High temperature materials and mechanisms

CERN Document Server

2014-01-01

The use of high-temperature materials in current and future applications, including silicone materials for handling hot foods and metal alloys for developing high-speed aircraft and spacecraft systems, has generated a growing interest in high-temperature technologies. High Temperature Materials and Mechanisms explores a broad range of issues related to high-temperature materials and mechanisms that operate in harsh conditions. While some applications involve the use of materials at high temperatures, others require materials processed at high temperatures for use at room temperature. High-temperature materials must also be resistant to related causes of damage, such as oxidation and corrosion, which are accelerated with increased temperatures. This book examines high-temperature materials and mechanisms from many angles. It covers the topics of processes, materials characterization methods, and the nondestructive evaluation and health monitoring of high-temperature materials and structures. It describes the ...

Characteristics of Syngas Auto-ignition at High Pressure and Low Temperature Conditions with Thermal Inhomogeneities

KAUST Repository

Pal, Pinaki; Mansfield, Andrew B.; Wooldridge, Margaret S.; Im, Hong G.

2015-01-01

Effects of thermal inhomogeneities on syngas auto-ignition at high-pressure low-temperature conditions, relevant to gas turbine operation, are investigated using detailed one-dimensional numerical simulations. Parametric tests are carried out for a range of thermodynamic conditions (T = 890-1100 K, P = 3-20 atm) and composition (Ф = 0.1, 0.5). Effects of global thermal gradients and localized thermal hot spots are studied. In the presence of a thermal gradient, the propagating reaction front transitions from spontaneous ignition to deflagration mode as the initial mean temperature decreases. The critical mean temperature separating the two distinct auto-ignition modes is computed using a predictive criterion and found to be consistent with front speed and Damkohler number analyses. The hot spot study reveals that compression heating of end-gas mixture by the propagating front is more pronounced at lower mean temperatures, significantly advancing the ignition delay. Moreover, the compression heating effect is dependent on the domain size.

Characteristics of Syngas Auto-ignition at High Pressure and Low Temperature Conditions with Thermal Inhomogeneities

KAUST Repository

Pal, Pinaki

2015-05-31

Effects of thermal inhomogeneities on syngas auto-ignition at high-pressure low-temperature conditions, relevant to gas turbine operation, are investigated using detailed one-dimensional numerical simulations. Parametric tests are carried out for a range of thermodynamic conditions (T = 890-1100 K, P = 3-20 atm) and composition (Ф = 0.1, 0.5). Effects of global thermal gradients and localized thermal hot spots are studied. In the presence of a thermal gradient, the propagating reaction front transitions from spontaneous ignition to deflagration mode as the initial mean temperature decreases. The critical mean temperature separating the two distinct auto-ignition modes is computed using a predictive criterion and found to be consistent with front speed and Damkohler number analyses. The hot spot study reveals that compression heating of end-gas mixture by the propagating front is more pronounced at lower mean temperatures, significantly advancing the ignition delay. Moreover, the compression heating effect is dependent on the domain size.

Features, present condition of development and future scope on the high temperature gas reactor as an innovative one

International Nuclear Information System (INIS)

Shiozawa, Shusaku

2001-01-01

The high temperature gas reactor has some features without previous reactors such as high temperature capable of taking-out, high specific safety, feasibility adaptable to versatile fuel cycle, and so on. Then, it is expected to be an innovative reactor to contribute to diversification of energy supply and expansion of energy application field. In Japan, under the HTTR (high temperature engineering test reactor) plan, construction of HTTR, which is the first high temperature gas reactor in Japan, was finished and its output upgrading test has been promoted. And, on the HTTR plan, together with promotion of full power operation, reactor performance tests, safety proof test, and so on, it is planned to carry out study on application of the high temperature heat such as hydrogen production and so on to aim to practise establishment and upgrading of technologies on high temperature gas reactor in Japan. Here were introduced features and present condition of development of the high temperature gas reactor as an innovative type reactor and described role and future scope in Japan. (G.K.)

CFD investigating the effects of different operating conditions on the performance and the characteristics of a high-temperature PEMFC

International Nuclear Information System (INIS)

Su, A.; Ferng, Y.M.; Shih, J.C.

2010-01-01

The effects of different operating conditions on the performance and the characteristics of a high-temperature proton exchange membrane fuel cell (PEMFC) are investigated using a three-dimensional (3-D) computational fluid dynamics (CFD) fuel-cell model. This model consists of the thermal-hydraulic equations and the electrochemical equations. Different operating conditions studied in this paper include the inlet gas temperature, system pressure, and inlet gas flow rate, respectively. Corresponding experiments are also carried out to assess the accuracy of this CFD model. Under the different operating conditions, the PEMFC performance curves predicted by the model correspond well with the experimentally measured ones. The performance of PEMFC is improved as the increase in the inlet temperature, system pressure or flow rate, which is precisely captured by the CFD fuel cell model. In addition, the concentration polarization caused by the insufficient supply of fuel gas can be also simulated as the high-temperature PEMFC is operated at the higher current density. Based on the calculation results, the localized thermal-hydraulic characteristics within a PEMFC can be reasonably captured. These characteristics include the fuel gas distribution, temperature variation, liquid water saturation distribution, and membrane conductivity, etc.

Maximum vehicle cabin temperatures under different meteorological conditions

Science.gov (United States)

Grundstein, Andrew; Meentemeyer, Vernon; Dowd, John

2009-05-01

A variety of studies have documented the dangerously high temperatures that may occur within the passenger compartment (cabin) of cars under clear sky conditions, even at relatively low ambient air temperatures. Our study, however, is the first to examine cabin temperatures under variable weather conditions. It uses a unique maximum vehicle cabin temperature dataset in conjunction with directly comparable ambient air temperature, solar radiation, and cloud cover data collected from April through August 2007 in Athens, GA. Maximum cabin temperatures, ranging from 41-76°C, varied considerably depending on the weather conditions and the time of year. Clear days had the highest cabin temperatures, with average values of 68°C in the summer and 61°C in the spring. Cloudy days in both the spring and summer were on average approximately 10°C cooler. Our findings indicate that even on cloudy days with lower ambient air temperatures, vehicle cabin temperatures may reach deadly levels. Additionally, two predictive models of maximum daily vehicle cabin temperatures were developed using commonly available meteorological data. One model uses maximum ambient air temperature and average daily solar radiation while the other uses cloud cover percentage as a surrogate for solar radiation. From these models, two maximum vehicle cabin temperature indices were developed to assess the level of danger. The models and indices may be useful for forecasting hazardous conditions, promoting public awareness, and to estimate past cabin temperatures for use in forensic analyses.

Effect of Water Vapor on High-Temperature Corrosion under Conditions Mimicking Biomass Firing

DEFF Research Database (Denmark)

Okoro, Sunday Chukwudi; Montgomery, Melanie; Jappe Frandsen, Flemming

2015-01-01

The variable flue gas composition in biomass-fired plants, among other parameters, contributes to the complexityof high-temperature corrosion of materials. Systematic parameter studies are thus necessary to understand the underlyingcorrosion mechanisms. This paper investigates the effect of water...... (H2O) vapor content in the flue gas on the high-temperaturecorrosion of austenitic stainless steel (TP 347H FG) under laboratory conditions, to improve the understanding of corrosionmechanisms. Deposit-coated and deposit-free samples were isothermally exposed for 72 h in a synthetic flue gas...... previouslyreported findings suggest that an increase in the water vapor content will cause competitive adsorption on active sites....

High temperature high vacuum creep testing facilities

International Nuclear Information System (INIS)

Matta, M.K.

1985-01-01

Creep is the term used to describe time-dependent plastic flow of metals under conditions of constant load or stress at constant high temperature. Creep has an important considerations for materials operating under stresses at high temperatures for long time such as cladding materials, pressure vessels, steam turbines, boilers,...etc. These two creep machines measures the creep of materials and alloys at high temperature under high vacuum at constant stress. By the two chart recorders attached to the system one could register time and temperature versus strain during the test . This report consists of three chapters, chapter I is the introduction, chapter II is the technical description of the creep machines while chapter III discuss some experimental data on the creep behaviour. Of helium implanted stainless steel. 13 fig., 3 tab

In Situ Observation of Gypsum-Anhydrite Transition at High Pressure and High Temperature

Institute of Scientific and Technical Information of China (English)

LIU Chuan-Jiang; ZHENG Hai-Fei

2012-01-01

An in-situ Raman spectroscopic study of gypsum-anhydrite transition under a saturated water condition at high pressure and high temperature is performed using a hydrothermal diamond anvil cell (HDAC).The experimental results show that gypsum dissolvs in water at ambient temperature and above 496 MPa.With increasing temperature,the anhydrite (CaSO4) phase precipitates at 250 320℃ in the pressure range of 1.0 1.5 GPa,indicating that under a saturated water condition,both stable conditions of pressure and temperature and high levels of Ca and SO4 ion concentrations in aqueous solution are essential for the formation of anhydrite.A linear relationship between the pressure and temperature for the precipitation of anhydrite is established as P(GPa) =0.0068T - 0.7126 (250℃≤T≤320℃).Anhydrite remained stable during rapid cooling of the sample chamber,showing that the gypsum-anhydrite transition involving both dissolution and precipitation processes is irreversible at high pressure and high temperature.%An in-situ Raman spectroscopic study of gypsum-anhydrite transition under a saturated water condition at high pressure and high temperature is performed using a hydrothermal diamond anvil cell (HDAC). The experimental results show that gypsum dissolvs in water at ambient temperature and above 496 Mpa. With increasing temperature, the anhydrite (CaSO4) phase precipitates at 250-320℃ in the pressure range of 1.0-1.5 Gpa, indicating that under a saturated water condition, both stable conditions of pressure and temperature and high levels of Ca and SO4 ion concentrations in aqueous solution are essential for the formation of anhydrite. A linear relationship between the pressure and temperature for the precipitation of anhydrite is established as P(Gpa) = 0.0068T - 0.7126 (250℃≤T≤320℃). Anhydrite remained stable during rapid cooling of the sample chamber, showing that the gypsum-anhydrite transition involving both dissolution and precipitation processes is

Thermophysical Properties Measurement of High-Temperature Liquids Under Microgravity Conditions in Controlled Atmospheric Conditions

Science.gov (United States)

Watanabe, Masahito; Ozawa, Shumpei; Mizuno, Akotoshi; Hibiya, Taketoshi; Kawauchi, Hiroya; Murai, Kentaro; Takahashi, Suguru

2012-01-01

Microgravity conditions have advantages of measurement of surface tension and viscosity of metallic liquids by the oscillating drop method with an electromagnetic levitation (EML) device. Thus, we are preparing the experiments of thermophysical properties measurements using the Materials-Science Laboratories ElectroMagnetic-Levitator (MSL-EML) facilities in the international Space station (ISS). Recently, it has been identified that dependence of surface tension on oxygen partial pressure (Po2) must be considered for industrial application of surface tension values. Effect of Po2 on surface tension would apparently change viscosity from the damping oscillation model. Therefore, surface tension and viscosity must be measured simultaneously in the same atmospheric conditions. Moreover, effect of the electromagnetic force (EMF) on the surface oscillations must be clarified to obtain the ideal surface oscillation because the EMF works as the external force on the oscillating liquid droplets, so extensive EMF makes apparently the viscosity values large. In our group, using the parabolic flight levitation experimental facilities (PFLEX) the effect of Po2 and external EMF on surface oscillation of levitated liquid droplets was systematically investigated for the precise measurements of surface tension and viscosity of high temperature liquids for future ISS experiments. We performed the observation of surface oscillations of levitated liquid alloys using PFLEX on board flight experiments by Gulfstream II (G-II) airplane operated by DAS. These observations were performed under the controlled Po2 and also under the suitable EMF conditions. In these experiments, we obtained the density, the viscosity and the surface tension values of liquid Cu. From these results, we discuss about as same as reported data, and also obtained the difference of surface oscillations with the change of the EMF conditions.

Interfacial tension measurement between CO2 and brines under high temperature and elevated pressure conditions

Science.gov (United States)

Li, X.; Boek, E. S.; Maitland, G. C.; Trusler, J. P. M.

2012-04-01

We have investigated the dependence of interfacial tension of (CO2 + brine) on temperature, pressure and salinity (including both salt type and molality) over the range of conditions applicable to CO2 storage in saline aquifers. The study covered a wide range of measurements of the interfacial tensions between carbon dioxide and (NaCl + KCl)(aq), CaCl2(aq), MgCl2(aq), Na2SO4(aq), KHCO3(aq), NaHCO3(aq) and two laboratory constructed brines with molality ranging from (0.3 to 5.0) mol·kg-1. The measurements were made at temperatures between (298 and 448) K at various pressures up to 50 MPa, using the pendant drop method in a high-pressure view cell filled with water-saturated CO2. The drop to be imaged was created by injecting brine from a high-pressure syringe pump into a capillary sealed through the top of the cell. The expanded uncertainties of the experimental state variables at 95 % confidence are +0.05 K in temperature and +70 kPa in pressure. For the interfacial tension, the overall expanded relative uncertainty at 95 % confidence was +1.6%. The experimental results show that interfacial tension for all the systems increases linearly with molality, indicating that relatively few measurements and simple interpolation procedures are adequate for describing this property accurately over wide ranges of conditions.

High temperature corrosion under conditions simulating biomass firing: depth-resolved phase identification

DEFF Research Database (Denmark)

Okoro, Sunday Chukwudi; Montgomery, Melanie; Jappe Frandsen, Flemming

2014-01-01

) were coated with KCl and is o-thermally exposed at 560 o C for 168 h under a flue gas corresponding to straw firing. Scanning Electron Microscopy (SEM), Energy Dispersive Spectroscopy (EDS), and X-ray Diffraction (XRD) characterization techniques were employed for comprehensive characterization......Both cross-sectional and plan view, ‘top-down’ characterization methods were employed , for a depth-resolved characterization of corrosion products resulting from high temperature corrosion under laboratory conditions simulating biomass firing. Samples of an austenitic stainless steel (TP 347H FG...... of the corrosion product. Results from this comprehensive characterization revealed more details on the morphology and composition of the corrosion product....

Investigations to the potential of the high temperature reactor for steam power processes with highest steam conditions and comparison with according conventional power plants

International Nuclear Information System (INIS)

Mondry, M.

1988-04-01

Already in the fifties conventional power plants with high parameters of the live steam were built to improve the total efficiency. The power plant with the highest steam conditions in the Federal Republic of Germany has 300 bar pressure and 600deg C temperature. Because of high material costs and other problems power plants with such high conditions were not continued to be built. Standard conditions of today's power plants are in the order of 180-250 bar pressure and 535deg C temperature. As the high temperature reactor is partly built up in another way than a conventional power plant, the results regarding the high steam parameters are not transferable. Possibilities for the technical realization of determined HTR-specific components are introduced and discussed. Then different HTR-power plants with steam conditions up to 350 bar pressure and 650deg C temperature are projected. Economical considerations show that an HTR with higher steam parameters brings financial profits. Further efficiency increase, which is possible by the high steam conditions, is shortly presented. The work ends with a technical and economical comparison of corresponding conventional power plants. (orig./UA) [de

Heat and Mass Transfer in a High-Porous Low-Temperature Thermal Insulation in Real Operating Conditions

Directory of Open Access Journals (Sweden)

Polovnikov Vyacheslav Yu.

2015-01-01

Full Text Available The results of numerical simulation of heat and mass transfer in a high-porous low-temperature insulation in conditions of insulation freezing, a moisture migration to the front of phase transition and a condensation forming on an outer contour of interaction were obtained. Values of heat leakage were established.

Petunia × hybrida floral scent production is negatively affected by high-temperature growth conditions.

Science.gov (United States)

Cna'ani, Alon; Mühlemann, Joelle K; Ravid, Jasmin; Masci, Tania; Klempien, Antje; Nguyen, Thuong T H; Dudareva, Natalia; Pichersky, Eran; Vainstein, Alexander

2015-07-01

Increasing temperatures due to changing global climate are interfering with plant-pollinator mutualism, an interaction facilitated mainly by floral colour and scent. Gas chromatography-mass spectroscopy analyses revealed that increasing ambient temperature leads to a decrease in phenylpropanoid-based floral scent production in two Petunia × hybrida varieties, P720 and Blue Spark, acclimated at 22/16 or 28/22 °C (day/night). This decrease could be attributed to down-regulation of scent-related structural gene expression from both phenylpropanoid and shikimate pathways, and up-regulation of a negative regulator of scent production, emission of benzenoids V (EOBV). To test whether the negative effect of increased temperature on scent production can be reduced in flowers with enhanced metabolic flow in the phenylpropanoid pathway, we analysed floral volatile production by transgenic 'Blue Spark' plants overexpressing CaMV 35S-driven Arabidopsis thaliana production of anthocyanin pigments 1 (PAP1) under elevated versus standard temperature conditions. Flowers of 35S:PAP1 transgenic plants produced the same or even higher levels of volatiles when exposed to a long-term high-temperature regime. This phenotype was also evident when analysing relevant gene expression as inferred from sequencing the transcriptome of 35S:PAP1 transgenic flowers under the two temperature regimes. Thus, up-regulation of transcription might negate the adverse effects of temperature on scent production. © 2014 John Wiley & Sons Ltd.

Experimental Assessment of residential split type air-conditioning systems using alternative refrigerants to R-22 at high ambient temperatures

International Nuclear Information System (INIS)

Joudi, Khalid A.; Al-Amir, Qusay R.

2014-01-01

Highlights: • R290, R407C and R410A in residential split A/C units at high ambient. • 1 and 2 TR residential air conditioners with R22 alternatives at high ambient. • Residential split unit performance at ambients up to 55 °C with R22 alternatives. - Abstract: Steady state performance of residential air conditioning systems using R22 and alternatives R290, R407C, R410A, at high ambient temperatures, have been investigated experimentally. System performance parameters such as optimum refrigerant charge, coefficient of performance, cooling capacity, power consumption, pressure ratio, power per ton of refrigeration and TEWI environmental factor have been determined. All refrigerants were tested in the cooling mode operation under high ambient air temperatures, up to 55 °C, to determine their suitability. Two split type air conditioner of 1 and 2 TR capacities were used. A psychrometric test facility was constructed consisting of a conditioned cool compartment and an environmental duct serving the condenser. Air inside the conditioned compartment was maintained at 25 °C dry bulb and 19 °C wet bulb for all tests. In the environmental duct, the ambient air temperature was varied from 35 °C to 55 °C in 5 °C increments. The study showed that R290 is the better candidate to replace R22 under high ambient air temperatures. It has lower TEWI values and a better coefficient of performance than the other refrigerants tested. It is suitable as a drop-in refrigerant. R407C has the closest performance to R22, followed by R410A

High temperature pipeline design

Energy Technology Data Exchange (ETDEWEB)

Greenslade, J.G. [Colt Engineering, Calgary, AB (Canada). Pipelines Dept.; Nixon, J.F. [Nixon Geotech Ltd., Calgary, AB (Canada); Dyck, D.W. [Stress Tech Engineering Inc., Calgary, AB (Canada)

2004-07-01

It is impractical to transport bitumen and heavy oil by pipelines at ambient temperature unless diluents are added to reduce the viscosity. A diluted bitumen pipeline is commonly referred to as a dilbit pipeline. The diluent routinely used is natural gas condensate. Since natural gas condensate is limited in supply, it must be recovered and reused at high cost. This paper presented an alternative to the use of diluent to reduce the viscosity of heavy oil or bitumen. The following two basic design issues for a hot bitumen (hotbit) pipeline were presented: (1) modelling the restart problem, and, (2) establishing the maximum practical operating temperature. The transient behaviour during restart of a high temperature pipeline carrying viscous fluids was modelled using the concept of flow capacity. Although the design conditions were hypothetical, they could be encountered in the Athabasca oilsands. It was shown that environmental disturbances occur when the fluid is cooled during shut down because the ground temperature near the pipeline rises. This can change growing conditions, even near deeply buried insulated pipelines. Axial thermal loads also constrain the design and operation of a buried pipeline as higher operating temperatures are considered. As such, strain based design provides the opportunity to design for higher operating temperature than allowable stress based design methods. Expansion loops can partially relieve the thermal stress at a given temperature. As the design temperature increase, there is a point at which above grade pipelines become attractive options, although the materials and welding procedures must be suitable for low temperature service. 3 refs., 1 tab., 10 figs.

A Status of Art-Report on the Fission Products Behavior Released from Spent Fuel at High Temperature Conditions

International Nuclear Information System (INIS)

Park, Geun Il; Kim, J. H.; Lee, J. W.

2003-04-01

The experiments on the fission products release behavior from spent fuel at high temperature assuming reactor accident conditions have been carried out at Oak Ridge Nation Laboratory of USA in HI/VI tests, CEA of France in HEVA/VERCOS tests, AEA of England and CRNL of Canada in HOX test. The VEGA program to study the fission product release behavior from LWR irradiated fuel was recently initiated at JAERI. The key parameter affecting the fission product(FP) release behavior is temperature. In addition, other parameters such as fuel oxidation, burnup, pre-transient conditions are found to affect the FP releases considerably in the earlier tests. The atmosphere conditions such as oxidizing atmosphere (steam or air) or reducing atmosphere (hydrogen) can cause significant change of FPs release and transport behavior due to chemical forms of the reactive FPs which is dependent on the oxidation potential. The effect of fuel burnup on the Kr-85 or Cs-137 release showed that the release rates of these radionuclides increased with the increase of burnup, meaning that release rates are dominated by the atomic diffusions in the grains and they are primarily a function of temperature. However, the data on FPs release behavior using higher burnups above 50,000 MWD/MTU are not so many reported up to now. This report summarizes the test results of FPs release behavior in reactor accident conditions produced from other countries mentioned above. This review and analysis on earlier studies would be useful for predicting the release characteristics of FPs from domestic spent fuel. The release rates of fission gas or FPs from spent fuel at high temperature conditions during fabrication process of dry recycling fuel were also analyzed using many data obtained from earlier tests

High-pressure high-temperature experiments: Windows to the Universe

International Nuclear Information System (INIS)

Santaria-Perez, D.

2011-01-01

From Earth compositional arguments suggested by indirect methods, such as the propagation of seismic waves, is possible to generate in the laboratory pressure and temperature conditions similar to those of the Earth or other planet interiors and to study how these conditions affect to a certain metal or mineral. These experiments are, therefore, windows to the Universe. The aim of this chapter is to illustrate the huge power of the experimental high-pressure high-temperature techniques and give a global overview of their application to different geophysical fields. Finally, we will introduce the MALTA Consolider Team, which gather most of the Spanish high-pressure community, and present their available high-pressure facilities. (Author) 28 refs.

Preliminary Guideline for the High Temperature Structure Integrity Assessment Procedure Part II. High Temperature Structural Integrity Assessment

Energy Technology Data Exchange (ETDEWEB)

Lee, Jae Han; Kim, J. B.; Lee, H. Y.; Park, C. G.; Joo, Y. S.; Koo, G. H.; Kim, S. H

2007-02-15

A high temperature structural integrity assessment belongs to the Part II of a whole preliminary guideline for the high temperature structure. The main contents of this guideline are the evaluation procedures of the creep-fatigue crack initiation and growth in high temperature condition, the high temperature LBB evaluation procedure, and the inelastic evaluations of the welded joints in SFR structures. The methodologies for the proper inelastic analysis of an SFR structures in high temperatures are explained and the guidelines of inelastic analysis options using ANSYS and ABAQUS are suggested. In addition, user guidelines for the developed NONSTA code are included. This guidelines need to be continuously revised to improve the applicability to the design and analysis of the SFR structures.

The Fuel Accident Condition Simulator (FACS) furnace system for high temperature performance testing of VHTR fuel

Energy Technology Data Exchange (ETDEWEB)

Demkowicz, Paul A., E-mail: paul.demkowicz@inl.gov [Idaho National Laboratory, 2525 Fremont Avenue, MS 3860, Idaho Falls, ID 83415-3860 (United States); Laug, David V.; Scates, Dawn M.; Reber, Edward L.; Roybal, Lyle G.; Walter, John B.; Harp, Jason M. [Idaho National Laboratory, 2525 Fremont Avenue, MS 3860, Idaho Falls, ID 83415-3860 (United States); Morris, Robert N. [Oak Ridge National Laboratory, 1 Bethel Valley Road, Oak Ridge, TN 37831 (United States)

2012-10-15

Highlights: Black-Right-Pointing-Pointer A system has been developed for safety testing of irradiated coated particle fuel. Black-Right-Pointing-Pointer FACS system is designed to facilitate remote operation in a shielded hot cell. Black-Right-Pointing-Pointer System will measure release of fission gases and condensable fission products. Black-Right-Pointing-Pointer Fuel performance can be evaluated at temperatures as high as 2000 Degree-Sign C in flowing helium. - Abstract: The AGR-1 irradiation of TRISO-coated particle fuel specimens was recently completed and represents the most successful such irradiation in US history, reaching peak burnups of greater than 19% FIMA with zero failures out of 300,000 particles. An extensive post-irradiation examination (PIE) campaign will be conducted on the AGR-1 fuel in order to characterize the irradiated fuel properties, assess the in-pile fuel performance in terms of coating integrity and fission metals release, and determine the fission product retention behavior during high temperature safety testing. A new furnace system has been designed, built, and tested to perform high temperature accident tests. The Fuel Accident Condition Simulator furnace system is designed to heat fuel specimens at temperatures up to 2000 Degree-Sign C in helium while monitoring the release of volatile fission metals (e.g. Cs, Ag, Sr, and Eu), iodine, and fission gases (Kr, Xe). Fission gases released from the fuel to the sweep gas are monitored in real time using dual cryogenic traps fitted with high purity germanium detectors. Condensable fission products are collected on a plate attached to a water-cooled cold finger that can be exchanged periodically without interrupting the test. Analysis of fission products on the condensation plates involves dry gamma counting followed by chemical analysis of selected isotopes. This paper will describe design and operational details of the Fuel Accident Condition Simulator furnace system and the associated

In Situ Observation of Gypsum-Anhydrite Transition at High Pressure and High Temperature

International Nuclear Information System (INIS)

Liu Chuan-Jiang; Zheng Hai-Fei

2012-01-01

An in-situ Raman spectroscopic study of gypsum-anhydrite transition under a saturated water condition at high pressure and high temperature is performed using a hydrothermal diamond anvil cell (HDAC). The experimental results show that gypsum dissolvs in water at ambient temperature and above 496 MPa. With increasing temperature, the anhydrite (CaSO 4 ) phase precipitates at 250–320°C in the pressure range of 1.0–1.5GPa, indicating that under a saturated water condition, both stable conditions of pressure and temperature and high levels of Ca and SO 4 ion concentrations in aqueous solution are essential for the formation of anhydrite. A linear relationship between the pressure and temperature for the precipitation of anhydrite is established as P(GPa) = 0.0068T−0.7126 (250°C≤T≤320°C). Anhydrite remained stable during rapid cooling of the sample chamber, showing that the gypsum-anhydrite transition involving both dissolution and precipitation processes is irreversible at high pressure and high temperature. (geophysics, astronomy, and astrophysics)

High-Temperature Structural Analysis of a Small-Scale PHE Prototype under the Test Condition of a Small-Scale Gas Loop

International Nuclear Information System (INIS)

Song, K.; Hong, S.; Park, H.

2012-01-01

A process heat exchanger (PHE) is a key component for transferring the high-temperature heat generated from a very high-temperature reactor (VHTR) to a chemical reaction for the massive production of hydrogen. The Korea Atomic Energy Research Institute has designed and assembled a small-scale nitrogen gas loop for a performance test on VHTR components and has manufactured a small-scale PHE prototype made of Hastelloy-X alloy. A performance test on the PHE prototype is underway in the gas loop, where different kinds of pipelines connecting to the PHE prototype are tested for reducing the thermal stress under the expansion of the PHE prototype. In this study, to evaluate the high-temperature structural integrity of the PHE prototype under the test condition of the gas loop, a realistic and effective boundary condition imposing the stiffness of the pipelines connected to the PHE prototype was suggested. An equivalent spring stiffness to reduce the thermal stress under the expansion of the PHE prototype was computed from the bending deformation and expansion of the pipelines connected to the PHE. A structural analysis on the PHE prototype was also carried out by imposing the suggested boundary condition. As a result of the analysis, the structural integrity of the PHE prototype seems to be maintained under the test condition of the gas loop.

On the Breeding of Bivoltine Breeds of the Silkworm, Bombyx mori L. (Lepidoptera: Bombycidae, Tolerant to High Temperature and High Humidity Conditions of the Tropics

Directory of Open Access Journals (Sweden)

Harjeet Singh

2010-01-01

Full Text Available The hot climatic conditions of tropics prevailing particularly in summer are contributing to the poor performance of the bivoltine breeds and the most important aspect is that many quantitative characters such as viability and cocoon traits decline sharply when temperature is high. Hence, in a tropical country like India, it is very essential to develop bivoltine breeds/hybrids which can withstand the high temperature stress conditions. This has resulted in the development of CSR18 × CSR19, compatible hybrid for rearing throughout the year by utilizing Japanese thermotolerant hybrids as breeding resource material. Though, the introduction of CSR18 × CSR19 in the field during summer months had considerable impact, the productivity level and returns realized do not match that of other productive CSR hybrids. Therefore, the acceptance level of this hybrid with the farmers was not up to the expected level. This has necessitated the development of a temperature tolerant hybrid with better productivity traits than CSR18 × CSR19. Though, it was a difficult task to break the negative correlation associated with survival and productivity traits, attempts on this line had resulted in the development of CSR46 × CSR47, a temperature tolerant bivoltine hybrid with better productivity traits than CSR18 × CSR19. However, though, these hybrids are tolerant to high temperature environments, they are not tolerant to many of the silkworm diseases. Keeping this in view, an attempt is made to develop silkworm hybrids tolerant to high temperature environments.

Amine promoted, metal enhanced degradation of Mirex under high temperature conditions

Energy Technology Data Exchange (ETDEWEB)

Jallad, Karim N. [American University of Sharjah, Department of Chemistry, P.O. Box 26666, Sharjah (United Arab Emirates)]. E-mail: kjallad@runbox.com; Lynn, Bert C. [University of Kentucky, Department of Chemistry, Lexington, KY 40506-055 (United States); Alley, Earl G. [Mississippi State University, Department of Chemistry, MS State, MS 39762 (United States)

2006-07-31

In this study, zero-valent metal dehalogenation of mirex was conducted with amine solvents at high temperatures. Mirex was treated with excess amine in sealed glass tube reactors under nitrogen. The amines used were n-butyl amine (l), ethyl amine (l), dimethyl amine (g), diethyl amine (l), triethyl amine (l), trimethyl amine (g) and ammonia (g). The metals used were copper, zinc, magnesium, aluminum and calcium. The most suitable amine solvent and metal were selected by running a series of reactions with different amines and different zero-valent metals, in order to optimize the conditions under which complete degradation of mirex takes place. These dehalogenation reactions illustrated the role of zero-valent metals as reductants, whereas the amine solvents acted as proton donors. In this study, we report that mirex was completely degraded with diethyl amine (l) in the presence of copper at 100 deg. C and the hydrogenated products accounted for more than 94 of the degraded mirex.

Passive Resistor Temperature Compensation for a High-Temperature Piezoresistive Pressure Sensor.

Science.gov (United States)

Yao, Zong; Liang, Ting; Jia, Pinggang; Hong, Yingping; Qi, Lei; Lei, Cheng; Zhang, Bin; Li, Wangwang; Zhang, Diya; Xiong, Jijun

2016-07-22

The main limitation of high-temperature piezoresistive pressure sensors is the variation of output voltage with operating temperature, which seriously reduces their measurement accuracy. This paper presents a passive resistor temperature compensation technique whose parameters are calculated using differential equations. Unlike traditional experiential arithmetic, the differential equations are independent of the parameter deviation among the piezoresistors of the microelectromechanical pressure sensor and the residual stress caused by the fabrication process or a mismatch in the thermal expansion coefficients. The differential equations are solved using calibration data from uncompensated high-temperature piezoresistive pressure sensors. Tests conducted on the calibrated equipment at various temperatures and pressures show that the passive resistor temperature compensation produces a remarkable effect. Additionally, a high-temperature signal-conditioning circuit is used to improve the output sensitivity of the sensor, which can be reduced by the temperature compensation. Compared to traditional experiential arithmetic, the proposed passive resistor temperature compensation technique exhibits less temperature drift and is expected to be highly applicable for pressure measurements in harsh environments with large temperature variations.

Oxidation performance of high temperature materials under oxyfuel conditions

Energy Technology Data Exchange (ETDEWEB)

Tuurna, Satu; Pohjanne, Pekka; Yli-Olli, Sanni; Kinnunen, Tuomo [VTT Technical Research Centre of Finland, Espoo (Finland)

2010-07-01

Oxyfuel combustion is widely seen as a major option to facilitate carbon capture and storage (CCS) from future boiler plants utilizing clean coal technologies. Oxyfuel combustion can be expected to differ from combustion in air by e.g. modified distribution of fireside temperatures, much reduced NOx but increased levels of fireside CO{sub 2}, SO{sub 2} and water levels due to extensive flue gas recirculation. Modified flue gas chemistry results in higher gas emissivity that can increase the thermal stresses at the heat transfer surfaces of waterwalls and superheaters. In addition, increased flue gas recirculation can increase the concentration of a number of contaminants in the deposited ash and promote fouling and corrosion. There is relatively little experimental information available about the effects of oxyfuel combustion on the performance of boiler material. In this work, the oxidation performance of steels X20CrMoV11-1 and TP347HFG has been determined at 580 C/650 C under simulated oxyfuel firing conditions. The results are presented and compared to corresponding results from simulated air firing conditions. (orig.)

Effect of halophilic conditions in stabilisation of RNA structure and function at high temperature under radiations.

Science.gov (United States)

Maurel, M.-C.

We have already shown the structural integrity of tRNA at high temperature - 82C for 30h - in high salt concentrations (Tehei et al, 2002). Stability were also performed by measuring the residual specific tRNA charge capacity after heat treatment for 30 h at 82C. RNA molecules are selected (in vitro selection) at high temperature at high salt concentration. We are undergoing studies of such molecules submitted to several stressful conditions, in particular high radiations. These studies provide support for the importance of salt to protect macromolecules against severe cosmic conditions. These could be useful for searching traces of life in planetary objects and space exploration. References : ElAmri, C., Baron, M-H., Maurel, M.-C. ``Adenine adsorption onto and release from meteorite specimens assessed by Surface Enhanced Raman Spectroscopy ''. Journal of Raman Spectroscopy (2004) in press. Meli, M., Vergne, J. and Maurel, M-C. "In vitro selection of adenine-dependent hairpin ribozymes" J. Biol. Chem., (2003), 278, 11, 9835-9842. ElAmri, C., Baron, M-H., Maurel, M.-C. ``Adenine in mineral samples : development of a methodology based on Surface Enhanced Raman Spectroscopy (SERS) for picomole detections ''. Spectrochimica Acta, A, 59, 2645-2654. Tehei, M., Franzetti, B., Maurel, M-C., Vergne, J., Hountondji, C. , Zaccai, G. ``Salt and the Search for Traces of Life '', Extremophiles, (2002), 6 : 427-430. Meli, M., Vergne, J., Décout, J.L., and Maurel, M-C. ``Adenine-Aptamer Complexes. A bipartite RNA site which binds the adenine nucleic base '', J. Biol. Chem., (2002), 277, 3, 2104-2111.

Accelerated Testing with Multiple Failure Modes under Several Temperature Conditions

Directory of Open Access Journals (Sweden)

Zongyue Yu

2014-01-01

Full Text Available A complicated device may have multiple failure modes, and some of the failure modes are sensitive to low temperatures. To assess the reliability of a product with multiple failure modes, this paper presents an accelerated testing in which both of the high temperatures and the low temperatures are applied. Firstly, an acceleration model based on the Arrhenius model but accounting for the influence of both the high temperatures and low temperatures is proposed. Accordingly, an accelerated testing plan including both the high temperatures and low temperatures is designed, and a statistical analysis method is developed. The reliability function of the product with multiple failure modes under variable working conditions is given by the proposed statistical analysis method. Finally, a numerical example is studied to illustrate the proposed accelerated testing. The results show that the proposed accelerated testing is rather efficient.

New methods to get valid signals at high temperature conditions by using DSP tools of the ASSA (Abnormal Signal Simulation Analyzer)

International Nuclear Information System (INIS)

Koo, Kil-Mo; Hong, Seong-Wan; Song, Jin-Ho; Baek, Won-Pil; Jung, Myung-Kwan

2012-01-01

A new method to get valid signals under high temperature conditions using DSP (Digital Signal Processing) tools of an ASSA (Abnormal Signal Simulation Analyzer) module through a signal analysis of important circuit modeling under severe accident conditions has been suggested. Already exist, such kinds of DSP technique operated by LabVIEW or MatLab code linked with PSpice code, which have convenient tools as a special function of the ASSA module including a signal reconstruction method. If we can obtain a shift data of the transient parameters such as the time constant of the R-L-C circuit affected by high temperature under a severe accident condition, it will be possible to reconstruct an abnormal signal using a trained deconvolution algorithm as a sort of DSP technique. (author)

Structural analysis technology for high-temperature design

International Nuclear Information System (INIS)

Greenstreet, W.L.

1977-01-01

Results from an ongoing program devoted to the development of verified high-temperature structural design technology applicable to nuclear reactor systems are described. The major aspects addressed by the program are (1) deformation behavior; (2) failure associated with creep rupture, brittle fracture, fatigue, creep-fatigue interactions, and crack propagation; and (3) the establishment of appropriate design criteria. This paper discusses information developed in the deformation behavior category. The material considered is type 304 stainless steel, and the temperatures range to 1100 0 F (593 0 C). In essence, the paper considers the ingredients necessary for predicting relatively high-temperature inelastic deformation behavior of engineering structures under time-varying temperature and load conditions and gives some examples. These examples illustrate the utility and acceptability of the computational methods identified and developed for prediting essential features of complex inelastic behaviors. Conditions and responses that can be encountered under nuclear reactor service conditions and invoked in the examples. (Auth.)

HYFIRE: a tokamak/high-temperature electrolysis system

International Nuclear Information System (INIS)

Fillo, J.A.; Powell, J.P.; Benenati, R.; Varljen, T.C.; Chi, J.W.H.; Karbowski, J.S.

1981-01-01

The HYFIRE studies to date have investigated a number of technical approaches for using the thermal energy produced in a high-temperature Tokamak blanket to provide the electrical and thermal energy required to drive a high-temperature (> 1000 0 C) water electrolysis process. Current emphasis is on two design points, one consistent with electrolyzer peak inlet temperatures of 1400 0 C, which is an extrapolation of present experience, and one consistent with a peak electrolyzer temperature of 1100 0 C. This latter condition is based on current laboratory experience with high-temperature solid electrolyte fuel cells. Our major conclusion to date is that the technical integration of fusion and high-temperature electrolysis appears to be feasible and that overall hydrogen production efficiencies of 50 to 55% seem possible

HIGH TEMPERATURE CORROSION RESISTANCE OF METALLIC MATERIALS IN HARSH CONDITIONS

OpenAIRE

Novello, Frederic; Dedry, Olivier; De Noose, Vincent; Lecomte-Beckers, Jacqueline

2014-01-01

Highly efficient energy recovery from renewable sources and from waste incineration causes new problems of corrosion at high temperature. A similar situation exists for new recycling processes and new energy storage units. These corrosions are generally considered to be caused by ashes or molten salts, the composition of which differs considerably from one plant to another. Therefore, for the assessment of corrosion-resistance of advanced materials, it is essential to precisely evaluate the c...

Respiratory alkalosis and primary hypocapnia in Labrador Retrievers participating in field trials in high-ambient-temperature conditions.

Science.gov (United States)

Steiss, Janet E; Wright, James C

2008-10-01

To determine whether Labrador Retrievers participating in field trials develop respiratory alkalosis and hypocapnia primarily in conditions of high ambient temperatures. 16 Labrador Retrievers. At each of 5 field trials, 5 to 10 dogs were monitored during a test (retrieval of birds over a variable distance on land [1,076 to 2,200 m]; 36 assessments); ambient temperatures ranged from 2.2 degrees to 29.4 degrees C. For each dog, rectal temperature was measured and a venous blood sample was collected in a heparinized syringe within 5 minutes of test completion. Blood samples were analyzed on site for Hct; pH; sodium, potassium, ionized calcium, glucose, lactate, bicarbonate, and total CO2 concentrations; and values of PvO2 and PvCO2. Scatterplots of each variable versus ambient temperature were reviewed. Regression analysis was used to evaluate the effect of ambient temperature ( 21 degrees C) on each variable. Compared with findings at ambient temperatures 21 degrees C; rectal temperature did not differ. Two dogs developed signs of heat stress in 1 test at an ambient temperature of 29 degrees C; their rectal temperatures were higher and PvCO2 values were lower than findings in other dogs. When running distances frequently encountered at field trials, healthy Labrador Retrievers developed hyperthermia regardless of ambient temperature. Dogs developed respiratory alkalosis and hypocapnia at ambient temperatures > 21 degrees C.

High-temperature granulites and supercontinents

Directory of Open Access Journals (Sweden)

J.L.R. Touret

2016-01-01

Full Text Available The formation of continents involves a combination of magmatic and metamorphic processes. These processes become indistinguishable at the crust-mantle interface, where the pressure-temperature (P-T conditions of (ultra high-temperature granulites and magmatic rocks are similar. Continents grow laterally, by magmatic activity above oceanic subduction zones (high-pressure metamorphic setting, and vertically by accumulation of mantle-derived magmas at the base of the crust (high-temperature metamorphic setting. Both events are separated from each other in time; the vertical accretion postdating lateral growth by several tens of millions of years. Fluid inclusion data indicate that during the high-temperature metamorphic episode the granulite lower crust is invaded by large amounts of low H2O-activity fluids including high-density CO2 and concentrated saline solutions (brines. These fluids are expelled from the lower crust to higher crustal levels at the end of the high-grade metamorphic event. The final amalgamation of supercontinents corresponds to episodes of ultra-high temperature metamorphism involving large-scale accumulation of these low-water activity fluids in the lower crust. This accumulation causes tectonic instability, which together with the heat input from the sub-continental lithospheric mantle, leads to the disruption of supercontinents. Thus, the fragmentation of a supercontinent is already programmed at the time of its amalgamation.

Effects of anthropogenic heat due to air-conditioning systems on an extreme high temperature event in Hong Kong

Science.gov (United States)

Wang, Y.; Li, Y.; Di Sabatino, S.; Martilli, A.; Chan, P. W.

2018-03-01

Anthropogenic heat flux is the heat generated by human activities in the urban canopy layer, which is considered the main contributor to the urban heat island (UHI). The UHI can in turn increase the use and energy consumption of air-conditioning systems. In this study, two effective methods for water-cooling air-conditioning systems in non-domestic areas, including the direct cooling system and central piped cooling towers (CPCTs), are physically based, parameterized, and implemented in a weather research and forecasting model at the city scale of Hong Kong. An extreme high temperature event (June 23-28, 2016) in the urban areas was examined, and we assessed the effects on the surface thermal environment, the interaction of sea-land breeze circulation and urban heat island circulation, boundary layer dynamics, and a possible reduction of energy consumption. The results showed that both water-cooled air-conditioning systems could reduce the 2 m air temperature by around 0.5 °C-0.8 °C during the daytime, and around 1.5 °C around 7:00-8:00 pm when the planetary boundary layer (PBL) height was confined to a few hundred meters. The CPCT contributed around 80%-90% latent heat flux and significantly increased the water vapor mixing ratio in the atmosphere by around 0.29 g kg-1 on average. The implementation of the two alternative air-conditioning systems could modify the heat and momentum of turbulence, which inhibited the evolution of the PBL height (a reduction of 100-150 m), reduced the vertical mixing, presented lower horizontal wind speed and buoyant production of turbulent kinetic energy, and reduced the strength of sea breeze and UHI circulation, which in turn affected the removal of air pollutants. Moreover, the two alternative air-conditioning systems could significantly reduce the energy consumption by around 30% during extreme high temperature events. The results of this study suggest potential UHI mitigation strategies and can be extended to

Effect of microstructure on the high temperature strength of nitride

Indian Academy of Sciences (India)

Effect of microstructure on the high temperature strength of nitride bonded silicon carbide composite. J Rakshit P K Das. Composites Volume ... The effect of these parameters on room temperature and high temperature strength of the composite up to 1300°C in ambient condition were studied. The high temperature flexural ...

High Temperature Operational Experiences of Helium Experimental Loop

International Nuclear Information System (INIS)

Kim, Chan Soo; Hong, Sung-Deok; Kim, Eung-Seon; Kim, Min Hwan

2015-01-01

The development of high temperature components of VHTR is very important because of its higher operation temperature than that of a common light water reactor and high pressure industrial process. The development of high temperature components requires the large helium loop. Many countries have high temperature helium loops or a plan for its construction. Table 1 shows various international state-of-the-art of high temperature and high pressure gas loops. HELP performance test results show that there is no problem in operation of HELP at the very high temperature experimental condition. These experimental results also provide the basic information for very high temperature operation with bench-scale intermediate heat exchanger prototype in HELP. In the future, various heat exchanger tests will give us the experimental data for GAMMA+ validation about transient T/H behavior of the IHX prototype and the optimization of the working fluid in the intermediate loop

Viscoelastic creep of high-temperature concrete

International Nuclear Information System (INIS)

Pfeiffer, P.A.; Marchertas, A.H.; Bazant, Z.P.

1985-01-01

Presented in this report is the analytical model for analysis of high temperature creep response of concrete. The creep law used is linear (viscoelastic), the temperature and moisture effects on the creep rate and also aging are included. Both constant and transient temperature as well as constant and transient moisture conditions are considered. Examples are presented to correlate experimental data with parameters of the analytical model by the use of a finite element scheme

A generalized conditional heteroscedastic model for temperature downscaling

Science.gov (United States)

Modarres, R.; Ouarda, T. B. M. J.

2014-11-01

This study describes a method for deriving the time varying second order moment, or heteroscedasticity, of local daily temperature and its association to large Coupled Canadian General Circulation Models predictors. This is carried out by applying a multivariate generalized autoregressive conditional heteroscedasticity (MGARCH) approach to construct the conditional variance-covariance structure between General Circulation Models (GCMs) predictors and maximum and minimum temperature time series during 1980-2000. Two MGARCH specifications namely diagonal VECH and dynamic conditional correlation (DCC) are applied and 25 GCM predictors were selected for a bivariate temperature heteroscedastic modeling. It is observed that the conditional covariance between predictors and temperature is not very strong and mostly depends on the interaction between the random process governing temporal variation of predictors and predictants. The DCC model reveals a time varying conditional correlation between GCM predictors and temperature time series. No remarkable increasing or decreasing change is observed for correlation coefficients between GCM predictors and observed temperature during 1980-2000 while weak winter-summer seasonality is clear for both conditional covariance and correlation. Furthermore, the stationarity and nonlinearity Kwiatkowski-Phillips-Schmidt-Shin (KPSS) and Brock-Dechert-Scheinkman (BDS) tests showed that GCM predictors, temperature and their conditional correlation time series are nonlinear but stationary during 1980-2000 according to BDS and KPSS test results. However, the degree of nonlinearity of temperature time series is higher than most of the GCM predictors.

Extreme temperatures increase the deleterious consequences of inbreeding under laboratory and semi-natural conditions

DEFF Research Database (Denmark)

Kristensen, Torsten Nygård; Barker, J. Stuart F.; Pedersen, Kamilla Sofie

2008-01-01

when compared with non-inbred lines of Drosophila melanogaster under different temperature conditions. Egg-to-adult viability, developmental time and sex ratio of emerging adults are studied under low, intermediate and high temperatures under laboratory as well as semi-natural conditions. The results...... show inbreeding depression for egg-to-adult viability. The level of inbreeding depression is highly dependent on test temperature and is observed only at low and high temperatures. Inbreeding did not affect the developmental time or the sex ratio of emerging adults. However, temperature affected...... the sex ratio with more females relative to males emerging at low temperatures, suggesting that selection against males in pre-adult life stages is stronger at low temperatures. The coefficient of variation (CV) of egg-to-adult viability within and among lines is higher for inbred flies and generally...

Loss of anthocyanins and modification of the anthocyanin profiles in grape berries of Malbec and Bonarda grown under high temperature conditions.

Science.gov (United States)

de Rosas, Inés; Ponce, María Teresa; Malovini, Emiliano; Deis, Leonor; Cavagnaro, Bruno; Cavagnaro, Pablo

2017-05-01

Malbec and Bonarda are the two most widely cultivated grape varieties in Argentina, and their derived red wines are recognized worldwide, being their intense color a major quality trait. The temperature during fruit ripening conditions berries color intensity. In the main viticulture region of Malbec and Bonarda a 2-3°C increase in temperature has been predicted for the upcoming years as consequence of the global climate change. In the present study, this predicted temperature raise was simulated under field-crop conditions, and its effect on anthocyanin pigmentation in berries of Malbec and Bonarda was monitored by HPLC analysis throughout the ripening process, in two growing seasons. Additionally, expression levels of regulatory (MYBA1 and MYB4) and structural (UFGT and Vv3AT) anthocyanin genes were monitored in Malbec berry skins. Although cultivar-dependent time-course variation was observed for total anthocyanin content, in general, the berries of both cultivars grown under high temperature (HT) conditions had significantly lower total anthocyanins (∼28-41% reduction), and a higher proportion of acylated anthocyanins, than their respective controls. Expression of MYBA1 and UFGT, but not MYB4, was correlated with anthocyanin pigmentation at half ripening and harvest, whereas overexpression of the acyltransferase gene Vv3AT was associated with higher anthocyanin acylation in HT berries. These results suggest that color development and pigment modifications in Malbec berries under HT are regulated at transcriptional level by MYBA1, UFGT, and Vv3AT genes. These data contribute to the general understanding on the effect of high temperatures on anthocyanin biochemistry and genetic regulation, and may have direct implications in the production of high-quality wines from Malbec and Bonarda. Copyright © 2017 Elsevier B.V. All rights reserved.

