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Sample records for high sulphur coal

  1. Biodesulphurisation of high sulphur coal by heap leaching

    Energy Technology Data Exchange (ETDEWEB)

    J. Cara; M.T. Carballo; A. Moran; D. Bonilla; O. Escolano; F.J. Garcia Frutos [Universidad de Leon, Leon (Spain). Departamento de Ingenieria Quimica

    2005-10-01

    The biodesulphurisation of coal carried out in pile could be an interesting option to clean coal. In view of the good results obtained in biodesulphurisation test column at lab scale on a sample of semianthracite coal that proceed of an industrial plant with a high sulphur content, mainly pyritic sulphur, the feasibility of the process at pilot plant scale was studied. The pile was formed with 6 ton of gravity middlings coal sample with a grain size -12+0.5 mm from S.A. Hullera Vasco-Leonesa industrial plant. The coal has a total sulphur content of 3.78% and a pyritic sulphur content of 2.88%, the rest of sulphur is organic sulphur. The biodesulphurisation process in pilot plant follows three stages: stabilization of the pile, biodesulphurisation and washing. Heap was sampled twice during stabilisation stage, at the end of desulphurisation process and finally once washed. A pyritic sulphur removal of 39% and total sulphur removal of 23% was obtained. To complete the bioleaching process, the treatment of purge of leachate was carried out with the objective to recycling to head of process. The best treatment was a pre-treatment of the leachate until pH 4, and further treatment by reverse osmosis of the clarified water. Comparing this process with conventional precipitation to reach disposal limits, the reagents consumption and sludges were reduced considerably and due to the high quality of permeate it permits to recycle it to head of process. 18 refs., 6 figs., 6 tabs.

  2. Reduced emissions from inexpensive high-sulphur coal briquettes

    International Nuclear Information System (INIS)

    Gammage, R.B.; Wachter, E.A.; Wade, J.; Wilson, D.L.; Haas, J.W.; Ahmad, N.; Siltain, F.; Raza, M.Z.

    1992-01-01

    Airborne emissions were measured during the combustion of Pakistani high-sulphur coal, cold briquetted with lime and clay; comparison was made to emissions from raw coal and traditional fuels burnt in a native, mud-lined Angethi stove. Compared to raw coal, the amended coal gave fourfold reduced emission of respirable-size particles (RSP) and threefold reduced total releases of SO 2 . In domestic cooking, substitution of the amended coal briquettes for traditional fuels will not worsen indoor air quality with respect to CO, SO 2 , NO x , and RSP. The high peak amounts of CO (100--250 ppm), SO 2 (2--5 ppm), and NO x (1--5 ppm) were limited to the early phase of burning. The high thermal value of the coal briquettes together with a simple briquetting technology, make this fuel an attractive energy alternative in countries that are underdeveloped, developing, or experiencing major restructuring

  3. Mathematical modelling of demineralisation of high sulphur coal by bioleaching

    Energy Technology Data Exchange (ETDEWEB)

    Weerasekara, N.S.; Frutos, F.J.G.; Cara, J.; Lockwood, F.C. [University of London Imperial College of Science Technology & Medicine, London (United Kingdom)

    2008-02-15

    During coal combustion various toxic compounds are generated from its sulphur content. Their environmental impacts are considered to be very important. While there are various conventional preparation methods to remove the sulphur in the fuel, recent work reveals that newly-isolated micro-organisms, naturally present in coal, have the ability to reduce its sulphur content. The removal of sulphur using biological leaching involving acidophilic iron oxidising bacteria like Acidithiobacillus ferrooxidans and Leptospirillum ferrooxidans are examined and a computational technique based on computational fluid dynamics is developed to model the biological leaching of sulphur from coal. The model was validated against a pack-column experiment carried out for iron separation during 60 days. The mathematical model predicted iron separation over time is similar to experimental measurements, with an average difference of 5.5%. According to the experimental results, there was an overall reduction of 33% of pyrite, whereas the model prediction was 32%. The model results shows overall good agreement with pack-column experimental data.

  4. Sumpor u ugljenu (Sulphur in Coal

    Directory of Open Access Journals (Sweden)

    Rađenović, A.

    2004-12-01

    Full Text Available The presence of sulphur in coal possesses important environmetal problems in its usage. The sulphur dioxide (S02 emissions produced during coal combustion account for a significant proportion of the total global output of anthropogenic SO2. The extent of sulphur separation depends on several variables such as the form of sulphur in coal, intimacy of contact between minerals and the products of devolatilization. The total sulphur in coal varies in the range of 0.2 - 11 wt %, although in most cases it is beetwen 1 and 3 wt %. Sulphur occurs in a variety of both inorganic and organic forms. Inorganic sulphur is found mainly as iron pyrite, marcasite, pyrrhotite, sphalerite, galena, chalcopirite and as sulphates (rarely exceeds w = 0,1 %. Organic sulphur is found in aromatic rings and aliphatic functionalities usually as mercaptans, aliphatic and aryl sulfides, disulfides and thiophenes. Organic and pyritic sulphur quantities depend on coal rank. Higher rank coals tend to have a high proportion of labile sulphur. All the organic sulphur is bivalent and it is spread throughout the organic coal matrix. Sulphur occurs in all the macerals and most minerals. Vitrinite contains the major part of organic sulphur and metals. Elemental sulphur is produced during coal weathering. The depolymerization methods as pyrolysis and hydrogenation are very drastic methods wich change the structure of the coal and the sulphur groups. In the case of pyrolysis, high levels of desulphurization, in chars and additional production of liquid hydrocarbon can be achieved. Thiophenes and sulphides were the major sulphur components of tars from coal pyrolysis. Hyrdogen sulphide and the lower mercaptans and sulphides were found in the volatile matters. Hydrogen sulphide and thiophenes are practically the only sulphur products of coal hydrogenation. H2S is produced in char hydrodesulphurization. A number of options are available for reducing sulphur emissions including the

  5. Performance evaluation of high-sulphur coal-fired USC plant integrated with SNOX and CO2 capture sections

    International Nuclear Information System (INIS)

    Cau, Giorgio; Tola, Vittorio; Bassano, Claudia

    2015-01-01

    In recent years coal-fired power plants have increased their role in the global energy scenario thanks to reliability, security of fuel supply and lower cost of fuel and electricity. In this framework global warming issues require a sustainable use of coal and great efforts for greenhouse gases reduction, addressing research and development projects towards more efficient solutions in terms of efficiency and environmental impact. With this aim in this paper a performance assessment of an Ultra Super Critical (USC) steam plant integrated with a CO 2 removal section was carried out. The study is based on simulation models specifically developed through Aspen-Plus and Gate-Cycle software platforms. Performance was assessed referring to typical USC commercial size plants (400–600 MW), fuelled by a mix of a low-sulphur coal and a Sardinian (Sulcis) high-sulphur coal. The USC plant, based on a reheated and regenerative Rankine cycle, is integrated with an SNOX section, with integrated DeNO x and DeSO x processes, and a low temperature CO 2 capture section. The SNOX technology shows several advantages in comparison to conventional de-nitrification and de-sulphuration systems. In particular it is capable to remove both nitrogen and sulphur oxides, requiring less energy absorption compared to traditional FGD systems, allowing a further preheating of the combustion air and without producing process waste. Besides the SNOX releases a commercial product as the sulphuric acid (H 2 SO 4 ) and operational costs are reduced when sulphur content in the coal increases. The CO 2 capture system was based on a chemical absorption process. A conventional system based on an amine (monoethanolamine, MEA) aqueous solution was considered. In order to match high pressure and purity CO 2 transportation requirements, the CO 2 removal section is also integrated with a conditioning and compression section. A performance assessment of the USC plant was carried out varying the high-sulphur coal

  6. Organically bound sulphur in coal: A molecular approach

    NARCIS (Netherlands)

    Sinninghe Damsté, J.S.; Leeuw, J.W. de

    1992-01-01

    A critical review of literature concerning the molecular characterization of low and high molecular weight organosulphur constitutents present in coal as well as a detailed analysis of organic sulphur compounds present in flash evaporates and pyrolysates of a suite of coals ranging in sulphur

  7. Self-cementitious properties of fly ashes from CFBC boilers co-firing coal and high-sulphur petroleum coke

    International Nuclear Information System (INIS)

    Sheng Guanghong; Li Qin; Zhai Jianping; Li Feihu

    2007-01-01

    Self-cementitious properties of fly ash from circulating fluidized bed combustion boiler co-firing coal and high-sulphur petroleum coke (CPFA) were investigated. CPFA was self-cementitious which was affected by its fineness and chemical compositions, especially the contents of SO 3 and free lime (f-CaO). Higher contents of SO 3 and f-CaO were beneficial to self-cementitious strength; the self-cementitious strength increases with a decrease of its 45 μm sieve residue. The expansive ratio of CPFA hardened paste was high because of generation of ettringite (AFt), which was influenced by its water to binder ratio (W/A), curing style and grinding of the ash. The paste cured in water had the highest expansive ratio, and grinding of CPFA was beneficial to its volume stability. The hydration products of CPFA detected by X-ray diffraction (XRD) and scanning electron microscopy (SEM) were portlandite, gypsum, AFt and hydrated calcium silicate (C-S-H)

  8. Development of a Temperature Programmed Identification Technique to Characterize the Organic Sulphur Functional Groups in Coal

    Directory of Open Access Journals (Sweden)

    Moinuddin Ghauri

    2017-06-01

    Full Text Available The Temperature Programmed Reduction (TPR technique is employed for the characterisation of various organic sulphur functional groups in coal. The TPR technique is modified into the Temperature Programmed Identification technique to investigate whether this method can detect various functional groups corresponding to their reduction temperatures. Ollerton, Harworth, Silverdale, Prince of Wales coal and Mequinenza lignite were chosen for this study. High pressure oxydesulphurisation of the coal samples was also done. The characterization of various organic sulphur functional groups present in untreated and treated coal by the TPR method and later by the TPI method confirmed that these methods can identify the organic sulphur groups in coal and that the results based on total sulphur are comparable with those provided by standard analytical techniques. The analysis of the untreated and treated coal samples showed that the structural changes in the organic sulphur matrix due to a reaction can be determined.

  9. Eco-restoration of a high-sulphur coal mine overburden dumping ...

    Indian Academy of Sciences (India)

    top bracket of environmental degradation (Chaoji. 2002), and coal mining is being considered for inclusion under the national superfund scheme. The chief environmental impacts due to mining are changes in soil stratification, reduced biotic diver- sity, and alteration of structure and functioning of ecosystems; these ...

  10. Eco-restoration of a high-sulphur coal mine overburden dumping site in northeast India: A case study

    Science.gov (United States)

    Dowarah, J.; Deka Boruah, H. P.; Gogoi, J.; Pathak, N.; Saikia, N.; Handique, A. K.

    2009-10-01

    Eco-restoration of mine overburden (OB) or abandoned mine sites is a major environmental concern. In the present investigation, an integrated approach was used to rejuvenate a high-sulphur mine OB dumping site in the Tirap Collieries, Assam, India, which is situated in the Indo-Burma mega-biodiversity hotspot. A mine OB is devoid of true soil character with poor macro and micronutrient content and contains elevated concentrations of trace and heavy metals. Planting of herbs, shrubs, cover crops and tree species at close proximity leads to primary and secondary sere state succession within a period of 3 to 5 years. A variety of plant species were screened for potential use in restoration: herbs, including Sccharum spontaneum, Cymbopogon winterianus Jowitt (citronella), and Cymbopogon flexuosus (lemon grass) cover plants, including Mimosa strigillosa, M. striata, and M. pigra; shrubs, including Sesbania rostrata (dhaincha) and Cassia streata (cassia); and tree species, including Gmelina arborea (gomari) and Dalbergia sissoo (sissoo). Amendment with unmined soil and bio-organic matter was required for primary establishment of some plant species. Management of these plant species at the site will ensure long term sustainable eco-restoration of the coal mine-degraded land.

  11. Eco-restoration of a high-sulphur coal mine overburden dumping site in northeast India: A case study

    Energy Technology Data Exchange (ETDEWEB)

    Dowarah, J.; Boruah, H.P.D.; Gogoi, J.; Pathak, N.; Saikia, N.; Handique, A.K. [CSIR, Jorhat (India). North East Institute of Science & Technology

    2009-10-15

    Eco-restoration of mine overburden (OB) or abandoned mine sites is a major environmental concern. In the present investigation, an integrated approach was used to rejuvenate a high-sulphur mine OB dumping site in the Tirap Collieries, Assam, India, which is situated in the Indo-Burma mega-biodiversity hotspot. A mine OB is devoid of true soil character with poor macro and micronutrient content and contains elevated concentrations of trace and heavy metals. Planting of herbs, shrubs, cover crops and tree species at close proximity leads to primary and secondary sere state succession within a period of 3 to 5 years. A variety of plant species were screened for potential use in restoration: herbs, including Sccharum spontaneum, Cymbopogon winterianus Jowitt (citronella), and Cymbopogon flexuosus (lemon grass) cover plants, including Mimosa strigillosa, M. striata, and M. pigra; shrubs, including Sesbania rostrata (dhaincha) and Cassia streata (cassia); and tree species, including Gmelina arborea (gomari) and Dalbergia sissoo (sissoo). Amendment with unmined soil and bio-organic matter was required for primary establishment of some plant species. Management of these plant species at the site will ensure long term sustainable eco-restoration of the coal mine-degraded land.

  12. Sulphur self–retention and sulphur dioxide capture with active calcium minerals in mineral–rich coals / Mchabe, D.

    OpenAIRE

    Mchabe, Dursman

    2011-01-01

    In order to provide information for the development of clean coal technology, the sulphur self–retention and sulphur dioxide capturing properties of minerals present in low grade coals was investigated. This study consisted of detailed mineral analyses of coal and ash samples using results obtained from QEMSCAN and separate retention (coal) and capture (ash) experiments with laboratory scale reactors. Typical South African coal samples were used in this study. The ash content v...

  13. The certification of the contents (mass fractions) of sulphur in six coals

    Energy Technology Data Exchange (ETDEWEB)

    Griepink, B; Maier, E A; Wilkinson, H C [CEC, Bruxelles (Belgium)

    1990-01-01

    This report presents the preparation and the certification of the sulphur content of six coal reference materials: low volatile steam coal (CRM 331), high volatile industrial coal (CRM 332), coking steam coal (CRM 333), anthracite (CRM 334), flame coal (CRM 335) and high volatile steam coal (CRM 336), as well as the homogeneity and stability studies. The analytical work leading to certification is also presented. The certified mass fractions for total sulphur in CRMs 331, 332, 333, 334, 335 and 336 respectively are 4.99 mg/g, 9.61 mg/g, 13.44 mg/g, 16.09 mg/g, 50.8 mg/g and 32.90 mg/g.

  14. Preparation of combustible material from high sulphur coal by means of pyrolysis: magnetic separation; Obtencion de combustibles limpios a partir de carbones con altos contenidos en azure mediante procesos de pirolisis: separacion magnetica

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1998-11-01

    Basic studies on coal desulphurization by pyrolysis have been carried out with a series of low rank coals with high total sulphur contents and differences in the distribution of sulphur forms. The evolved sulphur compounds were studied by sulphide selective electrode H{sub 2}S and Fourier transform infrared (FTIR) spectroscopy. The mechanisms affecting the sulphur removal during pyrolysis have been studied by scanning electron microscopy coupled with energy dispersive X-ray (SEM-EDX), X-ray diffraction (XRD) and photoelectronic spectroscopy (XPS). A sample coal of 11 Tm, representative of the Teruel basins was processed at pilot scale in a rotary kiln (coal HR). A series of pyrolysis runs simulating the experimental conditions of the rotary kiln were also carried out in laboratory scale. The magnetic behaviour of the chars from the rotary kiln and from the lab-scale pyrolysis was tested. The efficiency of the desulphurization, including pyrolysis and magnetic separation, was calculated. Chars from rotary kiln were tested by thermogravimetric analysis, air reactivity and carbon efficiency combustion in fluidized bed.

  15. Use of stable sulphur isotopes to monitor directly the behaviour of sulphur in coal during thermal desulphurization

    Science.gov (United States)

    Liu, Chao-Li; Hackley, Keith C.; Coleman, D.D.

    1987-01-01

    A method has been developed using stable sulphur isotope analyses to monitor the behaviour of sulphur forms in a coal during thermal desulphurization. In this method, the natural stable isotopic composition of the pyritic and organic sulphur in coal is used as a tracer to follow their mobility during the desulphurization process. This tracer method is based on the fact that the isotopic compositions of pyritic and organic sulphur are significantly different in some coals. Isotopic results of pyrolysis experiments at temperatures ranging from 350 to 750 ??C indicate that the sulphur released with the volatiles is predominantly organic sulphur. The pyritic sulphur is evolved in significant quantities only when pyrolysis temperatures exceed 500 ??C. The presence of pyrite seems to have no effect on the amount of organic sulphur evolved during pyrolysis. The chemical and isotopic mass balances achieved from three different samples of the Herrin (No. 6) coal of the Illinois Basin demonstrate that this stable isotope tracer method is quantitative. The main disadvantage of this tracing technique is that not all coals contain isotopically distinct organic and pyritic sulphur. ?? 1987.

  16. ONCE GRAND, NOW FORGOTTEN: WHAT DO WE KNOW ABOUT THE SUPERHIGH-ORGANIC-SULPHUR RAŠA COAL?

    Directory of Open Access Journals (Sweden)

    Gordana Medunić

    2016-10-01

    Full Text Available The Istrian coal mines, located in the eastern part of the Istrian Peninsula (Northern Adriatic Sea, Croatia had by far the most important and economically the most valuable deposits of the anthracite coal reserves in Croatia since the 18th century until the year 1999, when their excavation and use in the coal-fired power plant Plomin ceased. The coal is found within the Palaeocene Kozina limestone beds. Four coal basins, Karojba, Sveti Martin, Pićan, and the Labin basin, hosted seven coal mines, e.g. Tupljak, Potpićan, Kozljak, Štrmac, Raša, Ripenda, and Krapan. The coal has been generally known under the name of Raša coal. It is exceptional in world terms due to its high content of organic sulphur, which can be up to 14%. Herewithin, this paper reviews Croatian scientific publications devoted to various aspects of Raša coal, along with the most important publications on either similar coals or relevant subjects worldwide. A brief introduction deals with the role of coal in electricity production, and the history of coal mining in Istria. The following chapter summarises current knowledge of the coal sulphur geochemistry, with several examples of high-sulphur coals from India and China. It is followed by the geological, geochemical, and physical characterisation of Raša coal. Since perturbations to ecosystems caused by coal combustion have been documented in numerous papers from a number of countries, Croatian studies carried out to determine the impact of Raša coal combustion on the local environment are also presented.

  17. A compact XRF unit for determining total sulphur content in coals

    International Nuclear Information System (INIS)

    Sumitra, T.; Chankow, N.; Punnachaiya, S.; Srisatit, S.

    1994-01-01

    A microcomputer based x-ray fluorescence (XRF) unit was developed for off-line determination of total sulphur content in coal samples. The unit consisted of the x-ray exciting/measuring set and the microcomputer with a plug-in interface card. An Fe-55 radioisotope was used as the exciting source while a krypton-filled proportional counter was used to measure x-rays from the samples. The x-ray spectrum was simultaneously displayed on the microcomputer screen. For quantitative determination of sulphur, the intensities of sulphur K x-rays as well as calcium K x-rays and scattered x-rays were taken into account. The unit was tested with finely-ground, dried and compressed lignite, subbituminous and bituminous samples. If was found that for low-calcium coals, the results were in good agreement with those obtained from the standard chemical analysis method within ± 0.2% and within ± 0.5%S for high-calcium coals. 2 refs., 2 tabs., 3 figs

  18. Some environmental aspects related to sulphur emissions during combustion of Bulgarian coals

    International Nuclear Information System (INIS)

    Vassileva, C.; Vassilev, S.

    2004-01-01

    The mechanism of S emissions and their capture during combustion of some Bulgarian coals (Maritza East, Maritza West, Sofia, Pernik, Bobov Dol, Balkan) was studied based on the phase-mineral transformations in the inorganic matter during gradual heating of these coals. It was found that: 1) the organic, elemental and sulphide S is released from coal at 200-700 0 C; 2) the volatile S is initially captured by intermediate Ca-, Mg-, K-, Na-, Fc-, and Ba-oxides (mainly from decomposed organic matter and carbonates) with formation of their sulphates at 200-1000 0 C; 3) the decomposition of original and newly-formed sulphates occurs at 800-1300 0 C and they are the major source of volatile SO 2 from stack emissions of thermoelectric power stations (TPSs). The described mechanism of S emissions and their capture indicates that the traditional pulverized combustion (1200-1600 0 C) of the high-sulphur Bulgarian coals in TPSs is inadequate from an environmental point of view and other alternatives should be applied. Some of them such as fluidized-bed combustion and selective blending of the coals are proposed

  19. Neutron activation analysis for sulphur in coal samples and moisture content by gamma-ray transmission

    International Nuclear Information System (INIS)

    Selvi, S.

    1993-01-01

    A neutron activation analysis method is described for the determination of sulphur in coal samples by analysing the beta spectrum emitted from 32 P and 33 P following the reactions 32 S(n, p) 32 P and 33 S(n, p) 33 P using 252 Cf as a source of neutrons. The transmission of the combined gamma-rays emitted from three 137 Cs and three 241 Am sources is used to measure the water content of the coal samples. (author)

  20. The X-ray fluorescent method for determination of total sulphur in bituminous coals

    International Nuclear Information System (INIS)

    Widowska-Kusmierska, J.; Siess, K.

    1979-01-01

    The X-ray fluorescent technique for the determination of total sulphur covering concentrations from 0,1 to 10% has been applied for bituminous coals showing a great variability in qualitative and quantitative composition of mineral matter (ash). The described method is a quick one giving results during one hour. The obtained good accuracy of determinations gives prospects for wide industrial application. (author)

  1. Coal desulphurisation as a method of sulphur dioxide emission control

    Energy Technology Data Exchange (ETDEWEB)

    Skelton, R.L.; Cockshott, A.R.

    1983-11-01

    Three methods of washing power station coal are first described and their effectiveness is discussed. The following wet and dry flue gas desulphurisation processes are discussed briefly: alkali injection, adsorption processes, Davy/Wellman-Lord, lime/limestone, double alkali, citrate, aqueous carbonate, spray absorption and magnesium oxide.

  2. Forest fuel and sulphur

    International Nuclear Information System (INIS)

    Lundborg, A.

    1994-10-01

    This report illustrates the sulphur cycle in forest fuel and in the forest ecosystem. The hypothesis is that sulphur dioxide from combustion of forest fuel is not more acidifying than sulphur that is mineralized from tree biomass if it is left in the forest instead of being burnt. The report gives an overview of the sulphur cycle in general together with the acidifying effect of sulphur. The sulphur content in wood biomass is about 1 mg/g in the needles and 0.2-0.3 mg/g in wood. Chipped forest fuel contains 0.2-0.5 mg S/g. A removal of 40 tonnes of felling residues per hectare may contain about 8-30 kg S. The sulphur occurs both in organic, often reduced, form and as sulphate. In situations of high availability to sulphur there will be an increased proportion of sulphate. After combustion some, perhaps half, of the sulphur is left in the ashes, most of which appears to be sulphate. In mineralisation of reduced organic sulphur, of type R-SH, the sulphur is released in the form of sulphide. Hydrogen sulphide, H2S, can be oxidised by microbes to sulphate, which should be acidifying (2 H+ will remain). A very rough estimate suggests that emissions of sulphur dioxide from forest fuel, spread over the period the trees are growing, and on the area from which the trees are taken, corresponds to 0.5% of the sulphur deposition in southern Sweden. Sulphur emissions from biofuel combustion are much lower than Sweden's and the EU's most stringent emission limits for coal. Whole-tree removal with return of ashes will theoretically give a considerable reduction in soil acidity since large quantities of nitrogen are removed and thus the acidifying effect of nitrogen will not occur. This should be of greater importance for forest acidification than the effect of biomass sulphur. 80 refs, numerous tabs

  3. Relation between particle size and properties of some bituminous coals

    Energy Technology Data Exchange (ETDEWEB)

    Palmer, A.D.; Cheng, M.; Goulet, J.-C.; Furimsky, E. (CANMET, Ottawa, ON (Canada). Energy Research Laboratories)

    1990-02-01

    Coal fractions of different size distributions exhibited different H/C ratio, ash and sulphur contents, and surface structures. This was confirmed using two low-sulphur and two high-sulphur bituminous coals. The effect was much less pronounced for low-sulphur coals than for high-sulphur coals. A significant difference in properties was noted between the two high-sulphur coals in spite of similar basic compositional parameters. This was confirmed by the fractal dimensionality factor D of Illinois No. 6 coal, which exceeded the theoretical value. 14 refs., 9 figs., 5 tabs.

  4. High-sulfur coal: tonnage and money at risk

    International Nuclear Information System (INIS)

    McMahan, R.L.; Knutson, K.S.

    1991-01-01

    More than 286 million tons of coal exceeds the Phase I standard i.e. 2.5 lb SO 2 per mmBtu, of the US Clean Air Act (1990). 85 mmtpy goes to currently scrubbed or unaffected (i.e. small) units. This leaves 201 mmtpy of high-sulphur coal at risk. 129 mmtpy of this is moving on a spot basis or is shipped under contracts that expire by 1995. This leaves about 72 mmtpy of captive and longterm contracts which many utility fuel buyers assume will be cancelled or renegotiated at a lower price. The legal position remains uncertain. However, the massive cancellation and/or renegotiation of existing contracts will have a tremendous economic impact on the coal industry. The resultant price change will in turn influence decisions to scrub or switch to low sulphur coals. 2 figs., 2 tabs

  5. Nuclear physical express analysis of solid fuel sulphur content

    International Nuclear Information System (INIS)

    Pak, Yu.; Ponomaryova, M

    2005-01-01

    Full text: Sulphur content is an important qualitative coal parameter. The problem of coal sulphur content determining remains one of the most important both in Kazakhstan and in other coal-mining countries. The traditional method of sampling, the final stage of which is chemical analysis of coal for sulphur, is characterized by high labour intensity and low productivity. That's why it is ineffective for mass express analytical quality control and technological schemes of coal processing control. In this connection it is very urgent to develop a method of coal sulphur content on the base of a series nuclear-geophysical equipment with an isotope source of primary radiation, allowing to increase analysis representativity and maximally take into account coal real composition inconstancy. To solve the problem set it is necessary to study the main laws of X-ray-radiometric method applied to the coal quality analysis for working out instrumental methods of speed determining of coal sulphur content with satisfactory accuracy for technological tasks, to determine laws of changing the flows of characteristic X-ray and scattered radiation from coal sulphur content of various real composition and to optimize methodical and hardware parameters, providing minimal error of sulphur content control. On the base of studying laws of real composition coal components and their interconnections with sulphur content there has been substantiated the expediency of using hardware functions of calcium and iron to control coal sulphur contents; there has been suggested a model to estimate the methodical error of coal sulphur content determining on the base of the data about sensitivity to sulphur and effecting factors using ultimate methods of coal components substitution methods allowing to optimize sulphur control parameters; there has been worked out an algorithm of X-ray-radiometric control of sulphur content based on the sequential radiating the analyzed coal with gamma-radiation of

  6. Distribution of volatile sulphur containing products during fixed bed pyrolysis and gasification of coals

    Energy Technology Data Exchange (ETDEWEB)

    Furimsky, E.

    1991-08-01

    Various coals were used to study the evolution of H{sub 2}S COS, and SO{sub 2} in a fixed bed reactor. For all types of coal, most of H{sub 2}S and SO{sub 2} were released during the devolatilization stage. COS was formed only during the gasification stage in the presence of CO{sub 2}.

  7. Environmental and economic gains of the conversion of the Zvolen (Slovakia) district CHP plant from low quality brown coal combustion to co-firing of biomass and low-sulphur brown coal

    International Nuclear Information System (INIS)

    Ilavsky, Jan; Jankovsky, Julius

    2006-01-01

    Zvolen CHP plant was originally commissioned in 1954. Overall installed output is 311 MW in heat production and 44,3 MW in power. Annual supply to the consumers was 788,910 GJ of heat and 102,459 GJ of electricity in 2004. Some 60 % of the heat production was used for heat and hot water supply to more than 9,000 houses and apartments and 40 % to industrial consumers. It uses pulverized lignite with up to 1 % of sulphur content as fuel. The content of sulphur in emitted flue gas is as high as 3,500-4,000 mg SO 2 /m 3 . It causes serious environmental problems in the region. New national limits for greenhouse gases emissions are 1.700 mg SO 2 /m 3 and 600 mg NO x /m 3 with effect from 1 January 2007. CHP is not able to achieve them without substantial improvement of technology with very high investment costs. Several alternatives of technical changes have been analysed in a study. Shift from lignite to low-sulphur content brown coal with co-firing of biomass has been identified economically most feasible and environmentally acceptable solution. The paper presents results of the study analysing the whole chain from biomass resources in the region up to the technical solutions for boilers reconstruction. The first part of the study was focused at identification of biomass resources for energy use from forestry, wood processing industry and agriculture. Ecological, economic and operational factors limiting utilization of potential biomass resources were identified and factored into calculations. Two boilers, each of them with the output of 108 MW t , will be reconstructed for co-firing of pulverized low sulphur content brown coal and biomass. Biomass will share up to 30% of the combusted fuel. After the reconstruction one boiler will remain with the same output of 108 MW t and the other will be with the output of 65 MW t . Power will be produced by the back pressure 25 MW e turbine. Chips will be stored in 9.000 m 3 open depot and in 3.000 m 3 silo. Chips will be fed

  8. Economics of coal-based electricity generation

    Energy Technology Data Exchange (ETDEWEB)

    Hemming, D F; Johnston, R; Teper, M

    1979-01-01

    The report deals with base-load electricity generation from coal and compares the economics of four alternative technologies: conventional pulverised-fuel (PF) boiler with steam cycle; atmospheric fluidised-bed (AFB) boiler with steam cycle; pressurised fluidised-bed (PFB) boiler with combined cycle; and integrated air-blown coal gasification with combined cycle systems are compared for both a high sulphur (3.5%) coal with environmental regulations requiring 85% sulphur removal, and for a low sulphur coal without sulphur removal. The results indicate that there is no single clear 'winner' among the advanced technologies. The optimum system depends on coal price, required rate-of-return, sulphur content of the coal, taxation regime etc. (34 refs.) (Available from IEA Coal Research, Economic Assessment Service)

  9. Impact of Sulphur Content on Coal Quality at Delta Plain Depositional Environment: Case study in Geramat District, Lahat Regency, South Sumatra

    Directory of Open Access Journals (Sweden)

    Siska Linda Sari

    2017-09-01

    Full Text Available The research was conducted in Geramat District of Lahat Regency, South Sumatra. An evaluation of the geological condition of the research area shown that the coal deposits were found in Muara Enim Formation as a coal-bearing formation. The method used was literature study, field observation and the laboratory work includes proximate and petrography analysis. The aim of this research is to determine the environmental condition of coal based on the change of total sulphur content and to know the relation between ash content to calorific value.  As the result of proximate analysis conducted on five samples of coal, the research area obtained total sulphur (0,21-1,54% adb, ash content (3,16 - 71,11% adb and gross calorific value (953 - 5676 cal/g. adb. Based on the result of maceral analysis showed the maceral percentage of coal in research area composed by vitrinite (77,8-87,4 %, liptinite (0,6 %, inertinite (8,0 – 17,6 % and mineral matter concentration in the form of pyrite (1,6-4,6 %. The average reflectance value of vitrinite (Rv of coal in the research area (0.54%. the results analysis shows that the coal in Muara Enim Formation on the research area is in the transitional lower delta plain depositional environment phase. Any changes in the sedimentary environment affected by sea water will be followed by changes in total sulphur and the higher ash content, on the contrary, the lower calorific value of the coal.

  10. Isotopic equilibria between sulphur solute species at high temperature

    International Nuclear Information System (INIS)

    Robinson, B.W.

    1978-01-01

    Sulphur solute species in ore solutions and geothermal discharges include HSO 4 - , SO 4 2- , H 2 S, and HS - , as well as the ion-paired species, NaHS 0 , NaHSO 4 - and Na 2 SO 4 0 . Observed sulphate-sulphide fractionation factors and the rates of attainment of isotopic equilibrium are likely to depend on the nature of the sulphur species actually taking part in these isotopic equilibria. Preliminary experiments in alkaline solution (pH 10.1 at 20 0 C) were carried out in a gold cell. No significant isotope fractionation was observed between the SO 4 2- and HS - in 29 days at 200 0 C, 63days at 300 0 C, or 90 days at 250 0 C. However, similar experiments at 350 0 C in sealed gold capsules at room temperature pH 8.5 showed slow exchange(t( 1 / 2 ) was calculated to be 510 days for the SO 4 2- -HS - exchange reaction using the theoretical fractionation of 20.2 0 / 00 ). The addition of NaCl appeared to have no affect on the exchange. However, pH strongly controls the reaction rate, and exchange probably involves H 2 S and the HSO 4 - ion. Additional preliminary experiments were conducted with a fivefold increase in the sulphur concentration; a decrease in t( 1 / 2 ) to 142 days resulted. Some inter-relationship between sulphur concentration and exchange rate thus exists. The important controlling parameters of isotope exchange (temperature, pH, and ΣS) can be seen to have influenced exchange in natural systems.(auth.)

  11. Sulphur isotopes as tracers of the influence of a coal-fired power plant on a Scots pine forest in Catalonia (NE Spain)

    Science.gov (United States)

    Puig, R.; Àvila, A.; Soler, A.

    Stable sulphur isotopes and major ionic composition were analysed in precipitation and throughfall samples from a Scots pine ( Pinus sylvestris, L.) forest near the Cercs coal-fired power plant (Catalonia, NE Spain). The purpose of the study was to determine the main sources of sulphur deposition on this pine forest. Sulphur isotope measurements from the SO 2 power plant stack emissions were used to identify the isotopic signature of this source. Net throughfall fluxes of sulphur (26.1 kg S ha 1 yr -1) and nitrogen (16.3 kg N ha -1 yr -1) were higher—5-25 times higher for S and 5-15 times for N—at this site than in other forests in Catalonia. Sulphur isotope analysis confirmed that the net throughfall fluxes of sulphur were mostly due to the dry deposition of the SO 2 power plant emissions onto the pine canopies. Two potential atmospheric end-members were distinguished: regional background rainwater (δ 34S=+7.2‰) and power plant emissions (δ 34S=-2.8‰). By applying a two-component sulphur isotope mixing model, we found that during periods of low power plant activity (⩽10 emission h day -1), 62% of the throughfall sulphate could be attributed to the power plant emissions. At higher activity periods (⩾14 emission h day -1), this contribution rose to 73%. Although power plant contribution to bulk deposition was lower in both cases (34% and 45%), the possible influence of sulphate coming with long-range transport events from the polluted areas in the Mediterranean basin (δ 34S≈0‰) was not discarded.

  12. Coal comes clean

    International Nuclear Information System (INIS)

    Minchener, A.

    1991-01-01

    Coal's status as the dominant fuel for electricity generation is under threat because of concern over the environmental impacts of acid rain and the greenhouse effect. Sulphur dioxide and nitrogen oxides cause acid rain and carbon dioxide is the main greenhouse gas. All are produced when coal is burnt. Governments are therefore tightening the emission limits for fossil-fuel power plants. In the United Kingdom phased reductions of sulphur dioxide and nitrogen oxides emissions are planned. It will be the responsibility of the power generator to take the necessary steps to reduce the emissions. This will be done using a number of technologies which are explained and outlined briefly - flue gas desulfurization, separation of coal into high and low-sulphur coal, direct desulfurization of coal, circulating fluidised bed combustion, integrated-gasification combined cycle systems and topping cycles. All these technologies are aiming at cleaner, more efficient combustion of coal. (UK)

  13. Concentration of volatile sulphur-containing compounds along the gastrointestinal tract of pigs fed a high-sulphur or a low-sulphur diet

    DEFF Research Database (Denmark)

    Poulsen, Henrik Vestergaard; Canibe, Nuria; Finster, Kai

    2010-01-01

    Volatile sulphur-containing compounds (VSC) are formed in large quantities in the gastrointestinal tract (GI-tract) of pigs and upon excretion from the animal; these compounds are released from the faeces causing emission of foul odour. However, very little is known about the rate and extent of t...

  14. The effect of sulphide and moisture content on steel corrosion during transport of fine wet coal

    International Nuclear Information System (INIS)

    Waanders, F. B.; Vorster, S. W.

    2013-01-01

    In the present investigation the influence of compaction pressure (stress) on the corrosivity of wet coal was investigated. Two coal samples, one high in sulphur content (3 %) and the other low in sulphur content (0.6 %) were used to determine the influence of compaction stress on the corrosion rates of steel samples in contact with compacted coal. It was found that the pressure exerted on finely divided wet coal is an important factor in determining its water content and corrosivity towards mild steel. Corrosion of the steel was typically in the form of pitting and the sulphur content of the coal was an important factor in determining the corrosivity of the coal. The corrosion rate of the high sulphur content coal was higher than that of the low sulphur coal. Mössbauer spectroscopy showed that a FeS species developed on the steel surface.

  15. Analysis of material flow in a utillzation technology of low grade manganese ore and sulphur coal complementary

    Science.gov (United States)

    Wang, Bo-Zhi; Deng, Biao; Su, Shi-Jun; Ding, Sang-Lan; Sun, Wei-Yi

    2018-03-01

    Electrolytic manganese is conventionally produced through low-grade manganese ore leaching in SO2, with the combustion of high sulfur coal. Subsequently the coal ash and manganese slag, produced by the combustion of high sulfur coal and preparation of electrolytic manganese, can be used as raw ingredients for the preparation of sulphoaluminate cement. In order to realize the `coal-electricity-sulfur-manganese-building material' system of complementary resource utilization, the conditions of material inflow and outflow in each process were determined using material flow analysis. The material flow models in each unit and process can be obtained by analyzed of material flow for new technology, and the input-output model could be obtained. Through the model, it is possible to obtain the quantity of all the input and output material in the condition of limiting the quantity of a substance. Taking one ton electrolytic manganese as a basis, the quantity of other input material and cements can be determined with the input-output model. The whole system had thusly achieved a cleaner production level. Therefore, the input-output model can be used for guidance in practical production.

  16. Origin of organic sulphur compounds and sulphur-containing high molecular weight substances in sediments and immature crude oils

    NARCIS (Netherlands)

    Sinninghe Damsté, J.S.; Rijpstra, W.I.C.; Leeuw, J.W. de; Schenck, P.A.

    1988-01-01

    The distribution patterns of Organic Sulphur Compounds (OSC), occurring in certain sediments and immature crude oils, were compared with those of the corresponding hydrocarbons. Because of the complexity of the OSC mixtures, they were desulphurized to hydrocarbons (n-alkanes, isoprenoid alkanes,

  17. Modification of oxide inclusions in calcium-treated Al-killed high sulphur steels

    NARCIS (Netherlands)

    Gollapalli, Veerababu; Rao, M.B.Venkata; Karamched, P.S.; Borra, C.R.; Roy, G.G.; Srirangam, Prakash

    2018-01-01

    A study has been carried out to understand the modification of alumina inclusions in Al-killed high sulphur steel with calcium treatment. For calcium treatment to be effective, a general practice is to desulphurise the steel to prevent the formation of solid CaS inclusions that are harmful to

  18. The clean coal technologies for lignitic coal power generation in Pakistan

    International Nuclear Information System (INIS)

    Mir, S.; Raza, Z.; Aziz-ur-Rehman, A.

    1995-01-01

    Pakistan contains huge reserves of lignitic coals. These are high sulphur, high ash coals. In spite of this unfortunate situation, the heavy demand for energy production, requires the development utilization of these indigenous coal reserves to enhance energy production. The central of the environmental pollution caused by the combustion of these coals has been a major hindrance in their utilization. Recently a substantial reduction in coal combustion emissions have been achieved through the development of clean coal technologies. Pakistan through the transfer and adaptation of the advanced clean coal technologies can utilize incurring the high sulphur coals for energy production without incurring the environmental effects that the developed countries have experienced in the past. The author discusses the recently developed clean coal utilization technologies, their applications economies and feasibility of utilization with specific reference to Pakistan''s coal. (author)

  19. Quantification of sulphur amino acids by ultra-high performance liquid chromatography in aquatic invertebrates.

    Science.gov (United States)

    Thera, Jennifer C; Kidd, Karen A; Dodge-Lynch, M Elaine; Bertolo, Robert F

    2017-12-15

    We examined the performance of an ultra-high performance liquid chromatography method to quantify protein-bound sulphur amino acids in zooplankton. Both cysteic acid and methionine sulfone were linear from 5 to 250 pmol (r 2  = 0.99), with a method detection limit of 13 pmol and 9 pmol, respectively. Although there was no matrix effect on linearity, adjacent peaks and co-eluting noise from the invertebrate proteins increased the detection limits when compared to common standards. Overall, performance characteristics were reproducible and accurate, and provide a means for quantifying sulphur amino acids in aquatic invertebrates, an understudied group. Copyright © 2017 Elsevier Inc. All rights reserved.

  20. Sulphur output from oil sands : dramatically changing Alberta's sulphur balance

    International Nuclear Information System (INIS)

    D'Aquin, G.

    2008-01-01

    This paper discussed sulphur production from Alberta's gas and oil sands industries. While sulfur derived from natural gas production in the province is expected to decline as natural gas reserves diminish, Alberta's oil sands contain high amounts of sulphur. It is not yet known how much sulphur will be produced from the province's oil sands facilities. Alberta had considerable stockpiles of sulphur in the 1970s. By 1980, inventories began to decline. By 1996, output had increased to 7.1 million tonnes. Alberta's sulphur inventory reached 9.7 million tonnes following the collapse of the Soviet Union's government mandated fertilizer industry. In 2006, sulphur supplies in Alberta reached 12 million tonnes. Reduced global output has now lowered sulphur stockpiles. Increases in sulphur prices tend to reduce market demand, and lower prices will not typically change the volume of sulphur produced as a byproduct of oil and gas operations. Bitumen-derived sulphur output is expected to exceed gas-derived sulphur output in the near future. Sulphur from oil sands processing is expected to increase by 5 million tonnes by 2017. Increased sulphur production levels in Alberta will present a significant challenge for all sectors of the hydrocarbon industry. It was concluded that developing a plan for storing, selling or disposing of the sulphur will help to ensure the profitability of oil sands operations

  1. Study of the corrosion of metallic coatings and alloys containing aluminum in a mixed atmosphere - sulphur, oxygen - at high temperatures

    International Nuclear Information System (INIS)

    Fellmann, Daniel

    1982-01-01

    The objective of this research thesis is the development of materials for a sulphur experimental loop allowing the thermodynamic properties of such an energy cycle to be checked. As solutions must comply with industrial methods, rare materials are excluded as they are too expensive or difficult to implement. Iron-based materials have been tested but could not have at the same time a good corrosion resistance and high temperature forming and mechanical toughness properties. Therefore, metallic coatings have been chosen, specifically alumina. After having reported a bibliographical study on corrosion by sulphur vapour and by oxygen and by sulphur-oxygen, the author presents the experimental materials and methods. Then, the author reports the study of mixed corrosion (by sulphur and oxygen together) of metallic alloys (ferritic and austeno-ferritic alloys, aluminium and titanium alloys), and of the corrosion of FeAlx coatings, of AlTix alloys [fr

  2. Influence of sulphur and phosphorus on the hot deformation of Fe-Cr 13% high purity steel

    International Nuclear Information System (INIS)

    Lahreche, M.; Bouzabata, B.; Kobylanski, A.

    1995-01-01

    A series of Fe-Cr13%-C high purity steels containing increasing volume fractions of Sulphur (30, 60 and 100ppm) and Phosphorus (30, 60 and 100ppm) were prepared in order to study their hot deformation properties by tensile tests at various strain rates (10 -1 s -1 to 10 -4 s -1 ) and at temperatures from 700 C to 1100 C. It is observed that the hot ductility is lowered at 1000 C with the addition of sulphur. However, this decrease is relatively small (about 30% for 100ppm of sulphur) and quite similar for all additions of sulphur. When phosphorus is added, the embrittlement is along the whole deformed specimen. The usual criteria of ductility by parameter Z do not seem to be sufficient to describe this embrittlement. (orig.)

  3. Ball-milling synthesis of ZnO@sulphur/carbon nanotubes and Ni(OH)_2@sulphur/carbon nanotubes composites for high-performance lithium-sulphur batteries

    International Nuclear Information System (INIS)

    Gu, Xingxing; Tong, Chuan-jia; Wen, Bo; Liu, Li-min; Lai, Chao; Zhang, Shanqing

    2016-01-01

    Highlights: • Metal oxides or hydroxides coating sulfur-based composite are successfully prepared. • Large-scale synthesis can be realized via the facile wet ball-milling strategy. • Density functional theory (DFT) calculation is applied to calculate adsorption energy. • ZnO exhibits a higher adsorption energy for Li_2S_8 than that Ni(OH)_2. • ZnO@sulphur/carbon nanotubes composite show excellent cycle and discharge performance. - Abstract: Zinc oxide wrapped sulphur/carbon nanotubes (ZnO@S/CNT) and nickel hydroxide wrapped sulphur/carbon nanotubes (Ni(OH)_2@S/CNT) nanocomposites are prepared using a simple, low cost and scalable ball-milling method. As the cathodes in Li-S batteries, the as-prepared ZnO@S/CNT composite illustrates a superior high initial capacity of 1663 mAh g"−"1 at a charge/discharge rate of 160 mA g"−"1, and maintains a reversible capacity at approximately 942 mAh g"−"1 after 70 cycles. While for Ni(OH)_2@S/CNT composites, its initial capacity is also as high as 1331 mAh g"−"1, but a poorer cycling stability is presented. When the charge/discharge current is increased to 1600 mA g"−"1, a high reversible capacity of 698 mAh g"−"1 after 200 cycles still can be obtained for the ZnO@S/CNT composite, far better than that of Ni(OH)_2@S/CNT composites. The better cycling performance and high discharge capacity can be attributed to the strong interactions between ZnO and S_x"2"− species, which is verified by the density functional theory (DFT) calculation result that the ZnO exhibits a higher adsorption energy for Li_2S_8 than the Ni(OH)_2.

  4. HIGH PRESSURE COAL COMBUSTON KINETICS PROJECT

    Energy Technology Data Exchange (ETDEWEB)

    Stefano Orsino

    2005-03-30

    As part of the U.S. Department of Energy (DoE) initiative to improve the efficiency of coal-fired power plants and reduce the pollution generated by these facilities, DOE has funded the High-Pressure Coal Combustion Kinetics (HPCCK) Projects. A series of laboratory experiments were conducted on selected pulverized coals at elevated pressures with the specific goals to provide new data for pressurized coal combustion that will help extend to high pressure and validate models for burnout, pollutant formation, and generate samples of solid combustion products for analyses to fill crucial gaps in knowledge of char morphology and fly ash formation. Two series of high-pressure coal combustion experiments were performed using SRI's pressurized radiant coal flow reactor. The first series of tests characterized the near burner flame zone (NBFZ). Three coals were tested, two high volatile bituminous (Pittsburgh No.8 and Illinois No.6), and one sub-bituminous (Powder River Basin), at pressures of 1, 2, and 3 MPa (10, 20, and 30 atm). The second series of experiments, which covered high-pressure burnout (HPBO) conditions, utilized a range of substantially longer combustion residence times to produce char burnout levels from 50% to 100%. The same three coals were tested at 1, 2, and 3 MPa, as well as at 0.2 MPa. Tests were also conducted on Pittsburgh No.8 coal in CO2 entrainment gas at 0.2, 1, and 2 MPa to begin establishing a database of experiments relevant to carbon sequestration techniques. The HPBO test series included use of an impactor-type particle sampler to measure the particle size distribution of fly ash produced under complete burnout conditions. The collected data have been interpreted with the help of CFD and detailed kinetics simulation to extend and validate devolatilization, char combustion and pollutant model at elevated pressure. A global NOX production sub-model has been proposed. The submodel reproduces the performance of the detailed chemical

  5. Capital cost: high and low sulfur coal plants-1200 MWe. [High sulfur coal

    Energy Technology Data Exchange (ETDEWEB)

    1977-01-01

    This Commercial Electric Power Cost Study for 1200 MWe (Nominal) high and low sulfur coal plants consists of three volumes. The high sulfur coal plant is described in Volumes I and II, while Volume III describes the low sulfur coal plant. The design basis and cost estimate for the 1232 MWe high sulfur coal plant is presented in Volume I, and the drawings, equipment list and site description are contained in Volume II. The reference design includes a lime flue gas desulfurization system. A regenerative sulfur dioxide removal system using magnesium oxide is also presented as an alternate in Section 7 Volume II. The design basis, drawings and summary cost estimate for a 1243 MWe low sulfur coal plant are presented in Volume III. This information was developed by redesigning the high sulfur coal plant for burning low sulfur sub-bituminous coal. These coal plants utilize a mechanical draft (wet) cooling tower system for condenser heat removal. Costs of alternate cooling systems are provided in Report No. 7 in this series of studies of costs of commercial electrical power plants.

  6. Discharging a Li-S battery with ultra-high sulphur content cathode using a redox mediator.

    Science.gov (United States)

    Kim, Kwi Ryong; Lee, Kug-Seung; Ahn, Chi-Yeong; Yu, Seung-Ho; Sung, Yung-Eun

    2016-08-30

    Lithium-sulphur batteries are under intense research due to the high specific capacity and low cost. However, several problems limit their commercialization. One of them is the insulating nature of sulphur, which necessitates a large amount of conductive agent and binder in the cathode, reducing the effective sulphur load as well as the energy density. Here we introduce a redox mediator, cobaltocene, which acts as an electron transfer agent between the conductive surface and the polysulphides in the electrolyte. We confirmed that cobaltocene could effectively convert polysulphides to Li2S using scanning electron microscope, X-ray absorption near-edge structure and in-situ X-ray diffraction studies. This redox mediator enabled excellent electrochemical performance in a cathode with ultra-high sulphur content (80 wt%). It delivered 400 mAh g(-1)cathode capacity after 50 cycles, which is equivalent to 800 mAh g(-1)S in a typical cathode with 50 wt% sulphur. Furthermore, the volumetric capacity was also dramatically improved.

  7. Enhanced high temperature thermoelectric response of sulphuric acid treated conducting polymer thin films

    KAUST Repository

    Sarath Kumar, S. R.; Kurra, Narendra; Alshareef, Husam N.

    2015-01-01

    We report the high temperature thermoelectric properties of solution processed pristine and sulphuric acid treated poly(3, 4-ethylenedioxythiophene):poly(4-styrenesulfonate) (or PEDOT:PSS) films. The acid treatment is shown to simultaneously enhance the electrical conductivity and Seebeck coefficient of the metal-like films, resulting in a five-fold increase in thermoelectric power factor (0.052 W/m. K ) at 460 K, compared to the pristine film. By using atomic force micrographs, Raman and impedance spectra and using a series heterogeneous model for electrical conductivity, we demonstrate that acid treatment results in the removal of PSS from the films, leading to the quenching of accumulated charge-induced energy barriers that prevent hopping conduction. The continuous removal of PSS with duration of acid treatment also alters the local band structure of PEDOT:PSS, resulting in simultaneous enhancement in Seebeck coefficient.

  8. Clean utilization of high sulphur petroleum coke by circulating fluidized bed combustion (CFBC) in Romania

    International Nuclear Information System (INIS)

    Dragos, L.; Flueraru, C.; Girjoaba, M.

    1996-01-01

    The economic and environmental problems caused by inefficient utilization of residual high-sulphur petroleum coke resulted from oil cracking in Romania is discussed. A special research programme applying CFBC technology has been carried out in the Institute for Power Equipment, Bucharest. The results from both laboratory facilities and pilot plant are presented. The main operating conditions and parameters are pointed out. Data on quality and composition of petroleum coke, combustion efficiency, temperature range in different zones and flue gas composition at distinct operating loads are given. The results obtained will be used for innovative design of CFBC boilers based on petroleum coke. A project for implementing a CFBC boiler in one of the Romanian oil refineries is being developed. An analysis of technical and economic advantages of these boilers for energy generation is presented

  9. Enhanced high temperature thermoelectric response of sulphuric acid treated conducting polymer thin films

    KAUST Repository

    Sarath Kumar, S. R.

    2015-11-24

    We report the high temperature thermoelectric properties of solution processed pristine and sulphuric acid treated poly(3, 4-ethylenedioxythiophene):poly(4-styrenesulfonate) (or PEDOT:PSS) films. The acid treatment is shown to simultaneously enhance the electrical conductivity and Seebeck coefficient of the metal-like films, resulting in a five-fold increase in thermoelectric power factor (0.052 W/m. K ) at 460 K, compared to the pristine film. By using atomic force micrographs, Raman and impedance spectra and using a series heterogeneous model for electrical conductivity, we demonstrate that acid treatment results in the removal of PSS from the films, leading to the quenching of accumulated charge-induced energy barriers that prevent hopping conduction. The continuous removal of PSS with duration of acid treatment also alters the local band structure of PEDOT:PSS, resulting in simultaneous enhancement in Seebeck coefficient.

  10. Design and modeling of an advanced marine machinery system including waste heat recovery and removal of sulphur oxides

    DEFF Research Database (Denmark)

    Frimann Nielsen, Rasmus; Haglind, Fredrik; Larsen, Ulrik

    2014-01-01

    the efficiency of machinery systems. The wet sulphuric acid process is an effective way of removing flue gas sulphur oxides from land-based coal-fired power plants. Moreover, organic Rankine cycles (ORC) are suitable for heat to power conversion for low temperature heat sources. This paper describes the design...... that an ORC placed after the conventional waste heat recovery system is able to extract the sulphuric acid from the exhaust gas, while at the same time increase the combined cycle thermal efficiency by 2.6%. The findings indicate that the technology has potential in marine applications regarding both energy...... and modeling of a highly efficient machinery system which includes the removal of exhaust gas sulphur oxides. The system consists of a two-stroke diesel engine, the wet sulphuric process for sulphur removal, a conventional steam Rankine cycle and an ORC. Results of numerical modeling efforts suggest...

  11. Baking and coking properties of hard coal under high pressure

    Energy Technology Data Exchange (ETDEWEB)

    Beyer, H.D.

    1981-09-01

    For a better assessment of the baking and coking properties of hard coal under high pressure as in modern coal beneficiation processes, the determination of the swelling index and the dilatation curve are investigated.

  12. Solving the sulphur situation : research assesses viability of burying sulphur

    International Nuclear Information System (INIS)

    Proce, B.

    2006-01-01

    Oil sands mining companies are looking for ways to manage growing levels of sulphur production from the Athabasca region. Infrastructure is not in place to economically transport the sulphur even though there is a global market for it. Sulphur cannot be stockpiled indefinitely as it can react with air to produce sulphur dioxide. Although above-ground sulphur storage has been regulated for more than 30 years, the underground storage of sulphur is still in a research and development phase. Alberta Sulphur Research Ltd. is currently conducting an ongoing experiment in which 100 tonne test blocks have been buried above and below the water table so that surrounding areas could be monitored over a period of years. A series of tests is being conducted to examine changes in pH in water and sulphate levels. A multi-layered engineering casing to contain the sulphur and prevent seepage is also being investigated. Once stored underground, operators also have to consider how the sulphur will be accessed in the future, as it is subject to government royalties. The storage of sulphur may have economic benefits as the product can be sold when prices are high. Most sulphur produced in Alberta is sold as an export product in the United States for use in products such as fertilizer. Shell Canada penetrated the Chinese market in 2001 and has since become one of Canada's largest sulphur exporters. Shell has also introduced a number of products using sulphur, including fertilizers, enhanced asphalt, and concrete. It was concluded that companies must take action now to mitigate future losses and to utilize current markets in order to remain competitive. 3 figs

  13. Unstacked double-layer templated graphene for high-rate lithium-sulphur batteries

    Science.gov (United States)

    Zhao, Meng-Qiang; Zhang, Qiang; Huang, Jia-Qi; Tian, Gui-Li; Nie, Jing-Qi; Peng, Hong-Jie; Wei, Fei

    2014-03-01

    Preventing the stacking of graphene is essential to exploiting its full potential in energy-storage applications. The introduction of spacers into graphene layers always results in a change in the intrinsic properties of graphene and/or induces complexity at the interfaces. Here we show the synthesis of an intrinsically unstacked double-layer templated graphene via template-directed chemical vapour deposition. The as-obtained graphene is composed of two unstacked graphene layers separated by a large amount of mesosized protuberances and can be used for high-power lithium-sulphur batteries with excellent high-rate performance. Even after 1,000 cycles, high reversible capacities of ca. 530 mA h g-1 and 380 mA h g-1 are retained at 5 C and 10 C, respectively. This type of double-layer graphene is expected to be an important platform that will enable the investigation of stabilized three-dimensional topological porous systems and demonstrate the potential of unstacked graphene materials for advanced energy storage, environmental protection, nanocomposite and healthcare applications.

  14. Feasibility of high-resolution continuum source molecular absorption spectrometry in flame and furnace for sulphur determination in petroleum products

    Science.gov (United States)

    Kowalewska, Zofia

    2011-07-01

    For the first time, high-resolution molecular absorption spectrometry with a high-intensity xenon lamp as radiation source has been applied for the determination of sulphur in crude oil and petroleum products. The samples were analysed as xylene solutions using vaporisation in acetylene-air flame or in an electrothermally heated graphite furnace. The sensitive rotational lines of the CS molecule, belonging to the ∆ν = 0 vibrational sequence within the electronic transition X 1∑ + → A 1П, were applied. For graphite furnace molecular absorption spectrometry, the Pd + Mg organic modifier was selected. Strong interactions with Pd atoms enable easier decomposition of sulphur-containing compounds, likely through the temporal formation of Pd xS y molecules. At the 258.056 nm line, with the wavelength range covering central pixel ± 5 pixels and with application of interactive background correction, the detection limit was 14 ng in graphite furnace molecular absorption spectrometry and 18 mg kg -1 in flame molecular absorption spectrometry. Meanwhile, application of 2-points background correction found a characteristic mass of 12 ng in graphite furnace molecular absorption spectrometry and a characteristic concentration of 104 mg kg -1 in flame molecular absorption spectrometry. The range of application of the proposed methods turned out to be significantly limited by the properties of the sulphur compounds of interest. In the case of volatile sulphur compounds, which can be present in light petroleum products, severe difficulties were encountered. On the contrary, heavy oils and residues from distillation as well as crude oil could be analysed using both flame and graphite furnace vaporisation. The good accuracy of the proposed methods for these samples was confirmed by their mutual consistency and the results from analysis of reference samples (certified reference materials and home reference materials with sulphur content determined by X-ray fluorescence

  15. Feasibility of high-resolution continuum source molecular absorption spectrometry in flame and furnace for sulphur determination in petroleum products

    Energy Technology Data Exchange (ETDEWEB)

    Kowalewska, Zofia, E-mail: zofia.kowalewska@obr.pl

    2011-07-15

    For the first time, high-resolution molecular absorption spectrometry with a high-intensity xenon lamp as radiation source has been applied for the determination of sulphur in crude oil and petroleum products. The samples were analysed as xylene solutions using vaporisation in acetylene-air flame or in an electrothermally heated graphite furnace. The sensitive rotational lines of the CS molecule, belonging to the {Delta}{nu} = 0 vibrational sequence within the electronic transition X{sup 1}{Sigma}{sup +} {yields} A{sup 1}{Pi}, were applied. For graphite furnace molecular absorption spectrometry, the Pd + Mg organic modifier was selected. Strong interactions with Pd atoms enable easier decomposition of sulphur-containing compounds, likely through the temporal formation of Pd{sub x}S{sub y} molecules. At the 258.056 nm line, with the wavelength range covering central pixel {+-} 5 pixels and with application of interactive background correction, the detection limit was 14 ng in graphite furnace molecular absorption spectrometry and 18 mg kg{sup -1} in flame molecular absorption spectrometry. Meanwhile, application of 2-points background correction found a characteristic mass of 12 ng in graphite furnace molecular absorption spectrometry and a characteristic concentration of 104 mg kg{sup -1} in flame molecular absorption spectrometry. The range of application of the proposed methods turned out to be significantly limited by the properties of the sulphur compounds of interest. In the case of volatile sulphur compounds, which can be present in light petroleum products, severe difficulties were encountered. On the contrary, heavy oils and residues from distillation as well as crude oil could be analysed using both flame and graphite furnace vaporisation. The good accuracy of the proposed methods for these samples was confirmed by their mutual consistency and the results from analysis of reference samples (certified reference materials and home reference materials with

  16. The production of high load coal-water mixtures on the base of Kansk-Achinsk Coal Basin

    Energy Technology Data Exchange (ETDEWEB)

    Demidov, Y.; Bruer, G.; Kolesnikova, S. [Research and Design Institute for Problems of Development of Kansk-Achinsk Coal Basin (KATEKNilugol), Krasnoyarsk (Russian Federation)

    1995-12-01

    The results of the {open_quotes}KATEKNIIugol{close_quotes} work on the problems of high load coal-water mixtures are given in this article. General principles of the mixture production, short characteristics of Kansk-Achinsk coals, the experimental results of the coal mixture production on a test-industrial scale, the suspension preparation on the base of coal mixtures, technical-economical indexes of tested coal pipeline variants based on Kansk-Achinsk coals are described.

  17. Variations in pore characteristics in high volatile bituminous coals: Implications for coal bed gas content

    Science.gov (United States)

    Mastalerz, Maria; Drobniak, A.; Strapoc, D.; Solano-Acosta, W.; Rupp, J.

    2008-01-01

    The Seelyville Coal Member of the Linton Formation (Pennsylvanian) in Indiana was studied to: 1) understand variations in pore characteristics within a coal seam at a single location and compare these variations with changes occurring between the same coal at different locations, 2) elaborate on the influence of mineral-matter and maceral composition on mesopore and micropore characteristics, and 3) discuss implications of these variations for coal bed gas content. The coal is high volatile bituminous rank with R0 ranging from 0.57% to 0.60%. BET specific surface areas (determined by nitrogen adsorption) of the coals samples studied range from 1.8 to 22.9??m2/g, BJH adsorption mesopore volumes from 0.0041 to 0.0339??cm3/g, and micropore volumes (determined by carbon dioxide adsorption) from 0.0315 to 0.0540??cm3/g. The coals that had the largest specific surface areas and largest mesopore volumes occur at the shallowest depths, whereas the smallest values for these two parameters occur in the deepest coals. Micropore volumes, in contrast, are not depth-dependent. In the coal samples examined for this study, mineral-matter content influenced both specific surface area as well as mesopore and micropore volumes. It is especially clear in the case of micropores, where an increase in mineral-matter content parallels the decrease of micropore volume of the coal. No obvious relationships were observed between the total vitrinite content and pore characteristics but, after splitting vitrinite into individual macerals, we see that collotelinite influences both meso- and micropore volume positively, whereas collodetrinite contributes to the reduction of mesopore and micropore volumes. There are large variations in gas content within a single coal at a single location. Because of this variability, the entire thickness of the coal must be desorbed in order to determine gas content reliably and to accurately calculate the level of gas saturation. ?? 2008 Elsevier B.V. All

  18. The fate of sulphur in the Cu-based Chemical Looping with Oxygen Uncoupling (CLOU) Process

    International Nuclear Information System (INIS)

    Adánez-Rubio, Iñaki; Abad, Alberto; Gayán, Pilar; García-Labiano, Francisco; Diego, Luis F. de; Adánez, Juan

    2014-01-01

    Highlights: • 15 h of CLOU experiments using lignite were carried out in a continuously unit. • The sulphur split between fuel- and air-reactor streams in the process was analysed. • Most of the sulphur introduced with the fuel exits as SO 2 at the fuel-reactor. • The use of a carbon separation system to reduce the S emission was evaluated. • Coals with high S content can be burnt in a CLOU process with a Cu-based material. - Abstract: The Chemical Looping with Oxygen Uncoupling (CLOU) process is a type of Chemical Looping Combustion (CLC) technology that allows the combustion of solid fuels with air, as with conventional combustion, through the use of oxygen carriers that release gaseous oxygen inside the fuel reactor. The aim of this work was to study the behaviour of the sulphur present in fuel during CLOU combustion. Experiments using lignite as fuel were carried out in a continuously operated 1.5 kW th CLOU unit during more than 15 h. Particles containing 60 wt.% CuO on MgAl 2 O 4 , prepared by spray drying, were used as the oxygen carrier in the CLOU process. The temperature in the fuel reactor varied between 900 and 935 °C. CO 2 capture, combustion efficiency and the sulphur split between fuel and air reactor streams in the process were analysed. Complete combustion of the fuel to CO 2 and H 2 O was found in all experiments. Most of the sulphur introduced with the fuel exited as SO 2 at the fuel reactor outlet, although a small amount of SO 2 was measured at the air reactor outlet. The SO 2 concentration in the air reactor exit flow decreased as the temperature in the fuel reactor increased. A carbon capture efficiency of 97.6% was achieved at 935 °C, with 87.9 wt.% of the total sulphur exiting as SO 2 in the fuel reactor. Both the reactivity and oxygen transport capacity of the oxygen carrier were unaffected during operation with a high sulphur content fuel, and agglomeration problems did not occur. Predictions were calculated regarding the use

  19. A new approach for the determination of sulphur in food samples by high-resolution continuum source flame atomic absorption spectrometer.

    Science.gov (United States)

    Ozbek, N; Baysal, A

    2015-02-01

    The new approach for the determination of sulphur in foods was developed, and the sulphur concentrations of various fresh and dried food samples determined using a high-resolution continuum source flame atomic absorption spectrometer with an air/acetylene flame. The proposed method was optimised and the validated using standard reference materials, and certified values were found to be within the 95% confidence interval. The sulphur content of foods ranged from less than the LOD to 1.5mgg(-1). The method is accurate, fast, simple and sensitive. Copyright © 2014 Elsevier Ltd. All rights reserved.

  20. Sulphur capture by co-firing sulphur containing fuels with biomass fuels - optimization

    International Nuclear Information System (INIS)

    Nordin, A.

    1992-12-01

    Previous results concerning co-firing of high sulphur fuels with biomass fuels have shown that a significant part of the sulphur can be absorbed in the ash by formation of harmless sulphates. The aim of this work has been to (i) determine the maximum reduction that can be obtained in a bench scaled fluidized bed (5 kW); (ii) determine which operating conditions will give maximum reduction; (iii) point out the importance and applicability of experimental designs and multivariate methods when optimizing combustion processes; (iv) determine if the degree of sulphur capture can be correlated to the degree of slagging, fouling or bed sintering; and (v) determine if further studies are desired. The following are some of the more important results obtained: - By co-firing peat with biomass, a total sulphur retention of 70 % can be obtained. By co-firing coal with energy-grass, the total SO 2 emissions can be reduced by 90 %. - Fuel feeding rate, amount of combustion air and the primary air ratio were the most important operating parameters for the reduction. Bed temperature and oxygen level seem to be the crucial physical parameters. - The NO emissions also decreased by the sulphur reducing measures. The CO emissions were relatively high (130 mg/MJ) compared to large scale facilities due to the small reactor and the small fluctuations in the fuel feeding rate. The SO 2 emissions could however be reduced without any increase in CO emissions. - When the reactor was fired with a grass, the bed sintered at a low temperature ( 2 SO 4 and KCl are formed no sintering problems were observed. (27 refs., 41 figs., 9 tabs., 3 appendices)

  1. High pressure axial flow fans for modern coal power stations

    Energy Technology Data Exchange (ETDEWEB)

    Cyrus, Vaclav [AHT Energetika s.r.o., Praha (Czech Republic); Koci, Petr [ZVVZ Milevsko a.s. (Czech Republic)

    2008-07-01

    Brown coal fired power stations, located in Northern Bohemia, have mostly older boiler blocks with an output of 110 and 200 MWe. Flue gases are cleaned by the desulphurization plants installed between 1993 and 1997. Usually, each boiler block has two air fans and one to three flue gas fans. Flue gas fans operate in severe conditions; fan blades should be resistant to the flue gases containing sulphur and acid drops with the operating temperature at 170 C to 190 C. Additionally, flue gas also often contains ash particles. Currently, some boiler blocks are gradually being refurbished. New blocks with an electrical power output of 600 to 700 MWe are at the design stage. Submitted paper shows our design study of one stage axial flow fan for the new blocks. Results from the new aerodynamic research of the axial flow stages were used in the fan design. (orig.)

  2. Sulphur output from oil sands : dramatically changing Alberta's sulphur balance

    Energy Technology Data Exchange (ETDEWEB)

    D' Aquin, G. [Con-Sul Inc., Bigfork, MT (United States)

    2008-07-01

    This paper discussed sulphur production from Alberta's gas and oil sands industries. While sulfur derived from natural gas production in the province is expected to decline as natural gas reserves diminish, Alberta's oil sands contain high amounts of sulphur. It is not yet known how much sulphur will be produced from the province's oil sands facilities. Alberta had considerable stockpiles of sulphur in the 1970s. By 1980, inventories began to decline. By 1996, output had increased to 7.1 million tonnes. Alberta's sulphur inventory reached 9.7 million tonnes following the collapse of the Soviet Union's government mandated fertilizer industry. In 2006, sulphur supplies in Alberta reached 12 million tonnes. Reduced global output has now lowered sulphur stockpiles. Increases in sulphur prices tend to reduce market demand, and lower prices will not typically change the volume of sulphur produced as a byproduct of oil and gas operations. Bitumen-derived sulphur output is expected to exceed gas-derived sulphur output in the near future. Sulphur from oil sands processing is expected to increase by 5 million tonnes by 2017. Increased sulphur production levels in Alberta will present a significant challenge for all sectors of the hydrocarbon industry. It was concluded that developing a plan for storing, selling or disposing of the sulphur will help to ensure the profitability of oil sands operations.

  3. Gasification of high ash, high ash fusion temperature bituminous coals

    Science.gov (United States)

    Liu, Guohai; Vimalchand, Pannalal; Peng, WanWang

    2015-11-13

    This invention relates to gasification of high ash bituminous coals that have high ash fusion temperatures. The ash content can be in 15 to 45 weight percent range and ash fusion temperatures can be in 1150.degree. C. to 1500.degree. C. range as well as in excess of 1500.degree. C. In a preferred embodiment, such coals are dealt with a two stage gasification process--a relatively low temperature primary gasification step in a circulating fluidized bed transport gasifier followed by a high temperature partial oxidation step of residual char carbon and small quantities of tar. The system to process such coals further includes an internally circulating fluidized bed to effectively cool the high temperature syngas with the aid of an inert media and without the syngas contacting the heat transfer surfaces. A cyclone downstream of the syngas cooler, operating at relatively low temperatures, effectively reduces loading to a dust filtration unit. Nearly dust- and tar-free syngas for chemicals production or power generation and with over 90%, and preferably over about 98%, overall carbon conversion can be achieved with the preferred process, apparatus and methods outlined in this invention.

