Sub-chronic inhalation of high concentrations of manganese sulfate induces lower airway pathology in rhesus monkeys

Directory of Open Access Journals (Sweden)

Wong Brian A

2005-10-01

Full Text Available Abstract Background Neurotoxicity and pulmonary dysfunction are well-recognized problems associated with prolonged human exposure to high concentrations of airborne manganese. Surprisingly, histological characterization of pulmonary responses induced by manganese remains incomplete. The primary objective of this study was to characterize histologic changes in the monkey respiratory tract following manganese inhalation. Methods Subchronic (6 hr/day, 5 days/week inhalation exposure of young male rhesus monkeys to manganese sulfate was performed. One cohort of monkeys (n = 4–6 animals/exposure concentration was exposed to air or manganese sulfate at 0.06, 0.3, or 1.5 mg Mn/m3 for 65 exposure days. Another eight monkeys were exposed to manganese sulfate at 1.5 mg Mn/m3 for 65 exposure days and held for 45 or 90 days before evaluation. A second cohort (n = 4 monkeys per time point was exposed to manganese sulfate at 1.5 mg Mn/m3 and evaluated after 15 or 33 exposure days. Evaluations included measurement of lung manganese concentrations and evaluation of respiratory histologic changes. Tissue manganese concentrations were compared for the exposure and control groups by tests for homogeneity of variance, analysis of variance, followed by Dunnett's multiple comparison. Histopathological findings were evaluated using a Pearson's Chi-Square test. Results Animals exposed to manganese sulfate at ≥0.3 mg Mn/m3 for 65 days had increased lung manganese concentrations. Exposure to manganese sulfate at 1.5 mg Mn/m3 for ≥15 exposure days resulted in increased lung manganese concentrations, mild subacute bronchiolitis, alveolar duct inflammation, and proliferation of bronchus-associated lymphoid tissue. Bronchiolitis and alveolar duct inflammatory changes were absent 45 days post-exposure, suggesting that these lesions are reversible upon cessation of subchronic high-dose manganese exposure. Conclusion High-dose subchronic manganese sulfate inhalation is

Highly Conductive One-Dimensional Manganese Oxide Wires by Coating with Graphene Oxides

Science.gov (United States)

Tojo, Tomohiro; Shinohara, Masaki; Fujisawa, Kazunori; Muramatsu, Hiroyuki; Hayashi, Takuya; Ahm Kim, Yoong; Endo, Morinobu

2012-10-01

Through coating with graphene oxides, we have developed a chemical route to the bulk production of long, thin manganese oxide (MnO2) nanowires that have high electrical conductivity. The average diameter of these hybrid nanowires is about 25 nm, and their average length is about 800 nm. The high electrical conductivity of these nanowires (ca. 189.51+/-4.51 µS) is ascribed to the homogeneous coating with conductive graphene oxides as well as the presence of non-bonding manganese atoms. The growth mechanism of the nanowires is theoretically supported by the initiation of morphological conversion from graphene oxide to wrapped structures through the formation of covalent bonds between manganese and oxygen atoms at the graphene oxide edge.

The influence of deep cryogenic treatment on the properties of high-vanadium alloy steel

Energy Technology Data Exchange (ETDEWEB)

Li, Haizhi [Key Laboratory of Electromagnetic Processing of Materials (Ministry of Education), Northeastern University, Shenyang 110819 (China); Tong, Weiping, E-mail: wptong@mail.neu.edu.cn [Key Laboratory of Electromagnetic Processing of Materials (Ministry of Education), Northeastern University, Shenyang 110819 (China); Cui, Junjun [State Key Laboratory of Rolling and Automation, Northeastern University, Shenyang 110819 (China); Zhang, Hui [Key Laboratory of Electromagnetic Processing of Materials (Ministry of Education), Northeastern University, Shenyang 110819 (China); Chen, Liqing [State Key Laboratory of Rolling and Automation, Northeastern University, Shenyang 110819 (China); Zuo, Liang [Key Laboratory for Anisotropy and Texture of Materials (Ministry of Education), School of Materials and Metallurgy, Northeastern University, Shenyang 110819 (China)

2016-04-26

Deep cryogenic treatment can improve the mechanical properties of many metallic materials, but there are few reports of the effect of deep cryogenic treatment on high-vanadium alloy steel. The main objective of this work is to investigate the effect of deep cryogenic treatment on the microstructure, hardness, impact toughness and abrasive wear resistance of high-vanadium alloy steel. The results show that large amounts of small secondary carbide precipitation after deep cryogenic treatment and microcracks were detected and occurred preferentially at carbide/matrix interfaces; except for the hardness, the mechanical properties increased compared to those of the conventional treatment sample. By increasing the deep cryogenic processing time and cycle number, impact toughness and abrasive wear resistance can be further improved, the carbide contents continuously increase, and the hardness decreases.

Cryogenics Vision Workshop for High-Temperature Superconducting Electric Power Systems Proceedings

International Nuclear Information System (INIS)

Energetics, Inc.

2000-01-01

The US Department of Energy's Superconductivity Program for Electric Systems sponsored the Cryogenics Vision Workshop, which was held on July 27, 1999 in Washington, D.C. This workshop was held in conjunction with the Program's Annual Peer Review meeting. Of the 175 people attending the peer review meeting, 31 were selected in advance to participate in the Cryogenics Vision Workshops discussions. The participants represented cryogenic equipment manufactures, industrial gas manufacturers and distributors, component suppliers, electric power equipment manufacturers (Superconductivity Partnership Initiative participants), electric utilities, federal agencies, national laboratories, and consulting firms. Critical factors were discussed that need to be considered in describing the successful future commercialization of cryogenic systems. Such systems will enable the widespread deployment of high-temperature superconducting (HTS) electric power equipment. Potential research, development, and demonstration (RD and D) activities and partnership opportunities for advancing suitable cryogenic systems were also discussed. The workshop agenda can be found in the following section of this report. Facilitated sessions were held to discuss the following specific focus topics: identifying Critical Factors that need to be included in a Cryogenics Vision for HTS Electric Power Systems (From the HTS equipment end-user perspective) identifying R and D Needs and Partnership Roles (From the cryogenic industry perspective) The findings of the facilitated Cryogenics Vision Workshop were then presented in a plenary session of the Annual Peer Review Meeting. Approximately 120 attendees participated in the afternoon plenary session. This large group heard summary reports from the workshop session leaders and then held a wrap-up session to discuss the findings, cross-cutting themes, and next steps. These summary reports are presented in this document. The ideas and suggestions raised during

Cryogenic Beam Screens for High-Energy Particle Accelerators

CERN Document Server

Baglin, V; Tavian, L; van Weelderen, R

2013-01-01

Applied superconductivity has become a key enabling technology for high-energy particle accelerators, thus making them large helium cryogenic systems operating at very low temperature. The circulation of high-intensity particle beams in these machines generates energy deposition in the first wall through different processes. For thermodynamic efficiency, it is advisable to intercept these beam-induced heat loads, which may be large in comparison with cryostat heat in-leaks, at higher temperature than that of the superconducting magnets of the accelerator, by means of beam screens located in the magnet apertures. Beam screens may also be used as part of the ultra-high vacuum system of the accelerator, by sheltering the gas molecules cryopumped on the beam pipe from impinging radiation and thus avoiding pressure runaway. Space being extremely tight in the magnet apertures, cooling of the long, slender beam screens also raises substantial problems in cryogenic heat transfer and fluid flow. We present sizing rule...

Synthesis of manganese stearate for high density polyethylene (HDPE) and its biodegradation

Science.gov (United States)

Aras, Neny Rasnyanti M.; Arcana, I. Made

2015-09-01

An oxidant additive is one type of additive used for oxo-biodegradable polymers. This additive was prepared by reaction multivalent transition metals and fatty acids to accelerate the degradation process of polymers by providing a thermal treatment or irradiation with light. This study focused on the synthesis of manganese stearate as an additive for application in High Density Polyethylene (HDPE), and the influence of manganese stearate on the characteristics of HDPE including their biodegradability. Manganese stearate was synthesized by the reaction of stearic acid with sodium hydroxide, and sodium stearate formed was reacted with manganese chloride tetrahydrate to form manganese stearate with a melting point of 100-110 °C. Based on the FTIR spectrum showed absorption peak at wave number around 1560 cm-1 which is an asymmetric vibration of CO functional group that binds to the manganese. The films of oxo-biodegradable polymer were prepared by blending HDPE and manganese stearate additives at various concentrations with using the polymer melting method, followed heating at a temperature of 50°C and 70°C for 10 days. The characterizations of the oxo-biodegradable polymers were carried out by analysis the functional groups (FTIR and ATR),thermal properties (TGA), surface properties (SEM), as well as analysis of the biodegradability (the biodegradation test by using activated sludge, % weight loss). Based on COi indicate that the additive of manganese stearate is active in oxidizing polymer by heating treatment. Results of biodegradation by microorganisms from activated sludge showed that the percentage weight loss of polymers increase with the increasing incubation time and the concentration of manganese stearate in HDPE. Biodegradability of HDPE with the addition of manganese stearate and followed by heating at a higher temperature was better observed. The highest percentage weight loss was obtained at the polymer with concentration of 0.2% manganese stearate

Synthesis of manganese stearate for high density polyethylene (HDPE) and its biodegradation

Energy Technology Data Exchange (ETDEWEB)

Aras, Neny Rasnyanti M., E-mail: neny.rasnyanti@gmail.com; Arcana, I Made, E-mail: arcana@chem.itb.ac.id [Inorganic and Physical Chemistry Research Division, Faculty of Mathematics and Natural Sciences, Institut Teknologi Bandung, Jalan Ganesha 10, Bandung 40132 (Indonesia)

2015-09-30

An oxidant additive is one type of additive used for oxo-biodegradable polymers. This additive was prepared by reaction multivalent transition metals and fatty acids to accelerate the degradation process of polymers by providing a thermal treatment or irradiation with light. This study focused on the synthesis of manganese stearate as an additive for application in High Density Polyethylene (HDPE), and the influence of manganese stearate on the characteristics of HDPE including their biodegradability. Manganese stearate was synthesized by the reaction of stearic acid with sodium hydroxide, and sodium stearate formed was reacted with manganese chloride tetrahydrate to form manganese stearate with a melting point of 100-110 °C. Based on the FTIR spectrum showed absorption peak at wave number around 1560 cm{sup −1} which is an asymmetric vibration of CO functional group that binds to the manganese. The films of oxo-biodegradable polymer were prepared by blending HDPE and manganese stearate additives at various concentrations with using the polymer melting method, followed heating at a temperature of 50°C and 70°C for 10 days. The characterizations of the oxo-biodegradable polymers were carried out by analysis the functional groups (FTIR and ATR),thermal properties (TGA), surface properties (SEM), as well as analysis of the biodegradability (the biodegradation test by using activated sludge, % weight loss). Based on COi indicate that the additive of manganese stearate is active in oxidizing polymer by heating treatment. Results of biodegradation by microorganisms from activated sludge showed that the percentage weight loss of polymers increase with the increasing incubation time and the concentration of manganese stearate in HDPE. Biodegradability of HDPE with the addition of manganese stearate and followed by heating at a higher temperature was better observed. The highest percentage weight loss was obtained at the polymer with concentration of 0.2% manganese

Synthesis of manganese stearate for high density polyethylene (HDPE) and its biodegradation

International Nuclear Information System (INIS)

Aras, Neny Rasnyanti M.; Arcana, I Made

2015-01-01

An oxidant additive is one type of additive used for oxo-biodegradable polymers. This additive was prepared by reaction multivalent transition metals and fatty acids to accelerate the degradation process of polymers by providing a thermal treatment or irradiation with light. This study focused on the synthesis of manganese stearate as an additive for application in High Density Polyethylene (HDPE), and the influence of manganese stearate on the characteristics of HDPE including their biodegradability. Manganese stearate was synthesized by the reaction of stearic acid with sodium hydroxide, and sodium stearate formed was reacted with manganese chloride tetrahydrate to form manganese stearate with a melting point of 100-110 °C. Based on the FTIR spectrum showed absorption peak at wave number around 1560 cm −1 which is an asymmetric vibration of CO functional group that binds to the manganese. The films of oxo-biodegradable polymer were prepared by blending HDPE and manganese stearate additives at various concentrations with using the polymer melting method, followed heating at a temperature of 50°C and 70°C for 10 days. The characterizations of the oxo-biodegradable polymers were carried out by analysis the functional groups (FTIR and ATR),thermal properties (TGA), surface properties (SEM), as well as analysis of the biodegradability (the biodegradation test by using activated sludge, % weight loss). Based on COi indicate that the additive of manganese stearate is active in oxidizing polymer by heating treatment. Results of biodegradation by microorganisms from activated sludge showed that the percentage weight loss of polymers increase with the increasing incubation time and the concentration of manganese stearate in HDPE. Biodegradability of HDPE with the addition of manganese stearate and followed by heating at a higher temperature was better observed. The highest percentage weight loss was obtained at the polymer with concentration of 0.2% manganese

Recovery of manganese from manganese oxide ores in the EDTA solution

Science.gov (United States)

Zhang, Chao; Wang, Shuai; Cao, Zhan-fang; Zhong, Hong

2018-04-01

A new process has been experimentally and theoretically established for the recovery of manganese from manganese oxide ores, mainly including the reductive leaching of manganese by ethylenediaminetetraacetic acid (EDTA), EDTA recovery, and manganese electrolysis. The experimental conditions for this process were investigated. Moderate leaching environment by EDTA with the pH in the range of 5-6 is of benefit to leach manganese from some manganese oxide ores with high-content impurities, such as iron and aluminum. Most of EDTA can be recovered by acidification. A small amount of the residual EDTA in the electrolyte can prevent the generation of anode mud. In addition, trimanganese tetroxide (Mn3O4) can be obtained by the roasting of the EDTA-Mn crystallized product.

High Effectiveness Heat Exchanger for Cryogenic Refrigerators, Phase I

Data.gov (United States)

National Aeronautics and Space Administration — We propose an innovative high performance cryogenic heat exchanger manufactured of titanium by photo-etching and diffusion bonding. This is a parallel plate design...

HDM model magnet mechanical behavior with high manganese steel collars

International Nuclear Information System (INIS)

Snyder, J.R.

1994-01-01

Westinghouse Electric Corporation (WEC) is presently under contract to the SSCL to design, develop, fabricate, and deliver superconducting dipole magnets for the High Energy Booster (HEB). As a first step toward these objectives SSCL supplied a design for short model magnets of 1.8 m in length (DSB). This design was used as a developmental tool for all phases of engineering and fabrication. Mechanical analysis of the HDM (High Energy Booster Dipole Magnets) model magnet design as specified by SSCL was performed with the following objectives: (1) to develop a thorough understanding of the design; (2) to review and verify through analytical and numerical analyses the SSCL model magnet design; (3) to identify any deficiencies that would violate design parameters specified in the HDM Design Requirements Document. A detailed analysis of the model magnet mechanical behavior was pursued by constructing a quarter section finite element model and solving with the ANSYS finite element code. Collar materials of Nitronic-40 and High-Manganese steel were both considered for the HEB model magnet program with the High-Manganese being the final selection. The primary mechanical difference in the two materials is the much lower thermal contraction of the High-Manganese steel. With this material the collars will contract less than the enclosing yoke producing an increased collar yoke interference during cooldown

Cryogenics for high-energy particle accelerators: highlights from the first fifty years

CERN Document Server

AUTHOR|(CDS)2067931

2017-01-01

Applied superconductivity has become a key technology for high-energy particle accelerators, allowing to reach higher beam energy while containing size, capital expenditure and operating costs. Large and powerful cryogenic systems are therefore ancillary to low-temperature superconducting accelerator devices – magnets and high-frequency cavities – distributed over multi-kilometre distances and operating generally close to the normal boiling point of helium, but also above 4.2 K in supercritical and down to below 2 K in superfluid. Additionally, low-temperature operation in accelerators may also be required by considerations of ultra-high vacuum, limited stored energy and beam stability. We discuss the rationale for cryogenics in high-energy particle accelerators, review its development over the past half-century and present its outlook in future large projects, with reference to the main engineering domains of cryostat design and heat loads, cooling schemes, efficient power refrigeration and cryogenic flu...

High-Speed Thermal Characterization of Cryogenic Flows, Phase II

Data.gov (United States)

National Aeronautics and Space Administration — Luna proposes to continue development on a high-speed fiber optic sensor and readout system for cryogenic temperature measurements in liquid oxygen (LOX) and liquid...

A Cryogenic High-Reynolds Turbulence Experiment at CERN

CERN Document Server

Bézaguet, Alain-Arthur; Knoops, S; Lebrun, P; Pezzetti, M; Pirotte, O; Bret, J L; Chabaud, B; Garde, G; Guttin, C; Hébral, B; Pietropinto, S; Roche, P; Barbier-Neyret, J P; Baudet, C; Gagne, Y; Poulain, C; Castaing, B; Ladam, Y; Vittoz, F

2002-01-01

The potential of cryogenic helium flows for studying high-Reynolds number turbulence in the laboratory has been recognised for a long time and implemented in several small-scale hydrodynamic experiments. With its large superconducting particle accelerators and detector magnets, CERN, the European Laboratory for Particle Physics, has become a major world center in helium cryogenics, with several large helium refrigerators having capacities up to 18 kW @ 4.5 K. Combining a small fraction of these resources with the expertise of three laboratories at the forefront of turbulence research, has led to the design, swift implementation, and successful operation of GReC (Grands Reynolds Cryogéniques) a large axisymmetric turbulent-jet experiment. With flow-rates up to 260 g/s of gaseous helium at ~ 5 K and atmospheric pressure, Reynolds numbers up to 107 have been achieved in a 4.6 m high, 1.4 m diameter cryostat. This paper presents the results of the first runs and describes the experimental set-up comprehensively ...

Fabrication of ultrafine manganese oxide-decorated carbon nanofibers for high-performance electrochemical capacitors

Energy Technology Data Exchange (ETDEWEB)

Yang, Ying; Lee, Sungsik; Brown, Dennis E.; Zhao, Hairui; Li, Xinsong; Jiang, Daqiang; Hao, Shijie; Zhao, Yongxiang; Cong, Daoyong; Zhang, Xin; Ren, Yang

2016-09-01

Ultrafine manganese oxide-decorated carbon nanofibers (MnOn-CNF) as a new type of electrode materials are facilely fabricated by direct conversion of Mn, Zn-trimesic acid (H3BTC) metal organic framework fibers (Mn-ZnBTC). The construction and evolution of Mn-ZnBTC precursors are investigated by SEM and in situ high-energy XRD. The manganese oxides are highly dispersed onto the porous carbon nanofibers formed simultaneously, verified by TEM, X-ray absorption fine structure (XAFS), Raman, ICP-AES and N2 adsorption techniques. As expected, the resulting MnOn-CNF composites are highly stable, and can be cycled up to 5000 times with a high capacitance retention ratio of 98% in electrochemical capacitor measurements. They show a high capacitance of up to 179 F g–1 per mass of the composite electrode, and a remarkable capacitance of up to 18290 F g–1 per active mass of the manganese(IV) oxide, significantly exceeding the theoretical specific capacitance of manganese(IV) oxide (1370 F g–1). The maximum energy density is up to 19.7 Wh kg–1 at the current density of 0.25 A g–1, even orders higher than those of reported electric double-layer capacitors and pseudocapacitors. The excellent capacitive performance can be ascribed to the joint effect of easy accessibility, high porosity, tight contact and superior conductivity integrated in final MnOn-CNF composites.

Leaching of manganese from electrolytic manganese residue by electro-reduction.

Science.gov (United States)

Shu, Jiancheng; Liu, Renlong; Liu, Zuohua; Chen, Hongliang; Tao, Changyuan

2017-08-01

In this study, an improved process for leaching manganese from electrolytic manganese residue (EMR) by electro-reduction was developed. The mechanisms of the electro-reduction leaching were investigated through X-ray diffraction, scanning electron microscopy, X-ray fluorescence, and Brunauer Emmett Teller. The results show that the electric field could change the surface charge distribution of EMR particles, and the high-valent manganese can be reduced by electric field. The leaching efficient of manganese reached 84.1% under the optimal leaching condition: 9.2 wt% H 2 SO 4 , current density of 25 mA/cm 2 , solid-to-liquid ratio of 1:5, and leaching time for 1 h. It is 37.9% higher than that attained without an electric field. Meanwhile, the manganese content in EMR decreased from 2.57% to 0.48%.

Three manganese oxide-rich marine sediments harbor similar communities of acetate-oxidizing manganese-reducing bacteria

OpenAIRE

Vandieken, Verona; Pester, Michael; Finke, Niko; Hyun, Jung-Ho; Friedrich, Michael W; Loy, Alexander; Thamdrup, Bo

2012-01-01

Dissimilatory manganese reduction dominates anaerobic carbon oxidation in marine sediments with high manganese oxide concentrations, but the microorganisms responsible for this process are largely unknown. In this study, the acetate-utilizing manganese-reducing microbiota in geographically well-separated, manganese oxide-rich sediments from Gullmar Fjord (Sweden), Skagerrak (Norway) and Ulleung Basin (Korea) were analyzed by 16S rRNA-stable isotope probing (SIP). Manganese reduction was the p...

Nanostructured manganese oxides as highly active water oxidation catalysts: a boost from manganese precursor chemistry.

Science.gov (United States)

Menezes, Prashanth W; Indra, Arindam; Littlewood, Patrick; Schwarze, Michael; Göbel, Caren; Schomäcker, Reinhard; Driess, Matthias

2014-08-01

We present a facile synthesis of bioinspired manganese oxides for chemical and photocatalytic water oxidation, starting from a reliable and versatile manganese(II) oxalate single-source precursor (SSP) accessible through an inverse micellar molecular approach. Strikingly, thermal decomposition of the latter precursor in various environments (air, nitrogen, and vacuum) led to the three different mineral phases of bixbyite (Mn2 O3 ), hausmannite (Mn3 O4 ), and manganosite (MnO). Initial chemical water oxidation experiments using ceric ammonium nitrate (CAN) gave the maximum catalytic activity for Mn2 O3 and MnO whereas Mn3 O4 had a limited activity. The substantial increase in the catalytic activity of MnO in chemical water oxidation was demonstrated by the fact that a phase transformation occurs at the surface from nanocrystalline MnO into an amorphous MnOx (1manganese oxides including the newly formed amorphous MnOx . Both Mn2 O3 and the amorphous MnOx exhibit tremendous enhancement in oxygen evolution during photocatalysis and are much higher in comparison to so far known bioinspired manganese oxides and calcium-manganese oxides. Also, for the first time, a new approach for the representation of activities of water oxidation catalysts has been proposed by determining the amount of accessible manganese centers. © 2014 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

A Cryogenic High-Power-Density Bearingless Motor for Future Electric Propulsion

Science.gov (United States)

Choi, Benjamin; Siebert, Mark

2008-01-01

The NASA Glenn Research Center (GRC) is developing a high-power-density switched-reluctance cryogenic motor for all-electric and pollution-free flight. However, cryogenic operation at higher rotational speeds markedly shortens the life of mechanical rolling element bearings. Thus, to demonstrate the practical feasibility of using this motor for future flights, a non-contact rotor-bearing system is a crucial technology to circumvent poor bearing life that ordinarily accompanies cryogenic operation. In this paper, a bearingless motor control technology for a 12-8 (12 poles in the stator and 8 poles in the rotor) switched-reluctance motor operating in liquid nitrogen (boiling point, 77 K (-196 C or -321 F)) was presented. We pushed previous disciplinary limits of electromagnetic controller technique by extending the state-of-the-art bearingless motor operating at liquid nitrogen for high-specific-power applications. The motor was levitated even in its nonlinear region of magnetic saturation, which is believed to be a world first for the motor type. Also we used only motoring coils to generate motoring torque and levitation force, which is an important feature for developing a high specific power motor.

Cryogenic semiconductor high-intensity radiation monitors

International Nuclear Information System (INIS)

Palmieri, V.G.; Bell, W.H.; Borer, K.; Casagrande, L.; Da Via, C.; Devine, S.R.H.; Dezillie, B.; Esposito, A.; Granata, V.; Hauler, F.; Jungermann, L.; Li, Z.; Lourenco, C.; Niinikoski, T.O.; Shea, V. O'; Ruggiero, G.; Sonderegger, P.

2003-01-01

This paper describes a novel technique to monitor high-intensity particle beams by means of a semiconductor detector. It consists of cooling a semiconductor detector down to cryogenic temperature to suppress the thermally generated leakage current and to precisely measure the integrated ionization signal. It will be shown that such a device provides very good linearity and a dynamic range wider than is possible with existing techniques. Moreover, thanks to the Lazarus effect, extreme radiation hardness can be achieved providing in turn absolute intensity measurements against precise calibration of the device at low beam flux

Influence of cryogenic treatment on microstructure and mechanical properties of high strength AISI D2 tool steel =

Science.gov (United States)

Ghasemi Nanesa, Hadi

Cryogenic treatment, known as treating materials at sub-zero temperatures, has been added to conventional heat treatment cycle of high alloyed steels where martensitic transformation is incomplete after quenching to room temperature. Incomplete martensitic transformation occurs due to the effect of high content of alloying elements on pushing down martensite start and finish temperatures to very low values, specifically, on tool steels. In spite of obtaining significant improvements in mechanical and wear properties after cryogenic treatment, there is no cohesive picture about what exactly modifies the microstructure of tool steels during cryogenic treatment and therefore divergent opinions on the influence of process parameters are still reported. For example, the suggested time length for cryogenic treatment starts from few seconds to several days indicating the lack of understanding about micromechanisms responsible for microstructural evolution while holding at cryogenic temperatures. In this regard, the main objective of this project is to develop a better understanding on the fundamental micromechanisms operating during cryogenic treatment. To attain this objective, the following milestones are pursued. - To study the conventional cryogenic treatment and finding challenges. - To identify and characterize the optimum starting microstructure before cryogenic treatment. - To determine the important processing parameters those control the evolution of microstructure and hardness. - To investigate the interaction between carbide precipitation and martensitic transformation in the AISI D2 steel. - To propose an optimal cryogenic treatment for AISI D2 steel.

Comparison of tolerance to soil acidity among crop plants. II. Tolerance to high levels of aluminum and manganese. Comparative plant nutrition

Energy Technology Data Exchange (ETDEWEB)

Tanaka, A; Hayakawa, Y

1975-01-01

Research was conducted by growing various species of plants in solutions containing high concentrations of manganese or aluminum. A comparison was made of the tolerance of these plants to low pH and to the manganese and aluminum. In addition, the element content of the plants was compared. Plants high in calcium were found to have an intermediate tolerance to high concentrations of manganese and aluminum. Gramineae had a high tolerance to these elements and to low pH. They also accumulated high levels of these elements. Legumes had a high tolerance to manganese and aluminum and to low pH. However, they also accumulated high levels of these elements. Legumes had a high tolerance to manganese and aluminum and to low pH. However, they also accumulated high levels of these elements. Cruciferae had a low tolerance to the elements and to low pH. They contained low levels of manganese and aluminum. Chenopodiaceae had a low tolerance to the elements as well as low element contents. However, they were highly tolerant to low pH.

Manganese, Metallogenium, and Martian Microfossils

Science.gov (United States)

Stein, L. Y.; Nealson, K. H.

1999-01-01

Manganese could easily be considered an abundant element in the Martian regolith, assuming that the composition of martian meteorites reflects the composition of the planet. Mineralogical analyses of 5 SNC meteorites have revealed an average manganese oxide concentration of 0.48%, relative to the 0.1% concentration of manganese found in the Earth's crust. On the Earth, the accumulation of manganese oxides in oceans, soils, rocks, sedimentary ores, fresh water systems, and hydrothermal vents can be largely attributed to microbial activity. Manganese is also a required trace nutrient for most life forms and participates in many critical enzymatic reactions such as photosynthesis. The wide-spread process of bacterial manganese cycling on Earth suggests that manganese is an important element to both geology and biology. Furthermore, there is evidence that bacteria can be fossilized within manganese ores, implying that manganese beds may be good repositories for preserved biomarkers. A particular genus of bacteria, known historically as Metallogenium, can form star-shaped manganese oxide minerals (called metallogenium) through the action of manganese oxide precipitation along its surface. Fossilized structures that resemble metallogenium have been found in Precambrian sedimentary formations and in Cretaceous-Paleogene cherts. The Cretaceous-Paleogene formations are highly enriched in manganese and have concentrations of trace elements (Fe, Zn, Cu, and Co) similar to modern-day manganese oxide deposits in marine environments. The appearance of metallogenium-like fossils associated with manganese deposits suggests that bacteria may be preserved within the minerals that they form. Additional information is contained in the original extended abstract.

The effect of manganese content on mechanical properties of high titanium microalloyed steels

Energy Technology Data Exchange (ETDEWEB)

Li, Xiaolin, E-mail: lixiaolinwork@163.com [Shougang Research Institute of Technology, Beijing 100041 (China); Li, Fei; Cui, Yang; Xiao, Baoliang [Shougang Research Institute of Technology, Beijing 100041 (China); Wang, Xuemin [School of Materials Science and Engineering, University of Science and Technology Beijing, Beijing 100083 (China)

2016-11-20

In this work, in order to achieve an optimum combination of high strength, ductility and toughness of high Ti microalloyed steel, extensive research efforts were exerted to study the effect of soaking temperature, manganese and sulfur content on properties of titanium steels. Precipitation hardening of Ti-bearing steels has been found to vary with different soaking temperature. Higher strength was achieved in these steels at higher soaking temperature due to dissolution of more TiC, Ti{sub 4}S{sub 2}C{sub 2} and little TiN, which lead to re-precipitation of fine carbides with greater volume fraction. The results of transmission electron microscope (TEM)analysis indicates that there were more and finer TiC precipitates coherent or semi-coherent with the ferrite matrix in the high manganese content steel than in low manganese content steel. The marked improvement in strength is also associated with low sulfur content. TiC particles smaller than 20 nm in 8Ti-8Mn steel help enhance strength to higher than 302 MPa compared with 8Mn steel.

Manganese

Science.gov (United States)

Cannon, William F.; Kimball, Bryn E.; Corathers, Lisa A.; Schulz, Klaus J.; DeYoung,, John H.; Seal, Robert R.; Bradley, Dwight C.

2017-12-19

Manganese is an essential element for modern industrial societies. Its principal use is in steelmaking, where it serves as a purifying agent in iron-ore refining and as an alloy that converts iron into steel. Although the amount of manganese consumed to make a ton of steel is small, ranging from 6 to 9 kilograms, it is an irreplaceable component in the production of this fundamental material. The United States has been totally reliant on imports of manganese for many decades and will continue to be so for at least the near future. There are no domestic reserves, and although some large low-grade resources are known, they are far inferior to manganese ores readily available on the international market. World reserves of manganese are about 630 million metric tons, and annual global consumption is about 16 million metric tons. Current reserves are adequate to meet global demand for several decades. Global resources in traditional land-based deposits, including both reserves and rocks sufficiently enriched in manganese to be ores in the future, are much larger, at about 17 billion metric tons. Manganese resources in seabed deposits of ferromanganese nodules and crusts are larger than those on land and have not been fully quantified. No production from seabed deposits has yet been done, but current research and development activities are substantial and may bring parts of these seabed resources into production in the future. The advent of economically successful seabed mining could substantially alter the current scenario of manganese supply by providing a large new source of manganese in addition to traditional land-based deposits.From a purely geologic perspective, there is no global shortage of proven ores and potential new ores that could be developed from the vast tonnage of identified resources. Reserves and resources are very unevenly distributed, however. The Kalahari manganese district in South Africa contains 70 percent of the world’s identified resources

Cryogenics

International Nuclear Information System (INIS)

Gutierrez R, C.; Jimenez D, J.; Cejudo A, J.; Hernandez M, V.