New temperature monitoring devices for high-temperature irradiation experiments in the high flux reactor Petten

Energy Technology Data Exchange (ETDEWEB)

Laurie, M.; Futterer, M. A.; Lapetite, J. M. [European Commission Joint Research Centre, Institute for Energy, P.O. Box 2, NL-1755 ZG Petten (Netherlands); Fourrez, S. [THERMOCOAX SAS, BP 26, Planquivon, 61438 Flers Cedex (France); Morice, R. [Laboratoire National de Metrologie et d' Essais, 1 rue Gaston Boissier, 75724 Paris (France)

2009-07-01

Within the European High Temperature Reactor Technology Network (HTR-TN) and related projects a number of HTR fuel irradiations are planned in the High Flux Reactor Petten (HFR), The Netherlands, with the objective to explore the potential of recently produced fuel for even higher temperature and burn-up. Irradiating fuel under defined conditions to extremely high burn-ups will provide a better understanding of fission product release and failure mechanisms if particle failure occurs. After an overview of the irradiation rigs used in the HFR, this paper sums up data collected from previous irradiation tests in terms of thermocouple data. Some research and development work for further improvement of thermocouples and other on-line instrumentation will be outlined. (authors)

Identification of complex model thermal boundary conditions based on exterior temperature measurement

International Nuclear Information System (INIS)

Lu Jianming; Ouyang Guangyao; Zhang Ping; Rong Bojun

2012-01-01

Combining the advantages of the finite element software in temperature field analyzing with the multivariate function optimization arithmetic, a feasibility method based on the exterior temperature was proposed to get the thermal boundary conditions, which was required in temperature field analyzing. The thermal boundary conditions can be obtained only by some temperature measurement values. Taking the identification of the convection heat transfer coefficient of a high power density diesel engine cylinder head as an example, the calculation result shows that when the temperature measurement error was less than 0.5℃, the maximum relative error was less than 2%. It is shown that the new method was feasible (authors)

Finite temperature Casimir effect for a massless fractional Klein-Gordon field with fractional Neumann conditions

International Nuclear Information System (INIS)

Eab, C. H.; Lim, S. C.; Teo, L. P.

2007-01-01

This paper studies the Casimir effect due to fractional massless Klein-Gordon field confined to parallel plates. A new kind of boundary condition called fractional Neumann condition which involves vanishing fractional derivatives of the field is introduced. The fractional Neumann condition allows the interpolation of Dirichlet and Neumann conditions imposed on the two plates. There exists a transition value in the difference between the orders of the fractional Neumann conditions for which the Casimir force changes from attractive to repulsive. Low and high temperature limits of Casimir energy and pressure are obtained. For sufficiently high temperature, these quantities are dominated by terms independent of the boundary conditions. Finally, validity of the temperature inversion symmetry for various boundary conditions is discussed

A computational study of syngas auto-ignition characteristics at high-pressure and low-temperature conditions with thermal inhomogeneities

KAUST Repository

Pal, Pinaki

2015-07-30

A computational study was conducted to investigate the characteristics of auto-ignition in a syngas mixture at high-pressure and low-temperature conditions in the presence of thermal inhomogeneities. Highly resolved one-dimensional numerical simulations incorporating detailed chemistry and transport were performed. The temperature inhomogeneities were represented by a global sinusoidal temperature profile and a local Gaussian temperature spike (hot spot). Reaction front speed and front Damköhler number analyses were employed to characterise the propagating ignition front. In the presence of a global temperature gradient, the ignition behaviour shifted from spontaneous propagation (strong) to deflagrative (weak), as the initial mean temperature of the reactant mixture was lowered. A predictive Zel\\'dovich–Sankaran criterion to determine the transition from strong to weak ignition was validated for different parametric sets. At sufficiently low temperatures, the strong ignition regime was recovered due to faster passive scalar dissipation of the imposed thermal fluctuations relative to the reaction timescale, which was quantified by the mixing Damköhler number. In the presence of local hot spots, only deflagrative fronts were observed. However, the fraction of the reactant mixture consumed by the propagating front was found to increase as the initial mean temperature was lowered, thereby leading to more enhanced compression-heating of the end-gas. Passive scalar mixing was not found to be important for the hot spot cases considered. The parametric study confirmed that the relative magnitude of the Sankaran number translates accurately to the quantitative strength of the deflagration front in the overall ignition advancement. © 2015 Taylor & Francis

A computational study of syngas auto-ignition characteristics at high-pressure and low-temperature conditions with thermal inhomogeneities

Science.gov (United States)

Pal, Pinaki; Mansfield, Andrew B.; Arias, Paul G.; Wooldridge, Margaret S.; Im, Hong G.

2015-09-01

A computational study was conducted to investigate the characteristics of auto-ignition in a syngas mixture at high-pressure and low-temperature conditions in the presence of thermal inhomogeneities. Highly resolved one-dimensional numerical simulations incorporating detailed chemistry and transport were performed. The temperature inhomogeneities were represented by a global sinusoidal temperature profile and a local Gaussian temperature spike (hot spot). Reaction front speed and front Damköhler number analyses were employed to characterise the propagating ignition front. In the presence of a global temperature gradient, the ignition behaviour shifted from spontaneous propagation (strong) to deflagrative (weak), as the initial mean temperature of the reactant mixture was lowered. A predictive Zel'dovich-Sankaran criterion to determine the transition from strong to weak ignition was validated for different parametric sets. At sufficiently low temperatures, the strong ignition regime was recovered due to faster passive scalar dissipation of the imposed thermal fluctuations relative to the reaction timescale, which was quantified by the mixing Damköhler number. In the presence of local hot spots, only deflagrative fronts were observed. However, the fraction of the reactant mixture consumed by the propagating front was found to increase as the initial mean temperature was lowered, thereby leading to more enhanced compression-heating of the end-gas. Passive scalar mixing was not found to be important for the hot spot cases considered. The parametric study confirmed that the relative magnitude of the Sankaran number translates accurately to the quantitative strength of the deflagration front in the overall ignition advancement.

High temperature corrosion of metals

International Nuclear Information System (INIS)

Quadakkers, W.J.; Schuster, H.; Ennis, P.J.

1988-08-01

This paper covers three main topics: 1. high temperature oxidation of metals and alloys, 2. corrosion in sulfur containing environments and 3. structural changes caused by corrosion. The following 21 subjects are discussed: Influence of implanted yttrium and lanthanum on the oxidation behaviour of beta-NiA1; influence of reactive elements on the adherence and protective properties of alumina scales; problems related to the application of very fine markers in studying the mechanism of thin scale formation; oxidation behaviour of chromia forming Co-Cr-Al alloys with or without reactive element additions; growth and properties of chromia-scales on high-temperature alloys; quantification of the depletion zone in high temperature alloys after oxidation in process gas; effects of HC1 and of N2 in the oxidation of Fe-20Cr; investigation under nuclear safety aspects of Zircaloy-4 oxidation kinetics at high temperatures in air; on the sulfide corrosion of metallic materials; high temperature sulfide corrosion of Mn, Nb and Nb-Si alloys; corrosion behaviour or NiCrAl-based alloys in air and air-SO2 gas mixtures; sulfidation of cobalt at high temperatures; preoxidation for sulfidation protection; fireside corrosion and application of additives in electric utility boilers; transport properties of scales with complex defect structures; observations of whiskers and pyramids during high temperature corrosion of iron in SO2; corrosion and creep of alloy 800H under simulated coal gasification conditions; microstructural changes of HK 40 cast alloy caused by exploitation in tubes in steam reformer installation; microstructural changes during exposure in corrosive environments and their effect on mechanical properties; coatings against carburization; mathematical modeling of carbon diffusion and carbide precipitation in Ni-Cr-based alloys. (MM)

Ammonia oxidation at high pressure and intermediate temperatures

DEFF Research Database (Denmark)

Song, Yu; Hashemi, Hamid; Christensen, Jakob Munkholt

2016-01-01

Ammonia oxidation experiments were conducted at high pressure (30 bar and 100 bar) under oxidizing and stoichiometric conditions, respectively, and temperatures ranging from 450 to 925 K. The oxidation of ammonia was slow under stoichiometric conditions in the temperature range investigated. Under...... oxidizing conditions the onset temperature for reaction was 850–875 K at 30 bar, while at 100 bar it was about 800 K, with complete consumption of NH3 at 875 K. The products of reaction were N2 and N2O, while NO and NO2 concentrations were below the detection limit even under oxidizing conditions. The data...... was satisfactory. The main oxidation path for NH3 at high pressure under oxidizing conditions is NH3⟶+OH NH2⟶+HO2,NO2 H2NO⟶+O2 HNO⟶+O2 NO ⟶+NH2 N2. The modeling predictions are most sensitive to the reactions NH2 + NO = NNH + OH and NH2 + HO2 = H2NO + OH, which promote the ammonia consumption by forming OH...

Involvement of ascorbate peroxidase and heat shock proteins on citrus tolerance to combined conditions of drought and high temperatures.

Science.gov (United States)

Balfagón, Damián; Zandalinas, Sara I; Baliño, Pablo; Muriach, María; Gómez-Cadenas, Aurelio

2018-06-01

Usually several environmental stresses occur in nature simultaneously causing a unique plant response. However, most of the studies until now have focused in individually-applied abiotic stress conditions. Carrizo citrange (Poncirus trifoliata L. Raf. X Citrus sinensis L. Osb.) and Cleopatra mandarin (Citrus reshni Hort. ex Tan.) are two citrus rootstocks with contrasting tolerance to drought and heat stress and have been used in this work as a model for the study of plant tolerance to the combination of drought and high temperatures. According to our results, leaf integrity and photosynthetic machinery are less affected in Carrizo than in Cleopatra under combined conditions of drought and heat stress. The pattern of accumulation of three proteins (APX, HSP101 and HSP17.6) involved in abiotic stress tolerance shows that they do not accumulate under water stress conditions individually applied. However, contents of APX and HSP101 are higher in Carrizo than in Cleopatra under stress combination whereas HSP17.6 has a similar behavior in both types of plants. This, together with a better stomatal control and a higher APX activity of Carrizo, contributes to the higher tolerance of Carrizo plants to the combination of stresses and point to it as a better rootstock than Cleopatra (traditionally used in areas with scare water supplies) under the predictable future climatic conditions with frequent periods of drought combined with high temperatures. This work also provides the basis for testing the tolerance of different citrus varieties grafted on these rootstocks and growing under different field conditions. Copyright © 2018 Elsevier Masson SAS. All rights reserved.

NSTX High Temperature Sensor Systems

International Nuclear Information System (INIS)

McCormack, B.; Kugel, H.W.; Goranson, P.; Kaita, R.

1999-01-01

The design of the more than 300 in-vessel sensor systems for the National Spherical Torus Experiment (NSTX) has encountered several challenging fusion reactor diagnostic issues involving high temperatures and space constraints. This has resulted in unique miniature, high temperature in-vessel sensor systems mounted in small spaces behind plasma facing armor tiles, and they are prototypical of possible high power reactor first-wall applications. In the Center Stack, Divertor, Passive Plate, and vessel wall regions, the small magnetic sensors, large magnetic sensors, flux loops, Rogowski Coils, thermocouples, and Langmuir Probes are qualified for 600 degrees C operation. This rating will accommodate both peak rear-face graphite tile temperatures during operations and the 350 degrees C bake-out conditions. Similar sensor systems including flux loops, on other vacuum vessel regions are qualified for 350 degrees C operation. Cabling from the sensors embedded in the graphite tiles follows narrow routes to exit the vessel. The detailed sensor design and installation methods of these diagnostic systems developed for high-powered ST operation are discussed

Risk Associated With The Decompression Of High Pressure High Temperature Fluids - Study On Black Oil

DEFF Research Database (Denmark)

Figueroa, D. C.; Fosbøl, P. L.; Thomsen, K.

2015-01-01

Fluids produced from deep underground reservoirs may result in exponential increase in temperature. It is a consequence of adiabatic fluid decompression from the inverse Joule Thomson Effect (JTE). The phenomenon requires analysis in order to avoid any operational risks. This study evaluates...... the JTE upon decompression of black oil in high pressure-high temperature reservoirs. Also the effect caused by the presence of water and brine on the black oil is studied. The final temperature is calculated from the corresponding energy balance at isenthalpic and non-isenthalpic conditions. It is found...... that the final temperature of black oil increases upon adiabatic decompression. In the case of the isenthalpic process at initial conditions of the reservoir, e.g. 150°C and 1000 bars, it is found that the final temperature can increase to 173.7°C. At non-isenthalpic conditions the final temperature increases...

Laser-Machined Microcavities for Simultaneous Measurement of High-Temperature and High-Pressure

Directory of Open Access Journals (Sweden)

Zengling Ran

2014-08-01

Full Text Available Laser-machined microcavities for simultaneous measurement of high-temperature and high-pressure are demonstrated. These two cascaded microcavities are an air cavity and a composite cavity including a section of fiber and an air cavity. They are both placed into a pressure chamber inside a furnace to perform simultaneous pressure and high-temperature tests. The thermal and pressure coefficients of the short air cavity are ~0.0779 nm/°C and ~1.14 nm/MPa, respectively. The thermal and pressure coefficients of the composite cavity are ~32.3 nm/°C and ~24.4 nm/MPa, respectively. The sensor could be used to separate temperature and pressure due to their different thermal and pressure coefficients. The excellent feature of such a sensor head is that it can withstand high temperatures of up to 400 °C and achieve precise measurement of high-pressure under high temperature conditions.

Laser-machined microcavities for simultaneous measurement of high-temperature and high-pressure.

Science.gov (United States)

Ran, Zengling; Liu, Shan; Liu, Qin; Huang, Ya; Bao, Haihong; Wang, Yanjun; Luo, Shucheng; Yang, Huiqin; Rao, Yunjiang

2014-08-07

Laser-machined microcavities for simultaneous measurement of high-temperature and high-pressure are demonstrated. These two cascaded microcavities are an air cavity and a composite cavity including a section of fiber and an air cavity. They are both placed into a pressure chamber inside a furnace to perform simultaneous pressure and high-temperature tests. The thermal and pressure coefficients of the short air cavity are ~0.0779 nm/°C and ~1.14 nm/MPa, respectively. The thermal and pressure coefficients of the composite cavity are ~32.3 nm/°C and ~24.4 nm/MPa, respectively. The sensor could be used to separate temperature and pressure due to their different thermal and pressure coefficients. The excellent feature of such a sensor head is that it can withstand high temperatures of up to 400 °C and achieve precise measurement of high-pressure under high temperature conditions.

Short-time, high temperature mechanical testing of electrically conductive materials

International Nuclear Information System (INIS)

Marion, R.H.; Karnes, C.H.

1975-10-01

Design and performance details are given for a facility which was developed to obtain the mechanical properties of materials under high heating rate or transient temperature conditions and medium strain rates. The system is shown to be applicable to materials possessing electrical resistivities ranging from that of aluminum to that of graphite without taxing the heating capability. Heating rates as high as 2000 0 K/s in graphite are attained under controlled conditions. Methods of measuring temperature and the effects of expected temperature distributions are discussed. A method for measuring strain valid for transient temperature conditions to 3000 0 K is described. Results are presented for the stress-strain behavior of 316 stainless steel and ATJ(S) graphite obtained for heating times of a few seconds. (auth)

Des-acyl ghrelin prevents heatstroke-like symptoms in rats exposed to high temperature and high humidity.

Science.gov (United States)

Inoue, Yoshiyuki; Hayashi, Yujiro; Kangawa, Kenji; Suzuki, Yoshihiro; Murakami, Noboru; Nakahara, Keiko

2016-02-26

We have shown previously that des-acyl ghrelin decreases body temperature in rats through activation of the parasympathetic nervous system. Here we investigated whether des-acyl ghrelin ameliorates heatstroke in rats exposed to high temperature. Peripheral administration of des-acyl ghrelin significantly attenuated hyperthermia induced by exposure to high-temperature (35°C) together with high humidity (70-80%). Although biochemical analysis revealed that exposure to high temperature significantly increased hematocrit and the serum levels of aspartate amino transferase (AST), alanine transaminase (ALT), blood urea nitrogen (BUN), creatinine and electrolytes (Na(+), K(+), Cl(-)), most of these heatstroke-associated reactions were significantly reduced by treatment with des-acyl ghrelin. The level of des-acyl ghrelin in plasma was also found to be significantly increased under high-temperature conditions. These results suggest that des-acyl ghrelin could be useful for preventing heatstroke under high temperature condition. Copyright © 2016 Elsevier Ireland Ltd. All rights reserved.

Carvacrol suppresses high pressure high temperature inactivation of Bacillus cereus spores.

Science.gov (United States)

Luu-Thi, Hue; Corthouts, Jorinde; Passaris, Ioannis; Grauwet, Tara; Aertsen, Abram; Hendrickx, Marc; Michiels, Chris W

2015-03-16

The inactivation of bacterial spores generally proceeds faster and at lower temperatures when heat treatments are conducted under high pressure, and high pressure high temperature (HPHT) processing is, therefore, receiving an increased interest from food processors. However, the mechanisms of spore inactivation by HPHT treatment are poorly understood, particularly at moderately elevated temperature. In the current work, we studied inactivation of the spores of Bacillus cereus F4430/73 by HPHT treatment for 5 min at 600MPa in the temperature range of 50-100°C, using temperature increments of 5°C. Additionally, we investigated the effect of the natural antimicrobial carvacrol on spore germination and inactivation under these conditions. Spore inactivation by HPHT was less than about 1 log unit at 50 to 70°C, but gradually increased at higher temperatures up to about 5 log units at 100°C. DPA release and loss of spore refractility in the spore population were higher at moderate (≤65°C) than at high (≥70°C) treatment temperatures, and we propose that moderate conditions induced the normal physiological pathway of spore germination resulting in fully hydrated spores, while at higher temperatures this pathway was suppressed and replaced by another mechanism of pressure-induced dipicolinic acid (DPA) release that results only in partial spore rehydration, probably because spore cortex hydrolysis is inhibited. Carvacrol strongly suppressed DPA release and spore rehydration during HPHT treatment at ≤65°C and also partly inhibited DPA release at ≥65°C. Concomitantly, HPHT spore inactivation was reduced by carvacrol at 65-90°C but unaffected at 95-100°C. Copyright © 2014 Elsevier B.V. All rights reserved.

A study on heat resistance of high temperature resistant coating

Energy Technology Data Exchange (ETDEWEB)

Zhang, Liping; Wang, Xueying; Zhang, Qibin; Qin, Yanlong; Lin, Zhu [Research Institute of Engineering Technology of CNPC, Tianjin (China)

2005-04-15

A high temperature resistant coating has been developed, which is mainly for heavy oil production pipes deserved the serious corrosion. The coating has excellent physical and mechanical performance and corrosion resistance at room and high temperature. In order to simulate the underground working condition of heavy oil pipes,the heat resistance of the high temperature resistant coating has been studied. The development and a study on the heat resistance of the DHT high temperature resistance coating have been introduced in this paper

A study on heat resistance of high temperature resistant coating

International Nuclear Information System (INIS)

Zhang, Liping; Wang, Xueying; Zhang, Qibin; Qin, Yanlong; Lin, Zhu

2005-01-01

A high temperature resistant coating has been developed, which is mainly for heavy oil production pipes deserved the serious corrosion. The coating has excellent physical and mechanical performance and corrosion resistance at room and high temperature. In order to simulate the underground working condition of heavy oil pipes,the heat resistance of the high temperature resistant coating has been studied. The development and a study on the heat resistance of the DHT high temperature resistance coating have been introduced in this paper

High Temperature Fluoride Salt Test Loop

Energy Technology Data Exchange (ETDEWEB)

Aaron, Adam M. [Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States); Cunningham, Richard Burns [Univ. of Tennessee, Knoxville, TN (United States); Fugate, David L. [Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States); Holcomb, David Eugene [Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States); Kisner, Roger A. [Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States); Peretz, Fred J. [Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States); Robb, Kevin R. [Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States); Wilson, Dane F. [Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States); Yoder, Jr, Graydon L. [Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States)

2015-12-01

Effective high-temperature thermal energy exchange and delivery at temperatures over 600°C has the potential of significant impact by reducing both the capital and operating cost of energy conversion and transport systems. It is one of the key technologies necessary for efficient hydrogen production and could potentially enhance efficiencies of high-temperature solar systems. Today, there are no standard commercially available high-performance heat transfer fluids above 600°C. High pressures associated with water and gaseous coolants (such as helium) at elevated temperatures impose limiting design conditions for the materials in most energy systems. Liquid salts offer high-temperature capabilities at low vapor pressures, good heat transport properties, and reasonable costs and are therefore leading candidate fluids for next-generation energy production. Liquid-fluoride-salt-cooled, graphite-moderated reactors, referred to as Fluoride Salt Reactors (FHRs), are specifically designed to exploit the excellent heat transfer properties of liquid fluoride salts while maximizing their thermal efficiency and minimizing cost. The FHR s outstanding heat transfer properties, combined with its fully passive safety, make this reactor the most technologically desirable nuclear power reactor class for next-generation energy production. Multiple FHR designs are presently being considered. These range from the Pebble Bed Advanced High Temperature Reactor (PB-AHTR) [1] design originally developed by UC-Berkeley to the Small Advanced High-Temperature Reactor (SmAHTR) and the large scale FHR both being developed at ORNL [2]. The value of high-temperature, molten-salt-cooled reactors is also recognized internationally, and Czechoslovakia, France, India, and China all have salt-cooled reactor development under way. The liquid salt experiment presently being developed uses the PB-AHTR as its focus. One core design of the PB-AHTR features multiple 20 cm diameter, 3.2 m long fuel channels

High pressure study of high-temperature superconductors

Energy Technology Data Exchange (ETDEWEB)

Souliou, Sofia-Michaela

2014-09-29

The current thesis studies experimentally the effect of high external pressure on high-T{sub c} superconductors. The structure and lattice dynamics of several members of the high-T{sub c} cuprate and Fe-based superconductors families were investigated by means of Raman spectroscopy and X-ray diffraction under well-controlled, hydrostatic high pressure and low temperature conditions. The lattice dynamics of the high-T{sub c} superconductor YBa{sub 2}Cu{sub 3}O{sub 6+x} have been investigated systematically by Raman spectroscopy as a function of doping (x = 0.95, 0.75, 0.60, 0.55, and 0.45) and external pressure. Under ambient pressure conditions, in addition to the Raman modes expected from group theory, we observe new Raman active phonons upon cooling the underdoped samples, at temperatures well above the superconducting transition temperature. The doping dependence and the onset temperatures of the new Raman features suggest that they are associated with the incommensurate charge density wave (CDW) state recently discovered in underdoped cuprates using synchrotron X-ray scattering techniques. Under high pressure conditions (from 2 to 12 GPa), our Raman measurements on highly ordered underdoped YBa{sub 2}Cu{sub 3}O{sub 6.55} samples do not show any of the new Raman phonons seen at ambient pressure. High pressure and low temperature Raman measurements have been performed on the underdoped superconductor YBa{sub 2}Cu{sub 4}O{sub 8}. A clear renormalization of some of the Raman phonons is seen below T{sub c} as a result of the changes in the phonon self-energy upon the opening of the superconducting gap, with the most prominent one being that of the B{sub 1g}-like buckling phonon mode. The amplitude of this renormalization strongly increases with pressure, resembling the effect of hole doping in YBa{sub 2}Cu{sub 3}O{sub 6+x}. At ∝ 10 GPa, the system undergoes a reversible pressure-induced structural phase transition to a non-centrosymmmetric structure (space group

High pressure study of high-temperature superconductors

International Nuclear Information System (INIS)

Souliou, Sofia-Michaela

2014-01-01

The current thesis studies experimentally the effect of high external pressure on high-T c superconductors. The structure and lattice dynamics of several members of the high-T c cuprate and Fe-based superconductors families were investigated by means of Raman spectroscopy and X-ray diffraction under well-controlled, hydrostatic high pressure and low temperature conditions. The lattice dynamics of the high-T c superconductor YBa 2 Cu 3 O 6+x have been investigated systematically by Raman spectroscopy as a function of doping (x = 0.95, 0.75, 0.60, 0.55, and 0.45) and external pressure. Under ambient pressure conditions, in addition to the Raman modes expected from group theory, we observe new Raman active phonons upon cooling the underdoped samples, at temperatures well above the superconducting transition temperature. The doping dependence and the onset temperatures of the new Raman features suggest that they are associated with the incommensurate charge density wave (CDW) state recently discovered in underdoped cuprates using synchrotron X-ray scattering techniques. Under high pressure conditions (from 2 to 12 GPa), our Raman measurements on highly ordered underdoped YBa 2 Cu 3 O 6.55 samples do not show any of the new Raman phonons seen at ambient pressure. High pressure and low temperature Raman measurements have been performed on the underdoped superconductor YBa 2 Cu 4 O 8 . A clear renormalization of some of the Raman phonons is seen below T c as a result of the changes in the phonon self-energy upon the opening of the superconducting gap, with the most prominent one being that of the B 1g -like buckling phonon mode. The amplitude of this renormalization strongly increases with pressure, resembling the effect of hole doping in YBa 2 Cu 3 O 6+x . At ∝ 10 GPa, the system undergoes a reversible pressure-induced structural phase transition to a non-centrosymmmetric structure (space group Imm2). The structural transition is clearly reflected in the high pressure

High-Temperature Test of 800HT Printed Circuit Heat Exchanger in HELP

International Nuclear Information System (INIS)

Kim, Chan Soo; Hong, Sung-Deok; Kim, Min Hwan; Shim, Jaesool

2014-01-01

Korea Atomic Energy Research Institute has developed high-temperature Printed Circuit Heat Exchangers (PCHE) for a Very High Temperature gas-cooled Reactor and operated a very high temperature Helium Experimental LooP (HELP) to verify the performance of the high temperature heat exchanger at the component level environment. PCHE is one of the candidates for the intermediate heat exchanger in a VHTR, because its design temperature and pressure are larger than any other compact heat exchanger types. High temperature PCHEs in HELP consist of an alloy617 PCHE and an 800HT PCHE. This study presents the high temperature test of an 800HT PCHE in HELP. The experimental data include the pressure drops, the overall heat transfer coefficients, and the surface temperature distributions under various operating conditions. The experimental data are compared with the thermo-hydraulic analysis from COMSOL. In addition, the single channel tests are performed to quantify the friction factor under normal nitrogen and helium inlet conditions. (author)

A summary of high-temperature electronics research and development

International Nuclear Information System (INIS)

Thome, F.V.; King, D.B.

1991-01-01

Current and future needs in automative, aircraft, space, military, and well logging industries require operation of electronics at higher temperatures than today's accepted limit of 395 K. Without the availability of high-temperature electronics, many systems must operate under derated conditions or must accept severe mass penalties required by coolant systems to maintain electronic temperatures below critical levels. This paper presents ongoing research and development in the electronics community to bring high-temperature electronics to commercial realization. Much of this work was recently reviewed at the First International High-Temperature Electronics Conference held 16--20 June 1991 in Albuquerque, New Mexico. 4 refs., 1 tab

High-temperature bulk acoustic wave sensors

International Nuclear Information System (INIS)

Fritze, Holger

2011-01-01

Piezoelectric crystals like langasite (La 3 Ga 5 SiO 14 , LGS) and gallium orthophosphate (GaPO 4 ) exhibit piezoelectrically excited bulk acoustic waves at temperatures of up to at least 1450 °C and 900 °C, respectively. Consequently, resonant sensors based on those materials enable new sensing approaches. Thereby, resonant high-temperature microbalances are of particular interest. They correlate very small mass changes during film deposition onto resonators or gas composition-dependent stoichiometry changes of thin films already deposited onto the resonators with the resonance frequency shift of such devices. Consequently, the objective of the work is to review the high-temperature properties, the operation limits and the measurement principles of such resonators. The electromechanical properties of high-temperature bulk acoustic wave resonators such as mechanical stiffness, piezoelectric and dielectric constant, effective viscosity and electrical conductivity are described using a one-dimensional physical model and determined accurately up to temperatures as close as possible to their ultimate limit. Insights from defect chemical models are correlated with the electromechanical properties of the resonators. Thereby, crucial properties for stable operation as a sensor under harsh conditions are identified to be the formation of oxygen vacancies and the bulk conductivity. Operation limits concerning temperature, oxygen partial pressure and water vapor pressure are given. Further, application-relevant aspects such as temperature coefficients, temperature compensation and mass sensitivity are evaluated. In addition, approximations are introduced which make the exact model handy for routine data evaluation. An equivalent electrical circuit for high-temperature resonator devices is derived based on the one-dimensional physical model. Low- and high-temperature approximations are introduced. Thereby, the structure of the equivalent circuit corresponds to the

High-temperature bulk acoustic wave sensors

Science.gov (United States)

Fritze, Holger

2011-01-01

Piezoelectric crystals like langasite (La3Ga5SiO14, LGS) and gallium orthophosphate (GaPO4) exhibit piezoelectrically excited bulk acoustic waves at temperatures of up to at least 1450 °C and 900 °C, respectively. Consequently, resonant sensors based on those materials enable new sensing approaches. Thereby, resonant high-temperature microbalances are of particular interest. They correlate very small mass changes during film deposition onto resonators or gas composition-dependent stoichiometry changes of thin films already deposited onto the resonators with the resonance frequency shift of such devices. Consequently, the objective of the work is to review the high-temperature properties, the operation limits and the measurement principles of such resonators. The electromechanical properties of high-temperature bulk acoustic wave resonators such as mechanical stiffness, piezoelectric and dielectric constant, effective viscosity and electrical conductivity are described using a one-dimensional physical model and determined accurately up to temperatures as close as possible to their ultimate limit. Insights from defect chemical models are correlated with the electromechanical properties of the resonators. Thereby, crucial properties for stable operation as a sensor under harsh conditions are identified to be the formation of oxygen vacancies and the bulk conductivity. Operation limits concerning temperature, oxygen partial pressure and water vapor pressure are given. Further, application-relevant aspects such as temperature coefficients, temperature compensation and mass sensitivity are evaluated. In addition, approximations are introduced which make the exact model handy for routine data evaluation. An equivalent electrical circuit for high-temperature resonator devices is derived based on the one-dimensional physical model. Low- and high-temperature approximations are introduced. Thereby, the structure of the equivalent circuit corresponds to the Butterworth

Temperature field conduction solution by incomplete boundary condition

Energy Technology Data Exchange (ETDEWEB)

Novakovic, M; Petrasinovic, Lj; Djuric, M [Tehnoloski fakultet, Novi Sad (Yugoslavia); Perovic, N [Institut za Nuklearne Nauke Boris Kidric, Belgrade (Yugoslavia)

1977-01-01

The problem of determination of one part boundary conditions temperatures for Fourier partial differential equation when the other part of boundary condition and derivates (heat fluxes) are known is a practical interest as it enables one to determine and accessible temperature by measuring temperatures on other side, of the wall. Method developed and applied here consist of transforming the Fourier partial differential equation by time discretisation in sets of pairs of ordinary differential equations for temperature and heat flux. Such pair of differential equations of first order was solved by Runge-Kutta method. The integration proceeds along space interval simultaneosly for all time intervals. It is interesting to note that this procedure does not require the initial condition.

ASSET, An Information System for Alloy Corrosion in High Temperature Gases

International Nuclear Information System (INIS)

R. C. John; A. D. Pelton; A. L. Young; W. T. Thompson; I. G. Wright

2001-01-01

A large database for corrosion data and a corrosion prediction information system for metals and alloys corroding in high-temperature gases have been created. Corrosion data for about 75 commercial alloys, 4600 corrosion data measurements, and six million exposure hours have been compiled into an information system, ASSET. ASSET allows prediction of sound metal thickness losses for metals and alloys corroding by several common corrosion mechanisms at high-temperatures as functions of gas composition, temperature, time, and alloy. This paper presents examples of predicted metal losses of alloys corroding in standard conditions for several corrosion mechanisms expected in high-temperature gases. ASSET also provides a comprehensive capability to analyze the thermochemical interactions between alloys, corrosion products and exposure conditions. Some of the uses of the data compilation and the corrosion prediction feature are illustrated for oxidizing, sulfidizing, sulfidizing/oxidizing , and carburizing conditions

Containerless processing at high temperatures using acoustic levitation

Science.gov (United States)

Rey, C. A.; Merkley, D. R.; Hampton, S.; Devos, J.; Mapes-Riordan, D.; Zatarski, M.

1991-01-01

Advanced techniques are presented which facilitate the development of inert or reducing atmospheres in excess of 2000 K in order to improve processing of containerless capabilities at higher temperatures and to provide more contamination-free environments. Recent testing, in the laboratory and aboard the NASA KC-135 aircraft, of a high-temperature acoustic positioner demonstrated the effectiveness of a specimen motion damping system and of specimen spin control. It is found that stable positioning can be achieved under ambient and heated conditions, including the transient states of heat-up and cool-down. An incorporated high-temperature levitator was found capable of processing specimens of up to 6-mm diameter in a high-purity environment without the contaminating effects of a container at high temperatures and with relative quiescence.

Numerical Simulations of Evaporating Sprays in High Pressure and Temperature Operating Conditions (Engine Combustion Network [ECN])

Science.gov (United States)

2014-05-01

temperature effect in nonreacting and reacting diesel sprays using a novel injector , and imaging diagnostics for liquid phase penetration, light-off...ambient conditions. A single hole, modern common rail injector with an injector diameter of 90 µ (Bosch CRIN 2.4) is used at typical diesel injection...Temperature (K) 363 Ambient temperature (K) 900 Nozzle Diameter (mm) 0.09 Ambient density (kg/m3) 22.8 Injection Duration (ms) 1.5 Number of injector holes

Temperature profile evolution in quenching high-Tc ...

Indian Academy of Sciences (India)

Abstract. Irreversible normal zones leading to quench is an important aspect of high-temperature superconductors (HTS) in all practical applications. As a consequence of quench, transport current gets diverted to the matrix stabilizer material of the high-Tc composite and causes Joule heating till the original conditions are ...

Quenching ilmenite with a high-temperature and high-pressure phase using super-high-energy ball milling.

Science.gov (United States)

Hashishin, Takeshi; Tan, Zhenquan; Yamamoto, Kazuhiro; Qiu, Nan; Kim, Jungeum; Numako, Chiya; Naka, Takashi; Valmalette, Jean Christophe; Ohara, Satoshi

2014-04-25

The mass production of highly dense oxides with high-temperature and high-pressure phases allows us to discover functional properties that have never been developed. To date, the quenching of highly dense materials at the gramme-level at ambient atmosphere has never been achieved. Here, we provide evidence of the formation of orthorhombic Fe2TiO4 from trigonal FeTiO3 as a result of the high-temperature (>1250 K) and high-pressure (>23 GPa) condition induced by the high collision energy of 150 gravity generated between steel balls. Ilmenite was steeply quenched by the surrounding atmosphere, when iron-rich ilmenite (Fe2TiO4) with a high-temperature and high-pressure phase was formed by planetary collisions and was released from the collision points between the balls. Our finding allows us to infer that such intense planetary collisions induced by high-energy ball milling contribute to the mass production of a high-temperature and high-pressure phase.

Very High Temperature Test of Alloy617 Compact Heat Exchanger in Helium Experimental Loop

Energy Technology Data Exchange (ETDEWEB)

Kim, Chan Soo; Park, Byung-Ha; Kim, Eung-Seon [KAERI, Daejeon (Korea, Republic of)

2016-05-15

The Intermediate Heat eXchanger (IHX) is a key-challenged high temperature component which determines the efficiency and the economy of VHTR system. Heat generated in the VHTR fuel block is transferred from the VHTR to the intermediate loop through IHX. In the present, the shell-helical tube heat exchanger is generally used as IHX of the helium cooled reactor. Recently, a Printed Circuit Heat Exchanger (PCHE) is one of the candidates for the IHX in a VHTR because its operation temperature and pressure are larger than any other compact heat exchanger types. These test results show that there is no problem in operation of HELP at the very high temperature experimental condition and the alloy617 compact heat exchanger can be operated in the very high temperature condition above 850℃. In the future, the high temperature structural analysis will be studied to estimate the thermal stress during transient and thermal shock condition. The conditions and evaluation standard for the alloy 617 diffusion bonding will be minutely studied to fabricate the large-scale PCHE for the high temperature condition.

High and low temperatures have unequal reinforcing properties in Drosophila spatial learning.

Science.gov (United States)

Zars, Melissa; Zars, Troy

2006-07-01

Small insects regulate their body temperature solely through behavior. Thus, sensing environmental temperature and implementing an appropriate behavioral strategy can be critical for survival. The fly Drosophila melanogaster prefers 24 degrees C, avoiding higher and lower temperatures when tested on a temperature gradient. Furthermore, temperatures above 24 degrees C have negative reinforcing properties. In contrast, we found that flies have a preference in operant learning experiments for a low-temperature-associated position rather than the 24 degrees C alternative in the heat-box. Two additional differences between high- and low-temperature reinforcement, i.e., temperatures above and below 24 degrees C, were found. Temperatures equally above and below 24 degrees C did not reinforce equally and only high temperatures supported increased memory performance with reversal conditioning. Finally, low- and high-temperature reinforced memories are similarly sensitive to two genetic mutations. Together these results indicate the qualitative meaning of temperatures below 24 degrees C depends on the dynamics of the temperatures encountered and that the reinforcing effects of these temperatures depend on at least some common genetic components. Conceptualizing these results using the Wolf-Heisenberg model of operant conditioning, we propose the maximum difference in experienced temperatures determines the magnitude of the reinforcement input to a conditioning circuit.

Experimental investigation of optical fiber temperature sensors at cryogenic temperature and in high magnetic fields

International Nuclear Information System (INIS)

Tanaka, Y.; Ogata, M.; Nagashima, K.; Agawa, H.; Matsuura, S.; Kumagai, Y.

2010-01-01

If it is possible to monitor the conditions in the cryogenic equipments including the super-conducting magnets, the indication of failure can be detected beforehand and the reliability in the operation can improve. Optical fiber temperature sensing is an advantageous method in terms of heat invasion, electric insulation, etc. Therefore, the experiments which confirm the characteristics of optical fiber temperature sensors at cryogenic temperatures and in high magnetic fields were performed, and the possibility of measuring under these conditions was confirmed. However, since the resolution of temperature was a problem, the method of analysis that predicts the measurements was contrived, and the method to improve the problem was examined.

Promising materials for HTGR high temperature heat exchangers

International Nuclear Information System (INIS)

Kuznetsov, E.V.; Tokareva, T.B.; Ryabchenkov, A.V.; Novichkova, O.V.; Starostin, Yu.D.

1989-01-01

The service conditions for high-temperature heat-exchangers with helium coolant of HTGRs and requirements imposed on materials for their production are discussed. The choice of nickel-base alloys with solid-solution hardening for long-term service at high temperatures is grounded. Results of study on properties and structure of types Ni-25Cr-5W-5Mo and Ni-20Cr-20W alloy in the temperature range of 900 deg. - 1,000 deg. C are given. The ageing of Ni-25Cr-5W-5Mo alloy at 900 deg. - 950 deg. C results in decreased corrosion-mechanical properties and is caused by the change of structural metal stability. Alloy with 20% tungsten retains a high stability of both structure and properties after prolonged exposure in helium at above temperatures. The alloy has also increased resistance to delayed fracture and low-cycle fatigue at high temperatures. The developed alloy of type Ni-20Cr-20W with microalloying is recommended for production of tubes for HTGR high-temperature heat-exchangers with helium coolant. (author). 3 refs, 8 figs

Corrosion of high temperature alloys in the primary circuit helium of high temperature gas cooled reactors. Pt. 2

International Nuclear Information System (INIS)

Quadakkers, W.J.

1985-01-01

The reactive impurities H 2 O, CO, H 2 and CH 4 which are present in the primary coolant helium of high temperature gas-cooled reactors can cause scale formation, internal oxidation and carburization or decarburization of the high temperature structural alloys. In Part 1 of this contribution a theoretical model was presented, which allows the explanation and prediction of the observed corrosion effects. The model is based on a classical stability diagram for chromium, modified to account for deviations from equilibrium conditions caused by kinetic factors. In this paper it is shown how a stability diagram for a commercial alloy can be constructed and how this can be used to correlate the corrosion results with the main experimental parameters, temperature, gas and alloy composition. Using the theoretical model and the presented experimental results, conditions are derived under which a protective chromia based surface scale will be formed which prevents a rapid transfer of carbon between alloy and gas atmosphere. It is shown that this protective surface oxide can only be formed if the carbon monoxide pressure in the gas exceeds a critical value. Psub(CO), which depends on temperature and alloy composition. Additions of methane only have a limited effect provided that the methane/water ratio is not near to, or greater than, a critical value of around 100/1. The influence of minor alloying additions of strong oxide forming elements, commonly present in high temperature alloys, on the protective properties of the chromia surface scales and the kinetics of carbon transfer is illustrated. (orig.) [de

Investigations into High Temperature Components and Packaging

Energy Technology Data Exchange (ETDEWEB)

Marlino, L.D.; Seiber, L.E.; Scudiere, M.B.; M.S. Chinthavali, M.S.; McCluskey, F.P.

2007-12-31

The purpose of this report is to document the work that was performed at the Oak Ridge National Laboratory (ORNL) in support of the development of high temperature power electronics and components with monies remaining from the Semikron High Temperature Inverter Project managed by the National Energy Technology Laboratory (NETL). High temperature electronic components are needed to allow inverters to operate in more extreme operating conditions as required in advanced traction drive applications. The trend to try to eliminate secondary cooling loops and utilize the internal combustion (IC) cooling system, which operates with approximately 105 C water/ethylene glycol coolant at the output of the radiator, is necessary to further reduce vehicle costs and weight. The activity documented in this report includes development and testing of high temperature components, activities in support of high temperature testing, an assessment of several component packaging methods, and how elevated operating temperatures would impact their reliability. This report is organized with testing of new high temperature capacitors in Section 2 and testing of new 150 C junction temperature trench insulated gate bipolar transistor (IGBTs) in Section 3. Section 4 addresses some operational OPAL-GT information, which was necessary for developing module level tests. Section 5 summarizes calibration of equipment needed for the high temperature testing. Section 6 details some additional work that was funded on silicon carbide (SiC) device testing for high temperature use, and Section 7 is the complete text of a report funded from this effort summarizing packaging methods and their reliability issues for use in high temperature power electronics. Components were tested to evaluate the performance characteristics of the component at different operating temperatures. The temperature of the component is determined by the ambient temperature (i.e., temperature surrounding the device) plus the

Optimizing pentacene thin-film transistor performance: Temperature and surface condition induced layer growth modification.

Science.gov (United States)

Lassnig, R; Hollerer, M; Striedinger, B; Fian, A; Stadlober, B; Winkler, A

2015-11-01

In this work we present in situ electrical and surface analytical, as well as ex situ atomic force microscopy (AFM) studies on temperature and surface condition induced pentacene layer growth modifications, leading to the selection of optimized deposition conditions and entailing performance improvements. We prepared p ++ -silicon/silicon dioxide bottom-gate, gold bottom-contact transistor samples and evaluated the pentacene layer growth for three different surface conditions (sputtered, sputtered + carbon and unsputtered + carbon) at sample temperatures during deposition of 200 K, 300 K and 350 K. The AFM investigations focused on the gold contacts, the silicon dioxide channel region and the highly critical transition area. Evaluations of coverage dependent saturation mobilities, threshold voltages and corresponding AFM analysis were able to confirm that the first 3-4 full monolayers contribute to the majority of charge transport within the channel region. At high temperatures and on sputtered surfaces uniform layer formation in the contact-channel transition area is limited by dewetting, leading to the formation of trenches and the partial development of double layer islands within the channel region instead of full wetting layers. By combining the advantages of an initial high temperature deposition (well-ordered islands in the channel) and a subsequent low temperature deposition (continuous film formation for low contact resistance) we were able to prepare very thin (8 ML) pentacene transistors of comparably high mobility.

High temperature transient deformation of mixed oxide fuels

International Nuclear Information System (INIS)

Slagle, O.D.

1986-01-01

The purpose of this paper is to present recent experimental results on fuel creep under transient conditions at high temperatures. The effect of temperature, stress, heating rate, density and grain size were considered. An empirical formulation is derived for the relationship between strain, stress, temperature and heating rate. This relationship provides a means for incorporating stress relief into the analysis of fuel-cladding interaction during an overpower transient. The effect of sample density and initial grain size is considered by varying the sample parameters. Previously derived steady-state creep relationships for the high temperature creep of mixed oxide fuel were combined with the time dependency of creep found for UO 2 to calculate a transient creep relationship for mixed oxide fuel. These calculated results were found to be in good agreement with the measured high temperature transient creep results

High-Temperature Adhesives for Thermally Stable Aero-Assist Technologies

Science.gov (United States)

Eberts, Kenneth; Ou, Runqing

2013-01-01

Aero-assist technologies are used to control the velocity of exploration vehicles (EVs) when entering Earth or other planetary atmospheres. Since entry of EVs in planetary atmospheres results in significant heating, thermally stable aero-assist technologies are required to avoid the high heating rates while maintaining low mass. Polymer adhesives are used in aero-assist structures because of the need for high flexibility and good bonding between layers of polymer films or fabrics. However, current polymer adhesives cannot withstand temperatures above 400 C. This innovation utilizes nanotechnology capabilities to address this need, leading to the development of high-temperature adhesives that exhibit high thermal conductivity in addition to increased thermal decomposition temperature. Enhanced thermal conductivity will help to dissipate heat quickly and effectively to avoid temperature rising to harmful levels. This, together with increased thermal decomposition temperature, will enable the adhesives to sustain transient high-temperature conditions.

Nuclear reactor application for high temperature power industrial processes

International Nuclear Information System (INIS)

Dollezhal', N.A.; Zaicho, N.D.; Alexeev, A.M.; Baturov, B.B.; Karyakin, Yu.I.; Nazarov, E.K.; Ponomarev-Stepnoj, N.N.; Protzenko, A.M.; Chernyaev, V.A.

1977-01-01

This report gives the results of considerations on industrial heat and technology processes (in chemistry, steelmaking, etc.) from the point of view of possible ways, technical conditions and nuclear safety requirements for the use of high temperature reactors in these processes. Possible variants of energy-technological diagrams of nuclear-steelmaking, methane steam-reforming reaction and other processes, taking into account the specific character of nuclear fuel are also given. Technical possibilities and economic conditions of the usage of different types of high temperature reactors (gas cooled reactors and reactors which have other means of transport of nuclear heat) in heat processes are examined. The report has an analysis of the problem, that arises with the application of nuclear reactors in energy-technological plants and an evaluation of solutions of this problem. There is a reason to suppose that we will benefit from the use of high temperature reactors in comparison with the production based on high quality fossil fuel [ru

Nuclear Fuel Fretting Mechanisms in a Room Temperature Unlubricated Condition

Energy Technology Data Exchange (ETDEWEB)

Lee, Young Ho; Kim, Hyung Kyu [Korea Atomic Energy Research Institute, Daejeon (Korea, Republic of)

2008-10-15

Recently, efforts for evaluating the fretting wear mechanism have been carried out by many researchers in various conditions. In an unlubricated condition, especially, effects of a wear debris and/or its layer on the fretting wear behavior were proposed that the formation of a well-developed glaze layer has a beneficial effect for decreasing a friction coefficient. Otherwise, a wear rate was accelerated by a third-body abrasion. At this time, it is well known that wear debris behaviors are affected by test variables such as a temperature, environment, material characteristics, etc. In a nuclear fuel fretting, however, its contact condition is quite different when compared with general fretting wear studies and could be summarized as the following; first, a fuel rod is supported by spacer grid springs and dimples that were elastically deformable. This results in a unique friction loop and a different fretting mechanism when a fuel rod is vibrated due to a flow-induced vibration (FIV). Next, it is possible that some region of the wear scar area with a specific spring shape condition could be hidden due to different wear debris behavior. So, some of the wear debris layers could be found on the worn surfaces in previous studies even though fretting wear tests were performed in a water lubricated condition. Finally, initial contact condition could be changed both an actual operating condition in power plants (i.e. high temperature and pressurized water (HTHP) under severe irradiation conditions) and the fretting wear tests for evaluating the wear resistant spring in lab conditions (i.e. from room temperature to HTHP without irradiation conditions) due to material degradations and the formation of the wear scar, respectively. In summary, the spring shape effect and the variation of the contact condition with increasing fretting cycle should be evaluated in order to improve the wear resistance of the spacer grid spring. So, in this study, fretting wear tests have been

Interfacial failure in dissimilar weld joint of high boron 9% chromium steel and nickel-based alloy under high-temperature creep condition

Energy Technology Data Exchange (ETDEWEB)

Matsunaga, Tetsuya, E-mail: MATSUNAGA.Tetsuya@nims.go.jp; Hongo, Hiromichi, E-mail: HONGO.Hiromichi@nims.go.jp; Tabuchi, Masaaki, E-mail: TABUCHI.Masaaki@nims.go.jp

2017-05-17

The advanced ultra-supercritical (A-USC) power generation system is expected to become the next-generation base-load power station in Japan. Dissimilar weld joints between high-Cr heat-resistant steels and nickel-based alloys with a nickel-based filler metal (Alloy 82) will need to be adopted for this purpose. However, interfacial failure between the steels and weld metal has been observed under high-temperature creep conditions. Fractography and microstructure observations showed the failure initiated in a brittle manner by an oxide notch at the bottom of the U-groove. The fracture then proceeded along the bond line in a ductile manner with shallow dimples, where micro-Vickers hardness tests showed remarkable softening in the steel next to the bond line. In addition, the steel showed a much larger total elongation and reduction of area than the weld metal at low stresses under long-term creep conditions, leading to mismatch deformation at the interface. According to the results, it can be concluded that the interfacial failure between the 9Cr steels and Alloy 82 weld metal is initiated by an oxide notch and promoted by softening and the difference in the plasticity of the steels and weld metal.