  4. Unexpectedly high uptake of palladium by bituminous coals

    Energy Technology Data Exchange (ETDEWEB)

    Lakatos, J. [Research Lab. for Mining Chemistry, Hungarian Academy of Sciences, Miskolc-Egyetemvaros (Hungary); Brown, S.D.; Snape, C.E. [Univ. of Strathclyde, Dept. of Pure and Applied Chemistry, Glasgow (United Kingdom)

    1997-12-31

    The uptake of palladium as a conversion catalyst onto coals of different rank was investigated. Palladium fixation occurs by a different mode to that for alkaline earth and first row transition metals. Therefore, the dispersion of relatively high concentration of palladium by an ion sorption process is even possible for bituminous coals. (orig.)

  5. Studies on the effect of coal particle size on biodepyritization of high sulfur coal in batch bioreactor

    Directory of Open Access Journals (Sweden)

    Singh Sradhanjali

    2015-03-01

    Full Text Available The moderate thermophilic mix culture bacteria were used to depyritize the Illinois coal of varying particle sizes (-100 μm, 100-200 μm, +200 μm. Mineral libration analysis showed the presence of pyrite along with other minerals in coal. Microbial depyritization of coal was carried out in stirred tank batch reactors in presence of an iron-free 9K medium. The results indicate that microbial depyritization of coal using moderate thermophiles is an efficient process. Moreover, particle size of coal is an important parameter which affects the efficiency of microbial depyritization process. At the end of the experiment, a maximum of 75% pyrite and 66% of pyritic sulphur were removed from the median particle size. The XRD analysis showed the absence of pyrite mineral in the treated coal sample. A good mass balance was also obtained with net loss of mass ranging from 5-9% showing the feasibility of the process for large scale applications.

  6. High-performance graphene/sulphur electrodes for flexible Li-ion batteries using the low-temperature spraying method

    KAUST Repository

    Kumar, Pushpendra

    2015-01-01

    Elementary sulphur (S) has been shown to be an excellent cathode material in energy storage devices such as Li-S batteries owing to its very high capacity. The major challenges associated with the sulphur cathodes are structural degradation, poor cycling performance and instability of the solid-electrolyte interphase caused by the dissolution of polysulfides during cycling. Tremendous efforts made by others have demonstrated that encapsulation of S materials improves their cycling performance. To make this approach practical for large scale applications, the use of low-cost technology and materials has become a crucial and new focus of S-based Li-ion batteries. Herein, we propose to use a low temperature spraying process to fabricate graphene/S electrode material, where the ink is composed of graphene flakes and the micron-sized S particles prepared by grinding of low-cost S powders. The S particles are found to be well hosted by highly conductive graphene flakes and consequently superior cyclability (∼70% capacity retention after 250 cycles), good coulombic efficiency (∼98%) and high capacity (∼1500 mA h g-1) are obtained. The proposed approach does not require high temperature annealing or baking; hence, another great advantage is to make flexible Li-ion batteries. We have also demonstrated two types of flexible batteries using sprayed graphene/S electrodes. © The Royal Society of Chemistry 2015.

  7. Coal and recycling mark the way forward

    Energy Technology Data Exchange (ETDEWEB)

    Bignell, E.

    2000-11-01

    A report is given of this year's Mineral Engineering Society's annual conference held in Scarborough, UK. The themes of recycling and coal were chosen for the two days of technical presentations. Topics included the cleaning up of brown field sites; the use of recycled waste oxide to replace iron ore pellets for cooling furnaces in steel making; high pressure filtration of industrial mineral effluent; iron ore mining in Australia; screen development; the status of coal preparation technology, by RJB Mining; study of movement of material (to simulate coal) in a hopper; and a UK-Chinese project on reduction of sulphur in coal.

  8. Coal

    International Nuclear Information System (INIS)

    Teissie, J.; Bourgogne, D. de; Bautin, F.

    2001-12-01

    Coal world production represents 3.5 billions of tons, plus 900 millions of tons of lignite. 50% of coal is used for power generation, 16% by steel making industry, 5% by cement plants, and 29% for space heating and by other industries like carbo-chemistry. Coal reserves are enormous, about 1000 billions of tons (i.e. 250 years of consumption with the present day rate) but their exploitation will be in competition with less costly and less polluting energy sources. This documents treats of all aspects of coal: origin, composition, calorific value, classification, resources, reserves, production, international trade, sectoral consumption, cost, retail price, safety aspects of coal mining, environmental impacts (solid and gaseous effluents), different technologies of coal-fired power plants and their relative efficiency, alternative solutions for the recovery of coal energy (fuel cells, liquefaction). (J.S.)

  9. Reinforced sulphur concrete

    NARCIS (Netherlands)

    2014-01-01

    Reinforced sulphur concrete wherein one or more metal reinforcing members are in contact with sulphur concrete is disclosed. The reinforced sulphur concrete comprises an adhesion promoter that enhances the interaction between the sulphur and the one or more metal reinforcing members.

  10. High pressure treatments accelerate changes in volatile composition of sulphur dioxide-free wine during bottle storage.

    Science.gov (United States)

    Santos, Mickael C; Nunes, Cláudia; Rocha, M Angélica M; Rodrigues, Ana; Rocha, Sílvia M; Saraiva, Jorge A; Coimbra, Manuel A

    2015-12-01

    The impact of high hydrostatic pressure (HHP) treatments on volatile composition of sulphur dioxide-free wines during bottle storage was studied. For this purpose, white and red wines were produced without sulphur dioxide (SO2) and, at the end of the alcoholic fermentation, the wines were pressurised at 500 MPa and 425 MPa for 5 min. Wine with 40 ppm of SO2 and a wine without a preservation treatment were used as controls. More than 160 volatile compounds, distributed over 12 chemical groups, were identified in the wines by an advanced gas chromatography technique. The pressurised wines contained a higher content of furans, aldehydes, ketones, and acetals, compared with unpressurised wines after 9 months of storage. The changes in the volatile composition indicate that HHP treatments accelerated the Maillard reaction, and alcohol and fatty acid oxidation, leading to wines with a volatile composition similar to those of faster aged and/or thermally treated wines. Copyright © 2015 Elsevier Ltd. All rights reserved.

  11. Introduction to South African coal mining and exploration

    CSIR Research Space (South Africa)

    Jeffrey, L

    2015-01-01

    Full Text Available , such as is mined at the No. 2 Mine at Kriel Colliery9. Klip River The Bottom Seam in the Klip River Coalfield (equivalent to the Gus Seam) is high in sulphur & phosphorus, with sulphur usually ranging from 1.3% to 1.8%1, 10. The Top Seam (corresponding... to the Alfred Seam) has a smaller bright coal proportion than the Bottom Seam1, but like the Bottom Seam, the rank of the Top Seam ranges from bituminous to anthracitic with generally high sulphur & phosphorus content. In general, the Klip River Coalfield...

  12. High tech conveyors unitize Selby coal

    Energy Technology Data Exchange (ETDEWEB)

    1985-10-01

    Designs proposed by Anderson Strathclyde PLC and Cable Belt for single-flight conveyors to bring the output of the five Selby mines to the surface have both been developed by the UK National Coal Board. Both designs extend the limits of conveyor technology and are expected to economise on transport and longwalling costs. 4 references.

  13. Sulphur highways : value-added solutions to create sulphur demand

    Energy Technology Data Exchange (ETDEWEB)

    Macedo, R.

    2010-09-15

    Producers generally view sulphur as a nuisance with essentially no benefit. In Alberta, a greater portion of sulphur production will shift from natural gas to the oilsands producing areas where there is limited infrastructure to move it out. Increased amounts of sour oil and gas production together with greater fuel desulphurization have also led to more sulphur being produced. In order to address the inevitable storage issue, Shell is considering value-added uses for the product, such as sulphur asphalt. The company developed Thiopave, a sulphur-based product for use in asphalt paving mixtures that can improve the mechanical performance of asphalt. The sulphur can be added to the asphalt mix as a solid pellet, which helps reduce the emission of sulphur vapour, odour and eye irritation. Twenty Thiopave projects are planned for the 2010 paving season in 9 U.S. states and 2 Canadian provinces. Sulphur Enhanced Asphalt Modifier (SEAM) was the first generation of Thiopave developed in 2003. SEAM replaces 20 to 25 percent by volume of the bitumen in asphalt mix. The properties allow Thiopave-enhanced roads to perform better than conventional roads in both consistently high temperature regions and climates with wide temperature variations. In 2007, an asphalt mix containing 40 percent by mass of Thiopave was used in a trial in Qatar. The Thiopave asphalt mix was compared with a conventional mix at temperatures ranging from 10 to 40 degrees C to determine the stiffness ratio. It was determined that Thiopave mixes containing high-penetration bitumen can be used to build temperature resistant roads that are stiffer in hot summer temperatures while improving the pavement's cold weather cracking performance. 1 ref., 4 figs.

  14. High pressure MHD coal combustors investigation, phase 2

    Science.gov (United States)

    Iwata, H.; Hamberg, R.

    1981-05-01

    A high pressure MHD coal combustor was investigated. The purpose was to acquire basic design and support engineering data through systematic combustion experiments at the 10 and 20 thermal megawatt size and to design a 50 MW/sub t/ combustor. This combustor is to produce an electrically conductive plasma generated by the direct combustion of pulverized coal with hot oxygen enriched vitiated air that is seeded with potassium carbonate. Vitiated air and oxygen are used as the oxidizer, however, preheated air will ultimately be used as the oxidizer in coal fired MHD combustors.

  15. High-temperature removal of sulphur for biogenic gas products; Hochtemperatur-Entschwefelung fuer biogene Produktgase. Design und Optimierung - Schlussbericht/Jahresbericht

    Energy Technology Data Exchange (ETDEWEB)

    Schildhauer, T.; Biollaz, S.

    2009-12-15

    This final report for the Swiss Federal Office of Energy (SFOE) presents the results of a project concerning the development of basics ideas on the design and optimisation of high-temperature methods for the removal of sulphur from biogenic gas products. Tests made as part of the 'Methane from Wood' project at pilot installations in Switzerland and Austria are discussed. Low temperature and high-temperature methods are examined and discussed. A number of sulphur compounds were tested. Also, experiments made using nickel, HDS and CPO catalysers are discussed.

  16. High-performance graphene/sulphur electrodes for flexible Li-ion batteries using the low-temperature spraying method

    Science.gov (United States)

    Kumar, Pushpendra; Wu, Feng-Yu; Hu, Lung-Hao; Ali Abbas, Syed; Ming, Jun; Lin, Chia-Nan; Fang, Jason; Chu, Chih-Wei; Li, Lain-Jong

    2015-04-01

    Elementary sulphur (S) has been shown to be an excellent cathode material in energy storage devices such as Li-S batteries owing to its very high capacity. The major challenges associated with the sulphur cathodes are structural degradation, poor cycling performance and instability of the solid-electrolyte interphase caused by the dissolution of polysulfides during cycling. Tremendous efforts made by others have demonstrated that encapsulation of S materials improves their cycling performance. To make this approach practical for large scale applications, the use of low-cost technology and materials has become a crucial and new focus of S-based Li-ion batteries. Herein, we propose to use a low temperature spraying process to fabricate graphene/S electrode material, where the ink is composed of graphene flakes and the micron-sized S particles prepared by grinding of low-cost S powders. The S particles are found to be well hosted by highly conductive graphene flakes and consequently superior cyclability (~70% capacity retention after 250 cycles), good coulombic efficiency (~98%) and high capacity (~1500 mA h g-1) are obtained. The proposed approach does not require high temperature annealing or baking; hence, another great advantage is to make flexible Li-ion batteries. We have also demonstrated two types of flexible batteries using sprayed graphene/S electrodes.Elementary sulphur (S) has been shown to be an excellent cathode material in energy storage devices such as Li-S batteries owing to its very high capacity. The major challenges associated with the sulphur cathodes are structural degradation, poor cycling performance and instability of the solid-electrolyte interphase caused by the dissolution of polysulfides during cycling. Tremendous efforts made by others have demonstrated that encapsulation of S materials improves their cycling performance. To make this approach practical for large scale applications, the use of low-cost technology and materials has become

  17. Desulphurisation of coal pyrolysis and magnetic separation. Desulfuracion de carbones mediante pirolisis y separacion magnetica

    Energy Technology Data Exchange (ETDEWEB)

    Ruiz, J.C.; Ayala, N.; Ibarra, J.V.; Moliner, R.; Miranda, J.L.; Vazquez, A. (CENIM, Madrid (Spain))

    1991-07-01

    The desulphurisation of coal intended for use inthermal power stations is a priority issue in the national strategy for the reduction of acid rain. This article studies the feasibility of eliminating pyritic sulphur from coal by physical methods using high intensity pyrolysis and magnetic separation. 6 refs., 9 figs., 4 tabs.

  18. Organic sulphur in macromolecular sedimentary organic matter. II. Analysis of distributions of sulphur-containing pyrolysis products using multivariate techniques

    NARCIS (Netherlands)

    Sinninghe Damsté, J.S.; Eglinton, T.I.; Pool, W.; Leeuw, J.W. de; Eijkel, G.; Boon, J.J.

    1992-01-01

    This study describes the analysis of sulphur-containing products from Curie-point pyrolysis (Py) of eighty-five samples (kerogens, bitumen, and petroleum asphaltenes and coals) using gas chromatography (GC) in combination with sulphur-selective detection. Peak areas of approximately forty individual

  19. Coal gasification coal by steam using process heat from high-temperature nuclear reactors

    International Nuclear Information System (INIS)

    Heek, K.H. van; Juentgen, H.; Peters, W.

    1982-01-01

    This paper outlines the coal gasification process using a high-temperature nuclear reactor as a source of the process heat needed. Compared to conventional gasification processes coal is saved by 30-40%, coal-specific emissions are reduced and better economics of gas production are achieved. The introductory chapter deals with motives, aims and tasks of the development, followed by an explanation of the status of investigations, whereby especially the results of a semi-technical pilot plant operated by Bergbau-Forschung are given. Furthermore, construction details of a full-scale commercial gasifier are discussed, including the development of suitable alloys for the heat exchanger. Moreover problems of safety, licensing and economics of future plants have been investigated. (orig.) [de

  20. Effect of Chlorine and Sulphur on Stainless Steel (AISI 310) Due To High Temperature Corrosion.

    OpenAIRE

    Onaivi Daniel Azamata; Titus Yusuf Jibatswen; Odinize C. Michael

    2016-01-01

    In a power station boiler, there are temperature of regimes of corrosion which occurs mainly in the economizer, boiler steam generation tubes, super-heater tubes and air tubes. The specific gas temperatures in degrees centigrade for the following include: 150 – 370oC for the economizer, 1000 – 1650oC for the boiler steam generation tubes, 650 – 1000oC for super-heater tubes and 1000 – 1200oC for air tubes. For power station boilers that burn coal as the source of fuel it is recommended that a...

  1. Volatility of coal liquids at high temperatures and pressures

    Energy Technology Data Exchange (ETDEWEB)

    Wilson, G M; Johnston, R H; Hwang, S C; Tsonopoulos, C

    1981-01-01

    The volatility of coal liquids has been experimentally determined at 700-880 F and about 2000 psia. These measurements were made in a flow apparatus to minimize thermal decomposition effects at high temperatures. Three coal liquids in mixture with Hat2, methane, and Hat2S were investigated. Measurements were also made up to 900 F on the vapor pressure of pure compounds found in coal liquids and on the equilibrium pressure of narrow coal liquid cuts. These data were used to develop a new method for the prediction of the critical point and the superatmospheric vapour pressures of aromatic fractions that is superior to the Maxwell-Bonnell correlation. The VLE data on coal liquids and some recent high-temperature VLE data on binaries of aromatics with Hat2 or methane were analyzed with a modified Chao-Seader correlation and a modified Redlich-Kwong equation of state. Both VLE correlations are shown to be equivalent in the prediction of the volatility of coal liquids, when the new vapour pressure procedure is used.

  2. Preventing performance drops of coal mills due to high moisture content

    DEFF Research Database (Denmark)

    Odgaard, Peter Fogh; Stoustrup, Jakob; Mataji, B.

    2007-01-01

    Coal mills pulverize and dry the coal dust before it is blown into the furnace in coal-fired power plants. The coal mills can only deliver the requested coal flow if certain conditions are fulfilled. These are normally considered as constraints on individual variables. However, combinations of more...... than one variable might cause problems even though these individually variables are in an acceptable region. This paper deals with such a problem. The combination of a high load of the power plant, a large load change and high moisture content in the coal, can force the coal mill into a state where...... coal is accumulated instead of being blown into the furnace. This paper suggests a simple method for preventing the accumulation of the coal in the mill, by limiting the requested coal flow considering the coal moisture content and the temperature outside the mill.  ...

  3. Molecular analysis of sulphur-rich brown coals by flash pyrolysis-gas chromatography-mass spectrometry: The type III-S kerogen

    NARCIS (Netherlands)

    Sinninghe Damsté, J.S.; Las Heras, F.X.C. de; Leeuw, J.W. de

    1992-01-01

    The molecular composition of five brown coals from three different basins (Maestrazgo, Mequinenza and Rubielos) in Spain was investigated by flash pyrolysis-gas chromatography and flash pyrolysis-gas chromatography-mass spectrometry. In these techniques, the macromolecular material is thermally

  4. Experimental study of rapid brown coal pyrolysis at high temperature

    Energy Technology Data Exchange (ETDEWEB)

    Qian, Lin; Sun, Shaozeng; Meng, Shun; Meng, Xianyu; Guo, Yangzhou [Harbin Institute of Technology, Harbin (China). Combustion Engineering Research Inst.

    2013-07-01

    Rapid coal pyrolysis is a very important step in the early stage of combustion. Rapid pyrolysis experiments of a brown coal at high temperature have been studied on a laminar drop tube furnace. The volatile mass release measured in this study is high for low rank coal. The activation energy and pre-exponential factor of pyrolysis are 19901.22 kJ/mol and 102.71, respectively. The nitrogen distribution between volatile and char is 0.54. With the increase of temperature, the yields of NH{sub 3} decreases, while those of HCN increases, leading the value of HCN/NH{sub 3} to become larger. At high temperature, the main nitrogen- containing species of pyrolysis in volatile is HCN.

  5. Sulphur in Poland

    Directory of Open Access Journals (Sweden)

    Seman Peter

    2001-12-01

    Full Text Available Poland belongs to one of the last countries with native sulphur mining. Its history begun in 15th century. Deposit area of Tarnobrzeg re-presents 80% of all known sulphur reserves in this country. All of explored deposits in this area were created by metasomatic alteration of sulphur bearing limestones with sulphur mineralised liquids, which arised from melt gypsum. The average content is 25 - 30% of sulphur in Tarnobrzeg area. Considerable parts of deposits are created by calcite and native sulphur. Gypstone, baryte and stroncianite have only minera-logic occurencies. The extensive native sulphur deposits account for 88% of the country´s sulphur production. There were five sulphur mines in operation: Jeziórko, Grêbów, Machów I, Machów II and Basznia, but operations in Basznia were ended in 1992 and Machów and Machów II were liquidated. The sixth mine Osiek is currently producing. Only the Machów I mine operated an open-pit extraction and refining process, the other four mines producing sulphur using a modified Frasch method that gives elemental sulphur of up to 99,9% purity. Sulphur is an important export commodity with foreign sales totalling around 1.5 - 2.5 Mt/y. Modern benefication methods, which allowing to achieve sulphur from hydrocarbons, are causing decrease of native sulphur prices in the world and bringing about reduction of mining activities for this raw material in Poland.

  6. Coal-fired high performance power generating system. Final report

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1995-08-31

    As a result of the investigations carried out during Phase 1 of the Engineering Development of Coal-Fired High-Performance Power Generation Systems (Combustion 2000), the UTRC-led Combustion 2000 Team is recommending the development of an advanced high performance power generation system (HIPPS) whose high efficiency and minimal pollutant emissions will enable the US to use its abundant coal resources to satisfy current and future demand for electric power. The high efficiency of the power plant, which is the key to minimizing the environmental impact of coal, can only be achieved using a modern gas turbine system. Minimization of emissions can be achieved by combustor design, and advanced air pollution control devices. The commercial plant design described herein is a combined cycle using either a frame-type gas turbine or an intercooled aeroderivative with clean air as the working fluid. The air is heated by a coal-fired high temperature advanced furnace (HITAF). The best performance from the cycle is achieved by using a modern aeroderivative gas turbine, such as the intercooled FT4000. A simplified schematic is shown. In the UTRC HIPPS, the conversion efficiency for the heavy frame gas turbine version will be 47.4% (HHV) compared to the approximately 35% that is achieved in conventional coal-fired plants. This cycle is based on a gas turbine operating at turbine inlet temperatures approaching 2,500 F. Using an aeroderivative type gas turbine, efficiencies of over 49% could be realized in advanced cycle configuration (Humid Air Turbine, or HAT). Performance of these power plants is given in a table.

  7. Investigation of a high pressure oxy-coal process

    Energy Technology Data Exchange (ETDEWEB)

    Renz, U. [RWTH Aachen Univ. (Germany). Inst. of Heat and Mass Transfer

    2013-07-01

    A study was conducted to investigate the feasibility of an oxy-coal process, which is pressurized to a combustion pressure of 80 bar. At that pressure the water-vapor can be separated economically from the CO{sub 2}/H{sub 2}O flue gases, either by nucleate condensation or by condensation on cooled surfaces in condenser heat exchangers at a temperature of about 300 C. The heat of condensation can be recaptured to preheat the boiler feed water. So the number of economizers is drastically reduced compared to a conventional steam cycle. Another interesting feature of the high pressure oxy-coal process is the fact, that low rank coal with high moisture content can be fired. Such a process at a pressure of about 80 bar is currently investigated by Babcock, USA, as the ThermoEnergy Integrated Power System (TIPS) and will be analyzed in the present paper. A known disadvantage of the oxy-coal processes is the large recirculating flue gas stream to control the combustion temperature, and which need large pipes and heavy recirculation fans. This disadvantage could be avoided if instead of flue gas a part of the condensed water from the condenser heat exchangers is recirculated. Within the present study both types of processes have been simulated and for an electric power output of about 220 MW. Furthermore, results of CFD simulations of a pressurized 250 MW combustor with a single swirl burner and flue gas recirculation will be presented.

  8. The two faces of coal : uncertainty the common prospect for metallurgical and thermal coal

    International Nuclear Information System (INIS)

    Zlotnikov, D.

    2010-01-01

    Although the methods of producing thermal and metallurgical coal are the same, metallurgical coal is destined to cross the world for steel manufacturing and thermal coal is destined for power plants close to where it was mined. This article discussed the factors influencing the price of these 2 coals. The production of thermal coal can remain steady during an economic crisis because coal-fired power plants generally provide low-cost-base-load electricity that remains stable during economic cycles. However, the demand for metallurgical coal is more volatile during an economic crisis because it is directly related to the demand for steel products in the construction and automotive industry, which are very sensitive to the state of the economy. There have been recent indications that Canada's export market for thermal coal is on the rise. In 2008, China became a net importer of coking coal. China's need for more coal to fuel its growing economy despite the global economic slowdown has meant that producers are diverting excess supply from European markets to China. Higher-end thermal coal offers low sulphur content and higher energy content, both desirable traits for power utilities facing strict emissions control. In addition to having huge reserves of very high-quality coal that is becoming increasingly important to China, Canada has the advantage of having the available transportation capacity in its west coast terminals and on its rail network. 3 figs.

  9. Reduction of sulphur dioxide emissions by pyrolysis reduction of the burning sulfur of coal, applied in the power station 'Maritsa-East 3'

    International Nuclear Information System (INIS)

    Lyutskanov, L.; Dushanov, D.

    1999-01-01

    A study for applying of the new method for reduction of the sulfur content in solid fuel reported at the Energy Forum '98 has been carried out. The calculations for using this method at the power station 'Maritsa-East 3' were made. The advantages compared to the conventional methods for removing of SO 2 from flue gases are reported. The application of this method reduces the emissions of SO 2 with 83-85%. The heat saved is equal to the heat from 13.8% of the coal. The tar obtained after removing of sulfur can be used as fuel. The expenses for transport and treatment of limestone and of obtained gypsum (needed at the conventional methods for removing the sulfur) are eliminated. The capital investments needed are smaller because of the 25-30 times smaller volume of the equipment for sulfur reduction

  10. Influence of high-energy impact on the physical and technical characteristics of coal fuels

    Science.gov (United States)

    Mal'tsev, L. I.; Belogurova, T. P.; Kravchenko, I. V.

    2017-08-01

    Currently, in the world's large-scale coal-fired power industry, the combustion of pulverized coal is the most widely spread technology of combusting the coals. In recent years, the micropulverization technology for preparation and combustion of the coal has been developed in this field. As applied to the small-scale power industry, the method of combusting the coal in the form of a coal-water slurry has been explored for years. Fine coal powders are produced and used in the pulverized-coal gasification. Therefore, the coal preparation methods that involve high-dispersion disintegration of coals attract the greatest interest. The article deals with the problems of high-energy impact on the coal during the preparation of pulverized-coal fuels and coal-water slurries, in particular, during the milling of the coal in ball drum mills and the subsequent regrinding in disintegrators or the cavitation treatment of the coal-water slurries. The investigations were conducted using samples of anthracite and lignite from Belovskii open-pit mine (Kuznetsk Basin). It is shown that both the disintegration and the cavitation treatment are efficient methods for controlling the fuel characteristics. Both methods allow increasing the degree of dispersion of the coal. The content of the small-sized particles reground by cavitation considerably exceeds the similar figure obtained using the disintegrator. The specific surface area of the coal is increased by both cavitation and disintegration with the cavitation treatment producing a considerably greater effect. Being subjected to the cavitation treatment, most coal particles assume the form of a split characterized by the thermodynamically nonequilibrium state. Under external action, in particular, of temperature, the morphological structure of such pulverized materials changes faster and, consequently, the combustion of the treated coal should occur more efficiently. The obtained results are explained from the physical point of view.

  11. Expression and Characterisation of Recombinant Rhodocyclus tenuis High Potential Iron-Sulphur Protein

    DEFF Research Database (Denmark)

    Caspersen, Michael Bjerg; Bennet, K.; Christensen, Hans Erik Mølager

    2000-01-01

    The high potential iron-sulfur protein (HiPIP) from Rhodocyclus tenuis strain 2761 has been overproduced in Escherichia coli from its structural gene, purified to apparent homogeneity, and then characterized by an array of methods. UV-visible spectra of the reduced and oxidized recombinant protein...

  12. Free and sulphurized hopanoids and highly branched isoprenoids in immature lacustrine oil shales

    NARCIS (Netherlands)

    Sinninghe Damsté, J.S.; Las Heras, F.X.C. de; Grimalt, J.O.; Lopez, J.F.; Albaiges, J.; Leeuw, J.W. de

    1997-01-01

    A study of the solvent extracts of four samples from two immature oil shales from Tertiary lacustrine basins, Ribesalbes and Campins (southern European rift system), deposited under reducing conditions, has allowed the identification of S-containing hopanoids and novel highly branched isoprenoids

  13. Steam coal processing technology: handling, high-order processing, COM, meth-coal

    Energy Technology Data Exchange (ETDEWEB)

    Kamata, H.; Onodera, J.

    1982-01-01

    Topics covered include: various handling techologies (overland and marine transport, storage, water removal, drying, comminution and sizing); various coal processing technologies (gravity concentration, magnetic separation, multi-stage flotation, liquid-phase pelletizing, chemical processing); production methods for coal-oil mixtures (COM), their physical properties, stability, storage, transport, advantages, plus recent trends in research and development; production of coal-methanol slurry (meth-coal), its stability, storage, transport, utilization and environmental problems, plus latest trends in research and development. (In Japanese)

  14. Dry deposition of sulphur at a high-altitude background station in South Africa

    CSIR Research Space (South Africa)

    Zunckel, M

    1999-10-01

    Full Text Available station also plays a role in the observed day-to-day variation as pollutants are trapped immediately below this layer. The pressure difference between the base of the absolutely stable layer and the surface pressure at Ben MacDhui is used to indicate... AT A HIGH-ALTITUDE BACKGROUND STATION IN SOUTH AFRICA MARK ZUNCKEL1;2 , STUART PIKETH1 and TALI FREIMAN1 1 Climatology Research Group, University of Witwatersrand, Johannesburg, South Africa; 2 CSIR Environmentek, P.O. Box 17001, Congella, South Africa...

  15. 75 FR 17529 - High-Voltage Continuous Mining Machine Standard for Underground Coal Mines

    Science.gov (United States)

    2010-04-06

    ... High-Voltage Continuous Mining Machine Standard for Underground Coal Mines AGENCY: Mine Safety and... of high-voltage continuous mining machines in underground coal mines. It also revises MSHA's design...-- Underground Coal Mines III. Section-by-Section Analysis A. Part 18--Electric Motor-Driven Mine Equipment and...

  16. Pulverized coal devolatilization prediction

    International Nuclear Information System (INIS)

    Rojas, Andres F; Barraza, Juan M

    2008-01-01

    The aim of this study was to predict the two bituminous coals devolatilization at low rate of heating (50 Celsius degrade/min), with program FG-DVC (functional group Depolymerization. Vaporization and crosslinking), and to compare the devolatilization profiles predicted by program FG-DVC, which are obtained in the thermogravimetric analyzer. It was also study the volatile liberation at (10 4 k/s) in a drop-tube furnace. The tar, methane, carbon monoxide, and carbon dioxide, formation rate profiles, and the hydrogen, oxygen, nitrogen and sulphur, elemental distribution in the devolatilization products by FG-DVC program at low rate of heating was obtained; and the liberation volatile and R factor at high rate of heating was calculated. it was found that the program predicts the bituminous coals devolatilization at low rate heating, at high rate heating, a volatile liberation around 30% was obtained

  17. Coal-fired high performance power generating system

    Energy Technology Data Exchange (ETDEWEB)

    1992-07-01

    The goals of the program are to develop a coal-fired high performance power generation system (HIPPS) by the year 2000 that is capable of > 47% thermal efficiency; NO[sub x] SO [sub x] and Particulates < 25% NSPS; Cost of electricity 10% lower; coal > 65% of heat input and all solid wastes benign. In order to achieve these goals our team has outlined a research plan based on an optimized analysis of a 250 MW[sub e] combined cycle system applicable to both frame type and aeroderivative gas turbines. Under the constraints of the cycle analysis we have designed a high temperature advanced furnace (HITAF) which integrates several combustor and air heater designs with appropriate ash management procedures. Most of this report discusses the details of work on these components, and the R D Plan for future work. The discussion of the combustor designs illustrates how detailed modeling can be an effective tool to estimate NO[sub x] production, minimum burnout lengths, combustion temperatures and even particulate impact on the combustor walls. When our model is applied to the long flame concept it indicates that fuel bound nitrogen will limit the range of coals that can use this approach. For high nitrogen coals a rapid mixing, rich-lean, deep staging combustor will be necessary. The air heater design has evolved into two segments: a convective heat exchanger downstream of the combustion process; a radiant panel heat exchanger, located in the combustor walls; The relative amount of heat transferred either radiatively or convectively will depend on the combustor type and the ash properties.

  18. High radon exposure in a Brazilian underground coal mine

    International Nuclear Information System (INIS)

    Veiga, L H S; Melo, V; Koifman, S; Amaral, E C S

    2004-01-01

    The main source of radiation exposure in most underground mining operations is radon and radon decay products. The situation of radon exposure in underground mining in Brazil is still unknown, since there has been no national regulation regarding this exposure. A preliminary radiological survey in non-uranium mines in Brazil indicated that an underground coal mine in the south of Brazil had high radon concentration and needed to be better evaluated. This paper intends to present an assessment of radon and radon decay product exposure in the underground environment of this coal mining industry and to estimate the annual exposure to the workers. As a product of this assessment, it was found that average radon concentrations at all sampling campaign and excavation sites were above the action level range for workplaces of 500-1500 Bq m -3 recommended by the International Commission on Radiological Protection-ICRP 65. The average effective dose estimated for the workers was almost 30 times higher than the world average dose for coal miners

  19. Sulphurous mineral waters

    Directory of Open Access Journals (Sweden)

    Iluta Alexandru

    2011-09-01

    Full Text Available Sulphurous waters contain at least 1mg H2S, HS, S or thiosulphate per liter or complex colloidal sulfur water is presented as of simple or mixed sulphide (alkali, carbonated, chlorinated sodium.In the sulphurous waters, sulfur is found in several forms (hydrogen sulfide, free sulfide, sulfide groups, polysulfides acids. Yellow, opalescent white precipitate and deposit a glass of water on the bottom of sulphur oxidation by indicates the intensity of the wateroxidation process by oxygen in the air.

  20. Sulphurous Mineral Waters: New Applications for Health

    Directory of Open Access Journals (Sweden)

    Jose Manuel Carbajo

    2017-01-01

    Full Text Available Sulphurous mineral waters have been traditionally used in medical hydrology as treatment for skin, respiratory, and musculoskeletal disorders. However, driven by recent intense research efforts, topical treatments are starting to show benefits for pulmonary hypertension, arterial hypertension, atherosclerosis, ischemia-reperfusion injury, heart failure, peptic ulcer, and acute and chronic inflammatory diseases. The beneficial effects of sulphurous mineral waters, sulphurous mud, or peloids made from sulphurous mineral water have been attributed to the presence of sulphur mainly in the form of hydrogen sulphide. This form is largely available in conditions of low pH when oxygen concentrations are also low. In the organism, small amounts of hydrogen sulphide are produced by some cells where they have numerous biological signalling functions. While high levels of hydrogen sulphide are extremely toxic, enzymes in the body are capable of detoxifying it by oxidation to harmless sulphate. Hence, low levels of hydrogen sulphide may be tolerated indefinitely. In this paper, we review the chemistry and actions of hydrogen sulphide in sulphurous mineral waters and its natural role in body physiology. This is followed by an update of available data on the impacts of exogenous hydrogen sulphide on the skin and internal cells and organs including new therapeutic possibilities of sulphurous mineral waters and their peloids.

  1. Effects of sulphur ion implantation on the electrochemical behaviour of two stainless steels in sulphuric medium

    International Nuclear Information System (INIS)

    Nader-Roux, J.; Becdelievre, A.M. de; Gaillard, F.; Roux, R.; Becdelievre, J. de

    1986-01-01

    The electrochemical behaviour in sulphuric acid of two austenitic stainless steels (AISI 304 L and AISI 321) modified by sulphur ion implantation has been studied. Surface analysis of oxygen and sulphur by LEEIXS and XRFS were performed before and after polarization on unimplanted and on implanted samples. I/E curves with implanted steels reveal an important corrosion peak (α peak) recovering widely the active peak of unimplanted samples. For high implanted doses, another peak (β peak) appears in the passive range. High doses implanted steels polarized in the range of the α peak exhibit a sulphur enriched black surface layer. SEM examination of this layer shows it is constituted by flakes rolling up themselves. The formation of a superficial non-protective sulphide layer and the internal stresses of this layer explain the corrosion enhancement of sulphur implanted materials. After dissolution of this layer the behaviour of unimplanted steels is found again. (author)

  2. Clean coal technologies

    International Nuclear Information System (INIS)

    Bourillon, C.

    1994-01-01

    In 1993 more than 3.4 billion tonnes of coal was produced, of which half was used to generate over 44 per cent of the world's electricity. The use of coal - and of other fossil fuels- presents several environmental problems such as emissions of sulphur dioxide (SO 2 ), nitrogen oxides (NO 2 ), and carbon dioxide (CO 2 ) into the atmosphere. This article reviews the measures now available to mitigate the environmental impacts of coal. (author)

  3. Analysis of sulphur, phosphorus and silica in metals, alloys, inorganic compounds and solvents

    International Nuclear Information System (INIS)

    Upadhya, J.C.; Naik, S.S.; Khedikar, W.K.; Sudersanan, M.; Mathur, P.K

    1999-10-01

    Procedures for the analysis of sulphur, phosphorus and silica in various metals and alloys like mild steel, carbon steel and stainless steel as well as nickel base alloys are described. Procedures were also developed for the analysis of sulphur in thoria pellets and in other materials like crack check fluids, coal etc. Typical results obtained are summarised. (author)

  4. Preparation and characterization compatible pellets for immobilization of colloidal sulphur nanoparticles

    Science.gov (United States)

    Adlim, M.; Zarlaida, F.; Khaldun, I.; Dewi, R.; Jamilah, M.

    2018-03-01

    Mercury pollution in atmosphere is dominated by mercury vapour release from coal burning and gold-amalgam separation in gold mining. The initial steps in formulating a compatible mercury absorbent for mercury stabilization was fabrication of pellet supported colloidal sulphur. Sulphur is used to stabilize mercury vapour by formation of metacinnabar that has much lower toxicity. The sulphur reactivity toward mercury vapour can be enhanced by using colloidal sulphur nanoparticles immobilized on compatible pellets. Clay pellets would have heat resistance but in fact, they were less stable in aqueous solution although their stability increased with inclusion of rice husk ash and sawdust or pineapple leaf fibre in the composite. Pellets made of rice husk ash and polyvinyl acetate were stable in water at least for 24 hours. Sulphur from thiosulfate precursor that immobilized onto surface of pellet using chitosan as the stabilizer and the binding agent gave lower sulphur content compared to sulphur from other precursors (sulphur powder and sulphur-CS2). Sulphur from thiosulfate precursor was in form of colloid, has nanosize, and disperse particles on the surface of rice husk ash pellets. Sulphur immobilization methods affect on sulphur particles exposure on the pellet surface.

  5. Environmental assessment and nano-mineralogical characterization of coal, overburden and sediment from Indian coal mining acid drainage

    Directory of Open Access Journals (Sweden)

    Madhulika Dutta

    2017-11-01

    Full Text Available The deterioration of environmental conditions is the major contributory factor to poor health and quality of life that hinders sustainable development in any region. Coal mining is one of the major industries that contribute to the economy of a country but it also impacts the environment. The chemical parameters of the coal, overburden, soil and sediments along with the coal mine drainage (CMD were investigated in order to understand the overall environmental impact from high sulphur coal mining at northeastern coalfield (India. It was found that the total sulphur content of the coal is noticeably high compared to the overburden (OB and soil. The volatile matter of the coal is sufficiently high against the high ash content of the soil and overburden. The water samples have a High Electrical Conductivity (EC and high Total Dissolve Solid (TDS. Lower values of pH, indicate the dissolution of minerals present in the coal as well as other minerals in the mine rejects/overburden. The chemical and nano-mineralogical composition of coal, soil and overburden samples was studied using a High Resolution-Transmission Electron Microscopy (HR-TEM, Energy Dispersive Spectroscopy (EDS, Selected-Area Diffraction (SAED, Field Emission-Scanning Electron Microscopy (FE-SEM/EDS, X-ray diffraction (XRD, Fourier Transform Infrared Spectroscopy (FTIR, Raman and Ion-Chromatographic analysis, and Mössbauer spectroscopy. From different geochemical analysis it has been found that the mine water sample from Ledo colliery has the lowest pH value of 3.30, Tirap colliery samples have the highest electrical conductivity value of 5.40 ms cm−1. Both Ledo and Tirap coals have total sulphur contents within the range 3–3.50%. The coal mine water from Tirap colliery (TW-15B has high values of Mg2+ (450 ppm, and Br− (227.17 ppm. XRD analysis revealed the presence of minerals including quartz and hematite in the coals. Mineral analysis of coal mine overburden (OB indicates

  6. Rapid pyrolysis of Serbian soft brown coals

    Directory of Open Access Journals (Sweden)

    Jankes Goran

    2009-01-01

    Full Text Available Soft brown coals of the open coal fields of Kolubara and Kostolac are the main domestic energy sources of Serbia. This paper presents the results of investigations on rapid devolatilization of these two coals which have covered kinetics of devolatilization (based on total volatile yield, forms of sulphur and petrographic analysis of coal and char. Experiments of devolatilization were performed in inert gas (N2 at atmospheric pressure and in batch-type hot-wire screen reactor. The mass-loss values of both coals at selected final reaction temperatures (300-900°C and retention times (3-28 s were obtained. Anthony and Howard's kinetic model was applied over two temperature ranges (300-500 and 700-900°C. The types of sulphur as monosulphide, sulphate, pyritic, and organic sulphur were determined for chars and original coals. Strong transformation of pyrite was evident even at low temperatures (300°C. Devolatilization of all types of sulphur has started over 600 and at 900°C the content of sulphur in char remained only 66% of total sulphur in original coal. Microscopic investigations were carried out on samples prepared for reflected light measurements. The petrographic analysis included: the ratio of unchanged and changed coal, maceral types, the share of cenosferes, isotropic mixed carbonized grains, mixed grains, small fragments, clay, and pyrite. The change of the structure of devolatilized coal was also observed.

  7. Experimental study of desulfurization of Zhong Liang Shau high sulfur coal by flotation

    Energy Technology Data Exchange (ETDEWEB)

    Jiang, Z.; Huang, B.; Cao, J. [China University of Mining and Technology (China). Beijing Graduate School

    1994-12-01

    Emission of large amount of SO{sub 2} from combustion of high sulfur coal causes serious environmental pollution. Pre-combustion desulfurization of high sulfur coal has become a necessity. This paper reports test results of fine coal desulfurization with different flotation technology and the effect of pyrite depressant. Test work showed that when the coal sample from Zhong Liang Shau was processed with a Free Jet Flotation Column its pyritic sulfur content was reduced from 3.08% to 0.84%, with 72.22% recovery of combustible matter in clean coal. The concept of Desulfurization Efficiency Index E{sub ds} for comprehensive evaluation of desulfurization process is proposed, which is defined as the product of the ratio of sulfur content reduction of clean coal and the recovery of combustible matters. 6 refs., 4 figs., 3 tabs.

  8. Coal-fired power plants and the causes of high temperature corrosion

    Energy Technology Data Exchange (ETDEWEB)

    Oakey, J E; Simms, N J [British Coal Corporation, Coal Technology Development Div., Cheltenham, Glos (United Kingdom); Tomkings, A B [ERA Technology Ltd., Leatherhead, Surrey (United Kingdom)

    1996-12-01

    The heat exchangers in all types of coal-fired power plant operate in aggressive, high temperature environments where high temperature corrosion can severely limit their service lives. The extent of this corrosion is governed by the combined effects of the operating conditions of the heat exchanger and the presence of corrosive species released from the coal during operation. This paper reviews the coal-related factors, such as ash deposition, which influence the operating environments of heat exchangers in three types of coal-fired power plant - conventional pulverized coal boilers, fluidized bed boilers and coal gasification systems. The effects on the performance of the materials used for these heat exchangers are then compared. (au) 35 refs.

  9. Highly-productive mechanization systems for coal mining in the Polish coal industry

    Energy Technology Data Exchange (ETDEWEB)

    Sikora, W

    1985-01-01

    Effects of mechanization on underground coal mining in Poland from 1960 to 1980 and mining equipment used in Poland is reviewed. In 1983 black coal output increased to 191.1 Mt. There were 765 working faces, 442 of which with powered supports. Six hundred thirty-four shearer loaders were in use. About 82.7% of coal output fell on faces mined by sets of mining equipment (shearer loaders, powered supports and chain conveyors). The average coal output per working face amounted to 889 t/d. About 50% of mine roadways was driven by heading machines (346 heading machines were in use). The average coal output per face mined by a set of mining equipment amounted to 1248 t/d. About 86% of shearer loaders fell on double drum shearer loaders. Types of mining equipment used in underground mining are reviewed: powered supports (Pioma, Fazos, Glinik and the SOW), shearer loaders (drum shearer loaders and double-drum shearer loaders with chain haulage and chainless haulage systems for unidirectional and bi-directional mining), chain conveyors (Samson, Rybnik). Statistical data on working faces with various sets of equipment are given. 3 references.

  10. Coal-fueled high-speed diesel engine development: Task 2, Market assessment and economic analysis

    Energy Technology Data Exchange (ETDEWEB)

    Kakwani, R. M.; Wilson, Jr., R. P.; Winsor, R. E.

    1991-12-01

    Based on the preliminary coal engine design developed, this task was conducted to identify the best opportunity(s) to enter the market with the future coal-fueled, high-speed diesel engine. The results of this market and economic feasibility assessment will be used to determine what specific heavy duty engine application(s) are most attractive for coal fuel, and also define basic economic targets for the engine to be competitive.

  11. CLINSULF sub-dew-point process for sulphur recovery

    Energy Technology Data Exchange (ETDEWEB)

    Heisel, M.; Marold, F.

    1988-01-01

    In a 2-reactor system, the CLINSULF process allows very high sulphur recovery rates. When operated at 100/sup 0/C at the outlet, i.e. below the sulphur solidification point, a sulphur recovery rate of more than 99.2% was achieved in a 2-reactor series. Assuming a 70% sulphur recovery in an upstream Claus furnace plus sulphur condenser, an overall sulphur recovery of more than 99.8% results for the 2-reactor system. This is approximately 2% higher than in conventional Claus plus SDP units, which mostly consist of 4 reactors or more. This means the the CLINSULF SSP process promises to be an improvement both in respect of efficiency and low investment cost.

  12. The effects of early diagenetic bacterial sulphate reduction upon the petrology and chemistry of coal

    NARCIS (Netherlands)

    Sinninghe Damsté, J.S.; Veld, H.; Fermont, W.J.J.; Leeuw, J.W. de

    1991-01-01

    In the present study the correlation of the occurrence of sulphur with physical (optical) and chemical characteristics of coal will be discussed to test possible relationships between sulphur and %Rm.

  13. Multiple-heteroatom-containing sulfur compounds in a high sulfur coal

    International Nuclear Information System (INIS)

    Winans, R.E.; Neill, P.H.

    1990-01-01

    Flash vacuum pyrolysis of a high sulfur coal has been combined with high resolution mass spectrometry yielding information on aromatic sulfur compounds containing an additional heteroatom. Sulfur emission from coal utilization is a critical problem and in order to devise efficient methods for removing organic sulfur, it is important to know what types of molecules contain sulfur. A high sulfur Illinois No. 6 bituminous coal (Argonne Premium Coal Sample No. 3) was pyrolyzed on a platinum grid using a quartz probe inserted into a modified all glass heated inlet system and the products characterized by high resolution mass spectrometry (HRMS). A significant number of products were observed which contained both sulfur and an additional heteroatom. In some cases two additional heteroatoms were observed. These results are compared to those found in coal extracts and liquefaction products

  14. An assessment of chemical properties and hardgrove grindability index of punjab coal

    International Nuclear Information System (INIS)

    Shahzad, M.; Iqbal, M.M.; Hassan, S.A.

    2014-01-01

    This paper deals with the delamination of chemical properties and hardgrove grindability index (HGI) of coal samples collected from three different coal fields of Punjab; Eastern Salt Range, Central Salt Range and Makerwal coal fields. The chemical properties of Punjab coal reveal that most of the Punjab coal belongs to sub-bituminous category except coal of Tunnel C section of Makerwal Collieries and Iqbal Mineral coal mine of Dalwal, which are high volatile bituminous and lignite, respectively. The results of the research show that the HGI values of Punjab coal vary from 57 to 92. The eastern salt range coals are found to be the softest coals among that of three coal fields. It was further observed that the HGI values of the Punjab coal decrease with increasing moisture content, fixed carbon and sulphur contents, while it has a positive relation with volatile matter, ash content and gross calorific value. It was concluded that moisture content at its lower range has negligible effect on HGI of the Punjab coal. (author)

  15. Three-dimensional sulphur/nitrogen co-doped reduced graphene oxide as high-performance supercapacitor binder-free electrodes

    Science.gov (United States)

    Huo, Jinghao; Zheng, Peng; Wang, Xiaofei; Guo, Shouwu

    2018-06-01

    Sulphur/nitrogen co-doped reduced graphene oxide (SNG) aerogels were prepared by a simple solvothermal method with l-cysteine-assisted in ethylene glycol. The morphology and composition tests showed that the S/N heteroatoms were evenly distributed on SNG microsheets, and these microsheets were further composed of SNG aerogels with three-dimensional (3D) porous structure. The cyclic voltammetry and galvanostatic charge/discharge tests illustrated the SNG bind-free electrode possessed electric double-layer capacitance and pseudocapacitance, and had a capacitance of 254 F g-1 at a current density of 1 A g-1. After the 5000 cycles tests, the capacitance retained 83.54% at a current density of 2 A g-1. Meanwhile, the electrochemical impedance spectroscopy data shown the electrode materials had excellent capacity and good conductivity. Hence, the SNG aerogel prepared by l-cysteine-assisted solvothermal method is a great material for high-performance supercapacitors.

  16. Relationship between coal and coke microstructure and the high temperature properties of coke. [Temperature dependence

    Energy Technology Data Exchange (ETDEWEB)

    Tsuyuguchi, K; Yamaji, M; Sugimoto, Y

    1980-02-01

    This paper considers the relationship of the properties of coke and parent coal with the high temperature properties, including reactivity, of coke. Aspects considered include coke texture and grade, and the optical reflectivity of coal and coke. (8 refs.) (In Japanese)

  17. High rate spectroscopy for on-line nuclear coal analyzer (Nucoalyzer)

    International Nuclear Information System (INIS)

    McQuaid, J.H.; Brown, D.R.; Gozani, T.; Bozorgmanesh, H.

    1980-01-01

    A high count rate, time-variant Ge(Li) spectrometer has been developed for on-line coal analysis. The analyzer is being fabricated for use in a power generating station. Prompt neutron activation of coal samples is the basis of analysis, with 252 Cf as the source for irradiation. The spectroscopy system allows counting rates up to 150 k counts per second without significant loss in energy resolution or peak shape. The high data throughput allows the coal analyzer to be used for on-line process control. The coal analyzer will be discussed, with emphasis on the high-rate signal processing system. Results of analysis of coal samples will be presented

  18. Impacts of Natural Surfactant Soybean Phospholipid on Wettability of High-rank Coal Reservoir

    Science.gov (United States)

    Lyu, S.; Xiao, Y.; Yuan, M.; Wang, S.

    2017-12-01

    It is significant to change the surface wettability of coal rock with the surfactant in coal mining and coalbed methane exploitation. Soybean phospholipid (SP) is a kind of natural zwitterionic surfactant which is non-toxic and degradable. In order to study the effects of soybean phospholipid on wettability of high-rank coal in Qinshui Basin, some experiments including surface tension test, contact angle measurement on the coal surface, coal fines imbibition, observation of dispersion effect and gas permeability test were carried out, and water locking mechanism of fracturing fluid in micro fractures of coal reservoir was analyzed. The results show that the surface of high-rank coal was negatively charged in solution and of weak hydrophilicity. The soybean phospholipid with the mass fraction of 0.1% reduced the surface tension of water by 69%, and increased the wettability of coal. Meanwhile, the soybean phospholipid helped coal fines to disperse by observation of the filter cake with the scanning electron microscope. The rising rate of soybean phospholipid solution in the pipe filled with coal fines was lower than that of anionic and cationic surfactant, higher than that of clean water and non-ionic surfactant. Composite surfactant made up of soybean phospholipid and OP-10 at the ratio of 1:3 having a low surface tension and large contact angle, reduced the capillary force effectively, which could be conducive to discharge of fracturing fluid from coal reservoir micro fracture and improve the migration channels of gas. Therefore it has a broad application prospect.

  19. Trace element affinities in two high-Ge coals from China

    Energy Technology Data Exchange (ETDEWEB)

    Jing Li; Xinguo Zhuang; Xavier Querol [China University of Geosciences, Wuhan (China). Faculty of Earth Resources

    2011-01-15

    The Lincang (Yunnan Province, Southwest China) and Wulantuga (Inner Mongolia, Northeast China) coal deposits are known because of the high-Ge content. These coals have also a high concentration of a number of other elements. To determine the mode of occurrence of the enriched elements in both coals, six density fractions from {lt} 1.43 to {gt} 2.8 g/cm{sup 3} were obtained from two representative samples using heavy-liquids. A number of peculiar geochemical patterns characterize these high-Ge coals. Thus, the results of the chemical analysis of these density fractions showed that both coals (very distant and of a different geological age) are highly enriched (compared with the usual worldwide coal concentration ranges) in Ge, As, Sb, W, Be, and Tl. This may be due to similar geochemistry of hydrothermal fluids influencing the Earth Crust in these regions of China. Moreover, Wulantuga coal (Early Cretaceous subbituminous coal) is also enriched in Ca, Mg, and Na, and Lincang coal (Neogene subbituminous coal) in K, Rb, Nb, Mo, Sn, Cs, and U. A group of elements consisting of Ge, W, B, Nb, and Sb mostly occur with an organic affinity in both coals. Additionally, Be, U, and Mo (and partially Mn and Zn) in Lincang, and Na and Mg in Wulantuga occur also with a major organic affinity. Both coals have sulfide-arsenide mineral assemblages (Fe, S, As, Sn, and Pb, and in addition to Tl, Ta, and Cs in the Lincang coal). The occurrence of Al, P, Li, Sc, Ti, V, Cr, and Zr in both coals, and Ba in Lincang, are associated with the mineral assemblage of silico-aluminates and minor heavy minerals. Furthermore, P, Na, Li, Sc, Ti, Ga, Rb, Zr, Cr, Ba, Th, and LREE (La, Ce, Pr, Nd, and Gd) in Lincang are associated with mineral assemblages of phosphates and minor heavy minerals. The two later mineral assemblages are derived from the occurrence of detrital minerals. 34 refs., 7 figs., 3 tabs.

  20. Sulphur in the Sculptor dwarf spheroidal galaxy. Including NLTE corrections

    NARCIS (Netherlands)

    Skúladóttir, Á.; Andrievsky, S. M.; Tolstoy, E.; Hill, V.; Salvadori, S.; Korotin, S. A.; Pettini, M.

    In Galactic halo stars, sulphur has been shown to behave like other α-elements, but until now, no comprehensive studies have been done on this element in stars of other galaxies. Here, we use high-resolution ESO VLT/FLAMES/GIRAFFE spectra to determine sulphur abundances for 85 stars in the Sculptor

  1. Role of sulphur in rice production

    International Nuclear Information System (INIS)

    Sachdev, Pamila; Sachdev, M.S.

    2002-01-01

    Sulphur is an essential plant nutrient growing in international importance. Rice farmers usually apply nitrogen, phosphorus and potassium at high rates to the crop. Whenever there is an imbalance between off take and input of nutrients, it may lead to a decline in soil fertility and increase incidence of deficiencies of certain plant nutrients especially sulphur and zinc. On the basis of available information, nutritional requirement, uptake values, crop response and measures to overcome S deficiency are some of the aspects critically dealt with

  2. Sulphur-containing compounds in sulphur-rich crude oils from hypersaline lake sediments and their geochemical implications

    NARCIS (Netherlands)

    Sinninghe Damsté, J.S.; Guoying, S.; Jiamo, F.; Brassell, S.C.; Gowar, A.P.; Eglinton, G.; Leeuw, J.W. de; Schenck, P.A.

    1987-01-01

    Three sulphur-rich commercial crude oils have been studied, which contain sulphur as high as up to 4 —12 %. These samples were collected from Tertiary hypersaline lake sediments of the Jianghan Basin, Hubei Province at different depths, but above the oil generation threshold (2200m). FPD-GC and

  3. CO2 Emission Factors for Coals

    Directory of Open Access Journals (Sweden)

    P. Orlović-Leko

    2015-03-01

    (calcite and siderite directly contribute CO2 when they decompose during coal combustion. Variations in the maceral content can also influence CO2 emissions; high inertinite contents increase CO2 emissions. Sulphur in coal reduces EF(CO2. Fuel analysis is very important when estimating greenhouse gas emissions and emission factors. In this preliminary study, based on the results of the fuel analysis, CO2 emission factors for coals and peat from Livno, B&H have been calculated. EF(CO2 is defined as the amount of carbon dioxide emission per unit net calorific values of the fuel. Net calorific value (the lower heating value corresponds to the heat produced by combustion where total water in the combustion products exists as water vapour. The EF(CO2 obtained for sub-bituminous coal, lignite and peat were: 98.7, 109.5, and 147.9 t TJ−1, respectively, which correspond to the following net calorific values: 20.6, 11.5 and 3.6 MJ kg−1. The heating value is generally known to increase with the increase in carbon content (this parameter is connected with the degree of coalification, coal age. The other indispensable parameters are hydrogen, which has a positive effect on the net calorific value, and oxygen and water which impact the net calorific value negatively. The differences in net calorific values can be explained in part by the difference of total moisture content among the different fuel types. The CO2 emission factors calculated in this study were compared with those of IPCC. A significant difference was observed for peat (39.5 %, followed by lignite (8.2 % and sub-bituminous coal (4.3 %.

  4. Sulphur recirculation for reduced boiler corrosion; Minskad pannkorrosion med svavelrecirkulation

    Energy Technology Data Exchange (ETDEWEB)

    Andersson, Sven; Karlsson, Martin (Goetaverken Miljoe AB, Goeteborg (Sweden)); Blomqvist, Evalena; Baefver, Linda; Claesson, Frida; Davidsson, Kent (SP Sveriges Tekniska Forskningsinstitut, Boraas (Sweden)); Froitzheim, Jan; Pettersson, Jesper; Steenari, Britt-Marie (Chalmers Tekniska Hoegskola, Oorganisk miljoekemi, Goeteborg (Sweden))

    2010-03-15

    decreased by one third and the particle concentrations was decreased by half. In the sulphur recirculation exposure, the corrosion rate decreased for all tested materials (16Mo3, Sanicro 28 and Inconel 625) compared to the reference exposure. For the low-alloyed 16Mo3, the corrosion rate was reduced by more than 60%. The corrosion rate was rather low for the high-alloyed steels, even in the reference exposure. The corrosion morphology of the samples exposed in the sulphur recirculation exposure was different compared to the samples exposed in the reference exposure. Sulphur recirculation prevented the formation of transition metal chlorides at the metal/oxide interface, formation of chromate and reduced the presence of zinc in the corrosion products. When sulfur recirculation was applied to the process, the dioxin concentration (I-TEQ) of the flue gas was reduced by approximately a quarter (PCDFs were reduced by a factor of two but PCDD levels did not change significantly). Meanwhile the chlorobenzenes (PCBz) were reduced by half. A slight reduction of the dioxin levels (PCDD and PCDF) in the fly ash was found, which together with the reduced amounts of fly ash leads to less dioxins being landfilled

  5. Possible strategies in development of highly productive underground coal mining

    Energy Technology Data Exchange (ETDEWEB)

    Djoric, M

    1980-01-01

    This paper explains the basic strategies which may be applied in the exploitation of coal deposits by underground mining. It outlines the importance of combinations of extensive (non-mechanized) and intensive (mechanized) exploitation and their dependence on coal demand, available financial means, requirements concerning the protection of environment, unemployment of the population, availability of mechanical and electrical equipment, technical staff, etc. It is suggested that the applied strategy be revised and adapted to the current situation. Postponement of exploitation until the future when the demand and price of coal may be higher is criticized. The possibility of applying extensive underground mining in areas where unemployment and lack of capital speak against the application of fully mechanized working methods is also dealt with. (In Serbo-Croatian)

  6. Washability and Distribution Behaviors of Trace Elements of a High-Sulfur Coal, SW Guizhou, China

    Directory of Open Access Journals (Sweden)

    Wei Cheng

    2018-02-01

    Full Text Available The float-sink test is a commonly used technology for the study of coal washability, which determines optimal separation density for coal washing based on the desired sulfur and ash yield of the cleaned coal. In this study, the float-sink test is adopted for a high-sulfur Late Permian coal from Hongfa coalmine (No.26, southwestern Guizhou, China, to investigate its washability, and to analyze the organic affinities and distribution behaviors of some toxic and valuable trace elements. Results show that the coal is difficult to separate in terms of desulfurization. A cleaned coal could theoretically be obtained with a yield of 75.50%, sulfur 2.50%, and ash yield 11.33% when the separation density is 1.57 g/cm3. Trace elements’ distribution behaviors during the gravity separation were evaluated by correlation analysis and calculation. It was found that Cs, Ga, Ta, Th, Rb, Sb, Nb, Hf, Ba, Pb, In, Cu, and Zr are of significant inorganic affinity; while Sn, Co, Re, U, Mo, V, Cr, Ni, and Be are of relatively strong organic affinity. LREE (Light rare earth elements, however, seem to have weaker organic affinity than HREE (Heavy rare earth elements, which can probably be attributed to lanthanide contraction. When the separation density is 1.60 g/cm3, a large proportion of Sn, Be, Cr, U, V, Mo, Ni, Cd, Pb, and Cu migrate to the cleaned coal, but most of Mn, Sb and Th stay in the gangue. Coal preparation provides alternativity for either toxic elements removal or valuable elements preconcentration in addition to desulfurization and deashing. The enrichment of trace elements in the cleaned coal depends on the predetermined separation density which will influence the yields and ash yields of the cleaned coal.

  7. Control of spontaneous combustion of coal in goaf at high geotemperatureby injecting liquid carbon dioxide: inertand cooling characteristics of coal

    Science.gov (United States)

    Liu, Zhenling; Wen, Hu; Yu, Zhijin; Wang, Chao; Ma, Li

    2018-02-01

    The spontaneous combustion of coal in goaf at high geo temperatures is threatening safety production in coalmine. The TG-DSC is employed to study the variation of mass and energy at 4 atmospheres (mixed gases of N2, O2 and CO2) and heating rates (10°C/min) during oxidation of coal samples. The apparent activation energy and pre-exponential factor of coal oxidation decrease rapidly with increasing theCO2 concentration. Furthermore, its reaction rate is slow, its heat released reduces. Based on the conditions of 1301 face in the Longgucoalmine, a three-dimensional geometry model is developed to simulate the distributions stream field and temperature field and the variation characteristics ofCO2 concentration field after injecting liquidCO2. The results indicate that oxygen reached to depths of˜120m in goaf, 100m in the side of inlet air, and 10m in the side of outlet air before injecting liquidCO2. After injecting liquidCO2for 28.8min, the width of oxidation and heat accumulation zone is shortened by 20m, and the distance is 80m in the side of working face and 40˜60m in goafin the direction of dip affected by temperature.

  8. Ge distribution in the Wulantuga high-germanium coal deposit in the Shengli coalfield, Inner Mongolia, northeastern China

    Energy Technology Data Exchange (ETDEWEB)

    Du, Gang [Key Laboratory of Marginal Sea Geology, Chinese Academy of Sciences (China)]|[Coal Geology Bureau of Inner Mongolia, Hohhot, 010051 (China); Zhuang, Xinguo [Institute of Sedimentary Basin and Mineral, Faculty of Earth Resources, China University of Geosciences, Hubei, 430074 (China)]|[State Key Laboratory of Geological Processes and Mineral Resources, China University of Geosciences, Hubei, 430074 (China); Querol, Xavier; Izquierdo, Maria; Alastuey, Andres; Moreno, Teresa; Font, Oriol [Institute of Earth Science ' Jaume Almera' , CSIC, C/ LLuis Sole Sabaris s/n, 08028 Barcelona (Spain)

    2009-03-01

    The geological and geochemical controls of the Ge distribution in the Cretaceous Wulantuga high-Germanium coal deposit in the Shengli coal field, Inner Mongolia are investigated. This paper focuses mainly on the spatial distribution of the Ge contents in coal. The high-Ge coals mainly occur in three splits of the 6 coal in the southwestern part of the Shengli coal field. Mean germanium contents in the coal range from 32 to 820 {mu}g/g, with a mean value of 137 {mu}g/g, on a bulk coal basis (mean of 939 coal samples from 75 boreholes in the 6 coal seam) in an area of 2.2 km{sup 2}. The highest Ge content occurs SW of 6 coal seam, close to the margins of the coal basin, decreasing with a fan-shaped trend towards NW, the direction of the coal basin. There is an negative correlation between the mean Ge content and the thickness of the coal seam. Different distribution patterns of Ge content were found in vertical profiles. High Ge concentrations may occur in the middle parts of coal seams, at the bottom and/or the top of thick coal seams and inconspicuous variation. A major organic affinity was determined for Ge, with a special enriched in the banded bright and semibright coal. The high-Ge coals and the coalified wood in the sandstone overlaying the 6-1 coal highly enriched in Ge, As, Sb, W, Cs, Tl, Be, and Hg. The Late Jurassic silicified volcanic rocks in the NW of the Ge coal deposit relatively high enriched in Ge, Ga, Sb, As, Cs, Be, Ge and Hg. The correlation coefficients among the elements enriched showed marked variations at close sites in this deposit, suggesting a possible diagenetic origin of the geochemical anomaly. The main Ge anomaly was attributed to early Cretaceous hydrothermal fluids circulating through the fault systems and porous volcanic rocs, probably from the subjacent granitoid rocks. The fault systems, the porous coarse clastic rocks overlying coal seam and the lithotype of coal played an important role in the transport and trapping of Ge. A

  9. Characterization of Egyptian coal from Sinai using Moessbauer spectroscopy

    International Nuclear Information System (INIS)

    Eissa, N.A.; Abdel Meguid, M.M.; Deriu, A.; Albanese, G.

    1983-08-01

    The presence of iron bearing minerals in coal makes the Moessbauer Spectroscopy (MS) extremely useful for characterization of coals from different localities. In this paper the MS has been applied to characterize Egyptian coal from Sinai (Maghara). The chemical analysis of this coal is given. The MS results showed that pyritic sulphur (pyrite and marcasite) is the only bearing mineral in Egyptian coal. A review is given for the iron bearing minerals in coals from different countries measured by MS. (author)

  10. Impact of sulphur fumigation on the chemistry of ginger.

    Science.gov (United States)

    Wu, Cheng-Ying; Kong, Ming; Zhang, Wei; Long, Fang; Zhou, Jing; Zhou, Shan-Shan; Xu, Jin-Di; Xu, Jun; Li, Song-Lin

    2018-01-15

    Ginger (Zingiberis Rhizoma), a commonly-consumed food supplement, is often sulphur-fumigated during post-harvest handling, but it remains unknown if sulphur fumigation induces chemical transformations in ginger. In this study, the effects of sulphur fumigation on ginger chemicals were investigated by ultra-high performance liquid chromatography coupled with quadrupole time-of-flight mass spectrometry (UHPLC-QTOF-MS/MS)-based metabolomics. The results showed that sulphur fumigation significantly altered the holistic chemical profile of ginger by triggering chemical transformations of certain original components. 6-Gingesulphonic acid, previously reported as a naturally-occurring component in ginger, was revealed to be a sulphur fumigation-induced artificial derivative, which was deduced to be generated by electrophilic addition of 6-shogaol to sulphurous acid. Using UHPLC-QTOF-MS/MS extracting ion analysis with 6-gingesulphonic acid as a characteristic chemical marker, all the commercial ginger samples inspected were determined to be sulphur-fumigated. The research outcomes provide a chemical basis for further comprehensive safety and efficacy evaluations of sulphur-fumigated ginger. Copyright © 2017 Elsevier Ltd. All rights reserved.

  11. The mechanism of coking pressure generation I: Effect of high volatile matter coking coal, semi-anthracite and coke breeze on coking pressure and plastic coal layer permeability

    Energy Technology Data Exchange (ETDEWEB)

    Seiji Nomura; Merrick Mahoney; Koichi Fukuda; Kenji Kato; Anthony Le Bas; Sid McGuire [Nippon Steel Corporation, Chiba (Japan). Environment and Process Technology Center

    2010-07-15

    One of the most important aspects of the cokemaking process is to control and restrain the coking pressure since excessive coking pressure tends to lead to operational problems and oven wall damage. Therefore, in order to understand the mechanism of coking pressure generation, the permeability of the plastic coal layer and the coking pressure for the same single coal and the same blended coal were measured and the relationship between them was investigated. Then the 'inert' (pressure modifier) effect of organic additives such as high volatile matter coking coal, semi-anthracite and coke breeze was studied. The coking pressure peak for box charging with more uniform bulk density distribution was higher than that for top charging. It was found that the coking pressure peaks measured at different institutions (NSC and BHPBilliton) by box charging are nearly the same. The addition of high volatile matter coking coal, semi-anthracite and coke breeze to a low volatile matter, high coking pressure coal greatly increased the plastic layer permeability in laboratory experiments and correspondingly decreased the coking pressure. It was found that, high volatile matter coking coal decreases the coking pressure more than semi-anthracite at the same plastic coal layer permeability, which indicates that the coking pressure depends not only on plastic coal layer permeability but also on other factors. Coking pressure is also affected by the contraction behavior of the coke layer near the oven walls and a large contraction decreases the coal bulk density in the oven center and hence the internal gas pressure in the plastic layer. The effect of contraction on coking pressure needs to be investigated further. 33 refs., 18 figs., 5 tabs.

  12. Natural radionuclides in coal and waste material originating from coal fired power plant

    International Nuclear Information System (INIS)

    Marovic, Gordana; Franic, Zdenko; Sencar, Jasminka; Petrinec, Branko; Bituh, Tomislav; Kovac, Jadranka

    2008-01-01

    This paper presents long-term investigations of natural radioactivity in coal, used for power production in the coal-fired power plant (CFPP) situated on the Adriatic coast, and resulting slag and ash. Activity concentrations of 40 K, 232 Th, 226 Ra and 238 U in used coal and resulting waste material have been measured for 25 years. As expected, it was demonstrated that the content of radionuclides in deposited bottom and filter ash material are closely related with radionuclide activity concentrations and mineral matter fraction in used coals. The external hazard index has been calculated and discussed for the slag and ash depository. During the first decade of operation of the CFPP has been used domestic coal produced in nearby area characterized by higher background radiation compared with the rest of Croatia. Therefore, the coal itself had relatively high 226 Ra and 238 U activity concentrations while potassium and thorium content was very low, 40 K activity concentrations being 2-9% and those of 232 Th 1-3% of total activity. As, in addition, the sulphur concentrations in coal were very high use of domestic coal was gradually abandoned till it was completely substituted by imported coal originated from various sources and of low natural radioactivity. Upon this, activity concentrations of uranium series radionuclides in deposited waste materials decreased significantly. Consequently, waste material i.e., slag and ash, generated in the last several years of coal fired power plant operation could be readily used in cement industry and as additive to other building materials, without any special restrictions according to the Croatian regulations dealing with building materials and European directives. (author)

  13. Prompt nuclear coal analysis ups profits

    International Nuclear Information System (INIS)

    Barker, D.

    1982-01-01

    To maximise profitability it is essential that products should comply with specification, while ensuring that mining procedures are designed to optimise fully the exploitation of coal reserves. For the producer to realise maximum profits, it is necessary to produce a consistently satisfactory product, while utilising the lowest possible quality of reserves. For the potential need for on-stream analysis, a comprehensive research program, produced several unique systems. The Nucoalyzer CONAC has been developed to analyse continuously a coal sample stream of up to 13 t/h. On-stream analysis is also particularly appropriate as a means of controlling a coal beneficiation plant, especially where coal have a high middling content. Major coal users such as thermal power stations and Synfuel processes can also realise substantial economic benefits through the use of on-stream analysis. On-stream analysis can again significantly reduce operating costs, as it offers the possibility of controlling the level of sulphur in the coal feed. The analytical principle employed in the various Nucoalyzer system is based on Prompt Neutron Activation Analysis

  14. Zulia rich coal seams to fuel Venezuela

    Energy Technology Data Exchange (ETDEWEB)

    1983-06-16

    In March, 1982, Carbozulia awarded a contract to Fluor Corp. to provide basic engineering services, including mine planning and geology, for the two-phase project. The open pit mine and ancillary facilities, valued at more than $200 million, will provide steam and metallurgical coal for domestic use. The site, Mina Paso Diablo, is located about 60 miles northwest of Maracaibo. Upon phase one completion sometime in 1987, the mill will start production, gradually increasing to 4 million metric-tons-per-year. This will increase to 6.4 million metric tons when phase two is completed. In addition to the mine, the Venezuelan government plans to build an industrial complex along Lake Maracaibo. Corpozulia will build a steel-rolling mill and add a 350,000 metric tons-per-year coking oven, which will consume about 7% of the mine's metallurgical-coal production. Another government-owned firm, Electric Energy of Venezuela, plans to build a thermo-electric plant nearby. Two 250-megawatt units are planned initially, with potential to add another six units. At full capacity, the plant will burn more than 90% of the coal produced from the mine. Mina Paso Diablo contains one of Latin America's largest proven coal reserves - about 350 million metric tons - with guesstimates running as high as 4 billion metric tons for the Zulia coal basin. The coal is of superior quality, running about 12,000 to 13,000 Btu's per lb. with a low ash and sulphur content.