1997-01-01

Cryogenics is one of these technologies which contributes to scientific research that supports to the industry in the following benefits: 1. Storage ability and a great quantity of dense gases with cryogenic liquid which is found at high pressure. 2. Production ability at low cost with high purity gases through distillation or condensation. 3. Ability to use low temperatures in the refrigerating materials or alteration of the physical properties. This technology is used for reprocessing of those short and long half life radioactive wastes which always have been required that to be separated with classical methods. In this text we report the radioactive wastes separation by more sophisticated methods but more quickly and reliable. (Author)

MOSFET's for Cryogenic Amplifiers

Science.gov (United States)

Dehaye, R.; Ventrice, C. A.

1987-01-01

Study seeks ways to build transistors that function effectively at liquid-helium temperatures. Report discusses physics of metaloxide/semiconductor field-effect transistors (MOSFET's) and performances of these devices at cryogenic temperatures. MOSFET's useful in highly sensitive cryogenic preamplifiers for infrared astronomy.

Investigation of High-Speed Cryogenic Machining Based on Finite Element Approach

Directory of Open Access Journals (Sweden)

Pooyan Vahidi Pashaki

Full Text Available Abstract The simulation of cryogenic machining process because of using a three-dimensional model and high process duration time in the finite element method, have been studied rarely. In this study, to overcome this limitation, a 2.5D finite element model using the commercial finite element software ABAQUS has been developed for the cryogenic machining process and by considering more realistic assumptions, the chip formation procedure investigated. In the proposed method, the liquid nitrogen has been used as a coolant. At the modeling of friction during the interaction of tools - chip, the Coulomb law has been used. In order to simulate the behavior of plasticity and failure criterion, Johnson-Cook model was used, and unlike previous investigations, thermal and mechanical properties of materials as a function of temperature were applied to the software. After examining accuracy of the model with present experimental data, the effect of parameters such as rake angle and the cutting speed as well as dry machining of aluminum alloy by the use of coupled dynamic temperature solution has been studied. Results indicated that at the cutting velocity of 10 m/s, cryogenic cooling has caused into decreasing 60 percent of tools temperature in comparison with the dry cooling. Furthermore, a chip which has been made by cryogenic machining were connected and without fracture in contrast to dry machining.

Low copper and high manganese levels in prion protein plaques

Science.gov (United States)

Johnson, Christopher J.; Gilbert, P.U.P.A.; Abrecth, Mike; Baldwin, Katherine L.; Russell, Robin E.; Pedersen, Joel A.; McKenzie, Debbie

2013-01-01

Accumulation of aggregates rich in an abnormally folded form of the prion protein characterize the neurodegeneration caused by transmissible spongiform encephalopathies (TSEs). The molecular triggers of plaque formation and neurodegeneration remain unknown, but analyses of TSE-infected brain homogenates and preparations enriched for abnormal prion protein suggest that reduced levels of copper and increased levels of manganese are associated with disease. The objectives of this study were to: (1) assess copper and manganese levels in healthy and TSE-infected Syrian hamster brain homogenates; (2) determine if the distribution of these metals can be mapped in TSE-infected brain tissue using X-ray photoelectron emission microscopy (X-PEEM) with synchrotron radiation; and (3) use X-PEEM to assess the relative amounts of copper and manganese in prion plaques in situ. In agreement with studies of other TSEs and species, we found reduced brain levels of copper and increased levels of manganese associated with disease in our hamster model. We also found that the in situ levels of these metals in brainstem were sufficient to image by X-PEEM. Using immunolabeled prion plaques in directly adjacent tissue sections to identify regions to image by X-PEEM, we found a statistically significant relationship of copper-manganese dysregulation in prion plaques: copper was depleted whereas manganese was enriched. These data provide evidence for prion plaques altering local transition metal distribution in the TSE-infected central nervous system.

The Application of Cryogenic Laser Physics to the Development of High Average Power Ultra-Short Pulse Lasers

Directory of Open Access Journals (Sweden)

David C. Brown

2016-01-01

Full Text Available Ultrafast laser physics continues to advance at a rapid pace, driven primarily by the development of more powerful and sophisticated diode-pumping sources, the development of new laser materials, and new laser and amplification approaches such as optical parametric chirped-pulse amplification. The rapid development of high average power cryogenic laser sources seems likely to play a crucial role in realizing the long-sought goal of powerful ultrafast sources that offer concomitant high peak and average powers. In this paper, we review the optical, thermal, thermo-optic and laser parameters important to cryogenic laser technology, recently achieved laser and laser materials progress, the progression of cryogenic laser technology, discuss the importance of cryogenic laser technology in ultrafast laser science, and what advances are likely to be achieved in the near-future.

Autonomic function in manganese alloy workers

Energy Technology Data Exchange (ETDEWEB)

Barrington, W.W.; Angle, C.R.; Willcockson, N.K.; Padula, M.A. [Univ. of Nebraska Medical Center, Omaha, NE (United States); Korn, T.

1998-07-01

The observation of orthostatic hypotension in an index case of manganese toxicity lead to this prospective attempt to evaluate cardiovascular autonomic function and cognitive and emotional neurotoxicity in eight manganese alloy welders and machinists. The subjects consisted of a convenience sample consisting of an index case of manganese dementia, his four co-workers in a frog shop for gouging, welding, and grinding repair of high manganese railway track and a convenience sample of three mild steel welders with lesser manganese exposure also referred because of cognitive or autonomic symptoms. Frog shop air manganese samples 9.6--10 years before and 1.2--3.4 years after the diagnosis of the index case exceeded 1.0 mg/m{sup 3} in 29% and 0.2 mg/m{sup 3} in 62%. Twenty-four-hour electrocardiographic (Holter) monitoring was used to determine the temporal variability of the heartrate (RR{prime} interval) and the rates of change at low frequency and high frequency. MMPI and MCMI personality assessment and short-term memory, figure copy, controlled oral word association, and symbol digit tests were used.

Highly Chemo- and Stereoselective Transfer Semihydrogenation of Alkynes Catalyzed by a Stable, Well-defined Manganese(II) Complex

KAUST Repository

Brzozowska, Aleksandra; Azofra, Luis Miguel; Zubar, Viktoriia; Atodiresei, Iuliana; Cavallo, Luigi; Rueping, Magnus; El-Sepelgy, Osama

2018-01-01

The first example of manganese catalyzed semihydrogenation of internal alkynes to (Z)-alkenes using ammonia borane as a hydrogen donor is reported. The reaction is catalyzed by a pincer complex of the earth abundant manganese(II) salt in the absence of any additives, base or super hydride. The ammonia borane smoothly reduces the manganese pre-catalyst [Mn(II)-PNP][Cl]2 to the catalytically active species [Mn(I)-PNP]-hydride in the triplet spin state. This manganese hydride is highly stabilized by complexation with the alkyne substrate. Computational DFT analysis studies of the reaction mechanism rationalizes the origin of stereoselectivity towards formation of (Z)-alkenes.

Highly Chemo- and Stereoselective Transfer Semihydrogenation of Alkynes Catalyzed by a Stable, Well-defined Manganese(II) Complex

KAUST Repository

Brzozowska, Aleksandra

2018-03-30

The first example of manganese catalyzed semihydrogenation of internal alkynes to (Z)-alkenes using ammonia borane as a hydrogen donor is reported. The reaction is catalyzed by a pincer complex of the earth abundant manganese(II) salt in the absence of any additives, base or super hydride. The ammonia borane smoothly reduces the manganese pre-catalyst [Mn(II)-PNP][Cl]2 to the catalytically active species [Mn(I)-PNP]-hydride in the triplet spin state. This manganese hydride is highly stabilized by complexation with the alkyne substrate. Computational DFT analysis studies of the reaction mechanism rationalizes the origin of stereoselectivity towards formation of (Z)-alkenes.

Manganese

International Nuclear Information System (INIS)

Fayziev, A.R.

2002-01-01

Present article is devoted to manganese content in fluoride. The manganese content of some geologic deposits of Tajikistan was determined by means of chemical analysis. The mono mineral samples of fluorite of 5 geologic deposits of various mineralogical and genetic type was studied. The manganese content in fluorite of geologic deposits of various mineralogical and genetic type was defined.

Cryogenic Etching of High Aspect Ratio 400 nm Pitch Silicon Gratings.

Science.gov (United States)

Miao, Houxun; Chen, Lei; Mirzaeimoghri, Mona; Kasica, Richard; Wen, Han

2016-10-01

The cryogenic process and Bosch process are two widely used processes for reactive ion etching of high aspect ratio silicon structures. This paper focuses on the cryogenic deep etching of 400 nm pitch silicon gratings with various etching mask materials including polymer, Cr, SiO 2 and Cr-on-polymer. The undercut is found to be the key factor limiting the achievable aspect ratio for the direct hard masks of Cr and SiO 2 , while the etch selectivity responds to the limitation of the polymer mask. The Cr-on-polymer mask provides the same high selectivity as Cr and reduces the excessive undercut introduced by direct hard masks. By optimizing the etching parameters, we etched a 400 nm pitch grating to ≈ 10.6 μ m depth, corresponding to an aspect ratio of ≈ 53.

Three manganese oxide-rich marine sediments harbor similar communities of acetate-oxidizing manganese-reducing bacteria.

Science.gov (United States)

Vandieken, Verona; Pester, Michael; Finke, Niko; Hyun, Jung-Ho; Friedrich, Michael W; Loy, Alexander; Thamdrup, Bo

2012-11-01

Dissimilatory manganese reduction dominates anaerobic carbon oxidation in marine sediments with high manganese oxide concentrations, but the microorganisms responsible for this process are largely unknown. In this study, the acetate-utilizing manganese-reducing microbiota in geographically well-separated, manganese oxide-rich sediments from Gullmar Fjord (Sweden), Skagerrak (Norway) and Ulleung Basin (Korea) were analyzed by 16S rRNA-stable isotope probing (SIP). Manganese reduction was the prevailing terminal electron-accepting process in anoxic incubations of surface sediments, and even the addition of acetate stimulated neither iron nor sulfate reduction. The three geographically distinct sediments harbored surprisingly similar communities of acetate-utilizing manganese-reducing bacteria: 16S rRNA of members of the genera Colwellia and Arcobacter and of novel genera within the Oceanospirillaceae and Alteromonadales were detected in heavy RNA-SIP fractions from these three sediments. Most probable number (MPN) analysis yielded up to 10(6) acetate-utilizing manganese-reducing cells cm(-3) in Gullmar Fjord sediment. A 16S rRNA gene clone library that was established from the highest MPN dilutions was dominated by sequences of Colwellia and Arcobacter species and members of the Oceanospirillaceae, supporting the obtained RNA-SIP results. In conclusion, these findings strongly suggest that (i) acetate-dependent manganese reduction in manganese oxide-rich sediments is catalyzed by members of taxa (Arcobacter, Colwellia and Oceanospirillaceae) previously not known to possess this physiological function, (ii) similar acetate-utilizing manganese reducers thrive in geographically distinct regions and (iii) the identified manganese reducers differ greatly from the extensively explored iron reducers in marine sediments.

Metabolism of manganese, iron, copper, and selenium in calves

International Nuclear Information System (INIS)

Ho, S.Y.

1981-01-01

Sixteen male Holstein calves were used to study manganese and iron metabolism. The calves were fed one of the following diets for 18 days: control, control + iron, control + manganese, and control + iron and manganese. All calves were dosed orally with manganese-54. Tissue concentrations of manganese, iron and manganese-54 were determined. Small intestinal iron was lower in calves fed the high manganese diet than in controls. Tissue manganese-54 was lower in calves fed a high manganese diet. Fecal manganese content increased in calves fed both high manganese and high manganese-high iron diets. Serum total iron was not affected by the dietary treatments. To study the effects of high dietary levels of copper and selenium on the intracellular distributions of these two elements in liver and kidney cytosol, calves were fed one of four diets for 15 days. These were 0 and 100 ppM supplemental copper and 0 and 1 ppM added selenium. The control diet containing 0.1 ppM of selenium and 15 ppM of copper. All calves were orally dosed 48 hrs prior to sacrifice with selenium-75. A high copper diet increased copper concentrations in all intracellular liver fractions and most kidney fractions. Only the effects in the liver were significant. Less copper was found in the mitochondria fractions in liver and kidney of calves fed a high selenium diet. Three major copper-binding protein peaks were separated from the soluble fractions of calf liver and kidney. Peak 1 appeared to be the major copper-binding protein in liver and kidney cytosol of copper-loaded animals. Added selenium alone or in combination with copper accentuated the copper accumulation in this peak. Most of selenium-75 was recovered in the same peak as the copper. The results of this experiment indicated that the large molecular proteins in liver and kidney cytosol of calves play an important role in copper and selenium-75 metabolism

Cryogenics for LHC experiments

CERN Multimedia

2001-01-01

Cryogenic systems will be used by LHC experiments to maximize their performance. Institutes around the world are collaborating with CERN in the construction of these very low temperature systems. The cryogenic test facility in hall 180 for ATLAS magnets. High Energy Physics experiments have frequently adopted cryogenic versions of their apparatus to achieve optimal performance, and those for the LHC will be no exception. The two largest experiments for CERN's new flagship accelerator, ATLAS and CMS, will both use large superconducting magnets operated at 4.5 Kelvin - almost 270 degrees below the freezing point of water. ATLAS also includes calorimeters filled with liquid argon at 87 Kelvin. For the magnets, the choice of a cryogenic version was dictated by a combination economy and transparency to emerging particles. For the calorimeters, liquid argon was selected as the fluid best suited to the experiment's physics requirements. High Energy Physics experiments are the result of worldwide collaborations and...

Study on microstructure and mechanical properties of Al–Mg–Si–Cu alloy with high manganese content

International Nuclear Information System (INIS)

Han, Yi; Ma, Ke; Li, Lian; Chen, Wei; Nagaumi, Hiromi

2012-01-01

Highlights: ► We examine the precipitates by HRTEM in the high manganese Al–Mg–Si–Cu alloy. ► Manganese content determines amount of secondary phases after homogenization. ► Increasing magnesium content promotes to precipitate S phase. ► Yield strength of the new alloy is 52–65% higher than that of commercial 6061 alloy. ► Uniform distribution of Mn dispersoids encourages to enhance mechanical properties. -- Abstract: The microstructure and mechanical properties of Al–Mg–Si–Cu alloy with high manganese content were studied in the present work to develop a new alloy. The microstructure features were quantificationally determined by a combination of scanning electron microscope and high resolution transmission electron microscopy. The dominant strengthening precipitates comprising the needle-shaped pre-β″(or β″) and lath-shaped Q′ phases were identified in the T6 temper. With the increase of magnesium content, S phase was promoted to precipitate to give an enhancement in strength. The yield strength of the examined alloys with high manganese content was found to be about 52–65% higher than that of commercial 6061 alloy. It was considered that, in addition to the strengthening precipitates, Mn dispersoids generating the dispersion hardening effect and the homogeneous deformation contributed a lot to the favorable mechanical properties.

CALDER: High-sensitivity cryogenic light detectors

International Nuclear Information System (INIS)

Casali, N.; Bellini, F.; Cardani, L.

2017-01-01

The current bolometric experiments searching for rare processes such as neutrinoless double-beta decay or dark matter interaction demand for cryogenic light detectors with high sensitivity, large active area and excellent scalability and radio-purity in order to reduce their background budget. The CALDER project aims to develop such kind of light detectors implementing phonon-mediated Kinetic Inductance Detectors (KIDs). The goal for this project is the realization of a 5 × 5 cm"2 light detector working between 10 and 100mK with a baseline resolution RMS below 20 eV. In this work the characteristics and the performances of the prototype detectors developed in the first project phase will be shown.

Highly stable silica-coated manganese ferrite nanoparticles as high-efficacy T2 contrast agents for magnetic resonance imaging

Science.gov (United States)

Ahmad, Ashfaq; Bae, Hongsub; Rhee, Ilsu

2018-05-01

Highly stable silica-coated manganese ferrite nanoparticles were fabricated for application as magnetic resonance imagining (MRI) contrast agents. The manganese ferrite nanoparticles were synthesized using a hydrothermal technique and coated with silica. The particle size was investigated using transmission electron microscopy and was found to be 40-60 nm. The presence of the silica coating on the particle surface was confirmed by Fourier transform infrared spectroscopy. The crystalline structure was investigated by X-ray diffraction, and the particles were revealed to have an inverse spinel structure. Superparamagnetism was confirmed by the magnetic hysteresis curves obtained using a vibrating sample magnetometer. The efficiency of the MRI contrast agents was investigated by using aqueous solutions of the particles in a 4.7 T MRI scanner. The T1 and T2 relaxivities of the particles were 1.42 and 60.65 s-1 mM-1, respectively, in water. The ratio r2/r1 was 48.91, confirming that the silica-coated manganese ferrite nanoparticles were suitable high-efficacy T2 contrast agents.

Cryogenic systems for detectors and particle accelerators

International Nuclear Information System (INIS)

Sondericker, J.H.

1988-01-01

It's been one hundred years since the first successful experiments were carried out leading to the liquefaction of oxygen which birthed the field of cryogenics and about sixty years since cryogenics went commercial. Originally, cryogenics referred to the technology and art of producing low temperatures but today the definition adopted by the XII Congress of the International Institute of Refrigeration describes cryogenics as the study of phenomena, techniques, and concepts occurring at our pertaining to temperatures below 120 K. Modern acceptance of the importance and use of cryogenic fluids continues to grow. By far, the bulk of cryogenic products are utilized by industry for metal making, agriculture, medicine, food processing and as efficient storage of fuels. Cryogenics has found many uses in the scientific community as well, enabling the development of ultra low noise amplifiers, fast cold electronics, cryopumped ultra high vacuums, the production of intense magnetic fields and low loss power transmission through the sue of cryogenically cooled superconductors. High energy physic research has been and continues to use cryogenic hardware to produce liquids used as detector targets and to produce refrigeration necessary to cool superconducting magnets to design temperature for particle accelerator applications. In fact, today's super accelerators achieve energies that would be impossible to reach with conventional copper magnets, demonstrating that cryogenics has become an indispensable ingredient in today's scientific endeavors

Cryogenics; Criogenia

Energy Technology Data Exchange (ETDEWEB)

Gutierrez R, C; Jimenez D, J; Cejudo A, J; Hernandez M, V [Instituto Nacional de Investigaciones Nucleares, A.P. 18-1027, 11801 Mexico D.F. (Mexico)

1997-07-01

Cryogenics is one of these technologies which contributes to scientific research that supports to the industry in the following benefits: 1. Storage ability and a great quantity of dense gases with cryogenic liquid which is found at high pressure. 2. Production ability at low cost with high purity gases through distillation or condensation. 3. Ability to use low temperatures in the refrigerating materials or alteration of the physical properties. This technology is used for reprocessing of those short and long half life radioactive wastes which always have been required that to be separated with classical methods. In this text we report the radioactive wastes separation by more sophisticated methods but more quickly and reliable. (Author)

Nanotwin Formation in High-Manganese Austenitic Steels Under Explosive Shock Loading

Science.gov (United States)

Canadinc, D.; Uzer, B.; Elmadagli, M.; Guner, F.

2018-04-01

The micro-deformation mechanisms active in a high-manganese austenitic steel were investigated upon explosive shock loading. Single system of nanotwins forming within primary twins were shown to govern the deformation despite the elevated temperatures attained during testing. The benefits of nanotwin formation for potential armor materials were demonstrated.

Characterization of Sumbawa manganese ore and recovery of manganese sulfate as leaching products

Science.gov (United States)

Kusumaningrum, Retno; Rahmani, Siti Astari; Widayatno, Wahyu Bambang; Wismogroho, Agus Sukarto; Nugroho, Dwi Wahyu; Maulana, Syahrizal; Rochman, Nurul Taufiqu; Amal, M. Ikhlasul

2018-05-01

The aims of this research were to study the leaching process of manganese ore which originated from Sumbawa, Indonesia and its characterization. A high grade Indonesian manganese ore from Sumbawa, West of Nusa Tenggara was characterized by X-Ray Fluorescence (XRF). The result showed composition of 78.8 % Mn, 17.77% Fe and the rest were trace elements such as Si, Co, Ti, Zn, V and Zr contents. X-Ray Diffraction analysis showed that the manganese ore was consisted of pyrolusite (MnO2), rhodonite (MnSiO3), rhodochrosite (MnCO3) and hematite (Fe2O3). Manganese ore was also analyzed by thermal analysis to observe their thermal decomposition character. In this study, sulphuric acid (H2SO4, 6 M) was deployed as leaching agent. The leaching process was performed at 90 °C for two hours with the addition of NH4OH to control pH. Recovery percentage of leaching process yielded of 87 % Mn extracted. The crystallization process result at heating temperature of 200 °C was confirmed by XRD as manganese sulfate.

Development of a cryogenic hydrogen microjet for high-intensity, high-repetition rate experiments

Science.gov (United States)

Kim, J. B.; Göde, S.; Glenzer, S. H.

2016-11-01

The advent of high-intensity, high-repetition-rate lasers has led to the need for replenishing targets of interest for high energy density sciences. We describe the design and characterization of a cryogenic microjet source, which can deliver a continuous stream of liquid hydrogen with a diameter of a few microns. The jet has been imaged at 1 μm resolution by shadowgraphy with a short pulse laser. The pointing stability has been measured at well below a mrad, for a stable free-standing filament of solid-density hydrogen.

Characterization of a cryogenic ion guide at IGISOL

NARCIS (Netherlands)

Saastamoinen, A.; Moore, I. D.; Ranjan, M.; Dendooven, P.; Penttila, H.; Perajarvi, K.; Popov, A.; Aysto, J.

2012-01-01

A small volume cryogenic ion guide has been characterized at the IGISOL facility, Jyvaskyla, as a prototype to verify whether there are any major obstacles to the use of high-density cryogenic helium gas for the stopping and extraction of high-energy ions from a large volume cryogenic ion catcher.

Single Crystal Piezomotor for Large Stroke, High Precision and Cryogenic Actuations, Phase I

Data.gov (United States)

National Aeronautics and Space Administration — TRS Technologies proposes a novel single crystal piezomotor for large stroke, high precision, and cryogenic actuations with capability of position set-hold with...

Manganese oxide-based materials as electrochemical supercapacitor electrodes.

Science.gov (United States)

Wei, Weifeng; Cui, Xinwei; Chen, Weixing; Ivey, Douglas G

2011-03-01

Electrochemical supercapacitors (ECs), characteristic of high power and reasonably high energy densities, have become a versatile solution to various emerging energy applications. This critical review describes some materials science aspects on manganese oxide-based materials for these applications, primarily including the strategic design and fabrication of these electrode materials. Nanostructurization, chemical modification and incorporation with high surface area, conductive nanoarchitectures are the three major strategies in the development of high-performance manganese oxide-based electrodes for EC applications. Numerous works reviewed herein have shown enhanced electrochemical performance in the manganese oxide-based electrode materials. However, many fundamental questions remain unanswered, particularly with respect to characterization and understanding of electron transfer and atomic transport of the electrochemical interface processes within the manganese oxide-based electrodes. In order to fully exploit the potential of manganese oxide-based electrode materials, an unambiguous appreciation of these basic questions and optimization of synthesis parameters and material properties are critical for the further development of EC devices (233 references).

Cryogenics a textbook

CERN Document Server

Thipse, S S

2013-01-01

A Textbook covers lucidly various cryogenic applications including cryogenic engines and space and electronic applications. Importance of cryogenic engines in space propulsion, complete thermodynamic analysis of cryogenic systems with special emphasis on cryogenic cycles, Dewar vessels used to store cryogenic fluids and their applications in various industries have also been discussed in detail. Explanation of Superconductivity and its applications with a description of various Cryocoolers used in industry has also been provided with extensive details. Further technical information on cryogens has been specified alongwith the vacuum technology which has been sufficiently described with examples. Science of Cryonics has been elaborated and all aspects of technology related to functioning of cryogenic plants and their construction including valves, pipes has been incorporated in this book.

Mechanical Properties and Fractographic Analysis of High Manganese Steels After Dynamic Deformation Tests

Directory of Open Access Journals (Sweden)

Jabłońska M.B.

2014-10-01

Full Text Available Since few years many research centres conducting research on the development of high-manganese steels for manufacturing of parts for automotive and railway industry. Some of these steels belong to the group of AHS possessing together with high strength a great plastic elongation, and an ideal uniform work hardening behavior. The article presents the dynamic mechanical properties of two types of high manganese austenitic steel with using a flywheel machine at room temperature with strain rates between 5×102÷3.5×103s?–1. It was found that the both studied steels exhibit a high sensitivity Rm to the strain rate. With increasing the strain rate from 5×102 to 3.5×103s?–1 the hardening dominates the process. The fracture analysis indicate that after dynamic test both steel is characterized by ductile fracture surfaces which indicate good plasticity of investigated steels.

Treating electrolytic manganese residue with alkaline additives for stabilizing manganese and removing ammonia

Energy Technology Data Exchange (ETDEWEB)

Zhou, Changbo; Wang, Jiwei [Chinese Research Academy of Environmental Sciences, Beijing (China); Wang, Nanfang [Hunan Institute of Engineering, Xiangtan (China)

2013-11-15

Electrolytic manganese residue (EMR) from the electrolytic manganese industry is a solid waste containing mainly calcium sulfate dihydrate and quartzite. It is impossible to directly use the EMR as a building material due to some contaminants such as soluble manganese, ammonia nitrogen and other toxic substances. To immobilize the contaminants and reduce their release into the environment, treating EMR using alkaline additives for stabilizing manganese and removing ammonia was investigated. The physical and chemical characteristics of the original EMR were characterized by XRFS, XRD, and SEM. Leaching test of the original EMR shows that the risks to the environment are the high content of soluble manganese and ammonia nitrogen. The influence of various alkaline additives, solidifying reaction time, and other solidifying reaction conditions such as outdoor ventilation and sunlight, and rain flow on the efficiencies of Mn{sup 2+} solidification and ammonia nitrogen removal was investigated. The results show that with mass ratio of CaO to residue 1 : 8, when the solidifying reaction was carried out indoors for 4 h with no rain flow, the highest efficiencies of Mn{sup 2+} solidification and ammonia nitrogen removal (99.98% and 99.21%) are obtained. Leaching test shows that the concentration and emission of manganese and ammonia nitrogen of the treated EMR meets the requirements of the Chinese government legislation (GB8978-1996)

Treating electrolytic manganese residue with alkaline additives for stabilizing manganese and removing ammonia

International Nuclear Information System (INIS)

Zhou, Changbo; Wang, Jiwei; Wang, Nanfang

2013-01-01

Electrolytic manganese residue (EMR) from the electrolytic manganese industry is a solid waste containing mainly calcium sulfate dihydrate and quartzite. It is impossible to directly use the EMR as a building material due to some contaminants such as soluble manganese, ammonia nitrogen and other toxic substances. To immobilize the contaminants and reduce their release into the environment, treating EMR using alkaline additives for stabilizing manganese and removing ammonia was investigated. The physical and chemical characteristics of the original EMR were characterized by XRFS, XRD, and SEM. Leaching test of the original EMR shows that the risks to the environment are the high content of soluble manganese and ammonia nitrogen. The influence of various alkaline additives, solidifying reaction time, and other solidifying reaction conditions such as outdoor ventilation and sunlight, and rain flow on the efficiencies of Mn"2"+ solidification and ammonia nitrogen removal was investigated. The results show that with mass ratio of CaO to residue 1 : 8, when the solidifying reaction was carried out indoors for 4 h with no rain flow, the highest efficiencies of Mn"2"+ solidification and ammonia nitrogen removal (99.98% and 99.21%) are obtained. Leaching test shows that the concentration and emission of manganese and ammonia nitrogen of the treated EMR meets the requirements of the Chinese government legislation (GB8978-1996)

Rotor-dynamic design aspects for a variable frequency drive based high speed cryogenic centrifugal pump in fusion devices

International Nuclear Information System (INIS)

Das, Jotirmoy; Vaghela, Hitensinh; Bhattacharya, Ritendra; Patel, Pratik; Shukla, Vinit; Shah, Nitin; Sarkar, Biswanath

2015-01-01

Superconducting magnets of large size are inevitable for fusion devices due to high magnetic field requirements. Forced flow cooling of the superconducting magnets with high mass flowrate of the order ∼3 kg/s is required to keep superconducting magnets within its safe operational boundaries during various plasma scenarios. This important requirement can be efficiently fulfilled by employing high capacity and high efficiency cryogenic centrifugal pumps. The efficiency > 70% will ensure overall lower heat load to the cryoplant. Thermo-hydraulic design of cryogenic centrifugal pump revealed that to achieve the operational regime with high efficiency, the speed should be ∼ 10,000 revolutions per minute. In this regard, the rotor-dynamic design aspect is quite critical from the operational stability point of view. The rotor shaft design of the cryogenic pump is primarily an outcome of optimization between thermal heat-in leak at cryogenic temperature level from ambient, cryogenic fluid impedance and designed rotation speed of the impeller wheel. The paper describes the basic design related to critical speed of the rotor shaft, rotor whirl and system instability prediction to explore the ideal operational range of the pump from the system stability point of view. In the rotor-dynamic analysis, the paper also describes the Campbell plots to ensure that the pump is not disturbed by any of the critical speeds, especially while operating near the nominal and enhanced operating modes. (author)

Manganese

Science.gov (United States)

... research suggests that taking a specific product (7-Keto Naturalean) containing manganese, 7-oxo-DHEA, L-tyrosine, ... can absorb.Milk proteinAdding milk protein to the diet might increase the amount of manganese the body ...

CRYOGENIC AND VACUUM TECHNOLOGICAL ASPECTS OF THE LOW-ENERGY ELECTROSTATIC CRYOGENIC STORAGE RING

International Nuclear Information System (INIS)

Orlov, D. A.; Lange, M.; Froese, M.; Hahn, R. von; Grieser, M.; Mallinger, V.; Sieber, T.; Weber, T.; Wolf, A.; Rappaport, M.

2008-01-01

The cryogenic and vacuum concepts for the electrostatic Cryogenic ion Storage Ring (CSR), under construction at the Max-Planck-Institut fuer Kernphysik in Heidelberg, is presented. The ring will operate in a broad temperature range from 2 to 300 K and is required to be bakeable up to 600 K. Extremely high vacuum and low temperatures are necessary to achieve long lifetimes of the molecular ions stored in the ring so that the ions will have enough time to cool by radiation to their vibrational and rotational ground states. To test cryogenic and vacuum technological aspects of the CSR, a prototype is being built and will be connected to the commercial cryogenic refrigerator recently installed, including a specialized 2-K connection system. The first results and the status of current work with the prototype are also presented

Cryogenic Design of the New High Field Magnet Test Facility at CERN

Science.gov (United States)

Benda, V.; Pirotte, O.; De Rijk, G.; Bajko, M.; Craen, A. Vande; Perret, Ph.; Hanzelka, P.

