THE BOLOCAM GALACTIC PLANE SURVEY. VIII. A MID-INFRARED KINEMATIC DISTANCE DISCRIMINATION METHOD

Energy Technology Data Exchange (ETDEWEB)

Ellsworth-Bowers, Timothy P.; Glenn, Jason; Battersby, Cara; Ginsburg, Adam; Bally, John [CASA, University of Colorado, UCB 389, University of Colorado, Boulder, CO 80309 (United States); Rosolowsky, Erik [Department of Physics and Astronomy, University of British Columbia Okanagan, 3333 University Way, Kelowna, BC V1V 1V7 (Canada); Mairs, Steven [Department of Physics and Astronomy, University of Victoria, 3800 Finnerty Road, Victoria, BC V8P 1A1 (Canada); Evans, Neal J. II [Department of Astronomy, University of Texas, 1 University Station C1400, Austin, TX 78712 (United States); Shirley, Yancy L., E-mail: timothy.ellsworthbowers@colorado.edu [Steward Observatory, University of Arizona, 933 North Cherry Avenue, Tucson, AZ 85721 (United States)

2013-06-10

We present a new distance estimation method for dust-continuum-identified molecular cloud clumps. Recent (sub-)millimeter Galactic plane surveys have cataloged tens of thousands of these objects, plausible precursors to stellar clusters, but detailed study of their physical properties requires robust distance determinations. We derive Bayesian distance probability density functions (DPDFs) for 770 objects from the Bolocam Galactic Plane Survey in the Galactic longitude range 7. Degree-Sign 5 {<=} l {<=} 65 Degree-Sign . The DPDF formalism is based on kinematic distances, and uses any number of external data sets to place prior distance probabilities to resolve the kinematic distance ambiguity (KDA) for objects in the inner Galaxy. We present here priors related to the mid-infrared absorption of dust in dense molecular regions and the distribution of molecular gas in the Galactic disk. By assuming a numerical model of Galactic mid-infrared emission and simple radiative transfer, we match the morphology of (sub-)millimeter thermal dust emission with mid-infrared absorption to compute a prior DPDF for distance discrimination. Selecting objects first from (sub-)millimeter source catalogs avoids a bias towards the darkest infrared dark clouds (IRDCs) and extends the range of heliocentric distance probed by mid-infrared extinction and includes lower-contrast sources. We derive well-constrained KDA resolutions for 618 molecular cloud clumps, with approximately 15% placed at or beyond the tangent distance. Objects with mid-infrared contrast sufficient to be cataloged as IRDCs are generally placed at the near kinematic distance. Distance comparisons with Galactic Ring Survey KDA resolutions yield a 92% agreement. A face-on view of the Milky Way using resolved distances reveals sections of the Sagittarius and Scutum-Centaurus Arms. This KDA-resolution method for large catalogs of sources through the combination of (sub-)millimeter and mid-infrared observations of molecular

Science with High Spatial Resolution Far-Infrared Data

Science.gov (United States)

Terebey, Susan (Editor); Mazzarella, Joseph M. (Editor)

1994-01-01

The goal of this workshop was to discuss new science and techniques relevant to high spatial resolution processing of far-infrared data, with particular focus on high resolution processing of IRAS data. Users of the maximum correlation method, maximum entropy, and other resolution enhancement algorithms applicable to far-infrared data gathered at the Infrared Processing and Analysis Center (IPAC) for two days in June 1993 to compare techniques and discuss new results. During a special session on the third day, interested astronomers were introduced to IRAS HIRES processing, which is IPAC's implementation of the maximum correlation method to the IRAS data. Topics discussed during the workshop included: (1) image reconstruction; (2) random noise; (3) imagery; (4) interacting galaxies; (5) spiral galaxies; (6) galactic dust and elliptical galaxies; (7) star formation in Seyfert galaxies; (8) wavelet analysis; and (9) supernova remnants.

High resolution spectroscopy in the microwave and far infrared

Science.gov (United States)

Pickett, Herbert M.

1990-01-01

High resolution rotational spectroscopy has long been central to remote sensing techniques in atmospheric sciences and astronomy. As such, laboratory measurements must supply the required data to make direct interpretation of data for instruments which sense atmospheres using rotational spectra. Spectral measurements in the microwave and far infrared regions are also very powerful tools when combined with infrared measurements for characterizing the rotational structure of vibrational spectra. In the past decade new techniques were developed which have pushed high resolution spectroscopy into the wavelength region between 25 micrometers and 2 mm. Techniques to be described include: (1) harmonic generation of microwave sources, (2) infrared laser difference frequency generation, (3) laser sideband generation, and (4) ultrahigh resolution interferometers.

Mid-infrared Semiconductor Optoelectronics

CERN Document Server

Krier, Anthony

2006-01-01

The practical realisation of optoelectronic devices operating in the 2–10 µm (mid-infrared) wavelength range offers potential applications in a variety of areas from environmental gas monitoring around oil rigs and landfill sites to the detection of pharmaceuticals, particularly narcotics. In addition, an atmospheric transmission window exists between 3 µm and 5 µm that enables free-space optical communications, thermal imaging applications and the development of infrared measures for "homeland security". Consequently, the mid-infrared is very attractive for the development of sensitive optical sensor instrumentation. Unfortunately, the nature of the likely applications dictates stringent requirements in terms of laser operation, miniaturisation and cost that are difficult to meet. Many of the necessary improvements are linked to a better ability to fabricate and to understand the optoelectronic properties of suitable high-quality epitaxial materials and device structures. Substantial progress in these m...

Optical system design with common aperture for mid-infrared and laser composite guidance

Science.gov (United States)

Zhang, Xuanzhi; Yang, Zijian; Sun, Ting; Yang, Huamei; Han, Kunye; Hu, Bo

2017-02-01

When the field of operation of precision strike missiles is more and more complicated, autonomous seekers will soon encounter serious difficulties, especially with regard to low signature targets and complex scenarios. So the dual-mode sensors combining an imaging sensor with a semi-active laser seeker are conceived to overcome these specific problems. Here the sensors composed a dual field of view mid-infrared thermal imaging camera and a laser range finder have the common optical aperture which produced the minization of seeker construction. The common aperture optical systems for mid-infrared and laser dual-mode guildance have been developed, which could meet the passive middle infrared high-resolution imaging and the active laser high-precision indication and ranging. The optical system had good image quality, and fulfilled the performance requirement of seeker system. The design and expected performance of such a dual-mode optical system will be discussed.

MID-INFRARED PROPERTIES OF OH MEGAMASER HOST GALAXIES. I. SPITZER IRS LOW- AND HIGH-RESOLUTION SPECTROSCOPY

International Nuclear Information System (INIS)

Willett, Kyle W.; Darling, Jeremy; Spoon, Henrik W. W.; Charmandaris, Vassilis; Armus, Lee

2011-01-01

We present mid-infrared spectra and photometry from the Infrared Spectrograph on the Spitzer Space Telescope for 51 OH megamasers (OHMs), along with 15 galaxies confirmed to have no megamaser emission above L OH = 10 2.3 L sun . The majority of galaxies display moderate-to-deep 9.7 μm amorphous silicate absorption, with OHM galaxies showing stronger average absorption and steeper 20-30 μm continuum emission than non-masing galaxies. Emission from multiple polycyclic aromatic hydrocarbons (PAHs), especially at 6.2, 7.7, and 11.3 μm, is detected in almost all systems. Fine-structure atomic emission (including [Ne II], [Ne III], [S III], and [S IV]) and multiple H 2 rotational transitions are observed in more than 90% of the sample. A subset of galaxies show emission from rarer atomic lines, such as [Ne V], [O IV], and [Fe II]. Fifty percent of the OHMs show absorption from water ice and hydrogenated amorphous carbon grains, while absorption features from CO 2 , HCN, C 2 H 2 , and crystalline silicates are also seen in several OHMs. Column densities of OH derived from 34.6 μm OH absorption are similar to those derived from 1667 MHz OH absorption in non-masing galaxies, indicating that the abundance of masing molecules is similar for both samples. This data paper presents full mid-infrared spectra for each galaxy, along with measurements of line fluxes and equivalent widths, absorption feature depths, and spectral indices.

Mid-Infrared Properties of OH Megamaser Host Galaxies. I. Spitzer IRS Low- and High-Resolution Spectroscopy

Science.gov (United States)

Willett, Kyle W.; Darling, Jeremy; Spoon, Henrik W. W.; Charmandaris, Vassilis; Armus, Lee

2011-03-01

We present mid-infrared spectra and photometry from the Infrared Spectrograph on the Spitzer Space Telescope for 51 OH megamasers (OHMs), along with 15 galaxies confirmed to have no megamaser emission above L OH = 102.3 L sun. The majority of galaxies display moderate-to-deep 9.7 μm amorphous silicate absorption, with OHM galaxies showing stronger average absorption and steeper 20-30 μm continuum emission than non-masing galaxies. Emission from multiple polycyclic aromatic hydrocarbons (PAHs), especially at 6.2, 7.7, and 11.3 μm, is detected in almost all systems. Fine-structure atomic emission (including [Ne II], [Ne III], [S III], and [S IV]) and multiple H2 rotational transitions are observed in more than 90% of the sample. A subset of galaxies show emission from rarer atomic lines, such as [Ne V], [O IV], and [Fe II]. Fifty percent of the OHMs show absorption from water ice and hydrogenated amorphous carbon grains, while absorption features from CO2, HCN, C2H2, and crystalline silicates are also seen in several OHMs. Column densities of OH derived from 34.6 μm OH absorption are similar to those derived from 1667 MHz OH absorption in non-masing galaxies, indicating that the abundance of masing molecules is similar for both samples. This data paper presents full mid-infrared spectra for each galaxy, along with measurements of line fluxes and equivalent widths, absorption feature depths, and spectral indices.

The Spitzer Infrared Nearby Galaxies Survey: A High-Resolution Spectroscopy Anthology

Science.gov (United States)

Dale, Daniel A.; SINGS Team

2009-05-01

Results from high resolution mid-infrared spectroscopy are presented for 155 nuclear and extranuclear regions from SINGS. The SINGS sample shows a wide range in the ratio of [SIII]18.71/[SIII]33.48, but the average ratio of the ensemble indicates a typical interstellar electron density of 300--400 cm-3 on 23"x15" scales and 500--600 cm-3 using 11"x9" apertures, independent of whether the region probed is a star-forming nuclear, a star-forming extranuclear, or an AGN environment. Evidence is provided that variations in gas-phase metallicity play an important role in driving variations in radiation field hardness, as indicated by [NeIII]15.56/[NeII]12.81, for regions powered by star formation. Conversely, the radiation hardness for galaxy nuclei powered by accretion around a massive black hole is independent of metal abundance. Furthermore, for metal-rich environments AGN are distinguishable from star-forming regions by significantly larger [NeIII]15.56/[NeII]12.81 ratios. Finally, [FeII]25.99/[NeII]12.81 versus [SiII]34.82/[SIII]33.48 also provides an empirical method for discerning AGN from normal star-forming sources. However, similar to [NeIII]15.56/[NeII]12.81, these mid-infrared line ratios lose their AGN/star-formation diagnostic powers for very low metallicity star-forming systems with hard radiation fields.

Mid-infrared spectroscopic investigation

International Nuclear Information System (INIS)

Walter, L.; Vergo, N.; Salisbury, J.W.

1987-01-01

Mid-infrared spectroscopic research efforts are discussed. The development of a new instrumentation to permit advanced measurements in the mid-infrared region of the spectrum, the development of a special library of well-characterized mineral and rock specimens for interpretation of remote sensing data, and cooperative measurements of the spectral signatures of analogues of materials that may be present on the surfaces of asteroids, planets or their Moons are discussed

Mid-infrared interferometric variability of DG Tauri: Implications for the inner-disk structure

Science.gov (United States)

Varga, J.; Gabányi, K. É.; Ábrahám, P.; Chen, L.; Kóspál, Á.; Menu, J.; Ratzka, Th.; van Boekel, R.; Dullemond, C. P.; Henning, Th.; Jaffe, W.; Juhász, A.; Moór, A.; Mosoni, L.; Sipos, N.

2017-08-01

Context. DG Tau is a low-mass pre-main sequence star, whose strongly accreting protoplanetary disk exhibits a so-far enigmatic behavior: its mid-infrared thermal emission is strongly time-variable, even turning the 10 μm silicate feature from emission to absorption temporarily. Aims: We look for the reason for the spectral variability at high spatial resolution and at multiple epochs. Methods: Infrared interferometry can spatially resolve the thermal emission of the circumstellar disk, also giving information about dust processing. We study the temporal variability of the mid-infrared interferometric signal, observed with the VLTI/MIDI instrument at six epochs between 2011 and 2014. We fit a geometric disk model to the observed interferometric signal to obtain spatial information about the disk. We also model the mid-infrared spectra by template fitting to characterize the profile and time dependence of the silicate emission. We use physically motivated radiative transfer modeling to interpret the mid-infrared interferometric spectra. Results: The inner disk (r 1-3 au) spectra show a crystalline silicate feature in emission, similar to the spectra of comet Hale-Bopp. The striking difference between the inner and outer disk spectral feature is highly unusual among T Tauri stars. The mid-infrared variability is dominated by the outer disk. The strength of the silicate feature changed by more than a factor of two. Between 2011 and 2014 the half-light radius of the mid-infrared-emitting region decreased from 1.15 to 0.7 au. Conclusions: For the origin of the absorption we discuss four possible explanations: a cold obscuring envelope, an accretion heated inner disk, a temperature inversion on the disk surface and a misaligned inner geometry. The silicate emission in the outer disk can be explained by dusty material high above the disk plane, whose mass can change with time, possibly due to turbulence in the disk. Based on observations made with the ESO Very Large

Heterogeneously integrated silicon photonics for the mid-infrared and spectroscopic sensing.

Science.gov (United States)

Chen, Yu; Lin, Hongtao; Hu, Juejun; Li, Mo

2014-07-22

Besides being the foundational material for microelectronics, crystalline silicon has long been used for the production of infrared lenses and mirrors. More recently, silicon has become the key material to achieve large-scale integration of photonic devices for on-chip optical interconnect and signal processing. For optics, silicon has significant advantages: it offers a very high refractive index and is highly transparent in the spectral range from 1.2 to 8 μm. To fully exploit silicon’s superior performance in a remarkably broad range and to enable new optoelectronic functionalities, here we describe a general method to integrate silicon photonic devices on arbitrary foreign substrates. In particular, we apply the technique to integrate silicon microring resonators on mid-infrared compatible substrates for operation in the mid-infrared. These high-performance mid-infrared optical resonators are utilized to demonstrate, for the first time, on-chip cavity-enhanced mid-infrared spectroscopic analysis of organic chemicals with a limit of detection of less than 0.1 ng.

Mid-Infrared Lasers

Data.gov (United States)

National Aeronautics and Space Administration — Mid infrared solid state lasers for Differential Absorption Lidar (DIAL) systems required for understanding atmospheric chemistry are not available. This program...

Mid-infrared-to-mid-ultraviolet supercontinuum enhanced by third-to-fifteenth odd harmonics.

Science.gov (United States)

Mitrofanov, A V; Voronin, A A; Mitryukovskiy, S I; Sidorov-Biryukov, D A; Pugžlys, A; Andriukaitis, G; Flöry, T; Stepanov, E A; Fedotov, A B; Baltuška, A; Zheltikov, A M

2015-05-01

A high-energy supercontinuum spanning 4.7 octaves, from 250 to 6500 nm, is generated using a 0.3-TW, 3.9-μm output of a mid-infrared optical parametric chirped-pulse amplifier as a driver inducing a laser filament in the air. The high-frequency wing of the supercontinuum spectrum is enhanced by odd-order optical harmonics of the mid-infrared driver. Optical harmonics up to the 15th order are observed in supercontinuum spectra as overlapping, yet well-resolved peaks broadened, as verified by numerical modeling, due to spatially nonuniform ionization-induced blue shift.

Improved mid infrared detector for high spectral or spatial resolution and synchrotron radiation use

Energy Technology Data Exchange (ETDEWEB)

Faye, Mbaye; Bordessoule, Michel; Kanouté, Brahim; Brubach, Jean-Blaise; Roy, Pascale [Synchrotron SOLEIL, L’Orme des Merisiers, F-91192 Gif-sur-Yvette (France); Manceron, Laurent [Synchrotron SOLEIL, L’Orme des Merisiers, F-91192 Gif-sur-Yvette (France); Laboratoire MONARIS, CNRS-Université Pierre et Marie Curie, UMR 8233, 4 Place Jussieu, F-75252 Paris Cedex (France)

2016-06-15

When using bright, small effective size sources, such as synchrotron radiation light beam, for broadband spectroscopy at spectral or spatial high resolution for mid-IR FTIR measurements, a marked detectivity improvement can be achieved by setting up a device matching the detector optical étendue to that of the source. Further improvement can be achieved by reducing the background unmodulated flux and other intrinsic noise sources using a lower temperature cryogen, such as liquid helium. By the combined use of cooled apertures, cold reimaging optics, filters and adapted detector polarization, and preamplification electronics, the sensitivity of a HgCdTe photoconductive IR detector can be improved by a significant factor with respect to standard commercial devices (more than one order of magnitude on average over 6–20 μm region) and the usable spectral range extended to longer wavelengths. The performances of such an optimized detector developed on the AILES Beamline at SOLEIL are presented here.

Mid-infrared upconversion spectroscopy

DEFF Research Database (Denmark)

Tidemand-Lichtenberg, Peter; Dam, Jeppe Seidelin; Andersen, H. V.

2016-01-01

Mid-infrared (MIR) spectroscopy is emerging as an attractive alternative to near-infrared or visible spectroscopy. MIR spectroscopy offers a unique possibility to probe the fundamental absorption bands of a large number of gases as well as the vibrational spectra of complex molecules. In this paper...

Jupiter's Mid-Infrared Aurora: Solar Connection and Minor Constituents

Science.gov (United States)

Kostiuk, Theodore; Livengood, T.A.; Fast, K.E.; Hewagama, T.; Schmilling, F.; Sonnabend, G.; Delgado, J.

2009-01-01

High spectral resolution in the 12 pin region of the polar regions of Jupiter reveal unique information on auroral phenomena and upper stratospheric composition. Polar aurorae in Jupiter's atmosphere radiate; throughout the electromagnetic spectrum from X-ray through mid-infrared (mid-IR, 5 - 20 micron wavelength). Voyager IRIS data and ground-based. spectroscopic measurements of Jupiter's northern mid-IR aurora acquired since 1982, reveal a correlation between auroral brightness and solar activity that has not been observed in Jovian aurora at other wavelengths. Over nearly three solar cycles, Jupiter auroral ethane, emission brightness and solar 10.7-cm radar flux and sunspot number are positively correlated with high confidence. Ethane line emission intensity varies over tenfold between low and high scalar activity periods. Detailed measurements have been made using the GSFC HIPWAC spectrometer at the NASA IRTF since the last solar maximum, following the mid-IR emission through the declining phase toward solar minimum. An even more convincing correlation with solar activity is evident in these data. The spectra measured contain features that cannot be attributed to ethane and are most likely spectra of minor constituents whose molecular bands overlap the v9 band of ethane. Possible candidates are allene, propane, and other higher order hydrocarbons. These features appear to be enhanced in the active polar regions. Laboratory measurements at comparable spectral resolution of spectra of candidate molecules will be used to identify the constituents. Current analyses of these results will be described, including planned measurements on polar ethane line emission scheduled through the rise of the next solar maximum beginning in 2009, with a steep gradient to a maximum in 2012. This work is relevant to the Juno mission and to the development of the NASA/ESA Europa Jupiter System Mission.

NanoComposite Polymers for High Resolution Near Infrared Detectors

Data.gov (United States)

National Aeronautics and Space Administration — Develop nanocomposite materials with tuned refractive index in the near infra red spectral range as an index-matched immersion lens for high resolution infra-red...

Confronting Standard Models of Proto-planetary Disks with New Mid-infrared Sizes from the Keck Interferometer

OpenAIRE

Millan-Gabet, Rafael; Che, Xiao; Monnier, John D.; Sitko, Michael L.; Russell, Ray W.; Grady, Carol A.; Day, Amanda N.; Perry, R. B.; Harries, Tim J.; Aarnio, Alicia N.; Colavita, Mark M.; Wizinowich, Peter L.; Ragland, Sam; Woillez, Julien

2016-01-01

We present near- and mid-infrared (MIR) interferometric observations made with the Keck Interferometer Nuller and near-contemporaneous spectro-photometry from the infrared telescope facilities (IRTFs) of 11 well-known young stellar objects, several of which were observed for the first time in these spectral and spatial resolution regimes. With au-level spatial resolution, we first establish characteristic sizes of the infrared emission using a simple geometrical model consisting of a hot inne...

A Mid-Infrared Search for Kardashev Civilizations

Science.gov (United States)

Sigurdsson, Steinn; Wright, J.; Griffith, R.; Povich, M. S.

2014-01-01

We are using the WISE all-sky Source Catalog to search for and put upper limits on the existence of extraterrestrial civilizations with large energy supplies. Any galaxy-spanning (Type III) civilization with an energy supply of more than about one percent of its stellar luminosity will have detectable mid-infrared excess, and nearby (extended) galaxies with civilizations with supplies more than about 80% of their stellar luminosity will be well-distinguished from nearly all natural sources in WISE color-color space. Mid-infrared spectra, far-infrared photometry, and radio emission from CO can all be used to distinguish extraterrestrial mid-infrared radiation from dust.

Injection-seeded tunable mid-infrared pulses generated by difference frequency mixing

Science.gov (United States)

Miyamoto, Yuki; Hara, Hideaki; Masuda, Takahiko; Hiraki, Takahiro; Sasao, Noboru; Uetake, Satoshi

2017-03-01

We report on the generation of nanosecond mid-infrared pulses having frequency tunability, a narrow linewidth, and a high pulse energy. These pulses are obtained by frequency mixing between injection-seeded near-infrared pulses in potassium titanyl arsenate crystals. A continuous-wave external cavity laser diode or a Ti:sapphire ring laser is used as a tunable seeding source for the near-infrared pulses. The typical energy of the generated mid-infrared pulses is in the range of 0.4-1 mJ/pulse. The tuning wavelength ranges from 3142 to 4806 nm. A narrow linewidth of 1.4 GHz and good frequency reproducibility of the mid-infrared pulses are confirmed by observing a rovibrational absorption line of gaseous carbon monoxide at 4587 nm.

2 W high efficiency PbS mid-infrared surface emitting laser

Science.gov (United States)

Ishida, A.; Sugiyama, Y.; Isaji, Y.; Kodama, K.; Takano, Y.; Sakata, H.; Rahim, M.; Khiar, A.; Fill, M.; Felder, F.; Zogg, H.

2011-09-01

High efficiency laser operation with output power exceeding 2 W was obtained for vertical external-cavity PbS based IV-VI compound surface emitting quantum-well structures. The laser showed external quantum efficiency as high as 16%. Generally, mid-infrared III-V or II-VI semiconductor laser operation utilizing interband electron transitions are restricted by Auger recombination and free carrier absorption. Auger recombination is much lower in the IV-VI semiconductors, and the free-carrier absorption is significantly reduced by an optically pumped laser structure including multi-step optical excitation layers.

Laser-induced filaments in the mid-infrared

International Nuclear Information System (INIS)

Zheltikov, A M

2017-01-01

Laser-induced filamentation in the mid-infrared gives rise to unique regimes of nonlinear wave dynamics and reveals in many ways unusual nonlinear-optical properties of materials in this frequency range. The λ 2 scaling of the self-focusing threshold P cr , with radiation wavelength λ , allows the laser powers transmitted by single mid-IR filaments to be drastically increased without the loss of beam continuity and spatial coherence. When extended to the mid-infrared, laser filamentation enables new methods of pulse compression. Often working around the universal physical limitations, it helps generate few-cycle and subcycle field waveforms within an extraordinarily broad range of peak powers, from just a few up to hundreds of P cr . As a part of a bigger picture, laser-induced filamentation in the mid-infrared offers important physical insights into the general properties of the nonlinear-optical response of matter as a function of the wavelength. Unlike their near-infrared counterparts, which can be accurately described within the framework of perturbative nonlinear optics, mid-infrared filaments often entangle perturbative and nonperturbative nonlinear-optical effects, showing clear signatures of strong-field optical physics. With the role of nonperturbative nonlinear-optical phenomena growing, as a general tendency, with the field intensity and the driver wavelength, extension of laser filamentation to even longer driver wavelengths, toward the long-wavelength infrared, promises a hic sunt dracones land. (topical review)

Femtosecond few-cycle mid-infrared laser pulses

DEFF Research Database (Denmark)

Liu, Xing

The few-cycle pulses of mid-infrared (mid-IR, wavelength 2-10 microns) have attracted increasing attention owing to their great potentials for high order harmonic generation, time-resolved spectroscopy, precision of cutting and biomedical science.In this thesis, mid-IR frequency conversion.......2 - 5.5 μm with only one fixed pump wavelength, a feature absent in Kerr media. Finally, we experimentally observe supercontinuum generation spanning 1.5 octaves, generated in a 10 mm long silicon-rich nitride waveguide pumped by 100 pJ femtosecond pulses from an erbium fiber laser. The waveguide has...

Efficient, High-Power Mid-Infrared Laser for National Securityand Scientific Applications

Energy Technology Data Exchange (ETDEWEB)

Kiani, Leily S. [Lawrence Livermore National Lab. (LLNL), Livermore, CA (United States)

2017-11-02

The LLNL fiber laser group developed a unique short-wave-infrared, high-pulse energy, highaverage- power fiber based laser. This unique laser source has been used in combination with a nonlinear frequency converter to generate wavelengths, useful for remote sensing and other applications in the mid-wave infrared (MWIR). Sources with high average power and high efficiency in this MWIR wavelength region are not yet available with the size, weight, and power requirements or energy efficiency necessary for future deployment. The LLNL developed Fiber Laser Pulsed Source (FiLPS) design was adapted to Erbium doped silica fibers for 1.55 μm pumping of Cadmium Silicon Phosphide (CSP). We have demonstrated, for the first time optical parametric amplification of 2.4 μm light via difference frequency generation using CSP with an Erbium doped fiber source. In addition, for efficiency comparison purposes, we also demonstrated direct optical parametric generation (OPG) as well as optical parametric oscillation (OPO).

Young massive stars and their environment in the mid-infrared at high angular resolution

International Nuclear Information System (INIS)

Wit, W J de; Hoare, M G; Oudmaijer, R D; Fujiyoshi, T

2008-01-01

We present interferometric and single-dish mid-infrared observations of a sample of massive young stellar objects (BN-type objects), using VLTI-MIDI (10μm) and Subaru-COMICS (24.5 μm). We discuss the regions S140, Mon R2, M8E-IR, and W33A. The observations probe the inner regions of the dusty envelope at scales of 50 milli arcsecond and 0.6'' (∼100-1000 AU), respectively. Simultaneous model fits to spectral energy distributions and spatial data are achieved using self-consistent spherical envelope modelling. We conclude that those MYSO envelopes that are best described by a spherical geometry, the commensurate density distribution is a powerlaw with index -1.0. Such a powerlaw is predicted if the envelope is supported by turbulence on the 100-1000 AU scales probed with MIDI and COMICS, but the role of rotation at these spatial scales need testing.

High spectral resolution infrared observations of V1057 Cygni

International Nuclear Information System (INIS)

Hartmann, L.; Kenyon, S.J.

1987-01-01

High-resolution near-infrared spectra of V1057 Cygni obtained in 1986 with the KPNO 4-m Fourier transform spectrometer provide support for a previously proposed accretion disk model. The model predicts that the observed rotational broadening of spectral lines should be smaller in the infrared than in the optical. The present observations show that V1057 Cyg rotates more slowly at 2.3 microns than at 6000 A by an amount quantitatively consistent with the simple disk models. The absence of any radial velocity variations in either the infrared or optical spectral regions supports the suggestion that the accreted material arises from a remnant disk of protostellar material. 19 references

Infrared emission high spectral resolution atlas of the stratospheric limb

Science.gov (United States)

Maguire, William C.; Kunde, Virgil G.; Herath, Lawrence W.

1989-01-01

An atlas of high resolution infrared emission spectra identifies a number of gaseous atmospheric features significant to stratospheric chemistry in the 770-900/cm and 1100-1360/cm regions at six zenith angles from 86.7 to 95.1 deg. A balloon-borne Michelson interferometer was flown to obtain about 0.03/cm resolution spectra. Two 10/cm extracts are presented here.

Tunable Microcavity-Stabilized Quantum Cascade Laser for Mid-IR High-Resolution Spectroscopy and Sensing.

Science.gov (United States)

Borri, Simone; Siciliani de Cumis, Mario; Insero, Giacomo; Bartalini, Saverio; Cancio Pastor, Pablo; Mazzotti, Davide; Galli, Iacopo; Giusfredi, Giovanni; Santambrogio, Gabriele; Savchenkov, Anatoliy; Eliyahu, Danny; Ilchenko, Vladimir; Akikusa, Naota; Matsko, Andrey; Maleki, Lute; De Natale, Paolo

2016-02-17

The need for highly performing and stable methods for mid-IR molecular sensing and metrology pushes towards the development of more and more compact and robust systems. Among the innovative solutions aimed at answering the need for stable mid-IR references are crystalline microresonators, which have recently shown excellent capabilities for frequency stabilization and linewidth narrowing of quantum cascade lasers with compact setups. In this work, we report on the first system for mid-IR high-resolution spectroscopy based on a quantum cascade laser locked to a CaF₂ microresonator. Electronic locking narrows the laser linewidth by one order of magnitude and guarantees good stability over long timescales, allowing, at the same time, an easy way for finely tuning the laser frequency over the molecular absorption line. Improvements in terms of resolution and frequency stability of the source are demonstrated by direct sub-Doppler recording of a molecular line.

Generation of broadly tunable picosecond mid-infrared laser and sensitive detection of a mid-infrared signal by parametric frequency up-conversion in MgO:LiNbO3 optical parametric amplifiers

International Nuclear Information System (INIS)

Zhang Qiu-Lin; Zhang Jing; Qiu Kang-Sheng; Zhang Dong-Xiang; Feng Bao-Hua; Zhang Jing-Yuan

2012-01-01

Picosecond optical parametric generation and amplification in the near-infrared region within 1.361–1.656 μm and the mid-infrared region within 2.976–4.875 μm is constructed on the basis of bulk MgO:LiNbO 3 crystals pumped at 1.064 μm. The maximum pulse energy reaches 1.3 mJ at 1.464 μm and 0.47 mJ at 3.894 μm, corresponding to a pump-to-idler photon conversion efficiency of 25%. By seeding the hard-to-measure mid-infrared radiation as the idler in the optical parametric amplification and measuring the amplified and frequency up-converted signal in the near-infrared or even visible region, one can measure very week mid-infrared radiation with ordinary detectors, which are insensitive to mid-infrared radiation, with a very high gain. A maximum gain factor of about 7 × 10 7 is achieved at the mid-infrared wavelength of 3.374 μm and the corresponding energy detection limit is as low as about 390 aJ per pulse. (electromagnetism, optics, acoustics, heat transfer, classical mechanics, and fluid dynamics)

Tunable Microcavity-Stabilized Quantum Cascade Laser for Mid-IR High-Resolution Spectroscopy and Sensing

Directory of Open Access Journals (Sweden)

Simone Borri

2016-02-01

Full Text Available The need for highly performing and stable methods for mid-IR molecular sensing and metrology pushes towards the development of more and more compact and robust systems. Among the innovative solutions aimed at answering the need for stable mid-IR references are crystalline microresonators, which have recently shown excellent capabilities for frequency stabilization and linewidth narrowing of quantum cascade lasers with compact setups. In this work, we report on the first system for mid-IR high-resolution spectroscopy based on a quantum cascade laser locked to a CaF2 microresonator. Electronic locking narrows the laser linewidth by one order of magnitude and guarantees good stability over long timescales, allowing, at the same time, an easy way for finely tuning the laser frequency over the molecular absorption line. Improvements in terms of resolution and frequency stability of the source are demonstrated by direct sub-Doppler recording of a molecular line.

Mid-infrared response of reduced graphene oxide and its high-temperature coefficient of resistance

Directory of Open Access Journals (Sweden)

Haifeng Liang

2014-10-01

Full Text Available Much effort has been made to study the formation mechanisms of photocurrents in graphene and reduced graphene oxide films under visible and near-infrared light irradiation. A built-in field and photo-thermal electrons have been applied to explain the experiments. However, much less attention has been paid to clarifying the mid-infrared response of reduced graphene oxide films at room temperature. Thus, mid-infrared photoresponse and annealing temperature-dependent resistance experiments were carried out on reduced graphene oxide films. A maximum photocurrent of 75 μA was observed at room temperature, which was dominated by the bolometer effect, where the resistance of the films decreased as the temperature increased after they had absorbed light. The electrons localized in the defect states and the residual oxygen groups were thermally excited into the conduction band, forming a photocurrent. In addition, a temperature increase of 2 °C for the films after light irradiation for 2 minutes was observed using absorption power calculations. This work details a way to use reduced graphene oxide films that contain appropriate defects and residual oxygen groups as bolometer-sensitive materials in the mid-infrared range.

Mid-infrared spectroscopic characterisation of an ultra-broadband tunable EC-QCL system intended for biomedical applications

Science.gov (United States)

Vahlsing, T.; Moser, H.; Grafen, M.; Nalpantidis, K.; Brandstetter, M.; Heise, H. M.; Lendl, B.; Leonhardt, S.; Ihrig, D.; Ostendorf, A.

2015-07-01

Mid-infrared spectroscopy has been successfully applied for reagent-free clinical chemistry applications. Our aim is to design a portable bed-side system for ICU patient monitoring, based on mid-infrared absorption spectra of continuously sampled body-fluids. Robust and miniature bed-side systems can be achieved with tunable external cavity quantum cascade lasers (EC-QCL). Previously, single EC-QCL modules covering a wavenumber interval up to 250 cm-1 have been utilized. However, for broader applicability in biomedical research an extended interval around the mid-infrared fingerprint region should be accessible, which is possible with at least three or four EC-QCL modules. For such purpose, a tunable ultra-broadband system (1920 - 780 cm-1, Block Engineering) has been studied with regard to its transient emission characteristics in ns time resolution during different laser pulse widths using a VERTEX 80v FTIR spectrometer with step-scan option. Furthermore, laser emission line profiles of all four incorporated EC-QCL modules have been analysed at high spectral resolution (0.08 cm-1) and beam profiles with few deviations from the TEM 00 spatial mode have been manifested. Emission line reproducibility has been tested for various wavenumbers in step tune mode. The overall accuracy of manufacturer default wavenumber setting has been found between ± 3 cm-1 compared to the FTIR spectrometer scale. With regard to an application in clinical chemistry, theoretically achievable concentration accuracies for different blood substrates based on blood plasma and dialysate spectra previously recorded by FTIRspectrometers have been estimated taking into account the now accessible extended wavenumber interval.

High Resolution Infrared Radiation Sounder (HIRS) for the Nimbus F Spacecraft

Science.gov (United States)

Koenig, E. W.

1975-01-01

Flown on Nimbus F in June 1975, the high resolution infrared radiation sounder (HIRS) scans with a geographical resolution of 23KM and samples radiance in seventeen selected spectral channels from visible (.7 micron) to far IR (15 micron). Vertical temperature profiles and atmospheric moisture content can be inferred from the output. System operation and test results are described.

Immersion Gratings for Infrared High-resolution Spectroscopy

Science.gov (United States)

Sarugaku, Yuki; Ikeda, Yuji; Kobayashi, Naoto; Kaji, Sayumi; Sukegawa, Takashi; Sugiyama, Shigeru; Nakagawa, Takao; Arasaki, Takayuki; Kondo, Sohei; Nakanishi, Kenshi; Yasui, Chikako; Kawakita, Hideyo

2016-10-01

High-resolution spectroscopy in the infrared wavelength range is essential for observations of minor isotopologues, such as HDO for water, and prebiotic organic molecules like hydrocarbons/P-bearing molecules because numerous vibrational molecular bands (including non-polar molecules) are located in this wavelength range. High spectral resolution enables us to detect weak lines without spectral line confusion. This technique has been widely used in planetary sciences, e.g., cometary coma (H2O, CO, and organic molecules), the martian atmosphere (CH4, CO2, H2O and HDO), and the upper atmosphere of gas giants (H3+ and organic molecules such as C2H6). Spectrographs with higher resolution (and higher sensitivity) still have a potential to provide a plenty of findings. However, because the size of spectrographs scales with the spectral resolution, it is difficult to realize it.Immersion grating (IG), which is a diffraction grating wherein the diffraction surface is immersed in a material with a high refractive index (n > 2), provides n times higher spectral resolution compared to a reflective grating of the same size. Because IG reduces the size of spectrograph to 1/n compared to the spectrograph with the same spectral resolution using a conventional reflective grating, it is widely acknowledged as a key optical device to realize compact spectrographs with high spectral resolution.Recently, we succeeded in fabricating a CdZnTe immersion grating with the theoretically predicted diffraction efficiency by machining process using an ultrahigh-precision five-axis processing machine developed by Canon Inc. Using the same technique, we completed a practical germanium (Ge) immersion grating with both a reflection coating on the grating surface and the an AR coating on the entrance surface. It is noteworthy that the wide wavelength range from 2 to 20 um can be covered by the two immersion gratings.In this paper, we present the performances and the applications of the immersion

The Mid-Infrared Instrument for the James Webb Space Telescope, I: Introduction

DEFF Research Database (Denmark)

Rieke, G. H.; Wright, G. S.; Böker, T.

2015-01-01

MIRI (the Mid-Infrared Instrument for the James Webb Space Telescope [JWST]) operates from 5 to 28: 5 μm and combines over this range: (1) unprecedented sensitivity levels; (2) subarcsecond angular resolution; (3) freedom from atmospheric interference; (4) the inherent stability of observing...... in space; and (5) a suite of versatile capabilities including imaging, low- and medium-resolution spectroscopy (with an integral field unit), and coronagraphy. We illustrate the potential uses of this unique combination of capabilities with various science examples: (1) imaging exoplanets; (2) transit...

THE EXTENDED HIGH A ( V ) QUASAR SURVEY: SEARCHING FOR DUSTY ABSORBERS TOWARD MID-INFRARED-SELECTED QUASARS

Energy Technology Data Exchange (ETDEWEB)

Krogager, J.-K.; Noterdaeme, P. [Institut d’Astrophysique de Paris, CNRS-UPMC, UMR7095, 98bis bd Arago, F-75014 Paris (France); Fynbo, J. P. U.; Heintz, K. E.; Vestergaard, M. [Dark Cosmology Centre, Niels Bohr Institute, University of Copenhagen, Juliane Maries Vej 30, DK-2100 Copenhagen Ø (Denmark); Geier, S. [Instituto de Astrofísica de Canarias (IAC), E-38205 La Laguna, Tenerife (Spain); Ledoux, C. [European Southern Observatory, Alonso de Córdova 3107, Vitacura, Casilla 19001, Santiago 19 (Chile); Møller, P. [European Southern Observatory, Karl-Schwarzschildstrasse 2, D-85748 Garching bei München (Germany); Venemans, B. P. [Max-Planck Institute for Astronomy, Königstuhl 17, D-69117 Heidelberg (Germany)

2016-11-20

We present the results of a new spectroscopic survey for dusty intervening absorption systems, particularly damped Ly α absorbers (DLAs), toward reddened quasars. The candidate quasars are selected from mid-infrared photometry from the Wide-field Infrared Survey Explorer combined with optical and near-infrared photometry. Out of 1073 candidates, we secure low-resolution spectra for 108 using the Nordic Optical Telescope on La Palma, Spain. Based on the spectra, we are able to classify 100 of the 108 targets as quasars. A large fraction (50%) is observed to have broad absorption lines (BALs). Moreover, we find six quasars with strange breaks in their spectra, which are not consistent with regular dust reddening. Using template fitting, we infer the amount of reddening along each line of sight ranging from A ( V ) ≈ 0.1 to 1.2 mag (assuming a Small Magellanic Cloud extinction curve). In four cases, the reddening is consistent with dust exhibiting the 2175 Å feature caused by an intervening absorber, and for two of these, an Mg ii absorption system is observed at the best-fit absorption redshift. In the rest of the cases, the reddening is most likely intrinsic to the quasar. We observe no evidence for dusty DLAs in this survey. However, the large fraction of BAL quasars hampers the detection of absorption systems. Out of the 50 non-BAL quasars, only 28 have sufficiently high redshift to detect Ly α in absorption.

High spatial resolution infrared camera as ISS external experiment

Science.gov (United States)

Eckehard, Lorenz; Frerker, Hap; Fitch, Robert Alan

High spatial resolution infrared camera as ISS external experiment for monitoring global climate changes uses ISS internal and external resources (eg. data storage). The optical experiment will consist of an infrared camera for monitoring global climate changes from the ISS. This technology was evaluated by the German small satellite mission BIRD and further developed in different ESA projects. Compared to BIRD the presended instrument uses proven sensor advanced technologies (ISS external) and ISS on board processing and storage capabili-ties (internal). The instrument will be equipped with a serial interfaces for TM/TC and several relay commands for the power supply. For data processing and storage a mass memory is re-quired. The access to actual attitude data is highly desired to produce geo referenced maps-if possible by an on board processing.

Mid-infrared photonics in silicon and germanium

Science.gov (United States)

Soref, Richard

2010-08-01

Ingenious techniques are needed to extend group IV photonics from near-infrared to mid-infrared wavelengths. If achieved, the reward could be on-chip CMOS optoelectronic systems for use in spectroscopy, chemical and biological sensing, and free-space communications.

Mid infrared LHS system packaging using flexible waveguides

Science.gov (United States)

Yu, Chung

1987-01-01

As mid IR fiber optic systems are rapidly approaching a reality, so is the feasibility of fiber optic laser heterodyne systems. Laser heterodyne spectroscopy for high resolution monitoring of atmospheric gaseous pollutants is necessarily in the mid IR, the region in which the absorption signature of gaseous species is most prominent. It so happens that the lowest theoretical loss due to Rayleigh-Brillouin scattering also lies in the mid IR. Prospects of highly efficient laser heterodyne systems are thus very good. Such fibers are now beginning to be commercially available, and a test program is being conducted for such fibers with ambient temperature ranging from cryogenic to above room, and stringest mechanical flexibility requirements. Preliminary results are encouraging. A program is being started to explore the possibility of mid IR fiber optic device applications, by taking advantage of this phonon rich region. The potential long interaction length in fibers coupled with predicted extremely low losses point to stimulated Brillouin scattering based devices in the mW range. The generation of backscattered sBs at low laser powers is significant not only as an ultimate power limiting factor for laser transmission in fibers in the mid IR, but also the presence of frequency-shifted multiple order sBs Stokes and antiStokes lines will certainly have severe effect on the laser beats crucial in high resolution heterodyne spectroscopy.

Development of infrared Echelle spectrograph and mid-infrared heterodyne spectrometer on a small telescope at Haleakala, Hawaii for planetary observation

Science.gov (United States)

Sakanoi, Takeshi; Kasaba, Yasumasa; Kagitani, Masato; Nakagawa, Hiromu; Kuhn, Jeff; Okano, Shoichi

2014-08-01

We report the development of infrared Echelle spectrograph covering 1 - 4 micron and mid-infrared heterodyne spectrometer around 10 micron installed on the 60-cm telescope at the summit of Haleakala, Hawaii (alt.=3000m). It is essential to carry out continuous measurement of planetary atmosphere, such as the Jovian infrared aurora and the volcanoes on Jovian satellite Io, to understand its time and spatial variations. A compact and easy-to-use high resolution infrared spectrometer provide the good opportunity to investigate these objects continuously. We are developing an Echelle spectrograph called ESPRIT: Echelle Spectrograph for Planetary Research In Tohoku university. The main target of ESPRIT is to measure the Jovian H3+ fundamental line at 3.9 micron, and H2 nu=1 at 2.1 micron. The 256x256 pixel CRC463 InSb array is used. An appropriate Echelle grating is selected to optimize at 3.9 micron and 2.1 micron for the Jovian infrared auroral observations. The pixel scale corresponds to the atmospheric seeing (0.3 arcsec/pixel). This spectrograph is characterized by a long slit field-of-view of ~ 50 arcsec with a spectral resolution is over 20,000. In addition, we recently developed a heterodyne spectrometer called MILAHI on the 60 cm telescope. MILAHI is characterized by super high-resolving power (more than 1,500,000) covering from 7 - 13 microns. Its sensitivity is 2400 K at 9.6 micron with a MCT photo diode detector of which bandwidth of 3000 MHz. ESPRIT and MILAHI is planned to be installed on 60 cm telescope is planned in 2014.

Mid-infrared supercontinuum generation in the fingerprint region

DEFF Research Database (Denmark)

Møller, Uffe Visbech; Petersen, Christian Rosenberg; Kubat, Irnis

The mid-infrared spectral region is of great technical and scientific interest because most molecules display fundamental vibrational absorptions in this region, leaving distinctive spectral fingerprints. Here, we demonstrate experimentally that launching intense ultra-short pulses with a central...... the potential of fibres to emit across the mid-infrared molecular fingerprint region, which is of key importance for applications such as early cancer diagnostics, gas sensing and food quality control....

High resolution infrared spectroscopy of symbiotic stars

International Nuclear Information System (INIS)

Bensammar, S.

1989-01-01

We report here very early results of high resolution (5x10 3 - 4x10 4 ) infrared spectroscopy (1 - 2.5 μm) of different symbiotic stars (T CrB, RW Hya, CI Cyg, PU Vul) observed with the Fourier Transform Spectrometer of the 3.60m Canada France Hawaii Telescope. These stars are usually considered as interacting binaries and only little details are known about the nature of their cool component. CO absorption lines are detected for the four stars. Very different profiles of hydrogen Brackett γ and helium 10830 A lines are shown for CI Cyg observed at different phases, while Pu Vul shows very intense emission lines

THE SPITZER MID-INFRARED ACTIVE GALACTIC NUCLEUS SURVEY. I. OPTICAL AND NEAR-INFRARED SPECTROSCOPY OF OBSCURED CANDIDATES AND NORMAL ACTIVE GALACTIC NUCLEI SELECTED IN THE MID-INFRARED

Energy Technology Data Exchange (ETDEWEB)

Lacy, M. [National Radio Astronomy Observatory, 520 Edgemont Road, Charlottesville, VA 22903 (United States); Ridgway, S. E. [National Optical Astronomy Observatory, 950 North Cherry Avenue, Tucson, AZ 85719 (United States); Gates, E. L. [UCO/Lick Observatory, P.O. Box 85, Mount Hamilton, CA 95140 (United States); Nielsen, D. M. [Department of Astronomy, University of Wisconsin, 475 N. Charter Street, Madison, WI 53706 (United States); Petric, A. O. [Department of Astronomy, California Institute of Technology, Pasadena, CA 91125 (United States); Sajina, A. [Department of Physics and Astronomy, Tuffs University, 212 College Avenue, Medford, MA 02155 (United States); Urrutia, T. [Leibniz-Institut für Astrophysik Potsdam, An der Sternwarte 16, D-14482 Potsdam (Germany); Cox Drews, S. [946 Mangrove Avenue 102, Sunnyvale, CA 94086 (United States); Harrison, C. [Department of Astronomy, University of Michigan, Ann Arbor, MI 48109 (United States); Seymour, N. [CSIRO, P.O. Box 76, Epping, NSW 1710 (Australia); Storrie-Lombardi, L. J. [Spitzer Science Center, California Institute of Technology, Pasadena, CA 91125 (United States)

2013-10-01

We present the results of a program of optical and near-infrared spectroscopic follow-up of candidate active galactic nuclei (AGNs) selected in the mid-infrared. This survey selects both normal and obscured AGNs closely matched in luminosity across a wide range, from Seyfert galaxies with bolometric luminosities L {sub bol} ∼ 10{sup 10} L {sub ☉} to highly luminous quasars (L {sub bol} ∼ 10{sup 14} L {sub ☉}), all with redshifts ranging from 0 to 4.3. Samples of candidate AGNs were selected with mid-infrared color cuts at several different 24 μm flux density limits to ensure a range of luminosities at a given redshift. The survey consists of 786 candidate AGNs and quasars, of which 672 have spectroscopic redshifts and classifications. Of these, 137 (20%) are type 1 AGNs with blue continua, 294 (44%) are type 2 objects with extinctions A{sub V} ∼> 5 toward their AGNs, 96 (14%) are AGNs with lower extinctions (A{sub V} ∼ 1), and 145 (22%) have redshifts, but no clear signs of AGN activity in their spectra. Of the survey objects 50% have L {sub bol} > 10{sup 12} L {sub ☉}, in the quasar regime. We present composite spectra for type 2 quasars and objects with no signs of AGN activity in their spectra. We also discuss the mid-infrared—emission-line luminosity correlation and present the results of cross correlations with serendipitous X-ray and radio sources. The results show that: (1) obscured objects dominate the overall AGN population, (2) mid-infrared selected AGN candidates exist which lack AGN signatures in their optical spectra but have AGN-like X-ray or radio counterparts, and (3) X-ray and optical classifications of obscured and unobscured AGNs often differ.

Monolithic beam steering in a mid-infrared, surface-emitting, photonic integrated circuit.

Science.gov (United States)

Slivken, Steven; Wu, Donghai; Razeghi, Manijeh

2017-08-16

The mid-infrared (2.5 < λ < 25 μm) spectral region is utilized for many purposes, such as chemical/biological sensing, free space communications, and illuminators/countermeasures. Compared to near-infrared optical systems, however, mid-infrared component technology is still rather crude, with isolated components exhibiting limited functionality. In this manuscript, we make a significant leap forward in mid-infrared technology by developing a platform which can combine functions of multiple mid-infrared optical elements, including an integrated light source. In a single device, we demonstrate wide wavelength tuning (240 nm) and beam steering (17.9 degrees) in the mid-infrared with a significantly reduced beam divergence (down to 0.5 degrees). The architecture is also set up to be manufacturable and testable on a wafer scale, requiring no cleaved facets or special mirror coating to function.

MID-INFRARED PROPERTIES OF THE SWIFT BURST ALERT TELESCOPE ACTIVE GALACTIC NUCLEI SAMPLE OF THE LOCAL UNIVERSE. I. EMISSION-LINE DIAGNOSTICS

International Nuclear Information System (INIS)

Weaver, K. A.; Melendez, M.; Mushotzky, R. F.; Kraemer, S.; Engle, K.; Malumuth, E.; Tueller, J.; Markwardt, C.; Berghea, C. T.; Dudik, R. P.; Winter, L. M.; Armus, L.

2010-01-01

We compare mid-infrared emission-line properties from high-resolution Spitzer spectra of a hard X-ray (14-195 keV) selected sample of nearby (z < 0.05) active galactic nuclei (AGNs) detected by the Burst Alert Telescope (BAT) aboard Swift. The luminosity distribution for the mid-infrared emission lines, [O IV] 25.89 μm, [Ne II] 12.81 μm, [Ne III] 15.56 μm, and [Ne V] 14.32/24.32 μm, and hard X-ray continuum show no differences between Seyfert 1 and Seyfert 2 populations; however, six newly discovered BAT AGNs are under-luminous in [O IV], most likely the result of dust extinction in the host galaxy. The overall tightness of the mid-infrared correlations and BAT fluxes and luminosities suggests that the emission lines primarily arise in gas ionized by the AGNs. We also compare the mid-infrared emission lines in the BAT AGNs with those from published studies of ULIRGs, Palomar-Green quasars, star-forming galaxies, and LINERs. We find that the BAT AGN sample falls into a distinctive region when comparing the [Ne III]/[Ne II] and the [O IV]/[Ne III] ratios. These line ratios are lower in sources that have been previously classified in the mid-infrared/optical as AGNs than those found for the BAT AGNs, suggesting that, in our X-ray selected sample, the AGNs represent the main contribution to the observed line emission. These ratios represent a new emission line diagnostic for distinguishing between AGNs and star-forming galaxies.

Towards supercontinuum-driven hyperspectral microscopy in the mid-infrared

DEFF Research Database (Denmark)

Lindsay, I. D.; Valle, S.; Ward, J.

2016-01-01

The extension of supercontinuum (SC) sources into the mid-infrared, via the use of fluoride and chalcogenide optical fibers, potentially offers the high radiance of a laser combined with spectral coverage far exceeding that of typical tunable lasers and comparable to traditional black-body emitte...

Broadband mid-infrared superlattice light-emitting diodes

Science.gov (United States)

Ricker, R. J.; Provence, S. R.; Norton, D. T.; Boggess, T. F.; Prineas, J. P.

2017-05-01

InAs/GaSb type-II superlattice light-emitting diodes were fabricated to form a device that provides emission over the entire 3-5 μm mid-infrared transmission window. Variable bandgap emission regions were coupled together using tunnel junctions to emit at peak wavelengths of 3.3 μm, 3.5 μm, 3.7 μm, 3.9 μm, 4.1 μm, 4.4 μm, 4.7 μm, and 5.0 μm. Cascading the structure recycles the electrons in each emission region to emit several wavelengths simultaneously. At high current densities, the light-emitting diode spectra broadened into a continuous, broadband spectrum that covered the entire mid-infrared band. When cooled to 77 K, radiances of over 1 W/cm2 sr were achieved, demonstrating apparent temperatures above 1000 K over the 3-5 μm band. InAs/GaSb type-II superlattices are capable of emitting from 3 μm to 30 μm, and the device design can be expanded to include longer emission wavelengths.

Photon-Counting Microwave Kinetic Inductance Detectors (MKIDs) for High Resolution Far-Infrared Spectroscopy

Data.gov (United States)

National Aeronautics and Space Administration — We are developing ultrasensitive Microwave Kinetic Inductance Detectors (MKIDs) for high resolution far-infrared spectroscopy applications, with a long-term goal of...

Far-and mid-infrared properties of carbon layers elaborated by plasma sputtering

Energy Technology Data Exchange (ETDEWEB)

Rousseau, Benoit, E-mail: benoit.rousseau@univ-nantes.fr [Université de Nantes, CNRS, LTN UMR6607, La Chantrerie, Rue Christian Pauc, B.P. 50609, F-44306 Nantes Cedex 3 (France); Ammar, Mohamed Ramzi; Bormann, Denis; Simon, Patrick [CNRS, CEMHTI UPR3079, Université d' Orléans, F-55071 (France); Rabat, Hervé; Brault, Pascal [Université d' Orléans, CNRS, GREMI UMR7344, BP 6744, F-45067 Orléans Cedex 2 (France)

2016-12-30

Highlights: • Magnetron sputtering deposition of columnar, disordered carbon films. • Sputtered carbon films infrared properties are dependent on the local order. • Film texture at the micro-nanoscale explains difference of optical properties. - Abstract: The far-and mid-infrared reflectivity spectra of two carbon layers deposited on pure (100) silicon substrates by DC magnetron sputtering were investigated at room temperature in the 10–5000 cm{sup −1} wavenumber range. Their structural and textural features were also studied by combining Raman spectroscopy, Field Emission Scanning Electron Microscopy (FESEM), High Resolution Transmission Electron Microscopy (HRTEM), X-Ray Reflectivity (XRR) and Rutherford Backscattering Spectroscopy (RBS). The set of results was used to discuss afterwards the influence of the texture on the infrared properties at varying length scale. Thereby, the two layers were found to be heterogeneous as assessed by RBS, XRR and FESEM and their thicknesses had been measured by XRR and FESEM. The information on the structural organization and “crystallite” size was given by Raman spectroscopy. The influence of both the textural and structural parameters on the measured infrared reflectivity spectra was discussed. Finally, a methodology was proposed to recover the intrinsic index of refraction and the intrinsic index of absorption of each layer.

Mid-infrared Variability of Changing-look AGNs

International Nuclear Information System (INIS)

Sheng, Zhenfeng; Wang, Tinggui; Jiang, Ning; Yang, Chenwei; Peng, Bo; Yan, Lin; Dou, Liming

2017-01-01

It is known that some active galactic nuclei (AGNs) transit from Type 1 to Type 2 or vice versa. There are two explanations for the so-called changing-look AGNs: one is the dramatic change of the obscuration along the line of sight, and the other is the variation of accretion rate. In this Letter, we report the detection of large amplitude variations in the mid-infrared luminosity during the transitions in 10 changing-look AGNs using the Wide-field Infrared Survey Explorer ( WISE ) and newly released Near-Earth Object WISE Reactivation data. The mid-infrared light curves of 10 objects echo the variability in the optical band with a time lag expected for dust reprocessing. The large variability amplitude is inconsistent with the scenario of varying obscuration, rather it supports the scheme of dramatic change in the accretion rate.

Mid-infrared Variability of Changing-look AGNs

Energy Technology Data Exchange (ETDEWEB)

Sheng, Zhenfeng; Wang, Tinggui; Jiang, Ning; Yang, Chenwei; Peng, Bo [CAS Key Laboratory for Researches in Galaxies and Cosmology, University of Sciences and Technology of China, Hefei, Anhui 230026 (China); Yan, Lin [Caltech Optical Observatories, Cahill Center for Astronomy and Astrophysics, California Institute of Technology, Pasadena, CA 91125 (United States); Dou, Liming, E-mail: shengzf@mail.ustc.edu.cn, E-mail: twang@ustc.edu.cn [Center for Astrophysics, Guangzhou University, Guangzhou 510006 (China)

2017-09-01

It is known that some active galactic nuclei (AGNs) transit from Type 1 to Type 2 or vice versa. There are two explanations for the so-called changing-look AGNs: one is the dramatic change of the obscuration along the line of sight, and the other is the variation of accretion rate. In this Letter, we report the detection of large amplitude variations in the mid-infrared luminosity during the transitions in 10 changing-look AGNs using the Wide-field Infrared Survey Explorer ( WISE ) and newly released Near-Earth Object WISE Reactivation data. The mid-infrared light curves of 10 objects echo the variability in the optical band with a time lag expected for dust reprocessing. The large variability amplitude is inconsistent with the scenario of varying obscuration, rather it supports the scheme of dramatic change in the accretion rate.

High Power Mid-Infrared Generation with a Quasi-Phase Matched GaAs Guided-wave Optical Parametric Oscillator

National Research Council Canada - National Science Library

Harris, J

2000-01-01

...-power coherent mid-infrared sources. Considerable effort has been devoted over the past decade to the development of mid-IR coherent sources based on nonlinear optical frequency conversion, e.g...

Mid-infrared supercontinuum covering the 1.4–13.3 μm molecular fingerprint region using ultra-high NA chalcogenide step-index fibre

DEFF Research Database (Denmark)

Petersen, Christian Rosenberg; Møller, Uffe Visbech; Kubat, Irnis

2014-01-01

-power laser diodes, quantum cascade lasers and synchrotron radiation have precluded mid-infrared applications where the spatial coherence, broad bandwidth, high brightness and portability of a supercontinuum laser are all required. Here, we demonstrate experimentally that launching intense ultra-short pulses...... the potential of fibres to emit across the mid-infrared molecular ‘fingerprint region’, which is of key importance for applications such as early cancer diagnostics3, gas sensing and food quality control....

Two-crystal mid-infrared optical parametric oscillator for absorption and dispersion dual-comb spectroscopy.

Science.gov (United States)

Jin, Yuwei; Cristescu, Simona M; Harren, Frans J M; Mandon, Julien

2014-06-01

We present a femtosecond optical parametric oscillator (OPO) containing two magnesium-doped periodically poled lithium niobate crystals in a singly resonant ring cavity, pumped by two mode-locked Yb-fiber lasers. As such, the OPO generates two idler combs (up to 220 mW), covering a wavelength range from 2.7 to 4.2 μm, from which a mid-infrared dual-comb Fourier transform spectrometer is constructed. By detecting the heterodyning signal between the two idler beams a full broadband spectrum of a molecular gas can be observed over 250  cm(-1) within 70 μs with a spectral resolution of 15 GHz. The absorption and dispersion spectra of acetylene and methane have been measured around 3000  cm(-1), indicating that this OPO represents an ideal broadband mid-infrared source for fast chemical sensing.

Mid-infrared volume diffraction gratings in IG2 chalcogenide glass: fabrication, characterization, and theoretical verification

Science.gov (United States)

Butcher, Helen L.; MacLachlan, David G.; Lee, David; Brownsword, Richard A.; Thomson, Robert R.; Weidmann, Damien

2018-02-01

Ultrafast laser inscription (ULI) has previously been employed to fabricate volume diffraction gratings in chalcogenide glasses, which operate in transmission mode in the mid-infrared spectral region. Prior gratings were manufactured for applications in astrophotonics, at wavelengths around 2.5 μm. Rugged volume gratings also have potential use in remote atmospheric sensing and molecular spectroscopy; for these applications, longer wavelength operation is required to coincide with atmospheric transparency windows (3-5 μm) and intense ro-vibrational molecular absorption bands. We report on ULI gratings inscribed in IG2 chalcogenide glass, enabling access to the full 3-5 μm window. High-resolution broadband spectral characterization of fabricated gratings was performed using a Fourier transform spectrometer. The zeroth order transmission was characterized to derive the diffraction efficiency into higher orders, up to the fourth orders in the case of gratings optimized for first order diffraction at 3 μm. The outcomes imply that ULI in IG2 is well suited for the fabrication of volume gratings in the mid infrared, providing the impact of the ULI fabrication parameters on the grating properties are well understood. To develop this understanding, grating modeling was conducted. Parameters studied include grating thickness, refractive index modification, and aspect ratio of the modulation achieved by ULI. Knowledge of the contribution and sensitivity of these parameters was used to inform the design of a 4.3 μm grating expected to achieve > 95% first order efficiency. We will also present the characterization of these latest mid-infrared diffraction gratings in IG2.

Mid-infrared integrated photonics on silicon: a perspective

Directory of Open Access Journals (Sweden)

Lin Hongtao

2017-12-01

Full Text Available The emergence of silicon photonics over the past two decades has established silicon as a preferred substrate platform for photonic integration. While most silicon-based photonic components have so far been realized in the near-infrared (near-IR telecommunication bands, the mid-infrared (mid-IR, 2–20-μm wavelength band presents a significant growth opportunity for integrated photonics. In this review, we offer our perspective on the burgeoning field of mid-IR integrated photonics on silicon. A comprehensive survey on the state-of-the-art of key photonic devices such as waveguides, light sources, modulators, and detectors is presented. Furthermore, on-chip spectroscopic chemical sensing is quantitatively analyzed as an example of mid-IR photonic system integration based on these basic building blocks, and the constituent component choices are discussed and contrasted in the context of system performance and integration technologies.

Modelling of mid-infrared interferometric signature of hot exozodiacal dust emission

Science.gov (United States)

Kirchschlager, Florian; Wolf, Sebastian; Brunngräber, Robert; Matter, Alexis; Krivov, Alexander V.; Labdon, Aaron

2018-01-01

Hot exozodiacal dust emission was detected in recent surveys around two dozen main-sequence stars at distances of less than 1 au using the H- and K-band interferometry. Due to the high contrast as well as the small angular distance between the circumstellar dust and the star, direct observation of this dust component is challenging. An alternative way to explore the hot exozodiacal dust is provided by mid-infrared interferometry. We analyse the L, M and N bands interferometric signature of this emission in order to find stronger constraints for the properties and the origin of the hot exozodiacal dust. Considering the parameters of nine debris disc systems derived previously, we model the discs in each of these bands. We find that the M band possesses the best conditions to detect hot dust emission, closely followed by L and N bands. The hot dust in three systems - HD 22484 (10 Tau), HD 102647 (β Leo) and HD 177724 (ζ Aql) - shows a strong signal in the visibility functions, which may even allow one to constrain the dust location. In particular, observations in the mid-infrared could help to determine whether the dust piles up at the sublimation radius or is located at radii up to 1 au. In addition, we explore observations of the hot exozodiacal dust with the upcoming mid-infrared interferometer Multi AperTure mid-Infrared SpectroScopic Experiment (MATISSE) at the Very Large Telescope Interferometer.

Conceptual thermal design and analysis of a far-infrared/mid-infrared remote sensing instrument

Science.gov (United States)

Roettker, William A.

1992-07-01

This paper presents the conceptual thermal design and analysis results for the Spectroscopy of the Atmosphere using Far-Infrared Emission (SAFIRE) instrument. SAFIRE has been proposed for Mission to Planet Earth to study ozone chemistry in the middle atmosphere using remote sensing of the atmosphere in the far-infrared (21-87 microns) and mid-infrared (9-16 microns) spectra. SAFIRE requires that far-IR detectors be cooled to 3-4 K and mid-IR detectors to 80 K for the expected mission lifetime of five years. A superfluid helium dewar and Stirling-cycle cryocoolers provide the cryogenic temperatures required by the infrared detectors. The proposed instrument thermal design uses passive thermal control techniques to reject 465 watts of waste heat from the instrument.

Mid-Infrared Frequency-Agile Dual-Comb Spectroscopy

Science.gov (United States)

Luo, Pei-Ling; Yan, Ming; Iwakuni, Kana; Millot, Guy; Hänsch, Theodor W.; Picqué, Nathalie

2016-06-01

We demonstrate a new approach to mid-infrared dual-comb spectroscopy. It opens up new opportunities for accurate real-time spectroscopic diagnostics and it significantly simplifies the technique of dual-comb spectroscopy. Two mid-infrared frequency combs of slightly different repetition frequencies and moderate, but rapidly tunable, spectral span are generated in the 2800-3200 cm-1 region. The generators rely on electro-optic modulators, nonlinear fibers for spectral broadening and difference frequency generation and do not involve mode-locked lasers. Flat-top frequency combs span up to 10 cm-1 with a comb line spacing of 100 MHz (3×10-3 cm-1). The performance of the spectrometer without any phase-lock electronics or correction scheme is illustrated with spectra showing resolved comb lines and Doppler-limited spectra of methane. High precision on the spectroscopic parameter (line positions and intensities) determination is demonstrated for spectra measured on a millisecond time scale and it is validated with comparison with literature data. G. Millot, S. Pitois, M. Yan, T. Hovannysyan, A. Bendahmane, T.W. Hänsch, N. Picqué, Frequency-agile dual-comb spectroscopy, Nature Photonics 10, 27-30 (2016).

Generation of Mid-Infrared Frequency Combs for Spectroscopic Applications

Science.gov (United States)

Maser, Daniel L.

Mid-infrared laser sources prove to be a valuable tool in exploring a vast array of phenomena, finding their way into applications ranging from trace gas detection to X-ray generation and carbon dating. Mid-infrared frequency combs, in particular, are well-suited for many of these applications, owing to their inherent low-noise and broadband nature. Frequency comb technology is well-developed in the near-infrared as a result of immense technological development by the telecommunication industry in silica fiber and the existence of readily-available glass dopants such as ytterbium and erbium that enable oscillators at 1 and 1.5 ?m. However, options become substantially more limited at longer wavelengths, as silica is no longer transparent and the components required in a mid-infrared frequency comb system (oscillators, fibers, and both fiber and free-space components) are far less technologically mature. This thesis explores several different approaches to generating frequency comb sources in the mid-infrared region, and the development of sources used in the nonlinear processes implemented to reach these wavelengths. An optical parametric oscillator, two approaches to difference frequency generation, and nonlinear spectral broadening in chip-scale waveguides are developed, characterized, and spectroscopic potential for these techniques is demonstrated. The source used for these nonlinear processes, the erbium-doped fiber amplifier, is also studied and discussed throughout the design and optimization process. The nonlinear optical processes critical to this work are numerically modeled and used to confirm and predict experimental behavior.

Mid-infrared spectroscopy in skin cancer cell type identification

Science.gov (United States)

Kastl, Lena; Kemper, Björn; Lloyd, Gavin R.; Nallala, Jayakrupakar; Stone, Nick; Naranjo, Valery; Penaranda, Francisco; Schnekenburger, Jürgen

2017-07-01

Mid infrared spectroscopy samples were developed for the analysis of skin tumor cell types and three dimensional tissue phantoms towards the application of midIR spectroscopy for fast and reliable skin cancer diagnostics.

Mid-Season High-Resolution Satellite Imagery for Forecasting Site-Specific Corn Yield

Directory of Open Access Journals (Sweden)

Nahuel R. Peralta

2016-10-01

Full Text Available A timely and accurate crop yield forecast is crucial to make better decisions on crop management, marketing, and storage by assessing ahead and implementing based on expected crop performance. The objective of this study was to investigate the potential of high-resolution satellite imagery data collected at mid-growing season for identification of within-field variability and to forecast corn yield at different sites within a field. A test was conducted on yield monitor data and RapidEye satellite imagery obtained for 22 cornfields located in five different counties (Clay, Dickinson, Rice, Saline, and Washington of Kansas (total of 457 ha. Three basic tests were conducted on the data: (1 spatial dependence on each of the yield and vegetation indices (VIs using Moran’s I test; (2 model selection for the relationship between imagery data and actual yield using ordinary least square regression (OLS and spatial econometric (SPL models; and (3 model validation for yield forecasting purposes. Spatial autocorrelation analysis (Moran’s I test for both yield and VIs (red edge NDVI = NDVIre, normalized difference vegetation index = NDVIr, SRre = red-edge simple ratio, near infrared = NIR and green-NDVI = NDVIG was tested positive and statistically significant for most of the fields (p < 0.05, except for one. Inclusion of spatial adjustment to model improved the model fit on most fields as compared to OLS models, with the spatial adjustment coefficient significant for half of the fields studied. When selected models were used for prediction to validate dataset, a striking similarity (RMSE = 0.02 was obtained between predicted and observed yield within a field. Yield maps could assist implementing more effective site-specific management tools and could be utilized as a proxy of yield monitor data. In summary, high-resolution satellite imagery data can be reasonably used to forecast yield via utilization of models that include spatial adjustment to

An infrared view of high Tc superconductors

International Nuclear Information System (INIS)

Tanner, D.B.; Timusk, T.; McMaster Univ., Hamilton, ON

1989-01-01

Studies of the infrared properties of the high T c superconductors are reviewed, with particular emphasis on attempts to determine the energy gap by far infrared spectroscopy and on the properties of the strong absorption that occurs in the mid infrared. The authors argue that this mid-infrared absorption is a direct particle-hole excitation rather than a Holstein emission process. In addition, they conclude that although the energy gap is not easily observed, several recent experiments place it in the weak to moderate strong coupling range

Silicon Based Mid Infrared SiGeSn Heterostructure Emitters and Detectors

Science.gov (United States)

2016-05-16

AFRL-AFOSR-JP-TR-2016-0054 Silicon based mid infrared SiGeSn heterostrcture emitters and detectors Greg Sun UNIVERSITY OF MASSACHUSETTS Final Report... Silicon Based Mid Infrared SiGeSn Heterostructure Emitters and Detectors ” February 10, 2016 Principal Investigator: Greg Sun Engineering...diodes are incompatible with the CMOS process and therefore cannot be easily integrated with Si electronics . The GeSn mid IR detectors developed in

THE HIGH-RESOLUTION INFRARED SPECTRUM OF HCl{sup +}

Energy Technology Data Exchange (ETDEWEB)

Doménech, J. L.; Herrero, V. J.; Tanarro, I. [Molecular Physics Department, Instituto de Estructura de la Materia (IEM-CSIC), Serrano 123, E-28006 Madrid (Spain); Drouin, B. J. [Jet Propulsion Laboratory, California Institute of Technology, 4800 Oak Grove Drive, Pasadena, CA 91109-8099 (United States); Cernicharo, J., E-mail: jl.domenech@csic.es [Molecular Astrophysics Group, Instituto de Ciencia de Materiales de Madrid (ICMM-CSIC), Sor Juana Inés de la Cruz 3, Cantoblanco, E-28049 Madrid (Spain)

2016-12-20

The chloroniumyl cation, HCl{sup +}, has been recently identified in space from Herschel 's spectra. A joint analysis of extensive vis-UV spectroscopy emission data together with a few high-resolution and high-accuracy millimeter-wave data provided the necessary rest frequencies to support the astronomical identification. Nevertheless, the analysis did not include any infrared (IR) vibration–rotation data. Furthermore, with the end of the Herschel mission, IR observations from the ground may be one of the few available means to further study this ion in space. In this work, we provide a set of accurate rovibrational transition wavenumbers, as well as a new and improved global fit of vis-UV, IR, and millimeter-wave spectroscopy laboratory data, that will aid in future studies of this molecule.