  15. Oxidation of inorganic compounds of sulphur by various sulphur bacteria

    Energy Technology Data Exchange (ETDEWEB)

    Parker, C D; Prisk, J

    1953-01-01

    Cultures of thiobacillus thiooxidans, Th. thioparus, Th. novellus, Thiobacillus b strains t and kand Th. concretivorus, Thiobacillus x and the m strains, organisms isolated from concrete were examined to elucidate the mode of oxidation and to establish the identity of the organisms recently isolated from corroded concrete. Thiosulphate was oxidized by all these bacteria. Th. thiooxidans, Th. concretivorus and Thiobacillus x first converted it to tetrathionate and sulphate and then oxidized the tetrathionate to sulphate and free sulphuric acid. Thiobaciullus x differed from the other two in that, owing to a lesser acid tolerance, some tetrathionate was found in the final products of oxidation. Th. Thioparus converted thiosulphate to sulphate and sulphur, followed by partial oxidation of the sulphur to sulphuric acid. Th. novellus produced sulphate and sulphuric acid. Thiobacillus b, the t and k strains and the m strains formed sulphate and tetrathionate with temporary increase in pH value; only Thiobacillus x oxidized tetrationate, yielding sulphate and sulphuric acid. Elementary sulphur was oxidized by Th. thiooxidans, th. Concretivorus, thiobacillus x and Th. thioparus; the rates of oxidation decreased in that order, and the only product was sulphuric acid. Hydrogen sulphide was oxidized only at low concentrations and only by th. Concretivorus and Thiobacillus x; sulphuric acid was the end-product, and elementary sulphur may have been an intermediate. Thiobacillus x differed from Th. thiooxidans in pH range for growth and from Th. thioparus in its method of oxidation of thiosulphate, tetrathionate and H/sub 2/S. The m strains were similar to thiobacillus b and the t and k strains of trautwein.

  16. Mineralogic and element association of coals from the Gevra mine, Korba coal field, Madhya Pradesh, India

    International Nuclear Information System (INIS)

    Hart, B.R.; Powell, M.A.; Fyfe, W.S.; Sahu, K.C.; Tripathy, S.

    1991-01-01

    As a part of a project to study the content and distribution of trace elements in coals and coal by-products from coal mining areas of India, the mineral and elemental composition of the whole coal and concentration of the selective elements in the whole coal mined from the Gevra mine of the Korba coal field in Madhya Pradesh are studied. The vertical trend of the selected elements are defined and possible relationships of these elements to the minerals present in or associated with the above coal are examined. The Gevra Coals have ash contact ( 3 times world average) and low sulphur content (1/4 of world average). Most elements are found to be positively correlated with ash indicating an inorganic association. Elements which show organic affinity include S, Cl, I and In. Fe, Cu, Zn and Pb occur in sulfide phases, the dominant Fe phase identified is siderite which also contain Mn and Mg. Th and U along with varying proportions of rare earths, Ce, Dy, La and Y have been identified with discrete phosphate minerals. Most trace elements have been found to be concentrated in the upper and lower portions of the coal seam exposed in Gevra mine and in partings. It is, therefore, suggested that selective mining and removal of high ash/inorganic material, particularly the upper and lower portion of the seam, will greatly reduce the mobilization of Al, As, Co, Fe, Hf, Sc, Si, Ti and to a lesser degree Cr, La, Mn, Th U and V during combustion of coal in power plants and consequently will reduce the influx of trace elements to the environment. (M.G.B.). 23 refs., 5 figs

  17. Vapor mercury uptake with sulphur impregnated active carbons derived using sulphur dioxide

    International Nuclear Information System (INIS)

    Tong, S.; Methta, H.; Ahmed, I.; Morris, E.; Fuentes de Maria, L.; Jia, C.Q.

    2008-01-01

    Active carbon adsorption is the primary technology used for removal of vapour mercury from flue gases in coal-fired power plants, municipal solid waste combustors, and other sources. It can be carried out using two different processes, notably injection of powder active carbon into flue gas streams upstream of the particulate collection devices, and filtration with a granular active carbon fixed bed downstream of the flue gas desulphurization units and/or particulate collectors. This paper presented an investigation of vapour mercury uptake performance of laboratory-made sulphur impregnated active carbons (SIACs) using a fixed bed reactor in a temperature range of 25 to 200 degrees Celsius. The materials and methods as well as the properties of activated carbons studied were presented. The experimental set-up was also described. The paper discussed the effects of initial concentration, the flow rate, the loading amount of SIACs, temperature, and the sulphur impregnation on the mercury uptake performance. The study showed that SIACs produced with sulphur dioxide exhibited a more complicated behaviour when temperature was varied, implying a mixed adsorption mechanism. 10 refs., 3 tabs., 8 figs

  18. Modular High Temperature Gas-Cooled Reactor heat source for coal conversion

    International Nuclear Information System (INIS)

    Schleicher, R.W. Jr.; Lewis, A.C.

    1992-09-01

    In the industrial nations, transportable fuels in the form of natural gas and petroleum derivatives constitute a primary energy source nearly equivalent to that consumed for generating electric power. Nations with large coal deposits have the option of coal conversion to meet their transportable fuel demands. But these processes themselves consume huge amounts of energy and produce undesirable combustion by-products. Therefore, this represents a major opportunity to apply nuclear energy for both the environmental and energy conservation reasons. Because the most desirable coal conversion processes take place at 800 degree C or higher, only the High Temperature Gas-Cooled Reactors (HTGRs) have the potential to be adapted to coal conversion processes. This report provides a discussion of this utilization of HTGR reactors

  19. A new technology aimed at re-establishing a global sulphur supply/demand balance

    International Nuclear Information System (INIS)

    Slavens, A.F.; Jorgensen, C.; Ogg, D.

    2009-01-01

    The world's sulphur supply is mainly determined by involuntary production of elemental sulphur during the processing of oil and gas. As a result, sulphur supply is decoupled from demand, resulting in an imbalance between the two. For almost two decades, sulphur supply has exceeded demand, which has raised significant concerns for oil and gas producers such as where to store all of the excess sulphur, and how to transport a low-value commodity to market in an economically attractive fashion. Black and Veatch is involved in the development of a new technology called sulphur to energy process (STEP TM ) which has the potential to assist in balancing global sulphur supply and demand, as well as affording other benefits such as low-emission energy production. This paper presented the potential merits of the STEP as a means to reestablish a global sulphur supply/demand balance for the world trading market. It explored the other potential benefits that may result from the use of this new technology and compared STEP to other technologies and operating schemes that regulate sulphur supply. It was concluded that STEP has the potential to allow the processor to produce elemental sulphur when demand is high, or to provide safe and ecological disposal when demand is low, with the added benefits of energy recovery from the sulphur combustion process, and sour gas reservoir sweetening over time as sulphur dioxide reacts with hydrogen sulphide present in the reservoir. 13 refs., 3 tabs., 22 figs

  20. Biological parameters in technogenic soils of a former sulphur mine

    Science.gov (United States)

    Siwik-Ziomek, Anetta; Brzezińska, Małgorzata; Lemanowicz, Joanna; Koper, Jan; Szarlip, Paweł

    2018-04-01

    This study was conducted on the soils originating from a reclamation area of the former sulphur mine in Tarnobrzeg, Poland. Soil was sampled 16 years after the completion of mining works with the open-pit method at Machów, as well as 7 years after sulphur mining via the `smelting' method in the Jeziórko mine was abandoned. Several biological parameters were examined: soil respiration, soil microbial biomass and the activity of rhodanese and arylsulphatase enzymes taking part in sulphur transformation within the site's soils. The soils showed a high total sulphur and sulphates content. The SO42- constituted a large fraction of total sulphur, in some cases, exceeding 80% or even 95% of total sulphur. The soil pH decreased due to the degrading effects of sulphur mining. In the soils studied from the locations with the lowest soil pH value, no activity of arylsulphatase was reported and the activity of rhodanese was lowest. The highest soil respiration values were recorded from the 0-5 cm layer in the areas covered with forest vegetation. A high soil respiration value at the waste heap at Machów wherein a very high concentration of Stot and SO42- was observed can be due to the ability of fungi to produce hyphal strands and to survive unfavourable conditions.

  1. Mercury and sulphur among the High Medieval alchemists: from Rāzī and Avicenna to Albertus Magnus and pseudo-Roger Bacon.

    Science.gov (United States)

    Newman, William R

    2014-11-01

    This essay challenges the often expressed view that the principles of metals, namely mercury and sulphur, were generally viewed by alchemists as being of a 'metaphysical' character that made them inaccessible to the tools and operations of the laboratory. By examining a number of Arabo-Latin and Latin alchemical texts in circulation before the end of the thirteenth century, the author presents evidence that most alchemists of the period considered mercury and sulphur to be materials subject to techniques of purification in the same way that naturally occurring salts and minerals could be freed of their impurities or dross. The article also points to the immense influence of Avicenna and Albertus Magnus in formulating the theory that mercury and sulphur were compounds of different materials, containing both fixed and unfixed components. Finally, the author briefly examines the relationship between this materialist approach to the principles and the chymical atomism of early modern authors who were deeply aware of medieval alchemical literature.

  2. Effect of organized assemblies. Part 4. Formulation of highly concentrated coal-water slurry using a natural surfactant

    Energy Technology Data Exchange (ETDEWEB)

    Debadutta Das; Sagarika Panigrahi; Pramila K. Misra; Amalendu Nayak [Sambalpur University, Orissa (India). Centre of Studies in Surface Science and Technology

    2008-05-15

    Coal-water slurry has received considerable research nowadays due to its ability in substituting energy sources. The present work reports the formulation of highly concentrated coal-water slurry using a natural occurring surface active compound, saponin, extracted from the fruits of plant Sapindous laurifolia. The isolation of saponin from the plant and its surface activity has been discussed. The rheological characteristics of coal-water slurry have been investigated as a function of coal loading, ash content of coal, pH, temperature, and amount of saponin. The viscosity of the slurry and zeta potential are substantially decreased with concomitant shift of the isoelectric point of coal on adsorption of saponin to it. In the presence of 0.8% of saponin, coal-water slurry containing 64% weight fraction of coal could be achieved. The slurry is stable for a period of as long as 1 month in contrast to 4-5 h in the case of bare coal-water slurry. The results confirm the use of saponin as a suitable additive for coal-water slurry similar to the commercially available additive such as sodium dodecyl sulfate. Basing on the effect of pH on the zeta potential and viscosity of slurry, a suitable mechanism for saponin-coal interaction and orientation of saponin at the coal-water interface has been proposed. 47 refs., 12 figs., 5 tabs.

  3. Release of inorganic trace elements from high-temperature gasification of coal

    Energy Technology Data Exchange (ETDEWEB)

    Blaesing, Marc

    2012-05-30

    The development of cleaner, more efficient techniques in next-generation coal power plants is becoming increasingly important, especially regarding to the discussion of the influence of CO{sub 2} emissions on global warming. A promising coal utilisation process is the integrated gasification combined cycle process. The direct use of the raw gas requires gas clean-up to prevent downstream parts of the gasifier from several problems. An increased efficiency and a decreased amount of harmful species can be achieved through hot fuel gas cleaning. This clean-up technique requires a comprehensive knowledge of the release characteristics of inorganic coal constituents. The aim of this thesis was to provide enhanced knowledge of the effect of key process parameters and of the chemical constitution of coal on the release of Na, K, S, and Cl species from high-temperature coal gasification. The experimental setup consisted of atmospheric flow tube furnaces and a pressurised furnace. In-situ analysis of the product gas was carried out using molecular beam mass spectrometry. A broad spectrum of different coals with assumed qualitative and quantitative differences in the release characteristics was investigated. Additionally, experiments with model substances were performed. The results of the experimental investigation were compared with thermodynamic calculations. Finally, recommendations, for the operation of a high-temperature gasifier are formulated. (orig.)

  4. Technology Roadmap: High-Efficiency, Low-Emissions Coal-Fired Power Generation

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    2012-07-01

    Coal is the largest source of power globally and, given its wide availability and relatively low cost, it is likely to remain so for the foreseeable future. The High-Efficiency, Low-Emissions Coal-Fired Power Generation Roadmap describes the steps necessary to adopt and further develop technologies to improve the efficiency of the global fleet of coal. To generate the same amount of electricity, a more efficient coal-fired unit will burn less fuel, emit less carbon, release less local air pollutants, consume less water and have a smaller footprint. High-efficiency, low emissions (HELE) technologies in operation already reach a thermal efficiency of 45%, and technologies in development promise even higher values. This compares with a global average efficiency for today’s fleet of coal-fired plants of 33%, where three-quarters of operating units use less efficient technologies and more than half is over 25 years old. A successful outcome to ongoing RD&D could see units with efficiencies approaching 50% or even higher demonstrated within the next decade. Generation from older, less efficient technology must gradually be phased out. Technologies exist to make coal-fired power generation much more effective and cleaner burning. Of course, while increased efficiency has a major role to play in reducing emissions, particularly over the next 10 years, carbon capture and storage (CCS) will be essential in the longer term to make the deep cuts in carbon emissions required for a low-carbon future. Combined with CCS, HELE technologies can cut CO2 emissions from coal-fired power generation plants by as much as 90%, to less than 100 grams per kilowatt-hour. HELE technologies will be an influential factor in the deployment of CCS. For the same power output, a higher efficiency coal plant will require less CO2 to be captured; this means a smaller, less costly capture plant; lower operating costs; and less CO2 to be transported and stored.

  5. Experiences in sulphur capture in a 30 MWth Circulating Fluidized Bed boiler under oxy-combustion conditions

    International Nuclear Information System (INIS)

    Gómez, M.; Fernández, A.; Llavona, I.; Kuivalainen, R.

    2014-01-01

    CO 2 and SO 2 from fossil fuel combustion are contributors to greenhouse effect and acid rain respectively. Oxy-combustion technology produces a highly concentrated CO 2 stream almost ready for capture. Circulating Fluidized Bed (CFB) boiler technology allows in-situ injection of calcium-based sorbents for efficient SO 2 capture. CIUDEN's 30 MWth CFB boiler, supplied by Foster Wheeler and located at the Technology Development Centre for CO 2 Capture and Transport (es.CO 2 ) in Spain, is the first of its kind for executing test runs at large pilot scale under both air-combustion and oxy-combustion conditions. In this work, SO 2 emissions under different scenarios have been evaluated. Variables such as limestone composition, Ca/S molar ratio and bed temperature among others have been considered along different test runs in both air-combustion and oxy-combustion conditions to analyse its influence on SO 2 abatement. Fly and bottom ash, together with flue gas analysis have been carried-out. Desulphurization performance tests results are presented. - Highlights: •Sulphur capture efficiency (%) was higher in oxy-combustion compared to air-combustion in a 30 MW thermal CFB boiler using anthracite and limestone as sulphur sorbent. •For a Ca/S molar ratio higher than 2.6 there was barely any improvement on sulphur capture efficiency for both air-combustion and oxy-combustion conditions in a 30 MW thermal CFB boiler using anthracite and limestone as sulphur sorbent. •Optimum temperature for sulphur capture at a fixed Ca/S molar ratio is around 880–890 °C under oxy-combustion conditions and for anthracite coal with limestone as sorbent in a 30 MW thermal CFB boiler

  6. Investigation of sulfur-polycyclic aromatic hydrocarbon in coal derived tars of pyrolysis and hydropyrolysis

    Energy Technology Data Exchange (ETDEWEB)

    Chen, H.; Li, B.; Zhang, B. [Chinese Academy of Sciences, Taiyuan (China). State Key Laboratory of Coal Conversion

    1999-07-01

    A study was undertaken to characterize sulphur forms in coal derived tars from pyrolysis and hydropyrolysis of bituminous coal and lignite. The pyrolysis tars were analyzed for content of polycyclic aromatic sulfur hydrocarbons (PASH). 5 refs., 3 figs., 3 tabs.

  7. Sulphur in liquid fuels 2002

    Energy Technology Data Exchange (ETDEWEB)

    Guthrie, J. [Environment Canada, Gatineau, PQ (Canada). Fuels Div., Oil, Gas and Energy Branch ; Sabourin, R. [Carleton Univ., Ottawa, ON (Canada)

    2003-08-01

    Environment Canada has developed new regulations for sulphur content in fuels in an effort to align with requirements recently passed by the U.S. Environmental Protection Agency. This report summarizes data regarding sulphur content in liquid fuels for the year 2002. The requirements of the Sulphur in Gasoline Regulation came into effect in 2002, limiting the average sulphur content of gasoline to 150 mg/kg. In January 2005, a 30 mg/kg average limit will come into effect. Also, in July 2002, the Sulphur in Diesel Fuel Regulation stipulated a maximum limit of 500 mg/kg for on-road diesel fuel. The new regulation continues this limit until mid-2006 at which time a 15 mg/kg limit will come into effect for on-road diesel fuel. Nationally, the average sulphur content in gasoline in 2002 was 246 mg/kg, which was 14.3 per cent lower than in 2001. The data covers the period from January 1 to December 31, 2002 and was obtained from petroleum refineries and importing companies that are required to submit quarterly information to the regional office of Environment Canada. Failure to comply results in penalties. The report includes data for aviation turbo fuel, motor gasoline, aviation gasoline, kerosene oil, low-sulphur diesel fuel, diesel fuel, light fuel oil, and heavy fuel oil. 16 tabs., 17 figs., 7 appendices.

  8. Direct Utilization of Coal Syngas in High Temperature Fuel Cells

    Energy Technology Data Exchange (ETDEWEB)

    Celik, Ismail B. [West Virginia University, Morgantown, WV (United States)

    2014-10-30

    This EPSCoR project had two primary goals: (i) to build infrastructure and work force at WVU to support long-term research in the area of fuel cells and related sciences; (ii) study effects of various impurities found in coal-syngas on performance of Solid Oxide Fuel Cells (SOFC). As detailed in this report the WVU research team has made significant accomplishments in both of these areas. What follows is a brief summary of these accomplishments: State-of-the-art test facilities and diagnostic tools have been built and put into use. These include cell manufacturing, half-cell and full-cell test benches, XPS, XRD, TEM, Raman, EDAX, SEM, EIS, and ESEM equipment, unique in-situ measurement techniques and test benches (Environmental EM, Transient Mass-Spectrometer-MS, and IR Optical Temperature measurements). In addition, computational capabilities have been developed culminating in a multi-scale multi-physics fuel cell simulation code, DREAM-SOFC, as well as a Beowulf cluster with 64 CPU units. We have trained 16 graduate students, 10 postdoctoral fellows, and recruited 4 new young faculty members who have actively participated in the EPSCoR project. All four of these faculty members have already been promoted to the tenured associate professor level. With the help of these faculty and students, we were able to secure 14 research awards/contracts amounting to a total of circa $5.0 Million external funding in closely related areas of research. Using the facilities mentioned above, the effects of PH3, HCl, Cl2, and H2S on cell performance have been studied in detail, mechanisms have been identified, and also remedies have been proposed and demonstrated in the laboratory. For example, it has been determined that PH3 reacts rapidly with Ni to from secondary compounds which may become softer or even melt at high temperature and then induce Ni migration to the surface of the cell changing the material and micro-structural properties of the cell drastically. It is found that

  9. Lessons from previous 'coal Transitions'. High-level summary for decision-makers, Part of 'Coal Transitions: Research and Dialogue on the Future of Coal' Project

    International Nuclear Information System (INIS)

    Caldecott, Ben; Sartor, Oliver; Spencer, Thomas

    2017-01-01

    The need for a so-called 'just transition' is acknowledged, away from carbon intensive activities, such as coal production and use. But what might a just transition look like in practice? What specific risks need to be managed and what are the best approaches to managing them? There is an urgent need to develop a deeper understanding of these issues. It is to this need that this report tries to respond. It provides a summary of lessons from six historical case studies of regional coal mining transitions that have occurred or are ongoing in Europe and the United States in recent decades. These case studies and this report were developed as part of a broader project led by IDDRI and Climate Strategies, entitled 'Coal Transitions: Research and Dialogue on the Future of Coal'. This project seeks to utilise these historical lessons to facilitate the development of feasible coal transition scenarios in large coal producing countries today'

  10. Hydrocracking of coal extracts to highly aromatic petroleum

    Energy Technology Data Exchange (ETDEWEB)

    Kotowski, W; Gorski, R

    1972-07-01

    Coal extracts were hydrocracked at 400 to 450/sup 0/C, 250 atm, 0.8 to 2.0 hr/sup -1/ space velocity, and with 1.5 cu m/l./hr of hydrogen over a bed of fluidized, 0.6 to 0.8 mm granules of nickel-molybdenum zeolite catalyst using the Consolidation Coal Co. process. The 330/sup 0/C bp extract was diluted with the 230 to 320/sup 0/C fraction of the product. At 440/sup 0/C and 1.2 hr/sup -1/ space velocity, the hydrotreatment removed 97% of the sulfur compounds, 95% of oxygen compounds, and 92% of nitrogen compounds. The yield of 35 to 230/sup 0/C gasoline stock decreased with increasing feed space velocity, but that of 230 to 340/sup 0/C gas oils increased. The synthetic crude product contained 48.7% aromatics, 35.1% naphthenes, 13.4% paraffins, 2.8% olefins, 0.14% sulfur, and 1.07% asphaltene. The product is compared with Romashkino crude.

  11. Study on multi-stage hydropyrolysis of coal in fixed-bed reactor

    Energy Technology Data Exchange (ETDEWEB)

    Wang, N.; Li, W.; Li, B.-Q. [Chinese Academy of Sciences, Taiyuan (China). State Key Lab of Coal Conversion

    1999-07-01

    The composition and quantity of the oil in hydropyrolysis (HyPy) and multi-stage HyPy with high and slow heating rate were compared and the effect of multistage HyPy process on desulfurization was investigated. Multistage HyPy of lignite and high sulphur coal were investigated and the effects of residence time, heating rate and pressure on product yields were studied. 6 refs., 4 figs., 2 tabs.

  12. US export coal in the 1990s - price, volume and quality

    Energy Technology Data Exchange (ETDEWEB)

    Bennett, J

    1991-08-01

    This report examines the following: current US coal exports; the domestic steam coal market and the domestic coking coal market; transport of export coal; reserves, production and productivity; and export markets for US coal. The report concluded that from the mid-1990s, buyers of the leading US coal export brands will face steadily rising prices as a result of fundamental shifts in the US domestic market affecting those regions supplying the bulk of the country's exports. The coals at the forefront of these price rises will be low-sulphur steam coal and high-volatile coking coal. Districts 8 and 7, the region that produces most of these types of coal, will be called upon to expand production by 50 m short tons per year by the end of the decade. However, there will be little scope for further productivity gains and because of this, and the need for significant capital investment, mining costs will rise. Inland freight rates will also rise as barge companies and railroads seek to cover investments. 53 figs., 66 tabs.

  13. High temperature corrosion behaviour of Ti-46.6Al-1.4Mn-2Mo in environments of low oxygen and high sulphur potentials at 750 and 900 C

    International Nuclear Information System (INIS)

    Du, H.L.; Datta, P.K.; Hwang, S.K.

    1997-01-01

    In this paper, the oxidation and sulphidation behaviour of a TiAl-based intermetallic, Ti-46.6Al-1.4Mn-2Mo (at%) with duplex and laminar microstructures, was investigated in environments of H 2 /H 2 S/H 2 O at 750 and 900 C. The corrosion kinetics of the intermetallic were determined by means of discontinuous gravimetry and the as-received and exposed samples were characterised using SEM, EDX and XRD. The weight gain/time data in the oxygen and sulphur containing environment used indicated parabolic kinetics with Kp∝10 -12 g 2 /cm 4 /s at 750 C and cubic kinetics at 900 C. The increase in exposure temperature did not significantly change the corrosion behaviour of the materials. The material showed the development of a multilayered scale consisting of an outermost TiO 2 layer beneath which an Al 2 O 3 layer existed: the formation of MnS and Al 2 S 3 was observed to occur between the oxide layers and substrate. This paper will discuss the significance of these results and consider the mechanisms responsible for degradation of this type of intermetallics in high sulphur and low oxygen environment with reference to their limit of temperature tolerance. (orig.)

  14. 9th international conference on high-temperature reactors - coal and nuclear energy for electricity and gas generation

    International Nuclear Information System (INIS)

    Kelber, G.

    1987-01-01

    The site of the high-temperatur reactor in the Ruhr region neighbouring on a coal-fired power plant is not accidental. The potential of the high-temperature reactor as a central plant element for the supply of heat for heating purposes and process heat covers also the possibility of coal gasification and liquefaction. Therefore the high-temperature reactor is, in the long term, a ray of hope for the coal region, able to compensate for the production-related competitive disadvantages of local coal. It can contribute to guaranteeing in the long term the task of German hard coal as an essential pillar of our energy supply. The VGB as a technical association of thermal power plant operators is particularly committed to the integration of coal and nuclear energy. Within the bounds of its possibilities, it will contribute to promoting the safe and environmentally beneficial generation of electricity from the two primary energy sources. (orig./DG) [de

  15. A model of the enhancement of coal combustion using high intensity acoustic fields

    International Nuclear Information System (INIS)

    Yavuzkurt, S.; Ha, M.Y.; Koopmann, G.H.; Scaroni, A.

    1989-01-01

    In this paper a model for the enhancement of coal combustion in the presence of high intensity acoustics is developed. A high intensity acoustic field induces an oscillating velocity over pulverized coal particles otherwise entrained in the main gas stream, resulting in increased heat and mass transfer. The augmented heat and mass transfer coefficients, expressed as space- and time-averaged Nusselt and Sherwood numbers for the oscillating flow, were implemented in an existing computer code (PCGC-2) capable of predicting various aspects of pulverized coal combustion and gasification. Increases in the Nusselt and Sherwood numbers of about 45, 60 and 82.5% at sound pressure levels of 160, 165, and 170 dB for 100 μm coal particles were obtained due to increases in the acoustic slop velocity associated with the increased sound pressure levels. The main effect of the acoustic field was observed during the char combustion phase in a diffusionally controlled situation. A decrease in the char burnout length (time) of 15.7% at 160 dB and 30.2% at 170 dB was obtained compared to the case with no sound for the 100 μm coal particles

  16. Characterization of desulfurization, denitrogenation and process sulfur transfer during hydropyrolysis of Chinese high sulfur coals

    Energy Technology Data Exchange (ETDEWEB)

    Sun Chenggong; Li Baoqing [Chinese Academy of Sciences, Taiyuan (China). State Key Lab. of Coal Conversion; Snape, C.E. [Strathclyde Univ., Glasgow (United Kingdom). Dept. of Pure and Applied Chemistry

    1997-12-31

    The process desulphurization and denitrogenation of Chinese high sulfur coals and the characteristics of sulfur transformation during non-catalytic hydropyrolysis were investigated by a 10 g fixed-bed reactor and a small-scaled reactor with online spectrometry respectively. It was indicated that more than 70% of the total sulfur of the two high sulfur coals and almost all pyritic sulfur are removed as H{sub 2}S, leaving the char and tar products with much less sulfur distribution. The liability of sulfur transformation to tar products is closely related to the thiophenic structure forms rather than sulfidic forms. At the same time, the formation of trace amount of sulfur dioxide indicates the presence of inherent sulfur oxidation reactions inside coal frame structures even under H{sub 2} pressure. (orig.)

  17. Acid leaching of coal: to produce clean fuels from Turkish lignite

    Energy Technology Data Exchange (ETDEWEB)

    Seferinoglu, Meryem [Mineral Research and Exploration Directorate (Turkey)], email: meryem_seferinoglu66@yahoo.com; Duzenli, Derya [Ankara Central Laboratory (Turkey)

    2011-07-01

    With the increasing concerns about the environment, energy producers and governments are looking at developing clean energy sources. However, Turkey has limited clean energy resources and is using low grade coal which has high sulphur content as an alternative energy source. The aim of this paper is to study the possibility of generating clean fuel from Edirne Lignite and to get a better understanding of chemical mechanisms involved in coal leaching with hydrofluoric acid (HF) solutions. Leaching was conducted on Edirne Lignite with HF solution at ambient temperature and the effects of parameters such as reaction time and concentration of acid solutions on the process were evaluated. The optimum conditions were found and it was shown that ash levels can be reduced from 28.9% to 10.5% and the calorific value increased by 500kcal/kg with the HF leaching method. This study demonstrated that the production of clean fuel from high sulphur lignite is possible.

  18. Removal of pollutants from poor quality coals by pyrolysis

    Directory of Open Access Journals (Sweden)

    Natas Panagiotis

    2006-01-01

    Full Text Available Combustion of poor quality coals and wastes is used today worldwide for energy production. However, this entails significant environmental risks due to the presence of polluting compounds in them, i. e. S, N, Hg, and Cl. In the complex environment of combustion these substances are forming conventional (i. e. SOx, NOx and toxic (PCDD/Fs pollutants, while, the highly toxic Hg is volatilized in the gas phase mainly as elemental mercury. Aiming to meet the recently adopted strict environmental standards, and the need of affordable in cost clean power production, a preventive fuels pre-treatment technique, based on low temperature carbonization, has been tested. Clean coals were produced from two poor quality Greek coals (Ptolemais and Megalopolis and an Australian coal sample, in a lab-scale fixed bed reactor under helium atmosphere and ambient pressure. The effect of carbonization temperature (200-900 °C and residence time (5-120 minutes on the properties of the chars, obtained after pyrolysis, was investigated. Special attention was paid to the removal of pollutants such as S, N, Hg, and Cl. To account for possible mineral matter effects, mainly on sulphur removal, tests were also performed with demineralized coal. Reactivity variation of produced clean coals was evaluated by performing non-isothermal combustion tests in a TA Q600 thermo gravimetric analyzer. Results showed that the low temperature carbonization technique might contribute to clean coal production by effectively removing the major part of the existing polluting compounds contained in coal. Therefore, depending on coal type, nitrogen, mercury, and chlorine abatement continuously increases with temperature, while sulphur removal seems to reach a plateau above 500-600 °C. More-over, the prolongation of carbonization time above 20 minutes does not affect the elemental conversion of the pollutants and carbonization at 500-600 °C for ~20 minutes may be considered sufficient for clean

  19. Nigerian coal analysis by PIXE and HEBS techniques

    International Nuclear Information System (INIS)

    Olabanji, S.O.

    1989-05-01

    PIXE and HEBS techniques were employed for the measurement of the concentrations of the major, minor and trace elements in Nigerian coal samples from a major deposit. The samples were irradiated with 2.55 MeV protons from the 3 MeV tandem accelerator (NEC 3 UDH) in Lund. The PIXE results are reported and compared with an earlier work on Nigerian coal using FNAA and INAA analytical techniques while the HEBS results are compared with ASTM previous results. The results corroborate the assertion that Nigerian coals are of weak and noncoking grades with low sulphur (0.82-0.99%) and relatively high hydrogen (4.49-5.16%) contents. The motivation for this work is partly due to the projected usage of coal as metallurgical feedstocks and as fuel, and partly because of the genuine concern about the concomitant environmental effects of the increased burning of coal. The knowledge of the concentration of all elements is important for the characterization of coal and the determination and control of its products. Economic parameters such as the ash contents and calorific values are associated with the concentrations of coal's constituents. (author). 11 refs, 1 fig., 4 tabs

  20. Report of National Research Institute for Pollution and Resources for fiscal 1979. Research on conversion of coal to petroleum, research on coal liquefaction, high pressure liquid phase hydrogenation of coal by continuous test equipment, and manufacture of coal chemicals; 1979 nendo sekitan no yuka no kenkyu / sekitan no ekika no kenkyu / renzoku shiken sochi ni yoru sekitan no koatsu ekiso suisoka bunkai / coal chemicals no seizo

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1980-07-01

    Research was conducted on conversion of coal to petroleum for the purpose of securing substitute liquid fuel. Recovery of hydrogen from the waste gas from the conversion process was explained, as were the conversion results from various coals produced in Japan. In coal liquefaction researches with the aim of manufacturing artificial petroleum, a report was made on each of the researches, i.e., the experiment results of coal liquefaction using various catalysts, manufacture of hydrogen by water gas reaction, catalytic action against coal paste, action of mixed oil and pressure against coal paste, result of hydrogen adding test for coal paste using an intermediate scale device, test result of secondary hydrogen addition for coal liquefied oil, and the test result of continuous secondary hydrogen addition for the liquefied oil. In the manufacture of fuel oil by hydro-cracking of coal or tar, a report was made on high pressure liquid phase hydrogenation of coal using a continuous testing device. Aromatic chemicals useful as chemical materials are supposed to be obtained by cutting inter-polymerized-unit bonding to make low molecules from the chemical structure of coal, removing surrounding radicals and simplifying it. A report was also made on the experiment of manufacturing coal chemicals by combination of high pressure liquid phase hydrogenation and hydro-dealkylation. (NEDO)

  1. Rationale for continuing R&D in direct coal conversion to produce high quality transportation fuels

    Energy Technology Data Exchange (ETDEWEB)

    Srivastava, R.D.; McIlvried, H.G. [Burns and Roe Services Corp., Pittsburgh, PA (United States); Gray, D. [Mitre Corp, McLean, VA (United States)] [and others

    1995-12-31

    For the foreseeable future, liquid hydrocarbon fuels will play a significant role in the transportation sector of both the United States and the world. Factors favoring these fuels include convenience, high energy density, and the vast existing infrastructure for their production and use. At present the U.S. consumes about 26% of the world supply of petroleum, but this situation is expected to change because of declining domestic production and increasing competition for imports from countries with developing economies. A scenario and time frame are developed in which declining world resources will generate a shortfall in petroleum supply that can be allieviated in part by utilizing the abundant domestic coal resource base. One option is direct coal conversion to liquid transportation fuels. Continued R&D in coal conversion technology will results in improved technical readiness that can significantly reduce costs so that synfuels can compete economically in a time frame to address the shortfall.

  2. Sequence stratigraphic analysis and the origins of Tertiary brown coal lithotypes, Latrobe Valley, Gippsland Basin, Australia

    Energy Technology Data Exchange (ETDEWEB)

    Holdgate, G R; Kershaw, A P; Sluiter, I R.K. [Monash University, Clayton, Vic. (Australia). Dept. of Earth Sciences

    1995-11-01

    Sequence analysis methods have been applied to the onshore Gippsland Basin and to the Latrobe Valley Group coal measures. In the east of the Latrobe Valley evidence for marine transgressions into the coal measures are recorded in most of the interseam sediment splits by the presence of contained foraminifer and dinoflagellates. To the west these splits pinch out into continuous coal. However, they can be followed westwards as enhanced organic sulphur levels along sharply defined boundaries between light coal lithotypes below and dark coal lithotypes above. The dark lithotype immediately overlying each of these boundaries contains the highest sulphur value and warmer climate pollen assemblages. Colorimeter and lithotype logging supports an upwards lightening cyclicity to coal colour at 12-20 m intervals through the approx. 100 m thick seams, with cycle boundaries defined at sharp planar to undulating surfaces. The lightening upward lithotype cycles together with their unique boundary conditions are interpreted as parasequences and parasequence boundaries respectively. Each major coal seam can comprise up to five parasequences and is interpreted to represent deposition during an outbuilding high stand systems tract at one of several maximum periods of Tertiary coastal onlap. Stratigraphic correlation of the sequence boundaries identified in the coal measures to the internationally dated marine Seaspray Group, provides a basis for chronostratigraphic correlation of the coal successions to the coastal onlap charts of Haq et al (1989). It appears that each major seam is confined to high standards of third order eustatic cycles. It follows that the lithotype cycles that comprise each seam are related to fourth order eustatic cycles. 49 refs., 11 figs., 1 tab.

  3. Nitrogen conversion during rapid pyrolysis of coal and petroleum coke in a high-frequency furnace

    International Nuclear Information System (INIS)

    Yuan, Shuai; Zhou, Zhi-jie; Li, Jun; Wang, Fu-chen

    2012-01-01

    Highlights: ► Use a high-frequency furnace to study N-conversion during rapid pyrolysis of coal. ► Scarcely reported N-conversion during rapid pyrolysis of petroleum coke was studied. ► Both of NH 3 and HCN can be formed directly from coal during rapid pyrolysis. ► NH 3 –N yields are higher than HCN–N yields in most conditions. ► NH 3 –N yields of petroleum coke increase with temperature and no HCN detected. -- Abstract: Rapid pyrolysis of three typical Chinese coals, lignite from Inner Mongolia, bituminous from Shenfu coalfield, and anthracite from Guizhou, as well as a petroleum coke were carried out in a drop-style high-frequency furnace. The reactor was induction coil heated and had a very small high-temperature zone, which could restrain secondary conversions of nitrogen products. The effects of temperature and coal rank on conversions of fuel-N to primary nitrogen products (char-N, HCN–N, NH 3 –N and (tar + N 2 )–N) have been investigated. The results showed that, the increasing temperature reduced the yields of char-N and promoted the conversion of fuel-N to N 2 . Char-N yields increased, while volatile-N yields decreased as the coal rank increased. In most of the conditions, NH 3 –N yields were higher than HCN–N yields during rapid pyrolysis of coal. In the case of petroleum coke, NH 3 –N yields increased gradually with the increasing temperature, but no HCN was detected. We argue that NH 3 –N can be formed directly through the primary pyrolysis without secondary reactions. Although volatile-N yields of lignite were higher than those of bituminous, yields of (HCN + NH 3 )–N in volatile-N of lignite were lower than those of bituminous. While the (HCN + NH 3 )–N yields of anthracite were the lowest of the three coals. Both of the (HCN + NH 3 )–N yields and (HCN + NH 3 )–N proportions in volatile-N of petroleum coke were lower than the three coals.

  4. Chemical and mineralogical characterization of highly and less reactive coal from Northern Natal and Venda-Pafuri coalfields in South Africa

    Science.gov (United States)

    Kataka, M. O.; Matiane, A. R.; Odhiambo, B. D. O.

    2018-01-01

    Spontaneous combustion of coal is a major hazard associated with the coal mining industry over centuries. It also a major cause of underground fires in South African collieries and in opencast operations, spoil heaps and stockpiles. Spontaneous combustion incidents are manifested in all major aspects of coal mining namely, underground mining, surface mining, including during sea-borne transportation, storage and waste disposal. Previous studies indicate that there are various factors (both intrinsic and extrinsic) that influence the spontaneous combustion of coals. This paper characterizes highly reactive coal from the Vryheid coalfields and less reactive coal from at Venda-Pafuri coalfield, to identify and delineate some intrinsic coal parameters that are considered to be most critical in terms of heat 'generation' and relationships between the two coals types by tracing their similarities and differences in their spontaneous combustion parameters. Various tests were carried out to characterize these coals in terms of their intrinsic properties, namely: ultimate, proximate, petrographic analysis and Glasser spontaneous tests. The ultimate and proximate analysis showed that spontaneous coal has high contents of carbon, oxygen, and volatile matter as compared to non-spontaneous coal, making it more susceptible to spontaneous combustion. Non-spontaneous coal has higher ash content than the spontaneous coal. Furthermore, the petrographic analysis showed that spontaneous coal has high total reactivity compared to the non-spontaneous coal. Results from Glasser spontaneous test indicate that spontaneous coal absorbs more oxygen than non-spontaneous coal, which explains why spontaneous coal is more susceptible to spontaneous combustion. High reactive coal has low values of critical self-heating temperature (CSHT), indicating that this coal has potential of spontaneous ignition.

  5. 75 FR 20918 - High-Voltage Continuous Mining Machine Standard for Underground Coal Mines

    Science.gov (United States)

    2010-04-22

    ... DEPARTMENT OF LABOR Mine Safety and Health Administration 30 CFR Parts 18 and 75 RIN 1219-AB34 High-Voltage Continuous Mining Machine Standard for Underground Coal Mines Correction In rule document 2010-7309 beginning on page 17529 in the issue of Tuesday, April 6, 2010, make the following correction...

  6. Advanced gasifier and water gas shift technologies for low cost coal conversion to high hydrogen syngas

    Energy Technology Data Exchange (ETDEWEB)

    Kramer, Andrew Kramer [Gas Technology Inst., Des Plaines, IL (United States)

    2016-09-30

    The Gas Technology Institute (GTI) and team members RTI International (RTI), Coanda Research and Development, and Nexant, are developing and maturing a portfolio of technologies to meet the United States Department of Energy (DOE) goals for lowering the cost of producing high hydrogen syngas from coal for use in carbon capture power and coal-to-liquids/chemicals. This project matured an advanced pilot-scale gasifier, with scalable and commercially traceable components, to readiness for use in a first-of-a-kind commercially-relevant demonstration plant on the scale of 500-1,000 tons per day (TPD). This was accomplished through cold flow simulation of the gasifier quench zone transition region at Coanda and through an extensive hotfire gasifier test program on highly reactive coal and high ash/high ash fusion temperature coals at GTI. RTI matured an advanced water gas shift process and catalyst to readiness for testing at pilot plant scale through catalyst development and testing, and development of a preliminary design basis for a pilot scale reactor demonstrating the catalyst. A techno-economic analysis was performed by Nexant to assess the potential benefits of the gasifier and catalyst technologies in the context of power production and methanol production. This analysis showed an 18%reduction in cost of power and a 19%reduction in cost of methanol relative to DOE reference baseline cases.

  7. Mathematical modeling of a fluidized bed gasifier for steam gasification of coal using high-temperature nuclear reactor heat

    International Nuclear Information System (INIS)

    Kubiak, H.; vanHeek, K.-H.; Juntgen, H.

    1986-01-01

    Coal gasification is a well-known technique and has already been developed and used since a long time. In the last few years, forced by the energy situation, new efforts have been made to improve known processes and to start new developments. Conventional gasification processes use coal not only as feedstock to be gasified but also for supply of energy for reaction heat, steam production, and other purposes. With a nuclear high temperature reactor (HTR) as a source for process heat, it is possible to transform the whole of the feed coal into gas. This concept offers advantages over existing gasification processes: saving of coal, as more gas can be produced from coal; less emission of pollutants, as the HTR is used for the production of steam and electricity instead of a coal-fired boiler; and lower production costs for the gas

  8. Waterberg coal characteristics and SO2 minimum emissions standards in South African power plants.

    Science.gov (United States)

    Makgato, Stanford S; Chirwa, Evans M Nkhalambayausi

    2017-10-01

    Key characteristics of coal samples from the supply stock to the newly commissioned South African National Power Utility's (Eskom's) Medupi Power Station - which receives its supply coal from the Waterberg coalfield in Lephalale (Limpopo Province, South Africa) - were evaluated. Conventional coal characterisation such as proximate and ultimate analysis as well as determination of sulphur forms in coal samples were carried out following the ASTM and ISO standards. Coal was classified as medium sulphur coal when the sulphur content was detected in the range 1.15-1.49 wt.% with pyritic sulphur (≥0.51 wt.%) and organic sulphur (≥0.49 wt.%) accounted for the bulk of the total sulphur in coal. Maceral analyses of coal showed that vitrinite was the dominant maceral (up to 51.8 vol.%), whereas inertinite, liptinite, reactive semifusinite and visible minerals occurred in proportions of 22.6 vol.%, 2.9 vol.%, 5.3 vol.% and 17.5 vol.%, respectively. Theoretical calculations were developed and used to predict the resultant SO 2 emissions from the combustion of the Waterberg coal in a typical power plant. The sulphur content requirements to comply with the minimum emissions standards of 3500 mg/Nm 3 and 500 mg/Nm 3 were found to be ≤1.37 wt.% and ≤0.20 wt.%, respectively. Copyright © 2017 Elsevier Ltd. All rights reserved.

  9. Characterization of a coal tailing deposit for zero waste mine in the Brazilian coal field of Santa Catarina

    International Nuclear Information System (INIS)

    Amaral Filho, J.R.; Schneider, I.A.H.; Tubino, R.M.C.; Brum de, I.A.S.; Miltzarek, G.; Sampaio, C.H.

    2010-01-01

    Coal tailings deposits in Brazil are occupying large areas of land while also generating acid mine drainage (AMD) that includes heavy metals. This paper described an analytical study of a typical coal tailings deposit. The study objective was to separate low density, intermediate density, and high density fractions for future reuse. Particle size analysis, disymmetric studies, X-ray diffraction, and tests conducted to determine ash, total sulphur, and acid bases were conducted in order to characterize the coal tailings samples. Results of the study demonstrated a size distribution of 67 percent coarse, 14 percent fine, and 19 percent ultra-fine particles. The gravimetric concentration method was used to recover 34.2 percent of the total deposit for future energy use. Approximately 9.2 percent of the remaining deposit was a pyrite concentrate. The acid generating potential of the remaining materials was reduced by approximately 60 percent. 9 refs., 1 tab., 2 figs.

  10. Status of steam gasification of coal by using heat from high-temperature reactors (HTRs)

    International Nuclear Information System (INIS)

    Schroeter, H.J.; Kirchhoff, R.; Heek, K.H. van; Juentgen, H.; Peters, W.

    1984-01-01

    Bergbau-Forschung GmbH, Essen, is developing a process for steam gasification of coal by using process heat from high-temperature nuclear reactors (HTRs). The envisaged allothermal gas generator is heated by an internally mounted bundle of heat exchanging tubes through which the gaseous reactor coolant helium flows. Research and development work for this process has been under way for about 11 years. After intensive small-scale investigations the principle of the process was tested in a semi-technical plant with 0.2 t/h coal throughput. In its gasifier a fluidized bed of approximately 1 m 2 cross-section and up to 4 m high is operated at 40 bar. Heat is supplied to the bed from an immersed heat exchanger with helium flowing through it. The gas generator is a cut-out version of the full-scale generator, in which the height of the bed, and the arrangement of the heat-exchanger tubes correspond to the full-scale design. The semi-technical plant has now achieved a total gasification time of about 13,000 hours. Roughly 2000 t of coal have been put through. During recent years the gasification of Federal German coking coal by using a jet-feeding system was demonstrated successfully. The results, confirmed and expanded by material tests for the heat exchanger, engineering and computer models and design studies, have shown the feasibility of nuclear steam gasification of coal. The process described offers the following advantages compared with existing processes: higher efficiency as more gas can be produced from less coal; less emission of pollutants as, instead of a coal-fired boiler, the HTR is used for producing steam and electricity; lower production costs for gas. The next step in the project is a pilot plant of about 2-4 t/h coal throughput, still with non-nuclear heating, to demonstrate the construction and operation of the allothermal gas generator on a representative scale for commercial applications. (author)

  11. Chronic arsenic poisoning from burning high-arsenic-containing coal in Guizhou, China

    Energy Technology Data Exchange (ETDEWEB)

    Liu, J.; Zheng, B.S.; Aposhian, H.V.; Zhou, Y.S.; Chen, M.L.; Zhang, A.H.; Waalkes, M.P. [NIEHS, Research Triangle Park, NC (USA)

    2002-07-01

    Arsenic is an environmental hazard and the reduction of drinking water arsenic levels is under consideration. People are exposed to arsenic not only through drinking water but also through arsenic-contaminated air and food. Here the health effects of arsenic exposure from burning high arsenic-containing coal in Guizhou, China was investigated. Coal is burned inside the home in open pits for daily cooking and crop drying, producing a high concentration of arsenic in indoor air. Arsenic in the air coats and permeates food being dried producing high concentrations in food; however, arsenic concentrations in the drinking water are in the normal range. The estimated sources of total arsenic exposure in this area are from arsenic-contaminated food (50-80%), air (10-20%), water (1-5%), and direct contact in coal-mining workers (1%). At least 3,000 patients with arsenic poisoning were found in the Southwest Prefecture of Guizhou, and approximately 200,000 people are at risk for such over exposures. Skin lesions are common, including keratosis of the hands and feet, pigmentation on the trunk, skin ulceration, and skin cancers. Toxicities to internal organs, including lung dysfunction, neuropathy, and nephrotoxicity, are clinically evident. The prevalence of hepatomegaly was 20%, and cirrhosis, ascites, and liver cancer are the most serious outcomes of arsenic poisoning. The Chinese government and international organizations are attempting to improve the house conditions and the coal source, and thereby protect human health in this area.

  12. High Pressure Oxydesulphurisation of Coal—Effect of Oxidizing Agent, Solvent, Shear and Agitator Configuration

    Directory of Open Access Journals (Sweden)

    Moinuddin Ghauri

    2016-06-01

    Full Text Available The ambient temperature high pressure oxydesulphurisation technique was investigated to reduce the sulphur content. Prince of Wales coal was chosen for this study. The focus of the study was to investigate the reduction of both pyritic and organic sulphur while changing the KMnO4/Coal ratio, agitation speed, agitator configuration, and shear. The effect of different concentrations of acetone as a solvent and effect of particle size on the sulphur removal was also studied by a series of experimental runs at ambient temperature. Heating value recovery was found to be increased with the decreased KMnO4/Coal ratio and with decreased acetone concentration. It was found that sulphur removal was enhanced with the increase in shear using a turbine impeller. The effect of particle size was more significant on the pyritic sulphur removal as compared to the organic sulphur removal while heating value recovery was found to increase with decreased desulphurization tome for both, under atmospheric and high pressure.

  13. Investigation of the possibility of binding fly ash particles by elemental sulphur

    Directory of Open Access Journals (Sweden)

    Vidojković V.

    2006-01-01

    Full Text Available Thermal power plants in Serbia use lignite for electrical power production The secondary product of coal combustion is fly ash in the amount of 17%. Fly ash causes the pollution of air, water and soil, and also cause many human, especially lung diseases. Secondary sulphur is a product of crude oil refining. The aim of this study was to investigate the use of sulphur as a bonding material in ultra fine particle agglomeration (smaller than 63 μm in fly ash. The agglomeration should make the ash particles larger and heavy enough to fall without flying fractions. The experiments showed that during the homogenization of the ashes and sulphur from 150 to 170 °C in a reactor with intensive mixing, an amount of 15% sulphur was sufficient to bond particles and cause agglomeration without visible flying fractions.

  14. The non-participation of organic sulphur in acid mine drainage generation.

    Science.gov (United States)

    Casagrande, D J; Finkelman, R B; Caruccio, F T

    1989-12-01

    Acid mine drainage is commonly associated with land disturbances that encounter and expose iron sulphides to oxidising atmospheric conditions. The attendant acidic conditions solubilise a host of trace metals. Within this flow regime the potential exists to contaminate surface drinking water supplies with a variety of trace materials. Accordingly, in evaluating the applications for mines located in the headwaters of water sheds, the pre-mining prediction of the occurrence of acid mine drainage is of paramount importance.There is general agreement among investigators that coal organic sulphur is a nonparticipant in acid mine drainage generation; however, there is no scientific documentation to support this concensus. Using simulated weathering, kinetic, mass balance, petrographic analysis and a peroxide oxidation procedure, coal organic sulphur is shown to be a nonparticipant in acid mine drainage generation. Calculations for assessing the acid-generating potential of a sedimentary rock should not include organic sulphur content.

  15. Sequence stratigraphy, organic petrology and chemistry applied to the upper and lower coal seams in the Candiota Coalfield, Parana Basin, RS, Brazil

    Energy Technology Data Exchange (ETDEWEB)

    Oliveira, J.S. de; Kalkreuth, W. [Instituto de Geociencias, UFRGS, Porto Alegre (Brazil)

    2010-12-01

    The Permian age coal seams in the Candiota Coalfield represent the largest coal deposit of the country. Currently two seams are mined, called ''Camada Candiota Superior'' and ''Camada Candiota Inferior''. The other coal seams of the coalfield, seams S1-S9 (upper seams) and I1-I5 (lower seams) have as yet not been exploited. The objective of this paper is to perform a detailed sequence stratigraphic, petrologic and chemical study of the upper and lower coal seams, thereby generating data for assisting in the development and better use of the coal-bearing interval. The methodology includes application of the concepts of sequence stratigraphy, which includes the lithological interpretation of the core to establish the depositional environments and genetic correlation between facies associations to define parasequences and bounding surfaces; coal petrology (analysis of the reflectance of vitrinite, determination of the petrographic composition of the coals by maceral analyses), and chemical analyses such as sulphur determination, proximate analyses (ash, moisture, volatile matter, and fixed carbon), and elemental analyses. Three main depositional systems were so far identified: alluvial fan, fluvial system, lagoonal estuary system. This study shows that coal development was controlled by accommodation/accumulation rates, with coal seams with greater thickness and lateral continuity being formed within the transgressive systems tract (lagoonal depositional system) of parasequence 2 (PS2), indicating that the accumulation rates of the peat and distribution of the coal seams were controlled by stratigraphic setting. Vitrinite reflectances for the upper and lower coal seams are indicative of subbituminous rank (Rrandom = 0.36-0.47%), with evidence that anomalously low reflectance values are related to high mineral-matter contents. Maceral composition is highly variable, with some coal seams being extremely rich in inertinite (up to

  16. Gondwana basins and their coal resources in Bangladesh

    International Nuclear Information System (INIS)

    Nehaluddin, M.; Sultan-ul-Islam, M.

    1994-01-01

    Fault bounded five Gondwana basins have been discovered in the north western Bangladesh. Among these basins show considerable amount of coal deposits. The Gondwana rocks are highly formed during the Permo-carboniferous diastrophism and later on acquired dynamic characters. In almost all basins, the Permian rocks overlie the Precambrian basement and underlie either the Tertiary or the Cretaceous sediments, structural, stratigraphic, and depositional history of these basins is more or less similar. The sedimentary sequences are composed of light to dark gray, fine to very coarse grained, sub angular to sub rounded felspathic sandstone, dark grey carbonaceous shale and sandstone, variegated conglomerate and thick coal seams (single seam max. 42.38m). The rocks are often alternated and bear the characteristics of cyclic sedimentation. The depositional environments varied from restricted drainage to open fluvial dominated low to moderate sinuous drainage system. The coal bearing basins were flanked by vegetated and swampy over bank. Age of these coals is suggested to be the late permian. Proved and probable reserves of coal in Jamalganj-Paharpur basin are 670 and 1,460 million metric tons, in Barapukuria basin 303 and 3899 million metric tons; in Barapukuria basin 303 and 389 million metric tons; and in Khalaspir basin 143 and 685 million metric tons respectively. The coal is high volatile, low sulphur, bituminous type. It can be used for different forms of thermal conversion. (author)

  17. Development of economical and high efficient desulfurization process using low rank coal; Teitankadotan wo mochiita ankana kokoritsu datsuryuho no kaihatsu

    Energy Technology Data Exchange (ETDEWEB)

    Takarada, Y; Kato, K; Kuroda, M; Nakagawa, N [Gunma University, Gunma (Japan). Faculty of Engineering; Roman, M [New Energy and Industrial Technology Development Organization, Tokyo, (Japan)

    1997-02-01

    Experiment reveals the characteristics of low rank coal serving as a desulfurizing material in fluidized coal bed reactor with oxygen-containing functional groups exchanged with Ca ions. This effort aims at identifying inexpensive Ca materials and determining the desulfurizing characteristics of Ca-carrying brown coal. A slurry of cement sludge serving as a Ca source and low rank coal is agitated for the exchange of functional groups and Ca ions, and the desulfurizing characteristics of the Ca-carrying brown coal is determined. The Ca-carrying brown coal and high-sulfur coal char is mixed and incinerated in a fluidized bed reactor, and it is found that a desulfurization rate of 75% is achieved when the Ca/S ratio is 1 in the desulfurization of SO2. This rate is far higher than the rate obtained when limestone or cement sludge without preliminary treatment is used as a desulfurizer. Next, Ca-carrying brown coal and H2S are caused to react upon each other in a fixed bed reactor, and then it is found that desulfurization characteristics are not dependent on the diameter of the Ca-carrying brown coal grain, that the coal is different from limestone in that it stays quite active against H2S for long 40 minutes after the start of the reaction, and that CaO small in crystal diameter is dispersed in quantities into the char upon thermal disintegration of Ca-carrying brown coal to cause the coal to say quite active. 5 figs.

  18. Development and Application of High Strength TMCP Plate for Coal Mining Machinery

    Science.gov (United States)

    Yongqing, Zhang; Aimin, Guo; Liandeng, Yao

    Coal, as the most major energy in China, accounted for about 70% of China's primary energy production and consumption. While the percentage of coal as the primary energy mix would drop in the future due to serious smog pollution partly resulted from coal-burning, the market demand of coal will maintain because the progressive process of urbanization. In order to improve productivity and simultaneously decrease safety accidents, fully-mechanized underground mining technology based on complete equipment of powered support, armored face conveyor, shearer, belt conveyor and road-header have obtained quick development in recent years, of which powered support made of high strength steel plate accounts for 65 percent of total equipment investment, so, the integrated mechanical properties, in particular strength level and weldability, have a significant effects on working service life and productivity. Take hydraulic powered supports as example, this paper places priority to introduce the latest development of high strength steel plates of Q550, Q690 and Q890, as well as metallurgical design conception and production cost-benefits analysis between QT plate and TMCP plate. Through production and application practice, TMCP or DQ plate demonstrate great economic advantages compared with traditional QT plate.

  19. High pressure hydropyrolysis of coals by using a continuous free-fall reactor

    Energy Technology Data Exchange (ETDEWEB)

    W.-C. Xu; K. Matsuoka; H. Akiho; M. Kumagai; A. Tomita [Institute of Research and Innovation, Kashiwa (Japan)

    2003-04-01

    Rapid hydropyrolysis of coal was carried out at temperatures ranging from 923 to 1123 K and H{sub 2} pressures up to 7 MPa by using a continuous free-fall pyrolyzer. The effects of the reaction conditions on product yields were investigated. Carbon mass balance was fairly good. It was revealed that a large amount of methane was produced due to the hydrogenolysis of higher hydrocarbons and the hydrogasification of char. The influence of pyrolysis temperature was significant on both reactions while H{sub 2} pressure mainly affected the latter. A considerable amount of reactive carbon was formed during hydropyrolysis of coal. It was converted to methane at high temperatures and high H{sub 2} pressures, while the hydrogasification of reactive carbon takes place relatively slowly at low temperatures and low H{sub 2} pressures, resulting in a low overall carbon conversion. The coal conversions observed in the present study were much higher than those obtained with using reactors where the contact between coal particles and H{sub 2} is insufficient. 25 refs., 6 figs., 6 tabs.

  20. Sulphur removal in IGCC projects

    Energy Technology Data Exchange (ETDEWEB)

    Cross, F. (Parsons (United Kingdom))

    1998-01-01

    The technology for recovering elemental sulphur from H[sub 2]S bearing gases is well established. The modified Claus Process is the principal work-horse in sulphur recovery and can customarily achieve conversion efficiencies of 95% or better. Nowadays, such a level of recovery is no longer sufficient in most instances and sulphur recovery facility must then include some form of enhanced recovery, usually by treating the Claus tail gas. A number of processes have been introduced to enable the overall recovery to be increased. Recoveries in excess of 99% are both feasible and economic. Use of oxygen in place has become very popular in cases where oxygen is available cheaply or where capacity increases are designed. Most IGCC projects needing an air separation plant would automatically benefit from extending the use of oxygen to the sulphur recovery plant. The most popular route to minimising sulphur emissions in the context of IGCC projects has involved an oxygen based Claus plant followed by tail gas hydrogenation, hydrogen sulphide recovery and its recycle to the Claus section. The recovery of H[sub 2]S from the Claus tail gas can be integrated with the main gas treating system in the gasification plant. The cost advantage of doing so is significant. Parsons has been involved with the technology since 1949 and has been responsible for developments such as the ammonia burning Claus and jointly with Unocal, the BSRP tail gas process and Selectox processes. Recent innovations in response changing environmental and production requirements have included catalytic and tail gas processes which reduce sulphur emissions. 6 figs., 2 tabs.

  1. Sulphur removal in IGCC projects

    Energy Technology Data Exchange (ETDEWEB)

    Cross, F. [Parsons (United Kingdom)

    1998-12-31

    The technology for recovering elemental sulphur from H{sub 2}S bearing gases is well established. The modified Claus Process is the principal work-horse in sulphur recovery and can customarily achieve conversion efficiencies of 95% or better. Nowadays, such a level of recovery is no longer sufficient in most instances and sulphur recovery facility must then include some form of enhanced recovery, usually by treating the Claus tail gas. A number of processes have been introduced to enable the overall recovery to be increased. Recoveries in excess of 99% are both feasible and economic. Use of oxygen in place has become very popular in cases where oxygen is available cheaply or where capacity increases are designed. Most IGCC projects needing an air separation plant would automatically benefit from extending the use of oxygen to the sulphur recovery plant. The most popular route to minimising sulphur emissions in the context of IGCC projects has involved an oxygen based Claus plant followed by tail gas hydrogenation, hydrogen sulphide recovery and its recycle to the Claus section. The recovery of H{sub 2}S from the Claus tail gas can be integrated with the main gas treating system in the gasification plant. The cost advantage of doing so is significant. Parsons has been involved with the technology since 1949 and has been responsible for developments such as the ammonia burning Claus and jointly with Unocal, the BSRP tail gas process and Selectox processes. Recent innovations in response changing environmental and production requirements have included catalytic and tail gas processes which reduce sulphur emissions. 6 figs., 2 tabs.

  2. Exploration of coal-based pitch precursors for ultra-high thermal conductivity graphite fibers. Final report

    Energy Technology Data Exchange (ETDEWEB)

    Deshpande, G.V. [Amoco Performance Products, Inc., Alpharetta, GA (United States)

    1996-12-27

    Goal was to explore the utility of coal-based pitch precursors for use in ultra high thermal conductivity carbon (graphite) fibers. From graphite electrode experience, it was established that coal-based pitches tend to form more highly crystalline graphite at lower temperatures. Since the funding was limited to year 1 effort of the 3 year program, the goal was only partially achieved. The coal-base pitches can form large domain mesophase in spite of high N and O contents. The mesophase reactivity test performed on one of the variants of coal-based pitch (DO84) showed that it was not a good candidate for carbon fiber processing. Optimization of WVU`s isotropic pitch process is required to tailor the pitch for carbon fiber processing. The hetero atoms in the coal pitch need to be reduced to improve mesophase formation.

  3. Sulphur fertilization influences the sulphur species composition in Allium sativum: sulphomics using HPLC-ICPMS/MS-ESI-MS/MS.

    Science.gov (United States)

    Raab, Andrea; Ronzan, Marilena; Feldmann, Joerg

    2017-10-18

    Garlic (A. sativum) contains a large number of small sulphur (S)-containing metabolites, which are important for its taste and smell and vary with A. sativum variety and growth conditions. This study was designed to investigate the influence of different sulphur-fertilization regimes on low molecular weight S-species by attempting the first sulphur mass balance in A. sativum roots and bulbs using HPLC-ICPMS/MS-ESI-MS/MS. Species unspecific quantification of acid soluble S-containing metabolites was achieved using HPLC-ICP-MS/MS. For identification of the compounds, high resolution ESI-MS (Orbitrap LTQ and q-TOF) was used. The plants contained up to 54 separated sulphur-containing compounds, which constitute about 80% of the total sulphur present in A. sativum. The roots and bulbs of A. sativum contained the same compounds, but not necessarily the same amounts and proportions. The S-containing metabolites in the roots reacted more sensitively to manipulations of sulphur fertilization than those compounds in the bulbs. In addition to known compounds (e.g. γ-glutamyl-S-1-propenylcysteine) we were able to identify and partially quantify 31 compounds. Three as yet undescribed S-containing compounds were also identified and quantified for the first time. Putative structures were assigned to the oxidised forms of S-1-propenylmercaptoglutathione, S-2-propenylmercaptoglutathione, S-allyl/propenyl-containing PC-2 and 2-amino-3-[(2-carboxypropyl)sulfanyl]propanoic acid. The parallel use of ICP-MS/MS as a sulphur-specific detector and ESI-MS as a molecular detector simplifies the identification and quantification of sulphur containing metabolites without species specific standards. This non-target analysis approach enables a mass balance approach and identifies the occurrence of the so far unidentified organosulphur compounds. The experiments showed that the sulphur-fertilization regime does not influence sulphur-speciation, but the concentration of some S

  4. Discontinuities in Jovian sulphur plasma

    Energy Technology Data Exchange (ETDEWEB)

    Mekler, Y [Jet Propulsion Lab., Pasadena, CA (USA); Eviatar, A; Siscoe, G L

    1979-10-01

    In recent years, the Jovian sulphur nebula, which is the only component of the thermal plasma in the magnetosphere of Jupiter which emits in the visible, has been the subject of considerable study. A large number of investigators have come up with widely differing models for the density, composition and temperature of the Jovian magnetospheric plasma. In this paper a different characteristic of the sulphur emission, namely its radial distribution is discussed and an attempt is made to assess its implications for the plasma and magnetic field configuration of the inner magnetosphere of Jupiter.

  5. Muon transfer to sulphur dioxide

    International Nuclear Information System (INIS)

    Mulhauser, F.; Schneuwly, H.

    1993-01-01

    A systematic study of muon capture and muon transfer has been performed in seven different H 2 + SO 2 gas mixtures. From the single-exponential time structure of the muonic sulphur x-rays, one determines the lifetime of the μp atoms under the given experimental conditions. The reduced muon transfer rates to the sulphur dioxide molecule, deduced from these lifetimes, all agree well with each other. The muonic oxygen time spectra show an additional structure as if μp atoms of another kind were present. Comparable time structures are observed in a D 2 + SO 2 mixture. (author)

  6. Lab-scale investigation of Middle-Bosnia coals to achieve high-efficient and clean combustion technology

    Directory of Open Access Journals (Sweden)

    Smajevic Izet

    2014-01-01

    Full Text Available This paper describes full lab-scale investigation of Middle-Bosnia coals launched to support selection an appropriate combustion technology and to support optimization of the boiler design. Tested mix of Middle-Bosnia brown coals is projected coal for new co-generation power plant Kakanj Unit 8 (300-450 MWe, EP B&H electricity utility. The basic coal blend consisting of the coals Kakanj: Breza: Zenica at approximate mass ratio of 70:20:10 is low grade brown coal with very high percentage of ash - over 40%. Testing that coal in circulated fluidized bed combustion technique, performed at Ruhr-University Bohum and Doosan Lentjes GmbH, has shown its inconveniency for fluidized bed combustion technology, primarily due to the agglomeration problems. Tests of these coals in PFC (pulverized fuel combustion technology have been performed in referent laboratory at Faculty of Mechanical Engineering of Sarajevo University, on a lab-scale PFC furnace, to provide reliable data for further analysis. The PFC tests results are fitted well with previously obtained results of the burning similar Bosnian coal blends in the PFC dry bottom furnace technique. Combination of the coals shares, the process temperature and the air combustion distribution for the lowest NOx and SO2 emissions was found in this work, provided that combustion efficiency and CO emissions are within very strict criteria, considering specific settlement of lab-scale furnace. Sustainability assessment based on calculation economic and environmental indicators, in combination with Low Cost Planning method, is used for optimization the power plant design. The results of the full lab-scale investigation will help in selection optimal Boiler design, to achieve sustainable energy system with high-efficient and clean combustion technology applied for given coals.

  7. A X-ray diffraction analysis on graphene layers of Assam coal

    Energy Technology Data Exchange (ETDEWEB)

    Saikia, B.K.; Boruah, R.K.; Gogoi, P.K. [CSIR, Jorhat (India)

    2009-01-15

    The so-called turbostatic structure of carbons in coal with randomly oriented stacking of the lamellae (graphene) produces intense peaks, which are the dominant features in its X-ray diffraction profiles. The diffractogram may be conveniently divided into two regions of reciprocal space, the medium S region (1 < S < 3 {angstrom}) and a high S region (S > 3 {angstrom}) where S = 4 {pi} {lambda} {sup -1}sin{theta}. To better understand the molecular level structure of high sulphur Assam coal, two coal samples (Tirap-1 and Tirap-2) from Tirap colliery of Makum coalfield, Assam (India) has been interpreted in this study by using the X-ray diffraction profiles. Random layered (graphene) structural parameters of these coals were determined by using X-ray diffraction technique, which showed that the L{sub a} and L{sub c} are 64.99 angstrom and 22.63 angstrom for Tirap-2 and 55.54 angstrom and 23.80 angstrom for that of Tirap-1 coals respectively. The position of {gamma} band was found to be at 4.34 {angstrom} and 4.13 angstrom for Tirap-2 and Tirap-1 coals respectively. The number of layers and average number of carbon atoms (N) per aromatic graphene were found to be 21 and 8 for both the coal samples. Proximate, ultimate and ash analysis of the two coal samples were also carried out in this investigation.

  8. Sulphur cement pre-composition and process for preparing such sulphur cement pre-composition

    NARCIS (Netherlands)

    2013-01-01

    The invention provides a process for the preparation of a sulphur cement pre-composition comprising reacting sulphur modifier with polysulphide-containing organosilane to obtain in the presence of sulphur the sulphur cement pre-composition, wherein the organosilane has the general molecular formula:

  9. Coal background paper. Coal demand

    International Nuclear Information System (INIS)

    1997-01-01

    Statistical data are presented on coal demands in IEA and OECD member countries and in other countries. Coal coaking and coaking coal consumption data are tabulated, and IEA secretariat's coal demand projections are summarized. Coal supply and production data by countries are given. Finally, coal trade data are presented, broken down for hard coal, steam coal, coking coal (imports and export). (R.P.)

  10. Making the most of South Africa’s low-quality coal: Converting high-ash coal to fuel gas using bubbling fluidised bed gasifiers

    CSIR Research Space (South Africa)

    Engelbrecht, AD

    2010-08-31

    Full Text Available for process heating or for power generation using the IGCC (Integrated Gasification Combined Cycle) process. A high-ash coal from the Waterberg coalfield was tested in a bubbling fluidised bed gasifier using various gasification agents and operating conditions...

  11. SOME CHARACTERISTICS OF THE "KONGORA" - TOMISLAVGRAD COAL FIELD (WEST HERZEGOVINA

    Directory of Open Access Journals (Sweden)

    Stanislav Živković

    1997-12-01

    Full Text Available According to it's energy potential »Kongora« coal field is very important source of energy. Coal strech, spreading and laying and proportion between coal and barren give good presumption for a rentabile surface exploitation. The coal analyses, specially analysis of sulphur content showed, that content of harm component on the update technology level is in permissible limits, and exploitation in thermal power plants will not destroy environment (the paper is published in Croatian.

