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Sample records for high temperature embrittlement

  1. Shear Melting and High Temperature Embrittlement: Theory and Application to Machining Titanium

    OpenAIRE

    Ackland, Graeme J; Healy, Con; Koch, Sascha; Brunke, Florian; Siemers, Carsten

    2016-01-01

    We describe a dynamical phase transition occurring within a shear band at high temperature and under extremely high shear rates. With increasing temperature, dislocation deformation and grain boundary sliding are supplanted by amorphization in a highly localized nanoscale band, which allows for massive strain and fracture. The mechanism is similar to shear melting and leads to liquid metal embrittlement at high temperature. From simulation, we find that the necessary conditions are lack of di...

  2. Shear melting and high temperature embrittlement: theory and application to machining titanium.

    Science.gov (United States)

    Healy, Con; Koch, Sascha; Siemers, Carsten; Mukherji, Debashis; Ackland, Graeme J

    2015-04-24

    We describe a dynamical phase transition occurring within a shear band at high temperature and under extremely high shear rates. With increasing temperature, dislocation deformation and grain boundary sliding are supplanted by amorphization in a highly localized nanoscale band, which allows for massive strain and fracture. The mechanism is similar to shear melting and leads to liquid metal embrittlement at high temperature. From simulation, we find that the necessary conditions are lack of dislocation slip systems, low thermal conduction, and temperature near the melting point. The first two are exhibited by bcc titanium alloys, and we show that the final one can be achieved experimentally by adding low-melting-point elements: specifically, we use insoluble rare earth metals (REMs). Under high shear, the REM becomes mixed with the titanium, lowering the melting point within the shear band and triggering the shear-melting transition. This in turn generates heat which remains localized in the shear band due to poor heat conduction. The material fractures along the shear band. We show how to utilize this transition in the creation of new titanium-based alloys with improved machinability.

  3. Low Temperature Irradiation Embrittlement of Reactor Pressure Vessel Steels

    Energy Technology Data Exchange (ETDEWEB)

    Wang, Jy-An John [Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States)

    2015-08-01

    The embrittlement trend curve development project for HFIR reactor pressure vessel (RPV) steels was carried out with three major tasks. Which are (1) data collection to match that used in HFIR steel embrittlement trend published in 1994 Journal Nuclear Material by Remec et. al, (2) new embrittlement data of A212B steel that are not included in earlier HFIR RPV trend curve, and (3) the adjustment of nil-ductility-transition temperature (NDTT) shift data with the consideration of the irradiation temperature effect. An updated HFIR RPV steel embrittlement trend curve was developed, as described below. NDTT( C) = 23.85 log(x) + 203.3 log (x) + 434.7, with 2- uncertainty of 34.6 C, where parameter x is referred to total dpa. The developed update HFIR RPV embrittlement trend curve has higher embrittlement rate compared to that of the trend curve developed in 1994.

  4. High Fluency Low Flux Embrittlement Models of LWR Reactor Pressure Vessel Embrittlement and a Supporting Database from the UCSB ATR-2 Irradiation Experiment

    Energy Technology Data Exchange (ETDEWEB)

    Odette, G. Robert [Univ. of California, Santa Barbara, CA (United States)

    2017-01-24

    Reactor pressure vessel embrittlement may limit the lifetime of light water reactors (LWR). Embrittlement is primarily caused by formation of nano-scale precipitates, which cause hardening and a subsequent increase in the ductile-to-brittle transition temperature of the steel. While the effect of Cu has historically been the largest research focus of RPV embrittlement, there is increasing evidence that Mn, Ni and Si are likely to have a large effect at higher fluence, where Mn-Ni-Si precipitates can form, even in the absence of Cu. Therefore, extending RPV lifetimes will require a thorough understanding of both precipitation and embrittlement at higher fluences than have ever been observed in a power reactor. To address this issue, test reactors that irradiate materials at higher neutron fluxes than power reactors are used. These experiments at high neutron flux can reach extended life neutron fluences in only months or several years. The drawback of these test irradiations is that they add additional complexity to interpreting the data, as the irradiation flux also plays a role into both precipitate formation and irradiation hardening and embrittlement. This report focuses on developing a database of both microstructure and mechanical property data to better understand the effect of flux. In addition, a previously developed model that enables the comparison of data taken over a range of neutron flux is discussed.

  5. Irradiation embrittlement of reactor pressure vessel steel at very high neutron fluence

    Science.gov (United States)

    Kryukov, A.; Debarberis, L.; von Estorff, U.; Gillemot, F.; Oszvald, F.

    2012-03-01

    For the prediction of radiation embrittlement of RPV materials beyond the NPP design time the analysis of research data and extended surveillance data up to a fluence ˜23 × 1020 cm-2 (E > 0.5 MeV) has been carried out. The experimental data used for the analysis are extracted from the International Database of RPV materials. Key irradiation embrittlement mechanisms, direct matrix damage, precipitation and element segregation have been considered. The essential part of the analysis concerns the assessment of irradiation embrittlement of WWER-440 steel irradiated with very high neutron fluence. The analysis of several surveillance sets irradiated at a fluence up to 23 × 1020 cm-2 (E > 0.5 MeV) has been performed. The effect of the main influencing chemical elements phosphorus and copper has been verified up to a fluence of 4.6 × 1020 cm-2 (E > 0.5 MeV). The data are indicating good radiation stability, in terms of the Charpy transition temperature shift and yield strength increase for steels with relatively low concentrations of copper and phosphorus. The linear dependence between ΔTk and ΔRp0.2 can be an evidence of strengthening mechanisms of irradiation embrittlement and absence of non-hardening embrittlement even at very high neutron fluence.

  6. Hydrogen Environment Embrittlement on Austenitic Stainless Steels from Room Temperature to Low Temperatures

    Science.gov (United States)

    Ogata, Toshio

    2015-12-01

    Hydrogen environment embrittlement (HEE) on austenitic stainless steels SUS304, 304L, and 316L in the high pressure hydrogen gas was evaluated from ambient temperature to 20 K using a very simple mechanical properties testing procedure. In the method, the high- pressure hydrogen environment is produced just inside the hole in the specimen and the specimen is cooled in a cooled-alcohol dewar and a cryostat with a GM refrigerator. The effect of HEE was observed in tensile properties, especially at lower temperatures, and fatigue properties at higher stress level but almost no effect around the stress level of yield strength where almost no strain-induced martensite was produced. So, no effect of HEE on austenitic stainless steels unless the amount of the ferrite phase is small.

  7. Studies of low temperature, low flux radiation embrittlement of nuclear reactor structural materials. Final report

    Energy Technology Data Exchange (ETDEWEB)

    Odette, G.R.; Lucas, G.E.

    1993-06-01

    There are several existing research programs which have components pertinent to the issue of low flux/low temperature embrittlement; in particular, examination of the Shippingport shield tank which has been exposed to low flux and relatively low temperature is being performed by ANL, and evaluation of low temperature embrittlement in A508 and A533B steels in support of the HTGR is currently being performed by ORNL. However, these programs are not specifically directed at the broader issue of low flux/low temperature embrittlement in a range of structural steels. Hence, the authors coordinated their effort with these programs so that their investigations were complementary to existing programs, and they focused on a set of materials which expand the data base developed in these programs. In particular, the authors have investigated embrittlement phenomena in steels that are similar to those used in support structure.

  8. Hydrogen Embrittlement

    Science.gov (United States)

    Woods, Stephen; Lee, Jonathan A.

    2016-01-01

    hydrogen embrittlement. The effects of hydrogen gas on mechanical properties such as tensile strength, ductility, fracture, low and high cycle fatigue, crack growth rate, and creep rupture are analyzed with respect to the general trends established from the HEE index values. It is observed that the severity of HE effects is also influenced by environmental factors such as pressure, temperature, and hydrogen gas purity. The severity of HE effects is also influenced by material factors such as surface finish, heat treatment, and product forms, compositions, grain direction, and crystal orientations.

  9. Development of Press Hardening Steel with High Resistance to Hydrogen Embrittlement

    Science.gov (United States)

    Bian, Jian; Mohrbacher, Hardy; Lu, Hongzhou; Wang, Wenjun

    Press hardening has become the state-of-art technology in the car body manufacturing to enhance safety standard and to reduce CO2 emission of new vehicles. However the delayed cracking due to hydrogen embrittlement remains to be a critical issue. Generally press hardening steel is susceptible to hydrogen embrittlement due to ultra-high strength and martensitic microstructure. The hydrogen charging tests clearly demonstrate that only a few ppm of diffusible hydrogen is sufficient to cause such embrittlement. Currently the hydrogen embrittlement cannot be detected in the press hardened components and the embitteled components could collapse in the crash situation with fatal consequences arisen through dramatic loss in both strength and ductility. This paper introduces a new metallurgical solution to increase the resistance to hydrogen embrittlement of conventional press hardening steel based on 22MnB5 by Nb microalloying. In the hydrogen embrittlement and permeation tests the impact of Nb microalloying on the hydrogen embrittlement behavior was investigated under different hydrogen charging conditions and constant load. The test results revealed that Nb addition increases the resistance to hydrogen embrittlement due to reduced hydrogen diffusivity. The focus of this paper is to investigate the precipitation behavior of microalloying elements by using TEM and STEM and to find out the mechanisms leading to higher performance against hydrogen embrittlement of Nb alloyed steels.

  10. Empirical Method to Estimate Hydrogen Embrittlement of Metals as a Function of Hydrogen Gas Pressure at Constant Temperature

    Science.gov (United States)

    Lee, Jonathan A.

    2010-01-01

    High pressure Hydrogen (H) gas has been known to have a deleterious effect on the mechanical properties of certain metals, particularly, the notched tensile strength, fracture toughness and ductility. The ratio of these properties in Hydrogen as compared to Helium or Air is called the Hydrogen Environment Embrittlement (HEE) Index, which is a useful method to classify the severity of H embrittlement and to aid in the material screening and selection for safety usage H gas environment. A comprehensive world-wide database compilation, in the past 50 years, has shown that the HEE index is mostly collected at two conveniently high H pressure points of 5 ksi and 10 ksi near room temperature. Since H embrittlement is directly related to pressure, the lack of HEE index at other pressure points has posed a technical problem for the designers to select appropriate materials at a specific H pressure for various applications in aerospace, alternate and renewable energy sectors for an emerging hydrogen economy. Based on the Power-Law mathematical relationship, an empirical method to accurately predict the HEE index, as a function of H pressure at constant temperature, is presented with a brief review on Sievert's law for gas-metal absorption.

  11. Mechanisms of radiation embrittlement of VVER-1000 RPV steel at irradiation temperatures of (50-400)°C

    Science.gov (United States)

    Kuleshova, E. A.; Gurovich, B. A.; Bukina, Z. V.; Frolov, A. S.; Maltsev, D. A.; Krikun, E. V.; Zhurko, D. A.; Zhuchkov, G. M.

    2017-07-01

    This work summarizes and analyzes our recent research results on the effect of irradiation temperature within the range of (50-400)°C on microstructure and properties of 15Kh2NMFAA class 1 steel (VVER-1000 reactor pressure vessel (RPV) base metal). The paper considers the influence of accelerated irradiation with different temperature up to different fluences on the carbide and irradiation-induced phases, radiation defects, yield strength changes and critical brittleness temperature shift (ΔTK) as well as on changes of the fraction of brittle intergranular fracture and segregation processes in the steel. Low temperature irradiation resulted solely in formation of radiation defects - dislocation loops of high number density, the latter increased with increase in irradiation temperature while their size decreased. In this regard high embrittlement rate observed at low temperature irradiation is only due to the hardening mechanism of radiation embrittlement. Accelerated irradiation at VVER-1000 RPV operating temperature (∼300 °C) caused formation of radiation-induced precipitates and dislocation loops, as well as some increase in phosphorus grain boundary segregation. The observed ΔTK shift being within the regulatory curve for VVER-1000 RPV base metal is due to both hardening and non-hardening mechanisms of radiation embrittlement. Irradiation at elevated temperature caused more intense phosphorus grain boundary segregation, but no formation of radiation-induced precipitates or dislocation loops in contrast to irradiation at 300 °C. Carbide transformations observed only after irradiation at 400 °C caused increase in yield strength and, along with a contribution of the non-hardening mechanism, resulted in the lowest ΔTK shift in the studied range of irradiation temperature and fluence.

  12. Studies of low temperature, low flux radiation embrittlement of nuclear reactor structural materials. Final report

    Energy Technology Data Exchange (ETDEWEB)

    Odette, G.R.; Lucas, G.E.

    1998-09-02

    A large matrix of simple alloys and complex commercial type steels was irradiated over a range of fluxes at 60 C up to a fast fluence of about 3 {times} 10{sup 22} n/m{sup 2}. Combined with data in the literature, these results show a negligible effect of flux on irradiation hardening in the range of 2 {times} 10{sup 13} to 5 {times} 10{sup 18} n/m{sup 2}-s. This observation lends indirect support to the proposal that the accelerated embrittlement in the High Flux Isotope Reactor surveillance steels was due to an anomalously high level of damage from gamma rays. A weak dependence of hardening on a number of elements, including copper, nickel, phosphorus, molybdenum and manganese, can be described by a simple empirical chemistry factor. Particular combinations of elements resulted in hardening differences of up to about 60% in the complex commercial type steels and up to about 100% in simple model alloys. Direct effects of microstructure appear to be minimal. Hardening varies with the square root of fluence above a threshold around 4 {times} 10{sup 20} n/m{sup 2}. The results suggest that low temperature hardening is dominated by local intracascade processes leading to the formation of small defect-solute clusters/complexes. The observed hardening corresponds to nominal maximum end-of-life transition temperature shifts in support structure steels of about 120 C.

  13. Low-temperature embrittlement and fracture of metals with different crystal lattices – Dislocation mechanisms

    Directory of Open Access Journals (Sweden)

    V.M. Chernov

    2016-12-01

    Full Text Available The state of a low-temperature embrittlement (cold brittleness and dislocation mechanisms for formation of the temperature of a ductile-brittle transition and brittle fracture of metals (mono- and polycrystals with various crystal lattices (BCC, FCC, HCP are considered. The conditions for their formation connected with a stress-deformed state and strength (low temperature yield strength as well as the fracture breaking stress and mobility of dislocations in the top of a crack of the fractured metal are determined. These conditions can be met for BCC and some HCP metals in the initial state (without irradiation and after a low-temperature damaging (neutron irradiation. These conditions are not met for FCC and many HCP metals. In the process of the damaging (neutron irradiation such conditions are not met also and the state of low-temperature embrittlement of metals is absent (suppressed due to arising various radiation dynamic processes, which increase the mobility of dislocations and worsen the strength characteristics.

  14. Aging and Embrittlement of High Fluence Stainless Steels

    Energy Technology Data Exchange (ETDEWEB)

    Was, gary; Jiao, Zhijie; der ven, Anton Van; Bruemmer, Stephen; Edwards, Dan

    2012-12-31

    Irradiation of austenitic stainless steels results in the formation of dislocation loops, stacking fault tetrahedral, Ni-Si clusters and radiation-induced segregation (RIS). Of these features, it is the formation of precipitates which is most likely to impact the mechanical integrity at high dose. Unlike dislocation loops and RIS, precipitates exhibit an incubation period that can extend from 10 to 46 dpa, above which the cluster composition changes and a separate phase, (G-phase) forms. Both neutron and heavy ion irradiation showed that these clusters develop slowly and continue to evolve beyond 100 dpa. Overall, this work shows that the irradiated microstructure features produced by heavy ion irradiation are remarkably comparable in nature to those produced by neutron irradiation at much lower dose rates. The use of a temperature shift to account for the higher damage rate in heavy ion irradiation results in a fairly good match in the dislocation loop microstructure and the precipitate microstructure in austenitic stainless steels. Both irradiations also show segregation of the same elements and in the same directions, but to achieve comparable magnitudes, heavy ion irradiation must be conducted at a much higher temperature than that which produces a match with loops and precipitates. First-principles modeling has confirmed that the formation of Ni-Si precipitates under irradiation is likely caused by supersaturation of solute to defect sinks caused by highly correlated diffusion of Ni and Si. Thus, the formation and evolution of Ni-Si precipitates at high dose in austenitic stainless steels containing Si is inevitable.

  15. Alloy and composition dependence of hydrogen embrittlement susceptibility in high-strength steel fasteners

    Science.gov (United States)

    Brahimi, S. V.; Yue, S.; Sriraman, K. R.

    2017-06-01

    High-strength steel fasteners characterized by tensile strengths above 1100 MPa are often used in critical applications where a failure can have catastrophic consequences. Preventing hydrogen embrittlement (HE) failure is a fundamental concern implicating the entire fastener supply chain. Research is typically conducted under idealized conditions that cannot be translated into know-how prescribed in fastener industry standards and practices. Additionally, inconsistencies and even contradictions in fastener industry standards have led to much confusion and many preventable or misdiagnosed fastener failures. HE susceptibility is a function of the material condition, which is comprehensively described by the metallurgical and mechanical properties. Material strength has a first-order effect on HE susceptibility, which increases significantly above 1200 MPa and is characterized by a ductile-brittle transition. For a given concentration of hydrogen and at equal strength, the critical strength above which the ductile-brittle transition begins can vary due to second-order effects of chemistry, tempering temperature and sub-microstructure. Additionally, non-homogeneity of the metallurgical structure resulting from poorly controlled heat treatment, impurities and non-metallic inclusions can increase HE susceptibility of steel in ways that are measurable but unpredictable. Below 1200 MPa, non-conforming quality is often the root cause of real-life failures. This article is part of the themed issue 'The challenges of hydrogen and metals'.

  16. Intermediate temperature embrittlement of one new Ni-26W-6Cr based superalloy for molten salt reactors

    Energy Technology Data Exchange (ETDEWEB)

    Jiang, Li [Thorium Molten Salts Reactor Center, Shanghai Institute of Applied Physics, Chinese Academy of Sciences, Shanghai 201800 (China); University of Chinese Academy of Science, Beijing 100049 (China); Ye, Xiangxi [University of Chinese Academy of Science, Beijing 100049 (China); Cui, Chuanyong [Institute of Metal Research, Chinese Academy of Sciences, Shenyang 110016 (China); Huang, Hefei; Leng, Bin [Thorium Molten Salts Reactor Center, Shanghai Institute of Applied Physics, Chinese Academy of Sciences, Shanghai 201800 (China); Li, Zhijun, E-mail: lizhijun@sinap.ac.cn [Thorium Molten Salts Reactor Center, Shanghai Institute of Applied Physics, Chinese Academy of Sciences, Shanghai 201800 (China); Zhou, Xingtai [Thorium Molten Salts Reactor Center, Shanghai Institute of Applied Physics, Chinese Academy of Sciences, Shanghai 201800 (China)

    2016-06-21

    Ni-26W-6Cr based superalloy is considered a potential structure material for the molten salt reactors due to its high strength and good compatibility with the fluoride salt. In the present work, the temperature dependence of the tensile behavior of the alloy was studied by tensile tests in the temperature range of 25–850 °C. This alloy exhibited a good ductility at RT and 450 °C, a ductility minimum from 650 to 750 °C and an intermediate ductility at 850 °C. TEM and EBSD characterization was performed on specimens tested at three typical temperature points (RT, 650 °C and 850 °C) to determine the deformation and fracture mechanisms accounting for the intermediate temperature embrittlement. At RT, the grain boundaries can accommodate enough dislocations to provide compatibility of the sliding between adjacent grains, then M{sub 6}C carbides act as crack origins and cause the fracture. In case of 650 °C, the grain boundaries cannot withstand the local stress even if only a small number of dislocation pile-ups exist. The premature cracks at grain boundaries impede the development of plastic deformation from single slips to multiple ones and cause the low ductility. If tested at 850 °C, the fracture process is retarded by the dynamic recovery and local dynamic recrystallization at crack tips.

  17. Effects of 1000 C oxide surfaces on room temperature aqueous corrosion and environmental embrittlement of iron aluminides

    Energy Technology Data Exchange (ETDEWEB)

    Buchanan, R.A.; Perrin, R.L. [Univ. of Tennessee, Knoxville, TN (United States). Dept. of Materials Science and Engineering

    1997-12-01

    Results of electrochemical aqueous-corrosion studies at room temperature indicate that retained in-service-type high-temperature surface oxides (1000 C in air for 24 hours) on FA-129, FAL and FAL-Mo iron aluminides cause major reductions in pitting corrosion resistance in a mild acid-chloride solution designed to simulate aggressive atmospheric corrosion. Removal of the oxides by mechanical grinding restores the corrosion resistance. In a more aggressive sodium tetrathionate solution, designed to simulate an aqueous environment contaminated by sulfur-bearing combustion products, only active corrosion occurs for both the 1000 C oxide and mechanically cleaned surfaces at FAL. Results of slow-strain-rate stress-corrosion-cracking tests on FA-129, FAL and FAL-Mo at free-corrosion and hydrogen-charging potentials in the mild acid chloride solution indicate somewhat higher ductilities (on the order of 50%) for the 1000 C oxides retard the penetration of hydrogen into the metal substrates and, consequently, are beneficial in terms of improving resistance to environmental embrittlement. In the aggressive sodium tetrathionate solution, no differences are observed in the ductilities produced by the 1000 C oxide and mechanically cleaned surfaces for FAL.

  18. The hydrogen embrittlement of Ni-Cr-Fe alloys

    Energy Technology Data Exchange (ETDEWEB)

    Symons, D.M.

    1996-12-31

    It has been proposed that the stress corrosion cracking (SCC) of nickel-based alloys in low-temperature hydrogenated water is due to hydrogen embrittlement. The purpose of this work was to investigate the role of chromium on hydrogen embrittlement of Ni-Cr-Fe alloys and thus develop a better understanding of the low-temperature SCC phenomenon. The effect of chromium on the hydrogen embrittlement was examined using tensile tests followed by material evaluation via scanning electron microscopy and light optical microscopy. Four alloys were prepared with chromium contents ranging from 6 wt. percent to 35 wt. percent. In the noncharged condition, ductility, as measured by the percent elongation or reduction in area, increased as the alloy chromium content increased. Hydrogen appeared to have only minor effects on the mechanical properties of the low chromium alloys. The addition of hydrogen had a marked effect on the ductility of the higher chromium alloys. In the 26% chromium alloy, the elongation to failure was reduced from 53% to 14% with a change in fracture mode from ductile dimple to intergranular failure. A maximum in embrittlement was observed in the 26% Cr alloy. The maximum in embrittlement coincided with the minimum in stacking-fault energy. It is proposed that the increased hydrogen embrittlement in the high-chromium alloys is due to increased slip planarity caused by the low stacking-fault energy. Slip planarity did not appear to affect the fracture of the noncharged specimens.

  19. A cohesive zone model to simulate the hydrogen embrittlement effect on a high-strength steel

    Directory of Open Access Journals (Sweden)

    G. Gobbi

    2016-01-01

    Full Text Available The present work aims to model the fracture mechanical behavior of a high-strength low carbon steel, AISI 4130 operating in hydrogen contaminated environment. The study deals with the development of 2D finite element cohesive zone model (CZM reproducing a toughness test. Along the symmetry plane over the crack path of a C(T specimen a zero thickness layer of cohesive elements are implemented in order to simulate the crack propagation. The main feature of this kind of model is the definition of a traction-separation law (TSL that reproduces the constitutive response of the material inside to the cohesive elements. Starting from a TSL calibrated on hydrogen non-contaminated material, the embrittlement effect is simulated by reducing the cohesive energy according to the total hydrogen content including the lattice sites (NILS and the trapped amount. In this perspective, the proposed model consists of three steps of simulations. First step evaluates the hydrostatic pressure. It drives the initial hydrogen concentration assigned in the second step, a mass diffusion analysis, defining in this way the contribution of hydrogen moving across the interstitial lattice sites. The final stress analysis, allows getting the total hydrogen content, including the trapped amount, and evaluating the new crack initiation and propagation due to the hydrogen presence. The model is implemented in both plane strain and plane stress configurations; results are compared in the discussion. From the analyses, it resulted that hydrogen is located only into lattice sites and not in traps, and that the considered steel experiences a high hydrogen susceptibility. By the proposed procedure, the developed numerical model seems a reliable and quick tool able to estimate the mechanical behavior of steels in presence of hydrogen.

  20. Fuel Manifold Resists Embrittlement by Hydrogen

    Science.gov (United States)

    Adams, T.

    1986-01-01

    Completely-cast hydrogen-compatible alloy preferable to protective plating. Complexity of plating, welding, and brazing unnecessary if hydrogen-compatible alloy used for entire casting instead of protective overlay. Parts exposed to high-pressure hydrogen made immune to hydrogen embrittlement if fabricated from new alloy, Incoly 903 (or equivalent). Material strong and compatible with hydrogen at all temperatures and adapted for outlet manifold of Space Shuttle main combustion chamber.

  1. Effect of strain rate and temperature on the susceptibility of 304 austenitic stainless steel to hydrogen embrittlement

    Energy Technology Data Exchange (ETDEWEB)

    El Shawesh, F. [Petroleum Research Center, Tripoli (Libyan Arab Jamahiriya)

    1998-12-31

    Cathodic charging of notched 304 austenitic stainless steel specimens was carried out in aqueous solution of 1N H{sub 2}SO{sub 4}, containing 250 mg/l NaAsO{sub 2}, at room temperature and 70 {+-} 2 C while undergoing tensile straining over a wide range of crosshead speed (833 {micro}m/s, 83 {micro}m/s, 8.3 {micro}m/s, 833 nm/s, 83 nm/s and 9.8 nm/s). Test at room temperature 22 {+-} 2 C resulted in a marked reduction in the elongation to fracture ratio (Esol/Eair) by reducing the crosshead speed. However, little reduction was observed in the stress to fracture ratio ({sigma}sol/{sigma}air). Quasi cleavage and intergranular fractures where the predominant failure modes when tests were carried out at low crosshead speeds, The extent of these modes of fracture was observed to increase by reducing the crosshead speed. Cathodic charging of 304 austenitic stainless steel at 70 {+-} 2 C caused less reduction in the elongation to fracture ratio compared to the tests carried out at room temperature. Consistent with the room temperature test results, the reduction in the elongation to fracture ratio was found to increase with reduced crosshead speed. However, restoration in the elongation to fracture ratio was exhibited by 304 austenitic stainless steel specimens tested at the lowest crosshead speed (9.8 nm/s). These results are in good agreement with the finding that hydrogen embrittlement is temperature and strain dependent. Quasi cleavage fracture associated with the plastic deformation was the predominant failure mode exhibited by 304 austenitic stainless steel specimens tested at 70 {+-} 2 C at low crosshead speeds.

  2. Role of Different Kinds of Boundaries Against Cleavage Crack Propagation in Low-Temperature Embrittlement of Low-Carbon Martensitic Steel

    Science.gov (United States)

    Tsuboi, Mizuki; Shibata, Akinobu; Terada, Daisuke; Tsuji, Nobuhiro

    2017-07-01

    The present paper investigated the relationship between low-temperature embrittlement and microstructure of lath martensite in a low-carbon steel from both microstructural and crystallographic points of view. The fracture surface of the specimen after the miniaturized Charpy impact test at 98 K (-175 °C) mainly consisted of cleavage fracture facets parallel to crystallographic {001} planes of martensite. Through the crystallographic orientation analysis of micro-crack propagation, we found that the boundaries which separated different martensite variants having large misorientation angles of {001} cleavage planes could inhibit crack propagation. It was then concluded that the size of the aggregations of martensite variants belonging to the same Bain deformation group could control the low-temperature embrittlement of martensitic steels.

  3. Embrittlement data base, version 1

    Energy Technology Data Exchange (ETDEWEB)

    Wang, J.A.

    1997-08-01

    The aging and degradation of light-water-reactor (LWR) pressure vessels is of particular concern because of their relevance to plant integrity and the magnitude of the expected irradiation embrittlement. The radiation embrittlement of reactor pressure vessel (RPV) materials depends on many different factors such as flux, fluence, fluence spectrum, irradiation temperature, and preirradiation material history and chemical compositions. These factors must be considered to reliably predict pressure vessel embrittlement and to ensure the safe operation of the reactor. Based on embrittlement predictions, decisions must be made concerning operating parameters and issues such as low-leakage-fuel management, possible life extension, and the need for annealing the pressure vessel. Large amounts of data from surveillance capsules and test reactor experiments, comprising many different materials and different irradiation conditions, are needed to develop generally applicable damage prediction models that can be used for industry standards and regulatory guides. Version 1 of the Embrittlement Data Base (EDB) is such a comprehensive collection of data resulting from merging version 2 of the Power Reactor Embrittlement Data Base (PR-EDB). Fracture toughness data were also integrated into Version 1 of the EDB. For power reactor data, the current EDB lists the 1,029 Charpy transition-temperature shift data points, which include 321 from plates, 125 from forgoings, 115 from correlation monitor materials, 246 from welds, and 222 from heat-affected-zone (HAZ) materials that were irradiated in 271 capsules from 101 commercial power reactors. For test reactor data, information is available for 1,308 different irradiated sets (352 from plates, 186 from forgoings, 303 from correlation monitor materials, 396 from welds and 71 from HAZs) and 268 different irradiated plus annealed data sets.

  4. Influence of a cyclic load on the embrittlement kinetics of alloys by the example of the 475 C embrittlement of duplex steel and the dynamic embrittlement of a nickel base alloy; Einfluss einer zyklischen Belastung auf die Versproedungskinetik von Legierungen am Beispiel der 475 C-Versproedung von Duplexstahl und der dynamischen Versproedung einer Nickelbasislegierung

    Energy Technology Data Exchange (ETDEWEB)

    Wackermann, Ken

    2015-07-07

    The objective of this study was to investigate the dependence of high temperature embrittlement mechanisms on high temperature fatigue and vice versa. As model embrittlement mechanisms the 475 C Embrittlement of ferritic austenitic duplex stainless steel (1.4462) and the Dynamic Embrittlement of nickel-based superalloys (IN718) were selected. The 475 C Embrittlement is a thermally activated decomposition of the ferritic phase which hardens the material. In contrast to this a cyclic plastic deformation weakens the steel by a deformation-induced dissolution of the decomposition. Fatigue tests with different frequencies, loading amplitudes at room temperature and at 475 C with Duplex Stainless Steel in different states of embrittlement show that the ongoing 475 C Embrittlement and the deformation-induced dissolution are competing mechanisms. It depends on the frequency, the loading amplitude and the temperature which mechanism is dominant. Applying the model of the yield stress distribution function to the hysteresis branches of the fatigue tests allows an analysis of the fatigue behaviour of each phase individually. This analysis shows that the global fatigue behaviour for the test conditions applied in this study is mainly controlled by the ferritic phase. According to the existing understanding of Dynamic Embrittlement it is an oxygen grain boundary diffusion arising by tensile stress at elevated temperatures with the result of a fast intercrystalline crack propagation. In reference tests under vacuum conditions without oxygen grain boundary diffusion, a slow transcrystalline fracture appears. To analyse the Dynamic Embrittlement, the crack propagation was tested at 650 C with different frequencies and superimposed hold times in the fatigue cycle at maximum stress. The results shows that the existing model of Dynamic Embrittlement needs to be adapted to the effects of cyclic plastic deformation. In hold times, the oxygen grain boundary diffusion in front of the

  5. Current understanding on the neutron irradiation embrittlement of BWR reactor pressure vessel steels in Japan

    Energy Technology Data Exchange (ETDEWEB)

    Asano, K.; Nishiyama, T. [TEPCO (Japan); Soneda, N.; Dohi, K.; Nishida, K.; Nomoto, A. [CRIEPI (Japan); Ohta, T. [Japan Atomic Power Co. (Japan); Ishimaru, Y. [Chugoku EPCO (Japan); Yoneda, H. [Hokuriku EPCO (Japan); Lida, J. [Tohoku EPCO (Japan); Yuya, H. [Chubu EPCO (Japan)

    2011-07-01

    Neutron irradiation embrittlement of reactor pressure vessel (RPV) steels has been of concern primarily for the pressurized water reactors (PWRs). After long operation experiences, we are now becoming aware of the situation that the neutron irradiation embrittlement is also of concern for some of the boiling water reactors (BWRs) particularly with Cu-containing RPV steels. The surveillance data of Cu-containing BWR RPV steels show relatively larger shift in ductile-to-brittle transition temperature of fracture toughness than predicted by the embrittlement correlation method developed in late eighties and early nineties. Accurate evaluation of the amount of embrittlement is now very important for long-term operation of BWRs. In this paper, we will describe the neutron irradiation embrittlement of BWR RPVs in Japan. Some of the materials that show relatively large transition temperature shifts are investigated to understand the causes of embrittlement using state-of-the-art microstructural characterization techniques. Furthermore, some archive materials of such RPVs are irradiated in a material testing reactor with high neutron flux to understand the effect of flux on transition temperature shifts and corresponding microstructural changes. Microstructural evolution under irradiation, solute clustering in particular could explain the differences in transition temperature shift of the analyzed specimens. Larger BWR RPVs, which have larger water gaps, receive less neutron irradiation and harmful impurities in steels such as copper are well controlled since 1980 so irradiation embrittlement in BWR vessels can now be considered a concern only in old and small plants. All the new information obtained through these activities was considered in the development of new embrittlement correlation that is now adopted in JEAC 4201- 2007 of Japan Electric Association

  6. Models for embrittlement recovery due to annealing of reactor pressure vessel steels

    Energy Technology Data Exchange (ETDEWEB)

    Eason, E.D.; Wright, J.E.; Nelson, E.E. [Modeling and Computing Services, Boulder, CO (United States); Odette, G.R.; Mader, E.V. [California Univ., Santa Barbara, CA (United States)

    1995-05-01

    The reactor pressure vessel (RPV) surrounding the core of a commercial nuclear power plant is subject to embrittlement due to exposure to high energy neutrons. The effects of irradiation embrittlement can be reduced by thermal annealing at temperatures higher than the normal operating conditions. However, a means of quantitatively assessing the effectiveness of annealing for embrittlement recovery is needed. The objective of this work was to analyze the pertinent data on this issue and develop quantitative models for estimating the recovery in 30 ft-lb (41 J) Charpy transition temperature and Charpy upper shelf energy due to annealing. Data were gathered from the Test Reactor Embrittlement Data Base and from various annealing reports. An analysis data base was developed, reviewed for completeness and accuracy, and documented as part of this work. Independent variables considered in the analysis included material chemistries, annealing time and temperature, irradiation time and temperature, fluence, and flux. To identify important variables and functional forms for predicting embrittlement recovery, advanced statistical techniques, including pattern recognition and transformation analysis, were applied together with current understanding of the mechanisms governing embrittlement and recovery. Models were calibrated using multivariable surface-fitting techniques. Several iterations of model calibration, evaluation with respect to mechanistic and statistical considerations, and comparison with the trends in hardness data produced correlation models for estimating Charpy upper shelf energy and transition temperature after irradiation and annealing. This work provides a clear demonstration that (1) microhardness recovery is generally a very good surrogate for shift recovery, and (2) there is a high level of consistency between the observed annealing trends and fundamental models of embrittlement and recovery processes.

  7. Evaluation of hydrogen embrittlement and temper embrittlement by key curve method in instrumented Charpy test

    Directory of Open Access Journals (Sweden)

    Makita A.

    2010-06-01

    Full Text Available Instrumented Charpy test was conducted on small sized specimen of 21/4Cr-1Mo steel. In the test the single specimen key curve method was applied to determine the value of fracture toughness for the initiation of crack extension with hydrogen free, KIC, and for hydrogen embrittlement cracking, KIH. Also the tearing modulus as a parameter for resistance to crack extension was determined. The role of these parameters was discussed at an upper shelf temperature and at a transition temperature. Then the key curve method combined with instrumented Charpy test was proven to be used to evaluate not only temper embrittlement but also hydrogen embrittlement.

  8. Cladding embrittlement during postulated loss-of-coolant accidents.

    Energy Technology Data Exchange (ETDEWEB)

    Billone, M.; Yan, Y.; Burtseva, T.; Daum, R.; Nuclear Engineering Division

    2008-07-31

    The effect of fuel burnup on the embrittlement of various cladding alloys was examined with laboratory tests conducted under conditions relevant to loss-of-coolant accidents (LOCAs). The cladding materials tested were Zircaloy-4, Zircaloy-2, ZIRLO, M5, and E110. Tests were performed with specimens sectioned from as-fabricated cladding, from prehydrided (surrogate for high-burnup) cladding, and from high-burnup fuel rods which had been irradiated in commercial reactors. The tests were designed to determine for each cladding material the ductile-to-brittle transition as a function of steam oxidation temperature, weight gain due to oxidation, hydrogen content, pre-transient cladding thickness, and pre-transient corrosion-layer thickness. For short, defueled cladding specimens oxidized at 1000-1200 C, ring compression tests were performed to determine post-quench ductility at {le} 135 C. The effect of breakaway oxidation on embrittlement was also examined for short specimens oxidized at 800-1000 C. Among other findings, embrittlement was found to be sensitive to fabrication processes--especially surface finish--but insensitive to alloy constituents for these dilute zirconium alloys used as cladding materials. It was also demonstrated that burnup effects on embrittlement are largely due to hydrogen that is absorbed in the cladding during normal operation. Some tests were also performed with longer, fueled-and-pressurized cladding segments subjected to LOCA-relevant heating and cooling rates. Recommendations are given for types of tests that would identify LOCA conditions under which embrittlement would occur.

  9. Copper Alloy For High-Temperature Uses

    Science.gov (United States)

    Dreshfield, Robert L.; Ellis, David L.; Michal, Gary

    1994-01-01

    Alloy of Cu/8Cr/4Nb (numbers indicate parts by atom percent) improved over older high-temperature copper-based alloys in that it offers enhanced high temperature strength, resistance to creep, and ductility while retaining most of thermal conductivity of pure copper; in addition, alloy does not become embrittled upon exposure to hydrogen at temperatures as high as 705 degrees C. Designed for use in presence of high heat fluxes and active cooling; for example, in heat exchangers in advanced aircraft and spacecraft engines, and other high-temperature applications in which there is need for such material. High conductivity and hardness of alloy exploited in welding electrodes and in high-voltage and high-current switches and other applications in which wear poses design problem.

  10. Intergranular diffusion and embrittlement of a Ni–16Mo–7Cr alloy in Te vapor environment

    Energy Technology Data Exchange (ETDEWEB)

    Cheng, Hongwei [Shanghai Institute of Applied Physics, Chinese Academy of Sciences, Shanghai 201800 (China); University of Chinese Academy of Sciences, Beijing 100049 (China); Li, Zhijun [Shanghai Institute of Applied Physics, Chinese Academy of Sciences, Shanghai 201800 (China); Leng, Bin, E-mail: lengbin@sinap.ac.cn [Shanghai Institute of Applied Physics, Chinese Academy of Sciences, Shanghai 201800 (China); Zhang, Wenzhu [School of Materials Science and Engineering, Shanghai University, Shanghai 200072 (China); Han, Fenfen; Jia, Yanyan; Zhou, Xingtai [Shanghai Institute of Applied Physics, Chinese Academy of Sciences, Shanghai 201800 (China)

    2015-12-15

    Nickel and some nickel-base alloys are extremely sensitive to intergranular embrittlement and tellurium (Te) enhanced cracking, which should be concerned during their serving in molten salt reactors. Here, a systematic study about the effects of its temperature on the reaction products at its surface, the intergranular diffusion of Te in its body and its embrittlement for a Ni–16Mo–7Cr alloy contacting Te is reported. For exposed to Te vapor at high temperature (823–1073 K), the reaction products formed on the surface of the alloy were Ni{sub 3}Te{sub 2}, CrTe, and MoTe{sub 2}, and the most serious embrittlement was observed at 1073 K. The kinetic measurement in terms of Te penetration depth in the alloy samples gives an activation energy of 204 kJ/mol. Electron probe microanalysis confirmed the local enrichment of Te at grain boundaries. And clearly, the embrittlement was results from the intergranular diffusion and segregation of element Te. - Highlights: • Te-induced intergranular embrittlement and diffusion in Ni–16Mo–7Cr alloy were studied. • The EPMA mapping reveals Te segregate the grain boundaries. • Temperatures have significant effect Te cracking on grain boundaries. • Te basic diffusion parameters in Ni–16Mo–7Cr alloy have been established.

  11. Statistical analysis using the Bayesian nonparametric method for irradiation embrittlement of reactor pressure vessels

    Science.gov (United States)

    Takamizawa, Hisashi; Itoh, Hiroto; Nishiyama, Yutaka

    2016-10-01

    In order to understand neutron irradiation embrittlement in high fluence regions, statistical analysis using the Bayesian nonparametric (BNP) method was performed for the Japanese surveillance and material test reactor irradiation database. The BNP method is essentially expressed as an infinite summation of normal distributions, with input data being subdivided into clusters with identical statistical parameters, such as mean and standard deviation, for each cluster to estimate shifts in ductile-to-brittle transition temperature (DBTT). The clusters typically depend on chemical compositions, irradiation conditions, and the irradiation embrittlement. Specific variables contributing to the irradiation embrittlement include the content of Cu, Ni, P, Si, and Mn in the pressure vessel steels, neutron flux, neutron fluence, and irradiation temperatures. It was found that the measured shifts of DBTT correlated well with the calculated ones. Data associated with the same materials were subdivided into the same clusters even if neutron fluences were increased.

  12. Control of Hydrogen Embrittlement in High Strength Steel Using Special Designed Welding Wire

    Science.gov (United States)

    2016-03-01

    microstructure 4. A low near ambient temperature is reached. • All four factor must be simultaneously present 3 Mitigating HIC and Improving Weld Fatigue...Performance Through Weld Residual Stress Control UNCLASIFIED:DISTRIBUTION A. Approved for public release: distribution unlimited. Click to edit Master...title style 4 • Welding of Armor Steels favors all these conditions for HIC • Hydrogen Present in Sufficient Degree – Derived from moisture in the

  13. Control of Hydrogen Environment Embrittlement of Ultra-High Strength Steel for Naval Application

    Science.gov (United States)

    2005-07-01

    to the log da/dt vs. l/T data. Speidel reported simple Arrhenius behavior for lower strength Nimonic 105 (Cyys = 825 MPa) for 0°C < T < 100°C (Speidel...HYDROGEN ASSISTED CRACKING OF HIGH STRENGTH ALLOYS Richard P. Gangloff August. 2003 Page 115 of 194 L (a) R250 nm 250 nm SL (b) R Figure 43: Matching...34Hydrogen in Metals", Eds., I.M. Bernstein and A.W. Thompson, ASM International, Materials Park, OH, 1974, pp. 115 -147. W.W. Gerberich, Y.T. Chen and C

  14. PR-EDB: Power Reactor Embrittlement Database - Version 3

    Energy Technology Data Exchange (ETDEWEB)

    Wang, Jy-An John [ORNL; Subramani, Ranjit [ORNL

    2008-03-01

    The aging and degradation of light-water reactor pressure vessels is of particular concern because of their relevance to plant integrity and the magnitude of the expected irradiation embrittlement. The radiation embrittlement of reactor pressure vessel materials depends on many factors, such as neutron fluence, flux, and energy spectrum, irradiation temperature, and preirradiation material history and chemical compositions. These factors must be considered to reliably predict pressure vessel embrittlement and to ensure the safe operation of the reactor. Large amounts of data from surveillance capsules are needed to develop a generally applicable damage prediction model that can be used for industry standards and regulatory guides. Furthermore, the investigations of regulatory issues such as vessel integrity over plant life, vessel failure, and sufficiency of current codes, Standard Review Plans (SRPs), and Guides for license renewal can be greatly expedited by the use of a well-designed computerized database. The Power Reactor Embrittlement Database (PR-EDB) is such a comprehensive collection of data for U.S. designed commercial nuclear reactors. The current version of the PR-EDB lists the test results of 104 heat-affected-zone (HAZ) materials, 115 weld materials, and 141 base materials, including 103 plates, 35 forgings, and 3 correlation monitor materials that were irradiated in 321 capsules from 106 commercial power reactors. The data files are given in dBASE format and can be accessed with any personal computer using the Windows operating system. "User-friendly" utility programs have been written to investigate radiation embrittlement using this database. Utility programs allow the user to retrieve, select and manipulate specific data, display data to the screen or printer, and fit and plot Charpy impact data. The PR-EDB Version 3.0 upgrades Version 2.0. The package was developed based on the Microsoft .NET framework technology and uses Microsoft Access for

  15. Multiscale Modeling of Grain Boundary Segregation and Embrittlement in Tungsten for Mechanistic Design of Alloys for Coal Fired Plants

    Energy Technology Data Exchange (ETDEWEB)

    Luo, Jian; Tomar, Vikas; Zhou, Naixie; Lee, Hongsuk

    2013-06-30

    Based on a recent discovery of premelting-like grain boundary segregation in refractory metals occurring at high temperatures and/or high alloying levels, this project investigated grain boundary segregation and embrittlement in tungsten (W) based alloys. Specifically, new interfacial thermodynamic models have been developed and quantified to predict high-temperature grain boundary segregation in the W-Ni binary alloy and W-Ni-Fe, W-Ni-Ti, W-Ni-Co, W-Ni-Cr, W-Ni-Zr and W-Ni-Nb ternary alloys. The thermodynamic modeling results have been experimentally validated for selected systems. Furthermore, multiscale modeling has been conducted at continuum, atomistic and quantum-mechanical levels to link grain boundary segregation with embrittlement. In summary, this 3-year project has successfully developed a theoretical framework in combination with a multiscale modeling strategy for predicting grain boundary segregation and embrittlement in W based alloys.

  16. Precipitation hardening and hydrogen embrittlement of aluminum ...

    Indian Academy of Sciences (India)

    AA7020 Al–Mg–Zn, a medium strength aluminium alloy, is used in welded structures in military and aerospace applications. As it may be subjected to extremes of environmental exposures, including high pressure liquid hydrogen, it could suffer hydrogen embrittlement. Hydrogen susceptibility of alloy AA7020 was ...

  17. Slow Strain Rate Testing for Hydrogen Embrittlement Susceptibility of Alloy 718 in Substitute Ocean Water

    Science.gov (United States)

    LaCoursiere, M. P.; Aidun, D. K.; Morrison, D. J.

    2017-05-01

    The hydrogen embrittlement susceptibility of near-peak-aged UNS N07718 (Alloy 718) was evaluated by performing slow strain rate tests at room temperature in air and substitute ocean water. Tests in substitute ocean water were accomplished in an environmental cell that enabled in situ cathodic charging under an applied potential of -1.1 V versus SCE. Some specimens were cathodically precharged for 4 or 16 weeks at the same potential in a 3.5 wt.% NaCl-distilled water solution at 50 °C. Unprecharged specimens tested in substitute ocean water exhibited only moderate embrittlement with plastic strain to failure decreasing by about 20% compared to unprecharged specimens tested in air. However, precharged specimens exhibited significant embrittlement with plastic strain to failure decreasing by about 70%. Test environment (air or substitute ocean water with in situ charging) and precharge time (4 or 16 weeks) had little effect on the results of the precharged specimens. Fracture surfaces of precharged specimens were typical of hydrogen embrittlement and consisted of an outer brittle ring related to the region in which hydrogen infused during precharging, a finely dimpled transition zone probably related to the region where hydrogen was drawn in by dislocation transport, and a central highly dimpled ductile region. Fracture surfaces of unprecharged specimens tested in substitute ocean water consisted of a finely dimpled outer ring and heavily dimpled central region typical of ductile fracture.

  18. Current understanding of the effects of enviromental and irradiation variables on RPV embrittlement

    Energy Technology Data Exchange (ETDEWEB)

    Odette, G.R.; Lucas, G.E.; Wirth, B.; Liu, C.L. [Univ. of California, Santa Barbara, CA (United States)

    1997-02-01

    Radiation enhanced diffusion at RPV operating temperatures around 290{degrees}C leads to the formation of various ultrafine scale hardening phases, including copper-rich and copper-catalyzed manganese-nickel rich precipitates. In addition, defect cluster or cluster-solute complexes, manifesting a range of thermal stability, develop under irradiation. These features contribute directly to hardening which in turn is related to embrittlement, manifested as shifts in Charpy V-notch transition temperature. Models based on the thermodynamics, kinetics and micromechanics of the embrittlement processes have been developed; these are broadly consistent with experiment and rationalize the highly synergistic effects of most important irradiation (temperature, flux, fluence) and metallurgical (copper, nickel, manganese, phosphorous and heat treatment) variables on both irradiation hardening and recovery during post-irradiation annealing. A number of open questions remain which can be addressed with a hierarchy of new theoretical and experimental tools.

  19. A review of irradiation effects on LWR core internal materials - neutron embrittlement.

    Energy Technology Data Exchange (ETDEWEB)

    Chopra, O. K.; Rao, A. S. (Environmental Science Division); (U.S NRC)

    2011-05-01

    Austenitic stainless steels (SSs) are used extensively as structural alloys in the internal components of light water reactor (LWR) pressure vessels because of their relatively high strength, ductility, and fracture toughness. However, exposure to neutron irradiation for extended periods not only changes the microstructure and microchemistry of these steels, but also degrades their fracture properties. The existing data on irradiated austenitic SSs are reviewed to determine the effects of key parameters such as material type and condition and irradiation temperature, dose, and dose rate on neutron embrittlement. Differences in the radiation-induced degradation of fracture properties between LWR and fast-reactor irradiations are also discussed. The results are used to (a) define a threshold fluence above which irradiation effects on fracture toughness of the material are significant, (b) evaluate the potential of neutron embrittlement under LWR operating conditions, and (c) assess the potential effects of voids on fracture toughness.

  20. A review of irradiation effects on LWR core internal materials - Neutron embrittlement

    Energy Technology Data Exchange (ETDEWEB)

    Chopra, O.K., E-mail: okc@anl.gov [Environmental Science Division, Argonne National Laboratory, Argonne, IL 60439 (United States); Rao, A.S. [Division of Engineering, US Nuclear Regulatory Commission, Washington, DC 20555 (United States)

    2011-05-01

    Austenitic stainless steels (SSs) are used extensively as structural alloys in the internal components of light water reactor (LWR) pressure vessels because of their relatively high strength, ductility, and fracture toughness. However, exposure to neutron irradiation for extended periods not only changes the microstructure and microchemistry of these steels, but also degrades their fracture properties. The existing data on irradiated austenitic SSs are reviewed to determine the effects of key parameters such as material type and condition and irradiation temperature, dose, and dose rate on neutron embrittlement. Differences in the radiation-induced degradation of fracture properties between LWR and fast-reactor irradiations are also discussed. The results are used to (a) define a threshold fluence above which irradiation effects on fracture toughness of the material are significant, (b) evaluate the potential of neutron embrittlement under LWR operating conditions, and (c) assess the potential effects of voids on fracture toughness.

  1. Embrittlement recovery due to annealing of reactor pressure vessel steels

    Energy Technology Data Exchange (ETDEWEB)

    Eason, E.D.; Wright, J.E.; Nelson, E.E. [Modeling and Computing Services, Boulder, CO (United States); Odette, G.R.; Mader, E.V. [Univ. of California, Santa Barbara, CA (United States)

    1996-03-01

    Embrittlement of reactor pressure vessels (RPVs) can be reduced by thermal annealing at temperatures higher than the normal operating conditions. Although such an annealing process has not been applied to any commercial plants in the United States, one US Army reactor, the BR3 plant in Belgium, and several plants in eastern Europe have been successfully annealed. All available Charpy annealing data were collected and analyzed in this project to develop quantitative models for estimating the recovery in 30 ft-lb (41 J) Charpy transition temperature and Charpy upper shelf energy over a range of potential annealing conditions. Pattern recognition, transformation analysis, residual studies, and the current understanding of the mechanisms involved in the annealing process were used to guide the selection of the most sensitive variables and correlating parameters and to determine the optimal functional forms for fitting the data. The resulting models were fitted by nonlinear least squares. The use of advanced tools, the larger data base now available, and insight from surrogate hardness data produced improved models for quantitative evaluation of the effects of annealing. The quality of models fitted in this project was evaluated by considering both the Charpy annealing data used for fitting and the surrogate hardness data base. The standard errors of the resulting recovery models relative to calibration data are comparable to the uncertainty in unirradiated Charpy data. This work also demonstrates that microhardness recovery is a good surrogate for transition temperature shift recovery and that there is a high level of consistency between the observed annealing trends and fundamental models of embrittlement and recovery processes.

  2. High temperature measuring device

    Science.gov (United States)

    Tokarz, Richard D.

    1983-01-01

    A temperature measuring device for very high design temperatures (to 2,000.degree. C.). The device comprises a homogenous base structure preferably in the form of a sphere or cylinder. The base structure contains a large number of individual walled cells. The base structure has a decreasing coefficient of elasticity within the temperature range being monitored. A predetermined quantity of inert gas is confined within each cell. The cells are dimensionally stable at the normal working temperature of the device. Increases in gaseous pressure within the cells will permanently deform the cell walls at temperatures within the high temperature range to be measured. Such deformation can be correlated to temperature by calibrating similarly constructed devices under known time and temperature conditions.

  3. Moisture-induced embrittlement of iron aluminides. Final report

    Energy Technology Data Exchange (ETDEWEB)

    Castagna, A.; Stoloff, N.S. [Rensselaer Polytechnic Inst., Troy, NY (United States)

    1995-04-01

    FeAl alloys {ge}24 at. %Al are H embrittled by both H2 gas and water vapor. This examines effect of H embrittlement by H2 gas and moisture-bearing air on tensile properties and fatigue crack growth resistance of two ordered FeAl intermetallic alloys (28, 36 at. % Al) and one disordered Fe-Al alloy (16 at. % Al). Susceptibility to embrittlement varies with both Al content and ordered state. Tensile ductility of disordered low Al alloy is not affected by moisture-bearing air, and fatigue crack growth resistance is affected only slightly by moisture. However, the higher Al alloys are severely embrittled by moisture-bearing air. Oxidation of Al with concurrent release of H2 is responsible for embrittlement of Fe3Al alloys. It is likely that the smaller amount of Al available for the oxidation reaction in the 16at. % alloy precludes such embrittling reactions. In contrast, H2 is found to be embrittling to all alloys in both cyclic and monotonic tests. Fractography shows that H2 preferentially attacks cleavage planes in these alloys. Inherent fatigue crack growth resistance in an inert environment of the low Al disordered alloy is found to be much lower than that for the high Al alloys. Fatigue crack growth rate in an embrittling environment can be expressed as superposed mechanical fatigue and corrosion-fatigue components. Fatigue crack growth tests in inert and embrittling environments are used to isolate corrosion fatigue of the crack growth rate in Fe-28at. %Al. The corrosion-fatigue component displays a frequency dependence: At lower frequencies, more time is available for penetration of H ahead of the crack tip. H transport in the Fe-Al alloys occurs primarily by dislocation-assisted transport, which allows for penetration depths of 10-100x the distance that can be achieved by bulk diffusion. An equation is developed for the corrosion-fatigue component of crack growth rate which includes stress intensity range and frequency dependence.

  4. Effects of surface condition on aqueous corrosion and environmental embrittlement of iron aluminides

    Energy Technology Data Exchange (ETDEWEB)

    Perrin, R.L.; Buchanan, R.A. [Univ. of Tennessee, Knoxville, TN (United States)

    1996-08-01

    Effects of retained high-temperature surface oxides, produced during thermomechanical processing and/or heat treatment, on the aqueous-corrosion and environmental-embrittlement characteristics of Fe{sub 3}Al-based iron aluminides (FA-84, FA-129 and FAL-Mo), a FeAl-based iron aluminide (FA-385), and a disordered low-aluminum Fe-Al alloy (FAPY) were evaluated. All tests were conducted at room temperature in a mild acid-chloride solution. In cyclic-anodic-polarization testing for aqueous-corrosion behavior, the surface conditions examined were: as-received (i.e., with the retained high-temperature oxides), mechanically cleaned and chemically cleaned. For all materials, the polarization tests showed the critical pitting potentials to be significantly lower in the as-received condition than in the mechanically-cleaned and chemically-cleaned conditions. These results indicate detrimental effects of the retained high-temperature oxides in terms of increased susceptibilities to localized corrosion. In 200-hour U-bend stress-corrosion-cracking tests for environmental-embrittlement behavior, conducted at open-circuit corrosion potentials and at a hydrogen-charging potential of {minus}1500 mV (SHE), the above materials (except FA-385) were examined with retained oxides and with mechanically cleaned surfaces. At the open-circuit corrosion potentials, none of the materials in either surface condition underwent cracking. At the hydrogen-charging potential, none of the materials with retained oxides underwent cracking, but FA-84, FA-129 and FAL-Mo in the mechanically cleaned condition did undergo cracking. These results suggest beneficial effects of the retained high-temperature oxides in terms of increased resistance to environmental hydrogen embrittlement.

  5. Hydrogen embrittlement and hydrogen induced stress corrosion cracking of high alloyed austenitic materials; Wasserstoffversproedung und wasserstoffinduzierte Spannungsrisskorrosion hochlegierter austenitischer Werkstoffe

    Energy Technology Data Exchange (ETDEWEB)

    Mummert, K.; Uhlemann, M.; Engelmann, H.J. [Institut fuer Festkoerper- und Werkstofforschung Dresden e.V. (Germany)

    1998-11-01

    The susceptiblity of high alloyed austenitic steels and nickel base alloys to hydrogen-induced cracking is particularly determined by 1. the distribution of hydrogen in the material, and 2. the microstructural deformation behaviour, which last process is determined by the effects of hydrogen with respect to the formation of dislocations and the stacking fault energy. The hydrogen has an influence on the process of slip localization in slip bands, which in turn affects the microstructural deformation behaviour. Slip localization increases with growing Ni contents of the alloys and clearly reduces the ductility of the Ni-base alloy. Although there is a local hydrogen source involved in stress corrosion cracking, emanating from the corrosion process at the cathode, crack growth is observed only in those cases when the hydrogen concentration in a small zone ahead of the crack tip reaches a critical value with respect to the stress conditions. Probability of onset of this process gets lower with growing Ni content of the alloy, due to increasing diffusion velocity of the hydrogen in the austenitic lattice. This is why particularly austenitic steels with low Ni contents are susceptible to transcrystalline stress corrosion cracking. In this case, the microstructural deformation process at the crack tip is also influenced by analogous processes, as could be observed in hydrogen-loaded specimens. (orig./CB) [Deutsch] Die Empfindlichkeit von hochlegierten austentischen Staehlen und Nickelbasislegierungen gegen wasserstoffinduziertes Risswachstum wird im wesentlichen bestimmt durch 1. die Verteilung von Wasserstoff im Werkstoff und 2. das mikrostrukturelle Verformungsverhalten. Das mikrostrukturelle Deformationsverhalten ist wiederum durch den Einfluss von Wasserstoff auf die Versetzungsbildung und die Stapelfehlerenergie charakterisiert. Das mikrostrukturelle Verformungsverhalten wird durch wasserstoffbeeinflusste Gleitlokalisierung in Gleitbaendern bestimmt. Diese nimmt mit

  6. Estimation of embrittlement during aging of AISI 316 stainless steel ...

    Indian Academy of Sciences (India)

    Unknown

    Stainless steel; TIG welds; aging; Charpy impact; lower shelf energy; embrittlement. 1. Introduction. Austenitic stainless steels have high ductility, low yield strength, high tensile strength, are easy to fabricate and have good corrosion resistance (Harvey 1979). In welding of these steels there are some difficulties including hot.

  7. High temperature battery. Hochtemperaturbatterie

    Energy Technology Data Exchange (ETDEWEB)

    Bulling, M.

    1992-06-04

    To prevent heat losses of a high temperature battery, it is proposed to make the incoming current leads in the area of their penetration through the double-walled insulating housing as thermal throttle, particularly spiral ones.

  8. High temperature structural silicides

    Energy Technology Data Exchange (ETDEWEB)

    Petrovic, J.J.

    1997-03-01

    Structural silicides have important high temperature applications in oxidizing and aggressive environments. Most prominent are MoSi{sub 2}-based materials, which are borderline ceramic-intermetallic compounds. MoSi{sub 2} single crystals exhibit macroscopic compressive ductility at temperatures below room temperature in some orientations. Polycrystalline MoSi{sub 2} possesses elevated temperature creep behavior which is highly sensitive to grain size. MoSi{sub 2}-Si{sub 3}N{sub 4} composites show an important combination of oxidation resistance, creep resistance, and low temperature fracture toughness. Current potential applications of MoSi{sub 2}-based materials include furnace heating elements, molten metal lances, industrial gas burners, aerospace turbine engine components, diesel engine glow plugs, and materials for glass processing.

  9. High-temperature superconductors

    CERN Document Server

    Saxena, Ajay Kumar

    2010-01-01

    The present book aims at describing the phenomenon of superconductivity and high-temperature superconductors discovered by Bednorz and Muller in 1986. The book covers the superconductivity phenomenon, structure of high-Tc superconductors, critical currents, synthesis routes for high Tc materials, superconductivity in cuprates, the proximity effect and SQUIDs, theories of superconductivity and applications of superconductors.