Versatile silicon-waveguide supercontinuum for coherent mid-infrared spectroscopy

Science.gov (United States)

Nader, Nima; Maser, Daniel L.; Cruz, Flavio C.; Kowligy, Abijith; Timmers, Henry; Chiles, Jeff; Fredrick, Connor; Westly, Daron A.; Nam, Sae Woo; Mirin, Richard P.; Shainline, Jeffrey M.; Diddams, Scott

2018-03-01

Laser frequency combs, with their unique combination of precisely defined spectral lines and broad bandwidth, are a powerful tool for basic and applied spectroscopy. Here, we report offset-free, mid-infrared frequency combs and dual-comb spectroscopy through supercontinuum generation in silicon-on-sapphire waveguides. We leverage robust fabrication and geometrical dispersion engineering of nanophotonic waveguides for multi-band, coherent frequency combs spanning 70 THz in the mid-infrared (2.5 μm-6.2 μm). Precise waveguide fabrication provides significant spectral broadening with engineered spectra targeted at specific mid-infrared bands. We characterize the relative-intensity-noise of different bands and show that the measured levels do not pose any limitation for spectroscopy applications. Additionally, we use the fabricated photonic devices to demonstrate dual-comb spectroscopy of a carbonyl sulfide gas sample at 5 μm. This work forms the technological basis for applications such as point sensors for fundamental spectroscopy, atmospheric chemistry, trace and hazardous gas detection, and biological microscopy.

Versatile silicon-waveguide supercontinuum for coherent mid-infrared spectroscopy

Directory of Open Access Journals (Sweden)

Nima Nader

2018-03-01

Full Text Available Laser frequency combs, with their unique combination of precisely defined spectral lines and broad bandwidth, are a powerful tool for basic and applied spectroscopy. Here, we report offset-free, mid-infrared frequency combs and dual-comb spectroscopy through supercontinuum generation in silicon-on-sapphire waveguides. We leverage robust fabrication and geometrical dispersion engineering of nanophotonic waveguides for multi-band, coherent frequency combs spanning 70 THz in the mid-infrared (2.5 μm–6.2 μm. Precise waveguide fabrication provides significant spectral broadening with engineered spectra targeted at specific mid-infrared bands. We characterize the relative-intensity-noise of different bands and show that the measured levels do not pose any limitation for spectroscopy applications. Additionally, we use the fabricated photonic devices to demonstrate dual-comb spectroscopy of a carbonyl sulfide gas sample at 5 μm. This work forms the technological basis for applications such as point sensors for fundamental spectroscopy, atmospheric chemistry, trace and hazardous gas detection, and biological microscopy.

Graphene-based mid-infrared room-temperature pyroelectric bolometers with ultrahigh temperature coefficient of resistance.

Science.gov (United States)

Sassi, U; Parret, R; Nanot, S; Bruna, M; Borini, S; De Fazio, D; Zhao, Z; Lidorikis, E; Koppens, F H L; Ferrari, A C; Colli, A

2017-01-31

There is a growing number of applications demanding highly sensitive photodetectors in the mid-infrared. Thermal photodetectors, such as bolometers, have emerged as the technology of choice, because they do not need cooling. The performance of a bolometer is linked to its temperature coefficient of resistance (TCR, ∼2-4% K -1 for state-of-the-art materials). Graphene is ideally suited for optoelectronic applications, with a variety of reported photodetectors ranging from visible to THz frequencies. For the mid-infrared, graphene-based detectors with TCRs ∼4-11% K -1 have been demonstrated. Here we present an uncooled, mid-infrared photodetector, where the pyroelectric response of a LiNbO 3 crystal is transduced with high gain (up to 200) into resistivity modulation for graphene. This is achieved by fabricating a floating metallic structure that concentrates the pyroelectric charge on the top-gate capacitor of the graphene channel, leading to TCRs up to 900% K -1 , and the ability to resolve temperature variations down to 15 μK.

High-resolution far-infrared observations of the galactic center

International Nuclear Information System (INIS)

Harvey, P.M.; Campbell, M.F.; Hoffmann, W.F.

1976-01-01

A map at 53 μ with 17'' resolution and three-color observations at 53 μ, 100 μ, and 175 μ with approx.30'' beams of Sgr A are presented. Sagittarius A is resolved into two main sources, one associated with the cluster of strong 10 μ sources and another approx.45'' to the southwest coincident with a weak 10 μ source. The dust temperature peaks near the strong 10 μ sources, but the 100 μ and 175 μ fluxes and the far-infrared optical depth are greatest near the southwest source. The amount of dust required to explain the far-infrared emission is comparable to that observed in absorption in the near-infrared

MID-INFRARED SELECTION OF ACTIVE GALACTIC NUCLEI WITH THE WIDE-FIELD INFRARED SURVEY EXPLORER. I. CHARACTERIZING WISE-SELECTED ACTIVE GALACTIC NUCLEI IN COSMOS

International Nuclear Information System (INIS)

Stern, Daniel; Assef, Roberto J.; Eisenhardt, Peter; Benford, Dominic J.; Blain, Andrew; Cutri, Roc; Griffith, Roger L.; Jarrett, T. H.; Masci, Frank; Tsai, Chao-Wei; Yan, Lin; Dey, Arjun; Lake, Sean; Petty, Sara; Wright, E. L.; Stanford, S. A.; Harrison, Fiona; Madsen, Kristin

2012-01-01

The Wide-field Infrared Survey Explorer (WISE) is an extremely capable and efficient black hole finder. We present a simple mid-infrared color criterion, W1 – W2 ≥ 0.8 (i.e., [3.4]–[4.6] ≥0.8, Vega), which identifies 61.9 ± 5.4 active galactic nucleus (AGN) candidates per deg 2 to a depth of W2 ∼ 15.0. This implies a much larger census of luminous AGNs than found by typical wide-area surveys, attributable to the fact that mid-infrared selection identifies both unobscured (type 1) and obscured (type 2) AGNs. Optical and soft X-ray surveys alone are highly biased toward only unobscured AGNs, while this simple WISE selection likely identifies even heavily obscured, Compton-thick AGNs. Using deep, public data in the COSMOS field, we explore the properties of WISE-selected AGN candidates. At the mid-infrared depth considered, 160 μJy at 4.6 μm, this simple criterion identifies 78% of Spitzer mid-infrared AGN candidates according to the criteria of Stern et al. and the reliability is 95%. We explore the demographics, multiwavelength properties and redshift distribution of WISE-selected AGN candidates in the COSMOS field.

AN ORDERED MAGNETIC FIELD IN THE PROTOPLANETARY DISK OF AB Aur REVEALED BY MID-INFRARED POLARIMETRY

Energy Technology Data Exchange (ETDEWEB)

Li, Dan; Pantin, Eric; Telesco, Charles M.; Zhang, Han; Barnes, Peter J.; Mariñas, Naibí [Department of Astronomy, University of Florida, 211 Bryant Space Science Center, FL 32611 (United States); Wright, Christopher M. [School of Physical, Environmental, and Mathematical Sciences, University of New South Wales, Canberra, ACT 2610 (Australia); Packham, Chris, E-mail: d.li@ufl.edu [Physics and Astronomy Department, University of Texas at San Antonio, 1 UTSA Circle, San Antonio, TX 78249 (United States)

2016-11-20

Magnetic fields ( B -fields) play a key role in the formation and evolution of protoplanetary disks, but their properties are poorly understood due to the lack of observational constraints. Using CanariCam at the 10.4 m Gran Telescopio Canarias, we have mapped out the mid-infrared polarization of the protoplanetary disk around the Herbig Ae star AB Aur. We detect ∼0.44% polarization at 10.3 μ m from AB Aur's inner disk ( r  < 80 au), rising to ∼1.4% at larger radii. Our simulations imply that the mid-infrared polarization of the inner disk arises from dichroic emission of elongated particles aligned in a disk B -field. The field is well ordered on a spatial scale, commensurate with our resolution (∼50 au), and we infer a poloidal shape tilted from the rotational axis of the disk. The disk of AB Aur is optically thick at 10.3 μ m, so polarimetry at this wavelength is probing the B -field near the disk surface. Our observations therefore confirm that this layer, favored by some theoretical studies for developing magneto-rotational instability and its resultant viscosity, is indeed very likely to be magnetized. At radii beyond ∼80 au, the mid-infrared polarization results primarily from scattering by dust grains with sizes up to ∼1 μ m, a size indicating both grain growth and, probably, turbulent lofting of the particles from the disk mid-plane.

Spitzer mid-infrared spectra of cool-core galaxy clusters

NARCIS (Netherlands)

de Messières, G.E.; O'Connell, R.W.; McNamara, B.R.; Donahue, M.; Nulsen, P.E.J.; Voit, G.M.; Wise, M.W.; Smith, B.; Higdon, J.; Higdon, S.; Bastian, N.

2010-01-01

We have obtained mid-infrared spectra of nine cool-core galaxy clusters with the Infrared Spectrograph aboard the Spitzer Space Telescope. X-ray, ultraviolet and optical observations have demonstrated that each of these clusters hosts a cooling flow which seems to be fueling vigorous star formation

Terahertz and Mid Infrared

CERN Document Server

Shulika, Oleksiy; Detection of Explosives and CBRN (Using Terahertz)

2014-01-01

The reader will find here a timely update on new THz sources and detection schemes as well as concrete applications to the detection of Explosives and CBRN. Included is a method to identify hidden RDX-based explosives (pure and plastic ones) in the frequency domain study by Fourier Transformation, which has been complemented by the demonstration of improvement of the quality of the images captured commercially available THz passive cameras. The presented examples show large potential for the detection of small hidden objects at long distances (6-10 m).  Complementing the results in the short-wavelength range, laser spectroscopy with a mid-infrared, room temperature, continuous wave, DFB laser diode and high performance DFB QCL have been demonstrated to offer excellent enabling sensor technologies for environmental monitoring, medical diagnostics, industrial and security applications.  From the new source point of view a number of systems have been presented - From superconductors to semiconductors, e.g. Det...

SIBI: A compact hyperspectral camera in the mid-infrared

Science.gov (United States)

Pola Fossi, Armande; Ferrec, Yann; Domel, Roland; Coudrain, Christophe; Guerineau, Nicolas; Roux, Nicolas; D'Almeida, Oscar; Bousquet, Marc; Kling, Emmanuel; Sauer, Hervé

2015-10-01

Recent developments in unmanned aerial vehicles have increased the demand for more and more compact optical systems. In order to bring solutions to this demand, several infrared systems are being developed at ONERA such as spectrometers, imaging devices, multispectral and hyperspectral imaging systems. In the field of compact infrared hyperspectral imaging devices, ONERA and Sagem Défense et Sécurité have collaborated to develop a prototype called SIBI, which stands for "Spectro-Imageur Birefringent Infrarouge". It is a static Fourier transform imaging spectrometer which operates in the mid-wavelength infrared spectral range and uses a birefringent lateral shearing interferometer. Up to now, birefringent interferometers have not been often used for hyperspectral imaging in the mid-infrared because of the lack of crystal manufacturers, contrary to the visible spectral domain where the production of uniaxial crystals like calcite are mastered for various optical applications. In the following, we will present the design and the realization of SIBI as well as the first experimental results.

Nuclear mid-infrared properties of nearby low-luminosity AGN

International Nuclear Information System (INIS)

Asmus, D; Duschl, W J; Hönig, S F; Gandhi, P; Smette, A

2012-01-01

We present ground-based high-spatial resolution mid-infrared (MIR) observations of 20 nearby low-luminosity AGN (LLAGN) with VLT/VISIR and the preliminary analysis of a new sample of 10 low-luminosity Seyferts observed with Gemini/Michelle. LLAGN are of great interest because these objects are the most common among active galaxies, especially in the nearby universe. Studying them in great detail makes it possible to investigate the AGN evolution over cosmic timescale. Indeed, many LLAGN likely represent the final stage of an AGN's lifetime. We show that even at low luminosities and accretion rates nuclear unresolved MIR emission is present in most objects. Compared to lower spatial resolution Spitzer/IRS spectra, the high-resolution MIR photometry exhibits significantly lower fluxes and different PAH emission feature properties in many cases. By using scaled Spitzer/IRS spectra of typical starburst galaxies, we show that the star formation contribution to the 12 μm emission is minor in the central parsecs of most LLAGN. Therefore, the observed MIR emission in the VISIR and Michelle data is most likely emitted by the AGN itself, which, for higher luminosity AGN, is interpreted as thermal emission from a dusty torus. Furthermore, the 12 /amemission of the LLAGN is strongly correlated with the absorption corrected 2-10 keV luminosity and the MIR- X-ray correlation found previously for AGN is extended to a range from 10 40 to 10 45 erg/s. This correlation is independent of the object type, and in particular the low-luminosity Seyferts observed with Michelle fall exactly on the power-law fit valid for brighter AGN. In addition, no dependency of the MIR-X-ray ratio on the accretion rate is found. These results are consistent with the unification model being applicable even in the probed low-luminosity regime.

Reduced graphene oxide mid-infrared photodetector at 300 K

Energy Technology Data Exchange (ETDEWEB)

Fernandes, Gustavo E.; Kim, Jin Ho; Oller, Declan; Xu, Jimmy [School of Engineering, Brown University, Box D, Providence, Rhode Island 02912 (United States)

2015-09-14

We report on uncooled mid-infrared photovoltaic responses at 300 K arising in heterojunctions of reduced graphene oxide with p-Si. Two major photoresponse spectral peaks are observed, one in the near infrared starting at 1.1 μm corresponding to electron-hole pair generation in the Si substrate, and another at wavelengths below 2.5 μm, arising from properties of the reduced graphene oxide-Si heterojunction. Our analysis of the current-voltage characteristics at various temperatures suggests that the two materials form a type-II (broken-gap) heterojunction, with a characteristic transition between direct tunneling to field emission, to over-the-barrier excitation with increasing reverse voltage. Illumination was found to affect the onset of the transition between direct tunneling and field-emission, suggesting that the mid infrared response results from the excitation of minority carriers (electrons) from the Si and their collection in the reduced graphene oxide contact. The photoresponse near 1.1 μm showed a time constant at least five times faster than the one at 2.5 μm, which points to surface defects as well as high series resistance and capacitance as potentially limiting factors in this mode of operation. With proper device engineering considerations, these devices could be promising as a graphene-based platform for infrared sensing.

Towards diode-pumped mid-infrared praseodymium-ytterbium-doped fluoride fiber lasers

Science.gov (United States)

Woodward, R. I.; Hudson, D. D.; Jackson, S. D.

2018-02-01

We explore the potential of a new mid-infrared laser transition in praseodymium-doped fluoride fiber for emission around 3.4 μm, which can be conveniently pumped by 0.975 μm diodes via ytterbium sensitizer co-doping. Optimal cavity designs are determined through spectroscopic measurements and numerical modeling, suggesting that practical diode-pumped watt-level mid-infrared fiber sources beyond 3 μm could be achieved.

Preferential flow pathways revealed by field based stable isotope analysis of CO2 by mid-infrared laser spectroscopy

Science.gov (United States)

van Geldern, Robert; Nowak, Martin; Zimmer, Martin; Szizybalski, Alexandra; Myrttinen, Anssi; Barth, Johannes A. C.; Jost, Hj

2016-04-01

A newly developed and commercially available isotope ratio laser spectrometer for CO2 analyses has been tested during a 10-day field monitoring campaign at the Ketzin pilot site for CO2 storage in northern Germany. The laser instrument is based on tunable laser direct absorption in the mid-infrared. The instrument recorded a continuous 10-day carbon stable isotope data set with 30 minutes resolution directly on-site in a field-based laboratory container during a tracer experiment. To test the instruments performance and accuracy the monitoring campaign was accompanied by daily CO2 sampling for laboratory analyses with isotope ratio mass spectrometry (IRMS). The carbon stable isotope ratios measured by conventional IRMS technique and by the new mid-infrared laser spectrometer agree remarkably well within 2σ analytical precision (<0.3 ‰). This proves the capability of the new mid-infrared direct absorption technique to measure high precision and accurate real-time table isotope data directly in the field. The injected CO2 tracer had a distinct δ13C value that was largely different from the reservoir background value. The laser spectroscopy data revealed a prior to this study unknown, intensive dynamic with fast changing δ13C values. The arrival pattern of the tracer suggest that the observed fluctuations were probably caused by migration along separate and distinct preferential flow paths between injection well and observation well. The new technique might contribute to a better tracing of the migration of the underground CO2 plume and help to ensure the long-term integrity of the reservoir.

Mid-infrared materials and devices on a Si platform for optical sensing

Science.gov (United States)

Singh, Vivek; Lin, Pao Tai; Patel, Neil; Lin, Hongtao; Li, Lan; Zou, Yi; Deng, Fei; Ni, Chaoying; Hu, Juejun; Giammarco, James; Soliani, Anna Paola; Zdyrko, Bogdan; Luzinov, Igor; Novak, Spencer; Novak, Jackie; Wachtel, Peter; Danto, Sylvain; Musgraves, J David; Richardson, Kathleen; Kimerling, Lionel C; Agarwal, Anuradha M

2014-01-01

In this article, we review our recent work on mid-infrared (mid-IR) photonic materials and devices fabricated on silicon for on-chip sensing applications. Pedestal waveguides based on silicon are demonstrated as broadband mid-IR sensors. Our low-loss mid-IR directional couplers demonstrated in SiNx waveguides are useful in differential sensing applications. Photonic crystal cavities and microdisk resonators based on chalcogenide glasses for high sensitivity are also demonstrated as effective mid-IR sensors. Polymer-based functionalization layers, to enhance the sensitivity and selectivity of our sensor devices, are also presented. We discuss the design of mid-IR chalcogenide waveguides integrated with polycrystalline PbTe detectors on a monolithic silicon platform for optical sensing, wherein the use of a low-index spacer layer enables the evanescent coupling of mid-IR light from the waveguides to the detector. Finally, we show the successful fabrication processing of our first prototype mid-IR waveguide-integrated detectors. PMID:27877641

Mid-infrared beam splitter for ultrashort pulses.

Science.gov (United States)

Somma, Carmine; Reimann, Klaus; Woerner, Michael; Kiel, Thomas; Busch, Kurt; Braun, Andreas; Matalla, Mathias; Ickert, Karina; Krüger, Olaf

2017-08-01

A design is presented for a beam splitter suitable for ultrashort pulses in the mid-infrared and terahertz spectral range consisting of a structured metal layer on a diamond substrate. Both the theory and experiment show that this beam splitter does not distort the temporal pulse shape.

Mid-Infrared Tunable Resonant Cavity Enhanced Detectors

Directory of Open Access Journals (Sweden)

Hans Zogg

2008-09-01

Full Text Available Mid-infrared detectors that are sensitive only in a tunable narrow spectral band are presented. They are based on the Resonant Cavity Enhanced Detector (RCED principle and employing a thin active region using IV-VI narrow gap semiconductor layers. A Fabry-Pérot cavity is formed by two mirrors. The active layer is grown onto one mirror, while the second mirror can be displaced. This changes the cavity length thus shifting the resonances where the detector is sensitive. Using electrostatically actuated MEMS micromirrors, a very compact tunable detector system has been fabricated. Mirror movements of more than 3 μm at 30V are obtained. With these mirrors, detectors with a wavelength tuning range of about 0.7 μm have been realized. Single detectors can be used in mid-infrared micro spectrometers, while a detector arrangement in an array makes it possible to realize Adaptive Focal Plane Arrays (AFPA.

Novel mid-infrared imaging system based on single-mode quantum cascade laser illumination and upconversion

DEFF Research Database (Denmark)

Tomko, Jan; Junaid, Saher; Tidemand-Lichtenberg, Peter

2017-01-01

Compared to the visible or near-infrared (NIR) spectral regions, there is a lack of very high sensitivity detectors in the mid-infrared (MIR) that operate near room temperature. Upconversion of the MIR light to NIR light that is imaged using affordable, fast, and sensitive NIR detectors or camera...

Diagnostic studies of molecular plasmas using mid-infrared semiconductor lasers

NARCIS (Netherlands)

Röpcke, J.; Welzel, S.; Lang, N.; Hempel, F.; Gatilova, L.; Guaitella, O.; Rousseau, A.; Davies, P.B.

2008-01-01

Within the last decade mid-infrared absorption spectroscopy between 3 and 20 µm, known as infrared laser absorption spectroscopy (IRLAS) and based on tuneable semiconductor lasers, namely lead salt diode lasers, often called tuneable diode lasers (TDL), and quantum cascade lasers (QCL) has

Monsoonal response to mid-holocene orbital forcing in a high resolution GCM

Directory of Open Access Journals (Sweden)

J. H. C. Bosmans

2012-04-01

Full Text Available In this study, we use a sophisticated high-resolution atmosphere-ocean coupled climate model, EC-Earth, to investigate the effect of Mid-Holocene orbital forcing on summer monsoons on both hemispheres. During the Mid-Holocene (6 ka, there was more summer insolation on the Northern Hemisphere than today, which intensified the meridional temperature and pressure gradients. Over North Africa, monsoonal precipitation is intensified through increased landward monsoon winds and moisture advection as well as decreased moisture convergence over the oceans and more convergence over land compared to the pre-industrial simulation. Precipitation also extends further north as the ITCZ shifts northward in response to the stronger poleward gradient of insolation. This increase and poleward extent is stronger than in most previous ocean-atmosphere GCM simulations. In north-westernmost Africa, precipitation extends up to 35° N. Over tropical Africa, internal feedbacks completely overcome the direct warming effect of increased insolation. We also find a weakened African Easterly Jet. Over Asia, monsoonal precipitation during the Mid-Holocene is increased as well, but the response is different than over North-Africa. There is more convection over land at the expense of convection over the ocean, but precipitation does not extend further northward, monsoon winds over the ocean are weaker and the surrounding ocean does not provide more moisture. On the Southern Hemisphere, summer insolation and the poleward insolation gradient were weaker during the Mid-Holocene, resulting in a reduced South American monsoon through decreased monsoon winds and less convection, as well as an equatorward shift in the ITCZ. This study corroborates the findings of paleodata research as well as previous model studies, while giving a more detailed account of Mid-Holocene monsoons.

Super resolution reconstruction of infrared images based on classified dictionary learning

Science.gov (United States)

Liu, Fei; Han, Pingli; Wang, Yi; Li, Xuan; Bai, Lu; Shao, Xiaopeng

2018-05-01

Infrared images always suffer from low-resolution problems resulting from limitations of imaging devices. An economical approach to combat this problem involves reconstructing high-resolution images by reasonable methods without updating devices. Inspired by compressed sensing theory, this study presents and demonstrates a Classified Dictionary Learning method to reconstruct high-resolution infrared images. It classifies features of the samples into several reasonable clusters and trained a dictionary pair for each cluster. The optimal pair of dictionaries is chosen for each image reconstruction and therefore, more satisfactory results is achieved without the increase in computational complexity and time cost. Experiments and results demonstrated that it is a viable method for infrared images reconstruction since it improves image resolution and recovers detailed information of targets.

Mid-infrared supercontinuum generation in a suspended core chalcogenide fiber

DEFF Research Database (Denmark)

Møller, Uffe Visbech; Yu, Yi; Gai, Xin

The mid-infrared spectral region is of great interest because virtually all organic compounds display distinctive spectral fingerprints herein that reveal chemical information about them [1], and the mid-infrared region is therefore of key importance to many applications, including food quality...... control [2], gas sensing [3] and medical diagnostics [4] . We have used a low-loss suspended core As 38 Se 62 fiber with core diameter of 4.5 μ m and a zero - dispersion wavelength of 3.5 μ m to generate mid-infrared supercontinuum by pumping with an optical parametric amplifier delivering 320 fs pulses...... with a peak power of ~5.5 kW at a repetition rate of 21 MHz at different wavelengths from 3.3 to 4.7 μ m . By pumping at 4.4 μ m with a peak power of 5.2 kW coupled to the fiber a supercontinuum spanning from 1.7 to 7.5 μ m with an average output power of 15.6 mW was obtained. Figure 1 shows the results...

Star-forming Galaxies as AGN Imposters? A Theoretical Investigation of the Mid-infrared Colors of AGNs and Extreme Starbursts

Science.gov (United States)

Satyapal, Shobita; Abel, Nicholas P.; Secrest, Nathan J.

2018-05-01

We conduct for the first time a theoretical investigation of the mid-infrared spectral energy distribution (SED) produced by dust heated by an active galactic nucleus (AGN) and an extreme starburst. These models employ an integrated modeling approach using photoionization and stellar population synthesis models in which both the line and emergent continuum is predicted from gas exposed to the ionizing radiation from a young starburst and an AGN. In this work, we focus on the infrared colors from the Wide-field Infrared Survey Explorer, predicting the dependence of the colors on the input radiation field, the interstellar medium conditions, the obscuring column, and the metallicity. We find that an extreme starburst can mimic an AGN in two band mid-infrared color cuts employed in the literature. However, the three-band color cuts employed in the literature require starbursts with extremely high ionization parameters or gas densities. We show that the extreme mid-infrared colors seen in some blue compact dwarf galaxies are not due to metallicity but rather a combination of high ionization parameters and high column densities. Based on our theoretical calculations, we present a theoretical mid-infrared color cut that will exclude even the most extreme starburst that we have modeled in this work. The theoretical AGN demarcation region presented here can be used to identify elusive AGN candidates for future follow-up studies with the James Webb Space Telescope. The full suite of simulated SEDs are available online.

Mid-infrared mapping of Jupiter's temperatures, aerosol opacity and chemical distributions with IRTF/TEXES

Science.gov (United States)

Fletcher, Leigh N.; Greathouse, T. K.; Orton, G. S.; Sinclair, J. A.; Giles, R. S.; Irwin, P. G. J.; Encrenaz, T.

2016-11-01

Global maps of Jupiter's atmospheric temperatures, gaseous composition and aerosol opacity are derived from a programme of 5-20 μm mid-infrared spectroscopic observations using the Texas Echelon Cross Echelle Spectrograph (TEXES) on NASA's Infrared Telescope Facility (IRTF). Image cubes from December 2014 in eight spectral channels, with spectral resolutions of R ∼2000 - 12 , 000 and spatial resolutions of 2-4° latitude, are inverted to generate 3D maps of tropospheric and stratospheric temperatures, 2D maps of upper tropospheric aerosols, phosphine and ammonia, and 2D maps of stratospheric ethane and acetylene. The results are compared to a re-analysis of Cassini Composite Infrared Spectrometer (CIRS) observations acquired during Cassini's closest approach to Jupiter in December 2000, demonstrating that this new archive of ground-based mapping spectroscopy can match and surpass the quality of previous investigations, and will permit future studies of Jupiter's evolving atmosphere. The visibility of cool zones and warm belts varies from channel to channel, suggesting complex vertical variations from the radiatively-controlled upper troposphere to the convective mid-troposphere. We identify mid-infrared signatures of Jupiter's 5-μm hotspots via simultaneous M, N and Q-band observations, which are interpreted as temperature and ammonia variations in the northern Equatorial Zone and on the edge of the North Equatorial Belt (NEB). Equatorial plumes enriched in NH3 gas are located south-east of NH3-desiccated 'hotspots' on the edge of the NEB. Comparison of the hotspot locations in several channels across the 5-20 μm range indicate that these anomalous regions tilt westward with altitude. Aerosols and PH3 are both enriched at the equator but are not co-located with the NH3 plumes. The equatorial temperature minimum and PH3/aerosol maxima have varied in amplitude over time, possibly as a result of periodic equatorial brightenings and the fresh updrafts of

Confronting Standard Models of Proto-planetary Disks with New Mid-infrared Sizes from the Keck Interferometer

Science.gov (United States)

Millan-Gabet, Rafael; Che, Xiao; Monnier, John D.; Sitko, Michael L.; Russell, Ray W.; Grady, Carol A.; Day, Amanda N.; Perry, R. B.; Harries, Tim J.; Aarnio, Alicia N.; Colavita, Mark M.; Wizinowich, Peter L.; Ragland, Sam; Woillez, Julien

2016-08-01

We present near- and mid-infrared (MIR) interferometric observations made with the Keck Interferometer Nuller and near-contemporaneous spectro-photometry from the infrared telescope facilities (IRTFs) of 11 well-known young stellar objects, several of which were observed for the first time in these spectral and spatial resolution regimes. With au-level spatial resolution, we first establish characteristic sizes of the infrared emission using a simple geometrical model consisting of a hot inner rim and MIR disk emission. We find a high degree of correlation between the stellar luminosity and the MIR disk sizes after using near-infrared data to remove the contribution from the inner rim. We then use a semi-analytical physical model to also find that the very widely used “star + inner dust rim + flared disk” class of models strongly fails to reproduce the spectral energy distribution (SED) and spatially resolved MIR data simultaneously; specifically a more compact source of MIR emission is required than results from the standard flared disk model. We explore the viability of a modification to the model whereby a second dust rim containing smaller dust grains is added, and find that the 2-rim model leads to significantly improved fits in most cases. This complexity is largely missed when carrying out SED modeling alone, although detailed silicate feature fitting by McClure et al. recently came to a similar conclusion. As has been suggested recently by Menu et al., the difficulty in predicting MIR sizes from the SED alone might hint at “transition disk”-like gaps in the inner au; however, the relatively high correlation found in our MIR disk size versus stellar luminosity relation favors layered disk morphologies and points to missing disk model ingredients instead.

CONFRONTING STANDARD MODELS OF PROTO-PLANETARY DISKS WITH NEW MID-INFRARED SIZES FROM THE KECK INTERFEROMETER

Energy Technology Data Exchange (ETDEWEB)

Millan-Gabet, Rafael [California Institute of Technology, NASA Exoplanet Science Institute, Pasadena, CA 91125 (United States); Che, Xiao; Monnier, John D.; Aarnio, Alicia N. [University of Michigan Astronomy Department, 1085 S. University Avenue 303B West Hall University of Michigan, Ann Arbor, MI 48109-1107 (United States); Sitko, Michael L.; Day, Amanda N. [Department of Physics, University of Cincinnati, Cincinnati OH 45221 (United States); Russell, Ray W. [The Aerospace Corporation, Los Angeles, CA 90009 (United States); Grady, Carol A. [Eureka Scientific, 2452 Delmer, Suite 100, Oakland, CA 96002 (United States); Perry, R. B. [NASA Langley Research Center, MS 160, Hampton, VA 23681 (United States); Harries, Tim J. [Department of Physics and Astronomy, University of Exeter, Stocker Road, Exeter EX4 4QL (United Kingdom); Colavita, Mark M. [Jet Propulsion Laboratory, California Institute of Technology, 4800 Oak Grove Drive, Pasadena, CA 91109 (United States); Wizinowich, Peter L.; Ragland, Sam; Woillez, Julien, E-mail: R.Millan-Gabet@caltech.edu [Keck Observatory, 65-1120 Mamalahoa Hwy, Kamuela, HI 96743 (United States)

2016-08-01

We present near- and mid-infrared (MIR) interferometric observations made with the Keck Interferometer Nuller and near-contemporaneous spectro-photometry from the infrared telescope facilities (IRTFs) of 11 well-known young stellar objects, several of which were observed for the first time in these spectral and spatial resolution regimes. With au-level spatial resolution, we first establish characteristic sizes of the infrared emission using a simple geometrical model consisting of a hot inner rim and MIR disk emission. We find a high degree of correlation between the stellar luminosity and the MIR disk sizes after using near-infrared data to remove the contribution from the inner rim. We then use a semi-analytical physical model to also find that the very widely used “star + inner dust rim + flared disk” class of models strongly fails to reproduce the spectral energy distribution (SED) and spatially resolved MIR data simultaneously; specifically a more compact source of MIR emission is required than results from the standard flared disk model. We explore the viability of a modification to the model whereby a second dust rim containing smaller dust grains is added, and find that the 2-rim model leads to significantly improved fits in most cases. This complexity is largely missed when carrying out SED modeling alone, although detailed silicate feature fitting by McClure et al. recently came to a similar conclusion. As has been suggested recently by Menu et al., the difficulty in predicting MIR sizes from the SED alone might hint at “transition disk”-like gaps in the inner au; however, the relatively high correlation found in our MIR disk size versus stellar luminosity relation favors layered disk morphologies and points to missing disk model ingredients instead.

CONFRONTING STANDARD MODELS OF PROTO-PLANETARY DISKS WITH NEW MID-INFRARED SIZES FROM THE KECK INTERFEROMETER

International Nuclear Information System (INIS)

Millan-Gabet, Rafael; Che, Xiao; Monnier, John D.; Aarnio, Alicia N.; Sitko, Michael L.; Day, Amanda N.; Russell, Ray W.; Grady, Carol A.; Perry, R. B.; Harries, Tim J.; Colavita, Mark M.; Wizinowich, Peter L.; Ragland, Sam; Woillez, Julien

2016-01-01

We present near- and mid-infrared (MIR) interferometric observations made with the Keck Interferometer Nuller and near-contemporaneous spectro-photometry from the infrared telescope facilities (IRTFs) of 11 well-known young stellar objects, several of which were observed for the first time in these spectral and spatial resolution regimes. With au-level spatial resolution, we first establish characteristic sizes of the infrared emission using a simple geometrical model consisting of a hot inner rim and MIR disk emission. We find a high degree of correlation between the stellar luminosity and the MIR disk sizes after using near-infrared data to remove the contribution from the inner rim. We then use a semi-analytical physical model to also find that the very widely used “star + inner dust rim + flared disk” class of models strongly fails to reproduce the spectral energy distribution (SED) and spatially resolved MIR data simultaneously; specifically a more compact source of MIR emission is required than results from the standard flared disk model. We explore the viability of a modification to the model whereby a second dust rim containing smaller dust grains is added, and find that the 2-rim model leads to significantly improved fits in most cases. This complexity is largely missed when carrying out SED modeling alone, although detailed silicate feature fitting by McClure et al. recently came to a similar conclusion. As has been suggested recently by Menu et al., the difficulty in predicting MIR sizes from the SED alone might hint at “transition disk”-like gaps in the inner au; however, the relatively high correlation found in our MIR disk size versus stellar luminosity relation favors layered disk morphologies and points to missing disk model ingredients instead.

Room temperature high-detectivity mid-infrared photodetectors based on black arsenic phosphorus.

Science.gov (United States)

Long, Mingsheng; Gao, Anyuan; Wang, Peng; Xia, Hui; Ott, Claudia; Pan, Chen; Fu, Yajun; Liu, Erfu; Chen, Xiaoshuang; Lu, Wei; Nilges, Tom; Xu, Jianbin; Wang, Xiaomu; Hu, Weida; Miao, Feng

2017-06-01

The mid-infrared (MIR) spectral range, pertaining to important applications, such as molecular "fingerprint" imaging, remote sensing, free space telecommunication, and optical radar, is of particular scientific interest and technological importance. However, state-of-the-art materials for MIR detection are limited by intrinsic noise and inconvenient fabrication processes, resulting in high-cost photodetectors requiring cryogenic operation. We report black arsenic phosphorus-based long-wavelength IR photodetectors, with room temperature operation up to 8.2 μm, entering the second MIR atmospheric transmission window. Combined with a van der Waals heterojunction, room temperature-specific detectivity higher than 4.9 × 10 9 Jones was obtained in the 3- to 5-μm range. The photodetector works in a zero-bias photovoltaic mode, enabling fast photoresponse and low dark noise. Our van der Waals heterojunction photodetectors not only exemplify black arsenic phosphorus as a promising candidate for MIR optoelectronic applications but also pave the way for a general strategy to suppress 1/ f noise in photonic devices.

High Resolution Infrared Spectroscopy in Astronomy Proceedings of an ESO Workshop Held at Garching, Germany, 18-21 November 2003

CERN Document Server

Käufl, Hans Ulrich; Moorwood, Alan F. M

2005-01-01

Two specialized new instruments for ESO's VLT, VISIR and CRIRES, spawned the idea for this workshop. CRIRES is a dedicated very high resolution infrared spectrograph; VISIR features a high resolution spectroscopic mode. Together, the instruments combine the sensitivity of an 8m-telescope with the now well-established reliability of VLT-facility instruments. High resolution here means that lines in cool stellar atmospheres and HII-regions can be resolved. The astrophysical topics discussed in this rather specialized workshop range from the inner solar system to active galactic nuclei. There are many possibilities for new discoveries with these instruments, but the unique capability, which becomes available through high-resolution infrared spectroscopy, is the observation of molecular rotational-vibrational transitions in many astrophysical environments. Particularly interesting and surprising in this context, many papers on modeling and laboratory spectroscopy at the workshop appear to indicate that astronomic...

Heuristic modelling of laser written mid-infrared LiNbO3 stressed-cladding waveguides.

Science.gov (United States)

Nguyen, Huu-Dat; Ródenas, Airán; Vázquez de Aldana, Javier R; Martínez, Javier; Chen, Feng; Aguiló, Magdalena; Pujol, Maria Cinta; Díaz, Francesc

2016-04-04

Mid-infrared lithium niobate cladding waveguides have great potential in low-loss on-chip non-linear optical instruments such as mid-infrared spectrometers and frequency converters, but their three-dimensional femtosecond-laser fabrication is currently not well understood due to the complex interplay between achievable depressed index values and the stress-optic refractive index changes arising as a function of both laser fabrication parameters, and cladding arrangement. Moreover, both the stress-field anisotropy and the asymmetric shape of low-index tracks yield highly birefringent waveguides not useful for most applications where controlling and manipulating the polarization state of a light beam is crucial. To achieve true high performance devices a fundamental understanding on how these waveguides behave and how they can be ultimately optimized is required. In this work we employ a heuristic modelling approach based on the use of standard optical characterization data along with standard computational numerical methods to obtain a satisfactory approximate solution to the problem of designing realistic laser-written circuit building-blocks, such as straight waveguides, bends and evanescent splitters. We infer basic waveguide design parameters such as the complex index of refraction of laser-written tracks at 3.68 µm mid-infrared wavelengths, as well as the cross-sectional stress-optic index maps, obtaining an overall waveguide simulation that closely matches the measured mid-infrared waveguide properties in terms of anisotropy, mode field distributions and propagation losses. We then explore experimentally feasible waveguide designs in the search of a single-mode low-loss behaviour for both ordinary and extraordinary polarizations. We evaluate the overall losses of s-bend components unveiling the expected radiation bend losses of this type of waveguides, and finally showcase a prototype design of a low-loss evanescent splitter. Developing a realistic waveguide

Probing Conditions at Ionized/Molecular Gas Interfaces With High Resolution Near-Infrared Spectroscopy

Science.gov (United States)

Kaplan, Kyle Franklin

2017-08-01

Regions of star formation and star death in our Galaxy trace the cycle of gas and dust in the interstellar medium (ISM). Gas in dense molecular clouds collapses to form stars, and stars at the end of their lives return the gas that made up their outer layers back out into the Galaxy. Hot stars generate copious amounts of ultraviolet photons which interact with the surrounding medium and dominate the energetics, ionization state, and chemistry of the gas. The interface where molecular gas is being dissociated into neutral atomic gas by far-UV photons from a nearby hot source is called a photodissociation or photon-dominated region (PDR). PDRs are found primarily in star forming regions where O and B stars serve as the source of UV photons, and in planetary nebulae where the hot core of the dying star acts as the UV source. The main target of this dissertation is molecular hydrogen (H2), the most abundant molecule in the Universe, made from hydrogen formed during the Big Bang. H2 makes up the overwhelming majority of molecules found in the ISM and in PDRs. Far-UV radiation absorbed by H2 will excite an electron in the molecule. The molecule then either dissociates ( 10% of the time; Field et al. 1966) or decays into excited rotational and vibrational ("rovibrational") levels of the electronic ground state. These excited rovibrational levels then decay via a radiative cascade to the ground rovibrational state (v = 0, J = 0), giving rise to a large number of transitions observable in emission from the mid-IR to the optical (Black & van Dishoeck, 1987). These transitions provide an excellent probe of the excitation and conditions within the gas. These transitions are also observed in warm H2, such as in shocks, where collisions excite H2 to higher rovibrational levels. High resolution near-infrared spectroscopy, with its ability to see through dust, and avoid telluric absorption and emission, serves as an effective tool to detect emission from ions, atoms, and molecules

High-Resolution Infrared and Raman Spectra of the Polycrystalline Sinomenine Hydrochloride

Directory of Open Access Journals (Sweden)

Liu Xiao-Dong

2016-01-01

Full Text Available High-resolution infrared and Raman spectra of the polycrystalline sinomenine (SM hydrochloride have been measured to work out its whole really existing vibrational spectral bands. Except for the hydroxyl stretching modes and IR active bands less than 400 cm−1, most normal modes (about 34 are both IR and Raman active. In addition, 8 Raman bands less than 400 cm−1 are tentatively assigned, for the first time to our knowledge, to stretching/bending modes of the aromatic-ring−methoxyls and (SMH+–Cl− ions, respectively.

Efficient femtosecond mid-infrared pulse generation by dispersivewave radiation in bulk lithium niobate crystal

DEFF Research Database (Denmark)

Zhou, Binbin; Guo, Hairun; Bache, Morten

2014-01-01

We experimentally demonstrate efficient mid-infrared pulse generation by dispersive wave radiation in bulk lithium niobate crystal. Femtosecond mid-IR pulses centering from 2.8–2.92 µm are generated using the single pump wavelengths from 1.25–1.45 µm.......We experimentally demonstrate efficient mid-infrared pulse generation by dispersive wave radiation in bulk lithium niobate crystal. Femtosecond mid-IR pulses centering from 2.8–2.92 µm are generated using the single pump wavelengths from 1.25–1.45 µm....

New Opportunities in Mid-Infrared Emission Control

Directory of Open Access Journals (Sweden)

Peter Geiser

2015-09-01

Full Text Available Tunable laser absorption spectroscopy (TLAS has been well accepted as a preferred measurement technique for many industrial applications in recent years, especially for in situ applications. Previously, mainly near-infrared lasers have been used in TLAS sensors. The advent of compact mid-infrared light sources, like quantum cascade lasers and interband cascade lasers, has made it possible to detect gases with better sensitivity by utilizing fundamental absorption bands and to measure species that do not have any absorption lines in the near-infrared spectral region. This technological advancement has allowed developing new sensors for gases, such as nitric oxide and sulfur dioxide, for industrial applications. Detection limits of better than 1 ppm·m for nitric oxide and better than 10 ppm·m for sulfur dioxide are demonstrated in field experiments.

Mid-Infrared Spectral Properties of IR QSOs

International Nuclear Information System (INIS)

Xia, X. Y.; Cao, C.; Mao, S.; Deng, Z. G.

2008-01-01

We analyse mid-infrared (MIR) spectroscopic properties for 19 ultra-luminous infrared quasars (IR QSOs) in the local universe based on the spectra from the Infrared Spectrograph on board the Spitzer Space Telescope. The MIR properties of IR QSOs are compared with those of optically-selected Palomar-Green QSOs (PG QSOs) and ultra-luminous infrared galaxies (ULIRGs). The average MIR spectral features from ∼5 to 30 μm, including the spectral slopes, 6.2 μm PAH emission strengths and [NeII] 12.81 μm luminosities of IR QSOs, differ from those of PG QSOs. In contrast, IR QSOs and ULIRGs have comparable PAH and [NeII] luminosities. These results are consistent with IR QSOs being at a transitional stage from ULIRGs to classical QSOs. We also find the correlation between the EW (PAH 6.2 μm) and outflow velocities suggests that star formation activities are suppressed by feedback from AGNs and/or supernovae.

Adding a dimension to the infrared spectra of interfaces: 2D SFG spectroscopy via mid-IR pulse shaping

Science.gov (United States)

Zanni, Martin

2012-02-01

Sum-frequency generation spectroscopy provides an infrared spectrum of interfaces and thus has widespread use in the materials and chemical sciences. In this presentation, I will present our recent work in developing a 2D pulse sequence to generate 2D SFG spectra of interfaces, in analogy to 2D infrared spectra used to measure bulk species. To develop this spectroscopy, we have utilized many of the tricks-of-the-trade developed in the 2D IR and 2D Vis communities in the last decade, including mid-IR pulse shaping. With mid-IR pulse shaping, the 2D pulse sequence is manipulated by computer programming in the desired frequency resolution, rotating frame, and signal pathway. We believe that 2D SFG will become an important tool in the interfacial sciences in an analogous way that 2D IR is now being used in many disciplines.

Surface Temperature Mapping of the University of Northern Iowa Campus Using High Resolution Thermal Infrared Aerial Imageries

Directory of Open Access Journals (Sweden)

Ramanathan Sugumaran

2008-08-01

Full Text Available The goal of this project was to map the surface temperature of the University of Northern Iowa campus using high-resolution thermal infrared aerial imageries. A thermal camera with a spectral bandwidth of 3.0-5.0 μm was flown at the average altitude of 600 m, achieving ground resolution of 29 cm. Ground control data was used to construct the pixelto-temperature conversion model, which was later used to produce temperature maps of the entire campus and also for validation of the model. The temperature map then was used to assess the building rooftop conditions and steam line faults in the study area. Assessment of the temperature map revealed a number of building structures that may be subject to insulation improvement due to their high surface temperatures leaks. Several hot spots were also identified on the campus for steam pipelines faults. High-resolution thermal infrared imagery proved highly effective tool for precise heat anomaly detection on the campus, and it can be used by university facility services for effective future maintenance of buildings and grounds.

Surface Temperature Mapping of the University of Northern Iowa Campus Using High Resolution Thermal Infrared Aerial Imageries

Science.gov (United States)

Savelyev, Alexander; Sugumaran, Ramanathan

2008-01-01

The goal of this project was to map the surface temperature of the University of Northern Iowa campus using high-resolution thermal infrared aerial imageries. A thermal camera with a spectral bandwidth of 3.0-5.0 μm was flown at the average altitude of 600 m, achieving ground resolution of 29 cm. Ground control data was used to construct the pixel- to-temperature conversion model, which was later used to produce temperature maps of the entire campus and also for validation of the model. The temperature map then was used to assess the building rooftop conditions and steam line faults in the study area. Assessment of the temperature map revealed a number of building structures that may be subject to insulation improvement due to their high surface temperatures leaks. Several hot spots were also identified on the campus for steam pipelines faults. High-resolution thermal infrared imagery proved highly effective tool for precise heat anomaly detection on the campus, and it can be used by university facility services for effective future maintenance of buildings and grounds. PMID:27873800

Modeling of dispersion engineered chalcogenide rib waveguide for ultraflat mid-infrared supercontinuum generation in all-normal dispersion regime

Science.gov (United States)

Ahmad, H.; Karim, M. R.; Rahman, B. M. A.

2018-03-01

A rigorous numerical investigation has been carried out through dispersion engineering of chalcogenide rib waveguide for near-infrared to mid-infrared ultraflat broadband supercontinuum generation in all-normal group-velocity dispersion regime. We propose a novel design of a 1-cm-long air-clad rib waveguide which is made from {Ge}_{11.5} {As}_{24} {Se}_{64.5} chalcogenide glass as the core with either silica or {Ge}_{11.5} {As}_{24} {S}_{64.5} chalcogenide glass as a lower cladding separately. A broadband ultraflat supercontinuum spanning from 1300 to 1900 nm could be generated when pumped at 1.55 μ {m} with a low input peak power of 100 W. Shifting the pump to 2 μ {m}, the supercontinuum spectra extended in the mid-infrared region up to 3400 nm with a moderate-input peak power of 500 W. To achieve further extension in mid-infrared, we excite our optimized rib waveguide in both the anomalous and all-normal dispersion pumping regions at 3.1 μ {m} with a largest input peak power of 3 kW. In the case of anomalous dispersion region pumping, numerical analysis shows that supercontinuum spectrum can be extended in the mid-infrared up to 10 μ {m}, although this contains high spectral amplitude fluctuations over the entire bandwidth which limits the supercontinuum sources in the field of high precision measurement applications. On the other hand, by optimizing a rib waveguide geometry for pumping in all-normal dispersion region, we are able to generate a smooth and flat-top coherent supercontinuum spectrum with a moderate bandwidth spanning the wavelength range 2-5.5 μ {m} with less than 5 dB spectral fluctuation over the entire output bandwidth. Our proposed design is highly suitable for making on-chip SC light sources for a variety of applications such as biomedical imaging, and environmental and industrial sensing in the mid-infrared region.

The origin of the mid-infrared nuclear polarization of active galactic nuclei

Science.gov (United States)

Lopez-Rodriguez, E.; Alonso-Herrero, A.; Diaz-Santos, T.; Gonzalez-Martin, O.; Ichikawa, K.; Levenson, N. A.; Martinez-Paredes, M.; Nikutta, R.; Packham, C.; Perlman, E.; Almeida, C. Ramos; Rodriguez-Espinosa, J. M.; Telesco, C. M.

2018-05-01

We combine new (NGC 1275, NGC 4151, and NGC 5506) and previously published (Cygnus A, Mrk 231, and NGC 1068) sub-arcsecond resolution mid-infrared (MIR; 8-13 μm) imaging- and spectro-polarimetric observations of six Seyfert galaxies using CanariCam on the 10.4-m Gran Telescopio CANARIAS. These observations reveal a diverse set of physical processes responsible for the nuclear polarization, and permit characterization of the origin of the MIR nuclear polarimetric signature of active galactic nuclei (AGN). For all radio quiet objects, we found that the nuclear polarization is low (sensitivity to detect such extended emission (i.e., NGC 1068 and NGC 4151). We suggest that the higher degree of polarization previously found in lower resolution data arises only on the larger-than-nuclear scales. Only the radio-loud Cygnus A exhibits significant nuclear polarization (˜11 per cent), attributable to synchrotron emission from the pc-scale jet close to the core. We present polarization models that suggest that the MIR nuclear polarization for highly obscured objects arises from a self-absorbed MIR polarized clumpy torus and/or dichroism from the host galaxy, while for unabsorbed cores, MIR polarization arises from dust scattering in the torus and/or surrounding nuclear dust.

Supercontinuum: broad as a lamp, bright as a laser, now in the mid-infrared

Science.gov (United States)

Moselund, Peter M.; Petersen, Christian; Dupont, Sune; Agger, Christian; Bang, Ole; Keiding, Søren R.

2012-06-01

Based on the experience gained developing our market leading visible spectrum supercontinuum sources NKT Photonics has built the first mid-infrared supercontinuum source based on modelocked picosecond fiber lasers. The source is pumped by a ~ 2 um laser based on a combination of erbium and thulium and use ZBLAN fibers to generate a 1.75-4.4 μm spectrum. We will present results obtained by applying the source for mid-infrared microscopy where absorption spectra can be used to identify the chemical nature of different parts of a sample. Subsequently, we discuss the possible application of a mid-IR supercontinuum source in other areas including infrared countermeasures.

Dispersion compensated mid-infrared quantum cascade laser frequency comb with high power output

Directory of Open Access Journals (Sweden)

Q. Y. Lu

2017-04-01

Full Text Available Chromatic dispersion control plays an underlying role in optoelectronics and spectroscopy owing to its enhancement to nonlinear interactions by reducing the phase mismatching. This is particularly important to optical frequency combs based on quantum cascade lasers which require negligible dispersions for efficient mode locking of the dispersed modes into equally spaced comb modes. Here, we demonstrated a dispersion compensated mid-IR quantum cascade laser frequency comb with high power output at room temperature. A low-loss dispersive mirror has been engineered to compensate the device’s dispersion residue for frequency comb generation. Narrow intermode beating linewidths of 40 Hz in the comb-working currents were identified with a high power output of 460 mW and a broad spectral coverage of 80 cm-1. This dispersion compensation technique will enable fast spectroscopy and high-resolution metrology based on QCL combs with controlled dispersion and suppressed noise.

Visible and Mid-Infrared Gypsum Optical Constants for Modeling of Martian Deposits

Science.gov (United States)

Roush, Ted L.; Esposito, Francesca; Rossmann, George R.; Colangeli, Luigi

2007-08-01

Introduction: Recent and on-going remote and in situ observations indicate that sulfates are present in significant abundances at various locations on Mars [1-7]. The Mars Reconnaissance Orbiter (MRO) imaging spectrometer (CRISM) is returning hyperspectral data at higher spatial resolution [8] than the OMEGA instrument on the Mars Express Mission [3]. Data from both OMEGA and CRISM have provided spectral evidence for the presence of gypsum and various hydrated sulfates on the Martian surface [e.g. 3-7] Thus, the optical properties of sulfates, in general, are of interest to quantitative interpretation of this increasing volume of remotely sensed data. This is because optical constants describe how a material interacts with electromagnetic radiation and represent the fundamental values used in radiative transfer calculations describing a variety of physical environments. Such environments include atmospheres where aerosols are present, planetary and satellite regoliths, and circumstellar dust clouds. Here we focus upon gypsum because of its applicability due to its identification on Mars. Also, gypsum is a mineral that is readily available in samples sizes that are suitable for study using a variety of spectral measurements. In the infrared (>5 μm) several studies reporting the optical constants of gypsum can be used in evaluating the approach used here. Most importantly, there is a general lack of data regarding the optical constants for gypsum at visible and mid-infrared wavelengths (0.4-5 μm) that are being observed by OMEGA and CRISM. Background: In the infrared, there have been several studies focused at determining the optical constants of gypsum using classical dispersion models [9-11]. These have used a variety of samples including; crystals, compressed pellets of pure materials, and grains suspended in a KBr matrix. Spectral measurements of gypsum, and other sulfates, have existed for about 100 years at visible and mid-infrared wavelengths (0.4-5 μm) [e

The next-generation infrared astronomy mission SPICA under the new framework

NARCIS (Netherlands)

Nakagawa, Takao; Shibai, Hiroshi; Onaka, Takashi; Matsuhara, Hideo; Kaneda, Hidehiro; Kawakatsu, Yasuhiro; Roelfsema, Peter

We present the current status of SPICA (Space Infrared Telescope for Cosmology and Astrophysics), which is a mission optimized for mid- and far-infrared astronomy with a cryogenically cooled 3.2 m telescope. SPICA is expected to achieve high spatial resolution and unprecedented sensitivity in the

Mid-Infrared Spectrum of the Zodiacal Emission: Detection of Crystalline Silicates in Interplanetary Dust

Science.gov (United States)

Ootsubo, T.; Onaka, T.; Yamamura, I.; Ishihara, D.; Tanabe, T.; Roellig, T. L.

2003-01-01

Within a few astronomical units of the Sun the solar system is filled with interplanetary dust, which is believed to be dust of cometary and asteroidal origin. Spectroscopic observations of the zodiacal emission with moderate resolution provide key information on the composition and size distribution of the dust in the interplanetary space. They can be compared directly to laboratory measurements of candidate materials, meteorites, and dust particles collected in the stratosphere. Recently mid-infrared spectroscopic observations of the zodiacal emission have been made by two instruments on board the Infrared Space Observatory; the camera (ISOCAM) and the spectrophotometer (ISOPHOT-S). A broad excess emission feature in the 9-11 micron range is reported in the ISOCAM spectrum, whereas the ISOPHOT-S spectra in 6-12 microns can be well fitted by a blackbody radiation without spectral features.

a Study of Vibrational Mode Coupling in 2-FLUOROETHANOL and 1,2-DIFLUOROETHANE Using High-Resolution Infrared Spectroscopy.

Science.gov (United States)

Mork, Steven Wayne

High resolution infrared spectroscopy was used to examine intramolecular vibrational interactions in 2 -fluoroethanol (2FE) and 1,2-difluoroethane (DFE). A high resolution infrared spectrophotometer capable of better than 10 MHz spectral resolution was designed and constructed. The excitation source consists of three lasers: an argon-ion pumped dye laser which pumps a color -center laser. The infrared beam from the color-center laser is used to excite sample molecules which are rotationally and vibrationally cooled in a supersonic molecular beam. Rovibrational excitation of the sample molecules is detected by monitoring the kinetic energy of the molecular beam with a bolometer. The high resolution infrared spectrum of 2FE was collected and analyzed over the 2977-2990 cm^ {-1}^ectral region. This region contains the asymmetric CH stretch on the fluorinated carbon. The spectrum revealed extensive perturbations in the rotational fine structure. Analysis of these perturbations has provided a quantitative measure of selective vibrational mode coupling between the C-H stretch and its many neighboring dark vibrational modes. Interestingly, excitation of the C-H stretch is known to induce a photoisomerization reaction between 2FE's Gg^' and Tt conformers. Implications of the role of mode coupling in the reaction mechanism are also addressed. Similarly, the high resolution infrared spectrum of DFE was collected and analyzed over the 2978-2996 cm ^{-1}^ectral region. This region contains the symmetric combination of asymmetric C-H stretches in DFE. Perturbations in the rotational fine structure indicate vibrational mode coupling to a single dark vibrational state. The dark state is split by approximately 19 cm^{-1} due to tunneling between two identical gauche conformers. The coupling mechanism is largely anharmonic with a minor component of B/C-plane Coriolis coupling. Effects of centrifugal distortion along the molecular A-axis are also observed. The coupled vibrational

Quantitative mid-infrared spectra of allene and propyne from room to high temperatures

KAUST Repository

Es-sebbar, Et-touhami; Jolly, A.; Benilan, Y.; Farooq, Aamir

2014-01-01

Allene (a-C3H4; CH2CCH2) and propyne (p-C3H4; CH3C2H) have attracted much interest because of their relevance to the photochemistry in astrophysical environments as well as in combustion processes. Both allene and propyne have strong absorption in the infrared region. In the present work, infrared spectra of a-C3H4 and p-C3H4 are measured in the gas phase at temperatures ranging from 296 to 510 K. The spectra are measured over the 580-3400 cm-1 spectral region at resolutions of 0.08 and 0.25 cm-1 using Fourier Transform Infrared spectroscopy. Absolute integrated intensities of the main infrared bands are determined at room temperature and compared with values derived from literature for both molecules. Integrated band intensities are also determined as a function of temperature in various spectral regions.

Quantitative mid-infrared spectra of allene and propyne from room to high temperatures

KAUST Repository

Es-sebbar, Et-touhami

2014-11-01

Allene (a-C3H4; CH2CCH2) and propyne (p-C3H4; CH3C2H) have attracted much interest because of their relevance to the photochemistry in astrophysical environments as well as in combustion processes. Both allene and propyne have strong absorption in the infrared region. In the present work, infrared spectra of a-C3H4 and p-C3H4 are measured in the gas phase at temperatures ranging from 296 to 510 K. The spectra are measured over the 580-3400 cm-1 spectral region at resolutions of 0.08 and 0.25 cm-1 using Fourier Transform Infrared spectroscopy. Absolute integrated intensities of the main infrared bands are determined at room temperature and compared with values derived from literature for both molecules. Integrated band intensities are also determined as a function of temperature in various spectral regions.

MID-INFRARED ATOMIC FINE-STRUCTURE EMISSION-LINE SPECTRA OF LUMINOUS INFRARED GALAXIES: SPITZER/IRS SPECTRA OF THE GOALS SAMPLE

Energy Technology Data Exchange (ETDEWEB)

Inami, H. [National Optical Astronomy Observatory, Tucson, AZ 85719 (United States); Armus, L.; Stierwalt, S.; Díaz-Santos, T.; Surace, J.; Howell, J.; Marshall, J. [Spitzer Science Center, California Institute of Technology, CA 91125 (United States); Charmandaris, V. [Department of Physics and Institute of Theoretical and Computational Physics, University of Crete, GR-71003 Heraklion (Greece); Groves, B. [Max Planck Institute for Astronomy, Königstuhl 17, D-69117 Heidelberg (Germany); Kewley, L. [Research School of Astronomy and Astrophysics, The Australian National University, Cotter Road, Weston Creek, ACT 2611 (Australia); Petric, A. [Department of Astronomy, California Institute of Technology, MS 320-47, Pasadena, CA 91125 (United States); Rich, J. [The Observatories, Carnegie Institute of Washington, 813 Santa Barbara Street, Pasadena, CA 91101 (United States); Haan, S. [CSIRO Astronomy and Space Science, Marsfield, NSW 2122 (Australia); Evans, A. S. [Department of Astronomy, University of Virginia, P.O. Box 400325, Charlottesville, VA 22904 (United States); Mazzarella, J.; Lord, S. [Infrared Processing and Analysis Center, MS 100-22, California Institute of Technology, Pasadena, CA 91125 (United States); Appleton, P. [NASA Herschel Science Center, 770 South Wilson Avenue, Pasadena, CA 91125 (United States); Spoon, H. [Astronomy Department, Cornell University, Ithaca, NY 14853 (United States); Frayer, D. [National Radio Astronomy Observatory, P.O. Box 2, Green Bank, WV 24944 (United States); Matsuhara, H., E-mail: inami@noao.edu [Institute of Space and Astronautical Science, Japan Aerospace Exploration Agency (Japan); and others

2013-11-10

We present the data and our analysis of mid-infrared atomic fine-structure emission lines detected in Spitzer/Infrared Spectrograph high-resolution spectra of 202 local Luminous Infrared Galaxies (LIRGs) observed as part of the Great Observatories All-sky LIRG Survey (GOALS). We readily detect emission lines of [S IV], [Ne II], [Ne V], [Ne III], [S III]{sub 18.7{sub μm}}, [O IV], [Fe II], [S III]{sub 33.5{sub μm}}, and [Si II]. More than 75% of these galaxies are classified as starburst-dominated sources in the mid-infrared, based on the [Ne V]/[Ne II] line flux ratios and equivalent width of the 6.2 μm polycyclic aromatic hydrocarbon feature. We compare ratios of the emission-line fluxes to those predicted from stellar photo-ionization and shock-ionization models to constrain the physical and chemical properties of the gas in the starburst LIRG nuclei. Comparing the [S IV]/[Ne II] and [Ne III]/[Ne II] line ratios to the Starburst99-Mappings III models with an instantaneous burst history, the emission-line ratios suggest that the nuclear starbursts in our LIRGs have ages of 1-4.5 Myr, metallicities of 1-2 Z{sub ☉}, and ionization parameters of 2-8 × 10{sup 7} cm s{sup –1}. Based on the [S III]{sub 33.5{sub μm}}/[S III]{sub 18.7{sub μm}} ratios, the electron density in LIRG nuclei is typically one to a few hundred cm{sup –3}, with a median electron density of ∼300 cm{sup –3}, for those sources above the low density limit for these lines. We also find that strong shocks are likely present in 10 starburst-dominated sources of our sample. A significant fraction of the GOALS sources (80) have resolved neon emission-line profiles (FWHM ≥600 km s{sup –1}) and five show clear differences in the velocities of the [Ne III] or [Ne V] emission lines, relative to [Ne II], of more than 200 km s{sup –1}. Furthermore, six starburst and five active galactic nucleus dominated LIRGs show a clear trend of increasing line width with ionization potential

Multi-octave supercontinuum generation from mid-infrared filamentation in a bulk crystal

Directory of Open Access Journals (Sweden)

Faccio D.

2013-03-01

Full Text Available We present supercontinuum generation pumped by femtosecond mid-infrared pulses in a bulk homogeneous material. The spectrum extends from 450 nm into the midinfrared, and carries high spectral energy density (3 pJ/nm–10 nJ/nm. The supercontinuum has high shot-to-shot reproducibility and preserves the carrier-to-envelope phase. Our result paves the way for compact supercontinuum sources with unprecedented bandwidth.

MID-INFRARED PHOTOMETRY OF COLD BROWN DWARFS: DIVERSITY IN AGE, MASS, AND METALLICITY

International Nuclear Information System (INIS)

Leggett, S. K.; Burningham, Ben; Jones, H. R. A.; Lucas, P. W.; Pinfield, D. J.; Saumon, D.; Marley, M. S.; Warren, S. J.; Smart, R. L.; Tamura, Motohide

2010-01-01

We present new Spitzer Infrared Array Camera (IRAC) photometry of 12 very late-type T dwarfs: nine have [3.6], [4.5], [5.8], and [8.0] photometry and three have [3.6] and [4.5] photometry only. Combining this with previously published photometry, we investigate trends with type and color that are useful for both the planning and interpretation of infrared surveys designed to discover the coldest T or Y dwarfs. The online appendix provides a collation of MKO-system YJHKL'M' and IRAC photometry for a sample of M, L, and T dwarfs. Brown dwarfs with effective temperature (T eff ) below 700 K emit more than half their flux at wavelengths longer than 3 μm, and the ratio of the mid-infrared flux to the near-infrared flux becomes very sensitive to T eff at these low temperatures. We confirm that the color H (1.6 μm) - [4.5] is a good indicator of T eff with a relatively weak dependence on metallicity and gravity. Conversely, the colors H - K (2.2 μm) and [4.5] - [5.8] are sensitive to metallicity and gravity. Thus, near- and mid-infrared photometry provide useful indicators of the fundamental properties of brown dwarfs, and if temperature and gravity are known, then mass and age can be reliably determined from evolutionary models. There are 12 dwarfs currently known with H- [4.5] >3.0, and 500 K ∼ eff ∼<800 K, which we examine in detail. The ages of the dwarfs in the sample range from very young (0.1-1.0 Gyr) to relatively old (3-12 Gyr). The mass range is possibly as low as 5 Jupiter masses to up to 70 Jupiter masses, i.e., near the hydrogen burning limit. The metallicities also span a large range, from [m/H] = -0.3 to [m/H] = +0.3. The small number of T8-T9 dwarfs found in the UK Infrared Telescope Infrared Deep Sky Survey to date appear to be predominantly young low-mass dwarfs. Accurate mid-infrared photometry of cold brown dwarfs is essentially impossible from the ground, and extensions to the mid-infrared space missions, warm-Spitzer and Wide-Field Infrared

High-power, continuous-wave, mid-infrared optical parametric oscillator based on MgO:sPPLT.

Science.gov (United States)

Chaitanya Kumar, S; Ebrahim-Zadeh, M

2011-07-01

We report a stable, high-power, cw, mid-IR optical parametric oscillator using MgO-doped stoichiometric periodically poled LiTaO₃ (MgO:sPPLT) pumped by a Yb fiber laser at 1064 nm. The singly resonant oscillator (SRO), based on a 30 mm long crystal, is tunable over 430 nm from 3032 to 3462 nm and can generate as much as 5.5 W of mid-IR output power, with >4 W of over 60% of the tuning range and under reduced thermal effects, enabling room temperature operation. Idler power scaling measurements at ~3.3 μm are compared with an MgO-doped periodically poled LiNbO₃ cw SRO, confirming that MgO:sPPLT is an attractive material for multiwatt mid-IR generation. The idler output at 3299 nm exhibits a peak-to-peak power stability better than 12.8% over 5 h and frequency stability of ~1 GHz, while operating close to room temperature, and has a linewidth of ~0.2 nm, limited by the resolution of the wavemeter. The corresponding signal linewidth at 1570 nm is ~21 MHz.

Mid-infrared quantum cascade laser spectroscopy probing of the ...

Indian Academy of Sciences (India)

Aparajeo Chattopadhyay

2018-05-07

May 7, 2018 ... cm3 molecule. −1 s. −1 ... Quantum cascade laser; time-resolved mid-infrared spectroscopy; transient absorption; peroxy radicals .... peak of the laser emission profile. .... cal with O2 is a termolecular reaction (Eq. 3) and the.

Mid-infrared followup of cold brown dwarfs: diversity in age, mass and metallicity

Energy Technology Data Exchange (ETDEWEB)

Saumon, Didier [Los Alamos National Laboratory; Leggett, Sandy K [GEMINI OBSERVATORY; Burningham, Ben [HERTFORDSHITE UNIV; Marley, Mark S [NASA AMES; Waren, S J [IMPERIAL COLLEGE LONDON; Jones, H R A [HERTFORDSHIRE U; Pinfield, D J [HERTFORDSHIRE U; Smart, R L [ASTRONOMICAL OBS

2009-01-01

We present new Spitzer IRAC [3.6], [4.5], [5.8] and [8.0] photometry of nine very late-type T dwarfs. Combining this with previously published photometry, we investigate trends with type and color that are useful for both the planning and interpretation of infrared surveys designed to discover the coldest T or Y dwarfs. Brown dwarfs with effective temperature (T{sub eff}) below 700 K emit more than half their flux at wavelengths longer than 3 {micro}m, and the ratio of the mid-infrared flux to the near-infrared flux becomes very sensitive to T{sub eff} at these low temperatures. We confirm that the color H (1.6 {micro}m) - [4.5] is a good indicator of T{sub eff} with a relatively weak dependence on metallicity and gravity. Conversely, the colors H - K (2.2 {micro}m) and [4.5] - [5.8] are sensitive to metallicity and gravity. Thus near- and mid-infrared photometry provide useful indicators of the fundamental properties of brown dwarfs, and if temperature and gravity are known, then mass and age can be reliably determined from evolutionary models. There are twelve dwarfs currently known with H - [4.5] > 3.0, and {approx} 500 < T{sub eff} K {approx}< 800, which we examine in detail. The ages of the dwarfs in the sample range from very young (0.1 - 1.0 Gyr) to relatively old (3 - 12 Gyr). The mass range is possibly as low as 5 Jupiter masses to up to 70 Jupiter masses, i.e. near the hydrogen burning limit. The metallicities also span a large range, from [m/H]= -0.3 to [m/H]= +0.2. The small number of T8 - T9 dwarfs found in the UKIRT Infrared Deep Sky Survey to date appear to be predominantly young low-mass dwarfs. Accurate mid-infrared photometry of cold brown dwarfs is essentially impossible from the ground, and extensions to the mid-infrared space missions warm-Spitzer and WISE are desirable in order to obtain the vital mid-infrared data for cold brown dwarfs, and to discover more of these rare objects.

A full-sky, high-resolution atlas of galactic 12 μm dust emission with WISE

International Nuclear Information System (INIS)

Meisner, Aaron M.; Finkbeiner, Douglas P.