  12. ANN-GA based optimization of a high ash coal-fired supercritical power plant

    International Nuclear Information System (INIS)

    Suresh, M.V.J.J.; Reddy, K.S.; Kolar, Ajit Kumar

    2011-01-01

    Highlights: → Neuro-genetic power plant optimization is found to be an efficient methodology. → Advantage of neuro-genetic algorithm is the possibility of on-line optimization. → Exergy loss in combustor indicates the effect of coal composition on efficiency. -- Abstract: The efficiency of coal-fired power plant depends on various operating parameters such as main steam/reheat steam pressures and temperatures, turbine extraction pressures, and excess air ratio for a given fuel. However, simultaneous optimization of all these operating parameters to achieve the maximum plant efficiency is a challenging task. This study deals with the coupled ANN and GA based (neuro-genetic) optimization of a high ash coal-fired supercritical power plant in Indian climatic condition to determine the maximum possible plant efficiency. The power plant simulation data obtained from a flow-sheet program, 'Cycle-Tempo' is used to train the artificial neural network (ANN) to predict the energy input through fuel (coal). The optimum set of various operating parameters that result in the minimum energy input to the power plant is then determined by coupling the trained ANN model as a fitness function with the genetic algorithm (GA). A unit size of 800 MWe currently under development in India is considered to carry out the thermodynamic analysis based on energy and exergy. Apart from optimizing the design parameters, the developed model can also be used for on-line optimization when quick response is required. Furthermore, the effect of various coals on the thermodynamic performance of the optimized power plant is also determined.

  13. Coal option. [Shell Co

    Energy Technology Data Exchange (ETDEWEB)

    1978-01-01

    This paper notes the necessity of developing an international coal trade on a very large scale. The role of Shell in the coal industry is examined; the regions in which Shell companies are most active are Australia, Southern Africa, Indonesia; Europe and North America. Research is being carried out on marketing and transportation, especially via slurry pipelines; coal-oil emulsions; briquets; fluidized-bed combustion; recovery of coal from potential waste material; upgrading of low-rank coals; unconventional forms of mining; coal conversion (the Shell/Koppers high-pressure coal gasification process). Techniques for cleaning flue gas (the Shell Flue Gas Desulfurization process) are being examined.

  14. Reprint of “Experiences in sulphur capture in a 30 MWth Circulating Fluidized Bed boiler under oxy-combustion conditions”

    International Nuclear Information System (INIS)

    Gómez, M.; Fernández, A.; Llavona, I.; Kuivalainen, R.

    2015-01-01

    CO 2 and SO 2 from fossil fuel combustion are contributors to greenhouse effect and acid rain respectively. Oxy-combustion technology produces a highly concentrated CO 2 stream almost ready for capture. Circulating Fluidized Bed (CFB) boiler technology allows in-situ injection of calcium-based sorbents for efficient SO 2 capture. CIUDEN's 30 MWth CFB boiler, supplied by Foster Wheeler and located at the Technology Development Centre for CO 2 Capture and Transport (es.CO 2 ) in Spain, is the first of its kind for executing test runs at large pilot scale under both air-combustion and oxy-combustion conditions. In this work, SO 2 emissions under different scenarios have been evaluated. Variables such as limestone composition, Ca/S molar ratio and bed temperature among others have been considered along different test runs in both air-combustion and oxy-combustion conditions to analyse its influence on SO 2 abatement. Fly and bottom ash, together with flue gas analysis have been carried-out. Desulphurization performance tests results are presented. - Highlights: • Sulphur capture efficiency (%) was higher in oxy-combustion compared to air-combustion in a 30 MW thermal CFB boiler using anthracite and limestone as sulphur sorbent. • For a Ca/S molar ratio higher than 2.6 there was barely any improvement on sulphur capture efficiency for both air-combustion and oxy-combustion conditions in a 30 MW thermal CFB boiler using anthracite and limestone as sulphur sorbent. • Optimum temperature for sulphur capture at a fixed Ca/S molar ratio is around 880–890 °C under oxy-combustion conditions and for anthracite coal with limestone as sorbent in a 30 MW thermal CFB boiler

  15. Use of a Nuclear High Temperature Gas Reactor in a Coal-To-Liquids Process

    International Nuclear Information System (INIS)

    Robert S. Cherry; Richard A. Wood

    2006-01-01

    AREVA's High Temperature Gas Reactor (HTGR) can potentially provide nuclear-generated, high-level heat to chemical process applications. The use of nuclear heat to help convert coal to liquid fuels is particularly attractive because of concerns about the future availability of petroleum for vehicle fuels. This report was commissioned to review the technical and economic aspects of how well this integration might actually work. The objective was to review coal liquefaction processes and propose one or more ways that nuclear process heat could be used to improve the overall process economics and performance. Shell's SCGP process was selected as the gasifier for the base case system. It operates in the range of 1250 to 1600 C to minimize the formation of tars, oil, and methane, while also maximizing the conversion of the coal's carbon to gas. Synthesis gas from this system is cooled, cleaned, reacted to produce the proper ratio of hydrogen to carbon monoxide and fed to a Fischer-Tropsch (FT) reaction and product upgrading system. The design coal-feed rate of 18,800 ton/day produces 26.000 barrels/day of FT products. Thermal energy at approximately 850 C from a HTGR does not directly integrate into this gasification process efficiently. However, it can be used to electrolyze water to make hydrogen and oxygen, both of which can be beneficially used in the gasification/FT process. These additions then allow carbon-containing streams of carbon dioxide and FT tail-gas to be recycled in the gasifier, greatly improving the overall carbon recovery and thereby producing more FT fuel for the same coal input. The final process configuration, scaled to make the same amount of product as the base case, requires only 5,800 ton/day of coal feed. Because it has a carbon utilization of 96.9%, the process produces almost no carbon dioxide byproduct Because the nuclear-assisted process requires six AREVA reactors to supply the heat, the capital cost is high. The conventional plant is

  16. Effect of sulphur forms on colour and residue of sulphur during the storage at drying grapes by sulphur

    Directory of Open Access Journals (Sweden)

    Boztepe Özlem

    2016-01-01

    Full Text Available Turkey is the world leader in the manufacture and export of seedless raisins. Requirement of golden bleached raisins is increasing in food Industry of especially cake, bread and pastry year by year. In this research, the lowest residual value and the practical realization of such production was intended to determine by drying grapes with application of sulphur. In this case, sulphur residue and colour situations were determined during 12-mounth-storage according to sulphur forms. In this study sulphur studies were applied by Vitis Vinifera cv. “Sultani Çekirdeksiz” with Na2S2O5, which is liquid source of sulphur and SO2, which is gas source of sulphur. SO2 application were studied during 3, 6 and 8 hours and liquid form of sulphur is Na2S2O5 that was used during by 10, 20 and 30 minutes. Applications were prepared with 3 replicates which contain 20 kg fresh grape in each replicate. In conclusion, changes in dried grape have been identified in point of colour (chroma and hue and the sulphur content was determined according to sulphur forms in packing. Gas form of sulphur (SO2 which was applied 3 hours, gave the best result during 12-mounth-storage for colour and sulphur residue.

  17. A kinetic study of gaseous potassium capture by coal minerals in a high temperature fixed-bed reactor

    DEFF Research Database (Denmark)

    Zheng, Yuanjing; Jensen, Peter Arendt; Jensen, Anker Degn

    2008-01-01

    The reactions between gaseous potassium chloride and coal minerals were investigated in a lab-scale high temperature fixed-bed reactor using single sorbent pellets. The applied coal minerals included kaolin, mullite, silica, alumina, bituminous coal ash, and lignite coal ash that were formed...... into long cylindrical pellets. Kaolin and bituminous coal ash that both have significant amounts of Si and Al show superior potassium capture characteristics. Experimental results show that capture of potassium by kaolin is independent of the gas oxygen content. Kaolin releases water and forms metakaolin...... when heated at temperatures above 450°C. The amounts of potassium captured by metakaolin pellet decreases with increasing reaction temperature in the range of 900-1300°C and increases again with further increasing the temperature up to 1500°C. There is no reaction of pre-made mullite with KCl...

  18. High resolution seismic survey (of the) Rawlins, Wyoming underground coal gasification area. Final report

    Energy Technology Data Exchange (ETDEWEB)

    Youngberg, A.D.; Berkman, E.; Orange, A.S.

    1983-01-01

    In October 1982, a high resolution seismic survey was conducted at the Gulf Research and Development Company's underground coal gasification test site near Rawlins, Wyoming. The objectives of the survey were to utilize high resolution seismic technology to locate and characterize two underground coal burn zones. Seismic data acquisition and processing parameters were specifically designed to emphasize reflections at the shallow depths of interest. A three-dimensional grid of data was obtained over the Rawlins burn zones. Processing included time varying filters, trace composition, and two-dimensional areal stacking of the data in order to identify burn zone anomalies. An anomaly was discernable resulting from the rubble-collapse cavity associated with the burn zone which was studied in detail at the Rawlins 1 and 2 test sites. 21 refs., 20 figs.

  19. Critical evaluation of high-temperature gas-cooled reactors applicable to coal conversion

    International Nuclear Information System (INIS)

    Spiewak, I.; Jones, J.E. Jr.; Rittenhouse, P.L.; DeStefano, J.R.; Delene, J.G.

    1975-12-01

    A critical review is presented of the technology and costs of very high-temperature gas-cooled reactors (VHTRs) applicable to nuclear coal conversion. Coal conversion processes suitable for coupling to reactors are described. Vendor concepts of the VHTR are summarized. The materials requirements as a function of process temperature in the range 1400 to 2000 0 F are analyzed. Components, environmental and safety factors, economics and nuclear fuel cycles are reviewed. It is concluded that process heat supply in the range 1400 to 1500 0 F could be developed with a high degree of assurance. Process heat at 1600 0 F would require considerably more materials development. While temperatures up to 2000 0 F appear to be attainable, considerably more research and risk were involved. A demonstration plant would be required as a step in the commercialization of the VHTR

  20. Geochemistry of Toxic Elements and Their Removal via the Preparation of High-Uranium Coal in Southwestern China

    Directory of Open Access Journals (Sweden)

    Piaopiao Duan

    2018-02-01

    Full Text Available High-uranium (U coal is the dominant form of coal in Southwestern China. However, directly utilizing this resource can also harm the environment because this element is radioactive; it is, therefore, necessary to clean this kind of coal before burning. This research studied the geochemistry of toxic elements and their partitioning during the preparation of high-U coal in China. The results show that high-U coals are mainly distributed in Southwestern China and are characterized by a high organic sulfur (S content and vanadium (V-chromium (Cr-molybdenum (Mo-U element assemblage. These elements are well-correlated with one another, but are all negatively related to ash yield, indicating that all four are syngenetic in origin and associated with organic materials. A mineralogical analysis shows that U in Ganhe and Rongyang coal occurs within fine-grained anatase, clay minerals, guadarramite, and pyrite, while V occurs in clay minerals, pyrite, and dolomite, and Cr occurs in dolomite. Other elements, such as fluorine (F, lead (Pb, selenium (Se, and mercury (Hg, mainly occur in pyrite. By applying a gravity separation method to separate minerals from coal, the content of the enrichment element assemblage of V-Cr-Mo-U in Rongyang coal is still shown to be higher than, or close to, that of the original feed because this element assemblage is derived from hydrothermal fluids during syngenetic or early diagenetic phases, but other elements (beryllium [Be], F, manganese [Mn], zinc [Zn], Pb, arsenic [As], Se, Hg can be efficiently removed. Once cleaned, the coal obtained by gravity separation was subject to a flotation test to separate minerals; these results indicate that while a portion of V and Cr can be removed, Mo and U remain difficult to extract. It is evident that the two most commonly utilized industrialized coal preparation methods, gravity separation and flotation, cannot effectively remove U from coal where this element occurs in large

  1. 13C-NMR Study on Structure Evolution Characteristics of High-Organic-Sulfur Coals from Typical Chinese Areas

    Directory of Open Access Journals (Sweden)

    Qiang Wei

    2018-02-01

    Full Text Available The structure evolution characteristics of high-organic-sulfur (HOS coals with a wide range of ranks from typical Chinese areas were investigated using 13C-CP/MAS NMR. The results indicate that the structure parameters that are relevant to coal rank include CH3 carbon (fal*, quaternary carbon, CH/CH2 carbon + quaternary carbon (falH, aliphatic carbon (falC, protonated aromatic carbon (faH, protonated aromatic carbon + aromatic bridgehead carbon (faH+B, aromaticity (faCP, and aromatic carbon (farC. The coal structure changed dramatically in the first two coalification jumps, especially the first one. A large number of aromatic structures condensed, and aliphatic structures rapidly developed at the initial stage of bituminous coal accompanied by remarkable decarboxylation. Compared to ordinary coals, the structure evolution characteristics of HOS coals manifest in three ways: First, the aromatic CH3 carbon, alkylated aromatic carbon (faS, aromatic bridgehead carbon (faB, and phenolic ether (faP are barely relevant to rank, and abundant organic sulfur has an impact on the normal evolution process of coal. Second, the average aromatic cluster sizes of some super-high-organic-sulfur (SHOS coals are not large, and the extensive development of cross bonds and/or bridged bonds form closer connections among the aromatic fringes. Moreover, sulfur-containing functional groups are probably significant components in these linkages. Third, a considerable portion of “oxygen-containing functional groups” in SHOS coals determined by 13C-NMR are actually sulfur-containing groups, which results in the anomaly that the oxygen-containing structures increase with coal rank.

  2. Coal-fired high performance power generating system. Quarterly progress report

    Energy Technology Data Exchange (ETDEWEB)

    1992-07-01

    The goals of the program are to develop a coal-fired high performance power generation system (HIPPS) by the year 2000 that is capable of > 47% thermal efficiency; NO{sub x} SO {sub x} and Particulates < 25% NSPS; Cost of electricity 10% lower; coal > 65% of heat input and all solid wastes benign. In order to achieve these goals our team has outlined a research plan based on an optimized analysis of a 250 MW{sub e} combined cycle system applicable to both frame type and aeroderivative gas turbines. Under the constraints of the cycle analysis we have designed a high temperature advanced furnace (HITAF) which integrates several combustor and air heater designs with appropriate ash management procedures. Most of this report discusses the details of work on these components, and the R&D Plan for future work. The discussion of the combustor designs illustrates how detailed modeling can be an effective tool to estimate NO{sub x} production, minimum burnout lengths, combustion temperatures and even particulate impact on the combustor walls. When our model is applied to the long flame concept it indicates that fuel bound nitrogen will limit the range of coals that can use this approach. For high nitrogen coals a rapid mixing, rich-lean, deep staging combustor will be necessary. The air heater design has evolved into two segments: a convective heat exchanger downstream of the combustion process; a radiant panel heat exchanger, located in the combustor walls; The relative amount of heat transferred either radiatively or convectively will depend on the combustor type and the ash properties.

  3. Removing sulphur oxides from a fluid stream

    Science.gov (United States)

    Katz, Torsten; Riemann, Christian; Bartling, Karsten; Rigby, Sean Taylor; Coleman, Luke James Ivor; Lail, Marty Alan

    2014-04-08

    A process for removing sulphur oxides from a fluid stream, such as flue gas, comprising: providing a non-aqueous absorption liquid containing at least one hydrophobic amine, the liquid being incompletely miscible with water; treating the fluid stream in an absorption zone with the non-aqueous absorption liquid to transfer at least part of the sulphur oxides into the non-aqueous absorption liquid and to form a sulphur oxide-hydrophobic amine-complex; causing the non-aqueous absorption liquid to be in liquid-liquid contact with an aqueous liquid whereby at least part of the sulphur oxide-hydrophobic amine-complex is hydrolyzed to release the hydrophobic amine and sulphurous hydrolysis products, and at least part of the sulphurous hydrolysis products is transferred into the aqueous liquid; separating the aqueous liquid from the non-aqueous absorption liquid. The process mitigates absorbent degradation problems caused by sulphur dioxide and oxygen in flue gas.

  4. Processing low-grade coal to produce high-grade products

    CSIR Research Space (South Africa)

    de Korte, GJ

    2015-07-01

    Full Text Available of the coal being mined in the central basin is gradually becoming poorer. This necessitates that more of the coal be processed to improve the quality to meet customer requirements. The challenge to the coal processing industry is to process low-yielding coals...

  5. Sulphate sulphur concentration in vegetable crops, soil and ground water in the region affected by the sulphur dioxide emission from Plock oil refinery (central Poland)

    International Nuclear Information System (INIS)

    Mikula, W.

    1995-01-01

    Research was carried out in 1984-1990 in the region affected by the sulphur dioxide emission from one of the greatest oil refineries in Europe (Plock, central Poland). The sulphate sulphur concentration in the vegetable crops (red beet, carrot, parsley, bean, cabbage and dill), the soil and in ground water was defined in selected allotment gardens of Plock city and in a household garden located in the rural area about 25 km from the town. The highest amount of sulphur was found in the vegetable crops cultivated in the garden situated in the closest vicinity of the refinery. Sulphate sulphur contents harmful for plants (above 0.50 per cent d.m.) were noted in cabbage and carrot leaves in almost all the gardens (except one). The soil in all examined gardens was characterised by high sulphate sulphur concentration, which considerably exceeds the maximum amount admissible for light soil in Poland, i.e. 0.004 per cent d.m. The sulphate sulphur concentration in ground water in all the gardens exceeded the highest permissible content in drinking water in Poland. The sulphate sulphur content in the soil and ground water was not significantly dependent on the garden's distance from the refinery. Generally, the above normal sulphate sulphur concentrations occurred quite universally in the examined region and they concerned all the considered environmental components (vegetable crops, soil, ground water) and all the gardens. 22 refs., 6 tabs

  6. Effect of ash components on the ignition and burnout of high ash coals

    Energy Technology Data Exchange (ETDEWEB)

    Feng, B.; Yan, R.; Zheng, C.G. [Huazhong University of Science and Technology, Wuhan (China). National Laboratory of Coal Combustion

    1998-11-01

    The effect of the ash components on the ignition and burnout of four Chinese high ash coals were studied by thermogravimetric analysis. To investigate the influence of the ash components, comparative experiments were carried out with original, deashed and impregnated coals. Eleven types of ash components, such as SiO{sub 2}, CaCO{sub 3}, MgO, Na{sub 2}CO{sub 3}, K{sub 2}CO{sub 3}, Al{sub 2}O{sub 3}, TiO{sub 2}, Fe{sub 2}O{sub 3}, FeS{sub 2}, NH{sub 4}Fe(SO{sub 4}){sub 2}{center_dot}12H{sub 2}O and FeSO{sub 4},(NH{sub 4}){center_dot}6H{sub 2}O were used in the present study. It was found that most of the ash components have negative effects. The strong influence of some ash components suggests that the combustion characteristics of high ash coal may be determined by the ash composition. 5 refs., 2 figs., 2 tabs.

  7. Sulphur Extraction at Bryan Mound

    Energy Technology Data Exchange (ETDEWEB)

    Kirby, Carolyn L [Sandia National Lab. (SNL-NM), Albuquerque, NM (United States); Lord, Anna C. Snider [Sandia National Lab. (SNL-NM), Albuquerque, NM (United States)

    2015-08-01

    The Bryan Mound caprock was subjected to extens ive sulphur mining prior to the development of the Strategic Petroleum Reserve. Undoubtedl y, the mining has modified the caprock integrity. Cavern wells at Bryan Mound have been subject to a host of well integr ity concerns with many likely compromised by the cavernous capro ck, surrounding corrosive environment (H 2 SO 4 ), and associated elevated residual temperatures al l of which are a product of the mining activities. The intent of this study was to understand the sulphur mining process and how the mining has affected the stability of the caprock and how the compromised caprock has influenced the integrity of the cavern wells. After an extensiv e search to collect pert inent information through state agencies, literature sear ches, and the Sandia SPR librar y, a better understanding of the caprock can be inferred from the knowledge gaine d. Specifically, the discovery of the original ore reserve map goes a long way towards modeling caprock stability. In addition the gained knowledge of sulphur mining - subs idence, superheated corrosive wa ters, and caprock collapse - helps to better predict the post mi ning effects on wellbore integrity. This page intentionally left blank

  8. A LOW COST AND HIGH QUALITY SOLID FUEL FROM BIOMASS AND COAL FINES

    Energy Technology Data Exchange (ETDEWEB)

    John T. Kelly; George Miller; Mehdi Namazian

    2001-07-01

    Use of biomass wastes as fuels in existing boilers would reduce greenhouse gas emissions, SO2 and NOx emissions, while beneficially utilizing wastes. However, the use of biomass has been limited by its low energy content and density, high moisture content, inconsistent configuration and decay characteristics. If biomass is upgraded by conventional methods, the cost of the fuel becomes prohibitive. Altex has identified a process, called the Altex Fuel Pellet (AFP) process, that utilizes a mixture of biomass wastes, including municipal biosolids, and some coal fines, to produce a strong, high energy content, good burning and weather resistant fuel pellet, that is lower in cost than coal. This cost benefit is primarily derived from fees that are collected for accepting municipal biosolids. Besides low cost, the process is also flexible and can incorporate several biomass materials of interest The work reported on herein showed the technical and economic feasibility of the AFP process. Low-cost sawdust wood waste and light fractions of municipal wastes were selected as key biomass wastes to be combined with biosolids and coal fines to produce AFP pellets. The process combines steps of dewatering, pellet extrusion, drying and weatherizing. Prior to pilot-scale tests, bench-scale test equipment was used to produce limited quantities of pellets for characterization. These tests showed which pellet formulations had a high potential. Pilot-scale tests then showed that extremely robust pellets could be produced that have high energy content, good density and adequate weatherability. It was concluded that these pellets could be handled, stored and transported using equipment similar to that used for coal. Tests showed that AFP pellets have a high combustion rate when burned in a stoker type systems. While NOx emissions under stoker type firing conditions was high, a simple air staging approach reduced emissions to below that for coal. In pulverized-fuel-fired tests it was

  9. Tunable Diode Laser Sensors to Monitor Temperature and Gas Composition in High-Temperature Coal Gasifiers

    Energy Technology Data Exchange (ETDEWEB)

    Hanson, Ronald [Stanford Univ., CA (United States); Whitty, Kevin [Univ. of Utah, Salt Lake City, UT (United States)

    2014-12-01

    The integrated gasification combined cycle (IGCC) when combined with carbon capture and storage can be one of the cleanest methods of extracting energy from coal. Control of coal and biomass gasification processes to accommodate the changing character of input-fuel streams is required for practical implementation of integrated gasification combined-cycle (IGCC) technologies. Therefore a fast time-response sensor is needed for real-time monitoring of the composition and ideally the heating value of the synthesis gas (here called syngas) as it exits the gasifier. The goal of this project was the design, construction, and demonstration an in situ laserabsorption sensor to monitor multiple species in the syngas output from practical-scale coal gasifiers. This project investigated the hypothesis of using laser absorption sensing in particulateladen syngas. Absorption transitions were selected with design rules to optimize signal strength while minimizing interference from other species. Successful in situ measurements in the dusty, high-pressure syngas flow were enabled by Stanford’s normalized and scanned wavelength modulation strategy. A prototype sensor for CO, CH4, CO2, and H2O was refined with experiments conducted in the laboratory at Stanford University, a pilot-scale at the University of Utah, and an engineering-scale gasifier at DoE’s National Center for Carbon Capture with the demonstration of a prototype sensor with technical readiness level 6 in the 2014 measurement campaign.

  10. Potential to cofire high-sulfur coal and MSW/RDF in Illinois utility boilers: A survey and analysis

    International Nuclear Information System (INIS)

    South, D.W.

    1993-01-01

    The disposal of refuse is of ever-increasing concern for municipalities and other organizations and agencies throughout the United States. Disposal in landfills is becoming more costly, and new landfills are more difficult to site because of stricter environmental regulations. Mass burning incinerators for municipal solid wastes (MSW) have also met with increased public resistance due to excessive emissions. Nevertheless, increased awareness of the need for alternative disposal techniques has led to a new interest in cofiring MSW with coal. In addition to solid waste concerns, the requirements to reduce SO 2 and NO x emissions from coal-fired utility boilers in the Clean Air Act Amendments of 1990, present an opportunity to cofire MSW/RDF with coal as an emission control measure. These issues were the impetus for a 1992 study (conducted by ANL for the Illinois Clean Coal Institute) to examine the potential to cofire coal with MSW/RDF in Illinois utility boilers. This paper will provide a synopsis of the ANL/ICCI report. It will summarize (1) the combustibility and emission characteristics of high-sulfur coal and MSW/RDF; (2) the facilities firing RDF and/or producing/selling RDF, together with their combustion and emissions experience; (3) the applicable emissions regulations in Illinois; and (4) the analysis of candidate utility boilers in Illinois capable of cofiring, together with the effect on coal consumption and SO 2 and NO x emissions that would result from 20% cofiring with RDF/MSW

  11. Identification of high molecular weight nitroaromatic compounds from coal fly ash

    International Nuclear Information System (INIS)

    Harris, W.R.; Okamoto, D.J.; Chess, E.K.; Wilson, B.W.

    1983-01-01

    A large sample of stack-collected coal fly ash was extracted with 60:40 nu/nu benzene:methanol to remove as much of the soluble organic material as possible. This solution was concentrated by gentle evaporation, and was then fractionated on a series of high performance liquid chromatography columns to generate samples suitable for probe mass spectrometric analysis. A series of nitrated derivatives of C 21 H 12 polycyclic aromatic hydrocarbon have been tentatively identified by low and high resolution mass spectrometry and gas chromatography. The series includes a mononitro, two dinitro isomers, and a trinitro derivative

  12. Distribution and occurrence of lithium in high-alumina-coal fly ash

    DEFF Research Database (Denmark)

    Hu, Pengpeng; Hou, Xinjuan; Zhang, Jianbo

    2018-01-01

    the generalized gradient approximation (GGA) method indicated that Li occurred in Q3(0Al) and Q3(1Al) structures by reacting with Q4(0Al) and Q4(1Al). Based on the experimental and simulation results, we propose extracting Li during the pre-desilication process by dissolving the glass phase.......High-alumina-coal fly ash (HAFA) with a high Li content is regarded as a potential resource for Li production. To support the development of Li recovery technology from HAFA, the distribution and modes of occurrence of Li in HAFA were investigated. HAFA was separated into magnetic particles, glass...

  13. Combustion and environmental performance of clean coal end products

    Energy Technology Data Exchange (ETDEWEB)

    Skodras, G.; Sakellaropoulos, G. [Centre for Research and Technology, Hellas, Ptolemaidas-Kozanis, Ptolemaida (Greece). Inst. for Solid Fuel Technolgy and Applications]|[Aristotle Univ. of Thessaloniki, Thessaloniki (Greece). Dept. of Chemical Engineering, Chemical Process Engineering Lab]|[Chemical Process Engineering Research Inst., Thessaloniki (Greece). Lab. of Solid Fuels and Environment; Someus, E. [Thermal Desorption Technology Group (Greece); Grammelis, P.; Amarantos, P.S. [Centre for Research and Technology, Hellas, Ptolemaidas-Kozanis, Ptolemaida (Greece). Inst. for Solid Fuel Technolgy and Applications; Palladas, A.; Basinas, P.; Natas, P.; Prokopidou, M.; Diamantopoulou, I.; Sakellaropoulos, G. [Aristotle Univ. of Thessaloniki, Thessaloniki (Greece). Dept. of Chemical Engineering, Chemical Process Engineering Lab

    2006-07-01

    Clean and affordable power production is needed in order to achieve sustainable economic development. This paper focused on clean coal technologies in which coal-fired power plants are used in conjunction with large amounts of renewable energy sources to offer a high level of process safety and long term management of all residual operation streams. Thermal Desorption Recycle-Reduce-Reuse Technology (TDT-3R) was described as being a promising solid fuel pretreatment process for clean energy production up to 300 MWe capacities. TDT-3R is based on low temperature carbonisation fuel pre-treatment principles, which produce cleansed anthracite type fuels from coal and other carbonaceous material such as biomass and organic wastes. The combustion efficiency of such clean coals and the environmental performance of the TDT-3R process were investigated in this study via pilot scale tests of clean fuel production. Tests included flue gas emissions monitoring, raw fuel and product characterisation and thermogravimetric tests, polychlorinated dibenzo-p-dioxins and dibenzo-furans, and heavy metals analyses, and toxicity tests. Raw material included coal and biomass, such as willow, straw and demolition wood. The fuels were heated in a rotary kiln operating at 550 degrees C under slightly vacuum conditions. Clean coals were tested either alone or in conjunction with biomass fuels in a pilot scale combustion facility at Dresden, Germany. The clean coal samples were shown to have higher fixed carbon and ash content and lower volatiles compared to the respective raw coal samples. The major advantage of the TDT-3R process is the production of fuels with much lower pollutants content. Low nitrogen, sulphur, chlorine and heavy metal contents result in produced fuels that have excellent environmental performance, allow boiler operation in higher temperatures and overall better efficiency. Moreover, the use of clean fuels reduces deposition problems in the combustion chamber due to the

  14. Effect of the synthetic zeolite modification on its physicochemical and catalytic properties in the preparation of the catalysts effectively removing sulphur dioxide from exhaust gases

    Directory of Open Access Journals (Sweden)

    Marcewicz-Kuba Agnieszka

    2016-06-01

    Full Text Available This work presents the research results of the influence of modification deSONOx type catalyst of the sulfur dioxide emissions in the process of the hard coal combustion. The addition of zeolite catalysts modified by transition metal ions: V, Mg, activated by zinc sorbent with or without graphite addition caused the deeper burning of coal grains. The addition of the deSOx catalysts to the coal resulted in lowered sulphur dioxide emission. The addition of unmodified zeolite to coal during combustion reduced sulphur dioxide emission at about 5%. The modification of the support by both V and Mg reduced the amount of sulphur dioxide significantly. The obtained results of SO2 removal from exhaust gases were from 34.5% for Sip/Mg to 68.3% for Sip/V.

  15. Highly stable and regenerable Mn-based/SBA-15 sorbents for desulfurization of hot coal gas

    International Nuclear Information System (INIS)

    Zhang, F.M.; Liu, B.S.; Zhang, Y.; Guo, Y.H.; Wan, Z.Y.; Subhan, Fazle

    2012-01-01

    Highlights: ► A series of mesoporous Cu x Mn y O z /SBA-15 sorbents were fabricated for hot coal gas desulfurization. ► 1Cu9Mn/SBA-15 sorbent with high breakthrough sulfur capacity is high stable and regenerable. ► Utilization of SBA-15 constrained the sintering and pulverization of sorbents. - Abstract: A series of mesoporous xCuyMn/SBA-15 sorbents with different Cu/Mn atomic ratios were prepared by wet impregnation method and their desulfurization performance in hot coal gas was investigated in a fixed-bed quartz reactor in the range of 700–850 °C. The successive nine desulfurization–regeneration cycles at 800 °C revealed that 1Cu9Mn/SBA-15 presented high performance with durable regeneration ability due to the high dispersion of Mn 2 O 3 particles incorporated with a certain amount of copper oxides. The breakthrough sulfur capacity of 1Cu9Mn/SBA-15 observed 800 °C is 13.8 g S/100 g sorbents, which is remarkably higher than these of 40 wt%LaFeO 3 /SBA-15 (4.8 g S/100 g sorbents) and 50 wt%LaFe 2 O x /MCM-41 (5.58 g S/100 g sorbents) used only at 500–550 °C. This suggested that the loading of Mn 2 O 3 active species with high thermal stability to SBA-15 support significantly increased sulfur capacity at relatively higher sulfidation temperature. The fresh and used xCuyMn/SBA-15 sorbents were characterized by means of BET, XRD, XPS, XAES, TG/DSC and HRTEM techniques, confirmed that the structure of the sorbents remained intact before and after hot coal gas desulfurization.

  16. Investigations into NOx emissions and burnout for coals with high ash content in a bench scale test facility

    Energy Technology Data Exchange (ETDEWEB)

    Greul, U.; Kluger, F.; Peter, G.; Spliethoff, H.; Hein, K.R.G. [University of Stuttgart, Stuttgart (Germany). Inst. fuer Verfahrenstechnik und Dampfkesselwesen

    2000-07-01

    At the Stuttgart University's Institute of Process Engineering and Power Plant Technology (IVD) investigations of in-furnace DeNOx technologies with regard to their NOx reduction efficiency are carried out using an electrically heated bench-scale test facility to evaluate the effect of different process parameters independently. The DeNOx technologies of air and fuel staging have been demonstrated to be effective control techniques to reduce NOx from stationary sources. For a wide range of brown and hard coals from Europe, South Africa and Australia test runs with air-staged combustion have been carried out. The ash content of the hard coals used was in the range between 8 and 28%. The investigated parameters were temperature (1000-1300{degree}C), stoichiometry (1.25-0.55), and residence time (1-6 s) in the fuel rich primary zone. With increasing temperatures and residence times in fuel-rich conditions in air-staged combustion NOx emissions below 300 mg/m{sup 3} can be achieved even with hard coals. For a few brown coals NOx values lower than 100 mg/m{sup 3} are possible. Dependent on the coal rank individual parameters are more important than others. For low and medium volatile hard coals the increasing of the residence time is more effective than higher temperature or lower air ratios in the primary zone. However, with high volatile hard coal or brown coal as primary fuel the influence of temperature and stoichiometry in the primary zone plays a key role for NOx reduction effectiveness. The burnout led to restrictions in large scale applications for air-staged combustion especially with hard coals as primary fuel. Investigations at different primary air ratios and temperatures show the effect of these parameters on the burnout values along the course of combustion. 7 refs., 14 figs., 2 tabs.

  17. Coal - 97

    International Nuclear Information System (INIS)

    Sparre, C.

    1997-01-01

    The report deals with the use of coal and coke during 1996. Some information about techniques, environmental questions and markets are also given. Data have been collected by questionnaires to major users and by telephone to minor users. Preliminary statistical data from SCB have also been used. The use of steam coal for heating purposes during 1996 was 1,2 mill tons and 50% higher than in 1995. The increase is probably temporary and due to high prices of electricity because of lack of water power. The co-generation plants were the main users of coal. The minor plants have increased their use of forest fuels. Probably the use of steam coal will go down in the immediate years both in the heat generating and the co-generation plants. During the top year 1987 coal was used in 18 hotwater plants and 11 co-generation plants. 1996 these figures are 3 and 12. Taxes and environmental reasons explain this trend. The use of steam coal in the industry has been constant at the level 700 000 tons. This level is supposed to be constant or to vary with business cycles. The import of metallurgical coal in 1996 was 1,6 mill tons like the year before. 1,2 mill tons coke were produced. The coke consumption in the industry was 1,5 mill tons. 0,3 mill tons of coke were imported. The average price of steam coal imported in Sweden in 1996 was 340 SEK/ton or 2% higher than in 1995. For the world, the average import price was 51,5 USD/ton, nearly the same as the year before. The contract prices for delivery during 1997 are about equal as the end of 1996. All Swedish plants meet their emission limits of dust, SO 2 and NO x given by county administrations or concession boards

  18. Fuel production from coal by the Mobil Oil process using nuclear high-temperature process heat

    International Nuclear Information System (INIS)

    Hoffmann, G.

    1982-01-01

    Two processes for the production of liquid hydrocarbons are presented: Direct conversion of coal into fuel (coal hydrogenation) and indirect conversion of coal into fuel (syngas production, methanol synthesis, Mobil Oil process). Both processes have several variants in which nuclear process heat may be used; in most cases, the nuclear heat is introduced in the gas production stage. The following gas production processes are compared: LURGI coal gasification process; steam reformer methanation, with and without coal hydrogasification and steam gasification of coal. (orig./EF) [de

  19. Efficiency and emissions of coal combustion in two unvented cookstoves

    International Nuclear Information System (INIS)

    Kaoma, J.; Kasali, G.B.; Ellegaard, A.

    1994-01-01

    An improved chamber method was employed in the evaluation of the energy conversion and emission characteristics of coal in two unvented cookstoves known as the clay stove and the Maamba stove. Burn rate and stove efficiency were determined together with mission factors for carbon monoxide (CO), nitric oxide (NO) and respirable suspended particulates (RSP). Compared to Maamba stove, the clay stove exhibited a lower burn rate but higher efficiency. The clay stove recorded mean CO, SO 2 , NO 2 , NO and RSP emission factors of 200, 47, 10, 0.4 and 2.4 g/kg, respectively. The Maamba stove emission factors for the same pollutants were 170, 36, n.d., 1.2 and 8.0 g/kg, respectively. The emissions and concentrations of carbon monoxide were less than those previously found with charcoal use, but still exceeded air pollution guidelines by orders of magnitude. Thus the use of coal would not constitute any appreciable improvement over the present charcoal use. Sulphur dioxide emissions and concentrations are quite high, and would constitute a new pollutant in residential areas of Zambia. Particulate emissions and concentrations from coal are higher than from charcoal. In view of specific health risks associated with particulates from coal smoke the domestic use of raw coal is not recommended. 16 refs, 8 figs, 20 tabs

  20. Moderate temperature gas purification system: application to high calorific coal derived fuel

    Energy Technology Data Exchange (ETDEWEB)

    M. Kobayashi; H. Shirai; M. Nunokawa [Central Research Institute of Electric Power Industry (CRIEPI), Kanagawa (Japan)

    2005-07-01

    Simultaneous removal of dust, alkaline and alkaline-earth metals, halides and sulfur compounds is required to enlarge application of coal-derived gas to the high temperature fuel cells and the fuel synthesis through chemical processing. Because high calorific fuel gas, such as oxygen-blown coal gas, has high carbon monoxide content, high temperature gas purification system is always subjected to the carbon deposition and slippage of contaminant of high vapor pressure. It was suggested that moderate temperature operation of the gas purification system is applied to avoid the harmful disproportionation reaction and efficient removal of the various contaminants. To establish the moderate temperature gas purification system, the chemical-removal processes where the reaction rate is predominant to the performance of contaminant removal should be evaluated. Performance of the removal processes for halides and sulfur compounds were experimentally evaluated. The halide removal process with sodium based sorbent had potential good performance at around 300{sup o}C. The sulfur removal process was also applicable to the temperature range, although the improvement of the sulfidation reaction rate is considered to be essential. 11 refs., 8 figs., 1 tab.

  1. Trace element geochemistry and mineralogy of coal from Samaleswari open cast coal block (S-OCB), Eastern India

    Science.gov (United States)

    Saha, Debasree; Chatterjee, Debashis; Chakravarty, Sanchita; Mazumder, Madhurina

    2018-04-01

    Coal samples of Samaleswari open cast coal block (S-OCB) are high ash (Aad, mean value 35.43%) and low sulphur content (St, on dry basis, mean value 0.91% analysis. The work is further supported by the use of chemical fractionation experiment that reveals the multi mode of occurrence of several environmentally concern and interested trace elements (Sb, As, Be, Cd, Cr, Co, Cu, Pb, Mn, Ni, Zn). Among the analysed trace elements Co, Mn and Zn have major silicate association along with significant carbonate/oxide/monosulfide association. Whereas As, Cd, Cu, Pb and Ni have dominant pyritic association with notable silicate and carbonate/oxide/monosulfide association. The rest three elements (Sb, Be, Cr) have principally organic association with minor silicate and carbonate/oxide/monosulfide association. The stratigraphic variation of organo-mineral matrix content and detrital-authigenic mineral ratio are primarily related to coal rank. Geochemical character of coal also reflects a light towards proper utilisation of S-OCB coal from technical and environmental view point.

  2. Summary of workshop on materials issues in low emission boilers and high efficiency coal-fired cycles

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1997-12-01

    The purpose of the workshop was to review with experts in the field the materials issues associated with two of the primary coal power systems being developed by the DOE Office of Fossil Energy. The DOE-FE Advanced Power Systems Program includes natural gas-based and coal-based power systems. Major activities in the natural gas-based power systems area include the Advanced Turbine Systems (ATS) Program, the Fuel Cells Program, and Hybrid Cycles. The coal-based power systems projects include the Low Emissions Boiler Systems (LEBS) Program, the High-Performance Power Systems Program (HIPPS), the Integrated (Coal) Gasification Combined-Cycle Program, and the Fluidized-Bed Combustion Program. This workshop focused on the materials issues associated with the LEBS and HIPPS technologies.

  3. A process for briquetting coal with the production of briquets with high resistance to crushing

    Energy Technology Data Exchange (ETDEWEB)

    Ono, M; Ito, S; Nakagava, K

    1983-02-08

    Finely ground coal is mixed with a binder with a softening point of greater than or equal to 30 degrees and with heavy coal tar products, the mixture is molded with the formation of briquets in a two roller press. The mixing is conducted in heated steam or waste gases from a horizontal, helical mixer. The coal is subsequently irrigated by the melted binder and heavy coal tar products. The heavy coal tar products are a bottom residue formed by condensation of volatile products in a gas stream from coking which contains particles of coal and coke. Briquets with a point compression strength of 50 plus or minus 4 kilograms per sq. cur. and a bulk tensity of 1.17 grams per cubic centimeter are produced from a mixture which contains 6 percent binder, 80 percent coal and 20 percent heavy coal tar products.

  4. Teratogenicity following inhalation exposure of rats to a high-boiling coal liquid

    Energy Technology Data Exchange (ETDEWEB)

    Springer, D.L.; Poston, K.A.; Mahlum, D.D.; Sikov, M.R.

    1982-01-01

    On days 12 to 16 of gestation pregnant rats were exposed to heavy distillate (hd), the highest-boiling material derived from the solvent refined coal-II (SRC-II) process, and the litters were examined at day 21. Adverse biological effects were observed in the group of animals exposed to an aerosol concentration of 0.66 mg 1/sup -1/ (1.8 ..mu..m, mass medium aerodynamic diameter); groups of animals exposed to lower aerosol concentrations (0.084 and 0.017 mg 1/sup -1/) were largely unaffected. Embryolethality during mid- and late gestation appeared attributable to the coal liquid exposure. Fetuses from pregnant rats in the high exposure group were smaller in weight and length than fetuses from control animals, and skeletal ossification was reduced. Increased incidences of small lungs and cleft palate were observed in fetuses from the high exposure group. Pregnant rats in the high-exposure group gained less weight than controls during gestation; the reduced weight gain was accounted for by the reduced size of the fetuses and placentas. Even though maternal body weight (exclusive of the products of conception) was unaffected by the exposure, the weights of the maternal thymus, lung and spleen were altered in the high exposure group.

  5. Teratogenicity following inhalation exposure of rats to a high-boiling coal liquid

    Energy Technology Data Exchange (ETDEWEB)

    Springer, D.L.; Poston, K.A.; Mahlum, D.D.; Sikov, M.R.

    1982-01-01

    On days 12-16 of gestation pregnant rats were exposed to heavy distillate (HD), the highest-boiling material derived from the solvent refined coal-II (SRC-II) process, and the litters were examined at day 21. Adverse biological effects were observed in the group of animals exposed to an aerosol concentration of 0.66 mg 1/sup -1/ (1.8 ..mu..m, mass medium aerodynamic diameter (MMAD)); groups of animals exposed to lower aerosol concentrations (0.084 and 0.017 mg 1/sup -1/) were largely unaffected. Embryolethality during mid- and late gestation appeared attributable to the coal liquid exposure. Fetuses from pregnant rats in the high exposure group were smaller in weight and length than fetuses from control animals, and skeletal ossification was reduced. Increased incidences of small lungs and cleft palate were observed in fetuses from the high exposure group. Pregnant rats in the high-exposure group gained less weight than controls during gestation; the reduced weight gain was accounted for by the reduced size of the fetuses and placentas. Even though maternal body weight (exclusive of the products of conception) was unaffected by the exposure, the weights of the maternal thymus, lung and spleen were altered in the high exposure group.

  6. High-performance self-compacting concrete with the use of coal burning waste

    Science.gov (United States)

    Bakhrakh, Anton; Solodov, Artyom; Naruts, Vitaly; Larsen, Oksana; Alimov, Lev; Voronin, Victor

    2017-10-01

    Today, thermal power plants are the main producers of energy in Russia. Most of thermal power plants use coal as fuel. The remaining waste of coal burning is ash, In Russia ash is usually kept at dumps. The amount of utilized ash is quite small, less than 13%. Meanwhile, each ash dump is a local ecological disaster. Ash dumps take a lot of place and destroy natural landscape. The use of fly ash in building materials can solve the problem of fly ash dumps in Russia. A lot of papers of scientists are devoted to the use of fly ash as filler in concrete. The main advantage of admixing fly ash in concrete is decrease of amount of used cement. This investigation was held to find out if it is possible to utilize fly ash by its use in high amounts in self-compacting concrete. During experiments three mixtures of SCC with different properties were obtained. The first one is experimental and shows the possibility of obtaining SCC with high compressive strength with 60% of fly ash from the mass of cement. Two other mixtures were optimized with the help of the math planning method to obtain high 7-day and 28-day high compressive strength.

  7. Moderate temperature gas purification system: Application to high calorific coal-derived fuel

    Energy Technology Data Exchange (ETDEWEB)

    Kobayashi, M.; Shirai, H.; Nunokawa, M. [Central Research Institute of Electric Power Industry, Kanagawa (Japan)

    2008-01-15

    Simultaneous removal of dust, alkaline and alkaline-earth metals, halides and sulfur compounds is required to enlarge application of coal-derived gas to the high-temperature fuel cells and the fuel synthesis through chemical processing. Because high calorific fuel gas, such as oxygen-blown coal gas, has high carbon monoxide content, high-temperature (above 450{sup o}C) gas purification system is always subjected to the carbon deposition. We suggest moderate temperature (around 300{sup o}C) operation of the gas purification system to avoid the harmful disproportionation reaction and efficient removal of the various contaminants. Because the reaction rate is predominant to the performance of contaminant removal in the moderate temperature gas purification system, we evaluated the chemical removal processes; performance of the removal processes for halides and sulfur compounds was experimentally evaluated. The halide removal process with sodium aluminate sorbent had potential performance at around 300{sup o}C. The sulfur removal process with zinc ferrite sorbent was also applicable to the temperature range, though the reaction kinetics of the sorbent is essential to be approved.

  8. Desulphurization of coal: bioleaching versus bioconditioning and flotation

    Energy Technology Data Exchange (ETDEWEB)

    M. Zeki Dogan; Gulhan Ozbayoglu [Istanbul Technical University, Istanbul (Turkey). Faculty of Mining

    2007-07-01

    There are two bio-desulphurization methods for the removal of pyritic sulphur, namely, bacterial leaching and bacterial conditioning for pyrite depression followed by flotation of coal. Bacterial leaching is a slow process, consequently, microbial desulphurization is focused on conditioning coal by bacteria for a short time, followed by flotation. The application of Acidithiobacillus ferrooxidans in bioconditioning followed by flotation process help the oxidation of pyrite surface and enhance its depression during the flotation of coal. By bacterial conditioning for 4 hours followed by flotation, almost 78 % pyritic sulphur removal was attained with the yield of 78 % in the floated coal, whereas bacterial leaching resulted in pyritic sulphur removal of 56.60 % in 10 days. 17 refs., 5 tabs.

  9. Sulphur oxidising bacteria in mangrove ecosystem: A review

    African Journals Online (AJOL)

    SAM

    2014-07-16

    Jul 16, 2014 ... factors such as salinity and nutrient availability highly variable. Mangrove .... sulphate and converts it into organic sulphur compound. (Subba Rao ..... of organic fertilizer long favored in Australia. .... Fish. Technol. Soc. 21:126-130. Dias ACF, Andreote FD, Rigonato J, Fiore MF, Melo IS, Araujo WL. (2010).

  10. Hot atom chemistry of sulphur

    International Nuclear Information System (INIS)

    Todorovski, D. S.; Koleva, D. P.

    1982-01-01

    An attempt to cover all papers dealing with the hot atom chemistry of sulpphur is made. Publications which: a) only touch the problem, b) contain some data, indirectly connected with sulphur hot atom chemistry, c) deal with 35 S-production from a chloride matrix, are included as well. The author's name and literature source are given in the original language, transcribed, when it is necessary, in latine. A number of primery and secondary documents have been used including Chemical Abstracts, INIS Atomindex, the bibliographies of A. Siuda and J.-P. Adloff for 1973 - 77, etc. (authors)

  11. The effect of the particulate phase on coal biosolubilisation mediated by Trichoderma atroviride in a slurry bioreactor

    Energy Technology Data Exchange (ETDEWEB)

    Oboirien, B.O.; Burton, S.G. [Bioprocess Engineering Research Unit, Department of Chemical Engineering, University of Cape Town, Rondebosch, 7701 (South Africa); Cowan, D. [Bioprocess Engineering Research Unit, Department of Chemical Engineering, University of Cape Town, Rondebosch, 7701 (South Africa); Department of Biotechnology, University of the Western Cape, Belville (South Africa); Harrison, S.T.L.

    2008-02-15

    Low rank coal is currently under-utilised because of its low calorific value and high moisture and sulphur content. Its solubilisation by both bacterial and fungal cultures has been reported, the latter more commonly. Coal biosolubilisation processes have potential to convert low rank coal to either a clean, cost-effective energy source or complex aromatic compounds for biocatalytic conversion to value-added products. This can lead to an increased utilisation of low rank coal. In this study, the key variables of the slurry that affect biosolubilisation of low rank coal by Trichoderma atroviride in submerged culture were investigated. Results showed that the key operating variables that influence coal biosolubilisation in the slurry bioreactor are coal loading and particle size affecting available surface area. These factors affect the surface area available for coal biosolubilisation. The optimum coal loading occurred between 5 and 10% (w/v); an increase above this optimum led to inhibition of the fungal culture of T. atroviride (ES11) by fragmentation of the fungal mycelium. A decrease in particle size fraction led to an increase in the degree of coal solubilisation. Coal biosolubilisation was shown to increase 4-fold when particle size was decreased from 600-850 {mu}m to 150-300 {mu}m. A 28% biosolubilisation of coal of 150-300 {mu}m, characterised by a surface specific area of 2.17 cm{sup 2} g{sup -} {sup 1}, was measured as coal weight loss over 14 days at solids loading at 5%. This can be compared with a 7.8% coal weight loss at 600-850 {mu}m diameters (0.54 cm{sup 2} g{sup -} {sup 1}). Soluble phenolic compounds are not a significant product of the coal biosolubilisation process. The change in pH observed in the presence of both coal and fungi was independent of coal loading and was not directly related to the extent of coal solubilisation. While soluble intermediates were observed as total organic, further metabolism resulted in complete oxidation of a

  12. Small-Scale Coal-Biomass to Liquids Production Using Highly Selective Fischer-Tropsch Synthesis

    Energy Technology Data Exchange (ETDEWEB)

    Gangwal, Santosh K. [Southern Research Institute, Durham, NC (United States); McCabe, Kevin [Southern Research Institute, Durham, NC (United States)

    2015-04-30

    The research project advanced coal-to-liquids (CTL) and coal-biomass to liquids (CBTL) processes by testing and validating Chevron’s highly selective and active cobalt-zeolite hybrid Fischer-Tropsch (FT) catalyst to convert gasifier syngas predominantly to gasoline, jet fuel and diesel range hydrocarbon liquids, thereby eliminating expensive wax upgrading operations The National Carbon Capture Center (NCCC) operated by Southern Company (SC) at Wilsonville, Alabama served as the host site for the gasifier slip-stream testing/demonstration. Southern Research designed, installed and commissioned a bench scale skid mounted FT reactor system (SR-CBTL test rig) that was fully integrated with a slip stream from SC/NCCC’s transport integrated gasifier (TRIGTM). The test-rig was designed to receive up to 5 lb/h raw syngas augmented with bottled syngas to adjust the H2/CO molar ratio to 2, clean it to cobalt FT catalyst specifications, and produce liquid FT products at the design capacity of 2 to 4 L/day. It employed a 2-inch diameter boiling water jacketed fixed-bed heat-exchange FT reactor incorporating Chevron’s catalyst in Intramicron’s high thermal conductivity micro-fibrous entrapped catalyst (MFEC) packing to efficiently remove heat produced by the highly exothermic FT reaction.

  13. Coal geopolitics

    International Nuclear Information System (INIS)

    Giraud, P.N.; Suissa, A.; Coiffard, J.; Cretin, D.

    1991-01-01

    This book divided into seven chapters, describes coal economic cycle. Chapter one: coals definition; the principle characteristics and properties (origin, calorific power, international classification...) Chapter two: the international coal cycle: coal mining, exploration, coal reserves estimation, coal handling coal industry and environmental impacts. Chapter three: the world coal reserves. Chapter four: the consumptions, productions and trade. Chapter five: the international coal market (exporting mining companies; importing companies; distributors and spot market operators) chapter six: the international coal trade chapter seven: the coal price formation. 234 refs.; 94 figs. and tabs [fr

  14. Reducing the emissions of nitrogen oxides when burning Kuznetsk bituminous coals

    Energy Technology Data Exchange (ETDEWEB)

    Kotler, V.R.

    1983-02-01

    Bituminous coals from the Kuzbass have a high nitrogen content. As a result, emissions of NO/SUB/x from power stations burning these coals frequently exceed the existing Standard. In order to reduce NO/SUB/x emissions tests were carried out using stage-wise combustion, supplying to the burners only part of the air required for complete combustion. The remaining air is supplied via tertiary nozzles situated about 14 m above the burners. As a result of the tests, this method of combustion is recommended for low-sulphur Kuznetsk coals for all sub-critical boilers having dry-bottom furnaces. Extension to boilers with wet-bottom furnaces and to supercritical boilers requires further investigation.

  15. Coal -98

    International Nuclear Information System (INIS)

    Sparre, C.

    1998-01-01

    The following report deals with the use of coal and coke during 1997. Some information about technic, environmental questions and markets are also given. Data have been collected by questionnaires to major users and by telephone to minor users. Preliminary statistical data from SCB have also been used. The use of steam coal for heating purposes during 1997 was 730 000 tons and about 500 000 tons lower than in 1996. The extremely high figures of 1996 were due to twice the production of electricity because of lack of hydro power. The co-generation plants were the main users of coal. The minor plants have increased their use of forest fuels. Probably the use of steam coal will go down in the immediate years both in the heat generating and the co-generating plants. Some foreign analysts, however, estimate a doubled use of coal for energy use after 2020 because of the plans to phase out the nuclear power. During the top year 1987 coal was used in 18 hot water plants and 11 co-generation plants. 1997 these figures are 2 and 8. Taxes and environmental reasons explain this trend. The use of steam coal in the industry has been constant at the level 700 000 tons. This level is supposed to be constant or to vary with business cycles. The import of metallurgical coal in 1997 was 1.6 mill tons like the year before. 1.2 mill tons coke were produced. The coke consumption in the industry was 1.5 Mill tons. 0.3 mill tons of coke were imported. Several other plants have plans to replace the coal with forest fuels, waste fuels and NG. Even the biggest plant, Vaesteraas, has plans to build a block for bio fuels. Helsingborg has started to use wood pellets. The pellets replace most of the coal for the heat production in the co-generation plant. Norrkoeping Kraft AB has taken a fluid bed boiler for different fuels in operation, leading to more than half the coal consumption compared with previous years. They have also rebuilt one of their travelling grates for bio fuels. Stockholm

  16. Determination of sulfur in coal and ash slurry by high-resolution continuum source electrothermal molecular absorption spectrometry

    Energy Technology Data Exchange (ETDEWEB)

    Nakadi, Flávio V.; Rosa, Lilian R.; Veiga, Márcia A.M.S. da, E-mail: mamsveiga@ffclrp.usp.br

    2013-10-01

    We propose a procedure for the determination of sulfur in coal slurries by high resolution continuum source electrothermal molecular absorption spectrometry. The slurry, whose concentration is 1 mg mL{sup −1}, was prepared by mixing 50 mg of the sample with 5% v/v nitric acid and 0.04% m/v Triton X-100 and was homogenized manually. It sustained good stability. The determination was performed via CS molecular absorption at 257.592 nm, and the optimized vaporization temperature was 2500 °C. The accuracy of the method was ensured by analysis of certified reference materials SRM 1632b (trace elements in coal) and SRM 1633b (coal fly ash) from the National Institute of Standards and Technology, using external calibration with aqueous standards prepared in the same medium and used as slurry. We achieved good agreement with the certified reference materials within 95% confidence interval, LOD of 0.01% w/w, and RSD of 6%, which confirms the potential of the proposed method. - Highlights: • HR-CS ET MAS as a technique to determine sulfur in coal and ash • Utilization of (coal and coal fly ash) slurry as a sample preparation • Simple and fast method, which uses external calibration with aqueous standards without chemical modifier.

  17. Highly Dispersed Pseudo-Homogeneous and Heterogeneous Catalysts Synthesized via Inverse Micelle Solutions for the Liquefaction of Coal

    Energy Technology Data Exchange (ETDEWEB)

    Hampden-Smith, M.; Kawola, J.S.; Martino, A.; Sault, A.G.; Yamanaka, S.A.

    1999-01-05

    The mission of this project was to use inverse micelle solutions to synthesize nanometer sized metal particles and test the particles as catalysts in the liquefaction of coal and other related reactions. The initial focus of the project was the synthesis of iron based materials in pseudo-homogeneous form. The frost three chapters discuss the synthesis, characterization, and catalyst testing in coal liquefaction and model coal liquefaction reactions of iron based pseudo-homogeneous materials. Later, we became interested in highly dispersed catalysts for coprocessing of coal and plastic waste. Bifunctional catalysts . to hydrogenate the coal and depolymerize the plastic waste are ideal. We began studying, based on our previously devised synthesis strategies, the synthesis of heterogeneous catalysts with a bifunctional nature. In chapter 4, we discuss the fundamental principles in heterogeneous catalysis synthesis with inverse micelle solutions. In chapter 5, we extend the synthesis of chapter 4 to practical systems and use the materials in catalyst testing. Finally in chapter 6, we return to iron and coal liquefaction now studied with the heterogeneous catalysts.

  18. Extractive de-sulfurization and de-ashing of high sulfur coals by oxidation with ionic liquids

    International Nuclear Information System (INIS)

    Saikia, Binoy K.; Khound, Kakoli; Baruah, Bimala P.

    2014-01-01

    Highlights: • Extractive de-sulfurization and de-ashing process for cleaning high sulfur coals. • The process removes inorganic as well as organic sulfur components from high sulfur coals. • The process has less risk to chemists and other surroundings. - Abstract: The environmental consequences of energy production from coals are well known, and are driving the development of desulfurization technologies. In this investigation, ionic liquids were examined for extractive desulfurization and de-ashing in industrially important high sulfur sub-bituminous Indian coals. The ionic liquids, namely, 1-n-butyl-3-methylimidazolium tetrafluoroborate (IL1) and 1-n-butyl 3-methylimidazolium chloride (IL2) were employed for desulfurization of a few Indian coal samples in presence of HCOOH/H 2 O 2 and V 2 O 5 . Results show the maximum removal of 50.20% of the total sulfur, 48.00% of the organic sulfur, and 70.37 wt% of the ash in this process. The ionic liquids were recovered and subsequently used for further desulfurization. FT-IR spectra reveal the transformation of organic sulfur functionalities into the sulfoxides (S=O) and sulfones (-SO 2 ) due to the oxidative reactions. The sulfate, pyrite and sulfides (aryls) signals in the near edge X-ray absorption fine structure (NEXAFS) of the oxidized coal samples showed sulfur transformation during the desulfurization process. The study demonstrates the removal of significant amount of inorganic as well as organic sulfur (aryls) components from the original high sulfur coal samples to make them cleaner

  19. Enginnering development of coal-fired high performance power systems phase II and III

    International Nuclear Information System (INIS)

    1998-01-01

    This report presents work carried out under contract DE-AC22-95PC95144 ''Engineering Development of Coal-Fired High Performance Systems Phase II and III.'' The goals of the program are to develop a coal-fired high performance power generation system (HIPPS) that is capable of: thermal efficiency (HHV) >47%; NOx, SOx, and particulates 65% of heat input; all solid wastes benign; cost of electricity <90% of present plants. Phase I, which began in 1992, focused on the analysis of various configurations of indirectly fired cycles and on technical assessments of alternative plant subsystems and components, including performance requirements, developmental status, design options, complexity and reliability, and capital and operating costs. Phase I also included preliminary R ampersand D and the preparation of designs for HIPPS commercial plants approximately 300 MWe in size. This phase, Phase II, involves the development and testing of plant subsystems, refinement and updating of the HIPPS commercial plant design, and the site selection and engineering design of a HIPPS prototype plant. Work reported herein is from: Task 2.2 HITAF Air Heaters; Task 6 HIPPS Commercial Plant Design Update

  20. Development of a Linear Flow Channel Reactor for sulphur removal ...

    African Journals Online (AJOL)

    2013-09-23

    Sep 23, 2013 ... gation of sulphur production in floating sulphur biofilms as a means for addressing this problem. These 50 µm ... Preliminary studies on the use of the FSB system for sulphur removal in Integrated Managed Passive Treatment ...

  1. Coal as a supplemental heat source in sludge incineration

    Energy Technology Data Exchange (ETDEWEB)

    Swanson, G J; Bergstedt, D C

    1979-07-01

    The use of coal as a supplemental fuel in multiple hearth sludge incineration was investigated; how sulphur lump coal was added to dewatered sludge being fed to the furnace, reducing incinerator oil requirements by 70%. With full-scale retrofit of the treatment plant total annual costs for coal supplemental feeding would be 161,000 dollars, but oil savings would be 240,000 dollars.

  2. Optimal sulphuric acid production using Acidithiobacillus caldus ...

    African Journals Online (AJOL)

    AFRICAN JOURNALS ONLINE (AJOL) · Journals · Advanced Search · USING ... oxygen uptake rate of 1.35 g/L.day (OUR), 52% sulphur conversion at a rate of 0.83 ... achieving a sulphuric acid production rate of 2.76 g/L.day (dP/dt), while the ...

  3. Porous carbon nanosheets from coal tar for high-performance supercapacitors

    Science.gov (United States)

    He, Xiaojun; Ma, Hao; Wang, Jingxian; Xie, Yuanyang; Xiao, Nan; Qiu, Jieshan

    2017-07-01

    A hydroxide-template strategy coupled with in-situ chemical activation is reported for the first time to fabricate porous carbon nanosheets (PCNSs) from coal tar. The thin PCNSs feature abundant short pores accessible for fast ion transport and high specific surface area up to 3235 m2 g-1 for ion adsorption. As electrodes for supercapacitors, the PCNSs show a high capacitance of 296.2 F g-1 at 0.05 A g-1 in 6 M KOH electrolyte, an excellent rate performance with a capacitance of 220.7 F g-1 at 20 A g-1 and a superior cycle stability with over 97.2% capacitance retention after 11000 charge-discharge cycles at 3.5 A g-1. This work paves a new way for efficient fabrication of sheet-like carbon materials with tuned porous structure from polycyclic aromatic hydrocarbons for high performance supercapacitors.

  4. Atributos químicos relacionados ao processo de sulfurização em solos construídos após mineração de carvão Chemical attributes of constructed soils after surface coal mining related to sulphurization process

    Directory of Open Access Journals (Sweden)

    Alberto Vasconcellos Inda

    2010-05-01

    process changes soil and landscape characteristics, pirite may oxide and change soil chemical and mineralogical characteristics. In this context, the study aimed to evaluate the temporal evolution of soils reconstructed 2 (SA-2 and 24 (SA-24 year ago, in Boa Vista Coal Mining, in Minas do Leão, Rio Grande do Sul, Brazil. Soil characteristics measured were pH, electrical conductivity (EC, bases and aluminium content, potential acidity (H+Al, and contents of Al, Fe, Si, and soluble sulphate. Calculations accounted for cation exchange capacity, base saturation and aluminum saturation. Results indicated occurrence of oxidation processes in both reconstructed areas. Electrical condutivity and soluble phosphate contents were higher in SA-2, indicating a more active sulphurization stage in these soils. In soils of area SA-24, lower EC and smaller contents of soluble sulphate, lower base saturation, as well as higher aluminum saturation and H+Al suggest a more advanced sulphurization process compared to SA-2. Aluminum and P concentrated in older soil profiles. Soils in both areas have chemical limitations for plant growth with adversely affects to recuperation of the area.

  5. Bulk analysis of coal

    International Nuclear Information System (INIS)

    Sowerby, B.D.

    1982-01-01

    Nuclear techniques used in the coal industry to determine specific energy, ash and moisture are outlined. Ash analysis by radioisotope X-ray techniques include a single X-ray measurement using a transmission or backscatter geometry and techniques with compensation for iron variations. Neutron techniques can be used to measure the concentration of some specific elements in coal. The measurement of specific energy, ash and moisture then depends on the correlation of the particular parameter with the measured elemental composition. Carbon can be determined by a combination of a measurement of 4.43 MeV 12 C gamma-rays from neutron inelastic scattering with a separate 60 Co gamma-ray scattering measurement. Sulphur meters are based on the measurement of 5.42 MeV neutron capture of gamma rays

  6. Comparison of methods for the determination of reduced inorganic sulphur in acid sulphate soils

    International Nuclear Information System (INIS)

    Santomartino, S.L.

    1999-01-01

    Full text: The management of acid sulphate soils requires analytical methods that provide accurate data on the quantity of reduced inorganic sulphur within a soil, as it is this fraction that produces acid upon oxidation. This study uses sulphidic Coode Island Silt samples to compare common analytical methods including POCAS (Peroxide Oxidation-Combined Acidity and Sulphate) which consists of TSA (Total Sulphidic Acidity), S pos (Peroxide Oxidisable Sulphur), TOS (Total Oxidisable Sulphur) and chromium-reducible sulphur. The determination of total sulphur by Leco sulphur is strongly correlated with, but slightly less than, that analysed by XRF. Comparison of soil sulphide content by chromium-reducible sulphur, TSA and TOS methods indicates that TOS values are substantially higher than both other methods. The problem with the TOS method lies in the sulphate extraction procedure. Hot distilled water and HCI are commonly used as extractants, however hot distilled water fails to remove organic sulphur, thereby overestimating the sulphide content of the soil. Leco carbon analyses verify that a substantial proportion of organic matter exists within the samples. The HCI extraction process, which uses Ion Chromatography to analyse for sulphate, produces highly inaccurate results due to the interference of the sulphate peak by the chloride peak during analysis. An alternative method involving HCI extraction and XRF analysis of the soil residue is currently being undertaken. The use of KCI to extract sulphate generally produces values similar to the hot distilled water method. The sulphidic content measured by TSA is strongly correlated with, but slightly higher than that determined by the chromium-reducible sulphur method. This is attributed to the use of hydrogen peroxide in the TSA method, which oxidises organic matter to organic acids in addition to oxidising sulphides. These preliminary findings indicate that the chromium-reducible sulphur method is the most suitable

  7. Temperature induced development of porous structure of bituminous coal chars at high pressure

    Directory of Open Access Journals (Sweden)

    Natalia Howaniec

    2016-01-01

    Full Text Available The porous structure of chars affects their reactivity in gasification, having an impact on the course and product distribution of the process. The shape, size and connections between pores determine the mechanical properties of chars, as well as heat and mass transport in thermochemical processing. In the study the combined effects of temperature in the range of 973–1273 °K and elevated pressure of 3 MPa on the development of porous structure of bituminous coal chars were investigated. Relatively low heating rate and long residence time characteristic for the in-situ coal conversion were applied. The increase in the temperature to 1173 °K under pressurized conditions resulted in the enhancement of porous structure development reflected in the values of the specific surface area, total pore volume, micropore area and volume, as well as ratio of the micropore volume to the total pore volume. These effects were attributed to the enhanced vaporization and devolatilization, as well as swelling behavior along the increase of temperature and under high pressure, followed by a collapse of pores over certain temperature value. This proves the strong dependence of the porous structure of chars not only on the pyrolysis process conditions but also on the physical and chemical properties of the parent fuel.

  8. Engineering development of coal-fired high performance power systems, Phase II and III

    Energy Technology Data Exchange (ETDEWEB)

    None

    1999-04-01

    The goals of the program are to develop a coal-fired high performance power generation system (HIPPS) that is capable of: thermal efficiency (HHV) {ge} 47%, NOx, SOx, and particulates {le} 10% NSPS (New Source Performance Standard) coal providing {ge} 65% of heat input, all solid wastes benign, and cost of electricity {le} 90% of present plants. Phase 1, which began in 1992, focused on the analysis of various configurations of indirectly fired cycles and on technical assessments of alternative plant subsystems and components, including performance requirements, developmental status, design options, complexity and reliability, and capital and operating costs. Phase 1 also included preliminary R and D and the preparation of designs for HIPPS commercial plants approximately 300 MWe in size. This phase, Phase 2, involves the development and testing of plant subsystems, refinement and updating of the HIPPS commercial plant design, and the site selection and engineering design of a HIPPS prototype plant. Work reported herein is from: Task 2.1 HITAC Combustors; Task 2.2 HITAF Air Heaters; Task 6 HIPPS Commercial Plant Design Update.

  9. High temperature solvent extraction of oil shale and bituminous coal using binary solvent mixtures

    Energy Technology Data Exchange (ETDEWEB)

    Goetz, G.K.E. [Lehrstuhl fuer Geologie, Geochemie und Lagerstaetten des Erdoels und der Kohle, RWTH Aachen (Germany)

    1997-12-31

    A high volatile bituminous coal from the Saar Basin and an oil shale from the Messel deposit, both Germany, were extracted with binary solvent mixtures using the Advanced Solvent Extraction method (ASE). Extraction temperature and pressure were kept at 100 C, respectively 150 C, and 20,7 MPa. After the heating phase (5 min) static extractions were performed with mixtures (v:v, 1:3) of methanol with toluene, respectively trichloromethane, for further 5 min. Extract yields were the same or on a higher level compared to those from classical soxhlet extractions (3 days) using the same solvents at 60 C. Comparing the results from ASE with those from supercritical fluid extraction (SFE) the extract yields were similar. Increasing the temperature in ASE releases more soluble organic matter from geological samples, because compounds with higher molecular weight and especially more polar substances were solubilized. But also an enhanced extraction efficiency resulted for aliphatic and aromatic hydrocarbons which are used as biomarkers in Organic Geochemistry. Application of thermochemolysis with tetraethylammonium hydroxide (TEAH) using pyrolysis-gas chromatography-mass spectrometry (Py-GC-MS) on the extraction residues shows clearly that at higher extraction temperatures minor amounts of free fatty acids or their methyl esters (original or produced by ASE) were trapped inside the pore systems of the oil shale or the bituminous coal. ASE offers a rapid and very efficient extraction method for geological samples reducing analysis time and costs for solvents. (orig.)

  10. Steam reforming of commercial ultra-low sulphur diesel

    Energy Technology Data Exchange (ETDEWEB)

    Boon, J.; Van Dijk, E.; De Munck, S.; Van den Brink, R. [Energy research Centre of The Netherlands, ECN Hydrogen and Clean Fossil Fuels, P.O. Box 1, NL1755ZG Petten (Netherlands)

    2011-03-11

    Two main routes for small-scale diesel steam reforming exist: low-temperature pre-reforming followed by well-established methane steam reforming on the one hand and direct steam reforming on the other hand. Tests with commercial catalysts and commercially obtained diesel fuels are presented for both processes. The fuels contained up to 6.5 ppmw sulphur and up to 4.5 vol.% of biomass-derived fatty acid methyl ester (FAME). Pre-reforming sulphur-free diesel at around 475C has been tested with a commercial nickel catalyst for 118 h without observing catalyst deactivation, at steam-to-carbon ratios as low as 2.6. Direct steam reforming at temperatures up to 800C has been tested with a commercial precious metal catalyst for a total of 1190 h with two catalyst batches at steam-to-carbon ratios as low as 2.5. Deactivation was neither observed with lower steam-to-carbon ratios nor for increasing sulphur concentration. The importance of good fuel evaporation and mixing for correct testing of catalysts is illustrated. Diesel containing biodiesel components resulted in poor spray quality, hence poor mixing and evaporation upstream, eventually causing decreasing catalyst performance. The feasibility of direct high temperature steam reforming of commercial low-sulphur diesel has been demonstrated.