  10. Diagnostic experimental results on the hydrogen embrittlement of austenitic steels

    Energy Technology Data Exchange (ETDEWEB)

    Gavriljuk, V.G.; Shivanyuk, V.N.; Foct, J

    2003-03-14

    Three main available hypotheses of hydrogen embrittlement are analysed in relation to austenitic steels based on the studies of the hydrogen effect on the interatomic bonds, phase transformations and microplastic behaviour. It is shown that hydrogen increases the concentration of free electrons, i.e. enhances the metallic character of atomic interactions, although such a decrease in the interatomic bonding cannot be a reason for brittleness and rather assists an increased plasticity. The hypothesis of the critical role of the hydrogen-induced {epsilon} martensite was tested in the experiment with the hydrogen-charged Si-containing austenitic steel. Both the fraction of the {epsilon} martensite and resistance to hydrogen embrittlement were increased due to Si alloying, which is at variance with the pseudo-hydride hypothesis. The hydrogen-caused early start of the microplastic deformation and an increased mobility of dislocations, which are usually not observed in the common mechanical tests, are revealed by the measurements of the strain-dependent internal friction, which is consistent with the hypothesis of the hydrogen-enhanced localised plasticity. An influence of alloying elements on the enthalpy E{sub H} of hydrogen migration in austenitic steels is studied using the temperature-dependent internal friction and a correlation is found between the values of E{sub H} and hydrogen-caused decrease in plasticity. A mechanism for the transition from the hydrogen-caused microplasticity to the apparent macrobrittle fracture is proposed based on the similarity of the fracture of hydrogenated austenitic steels to that of high nitrogen steels.

  11. High Temperature Electrolysis

    DEFF Research Database (Denmark)

    Elder, Rachael; Cumming, Denis; Mogensen, Mogens Bjerg

    2015-01-01

    High temperature electrolysis of carbon dioxide, or co-electrolysis of carbon dioxide and steam, has a great potential for carbon dioxide utilisation. A solid oxide electrolysis cell (SOEC), operating between 500 and 900. °C, is used to reduce carbon dioxide to carbon monoxide. If steam is also...... input to the cell then hydrogen is produced giving syngas. This syngas can then be further reacted to form hydrocarbon fuels and chemicals. Operating at high temperature gives much higher efficiencies than can be achieved with low temperature electrolysis. Current state of the art SOECs utilise a dense...

  12. Effects of Lower Drying-Storage Temperature on the Ductility of High-Burnup PWR Cladding

    Energy Technology Data Exchange (ETDEWEB)

    Billone, M. C. [Argonne National Lab. (ANL), Argonne, IL (United States); Burtseva, T. A. [Argonne National Lab. (ANL), Argonne, IL (United States)

    2016-08-30

    The purpose of this research effort is to determine the effects of canister and/or cask drying and storage on radial hydride precipitation in, and potential embrittlement of, high-burnup (HBU) pressurized water reactor (PWR) cladding alloys during cooling for a range of peak drying-storage temperatures (PCT) and hoop stresses. Extensive precipitation of radial hydrides could lower the failure hoop stresses and strains, relative to limits established for as-irradiated cladding from discharged fuel rods stored in pools, at temperatures below the ductile-to-brittle transition temperature (DBTT).

  13. High Temperature QCD

    CERN Document Server

    Lombardo, M P

    2012-01-01

    I review recent results on QCD at high temperature on a lattice. Steady progress with staggered fermions and Wilson type fermions allow a quantitative description of hot QCD whose accuracy in many cases parallels that of zero temperature studies. Simulations with chiral quarks are coming of age, and togheter with theoretical developments trigger interesting developments in the analysis of the critical region. Issues related with the universality class of the chiral transition and the fate of the axial symmetry are discussed in the light of new numerical and analytical results. Transport coefficients and analysis of bottomonium spectra compare well with results of heavy ion collisions at RHIC and LHC. Model field theories, lattice simulations and high temperature systematic expansions help building a coherent picture of the high temperature phase of QCD. The (strongly coupled) Quark Gluon Plasma is heavily investigated, and asserts its role as an inspiring theoretical laboratory.

  14. Highly efficient high temperature electrolysis

    DEFF Research Database (Denmark)

    Hauch, Anne; Ebbesen, Sune; Jensen, Søren Højgaard

    2008-01-01

    High temperature electrolysis of water and steam may provide an efficient, cost effective and environmentally friendly production of H-2 Using electricity produced from sustainable, non-fossil energy sources. To achieve cost competitive electrolysis cells that are both high performing i.e. minimum...... electrolysis is favourable from a thermodynamic point of view, because a part of the required energy can be supplied as thermal heat, and the activation barrier is lowered increasing the H-2 production rate. Only two types of cells operating at high temperature (above 200 degrees C) have been described...... electrolysis using SOECs is competitive to H-2 production from fossil fuels at electricity prices below 0.02-0.03 is an element of per kWh. Though promising SOEC results on H-2 production have been reported a substantial R&D is still required to obtain inexpensive, high performing and long-term stable...

  15. High temperature superconducting materials

    Energy Technology Data Exchange (ETDEWEB)

    Alario-Franco, M.A. [Universidad Complutense de Madrid (Spain). Facultad de Ciencias Quimicas

    1995-02-01

    The perovskite structure is the basis of all known high-temperature superconducting materials. Many of the most successful (highest T{sub c}) materials are based on mercury and thallium phases but, due to the high toxicity of the component compounds effort has been invested in the substitution of these elements with silver. Progress is reviewed. (orig.)

  16. High temperature storage loop :

    Energy Technology Data Exchange (ETDEWEB)

    Gill, David Dennis; Kolb, William J.

    2013-07-01

    A three year plan for thermal energy storage (TES) research was created at Sandia National Laboratories in the spring of 2012. This plan included a strategic goal of providing test capability for Sandia and for the nation in which to evaluate high temperature storage (>650ÀC) technology. The plan was to scope, design, and build a flow loop that would be compatible with a multitude of high temperature heat transfer/storage fluids. The High Temperature Storage Loop (HTSL) would be reconfigurable so that it was useful for not only storage testing, but also for high temperature receiver testing and high efficiency power cycle testing as well. In that way, HTSL was part of a much larger strategy for Sandia to provide a research and testing platform that would be integral for the evaluation of individual technologies funded under the SunShot program. DOEs SunShot program seeks to reduce the price of solar technologies to 6/kWhr to be cost competitive with carbon-based fuels. The HTSL project sought to provide evaluation capability for these SunShot supported technologies. This report includes the scoping, design, and budgetary costing aspects of this effort

  17. Experimental investigation of processes responsible for dehydration weakening and embrittlement

    Science.gov (United States)

    Hirth, G.; Okazaki, K.; Proctor, B.

    2016-12-01

    We have conducted suites of experiments designed to test the efficacy of dehydration embrittlement for inducing intermediate depth earthquakes. Deformation experiments have been conducted in a Griggs apparatus at 1 to 2 GPa on both antigorite and lawsonite gouge. To scale experimental results to natural conditions, we conducted experiments where we use temperature ramps to induce dehydration while the samples deform at a constant strain rate. The weakening rate of the samples scales with the ratio of the temperature ramp rate over the strain rate. We also conducted experiments at these conditions where the pore fluid pressure is either drained or undrained. In this poster, we will describe the following observations: (1) Experiments on antigorite demonstrate that weakening is associated with an increase in pore-fluid pressure. However, weakening is always stable even when the weakening rate is the same as the apparatus stiffness. Strain rate stepping experiments on both antigorite, and dehydrating antigorite indicate velocity strengthening behavior and no AEs are resolvable during the dehydration reaction. (2) Experiments on lawsonite show unstable weakening (i.e. stick slip behavior) at all ratios of temperature ramp rate over strain rate. Experiments within the lawsonite stability field exhibit stick-slip behavior and AEs are detected both during deformation within the lawsonite stability field and during the dehydration reaction. These results indicate that dehydration embrittlement is suppressed when the reacting phase shows velocity strengthening frictional behavior. The results of the experiments on dehydration of antigorite also suggest that embrittlement of the reaction products is suppressed by enhancement of solution-precipitation processes. This observation provides a possible explanation for why dehydration of antigorite induces embrittlement at lower confining pressures (i.e. 200 MPa), where the dehydration temperature is lower and hence the

  18. HYDROGEN EMBRITTLEMENT OF METALS: A PRIMER FOR THE FAILURE ANALYST

    Energy Technology Data Exchange (ETDEWEB)

    Louthan, M

    2008-01-31

    Hydrogen reduces the service life of many metallic components. Such reductions may be manifested as blisters, as a decrease in fatigue resistance, as enhanced creep, as the precipitation of a hydride phase and, most commonly, as unexpected, macroscopically brittle failure. This unexpected, brittle fracture is commonly termed hydrogen embrittlement. Frequently, hydrogen embrittlement occurs after the component has been is service for a period of time and much of the resulting fracture surface is distinctly intergranular. Many failures, particularly of high strength steels, are attributed to hydrogen embrittlement simply because the failure analyst sees intergranular fracture in a component that served adequately for a significant period of time. Unfortunately, simply determining that a failure is due to hydrogen embrittlement or some other form of hydrogen induced damage is of no particular help to the customer unless that determination is coupled with recommendations that provide pathways to avoid such damage in future applications. This paper presents qualitative and phenomenological descriptions of the hydrogen damage processes and outlines several metallurgical recommendations that may help reduce the susceptibility of a particular component or system to the various forms of hydrogen damage.

  19. High temperature superconductivity: Proceedings

    Energy Technology Data Exchange (ETDEWEB)

    Bedell, K.S.; Coffey, D. (Los Alamos National Lab., NM (USA)); Meltzer, D.E. (Florida Univ., Gainesville, FL (USA)); Pines, D. (Illinois Univ., Urbana, IL (USA)); Schrieffer, J.R. (California Univ., Santa Barbara, CA (USA)) (eds.)

    1990-01-01

    This book is the result of a symposium at Los Alamos in 1989 on High Temperature Superconductivity. The topics covered include: phenomenology, quantum spin liquids, spin space fluctuations in the insulating and metallic phases, normal state properties, and numerical studies and simulations. (JF)

  20. Life at High Temperatures

    Indian Academy of Sciences (India)

    Home; Journals; Resonance – Journal of Science Education; Volume 10; Issue 9. Life at High Temperatures. Ramesh Maheshwari. General Article Volume 10 Issue 9 September 2005 pp 23-36. Fulltext. Click here to view fulltext PDF. Permanent link: http://www.ias.ac.in/article/fulltext/reso/010/09/0023-0036. Keywords.

  1. Irradiation embrittlement characterization of the EUROFER 97 material

    Science.gov (United States)

    Kytka, M.; Brumovsky, M.; Falcnik, M.

    2011-02-01

    The paper summarizes original results of irradiation embrittlement study of EUROFER 97 material that has been proposed as one candidate of structural materials for future fusion energy systems and GEN IV. Test specimens were manufactured from base metal as well as from weld metal and tested in initial unirradiated condition and also after neutron irradiation. Irradiation embrittlement was characterized by testing of toughness properties at transition temperature region - static fracture toughness and dynamic fracture toughness properties, all in sub-size three-point bend specimens (27 × 4 × 3 mm 3). Testing and evaluation was performed in accordance with ASTM and ESIS standards, fracture toughness KJC and KJd data were also evaluated with the "Master curve" approach. Moreover, J- R dependencies were determined and analyzed. The paper compares unirradiated and irradiated properties as well as changes in transition temperature shifts of these material parameters. Discussion about the correlation between static and dynamic properties is also given. Results from irradiation of EUROFER 97 show that this steel - base metal as well as weld metal - is suitable as a structural material for reactor pressure vessels of innovative nuclear systems - fusion energy systems and GEN IV. Transition temperature shifts after neutron irradiation by 2.5 dpa dose show a good agreement in the case of EUROFER 97 base material for both static and dynamic fracture toughness tests. From the results it can be concluded that there is a low sensitivity of weld metal to neutron irradiation embrittlement in comparison with EUROFER 97 base metal.

  2. High temperature future

    Energy Technology Data Exchange (ETDEWEB)

    Sheinkopf, K. [Solar Energy Research and Education Foundation, Washington, DC (United States)

    1994-09-01

    During the past few years, there have been dramatic accomplishments and success of high temperature solar thermal systems and significant development of these systems. High temperature technologies, about 500 F and higher, such as dish engines, troughs, central receiver power towers and solar process heat systems, have been tested, demonstrated and used in an array of applications, including many cost-effective utility bulk power production and demand side supply projects in the United States. Large systems provide power and hot water to prisons, schools, nursing homes and other institutions. Joint ventures with industry, utility projects, laboratory design assistance and other activities are building a solid industry of US solar thermal systems ready for use today.

  3. Evaluation of the diffusivity and susceptibility to hydrogen embrittlement of API 5L X80 steel welded joints

    Directory of Open Access Journals (Sweden)

    B Araújo

    2016-09-01

    Full Text Available This paper presents a study of susceptibility to hydrogen embrittlement of API 5L X80 steel welded joints by SMAW and GTAW processes. By varying the consumables used and the use of the same interpass temperature three different welded joints were obtained. Tests of hydrogen embrittlement susceptibility were performed according to ASTM G129-2006 with an aqueous solution (Solution A - TM0177/2005 NACE sodium thiosulfate (Na2S2O3 replacing the bubbling of H2S. From the elongation values was observed that the joint obtained in all welding conditions showed susceptibility to hydrogen embrittlement, which was determined by the elongation ratio. The joints that showed higher levels of hardness showed higher susceptibility to hydrogen embrittlement. The joints obtained with higher welding speeds for the same amount of heat input presented a reduction in the rate of hydrogen embrittlement. All joints tested in solution showed fracture surfaces with quasi cleavage zones.

  4. Thermal Embrittlement of Reactor Pressure Vessel Steel due to Aging

    Energy Technology Data Exchange (ETDEWEB)

    Kim, Sung Soo; Park, Duck Gun [Korea Atomic Energy Research Institute, Daejeon (Korea, Republic of)

    2015-10-15

    Thermal SS sets are located above the nuclear core where a fast neutron flux is negligible and temperature is 320 .deg. C (as opposed to 290 .deg. C in locations of high-irradiated SS). These SS allow monitoring of continuous operation temperature exposure effect on mechanical characteristics of the steels. Although transgranular cleavage is the predominant mode of brittle fracture in RPV steels, solute (e.g. phosphorus) segregation to grain boundaries can result in another type of brittle fracture known as intergranular (grain boundary) fracture. Figures 1 a) and b) show examples of transgranular and intergranular (IG) fracture, respectively, as viewed in a scanning electron microscope. The investigators have interpreted the intergranular cracking occurs as a result of segregation of sulfur and/or phosphorus at grain boundary. The IG cracking is a kind of symptom of embrittlement. It is reported that the IG cracking occurs in inert (Ar) environment under slow strain rate test. 1. The lath grain size in SA508 RPV steel increases slightly due to thermal aging at 350, 420, and 420 .deg. C for 2,250H. 2. The decrease in toughness appeared 4-25% and the lattice contraction appeared to be +0.004% - -0.022% due to thermal aging at 350, 420, and 420 .deg. C for 2,250H. 3. The amount of decrease in Charpy impact energy due to thermal aging is correlated well with the magnitude of lattice contraction.

  5. High Temperature Piezoelectric Drill

    Science.gov (United States)

    Bao, Xiaoqi; Bar-Cohen, Yoseph; Sherrit, Stewart; Badescu, Mircea; Shrout, Tom

    2012-01-01

    Venus is one of the planets in the solar systems that are considered for potential future exploration missions. It has extreme environment where the average temperature is 460 deg C and its ambient pressure is about 90 atm. Since the existing actuation technology cannot maintain functionality under the harsh conditions of Venus, it is a challenge to perform sampling and other tasks that require the use of moving parts. Specifically, the currently available electromagnetic actuators are limited in their ability to produce sufficiently high stroke, torque, or force. In contrast, advances in developing electro-mechanical materials (such as piezoelectric and electrostrictive) have enabled potential actuation capabilities that can be used to support such missions. Taking advantage of these materials, we developed a piezoelectric actuated drill that operates at the temperature range up to 500 deg C and the mechanism is based on the Ultrasonic/Sonic Drill/Corer (USDC) configuration. The detailed results of our study are presented in this paper

  6. High temperature materials and mechanisms

    CERN Document Server

    2014-01-01

    The use of high-temperature materials in current and future applications, including silicone materials for handling hot foods and metal alloys for developing high-speed aircraft and spacecraft systems, has generated a growing interest in high-temperature technologies. High Temperature Materials and Mechanisms explores a broad range of issues related to high-temperature materials and mechanisms that operate in harsh conditions. While some applications involve the use of materials at high temperatures, others require materials processed at high temperatures for use at room temperature. High-temperature materials must also be resistant to related causes of damage, such as oxidation and corrosion, which are accelerated with increased temperatures. This book examines high-temperature materials and mechanisms from many angles. It covers the topics of processes, materials characterization methods, and the nondestructive evaluation and health monitoring of high-temperature materials and structures. It describes the ...

  7. High temperature superconductors

    CERN Document Server

    Paranthaman, Parans

    2010-01-01

    This essential reference provides the most comprehensive presentation of the state of the art in the field of high temperature superconductors. This growing field of research and applications is currently being supported by numerous governmental and industrial initiatives in the United States, Asia and Europe to overcome grid energy distribution issues. The technology is particularly intended for densely populated areas. It is now being commercialized for power-delivery devices, such as power transmission lines and cables, motors and generators. Applications in electric utilities include current limiters, long transmission lines and energy-storage devices that will help industries avoid dips in electric power.

  8. Effect of lead factors on the embrittlement of RPV SA-508 cl 3 steel

    Energy Technology Data Exchange (ETDEWEB)

    Kempf, Rodolfo, E-mail: kempf@cnea.gov.ar [CNEA, Unidad Actividad Combustibles Nucleares, División Caracterización, Avda. Gral Paz 1499, C.P.B1650KNA, San Martín, Buenos Aires (Argentina); Troiani, Horacio, E-mail: troiani@cab.cnea.gov.ar [Centro Atómico Bariloche (CNEA) e Instituto Balseiro (UNCU), CONICET, Av. Bustillo 9500, CP 8400, Rio Negro (Argentina); Fortis, Ana Maria, E-mail: fortis@cnea.gov.ar [CNEA, Departamento Estructura y Comportamiento, UNSAM, Avda. Gral Paz 1499, C.P.B1650KNA, San Martín, Buenos Aires (Argentina)

    2013-03-15

    This paper presents a project to study the effect of lead factors on the mechanical behaviour of the SA-508 type 3 Reactor Pressure Vessel (RPV) steel used in the reactor under construction Atucha II in Argentina. Charpy-V notch specimens of this steel were irradiated at the RA1 experimental reactor at a temperature of 275 °C with two lead factors (186 and 93). The neutron flux was 3.71 × 10{sup 15} n m{sup −2} s{sup −1} and 1.85 × 10{sup 15} n m{sup −2} s{sup −1} (E > 1 MeV) respectively. In both cases, the fluence was 6.6 × 10{sup 21} n m{sup −2}, which is equivalent to that received by the PHWR Atucha II RPV in 10 years of full power irradiation. The results of Charpy tests revealed significant embrittlement both in the ΔT = 14 °C and ΔT = 21 °C shifts of the ductile–brittle transition temperatures (DBTT) and in the reduction of the maximum energy absorbed. This result shows that the shift of the DBTT with a lead factor of 93 is larger than that obtained with a lead factor of 186. Then, the results of irradiation in experimental reactors (MTR) with high lead factors may not be conservative with respect to the actual RPV embrittlement.

  9. High Temperature Aquifer Storage

    Science.gov (United States)

    Ueckert, Martina; Niessner, Reinhard; Baumann, Thomas

    2016-04-01

    Combined heat and power generation (CHP) is highly efficient because excess heat is used for heating and/or process energy. However, the demand of heat energy varies considerably throughout the year while the demand for electrical energy is rather constant. It seems economically and ecologically highly beneficial for municipalities and large power consumers such as manufacturing plants to store excess heat in groundwater aquifers and to recuperate this energy at times of higher demand. Within the project High Temperature Aquifer Storage, scientists investigate storage and recuperation of excess heat energy into the bavarian Malm aquifer. Apart from high transmissivity and favorable pressure gradients, the hydrochemical conditions are crucial for long-term operation. An enormous technical challenge is the disruption of the carbonate equilibrium - modeling results indicated a carbonate precipitation of 10 - 50 kg/d in the heat exchangers. The test included five injection pulses of hot water (60 °C up to 110 °C) and four tracer pulses, each consisting of a reactive and a conservative fluorescent dye, into a depth of about 300 m b.s.l. resp. 470 m b.s.l. Injection and production rates were 15 L/s. To achieve the desired water temperatures, about 4 TJ of heat energy were necessary. Electrical conductivity, pH and temperature were recorded at a bypass where also samples were taken. A laboratory container at the drilling site was equipped for analysing the concentration of the dyes and the major cations at sampling intervals of down to 15 minutes. Additional water samples were taken and analysed in the laboratory. The disassembled heat exchanger prooved that precipitation was successfully prevented by adding CO2 to the water before heating. Nevertheless, hydrochemical data proved both, dissolution and precipitation processes in the aquifer. This was also suggested by the hydrochemical modelling with PhreeqC and is traced back to mixture dissolution and changing

  10. High Temperature Hybrid Elastomers

    Science.gov (United States)

    Drake, Kerry Anthony

    Conventional high temperature elastomers are produced by chain polymerization of olefinic or fluorinated olefinic monomers. Ultimate thermal stabilities are limited by backbone bond strengths, lower thermal stability of cross-link sites relative to backbone bonds, and depolymerization or "unzipping" at high temperatures. In order to develop elastomers with enhanced thermal stability, hybrid thermally cross-linkable polymers that consisted only of organic-inorganic and aromatic bonds were synthesized and evaluated. The addition of phenylethynyl or phenylacetylinic functional groups to these polymers resulted in conversion of the polymers into high temperature elastomers when cross-linked by thermal curing. Polyphenyoxydiphenylsilanes were synthesized via several different condensation reactions. Results of these synthetic reactions, which utilized both hydroquinone and biphenol as monomers, were systematically evaluated to determine the optimal synthetic conditions for subsequent endcapping reactions. It was determined that dichlorodiphenylsilane condensations with biphenol in toluene or THF were best suited for this work. Use of excess dichlorodiphenylsilane yielded polymers of appropriate molecular weights with terminal reactive chlorosilane groups that could be utilized for coupling with phenylethynyl reagents in a subsequent reaction. Two new synthetic routes were developed to endcap biphenoxysilanes with ethynyl containing substituents, to yield polymers with cross-linkable end groups. Endcapping by lithiumphenylacetylide and 4[(4-fluorophenylethynyl))phenol yielded two new polymers that could be thermally cross-linked on heating above 300 °C. Successful endcapping was verified chemically by 13C NMR, FTIR and Raman analysis. Exothermic peaks consistent with ethynyl curing reactions were observed in endcapped polymers by DSC. A new diacetylinic polymer was prepared through reaction of 4,4'-buta-1,3-diyne-1,4-diyldiphenol and dichlorodiphenylsilane. This

  11. A study on the irradiation embrittlement and recovery characteristics of light water reactor pressure vessel steels

    Energy Technology Data Exchange (ETDEWEB)

    Chi, Se Hwan; Hong, Jun Hwa; Lee, Bong Sang; Oh, Jong Myung; Song, Sook Hyang; Milan, Brumovsky [NRI Czech (Czech Republic)

    1999-03-01

    The neutron irradiation embrittlement phenomenon of light water RPV steels greatly affects the life span for safe operation of a reactor. Reliable evaluation and prediction of the embrittlement of RPV steels, especially of aged reactors, are of importance to the safe operation of a reactor. In addition, the thermal recovery of embrittled RPV has been recognized as an option for life extension. This study aimed to tracer/refine available technologies for embrittlement characterization and prediction, to prepare relevant materials for several domestic RPV steels of the embrittlement and recovery, and to find out possible remedy for steel property betterment. Small specimen test techniques, magnetic measurement techniques, and the Meechan and Brinkmann's recovery curve analysis method were examined/applied as the evaluation techniques. Results revealed a high irradiation sensitivity in YG 3 RPV steel. Further extended study may be urgently needed. Both the small specimen test technique for the direct determination of fracture toughness, and the magnetic measurement technique for embrittlement evaluation appeared to be continued for the technical improvement and data base preparation. Manufacturing process relevant to the heat treatment appeared to be improved in lowering the irradiation sensitivity of the steel. Further study is needed especially in applying the present techniques to the new structural materials under new irradiation environment of advanced reactors. (author)

  12. HIGH TEMPERATURE VACUUM MIXER

    Directory of Open Access Journals (Sweden)

    E. D. Chertov

    2015-01-01

    Full Text Available The work is devoted to the creation of a new type of mixer to produce homogeneous mixtures of dissimilar materials applied to recycling of housing and communal services waste. The article describes the design of a dual-chamber device of the original high-temperature vacuum mixer, there investigated the processes occurring in the chambers of such devices. The results of theoretical and experimental research of the process of mixing recycled polyethylene with a mixture of "grinded food waste – Eco wool” are presented. The problem of the optimum choice of bending the curvilinear blades in the working volume of the seal, which is achieved by setting their profile in the form of involute arc of several circles of different radii, is examined . The dependences, allowing to define the limits of the changes of the main mode parameters the angular velocity of rotation of the working body of the mixer using two ways of setting the profile of the curvilinear blade mixer are obtained. Represented design of the mixer is proposed to use for a wide range of tasks associated with the mixing of the components with a strongly pronounced difference of physic al chemical properties and, in particular, in the production of composites out of housing and communal services waste.

  13. Seismic anisotropy evidence for dehydration embrittlement triggering intermediate-depth earthquakes.

    Science.gov (United States)

    Wang, Jian; Zhao, Dapeng; Yao, Zhenxing

    2017-06-01

    It has been proposed that dehydration embrittlement of hydrous materials can trigger intermediate-depth earthquakes and form a double seismic zone in a subducting slab. Seismic anisotropy may provide a possible insight into intermediate-depth intraslab seismicity, because anisotropic properties of minerals change with varying water distribution, temperature and pressure. Here we present a high-resolution model of P-wave radial anisotropy tomography of the Japan subduction zone down to ~400 km depth, which is obtained using a large number of arrival-time data of local earthquakes and teleseismic events. Our results reveal a close correlation between the pattern of intermediate-depth seismicity and anisotropic structures. The seismicity occurs in portions of the Pacific and Philippine Sea slabs where positive radial anisotropy (i.e., horizontal velocity being faster than vertical one) dominates due to dehydration, whereas the inferred anhydrous parts of the slabs are found to be aseismic where negative radial anisotropy (i.e., vertical velocity being faster than horizontal one) dominates. Our anisotropic results suggest that intermediate-depth earthquakes in Japan could be triggered by dehydration embrittlement of hydrous minerals in the subducting slabs.

  14. The impact of mobile point defect clusters in a kinetic model of pressure vessel embrittlement

    Energy Technology Data Exchange (ETDEWEB)

    Stoller, R.E.

    1998-05-01

    The results of recent molecular dynamics simulations of displacement cascades in iron indicate that small interstitial clusters may have a very low activation energy for migration, and that their migration is 1-dimensional, rather than 3-dimensional. The mobility of these clusters can have a significant impact on the predictions of radiation damage models, particularly at the relatively low temperatures typical of commercial, light water reactor pressure vessels (RPV) and other out-of-core components. A previously-developed kinetic model used to investigate RPV embrittlement has been modified to permit an evaluation of the mobile interstitial clusters. Sink strengths appropriate to both 1- and 3-dimensional motion of the clusters were evaluated. High cluster mobility leads to a reduction in the amount of predicted embrittlement due to interstitial clusters since they are lost to sinks rather than building up in the microstructure. The sensitivity of the predictions to displacement rate also increases. The magnitude of this effect is somewhat reduced if the migration is 1-dimensional since the corresponding sink strengths are lower than those for 3-dimensional diffusion. The cluster mobility can also affect the evolution of copper-rich precipitates in the model since the radiation-enhanced diffusion coefficient increases due to the lower interstitial cluster sink strength. The overall impact of the modifications to the model is discussed in terms of the major irradiation variables and material parameter uncertainties.

  15. Advances in high temperature chemistry

    CERN Document Server

    Eyring, Leroy

    1969-01-01

    Advances in High Temperature Chemistry, Volume 2 covers the advances in the knowledge of the high temperature behavior of materials and the complex and unfamiliar characteristics of matter at high temperature. The book discusses the dissociation energies and free energy functions of gaseous monoxides; the matrix-isolation technique applied to high temperature molecules; and the main features, the techniques for the production, detection, and diagnosis, and the applications of molecular beams in high temperatures. The text also describes the chemical research in streaming thermal plasmas, as w

  16. High-Temperature Piezoelectric Sensing

    Directory of Open Access Journals (Sweden)

    Xiaoning Jiang

    2013-12-01

    Full Text Available Piezoelectric sensing is of increasing interest for high-temperature applications in aerospace, automotive, power plants and material processing due to its low cost, compact sensor size and simple signal conditioning, in comparison with other high-temperature sensing techniques. This paper presented an overview of high-temperature piezoelectric sensing techniques. Firstly, different types of high-temperature piezoelectric single crystals, electrode materials, and their pros and cons are discussed. Secondly, recent work on high-temperature piezoelectric sensors including accelerometer, surface acoustic wave sensor, ultrasound transducer, acoustic emission sensor, gas sensor, and pressure sensor for temperatures up to 1,250 °C were reviewed. Finally, discussions of existing challenges and future work for high-temperature piezoelectric sensing are presented.

  17. High temperature superconductor accelerator magnets

    NARCIS (Netherlands)

    van Nugteren, J.

    2016-01-01

    For future particle accelerators bending dipoles are considered with magnetic fields exceeding 20T. This can only be achieved using high temperature superconductors (HTS). These exhibit different properties from classical low temperature superconductors and still require significant research and

  18. Life at High Temperatures

    Indian Academy of Sciences (India)

    2005-09-15

    Sep 15, 2005 ... or more in the vicinity of geothermal vents in the deep sea and the plant Tidestromia oblongifolia (Amaranthaceae) found in Death. Valley in California, where the hottest temperature on earth ever recorded during 43 consecutive days in 1917 was >48 °C. (Guinness Book of W orId Records, 1999).

  19. Role of Tungsten in the Tempered Martensite Embrittlement of a Modified 9 Pct Cr Steel

    Science.gov (United States)

    Fedoseeva, Alexandra; Dudova, Nadezhda; Kaibyshev, Rustam

    2017-03-01

    The effect of tempering on the mechanical properties and fracture behavior of two 3 pct Co-modified 9 pct Cr steels with 2 and 3 wt pct W was examined. Both steels were ductile in tension tests and tough under impact tests in high-temperature tempered conditions. At T ≤ 923 K (650 °C), the addition of 1 wt pct W led to low toughness and pronounced embrittlement. The 9Cr2W steel was tough after low-temperature tempering up to 723 K (450 °C). At 798 K (525 °C), the decomposition of retained austenite induced the formation of discontinuous and continuous films of M23C6 carbides along boundaries in the 9Cr2W and the 9Cr3W steels, respectively, which led to tempered martensite embrittlement (TME). In the 9Cr2W steel, the discontinuous boundary films played a role of crack initiation sites, and the absorption energy was 24 J cm-2. In the 9Cr3W steel, continuous films provided a fracture path along the boundaries of prior austenite grains (PAG) and interlath boundaries in addition that caused the drop of impact energy to 6 J cm-2. Tempering at 1023 K (750 °C) completely eliminated TME by spheroidization and the growth of M23C6 carbides, and both steels exhibited high values of adsorbed energy of ≥230 J cm-2. The addition of 1 wt pct W extended the temperature domain of TME up to 923 K (650 °C) through the formation of W segregations at boundaries that hindered the spheroidization of M23C6 carbides.

  20. High temperature materials; Materiaux a hautes temperatures

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    2003-07-01

    The aim of this workshop is to share the needs of high temperature and nuclear fuel materials for future nuclear systems, to take stock of the status of researches in this domain and to propose some cooperation works between the different research organisations. The future nuclear systems are the very high temperature (850 to 1200 deg. C) gas cooled reactors (GCR) and the molten salt reactors (MSR). These systems include not only the reactor but also the fabrication and reprocessing of the spent fuel. This document brings together the transparencies of 13 communications among the 25 given at the workshop: 1) characteristics and needs of future systems: specifications, materials and fuel needs for fast spectrum GCR and very high temperature GCR; 2) high temperature materials out of neutron flux: thermal barriers: materials, resistance, lifetimes; nickel-base metal alloys: status of knowledge, mechanical behaviour, possible applications; corrosion linked with the gas coolant: knowledge and problems to be solved; super-alloys for turbines: alloys for blades and discs; corrosion linked with MSR: knowledge and problems to be solved; 3) materials for reactor core structure: nuclear graphite and carbon; fuel assembly structure materials of the GCR with fast neutron spectrum: status of knowledge and ceramics and cermets needs; silicon carbide as fuel confinement material, study of irradiation induced defects; migration of fission products, I and Cs in SiC; 4) materials for hydrogen production: status of the knowledge and needs for the thermochemical cycle; 5) technologies: GCR components and the associated material needs: compact exchangers, pumps, turbines; MSR components: valves, exchangers, pumps. (J.S.)

  1. The effects of composition on the environmental embrittlement of Fe{sub 3}Al alloys

    Energy Technology Data Exchange (ETDEWEB)

    Alven, D.A.; Stoloff, N.S. [Rensselaer Polytechnic Inst., Troy, NY (United States)

    1997-12-01

    This paper reviews recent research on embrittlement of iron aluminides at room temperature brought about by exposure to moisture or hydrogen. The tensile and fatigue crack growth behavior of several Fe-28Al-5Cr alloys with small additions of Zr and C are described. It will be shown that fatigue crack growth behavior is dependent on composition, environment, humidity level, and frequency. Environments studied include vacuum, oxygen, hydrogen gas, and moist air. All cases of embrittlement are ultimately traceable to the interaction of hydrogen with the crack tip.

  2. High Temperature Superconductor Machine Prototype

    DEFF Research Database (Denmark)

    Mijatovic, Nenad; Jensen, Bogi Bech; Træholt, Chresten

    2011-01-01

    A versatile testing platform for a High Temperature Superconductor (HTS) machine has been constructed. The stationary HTS field winding can carry up to 10 coils and it is operated at a temperature of 77K. The rotating armature is at room temperature. Test results and performance for the HTS field...

  3. Specificity in liquid metal induced embrittlement

    CSIR Research Space (South Africa)

    Fernandes, PJL

    1996-12-01

    Full Text Available compounds between the solid and liquid metals. To study the embrittlement of two brass alloys by molten gallium (Tm = 29.8 °C), Tensile tests on smooth, unnotched specimens were used. The alloys used were CZ106, a 70/30 alpha-brass, and CZ109, a 60/40 alpha-beta...

  4. Evaluation of the Temper embrittlement in SA508 Gr. 4N Low Alloy Steel with Ni, Cr Contents Variation

    Energy Technology Data Exchange (ETDEWEB)

    Park, Sang Gyu; Wee, Dang Moon [KAIST, Daejeon (Korea, Republic of); Kim, Min Chul; Lee, Bong Sang [Korea Atomic Energy Research Institute, Daejeon (Korea, Republic of)

    2009-10-15

    It is well known that SA508 Gr.4N low alloy steel has an improved fracture toughness and strength, compared to commercial low alloy steels such as SA508 Gr.3 and SA533B which have less than 1% Ni. Higher strength and fracture toughness of low alloy steels could be achieved by Ni and Cr addition. So there are several researches on SA508 Gr.4N low alloy steel for a RPV application. The operation temperature of a reactor pressure vessel is more than 300 .deg. C and it operates for over 40 years. Therefore, in order to apply the SA508 Gr.4N low alloy steel for a reactor pressure vessel, it requires phase stability in the high temperature range including temper embrittlement resistance. Although temper brittlement has not been reported in SA508 Gr.4N low alloy steel, the evaluation of the temper embrittlement phenomena on SA508 Gr.4N is required for an RPV application. In a previous study, we have concluded that additional Ni and Cr could change the microstructures of SA508 Gr.4N low alloy steel, and changed microstructure may affect the susceptibility of temper embrittlement in SA508 Gr.4N. In this study, we have performed a Charpy impact test of SA508 Gr.4N low alloy steel with changing alloying element contents such as Ni and Cr. The mechanical properties of these low alloy steels after a long-term heat treatment(450 .deg. C, 2000hr) are also evaluated. Then, the fracture modes of each impact specimens are examined and grain boundary segregation is analyzed by AES. The precipitation behaviors of the low alloy steels are observed by SEM.

  5. High-Temperature Superconductors

    CERN Document Server

    Saxena, Ajay Kumar

    2012-01-01

    This book presents the current knowledge about superconductivity in high Tc cuprate superconductors. There is a large scientific interest and great potential for technological applications. The book discusses all the aspects related to all families of cuprate superconductors discovered so far. Beginning with the phenomenon of superconductivity, the book covers: the structure of cuprate HTSCs, critical currents, flux pinning, synthesis of HTSCs, proximity effect and SQUIDs, possible applications of high Tc superconductors and theories of superconductivity. Though a high Tc theory is still awaited, this book describes the present scenario and BCS and RVB theories. The second edition was  significantly extended by including film-substrate lattice matching and buffer layer considerations in thin film HTSCs, brick-wall microstructure in the epitaxial films, electronic structure of the CuO2 layer in cuprates, s-wave and d-wave coupling in HTSCs and possible scenarios of theories of high Tc superconductivity.

  6. High Temperature Electrostrictive Ceramics Project

    Data.gov (United States)

    National Aeronautics and Space Administration — TRS Technologies proposes to develop high temperature electrostrictors from bismuth-based ferroelectrics. These materials will exhibit high strain and low loss in...

  7. High Temperature Surface Interactions

    Science.gov (United States)

    1989-11-01

    oxidation rate of "pure SiC* in air (from compilation of data by Schlichting6). For T < 14001C, partial cristobalite formation; T > 1400"C, decreased...aluminium content is high enough, the beta phase percolates and contains a dispersion of -- Ni particles. Such a tructure is certainly less favourable

  8. High-temperature performance evaluation of adirectionally solidified nickel-base superalloy

    Science.gov (United States)

    Woodford, D. A.; Stiles, D.

    1997-08-01

    The application of a new approach, design for performance, for high-temperature alloy development, design analysis, and remaining life assessment, based on short-time high-precision testing, is described in this paper. The material tested was a directionally solidified nickel-base alloy, GTD111. It was found that the creep strength at 850 °C was indeed superior to that of a competitive alloy, IN738, but was not necessarily enhanced by the preferred alignment of grain boundaries and crystal orientation. In contrast, the fracture resistance at 800 °C was improved in the longitudinal direction compared with transverse and diagonal orientations in terms of susceptibility to gas phase embrittlement (GPE) by oxygen. Specimens cut transversely and diagonally to the growth direction were more sensitive to GPE than specimens taken from conventionally cast IN738. The new conceptual framework allows account to be taken of GPE and other embrittling phenomena, which may develop in service, leading to rational life management decisions for gas turbine users. Additionally, straightforward design analysis procedures can be developed from the test data, which for the first time allow separate measurements of creep strength and fracture resistance to be used for performance evaluation.

  9. Fracture analysis of HFIR beam tube caused by radiation embrittlement

    Energy Technology Data Exchange (ETDEWEB)

    Chang, S.J. [Oak Ridge National Lab., TN (United States). Research Reactors Div.

    1994-12-31

    With an attempt to estimate the neutron beam tube embrittlement condition for the Oak Ridge High Flux Isotope Reactor (HFIR), fracture mechanics calculations are carried out in this paper. The analysis provides some numerical result on how the tube has been structurally weakened. In this calculation, a lateral impact force is assumed. Numerical result is obtained on how much the critical crack size should be reduced if the beam tube has been subjected to an extended period of irradiation. It is also calculated that buckling strength of the tube is increased, not decreased, with irradiation.

  10. (Krauss) at constant high temperatures

    African Journals Online (AJOL)

    Snail Research Unit of the SAMRC and Department of Zoology, Potchefstroom University for CHE,. Potchefstroom. The survival of the freshwater snail species Bulinus africanus, Bulinus g/obosus and Biompha/aria pfeifferi at extreme high temperatures was experimentally investigated. Snails were exposed to temperatures ...

  11. HIGH TEMPERATURE POLYMER FUEL CELLS

    DEFF Research Database (Denmark)

    Jensen, Jens Oluf; Qingfeng, Li; He, Ronghuan

    2003-01-01

    This paper will report recent results from our group on polymer fuel cells (PEMFC) based on the temperature resistant polymer polybenzimidazole (PBI), which allow working temperatures up to 200°C. The membrane has a water drag number near zero and need no water management at all. The high working...

  12. Effect of retained austenite on the hydrogen embrittlement of a medium carbon quenching and partitioning steel with refined microstructure

    Energy Technology Data Exchange (ETDEWEB)

    Yang, Jilan; Huang, Feng; Guo, Zhenghong, E-mail: zhenghongguo@sjtu.edu.cn; Rong, Yonghua; Chen, Nailu

    2016-05-17

    The effect of retained austenite on the hydrogen embrittlement of a medium carbon quenching and partitioning steel was investigated by comparison to a traditional quenching and tempering steel with an identical chemical composition. Electrochemical precharging reduces the plasticity, including the elongation and reduction in area, of both steels, and the embrittlement phenomenon is more severe in the quenching and tempering steel based on a slow strain rate tensile test. As a result, the ultimate tensile strength decreases, as well. The fracture mode was dominated by intergranular features in the areas containing hydrogen, suggesting the weakening of boundary cohesion. Retained austenite, which retards diffusion and increases the solubility of hydrogen, is stable under the attack of hydrogen, contributing to the high hydrogen embrittlement resistance of quenching and partitioning steel. Refining the microstructure further improves plasticity due to the lower hydrogen content per area. In general, the quenching and partitioning steel with a refined microstructure exhibits the lowest hydrogen embrittlement susceptibility.

  13. High Temperature Bell Motor Project

    Data.gov (United States)

    National Aeronautics and Space Administration — The National Research Council (NRC) has identified the need for motors and actuators that can operate in extreme high and low temperature environments as a technical...

  14. High Temperature Materials Laboratory (HTML)

    Data.gov (United States)

    Federal Laboratory Consortium — The six user centers in the High Temperature Materials Laboratory (HTML), a DOE User Facility, are dedicated to solving materials problems that limit the efficiency...

  15. Development of High-Temperature Ferritic Alloys and Performance Prediction Methods for Advanced Fission Energy Systems

    Energy Technology Data Exchange (ETDEWEB)

    G. RObert Odette; Takuya Yamamoto

    2009-08-14

    Reports the results of a comprehensive development and analysis of a database on irradiation hardening and embrittlement of tempered martensitic steels (TMS). Alloy specific quantitative semi-empirical models were derived for the dpa dose, irradiation temperature (ti) and test (Tt) temperature of yield stress hardening (or softening) .

  16. Nanocrystalline Steels’ Resistance to Hydrogen Embrittlement

    Directory of Open Access Journals (Sweden)

    Skołek E.

    2015-04-01

    Full Text Available The aim of this study is to determine the susceptibility to hydrogen embrittlement in X37CrMoV5-1 steel with two different microstructures: a nanocrystalline carbide-free bainite and tempered martensite. The nanobainitic structure was obtained by austempering at the bainitic transformation zone. It was found, that after hydrogen charging, both kinds of microstructure exhibit increased yield strength and strong decrease in ductility. It has been however shown that the resistance to hydrogen embrittlement of X37CrMoV5-1 steel with nanobainitic structure is higher as compared to the tempered martensite. After hydrogen charging the ductility of austempered steel is slightly higher than in case of quenched and tempered (Q&T steel. This effect was interpreted as a result of phase composition formed after different heat treatments.

  17. Embrittlement of irradiated ferritic/martensitic steels in the absence of irradiation hardening

    Energy Technology Data Exchange (ETDEWEB)

    Klueh, R.L. [Oak Ridge Noational Laboratory, TN (United States); Shiba, K. [Japan Atomic Energy Agency, Tokai-mura, Naga-gun, Ibaraki-ken (Japan); Sokolov, M. [Oak Ridge National Laboratory, Materials Science and Technology Div., TN (United States)

    2007-07-01

    Full text of publication follows: Neutron irradiation of 9-12% Cr ferritic/martensitic steels below 425-450 deg. C produces microstructural defects that cause an increase in yield stress and ultimate tensile strength. This irradiation hardening causes embrittlement, which is observed in Charpy impact and toughness tests as an increase in ductile-brittle transition temperature (DBTT). Based on observations that show little change in strength in these steels irradiated above 425-450 deg. C, the general conclusion has been that no embrittlement occurs above this irradiation-hardening temperature regime. In a recent study of F82H steel irradiated at 300, 380, and 500 deg. C, irradiation hardening-an increase in yield stress-was observed in tensile specimens irradiated at the two lower temperatures, but no change was observed for the specimens irradiated at 500 deg. C. As expected, an increase in DBTT occurred for the Charpy specimens irradiated at 300 and 380 deg. C. However, there was an unexpected increase in the DBTT of the specimens irradiated at 500 deg. C. The observed embrittlement was attributed to the irradiation-accelerated precipitation of Laves phase. This conclusion was based on results from a detailed thermal aging study of F82H, in which tensile and Charpy specimens were aged at 500, 550, 600, and 650 deg. C to 30,000 h. These studies indicated that there was a decrease in yield stress at the two highest temperatures and essentially no change at the two lowest temperatures. Despite the strength decrease or no change, the DBTT increased for Charpy specimens irradiated at all four temperatures. Precipitates were extracted from thermally aged specimens, and the amount of precipitate was correlated with the increase in transition temperature. Laves phase was identified in the extracted precipitates by X-ray diffraction. Earlier studies on conventional elevated-temperature steels also showed embrittlement effects above the irradiation-hardening temperature

  18. Effect of prior-austenite grain refinement on microstructure, mechanical properties and thermal embrittlement of 9Cr-1Mo-0.1C steel

    Science.gov (United States)

    Karthikeyan, T.; Dash, Manmath Kumar; Ravikirana; Mythili, R.; Panneer Selvi, S.; Moitra, A.; Saroja, S.

    2017-10-01

    The effect of 'conventional normalizing and tempering' (CNT) and 'double austenitization based normalizing and tempering' (DNT) heat treatments on the microstructure, tensile, creep and impact toughness properties of 9Cr-1Mo steel has been studied. The tempered martensite microstructure obtained through DNT treatment exhibited smaller sizes of prior-austenite grains/martensite packets (28 μm/11 μm) compared to the CNT treatment (44 μm/14 μm). The tempered martensite morphology was largely retained after long-term thermal aging at 550 °C/5000 h, while the M23C6 and M2(C,N) type of precipitates were found to act as nucleation sites for precipitation of brittle Fe2Mo Laves phase. The grain refinement by DNT was found to be beneficial for minimizing the ductile-to-brittle transition characteristics (25 °C lower ductile-to-brittle transition temperature and 70 J higher upper shelf energy) over the CNT. Thermal embrittlement occurred in both heated treated steels, but the transition temperature of aged DNT steel remained below room temperature. Fractured Charpy specimens revealed ductile failure by void coalescence for high temperature tests, and a quasi-cleavage fracture at low temperatures with few isolated occurrence of intergranular crack in thermal embrittled steel. The DNT treated steel resulted in similar or better tensile and creep properties, when compared to the CNT treatment. The homogeneous fine grained tempered martensite microstructure obtained by DNT treatment resulted in improved embrittlement resistance and mechanical properties over the conventional treatment.

  19. Temperature optimization of high con

    Directory of Open Access Journals (Sweden)

    M. Sabry

    2016-06-01

    Full Text Available Active cooling is essential for solar cells operating under high optical concentration ratios. A system comprises four solar cells that are in thermal contact on top of a copper tube is proposed. Water is flowing inside the tube in order to reduce solar cells temperature for increasing their performance. Computational Fluid Dynamics (CFD simulation of such system has been performed in order to investigate the effect of water flow rate, tube internal diameter, and convective heat transfer coefficient on the temperature of the solar cells. It is found that increasing convective heat transfer coefficient has a significant effect on reducing solar cells temperatures operating at low flow rates and high optical concentration ratios. Also, a further increase of water flow rate has no effect on reducing cells temperatures.

  20. RPC operation at high temperature

    CERN Document Server

    Aielli, G; Cardarelli, R; Di Ciaccio, A; Di Stante, L; Liberti, B; Paoloni, A; Pastori, E; Santonico, R

    2003-01-01

    The resistive electrodes of RPCs utilised in several current experiments (ATLAS, CMS, ALICE, BABAR and ARGO) are made of phenolic /melaminic polymers, with room temperature resistivities ranging from 10**1**0 Omega cm, for high rate operation in avalanche mode, to 5 multiplied by 10**1**1 Omega cm, for streamer mode operation at low rate. The resistivity has however a strong temperature dependence, decreasing exponentially with increasing temperature. We have tested several RPCs with different electrode resistivities in avalanche as well as in streamer mode operation. The behaviours of the operating current and of the counting rate have been studied at different temperatures. Long-term operation has also been studied at T = 45 degree C and 35 degree C, respectively, for high and low resistivity electrodes RPCs.

  1. HIgh Temperature Photocatalysis over Semiconductors

    Science.gov (United States)

    Westrich, Thomas A.

    Due in large part to in prevalence of solar energy, increasing demand of energy production (from all sources), and the uncertain future of petroleum energy feedstocks, solar energy harvesting and other photochemical systems will play a major role in the developing energy market. This dissertation focuses on a novel photochemical reaction process: high temperature photocatalysis (i.e., photocatalysis conducted above ambient temperatures, T ≥ 100°C). The overarching hypothesis of this process is that photo-generated charge carriers are able to constructively participate in thermo-catalytic chemical reactions, thereby increasing catalytic rates at one temperature, or maintaining catalytic rates at lower temperatures. The photocatalytic oxidation of carbon deposits in an operational hydrocarbon reformer is one envisioned application of high temperature photocatalysis. Carbon build-up during hydrocarbon reforming results in catalyst deactivation, in the worst cases, this was shown to happen in a period of minutes with a liquid hydrocarbon. In the presence of steam, oxygen, and above-ambient temperatures, carbonaceous deposits were photocatalytically oxidized over very long periods (t ≥ 24 hours). This initial experiment exemplified the necessity of a fundamental assessment of high temperature photocatalytic activity. Fundamental understanding of the mechanisms that affect photocatalytic activity as a function of temperatures was achieved using an ethylene photocatalytic oxidation probe reaction. Maximum ethylene photocatalytic oxidation rates were observed between 100 °C and 200 °C; the maximum photocatalytic rates were approximately a factor of 2 larger than photocatalytic rates at ambient temperatures. The loss of photocatalytic activity at temperatures above 200 °C is due to a non-radiative multi-phonon recombination mechanism. Further, it was shown that the fundamental rate of recombination (as a function of temperature) can be effectively modeled as a

  2. Moire interferometry at high temperatures

    Science.gov (United States)

    Wu, Jau-Je

    1992-01-01

    The objective of this study was to provide an optical technique allowing full-field in-plane deformation measurements at high temperature by using high-sensitivity moire interferometry. This was achieved by a new approach of performing deformation measurements at high temperatures in a vacuum oven using an achromatic interferometer. The moire system setup was designed with particular consideration for the stability, compactness, flexibility, and ease of control. A vacuum testing environment was provided to minimize the instability of the patterns by protecting the optical instruments from the thermal convection currents. Also, a preparation procedure for the high-temperature specimen grating was developed with the use of the plasma-etched technique. Gold was used as a metallic layer in this procedure. This method was demonstrated on a ceramic block, metal/matrix composite, and quartz. Thermal deformation of a quartz specimen was successfully measured in vacuum at 980 degrees Celsius, with the sensitivity of 417 nm per fringe. The stable and well-defined interference patterns confirmed the feasibility of the developments, including the high-temperature moire system and high-temperature specimen grating. The moire system was demonstrated to be vibration-insensitive. Also, the contrast of interference fringes at high temperature was enhanced by means of a spatial filter and a narrow band interference filter to minimize the background noise from the flow of the specimen and heater. The system was verified by a free thermal expansion test of an aluminum block. Good agreement demonstrated the validity of the optical design. The measurements of thermal deformation mismatch were performed on a graphite/epoxy composite, a metal/matrix composite equipped with an optical fiber, and a cutting tool bit. A high-resolution data-reduction technique was used to measure the strain distribution of the cutting tool bit.

  3. High temperature superconductor accelerator magnets

    OpenAIRE

    van Nugteren, J.

    2016-01-01

    For future particle accelerators bending dipoles are considered with magnetic fields exceeding 20T. This can only be achieved using high temperature superconductors (HTS). These exhibit different properties from classical low temperature superconductors and still require significant research and development before they can be applied in a practical accelerator magnet. In order to study HTS in detail, a five tesla demonstrator magnet named Feather-M2 is designed and constructed. The magnet is ...

  4. High Temperature Superconductor Accelerator Magnets

    OpenAIRE

    Van Nugteren, Jeroen; ten Kate, Herman; de Rijk, Gijs; Dhalle, Marc

    2016-01-01

    For future particle accelerators bending dipoles are considered with magnetic fields exceeding $20T$. This can only be achieved using high temperature superconductors (HTS). These exhibit different properties from classical low temperature superconductors and still require significant research and development before they can be applied in a practical accelerator magnet. In order to study HTS in detail, a five tesla demonstrator magnet named Feather-M2 is designed and constructed. The magnet ...

  5. The Role of Surface Protection for High-Temperature Performance of TiAl Alloys

    Science.gov (United States)

    Schütze, Michael

    2017-09-01

    In the temperature range where TiAl alloys are currently being used in jet engine and automotive industries, surface reaction with the operating environment is not yet a critical issue. Surface treatment may, however, be needed in order to provide improved abrasion resistance. Development routes currently aim at a further increase in operation temperatures in gas turbines up to 800°C and higher, and in automotive applications for turbocharger rotors, even up to 1050°C. In this case, oxidation rates may reach levels where significant metal consumption of the load-bearing cross-section can occur. Another possibly even more critical issue can be high-temperature-induced oxygen and nitrogen up-take into the metal subsurface zone with subsequent massive ambient temperature embrittlement. Solutions for these problems are based on a deliberate phase change of the metal subsurface zone by diffusion treatments and by using effects such as the halogen effect to change the oxidation mechanism at high temperatures. Other topics of relevance for the use of TiAl alloys in high-temperature applications can be high-temperature abrasion resistance, thermal barrier coatings on TiAl and surface quality in additive manufacturing, in all these cases-focusing on the role of the operation environment. This paper addresses the recent developments in these areas and the requirements for future work.

  6. The Role of Surface Protection for High-Temperature Performance of TiAl Alloys

    Science.gov (United States)

    Schütze, Michael

    2017-12-01

    In the temperature range where TiAl alloys are currently being used in jet engine and automotive industries, surface reaction with the operating environment is not yet a critical issue. Surface treatment may, however, be needed in order to provide improved abrasion resistance. Development routes currently aim at a further increase in operation temperatures in gas turbines up to 800°C and higher, and in automotive applications for turbocharger rotors, even up to 1050°C. In this case, oxidation rates may reach levels where significant metal consumption of the load-bearing cross-section can occur. Another possibly even more critical issue can be high-temperature-induced oxygen and nitrogen up-take into the metal subsurface zone with subsequent massive ambient temperature embrittlement. Solutions for these problems are based on a deliberate phase change of the metal subsurface zone by diffusion treatments and by using effects such as the halogen effect to change the oxidation mechanism at high temperatures. Other topics of relevance for the use of TiAl alloys in high-temperature applications can be high-temperature abrasion resistance, thermal barrier coatings on TiAl and surface quality in additive manufacturing, in all these cases-focusing on the role of the operation environment. This paper addresses the recent developments in these areas and the requirements for future work.

  7. High-Temperature Optical Sensor

    Science.gov (United States)

    Adamovsky, Grigory; Juergens, Jeffrey R.; Varga, Donald J.; Floyd, Bertram M.

    2010-01-01

    A high-temperature optical sensor (see Figure 1) has been developed that can operate at temperatures up to 1,000 C. The sensor development process consists of two parts: packaging of a fiber Bragg grating into a housing that allows a more sturdy thermally stable device, and a technological process to which the device is subjected to in order to meet environmental requirements of several hundred C. This technology uses a newly discovered phenomenon of the formation of thermally stable secondary Bragg gratings in communication-grade fibers at high temperatures to construct robust, optical, high-temperature sensors. Testing and performance evaluation (see Figure 2) of packaged sensors demonstrated operability of the devices at 1,000 C for several hundred hours, and during numerous thermal cycling from 400 to 800 C with different heating rates. The technology significantly extends applicability of optical sensors to high-temperature environments including ground testing of engines, flight propulsion control, thermal protection monitoring of launch vehicles, etc. It may also find applications in such non-aerospace arenas as monitoring of nuclear reactors, furnaces, chemical processes, and other hightemperature environments where other measurement techniques are either unreliable, dangerous, undesirable, or unavailable.

  8. Neutron-irradiation + helium hardening and embrittlement modeling of 9% Cr-steels in an engineering perspective (HELENA)

    Energy Technology Data Exchange (ETDEWEB)

    Chaouadi, Rachid

    2008-07-01

    This report provides a physically-based engineering model to estimate the radiation hardening of 9%Cr-steels under both displacement damage (dpa) and helium. The model is essentially based on the dispersed barrier hardening theory and the dynamic re-solution of helium under displacement cascades. However, a number of assumptions and simplifications were considered to obtain a simple description of irradiation hardening and embrittlement primarily relying on the available experimental data. As a result, two components were basically identified, the dpa component that can be associated with black dots and small loops and the He-component accounting for helium bubbles. The dpa component is strongly dependent on the irradiation temperature and its dependence law was based on a first-order annealing kinetics. The damage accumulation law was also modified to take saturation into account. Finally, the global kinetics of the damage accumulation kept defined, its amplitude is fitted to one experimental condition. The model was rationalized on an experimental database that mainly consists of {proportional_to}9%Cr-steels irradiated in the technologically important temperature range of 50 to 600 C up do 50 dpa and with a He-content up to {proportional_to}5000 appm, including neutron and proton irradiation as well as implantation. The test temperature effect is taken into account through a normalization procedure based on the change of the Young's modulus and the anelastic deformation that occurs at high temperature. Finally, the hardening-to-embrittlement correlation is obtained using the load diagram approach. Despite the large experimental scatter, inherent to the variety of the materials and irradiation as well as testing conditions, the obtained results are very promising. Improvement of the model performance is still possible by including He-hardening saturation and high temperature softening but unfortunately, at this stage, a number of conflicting experimental data

  9. Solute strengthening at high temperatures

    Science.gov (United States)

    Leyson, G. P. M.; Curtin, W. A.

    2016-08-01

    The high temperature behavior of solute strengthening has previously been treated approximately using various scaling arguments, resulting in logarithmic and power-law scalings for the stress-dependent energy barrier Δ E(τ ) versus stress τ. Here, a parameter-free solute strengthening model is extended to high temperatures/low stresses without any a priori assumptions on the functional form of Δ E(τ ) . The new model predicts that the well-established low-temperature, with energy barrier Δ {{E}\\text{b}} and zero temperature flow stress {τy0} , transitions to a near-logarithmic form for stresses in the regime 0.2intermediate-temperature and the associated transition for the activation volume. Overall, the present analysis unifies the different qualitative models in the literature and, when coupled with the previous parameter-free solute strengthening model, provides a single predictive model for solute strengthening as a function of composition, temperature, and strain rate over the full range of practical utility.

  10. High temperature superconductor current leads

    Science.gov (United States)

    Hull, John R.; Poeppel, Roger B.

    1995-01-01

    An electrical lead having one end for connection to an apparatus in a cryogenic environment and the other end for connection to an apparatus outside the cryogenic environment. The electrical lead includes a high temperature superconductor wire and an electrically conductive material distributed therein, where the conductive material is present at the one end of the lead at a concentration in the range of from 0 to about 3% by volume, and at the other end of the lead at a concentration of less than about 20% by volume. Various embodiments are shown for groups of high temperature superconductor wires and sheaths.