In the framework of the R&D program related to the Large Hadron Collider (LHC) upgrades, a new High Field Magnet (HFM) vertical test bench is required. This facility located in the SM18 cryogenic test hall shall allow testing of up to 15 tons superconducting magnets with energy up to 10 MJ in a temperature range between 1.9 K and 4.5 K. The article describes the cryogenic architecture to be inserted in the general infrastructure of SM18 including the process and instrumentation diagram, the different operating phases including strategy for magnet cool down and warm up at controlled speed and quench management as well as the design of the main components.

Cryogenics safety

International Nuclear Information System (INIS)

Reider, R.

1977-01-01

The safety hazards associated with handling cryogenic fluids are discussed in detail. These hazards include pressure buildup when a cryogenic fluid is heated and becomes a gas, potential damage to body tissues due to surface contact, toxic risk from breathing air altered by cryogenic fluids, dangers of air solidification, and hazards of combustible cryogens such as liquified oxygen, hydrogen, or natural gas or of combustible mixtures. Safe operating procedures and emergency planning are described

Microstructure and properties of TiC-high manganese steel cermet prepared by different sintering processes

Energy Technology Data Exchange (ETDEWEB)

Wang, Zhi; Lin, Tao, E-mail: lintao@ustb.edu.cn; He, Xinbo; Shao, Huiping; Zheng, Jianshu; Qu, Xuanhui

2015-11-25

In the paper, the TiC −50 wt.% high manganese steel cermet was made with different sintering processes including vacuum sintering, hot pressing, microwave sintering and spark plasma sintering (SPS). The microstructure, porosity and fracture morphology of the samples were analyzed with scanning electron microscopy (SEM). Phase analysis was carried out using X-ray diffraction (XRD). The density, hardness, transverse rupture strength (TRS) and wear resistance were investigated for the effect of the sintering processes. The results showed that the core–shell structure was not clearly observed for the TiC particles in microstructures and the high manganese steel matrix is BCC structure. Hot pressing, microwave sintering and SPS are useful processes for densification of the cermet. Nearly full density and higher hardness can be reached by these three processes at a lower sintering temperature and in a shorter sintering time. However, higher TRS can be reached by means of alloying completely in a longer sintering time, for example vacuum sintering. Pre-sintering in a long sintering time at a lower sintering temperature is also useful for improving the TRS. Finally, vacuum sintering is an effective process for producing this composite with the lowest cost in the mass production. - Highlights: • TiC-high manganese steel cermets were prepared by four sintering processes. • The core–shell structure was not clearly observed for the TiC particles in microstructures. • Th high manganese steel matrix is BCC structure instead of FCC structure. • Pre-sintering before microwave sintering is also useful for improving the TRS. • Vacuum sintering can be effective way for prepare this cermet in mass production.

Spectroscopic Characteristics of Highly Selective Manganese Catalysis in Acqueous Polyurethane Systems

Directory of Open Access Journals (Sweden)

Miroljub Barac

2006-11-01

Full Text Available The latest investigations on producing more efficient catalytic aqueouspolyurethane systems are in the domain of metal complexes with mixed ligands. In ourprevious research works, the high selectivity for the isocyanate-hydroxyl reaction inaqueous polyurethane systems has been shown by the manganese(III mixed-ligandcomplexes. The two new complexes have been prepared with two acetylacetonate (acacligands and one maleate ligand and its hydroxylamine derivative of the general formula[Mn(C5H7O22L]. Their structures have been established by using the fundamental analyses,the FTIR and UV/VIS spectroscopic methods, as well as the magnetic measurements. Inorder to explain the different selectivity of the manganese(III mixed-ligand complexes, theUV and ESR spectroscopy have been employed to determine the kinetics of the complexes’decomposition. The thermal stability of the complexes has been determined by way of thedynamic TG method at the heating rate of 5°C⋅min-1 and at the temperature ranged 20-550°C. It suggests the decomposition of the complexes by loss of acid ligand. The main factor in the selective catalysis control in theaqueous polyurethane systems is the nature of the acid ligands and their impact on themanganese(II/manganese(III equilibrium.

Heat switch technology for cryogenic thermal management

Science.gov (United States)

Shu, Q. S.; Demko, J. A.; E Fesmire, J.

2017-12-01

Systematic review is given of development of novel heat switches at cryogenic temperatures that alternatively provide high thermal connection or ideal thermal isolation to the cold mass. These cryogenic heat switches are widely applied in a variety of unique superconducting systems and critical space applications. The following types of heat switch devices are discussed: 1) magnetic levitation suspension, 2) shape memory alloys, 3) differential thermal expansion, 4) helium or hydrogen gap-gap, 5) superconducting, 6) piezoelectric, 7) cryogenic diode, 8) magneto-resistive, and 9) mechanical demountable connections. Advantages and limitations of different cryogenic heat switches are examined along with the outlook for future thermal management solutions in materials and cryogenic designs.

Cryogenics

International Nuclear Information System (INIS)

Shukla, R.K.

1990-01-01

Cryogenics refers to the coldest area known in nature. This temperature range has an upper limit arbitrarily defined as -100 degrees C (-250 degrees C by some) and a lower limit of absolute zero. These limits separate it from the temperature range generally used in refrigerating engineering. One important application of cryogenics is the separation ad purification of air into its various components (oxygen, nitrogen, argon, and the rare gases). Other important developments have been the large-scale production of liquid hydrogen; helium extraction from natural gas; storage and transport of liquefied gases such as oxygen, argon, nitrogen, helium, neon, xenon, and hydrogen; liquefaction of natural gas for ocean transport and peak shaving; and many new types of cryogenic refrigeration devices. This paper introduces the topic of cryogenic engineering. Cryogenic processes generally range from ambient conditions to the boiling point of the cryogenic fluid. Cryogenic cycles also incorporate two or more pressure levels. These properties must also cover the vapor, vapor-liquid, and sometimes the solid regions. Therefore, the physical properties of fluids over a great range of temperatures and pressures must be known. Solubility of contaminants must be known in order to design for their removal. The main physical properties for design purposes are those usually used in unit operations, such as fluid flow, heat transfer, and the like, in addition to those directly related to the Joule-Thomson effect and expansion work. Properties such as density, viscosity, thermal conductivity, heat capacity, enthalpy, entropy, vapor pressure, and vapor-liquid equilibriums are generally obtained in graphical, tabular, or equation form, as a function of temperature and pressure

Helium cryogenics

CERN Document Server

Van Sciver, Steven W

2012-01-01

Twenty five years have elapsed since the original publication of Helium Cryogenics. During this time, a considerable amount of research and development involving helium fluids has been carried out culminating in several large-scale projects. Furthermore, the field has matured through these efforts so that there is now a broad engineering base to assist the development of future projects. Helium Cryogenics, 2nd edition brings these advances in helium cryogenics together in an updated form. As in the original edition, the author's approach is to survey the field of cryogenics with emphasis on helium fluids. This approach is more specialized and fundamental than that contained in other cryogenics books, which treat the associated range of cryogenic fluids. As a result, the level of treatment is more advanced and assumes a certain knowledge of fundamental engineering and physics principles, including some quantum mechanics. The goal throughout the work is to bridge the gap between the physics and engineering aspe...

Cryogenic exciter

Science.gov (United States)

Bray, James William [Niskayuna, NY; Garces, Luis Jose [Niskayuna, NY

2012-03-13

The disclosed technology is a cryogenic static exciter. The cryogenic static exciter is connected to a synchronous electric machine that has a field winding. The synchronous electric machine is cooled via a refrigerator or cryogen like liquid nitrogen. The static exciter is in communication with the field winding and is operating at ambient temperature. The static exciter receives cooling from a refrigerator or cryogen source, which may also service the synchronous machine, to selected areas of the static exciter and the cooling selectively reduces the operating temperature of the selected areas of the static exciter.

High-performance symmetric electrochemical capacitor based on graphene foam and nanostructured manganese oxide

CSIR Research Space (South Africa)

Bello, A

2013-01-01

Full Text Available We have fabricated a symmetric electrochemical capacitor with high energy and power densities based on a composite of graphene foam (GF) with 80 wt% of manganese oxide (MnO(sub2)) deposited by hydrothermal synthesis. Raman spectroscopy and X...

Comparison of cryogenic low-pass filters

Science.gov (United States)

Thalmann, M.; Pernau, H.-F.; Strunk, C.; Scheer, E.; Pietsch, T.

2017-11-01

Low-temperature electronic transport measurements with high energy resolution require both effective low-pass filtering of high-frequency input noise and an optimized thermalization of the electronic system of the experiment. In recent years, elaborate filter designs have been developed for cryogenic low-level measurements, driven by the growing interest in fundamental quantum-physical phenomena at energy scales corresponding to temperatures in the few millikelvin regime. However, a single filter concept is often insufficient to thermalize the electronic system to the cryogenic bath and eliminate spurious high frequency noise. Moreover, the available concepts often provide inadequate filtering to operate at temperatures below 10 mK, which are routinely available now in dilution cryogenic systems. Herein we provide a comprehensive analysis of commonly used filter types, introduce a novel compact filter type based on ferrite compounds optimized for the frequency range above 20 GHz, and develop an improved filtering scheme providing adaptable broad-band low-pass characteristic for cryogenic low-level and quantum measurement applications at temperatures down to few millikelvin.

Comparison of cryogenic low-pass filters.

Science.gov (United States)

Thalmann, M; Pernau, H-F; Strunk, C; Scheer, E; Pietsch, T

2017-11-01

Low-temperature electronic transport measurements with high energy resolution require both effective low-pass filtering of high-frequency input noise and an optimized thermalization of the electronic system of the experiment. In recent years, elaborate filter designs have been developed for cryogenic low-level measurements, driven by the growing interest in fundamental quantum-physical phenomena at energy scales corresponding to temperatures in the few millikelvin regime. However, a single filter concept is often insufficient to thermalize the electronic system to the cryogenic bath and eliminate spurious high frequency noise. Moreover, the available concepts often provide inadequate filtering to operate at temperatures below 10 mK, which are routinely available now in dilution cryogenic systems. Herein we provide a comprehensive analysis of commonly used filter types, introduce a novel compact filter type based on ferrite compounds optimized for the frequency range above 20 GHz, and develop an improved filtering scheme providing adaptable broad-band low-pass characteristic for cryogenic low-level and quantum measurement applications at temperatures down to few millikelvin.

Femtosecond Ti:sapphire cryogenic amplifier with high gain and MHz repetition rate

DEFF Research Database (Denmark)

Dantan, Aurelien Romain; Laurat, Julien; Ourjoumtsev, Alexei

2007-01-01

We demonstrate high gain amplification of 160-femtosecond pulses in a compact double-pass cryogenic Ti:sapphire amplifier. The setup involves a negative GVD mirrors recompression stage, and operates with a repetition rate between 0.2 and 4 MHz with a continuous pump laser. Amplification factors a...... as high as 17 and 320 nJ Fourier-limited pulses are obtained at a 800 kHz repetition rate....

Damping Capacity of High Manganese Austenitic Stainless Steel with a Two Phase Mixed Structure of Martensite and Austenite

International Nuclear Information System (INIS)

Hwang, Tae Hyun; Kang, Chang-Yong

2013-01-01

The damping capacity of high manganese austenitic stainless steel with a two phase mixed structure of deformation-induced martensite and reversed austenite was studied. Reversed austenite with an ultra-fine grain size of less than 0.2 μm was obtained by reversion treatment. The two phase structure of deformation-induced martensite and reversed austenite was obtained by annealing treatment at a range of 500-700 °C and various times in cold rolled high manganese austenitic stainless steel. The damping capacity increased with an increasing annealing temperature and time. In high manganese stainless steel with the two phase mixed structure of martensite and austenite, the damping capacity decreased with an increasing volume fraction of deformation-induced martensite. Thus, the damping capacity was strongly affected by deformation-induced martensite. The results confirmed that austenitic stainless steel with a good combination of strength and damping capacity was obtained from the two phase mixed structure of austenite and martensite.

High-performance symmetric electrochemical capacitor based on graphene foam and nanostructured manganese oxide

Directory of Open Access Journals (Sweden)

Abdulhakeem Bello

2013-08-01

Full Text Available We have fabricated a symmetric electrochemical capacitor with high energy and power densities based on a composite of graphene foam (GF with ∼80 wt% of manganese oxide (MnO2 deposited by hydrothermal synthesis. Raman spectroscopy and X-ray diffraction measurements showed the presence of nanocrystalline MnO2 on the GF, while scanning and transmission electron microscopies showed needle-like manganese oxide coated and anchored onto the surface of graphene. Electrochemical measurements of the composite electrode gave a specific capacitance of 240 Fg−1 at a current density of 0.1 Ag−1 for symmetric supercapacitors using a two-electrode configuration. A maximum energy density of 8.3 Whkg−1 was obtained, with power density of 20 kWkg−1 and no capacitance loss after 1000 cycles. GF is an excellent support for pseudo-capacitive oxide materials such as MnO2, and the composite electrode provided a high energy density due to a combination of double-layer and redox capacitance mechanisms.

Polyimide capsules may hold high pressure DT fuel without cryogenic support for the National Ignition Facility indirect-drive targets

International Nuclear Information System (INIS)

Sanchez, J.J.; Letts, S.A.

1997-01-01

New target designs for the Omega upgrade laser and ignition targets in the National Ignition Facility (NIF) require thick (80 - 100 microm) cryogenic fuel layers. The Omega upgrade target will require cryogenic handling after initial fill because of the high fill pressures and the thin capsule walls. For the NIF indirectly driven targets, a larger capsule size and new materials offer hope that they can be built, filled and stored in a manner similar to the targets used in the Nova facility without requiring cryogenic handling

The cryogenic cooling program in high-heat-load optics at the Advanced Photon Source

International Nuclear Information System (INIS)

Rogers, C.S.

1993-07-01

This paper describes some of the aspects of the cryogenic optics program at the Advanced Photon Source (APS). A liquid-nitrogen-cooled, high-vacuum, double crystal monochromator is being fabricated at Argonne National Laboratory (ANL). A pumping system capable of delivering a variable flow rate of up to 10 gallons per minute of pressurized liquid nitrogen and removing 5 kilowatts of x-ray power is also being constructed. This specialized pumping system and monochromator will be used to test the viability of cryogenically cooled, high-heat-load synchrotron optics. It has been determined that heat transfer enhancement will be required for optics used with APS insertion devices. An analysis of a porous-matrix-enhanced monochromator crystal is presented. For the particular case investigated, a heat transfer enhancement factor of 5 to 6 was calculated

Study on high temperature desulphurization (Part 2). Hydrogen sulphide adsorption and decomposition in the presence of manganese nodules

Energy Technology Data Exchange (ETDEWEB)

Yumura, Motoo; Furimsky, E. (National Chemical Lab. for Industry, Tsukuba, (Japan))

1989-06-29

Manganese nodule, with its large surface area and inclusion of much Fe and Mn, was found to have a high potentiality as an H{sub 2}S desulphurizing agent. Its desulphurization characteristics and reaction with H{sub 2}S were studied to confirm its potentiality as an H{sub 2}S desulphurizing agent. Improvement of its desulphurizing capacity by adding Ca was also attempted. The first stage of the desulphurization is sulphurizing by the agent. After the complete sulphurization, the adsorbent had catalytic effects on H{sub 2}S decomposition. The amount of H{sub 2}S desulphurization of the manganese nodule did not depend on temperature, but the amount of H{sub 2}S decomposition strongly depended on temperature, with the first and a half order respectively. The addition of 10 wt% of CaO to the manganese nodule improved the amount of desulphurization by 30%. The potentiality of the manganese nodule as a desulphurizing agent was verified, and it is suggested that low cost and high performance desulphurizing agents can be developed by adding low cost compounds which have affinity for H{sub 2}S and large surface areas. 11 refs., 4 figs., 2 tabs.

Neutron temporal diagnostic for high-yield deuterium–tritium cryogenic implosions on OMEGA

Energy Technology Data Exchange (ETDEWEB)

Stoeckl, C.; Boni, R.; Ehrne, F.; Forrest, C. J.; Glebov, V. Yu.; Katz, J.; Lonobile, D. J.; Magoon, J.; Regan, S. P.; Shoup, M. J.; Sorce, A.; Sorce, C.; Sangster, T. C.; Weiner, D. [Laboratory for Laser Energetics, University of Rochester, 250 East River Road, Rochester, New York 14623-1299 (United States)

2016-05-15

A next-generation neutron temporal diagnostic (NTD) capable of recording high-quality data for the highest anticipated yield cryogenic deuterium–tritium (DT) implosion experiments was recently installed at the Omega Laser Facility. A high-quality measurement of the neutron production width is required to determine the hot-spot pressure achieved in inertial confinement fusion experiments—a key metric in assessing the quality of these implosions. The design of this NTD is based on a fast-rise-time plastic scintillator, which converts the neutron kinetic energy to 350- to 450-nm-wavelength light. The light from the scintillator inside the nose-cone assembly is relayed ∼16 m to a streak camera in a well-shielded location. An ∼200× reduction in neutron background was observed during the first high-yield DT cryogenic implosions compared to the current NTD installation on OMEGA. An impulse response of ∼40 ± 10 ps was measured in a dedicated experiment using hard x-rays from a planar target irradiated with a 10-ps short pulse from the OMEGA EP laser. The measured instrument response includes contributions from the scintillator rise time, optical relay, and streak camera.

Cryogenic heat transfer

CERN Document Server

Barron, Randall F

2016-01-01

Cryogenic Heat Transfer, Second Edition continues to address specific heat transfer problems that occur in the cryogenic temperature range where there are distinct differences from conventional heat transfer problems. This updated version examines the use of computer-aided design in cryogenic engineering and emphasizes commonly used computer programs to address modern cryogenic heat transfer problems. It introduces additional topics in cryogenic heat transfer that include latent heat expressions; lumped-capacity transient heat transfer; thermal stresses; Laplace transform solutions; oscillating flow heat transfer, and computer-aided heat exchanger design. It also includes new examples and homework problems throughout the book, and provides ample references for further study.

Extraction of manganese from electrolytic manganese residue by bioleaching.

Science.gov (United States)

Xin, Baoping; Chen, Bing; Duan, Ning; Zhou, Changbo

2011-01-01

Extraction of manganese from electrolytic manganese residues using bioleaching was investigated in this paper. The maximum extraction efficiency of Mn was 93% by sulfur-oxidizing bacteria at 4.0 g/l sulfur after bioleaching of 9days, while the maximum extraction efficiency of Mn was 81% by pyrite-leaching bacteria at 4.0 g/l pyrite. The series bioleaching first by sulfur-oxidizing bacteria and followed by pyrite-leaching bacteria evidently promoted the extraction of manganese, witnessing the maximum extraction efficiency of 98.1%. In the case of sulfur-oxidizing bacteria, the strong dissolution of bio-generated sulfuric acid resulted in extraction of soluble Mn2+, while both the Fe2+ catalyzed reduction of Mn4+ and weak acidic dissolution of Mn2+ accounted for the extraction of manganese with pyrite-leaching bacteria. The chemical simulation of bioleaching process further confirmed that the acid dissolution of Mn2+ and Fe2+ catalyzed reduction of Mn4+ were the bioleaching mechanisms involved for Mn extraction from electrolytic manganese residues. Copyright © 2010 Elsevier Ltd. All rights reserved.

Cryogenic immersion microscope

Science.gov (United States)

Le Gros, Mark; Larabell, Carolyn A.

2010-12-14

A cryogenic immersion microscope whose objective lens is at least partially in contact with a liquid reservoir of a cryogenic liquid, in which reservoir a sample of interest is immersed is disclosed. When the cryogenic liquid has an index of refraction that reduces refraction at interfaces between the lens and the sample, overall resolution and image quality are improved. A combination of an immersion microscope and x-ray microscope, suitable for imaging at cryogenic temperatures is also disclosed.

High energy particle detectors utilizing cryogenic charge storage

Energy Technology Data Exchange (ETDEWEB)

Coon, D; Engels, E Jr; Plants, D; Shepard, P F; Yang, Y [Pittsburgh Univ., PA (USA); Sopira, M; Papania, R [Westinghouse Research and Development Labs., Monroeville, PA (USA)

1984-09-15

The mechanism of cryogenic charge storage as a method of particle detection is reviewed. A description of a simple multielement strip detector operated in this mode is given, and partial results on its operating characteristics presented.

Globally sustainable manganese metal production and use.

Science.gov (United States)

Hagelstein, Karen

2009-09-01

The "cradle to grave" concept of managing chemicals and wastes has been a descriptive analogy of proper environmental stewardship since the 1970s. The concept incorporates environmentally sustainable product choices-such as metal alloys utilized steel products which civilization is dependent upon. Manganese consumption is related to the increasing production of raw steel and upgrading ferroalloys. Nonferrous applications of manganese include production of dry-cell batteries, plant fertilizer components, animal feed and colorant for bricks. The manganese ore (high grade 35% manganese) production world wide is about 6 million ton/year and electrolytic manganese metal demand is about 0.7 million ton/year. The total manganese demand is consumed globally by industries including construction (23%), machinery (14%), and transportation (11%). Manganese is recycled within scrap of iron and steel, a small amount is recycled within aluminum used beverage cans. Recycling rate is 37% and efficiency is estimated as 53% [Roskill Metals and Minerals Reports, January 13, 2005. Manganese Report: rapid rise in output caused by Chinese crude steel production. Available from: http://www.roskill.com/reports/manganese.]. Environmentally sustainable management choices include identifying raw material chemistry, utilizing clean production processes, minimizing waste generation, recycling materials, controlling occupational exposures, and collecting representative environmental data. This paper will discuss two electrolytically produced manganese metals, the metal production differences, and environmental impacts cited to date. The two electrolytic manganese processes differ due to the addition of sulfur dioxide or selenium dioxide. Adverse environmental impacts due to use of selenium dioxide methodology include increased water consumption and order of magnitude greater solid waste generation per ton of metal processed. The use of high grade manganese ores in the electrolytic process also

Attenuation capability of low activation-modified high manganese austenitic stainless steel for fusion reactor system

Energy Technology Data Exchange (ETDEWEB)

Eissa, M.M. [Steel Technology Department, Central Metallurgical Research and Development Institute (CMRDI), Helwan (Egypt); El-kameesy, S.U.; El-Fiki, S.A. [Physics Department, Faculty of Science, Ain Shams University, Cairo (Egypt); Ghali, S.N. [Steel Technology Department, Central Metallurgical Research and Development Institute (CMRDI), Helwan (Egypt); El Shazly, R.M. [Physics Department, Faculty of Science, Al-Azhar University, Cairo (Egypt); Saeed, Aly, E-mail: aly_8h@yahoo.com [Nuclear Power station Department, Faculty of Engineering, Egyptian-Russian University, Cairo (Egypt)

2016-11-15

Highlights: • Improvement stainless steel alloys to be used in fusion reactors. • Structural, mechanical, attenuation properties of investigated alloys were studied. • Good agreement between experimental and calculated results has been achieved. • The developed alloys could be considered as candidate materials for fusion reactors. - Abstract: Low nickel-high manganese austenitic stainless steel alloys, SSMn9Ni and SSMn10Ni, were developed to use as a shielding material in fusion reactor system. A standard austenitic stainless steel SS316L was prepared and studied as a reference sample. The microstructure properties of the present stainless steel alloys were investigated using Schaeffler diagram, optical microscopy, and X-ray diffraction pattern. Mainly, an austenite phase was observed for the prepared stainless steel alloys. Additionally, a small ferrite phase was observed in SS316L and SSMn10Ni samples. The mechanical properties of the prepared alloys were studied using Vickers hardness and tensile tests at room temperature. The studied manganese stainless steel alloys showed higher hardness, yield strength, and ultimate tensile strength than SS316L. On the other hand, the manganese stainless steel elongation had relatively lower values than the standard SS316L. The removal cross section for both slow and total slow (primary and those slowed down in sample) neutrons were carried out using {sup 241}Am-Be neutron source. Gamma ray attenuation parameters were carried out for different gamma ray energy lines which emitted from {sup 60}Co and {sup 232}Th radioactive sources. The developed manganese stainless steel alloys had a higher total slow removal cross section than SS316L. While the slow neutron and gamma rays were nearly the same for all studied stainless steel alloys. From the obtained results, the developed manganese stainless steel alloys could be considered as candidate materials for fusion reactor system with low activation based on the short life

Influence of non-metallic inclusions on fatigue strength of high manganese steel

International Nuclear Information System (INIS)

Maekawa, I.; Shibata, H.; Lee, J.H.; Nishida, Shin-ichi

1991-01-01

Six series of high manganese austenitic steel, which contain different inclusion quantity, were prepared. Fatigue experiments, tensile tests and Charpy tests were carried out. Influence of non-metallic inclusion and of temperature on the stress intensity threshold, fatigue crack propagation behavior, elastic-plastic fracture toughness and Charpy value were studied at room temperature and low temperature. In general, strength of this high manganese steel was reduced with increase of inclusion content. Influences of the direction of elongated inclusion with regard to the rolling direction on their strengths were also discussed based on SEM observation and numerical analysis for the stress concentration at a crack tip when an inclusion was near by the tip. According to these results, an inclusion acted as an obstacle to crack propagation for LT specimen. The roughness of fracture surface of ST specimen was larger than that of SL specimen, and the crack growth rate of the former was less than that of the latter. Fatigue life was increased with decrease of temperature, and mechanical parameters such as ΔK th and J 1c were decreased with increase of temperature. The Charpy value decreased clearly with decrease of temperature

The evolution of cryogenic safety at Fermilab

International Nuclear Information System (INIS)

Stanek, R.; Kilmer, J.

1992-12-01

Over the past twenty-five years, Fermilab has been involved in cryogenic technology as it relates to pursuing experimentation in high energy physics. The Laboratory has instituted a strong cryogenic safety program and has maintained a very positive safety record. The solid commitment of management and the cryogenic community to incorporating safety into the system life cycle has led to policies that set requirements and help establish consistency for the purchase and installation of equipment and the safety analysis and documentation

Correlation between airborne manganese concentration at the workstations in the iron foundry and manganese concentration in workers’ blood

Directory of Open Access Journals (Sweden)

Seyedtaghi Mirmohammadi

2017-08-01

Full Text Available Background: Manganese (Mn used as raw material for melting process in the ferrous foundry is considered as hazardous neurotoxic substance because it accumulates in the central nervous system and may cause neurological disorders. The furnace-men and melting department workers are potentially exposed to manganese particles or fume in the workplace. The objective of the research has been to investigate the sources and levels of manganese exposure in the foundry by correlation of blood-manganese (B-Mn and air-manganese (air-Mn measurement. Material and Methods: Air-Mn and Mn of blood serum were measured involving workers who worked in a big-sized foundry during 1 year. The standard method of the Occupational Safety and Health Administration (OSHA ID-121 was used for air and blood assessment and atomic absorption spectroscopy (AAS was carried out for air and blood sample analysis. Results: The air sampling results have revealed that there is a high exposure to manganese (4.5 mg/m3 in the workplace as compared to the National Institute for Occupational Safety and Health’s (NIOSH time weighted average (the reference time-weighted average (TWA = 1 mg/m3. The average blood serum Mn concentration was 2.745 μg/l for subjects working for shorter than 3 months and 274.85 μg/l for subjects working 3–12 months. Conclusions: Against the research hypothesis there was no correlation between the air-Mn concentration and the B-Mn (serum level of manganese in the serum of the exposed subjects. It may be due to short time of air sampling of manganese airborne particles, and a real-time monitoring of airborne manganese particles is suggested for any future study. Med Pr 2017;68(4:449–458

Cryogen Safety Course 8876

Energy Technology Data Exchange (ETDEWEB)

Glass, George [Los Alamos National Lab. (LANL), Los Alamos, NM (United States)

2017-06-13

Cryogenics (from the Greek word κρvoζ, meaning frost or icy cold) is the study of the behavior of matter at very cold temperatures. The purpose of this course is to provide trainees with an introduction to cryogen use, the hazards and potential accidents related to cryogen systems, cryogen safety components, and the requirements that govern the design and use of cryogen systems at Los Alamos National Laboratory (LANL). The knowledge you gain will help you keep your workplace safe for yourself and your coworkers.

Modeling Manganese Sorption and Surface Oxidation During Filtration

OpenAIRE

Bierlein, Kevin Andrew

2012-01-01

Soluble manganese (Mn) is a common contaminant in drinking water sources. High levels of Mn can lead to aesthetic water quality problems, necessitating removal of Mn during treatment to minimize consumer complaints. Mn may be removed during granular media filtration by the â natural greensand effect,â in which soluble Mn adsorbs to manganese oxide-coated (MnOx(s)) media and is then oxidized by chlorine, forming more manganese oxide. This research builds on a previous model developed by Mer...

Experimental investigation of optical fiber temperature sensors at cryogenic temperature and in high magnetic fields

International Nuclear Information System (INIS)

Tanaka, Y.; Ogata, M.; Nagashima, K.; Agawa, H.; Matsuura, S.; Kumagai, Y.

2010-01-01

If it is possible to monitor the conditions in the cryogenic equipments including the super-conducting magnets, the indication of failure can be detected beforehand and the reliability in the operation can improve. Optical fiber temperature sensing is an advantageous method in terms of heat invasion, electric insulation, etc. Therefore, the experiments which confirm the characteristics of optical fiber temperature sensors at cryogenic temperatures and in high magnetic fields were performed, and the possibility of measuring under these conditions was confirmed. However, since the resolution of temperature was a problem, the method of analysis that predicts the measurements was contrived, and the method to improve the problem was examined.

Commissioning the cryogenic system of the first LHC sector

International Nuclear Information System (INIS)

Millet, F.; Claudet, S.; Ferlin, G.; Perin, A.; Riddone, G.; Serio, L.; Soubiran, M.; Tavian, L.; CERN; Ronayette, L.; GHMFL, Grenoble; Rabehl, R.; Fermilab

2007-01-01

The LHC machine, composed of eight sectors with superconducting magnets and accelerating cavities, requires a complex cryogenic system providing high cooling capacities (18 kW equivalent at 4.5 K and 2.4 W at 1.8 K per sector produced in large cold boxes and distributed via 3.3-km cryogenic transfer lines). After individual reception tests of the cryogenic subsystems (cryogen storages, refrigerators, cryogenic transfer lines and distribution boxes) performed since 2000, the commissioning of the cryogenic system of the first LHC sector has been under way since November 2006. After a brief introduction to the LHC cryogenic system and its specificities, the commissioning is reported detailing the preparation phase (pressure and leak tests, circuit conditioning and flushing), the cool-down sequences including the handling of cryogenic fluids, the magnet powering phase and finally the warm-up. Preliminary conclusions on the commissioning of the first LHC sector will be drawn with the review of the critical points already solved or still pending. The last part of the paper reports on the first operational experience of the LHC cryogenic system in the perspective of the commissioning of the remaining LHC sectors and the beam injection test

Spatial and temporal variations of manganese concentrations in drinking water.

Science.gov (United States)

Barbeau, Benoit; Carrière, Annie; Bouchard, Maryse F

2011-01-01

The objective of this study was to assess the variability of manganese concentrations in drinking water (daily, seasonal, spatial) for eight communities who participated in an epidemiological study on neurotoxic effects associated with exposure to manganese in drinking water. We also assessed the performance of residential point-of-use and point-of-entry devices (POE) for reducing manganese concentrations in water. While the total Mn concentrations measured during this study were highly variable depending on the location (manganese concentration for 4 out of 5 sampling locations. The efficiency of reverse osmosis and ion exchange for total Mn removal was consistently high while activated carbon provided variable results. The four POE greensand filters investigated all increased (29 to 199%) manganese concentration, indicating deficient operation and/or maintenance practices. Manganese concentrations in the distribution system were equal or lower than at the inlet, indicating that sampling at the inlet of the distribution system is conservative. The decline in total Mn concentration was linked to higher water residence time in the distribution system.