  11. Steam reforming of commercial ultra-low sulphur diesel

    Science.gov (United States)

    Boon, Jurriaan; van Dijk, Eric; de Munck, Sander; van den Brink, Ruud

    Two main routes for small-scale diesel steam reforming exist: low-temperature pre-reforming followed by well-established methane steam reforming on the one hand and direct steam reforming on the other hand. Tests with commercial catalysts and commercially obtained diesel fuels are presented for both processes. The fuels contained up to 6.5 ppmw sulphur and up to 4.5 vol.% of biomass-derived fatty acid methyl ester (FAME). Pre-reforming sulphur-free diesel at around 475 °C has been tested with a commercial nickel catalyst for 118 h without observing catalyst deactivation, at steam-to-carbon ratios as low as 2.6. Direct steam reforming at temperatures up to 800 °C has been tested with a commercial precious metal catalyst for a total of 1190 h with two catalyst batches at steam-to-carbon ratios as low as 2.5. Deactivation was neither observed with lower steam-to-carbon ratios nor for increasing sulphur concentration. The importance of good fuel evaporation and mixing for correct testing of catalysts is illustrated. Diesel containing biodiesel components resulted in poor spray quality, hence poor mixing and evaporation upstream, eventually causing decreasing catalyst performance. The feasibility of direct high temperature steam reforming of commercial low-sulphur diesel has been demonstrated.

  12. The dynamic behaviour of rail vehicles operating at high speeds for manriding in British coal mines

    Energy Technology Data Exchange (ETDEWEB)

    Manen, P. van

    1984-01-01

    The behaviour of trains used at high speeds for transporting men along mine railways is examined using a number of mathematical models. These models predict the responses of different rail vehicles to typical irregularities in the track, and are used to examine the guidance, the ride, and the likelihood of derailment of the main classes of manriding trains used in British coal mines. The outcome of the modelling compares favourably with the results of tests carried out on actual vehicles. The investigation has shown that the safe speed at which trains may operate is ultimately restricted by the condition of the track, but changes in the design of the vehicles can lead to an improved performance. The use of conventional wheelsets, for example, can reduce flange wear significantly and so allow higher speeds to be reached. Guidelines for the design of vehicles intended for high speed use are included in this thesis. (36 refs.)

  13. Research on desulfurisation of fine coal under compounding the physics force field

    Energy Technology Data Exchange (ETDEWEB)

    Tao, Y.; Fu, D.; Tao, D.; Liu, J.; Zhao, Y. [China University of Mining and Technology, Xuzhou (China)

    2005-08-15

    Desulphurization experiment carried on under compounding the physics force field was described for -0.5 mm fine particle of high sulphur coal. The experiment factorial plan of desulphurization on centrifugal gravity Falcon separator was designed and its results were analyzed by using Design-Expert 6.0 software. The 2-reactor interaction relation model between comprehensive desulphurization efficiency of pyrite sulphur and different operation variable was drawn, i.e. 2 FI model, and the 2-factor interaction on pyrite desulphurization efficiency of the operation factors differently was analyzed. The interaction on pyrite desulphurization efficiency of feed rate and feed concentration is significant. The optimization test condition for desulphurization was proposed by Design-Expert 6.0, and comprehensive desulphurization efficiency of 86.90% can be achieved. 5 refs., 3 figs., 7 tabs.

  14. Distinctive features of high-ash bituminuos coals combution with low milling fineness in furnace chambers with bottom blowing

    Science.gov (United States)

    Zroychikov, N. A.; Kaverin, A. A.; Biryukov, Ya A.

    2017-11-01

    Nowadays the problem of improvement of pulverized coal combustion schemes is an actual one for national power engineering, especially for combustion of coals with low milling fineness with significant portion of moisture or mineral impurities. In this case a big portion of inert material in the fuel may cause impairment of its ignition and combustion. In addition there are a lot of boiler installations on which nitrogen oxides emission exceeds standard values significantly. Decreasing of milling fineness is not without interest as a way of lowering an electric energy consumption for pulverization, which can reach 30% of power plant’s auxiliary consumption of electricity. Development of a combustion scheme meeting the requirements both for effective coal burning and environmental measures (related to NOx emission) is a complex task and demands compromising between these two factors, because implementation of NOx control by combustion very often leads to rising of carbon-in-ash loss. However widespread occurrence of such modern research technique as computer modeling allows to conduct big amount of variants calculations of combustion schemes with low cost and find an optimum. This paper presents results of numerical research of combined schemes of coal combustion with high portion of inert material based on straight-flow burners and nozzles. Several distinctive features of furnace aerodynamics, heat transfer and combustion has been found. The combined scheme of high-ash bituminouos coals combustion with low milling fineness, which allows effective combustion of pointed type of fuels with nitrogen oxides emission reduction has been proposed.

  15. Utilization of HSC-ROSE residue as coking aid for the production of high quality coke from brown coal

    Energy Technology Data Exchange (ETDEWEB)

    Bohlmann, D.; Limmer, H.; Naundorf, W.; Hood, R.L.; Washimi, K. (VEB Petrolchemisches Kombinat, Schwedt (German Democratic Republic))

    1989-04-01

    Evaluates suitability of HSC-ROSE petroleum pitch as binder for production of brown coal coke. This pitch has been available in the GDR since installation in 1988 of a 750 kt/a HSC (high conversion soaker cracking) plant, which processes 360 C visbreaker residue from Soviet crude oil, and the building of a ROSE (residue oil supercritical reaction) plant. Laboratory as well as semi-industrial experiments were carried out at the Freiberg Academy, GDR on pulverizing, briquetting and coking various brown coal types with HSC-ROSE pitch. Briquetting and coking results are shown in tables. Experiments showed that the resulting coke has 124% higher compression strength and 100% higher abrasion strength than regular brown coal coke without HSC-ROSE binder. The high quality coke is adequate for use as metallurgical blast furnace coke. An economic assessment of modifying an existing brown coal coking plant to process 2 Mt/a brown coal with 10% pitch binder is made. Required investment amounts to 54 million US dollars, estimated annual profits based on 1987 prices are 19.5 million US dollars. 4 refs.

  16. Distribution of sulphur and trace elements in peat. A literature survey with some additional sulphur analyses

    Energy Technology Data Exchange (ETDEWEB)

    Huttunen, S; Karhu, M

    1981-01-01

    A survey on the literature and contemporary research was made on peat sulphur and trace element studies. Marked variance between different peatlands and peat types has been noted. The available information is still inadequate for generalizations or statistical analysis mainly due to methodological variations and temporal and spatial variations in results. At the moment, the criteria applied in peatland inventories and evaluations are inadequate with respect to peat quality determinations. To some extent the quality of fuel peat should be determined in a mire inventory prior to peatland utilization. The areas over sulphide clay and some sulphate depositions may considerably increase the peat sulphur content. A proposal has been made to include the sulphur content monitoring in the cases where it exceeds 0.3 per cent. The trace elements may also bring about an increase in peat emissions if the deepest peat layers or polluted layers are burnt. The most important elements in this respect are Al, Fe, Mn, Pb, Zn, V, Ni, Hg, Cu, Cr, as well as As and U. The first ten because of the relatively high concentrations and last two because of pollution or toxocity and ore deposit factors. The peat hydrogen ion concentration has a positive correlation with copper and vanadium. The correlation is positive with the cobalt and nickel contents when the pH is low, and negative at a higher pH. A general peat type correlation shows maximum trace element contents in basal Carex peats with subsoil effects. The peat ash content and the Ti, Pb, V, Cr, Ni, and S contents have positive correlations. (Refs. 290).

  17. Distribution of sulphur and trace elements in peat. [Literature survey with some additional sulphur analyses

    Energy Technology Data Exchange (ETDEWEB)

    Huttunen, S; Karhu, M

    1981-01-01

    A survey on the literature and contemporary research was made on peat sulphur and trace element studies. Marked variance between different peatlands and peat types has been noted. The available information is still inadequate for generalizations or statistical analysis mainly due to methodological variations and temporal and spatial variations in results. At the moment, the criteria applied in peatland inventories and evaluations are inadequate with respect to peat quality determinations. To some extent the quality of fuel peat should be determined in a mire inventory prior to peatland utilization. The areas over sulphide clay and some sulphate depositions may considerably increase the peat sulphur content. A proposal has been made to include the sulphur content monitoring in the cases where it exceeds 0.3 per cent. The trace elements may also bring about an increase in peat emissions if the deepest peat layers or polluted layers are burnt. The most important elements in this respect are Al, Fe, Mn, Pb, Zn, V, Ni, Hg, Cu, Cr, as well as As and U. The first ten because of the relatively high concentrations and last two because of pollution or toxocity and ore deposit factors. The peat hydrogen ion concentration has a positive correlation with copper and vanadium. The correlation is positive with the cobalt and nickel contents when the pH is low, and negative at a higher pH. A general peat type correlation shows maximum trace element contents in basal Carex peats with subsoil effects. The peat ash content and the Ti, Pb, V, Cr, Ni and S contents have positive correlations.

  18. Survey on improvement in development of coal in Asia-Pacific region in fiscal 1998. Survey on expansion of production of high-grade coal in Shanxi Province, China; 1998 nendo Asia Taiheiyo sekitan kaihatsu kodoka chosa. Chugoku Sanseisho ni okeru kohin'itan no seisan kakudai ni kansuru chosa

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1999-03-01

    With the Datong mining area as the object, a Japan-China joint survey was carried out on improvement in coal development. The Datong coal field is the largest coal field in China. Measures for improving and stabilizing the quality of the coal are planned to achieve stable supply of high-grade coal to Japan. The city of Datong occupies a large part of the Datong coal field, producing more than 40 million tons. Minable reserve quantity reaches 2.47 billion tons. Measures to prevent foreign materials (such as detonators and metal pieces) from mixing in, and quality stabilization are the problems to be solved. Required measures include first of all not putting out used detonators, optimization and multiplexing of the magnet separator installing positions. Variation in the grade of original coal may include regional variation and that caused from coal beds, whereas optimization in coal dressing is important in improving the grade of coal product. The coal dressing rate at three coal mines possessing a coal dressing factory is 40 to 50%, and twelve other coal mines depend on sieve sorting. An on-line analyzer for product coal grade control is also required. Coal shipment and storage management is also important. Indispensable is structuring a system to feed back users' claims, evaluation and information. (NEDO)

  19. Regional modelling of anthropogenic sulphur in Southeast Asia

    Science.gov (United States)

    Engardt, M.; Leong, C. P.

    A co-operative research project between the Malaysian Meteorological Service (MMS) and the Swedish Meteorological and Hydrological Institute (SMHI) focussing on the usage of an atmospheric transport and chemistry model, has just been initiated. Here, we describe the main features of the dispersion model and discuss a first set of calculations in light of available measurements of sulphuric species in Southeast Asia. According to our results, anthropogenic sulphur concentrations and depositions are particularly high near the large cities of the region, around a metal smelter in the southern Philippines, and in a region extending from northern Vietnam into southeastern China. These areas coincide with the high-emissions regions of Southeast Asia and we tentatively conclude that regional transport of acidifying species is not as far-reaching as in the mid-latitudes. From our calculations, and from supporting measurements we conclude that most of rural Southeast Asia is not yet severely affected by anthropogenic sulphur, but given the rapid rate of economical development in this region the situation may deteriorate quickly. Areas that are particularly at risk include the large cities, northern Vietnam, most of central Thailand, most of peninsular Malaysia, eastern Sumatra and parts of Java, all of which receive total-sulphur depositions in excess of 0.5 g S m -2 yr -1. Our model simulates sulphate in precipitation in accordance with measurements, but it has a tendency to overestimate atmospheric SO 2. It remains to be investigated whether this is a problem in the model formulation or a result of unrepresentative sampling. An immediate continuation of this study should be performed with higher spatial resolution than the currently used 100×100 km 2. Other imperfections in this model study, which should be addressed in future work, include parameterised vertical transport in deep convective clouds, the influence of natural emissions (primarily from volcanoes) on the

  20. The detection of the coal roof interface by use of high pressure water

    Science.gov (United States)

    1981-01-01

    A device whereby water jets can be used to detect the interface between coal and the overlying roof rock is described. Once this identification is made this distance can be measured using instruments such as the autofocus systems recently developed in the photographic industry. Experiments carried out show that the device can discriminate between coal and rock at coal thicknesses up to 8 inches. An autofocus system was examined which indicates accuracies of better than 0.1 inches.

  1. Production of High-Hydrogen Content Coal-Derived Liquids [Part 3 of 3

    Energy Technology Data Exchange (ETDEWEB)

    Stephen Bergin

    2011-03-30

    The primary goal of this project has been to evaluate and compare the effect of the intrinsic differences between cobalt (Co) and iron (Fe) catalysts for Fischer-Tropsch (FT) synthesis using coal-derived syngas. Crude oil, especially heavy, high-sulfur crude, is no longer the appropriate source for the additional, or marginal, amounts of middle-distillate fuels needed to meet growing US and world demand for diesel and jet fuels. Only about 1/3 of the marginal crude oil barrel can be made into diesel and jet fuels. The remaining 2/3 contributes further to global surpluses of by-products. FT can produce these needed marginal, low-sulfur middle-distillate fuels more efficiently, with less environmental impact, and from abundant US domestic resources. Cobalt FT catalyst is more efficient, and less expensive overall, than iron FT catalyst. Mechanisms of cobalt FT catalyst functioning, and poisoning, have been elucidated. Each of these primary findings is amplified by several secondary findings, and these are presented, and verified in detail. The most effective step the United States can take to begin building toward improved long-term national energy security, and to reduce dependence, over time, on imported crude oil from unfriendly and increasingly unstable areas of the world, is to begin producing additional, or marginal amounts of, middle-distillate-type fuels, such as ultralow sulfur diesel (ULSD) and jet fuel (not gasoline) from US domestic resources other than petroleum. FT synthesis of these middle distillate fuels offers the advantage of being able to use abundant and affordable US coal and biomass as the primary feedstocks. Use of the cobalt FT catalyst system has been shown conclusively to be more effective and less expensive than the use of iron FT catalyst with syngas derived from coal, or from coal and biomass combined. This finding is demonstrated in detail for the initial case of a relatively small FT plant of about 2000 barrels per day based upon coal

  2. Production of High-Hydrogen Content Coal-Derived Liquids [Part 2 of 3

    Energy Technology Data Exchange (ETDEWEB)

    Stephen Bergin

    2011-03-30

    The primary goal of this project has been to evaluate and compare the effect of the intrinsic differences between cobalt (Co) and iron (Fe) catalysts for Fischer-Tropsch (FT) synthesis using coal-derived syngas. Crude oil, especially heavy, high-sulfur crude, is no longer the appropriate source for the additional, or marginal, amounts of middle-distillate fuels needed to meet growing US and world demand for diesel and jet fuels. Only about 1/3 of the marginal crude oil barrel can be made into diesel and jet fuels. The remaining 2/3 contributes further to global surpluses of by-products. FT can produce these needed marginal, low-sulfur middle-distillate fuels more efficiently, with less environmental impact, and from abundant US domestic resources. Cobalt FT catalyst is more efficient, and less expensive overall, than iron FT catalyst. Mechanisms of cobalt FT catalyst functioning, and poisoning, have been elucidated. Each of these primary findings is amplified by several secondary findings, and these are presented, and verified in detail. The most effective step the United States can take to begin building toward improved long-term national energy security, and to reduce dependence, over time, on imported crude oil from unfriendly and increasingly unstable areas of the world, is to begin producing additional, or marginal amounts of, middle-distillate-type fuels, such as ultralow sulfur diesel (ULSD) and jet fuel (not gasoline) from US domestic resources other than petroleum. FT synthesis of these middle distillate fuels offers the advantage of being able to use abundant and affordable US coal and biomass as the primary feedstocks. Use of the cobalt FT catalyst system has been shown conclusively to be more effective and less expensive than the use of iron FT catalyst with syngas derived from coal, or from coal and biomass combined. This finding is demonstrated in detail for the initial case of a relatively small FT plant of about 2000 barrels per day based upon coal

  3. Production of High-Hydrogen Content Coal-Derived Liquids [Part 1 of 3

    Energy Technology Data Exchange (ETDEWEB)

    Stephen Bergin

    2011-03-30

    The primary goal of this project has been to evaluate and compare the effect of the intrinsic differences between cobalt (Co) and iron (Fe) catalysts for Fischer-Tropsch (FT) synthesis using coal-derived syngas. Crude oil, especially heavy, high-sulfur crude, is no longer the appropriate source for the additional, or marginal, amounts of middle-distillate fuels needed to meet growing US and world demand for diesel and jet fuels. Only about 1/3 of the marginal crude oil barrel can be made into diesel and jet fuels. The remaining 2/3 contributes further to global surpluses of by-products. FT can produce these needed marginal, low-sulfur middle-distillate fuels more efficiently, with less environmental impact, and from abundant US domestic resources. Cobalt FT catalyst is more efficient, and less expensive overall, than iron FT catalyst. Mechanisms of cobalt FT catalyst functioning, and poisoning, have been elucidated. Each of these primary findings is amplified by several secondary findings, and these are presented, and verified in detail. The most effective step the United States can take to begin building toward improved long-term national energy security, and to reduce dependence, over time, on imported crude oil from unfriendly and increasingly unstable areas of the world, is to begin producing additional, or marginal amounts of, middle-distillate-type fuels, such as ultralow sulfur diesel (ULSD) and jet fuel (not gasoline) from US domestic resources other than petroleum. FT synthesis of these middle distillate fuels offers the advantage of being able to use abundant and affordable US coal and biomass as the primary feedstocks. Use of the cobalt FT catalyst system has been shown conclusively to be more effective and less expensive than the use of iron FT catalyst with syngas derived from coal, or from coal and biomass combined. This finding is demonstrated in detail for the initial case of a relatively small FT plant of about 2000 barrels per day based upon coal

  4. Coal Matrix Deformation and Pore Structure Change in High-Pressure Nitrogen Replacement of Methane

    Directory of Open Access Journals (Sweden)

    Xiaofeng Ji

    2018-01-01

    Full Text Available Coal matrix deformation is one of the main controlling factors for coal reservoir permeability changes in nitrogen foam fracturing. The characteristics and mechanism of coal matrix deformation during the process of adsorption/desorption were studied by isothermal adsorption/desorption experiments with methane and nitrogen. Based on the free-energy theories, the Langmuir equation, and elastic mechanics, mathematical models of coal matrix deformation were developed and the deformation characteristics in adsorption/desorption processes were examined. From the study, we deduced that the coal matrix swelling, caused by methane adsorption, was a Langmuir-type relationship with the gas pressure, and exponentially increased as the adsorption quantity increased. Then, the deformation rate and amplitude of the coal matrix decreased gradually with the increase of the pressure. At the following stage, where nitrogen replaces methane, the coal matrix swelling continued but the deformation amplitude decreased, which was only 19.60% of the methane adsorption stage. At the mixed gas desorption stage, the coal matrix shrank with the reduction of pressure and the shrinkage amount changed logarithmically with the pressure, which had the hysteresis effect when compared with the swelling in adsorption. The mechanism of coal matrix deformation was discussed through a comparison of the change of micropores, mesopores, and also part macropores in the adsorption process.

  5. Quality of Coal in the Deposit Kongora - Tomislavgrad

    International Nuclear Information System (INIS)

    Zivkovic, S.; Nuic, J.; Krasic, D.

    1998-01-01

    The document accepted in Kyoto, signed by the republic of Croatia, oblige the signatory countries in view of the Agreement on reducing emissions of noxious gases. These obligations burden the development of the energy sector by high technological requirements which will make energy even more expensive. The basic part of the energy system constitute fossil fuel driven thermal power plants (presently found less hazardous than the nuclear option). The commitment of the republic of Croatia to build up a basic thermal energy system in the years to come has initiated a series of discussions on energy sources, i.e. on the choice of fossil fuels. Possibilities have been studied as regards the import of gas (Siberia, Algeria), coal (Australia, the USA, Colombia, etc.), while at the same time neglecting the resources in immediate vicinity. Major coal deposits in the Dalmatian hinterland (Bosnia and Herzegovina), 70km from the Adriatic coast, deserve the attention of experts and scientists in surveying energy potential, particularly as it is a question of the low caloric value coal with scant sulphur (under 1 percent). So far the experiences are favourable and point to the coal deposit Kongora as a possible energy potential. (author)

  6. Relaxation and gas drainage boreholes for high performance longwall operations in low permeability coal seams

    Energy Technology Data Exchange (ETDEWEB)

    Imgrund, Thomas [DMT GmbH und Co. KG, Essen (Germany); Bauer, Frank [Hazemag und EPR GmbH, Duelmen (Germany). Mining

    2013-06-15

    With an increasing depth of cover, gas emission control and gas outbursts prevention has become an increasingly important issue in coal mining. Deep multi-seam mining often requires operation in an environment characterised by a high gas content and gas pressure. Control of gas related risks has to be realised during heading and close to the longwall by proper risk assessment and flexible drilling schemes. These cover exploration and relaxation drilling, in-seam drilling for pre-drainage and cross measure drilling for drainage of roof and the floor gas emissions. DMT provides comprehensive solutions based on a scientific background. These solutions are engineered considering their technical feasibility. Hazemag Mining offers a large number of complete machinery including tools systems for the implementation of those solutions. (orig.)

  7. The Chemical Percolation Devolatilization Model Applied to the Devolatilization of Coal in High Intensity Acoustic Fields

    Directory of Open Access Journals (Sweden)

    Veras Carlos A. G.

    2002-01-01

    Full Text Available The chemical percolation devolatilization model (CPD was extended for the prediction of drying and devolatilization of coal particles in high intensity acoustic fields found in Rijke tube reactors. The acoustic oscillations enhance the heat and mass transfer processes in the fuel bed as well as in the freeboard, above the grate. The results from simulations in a Rijke tube combustor have shown an increase in the rate of water evaporation and thermal degradation of the particles. The devolatilization model, based on chemical percolation, applied in pulsating regime allowed the dynamic prediction on the yields of CO, CO2, CH4, H2O, other light gases as well as tar which are important on ignition and stabilization of flames. The model predicted the quantity and form of nitrogen containing species generated during devolatilization, for which knowledge is strategically indispensable for reducing pollutant emissions (NOx in flames under acoustic excitation .

  8. Di- or polysulphide-bound biomarkers in sulphur-rich geomacromolecules as revealed by selective chemolysis

    NARCIS (Netherlands)

    Sinninghe Damsté, J.S.; Kohnen, M.E.L.; Kock-van Dalen, A.C.; Leeuw, J.W. de

    1991-01-01

    Three types of sulphur-rich, high-molecular-weight material in the alkylsulphide, the polar and the asphaltene fracions isolated from the bitumen of an immature bituminous shale from the Vena del Gesso basin (Italy) were desulphurised.

  9. Development of clean coal and clean soil technologies using advanced agglomeration technologies

    International Nuclear Information System (INIS)

    Ignasiak, B.; Pawlak, W.; Szymocha, K.; Marr, J.

    1990-04-01

    The specific objectives of the bituminous coal program were to explore and evaluate the application of advanced agglomeration technology for: (1)desulphurization of bituminous coals to sulphur content acceptable within the current EPA SO 2 emission guidelines; (2) deashing of bituminous coals to ash content of less than 10 percent; and (3)increasing the calorific value of bituminous coals to above 13,000 Btu/lb. (VC)

  10. Effect of Sulphur Fertilization on Grain Quality and Protein Composition of Durum Wheat (Triticum durum Desf.

    Directory of Open Access Journals (Sweden)

    Marianna Pompa

    2009-12-01

    Full Text Available The reduction of atmosphere emission of SO2 and the massive use of fertilizers high in nitrogen and phosphorus resulted in a decrease of the sulphur content in the soil. In durum wheat cultivation, sulphur supply plays a key role not only for plant growth, but also for grain quality. Sulphur is an essential macronutrient primarily used to synthesize methionine and cysteine and it is also involved in establishing protein structures by disulphide bonds. The aim of this study was to evaluate the effect of sulphur nutrition on grain quality and protein composition of durum wheat cultivars grown under water deficit conditions, typical of Mediterranean areas. To this purpose, in the 2003-2004 and 2004-2005 crop seasons a field trial was carried out by comparing two water regimes (irrigated and rainfed, two sulphur fertilizer levels and two durum wheat cultivars. Under our experimental conditions, an increase in protein and gluten content in the rainfed treatment and a positive effect of sulphur fertilization on quality parameters were observed. Few changes were observed in protein composition in response to sulphur fertilization.

  11. Assessing the suitability of Norway spruce wood as an environmental archive for sulphur

    International Nuclear Information System (INIS)

    Barrelet, T.; Ulrich, A.; Rennenberg, H.; Zwicky, C.N.; Kraehenbuehl, U.

    2008-01-01

    The aim of this study was to assess the suitability of Norway spruces (Picea abies L. Karst.) as an environmental archive for sulphur. For this purpose spruce trees were sampled in two distinct regions of Switzerland: the Alps and the Swiss Plateau, which differ significantly with respect to S immission. Wood samples were measured using two methods: LASER Ablation high resolution inductively coupled plasma mass spectrometry (LA-HR-ICP-MS) and inductively coupled plasma optical emission spectrometry (ICP-OES) after acid digestion. Independently corroborated by previous measurements of sulphur in peat bogs, the rise and fall of sulphur dioxide pollution in Switzerland appears to be reflected in spruce wood sulphur content. While the wood sulphur content profile of trees sampled in the Alps is relatively flat, the profiles of trees located on the Swiss Plateau display a characteristic sulphur peak. This corresponds to air pollution data in the different regions and indicates that the trees reacted on the changing S supply and recorded a pollution signal in the wood. - Norway spruce is a suitable archive for sulphur when physiological aspects and limitations are taken into account

  12. Trading sulphur emissions under the Second Sulphur Protocol

    Energy Technology Data Exchange (ETDEWEB)

    Foersund, Finn R.; Naevdal, Eric

    1997-07-01

    Emission trading is a potent policy instrument in theoretical analyses of environmental policy. However, trading in emission quotas of non-uniformly dispersed pollutants requires that the offsetting quantities vary with location of sources. Such a system is not yet in use. The Second Sulphur Protocol for Europe makes it possible to try out a system of ``exchange rates`` through a clause allowing ``joint implementation`` of emission reductions. In this report, the authors investigate some properties of a system with exogenous exchange rates within a simultaneous trade model based on cost efficiency. Incorporation of constraints on depositions in third party countries may be necessary in order to get third party country cooperation. It is demonstrated that imposition of constraints is feasible, but it is also revealed what demands such incorporation places on the design of the institutional setting. Constraints on trade should only be introduced when the concern for the environment of the various receptors fail to be captured adequately by the calibration of the exchange rates. 16 refs., 2 figs., 3 tabs.

  13. Gasification of coal as efficient means of environment protection and hydrogenation of heavy oils residues

    Energy Technology Data Exchange (ETDEWEB)

    Krichko, A.A.; Maloletnev, A.S. [Fossil Fuel Institute, Moscow (Russian Federation)

    1995-12-31

    The Russia`s more then 50% of coals produced in its European part contain over 2,5% of sulphur, and the coals containing less than 1.5% of sulphurs comprise ca.20%. Thus, utilisation of the sulphide coals is inevitable, and there a problem arises concerning the technology of their sensible use and considering the requirements on the environment protection. Russia`s specialists have developed a design and construction for a steam-gas installation with a closed cycle gasification of the solid fuel. The gasification process will proceed in the fluidized bed under forced pressure of the steam-air blast. Characteristic features of this process are the following: a higher efficiency (the capacity of one gas generator is 3-3,5 times larger than that attained in the present gas generators of the Lurgy`s type): 2-2,5 times decreased fuel losses as compared to the Winkler`s generators; retention of the sensible heat, resulting in an increased total energy efficiency. The main task for petroleum refining industry at the present stage is the increase of depth of oil processing with the aim to intensify motor fuel production. One of the ways to solve the problem is to involve heavy oil residues into the processing. But the high metal and asphaltenes contents in the latter make the application of traditional methods and processes more difficult. Up to now there is no simple and effective technology which could give the opportunity to use oil residues for distillate fractions production. In Fossil fuel institute a process for hydrogenation of high boiling oil products, including with high sulphur, vanadium and nickel contents ones, into distillates and metals concentrates. The main point of the new process is as follows: the water solution of catalytic additive, for which purpose water soluble metal salts of VI-VIII groups are used, is mixed with tar, dispersed and then subjected to additional supercavitation in a special apparatus.

  14. Self-scrubbing coal

    International Nuclear Information System (INIS)

    Kindig, J.K.

    1992-01-01

    More than 502 million tons - 65 percent of all coal shipped to utilities in 1990 - were above 1.2 pounds of sulfur dioxide per million Btu. Most of the coal, even though cleaned in conventional coal preparation plants, still does not meet the emission limitation the Clean Air Act Amendments mandate for the year 2000. To cope with this fact, most utilities plan to switch to low sulfur (western U.S. or Central Appalachian) coal or install scrubbers. Both solutions have serous drawbacks. Switching puts local miners out of work and weakens the economy in the utility's service territory. Scrubbing requires a major capital expenditure by the utility. Scrubbers also increase the operating complexity and costs of the generating station and produce yet another environmental problem, scrubber sludge. Employing three new cost-effective technologies developed by Customer Coals International (CCl), most non-compliance coals east of the Mississippi River can be brought into year-2000 compliance. The compliance approach employed, depends upon the characteristics of the raw coal. Three types of raw coal are differentiated, based upon the amount of organic sulfur in the coals and the ease (or difficultly) of liberating the pyrite. They are: Low organic sulfur content and pyrite that liberates easily. Moderate organic sulfur content and pyrite that liberates easily. High organic sulfur content or the pyrite liberates with difficulty. In this paper examples of each type of raw coal are presented below, and the compliance approach employed for each is described. The names of the beneficiated coal products produced from each type of raw coal give above are: Carefree Coal, Self-Scrubbing Coal and Dry-Scrubbing Coal

  15. Lance for injecting highly-loaded coal slurries into the blast furnace

    Energy Technology Data Exchange (ETDEWEB)

    Illuminati, D.

    1991-10-29

    A lance is used to inject fuel oil into a blast furnace. This simple design permits conversion of coal water and coal tar slurries to a fine mist at very low flow rates. This design prevents the build-up of deposits which increases service life and steadies the flow rate.

  16. Effect of bituminous coal properties on carbon dioxide and methane high pressure sorption

    Czech Academy of Sciences Publication Activity Database

    Weishauptová, Zuzana; Přibyl, Oldřich; Sýkorová, Ivana; Machovič, Vladimír

    2015-01-01

    Roč. 139, JAN 1 (2015), s. 115-124 ISSN 0016-2361 Institutional support: RVO:67985891 Keywords : bituminous coal * sorption capacity * maceral composition * Upper Silesian Coal Basin Subject RIV: CF - Physical ; Theoretical Chemistry Impact factor: 3.611, year: 2015

  17. Investigation on catalytic gasification of high-ash coal with mixing-gas in a small-scale fluidised bed

    Energy Technology Data Exchange (ETDEWEB)

    Chen, X.; Zhang, J.; Lin, J. [Fuzhou University, Fuzhou (China)

    2005-10-15

    The experimental study on the Yangquan high-ash coal catalytic gasification with mixing gas by using solid alkali or waste liquid of viscose fiber as the catalyst in a small-scale fluidized bed with 28 mm i.d. was carried out. The loading saturation levels of two catalysts in Yangquan high-ash coal are about 6%. Under the gasification temperature ranging from 830 to 900{sup o}C and from 900 to 920{sup o}C, the apparent reaction order of Yangquan high-ash coal with respect to the unreacted carbon fraction approximates to 2.3 and 1/3 for the non-catalyst case, respectively. Also, the different values of apparent reaction order in the two temperature ranges are presented for the case with 3% solid alkali catalyst loaded. At the low temperature ranging from 830 to 860{sup o}C, the apparent reaction order of catalytic gasification is 1 since enough active carbon sites on the coal surface are formed during the catalytic gasification by solid alkali. But at the high temperature ranging from 860 to 920{sup o}C, the sodium carbonate produced by the reaction of solid alkali with carbon dioxide can be easily fused, transferred and re-distributed, which affects the gasification reaction rate, and the apparent reaction order of catalytic gasification is reduced to 1.3. 10 refs., 9 figs., 4 tab s.

  18. A high resolution interferometric method to measure local swelling due to CO2 exposure in coal and shale

    NARCIS (Netherlands)

    Pluymakers, A.; Liu, J.; Kohler, F.; Renard, F.; Dysthe, D.

    2018-01-01

    We present an experimental method to study time-dependent, CO2-induced, local topography changes in mm-sized composite samples, plus results showing heterogeneous swelling of coal and shale on the nano- to micrometer scale. These results were obtained using high resolution interferometry

  19. Washability of Australian coals

    Energy Technology Data Exchange (ETDEWEB)

    Whitmore, R L

    1979-06-01

    Australian coals tend to be young in geological age and high in ash by world standards; preparation of the coal before marketing is almost universal. On the basis of float and sink data from 39 locations in the eastern Australian coalfields, the coals are place in four categories representing increasing difficulty in their washability characteristics. These seem to be related neither to the geological age nor the geographical position of the deposit and Hunter Valley coals, for example, span all categories. The influence of crushing on the washability of Australian coals is briefly considered and from limited data it is concluded to be appreciably smaller than for British or North American coals. A strategy for the float and sink analysis of Australian coals is proposed and the influence of washability characteristics on current trends in the selection of separating processes for coking and steaming products is discussed.

  20. Comparative study on sulphur reduction from heavy petroleum - Solvent extraction and microwave irradiation approach

    Energy Technology Data Exchange (ETDEWEB)

    Mohammed, Abdullahi Dyadya; Isah, Abubakar Garba; Umaru, Musa; Ahmed, Shehu [Department of Chemical Engineering, Federal University of Technology, P.M.B 65, Minna (Nigeria); Abdullahi, Yababa Nma [National Petroleum Investment Management Services (Nigeria National Petroleum Corporation), Lagos (Nigeria)

    2012-07-01

    Sulphur- containing compounds in heavy crude oils are undesirable in refining process as they affect the quality of the final product, cause catalyst poisoning and deactivation in catalytic converters as well as causing corrosion problems in oil pipelines, pumps and refining equipment aside environmental pollution from their combustion and high processing cost. Sulphur reduction has being studied using microwave irradiation set at 300W for 10 and 15minutes and oxidative- solvent extraction method using n- heptane and methanol by 1:1, 1:2 and 1:3 crude- solvent ratios after being oxidized with hydrogen peroxide, H2O2 oxidants. Percentage sulphur removal with n- heptane solvent by 1:1 and 1:2 are 81.73 and 85.47%; but extraction using methanol by different observed ratios gave less sulphur reduction. Indeed when microwave irradiated at 300W for 10 and 15minutes, 53.68 and 78.45% reduction were achieved. This indicates that microwave irradiation had caused oxidation by air in the oven cavity and results to formation of alkyl radicals and sulphoxide from sulphur compound in the petroleum. The prevailing sulphur found in the crude going by FT-IR results is sulphides which oxidized to sulphoxide or sulphones. It is clear that sulphur extraction with heptane is more efficient than microwave irradiation but economically due to demands for solvent and its industrial usage microwave irradiation can serve as alternative substitute for sulphur reduction in petroleum. Sulphur reduction by microwave radiation should be up- scaled from laboratory to a pilot plant without involving extraction column in the refining.

  1. Sulphur isotope variations in the atmosphere

    International Nuclear Information System (INIS)

    Newman, L.; Krouse, H.R.; Grinenko, V.A.

    1991-01-01

    The measurement of the isotope ratios of sulphur and oxygen can in principal be used to assess sulphur inputs into, transformation within, and removal from the atmosphere. Major inputs arise from both anthropogenic and biogenic activities. Transformations arise from oxidation, neutralization, and other chemical reactions. Advection causes dilution and the main removal processes are dry deposition (governed by gravitation and diffusion) and rain. The admixture of sources can be discerned from their isotopic signatures whereas transformations and removal can be followed from the isotopic fractionation that might occur. In this chapter, the atmospheric sulphur cycle and the associated chemistry are summarized. Also presented is information on natural isotopic variations and fundamental concepts relating to the use of isotopic data to delineate anthropogenic S in the atmosphere. Examples of successful applications of these concepts are given. Finally, consideration is given to the potential of using isotopically enriched sulphur to study transport and transformation of atmospheric S compounds. Refs, figs and tabs

  2. Sulphur recovery and sulphur emissions at Alberta sour gas plants : annual report for 2005

    International Nuclear Information System (INIS)

    2005-01-01

    The sulphur recovery of Alberta's grandfathered sour gas plants is monitored by the Alberta Energy and Utilities Board. This report provides an annual summary of industry performance for sulphur recovery at large acid gas flaring sour gas plants, and sulphur recovery at all acid gas injection sour gas plants. It follows Interim Directive (ID) 2001-3 which stipulates guidelines for sulphur recovery for the province of Alberta. It includes a list of grandfathered and non grandfathered plants in Alberta. Grandfathered sulphur recovery plants that exceed expectations have the option to file a sulphur emission performance credit report and can use the credits to meet some of their sulphur requirement in the future. Acid gas flaring plants face more stringent requirements and cannot earn credits. Several plants have degrandfathered in the past 5 years. Eleven have made upgrades, 4 have been relicensed to meet the requirements for new plants, and 4 have shut down. Forty-one grandfathered plants remain. Sulphur emissions have decreased 39 per cent for grandfathered acid gas flaring plants, and 28 per cent for grandfathered sulphur recovery plants. 10 tabs., 3 figs

  3. Old King Coal to the rescue as gas supplies dwindle

    International Nuclear Information System (INIS)

    Westbury, R. J.; Balash, A.

    2000-01-01

    Rumours persist about an impending shortage of natural gas, despite solid evidence to suggest that there are vast reserves yet to be discovered. The foundation for the rumours are the fact of increasing per capita demand for natural gas; insufficient financial incentive to vigorously pursue exploration since the easily discoverable reserves of oil and gas have been found long ago, and the cost of discovering oil and natural gas in more difficult formations have risen faster than the rate of inflation. Other reasons cited from time to time include the lack of present day technology that can extract the vast amounts of gas and oil in remaining reserves, and references to the exploding population of the developing world such as India, Pakistan and China, who are major users of oil and gas. It is not expected that nuclear power, wind, solar and geothermal energy sources will become fashionable in the near future, leaving hydrocarbons, and mainly coal, as the only readily available energy source. Although because of the high sulphur content coal gets a bad press, it is a fact that coal-fired power plants, equipped with modern scrubbing equipment, could meet the same pollution limits as natural gas-fired plants. For the moment, the power generating industry is reluctant to invest in the costly equipment for clean coal-fired plants, however, this short-sighted view may well lead to increases in the price of natural gas that will mimic the results of the OPEC increases in crude oil in the 1970s. These authors contend that if gas is wasted in power generation, society will suffer the reappearance of coal-fired home heating furnaces with all the attendant increases in air pollution due to the relatively inefficient combustion of coal in domestic space heating appliances

  4. Removal of chlorine from Illinois coal by high-temperature leaching: Final report, March 1--December 31, 1987

    Energy Technology Data Exchange (ETDEWEB)

    Chen, Han Lin

    1988-03-01

    The objectives of this research are to: (1) conduct experimental investigations of the removal of chlorine from coal by high- temperature leaching; (2) identify important factors affecting the chlorine removal process; (3) understand the mechanisms involved; and (4) develop a mathematical model to describe the process. A generalized mathematical model based on diffusion and relaxation has been developed for water leaching of chlorine from coal. The model has been fitted to four different samples of Illinois No. 6 coal: C22175, C22651, C8601, and C8602. The weight percent of chlorine ranged from 0.42 to 0.82. The experimental data on these samples covered a temperature range of 297 to 370K and a particle size range of 60 to 325 mesh. Based on the type of coal and the conditions of leaching, it was found that 40 to 80% of the original chlorine could be leached from the coal matrix. The model based on diffusion-relaxation concept predicted the leaching data within +-5% average absolute deviation. The diffusion rate constants at different temperatures were correlated to Arrhenius type relations. Attempts made to correlate the constants in the Arrhenius equations with the chlorine content in coal and with particle size have been discussed. The water leaching data were used to extract Fickian diffusivities based on the time required for 50% desorption. The calculated diffusivity values ranged from 0.6 to 3 /times/ 10/sup /minus/11/ cm/sup 2//sec. The effect of chemical additives on the rate of leaching has also been studied. Both HNO/sub 3/ and NH/sub 4/OH were used as additives. 28 refs., 3 figs., 7 tabs.

  5. Hypothermia reduces sulphur mustard toxicity

    International Nuclear Information System (INIS)

    Mi Lei; Gong Wenrong; Nelson, Peggy; Martin, Leanne; Sawyer, Thomas W.

    2003-01-01

    The effect of temperature on the development of sulphur mustard (HD)-induced toxicity was investigated in first passage cultures of human skin keratinocytes and on hairless guinea pig skin. When cells exposed to HD were incubated at 37 deg. C, a concentration-dependent decline in viability was observed that was maximal by 2 days. In contrast, no significant HD-induced toxicity was evident up to 4 days posttreatment when the cells were incubated at 25 deg. C. However, these protective effects were lost by 24 h when the cells were switched back to 37 deg. C. The protective effects of hypothermia were also demonstrated when apoptotic endpoints were examined. The HD concentration-dependent induction of fragmented DNA (as quantitated using soluble DNA and the TUNEL reaction), morphology, and p53 expression were all significantly depressed when cell cultures were incubated at 25 deg. C compared to 37 deg. C. When animals were exposed to HD vapour for 2, 4, and 6 min and left at room temperature, lesions were produced whose severity was dependent on exposure time and that were maximal by 72 h posttreatment. Moderate cooling (5-10 deg. C) of HD exposure sites posttreatment (4-6 h) significantly reduced the severity of the resultant lesions. However, in contrast to the in vitro results, these effects were permanent. It appears that the early and noninvasive act of cooling HD-exposed skin may provide a facile means of reducing the severity of HD-induced cutaneous lesions

  6. Sulphur in the metal poor globular cluster NGC 6397

    Science.gov (United States)

    Koch, A.; Caffau, E.

    2011-10-01

    Sulphur (S) is a non-refractory α-element that is not locked into dust grains in the interstellar medium. Thus no correction to the measured, interstellar sulphur abundance is needed and it can be readily compared to the S content in stellar photospheres. Here we present the first measurement of sulphur in the metal poor globular cluster (GC) NGC 6397, as detected in a MIKE/Magellan high signal-to-noise, high-resolution spectrum of one red giant star. While abundance ratios of sulphur are available for a larger number of Galactic stars down to an [Fe/H] of ~ -3.5 dex, no measurements in globular clusters more metal poor than -1.5 dex have been reported so far. We find aNLTE, 3-D abundance ratio of [S/Fe] = +0.52 ± 0.20 (stat.) ± 0.08 (sys.), based on theS I, Multiplet 1 line at 9212.8 Å. This value is consistent with a Galactic halo plateau as typical of other α-elements in GCs and field stars, but we cannot rule out its membership with a second branch of increasing [S/Fe] with decreasing [Fe/H], claimed in the literature, which leads to a large scatter at metallicities around - 2 dex. The [S/Mg] and [S/Ca] ratios in this star are compatible with a Solar value to within the (large) uncertainties. Despite the very large scatter in these ratios across Galactic stars between literature samples, this indicates that sulphur traces the chemical imprints of the other α-elements in metal poor GCs. Combined with its moderate sodium abundance ([S/Na]NLTE = 0.48), the [S/Fe] ratio in this GC extends a global, positive S-Na correlation that is not seen in field stars and might indicate that proton-capture reactions contributed to the production of sulphur in the (metal poor) early GC environments. This paper includes data gathered with the 6.5 m Magellan Telescopes located at Las Campanas Observatory, Chile.

  7. Comprehensive Technical Support for High-Quality Anthracite Production: A Case Study in the Xinqiao Coal Mine, Yongxia Mining Area, China

    Directory of Open Access Journals (Sweden)

    Wei Zhang

    2015-12-01

    Full Text Available The effective production of high-quality anthracite has attracted increasing global attention. Based on the coal occurrence in Yongxia Mining Area and mining conditions of a coalface in Xinqiao Coal Mine, we proposed a systematic study on the technical support for the production of high-quality anthracite. Six key steps were explored, including coal falling at the coalface, transport, underground bunker storage, main shaft hoisting, coal preparation on the ground, and railway wagon loading. The study resulted in optimized running parameters for the shearers, and the rotating patterns of the shearer drums was altered (one-way cutting was employed. Mining height and roof supporting intensity were reduced. Besides, loose presplitting millisecond blasting and mechanized mining were applied to upgrade the coal quantity and the lump coal production rate. Additionally, the coalface end transloading, coalface crush, transport systems, underground storage, and main shaft skip unloading processes were improved, and fragmentation-prevention techniques were used in the washing and railway wagon loading processes. As a result, the lump coal production rate was maintained at a high level and fragmentation was significantly reduced. Because of using the parameters and techniques determined in this research, high-quality coal production and increased profits were achieved. The research results could provide theoretical guidance and methodology for other anthracite production bases.

  8. Methanol from coal without CO2 production via the modular high temperature gas-cooled reactor

    International Nuclear Information System (INIS)

    Schleicher, R.W. Jr.; Engler, D.; Labar, M.P.

    1992-01-01

    Displacement options for petroleum fuels include natural gas (compressed or liquified), synthetic gasoline, biomass fuels, electric vehicles, hydrogen, and methanol. This paper reports that although no alternative meets all the desired characteristics of economics, environmental impact, supply logistics, and vehicle technology, methanol has often been cited as a good compromise and is perhaps the best coal derived fuel. The main criticism leveled at methanol is whether it can be produced economically in sufficient quantities to significantly displace petroleum-derived fuels. Although methanol can be manufactured from biomass, natural gas or coal feedstocks, only coal offers the potential for a substantial long term indigenous U.S. feedstock

  9. Fluidised bed gasification of high-ash South African coals: An experimental and modelling study

    CSIR Research Space (South Africa)

    Engelbrecht, AS

    2011-11-01

    Full Text Available model (CeSFaMB). The predictive capability of the model was analysed in terms of the degree of variation between experimental and simulated results for each test. The calibrated model was used to design a 15 MW fluidised bed coal gasifier...-scale BFBG are given in Figure 1 and Table 1. Process description Coal, air, oxygen and steam are the input streams to the process which produce the output streams: gas and char (ash). Coal is fed to the gasifier by means of a screw conveyor at a...

  10. Cardiovascular effects in rats following exposure to a high-boiling coal liquid.

    Science.gov (United States)

    Zangar, R C; Sasser, L B; Mahlum, D D; Abhold, R H; Springer, D L

    1987-11-01

    In previous work, increased blood pressure was observed in anesthetized rats following a subchronic aerosol exposure to solvent-refined coal heavy distillate (HD). To determine if this increase is a permanent, dose-related response, 11-week-old male rats were exposed by inhalation to 0, 0.24, or 0.70 mg/liter (control, low-exposure, and high-exposure groups, respectively) of HD for 6 hr/day, 5 days/week, for 6 weeks. In addition to blood pressure, select cardiovascular parameters were measured to obtain information on other possible toxic effects of the HD and also to gain some insight into potentially altered regulatory mechanisms that could be affecting the blood pressure. The angiotensin-aldosterone hormonal system, body fluid regulation, cardiac function and regulation, and pulmonary gas-exchange capabilities were examined. Two weeks after the end of exposure, mean blood pressures and heart rates of anesthetized animals in the low-and high-exposure groups were elevated relative to the controls. Plasma angiotensin concentrations decreased with increasing dose, whereas aldosterone concentrations were unaffected. In the high-dose group, blood and plasma volumes were 20 and 28%, respectively, higher than those of controls. Seven weeks after exposure, all measured cardiovascular parameters were similar to control values. Results from this study show that a 6-week exposure to HD resulted in dose-dependent, transient changes in a variety of physiological factors considered important in cardiovascular function.

  11. Polioencephalomalacia in ruminants caused by excessive amount of sulphur - a review

    Directory of Open Access Journals (Sweden)

    Lutnicki Krzysztof

    2014-06-01

    Full Text Available Polioencephalomalacia as a result of sulphur excess is a growing problem in cattle and sheep, mainly in young, growing animals. It is common in different regions of the world. The disease develops favoured by certain conditions such as sustained provision of feed and water with high sulphur content, use of dietary supplements containing sulphur, and a habitat with high hydrogen sulphide concentration. Pathogenesis of the disease is complex, but very important are oxidative-antioxidative imbalance, dysfunction of vessels, and secondary cerebral cortex ischaemia as a result of direct and/or indirect action of sulphur metabolites, namely hydrogen sulphide, sulphides, and sulphites. Clinical signs and changes in the cerebral cortex in the form of degenerative necrotic lesions are similar to those observed in polioencephalomalacia caused by vitamin B1 deficiency, and lead and salt intoxication. Highly increased sulphur content (more than 0.3-0.4 of dry matter in the diet is the basis for differential diagnosis, as well the high concentration of hydrogen sulphide in gas and sulphides in rumen fluid. In prophylaxis and treatment the most important measure is to limit sulphur intake and in acute cases to neutralise low pH in rumen and administer vitamin B1 injections.

  12. Use of high-temperature, high-torque rheometry to study the viscoelastic properties of coal during carbonization

    Energy Technology Data Exchange (ETDEWEB)

    Diaz, M.C.; Duffy, J.J.; Snape, C.E.; Steel, K.M. [University of Nottingham, Nottingham (United Kingdom)

    2007-09-15

    When coal is heated in the absence of oxygen it softens at approximately 400 degrees C, becomes viscoelastic, and volatiles are driven off. With further heating, the viscous mass reaches a minimum viscosity in the range of 10{sup 3}-10{sup 5} Pa s and then begins to resolidify. A high-torque, high-temperature, controlled-strain rheometer with parallel plates has been used to study the theology during this process. Under shear, the viscosity of the softening mass decreases with increasing shear rate. During resolidification, the viscosity increases as C-C bond formation and physical interactions gives rise to an aromatic network, but, under shear, the network breaks apart and flows. This is viewed as a yielding of the structure. The higher the shear rate, the earlier the yielding occurs, such that if the shear rate is low enough, the structure is able to build. Also, further into resolidification lower shear rates are able to break the structure. It is proposed that resolidification occurs through the formation of aromatic clusters that grow and become crosslinked by non-covalent interactions. As the clusters grow, the amount of liquid surrounding them decreases and it is thought that the non-covalent interactions between clusters and liquid could decrease and the ability of growing clusters to move past each other increases, which would explain the weakening of the structure under shear. This work is part of a program of work aimed at attaining a greater understanding of microstructural changes taking place during carbonization for different coals, in order to understand the mechanisms that give rise to good quality cokes and coke oven problems such as excessive wall pressure.

  13. Nanometre-sized pores in coal: Variations between coal basins and coal origin

    Science.gov (United States)

    Sakurovs, Richard; Koval, Lukas; Grigore, Mihaela; Sokolava, Anna; Ruppert, Leslie F.; Melnichenko, Yuri B.

    2018-01-01

    We have used small angle neutron scattering (SANS) to investigate the differences in methane and hexane penetration in pores in bituminous coal samples from the U.S., Canada, South Africa, and China, and maceral concentrates from Australian coals. This work is an extension of previous work that showed consistent differences between the extent of penetration by methane into 10–20 nm size pores in inertinite in bituminous coals from Australia, North America and Poland.In this study we have confirmed that there are differences in the response of inertinite to methane and hexane penetration in coals sourced from different coal basins. Inertinite in Permian Australian coals generally has relatively high numbers of pores in the 2.5–250 nm size range and the pores are highly penetrable by methane and hexane; coals sourced from Western Canada had similar penetrability to these Australian coals. However, the penetrability of methane and hexane into inertinite from the Australian Illawarra Coal Measures (also Permian) is substantially less than that of the other Australian coals; there are about 80% fewer 12 nm pores in Illawarra inertinite compared to the other Australian coals examined. The inertinite in coals sourced from South Africa and China had accessibility intermediate between the Illawarra coals and the other Australian coals.The extent of hexane penetration was 10–20% less than CD4 penetration into the same coal and this difference was most pronounced in the 5–50 nm pore size range. Hexane and methane penetrability into the coals showed similar trends with inertinite content.The observed variations in inertinite porosity between coals from different coal regions and coal basins may explain why previous studies differ in their observations of the relationships between gas sorption behavior, permeability, porosity, and maceral composition. These variations are not simply a demarcation between Northern and Southern Hemisphere coals.

  14. Early diagenetic high-magnesium calcite and dolomite indicate that coal balls formed in marine or brackish water: Stratigraphic and paleoclimatic implications

    Science.gov (United States)

    Raymond, Anne

    2016-04-01

    Coal balls are carbonate and pyrite permineralizations of peat that contain three-dimensional plant fossils preserved at the cellular level. Coal balls, which occur in Pennsylvanian and earliest Permian equatorial coals, provide a detailed record of terrestrial ecology and tropical climate during the Late Paleozoic Ice Age; yet their depositional environment remains controversial. The exquisite preservation of some coal-ball fossils, e.g. pollen with pollen tubes and leaves with mesophyll, indicates rapid formation. The presence of abundant, cement-filled, void spaces within and between the plant debris in most coal balls indicates that they formed in uncompacted peat, near the surface of the mire. Botanical, taphonomic and isotopic evidence point to a freshwater origin for coal balls. The nearest living relatives of coal ball plants (modern lycopsids, sphenopsids, marratialean ferns and conifers) grow in fresh water. Coal-ball peat contains a high percentage of aerial debris, similar to modern freshwater peat. The stable oxygen isotopes of coal-ball carbonate (δ18O = 16 to 3 per mil) suggest a freshwater origin. However, the widespread occurrence of marine invertebrates and early diagenetic framboidal pyrite in coal balls suggests that many formed in close proximity to marine water. Indeed, carbonate petrology points to a marine or brackish water origin for the first-formed carbonate cements in coal balls. Petrographic and geochemical (microprobe) analysis of coal-ball carbonates in Pennsylvanian coals from the midcontinent of North America (Western Interior Basin, West Pangaea) and the Ruhr and Donets Basins (East Pangaea) indicate that the first formed carbonate is either radaxial, nonstochiometric dolomite or high magnesium calcite (9 - 17 mol % MgCO3, indicating precipitation in marine or brackish water. Although both primary dolomite and high magnesium calcite can form in lacustrine settings, the lakes in which these minerals form occur in carbonate terranes

  15. Innovative clean coal technology (ICCT): demonstration of selective catalytic reduction (SCR) technology for the control of nitrogen oxide (NOx) emission from high-sulfur, coal-fired boilers - economic evaluation of commercial-scale SCR applications for utility boilers

    International Nuclear Information System (INIS)

    Healy, E.C.; Maxwell, J.D.; Hinton, W.S.

    1996-09-01

    This report presents the results of an economic evaluation produced as part of the Innovative Clean Coal Technology project, which demonstrated selective catalytic reduction (SCR) technology for reduction of NO x emissions from utility boilers burning U.S. high-sulfur coal. The document includes a commercial-scale capital and O ampersand M cost evaluation of SCR technology applied to a new facility, coal-fired boiler utilizing high-sulfur U.S. coal. The base case presented herein determines the total capital requirement, fixed and variable operating costs, and levelized costs for a new 250-MW pulverized coal utility boiler operating with a 60-percent NO x removal. Sensitivity evaluations are included to demonstrate the variation in cost due to changes in process variables and assumptions. This report also presents the results of a study completed by SCS to determine the cost and technical feasibility of retrofitting SCR technology to selected coal-fired generating units within the Southern electric system

  16. Engineering development of coal-fired high-performance power systems

    International Nuclear Information System (INIS)

    1998-01-01

    A High Performance Power System (HIPPS) is being developed. This system is a coal-fired, combined cycle plant with indirect heating of gas turbine air. Foster Wheeler Development Corporation and a team consisting of Foster Wheeler Energy Corporation, Bechtel Corporation, University of Tennessee Space Institute and Westinghouse Electric Corporation are developing this system. In Phase 1 of the project, a conceptual design of a commercial plant was developed. Technical and economic analyses indicated that the plant would meet the goals of the project which include a 47 percent efficiency (HHV) and a 10 percent lower cost of electricity than an equivalent size PC plant. The concept uses a pyrolyzation process to convert coal into fuel gas and char. The char is fired in a High Temperature Advanced Furnace (HITAF). The HITAF is a pulverized fuel-fired boiler/air heater where steam is generated and gas turbine air is indirectly heated. The fuel gas generated in the pyrolyzer is then used to heat the gas turbine air further before it enters the gas turbine. The project is currently in Phase 2, which includes engineering analysis, laboratory testing and pilot plant testing. Research and development is being done on the HIPPS systems that are not commercial or being developed on other projects. Pilot plant testing of the pyrolyzer subsystem and the char combustion subsystem are being done separately, and after each experimental program has been completed, a larger scale pyrolyzer will be tested at the Power Systems Development Facility (PSDF) in Wilsonville, Al. The facility is equipped with a gas turbine and a topping combustor, and as such, will provide an opportunity to evaluate integrated pyrolyzer and turbine operation. During this quarter, initial char combustion tests were performed at the CETF using a Foster Wheeler commercial burner. These preliminary tests were encouraging and will be used to support the development of an innovative char burner for the HIPPS

  17. Red soil as a regenerable sorbent for high temperature removal of hydrogen sulfide from coal gas

    International Nuclear Information System (INIS)

    Ko, T.-H.; Chu Hsin; Lin, H.-P.; Peng, C.-Y.

    2006-01-01

    In this study, hydrogen sulfide (H 2 S) was removed from coal gas by red soil under high temperature in a fixed-bed reactor. Red soil powders were collected from the northern, center and southern of Taiwan. They were characterized by XRPD, porosity analysis and DCB chemical analysis. Results show that the greater sulfur content of LP red soils is attributed to the higher free iron oxides and suitable sulfidation temperature is around 773 K. High temperature has a negative effect for use red soil as a desulfurization sorbent due to thermodynamic limitation in a reduction atmosphere. During 10 cycles of regeneration, after the first cycle the red soil remained stable with a breakthrough time between 31 and 36 min. Hydrogen adversely affects sulfidation reaction, whereas CO exhibits a positive effect due to a water-shift reaction. COS was formed during the sulfidation stage and this was attributed to the reaction of H 2 S and CO. Results of XRPD indicated that, hematite is the dominant active species in fresh red soil and iron sulfide (FeS) is a product of the reaction between hematite and hydrogen sulfide in red soils. The spinel phase FeAl 2 O 4 was found during regeneration, moreover, the amount of free iron oxides decreased after regeneration indicating the some of the free iron oxide formed a spinel phase, further reducting the overall desulfurization efficiency

  18. Effect of heat reflux extraction on the structure and composition of a high-volatile bituminous coal

    International Nuclear Information System (INIS)

    Tian, Bin; Qiao, Ying-yun; Tian, Yuan-yu; Xie, Ke-chang; Li, Da-wei

    2016-01-01

    Highlights: • A novel HRE process with CYC is proposed to dissolve coal. • Most of the aliphatic compounds in coal are extracted during HRE process. • The carbon crystallite structure of coal changes after HRE process with CYC. • The thermal degradation behavior of ER is significantly different from that of the SFHB. - Abstract: Heat reflux extraction (HRE) process with cyclohexanone (CYC) in a high-performance mass transfer extractor was applied to dissolve Shenmu-Fugu high-volatile bituminous (SFHB) coal for the first time to afford extract (E) and extract residue (ER) from the extraction. SFHB, E, and ER were characterized by elemental analysis, solid-state "1"3C NMR spectrometry, FTIR spectrometry, XRD, SEM, and TG-FTIR to elucidate the effect of HRE on the evolution of functional groups and macromolecular structure of coal during extraction. The soluble portion in SFHB was 24.37% in the course of HRE with CYC. The aromaticity of SFHB derived from both curve-fitting of "1"3C NMR and FTIR spectra was obviously increased after extraction suggesting that most of the aliphatic fractions were extracted during HRE process. It was clarified that the substituted degree of aromatic ring in SFHB became low but the substituents on aromatics were larger after extraction. Due to irreversibly swelling crystal structure of SFHB, its interlayer spacing became larger and the stacking height of crystallite decreased after extraction. Moreover, significant amounts of volatile matters were extracted, which caused relatively lower mass loss rate and contents of gaseous products (CO_2, aliphatic moieties, CH_4, and CO) of ER than SFHB during main pyrolysis stage.

  19. Sulphur uptake and yield of soybean as influenced by sulphur fertilization

    International Nuclear Information System (INIS)

    Shamima, N.; Farid, A. T. M.

    2005-01-01

    Effect of sulphur fertilization (0, 20, 40, 60 and 80 kg/ha) on sulphur uptake and seed yield was studied in sohag and Bangladesh soybean-4 varieties in the field of Bangladesh Agricultural Research Institute, Gazipur during the winter (rabi) seasons of 2000-2001 and 2001-2002 in grey Terrace soil (Albaquept). Addition of slphur fertilizer exerted significant influence on the yield attributes of soybean varieties. Sulphur uptake also significantly responded to the application of sulphur fertilizer. Variety Bangladesh soybean-4 was found superior to sohag in respect of sulphur uptake and yield. Greater sulphur utilization was observed at lower levels of fertilizer application. Seed yield and sulphur uptake were increased with the application of 40 kg/ ha for sohag and 60 kg/ha for Bangladesh soybean-4. Response of seed yield to added sulphur was quadratic. The economic optimum doses were found to be 49 kg s/ha for sohag and 52 kg s/ha for Bangladesh soybean-4, yielding 2060 and 2354 kg/ha, respectively. (author)

  20. Effects of sulphuric acid pollution on the biology of streams in the Transvaal, South Africa

    Energy Technology Data Exchange (ETDEWEB)

    Harrison, A D

    1958-01-01

    Strongly acid effluents or drainage waters are produced during gold and coal mining activities in the Transvaal. Sulphuric acid is produced during oxidation of pyrites exposed by mining operations and much of it finds its way into streams and creates serious pollution problems. The object of this paper is to give a short account of the effects of this acid pollution on the biology of these streams. The first streams considered are the Klip and Klipspruit near their confluence at Olifantsvlei, near Johannesburg. These were studied during a two-year investigation of the area. Both receive acid pollution from gold mine dumps and slimes dams, the seepages from which have pH values as low as 2.3. Both streams run over dolomite formations so the acid is gradually neutralised but highly mineralised, permanently hard water results. The Klip and the Klipspruit join in the middle of a y-shaped, swampy area, each stream coming down one of the upper arms of the y. A sampling station was set up on each where it runs slowly through the swamp just before confluence.

  1. Sulphur bacteria mediated formation of Palaeoproterozoic phosphorites

    Science.gov (United States)

    Joosu, Lauri; Lepland, Aivo; Kirsimäe, Kalle

    2014-05-01

    Modern phosphorite formation is typically associated with high productivity in upwelling areas where apatite (Ca-phosphate) precipitation is mediated by sulphur oxidising bacteria [1]. They inhabit the oxic/anoxic interface within the upper few centimetres of sediment column, accumulating phosphate in their cells under oxic conditions and releasing it rapidly when conditions become anoxic. Sulphur bacteria are known to live in close association with a consortium of anaerobic methane oxidising archaea and syntrophic sulphate-reducing bacteria. Paleoproterozoic, c. 2.0 Ga Zaonega Formation in Karelia, Russia contains several P-rich intervals in the upper part of 1500 m thick succession of organic-rich sedimentary rocks interlayered with mafic tuffs and lavas. Apatite in these P-rich intervals forms impure laminae, lenses and round-oval nodules which diameters typically range from 300 to 1000 μm. Individual apatite particles in P-rich laminae and nodules commonly occur as cylinders that are 1-8 μm long and have diameters of 0.5-4 μm. Cross-sections of best preserved cylindrical apatite particles reveal a thin outer rim whereas the internal parts consist of small anhedral elongated crystallites, intergrown with carbonaceous material. During recrystallization the outer rim thickens towards interior and cylinders may attain hexagonal crystal habit, but their size and shape remains largely unchanged [2]. The sizes of Zaonega nodules are similar to giant sulphide-oxidising bacteria known from modern and ancient settings [3, 4]. Individual apatite cylinders and aggregates have shapes and sizes similar to the methanotrophic archaea that inhabit microbial mats in modern seep/vent areas where they operate in close associations with sulphur-oxidising microbial communities [5]. Seep/vent influence during the Zaonega phosphogenesis is indicated by variable, though positive Eu anomaly, expected in magmatically active sedimentary environment experiencing several lava flows

  2. Clean coal technologies

    International Nuclear Information System (INIS)

    Aslanyan, G.S.

    1993-01-01

    According to the World Energy Council (WEC), at the beginning of the next century three main energy sources - coal, nuclear power and oil will have equal share in the world's total energy supply. This forecast is also valid for the USSR which possesses more than 40% of the world's coal resources and continuously increases its coal production (more than 700 million tons of coal are processed annually in the USSR). The stringent environmental regulations, coupled with the tendency to increase the use of coal are the reasons for developing different concepts for clean coal utilization. In this paper, the potential efficiency and environmental performance of different clean coal production cycles are considered, including technologies for coal clean-up at the pre-combustion stage, advanced clean combustion methods and flue gas cleaning systems. Integrated systems, such as combined gas-steam cycle and the pressurized fluidized bed boiler combined cycle, are also discussed. The Soviet National R and D program is studying new methods for coal utilization with high environmental performance. In this context, some basic research activities in the field of clean coal technology in the USSR are considered. Development of an efficient vortex combustor, a pressurized fluidized bed gasifier, advanced gas cleaning methods based on E-beam irradiation and plasma discharge, as well as new catalytic system, are are presented. In addition, implementation of technological innovations for retrofitting and re powering of existing power plants is discussed. (author)

  3. Coal-fired high performance power generating system. Quarterly progress report, July 1, 1993--September 30, 1993

    Energy Technology Data Exchange (ETDEWEB)

    1993-12-31

    This report covers work carried out under Task 3, Preliminary Research and Development, and Task 4, Commercial Generating Plant Design, under contract DE-AC22-92PC91155, {open_quotes}Engineering Development of a Coal Fired High Performance Power Generation System{close_quotes} between DOE Pittsburgh Energy Technology Center and United Technologies Research Center. The goals of the program are to develop a coal-fired high performance power generation system (HIPPS) by the year 2000 that is capable of >47% thermal efficiency; NO{sub x}, SO{sub x}, and particulates {le} 25% NSPS; cost {ge} 65% of heat input; and all solid wastes benign. The report discusses progress in cycle analysis, chemical reactor modeling, ash deposition rate calculations for HITAF (high temperature advanced furnace) convective air heater, air heater materials, and deposit initiation and growth on ceramic substrates.

  4. FY1995 development of economical and high efficient desulfurization process using low rank coal; 1995 nendo teitankadotan wo mochiita ankana kokoritsu datsuryuho no kaihatsu

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1997-03-01

    The objective of this study is to develop a new efficient desulfurization technique using a Ca ion-exchanged coal prepared from low rank coal and calcium raw material as a SO{sub 2} sorbent. Ion-exchange of calcium was carried out by soaking and mixing brown coal particles in milk of lime or slurry of industrial waste from concrete manufacture process. About 10wt% of Ca was easily incorporated into Yallourn coal. The ion-exchanged Ca was transformed to ultra-fine CaO particles upon pyrolysis of coal. The reactivity of CaO produced from Ca-exchanged coal to SO{sub 2} was extraordinary high and the CaO utilization of above 90% was easily achieved, while the conversion of natural limestone was less than 30% under the similar experimental conditions. High activity of Ca-exchanged coal was appreciably observed in a pressurized fluidized bed combustor. Ca-exchanged coal was quite effective for the removal of hydrogen sulfide. (NEDO)

  5. Innovative Clean Coal Technology (ICCT): Demonstration of selective catalytic reduction (SCR) technology for the control of nitrogen oxide (NO{sub x}) emissions from high-sulfur coal-fired boilers. Technical progress report, third and fourth quarters 1994

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1995-11-01

    The objective of this project is to demonstrate and evaluate commercially available selective catalytic reduction (SCR) catalysts from U.S., Japanese, and European catalyst suppliers on a high-sulfur U.S. Coal-fired boiler. SCR is a post-combustion nitrogen oxide (NO{sub x}) control technology that involves injecting ammonia into the flue gas generated from coal combustion in an electric utility boiler. The flue gas containing ammonia is then passed through a reactor that contains a specialized catalyst. In the presence of the catalyst, the ammonia reacts with NO{sub x} to form nitrogen and water vapor. Although SCR is widely practiced in Japan and European gas-, oil-, and low-sulfur coal-fired boilers, there are several technical uncertainties associated with applying SCR to U.S. coals. These uncertainties include: (1) potential catalyst deactivation due to poisoning by trace metal species present in U.S. coals that are not present in other fuels; (2) performance of the technology and effects on the balance-of-plant equipment in the presence of high amounts of SO{sub 2} and SO{sub 3}; performance of a wide variety of SCR catalyst compositions, geometries, and methods of manufacture under typical high-sulfur coal-fired utility operating conditions. These uncertainties are being explored by operating a series of small- scale SCR reactors and simultaneously exposing different SCR catalysts to flue gas derived from the combustion of high sulfur U.S. coal. The demonstration is being performed at Gulf Power Company`s Plant Crist Unit No. 5 (75 MW capacity) near Pensacola, Florida. The project is funded by the U.S. Department of Energy (DOE), Southern Company Services, Inc. (SCS on behalf of the entire Southern electric system), the Electric Power Research Institute (EPRI), and Ontario Hydro. SCS is the participant responsible for managing al aspects of this project. 1 ref., 69 figs., 45 tabs.

  6. Power generation from lignite coal in Bulgaria - problems and solutions

    International Nuclear Information System (INIS)

    Batov, S.; Gadjanov, P.; Panchev, T.