High temperature microscope (1961); Microscopie a haute temperature (1961)

Energy Technology Data Exchange (ETDEWEB)

Rousseau, P [Commissariat a l' Energie Atomique, Saclay (France). Centre d' Etudes Nucleaires

1961-06-15

The purpose of this work is the realization of an apparatus for observation of radioactive metallic samples at high temperature and low pressure. The operating conditions are as follows: to limit oxidation of the metal, pressure of about 10{sup -6} mm of Hg is maintained in the furnace. In case the oxidation of the sample would be too important, on ultra vacuum. device could be used; working temperatures range between room temperature and 1200 deg. C; furnace temperature is regulated; observation is done ever in polarized light or interference contrast; to insure protection of the operator, the apparatus is placed in a glove-box. With that apparatus, we have observed the {alpha}{yields}{beta}, {beta}{yields}{gamma} transformations of uranium. A movie has been done. (author) [French] Le but de ce travail est la realisation d'une appareillage permettant l'observation a chaud et sous vide d'echantillons metalliques radioactifs. Cet appareillage fonctionne dans les conditions suivantes: l'echantillon est chauffe sous une pression de l'ordre de 10{sup -6} mm de mercure afin de limiter l'oxydation du materiau examine. L'utilisation eventuelle d'un groupe de pompage pour ultra vide est prevue; l'echantillon peut etre porte a une temperature comprise entre quelques degres et 1200 deg. C; la temperature du four est regulee; l'observation s'effectue soit en lumiere polarisee soit en contraste interferentiel; l'appareil est dipose dans une boite a gants afin d'assurer la protection de l'operateur contre les poussieres radioactives; Les transformations {alpha}{yields}{beta}, {beta}{yields}{gamma} de l'uranium ont ete observees. Un film a ete realise. (auteur)

SiC-based neutron detector in quasi-realistic working conditions: efficiency and stability at room and high temperature under fast neutron irradiations

Energy Technology Data Exchange (ETDEWEB)

Ferone, Raffaello; Issa, Fatima; Ottaviani, Laurent; Biondo, Stephane; Vervisch, Vanessa [IM2NP, UMR CNRS 7334, Aix-Marseille University, Case 231,13397 Marseille Cedex 20, (France); Szalkai, Dora; Klix, Axel [KIT- Karlsruhe Institute of Technology, Institute of Neutron Physics and Reactor Technology Karlsruhe 76344, (Germany); Vermeeren, Ludo [SCK-CEN, Boeretang 200, B-2400 Mol, (Belgium); Saenger, Richard [Schlumberger, Clamart, (France); Lyoussi, Abadallah [CEA, DEN, Departement d' Etudes des Reacteurs, Service de Physique Experimentale, Laboratoire Dosimetrie Capteurs Instrumentation, 13108 Saint-Paul-lez-Durance, (France)

2015-07-01

In the framework of the European I SMART project, we have designed and made new SiC-based nuclear radiation detectors able to operate in harsh environments and to detect both fast and thermal neutrons. In this paper, we report experimental results of fast neutron irradiation campaign at high temperature (106 deg. C) in quasi-realistic working conditions. Our device does not suffer from high temperature, and spectra do show strong stability, preserving features. These experiments, as well as others in progress, show the I SMART SiC-based device skills to operate in harsh environments, whereas other materials would strongly suffer from degradation. Work is still demanded to test our device at higher temperatures and to enhance efficiency in order to make our device fully exploitable from an industrial point of view. (authors)

Influence of Surfactant Structure on the Stability of Water-in-Oil Emulsions under High-Temperature High-Salinity Conditions

Directory of Open Access Journals (Sweden)

Abdelhalim I. A. Mohamed

2017-01-01

Full Text Available Emulsified water-in-oil (W/O systems are extensively used in the oil industry for water control and acid stimulation. Emulsifiers are commonly utilized to emulsify a water-soluble material to form W/O emulsion. The selection of a particular surfactant for such jobs is critical and certainly expensive. In this work, the impact of surfactant structure on the stability of W/O emulsions is investigated using the hydrophilic-lipophilic balance (HLB of the surfactant. Different commercial surfactants were evaluated for use as emulsifiers for W/O systems at high-temperature (up to 120°C high-salinity (221,673 ppm HTHS conditions. Diverse surfactants were examined including ethoxylates, polyethylene glycols, fluorinated surfactants, and amides. Both commercial Diesel and waste oil are used for the oleic phase to prepare the emulsified system. Waste oil has shown higher stability (less separation in comparison with Diesel. This work has successfully identified stable emulsified W/O systems that can tolerate HTHS environments using HLB approach. Amine Acetate family shows higher stability in comparison with Glycol Ether family and at even lower concentration. New insights into structure-surfactant stability relationship, beyond the HLB approach, are provided for surfactant selection.

Catalyst dispersion and activity under conditions of temperature-staged liquefaction

Energy Technology Data Exchange (ETDEWEB)

Davis, A.; Schobert, H.H.; Mitchell, G.D.; Artok, L.

1993-02-01

This research program involves the investigation of the use of highly dispersed catalyst precursors for the pretreatment of coals by mild hydrogenation. During the course of this effort solvent preswelling of the coal was evaluated as a means of deeply impregnating catalysts into coal, active phases of catalysts under reaction conditions were studied and the impact of these techniques were evaluated during pretreatment and temperature-staged liquefaction. Two coals, a Texas subbituminous and a Utah high volatile A bituminous, were used to examine the effects of solvent swelling pretreatment and catalyst impregnation on conversion behavior at 275[degrees]C, representative of the first, low-temperature stage in a temperature-staged liquefaction reaction. Ferrous sulfate, iron pentacarbonyl, ammonium tetrathiomolybdate, and molybdenum hexacarbonyl were used as catalyst precursors. Without swelling pretreatment, impregnation of both coals increased conversion, mainly through increased yields of preasphaltenes.

Application on electrochemistry measurement of high temperature high pressure condition in PWR nuclear power plants

International Nuclear Information System (INIS)

Li Yuchun; Xiao Zhongliang; Jiang Ya; Yu Xiaowei; Pang Feifei; Deng Fenfang; Gao Fan; Zhou Nianguang

2011-01-01

High temperature high pressure electrochemistry testing system was comprehensively analyzed in this paper, according to actual status for supervision in primary and secondary circuits of PWR nuclear power plants. Three research methods were reviewed and discussed for in-situ monitor system. By combination with ECP realtime measurement it was executed for evaluation and water chemistry optimization in nuclear power plants. It is pointed out that in-situ electrochemistry measurement has great potential application for water chemistry evaluation in PWR nuclear power plants. (authors)

Part-load performance of a high temperature Kalina cycle

International Nuclear Information System (INIS)

Modi, Anish; Andreasen, Jesper Graa; Kærn, Martin Ryhl; Haglind, Fredrik

2015-01-01

Highlights: • Detailed algorithm to solve high temperature Kalina cycle in part load. • A central receiver concentrating solar power plant with direct vapour generation considered as case study. • Part-load performance curves and fitted equations presented. - Abstract: The Kalina cycle has recently seen increased interest as an alternative to the conventional steam Rankine cycle. The cycle has been studied for use with both low and high temperature applications such as geothermal power plants, ocean thermal energy conversion, waste heat recovery, gas turbine bottoming cycle, and solar power plants. The high temperature cycle layouts are inherently more complex than the low temperature layouts due to the presence of a distillation-condensation subsystem, three pressure levels, and several heat exchangers. This paper presents a detailed approach to solve the Kalina cycle in part-load operating conditions for high temperature (a turbine inlet temperature of 500 °C) and high pressure (100 bar) applications. A central receiver concentrating solar power plant with direct vapour generation is considered as a case study where the part-load conditions are simulated by changing the solar heat input to the receiver. Compared with the steam Rankine cycle, the Kalina cycle has an additional degree of freedom in terms of the ammonia mass fraction which can be varied in order to maximize the part-load efficiency of the cycle. The results include the part-load curves for various turbine inlet ammonia mass fractions and the fitted equations for these curves.

Present status of high temperature engineering test and research, 1994

International Nuclear Information System (INIS)

1994-10-01

High temperature gas-cooled reactors have excellent features such as the generation of high temperature close to 1000degC, very high inherent safety and high fuel burnup. By the advanced basic research under high temperature irradiation condition, the creation of various new technologies which become the momentum of future technical innovation can be expected. The construction of the high temperature engineering test reactor (HTTR) was decided in 1987, which aims at the thermal output of 30 MW and the coolant temperature at reactor exit of 950degC. The initial criticality is scheduled in 1998. Japan Atomic Energy Research Institute has advanced the high temperature engineering test and research, and plans the safety verifying test of the HTTR, the test of connecting heat utilization plants and so on. In this report, mainly the results obtained for one year from May, 1993 are summarized. The outline of the high temperature engineering test and development of the HTTR technologies are reported. (K.I.)

Elevated temperature erosion studies on some materials for high temperature applications

International Nuclear Information System (INIS)

Zhou Jianren.

1991-01-01

The surface degradation of materials due to high temperature erosion or combined erosion corrosion is a serious problem in many industrial and aeronautical applications. As such, it has become an important design consideration in many situations. The materials investigated in the present studies are stainless steels, Ti-6Al-4V, alumina ceramics, with and without silicate glassy phase, and zirconia. These are some of the potential materials for use in the high temperature erosive-corrosive environments. The erosion or erosion-corrosion experiments were performed in a high temperature sand-blast type of test rig. The variables studied included the temperature, material composition, heat treatment condition, impingement velocity and angle, erodent concentration, etc. The morphological features of the eroded or eroded-corroded surfaces, substrate deformation, and oxide characteristics were studied by optical and scanning electron microscopy, X-ray diffraction, energy dispersive X-ray spectroscopy, thermogravimetric analysis. The scratch test, single ball impact, and indentation tests were used to understand the behavior of oxide film in particle impacts. Based on these studies, the understanding of the mechanisms involved in the mechanical or combined mechanical and chemical actions in erosion was developed

Corrosion Behavior of Nickel-Plated Alloy 600 in High Temperature Water

International Nuclear Information System (INIS)

Kim, Ji Hyun; Hwang, Il Soon

2008-01-01

In this paper, electrochemical and microstructural characteristics of nickel-plated Alloy 600 wee investigated in order to identify the performance of electroless Ni-plating on Alloy 600 in high-temperature aqueous condition with the comparison of electrolytic nickel-plating. For high temperature corrosion test of nickel-plated Alloy 600, specimens were exposed for 770 hours to typical PWR primary water condition. During the test, open circuit potentials (OCP's) of all specimens were measured using a reference electrode. Also, resistance to flow accelerated corrosion (FAC) test was examined in order to check the durability of plated layers in high-velocity flow environment at high temperature. After exposures to high flow rate aqueous condition, the integrity of surfaces was confirmed by using both scanning electron microscopy (SEM) and energy dispersive spectroscopy (EDS). For the field application, a remote process for electroless nickel-plating was demonstrated using a plate specimen with narrow gap on a laboratory scale. Finally, a practical seal design was suggested for more convenient application

High temperature electrical energy storage: advances, challenges, and frontiers.

Science.gov (United States)

Lin, Xinrong; Salari, Maryam; Arava, Leela Mohana Reddy; Ajayan, Pulickel M; Grinstaff, Mark W

2016-10-24

With the ongoing global effort to reduce greenhouse gas emission and dependence on oil, electrical energy storage (EES) devices such as Li-ion batteries and supercapacitors have become ubiquitous. Today, EES devices are entering the broader energy use arena and playing key roles in energy storage, transfer, and delivery within, for example, electric vehicles, large-scale grid storage, and sensors located in harsh environmental conditions, where performance at temperatures greater than 25 °C are required. The safety and high temperature durability are as critical or more so than other essential characteristics (e.g., capacity, energy and power density) for safe power output and long lifespan. Consequently, significant efforts are underway to design, fabricate, and evaluate EES devices along with characterization of device performance limitations such as thermal runaway and aging. Energy storage under extreme conditions is limited by the material properties of electrolytes, electrodes, and their synergetic interactions, and thus significant opportunities exist for chemical advancements and technological improvements. In this review, we present a comprehensive analysis of different applications associated with high temperature use (40-200 °C), recent advances in the development of reformulated or novel materials (including ionic liquids, solid polymer electrolytes, ceramics, and Si, LiFePO 4 , and LiMn 2 O 4 electrodes) with high thermal stability, and their demonstrative use in EES devices. Finally, we present a critical overview of the limitations of current high temperature systems and evaluate the future outlook of high temperature batteries with well-controlled safety, high energy/power density, and operation over a wide temperature range.

The analysis of energy efficiency in water electrolysis under high temperature and high pressure

Science.gov (United States)

Hourng, L. W.; Tsai, T. T.; Lin, M. Y.

2017-11-01

This paper aims to analyze the energy efficiency of water electrolysis under high pressure and high temperature conditions. The effects of temperature and pressure on four different kinds of reaction mechanisms, namely, reversible voltage, activation polarization, ohmic polarization, and concentration polarization, are investigated in details. Results show that the ohmic and concentration over-potentials are increased as temperature is increased, however, the reversible and activation over-potentials are decreased as temperature is increased. Therefore, the net efficiency is enhanced as temperature is increased. The efficiency of water electrolysis at 350°C/100 bars is increased about 17%, compared with that at 80°C/1bar.

Phase stability of TiH{sub 2} under high pressure and temperatures

Energy Technology Data Exchange (ETDEWEB)

Selva Vennila, R.; Durygin, A.; Saxena, S.K. [Center for Study of Matter at Extreme Conditions (CeSMEC), Florida International University, VH-150, University Park, Miami, FL 33199 (United States); Merlini, Marco [European Synchrotron Radiation Facility (ESRF), Grenoble 38043 (France); Wang, Zhongwu [Cornell High Energy Synchrotron Source (CHESS), Wilson Laboratory, Cornell University, Ithaca, NY 14853 (United States)

2008-11-15

Phase stability of titanium hydride (TiH{sub 2}) was studied at high pressure-high temperature conditions using synchrotron radiation under non-hydrostatic conditions. Resistive heating method was used to heat the sample to a maximum temperature of 873 K in a diamond anvil cell (DAC) under pressure up to 12 GPa. Pressure-temperature behavior was studied by varying the temperature upto 823 K in steps of 50 K with pressure variations within 3 GPa. Structural phase transformation from tetragonal (I4/mmm) to cubic (Fm-3 m) was observed with increase in temperature. Tetragonal phase was found to be stabilized when the sample was subjected to pressure and temperature cycle. (author)

Comparison of estimated core body temperature measured with the BioHarness and rectal temperature under several heat stress conditions.

Science.gov (United States)

Seo, Yongsuk; DiLeo, Travis; Powell, Jeffrey B; Kim, Jung-Hyun; Roberge, Raymond J; Coca, Aitor

2016-08-01

Monitoring and measuring core body temperature is important to prevent or minimize physiological strain and cognitive dysfunction for workers such as first responders (e.g., firefighters) and military personnel. The purpose of this study is to compare estimated core body temperature (Tco-est), determined by heart rate (HR) data from a wearable chest strap physiology monitor, to standard rectal thermometry (Tre) under different conditions.  Tco-est and Tre measurements were obtained in thermoneutral and heat stress conditions (high temperature and relative humidity) during four different experiments including treadmill exercise, cycling exercise, passive heat stress, and treadmill exercise while wearing personal protective equipment (PPE).  Overall, the mean Tco-est did not differ significantly from Tre across the four conditions. During exercise at low-moderate work rates under heat stress conditions, Tco-est was consistently higher than Tre at all-time points. Tco-est underestimated temperature compared to Tre at rest in heat stress conditions and at a low work rate under heat stress while wearing PPE. The mean differences between the two measurements ranged from -0.1 ± 0.4 to 0.3 ± 0.4°C and Tco-est correlated well with HR (r = 0.795 - 0.849) and mean body temperature (r = 0.637 - 0.861).  These results indicate that, the comparison of Tco-est to Tre may result in over- or underestimation which could possibly lead to heat-related illness during monitoring in certain conditions. Modifications to the current algorithm should be considered to address such issues.

Structural Studies of NH4-exchanged Natrolites at Ambient Conditions and High Temperature

Energy Technology Data Exchange (ETDEWEB)

Y Lee; D Seoung; Y Jang; J Bai; Y Lee

2011-12-31

We report here for the first time that fully and partially NH{sub 4}-exchanged natrolites can be prepared in hydrated states using the solution exchange method with potassium-natrolite. The structural models of the as-prepared hydrated phases and their dehydrated forms at elevated temperature were refined in space group Fdd2 using in situ synchrotron X-ray powder diffraction data and Rietveld methods. The unit-cell volumes of the hydrated NH{sub 4}-exchanged natrolites at ambient conditions, (NH{sub 4}){sub 16(2)}Al{sub 16}Si{sub 24}O{sub 80}{center_dot}14.1(9)H{sub 2}O and (NH{sub 4}){sub 5.1(1)}K{sub 10.9(1)}Al{sub 16}Si{sub 24}O{sub 80}{center_dot}15.7(3)H{sub 2}O, are found to be larger than that the original sodium-natrolite by ca. 15.6% and 12.8%, respectively. Upon temperature increase, the fully NH{sub 4}-exchanged natrolite undergoes dehydration at ca. 150 C with ca. 16.4% contraction in the unit-cell volume. The dehydrated phase of the fully NH{sub 4}-exchanged natrolite exhibits marginal volume expansion up to 425 C and then becomes amorphized during temperature decrease and exposure to atmospheric condition. In the case of the partially NH{sub 4}-exchanged natrolite, the dehydration starts from ca. 175 C with {approx}15.1% volume contraction and leads to a partial phase separation to show a phase related to the dehydrated K-natrolite. The degree of the phase separation decreases with temperature increase up to 475 C, concomitant to the gradual volume contraction occurring in the partially NH{sub 4}-exchanged natrolite in the dehydrared state. Upon temperature decrease and exposure to atmospheric condition, only the dehydrated K-natrolite is recovered as a crystalline phase from the partially NH{sub 4}-exchanged natrolite. In the hydrated model of the fully NH{sub 4}-exchanged natrolite, the ammonium cations and water molecules are statistically distributed along the elliptical channels, similar to the disordered pattern observed in natrolites exchanged

Fretting wear of Inconel 625 at high temperature and in high vacuum

International Nuclear Information System (INIS)

Iwabuchi, A.

1985-01-01

The purpose of this work was to investigate the fretting properties of Inconel 625 at high temperature and in high vacuum. Experiments were carried out under constant conditions with a normal load of 14 N and a peak-to-peak slip amplitude of 110 μm and through 6x10 4 cycles. Several environmental conditions were used. Pressure was varied between 10 -3 and 10 5 Pa at temperatures of 20 and 500 0 C. Temperatures up to 500 0 C were also used at pressures of 10 -3 and 10 5 Pa. At 10 -3 Pa and 500 0 C wear loss was negligible but wear scars showed severe damage consisting of deep cracks and accretion of transferred debris. The coefficient of friction then maintained a high value of 1.7 throughout the fretting test. The critical pressure below which oxidation rate becomes reduced is 10 Pa, a value independent of temperature. At pressures below this critical value the coefficient of friction increases steeply and the fretting mechanism changes from one of oxidative wear to one of adhesive wear. A compacted so-called 'glaze' oxide was formed at temperatures above 300 0 C in air (10 5 Pa) and at pressures above 10 3 Pa at 500 0 C. A comparison of results for Inconel 625 with those for S45C and SUS304 steels and Inconel 600 is given. (orig.)

Long duration performance of high temperature irradiation resistant thermocouples

International Nuclear Information System (INIS)

Rempe, J.; Knudson, D.; Condie, K.; Cole, J.; Wilkins, S.C.

2007-01-01

Many advanced nuclear reactor designs require new fuel, cladding, and structural materials. Data are needed to characterize the performance of these new materials in high temperature, radiation conditions. However, traditional methods for measuring temperature in-pile degrade at temperatures above 1100 C degrees. To address this instrumentation need, the Idaho National Laboratory (INL) developed and evaluated the performance of a high temperature irradiation-resistant thermocouple that contains alloys of molybdenum and niobium. To verify the performance of INL's recommended thermocouple design, a series of high temperature (from 1200 to 1800 C) long duration (up to six months) tests has been initiated. This paper summarizes results from the tests that have been completed. Data are presented from 4000 hour tests conducted at 1200 and 1400 C that demonstrate the stability of this thermocouple (less than 2% drift). In addition, post test metallographic examinations are discussed which confirm the compatibility of thermocouple materials throughout these long duration, high temperature tests. (authors)

Highly efficient high temperature electrolysis

DEFF Research Database (Denmark)

Hauch, Anne; Ebbesen, Sune; Jensen, Søren Højgaard

2008-01-01

High temperature electrolysis of water and steam may provide an efficient, cost effective and environmentally friendly production of H-2 Using electricity produced from sustainable, non-fossil energy sources. To achieve cost competitive electrolysis cells that are both high performing i.e. minimum...... internal resistance of the cell, and long-term stable, it is critical to develop electrode materials that are optimal for steam electrolysis. In this article electrolysis cells for electrolysis of water or steam at temperatures above 200 degrees C for production of H-2 are reviewed. High temperature...... electrolysis is favourable from a thermodynamic point of view, because a part of the required energy can be supplied as thermal heat, and the activation barrier is lowered increasing the H-2 production rate. Only two types of cells operating at high temperature (above 200 degrees C) have been described...

YCl3-Catalyzed Highly Selective Ring Opening of Epoxides by Amines at Room Temperature and under Solvent-Free Conditions

Directory of Open Access Journals (Sweden)

Wuttichai Natongchai

2017-11-01

Full Text Available A simple, efficient, and environmentally benign approach for the synthesis of β-amino alcohols is herein described. YCl3 efficiently carried out the ring opening of epoxides by amines to produce β-amino alcohols under solvent-free conditions at room temperature. This catalytic approach is very effective, with several aromatic and aliphatic oxiranes and amines. A mere 1 mol % concentration of YCl3 is enough to deliver β-amino alcohols in good to excellent yields with high regioselectivity.

Influence of thermal conditioning media on Charpy specimen test temperature

International Nuclear Information System (INIS)

Nanstad, R.K.; Swain, R.L.; Berggren, R.G.

1989-01-01

The Charpy V-notch (CVN) impact test is used extensively for determining the toughness of structural materials. Research programs in many technologies concerned with structural integrity perform such testing to obtain Charpy energy vs temperature curves. American Society for Testing and Materials Method E 23 includes rather strict requirements regarding determination and control of specimen test temperature. It specifies minimum soaking times dependent on the use of liquids or gases as the medium for thermally conditioning the specimen. The method also requires that impact of the specimen occur within 5 s removal from the conditioning medium. It does not, however, provide guidance regarding choice of conditioning media. This investigation was primarily conducted to investigate the changes in specimen temperature which occur when water is used for thermal conditioning. A standard CVN impact specimen of low-alloy steel was instrumented with surface-mounted and embedded thermocouples. Dependent on the media used, the specimen was heated or cooled to selected temperatures in the range -100 to 100 degree C using cold nitrogen gas, heated air, acetone and dry ice, methanol and dry ice, heated oil, or heated water. After temperature stabilization, the specimen was removed from the conditioning medium while the temperatures were recorded four times per second from all thermocouples using a data acquisition system and a computer. The results show that evaporative cooling causes significant changes in the specimen temperatures when water is used for conditioning. Conditioning in the other media did not result in such significant changes. The results demonstrate that, even within the guidelines of E 23, significant test temperature changes can occur which may substantially affect the Charpy impact test results if water is used for temperature conditioning. 7 refs., 11 figs

Spectroscopic studies of sulfite-based polyoxometalates at high temperature and high pressure

International Nuclear Information System (INIS)

Quesada Cabrera, Raul; Firth, Steven; Blackman, Christopher S.; Long, De-Liang; Cronin, Leroy; McMillan, Paul F.

2012-01-01

Structural changes occurring within non-conventional Dawson-type [α/β-Mo 18 O 54 (SO 3 ) 2 ] 4− polyanions in the form of tetrapentylammonium salts were studied by a combination of IR, Raman and visible spectroscopy at high temperature and high pressure. Evidence of the formation of bronze-type materials above 400 K and also upon pressurization to 8 GPa is presented. This conclusion is suggested to be a general result for polyoxometalate compounds subjected to extreme conditions and it opens opportunities for the design of new materials with interesting optical and electronic properties. - Graphical abstract: Structural changes occurring within non-conventional Dawson-type [α/β-Mo 18 O 54 (SO 3 ) 2 ] 4− polyanions in the form of tetrapentylammonium salts were studied by a combination of IR, Raman and visible spectroscopy at high temperature and high pressure. Evidence of the formation of bronze-type materials above 400 K and also upon pressurization to 8 GPa is presented. This conclusion is suggested to be a general result for polyoxometalate compounds subjected to extreme conditions and it opens opportunities for the design of new materials with interesting optical and electronic properties. Highlights: ► Spectroscopy studies of non-conventional Wells–Dawson polyoxometalates (POMs) at high temperature and high pressure. ► Discussion on the stability of two POM isomers. ► Local formation of bronze-like materials: possibilities for a new synthetic method at high pressure from POM precursors.

Tests of ball bearing used in high-temperature and high-purity water

International Nuclear Information System (INIS)

Leng Chengmu; Hao Shouxin.

1987-01-01

According to the particular conditions and the operation environments in high-temperature and high-purity water, the test content and the measurement instrumentation for the ball bearing were defined. Through various tests, operational performances of the bearing have preliminarily been understood. It provided some useful information for the engineering application of the bearing

High temperature equation of state of metallic hydrogen

International Nuclear Information System (INIS)

Shvets, V. T.

2007-01-01

The equation of state of liquid metallic hydrogen is solved numerically. Investigations are carried out at temperatures from 3000 to 20 000 K and densities from 0.2 to 3 mol/cm 3 , which correspond both to the experimental conditions under which metallic hydrogen is produced on earth and the conditions in the cores of giant planets of the solar system such as Jupiter and Saturn. It is assumed that hydrogen is in an atomic state and all its electrons are collectivized. Perturbation theory in the electron-proton interaction is applied to determine the thermodynamic potentials of metallic hydrogen. The electron subsystem is considered in the randomphase approximation with regard to the exchange interaction and the correlation of electrons in the local-field approximation. The proton-proton interaction is taken into account in the hard-spheres approximation. The thermodynamic characteristics of metallic hydrogen are calculated with regard to the zero-, second-, and third-order perturbation theory terms. The third-order term proves to be rather essential at moderately high temperatures and densities, although it is much smaller than the second-order term. The thermodynamic potentials of metallic hydrogen are monotonically increasing functions of density and temperature. The values of pressure for the temperatures and pressures that are characteristic of the conditions under which metallic hydrogen is produced on earth coincide with the corresponding values reported by the discoverers of metallic hydrogen to a high degree of accuracy. The temperature and density ranges are found in which there exists a liquid phase of metallic hydrogen

Multilayer ceramic capacitors for pulsed power, high temperature applications

International Nuclear Information System (INIS)

Cygan, S.; McLarney, J.; Prymak, J.; Bohn, P.

1991-01-01

The performance of the multilayer ceramic capacitors (MLC) in high frequency power applications has improved significantly over the last years. One of the possible applications of MLC capacitors is the automotive industry where repetitive discharging of capacitors is required. A 0.25-μF capacitor using NPO dielectric subjected to repetitive discharging with the rate of 700 pulses per second, magnitude of 600-V and 195-A peak currents showed no degradation in performance at 298 K or 398 K even after 1 billion discharge cycles. Less than a 5-K temperature rise was observed under these conditions. The most exciting, newly emerging utilization for MLC capacitors, however, might be the high temperature application (up to 473 K for underhood utilization), where ceramic capacitors with higher volumetric efficiency as compared to glass or polymer type capacitors prove very superior. Moreover ceramic capacitors, which next to glass capacitors exhibit the greatest radiation resistance among all insulating materials (Hanks and Hamman 1971), might also be best suited in the future for high temperature operation in space environment. The pulsed power performance of the 0.25-μF NPO capacitor was evaluated under repetitive discharge conditions (200 V, 700 pps) at high temperature, 473 K, and the results are presented in this paper

High temperature refrigerator

International Nuclear Information System (INIS)

Steyert, W.A. Jr.

1978-01-01

A high temperature magnetic refrigerator is described which uses a Stirling-like cycle in which rotating magnetic working material is heated in zero field and adiabatically magnetized, cooled in high field, then adiabatically demagnetized. During this cycle the working material is in heat exchange with a pumped fluid which absorbs heat from a low temperature heat source and deposits heat in a high temperature reservoir. The magnetic refrigeration cycle operates at an efficiency 70% of Carnot

Organic matter cycling in a neotropical reservoir: effects of temperature and experimental conditions

Directory of Open Access Journals (Sweden)

Flávia Bottino

2013-06-01

Full Text Available AIM:This study reports a comparison between decomposition kinetics of detritus derived from two macrophyte species (Polygonum lapathifolium L.: Polygonaceae; Eichhornia azurea (Sw. Kunth.: Pontederiaceae growing in a neotropical reservoir (Brazil, under laboratory and field conditions, in order to assess hypotheses on the main differences in factors affecting organic matter cycling, including the effect of temperature. METHODS: Plant and water samples were collected from the reservoir in August 2009. In field incubation mass loss was assessed using a litter bag technique and in the laboratory the decay was followed using a decomposition chamber maintained under controlled conditions (i.e. in the dark, at 15 ºC and 25 ºC. A kinetic model was adopted to explain and compare the organic matter decay, ANOVA (Repeated Measures testing was used to describe the differences between the treatments and a linear correlation was used to compare in situ and in vitro experiments. RESULTS: The mass decay was faster in natural conditions with rapid release of the labile-soluble portion. The simulated values of mineralization rates of dissolved organic matter and refractory organic matter were rapid in high temperatures (25 ºC. The high Q10 results (mainly for E. azurea, and experimental conditions, and outcomes of ANOVA testing indicate the temperature variation (10 ºC influence the rates of mass decay. CONCLUSIONS: The results suggested rapid organic matter cycling in warm months (from October to December supporting the microbial loop. Although the particulate organic matter losses are high in field conditions the results are of the same magnitude in both conditions suggesting an equivalence of the mass decay kinetic.

High Temperature Testing with Sapphire Fiber White-Light Michelson Interferometers

Science.gov (United States)

Barnes, A.; Pedrazzani, J.; May, R.; Murphy, K.; Tran, T.; Coate, J.

1996-01-01

In the design of new aerospace materials, developmental testing is conducted to characterize the behavior of the material under severe environmental conditions of high stress, temperature, and vibration. But to test these materials under extreme conditions requires sensors that can perform in harsh environments. Current sensors can only monitor high temperature test samples using long throw instrumentation, but this is inherently less accurate than a surface mounted sensor, and provides no means for fabrication process monitoring. A promising alternative is the use of sapphire optical fiber sensors. Sapphire is an incredibly rugged material, being extremely hard (9 mhos), chemically inert, and having a melting temperature (over 2000 C). Additionally, there is a extensive background of optical fiber sensors upon which to draw for sapphire sensor configurations.

Temperature jump boundary conditions in radiation diffusion

International Nuclear Information System (INIS)

Alonso, C.T.

1976-12-01

The radiation diffusion approximation greatly simplifies radiation transport problems. Yet the application of this method has often been unnecessarily restricted to optically thick regions, or has been extended through the use of such ad hoc devices as flux limiters. The purpose of this paper is to review and draw attention to the use of the more physically appropriate temperature jump boundary conditions for extending the range of validity of the diffusion approximation. Pioneering work has shown that temperature jump boundary conditions remove the singularity in flux that occurs in ordinary diffusion at small optical thicknesses. In this review paper Deissler's equations for frequency-dependent jump boundary conditions are presented and specific geometric examples are calculated analytically for steady state radiation transfer. When jump boundary conditions are applied to radiation diffusion, they yield exact solutions which are naturally flux- limited and geometry-corrected. We believe that the presence of temperature jumps on source boundaries is probably responsible in some cases for the past need for imposing ad hoc flux-limiting constraints on pure diffusion solutions. The solution for transfer between plane slabs, which is exact to all orders of optical thickness, also provides a useful tool for studying the accuracy of computer codes

Preparation of silver doped high temperature superconductors

International Nuclear Information System (INIS)

Stavek, Jiri; Zapletal, Vladimir

1989-01-01

High temperature superconductors were prepared by the controlled double-jet precipitation to manipulate the chemical composition, composition gradients, average grain size, grain size distribution, and other factors which contribute to the actual properties and performance of HTSC. The cations (Y-Ba-Cu or Bi-Pb-Ca-Sr-Cu) and oxalic anions solutions were simultaneously separately introduced to the crystallizer with a stirred solution of gelatin under conditions where the temperature, excess of oxalic anions in solution, pH, reactant addition rate, and other reaction conditions were tightly controlled to prepare the high sinterability powder. To increase the sinterability of submicron particles of produced precursor, the silver ions were introduced at the end of the controlled double-jet precipitation. This approach improves the electrical and mechanical properties of produced HTSC specimens. The controlled double jet precipitation provides a viable technique for preparation of oxide superconductors and the process is amenable for scaling up

A Silicon Carbide Wireless Temperature Sensing System for High Temperature Applications

Science.gov (United States)

Yang, Jie

2013-01-01

In this article, an extreme environment-capable temperature sensing system based on state-of-art silicon carbide (SiC) wireless electronics is presented. In conjunction with a Pt-Pb thermocouple, the SiC wireless sensor suite is operable at 450 °C while under centrifugal load greater than 1,000 g. This SiC wireless temperature sensing system is designed to be non-intrusively embedded inside the gas turbine generators, acquiring the temperature information of critical components such as turbine blades, and wirelessly transmitting the information to the receiver located outside the turbine engine. A prototype system was developed and verified up to 450 °C through high temperature lab testing. The combination of the extreme temperature SiC wireless telemetry technology and integrated harsh environment sensors will allow for condition-based in-situ maintenance of power generators and aircraft turbines in field operation, and can be applied in many other industries requiring extreme environment monitoring and maintenance. PMID:23377189

High temperature measurements in severe accident experiments on the PLINIUS Platform

International Nuclear Information System (INIS)

Bouyer, V.; Cassiaut-Louis, N.; Fouquart, P.; Journeau, C.; Piluso, P.; Parga, C.

2013-06-01

Severe accident experiments are conducted on the PLINIUS platform in Cadarache, using prototypic corium. During these experiments, it is essential to measure the temperature to know the thermo-physical state of the corium in static and dynamic conditions or to monitor the concrete ablation phenomenology. Temperature in the corium can reach about 2000 to 3000 K. Such aggressive conditions restrict the type of diagnostics that can be employed to do high temperature measurements during the experiments. We employ both non-intrusive (pyrometers) and intrusive (K-type and C-type thermocouples) diagnostics. In this paper, we present the different high temperature measurements techniques and the results that can be obtained in severe accident experiments as corium heating tests and molten core concrete interaction experiments. (authors)

Very High Cycle Fatigue of Ni-Based Single-Crystal Superalloys at High Temperature

Science.gov (United States)

Cervellon, A.; Cormier, J.; Mauget, F.; Hervier, Z.; Nadot, Y.

2018-05-01

Very high cycle fatigue (VHCF) properties at high temperature of Ni-based single-crystal (SX) superalloys and of a directionally solidified (DS) superalloy have been investigated at 20 kHz and a temperature of 1000 °C. Under fully reversed conditions (R = - 1), no noticeable difference in VHCF lifetimes between all investigated alloys has been observed. Internal casting pores size is the main VHCF lifetime-controlling factor whatever the chemical composition of the alloys. Other types of microstructural defects (eutectics, carbides), if present, may act as stress concentration sites when the number of cycles exceed 109 cycles or when porosity is absent by applying a prior hot isostatic pressing treatment. For longer tests (> 30 hours), oxidation also controls the main crack initiation sites leading to a mode I crack initiation from oxidized layer. Under such conditions, alloy's resistance to oxidation has a prominent role in controlling the VHCF. When creep damage is present at high ratios (R ≥ 0.8), creep resistance of SX/DS alloys governs VHCF lifetime. Under such high mean stress conditions, SX alloys developed to retard the initiation and creep propagation of mode I micro-cracks from pores have better VHCF lifetimes.

High-temperature flaw assessment procedure

International Nuclear Information System (INIS)

Ruggles, M.B.; Takahashi, Y.; Ainsworth, R.A.

1991-08-01

Described is the background work performed jointly by the Electric Power Research Institute in the United States, the Central Research Institute of Electric Power Industry in Japan and Nuclear Electric plc in the United Kingdom with the purpose of developing a high-temperature flaw assessment procedure for reactor components. Existing creep-fatigue crack-growth models are reviewed, and the most promising methods are identified. Sources of material data are outlined, and results of the fundamental deformation and crack-growth tests are discussed. Results of subcritical crack-growth exploratory tests, creep-fatigue crack-growth tests under repeated thermal transient conditions, and exploratory failure tests are presented and contrasted with the analytical modeling. Crack-growth assessment methods are presented and applied to a typical liquid-metal reactor component. The research activities presented herein served as a foundation for the Flaw Assessment Guide for High-Temperature Reactor Components Subjected to Creep-Fatigue Loading published separately. 30 refs., 108 figs., 13 tabs

Hydrogen production from biomass pyrolysis gas via high temperature steam reforming process

International Nuclear Information System (INIS)

Wongchang, Thawatchai; Patumsawad, Suthum

2010-01-01

Full text: The aim of this work has been undertaken as part of the design of continuous hydrogen production using the high temperature steam reforming process. The steady-state test condition was carried out using syngas from biomass pyrolysis, whilst operating at high temperatures between 600 and 1200 degree Celsius. The main reformer operating parameters (e.g. temperature, resident time and steam to biomass ratio (S/B)) have been examined in order to optimize the performance of the reformer. The operating temperature is a key factor in determining the extent to which hydrogen production is increased at higher temperatures (900 -1200 degree Celsius) whilst maintaining the same as resident time and S/B ratio. The effects of exhaust gas composition on heating value were also investigated. The steam reforming process produced methane (CH 4 ) and ethylene (C 2 H 4 ) between 600 to 800 degree Celsius and enhanced production ethane (C 2 H 6 ) at 700 degree Celsius. However carbon monoxide (CO) emission was slightly increased for higher temperatures all conditions. The results show that the use of biomass pyrolysis gas can produce higher hydrogen production from high temperature steam reforming. In addition the increasing reformer efficiency needs to be optimized for different operating conditions. (author)

Development and high temperature sealing performance study of double sealing flange

International Nuclear Information System (INIS)

Zhang Qinhua; Fu Yuan; Xie Leidong; Li Zhong; Tang Zhongfeng

2013-01-01

Background: Flange is an important component used in the connection between pipes or between pipe and equipment. It is widely used in mechanical industry, petrochemical industry and nuclear industry. Ordinary flange could be oxidized oi corroded under high temperature and strong corrosion condition, which leads to flange's failure. Purpose: The aim is to design and validate the double sealing flange which could be used in high temperature and strong corrosion condition stably and supplied as a reliable detachable connection for petrochemical industry and nuclear industry under high temperature and strong corrosion environment. Methods: New flange is designed using flexible graphite spiral wound gaskets and C style metal ring double sealing structure. The unique protection gas design ensures the graphite spiral wound gasket used in high temperature reliably. Test bed is built to verify the stability of the flange. Results: Pressure reducing of graphite spiral wound gasket is only 0.01 MPa at 750℃, 0.7 MPa for 43 h, there is not obvious oxidation phenomenon at the same time. The leakage rate of metal C sealing ring is 11.51×10 -4 atm cc/s, and the metal C ring sealing's performance meets the engineering requirements. Conclusion: The leakage rate of double sealing flange is almost zero under 0.7 MPa at 750℃, which meets the engineering requirements. It avoids oxidizing at high temperature and corroding under strong corrosion condition. (authors)

Sintering Characteristics of Multilayered Thermal Barrier Coatings Under Thermal Gradient and Isothermal High Temperature Annealing Conditions

Science.gov (United States)

Rai, Amarendra K.; Schmitt, Michael P.; Bhattacharya, Rabi; Zhu, Dongming; Wolfe, Douglas E.

2014-01-01

Pyrochlore oxides have most of the relevant attributes for use as next generation thermal barrier coatings such as phase stability, low sintering kinetics and low thermal conductivity. One of the issues with the pyrochlore oxides is their lower toughness and therefore higher erosion rate compared to the current state-of-the-art TBC material, yttria (6 to 8 wt%) stabilized zirconia (YSZ). In this work, sintering characteristics were investigated for novel multilayered coating consisted of alternating layers of pyrochlore oxide viz Gd2Zr2O7 and t' low k (rare earth oxide doped YSZ). Thermal gradient and isothermal high temperature (1316 C) annealing conditions were used to investigate sintering and cracking in these coatings. The results are then compared with that of relevant monolayered coatings and a baseline YSZ coating.

Investigation on the bisoliton mechanism of high-temperature superconductors

International Nuclear Information System (INIS)

Zhang Lingyun; Li Bozang; Pu Fucho; Lin Jiatih

1996-01-01

Microscopic parameters in the Davydov model are calculated on the basis of the bisoliton idea. The energy gap is obtained from combining the condition for the solution of Davydov's equation with the condensation energy of the superconductive state in zero field, and some characteristic parameters of high-temperature superconductors such as coherence length, penetration depth, and density of critical current for a thin film in weak magnetic field are given. It is also proved that lattice displacement in Davydov's equation satisfies the φ 4 field form. The critical temperature and the coefficient of linear specific heat of high-temperature superconductors are studied from the statistics of lattice kinks. The agreement between theoretical and experimental values for YBaCuO oxide ceramics suggests that the bisoliton model gives a reasonable explanation of high-temperature superconductivity. (orig.)

Design of high temperature Engineering Test Reactor (HTTR)

International Nuclear Information System (INIS)

Saito, Shinzo; Tanaka, Toshiyuki; Sudo, Yukio

1994-09-01

Construction of High Temperature Engineering Test Reactor (HTTR) is now underway to establish and upgrade basic technologies for HTGRs and to conduct innovative basic research at high temperatures. The HTTR is a graphite-moderated and helium gas-cooled reactor with 30 MW in thermal output and outlet coolant temperature of 850degC for rated operation and 950degC for high temperature test operation. It is planned to conduct various irradiation tests for fuels and materials, safety demonstration tests and nuclear heat application tests. JAERI received construction permit of HTTR reactor facility in February 1990 after 22 months of safety review. This report summarizes evaluation of nuclear and thermal-hydraulic characteristics, design outline of major systems and components, and also includes relating R and D result and safety evaluation. Criteria for judgment, selection of postulated events, major analytical conditions for anticipated operational occurrences and accidents, computer codes used in safety analysis and evaluation of each event are presented in the safety evaluation. (author)

The high-temperature reactor

International Nuclear Information System (INIS)

Kirchner, U.

1991-01-01

The book deals with the development of the German high-temperature reactor (pebble-bed), the design of a prototype plant and its (at least provisional) shut-down in 1989. While there is a lot of material on the HTR's competitor, the fast breeder, literature is very incomplete on HTRs. The author describes HTR's history as a development which was characterised by structural divergencies but not effectively steered and monitored. There was no project-oriented 'community' such as there was for the fast breeder. Also, the new technology was difficult to control there were situations where no one quite knew what was going on. The technical conditions however were not taken as facts but as a basis for interpretation, wishes and reservations. The HTR gives an opportunity to consider the conditions under which large technical projects can be carried out today. (orig.) [de

Extremely Durable, Flexible Supercapacitors with Greatly Improved Performance at High Temperatures.

Science.gov (United States)

Kim, Sung-Kon; Kim, Hae Jin; Lee, Jong-Chan; Braun, Paul V; Park, Ho Seok

2015-08-25

The reliability and durability of energy storage devices are as important as their essential characteristics (e.g., energy and power density) for stable power output and long lifespan and thus much more crucial under harsh conditions. However, energy storage under extreme conditions is still a big challenge because of unavoidable performance decays and the inevitable damage of components. Here, we report high-temperature operating, flexible supercapacitors (f-SCs) that can provide reliable power output and extreme durability under severe electrochemical, mechanical, and thermal conditions. The outstanding capacitive features (e.g., ∼40% enhancement of the rate capability and a maximum capacitances of 170 F g(-1) and 18.7 mF cm(-2) at 160 °C) are attributed to facilitated ion transport at elevated temperatures. Under high-temperature operation and/or a flexibility test in both static and dynamic modes at elevated temperatures >100 °C, the f-SCs showed extreme long-term stability of 100000 cycles (>93% of initial capacitance value) and mechanical durability after hundreds of bending cycles (at bend angles of 60-180°). Even at 120 °C, the versatile design of tandem serial and parallel f-SCs was demonstrated to provide both desirable energy and power requirements at high temperatures.

Synthesis of high-temperature viscosity stabilizer used in drilling fluid

Science.gov (United States)

Zhang, Yanna; Luo, Huaidong; Shi, Libao; Huang, Hongjun

2018-02-01

Abstract For a well performance drilling fluid, when it operates in deep wells under high temperature, the most important property required is the thermal stability. The drilling fluid properties under high temperature can be controlled by proper selection of viscosity stabilizer, which can capture oxygen to protect polymer agent in the drilling fluid. In this paper a viscosity stabilizer PB-854 is described, which was synthesized by 4-phenoxybutyl bromide, paraformaldehyde, and phloroglucinol using etherification method and condensation reaction. We studied the effect of catalyst dosage, temperature, time, and stirring rate on the synthetic yield. Under this condition: molar ratio of 2-tert-Butylphenol, paraformaldehyde and phloroglucinol of 2:1:2.5, reacting temperature of 100 °C, stirring rate of 100 r min-1, and mass content of catalyst of 15 %, char yield of 5-bromine-3-tert-butyl salicylaldehyde reached 86 %. Under this condition: molar ratio of 5-bromine-3-tert-butyl salicylaldehyde and phloroglucinol of 4, reacting temperature of 60 °C, reacting time of 30 min, volume content of sulphuric acid of 80 %, char yield of the target product viscosity stabilizer PB-854 is 86%. Finally, in this paper, infrared spectroscopy is adopted to analyse the structure of the synthetic product PB-854.The improvement in the stability of drilling fluid was further shown after adding the viscosity stabilizer in the common polymer drilling fluid under high temperature conditions of 120 °C ˜ 180 °C. The results show significant change in terms of fluid stability in the presence of this new stabilizer as it provides better stability.

Abrasive wear of ceramic wear protection at ambient and high temperatures

Science.gov (United States)

Varga, M.; Adam, K.; Tumma, M.; Alessio, K. O.

2017-05-01

Ceramic wear protection is often applied in abrasive conditions due to their excellent wear resistance. This is especially necessary in heavy industries conveying large amounts of raw materials, e.g. in steel industry. Some plants also require material transport at high temperatures and velocities, making the need of temperature stable and abrasion resistant wear protection necessary. Various types and wear behaviour of ceramic protection are known. Hence, the goal of this study is to identify the best suitable ceramic materials for abrasive conditions in harsh environments at temperatures up to 950°C and severe thermal gradients. Chamottes, known for their excellent thermal shock resistance are compared to high abrasion resistant ceramic wear tiles and a cost efficient cement-bounded hard compound. Testing was done under high-stress three-body abrasion regime with a modified ASTM G65 apparatus enabling for investigations up to ~950°C. Thereto heated abrasive is introduced into the wear track and also preheated ceramic samples were used and compared to ambient temperature experiments. Results indicate a significant temperature influence on chamottes and the hard compound. While the chamottes benefit from temperature increase, the cement-bounded hard compound showed its limitation at abrasive temperatures of 950°C. The high abrasion resistant wear tiles represented the materials with the best wear resistance and less temperature influence in the investigated range.

Recycling cellulases for cellulosic ethanol production at industrial relevant conditions: potential and temperature dependency at high solid processes.

Science.gov (United States)

Lindedam, Jane; Haven, Mai Østergaard; Chylenski, Piotr; Jørgensen, Henning; Felby, Claus

2013-11-01

Different versions of two commercial cellulases were tested for their recyclability of enzymatic activity at high dry matter processes (12% or 25% DM). Recyclability was assessed by measuring remaining enzyme activity in fermentation broth and the ability of enzymes to hydrolyse fresh, pretreated wheat straw. Industrial conditions were used to study the impact of hydrolysis temperature (40 or 50°C) and residence time on recyclability. Enzyme recycling at 12% DM indicated that hydrolysis at 50°C, though ideal for ethanol yield, should be kept short or carried out at lower temperature to preserve enzymatic activity. Best results for enzyme recycling at 25% DM was 59% and 41% of original enzyme load for a Celluclast:Novozyme188 mixture and a modern cellulase preparation, respectively. However, issues with stability of enzymes and their strong adsorption to residual solids still pose a challenge for applicable methods in enzyme recycling. Copyright © 2013 Elsevier Ltd. All rights reserved.

