-down method for determining high temperatures using fiber-based Bragg gratings. Bragg gratings are distributed along the length of the optical fiber, and have high reflectivities whenever the optical wavelength is twice the grating spacing. These spatially distinct Bragg regions (located in the core of a fiber) are sensitive to local temperature changes. Since these fibers are silica-based they are easily affected by localized changes in temperature, which results in changes to both the grating spacing and the wavelength reflectivity. We exploit the shift in wavelength reflectivity to measure the change in the local temperature. Note that the Bragg region (sensing area) is some distance away from where the temperature is being measured. This is done so that we can measure temperatures that are much higher than the damage threshold of the fiber. We do this by affixing the fiber with the Bragg sensor to a material with a well-known coefficient of thermal expansion, and model the heat gradient from the region of interest to the actual sensor. The research described in this paper will culminate in a working device as well as be the second portion of a publication pending submission to Optics Letters.

  11. Electronic phase separation and high temperature superconductors

    Energy Technology Data Exchange (ETDEWEB)

    Kivelson, S.A. [Univ. of California, Los Angeles, CA (United States). Dept. of Physics; Emery, V.J. [Brookhaven National Lab., Upton, NY (United States)

    1994-01-11

    The authors review the extensive evidence from model calculations that neutral holes in an antiferromagnet separate into hole-rich and hole-poor phases. All known solvable limits of models of holes in a Heisenberg antiferromagnet exhibit this behavior. The authors show that when the phase separation is frustrated by the introduction of long-range Coulomb interactions, the typical consequence is either a modulated (charge density wave) state or a superconducting phase. The authors then review some of the strong experimental evidence supporting an electronically-driven phase separation of the holes in the cuprate superconductors and the related Ni oxides. Finally, the authors argue that frustrated phase separation in these materials can account for many of the anomalous normal state properties of the high temperature superconductors and provide the mechanism of superconductivity. In particular, it is shown that the T-linear resistivity of the normal state is a paraconductivity associated with a novel composite pairing, although the ordered superconducting state is more conventional.

  12. High temperature superconductors in electromagnetic applications

    CERN Document Server

    Richens, P E

    2000-01-01

    powder-in-tube and dip-coated, have been made using a novel single loop tensometer that enables the insertion of a reasonably long length of conductor into the bore of a high-field magnet. The design, construction, and characterization of a High Temperature Superconducting (HTS) magnet is described. The design stage has involved the development of computer software for the calculation of the critical current of a solenoid wound from anisotropic HTS conductor. This calculation can be performed for a variety of problems including those involving magnetic materials such as iron by the incorporation of finite element electromagnetic analysis software. This has enabled the optimization of the magnet's performance. The HTS magnet is wound from 190 m of silver-matrix Bi sub 2 Sr sub 2 Ca sub 2 Cu sub 3 O sub 1 sub 0 powder-in-tube tape conductor supplied by Intermagnetics General Corporation. The dimensions are 70 mm bore and 70 mm length, and it consists of 728 turns. Iron end-plates were utilized in order to reduc...

  13. High temperature superconductors at optimal doping

    Directory of Open Access Journals (Sweden)

    W. E. Pickett

    2006-09-01

    Full Text Available   Intensive study of the high temperature superconductors has been ongoing for two decades. A great deal of this effort has been devoted to the underdoped regime, where the new and difficult physics of the doped Mott insulator has met extra complications including bilayer coupling/splitting, shadow bands, and hot spots. While these complications continue to unfold, in this short overview the focus is moved to the region of actual high-Tc, that of optimal doping. The focus here also is not on the superconducting state itself, but primarily on the characteristics of the normal state from which the superconducting instability arises, and even these can be given only a broad-brush description. A reminder is given of two issues,(i why the “optimal Tc” varies,for n-layered systems it increases for n up to 3, then decreases for a given n, Tc increases according to the ‘basis’ atom in the order Bi, Tl, Hg (ii how does pressure, or a particular uniaxial strain, increase Tc when the zero-strain system is already optimally doped?

