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Sample records for high temperature thermal

  1. Thermal conductivity in high critical temperature superconductors

    International Nuclear Information System (INIS)

    Castello, D.J.

    1990-01-01

    A measuring procedure to obtain the electrical resistivity, thermal conductivity and thermoelectric power of samples of low conductivity has been developed. The setup was designed to allow the removal of the sample in clean fashion, so that further heat treatments could be performed, and therefore no adhesives were used in the mounting of the thermocouples or heat sinks, etc. The heat equation has been analyzed with time-dependent boundary conditions, with the purpose of developing a dynamic measuring method which avoids the long delays involved in reaching thermal equilibrium above 30K. Based on this analysis, the developed measuring method allows a precise and reliable measurements, in a continuous fashion, for temperatures above 25K. The same setup is used in a stationary mode at low temperatures, so the sample needs to be mounted only once. κ(T) has been measured in two ceramic samples of La 2 CuO 4 : the first semiconducting, the other superconducting (SC) as a consequence of an oxygen annealing. Both exhibit a strong thermal resistivity due to defects, though lower in the SC, where two maxima are observed and are attributed to an AF ordering: T N ' ≅ 40K and T N '' ≅ 240K. The low temperature dependence is T 1 .6 and T 2 .3 respectively. It was interpreted that the former sample presents a greater dispersion due to localized excitations, characteristic of amorphouus materials, 'tunneling two-level systems' (TS). A third syntherized sample of CuO exhibits a typical behaviour of an insulator, with T 2 .6 at low temperatures, a maximum at 40K and a decrease in T -1 at high temperatures. κ(T) in a SC sample of La 1 .85Sr 1 .15CuO 4 with T c =35.5K has also been measured, observing a small increase below T c because of the diminishing of the phonon dispersion due to the condensating electrons. κ(T) is lower than in the previous samples and thus a greater number of defects was inferred. At low temperatures, its dependence is T 1 .4 in agreement with the

  2. Thermal insulation of high temperature reactors

    International Nuclear Information System (INIS)

    Cornille, Y.

    1975-01-01

    Operating conditions of HTR thermal insulation are given and heat insulators currently developed are described (fibers kept in position by metallic structures). For future applications and higher temperatures, research is directed towards solutions using ceramics or associating fibers and ceramics [fr

  3. High Temperature Fiberoptic Thermal Imaging System, Phase I

    Data.gov (United States)

    National Aeronautics and Space Administration — The proposed Phase 1 program will fabricate and demonstrate a small diameter single fiber endoscope that can perform high temperature thermal imaging in a jet engine...

  4. High-Temperature Thermal Diffusivity Measurements of Silicate Glasses

    Science.gov (United States)

    Pertermann, M.; Hofmeister, A. M.; Whittington, A. G.; Spera, F. J.; Zayac, J.

    2005-12-01

    Transport of heat in geologically relevant materials is of great interest because of its key role in heat transport, magmatism and volcanic activity on Earth. To better understand the thermal properties of magmatic materials at high temperatures, we measured the thermal diffusivity of four synthetic end-member silicate glasses with the following compositions: albite (NaAlSi3O8), orthoclase (KAlSi3O8), anorthite (CaAl2Si2O8), and diopside (CaMgSi2O6). Thermal diffusivity measurements were conducted with the laser-flash technique and data were acquired from room temperature to a maximum temperature near 1100°C, depending on the glass transition temperature. The presence of sub-mm sized bubbles in one of the orthoclase samples had no discernable effect on measured diffusivities. At room temperature, the three feldspar-type glasses have thermal diffusivity (D) values of 0.58-0.61 mm2/s, whereas the diopside glass has 0.52 mm2/s. With increasing temperature, D decreases by 5-10% (relative) for all samples and becomes virtually constant at intermediate temperatures. At higher temperatures, the anorthite and diopside glasses exhibit significant drops in thermal diffusivity over a 50-100°C interval, correlating with previously published heat capacity changes near the glass transition for these compositions. For anorthite, D (in mm2/s) decreases from 0.48 at 750-860°C to 0.36 at 975-1075°C; for diopside, D changes from 0.42 at 630-750°C to 0.30 at 850-910°C, corresponding to relative drops of 24 and 29%, respectively. Albite and orthoclase glasses do not exhibit this change and also lack significant changes in heat capacity near the glass transition. Instead, D is constant at 400-800°C for albite, and for orthoclase values go through a minimum at 500-600°C before increasing slightly towards 1100°C but it never exceeds the room temperature D. Our data on thermal diffusivity correlate closely with other thermophysical properties. Thus, at least in case of simple

  5. Fiber Bragg Gratings for High-Temperature Thermal Characterization

    International Nuclear Information System (INIS)

    Stinson-Bagby, Kelly L.; Fielder, Robert S.

    2004-01-01

    Fiber Bragg grating (FBG) sensors were used as a characterization tool to study the SAFE-100 thermal simulator at the Nasa Marshal Space Flight Center. The motivation for this work was to support Nasa space nuclear power initiatives through the development of advanced fiber optic sensors for space-based nuclear power applications. Distributed high temperature measurements, up to 1150 deg. C, were made with FBG temperature sensors. Additionally, FBG strain measurements were taken at elevated temperatures to provide a strain profile of the core during operation. This paper will discuss the contribution of these measurements to meet the goals of Nasa Marshall Space Flight Center's Propulsion Research Center. (authors)

  6. Thermal analysis of high temperature phase transformations of steel

    Directory of Open Access Journals (Sweden)

    K. Gryc

    2013-10-01

    Full Text Available The series of thermal analysis measurements of high temperature phase transformations of real grain oriented electrical steel grade under conditions of two analytical devices (Netzsch STA 449 F3 Jupiter; Setaram SETSYS 18TM were carried out. Two thermo analytical methods were used (DTA and Direct thermal analysis. The different weight of samples was used (200 mg, 23 g. The stability/reproducibility of results obtained by used methodologies was verified. The liquidus and solidus temperatures for close to equilibrium conditions and during cooling (20 °C/min; 80 °C/min were determined. It has been shown that the higher cooling rate lead to lower temperatures for start and end of solidification process of studied steel grade.

  7. High temperature underground thermal energy storage system for solar energy

    Science.gov (United States)

    Collins, R. E.

    1980-01-01

    The activities feasibility of high temperature underground thermal storage of energy was investigated. Results indicate that salt cavern storage of hot oil is both technically and economically feasible as a method of storing huge quantities of heat at relatively low cost. One particular system identified utilizes a gravel filled cavern leached within a salt dome. Thermal losses are shown to be less than one percent of cyclically transferred heat. A system like this having a 40 MW sub t transfer rate capability and over eight hours of storage capacity is shown to cost about $13.50 per KWh sub t.

  8. High temperature solar thermal technology: The North Africa Market

    Energy Technology Data Exchange (ETDEWEB)

    1990-12-01

    High temperature solar thermal (HTST) technology offers an attractive option for both industrialized and non-industrialized countries to generate electricity and industrial process steam. The purpose of this report is to assess the potential market for solar thermal applications in the North African countries of Algeria, Egypt, Morocco and Tunisia. North Africa was selected because of its outstanding solar resource base and the variety of applications to be found there. Diminishing oil and gas resources, coupled with expanding energy needs, opens a large potential market for the US industry. The US high temperature solar trough industry has little competition globally and could build a large market in these areas. The US is already familiar with certain solar markets in North Africa due to the supplying of substantial quantities of US-manufactured flat plate collectors to this region.

  9. Positron annihilation in germanium in thermal equilibrium at high temperature

    Energy Technology Data Exchange (ETDEWEB)

    Uedono, Akira; Moriya, Tsuyoshi; Komuro, Naoyuki; Tanigawa, Shoichiro [Tsukuba Univ., Ibaraki (Japan). Inst. of Materials Science; Kawano, Takao; Ikari, Atsushi

    1996-09-01

    Annihilation characteristics of positrons in Ge in thermal equilibrium at high temperature were studied using a monoenergetic positron beam. Precise measurements of Doppler broadening profiles of annihilation radiation were performed in the temperature range between 300 K and 1211 K. The line shape parameters of Doppler broadening profiles were found to be almost constant at 300-600 K. The changes in these parameters were observed to start above 600 K. This was attributed to both the decrease in the fraction of positrons annihilating with core electrons and the lowering of the crystal symmetry around the region detected by positron-electron pairs. This suggests that behaviors of positrons are dominated by some form of positron-lattice coupling in Ge at high temperatures. The temperature dependence of the diffusion length of positrons was also discussed. (author)

  10. Thermal Protective Coating for High Temperature Polymer Composites

    Science.gov (United States)

    Barron, Andrew R.

    1999-01-01

    The central theme of this research is the application of carboxylate-alumoxane nanoparticles as precursors to thermally protective coatings for high temperature polymer composites. In addition, we will investigate the application of carboxylate-alumoxane nanoparticle as a component to polymer composites. The objective of this research was the high temperature protection of polymer composites via novel chemistry. The significance of this research is the development of a low cost and highly flexible synthetic methodology, with a compatible processing technique, for the fabrication of high temperature polymer composites. We proposed to accomplish this broad goal through the use of a class of ceramic precursor material, alumoxanes. Alumoxanes are nano-particles with a boehmite-like structure and an organic periphery. The technical goals of this program are to prepare and evaluate water soluble carboxylate-alumoxane for the preparation of ceramic coatings on polymer substrates. Our proposed approach is attractive since proof of concept has been demonstrated under the NRA 96-LeRC-1 Technology for Advanced High Temperature Gas Turbine Engines, HITEMP Program. For example, carbon and Kevlar(tm) fibers and matting have been successfully coated with ceramic thermally protective layers.

  11. Simultaneous reconstruction of thermal degradation properties for anisotropic scattering fibrous insulation after high temperature thermal exposures

    International Nuclear Information System (INIS)

    Zhao, Shuyuan; Zhang, Wenjiao; He, Xiaodong; Li, Jianjun; Yao, Yongtao; Lin, Xiu

    2015-01-01

    To probe thermal degradation behavior of fibrous insulation for long-term service, an inverse analysis model was developed to simultaneously reconstruct thermal degradation properties of fibers after thermal exposures from the experimental thermal response data, by using the measured infrared spectral transmittance and X-ray phase analysis data as direct inputs. To take into account the possible influence of fibers degradation after thermal exposure on the conduction heat transfer, we introduced a new parameter in the thermal conductivity model. The effect of microstructures on the thermal degradation parameters was evaluated. It was found that after high temperature thermal exposure the decay rate of the radiation intensity passing through the material was weakened, and the probability of being scattered decreased during the photons traveling in the medium. The fibrous medium scattered more radiation into the forward directions. The shortened heat transfer path due to possible mechanical degradation, along with the enhancement of mean free path of phonon scattering as devitrification after severe heat treatment, made the coupled solid/gas thermal conductivities increase with the rise of heat treatment temperature. - Highlights: • A new model is developed to probe conductive and radiative properties degradation of fibers. • To characterize mechanical degradation, a new parameter is introduced in the model. • Thermal degradation properties are reconstructed from experiments by L–M algorithm. • The effect of microstructures on the thermal degradation parameters is evaluated. • The analysis provides a powerful tool to quantify thermal degradation of fiber medium

  12. High temperature ductility of austenitic alloys exposed to thermal neutrons

    International Nuclear Information System (INIS)

    Watanabe, K.; Kondo, T.; Ogawa, Y.

    1982-01-01

    Loss of high temperature ductility due to thermal neutron irradiation was examined by slow strain rate test in vacuum up to 1000 0 C. The results on two heats of Hastelloy alloy X with different boron contents were analyzed with respect to the influence of the temperatures of irradiation and tensile tests, neutron fluence and the associated helium production due to nuclear transmutation reaction. The loss of ductility was enhanced by increasing either temperature or neutron fluence. Simple extrapolations yielded the estimated threshold fluence and the end-of-life ductility values at 900 and 1000 0 C in case where the materials were used in near-core regions of VHTR. The observed relationship between Ni content and the ductility loss has suggested a potential utilization of Fe-based alloys for seathing of the neutron absorber materials

  13. Fabrication of High Temperature Cermet Materials for Nuclear Thermal Propulsion

    Science.gov (United States)

    Hickman, Robert; Panda, Binayak; Shah, Sandeep

    2005-01-01

    Processing techniques are being developed to fabricate refractory metal and ceramic cermet materials for Nuclear Thermal Propulsion (NTP). Significant advances have been made in the area of high-temperature cermet fuel processing since RoverNERVA. Cermet materials offer several advantages such as retention of fission products and fuels, thermal shock resistance, hydrogen compatibility, high conductivity, and high strength. Recent NASA h d e d research has demonstrated the net shape fabrication of W-Re-HfC and other refractory metal and ceramic components that are similar to UN/W-Re cermet fuels. This effort is focused on basic research and characterization to identify the most promising compositions and processing techniques. A particular emphasis is being placed on low cost processes to fabricate near net shape parts of practical size. Several processing methods including Vacuum Plasma Spray (VPS) and conventional PM processes are being evaluated to fabricate material property samples and components. Surrogate W-Re/ZrN cermet fuel materials are being used to develop processing techniques for both coated and uncoated ceramic particles. After process optimization, depleted uranium-based cermets will be fabricated and tested to evaluate mechanical, thermal, and hot H2 erosion properties. This paper provides details on the current results of the project.

  14. Fused silica thermal conductivity dispersion at high temperature

    International Nuclear Information System (INIS)

    Bouchut, P.; Decruppe, D.; Delrive, L.

    2004-01-01

    A continuous CO 2 laser is focused to locally anneal small fused silica spots. A noncontact radiometry diagnostic enables us to follow surface temperature variation that occurs from site to site. A 'steady state' dispersion of surface temperature is observed across our sample. We show that nonhomogeneous silica thermal conductivity, above 1000 K is responsible for this temperature dispersion

  15. Thermal characteristics of high-temperature R718 heat pumps with turbo compressor thermal vapor recompression

    International Nuclear Information System (INIS)

    Šarevski, Milan N.; Šarevski, Vasko N.

    2017-01-01

    Highlights: • High pressure ratio, high speed, transonic R718 centrifugal compressors. • High efficient industrial evaporators/concentrators with turbo thermal vapor recompression. • Utilization of waste heat from industrial thermal and processing systems. • R718 is an ideal refrigerant for the novel high-temperature industrial heat pumps. • Application of single-stage R718 centrifugal compressors. - Abstract: Characteristics of R718 centrifugal compressors are analyzed and range of their applications in industrial high-temperature heat pumps, district heating systems and geothermal green house heating systems are estimated. Implementation of turbo compressor thermal vapor recompression in industrial evaporating/concentrating plants for waste heat utilization results in a high energy efficiency and in other technical, economical and environmental benefits. A novel concept of turbo compression R718 heat pumps is proposed and an assessment of their thermal characteristics is presented for utilization of waste heat from industrial thermal plants and systems (boilers, furnaces, various technological and metallurgical cooling processes, etc.), and for applications in district heating and geothermal green house heating systems. R718 is an ideal refrigerant for the novel high-temperature turbo compression industrial heat pumps. Direct evaporation and condensation are advantages of the proposed system which lead to higher COP, and to simplification of the plant and lower cost.

  16. High-temperature turbopump assembly for space nuclear thermal propulsion

    Science.gov (United States)

    Overholt, David M.

    1993-01-01

    The development of a practical, high-performance nuclear rocket by the U.S. Air Force Space Nuclear Thermal Propulsion (SNTP) program places high priority on maximizing specific impulse (ISP) and thrust-to-weight ratio. The operating parameters arising from these goals drive the propellant-pump design. The liquid hydrogen propellant is pressurized and pumped to the reactor inlet by the turbopump assembly (TPA). Rocket propulsion is effected by rapid heating of the propellant from 100 K to thousands of degrees in the particle-bed reactor (PBR). The exhausted propellant is then expanded through a high-temperature nozzle. One approach to achieve high performance is to use an uncooled carbon-carbon nozzle and duct turbine inlet. The high-temperature capability is obtained by using carbon-carbon throughout the TPA hot section. Carbon-carbon components in development include structural parts, turbine nozzles/stators, and turbine rotors. The technology spinoff is applicable to conventional liquid propulsion engines plus a wide variety of other turbomachinery applications.

  17. High-temperature turbopump assembly for space nuclear thermal propulsion

    International Nuclear Information System (INIS)

    Overholt, D.M.

    1993-01-01

    The development of a practical, high-performance nuclear rocket by the U.S. Air Force Space Nuclear Thermal Propulsion (SNTP) program places high priority on maximizing specific impulse (ISP) and thrust-to-weight ratio. The operating parameters arising from these goals drive the propellant-pump design. The liquid hydrogen propellant is pressurized and pumped to the reactor inlet by the turbopump assembly (TPA). Rocket propulsion is effected by rapid heating of the propellant from 100 K to thousands of degrees in the particle-bed reactor (PBR). The exhausted propellant is then expanded through a high-temperature nozzle. One approach to achieve high performance is to use an uncooled carbon-carbon nozzle and duct turbine inlet. The high-temperature capability is obtained by using carbon-carbon throughout the TPA hot section. Carbon-carbon components in development include structural parts, turbine nozzles/stators, and turbine rotors. The technology spinoff is applicable to conventional liquid propulsion engines plus a wide variety of other turbomachinery applications

  18. High Temperature Thermal Properties of Bentonite Foundry Sand

    Directory of Open Access Journals (Sweden)

    Krajewski P.K.

    2015-06-01

    Full Text Available The paper presents results of measuring thermal conductivity and heat capacity of bentonite foundry sand in temperature range ambient - 900­­°C. During the experiments a technical purity Cu plate was cast into the green-sand moulds. Basing on measurements of the mould temperature field during the solidification of the casting, the temperature relationships of the measured properties were evaluated. It was confirmed that water vaporization strongly influences thermal conductivity of the moulding sand in the first period of the mould heating by the poured casting.

  19. Thermal-mechanical fatigue of high temperature structural materials

    Science.gov (United States)

    Renauld, Mark Leo

    Experimental and analytical methods were developed to address the effect of thermal-mechanical strain cycling on high temperature structural materials under uniaxial and biaxial stress states. Two materials were used in the investigation, a nickel-base superalloy of low ductility, IN-738LC and a high ductility material, 316 stainless steel. A uniaxial life prediction model for the IN-738LC material was based on tensile hysteresis energy measured in stabilized, mid-life hysteresis loops. Hold-time effects and temperature cycling were incorporated in the hysteresis energy approach. Crack growth analysis was also included in the model to predict the number of TMF cycles to initiate and grow a fatigue crack through the coating. The nickel-base superalloy, IN-738LC, was primarily tested in out-of-phase (OP) TMF with a temperature range from 482-871sp°C (900-1600sp°F) under continuous and compressive hold-time cycling. IN-738LC fatigue specimens were coated either with an aluminide, NiCoCrAlHfSi overlay or CoNiCrAlY overlay coating on the outer surface of the specimen. Metallurgical failure analysis via optical and scanning electron microscopy, was used to characterize failure behavior of both substrate and coating materials. Type 316 SS was subjected to continuous biaxial strain cycling with an in-phase (IP) TMF loading and a temperature range from 399-621sp°C (750-1150sp°F). As a result, a biaxial TMF life prediction model was proposed on the basis of an extended isothermal fatigue model. The model incorporates a frequency effect and phase factors to assess the different damage mechanisms observed during TMF loading. The model was also applied to biaxial TMF data generated on uncoated IN-738LC.

  20. Near-Field Thermal Radiation for Solar Thermophotovoltaics and High Temperature Thermal Logic and Memory Applications

    Science.gov (United States)

    Elzouka, Mahmoud

    This dissertation investigates Near-Field Thermal Radiation (NFTR) applied to MEMS-based concentrated solar thermophotovoltaics (STPV) energy conversion and thermal memory and logics. NFTR is the exchange of thermal radiation energy at nano/microscale; when separation between the hot and cold objects is less than dominant radiation wavelength (˜1 mum). NFTR is particularly of interest to the above applications due to its high rate of energy transfer, exceeding the blackbody limit by orders of magnitude, and its strong dependence on separation gap size, surface nano/microstructure and material properties. Concentrated STPV system converts solar radiation to electricity using heat as an intermediary through a thermally coupled absorber/emitter, which causes STPV to have one of the highest solar-to-electricity conversion efficiency limits (85.4%). Modeling of a near-field concentrated STPV microsystem is carried out to investigate the use of STPV based solid-state energy conversion as high power density MEMS power generator. Numerical results for In 0.18Ga0.82Sb PV cell illuminated with tungsten emitter showed significant enhancement in energy transfer, resulting in output power densities as high as 60 W/cm2; 30 times higher than the equivalent far-field power density. On thermal computing, this dissertation demonstrates near-field heat transfer enabled high temperature NanoThermoMechanical memory and logics. Unlike electronics, NanoThermoMechanical memory and logic devices use heat instead of electricity to record and process data; hence they can operate in harsh environments where electronics typically fail. NanoThermoMechanical devices achieve memory and thermal rectification functions through the coupling of near-field thermal radiation and thermal expansion in microstructures, resulting in nonlinear heat transfer between two temperature terminals. Numerical modeling of a conceptual NanoThermoMechanical is carried out; results include the dynamic response under

  1. Thermal Stir Welding of High Strength and High Temperature Alloys for Aerospace Applications, Phase I

    Data.gov (United States)

    National Aeronautics and Space Administration — The Keystone and MSU team propose to demonstrate the feasibility of solid-state joining high strength and temperature alloys utilizing the Thermal Stir Welding...

  2. Estimated Viscosities and Thermal Conductivities of Gases at High Temperatures

    Science.gov (United States)

    Svehla, Roger A.

    1962-01-01

    Viscosities and thermal conductivities, suitable for heat-transfer calculations, were estimated for about 200 gases in the ground state from 100 to 5000 K and 1-atmosphere pressure. Free radicals were included, but excited states and ions were not. Calculations for the transport coefficients were based upon the Lennard-Jones (12-6) potential for all gases. This potential was selected because: (1) It is one of the most realistic models available and (2) intermolecular force constants can be estimated from physical properties or by other techniques when experimental data are not available; such methods for estimating force constants are not as readily available for other potentials. When experimental viscosity data were available, they were used to obtain the force constants; otherwise the constants were estimated. These constants were then used to calculate both the viscosities and thermal conductivities tabulated in this report. For thermal conductivities of polyatomic gases an Eucken-type correction was made to correct for exchange between internal and translational energies. Though this correction may be rather poor at low temperatures, it becomes more satisfactory with increasing temperature. It was not possible to obtain force constants from experimental thermal conductivity data except for the inert atoms, because most conductivity data are available at low temperatures only (200 to 400 K), the temperature range where the Eucken correction is probably most in error. However, if the same set of force constants is used for both viscosity and thermal conductivity, there is a large degree of cancellation of error when these properties are used in heat-transfer equations such as the Dittus-Boelter equation. It is therefore concluded that the properties tabulated in this report are suitable for heat-transfer calculations of gaseous systems.

  3. Sintering Characteristics of Multilayered Thermal Barrier Coatings Under Thermal Gradient and Isothermal High Temperature Annealing Conditions

    Science.gov (United States)

    Rai, Amarendra K.; Schmitt, Michael P.; Bhattacharya, Rabi; Zhu, Dongming; Wolfe, Douglas E.

    2014-01-01

    Pyrochlore oxides have most of the relevant attributes for use as next generation thermal barrier coatings such as phase stability, low sintering kinetics and low thermal conductivity. One of the issues with the pyrochlore oxides is their lower toughness and therefore higher erosion rate compared to the current state-of-the-art TBC material, yttria (6 to 8 wt%) stabilized zirconia (YSZ). In this work, sintering characteristics were investigated for novel multilayered coating consisted of alternating layers of pyrochlore oxide viz Gd2Zr2O7 and t' low k (rare earth oxide doped YSZ). Thermal gradient and isothermal high temperature (1316 C) annealing conditions were used to investigate sintering and cracking in these coatings. The results are then compared with that of relevant monolayered coatings and a baseline YSZ coating.

  4. Thermal hydraulics analysis of the Advanced High Temperature Reactor

    Energy Technology Data Exchange (ETDEWEB)

    Wang, Dean, E-mail: Dean_Wang@uml.edu [University of Massachusetts Lowell, One University Avenue, Lowell, MA 01854 (United States); Yoder, Graydon L.; Pointer, David W.; Holcomb, David E. [Oak Ridge National Laboratory, 1 Bethel Valley RD #6167, Oak Ridge, TN 37831 (United States)

    2015-12-01

    Highlights: • The TRACE AHTR model was developed and used to define and size the DRACS and the PHX. • A LOFF transient was simulated to evaluate the reactor performance during the transient. • Some recommendations for modifying FHR reactor system component designs are discussed. - Abstract: The Advanced High Temperature Reactor (AHTR) is a liquid salt-cooled nuclear reactor design concept, featuring low-pressure molten fluoride salt coolant, a carbon composite fuel form with embedded coated particle fuel, passively triggered negative reactivity insertion mechanisms, and fully passive decay heat rejection. This paper describes an AHTR system model developed using the Nuclear Regulatory Commission (NRC) thermal hydraulic transient code TRAC/RELAP Advanced Computational Engine (TRACE). The TRACE model includes all of the primary components: the core, downcomer, hot legs, cold legs, pumps, direct reactor auxiliary cooling system (DRACS), the primary heat exchangers (PHXs), etc. The TRACE model was used to help define and size systems such as the DRACS and the PHX. A loss of flow transient was also simulated to evaluate the performance of the reactor during an anticipated transient event. Some initial recommendations for modifying system component designs are also discussed. The TRACE model will be used as the basis for developing more detailed designs and ultimately will be used to perform transient safety analysis for the reactor.

  5. Role of high-temperature creep stress in thermally grown oxide growth of thermal barrier coatings

    Energy Technology Data Exchange (ETDEWEB)

    Ogawa, K.; Nakao, Y.; Seo, D.; Miura, H.; Shoji, T. [Tohoku Univ., Sendai (Japan)

    2008-07-01

    Thermally grown oxide (TGO) grows at the top / bond coating interface of the thermal barrier coating (TBC) in service. It is supposed that the failures of the TBC occur due to thermal stress and the decrease of adhesive strength caused by the TGO growth. Recently, large local stress has been found to change both the diffusion constant of oxygen through an existing oxide and the rate of chemical reaction at the oxide / oxidized material interface. Since high thermal stress occurs in the TBC, the volume expansion of the newly grown oxide, and centrifugal force, the growth rate of the TGO may change depending on not only temperature but also the stress. The aim of this study is to make clear the influence of stress on the growth rate of the TGO quantitatively. As a result, the thickness of the TGO clearly increases with increase of the amplitude of the applied stress and temperature. The increase rate of the TGO thickness is approximately 23% when the applied stress is increased from 0 to 205 MPa at 900 C, and approximately 29% when the stress is increased from 0 to 150 MPa at 950 C. (orig.)

  6. Thermal modelling of PV module performance under high ambient temperatures

    Energy Technology Data Exchange (ETDEWEB)

    Diarra, D.C.; Harrison, S.J. [Queen' s Univ., Kingston, ON (Canada). Dept. of Mechanical and Materials Engineering Solar Calorimetry Lab; Akuffo, F.O. [Kwame Nkrumah Univ. of Science and Technology, Kumasi (Ghana). Dept. of Mechanical Engineering

    2005-07-01

    When predicting the performance of photovoltaic (PV) generators, the actual performance is typically lower than test results conducted under standard test conditions because the radiant energy absorbed in the module under normal operation raises the temperature of the cell and other multilayer components. The increase in temperature translates to a lower conversion efficiency of the solar cells. In order to address these discrepancies, a thermal model of a characteristic PV module was developed to assess and predict its performance under real field-conditions. The PV module consisted of monocrystalline silicon cells in EVA between a glass cover and a tedlar backing sheet. The EES program was used to compute the equilibrium temperature profile in the PV module. It was shown that heat is dissipated towards the bottom and the top of the module, and that its temperature can be much higher than the ambient temperature. Modelling results indicate that 70-75 per cent of the absorbed solar radiation is dissipated from the solar cells as heat, while 4.7 per cent of the solar energy is absorbed in the glass cover and the EVA. It was also shown that the operating temperature of the PV module decreases with increased wind speed. 2 refs.

  7. Highly Effective Thermal Regenerator for Low Temperature Cryocoolers, Phase I

    Data.gov (United States)

    National Aeronautics and Space Administration — Future missions to investigate the structure and evolution of the universe require highly efficient, low-temperature cryocoolers for low-noise detector systems. We...

  8. Low-temperature thermal conductivity of highly porous copper

    International Nuclear Information System (INIS)

    Tomás, G; Bonfait, G; Martins, D; Cooper, A

    2015-01-01

    The development and characterization of new materials is of extreme importance in the design of cryogenic apparatus. Recently Versarien ® PLC developed a technique capable of producing copper foam with controlled porosity and pore size. Such porous materials could be interesting for cryogenic heat exchangers as well as of special interest in some devices used in microgravit.y environments where a cryogenic liquid is confined by capillarity.In the present work, a system was developed to measure the thermal conductivity by the differential steady-state mode of four copper foam samples with porosity between 58% and 73%, within the temperatures range 20 - 260 K, using a 2 W @ 20 K cryocooler. Our measurements were validated using a copper control sample and by the estimation of the Lorenz number obtained from electrical resistivity measurements at room temperature. With these measurements, the Resistivity Residual Ratio and the tortuosity were obtained. (paper)

  9. High-Temperature Adhesives for Thermally Stable Aero-Assist Technologies

    Science.gov (United States)

    Eberts, Kenneth; Ou, Runqing

    2013-01-01

    Aero-assist technologies are used to control the velocity of exploration vehicles (EVs) when entering Earth or other planetary atmospheres. Since entry of EVs in planetary atmospheres results in significant heating, thermally stable aero-assist technologies are required to avoid the high heating rates while maintaining low mass. Polymer adhesives are used in aero-assist structures because of the need for high flexibility and good bonding between layers of polymer films or fabrics. However, current polymer adhesives cannot withstand temperatures above 400 C. This innovation utilizes nanotechnology capabilities to address this need, leading to the development of high-temperature adhesives that exhibit high thermal conductivity in addition to increased thermal decomposition temperature. Enhanced thermal conductivity will help to dissipate heat quickly and effectively to avoid temperature rising to harmful levels. This, together with increased thermal decomposition temperature, will enable the adhesives to sustain transient high-temperature conditions.

  10. High temperature thermal energy storage in moving sand

    Science.gov (United States)

    Turner, R. H.; Awaya, H. I.

    1978-01-01

    Several high-temperature (to 500 C) heat-storage systems using sand as the storage medium are described. The advantages of sand as a storage medium include low cost for sand, widespread availability, non-toxicity, non-degradation characteristics, easy containment, and safety. The systems considered include: stationary sand with closely spaced tubes throughout the volume, the use of a fluidized bed, use of conveyor belt transporter, and the use of a blower rapid transport system. For a stationary sand bed, very close spacing of heat transfer tubes throughout the volume is required, manifesting as high power related system cost. The suggestion of moving sand past or around pipes is intended to reduce the power related costs at the penalty of added system complexity. Preliminary system cost estimates are offered. These rough calculations indicate that mobile sand heat storage systems cost less than the stationary sand approach.

  11. Gas cooled thermal reactors with high temperatures (VHTR)

    International Nuclear Information System (INIS)

    Bouchter, J.C.; Dufour, P.; Guidez, J.; Latge, C.; Renault, C.; Rimpault, G.; Vasile, A.

    2014-01-01

    VHTR is one of the 6 concepts retained for the 4. generation of nuclear reactors, it is an upgraded version of the HTR-type reactor (High Temperature Reactors). 5 HTR reactors were operated in the world in the eighties, now 2 experimental HTR are working in China and Japan and 2 HTR with an output power of 100 MWe are being built in China. The purpose of the VHTR is to provide an helium at very high temperatures around 1000 Celsius degrees that could be used directly in a thermochemical way to produce hydrogen for instance. HTR reactors are interesting in terms of safety but it does not optimise the consumption of uranium and the production of wastes. This article presents a brief historical account of HTR-type reactors and their main design and safety features. The possibility of using HTR to burn plutonium is also presented as well as the possibility of closing the fuel cycle and of using thorium-uranium fuel. (A.C.)

  12. Development of Thermally Actuated, High Temperature Composite Morphing Concepts

    Science.gov (United States)

    2016-03-31

    set of applications exists in gas turbine engines, which stand to benefit greatly from aerodynamic control in their combustors, turbines, and nozzles...Modelling Development 27 3.1 Mechanics . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 28 3.1.1 Achieving Snap-Through Behaviour ...Fabrication of Hybrid Laminate Shell and Strip Specimens . . . . . . 35 3.3.2 Measurement of Thermal Curvatures and Snap-Through Behaviour of Hybrid

  13. Development of Thermally Actuated, High-Temperature Composite Morphing Concepts

    Science.gov (United States)

    2016-05-11

    set of applications exists in gas turbine engines, which stand to benefit greatly from aerodynamic control in their combustors, turbines, and nozzles...Modelling Development 27 3.1 Mechanics . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 28 3.1.1 Achieving Snap-Through Behaviour ...Fabrication of Hybrid Laminate Shell and Strip Specimens . . . . . . 35 3.3.2 Measurement of Thermal Curvatures and Snap-Through Behaviour of Hybrid

  14. Thermal expansion studies on Inconel-600[reg] by high temperature X-ray diffraction

    International Nuclear Information System (INIS)

    Raju, S.; Sivasubramanian, K.; Divakar, R.; Panneerselvam, G.; Banerjee, A.; Mohandas, E.; Antony, M.P.

    2004-01-01

    The lattice thermal expansion characteristics of Inconel-600[reg] have been studied by high temperature X-ray diffraction (HT-XRD) technique in the temperature range 298-1200 K. Altogether four experimental runs were conducted on thin foils of about 75-100 μm thickness. The diffraction profiles have been accurately calibrated to offset the shift in 2θ values introduced by sample buckling at elevated temperatures. The corrected lattice parameter data have been used to estimate the instantaneous and mean linear thermal expansion coefficients as a function of temperature. The thermal expansion values estimated in the present study show a fair degree of agreement with other existing dilatometer based bulk thermal expansion estimates. The lattice parameter for this alloy at 300 K is found to be 0.3549(1) nm. The mean linear thermal expansivity is found to be 11.4 x 10 -6 K -1

  15. Measuring transient high temperature thermal phenomena in hostile environment

    International Nuclear Information System (INIS)

    Brenden, B.B.; Hartman, J.S.; Reich, F.R.

    1980-01-01

    The design of equipment for measuring temperature and strain in a rapidly heated and pressurized cylinder of stainless steel is discussed. Simultaneous cinematography of the full circumference of the cylinder without interference with temperature and strain measurements is also illustrated. The integrated system uses a reflective chamber for the sample and requires careful consideration of the spectral energy distribution utilized by each instrument

  16. Refractory porcelain enamel passive-thermal-control coating for high-temperature superalloys

    Science.gov (United States)

    Levin, H.; Auker, B. H.; Gardos, M. N.

    1973-01-01

    Study was conducted to match thermal expansion coefficients thereby preventing enamels from cracking. Report discusses various enamel coatings that are applied to two different high-temperature superalloys. Study may be of interest to manufacturers of chemical equipment, furnaces, and metal components intended for high-temperature applications.

  17. Thermal insulation of the high-temperature helium-cooled reactors

    International Nuclear Information System (INIS)

    Kharlamov, A.G.; Grebennik, V.N.

    1979-01-01

    Unlike the well-known thermal insulation methods, development of high-temperature helium reactors (HTGR) raises quite new problems. To understand these problems, it is necessary to consider behaviour of thermal insulation inside the helium circuit of HTGR and requirements imposed on it. Substantiation of these requirements is given in the presented paper

  18. High Temperature Exposure of HPC – Experimental Analysis of Residual Properties and Thermal Response

    Directory of Open Access Journals (Sweden)

    Pavlík Zbyšek

    2016-01-01

    Full Text Available The effect of high temperature exposure on properties of a newly designed High Performance Concrete (HPC is studied in the paper. The HPC samples are exposed to the temperatures of 200, 400, 600, 800, and 1000°C respectively. Among the basic physical properties, bulk density, matrix density and total open porosity are measured. The mechanical resistivity against disruptive temperature action is characterised by compressive strength, flexural strength and dynamic modulus of elasticity. To study the chemical and physical processes in HPC during its high-temperature exposure, Simultaneous Thermal Analysis (STA is performed. Linear thermal expansion coefficient is determined as function of temperature using thermodilatometry (TDA. In order to describe the changes in microstructure of HPC induced by high temperature loading, MIP measurement of pore size distribution is done. Increase of the total open porosity and connected decrease of the mechanical parameters for temperatures higher than 200 °C were identified.

  19. Thermal cyclic strength of molybdenum monocrystal at high temperatures

    International Nuclear Information System (INIS)

    Strizhalo, V.A.; Uskov, E.I.

    1975-01-01

    The results of the investigation of the thermocyclic creep and low-cycle fatigue of a molybdenum single crystal are discussed. The strength of a molybdenum single crystal under nonisothermal stressing has been investigated by using two different regimes of temperature and load variation. The temperature limits of the cycle were the same for the two testing regimes, the maximum temperature being 1700degC and the minimum 350degC. At higher temperatures (above 1500degC) the short-term strength of single-crystal molybdenum is comparable with that of commercial molybdenum and the refractory alloys, while the ductility is considerably higher. It should be noted that the failure of single-crystal molybdenum under rigid alternating loading is preceded by intensive distortion of the specimen, owing to directional cyclic creep of the metal in zones of bulging and thinning

  20. Experimental investigation of thermal de-stratification in rock bed TES systems for high temperature applications

    International Nuclear Information System (INIS)

    Okello, Denis; Nydal, Ole J.; Banda, Eldad J.K.

    2014-01-01

    Highlights: • High thermal stratifications exists rock bed TES when charge with high temperature heat. • Faster thermal degradation occurs in highly stratified bed irrespective of the bed length. • Average rate of heat loss as a function of storage time increases with increasing average bed temperature. - Abstract: Solar energy fluctuates so much that it cannot promote continuous use. Integration of Thermal Energy Storage (TES) with solar energy collection devices has the potential of making solar energy available on demand. Thermal energy can be stored in a bed of rocks at temperatures suitable for applications like cooking, boiling space heating, etc. During charging, temperature stratification is observed in the bed. In a stratified system, if the heat is used immediately, then it is possible to extract heat at reasonably high temperature from the top. For cases where the system is to be used after sometime (later at night or the following morning), the high temperature heat at the top is observed to degrade as the system tries to establish thermal equilibrium irrespective of the bed height. The average rate of heat loss from the TES unit to the ambient is found to increase with increasing average bed temperatures

  1. Measuring technique of super high temperature thermal properties of reactor core materials

    International Nuclear Information System (INIS)

    Ono, Akira; Baba, Tetsuya; Watanabe, Hideo; Matsumoto, Tsuyoshi

    1998-01-01

    In this study, thermal properties of reactor core materials used for water cooled reactors and FBR were tried to develop a technique to measure their melt states at less than 3,000degC in order to contribute more correct evaluation of the reactor core behavior at severe accident. Then, a thermal property measuring method of high temperature melt by using floating method was investigated and its fundamental design was begun to investigate under a base of optimum judgement on the air flow floating throw-down method. And, in order to measure emissivity of melt specimen surface essential for correct temperature measurement using the throw down method, a spectroscopic emissivity measuring unit using an ellipsometer was prepared and induced. On the thermal properties measurement using the holding method, a specimen container to measure thermal diffusiveness of the high temperature melts by using laser flashing method was tried to prepare. (G.K.)

  2. Thermal Stability of Hexamethyldisiloxane (MM for High-Temperature Organic Rankine Cycle (ORC

    Directory of Open Access Journals (Sweden)

    Markus Preißinger

    2016-03-01

    Full Text Available The design of efficient Organic Rankine Cycle (ORC units for the usage of industrial waste heat at high temperatures requires direct contact evaporators without intermediate thermal oil circuits. Therefore, the thermal stability of high-temperature working fluids gains importance. In this study, the thermal degradation of hexamethyldisiloxane (MM is investigated in an electrically heated tube. Qualitative results concerning remarks on degradation products as well as quantitative results like the annual degradation rate are presented. It is shown that MM is stable up to a temperature of 300 °C with annual degradation rates of less than 3.5%. Furthermore, the break of a silicon–carbon bond can be a main chemical reaction that influences the thermal degradation. Finally, it is discussed how the results may impact the future design of ORC units.

  3. High-Temperature Air-Cooled Power Electronics Thermal Design: Annual Progress Report

    Energy Technology Data Exchange (ETDEWEB)

    Waye, Scot [National Renewable Energy Lab. (NREL), Golden, CO (United States)

    2016-08-01

    Power electronics that use high-temperature devices pose a challenge for thermal management. With the devices running at higher temperatures and having a smaller footprint, the heat fluxes increase from previous power electronic designs. This project overview presents an approach to examine and design thermal management strategies through cooling technologies to keep devices within temperature limits, dissipate the heat generated by the devices and protect electrical interconnects and other components for inverter, converter, and charger applications. This analysis, validation, and demonstration intends to take a multi-scale approach over the device, module, and system levels to reduce size, weight, and cost.

  4. High-flux/high-temperature solar thermal conversion: technology development and advanced applications

    Directory of Open Access Journals (Sweden)

    Romero Manuel

    2016-01-01

    Full Text Available Solar Thermal Power Plants have generated in the last 10 years a dynamic market for renewable energy industry and a pro-active networking within R&D community worldwide. By end 2015, there are about 5 GW installed in the world, most of them still concentrated in only two countries, Spain and the US, though a rapid process of globalization is taking place in the last few years and now ambitious market deployment is starting in countries like South Africa, Chile, Saudi Arabia, India, United Arab Emirates or Morocco. Prices for electricity produced by today's plants fill the range from 12 to 16 c€/kWh and they are capital intensive with investments above 4000 €/kW, depending on the number of hours of thermal storage. The urgent need to speed up the learning curve, by moving forward to LCOE below 10 c€/kWh and the promotion of sun-to-fuel applications, is driving the R&D programmes. Both, industry and R&D community are accelerating the transformation by approaching high-flux/high-temperature technologies and promoting the integration with high-efficiency conversion systems.

  5. Thermal conductivity of beryllium under low temperature high dose neutron irradiation

    International Nuclear Information System (INIS)

    Chakin, V.P.; Latypov, R.N.; Suslov, D.N.; Kupriyanov, I.B.

    2004-01-01

    Thermal conductivity of compact beryllium of several Russian grades such as TE-400, TE-56, TE-30, TIP and DIP differing in the production technology, grain size and impurity content has been investigated. The thermal diffusivity of beryllium was measured on the disks in the initial and irradiated conditions using the pulse method in the range from room temperature to 200degC. The thermal conductivity was calculated using the table values for the beryllium thermal capacity. The specimens and beryllium neutron source fragments were irradiation in the SM reactor at 70degC and 200degC to a neutron fluence of (0.5-11.4)·10 22 cm -2 (E>0.1 MeV) and in the BOR-60 reactor at 400degC to 16·10 22 cm -2 (E>0.1MeV), respectively. The low-temperature irradiation leads to the drop decrease of the beryllium thermal conductivity and the effect depends on the irradiation parameters. The paper analyses the effect of irradiation parameters (temperature, neutron fluence), measurement temperature and structural factors on beryllium conductivity. The experiments have revealed that the short time post-irradiation annealing at high temperature results in partial reduction of the thermal conductivity of irradiated beryllium. (author)

  6. Thermal diffusivity measurements of liquid materials at high temperature with the ''laser flash'' method

    International Nuclear Information System (INIS)

    Otter, Claude; Vandevelde, Jean

    1982-01-01

    Two solutions, one analytical and the other numerical are proposed to solve the thermokinetic problem encountered when measuring the thermal diffusivity of liquid materials at very high temperature (T>3123K). The liquid material is contained in a parallel faced vessel. This liquid is traversed by a short thermal pulse from a relaxed laser. The temperature response of the back face of the measurement cell is analysed. The first model proposed which does not take thermal losses into consideration, is a mathematical model derived from the ''two layer model'' (Larson and Koyama, 1968) extended to ''three layers''. In order to take the possibility of thermal losses to the external environment at high temperature into consideration, a Crank-Nicolson (1947) type numerical model utilizing finite differences is employed. These thermokinetic studies were performed in order to interpret temperature response curves obtained from the back face of a tungsten-liquid UO 2 -tungsten thermal wall, the purpose of the measurements made being to determine the thermal properties of liquid uranium oxide [fr

  7. Thermal and rotational effect on giant dipole resonances in rotating nuclei at high temperature

    International Nuclear Information System (INIS)

    Sugawara-Tanabe, Kazuko; Tanabe, Kosai.

    1986-01-01

    Microscopic calculations are carried out for the giant dipole resonances excited on the thermal high spin states in 162 Er and 166 Er based on the thermal linear response theory with realistic forces and large single-particle space. The dynamical strength function is compared with the experimental γ-ray absorption cross section. The general trend that the resonance energy decreases and the resonance width increases with increasing angular momentum and temperature is well reproduced by the calculations. (author)

  8. Thermal-hydraulic code selection for modular high temperature gas-cooled reactors

    Energy Technology Data Exchange (ETDEWEB)

    Komen, E M.J.; Bogaard, J.P.A. van den

    1995-06-01

    In order to study the transient thermal-hydraulic system behaviour of modular high temperature gas-cooled reactors, the thermal-hydraulic computer codes RELAP5, MELCOR, THATCH, MORECA, and VSOP are considered at the Netherlands Energy Research Foundation ECN. This report presents the selection of the most appropriate codes. To cover the range of relevant accidents, a suite of three codes is recommended for analyses of HTR-M and MHTGR reactors. (orig.).

  9. New WC-Cu thermal barriers for fusion applications: High temperature mechanical behaviour

    Science.gov (United States)

    Tejado, E.; Dias, M.; Correia, J. B.; Palacios, T.; Carvalho, P. A.; Alves, E.; Pastor, J. Y.

    2018-01-01

    The combination of tungsten carbide and copper as a thermal barrier could effectively reduce the thermal mismatch between tungsten and copper alloy, which are proposed as base armour and heat sink, respectively, in the divertor of future fusion reactors. Furthermore, since the optimum operating temperature windows for these divertor materials do not overlap, a compatible thermal barrier interlayer between them is required to guarantee a smooth thermal transition, which in addition may mitigate radiation damage. The aim of this work is to study the thermo-mechanical properties of WC-Cu cermets fabricated by hot pressing. Focus is placed on the temperature effect and composition dependence, as the volume fraction of copper varies from 25 to 50 and 75 vol%. To explore this behaviour, fracture experiments are performed within a temperature range from room temperature to 800 °C under vacuum. In addition, elastic modulus and thermal expansion coefficient are estimated from these tests. Results reveal a strong dependence of the performance on temperature and on the volume fraction of copper and, surprisingly, a slight percent of Cu (25 vol%) can effectively reduce the large difference in thermal expansion between tungsten and copper alloy, which is a critical point for in service applications. The thermal performance of these materials, together with their mechanical properties could indeed reduce the heat transfer from the PFM to the underlying element while supporting the high thermal stresses of the joint. Thus, the presence of these cermets could allow the reactor to operate above the ductile to brittle transition temperature of tungsten, without compromising the underlying materials.

  10. An extended laser flash technique for thermal diffusivity measurement of high-temperature materials

    Science.gov (United States)

    Shen, F.; Khodadadi, J. M.

    1993-01-01

    Knowledge of thermal diffusivity data for high-temperature materials (solids and liquids) is very important in analyzing a number of processes, among them solidification, crystal growth, and welding. However, reliable thermal diffusivity versus temperature data, particularly those for high-temperature liquids, are still far from complete. The main measurement difficulties are due to the presence of convection and the requirement for a container. Fortunately, the availability of levitation techniques has made it possible to solve the containment problem. Based on the feasibility of the levitation technology, a new laser flash technique which is applicable to both levitated liquid and solid samples is being developed. At this point, the analysis for solid samples is near completion and highlights of the technique are presented here. The levitated solid sample which is assumed to be a sphere is subjected to a very short burst of high power radiant energy. The temperature of the irradiated surface area is elevated and a transient heat transfer process takes place within the sample. This containerless process is a two-dimensional unsteady heat conduction problem. Due to the nonlinearity of the radiative plus convective boundary condition, an analytic solution cannot be obtained. Two options are available at this point. Firstly, the radiation boundary condition can be linearized, which then accommodates a closed-form analytic solution. Comparison of the analytic curves for the temperature rise at different points to the experimentally-measured values will then provide the thermal diffusivity values. Secondly, one may set up an inverse conduction problem whereby experimentally obtained surface temperature history is used as the boundary conditions. The thermal diffusivity can then be elevated by minimizing the difference between the real heat flux boundary condition (radiation plus convection) and the measurements. Status of an experimental study directed at measuring the

  11. Rapid Thermal Annealing of Cathode-Garnet Interface toward High-Temperature Solid State Batteries.

    Science.gov (United States)

    Liu, Boyang; Fu, Kun; Gong, Yunhui; Yang, Chunpeng; Yao, Yonggang; Wang, Yanbin; Wang, Chengwei; Kuang, Yudi; Pastel, Glenn; Xie, Hua; Wachsman, Eric D; Hu, Liangbing

    2017-08-09

    High-temperature batteries require the battery components to be thermally stable and function properly at high temperatures. Conventional batteries have high-temperature safety issues such as thermal runaway, which are mainly attributed to the properties of liquid organic electrolytes such as low boiling points and high flammability. In this work, we demonstrate a truly all-solid-state high-temperature battery using a thermally stable garnet solid-state electrolyte, a lithium metal anode, and a V 2 O 5 cathode, which can operate well at 100 °C. To address the high interfacial resistance between the solid electrolyte and cathode, a rapid thermal annealing method was developed to melt the cathode and form a continuous contact. The resulting interfacial resistance of the solid electrolyte and V 2 O 5 cathode was significantly decreased from 2.5 × 10 4 to 71 Ω·cm 2 at room temperature and from 170 to 31 Ω·cm 2 at 100 °C. Additionally, the diffusion resistance in the V 2 O 5 cathode significantly decreased as well. The demonstrated high-temperature solid-state full cell has an interfacial resistance of 45 Ω·cm 2 and 97% Coulombic efficiency cycling at 100 °C. This work provides a strategy to develop high-temperature all-solid-state batteries using garnet solid electrolytes and successfully addresses the high contact resistance between the V 2 O 5 cathode and garnet solid electrolyte without compromising battery safety or performance.

  12. The design of high-temperature thermal conductivity measurements apparatus for thin sample size

    Directory of Open Access Journals (Sweden)

    Hadi Syamsul

    2017-01-01

    Full Text Available This study presents the designing, constructing and validating processes of thermal conductivity apparatus using steady-state heat-transfer techniques with the capability of testing a material at high temperatures. This design is an improvement from ASTM D5470 standard where meter-bars with the equal cross-sectional area were used to extrapolate surface temperature and measure heat transfer across a sample. There were two meter-bars in apparatus where each was placed three thermocouples. This Apparatus using a heater with a power of 1,000 watts, and cooling water to stable condition. The pressure applied was 3.4 MPa at the cross-sectional area of 113.09 mm2 meter-bar and thermal grease to minimized interfacial thermal contact resistance. To determine the performance, the validating process proceeded by comparing the results with thermal conductivity obtained by THB 500 made by LINSEIS. The tests showed the thermal conductivity of the stainless steel and bronze are 15.28 Wm-1K-1 and 38.01 Wm-1K-1 with a difference of test apparatus THB 500 are −2.55% and 2.49%. Furthermore, this apparatus has the capability to measure the thermal conductivity of the material to a temperature of 400°C where the results for the thermal conductivity of stainless steel is 19.21 Wm-1K-1 and the difference was 7.93%.

  13. Measurement of the Thermal Expansion Coefficient for Ultra-High Temperatures up to 3000 K

    Science.gov (United States)

    Kompan, T. A.; Kondratiev, S. V.; Korenev, A. S.; Puhov, N. F.; Inochkin, F. M.; Kruglov, S. K.; Bronshtein, I. G.

    2018-03-01

    The paper is devoted to a new high-temperature dilatometer, a part of the State Primary Standard of the thermal expansion coefficient (TEC) unit. The dilatometer is designed for investigation and certification of materials for TEC standards in the range of extremely high temperatures. The critical review of existing methods of TEC measurements is given. Also, the design, principles of operation and metrological parameters of the new device are described. The main attention is paid to the system of machine vision that allows accurate measurement of elongation at high temperatures. The results of TEC measurements for graphite GIP-4, single crystal Al2O3, and some other materials are also presented.

  14. Synthesis and thermal properties of a novel high temperature alkyl-center-trisphenolic-based phthalonitrile polymer

    International Nuclear Information System (INIS)

    Sheng, Haitong; Peng, Xuegang; Guo, Hui; Yu, Xiaoyan; Tang, Chengchun; Qu, Xiongwei; Zhang, Qingxin

    2013-01-01

    A novel alkyl-center-trisphenolic-based high-temperature phthalonitrile monomer, namely, 1,1,1-tris-[4-(3,4-dicyanophenoxy)phenyl]ethane (TDPE), was synthesized from 1,1,1-tris-(4-hydroxyphenyl)ethane (THPE) via a facile nucleophilic displacement of a nitro-substituent from 4-nitrophthalonitrile (NPN). The structure of TDPE monomer was characterized by Fourier transform infrared spectroscopy (FT-IR), nuclear magnetic resonance spectroscopy ( 1 H and 13 C NMR), elemental analysis (EA). Curing behaviors of TDPE with 4-(aminophenoxy)phthalonitrile (APPH) were recorded by differential scanning calorimetric (DSC) and it showed a large processing window (122 °C) which is favorable to processing TDPE polymers. The structure of TDPE polymer was discussed and the thermal stabilities of TDPE polymer were evaluated by thermogravimetric analysis (TGA). The TDPE polymer exhibits excellent thermal stability, and mechanism of thermal decompositions was explored. Dynamic mechanical analysis (DMA) revealed that the TDPE polymer has high storage modulus and high glass transition temperature (T g > 380 °C). - Highlights: • A novel high-temperature phthalonitrile polymer was synthesized. • Polymerization mechanism was explored. • The polymer shows excellent thermal stability. • Outstanding mechanical properties was achieved: storage modulus = 3.7 GPa, T g > 380 °C. • Thermal decomposition mechanism was discussed

  15. Thermal Cycling and High Temperature Reverse Bias Testing of Control and Irradiated Gallium Nitride Power Transistors

    Science.gov (United States)

    Patterson, Richard L.; Boomer, Kristen T.; Scheick, Leif; Lauenstein, Jean-Marie; Casey, Megan; Hammoud, Ahmad

    2014-01-01

    The power systems for use in NASA space missions must work reliably under harsh conditions including radiation, thermal cycling, and exposure to extreme temperatures. Gallium nitride semiconductors show great promise, but information pertaining to their performance is scarce. Gallium nitride N-channel enhancement-mode field effect transistors made by EPC Corporation in a 2nd generation of manufacturing were exposed to radiation followed by long-term thermal cycling and testing under high temperature reverse bias conditions in order to address their reliability for use in space missions. Result of the experimental work are presented and discussed.

  16. Evaluation of high temperature superconductive thermal bridges for space borne cryogenic detectors

    Science.gov (United States)

    Scott, Elaine P.

    1996-01-01

    Infrared sensor satellites are used to monitor the conditions in the earth's upper atmosphere. In these systems, the electronic links connecting the cryogenically cooled infrared detectors to the significantly warmer amplification electronics act as thermal bridges and, consequently, the mission lifetimes of the satellites are limited due to cryogenic evaporation. High-temperature superconductor (HTS) materials have been proposed by researchers at the National Aeronautics and Space Administration Langley's Research Center (NASA-LaRC) as an alternative to the currently used manganin wires for electrical connection. The potential for using HTS films as thermal bridges has provided the motivation for the design and the analysis of a spaceflight experiment to evaluate the performance of this superconductive technology in the space environment. The initial efforts were focused on the preliminary design of the experimental system which allows for the quantitative comparison of superconductive leads with manganin leads, and on the thermal conduction modeling of the proposed system. Most of the HTS materials were indicated to be potential replacements for the manganin wires. In the continuation of this multi-year research, the objectives of this study were to evaluate the sources of heat transfer on the thermal bridges that have been neglected in the preliminary conductive model and then to develop a methodology for the estimation of the thermal conductivities of the HTS thermal bridges in space. The Joule heating created by the electrical current through the manganin wires was incorporated as a volumetric heat source into the manganin conductive model. The radiative heat source on the HTS thermal bridges was determined by performing a separate radiant interchange analysis within a high-T(sub c) superconductor housing area. Both heat sources indicated no significant contribution on the cryogenic heat load, which validates the results obtained in the preliminary conduction

  17. High-temperature stability of yttria-stabilized zirconia thermal barrier ...

    Indian Academy of Sciences (India)

    The coatings before and after IR heating were investigated by scanning electron microscopy, X-ray diffraction, electron probe microanalysis, microhardness and residual stress measurements in order to understand the effect of thermal shock on the properties of the TBC. On account of these high-temperature properties, ...

  18. Critical currents and thermally activated flux motion in high-temperature superconductors

    NARCIS (Netherlands)

    Palstra, T.T.M.; Batlogg, B.; Dover, R.B. van; Schneemeyer, L.F.; Waszczak, J.V.

    1989-01-01

    We have measured the resistance below Tc of single crystals of the high-temperature superconductors Ba2YCu3O7 and Bi2.2Sr2Ca0.8Cu2O8+δ in magnetic fields up to 12 T. The resistive transition of both compounds is dominated by intrinsic dissipation which is thermally activated, resulting in an

  19. Thermal conductivity and diffusivity of climax stock quartz monzonite at high pressure and temperature

    International Nuclear Information System (INIS)

    Durham, W.B.; Abey, A.E.

    1981-11-01

    Measurements of thermal conductivity and thermal diffusivity have been made on two samples of Climax Stock quartz monzonite at pressures between 3 and 50 MPa and temperatures between 300 and 523 0 K. Following those measurements the apparatus was calibrated with respect to the thermal conductivity measurement using a reference standard of fused silica. Corrected thermal conductivity of the rock indicates a value at room temperature of 2.60 +- 0.25 W/mK at 3 MPa increasing linearly to 2.75 +- 0.25 W/mK at 50 MPa. These values are unchanged (+- 0.07 W/mK) by heating under 50-MPa pressure to as high as 473 0 K. The conductivity under 50-MPa confining pressure falls smoothly from 2.75 +- 0.25 W/mK at 313 0 K to 2.15 +- 0.25 W/mK at 473 0 K. Thermal diffusivity at 300 0 K was found to be 1.2 +- 0.4 X 10 -6 m 2 /s and shows approximately the same pressure and temperature dependencies as the thermal conductivity

  20. Thermal conductivity and diffusivity of climax stock quartz monzonite at high pressure and temperature

    Energy Technology Data Exchange (ETDEWEB)

    Durham, W.B.; Abey, A.E.

    1981-11-01

    Measurements of thermal conductivity and thermal diffusivity have been made on two samples of Climax Stock quartz monzonite at pressures between 3 and 50 MPa and temperatures between 300 and 523{sup 0}K. Following those measurements the apparatus was calibrated with respect to the thermal conductivity measurement using a reference standard of fused silica. Corrected thermal conductivity of the rock indicates a value at room temperature of 2.60 +- 0.25 W/mK at 3 MPa increasing linearly to 2.75 +- 0.25 W/mK at 50 MPa. These values are unchanged (+- 0.07 W/mK) by heating under 50-MPa pressure to as high as 473{sup 0}K. The conductivity under 50-MPa confining pressure falls smoothly from 2.75 +- 0.25 W/mK at 313{sup 0}K to 2.15 +- 0.25 W/mK at 473{sup 0}K. Thermal diffusivity at 300{sup 0}K was found to be 1.2 +- 0.4 X 10{sup -6} m{sup 2}/s and shows approximately the same pressure and temperature dependencies as the thermal conductivity.

  1. Solidification of high temperature molten salts for thermal energy storage systems

    Science.gov (United States)

    Sheffield, J. W.

    1981-01-01

    The solidification of phase change materials for the high temperature thermal energy storage system of an advanced solar thermal power system has been examined theoretically. In light of the particular thermophysical properties of candidate phase change high temperature salts, such as the eutectic mixture of NaF - MgF2, the heat transfer characteristics of one-dimensional inward solidification for a cylindrical geometry have been studied. The Biot number for the solidified salt is shown to be the critical design parameter for constant extraction heat flux. A fin-on-fin design concept of heat transfer surface augmentation is proposed in an effort to minimize the effects of the salt's low thermal conductivity and large volume change upon fusing.

  2. High-temperature thermal storage systems for advanced solar receivers materials selections

    Science.gov (United States)

    Wilson, D. F.; Devan, J. H.; Howell, M.

    1990-01-01

    Advanced space power systems that use solar energy and Brayton or Stirling heat engines require thermal energy storage (TES) systems to operate continuously through periods of shade. The receiver storage units, key elements in both Brayton and Stirling systems, are designed to use the latent heat of fusion of phase-change materials (PCMs). The power systems under current consideration for near-future National Aeronautics and Space Administration space missions require working fluid temperatures in the 1100 to 1400 K range. The PCMs under current investigation that gave liquid temperatures within this range are the fluoride family of salts. However, these salts have low thermal conductivity, which causes large temperature gradients in the storage systems. Improvements can be obtained, however, with the use of thermal conductivity enhancements or metallic PCMs. In fact, if suitable containment materials can be found, the use of metallic PCMs would virtually eliminate the orbit associated temperature variations in TES systems. The high thermal conductivity and generally low volume change on melting of germanium and alloys based on silicon make them attractive for storage of thermal energy in space power systems. An approach to solving the containment problem, involving both chemical and physical compatibility, preparation of NiSi/NiSi2, and initial results for containment of germanium and NiSi/NiSi2, are presented.

  3. Dimethyl terephthalate (DMT) as a candidate phase change material for high temperature thermal energy storage

    Energy Technology Data Exchange (ETDEWEB)

    Kuecuekaltun, Engin [Advansa Sasa Polyester San, A.S., Adana (Turkey); Paksoy, Halime; Bilgin, Ramazan; Yuecebilgic, Guezide [Cukurova Univ., Adana (Turkey). Chemistry Dept.; Evliya, Hunay [Cukurova Univ., Adana (Turkey). Center for Environmental Research

    2010-07-01

    Thermal energy storage at elevated temperatures, particularly in the range of 120-250 C is of interest with a significant potential for industrial applications that use process steam at low or intermediate pressures. At given temperature range there are few studies on thermal energy storage materials and most of them are dedicated to sensible heat. In this study, Dimethyl Terephthalate - DMT (CAS No: 120-61-6) is investigated as a candidate phase change material (PCM) for high temperature thermal energy storage. DMT is a monomer commonly used in Polyethylene terephtalate industry and has reasonable cost and availability. The Differential Scanning Calorimetry (DSC) analysis and heating cooling curves show that DMT melts at 140-146 C within a narrow window. Supercooling that was detected in DSC results was not observed in the cooling curve measurements made with a larger sample. With a latent heat of 193 J/g, DMT is a candidate PCM for high temperature storage. Potential limitations such as, low thermal conductivity and sublimation needs further investigation. (orig.)

  4. Experimental investigation of linear thermal expansion of pyrolytic graphite at high temperatures

    Science.gov (United States)

    Senchenko, V. N.; Belikov, R. S.

    2017-11-01

    Using the previously described [1] experimental setup for investigation of the thermophysical properties of refractory materials under high pressure and temperature a few experiments with pyrolytic graphite were carried out. The density of the material was equal to 2.18 g/cm3. Experimental data on the linear thermal expansion in the perpendicular and parallel to the basal plane direction were obtained. Thermal expansion in the perpendicular to the basal plane direction during the heating from room temperature up to the melting point was 16.4 ± 1.6%. The results obtained allow calculating the density of pyrolytic graphite in the wide range of high temperatures up to the melting point.

  5. Lifetime improvement of sheathed thermocouples for use in high-temperature and thermal transient operations

    International Nuclear Information System (INIS)

    McCulloch, R.W.; Clift, J.H.

    1982-01-01

    Premature failure of small-diameter, magnesium-oxide-insulated sheathed thermocouples occurred when they were placed within nuclear fuel rod simulators (FRSs) to measure high temperatures and to follow severe thermal transients encountered during simulation of nuclear reactor accidents in Oak Ridge National Laboratory (ORNL) thermal-hydraulic test facilities. Investigation of thermally cycled thermocouples yielded three criteria for improvement of thermocouple lifetime: (1) reduction of oxygen impurities prior to and during their fabrication, (2) refinement of thermoelement grain size during their fabrication, and (3) elimination of prestrain prior to use above their recrystallization temperature. The first and third criteria were satisfied by improved techniques of thermocouple assembly and by a recovery anneal prior to thermocouple use

  6. High-Temperature Thermal Energy Storage for electrification and district heating

    DEFF Research Database (Denmark)

    Pedersen, A. Schrøder; Engelbrecht, K.; Soprani, S.

    stability upon thermal cycling. The most promising material consists of basalt, diabase, and magnetite, whereas the less suited rocks contain larger proportions of quartz and mica. An HT-TES system, containing 1.5 m3 of rock pieces, was constructed. The rock bed was heated to 600 ˚C using an electric heater......The present work describes development of a High Temperature Thermal Energy Storage (HT-TES) system based on rock bed technology. A selection of rocks was investigated by thermal analysis in the range 20-800 ˚C. Subsequently, a shortlist was defined primarily based on mechanical and chemical...... to simulate thermal charging from wind energy. After complete heating of the rock bed it was left fully charged for hours to simulate actual storage conditions. Subsequently the bed discharging was performed by leading cold air through the rock bed whereby the air was heated and led to an exhaust. The results...

  7. Characteristics of Syngas Auto-ignition at High Pressure and Low Temperature Conditions with Thermal Inhomogeneities

    KAUST Repository

    Pal, Pinaki; Mansfield, Andrew B.; Wooldridge, Margaret S.; Im, Hong G.

    2015-01-01

    Effects of thermal inhomogeneities on syngas auto-ignition at high-pressure low-temperature conditions, relevant to gas turbine operation, are investigated using detailed one-dimensional numerical simulations. Parametric tests are carried out for a range of thermodynamic conditions (T = 890-1100 K, P = 3-20 atm) and composition (Ф = 0.1, 0.5). Effects of global thermal gradients and localized thermal hot spots are studied. In the presence of a thermal gradient, the propagating reaction front transitions from spontaneous ignition to deflagration mode as the initial mean temperature decreases. The critical mean temperature separating the two distinct auto-ignition modes is computed using a predictive criterion and found to be consistent with front speed and Damkohler number analyses. The hot spot study reveals that compression heating of end-gas mixture by the propagating front is more pronounced at lower mean temperatures, significantly advancing the ignition delay. Moreover, the compression heating effect is dependent on the domain size.

  8. Characteristics of Syngas Auto-ignition at High Pressure and Low Temperature Conditions with Thermal Inhomogeneities

    KAUST Repository

    Pal, Pinaki

    2015-05-31

    Effects of thermal inhomogeneities on syngas auto-ignition at high-pressure low-temperature conditions, relevant to gas turbine operation, are investigated using detailed one-dimensional numerical simulations. Parametric tests are carried out for a range of thermodynamic conditions (T = 890-1100 K, P = 3-20 atm) and composition (Ф = 0.1, 0.5). Effects of global thermal gradients and localized thermal hot spots are studied. In the presence of a thermal gradient, the propagating reaction front transitions from spontaneous ignition to deflagration mode as the initial mean temperature decreases. The critical mean temperature separating the two distinct auto-ignition modes is computed using a predictive criterion and found to be consistent with front speed and Damkohler number analyses. The hot spot study reveals that compression heating of end-gas mixture by the propagating front is more pronounced at lower mean temperatures, significantly advancing the ignition delay. Moreover, the compression heating effect is dependent on the domain size.

  9. Measuring the temperature dependent thermal diffusivity of geomaterials using high-speed differential scanning calorimetry

    Science.gov (United States)

    von Aulock, Felix W.; Wadsworth, Fabian B.; Vasseur, Jeremie; Lavallée, Yan

    2016-04-01

    Heat diffusion in the Earth's crust is critical to fundamental geological processes, such as the cooling of magma, heat dissipation during and following transient heating events (e.g. during frictional heating along faults), and to the timescales of contact metamorphosis. The complex composition and multiphase nature of geomaterials prohibits the accurate modeling of thermal diffusivities and measurements over a range of temperatures are sparse due to the specialized nature of the equipment and lack of instrument availability. We present a novel method to measure the thermal diffusivity of geomaterials such as minerals and rocks with high precision and accuracy using a commercially available differential scanning calorimeter (DSC). A DSC 404 F1 Pegasus® equipped with a Netzsch high-speed furnace was used to apply a step-heating program to corundum single crystal standards of varying thicknesses. The standards were cylindrical discs of 0.25-1 mm thickness with 5.2-6 mm diameter. Heating between each 50 °C temperature interval was conducted at a rate of 100 °C/min over the temperature range 150-1050 °C. Such large heating rates induces temperature disequilibrium in the samples used. However, isothermal segments of 2 minutes were used during which the temperature variably equilibrated with the furnace between the heating segments and thus the directly-measured heat-flow relaxed to a constant value before the next heating step was applied. A finite-difference 2D conductive heat transfer model was used in cylindrical geometry for which the measured furnace temperature was directly applied as the boundary condition on the sample-cylinder surfaces. The model temperature was averaged over the sample volume per unit time and converted to heat-flow using the well constrained thermal properties for corundum single crystals. By adjusting the thermal diffusivity in the model solution and comparing the resultant heat-flow with the measured values, we obtain a model

  10. AC Losses and Their Thermal Effect in High Temperature Superconducting Machines

    DEFF Research Database (Denmark)

    Song, Xiaowei (Andy); Mijatovic, Nenad; Zou, Shengnan

    2015-01-01

    In transient operations or fault conditions, high temperature superconducting (HTS) machines suffer AC losses which have an influence on the thermal stability of superconducting windings. In this paper, a method to calculate AC losses and their thermal effect in HTS machines is presented....... The method consists of three sub-models that are coupled only in one direction. The magnetic field distribution is first solved in a machine model, assuming a uniform current distribution in HTS windings. The magnetic fields on the boundaries are then used as inputs for an AC loss model which has...