Failure of manganese to protect from Shiga toxin.

Directory of Open Access Journals (Sweden)

Marsha A Gaston

Full Text Available Shiga toxin (Stx, the main virulence factor of Shiga toxin producing Escherichia coli, is a major public health threat, causing hemorrhagic colitis and hemolytic uremic syndrome. Currently, there are no approved therapeutics for these infections; however manganese has been reported to provide protection from the Stx1 variant isolated from Shigella dysenteriae (Stx1-S both in vitro and in vivo. We investigated the efficacy of manganese protection from Stx1-S and the more potent Stx2a isoform, using experimental systems well-established for studying Stx: in vitro responses of Vero monkey kidney cells, and in vivo toxicity to CD-1 outbred mice. Manganese treatment at the reported therapeutic concentration was toxic to Vero cells in culture and to CD-1 mice. At lower manganese concentrations that were better tolerated, we observed no protection from Stx1-S or Stx2a toxicity. The ability of manganese to prevent the effects of Stx may be particular to certain cell lines, mouse strains, or may only be manifested at high, potentially toxic manganese concentrations.

Insulation design of cryogenic bushing for superconducting electric power applications

Energy Technology Data Exchange (ETDEWEB)

Koo, J.Y., E-mail: koojy@hanyang.ac.kr [Department of Electronics, Electrical, Control and Instrumentation Engineering, Hanyang University, Ansan 426-791 (Korea, Republic of); Lee, Y.J.; Shin, W.J.; Kim, Y.H. [Department of Electronics, Electrical, Control and Instrumentation Engineering, Hanyang University, Ansan 426-791 (Korea, Republic of); Kim, J.T. [Department of Electrical Engineering, Daejin University, Pocheon 487-711 (Korea, Republic of); Lee, B.W. [Department of Electronics, Electrical, Control and Instrumentation Engineering, Hanyang University, Ansan 426-791 (Korea, Republic of); Lee, S.H., E-mail: k720lsh@kins.re.kr [Expert Group Electric and Control Department, Korea Institute of Nuclear Safety, Daejeon 305-600 (Korea, Republic of)

2013-01-15

Highlights: ► In this paper, design factors of cryogenic bushings were discussed and test results of specimen were introduced in detail. ► We focused on the comparative study of breakdown characteristics of different electrode materials. ► Puncture and creepage breakdown characteristics were analyzed based on the withstand voltage. ► We obtained the basic design factors of extra high voltage condenser bushing. ► We obtained the basic design factors of extra high voltage condenser bushing, which could be used in cryogenic environment. -- Abstract: Recently, the superconductivity projects to develop commercial superconducting devices for extra high voltage transmission lines have been undergoing in many countries. One of the critical components to be developed for high voltage superconducting devices, including superconducting transformers, cables, and fault current limiters, is a high voltage bushing, to supply high current to devices without insulating difficulties, that is designed for cryogenic environments. Unfortunately, suitable bushings for HTS equipment were not fully developed for some cryogenic insulation issues. Such high voltage bushings would need to provide electrical insulation capabilities from room temperature to cryogenic temperatures. In this paper, design factors of cryogenic bushings were discussed and test results of specimen were introduced in detail. First, the dielectric strength of three kinds of metals has been measured with uniform and non-uniform electrodes by withstand voltage of impulse and AC breakdown test in LN{sub 2}. Second, puncture breakdown voltage of glass fiber reinforced plastics (GFRPs) plates has been analyzed with non-uniform electrodes. Finally, creepage discharge voltages were measured according to the configuration of non-uniform and uniform electrode on the FRP plate. From the test results, we obtained the basic design factors of extra high voltage condenser bushing, which could be used in cryogenic

Development of Small-Volume, High-Precision, and Reliable Cryogenic Linear Actuators by Using Novel Intermetallic Compounds

Data.gov (United States)

National Aeronautics and Space Administration — Space missions often involve ultra-cold environments, and cryogenic actuators must be mechanically robust for long-term cyclic work, generate high power per volume,...

Voltammetric determination of arsenic in high iron and manganese groundwaters.

Science.gov (United States)

Gibbon-Walsh, Kristoff; Salaün, Pascal; Uroic, M Kalle; Feldmann, Joerg; McArthur, John M; van den Berg, Constant M G

2011-09-15

Determination of the speciation of arsenic in groundwaters, using cathodic stripping voltammetry (CSV), is severely hampered by high levels of iron and manganese. Experiments showed that the interference is eliminated by addition of EDTA, making it possible to determine the arsenic speciation on-site by CSV. This work presents the CSV method to determine As(III) in high-iron or -manganese groundwaters in the field with only minor sample treatment. The method was field-tested in West-Bengal (India) on a series of groundwater samples. Total arsenic was subsequently determined after acidification to pH 1 by anodic stripping voltammetry (ASV). Comparative measurements by ICP-MS as reference method for total As, and by HPLC for its speciation, were used to corroborate the field data in stored samples. Most of the arsenic (78±0.02%) was found to occur as inorganic As(III) in the freshly collected waters, in accordance with previous studies. The data shows that the modified on-site CSV method for As(III) is a good measure of water contamination with As. The EDTA was also found to be effective in stabilising the arsenic speciation for longterm sample storage at room temperature. Without sample preservation, in water exposed to air and sunlight, the As(III) was found to become oxidised to As(V), and Fe(II) oxidised to Fe(III), removing the As(V) by adsorption on precipitating Fe(III)-hydroxides within a few hours. Copyright © 2011 Elsevier B.V. All rights reserved.

Simultaneous stripping recovery of ammonia-nitrogen and precipitation of manganese from electrolytic manganese residue by air under calcium oxide assist.

Science.gov (United States)

Chen, Hongliang; Liu, Renlong; Shu, Jiancheng; Li, Wensheng

2015-01-01

Leaching tests of electrolytic manganese residue (EMR) indicated that high contents of soluble manganese and ammonia-nitrogen posed a high environmental risk. This work reports the results of simultaneous stripping recovery of ammonia-nitrogen and precipitation of manganese by air under calcium oxide assist. The ammonia-nitrogen stripping rate increased with the dosage of CaO, the air flow rate and the temperature of EMR slurry. Stripped ammonia-nitrogen was absorbed by a solution of sulfuric acid and formed soluble (NH4)2SO4 and (NH4)3H(SO4)3. The major parameters that effected soluble manganese precipitation were the dosage of added CaO and the slurry temperature. Considering these two aspects, the efficient operation conditions should be conducted with 8 wt.% added CaO, 60°C, 800 mL min(-1) air flow rate and 60-min reaction time. Under these conditions 99.99% of the soluble manganese was precipitated as Mn3O4, which was confirmed by XRD and SEM-EDS analyses. In addition, the stripping rate of ammonia-nitrogen was 99.73%. Leaching tests showed the leached toxic substances concentrations of the treated EMR met the integrated wastewater discharge standard of China (GB8978-1996).

Advances in cryogenic engineering. Volume 27 - Proceedings of the Cryogenic Engineering Conference, San Diego, CA, August 11-14, 1981

Science.gov (United States)

Fast, R. W.

Applications of superconductivity are considered, taking into account MHD and fusion, generators, transformers, transmission lines, magnets for physics, cryogenic techniques, electrtronics, and aspects of magnet stability. Advances related to heat transfer in He I are discussed along with subjects related to theat transfer in He II, refrigeration of superconducting systems, refrigeration and liquefaction, dilution and magnetic refrigerators, refrigerators for space applications, mass transfer and flow phenomena, and the properties of fluids. Developments related to cryogenic applications are also explored, giving attention to bulk storage and transfer of cryogenic fluids, liquefied natural gas operations, space science and technology, and cryopumping. Topics related to cryogenic instrumentation and controls include the production and use of high grade silicon diode temperature sensors, the choice of strain gages for use in a large superconducting alternator, microprocessor control of cryogenic pressure, and instrumentation, data acquisition and reduction for a large spaceborne helium dewar. For individual items see A83-43221 to A83-43250

Cryogenic System for a High-Temperature Superconducting Power Transmission Cable

International Nuclear Information System (INIS)

Demko, J.A.; Gouge, M.J.; Hughey, R.L.; Lue, J.W.; Martin, R.; Sinha, U.; Stovall, J.P.

1999-01-01

High-temperature superconducting (HTS) cable systems for power transmission are under development that will use pressurized liquid nitrogen to provide cooling of the cable and termination hardware. Southwire Company and Oak Ridge National Laboratory have been operating a prototype HTS cable system that contains many of the typical components needed for a commercial power transmission application. It is being used to conduct research in the development of components and systems for eventual commercial deployment. The cryogenic system was built by Air Products and Chemicals, Allentown, Pennsylvania, and can circulate up to 0.35 kg/s of liquid nitrogen at temperatures as low as 67 K at pressures of 1 to 10 bars. Sufficient cooling is provided for testing a 5-m-long HTS transmission cable system that includes the terminations required for room temperature electrical connections. Testing of the 5-m HTS transmission cable has been conducted at the design ac conditions of 1250 A and 7.5 kV line to ground. This paper contains a description of the essential features of the HTS cable cryogenic system and performance results obtained during operation of the system. The salient features of the operation that are important in large commercial HTS cable applications will be discussed

Role of manganese in the resistance of Micrococcus radiodurans to ionizing radiation

International Nuclear Information System (INIS)

Wierowski, J.V.

1980-01-01

Micrococcus radiodurans possesses a very high level of intracellular manganese compared to other organisms. This manganese content has previously been shown to participate in the exceptional ulraviolet radiation resistance of M. radiodurans. This study was undertaken to determine the role of manganese in the ionizing radiation resistant of M. radiodurans. The results indicate that manganese is essential for DNA degradation to occur during irradiation. Manganese has also proven essential for the second phase of post-irradiation thymine base damage removal. These factors work together to increase the rate of recovery from radiation damage, which is reflected in a larger Dq, D 37 and exponential portion of the survival curve of high Mn-grown cells

Manganese contents of soils as determined by activation analysis

International Nuclear Information System (INIS)

El-Kholi, A.F.; Hamdy, A.A.; Al Metwally, A.I.; El-Damaty, A.H.

1976-01-01

The object of this investigation is to determine total manganese by means of neutron activation analysis and evaluate this technique in comparison with the corresponding data obtained by conventional chemical analysis. Data obtained revealed that the values of total manganese in calcareous soils obtained by both chemical analysis and that by neutron activation analysis were similar. Therefore, activation analysis could be recommended as a quick laboratory, less tedious, and time consuming method for the determination of Mn content in both soils and plants than the conventional chemical techniques due to its great specificity, sensitivity and simplicity. Statistical analysis showed that there is a significant correlation at 5% probability level between manganese content in Soybean plant and total manganese determined by activation and chemical analysis giving the evidence that in the case of those highly calcareous soils of low total manganese content this fraction has to be considered as far as available soil manganese is concerned

Manganese Catalyzed C–H Halogenation

Energy Technology Data Exchange (ETDEWEB)

Liu, Wei; Groves, John T.

2015-06-16

The remarkable aliphatic C–H hydroxylations catalyzed by the heme-containing enzyme, cytochrome P450, have attracted sustained attention for more than four decades. The effectiveness of P450 enzymes as highly selective biocatalysts for a wide range of oxygenation reactions of complex substrates has driven chemists to develop synthetic metalloporphyrin model compounds that mimic P450 reactivity. Among various known metalloporphyrins, manganese derivatives have received considerable attention since they have been shown to be versatile and powerful mediators for alkane hydroxylation and olefin epoxidation. Mechanistic studies have shown that the key intermediates of the manganese porphyrin-catalyzed oxygenation reactions include oxo- and dioxomanganese(V) species that transfer an oxygen atom to the substrate through a hydrogen abstraction/oxygen recombination pathway known as the oxygen rebound mechanism. Application of manganese porphyrins has been largely restricted to catalysis of oxygenation reactions until recently, however, due to ultrafast oxygen transfer rates. In this Account, we discuss recently developed carbon–halogen bond formation, including fluorination reactions catalyzed by manganese porphyrins and related salen species. We found that biphasic sodium hypochlorite/manganese porphyrin systems can efficiently and selectively convert even unactivated aliphatic C–H bonds to C–Cl bonds. An understanding of this novel reactivity derived from results obtained for the oxidation of the mechanistically diagnostic substrate and radical clock, norcarane. Significantly, the oxygen rebound rate in Mn-mediated hydroxylation is highly correlated with the nature of the trans-axial ligands bound to the manganese center (L–Mn^V$=$O). Based on the ability of fluoride ion to decelerate the oxygen rebound step, we envisaged that a relatively long-lived substrate radical could be trapped by a Mn–F fluorine source, effecting carbon–fluorine bond

Coupled Cryogenic Thermal and Electrical Models for Transient Analysis of Superconducting Power Devices with Integrated Cryogenic Systems

Science.gov (United States)

Satyanarayana, S.; Indrakanti, S.; Kim, J.; Kim, C.; Pamidi, S.

2017-12-01

Benefits of an integrated high temperature superconducting (HTS) power system and the associated cryogenic systems on board an electric ship or aircraft are discussed. A versatile modelling methodology developed to assess the cryogenic thermal behavior of the integrated system with multiple HTS devices and the various potential configurations are introduced. The utility and effectiveness of the developed modelling methodology is demonstrated using a case study involving a hypothetical system including an HTS propulsion motor, an HTS generator and an HTS power cable cooled by an integrated cryogenic helium circulation system. Using the methodology, multiple configurations are studied. The required total cooling power and the ability to maintain each HTS device at the required operating temperatures are considered for each configuration and the trade-offs are discussed for each configuration. Transient analysis of temperature evolution in the cryogenic helium circulation loop in case of a system failure is carried out to arrive at the required critical response time. The analysis was also performed for a similar liquid nitrogen circulation for an isobaric condition and the cooling capacity ratio is used to compare the relative merits of the two cryogens.

Weld Metallurgy and Mechanical Properties of High Manganese Ultra-high Strength Steel Dissimilar Welds

Science.gov (United States)

Dahmen, Martin; Lindner, Stefan; Monfort, Damien; Petring, Dirk

The increasing demand for ultra-high strength steels in vehicle manufacturing leads to the application of new alloys. This poses a challenge on joining especially by fusion welding. A stainless high manganese steel sheet with excellent strength and deformation properties stands in the centre of the development. Similar and dissimilar welds with a metastable austenitic steel and a hot formed martensitic stainless steel were performed. An investigation of the mixing effects on the local microstructure and the hardness delivers the metallurgical features of the welds. Despite of carbon contents above 0.4 wt.% none of the welds have shown cracks. Mechanical properties drawn from tensile tests deliver high breaking forces enabling a high stiffness of the joints. The results show the potential for the application of laser beam welding for joining in assembly of structural parts.

Effects of cryogen spray cooling and high radiant exposures on selective vascular injury during laser irradiation of human skin.

Science.gov (United States)

Tunnell, James W; Chang, David W; Johnston, Carol; Torres, Jorge H; Patrick, Charles W; Miller, Michael J; Thomsen, Sharon L; Anvari, Bahman

2003-06-01

Increasing radiant exposure offers a means to increase treatment efficacy during laser-mediated treatment of vascular lesions, such as port-wine stains; however, excessive radiant exposure decreases selective vascular injury due to increased heat generation within the epidermis and collateral damage to perivascular collagen. To determine if cryogen spray cooling could be used to maintain selective vascular injury (ie, prevent epidermal and perivascular collagen damage) when using high radiant exposures (16-30 J/cm2). Observational study. Academic hospital and research laboratory. Twenty women with normal abdominal skin (skin phototypes I-VI). Skin was irradiated with a pulsed dye laser (wavelength = 585 nm; pulse duration = 1.5 milliseconds; 5-mm-diameter spot) using various radiant exposures (8-30 J/cm2) without and with cryogen spray cooling (50- to 300-millisecond cryogen spurts). Hematoxylin-eosin-stained histologic sections from each irradiated site were examined for the degree of epidermal damage, maximum depth of red blood cell coagulation, and percentage of vessels containing perivascular collagen coagulation. Long cryogen spurt durations (>200 milliseconds) protected the epidermis in light-skinned individuals (skin phototypes I-IV) at the highest radiant exposure (30 J/cm2); however, epidermal protection could not be achieved in dark-skinned individuals (skin phototypes V-VI) even at the lowest radiant exposure (8 J/cm2). The red blood cell coagulation depth increased with increasing radiant exposure (to >2.5 mm for skin phototypes I-IV and to approximately 1.2 mm for skin phototypes V-VI). In addition, long cryogen spurt durations (>200 milliseconds) prevented perivascular collagen coagulation in all skin types. Cryogen spurt durations much longer than those currently used in therapy (>200 milliseconds) may be clinically useful for protecting the epidermis and perivascular tissues when using high radiant exposures during cutaneous laser therapies

Guidelines for etching silicon MEMS structures using fluorine high-density plasmas at cryogenic temperatures

NARCIS (Netherlands)

de Boer, Meint J.; Gardeniers, Johannes G.E.; Jansen, Henricus V.; Gilde, M.J.; Roelofs, Gerard; Sasserath, Jay N.; Elwenspoek, Michael Curt

This paper presents guidelines for the deep reactive ion etching (DRIE) of silicon MEMS structures, employing SF6/O2-based high-density plasmas at cryogenic temperatures. Procedures of how to tune the equipment for optimal results with respect to etch rate and profile control are described. Profile

Tests of industrial ethylene-propylene rubber high voltage cable for cryogenic use

CERN Document Server

Balhan, B; Goddard, B; Muratori, G; Otwinowski, S; Rieubland, Jean Michel; Wang, H; CERN. Geneva. SPS and LEP Division

1999-01-01

At the beginning of 1999 UCLA has received a prototype High Voltage Cryogenic Cable supplied fee of charge by Pirelli. The cable is intended for more than ten years of service at 100 kV D.C. and liquid argon temperature. Thecable uses an all welded construction, whichi is axially tight and free of ionizable voids. The cable was submitted to a number of mechanical and electrical tests as described below.

Nanostructured manganese oxide thin films as electrode material for supercapacitors

Science.gov (United States)

Xia, Hui; Lai, Man On; Lu, Li

2011-01-01

Electrochemical capacitors, also called supercapacitors, are alternative energy storage devices, particularly for applications requiring high power densities. Recently, manganese oxides have been extensively evaluated as electrode materials for supercapacitors due to their low cost, environmental benignity, and promising supercapacitive performance. In order to maximize the utilization of manganese oxides as the electrode material for the supercapacitors and improve their supercapacitive performance, the nanostructured manganese oxides have therefore been developed. This paper reviews the synthesis of the nanostructured manganese oxide thin films by different methods and the supercapacitive performance of different nanostructures.

Analysis and Design of Cryogenic Pressure Vessels for Automotive Hydrogen Storage

Science.gov (United States)

Espinosa-Loza, Francisco Javier

Cryogenic pressure vessels maximize hydrogen storage density by combining the high pressure (350-700 bar) typical of today's composite pressure vessels with the cryogenic temperature (as low as 25 K) typical of low pressure liquid hydrogen vessels. Cryogenic pressure vessels comprise a high-pressure inner vessel made of carbon fiber-coated metal (similar to those used for storage of compressed gas), a vacuum space filled with numerous sheets of highly reflective metalized plastic (for high performance thermal insulation), and a metallic outer jacket. High density of hydrogen storage is key to practical hydrogen-fueled transportation by enabling (1) long-range (500+ km) transportation with high capacity vessels that fit within available spaces in the vehicle, and (2) reduced cost per kilogram of hydrogen stored through reduced need for expensive structural material (carbon fiber composite) necessary to make the vessel. Low temperature of storage also leads to reduced expansion energy (by an order of magnitude or more vs. ambient temperature compressed gas storage), potentially providing important safety advantages. All this is accomplished while simultaneously avoiding fuel venting typical of cryogenic vessels for all practical use scenarios. This dissertation describes the work necessary for developing and demonstrating successive generations of cryogenic pressure vessels demonstrated at Lawrence Livermore National Laboratory. The work included (1) conceptual design, (2) detailed system design (3) structural analysis of cryogenic pressure vessels, (4) thermal analysis of heat transfer through cryogenic supports and vacuum multilayer insulation, and (5) experimental demonstration. Aside from succeeding in demonstrating a hydrogen storage approach that has established all the world records for hydrogen storage on vehicles (longest driving range, maximum hydrogen storage density, and maximum containment of cryogenic hydrogen without venting), the work also

Manganese (II) induces chemical hypoxia by inhibiting HIF-prolyl hydroxylase: Implication in manganese-induced pulmonary inflammation

International Nuclear Information System (INIS)

Han, Jeongoh; Lee, Jong-Suk; Choi, Daekyu; Lee, Youna; Hong, Sungchae; Choi, Jungyun; Han, Songyi; Ko, Yujin; Kim, Jung-Ae; Mi Kim, Young; Jung, Yunjin

2009-01-01

Manganese (II), a transition metal, causes pulmonary inflammation upon environmental or occupational inhalation in excess. We investigated a potential molecular mechanism underlying manganese-induced pulmonary inflammation. Manganese (II) delayed HIF-1α protein disappearance, which occurred by inhibiting HIF-prolyl hydroxylase (HPH), the key enzyme for HIF-1α hydroxylation and subsequent von Hippel-Lindau(VHL)-dependent HIF-1α degradation. HPH inhibition by manganese (II) was neutralized significantly by elevated dose of iron. Consistent with this, the induction of cellular HIF-1α protein by manganese (II) was abolished by pretreatment with iron. Manganese (II) induced the HIF-1 target gene involved in pulmonary inflammation, vascular endothelial growth factor (VEGF), in lung carcinoma cell lines. The induction of VEGF was dependent on HIF-1. Manganese-induced VEGF promoted tube formation of HUVEC. Taken together, these data suggest that HIF-1 may be a potential mediator of manganese-induced pulmonary inflammation

Synchrotron micro-diffraction analysis of the microstructure of cryogenically treated high performance tool steels prior to and after tempering

Energy Technology Data Exchange (ETDEWEB)

Xu, N.; Cavallaro, G.P. [Applied Centre for Structural and Synchrotron Studies, Mawson Lakes Blvd, University of South Australia, Mawson Lakes, South Australia 5095 (Australia); Gerson, A.R., E-mail: Andrea.Gerson@unisa.edu.au [Applied Centre for Structural and Synchrotron Studies, Mawson Lakes Blvd, University of South Australia, Mawson Lakes, South Australia 5095 (Australia)

2010-10-15

The phase transformation and strain changes within cryogenically (-196 deg. C) treated high performance tool steels (AISI H13) before and after tempering have been examined using both laboratory XRD and synchrotron micro-diffraction. The martensitic unit cell was found to have very low tetragonality as expected for low carbon steel. Tempering resulted in the diffusion of excess carbon out of the martensite phase and consequent unit cell shrinkage. In addition on tempering the martensite became more homogeneous as compared to the same samples prior to tempering. For cryogenically treated samples, the effect was most pronounced for the rapidly cooled sample which was the least homogenous sample prior to tempering but was the most homogenous sample after tempering. This suggests that the considerable degree of disorder resulting from rapid cryogenic cooling results in the beneficial release of micro-stresses on tempering thus possibly resulting in the improved wear resistance and durability observed for cryogenically treated tool steels.

Synchrotron micro-diffraction analysis of the microstructure of cryogenically treated high performance tool steels prior to and after tempering

International Nuclear Information System (INIS)

Xu, N.; Cavallaro, G.P.; Gerson, A.R.

2010-01-01

The phase transformation and strain changes within cryogenically (-196 deg. C) treated high performance tool steels (AISI H13) before and after tempering have been examined using both laboratory XRD and synchrotron micro-diffraction. The martensitic unit cell was found to have very low tetragonality as expected for low carbon steel. Tempering resulted in the diffusion of excess carbon out of the martensite phase and consequent unit cell shrinkage. In addition on tempering the martensite became more homogeneous as compared to the same samples prior to tempering. For cryogenically treated samples, the effect was most pronounced for the rapidly cooled sample which was the least homogenous sample prior to tempering but was the most homogenous sample after tempering. This suggests that the considerable degree of disorder resulting from rapid cryogenic cooling results in the beneficial release of micro-stresses on tempering thus possibly resulting in the improved wear resistance and durability observed for cryogenically treated tool steels.

Effects of dietary manganese contents on 54Mn metabolism in mice

International Nuclear Information System (INIS)

Sato, I.; Matsusaka, N.; Kobayashi, H.; Nishimura, Y.

1996-01-01

Several parameters of 54 Mn metabolism were noted in mice maintained on diets with manganese contents of 80 to 8000 mg/kg. Excretion of 54 Mn was promoted as the dietary manganese contents increased. Clearance of 54 Mn from the liver, kidneys, pancreas, and spleen was markedly accelerated by feeding mice a high-manganese diet, but clearance from the muscles, femurs, and brain was relatively insensitive to the dietary manganese. Manganese concentrations in the tissue were regulated homoestatically upto the dietary manganese content of 2400 mg/kg, but marked accumulations of manganese occurred when mice were given 8000 mg/kg diet. No toxic symptoms were found up to the 2400 mg/kg diet, but consumption of the 8000 mg/kg diet was less than for other diets. These results suggest that an oral intake of excess manganese is effective for promoting the excretion of 54 Mn from a body contaminated with this isotope. (author)

Status of the Cryogenic Storage Ring (CSR)

Energy Technology Data Exchange (ETDEWEB)

Menk, Sebastian; Becker, Arno; Berg, Felix; Blaum, Klaus; Fellenberger, Florian; Froese, Michael; Goullon, Johannes; Grieser, Manfred; Krantz, Claude; Lange, Michael; Laux, Felix; Repnow, Roland; Schornikov, Andrey; Hahn, Robert von; Wolf, Andreas [Max-Planck-Institut fuer Kernphysik (MPIK), 69117 Heidelberg (Germany); Spruck, Kaija [Institut fuer Atom- und Molekuelphysik Justus-Liebig-Universitaet, 35392 Giessen (Germany)

2012-07-01

A novel cryogenic storage ring is currently under construction at the MPIK. By electrostatic ion optical elements, the 35 m circumference Cryogenic Storage Ring will be able to store ions at energies of up to 300 keV per charge unit without any mass limitations. The CSR consists of a cryogenic ({proportional_to}5 K) beam pipe surrounded by two radiation shields (40 and 80 K) in a large outer, thermal insulation vacuum. Extreme vacuum (density {proportional_to}10{sup 3} cm{sup -3}) will be achieved by 2 K cryopumping as demonstrated in a prototype ion beam trap. The ion optics was completely assembled within the precision cryogenic mounting and shielding structure of the first corner. There, cooldown tests to {proportional_to}40 K were performed which confirmed the required sub-millimeter accuracy of the specially designed electrode positioning under large temperature changes. The high-voltage connections to the cryogenic electrodes were installed and breakdown tests will be reported. Based on the test results the beam pipe, electrode mounting and shielding structures are under final construction for mounting during 2012.

Multiparameter Flowfield Measurements in High-Pressure, Cryogenic Environments Using Femtosecond Lasers

Science.gov (United States)

Burns, Ross A.; Danehy, Paul M.; Peters, Christopher J.

2016-01-01

Femtosecond laser electronic excitation tagging (FLEET) and Rayleigh scattering (RS) from a femtosecond laser are demonstrated in the NASA Langley 0.3-m Transonic Cryogenic Tunnel (TCT). The measured signals from these techniques are examined for their thermodynamic dependencies in pure nitrogen. The FLEET signal intensity and signal lifetimes are found to scale primarily with the gas density, as does the RS signal. Several models are developed, which capture these physical behaviors. Notably, the FLEET and Rayleigh scattering intensities scale linearly with the flow density, while the FLEET signal decay rates are a more complex function of the thermodynamic state of the gas. The measurement of various flow properties are demonstrated using these techniques. While density was directly measured from the signal intensities and FLEET signal lifetime, temperature and pressure were measured using the simultaneous FLEET velocity measurements while assuming the flow had a constant total enthalpy. Measurements of density, temperature, and pressure from the FLEET signal are made with accuracies as high as 5.3 percent, 0.62 percent, and 6.2 percent, respectively, while precisions were approximately 10 percent, 0.26 percent, and 11 percent for these same quantities. Similar measurements of density from Rayleigh scattering showed an overall accuracy of 3.5 percent and a precision of 10.2 percent over a limited temperature range (T greater than 195 K). These measurements suggest a high degree of utility at using the femtosecond-laser based diagnostics for making multiparameter measurements in high-pressure, cryogenic environments such as large-scale TCT facilities.

Cryogenics theory, processes and applications

CERN Document Server

Hayes, Allyson E

2011-01-01

Cryogenics is the study of the production of very low temperature (below -150 -C, -238 -F or 123 K) and the behaviour of materials at those temperatures. This book presents current research from across the globe in the study of cryogenics, including the effect of cryogenic treatment on microstructure and mechanical properties of light weight alloys; the application of Fiber Bragg grating sensors at cryogenic temperatures; cryogenic grinding; liquid oxygen magnetohydrodynamics; and, genetic engineering techniques used to improve tolerance to cryopreservation.

Solid-cryogen-stabilized, cable-in-conduit (CIC) superconducting cables

Science.gov (United States)

Voccio, J. P.; Michael, P. C.; Bromberg, L.; Hahn, S.

2015-12-01

This paper considers the use of a solid cryogen as a means to stabilize, both mechanically and thermally, magnesium diboride (MgB2) superconducting strands within a dual-channel cable-in-conduit (CIC) cable for use in AC applications, such as a generator stator winding. The cable consists of two separate channels; the outer channel contains the superconducting strands and is filled with a fluid (liquid or gas) that becomes solid at the device operating temperature. Several options for fluid will be presented, such as liquid nitrogen, hydrocarbons and other chlorofluorocarbons (CFCs) that have a range of melting temperatures and volumetric expansions (from solid at operating temperature to fixed volume at room temperature). Implications for quench protection and conductor stability, enhanced through direct contact with the solid cryogen, which has high heat capacity and thermal conductivity (compared with helium gas), will be presented. Depending on the cryogen, the conductor will be filled initially either with liquid at atmospheric conditions or a gas at high pressure (∼100 atm). After cooldown, the cryogen in the stranded-channel will be solid, essentially locking the strands in place, preventing strand motion and degradation due to mechanical deformation while providing enhanced thermal capacity for stability and protection. The effect of cryogen porosity is also considered. The relatively high heat capacity of solid cryogens at these lower temperatures (compared to gaseous helium) enhances the thermal stability of the winding. During operation, coolant flow through the open inner channel will minimize pressure drop.

Designs of pulsed power cryogenic transformers

International Nuclear Information System (INIS)

Singh, S.K.; Heyne, C.J.; Hackowrth, D.T.; Shestak, E.J.; Eckels, P.W.; Rogers, J.D.