  11. High temperature corrosion in gasifiers

    Directory of Open Access Journals (Sweden)

    Wate Bakker

    2004-03-01

    Full Text Available Several commercial scale coal gasification combined cycle power plants have been built and successfully operated during the last 5-10 years. Supporting research on materials of construction has been carried out for the last 20 years by EPRI and others. Emphasis was on metallic alloys for heat exchangers and other components in contact with hot corrosive gases at high temperatures. In this paper major high temperature corrosion mechanisms, materials performance in presently operating gasifiers and future research needs will be discussed.

  12. Nonlinear plasmonics at high temperatures

    Science.gov (United States)

    Sivan, Yonatan; Chu, Shi-Wei

    2017-01-01

    We solve the Maxwell and heat equations self-consistently for metal nanoparticles under intense continuous wave (CW) illumination. Unlike previous studies, we rely on experimentally-measured data for metal permittivity for increasing temperature and for the visible spectral range. We show that the thermal nonlinearity of the metal can lead to substantial deviations from the predictions of the linear model for the temperature and field distribution and, thus, can explain qualitatively the strong nonlinear scattering from such configurations observed experimentally. We also show that the incompleteness of existing data of the temperature dependence of the thermal properties of the system prevents reaching a quantitative agreement between the measured and calculated scattering data. This modeling approach is essential for the identification of the underlying physical mechanism responsible for the thermo-optical nonlinearity of the metal and should be adopted in all applications of high-temperature nonlinear plasmonics, especially for refractory metals, for both CW and pulsed illumination.

  13. Nonlinear plasmonics at high temperatures

    Directory of Open Access Journals (Sweden)

    Sivan Yonatan

    2016-10-01

    Full Text Available We solve the Maxwell and heat equations self-consistently for metal nanoparticles under intense continuous wave (CW illumination. Unlike previous studies, we rely on experimentally-measured data for metal permittivity for increasing temperature and for the visible spectral range. We show that the thermal nonlinearity of the metal can lead to substantial deviations from the predictions of the linear model for the temperature and field distribution and, thus, can explain qualitatively the strong nonlinear scattering from such configurations observed experimentally. We also show that the incompleteness of existing data of the temperature dependence of the thermal properties of the system prevents reaching a quantitative agreement between the measured and calculated scattering data. This modeling approach is essential for the identification of the underlying physical mechanism responsible for the thermo-optical nonlinearity of the metal and should be adopted in all applications of high-temperature nonlinear plasmonics, especially for refractory metals, for both CW and pulsed illumination.

  14. Chemistry of high temperature superconductors

    CERN Document Server

    1991-01-01

    This review volume contains the most up-to-date articles on the chemical aspects of high temperature oxide superconductors. These articles are written by some of the leading scientists in the field and includes a comprehensive list of references. This is an essential volume for researchers working in the fields of ceramics, materials science and chemistry.

  15. High temperature component life assessment

    CERN Document Server

    Webster, G A

    1994-01-01

    The aim of this book is to investigate and explain the rapid advances in the characterization of high temperature crack growth behaviour which have been made in recent years, with reference to industrial applications. Complicated mathematics has been minimized with the emphasis placed instead on finding solutions using simplified procedures without the need for complex numerical analysis.

  16. Properties of high temperature SQUIDS

    Energy Technology Data Exchange (ETDEWEB)

    Falco, C. M.; Wu, C. T.

    1978-01-01

    A review is given of the present status of weak links and dc and rf biased SQUIDs made with high temperature superconductors. A method for producing reliable, reproducible devices using Nb/sub 3/Sn is outlined, and comments are made on directions future work should take.

  17. High-temperature flooding injury

    Science.gov (United States)

    This problem, also called scald, is most serious in the hot desert valleys of the southwestern United States, subtropical regions in eastern Australia, and western Asia and northern Africa (Middle East) where fields are established and irrigated under high temperatures. The disorder also occurs to...

  18. Experimental Studies on Dehydration Embrittlement of Serpentinized Peridotite and Effect of Pressure on Creep of Olivine

    Science.gov (United States)

    Xia, Gang

    The origin of intermediate depth earthquakes has been debated for 90 years yet is still under active discussion. These earthquakes are localized in double seismic zones in descending lithosphere; both zones originate very close to oceanic trenches. A leading proposed initiation mechanism for these earthquakes since 1968 has been dehydration embrittlement of serpentine under stress. Despite the considerable evidence favoring this mechanism, a major argument against it has been that the lower seismic zone initiates at ˜40 km depth almost immediately below trenches and there does not appear to be a vehicle to carry water sufficiently deep to hydrate otherwise dry lithosphere. To directly address this problem, an experimental study has been carried out to investigate the minimum amount of serpentine that is required to trigger the dehydration embrittlement instability in serpentinized peridotite at high pressure (1-3 GPa) and temperature (720-750˚C). The results show that embrittlement occurs during dehydration of antigorite (the phase of serpentine stable at elevated pressure) in a wide range of compositions but both nearly dry peridotite and extensively altered peridotite are ductile. Fresh, unaltered, synthetic harzburgite and harzburgite with 4 vol% distributed antigorite are ductile, as are specimens with greater than 65% antigorite. Only compositions between 8 vol% and 65 vol% antigorite develop the instability. We suggest that very small degrees of serpentinization do not release sufficient H 2O to trigger the instability and that extensive serpentinization avoids the instability because soft, ductile, antigorite becomes the interconnected matrix with olivine and pyroxene existing only as isolated crystals. In that case, dehydration simply facilitates flow. These systematics suggest that small amounts of H2O transported down deep normal (bending) faults at trenches are sufficient to enable the instability in the lower seismic zones, thus providing additional

  19. High temperature thermoelectric energy conversion

    Science.gov (United States)

    Wood, Charles

    1987-01-01

    The theory and current status of materials research for high-temperature thermoelectric energy conversion are reviewed. Semiconductors are shown to be the preferred class of materials for this application. Optimization of the figure of merit of both broadband and narrow-band semiconductors is discussed as a function of temperature. Phonon scattering mechanisms are discussed, and basic material guidelines are given for reduction of thermal conductivity. Two general classes of materials show promise for high temperature figure of merit (Z) values, namely the rare earth chalcogenides and the boron-rich borides. The electronic transport properties of the rare earth chalcogenides are explicable on the basis of degenerate or partially degenerate n-type semiconductors. Boron and boron-rich borides exhibit p-type hopping conductivity, with detailed explanations proposed for the transport differing from compound to compound. Some discussion is presented on the reasons for the low thermal conductivities in these materials. Also, ZTs greater than one appear to have been realized at high temperature in many of these compounds.

  20. High temperature, high power piezoelectric composite transducers.

    Science.gov (United States)

    Lee, Hyeong Jae; Zhang, Shujun; Bar-Cohen, Yoseph; Sherrit, Stewart

    2014-08-08

    Piezoelectric composites are a class of functional materials consisting of piezoelectric active materials and non-piezoelectric passive polymers, mechanically attached together to form different connectivities. These composites have several advantages compared to conventional piezoelectric ceramics and polymers, including improved electromechanical properties, mechanical flexibility and the ability to tailor properties by using several different connectivity patterns. These advantages have led to the improvement of overall transducer performance, such as transducer sensitivity and bandwidth, resulting in rapid implementation of piezoelectric composites in medical imaging ultrasounds and other acoustic transducers. Recently, new piezoelectric composite transducers have been developed with optimized composite components that have improved thermal stability and mechanical quality factors, making them promising candidates for high temperature, high power transducer applications, such as therapeutic ultrasound, high power ultrasonic wirebonding, high temperature non-destructive testing, and downhole energy harvesting. This paper will present recent developments of piezoelectric composite technology for high temperature and high power applications. The concerns and limitations of using piezoelectric composites will also be discussed, and the expected future research directions will be outlined.

  1. High Temperature Composite Heat Exchangers

    Science.gov (United States)

    Eckel, Andrew J.; Jaskowiak, Martha H.

    2002-01-01

    High temperature composite heat exchangers are an enabling technology for a number of aeropropulsion applications. They offer the potential for mass reductions of greater than fifty percent over traditional metallics designs and enable vehicle and engine designs. Since they offer the ability to operate at significantly higher operating temperatures, they facilitate operation at reduced coolant flows and make possible temporary uncooled operation in temperature regimes, such as experienced during vehicle reentry, where traditional heat exchangers require coolant flow. This reduction in coolant requirements can translate into enhanced range or system payload. A brief review of the approaches and challengers to exploiting this important technology are presented, along with a status of recent government-funded projects.

  2. Summary: High Temperature Downhole Motor

    Energy Technology Data Exchange (ETDEWEB)

    Raymond, David W. [Sandia National Lab. (SNL-NM), Albuquerque, NM (United States)

    2017-10-01

    Directional drilling can be used to enable multi-lateral completions from a single well pad to improve well productivity and decrease environmental impact. Downhole rotation is typically developed with a motor in the Bottom Hole Assembly (BHA) that develops drilling power (speed and torque) necessary to drive rock reduction mechanisms (i.e., the bit) apart from the rotation developed by the surface rig. Historically, wellbore deviation has been introduced by a “bent-sub,” located in the BHA, that introduces a small angular deviation, typically less than 3 degrees, to allow the bit to drill off-axis with orientation of the BHA controlled at the surface. The development of a high temperature downhole motor would allow reliable use of bent subs for geothermal directional drilling. Sandia National Laboratories is pursuing the development of a high temperature motor that will operate on either drilling fluid (water-based mud) or compressed air to enable drilling high temperature, high strength, fractured rock. The project consists of designing a power section based upon geothermal drilling requirements; modeling and analysis of potential solutions; and design, development and testing of prototype hardware to validate the concept. Drilling costs contribute substantially to geothermal electricity production costs. The present development will result in more reliable access to deep, hot geothermal resources and allow preferential wellbore trajectories to be achieved. This will enable development of geothermal wells with multi-lateral completions resulting in improved geothermal resource recovery, decreased environmental impact and enhanced well construction economics.

  3. High temperature two component explosive

    Science.gov (United States)

    Mars, James E.; Poole, Donald R.; Schmidt, Eckart W.; Wang, Charles

    1981-01-01

    A two component, high temperature, thermally stable explosive composition comprises a liquid or low melting oxidizer and a liquid or low melting organic fuel. The oxidizer and fuel in admixture are incapable of substantial spontaneous exothermic reaction at temperatures on the order of 475.degree. K. At temperatures on the order of 475.degree. K., the oxidizer and fuel in admixture have an activation energy of at least about 40 kcal/mol. As a result of the high activation energy, the preferred explosive compositions are nondetonable as solids at ambient temperature, and become detonable only when heated beyond the melting point. Preferable oxidizers are selected from alkali or alkaline earth metal nitrates, nitrites, perchlorates, and/or mixtures thereof. Preferred fuels are organic compounds having polar hydrophilic groups. The most preferred fuels are guanidinium nitrate, acetamide and mixtures of the two. Most preferred oxidizers are eutectic mixtures of lithium nitrate, potassium nitrate and sodium nitrate, of sodium nitrite, sodium nitrate and potassium nitrate, and of potassium nitrate, calcium nitrate and sodium nitrate.

  4. Understanding the role of defect production in radiation embrittlement of reactor pressure vessels.

    Energy Technology Data Exchange (ETDEWEB)

    Alexander, D. E.

    1999-08-04

    Comparative experiments using high energy (10 MeV) electrons and test reactor neutrons have been undertaken to understand the role that primary damage state has on hardening (embrittlement) induced by irradiation at 300 C. Electrons produce displacement damage primarily by low energy atomic recoils, while fast neutrons produce displacements from considerably higher energy recoils. Comparison of changes resulting from neutron irradiation, in which nascent point defect clusters can form in dense cascades, with electron irradiation, where cascade formation is minimized, can provide insight into the role that the in-cascade point defect clusters have on the mechanisms of embrittlement. Tensile property changes induced by 10 MeV electrons or test reactor neutron irradiations of unalloyed iron and an Fe-0.9 wt.% Cu-1.0 wt.% Mn alloy were examined in the damage range of 9.0 x 10{sup {minus}5} dpa to 1.5 x 10{sup {minus}2} dpa. The results to date showed the ternary alloy experienced substantially greater embrittlement in both the electron and neutron irradiated samples relative to unalloyed iron. Surprisingly, despite their disparate nature of defect production, similar embrittlement trends with increasing radiation damage were observed for electrons and neutrons in both the ternary and unalloyed iron.

  5. Correlating radiation exposure with embrittlement: Comparative studies of electron- and neutron-irradiated pressure vessel alloys

    Energy Technology Data Exchange (ETDEWEB)

    Alexander, D. E.; Rehn, L. E.; Odette, G. R.; Lucas, G. E.; Klingensmith, D.; Gragg, D.

    1999-12-22

    Comparative experiments using high energy (10 MeV) electrons and test reactor neutrons have been undertaken to understand the role that primary damage state has on hardening (embrittlement) induced by irradiation at 300 C. Electrons produce displacement damage primarily by low energy atomic recoils, while fast neutrons produce displacements from considerably higher energy recoils. Comparison of changes resulting from neutron irradiation, in which nascent point defect clusters can form in dense cascades, with electron irradiation, where cascade formation is minimized, can provide insight into the role that the in-cascade point defect clusters have on the mechanisms of embrittlement. Tensile property changes induced by 10 MeV electrons or test reactor neutron irradiations of unalloyed iron and an Fe-O.9 wt.% Cu-1.0 wt.% Mn alloy were examined in the damage range of 9.0 x 10{sup {minus}5} dpa to 1.5 x 10{sup {minus}2} dpa. The results show the ternary alloy experienced substantially greater embrittlement in both the electron and neutron irradiate samples relative to unalloyed iron. Despite their disparate nature of defect production similar embrittlement trends with increasing radiation damage were observed for electrons and neutrons in both the ternary and unalloyed iron.

  6. High temperature structural sandwich panels

    Science.gov (United States)

    Papakonstantinou, Christos G.

    High strength composites are being used for making lightweight structural panels that are being employed in aerospace, naval and automotive structures. Recently, there is renewed interest in use of these panels. The major problem of most commercial available sandwich panels is the fire resistance. A recently developed inorganic matrix is investigated for use in cases where fire and high temperature resistance are necessary. The focus of this dissertation is the development of a fireproof composite structural system. Sandwich panels made with polysialate matrices have an excellent potential for use in applications where exposure to high temperatures or fire is a concern. Commercial available sandwich panels will soften and lose nearly all of their compressive strength temperatures lower than 400°C. This dissertation consists of the state of the art, the experimental investigation and the analytical modeling. The state of the art covers the performance of existing high temperature composites, sandwich panels and reinforced concrete beams strengthened with Fiber Reinforced Polymers (FRP). The experimental part consists of four major components: (i) Development of a fireproof syntactic foam with maximum specific strength, (ii) Development of a lightweight syntactic foam based on polystyrene spheres, (iii) Development of the composite system for the skins. The variables are the skin thickness, modulus of elasticity of skin and high temperature resistance, and (iv) Experimental evaluation of the flexural behavior of sandwich panels. Analytical modeling consists of a model for the flexural behavior of lightweight sandwich panels, and a model for deflection calculations of reinforced concrete beams strengthened with FRP subjected to fatigue loading. The experimental and analytical results show that sandwich panels made with polysialate matrices and ceramic spheres do not lose their load bearing capability during severe fire exposure, where temperatures reach several

  7. High Temperature Heat Exchanger Project

    Energy Technology Data Exchange (ETDEWEB)

    Anthony E. Hechanova, Ph.D.

    2008-09-30

    The UNLV Research Foundation assembled a research consortium for high temperature heat exchanger design and materials compatibility and performance comprised of university and private industry partners under the auspices of the US DOE-NE Nuclear Hydrogen Initiative in October 2003. The objectives of the consortium were to conduct investigations of candidate materials for high temperature heat exchanger componets in hydrogen production processes and design and perform prototypical testing of heat exchangers. The initial research of the consortium focused on the intermediate heat exchanger (located between the nuclear reactor and hydrogen production plan) and the components for the hydrogen iodine decomposition process and sulfuric acid decomposition process. These heat exchanger components were deemed the most challenging from a materials performance and compatibility perspective

  8. Motor for High Temperature Applications

    Science.gov (United States)

    Roopnarine (Inventor)

    2013-01-01

    A high temperature motor has a stator with poles formed by wire windings, and a rotor with magnetic poles on a rotor shaft positioned coaxially within the stator. The stator and rotor are built up from stacks of magnetic-alloy laminations. The stator windings are made of high temperature magnet wire insulated with a vitreous enamel film, and the wire windings are bonded together with ceramic binder. A thin-walled cylinder is positioned coaxially between the rotor and the stator to prevent debris from the stator windings from reaching the rotor. The stator windings are wound on wire spools made of ceramic, thereby avoiding need for mica insulation and epoxy/adhesive. The stator and rotor are encased in a stator housing with rear and front end caps, and rear and front bearings for the rotor shaft are mounted on external sides of the end caps to keep debris from the motor migrating into the bearings' races.

  9. Very High Temperature Sound Absorption Coating Project

    Data.gov (United States)

    National Aeronautics and Space Administration — Phase I demonstrated experimentally a very high temperature acoustically absorbing coating for ducted acoustics applications. High temperature survivability at 3500...

  10. Nanoscale high-temperature superconductivity

    Energy Technology Data Exchange (ETDEWEB)

    Mohanty, P.; Wei, J.Y.T.; Ananth, V.; Morales, P.; Skocpol, W

    2004-08-01

    We discuss the exciting prospects of studying high-temperature superconductivity in the nanometer scale from the perspective of experiments, theory and simulation. In addition to enabling studies of novel quantum phases in an unexplored regime of system dimensions and parameters, nanoscale high-temperature superconducting structures will allow exploration of fundamental mechanisms with unprecedented insight. The prospects include, spin-charge separation, detection of electron fractionalization via novel excitations such as vison, stripe states and their dynamics, preformed cooper pairs or bose-condensation in the underdoped regime, and other quantum-ordered states. Towards this initiative, we present the successful development of a novel nanofabrication technique for the epitaxial growth of nanoscale cuprates. Combining the techniques of e-beam lithography and nanomachining, we have been able to fabricate the first generation of high-temperature superconducting nanoscale devices, including Y-junctions, four-probe wires and rings. Their initial transport characterization and scanning tunneling microscopy reveal the integrity of the crystal structure, grown on nanometer scale lateral dimensions. Here, we present atomic force micrographs and electrical characterization of a few nanoscale YBa{sub 2}Cu{sub 3}O{sub 7} (YBCO) samples.

  11. Joining and fabrication techniques for high temperature structures including the first wall in fusion reactor

    Energy Technology Data Exchange (ETDEWEB)

    Lee, Ho Jin; Lee, B. S.; Kim, K. B

    2003-09-01

    The materials for PFC's (Plasma Facing Components) in a fusion reactor are severely irradiated with fusion products in facing the high temperature plasma during the operation. The refractory materials can be maintained their excellent properties in severe operating condition by lowering surface temperature by bonding them to the high thermal conducting materials of heat sink. Hence, the joining and bonding techniques between dissimilar materials is considered to be important in case of the fusion reactor or nuclear reactor which is operated at high temperature. The first wall in the fusion reactor is heated to approximately 1000 .deg. C and irradiated severely by the plasma. In ITER, beryllium is expected as the primary armour candidate for the PFC's; other candidates including W, Mo, SiC, B4C, C/C and Si{sub 3}N{sub 4}. Since the heat affected zones in the PFC's processed by conventional welding are reported to have embrittlement and degradation in the sever operation condition, both brazing and diffusion bonding are being considered as prime candidates for the joining technique. In this report, both the materials including ceramics and the fabrication techniques including joining technique between dissimilar materials for PFC's are described. The described joining technique between the refractory materials and the dissimilar materials may be applicable for the fusion reactor and Generation-4 future nuclear reactor which are operated at high temperature and high irradiation.

  12. High temperature PEM fuel cells

    Science.gov (United States)

    Zhang, Jianlu; Xie, Zhong; Zhang, Jiujun; Tang, Yanghua; Song, Chaojie; Navessin, Titichai; Shi, Zhiqing; Song, Datong; Wang, Haijiang; Wilkinson, David P.; Liu, Zhong-Sheng; Holdcroft, Steven

    There are several compelling technological and commercial reasons for operating H 2/air PEM fuel cells at temperatures above 100 °C. Rates of electrochemical kinetics are enhanced, water management and cooling is simplified, useful waste heat can be recovered, and lower quality reformed hydrogen may be used as the fuel. This review paper provides a concise review of high temperature PEM fuel cells (HT-PEMFCs) from the perspective of HT-specific materials, designs, and testing/diagnostics. The review describes the motivation for HT-PEMFC development, the technology gaps, and recent advances. HT-membrane development accounts for ∼90% of the published research in the field of HT-PEMFCs. Despite this, the status of membrane development for high temperature/low humidity operation is less than satisfactory. A weakness in the development of HT-PEMFC technology is the deficiency in HT-specific fuel cell architectures, test station designs, and testing protocols, and an understanding of the underlying fundamental principles behind these areas. The development of HT-specific PEMFC designs is of key importance that may help mitigate issues of membrane dehydration and MEA degradation.

  13. Temperature uniformity mapping in a high pressure high temperature reactor using a temperature sensitive indicator

    NARCIS (Netherlands)

    Grauwet, T.; Plancken, van der I.; Vervoort, L.; Matser, A.M.; Hendrickx, M.; Loey, van A.

    2011-01-01

    Recently, the first prototype ovomucoid-based pressure–temperature–time indicator (pTTI) for high pressure high temperature (HPHT) processing was described. However, for temperature uniformity mapping of high pressure (HP) vessels under HPHT sterilization conditions, this prototype needs to be

  14. Functional and structural fatigue of titanium tantalum high temperature shape memory alloys (HT SMAs)

    Energy Technology Data Exchange (ETDEWEB)

    Niendorf, T., E-mail: Thomas.Niendorf@iwt.tu-freiberg.de [Institute of Materials Engineering, Technische Universität Bergakademie Freiberg, 09599 Freiberg (Germany); Krooß, P. [Lehrstuhl für Werkstoffkunde (Materials Science), University of Paderborn, 33098 Paderborn (Germany); Batyrsina, E. [Institut für Werkstoffkunde (Materials Science), Leibniz Universität Hannover, 30823 Garbsen (Germany); Paulsen, A.; Motemani, Y.; Ludwig, A.; Buenconsejo, P.; Frenzel, J.; Eggeler, G. [Institut für Werkstoffe, Ruhr-Universität Bochum, 44801 Bochum (Germany); Maier, H.J. [Institut für Werkstoffkunde (Materials Science), Leibniz Universität Hannover, 30823 Garbsen (Germany)

    2015-01-03

    Due to their high work output and good mechanical properties, actuators made from shape memory alloys (SMAs) are used in numerous applications. Unfortunately, SMAs such as nickel–titanium (Ni–Ti) can only be employed at temperatures up to about 100 °C. Lately, high-temperature shape memory alloys (HT SMAs) have been introduced to overcome this limitation. Ternary systems based on Ni–Ti have been intensively characterized and alloys are available that can operate at elevated temperatures. However, these alloys either contain substantial amounts of expensive noble elements like platinum and palladium, or the materials are brittle. The titanium–tantalum (Ti–Ta) system has been developed to overcome these issues. Binary Ti–Ta provides relatively high M{sub S} temperature combined with excellent workability, but it suffers from fast cyclic degradation. By alloying with third elements this drawback can be overcome: The ternary Ti–Ta–Al alloy shows overall promising properties as will be shown in the present work. In-situ thermo-mechanical cycling experiments were conducted and allowed for evaluation of the factors affecting the functional and structural fatigue of this alloy. Functional fatigue is dominated by ω-phase evolution, while structural fatigue is triggered by an interplay of ω-phase induced embrittlement and deformation constraints imposed by unsuitable texture. In addition, a concept for fatigue life extension proposed very recently for binary Ti–Ta, is demonstrated to be also applicable for the ternary Ti–Ta–Al.

  15. High Temperature Radio Frequency Loads

    CERN Document Server

    Federmann, S; Grudiev, A; Montesinos, E; Syratchev, I

    2011-01-01

    In the context of energy saving and recovery requirements the design of reliable and robust RF power loads which permit a high outlet temperature and high pressure of the cooling water is desirable. Cooling water arriving at the outlet withmore than 150 ◦C and high pressure has a higher value than water with 50 ◦C under low pressure. Conventional RF power loads containing dielectric and magnetic materials as well as sensitive ceramic windows usually do not permit going much higher than 90 ◦C. Here we present and discuss several design concepts for "metal only" RF high power loads. One concept is the application of magnetic steel corrugated waveguides near cutoff – this concept could find practical use above several GHz. Another solution are resonant structures made of steel to be installed in large waveguides for frequencies of 500 MHz or lower. Similar resonant structures above 100 MHz taking advantage of the rather high losses of normal steel may also be used in coaxial line geometries with large di...

  16. High Temperature Superconductor Accelerator Magnets

    CERN Document Server

    AUTHOR|(CDS)2079328; de Rijk, Gijs; Dhalle, Marc

    2016-11-10

    For future particle accelerators bending dipoles are considered with magnetic fields exceeding $20T$. This can only be achieved using high temperature superconductors (HTS). These exhibit different properties from classical low temperature superconductors and still require significant research and development before they can be applied in a practical accelerator magnet. In order to study HTS in detail, a five tesla demonstrator magnet named Feather-M2 is designed and constructed. The magnet is based on ReBCO coated conductor, which is assembled into a $10kA$ class Roebel cable. A new and optimized Aligned Block layout is used, which takes advantage of the anisotropy of the conductor. This is achieved by providing local alignment of the Roebel cable in the coil windings with the magnetic field lines. A new Network Model capable of analyzing transient electro-magnetic and thermal phenomena in coated conductor cables and coils is developed. This model is necessary to solve critical issues in coated conductor ac...

  17. Faraday imaging at high temperatures

    Science.gov (United States)

    Hackel, Lloyd A.; Reichert, Patrick

    1997-01-01

    A Faraday filter rejects background light from self-luminous thermal objects, but transmits laser light at the passband wavelength, thus providing an ultra-narrow optical bandpass filter. The filter preserves images so a camera looking through a Faraday filter at a hot target illuminated by a laser will not see the thermal radiation but will see the laser radiation. Faraday filters are useful for monitoring or inspecting the uranium separator chamber in an atomic vapor laser isotope separation process. Other uses include viewing welds, furnaces, plasma jets, combustion chambers, and other high temperature objects. These filters are can be produced at many discrete wavelengths. A Faraday filter consists of a pair of crossed polarizers on either side of a heated vapor cell mounted inside a solenoid.

  18. Charles J. McMahon Interfacial Segregation and Embrittlement Symposium

    National Research Council Canada - National Science Library

    Vitek, Vaclav

    2003-01-01

    .... McMahon Interfacial Segregation and Embrittlement Symposium: Grain Boundary Segregation and Fracture in Steels was sponsored by ASM International, Materials Science Critical Technology Sector, Structural Materials Division, Materials Processing...

  19. High temperature autoclave vacuum seals

    Science.gov (United States)

    Hoffman, J. R.; Simpson, W. G.; Walker, H. M.

    1971-01-01

    Aluminum sheet forms effective sealing film at temperatures up to 728 K. Soft aluminum wire rings provide positive seal between foil and platen. For applications at temperatures above aluminum's service temperature, stainless steel is used as film material and copper wire as sealant.

  20. Neutron radiation embrittlement studies in support of continued operation, and validation by sampling of Magnox reactor steel pressure vessels and components

    Energy Technology Data Exchange (ETDEWEB)

    Jones, R.B.; Bolton, C.J. [Magnox Electric plc, Berkeley Centre, Glos (United Kingdom)

    1997-02-01

    Magnox steel reactor pressure vessels differ significantly from US LWR vessels in terms of the type of steel used, as well as their operating environment (dose level, exposure temperature range, and neutron spectra). The large diameter ferritic steel vessels are constructed from C-Mn steel plates and forgings joined together with manual metal and submerged-arc welds which are stress-relieved. All Magnox vessels are now at least thirty years old and their continued operation is being vigorously pursued. Vessel surveillance and other programmes are summarized which support this objective. The current understanding of the roles of matrix irradiation damage, irradiation-enhanced copper impurity precipitation and intergranular embrittlement effects is described in so far as these influence the form of the embrittlement and hardening trend curves for each material. An update is given on the influence of high temperature exposure, and on the role of differing neutron spectra. Finally, the validation offered by the results of an initial vessel sampling exercise is summarized together with the objectives of a more extensive future sampling programme.

  1. High Temperature Solid Lubricant Coating for High Temperature Wear Applications

    Science.gov (United States)

    DellaCorte, Christopher (Inventor); Edmonds, Brian J (Inventor)

    2014-01-01

    A self-lubricating, friction and wear reducing composite useful over a wide temperature range is described herein. The composite includes metal bonded chromium oxide dispersed in a metal binder having a substantial amount of nickel. The composite contains a fluoride of at least one Group I, Group II, or rare earth metal, and optionally a low temperature lubricant metal.

  2. Neutron-induced dpa, transmutations, gas production, and helium embrittlement of fusion materials

    CERN Document Server

    Gilbert, M R; Nguyen-Manh, D; Zheng, S; Packer, L W; Sublet, J -Ch

    2013-01-01

    In a fusion reactor materials will be subjected to significant fluxes of high-energy neutrons. As well as causing radiation damage, the neutrons also initiate nuclear reactions leading to changes in the chemical composition of materials (transmutation). Many of these reactions produce gases, particularly helium, which cause additional swelling and embrittlement of materials. This paper investigates, using a combination of neutron-transport and inventory calculations, the variation in displacements per atom (dpa) and helium production levels as a function of position within the high flux regions of a recent conceptual model for the "next-step" fusion device DEMO. Subsequently, the gas production rates are used to provide revised estimates, based on new density-functional-theory results, for the critical component lifetimes associated with the helium-induced grain-boundary embrittlement of materials. The revised estimates give more optimistic projections for the lifetimes of materials in a fusion power plant co...

  3. NEW Fe-C-Mn-Si-Cr BEARING ALLOY: TEMPERING CURVES AND TEMPERED MARTENSITE EMBRITTLEMENT

    Directory of Open Access Journals (Sweden)

    José Benedito Marcomini

    2012-12-01

    Full Text Available SAE 52100 steel is not only used as a rolled raw material for bearing manufacturing but for building some rolling devices as well, such as guide rollers and straightener rollers. The purpose of this work is the characterization of a Fe-C-Mn-Si-Cr bearing alloy (SAE 52100 steel, modified with 1.74% Si by plotting the variation of quenched and tempered hardness curve (tempering curve and tempered martensite embrittlement susceptibility. The present application is based on the same idea as 300M steel regarding SAE 4340 steel. The effect of silicon on the kinetics of cementite precipitation leads to a rise in temperature of tempered martensite embrittlement. Quench and temper treatments were carried out and impact tests were performed with modified and commercial steels and the results were compared. Microstructure aspects are studied by scanning electron microscopy and x-ray diffraction analysis. The silicon alloyed steel presents great resistance to softening after tempering and no tempered martensite embrittlement.

  4. Evaluation of Temper Embrittlement of 30Cr2MoV Rotor Steels Using Electrochemical Impedance Spectroscopy Technique

    Directory of Open Access Journals (Sweden)

    Zhang Shenghan

    2015-01-01

    Full Text Available Temper embrittlement tends to occur in the turbine rotor after long running, which refers to the decrease in notch toughness of alloy steels in a certain temperature range (e.g., 400°C to 600°C. The severity of temper embrittlement must be monitored timely to avoid further damagement, and the fracture appearance transition temperature (FATT50 is commonly used as an indicator parameter to characterize the temper embrittlement. Compared with conventional destructive methods (e.g., small punch test, nondestructive approaches have drawn significant attention in predicting the material degradation in turbine rotor steels without impairing the integrity of the components. In this paper, laboratory experiments were carried out based on a nondestructive method, electrochemical impedance spectroscopy (EIS, with groups of lab-charged specimens for predicting the temper embrittlement (FATT50 of turbine rotor steel. The results show that there was a linear relationship of interfacial impedance of the specimens and their FATT50 values. The predictive error based on the experiment study is within the range of ±15°C, indicating the predicting model is precise, effective, and reasonable.

  5. Influence of the composition on the radiation embrittlement alloys; Einfluss der Zusammensetzung auf die Strahlenversproedungslegierungen

    Energy Technology Data Exchange (ETDEWEB)

    Boehmert, J.; Kryukov, A.; Nikolaev, Yu.A.; Korolev, Yu.N.; Erak, D.Yu.; Gerashenko, S.S.

    1999-02-01

    The radiation embrittlement of the reactor pressure vessel is highly safety-relevant for VVER-type pressure vessels. The sensitivity against radiation embrittlement depends on the chemical composition of the pressure vessel steel. Using an irradiation experiment at surveillance positions in two Russian VVER 440-type reactors the effects of copper, phosphorus and nickel on the radiation embrittlement should be investigated. For that, eight mock-up alloys were selected. Their chemical composition varied between 0.015 and 0.42% Cu, 0.002 and 0.039% P, 0.01 and 1.98% Ni, 0.09 and 0.37% Si, and 0.35 and 0.49% Mn. Charpy-V impact tests and tensile tests were performed with specimens machined from these alloys. The specimens were tested in the as-received state, in the irradiated state (fluence: 1x10{sup 19} and 8x10{sup 19}/cm{sup 2} [E>0.5 MeV]) and in the post-irradiation annealed state. In the as-received state, the alloys have a ferritic microstructure. Apart from Cu, the alloyed elements are solved in the matrix. Irradiation produces strong hardening and embrittlement. The effect increases with the Cu and P content. Ni causes an additional embrittlement. It is independent on the Ni concentration within the range of 1.1 to 2% Ni and results in a shift of the ductile-brittle transition temperature of about 120 C after a fluence of 1x10{sup 19}/cm{sup 2} by a flux of 4x10{sup 11}/cm{sup 2} s. The shift does not depend on the Cu or P content. Furthermore, the upper shelf energy is especially reduced by the Mi-rich alloys. For very low content of Cu and P these relations are not valid. The irradiation effect can be eliminated by annealing at 475 C/100 h. For high content of Cu or P the recovery is incomplete, it remains a residue of 20 to 25% of the irradiation effect. Ni has no influence on the recovery. Comparing the results of this study with the ones of the surveillance programmes of the VVER 440-type reactors, the alloys with low Ni content show the same irradiation

  6. High-temperature borehole instrumentation

    Science.gov (United States)

    Dennis, B. R.; Koczan, S. P.; Stephani, E. L.

    1985-10-01

    A new method of extracting natural heat from the Earth's crust was invented at the Los Alamos National Laboratory in 1970. It uses fluid pressures (hydraulic fracturing) to produce cracks that connect two boreholes drilled into hot rock formations of low initial permeability. Pressurized water is then circulated through this connected underground loop to extract heat from the rock and bring it to the surface. The creation of the fracture reservior began with drilling boreholes deep within the Precambrian basement rock at the Fenton Hill Test Site. Hydraulic fracturing, flow testing, and well-completion operations required unique wellbore measurements using downhole instrumentation systems that would survive the very high borehole temperatures, 320(0)C (610(0)F). These instruments were not available in the oil and gas industrial complex, so the Los Alamos National Laboratory initiated an intense program upgrading existing technology where applicable, subcontracting materials and equipment development to industrial manufactures, and using the Laboratory resources to develop the necessary downhole instruments to meet programmatic schedules.

  7. High Temperature Superconducting Underground Cable

    Energy Technology Data Exchange (ETDEWEB)

    Farrell, Roger, A.

    2010-02-28

    The purpose of this Project was to design, build, install and demonstrate the technical feasibility of an underground high temperature superconducting (HTS) power cable installed between two utility substations. In the first phase two HTS cables, 320 m and 30 m in length, were constructed using 1st generation BSCCO wire. The two 34.5 kV, 800 Arms, 48 MVA sections were connected together using a superconducting joint in an underground vault. In the second phase the 30 m BSCCO cable was replaced by one constructed with 2nd generation YBCO wire. 2nd generation wire is needed for commercialization because of inherent cost and performance benefits. Primary objectives of the Project were to build and operate an HTS cable system which demonstrates significant progress towards commercial progress and addresses real world utility concerns such as installation, maintenance, reliability and compatibility with the existing grid. Four key technical areas addressed were the HTS cable and terminations (where the cable connects to the grid), cryogenic refrigeration system, underground cable-to-cable joint (needed for replacement of cable sections) and cost-effective 2nd generation HTS wire. This was the world’s first installation and operation of an HTS cable underground, between two utility substations as well as the first to demonstrate a cable-to-cable joint, remote monitoring system and 2nd generation HTS.

  8. AISI/DOE Technology Roadmap Program: Cold Work Embrittlement of Interstitial Free Steel

    Energy Technology Data Exchange (ETDEWEB)

    John T Bowker; Pierre Martin

    2002-10-31

    This work addresses the issues of measurement of secondary cold work embrittlement (SCWE) of an IF steel in deep-drawn parts using laboratory tests, and its correlation with real part fracture. It aimed at evaluating the influence of the steel chemistry and processing condition, microstructure, and test conditions, on SCWE as well as the effect of SCWE on fatigue properties. Size 6-in. cups produced with various draw ratios or trimmed at different heights were tested to determine the ductile-to-brittle-transition temperature (DBTT) as a function of strain. The 2-in. cup/expansion test, bend test and fracture of notched specimens were also used to generate information complementary to that provided by the 6-inch cup/expansion test. The relationship between laboratory tests and fracture in real parts was established by testing large-scale parts. The fatigue behavior was investigated in the as-rolled and deep drawn (high stain) conditions, using prestrained specimens taken from the wall of a formed part.

  9. High Temperature Chemistry at NASA: Hot Topics

    Science.gov (United States)

    Jacobson, Nathan S.

    2014-01-01

    High Temperature issues in aircraft engines Hot section: Ni and Co based Superalloys Oxidation and Corrosion (Durability) at high temperatures. Thermal protection system (TPS) and RCC (Reinforced Carbon-Carbon) on the Space Shuttle Orbiter. High temperatures in other worlds: Planets close to their stars.

  10. High temperature vapors science and technology

    CERN Document Server

    Hastie, John

    2012-01-01

    High Temperature Vapors: Science and Technology focuses on the relationship of the basic science of high-temperature vapors to some areas of discernible practical importance in modern science and technology. The major high-temperature problem areas selected for discussion include chemical vapor transport and deposition; the vapor phase aspects of corrosion, combustion, and energy systems; and extraterrestrial high-temperature species. This book is comprised of seven chapters and begins with an introduction to the nature of the high-temperature vapor state, the scope and literature of high-temp

  11. Using Small Punch tests in environment under static load for fracture toughness estimation in hydrogen embrittlement

    Science.gov (United States)

    Arroyo, B.; Álvarez, J. A.; Lacalle, R.; González, P.; Gutiérrez-Solana, F.

    2017-12-01

    In this paper, the response of three medium and high-strength steels to hydrogen embrittlement is analyzed by means of the quasi-non-destructive test known as the Small Punch Test (SPT). SPT tests on notched specimens under static load are carried out, applying Lacaclle’s methodology to estimate the fracture toughness for crack initiation, comparing the results to KIEAC fracture toughness obtained from C(T) precracked specimens tested in the same environment; SPT showed good correlation to standard tests. A novel expression was proposed to define the parameter KIEAC-SP as the suitable one to estimate the fracture toughness for crack initiation in hydrogen embrittlement conditions by Small Punch means, obtaining good accuracy in its estimations. Finally, Slow Rate Small Punch Tests (SRSPT) are proposed as a more efficient alternative, introducing an order of magnitude for the adequate rate to be employed.

  12. Grain-boundary engineering markedly reduces susceptibility to intergranular hydrogen embrittlement in metallic materials

    Energy Technology Data Exchange (ETDEWEB)

    Bechtle, Sabine; Kumar, Mukul; Somerday, Brian P.; Launey, Maximilien E.; Ritchie, Robert O.

    2009-05-10

    The feasibility of using 'grain-boundary engineering' techniques to reduce the susceptibility of a metallic material to intergranular embrittlement in the presence of hydrogen is examined. Using thermomechanical processing, the fraction of 'special' grain boundaries was increased from 46% to 75% (by length) in commercially pure nickel samples. In the presence of hydrogen concentrations between 1200 and 3400 appm, the high special fraction microstructure showed almost double the tensile ductility; also, the proportion of intergranular fracture was significantly lower and the J{sub c} fracture toughness values were some 20-30% higher in comparison with the low special fraction microstructure. We attribute the reduction in the severity of hydrogen-induced intergranular embrittlement to the higher fraction of special grain boundaries, where the degree of hydrogen segregation at these boundaries is reduced.

  13. Evaluation on the Effect of Composition on Radiation Hardening and Embrittlement in Model FeCrAl Alloys

    Energy Technology Data Exchange (ETDEWEB)

    Field, Kevin G. [Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States); Briggs, Samuel A. [Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States); Edmondson, Philip [Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States); Hu, Xunxiang [Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States); Littrell, Kenneth C. [Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States); Howard, Richard [Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States); Parish, Chad M. [Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States); Yamamoto, Yukinori [Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States)

    2015-09-18

    This report details the findings of post-radiation mechanical testing and microstructural characterization performed on a series of model and commercial FeCrAl alloys to assist with the development of a cladding technology with enhanced accident tolerance. The samples investigated include model alloys with simple ferritic grain structure and two commercial alloys with minor solute additions. These samples were irradiated in the High Flux Isotope Reactor (HFIR) at Oak Ridge National Laboratory (ORNL) up to nominal doses of 7.0 dpa near or at Light Water Reactor (LWR) relevant temperatures (300-400 C). Characterization included a suite of techniques including small angle neutron scattering (SANS), atom probe tomography (APT), and transmission based electron microscopy techniques. Mechanical testing included tensile tests at room temperature on sub-sized tensile specimens. The goal of this work was to conduct detailed characterization and mechanical testing to begin establishing empirical and/or theoretical structure-property relationships for radiation-induced hardening and embrittlement in the FeCrAl alloy class. Development of such relationships will provide insight on the performance of FeCrAl alloys in an irradiation environment and will enable further development of the alloy class for applications within a LWR environment. A particular focus was made on establishing trends, including composition and radiation dose. The report highlights in detail the pertinent findings based on this work. This report shows that radiation hardening in the alloys is primarily composition dependent due to the phase separation in the high-Cr FeCrAl alloys. Other radiation induced/enhanced microstructural features were less dependent on composition and when observed at low number densities, were not a significant contributor to the observed mechanical responses. Pre-existing microstructure in the alloys was found to be important, with grain boundaries and pre-existing dislocation

  14. Phase field modeling of liquid metal embrittlement

    Science.gov (United States)

    Spatschek, Robert; Wang, Nan; Karma, Alain

    2008-03-01

    Liquid metal embrittlement (LME) is a phenomenon whereby a liquid metal in contact with another, higher-melting-point polycrystalline metal, rapidly penetrates from the surface along grain boundaries. This phenomenon is known to be greatly accelerated by the application of tensile stress, resulting in the rapid propagation of intergranular cracks in normally ductile materials. Although this phenomenon has been known for a long time, it still lacks a convincing physical explanation. In particular, the relationship of LME to conventional fracture mechanics remains unclear. We investigate LME using a phenomenological three-order-parameter phase field model that describes both the short scale physics of crystal decohesion and macroscopic linear elasticity. The model reproduces expected macroscopic properties for well separated crack surfaces and additionally introduces short scale modifications for liquid layer thicknesses in the nanometric range, which depend on the interfacial and grain boundary energy as well as elastic effects. The results shed light on the relative importance of capillary phenomena and stress in the kinetics of LME.

  15. Measurement of thermodynamic temperature of high temperature fixed points

    Energy Technology Data Exchange (ETDEWEB)

    Gavrilov, V. R.; Khlevnoy, B. B.; Otryaskin, D. A.; Grigorieva, I. A.; Samoylov, M. L.; Sapritsky, V. I. [All-Russian Research Institute for Optical and Physical Measurements (VNIIOFI), 46 Ozernaya St., Moscow 119361 (Russian Federation)

    2013-09-11

    The paper is devoted to VNIIOFI's measurements of thermodynamic temperature of the high temperature fixed points Co-C, Pt-C and Re-C within the scope of the international project coordinated by the Consultative Committee for Thermometry working group 5 'Radiation Thermometry'. The melting temperatures of the fixed points were measured by a radiance mode radiation thermometer calibrated against a filter radiometer with known irradiance spectral responsivity via a high temperature black body. This paper describes the facility used for the measurements, the results and estimated uncertainties.

  16. Measurement of thermodynamic temperature of high temperature fixed points

    Science.gov (United States)

    Gavrilov, V. R.; Khlevnoy, B. B.; Otryaskin, D. A.; Grigorieva, I. A.; Samoylov, M. L.; Sapritsky, V. I.

    2013-09-01

    The paper is devoted to VNIIOFI's measurements of thermodynamic temperature of the high temperature fixed points Co-C, Pt-C and Re-C within the scope of the international project coordinated by the Consultative Committee for Thermometry working group 5 "Radiation Thermometry". The melting temperatures of the fixed points were measured by a radiance mode radiation thermometer calibrated against a filter radiometer with known irradiance spectral responsivity via a high temperature black body. This paper describes the facility used for the measurements, the results and estimated uncertainties.

  17. (Krauss) at constant high temperatures

    African Journals Online (AJOL)

    A number of opinions are held on the relative importance of the various physical ... optimum as well as extreme temperatures on vital functions such as survival, egg ..... solids on the biology of certain freshwater molluscs. D .Sc. thesis,. Potch.

  18. Effect of high-temperature water and hydrogen on the fracture behavior of a low-alloy reactor pressure vessel steel

    Energy Technology Data Exchange (ETDEWEB)

    Roychowdhury, S., E-mail: sroy27@gmail.com [Paul Scherrer Institut, Nuclear Energy and Safety Research Department, Laboratory for Nuclear Materials, 5232 Villigen, PSI (Switzerland); Materials Processing & Corrosion Engineering Division, Mod-Lab, D-Block, Bhabha Atomic Research Centre, Mumbai 400085 (India); Seifert, H.-P.; Spätig, P.; Que, Z. [Paul Scherrer Institut, Nuclear Energy and Safety Research Department, Laboratory for Nuclear Materials, 5232 Villigen, PSI (Switzerland)

    2016-09-15

    Structural integrity of reactor pressure vessels (RPV) is critical for safety and lifetime. Possible degradation of fracture resistance of RPV steel due to exposure to coolant and hydrogen is a concern. In this study tensile and elastic-plastic fracture mechanics (EPFM) tests in air (hydrogen pre-charged) and EFPM tests in hydrogenated/oxygenated high-temperature water (HTW) was done, using a low-alloy RPV steel. 2–5 wppm hydrogen caused embrittlement in air tensile tests at room temperature (25 °C) and at 288 °C, effects being more significant at 25 °C and in simulated weld coarse grain heat affected zone material. Embrittlement at 288 °C is strain rate dependent and is due to localized plastic deformation. Hydrogen pre-charging/HTW exposure did not deteriorate the fracture resistance at 288 °C in base metal, for investigated loading rate range. Clear change in fracture morphology and deformation structures was observed, similar to that after air tests with hydrogen. - Highlights: • Hydrogen content, microstructure of LAS, and strain rate affects tensile properties at 288 °C. • Strength affects hydrogen embrittlement susceptibility to a greater extent than grain size. • Hydrogen in LAS leads to strain localization and restricts cross-slip at 288 °C. • Possible hydrogen pickup due to exposure to 288 °C water alters fracture surface appearance without affecting fracture toughness in bainitic base material. • Simulated weld heat affected zone microstructure shows unstable crack propagation in 288 °C water.

  19. High temperature superconducting fault current limiter

    Science.gov (United States)

    Hull, John R.

    1997-01-01

    A fault current limiter (10) for an electrical circuit (14). The fault current limiter (10) includes a high temperature superconductor (12) in the electrical circuit (14). The high temperature superconductor (12) is cooled below its critical temperature to maintain the superconducting electrical properties during operation as the fault current limiter (10).

  20. Technological Evolution of High Temperature Superconductors

    Science.gov (United States)

    2015-12-01

    TEMPERATURE SUPERCONDUCTORS by Jordan R. White December 2015 Thesis Advisor: Clifford Whitcomb Co-Advisor: Fotis Papoulias THIS PAGE INTENTIONALLY...AND SUBTITLE TECHNOLOGICAL EVOLUTION OF HIGH TEMPERATURE SUPERCONDUCTORS 5. FUNDING NUMBERS 6. AUTHOR(S) Jordan R. White 7. PERFORMING ORGANIZATION...trends. 14. SUBJECT TERMS electric ships, high temperature superconductor , HTS 15. NUMBER OF PAGES 111 16. PRICE CODE 17. SECURITY CLASSIFICATION

  1. Deep Trek High Temperature Electronics Project

    Energy Technology Data Exchange (ETDEWEB)

    Bruce Ohme

    2007-07-31

    This report summarizes technical progress achieved during the cooperative research agreement between Honeywell and U.S. Department of Energy to develop high-temperature electronics. Objects of this development included Silicon-on-Insulator (SOI) wafer process development for high temperature, supporting design tools and libraries, and high temperature integrated circuit component development including FPGA, EEPROM, high-resolution A-to-D converter, and a precision amplifier.

  2. NDT methods for life-time assessment of high temperature plant; Ofoerstoerande provning foer livslaengdsbedoemning av hoegtemperaturanlaeggningar

    Energy Technology Data Exchange (ETDEWEB)

    Storesund, J. [Swedish Inst. for Metals Research, Stockholm (Sweden)

    1996-10-01

    A comprehensive literature study of NDT and analysis methods for residual life-time assessment of high temperature plant has been made. The study has been concentrated on components in boilers, steam piping and turbines in fossil fired power plant. Most types of components are exposed to creep which is also the life-time limiting mechanism in many cases. In addition to creep, other stresses and damages which appear in plant are described for each type of component. Thermal fatigue, corrosion and embrittlement as well as combined damage mechanisms are also life-time limiting in many cases. The literature shows a large number of NDT methods developed and under development in purpose to identify and measure the size and extent of damage in the components. The methods and their limitations are described in relation to the experience and understanding of character, distribution and development of damage in different situations. 83 refs, 12 figs, 1 tab

  3. Embrittling Components in Sintered Steels: Comparison of Phosphorus and Boron

    Science.gov (United States)

    Danninger, Herbert; Vassileva, Vassilka; Gierl-Mayer, Christian

    2017-12-01

    In ferrous powder metallurgy, both boron and phosphorus have been known to be sintering activators for a long time. However, the use has been widely different: while P is a standard additive to sintered iron and steels, boron has been frequently studied, but its use in practice is very limited. Both additives are also known to be potentially embrittling, though in a different way. In the present study the differences between the effects of both elements are shown: while P activates sintering up to a certain threshold, in part by stabilizing ferrite, in part by forming a transient liquid phase, boron is the classical additive enhancing persistent liquid phase, being virtually insoluble in the iron matrix. The consequence is that sintered steels can tolerate quite a proportion of phosphorus, depending on composition and sintering process; boron however is strongly embrittling in particular in combination with carbon, which requires establishing a precisely defined content that enhances sintering but is not yet embrittling. The fracture mode of embrittled materials is also different: while with Fe-P the classical intergranular fracture is observed, with boron a much more rugged fracture surface appears, indicating some failure through the eutectic interparticle network but mostly transgranular cleavage. If carbon is added, in both cases transgranular cleavage dominates even in the severely embrittled specimens, indicating that no more the grain boundaries and sintering necks are the weakest links in the systems.

  4. Grain boundary embrittlement and cohesion enhancement in copper

    Energy Technology Data Exchange (ETDEWEB)

    Paxton, Anthony; Lozovoi, Alexander [Atomistic Simulation Centre, Queen' s University Belfast, BT7 1NN (United Kingdom); Schweinfest, Rainer [Science+Computing ag, Hagellocher Weg 71-5, 720270 T ubingen (Germany); Finnis, Michael [Imperial College London, Exhibition Road, London SW7 2AZ (United Kingdom)

    2008-07-01

    There has been a long standing debate surrounding the mechanism of grain boundary embrittlement and cohesion enhancement in metals. Embrittlement can lead to catastrophic failure such as happened in the Hinkley Point disaster, or indeed in the case of the Titanic. This kind of embrittlement is caused by segregation of low solubility impurities to grain boundaries. While the accepted wisdom is that this is a phenomenon driven by electronic or chemical factors, using language such as charge transfer and electronegativity difference; we believe that in copper, at least, both cohesion enhancement and reduction are caused by a simple size effect. We have developed a theory that allows us to separate unambiguously, if not uniquely, chemical and structural factors. We have studied a large number of solutes in copper using first principles atomistic simulation to support this argument, and the results of these calculations are presented here.

  5. Investigation of Teflon FEP Embrittlement on Spacecraft in Low Earth Orbit

    Science.gov (United States)

    deGroh, Kim K.; Smith, Daniela C.

    1997-01-01

    Teflon(registered trademark) FEP (fluorinated ethylene-propylene) is commonly used on exterior spacecraft surfaces in the low Earth orbit (LEO) environment for thermal control. Silverized or aluminized FEP is used for the outer layer of thermal control blankets because of its low solar absorptance and high thermal emittance. FEP is also preferred over other spacecraft polymers because of its relatively high resistance to atomic oxygen erosion. Because of its low atomic oxygen erosion yield, FEP has not been protected in the space environment. Recent, long term space exposures such as on the Long Duration Exposure Facility (LDEF, 5.8 years in space), and the Hubble Space Telescope (HST, after 3.6 years in space) have provided evidence of LEO environmental degradation of FEP. These exposures provide unique opportunities for studying environmental degradation because of the long durations and the different conditions (such as differences in altitude) of the exposures. Samples of FEP from LDEF and from HST (retrieved during its first servicing mission) have been evaluated for solar induced embrittlement and for synergistic effects of solar degradation and atomic oxygen. Micro-indenter results indicate that the surface hardness increased as the ratio of atomic oxygen fluence to solar fluence decreased for the LDEF samples. FEP multilayer insulation (MLI) retrieved from HST provided evidence of severe embrittlement on solar facing surfaces. Micro-indenter measurements indicated higher surface hardness values for these samples than LDEF samples, but the solar exposures were higher. Cracks induced during bend testing were significantly deeper for the HST samples with the highest solar exposure than for LDEF samples with similar atomic oxygen fluence to solar fluence ratios. If solar fluences are compared, the LDEF samples appear as damaged as HST samples, except that HST had deeper induced cracks. The results illustrate difficulties in comparing LEO exposed materials from

  6. Thermoelastic properties of minerals at high temperature

    Indian Academy of Sciences (India)

    under high temperatures and calculated the second-order elastic constant (Cij ) and bulk modulus. (KT) of the above minerals, in two cases first by taking Anderson–Gruneisen parameter (δT) as temperature-independent and then by treating δT as temperature-dependent parameter. The results obtained when δT is ...

  7. High Temperature Capacitors for Venus Exploration Project

    Data.gov (United States)

    National Aeronautics and Space Administration — In this SBIR program, TRS Technologies has developed several new dielectrics for high temperature applications including signal conditioning, filtering and energy...

  8. Advances in high temperature chemistry 1

    CERN Document Server

    Eyring, Leroy

    2013-01-01

    Advances in High Temperature Chemistry, Volume 1 describes the complexities and special and changing characteristics of high temperature chemistry. After providing a brief definition of high temperature chemistry, this nine-chapter book goes on describing the experiments and calculations of diatomic transition metal molecules, as well as the advances in applied wave mechanics that may contribute to an understanding of the bonding, structure, and spectra of the molecules of high temperature interest. The next chapter provides a summary of gaseous ternary compounds of the alkali metals used in

  9. High temperature phase equilibria and phase diagrams

    CERN Document Server

    Kuo, Chu-Kun; Yan, Dong-Sheng

    2013-01-01

    High temperature phase equilibria studies play an increasingly important role in materials science and engineering. It is especially significant in the research into the properties of the material and the ways in which they can be improved. This is achieved by observing equilibrium and by examining the phase relationships at high temperature. The study of high temperature phase diagrams of nonmetallic systems began in the early 1900s when silica and mineral systems containing silica were focussed upon. Since then technical ceramics emerged and more emphasis has been placed on high temperature

  10. High-Temperature Test Technology

    Science.gov (United States)

    1987-03-01

    Do any of your facilities have vacuum test capability? YesO No~l If yes, What is the minimum vacuum chamber pressure? What is the maximum allowable...available? YesO N[-- If "yes," please Indicate the following: Vaporizer Superheater Capacity Capacity Max Temperature LH2 LN2 Are gaseous hydrogen...personnel safety? 5. Does the facility have radiant heating capability? YesO NoF- If "yes," please provide the following information: Lamp types Tungsten

  11. Thermodynamics of High Temperature Materials.

    Science.gov (United States)

    1985-03-15

    temperatures In the present range have also been obtained by Krauss and Warncke [8] and by Vollmer et al. [9], using adiabatic calorimetry, and by Kollie [10...value for heat capacity. The electrical resistivity results reported by Kollie [10] and by Powell et al. [13] are respectively about 1 and 1.5% lower...extensive annealing of the specimens used in the measurements: the specimen (>99.89% pure) used by Kollie was annealed at 1100 K for 24 h and Laubitz et al

  12. Investigations into High Temperature Components and Packaging

    Energy Technology Data Exchange (ETDEWEB)

    Marlino, L.D.; Seiber, L.E.; Scudiere, M.B.; M.S. Chinthavali, M.S.; McCluskey, F.P.

    2007-12-31

    The purpose of this report is to document the work that was performed at the Oak Ridge National Laboratory (ORNL) in support of the development of high temperature power electronics and components with monies remaining from the Semikron High Temperature Inverter Project managed by the National Energy Technology Laboratory (NETL). High temperature electronic components are needed to allow inverters to operate in more extreme operating conditions as required in advanced traction drive applications. The trend to try to eliminate secondary cooling loops and utilize the internal combustion (IC) cooling system, which operates with approximately 105 C water/ethylene glycol coolant at the output of the radiator, is necessary to further reduce vehicle costs and weight. The activity documented in this report includes development and testing of high temperature components, activities in support of high temperature testing, an assessment of several component packaging methods, and how elevated operating temperatures would impact their reliability. This report is organized with testing of new high temperature capacitors in Section 2 and testing of new 150 C junction temperature trench insulated gate bipolar transistor (IGBTs) in Section 3. Section 4 addresses some operational OPAL-GT information, which was necessary for developing module level tests. Section 5 summarizes calibration of equipment needed for the high temperature testing. Section 6 details some additional work that was funded on silicon carbide (SiC) device testing for high temperature use, and Section 7 is the complete text of a report funded from this effort summarizing packaging methods and their reliability issues for use in high temperature power electronics. Components were tested to evaluate the performance characteristics of the component at different operating temperatures. The temperature of the component is determined by the ambient temperature (i.e., temperature surrounding the device) plus the

  13. High temperature skin friction measurement

    Science.gov (United States)

    Tcheng, Ping; Holmes, Harlan K.; Supplee, Frank H., Jr.

    1989-01-01

    Skin friction measurement in the NASA Langley hypersonic propulsion facility is described. The sensor configuration utilized an existing balance, modified to provide thermal isolation and an increased standoff distance. For test run times of about 20 sec and ambient-air cooling of the test section and balance, the modified balance performed satisfactorily, even when it was subjected to acoustic and structural vibration. The balance is an inertially balanced closed-loop servo system where the current to a moving-coil motor needed to restore or null the output from the position sensor is a measure of the force or skin friction tending to displace the moving element. The accuracy of the sensor is directly affected by the position sensor in the feedback loop, in this case a linear-variable differential transformer which has proven to be influenced by temperature gradients.

  14. On critical hydrogen concentration for hydrogen embrittlement of Fe3Al

    Indian Academy of Sciences (India)

    Unknown

    The critical hydrogen concentration for hydrogen embrittlement in iron aluminide, Fe3Al has been estimated (0⋅42 wppm). The estimated critical hydrogen content has been correlated to structural aspects of the decohesion mechanism of hydrogen embrittlement. Keywords. Iron aluminides; hydrogen embrittlement; critical ...

  15. High Temperature Solid State Lithium Battery Project

    Data.gov (United States)

    National Aeronautics and Space Administration — Reliable energy systems with high energy density capable of operating at high temperatures, pressures and radiation levels are needed for certain NASA missions....

  16. Lightweight, High-Temperature Radiator Panels Project

    Data.gov (United States)

    National Aeronautics and Space Administration — Lightweight, high-temperature radiators are needed for future, high-efficiency power conversion systems for Nuclear Electric Propulsion (NEP). Creare has developed...

  17. High Temperature Rechargeable Battery Development Project

    Data.gov (United States)

    National Aeronautics and Space Administration — This small business innovation research is intended to develop and proof the concept of a highly efficient, high temperature rechargeable battery for supporting...