  14. High temperature and pressure alkaline electrolysis

    DEFF Research Database (Denmark)

    Allebrod, Frank; Chatzichristodoulou, Christodoulos; Mogensen, Mogens Bjerg

    2013-01-01

    for immobilization of aqueous KOH solutions. Electrolysis cells with this electrolyte and metal foam based gas diffusion electrodes were successfully demonstrated at temperatures up to 250 °C at 40 bar. Different electro-catalysts were tested in order to reduce the oxygen and hydrogen overpotentials. Current...... the operational temperature and pressure to produce pressurized hydrogen at high rate (m3 H2·h-1·m-2 cell area) and high electrical efficiency. This work describes an exploratory technical study of the possibility to produce hydrogen and oxygen with a new type of alkaline electrolysis cell at high temperatures...... densities of 1.1 A cm-2 and 2.3 A cm-2 have been measured at a cell voltage of 1.5 V and 1.75 V, respectively, without noble metal catalysts. Electrical efficiencies of almost 99 % at 1.1 A cm-2 and 85 % at 2.3 A cm-2 were obtained....

  15. High Temperature Fatigue Life Evaluation Using Small Specimen

    National Research Council Canada - National Science Library

    NOGAMI, Shuhei; HISAKA, Chiaki; FUJIWARA, Masaharu; WAKAI, Eichi; HASEGAWA, Akira

    2017-01-01

    For developing the high temperature fatigue life evaluation method using small specimen, the effect of specimen size and test environment on the high temperature fatigue life of the reduced activation...

  16. Blueberry polyphenol oxidase: Characterization and the kinetics of thermal and high pressure activation and inactivation.

    Science.gov (United States)

    Terefe, Netsanet Shiferaw; Delon, Antoine; Buckow, Roman; Versteeg, Cornelis

    2015-12-01

    Partially purified blueberry polyphenol oxidase (PPO) in Mcllvaine buffer (pH=3.6, typical pH of blueberry juice) was subjected to processing at isothermal-isobaric conditions at temperatures from 30 to 80 °C and pressure from 0.1 to 700 MPa. High pressure processing at 30-50 °C at all pressures studied caused irreversible PPO activity increase with a maximum of 6.1 fold increase at 500 MPa and 30 °C. Treatments at mild pressure-mild temperature conditions (0.1-400 MPa, 60 °C) also caused up to 3 fold PPO activity increase. Initial activity increase followed by a decrease occurred at relatively high pressure-mild temperature (400-600 MPa, 60 °C) and mild pressure-high temperature (0.1-400 MPa, 70-80 °C) combinations. At temperatures higher than 76 °C, monotonic decrease in PPO activity occurred at 0.1 MPa and pressures higher than 500 MPa. The activation/inactivation kinetics of the enzyme was successfully modelled assuming consecutive reactions in series with activation followed by inactivation. Crown Copyright © 2015. Published by Elsevier Ltd. All rights reserved.

  17. Entropy theory of metamorphic transitions in coals

    Energy Technology Data Exchange (ETDEWEB)

    Novgorodova, M.I.; Gutan, Y.M.; Losev, N.F.; Moshchenko, I.N. [Russian Academy of Sciences, Moscow (Russian Federation). Fersman Mineral Museum

    2000-07-01

    The paper proposes a model of metamorphic phase transition in coals that explains the change of the superionic conduction of coals at early stages of metamorphism by the electronic conductivity of anthracites. The model is based on a concept of quasiplane fragments of aromatic rings, the main component of microstructure of coals, the percolation approximation for determining the carbon concentration responsible for the formation of infinite clusters of aromatic rings, and the Lichtenecker approximation for determining the conductivity of the object coal substance + rock.

  18. Recent advances in high pressure neutron scattering at the Spallation Neutron Source at Oak Ridge National Laboratory

    Science.gov (United States)

    Tulk, C.; dos Santos, A.; Klug, D.; Guthrie, M.; Machida, S.; Molaison, J.