1988-01-01

The Westinghouse Electric Corporation has completed designs of three pulsed power cryogenic transformers of three pulsed power cryogenic transformers for the Los Alamos National Laboratory. These transformers will be configured to transfer their stored energy sequentially to an electro-magnetic launcher and form a three-stage power supply. The pulse transformers will act as two winding energy storage solenoids which provide a high current and energy pulse compression by transforming a 50 kA power supply into a megamp level power supply more appropriate for the electromagnetic launcher duty. This system differs from more traditional transformer applications in that significant current levels do not exists simultaneously in the two windings of the pulse transformer. This paper describes the designs of the pulsed power cryogenic transformers

Effect of manganese on neonatal rat: manganese distribution in vital organs

Energy Technology Data Exchange (ETDEWEB)

Husain, R; Mushtaq, M; Seth, P K; Chandra, S V

1976-01-01

At present very little is known about the effect of manganese on the early stage of life, though the metal poisoning in adult humans and experimental animals has been known for quite some time. The possibility of the exposure of the general public to the deleterious effects of the metal through the environmental contamination resulting from its increasing industrial applications, and the use of Methyl Cyclopentadienyl Manganese Tricarbonyl (MMT) in gasoline and motor fuel, points to the need for such an information. Our recent studies in this direction have shown that manganese exposed nursing dams can transfer significant amounts of the metal via maternal milk of their sucklings and the brain of the latter exhibited marked enzymatic alterations. The present communication deals with the distribution of manganese in the vital organs of rat pups nursing on mothers receiving the metal orally.

Energy Efficient Cryogenics

Science.gov (United States)

Meneghelli, Barry J.; Notardonato, William; Fesmire, James E.

2016-01-01

The Cryogenics Test Laboratory, NASA Kennedy Space Center, works to provide practical solutions to low-temperature problems while focusing on long-term technology targets for the energy-efficient use of cryogenics on Earth and in space.

Introduction to cryogenic engineering

CERN Multimedia

CERN. Geneva; Vandoni, Giovanna; Niinikoski, Tapio O

2005-01-01

Cryogenic engineering is one of the key technologies at CERN. It is widely used in research and has many applications in industry and last but not least in medicine. In research cryogenic engineering and its applications are omnipresent from the smallest laboratories to fusion reactors, hughe detectors and accelerators. With the termination of the LHC, CERN will in fact become the world's largest cryogenic installation. This series of talks intends to introduce the non-cryogenist to the basic principles and challenges of cryogenic engineering and its applications. The course will also provide a basis for practical application as well as for further learning.

Effect of manganese on neonatal rat: manganese concentration and enzymatic alterations in brain

Energy Technology Data Exchange (ETDEWEB)

Seth, P K; Husain, R; Mushtaq, M; Chandra, S V

1977-01-01

Suckling rats were exposed for 15 and 30 days to manganese through the milk of nursing dams receiving 15 mg MnCl/sub 2/.4H/sub 2/O/kg/day orally and after which the neurological manifestations of metal poisoning were studied. No significant differences in the growth rate, developmental landmarks and walking movements were observed between the control and manganese-exposed pups. The metal concentration was significantly increased in the brain of manganese-fed pups at 15 days and exhibited a further three-fold increase over the control, at 30 days. The accumulation of the metal in the brain of manganese-exposed nursing dams was comparatively much less. A significant decrease in succinic dehydrogenase, adenosine triphosphatase, adenosine deaminase, acetylcholine esterase and an increase in monoamine oxidase activity was observed in the brain of experimental pups and dams. The results suggest that the developing brain may also be susceptible to manganese.

Proceedings of the 26th International Cryogenic Engineering Conference - International Cryogenic Material Conference 2016

Science.gov (United States)

Datta, T. S.; Sharma, R. G.; Kar, S.

2017-02-01

Session There were 6 plenary talks delivered by the eminent scientist/ technologists. The topics on which these talks were delivered were Cryogenics for Indian Space Programme, The Cold Chain, Super-fluid Cooling Technology, Review on Superconducting Materials in China, Review on Cryogenics and Superconductivity for present day MRI and finally the Mendelssohn Award lecture on the 50 years of Cryogenics and Superconductivity for High Energy Physics. Other than the plenary talks, there were 102 oral presentations covered in 18 technical sessions, out of which 21 were Invited Talks. Each session was dedicated to a specific topic like Large Scale Cryogenics, Cryogenics for Accelerators, Fusion and Space, Cryocoolers, Heat Transfer, Cryogenic Instrumentation, Superconducting Materials, Superconducting Magnets & Cavities, Power Applications, LNG & Safety etc. In addition to oral presentations there were three poster sessions spread over three days and a total of 250 posters were displayed. 4. Award Session There was a dedicated session on Award Ceremony. Dr Haishan Cao, post doctoral researcher at the University of Twente, The Netherlands received the 2016 Klipping Award for his work on Micro-machined Joule-Thomson coolers. The ICMC Cryogenic Material Awardee for Excellence (2016) was Prof. Kazumasa Iida, Department of Crystalline Materials Science, Graduate School of Engineering, Nagoya University. Japan. The paper published in ” Cryogenics 72 (2015), p 111-121 by J. Bartlett, G. Hardy, and I.D. Hepburn, titled “Performance of a fast response miniature Adiabatic Demagnetization Refrigerator using a single crystal tungsten magneto resistive heat switch” was selected for the best paper award. The prestigious 2016 Mendelssohn Award was given to Dr. Philippe Lebrun of CERN, Geneva, Switzerland for his life-long contribution to Cryogenics and Superconductivity for accelerator programme. Each awardees was also presented with a complimentary book from Springer Nature through

MFTF magnet cryogenics

International Nuclear Information System (INIS)

VanSant, J.H.

1981-07-01

The prime requirement of the cryogenics of the magnets is to assure a superconducting state for the magnet coils, a large task considering their enormous size. The following presentation addresses the principal topics that have been considered in this cryogenic design

The Escherichia coli small protein MntS and exporter MntP optimize the intracellular concentration of manganese.

Directory of Open Access Journals (Sweden)

Julia E Martin

2015-03-01

Full Text Available Escherichia coli does not routinely import manganese, but it will do so when iron is unavailable, so that manganese can substitute for iron as an enzyme cofactor. When intracellular manganese levels are low, the cell induces the MntH manganese importer plus MntS, a small protein of unknown function; when manganese levels are high, the cell induces the MntP manganese exporter and reduces expression of MntH and MntS. The role of MntS has not been clear. Previous work showed that forced MntS synthesis under manganese-rich conditions caused bacteriostasis. Here we find that when manganese is scarce, MntS helps manganese to activate a variety of enzymes. Its overproduction under manganese-rich conditions caused manganese to accumulate to very high levels inside the cell; simultaneously, iron levels dropped precipitously, apparently because manganese-bound Fur blocked the production of iron importers. Under these conditions, heme synthesis stopped, ultimately depleting cytochrome oxidase activity and causing the failure of aerobic metabolism. Protoporphyrin IX accumulated, indicating that the combination of excess manganese and iron deficiency had stalled ferrochelatase. The same chain of events occurred when mutants lacking MntP, the manganese exporter, were exposed to manganese. Genetic analysis suggested the possibility that MntS exerts this effect by inhibiting MntP. We discuss a model wherein during transitions between low- and high-manganese environments E. coli uses MntP to compensate for MntH overactivity, and MntS to compensate for MntP overactivity.

High Intake of Manganese During Second Trimester, Increases the Risk of Preterm Delivery: A Large Scale Cohort Study.

Science.gov (United States)

Bakouei, Sare; Reisian, Fatemeh; Lamyian, Minoor; Haji Zadeh, Ebrahim; Zamanian, Hadi; Taheri Kharameh, Zahra

2015-03-18

Evidence indicates that nutrients and minerals might play an important role in preterm delivery (PTD). The aim of this study was to determine maternal nutritional status during second trimester of pregnancy and its association with preterm delivery (Food Frequency Questionnaire (FFQ) in pregnant women of 14 to 20 weeks gestational age. The participants were followed up until delivery. Dietary intake of women with preterm delivery was compared with women who had term delivery. The results show that 61.2% of women were primiparous and that the incidence of preterm delivery was 7%. Manganese dietary intake was significantly higher in mothers with preterm delivery than those with term delivery (P=.03). Manganese was the only micronutrient correlated with preterm delivery after adjustment for maternal characteristics during second trimesters of pregnancy (OR=1.12; P=.01). These results suggest that high maternal manganese dietary intake during the second trimester of pregnancy may be associated with the risk of preterm delivery in Iranian pregnant women.

The cryogenic control system of EAST

International Nuclear Information System (INIS)

Zhuang, M.; Hu, L.B.; Zhow, Z.W.; Xia, G.H.

2012-01-01

Highlights: ► A reliable and flexible duplex control system is required for cryogenic system. ► The cryogenic control system is based on Delta-V DCS. ► It has been proved to be an effective way to control cryogenic process. ► It will provide useful experience and inspiration for the development in the cryogenic control engineering. - Abstract: A large scale helium cryogenic system is one of the key components for the EAST tokamak device for the cooling of PF and TF coils, structures, thermal shields, buslines, current leads and cryopumps. Since the cooling scheme of the EAST cryogenic system is fairly complicated, a reliable and flexible control system is required for cryogenic system. The cryogenic control system is based on DeltaV DCS which is the process control software developed by Emerson Company. The EAST cryogenic system has been in operation for four years and has been proved to be safe, stable and energy saving by the past 7 experiments. This paper describes the redundant control network, hardware configuration, software structure, auxiliary system and the new development in the future.

Cryogenic Preamplifiers for Magnetic Resonance Imaging

DEFF Research Database (Denmark)

Johansen, Daniel H.; Sanchez-Heredia, Juan D.; Petersen, Jan R.

2018-01-01

Pursuing the ultimate limit of detection in magnetic resonance imaging (MRI) requires cryogenics to decrease the thermal noise of the electronic circuits. As cryogenic coils for MRI are slowly emerging cryogenic preamplifiers are required to fully exploit their potential. A cryogenic preamplifier...

Exploiting Process-Related Advantages of Selective Laser Melting for the Production of High-Manganese Steel.

Science.gov (United States)

Haase, Christian; Bültmann, Jan; Hof, Jan; Ziegler, Stephan; Bremen, Sebastian; Hinke, Christian; Schwedt, Alexander; Prahl, Ulrich; Bleck, Wolfgang

2017-01-11

Metal additive manufacturing has strongly gained scientific and industrial importance during the last decades due to the geometrical flexibility and increased reliability of parts, as well as reduced equipment costs. Within the field of metal additive manufacturing methods, selective laser melting (SLM) is an eligible technique for the production of fully dense bulk material with complex geometry. In the current study, we addressed the application of SLM for processing a high-manganese TRansformation-/TWinning-Induced Plasticity (TRIP/TWIP) steel. The solidification behavior was analyzed by careful characterization of the as-built microstructure and element distribution using optical and scanning electron microscopy (SEM). In addition, the deformation behavior was studied using uniaxial tensile testing and SEM. Comparison with conventionally produced TRIP/TWIP steel revealed that elemental segregation, which is normally very pronounced in high-manganese steels and requires energy-intensive post processing, is reduced due to the high cooling rates during SLM. Also, the very fast cooling promoted ε- and α'-martensite formation prior to deformation. The superior strength and pronounced anisotropy of the SLM-produced material was correlated with the microstructure based on the process-specific characteristics.

Exploiting Process-Related Advantages of Selective Laser Melting for the Production of High-Manganese Steel

Directory of Open Access Journals (Sweden)

Christian Haase

2017-01-01

Full Text Available Metal additive manufacturing has strongly gained scientific and industrial importance during the last decades due to the geometrical flexibility and increased reliability of parts, as well as reduced equipment costs. Within the field of metal additive manufacturing methods, selective laser melting (SLM is an eligible technique for the production of fully dense bulk material with complex geometry. In the current study, we addressed the application of SLM for processing a high-manganese TRansformation-/TWinning-Induced Plasticity (TRIP/TWIP steel. The solidification behavior was analyzed by careful characterization of the as-built microstructure and element distribution using optical and scanning electron microscopy (SEM. In addition, the deformation behavior was studied using uniaxial tensile testing and SEM. Comparison with conventionally produced TRIP/TWIP steel revealed that elemental segregation, which is normally very pronounced in high-manganese steels and requires energy-intensive post processing, is reduced due to the high cooling rates during SLM. Also, the very fast cooling promoted ε- and α’-martensite formation prior to deformation. The superior strength and pronounced anisotropy of the SLM-produced material was correlated with the microstructure based on the process-specific characteristics.

Cryogenic Fluid Management Technology for Moon and Mars Missions

Science.gov (United States)

Doherty, Michael P.; Gaby, Joseph D.; Salerno, Louis J.; Sutherlin, Steven G.

2010-01-01

In support of the U.S. Space Exploration Policy, focused cryogenic fluid management technology efforts are underway within the National Aeronautics and Space Administration. Under the auspices of the Exploration Technology Development Program, cryogenic fluid management technology efforts are being conducted by the Cryogenic Fluid Management Project. Cryogenic Fluid Management Project objectives are to develop storage, transfer, and handling technologies for cryogens to support high performance demands of lunar, and ultimately, Mars missions in the application areas of propulsion, surface systems, and Earth-based ground operations. The targeted use of cryogens and cryogenic technologies for these application areas is anticipated to significantly reduce propellant launch mass and required on-orbit margins, to reduce and even eliminate storage tank boil-off losses for long term missions, to economize ground pad storage and transfer operations, and to expand operational and architectural operations at destination. This paper organizes Cryogenic Fluid Management Project technology efforts according to Exploration Architecture target areas, and discusses the scope of trade studies, analytical modeling, and test efforts presently underway, as well as future plans, to address those target areas. The target areas are: liquid methane/liquid oxygen for propelling the Altair Lander Ascent Stage, liquid hydrogen/liquid oxygen for propelling the Altair Lander Descent Stage and Ares V Earth Departure Stage, liquefaction, zero boil-off, and propellant scavenging for Lunar Surface Systems, cold helium and zero boil-off technologies for Earth-Based Ground Operations, and architecture definition studies for long term storage and on-orbit transfer and pressurization of LH2, cryogenic Mars landing and ascent vehicles, and cryogenic production via in situ resource utilization on Mars.

Mechanical properties and fatigue strength of high manganese non-magnetic steel/carbon steel welded joints

International Nuclear Information System (INIS)

Nakaji, Eiji; Ikeda, Soichi; Kim, You-Chul; Nakatsuji, Yoshihiro; Horikawa, Kosuke.

1997-01-01

The dissimilar materials welded joints of high manganese non-magnetic steel/carbon steel (hereafter referred to as DMW joints), in which weld defects such as hot crack or blowhole are not found, were the good quality. Tensile strength of DMW joints was 10% higher than that of the base metal of carbon steel. In the bend tests, the DMW joints showed the good ductility without crack. Charpy absorbed energy at 0(degC) of the DMW joints was over 120(J) in the bond where it seems to be the lowest. Large hardening or softening was not detected in the heat affected zone. Fatigue strength of the DMW joints is almost the same with that of the welded joints of carbon steel/carbon steel. As the fatigue strength of the DMW joints exceeds the fatigue design standard curve of JSSC for carbon steel welded joints, the DMW joints can be treated the same as the welded joints of carbon steel/carbon steel of which strength is lower than that of high manganese non-magnetic steel, from the viewpoint of the fatigue design. (author)

Old age and gender influence the pharmacokinetics of inhaled manganese sulfate and manganese phosphate in rats

International Nuclear Information System (INIS)

Dorman, David C.; McManus, Brian E.; Marshall, Marianne W.; James, R. Arden; Struve, Melanie F.

2004-01-01

In this study, we examined whether gender or age influences the pharmacokinetics of manganese sulfate (MnSO 4 ) or manganese phosphate (as the mineral form hureaulite). Young male and female rats and aged male rats (16 months old) were exposed 6 h day -1 for 5 days week -1 to air, MnSO 4 (at 0.01, 0.1, or 0.5 mg Mn m -3 ), or hureaulite (0.1 mg Mn m -3 ). Tissue manganese concentrations were determined in all groups at the end of the 90-day exposure and 45 days later. Tissue manganese concentrations were also determined in young male rats following 32 exposure days and 91 days after the 90-day exposure. Intravenous 54 Mn tracer studies were also performed in all groups immediately after the 90-day inhalation to assess whole-body manganese clearance rates. Gender and age did not affect manganese delivery to the striatum, a known target site for neurotoxicity in humans, but did influence manganese concentrations in other tissues. End-of-exposure olfactory bulb, lung, and blood manganese concentrations were higher in young male rats than in female or aged male rats and may reflect a portal-of-entry effect. Old male rats had higher testis but lower pancreas manganese concentrations when compared with young males. Young male and female rats exposed to MnSO 4 at 0.5 mg Mn m -3 had increased 54 Mn clearance rates when compared with air-exposed controls, while senescent males did not develop higher 54 Mn clearance rates. Data from this study should prove useful in developing dosimetry models for manganese that consider age or gender as potential sensitivity factors

A word from the DG: A cryogenic success

CERN Multimedia

2007-01-01

The beginning of this month saw the start of a new phase in the LHC project, with its first inauguration, for the LHC cryogenics. This was marked with a symposium in the Globe attended by 178 representatives of the industrial partners and research institutes involved. It also coincided with stable low-temperature operation of the cryogenic plant for sector 7-8, the first sector of the LHC to be cooled down. A look at the LHC web site (http://lhc.web.cern.ch/lhc/) shows this steady operation. The cryogenic system for the LHC is the largest and most complex ever built, involving many large devices on an industrial scale, where reliability is of paramount importance. The LHC’s energy of 7 TeV required a high magnetic field provided by niobium-titanium coils operating at 1.9 K. This is a new temperature regime for large-scale cryogenics, chosen to make use of the excellent heat-transfer properties of helium in its superfluid state. The final design for the LHC cryogenics had to incorporate both newly ordered ...

Cryogenic system for liquid hydrogen polarimeter

International Nuclear Information System (INIS)

Kitami, T.; Chiba, M.; Hirabayashi, H.; Ishii, T.; Kato, S.

1979-01-01

A cryogenic system has been constructed for a liquid hydrogen polarimeter in order to measure polarization of high energy proton at the 1.3 GeV electron synchrotron of Institute for Nuclear Study, University of Tokyo. The system principally consists of a cryogenerator with a cryogenic transfer line, a liquid hydrogen cryostat, and a 14.5 l target container of thin aluminum alloy where liquid hydrogen is served for the experiment. The refrigeration capacity is about 54 W at 20.4 K without a target container. (author)

Cryogenic system design for a compact tokamak reactor

International Nuclear Information System (INIS)

Slack, D.S.; Kerns, J.A.; Miller, J.R.

1988-01-01

The International Tokamak Engineering Reactor (ITER) is a program presently underway to design a next-generation tokamak reactor. The cryogenic system for this reactor must meet unusual and new requirements. Unusually high heat loads (100 kW at 4.5 K) must be handled because neutron shielding has been limited to save space in the reactor core. Also, large variations in the cryogenics loads occur over short periods of time because of the pulsed nature of some of the operating scenarios. This paper describes a workable cryogenic system design for a compact tokamak reactor such as ITER. A design analysis is presented dealing with a system that handles transient loads, coil quenches, reactor cool-down and the effect of variations in helium-supply temperatures on the cryogenic stability of the coils. 5 refs., 4 figs., 1 tab

Integrated cryogenic sensors

International Nuclear Information System (INIS)

Juanarena, D.B.; Rao, M.G.

1991-01-01

Integrated cryogenic pressure-temperature, level-temperature, and flow-temperature sensors have several advantages over the conventional single parameter sensors. Such integrated sensors were not available until recently. Pressure Systems, Inc. (PSI) of Hampton, Virginia, has introduced precalibrated precision cryogenic pressure sensors at the Los Angeles Cryogenic Engineering Conference in 1989. Recently, PSI has successfully completed the development of integrated pressure-temperature and level-temperature sensors for use in the temperature range 1.5-375K. In this paper, performance characteristics of these integrated sensors are presented. Further, the effects of irradiation and magnetic fields on these integrated sensors are also reviewed

High-intensity laser-accelerated ion beam produced from cryogenic micro-jet target

Energy Technology Data Exchange (ETDEWEB)

Gauthier, M., E-mail: maxence.gauthier@stanford.edu; Kim, J. B.; Curry, C. B.; Gamboa, E. J.; Göde, S.; Propp, A.; Glenzer, S. H. [SLAC National Accelerator Laboratory, Menlo Park, California 94025 (United States); Aurand, B.; Willi, O. [Heinrich-Heine-University Düsseldorf, Düsseldorf (Germany); Goyon, C.; Hazi, A.; Pak, A.; Ruby, J.; Williams, G. J. [Lawrence Livermore National Laboratory, Livermore, California 94551 (United States); Kerr, S. [University of Alberta, Edmonton, Alberta T6G 1R1 (Canada); Ramakrishna, B. [Indian Institute of Technology, Hyderabad (India); Rödel, C. [SLAC National Accelerator Laboratory, Menlo Park, California 94025 (United States); Friedrich-Schiller-University Jena, Jena (Germany)

2016-11-15

We report on the successful operation of a newly developed cryogenic jet target at high intensity laser-irradiation. Using the frequency-doubled Titan short pulse laser system at Jupiter Laser Facility, Lawrence Livermore National Laboratory, we demonstrate the generation of a pure proton beam a with maximum energy of 2 MeV. Furthermore, we record a quasi-monoenergetic peak at 1.1 MeV in the proton spectrum emitted in the laser forward direction suggesting an alternative acceleration mechanism. Using a solid-density mixed hydrogen-deuterium target, we are also able to produce pure proton-deuteron ion beams. With its high purity, limited size, near-critical density, and high-repetition rate capability, this target is promising for future applications.

Cryogenic cooling system for HTS cable

Energy Technology Data Exchange (ETDEWEB)

Yoshida, Shigeru [Taiyo Nippon Sanso, Tsukuba (Japan)

2017-06-15

Recently, Research and development activity of HTS (High Temperature Superconducting) power application is very progressive worldwide. Especially, HTS cable system and HTSFCL (HTS Fault current limiter) system are proceeding to practical stages. In such system and equipment, cryogenic cooling system, which makes HTS equipment cooled lower than critical temperature, is one of crucial components. In this article, cryogenic cooling system for HTS application, mainly cable, is reviewed. Cryogenic cooling system can be categorized into conduction cooling system and immersion cooling system. In practical HTS power application area, immersion cooling system with sub-cooled liquid nitrogen is preferred. The immersion cooling system is besides grouped into open cycle system and closed cycle system. Turbo-Brayton refrigerator is a key component for closed cycle system. Those two cooling systems are focused in this article. And, each design and component of the cooling system is explained.

Cryogenic Fluid Management Facility

Science.gov (United States)

Eberhardt, R. N.; Bailey, W. J.

1985-01-01

The Cryogenic Fluid Management Facility is a reusable test bed which is designed to be carried within the Shuttle cargo bay to investigate the systems and technologies associated with the efficient management of cryogens in space. Cryogenic fluid management consists of the systems and technologies for: (1) liquid storage and supply, including capillary acquisition/expulsion systems which provide single-phase liquid to the user system, (2) both passive and active thermal control systems, and (3) fluid transfer/resupply systems, including transfer lines and receiver tanks. The facility contains a storage and supply tank, a transfer line and a receiver tank, configured to provide low-g verification of fluid and thermal models of cryogenic storage and transfer processes. The facility will provide design data and criteria for future subcritical cryogenic storage and transfer system applications, such as Space Station life support, attitude control, power and fuel depot supply, resupply tankers, external tank (ET) propellant scavenging, and ground-based and space-based orbit transfer vehicles (OTV).

Ternary manganese ferrite/graphene/polyaniline nanostructure with enhanced electrochemical capacitance performance

Science.gov (United States)

Xiong, Pan; Hu, Chenyao; Fan, Ye; Zhang, Wenyao; Zhu, Junwu; Wang, Xin

2014-11-01

A ternary manganese ferrite/graphene/polyaniline (MGP) nanostructure is designed and synthesized via a facile two-step approach. This nanostructure exhibits outstanding electrochemical performances, such as high specific capacitance (454.8 F g-1 at 0.2 A g-1), excellent rate capability (75.8% capacity retention at 5 A g-1), and good cycling stability (76.4% capacity retention after 5000 cycles at 2 A g-1), which are superior to those of its individual components (manganese ferrite, reduced-graphene oxide, polyaniline) and corresponding binary hybrids (manganese ferrite/graphene (MG), manganese ferrite/polyaniline (MP), and graphene/polyaniline (GP)). A symmetric supercapacitor device using the as-obtained hybrid has been fabricated and tested. The device exhibits a high specific capacitance of 307.2 F g-1 at 0.1 A g-1 with a maximum energy density of 13.5 W h kg-1. The high electrochemical performance of ternary MGP can be attributed to its well-designed nanostructure and the synergistic effect of the individual components.

Cryogenic forced convection refrigerating system

International Nuclear Information System (INIS)

Klee, D.J.

1988-01-01

This patent describes the method of refrigerating products by contact with a refrigerating gas which comprises introducing product into a refrigeration zone, contacting the product with the refrigerating gas for a sufficient time to refrigerate it to the appropriate extent and removing the refrigerated product. The improvement for producing the refrigeration gas from a liquid cryogen such that essentially all of the liquid cryogen is fully vaporized before contacting the product comprises: (a) introducing the liquid cryogen, selected from the group consisting of liquid air and liquid nitrogen, at elevated pressure into an ejector as the motive fluid to accelerate a portion of a warm refrigerating gas through the ejector while mixing the cryogen and gas to effect complete vaporization of the liquid cryogen and substantial cooling of the portion of the refrigerating gas resulting in a cold discharge gas which is above the liquefaction temperature of the cryogen; (b) introducing the cold discharge gas into a forced circulation pathway of refrigerating gas and producing a cold refrigerating gas which contacts and refrigerates product and is then at least partially recirculated; (c) sensing the temperature of the refrigerating gas in the forced circulation pathway and controlling the introduction of liquid cryogen with regard to the sensed temperature to maintain the temperature of the discharge gas above the liquefacton temperature of the cryogen utilized

Mineral resource of the month: manganese

Science.gov (United States)

Corathers, Lisa A.

2012-01-01

Manganese is a silver-colored metal resembling iron and often found in conjunction with iron. The earliest-known human use of manganese compounds was in the Stone Age, when early humans used manganese dioxide as pigments in cave paintings. In ancient Rome and Egypt, people started using it to color or remove the color from glass - a practice that continued to modern times. Today, manganese is predominantly used in metallurgical applications as an alloying addition, particularly in steel and cast iron production. Steel and cast iron together provide the largest market for manganese (historically 85 to 90 percent), but it is also alloyed with nonferrous metals such as aluminum and copper. Its importance to steel cannot be overstated, as almost all types of steel contain manganese and could not exist without it.

The dynamic range of ultra-high-resolution cryogenic gamma-ray spectrometers

Energy Technology Data Exchange (ETDEWEB)

Ali, Shafinaz [Advanced Detector Group, Lawrence Livermore National Laboratory, 7000 East Avenue, L-270, Livermore, CA 94550 (United States); Terracol, Stephane F. [Advanced Detector Group, Lawrence Livermore National Laboratory, 7000 East Avenue, L-270, Livermore, CA 94550 (United States); Drury, Owen B. [Advanced Detector Group, Lawrence Livermore National Laboratory, 7000 East Avenue, L-270, Livermore, CA 94550 (United States); Friedrich, Stephan [Advanced Detector Group, Lawrence Livermore National Laboratory, 7000 East Avenue, L-270, Livermore, CA 94550 (United States)]. E-mail: friedrich1@llnl.gov

2006-04-15

We are developing high-resolution cryogenic gamma-ray spectrometers for nuclear science and non-proliferation applications. The gamma-ray detectors are composed of a bulk superconducting Sn foil absorber attached to a multilayer Mo/Cu transition-edge sensor (TES). The energy resolution of a detector with a 1x1x0.25 mm{sup 3} Sn absorber is 50-90 eV FWHM for {gamma}-rays up to 100 keV, and it decreases for larger absorbers. Here, we present the detector performance for different absorber volumes, and discuss the trade-offs between energy resolution and dynamic range.

The Dynamic Range of Ultra-High Resolution Cryogenic Gamma-ray Spectrometers

International Nuclear Information System (INIS)

Ali, S; Terracol, S F; Drury, O B; Friedrich, S

2005-01-01

We are developing high-resolution cryogenic gamma-ray spectrometers for nuclear science and non-proliferation applications. The gamma-ray detectors are composed of a bulk superconducting Sn foil absorber attached to multilayer Mo/Cu transition-edge sensors (TES). The energy resolution achieved with a 1 x 1 x 0.25 mm 3 Sn absorber is 50 -90eV for γ-rays up to 100 keV and it decreases for large absorber sizes. We discuss the trade-offs between energy resolution and dynamic range, as well as development of TES arrays for higher count rates and better sensitivity

Photogeochemical reactions of manganese under anoxic conditions

Science.gov (United States)

Liu, W.; Yee, N.; Piotrowiak, P.; Falkowski, P. G.

2017-12-01

Photogeochemistry describes reactions involving light and naturally occurring chemical species. These reactions often involve a photo-induced electron transfer that does not occur in the absence of light. Although photogeochemical reactions have been known for decades, they are often ignored in geochemical models. In particular, reactions caused by UV radiation during an ozone free early Earth could have influenced the available oxidation states of manganese. Manganese is one of the most abundant transition metals in the crust and is important in both biology and geology. For example, the presence of manganese (VI) oxides in the geologic record has been used as a proxy for oxygenic photosynthesis; however, we suggest that the high oxidation state of Mn can be produced abiotically by photochemical reactions. Aqueous solutions of manganese (II) as well as suspensions of rhodochrosite (MnCO3) were irradiated under anoxic condition using a 450 W mercury lamp and custom built quartz reaction vessels. The photoreaction of the homogeneous solution of Mn(II) produced H2 gas and akhtenskite (ɛ-MnO2) as the solid product . This product is different than the previously identified birnessite. The irradiation of rhodochrosite suspensions also produced H2 gas and resulted in both a spectral shift as well as morphology changes of the mineral particles in the SEM images. These reactions offer alternative, abiotic pathways for the formation of manganese oxides.

High Manganese Tolerance and Biooxidation Ability of Serratia marcescens Isolated from Manganese Mine Water in Minas Gerais, Brazil

Directory of Open Access Journals (Sweden)

Natália R. Barboza

2017-10-01

Full Text Available Manganese is an important metal for the maintenance of several biological functions, but it can be toxic in high concentrations. One of the main forms of human exposure to metals, such as manganese (Mn, is the consumption of solar salt contaminated. Mn-tolerant bacteria could be used to decrease the concentration of this metal from contaminated sites through safer environmental-friendly alternative technology in the future. Therefore, this study was undertaken to isolate and identify Mn resistant bacteria from water samples collected from a Mn mine in the Iron Quadrangle region (Minas Gerais, Brazil. Two bacterial isolates were identified as Serratia marcescens based on morphological, biochemical, 16S rDNA gene sequencing and phylogeny analysis. Maximum resistance of the selected isolates against increasing concentrations of Mn(II, up to 1200 mg L-1 was determined in solid media. A batch assay was developed to analyze and quantify the Mn removal capacities of the isolates. Biological Mn removal capacities of over 55% were detected for both isolates. Whereas that mechanism like biosorption, precipitation and oxidation could be explaining the Mn removal, we seek to give an insight into some of the molecular mechanisms adopted by S. marcescens isolates. For this purpose, the following approaches were adopted: leucoberbelin blue I assay, Mn(II oxidation by cell-free filtrate and electron microscopy and energy-dispersive X-ray spectroscopy analyses. Overall, these results indicate that S. marcescens promotes Mn removal in an indirect mechanism by the formation of Mn oxides precipitates around the cells, which should be further explored for potential biotechnological applications for water recycling both in hydrometallurgical and mineral processing operations.