  18. The flavoured BFSS model at high temperature

    Energy Technology Data Exchange (ETDEWEB)

    Asano, Yuhma; Filev, Veselin G. [School of Theoretical Physics, Dublin Institute for Advanced Studies,10 Burlington Road, Dublin 4 (Ireland); Kováčik, Samuel [School of Theoretical Physics, Dublin Institute for Advanced Studies,10 Burlington Road, Dublin 4 (Ireland); Faculty of Mathematics, Physics and Informatics,Comenius University Bratislava, Mlynská dolina, Bratislava, 842 48 (Slovakia); O’Connor, Denjoe [School of Theoretical Physics, Dublin Institute for Advanced Studies,10 Burlington Road, Dublin 4 (Ireland)

    2017-01-25

    We study the high-temperature series expansion of the Berkooz-Douglas matrix model, which describes the D0/D4-brane system. At high temperature the model is weakly coupled and we develop the series to second order. We check our results against the high-temperature regime of the bosonic model (without fermions) and find excellent agreement. We track the temperature dependence of the bosonic model and find backreaction of the fundamental fields lifts the zero-temperature adjoint mass degeneracy. In the low-temperature phase the system is well described by a gaussian model with three masses m{sub A}{sup t}=1.964±0.003, m{sub A}{sup l}=2.001±0.003 and m{sub f}=1.463±0.001, the adjoint longitudinal and transverse masses and the mass of the fundamental fields respectively.

  19. Dissolution of alpha-prime precipitates in thermally embrittled S2205-duplex steels during reversion-heat treatment

    Directory of Open Access Journals (Sweden)

    V. Shamanth

    2015-01-01

    Full Text Available Duplex stainless steels offer an attractive combination of strength, corrosion resistance and cost. In annealed condition duplex steels will be in thermodynamically metastable condition but when they are subjected to intermediate homologous temperature of ∼475 °C and below significant embrittlement occurs, which is one of the key material degradation properties that limits its upper service temperature in many applications. Hence the present study is aimed to study the effect of reversion heat treatment and its time on mechanical properties of the thermally embrittled steel. The results showed that 60 min reversion heat treated samples were able to recover the mechanical properties which were very close to annealed properties because when the embrittled samples were reversion heat treated at an elevated temperature of 550 °C which is above the (α + α′ miscibility gap, the ferritic phase was homogenized again. In other words, Fe-rich α and Cr-rich α′ prime precipitates which were formed during ageing become thermodynamically unstable and dissolve inside the ferritic phase.

  20. Application of High Temperature Superconductors to Accelerators

    CERN Document Server

    Ballarino, A

    2000-01-01

    Since the discovery of high temperature superconductivity, a large effort has been made by the scientific community to investigate this field towards a possible application of the new oxide superconductors to different devices like SMES, magnetic bearings, flywheels energy storage, magnetic shielding, transmission cables, fault current limiters, etc. However, all present day large scale applications using superconductivity in accelerator technology are based on conventional materials operating at liquid helium temperatures. Poor mechanical properties, low critical current density and sensitivity to the magnetic field at high temperature are the key parameters whose improvement is essential for a large scale application of high temperature superconductors to such devices. Current leads, used for transferring currents from the power converters, working at room temperature, into the liquid helium environment, where the magnets are operating, represent an immediate application of the emerging technology of high t...

  1. Effect of heat treatments on the hydrogen embrittlement ...

    Indian Academy of Sciences (India)

    Unknown

    Abstract. Delayed failure tests were carried out on hydrogen charged API X-65 grade line-pipe steel in as received (controlled rolled), normalized, and quenched and tempered conditions. The resistance to hydrogen embrittlement was found in the order of controlled rolled > quenched and tempered > normalized. The frac-.

  2. Embrittlement and decrease of apparent strength in large-sized ...

    Indian Academy of Sciences (India)

    http://www.ias.ac.in/article/fulltext/sadh/027/04/0425-0448. Keywords. Concrete structures; size-effects; fractal geometry. Abstract. The problem of scale-effects on the performances of concrete structures is discussed. Experimentally observed decrease of nominal tensile strength, accompanied by structural embrittlement, ...

  3. TR-EDB: Test Reactor Embrittlement Data Base, Version 1

    Energy Technology Data Exchange (ETDEWEB)

    Stallmann, F.W.; Wang, J.A.; Kam, F.B.K. [Oak Ridge National Lab., TN (United States)

    1994-01-01

    The Test Reactor Embrittlement Data Base (TR-EDB) is a collection of results from irradiation in materials test reactors. It complements the Power Reactor Embrittlement Data Base (PR-EDB), whose data are restricted to the results from the analysis of surveillance capsules in commercial power reactors. The rationale behind their restriction was the assumption that the results of test reactor experiments may not be applicable to power reactors and could, therefore, be challenged if such data were included. For this very reason the embrittlement predictions in the Reg. Guide 1.99, Rev. 2, were based exclusively on power reactor data. However, test reactor experiments are able to cover a much wider range of materials and irradiation conditions that are needed to explore more fully a variety of models for the prediction of irradiation embrittlement. These data are also needed for the study of effects of annealing for life extension of reactor pressure vessels that are difficult to obtain from surveillance capsule results.

  4. Dynamic Model of High Temperature PEM Fuel Cell Stack Temperature

    DEFF Research Database (Denmark)

    Andreasen, Søren Juhl; Kær, Søren Knudsen

    2007-01-01

    The present work involves the development of a model for predicting the dynamic temperature of a high temperature PEM (HTPEM) fuel cell stack. The model is developed to test different thermal control strategies before implementing them in the actual system. The test system consists of a prototype...... cathode air cooled 30 cell HTPEM fuel cell stack developed at the Institute of Energy Technology at Aalborg University. This fuel cell stack uses PEMEAS Celtec P-1000 membranes, runs on pure hydrogen in a dead end anode configuration with a purge valve. The cooling of the stack is managed by running...... the stack at a high stoichiometric air flow. This is possible because of the PBI fuel cell membranes used, and the very low pressure drop in the stack. The model consists of a discrete thermal model dividing the stack into three parts: inlet, middle and end and predicting the temperatures in these three...

  5. High-temperature heat-pump fluids

    Science.gov (United States)

    Bertinat, M. P.

    1988-05-01

    Heat pumps could be immensely useful in many industrial processes, but standard working fluids are unsuitable for the high temperatures involved. The ideal high-temperature heat-pump fluid should have a high (but not too high) critical temperature, a moderate critical pressure ( approximately=5.0 MPa) and a low (but not too low) boiling point. There are many organic fluids that do meet the above thermodynamic criteria The author's list of 250 contained dozens of them including many of the common laboratory solvents such as ethanol, ether and especially acetone. Unfortunately most of them are highly flammable. The ideal work fluid for high-temperature heat pumps will probably always remain elusive and water, despite its drawbacks will continue to be the best choice in most applications

  6. Sandia_HighTemperatureComponentEvaluation_2015

    Energy Technology Data Exchange (ETDEWEB)

    Cashion, Avery T. [Sandia National Lab. (SNL-NM), Albuquerque, NM (United States)

    2015-03-01

    The objective of this project is to perform independent evaluation of high temperature components to determine their suitability for use in high temperature geothermal tools. Development of high temperature components has been increasing rapidly due to demand from the high temperature oil and gas exploration and aerospace industries. Many of these new components are at the late prototype or first production stage of development and could benefit from third party evaluation of functionality and lifetime at elevated temperatures. In addition to independent testing of new components, this project recognizes that there is a paucity of commercial-off-the-shelf COTS components rated for geothermal temperatures. As such, high-temperature circuit designers often must dedicate considerable time and resources to determine if a component exists that they may be able to knead performance out of to meet their requirements. This project aids tool developers by characterization of select COTS component performances beyond published temperature specifications. The process for selecting components includes public announcements of project intent (e.g., FedBizOps), direct discussions with candidate manufacturers,and coordination with other DOE funded programs.

  7. Aeronautical applications of high-temperature superconductors

    Science.gov (United States)

    Turney, George E.; Luidens, Roger W.; Uherka, Kenneth; Hull, John

    1989-01-01

    The successful development of high-temperature superconductors (HTS) could have a major impact on future aeronautical propulsion and aeronautical flight vehicle systems. A preliminary examination of the potential application of HTS for aeronautics indicates that significant benefits may be realized through the development and implementation of these newly discovered materials. Applications of high-temperature superconductors (currently substantiated at 95 k) were envisioned for several classes of aeronautical systems, including subsonic and supersonic transports, hypersonic aircraft, V/STOL aircraft, rotorcraft, and solar, microwave and laser powered aircraft. Introduced and described are the particular applications and potential benefits of high-temperature superconductors as related to aeronautics and/or aeronautical systems.

  8. Symposium on high temperature and materials chemistry

    Energy Technology Data Exchange (ETDEWEB)

    1989-10-01

    This volume contains the written proceedings of the Symposium on High Temperature and Materials Chemistry held in Berkeley, California on October 24--25, 1989. The Symposium was sponsored by the Materials and Chemical Sciences Division of Lawrence Berkeley Laboratory and by the College of Chemistry of the University of California at Berkeley to discuss directions, trends, and accomplishments in the field of high temperature and materials chemistry. Its purpose was to provide a snapshot of high temperature and materials chemistry and, in so doing, to define status and directions.

  9. Silicon Carbide Nanotube Oxidation at High Temperatures

    Science.gov (United States)

    Ahlborg, Nadia; Zhu, Dongming

    2012-01-01

    Silicon Carbide Nanotubes (SiCNTs) have high mechanical strength and also have many potential functional applications. In this study, SiCNTs were investigated for use in strengthening high temperature silicate and oxide materials for high performance ceramic nanocomposites and environmental barrier coating bond coats. The high · temperature oxidation behavior of the nanotubes was of particular interest. The SiCNTs were synthesized by a direct reactive conversion process of multiwall carbon nanotubes and silicon at high temperature. Thermogravimetric analysis (TGA) was used to study the oxidation kinetics of SiCNTs at temperatures ranging from 800degC to1300degC. The specific oxidation mechanisms were also investigated.

  10. High temperature spectral gamma well logging

    Energy Technology Data Exchange (ETDEWEB)

    Normann, R.A.; Henfling, J.A.

    1997-01-01

    A high temperature spectral gamma tool has been designed and built for use in small-diameter geothermal exploration wells. Several engineering judgments are discussed regarding operating parameters, well model selection, and signal processing. An actual well log at elevated temperatures is given with spectral gamma reading showing repeatability.

  11. The complexity of the tempered martensite embrittlement mechanism; A complexidade do mecanismo de fragilizacao da martensita revenida

    Energy Technology Data Exchange (ETDEWEB)

    Tokimatsu, R.C. [UNESP, SP (Brazil). DEM; Ferreira, I. [Universidade Estadual de Campinas, SP (Brazil). Faculdade de Engenharia Mecanica

    1995-12-31

    Although the general characteristics of the tempered embrittlement (TME) are known for several decades, the mechanism that causes the embrittlement are no entirely understood. Various trial models exist for providing a convinced explanation of the TME phenomenon. This paper studied the TME for a 300 M steel. Heat treatments have been characterized for different austenitizing (1143 K and 1373 K), and tempering (473 K, 630 K, 703 K and 823 K) temperatures. Different tests have been conducted for evaluation of the steel mechanical behaviour. Results suggested that various phenomena contributed for the TME occurrence which allows to conclude that the TME mechanism, for the 300 M steel, presents great complexity. Due to this complexity, there is the possibility that the TME mechanism can not be attributed to only one factor either carbide precipitation, retained austenite transformation, or impurities segregation. In these steels, it is almost right that the phenomenon is a result of factors interaction 60 refs., 4 figs., 2 tabs.

  12. STRUCTURAL INTERACTIONS OF HYDROGEN WITH BULK AMORPHOUS MICROSTRUCTURES IN METALLIC SYSTEMS UNDERSTANDING THE ROLE OF PARTIAL CRYSTALLINITY ON PERMEATION AND EMBRITTLEMENT

    Energy Technology Data Exchange (ETDEWEB)

    Brinkman, Kyle; Fox, Elise; Korinko, Paul; Adams, Thad

    2010-05-10

    The development of metallic glasses in bulk form has led to a resurgence of interest into the utilization of these materials for a variety of applications. A potentially exciting application for these bulk metallic glass (BMG) materials is their use as composite membranes to replace high cost Pd/Pd-alloy membranes for enhanced gas separation processes. One of the major drawbacks to the industrial use of Pd/Pd-alloy membranes is that during cycling above and below a critical temperature an irreversible change takes place in the palladium lattice structure which can result in significant damage to the membrane. Furthermore, the cost associated with Pd-based membranes is a potential detractor for their continued use and BMG alloys offer a potentially attractive alternative. Several BMG alloys have been shown to possess high permeation rates, comparable to those measured for pure Pd metal. In addition, high strength and toughness when either in-situ or ex-situ second phase dispersoids are present. Both of these properties, high permeation and high strength/toughness, potentially make these materials attractive for gas separation membranes that could resist hydrogen 'embrittlement'. However, a fundamental understanding of the relationship between partially crystalline 'structure'/devitrification and permeation/embrittlement in these BMG materials is required in order to determine the operating window for separation membranes and provide additional input to the material synthesis community for improved alloy design. This project aims to fill the knowledge gap regarding the impact of crystallization on the permeation properties of metallic glass materials. The objectives of this study are to (i) determine the crystallization behavior in different gas environments of Fe and Zr based commercially available bulk metallic glass and (ii) quantify the effects of partial crystallinity on the hydrogen permeation properties of these metallic glass membranes.

  13. Novel High Temperature Strain Gauge Project

    Data.gov (United States)

    National Aeronautics and Space Administration — Advanced high-temperature sensor technology and bonding methods are of great interests in designing and developing advanced future aircraft. Current state-of-the-art...

  14. High Temperature Fiberoptic Thermal Imaging System Project

    Data.gov (United States)

    National Aeronautics and Space Administration — The proposed Phase 1 program will fabricate and demonstrate a small diameter single fiber endoscope that can perform high temperature thermal imaging in a jet engine...

  15. High Temperature Capacitors for Venus Exploration Project

    Data.gov (United States)

    National Aeronautics and Space Administration — High temperature power electronics have become a vital aspect of future designs for power converters in spacecraft, battle zone electric power, satellite power...

  16. Ion Based High-Temperature Pressure Sensor

    National Research Council Canada - National Science Library

    Zdenek, Jeffrey S; Anthenien, Ralph A

    2004-01-01

    .... The environment encountered in such engines necessitates high temperature and durable (vibration resistant) devices. Traditional pressure sensors can be used, however thermal insulating materials must be used to protect the diaphragm...

  17. NASA High Operating Temperature Technology Program Overview

    Science.gov (United States)

    Nguyen, Q. V.; Hunter, G. W.

    2017-11-01

    NASA’s Planetary Science Division has begun the High Operating Temperature Technology (HOTTech) program to address Venus surface technology challenges by investing in new technology development. This presentation reviews this HOTTech program.

  18. Panel report on high temperature ceramics

    Energy Technology Data Exchange (ETDEWEB)

    Nolet, T C [ed.

    1979-01-01

    Fundamental research is reported concerning high temperature ceramics for application in turbines, engines, batteries, gasifiers, MHD, fuel cells, heat exchangers, and hot wall combustors. Ceramics microstructure and behavior are included. (FS)

  19. Mechanical Proprieties of Steel at High Temperatures

    Directory of Open Access Journals (Sweden)

    Ana-Diana Ancaş

    2005-01-01

    Full Text Available The experimental test results obtained in the study of steel mechanical proprieties variation in case of high temperatures (fire are presented. The proprieties are referring to: Young’s modulus, E, the elastic limit, σe, and the characteristic diagram of the material (the rotation stress-strain. Theoretical laws that the model the steel behaviour at high temperature have been elaborated based on the most significant studies presented in the literature.

  20. High temperature superconductors and other superfluids

    CERN Document Server

    Alexandrov, A S

    2017-01-01

    Written by eminent researchers in the field, this text describes the theory of superconductivity and superfluidity starting from liquid helium and a charged Bose-gas. It also discusses the modern bipolaron theory of strongly coupled superconductors, which explains the basic physical properties of high-temperature superconductors. This book will be of interest to fourth year graduate and postgraduate students, specialist libraries, information centres and chemists working in high-temperature superconductivity.

  1. Laser Plasma Coupling for High Temperature Hohlraums

    Energy Technology Data Exchange (ETDEWEB)

    Kruer, W.

    1999-11-04

    Simple scaling models indicate that quite high radiation temperatures can be achieved in hohlraums driven with the National Ignition Facility. A scaling estimate for the radiation temperature versus pulse duration for different size NIF hohlraums is shown in Figure 1. Note that a radiation temperature of about 650 ev is projected for a so-called scale 1 hohlraum (length 2.6mm, diameter 1.6mm). With such high temperature hohlraums, for example, opacity experiments could be carried out using more relevant high Z materials rather than low Z surrogates. These projections of high temperature hohlraums are uncertain, since the scaling model does not allow for the very strongly-driven laser plasma coupling physics. Lasnex calculations have been carried out to estimate the plasma and irradiation conditions in a scale 1 hohlraum driven by NIF. Linear instability gains as high as exp(100) have been found for stimulated Brillouin scattering, and other laser-driven instabilities are also far above their thresholds. More understanding of the very strongly-driven coupling physics is clearly needed in order to more realistically assess and improve the prospects for high temperature hohlraums. Not surprisingly, this regime has been avoided for inertial fusion applications and so is relatively unexplored.

  2. Electrons and Phonons in High Temperature Superconductors

    Directory of Open Access Journals (Sweden)

    Anu Singh

    2013-01-01

    Full Text Available The defect-induced anharmonic phonon-electron problem in high-temperature superconductors has been investigated with the help of double time thermodynamic electron and phonon Green’s function theory using a comprehensive Hamiltonian which includes the contribution due to unperturbed electrons and phonons, anharmonic phonons, impurities, and interactions of electrons and phonons. This formulation enables one to resolve the problem of electronic heat transport and equilibrium phenomenon in high-temperature superconductors in an amicable way. The problem of electronic heat capacity and electron-phonon problem has been taken up with special reference to the anharmonicity, defect concentration electron-phonon coupling, and temperature dependence.

  3. Melt processed high-temperature superconductors

    CERN Document Server

    1993-01-01

    The achievement of large critical currents is critical to the applications of high-temperature superconductors. Recent developments have shown that melt processing is suitable for producing high J c oxide superconductors. Using magnetic forces between such high J c oxide superconductors and magnets, a person could be levitated.This book has grown largely out of research works on melt processing of high-temperature superconductors conducted at ISTEC Superconductivity Research Laboratory. The chapters build on melt processing, microstructural characterization, fundamentals of flux pinning, criti

  4. Neutron experiments on high-temperature superconductors

    Science.gov (United States)

    Mook, H. A., Jr.

    1989-12-01

    This report details the trip to the ILL to perform neutron scattering research on high-temperature superconductivity. The trip was very successful because of the excellent users' facilities available at the ILL. The data we accumulated were of high quality and will make an impact on our understanding of high-temperature superconductivity. However, we cannot continue to run a research program in this field with the limited beam time available at the ILL. To make substantial progress in this field, we must restart the High Flux Isotope Reactor.

  5. High Temperature, Wireless Seismometer Sensor for Venus

    Science.gov (United States)

    Ponchak, George E.; Scardelletti, Maximilian C.; Taylor, Brandt; Beard, Steve; Meredith, Roger D.; Beheim, Glenn M.; Hunter Gary W.; Kiefer, Walter S.

    2012-01-01

    Space agency mission plans state the need to measure the seismic activity on Venus. Because of the high temperature on Venus (462? C average surface temperature) and the difficulty in placing and wiring multiple sensors using robots, a high temperature, wireless sensor using a wide bandgap semiconductor is an attractive option. This paper presents the description and proof of concept measurements of a high temperature, wireless seismometer sensor for Venus. A variation in inductance of a coil caused by the movement of an aluminum probe held in the coil and attached to a balanced leaf-spring seismometer causes a variation of 700 Hz in the transmitted signal from the oscillator/sensor system at 426? C. This result indicates that the concept may be used on Venus.

  6. High-temperature granulites and supercontinents

    Directory of Open Access Journals (Sweden)

    J.L.R. Touret

    2016-01-01

    Full Text Available The formation of continents involves a combination of magmatic and metamorphic processes. These processes become indistinguishable at the crust-mantle interface, where the pressure-temperature (P-T conditions of (ultra high-temperature granulites and magmatic rocks are similar. Continents grow laterally, by magmatic activity above oceanic subduction zones (high-pressure metamorphic setting, and vertically by accumulation of mantle-derived magmas at the base of the crust (high-temperature metamorphic setting. Both events are separated from each other in time; the vertical accretion postdating lateral growth by several tens of millions of years. Fluid inclusion data indicate that during the high-temperature metamorphic episode the granulite lower crust is invaded by large amounts of low H2O-activity fluids including high-density CO2 and concentrated saline solutions (brines. These fluids are expelled from the lower crust to higher crustal levels at the end of the high-grade metamorphic event. The final amalgamation of supercontinents corresponds to episodes of ultra-high temperature metamorphism involving large-scale accumulation of these low-water activity fluids in the lower crust. This accumulation causes tectonic instability, which together with the heat input from the sub-continental lithospheric mantle, leads to the disruption of supercontinents. Thus, the fragmentation of a supercontinent is already programmed at the time of its amalgamation.

  7. HIGH TEMPERATURE HIGH PRESSURE THERMODYNAMIC MEASUREMENTS FOR COAL MODEL COMPOUNDS

    Energy Technology Data Exchange (ETDEWEB)

    Vinayak N. Kabadi

    1999-02-20

    It is well known that the fluid phase equilibria can be represented by a number of {gamma}-models , but unfortunately most of them do not function well under high temperature. In this calculation, we mainly investigate the performance of UNIQUAC and NRTL models under high temperature, using temperature dependent parameters rather than using the original formulas. the other feature of this calculation is that we try to relate the excess Gibbs energy G{sup E}and enthalpy of mixing H{sup E}simultaneously. In other words, we will use the high temperature and pressure G{sup E} and H{sup E}data to regress the temperature dependant parameters to find out which model and what kind of temperature dependant parameters should be used.

  8. Low Temperature Heating and High Temperature Cooling in Buildings

    DEFF Research Database (Denmark)

    Kazanci, Ongun Berk

    , a single-family house designed for plus-energy targets and equipped with a radiant water-based floor heating and cooling system was studied by means of full-scale measurements, dynamic building simulations and thermodynamic evaluation tools. Thermal indoor environment and energy performance of the house......A heating and cooling system could be divided into three parts: terminal units (emission system), distribution system, and heating and cooling plant (generation system). The choice of terminal unit directly affects the energy performance, and the indoor environment in that space. Therefore......, a holistic system evaluation is necessary to ensure an optimal indoor environment for the occupants and to achieve energy efficiency simultaneously. Low temperature heating and high temperature cooling systems are one of the possible approaches to heat or cool indoor spaces in buildings. In this thesis...

  9. Change in the microstructure and mechanical properties of drawn pearlitic steel with low-temperature aging

    Science.gov (United States)

    Hirakami, D.; Ushioda, K.; Manabe, T.; Noguchi, K.; Takai, K.; Hata, Y.; Hata, S.; Nakashima, H.

    2017-07-01

    Hydrogen embrittlement is a serious problem in high-strength steels. Drawn pearlitic steel shows excellent resistance to hydrogen embrittlement despite its high strength, and aging treatment at a low temperature can simultaneously improve its strength and hydrogen-embrittlement resistance. To clarify the mechanism for this we have used thermal desorption analysis (TDA) and the newly developed precession electron diffraction analysis method in the transmission electron microscope. After aging at 100 °C for 10 min, the amount of hydrogen seen amount on the TDA curve reduced at around 100 °C. In contrast, when aging was performed at 300 °C, the hydrogen amount further reduced at around 100 °C and the unevenly deformed lamellar ferrite zone was locally recovered. For the samples that were aged at the low temperature, we confirmed that their yield strength and relaxation stress ratios increased simultaneously with improvement in the hydrogen-embrittlement property. We infer that segregation of carbon or formation of very fine carbide in dislocations during aging is the cause of these behaviors.

  10. Methodology for Estimating Thermal and Neutron Embrittlement of Cast Austenitic Stainless Steels During Service in Light Water Reactors

    Energy Technology Data Exchange (ETDEWEB)

    Chopra, O. K.; Rao, A. S.

    2016-04-28

    Cast austenitic stainless steel (CASS) materials, which have a duplex structure consisting of austenite and ferrite phases, are susceptible to thermal embrittlement during reactor service. In addition, the prolonged exposure of these materials, which are used in reactor core internals, to neutron irradiation changes their microstructure and microchemistry, and these changes degrade their fracture properties even further. This paper presents a revision of the procedure and correlations presented in NUREG/CR-4513, Rev. 1 (Aug. 1994) for predicting the change in fracture toughness and tensile properties of CASS components due to thermal aging during service in light water reactors (LWRs) at 280–330 °C (535–625 °F). The methodology is applicable to CF-3, CF-3M, CF-8, and CF-8M materials with a ferrite content of up to 40%. The fracture toughness, tensile strength, and Charpy-impact energy of aged CASS materials are estimated from known material information. Embrittlement is characterized in terms of room-temperature (RT) Charpy-impact energy. The extent or degree of thermal embrittlement at “saturation” (i.e., the minimum impact energy that can be achieved for a material after long-term aging) is determined from the chemical composition of the material. Charpy-impact energy as a function of the time and temperature of reactor service is estimated from the kinetics of thermal embrittlement, which are also determined from the chemical composition. The fracture toughness J-R curve for the aged material is then obtained by correlating RT Charpy-impact energy with fracture toughness parameters. A common “predicted lower-bound” J-R curve for CASS materials of unknown chemical composition is also defined for a given grade of material, range of ferrite content, and temperature. In addition, guidance is provided for evaluating the combined effects of thermal and neutron embrittlement of CASS materials used in the reactor core internal components. The correlations

  11. High temperature thrust chamber for spacecraft

    Science.gov (United States)

    Chazen, Melvin L. (Inventor); Mueller, Thomas J. (Inventor); Kruse, William D. (Inventor)

    1998-01-01

    A high temperature thrust chamber for spacecraft (20) is provided herein. The high temperature thrust chamber comprises a hollow body member (12) having an outer surface and an internal surface (16) defining the high temperature chamber (10). The body member (12) is made substantially of rhenium. An alloy (18) consisting of iridium and at least alloying metal selected of the group consisting of rhodium, platinum and palladium is deposited on at least a portion of the internal surface (16) of the body member (12). The iridium and the alloying metal are electrodeposited onto the body member (12). A HIP cycle is performed upon the body member (12) to cause the coating of iridium and the alloying metal to form the alloy (18) which protects the body member (12) from oxidation.

  12. Stability projections for high temperature superconductors

    Energy Technology Data Exchange (ETDEWEB)

    Laquer, H.L.; Edeskuty, F.J.; Hassenzahl, W.V.; Wipf, S.L.

    1989-03-01

    The stability of the new high temperature superconducting oxides has been analyzed, using the methodology developed over the last 25 years for conventional Type II superconductors. The results are presented in graphical form for the temperature range from 4 to 100 K. For a 90 K superconductor the first flux jump field peaks above 7 T at 60 K, ( and for a 120 k superconductor it peaks above 12 T at 75 K). The maximum adiabatically stable thickness increases dramatically. The linear dimension of the minimum propagating zone increases by a factor of 3 to 5, and the quench propagation velocity drops by 4 orders of magnitude. The high temperature superconducting materials will, therefore, have much higher stability than conventional Type II superconductors; their high flux jump fields will make ultra-fine multifilamentary conductors unnecessary and improve the outlook for tape conductors; the energy to create a propagating zone is increased; however, methods of coil protection will have to be modified.

  13. High temperature superconductivity the road to higher critical temperature

    CERN Document Server

    Uchida, Shin-ichi

    2015-01-01

    This book presents an overview of material-specific factors that influence Tc and give rise to diverse Tc values for copper oxides and iron-based high- Tc superconductors on the basis of more than 25 years of experimental data, to most of which the author has made important contributions. The book then explains why both compounds are distinct from others with similar crystal structure and whether or not one can enhance Tc, which in turn gives a hint on the unresolved pairing mechanism. This is an unprecedented new approach to the problem of high-temperature superconductivity and thus will be inspiring to both specialists and non-specialists interested in this field.   Readers will receive in-depth information on the past, present, and future of high-temperature superconductors, along with special, updated information on what the real highest Tc values are and particularly on the possibility of enhancing Tc for each member material, which is important for application. At this time, the highest Tc has not been...

  14. Computer Simulation of Intergranular Stress Corrosion Cracking via Hydrogen Embrittlement

    Energy Technology Data Exchange (ETDEWEB)

    Smith, R.W.

    2000-04-01

    Computer simulation has been applied to the investigation of intergranular stress corrosion cracking in Ni-based alloys based on a hydrogen embrittlement mechanism. The simulation employs computational modules that address (a) transport and reactions of aqueous species giving rise to hydrogen generation at the liquid-metal interface, (b) solid state transport of hydrogen via intergranular and transgranular diffusion pathways, and (c) fracture due to the embrittlement of metallic bonds by hydrogen. A key focus of the computational model development has been the role of materials microstructure (precipitate particles and grain boundaries) on hydrogen transport and embrittlement. Simulation results reveal that intergranular fracture is enhanced as grain boundaries are weakened and that microstructures with grains elongated perpendicular to the stress axis are more susceptible to cracking. The presence of intergranular precipitates may be expected to either enhance or impede cracking depending on the relative distribution of hydrogen between the grain boundaries and the precipitate-matrix interfaces. Calculations of hydrogen outgassing and in gassing demonstrate a strong effect of charging method on the fracture behavior.

  15. Temperature measurements of high power LEDs

    Science.gov (United States)

    Badalan (Draghici), Niculina; Svasta, Paul; Drumea, Andrei

    2016-12-01

    Measurement of a LED junction temperature is very important in designing a LED lighting system. Depending on the junction temperature we will be able to determine the type of cooling system and the size of the lighting system. There are several indirect methods for junction temperature measurement. The method used in this paper is based on the thermal resistance model. The aim of this study is to identify the best device that would allow measuring the solder point temperature and the temperature on the lens of power LEDs. For this purpose four devices for measuring temperature on a high-power LED are presented and compared according to the acquired measurements: an infrared thermal camera from FLIR Systems, a multimeter with K type thermocouple (Velleman DVM4200), an infrared-spot based noncontact thermometer (Raynger ST) and a measurement system based on a digital temperature sensor (DS1821 type) connected to a PC. The measurements were conducted on an 18W COB (chip-on-board) LED. The measurement points are the supply terminals and the lens of the LED.

  16. Fiber Bragg Grating Filter High Temperature Sensors

    Science.gov (United States)

    Lyons, Donald R.; Brass, Eric D.; Pencil, Eric (Technical Monitor)

    2001-01-01

    We present a scaled-down method for determining high temperatures using fiber-based Bragg gratings. Bragg gratings are distributed along the length of the optical fiber, and have high reflectivities whenever the optical wavelength is twice the grating spacing. These spatially distinct Bragg regions (located in the core of a fiber) are sensitive to local temperature changes. Since these fibers are silica-based they are easily affected by localized changes in temperature, which results in changes to both the grating spacing and the wavelength reflectivity. We exploit the shift in wavelength reflectivity to measure the change in the local temperature. Note that the Bragg region (sensing area) is some distance away from where the temperature is being measured. This is done so that we can measure temperatures that are much higher than the damage threshold of the fiber. We do this by affixing the fiber with the Bragg sensor to a material with a well-known coefficient of thermal expansion, and model the heat gradient from the region of interest to the actual sensor. The research described in this paper will culminate in a working device as well as be the second portion of a publication pending submission to Optics Letters.

  17. Materials for high-temperature fuel cells

    CERN Document Server

    Jiang, San Ping; Lu, Max

    2013-01-01

    There are a large number of books available on fuel cells; however, the majority are on specific types of fuel cells such as solid oxide fuel cells, proton exchange membrane fuel cells, or on specific technical aspects of fuel cells, e.g., the system or stack engineering. Thus, there is a need for a book focused on materials requirements in fuel cells. Key Materials in High-Temperature Fuel Cells is a concise source of the most important and key materials and catalysts in high-temperature fuel cells with emphasis on the most important solid oxide fuel cells. A related book will cover key mater

  18. High temperature and pressure electrochemical test station

    DEFF Research Database (Denmark)

    Chatzichristodoulou, Christodoulos; Allebrod, Frank; Mogensen, Mogens Bjerg

    2013-01-01

    An electrochemical test station capable of operating at pressures up to 100 bars and temperatures up to 400 ◦C has been established. It enables control of the partial pressures and mass flow of O2, N2, H2, CO2, and H2O in a single or dual environment arrangement, measurements with highly corrosive......, to the electrochemical characterization of high temperature and pressure alkaline electrolysis cells and the use of pseudo-reference electrodes for the separation of each electrode contribution. A future perspective of various electrochemical processes and devices that can be developed with the use of the established...

  19. High temperature reactors for cogeneration applications

    Energy Technology Data Exchange (ETDEWEB)

    Verfondern, Karl [Forschungszentrum Juelich (Germany). IEK-6; Allelein, Hans-Josef [Forschungszentrum Juelich (Germany). IEK-6; RWTH Aachen (Germany). Lehrstuhl fuer Reaktorsicherheit und -technik (LRST)

    2016-05-15

    There is a large potential for nuclear energy also in the non-electric heat market. Many industrial sectors have a high demand for process heat and steam at various levels of temperature and pressure to be provided for desalination of seawater, district heating, or chemical processes. The future generation of nuclear plants will be capable to enter the wide field of cogeneration of heat and power (CHP), to reduce waste heat and to increase efficiency. This requires an adjustment to multiple needs of the customers in terms of size and application. All Generation-IV concepts proposed are designed for coolant outlet temperatures above 500 C, which allow applications in the low and medium temperature range. A VHTR would even be able to cover the whole temperature range up to approx. 1 000 C.

  20. On-wafer high temperature characterization system

    Science.gov (United States)

    Teodorescu, L.; ǎghici, F., Dr; Rusu, I.; Brezeanu, G.

    2016-12-01

    In this work a on-wafer high temperature characterization system for wide bandgap semiconductor devices and circuits has been designed, implemented and tested. The proposed system can perform the wafer temperature adjustment in a large domain, from the room temperature up to 3000C with a resolution better than +/-0.50C. In order to obtain both low-noise measurements and low EMI, the heating element of the wafer chuck is supplied in two ways: one is from a DC linear power supply connected to the mains electricity, another one is from a second DC unit powered by batteries. An original temperature control algorithm, different from classical PID, is used to modify the power applied to the chuck.

  1. High Temperature Mechanisms for Venus Exploration

    Science.gov (United States)

    Ji, Jerri; Narine, Roop; Kumar, Nishant; Singh, Sase; Gorevan, Steven

    Future Venus missions, including New Frontiers Venus In-Situ Explorer and three Flagship Missions - Venus Geophysical Network, Venus Mobile Explorer and Venus Surface Sample Return all focus on searching for evidence of past climate change both on the surface and in the atmospheric composition as well as in the interior dynamics of the planet. In order to achieve these goals and objectives, many key technologies need to be developed for the Venus extreme environment. These key technologies include sample acquisition systems and other high-temperature mechanisms and mobility systems capable of extended operation when directly exposed to the Venus surface or lower atmosphere environment. Honeybee Robotics has developed two types of high temperature motors, the materials and components in both motors were selected based on the requirement to survive temperatures above a minimum of 460° C, at earth atmosphere. The prototype Switched Reluctance Motor (SRM) has been operated non-continuously for over 20 hours at Venus-like conditions (460° C temperature, mostly CO2 gas environment) and it remains functional. A drilling system, actuated by two SRMs was tested in Venus-like conditions, 460° C temperature and mostly CO2 gas environment, for more than 15 hours. The drill successfully completed three tests by drilling into chalk up to 6 inches deep in each test. A first generation Brushless DC (BLDC) Motor and high temperature resolver were also tested and the feasibility of the designs was demonstrated by the extended operation of both devices under Venus-like condition. Further development of the BLDC motor and resolver continues and these devices will, ultimately, be integrated into the development of a high temperature sample acquisition scoop and high temperature joint (awarded SBIR Phase II in October, 2007). Both the SR and BLDC motors will undergo extensive testing at Venus temperature and pressure (TRL6) and are expected to be mission ready before the next New

  2. High-Temperature Shape Memory Polymers

    Science.gov (United States)

    Yoonessi, Mitra; Weiss, Robert A.

    2012-01-01

    physical conformation changes when exposed to an external stimulus, such as a change in temperature. Such materials have a permanent shape, but can be reshaped above a critical temperature and fixed into a temporary shape when cooled under stress to below the critical temperature. When reheated above the critical temperature (Tc, also sometimes called the triggering or switching temperature), the materials revert to the permanent shape. The current innovation involves a chemically treated (sulfonated, carboxylated, phosphonated, or other polar function group), high-temperature, semicrystalline thermoplastic poly(ether ether ketone) (Tg .140 C, Tm = 340 C) mix containing organometallic complexes (Zn++, Li+, or other metal, ammonium, or phosphonium salts), or high-temperature ionic liquids (e.g. hexafluorosilicate salt with 1-propyl-3- methyl imidazolium, Tm = 210 C) to form a network where dipolar or ionic interactions between the polymer and the low-molecular-weight or inorganic compound forms a complex that provides a physical crosslink. Hereafter, these compounds will be referred to as "additives". The polymer is semicrystalline, and the high-melt-point crystals provide a temporary crosslink that acts as a permanent crosslink just so long as the melting temperature is not exceeded. In this example case, the melting point is .340 C, and the shape memory critical temperature is between 150 and 250 C. PEEK is an engineering thermoplastic with a high Young fs modulus, nominally 3.6 GPa. An important aspect of the invention is the control of the PEEK functionalization (in this example, the sulfonation degree), and the thermal properties (i.e. melting point) of the additive, which determines the switching temperature. Because the compound is thermoplastic, it can be formed into the "permanent" shape by conventional plastics processing operations. In addition, the compound may be covalently cross - linked after forming the permanent shape by S-PEEK by applying ionizing

  3. High Summer Temperatures and Mortality in Estonia.

    Directory of Open Access Journals (Sweden)

    Daniel Oudin Åström

    Full Text Available On-going climate change is predicted to result in a growing number of extreme weather events-such as heat waves-throughout Europe. The effect of high temperatures and heat waves are already having an important impact on public health in terms of increased mortality, but studies from an Estonian setting are almost entirely missing. We investigated mortality in relation to high summer temperatures and the time course of mortality in a coastal and inland region of Estonia.We collected daily mortality data and daily maximum temperature for a coastal and an inland region of Estonia. We applied a distributed lag non-linear model to investigate heat related mortality and the time course of mortality in Estonia.We found an immediate increase in mortality associated with temperatures exceeding the 75th percentile of summer maximum temperatures, corresponding to approximately 23°C. This increase lasted for a couple of days in both regions. The total effect of elevated temperatures was not lessened by significant mortality displacement.We observed significantly increased mortality in Estonia, both on a country level as well as for a coastal region and an inland region with a more continental climate. Heat related mortality was higher in the inland region as compared to the coastal region, however, no statistically significant differences were observed. The lower risks in coastal areas could be due to lower maximum temperatures and cooling effects of the sea, but also better socioeconomic condition. Our results suggest that region specific estimates of the impacts of temperature extremes on mortality are needed.

  4. Measuring nanowire thermal conductivity at high temperatures

    Science.gov (United States)

    Wang, Xiaomeng; Yang, Juekuan; Xiong, Yucheng; Huang, Baoling; Xu, Terry T.; Li, Deyu; Xu, Dongyan

    2018-02-01

    This work extends the micro-thermal-bridge method for thermal conductivity measurements of nanowires to high temperatures. The thermal-bridge method, based on a microfabricated device with two side-by-side suspended membranes with integrated platinum resistance heaters/thermometers, has been used to determine thermal conductivity of various nanowires/nanotubes/nanoribbons at relatively low temperatures. However, to date, thermal conductivity characterization of nanowires at temperatures above 600 K has seldom been reported presumably due to several technical difficulties including the instability of the microfabricated thermometers, radiation heat loss, and the effect of the background conductance on the measurement. Here we report on our attempt to address the aforementioned challenges and demonstrate thermal conductivity measurement of boron nanoribbons up to 740 K. To eliminate high temperature resistance instability, the device is first annealed at 1023 K for 5 min in an argon atmosphere. Two radiation shields are installed in the measurement chamber to minimize radiation heat loss from the measurement device to the surroundings; and the temperature of the device at each set point is calibrated by an additional thermocouple directly mounted on the chip carrier. The effect of the background conductance is eliminated by adopting a differential measurement scheme. With all these modifications, we successfully measured the thermal conductivity of boron nanoribbons over a wide temperature range from 27 K to 740 K. The measured thermal conductivity increases monotonically with temperature and reaches a plateau of ~2.5 W m‑1 K‑1 at approximately 400 K, with no clear signature of Umklapp scattering observed in the whole measurement temperature range.

  5. High Summer Temperatures and Mortality in Estonia.

    Science.gov (United States)

    Oudin Åström, Daniel; Åström, Christofer; Rekker, Kaidi; Indermitte, Ene; Orru, Hans

    2016-01-01

    On-going climate change is predicted to result in a growing number of extreme weather events-such as heat waves-throughout Europe. The effect of high temperatures and heat waves are already having an important impact on public health in terms of increased mortality, but studies from an Estonian setting are almost entirely missing. We investigated mortality in relation to high summer temperatures and the time course of mortality in a coastal and inland region of Estonia. We collected daily mortality data and daily maximum temperature for a coastal and an inland region of Estonia. We applied a distributed lag non-linear model to investigate heat related mortality and the time course of mortality in Estonia. We found an immediate increase in mortality associated with temperatures exceeding the 75th percentile of summer maximum temperatures, corresponding to approximately 23°C. This increase lasted for a couple of days in both regions. The total effect of elevated temperatures was not lessened by significant mortality displacement. We observed significantly increased mortality in Estonia, both on a country level as well as for a coastal region and an inland region with a more continental climate. Heat related mortality was higher in the inland region as compared to the coastal region, however, no statistically significant differences were observed. The lower risks in coastal areas could be due to lower maximum temperatures and cooling effects of the sea, but also better socioeconomic condition. Our results suggest that region specific estimates of the impacts of temperature extremes on mortality are needed.

  6. Gravimeter using high-temperature superconductor bearing.

    Energy Technology Data Exchange (ETDEWEB)

    Hull, J. R.

    1998-09-11

    We have developed a sensitive gravimeter concept that uses an extremely low-friction bearing based on a permanent magnet (PM) levitated over a high-temperature superconductor (HTS). A mass is attached to the PM by means of a cantilevered beam, and the combination of PM and HTS forms a bearing platform that has low resistance to rotational motion but high resistance to horizontal, vertical, or tilting motion. The combination acts as a low-loss torsional pendulum that can be operated in any orientation. Gravity acts on the cantilevered beam and attached mass, accelerating them. Variations in gravity can be detected by time-of-flight acceleration, or by a control coil or electrode that would keep the mass stationary. Calculations suggest that the HTS gravimeter would be as sensitive as present-day superconducting gravimeters that need cooling to liquid helium temperatures, but the HTS gravimeter needs cooling only to liquid nitrogen temperatures.

  7. High Accuracy, Miniature Pressure Sensor for Very High Temperatures Project

    Data.gov (United States)

    National Aeronautics and Space Administration — SiWave proposes to develop a compact, low-cost MEMS-based pressure sensor for very high temperatures and low pressures in hypersonic wind tunnels. Most currently...

  8. Research at Very High Pressures and High Temperatures

    Science.gov (United States)

    Bundy, Francis P.

    1977-01-01

    Reviews research and apparatus utilized in the study of the states and characteristics of materials at very high temperatures and pressures. Includes three examples of the research being conducted. (SL)

  9. Lightweight High-Temperature Thermal Insulation

    Science.gov (United States)

    Wagner, W. R.; Fasheh, J. I.

    1985-01-01

    Fine Ni/Cr fibers sintered into corrosion-resistant, fireproof batt. Possible applications include stoves, furnaces, safes, fire clothing, draperies in public buildings, wall firebreaks, airplane walls, and jetengine components. New insulation takes advantage of some of same properties of nickel/chromium alloy useful in heating elements in toasters, namely, corrosion and oxidation resistance even at high temperatures.

  10. High temperatures influence sexual development differentially in ...

    Indian Academy of Sciences (India)

    Although sex determination in amphibians is believed to be a genetic process, environmental factors such as temperatureare known to influence the sex differentiation and development. Extremely low and high temperatures influence gonadaldevelopment and sex ratio in amphibians but the mechanism of action is not ...

  11. High Temperature Corrosion in Biomass Incineration Plants

    DEFF Research Database (Denmark)

    Montgomery, Melanie; Maahn, Ernst emanuel; Gotthjælp, K.

    1997-01-01

    The aim of the project is to study the role of ash deposits in high temperature corrosion of superheater materials in biomass and refuse fire combined heat and power plants. The project has included the two main activities: a) A chemical characterisation of ash deposits collected from a major...

  12. High Temperature Resistant Exhaust Valve Spindle

    DEFF Research Database (Denmark)

    Bihlet, Uffe Ditlev

    of the engine, new high temperature alloys are required for a specific engine component, the exhaust valve spindle. Two alloys are used for an exhaust valve spindle; one for the bottom of the spindle, and one for the spindle seat. Being placed in the exhaust gas stream, combustion products such as V2O5 and Na2...

  13. Helium-cooled high temperature reactors

    Energy Technology Data Exchange (ETDEWEB)

    Trauger, D.B.

    1985-01-01

    Experience with several helium cooled reactors has been favorable, and two commercial plants are now operating. Both of these units are of the High Temperature Graphite Gas Cooled concept, one in the United States and the other in the Federal Republic of Germany. The initial helium charge for a reactor of the 1000 MW(e) size is modest, approx.15,000 kg.

  14. Complex performance during exposure to high temperatures.

    Science.gov (United States)

    1969-06-01

    The effects of high temperature on psychomotor performance and physiological function were studied on male pilots (age 30-51) holding a current medical certificate. A total of 41 runs were made at neutral (23.8C (75F), or hot (60.0C (140F), 71.1C (16...

  15. Thermoelastic properties of minerals at high temperature

    Indian Academy of Sciences (India)

    The knowledge of elasticity of the minerals is useful for interpreting the structure and composition of the lower mantle and also in seismic studies. The purpose of the present study is to discuss a simple and straightforward method for evaluating thermoelastic properties of minerals at high temperatures. We have extended ...

  16. High temperature fatigue behaviour of intermetallics

    Indian Academy of Sciences (India)

    There would be considerable benefits in developing new structural materials where high use temperatures and strength coupled with low density are minimum capabilities. Nickel and titanium aluminides exhibit considerable potential for near-term application in various branches of modern industry due to the number of ...

  17. High pressure and high temperature behaviour of ZnO

    Energy Technology Data Exchange (ETDEWEB)

    Thakar, Nilesh A. [K. K. Shah Jarodwala Maninagar Science College, Rambaug, Maninagar, Ahmedabad-380008 (India); Bhatt, Apoorva D. [Department of Physics, Gujarat University, Ahmedabad-380009 (India); Pandya, Tushar C., E-mail: pandyatc@gmail.com [St. Xavier' s College, Navrangpura, Ahmedabad-380009 (India)

    2014-04-24

    The thermodynamic properties with the wurtzite (B4) and rocksalt (B1) phases of ZnO under high pressures and high temperatures have been investigated using Tait's Equation of state (EOS). The effects of pressures and temperatures on thermodynamic properties such as bulk modulus, thermal expansivity and thermal pressure are explored for both two structures. It is found that ZnO material gradually softens with increase of temperature while it hardens with the increment of the pressure. Our predicted results of thermodynamics properties for both the phases of ZnO are in overall agreement with the available data in the literature.

  18. High-pressure-high-temperature treatment of natural diamonds

    CERN Document Server

    Royen, J V

    2002-01-01

    The results are reported of high-pressure-high-temperature (HPHT) treatment experiments on natural diamonds of different origins and with different impurity contents. The diamonds are annealed in a temperature range up to 2000 sup o C at stabilizing pressures up to 7 GPa. The evolution is studied of different defects in the diamond crystal lattice. The influence of substitutional nitrogen atoms, plastic deformation and the combination of these is discussed. Diamonds are characterized at room and liquid nitrogen temperature using UV-visible spectrophotometry, Fourier transform infrared spectrophotometry and photoluminescence spectrometry. The economic implications of diamond HPHT treatments are discussed.

  19. Effects of alloy composition in alleviating embrittlement problems associated with the tantalum alloy T-111

    Science.gov (United States)

    Stephens, J. R.

    1977-01-01

    The causes of aging embrittlement in T-111 (Ta-8W-2Hf) and the effects of alloy modification were investigated. Results showed that T-111 contains a critical combination of tungsten and hafnium that leads to loss of ductility at -196 C after aging near 1040 C. This appears to occur because tungsten enhances hafnium segregation to grain boundaries and this also leads to increased susceptibility to hydrogen embrittlement. Aging embrittlement was not observed in tantalum alloys with reduced tungsten or hafnium contents; however, most of the alloys studied have lower strengths than T-111 and exhibit susceptibility to hydrogen embrittlement.

  20. High temperature superconductors applications in telecommunications

    Energy Technology Data Exchange (ETDEWEB)

    Kumar, A.A.; Li, J.; Zhang, M.F. [Prairie View A& M Univ., Texas (United States)

    1994-12-31

    The purpose of this paper is twofold: to discuss high temperature superconductors with specific reference to their employment in telecommunications applications; and to discuss a few of the limitations of the normally employed two-fluid model. While the debate on the actual usage of high temperature superconductors in the design of electronic and telecommunications devices-obvious advantages versus practical difficulties-needs to be settled in the near future, it is of great interest to investigate the parameters and the assumptions that will be employed in such designs. This paper deals with the issue of providing the microwave design engineer with performance data for such superconducting waveguides. The values of conductivity and surface resistance, which are the primary determining factors of a waveguide performance, are computed based on the two-fluid model. A comparison between two models-a theoretical one in terms of microscopic parameters (termed Model A) and an experimental fit in terms of macroscopic parameters (termed Model B)-shows the limitations and the resulting ambiguities of the two-fluid model at high frequencies and at temperatures close to the transition temperature. The validity of the two-fluid model is then discussed. Our preliminary results show that the electrical transport description in the normal and superconducting phases as they are formulated in the two-fluid model needs to be modified to incorporate the new and special features of high temperature superconductors. Parameters describing the waveguide performance-conductivity, surface resistance and attenuation constant-will be computed. Potential applications in communications networks and large scale integrated circuits will be discussed. Some of the ongoing work will be reported. In particular, a brief proposal is made to investigate of the effects of electromagnetic interference and the concomitant notion of electromagnetic compatibility (EMI/EMC) of high T{sub c} superconductors.

  1. Sorbents Remove Oxygen At High Temperatures

    Science.gov (United States)

    Sharma, Pramod K.

    1995-01-01

    Cobalt-exchanged, platinized zeolites 13X and L found conveniently reducible in hot gaseous mixture of hydrogen and nitrogen and thereafter useful as sorbents of trace amounts of oxygen at high temperatures. Aided by catalytic action of platinum, sorbents exhibit rapid oxygen-sorption kinetics and, according to thermodynamic properties of O2/CoO system, capable of lowering level of oxygen in otherwise inert gaseous atmosphere to less than 1 part per trillion in temperature range of 400 to 800 degrees C. Inert atmospheres with these oxygen levels required for processing of certain materials in semiconductor industry.

  2. A review of high-temperature adhesives

    Science.gov (United States)

    St.clair, A. K.; St.clair, T. L.

    1981-01-01

    The development of high temperature adhesives and polyphenylquinoxalines (PPQ) is reported. Thermoplastic polyimides and linear PPQ adhesive are shown to have potential for bonding both metals and composite structures. A nadic terminated addition polyimide adhesive, LARC-13, and an acetylene terminated phenylquinoxaline (ATPQ) were developed. Both of the addition type adhesives are shown to be more readily processable than linear materials but less thermooxidatively stable and more brittle. It is found that the addition type adhesives are able to perform, at elevated temperatures up to 595 C where linear systems fail thermoplastically.

  3. High temperature dynamic engine seal technology development

    Science.gov (United States)

    Steinetz, Bruce M.; Dellacorte, Christopher; Machinchick, Michael; Mutharasan, Rajakkannu; Du, Guang-Wu; Ko, Frank; Sirocky, Paul J.; Miller, Jeffrey H.

    1992-01-01

    Combined cycle ramjet/scramjet engines being designed for advanced hypersonic vehicles, including the National Aerospace Plane (NASP), require innovative high temperature dynamic seals to seal the sliding interfaces of the articulated engine panels. New seals are required that will operate hot (1200 to 2000 F), seal pressures ranging from 0 to 100 psi, remain flexible to accommodate significant sidewall distortions, and resist abrasion over the engine's operational life. This report reviews the recent high temperature durability screening assessments of a new braided rope seal concept, braided of emerging high temperature materials, that shows promise of meeting many of the seal demands of hypersonic engines. The paper presents durability data for: (1) the fundamental seal building blocks, a range of candidate ceramic fiber tows; and for (2) braided rope seal subelements scrubbed under engine simulated sliding, temperature, and preload conditions. Seal material/architecture attributes and limitations are identified through the investigations performed. The paper summarizes the current seal technology development status and presents areas in which future work will be performed.

  4. High temperature aircraft research furnace facilities

    Science.gov (United States)

    Smith, James E., Jr.; Cashon, John L.

    1992-01-01

    Focus is on the design, fabrication, and development of the High Temperature Aircraft Research Furnace Facilities (HTARFF). The HTARFF was developed to process electrically conductive materials with high melting points in a low gravity environment. The basic principle of operation is to accurately translate a high temperature arc-plasma gas front as it orbits around a cylindrical sample, thereby making it possible to precisely traverse the entire surface of a sample. The furnace utilizes the gas-tungsten-arc-welding (GTAW) process, also commonly referred to as Tungsten-Inert-Gas (TIG). The HTARFF was developed to further research efforts in the areas of directional solidification, float-zone processing, welding in a low-gravity environment, and segregation effects in metals. The furnace is intended for use aboard the NASA-JSC Reduced Gravity Program KC-135A Aircraft.

  5. High temperature sensors for exhaust diagnosis

    Energy Technology Data Exchange (ETDEWEB)

    Svenningstorp, Henrik

    2000-07-01

    One of the largest problems that we will have to deal with on this planet this millennium is to stop the pollution of our environment. In many of the ongoing works to reduce toxic emissions, gas sensors capable of enduring rough environments and high temperatures, would be a great tool. The different applications where sensors like this would be useful vary between everything from online measurement in the paper industry and food industry to measurement in the exhaust pipe of a car. In my project we have tested Schottky diodes and MlSiCFET sensor as gas sensors operating at high temperatures. The measurement condition in the exhaust pipe of a car is extremely tough, not only is the temperature high and the different gases quite harmful, there are also a lot of particles that can affect the sensors in an undesirable way. In my project we have been testing Schottky diodes and MlSiCFET sensors based on SiC as high temperature sensors, both in the laboratory with simulated exhaust and after a real engine. In this thesis we conclude that these sensors can work in the hostile environment of an engines exhaust. It is shown that when measuring in a gas mixture with a fixed I below one, where the I-value is controlled by the O{sub 2} concentration, a sensor with a catalytic gate metal as sensitive material respond more to the increased O{sub 2} concentration than the increased HC concentration when varying the two correspondingly. A number of different sensors have been tested in simulated exhaust towards NO{sub x}. It was shown that resistivity changes in the thin gate metal influenced the gas response. Tests have been performed where sensors were a part of a SCR system with promising results concerning NH{sub 3} sensitivity. With a working temperature of 300 deg C there is no contamination of the metal surface.

  6. High Temperature Polymer Electrolyte Fuel Cells

    DEFF Research Database (Denmark)

    Fleige, Michael

    This thesis presents the development and application of electrochemical half-cell setups to study the catalytic reactions taking place in High Temperature Polymer Electrolyte Fuel Cells (HTPEM-FCs): (i) a pressurized electrochemical cell with integrated magnetically coupled rotating disk electrode...... to 140 ºC and oxygen pressures up to ~100 bar at room temperature. The GDE cell is successfully tested at 130 ºC by means of direct oxidation of methanol and ethanol, respectively. In the second part of the thesis, the emphasis is put on the ORR in H3PO4 with particular focus on the mass transport...... oxidation of ethanol is in principle a promising concept to supply HTPEM-FCs with a sustainable and on large scale available fuel (ethanol from biomass). However, the intermediate temperature tests in the GDE setup show that even on Pt-based catalysts the reaction rates become first significant...

  7. High Temperature Fluoride Salt Test Loop

    Energy Technology Data Exchange (ETDEWEB)

    Aaron, Adam M. [Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States); Cunningham, Richard Burns [Univ. of Tennessee, Knoxville, TN (United States); Fugate, David L. [Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States); Holcomb, David Eugene [Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States); Kisner, Roger A. [Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States); Peretz, Fred J. [Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States); Robb, Kevin R. [Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States); Wilson, Dane F. [Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States); Yoder, Jr, Graydon L. [Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States)

    2015-12-01

    Effective high-temperature thermal energy exchange and delivery at temperatures over 600°C has the potential of significant impact by reducing both the capital and operating cost of energy conversion and transport systems. It is one of the key technologies necessary for efficient hydrogen production and could potentially enhance efficiencies of high-temperature solar systems. Today, there are no standard commercially available high-performance heat transfer fluids above 600°C. High pressures associated with water and gaseous coolants (such as helium) at elevated temperatures impose limiting design conditions for the materials in most energy systems. Liquid salts offer high-temperature capabilities at low vapor pressures, good heat transport properties, and reasonable costs and are therefore leading candidate fluids for next-generation energy production. Liquid-fluoride-salt-cooled, graphite-moderated reactors, referred to as Fluoride Salt Reactors (FHRs), are specifically designed to exploit the excellent heat transfer properties of liquid fluoride salts while maximizing their thermal efficiency and minimizing cost. The FHR s outstanding heat transfer properties, combined with its fully passive safety, make this reactor the most technologically desirable nuclear power reactor class for next-generation energy production. Multiple FHR designs are presently being considered. These range from the Pebble Bed Advanced High Temperature Reactor (PB-AHTR) [1] design originally developed by UC-Berkeley to the Small Advanced High-Temperature Reactor (SmAHTR) and the large scale FHR both being developed at ORNL [2]. The value of high-temperature, molten-salt-cooled reactors is also recognized internationally, and Czechoslovakia, France, India, and China all have salt-cooled reactor development under way. The liquid salt experiment presently being developed uses the PB-AHTR as its focus. One core design of the PB-AHTR features multiple 20 cm diameter, 3.2 m long fuel channels

  8. Quench in high temperature superconductor magnets

    CERN Document Server

    Schwartz, J.

    2013-01-01

    High field superconducting magnets using high temperature superconductors are being developed for high energy physics, nuclear magnetic resonance and energy storage applications. Although the conductor technology has progressed to the point where such large magnets can be readily envisioned, quench protection remains a key challenge. It is well-established that quench propagation in HTS magnets is very slow and this brings new challenges that must be addressed. In this paper, these challenges are discussed and potential solutions, driven by new technologies such as optical fiber based sensors and thermally conducting electrical insulators, are reviewed.