    2012-12-01

    There have been significant improvements in the operation of the high pressure diffractometer, SNAP, at the Spallation Neutron Source over the past two years. This talk will highlight the current capacities which include low temperature systems, high temperature systems, and the introduction of new pressure cell technology that is based on supported diamond anvils and, with advances in software, is particularly suited for powder diffraction. Specific examples of our recent research will focus on high pressure transitions in hydrogen bonded systems such as methane and CO2 hydrate. The high pressure hexagonal phase of methane hydrate is studied to determine the nature of the hydrate cage loading, this provides detailed experimental data that will lead to better intermolecular potentials for methane - methane interactions, particularly when methane molecules are in close contact and strongly repelling. The high pressure structural systematics of carbon dioxide hydrate is reported. While the structural transformation sequence of most hydrates progress from sI (or sII) to the hexagonal form then to a flied ice structure, CO2 hydrate is an example of a system that skips the hexagonal phase and transforms directly into the filled ice structure. Finally examples of using SNAP to study disorder in amorphous systems will be given. Particularly amorphous vapor co-deposits of water, known as amorphous solid water, and clathrate forming molecules such as CO2, and the structural response of these systems to increased pressure at low temperature.

  19. Quantitative Imaging of Turbulent Mixing Dynamics in High-Pressure Fuel Injection to Enable Predictive Simulations of Engine Combustion

    Energy Technology Data Exchange (ETDEWEB)

    Frank, Jonathan H. [Sandia National Lab. (SNL-CA), Livermore, CA (United States). Reacting Flows Dept.; Pickett, Lyle M. [Sandia National Lab. (SNL-CA), Livermore, CA (United States). Engine Combustion Dept.; Bisson, Scott E. [Sandia National Lab. (SNL-CA), Livermore, CA (United States). Remote Sensing and Energetic Materials Dept.; Patterson, Brian D. [Sandia National Lab. (SNL-CA), Livermore, CA (United States). combustion Chemistry Dept.; Ruggles, Adam J. [Sandia National Lab. (SNL-CA), Livermore, CA (United States). Reacting Flows Dept.; Skeen, Scott A. [Sandia National Lab. (SNL-CA), Livermore, CA (United States). Engine Combustion Dept.; Manin, Julien Luc [Sandia National Lab. (SNL-CA), Livermore, CA (United States). Engine Combustion Dept.; Huang, Erxiong [Sandia National Lab. (SNL-CA), Livermore, CA (United States). Reacting Flows Dept.; Cicone, Dave J. [Sandia National Lab. (SNL-CA), Livermore, CA (United States). Engine Combustion Dept.; Sphicas, Panos [Sandia National Lab. (SNL-CA), Livermore, CA (United States). Engine Combustion Dept.

    2015-09-01

    In this LDRD project, we developed a capability for quantitative high - speed imaging measurements of high - pressure fuel injection dynamics to advance understanding of turbulent mixing in transcritical flows, ignition, and flame stabilization mechanisms, and to provide e ssential validation data for developing predictive tools for engine combustion simulations. Advanced, fuel - efficient engine technologies rely on fuel injection into a high - pressure, high - temperature environment for mixture preparation and com bustion. Howe ver, the dynamics of fuel injection are not well understood and pose significant experimental and modeling challenges. To address the need for quantitative high - speed measurements, we developed a Nd:YAG laser that provides a 5ms burst of pulses at 100 kHz o n a robust mobile platform . Using this laser, we demonstrated s patially and temporally resolved Rayleigh scattering imaging and particle image velocimetry measurements of turbulent mixing in high - pressure gas - phase flows and vaporizing sprays . Quantitativ e interpretation of high - pressure measurements was advanced by reducing and correcting interferences and imaging artifacts.

  20. Underground storage systems for high-pressure air and gases

    Science.gov (United States)

    Beam, B. H.; Giovannetti, A.

    1975-01-01

    This paper is a discussion of the safety and cost of underground high-pressure air and gas storage systems based on recent experience with a high-pressure air system installed at Moffett Field, California. The system described used threaded and coupled oil well casings installed vertically to a depth of 1200 ft. Maximum pressure was 3000 psi and capacity was 500,000 lb of air. A failure mode analysis is presented, and it is shown that underground storage offers advantages in avoiding catastrophic consequences from pressure vessel failure. Certain problems such as corrosion, fatigue, and electrolysis are discussed in terms of the economic life of such vessels. A cost analysis shows that where favorable drilling conditions exist, the cost of underground high-pressure storage is approximately one-quarter that of equivalent aboveground storage.