2014-01-01

We describe our custom processing of the entire Wide-field Infrared Survey Explorer (WISE) 12 μm imaging data set, and present a high-resolution, full-sky map of diffuse Galactic dust emission that is free of compact sources and other contaminating artifacts. The principal distinctions between our resulting co-added images and the WISE Atlas stacks are our removal of compact sources, including their associated electronic and optical artifacts, and our preservation of spatial modes larger than 1.°5. We provide access to the resulting full-sky map via a set of 430 12.°5 × 12.°5 mosaics. These stacks have been smoothed to 15'' resolution and are accompanied by corresponding coverage maps, artifact images, and bit-masks for point sources, resolved compact sources, and other defects. When combined appropriately with other mid-infrared and far-infrared data sets, we expect our WISE 12 μm co-adds to form the basis for a full-sky dust extinction map with angular resolution several times better than Schlegel et al.

Herbig-haro objects and mid-infrared outflows in the VELA C molecular cloud

International Nuclear Information System (INIS)

Zhang, Miaomiao; Wang, Hongchi; Henning, Thomas

2014-01-01

We have performed a deep [S II] λλ6717/6731 wide field Herbig-Haro (HH) object survey toward the Vela C molecular cloud with a sky coverage of about 2 deg 2 . In total, 18 new HH objects, HH 1090-1107, are discovered and the two previously known HH objects, HH 73-74, are also detected in our [S II] images. We also present an investigation of mid-infrared outflows in the Vela C molecular cloud using the Wide-field Infrared Survey Explorer images taken from AllWISE data release. Using the method suggested by Zhang and Wang, 11 extended green objects (EGOs) are identified to be the mid-infrared outflows, including 6 new mid-infrared outflows that have not been detected previously at other wavelengths and 5 mid-infrared counterparts of the HH objects detected in this work. Using the AllWISE Source Catalog and the source classification scheme suggested by Koenig et al., we have identified 56 young stellar object (YSO) candidates in the Vela C molecular cloud. The possible driving sources of the HH objects and EGOs are discussed based on the morphology of HH objects and EGOs and the locations of HH objects, EGOs and YSO candidates. Finally we associate 12 HH objects and 5 EGOs with 10 YSOs and YSO candidates. The median length of the outflows in Vela C is 0.35 pc and the outflows seem to be oriented randomly.

Dilute bismides for near and mid-infrared applications

DEFF Research Database (Denmark)

Song, Yuxin; Gu, Yi; Ye, Hong

2013-01-01

Dilute bismides are a group of emerging materials with unique properties. Incorporation of a small amount of Bi in common III–V host materials results in large band-gap reduction and strong spin-orbit splitting, leading to potential applications in near-infrared (NIR) and mid-infrared (MIR......) optoelectronics. Recent progresses on molecular beam epitaxy (MBE) of novel III-Sb-Bi, i.e. GaSbBi and InSbBi thin films from our group are summarised in this paper. Quantum well structures based on GaSbBi and InGaAsBi aiming for the optical communication window were grown and characterized....

Mid-Infrared Interferometry on Spectral Lines. III. Ammonia and Silane around IRC +10216 and VY Canis Majoris

Science.gov (United States)

Monnier, J. D.; Danchi, W. C.; Hale, D. S.; Tuthill, P. G.; Townes, C. H.

2000-11-01

Using the University of California Berkeley Infrared Spatial Interferometer with a radio frequency (RF) filter bank, the first interferometric observations of mid-infrared molecular absorption features of ammonia (NH3) and silane (SiH4) with very high spectral resolution (λ/Δλ~105) were made. Under the assumptions of spherical symmetry and uniform outflow, these new data permitted the molecular stratification around carbon star IRC +10216 and red supergiant VY CMa to be investigated. For IRC +10216, both ammonia and silane were found to form in the dusty outflow significantly beyond both the dust formation and gas acceleration zones. Specifically, ammonia was found to form before silane in a region of decaying gas turbulence (>~20R*), while the silane is produced in a region of relatively smooth gas flow much farther from the star (>~80R*). The depletion of gas-phase SiS onto grains soon after dust formation may fuel silane-producing reactions on the grain surfaces. For VY CMa, a combination of interferometric and spectral observations suggest that NH3 is forming near the termination of the gas acceleration phase in a region of high gas turbulence (~40R*).

THELI: CONVENIENT REDUCTION OF OPTICAL, NEAR-INFRARED, AND MID-INFRARED IMAGING DATA

International Nuclear Information System (INIS)

Schirmer, M.

2013-01-01

The last 15 years have seen a surge of new multi-chip optical and near-IR imagers. While some of them are accompanied by specific reduction pipelines, user-friendly and generic reduction tools are uncommon. In this paper I introduce THELI, an easy-to-use graphical interface driving an end-to-end pipeline for the reduction of any optical, near-IR, and mid-IR imaging data. The advantages of THELI when compared to other approaches are highlighted. Combining a multitude of processing algorithms and third party software, THELI provides researchers with a single, homogeneous tool. A short learning curve ensures quick success for new and more experienced observers alike. All tasks are largely automated, while at the same time a high level of flexibility and alternative reduction schemes ensure that widely different scientific requirements can be met. Over 90 optical and infrared instruments at observatories world-wide are pre-configured, while more can be added by the user. The Appendices contain three walk-through examples using public data (optical, near-IR, and mid-IR). Additional extensive documentation for training and troubleshooting is available online

The gas-rich circumbinary disk of HR 4049. I. A detailed study of the mid-infrared spectrum

Energy Technology Data Exchange (ETDEWEB)

Malek, S. E.; Cami, J., E-mail: sarahemalek@gmail.com, E-mail: jcami@uwo.ca [Department of Physics and Astronomy, University of Western Ontario, London, ON N6A 3K7 (Canada)

2014-01-01

We present a detailed analysis of the mid-infrared spectrum of the peculiar evolved object HR 4049. The full Spitzer-IRS high-resolution spectrum shows a wealth of emission with prominent features from CO{sub 2} and H{sub 2}O and possible contributions from HCN and OH. We model the molecular emission and find that it originates from a massive (M ≳ 8 × 10{sup –3} M {sub ☉}), warm (T {sub ex} ≈ 500 K) and radially extended gas disk that is optically thick at infrared wavelengths. We also report less enrichment in {sup 17}O and {sup 18}O than previously found and a comparison of the Spitzer observations to earlier data obtained by the Short Wavelength Spectrometer on board the Infrared Space Observatory reveals that the CO{sub 2} flux has more than doubled in 10 yr time, indicating active and ongoing chemical evolution in the circumbinary disk. If the gas originates from interaction between the stellar wind and the dust, this suggests that the dust could be oxygen-rich in nature. The molecular gas plays a crucial role in the thermal properties of the circumbinary disk by allowing visible light to heat the dust and then trapping the infrared photons emitted by the dust. This results in higher temperatures and a more homogeneous temperature structure in the disk.

Probing the mid-infrared spectrum of YBa2Cu3O6.0 with high magnetic fields and Zink doping

NARCIS (Netherlands)

Gruninger, M; vanderMarel, D; vanBentum, PJM; Erb, A; Wolf, T; Kopp, T

1996-01-01

The mid-infrared phonon and spin-wave spectrum of antiferromagnetic YBa2Cu3O6.0 was investigated by infrared transmission measurements (k(-->) parallel to c-axis) at T=4K. Peaks at 178 meV, 346 meV and 470 meV were previously interpreted as excitations of single magnons of the optical branch and of

A High-Power Continuous-Wave Mid-Infrared Optical Parametric Oscillator Module

Directory of Open Access Journals (Sweden)

Yichen Liu

2017-12-01

Full Text Available We demonstrate here a compact optical parametric oscillator module for mid-infrared generation via nonlinear frequency conversion. This module weighs only 2.5 kg and fits within a small volume of 220 × 60 × 55 mm3. The module can be easily aligned to various pump laser sources, and here we use a 50 W ytterbium (Yb-doped fiber laser as an example. With a two-channel MgO-doped periodically poled lithium niobate crystal (MgO:PPLN, our module covers a tuning range of 2416.17–2932.25 nm and 3142.18–3452.15 nm. The highest output power exceeds 10.4 W at 2.7 μm, corresponding to a conversion efficiency of 24%. The measured power stability is 2.13% Root Meat Square (RMS for a 10 h duration under outdoor conditions.

High-resolution imaging and near-infrared spectroscopy of penumbral decay

Science.gov (United States)

Verma, M.; Denker, C.; Balthasar, H.; Kuckein, C.; Rezaei, R.; Sobotka, M.; Deng, N.; Wang, H.; Tritschler, A.; Collados, M.; Diercke, A.; Manrique, S. J. González

2018-06-01

Aims: Combining high-resolution spectropolarimetric and imaging data is key to understanding the decay process of sunspots as it allows us to scrutinize the velocity and magnetic fields of sunspots and their surroundings. Methods: Active region NOAA 12597 was observed on 2016 September 24 with the 1.5-meter GREGOR solar telescope using high-spatial-resolution imaging as well as imaging spectroscopy and near-infrared (NIR) spectropolarimetry. Horizontal proper motions were estimated with local correlation tracking, whereas line-of-sight (LOS) velocities were computed with spectral line fitting methods. The magnetic field properties were inferred with the "Stokes Inversions based on Response functions" (SIR) code for the Si I and Ca I NIR lines. Results: At the time of the GREGOR observations, the leading sunspot had two light bridges indicating the onset of its decay. One of the light bridges disappeared, and an elongated, dark umbral core at its edge appeared in a decaying penumbral sector facing the newly emerging flux. The flow and magnetic field properties of this penumbral sector exhibited weak Evershed flow, moat flow, and horizontal magnetic field. The penumbral gap adjacent to the elongated umbral core and the penumbra in that penumbral sector displayed LOS velocities similar to granulation. The separating polarities of a new flux system interacted with the leading and central part of the already established active region. As a consequence, the leading spot rotated 55° clockwise over 12 h. Conclusions: In the high-resolution observations of a decaying sunspot, the penumbral filaments facing the flux emergence site contained a darkened area resembling an umbral core filled with umbral dots. This umbral core had velocity and magnetic field properties similar to the sunspot umbra. This implies that the horizontal magnetic fields in the decaying penumbra became vertical as observed in flare-induced rapid penumbral decay, but on a very different time-scale.

Cutting and skin-ablative properties of pulsed mid-infrared laser surgery.

Science.gov (United States)

Kaufmann, R; Hartmann, A; Hibst, R

1994-02-01

Pulsed mid-infrared lasers allow a precise removal of soft tissues with only minimal thermal damage. To study the potential dermatosurgical usefulness of currently available systems at different wavelengths (2010-nm Thulium:YAG laser, 2100-nm Holmium:YAG laser, 2790-nm Erbium:YSGG laser, and 2940-nm Erbium:YAG laser) in vivo on pig skin. Immediate effects and wound healing of superficial laser-abrasions and incisions were compared with those of identical control lesions produced by dermabrasion, scalpel incisions, or laser surgery performed by a 1060-nm Nd:YAG and a 1060-nm CO2 laser (continuous and superpulsed mode). Best efficiency and least thermal injury was found for the pulsed Erbium:YAG laser, leading to ablative and incisional lesions comparable to those obtained by dermabrasion or superficial scalpel incisions, respectively. In contrast to other mid-infrared lasers tested, the 2940-nm Erbium:YAG laser thus provides a potential instrument for future applications in skin surgery, especially when aiming at a careful ablative removal of delicate superficial lesions with maximum sparing of adjacent tissue structures. However, in the purely incisional application mode pulsed mid-infrared lasers, though of potential usefulness in microsurgical indications (eg, surgery of the cornea), do not offer a suggestive alternative to simple scalpel surgery of the skin.

Seasonal variation of the radial brightness contrast of Saturn's rings viewed in mid-infrared by Subaru/COMICS

Science.gov (United States)

Fujiwara, Hideaki; Morishima, Ryuji; Fujiyoshi, Takuya; Yamashita, Takuya

2017-03-01

Aims: This paper investigates the mid-infrared (MIR) characteristics of Saturn's rings. Methods: We collected and analyzed MIR high spatial resolution images of Saturn's rings obtained in January 2008 and April 2005 with the COoled Mid-Infrared Camera and Spectrometer (COMICS) mounted on the Subaru Telescope, and investigated the spatial variation in the surface brightness of the rings in multiple bands in the MIR. We also composed the spectral energy distributions (SEDs) of the C, B, and A rings and the Cassini Division, and estimated the temperatures of the rings from the SEDs assuming the optical depths. Results: We found that the C ring and the Cassini Division were warmer than the B and A rings in 2008, which could be accounted for by their lower albedos, lower optical depths, and smaller self-shadowing effect. We also fonud that the C ring and the Cassini Division were considerably brighter than the B and A rings in the MIR in 2008 and the radial contrast of the ring brightness is the inverse of that in 2005, which is interpreted as a result of a seasonal effect with changing elevations of the Sun and observer above the ring plane. The reduced images (FITS files) are only available at the CDS via anonymous ftp to http://cdsarc.u-strasbg.fr (http://130.79.128.5) or via http://cdsarc.u-strasbg.fr/viz-bin/qcat?J/A+A/599/A29

New High-Resolution Absorption Cross-Section Measurements of HCFC-142B in the Mid-Ir

Science.gov (United States)

Le Bris, Karine; Strong, Kimberly; Melo, Stella

2009-06-01

HCFC-142b (1-chloro-1,1-difluoroethane) is a temporary substitute for ozone-depleting chlorofluorocarbons (CFCs). However, due to its high absorption cross-sections in the mid-IR, HCFC-142b is also a highly potent greenhouse gas, now detectable from space by satellite missions. So far, the accuracy of the retrieval has been limited by the lack of reference data in a range of temperatures compatible with atmospheric observations. We present new absorption cross section measurements of HCFC-142b at high-resolution (0.02 cm^{-1}) from 223 K to 283 K in the 600 cm^{-1}- 4000 cm^{-1} spectral window. The composite spectra are calculated for each temperature from a set of acquisitions at different pressures by Fourier transform spectroscopy.

Ultrasensitive Detection of Infrared Photon Using Microcantilever: Theoretical Analysis

International Nuclear Information System (INIS)

Li-Xin, Cao; Feng-Xin, Zhang; Yin-Fang, Zhu; Jin-Ling, Yang

2010-01-01

We present a new method for detecting near-infrared, mid-infrared, and far-infrared photons with an ultrahigh sensitivity. The infrared photon detection was carried out by monitoring the displacement change of a vibrating microcantilever under light pressure using a laser Doppler vibrometer. Ultrathin silicon cantilevers with high sensitivity were produced using micro/nano-fabrication technology. The photon detection system was set up. The response of the microcantilever to the photon illumination is theoretically estimated, and a nanowatt resolution for the infrared photon detection is expected at room temperature with this method

Mid-infrared Spectroscopy/Bioimaging: Moving toward MIR optical biopsy

DEFF Research Database (Denmark)

Seddon, Angela B.; Napier, Bruce; Lindsay, Ian

2016-01-01

), with its ability to enable in vivo medical diagnosis, is particularly interesting. In fact, the European Commission provides support for a major effort to develop the technology through its Framework Seven (FP7) project called MINERVA (MId- to-NEaR- infrared spectroscopy for improVed medical diAgnostics)....

Silicon nitride photonics: from visible to mid-infrared wavelengths

Science.gov (United States)

Micó, Gloria; Bru, Luis A.; Pastor, Daniel; Doménech, David; Fernández, Juan; Sánchez, Ana; Cirera, Josep M.; Domínguez, Carlos; Muñoz, Pascual

2018-02-01

Silicon nitride has received a lot of attention during the last ten years, for applications such as bio-photonics, tele/datacom, optical signal processing and sensing. In this paper, firstly an updated review of the state of the art of silicon nitride photonics integration platforms will be provided. Secondly, our developments on a moderate confinement Si3N4 platform in the near-infrared will be presented. Finally, our steps towards establishing a Si3N4 based platform for broadband operation spanning from visible to mid-infrared wavelengths will be introduced.

Mid-infrared photoacoustic spectroscopy for atmospheric NO2 measurements

Science.gov (United States)

Lassen, Mikael; Lamard, Laurent; Balslev-Harder, David; Peremans, Andre; Petersen, Jan C.

2018-02-01

A photoacoustic (PA) sensor for spectroscopic measurements of NO2-N2 at ambient pressure and temperature is demonstrated. The PA sensor is pumped resonantly by a nanosecond pulsed single-mode mid-infrared (MIR) optical parametric oscillator (OPO). Spectroscopic measurements of NO2-N2 in the 3.25 μm to 3.55 μm wavelength region with a resolution bandwidth of 5 cm-1 and with a single shot detection limit of 1.6 ppmV (μmol/mol) is demonstrated. The measurements were conducted with a constant flow rate of 300 ml/min, thus demonstrating the suitability of the gas sensor for real time trace gas measurements. The acquired spectra is compared with data from the Hitran database and good agreement is found. An Allan deviation analysis shows that the detection limit at optimum integration time for the PAS sensor is 14 ppbV (nmol/mol) at 170 seconds of integration time, corresponding to a normalized noise equivalent absorption (NNEA) coefficient of 3.3×10-7 W cm-1 Hz-1/2.

Mid-infrared frequency comb via coherent dispersive wave generation in silicon nitride nanophotonic waveguides

Science.gov (United States)

Guo, Hairun; Herkommer, Clemens; Billat, Adrien; Grassani, Davide; Zhang, Chuankun; Pfeiffer, Martin H. P.; Weng, Wenle; Brès, Camille-Sophie; Kippenberg, Tobias J.

2018-06-01

Mid-infrared optical frequency combs are of significant interest for molecular spectroscopy due to the large absorption of molecular vibrational modes on the one hand, and the ability to implement superior comb-based spectroscopic modalities with increased speed, sensitivity and precision on the other hand. Here, we demonstrate a simple, yet effective, method for the direct generation of mid-infrared optical frequency combs in the region from 2.5 to 4.0 μm (that is, 2,500-4,000 cm-1), covering a large fraction of the functional group region, from a conventional and compact erbium-fibre-based femtosecond laser in the telecommunication band (that is, 1.55 μm). The wavelength conversion is based on dispersive wave generation within the supercontinuum process in an unprecedented large-cross-section silicon nitride (Si3N4) waveguide with the dispersion lithographically engineered. The long-wavelength dispersive wave can perform as a mid-infrared frequency comb, whose coherence is demonstrated via optical heterodyne measurements. Such an approach can be considered as an alternative option to mid-infrared frequency comb generation. Moreover, it has the potential to realize compact dual-comb spectrometers. The generated combs also have a fine teeth-spacing, making them suitable for gas-phase analysis.

Discrete parametric band conversion in silicon for mid-infrared applications.

Science.gov (United States)

Tien, En-Kuang; Huang, Yuewang; Gao, Shiming; Song, Qi; Qian, Feng; Kalyoncu, Salih K; Boyraz, Ozdal

2010-10-11

Silicon photonics has great potential for mid-wave-infrared applications. The dispersion of waveguide can be manipulated by waveguide dimension and cladding materials. Simulation shows that <3 μm wide conversion can be achieved by tuning the pump wavelength.

Cloud top structure of Venus revealed by Subaru/COMICS mid-infrared images

Science.gov (United States)

Sato, T. M.; Sagawa, H.; Kouyama, T.; Mitsuyama, K.; Satoh, T.; Ohtsuki, S.; Ueno, M.; Kasaba, Y.; Nakamura, M.; Imamura, T.

2014-11-01

We have investigated the cloud top structure of Venus by analyzing ground-based images taken at the mid-infrared wavelengths of 8.66 μm and 11.34 μm. Venus at a solar phase angle of ∼90°, with the morning terminator in view, was observed by the Cooled Mid-Infrared Camera and Spectrometer (COMICS), mounted on the 8.2-m Subaru Telescope, during the period October 25-29, 2007. The disk-averaged brightness temperatures for the observation period are ∼230 K and ∼238 K at 8.66 μm and 11.34 μm, respectively. The obtained images with good signal-to-noise ratio and with high spatial resolution (∼200 km at the sub-observer point) provide several important findings. First, we present observational evidence, for the first time, of the possibility that the westward rotation of the polar features (the hot polar spots and the surrounding cold collars) is synchronized between the northern and southern hemispheres. Second, after high-pass filtering, the images reveal that streaks and mottled and patchy patterns are distributed over the entire disk, with typical amplitudes of ∼0.5 K, and vary from day to day. The detected features, some of which are similar to those seen in past UV images, result from inhomogeneities of both the temperature and the cloud top altitude. Third, the equatorial center-to-limb variations of brightness temperatures have a systematic day-night asymmetry, except those on October 25, that the dayside brightness temperatures are higher than the nightside brightness temperatures by 0-4 K under the same viewing geometry. Such asymmetry would be caused by the propagation of the migrating semidiurnal tide. Finally, by applying the lapse rates deduced from previous studies, we demonstrate that the equatorial center-to-limb curves in the two spectral channels give access to two parameters: the cloud scale height H and the cloud top altitude zc. The acceptable models for data on October 25 are obtained at H = 2.4-4.3 km and zc = 66-69 km; this supports

Generating Efficient Femtosecond Mid-infrared Pulse by Single Near-infrared Pump Wavelength in Bulk Nonlinear Crystal Without Phase-matching

DEFF Research Database (Denmark)

Zhou, Binbin; Guo, Hairun; Bache, Morten

2014-01-01

We experimentally demonstrate efficient mid-infrared pulse generation by dispersive wave radiation in bulk lithium niobate crystal. Femtosecond mid-IR pulses centering from 2.8-2.92 μm are generated using the single pump wavelengths from 1.25-1.45 μm. © 2014 Optical Society of America...

Ultrafast Silicon Photonics with Visible to Mid-Infrared Pumping of Silicon Nanocrystals.

Science.gov (United States)

Diroll, Benjamin T; Schramke, Katelyn S; Guo, Peijun; Kortshagen, Uwe R; Schaller, Richard D

2017-10-11

Dynamic optical control of infrared (IR) transparency and refractive index is achieved using boron-doped silicon nanocrystals excited with mid-IR optical pulses. Unlike previous silicon-based optical switches, large changes in transmittance are achieved without a fabricated structure by exploiting strong light coupling of the localized surface plasmon resonance (LSPR) produced from free holes of p-type silicon nanocrystals. The choice of optical excitation wavelength allows for selectivity between hole heating and carrier generation through intraband or interband photoexcitation, respectively. Mid-IR optical pumping heats the free holes of p-Si nanocrystals to effective temperatures greater than 3500 K. Increases of the hole effective mass at high effective hole temperatures lead to a subpicosecond change of the dielectric function, resulting in a redshift of the LSPR, modulating mid-IR transmission by as much as 27%, and increasing the index of refraction by more than 0.1 in the mid-IR. Low hole heat capacity dictates subpicosecond hole cooling, substantially faster than carrier recombination, and negligible heating of the Si lattice, permitting mid-IR optical switching at terahertz repetition frequencies. Further, the energetic distribution of holes at high effective temperatures partially reverses the Burstein-Moss effect, permitting the modulation of transmittance at telecommunications wavelengths. The results presented here show that doped silicon, particularly in micro- or nanostructures, is a promising dynamic metamaterial for ultrafast IR photonics.

Versatile mid-infrared frequency-comb referenced sub-Doppler spectrometer

Science.gov (United States)

Gambetta, A.; Vicentini, E.; Coluccelli, N.; Wang, Y.; Fernandez, T. T.; Maddaloni, P.; De Natale, P.; Castrillo, A.; Gianfrani, L.; Laporta, P.; Galzerano, G.

2018-04-01

We present a mid-IR high-precision spectrometer capable of performing accurate Doppler-free measurements with absolute calibration of the optical axis and high signal-to-noise ratio. The system is based on a widely tunable mid-IR offset-free frequency comb and a Quantum-Cascade-Laser (QCL). The QCL emission frequency is offset locked to one of the comb teeth to provide absolute-frequency calibration, spectral-narrowing, and accurate fine frequency tuning. Both the comb repetition frequency and QCL-comb offset frequency can be modulated to provide, respectively, slow- and fast-frequency-calibrated scanning capabilities. The characterisation of the spectrometer is demonstrated by recording sub-Doppler saturated absorption features of the CHF3 molecule at around 8.6 μm with a maximum signal-to-noise ratio of ˜7 × 103 in 10 s integration time, frequency-resolution of 160 kHz, and accuracy of less than 10 kHz.

Versatile mid-infrared frequency-comb referenced sub-Doppler spectrometer

Directory of Open Access Journals (Sweden)

A. Gambetta

2018-04-01

Full Text Available We present a mid-IR high-precision spectrometer capable of performing accurate Doppler-free measurements with absolute calibration of the optical axis and high signal-to-noise ratio. The system is based on a widely tunable mid-IR offset-free frequency comb and a Quantum-Cascade-Laser (QCL. The QCL emission frequency is offset locked to one of the comb teeth to provide absolute-frequency calibration, spectral-narrowing, and accurate fine frequency tuning. Both the comb repetition frequency and QCL-comb offset frequency can be modulated to provide, respectively, slow- and fast-frequency-calibrated scanning capabilities. The characterisation of the spectrometer is demonstrated by recording sub-Doppler saturated absorption features of the CHF3 molecule at around 8.6 μm with a maximum signal-to-noise ratio of ∼7 × 103 in 10 s integration time, frequency-resolution of 160 kHz, and accuracy of less than 10 kHz.

SPITZER'S MID-INFRARED VIEW ON AN OUTER-GALAXY INFRARED DARK CLOUD CANDIDATE TOWARD NGC 7538

NARCIS (Netherlands)

Frieswijk, W. F.; Spaans, M.; Shipman, R. F.; Teyssier, D.; Carey, S. J.; Tielens, A. G. G. M.

2008-01-01

Infrared dark clouds (IRDCs) represent the earliest observed stages of clustered star formation, characterized by large column densities of cold and dense molecular material observed in silhouette against a bright background of mid-IR emission. Up to now, IRDCs were predominantly known toward the

Spitzer/infrared spectrograph investigation of mipsgal 24 μm compact bubbles: low-resolution observations

Energy Technology Data Exchange (ETDEWEB)

Nowak, M. [Département de Physique, École Normale Supérieure de Cachan, 61 Avenue du Président Wilson, F-94235 Cachan (France); Flagey, N. [Jet Propulsion Laboratory, California Institute of Technology, 4800 Oak Grove Drive, Pasadena, CA 91109 (United States); Noriega-Crespo, A.; Carey, S. J.; Van Dyk, S. D. [Spitzer Science Center, California Institute of Technology, 1200 East California Boulevard, MC 314-6, Pasadena, CA 91125 (United States); Billot, N. [Instituto de Radio Astronomía Milimétrica, Avenida Divina Pastora, 7, Local 20, E-18012 Granada (Spain); Paladini, R., E-mail: mathias.nowak@ens-cachan.fr [NASA Herschel Science Center, California Institute of Technology, Pasadena, CA 91125 (United States)

2014-12-01

We present Spitzer/InfraRed Spectrograph (IRS) low-resolution observations of 11 compact circumstellar bubbles from the MIPSGAL 24 μm Galactic plane survey. We find that this set of MIPSGAL bubbles (MBs) is divided into two categories and that this distinction correlates with the morphologies of the MBs in the mid-infrared (IR). The four MBs with central sources in the mid-IR exhibit dust-rich, low-excitation spectra, and their 24 μm emission is accounted for by the dust continuum. The seven MBs without central sources in the mid-IR have spectra dominated by high-excitation gas lines (e.g., [O IV] 26.0 μm, [Ne V] 14.3 and 24.3 μm, and [Ne III] 15.5 μm), and the [O IV] line accounts for 50% to almost 100% of the 24 μm emission in five of them. In the dust-poor MBs, the [Ne V] and [Ne III] line ratios correspond to high-excitation conditions. Based on comparisons with published IRS spectra, we suggest that the dust-poor MBs are highly excited planetary nebulae (PNs) with peculiar white dwarfs (e.g., Wolf-Rayet [WR] and novae) at their centers. The central stars of the four dust-rich MBs are all massive star candidates. Dust temperatures range from 40 to 100 K in the outer shells. We constrain the extinction along the lines of sight from the IRS spectra. We then derive distance, dust masses, and dust production rate estimates for these objects. These estimates are all consistent with the nature of the central stars. We summarize the identifications of MBs made to date and discuss the correlation between their mid-IR morphologies and natures. Candidate Be/B[e]/luminous blue variable and WR stars are mainly 'rings' with mid-IR central sources, whereas PNs are mostly 'disks' without mid-IR central sources. Therefore we expect that most of the 300 remaining unidentified MBs will be classified as PNs.

Subwavelength engineered fiber-to-chip silicon-on-sapphire interconnects for mid-infrared applications (Conference Presentation)

Science.gov (United States)

Alonso-Ramos, Carlos; Han, Zhaohong; Le Roux, Xavier; Lin, Hongtao; Singh, Vivek; Lin, Pao Tai; Tan, Dawn; Cassan, Eric; Marris-Morini, Delphine; Vivien, Laurent; Wada, Kazumi; Hu, Juejun; Agarwal, Anuradha; Kimerling, Lionel C.

2016-05-01

The mid-Infrared wavelength range (2-20 µm), so-called fingerprint region, contains the very sharp vibrational and rotational resonances of many chemical and biological substances. Thereby, on-chip absorption-spectrometry-based sensors operating in the mid-Infrared (mid-IR) have the potential to perform high-precision, label-free, real-time detection of multiple target molecules within a single sensor, which makes them an ideal technology for the implementation of lab-on-a-chip devices. Benefiting from the great development realized in the telecom field, silicon photonics is poised to deliver ultra-compact efficient and cost-effective devices fabricated at mass scale. In addition, Si is transparent up to 8 µm wavelength, making it an ideal material for the implementation of high-performance mid-IR photonic circuits. The silicon-on-insulator (SOI) technology, typically used in telecom applications, relies on silicon dioxide as bottom insulator. Unfortunately, silicon dioxide absorbs light beyond 3.6 µm, limiting the usability range of the SOI platform for the mid-IR. Silicon-on-sapphire (SOS) has been proposed as an alternative solution that extends the operability region up to 6 µm (sapphire absorption), while providing a high-index contrast. In this context, surface grating couplers have been proved as an efficient means of injecting and extracting light from mid-IR SOS circuits that obviate the need of cleaving sapphire. However, grating couplers typically have a reduced bandwidth, compared with facet coupling solutions such as inverse or sub-wavelength tapers. This feature limits their feasibility for absorption spectroscopy applications that may require monitoring wide wavelength ranges. Interestingly, sub-wavelength engineering can be used to substantially improve grating coupler bandwidth, as demonstrated in devices operating at telecom wavelengths. Here, we report on the development of fiber-to-chip interconnects to ZrF4 optical fibers and integrated SOS

Nimbus-2 High-Resolution Infrared Radiometer (HRIR) Imagery of Cloud Cover at Night on 70 mm Film V001

Data.gov (United States)

National Aeronautics and Space Administration — The HRIRN2IM data product contains scanned negatives of photofacsimile 70mm film strips from the Nimbus-2 High-Resolution Infrared Radiometer. The images contain...

Study of GeSn Alloy for Low Cost Monolithic Mid Infrared Quantum Well Sensor

Directory of Open Access Journals (Sweden)

Prakash PAREEK

2017-02-01

Full Text Available This paper focuses on theoretical study of Tin incorporated group IV alloys particularly GeSn and design of quantum well sensor for mid infrared sensing applications. Initially, the physics behind the selection of material for midinfrared sensor is explained. The importance of controlling strain in GeSn alloy is also explained. The physical background and motivation for incorporation of Tin(Sn in Germanium is briefly narrated. Eigen energy states for different Sn concentrations are obtained for strain compensated quantum well in G valley conduction band (GCB, heavy hole (HH band and light hole (LH band by solving coupled Schrödinger and Poisson equations simultaneously. Sn concentration dependent absorption spectra for HH- GCB transition reveals that significant absorption observed in mid infrared range (3-5 µm. So, Ge1-x Snx quantum well can be used for mid infrared sensing applications.

THE SUBARCSECOND MID-INFRARED VIEW OF LOCAL ACTIVE GALACTIC NUCLEI. III. POLAR DUST EMISSION

International Nuclear Information System (INIS)

Asmus, D.; Hönig, S. F.; Gandhi, P.

2016-01-01

Recent mid-infrared (MIR) interferometric observations have shown that in a few active galactic nuclei (AGNs) the bulk of the infrared emission originates from the polar region above the putative torus, where only a little dust should be present. Here, we investigate whether such strong polar dust emission is common in AGNs. Out of 149 Seyferts in the MIR atlas of local AGNs, 21 show extended MIR emission on single-dish images. In 18 objects, the extended MIR emission aligns with the position angle (PA) of the system axis, established by [O iii], radio, polarization, and maser-based PA measurements. The relative amount of resolved MIR emission is at least 40% and scales with the [O iv] fluxes, implying a strong connection between the extended continuum and [O iv] emitters. These results together with the radio-quiet nature of the Seyferts support the scenario that the bulk of MIR emission is emitted by dust in the polar region and not by the torus, which would demand a new paradigm for the infrared emission structure in AGNs. The current low detection rate of polar dust in the AGNs of the MIR atlas is explained by the lack of sufficient high-quality MIR data and the requirements on the orientation, strength of narrow-line region, and distance of the AGNs. The James Webb Space Telescope will enable much deeper nuclear MIR studies with comparable angular resolution, allowing us to resolve the polar emission and surroundings in most of the nearby AGNs.

Silicon Photonic Waveguides for Near- and Mid-Infrared Regions

Science.gov (United States)

Stankovic, S.; Milosevic, M.; Timotijevic, B.; Yang, P. Y.; Teo, E. J.; Crnjanski, J.; Matavulj, P.; Mashanovich, G. Z.

2007-11-01

The basic building block of every photonic circuit is a waveguide. In this paper we investigate the most popular silicon waveguide structures in the form of a silicon-on-insulator rib waveguide. We also analyse two structures that can find applications in mid- and long-wave infrared regions: free-standing and hollow core omnidirectional waveguides.

HIGH-EFFICIENCY INFRARED RECEIVER

Directory of Open Access Journals (Sweden)

A. K. Esman

2016-01-01

Full Text Available Recent research and development show promising use of high-performance solid-state receivers of the electromagnetic radiation. These receivers are based on the low-barrier Schottky diodes. The approach to the design of the receivers on the basis of delta-doped low-barrier Schottky diodes with beam leads without bias is especially actively developing because for uncooled receivers of the microwave radiation these diodes have virtually no competition. The purpose of this work is to improve the main parameters and characteristics that determine the practical relevance of the receivers of mid-infrared electromagnetic radiation at the operating room temperature by modifying the electrodes configuration of the diode and optimizing the distance between them. Proposed original design solution of the integrated receiver of mid-infrared radiation on the basis of the low-barrier Schottky diodes with beam leads allows to effectively adjust its main parameters and characteristics. Simulation of the electromagnetic characteristics of the proposed receiver by using the software package HFSS with the basic algorithm of a finite element method which implemented to calculate the behavior of electromagnetic fields on an arbitrary geometry with a predetermined material properties have shown that when the inner parts of the electrodes of the low-barrier Schottky diode is performed in the concentric elliptical convex-concave shape, it can be reduce the reflection losses to -57.75 dB and the standing wave ratio to 1.003 while increasing the directivity up to 23 at a wavelength of 6.09 μm. At this time, the rounded radii of the inner parts of the anode and cathode electrodes are equal 212 nm and 318 nm respectively and the gap setting between them is 106 nm. These parameters will improve the efficiency of the developed infrared optical-promising and electronic equipment for various purposes intended for work in the mid-infrared wavelength range. 

Mid-Infrared Silicate Dust Features in Seyfert 1 Spectra

Science.gov (United States)

Thompson, Grant D.; Levenson, N. A.; Sirocky, M. M.; Uddin, S.

2007-12-01

Silicate dust emission dominates the mid-infrared spectra of galaxies, and the dust produces two spectral features, at 10 and 18 μm. These features' strengths (in emission or absorption) and peak wavelengths reveal the geometry of the dust distribution, and they are sensitive to the dust composition. We examine mid-infrared spectra of 32 Seyfert 1 active galactic nuclei (AGN), observed with the Infrared Spectrograph aboard the Spitzer Space Telescope. In the spectra, we typically find the shorter-wavelength feature in emission, at an average peak wavelength of 10.0 μm, although it is known historically as the "9.7 μm" feature. In addition, peak wavelength increases with feature strength. The 10 and 18 μm feature strengths together are sensitive to the dust geometry surrounding the central heating engine. Numerical calculations of radiative transfer distinguish between clumpy and smooth distributions, and we find that the surroundings of these AGN (the obscuring "tori" of unified AGN schemes) are clumpy. Polycyclic aromatic hydrocarbon (PAH) features are associated with star formation, and we find strong PAH emission (luminosity ≥ 1042 erg/s) in only four sources, three of which show independent evidence for starbursts. We will explore the effects of luminosity on dust geometry and chemistry in a comparison sample of quasars. We acknowledge work supported by the NSF under grant number 0237291.

Intercomparison of three microwave/infrared high resolution line-by-line radiative transfer codes

Science.gov (United States)

Schreier, Franz; Milz, Mathias; Buehler, Stefan A.; von Clarmann, Thomas

2018-05-01

An intercomparison of three line-by-line (lbl) codes developed independently for atmospheric radiative transfer and remote sensing - ARTS, GARLIC, and KOPRA - has been performed for a thermal infrared nadir sounding application assuming a HIRS-like (High resolution Infrared Radiation Sounder) setup. Radiances for the 19 HIRS infrared channels and a set of 42 atmospheric profiles from the "Garand dataset" have been computed. The mutual differences of the equivalent brightness temperatures are presented and possible causes of disagreement are discussed. In particular, the impact of path integration schemes and atmospheric layer discretization is assessed. When the continuum absorption contribution is ignored because of the different implementations, residuals are generally in the sub-Kelvin range and smaller than 0.1 K for some window channels (and all atmospheric models and lbl codes). None of the three codes turned out to be perfect for all channels and atmospheres. Remaining discrepancies are attributed to different lbl optimization techniques. Lbl codes seem to have reached a maturity in the implementation of radiative transfer that the choice of the underlying physical models (line shape models, continua etc) becomes increasingly relevant.

Efficient Mid-Infrared Supercontinuum Generation in Tapered Large Mode Area Chalcogenide Photonic Crystal Fibers

DEFF Research Database (Denmark)

Petersen, Christian Rosenberg; Engelsholm, Rasmus Dybbro; Markos, Christos

2017-01-01

Mid-infrared supercontinuum spanning from 1.8-9  μm with an output power of 41.5 mW is demonstrated by pumping tapered large mode area chalcogenide photonic crystal fibers using a 4 μm optical parametric source.......Mid-infrared supercontinuum spanning from 1.8-9  μm with an output power of 41.5 mW is demonstrated by pumping tapered large mode area chalcogenide photonic crystal fibers using a 4 μm optical parametric source....

High resolution radio observations of nuclear and circumnuclear regions of luminous infrared galaxies (LIRGs)

Energy Technology Data Exchange (ETDEWEB)

Alberdi, A; Perez-Torres, M A [Instituto de Astrofisica de Andalucia (IAA, CSIC), PO Box 3004, 18080-Granada (Spain); Colina, L [Instituto de Estructura de la Materia - IEM, CSIC, C, Serrano 115, 28005 Madrid (Spain); Torrelles, J M [Instituto de Ciencias del Espacio (ICE, CSIC) and IEEC, Gran Capita 2-4, 08034 Barcelona (Spain)], E-mail: antxon@iaa.es, E-mail: torres@iaa.es, E-mail: colina@damir.iem.csic.es, E-mail: torrelle@ieec.fcr.es

2008-10-15

High-resolution radio observations of the nuclear region of Luminous and Ultraluminous Infrared Galaxies (ULIRGs) have shown that its radio structure consists of a compact high surface-brightness central radio source immersed in a diffuse low brightness circumnuclear halo. While the central component could be associated with an AGN or compact star-forming regions where radio supernovae are exploding, it is well known that the circumnuclear regions host bursts of star-formation. The studies of radio supernovae can provide essential information about stellar evolution and CSM/ISM properties in regions hidden by dust at optical and IR wavelengths. In this contribution, we show results from radio interferometric observations from NGC 7469, IRAS 18293-3413 and IRAS 17138-1017 where three extremely bright radio supernovae have been found. High-resolution radio observations of these and other LIRGs would allow us to determine the core-collapse supernova rate in them as well as their star-formation rate.

High spatial and spectral resolution measurements of Jupiter's auroral regions using Gemini-North-TEXES

Science.gov (United States)

Sinclair, J. A.; Orton, G. S.; Greathouse, T. K.; Lacy, J.; Giles, R.; Fletcher, L. N.; Vogt, M.; Irwin, P. G.

2017-12-01

Jupiter exhibits auroral emission at a multitude of wavelengths. Auroral emission at X-ray, ultraviolet and near-infrared wavelengths demonstrate the precipitation of ion and electrons in Jupiter's upper atmosphere, at altitudes exceeding 250 km above the 1-bar level. Enhanced mid-infrared emission of CH4, C2H2, C2H4 and further hydrocarbons is also observed coincident with Jupiter's auroral regions. Retrieval analyses of infrared spectra from IRTF-TEXES (Texas Echelon Cross Echelle Spectrograph on NASA's Infrared Telescope Facility) indicate strong heating at the 1-mbar level and evidence of ion-neutral chemistry, which enriches the abundances of unsaturated hydrocarbons (Sinclair et al., 2017b, doi:10.1002/2017GL073529, Sinclair et al., 2017c (under review)). The extent to which these phenomena in the stratosphere are correlated and coupled physically with the shorter-wavelength auroral emission originating from higher altitudes has been a challenge due to the limited spatial resolution available on the IRTF. Smaller-scale features observed in the near-infrared and ultraviolet emission, such as the main `oval', transient `swirls' and dusk-active regions within the main oval (e.g. Stallard et al., 2014, doi:10.1016/j/Icarus.2015.12.044, Nichols et al., 2017, doi: 10.1002/2017GL073029) are potentially being blurred in the mid-infrared by the diffraction-limited resolution (0.7") of IRTF's 3-metre primary aperture. However, on March 17-19th 2017, we obtained spectral measurements of H2 S(1), CH4, C2H2, C2H4 and C2H6 emission of Jupiter's high latitudes using TEXES on Gemini-North, which has a 8-metre primary aperture. This rare opportunity combines the superior spectral resolving power of TEXES and the high spatial resolution provided by Gemini-North's 8-metre aperture. We will perform a retrieval analyses to determine the 3D distributions of temperature, C2H2, C2H4 and C2H6. The morphology will be compared with near-contemporaneous measurements of H3+ emission from

THE CONTRIBUTION OF TP-AGB STARS TO THE MID-INFRARED COLORS OF NEARBY GALAXIES

International Nuclear Information System (INIS)

Chisari, Nora E.; Kelson, Daniel D.

2012-01-01

We study the mid-infrared color space of 30 galaxies from the Spitzer Infrared Nearby Galaxies Survey (SINGS) survey for which Sloan Digital Sky Survey data are also available. We construct two-color maps for each galaxy and compare them to results obtained from combining Maraston evolutionary synthesis models, galactic thermally pulsating asymptotic giant branch (TP-AGB) colors, and smooth star formation histories. For most of the SINGS sample, the spatially extended mid-IR emission seen by Spitzer in normal galaxies is consistent with our simple model in which circumstellar dust from TP-AGB stars dominates at 8 and 24 μm. There is a handful of exceptions that we identify as galaxies that have high star formation rates presumably with star formation histories that cannot be assumed to be smooth, or anemic galaxies, which were depleted of their H I at some point during their evolution and have very low ongoing star formation rates.

THE CONTRIBUTION OF TP-AGB STARS TO THE MID-INFRARED COLORS OF NEARBY GALAXIES

Energy Technology Data Exchange (ETDEWEB)

Chisari, Nora E. [Department of Astrophysical Sciences, Princeton University, 4 Ivy Lane, Princeton, NJ 08544 (United States); Kelson, Daniel D., E-mail: nchisari@astro.princeton.edu [Observatories of the Carnegie Institution of Science, 813 Santa Barbara St., Pasadena, CA 91101 (United States)

2012-07-10

We study the mid-infrared color space of 30 galaxies from the Spitzer Infrared Nearby Galaxies Survey (SINGS) survey for which Sloan Digital Sky Survey data are also available. We construct two-color maps for each galaxy and compare them to results obtained from combining Maraston evolutionary synthesis models, galactic thermally pulsating asymptotic giant branch (TP-AGB) colors, and smooth star formation histories. For most of the SINGS sample, the spatially extended mid-IR emission seen by Spitzer in normal galaxies is consistent with our simple model in which circumstellar dust from TP-AGB stars dominates at 8 and 24 {mu}m. There is a handful of exceptions that we identify as galaxies that have high star formation rates presumably with star formation histories that cannot be assumed to be smooth, or anemic galaxies, which were depleted of their H I at some point during their evolution and have very low ongoing star formation rates.

Optical Activation of Germanium Plasmonic Antennas in the Mid-Infrared

Science.gov (United States)

Fischer, Marco P.; Schmidt, Christian; Sakat, Emilie; Stock, Johannes; Samarelli, Antonio; Frigerio, Jacopo; Ortolani, Michele; Paul, Douglas J.; Isella, Giovanni; Leitenstorfer, Alfred; Biagioni, Paolo; Brida, Daniele

2016-07-01

Impulsive interband excitation with femtosecond near-infrared pulses establishes a plasma response in intrinsic germanium structures fabricated on a silicon substrate. This direct approach activates the plasmonic resonance of the Ge structures and enables their use as optical antennas up to the mid-infrared spectral range. The optical switching lasts for hundreds of picoseconds until charge recombination redshifts the plasma frequency. The full behavior of the structures is modeled by the electrodynamic response established by an electron-hole plasma in a regular array of antennas.

Mid-Infrared Sensing of Organic Pollutants in Aqueous Environments

Directory of Open Access Journals (Sweden)

Andrew Ross

2009-08-01

Full Text Available The development of chemical sensors for monitoring the levels of organic pollutants in the aquatic environment has received a great deal of attention in recent decades. In particular, the mid-infrared (MIR sensor based on attenuated total reflectance (ATR is a promising analytical tool that has been used to detect a variety of hydrocarbon compounds (i.e., aromatics, alkyl halides, phenols, etc. dissolved in water. It has been shown that under certain conditions the MIR-ATR sensor is capable of achieving detection limits in the 10-100 ppb concentration range. Since the infrared spectral features of every single organic molecule are unique, the sensor is highly selective, making it possible to distinguish between many different analytes simultaneously. This review paper discusses some of the parameters (i.e., membrane type, film thickness, conditioning that dictate MIR ATR sensor response. The performance of various chemoselective membranes which are used in the fabrication of the sensor will be evaluated. Some of the challenges associated with long-term environmental monitoring are also discussed.

Mid-Infrared Sensing of Organic Pollutants in Aqueous Environments

Science.gov (United States)

Pejcic, Bobby; Myers, Matthew; Ross, Andrew

2009-01-01

The development of chemical sensors for monitoring the levels of organic pollutants in the aquatic environment has received a great deal of attention in recent decades. In particular, the mid-infrared (MIR) sensor based on attenuated total reflectance (ATR) is a promising analytical tool that has been used to detect a variety of hydrocarbon compounds (i.e., aromatics, alkyl halides, phenols, etc.) dissolved in water. It has been shown that under certain conditions the MIR-ATR sensor is capable of achieving detection limits in the 10–100 ppb concentration range. Since the infrared spectral features of every single organic molecule are unique, the sensor is highly selective, making it possible to distinguish between many different analytes simultaneously. This review paper discusses some of the parameters (i.e., membrane type, film thickness, conditioning) that dictate MIR-ATR sensor response. The performance of various chemoselective membranes which are used in the fabrication of the sensor will be evaluated. Some of the challenges associated with long-term environmental monitoring are also discussed. PMID:22454582

Mid-Infrared Interferometry on Spectral Lines. II. Continuum (Dust) Emission Around IRC +10216 and VY Canis Majoris

Science.gov (United States)

Monnier, J. D.; Danchi, W. C.; Hale, D. S.; Lipman, E. A.; Tuthill, P. G.; Townes, C. H.

2000-11-01

The University of California Berkeley Infrared Spatial Interferometer has measured the mid-infrared visibilities of the carbon star IRC +10216 and the red supergiant VY CMa. The dust shells around these sources have been previously shown to be time variable, and these new data are used to probe the evolution of the dust shells on a decade timescale, complementing contemporaneous studies at other wavelengths. Self-consistent, spherically symmetric models at maximum and minimum light both show the inner radius of the IRC +10216 dust shell to be much larger (150 mas) than expected from the dust-condensation temperature, implying that dust production has slowed or stopped in recent years. Apparently, dust does not form every pulsational cycle (638 days), and these mid-infrared results are consistent with recent near-infrared imaging, which indicates little or no new dust production in the last 3 yr. Spherically symmetric models failed to fit recent VY CMa data, implying that emission from the inner dust shell is highly asymmetric and/or time variable.

Mid-infrared pulsed laser ultrasonic testing for carbon fiber reinforced plastics.

Science.gov (United States)

Kusano, Masahiro; Hatano, Hideki; Watanabe, Makoto; Takekawa, Shunji; Yamawaki, Hisashi; Oguchi, Kanae; Enoki, Manabu

2018-03-01

Laser ultrasonic testing (LUT) can realize contactless and instantaneous non-destructive testing, but its signal-to-noise ratio must be improved in order to measure carbon fiber reinforced plastics (CFRPs). We have developed a mid-infrared (mid-IR) laser source optimal for generating ultrasonic waves in CFRPs by using a wavelength conversion device based on an optical parametric oscillator. This paper reports a comparison of the ultrasonic generation behavior between the mid-IR laser and the Nd:YAG laser. The mid-IR laser generated a significantly larger ultrasonic amplitude in CFRP laminates than a conventional Nd:YAG laser. In addition, our study revealed that the surface epoxy matrix of CFRPs plays an important role in laser ultrasonic generation. Copyright © 2017 Elsevier B.V. All rights reserved.

Embedded clusters in NGC1808 central starburst - Near-infrared imaging and spectroscopy

OpenAIRE

Galliano, E.; Alloin, D.

2008-01-01

In the course of a mid-infrared imaging campaign of close-by active galaxies, we discovered the mid-infrared counterparts of bright compact radio sources in the central star-forming region of NGC1808. We aim at confirming that these sources are deeply embedded, young star clusters and at deriving some of their intrinsic properties. To complement the mid-infrared data, we have collected a set of near-infrared data with ISAAC at the VLT: J, Ks, and L' images, as well as low-resolution, long-sli...

Mid-Infrared Observations of the White Dwarf Brown Dwarf Binary GD 1400

OpenAIRE

Farihi, J.; Zuckerman, B.; Becklin, E. E.

2005-01-01

Fluxes are measured for the DA white dwarf plus brown dwarf pair GD 1400 with the Infrared Array Camera on the {\\em Spitzer Space Telescope}. GD 1400 displays an infrared excess over the entire $3-8\\mu$m region consistent with the presence of a mid- to late-type L dwarf companion. A discussion is given regarding current knowledge of this unique system.

Luminescence from ZnSe excited by picosecond mid-infrared FEL pulses

International Nuclear Information System (INIS)

Mitsuyu, T.; Suzuki, T.; Tomimasu, T.

1998-01-01

We have observed blue band-edge emission from a ZnSe crystal under irradiation of mid-infrared picosecond free electron laser (FEL) pulses. The emission characteristics including spectrum, excitation power dependence, excitation wavelength dependence, and decay time have been investigated. The experimental results have indicated that it is difficult to understand the excitation process by multiphoton excitation, thermal excitation, or excitation through mid-gap levels. (Copyright (c) 1998 Elsevier Science B.V., Amsterdam. All rights reserved.)

Athermal design for mid-wave infrared lens with long EFFL

Science.gov (United States)

Bai, Yu; Xing, Tingwen

2016-10-01

When the environment temperature has changed, then each parameter in infrared lens has also changed, thus the image quality became bad, so athermal technology is one of key technology in designing infrared lens. The temperature influence of each parameter in infrared lens is analyzed in the paper. In the paper, an athermal mid-wave infrared optical system with long focal length by Code-v optical design software was presented. The parameters of the athermal infrared system are 4.0 f/number, 704mm effective focal length (EFL) , 1° field of view and 3.7-4.8 μm spectrum region 100% cold shield efficiency. When the spatial frequency is 16lp/mm, the Modulation Transfer Function (MTF) of all the field of view was above 0.5 from the working temperature range -40° to 60°. From the image quality and thermal analysis result, we knew that the lens had good athermal performance.

Innovative mid-infrared detector concepts

Science.gov (United States)

Höfling, Sven; Pfenning, Andreas; Weih, Robert; Ratajczak, Albert; Hartmann, Fabian; Knebl, Georg; Kamp, Martin; Worschech, Lukas

2016-09-01

Gas sensing is a key technology with applications in various industrial, medical and environmental areas. Optical detection mechanisms allow for a highly selective, contactless and fast detection. For this purpose, rotational-vibrational absorption bands within the mid infrared (MIR) spectral region are exploited and probed with appropriate light sources. During the past years, the development of novel laser concepts such as interband cascade lasers (ICLs) and quantum cascade lasers (QCLs) has driven a continuous optimization of MIR laser sources. On the other hand side, there has been relatively little progress on detectors in this wavelength range. Here, we study two novel and promising GaSb-based detector concepts: Interband cascade detectors (ICD) and resonant tunneling diode (RTD) photodetectors. ICDs are a promising approach towards highly sensitive room temperature detection of MIR radiation. They make use of the cascading scheme that is enabled by the broken gap alignment of the two binaries GaSb and InAs. The interband transition in GaSb/InAs-superlattices (SL) allows for normal incidence detection. The cut-off wavelength, which determines the low energy detection limit, can be engineered via the SL period. RTD photodetectors act as low noise and high speed amplifiers of small optically generated electrical signals. In contrast to avalanche photodiodes, where the gain originates from multiplication due to impact ionization, in RTD photodetectors a large tunneling current is modulated via Coulomb interaction by the presence of photogenerated minority charge carriers. For both detector concepts, first devices operational at room temperature have been realized.

Near Infrared Microspectroscopy, Fluorescence Microspectroscopy, Infrared Chemical Imaging and High Resolution Nuclear Magnetic Resonance Analysis of Soybean Seeds, Somatic Embryos and Single Cells

CERN Document Server

Baianu, I C; Hofmann, N E; Korban, S S; Lozano, P; You, T; AOCS 94th Meeting, Kansas

2002-01-01

Novel methodologies are currently being developed and established for the chemical analysis of soybean seeds, embryos and single cells by Fourier Transform Infrared (FT-IR), Fourier Transform Near Infrared (FT-NIR) Microspectroscopy, Fluorescence and High-Resolution NMR (HR-NMR). The first FT-NIR chemical images of biological systems approaching one micron resolution are presented here. Chemical images obtained by FT-NIR and FT-IR Microspectroscopy are presented for oil in soybean seeds and somatic embryos under physiological conditions. FT-NIR spectra of oil and proteins were obtained for volumes as small as two cubic microns. Related, HR-NMR analyses of oil contents in somatic embryos are also presented here with nanoliter precision. Such 400 MHz 1H NMR analyses allowed the selection of mutagenized embryos with higher oil content (e.g. ~20%) compared to non-mutagenized control embryos. Moreover, developmental changes in single soybean seeds and/or somatic embryos may be monitored by FT-NIR with a precision ...

A Tunable Mid-Infrared Solid-State Laser with a Compact Thermal Control System

Directory of Open Access Journals (Sweden)

Deyang Yu

2018-05-01

Full Text Available Tunable mid-infrared lasers are widely used in laser spectroscopy, gas sensing and many other related areas. In order to solve heat dissipation problems and improve the environmental temperature adaptability of solid-state laser sources, a tunable all-fiber laser pumped optical parametric oscillator (OPO was established, and a compact thermal control system based on thermoelectric coolers, an automatic temperature control circuit, cooling fins, fans and heat pipes was integrated and designed for the laser. This system is compact, light and air-cooling which satisfies the demand for miniaturization of lasers. A mathematical model and method was established to estimate the cooling capacity of this thermal control system under different ambient environments. A finite-element model was built and simulated to analyze the thermal transfer process. Experiments in room and high temperature environments were carried out and showed that the substrate temperature of a pump module could be maintained at a stable value with controlled precision to 0.2 degrees, while the output power stability of the laser was within ±1%. The experimental results indicate that this compact air-cooling thermal control system could effectively solve the heat dissipation problem of mid-infrared solid-state lasers with a one hundred watts level pump module in room and high temperature environments.

Optimum output coupling for a mid-infrared KTiOAsO4 optical parametric oscillator

International Nuclear Information System (INIS)

Li, Guochao; Gao, Yesheng; Zheng, Guangjin; Zhao, Yao; Chen, Kunfeng; Wang, Qingpu; Bai, Fen

2013-01-01

Taking into account the turn off time of the Q-switch, the coupled equations for a mid-infrared KTiOAsO 4 optical parametric oscillator (OPO) are given. These rate equations are solved numerically and some key parameters for designing the laser system are determined. The key parameters include the optimal coupling and nonlinear crystal length which maximize the output power and OPO conversion efficiency. We found that a low-loss singly resonant OPO cavity not only enhances the mid-infrared output but also decreases the optimal OPO crystal length. (paper)

Silicon Nitride Photonic Integration Platforms for Visible, Near-Infrared and Mid-Infrared Applications

Science.gov (United States)

Micó, Gloria; Pastor, Daniel; Pérez, Daniel; Doménech, José David; Fernández, Juan; Baños, Rocío; Alemany, Rubén; Sánchez, Ana M.; Cirera, Josep M.; Mas, Roser

2017-01-01

Silicon nitride photonics is on the rise owing to the broadband nature of the material, allowing applications of biophotonics, tele/datacom, optical signal processing and sensing, from visible, through near to mid-infrared wavelengths. In this paper, a review of the state of the art of silicon nitride strip waveguide platforms is provided, alongside the experimental results on the development of a versatile 300 nm guiding film height silicon nitride platform. PMID:28895906

An In-Depth Look At the Lunar Crater Copernicus: Exposed Mineralogy by High-Resolution Near-Infrared Spectroscopy

OpenAIRE

2011-01-01

Abstract Highlights ?We present an in-depth study of Copernicus crater. ? First publication based on new NIR data from the SIR-2 mission to the Moon. ? New NIR spectral classification of surface materials within the crater. ? Highly detailed mapping of spectrally-prominent mineral species. Abstract Newly acquired, sequentially spaced, high resolution near-infrared spectra across the central section of crater Copernicus? interior have been analysed using a r...

Megapixel Longwave Infrared SLS FPAs for High Spatial Resolution Earth Observing Missions, Phase I

Data.gov (United States)

National Aeronautics and Space Administration — Earth observing missions like NASA's LANDSAT Data Continuity Mission - Thermal Infrared Sensor (LDCM-TIRS) require greater spatial resolution of the earth than the ~...

Megapixel Longwave Infrared SLS FPAs for High Spatial Resolution Earth Observing Missions, Phase II

Data.gov (United States)

National Aeronautics and Space Administration — Earth observing missions like NASA's LANDSAT Data Continuity Mission - Thermal Infrared Sensor (LDCM-TIRS) require greater spatial resolution of the earth than the ~...

Generation and application of ultrashort coherent mid-infrared electromagnetic radiation

Science.gov (United States)

Wandel, Scott

Particle accelerators are useful instruments that help address critical issues for the future development of nuclear energy. Current state-of-the-art accelerators based on conventional radio-frequency (rf) cavities are too large and expensive for widespread commercial use, and alternative designs must be considered for supplying relativistic beams to small-scale applications, including medical imaging, secu- rity screening, and scientific research in a university-scale laboratory. Laser-driven acceleration using micro-fabricated dielectric photonic structures is an attractive approach because such photonic microstructures can support accelerating fields that are 10 to 100 times higher than that of rf cavity-based accelerators. Dielectric laser accelerators (DLAs) use commercial lasers as a driving source, which are smaller and less expensive than the klystrons used to drive current rf-based accelerators. Despite the apparent need for compact and economical laser sources for laser-driven acceleration, the availability of suitable high-peak-power lasers that cover a broad spectral range is currently limited. To address the needs of several innovative acceleration mechanisms like DLA, it is proposed to develop a coherent source of mid-infrared (IR) electromagnetic radiation that can be implemented as a driving source of laser accelerators. The use of ultrashort mid-IR high peak power laser systems in various laser-driven acceleration schemes has shown the potential to greatly reduce the optical pump intensities needed to realize high acceleration gradients. The optical intensity needed to achieve a given ponderomotive potential is 25 times less when using a 5-mum mid-IR laser as compared to using a 1-mum near-IR solid-state laser. In addition, dielectric structure breakdown caused by multiphoton ionization can be avoided by using longer-wavelength driving lasers. Current mid-IR laser sources do not produce sufficiently short pulse durations, broad spectral bandwidths

Wireless Mid-Infrared Spectroscopy Sensor Network for Automatic Carbon Dioxide Fertilization in a Greenhouse Environment

Directory of Open Access Journals (Sweden)

Jianing Wang

2016-11-01

Full Text Available In this paper, a wireless mid-infrared spectroscopy sensor network was designed and implemented for carbon dioxide fertilization in a greenhouse environment. A mid-infrared carbon dioxide (CO2 sensor based on non-dispersive infrared (NDIR with the functionalities of wireless communication and anti-condensation prevention was realized as the sensor node. Smart transmission power regulation was applied in the wireless sensor network, according to the Received Signal Strength Indication (RSSI, to realize high communication stability and low-power consumption deployment. Besides real-time monitoring, this system also provides a CO2 control facility for manual and automatic control through a LabVIEW platform. According to simulations and field tests, the implemented sensor node has a satisfying anti-condensation ability and reliable measurement performance on CO2 concentrations ranging from 30 ppm to 5000 ppm. As an application, based on the Fuzzy proportional, integral, and derivative (PID algorithm realized on a LabVIEW platform, the CO2 concentration was regulated to some desired concentrations, such as 800 ppm and 1200 ppm, in 30 min with a controlled fluctuation of <±35 ppm in an acre of greenhouse.

Analysis of energy transfer process based emission spectra of erbium doped germanate glasses for mid-infrared laser materials

International Nuclear Information System (INIS)

Cai, Muzhi; Wei, Tao; Zhou, Beier; Tian, Ying; Zhou, Jiajia; Xu, Shiqing; Zhang, Junjie

2015-01-01

Highlights: • Er 3+ doped germanate glass with good thermal stability were prepared. • Ionic boding nature was proved by bonding parameter calculation. • Mid-infrared fluorescent behaviors and energy transfer were investigated. • Rate equation and Dexter’s theory were utilized to elucidate 2.7 μm emission. - Abstract: Er 3+ activated germanate glass with good thermal stability was prepared. Bonding parameters have been calculated and the nature of ionic bonding of the germanate glass has been determined. Mid-infrared fluorescence was observed and corresponding radiative properties were investigated. For Er 3+ : 4 I 11/2 → 4 I 13/2 transition, high spontaneous radiative transition probability (30.09 s −1 ), large emission cross section ((14.84 ± 0.10) × 10 −21 cm 2 ) and superior gain performance were obtained from the prepared glass. Besides, energy transfer processes concerning the 2.7 μm emission were also discussed in detail. According to simplified rate equation and Dexter’s theory, energy transfer microscopic parameters were computed to elucidate observed 2.7 μm emissions. Results demonstrate that the prepared germanate glass possessing excellent spectroscopic properties might be an attractive candidate for mid-infrared laser or amplifier

Wide-field Spatio-Spectral Interferometry: Bringing High Resolution to the Far- Infrared

Science.gov (United States)

Leisawitx, David

Wide-field spatio-spectral interferometry combines spatial and spectral interferometric data to provide integral field spectroscopic information over a wide field of view. This technology breaks through a mission cost barrier that stands in the way of resolving spatially and measuring spectroscopically at far-infrared wavelengths objects that will lead to a deep understanding of planetary system and galaxy formation processes. A space-based far-IR interferometer will combine Spitzer s superb sensitivity with a two order of magnitude gain in angular resolution, and with spectral resolution in the thousands. With the possible exception of detector technology, which is advancing with support from other research programs, the greatest challenge for far-IR interferometry is to demonstrate that the interferometer will actually produce the images and spectra needed to satisfy mission science requirements. With past APRA support, our team has already developed the highly specialized hardware testbed, image projector, computational model, and image construction software required for the proposed effort, and we have access to an ideal test facility.

Spectral-temporal composition matters when cascading supercontinua into the mid-infrared

DEFF Research Database (Denmark)

Petersen, Christian Rosenberg; Moselund, Peter M.; Petersen, Christian

2016-01-01

Supercontinuum generation in chalcogenide fibers is a promising technology for broadband spatially coherent sources in the mid-infrared, but it suffers from discouraging commercial prospects, mainly due to a lack of suitable pump lasers. Here, a promising approach is experimentally demonstrated u...

Rugged and compact mid-infrared solid-state laser for avionics applications

CSIR Research Space (South Africa)

Esser, MJD

2009-11-01

Full Text Available In order to demonstrate the feasibility of a helicopter-based application using advanced laser technology, the authors have developed a rugged and compact mid-infrared solid-state laser. The requirement for the laser was to simultaneously emit at 2...

RESOLVING THE ACTIVE GALACTIC NUCLEUS AND HOST EMISSION IN THE MID-INFRARED USING A MODEL-INDEPENDENT SPECTRAL DECOMPOSITION

Energy Technology Data Exchange (ETDEWEB)

Hernán-Caballero, Antonio; Alonso-Herrero, Almudena [Instituto de Física de Cantabria, CSIC-UC, Avenida de los Castros s/n, E-39005, Santander (Spain); Hatziminaoglou, Evanthia [European Southern Observatory, Karl-Schwarzschild-Strasse 2, D-85748 Garching bei München (Germany); Spoon, Henrik W. W. [Cornell University, CRSR, Space Sciences Building, Ithaca, NY 14853 (United States); Almeida, Cristina Ramos [Instituto de Astrofísica de Canarias, Vía Láctea s/n, E-38205 La Laguna, Tenerife (Spain); Santos, Tanio Díaz [Núcleo de Astronomía de la Facultad de Ingeniería, Universidad Diego Portales, Av. Ejército Libertador 441, Santiago (Chile); Hönig, Sebastian F. [School of Physics and Astronomy, University of Southampton, Southampton SO18 1BJ (United Kingdom); González-Martín, Omaira [Centro de Radioastronomía y Astrofísica (CRyA-UNAM), 3-72 (Xangari), 8701, Morelia (Mexico); Esquej, Pilar, E-mail: ahernan@ifca.unican.es [Departamento de Astrofísica, Facultad de CC. Físicas, Universidad Complutense de Madrid, E-28040 Madrid (Spain)

2015-04-20

We present results on the spectral decomposition of 118 Spitzer Infrared Spectrograph (IRS) spectra from local active galactic nuclei (AGNs) using a large set of Spitzer/IRS spectra as templates. The templates are themselves IRS spectra from extreme cases where a single physical component (stellar, interstellar, or AGN) completely dominates the integrated mid-infrared emission. We show that a linear combination of one template for each physical component reproduces the observed IRS spectra of AGN hosts with unprecedented fidelity for a template fitting method with no need to model extinction separately. We use full probability distribution functions to estimate expectation values and uncertainties for observables, and find that the decomposition results are robust against degeneracies. Furthermore, we compare the AGN spectra derived from the spectral decomposition with sub-arcsecond resolution nuclear photometry and spectroscopy from ground-based observations. We find that the AGN component derived from the decomposition closely matches the nuclear spectrum with a 1σ dispersion of 0.12 dex in luminosity and typical uncertainties of ∼0.19 in the spectral index and ∼0.1 in the silicate strength. We conclude that the emission from the host galaxy can be reliably removed from the IRS spectra of AGNs. This allows for unbiased studies of the AGN emission in intermediate- and high-redshift galaxies—currently inaccesible to ground-based observations—with archival Spitzer/IRS data and in the future with the Mid-InfraRed Instrument of the James Webb Space Telescope. The decomposition code and templates are available at http://denebola.org/ahc/deblendIRS.

Mid-Infrared Continuously Tunable Single Mode VECSEL

Science.gov (United States)

Khiar, A.; Rahim, M.; Felder, F.; Fill, M.; Zogg, H.

2011-12-01

Tunable mid-infrared vertical external cavity surface emitting lasers were developed for the wavelength range around 3.8-3.9 μm and 3.2-3.3 μm, respectively. The devices are based on lead salt materials epitaxially grown by MBE on a Si substrate. The active part consists of PbSe QW in a PbSrSe host layer. Both devices are operated around -20 °C and have output power of several 10 mW. By changing the cavity length, a single mode hop free tuning range up to 80 cm-1 is achieved.

Central Stars of Mid-Infrared Nebulae Discovered with Spitzer and WISE

Science.gov (United States)

Gvaramadze, V. V.; Kniazev, A. Y.

2017-02-01

Searches for compact mid-IR nebulae with the Spitzer Space Telescope and the Wide-field Infrared Survey Explorer (WISE), accompanied by spectroscopic observations of central stars of these nebulae led to the discovery of many dozens of massive stars at different evolutionary stages, of which the most numerous are candidate luminous blue variables (LBVs). In this paper, we give a census of candidate and confirmed Galactic LBVs revealed with Spitzer and WISE, and present some new results of spectroscopic observations of central stars of mid-IR nebulae.

Mid-infrared optical parametric oscillator pumped by an amplified random fiber laser

Science.gov (United States)

Shang, Yaping; Shen, Meili; Wang, Peng; Li, Xiao; Xu, Xiaojun

2017-01-01

Recently, the concept of random fiber lasers has attracted a great deal of attention for its feature to generate incoherent light without a traditional laser resonator, which is free of mode competition and insure the stationary narrow-band continuous modeless spectrum. In this Letter, we reported the first, to the best of our knowledge, optical parametric oscillator (OPO) pumped by an amplified 1070 nm random fiber laser (RFL), in order to generate stationary mid-infrared (mid-IR) laser. The experiment realized a watt-level laser output in the mid-IR range and operated relatively stable. The use of the RFL seed source allowed us to take advantage of its respective stable time-domain characteristics. The beam profile, spectrum and time-domain properties of the signal light were measured to analyze the process of frequency down-conversion process under this new pumping condition. The results suggested that the near-infrared (near-IR) signal light `inherited' good beam performances from the pump light. Those would be benefit for further develop about optical parametric process based on different pumping circumstances.

High power frequency comb based on mid-infrared quantum cascade laser at λ ∼ 9 μm

International Nuclear Information System (INIS)

Lu, Q. Y.; Razeghi, M.; Slivken, S.; Bandyopadhyay, N.; Bai, Y.; Zhou, W. J.; Chen, M.; Heydari, D.; Haddadi, A.; McClintock, R.; Amanti, M.; Sirtori, C.