  11. Thermal stability of multilayered Pt-Al2O3 nanocoatings for high temperature CSP systems

    CSIR Research Space (South Africa)

    Nuru, ZY

    2015-10-01

    Full Text Available B), 115-120 Thermal stability of multilayered Pt-Al2O3 nanocoatings for high temperature CSP systems Z.Y. Nuru a, b, *, L. Kotsedi a, b, C.J. Arendse c, D. Motaung d, B. Mwakikunga d, K. Roro d, e, M. Maaza a, b a UNESCO-UNISA Africa Chair... Pretoria, South Africa e R&D Core-Energy, Council for Scientific and Industrial Research, P O Box 395, 0001 Pretoria, South Africa Abstract This contribution reports on the effect of thermal annealing on sputtered Pt–Al(sub2)O(sub3) multilayered...

  12. Thermal energy storages analysis for high temperature in air solar systems

    International Nuclear Information System (INIS)

    Andreozzi, Assunta; Buonomo, Bernardo; Manca, Oronzio; Tamburrino, Salvatore

    2014-01-01

    In this paper a high temperature thermal storage in a honeycomb solid matrix is numerically investigated and a parametric analysis is accomplished. In the formulation of the model it is assumed that the system geometry is cylindrical, the fluid and the solid thermo physical properties are temperature independent and radiative heat transfer is taken into account whereas the effect of gravity is neglected. Air is employed as working fluid and the solid material is cordierite. The evaluation of the fluid dynamic and thermal behaviors is accomplished assuming the honeycomb as a porous medium. The Brinkman–Forchheimer–extended Darcy model is used in the governing equations and the local thermal non equilibrium is assumed. The commercial CFD Fluent code is used to solve the governing equations in transient regime. Numerical simulations are carried out with storage medium for different mass flow rates of the working fluid and different porosity values. Results in terms of temperature profiles, temperatures fields and stored thermal energy as function of time are presented. The effects of storage medium, different porosity values and mass flow rate on stored thermal energy and storage time are shown. - Highlights: • HTTES in a honeycomb solid matrix is numerically investigated. • The numerical analysis is carried out assuming the honeycomb as a porous medium. • The Brinkman–Forchheimer–extended Darcy model is used in the governing equations. • Results are carried out for different mass flow rates and porosity values. • The main effect is due to the porosity which set the thermal energy storage value

  13. Transcriptomic study to understand thermal adaptation in a high temperature-tolerant strain of Pyropia haitanensis.

    Science.gov (United States)

    Wang, Wenlei; Teng, Fei; Lin, Yinghui; Ji, Dehua; Xu, Yan; Chen, Changsheng; Xie, Chaotian

    2018-01-01

    Pyropia haitanensis, a high-yield commercial seaweed in China, is currently undergoing increasing levels of high-temperature stress due to gradual global warming. The mechanisms of plant responses to high temperature stress vary with not only plant type but also the degree and duration of high temperature. To understand the mechanism underlying thermal tolerance in P. haitanensis, gene expression and regulation in response to short- and long-term temperature stresses (SHS and LHS) was investigated by performing genome-wide high-throughput transcriptomic sequencing for a high temperature tolerant strain (HTT). A total of 14,164 differential expression genes were identified to be high temperature-responsive in at least one time point by high-temperature treatment, representing 41.10% of the total number of unigenes. The present data indicated a decrease in the photosynthetic and energy metabolic rates in HTT to reduce unnecessary energy consumption, which in turn facilitated in the rapid establishment of acclimatory homeostasis in its transcriptome during SHS. On the other hand, an increase in energy consumption and antioxidant substance activity was observed with LHS, which apparently facilitates in the development of resistance against severe oxidative stress. Meanwhile, ubiquitin-mediated proteolysis, brassinosteroids, and heat shock proteins also play a vital role in HTT. The effects of SHS and LHS on the mechanism of HTT to resist heat stress were relatively different. The findings may facilitate further studies on gene discovery and the molecular mechanisms underlying high-temperature tolerance in P. haitanensis, as well as allow improvement of breeding schemes for high temperature-tolerant macroalgae that can resist global warming.

  14. Thermal coupling of a high temperature PEM fuel cell with a complex hydride tank

    DEFF Research Database (Denmark)

    Pfeifer, P.; Wall, C.; Jensen, Jens Oluf

    2009-01-01

    the possibilities of a thermal coupling of a high temperature PEM fuel cell operating at 160-200 degrees C. The starting temperatures and temperature hold-times before starting fuel cell operation, the heat transfer characteristics of the hydride storage tanks, system temperature, fuel cell electrical power......Sodium alanate doped with cerium catalyst has been proven to have fast kinetics for hydrogen ab- and de-sorption as well as a high gravimetric storage density around 5 wt%. The kinetics of hydrogen sorption can be improved by preparing the alanate as nanocrystalline material. However, the second...... decomposition step, i.e. the decomposition of the hexahydride to sodium hydride and aluminium which refers to 1.8 wt% hydrogen is supposed to happen above 110 degrees C. The discharge of the material is thus limited by the level of heat supplied to the hydride storage tank. Therefore, we evaluated...

  15. Thermal analysis of heat and power plant with high temperature reactor and intermediate steam cycle

    Directory of Open Access Journals (Sweden)

    Fic Adam

    2015-03-01

    Full Text Available Thermal analysis of a heat and power plant with a high temperature gas cooled nuclear reactor is presented. The main aim of the considered system is to supply a technological process with the heat at suitably high temperature level. The considered unit is also used to produce electricity. The high temperature helium cooled nuclear reactor is the primary heat source in the system, which consists of: the reactor cooling cycle, the steam cycle and the gas heat pump cycle. Helium used as a carrier in the first cycle (classic Brayton cycle, which includes the reactor, delivers heat in a steam generator to produce superheated steam with required parameters of the intermediate cycle. The intermediate cycle is provided to transport energy from the reactor installation to the process installation requiring a high temperature heat. The distance between reactor and the process installation is assumed short and negligable, or alternatively equal to 1 km in the analysis. The system is also equipped with a high temperature argon heat pump to obtain the temperature level of a heat carrier required by a high temperature process. Thus, the steam of the intermediate cycle supplies a lower heat exchanger of the heat pump, a process heat exchanger at the medium temperature level and a classical steam turbine system (Rankine cycle. The main purpose of the research was to evaluate the effectiveness of the system considered and to assess whether such a three cycle cogeneration system is reasonable. Multivariant calculations have been carried out employing the developed mathematical model. The results have been presented in a form of the energy efficiency and exergy efficiency of the system as a function of the temperature drop in the high temperature process heat exchanger and the reactor pressure.

  16. Analytical method for estimating the thermal expansion coefficient of metals at high temperature

    International Nuclear Information System (INIS)

    Takamoto, S; Izumi, S; Nakata, T; Sakai, S; Oinuma, S; Nakatani, Y

    2015-01-01

    In this paper, we propose an analytical method for estimating the thermal expansion coefficient (TEC) of metals at high-temperature ranges. Although the conventional method based on quasiharmonic approximation (QHA) shows good results at low temperatures, anharmonic effects caused by large-amplitude thermal vibrations reduces its accuracy at high temperatures. Molecular dynamics (MD) naturally includes the anharmonic effect. However, since the computational cost of MD is relatively high, in order to make an interatomic potential capable of reproducing TEC, an analytical method is essential. In our method, analytical formulation of the radial distribution function (RDF) at finite temperature realizes the estimation of the TEC. Each peak of the RDF is approximated by the Gaussian distribution. The average and variance of the Gaussian distribution are formulated by decomposing the fluctuation of interatomic distance into independent elastic waves. We incorporated two significant anharmonic effects into the method. One is the increase in the averaged interatomic distance caused by large amplitude vibration. The second is the variation in the frequency of elastic waves. As a result, the TECs of fcc and bcc crystals estimated by our method show good agreement with those of MD. Our method enables us to make an interatomic potential that reproduces the TEC at high temperature. We developed the GEAM potential for nickel. The TEC of the fitted potential showed good agreement with experimental data from room temperature to 1000 K. As compared with the original potential, it was found that the third derivative of the wide-range curve was modified, while the zeroth, first and second derivatives were unchanged. This result supports the conventional theory of solid state physics. We believe our analytical method and developed interatomic potential will contribute to future high-temperature material development. (paper)

  17. CFX-10 Analysis of the High Temperature Thermal- Chemical Experiment (CS28-2)

    International Nuclear Information System (INIS)

    Kim, Hyoung Tae; Park, Joo Hwan; Rhee, Bo Wook

    2008-02-01

    A Computational Fluid Dynamics (CFD) model of a post-blowdown fuel channel analysis for aged CANDU reactors with crept pressure tube has been developed, and validated against a high temperature thermal-chemical experiment: CS28-2. The CS28-2 experiment is one of three series of experiments to simulate the thermal-chemical behavior of a 28-element fuel channel at a high temperature and a low steam flow rate which may occur in severe accident conditions such as a LBLOCA (Large Break Loss of Coolant Accident) of CANDU reactors. Pursuant to the objective of this study, the current study has focused on understanding the involved phenomena such as the thermal radiation and convection heat transfer, and the high temperature zirconium-steam reaction in a multi-ring geometry. Therefore, a zirconium-steam oxidation model based on a parabolic rate law was implemented into the CFX-10 code, which is a commercial CFD code offered from ANSYS Inc., and other heat transfer mechanisms in the 28-element fuel channel were modeled by the original CFX-10 heat transfer packages. To assess the capability of the CFX-10 code to model the thermal-chemical behavior of the 28-element fuel channel, the measured temperatures of the Fuel Element Simulators (FES) of three fuel rings in the test bundle and the pressure tube, and the hydrogen production in the CS28-2 experiment were compared with the CFX-10 predictions. In spite of some discrepancy between the measurement data and CFX results, it was found that the CFX-10 prediction based on the Urbanic-Heidrick correlation of the zirconium-steam reaction as well as the Discrete Transfer Model for a radiation heat transfer among the FES of three rings and the pressure tube are quite accurate and sound even for the offset a cluster fuel bundle of an aged fuel channel

  18. CFX-10 Analysis of the High Temperature Thermal- Chemical Experiment (CS28-2)

    Energy Technology Data Exchange (ETDEWEB)

    Kim, Hyoung Tae; Park, Joo Hwan; Rhee, Bo Wook

    2008-02-15

    A Computational Fluid Dynamics (CFD) model of a post-blowdown fuel channel analysis for aged CANDU reactors with crept pressure tube has been developed, and validated against a high temperature thermal-chemical experiment: CS28-2. The CS28-2 experiment is one of three series of experiments to simulate the thermal-chemical behavior of a 28-element fuel channel at a high temperature and a low steam flow rate which may occur in severe accident conditions such as a LBLOCA (Large Break Loss of Coolant Accident) of CANDU reactors. Pursuant to the objective of this study, the current study has focused on understanding the involved phenomena such as the thermal radiation and convection heat transfer, and the high temperature zirconium-steam reaction in a multi-ring geometry. Therefore, a zirconium-steam oxidation model based on a parabolic rate law was implemented into the CFX-10 code, which is a commercial CFD code offered from ANSYS Inc., and other heat transfer mechanisms in the 28-element fuel channel were modeled by the original CFX-10 heat transfer packages. To assess the capability of the CFX-10 code to model the thermal-chemical behavior of the 28-element fuel channel, the measured temperatures of the Fuel Element Simulators (FES) of three fuel rings in the test bundle and the pressure tube, and the hydrogen production in the CS28-2 experiment were compared with the CFX-10 predictions. In spite of some discrepancy between the measurement data and CFX results, it was found that the CFX-10 prediction based on the Urbanic-Heidrick correlation of the zirconium-steam reaction as well as the Discrete Transfer Model for a radiation heat transfer among the FES of three rings and the pressure tube are quite accurate and sound even for the offset a cluster fuel bundle of an aged fuel channel.

  19. An assessment of thermal spray coating technologies for high temperature corrosion protection

    International Nuclear Information System (INIS)

    Heath, G.R.; Heimgartner, P.; Gustafsson, S.; Irons, G.; Miller, R.

    1997-01-01

    The use of thermally sprayed coatings in combating high temperature corrosion continues to grow in the major industries of chemical, waste incineration, power generation and pulp and paper. This has been driven partially by the development of corrosion resistant alloys, improved knowledge and quality in the thermal spray industry and continued innovation in thermal spray equipment. There exists today an extensive range of thermal spray process options, often with the same alloy solution. In demanding corrosion applications it is not sufficient to just specify alloy and coating method. For the production of reliable coatings the whole coating production envelope needs to be considered, including alloy selection, spray parameters, surface preparation, base metal properties, heat input etc. Combustion, arc-wire, plasma, HVOF and spray+fuse techniques are reviewed and compared in terms of their strengths and limitations to provide cost-effective solutions for high temperature corrosion protection. Arc wire spraying, HP/HVOF and spray+fuse are emerging as the most promising techniques to optimise both coating properties and economic/practical aspects. (orig.)

  20. A new thermal conductivity probe for high temperature tests for the characterization of molten salts

    Science.gov (United States)

    Bovesecchi, G.; Coppa, P.; Pistacchio, S.

    2018-05-01

    A new thermal conductivity probe for high temperature (HT-TCP) has been built and tested. Its design and construction procedure are adapted from the ambient temperature thermal conductivity probe (AT-TCP) due to good performance of the latter device. The construction procedure and the preliminary tests are accurately described. The probe contains a Pt wire as a heater and a type K thermocouple (TC) as a temperature sensor, and its size is so small (0.6 mm in diameter and 60 mm in length) as to guarantee a length to diameter ratio of about 100. Calibration tests with glycerol for temperatures between 0 °C and 60 °C have shown good agreement with literature data, within 3%. Preliminary tests were also carried on a ternary molten salt for Concentrated Solar Power (CSP) (18% in mass of NaNO3, 52% KNO3, and 30% LiNO3) at 120 °C and 150 °C. Obtained results are within λ range of the Hitec® salt (53% KNO3, 7% NaNO3, 40% NaNO2). Unfortunately, at the higher temperature tested (200 °C), the viscosity of the salt highly decreases, and free convection starts, making the measurements unreliable.

  1. Positron annihilation in Si and Si-related materials in thermal equilibrium at high temperature

    International Nuclear Information System (INIS)

    Uedono, A.; Muramatsu, M.; Ubukata, T.; Tanino, H.; Shiraishi, T.; Tanigawa, S.; Takasu, S.

    2001-01-01

    Annihilation characteristics of positrons in the carbon/Si structure in thermal equilibrium at high temperature were studied using a monoenergetic positron beam. Doppler broadening spectra of the annihilation radiation were measured as a function of incident positron energy in the temperature range between 298 K and 1473 K. Above 1173 K, the value of S corresponding to the annihilation of positrons near the carbon/Si interface started to increase, which was attributed to the carbonization of Si and the introduction of open-space defects due to the diffusion of Si atoms toward the carbon layer. The behavior of Ps in a thermally grown SiO 2 film was also studied at 298-1523 K. (orig.)

  2. Potential for cladding thermal failure in LWRs during high temperature transients

    International Nuclear Information System (INIS)

    El Genk, M.S.

    1979-01-01

    The temperature increase in the fuel and the cladding during a PCM accident produces film boiling at the cladding surface which may induce zircaloy cladding failure, due to embrittlement, and fuel melting at the centerline of the fuel pellets. Molten fuel may extrude through radial cracks in the fuel and relocate in the fuel-cladding gap. Contact of extruded molten fuel with the cladding, which is at high temperature during film boiling, may induce cladding thermal failure due to melting. An assessment of central fuel melting and molten fuel extrusion into the fuel-cladding gap during a PCM accident is presented. The potential for thermal failure of the zircaloy cladding upon being contacted by molten fuel during such an accident is also analyzed and compared with the applicable experimental evidence

  3. Network structure and thermal stability study of high temperature seal glass

    Science.gov (United States)

    Lu, K.; Mahapatra, M. K.

    2008-10-01

    High temperature seal glass has stringent requirement on glass thermal stability, which is dictated by glass network structures. In this study, a SrO-La2O3-Al2O3-B2O3-SiO2 based glass system was studied using nuclear magnetic resonance, Raman spectroscopy, and x-ray diffraction for solid oxide cell application purpose. Glass structural unit neighboring environment and local ordering were evaluated. Glass network connectivity as well as silicon and boron glass former coordination were calculated for different B2O3:SiO2 ratios. Thermal stability of the borosilicate glasses was studied after thermal treatment at 850 °C. The study shows that high B2O3 content induces BO4 and SiO4 structural unit ordering, increases glass localized inhomogeneity, decreases glass network connectivity, and causes devitrification. Glass modifiers interact with either silicon- or boron-containing structural units and form different devitrified phases at different B2O3:SiO2 ratios. B2O3-free glass shows the best thermal stability among the studied compositions, remaining stable after thermal treatment for 200 h at 850 °C.

  4. Carbon dioxide as working fluid for medium and high-temperature concentrated solar thermal systems

    Directory of Open Access Journals (Sweden)

    Van Duong

    2014-03-01

    Full Text Available This paper explores the benefits and drawbacks of using carbon dioxide in solar thermal systems at medium and high operating temperatures. For medium temperatures, application of CO2 in non-imaging-optics based compound parabolic concentrators (CPC combined with evacuated-tube collectors is studied. These collectors have been shown to obtain efficiencies higher than 40% operating at around 200℃ without the need of tracking. Validated numerical models of external compound parabolic concentrators (XCPCs are used to simulate their performance using CO2 as working fluid. For higher temperatures, a mathematical model is implemented to analyze the operating performance of a parabolic trough solar collector (PTC using CO2 at temperatures between 100℃ and 600℃.

  5. High-temperature molten salt thermal energy storage systems for solar applications

    Science.gov (United States)

    Petri, R. J.; Claar, T. D.; Ong, E.

    1983-01-01

    Experimental results of compatibility screening studies of 100 salt/containment/thermal conductivity enhancement (TCE) combinations for the high temperature solar thermal application range of 704 deg to 871 C (1300 to 1600 F) are presented. Nine candidate containment/HX alloy materials and two TCE materials were tested with six candidate solar thermal alkali and alkaline earth carbonate storage salts (both reagent and technical grade of each). Compatibility tests were conducted with salt encapsulated in approx. 6.0 inch x 1 inch welded containers of test material from 300 to 3000 hours. Compatibility evaluations were end application oriented, considering the potential 30 year lifetime requirement of solar thermal power plant components. Analyses were based on depth and nature of salt side corrosion of materials, containment alloy thermal aging effects, weld integrity in salt environment, air side containment oxidation, and chemical and physical analyses of the salt. A need for more reliable, and in some cases first time determined thermophysical and transport property data was also identified for molten carbonates in the 704 to 871 C temperature range. In particular, accurate melting point (mp) measurements were performed for Li2CO3 and Na2CO3 while melting point, heat of fusion, and specific heat determinations were conducted on 81.3 weight percent Na2CO3-18.7 weight percent K2CO3 and 52.2 weight percent BaCO3-47.8 weight percent Na2CO3 to support future TES system design and ultimate scale up of solar thermal energy storage (TES) subsystems.

  6. A new technique for precise measurement of thermal conductivity of metals at normal and high temperatures

    International Nuclear Information System (INIS)

    Binkele, L.

    1990-09-01

    Theoretical and experimental investigations on a new measuring technique are described; a technique similar to the well known Kohlrausch measuring technique, which is characterized by direct electrical sample heating. Subject of the investigations is a cylindrical metallic sample, 5 mm thick and 200 mm in length, which is positioned vertically between water-cooled clamps in a vacuum container. The sample can be heated using two simultaneously operating current sources, a 50 Hz-source for axial flow (main heating) as well as a 200 kHz-induction source for generating eddy currents in two short regions above and below the sample centre (additional heating). By using two heating sources different symmetrical temperature profiles in a central eddy-current-free area of about ± 10mm can be produced for any given central sample temperature. The last chapter contains thermal conductivity and electrical resistivity measuring curves for Pt, W, Fe, Ni, Ag, Al, Mg, Ir, Ru, Re, Ho and Y in the temperature range 273 to 1500 K representative of all the metals and alloys investigated. In cases where comparisons with published precise conductivity data, established by other measuring techniques in restricted temperature ranges, were posible, the new measuring method is greatly supported (in the case of Pt, W, Ni, Ag, Al). For the Metals Ir, Ru, Re, Ho and Y high temperature thermal conductivity data are given for the first time. (orig./MM) [de

  7. High temperature glass thermal control structure and coating. [for application to spacecraft reusable heat shielding

    Science.gov (United States)

    Stewart, D. A.; Goldstein, H. E.; Leiser, D. B. (Inventor)

    1983-01-01

    A high temperature stable and solar radiation stable thermal control coating is described which is useful either as such, applied directly to a member to be protected, or applied as a coating on a re-usable surface insulation (RSI). It has a base coat layer and an overlay glass layer. The base coat layer has a high emittance, and the overlay layer is formed from discrete, but sintered together glass particles to give the overlay layer a high scattering coefficient. The resulting two-layer space and thermal control coating has an absorptivity-to-emissivity ratio of less than or equal to 0.4 at room temperature, with an emittance of 0.8 at 1200 F. It is capable of exposure to either solar radiation or temperatures as high as 2000 F without significant degradation. When used as a coating on a silica substrate to give an RSI structure, the coatings of this invention show significantly less reduction in emittance after long term convective heating and less residual strain than prior art coatings for RSI structures.

  8. Real time thermal hydraulic model for high temperature gas-cooled reactor core

    International Nuclear Information System (INIS)

    Sui Zhe; Sun Jun; Ma Yuanle; Zhang Ruipeng

    2013-01-01

    A real-time thermal hydraulic model of the reactor core was described and integrated into the simulation system for the high temperature gas-cooled pebble bed reactor nuclear power plant, which was developed in the vPower platform, a new simulation environment for nuclear and fossil power plants. In the thermal hydraulic model, the helium flow paths were established by the flow network tools in order to obtain the flow rates and pressure distributions. Meanwhile, the heat structures, representing all the solid heat transfer elements in the pebble bed, graphite reflectors and carbon bricks, were connected by the heat transfer network in order to solve the temperature distributions in the reactor core. The flow network and heat transfer network were coupled and calculated in real time. Two steady states (100% and 50% full power) and two transients (inlet temperature step and flow step) were tested that the quantitative comparisons of the steady results with design data and qualitative analysis of the transients showed the good applicability of the present thermal hydraulic model. (authors)

  9. Control performances of a piezoactuator direct drive valve system at high temperatures with thermal insulation

    Science.gov (United States)

    Han, Yung-Min; Han, Chulhee; Kim, Wan Ho; Seong, Ho Yong; Choi, Seung-Bok

    2016-09-01

    This technical note presents control performances of a piezoactuator direct drive valve (PDDV) operated at high temperature environment. After briefly discussing operating principle and mechanical dimensions of the proposed PDDV, an appropriate size of the PDDV is manufactured. As a first step, the temperature effect on the valve performance is experimentally investigated by measuring the spool displacement at various temperatures. Subsequently, the PDDV is thermally insulated using aerogel and installed in a large-size heat chamber in which the pneumatic-hydraulic cylinders and sensors are equipped. A proportional-integral-derivative feedback controller is then designed and implemented to control the spool displacement of the valve system. In this work, the spool displacement is chosen as a control variable since it is directly related to the flow rate of the valve system. Three different sinusoidal displacements with different frequencies of 1, 10 and 50 Hz are used as reference spool displacement and tracking controls are undertaken up to 150 °C. It is shown that the proposed PDDV with the thermal insulation can provide favorable control responses without significant tracking errors at high temperatures.

  10. Effects of carbon content on high-temperature mechanical and thermal fatigue properties of high-boron austenitic steels

    Directory of Open Access Journals (Sweden)

    Xiang Chen

    2016-01-01

    Full Text Available High-temperature mechanical properties of high-boron austenitic steels (HBASs were studied at 850 °C using a dynamic thermal-mechanical simulation testing machine. In addition, the thermal fatigue properties of the alloys were investigated using the self-restraint Uddeholm thermal fatigue test, during which the alloy specimens were cycled between room temperature and 800°C. Stereomicroscopy and scanning electron microscopy were used to study the surface cracks and cross-sectional microstructure of the alloy specimens after the thermal fatigue tests. The effects of carbon content on the mechanical properties at room temperature and high-temperature as well as thermal fatigue properties of the HBASs were also studied. The experimental results show that increasing carbon content induces changes in the microstructure and mechanical properties of the HBASs. The boride phase within the HBAS matrix exhibits a round and smooth morphology, and they are distributed in a discrete manner. The hardness of the alloys increases from 239 (0.19wt.% C to 302 (0.29wt.% C and 312 HV (0.37wt.% C; the tensile yield strength at 850 °C increases from 165.1 to 190.3 and 197.1 MPa; and the compressive yield strength increases from 166.1 to 167.9 and 184.4 MPa. The results of the thermal fatigue tests (performed for 300 cycles from room temperature to 800 °C indicate that the degree of thermal fatigue of the HBAS with 0.29wt.% C (rating of 2–3 is superior to those of the alloys with 0.19wt.% (rating of 4–5 and 0.37wt.% (rating of 3–4 carbon. The main cause of this difference is the ready precipitation of M23(C,B6-type borocarbides in the alloys with high carbon content during thermal fatigue testing. The precipitation and aggregation of borocarbide particles at the grain boundaries result in the deterioration of the thermal fatigue properties of the alloys.

  11. Thermal-hydraulic Analysis of High-temperature Cover Gas Region in STELLA-2

    Energy Technology Data Exchange (ETDEWEB)

    Jo, Youngchul; Son, Seok-Kwon; Yoon, Jung; Eoh, Jaehyuk; Jeong, Ji-Young [Korea Atomic Energy Research Institute, Daejeon (Korea, Republic of)

    2016-10-15

    The first phase of the program was focused on the key sodium component tests, and the second one has been concentrated on the sodium thermal-hydraulic integral effect test (STELLA-2). Based on its platform, simulation of the PGSFR transient will be made to evaluate plant dynamic behaviors as well as to demonstrate decay heat removal performance. Therefore, most design features of PGSFR have been modeled in STELLA-2 as closely as possible. The similarities of temperature and pressure between the model (STELLA-2) and the prototype (PGSFR) have been well preserved to reflect thermal-hydraulic behavior with natural convection as well as heat transfer between structure and sodium coolant inside the model reactor vessel (RV). For this reason, structural integrity of the entire test section should be confirmed as in the prototype. In particular, since the model reactor head in STELLA-2 supports key components and internal structures, its structural integrity exposed to high-temperature cover gas region should be confirmed. In order to reduce thermal radiation heat transfer from the hot sodium pool during normal operation, a dedicated insulation layer has been installed at the downward surface of the model reactor head to prevent direct heat flux from the sodium free surface at 545 .deg. C. Three-dimensional conjugate heat transfer analyses for the full-shape geometry of the upper part of the model reactor vessel in STELLA-2 have been carried out. Based on the results, steady-state temperature distributions in the cover gas region and the model reactor head itself have been obtained and the design requirement in temperature of the model reactor head has been newly proposed to be 350 .deg. C. For any elevated temperature conditions in STELLA-2, it was confirmed that the model reactor head generally satisfied the requirement. The CFD database constructed from this study will be used to optimize geometric parameters such as thicknesses and/or types of the insulator.

  12. Effects of thermal - mechanical treatment in the creep - and tensile properties of niobium at high temperature

    International Nuclear Information System (INIS)

    Botta Filho, W.J.; Pinatti, Dyonisio G.

    1981-01-01

    Mechanical behavior of Nb at high temperature was studied based upon the samples morfology. The samples were obtainned after thermal mechanical treatment of 50mm diameter and 250mm length ingot produced by electron beam vacuum. A lot of the samples was tensile tested as a function of temperature showing small interstitials solute effect and a matrix hardened probably by substitutionals. Other lot was creep tested at homologous temperature of 0,34 and stress between 80 and 120 MPa. The results of these tests were analysed as a function of the sample morfology and showed a dependence of the percentage of recrystalization and of the grain size on the minimum creep rate. The fracture analysis showed significant effect of the oxygen content although it didn't contribute to the creep results. (Author) [pt

  13. Phase competition and anomalous thermal evolution in high-temperature superconductors

    Science.gov (United States)

    Yu, Zuo-Dong; Zhou, Yuan; Yin, Wei-Guo; Lin, Hai-Qing; Gong, Chang-De

    2017-07-01

    The interplay of competing orders is relevant to high-temperature superconductivity known to emerge upon suppression of a parent antiferromagnetic order typically via charge doping. How such interplay evolves at low temperature—in particular at what doping level the zero-temperature quantum critical point (QCP) is located—is still elusive because it is masked by the superconducting state. The QCP had long been believed to follow a smooth extrapolation of the characteristic temperature T* for the strange normal state well above the superconducting transition temperature. However, recently the T* within the superconducting dome was reported to unexpectedly exhibit back-bending likely in the cuprate Bi2Sr2CaCu2O8 +δ . Here we show that the original and revised phase diagrams can be understood in terms of weak and moderate competitions, respectively, between superconductivity and a pseudogap state such as d -density or spin-density wave, based on both Ginzburg-Landau theory and the realistic t -t'-t''-J -V model for the cuprates. We further found that the calculated temperature and doping-level dependence of the quasiparticle spectral gap and Raman response qualitatively agrees with the experiments. In particular, the T* back-bending can provide a simple explanation of the observed anomalous two-step thermal evolution dominated by the superconducting gap and the pseudogap, respectively. Our results imply that the revised phase diagram is likely to take place in high-temperature superconductors.

  14. Response of Compacted Bentonites to Thermal and Thermo-Hydraulic Loadings at High Temperatures

    Directory of Open Access Journals (Sweden)

    Snehasis Tripathy

    2017-07-01

    Full Text Available The final disposal of high-level nuclear waste in many countries is preferred to be in deep geological repositories. Compacted bentonites are proposed for use as the buffer surrounding the waste canisters which may be subjected to both thermal and hydraulic loadings. A significant increase in the temperature is anticipated within the buffer, particularly during the early phase of the repository lifetime. In this study, several non-isothermal and non-isothermal hydraulic tests were carried on compacted MX80 bentonite. Compacted bentonite specimens (water content = 15.2%, dry density = 1.65 Mg/m3 were subjected to a temperature of either 85 or 150 °C at one end, whereas the temperature at the opposite end was maintained at 25 °C. During the non-isothermal hydraulic tests, water was supplied from the opposite end of the heat source. The temperature and relative humidity were monitored along predetermined depths of the specimens. The profiles of water content, dry density, and degree of saturation were established after termination of the tests. The test results showed that thermal gradients caused redistribution of the water content, whereas thermo-hydraulic gradients caused both redistribution and an increase in the water content within compacted bentonites, both leading to development of axial stress of various magnitudes. The applied water injection pressures (5 and 600 kPa and temperature gradients appeared to have very minimal impact on the magnitude of axial stress developed. The thickness of thermal insulation layer surrounding the testing devices was found to influence the temperature and relative humidity profiles thereby impacting the redistribution of water content within compacted bentonites. Under the influence of both the applied thermal and thermo-hydraulic gradients, the dry density of the bentonite specimens increased near the heat source, whereas it decreased at the opposite end. The test results emphasized the influence of

  15. Impacts of convection on high-temperature aquifer thermal energy storage

    Science.gov (United States)

    Beyer, Christof; Hintze, Meike; Bauer, Sebastian

    2016-04-01

    Seasonal subsurface heat storage is increasingly used in order to overcome the temporal disparities between heat production from renewable sources like solar thermal installations or from industrial surplus heat and the heat demand for building climatisation or hot water supply. In this context, high-temperature aquifer thermal energy storage (ATES) is a technology to efficiently store and retrieve large amounts of heat using groundwater wells in an aquifer to inject or withdraw hot or cold water. Depending on the local hydrogeology and temperature amplitudes during high-temperature ATES, density differences between the injected hot water and the ambient groundwater may induce significant convective flow components in the groundwater flow field. As a consequence, stored heat may accumulate at the top of the storage aquifer which reduces the heat recovery efficiency of the ATES system. Also, an accumulation of heat at the aquifer top will induce increased emissions of heat to overlying formations with potential impacts on groundwater quality outside of the storage. This work investigates the impacts of convective heat transport on the storage efficiency of a hypothetical high-temperature ATES system for seasonal heat storage as well as heat emissions to neighboring formations by numerical scenario simulations. The coupled groundwater flow and heat transport code OpenGeoSys is used to simulate a medium scale ATES system operating in a sandy aquifer of 20 m thickness with an average groundwater temperature of 10°C and confining aquicludes at top and bottom. Seasonal heat storage by a well doublet (i.e. one fully screened "hot" and "cold" well, respectively) is simulated over a period of 10 years with biannual injection / withdrawal cycles at pumping rates of 15 m³/h and for different scenarios of the temperature of the injected water (20, 35, 60 and 90 °C). Simulation results show, that for the simulated system significant convective heat transport sets in when

  16. High temperature thermal conductivity measurements of UO2 by Direct Electrical Heating. Final report

    International Nuclear Information System (INIS)

    Bassett, B.

    1980-10-01

    High temperature properties of reactor type UO 2 pellets were measured using a Direct Electrical Heating (DEH) Facility. Modifications to the experimental apparatus have been made so that successful and reproducible DEH runs may be carried out while protecting the pellets from oxidation at high temperature. X-ray diffraction measurements on the UO 2 pellets have been made before and after runs to assure that sample oxidation has not occurred. A computer code has been developed that will model the experiment using equations that describe physical properties of the material. This code allows these equations to be checked by comparing the model results to collected data. The thermal conductivity equation for UO 2 proposed by Weilbacher has been used for this analysis. By adjusting the empirical parameters in Weilbacher's equation, experimental data can be matched by the code. From the several runs analyzed, the resulting thermal conductivity equation is lambda = 1/4.79 + 0.0247T/ + 1.06 x 10 -3 exp[-1.62/kT/] - 4410. exp[-3.71/kT/] where lambda is in w/cm K, k is the Boltzman constant, and T is the temperature in Kelvin

  17. Using high thermal stability flexible thin film thermoelectric generator at moderate temperature

    Science.gov (United States)

    Zheng, Zhuang-Hao; Luo, Jing-Ting; Chen, Tian-Bao; Zhang, Xiang-Hua; Liang, Guang-Xing; Fan, Ping

    2018-04-01

    Flexible thin film thermoelectric devices are extensively used in the microscale industry for powering wearable electronics. In this study, comprehensive optimization was conducted in materials and connection design for fabricating a high thermal stability flexible thin film thermoelectric generator. First, the thin films in the generator, including the electrodes, were prepared by magnetron sputtering deposition. The "NiCu-Cu-NiCu" multilayer electrode structure was applied to ensure the thermal stability of the device used at moderate temperature in an air atmosphere. A design with metal layer bonding and series accordant connection was then employed. The maximum efficiency of a single PN thermocouple generator is >11%, and the output power loss of the generator is <10% after integration.

  18. Electromagnetic Acoustic Transducers Applied to High Temperature Plates for Potential Use in the Solar Thermal Industry

    Directory of Open Access Journals (Sweden)

    Maria Kogia

    2015-12-01

    Full Text Available Concentrated Solar Plants (CSPs are used in solar thermal industry for collecting and converting sunlight into electricity. Parabolic trough CSPs are the most widely used type of CSP and an absorber tube is an essential part of them. The hostile operating environment of the absorber tubes, such as high temperatures (400–550 °C, contraction/expansion, and vibrations, may lead them to suffer from creep, thermo-mechanical fatigue, and hot corrosion. Hence, their condition monitoring is of crucial importance and a very challenging task as well. Electromagnetic Acoustic Transducers (EMATs are a promising, non-contact technology of transducers that has the potential to be used for the inspection of large structures at high temperatures by exciting Guided Waves. In this paper, a study regarding the potential use of EMATs in this application and their performance at high temperature is presented. A Periodic Permanent Magnet (PPM EMAT with a racetrack coil, designed to excite Shear Horizontal waves (SH0, has been theoretically and experimentally evaluated at both room and high temperatures.

  19. Thermally activated flux creep in strongly layered high-temperature superconductors

    International Nuclear Information System (INIS)

    Chakravarty, S.; Ivlev, B.I.; Ovchinnikov, Y.N.

    1990-01-01

    Thermal activation energies for single vortices and vortex bundles in the presence of a magnetic field parallel to the layers are calculated. The pinning considered is intrinsic and is due to the strongly layered structure of high-temperature superconductors. The magnetic field and the current dependence of the activation energy are studied in detail. The calculation of the activation energy is used to determine the current-voltage characteristic. It may be possible to observe the effects discussed in this paper in a pure enough sample

  20. Tensile toughness test and high temperature fracture analysis of thermal barrier coatings

    International Nuclear Information System (INIS)

    Qian, G.; Nakamura, T.; Berndt, C.C.; Leigh, S.H.

    1997-01-01

    In this paper, an effective fracture toughness test which uses interface fracture mechanics theory is introduced. This method is ideally suited for determining fracture resistance of multilayered thermal barrier coatings (TBCs) consisting of ceramic and bond layers and, unlike other fracture experiments, requires minimal set-up over a simple tensile adhesion test. Furthermore, while other test methods usually use edge cracked specimens, the present test models a crack embedded within the coatings, which is more consistent with actual TBCs where failure initiates from internal voids or defects. The results of combined computational and experimental analysis show that any defects located within the ceramic coating can significantly weaken a TBC, whereas the debonding resistances of the bond coating and its interfaces are found to be much higher. In a separate analysis, the authors have studied fracture behavior of TBCs subjected to thermal loading in a high temperature environment. The computed fracture parameters reveal that when the embedded crack size is on order of the coating thickness, the fracture driving force is comparable to the fracture resistance of the coating found in the toughness test. In addition, the major driving force for fracture derives from the thermal insulating effect across the crack faces rather than the mismatch in the coefficients of thermal expansion. The authors have also investigated the effects of functionally graded material (FGM) within TBCs and found its influences on the fracture parameters to be small. This result implies that the FGM may not contribute toward enhancing the fracture toughness of the TBCs considered here

  1. Influence of coating on nanocrystalline magnetic properties during high temperature thermal ageing

    Energy Technology Data Exchange (ETDEWEB)

    Lekdim, Atef, E-mail: atef.lekdim@univ-lyon1.fr; Morel, Laurent; Raulet, Marie-Ange

    2017-05-15

    Since their birth or mergence the late 1980s, the nanocrystalline ultrasoft magnetic materials are taking a great importance in power electronic systems conception. One of the main advantages that make them more attractive nowadays is their ability to be packaged since the reduction of the magnetostrictive constant to almost zero. In aircraft applications, due to the high component compactness and to their location (for example near the jet engine), the operating temperature increases and may reach easily 200 °C and more. Consequently, the magnetic thermal ageing may occur but is, unfortunately, weakly studied. This paper focuses on the influence of the coating (packaging type) on the magnetic nanocrystalline performances during a thermal ageing. This study is based on monitoring the magnetic characteristics of two types of nanocrystalline cores (naked and coated) during a thermal activated ageing (100, 150 and 200 °C). Based on a dedicated monitoring protocol, a large magnetic characterization has been done and analyzed. Elsewhere, X-Ray Diffraction and magnetostriction measurements were carried out to support the study of the anisotropy energies evolution with ageing. This latter is discussed in this paper to explain and give hypothesis about the ageing phenomena. - Highlights: • The coating impacts drastically the magnetic properties during thermal ageing. • Irreversible ageing phenomena after the total coating breakage. • The deteriorations are related to the storage of the magnetoelastic anisotropy.

  2. Thermal conductivity in high critical temperature superconductors. Conductividad termica en los superconductores de alta temperatura critica

    Energy Technology Data Exchange (ETDEWEB)

    Castello, D J

    1990-01-01

    A measuring procedure to obtain the electrical resistivity, thermal conductivity and thermoelectric power of samples of low conductivity has been developed. The setup was designed to allow removal of the sample in clean fashion so that further heat treatments could be performed. The heat equation has been analyzed with time-dependent boundary conditions, with the purpose of developing a dynamic measuring method which avoids the long delays involved in reaching thermal equilibrium above 30K. The developed measuring method allows precise, reliable measurements in a continuous fashion for temperatures above 25K. The same setup is used in a stationary mode at low temperatures. {kappa}(T) has been measured in two ceramic samples of La{sub 2}CuO{sub 4}: the first semiconducting, the other superconducting (SC) as a consequence of an oxygen annealing. Both exhibit strong thermal resistivity due to defects, though lower in the SC, where two maxima are observed and are attributed to an AF ordering: T{sub N}' {approx equal} 40K and T{sub N}'' {approx equal} 240K. A third synthesized sample of CuO exhibits a typical behavior of an insulator, with T{sup 2}.6 at low temperatures, a maximum at 40K and a decrease in T{sup -1} at high temperatures. {kappa}(T) in a SC sample of La{sub 1}.85Sr{sub 1}.15CuO{sub 4} with T{sub c}=35.5K has also been measured. {kappa}(T) is lower than in the previous samples and thus a greater number of defects was inferred.

  3. Development and Performance Evaluation of High Temperature Concrete for Thermal Energy Storage for Solar Power Generation

    Energy Technology Data Exchange (ETDEWEB)

    Selvam, R. Panneer; Hale, Micah; Strasser, Matt

    2013-03-31

    Thermal energy can be stored by the mechanism of sensible or latent heat or heat from chemical reactions. Sensible heat is the means of storing energy by increasing the temperature of the solid or liquid. Since the concrete as media cost per kWhthermal is $1, this seems to be a very economical material to be used as a TES. This research is focused on extending the concrete TES system for higher temperatures (500 °C to 600 °C) and increasing the heat transfer performance using novel construction techniques. To store heat at high temperature special concretes are developed and tested for its performance. The storage capacity costs of the developed concrete is in the range of $0.91-$3.02/kWhthermal. Two different storage methods are investigated. In the first one heat is transported using molten slat through a stainless steel tube and heat is transported into concrete block through diffusion. The cost of the system is higher than the targeted DOE goal of $15/kWhthermal. The increase in cost of the system is due to stainless steel tube to transfer the heat from molten salt to the concrete blocks.The other method is a one-tank thermocline system in which both the hot and cold fluid occupy the same tank resulting in reduced storage tank volume. In this model, heated molten salt enters the top of the tank which contains a packed bed of quartzite rock and silica sand as the thermal energy storage (TES) medium. The single-tank storage system uses about half the salt that is required by the two-tank system for a required storage capacity. This amounts to a significant reduction in the cost of the storage system. The single tank alternative has also been proven to be cheaper than the option which uses large concrete modules with embedded heat exchangers. Using computer models optimum dimensions are determined to have an round trip efficiency of 84%. Additionally, the cost of the structured concrete thermocline configuration provides the TES

  4. Superconductivity degradation in Gd-containing high temperature superconductors (HTSC) under thermal neutron irradiation

    International Nuclear Information System (INIS)

    Petrov, A.; Kudrenitskis, I.; Makletsov, A.; Arhipov, A.; Karklin, N.

    1999-01-01

    The physical properties of ordered crystals are extremely sensitive to the degree of order in the distribution of the various kinds of atoms over the corresponding sites in the crystal lattice. An increasingly popular means of creating disordered states is to use nuclear radiation. The type of radiation defects which appear and the nature and degree of the structural changes in ordered crystals depend on the kind of radiation and the fluence level, the irradiation temperature, the type of crystal structure, the composition and initial disorder of the material, the character of the interatomic forces, etc. There are many such scientific publications where the effects of fast neutron irradiation on high temperature superconductors (HTSC) have been studied in both polycrystalline and single crystalline superconductors. It is known also that the role of thermal neutrons in structural defects forming is negligible in comparison with fast neutrons because of their small (∼0.025 eV) energy. But it is evident enough that in superconductors containing isotopes with large thermal neutron cross sections the important results concerning the role of point defects could be obtained. Such point defects are creating due to soft displacements of isotopes having interacted with thermal neutrons. Such the possibility of creating point defects in solids including HTSC is investigating by several groups (Austria, USA, China, Latvia) and these investigations have found the support in the person of IAEA. In this review the authors consider the changes brought about by thermal-neutron irradiation (E∼0.025 eV) in the structure, superconducting and magnetic properties of gadolinium containing ordered HTSC with the structure 123, whose extreme electric and magnetic properties continue to attract both research and practical interest. All of the studies reviewed have been done on bulk polycrystalline samples RBa 2 Cu 3 O 7-δ (where R - natural mixture of Gd isotopes, 155 Gd, 157 Gd, 160

  5. High-temperature thermal-chemical analysis of nuclear fuel channels

    Energy Technology Data Exchange (ETDEWEB)

    Nekhamkin, Y; Rosenband, V; Hasan, D; Elias, E; Wacholder, E; Gany, A [Technion-Israel Inst. of Tech., Haifa (Israel)

    1996-12-01

    In a severe accident situation, e.g., a postulated loss of coolant accident with a coincident loss of emergency core cooling (LOCA/LOECC), the core may become partially uncovered and steam may become the only coolant available. The thermodynamic conditions in the core, in this case, depend on ability of the steam to effectively remove the fuel decay heat and the heat generated by the exothermic steam/Zircaloy reaction., Therefore, it is important to understand the high-temperature behavior of an oxidizing fuel channel. The main objective of this work is to develop a methodology for calculating the clad temperature and rate of oxidation of a partially covered fuel pin. A criterion is derived to define the importance of the chemical reaction in the overall heat balance. The main parameters affecting the fuel thermal behavior are outlined (authors).

  6. Characterization of thermally sprayed coatings for high-temperature wear-protection applications

    International Nuclear Information System (INIS)

    Li, C.C.

    1980-03-01

    Under normal high-temperature gas-cooled reactor (HTGR) operating conditions, faying surfaces of metallic components under high contact pressure are prone to friction, wear, and self-welding damage. Component design calls for coatings for the protection of the mating surfaces. Anticipated operating temperatures up to 850 to 950 0 C (1562 to 1742 0 F) and a 40-y design life require coatings with excellent thermal stability and adequate wear and spallation resistance, and they must be compatible with the HTGR coolant helium environment. Plasma and detonation-gun (D-gun) deposited chromium carbide-base and stabilized zirconia coatings are under consideration for wear protection of reactor components such as the thermal barrier, heat exchangers, control rods, and turbomachinery. Programs are under way to address the structural integrity, helium compatibility, and tribological behavior of relevant sprayed coatings. In this paper, the need for protection of critical metallic components and the criteria for selection of coatings are discussed. The technical background to coating development and the experience with the steam cycle HTGR (HTGR-SC) are commented upon. Coating characterization techniques employed at General Atomic Company (GA) are presented, and the progress of the experimental programs is briefly reviewed. In characterizing the coatings for HTGR applications, it is concluded that a systems approach to establish correlation between coating process parameters and coating microstructural and tribological properties for design consideration is required

  7. Thermal and irradiation effects on high-temperature mechanical properties of materials for SCWR fuel cladding

    International Nuclear Information System (INIS)

    Kano, F.; Tsuchiya, Y.; Oka, K.

    2009-01-01

    The thermal and irradiation effects on high-temperature mechanical properties are examined for candidate alloys for fuel cladding of supercritical water-cooled reactors (SCRWs). JMTR (Japan Materials Testing Reactor) and Experimental Fast Reactor JOYO were utilized for neutron irradiation tests, considering their fluence and temperature. Irradiation was performed with JMTR at 600degC up to 4x10 24 n/m 2 and with JOYO at 600degC and 700degC up to 6x10 25 n/m 2 . Tensile test, creep test and hardness measurement were carried out for high-temperature mechanical properties. Based on the uniaxial creep test, the extrapolation curves were drawn with time-temperature relationships utilizing the Larson and Miller Parameter. Several candidate alloys are expected to satisfy the design requirement from the estimation of the creep rupture stress for 50000 hours. Comparing the creep strengths under irradiated and unirradiated conditions, it was inferred that creep deformation was dominated by the thermal effect rather than the irradiation at SCWR core condition. The microstructure was examined using transmission electron microscope (TEM) analysis, focusing on void swelling and helium (He) bubble formation. Void formation was observed in the materials irradiated with JOYO at 600degC but not at 700degC. However, its effect on the deformation of components was estimated to be tolerable since their size and density were negligibly small. The manufacturability of the thin-wall, small-diameter tube was confirmed for the potential candidate alloys through the trial tests in the factory where the fuel cladding tube is manufactured. (author)

  8. The Effect of High Temperatures on the Effective Thermal Conductivity of Concrete

    International Nuclear Information System (INIS)

    Weidenfeld, G.; Aharon, G.; Hochbaum, I.

    2002-01-01

    Concrete thermal conductivity is an important property for thermal analysis of nuclear accidents.Concrete compositions include water,sand,cement and aggregates of various kinds and combinations.Values of concrete's thermal conductivity for some different compositions can be found in the literature[1]but since the material composition and its temperature significantly affect this property,the exact value of a specific composition should be measured

  9. High-temperature stability of yttria-stabilized zirconia thermal barrier ...

    Indian Academy of Sciences (India)

    temperature drop was found to increase with the coating thickness of YSZ. The coatings ... thermal barrier coating system on niobium alloys for supersonic vehicles. .... Voltage (V). 75 ..... However, distribution of the other elements; such as Ni,.

  10. Thermal conductivities and conduction mechanisms of Sb-Te Alloys at high temperatures

    International Nuclear Information System (INIS)

    Lan, Rui; Endo, Rie; Kobayashi, Yoshinao; Susa, Masahiro; Kuwahara, Masashi

    2011-01-01

    Sb-Te alloys have drawn much attention due to its application in phase change memory as well as the unique properties as chalcogenide. In this work, the thermal conductivities of Sb-x mol%Te alloys (x = 14, 25, 44, 60, 70, and 90) have been measured by the hot strip method from room temperature up to temperature just below the respective melting points. For the intermetallic compound Sb 2 Te 3 (x = 60), the thermal conductivity decreases up to approximately 600 K and then increases. For other Sb-x mol%Te alloys where x > 60, the thermal conductivities of the alloys decrease with increasing temperature. In contrast, for x < 60, the thermal conductivities of the alloys keep roughly constant up to approximately 600 K and then increase with increasing temperature. It is proposed that free electron dominates the heat transport below 600 K, and ambipolar diffusion also contributes to the increase in the thermal conductivity at higher temperatures. The prediction equation from temperature and chemical composition has been proposed for thermal conductivities of Sb-Te alloys.

  11. High temperature deformation behavior, thermal stability and irradiation performance in Grade 92 steel

    Science.gov (United States)

    Alsagabi, Sultan

    The 9Cr-2W ferritic-martensitic steel (i.e. Grade 92 steel) possesses excellent mechanical and thermophysical properties; therefore, it has been considered to suit more challenging applications where high temperature strength and creep-rupture properties are required. The high temperature deformation mechanism was investigated through a set of tensile testing at elevated temperatures. Hence, the threshold stress concept was applied to elucidate the operating high temperature deformation mechanism. It was identified as the high temperature climb of edge dislocations due to the particle-dislocation interactions and the appropriate constitutive equation was developed. In addition, the microstructural evolution at room and elevated temperatures was investigated. For instance, the microstructural evolution under loading was more pronounced and carbide precipitation showed more coarsening tendency. The growth of these carbide precipitates, by removing W and Mo from matrix, significantly deteriorates the solid solution strengthening. The MX type carbonitrides exhibited better coarsening resistance. To better understand the thermal microstructural stability, long tempering schedules up to 1000 hours was conducted at 560, 660 and 760°C after normalizing the steel. Still, the coarsening rate of M23C 6 carbides was higher than the MX-type particles. Moreover, the Laves phase particles were detected after tempering the steel for long periods before they dissolve back into the matrix at high temperature (i.e. 720°C). The influence of the tempering temperature and time was studied for Grade 92 steel via Hollomon-Jaffe parameter. Finally, the irradiation performance of Grade 92 steel was evaluated to examine the feasibility of its eventual reactor use. To that end, Grade 92 steel was irradiated with iron (Fe2+) ions to 10, 50 and 100 dpa at 30 and 500°C. Overall, the irradiated samples showed some irradiation-induced hardening which was more noticeable at 30°C. Additionally

  12. Sensitivity analysis of recovery efficiency in high-temperature aquifer thermal energy storage with single well

    International Nuclear Information System (INIS)

    Jeon, Jun-Seo; Lee, Seung-Rae; Pasquinelli, Lisa; Fabricius, Ida Lykke

    2015-01-01

    High-temperature aquifer thermal energy storage system usually shows higher performance than other borehole thermal energy storage systems. Although there is a limitation in the widespread use of the HT-ATES system because of several technical problems such as clogging, corrosion, etc., it is getting more attention as these issues are gradually alleviated. In this study, a sensitivity analysis of recovery efficiency in two cases of HT-ATES system with a single well is conducted to select key parameters. For a fractional factorial design used to choose input parameters with uniformity, the optimal Latin hypercube sampling with an enhanced stochastic evolutionary algorithm is considered. Then, the recovery efficiency is obtained using a computer model developed by COMSOL Multiphysics. With input and output variables, the surrogate modeling technique, namely the Gaussian-Kriging method with Smoothly Clopped Absolute Deviation Penalty, is utilized. Finally, the sensitivity analysis is performed based on the variation decomposition. According to the result of sensitivity analysis, the most important input variables are selected and confirmed to consider the interaction effects for each case and it is confirmed that key parameters vary with the experiment domain of hydraulic and thermal properties as well as the number of input variables. - Highlights: • Main and interaction effects on recovery efficiency in HT-ATES was investigated. • Reliability depended on fractional factorial design and interaction effects. • Hydraulic permeability of aquifer had an important impact on recovery efficiency. • Site-specific sensitivity analysis of HT-ATES was recommended.

  13. Comparison of Two Models for Radiative Heat Transfer in High Temperature Thermal Plasmas

    Directory of Open Access Journals (Sweden)

    Matthieu Melot

    2011-01-01

    Full Text Available Numerical simulation of the arc-flow interaction in high-voltage circuit breakers requires a radiation model capable of handling high-temperature participating thermal plasmas. The modeling of the radiative transfer plays a critical role in the overall accuracy of such CFD simulations. As a result of the increase of computational power, CPU intensive methods based on the radiative transfer equation, leading to more accurate results, are now becoming attractive alternatives to current approximate models. In this paper, the predictive capabilities of the finite volume method (RTE-FVM and the P1 model are investigated. A systematic comparison between these two models and analytical solutions are presented for a variety of relevant test cases. Two implementations of each approach are compared, and a critical evaluation is presented.

  14. Design and Test of a Thermal Triggered Persistent Current System using High Temperature Superconducting Tapes

    Energy Technology Data Exchange (ETDEWEB)

    Park, Dong Keun [Department of Electrical and Electronic Engineering, Yonsei University, Shinchon-Dong 134, Seodaemun-Gu, Seoul 120-749 (Korea, Republic of); Kang, Hyoungku [Electro-Mechanical Research Institute, Hyundai Heavy Industries, Yongin (Korea, Republic of); Ahn, Min Cheol [Department of Electrical and Electronic Engineering, Yonsei University, Shinchon-Dong 134, Seodaemun-Gu, Seoul 120-749 (Korea, Republic of); Yang, Seong Eun [Department of Electrical and Electronic Engineering, Yonsei University, Shinchon-Dong 134, Seodaemun-Gu, Seoul 120-749 (Korea, Republic of); Yoon, Yong Soo [Department of Electrical Engineering, Ansan College of Technology, 671 Choji-Dong, Danwon-Gu, Ansan, 425-792 (Korea, Republic of); Lee, Sang Jin [Department of Electrical and Electronic Engineering, Yonsei University, Shinchon-Dong 134, Seodaemun-Gu, Seoul 120-749 (Korea, Republic of); Ko, Tae Kuk [Department of Electrical and Electronic Engineering, Yonsei University, Shinchon-Dong 134, Seodaemun-Gu, Seoul 120-749 (Korea, Republic of)

    2006-06-01

    A superconducting magnet which is operated in persistent current mode in SMES, NMR, MRI and MAGLEV has many advantages such as high uniformity of magnetic field and reduced thermal loss. A high temperature superconducting (HTS) persistent current switch (PCS) system was designed and tested in this research. The HTS PCS was optimally designed using two different HTS tapes, second generation coated conductor (CC) HTS tape and Bi-2223 HTS tape by the finite element method (FEM) in thermal quench characteristic view. The CC tape is more prospective applicable wire in these days for its high n value and critical current independency from external magnetic field than Bi-2223 tape. Also a prototype PCS system using Bi-2223 tape was manufactured and tested. The PCS system consists of a PCS part, a heater which induces the PCS to quench, and a superconducting magnet. The test was performed in various conditions of transport current. An initial current decay appeared when the superconducting magnet was energized in a PCS system was analyzed. This paper would be foundation of HTS PCS researches.

  15. The thermal expansion of a highly crystalline hexagonal BC2N compound synthesized under high temperature and pressure

    International Nuclear Information System (INIS)

    Wu Qinghua; Liu Zhongyuan; Hu Qianku; Li Hui; He Julong; Yu Dongli; Li Dongchun; Tian Yongjun

    2006-01-01

    The thermal expansion has been investigated for a highly crystalline hexagonal BC 2 N compound synthesized by the compression of a turbostratic B-C-N precursor with iron catalyst at the high temperature of 1500 deg. C and the high pressure of 5.5 GPa. The thermal expansion in the c direction is large and linear with an expansion coefficient of 35.86 x 10 -6 K -1 up to 1000 deg. C, while in the basal plane, the a dimension displays a slight linear contraction up to 750 deg. C with a contraction coefficient of -8.76 x 10 -7 K -1 , but above 750 deg. C a linear expansion is observed with a larger expansion coefficient of 1.52 x 10 -6 K -1

  16. Verification of High Temperature Free Atom Thermal Scattering in MERCURY Compared to TART

    International Nuclear Information System (INIS)

    Cullen, D E; McKinley, S; Hagmann, C

    2006-01-01

    This is part of a series of reports verifying the accuracy of the relatively new MERCURY [1] Monte Carlo particle transport code by comparing its results to those of the older TART [2] Monte Carlo particle transport code. In the future we hope to extend these comparisons to include deterministic (Sn) codes [3]. Here we verify the accuracy of the free atom thermal scattering model [4] by using it over a very large temperature range. We would like to be able to use these Monte Carlo codes for astrophysical applications, where the temperature of the medium can be extremely high compared to the temperatures we normally encounter in our terrestrial applications [5]. The temperature is so high that is it often defined in eV rather than Kelvin. For a correspondence between the two scale 293.6 Kelvin (room temperature) corresponds to 0.0253 eV ∼ 1/40 eV. So that 1 eV temperature is about 12,000 Kelvin, and 1 keV temperature is about 12 million Kelvin. Here we use a relatively small system measured in cm, but by using ρR scaling [6] our results are equally applicable to systems measured in Km or thousands of Km or any size that we need for astrophysical applications. The emphasis here is not on modeling any given real system, but rather in verifying the accuracy of the free atom model to represent theoretical results over a large temperature range. There are two primary objectives of this report: (1) Verify agreement between MERCURY and TART results, both using continuous energy cross sections. In particular we want to verify the free atom scattering treatment in MERCURY as used over an extended temperature range; by comparison to many other codes for TART this has already been verified over many years [4, 7]. (2) Demonstrate that this agreement depends on using continuous energy cross sections. To demonstrate this we also present TART using the Multi-Band method [8, 9], which accounts for resonance self-shielding, and Multi-Group method, without self-shielding [9

  17. Computational study of a high-temperature thermal nanoimprint lithographic (TNIL) process

    Science.gov (United States)

    Cleveland, Nicolas Joseph

    As an emerging manufacturing technique, nanoimprint lithography (NIL) can fabricate micro and nanoscale features of microfluidic devices at very high accuracy and reliability. The process parameters such as pressure, temperature, and material properties play critical roles in the NIL process. In this work, the process of thermal nanoimprint lithography (TNIL) is studied computationally and the developed model can accurately predict the nano and micro-pattern geometry and quality from TNIL processes based on complex mold-resist interaction. Applications of this modeling technique range from micro- and nano-patterns used in micro-channels for biomedical devices to other applications such as biological/particle sensors or superhydrophobic surfaces. In high-temperature TNIL process, a polymer melt such as polymethyl-methacrylate (PMMA) is heated beyond the melting temperature so that it behaves predominantly as a fluid during the imprint process. The effects of surface tension and shear thinning become significant at or above the melting point, whereas the polymer melt can be modeled as a viscoelastic solid, solved with finite element analysis, when process temperature remains between the glass transition and melting temperatures. Additionally, the mold used in TNIL can deform since it is made of soft-rubbery elastomer such as polydimethylsiloxane (PDMS), and it is of interest to include the effect of subsequent mold deformation. Leakage between channels or significant variation in channel width can occur in micro-fluidic devices if mold deformation exceeds design tolerances. In the current work, fluid-structure interaction (FSI) technology is leveraged to solve for significant mold deformation and its effect on the polymer melt flow field during TNIL process. The simulation result is compared to experimental results. The FSI simulation result is also compared to the equivalent case with a rigid mold in place of flexible material, which shows results of differing mold

  18. High-Temperature Wide Thermal Hysteresis of an Iron(II Dinuclear Double Helicate

    Directory of Open Access Journals (Sweden)

    Shiori Hora

    2017-07-01

    Full Text Available Two new dinuclear iron(II complexes (1·PF6 and 1·AsF6 of the general formula [FeII2(L2C32](X4·nH2O·mMeCN (X = PF6, n = m = 1.5 for 1·PF6 and X = AsF6, n = 3, m = 1 for 1·AsF6 have been prepared and structurally characterized, where L2C3 is a bis-1,2,3-triazolimine type Schiff-base ligand, 1,1′-[propane-1,3-diylbis(1H-1,2,3-triazole-1,4-diyl]bis{N-[2-(pyridin-2-ylethyl]methanimine}. Single crystal X-ray structure analyses revealed that 1·PF6 and 1·AsF6 are isostructural. The complex-cation [FeII2(L2C32]4+ of both has the same dinuclear double helicate architecture, in which each iron(II center has an N6 octahedral coordination environment. Neighboring helicates are connected by intermolecular π–π interactions to give a chiral one-dimensional (1D structure, and cationic 1D chains with the opposite chirality exist in the crystal lattice to give a heterochiral crystal. Magnetic and differential scanning calorimetry (DSC studies were performed only for 1·AsF6, since the thermal stability in a high-temperature spin crossover (SCO region of 1·PF6 is poorer than that of 1·AsF6. 1·AsF6 shows an unsymmetrical hysteretic SCO between the low-spin–low-spin (LS–LS and high-spin–high-spin (HS–HS states at above room temperature. The critical temperatures of warming (Tc↑ and cooling (Tc↓ modes in the abrupt spin transition area are 485 and 401 K, respectively, indicating the occurrence of 84 K-wide thermal hysteresis in the first thermal cycle.

  19. High-temperature thermal conductivity of uranium chromite and uranium niobate

    International Nuclear Information System (INIS)

    Fedoseev, D.V.; Varshavskaya, I.G.; Lavrent'ev, A.V.; Oziraner, S.N.; Kuznetsova, D.G.

    1979-01-01

    The technique of determining thermal conductivity coefficient of uranium niobate and uranium chromite on heating with laser radiation is described. Determined is the coefficient of free-convective heat transfer (with provision for a conduction component) by means of a standard specimen. The thermal conductivity coefficients of uranium chromite and niobate were measured in the 1300-1700 K temperature range. The results are presented in a diagram form. It has been calculated, that the thermal conductivity coefficient for uranium niobate specimens is greater in comparison with uranium chromite specimens. The thermal conductivity coefficients of the materials mentioned depend on temperature very slightly. Thermal conductivity of the materials considerably depends on their porosity. The specimens under investigation were fabricated by the pressing method and had the following porosity: uranium chromite - 30 %, uranium niobate - 10 %. Calculation results show, that thermal conductivity of dense uranium chromite is higher than thermal conductivity of dense uranium niobate. The experimental error equals approximately 20 %, that is mainly due to the error of measuring the temperature equal to +-25 deg, with a micropyrometer

  20. High Temperature Test Possibility at the HANARO Out-core Region through a Thermal Analysis

    International Nuclear Information System (INIS)

    Kang, Young-Hwan; Choi, Myung-Hwan; Cho, Man-Soon; Choo, Kee-Nam; Kim, Bong-Goo

    2007-01-01

    The development of an advanced reactor system such as a next generation nuclear plant and other generation IV systems require new fuels, claddings, and structural materials. To characterize the performance of these new materials, it is necessary for us to have a leading-edge technology to satisfy the specific test requirements such as the conditions of high neutron exposures and high operating temperatures. Thus, nuclear data on HANARO's vertical test holes have been gathered and reviewed to evaluate the usability of the test holes located at the out-core zone of HANARO. In 2007, neutron flux levels of the concerned test holes and the gamma heat of the specimens and two different specimen holder materials of Al and Mo at the concerned test hole were obtained to enhance the utilization of the HANARO reactor and to develop new design concepts for high temperature irradiation tests. Based on the data, a series of thermal analyses was implemented to provide a reasonable demonstration and guidance on limitations or application

  1. Cast thermally stable high temperature nickel-base alloys and casting made therefrom

    International Nuclear Information System (INIS)

    Acuncius, D.A.; Herchenroeder, R.B.; Kirchner, R.W.; Silence, W.L.

    1977-01-01

    A cast thermally stable high temperature nickel-base alloy characterized by superior oxidation resistance, sustainable hot strength and retention of ductility on aging is provided by maintaining the alloy chemistry within the composition molybdenum 13.7% to 15.5%; chromium 14.7% to 16.5%; carbon up to 0.1%, lanthanum in an effective amount to provide oxidation resistance up to 0.08%; boron up to 0.015%; manganese 0.3% to 1.0%; silicon 0.2% to 0.8%; cobalt up to 2.0%; iron up to 3.0%; tungsten up to 1.0%; copper up to 0.4%; phosphorous up to 0.02%; sulfur up to 0.015%; aluminum 0.1% to 0.5% and the balance nickel while maintaining the Nv number less than 2.31

  2. Thermal performance of an open thermosyphon using nanofluid for evacuated tubular high temperature air solar collector

    International Nuclear Information System (INIS)

    Liu, Zhen-Hua; Hu, Ren-Lin; Lu, Lin; Zhao, Feng; Xiao, Hong-shen

    2013-01-01

    Highlights: • A novel solar air collector with simplified CPC and open thermosyphon is designed and tested. • Simplified CPC has a much lower cost at the expense of slight efficiency loss. • Nanofluid effectively improves thermal performance of the above solar air collector. • Solar air collector with open thermosyphon is better than that with concentric tube. - Abstract: A novel evacuated tubular solar air collector integrated with simplified CPC (compound parabolic concentrator) and special open thermosyphon using water based CuO nanofluid as the working fluid is designed to provide air with high and moderate temperature. The experimental system has two linked panels and each panel includes an evacuated tube, a simplified CPC and an open thermosyphon. Outdoor experimental study has been carried out to investigate the actual solar collecting performance of the designed system. Experimental results show that air outlet temperature and system collecting efficiency of the solar air collector using nanofluid as the open thermosyphon’s working fluid are both higher than that using water. Its maximum air outlet temperature exceeds 170 °C at the air volume rate of 7.6 m 3 /h in winter, even though the experimental system consists of only two collecting panels. The solar collecting performance of the solar collector integrated with open thermosyphon is also compared with that integrated with common concentric tube. Experimental results show that the solar collector integrated with open thermosyphon has a much better collecting performance

  3. Microstructural characterization of thermal barrier coating on Inconel 617 after high temperature oxidation

    Directory of Open Access Journals (Sweden)

    Mohammadreza Daroonparvar

    2013-06-01

    Full Text Available A turbine blade was protected against high temperature corrosion and oxidation by thermal barrier coatings (TBCsusing atmospheric plasma spraying technique (APS on a Ni-based superalloy (Inconel 617. The coatings (NiCr6AlY/ YSZ and NiCr10AlY/YSZ consist of laminar structure with substantial interconnected porosity transferred oxygen from Yittria stabilized Zirconia (YSZ layer toward the bond coat (NiCrAlY. Hence, a thermally grown oxide layer (TGO was formed on the metallic bond coat and internal oxidation of the bond coat occurred during oxidation. The TBC systems were oxidized in a normal electrically heated furnace at 1150 °C for 18, 22, 26, 32 and 40h.Microstructural characterization of coatings demonstrated that the growth of the TGO layer on the nickel alloy with 6wt. % Al is more rapid than TGO with 10wt. % Al. In addition, many micro-cracks were observed at the interface of NiCr6AlY/YSZ. X-ray diffraction analysis (XRD showed the existence of detrimental oxides such as NiCr2O4, NiCrO3 and NiCrO4 in the bond coat containing 6wt. % Al, accompanied by rapid volume expansion causing the destruction of TBC. In contrast, in the bond coat with 10wt. % Al, NiO, Al2O3and Cr2O3 oxides were formed while very low volume expansion occurred. The oxygen could not penetrate into the TGO layer of bond coat with 10 wt. % Al during high temperature oxidation and the detrimental oxides were not extensively formed within the bond coat as more oxygen was needed. The YSZ with higher Al content showed higher oxidation resistance.

  4. [The physiological classification of human thermal states under high environmental temperatures].