γ-Radiolysis of benzophenone aqueous solution at elevated temperatures up to supercritical condition

International Nuclear Information System (INIS)

Miyazaki, Toyoaki; Katsumura, Yosuke; Lin Mingzhang; Muroya, Yusa; Kudo, Hisaaki; Asano, Masaharu; Yoshida, Masaru

2006-01-01

A product analysis study of γ-irradiated benzophenone aqueous solutions from room temperature to 400 deg. C has been carried out by the combination of a flow irradiation system and a liquid chromatographic method. At room temperature, the main decomposition products are phenol and hydroxybenzophenone isomers. In high temperature and supercritical water solutions, 9-fluorenone appears as an important product and the G-value of benzophenone consumption depends significantly on the water density under supercritical conditions

Array-type sensor to determine corrosive conditions in high temperature water under gamma rays irradiation

International Nuclear Information System (INIS)

Satoh, T.; Tsukada, T.; Uchida, S.; Katoh, C.

2010-01-01

One of the problems to determine electrochemical corrosion potential (ECP) in high temperature water under irradiation is to apply long-lived and reliable reference electrodes. In order to avoid troubles due to the reference electrode, a new concept to determine ECP without the reference electrode has been proposed. Several metal plates are applied as working electrodes and at the same time as the reference electrodes. Potential of the metal plates with stable oxide films on their surfaces show stable values in high temperature water. As a result of the combination of their potential values, ECP of each metal can be determined without any specific reference electrode. Array-type sensors consisting of several metal plates, e.g., Fe, Ni, Cr, Zr, Pt, Pd, Re, Ir, with well developed oxide films on their surface were prepared for ECP measurement in high temperature water under neutron/gamma ray irradiations. In order to confirm the feasibility of this concept, responses of the redox potentials of the pure metals to changes in the simulated BWR reactor water conditions were measured and the ECP was determined by the differences in potentials between a couple of metal plates. Major conclusions of the study are as follows: 1) The redox potentials of the Fe, Pt, Zr, Ir, Pd, and Re electrodes showed the different dependences on the changes in O 2 and H 2 O 2 concentrations. The redox potentials of the electrodes increased as the oxidant concentrations increased except for Zr electrode. The potential of the Zr electrode was kept the very low potential at the wide range of O 2 and H 2 O 2 concentrations differed form the other electrodes. 2) It was estimated that the redox potential of highly soluble metal may be increased, while that of low soluble metal may be decreased by an oxide film. The stable oxide film would cause the stable potential response of the electrode with oxide film. 3) The relationship between the oxidant concentrations and the redox potentials of the

Zircaloy behaviour in high temperature irradiated water

International Nuclear Information System (INIS)

Urbanic, V.F.

1982-04-01

The corrosion and hydriding of Zircaloy during irradiation in high temperature water is strongly dependent on the oxygen concentration of the water. Corrosion tests in the NRX and NRU research reactors using small samples have demonstrated the importance of water chemistry in maintaining Zircaloy corrosion and hydriding within acceptable limits. Zircaloy fuel cladding develops non-uniform, patch-type oxides during irradiation in hich temperature water containing dissolved oxygen. Results from examinations of prototype fuel cladding irradiated in the research reactors are presented to show how local variations in coolant flow, fast neutron flux, metallurgical structure and surface condition can influence the onset of non-uniform corrosion under these conditions. Destructive examinations of CANDU-PHW reactor fuel cladding have emphasized the importance of good chemistry control, especially the dissolved oxygen concentration of the water. When reactor coolants are maintained under normal reducing conditions at high pH (5 to 10 cm 3 D 2 /kg D 2 O; 2 /kg D 2 O; pH > 10 with LiOD), Zircaloy cladding develops non-uniform, patch-type oxides. These patch-type oxides tend to coalesce with time to form a thick, uniform oxide layer after extended exposure. Under reducing coolant conditions, Zircaloy cladding absorbs less than 200 mg D/kg Zr (approximately 2.5 mg/dm 2 equivalent hydrogen) in about 500 days. With oxygen in the coolant, deuterium absorption is considerably less despite the significant increase in corrosion under such conditions

Microstructural characteristics of high-temperature oxidation in nickel-base superalloy

International Nuclear Information System (INIS)

Khalid, F.A.

1997-01-01

Superalloys are used for aerospace and nuclear applications where they can withstand high-temperature and severe oxidizing conditions. High-temperature oxidation behavior of a nickel-base superalloy is examined using optical and scanning electron microscopical techniques. The morphology of the oxide layers developed is examined, and EDX microanalysis reveals diffusion of the elements across the oxide-metal interface. Evidence of internal oxidation is presented, and the role of structural defects is considered. The morphology of the oxide-metal interface formed in the specimens exposed in steam and air is examined to elucidate the mechanism of high-temperature oxidation

High temperature defect equilibrium in ZnS:Cu single crystals

Energy Technology Data Exchange (ETDEWEB)

Lott, K.; Shinkarenko, S.; Tuern, L.; Nirk, T.; Oepik, A. [Department of Materials Science, Tallinn University of Technology, Tallinn (Estonia); Kallavus, U. [Centre for Materials Research, Tallinn University of Technology, Tallinn (Estonia); Gorokhova, E. [Scientific Research and Technological Institute of Optical Material Science, S. I. Vavilov State Optical Institute, All-Russia Science Center, St. Petersburg (Russian Federation); Grebennik, A.; Vishnjakov, A. [Department of Physical Chemistry, D. Mendelejev University of Chemical Technology of Russia, Moscow (Russian Federation)

2010-07-15

High temperature investigations in ZnS:Cu crystals were performed under defined conditions. High temperature electrical conductivity and copper solubility data were obtained under different component vapour pressures and under different sample temperatures. The experimental data at sulphur vapour pressure can be explained by the inclusion of abnormal site occupation i.e. by antistructural disorder. Compensating association of copper with this antistructure defect may occur. Antistructure disorder disappears with increasing of zinc vapour pressure and with increasing role of holes in bipolar conductivity. The method for solving the system of quasichemical reactions without approximation was used to model high temperature defect equilibrium. This model contains antistructure disorder and copper solubility limitation. (Abstract Copyright [2010], Wiley Periodicals, Inc.)

Research on infrared radiation characteristics of Pyromark1200 high-temperature coating

Science.gov (United States)

Song, Xuyao; Huan, Kewei; Dong, Wei; Wang, Jinghui; Zang, Yanzhe; Shi, Xiaoguang

2014-11-01

Pyromark 1200 (Tempil Co, USA), which is a type of high-temperature high-emissivity coating, is silicon-based with good thermal radiation performance. Its stably working condition is at the temperature range 589~922 K thus a wide range of applications in industrial, scientific research, aviation, aerospace and other fields. Infrared emissivity is one of the most important factors in infrared radiation characteristics. Data on infrared spectral emissivity of Pyromark 1200 is in shortage, as well as the reports on its infrared radiation characteristics affected by its spray painting process, microstructure and thermal process. The results of this research show that: (1) The coating film critical thickness on the metal base is 10μm according to comparison among different types of spray painting process, coating film thickness, microstructure, which would influence the infrared radiation characteristics of Pyromark 1200 coating. The infrared spectral emissivity will attenuate when the coating film thickness is lower or much higher than that. (2) Through measurements, the normal infrared radiation characteristics is analyzed within the range at the temperature range 573~873 K under normal atmospheric conditions, and the total infrared spectral emissivity of Pyromark 1200 coating is higher than 0.93 in the 3~14 μm wavelength range. (3) The result of 72-hour aging test at the temperature 673 K which studied the effect of thermal processes on the infrared radiation characteristics of the coating shows that the infrared spectral emissivity variation range is approximately 0.01 indicating that Pyromark 1200 coating is with good stability. Compared with Nextel Velvet Coating (N-V-C) which is widely used in optics field, Pyromark 1200 high-temperature coating has a higher applicable temperature and is more suitable for spraying on the material surface which is in long-term operation under high temperature work conditions and requires high infrared spectral emissivity.

High Pressure and Temperature Effects in Polymers

Science.gov (United States)

Bucknall, David; Arrighi, Valeria; Johnston, Kim; Condie, Iain

Elastomers are widely exploited as the basis for seals in gas and fluid pipelines. The underlying behaviour of these elastomer at the high pressure, elevated temperatures they experience in operation is poorly understood. Consequently, the duty cycle of these materials is often deliberately limited to a few hours, and in order to prevent failure, production is stopped in order to change the seals in critical joints. The result is significant time lost due to bringing down production to change the seals as well as knock on financial costs. In order to address the fundamental nature of the elastomers at their intended operating conditions, we are studying the gas permeation behaviour of hydrogenated natural butyl rubber (HNBR) and fluorinated elastomers (FKM) at a high pressure and elevated temperature. We have developed a pressure system that permits gas permeation studies at gas pressures of up to 5000 psi and operating temperatures up to 150° C. In this paper, we will discuss the nature of the permeation behaviour at these extreme operating conditions, and how this relates to the changes in the polymer structure. We will also discuss the use of graphene-polymer thin layer coatings to modify the gas permeation behaviour of the elastomers.

Experimental needs of high temperature concrete

International Nuclear Information System (INIS)

Chern, J.C.; Marchertas, A.H.

1985-01-01

The needs of experimental data on concrete structures under high temperature, ranging up to about 370 0 C for operating reactor conditions and to about 900 0 C and beyond for hypothetical accident conditions, are described. This information is required to supplement analytical methods which are being implemented into the finite element code TEMP-STRESS to treat reinforced concrete structures. Recommended research ranges from material properties of reinforced/prestressed concrete, direct testing of analytical models used in the computer codes, to investigations of certain aspects of concrete behavior, the phenomenology of which is not well understood. 10 refs

Lipid and carotenoid production by Rhodotorula glutinis under irradiation/high-temperature and dark/low-temperature cultivation.

Science.gov (United States)

Zhang, Zhiping; Zhang, Xu; Tan, Tianwei

2014-04-01

The capacity of lipid and carotenoid production by Rhodotorula glutinis was investigated under different irradiation conditions, temperatures and C/N ratios. The results showed that dark/low-temperature could enhance lipid content, while irradiation/high-temperature increased the yields of biomass and carotenoid. The optimum C/N ratio for production was between 80 and 100. A two-stage cultivation strategy was used for lipid and carotenoid production in a 5L fermenter. In the first stage, the maximum biomass reached 28.1g/L under irradiation/high-temperature. Then, the cultivation condition was changed to dark/low-temperature, and C/N ratio was adjusted to 90. After the second stage, the biomass, lipid content and carotenoid reached 86.2g/L, 26.7% and 4.2mg/L, respectively. More significantly, the yields of biomass and lipid were 43.1% and 11.5%, respectively. Lipids contained 79.7% 18C and 16.8% 16C fatty acids by GC analysis. HPLC quantified the main carotenoids were β-carotene (68.4%), torularhodin (21.5%) and torulene (10.1%). Crown Copyright © 2014. Published by Elsevier Ltd. All rights reserved.

Propagation of sound wave in high density deuterium at high temperatures

International Nuclear Information System (INIS)

Inoue, Kazuko; Ariyasu, Tomio

1986-01-01

The velocity and the attenuation constant of sound wave have been calculated for high density (10 24 ∼ 10 27 /cm 3 ) deuterium at high temperatures (10 -1 ∼ 10 4 eV). This calculation was made to understand the fuel properties in inertial confinement fusion and to obtain the basic data for pellet design. The isentropic sound wave which propagates in deuterium in plasma state at temperature T i = T e , is dealt with. The velocity is derived using the modulus of bulk elasticity of the whole system and the modulus of shear elasticity due to ion-ion interaction. For the calculation of attenuation constant, the bulk and shear viscosity due to ion-ion interaction, the shear viscosity of free electron gas, and the thermal conductivity due to free electrons are considered. The condition of frequency for the existence of such isentropic sound wave is discussed. The possibility of penetration into the fuel pellet in inertial confinement fusion is also discussed. The followings have been found: (1) The sound velocity is determined mainly from the bulk elasticity. The contribution of the shear elasticity is small. The velocity ranges from 2.8 x 10 6 to 1.5 x 10 8 cm/s in the above mentioned temperature and density regions. (2) The coefficient of attenuation constant with respect to ω 2 /2ρu 3 plotted versus temperature with the parameter of density shows a minimum. At temperatures below this minimum, the attenuation comes mainly from the bulk viscosity due to ion-ion interaction and the shear viscosity due to free electron gas. At temperatures above this minimum, the sound is attenuated mainly by the thermal conductivity due to electrons. (3) The condition for the existence of such adiabatic sound wave, is satisfied with the frequency less than 10 10 Hz. But, as for the pellet design, the wave length of sound with frequency less than 10 10 Hz is longer than the diameter of pellet when compressed highly. (author)

A contribution to the question of creep and relaxation of concrete under high temperatures

International Nuclear Information System (INIS)

Schneider, U.

1979-01-01

It was initially shown that, in dealing with the high temperature problem, it is expedient to distinguish certain material properties in terms of isothermal and non-isothermal conditions. A general equation of state could be derived to describe the key question complex relating to deformation behaviour of concrete under high temperatures. For the case of an isothermal temperature load under 100 0 C numerous measurement results are available from the literature. The creep behaviour of light and normal concrete up to 450 0 C was investigated and discussed. Pre-storage, concrete utilization, inelastic deformation and the influence of conditions of stress in the heat-up phase on high-temperature creep were treated. It could be shown on the basis of numerous evaluations and computer studies that also under high temperature conditions the creep behaviour of concrete is best described in terms of exponential functions. Preliminary experimental results on creep behaviour under transient temperature conditions have already been published within the framework of the sub-project ''fire properties of components''. These results, together with new measurement values have been subjected to theoretical analysis. The creep functions (phi-functions) for light and normal concrete developed for the transient temperature state constitute an important part of this work. Various suggestions have been made for criteria of failure for concrete at high tempratures. For the transient state a critical concrete temperature can be specified. Investigations on rates of deformation at the time of failure have shown that a so-called high level and low level is possible. The question of high temperature relaxation of conrete was studied both experimentally and theoretically. The constraining force problem was considered in detail in this research for comparison purposes since it offers a number of possibilities for new approaches and solutions particularly from a theoretical viewpoint. (orig

Accounting for the temperature conditions during deep prospecting hole drilling

Energy Technology Data Exchange (ETDEWEB)

Shcherban, A N; Cheniak, V P; Zolotarenko, U P

1977-01-01

A methodology is described for calculating and controlling the temperature in inclined holes in order to establish a non-steady-state heat exchange between the medium circulating in the hole, and the construction components and rock. In order to verify the proposed methodology, the temperature of the drilling fluid is measured directly during the drilling process using a specially-designed automatic device which is lowered into the hole with the drilling string and turned on automatically at a given depth. This device makes it possible to record the drilling fluid temperature on magnetic tape, and convert the sensor signals arriving from the drilling string and the annular space. A comparison of calculation and experimental data confirmed the sufficiently high accuracy of the methods for predicting the thermal conditions in drilling deep prospecting holes.

Effect of forming temperature conditions on the properties of radiation laced polyethylene films

Energy Technology Data Exchange (ETDEWEB)

Trizno, M S; Gasparyan, K A; Arutyunyan, G V; Borovko, V N

1978-11-01

The effect of radiation lace on the thermomechanical properties of polyethylene films depending on the radiation dose and temperature conditions of their formation was studied. The samples were produced at 160 deg under the pressure of 150 kN/m/sup 2/ with the following cooling in two temperature conditions: 1) cooling of the sample just after pressing in the icy water, and 2) slow cooling of the sample in a press. Films obtained using above conditions were subjected to the radiation lace in the argon medium using ..gamma..-radiation of /sup 60/Co at the exposure dose of 0.8x10/sup 6/ rad/hr. The total radiation dose was from 30 to 200 Mrad. It is shown that the films, obtained under the first cooling conditions have a lower degree of crystallinity. Investigations of gel-fraction content, density, elastic modulus, deformability, modulus of high elasticity, breaking stress, and relative elongation for rupture depending on radiation doze and the degree of crystallinity have shown that minimum degree of crystallinity of initial films provided most uniform adn compact net structure in the laced polyethylene(LP). In this case the material working capacity increases at high temperatures. In order to improve the mechanical properties of LP when exploiting it in the amorphous crystalline state it is recommended to irradiate material with maximum degree of crystallinity.

High Temperature Piezoelectric Drill

Science.gov (United States)

Bao, Xiaoqi; Bar-Cohen, Yoseph; Sherrit, Stewart; Badescu, Mircea; Shrout, Tom

2012-01-01

Venus is one of the planets in the solar systems that are considered for potential future exploration missions. It has extreme environment where the average temperature is 460 deg C and its ambient pressure is about 90 atm. Since the existing actuation technology cannot maintain functionality under the harsh conditions of Venus, it is a challenge to perform sampling and other tasks that require the use of moving parts. Specifically, the currently available electromagnetic actuators are limited in their ability to produce sufficiently high stroke, torque, or force. In contrast, advances in developing electro-mechanical materials (such as piezoelectric and electrostrictive) have enabled potential actuation capabilities that can be used to support such missions. Taking advantage of these materials, we developed a piezoelectric actuated drill that operates at the temperature range up to 500 deg C and the mechanism is based on the Ultrasonic/Sonic Drill/Corer (USDC) configuration. The detailed results of our study are presented in this paper

Flux Balance Analysis of Escherichia coli under Temperature and pH Stress Conditions

KAUST Repository

Xu, Xiaopeng

2015-05-12

An interesting discovery in biology is that most genes in an organism are dispensable. That means these genes have minor effects on survival of the organism in standard laboratory conditions. One explanation of this discovery is that some genes play important roles in specific conditions and are essential genes under those conditions. E. coli is a model organism, which is widely used. It can adapt to many stress conditions, including temperature, pH, osmotic, antibiotic, etc. Underlying mechanisms and associated genes of each stress condition responses are usually different. In our analysis, we combined protein abundance data and mutant conditional fitness data into E. coli constraint-based metabolic models to study conditionally essential metabolic genes under temperature and pH stress conditions. Flux Balance Analysis was employed as the modeling method to analysis these data. We discovered lists of metabolic genes, which are E. coli dispensable genes, but conditionally essential under some stress conditions. Among these conditionally essential genes, atpA in low pH stress and nhaA in high pH stress found experimental evidences from previous studies. Our study provides new conditionally essential gene candidates for biologists to explore stress condition mechanisms.

Pressurized Recuperator For Heat Recovery In Industrial High Temperature Processes

Directory of Open Access Journals (Sweden)

Gil S.

2015-09-01

Full Text Available Recuperators and regenerators are important devices for heat recovery systems in technological lines of industrial processes and should have high air preheating temperature, low flow resistance and a long service life. The use of heat recovery systems is particularly important in high-temperature industrial processes (especially in metallurgy where large amounts of thermal energy are lost to the environment. The article presents the process design for a high efficiency recuperator intended to work at high operating parameters: air pressure up to 1.2 MPa and temperature of heating up to 900°C. The results of thermal and gas-dynamic calculations were based on an algorithm developed for determination of the recuperation process parameters. The proposed technical solution of the recuperator and determined recuperation parameters ensure its operation under maximum temperature conditions.

High temperature material characterization and advanced materials development

International Nuclear Information System (INIS)

Ryu, Woo Seog; Kim, D. H.; Kim, S. H. and others

2005-03-01

The study is to characterize the structural materials under the high temperature, one of the most significant environmental factors in nuclear systems. And advanced materials are developed for high temperature and/or low activation in neutron irradiation. Tensile, fatigue and creep properties have been carried out at high temperature to evaluate the mechanical degradation. Irradiation tests were performed using the HANARO. The optimum chemical composition and heat treatment condition were determined for nuclear grade 316NG stainless steel. Nitrogen, aluminum, and tungsten were added for increasing the creep rupture strength of FMS steel. The new heat treatment method was developed to form more stable precipitates. By applying the novel whiskering process, high density SiC/SiC composites with relative density above 90% could be obtained even in a shorter processing time than the conventional CVI process. Material integrated databases are established using data sheets. The databases of 6 kinds of material properties are accessible through the home page of KAERI material division

High temperature industrial heat pumps

Energy Technology Data Exchange (ETDEWEB)

Berghmans, J. (Louvain Univ., Heverlee (Belgium). Inst. Mechanica)

1990-01-01

The present report intends to describe the state of the art of high temperature industrial heat pumps. A description is given of present systems on the market. In addition the research and development efforts on this subject are described. Compression (open as well as closed cycle) systems, as well as absorption heat pumps (including transformers), are considered. This state of the art description is based upon literature studies performed by a team of researchers from the Katholieke Universiteit Leuven, Belgium. The research team also analysed the economics of heat pumps of different types under the present economic conditions. The heat pumps are compared with conventional heating systems. This analysis was performed in order to evaluate the present condition of the heat pump in the European industry.

Identifying Changes in the Probability of High Temperature, High Humidity Heat Wave Events

Science.gov (United States)

Ballard, T.; Diffenbaugh, N. S.

2016-12-01

Understanding how heat waves will respond to climate change is critical for adequate planning and adaptation. While temperature is the primary determinant of heat wave severity, humidity has been shown to play a key role in heat wave intensity with direct links to human health and safety. Here we investigate the individual contributions of temperature and specific humidity to extreme heat wave conditions in recent decades. Using global NCEP-DOE Reanalysis II daily data, we identify regional variability in the joint probability distribution of humidity and temperature. We also identify a statistically significant positive trend in humidity over the eastern U.S. during heat wave events, leading to an increased probability of high humidity, high temperature events. The extent to which we can expect this trend to continue under climate change is complicated due to variability between CMIP5 models, in particular among projections of humidity. However, our results support the notion that heat wave dynamics are characterized by more than high temperatures alone, and understanding and quantifying the various components of the heat wave system is crucial for forecasting future impacts.

Numerical investigation of heat transfer in high-temperature gas-cooled reactors

Energy Technology Data Exchange (ETDEWEB)

Chen, g.; Anghaie, S. [Univ. of Florida, Gainesville, FL (United States)

1995-09-01

This paper proposes a computational model for analysis of flow and heat transfer in high-temperature gas-cooled reactors. The formulation of the problem is based on using the axisymmetric, thin layer Navier-Stokes equations. A hybrid implicit-explicit method based on finite volume approach is used to numerically solve the governing equations. A fast converging scheme is developed to accelerate the Gauss-Siedel iterative method for problems involving the wall heat flux boundary condition. Several cases are simulated and results of temperature and pressure distribution in the core are presented. Results of a parametric analysis for the assessment of the impact of power density on the convective heat transfer rate and wall temperature are discussed. A comparative analysis is conducted to identify the Nusselt number correlation that best fits the physical conditions of the high-temperature gas-cooled reactors.

Thermal analysis of high temperature phase transformations of steel

Directory of Open Access Journals (Sweden)

K. Gryc

2013-10-01

Full Text Available The series of thermal analysis measurements of high temperature phase transformations of real grain oriented electrical steel grade under conditions of two analytical devices (Netzsch STA 449 F3 Jupiter; Setaram SETSYS 18TM were carried out. Two thermo analytical methods were used (DTA and Direct thermal analysis. The different weight of samples was used (200 mg, 23 g. The stability/reproducibility of results obtained by used methodologies was verified. The liquidus and solidus temperatures for close to equilibrium conditions and during cooling (20 °C/min; 80 °C/min were determined. It has been shown that the higher cooling rate lead to lower temperatures for start and end of solidification process of studied steel grade.

Quasispin model of itinerant magnetism: High-temperature theory

International Nuclear Information System (INIS)

Liu, S.H.

1977-01-01

The high-temperature properties of itinerant magnetic systems are examined by using the coherent-potential approximation. We assume a local moment on each atom so that at elevated temperatures there is a number of reversed spins. The coherent potential is solved, and from that the moment on each atom is determined self-consistently. It is found that when the condition for ferromagnetic ordering is satisfied, the local moments persist even above the critical temperature. Conversely, if local moments do not exist at high temperatures, the system can at most condense into a spin-density-wave state. Furthermore, spin-flip scatterings of the conduction electrons from the local moments give rise to additional correlation not treated in the coherent-potential approximation. This correlation energy is an important part of the coupling energy of the local moments. The relations between our work and the theories of Friedel, Hubbard, and others are discussed

Elastic Wave Velocity Measurements on Mantle Peridotite at High Pressure and Temperature

Science.gov (United States)

Mistler, G. W.; Ishikawa, M.; Li, B.

2002-12-01

With the success of conducting ultrasonic measurements at high pressure and high temperature in large volume high pressure apparatus with in-situ measurement of the sample length by X-ray imaging, it is now possible to measure elastic wave velocities on aggregate samples with candidate compositions of the mantle to the conditions of the Earth's transition zone in the laboratory. These data can be directly compared with seismic data to distinguish the compositional models in debate. In this work, we carried out velocity measurements on natural peridotite KLB-1 at the conditions of the Earth's upper mantle. Fine powered sample of natural KLB-1 was used as starting material. Specimens for ultrasonic measurements were hot-pressed and equilibrated at various pressure and temperature conditions along geotherm up to the transition zone. The recovered samples were characterized with density measurement, X-ray diffraction and microprobe analysis. Bench top P and S wave velocities of KLB-1 sample sintered at 3-4 GPa and 1400 degree centigrade showed a very good agreement with the VRH average of pyrolite. High pressure and high temperature measurements was conducted up to 7 GPa and 800 degree centigrade using ultrasonic interferometric method in a DIA-type high pressure apparatus in conjunction with X-ray diffraction and X-ray imaging. The utilization of X-ray imaging technique provides direct measurements of sample lengths at high pressure and high temperature, ensuring a precise determination of velocities. The results of P and S wave velocities at high pressure and high temperature as well as their comparison with calculated pyrolite model will be presented.

Containment test in area of high latitude and low temperature

International Nuclear Information System (INIS)

Cai Jiantao; Ni Yongsheng; Jia Wutong

2014-01-01

The effects of high latitude and low temperature on containment test are detailed analyzed from the view of design, equipment, construct and start-up, and the solution is put forward. The major problems resolved is as below: the effects of low temperature and high wind on defect inspection of the containment surface, the effects of test load on the affiliated equipment of containment in the condition of low temperature, and the effects of low temperature on the containment leak rate measurement. Application in Hongyanhe Unit 1 showed that the proposed scheme can effectively overcome the influence of adverse weather on the containment test. (authors)

Frictional characteristics of silicon graphite lubricated with water at high pressure and high temperature

International Nuclear Information System (INIS)

Lee, Jae Seon; Kim, Eun Hyun; Park, Jin Seok; Kim, Jong In

2001-01-01

Experimental frictional and wear characteristics of silicon graphite materials is studied in this paper. Those specimens are lubricated with high temperature and highly pressurized water to simulate the same operating condition for the journal bearing and the thrust bearing on the main coolant pump bearing in the newly developing nuclear reactor named SMART(System-integrated Modular Advanced ReacTor). Operating condition of the bearings is realized by the tribometer and the autoclave. Friction coefficient and wear loss are analyzed to choose the best silicon graphite material. Pin on plate test specimens are used and coned disk springs are used to control the applied force on the specimens. Wear loss and wear width are measured by a precision balance and a micrometer. The friction force is measured by the strain gauge which can be used under high temperature and high pressure. Three kinds of silicon graphite materials are examined and compared with each other, and each material shows similar but different results on frictional and wear characteristics

Electrode for improving electrochemical measurements in high temperature water

International Nuclear Information System (INIS)

Sengarsai, T.

2005-01-01

A silver/silver-chloride (Ag/AgCl) reference electrode was specially designed and constructed in a body of oxidized titanium for potentiometric measurements under high-temperature and high-pressure conditions. To avoid the thermal decomposition of silver-chloride, the electrode is designed to maintain the reference element at low temperature while it is still connected to high-temperature process zone via a non-isothermal electrolyte bridge. This configuration leads to the development of a thermal gradient along the length of the electrode. At room temperature, the stability of the Ag/AgCl reference electrode versus a standard calomel electrode (SCE) is maintained with an accuracy of 5 mV. The electrode's performance at high temperature and pressure (up to 300 o C and 1500 psi) was examined by measuring the potential difference against platinum, which acted as a reversible hydrogen electrode (RHE). Comparison of the experimental and theoretical values verifies the reliability and reproducibility of the electrode. Deviation from the Nernst equation is considered and related to the thermal liquid junction potential (TLJP). An empirical correction factor is used to maintain the Ag/AgCl potential within an acceptable accuracy limit of ±20 mV at high temperature. (author)

Design and realization of high voltage disconnector condition monitoring system

Science.gov (United States)

Shi, Jinrui; Xu, Tianyang; Yang, Shuixian; Li, Buoyang

2017-08-01

The operation status of the high voltage disconnector directly affects the safe and stable operation of the power system. This article uses the wireless frequency hopping communication technology of the communication module to achieve the temperature acquisition of the switch contacts and high voltage bus, to introduce the current value of the loop in ECS, and judge the operation status of the disconnector by considering the ambient temperature, calculating the temperature rise; And through the acquisition of the current of drive motor in the process of switch closing and opening, and fault diagnosis of the disconnector by analyzing the change rule of the drive motor current, the condition monitoring of the high voltage disconnector is realized.

Co and Fe-catalysts supported on sepiolite: effects of preparation conditions on their catalytic behaviors in high temperature gas flow treatment of dye.

Science.gov (United States)

Lin, Xiangfeng; Fang, Jian; Chen, Menglin; Huang, Zhi; Su, Chengyuan

2016-08-01

An efficient adsorbent/catalyst Co and Fe-catalysts loaded on sepiolite (Co-Fe/sepiolite) was successfully prepared for high temperature gas flow catalytic reaction by a simple impregnation method. The impact of preparation conditions (such as pH value of impregnation solution, impregnation time, calcination temperature, and time) on catalytic activity was studied. We found that the catalytic activity of Co-Fe/sepiolite was strongly influenced by all the investigated parameters. The regeneration efficiency (RE) was used to evaluate the catalytic activity. The RE is more noticeable at pH 5.0 of impregnation solution, impregnation time 18 h, calcination temperature 650 °C, and calcination time 3 h. This Co-Fe/sepiolite has great adsorption capacity in absorbing dye. It is used for an adsorbent to adsorb dye from wastewater solution under dynamic adsorption and saturated with dye, then regenerated with high temperature gas flow for adsorption/oxidation cycles. The Co-Fe/sepiolite acts as a catalyst to degrade the dye during regeneration under high temperature gas flow. Hence, the Co-Fe/sepiolite is not only an adsorbent but also a catalyst. The Co-Fe/sepiolite is more stable than sepiolite when applied in the treatment of plant's wastewater. The Co-Fe/sepiolite can be reused in adsorption-regeneration cycle. The results indicate the usability of the proposed combined process, dye adsorption on Co-Fe/sepiolite followed by the catalytic oxidation in high temperature gas flow.

High temperature superconductor current leads

International Nuclear Information System (INIS)

Zeimetz, B.; Liu, H.K.; Dou, S.X.

1996-01-01

Full text: The use of superconductors in high electrical current applications (magnets, transformers, generators etc.) usually requires cooling with liquid Helium, which is very expensive. The superconductor itself produces no heat, and the design of Helium dewars is very advanced. Therefore most of the heat loss, i.e. Helium consumption, comes from the current lead which connects the superconductor with its power source at room temperature. The current lead usually consists of a pair of thick copper wires. The discovery of the High Temperature Superconductors makes it possible to replace a part of the copper with superconducting material. This drastically reduces the heat losses because a) the superconductor generates no resistive heat and b) it is a very poor thermal conductor compared with the copper. In this work silver-sheathed superconducting tapes are used as current lead components. The work comprises both the production of the tapes and the overall design of the leads, in order to a) maximize the current capacity ('critical current') of the superconductor, b) minimize the thermal conductivity of the silver clad, and c) optimize the cooling conditions

Temperature effect on rose downy mildew development under environmental controlled conditions

Directory of Open Access Journals (Sweden)

Juan José Filgueira D.

2014-04-01

Full Text Available The rose downy mildew disease, caused by Peronospora sparsa Berkeley, is one of the most important that affect rose crops in Colombia. To manage this disease, flower growers must deal with high-costs due to the excessive application of fungicides, but without good results. Studies on P. sparsa behavior have shown its narrow relationship with environmental conditions. In this study, the temperature effect was evaluated during the infection and sporulation of P. sparsa in Charlotte leaflets, a susceptible commercial variety, through an environmental controlled conditions system. Infection and sporulation were observed at different temperatures in a range of from 4 to 40°C. Infection with the absence of or very low sporulation was observed at 4°C. The most favorable pathogen responses were between 15 and 18°C in terms of inoculum concentration and sporulation percentage. There was no infection or leaflet change above 35°C. According to the results, sporulation can occur from 4 to 33°C, confirming the fact that P. sparsa is able to reproduce throughout a wide temperature range.

High concentration agglomerate dynamics at high temperatures.

Science.gov (United States)

Heine, M C; Pratsinis, S E

2006-11-21

The dynamics of agglomerate aerosols are investigated at high solids concentrations that are typical in industrial scale manufacture of fine particles (precursor mole fraction larger than 10 mol %). In particular, formation and growth of fumed silica at such concentrations by chemical reaction, coagulation, and sintering is simulated at nonisothermal conditions and compared to limited experimental data and commercial product specifications. Using recent chemical kinetics for silica formation by SiCl4 hydrolysis and neglecting aerosol polydispersity, the evolution of the diameter of primary particles (specific surface area, SSA), hard- and soft-agglomerates, along with agglomerate effective volume fraction (volume occupied by agglomerate) is investigated. Classic Smoluchowski theory is fundamentally limited for description of soft-agglomerate Brownian coagulation at high solids concentrations. In fact, these high concentrations affect little the primary particle diameter (or SSA) but dominate the soft-agglomerate diameter, structure, and volume fraction, leading to gelation consistent with experimental data. This indicates that restructuring and fragmentation should affect product particle characteristics during high-temperature synthesis of nanostructured particles at high concentrations in aerosol flow reactors.

High Temperature Properties and Recent Research Trend of Mg-RE Alloys

Energy Technology Data Exchange (ETDEWEB)

Nam, Soo Woo [Korea Institute of Science and Technology Information, Seoul (Korea, Republic of)

2017-04-15

For the applications in automotive, aircraft, aerospace, and electronic industries, the lightest structural Mg alloys have received much attention since 2000. There has been some progress for the improvement of the mechanical properties such as room temperature strength, formability and mechanical anisotropy. However, the high temperature strength of Mg alloys is very low to be used for the parts and structures of high temperature conditions. For the last decade, considerable efforts are concentrated for the development of Mg alloys to be used at high temperature. Newly developing Mg-RE alloys are the good examples for the high temperature use. In this regard, this review paper introduces the recent research trends for the development of Mg-RE alloys strengthened with some precipitates and the long period stacking ordered (LPSO) structures related RE elements.

High Temperature Properties and Recent Research Trend of Mg-RE Alloys

International Nuclear Information System (INIS)

Nam, Soo Woo

2017-01-01

For the applications in automotive, aircraft, aerospace, and electronic industries, the lightest structural Mg alloys have received much attention since 2000. There has been some progress for the improvement of the mechanical properties such as room temperature strength, formability and mechanical anisotropy. However, the high temperature strength of Mg alloys is very low to be used for the parts and structures of high temperature conditions. For the last decade, considerable efforts are concentrated for the development of Mg alloys to be used at high temperature. Newly developing Mg-RE alloys are the good examples for the high temperature use. In this regard, this review paper introduces the recent research trends for the development of Mg-RE alloys strengthened with some precipitates and the long period stacking ordered (LPSO) structures related RE elements.

High-Temperature Structural Analysis of a Small-Scale Prototype of a Process Heat Exchanger (IV) - Macroscopic High-Temperature Elastic-Plastic Analysis -

International Nuclear Information System (INIS)

Song, Kee Nam; Hong, Sung Deok; Park, Hong Yoon

2011-01-01

A PHE (Process Heat Exchanger) is a key component required to transfer heat energy of 950 .deg. C generated in a VHTR (Very High Temperature Reactor) to a chemical reaction that yields a large quantity of hydrogen. A small-scale PHE prototype made of Hastelloy-X was scheduled for testing in a small-scale gas loop at the Korea Atomic Energy Research Institute. In this study, as a part of the evaluation of the high-temperature structural integrity of the PHE prototype, high-temperature structural analysis modeling, and macroscopic thermal and elastic-plastic structural analysis of the PHE prototype were carried out under the gas-loop test conditions as a preliminary qwer123$ study before carrying out the performance test in the gas loop. The results obtained in this study will be used to design the performance test setup for the modified PHE prototype

Numerical Analysis of Exergy for Air-Conditioning Influenced by Ambient Temperature

Directory of Open Access Journals (Sweden)

Jing-Nang Lee

2014-07-01

Full Text Available The article presents numerical analysis of exergy for air-conditioning influenced by ambient temperature. The model of numerical simulation uses an integrated air conditioning system exposed in varied ambient temperature to observe change of the four main devices, the compressor, the condenser, the capillary, and the evaporator in correspondence to ambient temperature. The analysis devices of the four devices’s exergy influenced by the varied ambient temperature and found that the capillary has unusual increasing exergy loss vs. increasing ambient temperature in comparison to the other devices. The result shows that reducing exergy loss of the capillary influenced by the ambient temperature is the key for improving working efficiency of an air-conditioning system when influence of the ambient temperature is considered. The higher ambient temperature causes the larger pressure drop of capillary and more exergy loss.

High temperature x-ray micro-tomography

Energy Technology Data Exchange (ETDEWEB)

MacDowell, Alastair A., E-mail: aamacdowell@lbl.gov; Barnard, Harold; Parkinson, Dilworth Y.; Gludovatz, Bernd [Lawrence Berkeley National Lab., Berkeley, CA 94720 (United States); Haboub, Abdel [Lawrence Berkeley National Lab., Berkeley, CA 94720 (United States); current –Lincoln Univ., Jefferson City, Missouri, 65101 (United States); Larson, Natalie; Zok, Frank [University California Santa Barbara, Santa Barbara CA 93106 (United States); Panerai, Francesco; Mansour, Nagi N. [NASA Ames Research Centre, Moffett Field, CA, 94035 (United States); Bale, Hrishikesh [University California Berkeley, Berkeley, CA 94720 (United States); current - Carl Zeiss X-ray Microscopy, 4385 Hopyard Rd #100, Pleasanton, CA 94588 (United States); Acevedo, Claire [Lawrence Berkeley National Lab., Berkeley, CA 94720 (United States); University California San Francisco, San Francisco, CA 94143 (United States); Liu, Dong [University of Bristol, Bristol BS8 1TH (United Kingdom); Ritchie, Robert O. [Lawrence Berkeley National Lab., Berkeley, CA 94720 (United States); University California Berkeley, Berkeley, CA 94720 (United States)

2016-07-27

There is increasing demand for 3D micro-scale time-resolved imaging of samples in realistic - and in many cases extreme environments. The data is used to understand material response, validate and refine computational models which, in turn, can be used to reduce development time for new materials and processes. Here we present the results of high temperature experiments carried out at the x-ray micro-tomography beamline 8.3.2 at the Advanced Light Source. The themes involve material failure and processing at temperatures up to 1750°C. The experimental configurations required to achieve the requisite conditions for imaging are described, with examples of ceramic matrix composites, spacecraft ablative heat shields and nuclear reactor core Gilsocarbon graphite.

A study on variations of the low cycle fatigue life of a high pressure turbine nozzle caused by inlet temperature profiles and installation conditions

Energy Technology Data Exchange (ETDEWEB)

Huh, Jae Sung; Kang, Young Seok; Rhee, Dong Ho [Aero-propulsion Research Office, Korea Aerospace Research Institute, Daejeon (Korea, Republic of); Seo, Do Young [School of Mechanical and Aerospace Engineering, Pusan National University, Busan (Korea, Republic of)

2015-11-15

High pressure components of a gas turbine engine must operate for a long life under severe conditions in order to maximize the performance and minimize the maintenance cost. Enhanced cooling design, thermal barrier coating techniques, and nickel-base superalloys have been applied for overcoming them and furthermore, material modeling, finite element analysis, statistical techniques, and etc. in design stage have been utilized widely. This article aims to evaluate the effects on the low cycle fatigue life of the high pressure turbine nozzle caused by different turbine inlet temperature profiles and installation conditions and to investigate the most favorable operating condition to the turbine nozzle. To achieve it, the structural analysis, which utilized the results of conjugate heat transfer analysis as loading boundary conditions, was performed and its results were the input for the assessment of low cycle fatigue life at several critical zones.

A Study on Variations of the Low Cycle Fatigue Life of a High Pressure Turbine Nozzle Caused by Inlet Temperature Profiles and Installation Conditions

Energy Technology Data Exchange (ETDEWEB)

Hur, Jae Sung; Kang, Young Seok; Rhee, Dong Ho [Korea Aerospace Research Institute, Daejeon (Korea, Republic of); Seo, Do Young [Pusan National Univ., Busan (Korea, Republic of)

2015-11-15

High pressure components of a gas turbine engine must operate for a long life under severe conditions in order to maximize the performance and minimize the maintenance cost. Enhanced cooling design, thermal barrier coating techniques, and nickel-base superalloys have been applied for overcoming them and furthermore, material modeling, finite element analysis, statistical techniques, and etc. in design stage have been utilized widely. This article aims to evaluate the effects on the low cycle fatigue life of the high pressure turbine nozzle caused by different turbine inlet temperature profiles and installation conditions and to investigate the most favorable operating condition to the turbine nozzle. To achieve it, the structural analysis, which utilized the results of conjugate heat transfer analysis as loading boundary conditions, was performed and its results were the input for the assessment of low cycle fatigue life at several critical zones.

Discussion on Design Transients of Pebble-bed High Temperature Gas-cooled Reactor

International Nuclear Information System (INIS)

Wang Yan; Li Fu; Zheng Yanhua

2014-01-01

In order to assure high quality for the components and their supports in the reactor coolant system, etc., some thermal-hydraulic transient conditions will be selected and researched for equipment design evaluation to satisfy the requirements ASME code, which are based on the conservative estimates of the magnitude and frequency of the temperature and pressure transients resulting from various operating conditions in the plant. In the mature design on pressurized water reactor, five conditions are considered. For the developing advanced pebble-bed high temperature gas-cooled reactor(HTGR), its design and operation has much difference with other reactors, so the transients of the pebble-bed high temperature gas-cooled reactor have distinctive characteristics. In this paper, the possible design transients of the pebble-bed HTGR will be discussed, and the frequency of design transients for equipment fatigue analysis and stress analysis due to cyclic stresses is also studied. The results will provide support for the design and construct of the pebble-bed HTGR. (author)

Practical ultrasonic transducers for high-temperature applications using bismuth titanate and Ceramabind 830

Science.gov (United States)

Xu, Janet L.; Batista, Caio F. G.; Tittmann, Bernhard R.

2018-04-01

Structural health monitoring of large valve bodies in high-temperature environments such as power plants faces several limitations: commercial transducers are not rated for such high temperatures, gel couplants will evaporate, and measurements cannot be made in-situ. To solve this, we have furthered the work of Ledford in applying a practical transducer in liquid form which hardens and air dries directly onto the substrate. The transducer material is a piezoceramic film composed of bismuth titanate and a high-temperature binding agent, Ceramabind 830. The effects of several fabrication conditions were studied to optimize transducer performance and ensure repeatability. These fabrication conditions include humidity, binder ratio, water ratio, substrate roughness, and film thickness. The final product is stable for both reactive and non-reactive substrates, has a quick fabrication time, and has an operating temperature up to the Curie temperature of BIT, 650°C, well beyond the safe operating temperature of PZT (150°C).

Advances in high temperature chemistry

CERN Document Server

Eyring, Leroy

1969-01-01

Advances in High Temperature Chemistry, Volume 2 covers the advances in the knowledge of the high temperature behavior of materials and the complex and unfamiliar characteristics of matter at high temperature. The book discusses the dissociation energies and free energy functions of gaseous monoxides; the matrix-isolation technique applied to high temperature molecules; and the main features, the techniques for the production, detection, and diagnosis, and the applications of molecular beams in high temperatures. The text also describes the chemical research in streaming thermal plasmas, as w

Performance test of ex-core high temperature and high pressure water loop test equipment (Contract research)

International Nuclear Information System (INIS)

Nakano, Hiroko; Uehara, Toshiaki; Takeuchi, Tomoaki; Shibata, Hiroshi; Nakamura, Jinichi; Matsui, Yoshinori; Tsuchiya, Kunihiko

2016-03-01

In Japan Atomic Energy Agency, we started research and development so as to monitor the situations in the Nuclear Plant Facilities during a severe accident, such as a radiation-resistant monitoring camera, a radiation-resistant transmission system for conveying the in-core information, and a heat-resistant signal cable. As a part of developments of the heat-resistant signal cable, we prepared ex-core high-temperature and high-pressure water loop test equipment, which can simulate the conditions of BWRs and PWRs, for evaluating reliability and properties of sheath materials of the cable. This equipment consists of autoclave, water conditioning tank, high-pressure metering pump, preheater, heat exchanger and water purification equipment, etc. This report describes the basic design and the performance test results of ex-core high-temperature and high-pressure water loop test equipment. (author)

Enhancing the high temperature capability of Ti-alloys

Energy Technology Data Exchange (ETDEWEB)

Donchev, Alexander; Schuetze, Michael [DECHEMA-Forschungsinstitut, Frankfurt/Main (Germany); Kolitsch, Andreas; Yankov, Rossen [Helmholtz-Zentrum Dresden-Rossendorf, Institute of Ion Beam Physics and Materials Research, Dresden (Germany)

2012-08-15

Titanium is a widely used structural material for applications below approximately 500 C but right now it cannot be used at higher temperatures. Titanium forms a fast growing rutile layer under these conditions. Furthermore enhanced oxygen uptake into the metal subsurface zone leads to embrittlement which deteriorates the mechanical properties. To overcome this problem a combined Al- plus F-treatment was developed. The combination of Al-enrichment in the surface zone so that intermetallic Ti{sub x}Al{sub y}-layers are produced which form a protective alumina layer during high temperature exposure plus stabilization of the Al{sub 2}O{sub 3}-scale by the fluorine effect led to significantly improved resistance against increased oxidation and embrittlement in high temperature exposure tests of several Ti-alloys. In this paper, the experimental procedures and achieved improvements are described. The results will be discussed for the use of Ti-alloys at elevated temperatures. (Copyright copyright 2012 WILEY-VCH Verlag GmbH and Co. KGaA, Weinheim)

Performance of HT9 clad metallic fuel at high temperature

International Nuclear Information System (INIS)

Pahl, R.G.; Lahm, C.E.; Hayes, S.L.

1992-01-01

Steady-state testing of HT9 clad metallic fuel at high temperatures was initiated in EBR-II in November of 1987. At that time U-10 wt. % Zr fuel clad with the low-swelling ferritic/martensitic alloy HT9 was being considered as driver fuel options for both EBR-II and FFTF. The objective of the X447 test described here was to determine the lifetime of HT9 cladding when operated with metallic fuel at beginning of life inside wall temperatures approaching ∼660 degree C. Though stress-temperature design limits for HT9 preclude its use for high burnup applications under these conditions due to excessive thermal creep, the X447 test was carried out to obtain data on high temperature breach phenomena involving metallic fuel since little data existed in that area

Potential uses of high gradient magnetic filtration for high-temperature water purification in boiling water reactors

International Nuclear Information System (INIS)

Elliott, H.H.; Holloway, J.H.; Abbott, D.G.

1979-01-01

Studies of various high-temperature filter devices indicate a potentially positive impact for high gradient magnetic filtration on boiling water reactor radiation level reduction. Test results on in-plant water composition and impurity crystallography are presented for several typical boiling water reactors (BWRs) on plant streams where high-temperature filtration may be particularly beneficial. An experimental model on the removal of red iron oxide (hematite) from simulated reactor water with a high gradient magnetic filter is presented, as well as the scale-up parameters used to predict the filtration efficiency on various high temperature, in-plant streams. Numerical examples are given to illustrate the crud removal potential of high gradient magnetic filters installed at alternative stream locations under typical, steady-state, plant operating conditions

Catalyst dispersion and activity under conditions of temperature-staged liquefaction. Final report

Energy Technology Data Exchange (ETDEWEB)

Davis, A.; Schobert, H.H.; Mitchell, G.D.; Artok, L.

1993-02-01

This research program involves the investigation of the use of highly dispersed catalyst precursors for the pretreatment of coals by mild hydrogenation. During the course of this effort solvent preswelling of the coal was evaluated as a means of deeply impregnating catalysts into coal, active phases of catalysts under reaction conditions were studied and the impact of these techniques were evaluated during pretreatment and temperature-staged liquefaction. Two coals, a Texas subbituminous and a Utah high volatile A bituminous, were used to examine the effects of solvent swelling pretreatment and catalyst impregnation on conversion behavior at 275{degrees}C, representative of the first, low-temperature stage in a temperature-staged liquefaction reaction. Ferrous sulfate, iron pentacarbonyl, ammonium tetrathiomolybdate, and molybdenum hexacarbonyl were used as catalyst precursors. Without swelling pretreatment, impregnation of both coals increased conversion, mainly through increased yields of preasphaltenes.

The Effect Of The Reactive Element On The CHROMOXIDE And Aluminide Layers In The High Temperature Condition

International Nuclear Information System (INIS)

Dani, Mohammad; Effendi, Nurdin

2000-01-01

Oxide layers at high temperature condition, as Cr 2 O 3 , AI 2 O 3 , growing act not only as corrosion barrier, but also as a diffusion barrier of agressive components. MA956 and Ni75Cr25 alloy were studied to observe the elIect of Yttrium coating on their oxidation behavior. The influence ofthese coatings on the oxidation behaviour of the alloy was studied, Thin coatings of Yttrium have been applied to the surface of those alloys by vacuum coating The growth of the oxide layers under controlled has been investigated in this work by Analytical Transmission Electron Microscope (ATEM) and Scanning Electron Microscopy (SEM), It was found that addition of small amounts of elements such as Yttrium to these alloys greatly increase their oxidation resistance,

High-temperature superconductivity

International Nuclear Information System (INIS)

Lynn, J.W.