  9. Energy storage via high temperature superconductivity (SMES)

    Energy Technology Data Exchange (ETDEWEB)

    Mikkonen, R. [Tampere Univ. of Technology (Finland)

    1998-10-01

    The technology concerning high temperature superconductors (HTS) is matured to enabling different kind of prototype applications including SMES. Nowadays when speaking about HTS systems, attention is focused on the operating temperature of 20-30 K, where the critical current and flux density are fairly close to 4.2 K values. In addition by defining the ratio of the energy content of a novel HTS magnetic system and the required power to keep the system at the desired temperature, the optimum settles to the above mentioned temperature range. In the frame of these viewpoints a 5 kJ HTS SMES system has been designed and tested at Tampere University of Technology with a coil manufactured by American Superconductor (AMSC). The HTS magnet has inside and outside diameters of 252 mm and 317 mm, respectively and axial length of 66 mm. It operates at 160 A and carries a total of 160 kA-turns to store the required amount of energy. The effective magnetic inductance is 0.4 H and the peak axial field is 1.7 T. The magnet is cooled to the operating temperature of 20 K with a two stage Gifford-McMahon type cryocooler with a cooling power of 60 W at 77 K and 8 W at 20 K. The magnetic system has been demonstrated to compensate a short term loss of power of a sensitive consumer

  10. High temperature deformation of silicon steel

    Energy Technology Data Exchange (ETDEWEB)

    Rodriguez-Calvillo, Pablo, E-mail: pablo.rodriguez@ctm.com.es [CTM - Technologic Centre, Materials Technology Area, Manresa, Cataluna (Spain); Department of Materials Science and Metallurgical Engineering, Universidad Politecnica de Cataluna, Barcelona (Spain); Houbaert, Yvan, E-mail: Yvan.Houbaert@UGent.be [Department of Materials Science and Engineering, University of Ghent (Belgium); Petrov, Roumen, E-mail: Roumen.Petrov@ugent.be [Department of Materials Science and Engineering, University of Ghent (Belgium); Kestens, Leo, E-mail: Leo.kestens@ugent.be [Department of Materials Science and Engineering, University of Ghent (Belgium); Colas, Rafael, E-mail: rafael.colas@uanl.edu.mx [Facultad de Ingenieria Mecanica y Electrica, Universidad Autonoma de Nuevo Leon (Mexico); Centro de Innovacion, Investigacion y Desarrollo en Ingenieria y Tecnologia, Universidad Autonoma de Nuevo Leon (Mexico)

    2012-10-15

    The microstructure and texture development during high temperature plane strain compression of 2% in weight silicon steel was studied. The tests were carried out at a constant strain rate of 5 s{sup -1} with reductions of 25, 35 and 75% at temperatures varying from 800 to 1100 Degree-Sign C. The changes in microstructure and texture were studied by means of scanning electron microscopy and electron backscattered diffraction. The microstructure close to the surface of the samples was equiaxed, which is attributed to the shear caused by friction, whereas that at the centre of the specimens was made of a mixture of elongated and fine equiaxed grains, the last ones attributed to the action of dynamic recovery followed by recrystallization. It was found that the volume fraction of these equiaxed grains augmented as reduction and temperature increased; a 0.7 volume fraction was accomplished with a 75% reduction at 1100 Degree-Sign C. The texture of the equiaxed and elongated grains was found to vary with the increase of deformation and temperature, as the {gamma}-fibre tends to disappear and the {alpha}-fibre to increase towards the higher temperature range. -- Highlights: Black-Right-Pointing-Pointer The plastic deformation of a silicon containing steel is studied by plane strain compression. Black-Right-Pointing-Pointer Equiaxed and elongated grains develop in different regions of the sample due to recrystallization. Black-Right-Pointing-Pointer Texture, by EBSD, is revealed to be similar in either type of grains.

  11. Gasification of high ash, high ash fusion temperature bituminous coals

    Science.gov (United States)

    Liu, Guohai; Vimalchand, Pannalal; Peng, WanWang

    2015-11-13

    This invention relates to gasification of high ash bituminous coals that have high ash fusion temperatures. The ash content can be in 15 to 45 weight percent range and ash fusion temperatures can be in 1150.degree. C. to 1500.degree. C. range as well as in excess of 1500.degree. C. In a preferred embodiment, such coals are dealt with a two stage gasification process--a relatively low temperature primary gasification step in a circulating fluidized bed transport gasifier followed by a high temperature partial oxidation step of residual char carbon and small quantities of tar. The system to process such coals further includes an internally circulating fluidized bed to effectively cool the high temperature syngas with the aid of an inert media and without the syngas contacting the heat transfer surfaces. A cyclone downstream of the syngas cooler, operating at relatively low temperatures, effectively reduces loading to a dust filtration unit. Nearly dust- and tar-free syngas for chemicals production or power generation and with over 90%, and preferably over about 98%, overall carbon conversion can be achieved with the preferred process, apparatus and methods outlined in this invention.

  12. Electrochemical high-temperature gas sensors

    Science.gov (United States)

    Saruhan, B.; Stranzenbach, M.; Yüce, A.; Gönüllü, Y.

    2012-06-01

    Combustion produced common air pollutant, NOx associates with greenhouse effects. Its high temperature detection is essential for protection of nature. Component-integration capable high-temperature sensors enable the control of combustion products. The requirements are quantitative detection of total NOx and high selectivity at temperatures above 500°C. This study reports various approaches to detect NO and NO2 selectively under lean and humid conditions at temperatures from 300°C to 800°C. All tested electrochemical sensors were fabricated in planar design to enable componentintegration. We suggest first an impedance-metric gas sensor for total NOx-detection consisting of NiO- or NiCr2O4-SE and PYSZ-electrolyte. The electrolyte-layer is about 200μm thickness and constructed of quasi-single crystalline columns. The sensing-electrode (SE) is magnetron sputtered thin-layers of NiO or NiCr2O4. Sensor sensitivity for detection of total NOx has been measured by applying impedance analysis. The cross-sensitivity to other emission gases such as CO, CO2, CH4 and oxygen (5 vol.%) has been determined under 0-1000ppm NO. Sensor maintains its high sensitivity at temperatures up to 550°C and 600°C, depending on the sensing-electrode. NiO-SE yields better selectivity to NO in the presence of oxygen and have shorter response times comparing to NiCr2O4-SE. For higher temperature NO2-sensing capability, a resistive DC-sensor having Al-doped TiO2-sensing layers has been employed. Sensor-sensitivity towards NO2 and cross-sensitivity to CO has been determined in the presence of H2O at temperatures 600°C and 800°C. NO2 concentrations varying from 25 to 100ppm and CO concentrations from 25 to 75ppm can be detected. By nano-tubular structuring of TiO2, NO2 sensitivity of the sensor was increased.

  13. Mechanical spectroscopy of reactor-pressure-vessel steel embrittlement: a progress report

    Energy Technology Data Exchange (ETDEWEB)

    Van Ouytsel, K

    1998-08-01

    An enhanced surveillance strategy for testing the fracture toughness of reactor-pressure-vessel steel embrittlement is described. Microstructural investigation in support of damage modelling is an essential element in this enhanced strategy. Temperature-dependent experiments are very sensitive to differences in chemical composition and to effects of neutron irradiation as well as thermal ageing. Amplitude-dependent experiments can be related to tensile test results and correspond to a model for the yield stress. A full range of experiments were carried out on base and weld metal from the Doel-I-II power plants. The results have indicated that internal friction yields information which cannot always be detected by means of standard testing techniques. An inverted torsion pendulum for measuring internal friction has been constructed.

  14. Vapor phase lubrication of high temperature alloys

    Energy Technology Data Exchange (ETDEWEB)

    Hanyaloglu, B.F.; Graham, E.E.; Oreskovic, T.; Hajj, C.G. [Cleveland State Univ., OH (United States)

    1995-06-01

    In a previous study, it was found that when a nickel-based superalloy IN750 was heated to high temperatures, a passive layer of aluminum oxide formed on the surface, preventing vapor phase lubrication. In this study, two nickel-chrome-iron alloys and a nickel-copper alloy were studied for high temperature lubrication to see if these alloys, which contained small amounts of aluminum, would exhibit similar behavior. It was found that under static conditions, all three alloys formed a lubricious nodular coating when exposed to a vapor of aryl phosphate. Under dynamic sliding conditions at 500{degrees}C, these alloys were successfully lubricated with a coefficient of friction of 0.1 and no detectable wear. In order to explain these results, a direct correlation between successful vapor phase lubrication and the composition of the alloys containing aluminum has been proposed. If the ratio of copper/aluminum or iron/aluminum is greater that 100 vapor phase, lubrication will be successful. If the ratio is less than 10, a passive aluminum oxide layer will prevent vapor phase lubrication. By selecting alloys with a high iron or copper content, vapor phase lubrication can provide excellent lubrication at high temperatures. 14 refs., 11 figs., 1 tab.

  15. Medium Deep High Temperature Heat Storage

    Science.gov (United States)

    Bär, Kristian; Rühaak, Wolfram; Schulte, Daniel; Welsch, Bastian; Chauhan, Swarup; Homuth, Sebastian; Sass, Ingo

    2015-04-01

    Heating of buildings requires more than 25 % of the total end energy consumption in Germany. Shallow geothermal systems for indirect use as well as shallow geothermal heat storage systems like aquifer thermal energy storage (ATES) or borehole thermal energy storage (BTES) typically provide low exergy heat. The temperature levels and ranges typically require a coupling with heat pumps. By storing hot water from solar panels or thermal power stations with temperatures of up to 110 °C a medium deep high temperature heat storage (MDHTS) can be operated on relatively high temperature levels of more than 45 °C. Storage depths of 500 m to 1,500 m below surface avoid conflicts with groundwater use for drinking water or other purposes. Permeability is typically also decreasing with greater depth; especially in the crystalline basement therefore conduction becomes the dominant heat transport process. Solar-thermal charging of a MDHTS is a very beneficial option for supplying heat in urban and rural systems. Feasibility and design criteria of different system configurations (depth, distance and number of BHE) are discussed. One system is designed to store and supply heat (300 kW) for an office building. The required boreholes are located in granodioritic bedrock. Resulting from this setup several challenges have to be addressed. The drilling and completion has to be planned carefully under consideration of the geological and tectonical situation at the specific site.

  16. Influence of the thermodynamic parameters on the temper embrittlement of SA508 Gr.4N Ni-Cr-Mo low alloy steel with variation of Ni, Cr and Mn contents

    Science.gov (United States)

    Park, Sang-Gyu; Lee, Ki-Hyoung; Min, Ki-Deuk; Kim, Min-Chul; Lee, Bong-Sang

    2012-07-01

    It is well known that SA508 Gr.4N low alloy steel offers improved fracture toughness and strength compared to commercial low alloy steels such as SA508 Gr.3 Mn-Mo-Ni low alloy steel. In this study, the effects of Cr, Mn, and Ni on temper embrittlement in SA508 Gr.4N low alloy steel were evaluated from the viewpoint of thermodynamic parameters such as P diffusivity and C activity. The changes of the ductile-brittle transition temperatures before and after aging were correlated with varying alloying element content, and the diffusivity of P and the activity of C were calculated and correlated with the transition behaviors. The addition of Ni, Cr, and Mn reduce the resistance to temper embrittlement, showing increased Transition-Temperature Shift (TTS) and an increased fraction of intergranular fracture. Although the diffusivity of P is changed by the addition of alloying elements, it does not considerably affect the temper embrittlement. The Mn and Cr content in the matrix significantly reduce the C activity, with showing an inversely proportional relationship to TTS. The change of susceptibility to temper embrittlement caused by Cr and Mn addition could be explained by the variation of C activity. Unlike Cr and Mn, Ni has little effect on the temper embrittlement and C activity.

  17. Influence of the thermodynamic parameters on the temper embrittlement of SA508 Gr.4N Ni-Cr-Mo low alloy steel with variation of Ni, Cr and Mn contents

    Energy Technology Data Exchange (ETDEWEB)

    Park, Sang-Gyu; Lee, Ki-Hyoung [Nuclear Materials Research Division, Korea Atomic Energy Research Institute, 150-1 Deogjin-dong, Yuseong-gu, Daejeon 305-353 (Korea, Republic of); Min, Ki-Deuk [Division of Material Science and Engineering, Hanyang University, 17 Haengdang-dong, Seongdong-gu, Seoul 133-791 (Korea, Republic of); Kim, Min-Chul, E-mail: mckim@kaeri.re.kr [Nuclear Materials Research Division, Korea Atomic Energy Research Institute, 150-1 Deogjin-dong, Yuseong-gu, Daejeon 305-353 (Korea, Republic of); Lee, Bong-Sang [Nuclear Materials Research Division, Korea Atomic Energy Research Institute, 150-1 Deogjin-dong, Yuseong-gu, Daejeon 305-353 (Korea, Republic of)

    2012-07-15

    It is well known that SA508 Gr.4N low alloy steel offers improved fracture toughness and strength compared to commercial low alloy steels such as SA508 Gr.3 Mn-Mo-Ni low alloy steel. In this study, the effects of Cr, Mn, and Ni on temper embrittlement in SA508 Gr.4N low alloy steel were evaluated from the viewpoint of thermodynamic parameters such as P diffusivity and C activity. The changes of the ductile-brittle transition temperatures before and after aging were correlated with varying alloying element content, and the diffusivity of P and the activity of C were calculated and correlated with the transition behaviors. The addition of Ni, Cr, and Mn reduce the resistance to temper embrittlement, showing increased Transition-Temperature Shift (TTS) and an increased fraction of intergranular fracture. Although the diffusivity of P is changed by the addition of alloying elements, it does not considerably affect the temper embrittlement. The Mn and Cr content in the matrix significantly reduce the C activity, with showing an inversely proportional relationship to TTS. The change of susceptibility to temper embrittlement caused by Cr and Mn addition could be explained by the variation of C activity. Unlike Cr and Mn, Ni has little effect on the temper embrittlement and C activity.

  18. Microstructure and embrittlement of VVER 440 reactor pressure vessel steels; Microstructure et fragilisation des aciers de cuve des reacteurs nucleaires VVER 440

    Energy Technology Data Exchange (ETDEWEB)

    Hennion, A

    1999-03-15

    27 VVER 440 pressurised water reactors operate in former Soviet Union and in Eastern Europe. The pressure vessel, is made of Cr-Mo-V steel. It contains a circumferential arc weld in front of the nuclear core. This weld undergoes a high neutron flux and contains large amounts of copper and phosphorus, elements well known for their embrittlement potency under irradiation. The embrittlement kinetic of the steel is accelerated, reducing the lifetime of the reactor. In order to get informations on the microstructure and mechanical properties of these steels, base metals, HAZ, and weld metals have been characterized. The high amount of phosphorus in weld metals promotes the reverse temper embrittlement that occurs during post-weld heat treatment. The radiation damage structure has been identified by small angle neutron scattering, atomic probe, and transmission electron microscopy. Nanometer-sized clusters of solute atoms, rich in copper with almost the same characteristics as in western pressure vessels steels, and an evolution of the size distribution of vanadium carbides, which are present on dislocation structure, are observed. These defects disappear during post-irradiation tempering. As in western steels, the embrittlement is due to both hardening and reduction of interphase cohesion. The radiation damage specificity of VVER steels arises from their high amount of phosphorus and from their significant density of fine vanadium carbides. (author)

  19. Impact of radiation embrittlement on integrity of pressure vessel supports for two PWR plants

    Energy Technology Data Exchange (ETDEWEB)

    Cheverton, R.D.; Pennell, W.E.; Robinson, G.C.; Nanstad, R.K.

    1989-01-01

    Recent data from the HFIR vessel surveillance program indicate a substantial radiation embrittlement rate effect at low irradiation temperatures (/approximately/120/degree/F) for A212-B, A350-LF3, A105-II, and corresponding welds. PWR vessel supports are fabricated of similar materials and are subjected to the same low temperatures and fast neutron fluxes (10/sup 8/ to 10/sup 9/ neutrons/cm/sup 2//center dot/s, E > 1.0 MeV) as those in the HFIR vessel. Thus, the embrittlement rate of these structures may be greater than previously anticipated. A study sponsored by the NRC is under way at ORNL to determine the impact of the rate effect on PWR vessel-support life expectancy. The scope includes the interpretation and application of the HFIR data, a survey of all light-water-reactor vessel support designs, and a structural and fracture-mechanics analysis of the supports for two specific PWR plants of particular interest with regard to a potential for support failure as a result of propagation of flaws. Calculations performed thus far indicate best-estimate critical flaw sizes, corresponding to 32 EFPY, of /approximately/0.2 in. for one plant and /approximately/0.4 in. for the other. These flaw sizes are small enough to be of concern. However, it appears that low-cycle fatigue is not a viable mechanism for creation of flaws of this size, and thus, presumably, such flaws would have to exist at the time of fabrication. 59 refs., 128 figs., 49 tabs.

  20. High temperature superconductors for magnetic suspension applications

    Science.gov (United States)

    Mcmichael, C. K.; Cooley, R. S.; Chen, Q. Y.; Ma, K. B.; Lamb, M. A.; Meng, R. L.; Chu, C. W.; Chu, W. K.

    1994-01-01

    High temperature superconductors (HTS) hold the promise for applications in magnetic levitation bearings, vibration damping, and torque coupling. Traditional magnetic suspension systems require active feedback and vibration controls in which power consumption and low frequency vibration are among the major engineering concerns. HTS materials have been demonstrated to be an enabling approach towards such problems due to their flux trapping properties. In our laboratory at TCSUH, we have been conducting a series of experiments to explore various mechanical applications using HTS. We have constructed a 30 lb. model flywheel levitated by a hybrid superconducting magnetic bearing (HSMB). We are also developing a levitated and vibration-dampled platform for high precision instrumentation. These applications would be ideal for space usages where ambient temperature is adequate for HTS to operate properly under greatly reduced cryogenic requirements. We will give a general overview of these potential applications and discuss the operating principles of the HTS devices we have developed.

  1. Metallic Membranes for High Temperature Hydrogen Separation

    DEFF Research Database (Denmark)

    Ma, Y.H.; Catalano, Jacopo; Guazzone, Federico

    2013-01-01

    Composite palladium membranes have extensively been studied in laboratories and, more recently, in small pilot industrial applications for the high temperature separation of hydrogen from reactant mixtures such as water-gas shift (WGS) reaction or methane steam reforming (MSR). Composite Pd...... membrane fabrication methods have matured over the last decades, and the deposition of very thin films (1–5 µm) of Pd over porous ceramics or modified porous metal supports is quite common. The H2 permeances and the selectivities achieved at 400–500 °C were in the order of 50–100 Nm3/m/h/bar0.5 and greater...... than 1000, respectively. This chapter describes in detail composite Pd-based membrane preparation methods, which consist of the grading of the support and the deposition of the dense metal layer, their performances, and their applications in catalytic membrane reactors (CMRs) at high temperatures (400...

  2. High Temperature Phenomena in Shock Waves

    CERN Document Server

    2012-01-01

    The high temperatures generated in gases by shock waves give rise to physical and chemical phenomena such as molecular vibrational excitation, dissociation, ionization, chemical reactions and inherently related radiation. In continuum regime, these processes start from the wave front, so that generally the gaseous media behind shock waves may be in a thermodynamic and chemical non-equilibrium state. This book presents the state of knowledge of these phenomena. Thus, the thermodynamic properties of high temperature gases, including the plasma state are described, as well as the kinetics of the various chemical phenomena cited above. Numerous results of measurement and computation of vibrational relaxation times, dissociation and reaction rate constants are given, and various ionization and radiative mechanisms and processes are presented. The coupling between these different phenomena is taken into account as well as their interaction with the flow-field. Particular points such as the case of rarefied flows an...

  3. Trends in Surface Temperature at High Latitudes

    Science.gov (United States)

    Comiso, Josefino C.

    2012-01-01

    The earliest signal of a climate change is expected to be found in the polar regions where warming is expected to be amplified on account of ice-albedo feedbacks associated with the high reflectivity of snow and ice. Because of general inaccessibility, there is a general paucity of in situ data and hence the need to use satellite data to observe the large-scale variability and trends in surface temperature in the region. Among the most important sensors for monitoring surface temperature has been the Advanced Very High Resolution Radiometer (AVHRR) which was first launched in 1978 and has provided continuous thermal infrared data since 1981. The top of the atmosphere data are converted to surface temperature data through various schemes that accounts for the unique atmospheric and surface conditions in the polar regions. Among the highest source of error in the data is cloud masking which is made more difficult in the polar region because of similar Signatures of clouds and snow lice covered areas. The availability of many more channels in the Moderate Resolution Imaging Spectroradiometer (MODIS) launched on board Terra satellite in December 1999 and on board Aqua in May 2002 (e.g., 36 visible and infrared channels compared to 5 for AVHRR) made it possible to minimize the error. Further capabilities were introduced with the Advanced Microwave Scanning Radiometer (AMSR) which has the appropriate frequency channels for the retrieval of sea surface temperature (SST). The results of analysis of the data show an amplified warming in the Arctic region, compared with global warming. The spatial distribution of warming is, however, not uniform and during the last 3 decades, positive temperature anomalies have been most pronounced in North America, Greenland and the Arctic basin. Some regions of the Arctic such as Siberia and the Bering Sea surprisingly show moderate cooling but this may be because these regions were anomalously warm in the 1980s when the satellite record

  4. Novel High Temperature Magnetic Bearings for Space Vehicle Systems Project

    Data.gov (United States)

    National Aeronautics and Space Administration — Previous high temperature magnetic bearings employed only electromagnets. The work proposed in this SBIR program seeks to utilize High Temperature Permanent Magnets...

  5. Novel High Temperature Magnetic Bearings for Space Vehicle Systems Project

    Data.gov (United States)

    National Aeronautics and Space Administration — Previous high temperature magnetic bearings employed electromagnets only. The work proposed in this SBIR program seeks to utilize High Temperature Permanent Magnets...

  6. High temperature impedance spectroscopy of barium stannate ...

    Indian Academy of Sciences (India)

    Abstract. Polycrystalline powder of BaSnO3 was prepared at 1300 ◦C using a high-temperature solid-state reac- tion technique. X-ray diffraction analysis indicated the formation of a single-phase cubic structure with lattice parameter: a = (4·1158 ± 0·0003) Å. The synthesized powder was characterized using X-ray diffraction ...

  7. High temperature mechanical properties of iron aluminides

    Directory of Open Access Journals (Sweden)

    Morris, D. G.

    2001-04-01

    Full Text Available Considerable attention has been given to the iron aluminide family of intermetallics over the past years since they offer considerable potential as engineering materials for intermediate to high temperature applications, particularly in cases where extreme oxidation or corrosion resistance is required. Despite efforts at alloy development, however, high temperature strength remains low and creep resistance poor. Reasons for the poor high-temperature strength of iron aluminides will be discussed, based on the ordered crystal structure, the dislocation structure found in the material, and the mechanisms of dislocation pinning operating. Alternative ways of improving high temperature strength by microstructural modification and the inclusion of second phase particles will also be considered.

    Durante los últimos años se ha prestado mucha atención a la familia de intermetálicos Fe-Al, puesto que estos constituyen un considerable potencial como materiales de ingeniería en aplicaciones a temperaturas intermedias o altas, sobre todo en casos donde se necesita alta resistencia a la oxidación o corrosión. A pesar del considerable esfuerzo desarrollado para obtener aleaciones con mejores propiedades, su resistencia mecánica a alta temperatura no es muy elevada. Se discutirán los aspectos que contribuyen a la baja resistencia mecánica a temperatura elevada en función de la estructura de dislocaciones y los mecanismos de anclaje que operan en este intermetálico. Se considerarán, también, maneras alternativas para mejorar la resistencia a temperatura elevada mediante la modificación de la microestructura y la incorporación de partículas de segunda fase.

  8. Fundamental aspects of high-temperature corrosion

    OpenAIRE

    Rapp, Robert

    1993-01-01

    Some recent considerations in three widely different aspects of high-temperature corrosion are summarized: 1) reactions at the metal/scale interface in support of scale growth; 2) mass transfer effects in the control of evaporation of volatile reaction products; and 3) the codeposition of multiple elements for diffusion coatings using halide-activated cementation packs. The climb of misfit edge dislocations from the metal/scale interface can achieve the annihilation of vacancies associated wi...

  9. Thermal fuse for high-temperature batteries

    Science.gov (United States)

    Jungst, Rudolph G.; Armijo, James R.; Frear, Darrel R.

    2000-01-01

    A thermal fuse, preferably for a high-temperature battery, comprising leads and a body therebetween having a melting point between approximately 400.degree. C. and 500.degree. C. The body is preferably an alloy of Ag--Mg, Ag--Sb, Al--Ge, Au--In, Bi--Te, Cd--Sb, Cu--Mg, In--Sb, Mg--Pb, Pb--Pd, Sb--Zn, Sn--Te, or Mg--Al.

  10. High-Temperature Thermoelectric Energy Conversion

    Science.gov (United States)

    Wood, C.

    1987-01-01

    Theory of thermoelectric energy conversion at high temperatures and status of research on conversion materials reviewed in report. Shows highest values of thermoelectric figure of merit, Z, found in semiconductor materials. Semiconductors keep wide choice of elements and compounds. Electrical properties tailored to particular application by impurity doping and control of stoichiometry. Report develops definition of Z useful for comparing materials and uses it to evaluate potentials of different classes of materialsmetals, semiconductors, and insulators.

  11. High Temperature Perforating System for Geothermal Applications

    Energy Technology Data Exchange (ETDEWEB)

    Smart, Moises E. [Schlumberger Technology Corporation, Sugar Land, TX (United States)

    2017-02-28

    The objective of this project is to develop a perforating system consisting of all the explosive components and hardware, capable of reliable performance in high temperatures geothermal wells (>200 ºC). In this light we will focused on engineering development of these components, characterization of the explosive raw powder and developing the internal infrastructure to increase the production of the explosive from laboratory scale to industrial scale.

  12. High-temperature technological processes: Thermophysical principles

    Science.gov (United States)

    Rykalin, N. N.; Uglov, A. A.; Anishchenko, L. M.

    The book is concerned with the principles of thermodynamics and heat transfer theory underlying high-temperature technological processes. Some characteristics of electromagnetic radiation and heat transfer in solids, liquids, and gases are reviewed, and boundary layer theory, surface phenomena, and phase transitions are examined. The discussion includes an analysis of a number of specific processes, such as treatment by concentrated energy fluxes (electron-beam and laser processing) and plasma machining.

  13. Brittle Materials Design, High Temperature Gas Turbine

    Science.gov (United States)

    1981-03-01

    Modulus and Poisson’s Ratio were determined by sonic techniques: thermal expansion values were measured on a differential dilatometer and thermal...accumulation of potentially explosive gases. 4. Thermal conductivity of the nitriding atmosphere is important for production of high quality RBSN...of varying MgO content. Measurements were conducted on a differential dilatometer from room temperatures up to 900°C, and are shown in Figure 3.2.3

  14. High temperature inorganic membranes for separating hydrogen

    Energy Technology Data Exchange (ETDEWEB)

    Fain, D.E.; Roettger, G.E. [Oak Ridge K-25 Site, TN (United States)

    1995-08-01

    Effort has continued to accumulate data on the transport of gases over the temperature range from room temperature to 275{degrees}C with inorganic membranes having a range of pore radii from approximately 0.25 nm to 3 mn. An experimental alumina membrane having an estimated mean pore radius of 0.25 nm has been fabricated and tested. Extensive testing of this membrane indicated that the separation factor for helium and carbon tetrafluoride at 250{degrees}C was 59 and the extrapolated high temperature separation factor was 1,193. For safety reasons, earlier flow measurements concentrated on helium, carbon dioxide, and carbon tetrafluoride. New data have been acquired with hydrogen to verify the agreement with the other gases. During the measurements with hydrogen, it was noted that a considerable amount of moisture was present in the test gas. The source of this moisture and its effect on permeance was examined. Improvements were implemented to the flow test system to minimize the water content of the hydrogen test gas, and subsequent flow measurements have shown excellent results with hydrogen. The extrapolation of separation factors as a function of temperature continues to show promise as a means of using the hard sphere model to determine the pore size of membranes. The temperature dependence of helium transport through membranes appears to be considerably greater than other gases for the smallest pore sizes. The effort to extend temperature dependence to the hard sphere model continues to be delayed, primarily because of a lack of adequate adsorption data.

  15. New fluid for high temperature applications

    Energy Technology Data Exchange (ETDEWEB)

    Riva, M.; Flohr, F. [Solvay Fluor GmbH, Hannover (Germany); Froeba, A.P. [Lehrstuhl fuer Technische Thermodynamik (LTT), Univ. Erlangen (Germany)

    2006-12-15

    As a result of the worldwide increased consumption of energy, energy saving measures come more and more in the focus of commercial acting. Besides the efficiency enhancement of energy consuming systems the utilization of waste heat is an additional possibility of saving energy. Areas where this might be feasible are geothermal power plants, local combined heat and power plants, solar-thermal-systems and high temperature heat pumps (HTHP). All these applications need a transfer fluid which secures the transport of the energy from it's source to the place where it is needed at high temperatures. The paper will start with a description or overview of promising energy sources and their utilization. The thermophysical properties of an azeotropic binary mixture of HFC-365mfc and a per-fluoro-poly-ether (PFPE) which fulfils the requirements on a high temperature working fluid are introduced in the second part of the paper. First results and practical experiences in an ORC process are shown in this context followed by an estimation regarding the saved energy or the improved efficiency respectively for other applications The paper will end with a brief outlook on possible new applications e.g. autarkic systems or immersion cooling of electrical parts. (orig.)

  16. High temperature and pressure alkaline electrolysis

    DEFF Research Database (Denmark)

    Allebrod, Frank; Chatzichristodoulou, Christodoulos; Mogensen, Mogens Bjerg

    2013-01-01

    for immobilization of aqueous KOH solutions. Electrolysis cells with this electrolyte and metal foam based gas diffusion electrodes were successfully demonstrated at temperatures up to 250 °C at 40 bar. Different electro-catalysts were tested in order to reduce the oxygen and hydrogen overpotentials. Current...... the operational temperature and pressure to produce pressurized hydrogen at high rate (m3 H2·h-1·m-2 cell area) and high electrical efficiency. This work describes an exploratory technical study of the possibility to produce hydrogen and oxygen with a new type of alkaline electrolysis cell at high temperatures...... densities of 1.1 A cm-2 and 2.3 A cm-2 have been measured at a cell voltage of 1.5 V and 1.75 V, respectively, without noble metal catalysts. Electrical efficiencies of almost 99 % at 1.1 A cm-2 and 85 % at 2.3 A cm-2 were obtained....

  17. Hydrogen embrittlement in power plant steels

    Indian Academy of Sciences (India)

    In power plants, several major components such as steam generator tubes, boilers, steam/water pipe lines, water box of condensers and the other auxiliary components like bolts, nuts, screws fasteners and supporting assemblies are commonly fabricated from plain carbon steels, as well as low and high alloy steels.

  18. High temperature superconducting digital circuits and subsystems

    Energy Technology Data Exchange (ETDEWEB)

    Martens, J.S.; Pance, A.; Whiteley, S.R.; Char, K.; Johansson, M.F.; Lee, L. [Conductus, Sunnyvale, CA (United States); Hietala, V.M.; Wendt, J.R. [Sandia National Labs., Albuquerque, NM (United States); Hou, S.Y.; Phillips, J. [AT and T Bell Labs., Murray Hill, NJ (United States)

    1993-10-01

    The advances in the fabrication of high temperature superconducting devices have enabled the demonstration of high performance and useful digital circuits and subsystems. The yield and uniformity of the devices is sufficient for circuit fabrication at the medium scale integration (MSI) level with performance not seen before at 77 K. The circuits demonstrated to date include simple gates, counters, analog to digital converters, and shift registers. All of these are mid-sized building blocks for potential applications in commercial and military systems. The processes used for these circuits and blocks will be discussed along with observed performance data.

  19. High-temperature alloys for high-power thermionic systems

    Energy Technology Data Exchange (ETDEWEB)

    Shin, Kwang S.; Jacobson, D.L.; D' cruz, L.; Luo, Anhua; Chen, Bor-Ling.

    1990-08-01

    The need for structural materials with useful strength above 1600 k has stimulated interest in refractory-metal alloys. Tungsten possesses an extreme high modulus of elasticity as well as the highest melting temperature among metals, and hence is being considered as one of the most promising candidate materials for high temperature structural applications such as space nuclear power systems. This report is divided into three chapters covering the following: (1) the processing of tungsten base alloys; (2) the tensile properties of tungsten base alloys; and (3) creep behavior of tungsten base alloys. Separate abstracts were prepared for each chapter. (SC)

  20. Investigation of Teflon FEP Embrittlement on Spacecraft in Low-Earth Orbit

    Science.gov (United States)

    deGroh, Kim K.; Banks, Bruce A.

    1997-01-01

    Teflon fluorinated ethylene propylene (FEP) (DuPont) is commonly used on exterior spacecraft surfaces for thermal control in the low-Earth orbit environment. Silverized or aluminized Teflon FEP is used for the outer layers of the thermal control blanket because of its high reflectance, low solar absorptance, and high thermal emittance. Teflon FEP is also desirable because, compared with other spacecraft polymers (such as Kapton), it has relatively high resistance to atomic oxygen erosion. Because of its comparably low atomic oxygen erosion yield, Teflon FEP has been used unprotected in the space environment. Samples of Teflon FEP from the Long Duration Exposure Facility (LDEF) and the Hubble Space Telescope (retrieved during its first servicing mission) were evaluated for solar-induced embrittlement and for synergistic effects of solar degradation and atomic oxygen.

  1. Microstructural Evolution and Mechanical Behavior of High Temperature Solders: Effects of High Temperature Aging

    Science.gov (United States)

    Hasnine, M.; Tolla, B.; Vahora, N.

    2017-12-01

    This paper explores the effects of aging on the mechanical behavior, microstructure evolution and IMC formation on different surface finishes of two high temperature solders, Sn-5 wt.% Ag and Sn-5 wt.% Sb. High temperature aging showed significant degradation of Sn-5 wt.% Ag solder hardness (34%) while aging has little effect on Sn-5 wt.% Sb solder. Sn-5 wt.% Ag experienced rapid grain growth as well as the coarsening of particles during aging. Sn-5 wt.% Sb showed a stable microstructure due to solid solution strengthening and the stable nature of SnSb precipitates. The increase of intermetallic compound (IMC) thickness during aging follows a parabolic relationship with time. Regression analysis (time exponent, n) indicated that IMC growth kinetics is controlled by a diffusion mechanism. The results have important implications in the selection of high temperature solders used in high temperature applications.

  2. High-temperature brushless DC motor controller

    Energy Technology Data Exchange (ETDEWEB)

    Cieslewski, Crzegorz; Lindblom, Scott C.; Maldonado, Frank J.; Eckert, Michael Nathan

    2017-05-16

    A motor control system for deployment in high temperature environments includes a controller; a first half-bridge circuit that includes a first high-side switching element and a first low-side switching element; a second half-bridge circuit that includes a second high-side switching element and a second low-side switching element; and a third half-bridge circuit that includes a third high-side switching element and a third; low-side switching element. The motor controller is arranged to apply a pulse width modulation (PWM) scheme to switch the first half-bridge circuit, second half-bridge circuit, and third half-bridge circuit to power a motor.

  3. High Pressure and Temperature Effects in Polymers

    Science.gov (United States)

    Bucknall, David; Arrighi, Valeria; Johnston, Kim; Condie, Iain

    Elastomers are widely exploited as the basis for seals in gas and fluid pipelines. The underlying behaviour of these elastomer at the high pressure, elevated temperatures they experience in operation is poorly understood. Consequently, the duty cycle of these materials is often deliberately limited to a few hours, and in order to prevent failure, production is stopped in order to change the seals in critical joints. The result is significant time lost due to bringing down production to change the seals as well as knock on financial costs. In order to address the fundamental nature of the elastomers at their intended operating conditions, we are studying the gas permeation behaviour of hydrogenated natural butyl rubber (HNBR) and fluorinated elastomers (FKM) at a high pressure and elevated temperature. We have developed a pressure system that permits gas permeation studies at gas pressures of up to 5000 psi and operating temperatures up to 150° C. In this paper, we will discuss the nature of the permeation behaviour at these extreme operating conditions, and how this relates to the changes in the polymer structure. We will also discuss the use of graphene-polymer thin layer coatings to modify the gas permeation behaviour of the elastomers.

  4. Conformal Properties in High Temperature QCD

    CERN Document Server

    Ishikawa, K -I; Nakayama, Yu; Yoshie, T

    2015-01-01

    We investigate the properties of quarks and gluons above the chiral phase transition temperature $T_c,$ using the RG improved gauge action and the Wilson quark action with two degenerate quarks mainly on a $32^3\\times 16$ lattice. In the one-loop perturbation theory, the thermal ensemble is dominated by the gauge configurations with effectively $Z(3)$ center twisted boundary conditions, making the thermal expectation value of the spatial Polyakov loop take a non-trivial $Z(3)$ center. This is in agreement with our lattice simulation of high temperature QCD. We further observe that the temporal propagator of massless quarks at extremely high temperature $\\beta=100.0 \\, (T \\simeq10^{58} T_c)$ remarkably agrees with the temporal propagator of free quarks with the $Z(3)$ twisted boundary condition for $t/L_t \\geq 0.2$, but differs from that with the $Z(3)$ trivial boundary condition. As we increase the mass of quarks $m_q$, we find that the thermal ensemble continues to be dominated by the $Z(3)$ twisted gauge fi...

  5. A new cladding embrittlement criterion derived from ring compression tests

    Energy Technology Data Exchange (ETDEWEB)

    Herb, Joachim, E-mail: Joachim.Herb@grs.de; Sievers, Jürgen, E-mail: Juergen.Sievers@grs.de; Sonnenburg, Heinz-Günther, E-mail: Heinz-Guenther.Sonnenburg@grs.de

    2014-07-01

    Highlights: • Using FEM it was possible to simulate measured ring compression test data. • The FEM provides burst stresses from Zry-4, M5 and ZIRLO cladding. • The ratio of burst stresses to yield stresses was correlated. • The ratio depends linearly on the state of oxidation and hydriding. • The ratio of stresses at unity can be applied as embrittlement criterion. - Abstract: It is of regulatory interest to prevent the breaking of fuel rods in LOCA transients. In current regulations this is accomplished by limiting the oxidation during LOCA to such an extent that still some residual ductility is preserved in the fuel rod cladding. The current oxidation limit in German as well as in US regulations is set to 17% ECR (Equivalent Cladding Reacted) which aims at maintaining a residual ductility for oxidized claddings. Recent ANL tests have shown that the combination of both oxidation and additionally hydrogen up-take affects the transition to zero-ductility. Furthermore, the oxidation during LOCA transient is accompanied by a significant up-take of hydrogen (secondary hydriding) if the fuel rod bursts during this transient. This secondary hydriding affects the cladding in the vicinity of the burst opening. These findings necessitate a new criterion for preserving cladding's strength. This paper describes a method how to derive a criterion which assures the required residual mechanical strength of the cladding for LOCA transients. This method utilizes the experimental results of 102 ring compression tests (RCT) conducted at ANL and KIT. RCTs of various cladding materials, oxidation levels and hydrogen content were considered. The basic approach was to compare the RCT test data with finite element analyses using the code ADINA. Starting with the cladding oxidation model of Leistikov, both the layer structure of the cladding and the distribution of the oxygen among these layers were determined. The mechanical properties of these layers were taken from

  6. Fast pyrolysis of biomass at high temperatures

    DEFF Research Database (Denmark)

    Trubetskaya, Anna

    . Different particle shapes of beechwood and leached wheat straw chars produced in the drop tube reactor which have similar potassium content suggested a stronger influence of the major biomass cell wall compounds (cellulose, hemicellulose, lignin and extractives) and silicates on the char morphology than...... multi core structures compared to pinewood soot generated at 1400°C, combining both single and multi core particles.Beechwood and wheat straw soot samples had multi and single core particles at both temperatures.In thermogravimetric analysis, the maximal reaction rate of pinewood soot was shifted...... pyrolysis at high temperatures plays a significant role in the overall combustion process since the biomass type, the reaction kinetics and heat transfer rates during pyrolysis influence the volatile gas release. The solid residue yield and its properties in suspension firing, including particle size...

  7. High Temperature Battery for Drilling Applications

    Energy Technology Data Exchange (ETDEWEB)

    Josip Caja

    2009-12-31

    In this project rechargeable cells based on the high temperature electrochemical system Na/beta''-alumina/S(IV) in AlCl3/NaCl were developed for application as an autonomous power source in oil/gas deep drilling wells. The cells operate in the temperature range from 150 C to 250 C. A prototype DD size cell was designed and built based on the results of finite element analysis and vibration testing. The cell consisted of stainless steel case serving as anode compartment with cathode compartment installed in it and a seal closing the cell. Critical element in cell design and fabrication was hermetically sealing the cell. The seal had to be leak tight, thermally and vibration stable and compatible with electrode materials. Cathode compartment was built of beta''-alumina tube which served as an electrolyte, separator and cathode compartment.

  8. Creep resistant high temperature martensitic steel

    Energy Technology Data Exchange (ETDEWEB)

    Hawk, Jeffrey A.; Jablonski, Paul D.; Cowen, Christopher J.

    2015-11-13

    The disclosure provides a creep resistant alloy having an overall composition comprised of iron, chromium, molybdenum, carbon, manganese, silicon, nickel, vanadium, niobium, nitrogen, tungsten, cobalt, tantalum, boron, and potentially additional elements. In an embodiment, the creep resistant alloy has a molybdenum equivalent Mo(eq) from 1.475 to 1.700 wt. % and a quantity (C+N) from 0.145 to 0.205. The overall composition ameliorates sources of microstructural instability such as coarsening of M.sub.23C.sub.6 carbides and MX precipitates, and mitigates or eliminates Laves and Z-phase formation. A creep resistant martensitic steel may be fabricated by preparing a melt comprised of the overall composition followed by at least austenizing and tempering. The creep resistant alloy exhibits improved high-temperature creep strength in the temperature environment of around 650.degree. C.

  9. Creep resistant high temperature martensitic steel

    Energy Technology Data Exchange (ETDEWEB)

    Hawk, Jeffrey A.; Jablonski, Paul D.; Cowen, Christopher J.

    2017-01-31

    The disclosure provides a creep resistant alloy having an overall composition comprised of iron, chromium, molybdenum, carbon, manganese, silicon, nickel, vanadium, niobium, nitrogen, tungsten, cobalt, tantalum, boron, copper, and potentially additional elements. In an embodiment, the creep resistant alloy has a molybdenum equivalent Mo(eq) from 1.475 to 1.700 wt. % and a quantity (C+N) from 0.145 to 0.205. The overall composition ameliorates sources of microstructural instability such as coarsening of M.sub.23C.sub.6carbides and MX precipitates, and mitigates or eliminates Laves and Z-phase formation. A creep resistant martensitic steel may be fabricated by preparing a melt comprised of the overall composition followed by at least austenizing and tempering. The creep resistant alloy exhibits improved high-temperature creep strength in the temperature environment of around 650.degree. C.

  10. FY16 ASME High Temperature Code Activities

    Energy Technology Data Exchange (ETDEWEB)

    Swindeman, M. J. [Chromtech Inc., Oak Ridge, TN (United States); Jetter, R. I. [R. I Jetter Consulting, Pebble Beach, CA (United States); Sham, T. -L. [Argonne National Lab. (ANL), Argonne, IL (United States)

    2016-09-01

    One of the objectives of the ASME high temperature Code activities is to develop and validate both improvements and the basic features of Section III, Division 5, Subsection HB, Subpart B (HBB). The overall scope of this task is to develop a computer program to be used to assess whether or not a specific component under specified loading conditions will satisfy the elevated temperature design requirements for Class A components in Section III, Division 5, Subsection HB, Subpart B (HBB). There are many features and alternative paths of varying complexity in HBB. The initial focus of this task is a basic path through the various options for a single reference material, 316H stainless steel. However, the program will be structured for eventual incorporation all the features and permitted materials of HBB. Since this task has recently been initiated, this report focuses on the description of the initial path forward and an overall description of the approach to computer program development.

  11. Diamond switches for high temperature electronics

    Energy Technology Data Exchange (ETDEWEB)

    Prasad, R.R.; Rondeau, G.; Qi, Niansheng [Alameda Applied Sciences Corp., San Leandro, CA (United States)] [and others

    1996-04-25

    Diamond switches are well suited for use in high temperature electronics. Laboratory feasibility of diamond switching at 1 kV and 18 A was demonstrated. DC blocking voltages up to 1 kV were demonstrated. A 50 {Omega} load line was switched using a diamond switch, with switch on-state resistivity {approx}7 {Omega}-cm. An electron beam, {approx}150 keV energy, {approx}2 {mu}s full width at half maximum was used to control the 5 mm x 5 mm x 100 {mu}m thick diamond switch. The conduction current temporal history mimics that of the electron beam. These data were taken at room temperature.

  12. Electrical Conductivity of Micas at High Temperatures

    Science.gov (United States)

    Watanabe, T.

    2008-12-01

    Electrical conductivity, along with seismic velocity, gives us clues to infer constituent materials and temperatures in the Earth's interior. Dry rocks have been considered to be electrically insulating at crustal temperatures. Observed high conductivity has been ascribed to the existence of fluids. However, Fuji-ta et al. (2007) recently reported that a dry gneiss shows relatively high conductivity (10-4-10-3 S/m) at the temperature of 300-400°C, and that it is strongly anisotropic in conductivity. They suggested that the alignment of biotite grains governs conductivity of the gneiss sample. Electrical properties of rock forming minerals are still poorly understood. We thus have measured electrical properties of biotite single crystals up to 700°C. In order to get a good understanding of conduction mechanisms, measurements have been also made on phlogopite and muscovite, which are common micas with similar crystallographic structures. Thin plates parallel to cleavages (thickness~0.1mm) were prepared from mica single crystals. Electrical impedance was measured by 2-electrode method. The specimen was kept in nitrogen or argon atmosphere. The conductivity measured parallel to cleavages is higher than that measured perpendicular to cleavages by 3-4 orders of magnitude. However, no significant difference in the activation energy of conductivity was observed between two directions. The activation energy of conductivity is ~50 kJ/mol for biotite and ~100 kJ/mol for phlogopite and muscovite. The conductivity of biotite is higher than those of phlogopite and muscovite by several orders of magnitude at the same temperature. The conductivity of biotite parallel to cleavages is ~10-1 S/m at 400°C. The conductivity of biotite increases irreversibly by heating. The irreversible change was not significant below 450°C. Remarkable increase is observed at the temperature of 450-550°C. No significant change was observed in the second heating. Such an increase in conductivity

  13. Temperature Prediction for High Pressure High Temperature Condensate Gas Flow Through Chokes

    Directory of Open Access Journals (Sweden)

    Changjun Li

    2012-03-01

    Full Text Available This study developed a theoretical model for predicting the downstream temperatures of high pressure high temperature condensate gas flowing through chokes. The model is composed of three parts: the iso-enthalpy choke model derived from continuity equation and energy conservation equation; the liquid-vapor equilibrium model based on the SRK equation of state (EoS; and the enthalpy model based on the Lee-Kesler EoS. Pseudocritical properties of mixtures, which are obtained by mixing rules, are very important in the enthalpy model, so the Lee-Kesler, Plocker-Knapp, Wong-Sandler and Prausnitz-Gunn mixing rules were all researched, and the combination mixing rules with satisfactory accuracy for high pressure high temperature condensate gases were proposed. The temperature prediction model is valid for both the critical and subcritical flows through different kinds of choke valves. The applications show the model is reliable for predicting the downstream temperatures of condensate gases with upstream pressures up to 85.54 MPa and temperatures up to 93.23 °C. The average absolute errors between the measured and calculated temperatures are expected for less than 2 °C by using the model.

  14. High-Temperature-High-Volume Lifting for Enhanced Geothermal Systems

    Energy Technology Data Exchange (ETDEWEB)

    Turnquist, Norman [GE Global Research, Munchen (Germany); Qi, Xuele [GE Global Research, Munchen (Germany); Raminosoa, Tsarafidy [GE Global Research, Munchen (Germany); Salas, Ken [GE Global Research, Munchen (Germany); Samudrala, Omprakash [GE Global Research, Munchen (Germany); Shah, Manoj [GE Global Research, Munchen (Germany); Van Dam, Jeremy [GE Global Research, Munchen (Germany); Yin, Weijun [GE Global Research, Munchen (Germany); Zia, Jalal [GE Global Research, Munchen (Germany)

    2013-12-20

    This report summarizes the progress made during the April 01, 2010 – December 30, 2013 period under Cooperative Agreement DE-EE0002752 for the U.S. Department of Energy entitled “High-Temperature-High-Volume Lifting for Enhanced Geothermal Systems.” The overall objective of this program is to advance the technology for well fluids lifting systems to meet the foreseeable pressure, temperature, and longevity needs of the Enhanced Geothermal Systems (EGS) industry for the coming ten years. In this program, lifting system requirements for EGS wells were established via consultation with industry experts and site visits. A number of artificial lift technologies were evaluated with regard to their applicability to EGS applications; it was determined that a system based on electric submersible pump (ESP) technology was best suited to EGS. Technical barriers were identified and a component-level technology development program was undertaken to address each barrier, with the most challenging being the development of a power-dense, small diameter motor that can operate reliably in a 300°C environment for up to three years. Some of the targeted individual component technologies include permanent magnet motor construction, high-temperature insulation, dielectrics, bearings, seals, thrust washers, and pump impellers/diffusers. Advances were also made in thermal management of electric motors. In addition to the overall system design for a full-scale EGS application, a subscale prototype was designed and fabricated. Like the full-scale design, the subscale prototype features a novel “flow-through-the-bore” permanent magnet electric motor that combines the use of high temperature materials with an internal cooling scheme that limits peak internal temperatures to <330°C. While the full-scale high-volume multi-stage pump is designed to lift up to 80 kg/s of process water, the subscale prototype is based on a production design that can pump 20 kg/s and has been modified

  15. Diamond based detectors for high temperature, high radiation environments

    Science.gov (United States)

    Metcalfe, A.; Fern, G. R.; Hobson, P. R.; Smith, D. R.; Lefeuvre, G.; Saenger, R.

    2017-01-01

    Single crystal CVD diamond has many desirable properties as a radiation detector; exceptional radiation hardness and physical hardness, chemical inertness, low Z (close to human tissue, good for dosimetry and transmission mode applications), wide bandgap (high temperature operation with low noise and solar blind), an intrinsic pathway to fast neutron detection through the 12C(n,α)9Be reaction. This combination of radiation hardness, temperature tolerance and ability to detect mixed radiation types with a single sensor makes diamond particularly attractive as a detector material for harsh environments such as nuclear power station monitoring (fission and fusion) and oil well logging. Effective exploitation of these properties requires the development of a metallisation scheme to give contacts that remain stable over extended periods at elevated temperatures (up to 250°C in this instance). Due to the cost of the primary detector material, computational modelling is essential to best utilise the available processing methods for optimising sensor response through geometry and conversion media configurations and to fully interpret experimental data. Monte Carlo simulations of our diamond based sensor have been developed, using MCNP6 and FLUKA2011, assessing the sensor performance in terms of spectral response and overall efficiency as a function of the detector and converter geometry. Sensors with varying metallisation schemes for high temperature operation have been fabricated at Brunel University London and by Micron Semiconductor Limited. These sensors have been tested under a varied set of conditions including irradiation with fast neutrons and alpha particles at high temperatures. The presented study indicates that viable metallisation schemes for high temperature contacts have been successfully developed and the modelling results, supported by preliminary experimental data from partners, indicate that the simulations provide a reasonable representation of

  16. Modeling Study of High Pressure and High Temperature Reservoir Fluids

    DEFF Research Database (Denmark)

    Varzandeh, Farhad

    With dwindling easily accessible oil and gas resources, more and more exploration and production activities in the oil industry are driven to technically challenging environments such as unconventional resources and deeper formations. The temperature and pressure can become extremely high, e.g., up...

  17. Assessment of high-temperature filtering elements

    Energy Technology Data Exchange (ETDEWEB)

    Monica Lupion; Francisco J. Gutierrez Ortiz; Benito Navarrete; Vicente J. Cortes [University of Seville, Seville (Spain). E.T.S. Ingenieros

    2008-07-01

    A complete experimental campaign has been carried out in a hot gas filtration test facility so as to test several filtering elements and configurations, particularly, three different types of bag filters and one ceramic candle. The facility was designed to operate under a wide range of conditions, thus providing an excellent tool for the investigation of hot gas filtration applications for the advanced electrical power generation industry such as IGCC, PFBC or fuel cell technologies. Relevant parameters for the characterization and optimization of the performance of the filters have been studied for a variety of operation conditions such as filtration velocity, particle concentration, pressure and temperature among others. Pressure drop across the filter, cleaning pulse interval, baseline pressure drop, filtration efficiency and durability of the filter have been investigated for each type considered and dependences on parameters have been established. On top of that, optimal operating conditions and cleaning strategies were determined. The tests results show that bag filters are a suitable alternative for the hot gas filtration due to the better performance and the high efficiency observed, which makes them suitable for industrial applications operating under high temperature high pressure conditions considered within the study (200-370{degree}C and 4-7.5 barg respectively). 7 refs., 7 figs., 10 tabs.

  18. High-temperature superconductors make major progress

    CERN Multimedia

    CERN Bulletin

    2014-01-01

    This month's Nature Materials featured an important breakthrough for high-temperature superconductors. A new method has been found for processing Bi-2212 high-temperature superconducting round wire in order to drastically increase its critical current density. The result confirms that this conductor is a serious candidate for future very-high-field magnets.   This image shows the cross-section of two Bi-2212 wires. The bottom wire has less leakage and void porosity due to a heat treatment done at an overpressure of 100 bar - about 100 times the pressure used to produce the top wire (image from [Nature Materials, Vol. 13 (2014), 10.1038/nmat3887]). The workhorse for building superconducting accelerator magnets has been, so far, the Niobium-Titanium (Nb-Ti) alloy superconductor. But with Nb-Ti having reached its full potential, other conductors must be used to operate in higher magnetic fields beyond those reached with the LHC magnets. Today, the intermetallic Niobium-Tin (Nb3Sn) is th...

  19. Pulse Radiolysis at High Temperatures and High Pressures

    DEFF Research Database (Denmark)

    Christensen, H.; Sehested, Knud

    1981-01-01

    A set-up enabling pulse radiolysis measurements at high temperatures (up to 320°C) and high pressures (up to 140 bar) has been constructed in collaboration between Risö National Laboratory and Studsvik Energiteknik. The cell has been used for experiments with aqueous solutions with the purpose.......2 kcal.mol−1) and OH+OH (tentatively 8 kJ·mol−1, 1.9 kcal·mol−1) have been determined. The absorption spectrum of the OH radical has been determined up to temperatures of 200°C. The absorption maximum is found at 230 nm at all temperatures. The reaction between Fe2+ and OH radicals has been studied up...... to a temperature of 220°C. An activation energy of 9 kJ·mol−1 (2.2 kcal·mol−1) has been determined and the spectrum of the transient formed in the reaction has been determined at different temperatures....

  20. High temperature behaviour of a zircon ceramic

    Energy Technology Data Exchange (ETDEWEB)

    Carbonneau, X.; Olagnon, C.; Fantozzi, G. [INSA, Villeurbanne (France). GEMMPM; Hamidouche, M. [Lab. Science des Materiaux, Univ. de Setif (Algeria); Torrecillas, R. [Inst. Nacional del Carbon, Oviedo (Spain)

    1997-12-31

    The high temperature properties of a sintered zircon material has been tested up to 1200 C. A significant creep rate is observed, mainly attributed to the presence of glassy phase. The sub-critical crack growth measured in double torsion showed that above 1000 C, the crack velocity is reduced either by stress relaxation or by crack healing. The thermal shock analysis under a heat exchange coefficient of 600 W/m{sup 2}/K showed a regular decrease rather that a sudden fall off of properties. (orig.) 3 refs.

  1. Encapsulation of high temperature molten salts

    Energy Technology Data Exchange (ETDEWEB)

    Oxley, James D.; Mathur, Anoop Kumar

    2017-05-16

    The present disclosure relates to a method of encapsulating microcapsules containing relatively high temperature phase change materials and the microcapsules so produced. The microcapsules are coated with an inorganic binder, film former and an inorganic filler. The microcapsules may include a sacrificial layer that is disposed between the particle and the coating. The microcapsules may also include an inner coating layer, sacrificial layer and outer coating layer. The microcapsules are particularly useful for thermal energy storage in connection with, e.g., heat collected from concentrating solar collectors.

  2. High Temperature Materials Laboratory third annual report

    Energy Technology Data Exchange (ETDEWEB)

    Tennery, V.J.; Foust, F.M.

    1990-12-01

    The High Temperature Materials Laboratory has completed its third year of operation as a designated DOE User Facility at the Oak Ridge National Laboratory. Growth of the user program is evidenced by the number of outside institutions who have executed user agreements since the facility began operation in 1987. A total of 88 nonproprietary agreements (40 university and 48 industry) and 20 proprietary agreements (1 university, 19 industry) are now in effect. Sixty-eight nonproprietary research proposals (39 from university, 28 from industry, and 1 other government facility) and 8 proprietary proposals were considered during this reporting period. Research projects active in FY 1990 are summarized.

  3. High point for CERN and high-temperature superconductors

    CERN Multimedia

    2007-01-01

    Amalia Ballarino is named the Superconductor Industry Person of the year 2006. Amalia Ballarino showing a tape of high-superconducting material used for the LHC current leads.The CERN project leader for the high-temperature superconducting current leads for the LHC, Amalia Ballarino, has received the award for "Superconductor Industry Person of the Year". This award, the most prestigious international award in the development and commercialization of superconductors, is presented by the leading industry newsletter "Superconductor Week". Amalia Ballarino was selected from dozens of nominations from around the world by a panel of recognized leading experts in superconductivity. "It is a great honour for me," says Amalia Ballarino. "It has been many years of hard work, and it’s a great satisfaction to see that the work has been completed successfully." Amalia Ballarino has been working on high-temperature superconducting materials sin...

  4. High temperature deformation of 6061 Al

    Energy Technology Data Exchange (ETDEWEB)

    Kyungtae Park; Lavernia, E.J.; Mohamed, F.A. (Univ. of California, Irvine (United States). Dept. of Mechanical and Aerospace Engineering)

    1994-03-01

    The creep behavior of powder metallurgy (PM) 6061 Al, which has been used as a metal matrix alloy in the development of discontinuous silicon carbide reinforced aluminum (SiC-Al) composites, has been studied over six orders of magnitude of strain rate. The experimental data show that the steady-state stage of the creep curve is of short duration; that the stress dependence of creep rate is high and variable; and that the temperature dependence of creep rate is much higher than that for self-diffusion in aluminum. The above creep characteristics are different from those documented for aluminum based solid-solution alloys but are similar to those reported for discontinuous SiC-Al composites and dispersion-strengthened (DS) alloys. Analysis of the experimental data shows that while the high stress dependence of creep rate in 6061 Al, like that in DS alloys, can be explained in terms of a threshold stress for creep, the strong temperature dependence of creep rate in the alloy is incompatible with the predictions of available threshold stress models and theoretical treatments proposed for DS alloys.

  5. Development of High Temperature Gas Sensor Technology

    Science.gov (United States)

    Hunter, Gary W.; Chen, Liang-Yu; Neudeck, Philip G.; Knight, Dak; Liu, Chung-Chiun; Wu, Quing-Hai; Zhou, Huan-Jun

    1997-01-01

    The measurement of engine emissions is important for their monitoring and control. However, the ability to measure these emissions in-situ is limited. We are developing a family of high temperature gas sensors which are intended to operate in harsh environments such as those in an engine. The development of these sensors is based on progress in two types of technology: (1) The development of SiC-based semiconductor technology; and (2) Improvements in micromachining and microfabrication technology. These technologies are being used to develop point-contact sensors to measure gases which are important in emission control especially hydrogen, hydrocarbons, nitrogen oxides, and oxygen. The purpose of this paper is to discuss the development of this point-contact sensor technology. The detection of each type of gas involves its own challenges in the fields of materials science and fabrication technology. Of particular importance is sensor sensitivity, selectivity, and stability in long-term, high temperature operation. An overview is presented of each sensor type with an evaluation of its stage of development. It is concluded that this technology has significant potential for use in engine applications but further development is necessary.

  6. Hole-doped cuprate high temperature superconductors

    Energy Technology Data Exchange (ETDEWEB)

    Chu, C.W.; Deng, L.Z.; Lv, B.

    2015-07-15

    Highlights: • Historical discoveries of hole-doped cuprates and representative milestone work. • Several simple and universal scaling laws of the hole-doped cuprates. • A comprehensive classification list with references for hole-doped cuprates. • Representative physical parameters for selected hole-doped cuprates. - Abstract: Hole-doped cuprate high temperature superconductors have ushered in the modern era of high temperature superconductivity (HTS) and have continued to be at center stage in the field. Extensive studies have been made, many compounds discovered, voluminous data compiled, numerous models proposed, many review articles written, and various prototype devices made and tested with better performance than their nonsuperconducting counterparts. The field is indeed vast. We have therefore decided to focus on the major cuprate materials systems that have laid the foundation of HTS science and technology and present several simple scaling laws that show the systematic and universal simplicity amid the complexity of these material systems, while referring readers interested in the HTS physics and devices to the review articles. Developments in the field are mostly presented in chronological order, sometimes with anecdotes, in an attempt to share some of the moments of excitement and despair in the history of HTS with readers, especially the younger ones.