    Science.gov (United States)

    Bobrov, A F; Kuznets, E I

    1995-01-01

    The paper deals with the physiological classification of human thermal states in a hot environment. A review of the basic systems of classifications of thermal states is given, their main drawbacks are discussed. On the basis of human functional state research in a broad range of environmental temperatures the system of evaluation and classification of human thermal states is proposed. New integral one-dimensional multi-parametric criteria for evaluation are used. For the development of these criteria methods of factor, cluster and canonical correlation analyses are applied. Stochastic nomograms capable of identification of human thermal state for different intensity of influence are given. In this case evaluation of intensity is estimated according to one-dimensional criteria taking into account environmental temperature, physical load and time of man's staying in overheating conditions.

  5. Microencapsulation of metal-based phase change material for high-temperature thermal energy storage.

    Science.gov (United States)

    Nomura, Takahiro; Zhu, Chunyu; Sheng, Nan; Saito, Genki; Akiyama, Tomohiro

    2015-03-13

    Latent heat storage using alloys as phase change materials (PCMs) is an attractive option for high-temperature thermal energy storage. Encapsulation of these PCMs is essential for their successful use. However, so far, technology for producing microencapsulated PCMs (MEPCMs) that can be used above 500°C has not been established. Therefore, in this study, we developed Al-Si alloy microsphere MEPCMs covered by α-Al2O3 shells. The MEPCM was prepared in two steps: (1) the formation of an AlOOH shell on the PCM particles using a boehmite treatment, and (2) heat-oxidation treatment in an O2 atmosphere to form a stable α-Al2O3 shell. The MEPCM presented a melting point of 573°C and latent heat of 247 J g(-1). The cycling performance showed good durability. These results indicated the possibility of using MEPCM at high temperatures. The MEPCM developed in this study has great promise in future energy and chemical processes, such as exergy recuperation and process intensification.

  6. WESF cesium capsule behavior at high temperature or during thermal cycling

    International Nuclear Information System (INIS)

    Tingey, G.L.; Gray, W.J.; Shippell, R.J.; Katayama, Y.B.

    1985-06-01

    Double-walled stainless steel (SS) capsules prepared for storage of radioactive 137 Cs from defense waste are now being considered for use as sources for commercial irradiation. Cesium was recovered at B-plant from the high-level radioactive waste generated during processing of defense nuclear fuel. It was then purified, converted to the chloride form, and encapsulated at the Hanford Waste Encapsulation and Storage Facility (WESF). The molten cesium chloride salt was encapsulated by pouring it into the inner of two concentric SS cylinders. Each cylinder was fitted with a SS end cap that was welded in place by inert gas-tungsten arc welding. The capsule configuration and dimensions are shown in Figure 1. In a recent review of the safety of these capsules, Tingey, Wheelwright, and Lytle (1984) indicated that experimental studies were continuing to produce long-term corrosion data, to reaffirm capsule integrity during a 90-min fire where capsule temperatures reached 800 0 C, to monitor mechanical properties as a function of time, and to assess the effects of thermal cycling due to periodic transfer of the capsules from a water storage pool to the air environment of an irradiator facility. This report covers results from tests that simulated the effects of the 90-min fire and from thermal cycling actual WESF cesium capsules for 3845 cycles over a period of six months. 11 refs., 39 figs., 9 tabs

  7. A High Temperature Kinetic Study for the Thermal Unimolecular Decomposition of Diethyl Carbonate

    KAUST Repository

    Alabbad, Mohammed

    2017-07-08

    Thermal unimolecular decomposition of diethyl carbonate (DEC) was investigated in a shock tube by measuring ethylene concentration with a CO2 gas laser over 900 - 1200 K and 1.2 – 2.8 bar. Rate coefficients were extracted using a simple kinetic scheme comprising of thermal decomposition of DEC as initial step followed by rapid thermal decomposition of the intermediate ethyl-hydrogen-carbonate. Our results were further analysed using ab initio and master equation calculations to obtain pressure- and temperature- dependence of rate coefficients. Similar to alkyl esters, unimolecular decomposition of DEC is found to undergo six-center retro-ene elimination of ethylene in a concerted manner.

  8. A High Temperature Kinetic Study for the Thermal Unimolecular Decomposition of Diethyl Carbonate

    KAUST Repository

    Alabbad, Mohammed; Giri, Binod; Szőri, Milan; Viskolcz, Bé la; Farooq, Aamir

    2017-01-01

    Thermal unimolecular decomposition of diethyl carbonate (DEC) was investigated in a shock tube by measuring ethylene concentration with a CO2 gas laser over 900 - 1200 K and 1.2 – 2.8 bar. Rate coefficients were extracted using a simple kinetic scheme comprising of thermal decomposition of DEC as initial step followed by rapid thermal decomposition of the intermediate ethyl-hydrogen-carbonate. Our results were further analysed using ab initio and master equation calculations to obtain pressure- and temperature- dependence of rate coefficients. Similar to alkyl esters, unimolecular decomposition of DEC is found to undergo six-center retro-ene elimination of ethylene in a concerted manner.

  9. High-temperature Raman study of L-alanine, L-threonine and taurine crystals related to thermal decomposition

    Energy Technology Data Exchange (ETDEWEB)

    Cavaignac, A.L.O. [Centro de Ciências Sociais, Saúde e Tecnologia, Universidade Federal do Maranhão, Imperatriz, MA 65900-410 (Brazil); Lima, R.J.C., E-mail: ricardo.lima.ufma@gmail.com [Centro de Ciências Sociais, Saúde e Tecnologia, Universidade Federal do Maranhão, Imperatriz, MA 65900-410 (Brazil); Façanha Filho, P.F. [Centro de Ciências Sociais, Saúde e Tecnologia, Universidade Federal do Maranhão, Imperatriz, MA 65900-410 (Brazil); Moreno, A.J.D. [Coordenação de Ciências Naturais, Universidade Federal do Maranhão, Bacabal, MA 65700-000 (Brazil); Freire, P.T.C. [Departamento de Física, Universidade Federal do Ceará, Fortaleza, CE 60455-760 (Brazil)

    2016-03-01

    In this work high-temperature Raman spectra are used to compare temperature dependence of the lattice mode wavenumber of L-alanine, L-threonine and taurine crystals. Anharmonic effects observed are associated with intermolecular N-H· · ·O hydrogen bond that plays an important role in thermal decomposition process of these materials. Short and strong hydrogen bonds in L-alanine crystal were associated with anharmonic effects in lattice modes leading to low thermal stability compared to taurine crystals. Connection between thermal decomposition process and anharmonic effects is furnished for the first time.

  10. High-temperature Raman study of L-alanine, L-threonine and taurine crystals related to thermal decomposition

    International Nuclear Information System (INIS)

    Cavaignac, A.L.O.; Lima, R.J.C.; Façanha Filho, P.F.; Moreno, A.J.D.; Freire, P.T.C.

    2016-01-01

    In this work high-temperature Raman spectra are used to compare temperature dependence of the lattice mode wavenumber of L-alanine, L-threonine and taurine crystals. Anharmonic effects observed are associated with intermolecular N-H· · ·O hydrogen bond that plays an important role in thermal decomposition process of these materials. Short and strong hydrogen bonds in L-alanine crystal were associated with anharmonic effects in lattice modes leading to low thermal stability compared to taurine crystals. Connection between thermal decomposition process and anharmonic effects is furnished for the first time.

  11. Theoretical Research on Thermal Shock Resistance of Ultra-High Temperature Ceramics Focusing on the Adjustment of Stress Reduction Factor

    Directory of Open Access Journals (Sweden)

    Daining Fang

    2013-02-01

    Full Text Available The thermal shock resistance of ceramics depends on not only the mechanical and thermal properties of materials, but also the external constraint and thermal condition. So, in order to study the actual situation in its service process, a temperature-dependent thermal shock resistance model for ultra-high temperature ceramics considering the effects of the thermal environment and external constraint was established based on the existing theory. The present work mainly focused on the adjustment of the stress reduction factor according to different thermal shock situations. The influences of external constraint on both critical rupture temperature difference and the second thermal shock resistance parameter in either case of rapid heating or cooling conditions had been studied based on this model. The results show the necessity of adjustment of the stress reduction factor in different thermal shock situations and the limitations of the applicable range of the second thermal shock resistance parameter. Furthermore, the model was validated by the finite element method.

  12. High-accuracy CFD prediction methods for fluid and structure temperature fluctuations at T-junction for thermal fatigue evaluation

    Energy Technology Data Exchange (ETDEWEB)

    Qian, Shaoxiang, E-mail: qian.shaoxiang@jgc.com [EN Technology Center, Process Technology Division, JGC Corporation, 2-3-1 Minato Mirai, Nishi-ku, Yokohama 220-6001 (Japan); Kanamaru, Shinichiro [EN Technology Center, Process Technology Division, JGC Corporation, 2-3-1 Minato Mirai, Nishi-ku, Yokohama 220-6001 (Japan); Kasahara, Naoto [Nuclear Engineering and Management, School of Engineering, The University of Tokyo, 7-3-1 Hongo, Bunkyo-ku, Tokyo 113-8656 (Japan)

    2015-07-15

    Highlights: • Numerical methods for accurate prediction of thermal loading were proposed. • Predicted fluid temperature fluctuation (FTF) intensity is close to the experiment. • Predicted structure temperature fluctuation (STF) range is close to the experiment. • Predicted peak frequencies of FTF and STF also agree well with the experiment. • CFD results show the proposed numerical methods are of sufficiently high accuracy. - Abstract: Temperature fluctuations generated by the mixing of hot and cold fluids at a T-junction, which is widely used in nuclear power and process plants, can cause thermal fatigue failure. The conventional methods for evaluating thermal fatigue tend to provide insufficient accuracy, because they were developed based on limited experimental data and a simplified one-dimensional finite element analysis (FEA). CFD/FEA coupling analysis is expected as a useful tool for the more accurate evaluation of thermal fatigue. The present paper aims to verify the accuracy of proposed numerical methods of simulating fluid and structure temperature fluctuations at a T-junction for thermal fatigue evaluation. The dynamic Smagorinsky model (DSM) is used for large eddy simulation (LES) sub-grid scale (SGS) turbulence model, and a hybrid scheme (HS) is adopted for the calculation of convective terms in the governing equations. Also, heat transfer between fluid and structure is calculated directly through thermal conduction by creating a mesh with near wall resolution (NWR) by allocating grid points within the thermal boundary sub-layer. The simulation results show that the distribution of fluid temperature fluctuation intensity and the range of structure temperature fluctuation are remarkably close to the experimental results. Moreover, the peak frequencies of power spectrum density (PSD) of both fluid and structure temperature fluctuations also agree well with the experimental results. Therefore, the numerical methods used in the present paper are

  13. Thermal and nonthermal electron cyclotron emission by high-temperature tokamak plasmas

    International Nuclear Information System (INIS)

    Airoldi, A.; Ramponi, G.

    1997-01-01

    An analysis of the electron cyclotron emission (ECE) spectra emitted by a high-temperature tokamak plasma in the frequency range of the second and third harmonic of the electron cyclotron frequency is made, both in purely Maxwellian and in non-Maxwellian cases (i.e., in the presence of a current-carrying superthermal tail). The work is motivated mainly by the experimental observations made in the supershot plasmas of the Tokamak Fusion Test Reactor (TFTR), where a systematic disagreement is found between the T e measurements by second-harmonic ECE and Thomson scattering. We show that, by properly taking into account the overlap of superthermals-emitted third harmonic with second-harmonic bulk emission, the radiation temperature observed about the central frequency of the second harmonic may be enhanced up to 30%endash 40% compared to the corresponding thermal value. Moreover we show that, for parameters relevant to the International Thermonuclear Experimental Reactor (ITER) with T e (0)>7 keV, the overlap between the second and the downshifted third harmonic seriously affects the central plasma region, so that the X-mode emission at the second harmonic becomes unsuitable for local T e measurements. copyright 1997 American Institute of Physics

  14. Enhancing thermal reliability of fiber-optic sensors for bio-inspired applications at ultra-high temperatures

    International Nuclear Information System (INIS)

    Kang, Donghoon; Kim, Heon-Young; Kim, Dae-Hyun

    2014-01-01

    The rapid growth of bio-(inspired) sensors has led to an improvement in modern healthcare and human–robot systems in recent years. Higher levels of reliability and better flexibility, essential features of these sensors, are very much required in many application fields (e.g. applications at ultra-high temperatures). Fiber-optic sensors, and fiber Bragg grating (FBG) sensors in particular, are being widely studied as suitable sensors for improved structural health monitoring (SHM) due to their many merits. To enhance the thermal reliability of FBG sensors, thermal sensitivity, generally expressed as α f + ξ f and considered a constant, should be investigated more precisely. For this purpose, the governing equation of FBG sensors is modified using differential derivatives between the wavelength shift and the temperature change in this study. Through a thermal test ranging from RT to 900 °C, the thermal sensitivity of FBG sensors is successfully examined and this guarantees thermal reliability of FBG sensors at ultra-high temperatures. In detail, α f + ξ f has a non-linear dependence on temperature and varies from 6.0 × 10 −6  °C −1 (20 °C) to 10.6 × 10 −6  °C −1 (650 °C). Also, FBGs should be carefully used for applications at ultra-high temperatures due to signal disappearance near 900 °C. (paper)

  15. Enhancing thermal reliability of fiber-optic sensors for bio-inspired applications at ultra-high temperatures

    Science.gov (United States)

    Kang, Donghoon; Kim, Heon-Young; Kim, Dae-Hyun

    2014-07-01

    The rapid growth of bio-(inspired) sensors has led to an improvement in modern healthcare and human-robot systems in recent years. Higher levels of reliability and better flexibility, essential features of these sensors, are very much required in many application fields (e.g. applications at ultra-high temperatures). Fiber-optic sensors, and fiber Bragg grating (FBG) sensors in particular, are being widely studied as suitable sensors for improved structural health monitoring (SHM) due to their many merits. To enhance the thermal reliability of FBG sensors, thermal sensitivity, generally expressed as αf + ξf and considered a constant, should be investigated more precisely. For this purpose, the governing equation of FBG sensors is modified using differential derivatives between the wavelength shift and the temperature change in this study. Through a thermal test ranging from RT to 900 °C, the thermal sensitivity of FBG sensors is successfully examined and this guarantees thermal reliability of FBG sensors at ultra-high temperatures. In detail, αf + ξf has a non-linear dependence on temperature and varies from 6.0 × 10-6 °C-1 (20 °C) to 10.6 × 10-6 °C-1 (650 °C). Also, FBGs should be carefully used for applications at ultra-high temperatures due to signal disappearance near 900 °C.

  16. High-flux/high-temperature solar thermal conversion: technology development and advanced applications

    OpenAIRE

    Romero Manuel; González-Aguilar José

    2016-01-01

    Solar Thermal Power Plants have generated in the last 10 years a dynamic market for renewable energy industry and a pro-active networking within R&D community worldwide. By end 2015, there are about 5 GW installed in the world, most of them still concentrated in only two countries, Spain and the US, though a rapid process of globalization is taking place in the last few years and now ambitious market deployment is starting in countries like South Africa, Chile, Saudi Arabia, India, United Ara...

  17. Thermal Degradation Study of IM7/DMBZ-15 High Temperature Composite by TGA/FTIR

    National Research Council Canada - National Science Library

    Nadler, Melvin

    2003-01-01

    (U) High temperature graphite composites such as IM7/8552 epoxy, IM7/5250 BMI, and IM7/DMBZ-15 polyimide show blistering and/or "catastrophic" delamination when rapidly heated to temperatures above...

  18. Numerical method for analysis of temperature rises and thermal stresses around high level radioactive waste repository in granite

    International Nuclear Information System (INIS)

    Shimooka, Hiroshi

    1982-01-01

    The disposal of high-level radioactive waste should result in temperature rises and thermal stresses which change the hydraulic conductivity of the rock around the repository. For safety analysis on disposal of high-level radioactive waste into hard rock, it is necessary to find the temperature rises and thermal stresses distributions around the repository. In this paper, these distribution changes are analyzed by the use of the finite difference method. In advance of numerical analysis, it is required to simplify the shapes and properties of the repository and the rock. Several kinds of numerical models are prepared, and the results of this analysis are examined. And, the waste disposal methods are discussed from the stand-points of the temperature rise and thermal stress analysis. (author)

  19. Nuclear Engineering Computer Modules, Thermal-Hydraulics, TH-3: High Temperature Gas Cooled Reactor Thermal-Hydraulics.

    Science.gov (United States)

    Reihman, Thomas C.

    This learning module is concerned with the temperature field, the heat transfer rates, and the coolant pressure drop in typical high temperature gas-cooled reactor (HTGR) fuel assemblies. As in all of the modules of this series, emphasis is placed on developing the theory and demonstrating its use with a simplified model. The heart of the module…

  20. Numerical study of finned heat pipe-assisted thermal energy storage system with high temperature phase change material

    International Nuclear Information System (INIS)

    Tiari, Saeed; Qiu, Songgang; Mahdavi, Mahboobe

    2015-01-01

    Highlights: • A finned heat pipe-assisted latent heat thermal energy storage system is studied. • The effects of heat pipes spacing and fins geometrical features are investigated. • Smaller heat pipes spacing and longer fins improve the melting rate. • The optimal heat pipe and fin arrangements are determined. - Abstract: In the present study, the thermal characteristics of a finned heat pipe-assisted latent heat thermal energy storage system are investigated numerically. A transient two-dimensional finite volume based model employing enthalpy-porosity technique is implemented to analyze the performance of a thermal energy storage unit with square container and high melting temperature phase change material. The effects of heat pipe spacing, fin length and numbers and the influence of natural convection on the thermal response of the thermal energy storage unit have been studied. The obtained results reveal that the natural convection has considerable effect on the melting process of the phase change material. Increasing the number of heat pipes (decreasing the heat pipe spacing) leads to the increase of melting rate and the decrease of base wall temperature. Also, the increase of fin length results in the decrease of temperature difference within the phase change material in the container, providing more uniform temperature distribution. It was also shown that number of the fins does not have a significant effect on the performance of the system

  1. High-temperature multiphase flowmeters in heavy-oil thermal production

    Energy Technology Data Exchange (ETDEWEB)

    Mehdizadeh, P. [Society of Petroleum Engineers, Richardson, TX (United States)]|[Production Technology Inc. (United States)

    2005-11-01

    A review of field tests assessing the capability and advantages of multi-phase metering technology in high temperature thermal recovery processes such as cyclic steam stimulation (CSS) and steam assisted gravity drainage (SAGD) was presented. A number of different tank gauging procedures were conducted to obtain a reference flow rate. Subsequent performance tests of metered data and tank data verified the accuracy of the meter, and that water cut sampling can be attained under practical field conditions. A 12 well field test was then conducted, and an allocation factor was obtained from conventional test separators and production measurements. An improvement in the allocation factor was noted. However, a full evaluation of the multiphase meter data obtained in the field was limited by the quality of the reference field data. A 30 day well testing campaign showed a comparison of well rate data from the multi-phase meter with data from an emulsion meter. It was concluded that the multiphase meter provided consistent measurements, matching the level of accuracy attained from rigorous tank measurements. In addition, the multiphase meter eliminated the need for the equipment modifications and extra personnel interventions needed to perform tank testing and manual and automatic water cut sampling. 15 refs., 2 tabs., 6 figs.

  2. A high temperature ceramic heat exchanger element for a solar thermal receiver

    Science.gov (United States)

    Strumpf, H. J.; Kotchick, D. M.; Coombs, M. G.

    1982-01-01

    The development of a high-temperature ceramic heat exchanger element to be integrated into a solar receiver producing heated air was studied. A number of conceptual designs were developed for heat exchanger elements of differing configuration. These were evaluated with respect to thermal performance, pressure drop, structural integrity, and fabricability. The final design selection identified a finned ceramic shell as the most favorable concept. The shell is surrounded by a larger metallic shell. The flanges of the two shells are sealed to provide a leak-tight pressure vessel. The ceramic shell is to be fabricated by a innovative combination of slip casting the receiver walls and precision casting the heat transfer finned plates. The fins are bonded to the shell during firing. The unit is sized to produce 2150 F air at 2.7 atm pressure, with a pressure drop of about 2 percent of the inlet pressure. This size is compatible with a solar collector providing a receiver input of 85 kw(th). Fabrication of a one-half scale demonstrator ceramic receiver was completed.

  3. High-temperature ceramic heat exchanger element for a solar thermal receiver

    Science.gov (United States)

    Strumpf, H. J.; Kotchick, D. M.; Coombs, M. G.

    1982-01-01

    A study was performed by AiResearch Manufacturing Company, a division of The Garrett Corporation, on the development a high-temperature ceramic heat exchanger element to be integrated into a solar receiver producing heated air. A number of conceptual designs were developed for heat exchanger elements of differing configuration. These were evaluated with respect to thermal performance, pressure drop, structural integrity, and fabricability. The final design selection identified a finned ceramic shell as the most favorable concept. The shell is surrounded by a larger metallic shell. The flanges of the two shells are sealed to provide a leak-tight pressure vessel. The ceramic shell is to be fabricated by an innovative combination of slip casting the receiver walls and precision casting the heat transfer finned plates. The fins are bonded to the shell during firing. The unit is sized to produce 2150 F ar at 2.7 atm pressure, with a pressure drop of about 2 percent of the inlet pressure. This size is compatible with a solar collector providing a receiver input of 85 kw(th). Fabrication of a one-half scale demonstrator ceramic receiver has been completed.

  4. Energy and exergy analyses of medium temperature latent heat thermal storage with high porosity metal matrix

    International Nuclear Information System (INIS)

    Kumar, Ashish; Saha, Sandip K.

    2016-01-01

    Graphical abstract: I. Metal matrix is used as the thermal conductivity enhancers (TCE) in PCM-based TES. II. Time evolution second law analysis is evaluated for different porosities and pore diameters. III. Reduction in fluctuation in HTF temperature is significantly affected by the change in porosity (ε) shown in figure. IV. Maximum energy and exergy efficiencies are obtained for porosity of 0.85. V. Effect of pore diameter on first law and second law efficiencies is found to be marginal. - Abstract: Thermal energy storage system in a concentrating solar plant (CSP) reduces the gap between energy demand and supply caused by the intermittent behaviour of solar radiation. In this paper, detailed exergy and energy analyses of shell and tube type latent heat thermal storage system (LHTES) for medium temperature solar thermal power plant (∼200 °C) are performed to estimate the net useful energy during the charging and discharging period in a cycle. A commercial-grade organic phase change material (PCM) is stored inside the annular space of the shell and the heat transfer fluid (HTF) flows through the tubes. Thermal conductivity enhancer (TCE) in the form of metal matrix is embedded in PCM to augment heat transfer. A numerical model is developed to investigate the fluid flow and heat transfer characteristics using the momentum equation and the two-temperature non-equilibrium energy equation coupled with the enthalpy method to account for phase change in PCM. The effects of storage material, porosity and pore-diameter on the net useful energy that can be stored and released during a cycle, are studied. It is found that the first law efficiency of sensible heat storage system is less compared to LHTES. With the decrease in porosity, the first law and second law efficiencies of LHTES increase for both the charging and discharging period. There is no significant variation in energy and exergy efficiencies with the change in pore-diameter of the metal matrix.

  5. Mathematical model for creep and thermal shrinkage of concrete at high temperature

    International Nuclear Information System (INIS)

    Bazant, Z.P.

    1983-01-01

    Based on the existing limited test data, it is possible to set up an approximate constitutive model for creep and shrinkage at temperatures above 100 0 C, up to about 400 0 C. The model presented here describes the effect of various constant temperatures on the creep rate and the rate of aging, similar effects of the specific water content, the creep increase caused by simultaneous changes in moisture content, the thermal volume changes as well as the volume changes caused by changes in moisture content (drying shrinkage or thermal shrinkage), and the effect of pore pressure produced by heating. Generalizations to time-variable stresses and multiaxial stresses are also given. The model should allow more realistic analysis of reactor vessels and containments for accident situations, of concrete structures subjected to fire, of vessels for coal gasification or liquefaction, etc. (orig.)

  6. Interplay of Interfacial Layers and Blend Composition To Reduce Thermal Degradation of Polymer Solar Cells at High Temperature.

    Science.gov (United States)

    Ben Dkhil, Sadok; Pfannmöller, Martin; Schröder, Rasmus R; Alkarsifi, Riva; Gaceur, Meriem; Köntges, Wolfgang; Heidari, Hamed; Bals, Sara; Margeat, Olivier; Ackermann, Jörg; Videlot-Ackermann, Christine

    2018-01-31

    The thermal stability of printed polymer solar cells at elevated temperatures needs to be improved to achieve high-throughput fabrication including annealing steps as well as long-term stability. During device processing, thermal annealing impacts both the organic photoactive layer, and the two interfacial layers make detailed studies of degradation mechanism delicate. A recently identified thermally stable poly[[4,8-bis[(2-ethylhexyl)oxy]benzo[1,2-b:4,5-b']dithiophene-2,6-diyl][3-fluoro-2-[(2-ethylhexyl)carbonyl]thieno[3,4-b]thiophenediyl

  7. Investigation of the thermal expansion of the refractory materials at high temperatures

    Science.gov (United States)

    Kostanovskiy, A.; Kostanovskaya, M.; Zeodinov, M.; Pronkin, A.

    2017-11-01

    We present the experimental investigation of the relative elongation and the coefficient of linear thermal expansion for monocrystaline alumina Al2O3 (1200 K - 1860 K), zirconia ZrO2 (1200 K - 2730 K) and siliconized silicon carbide SiC+Si (1150 K - 2500 K) in the specified range of temperatures. The following approach is used to measure the relative elongation: the through-cylindrical-marks located in the centre of isothermal part of the sample, and the measurement of temperature by two blackbody models, taken out of the area of the sample where the relative elongation is measured.

  8. THR-TH: a high-temperature gas-cooled nuclear reactor core thermal hydraulics code

    Energy Technology Data Exchange (ETDEWEB)

    Vondy, D.R.

    1984-07-01

    The ORNL version of PEBBLE, the (RZ) pebble bed thermal hydraulics code, has been extended for application to a prismatic gas cooled reactor core. The supplemental treatment is of one-dimensional coolant flow in up to a three-dimensional core description. Power density data from a neutronics and exposure calculation are used as the basic information for the thermal hydraulics calculation of heat removal. Two-dimensional neutronics results may be expanded for a three-dimensional hydraulics calculation. The geometric description for the hydraulics problem is the same as used by the neutronics code. A two-dimensional thermal cell model is used to predict temperatures in the fuel channel. The capability is available in the local BOLD VENTURE computation system for reactor core analysis with capability to account for the effect of temperature feedback by nuclear cross section correlation. Some enhancements have also been added to the original code to add pebble bed modeling flexibility and to generate useful auxiliary results. For example, an estimate is made of the distribution of fuel temperatures based on average and extreme conditions regularly calculated at a number of locations.

  9. THR-TH: a high-temperature gas-cooled nuclear reactor core thermal hydraulics code

    International Nuclear Information System (INIS)

    Vondy, D.R.

    1984-07-01

    The ORNL version of PEBBLE, the (RZ) pebble bed thermal hydraulics code, has been extended for application to a prismatic gas cooled reactor core. The supplemental treatment is of one-dimensional coolant flow in up to a three-dimensional core description. Power density data from a neutronics and exposure calculation are used as the basic information for the thermal hydraulics calculation of heat removal. Two-dimensional neutronics results may be expanded for a three-dimensional hydraulics calculation. The geometric description for the hydraulics problem is the same as used by the neutronics code. A two-dimensional thermal cell model is used to predict temperatures in the fuel channel. The capability is available in the local BOLD VENTURE computation system for reactor core analysis with capability to account for the effect of temperature feedback by nuclear cross section correlation. Some enhancements have also been added to the original code to add pebble bed modeling flexibility and to generate useful auxiliary results. For example, an estimate is made of the distribution of fuel temperatures based on average and extreme conditions regularly calculated at a number of locations

  10. Surface Temperature Mapping of the University of Northern Iowa Campus Using High Resolution Thermal Infrared Aerial Imageries

    Directory of Open Access Journals (Sweden)

    Ramanathan Sugumaran

    2008-08-01

    Full Text Available The goal of this project was to map the surface temperature of the University of Northern Iowa campus using high-resolution thermal infrared aerial imageries. A thermal camera with a spectral bandwidth of 3.0-5.0 μm was flown at the average altitude of 600 m, achieving ground resolution of 29 cm. Ground control data was used to construct the pixelto-temperature conversion model, which was later used to produce temperature maps of the entire campus and also for validation of the model. The temperature map then was used to assess the building rooftop conditions and steam line faults in the study area. Assessment of the temperature map revealed a number of building structures that may be subject to insulation improvement due to their high surface temperatures leaks. Several hot spots were also identified on the campus for steam pipelines faults. High-resolution thermal infrared imagery proved highly effective tool for precise heat anomaly detection on the campus, and it can be used by university facility services for effective future maintenance of buildings and grounds.

  11. Surface Temperature Mapping of the University of Northern Iowa Campus Using High Resolution Thermal Infrared Aerial Imageries

    Science.gov (United States)

    Savelyev, Alexander; Sugumaran, Ramanathan

    2008-01-01

    The goal of this project was to map the surface temperature of the University of Northern Iowa campus using high-resolution thermal infrared aerial imageries. A thermal camera with a spectral bandwidth of 3.0-5.0 μm was flown at the average altitude of 600 m, achieving ground resolution of 29 cm. Ground control data was used to construct the pixel- to-temperature conversion model, which was later used to produce temperature maps of the entire campus and also for validation of the model. The temperature map then was used to assess the building rooftop conditions and steam line faults in the study area. Assessment of the temperature map revealed a number of building structures that may be subject to insulation improvement due to their high surface temperatures leaks. Several hot spots were also identified on the campus for steam pipelines faults. High-resolution thermal infrared imagery proved highly effective tool for precise heat anomaly detection on the campus, and it can be used by university facility services for effective future maintenance of buildings and grounds. PMID:27873800

  12. High temperature resistant cermet and ceramic compositions. [for thermal resistant insulators and refractory coatings

    Science.gov (United States)

    Phillips, W. M. (Inventor)

    1978-01-01

    High temperature oxidation resistance, high hardness and high abrasion and wear resistance are properties of cermet compositions particularly to provide high temperature resistant refractory coatings on metal substrates, for use as electrical insulation seals for thermionic converters. The compositions comprise a sintered body of particles of a high temperature resistant metal or metal alloy, preferably molybdenum or tungsten particles, dispersed in and bonded to a solid solution formed of aluminum oxide and silicon nitride, and particularly a ternary solid solution formed of a mixture of aluminum oxide, silicon nitride and aluminum nitride. Ceramic compositions comprising a sintered solid solution of aluminum oxide, silicon nitride and aluminum nitride are also described.

  13. Design, Fabrication, Test Report of the Material Capsule(08M-10K) with Double Thermal Media for High-temperature Irradiation

    International Nuclear Information System (INIS)

    Cho, Man Soon; Choo, K. N.; Kang, Y. H.; Sohn, J. M.; Shin, Y. T.; Park, S. J.; Kim, B. G.; Oh, S. Y.

    2010-01-01

    To overcome the restriction of the irradiation test at a high temperature of the existing material capsule with Al thermal media, a capsule suitable for the irradiation at the high temperature was developed and the performance test was undertaken. The 08M-10K capsule was designed and fabricated as that with double thermal media to verify the structural and external integrity in the high-temperature irradiation higher than 500 .deg. C. The thermal performance test was undertaken at the out-pile test facility, and the soundness of the double thermal media was confirmed with the naked eye after disassembling the capsule. Though the temperatures of the specimens reach 500±20 .deg. C as a result maintaining the capsule during 5 hours after setting the specimens temperatures in the target range, the high-temperature thermal media with double structure was confirmed to maintain the soundness. And the specimens and the thermal media were heated to 600 .deg. C for about 3 minutes, but the thermal media were maintained sound. Especially, the Al thermal media were heated for 5 hours in range of 500±20 .deg. C and for 3 minutes at the temperature of 600 .deg. C. However, the thermal media were confirmed to maintain the soundness. Whether a capsule has only Al thermal media or the high-temperature thermal media with double structure, any capsule can be used in the range of 500±20 .deg. C as the result of this experiment maintaining the specimens high-temperature

  14. Metal temperature monitoring in corrosive gases at high temperature and high thermal flows; Monitoreo de temperaturas de metal en gases corrosivos a alta temperatura y altos flujos termicos

    Energy Technology Data Exchange (ETDEWEB)

    Huerta Espino, Mario; Martinez Flores, Marco Antonio; Martinez Villafane, Alberto; Porcayo Calderon, Jesus; Gomez Guzman, Roberto; Reyes Cervantes, Fernando [Instituto de Investigaciones Electricas, Cuernavaca (Mexico)

    1990-12-31

    The direct measurement of metal temperatures during operation in superheater, reheater, and water wall tubes in zones exposed to high thermal flows is of great interest for the operation and analysis of the correct functioning of a steam generator. The operation temperature measurement of these zones differs very much of the monitored temperature in headers in the dead chamber, since the temperature measured in this zone is the steam temperature that does not reflect the one detected in the gas zone. For this reason, the thermocouples implant in gas zones will detect the real metal temperature and the incidence that some operation variables might have on it (Martinez et al., (1990). [Espanol] La medicion directa de temperaturas de metal durante operacion en tubos de sobrecalentador, recalentador y pared de agua en zonas expuestas a altos flujos termicos es de gran interes para la operacion y analisis del buen funcionamiento de un generador de vapor. La medicion de la temperatura de operacion de estas zonas, difiere mucho de la temperatura monitoreada en cabezales en zona de camara muerta, ya que la temperatura registrada en esta zona es la de vapor que no es un reflejo de la detectada en zona de gases. Por esta razon, la implantacion de termopares en zona de gases detectara la temperatura de metal real y la incidencia que algunas variables de operacion tengan sobre esta (Martinez et al., 1990).

  15. Metal temperature monitoring in corrosive gases at high temperature and high thermal flows; Monitoreo de temperaturas de metal en gases corrosivos a alta temperatura y altos flujos termicos

    Energy Technology Data Exchange (ETDEWEB)

    Huerta Espino, Mario; Martinez Flores, Marco Antonio; Martinez Villafane, Alberto; Porcayo Calderon, Jesus; Gomez Guzman, Roberto; Reyes Cervantes, Fernando [Instituto de Investigaciones Electricas, Cuernavaca (Mexico)

    1991-12-31

    The direct measurement of metal temperatures during operation in superheater, reheater, and water wall tubes in zones exposed to high thermal flows is of great interest for the operation and analysis of the correct functioning of a steam generator. The operation temperature measurement of these zones differs very much of the monitored temperature in headers in the dead chamber, since the temperature measured in this zone is the steam temperature that does not reflect the one detected in the gas zone. For this reason, the thermocouples implant in gas zones will detect the real metal temperature and the incidence that some operation variables might have on it (Martinez et al., (1990). [Espanol] La medicion directa de temperaturas de metal durante operacion en tubos de sobrecalentador, recalentador y pared de agua en zonas expuestas a altos flujos termicos es de gran interes para la operacion y analisis del buen funcionamiento de un generador de vapor. La medicion de la temperatura de operacion de estas zonas, difiere mucho de la temperatura monitoreada en cabezales en zona de camara muerta, ya que la temperatura registrada en esta zona es la de vapor que no es un reflejo de la detectada en zona de gases. Por esta razon, la implantacion de termopares en zona de gases detectara la temperatura de metal real y la incidencia que algunas variables de operacion tengan sobre esta (Martinez et al., 1990).

  16. The use of salinity contrast for density difference compensation to improve the thermal recovery efficiency in high-temperature aquifer thermal energy storage systems

    NARCIS (Netherlands)

    van Lopik, J.H.; Hartog, N.; Zaadnoordijk, Willem Jan

    The efficiency of heat recovery in high-temperature (>60 °C) aquifer thermal energy storage (HT-ATES) systems is limited due to the buoyancy of the injected hot water. This study investigates the potential to improve the efficiency through compensation of the density difference by increased salinity

  17. Conceptual market potential framework of high temperature aquifer thermal energy storage - A case study in the Netherlands

    NARCIS (Netherlands)

    Wesselink, Maxim; Liu, Wen; Koornneef, Joris; van den Broek, Machteld

    2018-01-01

    High temperature aquifer thermal energy storage (HT-ATES) can contribute to the integration of renewable energy sources in the energy system, the replacement of fossil fuel-based heat supply and the utilization of surplus heat from industrial sources. However, there is limited understanding on the

  18. Lattice Thermal Conductivity of Ultra High Temperature Ceramics ZrB2 and HfB2 from Atomistic Simulations

    Science.gov (United States)

    Lawson, John W.; Murray, Daw S.; Bauschlicher, Charles W., Jr.

    2011-01-01

    Atomistic Green-Kubo simulations are performed to evaluate the lattice thermal conductivity for single crystals of the ultra high temperature ceramics ZrB2 and HfB2 for a range of temperatures. Recently developed interatomic potentials are used for these simulations. Heat current correlation functions show rapid oscillations which can be identified with mixed metal-Boron optical phonon modes. Agreement with available experimental data is good.

  19. Preparation of high critical temperature YBa2Cu3O7 superconducting coatings by thermal spray

    International Nuclear Information System (INIS)

    Lacombe, Jacques

    1991-01-01

    The objective of this research thesis is the elaboration of YBa 2 Cu 3 O 7 superconducting coatings by thermal spray. These coatings must have a high adherence, a high cohesion, and the best possible electrical characteristics. The author first briefly presents physical-chemical characteristics of this ceramic, and proposes a bibliographical synthesis on thick coatings prepared by thermal spray. In the next parts, he studies and describes conditions of elaboration of poly-granular coatings of YBa 2 Cu 3 O 7 , and their structural and electric characteristics [fr

  20. Thermal expansion and decomposition of jarosite: a high-temperature neutron diffraction study

    Energy Technology Data Exchange (ETDEWEB)

    Xu, Hongwu [Los Alamos National Laboratory; Zhao, Yusheng [Los Alamos National Laboratory; Vogel, Sven C [Los Alamos National Laboratory; Hickmott, Donald D [Los Alamos National Laboratory; Daemen, Luke L [Los Alamos National Laboratory; Hartl, Monika A [Los Alamos National Laboratory

    2009-01-01

    The structure of deuterated jarosite, KFe{sub 3}(SO{sub 4}){sub 2}(OD){sub 6}, was investigated using time-of-flight neutron diffraction up to its dehydroxylation temperature. Rietveld analysis reveals that with increasing temperature, its c dimension expands at a rate {approx}10 times greater than that for a. This anisotropy of thermal expansion is due to rapid increase in the thickness of the (001) sheet of [Fe(O,OH){sub 6}] octahedra and [SO{sub 4}] tetrahedra with increasing temperature. Fitting of the measured cell volumes yields a coefficient of thermal expansion, a = a{sub 0} + a{sub 1} T, where a{sub 0} = 1.01 x 10{sup -4} K{sup -1} and a{sub 1} = -1.15 x 10{sup -7} K{sup -2}. On heating, the hydrogen bonds, O1{hor_ellipsis}D-O3, through which the (001) octahedral-tetrahedral sheets are held together, become weakened, as reflected by an increase in the D{hor_ellipsis}O1 distance and a concomitant decrease in the O3-D distance with increasing temperature. On further heating to 575 K, jarosite starts to decompose into nanocrystalline yavapaiite and hematite (as well as water vapor), a direct result of the breaking of the hydrogen bonds that hold the jarosite structure together.

  1. Role of oxides and porosity on high temperature oxidation of liquid fuelled HVOF thermal sprayed Ni50Cr coatings

    OpenAIRE

    Song, B.; Bai, M.; Voisey, K.T.; Hussain, Tanvir

    2017-01-01

    High chromium content in Ni50Cr thermally sprayed coatings can generate a dense and protective scale at the surface of coating. Thus, the Ni50Cr coating is widely used in high temperature oxidation and corrosion applications. A commercially available gas atomized Ni50Cr powder was sprayed onto a power plant steel (ASME P92) using a liquid fuelled high velocity oxy-fuel (HVOF) thermal spray with three processing parameters in this study. Microstructure of as-sprayed coatings was examined using...

  2. KNO3/NaNO3 - Graphite materials for thermal energy storage at high temperature: Part I. - Elaboration methods and thermal properties

    International Nuclear Information System (INIS)

    Acem, Zoubir; Lopez, Jerome; Palomo Del Barrio, Elena

    2010-01-01

    Composites graphite/salt for thermal energy storage at high temperature (∼200 deg. C) have been developed and tested. As at low temperature in the past, graphite has been used to enhance the thermal conductivity of the eutectic system KNO 3 /NaNO 3 . A new elaboration method has been proposed as an alternative to graphite foams infiltration. It consists of cold-compression of a physical mixing of expanded natural graphite particles and salt powder. Two different compression routes have been investigated: uni-axial compression and isostatic compression. The first part of the paper has been devoted to the analysis of the thermal properties of these new graphite/salt composites. It is proven that cold-compression is a simple and efficient technique for improving the salt thermal conductivity. For instance, graphite amounts between 15 and 20%wt lead to apparent thermal conductivities close to 20 W/m/K (20 times greater than the thermal conductivity of the salt). Furthermore, some advantages in terms of cost and safety are expected because materials elaboration is carried out at room temperature. The second part of the paper is focused on the analyses of the phase transition properties of these graphite/salt composites materials.

  3. Nuclear reactor pressure vessel with an inner metal coating covered with a high temperature resistant thermal insulator

    International Nuclear Information System (INIS)

    1974-01-01

    The thermal insulator covering the metal coating of a reactor vessel is designed for resisting high temperatures. It comprises one or several porous layers of ceramic fibers or of stacked metal foils, covered with a layer of bricks or ceramic tiles. The latter are fixed in position by fasteners comprising pins fixed to the coating and passing through said porous layers and fasteners (nut or bolts) for individually fixing the bricks to said pins, whereas ceramic plugs mounted on said bricks or tiles provide for the thermal insulation of the pins and of the nuts or bolts; such a thermal insulation can be applied to high-temperature reactors or to fast reactors [fr

  4. Selection of high temperature thermal energy storage materials for advanced solar dynamic space power systems

    Science.gov (United States)

    Lacy, Dovie E.; Coles-Hamilton, Carolyn; Juhasz, Albert

    1987-01-01

    Under the direction of NASA's Office of Aeronautics and Technology (OAST), the NASA Lewis Research Center has initiated an in-house thermal energy storage program to identify combinations of phase change thermal energy storage media for use with a Brayton and Stirling Advanced Solar Dynamic (ASD) space power system operating between 1070 and 1400 K. A study has been initiated to determine suitable combinations of thermal energy storage (TES) phase change materials (PCM) that result in the smallest and lightest weight ASD power system possible. To date the heats of fusion of several fluoride salt mixtures with melting points greater than 1025 K have been verified experimentally. The study has indicated that these salt systems produce large ASD systems because of their inherent low thermal conductivity and low density. It is desirable to have PCMs with high densities and high thermal conductivities. Therefore, alternate phase change materials based on metallic alloy systems are also being considered as possible TES candidates for future ASD space power systems.

  5. Determination of heat conductivity and thermal diffusivity of waste glass melter feed: Extension to high temperatures

    International Nuclear Information System (INIS)

    Rice, Jarrett A.; Pokorny, Richard; Schweiger, Michael J.; Hrma, Pavel R.

    2014-01-01

    The heat conductivity (λ) and the thermal diffusivity (a) of reacting glass batch, or melter feed, control the heat flux into and within the cold cap, a layer of reacting material floating on the pool of molten glass in an all-electric continuous waste glass melter. After previously estimating λ of melter feed at temperatures up to 680 deg C, we focus in this work on the λ(T) function at T > 680 deg C, at which the feed material becomes foamy. We used a customized experimental setup consisting of a large cylindrical crucible with an assembly of thermocouples, which monitored the evolution of the temperature field while the crucible with feed was heated at a constant rate from room temperature up to 1100°C. Approximating measured temperature profiles by polynomial functions, we used the heat transfer equation to estimate the λ(T) approximation function, which we subsequently optimized using the finite-volume method combined with least-squares analysis. The heat conductivity increased as the temperature increased until the feed began to expand into foam, at which point the conductivity dropped. It began to increase again as the foam turned into a bubble-free glass melt. We discuss the implications of this behavior for the mathematical modeling of the cold cap

  6. High temperature thermal storage for solar gas turbines using encapsulated phase change materials

    CSIR Research Space (South Africa)

    Klein, P

    2014-01-01

    Full Text Available in the near term. Sensible heat storage in packed beds involves a random packing of ceramic pebbles/particles in an insulated container. The temperature change of the solid during charging/discharging is used to store/release thermal energy. The primary... the packed bed due to vaporization and condensation effects. 2.3. Macro-encapsulation of PCM In the macro-encapsulation approach the PCM is retained within a hollow shell material. The shell can be preformed, filled with a molten PCM and sealed; or it can...

  7. Thermal curing of PBI membranes for high temperature PEM fuel cells

    DEFF Research Database (Denmark)

    Aili, David; Cleemann, Lars N.; Li, Qingfeng

    2012-01-01

    (MEAs) is currently hampering the commercial viability of the technology. In the present study, thermoset PBI membranes were prepared by curing the membranes under inert atmosphere at temperatures of up to 350 °C prior to the acid doping. The systematic membrane characterizations with respect...... to solubility, phosphoric acid doping, radical-oxidative resistance and mechanical strength indicated that the PBI membranes were irreversibly cured by the thermal treatment. After curing, the PBI membranes demonstrated features that are fundamental characteristics of a thermoset resin including complete...

  8. Thermal expansion and phase transformation studies on some materials by high temperature x-ray powder diffractometry

    International Nuclear Information System (INIS)

    Rajagopalan, S.; Kutty, K.V.G.; Jajoo, H.K.; Ananthakrishnan, S.K.; Asurvatharaman, R.

    1988-01-01

    A high temperature chamber based on electrical resistance heating has been integrated to an existing x-ray powder diffractometer. The system is capable of going upto 2500degC at programmed rates of heating. Temperature measurement is carried out by means by Pt/Rh or W/Re thermocouples or by optical pyrometry depending upon the temperature range. Provision exists for performing high temperature x-ray diffractometry in vacuum or in a gaseous atmosphere of low x-ray absorption. The x-ray optical alignment has been ensured by accurately measuring the unit cell lengths of x-ray diffraction standards like silicon and tungsten. The thermocouples have been calibrated within the system by monitoring the melting points of gold and silver. The well characterized transformation of zirconia from the monoclinic to tetragonal structure occuring around 1100degC has been satisfactorily reproduced . The high temperature phase transitions in some rare earth oxides have been studi ed. lattice parameter measurements on a variety of materials as a function of temperature upto 1500degC have been carried out and the data found to be in agreement with the literature values. From the measured lattice parameter values, percentage thermal expansion and coefficients of thermal expansion have been calculated for many substances from room temperature to 15000degC. (author). 20 refs., 9 figs

  9. Development of thermal mixing enhancement method for lower plenum of the High Temperature Test Facility

    Energy Technology Data Exchange (ETDEWEB)

    Gradecka, Malwina Joanna, E-mail: malgrad@gmail.com; Woods, Brian G., E-mail: brian.woods@oregonstate.edu

    2016-08-15

    Highlights: • Coolant mixing in lower plenum might be insufficient and pose operational issues. • Two mixing methods were developed to lower the coolant temperature variation. • The methods resulted with reduction of the temperature variation by 60% and 71%. - Abstract: The High Temperature Gas-cooled Reactor (HTGR) is one of the most mature Gen IV reactor concepts under development today. The High Temperature Test Facility (HTTF) at Oregon State University is a test facility that supports the R&D needs for HTGRs. This study focuses on the issue of helium mixing after the core section in the HTTF, the results of which are generally applicable in HTGRs. In the HTTF, hot helium jets at different temperatures are supposed to uniformly mix in the lower plenum (LP) chamber. However, the level of mixing is not sufficient to reduce the peak helium temperature before the hot jet impinges the LP structure, which can cause issues with structural materials and operational issues in the heat exchanger downstream. The maximum allowable temperature variation in the outlet duct connected to the lower plenum is defined as 40 K (±20 K from the average temperature), while the CFD simulations of this study indicate that the reference design suffers temperature variations in the duct as high as 100 K. To solve this issue, the installation of mixing-enhancing structures within the outlet duct were proposed and analyzed using CFD modeling. We show that using either an optimized “Kwiat” structure (developed in this study) or a motionless mixer installed in the outlet duct, the temperature variations can be brought dramatically, with acceptable increases in pressure drop. The optimal solution appears to be to install double motionless mixers with long blades in the outlet duct, which brings the temperature variation into the acceptable range (from 100 K down to 18 K), with a resulting pressure drop increase in the HTTF loop of 0.73 kPa (6% of total pressure drop).

  10. Development of thermal mixing enhancement method for lower plenum of the High Temperature Test Facility

    International Nuclear Information System (INIS)

    Gradecka, Malwina Joanna; Woods, Brian G.

    2016-01-01

    Highlights: • Coolant mixing in lower plenum might be insufficient and pose operational issues. • Two mixing methods were developed to lower the coolant temperature variation. • The methods resulted with reduction of the temperature variation by 60% and 71%. - Abstract: The High Temperature Gas-cooled Reactor (HTGR) is one of the most mature Gen IV reactor concepts under development today. The High Temperature Test Facility (HTTF) at Oregon State University is a test facility that supports the R&D needs for HTGRs. This study focuses on the issue of helium mixing after the core section in the HTTF, the results of which are generally applicable in HTGRs. In the HTTF, hot helium jets at different temperatures are supposed to uniformly mix in the lower plenum (LP) chamber. However, the level of mixing is not sufficient to reduce the peak helium temperature before the hot jet impinges the LP structure, which can cause issues with structural materials and operational issues in the heat exchanger downstream. The maximum allowable temperature variation in the outlet duct connected to the lower plenum is defined as 40 K (±20 K from the average temperature), while the CFD simulations of this study indicate that the reference design suffers temperature variations in the duct as high as 100 K. To solve this issue, the installation of mixing-enhancing structures within the outlet duct were proposed and analyzed using CFD modeling. We show that using either an optimized “Kwiat” structure (developed in this study) or a motionless mixer installed in the outlet duct, the temperature variations can be brought dramatically, with acceptable increases in pressure drop. The optimal solution appears to be to install double motionless mixers with long blades in the outlet duct, which brings the temperature variation into the acceptable range (from 100 K down to 18 K), with a resulting pressure drop increase in the HTTF loop of 0.73 kPa (6% of total pressure drop).

  11. Thermal Cycling and High-Temperature Corrosion Tests of Rare Earth Silicate Environmental Barrier Coatings

    Science.gov (United States)

    Darthout, Émilien; Gitzhofer, François

    2017-12-01

    Lutetium and yttrium silicates, enriched with an additional secondary zirconia phase, environmental barrier coatings were synthesized by the solution precursor plasma spraying process on silicon carbide substrates. A custom-made oven was designed for thermal cycling and water vapor corrosion testing. The oven can test four specimens simultaneously and allows to evaluate environmental barrier performances under similar corrosion kinetics compared to turbine engines. Coatings structural evolution has been observed by SEM on the polished cross sections, and phase composition has been analyzed by XRD. All coatings have been thermally cycled between 1300 °C and the ambient temperature, without spallation, due to their porosity and the presence of additional secondary phase which increases the thermal cycling resistance. During water vapor exposure at 1200 °C, rare earth disilicates showed a good stability, which is contradictory with the literature, due to impurities—such as Si- and Al-hydroxides—in the water vapor jets. The presence of vertical cracks allowed the water vapor to reach the substrate and then to corrode it. It has been observed that thin vertical cracks induced some spallation after 24 h of corrosion.

  12. A novel highly porous ceramic foam with efficient thermal insulation and high temperature resistance properties fabricated by gel-casting process

    Science.gov (United States)

    Yu, Jiahong; Wang, Guixiang; Tang, Di; Qiu, Ya; Sun, Nali; Liu, Wenqiao

    2018-01-01

    The design of super thermal insulation and high-temperature resistant materials for high temperature furnaces is crucial due to the energy crisis and the huge wasting. Although it is told that numerous studies have been reported about various of thermal insulation materials prepared by different methods, the applications of yttria-stabilized zirconia (YSZ) ceramic foams fabricated through tert-butyl alcohol (TBA)-based gel-casting process in bulk thermal isolators were barely to seen. In this paper, highly porous yttria-stabilized zirconia (YSZ) ceramic foams were fabricated by a novel gel-casting method using tert-butyl alcohol (TBA) as solvent and pore-forming agent. Different raw material ratio, sintering temperature and soaking time were all investigated to achieve optimal thermal insulation and mechanical properties. We can conclude that porosity drops gradually while compressive strength increases significantly with the rising temperature from 1000-1500°C. With prolonged soaking time, there is no obvious change in porosity but compressive strength increases gradually. All specimens have uniformly distributed pores with average size of 0.5-2μm and show good structural stability at high temperature. The final obtained ceramic foams displayed an outstanding ultra-low thermal conductivity property with only 200.6 °C in cold surface while the hot side was 1000 °C (hold 60 min to keep thermal balance before testing) at the thickness of 10 mm.

  13. Low-temperature thermal expansion

    International Nuclear Information System (INIS)

    Collings, E.W.

    1986-01-01

    This chapter discusses the thermal expansion of insulators and metals. Harmonicity and anharmonicity in thermal expansion are examined. The electronic, magnetic, an other contributions to low temperature thermal expansion are analyzed. The thermodynamics of the Debye isotropic continuum, the lattice-dynamical approach, and the thermal expansion of metals are discussed. Relative linear expansion at low temperatures is reviewed and further calculations of the electronic thermal expansion coefficient are given. Thermal expansions are given for Cu, Al and Ti. Phenomenologic thermodynamic relationships are also discussed

  14. Thermal shock behaviour of H and H/He-exposed tungsten at high temperature

    International Nuclear Information System (INIS)

    Lemahieu, N; Linke, J; Pintsuk, G; Wirtz, M; Greuner, H; Maier, H; Oost, G Van; Noterdaeme, J-M

    2016-01-01

    Polycrystalline tungsten samples were characterized and exposed to a pure H beam or mixed H/He beam containing 6% He in GLADIS at a surface temperature of 600 °C, 1000 °C, or 1500 °C. After 5400 s of exposure time with a heat flux of 10.5 MW m −2 , the total accumulated fluence of 2 × 10 25 m −2 was reached. Thereafter, edge localized mode (ELM)-like thermal shocks with a duration of 1 ms and an absorbed power density of 190 MW m −2 and 380 MW m −2 were applied on the samples in JUDITH 1. During the thermal shocks, the base temperature was kept at 1000 °C. The ELM-experiments with the lowest transient power density did not result in any detected damage. The other tests showed the beginning of crack formation for every sample, except the sample pre-exposed with the pure H-beam at 1500 °C in GLADIS. This sample was roughened, but did not show any crack initiation. With exception to the roughened sample, the category of ELM-induced damage for the pre-exposed samples is identical to the reference tests without pre-exposure to a particle flux. (paper)

  15. Thermal stability and high temperature polymorphism of topochemically-prepared Dion–Jacobson triple-layered perovskites

    Energy Technology Data Exchange (ETDEWEB)

    Guertin, Stephen L.; Josepha, Elisha A.; Montasserasadi, Dariush; Wiley, John B., E-mail: jwiley@uno.edu

    2015-10-25

    The thermal stability of six Dion–Jacobson-related triple layered perovskites, ACa{sub 2}Nb{sub 3}O{sub 10} (A = H, NH{sub 4}, Li, Na, K, CuCl), was explored to 1000 °C. Each compound was produced topochemically by low-temperature (<500 °C) ion exchange from RbCa{sub 2}Nb{sub 3}O{sub 10}. The thermal behavior of the series was examined by variable temperature X-ray powder diffraction experiments in tandem with thermogravimetric analysis and differential scanning calorimetry. Five of the species were found to be low temperature/metastable phases, decomposing below 900 °C, where the stability of the series decreased with decreasing interlayer cation size. The compounds, A = Li, Na, K, exhibited high temperature polymorphism, with a completely reversible transition evident for KCa{sub 2}Nb{sub 3}O{sub 10}. - Highlights: • Thermal stability of topochemically prepared triple-layered perovskites studied. • Clear correlation seen between stability and identity of interlayer cation. • Several in ACa{sub 2}Nb{sub 3}O{sub 10} series (A = Li, Na, K) exhibit high temperature polymorphism.

  16. Characterization and Thermal Dehydration Kinetics of Highly Crystalline Mcallisterite, Synthesized at Low Temperatures

    Directory of Open Access Journals (Sweden)

    Emek Moroydor Derun

    2014-01-01

    Full Text Available The hydrothermal synthesis of a mcallisterite (Mg2(B6O7(OH62·9(H2O mineral at low temperatures was characterized. For this purpose, several reaction temperatures (0–70°C and reaction times (30–240 min were studied. Synthesized minerals were subjected to X-ray diffraction (XRD, fourier transform infrared (FT-IR, and Raman spectroscopies and scanning electron microscopy (SEM. Additionally, experimental analyses of boron trioxide (B2O3 content and reaction yields were performed. Furthermore, thermal gravimetry and differential thermal analysis (TG/DTA were used for the determination of thermal dehydration kinetics. According to the XRD results, mcallisterite, which has a powder diffraction file (pdf number of “01-070-1902,” was formed under certain reaction parameters. Pure crystalline mcallisterite had diagnostic FT-IR and Raman vibration peaks and according to the SEM analysis, for the minerals which were synthesized at 60°C and 30 min of reaction time, particle size was between 398.30 and 700.06 nm. Its B2O3 content and reaction yield were 50.80±1.12% and 85.80±0.61%, respectively. Finally, average activation energies (conversion values (α that were selected between 0.1 and 0.6 were calculated as 100.40 kJ/mol and 98.31 kJ/mol according to Ozawa and Kissinger-Akahira-Sunose (KAS methods, respectively.

  17. Thermal stress estimation in relation to spalling of HSC restrained with steel rings at high temperatures

    Directory of Open Access Journals (Sweden)

    Tanibe T.

    2013-09-01

    Full Text Available This paper reports on an experimental study regarding the behavior of steel ring-restrained concrete in response to fire exposure. The study was conducted to enable estimation of thermal stress based on steel ring strain in such concrete under the conditions of a RABT 30 heating curve. The specimens used were made from high-strength concrete (Fc: 80 MPa restrained using steel rings with thicknesses of 0.5, 8 and 18 mm.

  18. High temperature battery. Hochtemperaturbatterie

    Energy Technology Data Exchange (ETDEWEB)

    Bulling, M.

    1992-06-04

    To prevent heat losses of a high temperature battery, it is proposed to make the incoming current leads in the area of their penetration through the double-walled insulating housing as thermal throttle, particularly spiral ones.

  19. Study of magneto-thermal coupled phenomena in High Temperature Superconductors

    International Nuclear Information System (INIS)

    Berger, Kevin

    2006-01-01

    Theoretical study of HTS devices requires to solve magneto-thermal coupled equations. As coupling effects are very important in these materials, the development of numerical tools is almost unavoidable. A computer code based on the Finite Difference Method was developed in this direction, making it possible to solve 1D and 2D problems. It is then possible to numerically simulate the behavior of HTS. Study of the losses in a Bi-2223 current lead, fed by an alternating current at 50 Hz, subjected to a DC magnetic field and immersed in a liquid nitrogen bath, is then carried out in a theoretical and experimental way. Thermal instabilities were observed experimentally. This phenomenon was studied starting from the search for the stable and unstable steady state solutions. For a given current and magnetic field, a maximum temperature above which recovery of the superconducting state is not possible could be defined. YBCO pellets can trap strong magnetic fields and be used as very powerful cryo-magnets. The dynamic response of these pellets, subjected to variations of a magnetic field, is studied in a detailed way (current density, magnetic field and temperature distributions). Results of the simulations show significant differences when the influences of the magnetic field and temperature are taken into account in the electrical law E(J). An optimum of the maximum magnetic field to apply leading to a maximum of trapped flux could be given. This information is of great interest as it enables the design of the most effective pulse magnetization device. (author) [fr

  20. Effects of high-temperature thermal annealing on the electronic properties of In-Ga-Zn oxide thin films

    Energy Technology Data Exchange (ETDEWEB)

    Li, Qin; Song, Zhong Xiao; Ma, Fei, E-mail: mafei@mail.xjtu.edu.cn, E-mail: liyhemail@gmail.com; Li, Yan Huai, E-mail: mafei@mail.xjtu.edu.cn, E-mail: liyhemail@gmail.com [State Key Laboratory for Mechanical Behavior of Materials, Xi' an Jiaotong University, Xi' an, Shaanxi 710049 (China); Xu, Ke Wei [State Key Laboratory for Mechanical Behavior of Materials, Xi' an Jiaotong University, Xi' an, Shaanxi 710049, China and Department of Physics and Opt-electronic Engineering, Xi' an University of Arts and Science, Xi' an, Shaanxi 710065 (China)

    2015-03-15

    Indium gallium zinc oxide (IGZO) thin films were deposited by radio-frequency magnetron sputtering at room-temperature. Then, thermal annealing was conducted to improve the structural ordering. X-ray diffraction and high-resolution transmission electron microscopy demonstrated that the as-deposited IGZO thin films were amorphous and crystallization occurred at 800 and 950 °C. As a result of crystallization at high temperature, the carrier concentration and the Hall mobility of IGZO thin films were sharply increased, which could be ascribed to the increased oxygen vacancies and improved structural ordering of the thin films.

  1. An investigation on the effects of phase change material on material components used for high temperature thermal energy storage system

    Science.gov (United States)

    Kim, Taeil; Singh, Dileep; Zhao, Weihuan; Yua, Wenhua; France, David M.

    2016-05-01

    The latent heat thermal energy storage (LHTES) systems for concentrated solar power (CSP) plants with advanced power cycle require high temperature phase change materials (PCMs), Graphite foams with high thermal conductivity to enhance the poor thermal conductivity of PCMs. Brazing of the graphite foams to the structural metals of the LHTES system could be a method to assemble the system and a method to protect the structural metals from the molten salts. In the present study, the LHTES prototype capsules using MgCl2-graphite foam composites were assembled by brazing and welding, and tested to investigate the corrosion attack of the PCM salt on the BNi-4 braze. The microstructural analysis showed that the BNi-4 braze alloy can be used not only for the joining of structure alloy to graphite foams but also for the protecting of structure alloy from the corrosion by PCM.

  2. Thermal decomposition of polystyrene in the high temperature fabrication technology of hollow microspheres. Revision 1

    International Nuclear Information System (INIS)

    Dorogotovtsev, V.M.; Akunets, A.A.; Merkuliev, Y.A.; Turivnoy, A.P.

    1997-01-01

    The degree and nature of polymer degradation that occurs in the high temperature microshell formation process developed at the Lebedev Physical Institute has been examined experimentally. We find that significant mass degradation occurs during the final stages of shell formation. This manifests itself both in terms of mass loss and molecular weight degradation as measured by gel permeation chromatography. This decrease in the molecular weight may be in part responsible for the relatively fragile nature of the shells produced by this high temperature process. 9 refs., 6 figs., 2 tabs

  3. Thermal sterilization of heat-sensitive products using high-temperature short-time sterilization.

    Science.gov (United States)

    Mann, A; Kiefer, M; Leuenberger, H

    2001-03-01

    High-temperature short-time (HTST) sterilization with a continuous-flow sterilizer, developed for this study, was evaluated. The evaluation was performed with respect to (a) the chemical degradation of two heat-sensitive drugs in HTST range (140-160 degrees C) and (b) the microbiological effect of HTST sterilization. Degradation kinetics of two heat-sensitive drugs showed that a high peak temperature sterilization process resulted in less chemical degradation for the same microbiological effect than a low peak temperature process. Both drugs investigated could be sterilized with acceptable degradation at HTST conditions. For the evaluation of the microbiological effect, Bacillus stearothermophilus ATCC 7953 spores were used as indicator bacteria. Indicator spore kinetics (D(T), z value, k, and E(a)), were determined in the HTST range. A comparison between the Bigelow model (z value concept) and the Arrhenius model, used to describe the temperature coefficient of the microbial inactivation, demonstrated that the Bigelow model is more accurate in prediction of D(T) values in the HTST range. The temperature coefficient decreased with increasing temperature. The influence of Ca(2+) ions and pH value on the heat resistance of the indicator spores, which is known under typical sterilization conditions, did not change under HTST conditions.

  4. Synthesis, ionic conductivity, and thermal properties of proton conducting polymer electrolyte for high temperature fuel cell

    Energy Technology Data Exchange (ETDEWEB)

    Itoh, Takahito; Hamaguchi, Yohei; Uno, Takahiro; Kubo, Masataka [Department of Chemistry for Materials, Faculty of Engineering, Mie University, 1577 Kurima Machiya-cho, Tsu, Mie 514-8507 (Japan); Aihara, Yuichi; Sonai, Atsuo [Samsung Yokohama Research Institute, 2-7 Sugasawa-cho, Tsurumi-ku, Yokohama 230-0027 (Japan)

    2006-01-16

    Hyperbranched polymer (poly-1a) with sulfonic acid groups at the end of chains was successfully synthesized. Interpenetration reaction of poly-1a with a hyperbranched polymer with acryloyl groups at the end of chains (poly-1b) as a cross-linker afforded a tough electrolyte membrane. The poly-1a and the resulting electrolyte membrane showed the ionic conductivities of 7x10{sup -4} and 8x10{sup -5} S/cm, respectively, at 150C under dry condition. The ionic conductivities of the poly-1a and the electrolyte membrane exhibited the VTF type temperature dependence. And also, both poly-1a and the resulting electrolyte membrane were thermally stable up to 200C. (author)

  5. Modelling of thermal removal of tars in a high temperature stage fed by a plasma torch

    International Nuclear Information System (INIS)

    Fourcault, A.; Marias, F.; Michon, U.

    2010-01-01

    The thermal degradation of tars in a chamber fed by a non-transferred plasma torch is theoretically examined in this study. The input of this reactor is a product gas coming from a gasification unit with a temperature of about 800 o C. According to literature, naphthalene and toluene are chosen as model compounds to represent the behaviour of their classes. According to this choice and to the data available in the literature, a reaction pathway for the thermal degradation of tars and its associated kinetics are proposed in this study. This mechanism is introduced in a CSTR model in order to check the influence of the operating parameters of the reactor on the degradation efficiency. These computations clearly show that a complete conversion of toluene (>99.9%) and an important conversion of naphthalene (96.7%) can be reached in the reactor, with concentration levels compatible with the further use of gas engines for electricity production. This theoretical study requires to be validated by comparison with experimental results.

  6. Modelling of thermal removal of tars in a high temperature stage fed by a plasma torch

    Energy Technology Data Exchange (ETDEWEB)

    Fourcault, A. [Laboratoire Thermique Energetique et Procedes, LaTEP-ENSGTI, rue Jules Ferry, BP 7511, 64075 Pau Cedex (France); Europlasma, 21 rue Daugere, 33520 Bruges (France); Marias, F. [Laboratoire Thermique Energetique et Procedes, LaTEP-ENSGTI, rue Jules Ferry, BP 7511, 64075 Pau Cedex (France); Michon, U. [Europlasma, 21 rue Daugere, 33520 Bruges (France)

    2010-09-15

    The thermal degradation of tars in a chamber fed by a non-transferred plasma torch is theoretically examined in this study. The input of this reactor is a product gas coming from a gasification unit with a temperature of about 800 C. According to literature, naphthalene and toluene are chosen as model compounds to represent the behaviour of their classes. According to this choice and to the data available in the literature, a reaction pathway for the thermal degradation of tars and its associated kinetics are proposed in this study. This mechanism is introduced in a CSTR model in order to check the influence of the operating parameters of the reactor on the degradation efficiency. These computations clearly show that a complete conversion of toluene (>99.9%) and an important conversion of naphthalene (96.7%) can be reached in the reactor, with concentration levels compatible with the further use of gas engines for electricity production. This theoretical study requires to be validated by comparison with experimental results. (author)

  7. Characterization of Ternary NiTiPd High-Temperature Shape-Memory Alloys under Load-Biased Thermal Cycling

    Science.gov (United States)

    Bigelow, Glen S.; Padula, Santo A.; Noebe, Ronald D.; Garg, Anita; Gaydosh, Darrell

    2010-01-01

    While NiTiPd alloys have been extensively studied for proposed use in high-temperature shape-memory applications, little is known about the shape-memory response of these materials under stress. Consequently, the isobaric thermal cyclic responses of five (Ni,Pd)49.5Ti50.5 alloys with constant stoichiometry and Pd contents ranging from 15 to 46 at. pct were investigated. From these tests, transformation temperatures, transformation strain (which is proportional to work output), and unrecovered strain per cycle (a measure of dimensional instability) were determined as a function of stress for each alloy. It was found that increasing the Pd content over this range resulted in a linear increase in transformation temperature, as expected. At a given stress level, work output decreased while the amount of unrecovered strain produced during each load-biased thermal cycle increased with increasing Pd content, during the initial thermal cycles. However, continued thermal cycling at constant stress resulted in a saturation of the work output and nearly eliminated further unrecovered strain under certain conditions, resulting in stable behavior amenable to many actuator applications.

  8. Improving the temperature predictions of subsurface thermal models by using high-quality input data. Part 1: Uncertainty analysis of the thermal-conductivity parameterization

    DEFF Research Database (Denmark)

    Fuchs, Sven; Balling, Niels

    2016-01-01

    The subsurface temperature field and the geothermal conditions in sedimentary basins are frequently examined by using numerical thermal models. For those models, detailed knowledge of rock thermal properties are paramount for a reliable parameterization of layer properties and boundary conditions...