Applied superconductivity and cryogenic research activities in NIFS

International Nuclear Information System (INIS)

Mito, T.; Sagara, A.; Imagawa, S.; Yamada, S.; Takahata, K.; Yanagi, N.; Chikaraishi, H.; Maekawa, R.; Iwamoto, A.; Hamaguchi, S.; Sato, M.; Noda, N.; Yamauchi, K.; Komori, A.; Motojima, O.

2006-01-01

Since the foundation of National Institute for Fusion Science (NIFS) in 1989, the primary mission of the applied superconductivity and cryogenic researches has been focused on the development of the large helical device (LHD): the largest fusion experimental apparatus exclusively utilizing superconducting technologies. The applied superconductivity and cryogenics group in NIFS was organized to be responsible for this activity. As a result of extensive research activities, the construction of LHD was completed in 1997. Since then, the LHD superconducting system has been demonstrating high availability of more than 97% during eight years operation and it keeps proving high reliability of large-scale superconducting systems. This paper describes the extensive activities of the applied superconductivity and cryogenic researches in NIFS during and after the development of LHD and the fundamental researches that aim at realizing a helical-type fusion reactor

Cryogenics in CEBAF HMS dipole

International Nuclear Information System (INIS)

Bogensberger, P.; Ramsauer, F.; Brindza, P.; Wines, R.; Koefler, H.

1994-01-01

The paper will report upon the final design, manufacturing and tests of CEBAF's HMS Dipole cryogenic equipment. The liquid nitrogen circuits, the helium circuits and thermal insulation of the magnet will be addressed. The cryogenic reservoir and control module as an integral part of the HMS Dipole magnet will be presented. The construction, manufacturing, tests and final performance of the HMS Dipole cryogenic system will be reported. The LN 2 circuit and the He circuit are tied together by the control system for cool down, normal operation and standby. This system monitors proper temperature differences between both circuits and controls the cryogenic supply to meet the constraints. Implementation of the control features for the cryogenic system into the control system will be reported

Surface tension confined liquid cryogen cooler

International Nuclear Information System (INIS)

Castles, S.H.; Schein, M.E.

1989-01-01

A cryogenic cooler is described for use in craft such as launch, orbital and space vehicles subject to changes in orientation and conditions of vibration and weightlessness comprising: an insulated tank; a porous open celled sponge-like material disposed substantially throughout the contained volume of the insulated tank; a cryogenic fluid disposed within the sponge-like material; a cooling finger immersed in the cryogenic fluid, the finger extending from inside the insulated tank externally to an outside source such as an instrument detector for the purpose of transmitting heat from the outside source into the cryogenic fluid; means for filling the insulated tank with cryogenic fluid; and means for venting vaporized cryogenic fluid from the insulated tank

Device for delivering cryogen to rotary super-conducting winding of cryogen-cooled electrical machine

International Nuclear Information System (INIS)

Filippov, I.F.; Gorbunov, G.S.; Khutoretsky, G.M.; Popov, J.S.; Skachkov, J.V.; Vinokurov, A.A.

1980-01-01

A device is disclosed for delivering cryogen to a superconducting winding of a cryogen-cooled electrical machine comprising a pipe articulated along the axis of the electrical machine and intended to deliver cryogen. One end of said pipe is located in a rotary chamber which communicates through channels with the space of the electrical machine, and said space accommodating its superconducting winding. The said chamber accommodates a needle installed along the chamber axis, and the length of said needle is of sufficient length such that in the advanced position of said cryogen delivering pipe said needle reaches the end of the pipe. The layout of the electrical machine increases the reliability and effectiveness of the device for delivering cryogen to the superconducting winding, simplifies the design of the device and raises the efficiency of the electrical machine

Dietary manganese in the Glasgow area

International Nuclear Information System (INIS)

Cross, J.D.; Dale, I.M.; Raie, R.M.

1979-01-01

The manganese content of the diet and human tissue (adult and infant) in the Glasgow area is established. The total manganese intake by a breast fed infant (6 μg/day) is very much lower than that of an adult (5 mg/day). This does not appear to cause any upset in the infant's metabolism and the tissue levels of both groups are similar. This indicates that the human system can obtain its required manganese from both levels of intake. Tea is the major source of manganese in the diet: tobacco, which is rich in manganese, does not contribute a significant amount when smoked. (author)

Evaluation of high temperature superconductive thermal bridges for space borne cryogenic detectors

Science.gov (United States)

Scott, Elaine P.

1996-01-01

Infrared sensor satellites are used to monitor the conditions in the earth's upper atmosphere. In these systems, the electronic links connecting the cryogenically cooled infrared detectors to the significantly warmer amplification electronics act as thermal bridges and, consequently, the mission lifetimes of the satellites are limited due to cryogenic evaporation. High-temperature superconductor (HTS) materials have been proposed by researchers at the National Aeronautics and Space Administration Langley's Research Center (NASA-LaRC) as an alternative to the currently used manganin wires for electrical connection. The potential for using HTS films as thermal bridges has provided the motivation for the design and the analysis of a spaceflight experiment to evaluate the performance of this superconductive technology in the space environment. The initial efforts were focused on the preliminary design of the experimental system which allows for the quantitative comparison of superconductive leads with manganin leads, and on the thermal conduction modeling of the proposed system. Most of the HTS materials were indicated to be potential replacements for the manganin wires. In the continuation of this multi-year research, the objectives of this study were to evaluate the sources of heat transfer on the thermal bridges that have been neglected in the preliminary conductive model and then to develop a methodology for the estimation of the thermal conductivities of the HTS thermal bridges in space. The Joule heating created by the electrical current through the manganin wires was incorporated as a volumetric heat source into the manganin conductive model. The radiative heat source on the HTS thermal bridges was determined by performing a separate radiant interchange analysis within a high-T(sub c) superconductor housing area. Both heat sources indicated no significant contribution on the cryogenic heat load, which validates the results obtained in the preliminary conduction

The LHC cryogenic system and operational experience from the first three years run

International Nuclear Information System (INIS)

Delikaris, Dimitri; Tavian, Laurent

2014-01-01

The LHC (Large Hadron Collider) accelerator helium cryogenic system consists of eight cryogenically independent sectors, each 3.3 km long, all cooled and operated at 1.9 K. The overall, entropy equivalent, installed cryogenic capacity totalizes 144 kW (a) 4.5 K including 19.2 kW (a) 1.8 K with an associated helium inventory of 130 ton. The LHC cryogenic system is considered among the most complex and powerful in the world allowing the cooling down to superfluid helium temperature of 1.9 K. of the accelerators' high field superconducting magnets distributed over the 26.7 km underground ring. The present article describes the LHC cryogenic system and its associated cryogen infrastructure. Operational experience, including cryogen management, acquired from the first three years of LHC operation is finally presented. (author)

Effect of paramagnetic manganese ions doping on frequency and high temperature dependence dielectric response of layered Na1.9Li0.1Ti3O7 ceramics

International Nuclear Information System (INIS)

Pal, Dharmendra; Pandey, J.L.

2010-01-01

The manganese doped layered ceramic samples (Na 1.9 Li 0.1 )Ti 3 O 7 : XMn (0.01 ≤ X ≤ 0.1) have been prepared using high temperature solid state reaction. The room temperature electron paramagnetic resonance (EPR) investigations exhibit that at lower percentage of doping the substitution of manganese ions occur as Mn 3+ at Ti 4+ sites, whereas for higher percentage of doping Mn 2+ ions occupy the two different interlayer sodium/lithium sites. In both cases, the charge compensation mechanism should operate to maintain the overall charge neutrality of the lattice. The manganese doped derivatives of layered Na 1.9 Li 0. 1Ti 3 O 7 (SLT) ceramics have been investigated through frequency dependence dielectric spectroscopy in this work. The results indicate that the dielectric losses in these ceramics are the collective contribution of electric conduction, dipole orientation and space charge polarization. Smeared peaks in temperature dependence of permittivity plots suggest diffuse nature of high temperature ferroelectric phase transition. The light manganese doping in SLT enhances the dielectric constant. However, manganese doping decreases dielectric loss due to inhibition of domain wall motion, enhances electron-hopping conduction, and impedes the interlayer ionic conduction as well. Manganese doping also gives rise to contraction of interlayer space. (author)

Cryogenic process simulation

International Nuclear Information System (INIS)

Panek, J.; Johnson, S.

1994-01-01

Combining accurate fluid property databases with a commercial equation-solving software package running on a desktop computer allows simulation of cryogenic processes without extensive computer programming. Computer simulation can be a powerful tool for process development or optimization. Most engineering simulations to date have required extensive programming skills in languages such as Fortran, Pascal, etc. Authors of simulation code have also usually been responsible for choosing and writing the particular solution algorithm. This paper describes a method of simulating cryogenic processes with a commercial software package on a desktop personal computer that does not require these traditional programming tasks. Applications include modeling of cryogenic refrigerators, heat exchangers, vapor-cooled power leads, vapor pressure thermometers, and various other engineering problems

Fundamentals of cryogenic engineering

CERN Document Server

Mukhopadhyay, Mamata

2014-01-01

The author, with her vast and varied experience in teaching and allied fields, clearly enunciates the behaviour and various properties of common cryogenic fluids, methods of liquefaction, and separation and applications of cryogens with thermodynamic analysis for process selection. This profusely illustrated study with clear-cut diagrams and process charts, should serve not only as a textbook for students but also as an excellent reference for researchers and practising engineers on design of cryogenic refrigeration, and liquefaction and separation process plants for various applications.

Cryogenics will cool LHC

International Nuclear Information System (INIS)

Anon.

2001-01-01

Results of the investigation into the cryogenic regulating line (QRL) performed by the LHC laboratory are presented. It is projected that eight cryogenic units located in five places around the LHC ring will provide superconducting magnets by liquid helium through eight cryogenic regulating lines of 3.2 km each. All QRL zones remain to be independent. CERN uses three test units with the aim of the certification of chosen constructions and verification of their thermal and mechanical efficiency before starting full-scale production [ru

A simple route to synthesize manganese germanate nanorods

International Nuclear Information System (INIS)

Pei, L.Z.; Yang, Y.; Yuan, C.Z.; Duan Taike; Zhang Qianfeng

2011-01-01

Manganese germanate nanorods have been synthesized by a simple route using germanium dioxide and manganese acetate as the source materials. X-ray diffraction observation shows that the nanorods are composed of orthorhombic and monoclinic manganese germanate phases. Scanning electron microscopy and transmission electron microscopy observations display that the manganese germanate nanorods have flat tips with the length of longer than 10 micrometers and diameter of 60-350 nm, respectively. The role of the growth conditions on the formation of the manganese germanate nanorods shows that the proper selection and combination of the growth conditions are the key factor for controlling the formation of the manganese germanate nanorods. The photoluminescence spectrum of the manganese germanate nanorods exhibits four fluorescence emission peaks centered at 422 nm, 472 nm, 487 nm and 530 nm showing the application potential for the optical devices. - Research Highlights: → Manganese germanate nanorods have been synthesized by simple hydrothermal process. → The formation of manganese germanate nanorods can be controlled by growth conditions. → Manganese germanate nanorods exhibit good PL emission ability for optical device.

Technical presentation: BGM Cryogenic Engineering Limited

CERN Multimedia

Caroline Laignel - FI Department

2006-01-01

13 - 14 June 2006 TECHNICAL PRESENTATION BGM Cryogenic Engineering Limited 09:00 - 18:00, 60-2-016, Main Building. Presentation on BGM: 11:00 - 12:00, 60-2-016, Main Building. BGM Cryogenic Engineering Limited manufactures assemblies, sub-assemblies and machined components for the cryogenic technology sector. The primary markets served include superconducting magnets used in the healthcare sector (eg MRI body scanners), spectroscopy and NMR equipment for numerous R & D and technology applications, high vacuum applications and particle physics research. BGM has specialist assembly capability including stainless steel and aluminium welding, vacuum testing, electromechanical assembly and metal finishing. BGM offers a ‘one stop shop'facility to satisfy any customer requirement. Through our design partner we can offer a full design and modelling service, including 3D modelling and production of 2D drawings on your own borders. We can conduct heat load and force calculations and advise on the best...

Cold highly charged ions in a cryogenic Paul trap

Energy Technology Data Exchange (ETDEWEB)

Versolato, O. O., E-mail: oscar.versolato@mpi-hd.mpg.de; Schwarz, M.; Windberger, A.; Ullrich, J. [Max-Planck-Institut fuer Kernphysik (Germany); Schmidt, P. O. [Physikalisch-Technische Bundesanstalt (Germany); Drewsen, M. [University of Aarhus, Department of Physics and Astronomy (Denmark); Crespo Lopez-Urrutia, J. R. [Max-Planck-Institut fuer Kernphysik (Germany)

2013-03-15

Narrow optical transitions in highly charged ions (HCIs) are of particular interest for metrology and fundamental physics, exploiting the high sensitivity of HCIs to new physics. The highest sensitivity for a changing fine structure constant ever predicted for a stable atomic system is found in Ir{sup 17 + }. However, laser spectroscopy of HCIs is hindered by the large ({approx} 10{sup 6} K) temperatures at which they are produced and trapped. An unprecedented improvement in such laser spectroscopy can be obtained when HCIs are cooled down to the mK range in a linear Paul trap. We have developed a cryogenic linear Paul trap in which HCIs will be sympathetically cooled by {sup 9}Be{sup + } ions. Optimized optical access for laser light is provided while maintaining excellent UHV conditions. The Paul trap will be connected to an electron beam ion trap (EBIT) which is able to produce a wide range of HCIs. This EBIT will also provide the first experimental input needed for the determination of the transition energies in Ir{sup 17 + }, enabling further laser-spectroscopic investigations of this promising HCI.

Brain manganese, catecholamine turnover, and the development of startle in rats prenatally exposed to manganese

International Nuclear Information System (INIS)

Kontur, P.J.; Fechter, L.D.

1985-01-01

Manganese (Mn) can be neurotoxic when present in high concentrations. Neonatal animals show differential absorption, accumulation, and excretion of Mn relative to adults. If similar kinetic differences exist during gestation, then fetal animals may be susceptible to Mn neurotoxicity. The objective of this study was to examine maternal-fetal Mn transfer and the susceptibility of prenatal animals to Mn neurotoxicity. This was approached by studying the ability of Mn to cross the placenta and reach the fetal central nervous system using radiotracer and atomic absorption spectroscopy techniques. Manganese is thought to disrupt catecholamine neurotransmission in the central nervous system. This was examined in newborn rats by alpha-methyl-para-tyrosine induced catecholamine turnover and the development of the acoustic startle response. The results suggest that there are limits on fetal Mn accumulation under conditions of both normal and excessive dietary Mn levels. Manganese accumulation in the fetal brain after exposure to increased dietary Mn does not alter either dopamine or norepinephrine turnover or the development of the acoustic startle response. Excess Mn does not appear to be neurotoxic to fetal rats in spite of its limited accumulation in nervous tissue after gestational exposure

Effect of mass density on surface morphology of electrodeposited manganese oxide films

Science.gov (United States)

Singh, Avtar; Kumar, Davinder; Thakur, Anup; Kaur, Raminder

2018-05-01

This work focus on high surface area morphology of manganese oxide films which are currently required for electrochemical capacitor electrode to enhance their performance. Electrodeposition of manganese oxide films was carried out using Chronoamperometry for different deposition time ranging from 30 to 120 sec. Cronoamperomertic I-T integrated data have been used to analyze active mass of all electrodeposited films. Morphological study of the deposited films with different mass was carried out through scanning electron microscopy. Film deposited for 30 sec time show highest porous morphology than others. Manganese oxide films with high porosity are suitable for electrochemical capacitor electrode.

TPC magnet cryogenic system

International Nuclear Information System (INIS)

Green, M.A.; Burns, W.A.; Taylor, J.D.; Van Slyke, H.W.

1980-03-01

The Time Projection Chamber (TPC) magnet at LBL and its compensation solenoids are adiabatically stable superconducting solenoid magnets. The cryogenic system developed for the TPC magnet is discussed. This system uses forced two-phase tubular cooling with the two cryogens in the system. The liquid helium and liquid nitrogen are delivered through the cooled load by forced tubular flow. The only reservoirs of liquid cryogen exist in the control dewar (for liquid helium) and the conditioner dewar (for liquid nitrogen). The operation o these systems during virtually all phases of system operation are described. Photographs and diagrams of various system components are shown, and cryogenic system data are presented in the following sections: (1) heat leaks into the TPC coil package and the compensation solenoids; (2) heat leaks to various components of the TPC magnet cryogenics system besides the magnets and control dewar; (3) the control dewar and its relationship to the rest of the system; (4) the conditioner system and its role in cooling down the TPC magnet; (5) gas-cooled electrical leads and charging losses; and (6) a summation of the liquid helium and liquid nitrogen requirements for the TPC superconducting magnet system

Battery recycling: recovery of manganese in the form of electrolytic manganese dioxide

International Nuclear Information System (INIS)

Roriz, Elizabeth Rodrigues Rangel; Von Krüge, Paulo; Espinosa, Denise Crocce Romano; Tenorio, Jorge Alberto Soares

2010-01-01

This work seeks to verify the possibility of using depleted batteries as a source of manganese applying the electrolytic process, considering the growing demand for products containing manganese in their composition. It was used an electrolyte solution containing the metal ions: Ca (270mg / L), Ni (3000 mg / L), Co (630 mg / L), Mn (115.300 mg / L) , Ti (400 mg / L) and Pb (20 mg / L) in concentrated sulfuric acid. The production of electrolytic manganese dioxide (EMD) was performed through galvanization using a stabilized source that monitored the potential of the working electrode. It was used an electrode of lead and two counter electrodes of graphite at a temperature of 98 deg C (± 2 deg C) and current density of 1.69A.dm"-"2. The material obtained was analyzed through the process of X-ray fluorescence spectrometry and X-ray diffraction. The results indicated that it is possible to obtain electrolytic manganese dioxide with a purity of about 94% and that the main allotropic variety obtained under the conditions of the experiment was the ε-MnO_2. (author)

Removal of iron and manganese using biological roughing up flow filtration technology.

Science.gov (United States)

Pacini, Virginia Alejandra; María Ingallinella, Ana; Sanguinetti, Graciela

2005-11-01

The removal of iron and manganese from groundwater using biological treatment methods is almost unknown in Latin America. Biological systems used in Europe are based on the process of double rapid biofiltration during which dissolved oxygen and pH need to be strictly controlled in order to limit abiotic iron oxidation. The performance of roughing filter technology in a biological treatment process for the removal of iron and manganese, without the use of chemical agents and under natural pH conditions was studied. Two pilot plants, using two different natural groundwaters, were operated with the following treatment line: aeration, up flow roughing filtration and final filtration (either slow or rapid). Iron and manganese removal efficiencies were found to be between 85% and 95%. The high solid retention capability of the roughing filter means that it is possible to remove iron and manganese simultaneously by biotic and abiotic mechanisms. This system combines simple, low-cost operation and maintenance with high iron and manganese removal efficiencies, thus constituting a technology which is particularly suited to small waterworks.

21 CFR 582.5446 - Manganese chloride.

Science.gov (United States)

2010-04-01

... 21 Food and Drugs 6 2010-04-01 2010-04-01 false Manganese chloride. 582.5446 Section 582.5446 Food and Drugs FOOD AND DRUG ADMINISTRATION, DEPARTMENT OF HEALTH AND HUMAN SERVICES (CONTINUED) ANIMAL... Supplements 1 § 582.5446 Manganese chloride. (a) Product. Manganese chloride. (b) Conditions of use. This...

Precipitation Effect on Mechanical Properties and Phase Stability of High Manganese Steel

Science.gov (United States)

Bae, Cheoljun; Kim, Rosa; Lee, Un-Hae; Kim, Jongryoul

2017-09-01

High manganese (Mn) steels are attractive for automotive applications due to their excellent tensile strength and superior elongation. However, the relatively low yield strength of Mn steels compared to other advanced high-strength steels is a critical problem limiting their use in structural parts. In order to increase the yield strength, the precipitation hardening effect of Mn steels was investigated by the addition of carbide-forming elements. Changes in the austenite phase stability were also evaluated in terms of stacking fault energy (SFE). As a result, fine V(C,N) precipitates were found to increase the yield strength effectively but to lower the SFE by the consumption of matrix carbons. For achieving precipitation hardening without sacrificing austenite stability, the soluble carbon content was discussed.

The effects of high dose of two manganese supplements (organic and inorganic) on the rumen microbial ecosystem.

Science.gov (United States)

Kišidayová, Svetlana; Pristaš, Peter; Zimovčáková, Michaela; Blanár Wencelová, Monika; Homol'ová, Lucia; Mihaliková, Katarína; Čobanová, Klaudia; Grešáková, Ľubomíra; Váradyová, Zora

2018-01-01

Little is known about the effects of the high dose and types of manganese supplements on rumen environment at manganese intake level close above the limit of 150 mg/kg of dry feed matter. The effects of high dose of two manganese supplements (organic and inorganic) on rumen microbial ecosystem after four months of treatment of 18 lambs divided into three treatment groups were studied. We examined the enzyme activities (α-amylase, xylanase, and carboxymethyl cellulase), total and differential microscopic counts of rumen ciliates, total microscopic counts of bacteria, and fingerprinting pattern of the eubacterial and ciliates population analyzed by PCR-DGGE. Lambs were fed a basal diet with a basal Mn content (34.3 mg/kg dry matter; control) and supplemented either with inorganic manganous sulfate or organic Mn-chelate hydrate (daily 182.7, 184 mg/kg dry matter of feed, respectively). Basal diet, offered twice daily, consisted of ground barley and hay (268 and 732 g/kg dry matter per animal and day). The rumens of the lambs harbored ciliates of the genera of Entodinium, Epidinium, Diplodinium, Eudiplodinium, Dasytricha, and Isotricha. No significant differences between treatment groups were observed in the total ciliate number, the number of ciliates at the genus level, as well as the total number of bacteria. Organic Mn did decrease the species richness and diversity of the eubacterial population examined by PCR-DGGE. No effects of type of Mn supplement on the enzyme activities were observed. In comparison to the control, α-amylase specific activities were decreased and carboxymethyl-cellulase specific activities were increased by the Mn supplements. Xylanase activities were not influenced. In conclusion, our results suggested that the intake of tested inorganic and organic manganese supplements in excess may affect the specific groups of eubacteria. More studies on intake of Mn supplements at a level close to the limit can reveal if the changes in microbial

Compact insert design for cryogenic pressure vessels

Energy Technology Data Exchange (ETDEWEB)

Aceves, Salvador M.; Ledesma-Orozco, Elias Rigoberto; Espinosa-Loza, Francisco; Petitpas, Guillaume; Switzer, Vernon A.

2017-06-14

A pressure vessel apparatus for cryogenic capable storage of hydrogen or other cryogenic gases at high pressure includes an insert with a parallel inlet duct, a perpendicular inlet duct connected to the parallel inlet. The perpendicular inlet duct and the parallel inlet duct connect the interior cavity with the external components. The insert also includes a parallel outlet duct and a perpendicular outlet duct connected to the parallel outlet duct. The perpendicular outlet duct and the parallel outlet duct connect the interior cavity with the external components.

CEBAF cryogenic system

International Nuclear Information System (INIS)

1995-01-01

The CEBAF cryogenic system consists of 3 refrigeration systems: Cryogenic Test Facility (CTF), Central Helium Liquefier (CHL), and End Station Refrigerator (ESR). CHL is the main cryogenic system for CEBAF, consisting of a 4.8 kW, 2.0 K refrigerator and transfer line system to supply 2.0 K and 12 kW of 50 K shield refrigeration for the Linac cavity cryostats and 10 g/s of liquid for the end stations. This paper describes the 9-year effort to commission these systems, concentrating on CHL with the cold compressors. The cold compressors are a cold vacuum pump with an inlet temperature of 3 K which use magnetic bearings, thereby eliminating the possibility of air leaks into the subatmospheric He

Radiation Requirements and Testing of Cryogenic Thermometers for the Ilc

Science.gov (United States)

Barnett, T.; Filippov, Yu. P.; Filippova, E. Yu.; Mokhov, N. V.; Nakao, N.; Klebaner, A. L.; Korenev, S. A.; Theilacker, J. C.; Trenikhina, J.; Vaziri, K.

2008-03-01

Large quantity of cryogenic temperature sensors will be used for operation of the International Linear Collider (ILC). Most of them will be subject to high radiation doses during the accelerator lifetime. Understanding of particle energy spectra, accumulated radiation dose in thermometers and its impact on performance are vital in establishing technical specification of cryogenic thermometry for the ILC. Realistic MARS15 computer simulations were performed to understand the ILC radiation environment. Simulation results were used to establish radiation dose requirements for commercially available cryogenic thermometers. Two types of thermometers, Cernox® and TVO, were calibrated prior to irradiation using different technique. The sensors were subjected then to up to 200 kGy electron beam irradiation with kinetic energy of 5 MeV, a representative of the situation at the ILC operation. A post-irradiation behavior of the sensors was studied. The paper describes the MARS15 model, simulation results, cryogenic test set-up, irradiation tests, and cryogenic test results.

Radiation requirements and testing of cryogenic thermometers for the ILC

International Nuclear Information System (INIS)

Barnett, T.; Filippov, Yu.P.; Mokhov, N.V.; Nakao, N.; Klebaner, A.L.; Korenev, S.A.; Theilacker, J.C.; Trenikhina, J.; Vaziri, K.

2007-01-01

Large quantity of cryogenic temperature sensors will be used for operation of the International Linear Collider (ILC). Most of them will be subject to high radiation doses during the accelerator lifetime. Understanding of particle energy spectra, accumulated radiation dose in thermometers and its impact on performance are vital in establishing technical specification of cryogenic thermometry for the ILC. Realistic MARS15 computer simulations were performed to understand the ILC radiation environment. Simulation results were used to establish radiation dose requirements for commercially available cryogenic thermometers. Two types of thermometers, Cernox(reg s ign) and TVO, were calibrated prior to irradiation using different technique. The sensors were subjected then to up to 200 kGy electron beam irradiation with kinetic energy of 5 MeV, a representative of the situation at the ILC operation. A post-irradiation behavior of the sensors was studied. The paper describes the MARS15 model, simulation results, cryogenic test set-up, irradiation tests, and cryogenic test results

Manganese binding proteins in human and cow's milk

International Nuclear Information System (INIS)

Loennerdal, B.; Keen, C.L.; Hurley, L.S.

1985-01-01

Manganese nutrition in the neonatal period is poorly understood, due in part to a lack of information on the amount of manganese in infant foods and its bioavailability. Since the molecular localization of an element in foods is one determinant of its subsequent bioavailability, a study was made of the binding of manganese in human and cow's milk. An extrinsic label of 54 Mn was shown to equilibrate isotopically with native manganese in milks and formulas. Milk samples were separated into fat, casein and whey by ultracentrifugation. In human milk, the major part (71%) of manganese was found in whey, 11% in casein and 18% in the lipid fraction. In contrast, in cow's milk, 32% of total manganese was in whey, 67% in casein and 1% in lipid. Within the human whey fraction, most of the manganese was bound to lactoferrin, while in cow's whey, manganese was mostly complexed to ligands with molecular weights less than 200. The distribution of manganese in formulas was closer to that of human milk than of cow's milk. The bioavailability of manganese associated with lactoferrin, casein and low molecular weight complexes needs to be assessed

Cryogen free high magnetic field and low temperature sample environments for neutron scattering - latest developments

International Nuclear Information System (INIS)

Burgoyne, John

2016-01-01

Continuous progress has been made over many years now in the provision of low- and ultra-low temperature sample environments, together with new high-field superconducting magnets and increased convenience for both the user and the neutron research facility via new cooling technologies. Within Oxford Instrument's experience, this has been achieved in many cases through close collaboration with neutron scientists, and with the neutron facilities' sample environment leaders in particular. Superconducting magnet designs ranging from compact Small Angle (SANS) systems up to custom-engineered wide-angle scattering systems have been continuously developed. Recondensing, or 'zero boil-off' (ZBO), systems are well established for situations in which a high field magnet is not conducive to totally cryogen free cooling solutions, and offer a reliable route with the best trade-offs of maximum system capability versus running costs and user convenience. Fully cryogen free solutions for cryostats, dilution refrigerators, and medium-field magnets are readily available. Here we will present the latest technology developments in these options, describing the state-of-the art, the relative advantages of each, and the opportunities they offer to the neutron science community. (author)

Study of Hydrogen Pumping through Condensed Argon in Cryogenic pump

International Nuclear Information System (INIS)

Jadeja, K A; Bhatt, S B

2012-01-01

In ultra high vacuum (UHV) range, hydrogen is a dominant residual gas in vacuum chamber. Hydrogen, being light gas, pumping of hydrogen in this vacuum range is limited with widely used UHV pumps, viz. turbo molecular pump and cryogenic pump. Pre condensed argon layers in cryogenic pump create porous structure on the surface of the pump, which traps hydrogen gas at a temperature less than 20° K. Additional argon gas injection in the cryogenic pump, at lowest temperature, generates multiple layers of condensed argon as a porous frost with 10 to 100 A° diameters pores, which increase the pumping capacity of hydrogen gas. This pumping mechanism of hydrogen is more effective, to pump more hydrogen gas in UHV range applicable in accelerator, space simulation etc. and where hydrogen is used as fuel gas like tokamak. For this experiment, the cryogenic pump with a closed loop refrigerator using helium gas is used to produce the minimum cryogenic temperature as ∼ 14° K. In this paper, effect of cryosorption of hydrogen is presented with different levels of argon gas and hydrogen gas in cryogenic pump chamber.

Advances in Cryogenic Principles

Science.gov (United States)

Barron, R. F.

During the past 50 years, the use of digital computers has significantly influenced the design and analysis of cryogenic systems. At the time when the first Cryogenic Engineering Conference was held, thermodynamic data were presented in graphical or tabular form (the "steam table" format), whereas thermodynamic data for cryogenic system design is computer generated today. The thermal analysis of cryogenic systems in the 1950s involved analytical solutions, graphical solutions, and relatively simple finite-difference approaches. These approaches have been supplanted by finite-element numerical programs which readily solve complicated thermal problems that could not be solved easily using the methods of the 1950s. In distillation column design, the use of the McCabe-Thiele graphical method for determination of the number of theoretical plates has been replaced by numerical methods that allow consideration of several different components in the feed and product streams.

A High Reliability Gas-driven Helium Cryogenic Centrifugal Compressor

CERN Document Server

Bonneton, M; Gistau-Baguer, Guy M; Turcat, F; Viennot, P

1998-01-01

A helium cryogenic compressor was developed and tested in real conditions in 1996. The achieved objective was to compress 0.018 kg/s Helium at 4 K @ 1000 Pa (10 mbar) up to 3000 Pa (30 mbar). This project was an opportunity to develop and test an interesting new concept in view of future needs. The main features of this new specific technology are described. Particular attention is paid to the gas bearing supported rotor and to the pneumatic driver. Trade off between existing technologies and the present work are presented with special stress on the bearing system and the driver. The advantages are discussed, essentially focused on life time and high reliability without maintenance as well as non pollution characteristic. Practical operational modes are also described together with the experimental performances of the compressor. The article concludes with a brief outlook of future work.