2015-01-01

We investigate a frequency comb source based on a mid-infrared quantum cascade laser at λ ∼ 9 μm with high power output. A broad flat-top gain with near-zero group velocity dispersion has been engineered using a dual-core active region structure. This favors the locking of the dispersed Fabry-Pérot modes into equally spaced frequency lines via four wave mixing. A current range with a narrow intermode beating linewidth of 3 kHz is identified with a fast detector and spectrum analyzer. This range corresponds to a broad spectral coverage of 65 cm −1 and a high power output of 180 mW for ∼176 comb modes

Extending pure luminosity evolution models into the mid-infrared, far-infrared and submillimetre

Science.gov (United States)

Hill, Michael D.; Shanks, Tom

2011-07-01

Simple pure luminosity evolution (PLE) models, in which galaxies brighten at high redshift due to increased star formation rates (SFRs), are known to provide a good fit to the colours and number counts of galaxies throughout the optical and near-infrared. We show that optically defined PLE models, where dust reradiates absorbed optical light into infrared spectra composed of local galaxy templates, fit galaxy counts and colours out to 8 μm and to at least z≈ 2.5. At 24-70 μm, the model is able to reproduce the observed source counts with reasonable success if 16 per cent of spiral galaxies show an excess in mid-IR flux due to a warmer dust component and a higher SFR, in line with observations of local starburst galaxies. There remains an underprediction of the number of faint-flux, high-z sources at 24 μm, so we explore how the evolution may be altered to correct this. At 160 μm and longer wavelengths, the model fails, with our model of normal galaxies accounting for only a few percent of sources in these bands. However, we show that a PLE model of obscured AGN, which we have previously shown to give a good fit to observations at 850 μm, also provides a reasonable fit to the Herschel/BLAST number counts and redshift distributions at 250-500 μm. In the context of a ΛCDM cosmology, an AGN contribution at 250-870 μm would remove the need to invoke a top-heavy IMF for high-redshift starburst galaxies.

Mid-infrared GaSb-based resonant tunneling diode photodetectors for gas sensing applications

Science.gov (United States)

Rothmayr, F.; Pfenning, A.; Kistner, C.; Koeth, J.; Knebl, G.; Schade, A.; Krueger, S.; Worschech, L.; Hartmann, F.; Höfling, S.

2018-04-01

We present resonant tunneling diode-photodetectors (RTD-PDs) with GaAs0.15Sb0.85/AlAs0.1Sb0.9 double barrier structures combined with an additional quaternary Ga0.64In0.36As0.33Sb0.67 absorption layer covering the fingerprint absorption lines of various gases in the mid-infrared wavelength spectral region. The absorption layer cut-off wavelength is determined to be 3.5 μm, and the RTD-PDs show peak-to-valley current ratios up to 4.3 with a peak current density of 12 A/cm-2. The incorporation of the quaternary absorption layer enables the RTD-PDs to be sensitive to illumination with light up to the absorption lines of HCl at 3395 nm. At this wavelength, the detector shows a responsivity of 6.3 mA/W. At the absorption lines of CO2 and CO at 2004 nm and 2330 nm, respectively, the RTD-PDs reach responsivities up to 0.97 A/W. Thus, RTD-PDs pave the way towards high sensitive mid-infrared detectors that can be utilized in tunable laser absorption spectroscopy.

Mid-Infrared Observations of Possible Intergalactic Star Forming Regions in the Leo Ring

Science.gov (United States)

Giroux, Mark; Smith, B.; Struck, C.

2011-05-01

Within the Leo group of galaxies lies a gigantic loop of intergalactic gas known as the Leo Ring. Not clearly associated with any particular galaxy, its origin remains uncertain. It may be a primordial intergalactic cloud alternatively, it may be a collision ring, or have a tidal origin. Combining archival Spitzer images of this structure with published UV and optical data, we investigate the mid-infrared properties of possible knots of star formation in the ring. These sources are very faint in the mid-infrared compared to star forming regions in the tidal features of interacting galaxies. This suggests they are either deficient in dust, or they may not be associated with the ring.

BRIGHTNESS AND FLUCTUATION OF THE MID-INFRARED SKY FROM AKARI OBSERVATIONS TOWARD THE NORTH ECLIPTIC POLE

International Nuclear Information System (INIS)

Pyo, Jeonghyun; Jeong, Woong-Seob; Matsumoto, Toshio; Matsuura, Shuji

2012-01-01

We present the smoothness of the mid-infrared sky from observations by the Japanese infrared astronomical satellite AKARI. AKARI monitored the north ecliptic pole (NEP) during its cold phase with nine wave bands covering from 2.4 to 24 μm, out of which six mid-infrared bands were used in this study. We applied power-spectrum analysis to the images in order to search for the fluctuation of the sky brightness. Observed fluctuation is explained by fluctuation of photon noise, shot noise of faint sources, and Galactic cirrus. The fluctuations at a few arcminutes scales at short mid-infrared wavelengths (7, 9, and 11 μm) are largely caused by the diffuse Galactic light of the interstellar dust cirrus. At long mid-infrared wavelengths (15, 18, and 24 μm), photon noise is the dominant source of fluctuation over the scale from arcseconds to a few arcminutes. The residual fluctuation amplitude at 200'' after removing these contributions is at most 1.04 ± 0.23 nW m –2 sr –1 or 0.05% of the brightness at 24 μm and at least 0.47 ± 0.14 nW m –2 sr –1 or 0.02% at 18 μm. We conclude that the upper limit of the fluctuation in the zodiacal light toward the NEP is 0.03% of the sky brightness, taking 2σ error into account.

THE MID-INFRARED AND NEAR-ULTRAVIOLET EXCESS EMISSIONS OF QUIESCENT GALAXIES ON THE RED SEQUENCE

International Nuclear Information System (INIS)

Ko, Jongwan; Lee, Jong Chul; Hwang, Ho Seong; Sohn, Young-Jong

2013-01-01

We study the mid-infrared (IR) and near-ultraviolet (UV) excess emissions of spectroscopically selected quiescent galaxies on the optical red sequence. We use the Wide-field Infrared Survey Explorer mid-IR and Galaxy Evolution Explorer near-UV data for a spectroscopic sample of galaxies in the Sloan Digital Sky Survey Data Release 7 to study the possible connection between quiescent red-sequence galaxies with and without mid-IR/near-UV excess. Among 648 12 μm detected quiescent red-sequence galaxies without Hα emission, 26% and 55% show near-UV and mid-IR excess emissions, respectively. When we consider only bright (M r n 4000 than those without mid-IR and near-UV excess emissions. We also find that mid-IR weighted mean stellar ages of quiescent red-sequence galaxies with mid-IR excess are larger than those with near-UV excess, and smaller than those without mid-IR and near-UV excess. The environmental dependence of the fraction of quiescent red-sequence galaxies with mid-IR and near-UV excess seems strong even though the trends of quiescent red-sequence galaxies with near-UV excess differ from those with mid-IR excess. These results indicate that the recent star formation traced by near-UV (∼< 1 Gyr) and mid-IR (∼< 2 Gyr) excess is not negligible among nearby, quiescent, red, early-type galaxies. We suggest a possible evolutionary scenario of quiescent red-sequence galaxies from quiescent red-sequence galaxies with near-UV excess to those with mid-IR excess to those without near-UV and mid-IR excess.

Mid-infrared nonlinear upconversion imaging and sensing

DEFF Research Database (Denmark)

Pedersen, Christian; Tidemand-Lichtenberg, Peter

2016-01-01

The mid-IR wavelength range is highly relevant for a number of applications related to gas spectroscopy and spectral analysis of complex molecules such as those including CH bounds. The main obstacles for exploitation of mid-IR applications include suitable and affordable mid-IR light sources...

Black phosphorus saturable absorber for a diode-pumped passively Q-switched Er:CaF2 mid-infrared laser

Science.gov (United States)

Li, Chun; Liu, Jie; Guo, Zhinan; Zhang, Han; Ma, Weiwei; Wang, Jingya; Xu, Xiaodong; Su, Liangbi

2018-01-01

A multilayer black phosphorus, as a novel two dimensional saturable absorber, has superb saturable absorption properties for a Er:CaF2 solid-state pulse laser. The pulse laser is realized at mid-infrared region with the passively Q-switched technology by a diode-pumping. The high-quality black phosphorus saturable absorber is fabricated by liquid phase exfoliation method. The pulse laser generates the pulses operation with the pulse duration of 954.8 ns, the repetition rate of 41.93 kHz, the pulse energy of 4.25 μJ and the peak power of 4.45 W. Our work demonstrates that black phosphorus could be used as a kind of efficient mid-infrared region optical absorber for ultrafast photonics.

High spatial resolution mid-infrared spectroscopy of the starburst galaxies NGC3256, IIZw 40 and Henize 2-10

NARCIS (Netherlands)

Martin-Hernandez, N. L.; Schaerer, D.; Peeters, E.; Tielens, A. G. G. M.; Sauvage, M.

Aims. In order to show the importance of high spatial resolution observations of extra-galactic sources when compared to observations obtained with larger apertures such as ISO, we present N-band spectra (8-13 mu m) of some locations in three starburst galaxies. In particular, we show the two

Mid-IR Observations of Mira Circumstellar Environment

OpenAIRE

Marengo, Massimo; Karovska, Margarita; Fazio, Giovanni G.; Hora, Joseph L.; Hoffmann, William F.; Dayal, Aditya; Deutsch, Lynne K.

2001-01-01

This paper presents results from high-angular resolution mid-IR imaging of the Mira AB circumbinary environment using the MIRAC3 camera at the NASA Infrared Telescope Facility (IRTF). We resolved the dusty circumstellar envelope at 9.8, 11.7 and 18 micron around Mira A (o Ceti), and measured the size of the extended emission. Strong deviations from spherical symmetry are detected in the images of Mira AB system, including possible dust clumps in the direction of the companion (Mira B). These ...

Transparency of Semi-Insulating, n-Type, and p-Type Ammonothermal GaN Substrates in the Near-Infrared, Mid-Infrared, and THz Spectral Range

OpenAIRE

Robert Kucharski; Łukasz Janicki; Marcin Zajac; Monika Welna; Marcin Motyka; Czesław Skierbiszewski; Robert Kudrawiec

2017-01-01

GaN substrates grown by the ammonothermal method are analyzed by Fast Fourier Transformation Spectroscopy in order to study the impact of doping (both n- and p-type) on their transparency in the near-infrared, mid-infrared, and terahertz spectral range. It is shown that the introduction of dopants causes a decrease in transparency of GaN substrates in a broad spectral range which is attributed to absorption on free carriers (n-type samples) or dopant ionization (p-type samples). In the mid-in...

Learning-based compressed sensing for infrared image super resolution

Science.gov (United States)

Zhao, Yao; Sui, Xiubao; Chen, Qian; Wu, Shaochi

2016-05-01

This paper presents an infrared image super-resolution method based on compressed sensing (CS). First, the reconstruction model under the CS framework is established and a Toeplitz matrix is selected as the sensing matrix. Compared with traditional learning-based methods, the proposed method uses a set of sub-dictionaries instead of two coupled dictionaries to recover high resolution (HR) images. And Toeplitz sensing matrix allows the proposed method time-efficient. Second, all training samples are divided into several feature spaces by using the proposed adaptive k-means classification method, which is more accurate than the standard k-means method. On the basis of this approach, a complex nonlinear mapping from the HR space to low resolution (LR) space can be converted into several compact linear mappings. Finally, the relationships between HR and LR image patches can be obtained by multi-sub-dictionaries and HR infrared images are reconstructed by the input LR images and multi-sub-dictionaries. The experimental results show that the proposed method is quantitatively and qualitatively more effective than other state-of-the-art methods.

A Multiwavelength Study of Cygnus X-1: The First Mid-Infrared Spectroscopic Detection of Compact Jets

Science.gov (United States)

Rahoui, Farid; Lee, Julia C.; Heinz, Sebastian; Hines, Dean C.; Pottschmidt, Katja; Wilms, Joern

2011-01-01

We report on a Spitzer/IRS (mid-infrared), RXTE /PCA+HEXTE (X-ray), and Ryle (radio) simultaneous multi-wavelength study of the micro quasar Cygnus X-I, which aimed at an investigation of the origin of its mid-infrared emission. Compact jets were present in two out of three observations, and we show that they strongly contribute to the mid-infrared continuum. During the first observation, we detect the spectral break - where the transition from the optically thick to the optically thin regime takes place - at about 2.9 x 10(exp 13) Hz. We then show that the jet's optically thin synchrotron emission accounts for the Cygnus X-1's emission beyond 400 keY, although it cannot alone explain its 3-200 keV continuum. A compact jet was also present during the second observation, but we do not detect the break, since it has likely shifted to higher frequencies. In contrast, the compact jet was absent during the last observation, and we show that the 5-30 micron mid-infrared continuum of Cygnus X-I stems from the blue supergiant companion star HD 226868. Indeed, the emission can then be understood as the combination of the photospheric Raleigh-Jeans tail and the bremsstrahlung from the expanding stellar wind. Moreover, the stellar wind is found to be clumpy, with a filling factor f(sub infinity) approx.= 0.09-0.10. Its bremsstrahlung emission is likely anti-correlated to the soft X-ray emission, suggesting an anticorrelation between the mass-loss and mass-accretion rates. Nevertheless, we do not detect any mid-infrared spectroscopic evidence of interaction between the jets and the Cygnus X-1's environment and/or companion star's stellar wind.

Quantification of SOC and Clay Content Using Visible Near-Infrared Reflectance–Mid-Infrared Reflectance Spectroscopy With Jack-Knifing Partial Least Squares Regression

DEFF Research Database (Denmark)

Peng, Yi; Knadel, Maria; Gislum, René

2014-01-01

A total of 125 soil samples were collected from a Danish field varying in soil texture from sandy to loamy. Visible near-infrared reflectance (Vis-NIR) and mid-infrared reflectance (MIR) spectroscopy combined with chemometric methods were used to predict soil organic carbon (SOC) and clay content...

Tentative identification of polar and mid-polar compounds in extracts from wine lees by liquid chromatography-tandem mass spectrometry in high-resolution mode.

Science.gov (United States)

Delgado de la Torre, M P; Priego-Capote, F; Luque de Castro, M D

2015-06-01

Sustainable agriculture has a pending goal in the revalorization of agrofood residues. Wine lees are an abundant residue in the oenological industry. This residue, so far, has been used to obtain tartaric acid or pigments but not for being qualitatively characterized as a source of polar and mid-polar compounds such as flavonoids, phenols and essential amino acids. Lees extracts from 11 Spanish wineries have been analyzed by liquid chromatography coupled to tandem mass spectrometry (LC-MS/MS) in high resolution mode. The high-resolution power of LC-MS/MS has led to the tentative identification of the most representative compounds present in wine lees, comprising primary amino acids, anthocyans, flavanols, flavonols, flavones and non-flavonoid phenolic compounds, among others. Attending to the profile and content of polar and mid-polar compounds in wine lees, this study underlines the potential of wine lees as an exploitable source to isolate interesting compounds. Copyright © 2015 John Wiley & Sons, Ltd.

Conductive Oxides Trench Structures as Hyperbolic Metamaterials in Mid-infrared Range

DEFF Research Database (Denmark)

Takayama, Osamu; Shkondin, Evgeniy; Panah, Mohammad Esmail Aryaee

,2]. Moreover plasmonics for mid-infrared offer unique applications such as bio-sensing, thermal imaging and quest for novel materials and structures has been continuing [3]. In this report we show that vertical trench structures made of, for example, aluminum-doped ZnO (AZO) or other transparent conductive...

Diffuse-reflectance fourier-transform mid-infrared spectroscopy as a method of characterizing changes in soil organic matter

Science.gov (United States)

Diffuse-Reflectance Fourier-Transform Mid-Infrared Spectroscopy (MidIR) can identify the presence of important organic functional groups in soil organic matter (SOM). Soils contain myriad organic and inorganic components that absorb in the MidIR so spectral interpretation needs to be validated in or...

Highly-efficient mid-infrared CW laser operation in a lightly-doped 3 at.% Er:SrF2 single crystal.

Science.gov (United States)

Su, Liangbi; Guo, Xinsheng; Jiang, Dapeng; Wu, Qinghui; Qin, Zhipeng; Xie, Guoqiang

2018-03-05

3 at.% Er:SrF 2 laser crystals with high optical quality were successfully grown using the temperature gradient technique (TGT). The intense mid-infrared emission was observed around 2.7 μm with excitation by a 970 nm LD. Based on the Judd-Ofelt theory, the emission cross-sections of the 4 I 13/2 - 4 I 11/2 transition were calculated by using the Fuchtbauer-Ladenburg (FL) method. Efficient continuous-wave laser operation at 2.8 µm was achieved with the lightly-doped 3 at.% Er:SrF 2 crystal pumped by a 970 nm laser diode. The laser output power reached up to 1.06 W with a maximum slope efficiency of 26%.

Estimating optical feedback from a chalcogenide fiber in mid-infrared quantum cascade lasers

Directory of Open Access Journals (Sweden)

L. Jumpertz

2016-10-01

Full Text Available The amount of optical feedback originating from a chalcogenide fiber used to couple light from a mid-infrared quantum cascade laser is evaluated experimentally. Threshold reduction measurements on the fibered laser, combined with an analytical study of a rate equations model of the laser under optical feedback, allow estimating the feedback strength between 11% and 15% depending on the fiber cleavage quality. While this remains below the frontier of the chaotic regime, it is sufficient to deeply modify the optical spectrum of a quantum cascade laser. Hence for applications such as gas spectroscopy, where the shape of the optical spectrum is of prime importance, the use of mid-infrared optical isolators may be necessary for fibered quantum cascade lasers to be fully exploited.

Analysis of energy transfer process based emission spectra of erbium doped germanate glasses for mid-infrared laser materials

Energy Technology Data Exchange (ETDEWEB)

Cai, Muzhi; Wei, Tao; Zhou, Beier; Tian, Ying; Zhou, Jiajia; Xu, Shiqing, E-mail: shiqingxu@cjlu.edu.cn; Zhang, Junjie, E-mail: jjzhang@cjlu.edu.cn

2015-03-25

Highlights: • Er{sup 3+} doped germanate glass with good thermal stability were prepared. • Ionic boding nature was proved by bonding parameter calculation. • Mid-infrared fluorescent behaviors and energy transfer were investigated. • Rate equation and Dexter’s theory were utilized to elucidate 2.7 μm emission. - Abstract: Er{sup 3+} activated germanate glass with good thermal stability was prepared. Bonding parameters have been calculated and the nature of ionic bonding of the germanate glass has been determined. Mid-infrared fluorescence was observed and corresponding radiative properties were investigated. For Er{sup 3+}:{sup 4}I{sub 11/2}→{sup 4}I{sub 13/2} transition, high spontaneous radiative transition probability (30.09 s{sup −1}), large emission cross section ((14.84 ± 0.10) × 10{sup −21} cm{sup 2}) and superior gain performance were obtained from the prepared glass. Besides, energy transfer processes concerning the 2.7 μm emission were also discussed in detail. According to simplified rate equation and Dexter’s theory, energy transfer microscopic parameters were computed to elucidate observed 2.7 μm emissions. Results demonstrate that the prepared germanate glass possessing excellent spectroscopic properties might be an attractive candidate for mid-infrared laser or amplifier.

Study on the mechanism of human blood glucose concentration measuring using mid-infrared spectral analysis technology

Science.gov (United States)

Li, Xiang

2016-10-01

All forms of diabetes increase the risk of long-term complications. Blood glucose monitoring is of great importance for controlling diabetes procedure, preventing the complications and improving the patient's life quality. At present, the clinical blood glucose concentration measurement is invasive and could be replaced by noninvasive spectroscopy analytical techniques. The mid-infrared spectral region contains strong characteristic and well-defined absorption bands. Therefore, mid-infrared provides an opportunity for monitoring blood glucose invasively with only a few discrete bonds. Although the blood glucose concentration measurement using mid-infrared spectroscopy has a lot of advantages, the disadvantage is also obvious. The absorption in this infrared region is fundamental molecular group vibration. Absorption intensity is very strong, especially for biological molecules. In this paper, it figures out that the osmosis rate of glucose has a certain relationship with the blood glucose concentration. Therefore, blood glucose concentration could be measured indirectly by measuring the glucose exudate in epidermis layer. Human oral glucose tolerance tests were carried out to verify the correlation of glucose exudation in shallow layer of epidermis layer and blood glucose concentration. As it has been explained above, the mid-infrared spectral region contains well-defined absorption bands, the intensity of absorption peak around 1123 cm-1 was selected to measure the glucose and that around 1170 cm-1 was selected as reference. Ratio of absorption peak intensity was recorded for each set of measurement. The effect and importance of the cleaning the finger to be measured before spectrum measuring are discussed and also verified by experiment.

Mid-infrared plasmonic resonances exploiting heavily-doped Ge on Si

Science.gov (United States)

Biagioni, P.; Sakat, E.; Baldassarre, L.; Calandrini, E.; Samarelli, A.; Gallacher, K.; Frigerio, J.; Isella, G.; Paul, D. J.; Ortolani, M.

2015-03-01

We address the behavior of mid-infrared localized plasmon resonances in elongated germanium antennas integrated on silicon substrates. Calculations based on Mie theory and on the experimentally retrieved dielectric constant allow us to study the tunability and the figures of merit of plasmon resonances in heavily-doped germanium and to preliminarily compare them with those of the most established plasmonic material, gold.

Infrared galaxies evolution. From cosmological observations with ISO to a mid-infrared to sub-millimetric modeling

International Nuclear Information System (INIS)

Dole, Herve

2000-01-01

This thesis deals with the analysis of the FIRBACK deep survey performed in the far infrared at λ=170 μm with the Infrared Space Observatory whose aim is the study of the galaxies contributing to the Cosmic Infrared Background, and with the modelling of galaxy evolution in the mid-infrared to submillimeter range. The FIRBACK survey covers 3. 89 Sq. Deg. in 3 high galactic latitude and low foreground emission fields (2 of which are in the northern sky). I first present the techniques of reduction, processing and calibration of the ISOPHOT cosmological data. I show that there is a good agreement between PHOT and DIRBE on extended emission, thanks to the derivation of the PHOT footprint. Final maps are created, and the survey is confusion limited at σc=45 mJy. I present then the techniques of source extraction and the simulations for photometry needed to build the final catalog of 106 sources between 180 mJy (4σ) and 2.4 Jy. The complementary catalog is made of 90 sources between 135 and 180 mJy. Galaxy counts show a large excess with respect to local counts or models (with and without evolution), only compatible with strong evolution scenarios. The Cosmic Infrared Background (CIB) is resolved at 4 % at 170 μm. The identifications of the sources at other wavelengths suggest that most of the sources are local, but a non-negligible part lies above redshift 1. I have developed a phenomenological model of galaxy evolution in order to constrain galaxy evolution in the infrared and to have a better understanding of what the FIRBACK sources are. Using the local Luminosity Function (LF), and template spectra of starburst galaxies, it is possible to constrain the evolution of the LF using all the available data: deep source counts at 15, 170 and 850 μm and the CIB spectrum. I show that galaxy evolution is dominated by a high infrared luminosity population, peaking at L=2.0*10"1"1 Redshift distributions are in agreement with available observations. Predictions are

High power frequency comb based on mid-infrared quantum cascade laser at λ ∼ 9 μm

Energy Technology Data Exchange (ETDEWEB)

Lu, Q. Y.; Razeghi, M., E-mail: razeghi@eecs.northwestern.edu; Slivken, S.; Bandyopadhyay, N.; Bai, Y.; Zhou, W. J.; Chen, M.; Heydari, D.; Haddadi, A.; McClintock, R. [Center for Quantum Devices, Department of Electrical Engineering and Computer Science, Northwestern University, Evanston, Illinois 60208 (United States); Amanti, M.; Sirtori, C. [Laboratoire Matériaux et Phénomènes Quantiques, Université Paris Diderot and CNRS, UMR7162, 75205 Paris (France)

2015-02-02

We investigate a frequency comb source based on a mid-infrared quantum cascade laser at λ ∼ 9 μm with high power output. A broad flat-top gain with near-zero group velocity dispersion has been engineered using a dual-core active region structure. This favors the locking of the dispersed Fabry-Pérot modes into equally spaced frequency lines via four wave mixing. A current range with a narrow intermode beating linewidth of 3 kHz is identified with a fast detector and spectrum analyzer. This range corresponds to a broad spectral coverage of 65 cm{sup −1} and a high power output of 180 mW for ∼176 comb modes.

The MIRI Medium Resolution Spectrometer calibration pipeline

NARCIS (Netherlands)

Labiano, A.; Azzollini, R.; Bailey, J.; Beard, S.; Dicken, D.; García-Marín, M.; Geers, V.; Glasse, A.; Glauser, A.; Gordon, K.; Justtanont, K.; Klaassen, P.; Lahuis, F.; Law, D.; Morrison, J.; Müller, M.; Rieke, G.; Vandenbussche, B.; Wright, G.

2016-01-01

The Mid-Infrared Instrument (MIRI) Medium Resolution Spectrometer (MRS) is the only mid-IR Integral Field Spectrometer on board James Webb Space Telescope. The complexity of the MRS requires a very specialized pipeline, with some specific steps not present in other pipelines of JWST instruments,

Tropospheric and total ozone columns over Paris (France measured using medium-resolution ground-based solar-absorption Fourier-transform infrared spectroscopy

Directory of Open Access Journals (Sweden)

C. Viatte

2011-10-01

Full Text Available Ground-based Fourier-transform infrared (FTIR solar absorption spectroscopy is a powerful remote sensing technique providing information on the vertical distribution of various atmospheric constituents. This work presents the first evaluation of a mid-resolution ground-based FTIR to measure tropospheric ozone, independently of stratospheric ozone. This is demonstrated using a new atmospheric observatory (named OASIS for "Observations of the Atmosphere by Solar absorption Infrared Spectroscopy", installed in Créteil (France. The capacity of the technique to separate stratospheric and tropospheric ozone is demonstrated. Daily mean tropospheric ozone columns derived from the Infrared Atmospheric Sounding Interferometer (IASI and from OASIS measurements are compared for summer 2009 and a good agreement of −5.6 (±16.1 % is observed. Also, a qualitative comparison between in-situ surface ozone measurements and OASIS data reveals OASIS's capacity to monitor seasonal tropospheric ozone variations, as well as ozone pollution episodes in summer 2009 around Paris. Two extreme pollution events are identified (on the 1 July and 6 August 2009 for which ozone partial columns from OASIS and predictions from a regional air-quality model (CHIMERE are compared following strict criteria of temporal and spatial coincidence. An average bias of 0.2%, a mean square error deviation of 7.6%, and a correlation coefficient of 0.91 is found between CHIMERE and OASIS, demonstrating the potential of a mid-resolution FTIR instrument in ground-based solar absorption geometry for tropospheric ozone monitoring.

Broadly tunable mid-infrared VECSEL for multiple components hydrocarbon gas sensing

Science.gov (United States)

Rey, J. M.; Fill, M.; Felder, F.; Sigrist, M. W.

2014-12-01

A new sensing platform to simultaneously identify and quantify volatile C1 to C4 alkanes in multi-component gas mixtures is presented. This setup is based on an optically pumped, broadly tunable mid-infrared vertical-external-cavity surface-emitting laser (VECSEL) developed for gas detection. The lead-chalcogenide VECSEL is the key component of the presented optical sensor. The potential of the proposed sensing setup is illustrated by experimental absorption spectra obtained from various mixtures of volatile hydrocarbons and water vapor. The sensor has a sub-ppm limit of detection for each targeted alkane in a hydrocarbon gas mixture even in the presence of a high water vapor content.

Radiation budget studies using collocated observations from advanced Very High Resolution Radiometer, High-Resolution Infrared Sounder/2, and Earth Radiation Budget Experiment instruments

Science.gov (United States)

Ackerman, Steven A.; Frey, Richard A.; Smith, William L.

1992-01-01

Collocated observations from the Advanced Very High Resolution Radiometer (AVHRR), High-Resolution Infrared Sounder/2 (HIRS/2), and Earth Radiation Budget Experiment (ERBE) instruments onboard the NOAA 9 satellite are combined to describe the broadband and spectral radiative properties of the earth-atmosphere system. Broadband radiative properties are determined from the ERBE observations, while spectral properties are determined from the HIRS/2 and AVHRR observations. The presence of clouds, their areal coverage, and cloud top pressure are determined from a combination of the HIRS/2 and the AVHRR observations. The CO2 slicing method is applied to the HIRS/2 to determine the presence of upper level clouds and their effective emissivity. The AVHRR data collocated within the HIRS/2 field of view are utilized to determine the uniformity of the scene and retrieve sea surface temperature. Changes in the top of the atmosphere longwave and shortwave radiative energy budgets, and the spectral distribution of longwave radiation are presented as a function of cloud amount and cloud top pressure. The radiative characteristics of clear sky conditions over oceans are presented as a function of sea surface temperature and atmospheric water vapor structure.

Fourier Transform Near Infrared Microspectroscopy, Infrared Chemical Imaging, High-Resolution Nuclear Magnetic Resonance and Fluorescence Microspectroscopy Detection of Single Cancer Cells and Single Viral Particles

CERN Document Server

Baianu,I C; Hofmann, N E; Korban, S S; Lozano, P; You, T

2004-01-01

Single Cancer Cells from Human tumors are being detected and imaged by Fourier Transform Infrared (FT-IR), Fourier Transform Near Infrared (FT-NIR)Hyperspectral Imaging and Fluorescence Correlation Microspectroscopy. The first FT-NIR chemical, microscopic images of biological systems approaching one micron resolution are here reported. Chemical images obtained by FT-NIR and FT-IR Microspectroscopy are also presented for oil in soybean seeds and somatic embryos under physiological conditions. FT-NIR spectra of oil and proteins were obtained for volumes as small as two cubic microns. Related, HR-NMR analyses of oil contents in somatic embryos as well as 99% accurate calibrations are also presented here with nanoliter precision. Such high-resolution, 400 MHz H-1 NMR analyses allowed the selection of mutagenized embryos with higher oil content (e.g. >~20%) compared to the average levels in non-mutagenized control embryos. Moreover, developmental changes in single soybean seeds and/or somatic embryos may be monito...

The importance of resolution on the response of mid-latitude transients to enhanced CO2

International Nuclear Information System (INIS)

Senior, C.A.

1994-01-01

The impact of global warming on the activity of the mid-latitude transients is not well understood. Work with simple models suggests that there will be two competing effects on transient activity. Firstly, there will be a reduction in the baroclinicity due to a smaller pole-equator temperature gradient and secondly there will be increased moisture availability in a warmer atmosphere. A comparison of the mid-latitude transients from two versions of the Hadley Centre for Climate Prediction and Research GCM run at different resolutions is presented and the importance of resolution on the simulation of the high and low frequency variability is discussed. At higher resolution, one of the largest responses of the model to a doubling of atmospheric CO 2 is an enhancement of the westerly flow in the North Atlantic, but this is much reduced at lower resolution. Consistency is sort between changes in the time mean flow and the transient behavior

NOAA Climate Data Record (CDR) of Intersatellite Calibrated Clear-Sky High Resolution Infrared Radiation Sounder (HIRS) Channel 12 Brightness Temperature Version 3

Data.gov (United States)

National Oceanic and Atmospheric Administration, Department of Commerce — The High-Resolution Infrared Radiation Sounder (HIRS) of intersatellite calibrated channel 12 brightness temperature (TB) product is a gridded global monthly time...

Bio-analytical applications of mid-infrared spectroscopy using silver halide fiber-optic probes

International Nuclear Information System (INIS)

Heise, H.M.; Kuepper, L.; Butvina, L.N.

2002-01-01

Infrared-spectroscopy has proved to be a powerful method for the study of various biomedical samples, in particular for in-vitro analysis in the clinical laboratory and for non-invasive diagnostics. In general, the analysis of biofluids such as whole blood, urine, microdialysates and bioreactor broth media takes advantage of the fact that a multitude of analytes can be quantified simultaneously and rapidly without the need for reagents. Progress in the quality of infrared silver halide fibers enabled us to construct several flexible fiber-optic probes of different geometries, which are particularly suitable for the measurement of small biosamples. Recent trends show that dry film measurements by mid-infrared spectroscopy could revolutionize analytical tools in the clinical chemistry laboratory, and an example is given. Infrared diagnostic tools show a promising potential for patients, and minimal-invasive blood glucose assays or skin tissue pathology in particular cannot be left out using mid-infrared fiber-based probes. Other applications include the measurement of skin samples including penetration studies of vitamins and constituents of cosmetic cream formulations. A further field is the micro-domain analysis of biopsy samples from bog mummified corpses, and recent results on the chemistry of dermis and hair samples are reported. Another field of application, for which results are reported, is food analysis and bio-reactor monitoring

Characterization of the new NSLS infrared microspectroscopy beamline U10B

Energy Technology Data Exchange (ETDEWEB)

Carr, G.L.

1999-07-19

The first of several new infrared beamlines, built on a modified bending magnet port of the NSLS VUV ring, is now operational for mid-infrared microspectroscopy. The port simultaneously delivers 40 mrad by 40 mrad to two separate beamlines and spectrometer endstations designated U10A and U10B. The latter is equipped with a scanning infrared microspectrometer. The combination of this instrument and high brightness synchrotron radiation makes diffraction-limited microspectroscopy practical. This paper describes the beamline's performance and presents quantitative information on the diffraction-limited resolution.

Fiber Based Mid Infrared Supercontinuum Source for Spectroscopic Analysis in Food Production

DEFF Research Database (Denmark)

Ramsay, Jacob; Dupont, Sune Vestergaard Lund; Keiding, Søren Rud

Optimization of sustainable food production is a worldwide challenge that is undergoing continuous development as new technologies emerge. Applying solutions for food analysis with novel bright and broad mid-infrared (MIR) light sources has the potential to meet the increasing demands for food...

Facile and high spatial resolution ratio-metric luminescence thermal mapping in microfluidics by near infrared excited upconversion nanoparticles

Energy Technology Data Exchange (ETDEWEB)

Wang, Yu; Li, Shunbo; Wen, Weijia, E-mail: phwen@ust.hk [Department of Physics, KAUST-HKUST Joint Micro/Nanofluidic Laboratory, The Hong Kong University of Science and Technology, Clear Water Bay, Kowloon (Hong Kong); Cao, Wenbin [Nano Science and Technology Program, Department of Physics, The Hong Kong University of Science and Technology, Clear Water Bay, Kowloon (Hong Kong)

2016-02-01

A local area temperature monitor is important for precise control of chemical and biological processes in microfluidics. In this work, we developed a facile method to realize micron spatial resolution of temperature mapping in a microfluidic channel quickly and cost effectively. Based on the temperature dependent fluorescence emission of NaYF{sub 4}:Yb{sup 3+}, Er{sup 3+} upconversion nanoparticles (UCNPs) under near-infrared irradiation, ratio-metric imaging of UCNPs doped polydimethylsiloxane can map detailed temperature distribution in the channel. Unlike some reported strategies that utilize temperature sensitive organic dye (such as Rhodamine) to achieve thermal sensing, our method is highly chemically inert and physically stable without any performance degradation in long term operation. Moreover, this method can be easily scaled up or down, since the spatial and temperature resolution is determined by an optical imaging system. Our method supplied a simple and efficient solution for temperature mapping on a heterogeneous surface where usage of an infrared thermal camera was limited.

Facile and high spatial resolution ratio-metric luminescence thermal mapping in microfluidics by near infrared excited upconversion nanoparticles

International Nuclear Information System (INIS)

Wang, Yu; Li, Shunbo; Wen, Weijia; Cao, Wenbin

2016-01-01

A local area temperature monitor is important for precise control of chemical and biological processes in microfluidics. In this work, we developed a facile method to realize micron spatial resolution of temperature mapping in a microfluidic channel quickly and cost effectively. Based on the temperature dependent fluorescence emission of NaYF 4 :Yb 3+ , Er 3+ upconversion nanoparticles (UCNPs) under near-infrared irradiation, ratio-metric imaging of UCNPs doped polydimethylsiloxane can map detailed temperature distribution in the channel. Unlike some reported strategies that utilize temperature sensitive organic dye (such as Rhodamine) to achieve thermal sensing, our method is highly chemically inert and physically stable without any performance degradation in long term operation. Moreover, this method can be easily scaled up or down, since the spatial and temperature resolution is determined by an optical imaging system. Our method supplied a simple and efficient solution for temperature mapping on a heterogeneous surface where usage of an infrared thermal camera was limited

THE MID-INFRARED EVOLUTION OF THE FU ORIONIS DISK

Energy Technology Data Exchange (ETDEWEB)

Green, Joel D.; Jones, Olivia C.; Poteet, Charles A.; Sargent, Benjamin A. [Space Telescope Science Institute, Baltimore, MD 21218 (United States); Keller, Luke D. [Department of Physics and Astronomy, Ithaca College, Ithaca, NY (United States); Yang, Yao-Lun; Evans II, Neal J. [Department of Astronomy, The University of Texas at Austin, Austin, TX 78712 (United States); Fischer, William J. [Goddard Space Flight Center, Greenbelt, MD 20771 (United States); Rebull, Luisa M. [IPAC, Pasadena, CA 91125 (United States)

2016-11-20

We present new SOFIA-FORCAST observations obtained in 2016 February of the archetypal outbursting low-mass young stellar object FU Orionis, and we compare the continuum, solid-state, and gas properties with mid-infrared data obtained at the same wavelengths in 2004 with Spitzer -IRS. In this study, we conduct the first mid-infrared spectroscopic comparison of an FUor over a long time period. Over a 12-year period, UBVR monitoring indicates that FU Orionis has continued its steady decrease in overall brightness by ∼14%. We find that this decrease in luminosity occurs only at wavelengths ≲20 μ m. In particular, the continuum shortward of the silicate emission complex at 10 μ m exhibits a ∼12% (∼3 σ ) drop in flux density but no apparent change in slope; both the Spitzer and SOFIA spectra are consistent with a 7200 K blackbody. Additionally, the detection of water absorption is consistent with the Spitzer spectrum. The silicate emission feature at 10 μ m continues to be consistent with unprocessed grains, unchanged over 12 years. We conclude that either the accretion rate in FU Orionis has decreased by ∼12–14% over this time baseline or the inner disk has cooled, but the accretion disk remains in a superheated state outside the innermost region.

An atlas of high-resolution IRAS maps on nearby galaxies

Science.gov (United States)

Rice, Walter

1993-01-01

An atlas of far-infrared IRAS maps with near 1 arcmin angular resolution of 30 optically large galaxies is presented. The high-resolution IRAS maps were produced with the Maximum Correlation Method (MCM) image construction and enhancement technique developed at IPAC. The MCM technique, which recovers the spatial information contained in the overlapping detector data samples of the IRAS all-sky survey scans, is outlined and tests to verify the structural reliability and photometric integrity of the high-resolution maps are presented. The infrared structure revealed in individual galaxies is discussed. The atlas complements the IRAS Nearby Galaxy High-Resolution Image Atlas, the high-resolution galaxy images encoded in FITS format, which is provided to the astronomical community as an IPAC product.

Airborne Laser Infrared Absorption Spectrometer (ALIAS-II) for in situ Atmospheric Measurements of N(sub 2)0, CH(sub 4), CO, HCl, and NO(sub 2) from Balloon or RPA Platforms

Science.gov (United States)

Scott, D.; Herman, R.; Webster, C.; May, R.; Flesch, G.; Moyer, E.

1998-01-01

The Airborne Laser Infrared Absorption Spectrometer II (ALIAS-II) is a lightweight, high-resolution (0.0003 cm-1), scanning, mid-infrared absorption spectrometer based on cooled (80 K) lead-salt tunable diode laser sources.

Ultra-Broadband Infrared Pulses from a Potassium-Titanyl Phosphate Optical Parametric Amplifier for VIS-IR-SFG Spectroscopy

Science.gov (United States)

Isaienko, Oleksandr; Borguet, Eric

A non-collinear KTP-OPA to provide ultra-broadband mid-infrared pulses was designed and characterized. With proper pulse-front and phase correction, the system has a potential for high-time resolution vibrational VIS-IR-SFG spectroscopy.

Dielectric properties of vertically aligned multi-walled carbon nanotubes in the terahertz and mid-infrared range

Science.gov (United States)

Thomson, Mark D.; Zouaghi, Wissem; Meng, Fanqi; Wiecha, Matthias M.; Rabia, Kaneez; Heinlein, Thorsten; Hussein, Laith; Babu, Deepu; Yadav, Sandeep; Engstler, Jörg; Schneider, Jörg J.; Nicoloso, Norbert; Rychetský, Ivan; Kužel, Petr; Roskos, Hartmut G.

2018-01-01

We investigate the broadband dielectric properties of vertically aligned, multi-wall carbon nanotubes (VACNT), over both the terahertz (THz) and mid-infrared spectral ranges. The nominally undoped, metallic VACNT samples are probed at normal incidence, i.e. the response is predominantly due to polarisation perpendicular to the CNT axis. A detailed comparison of various conductivity models and previously reported results is presented for the non-Drude behaviour we observe in the conventional THz range (up to 2.5 THz). Extension to the mid-infrared range reveals an absorption peak at \

Modelling the mid-infrared drying of sweet potato: kinetics, mass and heat transfer parameters, and energy consumption

Science.gov (United States)

Onwude, Daniel I.; Hashim, Norhashila; Abdan, Khalina; Janius, Rimfiel; Chen, Guangnan

2018-04-01

This study investigated the drying kinetics, mass and heat transfer characteristics of sweet potato slices (0.4-0.6 cm thickness) during drying based on mid-infrared experimental set-up (intensity of 1100-1400 W/m2). Thin layer drying models were used to evaluate the drying kinetics of sweet potato slices. Two analytical models (Fick's diffusion model, and Dincer and Dost model) were used to study the mass transfer behaviour of sweet potato slices with and without shrinkage during mid-infrared drying. The heat transfer flux between the emitter and sweet potato slices was also investigated. Results demonstrated that an increase in infrared intensity from 1100 W/m2 to 1400 W/m2 resulted in increased in average radiation heat flux by 3.4 times and a 15% reduction in the overall drying time. The two-term exponential model was found to be the best in predicting the drying kinetics of sweet potato slices during mid-infrared drying. The specific heat consumption varied from 0.91-4.82 kWh/kg. The effective moisture diffusivity with and without shrinkage using the Fick's diffusion model varied from 2.632 × 10-9 to 1.596 × 10-8 m2/s, and 1.24 × 10-8 to 2.4 × 10-8 m2/s using Dincer and Dost model, respectively. The obtained values of mass transfer coefficient, Biot number and activation energy varied from 5.99 × 10-6 to 1.17 × 10-5 m/s, 0.53 to 2.62, and 12.83 kJ/mol to 34.64 kJ/mol, respectively. The values obtained for Biot number implied the existence of simultaneous internal and external resistances. The findings further explained that mid-infrared intensity of 1100 W/m2 did not significantly affect the quality of sweet potato during drying, demonstrating a great potential of applying low intensity mid-infrared radiation in the drying of agricultural crops.

Frequency locking of an extended-cavity quantum cascade laser to a frequency comb for precision mid infrared spectroscopy

KAUST Repository

Alsaif, Bidoor; Lamperti, Marco; Gatti, Davide; Laporta, Paolo; Fermann, Martin E.; Farooq, Aamir; Marangoni, Marco

2017-01-01

Extended-cavity quantum cascade lasers (EC-QCLs) enable mode-hope-free frequency sweeps in the mid-infrared region over ranges in excess of 100 cm−1, at speeds up to 1 THz/s and with a 100-mW optical power level. This makes them ideally suited for broadband absorption spectroscopy and for the simultaneous detection of multiple gases. On the other hand, their use for precision spectroscopy has been hampered so far by a large amount of frequency noise, resulting in an optical linewidth of about 30 MHz over 50 ms [1]. This is one of the reasons why neither their frequency nor their phase have been so far locked to a frequency comb. Their use in combination with frequency combs has been performed in an open loop regime only [2], which has the merit of preserving the inherently fast modulation speed of these lasers, yet not to afford high spectral resolution and accuracy.

Frequency locking of an extended-cavity quantum cascade laser to a frequency comb for precision mid infrared spectroscopy

KAUST Repository

Alsaif, Bidoor

2017-11-02

Extended-cavity quantum cascade lasers (EC-QCLs) enable mode-hope-free frequency sweeps in the mid-infrared region over ranges in excess of 100 cm−1, at speeds up to 1 THz/s and with a 100-mW optical power level. This makes them ideally suited for broadband absorption spectroscopy and for the simultaneous detection of multiple gases. On the other hand, their use for precision spectroscopy has been hampered so far by a large amount of frequency noise, resulting in an optical linewidth of about 30 MHz over 50 ms [1]. This is one of the reasons why neither their frequency nor their phase have been so far locked to a frequency comb. Their use in combination with frequency combs has been performed in an open loop regime only [2], which has the merit of preserving the inherently fast modulation speed of these lasers, yet not to afford high spectral resolution and accuracy.

Mid-Infrared Emission Features in the ISM: Feature-to-Features Flux Ratios

Science.gov (United States)

Lu, N. Y.

1998-01-01

Using a limited, but representative sample of sources in the ISM of our Galaxy with published spectra from the Infrared Space Observatory, we analyze flux ratios between the major mid-IR emission features (EFs) centered around 6.2, 7.7, 8.6 and 11.3 mu, respectively.

High-resolution focal plane array IR detection modules and digital signal processing technologies at AIM

Science.gov (United States)

Cabanski, Wolfgang A.; Breiter, Rainer; Koch, R.; Mauk, Karl-Heinz; Rode, Werner; Ziegler, Johann; Eberhardt, Kurt; Oelmaier, Reinhard; Schneider, Harald; Walther, Martin

2000-07-01

Full video format focal plane array (FPA) modules with up to 640 X 512 pixels have been developed for high resolution imaging applications in either mercury cadmium telluride (MCT) mid wave (MWIR) infrared (IR) or platinum silicide (PtSi) and quantum well infrared photodetector (QWIP) technology as low cost alternatives to MCT for high performance IR imaging in the MWIR or long wave spectral band (LWIR). For the QWIP's, a new photovoltaic technology was introduced for improved NETD performance and higher dynamic range. MCT units provide fast frame rates > 100 Hz together with state of the art thermal resolution NETD hardware platforms and software for image visualization and nonuniformity correction including scene based self learning algorithms had to be developed to accomplish for the high data rates of up to 18 M pixels/s with 14-bit deep data, allowing to take into account nonlinear effects to access the full NETD by accurate reduction of residual fixed pattern noise. The main features of these modules are summarized together with measured performance data for long range detection systems with moderately fast to slow F-numbers like F/2.0 - F/3.5. An outlook shows most recent activities at AIM, heading for multicolor and faster frame rate detector modules based on MCT devices.

RISING FROM THE ASHES: MID-INFRARED RE-BRIGHTENING OF THE IMPOSTOR SN 2010da IN NGC 300

Energy Technology Data Exchange (ETDEWEB)

Lau, Ryan M.; Ressler, Michael E. [Jet Propulsion Laboratory, California Institute of Technology, 4800 Oak Grove Drive, Pasadena, CA 91109 (United States); Kasliwal, Mansi M.; Jencson, Jacob [California Institute of Technology, Pasadena, CA 91125 (United States); Bond, Howard E.; Monson, Andrew J. [Department of Astronomy and Astrophysics, Pennsylvania State University, University Park, PA 16802 (United States); Smith, Nathan [Steward Observatory, University of Arizona, Tuscon, AZ 85721 (United States); Fox, Ori D. [Space Telescope Science Institute, 3700 San Martin Drive, Baltimore, MD 21218 (United States); Carlon, Robert; Dykhoff, Devin; Gehrz, Robert [Minnesota Institute for Astrophysics, School of Physics and Astronomy, 116 Church Street, SE, University of Minnesota, Minneapolis, MN 55455 (United States); Cody, Ann Marie [NASA Ames Research Center, Moffett Field, CA 94035 (United States); Contreras, Carlos [Las Campanas Observatory, Carnegie Observatories, Casilla 601, La Serena (Chile); Hsiao, Eric [Department of Physics, Florida State University, 77 Chieftain Way, Tallahassee, FL 32306 (United States); Khan, Rubab [NASA Goddard Space Flight Center, MC 665, 8800 Greenbelt Road, Greenbelt, MD 20771 (United States); Masci, Frank [Infrared Processing and Analysis Center, California Institute of Technology, M/S 100-22, Pasadena, CA 91125 (United States); Monard, L. A. G. [Bronberg and Kleinkaroo Observatories, P.O. Box 281, Calitzdorp 6660, Western Cape (South Africa); Morrell, Nidia; Phillips, Mark [Carnegie Institution of Washington, Las Campanas Observatory, Colina el Pino, Casilla 601, La Serena (Chile)

2016-10-20

We present multi-epoch mid-infrared (IR) photometry and the optical discovery observations of the “impostor” supernova (SN) 2010da in NGC 300 using new and archival Spitzer Space Telescope images and ground-based observatories. The mid-infrared counterpart of SN 2010da was detected as Spitzer Infrared Intensive Transient Survey (SPIRITS) 14bme in the SPIRITS, an ongoing systematic search for IR transients. Before erupting on 2010 May 24, the SN 2010da progenitor exhibited a constant mid-IR flux at 3.6 and only a slight ∼10% decrease at 4.5 μ m between 2003 November and 2007 December. A sharp increase in the 3.6 μ m flux followed by a rapid decrease measured ∼150 days before and ∼80 days after the initial outburst, respectively, reveal a mid-IR counterpart to the coincident optical and high luminosity X-ray outbursts. At late times, after the outburst (∼2000 days), the 3.6 and 4.5 μ m emission increased to over a factor of two times the progenitor flux and is currently observed (as of 2016 Feb) to be fading, but still above the progenitor flux. We attribute the re-brightening mid-IR emission to continued dust production and increasing luminosity of the surviving system associated with SN 2010da. We analyze the evolution of the dust temperature ( T {sub d} ∼ 700–1000 K), mass ( M {sub d} ∼ 0.5–3.8 × 10{sup −7} M {sub ⊙}), luminosity ( L {sub IR} ∼ 1.3–3.5 × 10{sup 4} L {sub ⊙}), and the equilibrium temperature radius ( R {sub eq} ∼ 6.4–12.2 au) in order to resolve the nature of SN 2010da. We address the leading interpretation of SN 2010da as an eruption from a luminous blue variable high-mass X-ray binary (HMXB) system. We propose that SN 2010da is instead a supergiant (sg)B[e]-HMXB based on similar luminosities and dust masses exhibited by two other known sgB[e]-HMXB systems. Additionally, the SN 2010da progenitor occupies a similar region on a mid-IR color–magnitude diagram (CMD) with known sgB[e] stars in the Large

Low-luminosity Blazars in Wise: A Mid-infrared View of Unification

Science.gov (United States)

Plotkin, Richard M.; Anderson, S. F.; Brandt, W. N.; Markoff, S.; Shemmer, O.; Wu, J.

2012-01-01

We use the preliminary data release from the Wide-Field Infrared Survey Explorer (WISE) to perform the first statistical study on the mid-infrared (IR) properties of a large number ( 102) of BL Lac objects -- low-luminosity Active Galactic Nuclei (AGN) with a jet beamed toward the Earth. As expected, many BL Lac objects are so highly beamed that their jet synchrotron emission dominates their IR spectral energy distributions (SEDs), and the shape of their SEDs in the IR correlates well with SED peak frequency. In other BL Lac objects, the jet is not strong enough to completely dilute the rest of the AGN, and we do not see observational signatures of the dusty torus from these weakly beamed BL Lac objects. While at odds with simple unification, the missing torus is consistent with recent suggestions that BL Lac objects are fed by radiatively inefficient accretion flows. We discuss implications on the ``nature vs. nurture" debate for FR I and FR II galaxies, and also on the standard orientation-based AGN unification model.

Development of tellurium oxide and lead-bismuth oxide glasses for mid-wave infra-red transmission optics

Science.gov (United States)

Zhou, Beiming; Rapp, Charles F.; Driver, John K.; Myers, Michael J.; Myers, John D.; Goldstein, Jonathan; Utano, Rich; Gupta, Shantanu

2013-03-01

Heavy metal oxide glasses exhibiting high transmission in the Mid-Wave Infra-Red (MWIR) spectrum are often difficult to manufacture in large sizes with optimized physical and optical properties. In this work, we researched and developed improved tellurium-zinc-barium and lead-bismuth-gallium heavy metal oxide glasses for use in the manufacture of fiber optics, optical components and laser gain materials. Two glass families were investigated, one based upon tellurium and another based on lead-bismuth. Glass compositions were optimized for stability and high transmission in the MWIR. Targeted glass specifications included low hydroxyl concentration, extended MWIR transmission window, and high resistance against devitrification upon heating. Work included the processing of high purity raw materials, melting under controlled dry Redox balanced atmosphere, finning, casting and annealing. Batch melts as large as 4 kilograms were sprue cast into aluminum and stainless steel molds or temperature controlled bronze tube with mechanical bait. Small (100g) test melts were typically processed in-situ in a 5%Au°/95%Pt° crucible. Our group manufactured and evaluated over 100 different experimental heavy metal glass compositions during a two year period. A wide range of glass melting, fining, casting techniques and experimental protocols were employed. MWIR glass applications include remote sensing, directional infrared counter measures, detection of explosives and chemical warfare agents, laser detection tracking and ranging, range gated imaging and spectroscopy. Enhanced long range mid-infrared sensor performance is optimized when operating in the atmospheric windows from ~ 2.0 to 2.4μm, ~ 3.5 to 4.3μm and ~ 4.5 to 5.0μm.

Design analysis of doped-silicon surface plasmon resonance immunosensors in mid-infrared range.

Science.gov (United States)

DiPippo, William; Lee, Bong Jae; Park, Keunhan

2010-08-30

This paper reports the design analysis of a microfabricatable mid-infrared (mid-IR) surface plasmon resonance (SPR) sensor platform. The proposed platform has periodic heavily doped profiles implanted into intrinsic silicon and a thin gold layer deposited on top, making a physically flat grating SPR coupler. A rigorous coupled-wave analysis was conducted to prove the design feasibility, characterize the sensor's performance, and determine geometric parameters of the heavily doped profiles. Finite element analysis (FEA) was also employed to compute the electromagnetic field distributions at the plasmon resonance. Obtained results reveal that the proposed structure can excite the SPR on the normal incidence of mid-IR light, resulting in a large probing depth that will facilitate the study of larger analytes. Furthermore, the whole structure can be microfabricated with well-established batch protocols, providing tunability in the SPR excitation wavelength for specific biosensing needs with a low manufacturing cost. When the SPR sensor is to be used in a Fourier-transform infrared (FTIR) spectroscopy platform, its detection sensitivity and limit of detection are estimated to be 3022 nm/RIU and ~70 pg/mm(2), respectively, at a sample layer thickness of 100 nm. The design analysis performed in the present study will allow the fabrication of a tunable, disposable mid-IR SPR sensor that combines advantages of conventional prism and metallic grating SPR sensors.

Mid infrared MEMS FTIR spectrometer

Science.gov (United States)

Erfan, Mazen; Sabry, Yasser M.; Mortada, Bassem; Sharaf, Khaled; Khalil, Diaa

2016-03-01

In this work we report, for the first time to the best of our knowledge, a bulk-micromachined wideband MEMS-based spectrometer covering both the NIR and the MIR ranges and working from 1200 nm to 4800 nm. The core engine of the spectrometer is a scanning Michelson interferometer micro-fabricated using deep reactive ion etching (DRIE) technology. The spectrum is obtained using the Fourier Transform techniques that allows covering a very wide spectral range limited by the detector responsivity. The moving mirror of the interferometer is driven by a relatively large stroke electrostatic comb-drive actuator. Zirconium fluoride (ZrF4) multimode optical fibers are used to connect light between the white light source and the interferometer input, as well as the interferometer output to a PbSe photoconductive detector. The recorded signal-to-noise ratio is 25 dB at the wavelength of 3350 nm. The spectrometer is successfully used in measuring the absorption spectra of methylene chloride, quartz glass and polystyrene film. The presented solution provides a low cost method for producing miniaturized spectrometers in the near-/mid-infrared.

Transparency of Semi-Insulating, n-Type, and p-Type Ammonothermal GaN Substrates in the Near-Infrared, Mid-Infrared, and THz Spectral Range

Directory of Open Access Journals (Sweden)

Robert Kucharski

2017-06-01

Full Text Available GaN substrates grown by the ammonothermal method are analyzed by Fast Fourier Transformation Spectroscopy in order to study the impact of doping (both n- and p-type on their transparency in the near-infrared, mid-infrared, and terahertz spectral range. It is shown that the introduction of dopants causes a decrease in transparency of GaN substrates in a broad spectral range which is attributed to absorption on free carriers (n-type samples or dopant ionization (p-type samples. In the mid-infrared the transparency cut-off, which for a semi-insulating GaN is at ~7 µm due to an absorption on a second harmonic of optical phonons, shifts towards shorter wavelengths due to an absorption on free carriers up to ~1 µm at n ~ 1020 cm−3 doping level. Moreover, a semi-insulating GaN crystal shows good transparency in the 1–10 THz range, while for n-and p-type crystal, the transparency in this spectral region is significantly quenched below 1%. In addition, it is shown that in the visible spectral region n-type GaN substrates with a carrier concentration below 1018 cm−3 are highly transparent with the absorption coefficient below 3 cm−1 at 450 nm, a satisfactory condition for light emitting diodes and laser diodes operating in this spectral range.

IPHAS A-TYPE STARS WITH MID-INFRARED EXCESSES IN SPITZER SURVEYS

International Nuclear Information System (INIS)

Hales, Antonio S.; Barlow, Michael J.; Drew, Janet E.; Unruh, Yvonne C.; Greimel, Robert; Irwin, Michael J.; Gonzalez-Solares, Eduardo

2009-01-01

We have identified 17 A-type stars in the Galactic Plane that have mid-infrared (mid-IR) excesses at 8 μm. From observed colors in the (r' - Hα) - (r' - i') plane, we first identified 23,050 early A-type main-sequence (MS) star candidates in the Isaac Newton Photometric H-Alpha Survey (IPHAS) point source database that are located in Spitzer Galactic Legacy Mid-Plane Survey Extraordinaire Galactic plane fields. Imposing the requirement that they be detected in all seven Two Micron All Sky Survey and Infrared Astronomical Satellite bands led to a sample of 2692 candidate A-type stars with fully sampled 0.6 to 8 μm spectral energy distributions (SEDs). Optical classification spectra of 18 of the IPHAS candidate A-type MS stars showed that all but one could be well fitted using MS A-type templates, with the other being an A-type supergiant. Out of the 2692 A-type candidates 17 (0.6%) were found to have 8 μm excesses above the expected photospheric values. Taking into account non-A-Type contamination estimates, the 8 μm excess fraction is adjusted to ∼0.7%. The distances to these sources range from 0.7 to 2.5 kpc. Only 10 out of the 17 excess stars had been covered by Spitzer MIPSGAL survey fields, of which five had detectable excesses at 24 μm. For sources with excesses detected in at least two mid-IR wavelength bands, blackbody fits to the excess SEDs yielded temperatures ranging from 270 to 650 K, and bolometric luminosity ratios L IR /L * from 2.2 x 10 -3 - 1.9 x 10 -2 , with a mean value of 7.9 x 10 -3 (these bolometric luminosities are lower limits as cold dust is not detectable by this survey). Both the presence of mid-IR excesses and the derived bolometric luminosity ratios are consistent with many of these systems being in the planet-building transition phase between the early protoplanetary disk phase and the later debris disk phase.

Masterpieces unmasked: New high-resolution infrared cameras produce rich, detailed images of artwork, and create new controversies

CERN Document Server

Marshall, J

2002-01-01

Luca Pezzati is a physicist who heads a group called Art Diagnostics, which is a part of the Opificio delle Pietre Dure, an institute devoted to the research and conservation of artworks in Italy. Pezzati and his group use high-resolution infrared scanning device to produce colour images of what lies below the surface of paintings. Their scanner is able to produce the best-known quality of images without harming the painting under examination (1 page).

Comment on "A spectroscopic comparison of selected Chinese kaolinite, coal bearing kaolinite and halloysite--a mid-infrared and near-infrared study" and "Infrared and infrared emission spectroscopic study of typical Chinese kaolinite and halloysite" by Hongfei Cheng et al. (2010).

Science.gov (United States)

Kloprogge, J Theo

2015-02-05

In two papers Cheng et al. (2010) reported in this journal on the mid-infrared, near-infrared and infrared emission spectroscopy of a halloysite from Hunan Xianrenwan, China. This halloysite contains around 8% of quartz (SiO2) and nearly 9% gibbsite (Al(OH)3). In their interpretation of the spectra these impurities were completely ignored. Careful comparison with a phase pure halloysite from Southern Belgium, synthetic gibbsite, gibbsite from Minas Gerais, and quartz show that these impurities do have a marked influence on the mid-infrared and infrared emission spectra. In the near-infrared, the effect is much less pronounced. Quartz does not show bands in this region and the gibbsite bands will be very weak. Comparison still show that the presence of gibbsite does contribute to the overall spectrum and bands that were ascribed to the halloysite alone do coincide with those of gibbsite. Copyright © 2014 Elsevier B.V. All rights reserved.

Mid-infrared pulsed laser ablation of the arterial wall. Mechanical origin of "acoustic" wall damage and its effect on wall healing

NARCIS (Netherlands)

van Erven, L.; van Leeuwen, T. G.; Post, M. J.; van der Veen, M. J.; Velema, E.; Borst, C.

1992-01-01

Pulsed mid-infrared lasers are an alternative to excimer lasers for transluminal angioplasty. The mid-infrared lasers, however, were reported to produce "acoustic" wall damage that might impair the immediate and long-term results. To study the immediate and long-term effects on the arterial wall,

Submillisecond mixing in a continuous-flow, microfluidic mixer utilizing mid-infrared hyperspectral imaging detection.

Science.gov (United States)

Kise, Drew P; Magana, Donny; Reddish, Michael J; Dyer, R Brian

2014-02-07

We report a continuous-flow, microfluidic mixer utilizing mid-infrared hyperspectral imaging detection, with an experimentally determined, submillisecond mixing time. The simple and robust mixer design has the microfluidic channels cut through a polymer spacer that is sandwiched between two IR transparent windows. The mixer hydrodynamically focuses the sample stream with two side flow channels, squeezing it into a thin jet and initiating mixing through diffusion and advection. The detection system generates a mid-infrared hyperspectral absorbance image of the microfluidic sample stream. Calibration of the hyperspectral image yields the mid-IR absorbance spectrum of the sample versus time. A mixing time of 269 μs was measured for a pD jump from 3.2 to above 4.5 in a D2O sample solution of adenosine monophosphate (AMP), which acts as an infrared pD indicator. The mixer was further characterized by comparing experimental results with a simulation of the mixing of an H2O sample stream with a D2O sheath flow, showing good agreement between the two. The IR microfluidic mixer eliminates the need for fluorescence labeling of proteins with bulky, interfering dyes, because it uses the intrinsic IR absorbance of the molecules of interest, and the structural specificity of IR spectroscopy to follow specific chemical changes such as the protonation state of AMP.

MAPPING THE SPATIAL DISTRIBUTION OF DUST EXTINCTION IN NGC 959 USING BROADBAND VISIBLE AND MID-INFRARED FILTERS

International Nuclear Information System (INIS)

Tamura, K.; Jansen, R. A.; Windhorst, R. A.

2009-01-01

We present a method to estimate and map the two-dimensional distribution of dust extinction in the late-type spiral galaxy NGC 959 from the theoretical and observed flux ratio of optical V and mid-IR (MIR) 3.6 μm images. Our method is applicable to both young and old stellar populations for a range of metallicities, and is not restricted to lines of sight toward star-formation (SF) regions. We explore this method using a pixel-based analysis on images of NGC 959 obtained in the V band at the Vatican Advanced Technology Telescope and at 3.6 μm (L band) with Spitzer/Infrared Array Camera. We present the original and extinction corrected Galaxy Evolution Explorer (GALEX) far-UV (FUV) and near-UV (NUV) images, as well as optical UBVR images of NGC 959. While the dust lanes are not clearly evident at GALEX resolution, our dust map clearly traces the dust that can be seen silhouetted against the galaxy's disk in the high-resolution Hubble Space Telescope (HST) images of NGC 959. The advantages of our method are (1) it only depends on two relatively common broadband images in the optical V band and in the MIR at 3.6 μm (but adding a near-UV band improves its fidelity); and (2) it is able to map the two-dimensional spatial distribution of dust within a galaxy. This powerful tool could be used to measure the detailed distribution of dust extinction within higher redshift galaxies to be observed with, e.g., the Hubble Space Telescope (HST)/WFC3 (optical near-IR) and James Webb Space Telescope (mid-IR), and to distinguish properties of dust within galaxy bulges, spiral arms, and inter-arm regions.

Exploring the Spatial Resolution of the Photothermal Beam Deflection Technique in the Infrared Region

CERN Document Server

Seidel, Wolfgang

2004-01-01

In photothermal beam deflection spectroscopy (PTBD) generating and detection of thermal waves occur generally in the sub-millimeter length scale. Therefore, PTBD provides spatial information about the surface of the sample and permits imaging and/or microspectrometry. Recent results of PTBD experiments are presented with a high spatial resolution which is near the diffraction limit of the infrared pump beam (CLIO-FEL). We investigated germanium substrates showing restricted O+-doped regions with an infrared absorption line at a wavelength around 11.6 microns. The spatial resolution was obtained by strongly focusing the probe beam (i.e. a HeNe laser) on a sufficiently small spot. The strong divergence makes it necessary to refocus the probe beam in front of the position detector. The influence of the focusing elements on spatial resolution and signal-to-noise ratio is discussed. In future studies we expect an enhanced spatial resolution due to an extreme focusing of the probe beam leading to a highly sensitive...

EVIDENCE FOR DYNAMICAL CHANGES IN A TRANSITIONAL PROTOPLANETARY DISK WITH MID-INFRARED VARIABILITY

International Nuclear Information System (INIS)

Muzerolle, James; Flaherty, Kevin; Balog, Zoltan; Smith, Paul S.; Rieke, George H.; Furlan, Elise; Allen, Lori; Muench, August; Calvet, Nuria; D'Alessio, Paola; Megeath, S. Thomas; Sherry, William H.

2009-01-01

We present multi-epoch Spitzer Space Telescope observations of the transitional disk LRLL 31 in the 2-3 Myr old star-forming region IC 348. Our measurements show remarkable mid-infrared variability on timescales as short as one week. The infrared continuum emission exhibits systematic wavelength-dependent changes that suggest corresponding dynamical changes in the inner disk structure and variable shadowing of outer disk material. We propose several possible sources for the structural changes, including a variable accretion rate or a stellar or planetary companion embedded in the disk. Our results indicate that variability studies in the infrared can provide important new constraints on protoplanetary disk behavior.

Determination of carbohydrates present in Saccharomyces cerevisiae using mid-infrared spectroscopy and partial least squares regression

OpenAIRE

Plata, Maria R.; Koch, Cosima; Wechselberger, Patrick; Herwig, Christoph; Lendl, Bernhard

2013-01-01

A fast and simple method to control variations in carbohydrate composition of Saccharomyces cerevisiae, baker's yeast, during fermentation was developed using mid-infrared (mid-IR) spectroscopy. The method allows for precise and accurate determinations with minimal or no sample preparation and reagent consumption based on mid-IR spectra and partial least squares (PLS) regression. The PLS models were developed employing the results from reference analysis of the yeast cells. The reference anal...

Critical coupling using the hexagonal boron nitride crystals in the mid-infrared range

Energy Technology Data Exchange (ETDEWEB)

Wu, Jipeng; Wang, Hengliang; Wen, Shuangchun [Key Laboratory for Micro-/Nano-Optoelectronic Devices of Ministry of Education, School of Physics and Electronics, Hunan University, Changsha 410082 (China); Jiang, Leyong; Guo, Jun; Dai, Xiaoyu [SZU-NUS Collaborative Innovation Center for Optoelectronic Science & Technology, Key Laboratory of Optoelectronic Devices and Systems of Ministry of Education and Guangdong Province, College of Optoelectronic Engineering, Shenzhen University, Shenzhen 518060 (China); Xiang, Yuanjiang, E-mail: xiangyuanjiang@126.com [Key Laboratory for Micro-/Nano-Optoelectronic Devices of Ministry of Education, School of Physics and Electronics, Hunan University, Changsha 410082 (China); SZU-NUS Collaborative Innovation Center for Optoelectronic Science & Technology, Key Laboratory of Optoelectronic Devices and Systems of Ministry of Education and Guangdong Province, College of Optoelectronic Engineering, Shenzhen University, Shenzhen 518060 (China)

2016-05-28

We theoretically demonstrate the perfect absorption phenomena in the hexagonal boron nitride (hBN) crystals in the mid-infrared wavelength ranges by means of critical coupling with a one-dimensional photonic crystal spaced by the air. Different from the polymer absorbing layer composed by a metal-dielectric composite film, the hyperbolic dispersion characteristics of hBN can meet the condition of critical coupling and achieve the total absorption in the mid-infrared wavelength ranges. However, the critical coupling phenomenon can only appear in the hBN crystals with the type II dispersion. Moreover, we discuss the influence of the thickness of hBN, the incident angle, and the thickness and permittivity of the space dielectric on the total absorption. Ultimately, the conditions for absorption enhancement and the optimization methods of perfect absorption are proposed, and the design rules for a totally absorbing system under the different conditions are achieved.