1990-01-01

This book discusses development in oxide materials with high superconducting transition temperature. Systems with Tc well above liquid nitrogen temperature are already a reality and higher Tc's are anticipated. The author discusses how the idea of a room-temperature superconductor appears to be a distinctly possible outcome of materials research

High-temperature helium-loop facility

International Nuclear Information System (INIS)

Tokarz, R.D.

1981-09-01

The high-temperature helium loop is a facility for materials testing in ultrapure helium gas at high temperatures. The closed loop system is capable of recirculating high-purity helium or helium with controlled impurities. The gas loop maximum operating conditions are as follows: 300 psi pressure, 500 lb/h flow rate, and 2100 0 F temperature. The two test sections can accept samples up to 3.5 in. diameter and 5 ft long. The gas loop is fully instrumented to continuously monitor all parameters of loop operation as well as helium impurities. The loop is fully automated to operate continuously and requires only a daily servicing by a qualified operator to replenish recorder charts and helium makeup gas. Because of its versatility and high degree of parameter control, the helium loop is applicable to many types of materials research. This report describes the test apparatus, operating parameters, peripheral systems, and instrumentation system. The experimental capabilities and test conand presents the results that have been obtained. The study has been conducted using a four-phase approach. The first phase develops the solution to the steady-state radon-diffusion equation in one-dimensieered barriers; disposal charge analysis; analysis of spent fuel policy implementation; spent f water. Field measurements and observations are reported for each site. Analytical data and field measurements are presented in tables and maps. Uranium concentrations in the sediments which were above detection limits ranged from 0.10 t 51.2 ppM. The mean of the logarithms of the uranium concentrations was 0.53. A group of high uranium concentrations occurs near the junctions of quadrangles AB, AC, BB, a 200 mK. In case 2), x-ray studies of isotopic phase separation in 3 He-- 4 He bcc solids were carried out by B. A. Fraass

High temperature measurement of water vapor absorption

Science.gov (United States)

Keefer, Dennis; Lewis, J. W. L.; Eskridge, Richard

1985-01-01

An investigation was undertaken to measure the absorption coefficient, at a wavelength of 10.6 microns, for mixtures of water vapor and a diluent gas at high temperature and pressure. The experimental concept was to create the desired conditions of temperature and pressure in a laser absorption wave, similar to that which would be created in a laser propulsion system. A simplified numerical model was developed to predict the characteristics of the absorption wave and to estimate the laser intensity threshold for initiation. A non-intrusive method for temperature measurement utilizing optical laser-beam deflection (OLD) and optical spark breakdown produced by an excimer laser, was thoroughly investigated and found suitable for the non-equilibrium conditions expected in the wave. Experiments were performed to verify the temperature measurement technique, to screen possible materials for surface initiation of the laser absorption wave and to attempt to initiate an absorption wave using the 1.5 kW carbon dioxide laser. The OLD technique was proven for air and for argon, but spark breakdown could not be produced in helium. It was not possible to initiate a laser absorption wave in mixtures of water and helium or water and argon using the 1.5 kW laser, a result which was consistent with the model prediction.

Full-length high-temperature severe fuel damage test No. 2

International Nuclear Information System (INIS)

Hesson, G.M.; Lombardo, N.J.; Pilger, J.P.; Rausch, W.N.; King, L.L.; Hurley, D.E.; Parchen, L.J.; Panisko, F.E.

1993-09-01

Hazardous conditions associated with performing the Full-Length High- Temperature (FLHT). Severe Fuel Damage Test No. 2 experiment have been analyzed. Major hazards that could cause harm or damage are (1) radioactive fission products, (2) radiation fields, (3) reactivity changes, (4) hydrogen generation, (5) materials at high temperature, (6) steam explosion, and (7) steam pressure pulse. As a result of this analysis, it is concluded that with proper precautions the FLHT- 2 test can be safely conducted

High temperature performance limit of containment system of transport cask

International Nuclear Information System (INIS)

Kato, Osamu; Saegusa, Toshiari

1998-01-01

The containment performance of a containment system using elastomer gaskets for transport casks under a high temperature and high pressure was clarified. Major results are as follows; (1) The deformation characteristics of the gaskets were represented by the compressive permanent strain rate (Dp). The temperature and time dependence was shown by Larson-Miller Parameter (LMP). (2) Generally, the high temperature performance limit is obtained by a value of LMP when the Dp value reaches 80%. However, the gaskets (FKM, VMQ, EPDM) used for real transport casks were not damaged and the containment performance was not deteriorated as a conservative condition. (3) Assuming that the service period of the gaskets for transport casks is 3 months or 1 year, the high temperature performance limit of the gasket made of fluorine rubber (FKM) is 202degC or 182degC, respectively, which includes safety margin. (author)

Rheological assessment of nanofluids at high pressure high temperature

Science.gov (United States)

Kanjirakat, Anoop; Sadr, Reza

2013-11-01

High pressure high temperature (HPHT) fluids are commonly encountered in industry, for example in cooling and/or lubrications applications. Nanofluids, engineered suspensions of nano-sized particles dispersed in a base fluid, have shown prospective as industrial cooling fluids due to their enhanced rheological and heat transfer properties. Nanofluids can be potentially utilized in oil industry for drilling fluids and for high pressure water jet cooling/lubrication in machining. In present work rheological characteristics of oil based nanofluids are investigated at HPHT condition. Nanofluids used in this study are prepared by dispersing commercially available SiO2 nanoparticles (~20 nm) in a mineral oil. The basefluid and nanofluids with two concentrations, namely 1%, and 2%, by volume, are considered in this investigation. The rheological characteristics of base fluid and the nanofluids are measured using an industrial HPHT viscometer. Viscosity values of the nanofluids are measured at pressures of 100 kPa to 42 MPa and temperatures ranging from 25°C to 140°C. The viscosity values of both nanofluids as well as basefluid are observed to have increased with the increase in pressure. Funded by Qatar National Research Fund (NPRP 08-574-2-239).

Double-layer rotor magnetic shield performance analysis in high temperature superconducting synchronous generators under short circuit fault conditions

Science.gov (United States)

Hekmati, Arsalan; Aliahmadi, Mehdi

2016-12-01

High temperature superconducting, HTS, synchronous machines benefit from a rotor magnetic shield in order to protect superconducting coils against asynchronous magnetic fields. This magnetic shield, however, suffers from exerted Lorentz forces generated in light of induced eddy currents during transient conditions, e.g. stator windings short-circuit fault. In addition, to the exerted electromagnetic forces, eddy current losses and the associated effects on the cryogenic system are the other consequences of shielding HTS coils. This study aims at investigating the Rotor Magnetic Shield, RMS, performance in HTS synchronous generators under stator winding short-circuit fault conditions. The induced eddy currents in different circumferential positions of the rotor magnetic shield along with associated Joule heating losses would be studied using 2-D time-stepping Finite Element Analysis, FEA. The investigation of Lorentz forces exerted on the magnetic shield during transient conditions has also been performed in this paper. The obtained results show that double line-to-ground fault is of the most importance among different types of short-circuit faults. It was revealed that when it comes to the design of the rotor magnetic shields, in addition to the eddy current distribution and the associated ohmic losses, two phase-to-ground fault should be taken into account since the produced electromagnetic forces in the time of fault conditions are more severe during double line-to-ground fault.

Breakup, instabilities, and dynamics of high-speed droplet under transcritical conditions

Directory of Open Access Journals (Sweden)

Yanfei Gao

2015-06-01

Full Text Available A droplet breakup model is developed for a single droplet introduced into transcritical and strong convective environments. The numerical model takes into account variable thermophysical properties, gas solubility in the liquid phase, and vapor–liquid interfacial thermodynamics. The influences of ambient conditions on droplet breakup characteristics are investigated. The results indicate that (1 the drag acceleration decreases slowly at first and then increases drastically with the initial droplet temperature increasing, but always increases at a constant rate with ambient pressure; (2 the pressure and the drop temperature have similar effects on the Kelvin–Helmholtz and Rayleigh–Taylor wave growth at high pressures (reduced pressure higher than 1.2 and high temperatures (reduced temperature higher than 0.7, but the impact of pressure on the wave growth is relatively stronger than that of droplet temperature at relatively low pressures (reduced pressure lower than 0.8 and low temperatures (reduced temperature lower than 0.63; (3 the temperature significantly affects the surface instability growth at high drop temperatures (reduced temperature higher than 0.7, but has no effect on the instability growth at low temperatures (reduced temperature lower than 0.63.

Analysis of influence of heat exchange conditions on the outer surface of the lithium-ion battery to electrolyte temperature under the conditions of high current loads

Directory of Open Access Journals (Sweden)

Krasnoshlykov Alexander

2017-01-01

Full Text Available Numerical analysis of thermal conditions of a lithium-ion battery using the software package ANSYS Electric and ANSYS Fluent has been carried out. Time dependence of the electrolyte temperature on the various heat exchange conditions on the outer surface has been obtained.

High Temperature Epoxy Foam: Optimization of Process Parameters

Directory of Open Access Journals (Sweden)

Samira El Gazzani

2016-06-01

Full Text Available For many years, reduction of fuel consumption has been a major aim in terms of both costs and environmental concerns. One option is to reduce the weight of fuel consumers. For this purpose, the use of a lightweight material based on rigid foams is a relevant choice. This paper deals with a new high temperature epoxy expanded material as substitution of phenolic resin, classified as potentially mutagenic by European directive Reach. The optimization of thermoset foam depends on two major parameters, the reticulation process and the expansion of the foaming agent. Controlling these two phenomena can lead to a fully expanded and cured material. The rheological behavior of epoxy resin is studied and gel time is determined at various temperatures. The expansion of foaming agent is investigated by thermomechanical analysis. Results are correlated and compared with samples foamed in the same temperature conditions. The ideal foaming/gelation temperature is then determined. The second part of this research concerns the optimization of curing cycle of a high temperature trifunctional epoxy resin. A two-step curing cycle was defined by considering the influence of different curing schedules on the glass transition temperature of the material. The final foamed material has a glass transition temperature of 270 °C.

Comparison of Diesel Spray Combustion in Different High-temperature, High-pressure Facilities

DEFF Research Database (Denmark)

Pickett, Lyle M.; Genzale, Caroline L.; Bruneaux, Gilles

2010-01-01

Diesel spray experimentation at controlled high-temperature and high-pressure conditions is intended to provide a more fundamental understanding of diesel combustion than can be achieved in engine experiments. This level of understanding is needed to develop the high-fidelity multi-scale CFD models...... participants in the ECN. Thus, in addition to the presentation of a comparative study, this paper demonstrates steps that are needed for other interested groups to participate in ECN spray research. We expect that this collaborative effort will generate a high-quality dataset to be used for advanced...

Temperature sensitivity of extracellular enzyme kinetics in subtropical wetland soils under different nutrient and water level conditions

Science.gov (United States)

Goswami, S.; Inglett, K.; Inglett, P.

2012-12-01

Microbial extracellular enzymes play an important role in the initial steps of soil organic matter decomposition and are involved in regulating nutrient cycle processes. Moreover, with the recent concern of climate change, microbial extracellular enzymes may affect the functioning (C losses, C sequestration, greenhouse gas emissions, vegetation changes) of different ecosystems. Hence, it is imperative to understand the biogeochemical processes that may be climate change sensitive. Here, we have measured the Michaelis Menten Kinetics [maximal rate of velocity (Vmax) and half-saturation constant (Km)] of 6 enzymes involved in soil organic matter decomposition (phosphatase, phosphodiesterase, β-D-glucosidase, cellobiohydrolase, leucine aminopeptidase, N-Acetyl-β-D glucosaminidase) in different nutrient(P) concentration both aerobically and anaerobically in Everglade water conservation area 2A (F1, F4-slough and U3-slough). Temperature sensitivity of different enzymes is assessed within soil of different P concentrations. We hypothesized that the temperature sensitivity of the enzyme changes with the biogeochemical conditions including water level and nutrient condition. Furthermore, we have tested specific hypothesis that higher P concentration will initiate more C demand for microbes leading to higher Vmax value for carbon processing enzymes in high P site. We found temperature sensitivity of all enzymes for Vmax and Km under both aerobic and anaerobic condition ranges from 0.6 to 3.2 for Vmax and 0.5 to 2.5 for Km. Q10 values of Km for glucosidase indicate more temperature sensitivity under anaerobic condition. Under aerobic condition higher temperature showed significant effect on Vmax for bisphosphatase between high P and low P site. Decreasing P concentration from F1 site to U3-S site had showed significant effect in all temperature on carbon processing enzyme. This suggests that in high P site, microbes will use more carbon-processing enzyme to get more carbon

High temperature oxidation behavior of SiC coating in TRISO coated particles

International Nuclear Information System (INIS)

Liu, Rongzheng; Liu, Bing; Zhang, Kaihong; Liu, Malin; Shao, Youlin; Tang, Chunhe

2014-01-01

Highlights: • High temperature oxidation tests of SiC coating in TRISO particles were carried out. • The dynamic oxidation process was established. • Oxidation mechanisms were proposed. • The existence of silicon oxycarbides at the SiO 2 /SiC interface was demonstrated. • Carbon was detected at the interface at high temperatures and long oxidation time. - Abstract: High temperature oxidation behavior of SiC coatings in tristructural-isotropic (TRISO) coated particles is crucial to the in-pile safety of fuel particles for a high temperature gas cooled reactor (HTGR). The postulated accident condition of air ingress was taken into account in evaluating the reliability of the SiC layer. Oxidation tests of SiC coatings were carried out in the ranges of temperature between 800 and 1600 °C and time between 1 and 48 h in air atmosphere. Based on the microstructure evolution of the oxide layer, the mechanisms and kinetics of the oxidation process were proposed. The existence of silicon oxycarbides (SiO x C y ) at the SiO 2 /SiC interface was demonstrated by X-ray photospectroscopy (XPS) analysis. Carbon was detected by Raman spectroscopy at the interface under conditions of very high temperatures and long oxidation time. From oxidation kinetics calculation, activation energies were 145 kJ/mol and 352 kJ/mol for the temperature ranges of 1200–1500 °C and 1550–1600 °C, respectively

An Evaluation Report on the High Temperature Design of the KALIMER-600 Reactor Structures

Energy Technology Data Exchange (ETDEWEB)

Park, Chang Gyu; Lee, Jae Han

2007-03-15

This report is on the validity evaluation of high temperature structural design for the reactor structures and piping of the pool-type Liquid Metal Reactor, KALIMER-600 subjected to the high temperature thermal load condition. The structural concept of the Upper Internal Structure located above the core is analyzed and the adequate UIS conceptual design for KALIMER-600 is proposed. Also, the high temperature structural integrity of the thermal liner which is to protect the UIS bottom plate from the high frequency thermal fatigue damage was evaluated by the thermal stripping analysis. The high temperature structural design of the reactor internal structure by considering the reactor startup-shutdown cycle was carried out and the structural integrity of it for a normal operating condition as well as the transient condition of the primary pump trip accident was confirmed. Additionally the structure design of the reactor internal structural was changed to prevent the non-uniform deformation of the primary pump which is induced by the thermal expansion difference between the reactor head and the baffle plate. The arrangement of the IHTS piping system which is a part of the reactor system is carried out and the structural integrity and the accumulated deformation by considering the reactor startup-shutdown cycle of a normal operating condition were evaluated. The structural integrity and the accumulated deformation of the PDRC hot leg piping by considering the PDRC operating condition were evaluated. The validity of KALIMER-600 high temperature structural design is confirmed through this study, and it is clearly found that the methodology research to evaluate the structural integrity considering the reactor life time of 60 years ensured is necessary.

Performance of solar collectors under low temperature conditions

DEFF Research Database (Denmark)

Bunea, Mircea; Eicher, Sara; Hildbrand, Catherine

The performance of four solar thermal collectors (flat plate, evacuated tube, unglazed with rear insulation and unglazed without rear insulation) was experimentally measured and simulated for temperatures below ambient. The influence of several parameters (e.g. collector inlet temperature, air...... evaluated and results compared to experimental measurements. A mathematical model is also under development to include, in addition to the condensation phenomena, the frost, the rain and the long-wave radiation gains/losses on the rear of the solar collector. While the potential gain from rain was estimated...... to be around 2%, frost heat gains were measured to be up to 40% per day, under specific conditions. Overall, results have shown that unglazed collectors are more efficient than flat plate or evacuated tube collectors at low operation temperatures or for night conditions, making them more suitable for heat pump...

High field conditioning of cryogenic RF cavities

International Nuclear Information System (INIS)

Cole, M.; Debiak, T.; Lom, C.; Shephard, W.; Sredniawski, J.

1993-01-01

Space-based and other related accelerators have conditioning and operation requirements that are not found in most machines. The use of cryogenic copper, relatively poor vacuum, and limited power storage and operating time put unusual demands on the high-field conditioning process and present some concerns. Two CW cryogenic engineering model open-quotes sparkerclose quotes cavities have been fabricated and tested to fairly high field levels. Tests included initial and repeated conditioning as well as sustained RF operations. The two cavities were an engineering model TDL and an engineering model RFQ. Both cavities operated at 425 MHz. The DTL was conditioned to 46 MV/m at 100% duty factor (CW) at cryogenic temperature. This corresponds to a gap voltage of 433 kV and a real estate accelerating gradient (energy gain/total cavity length) of 6.97 MV/m. The authors believe this to be record performance for cryo CW operation. During cryo pulsed operation, the same cavity reached 48 MV/m with 200 μsec pulses at 0.5% DF. The RFQ was conditioned to 30 MV/m CW at cryo, 85 kV gap voltage. During a brief period of cryo pulsed operation, the RFQ operated at 46 MV/m, or 125 kV gap voltage. Reconditioning experiments were performed on both cavities and no problems were encountered. It should be noted that the vacuum levels were not very stringent during these tests and no special cleanliness or handling procedures were followed. The results of these tests indicate that cavities can run CW without difficulty at cryogenic temperatures at normal conservative field levels. Higher field operation may well be possible, and if better vacuums are used and more attention is paid to cleanliness, much higher fields may be attainable

Thermal sterilization of heat-sensitive products using high-temperature short-time sterilization.

Science.gov (United States)

Mann, A; Kiefer, M; Leuenberger, H

2001-03-01

High-temperature short-time (HTST) sterilization with a continuous-flow sterilizer, developed for this study, was evaluated. The evaluation was performed with respect to (a) the chemical degradation of two heat-sensitive drugs in HTST range (140-160 degrees C) and (b) the microbiological effect of HTST sterilization. Degradation kinetics of two heat-sensitive drugs showed that a high peak temperature sterilization process resulted in less chemical degradation for the same microbiological effect than a low peak temperature process. Both drugs investigated could be sterilized with acceptable degradation at HTST conditions. For the evaluation of the microbiological effect, Bacillus stearothermophilus ATCC 7953 spores were used as indicator bacteria. Indicator spore kinetics (D(T), z value, k, and E(a)), were determined in the HTST range. A comparison between the Bigelow model (z value concept) and the Arrhenius model, used to describe the temperature coefficient of the microbial inactivation, demonstrated that the Bigelow model is more accurate in prediction of D(T) values in the HTST range. The temperature coefficient decreased with increasing temperature. The influence of Ca(2+) ions and pH value on the heat resistance of the indicator spores, which is known under typical sterilization conditions, did not change under HTST conditions.

FEM Modeling of the Relationship between the High-Temperature Hardness and High-Temperature, Quasi-Static Compression Experiment.

Science.gov (United States)

Zhang, Tao; Jiang, Feng; Yan, Lan; Xu, Xipeng

2017-12-26

The high-temperature hardness test has a wide range of applications, but lacks test standards. The purpose of this study is to develop a finite element method (FEM) model of the relationship between the high-temperature hardness and high-temperature, quasi-static compression experiment, which is a mature test technology with test standards. A high-temperature, quasi-static compression test and a high-temperature hardness test were carried out. The relationship between the high-temperature, quasi-static compression test results and the high-temperature hardness test results was built by the development of a high-temperature indentation finite element (FE) simulation. The simulated and experimental results of high-temperature hardness have been compared, verifying the accuracy of the high-temperature indentation FE simulation.The simulated results show that the high temperature hardness basically does not change with the change of load when the pile-up of material during indentation is ignored. The simulated and experimental results show that the decrease in hardness and thermal softening are consistent. The strain and stress of indentation were analyzed from the simulated contour. It was found that the strain increases with the increase of the test temperature, and the stress decreases with the increase of the test temperature.

FEM Modeling of the Relationship between the High-Temperature Hardness and High-Temperature, Quasi-Static Compression Experiment

Directory of Open Access Journals (Sweden)

Tao Zhang

2017-12-01

Full Text Available The high-temperature hardness test has a wide range of applications, but lacks test standards. The purpose of this study is to develop a finite element method (FEM model of the relationship between the high-temperature hardness and high-temperature, quasi-static compression experiment, which is a mature test technology with test standards. A high-temperature, quasi-static compression test and a high-temperature hardness test were carried out. The relationship between the high-temperature, quasi-static compression test results and the high-temperature hardness test results was built by the development of a high-temperature indentation finite element (FE simulation. The simulated and experimental results of high-temperature hardness have been compared, verifying the accuracy of the high-temperature indentation FE simulation.The simulated results show that the high temperature hardness basically does not change with the change of load when the pile-up of material during indentation is ignored. The simulated and experimental results show that the decrease in hardness and thermal softening are consistent. The strain and stress of indentation were analyzed from the simulated contour. It was found that the strain increases with the increase of the test temperature, and the stress decreases with the increase of the test temperature.

Surface Effects and Challenges for Application of Piezoelectric Langasite Substrates in Surface Acoustic Wave Devices Caused by High Temperature Annealing under High Vacuum.

Science.gov (United States)

Seifert, Marietta; Rane, Gayatri K; Kirbus, Benjamin; Menzel, Siegfried B; Gemming, Thomas

2015-12-19

Substrate materials that are high-temperature stable are essential for sensor devices which are applied at high temperatures. Although langasite is suggested as such a material, severe O and Ga diffusion into an O-affine deposited film was observed during annealing at high temperatures under vacuum conditions, leading to a damage of the metallization as well as a change of the properties of the substrate and finally to a failure of the device. Therefore, annealing of bare LGS (La 3 Ga 5 SiO 14 ) substrates at 800 ∘ C under high vacuum conditions is performed to analyze whether this pretreatment improves the suitability and stability of this material for high temperature applications in vacuum. To reveal the influence of the pretreatment on the subsequently deposited metallization, RuAl thin films are used as they are known to oxidize on LGS at high temperatures. A local study of the pretreated and metallized substrates using transmission electron microscopy reveals strong modification of the substrate surface. Micro cracks are visible. The composition of the substrate is strongly altered at those regions. Severe challenges for the application of LGS substrates under high-temperature vacuum conditions arise from these substrate damages, revealing that the pretreatment does not improve the applicability.

Surface Effects and Challenges for Application of Piezoelectric Langasite Substrates in Surface Acoustic Wave Devices Caused by High Temperature Annealing under High Vacuum

Directory of Open Access Journals (Sweden)

Marietta Seifert

2015-12-01

Full Text Available Substrate materials that are high-temperature stable are essential for sensor devices which are applied at high temperatures. Although langasite is suggested as such a material, severe O and Ga diffusion into an O-affine deposited film was observed during annealing at high temperatures under vacuum conditions, leading to a damage of the metallization as well as a change of the properties of the substrate and finally to a failure of the device. Therefore, annealing of bare LGS (La 3 Ga 5 SiO 14 substrates at 800 ∘ C under high vacuum conditions is performed to analyze whether this pretreatment improves the suitability and stability of this material for high temperature applications in vacuum. To reveal the influence of the pretreatment on the subsequently deposited metallization, RuAl thin films are used as they are known to oxidize on LGS at high temperatures. A local study of the pretreated and metallized substrates using transmission electron microscopy reveals strong modification of the substrate surface. Micro cracks are visible. The composition of the substrate is strongly altered at those regions. Severe challenges for the application of LGS substrates under high-temperature vacuum conditions arise from these substrate damages, revealing that the pretreatment does not improve the applicability.

Corrosion behaviour of high temperature alloys in the cooling gas of high temperature reactors

International Nuclear Information System (INIS)

Quadakkers, W.J.; Schuster, H.

1989-01-01

The reactive impurities in the primary cooling helium of advanced high temperature gas cooled reactors (HTGR) can cause oxidation, carburization or decarburization of the heat exchanging metallic components. By studies of the fundamental aspects of the corrosion mechanisms it became possible to define operating conditions under which the metallic construction materials show, from the viewpoint of technical application, acceptable corrosion behaviour. By extensive test programmes with exposure times of up to 30,000 hours, a data base has been obtained which allows a reliable extrapolation of the corrosion effects up to the envisaged service lives of the heat exchanging components. (author). 6 refs, 7 figs

Supersymmetry at high temperatures

International Nuclear Information System (INIS)

Das, A.; Kaku, M.

1978-01-01

We investigate the properties of Green's functions in a spontaneously broken supersymmetric model at high temperatures. We show that, even at high temperatures, we do not get restoration of supersymmetry, at least in the one-loop approximation

Spectral and Concentration Sensitivity of Multijunction Solar Cells at High Temperature: Preprint

Energy Technology Data Exchange (ETDEWEB)

Friedman, Daniel J.; Steiner, Myles A.; Perl, Emmett E.; Simon, John

2017-06-14

We model the performance of two-junction solar cells at very high temperatures of ~400 degrees C and beyond for applications such as hybrid PV/solar-thermal power production, and identify areas in which the design and performance characteristics behave significantly differently than at more conventional near-room-temperature operating conditions. We show that high-temperature operation reduces the sensitivity of the cell efficiency to spectral content, but increases the sensitivity to concentration, both of which have implications for energy yield in terrestrial PV applications. For other high-temperature applications such as near-sun space missions, our findings indicate that concentration may be a useful tool to enhance cell efficiency.

High temperature sensors for exhaust diagnosis

Energy Technology Data Exchange (ETDEWEB)

Svenningstorp, Henrik

2000-07-01

One of the largest problems that we will have to deal with on this planet this millennium is to stop the pollution of our environment. In many of the ongoing works to reduce toxic emissions, gas sensors capable of enduring rough environments and high temperatures, would be a great tool. The different applications where sensors like this would be useful vary between everything from online measurement in the paper industry and food industry to measurement in the exhaust pipe of a car. In my project we have tested Schottky diodes and MlSiCFET sensor as gas sensors operating at high temperatures. The measurement condition in the exhaust pipe of a car is extremely tough, not only is the temperature high and the different gases quite harmful, there are also a lot of particles that can affect the sensors in an undesirable way. In my project we have been testing Schottky diodes and MlSiCFET sensors based on SiC as high temperature sensors, both in the laboratory with simulated exhaust and after a real engine. In this thesis we conclude that these sensors can work in the hostile environment of an engines exhaust. It is shown that when measuring in a gas mixture with a fixed I below one, where the I-value is controlled by the O{sub 2} concentration, a sensor with a catalytic gate metal as sensitive material respond more to the increased O{sub 2} concentration than the increased HC concentration when varying the two correspondingly. A number of different sensors have been tested in simulated exhaust towards NO{sub x}. It was shown that resistivity changes in the thin gate metal influenced the gas response. Tests have been performed where sensors were a part of a SCR system with promising results concerning NH{sub 3} sensitivity. With a working temperature of 300 deg C there is no contamination of the metal surface.

Towards an optimum silicon heterojunction solar cell configuration for high temperature and high light intensity environment

KAUST Repository

Abdallah, Amir

2017-09-22

We report on the performance of Silicon Heterojunction (SHJ) solar cell under high operating temperature and varying irradiance conditions typical to desert environment. In order to define the best solar cell configuration that resist high operating temperature conditions, two different intrinsic passivation layers were tested, namely, an intrinsic amorphous silicon a-SiO:H with CO/SiH ratio of 0.4 and a-SiOx:H with CO/SiH ratio of 0.8, and the obtained performance were compared with those of a standard SHJ cell configuration having a-Si:H passivation layer. Our results showed how the short circuit current density J, and fill factor FF temperature-dependency are impacted by the cell\\'s configuration. While the short circuit current density J for cells with a-SiO:H layers was found to improve as compared with that of standard a-Si:H layer, introducing the intrinsic amorphous silicon oxide (a-SiO:H) layer with CO/SiH ratio of 0.8 has resulted in a reduction of the FF at room temperature due to hindering the carrier transport by the band structure. Besides, this FF was found to improve as the temperature increases from 15 to 45°C, thus, a positive FF temperature coefficient.

Towards an optimum silicon heterojunction solar cell configuration for high temperature and high light intensity environment

KAUST Repository

Abdallah, Amir; Daif, Ounsi El; Aï ssa, Brahim; Kivambe, Maulid; Tabet, Nouar; Seif, Johannes; Haschke, Jan; Cattin, Jean; Boccard, Mathieu; De Wolf, Stefaan; Ballif, Christophe

2017-01-01

We report on the performance of Silicon Heterojunction (SHJ) solar cell under high operating temperature and varying irradiance conditions typical to desert environment. In order to define the best solar cell configuration that resist high operating temperature conditions, two different intrinsic passivation layers were tested, namely, an intrinsic amorphous silicon a-SiO:H with CO/SiH ratio of 0.4 and a-SiOx:H with CO/SiH ratio of 0.8, and the obtained performance were compared with those of a standard SHJ cell configuration having a-Si:H passivation layer. Our results showed how the short circuit current density J, and fill factor FF temperature-dependency are impacted by the cell's configuration. While the short circuit current density J for cells with a-SiO:H layers was found to improve as compared with that of standard a-Si:H layer, introducing the intrinsic amorphous silicon oxide (a-SiO:H) layer with CO/SiH ratio of 0.8 has resulted in a reduction of the FF at room temperature due to hindering the carrier transport by the band structure. Besides, this FF was found to improve as the temperature increases from 15 to 45°C, thus, a positive FF temperature coefficient.

Difference in the Dissolution Behaviors of Tablets Containing Polyvinylpolypyrrolidone (PVPP) Depending on Pharmaceutical Formulation After Storage Under High Temperature and Humid Conditions.

Science.gov (United States)

Takekuma, Yoh; Ishizaka, Haruka; Sumi, Masato; Sato, Yuki; Sugawara, Mitsuru

Storage under high temperature and humid conditions has been reported to decrease the dissolution rate for some kinds of tablets containing polyvinylpolypyrrolidone (PVPP) as a disintegrant. The aim of this study was to elucidate the properties of pharmaceutical formulations with PVPP that cause a decrease in the dissolution rate after storage under high temperature and humid conditions by using model tablets with a simple composition. Model tablets, which consisted of rosuvastatin calcium or 5 simple structure compounds, salicylic acid, 2-aminodiphenylmethane, 2-aminobiphenyl, 2-(p-tolyl)benzoic acid or 4.4'-biphenol as principal agents, cellulose, lactose hydrate, PVPP and magnesium stearate as additives, were made by direct compression. The model tables were wrapped in paraffin papers and stored for 2 weeks at 40°C/75% relative humidity (RH). Dissolution tests were carried out by the paddle method in the Japanese Pharmacopoeia 16th edition. Model tablets with a simple composition were able to reproduce a decreased dissolution rate after storage at 40°C/75% RH. These tablets showed significantly decreased water absorption activities after storage. In the case of tablets without lactose hydrate by replacing with cellulose, a decreased dissolution rate was not observed. Carboxyl and amino groups in the structure of the principal agent were not directly involved in the decreased dissolution. 2-Benzylaniline tablets showed a remarkably decreased dissolution rate and 2-aminobiphenyl and 2-(p-tolyl)benzoic acid tablets showed slightly decreased dissolution rates, though 4,4'-biphenol tablets did not show a decrease dissolution rate. We demonstrated that additives and structure of the principal agent were involved in the decreased in dissolution rate for tablets with PVPP. The results suggested that one of the reasons for a decreased dissolution rate was the inclusion of lactose hydrate in tablets. The results also indicated that compounds as principal agents with low

Six-axis multi-anvil press for high-pressure, high-temperature neutron diffraction experiments

Energy Technology Data Exchange (ETDEWEB)

Sano-Furukawa, A., E-mail: sano.asami@jaea.go.jp; Hattori, T. [Quantum Beam Science Center, Japan Atomic Energy Agency, Ibaraki 319-1195 (Japan); J-PARC Center, Japan Atomic Energy Agency, Ibaraki 319-1195 (Japan); Arima, H. [Institute for Materials Research, Tohoku University, Sendai 980-8577 (Japan); Yamada, A. [The University of Shiga Prefecture, Shiga 522-8533 (Japan); Tabata, S.; Kondo, M.; Nakamura, A. [Sumitomo Heavy Industries Co., Ltd., Ehime 792-0001 (Japan); Kagi, H.; Yagi, T. [Geochemical Research Center, Graduate School of Science, The University of Tokyo, Tokyo 113-0033 (Japan)

2014-11-15

We developed a six-axis multi-anvil press, ATSUHIME, for high-pressure and high-temperature in situ time-of-flight neutron powder diffraction experiments. The press has six orthogonally oriented hydraulic rams that operate individually to compress a cubic sample assembly. Experiments indicate that the press can generate pressures up to 9.3 GPa and temperatures up to 2000 K using a 6-6-type cell assembly, with available sample volume of about 50 mm{sup 3}. Using a 6-8-type cell assembly, the available conditions expand to 16 GPa and 1273 K. Because the six-axis press has no guide blocks, there is sufficient space around the sample to use the aperture for diffraction and place an incident slit, radial collimators, and a neutron imaging camera close to the sample. Combination of the six-axis press and the collimation devices realized high-quality diffraction pattern with no contamination from the heater or the sample container surrounding the sample. This press constitutes a new tool for using neutron diffraction to study the structures of crystals and liquids under high pressures and temperatures.

Ultra-high temperature direct propulsion

International Nuclear Information System (INIS)

Araj, K.J.; Slovik, G.; Powell, J.R.; Ludewig, H.

1987-01-01

Potential advantages of ultra-high exhaust temperature (3000 K - 4000 K) direct propulsion nuclear rockets are explored. Modifications to the Particle Bed Reactor (PBR) to achieve these temperatures are described. Benefits of ultra-high temperature propulsion are discussed for two missions - orbit transfer (ΔV = 5546 m/s) and interplanetary exploration (ΔV = 20000 m/s). For such missions ultra-high temperatures appear to be worth the additional complexity. Thrust levels are reduced substantially for a given power level, due to the higher enthalpy caused by partial disassociation of the hydrogen propellant. Though technically challenging, it appears potentially feasible to achieve such ultra high temperatures using the PBR

Performance testing of elastomeric seal materials under low and high temperature conditions: Final report

Energy Technology Data Exchange (ETDEWEB)

BRONOWSKI,DAVID R.

2000-06-01

The US Department of Energy Offices of Defense Programs and Civilian Radioactive Waste Management jointly sponsored a program to evaluate elastomeric O-ring seal materials for radioactive material shipping containers. The report presents the results of low- and high-temperature tests conducted on 27 common elastomeric compounds.

High throughput measurement of high temperature strength of ceramics in controlled atmosphere and its use on solid oxide fuel cell anode supports

DEFF Research Database (Denmark)

Frandsen, Henrik Lund; Curran, Declan; Rasmussen, Steffen

2014-01-01

In the development of structural and functional ceramics for high temperature electrochemical conversion devices such as solid oxide fuel cells, their mechanical properties must be tested at operational conditions, i.e. at high temperature and controlled atmospheres. Furthermore, characterization...... for testing multiple samples at operational conditions providing a high throughput and thus the possibility achieve high reliability. Optical methods are used to measure deformations contactless, frictionless load measuring is achieved, and multiple samples are handled in one heat up. The methodology...... is validated at room temperature, and exemplified by measurement of the strength of solid oxide fuel cell anode supports at 800 C. © 2014 Elsevier B.V. All rights reserved....

Creep of concrete under various temperature, moisture, and loading conditions

International Nuclear Information System (INIS)

McDonald, J.E.

1976-01-01

An investigation was conducted to obtain information on the time-dependent deformation behavior of concrete in the presence of temperature, moisture, and loading conditions similar to those encountered in a prestressed concrete reactor vessel (PCRV). Variables included concrete strength, aggregate types, curing history, temperature, and types of loading (uniaxial, hydrostatic, biaxial, and triaxial). There were 66 test conditions for creep tests and 12 test conditions for unloaded or control specimens. Experimental results are presented and discussed. Comparisons are made concerning the effect of the various test conditions on the behavior of concrete, and general conclusions are formulated

High Temperature, High Pressure Equation of State: Solidification of Hydrocarbons and Measurement of Krytox Oil Using Rolling-Ball Viscometer Validation

Energy Technology Data Exchange (ETDEWEB)

Gamwo, Isaac K. [National Energy Technology Lab. (NETL), Pittsburgh, PA, (United States); Burgess, Ward [National Energy Technology Lab. (NETL), Pittsburgh, PA, (United States); Tapriyal, Deepak [National Energy Technology Lab. (NETL), Pittsburgh, PA, (United States)

2014-10-03

The global consumption of oil and gas continues to rise and has led to the search and recovery of petroleum sources from reservoirs exhibiting increasingly high-temperature, high-pressure conditions. For example, ultra-deep petroleum formations found at depths of approximately 5 km or more, can exhibit pressure and temperature values as high as 240 MPa (35,000 psi) and 533 K (260°C). The hydrocarbons produced from these ultra-deep formations experience significant decreases in temperature and pressure from reservoir to platform conditions. Hence, it is highly desirable to develop accurate equation of state models (EOS) and fluid properties databases that covers the entire temperature and pressure ranges associated with this process to promote the efficient, safe, and environmentally responsible production from these reservoirs at extreme conditions. Currently available databases and EOS models are generally limited to approximately 69 MPa and do not correlate accurately when extrapolated to the extreme environments associated with ultra-deep reservoirs where temperatures can reach as high as 533 K and pressures up to 240 MPa. Despite recent exploration and production of petroleum from ultra-deep formations, there are major gaps in the databases for pure and mixture density and viscosity of hydrocarbons. These are the most important fluid properties that enable accurate booking of reserves as well as the design of size and equipment to safely bring these fluids to the platform. The overall objective of this project is to develop methodologies to provide crude oil thermodynamic and transport properties—including density, viscosity, and phase composition— at extreme temperature and pressure conditions. The knowledge of these crude oil properties reduces uncertainties associated with deep drilling and promotes safer and reliable access to domestic energy resources. This report is an extension of work reported in our first Technical Report Series (TRS) released

Detonation cell size measurements in high-temperature hydrogen-air-steam mixtures at the BNL high-temperature combustion facility

International Nuclear Information System (INIS)

Ciccarelli, G.; Ginsberg, T.; Boccio, J.L.

1997-11-01

The High-Temperature Combustion Facility (HTCF) was designed and constructed with the objective of studying detonation phenomena in mixtures of hydrogen-air-steam at initially high temperatures. The central element of the HTCF is a 27-cm inner-diameter, 21.3-m long cylindrical test vessel capable of being heating to 700K ± 14K. A unique feature of the HTCF is the 'diaphragmless' acetylene-oxygen gas driver which is used to initiate the detonation in the test gas. Cell size measurements have shown that for any hydrogen-air-steam mixture, increasing the initial mixture temperature, in the range of 300K to 650K, while maintaining the initial pressure of 0.1 MPa, decreases the cell size and thus makes the mixture more detonable. The effect of steam dilution on cell size was tested in stoichiometric and off-stoichiometric (e.g., equivalence ratio of 0.5) hydrogen-air mixtures. Increasing the steam dilution in hydrogen-air mixtures at 0.1 MPa initial pressure increases the cell size, irrespective of initial temperature. It is also observed that the desensitizing effect of steam diminished with increased initial temperature. A 1-dimensional, steady-state Zel'dovich, von Neumann, Doring (ZND) model, with full chemical kinetics, has been used to predict cell size for hydrogen-air-steam mixtures at different initial conditions. Qualitatively the model predicts the overall trends observed in the measured cell size versus mixture composition and initial temperature and pressure. It was found that the proportionality constant used to predict detonation cell size from the calculated ZND model reaction zone varies between 10 and 100 depending on the mixture composition and initial temperature. 32 refs., 35 figs

Performance of iron–chromium–aluminum alloy surface coatings on Zircaloy 2 under high-temperature steam and normal BWR operating conditions

Energy Technology Data Exchange (ETDEWEB)

Zhong, Weicheng; Mouche, Peter A.; Han, Xiaochun [University of Illinois, Department of Nuclear, Radiological, and Plasma Engineering, Urbana, IL 61801 (United States); Heuser, Brent J., E-mail: bheuser@illinois.edu [University of Illinois, Department of Nuclear, Radiological, and Plasma Engineering, Urbana, IL 61801 (United States); Mandapaka, Kiran K.; Was, Gary S. [University of Michigan, Department of Nuclear Engineering and Radiological Sciences, Ann Arbor, MI 48109 (United States)

2016-03-15

Iron-chromium-aluminum (FeCrAl) coatings deposited on Zircaloy 2 (Zy2) and yttria-stabilized zirconia (YSZ) by magnetron sputtering have been tested with respect to oxidation weight gain in high-temperature steam. In addition, autoclave testing of FeCrAl-coated Zy2 coupons under pressure-temperature-dissolved oxygen coolant conditions representative of a boiling water reactor (BWR) environment has been performed. Four different FeCrAl compositions have been tested in 700 °C steam; compositions that promote alumina formation inhibited oxidation of the underlying Zy2. Parabolic growth kinetics of alumina on FeCrAl-coated Zy2 is quantified via elemental depth profiling. Autoclave testing under normal BWR operating conditions (288 °C, 9.5 MPa with normal water chemistry) up to 20 days demonstrates observable weight gain over uncoated Zy2 simultaneously exposed to the same environment. However, no FeCrAl film degradation was observed. The 900 °C eutectic in binary Fe–Zr is addressed with the FeCrAl-YSZ system. - Graphical abstract: Weight gain normalized to total sample surface area versus time during 700 °C steam exposure for FeCrAl samples with different composition (A) and Fe/Cr/Al:62/4/34 (B). In both cases, the responses of uncoated Zry2 (Zry2-13A and Zry2-19A) are shown for comparison. This uncoated Zry2 response shows the expected pre-transition quasi-cubic kinetic behavior and eventual breakaway (linear) kinetics. Highlights: • FeCrAl coatings deposited on Zy2 have been tested with respect to oxidation in high-temperature steam. • FeCrAl compositions promoting alumina formation inhibited oxidation of Zy2 and delay weight gain. • Autoclave testing to 20 days of coated Zy2 in a simulated BWR environment demonstrates minimal weight gain and no film degradation. • The 900 °C eutectic in binary Fe-Zr is addressed with the FeCrAl-YSZ system.

Physical properties of concrete under 3-years exposure to high temperatures up to 110degC

International Nuclear Information System (INIS)

Nishiuchi, T.; Kanazu, T.; Ishida, H.

1990-01-01

Concrete structural members in a storehouse of high level radioactive wastes are designed assuming that they may be subjected to elevated temperature for a long term. So, in this study, concrete properties under temperature conditions (between 65degC-temperature limitation specified in design and 110degC-vaporing temperature of gel water in concrete) and possibility of raising this temperature limitation has been investigated from the view point of long term concrete properties. In this experiment, many properties of concrete were examined, such as compressive strength, tensile strength. Young's modulus, weight loss, pore size distribution under combined conditions (temperature conditions, mix proportions of concrete, moisture conditions). Followings are the main conclusions obtained within the limit of the experiment. 1. Compressive strength of concrete becomes smaller according as temperature becomes high, but there is little difference between the compressive strength at 65degC and 85degC. 2. Young's modulus of concrete decreases linearly according as temperature becomes higher. 3. Weight loss of concrete increases according as temperature becomes higher. 4. Judging from the decreasing rate of physical properties of concrete, it seems possible to raise temperature limitation from 65degC to 85degC. (author)

High-temperature electronic structure with the Korringa-Kohn-Rostoker Green's function method

Science.gov (United States)

Starrett, C. E.

2018-05-01

Modeling high-temperature (tens or hundreds of eV), dense plasmas is challenging due to the multitude of non-negligible physical effects including significant partial ionization and multisite effects. These effects cause the breakdown or intractability of common methods and approximations used at low temperatures, such as pseudopotentials or plane-wave basis sets. Here we explore the Korringa-Kohn-Rostoker Green's function method at these high-temperature conditions. The method is all electron, does not rely on pseudopotentials, and uses a spherical harmonic basis set, and so avoids the aforementioned limitations. It is found to be accurate for solid density aluminum and iron plasmas when compared to a plane-wave method at low temperature, while being able to access high temperatures.

Experimental on moisture migration and pore pressure formation of concrete members subjected to high temperature

International Nuclear Information System (INIS)

Nagao, Kakuhiro; Nakane, Sunao

1993-01-01

The experimental studies concerning temperature, moisture migration, and pore pressure of mass concrete mock-up specimens heated up to high temperature at 110degC to 600degC, were performed, so as to correctly estimate the moisture migration behaviour of concrete members subjected to high temperature, which is considered significantly influenced on physical properties of concrete. As a results, it is confirmed that the moisture migration behavior of concrete members can be explained by temperature and pore pressure, and indicate the characteristics both sealed condition (dissipation of moisture is prevented) and unsealed condition (dissipation of moisture occur). (author)

An extended laser flash technique for thermal diffusivity measurement of high-temperature materials

Science.gov (United States)

Shen, F.; Khodadadi, J. M.

1993-01-01

Knowledge of thermal diffusivity data for high-temperature materials (solids and liquids) is very important in analyzing a number of processes, among them solidification, crystal growth, and welding. However, reliable thermal diffusivity versus temperature data, particularly those for high-temperature liquids, are still far from complete. The main measurement difficulties are due to the presence of convection and the requirement for a container. Fortunately, the availability of levitation techniques has made it possible to solve the containment problem. Based on the feasibility of the levitation technology, a new laser flash technique which is applicable to both levitated liquid and solid samples is being developed. At this point, the analysis for solid samples is near completion and highlights of the technique are presented here. The levitated solid sample which is assumed to be a sphere is subjected to a very short burst of high power radiant energy. The temperature of the irradiated surface area is elevated and a transient heat transfer process takes place within the sample. This containerless process is a two-dimensional unsteady heat conduction problem. Due to the nonlinearity of the radiative plus convective boundary condition, an analytic solution cannot be obtained. Two options are available at this point. Firstly, the radiation boundary condition can be linearized, which then accommodates a closed-form analytic solution. Comparison of the analytic curves for the temperature rise at different points to the experimentally-measured values will then provide the thermal diffusivity values. Secondly, one may set up an inverse conduction problem whereby experimentally obtained surface temperature history is used as the boundary conditions. The thermal diffusivity can then be elevated by minimizing the difference between the real heat flux boundary condition (radiation plus convection) and the measurements. Status of an experimental study directed at measuring the

High temperature structural silicides

International Nuclear Information System (INIS)

Petrovic, J.J.

1997-01-01

Structural silicides have important high temperature applications in oxidizing and aggressive environments. Most prominent are MoSi 2 -based materials, which are borderline ceramic-intermetallic compounds. MoSi 2 single crystals exhibit macroscopic compressive ductility at temperatures below room temperature in some orientations. Polycrystalline MoSi 2 possesses elevated temperature creep behavior which is highly sensitive to grain size. MoSi 2 -Si 3 N 4 composites show an important combination of oxidation resistance, creep resistance, and low temperature fracture toughness. Current potential applications of MoSi 2 -based materials include furnace heating elements, molten metal lances, industrial gas burners, aerospace turbine engine components, diesel engine glow plugs, and materials for glass processing

High temperature resistive phase transition in A15 high temperature superconductors

International Nuclear Information System (INIS)

Chu, C.W.; Huang, C.Y.; Schmidt, P.H.; Sugawara, K.

1976-01-01

Resistive measurements were made on A15 high temperature superconductors. Anomalies indicative of a phase transition were observed at 433 0 K in a single crystal Nb 3 Sn and at 485 0 K in an unbacked Nb 3 Ge sputtered thin film. Results are compared with the high temperature transmission electron diffraction studies of Nb 3 Ge films by Schmidt et al. A possible instability in the electron energy spectrum is discussed

Research on suitable heating conditions during local PWHT. Pt. 1. Influence of heating conditions on temperature distribution

International Nuclear Information System (INIS)

Tanaka, Jinkichi; Horii, Yukihiko; Sato, Masanobu; Murakawa, Hidekazu; Wang Jianhua

1999-01-01

To improve weld joint properties a heat treatment so called post weld heat treatment (PWHT) is often implemented for steel weldment. Generally, the PWHT is conducted in a furnace at a factory. But in site welds such as the girth joint of pipe, a local PWHT is applied using electric heater and so on. In the local PWHT steep temperature gradient occurs depending on the heating condition and it leads to rise of the thermal stress in addition to the welding residual stress. However, heating condition is not always defined the same in some standards. Therefore, suitable heat conditions for the local PWHT were studied supposing the power plant and so on experimentally and theoretically. Temperature distribution and thermal strains under different heating conditions were measured during the local PWHT using carbon steel pipes of 340 mm in diameter and 53 mm in wall thickness. The temperature gradient, thermal strain were also analyzed using Finite Element Method (FEM) as axis-symmetric model. Further, the influences of pipe size and heat transfer coefficient on the temperature distribution were analyzed and suitable heating source widths for various pipe sizes were proposed from the viewpoint of temperature distribution. (orig.)