  7. High-temperature ordered intermetallic alloys V

    Energy Technology Data Exchange (ETDEWEB)

    Baker, I. (ed.) (Dartmouth Coll., Hanover, NH (United States). Thayer School of Engineering); Darolia, R. (ed.) (GE Aircraft Engines, Cincinnati, OH (United States)); Whittenberger, J.D. (ed.) (NASA, Cleveland, OH (United States). Lewis Research Center); Yoo, M.H. (ed.) (Oak Ridge National Lab., TN (United States))

    1993-01-01

    These proceedings represent the written record of the High-Temperature Ordered Intermetallic Alloys 5 Symposium which was held in conjunction with the 1992 Fall Materials Research Society meeting in Boston, Massachusetts. This symposium, which was the fifth in the series originated by C.C Koch, C.T. Liu and N.S. Stoloff in 1984, was very successful with 86 oral presentations over four days, and approximately 140 posters given during two lively evening sessions. Such a response, in view of the increasing number of conferences being held on intermetallics each year, reveals the continued high regard for this series of symposia. Individual papers have been processed separately for inclusion in the appropriate data bases.

  8. Thermomechanics of composite structures under high temperatures

    CERN Document Server

    Dimitrienko, Yu I

    2016-01-01

    This pioneering book presents new models for the thermomechanical behavior of composite materials and structures taking into account internal physico-chemical transformations such as thermodecomposition, sublimation and melting at high temperatures (up to 3000 K). It is of great importance for the design of new thermostable materials and for the investigation of reliability and fire safety of composite structures. It also supports the investigation of interaction of composites with laser irradiation and the design of heat-shield systems. Structural methods are presented for calculating the effective mechanical and thermal properties of matrices, fibres and unidirectional, reinforced by dispersed particles and textile composites, in terms of properties of their constituent phases. Useful calculation methods are developed for characteristics such as the rate of thermomechanical erosion of composites under high-speed flow and the heat deformation of composites with account of chemical shrinkage. The author expan...

  9. Cast Aluminum Alloy for High Temperature Applications

    Science.gov (United States)

    Lee, Jonathan A.

    2003-01-01

    Originally developed by NASA as high performance piston alloys to meet U.S. automotive legislation requiring low exhaust emission, the novel NASA alloys now offer dramatic increase in tensile strength for many other applications at elevated temperatures from 450 F (232 C) to about 750 F (400 C). It is an ideal low cost material for cast automotive components such as pistons, cylinder heads, cylinder liners, connecting rods, turbo chargers, impellers, actuators, brake calipers and rotors. It can be very economically produced from conventional permanent mold, sand casting or investment casting, with silicon content ranging from 6% to 18%. At high silicon levels, the alloy exhibits excellent dimensional stability, surface hardness and wear resistant properties.

  10. Apparatus for accurately measuring high temperatures

    Science.gov (United States)

    Smith, D.D.

    The present invention is a thermometer used for measuring furnace temperatures in the range of about 1800/sup 0/ to 2700/sup 0/C. The thermometer comprises a broadband multicolor thermal radiation sensor positioned to be in optical alignment with the end of a blackbody sight tube extending into the furnace. A valve-shutter arrangement is positioned between the radiation sensor and the sight tube and a chamber for containing a charge of high pressure gas is positioned between the valve-shutter arrangement and the radiation sensor. A momentary opening of the valve shutter arrangement allows a pulse of the high gas to purge the sight tube of air-borne thermal radiation contaminants which permits the radiation sensor to accurately measure the thermal radiation emanating from the end of the sight tube.

  11. IAEA international studies on irradiation embrittlement of reactor pressure vessel steels

    Energy Technology Data Exchange (ETDEWEB)

    Brumovsky, M. [Nuclear Research Institute Rez plc (Czech Republic); Steele, L.E. [Chief Scientific Investigator of the Programme, Springfield, VA (United States)

    1997-02-01

    In last 25 years, three phases a Co-operative Research Programme on Irradiation Embrittlement of Reactor Pressure Vessel Steels has been organized by the International Atomic Energy Agency. This programme started with eight countries in 1971 and finally 16 countries took part in phase III of the Programme in 1983. Several main efforts were put into preparation of the programme, but the principal task was concentrated on an international comparison of radiation damage characterization by different laboratories for steels of {open_quotes}old{close_quotes} (with high impurity contents) and {open_quotes}advanced{close_quotes} (with low impurity contents) types as well as on development of small scale fracture mechanics procedures applicable to reactor pressure vessel surveillance programmes. This year, a new programme has been opened, concentrated mostly on small scale fracture mechanics testing.

  12. Study on the Hydrogen Embrittlement of Aermet100 Using Hydrogen Permeation and SSRT Techniques

    Science.gov (United States)

    Hu, Yabo; Dong, Chaofang; Luo, Hong; Xiao, Kui; Zhong, Ping; Li, Xiaogang

    2017-09-01

    Aermet100 steel suffers greatly from hydrogen embrittlement due to its ultra-high strength. During the corrosion process as part of its service life, reduction of H+ in an acidic environment and H2O in a deaerated near-neutral environment are the main sources of hydrogen generation. Hydrogen permeation into Aermet100 steel can occur even in the atmosphere. After tempering, the coherent precipitations can hinder diffusion of hydrogen in the tempered steel, causing the apparent hydrogen diffusivity and steady hydrogen permeation current to decrease. The fracture morphology of tempered Aermet100 steel after a slow strain rate test in an acidic solution is predominantly micro-void coalescence with few inner cracks. As the solution pH decreases, micro-cracks initiate not only on the side surface but also within the steel. Coalition of micro-cracks accelerates the overall cracking process.

  13. Effects of the Microstructure on Segregation behavior of Ni-Cr-Mo High Strength Low Alloy RPV Steel

    Energy Technology Data Exchange (ETDEWEB)

    Park, Sang Gyu; Wee, Dang Moon [Korea Advanced Institute of Science and Technology, Daejeon (Korea, Republic of); Kim, Min Chul; Lee, Bong Sang [Korea Atomic Energy Research Institute, Daejeon (Korea, Republic of)

    2010-10-15

    SA508 Gr.4N Ni-Cr-Mo low alloy steel has an improved fracture toughness and strength, compared to commercial Mn-Mo-Ni low alloy RPV steel SA508 Gr.3. Higher strength and fracture toughness of low alloy steels could be achieved by adding Ni and Cr. So there are several researches on SA508 Gr.4N low alloy steel for a RPV application. The operation temperature and time of a reactor pressure vessel is more than 300 .deg. C and over 40 years. Therefore, in order to apply the SA508 Gr.4N low alloy steel for a reactor pressure vessel, it requires a resistance of thermal embrittlement in the high temperature range including temper embrittlement resistance. S. Raoul reported that the susceptibility to temper embrittlement was increasing a function of the cooling rate in SA533 steel, which suggests the martensitic microstructures resulting from increased cooling rates are more susceptible to temper embrittlement. However, this result has not been proved yet. So the comparison of temper embrittlement behavior was made between martensitic microstructure and bainitic microstructure with a viewpoint of boundary features in SA508 Gr.4N, which have mixture of tempered bainite/martensite. In this study, we have compared temper embrittlement behaviors of SA508 Gr.4N low alloy steel with changing volume fraction of martensite. The mechanical properties of these low alloy steels) were evaluated after a long-term heat treatment(450 .deg. C, 2000hr. Then, the images of the segregated boundaries were observed and segregation behavior was analyzed by AES. In order to compare the misorientation distributions of model alloys, grain boundary structures were measured with EBSD

  14. Materials for High-Temperature Catalytic Combustion

    Energy Technology Data Exchange (ETDEWEB)

    Ersson, Anders

    2003-04-01

    Catalytic combustion is an environmentally friendly technique to combust fuels in e.g. gas turbines. Introducing a catalyst into the combustion chamber of a gas turbine allows combustion outside the normal flammability limits. Hence, the adiabatic flame temperature may be lowered below the threshold temperature for thermal NO{sub X} formation while maintaining a stable combustion. However, several challenges are connected to the application of catalytic combustion in gas turbines. The first part of this thesis reviews the use of catalytic combustion in gas turbines. The influence of the fuel has been studied and compared over different catalyst materials. The material section is divided into two parts. The first concerns bimetallic palladium catalysts. These catalysts showed a more stable activity compared to their pure palladium counterparts for methane combustion. This was verified both by using an annular reactor at ambient pressure and a pilot-scale reactor at elevated pressures and flows closely resembling the ones found in a gas turbine combustor. The second part concerns high-temperature materials, which may be used either as active or washcoat materials. A novel group of materials for catalysis, i.e. garnets, has been synthesised and tested in combustion of methane, a low-heating value gas and diesel fuel. The garnets showed some interesting abilities especially for combustion of low-heating value, LHV, gas. Two other materials were also studied, i.e. spinels and hexa aluminates, both showed very promising thermal stability and the substituted hexa aluminates also showed a good catalytic activity. Finally, deactivation of the catalyst materials was studied. In this part the sulphur poisoning of palladium, platinum and the above-mentioned complex metal oxides has been studied for combustion of a LHV gas. Platinum and surprisingly the garnet were least deactivated. Palladium was severely affected for methane combustion while the other washcoat materials were

  15. Ceramic membranes for high temperature hydrogen separation

    Energy Technology Data Exchange (ETDEWEB)

    Fain, D.E.; Roettger, G.E. [Oak Ridge K-25 Site, TN (United States)

    1996-08-01

    Ceramic gas separation membranes can provide very high separation factors if the pore size is sufficiently small to separate gas molecules by molecular sieving and if oversized pores are adequately limited. Ceramic membranes typically have some pores that are substantially larger than the mean pore size and that should be regarded as defects. To assess the effects of such defects on the performance of ceramic membranes, a simple mathematical model has been developed to describe flow through a gas separation membrane that has a primary mode of flow through very small pores but that has a secondary mode of flow through undesirably large pores. This model permits separation factors to be calculated for a specified gas pair as a function of the molecular weights and molecular diameters of the gases, the membrane pore diameter, and the diameter and number of defects. This model will be described, and key results from the model will be presented. The separation factors of the authors membranes continue to be determined using a permeance test system that measures flows of pure gases through a membrane at temperatures up to 275{degrees}C. A primary goal of this project for FY 1996 is to develop a mixed gas separation system for measuring the separation efficiency of membranes at higher temperatures. Performance criteria have been established for the planned mixed gas separation system and design of the system has been completed. The test system is designed to measure the separation efficiency of membranes at temperatures up to 600{degrees}C and pressures up to 100 psi by separating the constituents of a gas mixture containing hydrogen. The system will accommodate the authors typical experimental membrane that is tubular and has a diameter of about 9 mm and a length of about 23 cm. The design of the new test system and its expected performance will be discussed.

  16. Hydrogen embrittlement and stress corrosion cracking in metals

    Energy Technology Data Exchange (ETDEWEB)

    Kim, Young Suk; Cheong, Yong Mu; Im, Kyung Soo

    2004-10-15

    The objective of this report is to elucidate the mechanism for hydrogen embrittlement (HE) and stress corrosion cracking (SCC) in metals. To this end, we investigate the common features between delayed hydride cracking (DHC) in zirconium alloys and HE in metals with no precipitation of hydrides including Fe base alloys, Nickel base alloys, Cu alloys and Al alloys. Surprisingly, as with the crack growth pattern for the DHC in zirconium alloy, the metals mentioned above show a discontinuous crack growth, striation lines and a strong dependence of yield strength when exposed to hydrogen internally and externally. This study, for the first time, analyzes the driving force for the HE in metals in viewpoints of Kim's DHC model that a driving force for the DHC in zirconium alloys is a supersaturated hydrogen concentration coming from a hysteresis of the terminal solid solubility of hydrogen, not by the stress gradient, As with the crack growing only along the hydride habit plane during the DHC in zirconium alloys, the metals exposed to hydrogen seem to have the crack growing by invoking the dislocation slip along the preferential planes as a result of some interactions of the dislocations with hydrogen. Therefore, it seems that the hydrogen plays a role in inducing the slip only on the preferential planes so as to cause a strain localization at the crack tip. Sulfur in metals is detrimental in causing a intergranular cracking due to a segregation of the hydrogens at the grain boundaries. In contrast, boron in excess of 500 ppm added to the Ni3Al intermetallic compound is found to be beneficial in suppressing the HE even though further details of the mechanism for the roles of boron and sulfur are required. Carbon, carbides precipitating semi-continuously along the grain boundaries and the CSL (coherent site lattice) boundaries is found to suppress the intergranular stress corrosion cracking (IGSCC) in Alloy 600. The higher the volume fraction of twin boundaries, the

  17. High-temperature enzymatic breakdown of cellulose.

    Science.gov (United States)

    Wang, Hongliang; Squina, Fabio; Segato, Fernando; Mort, Andrew; Lee, David; Pappan, Kirk; Prade, Rolf

    2011-08-01

    Cellulose is an abundant and renewable biopolymer that can be used for biofuel generation; however, structural entrapment with other cell wall components hinders enzyme-substrate interactions, a key bottleneck for ethanol production. Biomass is routinely subjected to treatments that facilitate cellulase-cellulose contacts. Cellulases and glucosidases act by hydrolyzing glycosidic bonds of linear glucose β-1,4-linked polymers, producing glucose. Here we describe eight high-temperature-operating cellulases (TCel enzymes) identified from a survey of thermobacterial and archaeal genomes. Three TCel enzymes preferentially hydrolyzed soluble cellulose, while two preferred insoluble cellulose such as cotton linters and filter paper. TCel enzymes had temperature optima ranging from 85°C to 102°C. TCel enzymes were stable, retaining 80% of initial activity after 120 h at 85°C. Two modes of cellulose breakdown, i.e., with endo- and exo-acting glucanases, were detected, and with two-enzyme combinations at 85°C, synergistic cellulase activity was observed for some enzyme combinations.

  18. Effects of boundary characteristics on resistance to temper embrittlement and segregation behavior of Ni-Cr-Mo low alloy steel

    Energy Technology Data Exchange (ETDEWEB)

    Park, Sang-Gyu; Lee, Ki-Hyoung [Nuclear Materials Research Division, Korea Atomic Energy Research Institute, Daedeok-daero 989-111, Yuseong-gu, Daejeon 305-353 (Korea, Republic of); Kim, Min-Chul, E-mail: mckim@kaeri.re.kr [Nuclear Materials Research Division, Korea Atomic Energy Research Institute, Daedeok-daero 989-111, Yuseong-gu, Daejeon 305-353 (Korea, Republic of); Lee, Bong-Sang [Nuclear Materials Research Division, Korea Atomic Energy Research Institute, Daedeok-daero 989-111, Yuseong-gu, Daejeon 305-353 (Korea, Republic of)

    2013-01-20

    SA508 Gr.4N Ni-Cr-Mo low alloy steel has higher strength and fracture toughness than those of commercial SA508 Gr.3 low alloy steel, due to its tempered martensitic microstructure as well as the solid solution effect and its higher contents of Ni and Cr. Hence, several studies have been performed on SA508 Gr.4N for nuclear application. In this study, the effects of microstructure on temper embrittlement and segregation behaviors in Ni-Cr-Mo low alloy steel were evaluated from the viewpoint of grain boundary characteristics. To evaluate the microstructural effect while excluding chemistry effects, the same heat was used but different microstructure samples were prepared by changing the cooling rate after austenitization. The increased volume fraction of martensite reduces the resistance to temper embrittlement, showing an increased transition-temperature shift (TTS) and increased P segregation at prior austenite boundaries. The segregation occurred intensively at prior austenite grain boundaries in tempered martensite, while the segregation occurred simultaneously at both prior austenite boundaries and packet boundaries in tempered bainite. In the EBSD results, most of the packet boundaries in tempered martensite are special boundaries such as N-Ary-Summation 3 coincident site lattice (CSL) boundaries. The differences in P segregation between tempered martensite and tempered bainite are mainly caused by different portions of low energy special boundaries among the sub-grain boundaries. The reduction of temper embrittlement resistance in tempered martensite could be explained by the increased fraction of low energy CSL boundaries, which leads to a concentrated segregation of P at prior austenite grain boundaries.

  19. High temperature chemically resistant polymer concrete

    Science.gov (United States)

    Sugama, T.; Kukacka, L.E.

    High temperature chemically resistant, non-aqueous polymer concrete composites consist of about 12 to 20% by weight of a water-insoluble polymer binder. The binder is polymerized in situ from a liquid vinyl-type monomer or mixture of vinyl containing monomers such as triallylcyanurate, styrene, acrylonitrile, acrylamide, methacrylamide, methyl-methacrylate, trimethylolpropane trimethacrylate and divinyl benzene. About 5 to 40% by weight of a reactive inorganic filler selected from the group consisting of tricalcium silicate and dicalcium silicate and mixtures containing less than 2% free lime, and about 48 to 83% by weight of silica sand/ and a free radical initiator such as di-tert-butyl peroxide, azobisisobutyronitrile, benzoyl peroxide, lauryl peroxide, other orgaic peroxides and combinations to initiate polymerization of the monomer in the presence of the inorganic filers are used.

  20. Robust high temperature oxygen sensor electrodes

    DEFF Research Database (Denmark)

    Lund, Anders

    reaction kinetics. At oxygen partial pressures below 10-6 bar at 700 C, the mass transport processes dominated the response time. The response time increased with decreasing oxygen partial pressure and inlet gas flow rate. A series of porous platinum electrodes were impregnated with the ionically...... conducting gadolinium-doped cerium oxide (CGO). The addition of CGO was found to decrease the polarisation resistance of the oxygen reaction by up to an order of magnitude compared with a single phase platinum electrode by increasing the effective triple phase boundary (TPB) length. It did not have any......Platinum is the most widely used material in high temperature oxygen sensor electrodes. However, platinum is expensive and the platinum electrode may, under certain conditions, suffer from poisoning, which is detrimental for an oxygen sensor. The objective of this thesis is to evaluate electrode...

  1. Filter unit for use at high temperatures

    Science.gov (United States)

    Ciliberti, David F.; Lippert, Thomas E.

    1988-01-01

    A filtering unit for filtering particulates from high temperature gases uses a spiral ceramic spring to bias a ceramic, tubular filter element into sealing contact with a flange about an aperture of a metallic tube sheet. The ceramic spiral spring may contact the upper edge of the filter element and be restrained by a stop member spaced from one end of the tube sheet, or the spring may contact the bottom of the filter element and be restrained by a support member spaced from the opposite end of the tube sheet. The stop member and support member are adjustably secured to the tube sheet. A filtering system uses the ceramic spiral spring to bias a plurality of ceramic, tubular filter elements in a respective plurality of apertures in a tube sheet which divides a vessel into upper and lower enclosed sections.

  2. Toroidal high temperature superconducting coils for ISTTOK

    Energy Technology Data Exchange (ETDEWEB)

    Fernandes, H., E-mail: hf@ipfn.ist.utl.pt [Associacao Euratom/IST, Instituto de Plasmas e Fusao Nuclear, Laboratorio Associado, Instituto Superior Tecnico, 1049-001 Lisboa (Portugal); Goemoery, F. [Institute of Electrical Engineering, Slovak Academy of Sciences, Dubravska cesta 9, 84104 Bratislava (Slovakia); Corte, A. della; Celentano, G. [ENEA C.R. Frascati, Via E. Fermi 45, 00044 Frascati (Italy); Souc, J. [Institute of Electrical Engineering, Slovak Academy of Sciences, Dubravska cesta 9, 84104 Bratislava (Slovakia); Silva, C.; Carvalho, I.; Gomes, R. [Associacao Euratom/IST, Instituto de Plasmas e Fusao Nuclear, Laboratorio Associado, Instituto Superior Tecnico, 1049-001 Lisboa (Portugal); Di Zenobio, A.; Messina, G. [ENEA C.R. Frascati, Via E. Fermi 45, 00044 Frascati (Italy)

    2011-10-15

    High temperature superconductors (HTS) are very attractive to be used in fusion devices mainly due to lower operations costs. The HTS technology has reached a point where the construction of toroidal field coils for a tokamak is possible. The feasibility of a tokamak operating with HTS is extremely relevant and ISTTOK is the ideal candidate for a meaningful test due to its small size (and consequently lower cost) and the possibility to operate in a steady-state inductive regime. In this paper, a conceptual study of the ISTTOK upgrade to a superconducting device is presented, along with the relevant boundary conditions to achieve a permanent toroidal field with HTS. It is shown that the actual state of the art in HTS allows the design of a toroidal field coil capable of generating the appropriate field on plasma axis while respecting the structural specification of the machine.

  3. Iron-aluminum alloys having high room-temperature and method for making same

    Science.gov (United States)

    Sikka, V.K.; McKamey, C.G.

    1993-08-24

    A wrought and annealed iron-aluminum alloy is described consisting essentially of 8 to 9.5% aluminum, an effective amount of chromium sufficient to promote resistance to aqueous corrosion of the alloy, and an alloying constituent selected from the group of elements consisting of an effective amount of molybdenum sufficient to promote solution hardening of the alloy and resistance of the alloy to pitting when exposed to solutions containing chloride, up to about 0.05% carbon with up to about 0.5% of a carbide former which combines with the carbon to form carbides for controlling grain growth at elevated temperatures, and mixtures thereof, and the balance iron, wherein said alloy has a single disordered [alpha] phase crystal structure, is substantially non-susceptible to hydrogen embrittlement, and has a room-temperature ductility of greater than 20%.

  4. High temperature triaxial tests on Rochester shale

    Science.gov (United States)

    Bruijn, Rolf; Burlini, Luigi; Misra, Santanu

    2010-05-01

    Phyllosilicates are one of the major components of the crust, responsible for strength weakening during deformation. High pressure and temperature experiments of natural samples rich in phyllosilicates are needed to test the relevance of proposed weakening mechanisms induced by phyllosilicates, derived from lab experiments on single phase and synthetic polyphase rocks and single crystals. Here, we present the preliminary results of a series of high temperature triaxial tests performed on the illite-rich Rochester Shale (USA - New York) using a Paterson type gas-medium HPT testing machine. Cylindrical samples with homogeneous microstructure and 12-14% porosity were fabricated by cold and hot-isostatically pressing, hot-pressed samples were deformed up to a total shortening of 7.5 to 13%. To study the significance of mica dehydration, iron or copper jackets were used in combination with non-porous or porous spacers. Water content was measured before and after experiments using Karl Fischer Titration (KFT). All experiments show, after yielding at 0.6% strain, rapid hardening in nearly linear fashion until about 4-5% strain, from where stress increases at reducing rates to values at 10% strain, between 400 and 675 MPa, depending on experimental conditions. Neither failure nor steady state however, is achieved within the maximum strain of 13%. Experiments performed under 500 °C and 300 MPa confining pressure show weak strain rate dependence. In addition, iron-jacketed samples appear harder than copper-jacketed ones. At 700 °C samples are 17 to 37% weaker and more sensitive to strain rate than during 500 °C experiments. Although, iron-jacketed samples behave stronger than copper-jacketed ones. By visual inspection, samples appear homogeneously shortened. Preliminary analysis suggests that deformation is mostly accommodated by pore collapse. Although, with finite strain, pore collapse becomes less significant. A temperature, strain rate and jacket material dependent

  5. High Molecular Weight Polybenzimidazole Membranes for High Temperature PEMFC

    DEFF Research Database (Denmark)

    Yang, Jingshuai; Cleemann, Lars Nilausen; Steenberg, T.

    2014-01-01

    High temperature operation of proton exchange membrane fuel cells under ambient pressure has been achieved by using phosphoric acid doped polybenzimidazole (PBI) membranes. To optimize the membrane and fuel cells, high performance polymers were synthesized of molecular weights from 30 to 94 k......Da with good solubility in organic solvents. Membranes fabricated from the polymers were systematically characterized in terms of oxidative stability, acid doping and swelling, conductivity, mechanical strength and fuel cell performance and durability. With increased molecular weights the polymer membranes...

  6. Effects of irradiation at low temperature on V-4Cr-4Ti

    Energy Technology Data Exchange (ETDEWEB)

    Alexander, D.J.; Snead, L.L.; Zinkle, S.J. [Oak Ridge National Lab., TN (United States)] [and others

    1996-10-01

    Irradiation at low temperatures (100 to 275{degrees}C) to 0.5 dpa causes significant embrittlement and changes in the subsequent room temperature tensile properties of V-4Cr-4Ti. The yield strength and microhardness at room temperature increase with increasing irradiation temperature. The tensile flow properties at room temperature show large increases in strength and a complete loss of work hardening capacity with no uniform ductility. Embrittlement, as measured by an increase in the ductile-to-brittle transition temperature, increases with increasing irradiation temperature, at least up to 275{degrees}C. This embrittlement is not due to pickup of O or other interstitial solutes during the irradiation.

  7. HIGH TEMPERATURE HIGH PRESSURE THERMODYNAMIC MEASUREMENTS FOR COAL MODEL COMPOUNDS

    Energy Technology Data Exchange (ETDEWEB)

    Vinayak N. Kabadi

    2000-05-01

    The flow VLE apparatus designed and built for a previous project was upgraded and recalibrated for data measurements for this project. The modifications include better and more accurate sampling technique, addition of a digital recorder to monitor temperature and pressure inside the VLE cell, and a new technique for remote sensing of the liquid level in the cell. VLE data measurements for three binary systems, tetralin-quinoline, benzene--ethylbenzene and ethylbenzene--quinoline, have been completed. The temperature ranges of data measurements were 325 C to 370 C for the first system, 180 C to 300 C for the second system, and 225 C to 380 C for the third system. The smoothed data were found to be fairly well behaved when subjected to thermodynamic consistency tests. SETARAM C-80 calorimeter was used for incremental enthalpy and heat capacity measurements for benzene--ethylbenzene binary liquid mixtures. Data were measured from 30 C to 285 C for liquid mixtures covering the entire composition range. An apparatus has been designed for simultaneous measurement of excess volume and incremental enthalpy of liquid mixtures at temperatures from 30 C to 300 C. The apparatus has been tested and is ready for data measurements. A flow apparatus for measurement of heat of mixing of liquid mixtures at high temperatures has also been designed, and is currently being tested and calibrated.

  8. High Temperature Integrated Thermoelectric Ststem and Materials

    Energy Technology Data Exchange (ETDEWEB)

    Mike S. H. Chu

    2011-06-06

    The final goal of this project is to produce, by the end of Phase II, an all ceramic high temperature thermoelectric module. Such a module design integrates oxide ceramic n-type, oxide ceramic p-type materials as thermoelectric legs and oxide ceramic conductive material as metalizing connection between n-type and p-type legs. The benefits of this all ceramic module are that it can function at higher temperatures (> 700 C), it is mechanically and functionally more reliable and it can be scaled up to production at lower cost. With this all ceramic module, millions of dollars in savings or in new opportunities recovering waste heat from high temperature processes could be made available. A very attractive application will be to convert exhaust heat from a vehicle to reusable electric energy by a thermoelectric generator (TEG). Phase I activities were focused on evaluating potential n-type and p-type oxide compositions as the thermoelectric legs. More than 40 oxide ceramic powder compositions were made and studied in the laboratory. The compositions were divided into 6 groups representing different material systems. Basic ceramic properties and thermoelectric properties of discs sintered from these powders were measured. Powders with different particles sizes were made to evaluate the effects of particle size reduction on thermoelectric properties. Several powders were submitted to a leading thermoelectric company for complete thermoelectric evaluation. Initial evaluation showed that when samples were sintered by conventional method, they had reasonable values of Seebeck coefficient but very low values of electrical conductivity. Therefore, their power factors (PF) and figure of merits (ZT) were too low to be useful for high temperature thermoelectric applications. An unconventional sintering method, Spark Plasma Sintering (SPS) was determined to produce better thermoelectric properties. Particle size reduction of powders also was found to have some positive benefits

  9. Crystal Plasticity Model of Reactor Pressure Vessel Embrittlement in GRIZZLY

    Energy Technology Data Exchange (ETDEWEB)

    Chakraborty, Pritam [Idaho National Laboratory (INL), Idaho Falls, ID (United States); Biner, Suleyman Bulent [Idaho National Laboratory (INL), Idaho Falls, ID (United States); Zhang, Yongfeng [Idaho National Laboratory (INL), Idaho Falls, ID (United States); Spencer, Benjamin Whiting [Idaho National Laboratory (INL), Idaho Falls, ID (United States)

    2015-07-01

    The integrity of reactor pressure vessels (RPVs) is of utmost importance to ensure safe operation of nuclear reactors under extended lifetime. Microstructure-scale models at various length and time scales, coupled concurrently or through homogenization methods, can play a crucial role in understanding and quantifying irradiation-induced defect production, growth and their influence on mechanical behavior of RPV steels. A multi-scale approach, involving atomistic, meso- and engineering-scale models, is currently being pursued within the GRIZZLY project to understand and quantify irradiation-induced embrittlement of RPV steels. Within this framework, a dislocation-density based crystal plasticity model has been developed in GRIZZLY that captures the effect of irradiation-induced defects on the flow stress behavior and is presented in this report. The present formulation accounts for the interaction between self-interstitial loops and matrix dislocations. The model predictions have been validated with experiments and dislocation dynamics simulation.

  10. Lessons Learned From Developing Reactor Pressure Vessel Steel Embrittlement Database

    Energy Technology Data Exchange (ETDEWEB)

    Wang, Jy-An John [ORNL

    2010-08-01

    Materials behaviors caused by neutron irradiation under fission and/or fusion environments can be little understood without practical examination. Easily accessible material information system with large material database using effective computers is necessary for design of nuclear materials and analyses or simulations of the phenomena. The developed Embrittlement Data Base (EDB) at ORNL is this comprehensive collection of data. EDB database contains power reactor pressure vessel surveillance data, the material test reactor data, foreign reactor data (through bilateral agreements authorized by NRC), and the fracture toughness data. The lessons learned from building EDB program and the associated database management activity regarding Material Database Design Methodology, Architecture and the Embedded QA Protocol are described in this report. The development of IAEA International Database on Reactor Pressure Vessel Materials (IDRPVM) and the comparison of EDB database and IAEA IDRPVM database are provided in the report. The recommended database QA protocol and database infrastructure are also stated in the report.

  11. Fiber Optic Temperature Sensor Insert for High Temperature Environments

    Science.gov (United States)

    Black, Richard James (Inventor); Costa, Joannes M. (Inventor); Moslehi, Behzad (Inventor); Zarnescu, Livia (Inventor)

    2017-01-01

    A thermal protection system (TPS) test plug has optical fibers with FBGs embedded in the optical fiber arranged in a helix, an axial fiber, and a combination of the two. Optionally, one of the optical fibers is a sapphire FBG for measurement of the highest temperatures in the TPS plug. The test plug may include an ablating surface and a non-ablating surface, with an engagement surface with threads formed, the threads having a groove for placement of the optical fiber. The test plug may also include an optical connector positioned at the non-ablating surface for protection of the optical fiber during insertion and removal.

  12. Study Progress of Physiological Responses in High Temperature Environment

    Science.gov (United States)

    Li, K.; Zheng, G. Z.; Bu, W. T.; Wang, Y. J.; Lu, Y. Z.

    2017-10-01

    Certain workers are exposed to high temperatures for a long time. Heat stress will result in a series of physiological responses, and cause adverse effects on the health and safety of workers. This paper summarizes the physiological changes of cardiovascular system, core temperature, skin temperature, water-electrolyte metabolism, alimentary system, neuroendocrine system, reaction time and thermal fatigue in high temperature environments. It can provide a theoretical guidance for labor safety in high temperature environment.

  13. High Temperature High Pressure Thermodynamic Measurements for Coal Model Compounds

    Energy Technology Data Exchange (ETDEWEB)

    John C. Chen; Vinayak N. Kabadi

    1998-11-12

    The overall objective of this project is to develop a better thermodynamic model for predicting properties of high-boiling coal derived liquids, especially the phase equilibria of different fractions at elevated temperatures and pressures. The development of such a model requires data on vapor-liquid equilibria (VLE), enthalpy, and heat capacity which would be experimentally determined for binary systems of coal model compounds and compiled into a database. The data will be used to refine existing models such as UNIQUAC and UNIFAC. The flow VLE apparatus designed and built for a previous project was upgraded and recalibrated for data measurements for thk project. The modifications include better and more accurate sampling technique and addition of a digital recorder to monitor temperature, pressure and liquid level inside the VLE cell. VLE data measurements for system benzene-ethylbenzene have been completed. The vapor and liquid samples were analysed using the Perkin-Elmer Autosystem gas chromatography.

  14. Rapid sulfur capture studies at high temperatures

    Energy Technology Data Exchange (ETDEWEB)

    Richards, G.A.; Lawson, W.F.; Maloney, D.J.; Shaw, D.W.

    1990-12-01

    Determine conditions that would reproduce optimum sulfur capture ( super-equilibrium'') behavior. No attempt was made to extract kinetic data for calcination or sulfur capture, as might be done in a comprehensive study of sorbent behavior. While some interesting anomalies are present in the calcination data and in the limited surface area data, no attempt was made to pursue those issues. Since little sulfur capture was observed at operating conditions where super-equilibrium'' might be expected to occur, tests were stopped when the wide range of parameters that were studied failed to produce significant sulfur capture via the super-equilibrium mechanism. Considerable space in this report is devoted to a description of the experiment, including details of the GTRC construction. This description is included because we have received requests for a detailed description of the GTRC itself, as well as the pressurized dry powder feed system. In addition, many questions about accurately sampling the sulfur species from a high-temperature, high-pressure reactor were raised during the course of this investigation. A full account of the development of the gas and particulate sampling train in thus provided. 8 refs., 17 figs., 2 tabs.

  15. High temperature superconductors in electromagnetic applications

    CERN Document Server

    Richens, P E

    2000-01-01

    powder-in-tube and dip-coated, have been made using a novel single loop tensometer that enables the insertion of a reasonably long length of conductor into the bore of a high-field magnet. The design, construction, and characterization of a High Temperature Superconducting (HTS) magnet is described. The design stage has involved the development of computer software for the calculation of the critical current of a solenoid wound from anisotropic HTS conductor. This calculation can be performed for a variety of problems including those involving magnetic materials such as iron by the incorporation of finite element electromagnetic analysis software. This has enabled the optimization of the magnet's performance. The HTS magnet is wound from 190 m of silver-matrix Bi sub 2 Sr sub 2 Ca sub 2 Cu sub 3 O sub 1 sub 0 powder-in-tube tape conductor supplied by Intermagnetics General Corporation. The dimensions are 70 mm bore and 70 mm length, and it consists of 728 turns. Iron end-plates were utilized in order to reduc...

  16. High temperature superconductors at optimal doping

    Directory of Open Access Journals (Sweden)

    W. E. Pickett

    2006-09-01

    Full Text Available   Intensive study of the high temperature superconductors has been ongoing for two decades. A great deal of this effort has been devoted to the underdoped regime, where the new and difficult physics of the doped Mott insulator has met extra complications including bilayer coupling/splitting, shadow bands, and hot spots. While these complications continue to unfold, in this short overview the focus is moved to the region of actual high-Tc, that of optimal doping. The focus here also is not on the superconducting state itself, but primarily on the characteristics of the normal state from which the superconducting instability arises, and even these can be given only a broad-brush description. A reminder is given of two issues,(i why the “optimal Tc” varies,for n-layered systems it increases for n up to 3, then decreases for a given n, Tc increases according to the ‘basis’ atom in the order Bi, Tl, Hg (ii how does pressure, or a particular uniaxial strain, increase Tc when the zero-strain system is already optimally doped?

  17. Assessment of microelectronics packaging for high temperature, high reliability applications

    Energy Technology Data Exchange (ETDEWEB)

    Uribe, F.

    1997-04-01

    This report details characterization and development activities in electronic packaging for high temperature applications. This project was conducted through a Department of Energy sponsored Cooperative Research and Development Agreement between Sandia National Laboratories and General Motors. Even though the target application of this collaborative effort is an automotive electronic throttle control system which would be located in the engine compartment, results of this work are directly applicable to Sandia`s national security mission. The component count associated with the throttle control dictates the use of high density packaging not offered by conventional surface mount. An enabling packaging technology was selected and thermal models defined which characterized the thermal and mechanical response of the throttle control module. These models were used to optimize thick film multichip module design, characterize the thermal signatures of the electronic components inside the module, and to determine the temperature field and resulting thermal stresses under conditions that may be encountered during the operational life of the throttle control module. Because the need to use unpackaged devices limits the level of testing that can be performed either at the wafer level or as individual dice, an approach to assure a high level of reliability of the unpackaged components was formulated. Component assembly and interconnect technologies were also evaluated and characterized for high temperature applications. Electrical, mechanical and chemical characterizations of enabling die and component attach technologies were performed. Additionally, studies were conducted to assess the performance and reliability of gold and aluminum wire bonding to thick film conductor inks. Kinetic models were developed and validated to estimate wire bond reliability.

  18. Comparison of the segregation behavior between tempered martensite and tempered bainite in Ni-Cr-Mo high strength low alloy RPV steel

    Energy Technology Data Exchange (ETDEWEB)

    Park, Sang Gyu; Kim, Min Chul; Kim, Hyung Jun; Lee, Bong Sang [Korea Atomic Energy Research Institute, Daejeon (Korea, Republic of)

    2012-05-15

    SA508 Gr.4N Ni-Cr-Mo low alloy steel has an superior fracture toughness and strength, compared to commercial Mn-Mo-Ni low alloy RPV steel SA508 Gr.3. Higher strength and fracture toughness of low alloy steels could be obtained by adding Ni and Cr. So several were performed on researches on SA508 Gr.4N low alloy steel for a RPV application. The operation temperature and term of a reactor pressure vessel is more than 300 .deg. C and over 40 years. Therefore, in order to apply the SA508 Gr.4N low alloy steel for a reactor pressure vessel, the resistance of thermal embrittlement in the high temperature range including temper embrittlement is required. S. Raoul reported that the susceptibility to temper embrittlement was increasing a function of the cooling rate in SA533 steel, which suggests the martensitic microstructures resulting from increased cooling rates are more susceptible to temper embrittlement. However, this result has not been proved yet. So the comparison of temper embrittlement behavior was made between martensitic microstructure and bainitic microstructure with a viewpoint of boundary features in SA508 Gr.4N, which have mixture of tempered bainite/martensite. We have compared temper embrittlement behaviors of SA508 Gr.4N low alloy steel with changing volume fraction of martensite. The mechanical properties of these low alloy steels were evaluated after a long-term heat treatment. Then, the the segregated boundaries were observed and segregation behavior was analyzed by AES. In order to compare the misorientation distributions of model alloys, grain boundary structures were measured with EBSD

  19. High pressure study of high-temperature superconductors

    Energy Technology Data Exchange (ETDEWEB)

    Souliou, Sofia-Michaela

    2014-09-29

    The current thesis studies experimentally the effect of high external pressure on high-T{sub c} superconductors. The structure and lattice dynamics of several members of the high-T{sub c} cuprate and Fe-based superconductors families were investigated by means of Raman spectroscopy and X-ray diffraction under well-controlled, hydrostatic high pressure and low temperature conditions. The lattice dynamics of the high-T{sub c} superconductor YBa{sub 2}Cu{sub 3}O{sub 6+x} have been investigated systematically by Raman spectroscopy as a function of doping (x = 0.95, 0.75, 0.60, 0.55, and 0.45) and external pressure. Under ambient pressure conditions, in addition to the Raman modes expected from group theory, we observe new Raman active phonons upon cooling the underdoped samples, at temperatures well above the superconducting transition temperature. The doping dependence and the onset temperatures of the new Raman features suggest that they are associated with the incommensurate charge density wave (CDW) state recently discovered in underdoped cuprates using synchrotron X-ray scattering techniques. Under high pressure conditions (from 2 to 12 GPa), our Raman measurements on highly ordered underdoped YBa{sub 2}Cu{sub 3}O{sub 6.55} samples do not show any of the new Raman phonons seen at ambient pressure. High pressure and low temperature Raman measurements have been performed on the underdoped superconductor YBa{sub 2}Cu{sub 4}O{sub 8}. A clear renormalization of some of the Raman phonons is seen below T{sub c} as a result of the changes in the phonon self-energy upon the opening of the superconducting gap, with the most prominent one being that of the B{sub 1g}-like buckling phonon mode. The amplitude of this renormalization strongly increases with pressure, resembling the effect of hole doping in YBa{sub 2}Cu{sub 3}O{sub 6+x}. At ∝ 10 GPa, the system undergoes a reversible pressure-induced structural phase transition to a non-centrosymmmetric structure (space group

  20. Analytic Models of High-Temperature Hohlraums

    Energy Technology Data Exchange (ETDEWEB)

    Stygar, W.A.; Olson, R.E.; Spielman, R.B.; Leeper, R.J.

    2000-11-29

    A unified set of high-temperature-hohlraum models has been developed. For a simple hohlraum, P{sub s} = [A{sub s}+(1{minus}{alpha}{sub W})A{sub W}+A{sub H}]{sigma}T{sub R}{sup 4} + (4V{sigma}/c)(dT{sub R}{sup r}/dt) where P{sub S} is the total power radiated by the source, A{sub s} is the source area, A{sub W} is the area of the cavity wall excluding the source and holes in the wall, A{sub H} is the area of the holes, {sigma} is the Stefan-Boltzmann constant, T{sub R} is the radiation brightness temperature, V is the hohlraum volume, and c is the speed of light. The wall albedo {alpha}{sub W} {triple_bond} (T{sub W}/T{sub R}){sup 4} where T{sub W} is the brightness temperature of area A{sub W}. The net power radiated by the source P{sub N} = P{sub S}-A{sub S}{sigma}T{sub R}{sup 4}, which suggests that for laser-driven hohlraums the conversion efficiency {eta}{sub CE} be defined as P{sub N}/P{sub LASER}. The characteristic time required to change T{sub R}{sup 4} in response to a change in P{sub N} is 4V/C[(l{minus}{alpha}{sub W})A{sub W}+A{sub H}]. Using this model, T{sub R}, {alpha}{sub W}, and {eta}{sub CE} can be expressed in terms of quantities directly measurable in a hohlraum experiment. For a steady-state hohlraum that encloses a convex capsule, P{sub N} = {l_brace}(1{minus}{alpha}{sub W})A{sub W}+A{sub H}+[(1{minus}{alpha}{sub C})(A{sub S}+A{sub W}{alpha}{sub W})A{sub C}/A{sub T}]{r_brace}{sigma}T{sub RC}{sup 4} where {alpha}{sub C} is the capsule albedo, A{sub C} is the capsule area, A{sub T} {triple_bond} (A{sub S}+A{sub W}+A{sub H}), and T{sub RC} is the brightness temperature of the radiation that drives the capsule. According to this relation, the capsule-coupling efficiency of the baseline National-Ignition-Facility (NIF) hohlraum is 15% higher than predicted by previous analytic expressions. A model of a hohlraum that encloses a z pinch is also presented.

  1. High Temperature Electrical Insulation Materials for Space Applications Project

    Data.gov (United States)

    National Aeronautics and Space Administration — NASA's future space science missions cannot be realized without the state of the art high temperature insulation materials of which higher working temperature, high...

  2. High Temperature Fatigue Life Evaluation Using Small Specimen

    National Research Council Canada - National Science Library

    NOGAMI, Shuhei; HISAKA, Chiaki; FUJIWARA, Masaharu; WAKAI, Eichi; HASEGAWA, Akira

    2017-01-01

    For developing the high temperature fatigue life evaluation method using small specimen, the effect of specimen size and test environment on the high temperature fatigue life of the reduced activation...

  3. Laser Brazing of High Temperature Braze Alloy

    Science.gov (United States)

    Gao, Y. P.; Seaman, R. F.; McQuillan, T. J.; Martiens, R. F.

    2000-01-01

    The Space Shuttle Main Engine (SSME) consists of 1080 conical tubes, which are furnace brazed themselves, manifolds, and surrounding structural jacket making almost four miles of braze joints. Subsequent furnace braze cycles are performed due to localized braze voids between the coolant tubes. SSME nozzle experiences extremely high heat flux (180 mW/sq m) during hot fire. Braze voids between coolant tubes may result in hot combustion gas escape causing jacket bulges. The nozzle can be disqualified for flight or result in mission failure if the braze voids exceed the limits. Localized braze processes were considered to eliminate braze voids, however, damage to the parent materials often prohibited use of such process. Being the only manned flight reusable rocket engine, it has stringent requirement on the braze process. Poor braze quality or damage to the parent materials limits the nozzle service life. The objective of this study was to develop a laser brazing process to provide quality, localized braze joints without adverse affect on the parent materials. Gold (Au-Cu-Ni-Pd-Mn) based high temperature braze alloys were used in both powder and wire form. Thin section iron base superalloy A286 tube was used as substrate materials. Different Laser Systems including CO2 (10.6 micrometers, 1kW), ND:YAG (1.06 micrometers, 4kW). and direct diode laser (808nm. 150W) were investigated for brazing process. The laser process variables including wavelength. laser power, travel speed and angle of inclination were optimized according to bead geometry and braze alloy wetting at minimum heat input level, The properties of laser brazing were compared to that of furnace brazing. Microhardness profiles were used for braze joint property comparison between laser and furnace brazing. The cooling rate of laser brazing was compared to furnace brazing based on secondary dendritic arm spacing, Both optical and Scanning Electron Microscope (SEM) were used to evaluate the microstructures of

  4. Measuring Specific Heats at High Temperatures

    Science.gov (United States)

    Vandersande, Jan W.; Zoltan, Andrew; Wood, Charles

    1987-01-01

    Flash apparatus for measuring thermal diffusivities at temperatures from 300 to 1,000 degrees C modified; measures specific heats of samples to accuracy of 4 to 5 percent. Specific heat and thermal diffusivity of sample measured. Xenon flash emits pulse of radiation, absorbed by sputtered graphite coating on sample. Sample temperature measured with thermocouple, and temperature rise due to pulse measured by InSb detector.

  5. Thermoelectric Powered High Temperature Wireless Sensing

    Science.gov (United States)

    Kucukkomurler, Ahmet

    This study describes use of a thermoelectric power converter to transform waste heat into electrical energy to power an RF receiver and transmitter, for use in harsh environment wireless temperature sensing and telemetry. The sensing and transmitting module employs a DS-1820 low power digital temperature sensor to perform temperature to voltage conversion, an ATX-34 RF transmitter, an ARX-34 RF receiver module, and a PIC16f84A microcontroller to synchronize data communication between them. The unit has been tested in a laboratory environment, and promising results have been obtained for an actual automotive wireless under hood temperature sensing and telemetry implementation.

  6. High-temperature archeointensity measurements from Mesopotamia

    Science.gov (United States)

    Gallet, Yves; Le Goff, Maxime

    2006-01-01

    We present new archeointensity results obtained from 127 potsherds and baked brick fragments dated from the last four millennia BC which were collected from different Syrian archeological excavations. High temperature magnetization measurements were carried out using a laboratory-built triaxial vibrating sample magnetometer (Triaxe), and ancient field intensity determinations were derived from the experimental procedure described by Le Goff and Gallet [Le Goff and Gallet. Earth Planet. Sci. Lett. 229 (2004) 31-43]. As some of the studied samples were previously analyzed using the classical Thellier and Thellier [Thellier and Thellier . Ann. Geophys. 15 (1959) 285-376] method revised by Coe [Coe. J. Geophys. Res. 72 (1967) 3247-3262], a comparison of the results is made from the two methods. The differences both at the fragment and site levels are mostly within ± 5%, which strengthens the validity of the experimental procedure developed for the Triaxe. The new data help to better constrain the geomagnetic field intensity variations in Mesopotamia during archeological times, with the probable occurrence of an archeomagnetic jerk around 2800-2600 BC.

  7. Electronic phase separation and high temperature superconductors

    Energy Technology Data Exchange (ETDEWEB)

    Kivelson, S.A. [Univ. of California, Los Angeles, CA (United States). Dept. of Physics; Emery, V.J. [Brookhaven National Lab., Upton, NY (United States)

    1994-01-11

    The authors review the extensive evidence from model calculations that neutral holes in an antiferromagnet separate into hole-rich and hole-poor phases. All known solvable limits of models of holes in a Heisenberg antiferromagnet exhibit this behavior. The authors show that when the phase separation is frustrated by the introduction of long-range Coulomb interactions, the typical consequence is either a modulated (charge density wave) state or a superconducting phase. The authors then review some of the strong experimental evidence supporting an electronically-driven phase separation of the holes in the cuprate superconductors and the related Ni oxides. Finally, the authors argue that frustrated phase separation in these materials can account for many of the anomalous normal state properties of the high temperature superconductors and provide the mechanism of superconductivity. In particular, it is shown that the T-linear resistivity of the normal state is a paraconductivity associated with a novel composite pairing, although the ordered superconducting state is more conventional.

  8. High-temperature spreading kinetics of metals

    Energy Technology Data Exchange (ETDEWEB)

    Rauch, N.

    2005-05-15

    In this PhD work a drop transfer setup combined with high speed photography has been used to analyze the spreading of Ag on polished polycrystalline Mo and single crystalline Mo (110) and (100) substrates. The objective of this work was to unveil the basic phenomena controlling spreading in metal-metal systems. The observed spreading kinetics were compared with current theories of low and high temperature spreading such as a molecular kinetic model and a fluid flow model. Analyses of the data reveal that the molecular model does describe the fastest velocity data well for all the investigated systems. Therefore, the energy which is dissipated during the spreading process is a dissipation at the triple line rather than dissipation due to the viscosity in the liquid. A comparison of the determined free activation energy for wetting of {delta}G95{approx}145kJ/mol with literature values allows the statement that the rate determining step seems to be a surface diffusion of the Ag atoms along the triple line. In order to investigate possible ridge formation, due to local atomic diffusion of atoms of the substrate at the triple during the spreading process, grooving experiments of the polycrystalline Mo were performed to calculate the surface diffusities that will control ridge evolution. The analyses of this work showed that a ridge formation at the fastest reported wetting velocities was not possible if there is no initial perturbation for a ridge. If there was an initial perturbation for a ridge the ridge had to be much smaller than 1 nm in order to be able to move with the liquid font. Therefore ridge formation does not influence the spreading kinetics for the studied system and the chosen conditions. SEM, AFM and TEM investigations of the triple line showed that ridge formation does also not occur at the end of the wetting experiment when the drop is close to equilibrium and the wetting velocity is slow. (orig.)

  9. High temperature impedance spectroscopy of barium stannate ...

    Indian Academy of Sciences (India)

    ... differential thermal analysis, thermogravimetric analysis and Fourier transform infrared techniques. Electrical properties were studied using a.c. impedance spectroscopy technique in the temperature range of 50–650 °C and frequency range of 10 Hz–13 MHz. The complex impedance plots at temperature ≥ 300 °C show ...

  10. High temperatures influence sexual development differentially in ...

    Indian Academy of Sciences (India)

    Samadhan Krushna Phuge

    2017-06-20

    Jun 20, 2017 ... temperatures on gonadal development, sex ratio and metamorphosis was studied in the Indian skipper frog, Euphlyctis ..... Table 1. Effect of rearing water temperature on gonadal differentiation and sex ratio of Euphlyctis cyanophlyctis .... tures (28, 30 and 32°C) induced female to male sex reversal.

  11. Problem aspects of high temperature referral metrology

    Science.gov (United States)

    Khodunkov, V. P.

    2017-11-01

    The main problematic aspects of the reproduction and transmission of a unit of temperature by a direct method are considered. The methodology and hardware for its implementation are considered. An estimate of the expected uncertainty in the measurement of the thermodynamic temperature is given.

  12. On the Stress Corrosion Cracking and Hydrogen Embrittlement Behavior of Austenitic Stainless Steels in Boiling Saturated Magnesium Chloride Solutions

    Directory of Open Access Journals (Sweden)

    Osama M. Alyousif

    2012-01-01

    Full Text Available The stress corrosion cracking (SCC and hydrogen embrittlement (HE behaviors for types 304, 310, and 316 austenitic stainless steels were investigated in boiling saturated magnesium chloride solutions using a constant load method under different conditions including test temperature, applied stress, and sensitization. Both of type 304 and type 316 stainless steels showed quite similar behavior characteristics, whereas type 310 stainless steel showed a different behavior. The time to failure (tf parameter was used among other parameters to characterize the materials behavior in the test solution and to develop a mathematical model for predicting the time to failure in the chloride solution. The combination of corrosion curve parameters and fracture surface micrographs gave some explanation for the cracking modes as well as an indication for the cracking mechanisms. On the basis of the results obtained, it was estimated that intergranular cracking was resulted from hydrogen embrittlement due to strain-induced formation of martensite along the grain boundaries, while transgranular cracking took place by propagating cracks nucleated at slip steps by dissolution.

  13. Development of a non-destructive testing technique using ultrasonic wave for evaluation of irradiation embrittlement in nuclear materials

    Science.gov (United States)

    Ishii, T.; Ooka, N.; Hoshiya, T.; Kobayashi, H.; Saito, J.; Niimi, M.; Tsuji, H.

    2002-12-01

    To develop a non-destructive testing technique for evaluating embrittlement of irradiated materials, the correlation between ultrasonic characteristics and embrittlement was investigated from the results of the ultrasonic wave measurement and the Charpy impact test of irradiated specimens of commercial A533B-1 steel and welded material at the hot laboratory of the Japan Materials Testing Reactor (JMTR) in the Japan Atomic Energy Research Institute (JAERI). After irradiation at 523 or 563 K up to a fast neutron fluence of 1×10 24 N/m 2 ( E>1 MeV), velocities of both shear and longitudinal waves in the irradiated specimen were lower than those in the unirradiated one. The decrease in the velocities may be caused by the reductions of the shear and Young's moduli in the irradiated specimen. The attenuation coefficient of the longitudinal wave in the irradiated specimens increased compared with unirradiated ones. With increasing the shift amount of the Charpy transition temperature at 41 J absorbed energy, the velocity and attenuation coefficient of the ultrasonic waves decreased and increased, respectively.

  14. HIGH TEMPERATURE HIGH PRESSURE THERMODYNAMIC MEASUREMENTS FOR COAL MODEL COMPOUNDS

    Energy Technology Data Exchange (ETDEWEB)

    Vinayak N. Kabadi

    2000-05-01

    The Vapor Liquid Equilibrium measurement setup of this work was first established several years ago. It is a flow type high temperature high pressure apparatus which was designed to operate below 500 C temperature and 2000 psia pressure. Compared with the static method, this method has three major advantages: the first is that large quantity of sample can be obtained from the system without disturbing the equilibrium state which was established before; the second is that the residence time of the sample in the equilibrium cell is greatly reduced, thus decomposition or contamination of the sample can be effectively prevented; the third is that the flow system allows the sample to degas as it heats up since any non condensable gas will exit in the vapor stream, accumulate in the vapor condenser, and not be recirculated. The first few runs were made with Quinoline-Tetralin system, the results were fairly in agreement with the literature data . The former graduate student Amad used the same apparatus acquired the Benzene-Ethylbenzene system VLE data. This work used basically the same setup (several modifications had been made) to get the VLE data of Ethylbenzene-Quinoline system.

  15. High performance internal reforming unit for high temperature fuel cells

    Science.gov (United States)

    Ma, Zhiwen [Sandy Hook, CT; Venkataraman, Ramakrishnan [New Milford, CT; Novacco, Lawrence J [Brookfield, CT

    2008-10-07

    A fuel reformer having an enclosure with first and second opposing surfaces, a sidewall connecting the first and second opposing surfaces and an inlet port and an outlet port in the sidewall. A plate assembly supporting a catalyst and baffles are also disposed in the enclosure. A main baffle extends into the enclosure from a point of the sidewall between the inlet and outlet ports. The main baffle cooperates with the enclosure and the plate assembly to establish a path for the flow of fuel gas through the reformer from the inlet port to the outlet port. At least a first directing baffle extends in the enclosure from one of the sidewall and the main baffle and cooperates with the plate assembly and the enclosure to alter the gas flow path. Desired graded catalyst loading pattern has been defined for optimized thermal management for the internal reforming high temperature fuel cells so as to achieve high cell performance.

  16. Vortices in high-performance high-temperature superconductors

    Science.gov (United States)

    Kwok, Wai-Kwong; Welp, Ulrich; Glatz, Andreas; Koshelev, Alexei E.; Kihlstrom, Karen J.; Crabtree, George W.

    2016-11-01

    The behavior of vortex matter in high-temperature superconductors (HTS) controls the entire electromagnetic response of the material, including its current carrying capacity. Here, we review the basic concepts of vortex pinning and its application to a complex mixed pinning landscape to enhance the critical current and to reduce its anisotropy. We focus on recent scientific advances that have resulted in large enhancements of the in-field critical current in state-of-the-art second generation (2G) YBCO coated conductors and on the prospect of an isotropic, high-critical current superconductor in the iron-based superconductors. Lastly, we discuss an emerging new paradigm of critical current by design—a drive to achieve a quantitative correlation between the observed critical current density and mesoscale mixed pinning landscapes by using realistic input parameters in an innovative and powerful large-scale time dependent Ginzburg-Landau approach to simulating vortex dynamics.

  17. Spectral emissivity of candidate alloys for very high temperature reactors in high temperature air environment

    Energy Technology Data Exchange (ETDEWEB)

    Cao, G., E-mail: gcao@wisc.edu; Weber, S.J.; Martin, S.O.; Sridharan, K.; Anderson, M.H.; Allen, T.R.

    2013-10-15

    Emissivity measurements for candidate alloys for very high temperature reactors were carried out in a custom-built experimental facility, capable of both efficient and reliable measurements of spectral emissivities of multiple samples at high temperatures. The alloys studied include 304 and 316 austenitic stainless steels, Alloy 617, and SA508 ferritic steel. The oxidation of alloys plays an important role in dictating emissivity values. The higher chromium content of 304 and 316 austenitic stainless steels, and Alloy 617 results in an oxide layer only of sub-micron thickness even at 700 °C and consequently the emissivity of these alloys remains low. In contrast, the low alloy SA508 ferritic steel which contains no chromium develops a thicker oxide layer, and consequently exhibits higher emissivity values.

  18. Spectral emissivity of candidate alloys for very high temperature reactors in high temperature air environment

    Science.gov (United States)

    Cao, G.; Weber, S. J.; Martin, S. O.; Sridharan, K.; Anderson, M. H.; Allen, T. R.

    2013-10-01

    Emissivity measurements for candidate alloys for very high temperature reactors were carried out in a custom-built experimental facility, capable of both efficient and reliable measurements of spectral emissivities of multiple samples at high temperatures. The alloys studied include 304 and 316 austenitic stainless steels, Alloy 617, and SA508 ferritic steel. The oxidation of alloys plays an important role in dictating emissivity values. The higher chromium content of 304 and 316 austenitic stainless steels, and Alloy 617 results in an oxide layer only of sub-micron thickness even at 700 °C and consequently the emissivity of these alloys remains low. In contrast, the low alloy SA508 ferritic steel which contains no chromium develops a thicker oxide layer, and consequently exhibits higher emissivity values.

  19. Ultra-High Temperature Distributed Wireless Sensors

    Energy Technology Data Exchange (ETDEWEB)

    May, Russell; Rumpf, Raymond; Coggin, John; Davis, Williams; Yang, Taeyoung; O' Donnell, Alan; Bresnahan, Peter

    2013-03-31

    Research was conducted towards the development of a passive wireless sensor for measurement of temperature in coal gasifiers and coal-fired boiler plants. Approaches investigated included metamaterial sensors based on guided mode resonance filters, and temperature-sensitive antennas that modulate the frequency of incident radio waves as they are re-radiated by the antenna. In the guided mode resonant filter metamaterial approach, temperature is encoded as changes in the sharpness of the filter response, which changes with temperature because the dielectric loss of the guided mode resonance filter is temperature-dependent. In the mechanically modulated antenna approach, the resonant frequency of a vibrating cantilever beam attached to the antenna changes with temperature. The vibration of the beam perturbs the electrical impedance of the antenna, so that incident radio waves are phase modulated at a frequency equal to the resonant frequency of the vibrating beam. Since the beam resonant frequency depends on temperature, a Doppler radar can be used to remotely measure the temperature of the antenna. Laboratory testing of the guided mode resonance filter failed to produce the spectral response predicted by simulations. It was concluded that the spectral response was dominated by spectral reflections of radio waves incident on the filter. Laboratory testing of the mechanically modulated antenna demonstrated that the device frequency shifted incident radio waves, and that the frequency of the re-radiated waves varied linearly with temperature. Radio wave propagation tests in the convection pass of a small research boiler plant identified a spectral window between 10 and 13 GHz for low loss propagation of radio waves in the interior of the boiler.

  20. Packaging Technology for SiC High Temperature Electronics

    Science.gov (United States)

    Chen, Liang-Yu; Neudeck, Philip G.; Spry, David J.; Meredith, Roger D.; Nakley, Leah M.; Beheim, Glenn M.; Hunter, Gary W.

    2017-01-01

    High-temperature environment operable sensors and electronics are required for long-term exploration of Venus and distributed control of next generation aeronautical engines. Various silicon carbide (SiC) high temperature sensors, actuators, and electronics have been demonstrated at and above 500 C. A compatible packaging system is essential for long-term testing and application of high temperature electronics and sensors in relevant environments. This talk will discuss a ceramic packaging system developed for high temperature electronics, and related testing results of SiC integrated circuits at 500 C facilitated by this high temperature packaging system, including the most recent progress.