Applications of a Mid-IR Quantum Cascade Laser in Gas Sensing Research

KAUST Repository

Sajid, Muhammad Bilal

2015-05-01

Laser absorption based sensors are extensively used in a variety of gas sensing areas such as combustion, atmospheric research, human breath analysis, and high resolution infrared spectroscopy. Quantum cascade lasers have recently emerged as high resolution, high power laser sources operating in mid infrared region and can have wide tunability range. These devices provide an opportunity to access stronger fundamental and combination vibrational bands located in mid infrared region than previously accessible weaker overtone vibrational bands located in near infrared region. Spectroscopic region near 8 µm contains strong vibrational bands of methane, acetylene, hydrogen peroxide, water vapor and nitrous oxide. These molecules have important applications in a wide range of applications. This thesis presents studies pertaining to spectroscopy and combustion applications. Advancements in combustion research are imperative to achieve lower emissions and higher efficiency in practical combustion devices such as gas turbines and engines. Accurate chemical kinetic models are critical to achieve predictive models which contain several thousand reactions and hundreds of species. These models need highly reliable experimental data for validation and improvements. Shock tubes are ideal devices to obtain such information. A shock tube is a homogenous, nearly constant volume, constant pressure, adiabatic and 0-D reactor. In combination with laser absorption sensors, shock tubes can be used to measure reaction rates and species time histories of several intermediates and products formed during pyrolysis and oxidation of fuels. This work describes measurement of the decomposition rate of hydrogen peroxide which is an important intermediate species controlling reactivity of combustion system in the intermediate temperature range. Spectroscopic parameters (linestrengths, broadening coefficients and temperature dependent coefficients) are determined for various transitions of

Multi-wavelength study of infrared galaxies

International Nuclear Information System (INIS)

Marcillac, Delphine

2005-01-01

This thesis deals with a panchromatic study of luminous infrared galaxies (LIRGs) detected at 15 microns by ISOCAM (camera aboard ISO) and at 24 microns by MIPS (camera aboard the recently launched Spitzer satellite). These galaxies are today considered to be the Rosetta Stone of galaxy evolution since they are found to be far more numerous at high redshift and it is thought that a large part of stars seen in the local universe are born in such phases. The first part of this thesis presents a new study dedicated to dust emission of distant LIRGs in the mid-infrared range. Their dust emission has been compared to those of a local sample of LIRGs in addition to the prediction of several spectral energy distributions (SEDs) built on data available in the local universe. It has been shown that distant and local LIRGs present similar mid infrared spectral energy distribution: similar PAH bumps are detected in both local and distant LIRGs, however distant LIRGs show evidence of a stronger silicate absorption at 10 microns associated silicate grains. It also shows that distant LIRG mid infrared emission can be used together with local SEDs in order to estimate the total infrared luminosity. The second part of this thesis is dedicated to the burst of star formation and to the recent star formation history of these galaxies, which is responsible for the dust emission. This study was done thanks to a combination of high resolution spectra (R=2000 in the rest frame) obtained at VLT/FORS2 and the stellar population synthesis models called GALAXEV (Bruzual and Charlot, 2003). It has been shown that the burst of star formation has a duration of about 0.1 Gyear. About 10 % of the stellar content is formed during this burst of star formation. (author) [fr

Yb-fiber-pumped mid-infrared picosecond optical parametric oscillator tunable across 6.2-6.7 µm

Science.gov (United States)

Kumar, S. Chaitanya; Casals, J. Canals; Parsa, S.; Zawilski, K. T.; Schunemann, P. G.; Ebrahim-Zadeh, M.

2018-06-01

We report a high-average-power picosecond optical parametric oscillator (OPO) tunable in the mid-infrared (mid-IR) based on CdSiP2 synchronously pumped by an Yb-fiber laser at 80 MHz repetition rate. Successful operation of this high-repetition-rate singly-resonant picosecond OPO has been enabled by the improved CSP crystal quality over a long interaction length. The OPO can be tuned across 1264-1284 nm in the near-IR signal and 6205-6724 nm in the mid-IR idler by temperature tuning the CSP crystal over 39-134 °C. By deploying a 5% output coupler for the resonant signal, we have extracted up to 44 mW of average power in the near-IR and up to 95 mW of non-resonant idler power at 6205 nm at 6.3% total conversion efficiency, with > 50 mW over > 55% of the mid-IR tuning range. We have investigated temperature-tuning characteristics of the OPO and compared the data with the theoretical calculations using the recent Sellmeier and thermo-optic coefficients for CdSiP2. The signal pulses from the OPO exhibit a Gaussian pulse duration of 19 ps centered at 1284 nm. We have also studied the output power stability of the OPO, resulting in a passive stability better than 1.9% rms for the near-IR signal and 2.4% rms for the mid-IR idler, measured over > 17 h, with both beams in high spatial quality.

Two-octave mid-infrared supercontinuum generation in As-Se suspended core fibers

DEFF Research Database (Denmark)

Møller, Uffe Visbech; Petersen, Christian Rosenberg; Kubat, Irnis

2015-01-01

A more than two-octave mid-infrared supercontinuum with an average output power of 15.6 mW covering 1.7-7.5 μm (1,333-5,900 cm-1) is generated in a low-loss As38Se62 suspended core fiber with core diameter of 4.5 μm....

Optical–Mid-infrared Period–Luminosity Relations for W UMa-type Contact Binaries Based on Gaia DR 1: 8% Distance Accuracy

Science.gov (United States)

Chen, Xiaodian; Deng, Licai; de Grijs, Richard; Wang, Shu; Feng, Yuting

2018-06-01

W Ursa Majoris (W UMa)-type contact binary systems (CBs) are useful statistical distance indicators because of their large numbers. Here, we establish (orbital) period–luminosity relations (PLRs) in 12 optical to mid-infrared bands (GBVRIJHK s W1W2W3W4) based on 183 nearby W UMa-type CBs with accurate Tycho–Gaia parallaxes. The 1σ dispersion of the PLRs decreases from optical to near- and mid-infrared wavelengths. The minimum scatter, 0.16 mag, implies that W UMa-type CBs can be used to recover distances to 7% precision. Applying our newly determined PLRs to 19 open clusters containing W UMa-type CBs demonstrates that the PLR and open cluster CB distance scales are mutually consistent to within 1%. Adopting our PLRs as secondary distance indicators, we compiled a catalog of 55,603 CB candidates, of which 80% have distance estimates based on a combination of optical, near-infrared, and mid-infrared photometry. Using Fourier decomposition, 27,318 high-probability W UMa-type CBs were selected. The resulting 8% distance accuracy implies that our sample encompasses the largest number of objects with accurate distances within a local volume with a radius of 3 kpc available to date. The distribution of W UMa-type CBs in the Galaxy suggests that in different environments, the CB luminosity function may be different: larger numbers of brighter (longer-period) W UMa-type CBs are found in younger environments.

Near Infrared High Resolution Spectroscopy and Spectro-astrometry of Gas in Disks around Herbig Ae/Be Stars

OpenAIRE

Brittain, Sean D.; Najita, Joan R.; Carr, John S.

2015-01-01

In this review, we describe how high resolution near infrared spectroscopy and spectro-astrometry have been used to study the disks around Herbig~Ae/Be stars. We show how these tools can be used to identify signposts of planet formation and elucidate the mechanism by which Herbig Ae/Be stars accrete. We also highlight some of the artifacts that can complicate the interpretation of spectro-astrometric measurements and discuss best practices for mitigating these effects. We conclude with a brie...

Two-color mid-infrared spectroscopy of optically doped semiconductors

International Nuclear Information System (INIS)

Forcales, M.; Klik, M.A.J.; Vinh, N.Q.; Phillips, J.; Wells, J-P.R.; Gregorkiewicz, T.

2003-01-01

Optical doping is an attractive method to tailor photonic properties of semiconductor matrices for development of solid-state electroluminescent structures. For practical applications, thermal stability of emission obtained from these materials is required. Thermal processes can be conveniently investigated by two-color spectroscopy in the visible and the mid-infrared. Free-electron laser is a versatile high-brilliance source of radiation in the latter spectral range. In this contribution, we briefly review some of the results obtained recently by the two-color spectroscopy with a free-electron laser in different semiconductors optically doped with rare earth and transition metal ions. Effects leading to both enhancement and quenching of emission from optical dopants will be presented. For InP:Yb, Si:Er, and Si:Cu activation of particular optically induced non-radiative recombination paths will be shown. For Si:Er and Si:Ag, observation of a low temperature optical memory effect will be reported

Performance of the HIRS/2 instrument on TIROS-N. [High Resolution Infrared Radiation Sounder

Science.gov (United States)

Koenig, E. W.

1980-01-01

The High Resolution Infrared Radiation Sounder (HIRS/2) was developed and flown on the TIROS-N satellite as one means of obtaining atmospheric vertical profile information. The HIRS/2 receives visible and infrared spectrum radiation through a single telescope and selects 20 narrow radiation channels by means of a rotating filter wheel. A passive radiant cooler provides an operating temperature of 106.7 K for the HgCdTe and InSb detectors while the visible detector operates at instrument frame temperature. Low noise amplifiers and digital processing provide 13 bit data for spacecraft data multiplexing and transmission. The qualities of system performance that determine sounding capability are the dynamic range of data collection, the noise equivalent radiance of the system, the registration of the air columns sampled in each channel and the ability to upgrade the calibration of the instrument to maintain the performance standard throughout life. The basic features, operating characteristics and performance of the instrument in test are described. Early orbital information from the TIROS-N launched on October 13, 1978 is given and some observations on system quality are made.

Control of Refining Processes on Mid-Distillates by Near Infrared Spectroscopy

Directory of Open Access Journals (Sweden)

Zanier-Szydlowski N.

1999-07-01

Full Text Available The purpose of this paper is to demonstrate the accuracy of physicochemical determinations based on equations calculated by multivariate analysis of near infrared spectra which gives access to simultaneous analyses both on-line and off-line. Detailed results concerning the determination of the refractive index at 20°C, the density, the weight% of hydrogen, the % of aromatic carbon, the weight% of mono-, di- and total aromatics and the cetane number on mid-distillates are given in a shorter time than using the conventional approach by standardized methods. It is shown that near infrared spectroscopy combined with chemometrics should allow detailed and precise comparisons of the hydrotreatment process efficiencies.

Multi-Sensor Fusion of Infrared and Electro-Optic Signals for High Resolution Night Images

Directory of Open Access Journals (Sweden)

Victor Lawrence

2012-07-01

Full Text Available Electro-optic (EO image sensors exhibit the properties of high resolution and low noise level at daytime, but they do not work in dark environments. Infrared (IR image sensors exhibit poor resolution and cannot separate objects with similar temperature. Therefore, we propose a novel framework of IR image enhancement based on the information (e.g., edge from EO images, which improves the resolution of IR images and helps us distinguish objects at night. Our framework superimposing/blending the edges of the EO image onto the corresponding transformed IR image improves their resolution. In this framework, we adopt the theoretical point spread function (PSF proposed by Hardie et al. for the IR image, which has the modulation transfer function (MTF of a uniform detector array and the incoherent optical transfer function (OTF of diffraction-limited optics. In addition, we design an inverse filter for the proposed PSF and use it for the IR image transformation. The framework requires four main steps: (1 inverse filter-based IR image transformation; (2 EO image edge detection; (3 registration; and (4 blending/superimposing of the obtained image pair. Simulation results show both blended and superimposed IR images, and demonstrate that blended IR images have better quality over the superimposed images. Additionally, based on the same steps, simulation result shows a blended IR image of better quality when only the original IR image is available.

A COMPREHENSIVE SEARCH FOR STELLAR BOWSHOCK NEBULAE IN THE MILKY WAY: A CATALOG OF 709 MID-INFRARED SELECTED CANDIDATES

Energy Technology Data Exchange (ETDEWEB)

Kobulnicky, Henry A.; Chick, William T.; Schurhammer, Danielle P.; Andrews, Julian E.; Munari, Stephan A.; Olivier, Grace M.; Sorber, Rebecca L.; Wernke, Heather N.; Dale, Daniel A. [Dept. of Physics and Astronomy, University of Wyoming, Laramie, WY 82070 (United States); Povich, Matthew S.; Dixon, Don M. [Department of Physics and Astronomy, California State Polytechnic University, 3801 West Temple Avenue, Pomona, CA 91768 (United States)

2016-12-01

We identify 709 arc-shaped mid-infrared nebula in 24 μ m Spitzer Space Telescope or 22 μ m Wide Field Infrared Explorer surveys of the Galactic Plane as probable dusty interstellar bowshocks powered by early-type stars. About 20% are visible at 8 μ m or at shorter mid-infrared wavelengths. The vast majority (660) have no previous identification in the literature. These extended infrared sources are strongly concentrated near the Galactic mid-plane, with an angular scale height of ∼0.°6. All host a symmetrically placed star implicated as the source of a stellar wind sweeping up interstellar material. These are candidate “runaway” stars potentially having high velocities in the reference frame of the local medium. Among the 286 objects with measured proper motions, we find an unambiguous excess with velocity vectors aligned with the infrared morphology—kinematic evidence that many of these are “runaway” stars with large peculiar motions responsible for the bowshock signature. We discuss a population of “in situ” bowshocks (∼103 objects) that face giant H ii regions where the relative motions between the star and ISM may be caused by bulk outflows from an overpressured bubble. We also identify ∼58 objects that face 8 μ m bright-rimmed clouds and apparently constitute a sub-class of in situ bowshocks where the stellar wind interacts with a photoevaporative flow (PEF) from an eroding molecular cloud interface (i.e., “PEF bowshocks”). Orientations of the arcuate nebulae exhibit a correlation over small angular scales, indicating that external influences such as H ii regions are responsible for producing some bowshock nebulae. However, the vast majority of the nebulae in this sample appear to be isolated (499 objects) from obvious external influences.

Study of starburst galaxies and active galactic nuclei in the mid-infrared with the ISOCAM instrument

International Nuclear Information System (INIS)

Laurent, Olivier

1999-01-01

This thesis is dedicated to the study of starburst galaxies and active galactic nuclei (AGNs) in the mid-infrared between 3 and 16 μm with the ISOCAM instrument. The study of nearby prototypical galaxies such as NGC 1068 and M 82 lead me to decompose the emission into three components. The star forming regions are characterized by (1) the infrared bands at 6.2, 7.7, 8.6, 11.3 and 12.7 μm originating from the photo-dissociation regions and also by (2) a continuum at 15 μm produced by the very small grains in HII regions. I show that AGNs have (3) strong continuum with an important contribution between 3 and 10 μm arising from hot dust heated to high temperatures of the order of 1000 K. I present two diagnostic diagrams based on the spectral properties of the three components allowing me to distinguish AGNs from starburst regions. In interacting galaxies, I show that some extra-nuclear regions harboring starburst activity can dominate the emission at 15 μm as in the Cartwheel and the Antennae galaxies. Using mid-infrared spectral features, I also define two prototypes of ultra-luminous galaxies dominated either by starburst activity in the case of Arp 220 or by the AGN in the Super-Antennae galaxy (IRAS 19254-7245). I explain how this diagram and the selection criteria evolve according to redshift. Finally, I show how we can develop new diagnostics using filters of the IRAC instrument on board the next infrared space observatory SIRTF. (author) [fr

Optical - Near Infrared Photometric Calibration of M-dwarf Metallicity and Its Application

OpenAIRE

Hejazi, Neda; De Robertis, Michael M.; Dawson, Peter C.

2015-01-01

Based on a carefully constructed sample of dwarf stars, a new optical-near infrared photometric calibration to estimate the metallicity of late-type K and early-to-mid-type M dwarfs is presented. The calibration sample has two parts; the first part includes 18 M dwarfs with metallicities determined by high-resolution spectroscopy and the second part contains 49 dwarfs with metallicities obtained through moderate-resolution spectra. By applying this calibration to a large sample of around 1.3 ...

Source brightness fluctuation correction of solar absorption fourier transform mid infrared spectra

Directory of Open Access Journals (Sweden)

T. Ridder

2011-06-01

Full Text Available The precision and accuracy of trace gas observations using solar absorption Fourier Transform infrared spectrometry depend on the stability of the light source. Fluctuations in the source brightness, however, cannot always be avoided. Current correction schemes, which calculate a corrected interferogram as the ratio of the raw DC interferogram and a smoothed DC interferogram, are applicable only to near infrared measurements. Spectra in the mid infrared spectral region below 2000 cm⁻¹ are generally considered uncorrectable, if they are measured with a MCT detector. Such measurements introduce an unknown offset to MCT interferograms, which prevents the established source brightness fluctuation correction. This problem can be overcome by a determination of the offset using the modulation efficiency of the instrument. With known modulation efficiency the offset can be calculated, and the source brightness correction can be performed on the basis of offset-corrected interferograms. We present a source brightness fluctuation correction method which performs the smoothing of the raw DC interferogram in the interferogram domain by an application of a running mean instead of high-pass filtering the corresponding spectrum after Fourier transformation of the raw DC interferogram. This smoothing can be performed with the onboard software of commercial instruments. The improvement of MCT spectra and subsequent ozone profile and total column retrievals is demonstrated. Application to InSb interferograms in the near infrared spectral region proves the equivalence with the established correction scheme.

Ultra-High Resolution Spectroscopic Remote Sensing: A Microscope on Planetary Atmospheres

Science.gov (United States)

Kostiuk, Theodor

2010-01-01

Remote sensing of planetary atmospheres is not complete without studies of all levels of the atmosphere, including the dense cloudy- and haze filled troposphere, relatively clear and important stratosphere and the upper atmosphere, which are the first levels to experience the effects of solar radiation. High-resolution spectroscopy can provide valuable information on these regions of the atmosphere. Ultra-high spectral resolution studies can directly measure atmospheric winds, composition, temperature and non-thermal phenomena, which describe the physics and chemistry of the atmosphere. Spectroscopy in the middle to long infrared wavelengths can also probe levels where dust of haze limit measurements at shorter wavelength or can provide ambiguous results on atmospheric species abundances or winds. A spectroscopic technique in the middle infrared wavelengths analogous to a radio receiver. infrared heterodyne spectroscopy [1], will be describe and used to illustrate the detailed study of atmospheric phenomena not readily possible with other methods. The heterodyne spectral resolution with resolving power greater than 1,000.000 measures the true line shapes of emission and absorption lines in planetary atmospheres. The information on the region of line formation is contained in the line shapes. The absolute frequency of the lines can be measured to I part in 100 ,000,000 and can be used to accurately measure the Doppler frequency shift of the lines, directly measuring the line-of-sight velocity of the gas to --Im/s precision (winds). The technical and analytical methods developed and used to measure and analyze infrared heterodyne measurements will be described. Examples of studies on Titan, Venus, Mars, Earth, and Jupiter will be presented. 'These include atmospheric dynamics on slowly rotating bodies (Titan [2] and Venus [3] and temperature, composition and chemistry on Mars 141, Venus and Earth. The discovery and studies of unique atmospheric phenomena will also be

Detection of water leakage in buried pipes using infrared technology; a comparative study of using high and low resolution infrared cameras for evaluating distant remote detection

OpenAIRE

Shakmak, B; Al-Habaibeh, A

2015-01-01

Water is one of the most precious commodities around the world. However, significant amount of water is lost daily in many countries through broken and leaking pipes. This paper investigates the use of low and high resolution infrared systems to detect water leakage in relatively dry countries. The overall aim is to develop a non-contact and high speed system that could be used to detect leakage in pipes remotely via the effect of the change in humidity on the temperature of the ground due to...

Generation of 70-fs pulses at 286 μm from a mid-infrared fiber laser

Science.gov (United States)

Woodward, R. I.; Hudson, D. D.; Fuerbach, A.; Jackson, S. D.

2017-12-01

We propose and demonstrate a simple route to few-optical-cycle pulse generation from a mid-infrared fiber laser through nonlinear compression of pulses from a holmium-doped fiber oscillator using a short length of chalcogenide fiber and a grating pair. Pulses from the oscillator with 265-fs duration at 2.86 {\\mu}m are spectrally broadened through self-phase modulation in step-index As2S3 fiber to 141-nm bandwidth and then re-compressed to 70 fs (7.3 optical cycles). These are the shortest pulses from a mid-infrared fiber system to date, and we note that our system is compact, robust, and uses only commercially available components. The scalability of this approach is also discussed, supported by numerical modeling.

Human Milk Analysis Using Mid-Infrared Spectroscopy.

Science.gov (United States)

Groh-Wargo, Sharon; Valentic, Jennifer; Khaira, Sharmeel; Super, Dennis M; Collin, Marc

2016-04-01

The composition of human milk is known to vary with length of gestation, stage of lactation, and other factors. Human milk contains all nutrients required for infant health but requires fortification to meet the needs of low-birth-weight infants. Without a known nutrient profile of the mother's milk or donor milk fed to a baby, the composition of the fortified product is only an estimate. Human milk analysis has the potential to improve the nutrition care of high-risk newborns by increasing the information about human milk composition. Equipment to analyze human milk is available, and the technology is rapidly evolving. This pilot study compares mid-infrared (MIR) spectroscopy to reference laboratory milk analysis. After obtaining informed consent, we collected human milk samples from mothers of infants weighing milk obtained by MIR vs reference laboratory analysis. MIR analysis appears to provide an accurate assessment of macronutrient content in expressed human milk from mothers of preterm infants. The small sample size of this study limits confidence in the results. Measurement of lactose is confounded by the presence of oligosaccharides. Human milk analysis is a potentially useful tool for establishing an individualized fortification plan. © 2015 American Society for Parenteral and Enteral Nutrition.

Comparison of infrared spectroscopy techniques: developing an efficient method for high resolution analysis of sediment properties from long records

Science.gov (United States)

Hahn, Annette; Rosén, Peter; Kliem, Pierre; Ohlendorf, Christian; Persson, Per; Zolitschka, Bernd; Pasado Science Team

2010-05-01

The analysis of sediment samples in visible to mid-infrared spectra is ideal for high-resolution records. It requires only small amounts (0.01-0.1g dry weight) of sample material and facilitates rapid and cost efficient analysis of a wide variety of biogeochemical properties on minerogenic and organic substances (Kellner et al. 1998). One of these techniques, the Diffuse Reflectance Fourier Transform Infrared Spectrometry (DRIFTS), has already been successfully applied to lake sediment from very different settings and has shown to be a promising technique for high resolution analyses of long sedimentary records on glacial-interglacial timescales (Rosén et al. 2009). However, the DRIFTS technique includes a time-consuming step where sediment samples are mixed with KBr. To assess if alternative and more rapid infrared (IR) techniques can be used, four different IR spectroscopy techniques are compared for core catcher sediment samples from Laguna Potrok Aike - an ICDP site located in southernmost South America. Partial least square (PLS) calibration models were developed using the DRIFTS technique. The correlation coefficients (R) for correlations between DRIFTS-inferred and conventionally measured biogeochemical properties show values of 0.80 for biogenic silica (BSi), 0.95 for total organic carbon (TOC), 0.91 for total nitrogen (TN), and 0.92 for total inorganic carbon (TIC). Good statistical performance was also obtained by using the Attenuated Total Reflectance Fourier Transform Infrared Spectroscopy ATR-FTIRS technique which requires less sample preparation. Two devices were used, the full-sized Bruker Equinox 252 and the smaller and less expensive Bruker Alpha. R for ATR-FTIRS-inferred and conventionally measured biogeochemical properties were 0.87 (BSi), 0.93 (TOC), 0.90 (TN), and 0.91 (TIC) for the Alpha, and 0.78 (TOC), 0.85 (TN), 0.79 (TIC) for the Equinox 252 device. As the penetration depth of the IR beam is frequency dependent, a firm surface contact of

Determination of carbohydrates present in Saccharomyces cerevisiae using mid-infrared spectroscopy and partial least squares regression.

Science.gov (United States)

Plata, Maria R; Koch, Cosima; Wechselberger, Patrick; Herwig, Christoph; Lendl, Bernhard

2013-10-01

A fast and simple method to control variations in carbohydrate composition of Saccharomyces cerevisiae, baker's yeast, during fermentation was developed using mid-infrared (mid-IR) spectroscopy. The method allows for precise and accurate determinations with minimal or no sample preparation and reagent consumption based on mid-IR spectra and partial least squares (PLS) regression. The PLS models were developed employing the results from reference analysis of the yeast cells. The reference analyses quantify the amount of trehalose, glucose, glycogen, and mannan in S. cerevisiae. The selection and optimization of pretreatment steps of samples such as the disruption of the yeast cells and the hydrolysis of mannan and glycogen to obtain monosaccharides were carried out. Trehalose, glucose, and mannose were determined using high-performance liquid chromatography coupled with a refractive index detector and total carbohydrates were measured using the phenol-sulfuric method. Linear concentration range, accuracy, precision, LOD and LOQ were examined to check the reliability of the chromatographic method for each analyte.

Simultaneous generation of tunable giant dispersive waves in the visible and mid-infrared regions based on photonic crystal fibers

International Nuclear Information System (INIS)

Zhang, Lei; Yang, Si-Gang; Chen, Hong-Wei; Chen, Ming-Hua; Xie, Shi-Zhong; Han, Ying

2013-01-01

Cherenkov radiation (CR) in both the visible and mid-infrared regions is simultaneously generated experimentally based on a photonic crystal fiber with two zero-dispersion wavelengths. The generation of CR in the visible region originates from solitons located in the anomalous group velocity dispersion (GVD) regime which are perturbed by positive third order dispersion. Conversely, the generation of CR in the mid-infrared region requires that the solitons in the anomalous GVD regime are perturbed by negative third order dispersion. The peak wavelength of the CR in the visible region can be tuned from 498 to 425 nm by increasing the average input pump power from 70 to 400 mW, while the peak wavelength of the CR in the mid-infrared region can be tuned from 1986 to 2279 nm by increasing the average input pump power from 70 to 320 mW. (paper)

High-Resolution Spectroscopy of Stratospheric Ethane Following the Jupiter Impact of 2009

Science.gov (United States)

Fast, Kelly; Kostiuk, Theodor; Livengood, Timothy A.; Hewagama, Tilak; Amen, John

2010-01-01

We report on high-resolution infrared spectroscopy of ethane (C2H6) performed at the latitude of an impact site on Jupiter discovered on 19 July 2009 by A. Wesley from a location in Murrumbateman, Australia. The observations used the NASA Goddard Space Flight Center's Heterodyne Instrument for Planetary Wind and Composition (HIPWAC) at the NASA Infrared Telescope Facility (IRTF) on Mauna Kea, Hawaii. HIPWAC is a mid-infrared (9-12 microns) heterodyne spectrometer operating at the highest limit of spectral resolving power (lambda\\Delta\\lambda > l06), providing information on atmospheric constituent abundance and temperature through fully resolved tine shapes. Ethane is a stable trace product of methane photochemistry that is nearly uniformly mixed in Jupiter's stratosphere, providing an effective probe of that altitude region. Ethane emission line profiles near 11,74 microns in the Ug band were measured in Jupiter's stratosphere at 25 MHz (11.00083/cm) resolution. A sequence of spectra of ethane acquired over a range of longitude at the impact latitude (56S planetocentric) probes constituent abundance and temperature profile, both on and off the impact region. Near the site of the impact, ethane emission increased above levels measured well outside the impact region. Radiative transfer analysis indicates increased ethane mole fraction (30% greater). Variation in the measured continuum level and line intensities within 75deg of the impact longitude indicate the presence of an opacity source (haze) at altitudes near and above the tropopause and as high as the 10-mbar level near the impact site. The indication of possible haze opacity up to the 10-mbar level in the atmosphere is consistent with measurements made by HIPWAC's predecessor as part of the IRTF Shoemaker Levy-9 campaign in 1994.

AN INTERFEROMETRIC STUDY OF THE FOMALHAUT INNER DEBRIS DISK. II. KECK NULLER MID-INFRARED OBSERVATIONS

Energy Technology Data Exchange (ETDEWEB)

Mennesson, B.; Serabyn, E.; Colavita, M. M. [Jet Propulsion Laboratory, California Institute of Technology, 4800 Oak Grove Drive, Pasadena CA 91109-8099 (United States); Absil, O. [Departement d' Astrophysique, Geophysique et Oceanographie, Universite de Liege, 17 Allee du Six Aout, B-4000 Sart Tilman (Belgium); Lebreton, J.; Augereau, J.-C. [IPAG, UMR 5274, CNRS and Universite Joseph Fourier, BP 53, F-38041 Grenoble (France); Millan-Gabet, R. [Michelson Science Center, California Institute of Technology, 770 South Wilson Avenue, Pasadena CA 91125 (United States); Liu, W. [Infrared Processing and Analysis Center, California Institute of Technology, Mail Code 100-22, Pasadena, CA 91125 (United States); Hinz, P. [Steward Observatory, University of Arizona, 933 N Cherry Avenue, Tucson, AZ 85721 (United States); Thebault, P. [Observatoire de Paris, Section de Meudon, F-92195 Meudon Principal Cedex (France)

2013-02-15

We report on high-contrast mid-infrared observations of Fomalhaut obtained with the Keck Interferometer Nuller (KIN) showing a small resolved excess over the level expected from the stellar photosphere. The measured null excess has a mean value of 0.35% {+-} 0.10% between 8 and 11 {mu}m and increases from 8 to 13 {mu}m. Given the small field of view of the instrument, the source of this marginal excess must be contained within 2 AU of Fomalhaut. This result is reminiscent of previous VLTI K-band ({approx_equal}2{mu}m) observations, which implied the presence of a {approx}0.88% excess, and argued that thermal emission from hot dusty grains located within 6 AU from Fomalhaut was the most plausible explanation. Using a parametric two-dimensional radiative transfer code and a Bayesian analysis, we examine different dust disk structures to reproduce both the near- and mid-infrared data simultaneously. While not a definitive explanation of the hot excess of Fomalhaut, our model suggests that the most likely inner few AU disk geometry consists of a two-component structure, with two different and spatially distinct grain populations. The 2-11 {mu}m data are consistent with an inner hot ring of very small ({approx_equal}10-300 nm) carbon-rich grains concentrating around 0.1 AU. The second dust population-inferred from the KIN data at longer mid-infrared wavelengths-consists of larger grains (size of a few microns to a few tens of microns) located further out in a colder region where regular astronomical silicates could survive, with an inner edge around 0.4 AU-1 AU. From a dynamical point of view, the presence of the inner concentration of submicron-sized grains is surprising, as such grains should be expelled from the inner planetary system by radiation pressure within only a few years. This could either point to some inordinate replenishment rates (e.g., many grazing comets coming from an outer reservoir) or to the existence of some braking mechanism preventing the grains

Highly doped InP as a low loss plasmonic material for mid-IR region.

Science.gov (United States)

Panah, M E Aryaee; Takayama, O; Morozov, S V; Kudryavtsev, K E; Semenova, E S; Lavrinenko, A V

2016-12-12

We study plasmonic properties of highly doped InP in the mid-infrared (IR) range. InP was grown by metal-organic vapor phase epitaxy (MOVPE) with the growth conditions optimized to achieve high free electron concentrations by doping with silicon. The permittivity of the grown material was found by fitting the calculated infrared reflectance spectra to the measured ones. The retrieved permittivity was then used to simulate surface plasmon polaritons (SPPs) propagation on flat and structured surfaces, and the simulation results were verified in direct experiments. SPPs at the top and bottom interfaces of the grown epilayer were excited by the prism coupling. A high-index Ge hemispherical prism provides efficient coupling conditions of SPPs on flat surfaces and facilitates acquiring their dispersion diagrams. We observed diffraction into symmetry-prohibited diffraction orders stimulated by the excitation of surface plasmon-polaritons in a periodically structured epilayer. Characterization shows good agreement between the theory and experimental results and confirms that highly doped InP is an effective plasmonic material aiming it for applications in the mid-IR wavelength range.

Towards strong light-matter coupling at the single-resonator level with sub-wavelength mid-infrared nano-antennas

Energy Technology Data Exchange (ETDEWEB)

Malerba, M.; De Angelis, F., E-mail: francesco.deangelis@iit.it [Istituto Italiano di Tecnologia, Via Morego, 30, I-16163 Genova (Italy); Ongarello, T.; Paulillo, B.; Manceau, J.-M.; Beaudoin, G.; Sagnes, I.; Colombelli, R., E-mail: raffaele.colombelli@u-psud.fr [Centre for Nanoscience and Nanotechnology (C2N Orsay), CNRS UMR9001, Univ. Paris Sud, Univ. Paris Saclay, 91405 Orsay (France)

2016-07-11

We report a crucial step towards single-object cavity electrodynamics in the mid-infrared spectral range using resonators that borrow functionalities from antennas. Room-temperature strong light-matter coupling is demonstrated in the mid-infrared between an intersubband transition and an extremely reduced number of sub-wavelength resonators. By exploiting 3D plasmonic nano-antennas featuring an out-of-plane geometry, we observed strong light-matter coupling in a very low number of resonators: only 16, more than 100 times better than what reported to date in this spectral range. The modal volume addressed by each nano-antenna is sub-wavelength-sized and it encompasses only ≈4400 electrons.

Extraordinary mid-infrared transmission of subwavelength holes in gold films

KAUST Repository

Yue, Weisheng

2014-04-01

Gold (Au) nanoholes are fabricated with electron-beam lithography and used for the investigation of extraordinary transmission in mid-infrared regime. Transmission properties of the nanoholes are studied as the dependence on hole-size. Transmittance spectra are characterized by Fourier transform infrared spectroscopy (FTIR) and enhanced transmittance through the subwavelength holes is observed. The transmission spectra exhibit well-defined maximum and minimum of which the position are determined by the lattice of the hole array. The hole-size primarily influence the transmission intensity and bandwidth of the resonance peak. With an increase of hole-size, while keep lattice constant fixed, the intensity of the resonance peak and the bandwidth increases, which are due to the localized surface plasmons. Numerical simulation for the transmission through the subwavelength holes is performed and the simulated results agree with the experimental observations. Copyright © 2014 American Scientific Publishers.

Extraordinary mid-infrared transmission of subwavelength holes in gold films

KAUST Repository

Yue, Weisheng; Wang, Zhihong; Yang, Yang; Chen, Longqing; Syed, Ahad A.; Wang, Xianbin

2014-01-01

Gold (Au) nanoholes are fabricated with electron-beam lithography and used for the investigation of extraordinary transmission in mid-infrared regime. Transmission properties of the nanoholes are studied as the dependence on hole-size. Transmittance spectra are characterized by Fourier transform infrared spectroscopy (FTIR) and enhanced transmittance through the subwavelength holes is observed. The transmission spectra exhibit well-defined maximum and minimum of which the position are determined by the lattice of the hole array. The hole-size primarily influence the transmission intensity and bandwidth of the resonance peak. With an increase of hole-size, while keep lattice constant fixed, the intensity of the resonance peak and the bandwidth increases, which are due to the localized surface plasmons. Numerical simulation for the transmission through the subwavelength holes is performed and the simulated results agree with the experimental observations. Copyright © 2014 American Scientific Publishers.

LOCUSS: THE MID-INFRARED BUTCHER-OEMLER EFFECT

International Nuclear Information System (INIS)

Haines, C. P.; Smith, G. P.; Sanderson, A. J. R.; Egami, E.; Ellis, R. S.; Moran, S. M.; Merluzzi, P.; Busarello, G.; Smith, R. J.

2009-01-01

We study the mid-infrared (MIR) properties of galaxies in 30 massive galaxy clusters at 0.02 ≤ z ≤ 0.40, using panoramic Spitzer/MIPS 24 μm and near-infrared data, including 27 new observations from the LoCuSS and ACCESS surveys. This is the largest sample of clusters to date with such high-quality and uniform MIR data covering not only the cluster cores, but extending into the infall regions. We use these data to revisit the so-called Butcher-Oemler (BO) effect, measuring the fraction of massive infrared luminous galaxies (K IR > 5 x 10 10 L sun ) within r 200 , finding a steady increase in the fraction with redshift from ∼3% at z = 0.02 to ∼10% by z = 0.30, and an rms cluster-to-cluster scatter about this trend of 0.03. The best-fit redshift evolution model of the form f SF ∝ (1 + z) n has n = 5.7 +2.1 -1.8 , which is stronger redshift evolution than that of L* IR in both clusters and the field. We find that, statistically, this excess is associated with galaxies found at large cluster-centric radii, specifically r 500 200 , implying that the MIR BO effect can be explained by a combination of both the global decline in star formation in the universe since z ∼ 1 and enhanced star formation in the infall regions of clusters at intermediate redshifts. This picture is supported by a simple infall model based on the Millennium Simulation semianalytic galaxy catalogs, whereby star formation in infalling galaxies is instantaneously quenched upon their first passage through the cluster, in that the observed radial trends of f SF trace those inferred from the simulations. The observed f SF values, however, lie systematically above the predictions, suggesting an overall excess of star formation, either due to triggering by environmental processes, or a gradual quenching. We also find that f SF does not depend on simple indicators of the dynamical state of clusters, including the offset between the brightest cluster galaxy and the peak of the X-ray emission

Influence of spectral resolution, spectral range and signal-to-noise ratio of Fourier transform infra-red spectra on identification of high explosive substances

Science.gov (United States)

Banas, Krzysztof; Banas, Agnieszka M.; Heussler, Sascha P.; Breese, Mark B. H.

2018-01-01

In the contemporary spectroscopy there is a trend to record spectra with the highest possible spectral resolution. This is clearly justified if the spectral features in the spectrum are very narrow (for example infra-red spectra of gas samples). However there is a plethora of samples (in the liquid and especially in the solid form) where there is a natural spectral peak broadening due to collisions and proximity predominately. Additionally there is a number of portable devices (spectrometers) with inherently restricted spectral resolution, spectral range or both, which are extremely useful in some field applications (archaeology, agriculture, food industry, cultural heritage, forensic science). In this paper the investigation of the influence of spectral resolution, spectral range and signal-to-noise ratio on the identification of high explosive substances by applying multivariate statistical methods on the Fourier transform infra-red spectral data sets is studied. All mathematical procedures on spectral data for dimension reduction, clustering and validation were implemented within R open source environment.

Near-infrared to Mid-infrared Observations of Galaxy Mergers: NGC 2782 and NGC 7727

Science.gov (United States)

Onaka, Takashi; Nakamura, Tomohiko; Sakon, Itsuki; Wu, Ronin; Ohsawa, Ryou; Kaneda, Hidehiro; Lebouteiller, Vianney; Roellig, Thomas L.

2018-01-01

We present the results of near-infrared-to-mid-infrared (NIR-to-MIR) imaging and NIR spectroscopic observations of two galaxy mergers, NGC 2782 (Arp 215) and NGC 7727 (Arp 222), with the Infrared Camera on board AKARI. NGC 2782 shows extended MIR emission in the eastern side of the galaxy, which corresponds to the eastern tidal tail seen in the H I 21 cm map, while NGC 7727 shows extended MIR emission in the north of the galaxy, which is similar to the plumes seen in the residual image at the K-band after subtracting a galaxy model. Both extended structures are thought to have formed in association with their merger events. They show excess emission at 7–15 μm, which can be attributed to emission from polycyclic aromatic hydrocarbons (PAHs), while the observed spectral energy distributions (SEDs) decline longward of 24 μm, suggesting that very small grains (VSGs) are deficient. These characteristics of the observed MIR SED may be explained if PAHs are formed by fragmentation of VSGs during merger events. The star formation rate is estimated from the MIR PAH emission in the eastern tail region of NGC 2782 and it is in fair agreement with those estimated from Hα and [C II] 158 μm. MIR observations are efficient for the study of dust processing and structures formed during merger events.

High-Resolution Near-Infrared Spectroscopy of FU Orionis Objects

Science.gov (United States)

Hartmann, Lee; Hinkle, Kenneth; Calvet, Nuria

2004-07-01

We present an analysis of recent near-infrared, high-resolution spectra of the variable FU Ori objects. During a phase of rapid fading in optical brightness during 1997, V1057 Cyg exhibited shell absorption in first-overtone (v''-v'=2-0) CO lines, blueshifted by about 50 km s-1 from the system velocity. This shell component had not been seen previously, nor was it present in 1999, although some blueshifted absorption asymmetry is seen at the latter epoch. The appearance of this CO absorption shell is connected with the roughly contemporaneous appearance of blueshifted, low-excitation optical absorption lines with comparable low velocities; we suggest that this shell was also responsible for some of the peculiar emission features seen in red-optical spectra of V1057 Cyg. FU Ori continues to exhibit broad CO lines, with some evidence for the double-peaked profiles characteristic of an accretion disk; the line profiles are consistent with previous observations. Both FU Ori and V1057 Cyg continue to exhibit lower rotational broadening at 2.3 μm than at optical wavelengths, in agreement with the prediction of differentially rotating disk models; we have a marginal detection of the same effect in V1515 Cyg. The relative population of the first-overtone CO rotational levels in the FU Ori objects suggests low excitation temperatures. We compare disk models to the observations and find agreement with overall line strengths and rotational broadening, but the observed line profiles are generally less double-peaked than predicted. We suggest that the discrepancy in line profiles is due to turbulent motions in FU Ori disks, an effect qualitatively predicted by recent simulations of the magnetorotational instability in vertically stratified accretion disks. Based on observations obtained at the Gemini Observatory, which is operated by the Association of Universities for Research in Astronomy (AURA), Inc., under a cooperative agreement with the NSF, on behalf of the Gemini

Supercontinuum - broad as a lamp, bright as a laser, now in the mid-infrared

DEFF Research Database (Denmark)

Moselund, Peter M.; Petersen, Christian; Dupont, Sune

2012-01-01

Based on the experience gained developing our market leading visible spectrum supercontinuum sources NKT Photonics has built the first mid-infrared supercontinuum source based on modelocked picosecond fiber lasers. The source is pumped by a ≈ 2 um laser based on a combination of erbium and thuliu...

Geomagnetic Paleointensity Variations as a Cheap, High-Resolution Geochronometer for Recent Mid-Ocean Ridge Processes

Science.gov (United States)

DYMENT, J.; HEMOND, C.

2001-12-01

of the data confirms the quality of the oceanic crust as a recorder of the geomagnetic variations. Future work in the framework of Project GIMNAUT include 1) the processing and interpretation of the available magnetic signals to obtain a detailed sequence of the geomagnetic fluctuations for the last 800 ka; 2) the dating of collected samples with different radiochronologic methods such as K-Ar and Ar-Ar for samples older than 100-150 ka and 230Th-238U for samples aged between 300-10 ka; and 3) the calibration of the geomagnetic intensity variation sequence as a high resolution geochronometer for the last 800 ka. Such a magnetic geochronometer would present an obvious interest for mid-ocean ridge studies, because of its low cost and simplicity of operation: it would only require the addition of a deep-sea magnetometer onto existing means of investigation such as submersibles, ROVs or AUVs. Beyond this application, this magnetic geochronometer could also be used for accurate dating of pelagic sedimentary sequences, through the analysis of relative paleointensities on cores, or of continental or island volcanic flows, through the determination of absolute paleointensities by the Thellier-Thellier method. (*) N. Arnaud, C. Bassoullet, M.. Benoit, A. Briais, F. Chabaux, A.K. Chaubey, A. Chauvin, P. Gente, H. Guillou, H. Horen, M. Kitazawa, B. Le Gall, M. Maia, M. Ravilly

Fugitive methane leak detection using mid-infrared hollow-core photonic crystal fiber containing ultrafast laser drilled side-holes

Science.gov (United States)

Karp, Jason; Challener, William; Kasten, Matthias; Choudhury, Niloy; Palit, Sabarni; Pickrell, Gary; Homa, Daniel; Floyd, Adam; Cheng, Yujie; Yu, Fei; Knight, Jonathan

2016-05-01

The increase in domestic natural gas production has brought attention to the environmental impacts of persistent gas leakages. The desire to identify fugitive gas emission, specifically for methane, presents new sensing challenges within the production and distribution supply chain. A spectroscopic gas sensing solution would ideally combine a long optical path length for high sensitivity and distributed detection over large areas. Specialty micro-structured fiber with a hollow core can exhibit a relatively low attenuation at mid-infrared wavelengths where methane has strong absorption lines. Methane diffusion into the hollow core is enabled by machining side-holes along the fiber length through ultrafast laser drilling methods. The complete system provides hundreds of meters of optical path for routing along well pads and pipelines while being interrogated by a single laser and detector. This work will present transmission and methane detection capabilities of mid-infrared photonic crystal fibers. Side-hole drilling techniques for methane diffusion will be highlighted as a means to convert hollow-core fibers into applicable gas sensors.

Authentication of Whey Protein Powders by Portable Mid-Infrared Spectrometers Combined with Pattern Recognition Analysis.

Science.gov (United States)

Wang, Ting; Tan, Siow Ying; Mutilangi, William; Aykas, Didem P; Rodriguez-Saona, Luis E

2015-10-01

The objective of this study was to develop a simple and rapid method to differentiate whey protein types (WPC, WPI, and WPH) used for beverage manufacturing by combining the spectral signature collected from portable mid-infrared spectrometers and pattern recognition analysis. Whey protein powders from different suppliers are produced using a large number of processing and compositional variables, resulting in variation in composition, concentration, protein structure, and thus functionality. Whey protein powders including whey protein isolates, whey protein concentrates and whey protein hydrolysates were obtained from different suppliers and their spectra collected using portable mid-infrared spectrometers (single and triple reflection) by pressing the powder onto an Attenuated Total Reflectance (ATR) diamond crystal with a pressure clamp. Spectra were analyzed by soft independent modeling of class analogy (SIMCA) generating a classification model showing the ability to differentiate whey protein types by forming tight clusters with interclass distance values of >3, considered to be significantly different from each other. The major bands centered at 1640 and 1580 cm(-1) were responsible for separation and were associated with differences in amide I and amide II vibrations of proteins, respectively. Another important band in whey protein clustering was associated with carboxylate vibrations of acidic amino acids (∼1570 cm(-1)). The use of a portable mid-IR spectrometer combined with pattern recognition analysis showed potential for discriminating whey protein ingredients that can help to streamline the analytical procedure so that it is more applicable for field-based screening of ingredients. A rapid, simple and accurate method was developed to authenticate commercial whey protein products by using portable mid-infrared spectrometers combined with chemometrics, which could help ensure the functionality of whey protein ingredients in food applications. © 2015

High-Resolution Infrared Spectroscopic Observations of the Upper Scorpius Eclipsing Binary EPIC 203868608

Science.gov (United States)

Johnson, Marshall C.; Mace, Gregory N.; Kim, Hwihyun; Kaplan, Kyle; McLane, Jacob; Sokal, Kimberly R.

2017-06-01

EPIC 203868608 is a source in the ~10 Myr old Upper Scorpius OB association. Using K2 photometry and ground-based follow-up observations, David et al. (2016) found that it consists of two brown dwarfs with a tertiary object at a projected separation of ~20 AU; the former objects appear to be a double-lined eclipsing binary with a period of 4.5 days. This is one of only two known eclipsing SB2s where both components are below the hydrogen-burning limit. We present additional follow-up observations of this system from the IGRINS high-resolution near-infrared spectrograph at McDonald Observatory. Our measured radial velocities do not follow the orbital solution presented by David et al. (2016). Instead, our combined IGRINS plus literature radial velocity dataset appears to indicate a period significantly different than that of the eclipsing binary obvious from the K2 light curve. We will discuss possible scenarios to account for the conflicting observations of this system.

Mid-infrared, long wave infrared (4-12 μm) molecular emission signatures from pharmaceuticals using laser-induced breakdown spectroscopy (LIBS).

Science.gov (United States)

Yang, Clayton S-C; Brown, Ei E; Kumi-Barimah, Eric; Hommerich, Uwe H; Jin, Feng; Trivedi, Sudhir B; Samuels, Alan C; Snyder, A Peter

2014-01-01

In an effort to augment the atomic emission spectra of conventional laser-induced breakdown spectroscopy (LIBS) and to provide an increase in selectivity, mid-wave to long-wave infrared (IR), LIBS studies were performed on several organic pharmaceuticals. Laser-induced breakdown spectroscopy signature molecular emissions of target organic compounds are observed for the first time in the IR fingerprint spectral region between 4-12 μm. The IR emission spectra of select organic pharmaceuticals closely correlate with their respective standard Fourier transform infrared spectra. Intact and/or fragment sample molecular species evidently survive the LIBS event. The combination of atomic emission signatures derived from conventional ultraviolet-visible-near-infrared LIBS with fingerprints of intact molecular entities determined from IR LIBS promises to be a powerful tool for chemical detection.

Mesoscopic modeling of the response of human dental enamel to mid-infrared radiation

Science.gov (United States)

Vila Verde, Ana; Ramos, Marta; Stoneham, A. M.

2006-03-01

Ablation of human dental enamel, a composite biomaterial with water pores, is of significant importance in minimally invasive laser dentistry but progress in the area is hampered by the lack of optimal laser parameters. We use mesoscopic finite element models of this material to study its response to mid-infrared radiation. Our results indicate that the cost-effective, off-the-shelf CO2 laser at λ = 10.6 μm may in fact ablate enamel precisely, reproducibly and with limited unwanted side effects such as cracking or heating, provided that a pulse duration of 10 μs is used. Furthermore, our results also indicate that the Er:YAG laser (λ = 2.94 μm), currently popular for laser dentistry, may in fact cause unwanted deep cracking in the enamel when regions with unusually high water content are irradiated, and also provide an explanation for the large range of ablation threshold values observed for this material. The model may be easily adapted to study the response of any composite material to infrared radiation and thus may be useful for the scientific community.

Protoplanetary disks around intermediate-mass stars: the asset of imaging in the mid-infrared

International Nuclear Information System (INIS)

Doucet, Coralie

2006-01-01

The accrued efficiency of the instruments in many wavelengths has allowed to show that most young stellar objects were surrounded by circumstellar matter distributed in a disk. Direct imaging of such systems is very difficult because of their narrow angular size and their weak luminosity in comparison with the star. Nowadays, 50 % of low-mass pre-main sequence stars, i.e. T Tauri stars, are surrounded by a disk. This proportion is less obvious for intermediate-mass stars, like Herbig Ae stars, that are less numerous and whose direct disk detection is more difficult. Until now, only the interpretation of the Spectral Energy Distribution (SED) of such objects allows to have access to the geometry of the disk. But the solutions are degenerated and several parameters fit the same SED. It is essential to have direct images of the objects, the only evidence of the presence of disks. This PhD allows to show that mid-infrared imaging could rise a part of the degeneracy of the disk's parameters linked to the fit of the SED for several objects and gives constraints on the minimum external radius and inclination of the disk. We present a new observation mode with VISIR, the mid-infrared imager and spectrometer on the VLT (ESO, Chile): the so-called BURST mode. This mode allows to reach the diffraction limit of the telescope. Thanks to mid-infrared imaging with this instrument, we were able, for the first time, to have access to the geometry of a disk (flared structure) around a massive star that was, until now, only deduced from the SED modelling. (author) [fr

High-resolution optical coherence tomography, autofluorescence, and infrared reflectance imaging in Sjögren reticular dystrophy.

Science.gov (United States)

Schauwvlieghe, Pieter-Paul; Torre, Kara Della; Coppieters, Frauke; Van Hoey, Anneleen; De Baere, Elfride; De Zaeytijd, Julie; Leroy, Bart P; Brodie, Scott E

2013-01-01

To describe the phenotype of three cases of Sjögren reticular dystrophy in detail, including high-resolution optical coherence tomography, autofluorescence imaging, and near-infrared reflectance imaging. Two unrelated teenagers were independently referred for ophthalmologic evaluation. Both underwent a full ophthalmologic workup, including electrophysiologic and extensive imaging with spectral-domain optical coherence tomography, autofluorescence imaging, and near-infrared reflectance imaging. In addition, mutation screening of ABCA4, PRPH2, and the mitochondrial tRNA gene was performed in Patient 1. Subsequently, the teenage sister of Patient 2 was examined. Strikingly similar phenotypes were present in these three patients. Fundoscopy showed bilateral foveal pigment alterations, and a lobular network of deep retinal, pigmented deposits throughout the posterior pole, tapering toward the midperiphery, with relative sparing of the immediate perifoveal macula and peripapillary area. This network is mildly to moderately hyperautofluorescent on autofluorescence and bright on near-infrared reflectance imaging. Optical coherence tomography showed abnormalities of the retinal pigment epithelium-Bruch membrane complex, photoreceptor outer segments, and photoreceptor inner/outer segment interface. The results of retinal function test were entirely normal. No molecular cause was detected in Patient 1. Imaging suggested that the lobular network of deep retinal deposits in Sjögren reticular dystrophy is the result of accumulation of both pigment and lipofuscin between photoreceptors and retinal pigment epithelium, as well as within the retinal pigment epithelium.

Effect of preservatives on the accuracy of mid-infrared milk component testing.

Science.gov (United States)

Barbano, D M; Wojciechowski, K L; Lynch, J M

2010-12-01

Our objective was to determine the effect of commonly used milk preservatives on the accuracy of fat, protein, and lactose content determination in milk by mid-infrared (mid-IR) milk analysis. Two producer raw milks (Holstein and Jersey) and 2 pasteurized modified milks, 1 similar to Holstein milk and 1 similar to Jersey milk were used as the 4 different milk sources. Seven different milk preservative approaches (K(2)Cr(2)O(7) and 6 different bronopol-based preservatives) and a portion of unpreserved milk for each of the 4 different milks sources were tested for fat B, lactose, protein, and fat A. The experiment was replicated 3 times (28 d each) for a total of 84 d. Two mid-infrared (mid-IR) transmittance milk analyzers (an optical and a virtual filter instrument) were used. A large batch of pilot milk was prepared from pasteurized, homogenized, unpreserved whole milk, split into vials, quick frozen by immersion in liquid nitrogen, and transferred into a -80 °C freezer. Pilots were thawed and analyzed on each testing day during the study. Significant increases were observed in all uncorrected readings on the pilot milks over the 84 d of the study, but the increases were gradual and small on each instrument for all components. Results from the study were corrected for these changes. A significant difference in mid-IR fat A readings was observed, whereas no differences were detected for fat B, lactose, or protein between unpreserved and preserved milks containing 0.02% K(2)Cr(2)O(7.) Therefore, K(2)Cr(2)O(7) has little or no effect on mid-IR test results. All bronopol-based preservative approaches in this study differed in mid-IR test results compared with K(2)Cr(2)O(7)-preserved and unpreserved milks, with the largest effect on protein results. Mid-IR uncorrected readings increased with time of refrigerated storage at 4°C for all preservative approaches, with the largest increase for protein. The rate of increase in uncorrected readings with time of storage was

High Spectral Resolution SOFIA/EXES Observations of C2H2 toward Orion IRc2

Science.gov (United States)

Rangwala, Naseem; Colgan, Sean W. J.; Le Gal, Romane; Acharyya, Kinsuk; Huang, Xinchuan; Lee, Timothy J.; Herbst, Eric; deWitt, Curtis; Richter, Matt; Boogert, Adwin; McKelvey, Mark

2018-03-01

We present high spectral resolution observations from 12.96 to 13.33 microns toward Orion IRc2 using the mid-infrared spectrograph, Echelon-Cross-Echelle Spectrograph (EXES), at Stratospheric Observatory for Infrared Astronomy (SOFIA). These observations probe the physical and chemical conditions of the Orion hot core, which is sampled by a bright, compact, mid-infrared background continuum source in the region, IRc2. All 10 of the rovibrational C2H2 transitions expected in our spectral coverage are detected with high signal-to-noise ratios (S/Ns), yielding continuous coverage of the R-branch lines from J = 9–8 to J = 18–17, including both ortho and para species. Eight of these rovibrational transitions are newly reported detections. The isotopologue, 13CCH2, is clearly detected with a high S/N. This enabled a direct measurement of the 12C/13C isotopic ratio for the Orion hot core of 14 ± 1 and an estimated maximum value of 21. We also detected several HCN rovibrational lines. The ortho and para C2H2 ladders are clearly separate, and tracing two different temperatures, 226 K and 164 K, respectively, with a non-equilibrium ortho to para ratio (OPR) of 1.7 ± 0.1. Additionally, the ortho and para V LSR values differ by about 1.8 ± 0.2 km s‑1, while the mean line widths differ by 0.7 ± 0.2 km s‑1, suggesting that these species are not uniformly mixed along the line of sight to IRc2. We propose that the abnormally low C2H2 OPR could be a remnant from an earlier, colder phase, before the density enhancement (now the hot core) was impacted by shocks generated from an explosive event 500 years ago.

High Resolution Near Infrared Spectrometer to Study the Zodiacal Light Spectrum

Science.gov (United States)

Kutyrev, Alexander; Arendt, R.; Dwek, E.; Moseley, S. H.; Silverberg, R.; Rapchun, D.

2007-12-01

We are developing a near infrared spectrometer for measuring solar absorption lines in the zodiacal light in the near infrared region. R. Reynolds at el. (2004, ApJ 612, 1206) demonstrated that observing single Fraunhofer line can be a powerful tool for extracting zodiacal light parameters based on their measurements of the profile of the Mg I line at 5184 A. We are extending this technique to the near infrared with the primary goal of measuring the absolute intensity of the zodiacal light. This measurement will provide the crucial information needed to accurately subtract zodiacal emission from the DIRBE measurements to get a much higher quality measurement of the extragalactic IR background. The instrument design is based on a dual Fabry-Perot interferometer with a narrow band filter. Its double etalon design allows to achieve high spectral contrast to reject the bright out of band telluric OH emission. High spectral contrast is absolutely necessary to achieve detection limits needed to accurately measure the intensity of the absorption line. We present the design, estimated performance of the instrument with the expected results of the observing program. The project is supported by NASA ROSES-APRA grant.

Evaluation of detectable angle of mid-infrared slot antennas

Science.gov (United States)

Obara, R.; Horikawa, J.; Shimakage, H.; Kawakami, A.

2017-07-01

For evaluations of a mid-infrared (MIR) detectors with antenna, we constructed an angular dependence measurement system of the antenna properties. The fabricated MIR detector consisted of twin slot antennas and a bolometer. The area of the slot antennas was designed to be 2.6 × 0.2 μm2 as to resonate at 61 THz, and they were located parallel and separated 1.6 μm each other. The bolometer was fabricated using by a 7.0-nm thick NbN thin film, and located at the center of the twin antennas. We measured polarization angle dependence and directivity, and showed that the MIR antennas have polarization dependence and directivity like radiofrequency antennas.

Highly efficient dual-wavelength mid-infrared CW Laser in diode end-pumped Er:SrF2 single crystals

Science.gov (United States)

Ma, Weiwei; Qian, Xiaobo; Wang, Jingya; Liu, Jingjing; Fan, Xiuwei; Liu, Jie; Su, Liangbi; Xu, Jun

2016-11-01

The spectral properties and laser performance of Er:SrF2 single crystals were investigated and compared with Er:CaF2. Er:SrF2 crystals have larger absorption cross-sections at the pumping wavelength, larger mid-infrared stimulated emission cross-sections and much longer fluorescence lifetimes of the upper laser level (Er3+:4I11/2 level) than those of Er:CaF2 crystals. Dual-wavelength continuous-wave (CW) lasers around 2.8 μm were demonstrated in both 4at.% and 10at.% Er:SrF2 single crystals under 972 nm laser diode (LD) end pumping. The laser wavelengths are 2789.3 nm and 2791.8 nm in the former, and 2786.4 nm and 2790.7 nm in the latter, respectively. The best laser performance has been demonstrated in lightly doped 4at.% Er:SrF2 with a low threshold of 0.100 W, a high slope efficiency of 22.0%, an maximum output power of 0.483 W.

The impact of clustering and angular resolution on far-infrared and millimeter continuum observations

Science.gov (United States)

Béthermin, Matthieu; Wu, Hao-Yi; Lagache, Guilaine; Davidzon, Iary; Ponthieu, Nicolas; Cousin, Morgane; Wang, Lingyu; Doré, Olivier; Daddi, Emanuele; Lapi, Andrea

2017-11-01

Follow-up observations at high-angular resolution of bright submillimeter galaxies selected from deep extragalactic surveys have shown that the single-dish sources are comprised of a blend of several galaxies. Consequently, number counts derived from low- and high-angular-resolution observations are in tension. This demonstrates the importance of resolution effects at these wavelengths and the need for realistic simulations to explore them. We built a new 2 deg2 simulation of the extragalactic sky from the far-infrared to the submillimeter. It is based on an updated version of the 2SFM (two star-formation modes) galaxy evolution model. Using global galaxy properties generated by this model, we used an abundance-matching technique to populate a dark-matter lightcone and thus simulate the clustering. We produced maps from this simulation and extracted the sources, and we show that the limited angular resolution of single-dish instruments has a strong impact on (sub)millimeter continuum observations. Taking into account these resolution effects, we are reproducing a large set of observables, as number counts and their evolution with redshift and cosmic infrared background power spectra. Our simulation consistently describes the number counts from single-dish telescopes and interferometers. In particular, at 350 and 500 μm, we find that the number counts measured by Herschel between 5 and 50 mJy are biased towards high values by a factor 2, and that the redshift distributions are biased towards low redshifts. We also show that the clustering has an important impact on the Herschel pixel histogram used to derive number counts from P(D) analysis. We find that the brightest galaxy in the beam of a 500 μm Herschel source contributes on average to only 60% of the Herschel flux density, but that this number will rise to 95% for future millimeter surveys on 30 m-class telescopes (e.g., NIKA2 at IRAM). Finally, we show that the large number density of red Herschel sources

Welcome to the Twilight Zone: The Mid-infrared Properties of Post-starburst Galaxies

Science.gov (United States)

Alatalo, Katherine; Bitsakis, Theodoros; Lanz, Lauranne; Lacy, Mark; Brown, Michael J. I.; French, K. Decker; Ciesla, Laure; Appleton, Philip N.; Beaton, Rachael L.; Cales, Sabrina L.; Crossett, Jacob; Falcón-Barroso, Jesús; Kelson, Daniel D.; Kewley, Lisa J.; Kriek, Mariska; Medling, Anne M.; Mulchaey, John S.; Nyland, Kristina; Rich, Jeffrey A.; Urry, C. Meg

2017-07-01

We investigate the optical and Wide-field Survey Explorer (WISE) colors of “E+A” identified post-starburst galaxies, including a deep analysis of 190 post-starbursts detected in the 2 μm All Sky Survey Extended Source Catalog. The post-starburst galaxies appear in both the optical green valley and the WISE Infrared Transition Zone. Furthermore, we find that post-starbursts occupy a distinct region of [3.4]-[4.6] versus [4.6]-[12] WISE colors, enabling the identification of this class of transitioning galaxies through the use of broadband photometric criteria alone. We have investigated possible causes for the WISE colors of post-starbursts by constructing a composite spectral energy distribution (SED), finding that the mid-infrared (4-12 μm) properties of post-starbursts are consistent with either 11.3 μm polycyclic aromatic hydrocarbon emission, or thermally pulsating asymptotic giant branch (TP-AGB) and post-AGB stars. The composite SED of extended post-starburst galaxies with 22 μm emission detected with signal-to-noise ratio ≥slant 3 requires a hot dust component to produce their observed rising mid-infrared SED between 12 and 22 μm. The composite SED of WISE 22 μm non-detections (S/N systems. This could mean that including selections capable of identifying AGNs as part of a search for transitioning and post-starburst galaxies would create a more complete census of the transition pathways taken as a galaxy quenches its star formation.

Validation of mid-infrared spectroscopy for macronutrient analysis of human milk.

Science.gov (United States)

Parat, S; Groh-Wargo, S; Merlino, S; Wijers, C; Super, D M

2017-07-01

Human milk has considerable variation in its composition. Hence, the nutrient profile is only an estimate and can result in under- or over-estimation of the intake of preterm infants. Mid-infrared (MIR) spectroscopy is an evolving technique for analyzing human milk but needs validation before use in clinical practice. Human milk samples from 35 mothers delivering at 35 weeks to term gestation were analyzed for macronutrients by MIR spectroscopy and by standard laboratory methods using Kjeldahl assay for protein, Mojonnier assay for fat and high-pressure liquid chromatography assay for lactose. MIR analysis of the macronutrients in human milk correlated well with standard laboratory tests with intraclass correlation coefficients of 0.997 for fat, 0.839 for protein and 0.776 for lactose. Agreement between the two methods was excellent for fat, and moderate for protein and lactose (Pmilk. Agreement between the methodologies varies by macronutrient.

Application of mid-infrared tuneable diode laser absorption spectroscopy to plasma diagnostics: a review

International Nuclear Information System (INIS)

Roepcke, J; Lombardi, G; Rousseau, A; Davies, P B

2006-01-01

Within the last decade mid-infrared absorption spectroscopy over a region from 3 to 17μm and based on tuneable lead salt diode lasers, often called tuneable diode laser absorption spectroscopy or TDLAS, has progressed considerably as a powerful diagnostic technique for in situ studies of the fundamental physics and chemistry in molecular plasmas. The increasing interest in processing plasmas containing hydrocarbons, fluorocarbons, organo-silicon and boron compounds has led to further applications of TDLAS because most of these compounds and their decomposition products are infrared active. TDLAS provides a means of determining the absolute concentrations of the ground states of stable and transient molecular species, which is of particular importance for the investigation of reaction kinetic phenomena. Information about gas temperature and population densities can also be derived from TDLAS measurements. A variety of free radicals and molecular ions have been detected by TDLAS. Since plasmas with molecular feed gases are used in many applications such as thin film deposition, semiconductor processing, surface activation and cleaning, and materials and waste treatment, this has stimulated the adaptation of infrared spectroscopic techniques to industrial requirements. The recent development of quantum cascade lasers (QCLs) offers an attractive new option for the monitoring and control of industrial plasma processes. The aim of the present paper is threefold: (i) to review recent achievements in our understanding of molecular phenomena in plasmas (ii) to report on selected studies of the spectroscopic properties and kinetic behaviour of radicals and (iii) to describe the current status of advanced instrumentation for TDLAS in the mid-infrared

High efficiency quasi-monochromatic infrared emitter

Energy Technology Data Exchange (ETDEWEB)

Brucoli, Giovanni; Besbes, Mondher; Benisty, Henri, E-mail: henri.benisty@institutoptique.fr; Greffet, Jean-Jacques [Laboratoire Charles Fabry, UMR 8501, Institut d’Optique, CNRS, Université Paris-Sud 11, 2, Avenue Augustin Fresnel, 91127 Palaiseau Cedex (France); Bouchon, Patrick; Haïdar, Riad [Office National d’Études et de Recherches Aérospatiales, Chemin de la Hunière, 91761 Palaiseau (France)

2014-02-24

Incandescent radiation sources are widely used as mid-infrared emitters owing to the lack of alternative for compact and low cost sources. A drawback of miniature hot systems such as membranes is their low efficiency, e.g., for battery powered systems. For targeted narrow-band applications such as gas spectroscopy, the efficiency is even lower. In this paper, we introduce design rules valid for very generic membranes demonstrating that their energy efficiency for use as incandescent infrared sources can be increased by two orders of magnitude.

HIGH RESOLUTION NEAR-INFRARED SURVEY OF THE PIPE NEBULA. I. A DEEP INFRARED EXTINCTION MAP OF BARNARD 59

International Nuclear Information System (INIS)

Roman-Zuniga, Carlos G.; Alves, Joao F.; Lada, Charles J.

2009-01-01

We present our analysis of a fully sampled, high resolution dust extinction map of the Barnard 59 complex in the Pipe Nebula. The map was constructed with the infrared color excess technique applied to a photometric catalog that combines data from both ground and space based observations. The map resolves for the first time the high density center of the main core in the complex, which is associated with the formation of a small cluster of stars. We found that the central core in Barnard 59 shows an unexpected lack of significant substructure consisting of only two significant fragments. Overall, the material appears to be consistent with being a single, large core with a density profile that can be well fit by a King model. A series of NH 3 pointed observations toward the high column density center of the core appear to show that the core is still thermally dominated, with subsonic non-thermal motions. The stars in the cluster could be providing feedback to support the core against collapse, but the relatively narrow radio lines suggest that an additional source of support, for example, a magnetic field, may be required to stabilize the core. Outside the central core our observations reveal the structure of peripheral cores and resolve an extended filament into a handful of significant substructures whose spacing and masses appear to be consistent with Jeans fragmentation.

A Multi-instrument and Multi-wavelength High Angular Resolution Study of MWC 614: Quantum Heated Particles Inside the Disk Cavity

Science.gov (United States)

Kluska, Jacques; Kraus, Stefan; Davies, Claire L.; Harries, Tim; Willson, Matthew; Monnier, John D.; Aarnio, Alicia; Baron, Fabien; Millan-Gabet, Rafael; Ten Brummelaar, Theo; Che, Xiao; Hinkley, Sasha; Preibisch, Thomas; Sturmann, Judit; Sturmann, Laszlo; Touhami, Yamina

2018-03-01

High angular resolution observations of young stellar objects are required to study the inner astronomical units of protoplanetary disks in which the majority of planets form. As they evolve, gaps open up in the inner disk regions and the disks are fully dispersed within ∼10 Myr. MWC 614 is a pretransitional object with a ∼10 au radius gap. We present a set of high angular resolution observations of this object including SPHERE/ZIMPOL polarimetric and coronagraphic images in the visible, Keck/NIRC2 near-infrared (NIR) aperture masking observations, and Very Large Telescope Interferometer (AMBER, MIDI, and PIONIER) and Center for High Angular Resolution Astronomy (CLASSIC and CLIMB) long-baseline interferometry at infrared wavelengths. We find that all the observations are compatible with an inclined disk (i ∼ 55° at a position angle of ∼20°–30°). The mid-infrared data set confirms that the disk inner rim is at 12.3 ± 0.4 au from the central star. We determined an upper mass limit of 0.34 M ⊙ for a companion inside the cavity. Within the cavity, the NIR emission, usually associated with the dust sublimation region, is unusually extended (∼10 au, 30 times larger than the theoretical sublimation radius) and indicates a high dust temperature (T ∼ 1800 K). As a possible result of companion-induced dust segregation, quantum heated dust grains could explain the extended NIR emission with this high temperature. Our observations confirm the peculiar state of this object where the inner disk has already been accreted onto the star, exposing small particles inside the cavity to direct stellar radiation. Based on observations made with the Keck observatory (NASA program ID N104N2) and with ESO telescopes at the Paranal Observatory (ESO program IDs 073.C-0720, 077.C-0226, 077.C-0521, 083.C-0984, 087.C-0498(A), 190.C-0963, 095.C-0883) and with the Center for High Angular Resolution Astronomy observatory.

Research on propane leak detection system and device based on mid infrared laser

Science.gov (United States)

Jiang, Meng; Wang, Xuefeng; Wang, Junlong; Wang, Yizhao; Li, Pan; Feng, Qiaoling

2017-10-01

Propane is a key component of liquefied petroleum gas (LPG) and crude oil volatile. This issue summarizes the recent progress of propane detection technology. Meanwhile, base on the development trend, our latest progress is also provided. We demonstrated a mid infrared propane sensor system, which is based on wavelength modulation spectroscopy (WMS) technique with a CW interband cascade laser (ICL) emitting at 3370.4nm. The ICL laser scanned over a sharp feature in the broader spectrum of propane, and harmonic signals are obtained by lock-in amplifier for gas concentration deduction. The surrounding gas is extracted into the fine optical absorption cell through the pump to realize online detection. The absorption cell is designed in mid infrared windows range. An example experimental setup is shown. The second harmonic signals 2f and first harmonic signals1f are obtained. We present the sensor performance test data including dynamic precision and temperature stability. The propane detection sensor system and device is portable can carried on the mobile inspection vehicle platforms or intelligent robot inspection platform to realize the leakage monitoring of whole oil gas tank area.

Characterization methods of integrated optics for mid-infrared interferometry

Science.gov (United States)

Labadie, Lucas; Kern, Pierre Y.; Schanen-Duport, Isabelle; Broquin, Jean-Emmanuel

2004-10-01

his article deals with one of the important instrumentation challenges of the stellar interferometry mission IRSI-Darwin of the European Space Agency: the necessity to have a reliable and performant system for beam combination has enlightened the advantages of an integrated optics solution, which is already in use for ground-base interferometry in the near infrared. Integrated optics provides also interesting features in terms of filtering, which is a main issue for the deep null to be reached by Darwin. However, Darwin will operate in the mid infrared range from 4 microns to 20 microns where no integrated optics functions are available on-the-shelf. This requires extending the integrated optics concept and the undergoing technology in this spectral range. This work has started with the IODA project (Integrated Optics for Darwin) under ESA contract and aims to provide a first component for interferometry. In this paper are presented the guidelines of the characterization work that is implemented to test and validate the performances of a component at each step of the development phase. We present also an example of characterization experiment used within the frame of this work, is theoretical approach and some results.