  9. Probabilistic Material Strength Degradation Model for Inconel 718 Components Subjected to High Temperature, Mechanical Fatigue, Creep and Thermal Fatigue Effects

    Science.gov (United States)

    Bast, Callie Corinne Scheidt

    1994-01-01

    This thesis presents the on-going development of methodology for a probabilistic material strength degradation model. The probabilistic model, in the form of a postulated randomized multifactor equation, provides for quantification of uncertainty in the lifetime material strength of aerospace propulsion system components subjected to a number of diverse random effects. This model is embodied in the computer program entitled PROMISS, which can include up to eighteen different effects. Presently, the model includes four effects that typically reduce lifetime strength: high temperature, mechanical fatigue, creep, and thermal fatigue. Statistical analysis was conducted on experimental Inconel 718 data obtained from the open literature. This analysis provided regression parameters for use as the model's empirical material constants, thus calibrating the model specifically for Inconel 718. Model calibration was carried out for four variables, namely, high temperature, mechanical fatigue, creep, and thermal fatigue. Methodology to estimate standard deviations of these material constants for input into the probabilistic material strength model was developed. Using the current version of PROMISS, entitled PROMISS93, a sensitivity study for the combined effects of mechanical fatigue, creep, and thermal fatigue was performed. Results, in the form of cumulative distribution functions, illustrated the sensitivity of lifetime strength to any current value of an effect. In addition, verification studies comparing a combination of mechanical fatigue and high temperature effects by model to the combination by experiment were conducted. Thus, for Inconel 718, the basic model assumption of independence between effects was evaluated. Results from this limited verification study strongly supported this assumption.

  10. New composites graphite/salt for high temperature thermal energy storage: From elaboration to development of thermal characterization methods for orthotropic conductive materials

    International Nuclear Information System (INIS)

    Acem, Zoubir

    2007-01-01

    This PhD is carried out within the framework of DISTOR (European) and HTPSTOCK (French) projects, which have for objective to conceive and study new graphite/salt composites dedicated to high temperature energy storage (>200 deg. C). She is split into two distinct part. The first one focused mainly on works linked with elaboration and thermal characterisation of these new composites. The different composites ways of elaboration (Dispersion, uniaxial compression, isostatic) associated to the different kind of graphite (Natural expanded graphite (ENG), synthetic graphite) investigated during the PhD are presented. The results of the thermal characterization campaign of these composites are also presented and permit to highlight the impact of graphite in the thermal behaviour of studied materials. Based on these results, modelling studies of the evolution of the thermal conductivity have been undertaken to deepen the understanding of the effect of graphite (quantity, size of particles) on the effective conductivity composites. The second one describes the thermal characterization devices and associated thermo-kinetics models which had to be developed and adapted to the specificities of newly developed materials. This concerns mainly the materials prepared by compression, which present orthotropic properties and are difficult to reproduce. So, the characterization of this kind of material is very difficult and tedious. That is why we are committed to develop and adapt existing methods of characterization to allow the complete thermal characterisation of an orthotropic conductive material from a single experimentation on a single sample. (author) [fr

  11. Study of surfaces and surface layers on high temperature materials after short-time thermal loads

    International Nuclear Information System (INIS)

    Bolt, H.; Hoven, H.; Koizlik, K.; Linke, J.; Nickel, H.; Wallura, E.

    1985-11-01

    Being part of the plasma-wall interaction during TOKAMAK operation, erosion- and redeposition processes of First Wall materials substantially influence plasma parameters as well as the properties of the First Wall. An important redeposition process of eroded material is the formation of thin films by atomic condensation. Examinations of First Wall components after TOKAMAK operation lead to the assumption that these thin metallic films tend to agglomerate to small particles under subsequent heat load. In laboratory experiments it is shown that thin metallic films on various substrates can agglomerate under short time high heat fluxes and also under longer lasting lower thermal loads, thus verifying the ''agglomeration hypothesis''. (orig.) [de

  12. Testing and analyses of a high temperature thermal barrier for gas-cooled reactors

    International Nuclear Information System (INIS)

    Black, W.E.; Betts, W.S.; Felten, P.

    1979-01-01

    A full size, multi-panel section of a thermal barrier system was fabricated from a nickel-base superalloy and a combination of fibrous blanket insulation materials for specific application in a steam cycle gas-cooled nuclear reactor. The 2.4 m square array was representative of the sidewall of the lower core outlet plenum and included coverplates, attachments, seals, and a simulated water-cooled liner. Testing was conducted in a reactor grade, helium-filled chamber at 816 0 C for 100 hours, which established a normal (baseline) condition; 982 0 C for 10 hours, which satisfied an emergency condition; 1093 0 C for 1 hour, which simulated a faulted condition; and 1260 0 C, which was a non-design condition test to demonstrate the temperature overshoot capability of the system. Post-test examination indicated: (1) an acceptable performance by the anti-friction chromium carbide (Cr 3 C 2 ) coating; (2) no significant galling between non-coated surfaces; (3) no distortion of attachment fixtures; (4) predictable coverplate deflection during the design conditions testing (normal, emergency, and faulted); and (5) considerable plastic deformation resulting from the near-incipient melting temperature. (orig.)

  13. A Numerical Study on the Heat Transfer Characteristics of a Solar Thermal Receiver with High-temperature Heat Pipes

    International Nuclear Information System (INIS)

    Park, Young Hark; Jung, Eui Guk; Boo, Joon Hong

    2007-01-01

    A numerical analysis was conducted to predict the heat transfer characteristics of a solar receiver which is subject to very high heat fluxes and temperatures for solar thermal applications. The concentration ratio of the solar receiver ranges from 200 to 1000 and the concentrated heat is required to be transported to a certain distance for specific applications. The study deals with a solar receiver incorporating high-temperature sodium heat pipe as well as typical one that employs a molten-salt circulation loop. The isothermal characteristics in the receiver section is of major concern. The diameter of the solar thermal receiver was 120 mm and the length was 400 mm. For the molten-salt circulation type receiver, 48 axial channels of the same dimensions were attached to the outer wall of the receiver with even spacing in the circumferential direction. The molten salt fed through the channels by forced convection using a special pump. For the heat pipe receiver, the channels are changed to high-temperature sodium heat pipes. Commercial softwares were employed to deal with the radiative heat transfer inside the receiver cavity and the convection heat transfer along the channels. The numerical results are compared and analyzed from the view point of high-temperature solar receiver

  14. Partitioning planning studies: Preliminary evaluation of metal and radionuclide partitioning the high-temperature thermal treatment systems

    International Nuclear Information System (INIS)

    Liekhus, K.; Grandy, J.; Chambers, A.

    1997-03-01

    A preliminary study of toxic metals and radionuclide partitioning during high-temperature processing of mixed waste has been conducted during Fiscal Year 1996 within the Environmental Management Technology Evaluation Project. The study included: (a) identification of relevant partitioning mechanisms that cause feed material to be distributed between the solid, molten, and gas phases within a thermal treatment system; (b) evaluations of existing test data from applicable demonstration test programs as a means to identify and understand elemental and species partitioning; and, (c) evaluation of theoretical or empirical partitioning models for use in predicting elemental or species partitioning in a thermal treatment system. This preliminary study was conducted to identify the need for and the viability of developing the tools capable of describing and predicting toxic metals and radionuclide partitioning in the most applicable mixed waste thermal treatment processes. This document presents the results and recommendations resulting from this study that may serve as an impetus for developing and implementing these predictive tools

  15. Partitioning planning studies: Preliminary evaluation of metal and radionuclide partitioning the high-temperature thermal treatment systems

    Energy Technology Data Exchange (ETDEWEB)

    Liekhus, K.; Grandy, J.; Chambers, A. [and others

    1997-03-01

    A preliminary study of toxic metals and radionuclide partitioning during high-temperature processing of mixed waste has been conducted during Fiscal Year 1996 within the Environmental Management Technology Evaluation Project. The study included: (a) identification of relevant partitioning mechanisms that cause feed material to be distributed between the solid, molten, and gas phases within a thermal treatment system; (b) evaluations of existing test data from applicable demonstration test programs as a means to identify and understand elemental and species partitioning; and, (c) evaluation of theoretical or empirical partitioning models for use in predicting elemental or species partitioning in a thermal treatment system. This preliminary study was conducted to identify the need for and the viability of developing the tools capable of describing and predicting toxic metals and radionuclide partitioning in the most applicable mixed waste thermal treatment processes. This document presents the results and recommendations resulting from this study that may serve as an impetus for developing and implementing these predictive tools.

  16. Enterococcus faecium as a Salmonella surrogate in the thermal processing of wheat flour: Influence of water activity at high temperatures.

    Science.gov (United States)

    Liu, Shuxiang; Rojas, Rossana V; Gray, Peter; Zhu, Mei-Jun; Tang, Juming

    2018-09-01

    This study investigated the influence of temperature-dependent water activity (a w ) on thermal resistances of Enterococcus faecium NRRL B-2354 (E. faecium) and Salmonella Enteritidis PT 30 (S. Enteritidis) in wheat flour. The a w for wheat flour samples at 20, 40, and 60 °C was determined by a vapor sorption analyzer and at 75, 80 and 85 °C using custom-built thermal cells with high temperature humidity sensors. Full-factorial isothermal inactivation studies of both strains in sealed aluminum-test-cells included three temperatures (75, 80, and 85 °C) and three a w,25°C levels (0.30, 0.45 and 0.60 within ±0.02 range, prior to the thermal treatments). Isotherm results of wheat flour demonstrate a significant increase (P processing of wheat flour for control of Salmonella over a moisture content of 10-14% and treatment temperatures between 75 and 85 °C. Copyright © 2018 Elsevier Ltd. All rights reserved.

  17. Effect of the hydro-thermal load history on the high-temperature creep of HTR-concrete

    International Nuclear Information System (INIS)

    Diederichs, U.; Rostasy, F.S.; Becker, G.

    1991-01-01

    In the research and development works for the prestressed concrete vessel for the HTR-500 high temperature reactor, the comprehensive tests concerning mix design, manufacture as well as mechanical and thermal behavior of the concrete have been carried out. The concrete was put to the numerous tests for determining the strength and the creep behavior at elevated temperature. In the real PCRV, the concrete is heated at different heating rate depending on the location of a certain volume element of the concrete in the structure. Furthermore, the heat transport simultaneously causes the moisture transport. For this reason, the test has been planned to investigate the transient creep at various heating rates and in different states of moisture during heating to the accident temperature up to 300 deg C. The cylindrical specimens were used for the high temperature creep test. The test procedure and the test results are reported. It was shown that the thermal history (heating rate, duration of holding at a certain temperature and so on) determines the transient creep deformation to a great extent. (K.I.)

  18. Thermal characteristic of sintered AgeCu nano-paste for high-temperature die-attach application

    International Nuclear Information System (INIS)

    Tan, Kim Seah; Cheong, Kuan Yew; Wong, Yew Hoong

    2015-01-01

    In this work, thermal characteristic of silver-copper (Ag-Cu) nano-paste that consists of a mixture of nano-sized Ag and Cu particles and organic compounds meant for high-temperature die-attach application is reported. The Ag-Cu nano-paste was sintered at 380 deg. C for 30 min without the need of applying external pressure and the effect of Cu loading (20-80 wt%) on the thermal properties was investigated in against of pure Ag nano-paste and pure Cu nano-paste. The results showed the specific heat of sintered Ag-Cu nano-paste was increased as the loading of Cu increased. For thermal conductivity and coefficient of thermal expansion (CTE) of sintered Ag-Cu nano-paste, a declining trend has been recorded with the increment of Cu loading. Overall, the sintered Ag-Cu nano-paste with 20 wt% of Cu loading has demonstrated the best combination of thermal conductivity (K) and CTE (α), which were 159 W/m K and 13 x 10 -6 /K, respectively. It has proven that there was a strong correlation between the amount of pores and thermal properties of the nano-paste. The ratio of K/α is a performance index (M), which has shown a higher value (12.2 x 10 6 W/m) than most of the commonly used die-attach systems. Finally, the Ag-Cu nano-paste has demonstrated a melting point of 955 deg. C, which can be proposed as an alternative high-temperature die-attach material

  19. Comparative transcriptome profiling of a thermal resistant vs. sensitive silkworm strain in response to high temperature under stressful humidity condition.

    Directory of Open Access Journals (Sweden)

    Wenfu Xiao

    Full Text Available Thermotolerance is important particularly for poikilotherms such as insects. Understanding the mechanisms by which insects respond to high temperatures can provide insights into their adaptation to the environment. Therefore, in this study, we performed a transcriptome analysis of two silkworm strains with significantly different resistance to heat as well as humidity; the thermo-resistant strain 7532 and the thermos-sensitive strain Knobbed. We identified in total 4,944 differentially expressed genes (DEGs using RNA-Seq. Among these, 4,390 were annotated and 554 were novel. Gene Ontology (GO analysis of 747 DEGs identified between RT_48h (Resistant strain with high-temperature Treatment for 48 hours and ST_48h (Sensitive strain with high-temperature Treatment for 48 hours showed significant enrichment of 12 GO terms including metabolic process, extracellular region and serine-type peptidase activity. Moreover, we discovered 12 DEGs that may contribute to the heat-humidity stress response in the silkworm. Our data clearly showed that 48h post-exposure may be a critical time point for silkworm to respond to high temperature and humidity. These results provide insights into the genes and biological processes involved in high temperature and humidity tolerance in the silkworm, and advance our understanding of thermal tolerance in insects.

  20. Stability analysis of the high temperature thermal pebble bed nuclear reactor concept

    International Nuclear Information System (INIS)

    Vondy, D.R.

    1981-02-01

    A study was made of the stability of the high temperature gas-cooled pebble bed core against xenon-driven oscillation. This generic study indicated that a core as large as 3000 MW(t) could be stable. Several aspects present a challenge to analysis including the void space above the pebble bed, the effects of possible control rod configurations, and the temperature feedback contribution. Special methods of analysis were developed in this effort. Of considerable utility was the scheme of including an azimuthal buckling loss term in the neturon balance equations admitting direct solution of the first azimuthal harmonic for a core having azimuthal symmetry. This technique allows the linear stability analysis to be done solving two-dimensional (RZ) problems instead of three-dimensional problems. A scheme for removing the fundamental source contribution was also implemented to allow direct iteration toward the dominant harmonic solution, treating up to three dimensions with diffusion theory

  1. Thermally Stable and Electrically Conductive, Vertically Aligned Carbon Nanotube/Silicon Infiltrated Composite Structures for High-Temperature Electrodes.

    Science.gov (United States)

    Zou, Qi Ming; Deng, Lei Min; Li, Da Wei; Zhou, Yun Shen; Golgir, Hossein Rabiee; Keramatnejad, Kamran; Fan, Li Sha; Jiang, Lan; Silvain, Jean-Francois; Lu, Yong Feng

    2017-10-25

    Traditional ceramic-based, high-temperature electrode materials (e.g., lanthanum chromate) are severely limited due to their conditional electrical conductivity and poor stability under harsh circumstances. Advanced composite structures based on vertically aligned carbon nanotubes (VACNTs) and high-temperature ceramics are expected to address this grand challenge, in which ceramic serves as a shielding layer protecting the VACNTs from the oxidation and erosive environment, while the VACNTs work as a conductor. However, it is still a great challenge to fabricate VACNT/ceramic composite structures due to the limited diffusion of ceramics inside the VACNT arrays. In this work, we report on the controllable fabrication of infiltrated (and noninfiltrated) VACNT/silicon composite structures via thermal chemical vapor deposition (CVD) [and laser-assisted CVD]. In laser-assisted CVD, low-crystalline silicon (Si) was quickly deposited at the VACNT subsurfaces/surfaces followed by the formation of high-crystalline Si layers, thus resulting in noninfiltrated composite structures. Unlike laser-assisted CVD, thermal CVD activated the precursors inside and outside the VACNTs simultaneously, which realized uniform infiltrated VACNT/Si composite structures. The growth mechanisms for infiltrated and noninfiltrated VACNT/ceramic composites, which we attributed to the different temperature distributions and gas diffusion mechanism in VACNTs, were investigated. More importantly, the as-farbicated composite structures exhibited excellent multifunctional properties, such as excellent antioxidative ability (up to 1100 °C), high thermal stability (up to 1400 °C), good high velocity hot gas erosion resistance, and good electrical conductivity (∼8.95 Sm -1 at 823 K). The work presented here brings a simple, new approach to the fabrication of advanced composite structures for hot electrode applications.

  2. Geomechanical characterization of the Upper Carboniferous under thermal stress for the evaluation of a High Temperature - Mine Thermal Energy Storage (HT-MTES)

    Science.gov (United States)

    Hahn, Florian; Brüggemann, Nina; Bracke, Rolf; Alber, Michael

    2017-04-01

    The goal of this R&D project is to create a technically and economically feasible conceptual model for a High Temperature - Mine Thermal Energy Storage (HT-MTES) for the energetic reuse of a mine on the example of the Prosper-Haniel coal mine in Bottrop, Germany. This project is funded by the "Initiative Energy Storage" program of the German Federal Ministries BMWi, BMU and BMBF. At the end of 2018, the last operative coal mine in North Rhine-Westphalia, Germany (Prosper-Haniel), is going to be closed down, plugged and abandoned. Large amounts of subsurface infrastructures, resembled mainly by open parts of former galleries and mining faces are going to be flooded, after the mine is closed down and therefore have the potential to become an enormous geothermal reservoir for a seasonal heat storage. During the summer non-used (waste) heat from solar thermal power plants, garbage incineration, combined heat and power plants (CHP) or industrial production processes can be stored within dedicated drifts of the mine. During the winter season, this surplus heat can be extracted and directly utilized in commercial and/or residential areas. For the evaluation of such a HT-MTES within a former coal mine, the corresponding geomechanical parameters of the Upper Carboniferous under thermal stress needs to be evaluated. Therefore the main rock types of the Upper Carboniferous (claystone, siltstone and sandstone) are subject to a geomechanical characterization before and after thermal cyclic loadings of temperatures up to 200 °C. The samples have been collected directly from the coal mine Prosper-Haniel within a depth range of 1000 - 1200 m. Unconfined compressive and tensile strengths, as well as triaxial tests were performed at room temperature. Furthermore, a range of petrophysical properties like density, thin-section analysis and P-wave velocities were determined. First results show an indication that the overall strength properties of the samples are not effected by

  3. Temperature distribution and thermal stress

    Indian Academy of Sciences (India)

    Abstract. Thermal effects of a double-end-pumped cubic Nd:YVO4 laser crystal are investigated in this paper. A detailed analysis of temperature distribution and thermal stress in cubic crystal with circular shape pumping is discussed. It has been shown that by considering the total input powers as constant, the ...

  4. TEMPERATURE DEPENDENCE OF THE THERMAL ...

    African Journals Online (AJOL)

    Thermal conductivity values, in the temperature range 300 – 1200 K, have been measured in air and at atmospheric pressure for a Kenyan kaolinite refractory with 0% - 50% grog proportions. The experimental thermal conductivity values were then compared with those calculated using the Zumbrunnen et al [1] and the ...

  5. Thermal Processing Effects on the Adhesive Strength of PS304 High Temperature Solid Lubricant Coatings

    Science.gov (United States)

    DellaCorte, Christopher; Edmonds, Brian J.; Benoy, Patricia A.

    2001-01-01

    In this paper the effects of post deposition heat treatments on the cohesive and adhesive strength properties of PS304, a plasma sprayed nickel-chrome based, high temperature solid lubricant coating deposited on stainless steel, are studied. Plasma spray deposited coating samples were exposed in air at temperatures from 432 to 650 C for up to 500 hr to promote residual stress relief, enhance particle to particle bonding and increase coating to substrate bond strength. Coating pull-off strength was measured using a commercial adhesion tester that utilizes 13 mm diameter aluminum pull studs attached to the coating surface with epoxy. Pull off force was automatically recorded and converted to coating pull off strength. As deposited coating samples were also tested as a baseline. The as-deposited (untreated) samples either delaminated at the coating-substrate interface or failed internally (cohesive failure) at about 17 MPa. Samples heat treated at temperatures above 540 C for 100 hr or at 600 C or above for more than 24 hr exhibited strengths above 31 MPa, nearly a two fold increase. Coating failure occurred inside the body of the coating (cohesive failure) for nearly all of the heat-treated samples and only occasionally at the coating substrate interface (adhesive failure). Metallographic analyses of heat-treated coatings indicate that the Nickel-Chromium binder in the PS304 appears to have segregated into two phases, a high nickel matrix phase and a high chromium precipitated phase. Analysis of the precipitates indicates the presence of silicon, a constituent of a flow enhancing additive in the commercial NiCr powder. The exact nature and structure of the precipitate phase is not known. This microstructural change is believed to be partially responsible for the coating strength increase. Diffusion bonding between particles may also be playing a role. Increasing the heat treatment temperature, exposure time or both accelerate the heat treatment process. Preliminary

  6. Experimental study on thermal interaction between a high-temperature molten jet and plates

    International Nuclear Information System (INIS)

    Sato, K.; Saito, M.; Furutani, A.; Isozaki, M.; Imahori, S.; Konishi, K.

    1994-01-01

    This paper summarizes the recent simulant experiments to study molten corium-structure interactions under postulated core disruptive accident (CDA) conditions in liquid-metal fast breeder reactors (LMFMRs). These experiments were conducted in the MELT-II facility generating high-temperature molten simulants by an induction heating technique. From a series of molten jet-structure interaction experiments, the effects of the solidified crust layer and molten layer on the erosion behavior were identified, and analytical models were developed to assess the structure erosion rate with and without crust formation. Especially, we revealed the inherent mitigation mechanism that when the molten oxide jet with high melting point falls down onto the structure plate, solidified crust of the oxide can significantly reduce the erosion rate. (author)

  7. High temperature thermal conductivity measurements of UO/sub 2/ by Direct Electrical Heating. Final report. [MANTRA-III

    Energy Technology Data Exchange (ETDEWEB)

    Bassett, B

    1980-10-01

    High temperature properties of reactor type UO/sub 2/ pellets were measured using a Direct Electrical Heating (DEH) Facility. Modifications to the experimental apparatus have been made so that successful and reproducible DEH runs may be carried out while protecting the pellets from oxidation at high temperature. X-ray diffraction measurements on the UO/sub 2/ pellets have been made before and after runs to assure that sample oxidation has not occurred. A computer code has been developed that will model the experiment using equations that describe physical properties of the material. This code allows these equations to be checked by comparing the model results to collected data. The thermal conductivity equation for UO/sub 2/ proposed by Weilbacher has been used for this analysis. By adjusting the empirical parameters in Weilbacher's equation, experimental data can be matched by the code. From the several runs analyzed, the resulting thermal conductivity equation is lambda = 1/4.79 + 0.0247T/ + 1.06 x 10/sup -3/ exp(-1.62/kT/) - 4410. exp(-3.71/kT/) where lambda is in w/cm K, k is the Boltzman constant, and T is the temperature in Kelvin.

  8. High-temperature stability of chemically vapor-deposited tungsten-silicon couples rapid thermal annealed in ammonia and argon

    International Nuclear Information System (INIS)

    Broadbent, E.K.; Morgan, A.E.; Flanner, J.M.; Coulman, B.; Sadana, D.K.; Burrow, B.J.; Ellwanger, R.C.

    1988-01-01

    A rapid thermal anneal (RTA) in an NH 3 ambient has been found to increase the thermal stability of W films chemically vapor deposited (CVD) on Si. W films deposited onto single-crystal Si by low-pressure CVD were rapid thermal annealed at temperatures between 500 and 1100 0 C in NH 3 and Ar ambients. The reactions were studied using Rutherford backscattering spectrometry, x-ray diffraction, Auger electron spectroscopy, transmission electron microscopy, and four-point resistivity probe. High-temperature (≥1000 0 C) RTA in Ar completely converted W into the low resistivity (31 μΩ cm) tetragonal WSi 2 phase. In contrast, after a prior 900 0 C RTA in NH 3 , N inclusion within the W film and at the W/Si interface almost completely suppressed the W-Si reaction. Detailed examination, however, revealed some patches of WSi 2 formed at the interface accompanied by long tunnels extending into the substrate, and some crystalline precipitates in the substrate close to the interface. The associated interfacial contact resistance was only slightly altered by the 900 0 C NH 3 anneal. The NH 3 -treated W film acted as a diffusion barrier in an Al/W/Si contact metallurgy up to at least 550 0 C, at which point some increase in contact resistance was measured

  9. High-temperature stability of chemically vapor-deposited tungsten-silicon couples rapid thermal annealed in ammonia and argon

    Energy Technology Data Exchange (ETDEWEB)

    Broadbent, E.K.; Morgan, A.E.; Flanner, J.M.; Coulman, B.; Sadana, D.K.; Burrow, B.J.; Ellwanger, R.C.

    1988-12-15

    A rapid thermal anneal (RTA) in an NH/sub 3/ ambient has been found to increase the thermal stability of W films chemically vapor deposited (CVD) on Si. W films deposited onto single-crystal Si by low-pressure CVD were rapid thermal annealed at temperatures between 500 and 1100 /sup 0/C in NH/sub 3/ and Ar ambients. The reactions were studied using Rutherford backscattering spectrometry, x-ray diffraction, Auger electron spectroscopy, transmission electron microscopy, and four-point resistivity probe. High-temperature (greater than or equal to1000 /sup 0/C) RTA in Ar completely converted W into the low resistivity (31 ..mu cap omega.. cm) tetragonal WSi/sub 2/ phase. In contrast, after a prior 900 /sup 0/C RTA in NH/sub 3/, N inclusion within the W film and at the W/Si interface almost completely suppressed the W-Si reaction. Detailed examination, however, revealed some patches of WSi/sub 2/ formed at the interface accompanied by long tunnels extending into the substrate, and some crystalline precipitates in the substrate close to the interface. The associated interfacial contact resistance was only slightly altered by the 900 /sup 0/C NH/sub 3/ anneal. The NH/sub 3/-treated W film acted as a diffusion barrier in an Al/W/Si contact metallurgy up to at least 550 /sup 0/C, at which point some increase in contact resistance was measured.

  10. High temperature oxidation and corrosion in marine environments of thermal spray deposited coatings

    International Nuclear Information System (INIS)

    Chaliampalias, D.; Vourlias, G.; Pavlidou, E.; Stergioudis, G.; Skolianos, S.; Chrissafis, K.

    2008-01-01

    Flame spraying is a widely used technique for depositing a great variety of materials in order to enforce the mechanical or the anticorrosion characteristics of the substrate. Its high rate application is due to the rapidity of the process, its effectiveness and its low cost. In this work, flame-sprayed Al coatings are deposited on low carbon steels in order to enhance their anticorrosion performance. The main adhesion mechanism of the coating is mechanical anchorage, which can provide the necessary protection to steel used in several industrial and constructive applications. To evaluate the corrosion resistance of the coating, the as-coated samples are subjected in a salt spray chamber and in elevated temperature environments. The examination and characterization of the corroded samples is done by scanning electron microscopy and X-ray diffraction analysis. The as-formed coatings are extremely rough and have a lamellic homogeneous morphology. It is also found that Al coatings provide better protection in marine atmospheres, while at elevated temperatures a thick oxide layer is formed, which can delaminate after long oxidation periods due to its low adherence to the underlying coating, thus eliminating the substrate protection

  11. Thermal Spray Coatings for High-Temperature Corrosion Protection in Biomass Co-Fired Boilers

    Science.gov (United States)

    Oksa, M.; Metsäjoki, J.; Kärki, J.

    2015-01-01

    There are over 1000 biomass boilers and about 500 plants using waste as fuel in Europe, and the numbers are increasing. Many of them encounter serious problems with high-temperature corrosion due to detrimental elements such as chlorides, alkali metals, and heavy metals. By HVOF spraying, it is possible to produce very dense and well-adhered coatings, which can be applied for corrosion protection of heat exchanger surfaces in biomass and waste-to-energy power plant boilers. Four HVOF coatings and one arc sprayed coating were exposed to actual biomass co-fired boiler conditions in superheater area with a probe measurement installation for 5900 h at 550 and 750 °C. The coating materials were Ni-Cr, IN625, Fe-Cr-W-Nb-Mo, and Ni-Cr-Ti. CJS and DJ Hybrid spray guns were used for HVOF spraying to compare the corrosion resistance of Ni-Cr coating structures. Reference materials were ferritic steel T92 and nickel super alloy A263. The circulating fluidized bed boiler burnt a mixture of wood, peat and coal. The coatings showed excellent corrosion resistance at 550 °C compared to the ferritic steel. At higher temperature, NiCr sprayed with CJS had the best corrosion resistance. IN625 was consumed almost completely during the exposure at 750 °C.

  12. Absolute measurement of the thermal conductivity of insulating materials at high temperature

    International Nuclear Information System (INIS)

    Liermann, J.

    1975-01-01

    A device was developed at the CEA for the absolute measurement of the thermal conductivity of insulators. It can operate in controlled atmospheres (air, CO 2 , Ar, He) and between 100 and 1050 deg C [fr

  13. Advanced high-temperature thermal energy storage media for industrial applications

    Science.gov (United States)

    Claar, T. D.; Waibel, R. T.

    1982-02-01

    An advanced thermal energy storage media concept based on use of carbonate salt/ceramic composite materials is being developed for industrial process and reject heat applications. The composite latent/sensible media concept and its potential advantages over state of the art latent heat systems is described. Media stability requirements, on-going materials development efforts, and planned thermal energy storage (TES) performance evaluation tests are discussed.

  14. Plutonium and minor actinides management in thermal high - temperature reactors - the EU FP6 project puma

    International Nuclear Information System (INIS)

    Kuijper, J. C.

    2007-01-01

    The High Temperature gas-cooled Reactor (HTR) can fulfil a very useful niche for the purposes of Pu and Minor Actinide (MA) incineration due to its unique and unsurpassed safety features, as well as to the attractive incentives offered by the nature of the coated particle (CP) fuel. No European reactor of this type is currently available, but there has been, and still is, considerable interest internationally. Decisions to construct such a reactor in China and in South Africa have already been made or are about to be made. Apart from the unique and unsurpassed safety features offered by this reactor type, the nature of the CP fuel offers a number of attractive characteristics. In particular, it can withstand burn-ups far beyond that in either LWR or FR systems. Demonstrations as high as 75% FIMA have been achieved. The coated particle itself offers significantly improved proliferation resistance, and finally with a correct choice of the kernel composition, it can be a very effective support for direct geological disposal of the fuel. The overall objective of the PUMA project, a Specific Targeted Research Project (STREP) within the European Union 6th Framework (EU FP6), is to investigate the possibilities for the utilisation and transmutation of plutonium and especially minor actinides in contemporary and future (high temperature) gas-cooled reactor designs, which are promising tools for improving the sustainability of the nuclear fuel cycle. This contributes to the reduction of Pu and MA stockpiles, and also to the development of safe and sustainable reactors for CO 2 -free energy generation. A number of important issues concerning the use of Pu and MA in gas-cooled reactors have already been dealt with in other projects, or are being treated in ongoing projects, e.g. as part of EU FP6. However, further steps are required to demonstrate the potential of HTRs as Pu/MA transmuters based on realistic/feasible designs of CP Pu/MA fuel and the PUMA focuses on necessary

  15. Optimizing Neutron Thermal Scattering Effects in very High Temperature Reactors. Final Report

    International Nuclear Information System (INIS)

    Hawari, Ayman

    2014-01-01

    This project aims to develop a holistic understanding of the phenomenon of neutron thermalization in the VHTR. Neutron thermalization is dependent on the type and structure of the moderating material. The fact that the moderator (and reflector) in the VHTR is a solid material will introduce new and interesting considerations that do not apply in other (e.g. light water) reactors. The moderator structure is expected to undergo radiation induced changes as the irradiation (or burnup) history progresses. In this case, the induced changes in structure will have a direct impact on many properties including the neutronic behavior. This can be easily anticipated if one recognizes the dependence of neutron thermalization on the scattering law of the moderator. For the pebble bed reactor, it is anticipated that the moderating behavior can be tailored, e.g. using moderators that consist of composite materials, which could allow improved optimization of the moderator-to-fuel ratio.

  16. AC Losses and Their Thermal Effect in High-Temperature Superconducting Machines

    DEFF Research Database (Denmark)

    Song, Xiaowei (Andy); Mijatovic, Nenad; Zou, Shengnan

    2016-01-01

    In transient operations or fault conditions, hightemperature superconducting (HTS) machines suffer ac losses, which have an influence on the thermal stability of superconducting windings. In this paper, a method to calculate ac losses and their thermal effect in HTS machines is presented....... The method consists of three submodels that are coupled only in one direction. The magnetic field distribution is first solved in a machine model, assuming a uniform current distribution in HTS windings. The magnetic fields on the boundaries are then used as inputs for an ac loss model that has a homogeneous...

  17. Influence of nanoscale temperature rises on photoacoustic generation: Discrimination between optical absorbers based on thermal nonlinearity at high frequency.

    Science.gov (United States)

    Simandoux, Olivier; Prost, Amaury; Gateau, Jérôme; Bossy, Emmanuel

    2015-03-01

    In this work, we experimentally investigate thermal-based nonlinear photoacoustic generation as a mean to discriminate between different types of absorbing particles. The photoacoustic generation from solutions of dye molecules and gold nanospheres (same optical densities) was detected using a high frequency ultrasound transducer (20 MHz). Photoacoustic emission was observed with gold nanospheres at low fluence for an equilibrium temperature around 4 °C, where the linear photoacoustic effect in water vanishes, highlighting the nonlinear emission from the solution of nanospheres. The photoacoustic amplitude was also studied as a function of the equilibrium temperature from 2 °C to 20 °C. While the photoacoustic amplitude from the dye molecules vanished around 4 °C, the photoacoustic amplitude from the gold nanospheres remained significant over the whole temperature range. Our preliminary results suggest that in the context of high frequency photoacoustic imaging, nanoparticles may be discriminated from molecular absorbers based on nanoscale temperature rises.

  18. High temperature x-ray diffraction of zr-2.5nb during thermal cycling in vacuum

    Directory of Open Access Journals (Sweden)

    Tumanov Mikhail

    2017-01-01

    Full Text Available The cyclic thermal tests in vacuum of zirconium alloy Zr-2.5Nb in the temperature range 250-350°C is established the presence of anomalies of thermal deformation of the crystal lattice, reducing the efficiency of the fuel rods.

  19. High Temperature Oxidation of Spark Plasma Sintered and Thermally Sprayed FeAl-Based Iron Aluminides

    Czech Academy of Sciences Publication Activity Database

    Haušild, P.; Karlík, M.; Skiba, T.; Sajdl, P.; Dubský, Jiří; Palm, M.

    2012-01-01

    Roč. 122, č. 3 (2012), s. 465-468 ISSN 0587-4246. [International Symposium on Physics of Materials (ISPMA)/12./. Prague, 04.09.2011-08.09.2011] Institutional support: RVO:61389021 Keywords : thermal spraying * plasma sintering Subject RIV: JH - Ceramics, Fire-Resistant Materials and Glass Impact factor: 0.531, year: 2012

  20. New rapid-curing, stable polyimide polymers with high-temperature strength and thermal stability

    Science.gov (United States)

    Burns, E. A.; Jones, J. F.; Kendrick, W. R.; Lubowitz, H. R.; Thorpe, R. S.; Wilson, E. R.

    1969-01-01

    Additive-type polymerization reaction forms thermally stable polyimide polymers, thereby eliminating the volatile matter attendant with the condensation reaction. It is based on the utilization of reactive alicyclic rings positioned on the ends of polyimide prepolymers having relatively low molecular weights.

  1. Non-linear pressure/temperature-dependence of high pressure thermal inactivation of proteolytic Clostridium botulinum type B in foods.

    Directory of Open Access Journals (Sweden)

    Maximilian B Maier

    Full Text Available The effect of high pressure thermal (HPT processing on the inactivation of spores of proteolytic type B Clostridium botulinum TMW 2.357 in four differently composed low-acid foods (green peas with ham, steamed sole, vegetable soup, braised veal was studied in an industrially feasible pressure range and temperatures between 100 and 120°C. Inactivation curves exhibited rapid inactivation during compression and decompression followed by strong tailing effects. The highest inactivation (approx. 6-log cycle reduction was obtained in braised veal at 600 MPa and 110°C after 300 s pressure-holding time. In general, inactivation curves exhibited similar negative exponential shapes, but maximum achievable inactivation levels were lower in foods with higher fat contents. At high treatment temperatures, spore inactivation was more effective at lower pressure levels (300 vs. 600 MPa, which indicates a non-linear pressure/temperature-dependence of the HPT spore inactivation efficiency. A comparison of spore inactivation levels achievable using HPT treatments versus a conventional heat sterilization treatment (121.1°C, 3 min illustrates the potential of combining high pressures and temperatures to replace conventional retorting with the possibility to reduce the process temperature or shorten the processing time. Finally, experiments using varying spore inoculation levels suggested the presence of a resistant fraction comprising approximately 0.01% of a spore population as reason for the pronounced tailing effects in survivor curves. The loss of the high resistance properties upon cultivation indicates that those differences develop during sporulation and are not linked to permanent modifications at the genetic level.

  2. Temperature Modulated Nanomechanical Thermal Analysis

    DEFF Research Database (Denmark)

    Alves, Gustavo Marcati A.; Bose-Goswami, Sanjukta; Mansano, Ronaldo D.

    2018-01-01

    The response of microcantilever deflection to complex heating profiles was used to study thermal events like glass transition and enthalpy relaxation on nanograms of the biopolymer Poly(lactic-co-glycolic acid) (PLGA). The use of two heating rates enables the separation of effects on the deflection...... response that depends on previous thermal history (non-reversing signal) and effects that depends only on the heating rate variation (reversing signal). As these effects may appear superposed in the total response, temperature modulation can increase the measurement sensitivity to some thermal events when...

  3. Negative thermal expansion up to 1000 C of ZrTiO4-Al2TiO5 ceramics for high-temperature applications

    International Nuclear Information System (INIS)

    Kim, I.J.; Kim, H.C.; Han, I.S.; Aneziris, C.G.

    2005-01-01

    High temperature structural ceramics based on Al 2 TiO 5 -ZrTiO 4 (ZAT) having excellent thermal-shock-resistance were synthesized by a reaction sintering. The ZAT ceramics sintered at 1600 C had a negative thermal expansions up to 1000 C and a much lower thermal expansion coefficient (0.3 ∝ 1.3 x 10 -6 /K) than that of polycrystalline Al 2 TiO 5 (1.5 x 10 -6 /K). These low thermal expansion are apparently due to a combination of microcracking caused by the large thermal expansion anisotropy of the crystal axes of the Al 2 TiO 5 phase. The microstructural degradation of the composites after various thermal treatment for high temperature applications were analyzed by scanning electron microscopy, X-ray diffraction, ultrasonic and dilatometer. (orig.)

  4. Thermal Degradation Kinetics Modeling of Benzophenones and Xanthones during High-Temperature Oxidation of Cyclopia genistoides (L.) Vent. Plant Material.

    Science.gov (United States)

    Beelders, Theresa; de Beer, Dalene; Joubert, Elizabeth

    2015-06-10

    Degradation of the major benzophenones, iriflophenone-3-C-glucoside-4-O-glucoside and iriflophenone-3-C-glucoside, and the major xanthones, mangiferin and isomangiferin, of Cyclopia genistoides followed first-order reaction kinetics during high-temperature oxidation of the plant material at 80 and 90 °C. Iriflophenone-3-C-glucoside-4-O-glucoside was shown to be the most thermally stable compound. Isomangiferin was the second most stable compound at 80 °C, while its degradation rate constant was influenced the most by increased temperature. Mangiferin and iriflophenone-3-C-glucoside had comparable degradation rate constants at 80 °C. The thermal degradation kinetic model was subsequently evaluated by subjecting different batches of plant material to oxidative conditions (90 °C/16 h). The model accurately predicted the individual contents of three of the compounds in aqueous extracts prepared from oxidized plant material. The impact of benzophenone and xanthone degradation was reflected in the decreased total antioxidant capacity of the aqueous extracts, as determined using the oxygen radical absorbance capacity and DPPH(•) scavenging assays.

  5. High-temperature stable absorber coatings for linear concentrating solar thermal power plants; Hochtemperaturstabile Absorberschichten fuer linear konzentrierende solarthermische Kraftwerke

    Energy Technology Data Exchange (ETDEWEB)

    Hildebrandt, Christina

    2009-03-23

    This work describes the development of new absorber coatings for different applications - para-bolic trough and linear Fresnel collectors - and operating conditions - absorber in vacuum or in air. The demand for higher efficiencies of solar thermal power plants using parabolic trough technology results in higher temperatures in the collectors and on the absorber tubes. As heat losses increase strongly with increasing temperatures, the need for a lower emissivity of the absorber coating at constant absorptivity arises. The linear Fresnel application envisions ab-sorber tubes stable in air at high temperatures of about 450 C, which are to date commercially not available. This work comprises the theoretical background, the modeling and the fabrication of absorber tubes including the technology transfer to a production-size inline sputter coater. In annealing tests and accompanying optical measurements, degradation processes have been observed and specified more precisely by material characterization techniques. The simulations provided the capability of different materials used as potential IR-reflector. The highest selectivity can be achieved by applying silver which consequently has been chosen for the application in absorber coatings of the parabolic trough technology. Thin silver films how-ever need to be stabilized when used at high temperatures. Appropriate barrier layers as well as process and layer parameters were identified. A high selectivity was achieved and stability of the absorber coating for 1200 h at 500 C in vacuum has been demonstrated. For the application in air, silver was also analyzed as a potential IR-reflector. Even though the stability could be increased considerably, it nevertheless proved to be insufficient. The main factors influencing stability in a positive way are the use of higher quality polishing, additional barrier layers and adequate process parameters. This knowledge was applied for developing coatings which are stable in air at

  6. The use of salinity contrast for density difference compensation to improve the thermal recovery efficiency in high-temperature aquifer thermal energy storage systems

    Science.gov (United States)

    van Lopik, Jan H.; Hartog, Niels; Zaadnoordijk, Willem Jan

    2016-08-01

    The efficiency of heat recovery in high-temperature (>60 °C) aquifer thermal energy storage (HT-ATES) systems is limited due to the buoyancy of the injected hot water. This study investigates the potential to improve the efficiency through compensation of the density difference by increased salinity of the injected hot water for a single injection-recovery well scheme. The proposed method was tested through numerical modeling with SEAWATv4, considering seasonal HT-ATES with four consecutive injection-storage-recovery cycles. Recovery efficiencies for the consecutive cycles were investigated for six cases with three simulated scenarios: (a) regular HT-ATES, (b) HT-ATES with density difference compensation using saline water, and (c) theoretical regular HT-ATES without free thermal convection. For the reference case, in which 80 °C water was injected into a high-permeability aquifer, regular HT-ATES had an efficiency of 0.40 after four consecutive recovery cycles. The density difference compensation method resulted in an efficiency of 0.69, approximating the theoretical case (0.76). Sensitivity analysis showed that the net efficiency increase by using the density difference compensation method instead of regular HT-ATES is greater for higher aquifer hydraulic conductivity, larger temperature difference between injection water and ambient groundwater, smaller injection volume, and larger aquifer thickness. This means that density difference compensation allows the application of HT-ATES in thicker, more permeable aquifers and with larger temperatures than would be considered for regular HT-ATES systems.

  7. Thermal analysis and temperature characteristics of a braking resistor for high-speed trains for changes in the braking current

    Science.gov (United States)

    Lee, Dae-Dong; Kang, Hyun-Il; Shim, Jae-Myung

    2015-09-01

    Electric brake systems are used in high-speed trains to brake trains by converting the kinetic energy of a railway vehicle to electric energy. The electric brake system consists of a regenerative braking system and a dynamic braking system. When the electric energy generated during the dynamic braking process is changed to heat through the braking resistor, the braking resistor can overheat; thus, failures can occur to the motor block. In this paper, a braking resistor for a high-speed train was used to perform thermal analyses and tests, and the results were analyzed. The analyzed data were used to estimate the dependence of the brake currents and the temperature rises on speed changes up to 300 km/h, at which a test could not be performed.

  8. Reduced thermal budget processing of Y--Ba--Cu--O high temperature superconducting thin films by metalorganic chemical vapor deposition

    International Nuclear Information System (INIS)

    Singh, R.; Sinha, S.; Hsu, N.J.; Ng, J.T.C.; Chou, P.; Thakur, R.P.S.; Narayan, J.

    1991-01-01

    Metalorganic chemical vapor deposition (MOCVD) has the potential of emerging as a viable technique to fabricate ribbons, tapes, coated wires, and the deposition of films of high temperature superconductors, and related materials. As a reduced thermal budget processing technique, rapid isothermal processing (RIP) based on incoherent radiation as the source of energy can be usefully coupled to conventional MOCVD. In this paper we report on the deposition and characterization of high quality superconducting thin films of Y--Ba--Cu--O (YBCO) on MgO and SrTiO 3 substrates by RIP assisted MOCVD. By using a mixture of N 2 O and O 2 as the oxygen source films deposited initially at 600 degree C for 1 min and then at 740 degree C for 30 min are primarily c-axis oriented and with zero resistance being observed at 84 and 89 K for MgO and SrTiO 3 substrates, respectively. The zero magnetic field current densities at 77 K for MgO and SrTiO 3 substrates are 1.2x10 6 and 1.5x10 6 A/cm 2 , respectively. It is envisaged that high energy photons from the incoherent light source and the use of a mixture of N 2 O and O 2 as the oxygen source, assist chemical reactions and lower overall thermal budget for processing of these films

  9. Techno-economic study of hydrogen production by high temperature electrolysis and coupling with different thermal energy sources

    International Nuclear Information System (INIS)

    Rivera-Tinoco, R.

    2009-03-01

    This work focuses on the techno-economic study of massive hydrogen production by the High Temperature Electrolysis (HTE) process and also deals with the possibility of producing the steam needed in the process by using different thermal energy sources. Among several sources, those retained in this study are the biomass and domestic waste incineration units, as well as two nuclear reactors (European Pressurised water Reactor - EPR and Sodium Fast Reactor - SFR). Firstly, the technical evaluation of the steam production by each of these sources was carried out. Then, the design and modelling of the equipments composing the process, specially the electrolysers (Solid Oxides Electrolysis Cells), are presented. Finally, the hydrogen production cost for each energy sources coupled with the HTE process is calculated. Moreover, several sensibility studies were performed in order to determine the process key parameter and to evaluate the influence of the unit size effect, the electric energy cost, maintenance, the cells current density, their investment cost and their lifespan on the hydrogen production cost. Our results show that the thermal energy cost is much more influent on the hydrogen production cost than the steam temperature at the outlet stream of the thermal source. It seems also that the key parameters for this process are the electric energy cost and the c ells lifespan. The first one contributes for more than 70% of the hydrogen production cost. From several cell lifespan values, it seems that a 3 year value, rather than 1 year, could lead to a hydrogen production cost reduced on 34%. However, longer lifespan values going from 5 to 10 years would only lead to a 8% reduction on the hydrogen production cost. (author)

  10. Highly efficient high temperature electrolysis

    DEFF Research Database (Denmark)

    Hauch, Anne; Ebbesen, Sune; Jensen, Søren Højgaard

    2008-01-01

    High temperature electrolysis of water and steam may provide an efficient, cost effective and environmentally friendly production of H-2 Using electricity produced from sustainable, non-fossil energy sources. To achieve cost competitive electrolysis cells that are both high performing i.e. minimum...... internal resistance of the cell, and long-term stable, it is critical to develop electrode materials that are optimal for steam electrolysis. In this article electrolysis cells for electrolysis of water or steam at temperatures above 200 degrees C for production of H-2 are reviewed. High temperature...... electrolysis is favourable from a thermodynamic point of view, because a part of the required energy can be supplied as thermal heat, and the activation barrier is lowered increasing the H-2 production rate. Only two types of cells operating at high temperature (above 200 degrees C) have been described...

  11. Peculiar Features of Thermal Aging and Degradation of Rapidly Quenched Stainless Steels under High-Temperature Exposures

    Science.gov (United States)

    Shulga, A. V.

    2017-12-01

    This article presents the results of comparative studies of mechanical properties and microstructure of nuclear fuel tubes and semifinished stainless steel items fabricated by consolidation of rapidly quenched powders and by conventional technology after high-temperature exposures at 600 and 700°C. Tensile tests of nuclear fuel tube ring specimens of stainless austenitic steel of grade AISI 316 and ferritic-martensitic steel are performed at room temperature. The microstructure and distribution of carbon and boron are analyzed by metallography and autoradiography in nuclear fuel tubes and semifinished items. Rapidly quenched powders of the considered steels are obtained by the plasma rotating electrode process. Positive influence of consolidation of rapidly quenched powders on mechanical properties after high-temperature aging is confirmed. The correlation between homogeneous distribution of carbon and boron and mechanical properties of the considered steel is determined. The effects of thermal aging and degradation of the considered steels are determined at 600°C and 700°C, respectively.

  12. Thermo-Mechanical and Thermal behavior of High-Temperature Structural Materials.

    Science.gov (United States)

    1982-12-31

    EPR spectrum at 80K of an "as-grown" MgO:Ni crystal with the magnetic field ranging from 0 to 500 Gauss oriented along the > axis. The single...3000 4000 5000 GAUSS -Fig. 2. EPR spectrum of Ni-doped MgO crystal (a) before and (b) after being reduced for 2 hours. T-B0 :L!{)gt 1o 161 A MgO 14 0...Band 24, 5 P01g., Nov. 1935 , pp. 636-664. 13. BrennanJ. J., Bentsen, L. D., and Hasselman, D.P.H., "Measurement of the Thermal Conductivity and

  13. High-temperature acquifer thermal storage and underground heat storage; IEA ECES Annex 12: Hochtemperatur-Erdwaermesonden- und Aquiferwaermespeicher

    Energy Technology Data Exchange (ETDEWEB)

    Sanner, B.; Knoblich, K. [Giessen Univ. (Germany). Inst. fuer Angewandte Geowissenschaften; Koch, M.; Adinolfi, M. [Stuttgart Univ. (Germany). Inst. fuer Siedlungswasserbau, Wasserguete und Abfallwirtschaft

    1998-12-31

    Heat storage is essential for the reconciliation of heat supply and demand. The earth has already proved to be an excellent medium for storing large amounts of heat over longer periods of time, for instance during the cold and hot season. The efficiency of the storage is the better the lower storage losses are at high temperature levels. Unfortunately this can not be easily achieved. While thermal underground stores, which are widely used for cold storage, have proved to perform quite well at temperatures between 10 C - 40 C, it has been rather difficult to achieve similar results at higher temperatures up to 150 C as test and demonstration plants of the 1980s proved. This issue has again attracted so much interest that the IEA launched a project on high temperature underground storage in December 1998. (orig.) [Deutsch] Waermespeicherung ist von entscheidender Bedeutung, wenn es darum geht, ein Waermeangebot mit einer Waermenachfrage zeitlich zur Deckung zu bringen. Der Untergrund hat sich schon seit vielen Jahren als ein geeignetes Medium erwiesen, groessere Waermepumpen ueber laengere Zeitraeume wie etwa die kalten und warmen Jahreszeiten zu speichern. Die Effizienz eines solchen Speichers steigt mit der Hoehe des erreichten Temperaturniveaus und mit sinkenden Speicherverlusten, was leider eher gegenlaeufige Erscheinungen sind. Waehrend thermische Untergrundspeicher im Temperaturbereich von 10-40 C inzwischen erfolgreich demonstriert wurden und vor allem zur Kaeltespeicherung auch bereits vielfach eingesetzt werden, haben hoehere Temperaturen bis etwa 150 C in den Versuchs- und Demonstrationsanlagen der 80er Jahre vielfaeltige Probleme bereitet. Im Gefolge eines erneuten Interesses an unterirdischer thermischer Energiespeicherung wurde im Dezember 1997 ein Vorhaben des IEA Energiespeicherprogramms zu Untergrund-Waermespeichern hoeherer Temperatur eingerichtet. (orig.)

  14. Active (air-cooled) vs. passive (phase change material) thermal management of high power lithium-ion packs: Limitation of temperature rise and uniformity of temperature distribution

    Energy Technology Data Exchange (ETDEWEB)

    Sabbah, Rami; Kizilel, R.; Selman, J.R.; Al-Hallaj, S. [Center for Electrochemical Science and Engineering, Department of Chemical and Biological Engineering, Illinois Institute of Technology, 10 W. 33rd Street, Chicago, IL 60616 (United States)

    2008-08-01

    The effectiveness of passive cooling by phase change materials (PCM) is compared with that of active (forced air) cooling. Numerical simulations were performed at different discharge rates, operating temperatures and ambient temperatures of a compact Li-ion battery pack suitable for plug-in hybrid electric vehicle (PHEV) propulsion. The results were also compared with experimental results. The PCM cooling mode uses a micro-composite graphite-PCM matrix surrounding the array of cells, while the active cooling mode uses air blown through the gaps between the cells in the same array. The results show that at stressful conditions, i.e. at high discharge rates and at high operating or ambient temperatures (for example 40-45 C), air-cooling is not a proper thermal management system to keep the temperature of the cell in the desirable operating range without expending significant fan power. On the other hand, the passive cooling system is able to meet the operating range requirements under these same stressful conditions without the need for additional fan power. (author)

  15. Active (air-cooled) vs. passive (phase change material) thermal management of high power lithium-ion packs: Limitation of temperature rise and uniformity of temperature distribution

    Science.gov (United States)

    Sabbah, Rami; Kizilel, R.; Selman, J. R.; Al-Hallaj, S.

    The effectiveness of passive cooling by phase change materials (PCM) is compared with that of active (forced air) cooling. Numerical simulations were performed at different discharge rates, operating temperatures and ambient temperatures of a compact Li-ion battery pack suitable for plug-in hybrid electric vehicle (PHEV) propulsion. The results were also compared with experimental results. The PCM cooling mode uses a micro-composite graphite-PCM matrix surrounding the array of cells, while the active cooling mode uses air blown through the gaps between the cells in the same array. The results show that at stressful conditions, i.e. at high discharge rates and at high operating or ambient temperatures (for example 40-45 °C), air-cooling is not a proper thermal management system to keep the temperature of the cell in the desirable operating range without expending significant fan power. On the other hand, the passive cooling system is able to meet the operating range requirements under these same stressful conditions without the need for additional fan power.

  16. Thermal fluid dynamics study of nuclear advanced reactors of high temperature using RELAP5-3D

    International Nuclear Information System (INIS)

    Scari, Maria Elizabeth

    2017-01-01

    Fourth Generation nuclear reactors (GEN-IV) are being designed with special features such as intrinsic safety, reduction of isotopic inventory and use of fuel in proliferation-resistant cycles. Therefore, the investigation and evaluation of operational and safety aspects of the GEN-IV reactors have been the subject of numerous studies by the international community and also in Brazil. In 2008, in Brazil, was created the National Institute of Science and Technology of Innovative Nuclear Reactors, focusing on studies of projects and systems of new generation reactors, which included GEN-IV reactors as well as advanced PWR (Pressurized Water Reactor) concepts. The Department of Nuclear Engineering of the Federal University of Minas Gerais (DEN-UFMG) is a partner of this Institute, having started studies on the GEN-IV reactors in the year 2007. Therefore, in order to add knowledge to these studies, in this work, three projects of advanced reactors were considered to verify the simulation capability of the thermo-hydraulic RELAP5-3D code for these systems, either in stationary operation or in transient situations. The addition of new working fluids such as ammonia, carbon dioxide, helium, hydrogen, various types of liquid salts, among them Flibe, lead, lithium-bismuth, lithium-lead, was a major breakthrough in this version of the code, allowing also the simulation of GEN-IV reactors. The modeling of the respective core of an HTTR (High Temperature Engineering Test Reactor), HTR-10 (High Temperature Test Module Reactor) and LS-VHTR (Liquid-Salt-Cooled Very-High-Temperature Reactor) were developed and verified in steady state comparing the values found through the calculations with reference data from other simulations, when it is possible. The first two reactors use helium gas as coolant and the LS-VHTR uses a mixture of 66% LiF and 34% of BeF 2 , the LiF-BeF 2 , also know as Flibe. All the studied reactors use enriched uranium as fuel, in form of TRISO (Tristructural

  17. Controlling Growth High Uniformity Indium Selenide (In2Se3) Nanowires via the Rapid Thermal Annealing Process at Low Temperature.

    Science.gov (United States)

    Hsu, Ya-Chu; Hung, Yu-Chen; Wang, Chiu-Yen

    2017-09-15

    High uniformity Au-catalyzed indium selenide (In 2 Se 3) nanowires are grown with the rapid thermal annealing (RTA) treatment via the vapor-liquid-solid (VLS) mechanism. The diameters of Au-catalyzed In 2 Se 3 nanowires could be controlled with varied thicknesses of Au films, and the uniformity of nanowires is improved via a fast pre-annealing rate, 100 °C/s. Comparing with the slower heating rate, 0.1 °C/s, the average diameters and distributions (standard deviation, SD) of In 2 Se 3 nanowires with and without the RTA process are 97.14 ± 22.95 nm (23.63%) and 119.06 ± 48.75 nm (40.95%), respectively. The in situ annealing TEM is used to study the effect of heating rate on the formation of Au nanoparticles from the as-deposited Au film. The results demonstrate that the average diameters and distributions of Au nanoparticles with and without the RTA process are 19.84 ± 5.96 nm (30.00%) and about 22.06 ± 9.00 nm (40.80%), respectively. It proves that the diameter size, distribution, and uniformity of Au-catalyzed In 2 Se 3 nanowires are reduced and improved via the RTA pre-treated. The systemic study could help to control the size distribution of other nanomaterials through tuning the annealing rate, temperatures of precursor, and growth substrate to control the size distribution of other nanomaterials. Graphical Abstract Rapid thermal annealing (RTA) process proved that it can uniform the size distribution of Au nanoparticles, and then it can be used to grow the high uniformity Au-catalyzed In 2 Se 3 nanowires via the vapor-liquid-solid (VLS) mechanism. Comparing with the general growth condition, the heating rate is slow, 0.1 °C/s, and the growth temperature is a relatively high growth temperature, > 650 °C. RTA pre-treated growth substrate can form smaller and uniform Au nanoparticles to react with the In 2 Se 3 vapor and produce the high uniformity In 2 Se 3 nanowires. The in situ annealing TEM is used to realize the effect of heating

  18. A mathematical and numerical framework for the analysis of compressible thermal convection in gases at very high temperatures

    Energy Technology Data Exchange (ETDEWEB)

    Lappa, Marcello, E-mail: marcello.lappa@strath.ac.uk

    2016-05-15

    The relevance of non-equilibrium phenomena, nonlinear behavior, gravitational effects and fluid compressibility in a wide range of problems related to high-temperature gas-dynamics, especially in thermal, mechanical and nuclear engineering, calls for a concerted approach using the tools of the kinetic theory of gases, statistical physics, quantum mechanics, thermodynamics and mathematical modeling in synergy with advanced numerical strategies for the solution of the Navier–Stokes equations. The reason behind such a need is that in many instances of relevance in this field one witnesses a departure from canonical models and the resulting inadequacy of standard CFD approaches, especially those traditionally used to deal with thermal (buoyancy) convection problems. Starting from microscopic considerations and typical concepts of molecular dynamics, passing through the Boltzmann equation and its known solutions, we show how it is possible to remove past assumptions and elaborate an algorithm capable of targeting the broadest range of applications. Moving beyond the Boussinesq approximation, the Sutherland law and the principle of energy equipartition, the resulting method allows most of the fluid properties (density, viscosity, thermal conductivity, heat capacity and diffusivity, etc.) to be derived in a rational and natural way while keeping empirical contamination to the minimum. Special attention is deserved as well to the well-known pressure issue. With the application of the socalled multiple pressure variables concept and a projection-like numerical approach, difficulties with such a term in the momentum equation are circumvented by allowing the hydrodynamic pressure to decouple from its thermodynamic counterpart. The final result is a flexible and modular framework that on the one hand is able to account for all the molecule (translational, rotational and vibrational) degrees of freedom and their effective excitation, and on the other hand can guarantee

  19. Video and thermal imaging system for monitoring interiors of high temperature reaction vessels

    Science.gov (United States)

    Saveliev, Alexei V [Chicago, IL; Zelepouga, Serguei A [Hoffman Estates, IL; Rue, David M [Chicago, IL

    2012-01-10

    A system and method for real-time monitoring of the interior of a combustor or gasifier wherein light emitted by the interior surface of a refractory wall of the combustor or gasifier is collected using an imaging fiber optic bundle having a light receiving end and a light output end. Color information in the light is captured with primary color (RGB) filters or complimentary color (GMCY) filters placed over individual pixels of color sensors disposed within a digital color camera in a BAYER mosaic layout, producing RGB signal outputs or GMCY signal outputs. The signal outputs are processed using intensity ratios of the primary color filters or the complimentary color filters, producing video images and/or thermal images of the interior of the combustor or gasifier.

  20. Geological exploration for a high-temperature aquifer thermal energy storage (HT-ATES) system: a case study from Oman

    Science.gov (United States)

    Winterleitner, Gerd; Schütz, Felina; Huenges, Ernst

    2017-04-01

    , as second potential storage horizon, were deposited in a carbonate ramp setting. Individual facies belts extend over kilometres and thus horizontal reservoir connectivity is expected to be good with minor facies variability. Thin-section analyses point to the fossil-rich sections with high porosities and permeabilities and thus good storage qualities. Fluid flow and thermal modelling indicate that both potential storage horizons show good to very good storage characteristics but also have challenges such as reservoir heterogeneity and connectivity. In particular the tilting of the thermocline, specific to high-temperature systems poses a major challenge. We investigated scenarios to counterbalance the distortion of the subsurface heat-plume, which includes adjustments of the salinity contrast between injected and aquifer fluid to prohibit buoyancy-driven flow. Additionally, geological structures ("HT-ATES traps" e.g.: fault structures) were modelled in detail in order to analyse their suitability as high-temperature storage system. First results show that an effective HT-ATES trap is necessary in the alluvial fan system in order to keep in control of the heat-plume. Salinity adjustments are sufficient in the carbonate-dominated sequences where vertical permeability contrasts are higher and constitute natural vertical flow barriers.

  1. Thermal properties of KUO3(s) and K2U2O7 - by high temperature Calvet calorimeter

    International Nuclear Information System (INIS)

    Jayanthi, K.; Iyer, V.S.; Venugopal, V.

    1998-01-01

    The thermal properties of KUO 3 (s) and K 2 U 2 O 7 (s) were determined using a high temperature Calvet calorimeter by drop method. The enthalpy increments, (H T o - H 298.15 0 ), in kJ/mol for KUO 3 (s) and K 2 U 2 O 7 (s) can be represented by, H T o - H 298.15 0 KUO 3 (s) kJ/mol ± 0.7 = -39.15 + 0.129T + 0.1005x10 -4 T 2 (369-714K) and H T o -H 298.15 0 K 2 U 2 O 7 (s) kJ/mol ± 0.7 = -52.99 + 0.1361T + 0.146x10 -3 T 2 (391 - 683K). (author)

  2. Evaluation of thermal displacement behavior of high temperature piping system in power-up test of HTTR. No. 1 results up to 20 MW operation

    International Nuclear Information System (INIS)

    Hanawa, Satoshi; Kojima, Takao; Sumita, Junya; Tachibana, Yukio

    2002-03-01

    Temperature of the primary cooling system of the High Temperature Engineering Test Reactor, HTTR, becomes very high because the coolant temperature at the reactor outlet reaches 950degC, and 400degC at inlet of the reactor. Therefore, it is important to confirm the thermal displacement behavior of the high temperature piping system in the primary cooling system from the viewpoint of the structural integrity. Moreover, newly designed 3-dimensional floating support system is adopted to the cooling system, it is meaningful to verify the thermal displacement behavior of the piping system applied the 3-dimensional floating support system. In the power-up test (up to 20 MW operation), thermal displacement behavior of the high temperature piping system was measured. This paper describes the experimental and analytical results of thermal displacement characteristics of the high temperature piping system. The results showed that the resistance force induced from the supporting system effects to the thermal displacement behavior of cooling system, and the analytical results have a good agreement with the experimental results by optimizing the resistant force of the floating support system. Additionally, structural integrity at the 30 MW operation was confirmed by the analysis. (author)

  3. Colloquium 3: Thermal insulation materials in construction and in high-temperature plants. Lectures; Kolloquium 3: Waermedaemmstoffe im Bauwesen und in Hochtemperaturanlagen. Vortraege

    Energy Technology Data Exchange (ETDEWEB)

    Schlegel, E.; Gross, U.; Walter, G. [comps.

    1999-07-01

    Colloquium 3, ''Thermal insulation materials in construction and in high-temperature plants'' focused, for one thing, on the inter-relationships between the development of thermal insulation materials for construction and high-temperature applications and the development of processes and plants and, for another, on the standards of and amendments to the thermal protection ordinance. Calcium silicate and Silcapor as a thermal protection material and a high-temperature thermal insulant, respectively, are dealt with inter alia. The use of thermal insulants in industrial furnaces and different methods for measuring thermal conductivity are described. Further topics are the elements of the energy conservation ordinance being drafted, and thermal-insulation construction materials such as bricks and foam mortar. Ten papers are individually listed in the Energy database. (orig.) [German] Im Mittelpunkt des Kolloquium 3 ''Waermedaemmstoffe im Bauwesen und in Hochtemperaturanlagen'' stehen die wechselseitigen Zusammenhaenge zwischen der Entwicklung von Waermedaemmstoffen fuer das Bauwesen und die Hochtemperaturanwendung einerseits und der Prozess-und Anlagenentwicklung anderseits sowie die Normung und die Novellierung der Waermeschutzverordnung. Es wird u.a. auf den Waermedaemmstoff Calciumsilicat eingegangen ebensowie auf Silcapor als Hochtemperaturd ammstoff. Der Einsatz von Waermedaemmstoffen in Industrieoefen sowie die unterschiedlichen Messmethoden der Waermeleitfaehigkeit werden beschrieben. Weitere Themen sind die Grundlagen der kuenftigen Energiesparverordnung sowie waermedaemmende Baustoffe wie Ziegel und Porenbeton. Fuer die Datenbank Energy wurden zehn Arbeiten separat aufgenommen.

  4. Development of THYDE-HTGR: computer code for transient thermal-hydraulics of high-temperature gas-cooled reactor

    International Nuclear Information System (INIS)

    Hirano, Masashi; Hada, Kazuhiko

    1990-04-01

    The THYDE-HTGR code has been developed for transient thermal-hydraulic analyses of high-temperature gas-cooled reactors, based on the THYDE-W code. THYDE-W is a code developed at JAERI for the simulation of Light Water Reactor plant dynamics during various types of transients including loss-of-coolant accidents. THYDE-HTGR solves the conservation equations of mass, momentum and energy for compressible gas, or single-phase or two-phase flow. The major code modification from THYDE-W is to treat helium loops as well as water loops. In parallel to this, modification has been made for the neutron kinetics to be applicable to helium-cooled graphite-moderated reactors, for the heat transfer models to be applicable to various types of heat exchangers, and so forth. In order to assess the validity of the modifications, analyses of some of the experiments conducted at the High Temperature Test Loop of ERANS have been performed. In this report, the models applied in THYDE-HTGR are described focusing on the present modifications and the results from the assessment calculations are presented. (author)

  5. Capital cost expenditure of high temperature latent and sensible thermal energy storage systems

    Science.gov (United States)

    Jacob, Rhys; Saman, Wasim; Bruno, Frank

    2017-06-01

    In the following study cost estimates have been undertaken for an encapsulated phase change material (EPCM) packed bed, a packed bed thermocline and a traditional two-tank molten salt system. The effect of various heat transfer fluids (air and molten salt), system configuration (cascade vs one PCM, and direct vs indirect) and temperature difference (ΔT = 100-500 °C) on the cost estimate of the system was also investigated. Lastly, the storage system boundary was expanded to include heat exchangers, pumps and fans, and heat tracing so that a thorough cost comparison could be undertaken. The results presented in this paper provide a methodology to quickly compare various systems and configurations while providing design limits for the studied technologies.

  6. Manufacturing a Long-Period Grating with Periodic Thermal Diffusion Technology on High-NA Fiber and Its Application as a High-Temperature Sensor.

    Science.gov (United States)

    Shen, Xiang; Dai, Bin; Xing, Yingbin; Yang, Luyun; Li, Haiqing; Li, Jinyan; Peng, Jingang

    2018-05-08

    We demonstrated a kind of long-period fiber grating (LPFG), which is manufactured with a thermal diffusion treatment. The LPFG was inscribed on an ultrahigh-numerical-aperture (UHNA) fiber, highly doped with Ge and P, which was able to easily diffuse at high temperatures within a few seconds. We analyzed how the elements diffused at a high temperature over 1300 °C in the UHNA fiber. Then we developed a periodically heated technology with a CO₂ laser, which was able to cause the diffusion of the elements to constitute the modulations of an LPFG. With this technology, there is little damage to the outer structure of the fiber, which is different from the traditional LPFG, as it is periodically tapered. Since the LPFG itself was manufactured under high temperature, it can withstand higher temperatures than traditional LPFGs. Furthermore, the LPFG presents a higher sensitivity to high temperature due to the large amount of Ge doping, which is approximately 100 pm/°C. In addition, the LPFG shows insensitivity to the changing of the environment’s refractive index and strain.

  7. An Integrated Study of a Novel Thermal Coating for Nb-Based High Temperature Alloy

    Energy Technology Data Exchange (ETDEWEB)

    Yang, Shizhong [Southern Univ. and A & M College, Baton Rouge, LA (United States)

    2015-01-31

    This report summarizes our recent works of ab initio density functional theory (DFT) method and molecular dynamics (MD) simulation on the interfaces between niobium substrate and coatings at atomic level. Potential oxidation barrier bond coat, Nb₂AlC and high entropy alloys, and top coat candidates were synthesized, characterized, and evaluated in our labs. The simulation methods, experimental validation techniques, achievements already reached, students and postdoc training, and future improvement are briefly introduced.