Basic thermo-fluid dynamic problems in high temperature heat exchangers

International Nuclear Information System (INIS)

McEligot, D.M.

1986-01-01

The authors consider high temperature heat exchangers to be ones where the heat transfer coefficients cannot be predicted confidently by classical analyses for pure forced convection with constant fluid properties. Alternatively, one could consider heat exchangers operating above some arbitrary temperature, say 1000F or 600C perhaps, to be at high temperature conditions. In that case, most common working fluids will be superheated vapors or gases. While some liquid metal heat exchangers are designed to operate in this range, the heat transfer coefficients of liquid metals are usually sufficiently high that the dominant thermal resistance would be due to the second fluid. This paper concentrates on convective heat transfer with gases. Typical applications include modular gas cooled nuclear reactors, proposed nuclear propulsion systems and space power plants, and superheaters in Rankine steam cycles

Experimental facility for development of high-temperature reactor technology: instrumentation needs and challenges

Directory of Open Access Journals (Sweden)

Sabharwall Piyush

2015-01-01

Full Text Available A high-temperature, multi-fluid, multi-loop test facility is under development at the Idaho National Laboratory for support of thermal hydraulic materials, and system integration research for high-temperature reactors. The experimental facility includes a high-temperature helium loop, a liquid salt loop, and a hot water/steam loop. The three loops will be thermally coupled through an intermediate heat exchanger (IHX and a secondary heat exchanger (SHX. Research topics to be addressed include the characterization and performance evaluation of candidate compact heat exchangers such as printed circuit heat exchangers (PCHEs at prototypical operating conditions. Each loop will also include an interchangeable high-temperature test section that can be customized to address specific research issues associated with each working fluid. This paper also discusses needs and challenges associated with advanced instrumentation for the multi-loop facility, which could be further applied to advanced high-temperature reactors. Based on its relevance to advanced reactor systems, the new facility has been named the Advanced Reactor Technology Integral System Test (ARTIST facility. A preliminary design configuration of the ARTIST facility will be presented with the required design and operating characteristics of the various components. The initial configuration will include a high-temperature (750 °C, high-pressure (7 MPa helium loop thermally integrated with a molten fluoride salt (KF-ZrF4 flow loop operating at low pressure (0.2 MPa, at a temperature of ∼450 °C. The salt loop will be thermally integrated with the steam/water loop operating at PWR conditions. Experiment design challenges include identifying suitable materials and components that will withstand the required loop operating conditions. The instrumentation needs to be highly accurate (negligible drift in measuring operational data for extended periods of times, as data collected will be

Assessing the High Temperature, High Pressure Subsurface for Anaerobic Methane Oxidation

Science.gov (United States)

Harris, R. L.; Bartlett, D.; Byrnes, A. W.; Walsh, K. M.; Lau, C. Y. M.; Onstott, T. C.

2017-12-01

The anaerobic oxidation of methane (AOM) is an important sink in the global methane (CH4) budget. ANMEs are known to oxidize CH4 either independently or in consortia with bacteria, coupling the reduction of electron acceptors such as, SO42-, NO2-, NO3-, Mn4+, or Fe3+. To further constrain the contribution of AOM to the global CH4 budget, it is important to assess unexplored environments where AOM is thermodynamically possible such as the high pressure, high temperature deep biosphere. Provided plausible electron acceptor availability, increased temperature and pCH4 yield favorable Gibbs free energies for AOM reactions and the production of ATP (Fig. 1). To date, only sulfate-dependent AOM metabolism has been documented under high temperature conditions (50-72˚C), and AOM has not been assessed above 10.1 MPa. Given that ANMEs share close phylogenetic and metabolic heritage with methanogens and that the most heat-tolerant microorganism known is a barophilic methanogen, there possibly exist thermophilic ANMEs. Here we describe preliminary results from high pressure, high temperature stable isotope tracer incubation experiments on deep biosphere samples. Deep sub-seafloor sediments collected by IODP 370 from the Nankai Trough (257 - 865 m below seafloor) and deep fracture fluid from South Africa (1339 m below land surface) were incubated anaerobically in hydrostatic pressure vessels at 40 MPa in simulated in situ temperatures (40˚ - 80˚C). Sediments and fracture fluid were incubated in sulfate-free artificial seawater, a 2:98 13CH4:N2 headspace, and treated with one of the potential electron acceptors listed above in addition to kill and endogenous activity (i.e. no added electron acceptor) controls. Stable isotope analysis of dissolved inorganic carbon (DIC) suggests that AOM occurred within 60 days of incubation for all investigated electron acceptors and temperatures except 50˚C. Sulfate-dependent AOM rates are consistent with those previously reported in the

Design and Fabrication Technique of the Key Components for Very High Temperature Reactor

Energy Technology Data Exchange (ETDEWEB)

Lee, Ho Jin; Song, Ki Nam; Kim, Yong Wan

2006-12-15

The gas outlet temperature of Very High Temperature Reactor (VHTR) may be beyond the capability of conventional metallic materials. The requirement of the gas outlet temperature of 950 .deg. C will result in operating temperatures for metallic core components that will approach very high temperature on some cases. The materials that are capable of withstanding this temperature should be prepared, or nonmetallic materials will be required for limited components. The Ni-base alloys such as Alloy 617, Hastelloy X, XR, Incoloy 800H, and Haynes 230 are being investigated to apply them on components operated in high temperature. Currently available national and international codes and procedures are needed reviewed to design the components for HTGR/VHTR. Seven codes and procedures, including five ASME Codes and Code cases, one French code (RCC-MR), and on British Procedure (R5) were reviewed. The scope of the code and code cases needs to be expanded to include the materials with allowable temperatures of 950 .deg. C and higher. The selection of compact heat exchangers technology depends on the operating conditions such as pressure, flow rates, temperature, but also on other parameters such as fouling, corrosion, compactness, weight, maintenance and reliability. Welding, brazing, and diffusion bonding are considered proper joining processes for the heat exchanger operating in the high temperature and high pressure conditions without leakage. Because VHTRs require high temperature operations, various controlled materials, thick vessels, dissimilar metal joints, and precise controls of microstructure in weldment, the more advanced joining processes are needed than PWRs. The improved solid joining techniques are considered for the IHX fabrication. The weldability for Alloy 617 and Haynes 230 using GTAW and SMAW processes was investigated by CEA.

Design and Fabrication Technique of the Key Components for Very High Temperature Reactor

International Nuclear Information System (INIS)

Lee, Ho Jin; Song, Ki Nam; Kim, Yong Wan

2006-12-01

The gas outlet temperature of Very High Temperature Reactor (VHTR) may be beyond the capability of conventional metallic materials. The requirement of the gas outlet temperature of 950 .deg. C will result in operating temperatures for metallic core components that will approach very high temperature on some cases. The materials that are capable of withstanding this temperature should be prepared, or nonmetallic materials will be required for limited components. The Ni-base alloys such as Alloy 617, Hastelloy X, XR, Incoloy 800H, and Haynes 230 are being investigated to apply them on components operated in high temperature. Currently available national and international codes and procedures are needed reviewed to design the components for HTGR/VHTR. Seven codes and procedures, including five ASME Codes and Code cases, one French code (RCC-MR), and on British Procedure (R5) were reviewed. The scope of the code and code cases needs to be expanded to include the materials with allowable temperatures of 950 .deg. C and higher. The selection of compact heat exchangers technology depends on the operating conditions such as pressure, flow rates, temperature, but also on other parameters such as fouling, corrosion, compactness, weight, maintenance and reliability. Welding, brazing, and diffusion bonding are considered proper joining processes for the heat exchanger operating in the high temperature and high pressure conditions without leakage. Because VHTRs require high temperature operations, various controlled materials, thick vessels, dissimilar metal joints, and precise controls of microstructure in weldment, the more advanced joining processes are needed than PWRs. The improved solid joining techniques are considered for the IHX fabrication. The weldability for Alloy 617 and Haynes 230 using GTAW and SMAW processes was investigated by CEA

Glass precursor approach to high-temperature superconductors

Science.gov (United States)

Bansal, Narottam P.

1992-01-01

The available studies on the synthesis of high T sub c superconductors (HTS) via the glass precursor approach were reviewed. Melts of the Bi-Sr-Ca-Cu-O system as well as those doped with oxides of some other elements (Pb, Al, V, Te, Nb, etc.) could be quenched into glasses which, on further heat treatments under appropriate conditions, crystallized into the superconducting phase(s). The nature of the HTS phase(s) formed depends on the annealing temperature, time, atmosphere, and the cooling rate and also on the glass composition. Long term annealing was needed to obtain a large fraction of the 110 K phase. The high T sub c phase did not crystallize out directly from the glass matrix, but was preceded by the precipitation of other phases. The 110 K HTS was produced at high temperatures by reaction between the phases formed at lower temperatures resulting in multiphase material. The presence of a glass former such as B2O3 was necessary for the Y-Ba-Cu-O melt to form a glass on fast cooling. A discontinuous YBa2Cu3O(7-delta) HTS phase crystallized out on heat treatment of this glass. Attempts to prepare Tl-Ba-Ca-Cu-O system in the glassy state were not successful.

Performance evaluation of a piezoactuator-based single-stage valve system subjected to high temperature

Science.gov (United States)

Jeon, Juncheol; Han, Chulhee; Chung, Jye Ung; Choi, Seung-Bok

2015-01-01

In this paper, a novel single-stage valve system activated by a piezostack actuator is proposed and experimentally evaluated at both room temperature (20 °C) and high temperature (100 °C) conditions. A hinge-lever displacement amplifier is adopted in the valve system to magnify the displacement generated from the piezostack actuator. After explaining the operating principle of the proposed piezostack-driven single-stage valve system, the geometric dimensions and mechanical properties of the valve components are discussed in details. An experimental apparatus is then manufactured to evaluate the performances of the valve system such as flow rate. The experimental apparatus consists of a heat chamber, which can regulate the temperature of the valve system and oil, pneumatic-hydraulic cylinders, a hydraulic circuit, a pneumatic circuit, electronic devices, an interface card, and a high voltage amplifier. The pneumatic-hydraulic cylinder transforms the pneumatic pressure into hydraulic pressure. The performances of the valve system regarding spool response, pressure drop, and flow rate are evaluated and presented. In addition, the performance of the valve system under high temperature condition is compared with that under room temperature condition. The experimental results are plotted in both frequency and time domains.

Performance evaluation of a piezoactuator-based single-stage valve system subjected to high temperature

International Nuclear Information System (INIS)

Jeon, Juncheol; Han, Chulhee; Ung Chung, Jye; Choi, Seung-Bok

2015-01-01

In this paper, a novel single-stage valve system activated by a piezostack actuator is proposed and experimentally evaluated at both room temperature (20 °C) and high temperature (100 °C) conditions. A hinge-lever displacement amplifier is adopted in the valve system to magnify the displacement generated from the piezostack actuator. After explaining the operating principle of the proposed piezostack-driven single-stage valve system, the geometric dimensions and mechanical properties of the valve components are discussed in details. An experimental apparatus is then manufactured to evaluate the performances of the valve system such as flow rate. The experimental apparatus consists of a heat chamber, which can regulate the temperature of the valve system and oil, pneumatic-hydraulic cylinders, a hydraulic circuit, a pneumatic circuit, electronic devices, an interface card, and a high voltage amplifier. The pneumatic-hydraulic cylinder transforms the pneumatic pressure into hydraulic pressure. The performances of the valve system regarding spool response, pressure drop, and flow rate are evaluated and presented. In addition, the performance of the valve system under high temperature condition is compared with that under room temperature condition. The experimental results are plotted in both frequency and time domains. (paper)

Growth and Development Temperature Influences Level of Tolerance to High Light Stress 1

Science.gov (United States)

Steffen, Kenneth L.; Palta, Jiwan P.

1989-01-01

The influence of growth and development temperature on the relative tolerance of photosynthetic tissue to high light stress at chilling temperatures was investigated. Two tuber-bearing potato species, Solanum tuberosum L. cv Red Pontiac and Solanum commersonii were grown for 4 weeks, at either 12 or 24°C with 12 hours of about 375 micromoles per second per square meter of photosynthetically active radiation. Paired leaf discs were cut from directly across the midvein of leaflets of comparable developmental stage and light environment from each species at each growth temperature treatment. One disc of each pair was exposed to 1°C and about 1000 micromoles per second per square meter photosynthetically active radiation for 4 hours, and the other disc was held at 1°C in total darkness for the same duration. Photosynthetic tissue of S. tuberosum, developed at 12°C, was much more tolerant to high light and low temperature stress than tissue developed under 24°C conditions. Following the high light treatment, 24°C-grown S. tuberosum tissue demonstrated light-limited and light-saturated rates that were approximately 50% of their paired dark controls. In contrast, the 12°C-grown tissue from S. tuberosum that was subjected to the light stress showed only a 18 and 6% reduction in light-limited and light-saturated rates of photosynthetic oxygen evolution, respectively. Tissue from 24°C-grown S. commersonii was much less sensitive to the light stress than was tissue from S. tuberosum grown under the same conditions. The results presented here demonstrate that: (a) acclimation of S. tuberosum to lower temperature growth conditions with a constant light environment, results in the increased capacity of photosynthetic tissue to tolerate high light stress at chilling temperature and (b) following growth and development at relatively high temperatures S. commersonii, a frost- and heat-tolerant wild species, has a much greater tolerance to the high light stress at chilling

High-pressure high-temperature experiments: Windows to the Universe; Experimentos a alta presion y alta temperatura: Ventanas al universo

Energy Technology Data Exchange (ETDEWEB)

Santaria-Perez, D.

2011-07-01

From Earth compositional arguments suggested by indirect methods, such as the propagation of seismic waves, is possible to generate in the laboratory pressure and temperature conditions similar to those of the Earth or other planet interiors and to study how these conditions affect to a certain metal or mineral. These experiments are, therefore, windows to the Universe. The aim of this chapter is to illustrate the huge power of the experimental high-pressure high-temperature techniques and give a global overview of their application to different geophysical fields. Finally, we will introduce the MALTA Consolider Team, which gather most of the Spanish high-pressure community, and present their available high-pressure facilities. (Author) 28 refs.

Dissolution of nonmetallic inclusions at high-temperature heating

International Nuclear Information System (INIS)

Gubenko, S.I.

1983-01-01

The effect of high-temperature a nnealing on size, distribution and general content of non-metallic inclusions in steels is investigated. It is shown that high-temperature annealing of steel permits to reduce total amount of inclusions, their average size, as well as to control their composition and distribution in steel matrix. Partial or complete dissolution of inclusions takes place in respect to the type of non-metallic inclusions, temperature of annealing and holding duration. Cooling rate affects the investigated parameters. Under quenching the total amount of inclusions in steel is lower and average size of inclusions is larger than those under slow cooling. It is explained by precipitation of disperses ''satellites around the initial inclusions under low cooling. Composition of the satellites slightly differs from that of a ''mother's'' one. Change in composition of inclusions and creation of conditions for transition of unstable inclusions to a more stable state promotes change in properties of non-metallic inclusions that affects steel properties

Experimental facility for development of high-temperature reactor technology: instrumentation needs and challenges - 15066

International Nuclear Information System (INIS)

Sabharwall, P.; O'Brien, J.E.; Yoon, S.J.; Sun, X.

2015-01-01

A high-temperature, multi-fluid, multi-loop test facility is under development at the Idaho National Laboratory for support of thermal hydraulic, materials, and system integration research for high-temperature reactors. The experimental facility includes a high-temperature helium loop, a liquid salt loop, and a hot water/steam loop. The 3 loops will be thermally coupled through an intermediate heat exchanger (IHX) and a secondary heat exchanger (SHX). Research topics to be addressed include the characterization and performance evaluation of candidate compact heat exchangers such as printed circuits heat exchangers (PCHEs) at prototypical operating conditions. Each loop will also include an interchangeable high-temperature test section that can be customized to address specific research issues associated with each working fluid. This paper also discusses needs and challenges associated with advanced instrumentation for the multi-loop facility, which could be further applied to advanced high-temperature reactors. Based on its relevance to advanced reactor systems, the new facility has been named the Advanced Reactor Technology Integrated System Test (ARTIST) facility. A preliminary design configuration of the ARTIST facility will be presented with the required design and operating characteristics of the various components. The initial configuration will include a high-temperature (750 C. degrees), high-pressure (7 MPa) helium loop thermally integrated with a molten fluoride salt (KF-ZrF 4 ) flow loop operating at low pressure (0.2 MPa), at a temperature of ∼ 450 C. degrees. The salt loop will be thermally integrated with the steam/water loop operating at PWR conditions. Experiment design challenges include identifying suitable materials and components that will withstand the required loop operating conditions. The instrumentation needs to be highly accurate (negligible drift) in measuring operational data for extended periods of times, as data collected will be

High-entropy alloys as high-temperature thermoelectric materials

Energy Technology Data Exchange (ETDEWEB)

Shafeie, Samrand [Surface and Microstructure Engineering Group, Materials and Manufacturing Technology, Chalmers University of Technology, SE-41296 Gothenburg (Sweden); Department of Chemistry and Chemical Engineering, Chalmers University of Technology, SE-41296 Gothenburg (Sweden); Guo, Sheng, E-mail: sheng.guo@chalmers.se [Surface and Microstructure Engineering Group, Materials and Manufacturing Technology, Chalmers University of Technology, SE-41296 Gothenburg (Sweden); Hu, Qiang [Institute of Applied Physics, Jiangxi Academy of Sciences, Nanchang 330029 (China); Fahlquist, Henrik [Bruker AXS Nordic AB, 17067 Solna (Sweden); Erhart, Paul [Department of Applied Physics, Chalmers University of Technology, SE-41296 Gothenburg (Sweden); Palmqvist, Anders, E-mail: anders.palmqvist@chalmers.se [Department of Chemistry and Chemical Engineering, Chalmers University of Technology, SE-41296 Gothenburg (Sweden)

2015-11-14

Thermoelectric (TE) generators that efficiently recycle a large portion of waste heat will be an important complementary energy technology in the future. While many efficient TE materials exist in the lower temperature region, few are efficient at high temperatures. Here, we present the high temperature properties of high-entropy alloys (HEAs), as a potential new class of high temperature TE materials. We show that their TE properties can be controlled significantly by changing the valence electron concentration (VEC) of the system with appropriate substitutional elements. Both the electrical and thermal transport properties in this system were found to decrease with a lower VEC number. Overall, the large microstructural complexity and lower average VEC in these types of alloys can potentially be used to lower both the total and the lattice thermal conductivity. These findings highlight the possibility to exploit HEAs as a new class of future high temperature TE materials.

The procedure for determining the residual life of high-temperature aggregates

Science.gov (United States)

Nikiforov, A. S.; Prihodko, E. V.; Kinzhibekova, A. K.; Karmanov, A. E.

2018-01-01

One of the main reasons for the withdrawal of high-temperature aggregates for repairs is the destruction of enclosing structures due to the occurrence of temperature stresses. A wide range of refractory materials used, a large number of product names, a difference in the operation of even the same aggregates makes it impossible to apply general principles for determining the residual resource of high-temperature aggregates, which is based, as a rule, on the determination of temperature stresses. In the article there is suggested a technique based on the method of simulation modeling, allowing to estimate the remaining resource and reliability of the operating equipment. There are given data on the calculation of these indicators for a 25-ton steel-casting ladle. The values obtained make it possible to evaluate the rationality of the further operation of the high-temperature unit by the condition of reliability of the enclosing structures.

High temperature tensile properties and deep drawing of fully green composites

Directory of Open Access Journals (Sweden)

2009-01-01

Full Text Available In recent years, research and development of materials using biomass sources are much expected to construct a sustainable society. The so-called green composite consisting of natural fibers and biodegradable resin, is one of the most promising materials in developing biomass products. In this study, especially, we focus on the tensile deformation behavior of the green composites reinforced with ramie woven fabrics at high temperature. The results show that the fracture strain at high temperatures increases larger than that of room temperature, and initial deformation resistance of the composites seen at room temperature does not appear at high temperatures. Thus, several conditions to cause more deformability of the green composites were found. Finally, in order to utilize such deformability, Lankford-values of the green composites were clarified, and deep drawing was carried out for sheet materials made of the green composites.

Development of an inspection robot under iter relevant vacuum and temperature conditions

Energy Technology Data Exchange (ETDEWEB)

Hatchressian, J-C; Bruno, V; Gargiulo, L; Bayetti, P; Cordier, J-J; Samaille, F [Association Euratom-CEA, DSM/Departement de Recherche sur la Fusion Controlee, CEA Cadarache, F-13108 Saint Paul-Lez-Durance Cedex (France); Keller, D; Perrot, Y; Friconneau, J-P [CEA, LIST, Service de Robotique Interactive, 18 route du Panorama, BP6, Fontenay aux Roses F-92265 France (France); Palmer, J D [EFDA-CSU Max-Planck-Institut fuer Plasma Physik Boltzmannstr.2, D-85748 Garching Germany (Germany)

2008-03-15

Robotic operations are one of the major maintenance challenges for ITER and future fusion reactors. In vessel inspection operations without loss of conditioning could be very mandatory. Within this framework, the aim of the Articulated Inspection Arm (AIA) project is to demonstrate the feasibility of a multi-purpose in-vessel Remote Handling inspection system. It is a long reach, composed of 5 segments with in all 8 degrees of freedom, limited payload carrier (up to 10kg) and a total range of 8m. The project is currently developed by the CEA within the European work program. Some tests will validate chosen concepts for operations under ITER relevant vacuum and temperature conditions. The presence of magnetic fields, radiation and neutron beams will not be considered. This paper deals with the choices of the materials to minimize the out-gassing under vacuum and high temperature during conditioning, the implantation of the electronics which are enclosed in boxes with special gaskets, the design of the first embedded process which is a viewing system.

High-temperature protective coatings for C/SiC composites

OpenAIRE

Xiang Yang; Chen Zhao-hui; Cao Feng

2014-01-01

Carbon fiber-reinforced silicon carbide (C/SiC) composites were well-established light weight materials combining high specific strength and damage tolerance. For high-temperature applications, protective coatings had to provide oxidation and corrosion resistance. The literature data introduced various technologies and materials, which were suitable for the application of coatings. Coating procedures and conditions, materials design limitations related to the reactivity of the components of C...

High temperature vapors science and technology

CERN Document Server

Hastie, John

2012-01-01

High Temperature Vapors: Science and Technology focuses on the relationship of the basic science of high-temperature vapors to some areas of discernible practical importance in modern science and technology. The major high-temperature problem areas selected for discussion include chemical vapor transport and deposition; the vapor phase aspects of corrosion, combustion, and energy systems; and extraterrestrial high-temperature species. This book is comprised of seven chapters and begins with an introduction to the nature of the high-temperature vapor state, the scope and literature of high-temp

UO2 - Zr chemical interaction of PHWR fuel pins under high temperature

International Nuclear Information System (INIS)

Majumdar, P.; Mukhopadhyay, D.; Gupta, S.K.

2001-01-01

At high temperature Zircaloy clad interacts with the UO 2 fuel as well as with the steam to produce oxide layer of a-Zr(O) and ZrO 2 . This layer formation significantly reduces the structural strength of the clad. A computer code SFDCPA/MOD1 has been developed to simulate the interaction and predict the oxide layer thickness for any accidental transient condition. It is well validated with published experimental data on the isothermal and transient temperature condition. The program is applied to Indian Pressurized Heavy Water Reactor (PHWR) fuel pin under certain severe transient condition where it experiences temperature above 1000 C. The study gives an idea of the un-oxidized thickness of Zircaloy, which is an important criterion for fuel integrity. (author)

Study on the effect of subcooling on vapor film collapse on high temperature particle surface

International Nuclear Information System (INIS)

Abe, Yutaka; Tochio, Daisuke; Yanagida, Hiroshi

2000-01-01

Thermal detonation model is proposed to describe vapor explosion. According to this model, vapor film on pre-mixed high temperature droplet surface is needed to be collapsed for the trigger of the vapor explosion. It is pointed out that the vapor film collapse behavior is significantly affected by the subcooling of low temperature liquid. However, the effect of subcooling on micro-mechanism of vapor film collapse behavior is not experimentally well identified. The objective of the present research is to experimentally investigate the effect of subcooling on micro-mechanism of film boiling collapse behavior. As the results, it is experimentally clarified that the vapor film collapse behavior in low subcooling condition is qualitatively different from the vapor film collapse behavior in high subcooling condition. In case of vapor film collapse by pressure pulse, homogeneous vapor generation occurred all over the surface of steel particle in low subcooling condition. On the other hand, heterogeneous vapor generation was observed for higher subcooling condition. In case of vapor film collapse spontaneously, fluctuation of the gas-liquid interface after quenching propagated from bottom to top of the steel particle heterogeneously in low subcooling condition. On the other hand, simultaneous vapor generation occurred for higher subcooling condition. And the time transient of pressure, particle surface temperature, water temperature and visual information were simultaneously measured in the vapor film collapse experiment by external pressure pulse. Film thickness was estimated by visual data processing technique with the pictures taken by the high-speed video camera. Temperature and heat flux at the vapor-liquid interface were estimated by solving the heat condition equation with the measured pressure, liquid temperature and vapor film thickness as boundary conditions. Movement of the vapor-liquid interface were estimated with the PIV technique with the visual observation

The steam pressure effect on high temperature corrosion of zircaloy-4

International Nuclear Information System (INIS)

Kim, K. P.; Park, G. H.

1998-01-01

To find the effect of pressure on the high temperature oxidation of zircaloy-4, an autoclave capable of measuring the degree of oxidation at high temperatures and high pressure was manufactured. The degree of high temperature oxidation of zircaloy-4 was measured at three different conditions, high pressure steam, high pressure Ar gas with small amount of steam, and 1 atm steam. All the measurements were done at 750 deg C. The oxide thickness is much thicker in high pressure steam, comparing to that in the 1 atm steam. And, the higher is the steam pressure, the thicker becomes the oxide. No effect was observed in the case of high pressure Ar containing small amount of steam. Many cracks exist on the surface of specimens oxidized at high pressure steam, which come from the enhanced tetragonal to monoclinic phase transformation due to high pressure steam. The enhanced oxidation seems to oxide cracking

High-temperature expansion of the one-loop effective action induced by scalar and Dirac particles

Energy Technology Data Exchange (ETDEWEB)

Kalinichenko, Igor; Kazinski, Peter [Tomsk State University, Physics Faculty, Tomsk (Russian Federation)

2017-12-15

The complete nonperturbative expressions for the high-temperature expansion of the one-loop effective action induced by the charged scalar and the charged Dirac particles both at zero and finite temperatures are derived with account of possible nontrivial boundary conditions. The background electromagnetic field is assumed to be stationary and such that the corresponding Klein-Gordon operator or the Dirac Hamiltonian is self-adjoint. The contributions of particles and antiparticles are obtained separately. The explicit expressions for the C-symmetric and the non-C-symmetric vacuum energies of the Dirac fermions are derived. The leading corrections to the high-temperature expansion due to the nontrivial boundary conditions are explicitly found. The corrections to the logarithmic divergence of the effective action that come from the boundary conditions are derived. The high-temperature expansion of the naive one-loop effective action induced by charged fermions turns out to be divergent in the limit of a zero fermion mass. (orig.)

Research Activities on Development of Piping Design Methodology of High Temperature Reactors

Energy Technology Data Exchange (ETDEWEB)

Huh, Nam-Su [Seoul National Univ. of Science and Technology, Seoul(Korea, Republic of); Won, Min-Gu [Sungkyukwan Univ., Suwon (Korea, Republic of); Oh, Young-Jin [KEPCO Engineering and Construction Co. Inc., Gimcheon (Korea, Republic of); Lee, Hyeog-Yeon; Kim, Yoo-Gon [Korea Atomic Energy Research Institute, Daejeon(Korea, Republic of)

2016-10-15

A SFR is operated at high temperature and low pressure compared with commercial pressurized water reactor (PWR), and such an operating condition leads to time-dependent damages such as creep rupture, excessive creep deformation, creep-fatigue interaction and creep crack growth. Thus, high temperature design and structural integrity assessment methodology should be developed considering such failure mechanisms. In terms of design of mechanical components of SFR, ASME B and PV Code, Sec. III, Div. 5 and RCC-MRx provide high temperature design and assessment procedures for nuclear structural components operated at high temperature, and a Leak-Before-Break (LBB) assessment procedure for high temperature piping is also provided in RCC-MRx, A16. Three web-based evaluation programs based on the current high temperature codes were developed for structural components of high temperature reactors. Moreover, for the detailed LBB analyses of high temperature piping, new engineering methods for predicting creep C*-integral and creep COD rate based either on GE/EPRI or on reference stress concepts were proposed. Finally, the numerical methods based on Garofalo's model and RCC-MRx have been developed, and they have been implemented into ABAQUS. The predictions based on both models were compared with the experimental results, and it has been revealed that the predictions from Garafalo's model gave somewhat successful results to describe the deformation behavior of Gr. 91 at elevated temperatures.

HYFIRE II: fusion/high-temperature electrolysis conceptual-design study. Annual report

International Nuclear Information System (INIS)

Fillo, J.A.

1983-08-01

As in the previous HYFIRE design study, the current study focuses on coupling a Tokamak fusion reactor with a high-temperature blanket to a High-Temperature Electrolyzer (HTE) process to produce hydrogen and oxygen. Scaling of the STARFIRE reactor to allow a blanket power to 6000 MW(th) is also assumed. The primary difference between the two studies is the maximum inlet steam temperature to the electrolyzer. This temperature is decreased from approx. 1300 0 to approx. 1150 0 C, which is closer to the maximum projected temperature of the Westinghouse fuel cell design. The process flow conditions change but the basic design philosophy and approaches to process design remain the same as before. Westinghouse assisted in the study in the areas of systems design integration, plasma engineering, balance-of-plant design, and electrolyzer technology

Assessment of microelectronics packaging for high temperature, high reliability applications

Energy Technology Data Exchange (ETDEWEB)

Uribe, F.

1997-04-01

This report details characterization and development activities in electronic packaging for high temperature applications. This project was conducted through a Department of Energy sponsored Cooperative Research and Development Agreement between Sandia National Laboratories and General Motors. Even though the target application of this collaborative effort is an automotive electronic throttle control system which would be located in the engine compartment, results of this work are directly applicable to Sandia`s national security mission. The component count associated with the throttle control dictates the use of high density packaging not offered by conventional surface mount. An enabling packaging technology was selected and thermal models defined which characterized the thermal and mechanical response of the throttle control module. These models were used to optimize thick film multichip module design, characterize the thermal signatures of the electronic components inside the module, and to determine the temperature field and resulting thermal stresses under conditions that may be encountered during the operational life of the throttle control module. Because the need to use unpackaged devices limits the level of testing that can be performed either at the wafer level or as individual dice, an approach to assure a high level of reliability of the unpackaged components was formulated. Component assembly and interconnect technologies were also evaluated and characterized for high temperature applications. Electrical, mechanical and chemical characterizations of enabling die and component attach technologies were performed. Additionally, studies were conducted to assess the performance and reliability of gold and aluminum wire bonding to thick film conductor inks. Kinetic models were developed and validated to estimate wire bond reliability.

Temperature measurement on Zircaloy-clad fuel pins during high temperature excursions

International Nuclear Information System (INIS)

Meservey, R.H.

1976-04-01

The development of a sheathed thermocouple suitable for attachment to zircaloy-clad fuel rods and for use during high temperature (2,800 0 F) excursions under loss-of-coolant accident conditions is described. Development, fabrication, and testing of the thermocouples is covered in detail. In addition, the development of a process for laser welding the thermocouples to fuel rods is discussed. The thermocouples and attachment welds have been tested for resistance to corrosion and nuclear radiation and have been subjected to fast thermal cycle, risetime, and blowdown accident tests

Thermal conditions influence changes in body temperature induced by intragastric administration of capsaicin in mice.

Science.gov (United States)

Mori, Noriyuki; Urata, Tomomi; Fukuwatari, Tsutomu

2016-08-01

Capsaicin has been reported to have unique thermoregulatory actions. However, changes in core temperature after the administration of capsaicin are a controversial point. Therefore, we investigated the effects of environmental thermal conditions on changes in body temperature caused by capsaicin in mice. We showed that intragastric administration of 10 and 15 mg/kg capsaicin increased tail temperature and decreased colonic temperatures in the core temperature (CT)-constant and CT-decreasing conditions. In the CT-increasing condition, 15 mg/kg capsaicin increased tail temperature and decreased colonic temperature. However, 10 mg/kg capsaicin increased colonic temperature. Furthermore, the amount of increase in tail temperature was greater in the CT-decreasing condition and lower in the CT-increasing condition, compared with that of the CT-constant condition. These findings suggest that the changes in core temperature were affected by the environmental thermal conditions and that preliminary thermoregulation state might be more important than the constancy of temperature to evaluate the effects of heat diffusion and thermogensis.

Curious Case of Positive Current Collectors: Corrosion and Passivation at High Temperature.

Science.gov (United States)

Sayed, Farheen N; Rodrigues, Marco-Tulio F; Kalaga, Kaushik; Gullapalli, Hemtej; Ajayan, P M

2017-12-20

In the evaluation of compatibility of different components of cell for high-energy and extreme-conditions applications, the highly focused are positive and negative electrodes and their interaction with electrolyte. However, for high-temperature application, the other components are also of significant influence and contribute toward the total health of battery. In present study, we have investigated the behavior of aluminum, the most common current collector for positive electrode materials for its electrochemical and temperature stability. For electrochemical stability, different electrolytes, organic and room temperature ionic liquids with varying Li salts (LiTFSI, LiFSI), are investigated. The combination of electrochemical and spectroscopic investigations reflects the varying mechanism of passivation at room and high temperature, as different compositions of decomposed complexes are found at the surface of metals.

Sustainability and Efficiency Improvements of Gas-Cooled High Temperature Reactors

International Nuclear Information System (INIS)

Marmier, Alain

2012-01-01

high temperature irradiation to high burn-ups with fission gas release measurements. To this end, the HFR-EU1 fuel irradiation in the High Flux Reactor (HFR) Petten (2006-2010) explored the potential for high performance and high burn-up of existing German fuel (3 pebbles produced for the AVR reactor at the German research centre Juelich) and newly produced Chinese fuel (2 pebbles produced by INET for use in the HTR-10 test reactor in China). These five pebbles were irradiated for 445 days in separately controlled capsules, while the fission gas release was monitored by gamma spectrometry thus enabling evaluation of the characteristic release over birth fraction, indicative for the health of the fuel. In none of the pebbles, abnormally increased fission gas release was observed indicating that all of the approx. 45,000 coated particles in the pebbles had remained intact. The results presented in this thesis cover the first 332 days of irradiation. While HFR-EU1 was dedicated to a particularly high burn-up, HFR-EU1bis, performed between 2004 and 2005, investigated extremely high temperature for steady-state conditions. The comparison of both experiments confirms that temperature plays a decisive part in fuel performance and integrity. The peak fuel temperature in pebbles can be lowered with the so-called w allpaper fuel , in which the coated fuel particles are arranged in a spherical shell within a pebble. This wallpaper concept also enhances neutronic performance through improved neutron economy, resulting in reduced fissile material and/or enrichment needs or providing the potential to achieve higher burn-up. To quantify these improvements, calculations were performed using the Monte Carlo neutron transport and depletion codes MCNP/MCB (to assess conversion ratio, temperature coefficient of reactivity and neutron multiplication) and PANTHERMIX (for fuel cycle in steady state conditions and loss of coolant accident calculations). Based on PANTHERMIX steady

Effect of cold working and aging on high temperature deformation of high Mn stainless steel

International Nuclear Information System (INIS)

Yoshikawa, M.; Habara, Y.; Matsuki, R.; Aoyama, H.

1999-01-01

By the addition of N, the strength of high Mn stainless steel can be increased. Cold rolling and aging are effective to increase its strength further, and with those treatments this grade is often used for high temperature applications. In this study, creep deformation behavior and high temperature strength of the high Mn stainless steel in cold rolled and aged conditions are discussed as compared to Type 304 stainless steel. It has been revealed that as-rolled specimens show instant elongation at the beginning of creep tests and its amount is larger in the high Mn grade than in Type 304. Also, the creep rate of the high Mn stainless steel is smaller than that of Type 304. These facts may be related to the change in microstructure. (orig.)

Comparison of creep behavior under varying load/temperature conditions between Hastelloy XR alloys with different boron content levels

International Nuclear Information System (INIS)

Tsuji, Hirokazu; Nakajima, Hajime; Shindo, Masami; Tanabe, Tatsuhiko; Nakasone, Yuji.

1996-01-01

In the design of the high-temperature components, it is often required to predict the creep rupture life under the conditions in which the stress and/or temperature may vary by using the data obtained with the constant load and temperature creep rupture tests. Some conventional creep damage rules have been proposed to meet the above-mentioned requirement. Currently only limited data are available on the behavior of Hastelloy XR, which is a developed alloy as the structural material for high-temperature components of the High-Temperature Engineering Test Reactor (HTTR), under varying stress and/or temperature creep conditions. Hence a series of constant load and temperature creep rupture tests as well as varying load and temperature creep rupture tests was carried out on two kinds of Hastelloy XR alloys whose boron content levels are different, i.e., below 10 and 60 mass ppm. The life fraction rule completely fails in the prediction of the creep rupture life of Hastelloy XR with 60 mass ppm boron under varying load and temperature conditions though the rule shows good applicability for Hastelloy XR with below 10 mass ppm boron. The change of boron content level of the material during the tests is the most probable source of impairing the applicability of the life fraction rule to Hastelloy XR whose boron content level is 60 mass ppm. The modified life fraction rule has been proposed based on the dependence of the creep rupture strength on the boron content level of the alloy. The modified rule successfully predicts the creep rupture life under the two stage creep test conditions from 1000 to 900degC. The trend observed in the two stage creep tests from 900 to 1000degC can be qualitatively explained by the mechanism that the oxide film which is formed during the prior exposure to 900degC plays the role of the protective barrier against the boron dissipation into the environment. (J.P.N.)

Polarization behaviour of polyvinylidenefluoride-polysulfone (PVDF: PSF) blends under high field and high temperature condition

Science.gov (United States)

Shrivas, Sandhya; Patel, Swarnim; Dubey, R. K.; Keller, J. M.

2018-05-01

Thermally stimulated discharge currents of PVDF: PSF blend samples in ratio 80:20 and 95:05 prepared by the solution cast technique have been studied as a function of polarizing field and polarizing temperature, the temperature corresponding to a peak in TSDC is found to be independent of polarizing field but dependent on the polarizing temperature.

High-temperature, high-pressure bonding of nested tubular metallic components

International Nuclear Information System (INIS)

Quinby, T.C.

1980-01-01

This invention is a tool for effecting high-temperature, high compression bonding between the confronting faces of nested, tubular, metallic components. In a typical application, the tool is used to produce tubular target assemblies for irradiation in nuclear reactors or particle accelerators, the target assembly comprising a uranium foil and an aluminum-alloy substrate. The tool preferably is composed throughout of graphite. It comprises a tubular restraining member in which a mechanically expandable tubular core is mounted to form an annulus with the member. The components to be bonded are mounted in nested relation in the annulus. The expandable core is formed of individually movable, axially elongated segments whose outer faces cooperatively define a cylindrical pressing surface and whose inner faces cooperatively define two opposed, inwardly tapered, axial bores. Tapered rams extend respectively into the bores. The loaded tool is mounted in a conventional hot-press provided with evacuation means, heaters for maintaining its interior at bonding temperature, and hydraulic cylinders for maintaining a selected inwardly directed pressure on the tapered rams. With the hotpress evacuated and the loaded tool at the desired temperature, the cylinders are actuated to apply the selected pressure to the rams. The rams in turn expand the segmented core to maintain the nested components in compression against the restraining member. These conditions are maintained until the confronting faces of the nested components are joined in a continuous, uniform bond characterized by high thermal conductivity

High-temperature, high-pressure bonding of nested tubular metallic components

Science.gov (United States)

Quinby, T.C.

A tool is described for effecting high-temperature, high-compression bonding between the confronting faces of nested, tubular, metallic components. In a typical application, the tool is used to produce tubular target assemblies for irradiation in nuclear reactors or particle accelerators. The target assembly comprising a uranum foil and an aluninum-alloy substrate. The tool is composed of graphite. It comprises a tubular restraining member in which a mechanically expandable tubular core is mounted to form an annulus. The components to be bonded are mounted in nested relation in the annulus. The expandable core is formed of individually movable, axially elongated segments whose outer faces cooperatively define a cylindrical pressing surface and whose inner faces cooperatively define two opposed, inwardly tapered, axial bores. Tapered rams extend into the bores. The loaded tool is mounted in a conventional hot-press provided with evacuation means, heaters for maintaining its interior at bonding temperature, and hydraulic cylinders for maintaining a selected inwardly directed pressure on the tapered rams. With the hot-press evacuated and the loaded tool at the desired temperature, the cylinders are actuated to apply the selected pressure to the rams. The rams in turn expand the segmented core to maintain the nested components in compression against the restraining member. These conditions are maintained until the confronting faces of the nested components are joined in a continuous, uniform bond characterized by high thermal conductivity.

Combined conditioning in the high-temperature experimental nuclear reactor (AVR) at Juelich

International Nuclear Information System (INIS)

Nieder, R.; Vey, K.; Ivens, G.

1984-01-01

The high temperature experimental nuclear reactor (AVR) is the first nuclear power plant in which combined cycle operation has been introduced. The water-steam cycle has been operated for about 15 years according to the alkali method of working with ammonia and hydrazine. The VGB-guidelines have been adhered to througout. Since January 1983 cobined cycle operation has been employed, and in this process a pH-value of about 8.5 and an oxygen concentration of about 200 μg/kg in the feedwater have been used. A distinct reduction of tritium concentration in the water-steam cycle was the outstanding new result. (orig.) [de

New deployment of high temperature gas-cooled reactor

International Nuclear Information System (INIS)

Sekimoto, Hiroshi; Tsuchie, Yasuo; Kunitomi, Kazuhiko; Shiozawa, Shusaku; Konuki, Kaoru; Inagaki, Yoshiyuki; Hayakawa, Hitoshi

2002-01-01

The high temperature gas-cooled reactor (HTGR) is now under a condition difficult to know it well, because of considering not only power generation, but also diverse applications of its nuclear heat, of having extremely different safe principle from that of conventional reactors, of having two types of pebble-bed and block which are extremely different types, of promoting its construction plan in South Africa, of including its application to disposition of Russian surplus weapons plutonium of less reporting HTTR in Japan in spite of its full operation, and so on. However, HTGR is expected for an extremely important nuclear reactor aiming at the next coming one of LWR. HTGR which is late started and developed under complete private leading, is strongly conscious at environmental problem since its beginning. Before 30 years when large scale HTGR was expected to operate, it advertised a merit to reduce wasted heat because of its high temperature. As ratio occupied by electricity expands among application of energies, ratio occupied by the other energies are larger. When considering applications except electric power, high temperature thermal energy from HTGR can be thought wider applications than that from LWR and so on. (G.K.)

Temperature effect on rose downy mildew development under environmental controlled conditions

OpenAIRE

Filgueira D., Juan José; Zambrano, Angélica

2014-01-01

The rose downy mildew disease, caused by Peronospora sparsa Berkeley, is one of the most important that affect rose crops in Colombia. To manage this disease, flower growers must deal with high-costs due to the excessive application of fungicides, but without good results. Studies on P. sparsa behavior have shown its narrow relationship with environmental conditions. In this study, the temperature effect was evaluated during the infection and sporulation of P. sparsa in Charlotte leaflets, a ...

High Temperature Sliding Wear of NiAl-based Coatings Reinforced by Borides

Directory of Open Access Journals (Sweden)

Oleksandr UMANSKYI

2016-05-01

Full Text Available The development of composite materials (CM in the systems “metal-refractory compound” is one of the up-to-date trends in design of novel materials aimed at operating under the conditions of significant loads at high temperature. To design such material, NiAl, which is widely used for deposition of protective coatings on parts of gas-turbine engines, was selected for a matrix. To strengthen a NiAl under the conditions of intense wear and a broad temperature range (up to 1000 °C, it is reasonable to add refractory inclusions. Introduction of refractory borides into matrix leads to a marked increase in metal wear resistance. In order to research the behavior of the designed composites at high temperatures and to study the influence of oxides on the friction processes, the authors carried out high temperature oxidation of CM of the above systems at 1000 °С for 90 min. It was determined that all of the composites were oxidized selectively and that the thickness of oxide layers formed on the boride inclusions is 3 – 7 times that on the oxides formed on the NiAl matrix. The mechanism of wear of gas-thermal coatings of the NiAl – МеB2 systems was studied for conditions of high temperature tribotests using the «pin-on-disc» technique. The obtained results indicate that introduction of TiB2, CrB2 and ZrB2 leads to their more intense oxidation during high temperature tribotests as compared to the matrix. The oxides formed on refractory borides act as solid lubricants, which promote a decrease in wear of the contact friction pairs. For more detailed investigation of the effect of tribo-oxidation products on the friction processes, tribotests were conducted for prior oxidized (at 900 °С coatings NiAl – 15 wt.% CrB2 (TiB2, ZrB2.DOI: http://dx.doi.org/10.5755/j01.ms.22.1.8093

Ruthenium release at high temperature from irradiated PWR fuels in various oxidising conditions. Main findings from the VERCORS program

International Nuclear Information System (INIS)

Ducros, G.; Pontillon, Y.; Malgouyres, P.P.; Taylor, P.; Dutheillet, Y.

2005-01-01

Fission product release and transport in case of PWR severe accident is a major topic in reactor safety assessment due to the potential radiological consequences for surrounding populations and the environment. In this context, the Institute for Radiological Protection and Safety (IRSN) and Electricite de France (EDF) have supported the VERCORS analytical test program which was performed by the ''Commissariat a l'Energie Atomique'' (CEA). It is usually considered as complementary to the PHEBUS FP in-pile integral experimental program. 25 annealing tests were performed between 1983 and 2002 on irradiated PWR fuels under various conditions of temperature and atmospheres (oxidising or reducing conditions).The influence of the nature of the fuel (UO 2 versus MOX, burn-up) and the fuel morphology (initially intact or fragmented fuels) have also been investigated. These led to an extended data base allowing on the one hand to study mechanisms which promote fission products release, and on the other hand to enhance models implemented in severe accident codes. Among all the fission products investigated, ruthenium is of specific concern because of its high radiological effects due essentially to the combination of both its short and long half-life isotopes (i.e. 103 Ru and 106 Ru respectively), but also by its ability to generate volatile gaseous oxides (RuO 3 , RuO 4 ) in very oxidising conditions, in particular in the case of air ingress accidents. Important uncertainties still remain on the release and transport of this element in such situations, and investigations on this open issue are notably carried out in the SARNET European framework. The present communication gives a general overview of the VERCORS program and presents more deeply the main findings concerning the ruthenium release. Its global behaviour is analysed on the basis of several comparative tests: same UO 2 sample (35 and 50 GWd/t) under hydrogen or steam conditions, similar MOX sample (40 GWd/t) under

Lactating performance, water and feed consumption of rabbit does reared under a Mediterranean summer circadian cycle of temperature v. comfort temperature conditions.

Science.gov (United States)

Bakr, M H; Tusell, L; Rafel, O; Terré, M; Sánchez, J P; Piles, M

2015-07-01

The general aim of this research was to study the effect of high ambient temperature on the performance of does during lactation, specifically the following factors: average daily feed (ADFI) and water (ADWI) intakes, daily milk yield (DMY); milk composition: dry matter (DM), CP and gross energy (GE); doe BW (DW); individual kit weaning weight (IWW) and litter survival rate during lactation (SR). The study was undertaken comparing the performance of two groups of contemporary does reared under the same management, feeding regime and environmental conditions, except the environmental temperature and humidity. A total of 80 females were randomly allocated, at 60 days of age, into two identical and continuous rooms. In one room, the temperature was maintained permanently within the thermo-neutral zone (between 18°C to 22°C); thus, environmental conditions in this room were considered as comfort conditions. In the second room, the environmental temperature pattern simulated the daily temperature cycles that were characteristic of the summer in Mediterranean countries (24°C at 0800 h, increasing up to 29°C until 1100 h; maintenance at 29°C to 31°C for 4 h and decreasing to about 24°C to 26°C around 1700 h until 0800 h of the following day), which were considered as thermal stress conditions. Females followed a semi-intensive reproductive rhythm, first artificial insemination at 4.5 months of age, with subsequent 42-day reproductive cycles. Traits were recorded from a total of 138 lactations. Does were controlled up to the 5th lactation. Data were analyzed using linear and linear mixed models. High ambient temperature led to a lower ADFI (-9.4%), DW (-6.2%) and IWW (-8%), but it did not affect ADWI. No significant difference was found either for DMY, milk composition (DM, CP and GE) and SR during the lactation period. Heat stress was moderate, and does were able to adapt to it behaviorally by decreasing feed intake (to reduce heat production), but also live

Fuel temperature influence on diesel sprays in inert and reacting conditions

International Nuclear Information System (INIS)

Payri, Raul; García-Oliver, Jose M.; Bardi, Michele; Manin, Julien

2012-01-01

The detailed knowledge of the evaporation–combustion process of the Diesel spray is a key factor for the development of robust injection strategies able to reduce the pollutant emissions and keep or increase the combustion efficiency. In this work several typical measurement applied to the diesel spray diagnostic (liquid length, lift-off length and ignition delay) have been employed in a novel continuous flow test chamber that allows an accurate control on a wide range of thermodynamic test conditions (up to 1000 K and 15 MPa). A step forward in the control of the test boundary conditions has been done employing a special system to study the fuel temperature effect on the evaporation and combustion of the spray. The temperature of the injector body has been controlled with a thermostatic system and the relationship between injector body and fuel temperature has been observed experimentally. Imaging diagnostics have been employed to visualize the liquid phase penetration in evaporative/inert conditions and, lift-off length and ignition delay in reactive condition. The results underline a clear influence of the injector body temperature on both conditions, evaporative and, in a lesser degree, reactive; finally the physical models found in the literature have been compared with the results obtained experimentally. - Highlights: ► The effect of the fuel temperature is substantial on liquid length (up to 15%). ► Fuel temperature has low effect but still appreciable on LOL and ignition delay. ► Theoretical one dimensional spray models are able to reproduce the experimental results with good accuracy.