MISTiC Winds, a Micro-Satellite Constellation Approach to High Resolution Observations of the Atmosphere using Infrared Sounding and 3D Winds Measurements

Science.gov (United States)

Maschhoff, K. R.; Polizotti, J. J.; Aumann, H. H.; Susskind, J.

2017-12-01

MISTiCTM Winds is an approach to improve short-term weather forecasting based on a miniature high resolution, wide field, thermal emission spectrometry instrument that will provide global tropospheric vertical profiles of atmospheric temperature and humidity at high (3-4 km) horizontal and vertical ( 1 km) spatial resolution. MISTiC's extraordinarily small size, payload mass of less than 15 kg, and minimal cooling requirements can be accommodated aboard a ESPA-Class (50 kg) micro-satellite. Low fabrication and launch costs enable a LEO sun-synchronous sounding constellation that would provide frequent IR vertical profiles and vertically resolved atmospheric motion vector wind observations in the troposphere. These observations are highly complementary to present and emerging environmental observing systems, and would provide a combination of high vertical and horizontal resolution not provided by any other environmental observing system currently in operation. The spectral measurements that would be provided by MISTiC Winds are similar to those of NASA's Atmospheric Infrared Sounder. These new observations, when assimilated into high resolution numerical weather models, would revolutionize short-term and severe weather forecasting, save lives, and support key economic decisions in the energy, air transport, and agriculture arenas-at much lower cost than providing these observations from geostationary orbit. In addition, this observation capability would be a critical tool for the study of transport processes for water vapor, clouds, pollution, and aerosols. In this third year of a NASA Instrument incubator program, the compact infrared spectrometer has been integrated into an airborne version of the instrument for high-altitude flights on a NASA ER2. The purpose of these airborne tests is to examine the potential for improved capabilities for tracking atmospheric motion-vector wind tracer features, and determining their height using hyper-spectral sounding and

Performance of MgO:PPLN, KTA, and KNbO₃ for mid-wave infrared broadband parametric amplification at high average power.

Science.gov (United States)

Baudisch, M; Hemmer, M; Pires, H; Biegert, J

2014-10-15

The performance of potassium niobate (KNbO₃), MgO-doped periodically poled lithium niobate (MgO:PPLN), and potassium titanyl arsenate (KTA) were experimentally compared for broadband mid-wave infrared parametric amplification at a high repetition rate. The seed pulses, with an energy of 6.5 μJ, were amplified using 410 μJ pump energy at 1064 nm to a maximum pulse energy of 28.9 μJ at 3 μm wavelength and at a 160 kHz repetition rate in MgO:PPLN while supporting a transform limited duration of 73 fs. The high average powers of the interacting beams used in this study revealed average power-induced processes that limit the scaling of optical parametric amplification in MgO:PPLN; the pump peak intensity was limited to 3.8  GW/cm² due to nonpermanent beam reshaping, whereas in KNbO₃ an absorption-induced temperature gradient in the crystal led to permanent internal distortions in the crystal structure when operated above a pump peak intensity of 14.4  GW/cm².

ENHANCED WARM H2 EMISSION IN THE COMPACT GROUP MID-INFRARED ''GREEN VALLEY''

International Nuclear Information System (INIS)

Cluver, M. E.; Ogle, P.; Guillard, P.; Appleton, P. N.; Jarrett, T. H.; Rasmussen, J.; Lisenfeld, U.; Verdes-Montenegro, L.; Antonucci, R.; Bitsakis, T.; Charmandaris, V.; Boulanger, F.; Egami, E.; Xu, C. K.; Yun, M. S.

2013-01-01

We present results from a Spitzer mid-infrared spectroscopy study of a sample of 74 galaxies located in 23 Hickson Compact Groups (HCGs), chosen to be at a dynamically active stage of H I depletion. We find evidence for enhanced warm H 2 emission (i.e., above that associated with UV excitation in star-forming regions) in 14 galaxies (∼20%), with 8 galaxies having extreme values of L(H 2 S(0)-S(3))/L(7.7 μm polycyclic aromatic hydrocarbon), in excess of 0.07. Such emission has been seen previously in the compact group HCG 92 (Stephan's Quintet), and was shown to be associated with the dissipation of mechanical energy associated with a large-scale shock caused when one group member collided, at high velocity, with tidal debris in the intragroup medium. Similarly, shock excitation or turbulent heating is likely responsible for the enhanced H 2 emission in the compact group galaxies, since other sources of heating (UV or X-ray excitation from star formation or active galactic nuclei) are insufficient to account for the observed emission. The group galaxies fall predominantly in a region of mid-infrared color-color space identified by previous studies as being connected to rapid transformations in HCG galaxy evolution. Furthermore, the majority of H 2 -enhanced galaxies lie in the optical ''green valley'' between the blue cloud and red sequence, and are primarily early-type disk systems. We suggest that H 2 -enhanced systems may represent a specific phase in the evolution of galaxies in dense environments and provide new insight into mechanisms which transform galaxies onto the optical red sequence.

Mid-infrared emission and Raman spectra analysis of Er(3+)-doped oxyfluorotellurite glasses.

Science.gov (United States)

Chen, Fangze; Xu, Shaoqiong; Wei, Tao; Wang, Fengchao; Cai, Muzhi; Tian, Ying; Xu, Shiqing

2015-04-10

This paper reports on the spectroscopic and structural properties in Er(3+)-doped oxyfluorotellurite glasses. The compositional variation accounts for the evolutions of Raman spectra, Judd-Ofelt parameters, radiative properties, and fluorescent emission. It is found that, when maximum phonon energy changes slightly, phonon density plays a crucial role in quenching the 2.7 μm emission generated by the Er(3+):(4)I11/2→(4)I13/2 transition. The comparative low phonon density contributes strong 2.7 μm emission intensity. The high branching ratio (18.63%) and large emission cross section (0.95×10(-20)  cm(2)) demonstrate that oxyfluorotellurite glass contained with 50 mol.% TeO2 has potential application in the mid-infrared region laser.

Few-cycle high energy mid-infrared pulse from Ho:YLF laser

International Nuclear Information System (INIS)

Murari, Krishna

2017-04-01

Over the past decade, development of high-energy ultrafast laser sources has led to important breakthroughs in attoscience and strong-field physics study in atoms and molecules. Coherent pulse synthesis of few-cycle high-energy laser pulse is a promising tool to generate isolated attosecond pulses via high harmonics generation (HHG). An effective way to extend the HHG cut-off energy to higher values is making use of long mid-infrared (MIR) driver wavelength, as the ponderomotive potential scales quadratically with wavelength. If properly scaled in energy to multi-mJ level and few-cycle duration, such pulses provide a direct path to intriguing attoscience experiments in gases and solids, which even permit the realization of bright coherent table-top HHG sources in the water-window and keV X-ray region. However, the generation of high-intensity long-wavelength MIR pulses has always remained challenging, in particular starting from high-energy picosecond 2-μm laser driver, that is suitable for further energy scaling of the MIR pulses to multi-mJ energies by utilizing optical parametric amplifiers (OPAs). In this thesis, a front-end source for such MIR OPA is presented. In particular, a novel and robust strong-field few-cycle 2-μm laser driver directly from picosecond Ho:YLF laser and utilizing Kagome fiber based compression is presented. We achieved: a 70-fold compression of 140-μJ, 3.3-ps pulses from Ho:YLF amplifier to 48 fs with 11 μJ energy. The work presented in this thesis demonstrates a straightforward path towards generation of few-cycle MIR pulses and we believe that in the future the ultrafast community will benefit from this enabling technology. The results are summarized in mainly four parts: The first part is focused on the development of a 2-μm, high-energy laser source as the front-end. Comparison of available technology in general and promising gain media at MIR wavelength are discussed. Starting from the basics of an OPA, the design criteria

Few-cycle high energy mid-infrared pulse from Ho:YLF laser

Energy Technology Data Exchange (ETDEWEB)

Murari, Krishna

2017-04-15

Over the past decade, development of high-energy ultrafast laser sources has led to important breakthroughs in attoscience and strong-field physics study in atoms and molecules. Coherent pulse synthesis of few-cycle high-energy laser pulse is a promising tool to generate isolated attosecond pulses via high harmonics generation (HHG). An effective way to extend the HHG cut-off energy to higher values is making use of long mid-infrared (MIR) driver wavelength, as the ponderomotive potential scales quadratically with wavelength. If properly scaled in energy to multi-mJ level and few-cycle duration, such pulses provide a direct path to intriguing attoscience experiments in gases and solids, which even permit the realization of bright coherent table-top HHG sources in the water-window and keV X-ray region. However, the generation of high-intensity long-wavelength MIR pulses has always remained challenging, in particular starting from high-energy picosecond 2-μm laser driver, that is suitable for further energy scaling of the MIR pulses to multi-mJ energies by utilizing optical parametric amplifiers (OPAs). In this thesis, a front-end source for such MIR OPA is presented. In particular, a novel and robust strong-field few-cycle 2-μm laser driver directly from picosecond Ho:YLF laser and utilizing Kagome fiber based compression is presented. We achieved: a 70-fold compression of 140-μJ, 3.3-ps pulses from Ho:YLF amplifier to 48 fs with 11 μJ energy. The work presented in this thesis demonstrates a straightforward path towards generation of few-cycle MIR pulses and we believe that in the future the ultrafast community will benefit from this enabling technology. The results are summarized in mainly four parts: The first part is focused on the development of a 2-μm, high-energy laser source as the front-end. Comparison of available technology in general and promising gain media at MIR wavelength are discussed. Starting from the basics of an OPA, the design criteria

Mid Infrared Instrument cooler subsystem test facility overview

Science.gov (United States)

Moore, B.; Zan, J.; Hannah, B.; Chui, T.; Penanen, K.; Weilert, M.

2017-12-01

The Cryocooler for the Mid Infrared Instrument (MIRI) on the James Webb Space Telescope (JWST) provides cooling at 6.2K on the instrument interface. The cooler system design has been incrementally documented in previous publications [1][2][3][4][5]. It has components that traverse three primary thermal regions on JWST: Region 1, approximated by 40K; Region 2, approximated by 100K; and Region 3, which is at the allowable flight temperatures for the spacecraft bus. However, there are several sub-regions that exist in the transition between primary regions and at the heat reject interfaces of the Cooler Compressor Assembly (CCA) and Cooler Control Electronics Assembly (CCEA). The design and performance of the test facility to provide a flight representative thermal environment for acceptance testing and characterization of the complete MIRI cooler subsystem are presented.

Hybrid active pixel sensors in infrared astronomy

International Nuclear Information System (INIS)

Finger, Gert; Dorn, Reinhold J.; Meyer, Manfred; Mehrgan, Leander; Stegmeier, Joerg; Moorwood, Alan

2005-01-01

Infrared astronomy is currently benefiting from three main technologies providing high-performance hybrid active pixel sensors. In the near infrared from 1 to 5 μm two technologies, both aiming for buttable 2Kx2K mosaics, are competing, namely InSb and HgCdTe grown by LPE or MBE on Al 2 O 3 , Si or CdZnTe substrates. Blocked impurity band Si:As arrays cover the mid infrared spectral range from 8 to 28 μm. Adaptive optics combined with multiple integral field units feeding high-resolution spectrographs drive the requirements for the array format of infrared sensors used at ground-based infrared observatories. The pixel performance is now approaching fundamental limits. In view of this development, a detection limit for the photon flux of the ideal detector will be derived, depending only on the temperature and the impedance of the detector. It will be shown that this limit is approximated by state of the art infrared arrays for long on-chip integrations. Different detector materials are compared and strategies to populate large focal planes are discussed. The need for the development of small-format low noise sensors for adaptive optics and interferometry will be pointed out

Infrared sensor for water pollution and monitoring

Science.gov (United States)

Baudet, E.; Gutierrez-Arrovo, A.; Bailleul, M.; Rinnert, E.; Nemec, P.; Charrier, J.; Bodiou, L.; Colas, F.; Compère, C.; Boussard, C.; Bureau, B.; Michel, K.; Nazabal, V.

2017-05-01

Development of Mid-infrared sensors for the detection of biochemical molecules is a challenge of great importance. Mid-infrared range (4000 - 400 cm-1) contains the absorption bands related to the vibrations of organic molecules (nitrates, hydrocarbons, pesticides, etc.). Chalcogenide glasses are an important class of amorphous materials appropriate for sensing applications. Indeed, they are mainly studied and used for their wide transparency in the infrared range (up to 15 μm for selenide glasses) and high refractive index (between 2 and 3). The aim of this study is to synthesize and characterize chalcogenide thin films for developing mid-IR optical waveguides. Therefore, two (GeSe2)100-x(Sb2Se3)x chalcogenide glasses, where x=10 and 50 were chosen for their good mid-IR transparency, high stability against crystallization and their refractive index contrast suitable for mid-IR waveguiding. Chalcogenide glasses were prepared using the conventional melting and quenching method and then used for RF magnetron sputtering deposition. Sputtered thin films were characterized in order to determine dispersion of refractive index in UV-Vis-NIR-MIR. Obtained results were used for the simulation of the optical design in mid-infrared (λ = 7.7 μm). Selenide ridge waveguide were prepared by RIE-ICP dry etching process. Single-mode propagation at 7.7 μm was observed. Optical losses of 0.7 +/- 0.3 and 2.5 +/- 0.1 dB.cm-1 were measured in near-infrared (λ = 1.55 μm) and midinfrared (λ = 7.7 μm), respectively. Achieved results are promising for the fabrication of an integrated optical sensor operating in the mid-infrared.

Submillimeter-wave and far-infrared spectroscopy of high-J transitions of the ground and ν2 = 1 states of ammonia.

Science.gov (United States)

Yu, Shanshan; Pearson, John C; Drouin, Brian J; Sung, Keeyoon; Pirali, Olivier; Vervloet, Michel; Martin-Drumel, Marie-Aline; Endres, Christian P; Shiraishi, Tetsuro; Kobayashi, Kaori; Matsushima, Fusakazu

2010-11-07

Complete and reliable knowledge of the ammonia spectrum is needed to enable the analysis and interpretation of astrophysical and planetary observations. Ammonia has been observed in the interstellar medium up to J=18 and more highly excited transitions are expected to appear in hot exoplanets and brown dwarfs. As a result, there is considerable interest in observing and assigning the high J (rovibrational) spectrum. In this work, numerous spectroscopic techniques were employed to study its high J transitions in the ground and ν(2)=1 states. Measurements were carried out using a frequency multiplied submillimeter spectrometer at Jet Propulsion Laboratory (JPL), a tunable far-infrared spectrometer at University of Toyama, and a high-resolution Bruker IFS 125 Fourier transform spectrometer (FTS) at Synchrotron SOLEIL. Highly excited ammonia was created with a radiofrequency discharge and a dc discharge, which allowed assignments of transitions with J up to 35. One hundred and seventy seven ground state and ν(2)=1 inversion transitions were observed with microwave accuracy in the 0.3-4.7 THz region. Of these, 125 were observed for the first time, including 26 ΔK=3 transitions. Over 2000 far-infrared transitions were assigned to the ground state and ν(2)=1 inversion bands as well as the ν(2) fundamental band. Of these, 1912 were assigned using the FTS data for the first time, including 222 ΔK=3 transitions. The accuracy of these measurements has been estimated to be 0.0003-0.0006 cm(-1). A reduced root mean square error of 0.9 was obtained for a global fit of the ground and ν(2)=1 states, which includes the lines assigned in this work and all previously available microwave, terahertz, far-infrared, and mid-infrared data. The new measurements and predictions reported here will support the analyses of astronomical observations by high-resolution spectroscopy telescopes such as Herschel, SOFIA, and ALMA. The comprehensive experimental rovibrational energy levels

Mid-infrared spectroscopy for characterization of Baltic amber (succinite)

Science.gov (United States)

Wagner-Wysiecka, Ewa

2018-05-01

Natural Baltic amber (succinite) is the most appreciated fossil resin of the rich cultural traditions dating back to prehistoric times. Its unequivocal identification is extremely important in many branches of science and trades including archeology, paleontology, chemistry and finally mineralogical and gemological societies. Current methods of modification of natural succinite are more and more sophisticated making the identification of natural Baltic amber often challenging. In article the systematic analytical approach for identification of natural and modified under different conditions succinite, using mid-infrared spectroscopy (transmission, Drifts and ATR techniques) is presented. The correlation between spectral characteristics and properties of succinite is discussed pointing that the understanding of the nature of changes is the key of identification of this precious material.

THE ORIGIN OF THE INFRARED EMISSION IN RADIO GALAXIES. II. ANALYSIS OF MID- TO FAR-INFRARED SPITZER OBSERVATIONS OF THE 2JY SAMPLE

NARCIS (Netherlands)

Dicken, D.; Tadhunter, C.; Axon, D.; Morganti, R.; Inskip, K. J.; Holt, J.; Delgado, R. Gonzalez; Groves, B.

2009-01-01

We present an analysis of deep mid- to far-infrared (MFIR) Spitzer photometric observations of the southern 2Jy sample of powerful radio sources (0.05

Prospective for graphene based thermal mid-infrared light emitting devices

Science.gov (United States)

Lawton, L. M.; Mahlmeister, N. H.; Luxmoore, I. J.; Nash, G. R.

2014-08-01

We have investigated the spatial and spectral characteristics of mid-infrared thermal emission from large area Chemical Vapor Deposition (CVD) graphene, transferred onto SiO2/Si, and show that the emission is broadly that of a grey-body emitter, with emissivity values of approximately 2% and 6% for mono- and multilayer graphene. For the currents used, which could be sustained for over one hundred hours, the emission peaked at a wavelength of around 4 μm and covered the characteristic absorption of many important gases. A measurable modulation of thermal emission was obtained even when the drive current was modulated at frequencies up to 100 kHz.

Prospective for graphene based thermal mid-infrared light emitting devices

Directory of Open Access Journals (Sweden)

L. M. Lawton

2014-08-01

Full Text Available We have investigated the spatial and spectral characteristics of mid-infrared thermal emission from large area Chemical Vapor Deposition (CVD graphene, transferred onto SiO2/Si, and show that the emission is broadly that of a grey-body emitter, with emissivity values of approximately 2% and 6% for mono- and multilayer graphene. For the currents used, which could be sustained for over one hundred hours, the emission peaked at a wavelength of around 4 μm and covered the characteristic absorption of many important gases. A measurable modulation of thermal emission was obtained even when the drive current was modulated at frequencies up to 100 kHz.

Sol-gel based mid-infrared evanescent wave sensors for detection of organophosphate pesticides in aqueous solution

Energy Technology Data Exchange (ETDEWEB)

Janotta, Markus; Karlowatz, Manfred; Vogt, Frank; Mizaikoff, Boris

2003-10-31

This work demonstrates the application of organically modified sol-gels as recognition layers combined with mid-infrared evanescent wave sensors for in situ detection of nitrated organics in aqueous media. Sol-gels were prepared by acid-catalyzed copolymerization of phenyltrimethoxysilane (PTMOS) and tetramethoxysilane (TMOS) and were spin-coated onto ZnSe attenuated total reflection (ATR) waveguides. These sensors were investigated with respect to their enrichment properties of selected organophosphates, i.e. parathion, fenitrothion and paraoxon, respectively, and their capability of suppressing interfering water background absorptions. Figures of merit are derived from calibration curves determined to assess sensitivity and reproducibility of the applied sensor system. It can be concluded that sol-gel coated infrared optical sensors enable reproducible detection of organophosphates down to the sub-ppm concentration range. Furthermore, measurement of spiked river water samples demonstrates feasibility as remote field sensor system. Once the required sensitivity is achieved, sol-gel based mid-infrared evanescent wave sensors have the potential of being an alternative to commonly applied biosensors for detection of organophosphates in environmental analysis, since they provide superior mechanical and chemical stability during application relevant periods of time.

Potential and limitation of mid-infrared attenuated total reflectance spectroscopy for real time analysis of raw milk in milking lines.

Science.gov (United States)

Linker, Raphael; Etzion, Yael

2009-02-01

Real-time information about milk composition would be very useful for managing the milking process. Mid-infrared spectroscopy, which relies on fundamental modes of molecular vibrations, is routinely used for off-line analysis of milk and the purpose of the present study was to investigate the potential of attenuated total reflectance mid-infrared spectroscopy for real-time analysis of milk in milking lines. The study was conducted with 189 samples from over 70 cows that were collected during an 18 months period. Principal component analysis, wavelets and neural networks were used to develop various models for predicting protein and fat concentration. Although reasonable protein models were obtained for some seasonal sub-datasets (determination errors protein), the models lacked robustness and it was not possible to develop a model suitable for all the data. Determination of fat concentration proved even more problematic and the determination errors remained unacceptably large regardless of the sub-dataset analyzed or of the spectral intervals used. These poor results can be explained by the limited penetration depth of the mid-infrared radiation that causes the spectra to be very sensitive to the presence of fat globules or fat biofilms in the boundary layer that forms at the interface between the milk and the crystal that serves both as radiation waveguide and sensing element. Since manipulations such as homogenisation are not permissible for in-line analysis, these results show that the potential of mid-infrared attenuated total reflectance spectroscopy for in-line milk analysis is indeed quite limited.

Development of integrated platform based on chalcogenides for sensing applications in the mid-infrared

Science.gov (United States)

Gutierrez-Arroyo, Aldo; Bodiou, Loïc.; Lemaitre, Jonathan; Baudet, Emeline; Baillieul, Marion; Hardy, Isabelle; Caillaud, Celine; Colas, Florent; Boukerma, Kada; Rinnert, Emmanuel; Michel, Karine; Bureau, Bruno; Nazabal, Virginie; Charrier, Joël.

2018-03-01

Mid-Infrared (mid-IR) spectral range, spanning from 2 μm to 20 μm, is ideal for chemical sensing using spectroscopy thanks to the presence of vibrational absorption bands of many liquid and gas substances in this wavelength range. Indeed, mid-IR spectroscopy allows simultaneous qualitative and quantitative analysis by, respectively, identifying molecules from their spectral signature and relating the concentrations of different chemical agents to their absorption coefficient according to Beer-Lambert law. In the last years, photonic integrated sensors based on mid-IR spectroscopy have emerged as a cheap, accurate, and compact solution that would enable continuous real-time on-site diagnostics and monitoring of molecular species without the need to collect samples for off-site measurements. Here, we report the design, processing and characterization of a photonic integrated transducer based on selenide ridge waveguides. Evanescent wave detection of chemical substances in liquid phase (isopropyl alcohol, C3H8O, and acetic acid, C2H4O2, both dissolved in cyclohexane) is presented using their absorption at a wavelength of 7.7 μm.

A MID-INFRARED CENSUS OF STAR FORMATION ACTIVITY IN BOLOCAM GALACTIC PLANE SURVEY SOURCES

International Nuclear Information System (INIS)

Dunham, Miranda K.; Robitaille, Thomas P.; Evans, Neal J. II; Schlingman, Wayne M.; Cyganowski, Claudia J.; Urquhart, James

2011-01-01

We present the results of a search for mid-infrared signs of star formation activity in the 1.1 mm sources in the Bolocam Galactic Plane Survey (BGPS). We have correlated the BGPS catalog with available mid-IR Galactic plane catalogs based on the Spitzer Space Telescope GLIMPSE legacy survey and the Midcourse Space Experiment (MSX) Galactic plane survey. We find that 44% (3712 of 8358) of the BGPS sources contain at least one mid-IR source, including 2457 of 5067 (49%) within the area where all surveys overlap (10 deg. s tarlessBGPS sources which were not matched to any mid-IR sources. The mean 1.1 mm flux of each group increases with increasing probability of active star formation. We also find that the 'starless' BGPS sources are the most compact, while the sources with the highest probability of star formation activity are on average more extended with large skirts of emission. A subsample of 280 BGPS sources with known distances demonstrates that mass and mean H 2 column density also increase with probability of star formation activity.

Detection of high level carbon dioxide emissions using a compact optical fibre based mid-infrared sensor system for applications in environmental pollution monitoring

Energy Technology Data Exchange (ETDEWEB)

Muda, R; Lewis, E; O' Keeffe, S; Dooly, G; Clifford, J, E-mail: razali.muda@ul.i [Optical Fibre Sensors Research Centre, Electronic and Computer Engineering Department, University of Limerick (Ireland)

2009-07-01

A novel and highly compact optical fibre based sensor system for measurement of high concentrations CO{sub 2} gas emissions in modern automotive exhaust is presented. The sensor system works based on the principle of open-path direct absorption spectroscopy in the mid-infrared wavelength range. The sensor system, which comprises low cost components and is compact in design, is well suited for applications in monitoring CO{sub 2} emissions from the exhaust of automotive vehicles. The sensor system utilises calcium fluoride (CaF{sub 2}) lenses and a narrow band pass (NBP) filter for detection of CO{sub 2} gas. The response of the sensor to high concentrations of CO{sub 2} gas is presented and the result is compared with that of a commercial flue gas analyser. The sensor shows response times of 5.2s and demonstrates minimal susceptibility to cross interferences of other gases present in the exhaust system.

Thermal noise in mid-infrared broadband upconversion detectors

DEFF Research Database (Denmark)

Barh, Ajanta; Tidemand-Lichtenberg, Peter; Pedersen, Christian

2018-01-01

Low noise detection with state-of-the-art mid-infrared (MIR) detectors (e.g., PbS, PbSe, InSb, HgCdTe) is a primary challenge owing to the intrinsic thermal background radiation of the low bandgap detector material itself. However, researchers have employed frequency upconversion based detectors...... of the noise-equivalent power of an UCD system. In this article, we rigorously analyze the optical power generated by frequency upconversion of the intrinsic black-body radiation in the nonlinear material itself due to the crystals residual emissivity, i.e. absorption. The thermal radiation is particularly...... prominent at the optical absorption edge of the nonlinear material even at room temperature. We consider a conventional periodically poled lithium niobate (PPLN) based MIR-UCD for the investigation. The UCD is designed to cover a broad spectral range, overlapping with the entire absorption edge of the PPLN...

IV-VI mid-infrared VECSEL on Si-substrate

Science.gov (United States)

Fill, M.; Felder, F.; Rahim, M.; Khiar, A.; Rodriguez, R.; Zogg, H.; Ishida, A.

2012-03-01

Optically pumped VECSEL (vertical external cavity surface emitting lasers) based on IV-VI semiconductors grown on Si cover the entire wavelength range between 3.0 and 10 μm. Thanks to their simple structure and large wavelength coverage they are an interesting alternative laser technology to access the mid-infrared wavelength region. The active layers consist either of homogeneous "bulk" layers, double heterostructures or quantum well structures of the PbSe, PbTe or PbS material system. Maximum operation temperatures of 325 K are achieved with output powers above 200 mWp. Further, continuously tunable VECSEL are presented, emitting between 3.2 and 5.4 μm. The single emission mode is continuously tunable over 50-100 nm around the center wavelength, yielding an output power > 10 mWp. The axial symmetric emission beam has a half divergence angle of < 3.3°.

Microwave, High-Resolution Infrared, and Quantum Chemical Investigations of CHBrF2

DEFF Research Database (Denmark)

Cazzoli, Gabriele; Cludi, Lino; Puzzarini, Cristina

2011-01-01

terms as well as the hyperfine parameters (quadrupole-coupling and spin-rotation interaction constants) of the bromine nucleus. The determination of the latter was made possible by recording of spectra at sub-Doppler resolution, achieved by means of the Lamb-dip technique, and supporting the spectra......A combined microwave, infrared, and computational investigation of CHBrF2 is reported. For the vibrational ground state, measurements in the millimeter- and sub-millimeter-wave regions for (CHBrF2)-Br-79 and (CHBrF2)-Br-81 provided rotational and centrifugal-distortion constants up to the sextic...... parameters of the v(4) = 1 state were found to be close to those of the vibrational ground state, indicating that the v(4) band is essentially unaffected by perturbations....

Mid-IR Properties of an Unbiased AGN Sample of the Local Universe. 1; Emission-Line Diagnostics

Science.gov (United States)

Weaver, K. A.; Melendez, M.; Muhotzky, R. F.; Kraemer, S.; Engle, K.; Malumuth. E.; Tueller, J.; Markwardt, C.; Berghea, C. T.; Dudik, R. P.;

Non-invasive identification of metal-oxalate complexes on polychrome artwork surfaces by reflection mid-infrared spectroscopy.

Science.gov (United States)

Monico, Letizia; Rosi, Francesca; Miliani, Costanza; Daveri, Alessia; Brunetti, Brunetto G

2013-12-01

In this work a reflection mid-infrared spectroscopy study of twelve metal-oxalate complexes, of interest in art conservation science as alteration compounds, was performed. Spectra of the reference materials highlighted the presence of derivative-like and/or inverted features for the fundamental vibrational modes as result of the main contribution from the surface component of the reflected light. In order to provide insights in the interpretation of theses spectral distortions, reflection spectra were compared with conventional transmission ones. The Kramers-Kronig (KK) algorithm, employed to correct for the surface reflection distortions, worked properly only for the derivative-like bands. Therefore, to pay attention to the use of this algorithm when interpreting the reflection spectra is recommended. The outcome of this investigation was exploited to discriminate among different oxalates on thirteen polychrome artworks analyzed in situ by reflection mid-infrared spectroscopy. The visualization of the νs(CO) modes (1400-1200 cm(-1)) and low wavenumber bands (below 900 cm(-1)) in the raw reflection profiles allowed Ca, Cu and Zn oxalates to be identified. Further information about the speciation of different hydration forms of calcium oxalates were obtained by using the KK transform. The work proves reflection mid-infrared spectroscopy to be a reliable and sensitive spectro-analytical method for identifying and mapping different metal-oxalate alteration compounds on the surface of artworks, thus providing conservation scientists with a non-invasive tool to obtain information on the state of conservation and causes of alteration of artworks. Copyright © 2013 Elsevier B.V. All rights reserved.

Time resolved spectra in the infrared absorption and emission from shock heated hydrocarbons. [in interstellar medium

Science.gov (United States)

Bauer, S. H.; Borchardt, D. B.

1990-01-01

The wavelength range of a previously constructed multichannel fast recording spectrometer was extended to the mid-infrared. With the initial configuration, light intensities were recorded simultaneously with a silicon-diode array simultaneously at 20 adjacent wavelengths, each with a 20-micron time resolution. For studies in the infrared, the silicon diodes were replaced by a 20-element PbSe array of similar dimensions, cooled by a three-stage thermoelectric device. It is proposed that infrared emissions could be due to shock-heated low molecular-weight hydrocarbons. The full Swan band system appeared in time-integrated emission spectra from shock-heated C2H2; no soot was generated. At low resolution, the profiles on the high-frequency side of the black body maximum show no distinctive features. These could be fitted to Planck curves, with temperatures that declined with time from an initial high that was intermediate between T5 (no conversion) and T5(eq).

Achromatic wave plates for the mid-infrared

Science.gov (United States)

Beasley, J. Donald; Marlowe, Philip D.

2012-06-01

Achromatic wave plates are useful in various mid-IR applications, such as analyzing or controlling the spectrum available from CO2 and other lasers, and for the study of IR spectra from distant stars. Their production relies upon the technical skills of those who grow the required high quality crystals and upon those who fabricate the optical parts to the needed precision. Two materials are described - one useful for light in the spectral range of the visible through the near IR and another that functions well in mid-IR applications from 2.5 μm to 11.5 μm. Some limitations imposed by inherent material properties will also be discussed.

THE MID-INFRARED EXTINCTION LAW AND ITS VARIATION IN THE COALSACK NEBULA

Energy Technology Data Exchange (ETDEWEB)

Wang Shu; Gao Jian; Jiang, B. W.; Chen Yang [Department of Astronomy, Beijing Normal University, Beijing 100875 (China); Li Aigen, E-mail: shuwang@mail.bnu.edu.cn, E-mail: jiangao@bnu.edu.cn, E-mail: bjiang@bnu.edu.cn, E-mail: cheny@bnu.edu.cn, E-mail: lia@missouri.edu [Department of Physics and Astronomy, University of Missouri, Columbia, MO 65211 (United States)

2013-08-10

In recent years, the wavelength dependence of interstellar extinction from the ultraviolet (UV) to the near- and mid-infrared (IR) has been studied extensively. Although it is well established that the UV/optical extinction law varies significantly among the different lines of sight, it is not clear how IR extinction varies among various environments. In this work, using the color-excess method and taking red giants as the extinction tracer, we determine interstellar extinction A{sub {lambda}} in the four Spitzer/IRAC bands in [3.6], [4.5], [5.8], [8.0] {mu}m (relative to A{sub K{sub s}}, extinction in the Two Micron All Sky Survey (2MASS) K{sub s} band at 2.16 {mu}m) of the Coalsack nebula, a nearby starless dark cloud, based on the data obtained from the 2MASS and Spitzer/GLIMPSE surveys. We select five individual regions across the nebula that span a wide variety of physical conditions ranging from diffuse and translucent to dense environments, as traced by the visual extinction, the Spitzer/MIPS 24 {mu}m emission, and CO emission. We find that A{sub {lambda}}/A{sub K{sub s}}, mid-IR extinction relative to A{sub K{sub s}}, decreases from diffuse to dense environments, which may be explained in terms of ineffective dust growth in dense regions. The mean extinction (relative to A{sub K{sub s}}) is calculated for the four IRAC bands as well and exhibits a flat mid-IR extinction law consistent with previous determinations for other regions. Extinction in the IRAC 4.5 {mu}m band is anomalously high, much higher than that of the other three IRAC bands, and cannot be explained in terms of CO and CO{sub 2} ice. Mid-IR extinction in the four IRAC bands has also been derived for four representative regions in the Coalsack Globule 2, which respectively exhibit strong ice absorption, moderate or weak ice absorption, and very weak or no ice absorption. The derived mid-IR extinction curves are all flat, with A{sub {lambda}}/A{sub K{sub s}} increasing with the decrease of the

THE MID-INFRARED EXTINCTION LAW AND ITS VARIATION IN THE COALSACK NEBULA

International Nuclear Information System (INIS)

Wang Shu; Gao Jian; Jiang, B. W.; Chen Yang; Li Aigen

2013-01-01

In recent years, the wavelength dependence of interstellar extinction from the ultraviolet (UV) to the near- and mid-infrared (IR) has been studied extensively. Although it is well established that the UV/optical extinction law varies significantly among the different lines of sight, it is not clear how IR extinction varies among various environments. In this work, using the color-excess method and taking red giants as the extinction tracer, we determine interstellar extinction A λ in the four Spitzer/IRAC bands in [3.6], [4.5], [5.8], [8.0] μm (relative to A K s , extinction in the Two Micron All Sky Survey (2MASS) K s band at 2.16 μm) of the Coalsack nebula, a nearby starless dark cloud, based on the data obtained from the 2MASS and Spitzer/GLIMPSE surveys. We select five individual regions across the nebula that span a wide variety of physical conditions ranging from diffuse and translucent to dense environments, as traced by the visual extinction, the Spitzer/MIPS 24 μm emission, and CO emission. We find that A λ /A K s , mid-IR extinction relative to A K s , decreases from diffuse to dense environments, which may be explained in terms of ineffective dust growth in dense regions. The mean extinction (relative to A K s ) is calculated for the four IRAC bands as well and exhibits a flat mid-IR extinction law consistent with previous determinations for other regions. Extinction in the IRAC 4.5 μm band is anomalously high, much higher than that of the other three IRAC bands, and cannot be explained in terms of CO and CO 2 ice. Mid-IR extinction in the four IRAC bands has also been derived for four representative regions in the Coalsack Globule 2, which respectively exhibit strong ice absorption, moderate or weak ice absorption, and very weak or no ice absorption. The derived mid-IR extinction curves are all flat, with A λ /A K s increasing with the decrease of the 3.1 μm H 2 O ice absorption optical depth τ ice

Ultrafast Mid-Infrared Intra-Excitonic Response of Individualized Single-Walled Carbon Nanotubes

International Nuclear Information System (INIS)

Wang, Jigang; Graham, Matt W.; Ma, Yingzhong; Fleming, Graham R.; Kaindl, Robert A.

2009-01-01

The quasi-1D confinement and reduced screening of photoexcited charges in single-walled carbon nanotubes (SWNTs) entails strongly-enhanced Coulomb interactions and exciton binding energies. Such amplified electron-hole (e-h) correlations have important implications for both fundamental physics and optoelectronic applications of nanotubes. The availability of 'individualized' SWNT ensembles with bright and structured luminescence has rendered specific tube chiralities experimentally accessible. In these samples, evidence for excitonic behavior was found in absorption-luminescence maps, two-photon excited luminescence, or ultrafast carrier dynamics. Here, we report ultrafast mid-infrared (mid-IR) studies of individualized SWNTs, evidencing strong photoinduced absorption around 200 meV in semiconducting tubes of (6,5) and (7,5) chiralities. This manifests the observation of quasi-1D intra-excitonic transitions between different relative-momentum states, in agreement with the binding energy and calculated oscillator strength. Our measurements further reveal a saturation of the photoinduced absorption with increasing phase-space filling of the correlated e-h pairs. The transient mid-IR response represents a new tool, unhindered by restrictions of momentum or interband dipole moment, to investigate the density and dynamics of SWNT excitons.

Mid-infrared optical properties of chalcogenide glasses within tin-antimony-selenium ternary system.

Science.gov (United States)

Lin, Ruiqiang; Chen, Feifei; Zhang, Xiaoyu; Huang, Yicong; Song, Baoan; Dai, Shixun; Zhang, Xianghua; Ji, Wei

2017-10-16

In this work, we investigated the mid-infrared (MIR) optical properties of selenide (Se-based) chalcogenide glasses (ChGs) within an As- and Ge-free system, namely the environment-friendly and low-cost tin-antimony-selenium (Sn-Sb-Se, SSS) ternary system, which has not been systematically studied to the best of our knowledge. As compared to ChGs within those conventional Se-based systems, SSS ChGs were found to exhibit extended infrared transmittance range as well as larger linear refractive index (n 0 ). Femtosecond Z-scan measurements show the presence of evident three-photon absorption from Urbach absorption of the SSS ChGs at MIR wavelength, which resonantly enhanced the nonlinear refractive behavior and resulted in large nonlinear refractive index (n 2 ).

Global High Resolution Sea Surface Flux Parameters From Multiple Satellites

Science.gov (United States)

Zhang, H.; Reynolds, R. W.; Shi, L.; Bates, J. J.

2007-05-01

Advances in understanding the coupled air-sea system and modeling of the ocean and atmosphere demand increasingly higher resolution data, such as air-sea fluxes of up to 3 hourly and every 50 km. These observational requirements can only be met by utilizing multiple satellite observations. Generation of such high resolution products from multiple-satellite and in-situ observations on an operational basis has been started at the U.S. National Oceanic and Atmospheric Administration (NOAA) National Climatic Data Center. Here we describe a few products that are directly related to the computation of turbulent air-sea fluxes. Sea surface wind speed has been observed from in-situ instruments and multiple satellites, with long-term observations ranging from one satellite in the mid 1987 to six or more satellites since mid 2002. A blended product with a global 0.25° grid and four snapshots per day has been produced for July 1987 to present, using a near Gaussian 3-D (x, y, t) interpolation to minimize aliases. Wind direction has been observed from fewer satellites, thus for the blended high resolution vector winds and wind stresses, the directions are taken from the NCEP Re-analysis 2 (operationally run near real time) for climate consistency. The widely used Reynolds Optimum Interpolation SST analysis has been improved with higher resolutions (daily and 0.25°). The improvements use both infrared and microwave satellite data that are bias-corrected by in- situ observations for the period 1985 to present. The new versions provide very significant improvements in terms of resolving ocean features such as the meandering of the Gulf Stream, the Aghulas Current, the equatorial jets and other fronts. The Ta and Qa retrievals are based on measurements from the AMSU sounder onboard the NOAA satellites. Ta retrieval uses AMSU-A data, while Qa retrieval uses both AMSU-A and AMSU-B observations. The retrieval algorithms are developed using the neural network approach. Training

High-Resolution Spectroscopy at the Wyoming Infrared Observatory: Setting TESS Science on FHiRE

Science.gov (United States)

Jang-Condell, Hannah; Pierce, Michael J.; Pilachowski, C. A.; Kobulnicky, Henry; McLane, Jacob N.

2018-01-01

The Fiber High Resolution Echelle (FHiRE) spectrograph is a new instrument designed for the 2.3-m Wyoming InfraRed Observatory (WIRO). With the construction of a vacuum chamber for FHiRE to stabilize the spectrograph and a temperature-stabilized Thorium-Argon lamp for precise velocity calibration, we will be able to achieve 1 m/s RV precision, making it an ideal instrument for finding exoplanets. Details of the design of FHiRE are presented in a companion poster (Pierce et al.). The construction of this instrument is well-timed with the planned 2018 launch of NASA's Transiting Exoplanet Survey Satellite (TESS) mission. TESS will require a great deal of follow-up spectroscopy to characterize potential exoplanet host stars as well as radial velocity measurements to confirm new exoplanets. WIRO is ideally suited to acquire the long-term, high-cadence observations that will be required to make progress in this frontier area of astrophysics. We will coordinate our efforts with the TESS Follow-up Observing Program (TFOP), specifically as part of the Recon Spectroscopy and Precise Radial Velocity Work sub-groups.This work is supported by a grant from NASA EPSCOR.

Rapid measurement of human milk macronutrients in the neonatal intensive care unit: accuracy and precision of fourier transform mid-infrared spectroscopy.

Science.gov (United States)

Smilowitz, Jennifer T; Gho, Deborah S; Mirmiran, Majid; German, J Bruce; Underwood, Mark A

2014-05-01

Although it is well established that human milk varies widely in macronutrient content, it remains common for human milk fortification for premature infants to be based on historic mean values. As a result, those caring for premature infants often underestimate protein intake. Rapid precise measurement of human milk protein, fat, and lactose to allow individualized fortification has been proposed for decades but remains elusive due to technical challenges. This study aimed to evaluate the accuracy and precision of a Fourier transform (FT) mid-infrared (IR) spectroscope in the neonatal intensive care unit to measure human milk fat, total protein, lactose, and calculated energy compared with standard chemical analyses. One hundred sixteen breast milk samples across lactation stages from women who delivered at term (n = 69) and preterm (n = 5) were analyzed with the FT mid-IR spectroscope and with standard chemical methods. Ten of the samples were tested in replicate using the FT mid-IR spectroscope to determine repeatability. The agreement between the FT mid-IR spectroscope analysis and reference methods was high for protein and fat and moderate for lactose and energy. The intra-assay coefficients of variation for all outcomes were less than 3%. The FT mid-IR spectroscope demonstrated high accuracy in measurement of total protein and fat of preterm and term milk with high precision.

GOODS-HERSCHEL: SEPARATING HIGH-REDSHIFT ACTIVE GALACTIC NUCLEI AND STAR-FORMING GALAXIES USING INFRARED COLOR DIAGNOSTICS

Energy Technology Data Exchange (ETDEWEB)

Kirkpatrick, Allison; Pope, Alexandra [Department of Astronomy, University of Massachusetts, Amherst, MA 01002 (United States); Charmandaris, Vassilis [Department of Physics and Institute of Theoretical and Computational Physics, University of Crete, GR-71003, Heraklion (Greece); Daddi, Emmanuele; Elbaz, David; Pannella, Maurilio; Aussel, Herve; Dasyra, Kalliopi; Leiton, Roger [Laboratoire AIM, CEA/DSM-CNRS-Universite Paris Diderot, Irfu/SAp, Orme des Merisiers, F-91191 Gif-sur-Yvette (France); Hwang, Ho Seong [Smithsonian Astrophysical Observatory, 60 Garden Street, Cambridge, MA 02138 (United States); Scott, Douglas; Magnelli, Benjamin; Popesso, Paola [Max-Planck-Institut fuer Extraterrestrische Physik (MPE), Postfach 1312, D-85741, Garching (Germany); Altieri, Bruno; Coia, Daniela; Valtchanov, Ivan [Herschel Science Centre, European Space Astronomy Centre, Villanueva de la Canada, E-28691 Madrid (Spain); Dannerbauer, Helmut [Universitaet Wien, Institut fuer Astrophysik, Tuerkenschanzstrasse 17, A-1180 Wien (Austria); Dickinson, Mark; Kartaltepe, Jeyhan [National Optical Astronomy Observatory, 950 North Cherry Avenue, Tucson, AZ 85719 (United States); Magdis, Georgios [Department of Physics, University of Oxford, Keble Road, Oxford OX1 3RH (United Kingdom)

2013-02-15

We have compiled a large sample of 151 high-redshift (z = 0.5-4) galaxies selected at 24 {mu}m (S {sub 24} > 100 {mu}Jy) in the GOODS-N and ECDFS fields for which we have deep Spitzer IRS spectroscopy, allowing us to decompose the mid-infrared spectrum into contributions from star formation and activity in the galactic nuclei. In addition, we have a wealth of photometric data from Spitzer IRAC/MIPS and Herschel PACS/SPIRE. We explore how effective different infrared color combinations are at separating our mid-IR spectroscopically determined active galactic nuclei from our star-forming galaxies. We look in depth at existing IRAC color diagnostics, and we explore new color-color diagnostics combining mid-IR, far-IR, and near-IR photometry, since these combinations provide the most detail about the shape of a source's IR spectrum. An added benefit of using a color that combines far-IR and mid-IR photometry is that it is indicative of the power source driving the IR luminosity. For our data set, the optimal color selections are S {sub 250}/S {sub 24} versus S {sub 8}/S {sub 3.6} and S {sub 100}/S {sub 24} versus S {sub 8}/S {sub 3.6}; both diagnostics have {approx}10% contamination rate in the regions occupied primarily by star-forming galaxies and active galactic nuclei, respectively. Based on the low contamination rate, these two new IR color-color diagnostics are ideal for estimating both the mid-IR power source of a galaxy when spectroscopy is unavailable and the dominant power source contributing to the IR luminosity. In the absence of far-IR data, we present color diagnostics using the Wide-field Infrared Survey Explorer mid-IR bands which can efficiently select out high-z (z {approx} 2) star-forming galaxies.

Optical field emission from resonant gold nanorods driven by femtosecond mid-infrared pulses

Energy Technology Data Exchange (ETDEWEB)

Kusa, F. [Department of Applied Physics, Tokyo University of Agriculture and Technology, 2-24-16 Nakacho, Koganei Tokyo 184-8588 (Japan); Institute of Industrial Science, the University of Tokyo, 4-6-1 Komaba, Meguro-ku, Tokyo 153-8505 (Japan); Echternkamp, K. E.; Herink, G.; Ropers, C. [4th Physical Institute – Solids and Nanostructures, University of Göttingen, 37077 Göttingen (Germany); Ashihara, S., E-mail: ashihara@iis.u-tokyo.ac.jp [Institute of Industrial Science, the University of Tokyo, 4-6-1 Komaba, Meguro-ku, Tokyo 153-8505 (Japan)

2015-07-15

We demonstrate strong-field photoelectron emission from gold nanorods driven by femtosecond mid-infrared optical pulses. The maximum photoelectron yield is reached at the localized surface plasmon resonance, indicating that the photoemission is governed by the resonantly-enhanced optical near-field. The wavelength- and field-dependent photoemission yield allows for a noninvasive determination of local field enhancements, and we obtain intensity enhancement factors close to 1300, in good agreement with finite-difference time domain computations.

Mid-infrared spectroscopy and multivariate analysis for determination of tetracycline residues in cow's milk

Directory of Open Access Journals (Sweden)

Lizeth Mariel Casarrubias-Torres

2018-01-01

Full Text Available Mid-infrared spectroscopy and chemometric analysis were tested to determine tetracycline's residues in cow's milk. Cow's milk samples (n = 30 were spiked with tetracycline, chlortetracycline, and oxytetracycline in the range of 10-400 µg/l. Chemometric models to quantify each of the tetracycline's residues were developed by applying Partial Components Regression and Partial Least Squares algorithms. The Soft Independent Modeling of Class Analogy model was used to differentiate between pure milk and milk sample with tetracycline residues. The best models for predicting the levels of these antibiotics were obtained using Partial Least Square 1 algorithm (coefficient of determination between 0.997-0.999 and the standard error of calibration from 1.81 to 2.95. The Soft Independent Modeling of Class Analogy model showed well-separated groups allowing classification of milk samples and milk sample with antibiotics. The obtained results demonstrate the great analytical potential of chemometrics coupled with mid-infrared spectroscopy for the prediction of antibiotic in cow's milk at a concentration of microgram per litre (µg/l. This technique can be used to verify the safety of the milk rapidly and reliably.

Fabrication of Shatter-Proof Metal Hollow-Core Optical Fibers for Endoscopic Mid-Infrared Laser Applications

Directory of Open Access Journals (Sweden)

Katsumasa Iwai

2018-04-01

Full Text Available A method for fabricating robust and thin hollow-core optical fibers that carry mid-infrared light is proposed for use in endoscopic laser applications. The fiber is made of stainless steel tubing, eliminating the risk of scattering small glass fragments inside the body if the fiber breaks. To reduce the inner surface roughness of the tubing, a polymer base layer is formed prior to depositing silver and optical-polymer layers that confine light inside the hollow core. The surface roughness is greatly decreased by re-coating thin polymer base layers. Because of this smooth base layer surface, a uniform optical-polymer film can be formed around the core. As a result, clear interference peaks are observed in both the visible and mid-infrared regions. Transmission losses were also low for the carbon dioxide laser used for medical treatments as well as the visible laser diode used for an aiming beam. Measurements of bending losses for these lasers demonstrate the feasibility of the designed fiber for endoscopic applications.

Mid-infrared fiber-coupled supercontinuum spectroscopic imaging using a tapered chalcogenide photonic crystal fiber

Science.gov (United States)

Rosenberg Petersen, Christian; Prtljaga, Nikola; Farries, Mark; Ward, Jon; Napier, Bruce; Lloyd, Gavin Rhys; Nallala, Jayakrupakar; Stone, Nick; Bang, Ole

2018-02-01

We present the first demonstration of mid-infrared spectroscopic imaging of human tissue using a fiber-coupled supercontinuum source spanning from 2-7.5 μm. The supercontinuum was generated in a tapered large mode area chalcogenide photonic crystal fiber in order to obtain broad bandwidth, high average power, and single-mode output for good imaging properties. Tissue imaging was demonstrated in transmission by raster scanning over a sub-mm region of paraffinized colon tissue on CaF2 substrate, and the signal was measured using a fiber-coupled grating spectrometer. This demonstration has shown that we can distinguish between epithelial and surrounding connective tissues within a paraffinized section of colon tissue by imaging at discrete wavelengths related to distinct chemical absorption features.

Optical Frequency Comb Fourier Transform Spectroscopy with Resolution Exceeding the Limit Set by the Optical Path Difference

Science.gov (United States)

Foltynowicz, Aleksandra; Rutkowski, Lucile; Johanssson, Alexandra C.; Khodabakhsh, Amir; Maslowski, Piotr; Kowzan, Grzegorz; Lee, Kevin; Fermann, Martin

2015-06-01

Fourier transform spectrometers (FTS) based on optical frequency combs (OFC) allow detection of broadband molecular spectra with high signal-to-noise ratios within acquisition times orders of magnitude shorter than traditional FTIRs based on thermal sources. Due to the pulsed nature of OFCs the interferogram consists of a series of bursts rather than a single burst at zero optical path difference (OPD). The comb mode structure can be resolved by acquiring multiple bursts, in both mechanical FTS systems and dual-comb spectroscopy. However, in all existing demonstrations the resolution was ultimately limited either by the maximum available OPD between the interferometer arms or by the total acquisition time enabled by the storage memory. We present a method that provides spectral resolution exceeding the limit set by the maximum OPD using an interferogram containing only a single burst. The method allows measurements of absorption lines narrower than the OPD-limited resolution without any influence of the instrumental lineshape function. We demonstrate this by measuring undistorted CO2 and CO absorption lines with linewidth narrower than the OPD-limited resolution using OFC-based mechanical FTS in the near- and mid-infrared wavelength ranges. The near-infrared system is based on an Er:fiber femtosecond laser locked to a high finesse cavity, while the mid-infrared system is based on a Tm:fiber-laser-pumped optical parametric oscillator coupled to a multi-pass cell. We show that the method allows acquisition of high-resolution molecular spectra with interferometer length orders of magnitude shorter than traditional FTIR. Mandon, J., G. Guelachvili, and N. Picque, Nat. Phot., 2009. 3(2): p. 99-102. Zeitouny, M., et al., Ann. Phys., 2013. 525(6): p. 437-442. Zolot, A.M., et al., Opt. Lett., 2012. 37(4): p. 638-640.

YSOVAR: Mid-infrared variability in the star-forming region Lynds 1688

Energy Technology Data Exchange (ETDEWEB)

Günther, H. M.; Poppenhaeger, K.; Wolk, S. J.; Hora, J. L. [Harvard-Smithsonian Center for Astrophysics, 60 Garden Street, Cambridge, MA 02138 (United States); Cody, A. M. [Spitzer Science Center, California Institute of Technology, Pasadena, CA 91125 (United States); Covey, K. R. [Lowell Observatory, 1400 West Mars Hill Road, Flagstaff, AZ 86001 (United States); Hillenbrand, L. A. [Department of Astronomy, California Institute of Technology, Pasadena, CA 91125 (United States); Plavchan, P. [NASA Exoplanet Science Institute, California Institute of Technology, 770 South Wilson Avenue, Pasadena, CA 91125 (United States); Rebull, L. M.; Stauffer, J. R. [Spitzer Science Center/Caltech, 1200 East California Boulevard, Pasadena, CA 91125 (United States); Allen, L. [National Optical Astronomy Observatories, Tucson, AZ 85719 (United States); Bayo, A. [Max Planck Institut für Astronomie, Königstuhl 17, D-69117 Heidelberg (Germany); Gutermuth, R. A. [Department of Astronomy, University of Massachusetts, Amherst, MA 01003 (United States); Meng, H. Y. A. [Infrared Processing and Analysis Center, California Institute of Technology, MC 100-22, 770 South Wilson Avenue, Pasadena, CA 91125 (United States); Morales-Calderón, M. [Centro de Astrobiología (INTA-CSIC), ESAC Campus, P.O. Box 78, E-28691 Villanueva de la Canada (Spain); Parks, J. R. [Department of Physics and Astronomy, Georgia State University, 25 Park Place South, Atlanta, GA 30303 (United States); Song, Inseok, E-mail: hguenther@cfa.harvard.edu [Physics and Astronomy Department, University of Georgia, Athens, GA 30602-2451 (United States)

2014-12-01

The emission from young stellar objects (YSOs) in the mid-infrared (mid-IR) is dominated by the inner rim of their circumstellar disks. We present IR data from the Young Stellar Object VARiability (YSOVAR) survey of ∼800 objects in the direction of the Lynds 1688 (L1688) star-forming region over four visibility windows spanning 1.6 yr using the Spitzer Space Telescope in its warm mission phase. Among all light curves, 57 sources are cluster members identified based on their spectral energy distribution and X-ray emission. Almost all cluster members show significant variability. The amplitude of the variability is larger in more embedded YSOs. Ten out of 57 cluster members have periodic variations in the light curves with periods typically between three and seven days, but even for those sources, significant variability in addition to the periodic signal can be seen. No period is stable over 1.6 yr. Nonperiodic light curves often still show a preferred timescale of variability that is longer for more embedded sources. About half of all sources exhibit redder colors in a fainter state. This is compatible with time-variable absorption toward the YSO. The other half becomes bluer when fainter. These colors can only be explained with significant changes in the structure of the inner disk. No relation between mid-IR variability and stellar effective temperature or X-ray spectrum is found.

SPECTRAL CHARACTERISTICS OF MID-INFRARED LIGHT-EMITTING DIODES BASED ON InAs (Sb,P

Directory of Open Access Journals (Sweden)

N. K. Zhumashev

2016-01-01

Full Text Available Subject of Study. We consider spectral characteristics of mid-infrared light-emitting diodes with heterostructures based on InAs(Sb,P emitting at T=300 K in the wavelength range 3.4–4.1 micrometers. The aim of the study was to search for the ways of increasing the diode efficiency. Methods. The heterostructures were grown from metal-organic chemical compounds with the use of vapor-phase epitaxial technique. The spectra were recorded under pulse excitation with the use of computer-controlled installation employing MDR-23 grating monochromator and a lock-in amplifier. InSb photodiode was used as a detector. Comparative study of electroluminescence spectra of the diodes was carried out at the temperatures equal to 300 K and 77 K. We compared the obtained data with the calculation results of the band diagrams of the heterostructures. Main Results. As a result of comparative study of the electroluminescence spectra of the diodes recorded at 300 K and 77 K we have established that increasing of their efficiency is hindered by substantial influence of Auger recombination. For the first time at 77 К we have observed the effect of stimulated emission from InAsSb active layer in light-emitting structures made of InAs/InAsSb/InAsSbP. For heterostructures with quantum wells InAs/(InAs/InAsSb/InAsSbP we have found out that at 77 К the carrier recombination occurs outside quantum wells, which points out to the insufficient carrier localization in the active layer. Thus, we have shown that the efficiency of mid-infrared light-emitting diodes based on InAs(Sb,P can be increased via suppression of Auger-recombination and improvement of carrier localization in the active region. Practical Relevance. The results of the study can be used for development of heterostructures for mid-infrared light-emitting diodes.

THE MID-INFRARED EXTINCTION LAW IN THE OPHIUCHUS, PERSEUS, AND SERPENS MOLECULAR CLOUDS

International Nuclear Information System (INIS)

Chapman, Nicholas L.; Mundy, Lee G.; Lai, Shih-Ping; Evans, Neal J. II

2009-01-01

We compute the mid-IR extinction law from 3.6 to 24 μm in three molecular clouds-Ophiuchus, Perseus, and Serpens-by combining data from the 'Cores to Disks' Spitzer Legacy Science program with deep JHK s imaging. Using a new technique, we are able to calculate the line-of-sight (LOS) extinction law toward each background star in our fields. With these LOS measurements, we create, for the first time, maps of the χ 2 deviation of the data from two extinction law models. Because our χ 2 maps have the same spatial resolution as our extinction maps, we can directly observe the changing extinction law as a function of the total column density. In the Spitzer Infrared Array Camera (IRAC) bands, 3.6-8 μm, we see evidence for grain growth. Below A K s = 0.5, our extinction law is well fitted by the Weingartner and Draine R V = 3.1 diffuse interstellar-medium dust model. As the extinction increases, our law gradually flattens, and for A K s ≥1, the data are more consistent with the Weingartner and Draine R V = 5.5 model that uses larger maximum dust grain sizes. At 24 μm, our extinction law is 2-4 times higher than the values predicted by theoretical dust models, but is more consistent with the observational results of Flaherty et al. Finally, from our χ 2 maps we identify a region in Perseus where the IRAC extinction law is anomalously high considering its column density. A steeper near-IR extinction law than the one we have assumed may partially explain the IRAC extinction law in this region.

Highly doped InP as a low loss plasmonic material for mid-IR region

DEFF Research Database (Denmark)

Panah, Mohammad Esmail Aryaee; Takayama, Osamu; Morozov, S. V.

2016-01-01

by fitting the calculated infrared reflectance spectra to the measured ones. The retrieved permittivity was then used to simulate surface plasmon polaritons (SPPs) propagation on flat and structured surfaces, and the simulation results were verified in direct experiments. SPPs at the top and bottom......We study plasmonic properties of highly doped InP in the mid-infrared (IR) range. InP was grown by metal-organic vapor phase epitaxy (MOVPE) with the growth conditions optimized to achieve high free electron concentrations by doping with silicon. The permittivity of the grown material was found...... interfaces of the grown epilayer were excited by the prism coupling. A high-index Ge hemispherical prism provides efficient coupling conditions of SPPs on flat surfaces and facilitates acquiring their dispersion diagrams. We observed diffraction into symmetry-prohibited diffraction orders stimulated...

Demonstration of a mid-infrared NO molecular Faraday optical filter.

Science.gov (United States)

Wu, Kuijun; Feng, Yutao; Li, Juan; Yu, Guangbao; Liu, Linmei; Xiong, Yuanhui; Li, Faquan

2017-12-11

A molecular Faraday optical filter (MFOF) working in the mid-infrared region is realized for the first time. NO molecule was used as the working material of the MFOF for potential applications in atmospheric remote sensing and combustion diagnosis. We develop a complete theory to describe the performance of MFOF by taking both Zeeman absorption and Faraday rotation into account. We also record the Faraday rotation transmission (FRT) signal using a quantum cascade laser over the range of 1,820 cm -1 to 1,922 cm -1 and calibrate it by using a 101.6 mm long solid germanium etalon with a free spectral range of 0.012 cm -1 . Good agreement between the simulation results and experimental data is achieved. The NO-MFOF's transmission characteristics as a function of magnetic field and pressure are studied in detail. Both Comb-like FRT spectrum and single branch transmission spectrum are obtained by changing the magnetic field. The diversity of FRT spectrum expands the range of potential applications in infrared optical remote sensing. This filtering method can also be extended to the lines of other paramagnetic molecules.

Four novel alkyl 2-cyanoacylate monomers and their use in latent fingermark detection by mid-infrared spectral imaging.

Science.gov (United States)

Tahtouh, Mark; Scott, Sonia A; Kalman, John R; Reedy, Brian J

2011-04-15

Four novel alkyl 2-cyanoacrylate monomers (alkyl=1-cyanoethyl, 2-cyanoethyl, trideuteromethyl and pentadeuteroethyl) have been tested for their ability to develop latent fingermarks that can then be visualized using mid-infrared spectral (chemical) imaging. Each of the four monomers was chosen for its potential to produce a strong, isolated infrared spectral band in its corresponding polymer (to provide spectral contrast against most backgrounds), as well as for its potential ability to be fumed onto fingermarks in the manner of conventional ethyl 2-cyanoacrylate (superglue). With the exception of the 2-cyanoethyl 2-cyanoacrylate, which had to be fumed under reduced pressure, all of the monomers were found to be sufficiently volatile to be fumed in a conventional fuming cabinet. All four monomers polymerized selectively on fingermark ridges on a variety of non-porous and semi-porous surfaces, leading to excellent development of the fingermarks. Unfortunately, although high quality mid-infrared spectral images of the fingermarks could be formed for all of the polymers at various frequencies, the new CN or CD stretching vibrations did not give rise to strong enough absorption intensities for good contrast on difficult backgrounds such as polymer banknotes. However, in the 1-cyanoethyl 2-cyanoacrylate polymer, the presence of the additional nitrile group had the unintended but desirable effect of shifting the strong CO absorption to higher frequencies, moving it away from interfering banknote absorptions. This enabled fingermark contrast to be achieved even against the intaglio printing on the banknotes. Copyright © 2010 Elsevier Ireland Ltd. All rights reserved.

Analytical potential of mid-infrared detection in capillary electrophoresis and liquid chromatography: A review

International Nuclear Information System (INIS)

Kuligowski, Julia; Quintas, Guillermo; Guardia, Miguel de la; Lendl, Bernhard

2010-01-01

Literature published in the last decade concerning the use of mid-infrared spectrometry as a detection system in separation techniques employing a liquid mobile phase is reviewed. In addition to the continued use of isocratic liquid chromatographic (LC) techniques, advances in chemometric data evaluation techniques now allow the use of gradient techniques on a routine basis, thus significantly broadening the range of possible applications of LC-IR. The general trend towards miniaturized separation systems was also followed for mid-IR detection where two key developments are of special importance. Firstly, concerning on-line detection the advent of micro-fabricated flow-cells with inner volumes of only a few nL for transmission as well as attenuated total reflection measurements enabled on-line mid-IR detection in capillary LC and opened the path for the first successful realization of on-line mid-IR detection in capillary zone electrophoresis as well as micellar electrokinetic chromatography. Secondly, concerning off-line detection the use of micro-flow through dispensers now enables to concentrate eluting analytes on dried spots sized a few tens of micrometers, thus matching the dimensions for sensitive detection by mid-IR microscopy. Finally in an attempt to increase detection sensitivity of on-line mid-IR detection, mid-IR quantum cascade lasers have been used. Applications cover the field of food analysis, environmental analysis and the characterization of explosives among others. Best detection sensitivities for on-line and off-line detection have been achieved in miniaturized systems and are in the order of 50 ng and 2 ng on column, respectively.

Multispectral mid-infrared imaging using frequency upconversion

DEFF Research Database (Denmark)

Sanders, Nicolai Højer; Dam, Jeppe Seidelin; Jensen, Ole Bjarlin

2013-01-01

It has recently been shown that it is possible to upconvert infrared images to the near infrared region with high quantum efficiency and low noise by three-wave mixing with a laser field [1]. If the mixing laser is single-frequency, the upconverted image is simply a band-pass filtered version...... parameter, allowing for fast tuning and hence potentially fast image acquisition, paving the way for upconversion based real time multispectral imaging. In the present realization the upconversion module consists of an external cavity tapered diode laser in a Littrow configuration with a computer controlled...

High intensity mid infra-red spectroscopy of intersubband transitions in semiconductor quantum wells

International Nuclear Information System (INIS)

Serapiglia, G.B.

2000-01-01

High intensity (10 8 Wcm -2 ) mid-infrared spectroscopy has been used to study the optical response of intersubband transitions in InGaAs/InAlAs quantum wells with three conduction subbands. Steady state optical pumping of 2 x 10 11 cm -2 electrons into the excited vertical bar2> subband and subsequent electron relaxation (via phonon emission) back to the ground vertical bar1> subband creates a non-equilibrium phonon population (phonon occupancy∼1 at T=30K). Phonon re-absorption leads to a non-thermal electron distribution where electron-phonon scattering rates ∼200-500fs -1 are much faster than electron-electron scattering. In this regime, the intersubband absorption is inhomogeneously broadened. For substantially weaker optical pumping (∼1 saturation intensity) however, the electron distribution is able to thermalise and the absorption is homogeneously broadened. The phenomenon of electromagnetically-induced quantum coherence is demonstrated between 3 confined electron subband levels in a quantum well which are almost equally spaced in energy. Applying a strong coupling field, two-photon-resonant with the 1-3 intersubband transition, produces a pronounced narrow transparency feature in the 1-2 absorption line. This result can be understood in terms of all 3 states being simultaneously driven into ''phase-locked'' quantum coherence by a single coupling field. We describe the effect theoretically with a density matrix method and an adapted linear response theory. Efficient (∼1%) second harmonic generation, resonantly enhanced near λ=8.6μm, has been observed in asymmetric double multi-quantum well (ADQW) structures. Both waveguide mode and 45 deg. wedge multi-bounce geometries were used. The phase matching in the waveguide mode was achieved by incorporating a separate multiple QW region which modifies (via Kramers-Kronig relation) the dispersion of light. In the case of the 45 deg. wedge geometry, the phases of second harmonic waves generated at sequential

Recent advances in mid- and near-infrared spectroscopy with applications for research and teaching, focusing on petrochemistry and biotechnology relevant products

Science.gov (United States)

Heise, H. M.; Fritzsche, J.; Tkatsch, H.; Waag, F.; Karch, K.; Henze, K.; Delbeck, S.; Budde, J.

2013-11-01

Mid- and near-infrared spectroscopy is introduced as a versatile analytical method for characterizing liquid and solid chemicals as obtained from petrochemistry and biotechnology processes. Besides normal transmission measurements, special equipment with silver halide fiber-optic probes allowing efficient analysis based on mid-infrared attenuated total reflection, and an accessory for near-infrared diffuse reflection measurements, are presented. The latter technique can be used advantageously for powdered samples such as microalgae biomass and polysaccharides, as well as for different tissues such as meat samples. The advantages and disadvantages of both methods, which can be used for industrial process monitoring and chemical quality control applications, are discussed, and have been used in several research projects of BSc students within their degree course of bio- and nano-technologies of our University of Applied Sciences.

Recent advances in mid- and near-infrared spectroscopy with applications for research and teaching, focusing on petrochemistry and biotechnology relevant products

International Nuclear Information System (INIS)

Heise, H M; Fritzsche, J; Tkatsch, H; Waag, F; Karch, K; Henze, K; Delbeck, S; Budde, J

2013-01-01

Mid- and near-infrared spectroscopy is introduced as a versatile analytical method for characterizing liquid and solid chemicals as obtained from petrochemistry and biotechnology processes. Besides normal transmission measurements, special equipment with silver halide fiber-optic probes allowing efficient analysis based on mid-infrared attenuated total reflection, and an accessory for near-infrared diffuse reflection measurements, are presented. The latter technique can be used advantageously for powdered samples such as microalgae biomass and polysaccharides, as well as for different tissues such as meat samples. The advantages and disadvantages of both methods, which can be used for industrial process monitoring and chemical quality control applications, are discussed, and have been used in several research projects of BSc students within their degree course of bio- and nano-technologies of our University of Applied Sciences. (paper)

The potential of mid- and near-infrared diffuse reflectance spectroscopy for determining major- and trace-element concentrations in soils from a geochemical survey of North America

Science.gov (United States)

Reeves, J. B.; Smith, D.B.