Epidermal protection with cryogen spray cooling during high fluence pulsed dye laser irradiation: an ex vivo study.

Science.gov (United States)

Tunnell, J W; Nelson, J S; Torres, J H; Anvari, B

2000-01-01

Higher laser fluences than currently used in therapy (5-10 J/cm(2)) are expected to result in more effective treatment of port wine stain (PWS) birthmarks. However, higher incident fluences increase the risk of epidermal damage caused by absorption of light by melanin. Cryogen spray cooling offers an effective method to reduce epidermal injury during laser irradiation. The objective of this study was to determine whether high laser incident fluences (15-30 J/cm(2)) could be used while still protecting the epidermis in ex vivo human skin samples. Non-PWS skin from a human cadaver was irradiated with a Candela ScleroPlus Laser (lambda = 585 nm; pulse duration = 1.5 msec) by using various incident fluences (8-30 J/cm(2)) without and with cryogen spray cooling (refrigerant R-134a; spurt durations: 40-250 msec). Assessment of epidermal damage was based on histologic analysis. Relatively short spurt durations (40-100 msec) protected the epidermis for laser incident fluences comparable to current therapeutic levels (8-10 J/cm(2)). However, longer spurt durations (100-250 msec) increased the fluence threshold for epidermal damage by a factor of three (up to 30 J/cm(2)) in these ex vivo samples. Results of this ex vivo study show that epidermal protection from high laser incident fluences can be achieved by increasing the cryogen spurt duration immediately before pulsed laser exposure. Copyright 2000 Wiley-Liss, Inc.

Beneficiation studies of Bajaur manganese ore by different processing techniques

International Nuclear Information System (INIS)

Riaz, M.; Khan, F.U.; Yamin, A.; Bilquees, R.; Muhammad, N.

2010-01-01

The manganese ore of Bajaur Agency of Pakistan was subjected to flotation, heavy medium separation, gravity concentration and magnetic separation techniques for beneficiation. The original composition of the manganese ore was 45.56% Mn , 4% Fe/sub 2/O/sub 3/, 40% SiO/sub 2/. The Mn content was raised to a maximum 48.76 % in the concentrate with the recovery of 67.78 % through flotation technique. Other techniques rendered marginal increase in Mn concentration against the theoretical possibility of substantial enrichment by rejecting the 20 % gangue minerals. The separation of manganese minerals from associated gangue was difficult, due to mineralogical complexity of the ore, extreme fineness of the particle size, texture and minerals intergrowth. High Mn/Fe ratio, phosphorus, and silica contents were within tolerable limits for utilisation of the ore in ferro-manganese production. (author)

21 CFR 184.1446 - Manganese chloride.

Science.gov (United States)

2010-04-01

... 21 Food and Drugs 3 2010-04-01 2009-04-01 true Manganese chloride. 184.1446 Section 184.1446 Food and Drugs FOOD AND DRUG ADMINISTRATION, DEPARTMENT OF HEALTH AND HUMAN SERVICES (CONTINUED) FOOD FOR... Specific Substances Affirmed as GRAS § 184.1446 Manganese chloride. (a) Manganese chloride (MnCl2·4H2O, CAS...

Cryogenics in nuclear reactor technology

International Nuclear Information System (INIS)

Dharmadurai, G.

1982-01-01

The cryogenic technology has significantly contributed to the development of several proven techniques for use in the nuclear power industry. A noteworthy feature is the unique role of cryogenics in minimising the release of radioactive and some chemical pollutants to the environment during the operation of various plants associated with this industry. The salient technological features of several cryogenic processes relevant to the nuclear reactor technology are discussed. (author)

Surface Tension Confines Cryogenic Liquid

Science.gov (United States)

Castles, Stephen H.; Schein, Michael E.

1989-01-01

New type of Dewar provides passive, constant-temperature cryogenic cooling for scientific instruments under normal-to low-gravity conditions. Known as Surface-Tension-Contained Liquid Cryogen Cooler (STCLCC), keeps liquid cryogen in known location inside the Dewar by trapping liquid inside spongelike material. Unique sponge material fills most of volume of inner tank. Sponge is all-silica, open-cell material similar to that used for Space Shuttle thermal-protection tiles.

Cryogenic propulsion for lunar and Mars missions

Science.gov (United States)

Redd, Larry

1988-01-01

Future missions to the moon and Mars have been investigated with regard to propulsion system selection. The results of this analysis show that near state-of-the-art LO2/LH2 propulsion technology provides a feasible means of performing lunar missions and trans-Mars injections. In other words, existing cryogenic space engines with certain modifications and product improvements would be suitable for these missions. In addition, present day cryogenic system tankage and structural weights appear to scale reasonably when sizing for large payload and high energy missions such as sending men to Mars.

Electromagnetic dampers for cryogenic applications

Science.gov (United States)

Brown, Gerald V.; Dirusso, Eliseo

1988-01-01

Cryogenic turbomachinery of the type used to pump high-pressure liquid hydrogen at -423 F and liquid oxygen at -297 F to the main engines of the Space Shuttle are subjected to lateral rotor vibrations from unbalance forces and transient loads. Conventional dampers which utilize viscous fluids such as lubricating oil cannot be used in turbopumps because the bearing components are filled with either liquid hydrogen or liquid oxygen, which have viscosity comparable to air and, therefore, are not effective in viscous dampers. Electromagentic dampers are currently being explored as a means of providing damping in cryogenic turbopumps because their damping effectiveness increases as temperature decreases and because they are compatible with the liquid hydrogen or liquid oxygen in the turbopumps.

Polymers at cryogenic temperatures

CERN Document Server

Fu, Shao-Yun

2013-01-01

Kalia and Fu's novel monograph covers cryogenic treatment, properties and applications of cryo-treated polymer materials. Written by numerous international experts, the twelve chapters in this book offer the reader a comprehensive picture of the latest findings and developments, as well as an outlook on the field. Cryogenic technology has seen remarkable progress in the past few years and especially cryogenic properties of polymers are attracting attention through new breakthroughs in space, superconducting, magnetic and electronic techniques. This book is a valuable resource for researchers, educators, engineers and graduate students in the field and at technical institutions.

FRIB Cryogenic Plant Status

Energy Technology Data Exchange (ETDEWEB)

Dixon, Kelly D. [Thomas Jefferson National Accelerator Facility (TJNAF), Newport News, VA (United States); Ganni, Venkatarao [Thomas Jefferson National Accelerator Facility (TJNAF), Newport News, VA (United States); Knudsen, Peter N. [Thomas Jefferson National Accelerator Facility (TJNAF), Newport News, VA (United States); Casagranda, Fabio [Michigan State Univ., East Lansing, MI (United States)

2015-12-01

After practical changes were approved to the initial conceptual design of the cryogenic system for MSU FRIB and an agreement was made with JLab in 2012 to lead the design effort of the cryogenic plant, many activities are in place leading toward a cool-down of the linacs prior to 2018. This is mostly due to using similar equipment used at CHLII for the 12 GeV upgrade at JLab and an aggressive schedule maintained by the MSU Conventional Facilities department. Reported here is an updated status of the cryogenic plant, including the equipment procurement status, plant layout, facility equipment and project schedule.

Academic Training: Introduction to cryogenic Engineering

CERN Multimedia

Françoise Benz

2005-01-01

2005-2006 ACADEMIC TRAINING PROGRAMME LECTURE SERIES 5, 6, 7, 8 and 9 December from 11:00 to 12:00 - Main Auditorium, bldg. 500 Introduction to cryogenic Engineering by G. Perinic - CERN-AT Cryogenic engineering is one of the key technologies at CERN. It is widely used in research and has many applications in industry and last but not least in medicine. In research cryogenic engineering and its applications are omnipresent from the smallest laboratories to fusion reactors, huge detectors and accelerators. With the termination of the LHC, CERN will in fact become the world’s largest cryogenic installation. This series of talks intends to introduce the non-cryogenist to the basic principles and challenges of cryogenic engineering and its applications. The course will also provide a basis for practical application as well as for further learning. Monday 5.12.2005 Introduction: From History to Modern Refrigeration Cycles (Goran Perinic) Tuesday 6.12.2005 Refrigerants, Standard Cryostats, Cryogenic Des...

Academic Training: Introduction to cryogenic Engineering

CERN Multimedia

Françoise Benz

2005-01-01

2005-2006 ACADEMIC TRAINING PROGRAMME LECTURE SERIES 5, 6, 7, 8 and 9 December from 11:00 to 12:00 - Main Auditorium, bldg. 500 Introduction to cryogenic Engineering by G. Perinic - CERN-AT Cryogenic engineering is one of the key technologies at CERN. It is widely used in research and has many applications in industry and last but not least in medicine. In research cryogenic engineering and its applications are omnipresent from the smallest laboratories to fusion reactors, hughe detectors and accelerators. With the termination of the LHC, CERN will in fact become the world's largest cryogenic installation. This series of talks intends to introduce the non-cryogenist to the basic principles and challenges of cryogenic engineering and its applications. The course will also provide a basis for practical application as well as for further learning. From history to modern refrigeration cycles (1/5) Refrigerants, standard cryostats, cryogenic design (2/5) Heat transfer and insulation (3/5) Safety in cryoge...

X-ray fractography on fatigue fracture surface of high manganese austenitic steel

International Nuclear Information System (INIS)

Akita, Koichi; Misawa, Hiroshi; Kodama, Shotaro; Saito, Tetsuro.

1997-01-01

Fatigue tests were carried out under constant stress amplitude, using a non-magnetic high manganese Mn-Cr steel. X-ray fractography was applied on the fatigue fractured surface to investigate the relationship between stress intensity factor and residual stress or half-value breadth of the X-ray diffraction profile. The fatigue crack propagation rate of this non-magnetic Mn-Cr steel had the same tendency as in the ordinary structural ferritic steels. The relationship between stress intensity factor and the residual stress or half-value breadth of the steel was almost the same as that of the ferritic cyclic work hardening steels. No stress induced transformation was observed on the fracture surface, but the residual stress on the fractured surface was compressive in the high stress intensity factors range, which is typical in the cyclic work hardening steels. The half-value breadth on the fractured surface increased with increasing effective stress intensity factor range. The relationship between the half-value breadth and stress intensity factor range was represented by a linear line regardless of the stress ratio. Therefore, the acting stress intensity factor range at the time of fracture can be estimated from the half-value breadth. The depth of monotonic plastic zone was estimated from the distribution of half-value breadth beneath the fractured surface. The relationship between the maximum stress intensity factor and half-value breadth was expressed by the equation ω m α(K max /σ y ) 2 , where the value of α was 0.025. This is about one sixth of the value for ferritic steels, and the fact shows the severe work hardening occuring in the plastic zone in this manganese steel. (author)

Experimental study on cryogenic adsorption of methane by activated carbon for helium coolant purification of High-Temperature Gas-cooled Reactor

International Nuclear Information System (INIS)

Chang, Hua; Wu, Zong-Xin; Jia, Hai-Jun

2017-01-01

Highlights: • The cryogenic CH 4 adsorption on activated carbon was studied for design of HTGR. • The breakthrough curves at different conditions were analyzed by the MTZ model. • The CH 4 adsorption isotherm was fitted well by the Toth model and the D-R model. • The work provides valuable reference data for helium coolant purification of HTGR. - Abstract: The cryogenic adsorption behavior of methane on activated carbon was investigated for helium coolant purification of high-temperature gas-cooled reactor by using dynamic column breakthrough method. With helium as carrier gas, experiments were performed at −196 °C and low methane partial pressure range of 0–120 Pa. The breakthrough curves at different superficial velocities and different feed concentrations were measured and analyzed by the mass-transfer zone model. The methane single-component adsorption isotherm was obtained and fitted well by the Toth model and the Dubinin-Radushkevich model. The adsorption heat of methane on activated carbon was estimated. The cryogenic adsorption process of methane on activated carbon has been verified to be effective for helium coolant purification of high-temperature gas-cooled reactor.

Cryogenic Hydrogen Fuel for Controlled Inertial Confinement Fusion (Cryogenic Target Factory Concept Based on FST-Layering Method)

Science.gov (United States)

Aleksandrova, I. V.; Koresheva, E. R.; Koshelev, I. E.; Krokhin, O. N.; Nikitenko, A. I.; Osipov, I. E.

2017-12-01

A central element of a power plant based on inertial confinement fusion (ICF) is a target with cryogenic hydrogen fuel that should be delivered to the center of a reactor chamber with a high accuracy and repetition rate. Therefore, a cryogenic target factory (CTF) is an integral part of any ICF reactor. A promising way to solve this problem consists in the FST layering method developed at the Lebedev Physical Institute (LPI). This method (rapid fuel layering inside moving free-standing targets) is unique, having no analogs in the world. The further development of FST-layering technologies is implemented in the scope of the LPI program for the creation of a modular CTF and commercialization of the obtained results. In this report, we discuss our concept of CTF (CTF-LPI) that exhibits the following distinctive features: using a FST-layering technology for the elaboration of an in-line production of cryogenic targets, using an effect of quantum levitation of high-temperature superconductors (HTSCs) in magnetic field for noncontacting manipulation, transport, and positioning of the free-standing cryogenic targets, as well as in using a Fourier holography technique for an on-line characterization and tracking of the targets flying into the reactor chamber. The results of original experimental and theoretical investigations performed at LPI indicate that the existing and developing target fabrication capabilities and technologies can be applied to ICF target production. The unique scientific, engineering, and technological base developed in Russia at LPI allows one to make a CTFLPI prototype for mass production of targets and delivery thereof at the required velocity into the ICF reactor chamber.

Effects of manganese and manganese-nitrogen applications on growth and nutrition of Douglas-fir seedlings.

Science.gov (United States)

M. A. Radwan; John S. Shumway; Dean S. DeBell

1979-01-01

Effects of manganese (Mn) on Douglas-fir grown in soil, with and without urea, and in nutrient solution were investigated. In addition, Mn sorption by forest soils was evaluated. Results show that Douglas-fir does not respond to added Mn and is quite tolerant to high Mn levels. Moreover, Mn sorption by soils is high. It is doubtful that Mn toxicity is of practical...

Matrix isolation sublimation: An apparatus for producing cryogenic beams of atoms and molecules

Energy Technology Data Exchange (ETDEWEB)

Sacramento, R. L.; Alves, B. X.; Silva, B. A.; Wolff, W.; Cesar, C. L. [Instituto de Física, Universidade Federal do Rio de Janeiro, Caixa Postal 68528, 21941-972 Rio de Janeiro, RJ (Brazil); Oliveira, A. N. [Instituto de Física, Universidade Federal do Rio de Janeiro, Caixa Postal 68528, 21941-972 Rio de Janeiro, RJ (Brazil); INMETRO, Av. Nossa Senhora das Graças, 50 25250-020 Duque de Caxias, RJ (Brazil); Li, M. S. [Instituto de Física de São Carlos, Universidade de São Paulo, Ave. Trabalhador São Carlense, 400, 13565-590 São Carlos, SP (Brazil)

2015-07-15

We describe the apparatus to generate cryogenic beams of atoms and molecules based on matrix isolation sublimation. Isolation matrices of Ne and H{sub 2} are hosts for atomic and molecular species which are sublimated into vacuum at cryogenic temperatures. The resulting cryogenic beams are used for high-resolution laser spectroscopy. The technique also aims at loading atomic and molecular traps.

In vitro sensitivity testing of Cladobotryum mycophilum to carbendazim and prochloraz manganese

Directory of Open Access Journals (Sweden)

Alinesi Chakwiya

2015-11-01

Full Text Available Limited information of fungicide efficacy on cultivated mushrooms and resistance development potential is available. Minor crop industries in general have a smaller arsenal of protectants to rely on and the likelihood of resistance build-up is of greater concern. This study focused on Cladobotryum mycophilum's sensitivity to carbendazim and prochloraz manganese following recent reports on decreased efficacy of both fungicides. The median effective dose (ED50 values for carbendazim ranged between 0.02 mg/L and 4.31 mg/L with 60% of the South African isolates being moderately resistant. The highest resistance factor for carbendazim was 215. Prochloraz manganese ED50 values varied from 0.00001 mg/L to 0.55 mg/L. A significant difference in mean ED50 values for both fungicides tested was observed. Using cluster analysis, no discrimination of isolates previously exposed and unexposed to prochloraz manganese was observed. A wide range of differences in ED50 values indicated moderate resistance to carbendazim and high sensitivity to prochloraz manganese among isolates under investigation. Discriminant analysis indicated significant differences between clusters contributed by one or a few variables. This study provided evidence that prochloraz manganese remains highly fungitoxic to C. mycophilum. However, prochloraz manganese is to be used in a disease management strategy in combination with strict farm hygiene management strategies to retain product efficacy and ensure crop protection.

Dimensional crossover in manganese based analogues of iron pnictides

Energy Technology Data Exchange (ETDEWEB)

Zingl, Manuel; Assmann, Elias; Aichhorn, Markus [University of Technology, Institute of Theoretical Physics and Computational Physics, Graz (Austria)

2016-07-01

The manganese pnicitides BaMn{sub 2}As{sub 2} and LaOMnAs crystallize in the same structure as the extensively studied iron pnictide high-temperature superconductors BaFe{sub 2}As{sub 2} and LaOFeAs. In contrast to the d{sup 6} configuration of the iron systems, the manganese d-shell is only half-filled (d{sup 5}). As a consequence, electronic correlations are much stronger, placing these compounds at the verge of the Mott metal-insulator transition. In this region of the phase diagram materials are prone to enhanced magnetism, apparent in the remarkably high Neel temperature of 625 K for BaMn{sub 2}As{sub 2}. We demonstrate that the experimentally observed differences in the Neel temperatures, the band gap, and the optical properties of the manganese compounds under consideration can be traced back to their effective dimensionality. Our fully charge self-consistent DFT+DMFT calculations show excellent agreement with experiments, especially measured optical spectra.

Biological removal of iron and manganese in rapid sand filters - Process understanding of iron and manganese removal

DEFF Research Database (Denmark)

Lin, Katie

to precipitation and corrosion. Manganese and iron can either be removed physico-chemically or biologically or combined. The physico-chemical oxidation and precipitation of manganese can theoretically be achieved by aeration, but this process is slow unless pH is raised far above neutral, making the removal...... of manganese by simple aeration and precipitation under normal drinking water treatment conditions insignificant. Manganese may also be oxidized autocatalytically. Iron is usually easier to remove. First, iron is rapidly chemically oxidized by oxygen at neutral pH followed by precipitation and filtration......-filter, where iron is removed. Step 2: Filtration in an after-filter where e.g. ammonium and manganese is removed. The treatment relies on microbial processes and may present an alternative, greener and more sustainable approach for drinking water production spending less chemicals and energy than chemical (e...

The sorption of silver by poorly crystallized manganese oxides

Science.gov (United States)

Anderson, B.J.; Jenne, E.A.; Chao, T.T.

1973-01-01

The sorption of silver by poorly crystallized manganese oxides was studied using synthesized samples of three members of the manganous manganite (birnessite) group, of different chemical composition and crystallinity, and a poorly organized ??-MnO2. All four oxides sorbed significant quantities of silver. The manganous manganites showed the greatest sorption (up to 0.5 moles silver/mole MnOx at pH 7) while the ??-MnO2 showed the least (0.3 moles silver/ mole MnOx at pH 7). Sorption of silver was adequately described by the Langmuir equation over a considerable concentration range. The relationship failed at low pH values and high equilibrium silver concentrations. The sorption capacity showed a direct relationship with pH. However, the rate of increase of sorption capacity decreased at the higher pH values. Silver sorption maxima. were not directly related to surface area but appeared to vary with the amount of occluded sodium and potassium present in the manganese oxide. The important processes involved in the uptake of silver by the four poorly crystallized manganese oxides ara considered to be surface exchange for manganese, potassium and sodium as well as exchange for structural manganese, potassium and sodium. ?? 1973.

The effect of spices and manganese on meat starter culture activity.

Science.gov (United States)

Coventry, M J; Hickey, M W

1993-01-01

Three species, two proprietary spice blends and six starter preparations used in commercial salami manufacture were analysed for manganese and magnesium content. A mettwurst spices blend showed the highest levels of manganese (0·77 ppm expressed as effective product level assuming a 1% spice content) while mild and hot paprika and milano blend contained levels of manganese 1 4 - 1 3 lower. Magnesium levels for spices ranged from 3·14 to 25·81 ppm. Only two of the six meat starter cultures showed high levels of manganese (7·77 and 16·12 ppm as effective product level based on inoculation rate) while magnesium levels for all starter cultures did not exceed 0·37 ppm. The pH of salami products made with starter cultures containing no added manganese lagged behind that of products made with added mangenese (5 ppm) by 0·2 pH units at 48 h. The effect of manganese ions on the fermentation rate of starter bacteria was studied further in a salami model system, in the absence and presence of added spices. The mettwurst blend produced greatest stimulation and the milano the least. A level of 1·2 ppm of added manganese was sufficient to achieve an optimal (spices tested in the salami model system. Copyright © 1993. Published by Elsevier Ltd.

Automation, Operation, and Data Analysis in the Cryogenic, High Accuracy, Refraction Measuring System (CHARMS)

Science.gov (United States)

Frey, Bradley J.; Leviton, Douglas B.

2005-01-01

The Cryogenic High Accuracy Refraction Measuring System (CHARMS) at NASA's Goddard Space Flight Center has been enhanced in a number of ways in the last year to allow the system to accurately collect refracted beam deviation readings automatically over a range of temperatures from 15 K to well beyond room temperature with high sampling density in both wavelength and temperature. The engineering details which make this possible are presented. The methods by which the most accurate angular measurements are made and the corresponding data reduction methods used to reduce thousands of observed angles to a handful of refractive index values are also discussed.

Facile N...N coupling of manganese(V) imido species.

Science.gov (United States)

Yiu, Shek-Man; Lam, William W Y; Ho, Chi-Ming; Lau, Tai-Chu

2007-01-31

(Salen)manganese(V) nitrido species are activated by electrophiles such as trifluoroacetic anhydride (TFAA) or trifluoroacetic acid (TFA) to produce N2. Mechanistic studies suggest that the manganese(V) nitrido species first react with TFAA or TFA to produce an imido species, which then undergoes N...N coupling. It is proposed that the resulting manganese(III) mu-diazene species decomposes via internal redox to give N2 and manganese(II). The manganese(II) species is then rapidly oxidized by manganese(V) imide to give manganese(III) and CF3CONH2 (for TFAA) or NH3 (for TFA).

Development of high voltage PEEK wire with radiation-resistance and cryogenic characteristics

International Nuclear Information System (INIS)

Fujita, T.; Hirata, T.; Araki, S.; Ohara, H.; Nishimura, H.

1989-01-01

High voltage electric wires insulated with highly-refined polyetheretherketone (PEEK) have been developed for the wiring in fusion reactors, where the wire is required to withstand high voltage under high vacuum up to 10 -5 Torr. The PEEK wires having the advantages of PEEK resin including superior radiation resistance and cryogenic characteristics are usable over a wide range of temperature and in radiation fields. The results of withstand voltage tests proved that the PEEK wires exceeding 0.8 mm in insulation thickness withstand such specified high voltage conditions as 24 kV for 1 minutes by 10 times and 6.6 kV for 110 hours. The results also revealed that the withstand voltage is improved by providing a jacket layer over the insulation and decreased by periodical voltage charge, by bending of the specimen and by water in the conductor. This paper deal with the withstand voltage test results under varied conditions of the PEEK wires. (author)

Cryogenic storage tank with built-in pump

International Nuclear Information System (INIS)

Zwick, E.B.

1984-01-01

A cryogenic storage tank with a built-in pump for pumping cryogen directly from the primary storage container consistent with low boil-off losses of cryogen has an outer vessel, an inner vessel and an evacuated insulation space therebetween. A pump mounting tube assembly extends into the interior of the inner vessel and includes an inner pump mounting tube and an outer pump mounting tube joined at their lower rims to define an insulating jacket between the two tubes. The inner pump mounting tube is affixed at its upper end to the outer vessel while the outer pump mounting tube is affixed at its upper end to the inner vessel. The inner pump mounting tube defines a relatively long heat path into the cryogenic container and is itself insulated from the liquid cryogen by a pocket of trapped gas formed within the inner pump mounting tube by heated cryogen. A pump may be introduced through the inner pump mounting tube and is also insulated against contact with liquid cryogen by the trapped gas such that only the lowermost end of the pump is immersed in cryogen thereby minimizing heat leakage into the tank

High Rate Performance Nanocomposite Electrode of Mesoporous Manganese Dioxide/Silver Nanowires in KI Electrolytes

Directory of Open Access Journals (Sweden)

Yanhua Jiang

2015-10-01

Full Text Available In recent years, manganese dioxide has become a research hotspot as an electrode material because of its low price. However, it has also become an obstacle to industrialization due to its low ratio of capacitance and the low rate performance which is caused by the poor electrical conductivity. In this study, a KI solution with electrochemical activity was innovatively applied to the electrolyte, and we systematically investigated the rate performance of the mesoporous manganese dioxide and the composite electrode with silver nanowires in supercapacitors. The results showed that when mesoporous manganese dioxide and mesoporous manganese dioxide/silver nanowires composite were used as electrodes, the strength of the current was amplified five times (from 0.1 to 0.5 A/g, the remaining rates of specific capacitance were 95% (from 205.5 down to 197.1 F/g and 92% (from 208.1 down to 191.7 F/g in the KI electrolyte, and the rate performance was much higher than which in an Na2SO4 electrolyte with a remaining rate of 25% (from 200.3 down to 49.1 F/g and 60% (from 187.2 down to 113.1 F/g. The morphology and detail structure were investigated by Scanning electron microscopy, X-ray diffraction, Fourier transform infrared spectrometry and Nitrogen adsorption-desorption isotherms. The electrochemical performance was assessed by cyclic voltammograms, galvanostatic charge/discharge and electrochemical impedance spectroscopy.

Manganese and iron oxidation by fungi isolated from building stone.

Science.gov (United States)

de la Torre, M A; Gomez-Alarcon, G

1994-01-01

Acid and nonacid generating fungal strains isolated from weathered sandstone, limestone, and granite of Spanish cathedrals were assayed for their ability to oxidize iron and manganese. In general, the concentration of the different cations present in the mineral salt media directly affected Mn(IV) oxide formation, although in some cases, the addition of glucose and nitrate to the culture media was necessary. Mn(II) oxidation in acidogenic strains was greater in a medium containing the highest concentrations of glucose, nitrate, and manganese. High concentrations of Fe(II), glucose, and mineral salts were optimal for iron oxidation. Mn(IV) precipitated as oxides or hydroxides adhered to the mycelium. Most of the Fe(III) remained in solution by chelation with organic acids excreted by acidogenic strains. Other metabolites acted as Fe(III) chelators in nonacidogenic strains, although Fe(III) deposits around the mycelium were also detected. Both iron and manganese oxidation were shown to involve extracellular, hydrosoluble enzymes, with maximum specific activities during exponential growth. Strains able to oxidize manganese were also able to oxidize iron. It is concluded that iron and manganese oxidation reported in this work were biologically induced by filamentous fungi mainly by direct (enzymatic) mechanisms.

The cryogenic cooling program at the Advanced Photon Source

International Nuclear Information System (INIS)

Rogers, C.S.; Mills, D.M.; Assoufid, L.

1994-06-01

This paper describes the experimental and analytical program in cryogenic cooling of high-heat-load optics at the Advanced-Photon Source. A prototype liquid nitrogen pumping system has been procured. This pump provides a variable flow rate of 1 to 10 gpm of pressurized liquid nitrogen and is sized to handle up to 5 kW of optic heat load. Also, a high-vacuum, double-crystal monochromator testing tank has been fabricated. This system will be used to test cryogenic crystals at existing synchrotron sources. A finite element analysis has been performed for a cryogenically cooled Si crystal in the inclined geometry for Undulator A at 100 mA. The inclination angle was 80 degrees. It was set to diffract from the (111) planes at the first harmonic energy of 4.2 keV. The maximum slope error in the diffraction plane was calculated to be about 1 μrad with a peak temperature of 94 K. An analysis has also been performed for a cryogenically-cooled ''thin'' crystal oriented in the Bragg geometry which accepts 87% of the lst harmonic photons at 3.866 keV. The total absorbed power was 131 W at 100 mA current and the peak temperature was 124 K

Cryogen therapy of skin cancer

International Nuclear Information System (INIS)

Zikiryakhodjaev, D.Z.; Sanginov, D.R.

2001-01-01

In this chapter authors studied the cure of skin cancer in particular cryogen therapy of skin cancer. They noted that cryogen therapy of skin cancer carried new possibilities and improved results of neoplasms treatment

The Cryogenic Test Bed experiments: Cryogenic heat pipe flight experiment CRYOHP (STS-53). Cryogenic two phase flight experiment CRYOTP (STS-62). Cryogenic flexible diode flight experiment CRYOFD

Science.gov (United States)

Thienel, Lee; Stouffer, Chuck

1995-09-01

This paper presents an overview of the Cryogenic Test Bed (CTB) experiments including experiment results, integration techniques used, and lessons learned during integration, test and flight phases of the Cryogenic Heat Pipe Flight Experiment (STS-53) and the Cryogenic Two Phase Flight Experiment (OAST-2, STS-62). We will also discuss the Cryogenic Flexible Diode Heat Pipe (CRYOFD) experiment which will fly in the 1996/97 time frame and the fourth flight of the CTB which will fly in the 1997/98 time frame. The two missions tested two oxygen axially grooved heat pipes, a nitrogen fibrous wick heat pipe and a 2-methylpentane phase change material thermal storage unit. Techniques were found for solving problems with vibration from the cryo-collers transmitted through the compressors and the cold heads, and mounting the heat pipe without introducing parasitic heat leaks. A thermally conductive interface material was selected that would meet the requirements and perform over the temperature range of 55 to 300 K. Problems are discussed with the bi-metallic thermostats used for heater circuit protection and the S-Glass suspension straps originally used to secure the BETSU PCM in the CRYOTP mission. Flight results will be compared to 1-g test results and differences will be discussed.

Hot Ductility Behavior of Boron Containing Microalloyed Steels with Varying Manganese Contents

Science.gov (United States)

Brune, Tobias; Senk, Dieter; Walpot, Raphael; Steenken, Bernhard

2015-02-01

The hot ductility is measured for six different steel grades with different microalloying elements and with varying manganese contents using the hot tensile test machine with melting/solidification unit at the Department of Ferrous Metallurgy RWTH Aachen University. To identify the influence of manganese on hot ductility, tests are performed with varying the manganese content from 0.7 to 18.2 wt pct, a high manganese steel. Additionally, the effect of different cooling and strain rates is analyzed by changing the particular rate for selected samples in the minima. To investigate and detect the cause of cracking during testing, the fracture surfaces in the ductility minima are considered with scanning electron microscope-energy dispersive X-ray spectroscopy. Thermodynamic modeling is conducted on basis of the commercial software ThermoCalc©. A sharp decrease of the hot ductility is recognizable at 1398 K (1125 °C), at only 0.7 wt pct manganese because of the low manganese to sulfur ratio. The grades with a Mn content up to 1.9 wt pct show a good ductility with minimal ductility loss. In comparison, the steel grade with 18.2 wt pct has a poor hot ductility. Because of the formation of complex precipitates, where several alloying elements are involved, the influence of boron on hot ductility is not fully clarified. By increasing the cooling rate, the reduction of area values are shifted to smaller values. For high test temperatures, these measured values are decreased for lower strain rates. Thereby, an early drop of the ductility is noticeable for the high temperatures around 1373 K (1100 °C).