Experimental confirmation of the ITER cryopump high temperature regeneration scheme

International Nuclear Information System (INIS)

Day, C.; Haas, H.

2007-01-01

Forschungszentrum Karlsruhe (FZK) is developing the ITER high vacuum pumping systems for evacuation and maintenance of the required pressure levels in the torus (during burn and dwell, conditioning and leak detection), the neutral beam injectors and the cryostat vessel. All ITER high vacuum systems share the same concept of accumulative cryosorption pumping. The pumping surfaces, forced-cooled by 4.5 K supercritical helium, are coated with activated charcoal so as to be able to adsorb helium and hydrogens. All other gases are cryopumped by cryogenic phase transition from gaseous into the liquid/solid state. For the hydrogen processing pumps in the torus and the NBI, the maximum pumping time is given by the limitation of the maximum hydrogen inventory such that the resulting pressure in case of a loss of vacuum event and a corresponding oxy-hydrogen explosion is compatible to the design criteria of the vacuum vessel. To limit the gas accumulation, a staggered regeneration philosophy has been adopted, which involves three different temperature levels in order to achieve high regeneration efficiencies at best availability of the pumping system. The regular regeneration step is performed at a charcoal temperature of 90 K to release all hydrogen isotopomers (and helium), which are subsequently pumped out by the forevacuum pumping system. The second step at ambient temperature leads to the release of all air-like species. It has to be performed less frequently, probably over-night. Any water-like species with strong sorption bonding forces need still higher temperatures for effective desorption from the charcoal. These species comprise not only water itself but also high molecular tracers added to the water circuits in case of leak localisation and any pumped higher hydrocarbons from the plasma exhaust or. The latter in their tritiated forms may contribute significantly to the semi-permanent tritium inventory; a good knowledge of their regeneration characteristics is

Computer Simulation Studies of Ion Channels at High Temperatures

Science.gov (United States)

Song, Hyun Deok

The gramicidin channel is the smallest known biological ion channel, and it exhibits cation selectivity. Recently, Dr. John Cuppoletti's group at the University of Cincinnati showed that the gramicidin channel can function at high temperatures (360 ˜ 380K) with significant currents. This finding may have significant implications for fuel cell technology. In this thesis, we have examined the gramicidin channel at 300K, 330K, and 360K by computer simulation. We have investigated how the temperature affects the current and differences in magnitude of free energy between the two gramicidin forms, the helical dimer (HD) and the double helix (DH). A slight decrease of the free energy barrier inside the gramicidin channel and increased diffusion at high temperatures result in an increase of current. An applied external field of 0.2V/nm along the membrane normal results in directly observable ion transport across the channels at high temperatures for both HD and DH forms. We found that higher temperatures also affect the probability distribution of hydrogen bonds, the bending angle, the distance between dimers, and the size of the pore radius for the helical dimer structure. These findings may be related to the gating of the gramicidin channel. Methanococcus jannaschii (MJ) is a methane-producing thermophile, which was discovered at a depth of 2600m in a Pacific Ocean vent in 1983. It has the ability to thrive at high temperatures and high pressures, which are unfavorable for most life forms. There have been some experiments to study its stability under extreme conditions, but still the origin of the stability of MJ is not exactly known. MJ0305 is the chloride channel protein from the thermophile MJ. After generating a structure of MJ0305 by homology modeling based on the Ecoli ClC templates, we examined the thermal stability, and the network stability from the change of network entropy calculated from the adjacency matrices of the protein. High temperatures increase the

High temperature materials

International Nuclear Information System (INIS)

2003-01-01

The aim of this workshop is to share the needs of high temperature and nuclear fuel materials for future nuclear systems, to take stock of the status of researches in this domain and to propose some cooperation works between the different research organisations. The future nuclear systems are the very high temperature (850 to 1200 deg. C) gas cooled reactors (GCR) and the molten salt reactors (MSR). These systems include not only the reactor but also the fabrication and reprocessing of the spent fuel. This document brings together the transparencies of 13 communications among the 25 given at the workshop: 1) characteristics and needs of future systems: specifications, materials and fuel needs for fast spectrum GCR and very high temperature GCR; 2) high temperature materials out of neutron flux: thermal barriers: materials, resistance, lifetimes; nickel-base metal alloys: status of knowledge, mechanical behaviour, possible applications; corrosion linked with the gas coolant: knowledge and problems to be solved; super-alloys for turbines: alloys for blades and discs; corrosion linked with MSR: knowledge and problems to be solved; 3) materials for reactor core structure: nuclear graphite and carbon; fuel assembly structure materials of the GCR with fast neutron spectrum: status of knowledge and ceramics and cermets needs; silicon carbide as fuel confinement material, study of irradiation induced defects; migration of fission products, I and Cs in SiC; 4) materials for hydrogen production: status of the knowledge and needs for the thermochemical cycle; 5) technologies: GCR components and the associated material needs: compact exchangers, pumps, turbines; MSR components: valves, exchangers, pumps. (J.S.)

Hydrothermal carbonization of biomass waste under low temperature condition

Directory of Open Access Journals (Sweden)

Putra Herlian Eriska

2018-01-01

Full Text Available In this paper, the use of banana peel for energy purposes was investigated. Banana peel is a lignocellulosic waste since it is the most widely produced and consumed fruit in Indonesia. Among the others, hydrothermal carbonization (HTC was chosen as alternative themochemical process, suitable for high moisture biomass. Through a 1 L stirred reactor, hydrothermal treatments were performed under low temperature condition (190, 210 and 230 °C, residence times (30 and 60 min, and biomass to water ratio (1:3, 1:5, and 1:10. Three of product were collected from the process with primary material balance. Solid phase (hydrochar was evaluated in terms of calorific value, proximate and ultimate analysis. The results suggested that the hydrothermal carbonization of banana peel gave high heating value (HHV of 20.09 MJ/kg for its char after dried naturally.

Multi-species time-history measurements during high-temperature acetone and 2-butanone pyrolysis

KAUST Repository

Lam, Kingyiu; Ren, Wei; Pyun, Sunghyun; Farooq, Aamir; Davidson, David Frank; Hanson, Ronald Kenneth

2013-01-01

High-temperature acetone and 2-butanone pyrolysis studies were conducted behind reflected shock waves using five species time-history measurements (ketone, CO, CH3, CH4 and C2H4). Experimental conditions covered temperatures of 1100-1600 Kat 1.6 atm

Quantum electrodynamics at high temperature. 2

International Nuclear Information System (INIS)

Alvarez-Estrada, R.F.

1988-01-01

The photon sector of QED in d = 3 spatial dimensions is analyzed at high temperature thereby generalizing nontrivially a previous study for d = 1. The imaginary time formalism and an improved renormalized perturbation theory which incorporates second order Debye screening are used. General results are presented for the leading high temperature contributions to all renormalized connected photon Green's functions for fixed external momenta (much smaller than the temperature) to all orders in the improved perturbation theory. Those leading contributions are ultraviolet finite, infrared convergent and gauge invariant, and display an interesting form of dimensional reduction at high temperature. A new path integral representations is given for the high temperature partition function with an external photon source, which is shown to generate all leading high temperature Green's functions mentioned above, and, so, it displays neatly the kind of dimensional reduction which makes QED to become simpler at high temperature. This limiting partition function corresponds to an imaginary time dependent electron positron field interacting with an electromagnetic field at zero imaginary time, and it depends on the renormalized electron mass and electric charge, the second order contribution to the usual renormalization constant Z 3 and a new mass term, which is associated to the photon field with vanishing Lorentz index. The new mass term corresponds to a finite number of diagrams in the high temperature improved perturbation theory and carriers ultraviolet divergences which are compensated for by other contributions (so that the leading high temperature Green's functions referred to above are ultraviolet finite). The dominant high temperature contributions to the renormalized thermodynamic potential to all perturbative orders: i) are given in terms of the above leading high-temperature contributions to the photon Green's functions (except for a few diagrams of low order in the

High-temperature materials and structural ceramics

International Nuclear Information System (INIS)

1990-01-01

This report gives a survey of research work in the area of high-temperature materials and structural ceramics of the KFA (Juelich Nuclear Research Center). The following topics are treated: (1) For energy facilities: ODS materials for gas turbine blades and heat exchangers; assessment of the remaining life of main steam pipes, material characterization and material stress limits for First-Wall components; metallic and graphitic materials for high-temperature reactors. (2) For process engineering plants: composites for reformer tubes and cracking tubes; ceramic/ceramic joints and metal/ceramic and metal/metal joints; Composites and alloys for rolling bearing and sliding systems up to application temperatures of 1000deg C; high-temperature corrosion of metal and ceramic material; porous ceramic high-temperature filters and moulding coat-mix techniques; electrically conducting ceramic material (superconductors, fuel cells, solid electrolytes); high-temperature light sources (high-temperature chemistry); oil vapor engines with caramic components; ODS materials for components in diesel engines and vehicle gas turbines. (MM) [de

Fabrication of Metallic Glass Powder for Brazing Paste for High-Temperature Thermoelectric Modules

Science.gov (United States)

Seo, Seung-Ho; Kim, Suk Jun; Lee, Soonil; Seo, Won-Seon; Kim, Il-Ho; Choi, Soon-Mok

2018-06-01

Metallic glass (MG) offers the advantage of outstanding oxidation resistance, since it has disordered atomic-scale structure without grain boundaries. We fabricated Al-based MG ribbons (Al84.5Y10Ni5.5) by a melt spinning process. We evaluated the adhesion strength of interfaces between the Al-based MG and a Ni-coated Cu electrode formed under various conditions at high temperature. In addition, we attempted to optimize the process conditions for pulverizing MG ribbons to high-energy ball milling and planetary milling. We confirmed that the electrical resistivity of the Al-based MG ribbon was substantially reduced after annealing at high temperature (over 300°C) due to crystallization.

High temperature storage loop :

Energy Technology Data Exchange (ETDEWEB)

Gill, David Dennis; Kolb, William J.

2013-07-01

A three year plan for thermal energy storage (TES) research was created at Sandia National Laboratories in the spring of 2012. This plan included a strategic goal of providing test capability for Sandia and for the nation in which to evaluate high temperature storage (>650ÀC) technology. The plan was to scope, design, and build a flow loop that would be compatible with a multitude of high temperature heat transfer/storage fluids. The High Temperature Storage Loop (HTSL) would be reconfigurable so that it was useful for not only storage testing, but also for high temperature receiver testing and high efficiency power cycle testing as well. In that way, HTSL was part of a much larger strategy for Sandia to provide a research and testing platform that would be integral for the evaluation of individual technologies funded under the SunShot program. DOEs SunShot program seeks to reduce the price of solar technologies to 6/kWhr to be cost competitive with carbon-based fuels. The HTSL project sought to provide evaluation capability for these SunShot supported technologies. This report includes the scoping, design, and budgetary costing aspects of this effort

Rheology of serpentinite in high-temperature and low-slip-velocity regime

Science.gov (United States)

Takahashi, M.; Uehara, S.; Mizoguchi, K.; Takeda, N.; Masuda, K.

2009-12-01

This study was designed to clarify the rheology of serpentinite experimentally, related both the sliding velocity and the temperature. The frictional behavior of serpentinite is of particular interest in the study of earthquake generation processes along subducting plates and transform faults. Previous studies [Reinen et al., 1991-93] revealed that the serpentinites indicated two-mechanical behaviors at velocity-step test: ‘state-variable dominated behavior’ at relatively higher velocity (0.1-10 μm/sec) and ‘flow-dominated behavior’ at lower velocity (less than 0.1 μm/sec). Such complexity on the frictional behavior could make it complicated to forecast on the slip acceleration process from the plate motion velocity to the earthquake. Even under the room-temperature condition, those multiple behavior could be observed, thus, serpentinite can be a model substance to present a new constitutive law at the brittle-ductile transition regime. We, therefore, focus to discuss the transient behaviors of serpentinite at the velocity-step test. We used a gas-medium, high-pressure, and high-temperature triaxial testing machine belonging to the National Institute of Advanced Industrial Science and Technology (AIST), Japan. Sliding deformation was applied on the thin zone of the serpentinite gouge (1.0 g of almost pure antigorite powder) sandwiched between two alumina blocks with oblique surfaces at 30° to the axis. All experiments were carried out under a set of constant conditions, 100 MPa of the confining pressure (Ar-gas) and 30 MPa of the pore pressure (distilled water). The temperature conditions were varied from the room-temperature to 500° C, and three sliding velocity-regimes were adopted: low (0.0115 - 0.115 μm/sec), middle (0.115 - 1.15 μm/sec) and high (1.15 - 11.5 μm/sec) velocity regimes. In each velocity regime, the sliding velocity was increased or decreased in a stepwise fashion, and then we observed the transient behaviors until it reached the

Optimization analysis of high temperature heat pump coupling to desiccant wheel air conditioning system

DEFF Research Database (Denmark)

Sheng, Ying; Zhang, Yufeng; Fang, Lei

2014-01-01

The high temperature heat pump and desiccant wheel (HTHP&DW) system can make full use of heat released from the condenser of heat pump for DW regeneration without additional heat. In this study, DW operation in the HTHP&DW system was investigated experimentally, and the optimization analysis...... of HTHP&DW system was carried out. The performance of DW had influence on the dehumidification (evaluated by dehumidification and regeneration effectiveness) and cooling load (evaluated by thermal and adiabatic effectiveness). The results show that the enthalpy increase occurred in all the experiments...... of the system. When the regeneration temperature is 63°C, the maximal dehumidification effectiveness is 35.4% and the satisfied adiabatic effectiveness is 88%, which contributes to the optimal balance between dehumidification and cooling. © 2014 Tianjin University and Springer-Verlag Berlin Heidelberg....

Estimation of thermal sensation during varied air temperature conditions.

Science.gov (United States)

Katsuura, T; Tabuchi, R; Iwanaga, K; Harada, H; Kikuchi, Y

1998-03-01

Seven male students were exposed to four varied air temperature environments: hot (37 degrees C) to neutral (27 degrees C) (HN), neutral to hot (NH), cool (17 degrees C) to neutral (CN), and neutral to cool (NC). The air temperature was maintained at the first condition for 20 min, then was changed to the second condition after 15 min and was held there for 20 min. Each subject wore a T-shirt, briefs, trunks, and socks. Each sat on a chair and was continuously evaluated for thermal sensation, thermal comfort, and air velocity sensation. Some physiological and thermal parameters were also measured every 5 s during the experiment. The correlation between thermal sensation and skin temperature at 15 sites was found to be poor. The subjects felt much warmer during the rising phase of the air temperature (CN, NH) than during the descending phase (HN, NC) at a given mean skin temperature. However, thermal sensation at the same heat flux or at the same value of the difference between skin and air temperature (delta(Tsk - Ta)) was not so different among the four experimental conditions, and the correlation between thermal sensation and heat flux or delta(Tsk - Ta) was fairly good. The multiple regression equation of the thermal sensation (TS) on 15 sites of skin temperature (Tsk; degrees C) was calculated and the coefficient of determination (R*2) was found to be 0.656. Higher coefficients of determination were found in the equations of thermal sensation for the heat flux (H; kcal.m-2.h-1) at the right and left thighs of the subjects and on delta(Tsk - Ta) (degrees C) at 4 sites. They were as follows: TS = 2.04 - 0.016 Hright - 0.036 Hleft; R*2 = 0.717, TS = 1.649 + 0.013 delta(Tsk - Ta)UpperArm - 0.036 delta(Tsk - Ta)Chest - 0.223 delta(Tsk - Ta)Thigh-0.083 delta(Tsk - Ta)LowerLeg; R*2 = 0.752, respectively.

Microstructural Evolution and Mechanical Behavior of High Temperature Solders: Effects of High Temperature Aging

Science.gov (United States)

Hasnine, M.; Tolla, B.; Vahora, N.

2018-04-01

This paper explores the effects of aging on the mechanical behavior, microstructure evolution and IMC formation on different surface finishes of two high temperature solders, Sn-5 wt.% Ag and Sn-5 wt.% Sb. High temperature aging showed significant degradation of Sn-5 wt.% Ag solder hardness (34%) while aging has little effect on Sn-5 wt.% Sb solder. Sn-5 wt.% Ag experienced rapid grain growth as well as the coarsening of particles during aging. Sn-5 wt.% Sb showed a stable microstructure due to solid solution strengthening and the stable nature of SnSb precipitates. The increase of intermetallic compound (IMC) thickness during aging follows a parabolic relationship with time. Regression analysis (time exponent, n) indicated that IMC growth kinetics is controlled by a diffusion mechanism. The results have important implications in the selection of high temperature solders used in high temperature applications.

High temperature combustion facility: present capabilities and future prospects

International Nuclear Information System (INIS)

Boccio, J.L.; Ginsberg, T.; Ciccarelli, G.

1995-01-01

The high-temperature combustion facility constructed and operated by the Department of Advanced Technology of Brookhaven National Laboratory to support and promote research in the area of hydrogen combustion phenomena in mixtures prototypical to light-water reactor containment atmospheres under potential severe accident conditions is reported. The facility can accommodate combustion research activities encompassing the fields of detonation physics, flame acceleration, and low-speed deflagration in a wide range of combustible gas mixtures at initial temperatures up to 700 K and post-combustion pressures up to 100 atmospheres. Some preliminary test results are presented that provide further evidence that the effect of temperature is to increase the sensitivity of hydrogen-air-steam mixtures to undergo detonation [ru

IMPACT OF TROPICAL CONDITIONS ON THIN-LAYER CHROMATOGRAPHY IN ANALYTICAL TOXICOLOGY - HIGH-TEMPERATURES AND MODERATE HUMIDITIES

NARCIS (Netherlands)

DEZEEUW, RA; FRANKE, JP; DIK, E; TENDOLLE, W; KAM, BL

The impact of high temperatures (24 to 39-degrees-C) and low to moderately high humidities (20 to 70%) on the applicability of TLC systems for drug identification was studied during a 6 month climatologic cycle in Burkina Faso (West Africa). In general, the Rf values as observed on the plates were

Response Analysis on Electrical Pulses under Severe Nuclear Accident Temperature Conditions Using an Abnormal Signal Simulation Analysis Module

Directory of Open Access Journals (Sweden)

Kil-Mo Koo

2012-01-01

Full Text Available Unlike design basis accidents, some inherent uncertainties of the reliability of instrumentations are expected while subjected to harsh environments (e.g., high temperature and pressure, high humidity, and high radioactivity occurring in severe nuclear accident conditions. Even under such conditions, an electrical signal should be within its expected range so that some mitigating actions can be taken based on the signal in the control room. For example, an industrial process control standard requires that the normal signal level for pressure, flow, and resistance temperature detector sensors be in the range of 4~20 mA for most instruments. Whereas, in the case that an abnormal signal is expected from an instrument, such a signal should be refined through a signal validation process so that the refined signal could be available in the control room. For some abnormal signals expected under severe accident conditions, to date, diagnostics and response analysis have been evaluated with an equivalent circuit model of real instruments, which is regarded as the best method. The main objective of this paper is to introduce a program designed to implement a diagnostic and response analysis for equivalent circuit modeling. The program links signal analysis tool code to abnormal signal simulation engine code not only as a one body order system, but also as a part of functions of a PC-based ASSA (abnormal signal simulation analysis module developed to obtain a varying range of the R-C circuit elements in high temperature conditions. As a result, a special function for abnormal pulse signal patterns can be obtained through the program, which in turn makes it possible to analyze the abnormal output pulse signals through a response characteristic of a 4~20 mA circuit model and a range of the elements changing with temperature under an accident condition.

Stable solid state reference electrodes for high temperature water chemistry

International Nuclear Information System (INIS)

Jayaweera, P.; Millett, P.J.

1995-01-01

A solid state electrode capable of providing a stable reference potential under a wide range of temperatures and chemical conditions has been demonstrated. The electrode consists of a zirconia or yttria-stabilized zirconia tube packed with an inorganic polymer electrolyte and a silver/silver chloride sensing element. The sensing element is maintained near room temperature by a passive cooling heat sink. The electrode stability was demonstrated by testing it in high temperature (280 C) aqueous solutions over extended periods of time. This reference electrode is useful in many applications, particularly for monitoring the chemistry in nuclear and fossil power plants

The Temperature Condition of the Plate with Temperature-Dependent Thermal Conductivity and Energy Release

Directory of Open Access Journals (Sweden)

V. S. Zarubin

2016-01-01

Full Text Available The temperature state of a solid body, in addition to the conditions of its heat exchange with the environment, can greatly depend on the heat release (or heat absorption processes within the body volume. Among the possible causes of these processes should be noted such as a power release in the fuel elements of nuclear reactors, exothermic or endothermic chemical reactions in the solid body material, which respectively involve heat release or absorbtion, heat transfer of a part of the electric power in the current-carrying conductors (so-called Joule’s heat or the energy radiation penetrating into the body of a semitransparent material, etc. The volume power release characterizes an intensity of these processes.The extensive list of references to the theory of heat conductivity of solids offers solutions to problems to determine a stationary (steady over time and non-stationary temperature state of the solids (as a rule, of the canonical form, which act as the sources of volume power release. Thus, in general case, a possibility for changing power release according to the body volume and in solving the nonstationary problems also a possible dependence of this value on the time are taken into consideration.However, in real conditions the volume power release often also depends on the local temperature, and such dependence can be nonlinear. For example, with chemical reactions the intensity of heat release or absorption is in proportion to their rate, which, in turn, is sensitive to the temperature value, and a dependence on the temperature is exponential. A further factor that in such cases makes the analysis of the solid temperature state complicated, is dependence on the temperature and the thermal conductivity of this body material, especially when temperature distribution therein  is significantly non-uniform. Taking into account the influence of these factors requires the mathematical modeling methods, which allow us to build an adequate

High-temperature vitrification of Hanford residual-liquid waste in a continuous melter

International Nuclear Information System (INIS)

Barnes, S.M.

1980-04-01

Over 270 kg of high-temperature borosilicate glass have been produced in a series of three short-term tests in the High-Temperature Ceramic Melter vitrification system at PNL. The glass produced was formulated to vitrify simulated Hanford residual-liquid waste. The tests were designed to (1) demonstrate the feasibility of utilizing high-temperature, continuous-vitrification technology for the immobilization of the residual-liquid waste, (2) test the airlift draining technique utilized by the high-temperature melter, (3) compare glass produced in this process to residual-liquid glass produced under laboratory conditions, (4) investigate cesium volatility from the melter during waste processing, and (5) determine the maximum residual-liquid glass production rate in the high-temperature melter. The three tests with the residual-liquid composition confirmed the viability of the continuous-melting vitrification technique for the immobilization of this waste. The airlift draining technique was demonstrated in these tests and the glass produced from the melter was shown to be less porous than the laboratory-produced glass. The final glass produced from the second test was compared to a glass of the same composition produced under laboratory conditions. The comparative tests found the glasses to be indistinguishable, as the small differences in the test results fell within the precision range of the characterization testing equipment. The cesium volatility was examined in the final test. This examination showed that 0.44 wt % of the cesium (assumed to be cesium oxide) was volatilized, which translates to a volatilization rate of 115 mg/cm 2 -h

High-temperature reactor developments in the Netherlands

International Nuclear Information System (INIS)

Schram, R.P.C.; Cordfunke, E.H.P.; Heek, A.I. van

1996-01-01

The high-temperature reactor development in the Netherlands is embedded in the WHITE reactor program, in which several Dutch research institutes and engineering companies participate. The activities within the WHITE program are focused on the development of a small scale HTR for combined heat and power generation. In 1995, design choices for a pebble bed reactor were made at ECN. The first concept HTR will have a closed cycle helium turbine and a power level of 40 MWth. It is intended to make the market introduction of a commercially competitive HTR feasible. As a part of the HTR program at ECN, chemical aspects of HTR fuel and coated particles are studied. Experimental work on the oxidation resistance of coating materials and fission product attack on coating materials as well as thermochemical calculations of the fuel particles are done at ECN. The concept-HTR of ECN is fuelled with UO 2 , but the use of thorium is considered. The composition of the fuel determines the oxygen potential, which plays a key role in chemical safety of the fuel. Thermochemical calculations of the chemical form of cesium inside the HTR fuel particles were performed for a wide oxygen potential range. The chemical form of cesium determines the cesium pressure inside the fuel particle, which in turn determines the release behavior of Cs from defective particles. At normal operating temperatures and low oxygen potentials, the chemical form of cesium is C 60 Cs. It is known that cesium carbon compounds decompose above 650degC in vacuum. The stability of these compounds in the fuel particles at high temperatures(1000-1600degC) is questioned. Decomposition of these compounds may result in high cesium pressures even at normal operating conditions. Experimental work on the thermodynamic properties of cesium compounds at high temperatures is currently performed. (J.P.N.)

A Soft-Switching Inverter for High-Temperature Advanced Hybrid Electric Vehicle Traction Motor Drives

Energy Technology Data Exchange (ETDEWEB)

Lai, Jason [Virginia Polytechnic Inst. and State Univ. (Virginia Tech), Blacksburg, VA (United States); Yu, Wensong [Virginia Polytechnic Inst. and State Univ. (Virginia Tech), Blacksburg, VA (United States); Sun, Pengwei [Virginia Polytechnic Inst. and State Univ. (Virginia Tech), Blacksburg, VA (United States); Leslie, Scott [Powerex, Inc., Harrison, OH (United States); Prusia, Duane [Powerex, Inc., Harrison, OH (United States); Arnet, Beat [Azure Dynamics, Oak Park, MI (United States); Smith, Chris [Azure Dynamics, Oak Park, MI (United States); Cogan, Art [Azure Dynamics, Oak Park, MI (United States)

2012-03-31

The state-of-the-art hybrid electric vehicles (HEVs) require the inverter cooling system to have a separate loop to avoid power semiconductor junction over temperatures because the engine coolant temperature of 105°C does not allow for much temperature rise in silicon devices. The proposed work is to develop an advanced soft-switching inverter that will eliminate the device switching loss and cut down the power loss so that the inverter can operate at high-temperature conditions while operating at high switching frequencies with small current ripple in low inductance based permanent magnet motors. The proposed tasks also include high-temperature packaging and thermal modeling and simulation to ensure the packaged module can operate at the desired temperature. The developed module will be integrated with the motor and vehicle controller for dynamometer and in-vehicle testing to prove its superiority. This report will describe the detailed technical design of the soft-switching inverters and their test results. The experiments were conducted both in module level for the module conduction and switching characteristics and in inverter level for its efficiency under inductive and dynamometer load conditions. The performance will be compared with the DOE original specification.

Sandia_HighTemperatureComponentEvaluation_2015

Energy Technology Data Exchange (ETDEWEB)

Cashion, Avery T. [Sandia National Lab. (SNL-NM), Albuquerque, NM (United States)

2015-03-01

The objective of this project is to perform independent evaluation of high temperature components to determine their suitability for use in high temperature geothermal tools. Development of high temperature components has been increasing rapidly due to demand from the high temperature oil and gas exploration and aerospace industries. Many of these new components are at the late prototype or first production stage of development and could benefit from third party evaluation of functionality and lifetime at elevated temperatures. In addition to independent testing of new components, this project recognizes that there is a paucity of commercial-off-the-shelf COTS components rated for geothermal temperatures. As such, high-temperature circuit designers often must dedicate considerable time and resources to determine if a component exists that they may be able to knead performance out of to meet their requirements. This project aids tool developers by characterization of select COTS component performances beyond published temperature specifications. The process for selecting components includes public announcements of project intent (e.g., FedBizOps), direct discussions with candidate manufacturers,and coordination with other DOE funded programs.

High Temperature, High Power Piezoelectric Composite Transducers

Science.gov (United States)

Lee, Hyeong Jae; Zhang, Shujun; Bar-Cohen, Yoseph; Sherrit, StewarT.

2014-01-01

Piezoelectric composites are a class of functional materials consisting of piezoelectric active materials and non-piezoelectric passive polymers, mechanically attached together to form different connectivities. These composites have several advantages compared to conventional piezoelectric ceramics and polymers, including improved electromechanical properties, mechanical flexibility and the ability to tailor properties by using several different connectivity patterns. These advantages have led to the improvement of overall transducer performance, such as transducer sensitivity and bandwidth, resulting in rapid implementation of piezoelectric composites in medical imaging ultrasounds and other acoustic transducers. Recently, new piezoelectric composite transducers have been developed with optimized composite components that have improved thermal stability and mechanical quality factors, making them promising candidates for high temperature, high power transducer applications, such as therapeutic ultrasound, high power ultrasonic wirebonding, high temperature non-destructive testing, and downhole energy harvesting. This paper will present recent developments of piezoelectric composite technology for high temperature and high power applications. The concerns and limitations of using piezoelectric composites will also be discussed, and the expected future research directions will be outlined. PMID:25111242

High-temperature superconductivity

International Nuclear Information System (INIS)

Ginzburg, V.L.

1987-07-01

After a short account of the history of experimental studies on superconductivity, the microscopic theory of superconductivity, the calculation of the control temperature and its possible maximum value are presented. An explanation of the mechanism of superconductivity in recently discovered superconducting metal oxide ceramics and the perspectives for the realization of new high-temperature superconducting materials are discussed. 56 refs, 2 figs, 3 tabs

Pulse radiolysis study on temperature and pressure dependence of the yield of solvated electron in methanol from room temperature to supercritical condition

International Nuclear Information System (INIS)

Han, Zhenhui; He, Hui; Lin, Mingzhang; Muroya, Yusa; Katsumura, Yosuke

2012-09-01

A new concept of nuclear reactor, supercritical water-cooled reactor (SCWR), has been proposed, which is based on the success of the use of supercritical water (SCW) in fossil fuel power plants for more than three decades. This new concept reactor has advantages of higher thermal conversion efficiency, simplicity in structure, safety, etc, and it has been selected as one of the reactor concepts for the next generation nuclear reactor systems. In these reactors, the same as in boiling water reactors (BWR) and pressurized water reactors (PWR), water is used not only as a coolant but also as a moderator. It is very important to understand the behavior of the radiolysis products of water under the supercritical condition, since the water is exposed to a strong radiation field under very high temperature condition. Usually, in order to predict the concentrations of water decomposition products with carrying out some kinds of computer simulations, knowledge of the temperature and/or pressure dependent G-values (denoting the experimentally measured radiolytic yields) as well as of the rate constants of a set of reactions becomes very important. Therefore, in recent years, two groups from Argonne National Laboratory and The University of Tokyo, simultaneously conducted two projects aimed at obtaining basic data on radiolysis of SCW. However, it is still lack of reliable radiolytic yields of water decomposition products in very high temperature region. As we known, the properties of solvated electrons in polar liquid are very helpful for our understanding how they play a central role in many processes, such as solvation and reducing reactions. The solvated electron can also be used as a probe to determine the dynamic nature of the polar liquid systems. Comparing to water, the primary alcohols have much milder critical points, for example, for water and methanol, the critical temperature and pressure are 374 deg. C and 22.1 MPa and 239.5 deg. C and 8.1 MPa, respectively

High-temperature protective coatings for C/SiC composites

Directory of Open Access Journals (Sweden)

Xiang Yang

2014-12-01

Full Text Available Carbon fiber-reinforced silicon carbide (C/SiC composites were well-established light weight materials combining high specific strength and damage tolerance. For high-temperature applications, protective coatings had to provide oxidation and corrosion resistance. The literature data introduced various technologies and materials, which were suitable for the application of coatings. Coating procedures and conditions, materials design limitations related to the reactivity of the components of C/SiC composites, new approaches and coating systems to the selection of protective coatings materials were examined. The focus of future work was on optimization by further multilayer coating systems and the anti-oxidation ability of C/SiC composites at temperatures up to 2073 K or higher in water vapor.

Temperature control for high pressure processes up to 1400 MPa

International Nuclear Information System (INIS)

Reineke, K; Mathys, A; Knorr, D; Heinz, V

2008-01-01

Pressure- assisted sterilisation is an emerging technology. Hydrostatic high pressure can reduce the thermal load of the product and this allows quality retention in food products. To guarantee the safety of the sterilisation process it is necessary to investigate inactivation kinetics especially of bacterial spores. A significant roll during the inactivation of microorganisms under high pressure has the thermodynamic effect of the adiabatic heating. To analyse the individual effect of pressure and temperature on microorganism inactivation an exact temperature control of the sample to reach ideal adiabatic conditions and isothermal dwell times is necessary. Hence a heating/cooling block for a high pressure unit (Stansted Mini-Food-lab; high pressure capillary with 300 μL sample volume) was constructed. Without temperature control the sample would be cooled down during pressure built up, because of the non-adiabatic heating of the steel made vessel. The heating/cooling block allows an ideal adiabatic heat up and cooling of the pressure vessel during compression and decompression. The high pressure unit has a pressure build-up rate up to 250 MPa s -1 and a maximum pressure of 1400 MPa. Sebacate acid was chosen as pressure transmitting medium because it had no phase shift over the investigate pressure and temperature range. To eliminate the temperature difference between sample and vessel during compression and decompression phase, the mathematical model of the adiabatic heating/cooling of water and sebacate acid was implemented into a computational routine, written in Test Point. The calculated temperature is the setpoint of the PID controller for the heating/cooling block. This software allows an online measurement of the pressure and temperature in the vessel and the temperature at the outer wall of the vessel. The accurate temperature control, including the model of the adiabatic heating opens up the possibility to realise an ideal adiabatic heating and cooling

Structure of maraging steel after thermomechanical treatment at high temperature

International Nuclear Information System (INIS)

Prokoshkina, V.G.; Kaputkina, L.M.; Mozzhukhin, V.E.

1981-01-01

Developed polygonized substructure is formed in austenite of maraging Cr-Ni steels under the selected conditions of hot deformation during high temperature mechanical treatment (HTMT). Substructure of hot deformed austenite is inherited by packet martensite during cooling. Presence of developed polygonized substructure in austenite results in grinding and high uniformity of packet sizes of martensite crystals. Substructure of α-phase of the investigated steels after HTMT, as well as the one inherited from hot deformed austenite, is inherited at α→γ-transformation in the process of repetitive austenization, and it can be preserved within a limited temperature-time range of heating in γ-region [ru

Numerical simulations on a high-temperature particle moving in coolant

International Nuclear Information System (INIS)

Li Xiaoyan; Shang Zhi; Xu Jijun

2006-01-01

This study considers the coupling effect between film boiling heat transfer and evaporation drag around a hot-particle in cold liquid. Taking momentum and energy equations of the vapor film into account, a transient single particle model under FCI conditions has been established. The numerical simulations on a high-temperature particle moving in coolant have been performed using Gear algorithm. Adaptive dynamic boundary method is adopted during simulating to matching the dynamic boundary that is caused by vapor film changing. Based on the method presented above, the transient process of high-temperature particles moving in coolant can be simulated. The experimental results prove the validity of the HPMC model. (authors)

Heightened fire probability in Indonesia in non-drought conditions: the effect of increasing temperatures

Science.gov (United States)

Fernandes, Kátia; Verchot, Louis; Baethgen, Walter; Gutierrez-Velez, Victor; Pinedo-Vasquez, Miguel; Martius, Christopher

2017-05-01

In Indonesia, drought driven fires occur typically during the warm phase of the El Niño Southern Oscillation. This was the case of the events of 1997 and 2015 that resulted in months-long hazardous atmospheric pollution levels in Equatorial Asia and record greenhouse gas emissions. Nonetheless, anomalously active fire seasons have also been observed in non-drought years. In this work, we investigated the impact of temperature on fires and found that when the July-October (JASO) period is anomalously dry, the sensitivity of fires to temperature is modest. In contrast, under normal-to-wet conditions, fire probability increases sharply when JASO is anomalously warm. This describes a regime in which an active fire season is not limited to drought years. Greater susceptibility to fires in response to a warmer environment finds support in the high evapotranspiration rates observed in normal-to-wet and warm conditions in Indonesia. We also find that fire probability in wet JASOs would be considerably less sensitive to temperature were not for the added effect of recent positive trends. Near-term regional climate projections reveal that, despite negligible changes in precipitation, a continuing warming trend will heighten fire probability over the next few decades especially in non-drought years. Mild fire seasons currently observed in association with wet conditions and cool temperatures will become rare events in Indonesia.

Extreme implanting in Si: A study of ion-induced damage at high temperature and high dose

International Nuclear Information System (INIS)

Holland, O.W.

1994-01-01

Ion-solid interactions near room temperature and below have been well studied in single-crystal Si. While this has led to a better understanding of the mechanisms responsible for nucleation and growth of lattice damage during irradiation, these studies have not, in general, been extended to high temperatures (e.g., >200 degrees C). This is the case despite the commercialization of ion beam technologies which utilize high-temperature processing, such as separation by implantation of oxygen (SIMOX). In this process, a silicon-on-insulator (SOI) material is produced by implanting a high dose of oxygen ions into a Si wafer to form a buried, stoichiometric oxide layer. Results will be presented of a study of damage accumulation during high-dose implantation of Si at elevated temperatures. In particular, O + -ions were used because of the potential impact of the results on the SIMOX technology. It will be shown that the nature of the damage accumulation at elevated temperatures is quite distinctive and portends the presence of a new mechanism, one which is only dominant under the extreme conditions encountered during ion beam synthesis (i.e., high temperature and high dose). This mechanism is discussed and shown to be quite general and not dependent on the chemical identity of the ions. Also, techniques for suppressing this mechanism by open-quotes defect engineeringclose quotes are discussed. Such techniques are technologically relevant because they offer the possibility of reducing the defect density of the SOI produced by SIMOX

High-temperature peridotites - lithospheric or asthenospheric?

International Nuclear Information System (INIS)

Hops, J.J.; Gurney, J.J.

1990-01-01

High-temperature peridotites by definition yield equilibration temperatures greater than 1100 degrees C. On the basis of temperature and pressure calculations, these high-temperature peridotites are amongst the deepest samples entrained by kimberlites on route to the surface. Conflicting models proposing either a lithospheric or asthenospheric origin for the high-temperature peridotites have been suggested. A detailed study of these xenoliths from a single locality, the Jagersfontein kimberlite in the Orange Free State, has been completed as a means of resolving this controversy. 10 refs., 2 figs

Diffraction studies of order-disorder at high pressures and temperatures

International Nuclear Information System (INIS)

Parise, John B.; Antao, Sytle M.; Martin, Charles D.; Crichton, Wilson

2005-01-01

Recent developments at synchrotron X-ray beamlines now allow collection of data suitable for structure determination and Rietveld structure refinement at high pressures and temperatures on challenging materials. These include materials, such as dolomite (CaMg(CO 3 ) 2 ) that tends to calcine at high temperatures, and Fe-containing materials, such as the spinel MgFe 2 O 4 , which tend to undergo changes in oxidation state. Careful consideration of encapsulation along with the use of radial collimation produced powder diffraction patterns virtually free of parasitic scattering from the cell in the case of large volume high-pressure experiments. These features have been used to study a number of phase transitions, especially those where superior signal-to-noise discrimination is required to distinguish weak ordering reflections. The structures adopted by dolomite, and CaSO4, anhydrite, were determined from 298 to 1466 K at high pressures. Using laser-heated diamond-anvil cells to achieve simultaneous high pressure and temperature conditions, we have observed CaSO 4 undergo phase transitions to the monazite type and at highest pressure and temperature to crystallize in the barite-type structure. On cooling, the barite structure distorts, from an orthorhombic to a monoclinic lattice, to produce the AgMnO 4 -type structure.

High temperature measurement by noise thermometry

International Nuclear Information System (INIS)

Decreton, M.C.

1982-06-01

Noise thermometry has received a lot of attention for measurements of temperatures in the high range around 1000-2000 deg. K. For these measurements, laboratory type experiments have been mostly performed. These have shown the interest of the technique when long term stability, high precision and insensibility to external conditions are concerned. This is particularly true for measurements in nuclear reactors where important drifts due to irradiation effects are experienced with other measurement techniques, as thermocouple for instance. Industrial noise thermometer experiments have not been performed extensively up to now. The subject of the present study is the development of a 1800 deg. K noise thermometer for nuclear applications. The measurement method is based on a generalized noise power approach. The rms noise voltage (Vsub(s)) and noise current (Isub(s)) are successively measured on the resistive sensor. The same quantities are also measured on a dummy short circuited probe (Vsub(d) and Isub(d)). The temperature is then deduced from these measured values by the following formula: cTsub(s) = (Vsub(s) 2 - Vsub(d) 2 )(Vsub(s)/Isub(s) - Vsub(d)/Isub(d)) - 1 , where c is a constant and Tsub(s) the absolute temperature of the sensor. This approach has the particular advantage of greatly reducing the sensibility to environmental perturbations on the leads and to the influence of amplifier noise sources. It also eliminates the necessity of resistance measurement and keeps the electronic circuits as simple as possible

High-capacity NO2 denuder systems operated at various temperatures (298-473 K).

Science.gov (United States)

Wolf, Jan-Christoph; Niessner, Reinhard

2012-12-01

In this study, we investigated several coatings for high-temperature, high-capacity, and high-efficiency denuder-based NO(2) removal, with the scope to face the harsh conditions and requirements of automotive exhaust gas sampling. As first coating, we propose a potassium iodide (KI)/polyethylene glycol coating with a high removal efficiency (ε > 98%) for about 2 h and 50 ppm NO(2) at room temperature (298 K). At elevated temperatures (423 K), the initial capacity (100 ppmh) is decreased to 15 ppmh. Furthermore, this is the first proposal of the ionic liquid methyl-butyl-imidazolium iodide ([BMIm(+)][I(-)]) as denuder coating material. At room temperature, this ionic liquid exhibits far greater capacity (300 ppmh) and NO(2) removal efficiency (ε > 99.9%) than KI. Nevertheless, KI exhibits a slightly (~10%) higher capacity at elevated temperatures than [BMIm(+)][I(-)]. Both coatings presented are suitable for applications requiring selective denuding of NO(2) at temperatures up to 423 K.

Development and Performance Verification of Fiber Optic Temperature Sensors in High Temperature Engine Environments

Science.gov (United States)

Adamovsky, Grigory; Mackey, Jeffrey R.; Kren, Lawrence A.; Floyd, Bertram M.; Elam, Kristie A.; Martinez, Martel

2014-01-01

A High Temperature Fiber Optic Sensor (HTFOS) has been developed at NASA Glenn Research Center for aircraft engine applications. After fabrication and preliminary in-house performance evaluation, the HTFOS was tested in an engine environment at NASA Armstrong Flight Research Center. The engine tests enabled the performance of the HTFOS in real engine environments to be evaluated along with the ability of the sensor to respond to changes in the engine's operating condition. Data were collected prior, during, and after each test in order to observe the change in temperature from ambient to each of the various test point levels. An adequate amount of data was collected and analyzed to satisfy the research team that HTFOS operates properly while the engine was running. Temperature measurements made by HTFOS while the engine was running agreed with those anticipated.

Amorphous intergranular films in silicon nitride ceramics quenched from high temperatures

International Nuclear Information System (INIS)

Cinibulk, M.K.; Kleebe, H.; Schneider, G.A.; Ruehle, M.

1993-01-01

High-temperature microstructure of an MgO-hot-pressed Si 3 N 4 and a Yb 2 O 3 + Al 2 O 3 -sintered/annealed Si 3 N 4 were obtained by quenching thin specimens from temperatures between 1,350 and 1,550 C. Quenching materials from 1,350 C produced no observable exchanges in the secondary phases at triple-grain junctions or along grain boundaries. Although quenching from temperatures of ∼1,450 C also showed no significant changes in the general microstructure or morphology of the Si 3 N 4 grains, the amorphous intergranular film thickness increased substantially from an initial ∼1 nm in the slowly cooled material to 1.5--9 nm in the quenched materials. The variability of film thickness in a given material suggests a nonequilibrium state. Specimens quenched from 1,550 C revealed once again thin (1-nm) intergranular films at all high-angle grain boundaries, indicating an equilibrium condition. The changes observed in intergranular-film thickness by high-resolution electron microscopy can be related to the eutectic temperature of the system and to diffusional and viscous processes occurring in the amorphous intergranular film during the high-temperature anneal prior to quenching

Densification of Highly Defective Ceria by High Temperature Controlled Re-Oxidation

DEFF Research Database (Denmark)

Ni, De Wei; Glasscock, Julie; Pons, Aénor

2014-01-01

Highly enhanced densification and grain growth of Ce0.9Gd0.1O1.95-δ (CGO, gadolinium-doped ceria, with 10 mol% Gd) is achieved in low oxygen activity atmospheres. However, the material can suffer mechanical failures during cooling when the re-oxidation process is not controlled due to the large...... volume changes. In this work, the redox process of CGO is investigated using dilatometry, microscopy, electrochemical impedance spectroscopy and thermodynamic analysis. In addition, the conditions allowing controlled re-oxidation and cooling in order to preserve the mechanical integrity of the CGO...... component are defined: this can be achieved over a wide temperature range (800−1200◦C) by gradually increasing the oxygen content of the atmosphere. It is found that the electrical conductivity of the CGO, particularly at low temperature (oxidation...

The grapevine VviPrx31 peroxidase as a candidate gene involved in anthocyanin degradation in ripening berries under high temperature.

Science.gov (United States)

Movahed, Nooshin; Pastore, Chiara; Cellini, Antonio; Allegro, Gianluca; Valentini, Gabriele; Zenoni, Sara; Cavallini, Erika; D'Incà, Erica; Tornielli, Giovanni Battista; Filippetti, Ilaria

2016-05-01

Anthocyanin levels decline in some red grape berry varieties ripened under high-temperature conditions, but the underlying mechanism is not yet clear. Here we studied the effects of two different temperature regimes, representing actual Sangiovese (Vitis vinifera L.) viticulture regions, on the accumulation of mRNAs and enzymes controlling berry skin anthocyanins. Potted uniform plants of Sangiovese were kept from veraison to harvest, in two plastic greenhouses with different temperature conditions. The low temperature (LT) conditions featured average and maximum daily air temperatures of 20 and 29 °C, respectively, whereas the corresponding high temperature (HT) conditions were 22 and 36 °C, respectively. The anthocyanin concentration at harvest was much lower in HT berries than LT berries although their profile was similar under both conditions. Under HT conditions, the biosynthesis of anthocyanins was suppressed at both the transcriptional and enzymatic levels, but peroxidase activity was higher. This suggests that the low anthocyanin content of HT berries reflects the combined impact of reduced biosynthesis and increased degradation, particularly the direct role of peroxidases in anthocyanin catabolism. Overexpression of VviPrx31 decreased anthocyanin contents in Petunia hybrida petals under heat stress condition. These data suggest that high temperature can stimulate peroxidase activity thus anthocyanin degradation in ripening grape berries.

Effect of Groove Surface Texture on Tribological Characteristics and Energy Consumption under High Temperature Friction.

Science.gov (United States)

Wu, Wei; Chen, Guiming; Fan, Boxuan; Liu, Jianyou

2016-01-01

Energy consumption and tribological properties could be improved by proper design of surface texture in friction. However, some literature focused on investigating their performance under high temperature. In the study, different groove surface textures were fabricated on steels by a laser machine, and their tribological behaviors were experimentally studied with the employment of the friction and wear tester under distinct high temperature and other working conditions. The friction coefficient was recorded, and wear performance were characterized by double light interference microscope, scanning electron microscope (SEM) and x-ray energy dispersive spectrometry (EDS). Then, the performances of energy consumptions were carefully estimated. Results showed that friction coefficient, wear, and energy consumption could almost all be reduced by most textures under high temperature conditions, but to a different extent which depends on the experimental conditions and texture parameters. The main improvement mechanisms were analyzed, such as the hardness change, wear debris storage, thermal stress release and friction induced temperature reduction by the textures. Finally, a scattergram of the relatively reduced ratio of the energy consumption was drawn for different surface textures under four distinctive experimental conditions to illustrate the comprehensive energy consumption improving ability of textures, which was of benefit for the application of texture design.

Study on a Novel Gelled Foam for Conformance Control in High Temperature and High Salinity Reservoirs

Directory of Open Access Journals (Sweden)

Tong Li

2018-05-01

Full Text Available A novel gelled foam for conformance control was investigated for its ability to enhance oil recovery (EOR in high temperature and high salinity reservoirs. The formulation optimization, foaming performance, and core flooding performance of the gelled foam were systematically evaluated under harsh reservoir conditions. The gelled foam formulation was optimized with 0.4% polymer (hydrolyzed polyacrylamide; HPAM, 0.06% cross-linker (phenolic and 0.2% foaming agent (sulphobetaine; SB. The addition of the gel improved the stability of the foam system by 3.8 times that of traditional foam. A stabilization mechanism in the gelled foam was proposed to describe the stabilization process of the foam film. The uniformly distributed three-dimensional network structure of the gel provided a thick protective layer for the foam system that maintained the stability of the foam and improved the strength and thickness of the liquid film. The gelled foam exhibited good formation adaptability, profile control, and EOR performance. The foam flowed into the high permeability layer, plugged the dominant channel, and increased the swept volume. Oil recovery was enhanced by 29.4% under harsh high -temperature and high salinity conditions.