2009-01-01

In 2004, soils were collected at 220 sites along two transects across the USA and Canada as a pilot study for a planned soil geochemical survey of North America (North American Soil Geochemical Landscapes Project). The objective of the current study was to examine the potential of diffuse reflectance (DR) Fourier Transform (FT) mid-infrared (mid-IR) and near-infrared (NIRS) spectroscopy to reduce the need for conventional analysis for the determination of major and trace elements in such continental-scale surveys. Soil samples (n = 720) were collected from two transects (east-west across the USA, and north-south from Manitoba, Canada to El Paso, Texas (USA), n = 453 and 267, respectively). The samples came from 19 USA states and the province of Manitoba in Canada. They represented 31 types of land use (e.g., national forest, rangeland, etc.), and 123 different land covers (e.g., soybeans, oak forest, etc.). The samples represented a combination of depth-based sampling (0-5 cm) and horizon-based sampling (O, A and C horizons) with 123 different depths identified. The set was very diverse with few samples similar in land use, land cover, etc. All samples were analyzed by conventional means for the near-total concentration of 49 analytes (Ctotal, Ccarbonate and Corganic, and 46 major and trace elements). Spectra were obtained using dried, ground samples using a Digilab FTS-7000 FT spectrometer in the mid- (4000-400 cm-1) and near-infrared (10,000-4000 cm-1) at 4 cm-1 resolution (64 co-added scans per spectrum) using a Pike AutoDIFF DR autosampler. Partial least squares calibrations were develop using: (1) all samples as a calibration set; (2) samples evenly divided into calibration and validation sets based on spectral diversity; and (3) samples divided to have matching analyte concentrations in calibration and validation sets. In general, results supported the conclusion that neither mid-IR nor NIRS would be particularly useful in reducing the need for conventional

Recent advances of mid-infrared compact, field deployable sensors: principles and applications

Science.gov (United States)

Tittel, Frank; Gluszek, Aleksander; Hudzikowski, Arkadiusz; Dong, Lei; Li, Chunguang; Patimisco, Pietro; Sampaolo, Angelo; Spagnolo, Vincenzo; Wojtas, Jacek

2016-04-01

The recent development of compact interband cascade lasers(ICLs) and quantum cascade lasers (QCLs) based trace gas sensors will permit the targeting of strong fundamental rotational-vibrational transitions in the mid-infrared which are one to two orders of magnitude more intense than transitions in the overtone and combination bands in the near-infrared. This has led to the design and fabrication of mid-infrared compact, field deployable sensors for use in the petrochemical industry, environmental monitoring and atmospheric chemistry. Specifically, the spectroscopic detection and monitoring of four molecular species, methane (CH4) [1], ethane (C2H6), formaldehyde (H2CO) [2] and hydrogen sulphide (H2S) [3] will be described. CH4, C2H6 and H2CO can be detected using two detection techniques: mid-infrared tunable laser absorption spectroscopy (TDLAS) using a compact multi-pass gas cell and quartz enhanced photoacoustic spectroscopy (QEPAS). Both techniques utilize state-of-the-art mid-IR, continuous wave (CW), distributed feedback (DFB) ICLs and QCLs. TDLAS was performed with an ultra-compact 54.6m effective optical path length innovative spherical multipass gas cell capable of 435 passes between two concave mirrors separated by 12.5 cm. QEPAS used a small robust absorption detection module (ADM) which consists of a quartz tuning fork (QTF), two optical windows, gas inlet/outlet ports and a low noise frequency pre-amplifier. Wavelength modulation and second harmonic detection were employed for spectral data processing. TDLAS and QEPAS can achieve minimum detectable absorption losses in the range from 10-8 to 10-11cm-1/Hz1/2. Several recent examples of real world applications of field deployable gas sensors will be described. For example, an ICL based TDLAS sensor system is capable of detecting CH4 and C2H6 concentration levels of 1 ppb in a 1 sec. sampling time, using an ultra-compact, robust sensor architecture. H2S detection was realized with a THz QEPAS sensor

[Development of a portable mid-infrared rapid analyzer for oil concentration in water based on MEMS linear sensor array].

Science.gov (United States)

Gao, Zhi-fan; Zeng, Li-bo; Shi, Lei; Li, Kai; Yang, Yuan-zhou; Wu, Qiong-shui

2014-06-01

Aiming at the existing problems such as weak environmental adaptability, low analytic efficiency and poor measuring repeatability in the traditional spectral oil analyzers, the present paper designed a portable mid-infrared rapid analyzer for oil concentration in water. To reduce the volume of the instrument, the non-symmetrical folding M-type Czerny-Turner optical structure was adopted in the core optical path. With a periodically rotating chopper, controlled by digital PID algorithm, applied for infrared light modulation, the modulating accuracy reached ±0.5%. Different from traditional grating-scanning spectrophotometers, this instrument used a fixed grating for light dispersion and avoided rotating error in the course of the measuring procedures. A new-type MEMS infrared linear sensor array was applied for modulated spectral signals detection, which improved the measuring efficiency remarkably. Optical simulation and experimental results indicate that the spectral range is 2 800 - 3 200 cm(-1), the spectral resolution is 6 cm(-1) (@3 130 cm(-1)), and the signal to noise ratio is up to 5 200 : 1. The acquisition time is 13 milliseconds per spectrogram, and the standard deviation of absorbance is less than 3 x 10(-3). These performances meet the standards of oil concentration measurements perfectly. Compared with traditional infrared spectral analyzers for oil concentration, the instrument demonstrated in this paper has many advantages such as smaller size, more efficiency, higher precision, and stronger vibration & moisture isolation. In addition, the proposed instrument is especially suitable for the environmental monitoring departments to implement real-time measurements in the field for oil concentration in water, hence it has broad prospects of application in the field of water quality monitoring.

Proposal of ultrasonic-assisted mid-infrared spectroscopy for incorporating into daily life like smart-toilet and non-invasive blood glucose sensor

Science.gov (United States)

Kitazaki, Tomoya; Mori, Keita; Yamamoto, Naoyuki; Wang, Congtao; Kawashima, Natsumi; Ishimaru, Ichiro

2017-07-01

We proposed the extremely compact beans-size snap-shot mid-infrared spectroscopy that will be able to be built in smartphones. And also the easy preparation method of thin-film samples generated by ultrasonic standing wave is proposed. Mid-infrared spectroscopy is able to identify material components and estimate component concentrations quantitatively from absorption spectra. But conventional spectral instruments were very large-size and too expensive to incorporate into daily life. And preparations of thin-film sample were very troublesome task. Because water absorption in mid-infrared lights is very strong, moisture-containing-sample thickness should be less than 100[μm]. Thus, midinfrared spectroscopy has been utilized only by analytical experts in their laboratories. Because ultrasonic standing wave is compressional wave, we can generate periodical refractive-index distributions inside of samples. A high refractiveindex plane is correspond to a reflection boundary. When we use a several MHz ultrasonic transducer, the distance between sample surface and generated first node become to be several ten μm. Thus, the double path of this distance is correspond to sample thickness. By combining these two proposed methods, as for liquid samples, urinary albumin and glucose concentrations will be able to be measured inside of toilet. And as for solid samples, by attaching these apparatus to earlobes, the enhancement of reflection lights from near skin surface will create a new path to realize the non-invasive blood glucose sensor. Using the small ultrasonic-transducer whose diameter was 10[mm] and applied voltage 8[V], we detected the internal reflection lights from colored water as liquid sample and acrylic board as solid sample.

MID- AND FAR-INFRARED PROPERTIES OF A COMPLETE SAMPLE OF LOCAL ACTIVE GALACTIC NUCLEI

International Nuclear Information System (INIS)

Ichikawa, Kohei; Ueda, Yoshihiro; Terashima, Yuichi; Oyabu, Shinki; Gandhi, Poshak; Nakagawa, Takao; Matsuta, Keiko

2012-01-01

We investigate the mid- (MIR) to far-infrared (FIR) properties of a nearly complete sample of local active galactic nuclei (AGNs) detected in the Swift/Burst Alert Telescope (BAT) all-sky hard X-ray (14-195 keV) survey, based on the cross correlation with the AKARI infrared survey catalogs complemented by those with Infrared Astronomical Satellite and Wide-field Infrared Survey Explorer. Out of 135 non-blazer AGNs in the Swift/BAT nine-month catalog, we obtain the MIR photometric data for 128 sources either in the 9, 12, 18, 22, and/or 25 μm band. We find good correlation between their hard X-ray and MIR luminosities over three orders of magnitude (42 λ (9, 18 μm) < 45), which is tighter than that with the FIR luminosities at 90 μm. This suggests that thermal emission from hot dusts irradiated by the AGN emission dominate the MIR fluxes. Both X-ray unabsorbed and absorbed AGNs follow the same correlation, implying isotropic infrared emission, as expected in clumpy dust tori rather than homogeneous ones. We find excess signals around 9 μm in the averaged infrared spectral energy distribution from heavy obscured 'new type' AGNs with small scattering fractions in the X-ray spectra. This could be attributed to the polycyclic aromatic hydrocarbon emission feature, suggesting that their host galaxies have strong starburst activities.

High-speed infrared imaging for material characterization in experimental mechanics experiments

Science.gov (United States)

Gagnon, Marc-André; Marcotte, Frédérick; Lagueux, Philippe; Farley, Vincent; Guyot, Éric; Morton, Vince

2017-10-01

Heat transfers are involved in many phenomena such as friction, tensile stress, shear stress and material rupture. Among the challenges encountered during the characterization of such thermal patterns is the need for both high spatial and temporal resolution. Infrared imaging provides information about surface temperature that can be attributed to the stress response of the material and breaking of chemical bounds. In order to illustrate this concept, tensile and shear tests were carried out on steel, aluminum and carbon fiber composite materials and monitored using high-speed (Telops FASTM2K) and high-definition (Telops HD-IR) infrared imaging. Results from split-Hopkinson experiments carried out on a polymer material at high strain-rate are also presented. The results illustrate how high-speed and high-definition infrared imaging in the midwave infrared (MWIR, 3 - 5 μm) spectral range can provide detailed information about the thermal properties of materials undergoing mechanical testing.

Mid-infrared Fe2+:ZnSe semiconductor saturable absorber mirror for passively Q-switched Er3+-doped ZBLAN fiber laser

Directory of Open Access Journals (Sweden)

Shougui Ning

2018-02-01

Full Text Available A mid-infrared (mid-IR semiconductor saturable absorber mirror (SESAM based on Fe2+:ZnSe for passively Q-switched Er3+-doped ZBLAN fiber laser has been demonstrated. Fe2+:ZnSe SESAM was fabricated by electron beam evaporation method. Fe2+ was innovatively doped into the reflective Bragg stack, in which ZnSe layer served as both doped matrix and high refractive layer during the fabricating process. By using the Fe2+:ZnSe SESAM, stable passively Q-switched pulses with the minimum pulse width of 0.43 μs under a repetition rate of 160.82 kHz were obtained. The recorded maximum average output power of 873 mW with a peak power of 12.59 W and pulse energy of 5.43 μJ were achieved. The results demonstrated a new method for fabricating Fe2+:ZnSe SESAM, which can be used in compact mid-IR Q-switched fiber laser.

Near-infrared high-resolution real-time omnidirectional imaging platform for drone detection

Science.gov (United States)

Popovic, Vladan; Ott, Beat; Wellig, Peter; Leblebici, Yusuf

2016-10-01

Recent technological advancements in hardware systems have made higher quality cameras. State of the art panoramic systems use them to produce videos with a resolution of 9000 x 2400 pixels at a rate of 30 frames per second (fps).1 Many modern applications use object tracking to determine the speed and the path taken by each object moving through a scene. The detection requires detailed pixel analysis between two frames. In fields like surveillance systems or crowd analysis, this must be achieved in real time.2 In this paper, we focus on the system-level design of multi-camera sensor acquiring near-infrared (NIR) spectrum and its ability to detect mini-UAVs in a representative rural Swiss environment. The presented results show the UAV detection from the trial that we conducted during a field trial in August 2015.

A mid- to far-infrared variability study of the intermediate Seyfert galaxy, Mk 6

International Nuclear Information System (INIS)

Clement, R.; Sembay, S.; Coe, M.J.; Hanson, C.G.

1988-01-01

A mid- to far-infrared (MFIR) variability study of the intermediate Seyfert galaxy, Mk 6, is presented using data from the Infrared Astronomical Satellite (IRAS). We have analysed 25 observations of this source covering a period of about 1 month. Within the expected errors, the source shows no evidence for variability and this may be an indication that there is a strong contribution to the MFIR emission from thermal re-radiation by dust. This interpretation is consistent with previous studies which suggest that the bulk of the far-infrared (30 -100 μm) emission in Seyfert galaxies originates from cool (35 - 75 K) dust associated with star formation regions in the surrounding envelope of the active nucleus. The lack of variability at 12 and 25 μm can also be readily explained by dust emission. However, in this case, the dust temperatures required to produce emission at these wavelengths makes the narrow-line region a more feasible location for the dust grains. (author)

Mid infrared resonant cavity detectors and lasers with epitaxial lead-chalcogenides

Science.gov (United States)

Zogg, H.; Rahim, M.; Khiar, A.; Fill, M.; Felder, F.; Quack, N.

2010-09-01

Wavelength tunable emitters and detectors in the mid-IR wavelength region allow applications including thermal imaging and gas spectroscopy. One way to realize such tunable devices is by using a resonant cavity. By mechanically changing the cavity length with MEMS mirror techniques, the wavelengths may be tuned over a considerable range. Resonant cavity enhanced detectors (RCED) are sensitive at the cavity resonance only. They may be applied for low resolution spectroscopy, and, when arrays of such detectors are realized, as multicolour IR-FPA or "IR-AFPA", adaptive focal plane arrays. We report the first room temperature mid-IR VECSEL (vertical external cavity surface emitting laser) with a wavelength above 3 μm. The active region is just 850 nm PbSe, followed by a 2.5 pair Bragg mirror. Output power is > 10 mW at RT.

MID-INFRARED HIGH-CONTRAST IMAGING OF HD 114174 B: AN APPARENT AGE DISCREPANCY IN A ''SIRIUS-LIKE'' BINARY SYSTEM

Energy Technology Data Exchange (ETDEWEB)

Matthews, Christopher T.; Crepp, Justin R. [Department of Physics, University of Notre Dame, 225 Nieuwland Science Hall, Notre Dame, IN 46556 (United States); Skemer, Andrew; Hinz, Philip M.; Bailey, Vanessa P.; Defrere, Denis; Leisenring, Jarron [Department of Astronomy, University of Arizona, 993 N. Cherry Ave, Tucson, AZ 85721 (United States); Gianninas, Alexandros; Kilic, Mukremin [Department of Physics and Astronomy, University of Oklahoma, Norman, OK 73019 (United States); Skrutskie, Michael [Department of Astronomy, University of Virginia, Charlottesville, VA 22904 (United States); Esposito, Simone; Puglisi, Alfio [Istituto Nazionale di Astrofisica, Osservatorio Astrofisico di Arcetri Largo E. Fermi I-550125 Firenze (Italy)

2014-03-10

We present new observations of the faint ''Sirius-like'' companion discovered to orbit HD 114174. Previous attempts to image HD 114174 B at mid-infrared wavelengths using NIRC2 at Keck have resulted in a non-detection. Our new L'-band observations taken with the Large Binocular Telescope and L/M-band InfraRed Camera recover the companion (ΔL = 10.15 ± 0.15 mag, ρ = 0.''675 ± 0.''016) with a high signal-to-noise ratio (10σ). This measurement represents the deepest L' high-contrast imaging detection at subarcsecond separations to date, including extrasolar planets. We confirm that HD 114174 B has near-infrared colors consistent with the interpretation of a cool white dwarf (WD; J – L' = 0.76 ± 0.19 mag, K – L' = 0.64 ± 0.20). New model fits to the object's spectral energy distribution indicate a temperature T {sub eff} = 4260 ± 360 K, surface gravity log g = 7.94 ± 0.03, a cooling age t{sub c} ≈ 7.8 Gyr, and mass M = 0.54 ± 0.01 M {sub ☉}. We find that the cooling ages given by theoretical atmospheric models do not agree with the age of HD 114174 A derived from both isochronological and gyrochronological analyses. We speculate on possible scenarios to explain the apparent age discrepancy between the primary and secondary. HD 114174 B is a nearby benchmark WD that will ultimately enable a dynamical mass estimate through continued Doppler and astrometric monitoring. Efforts to characterize its physical properties in detail will test theoretical atmospheric models and improve our understanding of WD evolution, cooling, and progenitor masses.

Active mode-locking of mid-infrared quantum cascade lasers with short gain recovery time.

Science.gov (United States)

Wang, Yongrui; Belyanin, Alexey

2015-02-23

We investigate the dynamics of actively modulated mid-infrared quantum cascade lasers (QCLs) using space- and time-domain simulations of coupled density matrix and Maxwell equations with resonant tunneling current taken into account. We show that it is possible to achieve active mode locking and stable generation of picosecond pulses in high performance QCLs with a vertical laser transition and a short gain recovery time by bias modulation of a short section of a monolithic Fabry-Perot cavity. In fact, active mode locking in QCLs with a short gain recovery time turns out to be more robust to the variation of parameters as compared to previously studied lasers with a long gain recovery time. We investigate the effects of spatial hole burning and phase locking on the laser output.

A spectroscopic comparison of selected Chinese kaolinite, coal bearing kaolinite and halloysite - A mid-infrared and near-infrared study

Energy Technology Data Exchange (ETDEWEB)

Cheng, H.F.; Yang, J.; Liu, Q.F.; Zhang, J.S.; Frost, R.L. [Queensland University of Technology, Brisbane, Qld. (Australia). Faculty of Science & Technology

2010-11-15

Mid-infrared (MIR) and near-infrared (NIR) spectroscopy have been compared and evaluated for differentiating kaolinite, coal bearing kaolinite and halloysite. Kaolinite, coal bearing kaolinite and halloysite are the three relative abundant minerals of the kaolin group, especially in China. In the MIR spectra, the differences are shown in the 3000-3600 cm{sup -1} between kaolinite and halloysite. It cannot obviously differentiate the kaolinite and halloysite, leaving alone kaolinite and coal bearing kaolinite. However, NIR, together with MIR, gives us the sufficient evidence to differentiate the kaolinite and halloysite, especially kaolinite and coal bearing kaolinite. There are obvious differences between kaolinite and halloysite in all range of their spectra, and they also show some difference between kaolinite and coal bearing kaolinite. Therefore, the reproducibility of measurement, signal to noise ratio and richness of qualitative information should be simultaneously considered for proper selection of a spectroscopic method for mineral analysis.

Using mid-Infrared External Reflectance Spectroscopy to Distinguish Between Different Commercially Produced Poly[Methyl MethAcrylate] (PMMA) Samples - A Null Result

Science.gov (United States)

Fajardo, Mario; Neel, Christopher; Lacina, David

2017-06-01

We report (null) results of experiments testing the hypothesis that mid-infrared (mid-IR) spectroscopy can be used to distinguish samples of poly[methyl methacrylate] (PMMA) obtained from different commercial suppliers. This work was motivated by the desire for a simple non-destructive and non-invasive test for pre-sorting PMMA samples prior to use in shock and high-strain-rate experiments, where PMMA is commonly used as a standard material. We discuss: our choice of mid-IR external reflectance spectroscopy, our approach to recording reflectance spectra at near-normal (θ = 0 + / - 5 degree) incidence and for extracting the wavelength-weighted absorption spectrum from the raw reflectance data via a Kramers-Krönig analysis. We employ extensive signal, which necessitates adopting a special experimental protocol to mitigate the effects of instrumental drift. Finally, we report spectra of three PMMA samples with different commercial pedigrees, and show that they are virtually identical (+ / - 1 % error, 95% confidence); obviating the use of mid-IR reflectance spectroscopy to tell the samples apart.

VERY LARGE INTERSTELLAR GRAINS AS EVIDENCED BY THE MID-INFRARED EXTINCTION

Energy Technology Data Exchange (ETDEWEB)

Wang, Shu; Jiang, B. W. [Department of Astronomy, Beijing Normal University, Beijing 100875 (China); Li, Aigen, E-mail: shuwang@mail.bnu.edu.cn, E-mail: bjiang@bnu.edu.cn, E-mail: wanshu@missouri.edu, E-mail: lia@missouri.edu [Department of Physics and Astronomy, University of Missouri, Columbia, MO 65211 (United States)

2015-09-20

The sizes of interstellar grains are widely distributed, ranging from a few angstroms to a few micrometers. The ultraviolet (UV) and optical extinction constrains the dust in the size range of a couple hundredths of micrometers to several submicrometers. The near and mid infrared (IR) emission constrains the nanometer-sized grains and angstrom-sized very large molecules. However, the quantity and size distribution of micrometer-sized grains remain unknown because they are gray in the UV/optical extinction and they are too cold and emit too little in the IR to be detected by IRAS, Spitzer, or Herschel. In this work, we employ the ∼3–8 μm mid-IR extinction, which is flat in both diffuse and dense regions to constrain the quantity, size, and composition of the μm-sized grain component. We find that, together with nano- and submicron-sized silicate and graphite (as well as polycyclic aromatic hydrocarbons), μm-sized graphite grains with C/H ≈ 137 ppm and a mean size of ∼1.2 μm closely fit the observed interstellar extinction of the Galactic diffuse interstellar medium from the far-UV to the mid-IR, as well as the near-IR to millimeter thermal emission obtained by COBE/DIRBE, COBE/FIRAS, and Planck up to λ ≲ 1000 μm. The μm-sized graphite component accounts for ∼14.6% of the total dust mass and ∼2.5% of the total IR emission.

Resonance control of mid-infrared metamaterials using arrays of split-ring resonator pairs

KAUST Repository

Yue, Weisheng

2016-01-11

We present our design, fabrication and characterization of resonance-controllable metamaterials operating at mid-infrared wavelengths. The metamaterials are composed of pairs of back-to-back or face-to-face U-shape split-ring resonators (SRRs). Transmission spectra of the metamaterials are measured using Fourier-transform infrared spectroscopy. The results show that the transmission resonance is dependent on the distance between the two SRRs in each SRR pair. The dips in the transmission spectrum shift to shorter wavelengths with increasing distance between the two SRRs for both the back-to-back and face-to-face SRR pairs. The position of the resonance dips in the spectrum can hence be controlled by the relative position of the SRRs. This mechanism of resonance control offers a promising way of developing metamaterials with tunability for optical filters and bio/chemical sensing devices in integrated nano-optics.

Resonance control of mid-infrared metamaterials using arrays of split-ring resonator pairs

KAUST Repository

Yue, Weisheng; Wang, Zhihong; Whittaker, John; Schedin, Fredrik; Wu, Zhipeng; Han, Jiaguang

2016-01-01

We present our design, fabrication and characterization of resonance-controllable metamaterials operating at mid-infrared wavelengths. The metamaterials are composed of pairs of back-to-back or face-to-face U-shape split-ring resonators (SRRs). Transmission spectra of the metamaterials are measured using Fourier-transform infrared spectroscopy. The results show that the transmission resonance is dependent on the distance between the two SRRs in each SRR pair. The dips in the transmission spectrum shift to shorter wavelengths with increasing distance between the two SRRs for both the back-to-back and face-to-face SRR pairs. The position of the resonance dips in the spectrum can hence be controlled by the relative position of the SRRs. This mechanism of resonance control offers a promising way of developing metamaterials with tunability for optical filters and bio/chemical sensing devices in integrated nano-optics.

Identifying added value in high-resolution climate simulations over Scandinavia

DEFF Research Database (Denmark)

Mayer, Stephania; Fox Maule, Cathrine; Sobolowski, Stefan

2015-01-01

High-resolution data are needed in order to assess potential impacts of extreme events on infrastructure in the mid-latitudes. Dynamical downscaling offers one way to obtain this information. However, prior to implementation in any impacts assessment scheme, model output must be validated and det...

Comparative study of wine tannin classification using Fourier transform mid-infrared spectrometry and sensory analysis.

Science.gov (United States)

Fernández, Katherina; Labarca, Ximena; Bordeu, Edmundo; Guesalaga, Andrés; Agosin, Eduardo

2007-11-01

Wine tannins are fundamental to the determination of wine quality. However, the chemical and sensorial analysis of these compounds is not straightforward and a simple and rapid technique is necessary. We analyzed the mid-infrared spectra of white, red, and model wines spiked with known amounts of skin or seed tannins, collected using Fourier transform mid-infrared (FT-MIR) transmission spectroscopy (400-4000 cm(-1)). The spectral data were classified according to their tannin source, skin or seed, and tannin concentration by means of discriminant analysis (DA) and soft independent modeling of class analogy (SIMCA) to obtain a probabilistic classification. Wines were also classified sensorially by a trained panel and compared with FT-MIR. SIMCA models gave the most accurate classification (over 97%) and prediction (over 60%) among the wine samples. The prediction was increased (over 73%) using the leave-one-out cross-validation technique. Sensory classification of the wines was less accurate than that obtained with FT-MIR and SIMCA. Overall, these results show the potential of FT-MIR spectroscopy, in combination with adequate statistical tools, to discriminate wines with different tannin levels.

Nimbus-2 Level 2 Medium Resolution Infrared Radiometer (MRIR) V001

Data.gov (United States)

National Aeronautics and Space Administration — The Nimbus II Medium Resolution Infrared Radiometer (MRIR) was designed to measure electromagnetic radiation emitted and reflected from the earth and its atmosphere...

Mid-infrared emissions of Pr{sup 3+}-doped GeS{sub 2}–Ga{sub 2}S{sub 3}–CdI{sub 2} chalcohalide glasses

Energy Technology Data Exchange (ETDEWEB)

Lu, Chunfeng [State Key Laboratory of Transient Optics and Photonics, Xi’an Institute of Optics and precision Mechanics, Chinese Academy of Science (CAS), Xi’an, Shaanxi 710119 (China); Guo, Haitao, E-mail: guoht_001@opt.ac.cn [State Key Laboratory of Transient Optics and Photonics, Xi’an Institute of Optics and precision Mechanics, Chinese Academy of Science (CAS), Xi’an, Shaanxi 710119 (China); Xu, Yantao; Hou, Chaoqi; Lu, Min [State Key Laboratory of Transient Optics and Photonics, Xi’an Institute of Optics and precision Mechanics, Chinese Academy of Science (CAS), Xi’an, Shaanxi 710119 (China); He, Xin [School of Applied Physics and Materials, Wuyi University, Jiangmen, Guangdong 529020 (China); Wang, Pengfei; Li, Weinan [State Key Laboratory of Transient Optics and Photonics, Xi’an Institute of Optics and precision Mechanics, Chinese Academy of Science (CAS), Xi’an, Shaanxi 710119 (China); Peng, Bo, E-mail: bpeng@opt.ac.cn [State Key Laboratory of Transient Optics and Photonics, Xi’an Institute of Optics and precision Mechanics, Chinese Academy of Science (CAS), Xi’an, Shaanxi 710119 (China)

2014-12-15

Graphical abstract: ∼4.6 μm mid-infrared fluorescence emission from Pr{sup 3+} in the sulfide glass is successfully observed at room temperature excited by a 2.01 μm Tm{sup 3+}:YAG ceramic laser system. - Highlights: • Serial Pr{sup 3+}-doped GeS{sub 2}–Ga{sub 2}S{sub 3}–CdI{sub 2} chalcohalide glasses were synthesized. • ∼4.6 μm mid-infrared fluorescence from Pr{sup 3+} was observed at room temperature. • The compositional dependence of luminescence properties was studied. • Radiative properties have been determined using the Judd–Ofelt theory. - Abstract: For elucidation of the glass composition’s influence on the spectroscopic properties in the chalcohalide system and the discovery of a new material for applications in mid-infrared fiber-lasers, a serial Pr{sup 3+}-doped (100 − x)(0.8GeS{sub 2}·0.2Ga{sub 2}S{sub 3})xCdI{sub 2} (x = 5, 10, 15 and 20) chalcohalide glasses were prepared. ∼4.6 μm mid-infrared fluorescence emission from Pr{sup 3+} in the sulfide glass is successfully observed at room temperature excited by a 2.01 μm Tm{sup 3+}:YAG ceramic laser system, and the effective line-width of fluorescence band is 106–227 nm. Intense compositional dependence of mid-infrared emissions is found. The radiative rates of Pr{sup 3+} ions in these glasses were calculated by using the Judd–Ofelt theory.

Room-temperature mid-infrared single-photon imaging using upconversion

DEFF Research Database (Denmark)

Dam, Jeppe Seidelin; Tidemand-Lichtenberg, Peter; Pedersen, Christian

2014-01-01

The mid-wave infrared (MWIR) region is a fast developing research area due to many possible applications. Indeed a lot of research has been put into the development of novel light sources in the MWIR. This has led to very powerful sources such as quantum cascade lasers (QCL) and optical parametric...... detectors, when compared to silicon based detectors available for the visible and near visible spectral range. In fact, camera sensitivities down to the single photon level have been developed for sub-μm wavelengths. This discrepancy in sensitivity makes it attractive to perform wavelength upconversion...... upconversion efficiencies of 20 % for polarized collinear MWIR light. To make the module truly portable the laser cavity is assembled in a closed mechanical unit which ensures that visible light cannot enter from the outside, and provides a very stable mount for the optical components. Figure 1 depicts...

Application of mid-infrared free-electron laser tuned to amide bands for dissociation of aggregate structure of protein.

Science.gov (United States)

Kawasaki, Takayasu; Yaji, Toyonari; Ohta, Toshiaki; Tsukiyama, Koichi

2016-01-01

A mid-infrared free-electron laser (FEL) is a linearly polarized, high-peak powered pulse laser with tunable wavelength within the mid-infrared absorption region. It was recently found that pathogenic amyloid fibrils could be partially dissociated to the monomer form by the irradiation of the FEL targeting the amide I band (C=O stretching vibration), amide II band (N-H bending vibration) and amide III band (C-N stretching vibration). In this study, the irradiation effect of the FEL on keratin aggregate was tested as another model to demonstrate an applicability of the FEL for dissociation of protein aggregates. Synchrotron radiation infrared microscopy analysis showed that the α-helix content in the aggregate structure decreased to almost the same level as that in the monomer state after FEL irradiation tuned to 6.06 µm (amide I band). Both irradiations at 6.51 µm (amide II band) and 8.06 µm (amide III band) also decreased the content of the aggregate but to a lesser extent than for the irradiation at the amide I band. On the contrary, the irradiation tuned to 5.6 µm (non-absorbance region) changed little the secondary structure of the aggregate. Scanning-electron microscopy observation at the submicrometer order showed that the angular solid of the aggregate was converted to non-ordered fragments by the irradiation at each amide band, while the aggregate was hardly deformed by the irradiation at 5.6 µm. These results demonstrate that the amide-specific irradiation by the FEL was effective for dissociation of the protein aggregate to the monomer form.

Comparison of laser-based mitigation of fused silica surface damage using mid- versus far-infrared lasers

Energy Technology Data Exchange (ETDEWEB)

Yang, S T; Matthews, M J; Elhadj, S; Cooke, D; Guss, G M; Draggoo, V G; Wegner, P J

2009-12-16

Laser induced growth of optical damage can limit component lifetime and therefore operating costs of large-aperture fusion-class laser systems. While far-infrared (IR) lasers have been used previously to treat laser damage on fused silica optics and render it benign, little is known about the effectiveness of less-absorbing mid-IR lasers for this purpose. In this study, they quantitatively compare the effectiveness and efficiency of mid-IR (4.6 {micro}m) versus far-IR (10.6 {micro}m) lasers in mitigating damage growth on fused silica surfaces. The non-linear volumetric heating due to mid-IR laser absorption is analyzed by solving the heat equation numerically, taking into account the temperature-dependent absorption coefficient {alpha}(T) at {lambda} = 4.6 {micro}m, while far-IR laser heating is well-described by a linear analytic approximation to the laser-driven temperature rise. In both cases, the predicted results agree well with surface temperature measurements based on infrared radiometry, as well as sub-surface fictive temperature measurements based on confocal Raman microscopy. Damage mitigation efficiency is assessed using a figure of merit (FOM) relating the crack healing depth to laser power required, under minimally-ablative conditions. Based on their FOM, they show that for cracks up to at least 500 {micro}m in depth, mitigation with a 4.6 {micro}m mid-IR laser is more efficient than mitigation with a 10.6 {micro}m far-IR laser. This conclusion is corroborated by direct application of each laser system to the mitigation of pulsed laser-induced damage possessing fractures up to 225 {micro}m in depth.

"Slow-scanning" in Ground-based Mid-infrared Observations

Science.gov (United States)

Ohsawa, Ryou; Sako, Shigeyuki; Miyata, Takashi; Kamizuka, Takafumi; Okada, Kazushi; Mori, Kiyoshi; Uchiyama, Masahito S.; Yamaguchi, Junpei; Fujiyoshi, Takuya; Morii, Mikio; Ikeda, Shiro

2018-04-01

Chopping observations with a tip-tilt secondary mirror have conventionally been used in ground-based mid-infrared observations. However, it is not practical for next generation large telescopes to have a large tip-tilt mirror that moves at a frequency larger than a few hertz. We propose an alternative observing method, a "slow-scanning" observation. Images are continuously captured as movie data, while the field of view is slowly moved. The signal from an astronomical object is extracted from the movie data by a low-rank and sparse matrix decomposition. The performance of the "slow-scanning" observation was tested in an experimental observation with Subaru/COMICS. The quality of a resultant image in the "slow-scanning" observation was as good as in a conventional chopping observation with COMICS, at least for a bright point-source object. The observational efficiency in the "slow-scanning" observation was better than that in the chopping observation. The results suggest that the "slow-scanning" observation can be a competitive method for the Subaru telescope and be of potential interest to other ground-based facilities to avoid chopping.

Mid-wavelength infrared unipolar nBp superlattice photodetector

Science.gov (United States)

Kazemi, Alireza; Myers, Stephen; Taghipour, Zahra; Mathews, Sen; Schuler-Sandy, Ted; Lee, Seunghyun; Cowan, Vincent M.; Garduno, Eli; Steenbergen, Elizabeth; Morath, Christian; Ariyawansa, Gamini; Scheihing, John; Krishna, Sanjay

2018-01-01

We report a Mid-Wavelength Infrared (MWIR) barrier photodetector based on the InAs/GaSb/AlSb type-II superlattice (T2SL) material system. The nBp design consists of a single unipolar barrier (InAs/AlSb SL) placed between a 4 μm thick p-doped absorber (InAs/GaSb SL) and an n-type contact layer (InAs/GaSb SL). At 80 K, the device exhibited a 50% cut-off wavelength of 5 μm, was fully turned-ON at zero bias and the measured QE was 50% (front side illumination with no AR coating) at 4.5 μm with a dark current density of 4.7 × 10-6 A/cm2 at Vb = 50 mV. At 150 K and Vb = 50 mV, the 50% cut-off wavelength increased to 5.3 μm, and the QE was 54% at 4.5 μm with a dark current of 5.0 × 10-4 A/cm2.

Upconversion enhanced degenerate four-wave mixing in the mid-infrared for sensitive detection of acetylene in gas flows

DEFF Research Database (Denmark)

Høgstedt, Lasse; Dam, Jeppe Seidelin; Sahlberg, Anna-Lena

2014-01-01

We present a new background free method for in situ gas detection that combines degenerate four-wave mixing with an infra-red light detector based on parametric frequency upconversion of infra-red light. The system is demonstrated at mid infrared wavelengths for low concentration measurements...... of acetylene diluted in a N2 gas flow at ambient conditions. It is demonstrated that the system is able to cover more than 100 nm in scanning range and detect concentrations as low as 3 ppm based on the R9e line. A major issue in small signal measurements is scattered light and it is showed how a spatial...

THE SPATIAL EXTENT OF (U)LIRGs IN THE MID-INFRARED. I. THE CONTINUUM EMISSION

International Nuclear Information System (INIS)

DIaz-Santos, T.; Charmandaris, V.; Armus, L.; Petric, A. O.; Howell, J. H.; Murphy, E. J.; Inami, H.; Haan, S.; Marshall, J. A.; Stierwalt, S.; Surace, J. A.; Mazzarella, J. M.; Veilleux, S.; Bothun, G.; Appleton, P. N.; Evans, A. S.; Sanders, D. B.

2010-01-01

We present an analysis of the extended mid-infrared (MIR) emission of the Great Observatories All-Sky LIRG Survey sample based on 5-15 μm low-resolution spectra obtained with the Infrared Spectrograph on Spitzer. We calculate the fraction of extended emission (FEE) as a function of wavelength for the galaxies in the sample, FEE λ , defined as the fraction of the emission which originates outside of the unresolved component of a source at a given distance. We find that the FEE λ varies from one galaxy to another, but we can identify three general types of FEE λ : one where FEE λ is constant, one where features due to emission lines and polycyclic aromatic hydrocarbons appear more extended than the continuum, and a third which is characteristic of sources with deep silicate absorption at 9.7 μm. More than 30% of the galaxies have a median FEE λ larger than 0.5, implying that at least half of their MIR emission is extended. Luminous Infrared Galaxies (LIRGs) display a wide range of FEE in their warm dust continuum (0 ∼ 13.2 μ m ∼ 13.2 μ m that we find in many LIRGs suggest that the extended component of their MIR continuum emission originates in scales up to 10 kpc and may contribute as much as the nuclear region to their total MIR luminosity. The mean size of the LIRG cores at 13.2 μm is 2.6 kpc. However, once the IR luminosity of the systems reaches the threshold of L IR ∼ 10 11.8 L sun , slightly below the regime of Ultra-luminous Infrared Galaxies (ULIRGs), all sources become clearly more compact, with FEE 13.2 μ m ∼ IR ∼> 10 11.25 L sun strongly increases in those classified as mergers in their final stage of interaction. The FEE 13.2 μ m is also related to the contribution of an active galactic nucleus (AGN) to the MIR emission. Galaxies which are more AGN dominated are less extended, independently of their L IR . We finally find that the extent of the MIR continuum emission is correlated with the far-IR IRAS log(f 60 μ m /f 100 μ m

The panchromatic Hubble Andromeda treasury. VII. The steep mid-ultraviolet to near-infrared extinction curve in the central 200 pc of the M31 Bulge

International Nuclear Information System (INIS)

Dong, Hui; Lauer, Tod R.; Olsen, Knut; Saha, Abhijit; Li, Zhiyuan; Wang, Q. D.; Dalcanton, Julianne; Fouesneau, Morgan; Gordon, Karl; Bell, Eric; Bianchi, Luciana

2014-01-01

We measure the extinction curve in the central 200 pc of M31 at mid-ultraviolet to near-infrared wavelengths (from 1928 Å to 1.5 μm), using Swift/UVOT and Hubble Space Telescope (HST) Wide Field Camera 3 (WFC3)/Advanced Camera for Surveys (ACS) observations in 13 bands. Taking advantage of the high angular resolution of the HST/WFC3 and ACS detectors, we develop a method to simultaneously determine the relative extinction and the fraction of obscured starlight for five dusty complexes located in the circumnuclear region. The extinction curves of these clumps (R V = 2.4-2.5) are steeper than the average Galactic one (R V = 3.1), but are similar to optical and near-infrared curves recently measured toward the Galactic bulge (R V ∼ 2.5). This similarity suggests that steep extinction curves may be common in the inner bulge of galaxies. In the ultraviolet, the extinction curves of these clumps are also unusual. We find that one dusty clump (size < 2 pc) exhibits a strong UV bump (extinction at 2175 Å), more than three standard deviation higher than that predicted by common models. Although the high stellar metallicity of the M31 bulge indicates that there are sufficient carbon and silicon to produce large dust grains, the grains may have been destroyed by supernova explosions or past activity of the central supermassive black hole, resulting in the observed steepened extinction curve.

The panchromatic Hubble Andromeda treasury. VII. The steep mid-ultraviolet to near-infrared extinction curve in the central 200 pc of the M31 Bulge

Energy Technology Data Exchange (ETDEWEB)

Dong, Hui; Lauer, Tod R.; Olsen, Knut; Saha, Abhijit [National Optical Astronomy Observatory, Tucson, AZ 85719 (United States); Li, Zhiyuan [School of Astronomy and Space Science, Nanjing University, Nanjing 210093 (China); Wang, Q. D. [Department of Astronomy, University of Massachusetts, Amherst, MA 01003 (United States); Dalcanton, Julianne; Fouesneau, Morgan [Astronomy Department, University of Washington, Seattle, WA 98195 (United States); Gordon, Karl [Space Telescope Science Institute, 3700 San Martin Drive, Baltimore, MD 21218 (United States); Bell, Eric [Department of Astronomy, University of Michigan, Ann Arbor, MI 48109 (United States); Bianchi, Luciana, E-mail: hdong@noao.edu [Department of Physics and Astronomy, Johns Hopkins University, Baltimore, MD 21218 (United States)

2014-04-20

We measure the extinction curve in the central 200 pc of M31 at mid-ultraviolet to near-infrared wavelengths (from 1928 Å to 1.5 μm), using Swift/UVOT and Hubble Space Telescope (HST) Wide Field Camera 3 (WFC3)/Advanced Camera for Surveys (ACS) observations in 13 bands. Taking advantage of the high angular resolution of the HST/WFC3 and ACS detectors, we develop a method to simultaneously determine the relative extinction and the fraction of obscured starlight for five dusty complexes located in the circumnuclear region. The extinction curves of these clumps (R{sub V} = 2.4-2.5) are steeper than the average Galactic one (R{sub V} = 3.1), but are similar to optical and near-infrared curves recently measured toward the Galactic bulge (R{sub V} ∼ 2.5). This similarity suggests that steep extinction curves may be common in the inner bulge of galaxies. In the ultraviolet, the extinction curves of these clumps are also unusual. We find that one dusty clump (size < 2 pc) exhibits a strong UV bump (extinction at 2175 Å), more than three standard deviation higher than that predicted by common models. Although the high stellar metallicity of the M31 bulge indicates that there are sufficient carbon and silicon to produce large dust grains, the grains may have been destroyed by supernova explosions or past activity of the central supermassive black hole, resulting in the observed steepened extinction curve.

Quantitative determination of additive Chlorantraniliprole in Abamectin preparation: Investigation of bootstrapping soft shrinkage approach by mid-infrared spectroscopy

Science.gov (United States)

Yan, Hong; Song, Xiangzhong; Tian, Kuangda; Chen, Yilin; Xiong, Yanmei; Min, Shungeng

2018-02-01

A novel method, mid-infrared (MIR) spectroscopy, which enables the determination of Chlorantraniliprole in Abamectin within minutes, is proposed. We further evaluate the prediction ability of four wavelength selection methods, including bootstrapping soft shrinkage approach (BOSS), Monte Carlo uninformative variable elimination (MCUVE), genetic algorithm partial least squares (GA-PLS) and competitive adaptive reweighted sampling (CARS) respectively. The results showed that BOSS method obtained the lowest root mean squared error of cross validation (RMSECV) (0.0245) and root mean squared error of prediction (RMSEP) (0.0271), as well as the highest coefficient of determination of cross-validation (Qcv2) (0.9998) and the coefficient of determination of test set (Q2test) (0.9989), which demonstrated that the mid infrared spectroscopy can be used to detect Chlorantraniliprole in Abamectin conveniently. Meanwhile, a suitable wavelength selection method (BOSS) is essential to conducting a component spectral analysis.

A spectroscopic comparison of selected Chinese kaolinite, coal bearing kaolinite and halloysite--a mid-infrared and near-infrared study.

Science.gov (United States)

Cheng, Hongfei; Yang, Jing; Liu, Qinfu; Zhang, Jinshan; Frost, Ray L

2010-11-01

Mid-infrared (MIR) and near-infrared (NIR) spectroscopy have been compared and evaluated for differentiating kaolinite, coal bearing kaolinite and halloysite. Kaolinite, coal bearing kaolinite and halloysite are the three relative abundant minerals of the kaolin group, especially in China. In the MIR spectra, the differences are shown in the 3000-3600 cm⁻¹ between kaolinite and halloysite. It cannot obviously differentiate the kaolinite and halloysite, leaving alone kaolinite and coal bearing kaolinite. However, NIR, together with MIR, gives us the sufficient evidence to differentiate the kaolinite and halloysite, especially kaolinite and coal bearing kaolinite. There are obvious differences between kaolinite and halloysite in all range of their spectra, and they also show some difference between kaolinite and coal bearing kaolinite. Therefore, the reproducibility of measurement, signal to noise ratio and richness of qualitative information should be simultaneously considered for proper selection of a spectroscopic method for mineral analysis. Copyright © 2010 Elsevier B.V. All rights reserved.

The influence of melt purification and structure defects on mid-infrared light emitting diodes

CERN Document Server

Krier, A

2003-01-01

Mid-infrared light emitting diodes which exhibit more than 7 mW (pulsed) and 0.35 mW dc output power at 3.3 mu m and at room temperature have been fabricated by liquid phase epitaxy using Pb as a neutral solvent. Using Pb solution an increase in pulsed output power of between two and three times was obtained compared with InAs light emitting diodes (LEDs) made using rare-earth gettering. The performance improvements were attributed to a reduction in residual carrier concentration arising from the removal of un-intentional donors and structure defects in the InAs active region material. These LEDs are well matched to the CH sub 4 absorption spectrum and potentially could form the basis of a practical infrared CH sub 4 gas sensor.

low-Cost, High-Performance Alternatives for Target Temperature Monitoring Using the Near-Infrared Spectrum

Energy Technology Data Exchange (ETDEWEB)

Virgo, Mathew [Argonne National Lab. (ANL), Argonne, IL (United States); Quigley, Kevin J. [Argonne National Lab. (ANL), Argonne, IL (United States); Chemerisov, Sergey [Argonne National Lab. (ANL), Argonne, IL (United States); Vandegrift, George F. [Argonne National Lab. (ANL), Argonne, IL (United States)

2017-02-01

A process is being developed for commercial production of the medical isotope Mo-99 through a photo-nuclear reaction on a Mo-100 target using a highpower electron accelerator. This process requires temperature monitoring of the window through which a high-current electron beam is transmitted to the target. For this purpose, we evaluated two near infrared technologies: the OMEGA Engineering iR2 pyrometer and the Ocean Optics Maya2000 spectrometer with infrared-enhanced charge-coupled device (CCD) sensor. Measuring in the near infrared spectrum, in contrast to the long-wavelength infrared spectrum, offers a few immediate advantages: (1) ordinary glass or quartz optical elements can be used; (2) alignment can be performed without heating the target; and (3) emissivity corrections to temperature are typically less than 10%. If spatial resolution is not required, the infrared pyrometer is attractive because of its accuracy, low cost, and simplicity. If spatial resolution is required, we make recommendations for near-infrared imaging based on our data augmented by calculations

Indirect absorption spectroscopy using quantum cascade lasers: mid-infrared refractometry and photothermal spectroscopy.

Science.gov (United States)

Pfeifer, Marcel; Ruf, Alexander; Fischer, Peer

2013-11-04

We record vibrational spectra with two indirect schemes that depend on the real part of the index of refraction: mid-infrared refractometry and photothermal spectroscopy. In the former, a quantum cascade laser (QCL) spot is imaged to determine the angles of total internal reflection, which yields the absorption line via a beam profile analysis. In the photothermal measurements, a tunable QCL excites vibrational resonances of a molecular monolayer, which heats the surrounding medium and changes its refractive index. This is observed with a probe laser in the visible. Sub-monolayer sensitivities are demonstrated.

Development of an ultra-compact mid-infrared attenuated total reflectance spectrophotometer

Science.gov (United States)

Kim, Dong Soo; Lee, Tae-Ro; Yoon, Gilwon

2014-07-01

Mid-infrared spectroscopy has been an important tool widely used for qualitative analysis in various fields. However, portable or personal use is size and cost prohibitive for either Fourier transform infrared or attenuated total reflectance (ATR) spectrophotometers. In this study, we developed an ultra-compact ATR spectrophotometer whose frequency band was 5.5-11.0 μm. We used miniature components, such as a light source fabricated by semiconductor technology, a linear variable filter, and a pyro-electric array detector. There were no moving parts. Optimal design based on two light sources, a zippered configuration of the array detector and ATR optics could produce absorption spectra that might be used for qualitative analysis. A microprocessor synchronized the pulsed light sources and detector, and all the signals were processed digitally. The size was 13.5×8.5×3.5 cm3 and the weight was 300 grams. Due to its low cost, our spectrophotometer can replace many online monitoring devices. Another application could be for a u-healthcare system installed in the bathroom or attached to a smartphone for monitoring substances in body fluids.

Infrared Sky Surveys

Science.gov (United States)

Price, Stephan D.

2009-02-01

A retrospective is given on infrared sky surveys from Thomas Edison’s proposal in the late 1870s to IRAS, the first sensitive mid- to far-infrared all-sky survey, and the mid-1990s experiments that filled in the IRAS deficiencies. The emerging technology for space-based surveys is highlighted, as is the prominent role the US Defense Department, particularly the Air Force, played in developing and applying detector and cryogenic sensor advances to early mid-infrared probe-rocket and satellite-based surveys. This technology was transitioned to the infrared astronomical community in relatively short order and was essential to the success of IRAS, COBE and ISO. Mention is made of several of the little known early observational programs that were superseded by more successful efforts.

Cadmium zinc telluride as a mid-infrared variable retarder

Science.gov (United States)

FitzGerald, William; Taherion, Saeid; Kumar, F. Joseph; Giles, David; Hore, Dennis

2018-04-01

The electro-optic behavior of cadmium zinc telluride is examined in the mid-infrared region between 3 and 11 μm, for applied DC field strengths of up to 106 V/m. The measurements performed here include full characterization of the polarization state of the transmitted light by means of the Stokes vector. We demonstrate the suitability of this material for DC variable retarder applications such as those achieved by quarter- or half-wave retardation. A comparison of two different metallic coatings for electrodes, gold and indium, reveals important differences in performance that are attributed to the homogeneity of the field through the bulk of the crystal. We illustrate that, in the case of both metals, the same electro-optic coefficients are measured, but regions of higher and lower retardation result in significant depolarization in the case of gold. Such depolarization may adversely affect the contrast ratio in a light valve, or increase the voltage necessary for the operation of an arbitrary polarization state generator.

Mid-infrared and near-infrared spectroscopy for rapid detection of Gardeniae Fructus by a liquid-liquid extraction process.

Science.gov (United States)

Tao, Lingyan; Lin, Zhonglin; Chen, Jiashan; Wu, Yongjiang; Liu, Xuesong

2017-10-25

Gardeniae Fructus is widely used in the pharmaceutical industry, and many studies have confirmed its medical and economic value. In this study, samples collected from different liquid-liquid extraction batches of Gardeniae Fructus were detected by mid-infrared (MIR) and near-infrared (NIR) spectroscopy. Seven analytes, neochlorogenic acid (5-CQA), cryptochlorogenic acid (4-CQA), chlorogenic acid (3-CQA), geniposidic acid (GEA), deacetyl-asperulosidic acid methyl ester (DAAME), genipin-gentiobioside (GGB), and gardenoside (GA), were chosen as quality property indexes of Gardeniae Fructus. The two kinds of spectra were each used to build models by single partial least squares (PLS). Additionally, both spectral data were combined and modeled by multiblock PLS. For single spectroscopy modeling results, NIR had a better prediction for high-concentration analytes (3-CQA, DAAME, GGB, and GA) whereas MIR performed better for low-concentration analytes (5-CQA, 4-CQA, and GEA). The multiblock methodology was found to be better compared to single spectroscopy models for all seven analytes. Specifically, the coefficients of determination (R 2 ) of the NIR, MIR, and multiblock PLS calibration models of all seven components were higher than 0.95. Relative standard errors of prediction (RSEP) were all less than 7%, except for models of GGB, which were 10.36%, 13.24%, and 8.15% for the NIR-PLS, MIR-PLS, and multiblock models, respectively. These results indicate that MIR and NIR spectrographic techniques could provide a new choice for quality control in industrial production of Gardeniae Fructus. Copyright © 2017 Elsevier B.V. All rights reserved.

Primary experimental studies on mid-infrared FEL irradiation on dental substances at BFEL

CERN Document Server

Biao, Z J; Gao Xue Ju; He Wei; Huang Yu Ying; Li Yong Gui; LiuNianQing; Wang Min Kai; Wu Gan; Yan Xue Pin; Zhang Guo Qing

2001-01-01

A free electron laser (FEL) with its characteristics of wide wavelength tunability, ultrashort pulse time structure, and high peak power density is predominantly superior to all other conventional lasers in applications. Several experimental studies on mid-infrared FEL irradiation on dental enamel and dentine were performed at the Beijing FEL. Experimental aims were to investigate changes in the hardness, ratios of P to Ca and Cs before and after irradiation on samples with a characteristic absorption wavelength of 9.66 mu m, in the colors of these sample surfaces after irradiation with different wavelengths around the peak wavelength. The time dependence of temperature of the dentine sample was measured with its ps pulse effects compared to that with a continuous CO sub 2 laser. FTIR absorption spectra in the range of 2.5-15.4 mu m for samples of these hard dental substances and pure hydroxyapatite were first examined to decide their chemical components and absorption maximums. Primary experimental results w...

LOCAL LUMINOUS INFRARED GALAXIES. II. ACTIVE GALACTIC NUCLEUS ACTIVITY FROM SPITZER/INFRARED SPECTROGRAPH SPECTRA

Energy Technology Data Exchange (ETDEWEB)

Alonso-Herrero, Almudena; Pereira-Santaella, Miguel [Centro de Astrobiologia, INTA-CSIC, E-28850 Torrejon de Ardoz, Madrid (Spain); Rieke, George H. [Steward Observatory, University of Arizona, Tucson, AZ 85721 (United States); Rigopoulou, Dimitra [Astrophysics Department, University of Oxford, Oxford OX1 3RH (United Kingdom)

2012-01-01

We quantify the active galactic nucleus (AGN) contribution to the mid-infrared (mid-IR) and the total infrared (IR, 8-1000 {mu}m) emission in a complete volume-limited sample of 53 local luminous infrared galaxies (LIRGs, L{sub IR} = 10{sup 11}-10{sup 12} L{sub Sun }). We decompose the Spitzer Infrared Spectrograph low-resolution 5-38 {mu}m spectra of the LIRGs into AGN and starburst components using clumpy torus models and star-forming galaxy templates, respectively. We find that 50% (25/50) of local LIRGs have an AGN component detected with this method. There is good agreement between these AGN detections through mid-IR spectral decomposition and other AGN indicators, such as the optical spectral class, mid-IR spectral features, and X-ray properties. Taking all the AGN indicators together, the AGN detection rate in the individual nuclei of LIRGs is {approx}62%. The derived AGN bolometric luminosities are in the range L{sub bol}(AGN) = (0.4-50) Multiplication-Sign 10{sup 43} erg s{sup -1}. The AGN bolometric contribution to the IR luminosities of the galaxies is generally small, with 70% of LIRGs having L{sub bol}[AGN]/L{sub IR} {<=} 0.05. Only {approx_equal} 8% of local LIRGs have a significant AGN bolometric contribution L{sub bol}[AGN]/L{sub IR} > 0.25. From the comparison of our results with literature results of ultraluminous infrared galaxies (L{sub IR} = 10{sup 12}-10{sup 13} L{sub Sun }), we confirm that in the local universe the AGN bolometric contribution to the IR luminosity increases with the IR luminosity of the galaxy/system. If we add up the AGN bolometric luminosities we find that AGNs only account for 5%{sub -3%}{sup +8%} of the total IR luminosity produced by local LIRGs (with and without AGN detections). This proves that the bulk of the IR luminosity of local LIRGs is due to star formation activity. Taking the newly determined IR luminosity density of LIRGs in the local universe, we then estimate an AGN IR luminosity density of {Omega}{sup AGN

A high-transmission liquid-crystal Fabry-Perot infrared filter for electrically tunable spectral imaging detection

Science.gov (United States)

Liu, Zhonglun; Xin, Zhaowei; Long, Huabao; Wei, Dong; Dai, Wanwan; Zhang, Xinyu; Wang, Haiwei; Xie, Changsheng

2018-02-01

Previous studies have presented the usefulness of typical liquid-crystal Fabry-Perot (LC-FP) infrared filters for spectral imaging detection. Yet, their infrared transmission performances still remain to improve or even rise. In this paper, we propose a new type of electrically tunable LC-FP infrared filter to solve the problem above. The key component of the device is a FP resonant cavity composed of two parallel plane mirrors, in which the zinc selenide (ZnSe) materials with a very high transmittance in the mid-long-wavelength infrared regions are used as the electrode substrates and a layer of nano-aluminum (Al) film, which is directly contacted with liquid-crystal materials, is chosen to make high reflective mirrors as well as the electrodes. Particularly, it should be noted that the directional layer made up of ployimide (PI) used previously is removed. The experiment results indicate that the filter can reduce the absorption of infrared wave remarkably, and thus highlight a road to effectively improve the infrared transmittance ability.

Carnegie Hubble Program: A Mid-Infrared Calibration of the Hubble Constant

Science.gov (United States)

Freedman, Wendy L.; Madore, Barry F.; Scowcroft, Victoria; Burns, Chris; Monson, Andy; Persson, S. Eric; Seibert, Mark; Rigby, Jane

2012-01-01

Using a mid-infrared calibration of the Cepheid distance scale based on recent observations at 3.6 micrometers with the Spitzer Space Telescope, we have obtained a new, high-accuracy calibration of the Hubble constant. We have established the mid-IR zero point of the Leavitt law (the Cepheid period-luminosity relation) using time-averaged 3.6 micrometers data for 10 high-metallicity, MilkyWay Cepheids having independently measured trigonometric parallaxes. We have adopted the slope of the PL relation using time-averaged 3.6micrometers data for 80 long-period Large Magellanic Cloud (LMC) Cepheids falling in the period range 0.8 < log(P) < 1.8.We find a new reddening-corrected distance to the LMC of 18.477 +/- 0.033 (systematic) mag. We re-examine the systematic uncertainties in H(sub 0), also taking into account new data over the past decade. In combination with the new Spitzer calibration, the systematic uncertainty in H(sub 0) over that obtained by the Hubble Space Telescope Key Project has decreased by over a factor of three. Applying the Spitzer calibration to the Key Project sample, we find a value of H(sub 0) = 74.3 with a systematic uncertainty of +/-2.1 (systematic) kilometers per second Mpc(sup -1), corresponding to a 2.8% systematic uncertainty in the Hubble constant. This result, in combination with WMAP7measurements of the cosmic microwave background anisotropies and assuming a flat universe, yields a value of the equation of state for dark energy, w(sub 0) = -1.09 +/- 0.10. Alternatively, relaxing the constraints on flatness and the numbers of relativistic species, and combining our results with those of WMAP7, Type Ia supernovae and baryon acoustic oscillations yield w(sub 0) = -1.08 +/- 0.10 and a value of N(sub eff) = 4.13 +/- 0.67, mildly consistent with the existence of a fourth neutrino species.

WISE TF: A MID-INFRARED, 3.4 {mu}m EXTENSION OF THE TULLY-FISHER RELATION USING WISE PHOTOMETRY

Energy Technology Data Exchange (ETDEWEB)

Lagattuta, David J.; Mould, Jeremy R. [Centre for Astrophysics and Supercomputing, Swinburne University of Technology, P.O. Box 218, Hawthorn, VIC 3122 (Australia); Staveley-Smith, Lister; Hong Tao; Springob, Christopher M. [ARC Centre of Excellence for All-sky Astrophysics (CAASTRO), Redfern, NSW (Australia); Masters, Karen L. [Institute for Cosmology and Gravitation, University of Portsmouth, Dennis Sciama Building, Burnaby Road, Portsmouth, PO1 3FX (United Kingdom); Koribalski, Baerbel S. [CSIRO Astronomy and Space Science, Australia Telescope National Facility (ATNF) P.O. Box 76, Epping, NSW 1710 (Australia); Jones, D. Heath, E-mail: dlagattu@astro.swin.edu.au [School of Physics, Monash University, Clayton, VIC 3800 (Australia)

2013-07-10

We present a mid-infrared Tully-Fisher (TF) relation using photometry from the 3.4 {mu}m W1 band of the Wide-field Infrared Survey Explorer (WISE) satellite. The WISE TF relation is formed from 568 galaxies taken from the all-sky 2MASS Tully-Fisher (2MTF) galaxy catalog, spanning a range of environments including field, group, and cluster galaxies. This constitutes the largest mid-infrared TF relation constructed to date. After applying a number of corrections to galaxy magnitudes and line widths, we measure a master TF relation given by M{sub corr} = -22.24 - 10.05[log (W{sub corr}) - 2.5], with an average dispersion of {sigma}{sub WISE} = 0.686 mag. There is some tension between WISE TF and a preliminary 3.6 {mu}m relation, which has a shallower slope and almost no intrinsic dispersion. However, our results agree well with a more recent relation constructed from a large sample of cluster galaxies. We additionally compare WISE TF to the near-infrared 2MTF template relations, finding a good agreement between the TF parameters and total dispersions of WISE TF and the 2MTF K-band template. This fact, coupled with typical galaxy colors of (K - W1) {approx} 0, suggests that these two bands are tracing similar stellar populations, including the older, centrally-located stars in the galactic bulge which can (for galaxies with a prominent bulge) dominate the light profile.

WISE TF: A MID-INFRARED, 3.4 μm EXTENSION OF THE TULLY-FISHER RELATION USING WISE PHOTOMETRY

International Nuclear Information System (INIS)

Lagattuta, David J.; Mould, Jeremy R.; Staveley-Smith, Lister; Hong Tao; Springob, Christopher M.; Masters, Karen L.; Koribalski, Bärbel S.; Jones, D. Heath

2013-01-01

We present a mid-infrared Tully-Fisher (TF) relation using photometry from the 3.4 μm W1 band of the Wide-field Infrared Survey Explorer (WISE) satellite. The WISE TF relation is formed from 568 galaxies taken from the all-sky 2MASS Tully-Fisher (2MTF) galaxy catalog, spanning a range of environments including field, group, and cluster galaxies. This constitutes the largest mid-infrared TF relation constructed to date. After applying a number of corrections to galaxy magnitudes and line widths, we measure a master TF relation given by M corr = –22.24 – 10.05[log (W corr ) – 2.5], with an average dispersion of σ WISE = 0.686 mag. There is some tension between WISE TF and a preliminary 3.6 μm relation, which has a shallower slope and almost no intrinsic dispersion. However, our results agree well with a more recent relation constructed from a large sample of cluster galaxies. We additionally compare WISE TF to the near-infrared 2MTF template relations, finding a good agreement between the TF parameters and total dispersions of WISE TF and the 2MTF K-band template. This fact, coupled with typical galaxy colors of (K – W1) ∼ 0, suggests that these two bands are tracing similar stellar populations, including the older, centrally-located stars in the galactic bulge which can (for galaxies with a prominent bulge) dominate the light profile.

Low resolution infrared spectra of quasars

International Nuclear Information System (INIS)

Soifer, B.T.; Neugebauer, G.; Oke, J.B.; Matthews, K.

1980-01-01

Low resolution spectra of a significant sample of quasars show that the Paschen α and Balmer line ratios do not agree with the radiative recombination case B result and vary widely within the quasars sampled. The range in Pα:Hβ ratios is a factor of approximately 6, while the range in Lyα:Hα ratios is a factor of approximately 5. For the Pα:Balmer series, the deviations from case B recombination are not consistent with reddening, but appear, within large dispersions, to be consistent with optical depth effects in the Balmer lines affecting the line ratios. The Lyα:Hα ratio is, however, correlated with the continuum spectral index, and can be explained as due to reddening affecting both the lines and continuum. Recent observational results based on a joint infrared/optical survey of the hydrogen line spectra of a significant number of the brightest low and high redshift quasars are summarised. This survey includes 12 quasars in the redshift range 0.07 1.5, where Hα and/or Hβ is redshifted into the 1.65μm or 2.2μm atmospheric windows. (Auth.)

THE ORION H ii REGION AND THE ORION BAR IN THE MID-INFRARED

International Nuclear Information System (INIS)

Salgado, F.; Tielens, A. G. G. M.; Berné, O.; Adams, J. D.; Herter, T. L.; Keller, L. D.

2016-01-01

We present mid-infrared photometry of the Orion bar obtained with the Faint Object infraRed Camera for the SOFIA Telescope (FORCAST) on board SOFIA at 6.4, 6.6, 7.7, 19.7, 31.5, and 37.1 μ m. By complementing this observation with archival FORCAST and Herschel /PACS images, we are able to construct a complete infrared spectral energy distribution of the Huygens region in the Orion nebula. Comparing the infrared images with gas tracers, we find that PACS maps trace the molecular cloud, while the FORCAST data trace the photodissociation region (PDR) and the H ii region. Analysis of the energetics of the region reveal that the PDR extends for 0.28 pc along the line of sight and that the bar is inclined at an angle of 4°. The infrared and submillimeter images reveal that the Orion bar represents a swept-up shell with a thickness of 0.1 pc. The mass of the shell implies a shock velocity of ≃3 km s −1 and an age of ≃10 5 years for the H ii region. Our analysis shows that the UV and infrared dust opacities in the H ii region and the PDR are a factor 5 to 10 lower than in the diffuse interstellar medium. In the ionized gas, Ly α photons are a major source of dust heating at distances larger than ≃0.06 pc from θ 1 Ori C. Dust temperatures can be explained if the size of the grains is between 0.1 and 1 μ m. We derive the photoelectric heating efficiency of the atomic gas in the Orion bar. The results are in good qualitative agreement with models and the quantitative differences indicate a decreased polycyclic aromatic hydrocarbon abundance in this region.

THE ORION H ii REGION AND THE ORION BAR IN THE MID-INFRARED

Energy Technology Data Exchange (ETDEWEB)

Salgado, F.; Tielens, A. G. G. M. [Leiden Observatory, University of Leiden, P.O. Box 9513, 2300 RA Leiden (Netherlands); Berné, O. [Université de Toulouse, UPS-OMP, IRAP, Toulouse (France); Adams, J. D.; Herter, T. L. [Astronomy Department, 202 Space Sciences Building, Cornell University, Ithaca, NY 14853-6801 (United States); Keller, L. D. [Department of Physics and Astronomy, Ithaca College, Ithaca, NY 14850 (United States)

2016-10-20

We present mid-infrared photometry of the Orion bar obtained with the Faint Object infraRed Camera for the SOFIA Telescope (FORCAST) on board SOFIA at 6.4, 6.6, 7.7, 19.7, 31.5, and 37.1 μ m. By complementing this observation with archival FORCAST and Herschel /PACS images, we are able to construct a complete infrared spectral energy distribution of the Huygens region in the Orion nebula. Comparing the infrared images with gas tracers, we find that PACS maps trace the molecular cloud, while the FORCAST data trace the photodissociation region (PDR) and the H ii region. Analysis of the energetics of the region reveal that the PDR extends for 0.28 pc along the line of sight and that the bar is inclined at an angle of 4°. The infrared and submillimeter images reveal that the Orion bar represents a swept-up shell with a thickness of 0.1 pc. The mass of the shell implies a shock velocity of ≃3 km s{sup −1} and an age of ≃10{sup 5} years for the H ii region. Our analysis shows that the UV and infrared dust opacities in the H ii region and the PDR are a factor 5 to 10 lower than in the diffuse interstellar medium. In the ionized gas, Ly α photons are a major source of dust heating at distances larger than ≃0.06 pc from θ {sup 1} Ori C. Dust temperatures can be explained if the size of the grains is between 0.1 and 1 μ m. We derive the photoelectric heating efficiency of the atomic gas in the Orion bar. The results are in good qualitative agreement with models and the quantitative differences indicate a decreased polycyclic aromatic hydrocarbon abundance in this region.

Kinetic energy spectra, vertical resolution and dissipation in high-resolution atmospheric simulations.

Science.gov (United States)

Skamarock, W. C.

2017-12-01

We have performed week-long full-physics simulations with the MPAS global model at 15 km cell spacing using vertical mesh spacings of 800, 400, 200 and 100 meters in the mid-troposphere through the mid-stratosphere. We find that the horizontal kinetic energy spectra in the upper troposphere and stratosphere does not converge with increasing vertical resolution until we reach 200 meter level spacing. Examination of the solutions indicates that significant inertia-gravity waves are not vertically resolved at the lower vertical resolutions. Diagnostics from the simulations indicate that the primary kinetic energy dissipation results from the vertical mixing within the PBL parameterization and from the gravity-wave drag parameterization, with smaller but significant contributions from damping in the vertical transport scheme and from the horizontal filters in the dynamical core. Most of the kinetic energy dissipation in the free atmosphere occurs within breaking mid-latitude baroclinic waves. We will briefly review these results and their implications for atmospheric model configuration and for atmospheric dynamics, specifically that related to the dynamics associated with the mesoscale kinetic energy spectrum.

Constructing a WISE High Resolution Galaxy Atlas

Science.gov (United States)

Jarrett, T. H.; Masci, F.; Tsai, C. W.; Petty, S.; Cluver, M.; Assef, Roberto J.; Benford, D.; Blain, A.; Bridge, C.; Donoso, E.;

High-resolution transmission measurements of CO2 at high temperatures for industrial applications

DEFF Research Database (Denmark)

Evseev, Vadim; Fateev, Alexander; Clausen, Sønnik

2012-01-01

. The spectra have been recorded in a high-temperature flow gas cell and using a Fourier transform infrared (FTIR) spectrometer at a nominal resolution of 0.125 cm-1. The volume fractions of CO2 in the measurements were 1,10 and 100%. The measurements have been validated by comparison with medium...

PCA determination of the radiometric noise of high spectral resolution infrared observations from spectral residuals: Application to IASI

Science.gov (United States)

Serio, C.; Masiello, G.; Camy-Peyret, C.; Jacquette, E.; Vandermarcq, O.; Bermudo, F.; Coppens, D.; Tobin, D.

2018-02-01

The problem of characterizing and estimating the instrumental or radiometric noise of satellite high spectral resolution infrared spectrometers directly from Earth observations is addressed in this paper. An approach has been developed, which relies on the Principal Component Analysis (PCA) with a suitable criterion to select the optimal number of PC scores. Different selection criteria have been set up and analysed, which is based on the estimation theory of Least Squares and/or Maximum Likelihood Principle. The approach is independent of any forward model and/or radiative transfer calculations. The PCA is used to define an orthogonal basis, which, in turn, is used to derive an optimal linear reconstruction of the observations. The residual vector that is the observation vector minus the calculated or reconstructed one is then used to estimate the instrumental noise. It will be shown that the use of the spectral residuals to assess the radiometric instrumental noise leads to efficient estimators, which are largely independent of possible departures of the true noise from that assumed a priori to model the observational covariance matrix. Application to the Infrared Atmospheric Sounder Interferometer (IASI) has been considered. A series of case studies has been set up, which make use of IASI observations. As a major result, the analysis confirms the high stability and radiometric performance of IASI. The approach also proved to be efficient in characterizing noise features due to mechanical micro-vibrations of the beam splitter of the IASI instrument.

Mid - infrared transmission of polycrystalline (LaSr) (MnNi)O3

International Nuclear Information System (INIS)

Laksanawati, W. D.; Kurniawan, B.; Saptari, S. A.

2016-01-01

Polycrystalline (LaSr)(MnNi)O 3 was shintesized using sol gel methods with nitrat precursors La(NO 3 ) 3 , Sr(NO 3 ) 2 , Mn(NO 3 ) 2 .4H 2 O, and Ni(NO3)2.6H2O and the different heating process. Sample (LaSr)(MnNi)O 3 with chemical formulation La 0,67 Sr 0,33 Mn 1-x Ni x O 3 with × = 0,05 and 0,10. We report the crystallite structure of La 0,67 Sr 0,33 Mn 1-x Ni x O 3 with x= 0,00 and 0,10 are single phase with characterization by X-ray diffraction. Refinement has result that crystallite size of La 0,67 Sr 0,33 Mn 0,95 Ni 0,05 O 3 is 24,67 and La 0,67 Sr 0,33 Mn 0,9 Ni 0,1 O 3 is 21,84 with crystallite system rombohedral, it show us that increasing at Ni composition influence of decreased crystallite size. Sampel (LaSr)(MnNi)O3 has been characterization with Fourier Transform Infrared with range of wave number from 450 to 4000 cm -1 were chategories at mid infrared wave. The FTIR pattern show to us that the Mn-O-Mn bounded has absorp infrared at wave number 605 cm -1 and the dominant peak at wave number 3750 cm -1 caused the hidroxy compound in sampel La 0,67 Sr 0,33 Mn 0,95 Ni 0,05 O 3 . (paper)

Static and time-resolved mid-infrared spectroscopy of Hg0.95Cd0.05Cr2Se4 spinel.