    1997-01-01

    The bulk of lignite coal produced in Bulgaria is used as fuel for the thermal power plants (TPP) built in Maritsa East coal field. A small part of it goes to production of briquettes and to fuel the auxiliary power plants of industrial enterprises. The total installed capacity of the power plants in the region of Maritsa East is 2490 MW, and the electric power generated by them is about 30% of the total power generated in the country. It should be noted that these power plants were subjected to a number of rehabilitations aiming to improve their technical and economic parameters. Irrespective of that, however, solution has still to be sought to a number of problems related to utilisation of the low-grade lignite coal for power generation. On the whole, they can be divided in the following groups: Those related to lignite coal mining can be referred to the first group. Lignite coal is mined in comparatively complicated mining and geological conditions characterized mainly by earth creep and deformation. The second group of problems is related to coal quality control. It is a fact of major significance that the quality indices of coal keep changing all the time in uneven steps without any definite laws to govern it. That creates hard problems in the process of coal transportation, crushing and combustion. The next group of problems concerns operation and upgrading of the power generation equipment. That applies especially to the existing boilers which bum low-grade fuel in order to improve their operation in terms of higher thermal efficiency, controllability, reliability, improved environmental indices, etc. An increasingly high importance is attached to environmental impact problems incident to lignite coal utilisation. Abatement of sulphur oxide emissions and dust pollution is a problem solution of which cannot wait. The possibilities for partial solution of the environmental problems through increasing the thermal efficiency of facilities at the thermal Power

  7. Up the stack : coal-fired electricity's toxic impact : an OCAA air quality report

    International Nuclear Information System (INIS)

    Rang, S.

    2002-07-01

    Ontario Power Generation (OPG) must report annually its releases and transfers of 268 chemicals to the federal National Pollutant Release Inventory (NPRI). Each OPG facility reports the amount of chemicals released to the air, land, water and injected under ground at the facility site. The facilities must also report the amount of chemicals that are transferred off-site for treatment, sewage, disposal, recycling or energy recovery. In 1999 and 2000, atmospheric releases from OPG's coal-fired plants accounted for a significant percentage of the total pollutants released for Ontario and Canada. OPG's facilities are often in the top 5 in Ontario and Canada for releases of various chemicals, including persistent toxic chemicals. In 1999, the Nanticoke coal-fired power plant on Lake Erie was ranked first in Canada for releases to the air. Data reported for the 1999 and 2000 reporting period for dioxins and furans, hexachlorobenzene, mercury, metals (chromium, nickel and arsenic), and acid gases such as hydrochloric acid, hydrogen fluoride, and sulphuric acid clearly indicates that OPG coal-fired plants are a leading source of air pollution in Canada and Ontario. The Ontario Clean Air Alliance suggests the data is sufficient to phase-out the use of coal for power generation in Ontario. It recommends conserving energy and replacing coal-fired power with renewable energy sources such as wind and water power. Converting coal facilities to high-efficiency natural gas units would also reduce the toxic impacts of OPG's coal-fired power plants. As an immediate first step, it was recommended that the government should ban non-emergency exports of coal-fired electricity during smog-alert periods in Ontario. 11 tabs

  8. The future of coal-fired generation

    Energy Technology Data Exchange (ETDEWEB)

    White, G. [Sherritt International Corp., Calgary, AB (Canada)

    2004-07-01

    The 3 features that will ensure coal's place as a primary energy source are its affordability, availability and its abundance. Coal reserves represent more than 200 years of supply. Graphs depicting coal consumption in North America, Central and South America, Western Europe, Easter Europe, Middle East, Africa, and Asia show that coal use is expected to grow 1.5 per cent annually. Asia is the greatest consumer of coal, while the consumption of coal in Eastern Europe is steadily declining. About half of the electricity supply in the United States will continue to be generated by coal and non-electrical utilization is also expected to grow. Emerging technologies that are promoting efficiency of coal utilization include combustion technology, clean coal technology, conversion technology and emissions technology. These technologies also address environmental concerns regarding coal combustion, such as removal of carbon dioxide through sequestration and reduction in nitrogen oxides, sulphur dioxide and particulates. Mercury mitigation technologies are also being developed. It was noted that the use of coal is mitigated by other available supply such as nuclear, natural gas and hydro which provide the base load generation. Renewable energy supply can meet up to 20 per cent of the base load, while coal can fill be gap between base load and peak loads. It was noted that the use of coal in direct industrial processes allows for synergies such as syngas for bitumen upgrading, coal as a chemical feedstock with electricity as a by-product, combined heat and power and cogeneration. tabs., figs.

  9. Advanced CSiC composites for high-temperature nuclear heat transport with helium, molten salts, and sulphur-iodine thermochemical hydrogen process fluids

    International Nuclear Information System (INIS)

    Peterson, P.F.; Forsberg, Ch.W.; Pickard, P.S.

    2004-01-01

    This paper discusses the use of liquid-silicon-impregnated (LSI) carbon-carbon composites for the development of compact and inexpensive heat exchangers, piping, vessels and pumps capable of operating in the temperature range of 800 to 1 100 deg C with high-pressure helium, molten fluoride salts, and process fluids for sulfur-iodine thermochemical hydrogen production. LSI composites have several potentially attractive features, including ability to maintain nearly full mechanical strength to temperatures approaching 1 400 deg C, inexpensive and commercially available fabrication materials, and the capability for simple forming, machining and joining of carbon-carbon performs, which permits the fabrication of highly complex component geometries. In the near term, these materials may prove to be attractive for use with a molten-salt intermediate loop for the demonstration of hydrogen production with a gas-cooled high temperature reactor. In the longer term, these materials could be attractive for use with the molten-salt cooled advanced high temperature reactor, molten salt reactors, and fusion power plants. (author)

  10. New coal

    Energy Technology Data Exchange (ETDEWEB)

    1979-07-01

    Specially dedicated to coal, this edition comprises a series of articles of general interest dealing with the position of the French coalmining industry (interview with M.P. Gardent), the coal market in France, the work of CERCHAR, etc. New techniques, in-situ gasification of deep coal, gasification of coal by nuclear methods, the conversion of coal into petrol, the Emile Huchet power plant of Houilleres du Bassin de Lorraine, etc., are dealt with.

  11. Coal upgrading

    Energy Technology Data Exchange (ETDEWEB)

    Nunes, S. [IEA Clean Coal Centre, London (United Kingdom)

    2009-10-15

    This report examines current technologies and those likely to be used to produce cleaner coal and coal products, principally for use in power generation and metallurgical applications. Consideration is also given to coal production in the leading coal producing countries, both with developed and developing industries. A range of technologies are considered. These include the coal-based liquid fuel called coal water mixture (CWM) that may compete with diesel, the production of ultra-clean coal (UCC) and coal liquefaction which competes with oil and its products. Technologies for upgrading coal are considered, especially for low rank coals (LRC), since these have the potential to fill the gap generated by the increasing demand for coal that cannot be met by higher quality coals. Potential advantages and downsides of coal upgrading are outlined. Taking into account the environmental benefits of reduced pollution achieved through cleaner coal and reduced transport costs, as well as other positive aspects such as a predictable product leading to better boiler design, the advantages appear to be significant. The drying of low rank coals improves the energy productively released during combustion and may also be used as an adjunct or as part of other coal processing procedures. Coal washing technologies vary in different countries and the implications of this are outlined. Dry separation technologies, such as dry jigging and electrostatic separation, are also described. The demonstration of new technologies is key to their further development and demonstrations of various clean coal technologies are considered. A number of approaches to briquetting and pelletising are available and their use varies from country to country. Finally, developments in upgrading low rank coals are described in the leading coal producing countries. This is an area that is developing rapidly and in which there are significant corporate and state players. 81 refs., 32 figs., 3 tabs.

  12. A preliminary high-pressure thermogravimetric study of combustion reactivity of a Collie coal char

    Energy Technology Data Exchange (ETDEWEB)

    Chan, Yii Leng; Zhang, Zhezi; Zhu, Mingming; Zhang, Dongke [Western Australia Univ., Crawley, WA (Australia). Centre for Energy (M473); Luan, Chao [Western Australia Univ., Crawley, WA (Australia). Centre for Energy (M473); Tsinghua Univ., Beijing (China). Inst. of Thermal Engineering; You, Changfu [Tsinghua Univ., Beijing (China). Inst. of Thermal Engineering

    2013-07-01

    The effect of pressure(up to 20 bar)on the reactivity of a char(150-160 {mu}m) produced from Western Australian Collie coal has been studied using a high-pressure thermogravimetric analyser (HP TGA). The pressure demonstrated a positive effect in enhancing char combustion reactivities.Kinetic parameters have been determined from the experimental data.The apparent reaction order was found to be approximately 0.7 and the apparent activation energies were 91.0 kJ/mol at atmospheric pressure and 1.5 kJ/mol at an elevated pressure(10 bar),indicating a shift in the control regimes of the reaction at elevated pressures.The lumped effect of the sample size, bulk diffusion,interparticle and intraparticle diffusion at the elevated pressures played an important role in reducing the mass transfer during the HP-TGA experimentation.Thus the activation energy calculated at elevated pressures may not represent the intrinsic activation energy of the char particles but the apparent values of the bulk of the samples.

  13. Fluidized bed combustion of single coal char particles at high CO{sub 2} concentration

    Energy Technology Data Exchange (ETDEWEB)

    Scala, F.; Chirone, R. [CNR, Naples (Italy)

    2010-12-15

    Combustion of single coal char particles was studied at 850{sup o}C in a lab-scale fluidized bed at high CO{sub 2} concentration, typical of oxyfiring conditions. The burning rate of the particles was followed as a function of time by continuously measuring the outlet CO and O{sub 2} concentrations. Some preliminary evaluations on the significance of homogeneous CO oxidation in the reactor and of carbon gasification by CO{sub 2} in the char were also carried out. Results showed that the carbon burning rate increases with oxygen concentration and char particle size. The particle temperature is approximately equal to that of the bed up to an oxygen concentration of 2%, but it is considerably higher for larger oxygen concentrations. Both CO{sub 2} gasification of char and homogeneous CO oxidation are not negligible. The gasification reaction rate is slow and it is likely to be controlled by intrinsic kinetics. During purely gasification conditions the extent of carbon loss due to particle attrition by abrasion (estimated from the carbon mass balance) appears to be much more important than under combustion conditions.

  14. Application of coals as sorbents for the removal of Cr from aqueous waste streams

    Energy Technology Data Exchange (ETDEWEB)

    Lakatos, J.; Brown, S.D.; Snape, C.E. [University of Miskolc, Miskolc (Hungary). Dept. of Analytical Chemistry

    2001-09-01

    The study reported further understanding of how various electron transfer processes operate for Cr(VI) with a view to using coals for the removal of Cr(VI) from waste streams. Skye peat, Spanish and German lignites, UK high and low volatility bituminous coals and an activated carbon were used. After treatment to remove exchangeable cations, ion exchange experiments were conducted in 0.1 M acetic acid-sodium acetate (1:1) buffer and 0.05 M sulphuric acid solutions and the slurries were agitated once a day. The ion concentrations in the solutions were determined by flame atomic absorption spectroscopy. The Cr(VI) renaming in solution was determined by the standard calorimetric 1,5-diphenylcarbazide method. Peat and low rank (Spanish Mequinenza) coal exhibited a larger capacity for Cr(VI) removal than bituminous coal. Redox mechanisms are operative coupled with the oxidation of the coal and peat surfaces. Desorption of Cr(III) formed by reduction which occurs in strongly acidic media also needs to be considered. 1 ref., 3 figs.

  15. Cuttability of coal

    Energy Technology Data Exchange (ETDEWEB)

    Sikora, W

    1978-01-01

    The process of cutting dull M, dull bright MB, bright dull BM, and bright B coal under various compressive stress conditions was studied in laboratory tests. The efficiency of ploughs depends much more on the natural mining conditions than does that of shearer-loaders. For seams of medium workability, it is difficult to forecast whether ploughs will be successful. Cuttability tests are a good way of determining whether ploughs can be used. The effort necessary to cut coal in a stressed condition depends not only on such properties as the workability defined by the Protodyakonov index or compressive strength, but also, and mainly, on the petrographic structure and elastic properties of the coal. In bright coals with high elastic strain, and with BM and MB coals, a much greater increment of effort is necessary with increase in compressive stresses. The cuttability of dull coals from difficult mines was not very different.

  16. Recent Development of Carbonaceous Materials for Lithium–Sulphur Batteries

    Directory of Open Access Journals (Sweden)

    Xingxing Gu

    2016-11-01

    Full Text Available The effects of climate change are just beginning to be felt, and as such, society must work towards strategies of reducing humanity’s impact on the environment. Due to the fact that energy production is one of the primary contributors to greenhouse gas emissions, it is obvious that more environmentally friendly sources of power are required. Technologies such as solar and wind power are constantly being improved through research; however, as these technologies are often sporadic in their power generation, efforts must be made to establish ways to store this sustainable energy when conditions for generation are not ideal. Battery storage is one possible supplement to these renewable energy technologies; however, as current Li-ion technology is reaching its theoretical capacity, new battery technology must be investigated. Lithium–sulphur (Li–S batteries are receiving much attention as a potential replacement for Li-ion batteries due to their superior capacity, and also their abundant and environmentally benign active materials. In the spirit of environmental harm minimization, efforts have been made to use sustainable carbonaceous materials for applications as carbon–sulphur (C–S composite cathodes, carbon interlayers, and carbon-modified separators. This work reports on the various applications of carbonaceous materials applied to Li–S batteries, and provides perspectives for the future development of Li–S batteries with the aim of preparing a high energy density, environmentally friendly, and sustainable sulphur-based cathode with long cycle life.

  17. Distribution and mode of occurrence of selenium in US coals

    Science.gov (United States)

    Coleman, L.; Bragg, L.J.; Finkelman, R.B.

    1993-01-01

    Selenium excess and deficiency have been established as the cause of various health problems in man and animals. Combustion of fossil fuels, especially coal, may be a major source of the anthropogenic introduction of selenium in the environment. Coal is enriched in selenium relative to selenium's concentration in most other rocks and relative to selenium in the Earth's crust. Data from almost 9,000 coal samples have been used to determine the concentration and distribution of selenium in US coals. The geometric mean concentration of selenium in US coal is 1.7 ppm. The highest mean selenium value (geometric mean 4.7 ppm) is in the Texas Region. Atlantic Coast (Virginia and North Carolina) and Alaska coals have the lowest geometric means (0.2 and 0.42 ppm, respectively). All western coal regions have mean selenium concentrations of less than 2.0 ppm. In contrast, all coal basins east of the Rocky Mountains (except for several small basins in Rhode Island, Virginia, and North Carolina) have mean selenium values of 1.9 or greater. Generally, variations in selenium concentration do not correlate with variations in ash yield, pyritic sulphur, or organic sulphur concentrations. This may be the result of multiple sources of selenium; however, in some non-marine basins with restricted sources of selenium, selenium has positive correlations with other coal quality parameters. Selenium occurs in several forms in coal but appears to be chiefly associated with the organic fraction, probably substituting for organic sulphur. Other important forms of selenium in coal are selenium-bearing pyrite, selenium-bearing galena, and lead selenide (clausthalite). Water-soluble and ion-exchangeable selenium also have been reported. ?? 1993 Copyright Science and Technology Letters.

  18. Pyroclastic sulphur eruption at Poas Volcano, Costa Rica

    Energy Technology Data Exchange (ETDEWEB)

    Francis, P.W.; Thorpe, R.S.; Brown, G.C.; Glasscock, J.

    1980-01-01

    The recent Voyager missions to Jupiter have highlighted the role of sulphur in volcanic processes on io. Although fumarolic sulphur and SO/sub 2/ gas are almost universal in terrestrial active volcanoes, and rare instances of sulphur lava flows have been reported, sulphur in a pyroclastic form has only been described from Poas Volcano, Costa Rica. Here we amplify the original descriptions by Bennett and Raccichini and describe a recent eruption of pyroclastic sulphur scoria and ejected blocks that are characterised by miniature sulphur stalactites and stalagmites.

  19. Path dependence, fragmented property rights and the slow diffusion of high throughput technologies in inter-war British coal mining

    Energy Technology Data Exchange (ETDEWEB)

    Peter Scott

    2006-01-15

    This article examines the importance of path dependence effects in impeding the diffusion of high throughput mechanized mining systems in the British coal industry. It demonstrates that the industry had become 'locked in' to low throughput underground haulage technology, on account of institutional interrelatedness between Britain's traditional practice of extensive in-seam mining and its unique system of fragmented, privately owned mineral royalties. Fragmented royalties prevented the concentration of workings and introduction of high throughput main haulage systems that underpinned the rapid productivity growth of European producers. Meanwhile, technical interrelatedness between the haulage systems taking coal to the pit shaft and operations further 'upstream' created bottlenecks which both slowed the overall rate of mechanization and limited the productivity gains from the mechanization that did occur.

  20. Optimal coal import strategy

    International Nuclear Information System (INIS)

    Chen, C.Y.; Shih, L.H.

    1992-01-01

    Recently, the main power company in Taiwan has shifted the primary energy resource from oil to coal and tried to diversify the coal supply from various sources. The company wants to have the imported coal meet the environmental standards and operation requirements as well as to have high heating value. In order to achieve these objectives, establishment of a coal blending system for Taiwan is necessary. A mathematical model using mixed integer programming technique is used to model the import strategy and the blending system. 6 refs., 1 tab

  1. DEVELOPMENT OF DISPOSABLE SORBENTS FOR CHLORIDE REMOVAL FROM HIGH TEMPERATURE COAL-DERIVED GASES

    Energy Technology Data Exchange (ETDEWEB)

    Gopala Krishnan; Raghubir Gupta

    1999-09-01

    Advanced integrated-gasification combined-cycle (IGCC) and integrated-gasification fuel cell (IGFC) systems require the development of high temperature sorbents for the removal of hydrogen chloride (HCl) vapor to less than 1 parts-per-million (ppm) levels. HCl is a highly reactive, corrosive, and toxic gas which must be removed to meet environmental regulations, to protect power generation equipment, and to minimize deterioration of hot gas desulfurization sorbents. The objective of this program was to develop disposable, alkali-based sorbents capable of reducing HCl vapor levels to less than 1 ppm in the temperature range from 400 to 750 C and pressures in the range from 1 to 20 atm. The primary areas of focus of this program were to investigate different methods of sorbent fabrication, testing their suitability for different reactor configurations, obtaining reaction kinetics data, and conducting a preliminary economic feasibility assessment. This program was a joint effort between SRI International (SRI), Research Triangle Institute (RTI), and General Electric Corporate Research and Development (GE-CRD). SRI, the prime contractor and RTI, a major subcontractor, performed most of the work in this program. Thermochemical calculations indicated that sodium-based sorbents were capable of reducing HCl vapor levels to less than 1 ppm at temperatures up to 650 C, but the regeneration of spent sorbents would require complex process steps. Nahcolite (NaHCO{sub 3}), a naturally-occurring mineral, could be used as an inexpensive sorbent to remove HCl vapor in hot coal gas streams. In the current program, nahcolite powder was used to fabricate pellets suitable for fixed-bed reactors and granules suitable for fluidized-bed reactors. Pilot-scale equipment were used to prepare sorbents in large batches: pellets by disk pelletization and extrusion techniques, and granules by granulation and spray-drying techniques. Bench-scale fixed- and fluidized-bed reactors were assembled at

  2. Abatements of reduced sulphur compounds, colour, and organic matter from indigo dyeing effluents by electrocoagulation.

    Science.gov (United States)

    Tünay, Olcay; Simşeker, Merve; Kabdaşli, Isik; Olmez-Hanci, Tugba

    2014-08-01

    In the present study, the treatability of indigo dyeing effluents by the electrocoagulation (EC) process using stainless steel electrodes was experimentally investigated. The samples used were concentrated with main pollutant parameters of chemical oxygen demand (COD) (1000-1100 mg/L), reduced sulphur species (over 2000 mg SO2-(3)/L), and colour (0.12-0.13 1/cm). The study focused on the effect of main operation parameters on the EC process performance in terms of abatement of reduced sulphur compounds as well as decolourization and organic matter reduction. Results indicated that the performance of EC proved to be high providing total oxidation of the reduced sulphur compounds, almost complete decolourization, and COD removal up to 90%. Increasing applied current density from 22.5 to 45 mA/cm2 appreciably improved abatement of the reduced sulphur compounds for Sample I, but a further increase in the applied current density to 67.5 mA/cm2 did not accelerate the conversion rate to sulphate. The process performance was adversely affected by increasing initial concentration of the reduced sulphur compounds. Decolourization and organic matter removal efficiency enhanced with increasing applied current density. The main removal mechanism of the reduced sulphur compounds by EC was explained as conversion to sulphate via oxidation. Conversion rate to sulphate fitted pseudo-first-order kinetics very well.

  3. AO13. High energy, low methane syngas from low-rank coals for coal-to-liquids production

    Energy Technology Data Exchange (ETDEWEB)

    Lucero, Andrew [Southern Research Institute, Durham, NC (United States); Goyal, Amit [Southern Research Institute, Durham, NC (United States); McCabe, Kevin [Southern Research Institute, Durham, NC (United States); Gangwal, Santosh [Southern Research Institute, Durham, NC (United States)

    2015-06-30

    An experimental program was undertaken to develop and demonstrate novel steam reforming catalysts for converting tars, C2+ hydrocarbons, and methane under high temperature and sulfur environments at lab scale. Several catalysts were developed and synthesized along with some catalysts based on recipes found in the literature. Of these, two had good resistance at 90 ppm H2S with one almost not affected at all. Higher concentrations of H2S did affect methane conversion across the catalyst, but performance was fairly stable for up to 200 hours. Based on the results of the experimental program, a techno-economic analysis was developed for IGCC and CTL applications and compared to DOE reference cases to examine the effects of the new technology. In the IGCC cases, the reformer/POX system produces nearly the same amount of electricity for nearly the same cost, however, the reformers/POX case sequesters a higher percentage of the carbon when compared to IGCC alone. For the CTL case the economics of the new process were nearly identical to the CTL case, but due to improved yields, the greenhouse gas emissions for a given production of fuels was approximately 50% less than the baseline case.

  4. Coal-92

    International Nuclear Information System (INIS)

    Hillring, B.; Sparre, C.

    1992-11-01

    Swedish consumption of coal and coke during 1991 and trends in technology, environment and market aspects of coal use are reported. Steam coal use in the heating sector was unchanged from 1991, 1.2 Mtons. Reduced consumption in smaller district heating units (due to conversion to biofuels and gas) was compensated by increased use for power generation in cogeneration plants. Coal consumption in industry fell 0.10 Mton to 0.84 Mton due to lower production in one industry branch. Import of steam coal was 1.1 Mton (down 0.5 Mton from 1990) since new rules for strategic reserves allowed a reduction of stocks. During the last five years stocks have been reduced by 2 Mtons. Import of metallurgical coal was 1.6 Mton, unchanged from 1990. The report also gives statistics for the coal using plants in Sweden, on coal R and D, and on emission laws for coal firing. (9 tabs., 2 figs.)

  5. The effect of Co-firing with Straw and Coal on High Temperature Corrosion

    DEFF Research Database (Denmark)

    Montgomery, Melanie; Frandsen, Flemming; Larsen, OH

    2001-01-01

    As a part of ELSAMS development programme into alternative energy sources, various concepts of straw-firing have been investigated. This paper concerns co-firing of straw with coal to reduce the corrosion rate observed in straw-fired power plants. Co-firing with coal reduces the amount of potassium......: a) the exposure of metal rings on water/air cooled probes, and b) the exposure of a range of materials built into the existing superheaters. A range of austenitic and ferritic steels was exposed in the steam temperature region of 520-580°C. The flue gas temperature ranged from 925-1100°C....... The corrosion products for the various steel types were investigated using light optical and scanning electron microscopy. Corrosion mechanisms for the austenitic and ferritic steels are presented. These are discussed in relation to temperature and deposit composition. Co-firing with coal has removed potassium...

  6. Arsenic concentrations in Chinese coals

    International Nuclear Information System (INIS)

    Wang Mingshi; Zheng Baoshan; Wang Binbin; Li Shehong; Wu Daishe; Hu Jun

    2006-01-01

    The arsenic concentrations in 297 coal samples were collected from the main coal-mines of 26 provinces in China were determined by molybdenum blue coloration method. These samples were collected from coals that vary widely in coal rank and coal-forming periods from the five main coal-bearing regions in China. Arsenic content in Chinese coals range between 0.24 to 71 mg/kg. The mean of the concentration of Arsenic is 6.4 ± 0.5 mg/kg and the geometric mean is 4.0 ± 8.5 mg/kg. The level of arsenic in China is higher in northeastern and southern provinces, but lower in northwestern provinces. The relationship between arsenic content and coal-forming period, coal rank is studied. It was observed that the arsenic contents decreases with coal rank in the order: Tertiary > Early Jurassic > Late Triassic > Late Jurassic > Middle Jurassic > Late Permian > Early Carboniferous > Middle Carboniferous > Late Carboniferous > Early Permian; It was also noted that the arsenic contents decrease in the order: Subbituminous > Anthracite > Bituminous. However, compared with the geological characteristics of coal forming region, coal rank and coal-forming period have little effect on the concentration of arsenic in Chinese coal. The average arsenic concentration of Chinese coal is lower than that of the whole world. The health problems in China derived from in coal (arsenism) are due largely to poor local life-style practices in cooking and home heating with coal rather than to high arsenic contents in the coal

  7. Causes of coal degradation at working faces

    Energy Technology Data Exchange (ETDEWEB)

    Sikora, W

    1985-01-01

    Coal comminution by shearer loaders at working faces and factors influencing it are analyzed. Three groups of factors are evaluated: coal mechanical properties, design and specifications of shearer loaders and mining schemes. On the basis of analyses, recommendations for increasing proportion of coarse coal and reducing coal comminution in underground coal mines in Poland are made. Increasing output of coarse coal in coal seams with a high proportion of dull coal is most economic. Increasing power of drive systems for shearer loaders to 500 kW or more decisively influences grain size distribution of coal and increases proportion of coarse coal, especially in seams of dull coal. Gradually increasing cutting depth of a shearer loader negatively influences haulage speed and coarse coal output. Replacing gradual cutting depth increase by attack at the full cutting depth increases proportion of coarse coal. When medium or thick coal seams are mined a coal bench from 0.3 to 0.5 m thick should be left in the roof or between 2 benches cut by 2 cutting drums. The coal bench left in the face disintegrates under the influence of gravity and the proportion of coarse coal increases. Optimizing yield strength of powered supports at a working face is a further method for improving grain size distribution of coal and increasing proportion of coarse coal. 2 references.

  8. Sulphur isotope measurements on sulphates from Antarctic atmospheric precipitations, lake waters and salt efflorescences: a contribution to the study of the natural sulphur cycle

    International Nuclear Information System (INIS)

    Wand, U.; Maass, I.; Haendel, D.

    1987-01-01

    Sulphur isotope analyses are an important tool for the study of the natural sulphur cycle. However, on the northern hemisphere such studies particularly of the atmospheric component of the cycle are seriously hampered and in many regions practically impossible because of the high emission rate of anthropogenic sulphur. Only in remote areas of the world such as the Antarctic 34 S analyses can be used with success to identify the various natural sulphur sources (marine, biogenic and volcanic sources). We report here preliminary results of 34 S isotope measurements on sulphates from recent atmospheric precipitations (snow), lake waters and salt efflorescences sampled in the Schirmacher Oasis and the Wohlthat Massif, central Queen Maud Land, East Antarctica. Except for 4 efflorescence samples the sulphates investigated in this work are enriched in 34 S relative to the meteoritic sulphur standard (CDT). On an average the sulphates of our study area are isotopically lighter than those from the McMurdo region, South Victoria land. The latter region is characterized by the predominance of salts of marine origin. (author)

  9. Global thermal coal trade outlook

    International Nuclear Information System (INIS)

    Ewart, E.

    2008-01-01

    Wood Mackenzie operates coal consulting offices in several cities around the world and is the number one consulting company in terms of global coal coverage. The company offers a unique mine-by-mine research methodology, and owns a proprietary modeling system for coal and power market forecasting. This presentation provided an overview of global thermal markets as well as recent market trends. Seaborne markets have an impact on price far greater than the volume of trade would imply. Research has also demonstrated that the global thermal coal market is divided between the Pacific and Atlantic Basins. The current status of several major coal exporting countries such as Canada, the United States, Venezuela, Colombia, Indonesia, Australia, China, South Africa, and Russia was displayed in an illustration. The presentation included several graphs indicating that the seaborne thermal coal market is highly concentrated; traditional coal flow and pricing trends shift as Asian demand growth and supply constraints lead to chronic under supply; coal prices have risen to historic highs in recent times; and, the Asian power sector demand is a major driver of future growth. The correlation between oil and gas markets to thermal coal was illustrated along with two scenarios of coal use in the United States in a carbon-constrained world. The impact of carbon legislation on coal demand from selected coal regions in the United States was also discussed. Wood Mackenzie forecasts a very strong growth in global thermal coal demand, driven largely by emerging Asian economies. tabs., figs

  10. Effects of changes in the UK energy demand and environmental legislation on atmospheric pollution by sulphur dioxide

    International Nuclear Information System (INIS)

    Blakemore, F.B.; Davies, C.; Isaac, J.G.

    1999-01-01

    Ninety-nine percent of the sulphur dioxide generated over the period 1970 to 1994 arose from the combustion of fossil fuels in the energy sector. The annual mass emission of sulphur dioxide has fallen by 58% over this period, due to the reductions in outputs from coal and petroleum fired plants. The influence of natural-gas power generation has played an important part in this reduction. Four major pieces of environmental legislation have been enacted to control sulphur-dioxide emissions: the Control of Pollution Act 1974, and three EEC Directives are discussed. The UK emissions in 1994 were 49% below the 1980 baseline and 9% ahead of the 1998 EU target level. The protocol on the reduction of sulphur-dioxide emissions, adopted in 1985, required a cut in the total SO 2 emissions of 30% by 1993, based on 1980 levels. The UK achieved a reduction of 37% by the end of 1993. Sulphur-dioxide emissions are predicted to fall according to the six scenarios in Energy paper 65 as a reference case. The predicted decline is in line with the UNECE targets set for 2010. (Copyright (c) 1999 Elsevier Science B.V., Amsterdam. All rights reserved.)

  11. In Developping a Bench-Scale Circulating Fluidized Bed Combustor to Burn High Ash Brazilian Coal-Dolomites Mixtures

    Science.gov (United States)

    Ramírez Behainne, Jhon Jairo; Hory, Rogério Ishikawa; Goldstein, Leonardo; Bernárdez Pécora, Araí Augusta

    This work considers some of the questions in burning high ash Brazilian coal-dolomite mixtures in a bench-scale circulating fluidized bed combustor (CFBC). Experimental tests were performed with the CE4500 coal from Santa Catarina State, in southern Brazil, with a Sauter mean diameter d p =43 μm. The coal particles were mixed with dolomite particles of d p = 111 μm and this fuel mixture was fed into the circulating fluidized reactor, previously loaded with quartz sand particles of d p =353 μm. This inert material was previously heated by the combustion of liquefied petroleum gas up to the ignition temperature of the fuel mixture. The CFBC unit has a 100mm internal diameter riser, 4.0m high, as well as a 62.8mm internal diameter downcomer. The loop has a cyclone, a sampling valve to collect particles and a 62.8mm internal diameter L-valve to recirculate the particles in the loop. A screw feeder with a rotation control system was used to feed the fuel mixture to the reactor. The operational conditions were monitored by pressure taps and thermocouples installed along the loop. A data acquisition system showed the main operational conditions to control. Experimental tests performed put in evidence the problems found during bed operation, with special attention to the solids feed device, to the L-valve operation, to particle size, solids inventory, fluidized gas velocity, fuel mixture and recirculated solids feeding positions.

  12. Fluorine determination in coal using high-resolution graphite furnace molecular absorption spectrometry and direct solid sample analysis

    Energy Technology Data Exchange (ETDEWEB)

    Machado, Patrícia M.; Morés, Silvane; Pereira, Éderson R. [Departamento de Química, Universidade Federal de Santa Catarina, 88040-900 Florianópolis, SC (Brazil); Welz, Bernhard, E-mail: w.bernardo@terra.com.br [Departamento de Química, Universidade Federal de Santa Catarina, 88040-900 Florianópolis, SC (Brazil); Instituto Nacional de Ciência e Tecnologia do CNPq, INCT de Energia e Ambiente, Universidade Federal da Bahia, 40170-115 Salvador, BA (Brazil); Carasek, Eduardo [Departamento de Química, Universidade Federal de Santa Catarina, 88040-900 Florianópolis, SC (Brazil); Andrade, Jailson B. de [Instituto Nacional de Ciência e Tecnologia do CNPq, INCT de Energia e Ambiente, Universidade Federal da Bahia, 40170-115 Salvador, BA (Brazil)

    2015-03-01

    The absorption of the calcium mono-fluoride (CaF) molecule has been employed in this study for the determination of fluorine in coal using direct solid sample analysis and high-resolution continuum source graphite furnace molecular absorption spectrometry (HR-CS GF MAS). The rotational line at 606.440 nm was used for measuring the molecular absorption in the gas phase. The pyrolysis and vaporization temperatures were 700 °C and 2100 °C, respectively. Different chemical modifiers have been studied, such as Pd and Ir as permanent modifiers, and Pd and the mixed Pd/Mg modifier in solution. The limit of detection and the characteristic mass were 0.3 and 0.1 ng F, respectively. One certified reference material (CRM) of coal (NIST 1635) and four CRMs with a non-certified value for F (SARM 18, SARM 20, BCR 40, BCR 180) were used to evaluate the accuracy and precision of the method, obtaining good agreement (104%) with the certified value and with the informed values (ranging from 90 to 103%). - Highlights: • High-resolution Graphite Furnace Molecular Absorption Spectrometry (HR-GF MAS) • Fluorine has been determined using HR-GF MAS of the CaF molecule. • The CaF molecule was generated in a graphite furnace at a temperature of 2100 °C • Coal samples have been analyzed using direct solid sample introduction. • Aqueous standard solutions have been used for calibration.

  13. Molecular indicators for palaeoenvironmental change in a Messinian evaporitic sequence (Vena del Gesso, Italy). II: High-resolution variations in abundances and 13C contents of free and sulphur-bound carbon skeletons in a single marl bed

    Science.gov (United States)

    Kenig, F.; Damste, J. S.; Frewin, N. L.; Hayes, J. M.; De Leeuw, J. W.

    1995-01-01

    The extractable organic matter of 10 immature samples from a marl bed of one evaporitic cycle of the Vena del Gesso sediments (Gessoso-solfifera Fm., Messinian, Italy) was analyzed quantitatively for free hydrocarbons and organic sulphur compounds. Nickel boride was used as a desulphurizing agent to recover sulphur-bound lipids from the polar and asphaltene fractions. Carbon isotopic compositions (delta vs PDB) of free hydrocarbons and of S-bound hydrocarbons were also measured. Relationships between these carbon skeletons, precursor biolipids, and the organisms producing them could then be examined. Concentrations of S-bound lipids and free hydrocarbons and their delta values were plotted vs depth in the marl bed and the profiles were interpreted in terms of variations in source organisms, 13 C contents of the carbon source, and environmentally induced changes in isotopic fractionation. The overall range of delta values measured was 24.7%, from -11.6% for a component derived from green sulphur bacteria (Chlorobiaceae) to -36.3% for a lipid derived from purple sulphur bacteria (Chromatiaceae). Deconvolution of mixtures of components deriving from multiple sources (green and purple sulphur bacteria, coccolithophorids, microalgae and higher plants) was sometimes possible because both quantitative and isotopic data were available and because either the free or S-bound pool sometimes appeared to contain material from a single source. Several free n-alkanes and S-bound lipids appeared to be specific products of upper-water-column primary producers (i.e. algae and cyanobacteria). Others derived from anaerobic photoautotrophs and from heterotrophic protozoa (ciliates), which apparently fed partly on Chlorobiaceae. Four groups of n-alkanes produced by algae or cyanobacteria were also recognized based on systematic variations of abundance and isotopic composition with depth. For hydrocarbons probably derived from microalgae, isotopic variations are well correlated with

  14. A novel concept for high conversion of coal to liquids. Final report, 1 September 1988--31 August 1992

    Energy Technology Data Exchange (ETDEWEB)

    Wiser, W.H.; Shabtai, J.

    1994-04-01

    A batch microreactor was designed and fabricated as a means of investigating maximum yields of liquids obtainable in very short reaction times of the order of a few seconds, and the maximum ratios of liquids/hydrocarbon (HC) gases obtainable under those conditions. A Wyodak sub-bituminous coal, crushed and sieved to {minus}200 mesh particle size, was used in the experiments, with a temperature of 500{degrees}C and a pressure of 1500 psi. The fine coal particles were fed dry to the reactor and heated to reaction temperature in times of one to two seconds. At a time of 3 seconds at reaction temperature, in a single pass a liquid yield of 60% by weight of the coal was obtained, accompanied by a ratio of liquids/(HC) gases of 30/1. When the unreacted solids were recycled to the reactor, and the results combined with those of the first pass, a liquid yield of 82% by weight of the coal was achieved, accompanied by a ratio of liquids/HC gases of 30/1. This ratio represents only about 3 wt percent HC gases, much lower that is produced in current advanced technologies, and represents a large saving in hydrogen consumption. A simulated distillation technique was applied to the liquids. The liquid product contained 86% by weight (of the liquids) total distillables (boiling point below 538{degrees}C), including 70% by weight of low-boiling fractions in the gasoline, kerosene and gas oil range (boiling point up to 325{degrees}C). The liquid product exhibited a H/C ratio of 1.5, which is considerably higher than observed in current advanced technologies for the primary liquids. Several catalysts were investigated. Iron catalysts, specifically ferric chloride hexahydrate and ferric sulfate pentahydrate, each produced these high conversions and high ratios of liquids/HC gases.

  15. AISI/DOE Technology Roadmap Program: A Technology of Low Coal Rate and High Productivity of RHF Ironmaking

    Energy Technology Data Exchange (ETDEWEB)

    Wei-Kao Lu

    2002-09-15

    An economical and environment-friendly ironmaking process based on heating the chemiexecy self-sufficient green balls of iron ore and coal in a hearth furnace is being developed with financial support from AISI members and DOE. DRI, which is hot (1400 C), dense (3.2 g/cm) and of high degree of metallization (95%), has been produced in laboratory and in a pilot plant in Genoa, Italy. Products of such quality have been made from American and Brazilian ores, BOF sludge, EAF dust/BOF sludge mixtures and millscale. The removal of zinc and lead from green balls by this process is essentially complete. In comparison with typical blast furnace operation, the new technology with a melter would have a lower total coal rate by 200kg.THM. The elimination of cokemaking and high temperature agglomeration steps, and a simpler gas handling system would lead to lower capital and operating costs. In comparison with commercial RHF practice it is different in atmosphere (fully oxidized at 1600 to 1650 C), in bed height (120 mm instead of 20-25 mm) and in pellet composition (much less coal but of higher VM). The combined effect leads to three times higher furnace productivity, lower coal consumption and superior DRI quality. The risk of re-oxidation (slag formation) and dusty operation are practiexecy eliminated. The process is stable, tolerant and independent of the size, shape and movement of the hearth. However, materials handling (e.g., discharge of hot DRI) and the exact energy savings have to be established in a larger furnace, straight or rotary, and in a continuous mode of operation.

  16. On the high-temperature desulfurization of coal gas: The development of a regenerable absorbent

    Energy Technology Data Exchange (ETDEWEB)

    Van Yperen, Renee

    1994-05-18

    There is actually no solid absorbent based on bulk metal oxides available that meets the conditions for application in high-temperature desulfurization processes. This research was aimed to develop an absorbent that fulfills all the specifications for employment in hot-gas clean up. Chapter 2 deals with the development of amorphous aluminium phosphate as a support material. The influence of the preparation conditions onto the specific surface area, pore structure, thermal and chemical stability, and acidity of amorphous aluminium phosphate was investigated. The application of iron oxide onto amorphous aluminium phosphate by means of deposition-precipitation from a homogeneous solution is discussed in chapter 3. The influence of amorphous aluminium phosphate onto the stability, activity, and capacity of the iron oxide is described in detail. Chapter 4 surveys the activity and capacity of several active materials in the absorption of hydrogen sulphide. It is shown that the most promising active material is a mixture of iron oxide and molybdenum oxide. In chapter 5 the properties of iron-molybdenum mixed oxide absorbents are discussed. The effect of the iron to molybdenum ratio onto the formation of iron-(III)-sulphates and the stability of the molybdenum compound is examined. Chapter 6 deals with the preparation of iron-molybdenum mixed oxide absorbents by means of impregnation of modified pre-shaped alumina support bodies. In chapter 7 the effect of the hydrogen and carbon monoxide concentration and in chapter 8 the effect of the water concentration in the coal gas on the activity and the capacity of the iron-molybdenum mixed oxide absorbents is described. Regeneration of the loaded absorbents is an important part of the desulfurization process, dealt with in chapter 9. A number of regeneration procedures have been tested. (Abstract Truncated)

  17. Coal -94

    International Nuclear Information System (INIS)

    Sparre, C.

    1994-05-01

    This report deals with use of coal and coke during 1993; information about techniques, environmental questions and markets are also given. Use of steamcoal for heating purposes has been reduced about 3 % during 1993 to 1,0 mill tons. This is the case especially for the heat generating boilers. Production in co-generation plants has been constant and has increased for electricity production. Minor plants have increased their use of forest fuels, LPG and NG. Use of steamcoal will probably go down in the immediate years both in heat generating and co-generating plants. Coal-based electricity has been imported from Denmark during 1993 corresponding to about 400 000 tons of coal, when several of our nuclear plants were stopped. Use of steamcoal in the industry has been constant at 700 000 tons. This level is supposed to be constant or to vary with business cycles. The import of metallurgical coal in 1993 was 1,6 mill tons like the year before. 1,2 mill tons coke were produced. Coke consumption in industry was 1,4 mill tons. 0,2 mill tons of coke were imported. Average price of steamcoal imported to Sweden in 1993 was 308 SEK/ton or 13 % higher than in 1992; this can be explained by the dollar price level increasing 34% in 1993. For the world, the average import price was 50,0 USD/ton, a decrease of 6 %. The coal market during 1993 was affected by less consumption in Europe, shut downs of European mines and decreasing prices. High freight price raises in Russia has affected the Russian export and the market in northern Europe. The prices have been stabilized recently. All Swedish plants meet emission limits of dust, SO 2 and NO x . Co-generation plants all have some sort of SO 2 -removal system; the wet-dry method is mostly used. A positive effect of the recently introduced NO x -duties is a 40% reduction

  18. Coal 1992

    Energy Technology Data Exchange (ETDEWEB)

    1992-01-01

    ACR's Coal 1992, the successor to the ACR Coal Marketing Manual, contains a comprehensive set of data on many aspects of the Australian coal industry for several years leading up to 1992. Tables and text give details of coal production and consumption in New South Wales, Queensland and other states. Statistics of the Australian export industry are complemented by those of South Africa, USA, New Zealand, Canada, Indonesia, China, Colombia, Poland and ex-USSR. Also listed are prices of Australian coking and non-coking coal, Australian coal stocks (and those of other major countries), loading port capacities, freight rates and coal quality requirements (analysis of coals by brand and supplier). A listing of Australian coal exporting companies is provided. A description of the spot Coal Screen Dealing System is given. World hard coal imports are listed by country and coal imports by major Asian countries tabulated. A forecast of demand by coal type and country up to the year 2000 is included.

  19. Management of high sulfur coal combustion residues, issues and practices: Proceedings

    Energy Technology Data Exchange (ETDEWEB)

    Chugh, Y.P.; Beasley, G.A. [eds.

    1994-10-01

    Papers presented at the following sessions are included in this proceedings: (1) overview topic; (2) characterization of coal combustion residues; (3) environmental impacts of residues management; (4) materials handling and utilization, Part I; and (5) materials handling and utilization, Part II. Selected paper have been processed separately for inclusion in the Energy Science and Technology Database.

  20. DOLOMITE DESULFURIZATION BEHAVIOR IN A BUBBLING FLUIDIZED BED PILOT PLANT FOR HIGH ASH COAL

    Directory of Open Access Journals (Sweden)

    G. M. F. Gomes

    Full Text Available Abstract Although fluidized bed in situ desulphurization from coal combustion has been widely studied, there are aspects that remain under investigation. Additionally, few publications address Brazilian coal desulphurization via fluidized beds. This study used a 250 kWth bubbling fluidized bed pilot plant to analyze different aspects of the dolomite desulphurization of two Brazilian coals. Superficial velocities of 0.38 and 0.46 m/s, flue gas recycling, Ca/S molar ratios and elutriation were assessed. Results confirmed the influence of the Ca/S molar ratio and superficial velocity - SO2 conversion up to 60.5% was achieved for one coal type, and 70.9% was achieved for the other type. A recycling ratio of 54.6% could increase SO2 conversion up to 86.1%. Elutriation and collection of ashes and Ca-containing products did not present the same behavior because a lower wt. % of CaO was collected by the gas controlled mechanism compared to the ash.

  1. Surface chemical properties of novel high surface area solids synthesized from coal fly ash

    CSIR Research Space (South Africa)

    Pretorius, PJ

    2003-07-23

    Full Text Available The zeolite, Na-P1, was synthesized from fly ash samples originating from coal-fired power stations in South Africa by hydrothermal treatment of the raw ash with concentrated aqueous NaOH solutions. The zeolite was then further modified by acid...

  2. Application of Acidithiobacillus Ferrooxidans in coal flotation

    Energy Technology Data Exchange (ETDEWEB)

    Amini, E.; Hosseini, T.R.; Oliazadeh, M.; Kolahdoozan, M. [University of Queensland, Brisbane, Qld. (Australia)

    2009-07-01

    Bioflotation is a potential method for removing pyritic sulphur from coal. Sodium cyanide is a well-known depressant for pyrite in flotation of sulphide minerals; however, for coal this reagent is unacceptable from the environmental point of view. This study investigates an alternate to sodium cyanide, Acidithiobacillus Ferrooxidans, a nonharmful bacterial reagent as a pyrite depressant. The flotation behavior of pyrite and other gangue particles using the sodium cyanide and the Ferrooxidans is compared by applying the general first-order flotation model. The kinetic parameters extracted from the model demonstrated that the modified flotation rate of pyrite was reduced, and the selectivity between coal and gangue was improved using the bacteria. These results indicate that Acidithiobacillus Ferrooxidans has potential in removing pyritic sulfur from coal.

  3. Next Generation Pressurized Oxy-Coal Combustion: High Efficiency and No Flue Gas Recirculation

    Energy Technology Data Exchange (ETDEWEB)

    Rue, David

    2013-09-30

    The Gas Technology Institute (GTI) has developed a pressurized oxy-coal fired molten bed boiler (MBB) concept, in which coal and oxygen are fired directly into a bed of molten coal slag through burners located on the bottom of the boiler and fired upward. Circulation of heat by the molten slag eliminates the need for a flue gas recirculation loop and provides excellent heat transfer to steam tubes in the boiler walls. Advantages of the MBB technology over other boilers include higher efficiency (from eliminating flue gas recirculation), a smaller and less expensive boiler, modular design leading to direct scalability, decreased fines carryover and handling costs, smaller exhaust duct size, and smaller emissions control equipment sizes. The objective of this project was to conduct techno-economic analyses and an engineering design of the MBB project and to support this work with thermodynamic analyses and oxy-coal burner testing. Techno-economic analyses of GTI’s pressurized oxy-coal fired MBB technology found that the overall plant with compressed CO2 has an efficiency of 31.6%. This is a significant increase over calculated 29.2% efficiency of first generation oxy-coal plants. Cost of electricity (COE) for the pressurized MBB supercritical steam power plant with CO2 capture and compression was calculated to be 134% of the COE for an air-coal supercritical steam power plant with no CO2 capture. This compares positively with a calculated COE for first generation oxy-coal supercritical steam power plants with CO2 capture and compression of 164%. The COE for the MBB power plant is found to meet the U.S. Department of Energy (DOE) target of 135%, before any plant optimization. The MBB power plant was also determined to be simpler than other oxy-coal power plants with a 17% lower capital cost. No other known combustion technology can produce higher efficiencies or lower COE when CO2 capture and compression are included. A thermodynamic enthalpy and exergy analysis

  4. Coal pump

    Science.gov (United States)

    Bonin, John H.; Meyer, John W.; Daniel, Jr., Arnold D.

    1983-01-01

    A device for pressurizing pulverized coal and circulating a carrier gas is disclosed. This device has utility in a coal gasification process and eliminates the need for a separate collection hopper and eliminates the separate compressor.

  5. Reactions of sulphur mustard on impregnated carbons.

    Science.gov (United States)

    Prasad, G K; Singh, Beer

    2004-12-31

    Activated carbon of surface area 1100 m2/gm is impregnated with 4% sodium hydroxide plus 3% Cr(VI) as CrO3 with and without 5% ethylene diamine (EDA), 4% magnesium nitrate and 5% ruthenium chloride by using their aqueous solutions. These carbons are characterized for surface area analysis by BET conventional method and exposed to the vapours of sulphur mustard (HD) at room temperature (30 degrees C). After 24 h, the reaction products are extracted in dichloromethane and analyzed using gas chromatography and mass spectrometry (GC-MS). Hemisulphur mustard, thiodiglycol, 1,4-oxathiane are observed to be the products of reaction between sulphur mustard and NaOH/CrO3/C system, whereas on NaOH/CrO3/EDA/C system HD reacted to give 1,4-thiazane. On Mg(NO3)2/C system it gave hemisulphur mustard and thiodiglycol. On RuCl3/C system it degraded to divinyl sulphone. Residual sulphur mustard is observed along with reaction products in all systems studied. Reaction mechanisms are also proposed for these interesting surface reactions. Above-mentioned carbons can be used in filtration systems for protection against hazardous gases such as sulphur mustard.

  6. Reactions of sulphur mustard on impregnated carbons

    International Nuclear Information System (INIS)

    Prasad, G.K.; Singh, Beer

    2004-01-01

    Activated carbon of surface area 1100 m 2 /gm is impregnated with 4% sodium hydroxide plus 3% Cr(Vi) as CrO 3 with and without 5% ethylene diamine (EDA), 4% magnesium nitrate and 5% ruthenium chloride by using their aqueous solutions. These carbons are characterized for surface area analysis by BET conventional method and exposed to the vapours of sulphur mustard (HD) at room temperature (30 deg. C). After 24 h, the reaction products are extracted in dichloromethane and analyzed using gas chromatography and mass spectrometry (GC-MS). Hemisulphur mustard, thiodiglycol, 1,4-oxathiane are observed to be the products of reaction between sulphur mustard and NaOH/CrO 3 /C system, whereas on NaOH/CrO 3 /EDA/C system HD reacted to give 1,4-thiazane. On Mg(NO 3 ) 2 /C system it gave hemisulphur mustard and thiodiglycol. On RuCl 3 /C system it degraded to divinyl sulphone. Residual sulphur mustard is observed along with reaction products in all systems studied. Reaction mechanisms are also proposed for these interesting surface reactions. Above-mentioned carbons can be used in filtration systems for protection against hazardous gases such as sulphur mustard

  7. Intensification of zinc dissolution process in sulphuric acid

    Directory of Open Access Journals (Sweden)

    Stanojević D.

    2005-01-01

    Full Text Available Many high purity salts are produced by dissolving pure metal in non-oxidizing mineral acids. If hydrogen overpotential on the given metal is high, then the rate of overall process is defined by reaction of hydrogen ion reduction. This study investigated the possibility of accelerated dissolving of metal zinc in sulphuric acid by introducing copper cathode on which evolving hydrogen is much easier than on zinc. It was found out that the acceleration of zinc dissolving is possible and, at constant surface of copper cathode depends on the quality of electrical contact between copper electrode and zinc.

  8. Sulphur oxidising bacteria in mangrove ecosystem: A review ...

    African Journals Online (AJOL)

    Sulphur-oxidizing bacteria such as photoautotrophs, chemolithotrophs and heterotrophs play an important role in the mangrove environment for the oxidation of the toxic sulphide produced by sulphur reducing bacteria and act as a key driving force behind all sulphur transformations in the mangrove ecosystem which is ...

  9. Development of the floating sulphur biofilm reactor for sulphide ...

    African Journals Online (AJOL)

    Development of the floating sulphur biofilm reactor for sulphide oxidation in biological water treatment systems. ... The effect of influent sulphide concentrations, flow rate and reactor dimensions on the sulphur biofilm formation were investigated for the optimisation of elemental sulphur recovery and sulphide removal ...

  10. The useful application of sulphur-bound waste materials

    NARCIS (Netherlands)

    Alkemade, M.M.C.; Koene, J.I.A.

    1996-01-01

    An immobilization process is described which is based on sulphur (instead of cement) as a binding agent for the treatment of hazardous waste materials. Elemental sulphur is able to bind chemically metals such as mercury and, to a lesser extent, lead as metal sulphides. Furthermore, sulphur forms a

  11. Depositional controls on coal distribution and quality in the Eocene Brunner Coal Measures, Buller Coalfield, South Island, New Zealand

    Science.gov (United States)

    Flores, R.M.; Sykes, R.

    1996-01-01

    The Buller Coalfield on the West Coast of the South Island, New Zealand, contains the Eocene Brunner Coal Measures. The coal measures unconformably overlie Paleozoic-Cretaceous basement rocks and are conformably overlain by, and laterally interfinger with, the Eocene marine Kaiata Formation. This study examines the lithofacies frameworks of the coal measures in order to interpret their depositional environments. The lower part of the coal measures is dominated by conglomeratic lithofacies that rest on a basal erosional surface and thicken in paleovalleys incised into an undulating peneplain surface. These lithofacies are overlain by sandstone, mudstone and organic-rich lithofacies of the upper part of the coal measures. The main coal seam of the organic-rich lithofacies is thick (10-20 m), extensive, locally split, and locally absent. This seam and associated coal seams in the Buller Coalfield are of low- to high-volatile bituminous rank (vitrinite reflectance between 0.65% and 1.75%). The main seam contains a variable percentage of ash and sulphur. These values are related to the thickening and areal distribution of the seam, which in turn, were controlled by the nature of clastic deposition and peat-forming mire systems, marine transgression and local tidal incursion. The conglomeratic lithofacies represent deposits of trunk and tributary braided streams that rapidly aggraded incised paleovalleys during sea-level stillstands. The main seam represents a deposit of raised mires that initially developed as topogenous mires on abandoned margins of inactive braidbelts. Peat accumulated in mires as a response to a rise in the water table, probably initially due to gradual sea-level rise and climate, and the resulting raised topography served as protection from floods. The upper part of the coal measures consists of sandstone lithofacies of flu vial origin and bioturbated sandstone, mudstone and organic-rich lithofacies, which represent deposits of paralic (deltaic

  12. Influence of Environmentally Friendly and High-Efficiency Composite Additives on Pulverized Coal Combustion in Cement Industry

    Directory of Open Access Journals (Sweden)

    Zhiyong Wang

    2016-01-01

    Full Text Available 4 kinds of chemical reagents and 3 kinds of industrial wastes were selected as burning additives for 2 kinds of coals in cement industry. The work focused on the replacement of partial chemical reagents by industrial wastes, which not only reduced the cost and took full advantage of industrial wastes, but also guaranteed the high combustion efficiency and removed the NOX and SO2 simultaneously. The experiments were carried out in DTF. The combustion residues were analyzed by SEM and XRD. The results showed that the burnout rate was increased after adding the additives; meanwhile, the NOX and SO2 release concentration were reduced, but the degree of action varied for different additives and coals. The substitute of chemical reagents by industrial wastes was very effective; overall, the cold-rolled iron oxide worked better than others; the particles surface was tougher and the peaks of crystalline phase were lower than raw coal, which indicated that the additives played good roles in combustion process.

  13. Plant concept of heat utilization of high temperature gas-cooled reactors. Co-generation and coal-gasification

    International Nuclear Information System (INIS)

    Tonogouchi, M.; Maeda, S.; Ide, A.

    1996-01-01

    In Japan, JAERI is now constructing the High temperature Engineering Test Reactor (HTTR) and the new era is coming for the development and utilization of HTR. Recognizing that the heat utilization of HTR would mitigate problems of environment and resources and contribute the effective use and steady supply of the energy, FAPIG organized a working group named 'HTR-HUC' to study the heat utilization of HTR in the field other than electric power generation. We chose three kinds of plants to study, 1) a co-generation plant in which the existing power units supplying steam and electricity can be replaced by a nuclear plant, 2) Coal gasification plant which can accelerate the clean use of coal and contribute stable supply of the energy and preservation of the environment in the world and 3) Hydrogen production plant which can help to break off the use of the new energy carrier HYDROGEN and will release people from the dependence of fossil energy. In this paper the former two plants, Co-generation chemical plant and Coal-gasification plant are focussed on. The main features, process flow and safety assessment of these plants are discussed. (J.P.N.)

  14. Demonstration of SCR technology for the control of NOx emissions from high-sulfur coal-fired utility boilers

    Energy Technology Data Exchange (ETDEWEB)

    Hinton, W.S. [W.S. Hinton and Associates, Cantonment, FL (United States); Maxwell, J.D.; Healy, E.C.; Hardman, R.R. [Southern Company Services, Inc., Birmingham, AL (United States); Baldwin, A.L. [Dept. of Energy, Pittsburgh, PA (United States)

    1997-12-31

    This paper describes the completed Innovative Clean Coal Technology project which demonstrated SCR technology for reduction of flue gas NO{sub x} emissions from a utility boiler burning US high-sulfur coal. The project was sponsored by the US Department of Energy, managed and co-funded by Southern Company Services, Inc. on behalf of the Southern Company, and also co-funded by the Electric Power Research Institute and Ontario Hydro. The project was located at Gulf Power Company`s Plant Crist Unit 5 (a 75 MW tangentially-fired boiler burning US coals that had a sulfur content ranging from 2.5--2.9%), near Pensacola, Florida. The test program was conducted for approximately two years to evaluate catalyst deactivation and other SCR operational effects. The SCR test facility had nine reactors: three 2.5 MW (5,000 scfm), and operated on low-dust flue gas. The reactors operated in parallel with commercially available SCR catalysts obtained from suppliers throughout the world. Long-term performance testing began in July 1993 and was completed in July 1995. A brief test facility description and the results of the project are presented in this paper.

  15. Investigation to develop methods for removal of oxygen from coals. [None

    Energy Technology Data Exchange (ETDEWEB)

    Cooke, N.E.; Khandhadia, P.S.; Furimsky, E.

    1985-02-01

    Several inorganic reducing agents of various chemical characteristics have been tested to see if they reduce the oxygen contained in coal. It was found that oxygen content of coals decreased when they were heated in only water (blank runs). The treatment with the reducing agents containing sulphur did not increase the oxygen removal over that achieved in the blank runs. However, it appears that the ferrous salt catalytically deoxygenated both the lignite and bituminous coals. 5 references.

  16. Experience in a 6.2 MW{sub e} pressurized fluidized bed gasifier with high ash Indian coals

    Energy Technology Data Exchange (ETDEWEB)

    Viswanathan, G.; Rajasekaran, A.; Periyakaruppan, V.; Krishnamoorthy, S. [Bharat Heavy Electricals Ltd., Tiruchirappalli (India)

    2006-07-01

    Bharat Heavy Electrical Limited has installed a 165 tons/day air-blown pressurized fluidized bed gasifier (PFBG) as an add-on to their 6.2 MW IGCC demonstration plant and has operated it for more than 4000 hours. Improvements in the gasifier refractory lining, ash extraction and cooling devices, air distribution and temperature measuring devices were incorporated to improve the reliability and performance. Coal with 30-42% ash and high calorific value in the range of 15-20 MJ/kg was used during these operations with crushed coal of 1-4 mm as well as -6 mm coal with fines. Tests were conducted at gasifier pressure of 0.3-1.0 MPa, fluidized bed temperature of 980-1050{sup o}C and at various fluidized velocities and air to steam ratios. Once through carbon conversion efficiency of 90%, cold gas efficiency of 69% and dry gas calorific value of 4.4-4.6 MJ/Nm{sup 3} were obtained. About 15% char in fly ash (with 40% ash coal) was established by TGA. Seal pot system was added for recyling fly ash from the first cyclone to enhance carbon conversion, other parameters and to reduce the char in fly ash to acceptable level. Trends and correlations were established for constituents of gas, carbon conversion efficiency, cold gas efficiency, calorific value of gas and gas yield. BHEL is currently working with a partner to install a 125 MW IGCC plant. The paper elaborates the schematic and constructional details of the PFBG, operating experience and performance. 3 refs., 9 figs.

  17. HIGH-QUALITY SELF-COMPACTING CONCRETE WITH COAL BURNING WASTE

    Directory of Open Access Journals (Sweden)

    Voronin Viktor Valerianovich

    2018-01-01

    Full Text Available Subject: nowadays self-compacting concretes (SCC, the use of which requires no additional compaction, have become widespread for use in densely-reinforced structures and hard-to-reach places. In self-compacting concretes, finely-ground admixtures-microfillers are widely used for controlling technological properties. Their introduction into the concrete mix allows us to obtain more dense structure of concrete. The influence of micro-fillers on water consumption and plasticity of concrete mix, on kinetics of strength gain rate, heat release and corrosion resistance is also noticeable. Research objectives: the work focuses on the development of composition of self-compacting concrete with assigned properties with the use of fly ash based on coal burning waste, optimized with the help of experimental design method in order to clarify the influence of ash and cement quantity, sand size on strength properties. Materials and methods: pure Portland cement CEM I 42.5 N was used as a binder. Crushed granite of fraction 5…20 mm was used as coarse aggregate, coarse quartz sand with the fineness modulus of 2.6 and fine sand with the fineness modulus of 1.4 were used as fillers. A superplasticizer BASF-Master Glenium 115 was used as a plasticizing admixture. The fly ash from Cherepetskaya thermal power plant was used as a filler. The study of strength and technological properties of self-compacting concrete was performed by using standard methods. Results: we obtained three-factor quadratic dependence of strength properties on the content of ash, cement and fraction of fine filler in the mix of fine fillers. Conclusions: introduction of micro-filler admixture based on the fly ash allowed us to obtain a concrete mix with high mobility, fluidity and self-compaction property. The obtained concrete has high strength characteristics, delayed strength gain rate due to replacement of part of the binder with ash. Introduction of the fly ash increases degree of

  18. The Indonesian coal industry

    International Nuclear Information System (INIS)

    Cook, A.; Daulay, B.

    2000-01-01

    In this comprehensive article the authors describe the origins and progress of the Indonesian coal industry and the role it plays, and will play, in the domestic energy scene and world coal trade. In the '80s, the Indonesian coal industry laid the basis for major expansion such that coal production rose from under a million tonnes in 1983 to 10.6 million tonnes in 1990, 50.9 million tonnes by 1996 and 61.2 million tonnes in 1992. At the same time, exports have increased from 0.4 million tonnes to 44.8 million tonnes. Current export levels are higher than originally expected, due in part to a slow down in the construction of electric power stations and a partial switch to natural gas. This has slowed the rate at which domestic coal demand has built up. The majority of coals currently exported are low rank steam coals, but some of the higher rank and very low ash coals are used for blast furnace injection, and a very small proportion may even be used within coking blends, even though they have poor coking properties. The Indonesian coal industry has developed very rapidly over the last six years to become a significant exporter, especially within the ASEAN context. The resources base appears to be large enough to support further increases in production above those already planned. It is probable that resources and reserves can be increased above the current levels. It is likely that some reserves of high value coals can be found, but it is also probable that the majority of additions to reserves will be lower in rank (and therefore quality) compared with the average of coals currently being mined. Reserves of qualities suitable for export will support that industry for a considerable period of time. However, in the longer term, the emphasis of production will increasingly swing to the domestic market

  19. Thermal stability studies on atomically clean and sulphur passivated InGaAs surfaces

    Energy Technology Data Exchange (ETDEWEB)

    Chauhan, Lalit; Hughes, Greg [School of Physical Sciences, Dublin City University, Glasnevin, Dublin 9 (Ireland)

    2013-03-15

    High resolution synchrotron radiation core level photoemission measurements have been used to study the high temperature stability of sulphur passivated InGaAs surfaces and comparisons made with atomically clean surfaces subjected to the same annealing temperatures. Sulphur passivation of clean InGaAs surfaces prepared by the thermal removal of an arsenic capping layer was carried out using an in situ molecular sulphur treatment in ultra high vacuum. The elemental composition of the surfaces of these materials was measured at a series of annealing temperatures up to 530 C. Following a 480 C anneal In:Ga ratio was found to have dropped by 33% on sulphur passivated surface indicating a significant loss of indium, while no drop in indium signal was recorded at this temperature on the atomically InGaAs surface. No significant change in the As surface concentration was measured at this temperature. These results reflect the reduced thermal stability of the sulphur passivated InGaAs compared to the atomically clean surface which has implications for device fabrication. (Copyright copyright 2013 WILEY-VCH Verlag GmbH and Co. KGaA, Weinheim)

  20. Dew point of flue gas in the combustion of brown coal briquettes

    Energy Technology Data Exchange (ETDEWEB)

    Schinkel, W

    1977-08-01

    Economical operation of small steam generators can follow two courses, viz. to channel the emitted gases through the plant and reduce waste gas loss. Two possibilities exist to achieve this: firstly a steam generating process with only slight excess air; secondly a reduction of the emitted gas temperature. The lowest waste gas temperature found in sulphur-containing combustion materials is measured by finding the acid dew-point of the waste gas. The following results in the case of brown coal briquettes were found. Measurements of the dew point of flue gas in two steam generators, both of the double flue type, one having a capacity of 12.5 t/h, the other 25 t/h, one using brown coal briquettes with 1% sulphur content, the other with 3%, resulted in the fact that the dew point can be measured. It was shown that a low air ratio leads to a lowering of the dew point. However this process is unfortunately economically unviable in chain grate generators as the waste gas becomes so thin under a high air ratio that the dew point can only be minimally reduced. Further the acid dew point is only slightly influenced by partial operation of the generator and the infusion of briquette residue.

  1. Modified sulphur cement: A low porosity encapsulation material for low, medium and alpha waste

    International Nuclear Information System (INIS)

    Dalen, A. van; Rijpkema, J.E.

    1989-01-01

    Modified sulphur cement, available under the trade name Chement 2000, is a thermoplastic candidate material for the matrix of low, intermediate and alpha radioactive waste. The main source of sulphur is the desulphurization of fossil fuels. In view of the future increase of this product a modified compound of sulphur has been developed at the US Bureau of Mines. Modified sulphur cement as matrix material has properties in common with Portland or blast furnace cement and bitumen. The mechanical strength is comparable to hydraulic cement products. The process to incorporate waste materials is identical to bitumization. The leachability and the resistance to attack by chemicals is nearly the same as for bituminized products. This study showed also that the radiation resistance is high without radiolytic gas production and without change in dimensions (swelling). The rigidity of the matrix is a disadvantage when internal pressures are built up. The thermal conductivity and the heat of combustion of sulphur is low resulting in slow damage to the waste form under fire conditions, even when the temperature of self ignition in air is 220 0 C. The low leachability, the very slow effective diffusion of H 2 O and HTO, and the low permeability is due to the small pore diameters in the modified sulphur matrix. The loading capacity of modified sulphur cement depends on grain size and distribution and is for ungraded ashes, precipitates, dried sludges, etc., in the order of 40-50% of weight. The price of Chement 2000 per tonne is equal to those of blown bitumen

  2. Underground Coal Thermal Treatment

    Energy Technology Data Exchange (ETDEWEB)

    Smith, P. [Univ. of Utah, Salt Lake City, UT (United States); Deo, M. [Univ. of Utah, Salt Lake City, UT (United States); Eddings, E. [Univ. of Utah, Salt Lake City, UT (United States); Sarofim, A. [Univ. of Utah, Salt Lake City, UT (United States); Gueishen, K. [Univ. of Utah, Salt Lake City, UT (United States); Hradisky, M. [Univ. of Utah, Salt Lake City, UT (United States); Kelly, K. [Univ. of Utah, Salt Lake City, UT (United States); Mandalaparty, P. [Univ. of Utah, Salt Lake City, UT (United States); Zhang, H. [Univ. of Utah, Salt Lake City, UT (United States)

    2012-01-11

    The long-term objective of this work is to develop a transformational energy production technology by insitu thermal treatment of a coal seam for the production of substitute natural gas (SNG) while leaving much of the coal's carbon in the ground. This process converts coal to a high-efficiency, low-GHG emitting gas fuel. It holds the potential of providing environmentally acceptable access to previously unusable coal resources. This topical report discusses the development of experimental capabilities, the collection of available data, and the development of simulation tools to obtain process thermo-chemical and geo-thermal parameters in preparation for the eventual demonstration in a coal seam. It also includes experimental and modeling studies of CO2 sequestration.

  3. Modelling temperature-dependent heat production over decades in High Arctic coal waste rock piles

    DEFF Research Database (Denmark)

    Hollesen, Jørgen; Elberling, Bo; Jansson, P.E.

    2011-01-01

    Subsurface heat production from oxidation of pyrite is an important process that may increase subsurface temperatures within coal waste rock piles and increase the release of acid mine drainage, AMD. Waste rock piles in the Arctic are especially vulnerable to changes in subsurface temperatures...... such as heat production from coal oxidation may be equally important....... as the release of AMD normally is limited by permafrost. Here we show that temperatures within a 20 year old heat-producing waste rock pile in Svalbard (78°N) can be modelled by the one-dimensional heat and water flow model (CoupModel) with a new temperature-dependent heat-production module that includes both...

  4. Method of burning highly reactive strongly slagging coal dust in a chamber furnace

    Energy Technology Data Exchange (ETDEWEB)

    Protsaylo, M.Ya.; Kotler, V.R.; Lobov, G.V.; Mechev, V.P.; Proshkin, A.V.; Zhuravlev, Yu.A.

    1982-01-01

    In the chamber furnace in order to reduce slagging, it is proprosed that, above the coal dust burners, nozzles be installed with inclination downwards through which air is fed in a mixture with flue gases. Under the influence of this flue gas-air mixture, the coal dust flame is deviated downwards. In this case there is an increase in the length of the flame and degree of filling of the volume of the furnace with the flame. This increases the effectiveness of dust burning. The input into the furnace of fuel jointly with the air and flue gases (optimally 10-15% of the total quantity of gases formed during fuel combustion) makes it possible to reduce the temperature in the furnace and the probability of slagging of the furnace walls.

  5. Computational Fluid Dynamics (CFD) Modeling for High Rate Pulverized Coal Injection (PCI) to Blast Furnaces

    International Nuclear Information System (INIS)

    Zhou, Chenn

    2008-01-01

    Pulverized coal injection (PCI) into the blast furnace (BF) has been recognized as an effective way to decrease the coke and total energy consumption along with minimization of environmental impacts. However, increasing the amount of coal injected into the BF is currently limited by the lack of knowledge of some issues related to the process. It is therefore important to understand the complex physical and chemical phenomena in the PCI process. Due to the difficulty in attaining trus BF measurements, Computational fluid dynamics (CFD) modeling has been identified as a useful technology to provide such knowledge. CFD simulation is powerful for providing detailed information on flow properties and performing parametric studies for process design and optimization. In this project, comprehensive 3-D CFD models have been developed to simulate the PCI process under actual furnace conditions. These models provide raceway size and flow property distributions. The results have provided guidance for optimizing the PCI process

  6. PALLADIUM/COPPER ALLOY COMPOSITE MEMBRANES FOR HIGH TEMPERATURE HYDROGEN SEPARATION FROM COAL-DERIVED GAS STREAMS; F

    International Nuclear Information System (INIS)

    J. Douglas Way; Robert L. McCormick

    2001-01-01

    Recent advances have shown that Pd-Cu composite membranes are not susceptible to the mechanical, embrittlement, and poisoning problems that have prevented widespread industrial use of Pd for high temperature H(sub 2) separation. These membranes consist of a thin ((approx)10(micro)m) film of metal deposited on the inner surface of a porous metal or ceramic tube. Based on preliminary results, thin Pd(sub 60)Cu(sub 40) films are expected to exhibit hydrogen flux up to ten times larger than commercial polymer membranes for H(sub 2) separation, and resist poisoning by H(sub 2)S and other sulfur compounds typical of coal gas. Similar Pd-membranes have been operated at temperatures as high as 750 C. The overall objective of the proposed project is to demonstrate the feasibility of using sequential electroless plating to fabricate Pd(sub 60)Cu(sub 40) alloy membranes on porous supports for H(sub 2) separation. These following advantages of these membranes for processing of coal-derived gas will be demonstrated: High H(sub 2) flux; Sulfur tolerant, even at very high total sulfur levels (1000 ppm); Operation at temperatures well above 500 C; and Resistance to embrittlement and degradation by thermal cycling. The proposed research plan is designed to providing a fundamental understanding of: Factors important in membrane fabrication; Optimization of membrane structure and composition; Effect of temperature, pressure, and gas composition on H(sub 2) flux and membrane selectivity; and How this membrane technology can be integrated in coal gasification-fuel cell systems

  7. Study of mechanically activated coal combustion

    Directory of Open Access Journals (Sweden)

    Burdukov Anatolij P.