THE BEHAVIOR OF SOLUBLE METALS ELUTED FROM Ni/Fe-BASED ALLOY REACTORS AFTER HIGH-TEMPERATURE AND HIGH-PRESSURE WATER PROCESS

Directory of Open Access Journals (Sweden)

M. Faisal

2012-05-01

Full Text Available The behavior of heavy metals eluted from the wall of Ni/Fe-based alloy reactors after high-temperature and high-pressure water reaction were studied at temperatures ranging from 250 to 400oC. For this purpose, water and cysteic acid were heated in two reactor materials which are SUS 316 and Inconel 625. Under the tested conditions, the erratic behaviors of soluble metals eluted from the wall of Ni/Fe-based alloy in high temperature water were observed. Results showed that metals could be eluted even at a short contact time. The presence of air also promotes elution at sub-critical conditions. At sub-critical conditions, a significant amount of Cr was extracted from SUS 316, while only traces of Ni, Fe, Mo and Mn were eluted. In contrast, Ni was removed in significant amounts compared to Cr when Inconel 625 was tested. It was observed that eluted metals tend to increased under acidic conditions and most of those metals were over the limit of WHO guideline for drinking water. The results are significant both on the viewpoint of environmental regulation on disposal of wastes containing heavy metals, toxicity of resulting product and catalytic effect on a particular reaction.

Advanced High Temperature Structural Seals

Science.gov (United States)

Newquist, Charles W.; Verzemnieks, Juris; Keller, Peter C.; Rorabaugh, Michael; Shorey, Mark

2002-10-01

This program addresses the development of high temperature structural seals for control surfaces for a new generation of small reusable launch vehicles. Successful development will contribute significantly to the mission goal of reducing launch cost for small, 200 to 300 pound payloads. Development of high temperature seals is mission enabling. For instance, ineffective control surface seals can result in high temperature (3100 F) flows in the elevon area exceeding structural material limits. Longer sealing life will allow use for many missions before replacement, contributing to the reduction of hardware, operation and launch costs.

High temperature materials; Materiaux a hautes temperatures

Energy Technology Data Exchange (ETDEWEB)

NONE

2003-07-01

The aim of this workshop is to share the needs of high temperature and nuclear fuel materials for future nuclear systems, to take stock of the status of researches in this domain and to propose some cooperation works between the different research organisations. The future nuclear systems are the very high temperature (850 to 1200 deg. C) gas cooled reactors (GCR) and the molten salt reactors (MSR). These systems include not only the reactor but also the fabrication and reprocessing of the spent fuel. This document brings together the transparencies of 13 communications among the 25 given at the workshop: 1) characteristics and needs of future systems: specifications, materials and fuel needs for fast spectrum GCR and very high temperature GCR; 2) high temperature materials out of neutron flux: thermal barriers: materials, resistance, lifetimes; nickel-base metal alloys: status of knowledge, mechanical behaviour, possible applications; corrosion linked with the gas coolant: knowledge and problems to be solved; super-alloys for turbines: alloys for blades and discs; corrosion linked with MSR: knowledge and problems to be solved; 3) materials for reactor core structure: nuclear graphite and carbon; fuel assembly structure materials of the GCR with fast neutron spectrum: status of knowledge and ceramics and cermets needs; silicon carbide as fuel confinement material, study of irradiation induced defects; migration of fission products, I and Cs in SiC; 4) materials for hydrogen production: status of the knowledge and needs for the thermochemical cycle; 5) technologies: GCR components and the associated material needs: compact exchangers, pumps, turbines; MSR components: valves, exchangers, pumps. (J.S.)

Scale hierarchy in high-temperature QCD

CERN Document Server

Akerlund, Oscar

2013-01-01

Because of asymptotic freedom, QCD becomes weakly interacting at high temperature: this is the reason for the transition to a deconfined phase in Yang-Mills theory at temperature $T_c$. At high temperature $T \\gg T_c$, the smallness of the running coupling $g$ induces a hierachy betwen the "hard", "soft" and "ultrasoft" energy scales $T$, $g T$ and $g^2 T$. This hierarchy allows for a very successful effective treatment where the "hard" and the "soft" modes are successively integrated out. However, it is not clear how high a temperature is necessary to achieve such a scale hierarchy. By numerical simulations, we show that the required temperatures are extremely high. Thus, the quantitative success of the effective theory down to temperatures of a few $T_c$ appears surprising a posteriori.

Advances in high temperature chemistry 1

CERN Document Server

Eyring, Leroy

2013-01-01

Advances in High Temperature Chemistry, Volume 1 describes the complexities and special and changing characteristics of high temperature chemistry. After providing a brief definition of high temperature chemistry, this nine-chapter book goes on describing the experiments and calculations of diatomic transition metal molecules, as well as the advances in applied wave mechanics that may contribute to an understanding of the bonding, structure, and spectra of the molecules of high temperature interest. The next chapter provides a summary of gaseous ternary compounds of the alkali metals used in

Design and safety consideration in the High-Temperature Engineering Test Reactor (HTTR)

International Nuclear Information System (INIS)

Saito, Shinzo; Tanaka, Toshiuki; Sudo, Yukio; Baba, Osamu; Shiozawa, Shusaku; Okubo, Minoru

1990-01-01

The budget for construction of the High-Temperature Engineering Test Reactor (HTTR) was recently committed by the Government in Japan. The HTTR is a test reactor with thermal output of 30 MW and reactor outlet coolant temperature of 950 deg. C at high temperature test operation. The HTTR plant uses a pin-in-block design core and will be used as an experience leading to high temperature applications. Several major important safety considerations are adopted in the design of the HTTR. These are as follows: 1) A coated particle fuel must not be failed during a normal reactor operation and an anticipated operational occurrence; 2) Two independent and diverse reactor shut-down systems are provided in order to shut down the reactor safely and reliably in any condition; 3) Back-up reactor cooling systems which are safety ones are provided in order to remove residual heat of reactor in any condition; 4) Multiple barriers and countermeasures are provided to contain fission products such as a containment, pressure gradient between the primary and secondary cooling circuit and so on, though coated particle fuels contain fission products with high reliability; 5) The functions of materials used in the primary cooling circuit are separated to be pressure-resisting and heat-resisting in order to resolve material problems and maintain high reliability. The detailed design of the HTTR was completed with extensive accumulation of material data and component tests. (author)

The development of an adsorbent for corrosion products in high-temperature water

International Nuclear Information System (INIS)

Kim, Yong Ik; Sung, Ki Woung; Kim, Kwang Rag; Kim, Yu Hwan; Koo, Jae Hyoo

1996-08-01

In order to use as adsorbent for removal of the soluble corrosion products, mainly Co 60 under PWR reactor coolant conditions (300 deg C, 160 kg/cm 2 ), stable ZrO 2 adsorbent was prepared using sol-gel process from zirconyl nitrate, AlO adsorbent was prepared by hydrolysis of aluminum isopropoxide, and titanium tetraisopropoxide, respectively. The prepared adsorbents were calcined at various temperature and analyzed by physical properties and the Co 2+ adsorption capacity. And it was shown that the Co 2+ adsorption capacity of the TiO 2 -Al 2 O 3 adsorbents were found to have larger than that of ZrO 2 and Al 2 O 3 adsorbents in high-temperature water. ZrO 2 , Al 2 O 3 and TiO 2 -Al 2 O 3 adsorbents were found to be suitable high-temperature adsorbents for the removal of dissolved corrosion products, mainly Co in PWR reactor coolant conditions. 15 tabs., 51 figs., 55 refs. (Author)

A Shear Horizontal Waveguide Technique for Monitoring of High Temperature Pipe Thinning

International Nuclear Information System (INIS)

Cheong, Yongmoo; Kim, Hongpyo; Lee, Duckhyun

2014-01-01

An ultrasonic thickness measurement method is a well-known and most commonly used non-destructive testing technique for wall thickness monitoring of a piping or plate. However, current commonly available ultrasonic transducers cannot withstand high temperatures of, above 200 .deg. C. Currently, the variation of wall thickness of the pipes is determined by a portable ultrasonic gauge during plant shutdowns. This manual ultrasonic method reveals several disadvantages: inspections have to be performed during shutdowns with the possible consequences of prolonging down time and increasing production losses, insulation has to be removed and replaced for each manual measurement, and scaffolding has to be installed to inaccessible areas, resulting in considerable cost for intervention. In addition, differences of the measurement conditions such as examiner, temperature, and couplant could result in measurement errors. It has been suggested that a structural health monitoring approach with permanently installed ultrasonic thickness gauges could have substantial benefits over current practices. In order to solve those fundamental problems occurring during the propagation of ultrasound at high temperature, a shear horizontal waveguide technique for wall thickness monitoring at high temperatures is developed. A dry clamping device without a couplant for the acoustic contact between waveguide and pipe surface was designed and fabricated. The shear horizontal waveguides and clamping device result in an excellent S/N ratio and high accuracy of measurement with long exposure in an elevated temperature condition. A computer program for on-line monitoring of the pipe thickness at high temperature for a long period of time was developed. The system can be applied to monitor the FAC in carbon steel piping in a nuclear power plant after a verification test for a long period of time

Deep Trek High Temperature Electronics Project

Energy Technology Data Exchange (ETDEWEB)

Bruce Ohme

2007-07-31

This report summarizes technical progress achieved during the cooperative research agreement between Honeywell and U.S. Department of Energy to develop high-temperature electronics. Objects of this development included Silicon-on-Insulator (SOI) wafer process development for high temperature, supporting design tools and libraries, and high temperature integrated circuit component development including FPGA, EEPROM, high-resolution A-to-D converter, and a precision amplifier.

Evaluation of creep-fatigue strength of P122 high temperature boiler material

International Nuclear Information System (INIS)

Pumwa, John

2003-01-01

In components, which operate at high temperatures, changes in conditions at the beginning and end of operation or during operation result in transient temperature gradients. If these transients are repeated, the differential thermal expansion during each transient may result in thermally induced cyclic stresses. The extent of the resulting fatigue damage depends on the nature and frequency of the transient, the thermal gradient in the component, and the material properties. Components, which are subjected to thermally induced stresses generally, operate within the creep range so that damage due to both fatigue and creep has to be taken into account. In order to select the correct materials for these hostile operating environmental conditions, it is vitally important to understand the behaviour of mechanical properties such as creep-fatigue properties of these materials. This paper reports the results of standard creep-fatigue tests conducted using P122 (HCM12A or 12Cr-1.8W-1.5Cu) high temperature boiler material. P122 is one of the latest developed materials for high temperature environments, which has the potential to be successful in such hostile operation environments. The tests were conducted at temperatures ranging from 550degC to 700degC at 50degC intervals with strain ranges of ±1.5 to ±3.0% at 0.5% intervals and a strain rate of 4 x 10 -3 s -1 with an application of 10-minute tensile hold time using a closed-loop hydraulic Instron material testing machine with a servo hydraulic controller. The results confirm that P122 is comparable to conventional high temperature steels. (author)

High Temperatures Health Monitoring of the Condensed Water Height in Steam Pipe Systems

Science.gov (United States)

Lih, Shyh-Shiuh; Bar-Cohen, Yoseph; Lee, Hyeong Jae; Badescu, Mircea; Bao, Xiaoqi; Sherrit, Stewart; Takano, Nobuyuki; Ostlund, Patrick; Blosiu, Julian

2013-01-01

Ultrasonic probes were designed, fabricated and tested for high temperature health monitoring system. The goal of this work was to develop the health monitoring system that can determine the height level of the condensed water through the pipe wall at high temperature up to 250 deg while accounting for the effects of surface perturbation. Among different ultrasonic probe designs, 2.25 MHz probes with air backed configuration provide satisfactory results in terms of sensitivity, receiving reflections from the target through the pipe wall. A series of tests were performed using the air-backed probes under irregular conditions, such as surface perturbation and surface disturbance at elevated temperature, to qualify the developed ultrasonic system. The results demonstrate that the fabricated air-backed probes combined with advanced signal processing techniques offer the capability of health monitoring of steam pipe under various operating conditions.

Statistical modeling of urban air temperature distributions under different synoptic conditions

Science.gov (United States)

Beck, Christoph; Breitner, Susanne; Cyrys, Josef; Hald, Cornelius; Hartz, Uwe; Jacobeit, Jucundus; Richter, Katja; Schneider, Alexandra; Wolf, Kathrin

2015-04-01

Within urban areas air temperature may vary distinctly between different locations. These intra-urban air temperature variations partly reach magnitudes that are relevant with respect to human thermal comfort. Therefore and furthermore taking into account potential interrelations with other health related environmental factors (e.g. air quality) it is important to estimate spatial patterns of intra-urban air temperature distributions that may be incorporated into urban planning processes. In this contribution we present an approach to estimate spatial temperature distributions in the urban area of Augsburg (Germany) by means of statistical modeling. At 36 locations in the urban area of Augsburg air temperatures are measured with high temporal resolution (4 min.) since December 2012. These 36 locations represent different typical urban land use characteristics in terms of varying percentage coverages of different land cover categories (e.g. impervious, built-up, vegetated). Percentage coverages of these land cover categories have been extracted from different sources (Open Street Map, European Urban Atlas, Urban Morphological Zones) for regular grids of varying size (50, 100, 200 meter horizonal resolution) for the urban area of Augsburg. It is well known from numerous studies that land use characteristics have a distinct influence on air temperature and as well other climatic variables at a certain location. Therefore air temperatures at the 36 locations are modeled utilizing land use characteristics (percentage coverages of land cover categories) as predictor variables in Stepwise Multiple Regression models and in Random Forest based model approaches. After model evaluation via cross-validation appropriate statistical models are applied to gridded land use data to derive spatial urban air temperature distributions. Varying models are tested and applied for different seasons and times of the day and also for different synoptic conditions (e.g. clear and calm

High-temperature oxidation of Zircaloy in hydrogen-steam mixtures

International Nuclear Information System (INIS)

Chung, H.M.; Thomas, G.R.

1982-09-01

Oxidation rates of Zircaloy-4 cladding tubes have been measured in hydrogen-steam mixtures at 1200 to 1700 0 C. For a given isothermal oxidation temperature, the oxide layer thicknesses have been measured as a function of time, steam supply rate, and hydrogen overpressure. The oxidation rates in the mixtures were compared with similar data obtained in pure steam and helium-steam environments under otherwise identical conditions. The rates in pure steam and helium-steam mixtures were equivalent and comparable to the parabolic rates obtained under steam-saturated conditions and reported in the literature. However, when the helium was replaced with hydrogen of equivalent partial pressure, a significantly smaller oxidation rate was observed. For high steam-supply rates, the oxidation kinetics in a hydrogen-steam mixture were parabolic, but the rate was smaller than for pure steam or helium-steam mixtures. Under otherwise identical conditions, the ratio of the parabolic rate for hydrogen-steam to that for pure steam decreased with increasing temperature and decreasing steam-supply rate

Durability of bends in high-temperature steam lines under the conditions of long-term operation

Science.gov (United States)

Katanakha, N. A.; Semenov, A. S.; Getsov, L. B.

2015-04-01

The article presents the results of stress-strain state computations and durability of bent and steeply curved branches of high-temperature steam lines carried out on the basis of the finite element method using the modified Soderberg formula for describing unsteady creep processes with taking the accumulation of damage into account. The computations were carried out for bends made of steel grades that are most widely used for manufacturing steam lines (12Kh1MF, 15Kh1M1F, and 10Kh9MFB) and operating at different levels of inner pressure and temperature. The solutions obtained using the developed creep model are compared with those obtained using the models widely used in practice.

Sensory profiling of Dalmatian dry-cured ham under different temperature conditions

Directory of Open Access Journals (Sweden)

Zlatko Janječić

2010-01-01

Full Text Available To investigate the influence of the Dalmatian ham processing conditions on weight loss and sensory characteristics, 20 hams were processed following different temperature conditions during salting and ripening. For that purpose, hams were evaluated using quantitative descriptive analysis. The weight loss was higher and all sensory traits except presence of tyrosine and phenylalanine crystals were higher rated for hams processed at higher temperatures. The most significant (P<0.0001 influence of temperature was established on subcutaneous fat color, muscle color and presence of tyrosine and phenylalanine, whereas no influence was established on appearance, marbling, flavor and melting. This concludes that there is overall significant effect of higher temperature on sensory characteristics most likely due to the more intense proteolysis and lipolysis.

Technological improvements to high temperature thermocouples for nuclear reactor applications

International Nuclear Information System (INIS)

Schley, R.; Leveque, J.P.

1980-07-01

The specific operating conditions of thermocouples in nuclear reactors have provided an incentive for further advances in high temperature thermocouple applications and performance. This work covers the manufacture and improvement of existing alloys, the technology of clad thermocouples, calibration drift during heat treatment, resistance to thermal shock and the compatibility of insulating materials with thermo-electric alloys. The results lead to specifying improved operating conditions for thermocouples in nuclear reactor media (pressurized water, sodium, uranium oxide) [fr

High temperature thermometric phosphors

Science.gov (United States)

Allison, Stephen W.; Cates, Michael R.; Boatner, Lynn A.; Gillies, George T.

1999-03-23

A high temperature phosphor consists essentially of a material having the general formula LuPO.sub.4 :Dy.sub.(x),Eu.sub.y) wherein: 0.1 wt %.ltoreq.x.ltoreq.20 wt % and 0.1 wt %.ltoreq.y.ltoreq.20 wt %. The high temperature phosphor is in contact with an article whose temperature is to be determined. The article having the phosphor in contact with it is placed in the environment for which the temperature of the article is to be determined. The phosphor is excited by a laser causing the phosphor to fluoresce. The emission from the phosphor is optically focused into a beam-splitting mirror which separates the emission into two separate emissions, the emission caused by the dysprosium dopant and the emission caused by the europium dopent. The separated emissions are optically filtered and the intensities of the emission are detected and measured. The ratio of the intensity of each emission is determined and the temperature of the article is calculated from the ratio of the intensities of the separate emissions.

A high-temperature fiber sensor using a low cost interrogation scheme.

Science.gov (United States)

Barrera, David; Sales, Salvador

2013-09-04

Regenerated Fibre Bragg Gratings have the potential for high-temperature monitoring. In this paper, the inscription of Fibre Bragg Gratings (FBGs) and the later regeneration process to obtain Regenerated Fiber Bragg Gratings (RFBGs) in high-birefringence optical fiber is reported. The obtained RFBGs show two Bragg resonances corresponding to the slow and fast axis that are characterized in temperature terms. As the temperature increases the separation between the two Bragg resonances is reduced, which can be used for low cost interrogation. The proposed interrogation setup is based in the use of optical filters in order to convert the wavelength shift of each of the Bragg resonances into optical power changes. The design of the optical filters is also studied in this article. In first place, the ideal filter is calculated using a recursive method and defining the boundary conditions. This ideal filter linearizes the output of the interrogation setup but is limited by the large wavelength shift of the RFBG with temperature and the maximum attenuation. The response of modal interferometers as optical filters is also analyzed. They can be easily tuned shifting the optical spectrum. The output of the proposed interrogation scheme is simulated in these conditions improving the sensitivity.

New alloys for high temperature applications in incineration plants

International Nuclear Information System (INIS)

Martinz, H.P.; Koeck, W.

1993-01-01

The hot components of incineration plants exposed to temperatures between 800 and 1,200 C like boilers, grates, thermocouple sheaths and nozzles suffer from severe joint slag and hot gas attack. Considering corrosion resistance only, ceramic materials show excellent performance under these conditions. But because of the ceramics' brittleness metallic materials exhibit an overall advantage although being corroded faster. Within the class of suitable metals PM-ODS (oxide dispersion strengthened)-superalloys based on iron or nickel and PM-Cr-base-alloys are among the most promising ones. This can be derived from various laboratory and field tests which were performed up to now. Laboratory oxidation tests indicate that these new alloys can be used at temperatures up to 1,300 C in hot air. High temperature erosion tests with quartz particles show that PM 2,000 (Fe 19,5Cr5,5Al0,5Ti0,5Y 2 O 3 ) and Ducropur (99.7% Cr) have almost the same resistance against particle impact as alumina or zirconia at 900 C. The corresponding laboratory and field tests under typical joint slag and hot gas conditions at temperatures up to 1,200 C show good results for PM 2,000 and already lead to the actual application of boiler components. Extensive testing has been performed in the field of municipal waste incineration. Depending on temperature, slag and hot gas composition selected grades of the PM-ODS and Cr-base-alloy-group give satisfactory results in the field tests. In the pulp industry black liquor, an alkaline solution with high concentrations of organic waste, is incinerated for the recovery of caustic soda. Flame sprayed coatings of Ducrolloy Cr50Ni give a sixfold increase of the lifetime of the burner nozzles compared to unprotected stainless steel

Integrated discharge scenario for high-temperature helical plasma on LHD

International Nuclear Information System (INIS)

Nagaoka, K.; Takahashi, H.; Murakami, S.

2014-10-01

Discharge scenario of high temperature plasma with helical configuration has been significantly progressed. The increase of central ion temperature due to reduction of wall recycling was clearly observed. The neutral particle profile was measured with a high-dynamic range of Balmer-α spectroscopy, and the reduction of neutral density was identified after helium conditioning main discharges. The peaking of ion heating profile and the reduction of charge exchange loss of energetic ions play an important role for improvement of ion heat transport in the core. The ion ITB and electron ITB have been successfully integrated due to superposition of centrally focused electron cyclotron heating to the ion ITB plasma, and the high temperature regime of T i ∼T e has been significantly extended. The normalized temperature gradient of ion and electron (R/L T ) were observed to exceed 10, indicating the significant improvement of both ion and electron heat transports at the barrier position. The positive radial electric field was observed by heavy ion beam probe, while the negative radial electric field was observed in ion ITB plasmas. The ion temperature gradient was observed to decrease with the increase of temperature ratio (T e /T i ). This experiment demonstrated that the profile control is a key to combine ion ITB and electron ITB and have a potential to improve the performance of helical plasmas. (author)

Anisotropic deformation of Zr–2.5Nb pressure tube material at high temperatures

Energy Technology Data Exchange (ETDEWEB)

Fong, R.W.L., E-mail: fongr@aecl.ca [Fuel and Fuel Channel Safety Branch, Atomic Energy of Canada Limited, Chalk River Nuclear Laboratories, Chalk River, Ontario (Canada)

2013-09-15

Zr–2.5Nb alloy is used for the pressure tubes in CANDU® reactor fuel channels. In reactor, the pressure tube normally operates at 300 °C and experiences a primary coolant fluid internal pressure of approximately 10 MPa. Manufacturing and processing procedures generate an anisotropic state in the pressure tube which makes the tube stronger in the hoop (transverse) direction than in the axial (longitudinal) direction. This anisotropy condition is present for temperatures less than 500 °C. During postulated accident conditions where the material temperature could reach 1000 °C, it might be assumed that the high temperature and subsequent phase change would reduce the inherent anisotropy, and thus affect the deformation behaviour (ballooning) of the pressure tube. From constant-load, rapid-temperature-ramp, uniaxial deformation tests, the deformation rate in the longitudinal direction of the tube behaves differently than the deformation rate in the transverse direction of the tube. This anisotropic mechanical behaviour appears to persist at temperatures up to 1000 °C. This paper presents the results of high-temperature deformation tests using longitudinal and transverse specimens taken from as-received Zr–2.5Nb pressure tubes. It is shown that the anisotropic deformation behaviour observed at high temperatures is largely due to the stable crystallographic texture of the α-Zr phase constituent in the material that was previously observed by neutron diffraction measurements during heating at temperatures up to 1050 °C. The deformation behaviour is also influenced by the phase transformation occurring at high temperatures during heating. The effects of texture and phase transformation on the anisotropic deformation of as-received Zr–2.5Nb pressure tube material are discussed in the context of the tube ballooning behaviour. Because of the high temperatures in postulated accident scenarios, any irradiation damage will be annealed from the pressure tube material

ACBC to Balcite: Bioinspired Synthesis of a Highly Substituted High-Temperature Phase from an Amorphous Precursor

Energy Technology Data Exchange (ETDEWEB)

Whittaker, Michael L.; Joester, Derk (NWU)

2017-04-28

Energy-efficient synthesis of materials locked in compositional and structural states far from equilibrium remains a challenging goal, yet biomineralizing organisms routinely assemble such materials with sophisticated designs and advanced functional properties, often using amorphous precursors. However, incorporation of organics limits the useful temperature range of these materials. Herein, the bioinspired synthesis of a highly supersaturated calcite (Ca0.5Ba0.5CO3) called balcite is reported, at mild conditions and using an amorphous calcium–barium carbonate (ACBC) (Ca1- x Ba x CO3·1.2H2O) precursor. Balcite not only contains 50 times more barium than the solubility limit in calcite but also displays the rotational disorder on carbonate sites that is typical for high-temperature calcite. It is significantly harder (30%) and less stiff than calcite, and retains these properties after heating to elevated temperatures. Analysis of balcite local order suggests that it may require the formation of the ACBC precursor and could therefore be an example of nonclassical nucleation. These findings demonstrate that amorphous precursor pathways are powerfully enabling and provide unprecedented access to materials far from equilibrium, including high-temperature modifications by room-temperature synthesis.

Effect of seawater and high-temperature history on swelling characteristics of bentonite

International Nuclear Information System (INIS)

Tanaka, Yukihisa; Nakamura, Kunihiko

2005-01-01

In the case of construction of repository for nuclear waste near the coastal area, the effect of seawater on swelling characteristics of bentonite as an engineering as an engineering barrier should be considered. Effects of high-temperature history on swelling characteristics of bentonite should also be considered because nuclear waste generates heat. Thus, in this study, swelling characteristics of bentonite on the conditions of high temperature history and seawater are investigated. The results of this study imply that : (1) Swelling strain of sodium bentonite or transformed sodium bentonite decrease as the salinity of water increases, whereas those of calcium bentonite are not affected by salinity of the water. (2) Quantitative evaluation method for swelling strain and swelling pressure of several kinds of bentonites under brine is proposed. (3) Using distilled water, swelling strain and swelling pressure of sodium bentonite with high-temperature history is less than those without high-temperature history. (author)

A brief review study of various thermodynamic cycles for high temperature power generation systems

International Nuclear Information System (INIS)

Yu, Si-Cong; Chen, Lin; Zhao, Yan; Li, Hong-Xu; Zhang, Xin-Rong

2015-01-01

Highlights: • Various high temperature power generation cycles for are reviewed and analyzed. • The operating temperature is higher than 700 K for high temperature power systems. • Thermodynamic cycle model study and working fluid choices are discussed. • Characteristics and future developments of high temperature cycles are presented and compared. - Abstract: This paper presents a review of the previous studies and papers about various thermodynamic cycles working for high temperature power generation procedures, in these cycles the highest temperature is not lower than 700 K. Thermodynamic cycles that working for power generation are divided into two broad categories, thermodynamic cycle model study and working fluid analysis. Thermodynamic cycle contains the simple cycle model and the complex cycle model, emphasis has been given on the complex thermodynamic cycles due to their high thermal efficiencies. Working fluids used for high temperature thermodynamic cycles is a dense gas rather than a liquid. A suitable thermodynamic cycle is crucial for effectively power generation especially under the condition of high temperature. The main purpose is to find out the characteristics of various thermodynamic cycles when they are working in the high temperature region for power generation. As this study shows, combined cycles with both renewable and nonrenewable energies as the heat source can show good performance

Electric breakdown of high polymer insulating materials at cryogenic temperature

International Nuclear Information System (INIS)

Kim, Sanhyon; Yoshino, Katsumi

1985-01-01

Cryogenic properties : temperature dependence of E sub(b) and effects of media upon E sub(b) were investigated on several high polymers. Temperature conditions were provided by liquid He (4.2 K), liquid N 2 (77 K) and cryogen (dry ice-methyl alcohol, 194 K). Silicone oil was used also at ambient temperature and elevated temperature. Polymer film coated with gold by vacuum evaporation was placed in cryostat, and high tension from pulse generator was applied to the film. Dielectric breakdowns were detected by oscilloscope and observed visually. The results of experiment are summerized as follow. (1) E sub(b) of film in He is affected by medium remarkably, and covering with 3-methyl pentane is effective for increasing E sub(b). (2) Temperature dependence of E sub(b) was not recognized in cryogenic temperature below liquid N 2 . (3) Temperature characteristic of E sub(b) changes considerably at the critical temperature T sub(c), and T sub(c) is dependent on material. (4) Strength against dielectric breakdown under cryogenic temperature is not affected by bridging caused by irradiation of electron beam. (5) Dielectric breakdown is thought to be caused by electronic process such as electron avalanche. Consequently, for designing insulation for the temperature below liquid He, insulation design for liquid N 2 is thought to be sufficient. However, the degradation and breakdown by mechanical stress under cryogenic temperature must be taken into consideration. (Ishimitsu, A.)

Polyurethane-Based Ionogels Exhibiting Durable Thermoresponsive Optical Behavior Under High-Temperature Conditions.

Science.gov (United States)

Sato, Tomoya; England, Matt W; Wang, Liming; Urata, Chihiro; Kakiuchida, Hiroshi; Hozumi, Atsushi

2018-01-01

Polyurethane (PU)-based transparent and flexible ionogels, showing unusual thermo-responsive optical properties, were successfully prepared by mixing PU-precursor and a hydrophobic ionic liquid, 1-ethyl-3-methylimidazolium bis(trifluoromethanesulfonyl)imide (EMIM-TFSI). Although the initial ionogels were transparent at room temperature, significant increases in opacity were observed with increasing temperature up to 120°C, because of macroscopic phase separation of the PU-matrix and hydrophobic EMIM-TFSI. In addition, the optical transition temperature could be arbitrarily controlled simply by varying the mixing ratio of EMIM-TFSI within the PU-matrix. As confirmed by UV-Vis spectra acquired at different temperatures, this thermo-responsive optical behavior was found to be reversible, repeatable and durable even after 30 cycles of a thermal-stress testing between 30 and 100°C.

High-Temperature Corrosion Behavior of Alloy 617 in Helium Environment of Very High Temperature Gas Reactor

International Nuclear Information System (INIS)

Lee, Gyeong-Geun; Jung, Sujin; Kim, Daejong; Jeong, Yong-Whan; Kim, Dong-Jin

2012-01-01

Alloy 617 is a Ni-base superalloy and a candidate material for the intermediate heat exchanger (IHX) of a very high temperature gas reactor (VHTR) which is one of the next generation nuclear reactors under development. The high operating temperature of VHTR enables various applications such as mass production of hydrogen with high energy efficiency. Alloy 617 has good creep resistance and phase stability at high temperatures in an air environment. However, it was reported that the mechanical properties decreased at a high temperature in an impure helium environment. In this study, high-temperature corrosion tests were carried out at 850°C-950°C in a helium environment containing the impurity gases H_2, CO, and CH_4, in order to examine the corrosion behavior of Alloy 617. Until 250 h, Alloy 617 specimens showed a parabolic oxidation behavior at all temperatures. The activation energy for oxidation in helium environment was 154 kJ/mol. The SEM and EDS results elucidated a Cr-rich surface oxide layer, Al-rich internal oxides and depletion of grain boundary carbides. The thickness and depths of degraded layers also showed a parabolic relationship with time. A normal grain growth was observed in the Cr-rich surface oxide layer. When corrosion tests were conducted in a pure helium environment, the oxidation was suppressed drastically. It was elucidated that minor impurity gases in the helium would have detrimental effects on the high temperature corrosion behavior of Alloy 617 for the VHTR application.

Heat exchangers for high-temperature thermodynamic cycles

International Nuclear Information System (INIS)

Fraas, A.P.

1975-01-01

The special requirements of heat exchangers for high temperature thermodynamic cycles are outlined and discussed with particular emphasis on cost and thermal stress problems. Typical approaches that have been taken to a comprehensive solution intended to meet all of the many boundary conditions are then considered by examining seven typical designs including liquid-to-liquid heat exchangers for nuclear plants, a heater for a closed cycle gas turbine coupled to a fluidized bed coal combustion chamber, steam generators for nuclear plants, a fossil fuel-fired potassium boiler, and a potassium condenser-steam generator. (auth)

Influence of high temperature and ethanol on thermostable lignocellulolytic enzymes

DEFF Research Database (Denmark)

Skovgaard, Pernille Anastasia; Jørgensen, Henning

2013-01-01

the influence of temperature and ethanol on enzyme activity and stability in the distillation step, where most enzymes are inactivated due to high temperatures. Two enzyme mixtures, a mesophilic and a thermostable mixture, were exposed to typical process conditions [temperatures from 55 to 65 °C and up to 5...... % ethanol (w/v)] followed by specific enzyme activity analyses and SDS-PAGE. The thermostable and mesophilic mixture remained active at up to 65 and 55 °C, respectively. When the enzyme mixtures reached their maximum temperature limit, ethanol had a remarkable influence on enzyme activity, e.g., the more...... ethanol, the faster the inactivation. The reason could be the hydrophobic interaction of ethanol on the tertiary structure of the enzyme protein. The thermostable mixture was more tolerant to temperature and ethanol and could therefore be a potential candidate for recycling after distillation....

High temperature oxidation in boiler environment of chromized steel

Science.gov (United States)

Alia, F. F.; Kurniawan, T.; Asmara, Y. P.; Ani, M. H. B.; Nandiyanto, A. B. D.

2017-10-01

The demand for increasing efficiency has led to the development and construction of higher operating temperature power plant. This condition may lead to more severe thickness losses in boiler tubes due to excessive corrosion process. Hence, the research to improve the corrosion resistance of the current operated material is needed so that it can be applied for higher temperature application. In this research, the effect of chromizing process on the oxidation behaviour of T91 steel was investigated under steam condition. In order to deposit chromium, mixture of chromium (Cr) powder as master alloy, halide salt (NH4Cl) powder as activator and alumina (Al2O3) powder as inert filler were inserted into alumina retort together with the steel sample and heated inside furnace at 1050°C for ten hours under argon gas environment. Furthermore, for the oxidation process, steels were exposed at 700°C at different oxidation time (6h-24h) under steam condition. From FESEM/EDX analysis, it was found that oxidation rate of pack cemented steel was lower than the un-packed steel. These results show that Cr from chromizing process was able to become reservoir for the formation of Cr2O3 in high temperature steam oxidation, and its existence can be used for a longer oxidation time.

Low temperature superconductor and aligned high temperature superconductor magnetic dipole system and method for producing high magnetic fields

Science.gov (United States)

Gupta, Ramesh; Scanlan, Ronald; Ghosh, Arup K.; Weggel, Robert J.; Palmer, Robert; Anerella, Michael D.; Schmalzle, Jesse

2017-10-17

A dipole-magnet system and method for producing high-magnetic-fields, including an open-region located in a radially-central-region to allow particle-beam transport and other uses, low-temperature-superconducting-coils comprised of low-temperature-superconducting-wire located in radially-outward-regions to generate high magnetic-fields, high-temperature-superconducting-coils comprised of high-temperature-superconducting-tape located in radially-inward-regions to generate even higher magnetic-fields and to reduce erroneous fields, support-structures to support the coils against large Lorentz-forces, a liquid-helium-system to cool the coils, and electrical-contacts to allow electric-current into and out of the coils. The high-temperature-superconducting-tape may be comprised of bismuth-strontium-calcium-copper-oxide or rare-earth-metal, barium-copper-oxide (ReBCO) where the rare-earth-metal may be yttrium, samarium, neodymium, or gadolinium. Advantageously, alignment of the large-dimension of the rectangular-cross-section or curved-cross-section of the high-temperature-superconducting-tape with the high-magnetic-field minimizes unwanted erroneous magnetic fields. Alignment may be accomplished by proper positioning, tilting the high-temperature-superconducting-coils, forming the high-temperature-superconducting-coils into a curved-cross-section, placing nonconducting wedge-shaped-material between windings, placing nonconducting curved-and-wedge-shaped-material between windings, or by a combination of these techniques.

Comparative transcriptome profiling of a thermal resistant vs. sensitive silkworm strain in response to high temperature under stressful humidity condition.

Directory of Open Access Journals (Sweden)

Wenfu Xiao

Full Text Available Thermotolerance is important particularly for poikilotherms such as insects. Understanding the mechanisms by which insects respond to high temperatures can provide insights into their adaptation to the environment. Therefore, in this study, we performed a transcriptome analysis of two silkworm strains with significantly different resistance to heat as well as humidity; the thermo-resistant strain 7532 and the thermos-sensitive strain Knobbed. We identified in total 4,944 differentially expressed genes (DEGs using RNA-Seq. Among these, 4,390 were annotated and 554 were novel. Gene Ontology (GO analysis of 747 DEGs identified between RT_48h (Resistant strain with high-temperature Treatment for 48 hours and ST_48h (Sensitive strain with high-temperature Treatment for 48 hours showed significant enrichment of 12 GO terms including metabolic process, extracellular region and serine-type peptidase activity. Moreover, we discovered 12 DEGs that may contribute to the heat-humidity stress response in the silkworm. Our data clearly showed that 48h post-exposure may be a critical time point for silkworm to respond to high temperature and humidity. These results provide insights into the genes and biological processes involved in high temperature and humidity tolerance in the silkworm, and advance our understanding of thermal tolerance in insects.

Influence of the mix parameters and microstructure on the behaviour of concrete at high temperature

International Nuclear Information System (INIS)

Kanema, M.; Noumowe, A.; Gallias, J.-L.; Cabrillac, R.

2005-01-01

Concrete is used in structures likely to be exposed to high temperature. Data on the behaviour of concrete at high temperature are necessary to design buildings and other civil engineering structures in order to resist under accidental conditions (fire) or particular conditions of service (storage of radioactive waste). The present experimental study was carried out on the behaviour of five concretes containing the same nature and quantity of aggregates and presenting different water/cement ratios. Concrete specimens were submitted to heating-cooling cycles whose maximum temperatures were 150, 300, 450 and 600 degree C. Measurements of compressive and tensile strength, modulus of elasticity and permeability were carried out on cylindrical specimens before and after heating-cooling cycles. The results showed the influence of concrete mix parameters on the residual properties and the dehydration of the cement paste matrix, the evolution of the permeability and thermal stability of concrete when it is subjected to high temperature. (authors)

Analysis of heat transfer under high heat flux nucleate boiling conditions

Energy Technology Data Exchange (ETDEWEB)

Liu, Y.; Dinh, N. [3145 Burlington Laboratories, Raleigh, NC (United States)

2016-07-15

Analysis was performed for a heater infrared thermometric imaging temperature data obtained from high heat flux pool boiling and liquid film boiling experiments BETA. With the OpenFOAM solver, heat flux distribution towards the coolant was obtained by solving transient heat conduction of heater substrate given the heater surface temperature data as boundary condition. The so-obtained heat flux data was used to validate them against the state-of-art wall boiling model developed by D. R. Shaver (2015) with the assumption of micro-layer hydrodynamics. Good agreement was found between the model prediction and data for conditions away from the critical heat flux (CHF). However, the data indicate a different heat transfer pattern under CHF, which is not captured by the current model. Experimental data strengthen the notion of burnout caused by the irreversible hot spot due to failure of rewetting. The observation forms a basis for a detailed modeling of micro-layer hydrodynamics under high heat flux.

Analysis of heat transfer under high heat flux nucleate boiling conditions

International Nuclear Information System (INIS)

Liu, Y.; Dinh, N.

2016-01-01

Analysis was performed for a heater infrared thermometric imaging temperature data obtained from high heat flux pool boiling and liquid film boiling experiments BETA. With the OpenFOAM solver, heat flux distribution towards the coolant was obtained by solving transient heat conduction of heater substrate given the heater surface temperature data as boundary condition. The so-obtained heat flux data was used to validate them against the state-of-art wall boiling model developed by D. R. Shaver (2015) with the assumption of micro-layer hydrodynamics. Good agreement was found between the model prediction and data for conditions away from the critical heat flux (CHF). However, the data indicate a different heat transfer pattern under CHF, which is not captured by the current model. Experimental data strengthen the notion of burnout caused by the irreversible hot spot due to failure of rewetting. The observation forms a basis for a detailed modeling of micro-layer hydrodynamics under high heat flux.

High temperature mechanical performance of a hot isostatically pressed silicon nitride

Energy Technology Data Exchange (ETDEWEB)

Wereszczak, A.A.; Ferber, M.K.; Jenkins, M.G.; Lin, C.K.J. [and others

1996-01-01

Silicon nitride ceramics are an attractive material of choice for designers and manufacturers of advanced gas turbine engine components for many reasons. These materials typically have potentially high temperatures of usefulness (up to 1400{degrees}C), are chemically inert, have a relatively low specific gravity (important for inertial effects), and are good thermal conductors (i.e., resistant to thermal shock). In order for manufacturers to take advantage of these inherent properties of silicon nitride, the high-temperature mechanical performance of the material must first be characterized. The mechanical response of silicon nitride to static, dynamic, and cyclic conditions at elevated temperatures, along with reliable and representative data, is critical information that gas turbine engine designers and manufacturers require for the confident insertion of silicon nitride components into gas turbine engines. This final report describes the high-temperature mechanical characterization and analyses that were conducted on a candidate structural silicon nitride ceramic. The high-temperature strength, static fatigue (creep rupture), and dynamic and cyclic fatigue performance were characterized. The efforts put forth were part of Work Breakdown Structure Subelement 3.2.1, {open_quotes}Rotor Data Base Generation.{close_quotes} PY6 is comparable to other hot isostatically pressed (HIPed) silicon nitrides currently being considered for advanced gas turbine engine applications.

Development and application of a high-temperature sampling probe for burning chamber conditions of fluidized-bed combustion; Korkean laempoetilan naeytteenottosondin kehittaeminen ja soveltaminen leijukerrospolton tulipesaeolosuhteisiin

Energy Technology Data Exchange (ETDEWEB)

Larjava, K.; Paerkkae, M.; Jormanainen, P.; Roine, J.; Paakkinen, K. [VTT Chemistry, Espoo (Finland); Linna, V. [VTT Energy, Jyvaeskylae (Finland)

1996-12-01

A sampling probe for the burning chamber conditions of fluidized-bed combustion will be developed in this project. The probe will be suitable for sampling vaporous heavy and alkali metals and other condensing compounds (e.g. chlorides) as well combustion gases and alternatively also flue gas particles at high temperatures. The knowledge gained with the probe will help understanding, developing and modeling combustion processes and will thus aid the manufacturers of the boilers. (author)

Fusion blanket high-temperature heat transfer

International Nuclear Information System (INIS)

Fillo, J.A.

1983-01-01

Deep penetration of 14 MeV neutrons makes two-temperature region blankets feasible. A relatively low-temperature (approx. 300 0 C) metallic structure is the vacuum/coolant pressure boundary, while the interior of the blanket, which is a simple packed bed of nonstructural material, operates at very high temperatures (>1000 0 C). The water-cooled shell structure is thermally insulated from the steam-cooled interior. High-temperature steam can dramatically increase the efficiency of electric power generation, as well as produce hydrogen and oxygen-based synthetic fuels at high-efficiency

High temperature phase transitions in nuclear fuels of the fourth generation

International Nuclear Information System (INIS)

De Bruycker, F.

2010-01-01

Understanding the behaviour of nuclear materials in extreme conditions is of prime importance for the analysis of the operation limits of nuclear fuels, and prediction of possible nuclear reactor accidents, relevant to the general objectives of nuclear safety research. The main purpose of this thesis is the study of high temperature phase transitions in nuclear materials, with special attention to the candidate fuel materials for the reactors of the 4. Generation. In this framework, material properties need to be investigated at temperatures higher than 2500 K, where equilibrium conditions are difficult to obtain. Laser heating combined with fast pyrometer is the method used at the European Institute for Transuranium Elements (JRC - ITU). It is associated to a novel process used to determine phase transitions, based on the detection, via a suited low-power (mW) probe laser, of changes in surface reflectivity that may accompany solid/liquid phase transitions. Fast thermal cycles, from a few ms up to the second, under almost container-free conditions and control atmosphere narrow the problem of vaporisation and sample interactions usually meet with traditional method. This new experimental approach has led to very interesting results. It confirmed earlier research for material systems known to be stable at high temperature (such as U-C) and allowed a refinement of the corresponding phase diagrams. But it was also feasible to apply this method to materials highly reactive, thus original results are presented on PuO 2 , NpO 2 , UO 2 -PuO 2 and Pu-C systems. (author)

High temperature slagging incinerator for TRU-waste treatment

International Nuclear Information System (INIS)

Van De Voorde, N.; Hennart, D.; Gijbels, J.; Mergan, L.

1984-01-01

Since 1974 the Belgian Nuclear Study Center (SCK/CEN) at Mol, with the support of the European Communities, has developed an ''integral'' system for the treatment and the conditioning of radioactive contaminated wastes. The system converts directly, at high temperature (1500 0 C), mixtures of combustibles (paper, plastics, rubber etc.) and non-combustibles (metals, soil, sludge, concrete.) contaminated with transuranium elements as well as beta-gamma emitting isotopes, into a chemically inert and physically stable slag. More than 4000 hours of successful operation, with wide variety of simulated waste composition as well as real waste, have confirmed the safe operability of the high temperature sl'Gging incinerator and the connected installations, such as sorting cells, waste shredder, off-gas purification train, slag extraction system, remoted control, and the alpha-containment building. During the fall of 1983, a final confirmation of the performance of the installation was given by the successful accomplishment of an incineration campaign of 16 to 17 tons of simulated solid plutonium contaminated wastes

Concept of an inherently-safe high temperature gas-cooled reactor

International Nuclear Information System (INIS)

Ohashi, Hirofumi; Sato, Hiroyuki; Tachibana, Yukio; Kunitomi, Kazuhiko; Ogawa, Masuro

2012-01-01

As the challenge to ensure no harmful release of radioactive materials at the accidents by deterministic approach instead to satisfy acceptance criteria or safety goal for risk by probabilistic approach, new concept of advanced reactor, an inherently-safe high temperature gas-cooled reactor, is proposed based on the experience of the operation of the actual High Temperature Gas-cooled Reactor (HTGR) in Japan, High Temperature Engineering Test Reactor (HTTR), and the design of the commercial plant (GTHTR300), utilizing the inherent safety features of the HTGR (i.e., safety features based on physical phenomena). The safety design philosophy of the inherently-safe HTGR for the safety analysis of the radiological consequences is determined as the confinement of radioactive materials is assured by only inherent safety features without engineered safety features, AC power or prompt actions by plant personnel if the design extension conditions occur. Inherent safety features to prevent the loss or degradation of the confinement function are identified. It is proposed not to apply the probabilistic approach for the evaluation of the radiological consequences of the accidents in the safety analysis because no inherent safety features fail for the mitigation of the consequences of the accidents. Consequently, there are no event sequences to harmful release of radioactive materials if the design extension conditions occur in the inherently-safe HTGR concept. The concept and future R and D items for the inherently-safe HTGR are described in this paper.

Accelerated Testing with Multiple Failure Modes under Several Temperature Conditions

OpenAIRE

Zongyue Yu; Zhiqian Ren; Junyong Tao; Xun Chen

2014-01-01

A complicated device may have multiple failure modes, and some of the failure modes are sensitive to low temperatures. To assess the reliability of a product with multiple failure modes, this paper presents an accelerated testing in which both of the high temperatures and the low temperatures are applied. Firstly, an acceleration model based on the Arrhenius model but accounting for the influence of both the high temperatures and low temperatures is proposed. Accordingly, an accelerated testi...

13. TOPICAL CONFERENCE ON HIGH TEMPERATURE PLASMA DIAGNOSTICS SCIENTIFIC PROGRAM

International Nuclear Information System (INIS)

Barnes, C.

2000-01-01

Electron cyclotron emission (ECE) has been employed as a standard electron temperature profile diagnostic on many tokamaks and stellarators, but most magnetically confined plasma devices cannot take advantage of standard ECE diagnostics to measure temperature. They are either overdense, operating at high density relative to the magnetic field (e.g. ω pe >> (Omega) ce in a spherical torus) or they have insufficient density and temperature to reach the blackbody condition (τ > 2). Electron Bernstein waves (EBWs) are electrostatic waves which can propagate in overdense plasmas and have a high optical thickness at the electron cyclotron resonance layers, as a result of their large K i . This talk reports on measurements of EBW emission on the CDX-U spherical torus, where B 0 ∼ 2 kG, e > ∼ 10 13 cm -3 and T e ∼ 10 - 200 eV. Results will be presented for both direct detection of EBWs and for mode-converted EBW emission. The EBW emission was absolutely calibrated and compared to the electron temperature profile measured by a multi-point Thomson scattering diagnostic. Depending on the plasma conditions, the mode-converted EBW radiation temperature was found to be ≤ T e and the emission source was determined to be radially localized at the electron cyclotron resonance layer. A Langmuir triple probe was employed to measure changes in edge density profile in the vicinity of the upper hybrid resonance where the mode conversion of the EBWs is expected to occur. Changes in the mode conversion efficiency may explain the observation of mode-converted EBW radiation temperatures below T e . Initial results suggest EBW emission and EBW heating are viable concepts for plasmas where ω pe >> (Omega) ce

Circuit for Communication over DC Power Line Using High Temperature Electronics

Science.gov (United States)

Krasowski, Michael J. (Inventor); Prokop, Norman F. (Inventor)

2014-01-01

A high temperature communications circuit includes a power conductor for concurrently conducting electrical energy for powering circuit components and transmitting a modulated data signal, and a demodulator for demodulating the data signal and generating a serial bit stream based on the data signal. The demodulator includes an absolute value amplifier for conditionally inverting or conditionally passing a signal applied to the absolute value amplifier. The absolute value amplifier utilizes no diodes to control the conditional inversion or passing of the signal applied to the absolute value amplifier.

The influence of boron on the crystal structure and properties of mullite. Investigations at ambient, high-pressure, and high-temperature conditions

Energy Technology Data Exchange (ETDEWEB)

Luehrs, Hanna

2013-11-21