Science.gov (United States)

Barsaume, S; Telegin, A V; Sukhorukov, Yu P; Stavrias, N; Fedorov, V A; Menshchikova, T K; Kimel, A V

2017-08-16

Static and time-resolved mid-infrared spectroscopy of ferromagnetic single crystal Hg 0.95 Cd 0.05 Cr 2 Se 4 was performed below the absorption edge, in order to reveal the origin of the electronic transitions contributing to the magneto-optical properties of this material. The mid-infrared spectroscopy reveals a strong absorption peak around 0.236 eV which formerly was assigned to a transition within the selenide-chromium complexes ([Formula: see text] Se -Cr 2+ ). To reveal the sensitivity of the transition to the magnetic order, we performed the studies in a temperature range across the Curie temperature and magnetic fields across the value at which the saturation of ferromagnetic magnetization occurs. Despite the fact that the Curie temperature of this ferromagnetic semiconductor is around 107 K, the intensity of the mid-infrared transition reduces substantially increasing the temperature, so that already at 70 K the absorption peak is hardly visible. Such a dramatic decrease of the oscillator strength is observed simultaneously with the strong red-shift of the absorption edge in the magnetic semiconductor. Employing a time-resolved pump-and-probe technique enabled us to determine the lifetime of the electrons in the excited state of this optical transition. In the temperature range from 7 K to 80 K, the lifetime changes from 3 ps to 6 ps. This behavior agrees with the phenomenon of giant oscillator strength described earlier for weakly bound excitons in nonmagnetic semiconductors.

High resolution, high speed ultrahigh vacuum microscopy

International Nuclear Information System (INIS)

Poppa, Helmut

2004-01-01

spectroscopy, ultraviolet photoelectron spectroscopy, Auger electron spectroscopy, low-energy electron diffraction, temperature programmed desorption, high-resolution electron energy-loss and Fourier-transform infrared spectroscopies, and others. Material systems ranging from atomic layers of metals and semiconductors to biology related depositions are being investigated. In the case of biological materials, however, strict limitations to high-resolution applications are imposed by electron radiation damage considerations

Polarization effects in above-threshold ionization with a mid-infrared strong laser field

Science.gov (United States)

Kang, Hui-Peng; Xu, Song-Po; Wang, Yan-Lan; Yu, Shao-Gang; Zhao, Xiao-Yun; Hao, Xiao-Lei; Lai, Xuan-Yang; Pfeifer, Thomas; Liu, Xiao-Jun; Chen, Jing; Cheng, Ya; Xu, Zhi-Zhan

2018-05-01

Using a semiclassical approach, we theoretically study the above-threshold ionization of magnesium by intense, mid-infrared laser pulses. The formation of low-energy structures in the photoelectron spectrum is found to be enhanced by comparing with a calculation based on the single-active electron approximation. By performing electron trajectory and recollision-time distribution analysis, we demonstrate that this phenomenon is due to the laser-induced ionic core polarization effects on the recolliding electrons. We also show that the polarization effects should be experimentally detectable. Our finding provides new insight into ultrafast control of strong-field photoionization and imaging of polar molecules.

Complementary periodic diffracting metallic nanohole and nanodipole arrays in the mid-infrared range

Science.gov (United States)

Ye, Yong-Hong; Zhang, Jia-Yu; Feng Ma, Hui; Yao, Jie; Wang, Xudong

2012-10-01

Metallic nanohole arrays and metallic nanodipole arrays are fabricated and experimentally characterized. A complementary response is observed in both transmission and reflection. For the metallic nanohole arrays, a peak (dip) in transmission (reflection) is observed at resonance whereas the metallic nanodipole arrays display a dip (peak) in transmission (reflection). The resonant frequency of both the metallic nanohole arrays and the nanodipole arrays depends on the dipole arm length, the incident angle, and the period. The resonant position of the nanohole arrays matches that of its complement, which means that Babinet's principle nearly holds for these structures in the mid-infrared region.

Strong electron-phonon interaction in the high-Tc superconductors: Evidence from the infrared

International Nuclear Information System (INIS)

Timusk, T.; Porter, C.D.; Tanner, D.B.

1991-01-01

We show that low-frequency structure in the infrared reflectance of the high-temperature superconductor YBa 2 Cu 3 O 7 results from the electron-phonon interaction. Characteristic antiresonant line shapes are seen in the phonon region of the spectrum and the frequency-dependent scattering rate of the mid-infrared electronic continuum has peaks at 150 cm -1 (19 meV) and at 360 cm -1 (45 meV) in good agreement with phonon density-of-states peaks in neutron time-of-flight spectra that develop in superconducting samples. The interaction between the phonons and the charge carriers can be understood in terms of a charged-phonon model

CHARACTERIZING THE MID-INFRARED EXTRAGALACTIC SKY WITH WISE AND SDSS

International Nuclear Information System (INIS)

Yan Lin; Donoso, E.; Tsai, Chao-Wei; Cutri, R.; Jarrett, T.; Stern, D.; Assef, R. J.; Eisenhardt, P.; Blain, A. W.; Stanford, S. A.; Wright, E.; Bridge, C.; Riechers, D. A.

2013-01-01

The Wide-field Infrared Survey Explorer (WISE) has completed its all-sky survey in four channels at 3.4-22 μm, detecting hundreds of millions of objects. We merge the WISE mid-infrared data with optical data from the Sloan Digital Sky Survey (SDSS) and provide a phenomenological characterization of WISE extragalactic sources. WISE is most sensitive at 3.4 μm (W1) and least sensitive at 22 μm (W4). The W1 band probes massive early-type galaxies out to z ∼> 1. This is more distant than SDSS identified early-type galaxies, consistent with the fact that 28% of 3.4 μm sources have faint or no r-band counterparts (r > 22.2). In contrast, 92%-95% of 12 μm and 22 μm sources have SDSS optical counterparts with r ≤ 22.2. WISE 3.4 μm detects 89.8% of the entire SDSS QSO catalog at S/N W1 >7σ, but only 18.9% at 22 μm with S/N W4 > 5σ. We show that WISE colors alone are effective in isolating stars (or local early-type galaxies), star-forming galaxies, and strong active galactic nuclei (AGNs)/QSOs at z ∼ 0.8 and W2 –2 . (2) Selection of dust-obscured, type-2 AGN/QSO candidates. We show that WISE W1 – W2 > 0.8, W2 6 (Vega) colors can be used to identify type-2 AGN candidates. The fraction of these type-2 AGN candidates is one-third of all WISE color-selected AGNs. (3) Selection of ultraluminous infrared galaxies (ULIRGs) at z ∼ 2 with extremely red colors, r – W4 > 14 or well-detected 22 μm sources lacking detections in the 3.4 and 4.6 μm bands. The surface density of z ∼ 2 ULIRG candidates selected with r – W4 > 14 is 0.9 ± 0.07 deg –2 at S/N W4 ≥ 5 (the corresponding, lowest flux density of 2.5 mJy), which is consistent with that inferred from smaller area Spitzer surveys. Optical spectroscopy of a small number of these high-redshift ULIRG candidates confirms our selection, and reveals a possible trend that optically fainter or r – W4 redder candidates are at higher redshifts.

Suspended mid-infrared fiber-to-chip grating couplers for SiGe waveguides

Science.gov (United States)

Favreau, Julien; Durantin, Cédric; Fédéli, Jean-Marc; Boutami, Salim; Duan, Guang-Hua

2016-03-01

Silicon photonics has taken great importance owing to the applications in optical communications, ranging from short reach to long haul. Originally dedicated to telecom wavelengths, silicon photonics is heading toward circuits handling with a broader spectrum, especially in the short and mid-infrared (MIR) range. This trend is due to potential applications in chemical sensing, spectroscopy and defense in the 2-10 μm range. We previously reported the development of a MIR photonic platform based on buried SiGe/Si waveguide with propagation losses between 1 and 2 dB/cm. However the low index contrast of the platform makes the design of efficient grating couplers very challenging. In order to achieve a high fiber-to-chip efficiency, we propose a novel grating coupler structure, in which the grating is locally suspended in air. The grating has been designed with a FDTD software. To achieve high efficiency, suspended structure thicknesses have been jointly optimized with the grating parameters, namely the fill factor, the period and the grating etch depth. Using the Efficient Global Optimization (EGO) method we obtained a configuration where the fiber-to-waveguide efficiency is above 57 %. Moreover the optical transition between the suspended and the buried SiGe waveguide has been carefully designed by using an Eigenmode Expansion software. Transition efficiency as high as 86 % is achieved.

Temperature-sensitive junction transformations for mid-wavelength HgCdTe photovoltaic infrared detector arrays by laser beam induced current microscope

Energy Technology Data Exchange (ETDEWEB)

Qiu, Weicheng [College of Photoelectric Science and Engineering, National University of Defense Technology, Changsha, Hunan 410073 (China); National Laboratory for Infrared Physics, Shanghai Institute of Technical Physics, Chinese Academy of Sciences, Shanghai 200083 (China); Hu, Weida, E-mail: wdhu@mail.sitp.ac.cn; Lin, Tie; Yin, Fei; Zhang, Bo; Chen, Xiaoshuang; Lu, Wei [National Laboratory for Infrared Physics, Shanghai Institute of Technical Physics, Chinese Academy of Sciences, Shanghai 200083 (China); Cheng, Xiang' ai, E-mail: xiang-ai-cheng@126.com; Wang, Rui [College of Photoelectric Science and Engineering, National University of Defense Technology, Changsha, Hunan 410073 (China)

2014-11-10

In this paper, we report on the disappearance of the photosensitive area extension effect and the unusual temperature dependence of junction transformation for mid-wavelength, n-on-p HgCdTe photovoltaic infrared detector arrays. The n-type region is formed by B{sup +} ion implantation on Hg-vacancy-doped p-type HgCdTe. Junction transformations under different temperatures are visually captured by a laser beam induced current microscope. A physical model of temperature dependence on junction transformation is proposed and demonstrated by using numerical simulations. It is shown that Hg-interstitial diffusion and temperature activated defects jointly lead to the p-n junction transformation dependence on temperature, and the weaker mixed conduction compared with long-wavelength HgCdTe photodiode contributes to the disappearance of the photosensitive area extension effect in mid-wavelength HgCdTe infrared detector arrays.

AN IN-DEPTH VIEW OF THE MID-INFRARED PROPERTIES OF POINT SOURCES AND THE DIFFUSE ISM IN THE SMC GIANT H II REGION, N66

International Nuclear Information System (INIS)

Whelan, David G.; Johnson, Kelsey E.; Indebetouw, Rémy; Lebouteiller, Vianney; Galliano, Frédéric; Peeters, Els; Bernard-Salas, Jeronimo; Brandl, Bernhard R.

2013-01-01

The focus of this work is to study mid-infrared point sources and the diffuse interstellar medium (ISM) in the low-metallicity (∼0.2 Z ☉ ) giant H II region N66 in order to determine properties that may shed light on star formation in these conditions. Using the Spitzer Space Telescope's Infrared Spectrograph, we study polycyclic aromatic hydrocarbon (PAH), dust continuum, silicate, and ionic line emission from 14 targeted infrared point sources as well as spectra of the diffuse ISM that is representative of both the photodissociation regions (PDRs) and the H II regions. Among the point source spectra, we spectroscopically confirm that the brightest mid-infrared point source is a massive embedded young stellar object, we detect silicates in emission associated with two young stellar clusters, and we see spectral features of a known B[e] star that are commonly associated with Herbig Be stars. In the diffuse ISM, we provide additional evidence that the very small grain population is being photodestroyed in the hard radiation field. The 11.3 μm PAH complex emission exhibits an unexplained centroid shift in both the point source and ISM spectra that should be investigated at higher signal-to-noise and resolution. Unlike studies of other regions, the 6.2 μm and 7.7 μm band fluxes are decoupled; the data points cover a large range of I 7.7 /I 11.3 PAH ratio values within a narrow band of I 6.2 /I 11.3 ratio values. Furthermore, there is a spread in PAH ionization, being more neutral in the dense PDR where the radiation field is relatively soft, but ionized in the diffuse ISM/PDR. By contrast, the PAH size distribution appears to be independent of local ionization state. Important to unresolved studies of extragalactic low-metallicity star-forming regions, we find that emission from the infrared-bright point sources accounts for only 20%-35% of the PAH emission from the entire region. These results make a comparative data set to other star-forming regions with

High resolution carbon isotope stratigraphy and glendonite occurrences of the Christopher Formation, Sverdrup Basin (Axel Heiberg Island, Canada): implications for mid Cretaceous high latitude climate change

Science.gov (United States)

Herrle, Jens O.; Schröder-Adams, Claudia J.; Galloway, Jennifer M.; Pugh, Adam T.

2013-04-01

Understanding the evolution of Canada's Arctic region, as a crucial component of Earth's climate system, is fundamental to assess short and long-term climate, environmental, and paleogeographic change. However, the stratigraphy and paleoenvironmental evolution of the Cretaceous Arctic is poorly constrained and a detailed bio- and chemostratigraphic correlation of major mid-Cretaceous paleoceanographic turning points such as Oceanic Anoxic Events, cold snaps, and biotic turnovers with key locations of the high- and low latitudes is missing. Here we present for the first time a high resolution bio- and carbon isotope stratigraphy of the Arctic Albian Christopher Formation of the Sverdrup Basin at Glacier Fiord in the southern part of Axel Heiberg Island, Canadian High Arctic. By using these techniques we developed a high temporal framework to record major environmental changes as it is indicated by the occurrence of glendonites and sandstone intervals of our studied Albian succession. The Albian Christopher Formation is a shale dominated marine unit with a thickness of approximately 1200 m. Several transgressive/ regressive cycles can be recognized by prograding shoreface units that break up mudrock deposition. In addition, glendonites are mainly found in the lower part of the Christopher Formation. Glendonites are pseudomorphs of calcite, after the metastable mineral ikaite, and have been often described from high latitude Permian, Jurassic and Cretaceous marine environments from the Canadian Arctic, Spitsbergen and Australia. The formation of glendonites takes place in the uppermost layer of the sediment and requires near-freezing temperatures, high salinity, and orthophosphate-rich bottom water. Although the presence of glendonites implies a range of paleoenvironmental conditions there is a consensus in the scientific literature that they reflect cooler paleoenvironmental conditions. Preliminary bio- and carbon isotope stratigraphic results suggest that the

THE DARKEST SHADOWS: DEEP MID-INFRARED EXTINCTION MAPPING OF A MASSIVE PROTOCLUSTER

Energy Technology Data Exchange (ETDEWEB)

Butler, Michael J. [Institute of Theoretical Physics, University of Zürich, CH-8057 Zürich (Switzerland); Tan, Jonathan C. [Departments of Astronomy and Physics, University of Florida, Gainesville, FL 32611 (United States); Kainulainen, Jouni [Max-Planck-Institute for Astronomy, Königstuhl 17, D-69117, Heidelberg (Germany)

2014-02-20

We use deep 8 μm Spitzer-IRAC imaging of massive Infrared Dark Cloud (IRDC) G028.37+00.07 to construct a mid-infrared (MIR) extinction map that probes mass surface densities up to Σ ∼ 1 g cm{sup –2} (A{sub V} ∼ 200 mag), amongst the highest values yet probed by extinction mapping. Merging with an NIR extinction map of the region creates a high dynamic range map that reveals structures down to A{sub V} ∼ 1 mag. We utilize the map to: (1) measure a cloud mass ∼7 × 10{sup 4} M {sub ☉} within a radius of ∼8 pc. {sup 13}CO kinematics indicate that the cloud is gravitationally bound. It thus has the potential to form one of the most massive young star clusters known in the Galaxy. (2) Characterize the structures of 16 massive cores within the IRDC, finding they can be fit by singular polytropic spheres with ρ∝r{sup −k{sub ρ}} and k {sub ρ} = 1.3 ± 0.3. They have Σ-bar ≃0.1--0.4 g cm{sup −2}—relatively low values that, along with their measured cold temperatures, suggest that magnetic fields, rather than accretion-powered radiative heating, are important for controlling fragmentation of these cores. (3) Determine the Σ (equivalently column density or A{sub V} ) probability distribution function (PDF) for a region that is nearly complete for A{sub V} > 3 mag. The PDF is well fit by a single log-normal with mean A-bar {sub V}≃9 mag, high compared to other known clouds. It does not exhibit a separate high-end power law tail, which has been claimed to indicate the importance of self-gravity. However, we suggest that the PDF does result from a self-similar, self-gravitating hierarchy of structures present over a wide range of scales in the cloud.

Crossing the Resolution Limit in Near-Infrared Imaging of Silicon Chips: Targeting 10-nm Node Technology

Directory of Open Access Journals (Sweden)

Krishna Agarwal

2015-05-01

Full Text Available The best reported resolution in optical failure analysis of silicon chips is 120-nm half pitch demonstrated by Semicaps Private Limited, whereas the current and future industry requirement for 10-nm node technology is 100-nm half pitch. We show the first experimental evidence for resolution of features with 100-nm half pitch buried in silicon (λ/10.6, thus fulfilling the industry requirement. These results are obtained using near-infrared reflection-mode imaging using a solid immersion lens. The key novel feature of our approach is the choice of an appropriately sized collection pinhole. Although it is usually understood that, in general, resolution is improved by using the smallest pinhole consistent with an adequate signal level, it is found that in practice for silicon chips there is an optimum pinhole size, determined by the generation of induced currents in the sample. In failure analysis of silicon chips, nondestructive imaging is important to avoid disturbing the functionality of integrated circuits. High-resolution imaging techniques like SEM or TEM require the transistors to be exposed destructively. Optical microscopy techniques may be used, but silicon is opaque in the visible spectrum, mandating the use of near-infrared light and thus poor resolution in conventional optical microscopy. We expect our result to change the way semiconductor failure analysis is performed.

INFRARED HIGH-RESOLUTION INTEGRATED LIGHT SPECTRAL ANALYSES OF M31 GLOBULAR CLUSTERS FROM APOGEE

Energy Technology Data Exchange (ETDEWEB)

Sakari, Charli M. [Department of Astronomy, University of Washington, Seattle WA 98195-1580 (United States); Shetrone, Matthew D. [McDonald Observatory, University of Texas at Austin, HC75 Box 1337-MCD, Fort Davis, TX 79734 (United States); Schiavon, Ricardo P. [Gemini Observatory, 670 N. A’Ohoku Place, Hilo, HI 96720 (United States); Bizyaev, Dmitry; Pan, Kaike [Apache Point Observatory and New Mexico State University, P.O. Box 59, Sunspot, NM, 88349-0059 (United States); Prieto, Carlos Allende; García-Hernández, Domingo Aníbal [Instituto de Astrofísica de Canarias (IAC), Va Lactea s/n, E-38205 La Laguna, Tenerife (Spain); Beers, Timothy C. [Department of Physics and JINA Center for the Evolution of the Elements, University of Notre Dame, Notre Dame, IN 46556 (United States); Caldwell, Nelson [Harvard-Smithsonian Center for Astrophysics, 60 Garden Street, Cambridge, MA 02138 (United States); Lucatello, Sara [INAF Osservatorio Astronomico di Padova, Vicolo dellOsservatorio 5, I-35122 Padova (Italy); Majewski, Steven; O’Connell, Robert W. [Dept. of Astronomy, University of Virginia, Charlottesville, VA 22904-4325 (United States); Strader, Jay, E-mail: sakaricm@u.washington.edu [Department of Physics and Astronomy, Michigan State University, East Lansing, MI 48824 (United States)

2016-10-01

Chemical abundances are presented for 25 M31 globular clusters (GCs), based on moderately high resolution ( R = 22,500) H -band integrated light (IL) spectra from the Apache Point Observatory Galactic Evolution Experiment (APOGEE). Infrared (IR) spectra offer lines from new elements, lines of different strengths, and lines at higher excitation potentials compared to the optical. Integrated abundances of C, N, and O are derived from CO, CN, and OH molecular features, while Fe, Na, Mg, Al, Si, K, Ca, and Ti abundances are derived from atomic features. These abundances are compared to previous results from the optical, demonstrating the validity and value of IR IL analyses. The CNO abundances are consistent with typical tip of the red giant branch stellar abundances but are systematically offset from optical Lick index abundances. With a few exceptions, the other abundances agree between the optical and the IR within the 1 σ uncertainties. The first integrated K abundances are also presented and demonstrate that K tracks the α elements. The combination of IR and optical abundances allows better determinations of GC properties and enables probes of the multiple populations in extragalactic GCs. In particular, the integrated effects of the Na/O anticorrelation can be directly examined for the first time.

Recent progress in diode-pumped mid-infrared vibronic solid-state lasers

International Nuclear Information System (INIS)

Sorokina, I.T.; Sorokin, E.; Mirov, S.; Schaffers, K.

2002-01-01

Full text: The last few years were marked by the increased interest of researchers towards the new class of transition-metal doped zinc chalcogenides. In particular Cr:ZnSe attracts a lot of attention as broadly tunable continuous-wave (cw), mode-locked and diode-pumped lasers operating around 2.5 mm. This interest is explained by the absence of other comparable tunable room-temperature laser sources in this spectral region. However, another member of the II-VI compounds family Cr:ZnS, has yet remained barely studied as a laser medium. Recently we demonstrated the first continuous-wave room-temperature tunable over more than 280 nm around 2.3 μm Cr 2+ :ZnS laser, pumped with a Co:MgF2 laser and yielding over 100 mW of output power. The most recent result is the development of a compact tunable over 700 nm continuous-wave room-temperature Cr 2+ :ZnS laser, pumped by the diode-pumped Er-fiber laser at 1.6 μm and generating 0.7 W of the linearly polarized radiation. We also demonstrated direct diode-pumping at 1.6 μm of the Cr 2+ :ZnS. Although the Cr:ZnS exhibited lower (relatively to the Cr:ZnSe) efficiency and output power due to the higher passive losses of the available Cr:ZnS samples, the analysis of the spectroscopic and laser data indicates the high potential of Cr:ZnS for compact broadly tunable mid-infrared systems, as well as for high power applications. The physics of the novel diode-pumped laser systems is highly interesting. It comprises the features of the ion-doped dielectric crystalline lasers and semiconductors. For example, we observe in these media, for the first time to our knowledge, a new nonlinear phenomenon, which is analogous to the opto-optical switching process, where the laser output of the diode-pumped continuous-wave Cr:ZnSe and Cr:ZnS lasers around 2.5 μm is modulated by only a few milliwatt of the visible (470-500 nm) and near-infrared radiation (740-770 nm). We present a physical explanation of the observed effect. Refs. 4 (author)

Synergy Effect of Combining Fluorescence and Mid Infrared Fiber Spectroscopy for Kidney Tumor Diagnostics

Directory of Open Access Journals (Sweden)

Andrey Bogomolov

2017-11-01

Full Text Available Matching pairs of tumor and non-tumor kidney tissue samples of four patients were investigated ex vivo using a combination of two methods, attenuated total reflection mid infrared spectroscopy and fluorescence spectroscopy, through respectively prepared and adjusted fiber probes. In order to increase the data information content, the measurements on tissue samples in both methods were performed in the same 31 preselected positions. Multivariate data analysis revealed a synergic effect of combining the two methods for the diagnostics of kidney tumor compared to individual techniques.

Rapid determination of carbohydrates, ash, and extractives contents of straw using attenuated total reflectance fourier transform mid-infrared spectroscopy.

Science.gov (United States)

Tamaki, Yukihiro; Mazza, Giuseppe

2011-06-22

Analysis of the chemical components of lignocellulosic biomass is essential to understanding its potential for utilization. Mid-infrared spectroscopy and partial least-squares regression were used for rapid measurement of the carbohydrate (total glycans; glucan; xylan; galactan; arabinan; mannan), ash, and extractives content of triticale and wheat straws. Calibration models for total glycans, glucan, and extractives showed good and excellent predictive performance on the basis of slope, r², RPD, and R/SEP criteria. The xylan model showed good and acceptable predictive performance. However, the ash model was evaluated as providing only approximate quantification and screening. The models for galactan, arabinan, and mannan indicated poor and insufficient prediction for application. Most models could predict both triticale and wheat straw samples with the same degree of accuracy. Mid-infrared spectroscopic techniques coupled with partial least-squares regression can be used for rapid prediction of total glycans, glucan, xylan, and extractives in triticale and wheat straw samples.

Evaluation of chemical parameters in soft mold-ripened cheese during ripening by mid-infrared spectroscopy.

Science.gov (United States)

Martín-del-Campo, S T; Picque, D; Cosío-Ramírez, R; Corrieu, G

2007-06-01

The suitability of mid-infrared spectroscopy (MIR) to follow the evolution throughout ripening of specific physicochemical parameters in Camembert-type cheeses was evaluated. The infrared spectra were obtained directly from raw cheese samples deposited on an attenuated total reflectance crystal. Significant correlations were observed between physicochemical data, pH, acid-soluble nitrogen, nonprotein nitrogen, ammonia (NH4+), lactose, and lactic acid. Dry matter showed significant correlation only with lactose and nonprotein nitrogen. Principal components analysis factorial maps of physicochemical data showed a ripening evolution in 2 steps, from d 1 to d 7 and from d 8 to d 27, similar to that observed previously from infrared spectral data. Partial least squares regressions made it possible to obtain good prediction models for dry matter, acid-soluble nitrogen, nonprotein nitrogen, lactose, lactic acid, and NH4+ values from spectral data of raw cheese. The values of 3 statistical parameters (coefficient of determination, root mean square error of cross validation, and ratio prediction deviation) are satisfactory. Less precise models were obtained for pH.

Sensitive Multi-Species Emissions Monitoring: Infrared Laser-Based Detection of Trace-Level Contaminants

Energy Technology Data Exchange (ETDEWEB)

Steill, Jeffrey D. [Sandia National Lab. (SNL-CA), Livermore, CA (United States); Huang, Haifeng [Sandia National Lab. (SNL-CA), Livermore, CA (United States); Hoops, Alexandra A. [Sandia National Lab. (SNL-CA), Livermore, CA (United States); Patterson, Brian D. [Sandia National Lab. (SNL-CA), Livermore, CA (United States); Birtola, Salvatore R. [Sandia National Lab. (SNL-CA), Livermore, CA (United States); Jaska, Mark [Sandia National Lab. (SNL-CA), Livermore, CA (United States); Strecker, Kevin E. [Sandia National Lab. (SNL-CA), Livermore, CA (United States); Chandler, David W. [Sandia National Lab. (SNL-CA), Livermore, CA (United States); Bisson, Soott [Sandia National Lab. (SNL-CA), Livermore, CA (United States)

2014-09-01

This report summarizes our development of spectroscopic chemical analysis techniques and spectral modeling for trace-gas measurements of highly-regulated low-concentration species present in flue gas emissions from utility coal boilers such as HCl under conditions of high humidity. Detailed spectral modeling of the spectroscopy of HCl and other important combustion and atmospheric species such as H 2 O, CO 2 , N 2 O, NO 2 , SO 2 , and CH 4 demonstrates that IR-laser spectroscopy is a sensitive multi-component analysis strategy. Experimental measurements from techniques based on IR laser spectroscopy are presented that demonstrate sub-ppm sensitivity levels to these species. Photoacoustic infrared spectroscopy is used to detect and quantify HCl at ppm levels with extremely high signal-to-noise even under conditions of high relative humidity. Additionally, cavity ring-down IR spectroscopy is used to achieve an extremely high sensitivity to combustion trace gases in this spectral region; ppm level CH 4 is one demonstrated example. The importance of spectral resolution in the sensitivity of a trace-gas measurement is examined by spectral modeling in the mid- and near-IR, and efforts to improve measurement resolution through novel instrument development are described. While previous project reports focused on benefits and complexities of the dual-etalon cavity ring-down infrared spectrometer, here details on steps taken to implement this unique and potentially revolutionary instrument are described. This report also illustrates and critiques the general strategy of IR- laser photodetection of trace gases leading to the conclusion that mid-IR laser spectroscopy techniques provide a promising basis for further instrument development and implementation that will enable cost-effective sensitive detection of multiple key contaminant species simultaneously.

Fourier Transform Infrared Spectroscopic Studies Of Wheat In The Mid Infrared

Science.gov (United States)

Olinger, Jill M.; Griffiths, Peter R.

1989-12-01

Official grain standards of the United States state that wheat may be divided into seven classes which are: Durum, Red Durum, Hard Red Spring, Hard Red Winter, Soft Red Winter, White, and Mixed.1 Most end uses of wheat involve converting the grain into flour through one of a variety of grinding methods. The quality of wheat-based products is often very dependent upon the type or class of wheat which was used to make the flour. Pasta products, for example, are made almost exclusively from the flour of durum wheats, which are the hardest of the wheats listed above. The highest quality breads are produced using flour from wheats classed as hard, whereas cakes, cookies and pastries are considered best when flour from wheats classed as soft are used. It is obvious then that the capability of determining the class of a particular wheat, especially with respect to hardness, is of economic importance to growers, processors, and merchants of wheat and wheat products. Hardness has been measured in many different ways 2-5 but, as of yet, no one method has become the method of choice. This paper reports on the use of principal components analysis (PCA) of mid infrared diffuse reflectance (DR) spectra of diluted ground wheats to aid in the classification of those wheats with respect to their hardness. The theory and mathematics involved in a principal component analysis have been described elsewhere.9

New Measurements of s-Process Enrichments in Planetary Nebulae from High-Resolution Near-Infrared Spectra

Science.gov (United States)

Dinerstein, Harriet L.; Karakas, Amanda; Sterling, Nicholas C.; Kaplan, Kyle

2017-06-01

We present preliminary results from a high-spectral resolution survey of near-infrared emission lines of neutron-capture elements in planetary nebulae using the Immersion Grating Infrared Spectrometer, IGRINS (Park et al. 2014, SPIE. 9147, 1), which spans the H- and K-bands at spectral resolving power R ≈ 45,000. Both the [Kr III] and [Se IV] lines identified by Dinerstein (2001, ApJL, 550, L223) are seen in nearly all of an initial sample of ≈ 15 nebulae, with improved accuracy over earlier studies based on lower-resolution data (Sterling & Dinerstein 2008, ApJS, 174, 158; Sterling, Porter, & Dinerstein 2015, ApJS, 218, 25). Several new detections of the [Rb IV], [Cd IV], and [Ge VI] lines identified by Sterling et al. (2016, ApJL, 819, 9), as well as a [Br V] line, were made. About half the objects in this sample descend from stars with [Fe/H] = -0.7 ± 0.2 dex, while the remainder have -0.3 ≤ [Fe/H] ≤ 0. We compare the measured enhancements of Se, Kr, Rb, and Cd with predictions of their production by slow-neutron captures (the s-process) during the AGB from theoretical evolutionary models for the corresponding metallicities and various initial masses. New nucleosynthesis calculations were carried out for [Fe/H] = -0.7 for initial masses between 1.1 and 3 M⊙ using the Monash stellar evolution and post-processing codes described in Karakas & Lugaro (2016, ApJ, 825, 26), which provides the nucleosynthesis predictions for the metal-rich end of our sample. The Monash models predict enrichments larger by factors of two or more than those from FRUITY (Cristallo et al. 2015, ApJS, 219, 40) and NuGRID (Pignatari et al. 2016, ApJS, 225, 24) models for the same masses and metallicities. We find that the Monash models are in substantially better agreement than the others with the abundances derived from the IGRINS observations.This work is based on data taken at the McDonald Observatory of the University of Texas at Austin. IGRINS was developed with support from

Increasing sensitivity and angle-of-view of mid-wave infrared detectors by integration with dielectric microspheres

Energy Technology Data Exchange (ETDEWEB)

Allen, Kenneth W., E-mail: kenneth.allen@gtri.gatech.edu; Astratov, Vasily N., E-mail: astratov@uncc.edu [Department of Physics and Optical Science, Center for Optoelectronics and Optical Communications, University of North Carolina at Charlotte, Charlotte, North Carolina 28223-0001 (United States); Air Force Research Laboratory, Sensors Directorate, Wright Patterson AFB, Ohio 45433 (United States); UES, Dayton, Ohio 45433 (United States); Abolmaali, Farzaneh [Department of Physics and Optical Science, Center for Optoelectronics and Optical Communications, University of North Carolina at Charlotte, Charlotte, North Carolina 28223-0001 (United States); Duran, Joshua M.; Ariyawansa, Gamini; Limberopoulos, Nicholaos I. [Air Force Research Laboratory, Sensors Directorate, Wright Patterson AFB, Ohio 45433 (United States); Urbas, Augustine M. [Air Force Research Laboratory, Materials and Manufacturing Directorate, Wright-Patterson AFB, Ohio 45433 (United States)

2016-06-13

We observed up to 100 times enhancement of sensitivity of mid-wave infrared photodetectors in the 2–5 μm range by using photonic jets produced by sapphire, polystyrene, and soda-lime glass microspheres with diameters in the 90–300 μm range. By finite-difference time-domain (FDTD) method for modeling, we gain insight into the role of the microspheres refractive index, size, and alignment with respect to the detector mesa. A combination of enhanced sensitivity with angle-of-view (AOV) up to 20° is demonstrated for individual photodetectors. It is proposed that integration with microspheres can be scaled up for large focal plane arrays, which should provide maximal light collection efficiencies with wide AOVs, a combination of properties highly attractive for imaging applications.

High-Resolution Mid-IR Imaging of Jupiter's Great Red Spot: Comparing Cassini, VLT and Subaru Observations

Science.gov (United States)

Fletcher, Leigh N.; Orton, G. S.; Yanamandra-Fisher, P.; Irwin, P. G. J.; Baines, K. H.; Edkins, E.; Line, M. R.; Mousis, O.; Parrish, P. D.; Vanzi, L.; Fuse, T.; Fujoyoshi, T.

2008-09-01

In the eight years since the Cassini fly-by of Jupiter, the spatial resolution of ground-based observations of Jupiter's giant anticyclonic storm systems (the Great Red Spot, Oval BA and others) using 8m-class telescopes has surpassed the resolution of the Cassini/CIRS maps. We present a time-series of mid-IR imaging of the Great Red Spot (GRS) and its environs from the VISIR instrument on the Very Large Telescope (UT3/Melipal) and the COMICS instrument on the Subaru telescope (Hawaii). The NEMESIS optimal-estimation retrieval algorithm (Irwin et al., 2008) is used to analyse both the 7-25 micron filtered imaging from 2005-2008 and Cassini/CIRS 7-16 micron data from 2000. We demonstrate the ability to map temperatures in the 100-400 mbar range, NH3, aerosol opacity and the para-H2 fraction from the filtered imaging. Furthermore, the Cassini/CIRS spectra are used to map the PH3 mole fraction around the GRS. The thermal field, gaseous composition and aerosol distribution are used as diagnostics for the atmospheric motion associated with the GRS. Changes in the atmospheric state in response to close encounters with Oval BA and other vortices will be assessed. These results will be discussed in light of their implications for the planning of the Europa-Jupiter System Mission.

Restraint deformation and corrosion protection of gold deposited aluminum mirrors for cold optics of mid-infrared instruments

Science.gov (United States)

Uchiyama, Mizuho; Miyata, Takashi; Sako, Shigeyuki; Kamizuka, Takafumi; Nakamura, Tomohiko; Asano, Kentaro; Okada, Kazushi; Onaka, Takashi; Sakon, Itsuki; Kataza, Hirokazu; Sarugaku, Yuki; Kirino, Okiharu; Nakagawa, Hiroyuki; Okada, Norio; Mitsui, Kenji

2014-07-01

We report the restraint deformation and the corrosion protection of gold deposited aluminum mirrors for mid-infrared instruments. To evaluate the deformation of the aluminum mirrors by thermal shrinkage, monitoring measurement of the surface of a mirror has been carried out in the cooling cycles from the room temperature to 100 K. The result showed that the effect of the deformation was reduced to one fourth if the mirror was screwed with spring washers. We have explored an effective way to prevent the mirror from being galvanically corroded. A number of samples have been prepared by changing the coating conditions, such as inserting an insulation layer, making a multi-layer and overcoating water blocking layer, or carrying out precision cleaning before coating. Precision cleaning before the deposition and protecting coat with SiO over the gold layer seemed to be effective in blocking corrosion of the aluminum. The SiO over-coated mirror has survived the cooling test for the mid-infrared use and approximately 1 percent decrease in the reflectance has been detected at 6-25 microns compared to gold deposited mirror without coating.

Extended mid-infrared emission from VV 114: Probing the birth of a ULIRG

Science.gov (United States)

Le Floc'h, E.; Charmandaris, V.; Laurent, O.; Mirabel, I. F.; Gallais, P.; Sauvage, M.; Vigroux, L.; Cesarsky, C.

2002-08-01

We present our 5-16 mu m spectro-imaging observations of VV 114, an infrared luminous early-stage merger of two galaxies VV 114E and VV 114W, taken with the ISOCAM camera on-board the Infrared Space Observatory. We find that only 40% of the mid-infrared (MIR) flux is associated with a compact nuclear region of VV 114E, while the rest of the emission originates from a rather diffuse component extended over several kpc in the regions between VV 114E and VV 114W. This is in stark contrast with the very compact MIR starbursts usually seen in luminous and ultraluminous infrared galaxies. A secondary peak of MIR emission is associated with an extra-nuclear star forming region of VV 114W which displays the largest Hα equivalent width in the whole system. Comparing our data with the distribution of the molecular gas and cold dust, as well as with radio observations, it becomes evident that the conversion of molecular gas into stars can be triggered over large areas at the very first stages of an interaction. This extended star formation along with the extreme nuclear starburst observed in VV 114E can easily lead to the heating of dust grains found in the tidally disturbed disks of the progenitor galaxies and subsequently traced via their MIR emission. The presence of a very strong continuum at the 5-6.5 mu m range in the spectrum of VV 114E indicates that an enshrouded active galactic nucleus (AGN) may contribute to ~ 40% of its MIR flux. We finally note that the relative variations in the UV to radio spectral properties between VV 114E and VV 114W provide evidence that the extinction-corrected star formation rate of similar objects at high z, such as those detected in optical deep surveys, cannot be accurately derived from their rest-frame UV properties. Based on observations with the ISO satellite, an ESA project with instruments funded by ESA Member States (especially the PI countries: France, Germany, the Netherlands and the United Kingdom) and with the participation

THE ULTRAVIOLET-TO-MID-INFRARED SPECTRAL ENERGY DISTRIBUTION OF WEAK EMISSION LINE QUASARS

International Nuclear Information System (INIS)

Lane, Ryan A.; Shemmer, Ohad; Diamond-Stanic, Aleksandar M.; Fan Xiaohui; Anderson, Scott F.; Brandt, W. N.; Schneider, Donald P.; Plotkin, Richard M.; Richards, Gordon T.; Strauss, Michael A.

2011-01-01

We present Spitzer Space Telescope photometry of 18 Sloan Digital Sky Survey (SDSS) quasars at 2.7 ≤ z ≤ 5.9 which have weak or undetectable high-ionization emission lines in their rest-frame ultraviolet (UV) spectra (hereafter weak-lined quasars, or WLQs). The Spitzer data are combined with SDSS spectra and ground-based, near-infrared (IR) photometry of these sources to produce a large inventory of spectral energy distributions (SEDs) of WLQs across the rest-frame ∼0.1-5 μm spectral band. The SEDs of our sources are inconsistent with those of BL Lacertae objects which are dominated by synchrotron emission due to a jet aligned close to our line of sight, but are consistent with the SED of ordinary quasars with similar luminosities and redshifts that exhibit a near-to-mid-IR 'bump', characteristic of hot dust emission. This indicates that broad emission lines in WLQs are intrinsically weak, rather than suffering continuum dilution from a jet, and that such sources cannot be selected efficiently from traditional photometric surveys.

THE ULTRAVIOLET-TO-MID-INFRARED SPECTRAL ENERGY DISTRIBUTION OF WEAK EMISSION LINE QUASARS

Energy Technology Data Exchange (ETDEWEB)

Lane, Ryan A.; Shemmer, Ohad [Department of Physics, University of North Texas, Denton, TX 76203 (United States); Diamond-Stanic, Aleksandar M. [Center for Astrophysics and Space Sciences, University of California, San Diego, La Jolla, CA 92093 (United States); Fan Xiaohui [Steward Observatory, University of Arizona, 933 North Cherry Avenue, Tucson, AZ 85721 (United States); Anderson, Scott F. [Department of Astronomy, University of Washington, Box 351580, Seattle, WA 98195 (United States); Brandt, W. N.; Schneider, Donald P. [Department of Astronomy and Astrophysics, The Pennsylvania State University, University Park, PA 16802 (United States); Plotkin, Richard M. [Astronomical Institute ' Anton Pannekoek' , University of Amsterdam, Science Park 904, NL-1098 XH Amsterdam (Netherlands); Richards, Gordon T. [Department of Physics, Drexel University, 3141 Chestnut Street, Philadelphia, PA 19104 (United States); Strauss, Michael A., E-mail: RyanLane@my.unt.edu, E-mail: ohad@unt.edu [Princeton University Observatory, Peyton Hall, Princeton, NJ 08544 (United States)

2011-12-20

We present Spitzer Space Telescope photometry of 18 Sloan Digital Sky Survey (SDSS) quasars at 2.7 {<=} z {<=} 5.9 which have weak or undetectable high-ionization emission lines in their rest-frame ultraviolet (UV) spectra (hereafter weak-lined quasars, or WLQs). The Spitzer data are combined with SDSS spectra and ground-based, near-infrared (IR) photometry of these sources to produce a large inventory of spectral energy distributions (SEDs) of WLQs across the rest-frame {approx}0.1-5 {mu}m spectral band. The SEDs of our sources are inconsistent with those of BL Lacertae objects which are dominated by synchrotron emission due to a jet aligned close to our line of sight, but are consistent with the SED of ordinary quasars with similar luminosities and redshifts that exhibit a near-to-mid-IR 'bump', characteristic of hot dust emission. This indicates that broad emission lines in WLQs are intrinsically weak, rather than suffering continuum dilution from a jet, and that such sources cannot be selected efficiently from traditional photometric surveys.

NATO Advanced Research Workshop on Terahertz and Mid Infrared Radiation

CERN Document Server

Pereira, Mauro F; Terahertz and Mid Infrared Radiation

2011-01-01

Terahertz (THz) and Mid-Infrared (MIR) radiation  (TERA-MIR) can be transmitted through nearly any material without causing biological harm. Novel and rapid methods of detection can be created with devices operation in these spectral ranges allowing scanning for weapons, detecting hidden explosives (including plastic landmines), controlling the quality of food and a host of other exciting applications.  This book focuses on mathematical and physical aspects of the field, on unifying these two spectral domains (THz and MIR) with regard to common sources, detectors, materials and applications, and on key interdisciplinary topics. The main THz and MIR source is the quantum cascade laser (QCL). Thus significant attention is paid to the challenge of turning this advanced technology into affordable commercial devices so as to exploit its enormous potential. However other alternatives to THz QCLs are also presented, e.g.  sub-terahertz imaging from avalanching GaAs bipolar transistors, Josephson junctions as THz ...

New frontiers of high-resolution spectroscopy: Probing the atmospheres of brown dwarfs and reflected light from exoplanets

Science.gov (United States)

Birkby, Jayne; Alonso, Roi; Brogi, Matteo; Charbonneau, David; Fortney, Jonathan; Hoyer, Sergio; Johnson, John Asher; de Kok, Remco; Lopez-Morales, Mercedes; Montet, Ben; Snellen, Ignas

2015-12-01

High-resolution spectroscopy (R>25,000) is a robust and powerful tool in the near-infrared characterization of exoplanet atmospheres. It has unambiguously revealed the presence of carbon monoxide and water in several hot Jupiters, measured the rotation rate of beta Pic b, and suggested the presence of fast day-to-night winds in one atmosphere. The method is applicable to transiting, non-transiting, and directly-imaged planets. It works by resolving broad molecular bands in the planetary spectrum into a dense, unique forest of individual lines and tracing them directly by their Doppler shift, while the star and tellurics remain essentially stationary. I will focus on two ongoing efforts to expand this technique. First, I will present new results on 51 Peg b revealing its infrared atmospheric compositional properties, then I will discuss an ongoing optical HARPS-N/TNG campaign (due mid October 2015) to obtain a detailed albedo spectrum of 51 Peg b at 387-691 nm in bins of 50nm. This spectrum would provide strong constraints on the previously claimed high albedo and potentially cloudy nature of this planet. Second, I will discuss preliminary results from Keck/NIRSPAO observations (due late September 2015) of LHS 6343 C, a 1000 K transiting brown dwarf with an M-dwarf host star. The high-resolution method converts this system into an eclipsing, double-lined spectroscopic binary, thus allowing dynamical mass and radius estimates of the components, free from astrophysical assumptions. Alongside probing the atmospheric composition of the brown dwarf, these data would provide the first model-independent study of the bulk properties of an old brown dwarf, with masses accurate to <5%, placing a crucial constraint on brown dwarf evolution models.

Sensores ópticos com detecção no infravermelho próximo e médio Near and mid infrared optical sensors

Directory of Open Access Journals (Sweden)

Kássio M. G. Lima

2009-01-01

Full Text Available Optical chemical sensors with detection in the near and mid infrared region are reviewed. Fundamental concepts of infrared spectroscopy and optical chemical sensors are briefly described, before presenting some aspects on optical chemical sensors, such as synthesis of NIR and IR reagents, preparation of new materials as well as application in determinations of species of biological, industrial and environmental importance.

Generation and Applications of High Average Power Mid-IR Supercontinuum in Chalcogenide Fibers

OpenAIRE

Petersen, Christian Rosenberg

2016-01-01

Mid-infrared supercontinuum with up to 54.8 mW average power, and maximum bandwidth of 1.77-8.66 μm is demonstrated as a result of pumping tapered chalcogenide photonic crystal fibers with a MHz parametric source at 4 μm

A multispectral study of an extratropical cyclone with Nimbus 3 medium resolution infrared radiometer data

Science.gov (United States)

Holub, R.; Shenk, W. E.

1973-01-01

Four registered channels (0.2 to 4, 6.5 to 7, 10 to 11, and 20 to 23 microns) of the Nimbus 3 Medium Resolution Infrared Radiometer (MRIR) were used to study 24-hr changes in the structure of an extratropical cyclone during a 6-day period in May 1969. Use of a stereographic-horizon map projection insured that the storm was mapped with a single perspective throughout the series and allowed the convenient preparation of 24-hr difference maps of the infrared radiation fields. Single-channel and multispectral analysis techniques were employed to establish the positions and vertical slopes of jetstreams, large cloud systems, and major features of middle and upper tropospheric circulation. Use of these techniques plus the difference maps and continuity of observation allowed the early detection of secondary cyclones developing within the circulation of the primary cyclone. An automated, multispectral cloud-type identification technique was developed, and comparisons that were made with conventional ship reports and with high-resolution visual data from the image dissector camera system showed good agreement.

Infrared upconversion hyperspectral imaging

DEFF Research Database (Denmark)

Kehlet, Louis Martinus; Tidemand-Lichtenberg, Peter; Dam, Jeppe Seidelin

2015-01-01

In this Letter, hyperspectral imaging in the mid-IR spectral region is demonstrated based on nonlinear frequency upconversion and subsequent imaging using a standard Si-based CCD camera. A series of upconverted images are acquired with different phase match conditions for the nonlinear frequency...... conversion process. From this, a sequence of monochromatic images in the 3.2-3.4 mu m range is generated. The imaged object consists of a standard United States Air Force resolution target combined with a polystyrene film, resulting in the presence of both spatial and spectral information in the infrared...... image. (C) 2015 Optical Society of America...

Gain and Threshold Current in Type II In(AsSb Mid-Infrared Quantum Dot Lasers

Directory of Open Access Journals (Sweden)

Qi Lu

2015-04-01

Full Text Available In this work, we improved the performance of mid-infrared type II InSb/InAs quantum dot (QD laser diodes by incorporating a lattice-matched p-InAsSbP cladding layer. The resulting devices exhibited emission around 3.1 µm and operated up to 120 K in pulsed mode, which is the highest working temperature for this type of QD laser. The modal gain was estimated to be 2.9 cm−1 per QD layer. A large blue shift (~150 nm was observed in the spontaneous emission spectrum below threshold due to charging effects. Because of the QD size distribution, only a small fraction of QDs achieve threshold at the same injection level at 4 K. Carrier leakage from the waveguide into the cladding layers was found to be the main reason for the high threshold current at higher temperatures.

An in-depth look at the lunar crater Copernicus: Exposed mineralogy by high-resolution near-infrared spectroscopy

Science.gov (United States)

Bugiolacchi, Roberto; Mall, Urs; Bhatt, Megha; McKenna-Lawlor, Susan; Banaszkiewicz, Marek; Brønstad, Kjell; Nathues, Andreas; Søraas, Finn; Ullaland, Kjetil; Pedersen, Rolf B.

2011-05-01

Newly acquired, sequentially spaced, high-resolution near-infrared spectra across the central section of crater Copernicus' interior have been analyzed using a range of complementary techniques and indexes. We have developed a new interpretative method based on a multiple stage normalization process that appears to both confirm and expand on previous mineralogical estimations and mapping. In broad terms, the interpreted distribution of the principle mafic species suggests an overall composition of surface materials dominated by calcium-poor pyroxenes and minor olivine but with notable exceptions: the southern rim displays strong ca-rich pyroxene absorption features and five other locations, the uppermost northern crater wall, opposite rim sections facing the crater floor, and the central peak Pk1 and at the foot of Pk3, show instead strong olivine signatures. We also propose impact glass an alternative interpretation to the source of the weak but widespread olivine-like spectral signature found in low-reflectance samples, since it probably represents a major regolith constituent and component in large craters such as Copernicus. The high quality and performance of the SIR-2 data allows for the detection of diagnostic key mineral species even when investigating spectral samples with very subdued absorption features, confirming the intrinsic high-quality value of the returned data.

The High Time Resolution Universe surveys for pulsars and fast transients

Science.gov (United States)

Keith, Michael J.

2013-03-01

The High Time Resolution Universe survey for pulsars and transients is the first truly all-sky pulsar survey, taking place at the Parkes Radio Telescope in Australia and the Effelsberg Radio Telescope in Germany. Utilising multibeam receivers with custom built all-digital recorders the survey targets the fastest millisecond pulsars and radio transients on timescales of 64 μs to a few seconds. The new multibeam digital filter-bank system at has a factor of eight improvement in frequency resolution over previous Parkes multibeam surveys, allowing us to probe further into the Galactic plane for short duration signals. The survey is split into low, mid and high Galactic latitude regions. The mid-latitude portion of the southern hemisphere survey is now completed, discovering 107 previously unknown pulsars, including 26 millisecond pulsars. To date, the total number of discoveries in the combined survey is 135 and 29 MSPs These discoveries include the first magnetar to be discovered by it's radio emission, unusual low-mass binaries, gamma-ray pulsars and pulsars suitable for pulsar timing array experiments.

Coastal barrier stratigraphy for Holocene high-resolution sea-level reconstruction.

Science.gov (United States)

Costas, Susana; Ferreira, Óscar; Plomaritis, Theocharis A; Leorri, Eduardo

2016-12-08

The uncertainties surrounding present and future sea-level rise have revived the debate around sea-level changes through the deglaciation and mid- to late Holocene, from which arises a need for high-quality reconstructions of regional sea level. Here, we explore the stratigraphy of a sandy barrier to identify the best sea-level indicators and provide a new sea-level reconstruction for the central Portuguese coast over the past 6.5 ka. The selected indicators represent morphological features extracted from coastal barrier stratigraphy, beach berm and dune-beach contact. These features were mapped from high-resolution ground penetrating radar images of the subsurface and transformed into sea-level indicators through comparison with modern analogs and a chronology based on optically stimulated luminescence ages. Our reconstructions document a continuous but slow sea-level rise after 6.5 ka with an accumulated change in elevation of about 2 m. In the context of SW Europe, our results show good agreement with previous studies, including the Tagus isostatic model, with minor discrepancies that demand further improvement of regional models. This work reinforces the potential of barrier indicators to accurately reconstruct high-resolution mid- to late Holocene sea-level changes through simple approaches.

Narrowband widely tunable CW mid-infrared generator based on difference frequency generation in periodically poled KTP and KTA crystals

Czech Academy of Sciences Publication Activity Database

Baravets, Yauhen; Honzátko, Pavel; Todorov, Filip; Gladkov, Petar

2016-01-01

Roč. 48, č. 5 (2016), May ISSN 0306-8919 R&D Projects: GA MŠk LD14112 Grant - others:COST(XE) MP1204 Institutional support: RVO:67985882 Keywords : Fiber optics amplifiers * Difference-frequency generation * Mid-infrared tunable laser source Subject RIV: BH - Optics , Masers, Lasers Impact factor: 1.055, year: 2016

GTC/OSIRIS SPECTROSCOPIC IDENTIFICATION OF A FAINT L SUBDWARF IN THE UKIRT INFRARED DEEP SKY SURVEY

International Nuclear Information System (INIS)

Lodieu, N.; Osorio, M. R. Zapatero; MartIn, E. L.; Solano, E.; Aberasturi, M.

2010-01-01

We present the discovery of an L subdwarf in 234 deg 2 common to the UK InfraRed Telescope (UKIRT) Infrared Deep Sky Survey Large Area Survey Data Release 2 and the Sloan Digital Sky Survey Data Release 3. This is the fifth L subdwarf announced to date, the first one identified in the UKIRT Infrared Deep Sky Survey, and the faintest known. The blue optical and near-infrared colors of ULAS J135058.86+081506.8 and its overall spectra energy distribution are similar to the known mid-L subdwarfs. Low-resolution optical (700-1000 nm) spectroscopy with the Optical System for Imaging and low Resolution Integrated Spectroscopy spectrograph on the 10.4 m Gran Telescopio de Canarias reveals that ULAS J135058.86+081506.8 exhibits a strong K I pressure-broadened line at 770 nm and a red slope longward of 800 nm, features characteristics of L-type dwarfs. From direct comparison with the four known L subdwarfs, we estimate its spectral type to be sdL4-sdL6 and derive a distance in the interval 94-170 pc. We provide a rough estimate of the space density for mid-L subdwarfs of 1.5 x 10 -4 pc -3 .

Validation of mid-infrared spectrometry in milk for predicting body energy status in Holstein-Friesian cows

OpenAIRE

McParland, S.; Banos, G.; McCarthy, B.; Lewis, E.; Coffey, M. P.; O'Neill, B.; O'Donovan, M.; Wall, E.; Berry, D. P.

2012-01-01

Cow energy balance is known to be associated with cow health and fertility; therefore, routine access to data on energy balance can be useful in both management and breeding decisions to improve cow performance. The objective of this study was to determine if individual cow milk mid-infrared spectra (MIR) could be useful to predict cow energy balance across contrasting production systems. Direct energy balance was calculated as the differential between energy intake and energy output in milk ...

MID-INFRARED EVIDENCE FOR ACCELERATED EVOLUTION IN COMPACT GROUP GALAXIES

International Nuclear Information System (INIS)

Walker, Lisa May; Johnson, Kelsey E.; Gallagher, Sarah C.; Hibbard, John E.; Hornschemeier, Ann E.; Tzanavaris, Panayiotis; Charlton, Jane C.; Jarrett, Thomas H.

2010-01-01

Compact galaxy groups are at the extremes of the group environment, with high number densities and low velocity dispersions that likely affect member galaxy evolution. To explore the impact of this environment in detail, we examine the distribution in the mid-infrared (MIR) 3.6-8.0 μm color space of 42 galaxies from 12 Hickson compact groups (HCGs) in comparison with several control samples, including the LVL+SINGS galaxies, interacting galaxies, and galaxies from the Coma Cluster. We find that the HCG galaxies are strongly bimodal, with statistically significant evidence for a gap in their distribution. In contrast, none of the other samples show such a marked gap, and only galaxies in the Coma infall region have a distribution that is statistically consistent with the HCGs in this parameter space. To further investigate the cause of the HCG gap, we compare the galaxy morphologies of the HCG and LVL+SINGS galaxies, and also probe the specific star formation rate (SSFR) of the HCG galaxies. While galaxy morphology in HCG galaxies is strongly linked to position with MIR color space, the more fundamental property appears to be the SSFR, or star formation rate normalized by stellar mass. We conclude that the unusual MIR color distribution of HCG galaxies is a direct product of their environment, which is most similar to that of the Coma infall region. In both cases, galaxy densities are high, but gas has not been fully processed or stripped. We speculate that the compact group environment fosters accelerated evolution of galaxies from star-forming and neutral gas-rich to quiescent and neutral gas-poor, leaving few members in the MIR gap at any time.

THE MID-INFRARED EXTINCTION LAW IN THE LARGE MAGELLANIC CLOUD

International Nuclear Information System (INIS)

Gao, Jian; Jiang, B. W.; Xue, M. Y.; Li, Aigen

2013-01-01

Based on photometric data from the Spitzer/SAGE survey, using red giants as extinction tracers, the mid-infrared (MIR) extinction laws in the Large Magellanic Cloud (LMC) are derived for the first time in the form of A λ /A K S . This quantity refers to the extinction in the four Infrared Array Camera (IRAC) bands (i.e., [3.6], [4.5], [5.8], and [8.0] μm) relative to the Two Micron All Sky Survey K S band at 2.16 μm. We obtain the near-infrared extinction coefficient to be E(J – H)/E(H – K S ) ≈ 1.29 ± 0.04 and E(J – K S )/E(H – K S ) ≈ 1.94 ± 0.04. The wavelength dependence of the MIR extinction A λ /A K S in the LMC varies from one sightline to another. The overall mean MIR extinction is A [3.6] /A K S ∼0.72±0.03, A [4.5] /A K S ∼0.94±0.03, A [5.8] /A K S ∼0.58±0.04, and A [8.0] /A K S ∼0.62±0.05. Except for the extinction in the IRAC [4.5] μm band, which may be contaminated by the 4.6 μm CO gas absorption of red giants used to trace LMC extinction, the extinction in the other three IRAC bands show a flat curve, close to the Milky Way R V = 5.5 model extinction curve, where R V is the optical total-to-selective extinction ratio. The possible systematic bias caused by the correlated uncertainties of K S – λ and J – K S is explored in terms of Monte Carlo simulations. We find that this bias could lead to an overestimation of A λ /A K S in the MIR

A high-resolution atlas of the infrared spectrum of the Sun and the Earth atmosphere from space. Volume 3: Key to identification of solar features

Science.gov (United States)

Geller, Murray

1992-01-01

During the period April 29 through May 2, 1985, the Atmospheric Trace Molecule Spectroscopy (ATMOS) experiment was operated as part of the Spacelab-3 (SL-3) payload on the shuttle Challenger. The instrument, a Fourier transform spectrometer, recorded over 2000 infrared solar spectra from an altitude of 360 km. Although the majority of the spectra were taken through the limb of the Earth's atmosphere in order to better understand its composition, several hundred of the 'high-sun' spectra were completely free from telluric absorption. These high-sun spectra recorded from space are, at the present time, the only high-resolution infrared spectra ever taken of the Sun free from absorptions due to constituents in the Earth's atmosphere. Volumes 1 and 2 of this series provide a compilation of these spectra arranged in a format suitable for quick-look reference purposes and are the first record of the continuous high-resolution infrared spectrum of the Sun and the Earth's atmosphere from space. In the Table of Identifications, which constitutes the main body of this volume, each block of eight wavenumbers is given a separate heading and corresponds to a page of two panels in Volume 1 of this series. In addition, three separate blocks of data available from ATMOS from 622-630 cm(exp -1), 630-638 cm(exp -1) and 638-646 cm(exp -1), excluded from Volume 1 because of the low signal-to-noise ratio, have been included due to the certain identification of several OH and NH transitions. In the first column of the table, the corrected frequency is given. The second column identifies the molecular species. The third and fourth columns represent the assigned transition. The fifth column gives the depth of the molecular line in millimeters. Also included in this column is a notation to indicate whether the line is a blend or lies on the shoulder(s) of another line(s). The final column repeats a question mark if the line is unidentified.

Dual-channel operation in a synchronously pumped optical parametric oscillator for the generation of broadband mid-infrared coherent light sources.

Science.gov (United States)

Liu, Pei; Wang, Sicong; He, Puyuan; Zhang, Zhaowei

2018-05-01

We report, to the best of our knowledge, a novel approach for generating broadband mid-infrared (mid-IR) light by implementing a dual-channel scheme in a synchronously pumped optical parametric oscillator (SPOPO). Two-channel operation was achieved by inserting a prism pair and two reflection mirrors inside an optical parametric oscillator (OPO) cavity. Pumped by a Yb-fiber laser, the OPO generated an idler wave at ∼3150  nm with a -10  dB bandwidth of ∼13.2  THz, which was twice as much as that of the pump source. This scheme represents a promising technical route to transform conventional SPOPOs into a device capable of generating mid-IR light with very broad instantaneous bandwidth.

Characterization of a ZnxCd1-xSe/Znx'Cdy'Mg1-x'-y'Se multiple quantum well structure for mid-infrared device applications by contactless electroreflectance and Fourier transform infrared spectroscopy

International Nuclear Information System (INIS)

Wu, J D; Lin, J W; Huang, Y S; Charles, W O; Shen, A; Zhang, Q; Tamargo, M C

2009-01-01

Contactless electroreflectance (CER) and Fourier transform infrared (FTIR) spectroscopy were used to study the intersubband transitions of a Zn x Cd 1-x Se/Zn x' Cd y' Mg 1-x'-y' Se multiple quantum well (MQW) structure grown by molecular beam epitaxy for mid-infrared device applications. The CER spectrum revealed a wide range of possible optical transitions in the MQW structure. The ground state transition was assigned by comparison with the photoluminescence emission signal taken from the same structure. A comprehensive analysis of the CER spectrum led to the identification of various interband transitions. The intersubband transitions were estimated and confirmed by FTIR measurements. The results demonstrate the potential of using CER as a complementary technique for the contactless and nondestructive characterization of the wide band gap II-VI MQW structures for mid-IR intersubband device applications.

Influence of composition and roughness on the pigment mapping of paintings using mid-infrared fiberoptics reflectance spectroscopy (mid-IR FORS) and multivariate calibration.

Science.gov (United States)

Sessa, Clarimma; Bagán, Héctor; García, Jose Francisco

2014-10-01

Mid-infrared fiberoptics reflectance spectroscopy (mid-IR FORS) is a very interesting technique for artwork characterization purposes. However, the fact that the spectra obtained are a mixture of surface (specular) and volume (diffuse) reflection is a significant drawback. The physical and chemical features of the artwork surface may produce distortions in the spectra that hinder comparison with reference databases acquired in transmission mode. Several studies attempted to understand the influence of the different variables and propose procedures to improve the interpretation of the spectra. This article is focused on the application of mid-IR FORS and multivariate calibration to the analysis of easel paintings. The objectives are the evaluation of the influence of the surface roughness on the spectra, the influence of the matrix composition for the classification of unknown spectra, and the capability of obtaining pigment composition mappings. A first evaluation of a fast procedure for spectra management and pigment discrimination is discussed. The results demonstrate the capability of multivariate methods, principal component analysis (PCA), and partial least squares discrimination analysis (PLS-DA), to model the distortions of the reflectance spectra and to delimitate and discriminate areas of uniform composition. The roughness of the painting surface is found to be an important factor affecting the shape and relative intensity of the spectra. A mapping of the major pigments of a painting is possible using mid-IR FORS and PLS-DA when the calibration set is a palette that includes the potential pigments present in the artwork mixed with the appropriate binder and that shows the different paint textures.

Real-Time and Label-Free Chemical Sensor-on-a-chip using Monolithic Si-on-BaTiO3 Mid-Infrared waveguides.

Science.gov (United States)

Jin, Tiening; Li, Leigang; Zhang, Bruce; Lin, Hao-Yu Greg; Wang, Haiyan; Lin, Pao Tai

2017-07-19

Chip-scale chemical detection is demonstrated by using mid-Infrared (mid-IR) photonic circuits consisting of amorphous silicon (a-Si) waveguides on an epitaxial barium titanate (BaTiO 3 , BTO) thin film. The highly c-axis oriented BTO film was grown by the pulsed laser deposition (PLD) method and it exhibits a broad transparent window from λ = 2.5 μm up to 7 μm. The waveguide structure was fabricated by the complementary metal-oxide-semiconductor (CMOS) process and a sharp fundamental waveguide mode has been observed. By scanning the spectrum within the characteristic absorption regime, our mid-IR waveguide successfully perform label-free monitoring of various organic solvents. The real-time heptane detection is accomplished by measuring the intensity attenuation at λ = 3.0-3.2 μm, which is associated with -CH absorption. While for methanol detection, we track the -OH absorption at λ = 2.8-2.9 μm. Our monolithic Si-on-BTO waveguides establish a new sensor platform that enables integrated photonic device for label-free chemical detection.

Spectroscopic Characterisation of CARMENES Target Candidates from FEROS, CAFE and HRS High-Resolution Spectra

Science.gov (United States)

Passegger, Vera Maria; Reiners, Ansgar; Jeffers, Sandra V.; Wende, Sebastian; Schöfer, Patrick; Amado, Pedro J.; Caballero, Jose A.; Montes, David; Mundt, Reinhard; Ribas, Ignasi; Quirrenbach, Andreas

2016-07-01

CARMENES (Calar Alto high-Resolution search for M dwarfs with Exoearths with Near-infrared and optical Échelle Spectrographs) started a new planet survey on M-dwarfs in January this year. The new high-resolution spectrographs are operating in the visible and near-infrared at Calar Alto Observatory. They will perform high-accuracy radial-velocity measurements (goal 1 m s-1) of about 300 M-dwarfs with the aim to detect low-mass planets within habitable zones. We characterised the candidate sample for CARMENES and provide fundamental parameters for these stars in order to constrain planetary properties and understand star-planet systems. Using state-of-the-art model atmospheres (PHOENIX-ACES) and χ2-minimization with a downhill-simplex method we determine effective temperature, surface gravity and metallicity [Fe/H] for high-resolution spectra of around 480 stars of spectral types M0.0-6.5V taken with FEROS, CAFE and HRS. We find good agreement between the models and our observed high-resolution spectra. We show the performance of the algorithm, as well as results, parameter and spectral type distributions for the CARMENES candidate sample, which is used to define the CARMENES target sample. We also present first preliminary results obtained from CARMENES spectra.

Continuously tunable monomode mid-infrared vertical external cavity surface emitting laser on Si

Science.gov (United States)

Khiar, A.; Rahim, M.; Fill, M.; Felder, F.; Hobrecker, F.; Zogg, H.

2010-10-01

A tunable PbTe based mid-infrared vertical external cavity surface emitting laser is described. The active part is a ˜1 μm thick PbTe layer grown epitaxially on a Bragg mirror on the Si-substrate. The cavity is terminated with a curved Si/SiO Bragg top mirror and pumped optically with a 1.55 μm laser. Cavity length is <100 μm in order that only one longitudinal mode is supported. By changing the cavity length, up to 5% wavelength continuous and mode-hop free tuning is achieved at fixed temperature. The total tuning extends from 5.6 to 4.7 μm at 100-170 K operation temperature.

High-Resolution Infrared Spectroscopic Measurements of Comet 2PlEncke: Unusual Organic Composition and Low Rotational Temperatures

Science.gov (United States)

Radeva, Yana L.; Mumma, Michael J.; Villanueva, Geronimo L.; Bonev, Boncho P.; DiSanti, Michael A.; A'Hearn, Michael F.; Dello Russo, Neil

2013-01-01

We present high-resolution infrared spectroscopic measurements of the ecliptic comet 2P/Encke, observed on 4-6 Nov. 2003 during its close approach to the Earth, using the Near Infrared Echelle Spectrograph on the Keck II telescope. We present flux-calibrated spectra, production rates, and mixing ratios for H2O, CH3OH, HCN, H2CO, C2H2, C2H6, CH4 and CO. Comet 2P/Encke is a dynamical end-member among comets because of its short period of 3.3 years. Relative to "organics-normal" comets, we determined that 2PlEncke is depleted in HCN, H2CO, C2H2, C2H6, CH4 and CO, but it is enriched in CH3OH. We compared mixing ratios of these organic species measured on separate dates, and we see no evidence of macroscopic chemical heterogeneity in the nucleus of 2P/Encke, however, this conclusion is limited by sparse temporal sampling. The depleted abundances of most measured species suggest that 2P/Encke may have formed closer to the young Sun, before its insertion to the Kuiper belt, compared with "organics-normal" comets - as was previously suggested for other depleted comets (e.g. C/1999 S4 (LINEAR)). We measured very low rotational temperatures of 20 - 30 K for H2O, CH3OH and HCN in the near nucleus region of 2P/Encke, which correlate with one of the lowest cometary gas production rates (approx. 2.6 x 10(exp 27) molecules/s) measured thus far in the infrared. This suggests that we are seeing the effects of more efficient radiative cooling, insufficient collisional excitation, and/or inefficient heating by fast H-atoms (and icy grains) in the observed region of the coma. Its extremely short orbital period, very low gas production rate, and classification as an ecliptic comet, make 2PlEncke an important addition to our growing database, and contribute significantly to the establishment of a chemical taxonomy of comets.

Exploring the mid-infrared region for urban remote sensing: seasonal and view angle effects

Science.gov (United States)

Krehbiel, C. P.; Kovalskyy, V.; Henebry, G. M.

2013-12-01

Spanning 3-5 microns, the mid-infrared (MIR) region is the mixing zone between reflected sunlight and emitted earthlight in roughly equal proportions. While the MIR has been utilized in atmospheric remote sensing, its potential in terrestrial remote sensing--particularly urban remote sensing, has yet to be realized. One major advantage of the MIR is the ability to penetrate most anthropogenic haze and smog. Green vegetation appears MIR-dark, urban building materials appear MIR-grey, and bare soil and dried vegetation appear MIR-bright. Thus, there is an intrinsic seasonality in MIR radiance dynamics due both to surface type differences and to seasonal change in insolation. These factors merit exploration into the potential applications of the MIR for monitoring urban change. We investigated MIR radiance dynamics in relation to (1) the spectral properties of land cover types, (2) time of year and (3) sensor view zenith angle (VZA). We used Aqua MODIS daily swaths for band 23 (~ 4.05 μm) at 1 km spatial resolution from 2009-2010 and the NLCD Percent Impervious Surface Area (%ISA) 30 m product from 2001 and 2006. We found the effects of time of year, sensor VZA, and %ISA to be three principal factors influencing MIR radiance dynamics. We focused on analyzing the relationship between MIR radiance and %ISA over eight major cities in the Great Plains of the USA. This region is characterized by four distinct seasons, relatively flat terrain, and isolated urban centers situated within a vegetated landscape. We used west-east transects beginning in the agricultural areas outside of each city, passing through the urban core and extending back out into the agricultural periphery to observe the spatial pattern of MIR radiance and how it changes seasonally. Sensor VZA influences radiance dynamics by affecting the proportion of surface elements detected--especially pertinent at the coarse spatial resolution (~1 km) of MODIS. For example, smaller VZAs (30°). Larger VZAs detect