  8. Analysis of recovery efficiency in high-temperature aquifer thermal energy storage: a Rayleigh-based method

    Science.gov (United States)

    Schout, Gilian; Drijver, Benno; Gutierrez-Neri, Mariene; Schotting, Ruud

    2014-01-01

    High-temperature aquifer thermal energy storage (HT-ATES) is an important technique for energy conservation. A controlling factor for the economic feasibility of HT-ATES is the recovery efficiency. Due to the effects of density-driven flow (free convection), HT-ATES systems applied in permeable aquifers typically have lower recovery efficiencies than conventional (low-temperature) ATES systems. For a reliable estimation of the recovery efficiency it is, therefore, important to take the effect of density-driven flow into account. A numerical evaluation of the prime factors influencing the recovery efficiency of HT-ATES systems is presented. Sensitivity runs evaluating the effects of aquifer properties, as well as operational variables, were performed to deduce the most important factors that control the recovery efficiency. A correlation was found between the dimensionless Rayleigh number (a measure of the relative strength of free convection) and the calculated recovery efficiencies. Based on a modified Rayleigh number, two simple analytical solutions are proposed to calculate the recovery efficiency, each one covering a different range of aquifer thicknesses. The analytical solutions accurately reproduce all numerically modeled scenarios with an average error of less than 3 %. The proposed method can be of practical use when considering or designing an HT-ATES system.

  9. Effects of High Temperature and Thermal Cycling on the Performance of Perovskite Solar Cells: Acceleration of Charge Recombination and Deterioration of Charge Extraction

    KAUST Repository

    Sheikh, Arif D.

    2017-09-18

    In this work, we investigated the effects of high operating temperature and thermal cycling on the photovoltaic performance of perovskite solar cells (PSCs) with a typical mesostructured (m)-TiO2-CH3NH3PbI3-xClx-spiro-OMeTAD architecture. After carrying out temperature-dependent grazing incidence wide-angle X-ray scattering (GIWAXS), in-situ X-ray diffraction (XRD) and optical absorption experiments, thermal durability of PSCs was tested by subjecting the devices to repetitive heating to 70 °C and cooling to room temperature (20 °C). An unexpected regenerative effect was observed after the first thermal cycle; the average power conversion efficiency (PCE) increased by approximately 10 % in reference to the as-prepared device. This increase of PCE was attributed to the heating-induced improvement of crystallinity and p-doping in the hole-transporter, Spiro-OMeTAD, which promotes the efficient extraction of photo-generated carriers. However, further thermal cycles produced a detrimental effect on the photovoltaic performance of PSCs with short-circuit current and fill factor degrading faster than the open-circuit voltage. Similarly, the photovoltaic performance of PSCs degraded at high operation temperatures; both short-circuit current and open-circuit voltage decreased with increasing temperature, but the temperature-dependent trend of fill factor was opposite. Our impedance spectroscopy analysis revealed a monotonous increase of charge transfer resistance and a concurrent decrease of charge recombination resistance with increasing temperature, indicating high recombination of charge carriers. Our results revealed that both thermal cycling and high temperatures produce irreversible detrimental effects on the PSC performance due to the deteriorated interfacial photo-carrier extraction. The present findings suggest that development of robust charge transporters and proper interface engineering are critical for the deployment of perovskite photovoltaics in harsh

  10. Mass separation of rare-earth elements by a high-temperature thermal ion source coupled with a He-jet system

    International Nuclear Information System (INIS)

    Kawase, Y.; Okano, K.; Aoki, K.

    1987-01-01

    By using a high-temperature thermal ion source coupled to a He-jet system, neutron-rich isotopes of rare-earth elements such as cerium, praseodymium, neodymium and promethium produced by the thermal-neutron fission of /sup 235/U were ionized and successfully separated. The temperature dependence of the ionization efficiency has been measured and found to be explained qualitatively by the vapour pressure of the relevant elements. The characteristic temperature dependence of the ionization efficiency has been utilized for Z-identification of several isobars of rare-earth elements. The heaviest isotopes of neodymium and promethium, /sup 155/Nd and /sup 156/Pm, have recently been identified

  11. Neutronics and Thermal Hydraulics Analysis of a Conceptual Ultra-High Temperature MHD Cermet Fuel Core for Nuclear Electric Propulsion

    Directory of Open Access Journals (Sweden)

    Jian Song

    2018-04-01

    Full Text Available Nuclear electric propulsion (NEP offers unique advantages for the interplanetary exploration. The extremely high conversion efficiency of magnetohydrodynamics (MHD conversion nuclear reactor makes it a highly potential space power source in the future, especially for NEP systems. Research on ultra-high temperature reactor suitable for MHD power conversion is performed in this paper. Cermet is chosen as the reactor fuel after a detailed comparison with the (U,ZrC graphite-based fuel and mixed carbide fuel. A reactor design is carried out as well as the analysis of the reactor physics and thermal-hydraulics. The specific design involves fuel element, reactor core, and radiation shield. Two coolant channel configurations of fuel elements are considered and both of them can meet the demands. The 91 channel configuration is chosen due to its greater heat transfer performance. Besides, preliminary calculation of nuclear criticality safety during launch crash accident is also presented. The calculation results show that the current design can meet the safety requirements well.

  12. Ghosts of thermal past: reef fish exposed to historic high temperatures have heightened stress response to further stressors

    Science.gov (United States)

    Mills, S. C.; Beldade, R.; Chabanet, P.; Bigot, L.; O'Donnell, J. L.; Bernardi, G.

    2015-12-01

    Individual exposure to stressors can induce changes in physiological stress responses through modulation of the hypothalamic-pituitary-interrenal (HPI) axis. Despite theoretical predictions, little is known about how individuals will respond to unpredictable short-lived stressors, such as thermal events. We examine the primary neuroendocrine response of coral reef fish populations from the Îles Eparses rarely exposed to anthropogenic stress, but that experienced different thermal histories. Skunk anemonefish, Amphiprion akallopisos, showed different cortisol responses to a generic stressor between islands, but not along a latitudinal gradient. Those populations previously exposed to higher maximum temperatures showed greater responses of their HPI axis. Archive data reveal thermal stressor events occur every 1.92-6 yr, suggesting that modifications to the HPI axis could be adaptive. Our results highlight the potential for adaptation of the HPI axis in coral reef fish in response to a climate-induced thermal stressor.

  13. Discharging process of a finned heat pipe–assisted thermal energy storage system with high temperature phase change material

    International Nuclear Information System (INIS)

    Tiari, Saeed; Qiu, Songgang; Mahdavi, Mahboobe

    2016-01-01

    Highlights: • The discharging process of a latent heat thermal energy storage system is studied. • The thermal energy storage system is assisted by finned heat pipes. • The influences of heat pipe spacing and fins geometrical features are studied. • Smaller heat pipe spacing enhances the solidification rate. • Better heat pipe and fin arrangements are determined. - Abstract: This paper presents the results of a numerical study conducted to investigate the discharging process of a latent heat thermal energy storage system assisted by finned heat pipes. A two-dimensional finite volume based numerical model along with enthalpy-porosity technique is employed to simulate the phase change of storage media during the discharging mode. The thermal energy storage system in this study consists of a square container, finned heat pipes, and potassium nitrate (KNO 3 ) as the phase change material. The charging process of the same thermal energy storage system was reported in an early paper by the authors. This paper reports the results of discharging process of the thermal energy storage system. The influences of heat pipe spacing, fin geometry and quantities as well as the effects of natural convection heat transfer on the thermal performance of the storage system were studied. The results indicate that the phase change material solidification process is hardly affected by the natural convection. Decreasing the heat pipe spacing results in faster discharging process and higher container base wall temperature. Increasing the fins length does not change the discharging time but yields higher base wall temperature. Using more fins also accelerates the discharging process and increases the container base wall temperature.

  14. Thermal expansion of diamond at low temperatures.

    Science.gov (United States)

    Stoupin, Stanislav; Shvyd'ko, Yuri V

    2010-02-26

    Temperature variation of a lattice parameter of a synthetic diamond crystal (type IIa) was measured using high-energy-resolution x-ray Bragg diffraction in backscattering. A 2 order of magnitude improvement in the measurement accuracy allowed us to directly probe the linear thermal expansion coefficient at temperatures below 100 K. The lowest value measured was 2x10{-9} K-1. It was found that the coefficient deviates from the expected Debye law (T3) while no negative thermal expansion was observed. The anomalous behavior might be attributed to tunneling states due to low concentration impurities.

  15. Pore Scale Thermal Hydraulics Investigations of Molten Salt Cooled Pebble Bed High Temperature Reactor with BCC and FCC Configurations

    Directory of Open Access Journals (Sweden)

    Shixiong Song

    2014-01-01

    CFD results and empirical correlations’ predictions of pressure drop and local Nusselt numbers. Local pebble surface temperature distributions in several default conditions are investigated. Thermal removal capacities of molten salt are confirmed in the case of nominal condition; the pebble surface temperature under the condition of local power distortion shows the tolerance of pebble in extreme neutron dose exposure. The numerical experiments of local pebble insufficient cooling indicate that in the molten salt cooled pebble bed reactor, the pebble surface temperature is not very sensitive to loss of partial coolant. The methods and results of this paper would be useful for optimum designs and safety analysis of molten salt cooled pebble bed reactors.

  16. Thermal expansivity and bulk modulus of ZnO with NaCl-type cubic structure at high pressures and temperatures

    International Nuclear Information System (INIS)

    Sun Xiaowei; Liu Zijiang; Chen Qifeng; Chu Yandong; Wang Chengwei

    2006-01-01

    The thermal expansivity and bulk modulus of ZnO with NaCl-type cubic structure were estimated by using the constant temperature and pressure molecular dynamics technique with effective pair potentials which consist of the Coulomb, dispersion, and repulsion interaction at high pressures and temperatures. It is shown that the calculated thermodynamic parameters including linear thermal expansion coefficient, isothermal bulk modulus and its pressure derivative are in good agreement with the available experimental data and the latest theoretical results. At an extended pressure and temperature ranges, linear thermal expansion coefficient and isothermal bulk modus have also been predicted. The thermodynamic properties of ZnO with NaCl-type cubic structure are summarized in the pressure 0-150 GPa ranges and the temperature up to 3000 K

  17. Natural convection of high-temperature, high-pressure gas in a horizontal annular layer of thermal insulator, (1)

    International Nuclear Information System (INIS)

    Ogawa, Masuro; Takizuka, Takakazu; Sanokawa, Konomo

    1979-02-01

    Numerical calculations are described of the natural convection in a horizontal annular layer of thermal insulator. The purpose is to compare the numerical results for variable physical properties with those for constant properties. The numerical procedure and typical results are presented. (author)

  18. High temperature pipeline design

    Energy Technology Data Exchange (ETDEWEB)

    Greenslade, J.G. [Colt Engineering, Calgary, AB (Canada). Pipelines Dept.; Nixon, J.F. [Nixon Geotech Ltd., Calgary, AB (Canada); Dyck, D.W. [Stress Tech Engineering Inc., Calgary, AB (Canada)

    2004-07-01

    It is impractical to transport bitumen and heavy oil by pipelines at ambient temperature unless diluents are added to reduce the viscosity. A diluted bitumen pipeline is commonly referred to as a dilbit pipeline. The diluent routinely used is natural gas condensate. Since natural gas condensate is limited in supply, it must be recovered and reused at high cost. This paper presented an alternative to the use of diluent to reduce the viscosity of heavy oil or bitumen. The following two basic design issues for a hot bitumen (hotbit) pipeline were presented: (1) modelling the restart problem, and, (2) establishing the maximum practical operating temperature. The transient behaviour during restart of a high temperature pipeline carrying viscous fluids was modelled using the concept of flow capacity. Although the design conditions were hypothetical, they could be encountered in the Athabasca oilsands. It was shown that environmental disturbances occur when the fluid is cooled during shut down because the ground temperature near the pipeline rises. This can change growing conditions, even near deeply buried insulated pipelines. Axial thermal loads also constrain the design and operation of a buried pipeline as higher operating temperatures are considered. As such, strain based design provides the opportunity to design for higher operating temperature than allowable stress based design methods. Expansion loops can partially relieve the thermal stress at a given temperature. As the design temperature increase, there is a point at which above grade pipelines become attractive options, although the materials and welding procedures must be suitable for low temperature service. 3 refs., 1 tab., 10 figs.

  19. Solvothermal method as a green chemistry solution for micro-encapsulation of phase change materials for high temperature thermal energy storage

    Science.gov (United States)

    Tudor, Albert Ioan; Motoc, Adrian Mihail; Ciobota, Cristina Florentina; Ciobota, Dan. Nastase; Piticescu, Radu Robert; Romero-Sanchez, Maria Dolores

    2018-05-01

    Thermal energy storage systems using phase change materials (PCMs) as latent heat storage are one of the main challenges at European level in improving the performances and efficiency of concentrated solar power energy generation due to their high energy density. PCM with high working temperatures in the temperature range 300-500 °C are required for these purposes. However their use is still limited due to the problems raised by the corrosion of the majority of high temperature PCMs and lower thermal transfer properties. Micro-encapsulation was proposed as one method to overcome these problems. Different micro-encapsulation methods proposed in the literature are presented and discussed. An original process for the micro-encapsulation of potassium nitrate as PCM in inorganic zinc oxide shells based on a solvothermal method followed by spray drying to produce microcapsules with controlled phase composition and distribution is proposed and their transformation temperatures and enthalpies measured by differential scanning calorimetry are presented.

  20. Low temperature thermal conductivities of glassy carbons

    International Nuclear Information System (INIS)

    Anderson, A.C.

    1979-01-01

    The thermal conductivity of glassy carbon in the temperature range 0.1 to 100 0 K appears to depend only on the temperature at which the material was pyrolyzed. The thermal conductivity can be related to the microscopic structure of glassy carbon. The reticulated structure is especially useful for thermal isolation at cryogenic temperatures

  1. Local temperature in quantum thermal states

    International Nuclear Information System (INIS)

    Garcia-Saez, Artur; Ferraro, Alessandro; Acin, Antonio

    2009-01-01

    We consider blocks of quantum spins in a chain at thermal equilibrium, focusing on their properties from a thermodynamical perspective. In a classical system the temperature behaves as an intensive magnitude, above a certain block size, regardless of the actual value of the temperature itself. However, a deviation from this behavior is expected in quantum systems. In particular, we see that under some conditions the description of the blocks as thermal states with the same global temperature as the whole chain fails. We analyze this issue by employing the quantum fidelity as a figure of merit, singling out in detail the departure from the classical behavior. As it may be expected, we see that quantum features are more prominent at low temperatures and are affected by the presence of zero-temperature quantum phase transitions. Interestingly, we show that the blocks can be considered indeed as thermal states with a high fidelity, provided an effective local temperature is properly identified. Such a result may originate from typical properties of reduced subsystems of energy-constrained Hilbert spaces. Finally, the relation between local and global temperatures is analyzed as a function of the size of the blocks and the system parameters.

  2. Thermal expansion and density measurements of molten and solid materials at high temperatures by the gamma attenuation technique

    International Nuclear Information System (INIS)

    Drotning, W.D.

    1979-05-01

    An apparatus is described for the measurement of the density and thermal expansion of molten materials to 3200 0 K using the gamma attenuation technique. The precision of the experimental technique was analytically examined for both absolute and relative density determinations. Three analytical expressions used to reduce data for liquid density determinations were evaluated for their precision. Each allows use of a different set of input data parameters, which can be chosen based on experimental considerations. Using experimentally reasonable values for the precision of the parameters yields a similar resultant density precision from the three methods, on the order of 0.2%. The analytical method for measurements of the linear thermal expansion of solids by the gamma method is also described. To demonstrate the use of the technique on reasonably well-characterized systems, data are presented for (1) the density and thermal expansion of molten tin, lead, and aluminum to 1300 0 K, (2) the thermal expansion of solid aluminum to the melting point, and (3) the thermal expansion of a low melting point glass through the transition temperature and melting region. The data agree very well with published results using other methods where such published data exist

  3. Bimetallic low thermal-expansion panels of Co-base and silicide-coated Nb-base alloys for high-temperature structural applications

    International Nuclear Information System (INIS)

    Rhein, R.K.; Novak, M.D.; Levi, C.G.; Pollock, T.M.

    2011-01-01

    Research highlights: → Low net thermal expansion bimetallic structural lattice constructed. → Temperatures on the order of 1000 deg. C reached. → Improved silicide coating for niobium alloy developed. - Abstract: The fabrication and high temperature performance of low thermal expansion bimetallic lattices composed of Co-base and Nb-base alloys have been investigated. A 2D sheet lattice with a coefficient of thermal expansion (CTE) lower than the constituent materials of construction was designed for thermal cycling to 1000 deg. C with the use of elastic-plastic finite element analyses. The low CTE lattice consisted of a continuous network of the Nb-base alloy C-103 with inserts of high CTE Co-base alloy Haynes 188. A new coating approach wherein submicron alumina particles were incorporated into (Nb, Cr, Fe) silicide coatings was employed for oxidation protection of the Nb-base alloy. Thermal gravimetric analysis results indicate that the addition of submicron alumina particles reduced the oxidative mass gain by a factor of four during thermal cycling, increasing lifetime. Bimetallic cells with net expansion of 6 x 10 -6 /deg. C and 1 x 10 -6 /deg. C at 1000 deg. C were demonstrated and their measured thermal expansion characteristics were consistent with analytical models and finite element analysis predictions.

  4. Effects of High Temperature and Thermal Cycling on the Performance of Perovskite Solar Cells: Acceleration of Charge Recombination and Deterioration of Charge Extraction

    KAUST Repository

    Sheikh, Arif D.; Munir, Rahim; Haque, Mohammed; Bera, Ashok; Hu, Weijin; Shaikh, Parvez Abdul Ajij; Amassian, Aram; Wu, Tao

    2017-01-01

    In this work, we investigated the effects of high operating temperature and thermal cycling on the photovoltaic performance of perovskite solar cells (PSCs) with a typical mesostructured (m)-TiO2-CH3NH3PbI3-xClx-spiro-OMeTAD architecture. After

  5. High Thermal Conductivity Materials

    CERN Document Server

    Shinde, Subhash L

    2006-01-01

    Thermal management has become a ‘hot’ field in recent years due to a need to obtain high performance levels in many devices used in such diverse areas as space science, mainframe and desktop computers, optoelectronics and even Formula One racing cars! Thermal solutions require not just taking care of very high thermal flux, but also ‘hot spots’, where the flux densities can exceed 200 W/cm2. High thermal conductivity materials play an important role in addressing thermal management issues. This volume provides readers a basic understanding of the thermal conduction mechanisms in these materials and discusses how the thermal conductivity may be related to their crystal structures as well as microstructures developed as a result of their processing history. The techniques for accurate measurement of these properties on large as well as small scales have been reviewed. Detailed information on the thermal conductivity of diverse materials including aluminum nitride (AlN), silicon carbide (SiC), diamond, a...

  6. High temperature study on the thermal properties of few-layer Mo0.5W0.5S2 and effects of capping layers

    Directory of Open Access Journals (Sweden)

    Hong Gu

    Full Text Available We investigated the thermal properties of few-layer Mo0.5W0.5S2 using a series of samples with different kinds of capping layers. Temperature-dependent Raman measurements were conducted in the range of 300–500 K, with power-dependent measurements also carried out. It indicated, for the few-layer Mo0.5W0.5S2, the temperature coefficients of the WS2-like E12g mode, MoS2-like E12g mode and A1g mode were −0.0155 cm−1/K, −0.0146 cm−1/K, and −0.0130 cm−1/K, respectively. And the thermal conductivity was estimated to be 44.8 W/mK. Moreover, the Mo0.5W0.5S2 samples coated with capping layers (ZrO2, HfO2 both showed a better thermal stability and a larger thermal conductivity than the one without. The results revealed that the capping layer should be an important factor in the thermal property. Keywords: Mo0.5W0.5S2, TMDs, Thermal properties, High temperature, Capping layers, Raman

  7. Advances in high temperature chemistry

    CERN Document Server

    Eyring, Leroy

    1969-01-01

    Advances in High Temperature Chemistry, Volume 2 covers the advances in the knowledge of the high temperature behavior of materials and the complex and unfamiliar characteristics of matter at high temperature. The book discusses the dissociation energies and free energy functions of gaseous monoxides; the matrix-isolation technique applied to high temperature molecules; and the main features, the techniques for the production, detection, and diagnosis, and the applications of molecular beams in high temperatures. The text also describes the chemical research in streaming thermal plasmas, as w

  8. High temperature (>350 °C) thermal histories of the long lived (>500 Ma) active margin of Ecuador and Colombia: Apatite, titanite and rutile U-Pb thermochronology

    Science.gov (United States)

    Paul, Andre N.; Spikings, Richard A.; Ulianov, Alexey; Ovtcharova, Maria

    2018-05-01

    Quantitative reconstruction of thermal histories can be a powerful tool to study numerous natural processes such as tectonic plate interaction, cratonic stability and extra-terrestrial phenomena such as asteroid ejection. A majority of thermochronological studies have focused on temperatures lower than 300 °C. Few previous studies have demonstrated that U-Pb data from apatite and other accessory phases can be used to recover thermal history information at T > 350 °C. We present U-Pb data from apatite, to constrain the thermal histories of Triassic peralluminous anatectites from the Northern Andes between the temperatures of ∼350-550 °C. The accuracy of the thermal history models is assessed by comparisons with previous geological models, and comparisons with pre-existing and newly acquired U/Pb (titanite and rutile), 40Ar/39Ar (muscovite) and low temperature thermochronological data. This study also examines the feasibility of using a large, regionally dispersed apatite U-Pb data set to obtain continuous thermal history paths along a long-lived (>500 Ma) active margin. A second aim of this study is to further test the hypothesis that the dominant mechanism for Pb displacement through apatite is volume diffusion, as opposed to aqueous fluid interaction. The thermal history models derived from the Triassic anatectites exposed in the Andes of Colombia and Ecuador are entirely consistent with lower temperature thermochronological constraints, and previously established geochronological and geochemical constraints. They reveal and quantify trench parallel changes in the amount of Jurassic - Early Cretaceous extension, significantly bolstering and adding to previous tectonic interpretations. Confirmation of the utility of U-Pb thermochronology provides geologists with a powerful tool for investigating the high-temperature thermal evolution of accessory minerals.

  9. Experimental study on high cycle thermal fatigue in T-junction. Effect of local flow velocity on transfer of temperature fluctuation from fluid to structure

    International Nuclear Information System (INIS)

    Kimura, Nobuyuki; Ono, Ayako; Miyakoshi, Hiroyuki; Kamide, Hideki

    2009-01-01

    A quantitative evaluation on high cycle thermal fatigue due to temperature fluctuation in fluid is of importance for structural integrity in the reactor. It is necessary for the quantitative evaluation to investigate occurrence and propagation processes of temperature fluctuation, e.g., decay of fluctuation intensity near structures and transfer of temperature fluctuation from fluid to structures. The JSME published a guideline for evaluation of high-cycle thermal fatigue of a pipe as the JSME guideline in 2003. This JSME standard covers T-pipe junction used in LWRs operated in Japan. In the guideline, the effective heat transfer coefficients were obtained from temperature fluctuations in fluid and structure in experiments. In the previous studies, the effective heat transfer coefficients were 2 - 10 times larger than the heat transfer coefficients under steady state conditions in a straight tube. In this study, a water experiment of T-junction was performed to evaluate the transfer characteristics of temperature fluctuation from fluid to structure. In the experiment, temperatures in fluid and structure were measured simultaneously at 20 positions to obtain spatial distributions of the effective heat transfer coefficient. In addition, temperatures in structure and local velocities in fluid were measured simultaneously to evaluate the correlation between the temperature and velocity under the non-stationary fields. The large heat transfer coefficients were registered at the region where the local velocity was high. Furthermore it was found that the heat transfer coefficients were correlated with the time-averaged turbulent heat flux near the pipe wall. (author)

  10. High temperature storage loop :

    Energy Technology Data Exchange (ETDEWEB)

    Gill, David Dennis; Kolb, William J.

    2013-07-01

    A three year plan for thermal energy storage (TES) research was created at Sandia National Laboratories in the spring of 2012. This plan included a strategic goal of providing test capability for Sandia and for the nation in which to evaluate high temperature storage (>650ÀC) technology. The plan was to scope, design, and build a flow loop that would be compatible with a multitude of high temperature heat transfer/storage fluids. The High Temperature Storage Loop (HTSL) would be reconfigurable so that it was useful for not only storage testing, but also for high temperature receiver testing and high efficiency power cycle testing as well. In that way, HTSL was part of a much larger strategy for Sandia to provide a research and testing platform that would be integral for the evaluation of individual technologies funded under the SunShot program. DOEs SunShot program seeks to reduce the price of solar technologies to 6/kWhr to be cost competitive with carbon-based fuels. The HTSL project sought to provide evaluation capability for these SunShot supported technologies. This report includes the scoping, design, and budgetary costing aspects of this effort

  11. SCC growth behavior of stainless steel weld metals in high-temperature water. Influence of corrosion potential, weld type, thermal aging, cold-work and temperature

    International Nuclear Information System (INIS)

    Yamada, Takuyo; Terachi, Takumi; Miyamoto, Tomoki; Arioka, Koji

    2009-01-01

    Recent studies on crack growth rate measurement in oxygenated high-temperature pure water conditions, such as normal water chemistry in boiling water reactors, using compact tension type specimens have shown that weld stainless steels are susceptible to stress corrosion cracking. However, to our knowledge, there is no crack growth data of weld stainless steels in pressurized water reactor primary water. The principal purpose of this study was to examine the SCC growth behavior of stainless steel weld metals in simulated PWR primary water. A second objective was to examine the effect of (1) corrosion potential, (2) thermal-aging, (3) Mo in alloy and (4) cold-working on SCC growth in hydrogenated and oxygenated water environments at 320degC. In addition, the temperature dependence of SCC growth in simulated PWR primary water was also studied. The results were as follows: (1) No significant SCC growth was observed on all types of stainless steel weld metals: as-welded, aged (400degC x 10 kh) 308L and 316L, in 2.7 ppm-hydrogenated (low-potential) water at 320degC. (2) 20% cold-working markedly accelerated the SCC growth of weld metals in high-potential water at 320degC, but no significant SCC growth was observed in the hydrogenated water, even after 20% cold-working. (3) No significant SCC growth was observed on stainless steel weld metals in low-potential water at 250degC and 340degC. Thus, stainless steel weld metals have excellent SCC resistance in PWR primary water. On the other hand, (4) significant SCC growth was observed on all types of stainless steel weld metals: as-weld, aged (400degC x 10 kh) and 20% cold-worked 308L and 316L, in 8 ppm-oxygenated (high-potential) water at 320degC. (5) No large difference in SCC growth was observed between 316L (Mo) and 308L. (6) No large effect on SCC growth was observed between before and after aging up to 400degC for 10 kh. (7) 20% cold-working markedly accelerated the SCC growth of stainless steel weld metals. (author)

  12. Body Temperature Controlled Optical and Thermal Information Storage Light Scattering Display with Fluorescence Effect and High Mechanical Strength.

    Science.gov (United States)

    Chen, Si; Tong, Xiaoqian; He, Huiwen; Ma, Meng; Shi, Yanqin; Wang, Xu

    2017-04-05

    A kind of body temperature controlled optical and thermal information storage light scattering display based on super strong liquid crystalline physical gel with special "loofah-like gel network" was successfully prepared. Such liquid crystal (LC) gel was obtained by mixing a dendritic gelator (POSS-G1-BOC), an azobenzene compound (2Azo2), and a phosphor tethered liquid crystalline host (5CB), which could show its best contrast ratio at around human body temperature under UV light because of the phosphor's fluorescence effect. The gel also has quite strong mechanical strength, which could be used in wearable device field especially under sunlight, even under the forcing conditions as harsh as being centrifuged for 10 min at the speed of 2000 r/min. The whole production process of such a display is quite simple and could lead to displays at any size through noncontact writing. We believe it will have wide applications in the future.

  13. Wiedemann-Franz ratio in high-pressure and low-temperature thermal xenon plasma with 10% caesium

    International Nuclear Information System (INIS)

    Novakovic, N.V.; Milic, B.S.; Stojilkovic, S.M.

    1995-01-01

    Theoretical investigations of various transport properties of low-temperature noble-gas plasmas with additives has aroused a continuous interest over a considerable spall of time, due to numerous applications. In this paper the results of a theoretical evaluation of electrical conductivity, thermal conductivity and their ratio (the Wiedemann-Franz ratio) in xenon plasma with 10% of argon and 10% of caesium are presented, for the temperature range from 2000 K to 20000 K, and for pressures equal to or 5, 10, and 15 time higher than the normal atmospheric pressure. The plasma was regarded as weakly non-ideal and in the state of local thermodynamical equilibrium with the assumption that the equilibrium is attained with the pressure kept constant. The plasma composition was determined on the ground of a set of Saha equations; the ionization energy lowerings were expressed with the aid of a modified plasma Debye radius r* D (rather than the standard r D ), as proposed previously

  14. Advantages of a Vertical High-Resolution Distributed-Temperature-Sensing System Used to Evaluate the Thermal Behavior of Green Roofs

    Science.gov (United States)

    Hausner, M. B.; Suarez, F. I.; Cousiño, J. A.; Victorero, F.; Bonilla, C. A.; Gironas, J. A.; Vera, S.; Bustamante, W.; Rojas, V.; Leiva, E.; Pasten, P.

    2015-12-01

    Technological innovations used for sustainable urban development, green roofs offer a range of benefits, including reduced heat island effect, rooftop runoff, roof surface temperatures, energy consumption, and noise levels inside buildings, as well as increased urban biodiversity. Green roofs feature layered construction, with the most important layers being the vegetation and the substrate layers located above the traditional roof. These layers provide both insulation and warm season cooling by latent heat flux, reducing the thermal load to the building. To understand and improve the processes driving this thermal energy reduction, it is important to observe the thermal dynamics of a green roof at the appropriate spatial and temporal scales. Traditionally, to observe the thermal behavior of green roofs, a series of thermocouples have been installed at discrete depths within the layers of the roof. Here, we present a vertical high-resolution distributed-temperature-sensing (DTS) system installed in different green roof modules of the Laboratory of Vegetated Infrastructure for Buildings (LIVE -its acronym in Spanish) of the Pontifical Catholic University of Chile. This DTS system allows near-continuous measurement of the thermal profile at spatial and temporal resolutions of approximately 1 cm and 30 s, respectively. In this investigation, the temperature observations from the DTS system are compared with the measurements of a series of thermocouples installed in the green roofs. This comparison makes it possible to assess the value of thermal observations at better spatial and temporal resolutions. We show that the errors associated with lower resolution observations (i.e., from the thermocouples) are propagated in the calculations of the heat fluxes through the different layers of the green roof. Our results highlight the value of having a vertical high-resolution DTS system to observe the thermal dynamics in green roofs.

  15. The Development of a Low-Cost, Near Infrared, High-Temperature Thermal Imaging System and Its Application to the Retrieval of Accurate Lava Lake Temperatures at Masaya Volcano, Nicaragua

    Directory of Open Access Journals (Sweden)

    Thomas Charles Wilkes

    2018-03-01

    Full Text Available Near infrared thermal cameras can provide useful low-cost imaging systems for high temperature applications, as an alternative to ubiquitous mid-/long-wavelength infrared systems. Here, we present a new Raspberry Pi-based near infrared thermal camera for use at temperatures of ≈>500 °C. We discuss in detail the building of the optical system, calibration using a Sakuma-Hattori model and quantification of uncertainties in remote temperature retrievals. We then present results from the deployment of the system on Masaya Volcano, Nicaragua, where the active lava lake was imaged. Temperatures reached a maximum of 1104 ± 14 °C and the lake radiative power output was found to range between 30 and 45 MW. To the best of our knowledge, this is the first published ground-based data on the thermal characteristics of this relatively nascent lava lake, which became visible in late 2015.

  16. High temperature oxidation interfacial growth kinetics in YSZ thermal barrier coatings with bond coatings of NiCoCrAlY with 0.25% Hf

    Energy Technology Data Exchange (ETDEWEB)

    Soboyejo, W.O. [Department of Mechanical and Aerospace Engineering, Princeton University, Princeton, NJ 08544 (United States); Mensah, P., E-mail: mensah@engr.subr.edu [Department of Mechanical Engineering, Southern University and A and M College, Baton Rouge, LA 70813 (United States); Diwan, R. [Department of Mechanical Engineering, Southern University and A and M College, Baton Rouge, LA 70813 (United States); Crowe, J. [Department of Mechanical and Aerospace Engineering, Princeton University, Princeton, NJ 08544 (United States); Akwaboa, S. [Department of Mechanical Engineering, Southern University and A and M College, Baton Rouge, LA 70813 (United States)

    2011-03-15

    Research highlights: {yields} Isothermal oxidation of standard (STD) and vertically cracked (VC) TBCs has been investigated. {yields} The temporal TGO growth kinetics is parabolic in the temperature range between 900 and 1100 deg. C. {yields} Activation energies correspond to growth kinetics controlled by the diffusion of O{sub 2} in Al{sub 2}O{sub 3}. {yields} Variation in oxidation of TBCs is attributed to its microstructure and in-situ oxygen ingression. {yields} Doping TBC bond coat with Hf appears to have potential for enhancing the development of robust TBCs. - Abstract: The results of an experimental study of the high-temperature isothermal oxidation behavior and microstructural evolution in two variations of air plasma sprayed ceramic thermal barrier coatings (TBCs) are discussed in the paper. Two types of TBC specimens were produced for testing. These include a standard and vertically cracked APS. High temperature oxidation was carried out at 900, 1000, 1100 and 1200 deg. C. The experiments were performed in air under isothermal conditions. At each temperature, the specimens were exposed for 25, 50, 75 and 100 h. The corresponding microstructures and microchemistries of the TBC layers were examined using scanning electron microscopy and energy dispersive X-ray spectroscopy. Changes in the dimensions of the thermally grown oxide layer were determined as functions of time and temperature. The evolution of bond coat microstructures/interdiffusion zones and thermally grown oxide layers were compared in the TBC specimens with standard and vertically cracked microstructures.

  17. Beyond peak summer temperatures, branching corals in the Gulf of Aqaba are resilient to thermal stress but sensitive to high light

    Science.gov (United States)

    Bellworthy, Jessica; Fine, Maoz

    2017-12-01

    Despite rapidly rising sea surface temperatures and recurrent positive temperature anomalies, corals in the Gulf of Aqaba (GoA) rarely experience thermal bleaching. Elsewhere, mass coral bleaching has been observed in corals when the water temperature exceeds 1-2 °C above the local maximum monthly mean (MMM). This threshold value or "bleaching rule" has been used to create predictive models of bleaching from satellite sea surface temperature observations, namely the "degree heating week" index. This study aimed to characterize the physiological changes of dominant reef building corals from the GoA in response to a temperature and light stress gradient. Coral collection and experiments began after a period of 14 consecutive days above MMM in the field. Stylophora pistillata showed negligible changes in symbiont and host physiology parameters after accumulating up to 9.4 degree heating weeks during peak summer temperatures, for which the index predicts widespread bleaching and some mortality. This result demonstrates acute thermal tolerance in S. pistillata from the GoA and deviation from the bleaching rule. In a second experiment after 4 weeks at 4 °C above peak summer temperatures, S. pistillata and Acropora eurystoma in the high-light treatment visibly paled and suffered greater midday and afternoon photoinhibition compared to corals under low-light conditions (35% of high-light treatment). However, light, not temperature (alone or in synergy with light), was the dominant factor in causing paling and the effective quantum yield of corals at 4 °C above ambient was indistinguishable from those in the ambient control. This result highlights the exceptional, atypical thermal tolerance of dominant GoA branching corals. Concomitantly, it validates the efficacy of protecting GoA reefs from local stressors if they are to serve as a coral refuge in the face of global sea temperature rise.

  18. Thermal-permeability structure and recharge conditions of the Mutnovsky high-temperature geothermal field (Kamchatka, Russia)

    Science.gov (United States)

    Kiryukhin, A. V.; Polyakov, A. Y.; Usacheva, O. O.; Kiryukhin, P. A.

    2018-05-01

    The Mutnovsky geothermal area is part of the Eastern Kamchatka active volcano belt. Mutnovsky, 80 kY old and an aging strato-volcano (a complex of 4 composite volcanic cones), acts as a magma- and water-injector into the 25-km-long North Mutnovsky extension zone. Magmatic injection events (dykes) are associated with plane-oriented MEQ (Micro Earth Quakes) clusters, most of them occurring in the NE sector of the volcano (2 × 10 km2) at elevations from -4 to -2 km, while some magmatic injections occur at elevations from -6.0 to -4.0 km below the Mutnovsky production field. Water recharge of production reservoirs is from the Mutnovsky volcano crater glacier (+1500 to +1800 masl), which was confirmed by water isotopic data (δD, δ18O) of production wells at an earlier stage of development. The Mutnovsky (Dachny) 260-310 °C high-temperature production geothermal reservoir with a volume of 16 km3 is at the junction of NNE- and NE-striking normal faults, which coincides with the current dominant dyke injection orientation. TOUGH2-modeling estimates of the reservoir properties are as follows: the reservoir permeability is 90-600 e-15 m2, the deep upflow recharge is 80 kg/s and the enthalpy is 1420 kJ/kg. Modeling was used to reproduce the history of the Mutnovsky (Dachny) reservoir exploitation since 1983 with an effective power of 48 MWe by 2016. Modeling also showed that the reservoir is capable of yielding 65-83 MWe of sustainable production until 2055, if additional production drilling in the SE part of the field is performed. Moreover, this power value may increase to 87-105 MWe if binary technologies are applied. Modeling also shows that the predicted power is sensitive to local meteoric water influx during development. Conceptual iTOUGH2-EOS1sc thermal hydrodynamic modeling of the Mutnovsky magma-hydrothermal system as a whole reasonably explains its evolution over the last 1500-5000 years in terms of heat recharge (dyke injection from the Mutnovsky-4 funnel) and

  19. Multi-parametric study of temperature and thermal damage of tumor exposed to high-frequency nanosecond-pulsed electric fields based on finite element simulation.

    Science.gov (United States)

    Mi, Yan; Rui, Shaoqin; Li, Chengxiang; Yao, Chenguo; Xu, Jin; Bian, Changhao; Tang, Xuefeng

    2017-07-01

    High-frequency nanosecond-pulsed electric fields were recently introduced for tumor or abnormal tissue ablation to solve some problems of conventional electroporation. However, it is necessary to study the thermal effects of high-field-intensity nanosecond pulses inside tissues. The multi-parametric analysis performed here is based on a finite element model of liver tissue with a tumor that has been punctured by a pair of needle electrodes. The pulse voltage used in this study ranges from 1 to 4 kV, the pulse width ranges from 50 to 500 ns, and the repetition frequency is between 100 kHz and 1 MHz. The total pulse length is 100 μs, and the pulse burst repetition frequency is 1 Hz. Blood flow and metabolic heat generation have also been considered. Results indicate that the maximum instantaneous temperature at 100 µs can reach 49 °C, with a maximum instantaneous temperature at 1 s of 40 °C, and will not cause thermal damage during single pulse bursts. By parameter fitting, we can obtain maximum instantaneous temperature at 100 µs and 1 s for any parameter values. However, higher temperatures will be achieved and may cause thermal damage when multiple pulse bursts are applied. These results provide theoretical basis of pulse parameter selection for future experimental researches.

  20. Effect of thermal exposure, forming, and welding on high-temperature, dispersion-strengthened aluminum alloy: Al-8Fe-1V-2Si

    Science.gov (United States)

    Kennedy, J. R.; Gilman, P. S.; Zedalis, M. S.; Skinner, D. J.; Peltier, J. M.

    1991-01-01

    The feasibility of applying conventional hot forming and welding methods to high temperature aluminum alloy, Al-8Fe-1V-2Si (FVS812), for structural applications and the effect of thermal exposure on mechanical properties were determined. FVS812 (AA8009) sheet exhibited good hot forming and resistance welding characteristics. It was brake formed to 90 deg bends (0.5T bend radius) at temperatures greater than or equal to 390 C (730 F), indicating the feasibility of fabricating basic shapes, such as angles and zees. Hot forming of simple contoured-flanged parts was demonstrated. Resistance spot welds with good static and fatigue strength at room and elevated temperatures were readily produced. Extended vacuum degassing during billet fabrication reduced porosity in fusion and resistance welds. However, electron beam welding was not possible because of extreme degassing during welding, and gas-tungsten-arc welds were not acceptable because of severely degraded mechanical properties. The FVS812 alloy exhibited excellent high temperature strength stability after thermal exposures up to 315 C (600 F) for 1000 h. Extended billet degassing appeared to generally improve tensile ductility, fatigue strength, and notch toughness. But the effects of billet degassing and thermal exposure on properties need to be further clarified. The manufacture of zee-stiffened, riveted, and resistance-spot-welded compression panels was demonstrated.

  1. Thermal response to heat fluxes of the W7-AS divertor surface submitted to surface modification under high temperature treatment

    Energy Technology Data Exchange (ETDEWEB)

    Hildebrandt, D., E-mail: dieter.hildebrandt@ipp.mpg.d [Euratom Association, Max-Planck-Institut fuer Plasmaphysik, Teilinstitut Greifswald, Wendelsteinstrasse 1, 17491 Greifswald (Germany); Duebner, A. [Euratom Association, Max-Planck-Institut fuer Plasmaphysik, Teilinstitut Greifswald, Wendelsteinstrasse 1, 17491 Greifswald (Germany); Greuner, H.; Wiltner, A. [Teilinstitut Garching, Boltzmannstr. 2, 85748 Garching (Germany)

    2009-06-15

    Some target tiles of the W7-AS divertor has been investigated with respect to their thermal behaviour at the surface during power loading with well-defined heat fluxes in the Gladis facility. The primary aim was to examine uncertainties in the determination of heat fluxes derived from IR-thermography during operation of W7-AS. It is found that the derived heat flux profiles are strongly influenced by the local distribution of plasma-deposited contamination analyzed by AES and SIMS. With the observed actual surface conditions characterized by redeposited contamination equivalent up to about 1 mum thickness, the heat fluxes were partially overestimated up to a factor of 4 during operation of W7-AS. This uncertainty is observed to be significantly reduced after heat treatment at temperatures beyond 700 deg. C attained at power flux densities of 10.5 MW/m{sup 2} and durations longer than 5 s.

  2. An Electron Microscope Study of the Thermal Neutron Induced Loss in High Temperature Tensile Ductility of Nb Stabilized Austenitic Steels

    Energy Technology Data Exchange (ETDEWEB)

    Roy, R B

    1965-04-15

    Irradiated {approx}3 x 10{sup 19} n/cm{sup 2} (thermal), <3 x 10{sup 18} n/cm{sup 2} (> 1 MeV) at 40 deg C and the corresponding unirradiated control tensile specimens of a 20 % Cr, 25 % Ni, Nb stabilized steel tested at 650 deg C, 750 deg C and 800 deg C have been examined by transmission electron microscopy. The results indicate that the irradiation induced embrittlement of the tensile specimens at elevated temperatures is preceded by the formation of fine precipitates within the grains. These precipitates may restrict the deformation within the grains such that the stresses are concentrated at the grain boundaries thereby leading to premature failure. It is suggested that the main effect of the irradiation is to promote conditions necessary for the formation of these precipitates, namely, super saturation and fresh nucleation sites within the matrix through the energetic emission of He and Li atoms from boron as an impurity.

  3. Thermal response to heat fluxes of the W7-AS divertor surface submitted to surface modification under high temperature treatment

    International Nuclear Information System (INIS)

    Hildebrandt, D.; Duebner, A.; Greuner, H.; Wiltner, A.

    2009-01-01

    Some target tiles of the W7-AS divertor has been investigated with respect to their thermal behaviour at the surface during power loading with well-defined heat fluxes in the Gladis facility. The primary aim was to examine uncertainties in the determination of heat fluxes derived from IR-thermography during operation of W7-AS. It is found that the derived heat flux profiles are strongly influenced by the local distribution of plasma-deposited contamination analyzed by AES and SIMS. With the observed actual surface conditions characterized by redeposited contamination equivalent up to about 1 μm thickness, the heat fluxes were partially overestimated up to a factor of 4 during operation of W7-AS. This uncertainty is observed to be significantly reduced after heat treatment at temperatures beyond 700 deg. C attained at power flux densities of 10.5 MW/m 2 and durations longer than 5 s.

  4. An Electron Microscope Study of the Thermal Neutron Induced Loss in High Temperature Tensile Ductility of Nb Stabilized Austenitic Steels

    International Nuclear Information System (INIS)

    Roy, R.B.

    1965-04-01

    Irradiated ∼3 x 10 19 n/cm 2 (thermal), 18 n/cm 2 (> 1 MeV) at 40 deg C and the corresponding unirradiated control tensile specimens of a 20 % Cr, 25 % Ni, Nb stabilized steel tested at 650 deg C, 750 deg C and 800 deg C have been examined by transmission electron microscopy. The results indicate that the irradiation induced embrittlement of the tensile specimens at elevated temperatures is preceded by the formation of fine precipitates within the grains. These precipitates may restrict the deformation within the grains such that the stresses are concentrated at the grain boundaries thereby leading to premature failure. It is suggested that the main effect of the irradiation is to promote conditions necessary for the formation of these precipitates, namely, super saturation and fresh nucleation sites within the matrix through the energetic emission of He and Li atoms from boron as an impurity

  5. Thermal stability of a highly-deformed warm-rolled tungsten plate in the temperature range 1100 °C to 1250 °C

    DEFF Research Database (Denmark)

    Alfonso Lopez, Angel; Juul Jensen, Dorte; Luo, G.-N.

    2015-01-01

    plastic strain by 90% thickness reduction was investigated by isothermal annealing for up to 190 h in the temperature range between 1100 °C and 1250 °C. Vickers hardness testing allowed tracking the changes in mechanical properties caused by recovery and recrystallization. The hardness evolution could......Pure tungsten is considered as armor material for the most critical parts of fusion reactors (i.e. the divertor and the first wall), among other reasons due to its high melting point (3422 °C) and recrystallization temperature. The thermal stability of a pure tungsten plate warm-rolled to a high...... suggest that large plastic deformations (e.g. applied during shaping) are only suitable to produce tungsten components to be used at relatively low temperatures (up to 900 °C for a 2 years lifespan). Higher operation temperatures will lead to fast degradation of the microstructure during operation....

  6. Effects of thermal-hydraulic feedback on burnup modeling of the deep burn modular high temperature reactor (DB-MHR)

    International Nuclear Information System (INIS)

    Bei, Yea; Wen, Wua; Di, Yuna; Stubbins, J.F.; Venneri, F.

    2007-01-01

    The Deep-Burn concept investigates the use of commercial high temperature gas-cooled reactors such as modular helium reactors (DB-MHR) to transmute spent fuel from light water reactors (LWRs). An essential feature of this technology is the fabrication of spent fuel into TRISO particles with full transuranic composition to achieve very extensive destruction levels (deep-burn) in a one-pass fuel cycle. Due to the strong temperature influence on the cross sections of transuranics, the coupling between temperature and neutronics is very important to be able to simulate realistic operations of the deep burn reactor. In this study, detailed simulations of the DB-MHR operation are performed with a Monte Carlo code system (MCNP-5 + ORIGEN-2.2 + MONTEBURNS-2 for neutronics calculations), POKE code (General Atomics, for thermohydraulics calculations) and NJOY-99 code (for processing nuclear data libraries), called MHRBURNS. Resulting power densities of fuel blocks (from neutronics calculations) are provided as input to the POKE code, which in turn, calculates new temperature distributions. The temperature distributions obtained from POKE are used to update the MCNP input, and NJOY is called to process new nuclear cross sections based on appropriate temperatures. These steps are repeated to calculate the entire burnup performance of the system. In this preliminary study only the feedback on graphite temperature is taken into account. It is observed that the temperature feedback results show a 200 K higher temperature and thus a slight difference in 237 Np and 239 Pu destruction rates, although the overall burnup rates remain the same

  7. Thermal response of core and central-cavity components of a high-temperature gas-cooled reactor in the absence of forced convection coolant flow

    International Nuclear Information System (INIS)

    Whaley, R.L.; Sanders, J.P.

    1976-09-01

    A means of determining the thermal responses of the core and the components of a high-temperature gas-cooled reactor after loss of forced coolant flow is discussed. A computer program, using a finite-difference technique, is presented together with a solution of the confined natural convection. The results obtained are reasonable and demonstrate that the computer program adequately represents the confined natural convection

  8. Heat and Mass Transfer in a High-Porous Low-Temperature Thermal Insulation in Real Operating Conditions

    Directory of Open Access Journals (Sweden)

    Polovnikov Vyacheslav Yu.

    2015-01-01

    Full Text Available The results of numerical simulation of heat and mass transfer in a high-porous low-temperature insulation in conditions of insulation freezing, a moisture migration to the front of phase transition and a condensation forming on an outer contour of interaction were obtained. Values of heat leakage were established.

  9. Thermal conductivity at very low temperature

    Energy Technology Data Exchange (ETDEWEB)

    Locatelli, M [CEA Centre d' Etudes Nucleaires de Grenoble, 38 (France). Service des Basses Temperatures

    1976-06-01

    The interest of low and very low temperatures in solid physics and especially that of thermal measurements is briefly mentioned. Some notes on the thermal conductivity of dielectrics, the method and apparatus used to measure this property at very low temperatures (T<1.5K) and some recent results of fundamental and applied research are then presented.

  10. RANS simulation of the thermal mixing in HTTF LP during normal operation conditions – High Temperature Test Facility at Oregon State University

    International Nuclear Information System (INIS)

    Gradecka, Malwina J.; Woods, Brian

    2014-01-01

    Since High Temperature Gas-cooled Reactors are being considered as the most promising design of upcoming IV Gen reactors, key research areas were identified to address safety aspects of this design. A number of simulations and experiments need to be conducted in this field. In this paper, thermal-hydraulics aspects of coolant flow through Lower Plenum (LP) of HTGR were considered, specifically flow characteristics to identify the risk of temperature stratification in LP and hot spotting on LP floor. Local temperature gradients can cause material degradation. As the power profile is non-uniform across the core, jets of coolant exit the core region at different temperatures and enter the LP impinging on LP floor causing hot spots at LP structure and temperature stratification. To address those issues numerical simulation and an experiment are being developed. The numerical simulation provides coolant flow velocity and temperature fields. The purpose of this study is to investigate the mixing phenomenon in the LP due to risk of the hot streaking and thermal stratification phenomena during normal operation of HTTF. The following aspect are being examined: identification of gas flow behavior in lower plenum of HTTF based on CFD simulations, identification of hot streaking issue in the HTTF lower plenum using CFD tools, and computational investigation of gas mixing efficiency. This paper includes a description of experimental setup of HTTF, guidance for LP CFD modeling, and the results and analysis of CFD simulation. (author)

  11. High temperature materials

    International Nuclear Information System (INIS)

    2003-01-01

    The aim of this workshop is to share the needs of high temperature and nuclear fuel materials for future nuclear systems, to take stock of the status of researches in this domain and to propose some cooperation works between the different research organisations. The future nuclear systems are the very high temperature (850 to 1200 deg. C) gas cooled reactors (GCR) and the molten salt reactors (MSR). These systems include not only the reactor but also the fabrication and reprocessing of the spent fuel. This document brings together the transparencies of 13 communications among the 25 given at the workshop: 1) characteristics and needs of future systems: specifications, materials and fuel needs for fast spectrum GCR and very high temperature GCR; 2) high temperature materials out of neutron flux: thermal barriers: materials, resistance, lifetimes; nickel-base metal alloys: status of knowledge, mechanical behaviour, possible applications; corrosion linked with the gas coolant: knowledge and problems to be solved; super-alloys for turbines: alloys for blades and discs; corrosion linked with MSR: knowledge and problems to be solved; 3) materials for reactor core structure: nuclear graphite and carbon; fuel assembly structure materials of the GCR with fast neutron spectrum: status of knowledge and ceramics and cermets needs; silicon carbide as fuel confinement material, study of irradiation induced defects; migration of fission products, I and Cs in SiC; 4) materials for hydrogen production: status of the knowledge and needs for the thermochemical cycle; 5) technologies: GCR components and the associated material needs: compact exchangers, pumps, turbines; MSR components: valves, exchangers, pumps. (J.S.)

  12. Plutonium and Minor Actinide Management in Thermal High-Temperature Gas-Cooled Reactors. Publishable Final Activity Report

    International Nuclear Information System (INIS)

    Kuijper, J.C.; Somers, J.; Van Den Durpel, L.

    2013-01-01

    The PUMA project - the acronym stands for “Plutonium and Minor Actinide Management in Thermal High-Temperature Gas-Cooled Reactors” - was a Specific Targeted Research Project (STREP) within the Euratom 6th Framework (EU FP6). The PUMA project ran from September 1, 2006, until August 31, 2009, and was executed by a consortium of 14 European partner organisations and one from the USA. This report serves 2 purposes. It is both the 'Publishable Final Activity Report' and the 'Final (Summary) Report', describing, per Work Package, the specific objectives, research activities, main conclusions, recommendations and supporting documents. PUMA's main objective was to investigate the possibilities for the utilisation and transmutation of plutonium and especially minor actinides in contemporary and future (high temperature) gas-cooled reactor designs, which are promising tools for improving the sustainability of the nuclear fuel cycle. This contributes to the reduction of Pu and MA stockpiles, and also to the development of safe and sustainable reactors for CO2-free energy generation. The PUMA project has assessed the impact of the introduction of Pu/MA-burning HTRs at three levels: fuel and fuel performance (modelling), reactor (transmutation performance and safety) and reactor/fuel cycle facility park. Earlier projects already indicated favourable characteristics of HTRs with respect to Pu burning. So, core physics of Pu/MA fuel cycles for HTRs has been investigated to study the CP fuel and reactor characteristics and to assure nuclear stability of a Pu/MA HTR core, under both normal and abnormal operating conditions. The starting point of this investigation comprised the two main contemporary HTR designs, viz. the pebble-bed type HTR, represented by the South-African PBMR, and hexagonal block type HTR, represented by the GT-MHR. The results (once again) demonstrate the flexibility of the contemporary (and near future) HTR designs and their ability to accept a variety

  13. Plutonium and Minor Actinide Management in Thermal High-Temperature Gas-Cooled Reactors. Publishable Final Activity Report

    International Nuclear Information System (INIS)

    Kuijper, J.C.; Somers, J.; Van Den Durpel, L.; Chauvet, V.; Cerullo, N.; Cetnar, J.; Abram, T.; Bakker, K.; Bomboni, E.; Bernnat, W.; Domanska, J.G.; Girardi, E.; De Haas, J.B.M.; Hesketh, K.; Hiernaut, J.P.; Hossain, K.; Jonnet, J.; Kim, Y.; Kloosterman, J.L.; Kopec, M.; Murgatroyd, J.; Millington, D.; Lecarpentier, D.; Lomonaco, G.; McEachern, D.; Meier, A.; Mignanelli, M.; Nabielek, H.; Oppe, J.; Petrov, B.Y.; Pohl, C.; Ruetten, H.J.; Schihab, S.; Toury, G.; Trakas, C.; Venneri, F.; Verfondern, K.; Werner, H.; Wiss, T.; Zakova, J.

    2010-11-01

    The PUMA project -the acronym stands for 'Plutonium and Minor Actinide Management in Thermal High-Temperature Gas-Cooled Reactors'- was a Specific Targeted Research Project (STREP) within the EURATOM 6th Framework Program (EU FP6). The PUMA project ran from September 1, 2006, until August 31, 2009, and was executed by a consortium of 14 European partner organisations and one from the USA. This report serves 2 purposes. It is both the 'Publishable Final Activity Report' and the 'Final (Summary) Report', describing, per Work Package, the specific objectives, research activities, main conclusions, recommendations and supporting documents. PUMA's main objective was to investigate the possibilities for the utilisation and transmutation of plutonium and especially minor actinides in contemporary and future (high temperature) gas-cooled reactor designs, which are promising tools for improving the sustainability of the nuclear fuel cycle. This contributes to the reduction of Pu and MA stockpiles, and also to the development of safe and sustainable reactors for CO 2 -free energy generation. The PUMA project has assessed the impact of the introduction of Pu/MA-burning HTRs at three levels: fuel and fuel performance (modelling), reactor (transmutation performance and safety) and reactor/fuel cycle facility park. Earlier projects already indicated favourable characteristics of HTRs with respect to Pu burning. So, core physics of Pu/MA fuel cycles for HTRs has been investigated to study the CP fuel and reactor characteristics and to assure nuclear stability of a Pu/MA HTR core, under both normal and abnormal operating conditions. The starting point of this investigation comprised the two main contemporary HTR designs, viz. the pebble-bed type HTR, represented by the South-African PBMR, and hexagonal block type HTR, represented by the GT-MHR. The results (once again) demonstrate the flexibility of the contemporary (and near future) HTR designs and their ability to accept a

  14. Plutonium and Minor Actinide Management in Thermal High-Temperature Gas-Cooled Reactors. Publishable Final Activity Report

    Energy Technology Data Exchange (ETDEWEB)

    Kuijper, J.C., E-mail: kuijper@nrg.eu [Nuclear Research and Consultancy Group (NRG), Petten (Netherlands); Somers, J; Van Den Durpel, L; Chauvet, V; Cerullo, N; Cetnar, J; Abram, T; Bakker, K; Bomboni, E; Bernnat, W; Domanska, J G; Girardi, E; De Haas, J B.M.; Hesketh, K; Hiernaut, J P; Hossain, K; Jonnet, J; Kim, Y; Kloosterman, J L; Kopec, M; Murgatroyd, J; Millington, D; Lecarpentier, D; Lomonaco, G; McEachern, D; Meier, A; Mignanelli, M; Nabielek, H; Oppe, J; Petrov, B Y; Pohl, C; Ruetten, H J; Schihab, S; Toury, G; Trakas, C; Venneri, F; Verfondern, K; Werner, H; Wiss, T; Zakova, J

    2010-11-15

    The PUMA project -the acronym stands for 'Plutonium and Minor Actinide Management in Thermal High-Temperature Gas-Cooled Reactors'- was a Specific Targeted Research Project (STREP) within the EURATOM 6th Framework Program (EU FP6). The PUMA project ran from September 1, 2006, until August 31, 2009, and was executed by a consortium of 14 European partner organisations and one from the USA. This report serves 2 purposes. It is both the 'Publishable Final Activity Report' and the 'Final (Summary) Report', describing, per Work Package, the specific objectives, research activities, main conclusions, recommendations and supporting documents. PUMA's main objective was to investigate the possibilities for the utilisation and transmutation of plutonium and especially minor actinides in contemporary and future (high temperature) gas-cooled reactor designs, which are promising tools for improving the sustainability of the nuclear fuel cycle. This contributes to the reduction of Pu and MA stockpiles, and also to the development of safe and sustainable reactors for CO{sub 2}-free energy generation. The PUMA project has assessed the impact of the introduction of Pu/MA-burning HTRs at three levels: fuel and fuel performance (modelling), reactor (transmutation performance and safety) and reactor/fuel cycle facility park. Earlier projects already indicated favourable characteristics of HTRs with respect to Pu burning. So, core physics of Pu/MA fuel cycles for HTRs has been investigated to study the CP fuel and reactor characteristics and to assure nuclear stability of a Pu/MA HTR core, under both normal and abnormal operating conditions. The starting point of this investigation comprised the two main contemporary HTR designs, viz. the pebble-bed type HTR, represented by the South-African PBMR, and hexagonal block type HTR, represented by the GT-MHR. The results (once again) demonstrate the flexibility of the contemporary (and near future) HTR designs and their ability to accept a

  15. Plutonium and Minor Actinide Management in Thermal High-Temperature Gas-Cooled Reactors. Publishable Final Activity Report

    Energy Technology Data Exchange (ETDEWEB)

    Kuijper, J.C., E-mail: kuijper@nrg.eu [Nuclear Research and Consultancy Group (NRG), Petten (Netherlands); Somers, J.; Van Den Durpel, L.; Chauvet, V.; Cerullo, N.; Cetnar, J.; Abram, T.; Bakker, K.; Bomboni, E.; Bernnat, W.; Domanska, J.G.; Girardi, E.; De Haas, J.B.M.; Hesketh, K.; Hiernaut, J.P.; Hossain, K.; Jonnet, J.; Kim, Y.; Kloosterman, J.L.; Kopec, M.; Murgatroyd, J.; Millington, D.; Lecarpentier, D.; Lomonaco, G.; McEachern, D.; Meier, A.; Mignanelli, M.; Nabielek, H.; Oppe, J.; Petrov, B.Y.; Pohl, C.; Ruetten, H.J.; Schihab, S.; Toury, G.; Trakas, C.; Venneri, F.; Verfondern, K.; Werner, H.; Wiss, T.; Zakova, J.

    2010-11-15

    The PUMA project -the acronym stands for 'Plutonium and Minor Actinide Management in Thermal High-Temperature Gas-Cooled Reactors'- was a Specific Targeted Research Project (STREP) within the EURATOM 6th Framework Program (EU FP6). The PUMA project ran from September 1, 2006, until August 31, 2009, and was executed by a consortium of 14 European partner organisations and one from the USA. This report serves 2 purposes. It is both the 'Publishable Final Activity Report' and the 'Final (Summary) Report', describing, per Work Package, the specific objectives, research activities, main conclusions, recommendations and supporting documents. PUMA's main objective was to investigate the possibilities for the utilisation and transmutation of plutonium and especially minor actinides in contemporary and future (high temperature) gas-cooled reactor designs, which are promising tools for improving the sustainability of the nuclear fuel cycle. This contributes to the reduction of Pu and MA stockpiles, and also to the development of safe and sustainable reactors for CO{sub 2}-free energy generation. The PUMA project has assessed the impact of the introduction of Pu/MA-burning HTRs at three levels: fuel and fuel performance (modelling), reactor (transmutation performance and safety) and reactor/fuel cycle facility park. Earlier projects already indicated favourable characteristics of HTRs with respect to Pu burning. So, core physics of Pu/MA fuel cycles for HTRs has been investigated to study the CP fuel and reactor characteristics and to assure nuclear stability of a Pu/MA HTR core, under both normal and abnormal operating conditions. The starting point of this investigation comprised the two main contemporary HTR designs, viz. the pebble-bed type HTR, represented by the South-African PBMR, and hexagonal block type HTR, represented by the GT-MHR. The results (once again) demonstrate the flexibility of the contemporary (and near future) HTR

  16. From a Single-Band Metal to a High-Temperature Superconductor via Two Thermal Phase Transitions

    Energy Technology Data Exchange (ETDEWEB)

    He, R.-H.; Hashimoto, M.; Karapetyan, H.; Koralek, J.D.; Hinton, J.P.; Testaud, J.P.; Nathan, V.; Yoshida, Y.; Yao, H.; Tanaka, K.; Meevasana, W.; Moore, R.G.; Lu, D.H.; Mo, S.-K.; Ishikado, M.; Eisaki, H.; Hussain, Z.; Devereaux, T.P.; Kivelson, S.A.; Orenstein, J.; Kapitulnik, A.

    2011-11-08

    The nature of the pseudogap phase of cuprate high-temperature superconductors is one of the most important unsolved problems in condensed matter physics. We studied the commencement of the pseudogap state at temperature T* using three different techniques (angle-resolved photoemission spectroscopy, polar Kerr effect, and time-resolved reflectivity) on the same optimally-doped Bi2201 crystals. We observe the coincident onset at T* of a particle-hole asymmetric antinodal gap, a non-zero Kerr rotation, and a change in the relaxational dynamics, consistent with a phase transition. Upon further cooling, spectroscopic signatures of superconductivity begin to grow close to the superconducting transition temperature (T{sub c}), entangled in an energy-momentum dependent fashion with the pre-existing pseudogap features.

  17. Validation of a CATHENA fuel channel model for the post blowdown analysis of the high temperature thermal-chemical experiment CS28-1, I - Steady state

    International Nuclear Information System (INIS)

    Rhee, Bo Wook; Kim, Hyoung Tae; Park, Joo Hwan

    2008-01-01

    To form a licensing basis for the new methodology of the fuel channel safety analysis code system for CANDU-6, a CATHENA model for the post-blowdown fuel channel analysis for a Large Break LOCA has been developed, and tested for the steady state of a high temperature thermal-chemical experiment CS28-1. As the major concerns of the post-blowdown fuel channel analysis of the current CANDU-6 design are how much of the decay heat can be discharged to the moderator via a radiation and a convective heat transfer at the expected accident conditions, and how much zirconium sheath would be oxidized to generate H 2 at how high a fuel temperature, this study has focused on understanding these phenomena, their interrelations, and a way to maintain a good accuracy in the prediction of the fuel and the pressure tube temperatures without losing the important physics of the involved phenomena throughout the post-blowdown phase of a LBLOCA. For a better prediction, those factors that may significantly contribute to the prediction accuracy of the steady state of the test bundles were sought. The result shows that once the pressure tube temperature is predicted correctly by the CATHENA heat transfer model between the pressure tube and the calandria tube through a gap thermal resistance adjustment, all the remaining temperatures of the inner ring, middle ring and outer ring FES temperatures can be predicted quite satisfactorily, say to within an accuracy range of 20-25 deg. C, which is comparable to the reported accuracy of the temperature measurement, ±2%. Also the analysis shows the choice of the emissivity of the solid structures (typically, 0.80, 0.34, 0.34 for FES, PT, CT), and the thermal resistance across the CO 2 annulus are factors that significantly affect the steady state prediction accuracy. A question on the legitimacy of using 'transparent' assumption for the CO 2 gas annulus for the radiation heat transfer between the pressure tube and the calandria tube in CATHENA

  18. Thermal conductivity of high purity vanadium

    International Nuclear Information System (INIS)

    Jung, W.D.

    1975-01-01

    The thermal conductivity, Seebeck coefficient, and electrical resistivity of four high-purity vanadium samples were measured over the temperature range 5 to 300 0 K. The highest purity sample had a resistance ratio (rho 273 /rho 4 . 2 ) of 1524. The highest purity sample had a thermal conductivity maximum of 920 W/mK at 9 0 K and had a thermal conductivity of 35 W/mK at room temperature. At low temperatures, the thermal resistivity was limited by the scattering of electrons by impurities and phonons. The thermal resistivity of vanadium departed from Matthiessen's rule at low temperatures. The electrical resistivity and Seebeck coefficient of high purity vanadium showed no anomalous behavior above 130 0 K. The intrinsic electrical resistivity at low temperatures was due primarily to interband scattering of electrons. The Seebeck coefficient was positive from 10 to 240 0 K and had a maximum which was dependent upon sample purity

  19. Density, thermal expansion coefficient and viscosity of sodium tetraborate (borax)-UO2 and of sodium metaborate-UO2 solutions at high temperatures

    International Nuclear Information System (INIS)

    Dalle Donne, M.; Dorner, S.; Roth, A.

    1983-01-01

    Measurements have been performed of the density, of the volumetric thermal expansion coefficient and of the viscosity of liquid sodium tetraborate (borax) and of sodium metaborate both pure and with two different amounts of UO 2 dissolved in each. The viscosity measurements have been performed for the solution of sodium tetraborate with UO 2 and CeO 2 , and with CeO 2 only as well. These data are required for the design of core-catchers based on sodium borates. The density measurements have been performed with the buoyancy method in the temperature range from 825 0 C to 1300 0 C, the viscosity measurements in the temperature range 700-1250 0 C with a modified Haake viscosity balance. The balance was previously calibrated at ambient temperature with a standard calibration liquid and at high temperatures, with data for pure borax available from the literature. (orig.)

  20. High thermal load receiving heat plate

    International Nuclear Information System (INIS)

    Shibutani, Jun-ichi; Shibayama, Kazuhito; Yamamoto, Keiichi; Uchida, Takaho.

    1993-01-01

    The present invention concerns a high thermal load heat receiving plate such as a divertor plate of a thermonuclear device. The high thermal load heat receiving plate of the present invention has a cooling performance capable of suppressing the temperature of an armour tile to less than a threshold value of the material against high thermal loads applied from plasmas. Spiral polygonal pipes are inserted in cooling pipes at a portion receiving high thermal loads in the high temperature load heat receiving plate of the present invention. Both ends of the polygonal pipes are sealed by lids. An area of the flow channel in the cooling pipes is thus reduced. Heat conductivity on the cooling surface of the cooling pipes is increased in the high thermal load heat receiving plate having such a structure. Accordingly, temperature elevation of the armour tile can be suppressed. (I.S.)

  1. Solvothermal method as a green chemistry solution for micro-encapsulation of phase change materials for high temperature thermal energy storage

    Directory of Open Access Journals (Sweden)

    Tudor Albert Ioan

    2018-01-01

    Full Text Available Thermal energy storage systems using phase change materials (PCMs as latent heat storage are one of the main challenges at European level in improving the performances and efficiency of concentrated solar power energy generation due to their high energy density. PCM with high working temperatures in the temperature range 300–500 °C are required for these purposes. However their use is still limited due to the problems raised by the corrosion of the majority of high temperature PCMs and lower thermal transfer properties. Micro-encapsulation was proposed as one method to overcome these problems. Different micro-encapsulation methods proposed in the literature are presented and discussed. An original process for the micro-encapsulation of potassium nitrate as PCM in inorganic zinc oxide shells based on a solvothermal method followed by spray drying to produce microcapsules with controlled phase composition and distribution is proposed and their transformation temperatures and enthalpies measured by differential scanning calorimetry are presented.