  1. High temperature cement raw meal flowability

    DEFF Research Database (Denmark)

    Maarup, Claus; Hjuler, Klaus; Dam-Johansen, Kim

    2014-01-01

    The flowability of cement raw meal is investigated at temperatures up to 850°C in a specially designed monoaxial shear tester. Consolidation stresses of 0.94, 1.87 and 2.79kPa are applied. The results show that the flowability is reduced as temperature is increased above 550°C, indicated by incre......The flowability of cement raw meal is investigated at temperatures up to 850°C in a specially designed monoaxial shear tester. Consolidation stresses of 0.94, 1.87 and 2.79kPa are applied. The results show that the flowability is reduced as temperature is increased above 550°C, indicated...

  2. Extreme Environment High Temperature Communication Systems Project

    Data.gov (United States)

    National Aeronautics and Space Administration — The purpose of this project is to develop and demonstrate a communications system capable of operation at extreme temperatures and pressures in hostile and corrosive...

  3. High Temperature Characterization of Ceramic Pressure Sensors

    National Research Council Canada - National Science Library

    Fonseca, Michael A; English, Jennifer M; Von Arx, Martin; Allen, Mark G

    2001-01-01

    This work reports functional wireless ceramic micromachined pressure sensors operating at 450 C, with demonstrated materials and readout capability indicating potential extension to temperatures in excess of 600 C...

  4. High Temperature Acoustic Noise Reduction Materials Project

    Data.gov (United States)

    National Aeronautics and Space Administration — The proposed innovation is to use combustion synthesis techniques to manufacture ceramic-based acoustic liners capable of withstanding temperatures up to 2500?C....

  5. CAST-IRONS AT HIGH TEMPERATURES

    Directory of Open Access Journals (Sweden)

    A. N. Krutilin

    2008-01-01

    Full Text Available The results of investigations of physical-mechanical characteristics of cast iron slugs, received by semicontinuos way of casting, at temperatures from 850 up to 1100^ С are given. 

  6. NOvel Refractory Materials for High Alkali, High Temperature Environments

    Energy Technology Data Exchange (ETDEWEB)

    Hemrick, J.G.; Griffin, R. (MINTEQ International, Inc.)

    2011-08-30

    Refractory materials can be limited in their application by many factors including chemical reactions between the service environment and the refractory material, mechanical degradation of the refractory material by the service environment, temperature limitations on the use of a particular refractory material, and the inability to install or repair the refractory material in a cost effective manner or while the vessel was in service. The objective of this project was to address the need for new innovative refractory compositions by developing a family of novel MgO-Al2O3 spinel or other similar magnesia/alumina containing unshaped refractory composition (castables, gunnables, shotcretes, etc) utilizing new aggregate materials, bond systems, protective coatings, and phase formation techniques (in-situ phase formation, altered conversion temperatures, accelerated reactions, etc). This family of refractory compositions would then be tailored for use in high-temperature, highalkaline industrial environments like those found in the aluminum, chemical, forest products, glass, and steel industries. A research team was formed to carry out the proposed work led by Oak Ridge National Laboratory (ORNL) and was comprised of the academic institution Missouri University of Science and Technology (MS&T), and the industrial company MINTEQ International, Inc. (MINTEQ), along with representatives from the aluminum, chemical, glass, and forest products industries. The two goals of this project were to produce novel refractory compositions which will allow for improved energy efficiency and to develop new refractory application techniques which would improve the speed of installation. Also methods of hot installation were sought which would allow for hot repairs and on-line maintenance leading to reduced process downtimes and eliminating the need to cool and reheat process vessels.

  7. Multiscale Modeling of Hydrogen Embrittlement for Multiphase Material

    KAUST Repository

    Al-Jabr, Khalid A.

    2014-05-01

    Hydrogen Embrittlement (HE) is a very common failure mechanism induced crack propagation in materials that are utilized in oil and gas industry structural components and equipment. Considering the prediction of HE behavior, which is suggested in this study, is one technique of monitoring HE of equipment in service. Therefore, multi-scale constitutive models that account for the failure in polycrystalline Body Centered Cubic (BCC) materials due to hydrogen embrittlement are developed. The polycrystalline material is modeled as two-phase materials consisting of a grain interior (GI) phase and a grain boundary (GB) phase. In the first part of this work, the hydrogen concentration in the GI (Cgi) and the GB (Cgb) as well as the hydrogen distribution in each phase, were calculated and modeled by using kinetic regime-A and C, respectively. In the second part of this work, this dissertation captures the adverse effects of hydrogen concentration, in each phase, in micro/meso and macro-scale models on the mechanical behavior of steel; e.g. tensile strength and critical porosity. The models predict the damage mechanisms and the reduction in the ultimate strength profile of a notched, round bar under tension for different hydrogen concentrations as observed in the experimental data available in the literature for steels. Moreover, the study outcomes are supported by the experimental data of the Fractography and HE indices investigation. In addition to the aforementioned continuum model, this work employs the Molecular Dynamics (MD) simulations to provide information regarding bond formulation and breaking. The MD analyses are conducted for both single grain and polycrystalline BCC iron with different amounts of hydrogen and different size of nano-voids. The simulations show that the hydrogen atoms could form the transmission in materials configuration from BCC to FCC (Face Centered Cubic) and HCP (Hexagonal Close Packed). They also suggest the preferred sites of hydrogen for

  8. Design of High Field Solenoids made of High Temperature Superconductors

    Energy Technology Data Exchange (ETDEWEB)

    Bartalesi, Antonio; /Pisa U.

    2010-12-01

    This thesis starts from the analytical mechanical analysis of a superconducting solenoid, loaded by self generated Lorentz forces. Also, a finite element model is proposed and verified with the analytical results. To study the anisotropic behavior of a coil made by layers of superconductor and insulation, a finite element meso-mechanic model is proposed and designed. The resulting material properties are then used in the main solenoid analysis. In parallel, design work is performed as well: an existing Insert Test Facility (ITF) is adapted and structurally verified to support a coil made of YBa{sub 2}Cu{sub 3}O{sub 7}, a High Temperature Superconductor (HTS). Finally, a technological winding process was proposed and the required tooling is designed.

  9. Effect of microstructure on the high temperature strength of nitride ...

    Indian Academy of Sciences (India)

    The effect of these parameters on room temperature and high temperature strength of the composite up to 1300°C in ambient condition were studied. The high temperature flexural strength of the composite of all compositions increased at 1200 and 1300°C because of oxidation of Si3N4 phase and blunting crack front.

  10. 46 CFR 56.60-5 - Steel (High temperature applications).

    Science.gov (United States)

    2010-10-01

    ... 46 Shipping 2 2010-10-01 2010-10-01 false Steel (High temperature applications). 56.60-5 Section... SYSTEMS AND APPURTENANCES Materials § 56.60-5 Steel (High temperature applications). (a) (Reproduces 124.2.A.) Upon prolonged exposure to temperatures above 775 °F (412 °C), the carbide phase of plain carbon...

  11. The impact of high temperatures on foraging behaviour and body ...

    African Journals Online (AJOL)

    High temperatures can pose significant thermoregulation challenges for endotherms, and determining how individual species respond to high temperatures will be important for predicting the impact of global warming on wild populations. Animals can adjust their behaviour or physiology to cope with higher temperatures, ...

  12. Pargasite at high pressure and temperature

    Science.gov (United States)

    Comboni, Davide; Lotti, Paolo; Gatta, G. Diego; Merlini, Marco; Liermann, Hanns-Peter; Frost, Daniel J.

    2017-08-01

    The P-T phase stability field, the thermoelastic behavior and the P-induced deformation mechanisms at the atomic scale of pargasite crystals, from the "phlogopite peridotite unit" of the Finero mafic-ultramafic complex (Ivrea-Verbano Formation, Italy), have been investigated by a series of in situ experiments: (a) at high pressure (up to 20.1 GPa), by single-crystal synchrotron X-ray diffraction with a diamond anvil cell, (b) at high temperature (up to 823 K), by powder synchrotron X-ray diffraction using a hot air blower device, and (c) at simultaneous HP-HT conditions, by single-crystal synchrotron X-ray diffraction with a resistive-heated diamond anvil cell (P max = 16.5 GPa, T max = 1200 K). No phase transition has been observed within the P-T range investigated. At ambient T, the refined compressional parameters, calculated by fitting a second-order Birch-Murnaghan Equation of State (BM-EoS), are: V 0 = 915.2(8) Å3 and K P0,T0 = 95(2) GPa (β P0,T0 = 0.0121(2) GPa-1) for the unit-cell volume; a 0 = 9.909(4) Å and K(a) P0,T0 = 76(2) GPa for the a-axis; b 0 = 18.066(7) Å and K(b) P0,T0 = 111(2) GPa for the b-axis; c 0 = 5.299(5) Å and K(c) P0,T0 = 122(12) GPa for the c-axis [K(c) P0,T0 K(b) P0,T0 > K(a) P0,T0]. The high-pressure structure refinements (at ambient T) show a moderate contraction of the TO4 double chain and a decrease of its bending in response to the hydrostatic compression, along with a pronounced compressibility of the A- and M(4)-polyhedra [K P0, T0(A) = 38(2) GPa, K P0, T0(M4) = 79(5) GPa] if compared to the M(1)-, M(2)-, M(3)-octahedra [K P0, T0(M1,2,3) ≤ 120 GPa] and to the rigid tetrahedra [K P0, T0(T1,T2) 300 GPa]. The thermal behavior, at ambient pressure up to 823 K, was modelled with Berman's formalism, which gives: V 0 = 909.1(2) Å3, α0 = 2.7(2)·10-5 K-1 and α1 = 1.4(6)·10-9 K-2 [with α0(a) = 0.47(6)·10-5 K-1, α0(b) = 1.07(4)·10-5 K-1, and α0(c) = 0.97(7)·10-5 K-1]. The petrological implications for the experimental

  13. Development of High Strength Low Alloy Steel for Nuclear Reactor Vessel

    Energy Technology Data Exchange (ETDEWEB)

    Lee, B. S.; Kim, M. C.; Yoon, J. H; Choi, K. J.; Kim, J. M.; Hong, J. H.

    2013-11-15

    SA508 Gr. 4N Ni-Cr-Mo low alloy steel has an improved strength and fracture toughness, compared to commercial low alloy steels such as SA508 Gr. 3 Mn-Mo-Ni low alloy steel. In this study, the microstructural observation and baseline test were carried out using SA508 Gr. 4N model alloy of 1 ton scale. Thermal embrittlement and neutron irradiation embrittlement behaviors of SA508 Gr. 4N model alloy were also evaluated. The yield strength of 540MPa, Charpy transition temperature, T{sub 41J} of -132 .deg. C, Reference temperature, T{sub 0} of -146 .deg. C, and RT{sub NDT} of -105 .deg. C were obtained from large scale SA508 Gr. 3 low alloy steel. Effect of alloy elements on thermal embrittlement was carefully evaluated and embrittlement mechanism was characterized using small scale model alloys with various alloy composition. Neutron irradiation behavior at high fluence level up to 1.5x10{sup 20} n/cm{sup 2} corresponding over 80 years operation of RPV were investigated using irradiated samples from research reactor 'HANARO'. The irradiation embrittlement behavior of SA508 Gr. 4N model alloy was similar to that of commercial RPV steel. However, after neutron irradiation up to 1.3x10{sup 20} n/cm{sup 2}, SA508 Gr. 4N model alloy shows lower transition temperature(T{sub 41J} = -63 .deg. C) than unirradiated commercial RPV steel because it has a superior initial toughness.

  14. Transport Processes in High Temperature QCD Plasmas

    Science.gov (United States)

    Hong, Juhee

    The transport properties of high temperature QCD plasmas can be described by kinetic theory based on the Boltzmann equation. At a leading-log approximation, the Boltzmann equation is reformulated as a Fokker-Planck equation. First, we compute the spectral densities of Tµν and Jµ by perturbing the system with weak gravitational and electromagnetic fields. The spectral densities exhibit a smooth transition from free-streaming quasi-particles to hydrodynamics. This transition is analyzed with hydrodynamics and diffusion equation up to second order. We determine all of the first and second order transport coefficients which characterize the linear response in the hydrodynamic regime. Second, we simulate the wake of a heavy quark moving through the plasmas. At long distances, the energy density and flux distributions show sound waves and a diffusion wake. The kinetic theory calculations based on the Boltzmann equation at weak coupling are compared to the strong coupling results given by the AdS/CFT correspondence. By using the hard-thermal-loop effective theory, we determine the photon emission rate at next-to-leading order (NLO), i.e., at order g2mD /T. There are three mechanisms which contribute to the leading-order photon emission: (2 ↔ 2) elastic scatterings, (1 ↔ 2) collinear bremsstrahlung, and (1 ↔ 1) quark-photon conversion due to soft fermion exchange. At NLO, these three mechanisms are not completely independent. When the transverse momentum between quark and photon becomes soft, the Compton scattering with a soft gluon reduces to wide-angle bremsstrahlung. Similarly, bremsstrahlung reduces to the quark-photon conversion process when the photon carries most of the incoming momentum. Therefore, the rates should be matched to determine the wide-angle NLO correction. Collinear bremsstrahlung can be accounted for by solving an integral equation which corresponds to summing ladder diagrams. With O(g) corrections in the collision kernel and the asymptotic

  15. Magnesium Diecasting Alloys for High Temperature Applications

    Science.gov (United States)

    Pekguleryuz, Mihriban O.; Kaya, A. Arslan

    New growth area for automotive use of magnesium is powertrain applications such as the transmission case and engine block. These applications see service conditions in the temperature range of 150-200C under 50-70 MPa of tensile and compressive loads. In addition, metallurgical stability, fatigue resistance, corrosion resistance and castability requirements need to be met. A decade of research and development has resulted in a number of creep- resistant magnesium alloys that are potential candidates for elevated-temperature automotive applications. These alloys are mostly based on rare-earth and alkaline earth element additions to magnesium. This paper gives an overview of the various magnesium alloy systems for use in elevated-temperature applications.

  16. High Temperature and Pressure Alkaline Electrolysis

    DEFF Research Database (Denmark)

    Allebrod, Frank

    temperatures and pressures. Aqueous potassium hydroxide immobilized electrolyte in porous SrTiO3 was used in those cells. Electrolysis cells with metal foam based gas diffusion electrodes and the immobilized electrolyte were successfully demonstrated at temperatures up to 250 °C and 40 bar. Different electro-catalysts...... were tested in order to reduce the oxygen and hydrogen overpotentials. Current densities of 1.1 A cm-2 and 2.3 A cm-2 have been measured at a cell voltage of 1.5 V and 1.75 V, respectively, without using expensive noble metal catalysts. Electrical efficiencies of almost 99 % at 1.1 A cm-2 and 85 % at 2...... against conventional technologies for hydrogen production, such as natural gas reforming, the production and investment costs have to be reduced. A reduction of the investment costs may be achieved by increasing the operational pressure and temperature of the electrolyzer, as this will result in: 1...

  17. NOVEL REFRACTORY MATERIALS FOR HIGH ALKALI, HIGH TEMPERATURE ENVIRONMENTS

    Energy Technology Data Exchange (ETDEWEB)

    Hemrick, James Gordon [ORNL; Smith, Jeffrey D [ORNL; O' Hara, Kelley [University of Missouri, Rolla; Rodrigues-Schroer, Angela [Minteq International, Inc.; Colavito, [Minteq International, Inc.

    2012-08-01

    A project was led by Oak Ridge National Laboratory (ORNL) in collaboration with a research team comprised of the academic institution Missouri University of Science and Technology (MS&T), and the industrial company MINTEQ International, Inc. (MINTEQ), along with representatives from the aluminum, chemical, glass, and forest products industries. The project was to address the need for new innovative refractory compositions by developing a family of novel MgO-Al 2O3, MgAl2O4, or other similar spinel structured or alumina-based unshaped refractory compositions (castables, gunnables, shotcretes, etc.) utilizing new aggregate materials, bond systems, protective coatings, and phase formation techniques (in-situ phase formation, altered conversion temperatures, accelerated reactions, etc). This family of refractory compositions would then be tailored for use in high-temperature, high-alkaline industrial environments like those found in the aluminum, chemical, forest products, glass, and steel industries. Both practical refractory development experience and computer modeling techniques were used to aid in the design of this new family of materials. The newly developed materials were expected to offer alternative material choices for high-temperature, high-alkali environments that were capable of operating at higher temperatures (goal of increasing operating temperature by 100-200oC depending on process) or for longer periods of time (goal of twice the life span of current materials or next process determined service increment). This would lead to less process down time, greater energy efficiency for associated manufacturing processes (more heat kept in process), and materials that could be installed/repaired in a more efficient manner. The overall project goal was a 5% improvement in energy efficiency (brought about through a 20% improvement in thermal efficiency) resulting in a savings of 3.7 TBtu/yr (7.2 billion ft3 natural gas) by the year 2030. Additionally, new

  18. High incubation temperatures enhance mitochondrial energy metabolism in reptile embryos.

    Science.gov (United States)

    Sun, Bao-Jun; Li, Teng; Gao, Jing; Ma, Liang; Du, Wei-Guo

    2015-03-09

    Developmental rate increases exponentially with increasing temperature in ectothermic animals, but the biochemical basis underlying this thermal dependence is largely unexplored. We measured mitochondrial respiration and metabolic enzyme activities of turtle embryos (Pelodiscus sinensis) incubated at different temperatures to identify the metabolic basis of the rapid development occurring at high temperatures in reptile embryos. Developmental rate increased with increasing incubation temperatures in the embryos of P. sinensis. Correspondingly, in addition to the thermal dependence of mitochondrial respiration and metabolic enzyme activities, high-temperature incubation further enhanced mitochondrial respiration and COX activities in the embryos. This suggests that embryos may adjust mitochondrial respiration and metabolic enzyme activities in response to developmental temperature to achieve high developmental rates at high temperatures. Our study highlights the importance of biochemical investigations in understanding the proximate mechanisms by which temperature affects embryonic development.

  19. Comparison of Hydrogen Embrittlement Resistance between 2205 Duplex Stainless Steels and type 316L Austenitic Stainless Steels Under the Cathodic Applied Potential

    Energy Technology Data Exchange (ETDEWEB)

    Seo, Dong-Il; Lee, Jae-Bong [Kookmin University, Seoul (Korea, Republic of)

    2016-10-15

    2205 duplex stainless steels have been used for the construction of the marine environment, because of their excellent corrosion resistance and high strength. However, the resistance to hydrogen embrittlement (HE) may be less than that of 316L austenitic stainless steel. The reason why 316L stainless steels have better resistance to HE is associated with crystal structure (FCC, face centered cubic) and the higher stacking faults energy than 2205 duplex stainless steels. Furthermore 2205 stainless steels with or without tungsten were also examined in terms of HE. 2205 stainless steels containing tungsten is less resistible to HE. It is because dislocation tangle was formed in 2205 duplex stainless steels. Slow strain-rate tensile test (SSRT) was conducted to measure the resistance to HE under the cathodic applied potential. Hydrogen embrittlement index (HEI) was used to evaluate HE resistance through the quantitative calculation.

  20. High temperature superconductor cable concepts for fusion magnets

    CERN Document Server

    AUTHOR|(CDS)2078397

    2013-01-01

    Three concepts of high temperature superconductor cables carrying kA currents (RACC, CORC and TSTC) are investigated, optimized and evaluated in the scope of their applicability as conductor in fusion magnets. The magnetic field and temperature dependence of the cables is measured; the thermal expansion and conductivity of structure, insulation and filling materials are investigated. High temperature superconductor winding packs for fusion magnets are calculated and compared with corresponding low temperature superconductor cases.

  1. Maintenance in Service of High Temperature Parts

    Science.gov (United States)

    1982-01-01

    program activities. io4 6-1 DEFECTS AND THEIR EFFECT ON THE BEHAVIOUR OF GAS TIURBNE DISCS Robert H Jeal Head of Materials Engineering Rolls-Royce Limited...temperature sulphidatien and hot forrosal. m 5.• ACKNOWLEDGEMENT The author wishes to thank N. Swindells of the University of Livernool for his efforts in

  2. Micromechanics of high temperature hydrogen attack

    NARCIS (Netherlands)

    Schlögl, Sabine M.; Giessen, Erik van der

    1999-01-01

    Hydrogen attack is a material degradation process that occurs at elevated temperatures in hydrogen-rich environments, such as found in petro-chemical installations. Weldments in components such as reactor vessels are particularly susceptible to hydrogen attack. This paper discusses a multi-scale

  3. Improving the high performance concrete (HPC behaviour in high temperatures

    Directory of Open Access Journals (Sweden)

    Cattelan Antocheves De Lima, R.

    2003-12-01

    Full Text Available High performance concrete (HPC is an interesting material that has been long attracting the interest from the scientific and technical community, due to the clear advantages obtained in terms of mechanical strength and durability. Given these better characteristics, HFC, in its various forms, has been gradually replacing normal strength concrete, especially in structures exposed to severe environments. However, the veiy dense microstructure and low permeability typical of HPC can result in explosive spalling under certain thermal and mechanical conditions, such as when concrete is subject to rapid temperature rises, during a f¡re. This behaviour is caused by the build-up of internal water pressure, in the pore structure, during heating, and by stresses originating from thermal deformation gradients. Although there are still a limited number of experimental programs in this area, some researchers have reported that the addition of polypropylene fibers to HPC is a suitable way to avoid explosive spalling under f re conditions. This change in behavior is derived from the fact that polypropylene fibers melt in high temperatures and leave a pathway for heated gas to escape the concrete matrix, therefore allowing the outward migration of water vapor and resulting in the reduction of interned pore pressure. The present research investigates the behavior of high performance concrete on high temperatures, especially when polypropylene fibers are added to the mix.

    El hormigón de alta resistencia (HAR es un material de gran interés para la comunidad científica y técnica, debido a las claras ventajas obtenidas en término de resistencia mecánica y durabilidad. A causa de estas características, el HAR, en sus diversas formas, en algunas aplicaciones está reemplazando gradualmente al hormigón de resistencia normal, especialmente en estructuras expuestas a ambientes severos. Sin embargo, la microestructura muy densa y la baja permeabilidad t

  4. Ceramic membranes for high temperature hydrogen separation

    Energy Technology Data Exchange (ETDEWEB)

    Adcock, K.D.; Fain, D.E.; James, D.L.; Powell, L.E.; Raj, T.; Roettger, G.E.; Sutton, T.G. [East Tennessee Technology Park, Oak Ridge, TN (United States)

    1997-12-01

    The separative performance of the authors` ceramic membranes has been determined in the past using a permeance test system that measured flows of pure gases through a membrane at temperatures up to 275 C. From these data, the separation factor was determined for a particular gas pair from the ratio of the pure gas specific flows. An important project goal this year has been to build a Mixed Gas Separation System (MGSS) for measuring the separation efficiencies of membranes at higher temperatures and using mixed gases. The MGSS test system has been built, and initial operation has been achieved. The MGSS is capable of measuring the separation efficiency of membranes at temperatures up to 600 C and pressures up to 100 psi using a binary gas mixture such as hydrogen/methane. The mixed gas is fed into a tubular membrane at pressures up to 100 psi, and the membrane separates the feed gas mixture into a permeate stream and a raffinate stream. The test membrane is sealed in a stainless steel holder that is mounted in a split tube furnace to permit membrane separations to be evaluated at temperatures up to 600 C. The compositions of the three gas streams are measured by a gas chromatograph equipped with thermal conductivity detectors. The test system also measures the temperatures and pressures of all three gas streams as well as the flow rate of the feed stream. These data taken over a range of flows and pressures permit the separation efficiency to be determined as a function of the operating conditions. A mathematical model of the separation has been developed that permits the data to be reduced and the separation factor for the membrane to be determined.

  5. High temperature structural, polymeric foams from high internal emulsion polymerization

    Energy Technology Data Exchange (ETDEWEB)

    Hoisington, M.A.; Duke, J.R.; Apen, P.G.

    1996-02-01

    In 1982, a high internal phase emulsion (HIPE) polymerization process to manufacture microcellular, polymeric foam systems was patented by Unilever. This patent discloses a polymerization process that occurs in a water-in-oil emulsion in which the water represents at least 76% of the emulsion by volume. The oil phase consists of vinyl monomers such as styrene and acrylates that are crosslinked by divinyl monomers during polymerization. After polymerization and drying to remove the water phase, the result is a crosslinked polymer foam with an open cell microstructure that is homogeneous throughout in terms of morphology, density, and mechanical properties. Since 1982, numerous patents have examined various HIPE polymerized foam processing techniques and applications that include absorbents for body fluids, cleaning materials, and ion exchange systems. All the published HIPE polymerized foams have concentrated on materials for low temperature applications. Copolymerization of styrene with maleic anhydride and N-substituted maleimides to produce heat resistant thermoplastics has been studied extensively. These investigations have shown that styrene will free radically copolymerize with N-substituted maleimides to create an alternating thermoplastic copolymer with a Tg of approximately 200{degrees}C. However, there are many difficulties in attempting the maleimide styrene copolymerization in a HIPE such as lower polymerization temperatures, maleimide solubility difficulties in both styrene and water, and difficulty obtaining a stable HIPE with a styrene/maleimide oil phase. This work describes the preparation of copolymer foams from N-ethylmaleimide and Bis(3-ethyl-5-methyl-4-maleimide-phenyl)methane with styrene based monomers and crosslinking agents.

  6. Effect of Strain-Induced Martensite on Tensile Properties and Hydrogen Embrittlement of 304 Stainless Steel

    Science.gov (United States)

    Kim, Young Suk; Bak, Sang Hwan; Kim, Sung Soo

    2016-01-01

    Room temperature tensile tests have been conducted at different strain rates ranging from 2 × 10-6 to 1 × 10-2/s on hydrogen-free and hydrogen-charged 304 stainless steel (SS). Using a ferritescope and neutron diffraction, the amount of strain-induced martensite (SIM) has been in situ measured at the center region of the gage section of the tensile specimens or ex situ measured on the fractured tensile specimens. The ductility, tensile stress, hardness, and the amount of SIM increase with decreasing strain rate in hydrogen-free 304 SS and decrease in hydrogen-charged one. Specifically, SIM that forms during tensile tests is beneficial in increasing the ductility, strain hardening, and tensile stress of 304 SS, irrespective of the presence of hydrogen. A correlation of the tensile properties of hydrogen-free and hydrogen-charged 304 SS and the amount of SIM shows that hydrogen suppresses the formation of SIM in hydrogen-charged 304 SS, leading to a ductility loss and localized brittle fracture. Consequently, we demonstrate that hydrogen embrittlement of 304 SS is related to hydrogen-suppressed formation of SIM, corresponding to the disordered phase, according to our proposition. Compelling evidence is provided by the observations of the increased lattice expansion of martensite with decreasing strain rate in hydrogen-free 304 SS and its lattice contraction in hydrogen-charged one.

  7. Probing thermodynamic fluctuations in high temperature superconductors

    Science.gov (United States)

    Vidal, Felix; Veira, J. A.; Maza, J.; Miguélez, F.; Morán, E.; Alario, M. A.

    1988-04-01

    We probe thermodynamic fluctuations in HTSC by measuring the excess electrical conductivity, Δσ, abovr T c in single-phase (within 4%) Ba 2LnCu 3O 7-δ compounds, with LnY, Ho and Sm. As expected, the measured relative effect, Δσ / σ (300 K), is much more important in HTSC than for low-temperature superconductors (at least one order of magnitude). In the reduced temperature region -5=-0.47 ± 0.06. This result confirms an universal critical behaviour of Δσ in HTSC, and the value of agrees with that predicted by the Aslamazov-Larkin (AL) theory for three-dimensional BCS superconductivity. However, A shows a normal conductivity dependence which is not accounted for by the AL theory.

  8. Elastic properties and stress-temperature phase diagrams of high-temperature phases with low-temperature lattice instabilities

    Science.gov (United States)

    Thomas, John C.; Van der Ven, Anton

    2014-12-01

    The crystal structures of many technologically important high-temperature phases are predicted to have lattice instabilities at low temperature, making their thermodynamic and mechanical properties inaccessible to standard first principles approaches that rely on the (quasi) harmonic approximation. Here, we use the recently developed anharmonic potential cluster expansion within Monte Carlo simulations to predict the effect of temperature and anisotropic stress on the elastic properties of ZrH2, a material that undergoes diffusionless transitions among cubic, tetragonal, and orthorhombic phases. Our analysis shows that the mechanical properties of high-temperature phases with low-temperature vibrational instabilities are very sensitive to temperature and stress state. These findings have important implications for materials characterization and multi-scale simulations and suggest opportunities for enhanced strain engineering of high-temperature phases exhibiting soft-mode instabilities.

  9. Double Bag VARTM for High Temperature Composites Project

    Data.gov (United States)

    National Aeronautics and Space Administration — Cost and size are limiting factors in efforts to produce high strength, high stiffness, and high temperature composite parts. To address these issues, new processes...

  10. Confinement Studies in High Temperature Spheromak Plasmas

    Energy Technology Data Exchange (ETDEWEB)

    Hill, D N; Mclean, H S; Wood, R D; Casper, T A; Cohen, B I; Hooper, E B; LoDestro, L L; Pearlstein, L D; Romero-Talamas, C

    2006-10-23

    Recent results from the SSPX spheromak experiment demonstrate the potential for obtaining good energy confinement (Te > 350eV and radial electron thermal diffusivity comparable to tokamak L-mode values) in a completely self-organized toroidal plasma. A strong decrease in thermal conductivity with temperature is observed and at the highest temperatures, transport is well below that expected from the Rechester-Rosenbluth model. Addition of a new capacitor bank has produced 60% higher magnetic fields and almost tripled the pulse length to 11ms. For plasmas with T{sub e} > 300eV, it becomes feasible to use modest (1.8MW) neutral beam injection (NBI) heating to significantly change the power balance in the core plasma, making it an effective tool for improving transport analysis. We are now developing detailed designs for adding NBI to SSPX and have developed a new module for the CORSICA transport code to compute the correct fast-ion orbits in SSPX so that we can simulate the effect of adding NBI; initial results predict that such heating can raise the electron temperature and total plasma pressure in the core by a factor of two.

  11. Scaling Studies for High Temperature Test Facility and Modular High Temperature Gas-Cooled Reactor

    Energy Technology Data Exchange (ETDEWEB)

    Richard R. Schult; Paul D. Bayless; Richard W. Johnson; James R. Wolf; Brian Woods

    2012-02-01

    The Oregon State University (OSU) High Temperature Test Facility (HTTF) is an integral experimental facility that will be constructed on the OSU campus in Corvallis, Oregon. The HTTF project was initiated, by the U.S. Nuclear Regulatory Commission (NRC), on September 5, 2008 as Task 4 of the 5-year High Temperature Gas Reactor Cooperative Agreement via NRC Contract 04-08-138. Until August, 2010, when a DOE contract was initiated to fund additional capabilities for the HTTF project, all of the funding support for the HTTF was provided by the NRC via their cooperative agreement. The U.S. Department of Energy (DOE) began their involvement with the HTTF project in late 2009 via the Next Generation Nuclear Plant (NGNP) project. Because the NRC's interests in HTTF experiments were only centered on the depressurized conduction cooldown (DCC) scenario, NGNP involvement focused on expanding the experimental envelope of the HTTF to include steady-state operations and also the pressurized conduction cooldown (PCC).

  12. First high-temperature electronics products survey 2005.

    Energy Technology Data Exchange (ETDEWEB)

    Normann, Randy Allen

    2006-04-01

    On April 4-5, 2005, a High-Temperature Electronics Products Workshop was held. This workshop engaged a number of governmental and private industry organizations sharing a common interest in the development of commercially available, high-temperature electronics. One of the outcomes of this meeting was an agreement to conduct an industry survey of high-temperature applications. This report covers the basic results of this survey.

  13. A model of evaluating the pseudogap temperature for high ...

    Indian Academy of Sciences (India)

    We have presented a model of evaluating the pseudogap temperature for high temperature superconductors using paraconductivity approach. The theoretical analysis is based on the crossing point technique of the conductivity expressions. The pseudogap temperature T ∗ is found to depend on dimension and is ...

  14. Predicting High Temperature Dislocation Physics in HCP Crystal Structures

    Energy Technology Data Exchange (ETDEWEB)

    Hunter, Abigail [Los Alamos National Lab. (LANL), Los Alamos, NM (United States); Carpenter, John S. [Los Alamos National Lab. (LANL), Los Alamos, NM (United States); Martinez Saez, Enrique [Los Alamos National Lab. (LANL), Los Alamos, NM (United States)

    2016-05-09

    This report applies models and experiments to answer key questions about the way materials deform; specifics regarding phase field dislocations dynamics; as well as high temperature rolling experiments.

  15. Gallium Oxide Nanostructures for High Temperature Sensors

    Energy Technology Data Exchange (ETDEWEB)

    Chintalapalle, Ramana V. [Univ. of Texas, El Paso, TX (United States)

    2015-04-30

    Gallium oxide (Ga2O3) thin films were produced by sputter deposition by varying the substrate temperature (Ts) in a wide range (Ts=25-800 °C). The structural characteristics and electronic properties of Ga2O3 films were evaluated using X-ray diffraction (XRD), scanning electron microscopy (SEM), energy-dispersive X-ray spectrometry (EDS), Rutherford backscattering spectrometry (RBS) and spectrophotometric measurements. The effect of growth temperature is significant on the chemistry, crystal structure and morphology of Ga2O3 films. XRD and SEM analyses indicate that the Ga2O3 films grown at lower temperatures were amorphous while those grown at Ts≥500 oC were nanocrystalline. RBS measurements indicate the well-maintained stoichiometry of Ga2O3 films at Ts=300-800 °C. The electronic structure determination indicated that the nanocrystalline Ga2O3films exhibit a band gap of ~5 eV. Tungsten (W) incorporated Ga2O3 films were produced by co-sputter deposition. W-concentration was varied by the applied sputtering-power. No secondary phase formation was observed in W-incorporated Ga2O3 films. W-induced effects were significant on the structure and electronic properties of Ga2O3 films. The band gap of Ga2O3 films without W-incorporation was ~5 eV. Oxygen sensor characteristics evaluated using optical and electrical methods indicate a faster response in W-doped Ga2O3 films compared to intrinsic Ga2O3 films. The results demonstrate the applicability of both intrinsic and W-doped Ga-oxide films for oxygen sensor application at temperatures ≥700 °C.

  16. Hardening and embrittlement mechanisms of reduced activation ferritic/martensitic steels irradiated at 573 K

    Energy Technology Data Exchange (ETDEWEB)

    Tanigawa, H. [Japan Atomic Energy Agency, Tokai-mura, Naga-gun, Ibaraki-ken (Japan); Klueh, R.L. [Oak Ridge Noational Laboratory, TN (United States); Hashimoto, N. [Hokkaido Univ., Materials Science and Engineering Div., Graduate School of Engineering, Sapporo (Japan); Sokolov, M. [Oak Ridge National Laboratory, Materials Science and Technology Div., TN (United States)

    2007-07-01

    Full text of publication follows: It has been reported that reduced-activation ferritic/martensitic steels (RAFMs), such as F82H, ORNL9Cr-2WVTa, and JLF-1, showed a variety of changes in ductile-brittle transition temperature and yield stress after irradiation at 573 K up to 5 dpa, and those differences could not be interpreted solely by the difference of dislocation microstructure induced by irradiation. To investigate the impact of other microstructural feature, i.e. precipitates, the precipitation behavior of F82H, ORNL 9Cr-2WVTa, and JLF-1 was examined. It was revealed that irradiation-induced precipitation and amorphization of precipitates partly occurred and caused the different precipitation on block, packet and prior austenitic grain boundaries. In addition to these phenomena, irradiation-induced nano-size precipitates were also observed in the matrix. It was also revealed that the chemical compositions of precipitates approached the calculated thermal equilibrium state of M{sub 23}C{sub 6} at an irradiation temperature of 573 K. The calculation also suggests the presence of Laves phase at 573 K, which is usually not observed at this temperature, but the ion irradiation on aged F82H with Laves phase suggests that Laves phase becomes amorphous and could not be stable under irradiation at 573 K. This observation indicates the possibility that the irradiation-induced nano-size precipitation could be the consequence of the conflict between precipitation and amorphization of Laves phase. Over all, these observations suggests that the variety of embrittlement and hardening of RAFMs observed at 573 K irradiation up to 5 dpa might be the consequence of the transition phenomena that occur as the microstructure approaches thermal equilibrium during irradiation at 573 K. (authors)

  17. High temperature lithium cells with solid polymer electrolytes

    Science.gov (United States)

    Yang, Jin; Eitouni, Hany Basam; Singh, Mohit

    2017-03-07

    Electrochemical cells that use electrolytes made from new polymer compositions based on poly(2,6-dimethyl-1,4-phenylene oxide) and other high-softening-temperature polymers are disclosed. These materials have a microphase domain structure that has an ionically-conductive phase and a phase with good mechanical strength and a high softening temperature. In one arrangement, the structural block has a softening temperature of about 210.degree. C. These materials can be made with either homopolymers or with block copolymers. Such electrochemical cells can operate safely at higher temperatures than have been possible before, especially in lithium cells. The ionic conductivity of the electrolytes increases with increasing temperature.

  18. Hydrogen Embrittlement of Pipeline Steels: Causes and Remediation

    Energy Technology Data Exchange (ETDEWEB)

    Sofronis, Petros [University of Illinois at Urbana-Champaign; Robertson, Ian M [University of Wisconsin-Madison

    2013-08-01

    Fundamental studies of hydrogen embrittlement of materials using both experimental observations and numerical simulations of the hydrogen/deformation interactions have been conducted. Our approach integrates mechanical property testing at the macro-scale, microstructural analyses and TEM observations of the deformation processes at the micro- and nano-scale, first-principles calculations of interfacial cohesion at the atomic scale, and finite element simulation and modeling at the micro- and macro-level. Focused Ion Beam machining in conjunction with Transmission Electron Microscopy were used to identify the salient micro-mechanisms of failure in the presence of hydrogen. Our analysis of low strength ferritic steels led to the discovery that “quasi-cleavage” is a dislocation plasticity controlled failure mode in agreement with the hydrogen enhanced plasticity mechanism. The microstructure underneath the fracture surface of 304 and 316 stainless steels was found to be significantly more complex than would have been predicted by the traditional models of fatigue. The general refinement of the microstructure that occurred near the fracture surface in the presence of hydrogen was such that one may argue that hydrogen stabilizes microstructural configurations to an extent not achievable in its absence. Finite element studies of hydrogen and deformation field similitude for cracks in real-life pipelines and laboratory fracture specimens yielded that the Single Edge Notch Tension specimen can be used to reliably study hydrogen material compatibility for pipeline structures. In addition, simulation of onset of crack propagation in low strength ferritic systems by void growth indicated that hydrogen can reduce the fracture toughness of the material by as much as 30%. Both experimental observations and numerical studies of hydrogen transport on hydrogen accumulations ahead of a crack tip yielded that dislocation transport can markedly enhance hydrogen populations which

  19. Hydrogen embrittlement, revisited by in situ electrochemical nanoindentation

    Energy Technology Data Exchange (ETDEWEB)

    Barnoush, Afrooz

    2007-07-01

    The fine scale mechanical probing capability of NI-AFM was used to examine hydrogen interaction with plasticity. To realize this, an electrochemical three electrode setup was incorporated into the NI-AFM. The developed ECNI-AFM is capable of performing nanoindentation as well as imaging surfaces inside electrolytes. The developed ECNI-AFM setup was used to examine the effect of cathodically charged hydrogen on dislocation nucleation in pure metals and alloys. It was shown that hydrogen reduces the pop-in load in all of the tested materials except Cu. The reduced pop-in load can be interpreted as the HELP mechanism. Classical dislocation theory was used to model the homogeneous dislocation nucleation and it was shown that H reduces the activation energy for dislocation nucleation in H sensitive metals which are not undergoing a phase transformation. The activation energy for dislocation nucleation is related to the material specific parameters; shear modulus {mu}, dislocation core radius {rho} and in the case of partial dislocation nucleation, stacking fault energy {gamma}. These material properties can be influenced by H resulting in a reduced activation energy for dislocation nucleation. The universality of cohesion in bulk metals relates the reduction of the shear modulus to the reduction of the cohesion, meaning HEDE mechanism. The increase in the core radius of a dislocation due to H is a direct evidence of decrease in dislocation line energy and H segregation on the dislocation line. In the case of partial dislocations, the H can segregate on to the stacking fault ribbon and decrease {gamma}. This inhibits the cross slip process and enhances the slip planarity. Thus, HELP and HEDE are the two sides of a coin resulting in H embrittlement. However depending on the experimental approach utilized to probe the H effect, either HELP or HEDE can be observed. In this study, however, by utilizing a proper experimental approach, it was possible to resolve the

  20. High Work Output Ni-Ti-Pt High Temperature Shape Memory Alloys and Associated Processing Methods

    Science.gov (United States)

    Noebe, Ronald D. (Inventor); Draper, Susan L. (Inventor); Nathal, Michael V. (Inventor); Garg, Anita (Inventor)

    2009-01-01

    According to the invention, compositions of Ni-Ti-Pt high temperature, high force, shape memory alloys are disclosed that have transition temperatures above 100 C.; have narrow hysteresis; and produce a high specific work output.

  1. Spectroscopic diagnostics of high temperature plasmas

    Energy Technology Data Exchange (ETDEWEB)

    Moos, W.

    1990-01-01

    A three-year research program for the development of novel XUV spectroscopic diagnostics for magnetically confined fusion plasmas is proposed. The new diagnostic system will use layered synthetic microstructures (LSM) coated, flat and curved surfaces as dispersive elements in spectrometers and narrow band XUV filter arrays. In the framework of the proposed program we will develop impurity monitors for poloidal and toroidal resolved measurements on PBX-M and Alcator C-Mod, imaging XUV spectrometers for electron density and temperature fluctuation measurements in the hot plasma core in TEXT or other similar tokamaks and plasma imaging devices in soft x-ray light for impurity behavior studies during RF heating on Phaedrus T and carbon pellet ablation in Alcator C-Mod. Recent results related to use of multilayer in XUV plasma spectroscopy are presented. We also discuss the latest results reviewed to q{sub o} and local poloidal field measurements using Zeeman polarimetry.

  2. High Temperature Processable Flexible Polymer Films

    Science.gov (United States)

    Sundar, D. Shanmuga; Raja, A. Sivanantha; Sanjeeviraja, C.; Jeyakumar, D.

    Recent developments in the field of flexible electronics motivated the researchers to start working in verdict of new flexible substrate for replacing the existing rigid glass and flexible plastics. Flexible substrates offer significant rewards in terms of being able to fabricate flexible electronic devices that are robust, thinner, conformable, lighter and can be rolled away when needed. In this work, a new flexible and transparent substrate with the help of organic materials such as Polydimethylsiloxane (PDMS) and tetra ethoxy orthosilicate (TEOS) is synthesized. Transmittance of about 90-95% is acquired in the visible region (400-700nm) and the synthesized substrate shows better thermal characteristics and withstands temperature up to 200∘C without any significant degradation. Characteristics such as transmittance (T), absorption (A), reflectance (R), refractive index (n) and extinction coefficient (k) are also reported.

  3. High Temperature Superconductivity in Cuprates: a model

    CERN Document Server

    Silva, P R

    2010-01-01

    A model is proposed such that quasi-particles (electrons or holes) residing in the CuO2 planes of cuprates may interact leading to metallic or superconducting behaviors. The metallic phase is obtained when the quasi-particles are treated as having classical kinetic energies and the superconducting phase occurs when the quasi-particles are taken as extremely relativistic objects. The interaction between both kinds of particles is provided by a force dependent-on-velocity. In the case of the superconducting behavior, the motion of apical oxygen ions provides the glue to establish the Cooper pair. The model furnishes explicit relations for the Fermi velocity, the perpendicular and the in-plane coherence lengths, the zero-temperature energy gap, the critical current density, the critical parallel and perpendicular magnetic fields. All these mentioned quantities are expressed in terms of fundamental physical constants as: charge and mass of the electron, light velocity in vacuum, Planck constant, electric permitti...

  4. Study of High Temperature Insulation Materials

    Directory of Open Access Journals (Sweden)

    Vaclav Mentlik

    2004-01-01

    Full Text Available One of current objectives of the electro insulating technology is the development of the material for extreme conditions. There is a need to operate some devices in extreme temperatures, for example the propulsion of the nuclear fuel bars. In these cases there is necessary to provide not just insulating property, but also the thermal endurance with the required durability of the insulating materials. Critical is the determination of the limit stress for the irreversible structure modification with relation to material property changes. For this purpose there is necessary to conduct lot of test on chosen materials to determine the limits mentioned above. Content of this article is the definition of diagnostic mode, including the definition of the exposure factors, definitions of the diagnostic system for data acquisition and first result of examinations.

  5. High temperature performance of polymer composites

    CERN Document Server

    Keller, Thomas

    2014-01-01

    The authors explain the changes in the thermophysical and thermomechanical properties of polymer composites under elevated temperatures and fire conditions. Using microscale physical and chemical concepts they allow researchers to find reliable solutions to their engineering needs on the macroscale. In a unique combination of experimental results and quantitative models, a framework is developed to realistically predict the behavior of a variety of polymer composite materials over a wide range of thermal and mechanical loads. In addition, the authors treat extreme fire scenarios up to more than 1000°C for two hours, presenting heat-protection methods to improve the fire resistance of composite materials and full-scale structural members, and discuss their performance after fire exposure. Thanks to the microscopic approach, the developed models are valid for a variety of polymer composites and structural members, making this work applicable to a wide audience, including materials scientists, polymer chemist...

  6. High-Temperature Coatings Offer Energy Savings

    Science.gov (United States)

    2012-01-01

    The U.S. X-Plane Program included the first-of-its-kind research in aerodynamics and astronautics with experimental vehicles, including the first aircraft to break the sound barrier; the first aircraft to fly in excess of 100,000, then 200,000, and then 300,000 feet; and the first aircraft to fly at three, four, five, and then six times the speed of sound. During the 1990s, NASA started developing a new thermal protection material to test on the X-33 and X-34 supersonic aircraft. The X-33 was intended to demonstrate the technologies needed for a new reusable launch vehicle and was projected to reach an altitude of approximately 50 miles and speeds of more than Mach 11. The X-34, a small, reusable technology demonstrator for a launch vehicle, was intended to reach an altitude of 250,000 feet and fly at speeds of Mach 8. As a result of its research and development efforts, NASA s Ames Research Center invented the Protective Ceramic Coating Material (PCCM). Applied to a surface, the thin, lightweight coating could protect the material underneath from extreme temperatures. The capability of the technology came from its emissivity, which radiated heat away from the surface it covered, thereby decreasing the amount of heat transferred to the underlying material. PCCM not only increased the capability of materials to withstand higher temperatures, it also exhibited impressive thermal shock, vibration, and acoustic performance. In addition, it proved to be resistant to abrasion and mechanical damage and was also environmentally safe, due to it being water-based and containing no solvents. Even though funding for the X-33 and X-34 ended in 2001, PCCM continued on a path of innovation.

  7. Advanced High-Temperature, High-Pressure Transport Reactor Gasification

    Energy Technology Data Exchange (ETDEWEB)

    Michael Swanson; Daniel Laudal

    2008-03-31

    . Higher-reactivity (low-rank) coals appear to perform better in a transport reactor than the less reactive bituminous coals. Factors that affect TRDU product gas quality appear to be coal type, temperature, and air/coal ratios. Testing with a higher-ash, high-moisture, low-rank coal from the Red Hills Mine of the Mississippi Lignite Mining Company has recently been completed. Testing with the lignite coal generated a fuel gas with acceptable heating value and a high carbon conversion, although some drying of the high-moisture lignite was required before coal-feeding problems were resolved. No ash deposition or bed material agglomeration issues were encountered with this fuel. In order to better understand the coal devolatilization and cracking chemistry occurring in the riser of the transport reactor, gas and solid sampling directly from the riser and the filter outlet has been accomplished. This was done using a baseline Powder River Basin subbituminous coal from the Peabody Energy North Antelope Rochelle Mine near Gillette, Wyoming.

  8. Photochemistry at high temperatures - potential of ZnO as a high temperature photocatalyst

    Energy Technology Data Exchange (ETDEWEB)

    Schubnell, M.; Beaud, P.; Kamber, I. [Paul Scherrer Inst. (PSI), Villigen (Switzerland)

    1997-06-01

    Direct conversion of solar radiation into useful, storeable and transportable chemical products is the primary goal of solar chemistry. In this paper we discuss some fundamental aspects of photochemistry at elevated temperatures. We show that luminescence can serve as an indicator of the potential use of a system as a photoconverter. As an example we present experimental data on the chemical potential and on the lifetime of the excited states of ZnO. The low luminescence quantum yield together with a lifetime of about 200 ps indicate that an efficient photochemical conversion on ZnO is highly improbable. We believe this to be a general feature of chemical systems based on a semiconductor photocatalyst, in particular of photoreactions at a solid/gas interface. (author) 3 figs., 6 refs

  9. High Temperature Superconductor Resonator Detectors Project

    Data.gov (United States)

    National Aeronautics and Space Administration — There is a well-established need for more sensitive detectors in the 10 - 200 um wavelength range with high detectivity, D*>1010 cm-Hz1/2/W to increase the...

  10. Dynamic mechanical response and a constitutive model of Fe-based high temperature alloy at high temperatures and strain rates.

    Science.gov (United States)

    Su, Xiang; Wang, Gang; Li, Jianfeng; Rong, Yiming

    2016-01-01

    The effects of strain rate and temperature on the dynamic behavior of Fe-based high temperature alloy was studied. The strain rates were 0.001-12,000 s(-1), at temperatures ranging from room temperature to 800 °C. A phenomenological constitutive model (Power-Law constitutive model) was proposed considering adiabatic temperature rise and accurate material thermal physical properties. During which, the effects of the specific heat capacity on the adiabatic temperature rise was studied. The constitutive model was verified to be accurate by comparison between predicted and experimental results.

  11. SiC device development for high temperature sensor applications

    Science.gov (United States)

    Shor, J. S.; Goldstein, David; Kurtz, A. D.; Osgood, R. M.

    1992-01-01

    Progress made in the processing and characterization of 3C-SiC for high temperature sensor applications is reviewed. Piezoresistance properties of silicon carbide and the temperature coefficient of resistivity of n-type beta-SiC are presented. In addition, photoelectrical etching and dopant selective etch-stops in SiC and high temperature Ohmic contacts for n-type beta-SiC sensors are discussed.

  12. Dynamic high-temperature Kolsky tension bar techniques

    OpenAIRE

    Song Bo; Nelson Kevin; Lipinski Ronald; Bignell John; Ulrich G.B.; George E.P.

    2015-01-01

    Kolsky tension bar techniques were modified for dynamic high-temperature tensile characterization of thin-sheet alloys. An induction coil heater was used to heat the specimen while a cooling system was applied to keep the bars at room temperature during heating. A preload system was developed to generate a small pretension load in the bar system during heating in order to compensate for the effect of thermal expansion generated in the high-temperature tensile specimen. A laser system was appl...

  13. Extruded Self-Lubricating Solid For High-Temperature Use

    Science.gov (United States)

    Sliney, H. E.; Waters, W. J.; Soltis, R. F.; Bemis, K.

    1996-01-01

    "EX-212" denotes high-density extruded form of composite solid material self-lubricating over wide range of temperatures. Properties equal or exceed those of powder-metallurgy version of this material. Developed for use in advanced engines at high temperatures at which ordinary lubricants destroyed.

  14. High temperature heat exchange: nuclear process heat applications

    Energy Technology Data Exchange (ETDEWEB)

    Vrable, D.L.

    1980-09-01

    The unique element of the HTGR system is the high-temperature operation and the need for heat exchanger equipment to transfer nuclear heat from the reactor to the process application. This paper discusses the potential applications of the HTGR in both synthetic fuel production and nuclear steel making and presents the design considerations for the high-temperature heat exchanger equipment.

  15. Electron beam damage in high temperature polymers

    Energy Technology Data Exchange (ETDEWEB)

    Kumar, S. (Dayton Univ., OH (USA). Research Inst.); Adams, W.W. (Air Force Materials Lab., Wright-Patterson AFB, OH (USA))

    1990-01-01

    Electron microscopic studies of polymers are limited due to beam damage. Two concerns are the damage mechanism in a particular material, and the maximum dose for a material before damage effects are observed. From the knowledge of the dose required for damage to the polymer structure, optimum parameters for electron microscopy imaging can be determined. In the present study, electron beam damage of polymers has been quantified by monitoring changes in the diffraction intensity as a function of electron dose. The beam damage characteristics of the following polymers were studied: poly(p-phenylene benzobisthiazole) (PBZT); poly(p-phenylene benzobisoxazole) (PBO); poly(benzoxazole) (ABPBO); poly(benzimidazole) (ABPBI); poly(p-phenylene terephthalamide) (PPTA); and poly(aryl ether ether ketone) (PEEK). Previously published literature results on polyethylene (PE), polyoxymethylene (POM), nylon-6, poly(ethylene oxide) (PEO), PBZT, PPTA, PPX, iPS, poly(butylene terephthalate) (PBT), and poly(phenylene sulphide) (PPS) were reviewed. This study demonstrates the strong dependence of the electron beam resistivity of a polymer on its thermal stability/melt temperature. (author).

  16. InGaN High Temperature Photovoltaic Cells Project

    Data.gov (United States)

    National Aeronautics and Space Administration — The objectives of this Phase II project are to develop InGaN photovoltaic cells for high temperature and/or high radiation environments to TRL 4 and to define the...

  17. Grain boundaries in high temperature superconductors

    NARCIS (Netherlands)

    Hilgenkamp, Johannes W.M.; Mannhart, J.

    2002-01-01

    Since the first days of high-Tc superconductivity, the materials science and the physics of grain boundaries in superconducting compounds have developed into fascinating fields of research. Unique electronic properties, different from those of the grain boundaries in conventional metallic

  18. Hydrogen embrittlement of duplex steel tested using slow strain rate test

    Directory of Open Access Journals (Sweden)

    P. Vaňova

    2014-04-01

    Full Text Available This paper is dealing with hydrogen embrittlement of austenitic-ferritic 2205 duplex steel using the slow strain rate test (SSRT. The original material was subjected to heat treatment under 700 °C during 5 hours and following aircooling with the aim of provoking sigma phase precipitation and embrittlement of the material. The samples of both states were electrolytic saturation with hydrogen in 0,1N solution of sulfuric acid (H2SO4 with addition KSCN during 24 hours. The hydrogen embrittlement appeared on fracture surfaces of tested tensile bars as a quasi-cleavage damage on their perimeter. From the established depth of hydrogen charging the diffusion coefficient of hydrogen in duplex steel with ferritic-austenitic structure and with the structure containing the sigma phase as well were estimated.

  19. Aqueous chloride stress corrosion cracking of titanium - A comparison with environmental hydrogen embrittlement

    Science.gov (United States)

    Nelson, H. G.

    1974-01-01

    The physical characteristics of stress corrosion cracking of titanium in an aqueous chloride environment are compared with those of embrittlement of titanium by a gaseous hydrogen environment in an effort to help contribute to the understanding of the possible role of hydrogen in the complex stress corrosion cracking process. Based on previous studies, the two forms of embrittlement are shown to be similar at low hydrogen pressures (100 N/sq m) but dissimilar at higher hydrogen pressures. In an effort to quantify this comparison, tests were conducted in an aqueous chloride solution using the same material and test techniques as had previously been employed in a gaseous hydrogen environment. The results of these tests strongly support models based on hydrogen as the embrittling species in an aqueous chloride environment.

  20. Dynamic High-Temperature Characterization of an Iridium Alloy in Compression at High Strain Rates

    Energy Technology Data Exchange (ETDEWEB)

    Song, Bo [Sandia National Lab. (SNL-NM), Albuquerque, NM (United States). Experimental Environment Simulation Dept.; Nelson, Kevin [Sandia National Lab. (SNL-CA), Livermore, CA (United States). Mechanics of Materials Dept.; Lipinski, Ronald J. [Sandia National Lab. (SNL-NM), Albuquerque, NM (United States). Advanced Nuclear Fuel Cycle Technology Dept.; Bignell, John L. [Sandia National Lab. (SNL-NM), Albuquerque, NM (United States). Structural and Thermal Analysis Dept.; Ulrich, G. B. [Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States). Radioisotope Power Systems Program; George, E. P. [Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States). Radioisotope Power Systems Program

    2014-06-01

    Iridium alloys have superior strength and ductility at elevated temperatures, making them useful as structural materials for certain high-temperature applications. However, experimental data on their high-temperature high-strain-rate performance are needed for understanding high-speed impacts in severe elevated-temperature environments. Kolsky bars (also called split Hopkinson bars) have been extensively employed for high-strain-rate characterization of materials at room temperature, but it has been challenging to adapt them for the measurement of dynamic properties at high temperatures. Current high-temperature Kolsky compression bar techniques are not capable of obtaining satisfactory high-temperature high-strain-rate stress-strain response of thin iridium specimens investigated in this study. We analyzed the difficulties encountered in high-temperature Kolsky compression bar testing of thin iridium alloy specimens. Appropriate modifications were made to the current high-temperature Kolsky compression bar technique to obtain reliable compressive stress-strain response of an iridium alloy at high strain rates (300 – 10000 s-1) and temperatures (750°C and 1030°C). Uncertainties in such high-temperature high-strain-rate experiments on thin iridium specimens were also analyzed. The compressive stress-strain response of the iridium alloy showed significant sensitivity to strain rate and temperature.

  1. Low temperature superconductor and aligned high temperature superconductor magnetic dipole system and method for producing high magnetic fields

    Energy Technology Data Exchange (ETDEWEB)

    Gupta, Ramesh; Scanlan, Ronald; Ghosh, Arup K.; Weggel, Robert J.; Palmer, Robert; Anerella, Michael D.; Schmalzle, Jesse

    2017-10-17

    A dipole-magnet system and method for producing high-magnetic-fields, including an open-region located in a radially-central-region to allow particle-beam transport and other uses, low-temperature-superconducting-coils comprised of low-temperature-superconducting-wire located in radially-outward-regions to generate high magnetic-fields, high-temperature-superconducting-coils comprised of high-temperature-superconducting-tape located in radially-inward-regions to generate even higher magnetic-fields and to reduce erroneous fields, support-structures to support the coils against large Lorentz-forces, a liquid-helium-system to cool the coils, and electrical-contacts to allow electric-current into and out of the coils. The high-temperature-superconducting-tape may be comprised of bismuth-strontium-calcium-copper-oxide or rare-earth-metal, barium-copper-oxide (ReBCO) where the rare-earth-metal may be yttrium, samarium, neodymium, or gadolinium. Advantageously, alignment of the large-dimension of the rectangular-cross-section or curved-cross-section of the high-temperature-superconducting-tape with the high-magnetic-field minimizes unwanted erroneous magnetic fields. Alignment may be accomplished by proper positioning, tilting the high-temperature-superconducting-coils, forming the high-temperature-superconducting-coils into a curved-cross-section, placing nonconducting wedge-shaped-material between windings, placing nonconducting curved-and-wedge-shaped-material between windings, or by a combination of these techniques.

  2. Probing High Temperature Superconductors with Magnetometry in Ultrahigh Magnetic Fields

    Energy Technology Data Exchange (ETDEWEB)

    Li, Lu [Univ. of Michigan, Ann Arbor, MI (United States)

    2017-07-26

    The objective of this research is to investigate the high-field magnetic properties of high temperature superconductors, materials that conduct electricity without loss. A technique known as high-resolution torque magnetometry that was developed to directly measure the magnetization of high temperature superconductors. This technique was implemented using the 65 Tesla pulsed magnetic field facility that is part of the National High Magnetic Field Laboratory at Los Alamos National Laboratory. This research addressed unanswered questions about the interplay between magnetism and superconductivity, determine the electronic structure of high temperature superconductors, and shed light on the mechanism of high temperature superconductivity and on potential applications of these materials in areas such as energy generation and power transmission. Further applications of the technology resolve the novel physical phenomena such as correlated topological insulators, and spin liquid state in quantum magnets.

  3. Analysis of the high-temperature particulate collection problem

    Energy Technology Data Exchange (ETDEWEB)

    Razgaitis, R.

    1977-10-01

    Particulate agglomeration and separation at high temperatures and pressures are examined, with particular emphasis on the unique features of the direct-cycle application of fluidized-bed combustion. The basic long-range mechanisms of aerosol separation are examined, and the effects of high temperature and high pressure on usable collection techniques are assessed. Primary emphasis is placed on those avenues that are not currently attracting widespread research. The high-temperature, particulate-collection problem is surveyed, together with the peculiar requirements associated with operation of turbines with particulate-bearing gas streams. 238 references.