    2009-01-01

    Full Text Available Combustion and air gasification of mechanically activated micro-ground coals in the flux have been studied. Influence of mechanically activated methods at coals grinding on their chemical activeness at combustion and gasification has been determined. Intense mechanical activation of coals increases their chemical activeness that enables development of new highly boosted processing methods for coals with various levels of metamorphism.

  8. Enrichment of coal pulps by selective flocculation

    Energy Technology Data Exchange (ETDEWEB)

    Blaschke, Z

    1977-01-01

    The results are presented of selective flocculation of coal pulps using different reagents. In some tests the coal particles were flocculated, and in others the coal remained in suspension and the dirt was flocculated. Selective flocculation makes it possible to obtain coal concentrates with a very low ash content from slurries with a high ash content. (In Polish)

  9. Enrichment of coal pulps by selective flocculation

    Energy Technology Data Exchange (ETDEWEB)

    Blaschke, Z

    1977-01-01

    The results are presented of selective flocculation of coal pulps using different reagents. In some tests the coal particles were flocculated, and in others the coal remained in suspension and the dirt was flocculated. Selective flocculation makes it possible to obtain coal concentrates with a very low ash content from slurries with a high ash content.

  10. Heavy coal combustion as the dominant source of particulate pollution in Taiyuan, China, corroborated by high concentrations of arsenic and selenium in PM10

    International Nuclear Information System (INIS)

    Xie, RuiKai; Seip, Hans Martin; Wibetoe, Grethe; Nori, Showan; McLeod, Cameron William

    2006-01-01

    Coal burning generates toxic elements, some of which are characteristic of coal combustion such as arsenic and selenium, besides conventional coal combustion products. Airborne particulate samples with aerodynamic diameter less than 10 μm (PM 10 ) were collected in Taiyuan, China, and multi-element analyses were performed by inductively coupled plasma atomic emission spectrometry (ICP-AES) and inductively coupled plasma mass spectrometry (ICP-MS). Concentrations of arsenic and selenium from ambient air in Taiyuan (average 43 and 58 ng m -3 , respectively) were relatively high compared to what is reported elsewhere. Arsenic and selenium were found to be highly correlated (r=0.997), indicating an overwhelmingly dominant source. Correlation between these two chalcophile elements and the lithophile element Al is high (r is 0.75 and 0.72 for As and Se, respectively). This prompted the hypothesis that the particles were from coal combustion. The enrichment of the trace elements could be explained by the volatilization-condensation mechanism during coal combustion process. Even higher correlations of arsenic and selenium with PM 10 (r=0.90 and 0.88) give further support that airborne particulate pollution in Taiyuan is mainly a direct result of heavy coal consumption. This conclusion agrees with the results from our previous study of individual airborne particles in Taiyuan. (author)

  11. Strange and non-strange baryon and antibaryon production in sulphur-tungsten and sulphur-sulphur interactions at 200 A Gev/c

    Energy Technology Data Exchange (ETDEWEB)

    Holme, A.K.

    1995-11-01

    The author has studied production of strange and multistrange baryons and antibaryons in central sulphur-tungsten, sulphur-sulphur, and lead-lead interactions at relativistic energies. The spectra of strange baryons and antibaryons provide information about the dynamics of hadronic matter under the extreme conditions realised in these collisions. The particle ratios allow the degree and the nature of the flavour equilibrium to be studied, while the transverse mass distributions provide independent information of the temperatures achieved. 143 refs.

  12. Strange and non-strange baryon and antibaryon production in sulphur-tungsten and sulphur-sulphur interactions at 200 A Gev/c

    International Nuclear Information System (INIS)

    Holme, A.K.

    1995-11-01

    The author has studied production of strange and multistrange baryons and antibaryons in central sulphur-tungsten, sulphur-sulphur, and lead-lead interactions at relativistic energies. The spectra of strange baryons and antibaryons provide information about the dynamics of hadronic matter under the extreme conditions realised in these collisions. The particle ratios allow the degree and the nature of the flavour equilibrium to be studied, while the transverse mass distributions provide independent information of the temperatures achieved. 143 refs

  13. Radiation-thermal processes of conversion in the coals

    International Nuclear Information System (INIS)

    Mustafaev, I.I.

    2002-01-01

    steam and carbon dioxide. c)Desulphurization The application of radiation action to desulphurization of solid fuels is perspectively. At the radiation action it is possible the occurrence selective activation of sulphuric bounds. Pulse electric discharge, laser, microwave vibration, high frequency electric field, can effectively activate desulphurization processes as a result of stimulation of pyrite decomposition. In this work were investigated the stimulation of the sulphur removal processes at the radiation thermal hydro desulphurization of brown coal in presence of the methane. The radiation-thermal desulphurization of brown coal (So=4%) in presence of methane, oxygen, steam and argon under the accelerated electrons with dose rate P=350 Gy/s in the intervals of temperature T=200-500 degrees centigrade, absorbed dose up to 60 kGy have been studied. d)Production and modification of active carbon: In the thermal processes of carbonization of raw materials (coals, polymers, natural compounds, etc) the micro- and macroporous in the product are cleaned non-completely, the part of sorption ability is lost. In case of using of ionizing radiation due to a high penetrating ability and destructive effect these pores are cleaned of tarry matters. By radiation-thermal impact on semi coke of brown coal the high quality activated carbon with adsorption capacity V=0.55 ml/g are produced. In case of modification of carbonic adsorbent it is possible to increase of the specific surface in 2 times at absorbed doses 250 kGy and temperature 300-350 0 C. e) Influence of preirradiation on optical and paramagnetic properties of coals. It has been shown, that at g-preirradiation of lignites in low doses ( 100 kGy) - polycondensation processes. By Application of Electron-spin Resonance and Infra-red Spectroscopy were measured of effectivity destructive and polycondensation processes

  14. Petrography and rank of the Bhangtar coals, southeastern Bhutan

    Energy Technology Data Exchange (ETDEWEB)

    Pareek, H S [BH23, Meerut (India)

    1990-07-01

    In Bhutan, a potential coal deposit is exposed at Bhangtar in the 'landslide zone'. Nineteen coal seams are encountered in this area, and occur in the Lower Gondwana Supergroup preserved in between the Main Boundary Fault and the Thrust. The coal is low in moisture, {lt}1.76%, but the coal cores show moisture values of 3.16%. The ash content is up to 48.87% and increases substantially in the younger seams. The volatile content (on a pure coal basis) ranges from 23.38% to 41.02%. The sulphur content is less than 0.61%. The coals are non-coking. The amount of trace elements in the coal is quite low. The average petrographic composition of the Bhangtar coal is vitrinite - 31%, exinite - 2%, inertinite - 31%, and mineral and shaly matter - 36%, the vitrinite proportion decreases from the older to the younger seams, which are shaly. an age can be assigned to the Bhangtar coal. Based on oil reflectance, the rank of the coal is metalignitous to hypobituminous. The average microlithotype composition of the coal is vitrite - 30%, clarite - 1%, vitrinertite V - 14%, vitrinertite I - 11%, durite - 3%, fusite - 14%, and carbominerite - 27%. Vitrite decreases in proportion towards the younger seams, 'intermediates' show a concomitant increase, while durite and fusite remain constant. Carbonaceous shale contains fragmentary inertinite and vitrinite macerals and is interlayered with micro-bands of shaly coal which is characterised by abundant fragments of fusinite and vitrinite. The coal is very fragile and thus amenable to economic beneficiation. The coal is used as fuel in electric power plants. The Bhangtar coal is characteristically distinct from the Gondwana coals of India in petrography and rank, but correlates petrographically with the Kameng coals of Arunachal Pradesh, India. 18 refs., 4 figs., 8 tabs., 3 plates.

  15. The new deal of coal

    International Nuclear Information System (INIS)

    Kalaydjian, F.; Cornot-Gandolphe, S.

    2008-01-01

    While coal appears as an inescapable resource to answer the energy needs of the 21. century, its highly CO 2 emitting combustion represents a major risk with respect to the requirements of the fight against climate change. In the first part of this book, the basic aspects of energy markets are explained and in particular the role that coal is going to play in the world's energy supplies. In the second part, the new coal usages are presented, which, combined with CO 2 capture and sequestration techniques, should allow to conciliate a massive use of coal and the respect of environmental constraints. This book is based on the works presented in February 2008 by the French institute of petroleum (IFP) about the new outlets of coal and the risks for climate change. Content: 1 - coal, energy of the 21. century: abundant and well distributed reserves; growing up world production; exponential world demand; international trade: still limited but in full expansion; 2 - Technologies for a CO 2 -free coal: CO 2 capture and sequestration technologies; towards poly-generation; production of coal-derived liquid fuels; 3 - Appendices: coals formation; coal in China: status and perspectives; coal in the USA: status and perspectives; coal in India: status and perspectives; COACH: an ambitious European project; CBM - E-CBM, status and perspectives. (J.S.)

  16. Quantitative Aspects of Sulphur Metabolism in the Ruminant

    Energy Technology Data Exchange (ETDEWEB)

    Landis, J. [Institut fuer Tierernaehrung, Eidgenoessische Technische Hochschule, Zurich (Switzerland)

    1968-07-01

    In a series of four experiments {sup 35}S sulphate was given intra-ruminally to lactating dairy goats at feeding times (twice daily) during periods of 10 to 11 d. Rumen contents were sampled on the 8th, 9th and 10th day of {sup 35}S application. Radioactivity was determined in the volatile sulphur fraction (sulphide-sulphur) and in protein-bound sulphur (fraction insoluble in trichloroacetic acid). The ratio between the specific activities of protein sulphur and of sulphide sulphur was considered to be an estimate for that fraction of sulphur-containing amino acids present in the proteins of rumen contents, which was synthesized by microorganisms. This interpretation is based on the assumption that sulphide is the most important source of inorganic sulphur for the synthesis of sulphur amino acids and that incorporation of inorganic sulphur compounds of a a higher state of oxidation into organic molecules may quantitatively be neglected. In three experiments the animals received rations containing 16% to 17% crude protein. In these experiments the ratio of specific activities of protein and sulphide sulphur was found to vary from 0.32 to 0.41. According to the assumptions mentioned above, this would indicate that 32 to 41% of the total amount of protein-bound sulphur amino acids were synthesized by microorganisms from inorganic (sulphide) sulphur. In the fourth experiment the animal received a ration containing only 10% protein but supplemented with urea to bring the total crude protein content to 13%. In this experiment the ratio of specific activities was 0.70, indicating a much higher contribution of microbial synthesis of sulphur amino acids than in the experiments with a more abundant protein supply. The time course of the specific activity of protein-bound-sulphur in the milk is taken as a reference base for an interpretation of labelling of body proteins in terms of turnover rates.

  17. The shell coal gasification process

    Energy Technology Data Exchange (ETDEWEB)

    Koenders, L.O.M.; Zuideveld, P.O. [Shell Internationale Petroleum Maatschappij B.V., The Hague (Netherlands)

    1995-12-01

    Future Integrated Coal Gasification Combined Cycle (ICGCC) power plants will have superior environmental performance and efficiency. The Shell Coal Gasification Process (SCGP) is a clean coal technology, which can convert a wide range of coals into clean syngas for high efficiency electricity generation in an ICGCC plant. SCGP flexibility has been demonstrated for high-rank bituminous coals to low rank lignites and petroleum coke, and the process is well suited for combined cycle power generation, resulting in efficiencies of 42 to 46% (LHV), depending on choice of coal and gas turbine efficiency. In the Netherlands, a 250 MWe coal gasification combined cycle plant based on Shell technology has been built by Demkolec, a development partnership of the Dutch Electricity Generating Board (N.V. Sep). The construction of the unit was completed end 1993 and is now followed by start-up and a 3 year demonstration period, after that the plant will be part of the Dutch electricity generating system.

  18. Identification and quantification of priority species from coal combustion

    Energy Technology Data Exchange (ETDEWEB)

    Furimsky, E.; Zheng, L.; Hlavacek, T. [Canada Centre for Mineral and Energy Technology, Ottawa, ON (Canada). Energy Research Laboratories

    1996-07-01

    The objective is to quantify and characterize emissions from pulverized coal combustion of seven coals and the circulating fluidized bed combustion of four coals. The species of particular interest are sulphur, nitrogen, chlorine, arsenic, mercury, lead, cadmium, potassium, and sodium. The Facility for Analysis of Chemical Thermodynamics (F{asterisk}A{asterisk}C{asterisk}T) method is used to predict type and amount of priority species. Prediction is made for combustion with and without the presence of limestone. The results show that the combustion technology used influences the amount of priority species emitted. 16 tabs., 3 apps.

  19. Galactic evolution of sulphur as traced by globular clusters

    Science.gov (United States)

    Kacharov, N.; Koch, A.; Caffau, E.; Sbordone, L.

    2015-05-01

    Context. Sulphur is an important volatile α element, but its role in the Galactic chemical evolution is still uncertain, and more observations constraining the sulphur abundance in stellar photospheres are required. Aims: We derive the sulphur abundances in red giant branch (RGB) stars in three Galactic halo globular clusters (GC) that cover a wide metallicity range (-2.3 noise (S/N ~ 200 per px) spectra in the region of the S I multiplet 3 at 1045 nm for 15 GC stars selected from the literature (six stars in M 4,six stars in M 22, and three stars in M 30). Multiplet 3 is better suited for S abundance derivation than the more commonly used lines of multiplet 1 at 920 nm, since its lines are not blended by telluric absorption or other stellar features at low metallicity. Results: We used spectral synthesis to derive the [S/Fe] ratio of the stars assuming local thermodynamic equilibrium (LTE). We find mean [S/Fe]LTE = 0.58 ± 0.01 ± 0.20 dex (statistical and systematic error) for M 4, [S/Fe]LTE = 0.57 ± 0.01 ± 0.19 dex for M 22, and [S/Fe]LTE = 0.55 ± 0.02 ± 0.16 dex for M 30. The negative NLTE corrections are estimated to be in the order of the systematic uncertainties. We do not detect star-to-star variations of the S abundance in any of the observed GCs, with the possible exception of two individual stars, one in M 22 and one in M 30, which appear to be highly enriched in S. Conclusions: With the tentative exception of two stars with measured high S abundances, we conclude that sulphur behaves like a typical α element in the studied Galactic GCs, showing enhanced abundances with respect to the solar value at metallicities below [Fe/H]-1.0 dex without a considerable spread. Based on observations made with ESO telescopes at the La Silla Paranal Observatory under programmes ID 091.B-0171(A).The reduced spectra and the best fit synthetic models are available at the CDS via anonymous ftp to http://cdsarc.u-strasbg.fr (ftp://130.79.128.5) or via http://cdsarc

  20. Single particle aerosol mass spectrometry of coal combustion particles associated with high lung cancer rates in Xuanwei and Fuyuan, China.

    Science.gov (United States)

    Lu, Senlin; Tan, Zhengying; Liu, Pinwei; Zhao, Hui; Liu, Dingyu; Yu, Shang; Cheng, Ping; Win, Myat Sandar; Hu, Jiwen; Tian, Linwei; Wu, Minghong; Yonemochi, Shinich; Wang, Qingyue

    2017-11-01

    Coal combustion particles (CCPs) are linked to the high incidence of lung cancer in Xuanwei and in Fuyuan, China, but studies on the chemical composition of the CCPs are still limited. Single particle aerosol mass spectrometry (SPAMS) was recently developed to measure the chemical composition and size of single particles in real-time. In this study, SPAMS was used to measure individual combustion particles emitted from Xuanwei and Fuyuan coal samples and the results were compared with those by ICP-MS and transmission electron microscopy (TEM). The total of 38,372 particles mass-analyzed by SPAMS can be divided into 9 groups based on their chemical composition and their number percentages: carbonaceous, Na-rich, K-rich, Al-rich, Fe-rich, Si-rich, Ca-rich, heavy metal-bearing, and PAH-bearing particles. The carbonaceous and PAH-bearing particles are enriched in the size range below 0.56 μm, Fe-bearing particles range from 0.56 to 1.0 μm in size, and heavy metals such as Ti, V, Cr, Cu, Zn, and Pb have diameters below 1 μm. The TEM results show that the particles from Xuanwei and Fuyuan coal combustion can be classified into soot aggregates, Fe-rich particles, heavy metal containing particles, and mineral particles. Non-volatile particles detected by SPAMS could also be observed with TEM. The number percentages by SPAMS also correlate with the mass concentrations measured by ICP-MS. Our results could provide valuable insight for understanding high lung cancer incidence in the area. Copyright © 2017 Elsevier Ltd. All rights reserved.

  1. Fractal and variability analysis of simulations in ozone level due to oxides of nitrogen and sulphur

    Science.gov (United States)

    Bhardwaj, Rashmi; Pruthi, Dimple

    2017-10-01

    Air pollution refers to the release of pollutants into the air. These pollutants are detrimental to human the planet as a whole. Apart from causing respiratory infections and pulmonary disorders, rising levels of Nitrogen Dioxide is worsening ozone pollution. Formation of Ground-level ozone involves nitrogen oxides and volatile gases in the sunlight. Volatile gases are emitted from vehicles primarily. Ozone is harmful gas and its exposure can trigger serious health effects as it damages lung tissues. In order to decrease the level of ozone, level of oxides leading to ozone formation has to be dealt with. This paper deals with the simulations in ozone due to oxides of nitrogen and sulphur. The data from Central Pollution Control Board shows positive correlation for ozone with oxides of sulphur and nitrogen for RK Puram, Delhi in India where high concentration of ozone has been found. The correlation between ozone and sulphur, nitrogen oxides is moderate during summer while weak during winters. Ozone with nitrogen and sulphur dioxide follow persistent behavior as Hurst exponent is between 0.5 and 1. The fractal dimension for Sulphur dioxide is 1.4957 indicating the Brownian motion. The behavior of ozone is unpredictable as index of predictability is close to zero.

  2. Sulphur mustard degradation on zirconium doped Ti-Fe oxides

    Energy Technology Data Exchange (ETDEWEB)

    Stengl, Vaclav, E-mail: stengl@iic.cas.cz [Department of Solid State Chemistry, Institute of Inorganic Chemistry AS CR v.v.i 250 68 Husinec-Rez (Czech Republic); Grygar, Tomas Matys [Department of Solid State Chemistry, Institute of Inorganic Chemistry AS CR v.v.i 250 68 Husinec-Rez (Czech Republic); Oplustil, Frantisek; Nemec, Tomas [Military Technical Institute of Protection Brno Veslarska 230, 628 00 Brno (Czech Republic)

    2011-09-15

    Highlights: {yields} New stechiometric materials for sulphur mustard degradation. {yields} High degree of degradation, more then 95% h{sup -1}. {yields} One-pot synthesis procedure. - Abstract: Zirconium doped mixed nanodispersive oxides of Ti and Fe were prepared by homogeneous hydrolysis of sulphate salts with urea in aqueous solutions. Synthesized nanodispersive metal oxide hydroxides were characterised as the Brunauer-Emmett-Teller (BET) surface area and Barrett-Joiner-Halenda porosity (BJH), X-ray diffraction (XRD), infrared (IR) spectroscopy, scanning electron microscopy (SEM) with energy-dispersive X-ray (EDX) microanalysis, and acid-base titration. These oxides were taken for an experimental evaluation of their reactivity with sulphur mustard (chemical warfare agent HD or bis(2-chloroethyl)sulphide). The presence of Zr{sup 4+} dopant tends to increase both the surface area and the surface hydroxylation of the resulting doped oxides in such a manner that it can contribute to enabling the substrate adsorption at the oxide surface and thus accelerate the rate of degradation of warfare agents. The addition of Zr{sup 4+} to the hydrolysis of ferric sulphate with urea shifts the reaction route and promotes formation of goethite at the expense of ferrihydrite. We discovered that Zr{sup 4+} doped oxo-hydroxides of Ti and Fe exhibit a higher degradation activity towards sulphur mustard than any other yet reported reactive sorbents. The reaction rate constant of the slower parallel reaction of the most efficient reactive sorbents is increased with the increasing amount of surface base sites.

  3. NA35: sulphur-gold collision

    CERN Multimedia

    1991-01-01

    In this image the real particles produced by the collision of a 6400 GeV sulphur ion with a gold target can be seen as they pass through a streamer chamber. Streamer chambers consist of a gas chamber through which a strong pulsed electric field is passed, creating sparks as a charged particle passes through it. The NA35 experiment, which was in operation in the 1980s, was part of CERN's ongoing heavy ion project.

  4. K lines in the sulphur isonuclear sequence

    International Nuclear Information System (INIS)

    Palmeri, P.; Mendoza, C.; Bautista, M.A.; Garcia, J.; Kallman, T.R.

    2006-01-01

    Accurate and complete sets of atomic data are being computed for the radiative and Auger processes giving rise to K lines in ions of sulphur. AUTOSTRUCTURE, HFR and BPRM codes are used, taking into account configuration interaction, core relaxation and relativistic effects so as to generate data following an approach used in our previous studies on iron and oxygen. Level energies, wavelengths, A-values and Auger rates are compared with available measurements and previous calculations

  5. Sulphur mountain: Cosmic ray intensity records

    International Nuclear Information System (INIS)

    Venkatesan, D.; Mathews, T.

    1985-01-01

    This book deals with the comic ray intensity registrations at the Sulphur Mountain Cosmic Ray Laboratory. The time series of intensity form a valuable data-set, for studying cosmic ray intensity variations and their dependence on solar activity. The IGY neutron monitor started operating from July 1, 1957 and continued through 1963. Daily mean values are tabulated for the period and these are also represented in plots. This monitor was set up by the National Research Council of Canada

  6. National Coal Quality Inventory (NACQI)

    Energy Technology Data Exchange (ETDEWEB)

    Robert Finkelman

    2005-09-30

    The U.S. Geological Survey (USGS) conducted the National Coal Quality Inventory (NaCQI) between 1999 and 2005 to address a need for quality information on coals that will be mined during the next 20-30 years. Collaboration between the USGS, State geological surveys, universities, coal burning utilities, and the coal mining industry plus funding support from the Electric Power Research Institute (EPRI) and the U.S. Department of Energy (DOE) permitted collection and submittal of coal samples for analysis. The chemical data (proximate and ultimate analyses; major, minor and trace element concentrations) for 729 samples of raw or prepared coal, coal associated shale, and coal combustion products (fly ash, hopper ash, bottom ash and gypsum) from nine coal producing States are included. In addition, the project identified a new coal reference analytical standard, to be designated CWE-1 (West Elk Mine, Gunnison County, Colorado) that is a high-volatile-B or high-volatile-A bituminous coal with low contents of ash yield and sulfur, and very low, but detectable contents of chlorine, mercury and other trace elements.

  7. Development of a high-performance, coal-fired power generating system with a pyrolysis gas and char-fired high-temperature furnace

    International Nuclear Information System (INIS)

    Shenker, J.

    1995-01-01

    A high-performance power system (HIPPS) is being developed. This system is a coal-fired, combined-cycle plant that will have an efficiency of at least 47 percent, based on the higher heating value of the fuel. The original emissions goal of the project was for NOx and SOx to each be below 0.15 lb/MMBtu. In the Phase 2 RFP this emissions goal was reduced to 0.06 lb/MMBtu. The ultimate goal of HIPPS is to have an all-coal-fueled system, but initial versions of the system are allowed up to 35 percent heat input from natural gas. Foster Wheeler Development Corporation is currently leading a team effort with AlliedSignal, Bechtel, Foster Wheeler Energy Corporation, Research-Cottrell, TRW and Westinghouse. Previous work on the project was also done by General Electric. The HIPPS plant will use a high-Temperature Advanced Furnace (HITAF) to achieve combined-cycle operation with coal as the primary fuel. The HITAF is an atmospheric-pressure, pulverized-fuel-fired boiler/air heater. The HITAF is used to heat air for the gas turbine and also to transfer heat to the steam cycle. its design and functions are very similar to conventional PC boilers. Some important differences, however, arise from the requirements of the combined cycle operation

  8. Development of a high-performance, coal-fired power generating system with a pyrolysis gas and char-fired high-temperature furnace

    Energy Technology Data Exchange (ETDEWEB)

    Shenker, J.

    1995-11-01

    A high-performance power system (HIPPS) is being developed. This system is a coal-fired, combined-cycle plant that will have an efficiency of at least 47 percent, based on the higher heating value of the fuel. The original emissions goal of the project was for NOx and SOx to each be below 0.15 lb/MMBtu. In the Phase 2 RFP this emissions goal was reduced to 0.06 lb/MMBtu. The ultimate goal of HIPPS is to have an all-coal-fueled system, but initial versions of the system are allowed up to 35 percent heat input from natural gas. Foster Wheeler Development Corporation is currently leading a team effort with AlliedSignal, Bechtel, Foster Wheeler Energy Corporation, Research-Cottrell, TRW and Westinghouse. Previous work on the project was also done by General Electric. The HIPPS plant will use a high-Temperature Advanced Furnace (HITAF) to achieve combined-cycle operation with coal as the primary fuel. The HITAF is an atmospheric-pressure, pulverized-fuel-fired boiler/air heater. The HITAF is used to heat air for the gas turbine and also to transfer heat to the steam cycle. its design and functions are very similar to conventional PC boilers. Some important differences, however, arise from the requirements of the combined cycle operation.

  9. Integrated process for synthetic natural gas production from coal and coke-oven gas with high energy efficiency and low emission

    International Nuclear Information System (INIS)

    Man, Yi; Yang, Siyu; Qian, Yu

    2016-01-01

    Highlights: • A novel coal and coke-oven gas to SNG (CGtSNG) process is proposed. • Energy efficiency of CGtSNG increases 8% compared to coal-to-SNG process. • CGtSNG reduces 60% CO_2 emission and 72% effluent discharge. • CGtSNG proposes an idea of using redundant coke-oven gas for producing SNG production. - Abstract: There was a rapid development of coal to synthetic natural gas (SNG) projects in the last few years in China. The research from our previous work and some other researchers have found coal based SNG production process has the problems of environmental pollution and emission transfer, including CO_2 emission, effluent discharge, and high energy consumption. This paper proposes a novel co-feed process of coal and coke-oven gas to SNG process by using a dry methane reforming unit to reduce CO_2 emissions, more hydrogen elements are introduced to improve resource efficiency. It is shown that the energy efficiency of the co-feed process increases by 4%, CO_2 emission and effluent discharge is reduced by 60% and 72%, whereas the production cost decreases by 16.7%, in comparison to the conventional coal to SNG process. As coke-oven gas is a waste gas in most of the coking plant, this process also allows to optimize the allocation of resources.

  10. Development of disposal sorbents for chloride removal from high-temperature coal-derived gases

    Energy Technology Data Exchange (ETDEWEB)

    Krishnan, G.N.; Wood, B.J.; Canizales, A. [and others

    1995-11-01

    The objective of this program is to develop alkali-based disposable sorbents capable of reducing HCl vapor concentrations to less than 1 ppmv in coal gas streams at temperatures in the range 400{degrees} to 750{degrees}C and pressures in the range 1 to 20 atm. The primary areas of focus of this program are investigation of different processes for fabricating the sorbents, testing their suitability for different reactor configurations, obtaining kinetic data for commercial reactor design, and updating the economics of the process.

  11. Inverse gas chromatography determination of some physicochemical parameters of a high rank Colombian coal

    Energy Technology Data Exchange (ETDEWEB)

    Baquero-Haeberlin, M.C.; Rincon, J.M. [Universidad Nacional de Colombia, Santafe de Bogota (Colombia). Departamento de Quimica

    1997-12-31

    Dispersive component of the free surface energy of a Colombian semianthracite type coal - Paramo de Guerrero - was determined by Inverse Gas Chromatography (IGC), at zero coverage injecting the series of n-alkanes at 313, 333, 353 and 373 K. For the retention time, the mass center determination was used instead of the maximum peak in the chromatograms. The free surface energy (-{Delta}G{sub A}) increase linearly with the carbon atom number to the alkanes but is not constant due, probably to the conformational structure of the probes. The IGC study of the adsorption process in function of the temperature, provides the respective Enthalpy and Entropy values. (orig.)

  12. Investigation of thermochemical conversions of coal pitches using high resolution PMR and IR spectroscopy

    Energy Technology Data Exchange (ETDEWEB)

    Kekin, N.A.; Belkina, T.V.; Stepanenko, M.A.; Gordienko, V.G.

    1982-01-01

    The hydrogen bonds in organic compounds present in coal pitch and fractions were investigated by infrared spectroscopy and proton magnetic resonance. The investigation was extended to include pitch that was thermally treated at 360 degrees C to raise the softening point to 85-90 degrees C. The infrared spectra revealed hydrogen present in OH groups, NH groups, COOH groups, unsaturated carbon double bonds, and multiple carbon double bonds. It was also determined that thermal treating increased the hydrogen present in aromatic compounds and decreased hydrogen present in aliphatic forms. (JMT)

  13. Microbial desulfurization of coal

    International Nuclear Information System (INIS)

    Bos, P.; Boogerd, F.C.; Kuenen, J.G.

    1992-01-01

    In recent years, studies have been initiated to explore the possibilities of the use of biological systems in coal technology. This chapter discusses the principles behind the bioprocessing of coal, the advantages and disadvantages, and the economic feasibility of the process. For large-scale, coal-using, energy-producing plants, stack gas cleaning should be the treatment of choice. Biodesulfurization is preferable with industrial, small-scale, energy-producing plants. Treatment of the stack gases of these plants is not advisable because of high investment costs. Finally, it should be realized that biodesulfurization produces a waste stream that needs further treatment. 91 refs

  14. Coal liquefaction becomes viable

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    2005-11-15

    In 2003 the May/June issue of CoalTrans International speculated that coal liquefaction would become viable due to falling coal prices. This has not proved the case but the sustained high oil price is sparking new interest. A survey by Energy Intelligence and Marketing Research during November 2005 revealed a growth in the number of projects under development or at the feasibility stage. The article reports projects in China, the USA, Australia, New Zealand, the Philippines and India. China is commissioning the first wave of large liquefaction plants. The key question is whether other countries, particularly the USA, will follow.

  15. Present state in coal preparation. Stanje u pripremi uglja

    Energy Technology Data Exchange (ETDEWEB)

    Jevremovic, C. (Rudarsko-Geoloski Fakultet, Tuzla (Yugoslavia))

    1990-01-01

    Describes the low technological state of Yugoslav coal enterprises,in particular of those that exploit low grade lignite and brown coal with high ash and sulfur content. Unadjusted coal prices (almost the same price level for low and high energy coal) and absence of stringent laws on environmental pollution are regarded as main reasons for the low technological level of coal preparation and beneficiation plants. Modern preparation equipment for coal classification, coal washing, coal drying and briquetting is pointed out. Advanced coal carbonization and gasification should have a wider application in Yugoslavia for reducing environmental pollution and producing clean fuel.

  16. Australian coal

    Energy Technology Data Exchange (ETDEWEB)

    1985-11-01

    Total export shipments of coal in Australia in the year ending June 30 1985 reached a record of 83.8 Mt. The export trade is expected to bring in an income of 4 billion Australian dollars in the current year making coal Australia's biggest revenue-earning export commodity. This article presents a brief overview of the Australian coal industry with production and export statistics and information on major open pit and underground mines.

  17. Coal - 96

    International Nuclear Information System (INIS)

    Sparre, C.

    1996-09-01

    The report deals mainly with coal consumption, but also gives some information about technology, environmental aspects and markets. Data have been collected by questionnaires or via telephone. The use of steam coal for heating was 0.8 Mtons (down 20% from 1994). Cogeneration plants were the main users. Taxes and environmental reasons cause a reduction of the coal use that will probably continue the next years. Use of steam coal in industry has been constant at a level of 0.7 Mtons. The import of metallurgical coal rests constant at a level of 1.6 Mtons. 1.2 Mtons of coke was produced, and 0.3 Mtons imported. The PFBC-plant at Vaertan, Stockholm used 0.13 Mtons of coal, while some coal fired power plants have been converted to peat and wood fuels. The average price of steam coal imported to Sweden in 1995 was 333 SEK/ton, 6% higher than in 1994. The contract prices for delivery 1996 are about the same as at the end of 1995. All cogeneration plants have some sort of SO 2 removal system, mostly wet-dry. The largest plant, at Vaesteraas, has recently invested in a SCR system for NO x removal. Most other plants are using low NO x burners or SNCR systems, based on ammonia or urea, which reduce the emissions 50 - 70%. Some statistic about the world coal market is also given in the report

  18. Venezuelan coal

    International Nuclear Information System (INIS)

    Vazquez, L.U.

    1991-01-01

    The existence of coal deposits in Venezuela has been known since the early nineteenth century, when the Naricual Mines were discovered in the State of Anzoategui Eastern Venezuela. Through the years the Venezuelan coal business had its ups and downs, but it was not until 1988 that we could properly say that our coal began to play a role in the international market. This paper reports that it is only now, in the nineties, that Venezuelan coal projects have come under a planning, promotional and developmental policy preparing the ground for the great projects Venezuela will have in the not-too-distant future

  19. Formation and retention of methane in coal

    Energy Technology Data Exchange (ETDEWEB)

    Hucka, V.J.; Bodily, D.M.; Huang, H.

    1992-05-15

    The formation and retention of methane in coalbeds was studied for ten Utah coal samples, one Colorado coal sample and eight coal samples from the Argonne Premium Coal Sample Bank.Methane gas content of the Utah and Colorado coals varied from zero to 9 cm{sup 3}/g. The Utah coals were all high volatile bituminous coals. The Colorado coal was a gassy medium volatile bituminous coal. The Argonne coals cover a range or rank from lignite to low volatile bituminous coal and were used to determine the effect of rank in laboratory studies. The methane content of six selected Utah coal seams and the Colorado coal seam was measured in situ using a special sample collection device and a bubble desorbometer. Coal samples were collected at each measurement site for laboratory analysis. The cleat and joint system was evaluated for the coal and surrounding rocks and geological conditions were noted. Permeability measurements were performed on selected samples and all samples were analyzed for proximate and ultimate analysis, petrographic analysis, {sup 13}C NMR dipolar-dephasing spectroscopy, and density analysis. The observed methane adsorption behavior was correlated with the chemical structure and physical properties of the coals.

  20. Impact of pedospheric and atmospheric sulphur nutrition on sulphur metabolism of Allium cepa L., a species with a potential sink capacity for secondary sulphur compounds

    NARCIS (Netherlands)

    Durenkamp, M.; De Kok, L.J.

    Onion (Afflum cepa L.) was able to use atmospheric H2S as sole sulphur source for growth. The foliarly absorbed H2S was rapidly metabolized into water-soluble, non-protein thiol compounds, including cysteine, and subsequently into other sulphur compounds in the shoots. In H2S-exposed plants, the

  1. Development of self-powered wireless high temperature electrochemical sensor for in situ corrosion monitoring of coal-fired power plant.

    Science.gov (United States)

    Aung, Naing Naing; Crowe, Edward; Liu, Xingbo

    2015-03-01

    Reliable wireless high temperature electrochemical sensor technology is needed to provide in situ corrosion information for optimal predictive maintenance to ensure a high level of operational effectiveness under the harsh conditions present in coal-fired power generation systems. This research highlights the effectiveness of our novel high temperature electrochemical sensor for in situ coal ash hot corrosion monitoring in combination with the application of wireless communication and an energy harvesting thermoelectric generator (TEG). This self-powered sensor demonstrates the successful wireless transmission of both corrosion potential and corrosion current signals to a simulated control room environment. Copyright © 2014 ISA. All rights reserved.

  2. Coal: Less than lackluster

    International Nuclear Information System (INIS)

    Doerell, P.

    1994-01-01

    Not many in the world coal industry will remember 1993 as a good year. The reasons for the poor state of affairs were first the weak economic climate, and second, the energy glut. For the first time after expanding steadily since the 70s, seaborne trade in hard coal fell by about 4% to 350M mt. Steam coal accounted for a good half of this volume. While demand continued to rise in the newly industrialized countries of the Pacific area, imports into Europe of both coking coal and steam coal fell sharply. The United States, CIS, and Canada had to accept substantial losses of export volume. Australia, as well as South Africa, Colombia, and Indonesia consolidated their market positions and Poland, too, recorded high volumes available for export. The positive news came from Australia, where in mid-December the New South Wales coal industry reported an increase in the net profit after tax from $A83M (about $55M) to $A98M (about $126M) in 1992/1993. This success was however ascribed less to an improvement in the fundamental mining indicators than to the fall in the Australian dollar and the lowering of corporate tax. The reduction in capital investment by 26% down to $A330M (after the previous year when it had also been cut by 25%) is seen by the chairman of the NSW Coal Assoc. as not auguring well for the industry's ability to meet the forecast growth in demand to the year 2000

  3. Effects of phosphorus, silicon and sulphur on microstructural evolution in austenitic stainless steels during electron irradiation

    International Nuclear Information System (INIS)

    Fukuya, K.; Nakahigashi, S.; Ozaki, S.; Shima, S.

    1991-01-01

    Fe-18Cr-9Ni-1,5Mn austenitic alloys containing phosphorus, silicon and sulphur were irradiated by 1 MeV electrons at 573-773 K. Phosphorus increased the interstitial loop nucleation and decreased the void swelling by increasing void number density and suppressing void growth. Silicon had a similar effect to phosphorus but its effect was weaker than phosphorus. Sulphur enhanced void swelling through increasing the void density. Nickel enrichment at grain boundaries was suppressed only in the alloy containing phosphorus. These phosphorus effects may be explained by a strong interaction with interstitials resulting in a high density of sinks for point defects. (orig.)

  4. Clean Coal Day '94 Hokkaido International Seminar; Clean coal day '94 Hokkaido kokusai seminar

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1994-06-01

    The lectures given at the seminar were 1) Coal energy be friendly toward the earth, 2) Clean coal technology in the United Kingdom, and 3) How clean coal should be in Australia. In lecture 1), remarks are made on the importance of coal and its future, coal that protects forest, whether coal is a dirty fuel, coal combustion tests started relative to environmental pollution, acid rain in China and coal combustion, briquets effective in energy conservation, etc. In lecture 2), remarks are made on the importance of coal utilization in the United Kingdom, current state of coal utilization in power generation, problems related to gasification furnaces, problems related to combustors, problems related to high-temperature gas cleaning, function of cleaning filters, advantages of high-temperature gas treatment, actualities of gas combustors, studies of gas combustors, etc. In lecture 3), remarks are made on Australia's coal situation, problems related to clean coal technology, problems related to coal preparation technology, potentialities of Australian brown coal, coal utilization in power generation, need of new technology development, current state of coal utilization in Australia, coal utilization in metal-making industry, international cooperation on technology, etc. (NEDO)

  5. Clean Coal Day '94 Hokkaido International Seminar; Clean coal day '94 Hokkaido kokusai seminar

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1994-06-01

    The lectures given at the seminar were 1) Coal energy be friendly toward the earth, 2) Clean coal technology in the United Kingdom, and 3) How clean coal should be in Australia. In lecture 1), remarks are made on the importance of coal and its future, coal that protects forest, whether coal is a dirty fuel, coal combustion tests started relative to environmental pollution, acid rain in China and coal combustion, briquets effective in energy conservation, etc. In lecture 2), remarks are made on the importance of coal utilization in the United Kingdom, current state of coal utilization in power generation, problems related to gasification furnaces, problems related to combustors, problems related to high-temperature gas cleaning, function of cleaning filters, advantages of high-temperature gas treatment, actualities of gas combustors, studies of gas combustors, etc. In lecture 3), remarks are made on Australia's coal situation, problems related to clean coal technology, problems related to coal preparation technology, potentialities of Australian brown coal, coal utilization in power generation, need of new technology development, current state of coal utilization in Australia, coal utilization in metal-making industry, international cooperation on technology, etc. (NEDO)

  6. Facile solid-state synthesis of highly dispersed Cu nanospheres anchored on coal-based activated carbons as an efficient heterogeneous catalyst for the reduction of 4-nitrophenol

    Science.gov (United States)

    Wang, Shan; Gao, Shasha; Tang, Yakun; Wang, Lei; Jia, Dianzeng; Liu, Lang

    2018-04-01

    Coal-based activated carbons (AC) were acted as the support, Cu/AC catalysts were synthesized by a facile solid-state reaction combined with subsequent heat treatment. In Cu/AC composites, highly dispersed Cu nanospheres were anchored on AC. The catalytic activity for 4-nitrophenol (4-NP) was investigated, the effects of activation temperature and copper loading on the catalytic performance were studied. The catalysts exhibited very high catalytic activity and moderate chemical stability due to the unique characteristics of the particle-assembled nanostructures, the high surface area and the porous structure of coal-based AC and the good dispersion of metal particles. Design and preparation of non-noble metal composite catalysts provide a new direction for improving the added value of coal.

  7. Co-combustion characteristics and blending optimization of tobacco stem and high-sulfur bituminous coal based on thermogravimetric and mass spectrometry analyses.

    Science.gov (United States)

    Zhang, Kaihua; Zhang, Kai; Cao, Yan; Pan, Wei-ping

    2013-03-01

    Despite much research on co-combustion of tobacco stem and high-sulfur coal, their blending optimization has not been effectively found. This study investigated the combustion profiles of tobacco stem, high-sulfur bituminous coal and their blends by thermogravimetric analysis. Ignition and burnout performances, heat release performances, and gaseous pollutant emissions were also studied by thermogravimetric and mass spectrometry analyses. The results indicated that combustion of tobacco stem was more complicated than that of high-sulfur bituminous coal, mainly shown as fixed carbon in it was divided into two portions with one early burning and the other delay burning. Ignition and burnout performances, heat release performances, and gaseous pollutant emissions of the blends present variable trends with the increase of tobacco stem content. Taking into account the above three factors, a blending ratio of 0–20% tobacco stem content is conservatively proposed as optimum amount for blending. Copyright © 2012 Elsevier Ltd. All rights reserved.

  8. Significance and development of the utilization of brown coal high temperature coke in the economy of the GDR for the period 1964 to 1974

    Energy Technology Data Exchange (ETDEWEB)

    Klose, E.; Heschel, W.

    1979-01-01

    Brown coal high temperature coke production in GDR in the years since 1964 is described. In 1969 the second large brown coal high temperature coking plant, Schwarze Pumpe, went into operation, increasing the total brown coal high temperature coke production to 2 million tons annually. Utilization of the coke size classes in mm from 0-3.15, 3.15-20, 20-31.5, 31.5-45 and greater than 45 mm in the metallurgical, chemical, and energy industries as well as for household heating is shown with figures from 1964, 1970 and 1974. The increasing use of coke in households partly as briquet substitution is also shown (in 1970 42% of the coke was used in households). The substitution of black coal coke by brown coal coke in additional fields of industrial production was also further advanced. Coke production at the Schwarze Pumpe plant is scheduled to increase to 1.6 million tons by 1985 by means of the application of improved coking technologies. Investigations for future industrial solutions to the following coking problems are being conducted: processing coke fines (which make up 10 to 12% of the total produced coke) by briquetting with binders into formed coke, firing coke fines in blast furnaces and power plants, mixed briquetting of coke fines with limestone for carbide production and mixed briquetting of coke and ore fines for metallurgical purposes. (8 refs.) (In German)

  9. Optimal thermionic energy conversion with established electrodes for high-temperature topping and process heating. [coal combustion product environments

    Science.gov (United States)

    Morris, J. F.

    1980-01-01

    Applied research-and-technology (ART) work reveals that optimal thermionic energy conversion (TEC) with approximately 1000 K to approximately 1100 K collectors is possible using well established tungsten electrodes. Such TEC with 1800 K emitters could approach 26.6% efficiency at 27.4 W/sq cm with approximately 1000 K collectors and 21.7% at 22.6 W/sq cm with approximately 1100 K collectors. These performances require 1.5 and 1.7 eV collector work functions (not the 1 eV ultimate) with nearly negligible interelectrode losses. Such collectors correspond to tungsten electrode systems in approximately 0.9 to approximately 6 torr cesium pressures with 1600 K to 1900 K emitters. Because higher heat-rejection temperatures for TEC allow greater collector work functions, interelectrode loss reduction becomes an increasingly important target for applications aimed at elevated temperatures. Studies of intragap modifications and new electrodes that will allow better electron emission and collection with lower cesium pressures are among the TEC-ART approaches to reduced interelectrode losses. These solutions will provide very effective TEC to serve directly in coal-combustion products for high-temperature topping and process heating. In turn this will help to use coal and to use it well.

  10. Selective methods for polyphenols and sulphur dioxide determination in wines.

    Science.gov (United States)

    García-Guzmán, Juan J; Hernández-Artiga, María P; Palacios-Ponce de León, Lourdes; Bellido-Milla, Dolores

    2015-09-01

    A critical review to the methods recommended by international bodies and widely used in the winery industry and research studies was performed. A Laccase biosensor was applied to the selective determination of polyphenols in wines. The biosensor response was characterised and it responds mainly to o-diphenols which are the principal polyphenols responsible for the stability and sensory qualities of wines. The spectrophotometric method to determine free and total sulphur dioxide recommended for beers was applied directly to wines. A sampling of 14 red and white wines was performed and they were analysed for biosensor polyphenol index (IBP) and sulphur dioxide concentration (SO2). The antioxidant capacity by the ABTS(+) spectrophotometric method was also determined. A correlation study was performed to elucidate the influence of the polyphenols and SO2 on the wines stability. High correlations were found between IBP and antioxidant capacity and low correlation between SO2 and antioxidant capacity. To evaluate the benefits of wine drinking a new parameter (IBP/SO2) is proposed. Copyright © 2015 Elsevier Ltd. All rights reserved.

  11. Relationship between sulphate and sulphur dioxide in the air

    Energy Technology Data Exchange (ETDEWEB)

    Fugas, M; Gentilizza, M

    1978-01-01

    The relationship between the sulphate in suspended particulates and sulphur dioxide in the air was studied in various urban and industrial areas. The relationship is best described by the equation y = ax/sup b/, where y is the percentage of the sulphate S in the total S (sulphate and sulphur dioxide) and x is the concentration of the total S in the air. The regression coefficients a and b seem to be characteristics of the area. In urban areas studied so far a was between 316 and 378 and b between -0.74 and -0.83. In industrial areas polluted by dust which contains elevated concentrations of metals a was between 91 and 107 and b between -0.35 and -0.49. In the area polluted by cement dust there was practically no correlation between the sulphate S (%) and the total S, but a relatively high correlation between absolute amounts of the sulphate S and the total S. The relations indicate that the limitation of SO/sub 2/ conversion is influenced by aerosol composition. Aerosols containing certain metals may promote the conversion by a catalytic effect while alkaline substances by increasing the pH. Whether this can only happen in the plume or in the air as well remains to be clarified.

  12. Coal summit II

    Energy Technology Data Exchange (ETDEWEB)

    1983-01-01

    Various papers were presented on world coal trade. Papers include: Poland as a producer and exporter of coal; the dynamics of world coal trade; Cerrejon coal production perspectives; present state of the Australian coal industry; present state of the EC coal market and future prospects; prospects of US coal exports to Europe; forecast of Italian coal supply and demand through 1990; statistics from coal transportation outlook; status of world coal ports.

  13. Passivation of chalcopyrite during the leaching with sulphuric acid solution in presence of sodium nitrate

    Directory of Open Access Journals (Sweden)

    Sokić Miroslav D.

    2010-01-01

    Full Text Available In this work, the process of the chalcopyrite leaching in sulphuric acid solution was investigated. Sodium nitrate was used as oxidant in the leaching process. Chemical reactions of leaching and their thermodynamic possibilities are predicted based on the calculated Gibbs energies and analysis of E−pH diagrams. The negative values of the Gibbs energy show that all chemical reactions are thermodynamically feasible at atmospheric pressure and in a temperature range 25-90°C. At high electrode potential and low pH values, Cu2+, Fe2+ and Fe3+ ions exist in water solutions. The increase of temperature reduces the probability of Fe3+ ion existence in the system. The chalcopyrite concentrate, enriched in the “Rudnik” flotation plant, with 27.08% Cu, 25.12% Fe, 4.15% Zn and 2.28% Pb was used in the work. XRD and DTA analysis of the concentrate reveals that the sample contains mainly the chalcopyrite with small amount of sphalerite. For the description of the reaction of leaching process the leach residuals, obtained at different conditions, were chosen for XRD, TG/DTA and SEM/EDX analyses. The elemental sulphur and chalcopyrite phases identified in leach residuals confirm our prediction that the elemental sulphur is formed during the leaching process. Accordingly, elemental sulphur is the main product of the reaction, while a minor amount of sulphide sulphur is oxidized to sulphate during the leaching. The sulphur formed during the reaction was precipitated at the particle surfaces, and slowed down the leaching rate in the final stage of leaching process. In the initial stage, the reaction rate was controlled by the surface reaction. The mechanism, latter has been changed into a diffusion controlled one.

  14. Direct liquefaction of low-rank coals under mild conditions

    Energy Technology Data Exchange (ETDEWEB)

    Braun, N.; Rinaldi, R. [Max-Planck-Institut fuer Kohlenforschung, Muelheim an der Ruhr (Germany)

    2013-11-01

    Due to decreasing of petroleum reserves, direct coal liquefaction is attracting renewed interest as an alternative process to produce liquid fuels. The combination of hydrogen peroxide and coal is not a new one. In the early 1980, Vasilakos and Clinton described a procedure for desulfurization by leaching coal with solutions of sulphuric acid/H{sub 2}O{sub 2}. But so far, H{sub 2}O{sub 2} has never been ascribed a major role in coal liquefaction. Herein, we describe a novel approach for liquefying low-rank coals using a solution of H{sub 2}O{sub 2} in presence of a soluble non-transition metal catalyst. (orig.)

  15. Coal-fired combined plants and power stations with high-temperature reactors for the energy supply of tomorrow

    International Nuclear Information System (INIS)

    Knizia, K.; Simon, M.

    1989-01-01

    Dwindling resources as well as threatening climatic changes caused by CO 2 seem to make it necessary to increase the energy conversion processes which promise a relief with regard to both problematic situations. Promising are the development of the combined gas and steam turbine process for the electricity generation from coal, as well as that of the high-temperature reactor, which enables besides the generation of electric energy the provision of heat at a high temperature range, too. The combination of these two components in a partly modified form allows, moreover, the provision of a number of gaseous energy carriers. The authors present these two components in detail, describe their development stage, as well as their existing development potential. (orig.) [de

  16. A method for analyzing low statistics high resolution spectra from 210Pb in underground coal miners from Brazil

    International Nuclear Information System (INIS)

    Dantas, A.L.A.; Dantas, B.M.; Lipsztein, J.L.; Spitz, H.B.

    2006-01-01

    A survey conducted by the IRD-CNEN determined that some workers from an underground coal mine in the south of Brazil were exposed to elevated airborne concentrations of 222 Rn. Because inhalation of high airborne concentrations of 222 Rn can lead to an increase of 210 Pb in bone, in vivo measurements of 210 Pb in the skeleton were performed in selected underground workers from this mine. Measurements were performed using an array of high-resolution germanium detectors positioned around the head and knee to detect the low abundant 46.5 keV photon emitted by 210 Pb. The gamma-ray spectra were analyzed using a moving median smoothing function to detect the presence of a photopeak at 46.5 keV. The minimum detectable activity of 210 Pb in the skeleton using this methodology was 50 Bq. (author)

  17. Utilisation of chemically treated coal

    Directory of Open Access Journals (Sweden)

    Bežovská Mária

    2002-03-01

    Full Text Available The numerous application of coal with high content of humic substances are known. They are used in many branches of industry. The complex study of the composition of coal from upper Nitra mines has directed research to its application in the field of ecology and agriculture. The effective sorption layers of this coal and their humic acids can to trap a broad spectrum of toxic harmful substances present in industrial wastes, particularly heavy metals. A major source of humic acids is coal - the most abundant and predominant product of plant residue coalification. All ranks of coal containt humic acids but lignite from Nováky deposit represents the most easily available and concentrated form of humic acids. Deep oxidation of coal by HNO3 oxidation - degradation has been performed to produce water-soluble-organic acids. The possibilities of utilisation of oxidised coal and humic acids to remove heavy metals from waste waters was studied. The residual concentrations of the investigated metals in the aqueous phase were determined by AAs. From the results follows that the samples of oxidised coal and theirs humic acids can be used for the heavy metal removal from metal solutions and the real acid mine water.Oxidised coal with a high content of humic acids and nitrogen is used in agriculture a fertilizer. Humic acids are active component in coal and help to utilize almost quantitatively nitrogen in soil. The humic substances block and stabiliz toxic metal residues already present in soil.

  18. Mineralogical and compositional characteristics of Late Permian coals from an area of high lung cancer rate in Xuan Wei, Yunnan, China: Occurrence and origin of quartz and chamosite

    Energy Technology Data Exchange (ETDEWEB)

    Dai, Shifeng; Zhao, Lei; Cao, Hongzhi; Ren, Deyi [State Key Laboratory of Coal Resources and Safe Mining, China University of Mining and Technology, Beijing 100083 (China); Tian, Linwei [School of Public Health, Chinese University of Hong Kong, Hong Kong SAR (China); Chou, Chen-Lin [Illinois State Geological Survey (Emeritus), 615 East Peabody Drive, Champaign, IL 61820 (United States); Zhou, Yiping; Zhang, Mingquan; Wang, Jumin; Yang, Zong [Yunnan Institute of Coal Geology Prospection, Kunming 650218 (China)

    2008-12-01

    Some townships in Xuan Wei County, Yunnan Province, have one of the highest lung cancer mortality rates in China and the epidemic disease in the area has generally been attributed to the polycyclic aromatic hydrocarbons (PAHs) released from domestic coal burning. However, the cancer-causing culprit is not settled as Tian [Tian, L., 2005. Coal Combustion Emissions and Lung Cancer in Xuan Wei, China. Ph.D. thesis, University of California, Berkeley.] found nanometer quartz in these coals, soot emissions, and lung cancer tissues. We have conducted mineralogical and geochemical studies of the coals from Xuan Wei for the purpose of shedding light on the minerals which may be related to the epidemic lung cancer. In this paper, abundances, modes of occurrence, and origins of minerals and elements in the coals from two mines in Xuan Wei have been studied using optical microscope, low-temperature ashing, X-ray diffraction analysis, scanning electron microscope equipped with energy-dispersive X-ray spectrometer, and inductively-coupled plasma mass spectrometry. The minerals in the coals are mainly composed of quartz, chamosite, kaolinite, and calcite. The particle size of quartz is rather small, mostly less than 20 {mu}m and it is of authigenic origin. Chamosite occurs mainly as cell-fillings. The occurrence of quartz and chamosite indicates that they were derived from the hydrothermal fluids. Epigenetic calcite is derived from calcic fluids. Kaolinite is derived mainly from sediment source region of Kangdian Oldland to the west of coal basin. The composition of Xuan Wei coal is high in SiO{sub 2}, Fe{sub 2}O{sub 3}, TiO{sub 2}, CaO, MnO, V, Co, Ni, Cu, and Zn. The high SiO{sub 2} content is attributed to quartz, and the Fe{sub 2}O{sub 3} content to chamosite. The high Mn and low Mg contents in the coal indicate the inputs of hydrothermal fluids. CaO occurs mainly in epigenetic calcite. Elements Ti, Co, Ni, Cu, Zn, and rare earth elements were derived from the basaltic rocks

  19. Prevention of formation of acid drainage from high-sulfur coal refuse by inhibition of iron- and sulfur-oxidizing microorganisms. 1. Preliminary experiments in controlled shaken flasks

    Energy Technology Data Exchange (ETDEWEB)

    Dugan, P.R.

    1987-01-01

    Changes of pH and sulfate concentration in high-sulfur coal refuse slurries are used as measurements of microbial pyrite oxidation in the laboratory. Sodium lauryl sulfate (SLS), alkylbenzene sulfonate (ABS), benzoic acid (BZ) and combinations of SLS plus BZ and ABS plus BZ effectively inhibited formation of sulfate and acid when added in concentrations greater than 50 mg/l to inoculated 20 or 30% coal refuse slurries. Here 25 mg/l concentrations of SLS, ABS and ABS plus BZ stimulated acid production. Formic, hexanoic, oxalic, propionic, and pyruvic acids at 0.1% concentrations were also effective inhibitors. Four different lignin sulfonates were only slightly effective inhibitors at 0.1% concentrations. It was concluded that acid formation resulting from microbial oxidation in high-sulfur coal refuse can be inhibited. 22 references.

  20. Environmental impacts of nuclear and coal-fired power plants

    International Nuclear Information System (INIS)

    Horyna, J.; Horynova, H.

    1984-01-01

    The current situation in the development of nuclear power in the world and in Czechoslovakia is briefly outlined and the possibilities are discussed of alternative energy resources. The environmental impact is described of conventional power plants firing coal; sulphur and nitrogen oxides are mentioned and their environmental impacts shown. Their quantities and the quantities of other gaseous, liquid and soid wastes produced by coal power plants are given. Annual estimates are presented of radioactive material emissions; trace amount emissions of toxic metals and their ecological risks are shown. Concern over the increasing concentration of CO 2 in the atmosphere is voiced. For nuclear power plants, the amount of radionuclides in stack emission and of those released into water flows is tabulated. Their effect on the aqueous ecosystem is characterized as is thermal pollution of water flows and the environmental impact of cooling towers. Other factors are also mentioned, such as the increased industrial land use, the effect of high voltage transmission lines and aesthetic effects. The conclusion is arrived at that the construction of nuclear power plants will eliminate the adverse environmental impact of emissions while the other impacts of the two types of power plants are comparable. (A.K.)

  1. The recovery of sulphur, uranium and gold from residues in OFS scheme

    International Nuclear Information System (INIS)

    Ruhmer, W.T.; Botha, F.; Adams, J.S.

    1978-01-01

    This article describes a project comprising three plants for the flotation of pyrite, a twin-stream uranium plant in which high-grade slimes and pyrite can be leached separately, a pyrite burning sulphuric acid plant, and a plant for the recovery of gold from calcines. Details of these plants including capital costs and estimate production are given

  2. Reduction of Sulphur Content of Urals Crude Oil Prior to Processing ...

    African Journals Online (AJOL)

    The presence of sulphur in crude oil poses enormous challenges as regards its negative environmental and economic impacts. As such, the safety of the personnel and the equipment is at high risk during the processing of Urals crude oil in Kaduna Refining and Petrochemical Company (KRPC) because of its sour nature.

  3. Aspects of combustion behaviour of coals from some New Zealand lignite-coal regions determined by thermogravimetry

    Energy Technology Data Exchange (ETDEWEB)

    Benfell, K.E.; Beamish, B.B.; Rodgers, K.A. [University of Newcastle, Callaghan, NSW (Australia). Dept. of Geology

    1997-08-25

    The papers describes how thermogravimetric analysis of five Late Cretaceous and Cenozoic New Zealand lignites demonstrate that their combustion behaviour is distinct from that of subbituminous coals and may be characterised by peak temperature of 377-416{degree}C, maximum rate of combustion of 25-31 wt% min{sup -1}, and temperature of char burnout 421-497{degree}C. These parameters reflect variation in thermal behaviour associated with both the organic and inorganic constituents of the coal. The information obtained is additional to that provided by proximate analysis; the latter is insufficient to predict the combustion behaviour of the coals relative to one another. A post-combustion thermal event is seen among the lignites as in other low-rank coals combusting below 600{degree}C, which appears to be related to the organic sulphur content of the coal.

  4. Sulphur levels in saliva as an estimation of sulphur status in cattle: a validation study

    NARCIS (Netherlands)

    Dermauw, V.; Froidmont, E.; Dijkstra, J.; Boever, de J.L.; Vyverman, W.; Debeer, A.E.; Janssens, G.P.J.

    2012-01-01

    Effective assessment of sulphur (S) status in cattle is important for optimal health, yet remains difficult. Rumen fluid S concentrations are preferred, but difficult to sample under practical conditions. This study aimed to evaluate salivary S concentration as estimator of S status in cattle.

  5. Potential to reduce emissions of sulphur dioxide through reducing sulphur levels in heavy and light fuel oils - a discussion paper

    International Nuclear Information System (INIS)

    Tushingham, M.; Bellamy, J.

    2001-01-01

    Background information on the sulphur levels in light fuel oil (used in residential heating) and heavy fuel oil (used as industrial fuel oil) is provided. In addition to the description of sulphur levels in light and heavy fuel oils, the report also provides a summary of regulatory limits in Canada and elsewhere, and a description of the emission benefits of decreasing sulphur in fuels. 4 refs., 10 tabs., 12 figs

  6. International Coal Report's coal year 1991

    Energy Technology Data Exchange (ETDEWEB)

    McCloskey, G [ed.

    1991-05-31

    Following introductory articles on factors affecting trade in coal and developments in the freight market, tables are given for coal exports and coal imports for major countries worldwide for 1989 and 1990. Figures are also included for coal consumption in Canada and the Eastern bloc,, power station consumption in Japan, coal supply and demand in the UK, electric utility coal consumption and stocks in the USA, coal production in Australia, Canada and USA by state, and world hard coal production. A final section gives electricity production and hard coal deliveries in the EEC, sales of imported and local coal and world production of pig iron and steel.

  7. Gas chromatography and silver-ion high-performance liquid chromatography analysis of conjugated linoleic acid isomers in free fatty acid form using sulphuric acid in methanol as catalyst.

    Science.gov (United States)

    Luna, Pilar; Juárez, Manuela; de la Fuente, Miguel Angel

    2008-09-12

    This study used GC and silver-ion HPLC to examine the effects of temperature and time on methylation of individual and mixtures of conjugated linoleic acid (CLA) isomers in free fatty acid form using sulphuric acid as catalyst. In the conditions tested (temperatures between 20 and 50 degrees C and times between 10 and 60 min) methylation was complete while avoiding isomerization of conjugated dienes and the formation of artefacts that could interfere with chromatographic determinations. An analytical method using solvent extraction of the lipids followed by selective elution of the free fatty acids from aminopropyl bonded phase columns and methylation with H(2)SO(4) in mild conditions was then applied to determine the CLA isomers in free fatty acid form in rumen fluid, and the results were evaluated.

  8. Thermal effects from the release of selenium from a coal combustion during high-temperature processing: a review.

    Science.gov (United States)

    Hu, Jianjun; Sun, Qiang; He, Huan

    2018-04-11

    The release of selenium (Se) during coal combustion can have serious impacts on the ecological environment and human health. Therefore, it is very important to study the factors that concern the release of Se from coal combustion. In this paper, the characteristics of the release of Se from coal combustion, pyrolysis, and gasification of different coal species under different conditions are studied. The results show that the amount of released Se increases at higher combustion temperatures. There are obvious increases in the amount of released Se especially in the temperature range of 300 to 800 °C. In addition, more Se is released from the coal gasification than coal combustion process, but more Se is released from coal combustion than pyrolysis. The type of coal, rate of heating, type of mineral ions, and combustion atmosphere have different effects on the released percentage of Se. Therefore, having a good understanding of the factors that surround the release of Se during coal combustion, and then establishing the combustion conditions can reduce the impacts of this toxic element to humans and the environment.

  9. Investigation on the effect of heavy diesel fraction properties on product sulphur during ultra deep diesel hydrodesulphurization

    Energy Technology Data Exchange (ETDEWEB)

    Stratiev, D.; Tzingov, T. [Research and Development Dept., Lukoil Neftochim Bourgas, Bourgas (Bulgaria); Galkin, V. [Future Development Dept., Lukoil Neftochim Bourgas, Bourgas (Bulgaria)

    2006-02-01

    This work investigates the hydrotreatment of heavy diesel fractions in order to achieve product sulphurs of 50 and 10 ppm. The heavy diesel fractions were obtained in the Lukoil Neftochim Bulgaria (LNB) crude distillation and vacuum distillation units (SRGO1, SRGO2, AGO, LVGO ASTM D-86 95%vol. of 360, 392 395, and 377 C respectively) by distillation of crude oil type ''Ural'', containing some quantities of naphtha, atmospheric residue, vacuum gas oil and low sulphur crude oil, in the mild hydrocracking unit (MHC diesel 95%vol. of 389 C) and in the fluid catalytic cracking unit - heavy cycle oil (FCC HCO; 95%vol. of 360 C). The diesel fractions were hydrotreated in a trickle bed pilot plant at following conditions: reactor inlet temperature range of 300-380 C; liquid hourly space velocity (LHSV) range of 0.5-3.0 h{sup -1}, total reactor pressure range of 3.5- 7.0 MPa; treating gas/feedstock ratio of 250 Nm{sup 3}/m{sup 3}. It was found that in the investigated range of operating conditions the product sulphur depended linearly on the LHSV. As a measure of the diesel hydrodesulphurization (HDS) reactivity the LHSV at 360 C reactor inlet temperature was interpolated at a constant product sulphur level of 50 ppm and extrapolated at 10 ppm sulphur. It was found that the most refractory feedstock was the diesel mixture 80%SRGO1 / 20%FCCHCO (LHSV of 0.4 h{sup -1} for 50 ppm and 0.2 h{sup -1} for 10 ppm sulphur). The catalyst volume increase required to reduce the product sulphur from 50 to 10 ppm was found to be as high as twice for all diesel fractions except the MHC diesel. This material required five times the catalyst volume for the product sulphur reduction from 50 to 10 ppm. The total reactor pressure was found to have less impact on the product sulphur than the LHSV. Doubling the reactor pressure from 3.5 to 7.0 MPa by hydrotreatment of LVGO reduced the product sulphur as low as twice while the reduction of the LHSV from 1 to 0.5 h{sup -1} at a

  10. New coal-based energy systems

    International Nuclear Information System (INIS)

    Barnert, H.

    1986-01-01

    Conversion of coal into liquid fuels or into coal gas is considered and the use of high temperature nuclear reactors whose waste heat can be used for remote (district) heating mentioned. The use of high temperature reactors as energy source for coal gasification is also examined and, finally, the extraction of heat from combined coal, steel and high temperature nuclear reactors is suggested. (G.M.E.)

  11. Effect of both sulphur content and deoxidation degree on the hot ductility of resulphurized austenitic stainless steels in the solidified state

    International Nuclear Information System (INIS)

    Botella, J.; Sanchez, R.

    1998-01-01

    The manufacture of free machining austenitic stainless steels features a specific drawback derived from their high sulphur content, which is needed for generating, into the austenitic matrix inclusions to optimize the different machining operations. However, sulphur has ahamfull effect on hot workability. This paper deals with assessing the effect of sulphur content and deoxidation level on the hot ductility of resulphurized austenitic stainless steels in as cast condition. Hot tensile tests were conducted on a Gleeble machine, at temperatures between 1,150 and 1,250 degree celsius, studying a suctility factor as a function of sulphur content, deoxidation degree, as well as type, size and distribution of sulfides. Results point out the harmful effect of increasing sulphur and oxygen contents on the hot workability of resulphurized austenitic stainless steels, and the need to control carefully the level of oxides of these steels. (Author) 5 refs

  12. Quality and petrographic characteristics of the lacustrine Ermenek coal (early Miocene), Turkey

    Energy Technology Data Exchange (ETDEWEB)

    Demirel, I.H.; Karayigit, A.I. [Hacettepe Univ., Beytepe-Ankara (Turkey). Dept. of Geological Engineering

    1999-05-01

    The early Miocene Yenimahalle Formation including alluvial-lacustrine sediments and a mineable coal steam with an average of 5 m in thickness rests unconformably upon the basement and is also unconformably overlain by marine limestones of the middle-late Miocene Mut Formation in the Ermenek coal basin. The coal basin in the present study has been subdivided into two areas, Canakci and Pamuklu-Tepebasi, which are separated by the basement and a fault, in order to determine coal properties in detail. The investigated subbituminous coals with an average of 0.40%Ro huminite reflectance often contain gastropod shells (Planorbidae) which commonly maintain the original aragonite and calcite composition. The coals have similar chemical properties and petrographic composition in the two areas, but their sulphur contents are clearly different. In the Canakci area the coals on an air-dried basis contain distinctly less total sulphur (avg. 1.3%) and organic sulphur contents (0.13--0.15%) than in the Pamuklu-Tepebasi area (avg. 4.5% and 4.25%, respectively). This difference is interpreted to be controlled by mire chemistry and sedimentation during peat formation.

  13. Quality and petrographic characteristics of the Lacustrine Ermenek Coal (Early Miocene), Turkey

    Energy Technology Data Exchange (ETDEWEB)

    Demirel, I.H.; Karayigit, A.I.

    1999-04-15

    The early Miocene Yenimahalle Formation including alluvial-lacustrine sediments and a mineable coal seam with an average of 5 m in thickness rests unconformably upon the basement and is also unconformably overlain by marine limestones of the middle-late Miocene Mut Formation in the Ermenek coal basin. The coal basin in the present study has been subdivided into two areas, Canakci and Pamuklu-Tepebasi, which are separated by the basement and a fault, in order to determine coal properties in detail. The investigated subbituminous coals with an average of 0.40% Ro huminite reflectance often contain gastropod shells (Planorbidae) which commonly maintain the original aragonite and calcite composition. The coals have similar chemical properties and petrographic composition in the two areas, but their sulphur contents are clearly different. In the Canakci area the coals on an air-dried basis contain distinctly less total sulphur (avg. 1.3%) and organic sulphur contents (0.13 0.15%) than in the Pamuklu-Tepebasi area (avg. 4.5% and 4.25%, respectively). This difference is interpreted to be controlled by mire chemistry and sedimentation during peat formation. (author)

  14. The Charfuel coal refining process

    International Nuclear Information System (INIS)

    Meyer, L.G.