  2. A computational study of syngas auto-ignition characteristics at high-pressure and low-temperature conditions with thermal inhomogeneities

    KAUST Repository

    Pal, Pinaki

    2015-07-30

    A computational study was conducted to investigate the characteristics of auto-ignition in a syngas mixture at high-pressure and low-temperature conditions in the presence of thermal inhomogeneities. Highly resolved one-dimensional numerical simulations incorporating detailed chemistry and transport were performed. The temperature inhomogeneities were represented by a global sinusoidal temperature profile and a local Gaussian temperature spike (hot spot). Reaction front speed and front Damköhler number analyses were employed to characterise the propagating ignition front. In the presence of a global temperature gradient, the ignition behaviour shifted from spontaneous propagation (strong) to deflagrative (weak), as the initial mean temperature of the reactant mixture was lowered. A predictive Zel\\'dovich–Sankaran criterion to determine the transition from strong to weak ignition was validated for different parametric sets. At sufficiently low temperatures, the strong ignition regime was recovered due to faster passive scalar dissipation of the imposed thermal fluctuations relative to the reaction timescale, which was quantified by the mixing Damköhler number. In the presence of local hot spots, only deflagrative fronts were observed. However, the fraction of the reactant mixture consumed by the propagating front was found to increase as the initial mean temperature was lowered, thereby leading to more enhanced compression-heating of the end-gas. Passive scalar mixing was not found to be important for the hot spot cases considered. The parametric study confirmed that the relative magnitude of the Sankaran number translates accurately to the quantitative strength of the deflagration front in the overall ignition advancement. © 2015 Taylor & Francis

  3. A computational study of syngas auto-ignition characteristics at high-pressure and low-temperature conditions with thermal inhomogeneities

    Science.gov (United States)

    Pal, Pinaki; Mansfield, Andrew B.; Arias, Paul G.; Wooldridge, Margaret S.; Im, Hong G.

    2015-09-01

    A computational study was conducted to investigate the characteristics of auto-ignition in a syngas mixture at high-pressure and low-temperature conditions in the presence of thermal inhomogeneities. Highly resolved one-dimensional numerical simulations incorporating detailed chemistry and transport were performed. The temperature inhomogeneities were represented by a global sinusoidal temperature profile and a local Gaussian temperature spike (hot spot). Reaction front speed and front Damköhler number analyses were employed to characterise the propagating ignition front. In the presence of a global temperature gradient, the ignition behaviour shifted from spontaneous propagation (strong) to deflagrative (weak), as the initial mean temperature of the reactant mixture was lowered. A predictive Zel'dovich-Sankaran criterion to determine the transition from strong to weak ignition was validated for different parametric sets. At sufficiently low temperatures, the strong ignition regime was recovered due to faster passive scalar dissipation of the imposed thermal fluctuations relative to the reaction timescale, which was quantified by the mixing Damköhler number. In the presence of local hot spots, only deflagrative fronts were observed. However, the fraction of the reactant mixture consumed by the propagating front was found to increase as the initial mean temperature was lowered, thereby leading to more enhanced compression-heating of the end-gas. Passive scalar mixing was not found to be important for the hot spot cases considered. The parametric study confirmed that the relative magnitude of the Sankaran number translates accurately to the quantitative strength of the deflagration front in the overall ignition advancement.

  4. Literature review of thermal and radiation performance parameters for high-temperature, uranium dioxide fueled cermet materials

    International Nuclear Information System (INIS)

    Haertling, C.; Hanrahan, R.J.

    2007-01-01

    High-temperature fissile-fueled cermet literature was reviewed. Data are presented primarily for the W-UO 2 as this was the system most frequently studied; other reviewed systems include cermets with Mo, Re, or alloys as a matrix. Failure mechanisms for the cermets are typically degradation of mechanical integrity and loss of fuel. Mechanical failure can occur through stresses produced from dissimilar expansion coefficients, voids created from diffusion of dissimilar materials or formation of metal hydride and subsequent volume expansion. Fuel loss failure can occur by high temperature surface vaporization or by vaporization after loss of mechanical integrity. Techniques found to aid in retaining fuel include the use of coatings around UO 2 fuel particles, use of oxide stabilizers in the UO 2 , minimizing grain sizes in the metal matrix, minimizing impurities, controlling the cermet sintering atmosphere, and cladding around the cermet

  5. Zirconium-cerin solid solutions: thermodynamic model and thermal stability at high temperature; Solutions solides de zirconium dans la cerine: modele thermodynamique et stabilite thermique a haute temperature

    Energy Technology Data Exchange (ETDEWEB)

    Janvier, C.

    1998-04-02

    The oxides-gaseous dioxygen equilibria and the textural thermal stability of six zirconium-cerin solutions Ce{sub 1-x}Zr{sub x}O{sub 2} (0thermal gravimetric analysis at 600 degrees Celsius has shown that these solutions have not a ideal behaviour. A thermodynamic model where the point defects of solutions are included describe them the best. It becomes then possible to know the variations of the concentrations of the point defects in terms of temperature, oxygen pressure and zirconium concentration. A kinetic study (by calcination at 950 degrees Celsius of the solid solutions) of the specific surface area decrease has revealed a minima (0

  6. Core/Shell Structure of TiO2-Coated MWCNTs for Thermal Protection for High-Temperature Processing of Metal Matrix Composites

    Directory of Open Access Journals (Sweden)

    Laura Angélica Ardila Rodriguez

    2018-01-01

    Full Text Available The production of metal matrix composites with elevated mechanical properties depends largely on the reinforcing phase properties. Due to the poor oxidation resistance of multiwalled carbon nanotubes (MWCNTs as well as their high reactivity with molten metal, the processing conditions for the production of MWCNT-reinforced metal matrix composites may be an obstacle to their successful use as reinforcement. Coating MWCNTs with a ceramic material that acts as a thermal protection would be an alternative to improve oxidation stability. In this work, MWCNTs previously functionalized were coated with titanium dioxide (TiO2 layers of different thicknesses, producing a core-shell structure. Heat treatments at three different temperatures (500°C, 750°C, and 1000°C were performed on coated nanotubes in order to form a stable metal oxide structure. The MWCNT/TiO2 hybrids produced were evaluated in terms of thermal stability. Thermogravimetric analysis (TGA, X-ray diffraction (XRD, scanning electron microscopy (SEM, Fourier transform infrared spectroscopy (FTIR, Raman spectroscopy (RS, and X-ray photoelectron spectroscopy (XPS were performed in order to investigate TiO2-coated MWCNT structure and thermal stability under oxidative atmosphere. It was found that the thermal stability of the TiO2-coated MWCNTs was dependent of the TiO2 layer morphology that in turn depends on the heat treatment temperature.

  7. Non-linear thermal evolution of the crystal structure and phase transitions of LaFeO3 investigated by high temperature X-ray diffraction

    International Nuclear Information System (INIS)

    Selbach, Sverre M.; Tolchard, Julian R.; Fossdal, Anita; Grande, Tor

    2012-01-01

    The crystal structure, anisotropic thermal expansion and structural phase transition of the perovskite LaFeO 3 has been studied by high-temperature X-ray diffraction from room temperature to 1533 K. The structural evolution of the orthorhombic phase with space group Pbnm and the rhombohedral phase with R3 ¯ c structure of LaFeO 3 is reported in terms of lattice parameters, thermal expansion coefficients, atomic positions, octahedral rotations and polyhedral volumes. Non-linear lattice expansion across the antiferromagnetic to paramagnetic transition of LaFeO 3 at T N =735 K was compared to the corresponding behavior of the ferroelectric antiferromagnet BiFeO 3 to gain insight to the magnetoelectric coupling in BiFeO 3 , which is also multiferroic. The first order phase transition of LaFeO 3 from Pbnm to R3 ¯ c was observed at 1228±9 K, and a subsequent transition to Pm3 ¯ m was extrapolated to occur at 2140±30 K. The stability of the Pbnm and R3 ¯ c polymorphs of LaFeO 3 is discussed in terms of the competing enthalpy and entropy of the two crystal polymorphs and the thermal evolution of the polyhedral volume ratio V A /V B . - Graphical abstract: Aniostropic thermal evolution of the lattice parameters and phase transition of LaFeO 3 . Highlights: ► The crystal structure of LaFeO 3 is studied by HTXRD from RT to 1533 K. ► A non-linear expansion across the Néel temperature is observed for LaFeO 3 . ► The ratio V A /V B is used to rationalize the thermal evolution of the structure.

  8. Role of Oxides and Porosity on High-Temperature Oxidation of Liquid-Fueled HVOF Thermal-Sprayed Ni50Cr Coatings

    Science.gov (United States)

    Song, B.; Bai, M.; Voisey, K. T.; Hussain, T.

    2017-02-01

    High chromium content in Ni50Cr thermally sprayed coatings can generate a dense and protective scale at the surface of coating. Thus, the Ni50Cr coating is widely used in high-temperature oxidation and corrosion applications. A commercially available gas atomized Ni50Cr powder was sprayed onto a power plant steel (ASME P92) using a liquid-fueled high velocity oxy-fuel thermal spray with three processing parameters in this study. Microstructure of as-sprayed coatings was examined using oxygen content analysis, mercury intrusion porosimetry, scanning electron microscope (SEM), energy-dispersive x-ray spectroscopy (EDX) and x-ray diffraction (XRD). Short-term air oxidation tests (4 h) of freestanding coatings (without boiler steel substrate) in a thermogravimetric analyzer at 700 °C were performed to obtain the kinetics of oxidation of the as-sprayed coating. Long-term air oxidation tests (100 h) of the coated substrates were performed at same temperature to obtain the oxidation products for further characterization in detail using SEM/EDX and XRD. In all samples, oxides of various morphologies developed on top of the Ni50Cr coatings. Cr2O3 was the main oxidation product on the surface of all three coatings. The coating with medium porosity and medium oxygen content has the best high-temperature oxidation performance in this study.

  9. Green chemistry solutions for sol–gel micro-encapsulation of phase change materials for high-temperature thermal energy storage

    Directory of Open Access Journals (Sweden)

    Romero-Sanchez Maria Dolores

    2018-01-01

    Full Text Available NaNO3 has been selected as phase change material (PCM due to its convenient melting and crystallization temperatures for thermal energy storage (TES in solar plants or recovering of waste heat in industrial processes. However, incorporation of PCMs and NaNO3 in particular requires its protection (i.e. encapsulation into containers or support materials to avoid incompatibility or chemical reaction with the media where incorporated (i.e. corrosion in metal storage tanks. As a novelty, in this study, microencapsulation of an inorganic salt has been carried out also using an inorganic compound (SiO2 instead of the conventional polymeric shells used for organic microencapsulations and not suitable for high temperature applications (i.e. 300–500 °C. Thus, NaNO3 has been microencapsulated by sol–gel technology using SiO2 as shell material. Feasibility of the microparticles synthetized has been demonstrated by different experimental techniques in terms of TES capacity and thermal stability as well as durability through thermal cycles. The effectiveness of microencapsulated NaNO3 as TES material depends on the core:shell ratio used for the synthesis and on the maximum temperature supported by NaNO3 during use.

  10. Characterizing the Diurnal Cycle of Land Surface Temperature and Evapotranspiration at High Spatial Resolution Using Thermal Observations from sUAS.

    Science.gov (United States)

    Dutta, D.; Drewry, D.; Johnson, W. R.

    2017-12-01

    The surface temperature of plant canopies is an important indicator of the stomatal regulation of plant water use and the associated water flux from plants to atmosphere (evapotranspiration (ET)). Remotely sensed thermal observations using compact, low-cost, lightweight sensors from small unmanned aerial systems (sUAS) have the potential to provide surface temperature (ST) and ET estimates at unprecedented spatial and temporal resolutions, allowing us to characterize the intra-field diurnal variations in canopy ST and ET for a variety of vegetation systems. However, major challenges exist for obtaining accurate surface temperature estimates from low-cost uncooled microbolometer-type sensors. Here we describe the development of calibration methods using thermal chamber experiments, taking into account the ambient optics and sensor temperatures, and applying simple models of spatial non-uniformity correction to the sensor focal-plane-array. We present a framework that can be used to derive accurate surface temperatures using radiometric observations from low-cost sensors, and demonstrate this framework using a sUAS-mounted sensor across a diverse set of calibration and vegetation targets. Further, we demonstrate the use of the Surface Temperature Initiated Closure (STIC) model for computing spatially explicit, high spatial resolution ET estimates across several well-monitored agricultural systems, as driven by sUAS acquired surface temperatures. STIC provides a physically-based surface energy balance framework for the simultaneous retrieval of the surface and atmospheric vapor conductances and surface energy fluxes, by physically integrating radiometric surface temperature information into the Penman-Monteith equation. Results of our analysis over agricultural systems in Ames, IA and Davis, CA demonstrate the power of this approach for quantifying the intra-field spatial variability in the diurnal cycle of plant water use at sub-meter resolutions.

  11. Preparation and encapsulation performance of Al_2O_3-SiO_2-B_2O_3 glass-ceramic for high temperature thermal storage

    International Nuclear Information System (INIS)

    Li, Ruguang; Zhu, Jiaoqun; Zhou, Weibing; Cheng, Xiaomin; Liu, Fengli

    2017-01-01

    Highlights: • Al_2O_3-B_2O_3-SiO_2 has good chemical durability, corrosion resistance and dense structure. • The material rarely used in high temperature thermal storage. • The material was prepared and characterized in the paper. - Abstract: In this paper, Al_2O_3-SiO_2-B_2O_3 glass-ceramic was prepared and characterized by X-ray diffraction (XRD) and scanning electron microscopy (SEM), further, the porosity was detected by Archimedes principle, thermo physical properties were investigated by differential scanning calorimeter (DSC), respectively. The phase composition was detected by XRD, and the morphology was observed by SEM. The results indicated that the thermal conductivities of the Al_2O_3-SiO_2-B_2O_3 glass-ceramic were between 1.3 and 1.5 W·(m·K)"−"1, and the material had good thermal stability in the range of 300–900 °C. The porosity and apparent density were increased with the temperature. The porosity of Al_2O_3-SiO_2-B_2O_3 glass-ceramic in ranging from 1.2 to 9.6%, the apparent density were between 2.12 and 2.67 g·cm"−"3, and heat capacities were between 0.64 and 0.79 kJ/(kg·K). All the results indicated that the Al_2O_3-SiO_2-B_2O_3 glass-ceramic can be applied as encapsulation material in high temperature latent thermal energy storage.

  12. Effects of a Mixed Zone on TGO Displacement Instabilities of Thermal Barrier Coatings at High Temperature in Gas-Cooled Fast Reactors

    Directory of Open Access Journals (Sweden)

    Jian Wang

    2016-01-01

    Full Text Available Thermally grown oxide (TGO, commonly pure α-Al2O3, formed on protective coatings acts as an insulation barrier shielding cooled reactors from high temperatures in nuclear energy systems. Mixed zone (MZ oxide often grows at the interface between the alumina layer and top coat in thermal barrier coatings (TBCs at high temperature dwell times accompanied by the formation of alumina. The newly formed MZ destroys interface integrity and significantly affects the displacement instabilities of TGO. In this work, a finite element model based on material property changes was constructed to investigate the effects of MZ on the displacement instabilities of TGO. MZ formation was simulated by gradually changing the metal material properties into MZ upon thermal cycling. Quantitative data show that MZ formation induces an enormous stress in TGO, resulting in a sharp change of displacement compared to the alumina layer. The displacement instability increases with an increase in the MZ growth rate, growth strain, and thickness. Thus, the formation of a MZ accelerates the failure of TBCs, which is in agreement with previous experimental observations. These results provide data for the understanding of TBC failure mechanisms associated with MZ formation and of how to prolong TBC working life.

  13. Supersymmetry at high temperatures

    International Nuclear Information System (INIS)

    Das, A.; Kaku, M.

    1978-01-01

    We investigate the properties of Green's functions in a spontaneously broken supersymmetric model at high temperatures. We show that, even at high temperatures, we do not get restoration of supersymmetry, at least in the one-loop approximation

  14. Multiscale Modeling of Ultra High Temperature Ceramics (UHTC) ZrB2 and HfB2: Application to Lattice Thermal Conductivity

    Science.gov (United States)

    Lawson, John W.; Daw, Murray S.; Squire, Thomas H.; Bauschlicher, Charles W.

    2012-01-01

    We are developing a multiscale framework in computational modeling for the ultra high temperature ceramics (UHTC) ZrB2 and HfB2. These materials are characterized by high melting point, good strength, and reasonable oxidation resistance. They are candidate materials for a number of applications in extreme environments including sharp leading edges of hypersonic aircraft. In particular, we used a combination of ab initio methods, atomistic simulations and continuum computations to obtain insights into fundamental properties of these materials. Ab initio methods were used to compute basic structural, mechanical and thermal properties. From these results, a database was constructed to fit a Tersoff style interatomic potential suitable for atomistic simulations. These potentials were used to evaluate the lattice thermal conductivity of single crystals and the thermal resistance of simple grain boundaries. Finite element method (FEM) computations using atomistic results as inputs were performed with meshes constructed on SEM images thereby modeling the realistic microstructure. These continuum computations showed the reduction in thermal conductivity due to the grain boundary network.

  15. Thermal properties of Na2MoO4(s) and Na2Mo2O7(s) by high-temperature Calvet calorimetry in the temperature range 335 K to 760 K

    International Nuclear Information System (INIS)

    Iyer, V.S.; Agarwal, Renu; Roy, K.N.; Venkateswaran, R.S.; Venugopal, V.; Sood, D.D.

    1990-01-01

    Enthalpy increment measurements were made on Na 2 MoO 4 and Na 2 Mo 2 O 7 in the temperature range 335 K to 760 K by the drop method using a high-temperature Calvet calorimeter. The calorimeter was calibrated using an electrical method and synthetic sapphire SRM-720(Al 2 O 3 ). An on-line computer was used for acquiring and processing results from the calorimeter. The enthalpy increments for Na 2 MoO 4 and Na 2 Mo 2 O 7 were least-squares fitted to a polynomial with temperature and are given. The thermal properties of Na 2 MoO 4 and Na 2 Mo 2 O 7 were obtained using the above experimental values. These are the first experimental results on the thermal properties of these compounds. (author)

  16. High temperature corrosion of thermally sprayed NiCr- and amorphous Fe-based coatings covered with a KCl-K{sub 2}SO{sub 4} salt

    Energy Technology Data Exchange (ETDEWEB)

    Varis, T.; Suhonen, T.; Tuurna, S.; Ruusuvuori, K.; Holmstroem, S.; Salonen, J. [VTT, Espoo (Finland); Bankiewicz, D.; Yrjas, P. [Aabo Akademi Univ., Turku (Finland)

    2010-07-01

    New process conditions due to the requirement of higher efficiency together with the use of high-chlorine and alkali containing fuels such as biomass and waste fuels for heat and electricity production will challenge the resistance and life of tube materials. In conventional materials the addition of alloying elements to increase the corrosion resistance in aggressive combustion conditions increases costs relatively rapidly. Thermally sprayed coating offer promising, effective, flexible and cost efficient solutions to fulfill the material needs for the future. Some heat exchanger design alteractions before global commercialization have to be overcome, though. High temperature corrosion in combustion plants can occur by a variety of mechanisms including passive scale degradation with subsequent rapid scaling, loss of adhesion and scale detachment, attack by melted or partly melted deposits via fluxing reactions and intergranular-/interlamellar corrosion. A generally accepted model of the ''active oxidation'' attributes the responsibility for inducing corrosion to chlorine. The active oxidation mechanism plays a key role in the thermally sprayed coatings due to their unique lamellar structure. In this study, the corrosion behaviour of NiCr (HVOF and Wire Arc), amorphous Fe-based, and Fe13Cr (Wire Arc) thermally sprayed coatings, were tested in the laboratory under simplified biomass combustion conditions. The tests were carried out by using a KCl-K{sub 2}SO{sub 4} salt mixture as a synthetic biomass ash, which was placed on the materials and then heat treated for one week (168h) at two different temperatures (550{sup 0}C and 600 C) and in two different gas atmospheres (air and air+30%H{sub 2}O). After the exposures, the metallographic cross sections of the coatings were studied with SEM/EDX analyzer. The results showed that the coatings behaved relatively well at the lower test temperature while critical corrosion through the lamella boundaries

  17. More with thermal energy storage. Report 6. High temperature storage. Overview of knowledge and results of measurements with regard to high temperature storage systems. Final report; Meer met bodemenergie. Rapport 6. Hogetemperatuuropslag. Kennisoverzicht en praktijkmetingen rondom hogetemperatuuropslagsystemen. Eindrapport

    Energy Technology Data Exchange (ETDEWEB)

    Drijver, B. [IF Technology, Arnhem (Netherlands)

    2012-03-30

    The project More With Thermal Energy Storage (MMB, abbreviated in Dutch) focuses on knowledge gaps and potential opportunities regarding open systems. The main questions to be answered are: (1) What effects (hydrological, thermal, microbiological and chemical) occur in the soil system by application of thermal energy storage; (2) Which technical options are available for a sustainable integration of thermal energy storage in the water and energy chain?; (3) Is it possible to achieve multiple objectives by using smart combinations? The project is organized in different work packages. In work package 2, the effects of individual and collective thermal energy storage storage systems on subsoils and the environment are determined. In work package 3 the opportunities for thermal energy storage and soil remediation are examined, while in work package 4 the focus is on new sustainable combinations of heat and cold storage. Work package 1 is the umbrella part where communication and policy of and participation in MMB are the main subjects. This report includes the results of research in the field of high temperature heat storage. Residual heat, which comes available in the summer can be used for heating purposes in the winter. To realize that heat can be stored temporarily. It appears that the subsurface can be used, which has resulted in a strong growth of heat and cold storage systems [Dutch] Het project Meer Met Bodemenergie (MMB) richt zich op het invullen van kennisleemtes en mogelijke kansen ten aanzien van open systemen. De belangrijkste vragen waarop het onderzoeksprogramma MMB antwoord geeft zijn: (1) Welke effecten (hydrologisch, thermisch, microbiologisch en chemisch) treden op in het bodemsysteem bij toepassing van bodemenergie?; (2) Welke technische mogelijkheden zijn er voor het duurzaam inpassen van bodem-energie in de water- en energieketen?; (3) Is het mogelijk om meerdere doelstellingen tegelijk te verwezenlijken door slimme combinaties te maken? Het

  18. Rise-to-power test in High Temperature Engineering Test Reactor. Test progress and summary of test results up to 30 MW of reactor thermal power

    International Nuclear Information System (INIS)

    Nakagawa, Shigeaki; Fujimoto, Nozomu; Shimakawa, Satoshi

    2002-08-01

    The High Temperature Engineering Test Reactor (HTTR) is a graphite moderated and gas cooled reactor with the thermal power of 30 MW and the reactor outlet coolant temperature of 850degC/950degC. Rise-to-power test in the HTTR was performed from April 23rd to June 6th in 2000 as phase 1 test up to 10 MW in the rated operation mode, from January 29th to March 1st in 2001 as phase 2 test up to 20 MW in the rated operation mode and from April 14th to June 8th in 2001 as phase 3 test up to 20 MW in the high temperature test the mechanism of the reactor outlet coolant temperature becomes 850degC at 30 MW in the rated operation mode and 950degC in the high temperature test operation mode. Phase 4 rise-to-power test to achieve the thermal reactor power of 30 MW started on October 23rd in 2001. On December 7th in 2001 it was confirmed that the thermal reactor power and the reactor outlet coolant temperature reached to 30 MW and 850degC respectively in the single loaded operation mode in which only the primary pressurized water cooler is operating. Phase 4 test was performed until March 6th in 2002. JAERI (Japan Atomic Energy Research Institute) obtained the certificate of the pre-operation test from MEXT (Ministry of Education Culture Sports Science and Technology) after all the pre-operation tests by MEXT were passed successfully with the reactor transient test at an abnormal event as a final pre-operation test. From the test results of the rise-up-power test up to 30 MW in the rated operation mode, performance of the reactor and cooling system were confirmed, and it was also confirmed that an operation of reactor facility can be performed safely. Some problems to be solved were found through the tests. By solving them, the reactor operation with the reactor outlet coolant temperature of 950degC will be achievable. (author)

  19. Lattice Thermal Conductivity of Ultra High Temperature Ceramics (UHTC) ZrB2 and HfB2 from Atomistic Simulations

    Science.gov (United States)

    Lawson, John W.; Daw, Murray S.; Bauschlicher, Charles W.

    2012-01-01

    Ultra high temperature ceramics (UHTC) including ZrB2 and HfB2 have a number of properties that make them attractive for applications in extreme environments. One such property is their high thermal conductivity. Computational modeling of these materials will facilitate understanding of fundamental mechanisms, elucidate structure-property relationships, and ultimately accelerate the materials design cycle. Progress in computational modeling of UHTCs however has been limited in part due to the absence of suitable interatomic potentials. Recently, we developed Tersoff style parameterizations of such potentials for both ZrB2 and HfB2 appropriate for atomistic simulations. As an application, Green-Kubo molecular dynamics simulations were performed to evaluate the lattice thermal conductivity for single crystals of ZrB2 and HfB2. The atomic mass difference in these binary compounds leads to oscillations in the time correlation function of the heat current, in contrast to the more typical monotonic decay seen in monoatomic materials such as Silicon, for example. Results at room temperature and at elevated temperatures will be reported.

  20. Thermal operator representation of finite temperature graphs

    International Nuclear Information System (INIS)

    Brandt, F.T.; Frenkel, J.; Das, Ashok; Espinosa, Olivier; Perez, Silvana

    2005-01-01

    Using the mixed space representation (t,p→) in the context of scalar field theories, we prove in a simple manner that the Feynman graphs at finite temperature are related to the corresponding zero temperature diagrams through a simple thermal operator, both in the imaginary time as well as in the real time formalisms. This result is generalized to the case when there is a nontrivial chemical potential present. Several interesting properties of the thermal operator are also discussed

  1. High temperature divertor plasma operation

    International Nuclear Information System (INIS)

    Ohyabu, Nobuyoshi.

    1991-02-01

    High temperature divertor plasma operation has been proposed, which is expected to enhance the core energy confinement and eliminates the heat removal problem. In this approach, the heat flux is guided through divertor channel to a remote area with a large target surface, resulting in low heat load on the target plate. This allows pumping of the particles escaping from the core and hence maintaining of the high divertor temperature, which is comparable to the core temperature. The energy confinement is then determined by the diffusion coefficient of the core plasma, which has been observed to be much lower than the thermal diffusivity. (author)

  2. A IR-Femtosecond Laser Hybrid Sensor to Measure the Thermal Expansion and Thermo-Optical Coefficient of Silica-Based FBG at High Temperatures.

    Science.gov (United States)

    Li, Litong; Lv, Dajuan; Yang, Minghong; Xiong, Liangming; Luo, Jie

    2018-01-26

    In this paper, a hybrid sensor was fabricated using a IR-femtosecond laser to measure the thermal expansion and thermo-optical coefficient of silica-based fiber Bragg gratings (FBGs). The hybrid sensor was composed of an inline fiber Fabry-Perot interferometer (FFPI) cavity and a type-II FBG. Experiment results showed that the type-II FBG had three high reflectivity resonances in the wavelength ranging from 1100 to 1600 nm, showing the peaks in 1.1, 1.3 and 1.5 μm, respectively. The thermal expansion and thermo-optical coefficient (1.3 μm, 1.5 μm) of silica-based FBG, under temperatures ranging from 30 to 1100 °C, had been simultaneously calculated by measuring the wavelength of the type-II FBG and FFPI cavity length.

  3. Determination of thermal properties of Cs2Cr2O7(s,l) by high temperature Calvet calorimetry

    International Nuclear Information System (INIS)

    Prasad, R.; Agarwal, R.; Roy, K.N.; Iyer, V.S.; Venugopal, V.; Sood, D.D.

    1989-01-01

    Enthalpy increments have been determined for caesium dichromate in the temperature range 335 to 826 K using a high temperature Calvet micro calorimeter. A solid-solid transition has been observed at (620.5±1.5 K) and the melting temperature was found to be (657.0±1.0) K. The corresponding enthalpy values are 15.6±0.2) kJ/mol and 17.0±0.22) kJ/mol. The results thus obtained are utilised for the evaluation of molar heat capacities, standard entropies and free energy functions for Cs 2 Cr 2 O 7 (s,l). The enthalpy increment values were fitted to a polynomial and can be presented by eqs. (1) to (3), respectivley: (1) (H T 0 -H 0 298.15 )(Cs 2 Cr 2 O 7 ,s) (J/mol)=-6.410x10 4 +1.939x10 2 T(K)+7.441x10 -2 T(K) 2 (335 to 620.5 K), (2) (H T 0 -H 0 298.15 )(Cs 2 Cr 2 O 7 ,s) (J/mol)=1.313x10 6 -4.137x10 3 T(K)+3.517T(K) 2 (620.5 to 656 K), (3) (H T 0 -H 0 298.15 )(Cs 2 Cr 2 O 7 ,l) (J/mol)=-1.218x10 5 +3.890x10 2 T(K) (657 to 826 K). (orig.)

  4. Linear thermal expansion, thermal diffusivity and melting temperature of Am-MOX and Np-MOX

    International Nuclear Information System (INIS)

    Prieur, D.; Belin, R.C.; Manara, D.; Staicu, D.; Richaud, J.-C.; Vigier, J.-F.; Scheinost, A.C.; Somers, J.; Martin, P.

    2015-01-01

    Highlights: • The thermal properties of Np- and Am-MOX solid solutions were investigated. • Np- and Am-MOX solid solutions exhibit the same linear thermal expansion. • The thermal conductivity of Am-MOX is about 10% higher than that of Np-MOX. • The melting temperatures of Np-MOX and Am-MOX are 3020 ± 30 K and 3005 ± 30 K, respectively. - Abstract: The thermal properties of Np- and Am-MOX solid solution materials were investigated. Their linear thermal expansion, determined using high temperature X-ray diffraction from room temperature to 1973 K showed no significant difference between the Np and the Am doped MOX. The thermal conductivity of the Am-MOX is about 10% higher than that of Np-MOX. The melting temperatures of Np-MOX and Am-MOX, measured using a laser heating self crucible arrangement were 3020 ± 30 K and 3005 ± 30 K, respectively

  5. Thermal diffusivity of electrical insulators at high temperatures: Evidence for diffusion of bulk phonon-polaritons at infrared frequencies augmenting phonon heat conduction

    Science.gov (United States)

    Hofmeister, Anne M.; Dong, Jianjun; Branlund, Joy M.

    2014-04-01

    We show that laser-flash analysis measurements of the temperature (T) dependence of thermal diffusivity (D) for diverse non-metallic (e.g., silicates) single-crystals is consistently represented by D(T) = FT-G + HT above 298 K, with G ranging from 0.3 to 2, depending on structure, and H being ˜10-4 K-1 for 51 single-crystals, 3 polycrystals, and two glasses unaffected by disorder or reconstructive phase transitions. Materials exhibiting this behavior include complex silicates with variable amounts of cation disorder, perovskite structured materials, and graphite. The high-temperature term HT becomes important by ˜1300 K, above which temperature its contribution to D(T) exceeds that of the FT-G term. The combination of the FT-G and HT terms produces the nearly temperature independent high-temperature region of D previously interpreted as the minimal phonon mean free path being limited by the finite interatomic spacing. Based on the simplicity of the fit and large number of materials it represents, this finding has repercussions for high-temperature models of heat transport. One explanation is that the two terms describing D(T) are associated with two distinct microscopic mechanisms; here, we explore the possibility that the thermal diffusivity of an electrical insulator could include both a contribution of lattice phonons (the FT-G term) and a contribution of diffusive bulk phonon-polaritons (BPP) at infrared (IR) frequencies (the HT term). The proposed BPP diffusion exists over length scales smaller than the laboratory sample sizes, and transfers mixed light and vibrational energy at a speed significantly smaller than the speed of light. Our diffusive IR-BPP hypothesis is consistent with other experimental observations such as polarization behavior, dependence of D on the number of IR peaks, and H = 0 for Ge and Si, which lack IR fundamentals. A simple quasi-particle thermal diffusion model is presented to begin understanding the contribution from bulk phonon

  6. High-temperature catalytic reforming of n-hexane over supported and core-shell Pt nanoparticle catalysts: role of oxide-metal interface and thermal stability.

    Science.gov (United States)

    An, Kwangjin; Zhang, Qiao; Alayoglu, Selim; Musselwhite, Nathan; Shin, Jae-Youn; Somorjai, Gabor A

    2014-08-13

    Designing catalysts with high thermal stability and resistance to deactivation while simultaneously maintaining their catalytic activity and selectivity is of key importance in high-temperature reforming reactions. We prepared Pt nanoparticle catalysts supported on either mesoporous SiO2 or TiO2. Sandwich-type Pt core@shell catalysts (SiO2@Pt@SiO2 and SiO2@Pt@TiO2) were also synthesized from Pt nanoparticles deposited on SiO2 spheres, which were encapsulated by either mesoporous SiO2 or TiO2 shells. n-Hexane reforming was carried out over these four catalysts at 240-500 °C with a hexane/H2 ratio of 1:5 to investigate thermal stability and the role of the support. For the production of high-octane gasoline, branched C6 isomers are more highly desired than other cyclic, aromatic, and cracking products. Over Pt/TiO2 catalyst, production of 2-methylpentane and 3-methylpentane via isomerization was increased selectively up to 420 °C by charge transfer at Pt-TiO2 interfaces, as compared to Pt/SiO2. When thermal stability was compared between supported catalysts and sandwich-type core@shell catalysts, the Pt/SiO2 catalyst suffered sintering above 400 °C, whereas the SiO2@Pt@SiO2 catalyst preserved the Pt nanoparticle size and shape up to 500 °C. The SiO2@Pt@TiO2 catalyst led to Pt nanoparticle sintering due to incomplete protection of the TiO2 shells during the reaction at 500 °C. Interestingly, over the Pt/TiO2 catalyst, the average size of Pt nanoparticles was maintained even after 500 °C without sintering. In situ ambient pressure X-ray photoelectron spectroscopy demonstrated that the Pt/TiO2 catalyst did not exhibit TiO2 overgrowth on the Pt surface or deactivation by Pt sintering up to 600 °C. The extraordinarily high stability of the Pt/TiO2 catalyst promoted high reaction rates (2.0 μmol · g(-1) · s(-1)), which was 8 times greater than other catalysts and high isomer selectivity (53.0% of C6 isomers at 440 °C). By the strong metal-support interaction

  7. High thermal load component

    International Nuclear Information System (INIS)

    Fuse, Toshiaki; Tachikawa, Nobuo.

    1996-01-01

    A cooling tube made of a pure copper is connected to the inner portion of an armour (heat resistant member) made of an anisotropic carbon/carbon composite (CFC) material. The CFC material has a high heat conductivity in longitudinal direction of fibers and has low conductivity in perpendicular thereto. Fibers extending in the armour from a heat receiving surface just above the cooling tube are directly connected to the cooling tube. A portion of the fibers extending from a heat receiving surface other than portions not just above the cooling tube is directly bonded to the cooling tube. Remaining fibers are disposed so as to surround the cooling tube. The armour and the cooling tube are soldered using an active metal flux. With such procedures, high thermal load components for use in a thermonuclear reactor are formed, which are excellent in a heat removing characteristic and hardly causes defects such as crackings and peeling. (I.N.)

  8. Thermal inactivation of foot-and-mouth disease virus in milk using high-temperature, short-time pasteurization.

    Science.gov (United States)

    Tomasula, P M; Kozempel, M F; Konstance, R P; Gregg, D; Boettcher, S; Baxt, B; Rodriguez, L L

    2007-07-01

    Previous studies of laboratory simulation of high temperature, short time pasteurization (HTST) to eliminate foot-and-mouth disease virus (FMDV) in milk have shown that the virus is not completely inactivated at the legal pasteurization minimum (71.7 degrees C/15 s) but is inactivated in a flow apparatus at 148 degrees C with holding times of 2 to 3 s. It was the intent of this study to determine whether HTST pasteurization conducted in a continuous-flow pasteurizer that simulates commercial operation would enhance FMDV inactivation in milk. Cows were inoculated in the mammary gland with the field strain of FMDV (01/UK). Infected raw whole milk and 2% milk were then pasteurized using an Arm-field pilot-scale, continuous-flow HTST pasteurizer equipped with a plate-and-frame heat exchanger and a holding tube. The milk samples, containing FMDV at levels of up to 10(4) plaque-forming units/mL, were pasteurized at temperatures ranging from 72 to 95 degrees C at holding times of either 18.6 or 36 s. Pasteurization decreased virus infectivity by 4 log10 to undetectable levels in tissue culture. However, residual infectivity was still detectable for selected pasteurized milk samples, as shown by intramuscular and intradermal inoculation of milk into naïve steers. Although HTST pasteurization did not completely inactivate viral infectivity in whole and 2% milk, possibly because a fraction of the virus was protected by the milk fat and the casein proteins, it greatly reduced the risk of natural transmission of FMDV by milk.

  9. High thermal load structure

    International Nuclear Information System (INIS)

    Tsujimura, Seiichi; Toyota, Masahiko.

    1995-01-01

    A highly thermal load structure applied to a plasma-opposed equipment of a thermonuclear device comprises heat resistant protection tiles and a cooling tube disposed in the protection tiles. As the protection tiles, a carbon/carbon composite material is used. The carbon/carbon composite material on the heat receiving surface comprises carbon fibers disposed in one direction (one dimensionally) arranged from the heat receiving surface toward the cooling tube. The carbon/carbon composite material on the side opposite to the heat receiving surface comprises carbon fibers arranged two-dimensionally in the direction perpendicular to the longitudinal direction of the cooling tube. Then, the cooling tube is interposed between the one-dimensional carbon/carbon composite material and the two-dimensional carbon/carbon composite material, and they are joined with each other by vacuum brazing. This can improve heat removing performance. In addition, thermal stresses at the joined portion is reduced. Further, electromagnetic force generated in the thermonuclear device is reduced. (I.N.)

  10. High thermal load structure

    Energy Technology Data Exchange (ETDEWEB)

    Tsujimura, Seiichi; Toyota, Masahiko

    1995-06-16

    A highly thermal load structure applied to a plasma-opposed equipment of a thermonuclear device comprises heat resistant protection tiles and a cooling tube disposed in the protection tiles. As the protection tiles, a carbon/carbon composite material is used. The carbon/carbon composite material on the heat receiving surface comprises carbon fibers disposed in one direction (one dimensionally) arranged from the heat receiving surface toward the cooling tube. The carbon/carbon composite material on the side opposite to the heat receiving surface comprises carbon fibers arranged two-dimensionally in the direction perpendicular to the longitudinal direction of the cooling tube. Then, the cooling tube is interposed between the one-dimensional carbon/carbon composite material and the two-dimensional carbon/carbon composite material, and they are joined with each other by vacuum brazing. This can improve heat removing performance. In addition, thermal stresses at the joined portion is reduced. Further, electromagnetic force generated in the thermonuclear device is reduced. (I.N.).

  11. High Temperature Chemistry at NASA: Hot Topics

    Science.gov (United States)

    Jacobson, Nathan S.

    2014-01-01

    High Temperature issues in aircraft engines Hot section: Ni and Co based Superalloys Oxidation and Corrosion (Durability) at high temperatures. Thermal protection system (TPS) and RCC (Reinforced Carbon-Carbon) on the Space Shuttle Orbiter. High temperatures in other worlds: Planets close to their stars.

  12. High temperature oxidation behavior of hafnium modified NiAl bond coat in EB-PVD thermal barrier coating system

    Energy Technology Data Exchange (ETDEWEB)

    Guo Hongbo; Sun Lidong; Li Hefei [Department of Material Science and Engineering, Beijing University of Aeronautics and Astronautics, No.37 Xueyuan Road, Beijing 100083 (China); Gong Shengkai [Department of Material Science and Engineering, Beijing University of Aeronautics and Astronautics, No.37 Xueyuan Road, Beijing 100083 (China)], E-mail: gongsk@buaa.edu.cn

    2008-06-30

    NiAl coatings doped with 0.5 at.% and 1.5 at.% Hf were produced by co-evaporation of NiAl and Hf ingots by electron beam physical vapor deposition (EB-PVD), respectively. The addition of 0.5 at.% Hf significantly improved the cyclic oxidation resistance of the NiAl coating. The TGO layer in the 1.5 at.% Hf doped NiAl coating is straight; while that in the 0.5 at.% Hf doped coating became undulated after thermal cycling. The doped NiAl thermal barrier coatings (TBCs) revealed improved thermal cycling lifetimes at 1423 K, compared to the undoped TBC. Failure of the 0.5 at.% Hf doped TBC occurred by cracking at the interface between YSZ topcoat and bond coat, while the 1.5 at.% Hf doped TBC cracked at the interface between bond coat and substrate.

  13. Study of mixed radiative thermal mass transfer in the case of spherical liquide particle evaporation in a high temperature thermal air plasma

    International Nuclear Information System (INIS)

    Garandeau, S.

    1984-01-01

    Radiative transfer in a semi-transparent non-isothermal medium with spherical configuration has been studied. Limit conditions have been detailed, among which the semi-transparent inner sphere case is a new case. Enthalpy and matter transfer equations related to these different cases have been established. An adimensional study of local conservation laws allowed to reveal a parameter set characteristic of radiation coupled phenomena thermal conduction, convection, diffusion. Transfer equations in the case of evaporation of a liquid spherical particle in an air thermal plasma have been simplified. An analytical solution for matter transfer is proposed. Numerical solution of radiative problems and matter transfer has been realized [fr

  14. Hydrothermal hardened high-temperature thermal insulation material CALUTHERM {sup registered} from hibonite and alumina cement. Pt. 1; Hydrothermal erhaerteter Hochtemperaturwaermedaemmstoff CALUTHERM {sup registered} aus Hibonit und Tonerdezement. T. 1

    Energy Technology Data Exchange (ETDEWEB)

    Hoelscher, Tobias; Schneider, Hans-Juergen [Calsitherm Silikatbaustoffe GmbH, Bad Lippspringe (Germany); Schlegel, Ernst

    2013-07-01

    The first part features an overview to the properties of all calcium aluminates followed by a presentation of CALUTHERM {sup registered}, a high temperature-thermal insulating material. CALUTHERM is produced on the bases of SLA-92, a calcium hexaaluminat aggregate, and calcium aluminate cement CA-14 W as binder. The comprehensive studies focus on properties and changes of these raw materials during the technological stages of the CALUTHERM's production. The second part will present CALUTHERM's properties and its variants throughout the production process. A possible correlation between the properties of raw materials and thermal insulation material is researched and finally application examples are presented. CALUTHERM is suited for thermal insulation up to 1600 C and has a remarkable low thermal conductivity near 0.4 W/m . K at these high temperatures. For that reason CALUTHERM is a top high-temperature thermal insulating material. (orig.)

  15. High-temperature resistant, thermally sprayed diffusion barrier coatings on CFC lightweight materials; Hochtemperaturbestaendige, thermisch gespritzte Diffusionsbarriereschichten auf CFC-Leichtbauchargiergestellen

    Energy Technology Data Exchange (ETDEWEB)

    Drehmann, Rico; Rupprecht, Christian; Wielage, Bernhard; Lampke, Thomas [Technische Univ. Chemnitz (Germany). Inst. fuer Werkstoffwissenschaft und Werkstofftechnik (IWW); Gilbert, Maria; Uhlig, Volker; Trimis, Dimosthenis [Technische Univ. Bergakademie Freiberg (Germany). Inst. fuer Waermetechnik und Thermodynamik (IWTT); Heuer, Volker [ALD Vacuum Technologies GmbH, Hanau (Germany)

    2013-03-15

    In heat treating processes as well as in high temperature brazing processes, charge carriers enable the positioning and transport of work pieces. Recently, charge carriers consisting of graphite or carbon fibre reinforced carbon (CFC) are used. The main disadvantage of charge carriers based on CFC is the undesirable carburization of the overlying components due to diffusion processes. Under this aspect, thermally sprayed coatings are applied on CFC and tested with respect to their suitability as a high-temperature diffusion barrier. The ceramic powders aluminium oxide, aluminium oxide/chromium oxide, aluminium oxide/titanium oxide and zirconium oxide/yttrium oxide are used as a coating material which is processed by means of the powder flame spraying as well as atmospheric plasma spraying. Molybdenum and silicon carbide are used as an adhesive layer. The coating materials aluminium oxide and aluminium oxide/chromium oxide on siliconized CFC presented excellent results. This supplies a large potential of application for thermally sprayed ceramic coatings on carbon-based lightweight materials.

  16. Physical and thermal waste utilisation in industrial high-temperature processes; Stoffliche und thermische Verwertung von Abfaellen in industriellen Hochtemperaturprozessen. Fachseminar

    Energy Technology Data Exchange (ETDEWEB)

    Leithner, R. [ed.

    1998-09-01

    This year`s DVV Colloquium, the eleventh of its kind, was dedicated to ``Physical and thermal waste utilisation in industrial high-temperature processes``, a topic of growing importance in our time. The three old principles of Disperse, Bury, and Forget having been found inexpedient, there is now a growing interest in the three new principles of Avoid, Reduce, and Utilise. The colloquium saw a scientific discussion on physical and thermal waste utilisation in high-temperature processes. Proposals were made for the solution of specific problems, and the economic implications and impact of these solutions on products and the environment were elucidated. [Deutsch] Das diesjaehrige 11. DVV-Kolloquium mit dem Thema: `Stoffliche und thermische Verwertung von Abfaellen in industriellen Hochtemperaturprozessen`, behandelt einen Themenkomplex, der immer mehr an Bedeutung gewinnt. Nachdem sich die drei alten Prinzipien Verteilen, Vergraben, Vergessen als unzweckmaessig herausgestellt haben, gewinnen die drei neuen Prinzipien Vermeiden, Vermindern, Verwerten immer groessere Bedeutung. Stoffliche und thermische Verwertung in industriellen Hochtemperaturprozessen werden in diesem Kolloquium wissenschaftlich diskutiert und Loesungsvorschlaege und deren wirtschaftliche Implikationen und deren Auswirkungen auf die Produkte und die Umwelt beleuchtet. (orig.)

  17. Thermal conduction down steep temperature gradients

    International Nuclear Information System (INIS)

    Bell, A.R.; Evans, R.G.; Nicholas, D.J.

    1980-08-01

    The Fokker-Planck equation has been solved numerically in one spatial and two velocity dimensions in order to study thermal conduction in large temperature gradients. An initially cold plasma is heated at one end of the spatial grid producing temperature gradients with scale lengths of a few times the electron mean free path. The heat flow is an order of magnitude smaller than that predicted by the classical theory which is valid in the limit of small temperature gradients. (author)

  18. High temperature refrigerator

    International Nuclear Information System (INIS)

    Steyert, W.A. Jr.

    1978-01-01

    A high temperature magnetic refrigerator is described which uses a Stirling-like cycle in which rotating magnetic working material is heated in zero field and adiabatically magnetized, cooled in high field, then adiabatically demagnetized. During this cycle the working material is in heat exchange with a pumped fluid which absorbs heat from a low temperature heat source and deposits heat in a high temperature reservoir. The magnetic refrigeration cycle operates at an efficiency 70% of Carnot

  19. SIMS and thermal evolution analysis of oxygen in Zr-1%Nb alloy after high-temperature transitions

    Czech Academy of Sciences Publication Activity Database

    Lorinčík, Jan; Klouček, V.; Negyesi, M.; Kabátová, J.; Novotný, L.; Vrtílková, V.

    2011-01-01

    Roč. 43, 1-2 (2011), s. 618-620 ISSN 0142-2421 Institutional research plan: CEZ:AV0Z20670512 Keywords : SIMS * Thermal evolution analysis * Zirconium alloy Subject RIV: JA - Electronics ; Optoelectronics, Electrical Engineering Impact factor: 1.180, year: 2011

  20. High-temperature superconductivity

    International Nuclear Information System (INIS)

    Lynn, J.W.

    1990-01-01

    This book discusses development in oxide materials with high superconducting transition temperature. Systems with Tc well above liquid nitrogen temperature are already a reality and higher Tc's are anticipated. The author discusses how the idea of a room-temperature superconductor appears to be a distinctly possible outcome of materials research

  1. The film thickness dependent thermal stability of Al{sub 2}O{sub 3}:Ag thin films as high-temperature solar selective absorbers

    Energy Technology Data Exchange (ETDEWEB)

    Xiao Xiudi; Xu Gang, E-mail: xiudixiao@163.com; Xiong Bin; Chen Deming; Miao Lei [Chinese Academy of Sciences, Key Laboratory of Renewable Energy and Gas Hydrates, Guangzhou Institute of Energy Conversion (China)

    2012-03-15

    The monolayer Al{sub 2}O{sub 3}:Ag thin films were prepared by magnetron sputtering. The microstructure and optical properties of thin film after annealing at 700 Degree-Sign C in air were characterized by transmission electron microscopy, X-ray diffraction, X-ray photoelectron spectroscopy, and spectrophotometer. It revealed that the particle shape, size, and distribution across the film were greatly changed before and after annealing. The surface plasmon resonance absorption and thermal stability of the film were found to be strongly dependent on the film thickness, which was believed to be associated with the evolution process of particle diffusion, agglomeration, and evaporation during annealing at high temperature. When the film thickness was smaller than 90 nm, the film SPR absorption can be attenuated until extinct with increasing annealing time due to the evaporation of Ag particles. While the film thickness was larger than 120 nm, the absorption can keep constant even after annealing for 64 h due to the agglomeration of Ag particles. On the base of film thickness results, the multilayer Al{sub 2}O{sub 3}:Ag solar selective thin films were prepared and the thermal stability test illustrated that the solar selectivity of multilayer films with absorbing layer thickness larger than 120 nm did not degrade after annealing at 500 Degree-Sign C for 70 h in air. It can be concluded that film thickness is an important factor to control the thermal stability of Al{sub 2}O{sub 3}:Ag thin films as high-temperature solar selective absorbers.

  2. Crack initiation and crack growth in high temperature materials under cyclic thermal stresses; Rissinitiierung und Risswachstum in Hochtemperaturwerkstoffen unter zyklisch thermischer Beanspruchung

    Energy Technology Data Exchange (ETDEWEB)

    Gruen, C.

    1996-12-01

    The high temperatures of use in drive units, such as the combustion chamber or the hot gas turbine, for example, usually cause high temperature changes. Great temperature differences occur for short periods in the components, and thermal shock is produced. In this work, theoretical and experimental investigations are introduced on crack initiation and crack growth in high temperature materials under cyclic thermal stresses. The experiments were carried out with the inter-metallic phase Ni{sub 3}Al, the nickel-based alloy Nimonic 80A and the iron-based alloy PM 2000 strengthened by oxide dispersion (ODS). A characteristic crack appearance picture was found for each material, which was examined more closely. The stresses occurring in the sample during one cycle were calculated with the aid of the finite element program ABAQUS, knowing the specific material parameters. Based on the linear-elastic fracture mechanics, stress intensity factors were calculated on the superimposition principle. Using the material data from isothermal crack propagation experiments, the prediction of fatigue crack spread with cyclic thermal stresses is compared with the experimental findings. (orig./AKF) [Deutsch] Die hohen Einsatztemperaturen in Antriebsaggregaten wie z.B. der Brennkammer oder der Heissgasturbine bedingen in der Regel hohe Temperaturwechsel. Dabei treten kurzzeitig grosse Temperaturunterschiede in den Bauteilen auf, ein Thermoschock wird erzeugt. In der vorliegenden Arbeit werden theoretische und experimentelle Untersuchungen zur Rissinitiierung und zum Risswachstum in Hochtemperaturwerkstoffen unter zyklisch thermischer Belastung vorgestellt. Die Experimente wurden mit der intermetallischen Phase Ni{sub 3}Al, der Nickelbasislegierung Nimonic 80A und der oxid-dispersionsverfestigten (ODS) Eisenbasislegierung PM2000 durchgefuehrt. Fuer jeden Werkstoff stellte sich ein charakteristisches Risserscheinungsbild dar, das naeher untersucht wurde. Die in der Probe auftretenden

  3. Tailoring a High Temperature Corrosion Resistant FeNiCrAl for Oxy-Combustion Application by Thermal Spray Coating and HIP

    Directory of Open Access Journals (Sweden)

    Jarkko Metsäjoki

    2015-10-01

    Full Text Available Oxy-fuel combustion combined with CCS (carbon capture and storage aims to decrease CO2 emissions in energy production using fossil fuels. Oxygen firing changes power plant boiler conditions compared to conventional firing. Higher material temperatures and harsher and more variable environmental conditions cause new degradation processes that are inadequately understood at the moment. In this study, an Fe-Ni-Cr-Al alloy was developed based on thermodynamic simulations. The chosen composition was manufactured as powder by gas atomization. The powder was sieved into two fractions: The finer was used to produce thermal spray coatings by high velocity oxy-fuel (HVOF and the coarser to manufacture bulk specimens by hot isostatic pressing (HIP. The high temperature corrosion properties of the manufactured FeNiCrAl coating and bulk material were tested in laboratory conditions simulating oxy-combustion. The manufacturing methods and the results of high temperature corrosion performance are presented. The corrosion performance of the coating was on average between the bulk steel references Sanicro 25 and TP347HFG.

  4. Phase Change Material Selection for Thermal Energy Storage at High Temperature Range between 210 °C and 270 °C

    Directory of Open Access Journals (Sweden)

    José Miguel Maldonado

    2018-04-01

    Full Text Available The improvement of thermal energy storage systems implemented in solar technologies increases not only their performance but also their dispatchability and competitiveness in the energy market. Latent heat thermal energy storage systems are one of those storing methods. Therefore, the need of finding the best materials for each application becomes an appealing research subject. The main goal of this paper is to find suitable and economically viable materials able to work as phase change material (PCM within the temperature range of 210–270 °C and endure daily loading and unloading processes in a system with Fresnel collector and an organic Rankine cycle (ORC. Twenty-six materials have been tested and characterized in terms of their thermophysical conditions, thermal and cycling stability, and health hazard. Two materials out of the 26 candidates achieved the last stage of the selection process. However, one of the two finalists would require an inert working atmosphere, which would highly increase the cost for the real scale application. This leads to a unique suitable material, solar salt (40 wt % KNO3/60 wt % NaNO3.

  5. Evaluation of Effective thermal conductivity models on the prismatic fuel block of a Very High Temperature Reactor by CFD analysis

    International Nuclear Information System (INIS)

    Shin, Dong-Ho; Cho, Hyoung-Kyu; Tak, Nam-Il; Park, Goon-Cherl

    2014-01-01

    Effective thermal conductivity models which can be used to analyze the heat transfer phenomena of a prismatic fuel block were evaluated by CFD analysis. In the accident condition of VHTR when forced convection is lost, the heat flows in radial direction through the hexagonal fuel blocks that contain the large number of coolant holes and fuel compacts. Due to the complex geometry of fuel block and radiation heat transfer; the detail heat transfer computation on the fuel block needs excessive computation resources. Therefore, the detail computation isn’t appropriate for the lumped parameter code. The system code such as GAMMA+ adopts effective thermal conductivity model. Despite the complexity in heat transfer modes, the accurate analysis on the heat transfer in fuel block is necessary since it is directly relevant to the integrity of nuclear fuel embedded in fuel block. To satisfy the accurate analysis of complex heat transfer modes with limited computing sources, the credible effective thermal conductivity (ETC) models in which the effects of all of heat transfer modes are lumped is necessary. In this study, various ETC models were introduced and they are evaluated with CFD calculations. It is estimated that Maxwell-based model was the most pertinent one among the introduced ETC models. (author)

  6. TORT-TD/ATTICA3D: a coupled neutron transport and thermal hydraulics code system for 3-D transient analysis of gas cooled high temperature reactors

    International Nuclear Information System (INIS)

    Lapins, J.; Seubert, A.; Buck, M.; Bader, J.; Laurien, E.

    2011-01-01

    Comprehensive safety studies of high temperature gas cooled reactors (HTR) require full three dimensional coupled treatments of both neutron kinetics and thermal-hydraulics. In a common effort, GRS and IKE developed the coupled code system TORT-TD/ATTICA3D for pebble bed type HTR that connects the 3-D transient discrete-ordinates transport code TORT-TD with the 3-D porous medium thermal-hydraulics code ATTICA3D. In this paper, the physical models and calculation capabilities of TORT-TD and ATTICA3D are presented, focusing on model improvements in ATTICA3D and extensions made in TORT-TD related to HTR application. For first applications, the OECD/NEA/NSC PBMR-400 benchmark has been chosen. Results obtained with TORT-TD/ATTICA3D will be shown for transient exercises, e.g. control rod withdrawal and a control rod ejection. Results are compared to other benchmark participants' solutions with special focus on fuel temperature modelling features of ATTICA3D. The provided “grey-curtain” nuclear cross section libraries have been used. First results on 3-D effects during a control rod withdrawal transient will be presented. (author)

  7. Assessment for the Applicability of Effective Thermal Conductivity Models on the Prismatic Fuel Assembly of Very High Temperature Reactor

    International Nuclear Information System (INIS)

    Shin, Dong-ho; Cho, Hyoung-kyu; Tak, Nam-il; Park, Goon-cherl

    2014-01-01

    A prismatic gas-cooled reactor is promising reactor type in the Nuclear Hydrogen Development and Demonstration (NHDD) project which was launched at KAERI (Korea Atomic Energy Research Institute). One of the most favorable characteristics of a prismatic gas-cooled reactor is its inherent and passive safety. As one of its inherent safety features, the heat flows through the prismatic core radially during the High Pressure Conduction Cooling (HPCC) or Low Pressure Conduction Cooling (LPCC) event and the radial heat transfer cools down the reactor core passively under such conditions. To verify the inherent safety of its design, the GAMMA+ code that is used to analyze VHTR thermo-fluid transients has been developed by KAERI. The code adopts effective thermal conductivity (ETC) model to analyze radial heat transfer in the core as a lumped parameter model. It is because the fuel block has complex geometry with large number of coolant holes and fuel compacts and the detail heat transfer calculations on that geometry needs excessive computation resources. GAMMA+ is adopting the Maxwell-based ETC model, however, there are several ETC models that could be applied to the GAMMA+ code. In this study, several ETC models will be introduced. They will be compared to CFD calculations which have similar condition with the fuel block. And then the most appropriate ETC model will be suggested for calculating the ETC of the fuel block. For the CFD calculation, unit cell tests with simple geometries were conducted. With unit cell test, the applicability of the ETC models were investigated. And proper ETC models were used to calculate the ETC of the fuel block and the results were compared to that of CFD calculation on the fuel block. In this study, the ETC models are introduced and the applicability of the ETC models to VHTR fuel block was investigated. The results of the ETC models were compared to those of CFD calculation. The CFD calculations were conducted for square graphite block

  8. Thermal stability of a highly-deformed warm-rolled tungsten plate in the temperature range 1100–1250 °C

    Energy Technology Data Exchange (ETDEWEB)

    Alfonso, A., E-mail: aalz@dtu.dk [Section of Materials and Surface Engineering, Department of Mechanical Engineering, Technical University of Denmark, 2800 Lyngby (Denmark); Sino-Danish Center for Education and Research, Denmark and China (Denmark); Juul Jensen, D. [Danish-Chinese Center for Nanometals, Section of Materials Science and Advanced Characterization, Department of Wind Energy, Technical University of Denmark, Risø Campus, 4000 Roskilde (Denmark); Sino-Danish Center for Education and Research, Denmark and China (Denmark); Luo, G.-N. [Fusion Reactor Materials Science and Technology Division, Institute of Plasma Physics, Chinese Academy of Sciences, 230031 Hefei, Anhui (China); Sino-Danish Center for Education and Research, Denmark and China (Denmark); Pantleon, W. [Section of Materials and Surface Engineering, Department of Mechanical Engineering, Technical University of Denmark, 2800 Lyngby (Denmark); Association EURATOM-DTU (Denmark); Sino-Danish Center for Education and Research, Denmark and China (Denmark)

    2015-10-15

    Highlights: • Annealing kinetics of highly-deformed tungsten up to 190 h between 1100 °C and 1250 °C. • Loss of mechanical strength characterized by Vickers hardness measurements. • Two distinct stages of recovery and recrystallization identified and described by established models. • Activation energy of recrystallization lower than after moderate deformation of tungsten. • Comparable to activation energy of grain boundary diffusion due to abundance of low angle boundaries. - Abstract: Pure tungsten is considered as armor material for the most critical parts of fusion reactors (i.e. the divertor and the first wall), among other reasons due to its high melting point (3422 °C) and recrystallization temperature. The thermal stability of a pure tungsten plate warm-rolled to a high plastic strain by 90% thickness reduction was investigated by isothermal annealing for up to 190 h in the temperature range between 1100 °C and 1250 °C. Vickers hardness testing allowed tracking the changes in mechanical properties caused by recovery and recrystallization. The hardness evolution could be rationalized in terms of a logarithmic recovery kinetics and a Johnson–Mehl–Avrami–Kolmogorov recrystallization kinetics accounting for an incubation time of recrystallization. The observed time spans for recrystallization and the corresponding recrystallization activation energy for this highly deformed plate suggest that large plastic deformations (e.g. applied during shaping) are only suitable to produce tungsten components to be used at relatively low temperatures (up to 900 °C for a 2 years lifespan). Higher operation temperatures will lead to fast degradation of the microstructure during operation.

  9. Thermal stability of a highly-deformed warm-rolled tungsten plate in the temperature range 1100–1250 °C

    International Nuclear Information System (INIS)

    Alfonso, A.; Juul Jensen, D.; Luo, G.-N.; Pantleon, W.

    2015-01-01

    Highlights: • Annealing kinetics of highly-deformed tungsten up to 190 h between 1100 °C and 1250 °C. • Loss of mechanical strength characterized by Vickers hardness measurements. • Two distinct stages of recovery and recrystallization identified and described by established models. • Activation energy of recrystallization lower than after moderate deformation of tungsten. • Comparable to activation energy of grain boundary diffusion due to abundance of low angle boundaries. - Abstract: Pure tungsten is considered as armor material for the most critical parts of fusion reactors (i.e. the divertor and the first wall), among other reasons due to its high melting point (3422 °C) and recrystallization temperature. The thermal stability of a pure tungsten plate warm-rolled to a high plastic strain by 90% thickness reduction was investigated by isothermal annealing for up to 190 h in the temperature range between 1100 °C and 1250 °C. Vickers hardness testing allowed tracking the changes in mechanical properties caused by recovery and recrystallization. The hardness evolution could be rationalized in terms of a logarithmic recovery kinetics and a Johnson–Mehl–Avrami–Kolmogorov recrystallization kinetics accounting for an incubation time of recrystallization. The observed time spans for recrystallization and the corresponding recrystallization activation energy for this highly deformed plate suggest that large plastic deformations (e.g. applied during shaping) are only suitable to produce tungsten components to be used at relatively low temperatures (up to 900 °C for a 2 years lifespan). Higher operation temperatures will lead to fast degradation of the microstructure during operation.

  10. Study of elevated temperature design standard against thermal loads

    International Nuclear Information System (INIS)

    Kasahara, Naoto; Asayama, Tai; Morishita, Masaki

    2001-01-01

    Elevated temperature components must be designed against both pressure and thermal loads. In the case of sodium circuits of fast breeder reactors, a restriction from the pressure load becomes small because of the high boiling point of sodium. Design approaches for thermal loads (displacement-controlled) are compared with those against pressure loads (load-controlled). Considering differences between those two approaches, a concept of the elevated temperature design standard that takes the nature of thermal loads fully into account is proposed. This concept is a basis of load evaluation techniques and an inelastic analysis guide, that are being developed. Finally, problems and plans to realize the above concept are discussed. (author)

  11. Thermal contraction effects in epoxy resin composites at low temperatures

    International Nuclear Information System (INIS)

    Evans, D.; Morgan, J.T.

    1979-10-01

    Because of their electrical and thermal insulation characteristics, high strength fibreglass/epoxy composites are widely used in the construction of bubble chamber and other cryogenic equipment. Thermal contraction effects on cooling to operating temperature present problems which need to be taken into account at the design stage. This paper gives results of thermal contraction tests carried out on fibreglass/epoxy composites including the somewhat anomalous results obtained with rings and tubes. Also considered are some of the problems associated with the use of these materials at temperatures in the region of 20K. (author)

  12. The Development of an INL Capability for High Temperature Flow, Heat Transfer, and Thermal Energy Storage with Applications in Advanced Small Modular Reactors, High Temperature Heat Exchangers, Hybrid Energy Systems, and Dynamic Grid Energy Storage C

    International Nuclear Information System (INIS)

    Sun, Xiaodong; Zhang, Xiaoqin; Kim, Inhun; O'Brien, James; Sabharwall, Piyush

    2014-01-01

    The overall goal of this project is to support Idaho National Laboratory in developing a new advanced high temperature multi fluid multi loop test facility that is aimed at investigating fluid flow and heat transfer, material corrosion, heat exchanger characteristics and instrumentation performance, among others, for nuclear applications. Specifically, preliminary research has been performed at The Ohio State University in the following areas: 1. A review of fluoride molten salts' characteristics in thermal, corrosive, and compatibility performances. A recommendation for a salt selection is provided. Material candidates for both molten salt and helium flow loop have been identified. 2. A conceptual facility design that satisfies the multi loop (two coolant loops [i.e., fluoride molten salts and helium]) multi purpose (two operation modes [i.e., forced and natural circulation]) requirements. Schematic models are presented. The thermal hydraulic performances in a preliminary printed circuit heat exchanger (PCHE) design have been estimated. 3. An introduction of computational methods and models for pipe heat loss analysis and cases studies. Recommendations on insulation material selection have been provided. 4. An analysis of pipe pressure rating and sizing. Preliminary recommendations on pipe size selection have been provided. 5. A review of molten fluoride salt preparation and chemistry control. An introduction to the experience from the Molten Salt Reactor Experiment at Oak Ridge National Laboratory has been provided. 6. A review of some instruments and components to be used in the facility. Flowmeters and Grayloc connectors have been included. This report primarily presents the conclusions drawn from the extensive review of literatures in material selections and the facility design progress at the current stage. It provides some useful guidelines in insulation material and pipe size selection, as well as an introductory review of facility process and

  13. The Development of an INL Capability for High Temperature Flow, Heat Transfer, and Thermal Energy Storage with Applications in Advanced Small Modular Reactors, High Temperature Heat Exchangers, Hybrid Energy Systems, and Dynamic Grid Energy Storage C

    Energy Technology Data Exchange (ETDEWEB)

    Sun, Xiaodong [The Ohio State Univ., Columbus, OH (United States); Zhang, Xiaoqin [The Ohio State Univ., Columbus, OH (United States); Kim, Inhun [The Ohio State Univ., Columbus, OH (United States); O' Brien, James [Idaho National Lab. (INL), Idaho Falls, ID (United States); Sabharwall, Piyush [Idaho National Lab. (INL), Idaho Falls, ID (United States)

    2014-10-01

    The overall goal of this project is to support Idaho National Laboratory in developing a new advanced high temperature multi fluid multi loop test facility that is aimed at investigating fluid flow and heat transfer, material corrosion, heat exchanger characteristics and instrumentation performance, among others, for nuclear applications. Specifically, preliminary research has been performed at The Ohio State University in the following areas: 1. A review of fluoride molten salts’ characteristics in thermal, corrosive, and compatibility performances. A recommendation for a salt selection is provided. Material candidates for both molten salt and helium flow loop have been identified. 2. A conceptual facility design that satisfies the multi loop (two coolant loops [i.e., fluoride molten salts and helium]) multi purpose (two operation modes [i.e., forced and natural circulation]) requirements. Schematic models are presented. The thermal hydraulic performances in a preliminary printed circuit heat exchanger (PCHE) design have been estimated. 3. An introduction of computational methods and models for pipe heat loss analysis and cases studies. Recommendations on insulation material selection have been provided. 4. An analysis of pipe pressure rating and sizing. Preliminary recommendations on pipe size selection have been provided. 5. A review of molten fluoride salt preparation and chemistry control. An introduction to the experience from the Molten Salt Reactor Experiment at Oak Ridge National Laboratory has been provided. 6. A review of some instruments and components to be used in the facility. Flowmeters and Grayloc connectors have been included. This report primarily presents the conclusions drawn from the extensive review of literatures in material selections and the facility design progress at the current stage. It provides some useful guidelines in insulation material and pipe size selection, as well as an introductory review of facility process and components.

  14. A Lumped Thermal Model Including Thermal Coupling and Thermal Boundary Conditions for High Power IGBT Modules

    DEFF Research Database (Denmark)

    Bahman, Amir Sajjad; Ma, Ke; Blaabjerg, Frede

    2018-01-01

    Detailed thermal dynamics of high power IGBT modules are important information for the reliability analysis and thermal design of power electronic systems. However, the existing thermal models have their limits to correctly predict these complicated thermal behavior in the IGBTs: The typically used...... thermal model based on one-dimensional RC lumps have limits to provide temperature distributions inside the device, moreover some variable factors in the real-field applications like the cooling and heating conditions of the converter cannot be adapted. On the other hand, the more advanced three......-dimensional thermal models based on Finite Element Method (FEM) need massive computations, which make the long-term thermal dynamics difficult to calculate. In this paper, a new lumped three-dimensional thermal model is proposed, which can be easily characterized from FEM simulations and can acquire the critical...

  15. Thermal annealing of high dose radiation induced damage at room temperature in alkaline. Stored energy, thermoluminescence and coloration

    International Nuclear Information System (INIS)

    Delgado, L.