  4. High Temperature Protonic Conductors by Melt Growth

    Science.gov (United States)

    2006-11-21

    electrolyzers, solid state fuel cells, gas separation membranes, moisture sensors and high-density energy storage applications, among others (1-5...A.R. de Arellano-López, A. Sayir. “Microestructura y Comportamiento Plástico de Perovsquitas Conductoras Protónicas de Alta Temperatura ”. Bol. Soc...Conductores Protónicos de Alta Temperatura Crecidos por Fusión de Zona Flotante”. VII Reunión Nacional y VI Conferencia Iberoamericana (Electrocerámica

  5. Temperature and Voltage Offsets in High-ZT Thermoelectrics

    Science.gov (United States)

    Levy, George S.

    2017-10-01

    Thermodynamic temperature can take on different meanings. Kinetic temperature is an expectation value and a function of the kinetic energy distribution. Statistical temperature is a parameter of the distribution. Kinetic temperature and statistical temperature, identical in Maxwell-Boltzmann statistics, can differ in other statistics such as those of Fermi-Dirac or Bose-Einstein when a field is present. Thermal equilibrium corresponds to zero statistical temperature gradient, not zero kinetic temperature gradient. Since heat carriers in thermoelectrics are fermions, the difference between these two temperatures may explain voltage and temperature offsets observed during meticulous Seebeck measurements in which the temperature-voltage curve does not go through the origin. In conventional semiconductors, temperature offsets produced by fermionic electrical carriers are not observable because they are shorted by heat phonons in the lattice. In high-ZT materials, however, these offsets have been detected but attributed to faulty laboratory procedures. Additional supporting evidence for spontaneous voltages and temperature gradients includes data collected in epistatic experiments and in the plasma Q-machine. Device fabrication guidelines for testing the hypothesis are suggested including using unipolar junctions stacked in a superlattice, alternating n/n + and p/p + junctions, selecting appropriate dimensions, doping, and loading.

  6. High Temperature Corrosion on Biodust Firing

    DEFF Research Database (Denmark)

    Okoro, Sunday Chukwudi

    The high content of alkali metals and chlorine in biomass gives rise to fouling/slagging and corrosion of heat exchange components, such as superheaters, in biomass fired power plants. Increasing the lifetime of these components, and in addition, preventing unwarranted plant shutdowns due...... to their failure, requires understanding of the complex corrosion mechanisms, as well as development of materials that are resistant to corrosion under biomass firing conditions, thereby motivating the current work. To understand the mechanisms of corrosion attack, comprehensive analysis of corrosion products...... was necessary. In the present work, two complementary methodologies based on analysis of cross sections and plan views were applied to achieve comprehensive characterization of corrosion products. The suitability of these methods for both laboratory scale and full scale corrosion investigations was demonstrated...

  7. High Temperature Superconductor Josephson Weak Links

    Science.gov (United States)

    Hunt, B. D.; Barner, J. B.; Foote, M. C.; Vasquez, R. C.

    1993-01-01

    High T_c edge-geometry SNS microbridges have been fabricated using ion-damaged YBa_2Cu_3O_(7-x) (YBCO) and a nonsuperconducting phase of YBCO (N-YBCO) as normal metals. Optimization of the ion milling process used for YBCO edge formation and cleaning has resulted in ion-damage barrier devices which exhibit I-V characteristics consistent with the Resistively-Shunted-Junction (RSJ) model, with typical current densities (J_c) of approximately 5 x 10^6 A/cm^2 at 4.2 K. Characterization of N-YBCO films suggests that N-YBCO is the orthorhombic YBCO phase with oxygen disorder suppressing T_c...

  8. High skin temperature and hypohydration impair aerobic performance.

    Science.gov (United States)

    Sawka, Michael N; Cheuvront, Samuel N; Kenefick, Robert W

    2012-03-01

    This paper reviews the roles of hot skin (>35°C) and body water deficits (>2% body mass; hypohydration) in impairing submaximal aerobic performance. Hot skin is associated with high skin blood flow requirements and hypohydration is associated with reduced cardiac filling, both of which act to reduce aerobic reserve. In euhydrated subjects, hot skin alone (with a modest core temperature elevation) impairs submaximal aerobic performance. Conversely, aerobic performance is sustained with core temperatures >40°C if skin temperatures are cool-warm when euhydrated. No study has demonstrated that high core temperature (∼40°C) alone, without coexisting hot skin, will impair aerobic performance. In hypohydrated subjects, aerobic performance begins to be impaired when skin temperatures exceed 27°C, and even warmer skin exacerbates the aerobic performance impairment (-1.5% for each 1°C skin temperature). We conclude that hot skin (high skin blood flow requirements from narrow skin temperature to core temperature gradients), not high core temperature, is the 'primary' factor impairing aerobic exercise performance when euhydrated and that hypohydration exacerbates this effect.

  9. Quantitative Temperature Dependence of Longitudinal Spin Seebeck Effect at High Temperatures

    Directory of Open Access Journals (Sweden)

    Ken-ichi Uchida

    2014-11-01

    Full Text Available We report temperature-dependent measurements of longitudinal spin Seebeck effects (LSSEs in Pt/Y_{3}Fe_{5}O_{12} (YIG/Pt systems in a high temperature range from room temperature to above the Curie temperature of YIG. The experimental results show that the magnitude of the LSSE voltage in the Pt/YIG/Pt systems rapidly decreases with increasing the temperature and disappears above the Curie temperature. The critical exponent of the LSSE voltage in the Pt/YIG/Pt systems at the Curie temperature is estimated to be 3, which is much greater than that for the magnetization curve of YIG. This difference highlights the fact that the mechanism of the LSSE cannot be explained in terms of simple static magnetic properties in YIG.

  10. High Precision Infrared Temperature Measurement System Based on Distance Compensation

    Directory of Open Access Journals (Sweden)

    Chen Jing

    2017-01-01

    Full Text Available To meet the need of real-time remote monitoring of human body surface temperature for optical rehabilitation therapy, a non-contact high-precision real-time temperature measurement method based on distance compensation was proposed, and the system design was carried out. The microcontroller controls the infrared temperature measurement module and the laser range module to collect temperature and distance data. The compensation formula of temperature with distance wass fitted according to the least square method. Testing had been performed on different individuals to verify the accuracy of the system. The results indicate that the designed non-contact infrared temperature measurement system has a residual error of less than 0.2°C and the response time isless than 0.1s in the range of 0 to 60cm. This provides a reference for developing long-distance temperature measurement equipment in optical rehabilitation therapy.

  11. Experimental Research on High Temperature Resistance of Modified Lightweight Concrete after Exposure to Elevated Temperatures

    OpenAIRE

    Ke-cheng He; Rong-xin Guo; Qian-min Ma; Feng Yan; Zhi-wei Lin; Yan-Lin Sun

    2016-01-01

    In order to improve the spalling resistance of lightweight aggregate concrete at high temperature, two types of modified materials were used to modify clay ceramsite lightweight aggregates by adopting the surface coating modification method. Spalling of the concrete specimens manufactured by using the modified aggregates was observed during a temperature elevation. Mass loss and residual axial compressive strength of the modified concrete specimens after exposure to elevated temperatures were...

  12. Test plans of the high temperature test operation at HTTR

    Energy Technology Data Exchange (ETDEWEB)

    Sakaba, Nariaki; Nakagawa, Shigeaki; Takada, Eiji [Japan Atomic Energy Research Inst., Oarai, Ibaraki (Japan). Oarai Research Establishment] [and others

    2003-03-01

    HTTR plans a high temperature test operation as the fifth step of the rise-to-power tests to achieve a reactor outlet coolant temperature of 950 degrees centigrade in the 2003 fiscal year. Since HTTR is the first HTGR in Japan which uses coated particle fuel as its fuel and helium gas as its coolant, it is necessary that the plan of the high temperature test operation is based on the previous rise-to-power tests with a thermal power of 30 MW and a reactor outlet coolant temperature at 850 degrees centigrade. During the high temperature test operation, reactor characteristics, reactor performances and reactor operations are confirmed for the safety and stability of operations. This report describes the evaluation result of the safety confirmations of the fuel, the control rods and the intermediate heat exchanger for the high temperature test operation. Also, problems which were identified during the previous operations are shown with their solution methods. Additionally, there is a discussion on the contents of the high temperature test operation. As a result of this study, it is shown that the HTTR can safely achieve a thermal power of 30 MW with the reactor outlet coolant temperature at 950 degrees centigrade. (author)

  13. Heat conductivity of high-temperature thermal insulators

    Science.gov (United States)

    Kharlamov, A. G.

    The book deals essentially with the mechanisms of heat transfer by conduction, convection, and thermal radiation in absorbing and transmitting media. Particular attention is given to materials for gas-cooled reactor systems, the temperature dependent conductivities of high-temperature insulations in vacuum, and the thermal conductivities of MgO, Al2O3, ZrO2, and other powders at temperatures up to 2000 C. The thermal conductivity of pyrolitic graphite and graphite foam are studied.

  14. Aqueous Geochemistry at High Pressures and High Temperatures

    Energy Technology Data Exchange (ETDEWEB)

    Bass, Jay D. [Univ. of Illinois, Urbana-Champaign, IL (United States)

    2015-05-21

    This project is aimed at experimental characterization of the sound velocities, equations of state (EOS), and derived physical and chemical properties of aqueous solutions and carbon dioxide at extreme pressure and temperature conditions relevant to processes occurring in the interior of the Earth. Chemical transport, phase changes (including melting), fluid-solid reactions, and formation of magmatic liquids at convergent plat boundaries are a key motivation for this project. Research in this area has long been limited by the extreme experimental challenges and lack of data under the appropriate pressure-temperature (P-T) conditions. The vast majority of studies of aqueous geochemistry relevant to terrestrial problems of fluid-rock interactions have been conducted at 0.3 GPa or less, and the widely used Helgeson-Kirkham-Flowers equation of state for aqueous species is applicable only at ~ < 0.5 GPa. These limits are unfortunate because fluid flow and reactions plays a central role in many deeper environments. Recent efforts including our own, have resulted in new experimental techniques that now make it possible to investigate properties of homogeneous and heterogeneous equilibria involving aqueous species and minerals over a much broader range of pressure and temperature appropriate for deep crustal and upper mantle processes involving water-rich fluids. We carried out 1) Brillouin scattering measurements of the equations of state and molar volume of water and carbon dioxide to over 10 GPa and 870K using precise resistance heating of samples under pressure in the diamond anvil cell, and 2) the phase diagrams of the water and CO2, and 3) Exploring new experimental approaches, including CO2 laser heating of samples in a diamond cell, to measurements of sound velocities, EOS, and phase relations by Brillouin scattering to far greater pressures and temperatures.

  15. Pulse Radiolysis at High Temperatures and High Pressures

    DEFF Research Database (Denmark)

    Christensen, H.; Sehested, Knud

    1980-01-01

    A cell for pulse radiolytic measurements up to temperatures of 320°C and pressures of 14 MPa is constructed. The activation energy of the reaction OH + Cu2+ is determined to 13.3 kJ × mol−1 (3.2 kcal × mol−1). A preliminary study of the reaction e−aq + e−aq yields an activation energy of 22 k...

  16. Proteomics of Rice Grain under High Temperature Stress

    Directory of Open Access Journals (Sweden)

    Toshiaki eMitsui

    2013-03-01

    Full Text Available Recent proteomic analyses revealed dynamic changes of metabolisms during rice grain development. Interestingly, proteins involved in glycolysis, citric acid cycle, lipid metabolism, and proteolysis were accumulated at higher levels in mature grain than those of developing stages. High temperature stress in rice ripening period causes damaged (chalky grains which have loosely packed round shape starch granules. The high temperature stress response on protein expression is complicated, and the molecular mechanism of the chalking of grain is obscure yet. Here, the current state on the proteomics research of rice grain grown under high temperature stress is briefly overviewed.

  17. Processing of extraterrestrial materials by high temperature vacuum vaporization

    Science.gov (United States)

    Grimley, R. T.; Lipschutz, M. E.

    1983-01-01

    It is noted that problems associated with the extraction and concentration of elements and commpounds important for the construction and operation of space habitats have received little attention. High temperature vacuum vaporization is considered a promising approach; this is a technique for which the space environment offers advantages in the form of low ambient pressures and temperatures and the possibility of sustained high temperatures via solar thermal energy. To establish and refine this new technology, experimental determinations must be made of the material release profiles as a function of temperature, of the release kinetics and chemical forms of material being transported, and of the various means of altering release kinetics. Trace element data determined by neutron activation analysis of meteorites heated to 1400 C in vacuum is summarized. The principal tool, high temperature spectrometry, is used to examine the vaporization thermodynamics and kinetics of major and minor elements from complex multicomponent extraterrestrial materials.

  18. Solar Power for Near Sun, High-Temperature Missions

    Science.gov (United States)

    Landis, Geoffrey A.

    2008-01-01

    Existing solar cells lose performance at the high temperatures encountered in Mercury orbit and inward toward the sun. For future missions designed to probe environments close to the sun, it is desirable to develop array technologies for high temperature and high light intensity. Approaches to solar array design for near-sun missions include modifying the terms governing temperature of the cell and the efficiency at elevated temperature, or use of techniques to reduce the incident solar energy to limit operating temperature. An additional problem is found in missions that involve a range of intensities, such as the Solar Probe + mission, which ranges from a starting distance of 1 AU from the sun to a minimum distance of 9.5 solar radii, or 0.044 AU. During the mission, the solar intensity ranges from one to about 500 times AM0. This requires a power system to operate over nearly three orders of magnitude of incident intensity.

  19. Liquid Fuel Production from Biomass via High Temperature Steam Electrolysis

    Energy Technology Data Exchange (ETDEWEB)

    Grant L. Hawkes; Michael G. McKellar

    2009-11-01

    A process model of syngas production using high temperature electrolysis and biomass gasification is presented. Process heat from the biomass gasifier is used to heat steam for the hydrogen production via the high temperature steam electrolysis process. Hydrogen from electrolysis allows a high utilization of the biomass carbon for syngas production. Oxygen produced form the electrolysis process is used to control the oxidation rate in the oxygen-fed biomass gasifier. Based on the gasifier temperature, 94% to 95% of the carbon in the biomass becomes carbon monoxide in the syngas (carbon monoxide and hydrogen). Assuming the thermal efficiency of the power cycle for electricity generation is 50%, (as expected from GEN IV nuclear reactors), the syngas production efficiency ranges from 70% to 73% as the gasifier temperature decreases from 1900 K to 1500 K. Parametric studies of system pressure, biomass moisture content and low temperature alkaline electrolysis are also presented.

  20. Low temperature heating and high temperature cooling embedded water based surface heating and cooling systems

    CERN Document Server

    Babiak, Jan; Petras, Dusan

    2009-01-01

    This Guidebook describes the systems that use water as heat-carrier and when the heat exchange within the conditioned space is more than 50% radiant. Embedded systems insulated from the main building structure (floor, wall and ceiling) are used in all types of buildings and work with heat carriers at low temperatures for heating and relatively high temperature for cooling.

  1. genetic analysis for high temperature tolerance in bread wheat ...

    African Journals Online (AJOL)

    Prof. Adipala Ekwamu

    selection (Reynolds et al., 1994). A number of high temperature stress-related traits have received considerable attention, in particular membrane thermostability (Saadalla et al., 1990), canopy temperature depression (Blum et al., 1982), proline content and chlorophyll content. Information on the genetic control of ...

  2. High-temperature thermoelectric behavior of lead telluride

    Indian Academy of Sciences (India)

    Usefulness of a material in thermoelectric devices is temperature specific. The central problem in thermoelectric material research is the selection of materials with high figure-of-merit in the given temperature range of operation. It is of considerable interest to know the utility range of the material, which is decided by the ...

  3. A model of evaluating the pseudogap temperature for high ...

    Indian Academy of Sciences (India)

    DOI: 10.1007/s12043-015-1088-3; ePublication: 30 September 2015. Abstract. We have presented a model of evaluating the pseudogap temperature for high- temperature superconductors using paraconductivity approach. The theoretical analysis is based on the crossing point technique of the conductivity expressions.

  4. Core Physics of Pebble Bed High Temperature Nuclear Reactors

    NARCIS (Netherlands)

    Auwerda, G.J.

    2014-01-01

    To more accurately predict the temperature distribution inside the reactor core of pebble bed type high temperature reactors, in this thesis we investigated the stochastic properties of randomly stacked beds and the effects of the non-homogeneity of these beds on the neutronics and

  5. Influence of temperature on denitrification of an industrial high ...

    African Journals Online (AJOL)

    The temperature effect on denitrification rate of a two-sludge system has been studied. An industrial high-strength wastewater and an industrial by-product containing mainly methanol, as external carbon source, were used in this study. The maximum denitrification rate (MDR) was determined at six different temperatures: 6, ...

  6. Tetrazole substituted polymers for high temperature polymer electrolyte fuel cells

    DEFF Research Database (Denmark)

    Henkensmeier, Dirk; My Hanh Duong, Ngoc; Brela, Mateusz

    2015-01-01

    interesting for use in a high temperature fuel cell (HT PEMFC). Based on these findings, two polymers incorporating the proposed TZ groups were synthesised, formed into membranes, doped with PA and tested for fuel cell relevant properties. At room temperature, TZ-PEEN and commercial meta-PBI showed...

  7. Adaptation of microorganisms and their transport systems to high temperatures

    NARCIS (Netherlands)

    Tolner, B; Poolman, B.; Konings, W.N

    1997-01-01

    Growth of Bacteria and Archaea has been observed at temperatures up to 95 and 110 degrees C, respectively. These thermophiles are adapted to environments of high temperature by changes in the membrane lipid composition, higher thermostabilities of the (membrane) proteins, higher turnover rates of

  8. Hydrogen embrittlement: the game changing factor in the applicability of nickel alloys in oilfield technology

    Science.gov (United States)

    Sarmiento Klapper, Helmuth; Klöwer, Jutta; Gosheva, Olesya

    2017-06-01

    Precipitation hardenable (PH) nickel (Ni) alloys are often the most reliable engineering materials for demanding oilfield upstream and subsea applications especially in deep sour wells. Despite their superior corrosion resistance and mechanical properties over a broad range of temperatures, the applicability of PH Ni alloys has been questioned due to their susceptibility to hydrogen embrittlement (HE), as confirmed in documented failures of components in upstream applications. While extensive work has been done in recent years to develop testing methodologies for benchmarking PH Ni alloys in terms of their HE susceptibility, limited scientific research has been conducted to achieve improved foundational knowledge about the role of microstructural particularities in these alloys on their mechanical behaviour in environments promoting hydrogen uptake. Precipitates such as the γ', γ'' and δ-phase are well known for defining the mechanical and chemical properties of these alloys. To elucidate the effect of precipitates in the microstructure of the oil-patch PH Ni alloy 718 on its HE susceptibility, slow strain rate tests under continuous hydrogen charging were conducted on material after several different age-hardening treatments. By correlating the obtained results with those from the microstructural and fractographic characterization, it was concluded that HE susceptibility of oil-patch alloy 718 is strongly influenced by the amount and size of precipitates such as the γ' and γ'' as well as the δ-phase rather than by the strength level only. In addition, several HE mechanisms including hydrogen-enhanced decohesion and hydrogen-enhanced local plasticity were observed taking place on oil-patch alloy 718, depending upon the characteristics of these phases when present in the microstructure. This article is part of the themed issue 'The challenges of hydrogen and metals'.

  9. Miniature High Stability High Temperature Space Rated Blackbody Radiance Source

    Science.gov (United States)

    Jones, J. A.; Beswick, A. G.

    1987-09-01

    This paper presents the design and test performance of a conical cavity type blackbody radiance source that will meet the requirements of the Halogen Occultation Experiment (HALOE) on the NASA Upper Atmospheric Research Satellite program (UARS). Since a radiance source meeting the requirements of this experiment was unavailable in the commercial market, a development effort was undertaken by the HALOE Project. The blackbody radiance source operates in vacuum at 1300 K + 0.5 K over any 15-minute interval, uses less than 7.5 watts of power, maintains a 49°C outer case temperature, and fits within the 2.5 x 2.5 x 3.0 inch envelope allocated inside the HALOE instrument. Also, the unit operates in air, during ground testing of the HALOE instrument, where it uses 17 watts of power with an outer case temperature of 66°C. The thrust of this design effort was to minimize the heat losses, in order to keep the power usage under 7.5 watts, and to minimize the amount of silica in the materials. Silica in the presence of the platinum heater winding used in this design would cause the platinum to erode, changing the operating temperature set-point. The design required the development of fabrication techniques which would provide very small, close tolerance parts from extremely difficult-to-machine materials. Also, a space rated ceramic core and unique, low thermal conductance, ceramic-to-metal joint was developed, tested and incorporated in this design. The completed flight qualification hardware has undergone performance, environmental and life testing. The design configuration and test results are discussed in detail in this paper.

  10. High-temperature transport in the Hubbard Model

    Science.gov (United States)

    Shastry, B. Sriram; Perepelitsky, Edward; Galatas, Andrew; Khatami, Ehsan; Mravlje, Jernej; Georges, Antoine

    We examine the general behavior of the frequency and momentum dependent single-particle scattering rate and the transport coefficients, of many-body systems in the high-temperature limit. We find that the single-particle scattering rate always saturates in temperature, while the transport coefficients always decay like 1/T, where T is the temperature. A consequence of this is a resistivity which is ubiquitously linear in T at high temperatures. For the Hubbard model, by using the high-temperature series, we are able to calculate the first few moments of the single particle scattering rate Σ (k --> , ω) and the conductivity σ (k --> , ω) in the high-temperature regime in d spatial dimensions. Further in the case of d --> ∞ , we are able to calculate a large number of moments using symbolic computation. We make a direct comparison between these moments and those obtained through Dynamical Mean Field Theory (DMFT). Finally, we use the moments to reconstruct the ω-dependent optical conductivity σ (ω) =limk-->0 σ (k --> , ω) in the high-temperature regime. The work at UCSC was supported by the U.S. Department of Energy (DOE), Office of Science, Basic Energy Sciences (BES) under Award # FG02-06ER46319.

  11. Decomposition of silicon carbide at high pressures and temperatures

    Energy Technology Data Exchange (ETDEWEB)

    Daviau, Kierstin; Lee, Kanani K. M.

    2017-11-01

    We measure the onset of decomposition of silicon carbide, SiC, to silicon and carbon (e.g., diamond) at high pressures and high temperatures in a laser-heated diamond-anvil cell. We identify decomposition through x-ray diffraction and multiwavelength imaging radiometry coupled with electron microscopy analyses on quenched samples. We find that B3 SiC (also known as 3C or zinc blende SiC) decomposes at high pressures and high temperatures, following a phase boundary with a negative slope. The high-pressure decomposition temperatures measured are considerably lower than those at ambient, with our measurements indicating that SiC begins to decompose at ~ 2000 K at 60 GPa as compared to ~ 2800 K at ambient pressure. Once B3 SiC transitions to the high-pressure B1 (rocksalt) structure, we no longer observe decomposition, despite heating to temperatures in excess of ~ 3200 K. The temperature of decomposition and the nature of the decomposition phase boundary appear to be strongly influenced by the pressure-induced phase transitions to higher-density structures in SiC, silicon, and carbon. The decomposition of SiC at high pressure and temperature has implications for the stability of naturally forming moissanite on Earth and in carbon-rich exoplanets.

  12. Properties of thin films for high temperature flow sensors

    Science.gov (United States)

    Albin, Sacharia

    1991-01-01

    Requirements of material parameters of high temperature flow sensors are identified. Refractory metal silicides offer high temperature sensitivity and high frequency response and are stable up to 1000 C. Intrinsic semiconductors of high band gap are also considered as sensor elements. SiC and diamond are identified. Combined with substrates of low thermal and electrical conductivity, such as quartz or Al2O3, these materials meet several requirements of high sensitivity and frequency response. Film deposition and patterning techniques suitable for these materials are identified.

  13. HALLIBURTON SPERRY-SUN DOE HIGH TEMPERATURE LWD PROJECT

    Energy Technology Data Exchange (ETDEWEB)

    Ronald L. Spross

    2005-03-15

    The objective of this project was to build a high temperature, cost-effective, logging while drilling (HT-LWD) system with the ability to operate at 175 C with more than 100 hours mean time between failures (MTBF). Such a commercial real-time formation evaluation (FE) system would help operators to drill and produce hydrocarbon resources from moderately deep, hot reservoirs which otherwise might be uneconomic to drill. The project plan was to combine the existing Sperry-Sun high temperature directional and gamma logging system with lower temperature FE sensors which were upgraded to higher temperature operation as part of the project. The project was to be completed in two phases. Phase I included the development of the HT system, building two complete systems, demonstrating operational capability at 175 C and survivability at 200 C in the laboratory, and successfully testing the system in two low temperature field tests. Phase II was to test the system in a well with a bottom hole temperature of 175 C. The high temperature FE sensors developed as part of this project include gamma ray (DGR), resistivity (EWR-Phase 4), neutron (CTN), and density (SLD). The existing high temperature pulser and telemetry system was upgraded to accommodate the data and bandwidth requirements of the additional sensors. Environmental and lifetime testing of system components and modules indicates that system life and reliability goals will be substantially exceeded. The system has performed well in domestic and international high temperature wells (to 175 C). In addition to the sensor modules specified in the project contract, Sperry has now upgraded other system components to higher temperature as well. These include a LWD sonic sensor (BAT), pressure while drilling sensor (PWD), and a more powerful central system controller (CIM).

  14. InGaN High Temperature Photovoltaic Cells Project

    Data.gov (United States)

    National Aeronautics and Space Administration — The objective of this Phase I project is to demonstrate InGaN materials are appropriate for high operating temperature single junction solar cells. Single junction...

  15. Inorganic Nanostructured High-Temperature Magnet Wires Project

    Data.gov (United States)

    National Aeronautics and Space Administration — This project will develop a high-temperature tolerant electrically-insulating coating for magnet wires. The Phase I program will result in a flexible, inorganic...

  16. Transmission Level High Temperature Superconducting Fault Current Limiter

    Energy Technology Data Exchange (ETDEWEB)

    Stewart, Gary [SuperPower, Inc., Schenectady, NY (United States)

    2016-10-05

    The primary objective of this project was to demonstrate the feasibility and reliability of utilizing high-temperature superconducting (HTS) materials in a Transmission Level Superconducting Fault Current Limiter (SFCL) application. During the project, the type of high-temperature superconducting material used evolved from 1st generation (1G) BSCCO-2212 melt cast bulk high-temperature superconductors to 2nd generation (2G) YBCO-based high-temperature superconducting tape. The SFCL employed SuperPower's “Matrix” technology, that offers modular features to enable scale up to transmission voltage levels. The SFCL consists of individual modules that contain elements and parallel inductors that assist in carrying the current during the fault. A number of these modules are arranged in an m x n array to form the current-limiting matrix.

  17. Radiation Shielding Utilizing A High Temperature Superconducting Magnet Project

    Data.gov (United States)

    National Aeronautics and Space Administration — This project aims to leverage near-term high-temperature superconducting technologies to assess applicability of magnetic shielding for protecting against exposure...

  18. Micromachined High-Temperature Sensors for Planet Exploration Project

    Data.gov (United States)

    National Aeronautics and Space Administration — In phase I of the SBIR program, LEEOAT Company will develop, simulate, fabricate and test high-temperature piezoelectric miniature sensors (up to 800oC), for...

  19. Heat exchangers and recuperators for high temperature waste gases

    Science.gov (United States)

    Meunier, H.

    General considerations on high temperature waste heat recovery are presented. Internal heat recovery through combustion air preheating and external heat recovery are addressed. Heat transfer and pressure drop in heat exchanger design are discussed.

  20. High Temperature Membrane with Humidification-Independent Cluster Structure

    Energy Technology Data Exchange (ETDEWEB)

    Lipp, Ludwig [FuelCell Energy, Inc., Danbury, CT (United States)

    2015-07-10

    The objective of this project was to develop high temperature membranes to facilitate the wide-spread deployment of hydrogen fuel cells. High temperature membranes offer significant advantages in PEM system operation, overall capital and operating costs. State-of-the-art Nafion-based membranes are inadequate for the high temperature operation. These conventional membranes become unstable at higher temperatures (90-120°C) and lose their conductivity, particularly at low relative humidity. In this program, alternate materials were developed to enable fabrication of novel high performance composite membranes. FCE’s concept for the multi-component composite membrane, named mC2, has been used in the design of more conductive membranes.

  1. Leaders in high temperature superconductivity commercialization win superconductor industry award

    CERN Multimedia

    2007-01-01

    CERN's Large Hadron Collider curretn leads project head Amalia Ballarino named superconductor industry person of the year 2006. Former high temperature superconductivity program manager at the US Department of energy James Daley wins lifetime achievement award. (1,5 page)

  2. Planar high temperature superconductor filters with backside coupling

    Science.gov (United States)

    Shen, Zhi-Yuan (Inventor)

    1998-01-01

    An improved high temperature superconducting planar filter wherein the coupling circuit or connecting network is located, in whole or in part, on the side of the substrate opposite the resonators and enables higher power handling capability.

  3. High Temperature Radiators for Electric Propulsion Systems Project

    Data.gov (United States)

    National Aeronautics and Space Administration — The VASIMR propulsion system uses a high temperature Loop Heat Pipe (LHP) radiator to reject heat from the helicon section. The current baseline radiator uses...

  4. High Power Room Temperature Terahertz Local Oscillator Project

    Data.gov (United States)

    National Aeronautics and Space Administration — We propose to build a high-power, room temperature compact continuous wave terahertz local oscillator for driving heterodyne receivers in the 1-5 THz frequency...

  5. High Temperature Sound Absorption Coating - Soundown HT Project

    Data.gov (United States)

    National Aeronautics and Space Administration — MPAC and UMR are proposing development of an Acoustic Control System for high temperature gas flow in ducts. This control system is based on a passive inorganic...

  6. High Operating Temperature, Radiation-Hard MIM Thermophotovoltaic Converters Project

    Data.gov (United States)

    National Aeronautics and Space Administration — Spire Corporation proposes to investigate InGaAs thermophotovoltaic (TPV) cells optimized for high temperature operation (~150C) and radiation hardness against the...

  7. High Temperature Venus Drill and Sample Delivery System Project

    Data.gov (United States)

    National Aeronautics and Space Administration — We proposed to design, build and test a high temperature Pneumatic Drill and Trencher system for Venus subsurface exploration. The Venus Drill and Trencher will be...

  8. Novel High Temperature Membrane for PEM Fuel Cells Project

    Data.gov (United States)

    National Aeronautics and Space Administration — The innovation proposed in this STTR program is a high temperature membrane to increase the efficiency and power density of PEM fuel cells. The NASA application is...

  9. High temperature and performance in a flight task simulator.

    Science.gov (United States)

    1972-05-01

    The effects of high cockpit temperature on physiological responses and performance were determined on pilots in a general aviation simulator. The pilots (all instrument rated) 'flew' an instrument flight while exposed to each of three cockpit tempera...

  10. Highly Effective Thermal Regenerator for Low Temperature Cryocoolers Project

    Data.gov (United States)

    National Aeronautics and Space Administration — Future missions to investigate the structure and evolution of the universe require highly efficient, low-temperature cryocoolers for low-noise detector systems. We...

  11. NOAA High-Resolution Sea Surface Temperature (SST) Analysis Products

    Data.gov (United States)

    National Oceanic and Atmospheric Administration, Department of Commerce — This archive covers two high resolution sea surface temperature (SST) analysis products developed using an optimum interpolation (OI) technique. The analyses have a...

  12. Thermodynamic Temperature of High-Temperature Fixed Points Traceable to Blackbody Radiation and Synchrotron Radiation

    Science.gov (United States)

    Wähmer, M.; Anhalt, K.; Hollandt, J.; Klein, R.; Taubert, R. D.; Thornagel, R.; Ulm, G.; Gavrilov, V.; Grigoryeva, I.; Khlevnoy, B.; Sapritsky, V.

    2017-10-01

    Absolute spectral radiometry is currently the only established primary thermometric method for the temperature range above 1300 K. Up to now, the ongoing improvements of high-temperature fixed points and their formal implementation into an improved temperature scale with the mise en pratique for the definition of the kelvin, rely solely on single-wavelength absolute radiometry traceable to the cryogenic radiometer. Two alternative primary thermometric methods, yielding comparable or possibly even smaller uncertainties, have been proposed in the literature. They use ratios of irradiances to determine the thermodynamic temperature traceable to blackbody radiation and synchrotron radiation. At PTB, a project has been established in cooperation with VNIIOFI to use, for the first time, all three methods simultaneously for the determination of the phase transition temperatures of high-temperature fixed points. For this, a dedicated four-wavelengths ratio filter radiometer was developed. With all three thermometric methods performed independently and in parallel, we aim to compare the potential and practical limitations of all three methods, disclose possibly undetected systematic effects of each method and thereby confirm or improve the previous measurements traceable to the cryogenic radiometer. This will give further and independent confidence in the thermodynamic temperature determination of the high-temperature fixed point's phase transitions.

  13. Plasticity In High Temperature Materials: Tantalum and Monazite

    Science.gov (United States)

    2014-03-12

    AFRL-OSR-VA-TR-2014-0065 PLASTICITY IN HIGH TEMPERATURE MATERIALS: TANTALUM AND MONAZITE Jeffrey Kysar THE TRUSTEES OF COLUMBIA UNIVERSITY IN THE...Agency Air Force Office of Scientific Research Title of Project Plasticity in High Temperature Materials: Tantalum and Monazite February 28, 2014...centered cu- bic tantalum , the methodology also demonstrated a relationship between dislocation mean free path length and GND density. A framework to

  14. High temperature resistant nanofiber by bubbfil-spinning

    Directory of Open Access Journals (Sweden)

    Li Ya

    2015-01-01

    Full Text Available Heat-resisting nanofibers have many potential applications in various industries, and the bubbfil spinning is the best candidate for mass-production of such materials. Polyether sulfone/zirconia solution with a bi-solvent system is used in the experiment. Experimental result reveals that polyether sulfone/zirconia nanofibers have higher resistance to high temperature than pure polyether sulfone fibers, and can be used as high-temperature-resistant filtration materials.

  15. High-Temperature Luminescence Quenching of Colloidal Quantum Dots

    OpenAIRE

    Zhao, Y.; Riemersma, C.; Pietra, F; de Mello Donega, C.; Meijerink, A.

    2012-01-01

    Thermal quenching of quantum dot (QD) luminescence is important for application in luminescent devices. Systematic studies of the quenching behavior above 300 K are, however, lacking. Here, high-temperature (300–500 K) luminescence studies are reported for highly efficient CdSe core–shell quantum dots (QDs), aimed at obtaining insight into temperature quenching of QD emission. Through thermal cycling (yoyo) experiments for QDs in polymer matrices, reversible and irreversible luminescence quen...

  16. High temperature deformation mechanisms of cemented carbides and cermets

    OpenAIRE

    Buss, Katharina

    2004-01-01

    The motivation of this work derives from the need of the cutting tool industry to improve its products in order to support harder and harder working conditions, namely increasing cutting speeds and working on stronger modern materials. The lifetime of the tools is limited by plastic deformation that occurs at the cutting edge under working conditions, which involve high temperatures and stresses. The high temperature deformation of the materials that are used for the production of cutting too...

  17. Packaging Technologies for High Temperature Electronics and Sensors

    Science.gov (United States)

    Chen, Liangyu; Hunter, Gary W.; Neudeck, Philip G.; Beheim, Glenn M.; Spry, David J.; Meredith, Roger D.

    2013-01-01

    This paper reviews ceramic substrates and thick-film metallization based packaging technologies in development for 500degC silicon carbide (SiC) electronics and sensors. Prototype high temperature ceramic chip-level packages and printed circuit boards (PCBs) based on ceramic substrates of aluminum oxide (Al2O3) and aluminum nitride (AlN) have been designed and fabricated. These ceramic substrate-based chiplevel packages with gold (Au) thick-film metallization have been electrically characterized at temperatures up to 550degC. A 96% alumina based edge connector for a PCB level subsystem interconnection has also been demonstrated recently. The 96% alumina packaging system composed of chip-level packages and PCBs has been tested with high temperature SiC devices at 500degC for over 10,000 hours. In addition to tests in a laboratory environment, a SiC JFET with a packaging system composed of a 96% alumina chip-level package and an alumina printed circuit board mounted on a data acquisition circuit board was launched as a part of the MISSE-7 suite to the International Space Station via a Shuttle mission. This packaged SiC transistor was successfully tested in orbit for eighteen months. A spark-plug type sensor package designed for high temperature SiC capacitive pressure sensors was developed. This sensor package combines the high temperature interconnection system with a commercial high temperature high pressure stainless steel seal gland (electrical feed-through). Test results of a packaged high temperature capacitive pressure sensor at 500degC are also discussed. In addition to the pressure sensor package, efforts for packaging high temperature SiC diode-based gas chemical sensors are in process.

  18. Process for Forming a High Temperature Single Crystal Canted Spring

    Science.gov (United States)

    DeMange, Jeffrey J (Inventor); Ritzert, Frank J (Inventor); Nathal, Michael V (Inventor); Dunlap, Patrick H (Inventor); Steinetz, Bruce M (Inventor)

    2017-01-01

    A process for forming a high temperature single crystal canted spring is provided. In one embodiment, the process includes fabricating configurations of a rapid prototype spring to fabricate a sacrificial mold pattern to create a ceramic mold and casting a canted coiled spring to form at least one canted coil spring configuration based on the ceramic mold. The high temperature single crystal canted spring is formed from a nickel-based alloy containing rhenium using the at least one coil spring configuration.

  19. Comparison of the Microstructure and Segregation behavior between SA508 Gr.3 and SA508 Gr.4N High Strength Low Alloy RPV Steel

    Energy Technology Data Exchange (ETDEWEB)

    Park, Sang Gyu; Wee, Dang Moon [KAIST, Daejeon (Korea, Republic of); Kim, Min Chul; Lee, Bong Sang [Korea Atomic Energy Research Institute, Daejeon (Korea, Republic of)

    2010-05-15

    It is generally known that SA508 Gr.4N low alloy steel has an improved fracture toughness and strength, compared to commercial low alloy steels such as SA508 Gr.3 which have lower than 1% Ni. Higher strength and fracture toughness of low alloy steels could be achieved by adding Ni and Cr. So there are several researches on SA508 Gr.4N low alloy steel for a RPV application. The operation temperature and time of a reactor pressure vessel is more than 300 .deg. C and over 40 years. Therefore, in order to apply the SA508 Gr.4N low alloy steel for a reactor pressure vessel, it requires a phase stability in the high temperature range including temper embrittlement resistance. S. Raoul reported that the susceptibility to temper embrittlement was increasing an function of the cooling rate in SA533 steel, which suggests the martensitic microstructures resulting from increased cooling rates are more susceptible to temper embrittlement. However, this result has not been proved yet. So comparison was made between the temper embrittlement behaviors of SA508 Gr.3 and Gr.4N low alloy steel with a viewpoint of boundary features, which have different microstructures of tempered bainite(SA508 Gr.3) and tempered martensite(SA508 Gr.4N). In this study, we have compared temper embrittlement behaviors of SA508 Gr.3 and SA508 Gr.4N low alloy steel. The mechanical properties of these low alloy steels after a long-term heat treatment(450 .deg. C, 2000hr) were evaluated. Then, the images of the fracture surfaces were observed and grain boundary segregation was analyzed by AES. In order to compare the misorientation distributions of two model alloys, the grain boundary structures of the low alloy steels with EBSD were measured

  20. Fiber optic, Fabry-Perot high temperature sensor

    Science.gov (United States)

    James, K.; Quick, B.

    1984-01-01

    A digital, fiber optic temperature sensor using a variable Fabry-Perot cavity as the sensor element was analyzed, designed, fabricated, and tested. The fiber transmitted cavity reflection spectra is dispersed then converted from an optical signal to electrical information by a charged coupled device (CCD). A microprocessor-based color demodulation system converts the wavelength information to temperature. This general sensor concept not only utilizes an all-optical means of parameter sensing and transmitting, but also exploits microprocessor technology for automated control, calibration, and enhanced performance. The complete temperature sensor system was evaluated in the laboratory. Results show that the Fabry-Perot temperature sensor has good resolution (0.5% of full seale), high accuracy, and potential high temperature ( 1000 C) applications.

  1. Structural stability of high entropy alloys under pressure and temperature

    DEFF Research Database (Denmark)

    Ahmad, Azkar S.; Su, Y.; Liu, S. Y.

    2017-01-01

    The stability of high-entropy alloys (HEAs) is a key issue before their selection for industrial applications. In this study, in-situ high-pressure and high-temperature synchrotron radiation X-ray diffraction experiments have been performed on three typical HEAs Ni20Co20Fe20Mn20Cr20, Hf25Nb25Zr25Ti...

  2. Design of Experiment Approach to Hydrogen Re-embrittlement Evaluation WP-2152

    Science.gov (United States)

    2015-04-01

    aircraft components they do not cause embrittlement of the steel. Therefore, aircraft maintenance chemicals (cleaners, deicers, paint strippers ...this work. Mr Richard Green of Green Specialty Service and Mr Craig Willan of Omega Research Inc. are acknowledged for the material specimens and

  3. Influence of physical aging on impact embrittlement of uPVC pipes

    NARCIS (Netherlands)

    Visser, Roy; Bor, Teunis Cornelis; Wolters, Mannes; Warnet, Laurent; Govaert, L.E.

    2011-01-01

    Most failures of unplasticised poly(vinyl chloride) (uPVC) pipes used in the Dutch gas distribution network originate from third party damage. Brittle pipes should therefore be replaced to ensure safe operation of the network. In this study, the relation between physical aging and embrittlement of

  4. High temperature measurements in irradiated environment using Raman fiber optics distributed temperature sensing

    Science.gov (United States)

    Lecomte, Pierre; Blairon, Sylvain; Boldo, Didier; Taillade, Frédéric; Caussanel, Matthieu; Beauvois, Gwendal; Duval, Hervé; Grieu, Stéphane; Laffont, Guillaume; Lainé, Frédéric; Carrel, Frédéric

    2016-04-01

    Optical fiber temperature sensors using Raman effect are a promising technology for temperature mapping of nuclear power plant pipes. These pipes are exposed to high temperature (350 °C) and gamma radiations, which is a harsh environment for standard telecom fibers. Therefore metal coated fibers are to be used to perform measurement over 300 °C. Temperature variations can affect the attenuation of the metallic coated fiber before irradiation. The latter induces an extra attenuation, due to light absorption along the fiber by radiation-induced defects. The recombination of these defects can be strongly accelerated by the high temperature value. As backscattered Raman signal is weak it is important to test optical fibers under irradiation to observe how it gets attenuated. Different experiments are described in this conference paper: two in situ irradiation campaigns with different dose rates at, both ambient and high temperature. We observe that the tested off-the-shelf metallic coated fibers have a high attenuation under irradiation. We also noticed the fact that thermal annealing plays a massive role in the +300 °C temperature range.

  5. Innovative Instrumentation and Analysis of the Temperature Measurement for High Temperature Gasification

    Energy Technology Data Exchange (ETDEWEB)

    Seong W. Lee

    2005-10-01

    The objectives of this project during this semi-annual reporting period are to test the effects of coating layer of the thermal couple on the temperature measurement and to screen out the significant factors affecting the temperature reading under different operational conditions. The systematic tests of the gasifier simulator on the high velocity oxygen fuel (HVOF) spray coated thermal couples were completed in this reporting period. The comparison tests of coated and uncoated thermal couples were conducted under various operational conditions. The temperature changes were recorded and the temperature differences were calculated to describe the thermal spray coating effect on the thermal couples. To record the temperature data accurately, the computerized data acquisition system (DAS) was adopted to the temperature reading. The DAS could record the data with the accuracy of 0.1 C and the recording parameters are configurable. In these experiments, DAS was set as reading one data for every one (1) minute. The operational conditions are the combination of three parameters: air flow rate, water/ammonia flow rate and the amount of fine dust particles. The results from the temperature readings show the temperature of uncoated thermal couple is uniformly higher than that of coated thermal couple for each operational condition. Analysis of Variances (ANOVA) was computed based on the results from systematic tests to screen out the significant factors and/or interactions. The temperature difference was used as dependent variable and three operational parameters (i.e. air flow rate, water/ammonia flow rate and amount of fine dust particle) were used as independent factors. The ANOVA results show that the operational parameters are not the statistically significant factors affecting the temperature readings which indicate that the coated thermal couple could be applied to temperature measurement in gasifier. The actual temperature reading with the coated thermal couple in

  6. Sapphire-fiber-based distributed high-temperature sensing system.

    Science.gov (United States)

    Liu, Bo; Yu, Zhihao; Hill, Cary; Cheng, Yujie; Homa, Daniel; Pickrell, Gary; Wang, Anbo

    2016-09-15

    We present, for the first time to our knowledge, a sapphire-fiber-based distributed high-temperature sensing system based on a Raman distributed sensing technique. High peak power laser pulses at 532 nm were coupled into the sapphire fiber to generate the Raman signal. The returned Raman Stokes and anti-Stokes signals were measured in the time domain to determine the temperature distribution along the fiber. The sensor was demonstrated from room temperature up to 1200°C in which the average standard deviation is about 3.7°C and a spatial resolution of about 14 cm was achieved.

  7. High temperature fracture characteristics of a nanostructured ferritic alloy (NFA)

    Science.gov (United States)

    Byun, Thak Sang; Kim, Jeoung Han; Yoon, Ji Hyun; Hoelzer, David T.

    2010-12-01

    The nanostructured ferritic alloys (NFAs) have been developed to improve high temperature strength and radiation resistance by refining grains and including nanoclusters. Among the key properties of NFAs needed to be assessed for advanced reactor applications the cracking resistance at high temperatures has not been well known. In this work, therefore, the high temperature fracture behavior has been investigated for the latest nanostructured ferritic alloy 14YWT (SM10). The fracture toughness of the alloy was above 140 MPa √m at low temperatures, room temperature (RT) and 200 °C, but decreased to a low fracture toughness range of 52-82 MPa √m at higher temperatures up to 700 °C. This behavior was explained by the fractography results indicating that the unique nanostructure of 14YWT alloy produced shallow plasticity layers at high temperatures and a low-ductility grain boundary debonding occurred at 700 °C. The discussion also proposes methods to improve resistance to cracking.

  8. Phase Evolution of Hydrous Enstatite at High Pressures and Temperatures

    Science.gov (United States)

    Xu, J.; Zhang, D.; Dera, P.; Zhang, J.; Fan, D.

    2016-12-01

    Pyroxenes, including Mg-rich orthopyroxene and Ca-rich clinopyroxene, are among the most important minerals in the Earth's upper mantle (account for 20% by volume). Pyroxenes are major phases of harzburgite and lherzolite, which are important components of subducting slabs, so the high pressure behavior of pyroxenes should influence the physical properties of the subducted slabs. Therefore, understanding the phase evolution and thermal equations of state and of pyroxenes at elevated pressure and temperature is crucial to model theupper mantle and subduction zones. On the other hand, water is expected to be incorporated into pyroxene minerals in the upper mantle environments, yet the effect of water on the high pressure behavior of pyroxene has not been fully explored. In this study, we conducted high-pressure single-crystal X-ray diffraction study on hydrous enstatite sample (Mg2Si2O6) at ambient and high temperatures. High-pressure single-crystal diffraction experiments at ambient temperature were performed to 30 GPa at the experimental station 13BMC of the Advanced Photon Source. Two phase transformations were detected within the pressure range. High-pressure and high-temperature single crystal diffraction experiments were conducted to 27 GPa and 700 K also at 13BMC. From the experimental data, we derived the thermoelastic parameters of enstatite and performed structural refinements of enstatite at high pressures and temperatures, which is of implication for understanding of geophysics and geochemistry of subducting slabs.

  9. High Temperature, High Frequency Fuel Metering Valve Project

    Data.gov (United States)

    National Aeronautics and Space Administration — Active Signal Technologies and its subcontractor Moog propose to develop a high-frequency actuator driven valve intended to achieve TRL 6 by the end of Phase II....

  10. Temperature Stabilized Characterization of High Voltage Power Supplies

    CERN Document Server

    Krarup, Ole

    2017-01-01

    High precision measurements of the masses of nuclear ions in the ISOLTRAP experiment relies on an MR-ToF. A major source of noise and drift is the instability of the high voltage power supplies employed. Electrical noise and temperature changes can broaden peaks in time-of-flight spectra and shift the position of peaks between runs. In this report we investigate how the noise and drift of high-voltage power supplies can be characterized. Results indicate that analog power supplies generally have better relative stability than digitally controlled ones, and that the high temperature coefficients of all power supplies merit efforts to stabilize them.

  11. Analysis on High Temperature Aging Property of Self-brazing Aluminum Honeycomb Core at Middle Temperature

    Directory of Open Access Journals (Sweden)

    ZHAO Huan

    2016-11-01

    Full Text Available Tension-shear test was carried out on middle temperature self-brazing aluminum honeycomb cores after high temperature aging by micro mechanical test system, and the microstructure and component of the joints were observed and analyzed using scanning electron microscopy and energy dispersive spectroscopy to study the relationship between brazing seam microstructure, component and high temperature aging properties. Results show that the tensile-shear strength of aluminum honeycomb core joints brazed by 1060 aluminum foil and aluminum composite brazing plate after high temperature aging(200℃/12h, 200℃/24h, 200℃/36h is similar to that of as-welded joints, and the weak part of the joint is the base metal which is near the brazing joint. The observation and analysis of the aluminum honeycomb core microstructure and component show that the component of Zn, Sn at brazing seam is not much affected and no compound phase formed after high temperature aging; therefore, the main reason for good high temperature aging performance of self-brazing aluminum honeycomb core is that no obvious change of brazing seam microstructure and component occurs.

  12. Signature of electron-phonon interaction in high temperature superconductors

    Directory of Open Access Journals (Sweden)

    Vinod Ashokan

    2011-09-01

    Full Text Available The theory of thermal conductivity of high temperature superconductors (HTS based on electron and phonon line width (life times formulation is developed with Quantum dynamical approach of Green's function. The frequency line width is observed as an extremely sensitive quantity in the transport phenomena of HTS as a collection of large number of scattering processes. The role of resonance scattering and electron-phonon interaction processes is found to be most prominent near critical temperature. The theory successfully explains the spectacular behaviour of high Tc superconductors in the vicinity of transition temperature. A successful agreement between theory and experiment has been obtained by analyzing the thermal conductivity data for the sample La1.8Sr0.2CuO4 in the temperature range 0 − 200K. The theory is equally and successfully applicable to all other high Tc superconductors.

  13. Structure of liquid oxides at very high temperatures

    CERN Document Server

    Landron, C; Thiaudiere, D; Price, D L; Greaves, G N

    2003-01-01

    The structural characterization of condensed matter by synchrotron radiation combined with neutron data constitutes a powerful structural tool in material science. In order to investigate refractory liquids at very high temperatures, we have developed a new analysis chamber for performing combined X-ray absorption and diffraction measurements by using laser heating and aerodynamic levitation. A similar system has been designed for neutron experiments. This high temperature equipment presents several advantages: the container does not physically or chemically perturb the sample, heterogeneous nucleation during cooling is suppressed and pollution by the container is removed. This cell can operate under various gas conditions from room temperature up to 3000 deg. C obtained by means of a sealed 125 W CO sub 2 laser. Experiments have been performed at LURE, ESRF and at ISIS. We have studied the local structure around the cations in several liquid and solid oxides. We have shown that high temperature synchrotron d...

  14. Improved controlled atmosphere high temperature scanning probe microscope

    DEFF Research Database (Denmark)

    Hansen, Karin Vels; Wu, Yuehua; Jacobsen, Torben

    2013-01-01

    ) is monitored by an oxygen sensor. We present here some examples of its capabilities demonstrated by high temperature topography with simultaneously ac electrical conductance measurements during atmosphere changes, electrochemical impedance spectroscopy at various temperatures, and measurements of the surface......To locally access electrochemical active surfaces and interfaces in operando at the sub-micron scale at high temperatures in a reactive gas atmosphere is of great importance to understand the basic mechanisms in new functional materials, for instance, for energy technologies, such as solid oxide...... fuel cells and electrolyzer cells. Here, we report on advanced improvements of our original controlled atmosphere high temperature scanning probe microscope, CAHT-SPM. The new microscope can employ a broad range of the scanning probe techniques including tapping mode, scanning tunneling microscopy...

  15. High-temperature injury and auxin biosynthesis in microsporogenesis.

    Directory of Open Access Journals (Sweden)

    Atsushi eHigashitani

    2013-03-01

    Full Text Available Plant reproductive development is more sensitive than vegetative growth to many environmental stresses. With global warming, in particular, plant high temperature injury is becoming an increasingly serious problem. In wheat, barley, and various other commercially important crops, the early phase of anther development is especially susceptible to high temperatures. We recently demonstrated that high temperature causes cell-proliferation arrest and represses auxin signaling in a tissue-specific manner of the anther cells of barley and Arabidopsis. These phenomena were accompanied by comprehensive alterations in transcription including repression of cell-proliferation related genes and YUCCA auxin biosynthesis genes. Moreover, application of auxin completely improved the transcriptional alterations, the production of normal pollen grains, and seed setting rate under increasing temperatures. These denote that auxin, which has been used widely as potent and selective herbicides, is useful for the promotion of plant fertility and maintenance of crop yields under the global warming conditions.

  16. Handbook of high-temperature superconductivity theory and experiment

    CERN Document Server

    Brooks, James S

    2007-01-01

    Since the 1980s, a general theme in the study of high-temperature superconductors has been to test the BCS theory and its predictions against new data. At the same time, this process has engendered new physics, new materials, and new theoretical frameworks. Remarkable advances have occurred in sample quality and in single crystals, in hole and electron doping in the development of sister compounds with lower transition temperatures, and in instruments to probe structure and dynamics. Handbook of High-Temperature Superconductvity is a comprehensive and in-depth treatment of both experimental and theoretical methodologies by the the world's top leaders in the field. The Editor, Nobel Laureate J. Robert Schrieffer, and Associate Editor James S. Brooks, have produced a unified, coherent work providing a global view of high-temperature superconductivity covering the materials, the relationships with heavy-fermion and organic systems, and the many formidable challenges that remain.

  17. The application of high temperature elastomer PCP in CSS wells

    Energy Technology Data Exchange (ETDEWEB)

    Zhang, S.; Song, F.; Wu, F.; Luo, E. [Petro-China, Liaohe (China). Liaohe Oilfield Co.; Seince, L.; Wu, B. [PCM, Vanves (France); Xiao, J.H. [Andmir Environmental Group, Calgary, AB (Canada)

    2009-07-01

    Progressive cavity pumps (PCPs) are now widely used in oil field applications. This paper discussed the feasibility of using a high temperature elastomer PCP in cyclic steam stimulation (CSS) applications. Data were obtained for fluid yields, speed, and wellhead temperature and dynamics. The study showed that during the initial production phase, wellhead temperature reached 80 degrees C. Water was injected to reduce the temperature to under 70 degrees C. The well has been operational for a period of 10 months. A second trial with a PCP with steam injection parameters of 14.6 MPa, a flow rate of 15.7 ton/h, and total steam injection of 1451 tonnes was then conducted. A set of optical fibres was used to obtain downhole temperature distribution data. The well has now been operational for more than 6 months, yielding 44.7 tonnes of fluid per day, with a daily oil yield of 14.8 tonnes per day. Actual pump-depth temperature before the pump start up was 98 degrees C. After start-up, actual pump depth temperatures reached 145 degrees C, which was decreased over time to 125 degrees C. It was concluded that the pumps are capable of withstanding the high temperature CSS environment. 8 refs., 1 tab., 4 figs.

  18. INNOVATIVE INSTRUMENTATION AND ANALYSIS OF THE TEMPERATURE MEASUREMENT FOR HIGH TEMPERATURE GASIFICATION

    Energy Technology Data Exchange (ETDEWEB)

    Seong W. Lee

    2005-04-01

    The systematic tests of the gasifier simulator on the ultrasonic vibration application for cleaning method were completed in this reporting period. Within the systematic tests on the ultrasonic vibration application, the ambient temperature and high temperature status condition were tested separately. The sticky dirt on the thermocouple tip was simulated by the cement-covered layer on the thermocouple tip. At the ambient temperature status, four (4) factors were considered as the input factors affecting the response variable of peeling off rate. The input factors include the shape of the cement-covered layer (thickness and length), the ultrasonic vibration output power, and application time. At the high temperature tests, four (4) different environments were considered as the experimental parameters including air flow supply, water and air supply environment, water/air/fine dust particle supply, and air/water/ammonia/fine dust particle supply environment. The factorial design method was used in the experiment design with twelve (12) data sets of readings. Analysis of Variances (ANOVA) was applied to the results from systematic tests. The ANOVA results show that the thickness and length of the cement-covered layer have the significant impact on the peeling off rate of ultrasonic vibration application at the ambient temperature environment. For the high temperature tests, the different environments do not seem to have significant impact on the temperature changes. These results may indicate that the ultrasonic vibration is one of best cleaning methods for the thermocouple tip.

  19. Investigation of moisture-induced embrittlement of iron aluminides. Final report

    Energy Technology Data Exchange (ETDEWEB)

    Alven, D.A.; Stoloff, N.S. [Rensselaer Polytechnic Inst., Troy, NY (United States). Materials Engineering Dept.

    1997-06-05

    Iron-aluminum alloys with 28 at.% Al and 5 at.% Cr were shown to be susceptible to hydrogen embrittlement by exposure to both gaseous hydrogen and water vapor. This study examined the effect of the addition of zirconium and carbon on the moisture-induced hydrogen embrittlement of an Fe{sub 3}Al,Cr alloy through the evaluation of tensile properties and fatigue crack growth resistance in hydrogen gas and moisture-bearing air. Susceptibility to embrittlement was found to vary with the zirconium content while the carbon addition was found to only affect the fracture toughness. Inherent fatigue crack growth resistance and fracture toughness, as measured in an inert environment, was found to increase with the addition of 0.5 at.% Zr. The combined addition of 0.5 at.% Zr and carbon only increased the fracture toughness. The addition of 1 at.% Zr and carbon was found to have no effect on the crack growth rate when compared to the base alloy. Susceptibility to embrittlement in moisture-bearing environments was found to decrease with the addition of 0.5 at.% Zr. In gaseous hydrogen, the threshold value of the Zr-containing alloys was found to increase above that found in the inert environment while the crack growth resistance was much lower. By varying the frequency of fatigue loading, it was shown that the corrosion fatigue component of the fatigue crack growth rate in an embrittling environment displays a frequency dependence. Hydrogen transport in iron aluminides was shown to occur primarily by a dislocation-assisted transport mechanism. This mechanism, in conjunction with fractography, indicates that the zirconium-containing precipitates act as traps for the hydrogen that is carried along by the dislocations through the lattice.

  20. Film collapse behavior on high temperature particle surface

    Energy Technology Data Exchange (ETDEWEB)

    Tochio, Daisuke; Abe, Yutaka [Department of Mechanical Systems Engineering, Yamagata University, Yonezawa, Yamagata (Japan)

    1999-07-01

    It is pointed out that large-scale vapor explosion may occurred during a severe accident of a nuclear power plant. It is important to predict the possibility of the vapor explosion for the accident management of the nuclear power plant during a severe accident. The thermal detonation model is proposed to predict the vapor explosion. In the thermal detonation model, vapor explosion is started by a trigger. The trigger is vapor film collapse around high temperature material droplets coarsely pre-mixed in low temperature liquid. In the premixing stage, high temperature material droplets are insulated from low temperature liquid by the vapor film. Once the vapor film is collapsed, very quick and large heat transfer starts followed by the atomization. In order to clarify the trigger condition of the vapor explosion, it is necessary to identify the mechanism of the film collapse on the high temperature droplet surface in low temperature particle surface. Since the steam film on a high temperature droplet is unstable in high subcooling condition of low temperature liquid, the possibility of the self-collapse of the steam film is high. On the other hand, the possibility of the film collapse is not high in low subcooling or saturated condition since the steam film is tough. There are many experimental studies on the vapor film collapse behavior on the high temperature material surface. Most of those studies, vapor film collapse follows by the atomization , since melted droplets are used in those experiments. And the experiments used solid material is limited for the cylindrical or flat plate geometry. At present, there is no experimental database on the microscopic mechanism of steam film collapse behavior in spherical geometry for wide range of subcooling conditions. In the present study, steam film collapse behavior on a stainless steel particle surface is experimentally investigated. The stainless steel particle heated up by a burner is immersed into water in a stainless