    1991-01-01

    The patented Charfuel coal refining process employs fluidized hydrocracking to produce char and liquid products from virtually all types of volatile-containing coals, including low rank coal and lignite. It is not gasification or liquefaction which require the addition of expensive oxygen or hydrogen or the use of extreme heat or pressure. It is not the German pyrolysis process that merely 'cooks' the coal, producing coke and tar-like liquids. Rather, the Charfuel coal refining process involves thermal hydrocracking which results in the rearrangement of hydrogen within the coal molecule to produce a slate of co-products. In the Charfuel process, pulverized coal is rapidly heated in a reducing atmosphere in the presence of internally generated process hydrogen. This hydrogen rearrangement allows refinement of various ranks of coals to produce a pipeline transportable, slurry-type, environmentally clean boiler fuel and a slate of value-added traditional fuel and chemical feedstock co-products. Using coal and oxygen as the only feedstocks, the Charfuel hydrocracking technology economically removes much of the fuel nitrogen, sulfur, and potential air toxics (such as chlorine, mercury, beryllium, etc.) from the coal, resulting in a high heating value, clean burning fuel which can increase power plant efficiency while reducing operating costs. The paper describes the process, its thermal efficiency, its use in power plants, its pipeline transport, co-products, environmental and energy benefits, and economics

  15. Report on the coal type committee meetings in fiscal 1988; 1989 nendo tanshu iinkai hokokusho

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1990-03-01

    This paper is a report on the coal type committee meetings in fiscal 1988. It summarizes the report mainly on the data distributed at the first and second coal type committee meetings. It describes liquefaction performance tests on Chinese coals in the coal type selection and investigation. In order to develop jointly by Japan and China the coal liquefaction technology, liquefaction tests have been performed on Chinese coals since fiscal 1982 by using the small continuous testing equipment (0.1 t/d) installed in the Beijing Soot and Coal Science Research Institute. The test is now in the third phase. The first sub-committee meeting reported the result on the Shenmu Simengou coal. The coal type investigation has analyzed coal samples collected from the world, classified them into brown coal, sub-bituminous coal of low coal rank, sub-bituminous coal, highly volatile bituminous coal of low coal rank, and highly volatile bituminous coal, and presented a list of candidate coals for liquefaction. Regarding the liquefaction performance tests on Chinese coals, the second coal type committee meeting reported the result on the Fuxin Qinghemen coal, and the result on the Tianzhu coal as revealed by using the NEDOL process BSU. The paper also presents the interim report on the research achievements in fiscal 1988 on the liquefaction performance tests on Chinese coals and the research achievements of the investigation and study in fiscal 1988 on the treatment technologies for coals used for coal gasification 'coal type selection and investigation'. (NEDO)

  16. Comparative Study of Coal and Biomass Co-Combustion With Coal Burning Separately Through Emissions Analysis

    OpenAIRE

    Mohammad Siddique; Suhail Ahmed Soomro; Aziza Aftab; Zahid Naeem Qaisrani; Abdul Sattar Jatoi; Asadullah; Ghulamullah Khan; Ehsanullah Kakar

    2016-01-01

    Appropriate eco-friendly methods to mitigate the problem of emissions from combustion of fossil fuel are highly demanded. The current study was focused on the effect of using coal & coal-biomass co-combustion on the gaseous emissions. Different biomass' were used along with coal. The coal used was lignite coal and the biomass' were tree waste, cow dung and banana tree leaves. Various ratios of coal and biomass were used to investigate the combustion behavior of coal-biomass blends and their ...

  17. High Temperature Behavior of Cr3C2-NiCr Coatings in the Actual Coal-Fired Boiler Environment

    Science.gov (United States)

    Bhatia, Rakesh; Sidhu, Hazoor Singh; Sidhu, Buta Singh

    2015-03-01

    Erosion-corrosion is a serious problem observed in steam-powered electricity generation plants, and industrial waste incinerators. In the present study, four compositions of Cr3C2-(Ni-20Cr) alloy coating powder were deposited by high-velocity oxy-fuel spray technique on T-91 boiler tube steel. The cyclic studies were performed in a coal-fired boiler at 1123 K ± 10 K (850 °C ± 10 °C). X-ray diffraction, scanning electron microscopy/energy dispersive X-ray analysis and elemental mapping analysis techniques were used to analyze the corrosion products. All the coatings deposited on T-91 boiler tube steel imparted hot corrosion resistance. The 65 pctCr3C2 -35 pct (Ni-20Cr)-coated T-91 steel sample performed better than all other coated samples in the given environment.

  18. High-performance liquid chromatographic determination of selenium in coal after derivatization to 2,1,3-benzoselenadiazoles

    Energy Technology Data Exchange (ETDEWEB)

    Khuhawar, M.Y.; Bozdar, R.B.; Babar, M.A. (Sindh University, Jamshoro (Pakistan). Inst. of Chemistry)

    1992-11-01

    High-performance liquid chromatography was examined for the determination of selenium after derivatization to 2,1,3-benzoselenadiazoles using 1,2-diaminobenzene, 1,2-diamino-4-nitrobenzene (NDAB), 2,3-diaminonaphthalene and 3,3-diaminobenzidine as derivatizing agents. Elution was carried out using a mixture of chloroform and hexane, with ultraviolet spectrophotometric detection. The 2,1,3-benzoselenadiazoles were extracted into toluene. Linear calibrations were obtained for 0-4[mu]g of selenium in 10 cm[sup 3] of solution and the detection limits were 20-50 ng of selenium in 10 cm[sup 3] of solution. The method was applied to the determination of selenium in coal samples and a shampoo using NDAB as the derivatizing reagent in acidic solution.

  19. SO2 emission reducing by Ca(OH)2 using at combustion of coal from East-Maritsa basin

    International Nuclear Information System (INIS)

    Batov, S.; Gadzhanov, P.; Popov, D.; Panchev, T.; Mikhajlov, Ya.; Shushulov, D.; Grozev, A.

    1997-01-01

    The 'Maritsa-Iztok' coal field contains about 65% of the lignite and 57% of the Bulgarian coal resources.The 'Maritsa-Iztok' lignite coal have a low combustion temperature and high concentration of ashes, moisture and sulfur. The concentration of sulphur oxides emitted is about 800 000 t per year, which is among the highest concentrations for Europe. In order to reduce the sulphur concentration, theoretical and experimental studies have been performed. A determination of the efficiency of some new methods for SO 2 reduction has been done. In this paper the results from experiments using Ca(OH) 2 as reagent, are presented. The experimental facility is a non-cooled combustion chamber which provides the same conditions as in the lignite coal boilers. In the experiments ground and dried lignite coal have been used. The controlled values are O 2 , CO, NO x , SO 2 , as well as the temperature of the hot and cold air and the combustion products after the cooler and absorber. Four different technologies have been performed. The first is adding of Ca(OH) 2 which give about 30% maximal SO 2 reducing for grain size 45μm and Ca/S=1.6. The obtaining of this small size is now difficult. The second technology is introduction of Ca(OH) 2 in the combustion chamber at a temperature 900-1050 o C. The cleaning efficiency is about 48.5% for the optimal concentration of the additive. As a washing of the combustion product with water in the absorber after the desulfurization. The second phase give 20% additional cleaning. Thus the total cleaning effect is 65-70%. The third method used lime washing of the combustion products. For the Bulgarian coal with a great S content it is the most suitable method. It gives a SO 2 cleaning up to 95%. Lime wash with pH=12.3 has been used with various amounts of the reagent. Experiments with different amounts of lime wash and different quality of the coal are performed and the specific reagent consumption has been determined

  20. Converting coal

    Energy Technology Data Exchange (ETDEWEB)

    Avigliano, A. [Bedeschi (Italy)

    2006-10-15

    In September 2005, Bedeschi was commissioned to design and supply a coal unloading, conveying and storage facility for a new raw coal line system within Hatien II Cement Co. The new plant is composed of a grab unloader, a conveyor system, a storage shed with stacking and reclaiming facilities, a complete dedusting system and civil and steel structure engineering. The scope of supply includes a local fabrication portion; however, main components will be imported. The project will be completed in 21 months. The paper looks into the mechanics of loading and unloading coal. 4 figs., 4 photos.

  1. Analysis of anomalous high concentration of lead and selenium and their origin in the main minable coal seam in the Junger coalfield

    Energy Technology Data Exchange (ETDEWEB)

    Li Sheng-sheng; Ren De-yi [State Administration of Work Safety, Beijing (China)

    2006-07-01

    The concentration, occurrence, and geological origin of lead and selenium in the main minable coal seam from the Junger coalfield were studied using inductively coupled plasma mass spectrometry (CICP-MS), instrumental neutron activation analysis (CINAA), scanning electron microscope equipped with an energy-dispersive X-ray spectrometer (SEM-EDX), and optical microscope. The results show that the average concentrations of Pb and Se are as high as 35.7 {mu}g/g and 8.2 {mu}g/g, respectively, which are much higher than those of coals from North China, Guizhou, China, and USA. In addition, their enrichment factors are up to 2.4 and 68.1, respectively. Lead and selenium are significantly enriched in the seam. Lead and selenium mainly exist in galena, clausthalite, and selenio-galena which occur as cell-filling of coal-forming plants and are of chemical-sedimentary origin. 22 refs., 3 figs., 1 tab.

  2. Non-covalent associative structure of coal

    Energy Technology Data Exchange (ETDEWEB)

    Shui, H. [Anhui University of Technology, Maanshan (China). School of Chemistry and Chemical Engineering

    2004-06-01

    The recent progress of non-covalent associative structure of coal and the mechanisms of the carbon disulphide-N-methyl-2-pyrrolidone (CS{sub 2}/NMP) are mixed solvent and the additive addition enhancing the extraction yield of coals are reviewed, and the aggregation behaviour of coal in solid and solution states are presented, and the aggregation behavior of coal in solid and solution states are introduced in this paper. Coal extraction and swelling in organic solvents at room temperature were the most useful methods to understand the associative structure of coal. CS{sub 2}/NMP is a unique solvent to give high extraction yields for some bituminous coals. Some additives such as tetracyanoethylene (TCNE) can dissociate the stronger interactions among coal molecules and enhance the extraction yields of coal in the mixed solvent. 37 refs., 1 fig.

  3. Analyses of Large Coal-Based SOFCs for High Power Stack Block Development

    Energy Technology Data Exchange (ETDEWEB)

    Recknagle, Kurtis P; Koeppel, Brian J

    2010-10-01

    This report summarizes the numerical modeling and analytical efforts for SOFC stack development performed for the coal-based SOFC program. The stack modeling activities began in 2004, but this report focuses on the most relevant results obtained since August 2008. This includes the latter half of Phase-I and all of Phase-II activities under technical guidance of VPS and FCE. The models developed to predict the thermal-flow-electrochemical behaviors and thermal-mechanical responses of generic planar stacks and towers are described. The effects of cell geometry, fuel gas composition, on-cell reforming, operating conditions, cell performance, seal leak, voltage degradation, boundary conditions, and stack height are studied. The modeling activities to evaluate and achieve technical targets for large stack blocks are described, and results from the latest thermal-fluid-electrochemical and structural models are summarized. Modeling results for stack modifications such as scale-up and component thickness reduction to realize cost reduction are presented. Supporting modeling activities in the areas of cell fabrication and loss of contact are also described.

  4. Research of coal flash hydropyrolysis

    Energy Technology Data Exchange (ETDEWEB)

    Zhu, Z.; Zhu, H.; Wu, Y.; Tang, L.; Cheng, L.; Xu, Z. [East China University of Science and Technology, Shanghai (China)

    2001-02-01

    Using x-ray photoelectron spectroscopy (XPS) analyses the organic sufur of seven different Chinese coals and their semi-cokes from flash hydropyrolysis were studied. The results showed that the organic sulfur in coal was alkyal sulfur and thiophene with the peak of XPS located in 163.1-163.5 eV and 164.1-164.5 eV. The relative thiophene content in coal increased with the coal rank. The type of organic sulfur in semi-coke in flash hydropyrolysis was generally thiophene species; its XPS peak also located in 164.1-164.5 eV, and was in accord with its corresponding coal. Total alkyl sulfur and some thiophene sulfur were removed during the flash hydropyrolysis process. The alkyl sulfur had very high activity in hydrogenation reaction. Flash hydropyrolysis was an important new clean-coal technique and had notable desulfurization effect. 13 refs., 2 figs., 4 tabs.

  5. Changes in the content of water-soluble sulphur in the soil after an application of straw and elemental sulphur

    Directory of Open Access Journals (Sweden)

    Pavel Ryant

    2007-01-01

    Full Text Available The changes in the content of water-soluble sulphur in the soil after the application of straw and elemental sulphur (ES were explored in a 2-year vegetation pot experiment. The following variants were included in the experiment: 1 unfertilised control; 2 wheat straw; 3 rape straw; 4 ES; 5 wheat straw + ES; 6 rape straw + ES. The two types of straw were applied in a dose of 32 g of dry matter and elemental sulphur was applied in a dose of 0.42 g per pot, i.e. 6 kg of soil. The unsatisfactory C:N ratio in the straw was optimised to 25:1 by adding nitrogen in urea. Soil samples were taken prior to sowing of the model plant (spring wheat in 2005 and white mustard in 2006 and then in regular monthly intervals until harvesting (5 times a year. The content of water-soluble sulphur in the soil was evaluated by multifactorial analysis of variance monitoring the effect of the crop, date of soil sampling, application of straw and elemental sulphur.The contents of water-soluble sulphur differed statistically significantly (P > 0.999 when growing the individual model plants. When growing white mustard in 2006 the amount of available sulphur was by 1/5 higher and could have been partly affected by the warm year 2006, as compared to 2005 when spring wheat was grown. Significant differences (P > 0.999 were also discovered among the dates of soil sampling; higher values were detected before the sowing of model plants, i.e. after incubation in the winter, during vegetation the content of water-soluble sulphur decreased and sulphur showed the significantly highest values at the harvest of model plants. When wheat straw was applied the sulphur content did not increase and this may be associated with the wide C:S ratio, whereas after the application of rape straw the content of water-soluble sulphur increased by one third more than in the unfertilised control. The application of elemental sulphur also significantly increased the amount of water-soluble sulphur in

  6. Sulfur transformation during rapid hydropyrolysis of coal under high pressure by using a continuous free fall pyrolyzer

    Energy Technology Data Exchange (ETDEWEB)

    W.-C. Xu; M. Kumagai

    2003-02-01

    The behavior of sulfur transformation during rapid hydropyrolysis of coal was investigated using a pressurized, continuous free fall pyrolyzer under the conditions of temperature ranging from 923 to 1123 K and hydrogen pressure up to 5 MPa. The yields of sulfur converted to gas, tar and char were determined, together with the analyses of sulfur form distributions in coals and chars. The results showed that the decomposition of inorganic sulfur species was affected only by the temperature, while the increases in temperature and hydrogen pressure obviously enhanced the removal of organic sulfur from coal. The extent of organic sulfur removal was proportional to the coal conversion, depending on coal type. A significant retention of gaseous sulfur products by the organic matrix of the char was observed during hydropyrolysis of a Chinese coal above 1023 K, even under the pressurized hydrogen atmosphere. The kinetic analysis indicates that the rate of organic sulfur removal from coal was 0.2th-order with respect to the hydrogen pressure, and the activation energy for total sulfur removal and organic sulfur removal is 17 26 and 13 55 kJ/mol, respectively. The low activation energies suggest that the transformation and removal of sulfur from coal might be controlled by the diffusion and/or thermodynamic equilibrium during hydropyrolysis under the pressurized conditions. 29 refs., 10 figs., 3 tabs.

  7. Integration of coal gasification and packed bed CLC for high efficiency and near-zero emission power generation

    NARCIS (Netherlands)

    Spallina, V.; Romano, M.C.; Chiesa, P.; Gallucci, F.; Sint Annaland, van M.; Lozza, G.

    2014-01-01

    A detailed thermodynamic analysis has been carried out of large-scale coal gasification-based power plant cycles with near zero CO2 emissions, integrated with chemical looping combustion (CLC). Syngas from coal gasification is oxidized in dynamically operated packed bed reactors (PBRs), generating a

  8. Efficacy and phytotoicity of lime sulphur in organic apple production

    NARCIS (Netherlands)

    Holb, I.J.; Jong, de P.F.; Heijne, B.

    2003-01-01

    Curative and preventive efficacy and phytotoxicity of lime sulphur spray schedules, based on a warning system, were evaluated in the Netherlands during two growing seasons under field conditions. In most cases, lime sulphur treatments applied either curatively or preventively resulted in

  9. SULPHUR CONTAINING LICKS AND THEIR EFFECT ON THE ...

    African Journals Online (AJOL)

    amounts of sulphur, there are some of particular importance such as the vitamins thiamine and biotin. Sulphur is also ingested in the inorganic sulphide and sulphate forms, fractions of which are utilized in metabolic processes, whereas substantial portions are also excreted. It has been determined that thiol cornpounds.

  10. In Situ Catalytic Pyrolysis of Low-Rank Coal for the Conversion of Heavy Oils into Light Oils

    Directory of Open Access Journals (Sweden)

    Muhammad Nadeem Amin

    2017-01-01

    Full Text Available Lighter tars are largely useful in chemical industries but their quantity is quite little. Catalytic cracking is applied to improve the yield of light tars during pyrolysis. Consequently, in situ upgrading technique through a MoS2 catalyst has been explored in this research work. MoS2 catalyst is useful for the conversion of high energy cost into low energy cost. The variations in coal pyrolysis tar without and with catalyst were determined. Meanwhile, the obtained tar was analyzed using simulated distillation gas chromatograph and Elemental Analyzer. Consequently, the catalyst reduced the pitch contents and increased the fraction of light tar from 50 to 60 wt.% in coal pyrolysis tar. MoS2 catalyst increased the liquid yield from 18 to 33 (wt.%, db and decreased gas yield from 27 to 12 (wt.%, db compared to coal without catalyst. Moreover, it increased H content and hydrogen-to-carbon ratio by 7.9 and 3.3%, respectively, and reduced the contents of nitrogen, sulphur, and oxygen elements by 8.1%, 15.2%, and 23.9%, respectively, in their produced tars compared to coal without catalyst.

  11. Coal competitiveness?

    International Nuclear Information System (INIS)

    Rogeaux, B.

    2006-01-01

    Will coal electrical plants be more competitive in the coming years? Answering this one cannot be limited to merely comparing estimates based on reference electricity production costs. The competitiveness of coal will indeed depend on the final product marketed, as the MWhs are not equal: is the purpose to produce base, half-base MWh? Does the electrical equipment structure require flexible MWh (for instance in the event of significant intermittent renewable energy amounts), and therefore plants able to adjust their power rapidly? But the competitiveness of coal will also depend on many factors that will correct reference cost estimates: uncertainties, risks, externalities. These factors will need to be appreciated on a case by case basis. We introduce some of the reasoning used to better appreciate the future competitiveness of coal, and the main factors conditioning it in three contrasting regions of the world: Europe, USA, china. (author)

  12. CAPTO method application to the quality assessment of Slovak brown coal

    Directory of Open Access Journals (Sweden)

    Turèániová ¼udmila

    1998-09-01

    Full Text Available This paper describes the principle and application of CAPTO (Controlled - atmosphere programmed - temperature oxidation method for the sulphur content valuation in coal. The principle of CAPTO consists in mixing the coal with an inert material (WO3 and oxidation of the sample by a linear increase of temperature to 1000oC. The evolved gases (CO2, H2O, SO2 and NO2 are analyzed by infrared sensors. The method enables the determination of different sulphur forms (sulphidic, elemental, sulphate, organic aromatic and organic non-aromatic, hydrogen, carbon and humidity. The results on Americal coal Illionois No. 6 and Slovakian brown coal Nováky serve as an illustration of the CAPTO method possibility.

  13. Investigation on the Activity Activation and Cementitious Property of Coal Gangue with High Iron and Silica Contents

    Science.gov (United States)

    Wu, Hong; Li, Yu; Teng, Min; Yang, Yu

    2017-11-01

    The activity of coal gangue by thermal activation and composite activation technologies was investigated. The crystal composition, framework structure and morphology change were analyzed by XRD, FT-IR and SEM, respectively. The cementitious property of coal gangue was measured by strength test. The results showed that thermal activation decomposed kaolinite in coal gangue, and formed the metastable structure with a porous state, multiple internal broken bonds and large specific surface areas. Based on thermal activation, the added lime provided the alkaline environment, then this reduced the bond energy of reactant particles and the degree of crystallinity of quartz in coal gangue. The two activation methods could effectively improve the cementitious property of coal gangue based unburned bricks, and that the composite activation technology was superior performance.

  14. Distribution of sulphur into products from waste tire pyrolysis

    International Nuclear Information System (INIS)

    Susa, D.; Haydary, J.; Markos, J.

    2012-01-01

    Tire pyrolysis is getting growing attention as an effective waste tire disposal method in comparison to environmentally less friendly methods like dumping or incineration. But the scrap tire sulphur content can be a potential obstacle to scrap tire utilization as a fuel. In this paper the distribution of sulphur into tire pyrolysis yields, solid (char) and liquid (tar), was investigated. The pyrolysis experiments were carried out under different conditions to determine the partitioning of sulphur into pyrolysis products. The influence of different temperatures and reaction times was investigated in a laboratory flow reactor under nitrogen atmosphere. Solid and liquid residues were collected and analyzed by elemental analysis. The sulphur content in residual char and tar was determined using an elemental analyzer and the sulphur forms in tar were characterized by the X-ray photoelectron spectroscopy (XPS). (Authors)

  15. Study on the coal mixing ratio optimization for a power plant

    Science.gov (United States)

    Jin, Y. A.; Cheng, J. W.; Bai, Q.; Li, W. B.

    2017-12-01

    For coal-fired power plants, the application of blended coal combustion has been a great issue due to the shortage and rising prices of high-rank coal. This paper describes the optimization of blending methods between Xing'an lignite coal, Shaltala lignite coal, Ura lignite coal, and Inner Mongolia bituminous coal. The multi-objective decision-making method based on fuzzy mathematics was used to determine the optimal blending ratio to improve the power plant coal-fired economy.

  16. Natural revegetation of coal fly ash in a highly saline disposal lagoon in Hong Kong

    Energy Technology Data Exchange (ETDEWEB)

    Chu, L.M. [Chinese University of Hong Kong, Hong Kong (China). Dept. of Biology

    2008-08-15

    Question: What is the relationship of the naturally colonizing vegetation and substrate characteristics in fly ash lagoons? Location: West lagoon, Deep Bay, a 13-ha coastal lagoon in Hong Kong in subtropical Southeast Asia. Methods: Vegetation establishment was examined in a coal fly ash lagoon two years after its abandonment to investigate the distribution of vegetation in relationship to the chemical properties of the fly ash in the lagoon. A greenhouse experiment assessed the limits imposed on plant growth in fly ash. Results: The fly ash was saline, slightly alkaline and very poor in organic matter and nitrogen. Ash from bare and vegetated areas differed significantly in their salinity and extractable concentrations of inorganic nitrogen and various metals. Bare ash had a significantly higher conductivity and extractable sodium, aluminum, manganese, potassium. and lead. In total 11 plant species that belonged to seven families were found growing on the fly ash: all species except the shrub Tamarix chinensis were herbaceous. Using discriminant analysis, the most important factors in distinguishing bare and vegetated ashes were conductivity and sodium. Cluster analysis of bare samples gave two distinct groups, one from the periphery of the lagoon, which had lower sodium, conductivity, organic carbon, potassium and copper, and the other from a second group that contained ashes from the central region of the lagoon. Results of the greenhouse experiment showed that the inhibition of plant growth was significantly correlated with the presence of soluble toxic elements in ash. Conclusion: Toxicity and salinity seem to be the major limiting factors to plant establishment in fly ash, and these factors must be ameliorated for the successful reclamation of these fly ash lagoons.

  17. Firing a sub-bituminous coal in pulverized coal boilers configured for bituminous coals

    Energy Technology Data Exchange (ETDEWEB)

    N. Spitz; R. Saveliev; M. Perelman; E. Korytni; B. Chudnovsky; A. Talanker; E. Bar-Ziv [Ben-Gurion University of the Negev, Beer-Sheva (Israel)

    2008-07-15

    It is important to adapt utility boilers to sub-bituminous coals to take advantage of their environmental benefits while limiting operation risks. We discuss the performance impact that Adaro, an Indonesian sub-bituminous coal with high moisture content, has on opposite-wall and tangentially-fired utility boilers which were designed for bituminous coals. Numerical simulations were made with GLACIER, a computational-fluid-dynamic code, to depict combustion behavior. The predictions were verified with full-scale test results. For analysis of the operational parameters for firing Adaro coal in both boilers, we used EXPERT system, an on-line supervision system developed by Israel Electric Corporation. It was concluded that firing Adaro coal, compared to a typical bituminous coal, lowers NOx and SO{sub 2} emissions, lowers LOI content and improves fouling behavior but can cause load limitation which impacts flexible operation. 21 refs., 7 figs., 3 tabs.

  18. The isotopic composition and content of sulphur in soils of Kansk-Achinsk fuel power generation complex

    International Nuclear Information System (INIS)

    Grinenko, L.N.; Grinenko, V.A.

    1991-01-01

    In the 1970s the first phase of a large coal-burning power complex was brought into operation in the Kansk-Achinsk region of the Soviet Union. The target consumption for this complex is 50 x 10 6 tonnes yr -1 and most of this is supplied from local open-pit mines. The emission of SO 2 from this plant caused concern as to its impact on the local environment and prompted a study of the sulphurous depositions. Monitoring the areal extent and distribution of the deposited S and its fate in the environment can be a mammoth task involving continual measurement of many biological and physical factors including atmospheric concentrations, wind speed, emission rates, and forms of S in soil, plants, and animals. A possible alternative for evaluating the amount, distribution, and fate of the emitted S in the ecosystem is stable sulphur isotope analyses since different coals and SO 2 from their combustion often have δ 34 S values differing from those of soils and plants in the region. The study reported here was initiated to see if the δ 34 S values for emissions differed significantly from the natural environment. Assuming that the difference was sufficient, a second objective was to document changes that have occurred in the sulphur isotope compositions of the environmental receptors over time. Soil samples from 23 sites were collected and analysed for S content and δ 34 S values. Coal, cinder and ash collected from furnaces and SO 2 from the combustion products were similarly analysed. Figs and tabs

  19. The fate of injectant coal in blast furnaces: The origin of extractable materials of high molecular mass in blast furnace carryover dusts

    Energy Technology Data Exchange (ETDEWEB)

    Dong, S.N.; Wu, L.; Paterson, N.; Herod, A.A.; Dugwell, D.R.; Kandiyoti, R. [University of London Imperial College of Science & Technology, London (United Kingdom). Dept. of Chemical Engineering

    2005-07-01

    The aim of the work was to investigate the fate of injectant coal in blast furnaces and the origin of extractable materials in blast furnace carryover dusts. Two sets of samples including injectant coal and the corresponding carryover dusts from a full sized blast furnace and a pilot scale rig have been examined. The samples were extracted using 1-methyl-2-pyrrolidinone (NMP) solvent and the extracts studied by size exclusion chromatography (SEC). The blast furnace carryover dust extracts contained high molecular weight carbonaceous material, of apparent mass corresponding to 10{sup 7}-10{sup 8} u, by polystyrene calibration. In contrast, the feed coke and char prepared in a wire mesh reactor under high temperature conditions did not give any extractable material. Meanwhile, controlled combustion experiments in a high-pressure wire mesh reactor suggest that the extent of combustion of injectant coal in the blast furnace tuyeres and raceways is limited by time of exposure and very low oxygen concentration. It is thus likely that the extractable, soot-like material in the blast furnace dust originated in tars is released by the injectant coal. Our results suggest that the unburned tars were thermally altered during the upward path within the furnace, giving rise to the formation of heavy molecular weight (soot-like) materials.

  20. Selective environmental stress from sulphur emitted by continental flood basalt eruptions

    Science.gov (United States)

    Schmidt, Anja; Skeffington, Richard; Thordarson, Thorvaldur; Self, Stephen; Forster, Piers; Rap, Alexandru; Ridgwell, Andy; Fowler, David; Wilson, Marjorie; Mann, Graham; Wignall, Paul; Carslaw, Ken

    2016-04-01

    Several biotic crises during the past 300 million years have been linked to episodes of continental flood basalt volcanism, and in particular to the release of massive quantities of magmatic sulphur gas species. Flood basalt provinces were typically formed by numerous individual eruptions, each lasting years to decades. However, the environmental impact of these eruptions may have been limited by the occurrence of quiescent periods that lasted hundreds to thousands of years. Here we use a global aerosol model to quantify the sulphur-induced environmental effects of individual, decade-long flood basalt eruptions representative of the Columbia River Basalt Group, 16.5-14.5 million years ago, and the Deccan Traps, 65 million years ago. For a decade-long eruption of Deccan scale, we calculate a decadal-mean reduction in global surface temperature of 4.5 K, which would recover within 50 years after an eruption ceased unless climate feedbacks were very different in deep-time climates. Acid mists and fogs could have caused immediate damage to vegetation in some regions, but acid-sensitive land and marine ecosystems were well-buffered against volcanic sulphur deposition effects even during century-long eruptions. We conclude that magmatic sulphur from flood basalt eruptions would have caused a biotic crisis only if eruption frequencies and lava discharge rates had been high and sustained for several centuries at a time.

  1. Di- or polysulphide-bound biomarkers in sulphur-rich geomacromolecules as revealed by selective chemolysis

    Science.gov (United States)

    Kohnen, Math E. l.; Sinninghe Damsté, Jaap S.; Kock-van Dalen, A. c.; Jan, W. De Leeuw

    1991-05-01

    Three types of sulphur-rich high-molecular-weight material in the alkylsulphide, the polar, and the asphaltene fractions isolated from the bitumen of an immature bituminous shale from the Vena del Gesso basin (Italy) were desulphurised using Raney Ni and were treated with MeLi/MeI, a chemical degradation method which cleaves selectively and quantitatively di- or polysulphide linkages. The products formed were characterised by gas chromatography-mass spectrometry. Raney Ni desulphurisation revealed that these S-rich macromolecules are in substantial part composed of sulphur-linked biomarkers with linear, branched, isoprenoid, steroid, hopanoid, and carotenoid carbon skeletons. MeLi/Mel treatment provided evidence that a major part of the total amount of macromolecularly bound biomarkers are linked via di- or polysulphide moieties to the macromolecular network. Since the di- or polysulphide linkages are attached at specific positions of the bound biomarkers it is proposed that they are formed by intermolecular incorporation reactions of HS x- into low-molecular-weight functionalised biological lipids during early diagenesis. The different properties (solubility and molecular weight) of the sulphur-rich macromolecules in the alkylsulphide, the resin, and the asphaltene fractions can be explained simply by differences in degree of sulphur cross-linking.

  2. Hepatobiliary scintigraphy with 99Tcsup(m)-HIDA and 99Tcsup(m)-sulphur colloid

    International Nuclear Information System (INIS)

    Pedersen, S.A.; Oster-Jorgensen, E.; Schoubye, J.; Odense Univ.

    1980-01-01

    The results of a study comparing the ability of 99 Tcsup(m)-sulphur colloid and 99 Tcsup(m)- HIDA to demonstrate circumsribed defects and obstruction of the biliary flow to the intestines are reported. As regards focal liver diseases, colloid scintigraphy (SC) had a nosographic sensitivity and specificity of 0.87 and 0.85, respectively. The corresponding figures for the HIDA scintigraphy were 0.40 and 0.92. Concerning the diagnosis of extrahepatic obstrtuction, sulphur colloid scintigraphy had a nosographic sensitivity and specificity of 0.31 and 0.94. The corresponding figures for HIDA scintigraphy were 0.69 and 0.84. The most frequent cause of false results was pattern of hepatocellular disease in sulphur colloid scans in patients with a longstanding biliary onbstruction. The second most frequent error was due to circumscribed defects in SC as well as in HIDA scans in patients with obstructive diseases and a high value of serum bilirubin. A third source of error was the pattern of an obstruction in HIDA scans in patients with focal diseases. The significance of the star pattern the sulphur colloid scan in patients with obstruction is stressed, as the significance of this pattern not has been evaluated previously. It is concluded that the two different scintigraphic methods are complementary tools in the examination of patients with liver diseases. (orig.) [de

  3. Emissions reduction in the UK: accommodating waste production from sulphur abatement systems

    Energy Technology Data Exchange (ETDEWEB)

    Crofts, C. (British Coal, London (UK). Operational Research Executive)

    1990-01-01

    Concern for the atmosphere environment has resulted in EC legislation limiting sulphur dioxide emissions. The emission limits are being met by the installation of flue gas desulphurisation and advanced coal combustion systems, which produce large quantities of waste for utilisation or disposal. There are now environmental, economic and regulatory reasons for industry to provide comprehensive assessment of waste disposal/utilisation issues during the design stage of a project. This paper considers the management of waste produced from the limestone/gypsum and spray dry FGD processes, and from advanced coal combustion equipment. The assessment shows that environmentally acceptable methods of disposal and utilisation can be identified for these wastes. It is expected that a substantial proportion of FGD gypsum will be utilized in the manufacture of plasterboard, bag plaster and cement. There may also be opportunities for utilisation of spray dry waste and waste from advanced coal combustion systems in structural and agricultural applications. Landfill would be an appropriate form of disposal for the wastes considered in this paper, but utilisation options offer environmentally superior alternatives to disposal justifying further research. 19 refs., 3 figs.

  4. Seasonal and annual variability of coastal sulphur plumes in the northern Benguela upwelling system.

    Science.gov (United States)

    Ohde, Thomas; Dadou, Isabelle

    2018-01-01

    We investigated the seasonal and annual variability of surface sulphur plumes in the northern Benguela upwelling system off Namibia because of their significant impacts on the marine ecosystem, fishing industry, aquaculture farming and tourism due to their toxic properties. We identified the sulphur plumes in ocean colour satellite data of the medium resolution imaging spectrometer (MERIS) for the 2002-2012 time period using the differences in the spectral properties of Namibian Benguela optical water types. The sulphur events have a strong seasonal cycle with pronounced main and off-seasons forced by local and remote-driven processes. The main peak season is in late austral summer and early austral autumn at the beginning of the annual upwelling cycle caused by increasing equatorwards alongshore winds. The sulphur plume activity is high between February and April during the seasonal oxygen minimum associated with the seasonal reduction of cross-shore ventilation of the bottom waters, the seasonal southernmost position of the Angola Benguela Frontal Zone, the seasonal maximum of water mass fractions of South Atlantic and Angola Gyre Central Waters as well as the seasonal arrival of the downwelling coastal trapped waves. The off-season is in austral spring and early austral summer during increased upwelling intensity and enhanced oxygen supply. The annual variability of sulphur events is characterized by very high activities in years 2004, 2005 and 2010 interrupted by periods of lower activity in years 2002 to 2003, 2006 to 2009 and 2011 to 2012. This result can be explained by the relative contributions or adding effects of local and remote-driven forces (from the equatorial area). The probability for the occurrence of sulphur plumes is enhanced in years with a lower annual mean of upwelling intensity, decreased oxygen supply associated with decreased lateral ventilation of bottom waters, more southern position of the Angola Benguela Frontal Zone, increased mass

  5. Seasonal and annual variability of coastal sulphur plumes in the northern Benguela upwelling system.

    Directory of Open Access Journals (Sweden)

    Thomas Ohde

    Full Text Available We investigated the seasonal and annual variability of surface sulphur plumes in the northern Benguela upwelling system off Namibia because of their significant impacts on the marine ecosystem, fishing industry, aquaculture farming and tourism due to their toxic properties. We identified the sulphur plumes in ocean colour satellite data of the medium resolution imaging spectrometer (MERIS for the 2002-2012 time period using the differences in the spectral properties of Namibian Benguela optical water types. The sulphur events have a strong seasonal cycle with pronounced main and off-seasons forced by local and remote-driven processes. The main peak season is in late austral summer and early austral autumn at the beginning of the annual upwelling cycle caused by increasing equatorwards alongshore winds. The sulphur plume activity is high between February and April during the seasonal oxygen minimum associated with the seasonal reduction of cross-shore ventilation of the bottom waters, the seasonal southernmost position of the Angola Benguela Frontal Zone, the seasonal maximum of water mass fractions of South Atlantic and Angola Gyre Central Waters as well as the seasonal arrival of the downwelling coastal trapped waves. The off-season is in austral spring and early austral summer during increased upwelling intensity and enhanced oxygen supply. The annual variability of sulphur events is characterized by very high activities in years 2004, 2005 and 2010 interrupted by periods of lower activity in years 2002 to 2003, 2006 to 2009 and 2011 to 2012. This result can be explained by the relative contributions or adding effects of local and remote-driven forces (from the equatorial area. The probability for the occurrence of sulphur plumes is enhanced in years with a lower annual mean of upwelling intensity, decreased oxygen supply associated with decreased lateral ventilation of bottom waters, more southern position of the Angola Benguela Frontal Zone

  6. Mongolian coal liquefaction test; Mongorutan no ekika tokusei

    Energy Technology Data Exchange (ETDEWEB)

    Yamamoto, H.; Kubo, H. [Mitsui SRC Development Co. Ltd., Tokyo (Japan); Tsedevsuren, T. [National Research Center of Chemistry and Technology of Coal in Mongoria (Mongolia)

    1996-10-28

    This paper describes the results of liquefaction tests of Mongolian coals using an autoclave and a flow micro reactor. Uvdughudag coal, Hootiinhonhor coal, and Shivee-Ovoo coal were used for liquefaction tests with an autoclave. Oil yields of Uvdughudag and Hootiinhonhor coals were 55.56 wt% and 55.29 wt%, respectively, which were similar to that of Wyoming coal. Similar results were obtained, as to produced gas and water yields. These coals were found to be suitable for coal liquefaction. Lower oil yield, 42.55 wt% was obtained for Shivee-Ovoo coal, which was not suitable for liquefaction. Liquefaction tests were conducted for Uvdughudag coal with a flow micro reactor. The oil yield was 55.7 wt%, which was also similar to that of Wyoming coal, 56.1 wt%. Hydrogen consumption of Uvdughudag coal was also similar to that of Wyoming coal. From these, Uvdughudag coal can be a prospective coal for liquefaction. From the distillation distribution of oil, distillate fraction yield below 350{degree}C of Uvdughudag coal was 50.7 wt%, which was much higher than that of Wyoming coal, 35.6 wt%. Uvdughudag coal is a coal with high light oil fraction yield. 2 figs., 5 tabs.

  7. Wet precipitators for sulphuric acid plants

    International Nuclear Information System (INIS)

    Ojanpera, R.O.

    1989-01-01

    Both the service requirements and design construction details have changed considerably in recent years for wet electrostatic precipitators as used for gas cleaning ahead of metallurgical sulphuric acid plants. Increased concern over acid quality has resulted in more emphasis on dust efficiencies compared to collection of acid mist. Also, higher static operating pressures have caused large structural loads on casing and internal components. In this paper these two issues are addressed in the following ways: Recognition that all dusts do not collect similarly. The mechanism by which various dusts collect affect the design of the entire wet gas cleaning system. Use of both traditional and newer materials of construction to accommodate the higher design pressures while still maintaining corrosion resistance

  8. Physico-chemical fracturing and cleaning of coal. [Treatment with CO/sub 2/ in water at high pressure

    Science.gov (United States)

    Sapienza, R.S.; Slegeir, W.A.R.

    1983-09-30

    This invention relates to a method of producing a crushable coal and reducing the metallic values in coal represented by Si, Al, Ca, Na, K, and Mg, which comprises contacting a coal/water mix in a weight ratio of from about 4:1 to 1:6 in the presence of CO/sub 2/ at pressures of about 100 to 1400 psi and a minimum temperature of about 15/sup 0/C for a period of about one or more hours to produce a treated coal/water mix. In the process the treated coal/water mix has reduced values for Ca and Mg of up to 78% over the starting mix and the advantageous CO/sub 2/ concentration is in the range of about 3 to 30 g/L. Below 5 g/L CO/sub 2/ only small effects are observed and above 30 g/L no further special advantages are achieved. The coal/water ratios in the range 1:2 to 2:1 are particularly desirable and such ratios are compatible with coal water slurry applications.

  9. Coal 95

    International Nuclear Information System (INIS)

    Sparre, C.

    1995-01-01

    The report deals with the use of coal and coke in Sweden during 1994. Some information about technology, environmental questions and markets are also given. Data have been collected by questionnaires to major users and by telephone to minor users. Preliminary statistical data from Statistics Sweden have also been used.The use of steam coal for heating purposes has been unchanged during 1994 at a level of 1 Mtons. The production in the cogeneration plants has been constant, but has increased for electricity production. The minor plants have increased their use of forest fuels. The use of steam coal will probably go down in the next years both for heat and cogeneration plants. During the top year 1987 coal was used in 18 hot water and 11 cogeneration plants. 1994 these figures are 3 and 12. Taxes and environmental reasons explain this trend. The use of steam coal in industry has been constant at the level 0.7 Mtons. The import of metallurgical coal in 1993 was 1.6 Mtons, like 1992. Import of 0.3 Mtons of coke gives the total consumption of coke in industry as 1.5 Mtons. the average price of steam coal imported to Sweden was 317 SEK/ton, 3% higher than 1993. All Swedish plants meet their emission limit of dust, SO 2 and NO x as given by county administrations or concession boards. The cogeneration plants all have some SO 2 removal system. The biggest cogeneration plant (Vaesteraas) has recently invested in a SCR NO x cleaning system. Most other plants use low NO x burners or SNR injection systems based on ammonia or urea. 2 figs, 13 tabs

  10. Analysis and Prevention of Geo-Environmental Hazards with High-Intensive Coal Mining: A Case Study in China’s Western Eco-Environment Frangible Area

    Directory of Open Access Journals (Sweden)

    Qiang Sun

    2017-06-01

    Full Text Available This study seeks to address the problems of major geo-environmental hazards caused by high-intensive coal mining in China’s western eco-environment frangible area including strong mining pressure, surface subsidence, soil and water loss, and land desertification. Using the high-intensive mining at the Xiao-jihan Coal Mine, this paper investigates the compaction characteristics of aeolian sand-based backfilling materials, and then the evolution of water-conducting fractures and surface deformation laws with different backfill material’s compression ratios (BMCRs by using physical simulation and numerical simulation analysis methods. This study presents the technical system of water-preserved and environmental protection with rapid-backfilling methods in China’s western eco-environment frangible area. The backfill coal mining technique and application prospects are assessed and discussed. The results will be helpful for coordinated development of coal resources exploitation and environmental protection in China’s western eco-environment frangible area.

  11. Clean coal technology: The new coal era

    Energy Technology Data Exchange (ETDEWEB)

    1994-01-01

    The Clean Coal Technology Program is a government and industry cofunded effort to demonstrate a new generation of innovative coal processes in a series of full-scale showcase`` facilities built across the country. Begun in 1986 and expanded in 1987, the program is expected to finance more than $6.8 billion of projects. Nearly two-thirds of the funding will come from the private sector, well above the 50 percent industry co-funding expected when the program began. The original recommendation for a multi-billion dollar clean coal demonstration program came from the US and Canadian Special Envoys on Acid Rain. In January 1986, Special Envoys Lewis and Davis presented their recommendations. Included was the call for a 5-year, $5-billion program in the US to demonstrate, at commercial scale, innovative clean coal technologies that were beginning to emerge from research programs both in the US and elsewhere in the world. As the Envoys said: if the menu of control options was expanded, and if the new options were significantly cheaper, yet highly efficient, it would be easier to formulate an acid rain control plan that would have broader public appeal.

  12. Combined coal gasification and Fe{sub 3}O{sub 4}-reduction using high-temperature solar process heat

    Energy Technology Data Exchange (ETDEWEB)

    Tamaura, Y [Tokyo Inst. of Technology, Tokyo (Japan); Ehrensberger, K; Steinfeld, A [Paul Scherrer Inst. (PSI), Villigen (Switzerland)

    1997-06-01

    The coal/Fe{sub 3}O{sub 4} system was experimentally studied at PSI solar furnace. The reactants were directly exposed to a solar flux irradiation of 3,000 suns (1 sun = 1 kW/m{sup 2}). The combined gasification of coal and reduction of Fe{sub 2}O{sub 3} proceeded rapidly after only one second exposure, suggesting an efficient heat transfer and chemical conversion by direct solar energy absorption at the reaction site. The proposed solar thermochemical process offers the possibility of converting coal to a cleaner fluid fuel with a solar-upgraded calorific value. (author) 2 figs., 8 refs.

  13. Mechanical Properties of High Strength Concrete Containing Coal Bottom Ash and Oil-Palm Boiler Clinker as Fine Aggregates

    Directory of Open Access Journals (Sweden)

    Soofinajafi Mahmood

    2016-01-01

    Full Text Available This research aims to utilize Coal Furnace Bottom ash (CBA and Oil-Palm Boiler Clinker (OPBC as fine aggregate in concrete mix proportions. They are solid wastes from power plant and Oil Palm industry, respectively. Since these by-products do not have any primary use and are pure waste, an opportunity to use them as aggregate in concrete industry not only is economical but also will be an environmental friendly opportunity leading towards a more sustainable production chain. CBA and OPBC sands had similar grading to normal sand but have lower density and higher water absorption. In a high strength concrete, normal sand was replaced up to 25% with either CBA or OPBC. Test results showed that although water absorption of these wastes was more than normal sand but the slump value of concrete containing each of these wastes showed that these concretes had good workability. All mixes containing these wastes had slightly lower compressive strength at early ages and equivalent or higher compressive strength at later ages compared to control mix. The 28-day compressive strength of these concretes was in the range of 69–76 MPa which can be categorized as high strength concrete. In general, the performance of OPBC was better than CBA at 25% replacement level. However, it is recommended that at least 12.5% of total volume of fine aggregate in a high strength concrete is used of CBA or OPBC.

  14. Reducing coal miner absenteeism

    Energy Technology Data Exchange (ETDEWEB)

    Peters, R.H.; Clingan, M.R. (Bureau of Mines, PA (USA). Pittsburgh Research Center)

    1989-09-01

    High absenteeism at coal mines can seriously affect safety and hamper productivity. Several effective strategies for achieving high attendance which mine operators may not have considered are presented and a method is proposed for implementing programs for minimizing absenteeism among coal miners. The best strategies for improving attendance will vary according to the needs and circumstances of the particular mine, however, the process for establishing such a program is relatively invariant. A four-stage process is recommended; evaluate data from prior attendance records, communicate attendance goals and policy, develop and implement an attendance promotion program, and recycle. 12 refs., 5 figs.

  15. Coal 99; Kol 99

    Energy Technology Data Exchange (ETDEWEB)

    Sparre, C

    2000-07-01

    The following report deals with the use of coal and coke during 1998. Some information about techniques, environmental questions and markets are also given. Data have been collected by questionnaires to major users and by telephone to minor users. Preliminary statistical data from Statistics Sweden have also been used. The use of steam coal for heating purposes during 1998 was 680 000 tons and somewhat lower than in 1997. The extremely high figures of 1996 were due to twice the production of electricity because of lack of waterpower. The co-generation plants were the main users of coal. The minor plants have increased their use of forest fuels. Probably the use of steam coal will go down in the immediate years both in the heat generating and the co-generating plants. During the top year 1987 coal was used in 18 hot water plants and 11 co-generation plants. During 1998 these figures are 1 and 8. Taxes and environmental reasons explain this trend. The use of steam coal in the industry has been constant at the level 700 000 tons. This level is supposed to be constant or to vary with business cycles. Steel-works, however, increase their use of steam coal in order to replace the more expensive coke. The import of metallurgical coal in 1998 was 1.6 mill tons like the year before. 1.1 mill tons of coke were produced. The coke consumption in the industry was 1.4 mill tons from which 0.3 mill tons were imported. Several other plants have plans to replace the coal with forest fuels, waste fuels and NG. Even the biggest plant, Vaesteraas, has ordered a block for bio fuels. Helsingborg has started to use wood pellets. The pellets replace most of the coal for the heat production in the co-generation plant. Norrkoeping Kraft AB has put a fluid bed boiler for various fuels into operation, leading to more than half the coal consumption compared with previous years. They have also rebuilt one of their travelling grates for bio fuels. Stockholm Energi, Haesselbyverket, has invested

  16. Alkaline leaching of coal by the mechanochemical treatment

    Directory of Open Access Journals (Sweden)

    Turèániová ¼udmila

    1998-09-01

    Full Text Available The possibility of application of a new process GACL (Grinding and Aqueous Caustic Leaching for the reduction of mineral components in the brown coal Nováky was tested. The simultaneous grinding and chemical leaching enable us to extract 41 % total sulphur, 95 % arsenic and to reduce the ash content to 43 %. The process proceeds at the atmospheric pressure, temperature 90oC and in diluted NaOH solutions (5 %.

  17. World coal prices and future energy demand

    International Nuclear Information System (INIS)

    Bennett, J.

    1992-01-01

    The Clean Air Act Amendments will create some important changes in the US domestic steam coal market, including price increases for compliance coal by the year 2000 and price decreases for high-sulfur coal. In the international market, there is likely to be a continuing oversupply which will put a damper on price increases. The paper examines several forecasts for domestic and international coal prices and notes a range of predictions for future oil prices

  18. Coal preparation

    International Nuclear Information System (INIS)

    Anon.

    1991-01-01

    The acid rain control legislation has prompted the Department of Energy (DOE) to seek new technology using the Clean Coal Technology program solicitation. The main goal of the program is to reduce SO 2 emissions below 9 Mt/a (10 million stpy) and NO x emission below 5.4 Mt/a (6 million stpy) by the year 2000. This would be accomplished by using precombustion, combustion, post combustion and conversion technology. Utilities are considering installing new scrubbers, switching fuel or possibly deep clean. However, the time required to implement the control technology is short. Due to the legislation, about 110 plants will have to adopt one of the approaches. This paper reports that in characterization of coal, Ames Laboratory used a scanning electron microscope- based, automated image analysis (SEM-AIA) technique to identify coal and mineral matter association. Various forms of organic sulfur were identified using peroxyacetic acid oxidation of coal. This was followed by subsequent microscopic, GC-MS, and HRMS analysis by Southern Illinois University. In ultrafine grinding of coal, it was reported by the Mining and Mineral Institute of Alabama that silica sand or flint shot used less energy compared to steel ball mills

  19. Decomposition of pyrite and the interaction of pyrite with coal organic matrix in pyrolysis and hydropyrolysis

    Energy Technology Data Exchange (ETDEWEB)

    Chen, H.; Li, B.; Zhang, B. [Chinese Academy of Sciences, Taiyuan (China). Institute of Coal Chemistry

    1999-07-01

    The thermal decomposition and reduction behaviour of pure pyrite crystals were studied under nitrogen and hydrogen atmospheres. Decomposition of pyrite in coal during pyrolysis and hydropyrolysis, and the behaviour of organic sulphur, are discussed. Temperature and pressure effects are considered. 7 refs., 6 figs., 1 tab.

  20. Evaluation of the protein concentration in enzymes via the determination of sulphur by TXRF

    International Nuclear Information System (INIS)

    Mertens, M.; Rittmeyer, C.; Kolbesen, B.O.

    2000-01-01

    Total reflection x-ray fluorescence spectrometry (TXRF) offers many advantages for the identification of trace elements in biological samples like enzymes, tissues or plants. Without any preliminary treatment elements may be determined with high accuracy especially transition metals like Fe, Ni, Cu, Mo and the alkaline earth metal Ca. A further aspect of the investigation of enzymes is the simple and simultaneous determination of light elements. Especially sulphur is of interest. The element sulphur exists mainly in the two amino, acids methionine and cysteine as well as in iron-sulphur clusters and may be used for an easy and simultaneous calculation of the protein concentration. Hence the quantitative determination of sulphur by TXRF allows a cross-check regarding of the conventional quantitative determination of protein concentration by, for example, the Lowry method. On the basis of three enzymes of different origins and molecular weights the presentation will show the influence of the bio-organic matrix and different buffer media on element determination by TXRF. As is already known the influence of the matrix on the detection of light elements is stronger than on transition metals. It can be discussed whether layer thickness and layer effects of the drying residues (characterization by SEM and thickness profilometer (ALPHA-step)) and / or self absorption effects as well as the excitation are of significance. The results indicate that with enzymes of low molecular weight a reliable determination of sulphur is possible whereas those with higher molecular weights gave poorer results on account of the matrix effects described. (author)

  1. Coal: an economic source of energy

    International Nuclear Information System (INIS)

    Ali, I.; Ali, M.M.

    2001-01-01

    Coal, in spite its abundance availability in Pakistan, is a neglected source of energy. Its role as fuel is not more than five percent for the last four decades. Some of the coal, mined, in used as space heating in cold areas of Pakistan but more than 90% is being used in brick kilns. There are 185 billion tonnes of coal reserves in the country and hardly 3 million tonnes of coal is, annually, mined. Lakhra coal field is, presently, major source of coal and is considered the largest productive/operative coal field of Pakistan. It is cheaper coal compared to other coals available in Pakistan. As an average analysis of colas of the country, it shows that most of the coals are lignitic in nature with high ash and sulfur content. The energy potential is roughly the same but the cost/ton of coal is quite different. It may be due to methods of mining. There should be some criteria for fixing the cost of the coal. It should be based on energy potential of unit mass of coal. (author)

  2. Coal liquids -- Who needs them?

    International Nuclear Information System (INIS)

    Gray, D.; Tomlinson, G.

    1995-01-01

    The paper discusses the global energy demand situation as presented at the last World Energy Congress. The total energy demand was calculated for each country and projected to 2100. The paper then discusses the energy situation in the United States, especially the forecasted demand for crude oil and natural gas liquids. Imports will be needed to make up the shortfall in domestic production. The shortfall in conventional petroleum could be supplied by converting coal into liquid fuels. Currently the cost of high quality coal liquids is too high to compete with petroleum, but trends suggest that the price will be competitive in the year 2030 using current technology. Continuing research on coal liquefaction will reduce the price of coal liquids so that coal liquids could play a significant role sooner

  3. Low Cost, High Capacity Regenerable Sorbent for Carbon Dioxide Capture from Existing Coal-fired Power Plants

    Energy Technology Data Exchange (ETDEWEB)

    Alptekin, Gokhan [TDA Research, Inc., Wheat Ridge, CO (United States); Jayaraman, Ambalavanan [TDA Research, Inc., Wheat Ridge, CO (United States); Dietz, Steven [TDA Research, Inc., Wheat Ridge, CO (United States)

    2016-03-03

    In this project TDA Research, Inc (TDA) has developed a new post combustion carbon capture technology based on a vacuum swing adsorption system that uses a steam purge and demonstrated its technical feasibility and economic viability in laboratory-scale tests and tests in actual coal derived flue gas. TDA uses an advanced physical adsorbent to selectively remove CO2 from the flue gas. The sorbent exhibits a much higher affinity for CO2 than N2, H2O or O2, enabling effective CO2 separation from the flue gas. We also carried out a detailed process design and analysis of the new system as part of both sub-critical and super-critical pulverized coal fired power plants. The new technology uses a low cost, high capacity adsorbent that selectively removes CO2 in the presence of moisture at the flue gas temperature without a need for significant cooling of the flue gas or moisture removal. The sorbent is based on a TDA proprietary mesoporous carbon that consists of surface functionalized groups that remove CO2 via physical adsorption. The high surface area and favorable porosity of the sorbent also provides a unique platform to introduce additional functionality, such as active groups to remove trace metals (e.g., Hg, As). In collaboration with the Advanced Power and Energy Program of the University of California, Irvine (UCI), TDA developed system simulation models using Aspen PlusTM simulation software to assess the economic viability of TDA’s VSA-based post-combustion carbon capture technology. The levelized cost of electricity including the TS&M costs for CO2 is calculated as $116.71/MWh and $113.76/MWh for TDA system integrated with sub-critical and super-critical pulverized coal fired power plants; much lower than the $153.03/MWhand $147.44/MWh calculated for the corresponding amine based systems. The cost of CO2 captured for TDA’s VSA based system is $38

  4. Special emission measurements on Riley Stoker's advanced CFB pilot facility co-firing non-recyclable de-inking paper fiber and high sulfur eastern bituminous coal

    International Nuclear Information System (INIS)

    Dixit, V.B.; Mongeon, R.K.; Reicker, E.L.

    1993-01-01

    Riley Stoker has developed advanced industrial CFB designs that utilize eastern bituminous coals as fuel, and have the potential to use coal in combination with other fuels. Various fiber waste streams in paper recycling processes have sufficient carbonaceous content to be considered as possible sources of such fuels that could fire FBC combustors. The American Paper Institute estimates that by the mid-1990's more than 40% of the waste paper will be recycled, reaching much higher numbers by the year 2000. To evaluate the effectiveness of co-firing such fuels, a test program was conducted on Riley's pilot-scale circulating fluidized bed test facility. A de-inked newsprint derived fiber waste was successfully co-fired with high sulfur coal. The waste fiber material containing approximately 50% moisture had a heating value of 3500 Btu/lb. The coal was strip-mined and contained a lot of clay and excessive quantities of fines making it difficult to burn in conventional boilers. Tests were also conducted with a combination fuel consisting of coal, fiber waste and a high carbon fly ash. In addition to obtaining performance data on combustion efficiency, sulfur capture, and NO x emissions, special emission measurements were also made to quantify the organics, trace metals and hydrochloric acid levels in the flue gas. The co-firing tests achieved a maximum combustion efficiency of 98% and sulfur capture of 90%. The effect of Ca/S mole ratio and temperature is discussed. Although there are no formal regulations in place for FBC systems regarding special emissions, the levels measured were far below the allowable limits for waste incinerators. Materials handling experience on the pilot facility relating to co-firing is also discussed. This is done to identify special considerations for designing commercial facilities. A brief overview of the de-inking waste fiber combustion market is also presented

  5. Comparison of chest radiography and high-resolution computed tomography findings in early and low-grade coal worker's pneumoconiosis

    Energy Technology Data Exchange (ETDEWEB)

    Savranlar, A.; Altin, R.; Mahmutyazicioglu, K.; Ozdemir, H.; Kart, L.; Ozer, T.; Gundogdu, S. [Zonguldak Karaelmas University, Zonguldak (Turkey). Faculty of Medicine

    2004-08-01

    High-resolution computed tomography (HRCT) is more sensitive than chest X-ray (CXR) in the depiction of parenchymal abnormalities. The paper presents and compares CXR and HRCT findings in coal workers with and without early and low-grade coal worker's pneumoconiosis (CWP). 71 coal workers were enrolled in the study. HRCT's were graded according to Hosoda and Shida's Japanese classification. After grading, 67 workers with CXR profusion 0/0-2/2 were included in the study. Four patients with major opacity were excluded. Profusion 0/1 to 1/1 cases were accepted as early and profusion and 2/2 cases as low-grade pneumoconiosis. Discordance rate was found to be higher in the early pneumoconiosis cases with negative CXR than low-grade pneumoconiosis (60, 36 and 8%, respectively). When coal miners with normal CXR were evaluated by HRCT, six out of 10 cases were diagnosed as positive. In low-grade pneumoconiosis group, the number of patients with positive CXR but negative HRCT were low in comparison to patients with CXR negative and early pneumoconiosis findings. Most of the CXR category 0 patients (10/16) were diagnosed as category 1 by HRCT. Eleven cases diagnosed as CXR category 1 were diagnosed as category 0 (7/11) and category 2 (4/11) by HRCT. In CXR category 2 (eight cases), there were four cases diagnosed as category 1 by HRCT. Overall, discordance between CXR and HRCT was high, especially for CXR negative and early pneumoconiosis cases. The role of CXR in screening coal workers to detect early pneumoconiosis findings should be questioned. The authors suggest using HRCT as a standard screening method instead of CXR to distinguish between normal and early pneumoconiosis.

  6. Being green on sulphur: Targets, measures and side-effects

    DEFF Research Database (Denmark)

    Kontovas, Christos A.; Panagakos, George; Psaraftis, Harilaos N.

    2016-01-01

    to sea to reduce congestion, and might ultimately (under certain circumstances) increase the overall level of CO2 emissions along the entire supply chain. The purpose of this chapter is to investigate the potential effect of sulphur regulations on the share of cargo transported by the waterborne mode vis......Green House Gas (GHG) emissions are not the only emissions of concern to the international transport community. SOx emissions are non-GHG emissions that are caused by the presence of sulphur in the fuel. As the maximum percentage of sulphur in automotive and aviation fuels is strictly regulated...

  7. Distilling coal

    Energy Technology Data Exchange (ETDEWEB)

    Blythe, F C

    1914-09-14

    In the destructive distillation of bituminous coal, heavy hydrocarbon oil, such as petroleum, kerosine, shale oil, and heavy tar oil, obtained in some cases during the process, is added to the coal, which is then distilled under pressure and at a comparatively low temperature regulated so as to produce a large proportion of hydrocarbon oils and a small proportion of permanent gas. In one method, about 5 to 10 parts of hydrocarbon oil are mixed with 100 parts of crushed or ground coal, and the mixture is heated in a closed vessel, provided in some cases with an agitator, under a pressure of about 60 lb/in/sup 2/, and the temperature may be gradually raised to 350/sup 0/C and then to about 500/sup 0/C. The heating may be by means of superheated steam with or without external heat.

  8. Demonstration of Selective Catalytic Reduction Technology to Control Nitrogen Oxide Emissions From High-Sulfur, Coal-Fired Boilers: A DOE Assessment

    International Nuclear Information System (INIS)

    Federal Energy Technology Center

    1999-01-01

    The goal of the U.S. Department of Energy (DOE) Clean Coal Technology (CCT) program is to furnish the energy marketplace with a number of advanced, more efficient, and environmentally responsible coal utilization technologies through demonstration projects. These projects seek to establish the commercial feasibility of the most promising advanced coal technologies that have developed beyond the proof-of-concept stage. This document serves as a DOE post-project assessment of a project selected in CCT Round 2. The project is described in the report ''Demonstration of Selective Catalytic Reduction (SCR) Technology for the Control of Nitrogen Oxide (NO(sub x)) Emissions from High-Sulfur, Coal-Fired Boilers'' (Southern Company Services 1990). In June 1990, Southern Company Services (Southern) entered into a cooperative agreement to conduct the study. Southern was a cofunder and served as the host at Gulf Power Company's Plant Crist. Other participants and cofunders were EPRI (formerly the Electric Power Research Institute) and Ontario Hydro. DOE provided 40 percent of the total project cost of$23 million. The long-term operation phase of the demonstration was started in July 1993 and was completed in July 1995. This independent evaluation is based primarily on information from Southern's Final Report (Southern Company Services 1996). The SCR process consists of injecting ammonia (NH(sub 3)) into boiler flue gas and passing the 3 flue gas through a catalyst bed where the NO(sub x) and NH(sub 3) react to form nitrogen and water vapor. The objectives of the demonstration project were to investigate: Performance of a wide variety of SCR catalyst compositions, geometries, and manufacturing methods at typical U.S. high-sulfur coal-fired utility operating conditions; Catalyst resistance to poisoning by trace metal species present in U.S. coals but not present, or present at much lower concentrations, in fuels from other countries; and Effects on the balance-of-plant equipment

  9. Ion-exchanged calcium from calcium carbonate and low-rank coals: high catalytic activity in steam gasification

    Energy Technology Data Exchange (ETDEWEB)

    Ohtsuka, Y.; Asami, K. [Tokoku University, Sendai (Japan). Inst. for Chemical Reaction Science

    1996-03-01

    Interactions between CaCO{sub 3} and low-rank coals were examined, and the steam gasification of the resulting Ca-loaded coals was carried out at 973 K with a thermobalance. Chemical analysis and FT-IR spectra show that CaCO{sub 3} can react readily with COOH groups to form ion-exchanged Ca and CO{sub 2} when mixed with brown coal in water at room temperature. The extent of the exchange is dependent on the crystalline form of CaCO{sub 3}, and higher for aragonite naturally present in seashells and coral reef than for calcite from limestone. The FT-IR spectra reveal that ion-exchange reactions also proceed during kneading CaCO{sub 3} with low-rank coals. The exchanged Ca promotes gasification and achieves 40-60 fold rate enhancement for brown coal with a lower content of inherent minerals. Catalyst effectiveness of kneaded CaCO{sub 3} depends on the coal type, in other words, the extent of ion exchange. 11 refs., 7 figs., 3 tabs.

  10. Relation of ash composition to the uses of coal

    Energy Technology Data Exchange (ETDEWEB)

    Fieldner, A C; Selvig, W A

    1926-02-01

    The effects of coal ash and ash components on the utilization of coal for coke and gas production, steam generation, water gas production, smithing, and domestic uses were described in a review of literature. Calcite, gypsum, and pyrite which occur in high amounts in coal, increase the ash fusibility of the coal and render it unsuitable for many industrial and domestic uses. As a rule, coal ash of high Si content and low Fe content would not be readily fusible. High amounts of ash in coal also have the effect of reducing the heating value of the coal.

  11. Utilisation of chemically treated coal

    International Nuclear Information System (INIS)

    Bezovska, M.

    2002-01-01

    The numerous application of coal with high content of humic substances are known. They are used in many branches of industry. The complex study of the composition of coal from upper Nitra mines has directed research to its application in the field of ecology and agriculture. The effective sorption layers of this coal and their humic acids can trap a broad spectrum of toxic harmful substances present in industrial wastes, particularly heavy metals. A major source of humic acids is coal - the most abundant and predominant product of plant residue coalification. All ranks of coal contain humic acids but lignite from Novaky deposit represents the most easily available and concentrated from of humic acids. The possibilities of utilisation of humic acids to remove heavy metals from waste waters was studied. The residual concentrations of the investigated metals in the aqueous phase were determined by AAs. From the results follows that the samples of coals humic acids can be used for the heavy metal removal from metal solutions and the real acid mine water. Oxidised coal with high content of humic acids and nitrogen is used in agriculture as fertilizer. Humic acids are active component in coal and can help to utilize almost quantitatively nitrogen in soil. The humic substances block and stabilize toxic metal residues already present in soil. (author)

  12. Electricity and fluid fuels from biomass and coal using advanced technologies: a cost comparison for developing country applications

    Energy Technology Data Exchange (ETDEWEB)

    Kartha, S; Larson, E D; Williams, R H [Center for Energy and Environment Studies School of Engineering and Applied Science, Princeton University, Princeton, NJ (United States); Katofsky, R E [Arthur D. Little Co., Cambridge, MA (United States); Chen, J [Thermo Fibertek, Inc., Auburn, MA (United States); Marrison, C I [Oliver, Wyman and Co., New York, NY (United States)

    1995-12-01

    Recent analyses of alternative global energy supply strategies, such as the forthcoming report of the Intergovernmental Panel on Climate Change (IPCC), to be published in 1996, have drawn attention to the possibility that biomass modernized with advanced technologies could play an important role in meeting global energy needs in the next century. This paper discusses two promising classes of advanced technologies that offer the potential for providing modem energy carriers (electricity and fluid fuels) from biomass at competitive costs within one or two decades. These technologies offer significantly more efficient use of land than currently commercial technologies for producing electricity and fluid fuels from biomass, as well as substantially improved energy balances. Electricity is Rely to be the first large market for modernized biomass, but the potential market for fluid fuel production is likely to be much larger. As coal is likely to present a more serious competitive challenge to biomass in the long run, we present an economic comparison with coal-based electricity and fluid fuels. A meaningful economic comparison between coal and biomass is possible because these feedstocks are sufficiently alike in their physical characteristics that similar conversion technologies may well be used for producing electricity and fluid fuels from them. When similar conversion technologies are used for both feedstocks, the relative costs of electricity or fluid fuels will be determined by the distinguishing technical characteristics of the feedstocks (sulphur content, moisture content and reactivity) and by the relative feedstock prices. Electric power generation from biomass and coal are compared here using an advanced integrated gasifier/gas turbine cycle that offers the potential for achieving high efficiency, low unit capital cost and low local pollutant emissions: the steam-injected gas turbine coupled to an air-blown gasifier. For both feedstocks, generation costs are

  13. Electricity and fluid fuels from biomass and coal using advanced technologies: a cost comparison for developing country applications

    International Nuclear Information System (INIS)

    Kartha, S.; Larson, E.D.; Williams, R.H.; Katofsky, R.E.; Chen, J.; Marrison, C.I.

    1995-01-01

    Recent analyses of alternative global energy supply strategies, such as the forthcoming report of the Intergovernmental Panel on Climate Change (IPCC), to be published in 1996, have drawn attention to the possibility that biomass modernized with advanced technologies could play an important role in meeting global energy needs in the next century. This paper discusses two promising classes of advanced technologies that offer the potential for providing modem energy carriers (electricity and fluid fuels) from biomass at competitive costs within one or two decades. These technologies offer significantly more efficient use of land than currently commercial technologies for producing electricity and fluid fuels from biomass, as well as substantially improved energy balances. Electricity is Rely to be the first large market for modernized biomass, but the potential market for fluid fuel production is likely to be much larger. As coal is likely to present a more serious competitive challenge to biomass in the long run, we present an economic comparison with coal-based electricity and fluid fuels. A meaningful economic comparison between coal and biomass is possible because these feedstocks are sufficiently alike in their physical characteristics that similar conversion technologies may well be used for producing electricity and fluid fuels from them. When similar conversion technologies are used for both feedstocks, the relative costs of electricity or fluid fuels will be determined by the distinguishing technical characteristics of the feedstocks (sulphur content, moisture content and reactivity) and by the relative feedstock prices. Electric power generation from biomass and coal are compared here using an advanced integrated gasifier/gas turbine cycle that offers the potential for achieving high efficiency, low unit capital cost and low local pollutant emissions: the steam-injected gas turbine coupled to an air-blown gasifier. For both feedstocks, generation costs are

  14. Genetic-industrial classification of brown coals in Serbia

    Energy Technology Data Exchange (ETDEWEB)

    Ercegovac, Marko [Serbian Academy of Sciences and Arts, Knez Mihailova 35, 11000 Belgrade (Serbia and Montenegro); ?ivotic, Dragana; Kostic, Aleksandar [University of Belgrade, Faculty of Mining and Geology, Djusina 7, 11000 Belgrade (Serbia and Montenegro)

    2006-08-01

    The petrologic, chemical and technological features of low-rank coals from nineteen of the most important basins in Serbia have been studied as part of the research project of genetic-industrial classification of low-rank coals of Serbia. Most of these features have been included as parameters of the codification system for low-rank coals. The paper discusses the main genetic, technological and supplementary parameters of the Serbian brown coals such as rank, petrographic composition, gelification degree, total moisture, ash content, sulphur content, calorific value, tar yield, the chemical composition and the thermotechnical properties of ash. The rank of brown coals from Serbia has been defined on the basis of the following parameters: random reflectance of huminite/vitrinite (R{sub r}=0.26-0.50%), total moisture (W{sup ar}=13.18-49.11%), gross calorific value (Q{sup daf}=22.3-29.2MJ/kg, dry, ash-free basis), net calorific value (Q{sup daf}=21.2-28.1MJ/kg, dry, ash-free basis). The results from the maceral analysis confirm that the humic coals, in general, are characterized by high huminite content (76.0-97.9vol.%, mineral matter free), low inertinite amount (0.7-6.3vol.%, mineral matter free), and a variable amount of liptinite (0.8-15.5vol.%, mineral matter free). It is possible to define three groups of Serbian brown coals on the basis of the primary, or genetic parameters, technological, or chemical parameters, and supplementary parameters: soft (Low-Rank C; [Economic Commission for Europe, Committee on Sustainable Energy- United Nations (ECE-UN), 1998. International Classification of in-Seam Coals. Energy 19, 41 pp.; Economic Commission for Europe, Committee on Sustainable Energy- United Nations (ECE-UN), 1999. International Codification System for Low-Rank Coals. Energy 9, 19 pp.; Economic Commissio