    1980-01-01

    The possible relation between stored energy, thermoluminescence and colour centre annealing in gamma and electron irradiated alkali halides is studied. Thermoluminescence occurs at temperature higher than the temperature at which the main stored energy peak appears. No stored energy release is detected in additively coloured KC1 samples. Plastic deformation and doping with Ca and Sr induce a stored energy spectrum different from the spectrum observed in pure and as cleaved samples, but the amount of stored energy does not change for a given irradiation dose.Capacity of alkali halides to store energy by irradiation increases as the cation size decreases. (Author) 51 refs

  16. Thermal expansion behavior of empressite, AgTe: A structural study by means of in situ high-temperature single-crystal X-ray diffraction

    International Nuclear Information System (INIS)

    Bindi, Luca

    2009-01-01

    The crystal structure of empressite, AgTe, a rare silver telluride, has been investigated by in situ X-ray single-crystal diffraction methods within the temperature range 298-463 K. AgTe remains orthorhombic, space group Pmnb (Pnma as standard), and shows only normal thermal expansion over the entire temperature range. The unit-cell parameters show a gradual increase with the increase of temperature. Slight adjustments in the geometry of Ag-tetrahedra and in the crystal-chemical environment of tellurium atoms occur in a continuous way without abrupt structural changes. The coefficients of thermal expansion along various axes are: α a = 1.5 x 10 -5 K -1 , α b = 3.0 x 10 -5 K -1 , α c = 2.2 x 10 -5 K -1 , and the bulk thermal expansion coefficient α V is 5.4 x 10 -5 K -1 for the temperature range 298-463 K

  17. High temperature materials; Materiaux a hautes temperatures

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    2003-07-01

    The aim of this workshop is to share the needs of high temperature and nuclear fuel materials for future nuclear systems, to take stock of the status of researches in this domain and to propose some cooperation works between the different research organisations. The future nuclear systems are the very high temperature (850 to 1200 deg. C) gas cooled reactors (GCR) and the molten salt reactors (MSR). These systems include not only the reactor but also the fabrication and reprocessing of the spent fuel. This document brings together the transparencies of 13 communications among the 25 given at the workshop: 1) characteristics and needs of future systems: specifications, materials and fuel needs for fast spectrum GCR and very high temperature GCR; 2) high temperature materials out of neutron flux: thermal barriers: materials, resistance, lifetimes; nickel-base metal alloys: status of knowledge, mechanical behaviour, possible applications; corrosion linked with the gas coolant: knowledge and problems to be solved; super-alloys for turbines: alloys for blades and discs; corrosion linked with MSR: knowledge and problems to be solved; 3) materials for reactor core structure: nuclear graphite and carbon; fuel assembly structure materials of the GCR with fast neutron spectrum: status of knowledge and ceramics and cermets needs; silicon carbide as fuel confinement material, study of irradiation induced defects; migration of fission products, I and Cs in SiC; 4) materials for hydrogen production: status of the knowledge and needs for the thermochemical cycle; 5) technologies: GCR components and the associated material needs: compact exchangers, pumps, turbines; MSR components: valves, exchangers, pumps. (J.S.)

  18. Thermal annealing of high dose radiation induced damage at room temperature in alkali halides. Stored energy, thermoluminiscence and colouration

    International Nuclear Information System (INIS)

    Delgado, L.

    1980-01-01

    The possible relation between stored energy, thermoluminiscence and colour centre annealing in gamma and electron irradiated alkali halides is studied. Thermoluminiscence occurs at temperature higher than the temperature at which the main stored energy peak appears. No stored energy release is detected in additively coloured KCl samples. Plastic deformation and doping with Ca and Sr induce a stored energy spectrum different from the spectrum observed in pure and as cleaved samples, but the amount of stored energy does not change for a given irradiation dose. Capacity of alkali halides to sotore energy by irradiation increases as the cation size decreases. It appears that most of the observed release is not related to annealing processes of the radiation induced anion Frenkel pairs. The existence of damage in the cation sublattice with which this energy release might be related is considered. (auth.)

  19. Compton scattering at finite temperature: thermal field dynamics approach

    International Nuclear Information System (INIS)

    Juraev, F.I.

    2006-01-01

    Full text: Compton scattering is a classical problem of quantum electrodynamics and has been studied in its early beginnings. Perturbation theory and Feynman diagram technique enables comprehensive analysis of this problem on the basis of which famous Klein-Nishina formula is obtained [1, 2]. In this work this problem is extended to the case of finite temperature. Finite-temperature effects in Compton scattering is of practical importance for various processes in relativistic thermal plasmas in astrophysics. Recently Compton effect have been explored using closed-time path formalism with temperature corrections estimated [3]. It was found that the thermal cross section can be larger than that for zero-temperature by several orders of magnitude for the high temperature realistic in astrophysics [3]. In our work we use a main tool to account finite-temperature effects, a real-time finite-temperature quantum field theory, so-called thermofield dynamics [4, 5]. Thermofield dynamics is a canonical formalism to explore field-theoretical processes at finite temperature. It consists of two steps, doubling of Fock space and Bogolyubov transformations. Doubling leads to appearing additional degrees of freedom, called tilded operators which together with usual field operators create so-called thermal doublet. Bogolyubov transformations make field operators temperature-dependent. Using this formalism we treat Compton scattering at finite temperature via replacing in transition amplitude zero-temperature propagators by finite-temperature ones. As a result finite-temperature extension of the Klein-Nishina formula is obtained in which differential cross section is represented as a sum of zero-temperature cross section and finite-temperature correction. The obtained result could be useful in quantum electrodynamics of lasers and for relativistic thermal plasma processes in astrophysics where correct account of finite-temperature effects is important. (author)

  20. Measuring Thermal Conductivity at LH2 Temperatures

    Science.gov (United States)

    Selvidge, Shawn; Watwood, Michael C.

    2004-01-01

    For many years, the National Institute of Standards and Technology (NIST) produced reference materials for materials testing. One such reference material was intended for use with a guarded hot plate apparatus designed to meet the requirements of ASTM C177-97, "Standard Test Method for Steady-State Heat Flux Measurements and Thermal Transmission Properties by Means of the Guarded-Hot-Plate Apparatus." This apparatus can be used to test materials in various gaseous environments from atmospheric pressure to a vacuum. It allows the thermal transmission properties of insulating materials to be measured from just above ambient temperature down to temperatures below liquid hydrogen. However, NIST did not generate data below 77 K temperature for the reference material in question. This paper describes a test method used at NASA's Marshall Space Flight Center (MSFC) to optimize thermal conductivity measurements during the development of thermal protection systems. The test method extends the usability range of this reference material by generating data at temperatures lower than 77 K. Information provided by this test is discussed, as are the capabilities of the MSFC Hydrogen Test Facility, where advanced methods for materials testing are routinely developed and optimized in support of aerospace applications.

  1. Thermal effects from the release of selenium from a coal combustion during high-temperature processing: a review.

    Science.gov (United States)

    Hu, Jianjun; Sun, Qiang; He, Huan

    2018-04-11

    The release of selenium (Se) during coal combustion can have serious impacts on the ecological environment and human health. Therefore, it is very important to study the factors that concern the release of Se from coal combustion. In this paper, the characteristics of the release of Se from coal combustion, pyrolysis, and gasification of different coal species under different conditions are studied. The results show that the amount of released Se increases at higher combustion temperatures. There are obvious increases in the amount of released Se especially in the temperature range of 300 to 800 °C. In addition, more Se is released from the coal gasification than coal combustion process, but more Se is released from coal combustion than pyrolysis. The type of coal, rate of heating, type of mineral ions, and combustion atmosphere have different effects on the released percentage of Se. Therefore, having a good understanding of the factors that surround the release of Se during coal combustion, and then establishing the combustion conditions can reduce the impacts of this toxic element to humans and the environment.

  2. Effect of heat source shape on the thermal field in the pebble bed core of High Temperature Gas-cooled Reactor (HTGR)

    Energy Technology Data Exchange (ETDEWEB)

    Chen, Leisheng; Lee, Jaeyoung [Handong Global University, Pohang (Korea, Republic of)

    2015-10-15

    In this study, in order to minimize the error brought by non-uniform heat flux, the spherical heaters are employed as heat source; subsequently, thermal field and heat transfer characteristics of the pebbles are investigated. The thermal field of the pebble surface in PBR is measured with heat source in different shapes. The HTGR design concept exhibits excellent safety features due to the low power density and the large amount of graphite present in the core which gives a large thermal inertia in an accident such as loss of coolant. However, the possible appearance of hot spots in the pebble bed cores of HTGR may affect the integrity of the pebbles, which has drawn the attention of many scientists to investigate the thermal field and to predict the maximum temperature locations in the pebbles using CFD method, Lee et.al has also done some experimental work on measuring the surface temperature of the pebbles as well as visualizing flow patterns of the coolant gas, and it was found that the temperature near the contacting points between pebbles was not higher than the flow stagnation points due to the higher thermal conductivity of the pebble. Certain error of temperature measurement might occur because of not very uniform heat flux in the pebbles since heater in cylindrical shape was utilized as heat source in previous experiment. More uniform heat flux and more complicated thermal profile are found in the result obtained using spherical heaters. The result shows that the temperature in contact point is higher than that in the top point, which is different from the previous results. The complex thermal phenomena observed in the lower-half side-sphere can be explained by the flow pattern near the surface.

  3. Low Conductive Thermal Barrier Coatings Produced by Ion Beam Assisted EB-PVD with Controlled Porosity, Microstructure Refinement and Alloying Additions for High Temperature Applications

    Science.gov (United States)

    Wolfe, Douglas E.; Singh, Jogender

    2005-01-01

    Various advanced Hafnia-based thermal barrier coatings (TBC) were applied on nickel-based superalloy coupons by electron beam physical vapor deposition. In addition, microstructural modifications to the coating material were made in an effort to reduce the thermal conductivity of the coating materials. Various processing parameters and coating system modifications were made in order to deposit the alloyed TBC with the desired microstructure and thus coating performance, some of which include applying coatings at substrate temperatures of 1150 C on both PtAl and CoNiCrAlY bond coated samples, as well as using 8YSZ as a bond layer. In addition, various characterization techniques including thermal cyclic tests, scanning electron microscopy, x-ray diffraction, thermal conductivity, and reflectivity measurements were performed. Although the coating microstructure was never fully optimized due to funding being cut short, significant reductions in thermal conductivity were accomplished through both chemistry changes (composition) and microstructural modifications.

  4. High temperature structural silicides

    International Nuclear Information System (INIS)

    Petrovic, J.J.

    1997-01-01

    Structural silicides have important high temperature applications in oxidizing and aggressive environments. Most prominent are MoSi 2 -based materials, which are borderline ceramic-intermetallic compounds. MoSi 2 single crystals exhibit macroscopic compressive ductility at temperatures below room temperature in some orientations. Polycrystalline MoSi 2 possesses elevated temperature creep behavior which is highly sensitive to grain size. MoSi 2 -Si 3 N 4 composites show an important combination of oxidation resistance, creep resistance, and low temperature fracture toughness. Current potential applications of MoSi 2 -based materials include furnace heating elements, molten metal lances, industrial gas burners, aerospace turbine engine components, diesel engine glow plugs, and materials for glass processing

  5. Evidence for tectonic, lithologic, and thermal controls on fracture system geometries in an andesitic high-temperature geothermal field

    Science.gov (United States)

    Massiot, Cécile; Nicol, Andrew; McNamara, David D.; Townend, John

    2017-08-01

    Analysis of fracture orientation, spacing, and thickness from acoustic borehole televiewer (BHTV) logs and cores in the andesite-hosted Rotokawa geothermal reservoir (New Zealand) highlights potential controls on the geometry of the fracture system. Cluster analysis of fracture orientations indicates four fracture sets. Probability distributions of fracture spacing and thickness measured on BHTV logs are estimated for each fracture set, using maximum likelihood estimations applied to truncated size distributions to account for sampling bias. Fracture spacing is dominantly lognormal, though two subordinate fracture sets have a power law spacing. This difference in spacing distributions may reflect the influence of the andesitic sequence stratification (lognormal) and tectonic faults (power law). Fracture thicknesses of 9-30 mm observed in BHTV logs, and 1-3 mm in cores, are interpreted to follow a power law. Fractures in thin sections (˜5 μm thick) do not fit this power law distribution, which, together with their orientation, reflect a change of controls on fracture thickness from uniform (such as thermal) controls at thin section scale to anisotropic (tectonic) at core and BHTV scales of observation. However, the ˜5% volumetric percentage of fractures within the rock at all three scales suggests a self-similar behavior in 3-D. Power law thickness distributions potentially associated with power law fluid flow rates, and increased connectivity where fracture sets intersect, may cause the large permeability variations that occur at hundred meter scales in the reservoir. The described fracture geometries can be incorporated into fracture and flow models to explore the roles of fracture connectivity, stress, and mineral precipitation/dissolution on permeability in such andesite-hosted geothermal systems.

  6. Crystal structure and thermal expansion of the low- and high-temperature forms of Ba MIV(PO 4) 2 compounds ( M=Ti, Zr, Hf and Sn)

    Science.gov (United States)

    Bregiroux, D.; Popa, K.; Jardin, R.; Raison, P. E.; Wallez, G.; Quarton, M.; Brunelli, M.; Ferrero, C.; Caciuffo, R.

    2009-05-01

    The crystal structure of β-BaZr(PO 4) 2, archetype of the high-temperature forms of Ba M(PO 4) 2 phosphates (with M=Ti, Zr, Hf and Sn), has been solved ab initio by Rietveld analysis from synchrotron X-ray powder diffraction data. The phase transition appears as a topotactic modification of the monoclinic (S.G. C2/m) lamellar α-structure into a trigonal one (S.G. P3¯m1) through a simple mechanism involving the unfolding of the [Zr)]n2- layers. The thermal expansion is very anisotropic (e.g., -4.1< α i<34.0×10 -6 K -1 in the case of α-BaZr(PO 4) 2) and quite different in the two forms, as a consequence of symmetry. It stems from a complex combination of several mechanisms, involving bridging oxygen rocking in M-O-P linkages, and "bond thermal expansion".

  7. Computational thermal-fluid dynamics analysis of the laminar flow regime in the meander flow geometry characterizing the heat exchanger used in high temperature superconducting current leads

    International Nuclear Information System (INIS)

    Rizzo, Enrico; Heller, Reinhard; Richard, Laura Savoldi; Zanino, Roberto

    2013-01-01

    Highlights: • The laminar regime in the meander flow geometry has been analysed with a previously validated computational strategy. • Several meander flow geometries as well as flow conditions have been analysed. • A range for the Reynolds number has been defined in which the flow can be considered laminar. • Correlations for the pressure drop and the heat transfer coefficients in the laminar regime have been derived. • A comparison between the computed the experimental pressure drop of the W7-X HTS current lead prototype is presented. -- Abstract: The Karlsruhe Institute of Technology and the Politecnico di Torino have developed and validated a computational thermal-fluid dynamics (CtFD) strategy for the systematic analysis of the thermal-hydraulics inside the meander flow heat exchanger used in high-temperature superconducting current leads for fusion applications. In the recent past, the application of this CtFD technique has shown that some operating conditions occurring in these devices may not reach the turbulent regime region. With that motivation, the CtFD analysis of the helium thermal-fluid dynamics inside different meander flow geometries is extended here to the laminar flow regime. Our first aim is to clarify under which operative conditions the flow regime can be considered laminar and how the pressure drop as well as the heat transfer are related to the geometrical parameters and to the flow conditions. From the results of this analysis, correlations for the pressure drop and for the heat transfer coefficient in the meander flow geometry have been derived, which are applicable with good accuracy to the design of meander flow heat exchangers over a broad range of geometrical parameters

  8. Computational thermal-fluid dynamics analysis of the laminar flow regime in the meander flow geometry characterizing the heat exchanger used in high temperature superconducting current leads

    Energy Technology Data Exchange (ETDEWEB)

    Rizzo, Enrico, E-mail: enrico.rizzo@kit.edu [Institute for Technical Physics, Karlsruhe Institute of Technology, 76021 Karlsruhe (Germany); Heller, Reinhard [Institute for Technical Physics, Karlsruhe Institute of Technology, 76021 Karlsruhe (Germany); Richard, Laura Savoldi; Zanino, Roberto [Dipartimento Energia, Politecnico di Torino, 10129 Torino (Italy)

    2013-11-15

    Highlights: • The laminar regime in the meander flow geometry has been analysed with a previously validated computational strategy. • Several meander flow geometries as well as flow conditions have been analysed. • A range for the Reynolds number has been defined in which the flow can be considered laminar. • Correlations for the pressure drop and the heat transfer coefficients in the laminar regime have been derived. • A comparison between the computed the experimental pressure drop of the W7-X HTS current lead prototype is presented. -- Abstract: The Karlsruhe Institute of Technology and the Politecnico di Torino have developed and validated a computational thermal-fluid dynamics (CtFD) strategy for the systematic analysis of the thermal-hydraulics inside the meander flow heat exchanger used in high-temperature superconducting current leads for fusion applications. In the recent past, the application of this CtFD technique has shown that some operating conditions occurring in these devices may not reach the turbulent regime region. With that motivation, the CtFD analysis of the helium thermal-fluid dynamics inside different meander flow geometries is extended here to the laminar flow regime. Our first aim is to clarify under which operative conditions the flow regime can be considered laminar and how the pressure drop as well as the heat transfer are related to the geometrical parameters and to the flow conditions. From the results of this analysis, correlations for the pressure drop and for the heat transfer coefficient in the meander flow geometry have been derived, which are applicable with good accuracy to the design of meander flow heat exchangers over a broad range of geometrical parameters.

  9. Thermal oxidation induced degradation of carbon fiber reinforced composites and carbon nanotube sheet enhanced fiber/matrix interface for high temperature aerospace structural applications

    Science.gov (United States)

    Haque, Mohammad Hamidul

    Recent increase in the use of carbon fiber reinforced polymer matrix composite, especially for high temperature applications in aerospace primary and secondary structures along with wind energy and automotive industries, have generated new challenges to predict its failure mechanisms and service life. This dissertation reports the experimental study of a unidirectional carbon fiber reinforced bismaleimide (BMI) composites (CFRC), an excellent candidate for high temperature aerospace components, undergoing thermal oxidation at 260 °C in air for over 3000 hours. The key focus of the work is to investigate the mechanical properties of the carbon fiber BMI composite subjected to thermal aging in three key aspects - first, studying its bulk flexural properties (in macro scale), second, characterizing the crack propagation along the fiber direction, representing the interfacial bonding strength between fiber and matrix (in micro scale), and third, introducing nano-structured materials to modify the interface (in nano scale) between the carbon fiber and BMI resin and mechanical characterization to study its influence on mitigating the aging effect. Under the first category, weight loss and flexural properties have been monitored as the oxidation propagates through the fiber/matrix interface. Dynamic mechanical analysis and micro-computed tomography analysis have been performed to analyze the aging effects. In the second category, the long-term effects of thermal oxidation on the delamination (between the composite plies) and debonding (between fiber and matrix) type fracture toughness have been characterized by preparing two distinct types of double cantilever beam specimens. Digital image correlation has been used to determine the deformation field and strain distribution around the crack propagation path. Finally the resin system and the fiber/matrix interface have been modified using nanomaterials to mitigate the degradations caused by oxidation. Nanoclay modified

  10. Temperature dependence of thermal pressure for NaCl

    Science.gov (United States)

    Singh, Chandra K.; Pande, Brijesh K.; Pandey, Anjani K.

    2018-05-01

    Engineering applications of the materials can be explored upto the desired limit of accuracy with the better knowledge of its mechanical and thermal properties such as ductility, brittleness and Thermal Pressure. For the resistance to fracture (K) and plastic deformation (G) the ratio K/G is treated as an indication of ductile or brittle character of solids. In the present work we have tested the condition of ductility and brittleness with the calculated values of K/G for the NaCl. It is concluded that the nature of NaCl can be predicted upto high temperature simply with the knowledge of its elastic stiffness constant only. Thermoelastic properties of materials at high temperature is directly related to thermal pressure and volume expansion of the materials. An expression for the temperature dependence of thermal pressure is formulated using basic thermodynamic identities. It is observed that thermal pressure ΔPth calculated for NaCl by using Kushwah formulation is in good agreement with the experimental values also the thermal pressure increases with the increase in temperature.

  11. Thermal geometry from CFT at finite temperature

    Directory of Open Access Journals (Sweden)

    Wen-Cong Gan

    2016-09-01

    Full Text Available We present how the thermal geometry emerges from CFT at finite temperature by using the truncated entanglement renormalization network, the cMERA. For the case of 2d CFT, the reduced geometry is the BTZ black hole or the thermal AdS as expectation. In order to determine which spacetimes prefer to form, we propose a cMERA description of the Hawking–Page phase transition. Our proposal is in agreement with the picture of the recent proposed surface/state correspondence.

  12. Thermal geometry from CFT at finite temperature

    Energy Technology Data Exchange (ETDEWEB)

    Gan, Wen-Cong, E-mail: ganwencong@gmail.com [Department of Physics, Nanchang University, Nanchang 330031 (China); Center for Relativistic Astrophysics and High Energy Physics, Nanchang University, Nanchang 330031 (China); Shu, Fu-Wen, E-mail: shufuwen@ncu.edu.cn [Department of Physics, Nanchang University, Nanchang 330031 (China); Center for Relativistic Astrophysics and High Energy Physics, Nanchang University, Nanchang 330031 (China); Wu, Meng-He, E-mail: menghewu.physik@gmail.com [Department of Physics, Nanchang University, Nanchang 330031 (China); Center for Relativistic Astrophysics and High Energy Physics, Nanchang University, Nanchang 330031 (China)

    2016-09-10

    We present how the thermal geometry emerges from CFT at finite temperature by using the truncated entanglement renormalization network, the cMERA. For the case of 2d CFT, the reduced geometry is the BTZ black hole or the thermal AdS as expectation. In order to determine which spacetimes prefer to form, we propose a cMERA description of the Hawking–Page phase transition. Our proposal is in agreement with the picture of the recent proposed surface/state correspondence.

  13. The application of thermal solar energy to high temperature processes: case study of the synthesis of alumina from boehmite.

    Science.gov (United States)

    Padilla, Isabel; López-Delgado, Aurora; López-Andrés, Sol; Álvarez, Marta; Galindo, Roberto; Vazquez-Vaamonde, Alfonso J

    2014-01-01

    The aim of this paper is to evaluate the feasibility of obtaining alumina from boehmite using a free, clean, and unlimited power source as the solar energy. Boehmite was obtained by hydrothermal treatment of a hazardous waste coming from aluminum slag milling. The waste is considered as a hazardous substance because of it releasing toxic gases (hydrogen, ammonia, methane, and hydrogen sulfide) in the presence of water. The as-obtained boehmite was transformed into alumina, in air atmosphere, using a solar energy concentrator (Fresnel lens). The solar installation provides a power density of 260 W · cm(-2) which allows reaching temperatures upper than 1000 °C at few minutes of exposure. Tests were performed at different periods of time that ranged between 5 and 90 min. The percentage of transformation of boehmite into alumina was followed by the water content of samples after solar radiation exposure. Samples were characterized by X-ray diffraction, infrared spectroscopy, and thermogravimetry. Metastable aluminas started to appear at 5 min and the crystalline and stable phase corundum at 10 min of solar radiation exposure.

  14. The Application of Thermal Solar Energy to High Temperature Processes: Case Study of the Synthesis of Alumina from Boehmite

    Directory of Open Access Journals (Sweden)

    Isabel Padilla

    2014-01-01

    Full Text Available The aim of this paper is to evaluate the feasibility of obtaining alumina from boehmite using a free, clean, and unlimited power source as the solar energy. Boehmite was obtained by hydrothermal treatment of a hazardous waste coming from aluminum slag milling. The waste is considered as a hazardous substance because of it releasing toxic gases (hydrogen, ammonia, methane, and hydrogen sulfide in the presence of water. The as-obtained boehmite was transformed into alumina, in air atmosphere, using a solar energy concentrator (Fresnel lens. The solar installation provides a power density of 260 W·cm−2 which allows reaching temperatures upper than 1000°C at few minutes of exposure. Tests were performed at different periods of time that ranged between 5 and 90 min. The percentage of transformation of boehmite into alumina was followed by the water content of samples after solar radiation exposure. Samples were characterized by X-ray diffraction, infrared spectroscopy, and thermogravimetry. Metastable aluminas started to appear at 5 min and the crystalline and stable phase corundum at 10 min of solar radiation exposure.

  15. High Thermal Conductivity Composite Structures

    National Research Council Canada - National Science Library

    Bootle, John

    1999-01-01

    ... applications and space based radiators. The advantage of this material compared to competing materials that it can be used to fabricate high strength, high thermal conductivity, relatively thin structures less than 0.050" thick...

  16. Temperature and thermal stress analysis of a switching tube anode

    International Nuclear Information System (INIS)

    Sutton, S.B.

    1979-01-01

    In the design of high power density switching tubes which are subjected to cyclic thermal loads, the temperature induced stresses must be minimized in order to maximize the life expectancy of the tube. Following are details of an analysis performed for the Magnetic Fusion Program at the Lawrence Livermore Laboratory on a proposed tube. The tube configuration is given. The problem was simplified to one-dimensional approximations for both the thermal and stress analyses. The underlying assumptions and their implications are discussed

  17. Comparison of the Organic Flash Cycle (OFC) to other advanced vapor cycles for intermediate and high temperature waste heat reclamation and solar thermal energy

    International Nuclear Information System (INIS)

    Ho, Tony; Mao, Samuel S.; Greif, Ralph

    2012-01-01

    The Organic Flash Cycle (OFC) is proposed as a vapor power cycle that could potentially improve the efficiency with which high and intermediate temperature finite thermal sources are utilized. The OFC's aim is to improve temperature matching and reduce exergy losses during heat addition. A theoretical investigation is conducted using high accuracy equations of state such as BACKONE, Span–Wagner, and REFPROP in a detailed thermodynamic and exergetic analysis. The study examines 10 different aromatic hydrocarbons and siloxanes as potential working fluids. Comparisons are drawn between the OFC and an optimized basic Organic Rankine Cycle (ORC), a zeotropic Rankine cycle using a binary ammonia-water mixture, and a transcritical CO 2 cycle. Results showed aromatic hydrocarbons to be the better suited working fluid for the ORC and OFC due to higher power output and less complex turbine designs. Results also showed that the single flash OFC achieves comparable utilization efficiencies to the optimized basic ORC. Although the OFC improved heat addition exergetic efficiency, this advantage was negated by irreversibilities introduced during flash evaporation. A number of potentially significant improvements to the OFC are possible though which includes using a secondary flash stage or replacing the throttling valve with a two-phase expander. -- Highlights: ► The Organic Flash Cycle (OFC) is proposed to improve temperature matching. ► Ten aromatic hydrocarbon and siloxane working fluids are considered. ► Accurate equations of state explicit in Helmholtz energy are used in the analysis. ► The OFC is compared to basic ORCs, zeotropic, and transcritical cycles. ► The OFC achieves comparable power output to the optimized basic ORC.

  18. High-Temperature Oxidation-Resistant and Low Coefficient of Thermal Expansion NiAl-Base Bond Coat Developed for a Turbine Blade Application

    Science.gov (United States)

    2003-01-01

    Many critical gas turbine engine components are currently made from Ni-base superalloys that are coated with a thermal barrier coating (TBC). The TBC consists of a ZrO2-based top coat and a bond coat that is used to enhance the bonding between the superalloy substrate and the top coat. MCrAlY alloys (CoCrAlY and NiCrAlY) are currently used as bond coats and are chosen for their very good oxidation resistance. TBC life is frequently limited by the oxidation resistance of the bond coat, along with a thermal expansion mismatch between the metallic bond coat and the ceramic top coat. The aim of this investigation at the NASA Glenn Research Center was to develop a new longer life, higher temperature bond coat by improving both the oxidation resistance and the thermal expansion characteristics of the bond coat. Nickel aluminide (NiAl) has excellent high-temperature oxidation resistance and can sustain a protective Al2O3 scale to longer times and higher temperatures in comparison to MCrAlY alloys. Cryomilling of NiAl results in aluminum nitride (AlN) formation that reduces the coefficient of thermal expansion (CTE) of the alloy and enhances creep strength. Thus, additions of cryomilled NiAl-AlN to CoCrAlY were examined as a potential bond coat. In this work, the composite alloy was investigated as a stand-alone substrate to demonstrate its feasibility prior to actual use as a coating. About 85 percent of prealloyed NiAl and 15 percent of standard commercial CoCrAlY alloys were mixed and cryomilled in an attritor with stainless steel balls used as grinding media. The milling was carried out in the presence of liquid nitrogen. The milled powder was consolidated by hot extrusion or by hot isostatic pressing. From the consolidated material, oxidation coupons, four-point bend, CTE, and tensile specimens were machined. The CTE measurements were made between room temperature and 1000 C in an argon atmosphere. It is shown that the CTE of the NiAl-AlN-CoCrAlY composite bond coat

  19. Thermal characteristics of highly compressed bentonite

    International Nuclear Information System (INIS)

    Sueoka, Tooru; Kobayashi, Atsushi; Imamura, S.; Ogawa, Terushige; Murata, Shigemi.

    1990-01-01

    In the disposal of high level radioactive wastes in strata, it is planned to protect the canisters enclosing wastes with buffer materials such as overpacks and clay, therefore, the examination of artificial barrier materials is an important problem. The concept of the disposal in strata and the soil mechanics characteristics of highly compressed bentonite as an artificial barrier material were already reported. In this study, the basic experiment on the thermal characteristics of highly compressed bentonite was carried out, therefore, it is reported. The thermal conductivity of buffer materials is important because the possibility that it determines the temperature of solidified bodies and canisters is high, and the buffer materials may cause the thermal degeneration due to high temperature. Thermophysical properties are roughly divided into thermodynamic property, transport property and optical property. The basic principle of measured thermal conductivity and thermal diffusivity, the kinds of the measuring method and so on are explained. As for the measurement of the thermal conductivity of highly compressed bentonite, the experimental setup, the procedure, samples and the results are reported. (K.I.)

  20. High temperature reaction kinetics

    International Nuclear Information System (INIS)

    Jonah, C.D.; Beno, M.F.; Mulac, W.A.; Bartels, D.

    1985-01-01

    During the last year the dependence of the apparent rate of OD + CO on water pressure was measured at 305, 570, 865 and 1223 K. An explanation was found and tested for the H 2 O dependence of the apparent rate of OH(OD) + CO at high temperatures. The isotope effect for OH(D) with CO was determined over the temperature range 330 K to 1225 K. The reason for the water dependence of the rate of OH(OD) + CO near room temperatures has been investigated but no clear explanation has been found. 1 figure

  1. High-temperature superconductivity

    International Nuclear Information System (INIS)

    Ginzburg, V.L.

    1987-07-01

    After a short account of the history of experimental studies on superconductivity, the microscopic theory of superconductivity, the calculation of the control temperature and its possible maximum value are presented. An explanation of the mechanism of superconductivity in recently discovered superconducting metal oxide ceramics and the perspectives for the realization of new high-temperature superconducting materials are discussed. 56 refs, 2 figs, 3 tabs

  2. High Temperature Transparent Furnace Development

    Science.gov (United States)

    Bates, Stephen C.

    1997-01-01

    This report describes the use of novel techniques for heat containment that could be used to build a high temperature transparent furnace. The primary objective of the work was to experimentally demonstrate transparent furnace operation at 1200 C. Secondary objectives were to understand furnace operation and furnace component specification to enable the design and construction of a low power prototype furnace for delivery to NASA in a follow-up project. The basic approach of the research was to couple high temperature component design with simple concept demonstration experiments that modify a commercially available transparent furnace rated at lower temperature. A detailed energy balance of the operating transparent furnace was performed, calculating heat losses through the furnace components as a result of conduction, radiation, and convection. The transparent furnace shells and furnace components were redesigned to permit furnace operation at at least 1200 C. Techniques were developed that are expected to lead to significantly improved heat containment compared with current transparent furnaces. The design of a thermal profile in a multizone high temperature transparent furnace design was also addressed. Experiments were performed to verify the energy balance analysis, to demonstrate some of the major furnace improvement techniques developed, and to demonstrate the overall feasibility of a high temperature transparent furnace. The important objective of the research was achieved: to demonstrate the feasibility of operating a transparent furnace at 1200 C.

  3. Dense high-temperature plasma transport processes

    International Nuclear Information System (INIS)

    Giniyatova, Sh.G.

    2002-01-01

    In this work the transport processes in dense high-temperature semiclassical plasma are studied on the base of the kinetic equation, where the semiclassical potential was used, in its collision integral. The coefficient of plasma electrical conductivity, viscosity and thermal conductivity were received. There were compared with the other authors' results. The Grad's method was used obtaining of viscosity and thermal coefficients. (author)

  4. SCC growth behavior of cast stainless steels in high-temperature water. Influences of corrosion potential, steel type, thermal aging and cold-work

    International Nuclear Information System (INIS)

    Yamada, Takuyo; Terachi, Takumi; Miyamoto, Tomoki; Arioka, Koji

    2011-01-01

    Recent studies on crack growth rate (CGR) measurement in oxygenated high-temperature pure water conditions, such as normal water chemistry (NWC) in BWRs, using compact tension (CT) type specimens have shown that stainless steel weld metal are susceptible to stress corrosion cracking (SCC). On the other hand, the authors reported that no significant SCC growth was observed on stainless steel weld metals in PWR primary water at temperatures from 250degC to 340degC. Cast austenitic stainless steels are widely used in light water reactors, and there is a similarity between welded and cast stainless steels in terms of the microstructure of the ferrite/austenite duplex structure. However, there are a few reports giving CGR data on cast stainless steels in the BWRs and PWRs. The principal purpose of this study was to examine the SCC growth behavior of cast stainless steels in simulated PWR primary water. A second objective was to examine the effects on SCC growth in hydrogenated and oxygenated water environments at 320degC of: (1) corrosion potential; (2) steels type (Mo in alloy); (3) thermal-aging (up to 400degC x 40 kh); and (4) cold-working (10%). The results were as follows: (1) No significant SCC growth was observed on all types of cast stainless steels: aged (400degC x 40 kh) of SCS14A and SCS13A and 10% cold-working, in hydrogenated (low-potential) water at 320degC. (2) Aging at 400degC x 40 kh SCS14A (10%CW) markedly accelerated the SCC growth of cast material in high-potential water at 320degC, but no significant SCC growth was observed in the hydrogenated water, even after long-term thermal aging (400degC x 40 kh). (3) Thus, cast stainless steels have excellent SCC resistance in PWR primary water. (4) On the other hand, significant SCC growth was observed on all types of cast stainless steels: 10%CW SCS14A and SCS13A, in 8 ppm-oxygenated (high-potential) water at 320degC. (5) No large difference in SCC growth was observed between SCS14A (Mo) and SCS13A. (6) No

  5. Thermal conductivity measurements at cryogenic temperatures at LASA

    International Nuclear Information System (INIS)

    Broggi, F.; Pedrini, D.; Rossi, L.

    1995-08-01

    Here the improvement realised to have better control of the reference junction temperature and measurements carried out on Nb 3 Sn cut out from 2 different coils (named LASA3 and LASA5), showing the difference between the longitudinal and the transverse thermal conductivity, is described. Two different methods of data analysis are presented, the DAM (derivative approximated method) and the TCI (thermal conductivity integral. The data analysis for the tungsten and the LASA5 coil has been done according to the two methods showing that the TCI method with polynomial functions is not adequate to describe the thermal conductivity. Only a polynomial fit based on the TCI method but limited at a lower order than the nominal, when the data are well distributed along the range of measurements, can describe reasonably the thermal conductivity dependence with the temperature. Finally the measurements on a rod of BSCCO 2212 high T c superconductor are presented

  6. 1-D thermal-hydraulic analysis of the high temperature superconducting current leads for the ITER magnet system from 5 K to 300 K

    Energy Technology Data Exchange (ETDEWEB)

    Rizzo, Enrico, E-mail: enrico.rizzo@kit.edu [Institute for Technical Physics, Karlsruhe Institute of Technology, 76344 Eggenstein-Leopoldshafen (Germany); Bauer, Pierre [ITER Organization, Cadarache (France); Heller, Reinhard [Institute for Technical Physics, Karlsruhe Institute of Technology, 76344 Eggenstein-Leopoldshafen (Germany); Richard, Laura Savoldi; Zanino, Roberto [Dipartimento Energia, Politecnico di Torino, 10129 Torino (Italy)

    2013-12-15

    Highlights: • A global, predictive picture of the ITER HTS current lead is not yet available. • A predictive 1-D, steady state thermal-hydraulic analysis of the full length HTS current leads has been performed. • For the heat exchanger, correlations previously derived by the same authors have been used. • The results have been compared with the ITER relevant requirements. • According to our results, the ITER HTS current leads will fulfill the requirements. -- Abstract: The magnet system of ITER includes high temperature superconducting (HTS) current leads with a maximum current of 68 kA for the toroidal field (TF) coils, 55 kA for the poloidal field (PF)/central solenoid (CS) coils and 10 kA for the control coils (CC), respectively. Although different in terms of size and operative conditions, the ITER HTS current leads have been all designed on the basis of an established concept, which was successfully developed for the LHC at CERN and proven by the so-called 70 kA “demonstrator” lead made by KIT and by the ITER pre-prototypes made by ASIPP in China. A broad R and D campaign has been undertaken by ASIPP and CERN in order to find optimized designs for each component of the leads. Nevertheless, a comprehensive picture of the performance of the entire HTS current leads is not yet available. In this paper, a steady state, full length, thermal-hydraulic 1-D modeling is applied to the study of the three types (TF, PF/CS, CC) of ITER HTS current leads. The results of this predictive analysis are then compared with relevant ITER requirements. It was found that the present design of the HTS current leads will fulfill these specifications.

  7. Non-uniform temperature gradients and thermal stresses produced ...

    Indian Academy of Sciences (India)

    thermally-induced stress distributions in a hollow steel sphere heated by a moving uniform ... models to evaluate temperatures according to the frictional heat generation, ... of these thermal effects include thermal stress, strain and deformation.

  8. High temperature niobium alloys

    International Nuclear Information System (INIS)

    Wojcik, C.C.

    1991-01-01

    Niobium alloys are currently being used in various high temperature applications such as rocket propulsion, turbine engines and lighting systems. This paper presents an overview of the various commercial niobium alloys, including basic manufacturing processes, properties and applications. Current activities for new applications include powder metallurgy, coating development and fabrication of advanced porous structures for lithium cooled heat pipes

  9. High Temperature Electrolysis

    DEFF Research Database (Denmark)

    Elder, Rachael; Cumming, Denis; Mogensen, Mogens Bjerg

    2015-01-01

    High temperature electrolysis of carbon dioxide, or co-electrolysis of carbon dioxide and steam, has a great potential for carbon dioxide utilisation. A solid oxide electrolysis cell (SOEC), operating between 500 and 900. °C, is used to reduce carbon dioxide to carbon monoxide. If steam is also i...

  10. Nuclear fuels for very high temperature applications

    International Nuclear Information System (INIS)

    Lundberg, L.B.; Hobbins, R.R.

    1992-01-01

    The success of the development of nuclear thermal propulsion devices and thermionic space nuclear power generation systems depends on the successful utilization of nuclear fuel materials at temperatures in the range 2000 to 3500 K. Problems associated with the utilization of uranium bearing fuel materials at these very high temperatures while maintaining them in the solid state for the required operating times are addressed. The critical issues addressed include evaporation, melting, reactor neutron spectrum, high temperature chemical stability, fabrication, fission induced swelling, fission product release, high temperature creep, thermal shock resistance, and fuel density, both mass and fissile atom. Candidate fuel materials for this temperature range are based on UO 2 or uranium carbides. Evaporation suppression, such as a sealed cladding, is required for either fuel base. Nuclear performance data needed for design are sparse for all candidate fuel forms in this temperature range, especially at the higher temperatures

  11. Temperature measurement by thermal strain imaging with diagnostic power ultrasound, with potential for thermal index determination.

    Science.gov (United States)

    Liang, Hai-Dong; Zhou, Li-Xia; Wells, Peter N T; Halliwell, Michael

    2009-05-01

    Over the years, there has been a substantial increase in acoustic exposure in diagnostic ultrasound as new imaging modalities with higher intensities and frame rates have been introduced; and more electronic components have been packed into the probe head, so that there is a tendency for it to become hotter. With respect to potential thermal effects, including those which may be hazardous occurring during ultrasound scanning, there is a correspondingly growing need for in vivo techniques to guide the operator as to the actual temperature rise occurring in the examined tissues. Therefore, an in vivo temperature estimator would be of considerable practical value. The commonly-used method of tissue thermal index (TI) measurement with a hydrophone in water could underestimate the actual value of TI (in one report by as much as 2.9 times). To obtain meaningful results, it is necessary to map the temperature elevation in 2-D (or 3-D) space. We present methodology, results and validation of a 2-D spatial and temporal thermal strain ultrasound temperature estimation technique in phantoms, and its apparently novel application in tracking the evolution of heat deposition at diagnostic exposure levels. The same ultrasound probe is used for both transmission and reception. The displacement and thermal strain estimation methods are similar to those used in high-intensity focused ultrasound thermal monitoring. The use of radiofrequency signals permits the application of cross correlation as a similarity measurement for tracking feature displacement. The displacement is used to calculate the thermal strain directly related to the temperature rise. Good agreement was observed between the temperature rise and the ultrasound power and scan duration. Thermal strain up to 1.4% was observed during 4000-s scan. Based on the results obtained for the temperature range studied in this work, the technique demonstrates potential for applicability in phantom (and possibly in vivo tissue

  12. Faraday imaging at high temperatures

    Science.gov (United States)

    Hackel, Lloyd A.; Reichert, Patrick

    1997-01-01

    A Faraday filter rejects background light from self-luminous thermal objects, but transmits laser light at the passband wavelength, thus providing an ultra-narrow optical bandpass filter. The filter preserves images so a camera looking through a Faraday filter at a hot target illuminated by a laser will not see the thermal radiation but will see the laser radiation. Faraday filters are useful for monitoring or inspecting the uranium separator chamber in an atomic vapor laser isotope separation process. Other uses include viewing welds, furnaces, plasma jets, combustion chambers, and other high temperature objects. These filters are can be produced at many discrete wavelengths. A Faraday filter consists of a pair of crossed polarizers on either side of a heated vapor cell mounted inside a solenoid.

  13. Faraday imaging at high temperatures

    International Nuclear Information System (INIS)

    Hackel, L.A.; Reichert, P.

    1997-01-01

    A Faraday filter rejects background light from self-luminous thermal objects, but transmits laser light at the passband wavelength, thus providing an ultra-narrow optical bandpass filter. The filter preserves images so a camera looking through a Faraday filter at a hot target illuminated by a laser will not see the thermal radiation but will see the laser radiation. Faraday filters are useful for monitoring or inspecting the uranium separator chamber in an atomic vapor laser isotope separation process. Other uses include viewing welds, furnaces, plasma jets, combustion chambers, and other high temperature objects. These filters are can be produced at many discrete wavelengths. A Faraday filter consists of a pair of crossed polarizers on either side of a heated vapor cell mounted inside a solenoid. 3 figs

  14. Evaluation of high temperature pressure sensors

    International Nuclear Information System (INIS)

    Choi, In-Mook; Woo, Sam-Yong; Kim, Yong-Kyu

    2011-01-01

    It is becoming more important to measure the pressure in high temperature environments in many industrial fields. However, there is no appropriate evaluation system and compensation method for high temperature pressure sensors since most pressure standards have been established at room temperature. In order to evaluate the high temperature pressure sensors used in harsh environments, such as high temperatures above 250 deg. C, a specialized system has been constructed and evaluated in this study. The pressure standard established at room temperature is connected to a high temperature pressure sensor through a chiller. The sensor can be evaluated in conditions of changing standard pressures at constant temperatures and of changing temperatures at constant pressures. According to the evaluation conditions, two compensation methods are proposed to eliminate deviation due to sensitivity changes and nonlinear behaviors except thermal hysteresis.

  15. High temperature thermometric phosphors

    Science.gov (United States)

    Allison, Stephen W.; Cates, Michael R.; Boatner, Lynn A.; Gillies, George T.

    1999-03-23

    A high temperature phosphor consists essentially of a material having the general formula LuPO.sub.4 :Dy.sub.(x),Eu.sub.y) wherein: 0.1 wt %.ltoreq.x.ltoreq.20 wt % and 0.1 wt %.ltoreq.y.ltoreq.20 wt %. The high temperature phosphor is in contact with an article whose temperature is to be determined. The article having the phosphor in contact with it is placed in the environment for which the temperature of the article is to be determined. The phosphor is excited by a laser causing the phosphor to fluoresce. The emission from the phosphor is optically focused into a beam-splitting mirror which separates the emission into two separate emissions, the emission caused by the dysprosium dopant and the emission caused by the europium dopent. The separated emissions are optically filtered and the intensities of the emission are detected and measured. The ratio of the intensity of each emission is determined and the temperature of the article is calculated from the ratio of the intensities of the separate emissions.

  16. Thermal Conductance and High-Frequency Properties of Cryogenic Normal or Superconducting Semi-rigid Coaxial Cables in the Temperature Range of 1-8 K

    Science.gov (United States)

    Kushino, A.; Kasai, S.; Ukibe, M.; Ohkubo, M.

    2018-04-01

    In this study, the characteristics of thin semi-rigid cables composed of different conductors and with outer diameters ranging from 0.86 to 1.19 mm were investigated at low temperatures. The thermal conductance was measured between approximately 1 and 8 K, and the frequency dependence of the attenuation in the cables was obtained at 3 K. The electrical conductors used in the cables were alloys: beryllium copper, brass, stainless steel (SUS304), phosphor bronze, cupronickel (CuNi), and niobium-titanium (NbTi). The thermal conductance of a commercial miniature coaxial cable with braided wires forming the outer electrical conductor was also examined for reference. The measured thermal conductance was compared to published data and that generated from material libraries and databases. Among the measured cables using normal metals, the semi-rigid cable composed of SUS304 conductors and a polytetrafluoroethylene insulator showed the lowest thermal conductance. The transmission performance of the semi-rigid cables using SUS304 or CuNi was improved by plating the central conductors with a silver coating of approximately 3 μm thickness, and their thermal conductance with the plating increased by approximately one order of magnitude. The superconducting NbTi semi-rigid cable exhibited the lowest thermal conductance of all the cables considered in the present study along with very small attenuation up to above 5 GHz.

  17. Multiple temperature effects on up-conversion fluorescences of Er3+-Y b3+-Mo6+ codoped TiO2 and high thermal sensitivity

    Directory of Open Access Journals (Sweden)

    B. S. Cao

    2015-08-01

    Full Text Available We report multiple temperature effects on green and red up-conversion emissions in Er3+-Y b3+-Mo6+ codoped TiO2 phosphors. With increasing temperature, the decrease of the red emission from 4F9/2→4I15/2, the increase of green emission from 2H11/2→4I15/2 and another unchanged green emission from 4S3/2→4I15/2 were simultaneously observed, which are explained by steady-state rate equations analysis. Due to different evolution with temperature of the two green emissions, higher thermal sensitivity of optical thermal sensor was obtained based on the transitions with the largest fluorescence intensity ratio. Two parameters, maximum theoretical sensitivity (Smax and optimum operating temperature (Tmax are given to describe thermal sensing properties of the produced sensors. The intensity ratio and energy difference ΔE of a pair of energy levels are two main factors for the sensitivity and accuracy of sensors, which should be referred to design sensors with optimized sensing properties.

  18. Thermal expansion behavior of empressite, AgTe: A structural study by means of in situ high-temperature single-crystal X-ray diffraction

    Energy Technology Data Exchange (ETDEWEB)

    Bindi, Luca [Museo di Storia Naturale, sez. di Mineralogia, Universita di Firenze, Via La Pira 4, I-50121 Firenze (Italy)], E-mail: luca.bindi@unifi.it

    2009-04-03

    The crystal structure of empressite, AgTe, a rare silver telluride, has been investigated by in situ X-ray single-crystal diffraction methods within the temperature range 298-463 K. AgTe remains orthorhombic, space group Pmnb (Pnma as standard), and shows only normal thermal expansion over the entire temperature range. The unit-cell parameters show a gradual increase with the increase of temperature. Slight adjustments in the geometry of Ag-tetrahedra and in the crystal-chemical environment of tellurium atoms occur in a continuous way without abrupt structural changes. The coefficients of thermal expansion along various axes are: {alpha}{sub a} = 1.5 x 10{sup -5} K{sup -1}, {alpha}{sub b} = 3.0 x 10{sup -5} K{sup -1}, {alpha}{sub c} = 2.2 x 10{sup -5} K{sup -1}, and the bulk thermal expansion coefficient {alpha}{sub V} is 5.4 x 10{sup -5} K{sup -1} for the temperature range 298-463 K.

  19. Pretest Calculations of Temperature Changes for Field Thermal Conductivity Tests

    International Nuclear Information System (INIS)

    N.S. Brodsky

    2002-01-01

    A large volume fraction of the potential monitored geologic repository at Yucca Mountain may reside in the Tptpll (Tertiary, Paintbrush Group, Topopah Spring Tuff, crystal poor, lower lithophysal) lithostratigraphic unit. This unit is characterized by voids, or lithophysae, which range in size from centimeters to meters. A series of thermal conductivity field tests are planned in the Enhanced Characterization of the Repository Block (ECRB) Cross Drift. The objective of the pretest calculation described in this document is to predict changes in temperatures in the surrounding rock for these tests for a given heater power and a set of thermal transport properties. The calculation can be extended, as described in this document, to obtain thermal conductivity, thermal capacitance (density x heat capacity, J · m -3 · K -1 ), and thermal diffusivity from the field data. The work has been conducted under the ''Technical Work Plan For: Testing and Monitoring'' (BSC 2001). One of the outcomes of this analysis is to determine the initial output of the heater. This heater output must be sufficiently high that it will provide results in a reasonably short period of time (within several weeks or a month) and be sufficiently high that the heat increase is detectable by the instruments employed in the test. The test will be conducted in stages and heater output will be step increased as the test progresses. If the initial temperature is set too high, the experiment will not have as many steps and thus fewer thermal conductivity data points will result

  20. Examining the microhardness evolution and thermal stability of an Al–Mg–Sc alloy processed by high-pressure torsion at a high temperature

    Directory of Open Access Journals (Sweden)

    Pedro Henrique R. Pereira

    2017-10-01

    Full Text Available An Al–3% Mg–0.2% Sc alloy was solution treated and processed through 10 turns of high-pressure torsion (HPT at 450 K. Afterwards, the HPT-processed alloy was annealed for 1 h at temperatures ranging from 423 to 773 K and its mechanical properties and microstructural evolution were examined using microhardness measurements and electron backscattered diffraction (EBSD analysis. The results demonstrate that HPT processing at an elevated temperature leads to a more uniform microhardness distribution and to an early saturation in the hardness values in the Al alloy compared with high-pressure torsion at room temperature. In addition, detailed EBSD analysis conducted on the HPT-processed samples immediately after annealing revealed that the Al–Mg–Sc alloy subjected to HPT processing at 450 K exhibits superior thermal stability by comparison with the same material subjected to HPT at 300 K. Keywords: Aluminium alloys, Hall–Petch relationship, Hardness, High-pressure torsion, Severe plastic deformation, Thermal stability

  1. Borehole Stability in High-Temperature Formations

    Science.gov (United States)

    Yan, Chuanliang; Deng, Jingen; Yu, Baohua; Li, Wenliang; Chen, Zijian; Hu, Lianbo; Li, Yang

    2014-11-01

    In oil and gas drilling or geothermal well drilling, the temperature difference between the drilling fluid and formation will lead to an apparent temperature change around the borehole, which will influence the stress state around the borehole and tend to cause borehole instability in high geothermal gradient formations. The thermal effect is usually not considered as a factor in most of the conventional borehole stability models. In this research, in order to solve the borehole instability in high-temperature formations, a calculation model of the temperature field around the borehole during drilling is established. The effects of drilling fluid circulation, drilling fluid density, and mud displacement on the temperature field are analyzed. Besides these effects, the effect of temperature change on the stress around the borehole is analyzed based on thermoelasticity theory. In addition, the relationships between temperature and strength of four types of rocks are respectively established based on experimental results, and thermal expansion coefficients are also tested. On this basis, a borehole stability model is established considering thermal effects and the effect of temperature change on borehole stability is also analyzed. The results show that the fracture pressure and collapse pressure will both increase as the temperature of borehole rises, and vice versa. The fracture pressure is more sensitive to temperature. Temperature has different effects on collapse pressures due to different lithological characters; however, the variation of fracture pressure is unrelated to lithology. The research results can provide a reference for the design of drilling fluid density in high-temperature wells.

  2. High Temperature, High Power Piezoelectric Composite Transducers

    Science.gov (United States)

    Lee, Hyeong Jae; Zhang, Shujun; Bar-Cohen, Yoseph; Sherrit, StewarT.

    2014-01-01

    Piezoelectric composites are a class of functional materials consisting of piezoelectric active materials and non-piezoelectric passive polymers, mechanically attached together to form different connectivities. These composites have several advantages compared to conventional piezoelectric ceramics and polymers, including improved electromechanical properties, mechanical flexibility and the ability to tailor properties by using several different connectivity patterns. These advantages have led to the improvement of overall transducer performance, such as transducer sensitivity and bandwidth, resulting in rapid implementation of piezoelectric composites in medical imaging ultrasounds and other acoustic transducers. Recently, new piezoelectric composite transducers have been developed with optimized composite components that have improved thermal stability and mechanical quality factors, making them promising candidates for high temperature, high power transducer applications, such as therapeutic ultrasound, high power ultrasonic wirebonding, high temperature non-destructive testing, and downhole energy harvesting. This paper will present recent developments of piezoelectric composite technology for high temperature and high power applications. The concerns and limitations of using piezoelectric composites will also be discussed, and the expected future research directions will be outlined. PMID:25111242

  3. Improved Thermal-Insulation Systems for Low Temperatures

    Science.gov (United States)

    Fesmire, James E.; Augustynowicz, Stanislaw D.

    2003-01-01

    Improved thermal-insulation materials and structures and the techniques for manufacturing them are undergoing development for use in low-temperature applications. Examples of low-temperature equipment for which these thermal insulation systems could provide improved energy efficiency include storage tanks for cryogens, superconducting electric-power-transmission equipment, containers for transport of food and other perishable commodities, and cold boxes for low-temperature industrial processes. These systems could also be used to insulate piping used to transfer cryogens and other fluids, such as liquefied natural gas, refrigerants, chilled water, crude oil, or low-pressure steam. The present thermal-insulation systems are layer composites based partly on the older class of thermal-insulation systems denoted generally as multilayer insulation (MLI). A typical MLI structure includes an evacuated jacket, within which many layers of radiation shields are stacked or wrapped close together. Low-thermal-conductivity spacers are typically placed between the reflection layers to keep them from touching. MLI can work very well when a high vacuum level (less than 10(exp-4) torr) is maintained and utmost care is taken during installation, but its thermal performance deteriorates sharply as the pressure in the evacuated space rises into the soft vacuum range [pressures greater than 0.1 torr (greater than 13 Pa)]. In addition, the thermal performance of MLI is extremely sensitive to mechanical compression and edge effects and can easily decrease from one to two orders of magnitude from its ideal value even when the MLI is kept under high vacuum condition. The present thermal-insulation systems are designed to perform well under soft vacuum level, in particular the range of 1 to 10 torr. They are also designed with larger interlayer spacings to reduce vulnerability to compression (and consequent heat leak) caused by installation and use. The superiority of these systems is the

  4. Exploration of porous SiC nanostructures as thermal insulator with high thermal stability and low thermal conductivity

    Institute of Scientific and Technical Information of China (English)

    Peng; WAN; Jingyang; WANG

    2016-01-01

    The crucial challenge for current nanoscale thermal insulation materials,such as Al2O3 and SiO2 aerogel composites,is to solve the trade-off between extremely low thermal conductivity and unsatisfied thermal stability.Typical high-temperature ceramic SiC possesses excellent mechanical properties and

  5. Kalman filtered MR temperature imaging for laser induced thermal therapies.

    Science.gov (United States)

    Fuentes, D; Yung, J; Hazle, J D; Weinberg, J S; Stafford, R J

    2012-04-01

    The feasibility of using a stochastic form of Pennes bioheat model within a 3-D finite element based Kalman filter (KF) algorithm is critically evaluated for the ability to provide temperature field estimates in the event of magnetic resonance temperature imaging (MRTI) data loss during laser induced thermal therapy (LITT). The ability to recover missing MRTI data was analyzed by systematically removing spatiotemporal information from a clinical MR-guided LITT procedure in human brain and comparing predictions in these regions to the original measurements. Performance was quantitatively evaluated in terms of a dimensionless L(2) (RMS) norm of the temperature error weighted by acquisition uncertainty. During periods of no data corruption, observed error histories demonstrate that the Kalman algorithm does not alter the high quality temperature measurement provided by MR thermal imaging. The KF-MRTI implementation considered is seen to predict the bioheat transfer with RMS error 10 sec.

  6. High temperature materials characterization

    Science.gov (United States)

    Workman, Gary L.

    1990-01-01

    A lab facility for measuring elastic moduli up to 1700 C was constructed and delivered. It was shown that the ultrasonic method can be used to determine elastic constants of materials from room temperature to their melting points. The ease in coupling high frequency acoustic energy is still a difficult task. Even now, new coupling materials and higher power ultrasonic pulsers are being suggested. The surface was only scratched in terms of showing the full capabilities of either technique used, especially since there is such a large learning curve in developing proper methodologies to take measurements into the high temperature region. The laser acoustic system does not seem to have sufficient precision at this time to replace the normal buffer rod methodology.

  7. Experimental study on thermophysical properties of C/C composites at high temperature

    Institute of Scientific and Technical Information of China (English)

    ZHANG Wei; YI Fa-jun; HAN Jie-cai; MENG Song-he

    2006-01-01

    The coefficient of thermal expansion, thermal diffusivity and specific heat of C/C composites from room temperature to ultra high temperature were experimentally investigated. Thermal conductivity and thermal stress resistance of the composites were therefore computed based on experimental results. The results show that the composite has a very low thermal expansion coefficient. Thermal diffusivity decreases exponentially with temperature increase. The specific heat increases linearly as the temperature rises, and the variation trend of thermal conductivity is similar to that of thermal diffusivity. The thermal stress coefficient of C/C composite has little change with temperature variation, and thermal stress resistance of the composite at high temperature is stable.

  8. High temperature superconductor current leads

    International Nuclear Information System (INIS)

    Zeimetz, B.; Liu, H.K.; Dou, S.X.

    1996-01-01

    Full text: The use of superconductors in high electrical current applications (magnets, transformers, generators etc.) usually requires cooling with liquid Helium, which is very expensive. The superconductor itself produces no heat, and the design of Helium dewars is very advanced. Therefore most of the heat loss, i.e. Helium consumption, comes from the current lead which connects the superconductor with its power source at room temperature. The current lead usually consists of a pair of thick copper wires. The discovery of the High Temperature Superconductors makes it possible to replace a part of the copper with superconducting material. This drastically reduces the heat losses because a) the superconductor generates no resistive heat and b) it is a very poor thermal conductor compared with the copper. In this work silver-sheathed superconducting tapes are used as current lead components. The work comprises both the production of the tapes and the overall design of the leads, in order to a) maximize the current capacity ('critical current') of the superconductor, b) minimize the thermal conductivity of the silver clad, and c) optimize the cooling conditions

  9. High temperature radioisotope capsule

    International Nuclear Information System (INIS)

    Bradshaw, G.B.

    1976-01-01

    A high temperature radioisotope capsule made up of three concentric cylinders, with the isotope fuel located within the innermost cylinder is described. The innermost cylinder has hemispherical ends and is constructed of a tantalum alloy. The intermediate cylinder is made of a molybdenum alloy and is capable of withstanding the pressure generated by the alpha particle decay of the fuel. The outer cylinder is made of a platinum alloy of high resistance to corrosion. A gas separates the innermost cylinder from the intermediate cylinder and the intermediate cylinder from the outer cylinder

  10. Development of high temperature turbine

    Energy Technology Data Exchange (ETDEWEB)

    Takahara, Kitao; Nouse, Hiroyuki; Yoshida, Toyoaki; Minoda, Mitsuhiro; Matsusue, Katsutoshi; Yanagi, Ryoji

    1988-07-01

    For the contribution to the development of FJR710, high by-pass ratio turbofan engine, with the study for many years of the development of high efficiency turbine for the jet engine, the first technical prize from the Energy Resource Research Committee was awarded in April, 1988. This report introduced its technical contents. In order to improve the thermal efficiency and enlarge the output, it is very effective to raise the gas temperature at the inlet of gas turbine. For its purpose, by cooling the nozzle and moving blades and having those blades operate at lower temperature than that of the working limitation, they realized, for the first time in Japan, the technique of cooling turbine to heighten the operational gas temperature. By that technique, it was enabled to raise the gas temperature at the inlet of turbine, to 1,350/sup 0/C from 850/sup 0/C. This report explain many important points of study covering the basic test, visualizing flow experiment, material discussion and structural design in the process of development. (9 figs)

  11. High-temperature uncertainty

    International Nuclear Information System (INIS)

    Timusk, T.

    2005-01-01

    Recent experiments reveal that the mechanism responsible for the superconducting properties of cuprate materials is even more mysterious than we thought. Two decades ago, Georg Bednorz and Alex Mueller of IBM's research laboratory in Zurich rocked the world of physics when they discovered a material that lost all resistance to electrical current at the record temperature of 36 K. Until then, superconductivity was thought to be a strictly low-temperature phenomenon that required costly refrigeration. Moreover, the IBM discovery - for which Bednorz and Mueller were awarded the 1987 Nobel Prize for Physics - was made in a ceramic copper-oxide material that nobody expected to be particularly special. Proposed applications for these 'cuprates' abounded. High-temperature superconductivity, particularly if it could be extended to room temperature, offered the promise of levitating trains, ultra-efficient power cables, and even supercomputers based on superconducting quantum interference devices. But these applications have been slow to materialize. Moreover, almost 20 years on, the physics behind this strange state of matter remains a mystery. (U.K.)

  12. The thermal equation of state of FeTiO3 ilmenite based on in situ X-ray diffraction at high pressures and temperatures

    International Nuclear Information System (INIS)

    Tronche, E.J.; Van Kan Parker, M.; De Vries, J.; Wang, Y.; Sanehire, T.; Li, J.; Chen, B.; Gao, L.; Klemme, S.; McCammon, C.A.; Van Westerenen, W.

    2010-01-01

    We present in situ measurements of the unit-cell volume of a natural terrestrial ilmenite (Jagersfontein mine, South Africa) and a synthetic reduced ilmenite (FeTiO 3 ) at simultaneous high pressure and high temperature up to 16 GPa and 1273 K. Unit-cell volumes were determined using energy-dispersive synchrotron X-ray diffraction in a multi-anvil press. Moessbauer analyses show that the synthetic sample contained insignificant amounts of Fe 3+ both before and after the experiment. Results were fit to Birch-Murnaghan thermal equations of state, which reproduce the experimental data to within 0.5 and 0.7 GPa for the synthetic and natural samples, respectively. At ambient conditions, the unit-cell volume of the natural sample (V 0 = 314.75 ± 0.23 (1σ) (angstrom) 3 ) is significantly smaller than that of the synthetic sample (V 0 = 319.12 ± 0.26 (angstrom) 3 ). The difference can be attributed to the presence of impurities and Fe 3+ in the natural sample. The 1 bar isothermal bulk moduli K T0 for the reduced ilmenite is slightly larger than for the natural ilmenite (181 ± 7 and 165 ± 6 GPa, respectively), with pressure derivatives K(prime) 0 = 3 ± 1. Our results, combined with literature data, suggest that the unit-cell volume of reduced ilmenite is significantly larger than that of oxidized ilmenite, whereas their thermoelastic parameters are similar. Our data provide more appropriate input parameters for thermo-chemical models of lunar interior evolution, in which reduced ilmenite plays a critical role.

  13. Thermal ratchetting in pipes subjected to intermittent thermal downshocks at elevated temperatures

    International Nuclear Information System (INIS)

    Corum, J.M.; Young, H.C.; Grindell, A.G.

    1974-01-01

    The results of two thermal ratchetting tests on straight sections of pipe are presented. The pipes, each of which was machined from a well-characterized heat of type 304 stainless steel, were subjected to a series of thermal downshocks on their inner surface, followed by sustained periods under an internal pressure loading at a temperature of 1100 0 F. Testing was carried out in a special sodium test facility built for the purpose, and the outer surface strain histories were measured using high-temperature capacitive strain gages. The circumferential strain responses, which typify the inelastic behaviors, are presented. 7 references. (U.S.)

  14. High Temperature Piezoelectric Drill

    Science.gov (United States)

    Bao, Xiaoqi; Bar-Cohen, Yoseph; Sherrit, Stewart; Badescu, Mircea; Shrout, Tom

    2012-01-01

    Venus is one of the planets in the solar systems that are considered for potential future exploration missions. It has extreme environment where the average temperature is 460 deg C and its ambient pressure is about 90 atm. Since the existing actuation technology cannot maintain functionality under the harsh conditions of Venus, it is a challenge to perform sampling and other tasks that require the use of moving parts. Specifically, the currently available electromagnetic actuators are limited in their ability to produce sufficiently high stroke, torque, or force. In contrast, advances in developing electro-mechanical materials (such as piezoelectric and electrostrictive) have enabled potential actuation capabilities that can be used to support such missions. Taking advantage of these materials, we developed a piezoelectric actuated drill that operates at the temperature range up to 500 deg C and the mechanism is based on the Ultrasonic/Sonic Drill/Corer (USDC) configuration. The detailed results of our study are presented in this paper

  15. High-G Thermal Characterization Centrifuge

    Data.gov (United States)

    Federal Laboratory Consortium — High-G testing of thermal components enables improved understanding of operating behavior under military-relevant environments. The High-G Thermal Characterization...

  16. High temperature materials and mechanisms

    CERN Document Server

    2014-01-01

    The use of high-temperature materials in current and future applications, including silicone materials for handling hot foods and metal alloys for developing high-speed aircraft and spacecraft systems, has generated a growing interest in high-temperature technologies. High Temperature Materials and Mechanisms explores a broad range of issues related to high-temperature materials and mechanisms that operate in harsh conditions. While some applications involve the use of materials at high temperatures, others require materials processed at high temperatures for use at room temperature. High-temperature materials must also be resistant to related causes of damage, such as oxidation and corrosion, which are accelerated with increased temperatures. This book examines high-temperature materials and mechanisms from many angles. It covers the topics of processes, materials characterization methods, and the nondestructive evaluation and health monitoring of high-temperature materials and structures. It describes the ...

  17. Microscale solid-state thermal diodes enabling ambient temperature thermal circuits for energy applications

    KAUST Repository

    Wang, Song; Cottrill, Anton L.; Kunai, Yuichiro; Toland, Aubrey R.; Liu, Pingwei; Wang, Wen-Jun; Strano, Michael S.

    2017-01-01

    rectifications range from 1.18 to 1.34. We show that such devices perform reliably enough to operate in thermal diode bridges, dynamic thermal circuits capable of transforming oscillating temperature inputs into single polarity temperature differences – analogous

  18. High temperature superconductors

    CERN Document Server

    Paranthaman, Parans

    2010-01-01

    This essential reference provides the most comprehensive presentation of the state of the art in the field of high temperature superconductors. This growing field of research and applications is currently being supported by numerous governmental and industrial initiatives in the United States, Asia and Europe to overcome grid energy distribution issues. The technology is particularly intended for densely populated areas. It is now being commercialized for power-delivery devices, such as power transmission lines and cables, motors and generators. Applications in electric utilities include current limiters, long transmission lines and energy-storage devices that will help industries avoid dips in electric power.

  19. Fusion blanket high-temperature heat transfer

    International Nuclear Information System (INIS)

    Fillo, J.A.

    1983-01-01

    Deep penetration of 14 MeV neutrons makes two-temperature region blankets feasible. A relatively low-temperature (approx. 300 0 C) metallic structure is the vacuum/coolant pressure boundary, while the interior of the blanket, which is a simple packed bed of nonstructural material, operates at very high temperatures (>1000 0 C). The water-cooled shell structure is thermally insulated from the steam-cooled interior. High-temperature steam can dramatically increase the efficiency of electric power generation, as well as produce hydrogen and oxygen-based synthetic fuels at high-efficiency

  20. High temperature and high pressure equation of state of gold

    International Nuclear Information System (INIS)

    Matsui, Masanori

    2010-01-01

    High-temperature and high-pressure equation of state (EOS) of Au has been developed using measured data from shock compression up to 240 GPa, volume thermal expansion between 100 and 1300 K and 0 GPa, and temperature dependence of bulk modulus at 0 GPa from ultrasonic measurements. The lattice thermal pressures at high temperatures have been estimated based on the Mie-Grueneisen-Debye type treatment with the Vinet isothermal EOS. The contribution of electronic thermal pressure at high temperatures, which is relatively insignificant for Au, has also been included here. The optimized EOS parameters are K' 0T = 6.0 and q = 1.6 with fixed K 0T = 167 GPa, γ 0 = 2.97, and Θ 0 = 170 K from previous investigations. We propose the present EOS to be used as a reliable pressure standard for static experiments up to 3000K and 300 GPa.

  1. Ultra-miniature wireless temperature sensor for thermal medicine applications.

    Science.gov (United States)

    Khairi, Ahmad; Hung, Shih-Chang; Paramesh, Jeyanandh; Fedder, Gary; Rabin, Yoed

    2011-01-01

    This study presents a prototype design of an ultra-miniature, wireless, battery-less, and implantable temperature-sensor, with applications to thermal medicine such as cryosurgery, hyperthermia, and thermal ablation. The design aims at a sensory device smaller than 1.5 mm in diameter and 3 mm in length, to enable minimally invasive deployment through a hypodermic needle. While the new device may be used for local temperature monitoring, simultaneous data collection from an array of such sensors can be used to reconstruct the 3D temperature field in the treated area, offering a unique capability in thermal medicine. The new sensory device consists of three major subsystems: a temperature-sensing core, a wireless data-communication unit, and a wireless power reception and management unit. Power is delivered wirelessly to the implant from an external source using an inductive link. To meet size requirements while enhancing reliability and minimizing cost, the implant is fully integrated in a regular foundry CMOS technology (0.15 μm in the current study), including the implant-side inductor of the power link. A temperature-sensing core that consists of a proportional-to-absolute-temperature (PTAT) circuit has been designed and characterized. It employs a microwatt chopper stabilized op-amp and dynamic element-matched current sources to achieve high absolute accuracy. A second order sigma-delta (Σ-Δ) analog-to-digital converter (ADC) is designed to convert the temperature reading to a digital code, which is transmitted by backscatter through the same antenna used for receiving power. A high-efficiency multi-stage differential CMOS rectifier has been designed to provide a DC supply to the sensing and communication subsystems. This paper focuses on the development of the all-CMOS temperature sensing core circuitry part of the device, and briefly reviews the wireless power delivery and communication subsystems.

  2. Modelling and analysis of radial thermal stresses and temperature ...

    African Journals Online (AJOL)

    A theoretical investigation has been undertaken to study operating temperatures, heat fluxes and radial thermal stresses in the valves of a modern diesel engine with and without air-cavity. Temperatures, heat fluxes and radial thermal stresses were measured theoretically for both cases under all four thermal loading ...

  3. Effect of heat treatment temperature on binder thermal conductivities

    International Nuclear Information System (INIS)

    Wagner, P.

    1975-12-01

    The effect of heat treatment on the thermal conductivities of a pitch and a polyfurfuryl alcohol binder residue was investigated. Graphites specially prepared with these two binders were used for the experiments. Measured thermal conductivities were treated in terms of a two-component system, and the binder thermal conductivities were calculated. Both binder residues showed increased thermal conductivity with increased heat treatment temperature

  4. High temperature interface superconductivity

    International Nuclear Information System (INIS)

    Gozar, A.; Bozovic, I.

    2016-01-01

    Highlight: • This review article covers the topic of high temperature interface superconductivity. • New materials and techniques used for achieving interface superconductivity are discussed. • We emphasize the role played by the differences in structure and electronic properties at the interface with respect to the bulk of the constituents. - Abstract: High-T_c superconductivity at interfaces has a history of more than a couple of decades. In this review we focus our attention on copper-oxide based heterostructures and multi-layers. We first discuss the technique, atomic layer-by-layer molecular beam epitaxy (ALL-MBE) engineering, that enabled High-T_c Interface Superconductivity (HT-IS), and the challenges associated with the realization of high quality interfaces. Then we turn our attention to the experiments which shed light on the structure and properties of interfacial layers, allowing comparison to those of single-phase films and bulk crystals. Both ‘passive’ hetero-structures as well as surface-induced effects by external gating are discussed. We conclude by comparing HT-IS in cuprates and in other classes of materials, especially Fe-based superconductors, and by examining the grand challenges currently laying ahead for the field.

  5. High-entropy alloys as high-temperature thermoelectric materials

    Energy Technology Data Exchange (ETDEWEB)

    Shafeie, Samrand [Surface and Microstructure Engineering Group, Materials and Manufacturing Technology, Chalmers University of Technology, SE-41296 Gothenburg (Sweden); Department of Chemistry and Chemical Engineering, Chalmers University of Technology, SE-41296 Gothenburg (Sweden); Guo, Sheng, E-mail: sheng.guo@chalmers.se [Surface and Microstructure Engineering Group, Materials and Manufacturing Technology, Chalmers University of Technology, SE-41296 Gothenburg (Sweden); Hu, Qiang [Institute of Applied Physics, Jiangxi Academy of Sciences, Nanchang 330029 (China); Fahlquist, Henrik [Bruker AXS Nordic AB, 17067 Solna (Sweden); Erhart, Paul [Department of Applied Physics, Chalmers University of Technology, SE-41296 Gothenburg (Sweden); Palmqvist, Anders, E-mail: anders.palmqvist@chalmers.se [Department of Chemistry and Chemical Engineering, Chalmers University of Technology, SE-41296 Gothenburg (Sweden)

    2015-11-14

    Thermoelectric (TE) generators that efficiently recycle a large portion of waste heat will be an important complementary energy technology in the future. While many efficient TE materials exist in the lower temperature region, few are efficient at high temperatures. Here, we present the high temperature properties of high-entropy alloys (HEAs), as a potential new class of high temperature TE materials. We show that their TE properties can be controlled significantly by changing the valence electron concentration (VEC) of the system with appropriate substitutional elements. Both the electrical and thermal transport properties in this system were found to decrease with a lower VEC number. Overall, the large microstructural complexity and lower average VEC in these types of alloys can potentially be used to lower both the total and the lattice thermal conductivity. These findings highlight the possibility to exploit HEAs as a new class of future high temperature TE materials.

  6. The effect of thermal cycling on tetragonal to monoclinic transformation in ZrO2(2%Y2O3) ceramic studied by high temperature X-ray diffraction

    International Nuclear Information System (INIS)

    Zhu, W.Z.; Lei, T.C.; Zhou, Y.

    1993-01-01

    It has been established that brittleness and reliability of ceramics can be improved by a stress-triggered tetragonal (T) to monoclinic (M) transformation in zirconia termed transformation toughening. The T → M transformation is not only influenced by such intrinsic factors as the variety and amount of stabilizers, grain size and morphology of T phase, but can be affected by the cooling rate as well. A previous study by Tsubadin, using a dilation experiment to determine the effect of thermal cycling on the T → M transformation in partially stabilized zirconia suggested that sintering temperature determined the role of thermal cycling, while the underlying cause still remains ambiguous. The intent of the present paper is to reinvestigate the effect of thermal cycling on the T → M transition in a hot pressed ZrO 2 (2%y 2 O 3 ) ceramic, using a high temperature x-ray diffractometer, and rationalize the experimental results from the viewpoint of thermodynamics

  7. Verification of in-core thermal and hydraulic analysis code FLOWNET/TRUMP for the high temperature engineering test reactor (HTTR) at JAERI

    International Nuclear Information System (INIS)

    Maruyama, Soh; Sudo, Yukio; Saito, Shinzo; Kiso, Yoshihiro; Hayakawa, Hitoshi

    1989-01-01

    The FLOWNET/TRUMP code consists of a flow network analysis code 'FLOWNET' for calculations of coolant flow distribution and coolant temperature distribution in the core with a thermal conduction analysis code 'TRUMP' for calculation of temperature distribution in solid structures. The verification of FLOWNET/TRUMP was made by the comparison of the analytical results with the results of steady state experiments by the HENDEL multichannel test rig, T1-M, which consisted of twelve simulated fuel rods heated electrically and eleven hexagonal graphite fuel blocks. The T1-M simulated the one fuel column in the core. The analytical results agreed well with the results of the experiment in which the HTTR operating conditions were simulated. (orig.)

  8. Dynamic Model of High Temperature PEM Fuel Cell Stack Temperature

    DEFF Research Database (Denmark)

    Andreasen, Søren Juhl; Kær, Søren Knudsen

    2007-01-01

    cathode air cooled 30 cell HTPEM fuel cell stack developed at the Institute of Energy Technology at Aalborg University. This fuel cell stack uses PEMEAS Celtec P-1000 membranes, runs on pure hydrogen in a dead end anode configuration with a purge valve. The cooling of the stack is managed by running......The present work involves the development of a model for predicting the dynamic temperature of a high temperature PEM (HTPEM) fuel cell stack. The model is developed to test different thermal control strategies before implementing them in the actual system. The test system consists of a prototype...... the stack at a high stoichiometric air flow. This is possible because of the PBI fuel cell membranes used, and the very low pressure drop in the stack. The model consists of a discrete thermal model dividing the stack into three parts: inlet, middle and end and predicting the temperatures in these three...

  9. High thermal conductivity materials for thermal management applications

    Science.gov (United States)

    Broido, David A.; Reinecke, Thomas L.; Lindsay, Lucas R.

    2018-05-29

    High thermal conductivity materials and methods of their use for thermal management applications are provided. In some embodiments, a device comprises a heat generating unit (304) and a thermally conductive unit (306, 308, 310) in thermal communication with the heat generating unit (304) for conducting heat generated by the heat generating unit (304) away from the heat generating unit (304), the thermally conductive unit (306, 308, 310) comprising a thermally conductive compound, alloy or composite thereof. The thermally conductive compound may include Boron Arsenide, Boron Antimonide, Germanium Carbide and Beryllium Selenide.

  10. Thermal diffusivity of felsic to mafic granulites at elevated temperatures

    Science.gov (United States)

    Ray, Labani; Förster, H.-J.; Schilling, F. R.; Förster, A.

    2006-11-01

    The thermal diffusivity of felsic and intermediate granulites (charnockites, enderbites), mafic granulites, and amphibolite-facies gneisses has been measured up to temperatures of 550 °C using a transient technique. The rock samples are from the Archean and Pan-African terranes of the Southern Indian Granulite Province. Thermal diffusivity at room temperature ( DRT) for different rock types ranges between 1.2 and 2.2 mm 2 s - 1 . For most of the rocks, the effect of radiative heat transfer is observed at temperatures above 450 °C. However, for few enderbites and mafic granulites, radiative heat transfer is negligible up to 550 °C. In the temperature range of conductive heat transfer, i.e., between 20 ° and 450 °C, thermal diffusivity decreases between 35% and 45% with increasing temperature. The temperature dependence of the thermal diffusivity is directly correlated with the thermal diffusivity at room temperature, i.e., the higher the thermal diffusivity at room temperature, DRT, the greater is its temperature dependence. In this temperature range i.e., between 20 and 450 °C, thermal diffusivity can be expressed as D = 0.7 mm 2 s -1 + 144 K ( DRT - 0.7 mm 2 s -1 ) / ( T - 150 K), where T is the absolute temperature in Kelvin. At higher temperatures, an additional radiative contribution is observed according to CT3, where C varies from 10 - 9 to 10 - 10 depending on intrinsic rock properties (opacity, absorption behavior, grain size, grain boundary, etc). An equation is presented that describes the temperature and pressure dependence thermal diffusivity of rocks based only on the room-temperature thermal diffusivity. Room-temperature thermal diffusivity and its temperature dependence are mainly dependent on the major mineralogy of the rock. Because granulites are important components of the middle and lower continental crust, the results of this study provide important constraints in quantifying more accurately the thermal state of the deeper continental

  11. High temperature metallic recuperator

    Science.gov (United States)

    Ward, M. E.; Solmon, N. G.; Smeltzer, C. E.

    1981-06-01

    An industrial 4.5 MM Btu/hr axial counterflow recuperator, fabricated to deliver 1600 F combustion air, was designed to handle rapid cyclic loading, a long life, acceptable costs, and a low maintenance requirement. A cost benefit anlysis of a high temperature waste heat recovery system utilizing the recurperator and components capable of 1600 F combustion air preheat shows that this system would have a payback period of less than two years. Fifteen companies and industrial associations were interviewed and expressed great interest in recuperation in large energy consuming industries. Determination of long term environmental effects on candidate recuperator tubing alloys was completed. Alloys found to be acceptable in the 2200 F flue gas environment of a steel billet reheat furnace, were identified.

  12. Effect of high thermal expansion glass infiltration on mechanical ...

    Indian Academy of Sciences (India)

    This work studies the effect on the mechanical properties of alumina-10 wt% zirconia (3 mol% yttria stabilized) composite by infiltrating glass of a higher thermal expansion (soda lime glass) on the surface at high temperature. The glass improved the strength of composite at room temperature as well as at high temperature.

  13. A temperature dependent slip factor based thermal model for friction

    Indian Academy of Sciences (India)

    This paper proposes a new slip factor based three-dimensional thermal model to predict the temperature distribution during friction stir welding of 304L stainless steel plates. The proposed model employs temperature and radius dependent heat source to study the thermal cycle, temperature distribution, power required, the ...

  14. Thermal conductivity of highly porous mullite material

    International Nuclear Information System (INIS)

    Barea, Rafael; Osendi, Maria Isabel; Ferreira, Jose M.F.; Miranzo, Pilar

    2005-01-01

    The thermal diffusivity of highly porous mullite materials (35-60 vol.% porosity) has been measured up to 1000 deg C by the laser flash method. These materials were fabricated by a direct consolidation method based on the swelling properties of starch granules in concentrated aqueous suspensions and showed mainly spherical shaped pores of about 30 μm in diameter. From the point of view of heat conduction, they behave as a bi-phase material of voids dispersed in the continuous mullite matrix. The temperature dependence of thermal conductivity for the different porosities was modeled by a simple equation that considers the contribution to heat conduction of the mullite matrix and the gas inside the pores, as well as the radiation. The thermal conductivity of the matrix was taken from the measurements done in a dense mullite while the conductivity in the voids was assumed to be that of the testing atmosphere

  15. Estimation of Thermal Sensation Based on Wrist Skin Temperatures

    Science.gov (United States)

    Sim, Soo Young; Koh, Myung Jun; Joo, Kwang Min; Noh, Seungwoo; Park, Sangyun; Kim, Youn Ho; Park, Kwang Suk

    2016-01-01

    Thermal comfort is an essential environmental factor related to quality of life and work effectiveness. We assessed the feasibility of wrist skin temperature monitoring for estimating subjective thermal sensation. We invented a wrist band that simultaneously monitors skin temperatures from the wrist (i.e., the radial artery and ulnar artery regions, and upper wrist) and the fingertip. Skin temperatures from eight healthy subjects were acquired while thermal sensation varied. To develop a thermal sensation estimation model, the mean skin temperature, temperature gradient, time differential of the temperatures, and average power of frequency band were calculated. A thermal sensation estimation model using temperatures of the fingertip and wrist showed the highest accuracy (mean root mean square error [RMSE]: 1.26 ± 0.31). An estimation model based on the three wrist skin temperatures showed a slightly better result to the model that used a single fingertip skin temperature (mean RMSE: 1.39 ± 0.18). When a personalized thermal sensation estimation model based on three wrist skin temperatures was used, the mean RMSE was 1.06 ± 0.29, and the correlation coefficient was 0.89. Thermal sensation estimation technology based on wrist skin temperatures, and combined with wearable devices may facilitate intelligent control of one’s thermal environment. PMID:27023538

  16. Low-Temperature Bainite: A Thermal Stability Study

    Science.gov (United States)

    Santajuana, Miguel A.; Rementeria, Rosalia; Kuntz, Matthias; Jimenez, Jose A.; Caballero, Francisca G.; Garcia-Mateo, Carlos

    2018-06-01

    The thermal stability of nanobainitic structures obtained by heat treating two different high-carbon high-silicon steels at temperatures between 200 °C and 600 °C has been investigated by means of three complementary techniques, i.e., field emission gun-scanning electron microscopy, X-ray diffraction, and high-resolution dilatometry. Three main stages have been established, each of them characterized by a distinctive microstructure. Furthermore, the nanocrystalline structure generated by the bainite reaction confers the steel with an extraordinary tempering resistance.

  17. Non-Fourier conduction model with thermal source term of ultra short high power pulsed laser ablation and temperature evolvement before melting

    International Nuclear Information System (INIS)

    Zhang Duanming; Li, Li; Li Zhihua; Guan Li; Tan Xinyu

    2005-01-01

    A non-Fourier conduction model with heat source term is presented to study the target temperature evolvement when the target is radiated by high power (the laser intensity is above 10 9 w/cm 2 ) and ultra short (the pulse width is less than 150 ps) pulsed laser. By Laplace transform, the analytical expression of the space- and time-dependence of temperature is derived. Then as an example of aluminum target, the target temperature evolvement is simulated. Compared with the results of Fourier conduction model and non-Fourier model without heat source term, it is found that the effect of non-Fourier conduction is notable and the heat source plays an important role during non-Fourier conduction which makes surface temperature ascending quickly with time. Meanwhile, the corresponding physical mechanism is analyzed theoretically

  18. Dynamics of Gauge Fields at High Temperature

    NARCIS (Netherlands)

    Nauta, B.J.

    2000-01-01

    An effective description of dynamical Bose fields is provided by the classical (high-temperature) limit of thermal field theory. The main subject of this thesis is to improve the ensuing classical field theory, that is, to include the dominant quantum corrections and to add counter terms for the

  19. High temperature estimation through computer vision

    International Nuclear Information System (INIS)

    Segovia de los R, J.A.

    1996-01-01

    The form recognition process has between his purposes to conceive and to analyze the classification algorithms applied to the image representations, sounds or signals of any kind. In a process with a thermal plasma reactor in which cannot be employed conventional dispositives or methods for the measurement of the very high temperatures. The goal of this work was to determine these temperatures in an indirect way. (Author)

  20. High Temperature Superconductor Accelerator Magnets

    CERN Document Server

    AUTHOR|(CDS)2079328; de Rijk, Gijs; Dhalle, Marc

    2016-11-10

    For future particle accelerators bending dipoles are considered with magnetic fields exceeding $20T$. This can only be achieved using high temperature superconductors (HTS). These exhibit different properties from classical low temperature superconductors and still require significant research and development before they can be applied in a practical accelerator magnet. In order to study HTS in detail, a five tesla demonstrator magnet named Feather-M2 is designed and constructed. The magnet is based on ReBCO coated conductor, which is assembled into a $10kA$ class Roebel cable. A new and optimized Aligned Block layout is used, which takes advantage of the anisotropy of the conductor. This is achieved by providing local alignment of the Roebel cable in the coil windings with the magnetic field lines. A new Network Model capable of analyzing transient electro-magnetic and thermal phenomena in coated conductor cables and coils is developed. This model is necessary to solve critical issues in coated conductor ac...

  1. Layout-Driven Post-Placement Techniques for Temperature Reduction and Thermal Gradient Minimization

    DEFF Research Database (Denmark)

    Liu, Wei; Calimera, Andrea; Macii, Alberto

    2013-01-01

    With the continuing scaling of CMOS technology, on-chip temperature and thermal-induced variations have become a major design concern. To effectively limit the high temperature in a chip equipped with a cost-effective cooling system, thermal specific approaches, besides low power techniques, are ...

  2. Extreme Temperature Radiation Tolerant Instrumentation for Nuclear Thermal Propulsion Engines, Phase I

    Data.gov (United States)

    National Aeronautics and Space Administration — The objective of this proposal is to develop and commercialize a high reliability, high temperature smart neutron flux sensor for NASA Nuclear Thermal Propulsion...

  3. Glass transition temperatures of liquid prepolymers obtained by thermal penetrometry

    Science.gov (United States)

    Potts, J. E., Jr.; Ashcraft, A. C.

    1973-01-01

    Thermal penetrometry is experimental technique for detecting temperature at which frozen prepolymer becomes soft enough to be pierced by weighted penetrometer needle; temperature at which this occurs is called penetration temperature. Apparatus used to obtain penetration temperatures can be set up largely from standard parts.

  4. High-Temperature Piezoelectric Sensing

    Directory of Open Access Journals (Sweden)

    Xiaoning Jiang

    2013-12-01

    Full Text Available Piezoelectric sensing is of increasing interest for high-temperature applications in aerospace, automotive, power plants and material processing due to its low cost, compact sensor size and simple signal conditioning, in comparison with other high-temperature sensing techniques. This paper presented an overview of high-temperature piezoelectric sensing techniques. Firstly, different types of high-temperature piezoelectric single crystals, electrode materials, and their pros and cons are discussed. Secondly, recent work on high-temperature piezoelectric sensors including accelerometer, surface acoustic wave sensor, ultrasound transducer, acoustic emission sensor, gas sensor, and pressure sensor for temperatures up to 1,250 °C were reviewed. Finally, discussions of existing challenges and future work for high-temperature piezoelectric sensing are presented.

  5. An experimental study of thermal comfort at different combinations of air and mean radiant temperature

    DEFF Research Database (Denmark)

    Simone, Angela; Olesen, Bjarne W.

    2009-01-01

    It is often discussed if a person prefers a low air temperature (ta) and a high mean radiant temperature (tr), vice-versa or it does not matter as long as the operative temperature is acceptable. One of the hypotheses is that it does not matter for thermal comfort but for perceived air quality......, a lower air temperature is preferred. This paper presents an experimental study with 30 human subjects exposed to three different combinations of air- and mean radiant temperature with an operative temperature around 23 °C. The subjects gave subjective evaluations of thermal comfort and perceived air...... quality during the experiments. The PMV-index gave a good estimation of thermal sensation vote (TSV) when the air and mean radiant temperature were the same. In the environment with different air- and mean radiant temperatures, a thermal comfort evaluation shows an error up to 1 scale unit on the 7-point...

  6. High temperature superconductor accelerator magnets

    NARCIS (Netherlands)

    van Nugteren, J.

    2016-01-01

    For future particle accelerators bending dipoles are considered with magnetic fields exceeding 20T. This can only be achieved using high temperature superconductors (HTS). These exhibit different properties from classical low temperature superconductors and still require significant research and

  7. DETERMINATION OF TEMPERATURE DISTRIBUTION FOR ANNULAR FINS WITH TEMPERATURE DEPENDENT THERMAL CONDUCTIVITY BY HPM

    Directory of Open Access Journals (Sweden)

    Davood Domairry Ganji

    2011-01-01

    Full Text Available In this paper, homotopy perturbation method has been used to evaluate the temperature distribution of annular fin with temperature-dependent thermal conductivity and to determine the temperature distribution within the fin. This method is useful and practical for solving the nonlinear heat transfer equation, which is associated with variable thermal conductivity condition. The homotopy perturbation method provides an approximate analytical solution in the form of an infinite power series. The annular fin heat transfer rate with temperature-dependent thermal conductivity has been obtained as a function of thermo-geometric fin parameter and the thermal conductivity parameter describing the variation of the thermal conductivity.

  8. Medium Deep High Temperature Heat Storage

    Science.gov (United States)

    Bär, Kristian; Rühaak, Wolfram; Schulte, Daniel; Welsch, Bastian; Chauhan, Swarup; Homuth, Sebastian; Sass, Ingo

    2015-04-01

    Heating of buildings requires more than 25 % of the total end energy consumption in Germany. Shallow geothermal systems for indirect use as well as shallow geothermal heat storage systems like aquifer thermal energy storage (ATES) or borehole thermal energy storage (BTES) typically provide low exergy heat. The temperature levels and ranges typically require a coupling with heat pumps. By storing hot water from solar panels or thermal power stations with temperatures of up to 110 °C a medium deep high temperature heat storage (MDHTS) can be operated on relatively high temperature levels of more than 45 °C. Storage depths of 500 m to 1,500 m below surface avoid conflicts with groundwater use for drinking water or other purposes. Permeability is typically also decreasing with greater depth; especially in the crystalline basement therefore conduction becomes the dominant heat transport process. Solar-thermal charging of a MDHTS is a very beneficial option for supplying heat in urban and rural systems. Feasibility and design criteria of different system configurations (depth, distance and number of BHE) are discussed. One system is designed to store and supply heat (300 kW) for an office building. The required boreholes are located in granodioritic bedrock. Resulting from this setup several challenges have to be addressed. The drilling and completion has to be planned carefully under consideration of the geological and tectonical situation at the specific site.

  9. High-Thermal-Conductivity Fabrics

    Science.gov (United States)

    Chibante, L. P. Felipe

    2012-01-01

    Heat management with common textiles such as nylon and spandex is hindered by the poor thermal conductivity from the skin surface to cooling surfaces. This innovation showed marked improvement in thermal conductivity of the individual fibers and tubing, as well as components assembled from them. The problem is centered on improving the heat removal of the liquid-cooled ventilation garments (LCVGs) used by astronauts. The current design uses an extensive network of water-cooling tubes that introduces bulkiness and discomfort, and increases fatigue. Range of motion and ease of movement are affected as well. The current technology is the same as developed during the Apollo program of the 1960s. Tubing material is hand-threaded through a spandex/nylon mesh layer, in a series of loops throughout the torso and limbs such that there is close, form-fitting contact with the user. Usually, there is a nylon liner layer to improve comfort. Circulating water is chilled by an external heat exchanger (sublimator). The purpose of this innovation is to produce new LCVG components with improved thermal conductivity. This was addressed using nanocomposite engineering incorporating high-thermalconductivity nanoscale fillers in the fabric and tubing components. Specifically, carbon nanotubes were added using normal processing methods such as thermoplastic melt mixing (compounding twin screw extruder) and downstream processing (fiber spinning, tubing extrusion). Fibers were produced as yarns and woven into fabric cloths. The application of isotropic nanofillers can be modeled using a modified Nielsen Model for conductive fillers in a matrix based on Einstein s viscosity model. This is a drop-in technology with no additional equipment needed. The loading is limited by the ability to maintain adequate dispersion. Undispersed materials will plug filtering screens in processing equipment. Generally, the viscosity increases were acceptable, and allowed the filled polymers to still be

  10. Assessment of optical performance of three non-tracking, non-imaging, external compound parabolic concentrators designed for high temperature solar thermal collector units

    OpenAIRE

    Cisneros, Jesus

    2010-01-01

    The objective of this thesis is to perform a preliminary optical assessment of the external compound parabolic concentrator (XCPC) component in three concentrating solar thermal units. Each solar thermal unit consists an optical element (the non-imaging concentrating reflector) and a thermal element (the evacuated glass tube solar absorber). The three concentrating solar thermal units discussed in this work are DEWAR 58, a direct flow all-glass dewar, DEWAR 47 an indirect flow ...

  11. Design and modeling of low temperature solar thermal power station

    International Nuclear Information System (INIS)

    Shankar Ganesh, N.; Srinivas, T.

    2012-01-01

    Highlights: ► The optimum conditions are different for efficiency and power conditions. ► The current model works up to a maximum separator temperature of 150 °C. ► The turbine concentration influences the high pressure. ► High solar beam radiation and optimized cycle conditions give low collector cost. -- Abstract: During the heat recovery in a Kalina cycle, a binary aqua–ammonia mixture changes its state from liquid to vapor, the more volatile ammonia vaporizes first and then the water starts vaporization to match temperature profile of the hot fluid. In the present work, a low temperature Kalina cycle has been investigated to optimize the heat recovery from solar thermal collectors. Hot fluid coming from solar parabolic trough collector with vacuum tubes is used to generate ammonia rich vapor in a boiler for power generation. The turbine inlet conditions are optimized to match the variable hot fluid temperature with the intermittent nature of the solar radiation. The key parameters discussed in this study are strong solution concentration, separator temperature which affects the hot fluid inlet temperature and turbine ammonia concentration. Solar parabolic collector system with vacuum tubes has been designed at the optimized power plant conditions. This work can be used in the selection of boiler, separator and turbine conditions to maximize the power output as well as efficiency of power generation system. The current model results a maximum limit temperature for separator as 150 °C at the Indian climatic conditions. A maximum specific power of 105 kW per kg/s of working fluid can be obtained at 80% of strong solution concentration with 140 °C separator temperature. The corresponding plant and cycle efficiencies are 5.25% and 13% respectively. But the maximum efficiencies of 6% and 15% can be obtained respectively for plant and Kalina cycle at 150 °C of separator temperature.

  12. Bulk temperature measurement in thermally striped pipe flows

    International Nuclear Information System (INIS)

    Lemure, N.; Olvera, J.R.; Ruggles, A.E.

    1995-12-01

    The hot leg flows in some Pressurized Water Reactor (PWR) designs have a temperature distribution across the pipe cross-section. This condition is often referred to as a thermally striped flow. Here, the bulk temperature measurement of pipe flows with thermal striping is explored. An experiment is conducted to examine the feasibility of using temperature measurements on the external surface of the pipe to estimate the bulk temperature of the flow. Simple mixing models are used to characterize the development of the temperature profile in the flow. Simple averaging techniques and Backward Propagating Neural Net are used to predict bulk temperature from the external temperature measurements. Accurate bulk temperatures can be predicted. However, some temperature distributions in the flow effectively mask the bulk temperature from the wall and cause significant error in the bulk temperature predicted using this technique

  13. Thermal infrared remote sensing of water temperature in riverine landscapes

    Science.gov (United States)

    Handcock, Rebecca N.; Torgersen, Christian E.; Cherkauer, Keith A.; Gillespie, Alan R.; Klement, Tockner; Faux, Russell N.; Tan, Jing; Carbonneau, Patrice E.; Piégay, Hervé

    2012-01-01

    Water temperature in riverine landscapes is an important regional indicator of water quality that is influenced by both ground- and surface-water inputs, and indirectly by land use in the surrounding watershed (Brown and Krygier, 1970; Beschta et al., 1987; Chen et al., 1998; Poole and Berman, 2001).Coldwater fishes such as salmon and trout are sensitive to elevated water temperature; therefore, water temperature must meet management guidelines and quality standards, which aim to create a healthy environment for endangered populations (McCullough et al., 2009). For example, in the USA, the Environmental Protection Agency (EPA) has established water quality standards to identify specific temperature criteria to protect coldwater fishes (Environmental Protection Agency, 2003). Trout and salmon can survive in cool-water refugia even when temperatures at other measurement locations are at or above the recommended maximums (Ebersole et al., 2001; Baird and Krueger, 2003; High et al., 2006). Spatially extensive measurements of water temperature are necessary to locate these refugia, to identify the location of ground- and surface-water inputs to the river channel, and to identify thermal pollution sources. Regional assessment of water temperature in streams and rivers has been limited by sparse sampling in both space and time. Water temperature has typically been measured using a network of widely distributed instream gages, which record the temporal change of the bulk, or kinetic, temperature of the water (Tk) at specific locations. For example, the State of Washington (USA) recorded water quality conditions at 76 stations within the Puget Lowlands eco region, which contains 12,721 km of streams and rivers (Washington Department of Ecology, 1998). Such gages are sparsely distributed, are typically located only in larger streams and rivers, and give limited information about the spatial distribution of water temperature.

  14. Performance Limits and Opportunities for Low Temperature Thermal Desalination

    OpenAIRE

    Nayar, Kishor Govind; Swaminathan, Jaichander; Warsinger, David Elan Martin; Lienhard, John H.

    2015-01-01

    Conventional low temperature thermal desalination (LTTD) uses ocean thermal temperature gradients to drive a single stage flash distillation process to produce pure water from seawater. While the temperature difference in the ocean drives distillation and provides cooling in LTTD, external electrical energy is required to pump the water streams from the ocean and to maintain a near vacuum in the flash chamber. In this work, an LTTD process from the literature is compared against, the thermody...

  15. Temperature-gated thermal rectifier for active heat flow control.

    Science.gov (United States)

    Zhu, Jia; Hippalgaonkar, Kedar; Shen, Sheng; Wang, Kevin; Abate, Yohannes; Lee, Sangwook; Wu, Junqiao; Yin, Xiaobo; Majumdar, Arun; Zhang, Xiang

    2014-08-13

    Active heat flow control is essential for broad applications of heating, cooling, and energy conversion. Like electronic devices developed for the control of electric power, it is very desirable to develop advanced all-thermal solid-state devices that actively control heat flow without consuming other forms of energy. Here we demonstrate temperature-gated thermal rectification using vanadium dioxide beams in which the environmental temperature actively modulates asymmetric heat flow. In this three terminal device, there are two switchable states, which can be regulated by global heating. In the "Rectifier" state, we observe up to 28% thermal rectification. In the "Resistor" state, the thermal rectification is significantly suppressed (Rectifier state. This temperature-gated rectifier can have substantial implications ranging from autonomous thermal management of heating and cooling systems to efficient thermal energy conversion and storage.

  16. Regional differences in temperature sensation and thermal comfort in humans.

    Science.gov (United States)

    Nakamura, Mayumi; Yoda, Tamae; Crawshaw, Larry I; Yasuhara, Saki; Saito, Yasuyo; Kasuga, Momoko; Nagashima, Kei; Kanosue, Kazuyuki

    2008-12-01

    Sensations evoked by thermal stimulation (temperature-related sensations) can be divided into two categories, "temperature sensation" and "thermal comfort." Although several studies have investigated regional differences in temperature sensation, less is known about the sensitivity differences in thermal comfort for the various body regions. In the present study, we examined regional differences in temperature-related sensations with special attention to thermal comfort. Healthy male subjects sitting in an environment of mild heat or cold were locally cooled or warmed with water-perfused stimulators. Areas stimulated were the face, chest, abdomen, and thigh. Temperature sensation and thermal comfort of the stimulated areas were reported by the subjects, as was whole body thermal comfort. During mild heat exposure, facial cooling was most comfortable and facial warming was most uncomfortable. On the other hand, during mild cold exposure, neither warming nor cooling of the face had a major effect. The chest and abdomen had characteristics opposite to those of the face. Local warming of the chest and abdomen did produce a strong comfort sensation during whole body cold exposure. The thermal comfort seen in this study suggests that if given the chance, humans would preferentially cool the head in the heat, and they would maintain the warmth of the trunk areas in the cold. The qualitative differences seen in thermal comfort for the various areas cannot be explained solely by the density or properties of the peripheral thermal receptors and thus must reflect processing mechanisms in the central nervous system.

  17. A high temperature reactor for ship propulsion

    International Nuclear Information System (INIS)

    Lobet, P.; Seigel, R.; Thompson, A.C.; Beadnell, R.M.; Beeley, P.A.

    2002-01-01

    The initial thermal hydraulic and physics design of a high temperature gas cooled reactor for ship propulsion is described. The choice of thermodynamic cycle and thermal power is made to suit the marine application. Several configurations of a Helium cooled, Graphite moderated reactor are then analysed using the WIMS and MONK codes from AEA Technology. Two geometries of fuel elements formed using micro spheres in prismatic blocks, and various arrangements of control rods and poison rods are examined. Reactivity calculations through life are made and a pattern of rod insertion to flatten the flux is proposed and analysed. Thermal hydraulic calculations are made to find maximum fuel temperature under high power with optimized flow distribution. Maximum temperature after loss of flow and temperatures in the reactor vessel are also computed. The temperatures are significantly below the known limits for the type of fuel proposed. It is concluded that the reactor can provide the required power and lifetime between refueling within likely space and weight constraints. (author)

  18. The thermal power of aluminum nitride at temperatures between 1350 and 1650 deg C in argon and nitrogen atmospheres. Ph.D. Thesis - Rhine-Westphalia High School at Aachen

    Science.gov (United States)

    Fischer, W. A.; Schuh, B.

    1978-01-01

    The test apparatus for measuring the thermal voltage of aluminum nitride for temperature differences of up to + or - 60 C between 1350 and 1650 C is described. The thermal power and its homogeneous proportion are determined and the heat transfer of the migration ions resulting from the homogeneous thermal power is calculated. The conduction mechanism in aluminum nitride is discussed.

  19. Study Progress of Physiological Responses in High Temperature Environment

    Science.gov (United States)

    Li, K.; Zheng, G. Z.; Bu, W. T.; Wang, Y. J.; Lu, Y. Z.

    2017-10-01

    Certain workers are exposed to high temperatures for a long time. Heat stress will result in a series of physiological responses, and cause adverse effects on the health and safety of workers. This paper summarizes the physiological changes of cardiovascular system, core temperature, skin temperature, water-electrolyte metabolism, alimentary system, neuroendocrine system, reaction time and thermal fatigue in high temperature environments. It can provide a theoretical guidance for labor safety in high temperature environment.

  20. High Temperature Superconductor Resonator Detectors

    Data.gov (United States)

    National Aeronautics and Space Administration — High Temperature Superconductor (HTS) infrared detectors were studied for years but never matured sufficiently for infusion into instruments. Several recent...

  1. Thermal Behavior of Cylindrical Buckling Restrained Braces at Elevated Temperatures

    Directory of Open Access Journals (Sweden)

    Elnaz Talebi

    2014-01-01

    Full Text Available The primary focus of this investigation was to analyze sequentially coupled nonlinear thermal stress, using a three-dimensional model. It was meant to shed light on the behavior of Buckling Restraint Brace (BRB elements with circular cross section, at elevated temperature. Such bracing systems were comprised of a cylindrical steel core encased in a strong concrete-filled steel hollow casing. A debonding agent was rubbed on the core’s surface to avoid shear stress transition to the restraining system. The numerical model was verified by the analytical solutions developed by the other researchers. Performance of BRB system under seismic loading at ambient temperature has been well documented. However, its performance in case of fire has yet to be explored. This study showed that the failure of brace may be attributed to material strength reduction and high compressive forces, both due to temperature rise. Furthermore, limiting temperatures in the linear behavior of steel casing and concrete in BRB element for both numerical and analytical simulations were about 196°C and 225°C, respectively. Finally it is concluded that the performance of BRB at elevated temperatures was the same as that seen at room temperature; that is, the steel core yields prior to the restraining system.

  2. Thermal behavior of cylindrical buckling restrained braces at elevated temperatures.

    Science.gov (United States)

    Talebi, Elnaz; Tahir, Mahmood Md; Zahmatkesh, Farshad; Yasreen, Airil; Mirza, Jahangir

    2014-01-01

    The primary focus of this investigation was to analyze sequentially coupled nonlinear thermal stress, using a three-dimensional model. It was meant to shed light on the behavior of Buckling Restraint Brace (BRB) elements with circular cross section, at elevated temperature. Such bracing systems were comprised of a cylindrical steel core encased in a strong concrete-filled steel hollow casing. A debonding agent was rubbed on the core's surface to avoid shear stress transition to the restraining system. The numerical model was verified by the analytical solutions developed by the other researchers. Performance of BRB system under seismic loading at ambient temperature has been well documented. However, its performance in case of fire has yet to be explored. This study showed that the failure of brace may be attributed to material strength reduction and high compressive forces, both due to temperature rise. Furthermore, limiting temperatures in the linear behavior of steel casing and concrete in BRB element for both numerical and analytical simulations were about 196°C and 225°C, respectively. Finally it is concluded that the performance of BRB at elevated temperatures was the same as that seen at room temperature; that is, the steel core yields prior to the restraining system.

  3. High Temperature Superconductor Machine Prototype

    DEFF Research Database (Denmark)

    Mijatovic, Nenad; Jensen, Bogi Bech; Træholt, Chresten

    2011-01-01

    A versatile testing platform for a High Temperature Superconductor (HTS) machine has been constructed. The stationary HTS field winding can carry up to 10 coils and it is operated at a temperature of 77K. The rotating armature is at room temperature. Test results and performance for the HTS field...

  4. High thermal expansion, sealing glass

    Science.gov (United States)

    Brow, R.K.; Kovacic, L.

    1993-11-16

    A glass composition is described for hermetically sealing to high thermal expansion materials such as aluminum alloys, stainless steels, copper, and copper/beryllium alloys, which includes between about 10 and about 25 mole percent Na[sub 2]O, between about 10 and about 25 mole percent K[sub 2]O, between about 5 and about 15 mole percent Al[sub 2]O[sub 3], between about 35 and about 50 mole percent P[sub 2]O[sub 5] and between about 5 and about 15 mole percent of one of PbO, BaO, and mixtures thereof. The composition, which may also include between 0 and about 5 mole percent Fe[sub 2]O[sub 3] and between 0 and about 10 mole percent B[sub 2]O[sub 3], has a thermal expansion coefficient in a range of between about 160 and 210[times]10[sup [minus]7]/C and a dissolution rate in a range of between about 2[times]10[sup [minus]7] and 2[times]10[sup [minus]9]g/cm[sup 2]-min. This composition is suitable to hermetically seal to metallic electrical components which will be subjected to humid environments over an extended period of time.

  5. Nonmonotonic Thermal Casimir Force from Geometry-Temperature Interplay

    International Nuclear Information System (INIS)

    Weber, Alexej; Gies, Holger

    2010-01-01

    The geometry dependence of Casimir forces is significantly more pronounced in the presence of thermal fluctuations due to a generic geometry-temperature interplay. We show that the thermal force for standard sphere-plate or cylinder-plate geometries develops a nonmonotonic behavior already in the simple case of a fluctuating Dirichlet scalar. In particular, the attractive thermal force can increase for increasing distances below a critical temperature. This anomalous behavior is triggered by a reweighting of relevant fluctuations on the scale of the thermal wavelength. The essence of the phenomenon becomes transparent within the worldline picture of the Casimir effect.

  6. Development of temperature related thermal neutron scattering database for MCNP

    International Nuclear Information System (INIS)

    Mei Longwei; Cai Xiangzhou; Jiang Dazhen; Chen Jingen; Guo Wei

    2013-01-01

    Based on ENDF/B-Ⅶ neutron library, the thermal neutron scattering library S(α, β) for molten salt reactor moderators was developed. The temperatures of this library were chose as the characteristic temperature of the molten salt reactor. The cross section of the thermal neutron scattering of ACE format was investigated, and this library was also validated by the benchmarks of ICSBEP. The uncertainties shown in the validation were in reasonable range when compared with the thermal neutron scattering library tmccs which included in the MCNP data library. It was proved that the thermal neutron scattering library processed in this study could be used in the molten salt reactor design. (authors)

  7. Ceramic/Metal Composites with Positive Temperature Dependence of Thermal Conductivity

    International Nuclear Information System (INIS)

    Li Jianhui; Yu Qi; Sun Wei; Zhang Rui; Wang Ke; Li Jingfeng; Ichigozaki, Daisuke

    2013-01-01

    Most materials show decreasing thermal conductivity with increasing temperature, but an opposite temperature dependence of thermal conductivity is required for some industrial applications. The present work was conducted with a motivation to develop composite materials with a positive temperature dependence of thermal conductivity. ZrO 2 / stainless steel powders (304L) composite, with 3% stearic acid, was prepared by normal sintering under the protecting of Ar after mixing by mechanical ball milling technique. With the 304L content increasing from 10% to 20%, the thermal conductivity values increased. For all samples, the thermal conductivity in the temperature range of room temperature to 700 °C decreased with temperature below 300 °C, and then began to increase. The increasing thermal conductivity of the composites (within the high temperature range was attributed to the difference of the thermal conductivity and thermal expansion coefficient between ZrO 2 ceramic and 304L stainless steel powders. Two simple models were also used to estimate the thermal conductivity of the composites, which were in good agreement with the experiment results.

  8. Potentialities of high temperature reactors (HTR)

    International Nuclear Information System (INIS)

    Hittner, D.

    2001-01-01

    This articles reviews the assets of high temperature reactors concerning the amount of radioactive wastes produced. 2 factors favors HTR-type reactors: high thermal efficiency and high burn-ups. The high thermal efficiency is due to the high temperature of the coolant, in the case of the GT-MHR project (a cooperation between General Atomic, Minatom, Framatome, and Fuji Electric) designed to burn Russian military plutonium, the expected yield will be 47% with an outlet helium temperature of 850 Celsius degrees. The high temperature of the coolant favors a lot of uses of the heat generated by the reactor: urban heating, chemical processes, or desalination of sea water.The use of a HTR-type reactor in a co-generating way can value up to 90% of the energy produced. The high burn-up is due to the technology of HTR-type fuel that is based on encapsulation of fuel balls with heat-resisting materials. The nuclear fuel of Fort-Saint-Vrain unit (Usa) has reached values of burn-ups from 100.000 to 120.000 MWj/t. It is shown that the quantity of unloaded spent fuel can be divided by 4 for the same amount of electricity produced, in the case of the GT-MHR project in comparison with a light water reactor. (A.C.)

  9. Thermal and Hygric Expansion of High Performance Concrete

    OpenAIRE

    J. Toman; R. Černý

    2001-01-01

    The linear thermal expansion coefficient of two types of high performance concrete was measured in the temperature range from 20 °C to 1000 °C, and the linear hygric expansion coefficient was determined in the moisture range from dry material to saturation water content. Comparative methods were applied for measurements of both coefficients. The experimental results show that both the effect of temperature on the values of linear thermal expansion coefficients and the effect of moisture on th...

  10. Fluid temperatures: Modeling the thermal regime of a river network

    Science.gov (United States)

    Rhonda Mazza; Ashley Steel

    2017-01-01

    Water temperature drives the complex food web of a river network. Aquatic organisms hatch, feed, and reproduce in thermal niches within the tributaries and mainstem that comprise the river network. Changes in water temperature can synchronize or asynchronize the timing of their life stages throughout the year. The water temperature fluctuates over time and place,...

  11. Preferred temperature and thermal breadth of birds wintering in peninsular Spain: the limited effect of temperature on species distribution

    Directory of Open Access Journals (Sweden)

    Luis M. Carrascal

    2016-07-01

    Full Text Available Background. The availability of environmental energy, as measured by temperature, is expected to limit the abundance and distribution of endotherms wintering at temperate latitudes. A prediction of this hypothesis is that birds should attain their highest abundances in warmer areas. However, there may be a spatial mismatch between species preferred habitats and species preferred temperatures, so some species might end-up wintering in sub-optimal thermal environments. Methods. We model the influence of minimum winter temperature on the relative abundance of 106 terrestrial bird species wintering in peninsular Spain, at 10 ×10 km2 resolution, using 95%-quantile regressions. We analyze general trends across species on the shape of the response curves, the environmental preferred temperature (at which the species abundance is maximized, the mean temperature in the area of distribution and the thermal breadth (area under the abundance-temperature curve. Results. Temperature explains a low proportion of variation in abundance. The most significant effect is on limiting the maximum potential abundance of species. Considering this upper-limit response, there is a large interspecific variability on the thermal preferences and specialization of species. Overall, there is a preponderance of positive relationships between species abundance and temperature; on average, species attain their maximum abundances in areas 1.9 °C warmer than the average temperature available in peninsular Spain. The mean temperature in the area of distribution is lower than the thermal preferences of the species. Discussion. Many species prefer the warmest areas to overwinter, which suggests that temperature imposes important restrictions to birds wintering in the Iberian Peninsula. However, one third of species overwinter in locations colder than their thermal preferences, probably reflecting the interaction between habitat and thermal requirements. There is a high inter

  12. Gaseous byproducts from high-temperature thermal conversion elemental analysis of nitrogen- and sulfur-bearing compounds with considerations for δ2H and δ18O analyses.

    Science.gov (United States)

    Hunsinger, Glendon B; Tipple, Christopher A; Stern, Libby A

    2013-07-30

    High-temperature, conversion-reduction (HTC) systems convert hydrogen and oxygen in materials into H2 and CO for δ(2)H and δ(18)O measurements by isotope ratio mass spectrometry. HTC of nitrogen- and sulfur-bearing materials produces unintended byproduct gases that could affect isotope analyses by: (1) allowing isotope exchange reactions downstream of the HTC reactor, (2) creating isobaric or co-elution interferences, and (3) causing deterioration of the chromatography. This study characterizes these HTC byproducts. A HTC system (ThermoFinnigan TC/EA) was directly connected to a gas chromatograph/quadrupole mass spectrometer in scan mode (m/z 8 to 88) to identify the volatile products generated by HTC at conversion temperatures of 1350 °C and 1450 °C for a range of nitrogen- and sulfur-bearing solids [keratin powder, horse hair, caffeine, ammonium nitrate, potassium nitrate, ammonium sulfate, urea, and three nitrated organic explosives (PETN, RDX, and TNT)]. The prominent HTC byproduct gases include carbon dioxide, hydrogen cyanide, methane, acetylene, and water for all nitrogen-bearing compounds, as well as carbon disulfide, carbonyl sulfide, and hydrogen sulfide for sulfur-bearing compounds. The 1450 °C reactor temperature reduced the abundance of most byproduct gases, but increased the significant byproduct, hydrogen cyanide. Inclusion of a post-reactor chemical trap containing Ascarite II and Sicapent, in series, eliminated the majority of byproducts. This study identified numerous gaseous HTC byproducts. The potential adverse effects of these gases on isotope ratio analyses are unknown but may be mitigated by higher HTC reactor temperatures and purifying the products with a purge-and-trap system or with chemical traps. Published in 2013. This article is a U.S. Government work and is in the public domain in the USA.

  13. On high temperature strength of carbon steels

    International Nuclear Information System (INIS)

    Ichinose, Hiroyuki; Tamura, Manabu; Kanero, Takahiro; Ihara, Yoshihito

    1977-01-01

    In the steels for high temperature use, the oxidation resistance is regarded as important, but carbon steels show enough oxidation resistance to be used continuously at the temperature up to 500 deg. C if the strength is left out of consideration, and up to 450 deg. C even when the strength is taken into account. Moreover, the production is easy, the workability and weldability are good, and the price is cheap in carbon steels as compared with alloy steels. In the boilers for large thermal power stations, 0.15-0.30% C steels are used for reheater tubes, main feed water tubes, steam headers, wall water tubes, economizer tubes, bypass pipings and others, and they account for 70% of all steel materials used for the boilers of 350 MW class and 30% in 1000 MW class. The JIS standard for the carbon steels for high temperature use and the related standards in foreign countries are shown. The high temperature strength of carbon steels changes according to the trace elements, melting and heat treatment as well as the main compositions of C, Si and Mn. Al and N affect the high temperature strength largely. The characteristics of carbon steels after the heating for hours, the factors controlling the microstructure and high temperature strength, and the measures to improve the high temperature strength of carbon steels are explained. (Kako, I.)

  14. Apparatus for accurately measuring high temperatures

    Science.gov (United States)

    Smith, D.D.

    The present invention is a thermometer used for measuring furnace temperatures in the range of about 1800/sup 0/ to 2700/sup 0/C. The thermometer comprises a broadband multicolor thermal radiation sensor positioned to be in optical alignment with the end of a blackbody sight tube extending into the furnace. A valve-shutter arrangement is positioned between the radiation sensor and the sight tube and a chamber for containing a charge of high pressure gas is positioned between the valve-shutter arrangement and the radiation sensor. A momentary opening of the valve shutter arrangement allows a pulse of the high gas to purge the sight tube of air-borne thermal radiation contaminants which permits the radiation sensor to accurately measure the thermal radiation emanating from the end of the sight tube.

  15. Hydrogen Production from Nuclear Energy via High Temperature Electrolysis

    International Nuclear Information System (INIS)

    James E. O'Brien; Carl M. Stoots; J. Stephen Herring; Grant L. Hawkes

    2006-01-01

    This paper presents the technical case for high-temperature nuclear hydrogen production. A general thermodynamic analysis of hydrogen production based on high-temperature thermal water splitting processes is presented. Specific details of hydrogen production based on high-temperature electrolysis are also provided, including results of recent experiments performed at the Idaho National Laboratory. Based on these results, high-temperature electrolysis appears to be a promising technology for efficient large-scale hydrogen production

  16. Evaluation of the effects of thermal annealing temperature and high-k dielectrics on amorphous InGaZnO thin films by using pseudo-MOS transistors

    International Nuclear Information System (INIS)

    Lee, Se-Won; Cho, Won-Ju

    2012-01-01

    The effects of annealing temperatures and high-k gate dielectric materials on the amorphous In-Ga-Zn-O thin-film transistors (a-IGZO TFTs) were investigated using pseudo-metal-oxide semiconductor transistors (Ψ-MOSFETs), a method without conventional source/drain (S/D) layer deposition. Annealing of the a-IGZO film was carried out at 150 - 900 .deg. C in a N 2 ambient for 30 min. As the annealing temperature was increased, the electrical characteristics of Ψ-MOSFETs on a-IGZO were drastically improved. However, when the annealing temperature exceeded 700 .deg. C, a deterioration of the MOS parameters was observed, including a shift of the threshold voltage (V th ) in a negative direction, an increase in the subthreshold slope (SS) and hysteresis, a decrease in the field effect mobility (μ FE ), an increase in the trap density (N t ), and a decrease in the on/off ratio. Meanwhile, the high-k gate dielectrics enhanced the performance of a-IGZO Ψ-MOSFETs. The ZrO 2 gate dielectrics particularly exhibited excellent characteristics in terms of SS (128 mV/dec), μ FE (10.2 cm -2 /V·s), N t (1.1 x 10 12 cm -2 ), and on/off ratio (5.3 x 10 6 ). Accordingly, the Ψ-MOSFET structure is a useful method for rapid evaluation of the effects of the process and the material on a-IGZO TFTs without a conventional S/D layer deposition.

  17. Low-temperature thermal properties of yttrium and lutetium dodecaborides

    International Nuclear Information System (INIS)

    Czopnik, A; Shitsevalova, N; Pluzhnikov, V; Krivchikov, A; Paderno, Yu; Onuki, Y

    2005-01-01

    The heat capacity (C p ) and dilatation (α) of YB 12 and LuB 12 are studied. C p of the zone-melted YB 12 tricrystal is measured in the range 2.5-70 K, of the zone-melted LuB 12 single crystal in the range 0.6-70 K, and of the LuB 12 powder sample in the range 4.3-300 K; α of the zone-melted YB 12 tricrystal and LuB 12 single crystals is measured in the range 5-200 K. At low temperatures a negative thermal expansion (NTE) is revealed for both compounds: for YB 12 at 50-70 K, for LuB 12 at 10-20 K and 60-130 K. Their high-temperature NTE is a consequence of nearly non-interacting freely oscillating metal ions (Einstein oscillators) in cavities of a simple cubic rigid Debye lattice formed by B 12 cage units. The Einstein temperatures are ∼254 and ∼164 K, and the Debye temperatures are ∼1040 K and ∼1190 K for YB 12 and LuB 12 respectively. The LuB 12 low-temperature NTE is connected with an induced low-energy defect mode. The YB 12 superconducting transition has not been detected up to 2.5 K

  18. Electrothermal efficiency, temperature and thermal conductivity of ...

    Indian Academy of Sciences (India)

    Different types of DC plasma torches operating at power levels between 2 to 6000 kW [1] ... systems and showed that η was higher for the LPPS system. ..... [8] M I Boulos, P Fauchais and E Pfender, Thermal plasmas fundamentals and ...

  19. Using Upper Extremity Skin Temperatures to Assess Thermal Comfort in Office Buildings in Changsha, China

    Directory of Open Access Journals (Sweden)

    Zhibin Wu

    2017-09-01

    Full Text Available Existing thermal comfort field studies are mainly focused on the relationship between the indoor physical environment and the thermal comfort. In numerous chamber experiments, physiological parameters were adopted to assess thermal comfort, but the experiments’ conclusions may not represent a realistic thermal environment due to the highly controlled thermal environment and few occupants. This paper focuses on determining the relationships between upper extremity skin temperatures (i.e., finger, wrist, hand and forearm and the indoor thermal comfort. Also, the applicability of predicting thermal comfort by using upper extremity skin temperatures was explored. Field studies were performed in office buildings equipped with split air-conditioning (SAC located in the hot summer and cold winter (HSCW climate zone of China during the summer of 2016. Psychological responses of occupants were recorded and physical and physiological factors were measured simultaneously. Standard effective temperature (SET* was used to incorporate the effect of humidity and air velocity on thermal comfort. The results indicate that upper extremity skin temperatures are good indicators for predicting thermal sensation, and could be used to assess the thermal comfort in terms of physiological mechanism. In addition, the neutral temperature was 24.7 °C and the upper limit for 80% acceptability was 28.2 °C in SET*.

  20. Using Upper Extremity Skin Temperatures to Assess Thermal Comfort in Office Buildings in Changsha, China.

    Science.gov (United States)

    Wu, Zhibin; Li, Nianping; Cui, Haijiao; Peng, Jinqing; Chen, Haowen; Liu, Penglong

    2017-09-21

    Existing thermal comfort field studies are mainly focused on the relationship between the indoor physical environment and the thermal comfort. In numerous chamber experiments, physiological parameters were adopted to assess thermal comfort, but the experiments' conclusions may not represent a realistic thermal environment due to the highly controlled thermal environment and few occupants. This paper focuses on determining the relationships between upper extremity skin temperatures (i.e., finger, wrist, hand and forearm) and the indoor thermal comfort. Also, the applicability of predicting thermal comfort by using upper extremity skin temperatures was explored. Field studies were performed in office buildings equipped with split air-conditioning (SAC) located in the hot summer and cold winter (HSCW) climate zone of China during the summer of 2016. Psychological responses of occupants were recorded and physical and physiological factors were measured simultaneously. Standard effective temperature (SET*) was used to incorporate the effect of humidity and air velocity on thermal comfort. The results indicate that upper extremity skin temperatures are good indicators for predicting thermal sensation, and could be used to assess the thermal comfort in terms of physiological mechanism. In addition, the neutral temperature was 24.7 °C and the upper limit for 80% acceptability was 28.2 °C in SET*.

  1. Microscale solid-state thermal diodes enabling ambient temperature thermal circuits for energy applications

    KAUST Repository

    Wang, Song

    2017-05-10

    Thermal diodes, or devices that transport thermal energy asymmetrically, analogous to electrical diodes, hold promise for thermal energy harvesting and conservation, as well as for phononics or information processing. The junction of a phase change material and phase invariant material can form a thermal diode; however, there are limited constituent materials available for a given target temperature, particularly near ambient. In this work, we demonstrate that a micro and nanoporous polystyrene foam can house a paraffin-based phase change material, fused to PMMA, to produce mechanically robust, solid-state thermal diodes capable of ambient operation with Young\\'s moduli larger than 11.5 MPa and 55.2 MPa above and below the melting transition point, respectively. Moreover, the composites show significant changes in thermal conductivity above and below the melting point of the constituent paraffin and rectification that is well-described by our previous theory and the Maxwell–Eucken model. Maximum thermal rectifications range from 1.18 to 1.34. We show that such devices perform reliably enough to operate in thermal diode bridges, dynamic thermal circuits capable of transforming oscillating temperature inputs into single polarity temperature differences – analogous to an electrical diode bridge with widespread implications for transient thermal energy harvesting and conservation. Overall, our approach yields mechanically robust, solid-state thermal diodes capable of engineering design from a mathematical model of phase change and thermal transport, with implications for energy harvesting.

  2. Thermal Stability of W-xRe/TiC/SiC Systems (x=0, 5 and 25 at % Re) at High Temperature

    International Nuclear Information System (INIS)

    Roger, J.; Le Petitcorps, Y.; Roger, J.; Audubert, F.

    2009-01-01

    During this work, we examined the effect of an additional TiC interlayer between SiC and the W-xRe substrate (x=0.5 and 25 at% Re). The first aim was to limit the chemical reaction leading to the formation of the silicide W 5 Si 3 and the carbide WC. Samples were prepared by hot-filament rapid chemical vapour deposition. The TiC layer thicknesses were between 2 and about 100 μm. After thermal treatment between 1573 and 1873 K, the samples were characterized and revealed the existence of a reaction whatever thickness was used, with predominant formation of the carbide W 2 C. This is the first effect induced by the addition of TiC; the reaction scheme is deeply modified. Another main fact is the role played by the TiC thickness. Depending on layer's size, we can have a variable reduction of the reaction zone with the existence of a maximum effect. Indeed, it appears that the total elimination of the reaction at the highest temperatures is hardly conceivable owing to the intrinsic diffusion of carbon atoms into the TiC. In many cases, a reaction occurs with the formation of the carbide W 2 C. It appears during our investigations that, at above 1673 K, molten silicon is obtained between the SiC and the TiC. In comparison with the data obtained at 1573 K, the presence of this molten phase induces a strong limitation for carbon diffusion, even for thin TiC layers. Nevertheless, it seems impossible to reach an efficiency of 100% above 1673 K. This aim is probably more accessible at lower temperatures according to extrapolations at 1573 K. The third and last parameter considered herein was the role played by the concentration of rhenium into the substrate. According to our results, the addition of this metal is quite beneficial; a more-important effect is clearly obtained, especially for the thinner TiC layer, the maximal effect appearing to be slightly more pronounced when the rhenium concentration increases. We can deduce from this study that TiC is an efficient

  3. Negative thermal expansion of lithium aluminosilicate ceramics at cryogenic temperatures

    International Nuclear Information System (INIS)

    Garcia-Moreno, Olga; Fernandez, Adolfo; Khainakov, Sergei; Torrecillas, Ramon

    2010-01-01

    Five lithium aluminosilicate compositions of the LAS system have been synthesized and sintered. The coefficient of thermal expansion of the sintered samples has been studied down to cryogenic conditions. The data presented here under cryogenic conditions will be of value in the future design of new composite materials with very low thermal expansion values. The variation in thermal expansion properties with composition and sintering temperature was studied and is discussed in relation to composition and crystal structure.

  4. Modelling and analysis of radial thermal stresses and temperature ...

    African Journals Online (AJOL)

    user

    The temperature field, heat transfer rate and thermal stresses were investigated with numerical simulation models using FORTRAN FE (finite element) software. ...... specific heats, International Communications in Heat and Mass Transfer, Vol.

  5. Thermal and electrical conductivities of high purity tantalum

    International Nuclear Information System (INIS)

    Archer, S.L.

    1978-01-01

    The electrical resistivity and thermal conductivity of three high purity tantalum samples have been measured as functions of temperature over a temperature range of 5K to 65K. Sample purities ranged up to a resistivity ratio of 1714. The highest purity sample had a residual resistivity of .76 x 10 -10 OMEGA-m. The intrinsic resistivity varied as T 3 . 9 from 10K to 31K. The thermal conductivity of the purest sample had a maximum of 840 W/mK at 9.8K. The intrinsic thermal resistivity varied as T 2 . 4 from 10K to 35K. At low temperatures electrons were scattered primarily by impurities and by phonons with both interband and intraband transitions observed. The electrical and thermal resistivity is departed from Matthiessen's rule at low temperatures

  6. Thermal interface pastes nanostructured for high performance

    Science.gov (United States)

    Lin, Chuangang

    thermal paste that is particularly effective for smooth surfaces was obtained by using nanoclay platelets (obtained by organic modification and subsequent chemical exfoliation) as the solid component. The superiority of the nanoclay paste for smooth surfaces is attributed to the submicrometer bond line thickness. Electrically nonconductive high-performance thermal paste was obtained by using either fumed alumina or fumed zinc oxide. The nonconductivity serves to avoid short circuiting in the electronic application environment. The fumed oxides are as effective as carbon black, but are advantageous in their electrical nonconductivity. Without fuming, the oxides are less effective. The silane coating on fumed metal oxides helps. Electrically nonconductive thermal pastes have also been attained using carbon as the thermally conductive solid component. Either fumed alumina or nanoclay is used to break the electrical connectivity of the carbon in the paste to obtain electrical nonconductivity. Among the nanostrucutred pastes developed in this dissertation research, the nanoclay (0.6 vol.%) paste is recommended for smooth surfaces. With the overall performance for smooth and rough surfaces considered, the carbon black (Tokai, 15 vol.%) paste is recommended. Carbon black (Tokai) is more effective than carbon black (Cabot), due to its small aggregate size. All the pastes developed are much more effective than carbon nanotube arrays investigated by others. The rheological behavior of the thermal pastes was studied under strain sweep, frequency sweep, steady state flow and temperature ramping. In the absence of a solid component, the vehicle is Newtonian and fluid-like. In the presence of a solid component, the paste is a Bingham plastic that exhibits shear thinning and mainly solid-like behavior. The addition of antioxidants enhances the solid-like character, increases the yield stress, the plastic viscosity and the bond line thickness, and decreases the thermal contact

  7. Energy and indoor temperature consequences of adative thermal comfort standards

    NARCIS (Netherlands)

    Centnerova, L.; Hensen, J.L.M.

    2001-01-01

    The intent of the presented study was to quantify the implications for energy demand of indoor temperature requirements based on a proposed adaptive thermal comfort standard (7) relative to a more traditional thermal comfort approach. The study focuses on a typical office situation in a moderate

  8. Low upper-shelf toughness, high transition temperature test insert in HSST [Heavy Section Steel Technology] PTSE-2 [Pressurized Thermal Shock Experiment-2] vessel and wide plate test specimens: Final report

    International Nuclear Information System (INIS)

    Domian, H.A.

    1987-02-01

    A piece of A387, Grade 22 Class 2 (2-1/4 Cr - 1 Mo) steel plate specially heat treated to produce low upper-shelf (LUS) toughness and high transition temperature was installed in the side wall of Heavy Section Steel Technology (HHST) vessel V-8. This vessel is to be tested by the Oak Ridge National Laboratory (ORNL) in the Pressurized Thermal Shock Experiment-2 (PTSE-2) project of the HSST program. Comparable pieces of the plate were made into six wide plate specimens and other samples. These samples underwent tensile tests, Charpy tests, and J-integral tests. The results of these tests are given in this report

  9. Extreme temperature stability of thermally insulating graphene-mesoporous-silicon nanocomposite

    Science.gov (United States)

    Kolhatkar, Gitanjali; Boucherif, Abderraouf; Rahim Boucherif, Abderrahim; Dupuy, Arthur; Fréchette, Luc G.; Arès, Richard; Ruediger, Andreas

    2018-04-01

    We demonstrate the thermal stability and thermal insulation of graphene-mesoporous-silicon nanocomposites (GPSNC). By comparing the morphology of GPSNC carbonized at 650 °C as-formed to that after annealing, we show that this nanocomposite remains stable at temperatures as high as 1050 °C due to the presence of a few monolayers of graphene coating on the pore walls. This does not only make this material compatible with most thermal processes but also suggests applications in harsh high temperature environments. The thermal conductivity of GPSNCs carbonized at temperatures in the 500 °C-800 °C range is determined through Raman spectroscopy measurements. They indicate that the thermal conductivity of the composite is lower than that of silicon, with a value of 13 ± 1 W mK-1 at room temperature, and not affected by the thin graphene layer, suggesting a role of the high concentration of carbon related-defects as indicated by the high intensity of the D-band compared to G-band of the Raman spectra. This morphological stability at high temperature combined with a high thermal insulation make GPSNC a promising candidate for a broad range of applications including microelectromechanical systems and thermal effect microsystems such as flow sensors or IR detectors. Finally, at 120 °C, the thermal conductivity remains equal to that at room temperature, attesting to the potential of using our nanocomposite in devices that operate at high temperatures such as microreactors for distributed chemical conversion, solid oxide fuel cells, thermoelectric devices or thermal micromotors.

  10. Temperature and Thermal Stress Analysis of Refractory Products

    Directory of Open Access Journals (Sweden)

    Shaoyang Shi

    2013-05-01

    Full Text Available Firstly current status of temperature and thermal stress research of refractory product at home and aboard are analyzed. Finite element model of two classical refractory products is building by using APDL language. Distribution law of temperature and thermal stress of two typical refractory products-ladles and tundish are analyzed and their structures are optimized. Stress of optimal structure is dropped obviously, and operation life is increased effectively.

  11. Identification of temperature-dependent thermal conductivity and experimental verification

    International Nuclear Information System (INIS)

    Pan, Weizhen; Yi, Fajun; Zhu, Yanwei; Meng, Songhe

    2016-01-01

    A modified Levenberg–Marquardt method (LMM) for the identification of temperature-dependent thermal conductivity is proposed; the experiment and structure of the specimen for identification are also designed. The temperature-dependent thermal conductivities of copper C10200 and brass C28000 are identified to verify the effectiveness of the proposed identification method. The comparison between identified results and the measured data of laser flash diffusivity apparatus indicates the fine consistency and potential usage of the proposed method. (paper)

  12. Use of a thermal imager for snow pit temperatures

    Directory of Open Access Journals (Sweden)

    C. Shea

    2012-03-01

    Full Text Available Weak snow of interest to avalanche forecasting often forms and changes as thin layers. Thermometers, the current field technology for measuring the temperature gradients across such layers – and for thus estimating the expected vapour flux and future type of crystal metamorphism – are difficult to use at distances shorter than 1 cm. In contrast, a thermal imager can provide thousands of simultaneous temperature measurements across small distances with better accuracy. However, a thermal imager only senses the exposed surface, complicating its methods for access and accuracy of buried temperatures. This paper presents methods for exposing buried layers on pit walls and using a thermal imager to measure temperatures on these walls, correct for lens effects with snow, adjust temperature gradients, adjust time exposed, and calculate temperature gradients over millimetre distances. We find lens error on temperature gradients to be on the order of 0.03 °C between image centre and corners. We find temperature gradient change over time to usually decrease – as expected with atmospheric equalization as a strong effect. Case studies including thermal images and visual macro photographs of crystals, collected during the 2010–2011 winter, demonstrate large temperature differences over millimetre-scale distances that are consistent with observed kinetic metamorphism. Further study is needed to use absolute temperatures independently of supporting gradient data.

  13. The elevated temperature and thermal shock fracture toughnesses of nuclear pressure vessel steel

    International Nuclear Information System (INIS)

    Hirano, Kazumi; Kobayashi, Hideo; Nakazawa, Hajime; Nara, Atsushi.

    1979-01-01

    Thermal shock experiments were conducted on nuclear pressure vessel steel A533 Grade B Class 1. Elastic-plastic fracture toughness tests were carried out within the same high temperature range of the thermal shock experiment and the relation between stretched zone width, SZW and J-integral was clarified. An elastic-plastic thermal shock fracture toughness value. J sub(tsc) was evaluated from a critical value of stretched zone width, SZW sub(tsc) at the initiation of thermal shock fracture by using the relation between SZW and J. The J sub(tsc) value was compared with elastic-plastic fracture toughness values, J sub( ic), and the difference between the J sub(tsc) and J sub( ic) values was discussed. The results obtained are summarized as follows; (1) The relation between SZW and J before the initiation of stable crack growth in fracture toughness test at a high temperature can be expressed by the following equation regardless of test temperature, SZW = 95(J/E), where E is Young's modulus. (2) Elevated temperature fracture toughness values ranging from room temperature to 400 0 C are nearly constant regardless of test temperature. It is confirmed that upper shelf fracture toughness exists. (3) Thermal shock fracture toughness is smaller than elevated temperature fracture toughness within the same high temperature range of thermal shock experiment. (author)

  14. Thermal characteristics of rocks for high-level waste repository

    International Nuclear Information System (INIS)

    Shimooka, Kenji; Ishizaki, Kanjiro; Okamoto, Masamichi; Kumata, Masahiro; Araki, Kunio; Amano, Hiroshi

    1980-12-01

    Heat released by the radioactive decay of high-level waste in an underground repository causes a long term thermal disturbance in the surrounding rock mass. Several rocks constituting geological formations in Japan were gathered and specific heat, thermal conductivity, thermal expansion coefficient and compressive strength were measured. Thermal analysis and chemical analysis were also carried out. It was found that volcanic rocks, i.e. Andesite and Basalt had the most favorable thermal characteristics up to around 1000 0 C and plutonic rock, i.e. Granite had also favorable characteristics under 573 0 C, transition temperature of quartz. Other igneous rocks, i.