Uniform manganese hexacyanoferrate hydrate nanocubes featuring superior performance for low-cost supercapacitors and nonenzymatic electrochemical sensors

Science.gov (United States)

Pang, Huan; Zhang, Yizhou; Cheng, Tao; Lai, Wen-Yong; Huang, Wei

2015-09-01

Uniform manganese hexacyanoferrate hydrate nanocubes are prepared via a simple chemical precipitation method at room temperature. Due to both micro/mesopores of the Prussian blue analogue and nanocubic structures, the manganese hexacyanoferrate hydrate nanocubes allow the efficient charge transfer and mass transport for electrolyte solution and chemical species. Thus, the manganese hexacyanoferrate hydrate nanocube electrode shows a good rate capability and cycling stability for electrochemical capacitors. Furthermore, electrodes modified with manganese hexacyanoferrate hydrate nanocubes demonstrate a sensitive electrochemical response to hydrogen peroxide (H2O2) in buffer solutions with a high selectivity.Uniform manganese hexacyanoferrate hydrate nanocubes are prepared via a simple chemical precipitation method at room temperature. Due to both micro/mesopores of the Prussian blue analogue and nanocubic structures, the manganese hexacyanoferrate hydrate nanocubes allow the efficient charge transfer and mass transport for electrolyte solution and chemical species. Thus, the manganese hexacyanoferrate hydrate nanocube electrode shows a good rate capability and cycling stability for electrochemical capacitors. Furthermore, electrodes modified with manganese hexacyanoferrate hydrate nanocubes demonstrate a sensitive electrochemical response to hydrogen peroxide (H2O2) in buffer solutions with a high selectivity. Electronic supplementary information (ESI) available. See DOI: 10.1039/c5nr04322k

Hydrometallurgical Process and Kinetics of Leaching Manganese from Semi-Oxidized Manganese Ores with Sucrose

Directory of Open Access Journals (Sweden)

Yuhong Wang

2017-02-01

Full Text Available The extraction of manganese from a semi-oxidized manganese ore was investigated with sucrose as the reducing agent in dilute sulfuric acid medium. The kinetics of leaching manganese from the complex ore containing MnCO3 and MnO2 was also investigated. The effects of sucrose and sulfuric acid concentrations, leaching temperature and reaction time on the total Mn (TMn, MnO2 and MnCO3 leaching were investigated. Results showed that MnCO3 could more easily react with hydrogen ions than MnO2 in ores, and MnO2 decomposition could be advantageous for MnCO3 leaching. The leaching efficiencies of 91.8% for total Mn, 91.4% for MnO2 and 96.9% for MnCO3 were obtained under the following optimized conditions: 0.035 mol/L sucrose concentration, 5 mol/L sulfuric acid concentration, 60 min of reaction time and 363.2 K of leaching temperature. In addition, it was found that the leaching process of semi-oxidized manganese ore follows the shrinking core model and the leaching rate was controlled by chemical reaction and diffusion. The apparent activation energy of the total manganese, MnO2, and MnCO3 leaching were 40.83, 40.59, and 53.33 kJ·mol−1, respectively.

Hybrid Cryogenic Tank Construction and Method of Manufacture Therefor

Science.gov (United States)

DeLay, Thomas K. (Inventor)

2011-01-01

A lightweight, high-pressure cryogenic tank construction includes an inner layer comprising a matrix of fiber and resin suitable for cryogenic use. An outer layer in intimate contact with the inner layer provides support of the inner layer, and is made of resin composite. The tank is made by placing a fiber preform on a mandrel and infusing the preform with the resin. The infused preform is then encapsulated within the outer layer.

Soil manganese enrichment from industrial inputs: a gastropod perspective.

Directory of Open Access Journals (Sweden)

Despina-Maria Bordean

Full Text Available Manganese is one of the most abundant metal in natural environments and serves as an essential microelement for all living systems. However, the enrichment of soil with manganese resulting from industrial inputs may threaten terrestrial ecosystems. Several studies have demonstrated harmful effects of manganese exposure by cutaneous contact and/or by soil ingestion to a wide range of soil invertebrates. The link between soil manganese and land snails has never been made although these invertebrates routinely come in contact with the upper soil horizons through cutaneous contact, egg-laying, and feeding activities in soil. Therefore, we have investigated the direct transfer of manganese from soils to snails and assessed its toxicity at background concentrations in the soil. Juvenile Cantareus aspersus snails were caged under semi-field conditions and exposed first, for a period of 30 days, to a series of soil manganese concentrations, and then, for a second period of 30 days, to soils with higher manganese concentrations. Manganese levels were measured in the snail hepatopancreas, foot, and shell. The snail survival and shell growth were used to assess the lethal and sublethal effects of manganese exposure. The transfer of manganese from soil to snails occurred independently of food ingestion, but had no consistent effect on either the snail survival or shell growth. The hepatopancreas was the best biomarker of manganese exposure, whereas the shell did not serve as a long-term sink for this metal. The kinetics of manganese retention in the hepatopancreas of snails previously exposed to manganese-spiked soils was significantly influenced by a new exposure event. The results of this study reveal the importance of land snails for manganese cycling in terrestrial biotopes and suggest that the direct transfer from soils to snails should be considered when precisely assessing the impact of anthropogenic Mn releases on soil ecosystems.

Synchrotron-Based Techniques Shed Light on Mechanisms of Plant Sensitivity and Tolerance to High Manganese in the Root Environment

Science.gov (United States)

Plant species differ in response to high available manganese (Mn), but the mechanisms of sensitivity and tolerance are poorly understood. In solution culture, greater than or equal to 30 µM Mn decreased the growth of soybean (Glycine max), but white lupin (Lupinus albu...

The effect of prior tempering on cryogenic treatment to reduce retained austenite

International Nuclear Information System (INIS)

Stratton, Paul

2010-01-01

The consensus view is that a high carbon case gives gears the best overall properties provided that there is no carbide network and that the retained austenite has been reduced below 20% by cryogenic treatment. This view is effectively enshrined in the SAE AMS 2759/7 standard. The cryogenic treatment usually takes place immediately after the quench to avoid austenite stabilisation. However, for some parts with complex geometries that might crack during the treatment, a short low temperature temper is carried out first. Little is known on how this temper affects the subsequent cryogenic treatment. Three carburizing steels used extensively in the aerospace industry were carburized to produce high retained austenite levels in the case using two different, but typical carburizing cycles. The retained austenite was determined by XRD before and after cryogenic treatment carried out in accordance with the standard and compared with that obtained when an intermediate temper was used. This study shows that for three typical carburizing steels, carburized using typical cycles, the efficacy of the cryogenic treatment is reduced only slightly after the temper, and not enough to be industrially significant. (author)

Manganese determination om minerals by activation analysis, using the californium-252 as a neutron source

International Nuclear Information System (INIS)

Cardoso, Antonio

1976-01-01

Neutron Activation Analysis, using a Californium-252 neutron source, has been applied for the determination of manganese in ores such as pyrolusite, rodonite (manganese silicate)' and blending used in dry-batteries The favorable nuclear properties of manganese, such as high thermal neutron cross-section for the reaction 55 Mn (n.gamma) 56 Mn, high concentration of manganese in the matrix and short half - life of 56 Mn, are an ideal combination for non-destructive analysis of manganese in ores. Samples and standards of manganese dioxide were irradiated for about 20 minutes, followed by a 4 to 15 minutes decay and counted in a single channel pulse-height discrimination using a NaI(Tl) scintillation detector. Counting time was equal to 10 minutes. The interference of nuclear reactions 56 Fe(n,p) 56 Mn and 59 Co (n, α) 56 were studied, as well as problems in connection with neutron shadowing during irradiation, gamma-rays attenuation during counting and influence of granulometry of samples. One sample,was also analysed by wet-chemical method (sodium bismuthate) in order to compare results. As a whole, i t was shown that the analytical method of neutron activation for manganese in ores and blending, is a method simple, rapid and with good precision and accuracy. (author)

Specification of the 2nd cryogenic plant for RAON

Science.gov (United States)

Yoon, S.; Ki, T.; Lee, K. W.; Kim, Y.; Jo, H. C.; Kim, D. G.

2017-12-01

RAON is a rare isotope beam facility being built at Daejeon, South Korea. The RAON consists of three linear accelerators, SCL1 (1st SuperConducting LINAC), SCL2, and SCL3. Each LINAC has its own cryogenic plant. The cryogenic plant for SCL2 will provide the cooling for cryomodules, low temperature SC magnets, high temperature SC magnets, and a cryogenic distribution system. This paper describes the specification of the plant including cooling capacity, steady state and transient operation modes, and cooling strategies. In order to reduce CAPEX with the specification, two suppliers will consider no liquid nitrogen pre-cooling, one integrated cold box, and one back-up HP compressor. The detail design of the plant will be started at the end of this year.

Termination for a superconducting power transmission line including a horizontal cryogenic bushing

Science.gov (United States)

Minati, Kurt F.; Morgan, Gerry H.; McNerney, Andrew J.; Schauer, Felix

1984-01-01

A termination for a superconducting power transmission line is disclosed which is comprised of a standard air entrance insulated vertical bushing with an elbow, a horizontal cryogenic bushing linking the pressurized cryogenic cable environment to the ambient temperature bushing and a stress cone which terminates the cable outer shield and transforms the large radial voltage gradient in the cable dielectric into a much lower radial voltage gradient in the high density helium coolant at the cold end of the cryogenic bushing.

Manganese in silicon carbide

Energy Technology Data Exchange (ETDEWEB)

Linnarsson, M.K., E-mail: marga@kth.se [Royal Institute of Technology, School of Information and Communication Technology, P.O. Box E229, SE-16440 Kista-Stockhom (Sweden); Hallen, A. [Royal Institute of Technology, School of Information and Communication Technology, P.O. Box E229, SE-16440 Kista-Stockhom (Sweden)

2012-02-15

Structural disorder and relocation of implanted Mn in semi-insulating 4H-SiC has been studied. Subsequent heat treatment of Mn implanted samples has been performed in the temperature range 1400-2000 Degree-Sign C. The depth distribution of manganese is recorded by secondary ion mass spectrometry. Rutherford backscattering spectrometry has been employed for characterization of crystal disorder. Ocular inspection of color changes of heat-treated samples indicates that a large portion of the damage has been annealed. However, Rutherford backscattering shows that after heat treatment, most disorder from the implantation remains. Less disorder is observed in the [0 0 0 1] channel direction compared to [112{sup Macron }3] channel direction. A substantial rearrangement of manganese is observed in the implanted region. No pronounced manganese diffusion deeper into the sample is recorded.

Manganese in silicon carbide

International Nuclear Information System (INIS)

Linnarsson, M.K.; Hallén, A.

2012-01-01

Structural disorder and relocation of implanted Mn in semi-insulating 4H–SiC has been studied. Subsequent heat treatment of Mn implanted samples has been performed in the temperature range 1400–2000 °C. The depth distribution of manganese is recorded by secondary ion mass spectrometry. Rutherford backscattering spectrometry has been employed for characterization of crystal disorder. Ocular inspection of color changes of heat-treated samples indicates that a large portion of the damage has been annealed. However, Rutherford backscattering shows that after heat treatment, most disorder from the implantation remains. Less disorder is observed in the [0 0 0 1] channel direction compared to [112 ¯ 3] channel direction. A substantial rearrangement of manganese is observed in the implanted region. No pronounced manganese diffusion deeper into the sample is recorded.

Cryogenics for the MuCool Test Area (MTA)

International Nuclear Information System (INIS)

Darve, Christine; Norris, Barry; Pei, Liujin

2006-01-01

MuCool Test Area (MTA) is a complex of buildings at Fermi National Accelerator Laboratory, which are dedicated to operate components of a cooling cell to be used for Muon Collider and Neutrino Factory R and D. The long-term goal of this facility is to test ionization cooling principles by operating a 25-liter liquid hydrogen (LH2) absorber embedded in a 5 Tesla superconducting solenoid magnet. The MTA solenoid magnet will be used with RF cavities exposed to a high intensity beam. Cryogens used at the MTA include LHe, LN2 and LH2. The latter dictates stringent system design for hazardous locations. The cryogenic plant is a modified Tevatron refrigerator based on the Claude cycle. The implementation of an in-house refrigerator system and two 300 kilowatt screw compressors is under development. The helium refrigeration capacity is 500 W at 14 K. In addition the MTA solenoid magnet will be batch-filled with LHe every 2 days using the same cryo-plant. This paper reviews cryogenic systems used to support the Muon Collider and Neutrino Factory R and D programs and emphasizes the feasibility of handling cryogenic equipment at MTA in a safe manner

Sedimentary manganese metallogenesis in response to the evolution of the Earth system

Science.gov (United States)

Roy, Supriya

2006-08-01

supercontinent. Tectonic rifting and mantle outgassing led to deglaciation. Dissolved Mn 2+ and Fe 2+ concentrated earlier in highly saline stagnant seawater below the ice cover were exported to shallow shelves by transgression during deglaciation. During the Sturtian glacial-interglacial event (ca. 750-700 Ma), interstratified Mn oxide and BIF deposits of Damara sequence, Namibia, was formed. The Varangian (≡ Marinoan; ca. 600 Ma) cryogenic event produced Mn oxide and BIF deposits at Urucum, Jacadigo Group, Brazil. The Datangpo interglacial sequence, South China (Liantuo-Nantuo ≡ Varangian event) contains black shale-hosted Mn carbonate deposits. The Early Paleozoic witnessed several glacioeustatic sea level changes producing small Mn carbonate deposits of Tiantaishan (Early Cambrian) and Taojiang (Mid-Ordovician) in black shale sequences, China, and the major Mn oxide-carbonate deposits of Karadzhal-type, Central Kazakhstan (Late Devonian). The Mesozoic period of intense plate movements and volcanism produced greenhouse climate and stratified oceans. During the Early Jurassic OAE, organic-rich sediments host many Mn carbonate deposits in Europe (e.g., Úrkút, Hungary) in black shale sequences. The Late Jurassic giant Mn Carbonate deposit at Molango, Mexico, was also genetically related to sea level change. Mn carbonates were always derived from Mn oxyhydroxides during early diagenesis. Large Mn oxide deposits of Cretaceous age at Groote Eylandt, Australia and Imini-Tasdremt, Morocco, were also formed during transgression-regression in greenhouse climate. The Early Oligocene giant Mn oxide-carbonate deposit of Chiatura (Georgia) and Nikopol (Ukraine) were developed in a similar situation. Thereafter, manganese sedimentation was entirely shifted to the deep seafloor and since ca. 15 Ma B.P. was climatically controlled (glaciation-deglaciation) assisted by oxygenated polar bottom currents (AABW, NADW). The changes in climate and the sea level were mainly tectonically forced.

Contribution to the study of iron-manganese alloy oxidation in oxygen at high temperatures

International Nuclear Information System (INIS)

Olivier, Francoise

1972-01-01

This research thesis reports a systematic investigation of the oxidation of three relatively pure iron-manganese alloys in oxygen, under atmospheric pressure, and between 400 and 1000 C, these alloys being annealed as well as work-hardened. It also compares their behaviour with that of non-alloyed iron oxidized under the same conditions. The author describes the experimental techniques and installations, discusses the morphology of oxide films formed under the experimental conditions, discusses the film growth kinetics which is studied by thermogravimetry, proposes interpretations of results, and outlines the influence of manganese addition to iron on iron oxidation

Reduction of ripening time of full-scale manganese removal filters with manganese oxide-coated media

NARCIS (Netherlands)

Bruins, J.H.; Petrusevski, B.; Slokar, Y.M.; Huysman, K.; Joris, K.; Kruithof, J.C.; Kennedy, M.D.

2015-01-01

Effective manganese removal by conventional aeration-filtration with virgin filter media requires a long ripening time. The aim of this study was to assess the potential of manganese oxide-coated media to shorten the ripening time of filters with virgin media, under practical conditions. A full

Autoradiography of manganese: accumulation and retention in the pancreas

International Nuclear Information System (INIS)

Lyden, A.; Lindquist, N.G.; Larsson, B.S.

1983-01-01

By means of whole-body autoradiography, the general distribution of 54 MnCl 2 was studied in mice and a Marmoset monkey. High accumulation and retention were observed in the pancreas in both species. Gamma counting experiments in mice after a single intravenous injection of 54 MnCl 2 showed that the level in the pancreas exceeded that of the liver at all survival times (20 min. - 30 days). Also in the monkey, the concentration in the pancreas exceeded that of the liver, and the pancreas had the highest tissue/liver ratio of the organs measured at 24 hours after injection. The high uptake and long retention in the pancreas suggest that manganese is of importance for the pancreatic function but also that the pancreas may be a target organ for manganese toxicity. Positron tomography, using 11 C-labelled amino acids, has been found to be a promising diagnostic technique for the study of pancreatic disease. Positron emitting manganese isotopes may be worth further studies as possible agents for pancreatic imaging. (author)

National and International Security Applications of Cryogenic Detectors - Mostly Nuclear Safeguards

International Nuclear Information System (INIS)

Rabin, Michael W.

2009-01-01

As with science, so with security--in both arenas, the extraordinary sensitivity of cryogenic sensors enables high-confidence detection and high-precision measurement even of the faintest signals. Science applications are more mature, but several national and international security applications have been identified where cryogenic detectors have high potential payoff. International safeguards and nuclear forensics are areas needing new technology and methods to boost speed, sensitivity, precision and accuracy. Successfully applied, improved nuclear materials analysis will help constrain nuclear materials diversion pathways and contribute to treaty verification. Cryogenic microcalorimeter detectors for X-ray, gamma-ray, neutron, and alpha-particle spectrometry are under development with these aims in mind. In each case the unsurpassed energy resolution of microcalorimeters reveals previously invisible spectral features of nuclear materials. Preliminary results of quantitative analysis indicate substantial improvements are still possible, but significant work will be required to fully understand the ultimate performance limits.

National and International Security Applications of Cryogenic Detectors—Mostly Nuclear Safeguards

Science.gov (United States)

Rabin, Michael W.

2009-12-01

As with science, so with security—in both arenas, the extraordinary sensitivity of cryogenic sensors enables high-confidence detection and high-precision measurement even of the faintest signals. Science applications are more mature, but several national and international security applications have been identified where cryogenic detectors have high potential payoff. International safeguards and nuclear forensics are areas needing new technology and methods to boost speed, sensitivity, precision and accuracy. Successfully applied, improved nuclear materials analysis will help constrain nuclear materials diversion pathways and contribute to treaty verification. Cryogenic microcalorimeter detectors for X-ray, gamma-ray, neutron, and alpha-particle spectrometry are under development with these aims in mind. In each case the unsurpassed energy resolution of microcalorimeters reveals previously invisible spectral features of nuclear materials. Preliminary results of quantitative analysis indicate substantial improvements are still possible, but significant work will be required to fully understand the ultimate performance limits.

International and national security applications of cryogenic detectors - mostly nuclear safeguards

International Nuclear Information System (INIS)

Rabin, Michael W.

2009-01-01

As with science, so with security - in both arenas, the extraordinary sensitivity of cryogenic sensors enables high-confidence detection and high-precision measurement even of the faintest signals. Science applications are more mature, but several national and international security applications have been identified where cryogenic detectors have high potential payoff. International safeguards and nuclear forensics are areas needing new technology and methods to boost speed, sensitivity, precision and accuracy. Successfully applied, improved nuclear materials analysis will help constrain nuclear materials diversion pathways and contribute to treaty verification. Cryogenic microcalorimeter detectors for X-ray, gamma ray, neutron, and alpha particle spectrometry are under development with these aims in mind. In each case the unsurpassed energy resolution of microcalorimeters reveals previously invi sible spectral features of nuclear materials. Preliminary results of quantitative analysis indicate substantial improvements are still possible, but significant work will be required to fully understand the ultimate performance limits.

Sinterization of manganese ore tailings under argon atmosphere

Energy Technology Data Exchange (ETDEWEB)

Valduga, M.M.F.; Lima, F.; Lima, R.M.F. [Universidade Federal de Ouro Preto (UFOP), MG (Brazil)

2014-07-01

Manganese is an element widely used in Metallurgy, however the Brazilian reserves has low grade. The aim of this work was to obtain and characterize the sinters from manganese ore tailings. The fines (less than 400⧣) were calcinated (800°C - 3600s) and homogenized with activated charcoal (7 and 10%) and CaO (5 and 10%). The sintering were carried out at 1135, 1140 and 1145°C during 7200 and 14400s under argon atmosphere. The sintered products were characterized by EDS analysis, BET surface area, apparent density, X-rays diffraction and SEM/EDS. The surface area was 0.03m2/g. The alkali element present (potassium) justified the low melting point of waste (1140°C). Due to the chemical complexity of the tailings, several phases were characterized in the products: pores, silicates with high content of manganese in the matrix, other silicates with different proportions of Al, Mn, Mg and Ca, pure Fe, SiO2, etc. (author)

Sinterization of manganese ore tailings under natural air

Energy Technology Data Exchange (ETDEWEB)

Lima, M.M.F.; Souza, L.G.P.R.M.F. [Universidade Federal de Ouro Preto (UFOP), MG (Brazil)

2014-07-01

The manganese ore has wide application in metallurgy. However, from each of three hundred concentrations found, only one can be seen as a deposit. The aim of this study was to obtain and characterize a sinter from manganese ore tailing. The tailing was milled, classified (<400 ⧣) and calcinated (800°C - 3600s). The mixture had 12% moisture, 7 and 9% of activated charcoal. After homogenization, the sintering were carried out at 1140, 1145 and 1150°C during 1800, 7200 and 14400s at natural air. The sintered products were characterized by EDS analysis, BET surface area, apparent density, X-rays diffraction and SEM/EDS. The mass loss was approximately 14% and 16% in the calcination and sintering, respectively, due to the elimination of volatile products and water. The main phases characterized: SiO2, silicate with high content of manganese in the matrix and other silicates with different proportions of Ti, Na, Mn, Mg and Ca. (author)

A Fine Grain, High Mn Steel with Excellent Cryogenic Temperature Properties and Corresponding Constitutive Behaviour

Directory of Open Access Journals (Sweden)

Yuhui Wang

2018-02-01

Full Text Available A Fe-34.5 wt % Mn-0.04 wt % C ultra-high Mn steel with a fully recrystallised fine-grained structure was produced by cold rolling and subsequent annealing. The steel exhibited excellent cryogenic temperature properties with enhanced work hardening rate, high tensile strength, and high uniform elongation. In order to capture the unique mechanical behaviour, a constitutive model within finite strain plasticity framework based on Hill-type yield function was established with standard Armstrong-Frederick type isotropic hardening. In particular, the evolution of isotropic hardening was determined by the content of martensite; thus, a relationship between model parameters and martensite content is built explicitly.

Cryogenic systems for inertial fusion energy

International Nuclear Information System (INIS)

Chatain, D.; Perin, J.P.; Bonnay, P.; Bouleau, E.; Chichoux, M.; Communal, D.; Manzagol, J.; Viargues, F.; Brisset, D.; Lamaison, V.; Paquignon, G.

2008-01-01

The Low Temperatures Laboratory of CEA/Grenoble (France) is involved in the development of cryogenic systems for inertial fusion since a ten of years. A conceptual design for the cryogenic infrastructure of the Laser MegaJoule (LMJ) facility has been proposed. Several prototypes have been designed, built and tested like for example the 1500 bars cryo-compressor for the targets filling, the target positioner and the thermal shroud remover. The HIPER project will necessitate the development of such equipments. The main difference is that this time, the cryogenic targets are direct drive targets. The first phase of HIPER experiments is a single shot period. Based oil the experience gained the last years, not only by our laboratory but also by Omega and G.A teams, we could design the new HIPER equipments for this phase. Some experimental results obtained with the prototypes of the LMJ cryogenic system are given and a first conceptual design for the HIPER single shot cryogenic system is shown. (authors)

Microwave Production of Manganese from Manganese (IV) Oxide ...

African Journals Online (AJOL)

Michael O. Mensah

2015-12-02

Dec 2, 2015 ... energy consumption occurs in the upper part of the ferromanganese furnace ... The pre-reduction of manganese ores by carbon has been investigated by Abdel ..... Awaso Bauxite Ore using Waste Pure Water. Sachets as ...

Restoration of growth by manganese in a mutant strain of Escherichia coli lacking most known iron and manganese uptake systems

DEFF Research Database (Denmark)

Taudte, Nadine; German, Nadezhda; Zhu, Yong-Guan

2016-01-01

The interplay of manganese and iron homeostasis and oxidative stress in Escherichia coli can give important insights into survival of bacteria in the phagosome and under differing iron or manganese bioavailabilities. Here, we characterized a mutant strain devoid of all know iron/manganese-uptake ......The interplay of manganese and iron homeostasis and oxidative stress in Escherichia coli can give important insights into survival of bacteria in the phagosome and under differing iron or manganese bioavailabilities. Here, we characterized a mutant strain devoid of all know iron...

Cryogenic testing of the TPC superconducting solenoid

International Nuclear Information System (INIS)

Green, M.A.; Smits, R.G.; Taylor, J.D.

1983-06-01

This report describes the results of a series of tests on the TPC superconducting magnet cryogenic system which occurred during the winter and spring of 1983. The tests occurred at interaction region 2 of the PEP colliding beam facility at the Stanford Linear Accelerator Center (SLAC). The TPC Magnet Cryogenic System which was tested includes the following major components: a remote helium compressor with a full flow liquid nitrogen purification station, 400 meters of high pressure supply and low pressure return lines; and locally a CTi Model 2800 refrigerator with two Sulzer gas bearing turbines, the TPC magnet control dewar, 70 meters of transfer lines, and the TPC thin superconducting solenoid magnet. In addition, there is a conditioner (liquid nitrogen heat exchangers and gas heaters) system for cooldown and warmup of the magnet. This report describes the local cryogenic system and describes the various steps in the cooldown and operation of the TPC magnet. The tests were successful in that they showed that the TPC magnet could be cooled down in 24 hours and the magnet could be operated on the refrigerator or a helium pump with adequate cooling margin. The tests identified problems with the cryogenic system and the 2800 refrigerator. Procedures for successful operation and quenching of the superconducting magnet were developed. 19 references

Energetic basis of catalytic activity of layered nanophase calcium manganese oxides for water oxidation.

Science.gov (United States)

Birkner, Nancy; Nayeri, Sara; Pashaei, Babak; Najafpour, Mohammad Mahdi; Casey, William H; Navrotsky, Alexandra

2013-05-28

Previous measurements show that calcium manganese oxide nanoparticles are better water oxidation catalysts than binary manganese oxides (Mn3O4, Mn2O3, and MnO2). The probable reasons for such enhancement involve a combination of factors: The calcium manganese oxide materials have a layered structure with considerable thermodynamic stability and a high surface area, their low surface energy suggests relatively loose binding of H2O on the internal and external surfaces, and they possess mixed-valent manganese with internal oxidation enthalpy independent of the Mn(3+)/Mn(4+) ratio and much smaller in magnitude than the Mn2O3-MnO2 couple. These factors enhance catalytic ability by providing easy access for solutes and water to active sites and facile electron transfer between manganese in different oxidation states.

Structural and surface changes of cobalt modified manganese oxide during activation and ethanol steam reforming reaction

Science.gov (United States)

Gac, Wojciech; Greluk, Magdalena; Słowik, Grzegorz; Turczyniak-Surdacka, Sylwia

2018-05-01

Surface and structural changes of unmodified manganese and cobalt-manganese oxide during activation and ethanol steam reforming reaction conditions (ESR) were studied by means of X-ray diffraction, X-ray photoelectron spectroscopy, temperature-programmed reduction/oxidation (TPR/TPO) and transmission electron microscopy. It was shown that synthesis of cobalt manganese oxide by the redox precipitation method led to the formation of strongly dispersed cobalt ionic species within cryptomelane-based manganese oxide structure. Development of large cube-like MnO nanoparticles with spherical cobalt metallic crystallites decorated by manganese oxide on the high oxidation state and potassium species was observed during reduction. Cobalt manganese catalyst showed high initial activity and selectivity to H2 and CO2 in ethanol stem reforming reaction in the range of 390-480 °C. The drop of ethanol conversion and changes of selectivity with the time-on-stream were observed. An increase of reaction temperature led to intensification of deactivation phenomena. TEM studies evidenced coexistence of Co and CoOx nanoparticles formed under ethanol steam reforming conditions, partially covered by filamentous and encapsulating carbonaceous deposits.

Development of cryogenic permanent magnet undulator

International Nuclear Information System (INIS)

Hara, Toru; Tanaka, Takashi; Shirasawa, Katsutoshi; Kitamura, Hideo; Bizen, Teruhiko; Seike, Takamitsu; Marechal, Xavier; Tsuru, Rieko; Iwaki, Daisuke

2005-01-01

A short period undulator increases not only the photon energy of undulator radiation, but also the brilliance due to its increased number of undulator periods. As a result, brilliant undulator radiation becomes available in the photon energy range, which is currently covered by wigglers. In order to develop a short period undulator, high performance magnets are indispensable and superconductive undulators have been actively investigated in recent years. In this paper, however, we propose a new approach, so called a cryogenic permanent magnet undulator using NdFeB magnets at the temperatures around 150 K. The current status of this cryogenic permanent magnet undulator development at SPring-8 is presented including the results of the magnetic field measurements on a prototype undulator. (author)

Cryogenic aluminum-wound generator rotor concept for nuclear power conversion

International Nuclear Information System (INIS)

Schlicher, R.L.; Oberly, C.E.

1987-01-01

This paper presents a design outline for a liquid hydrogen cooled generator rotor that could be used to fabricate a 20-megawatt cryogenic generator. The armature of an existing 20-megawatt superconducting generator could be utilized in this new cryogenic generator concept without electrical modification and with minimum modification to its housing. The acquisition and operating expense of liquid helium liquefiers, refrigeration requirements and the expense of fabricating a superconductor wound generator rotor make an aluminum-wound rotor a viable alternative. Ideally, the aluminum rotor could use the higher cryogenic temperatures of liquid hydrogen at 21 K as conductor coolant and not require the more difficult fabrication techniques of a superconducting generator rotor. A most likely conductor candidate is high purity aluminum which has 0.2% its room temperature resistance at liquid hydrogen temperatures. Recent research has indicated the feasibility of fabricating high-purity aluminum conductors in a composite conductor form

Manganese activated phosphate glass for dosimetry

International Nuclear Information System (INIS)

Regulla, D.

1975-01-01

A measuring element comprises a metaphosphate glass doped with manganese as an activator. The manganese activated metaphosphate glass can detect and determine radiation doses in the range between milliroentgens and more than 10 megaroentgens. (auth)

On electrical resistivity of AISI D2 steel during various stages of cryogenic treatment

Science.gov (United States)

Lomte, Sachin Vijay; Gogte, Chandrashekhar Laxman; Peshwe, Dilip

2012-06-01

The effect of dislocation densities and residual stresses is well known in tool steels. Measurement of electrical resistivity in order to monitor dislocation densities or residual stresses has seldom been used in investigating the effect of cryogenic treatment on tool steels. Monitoring residual stresses during cryogenic treatment becomes important as it is directly related to changes due to cryogenic treatment of tool steels. For high carbon high chromium (HCHC- AISI D2) steels, not only wear resistance but dimensional stability is an important issue as the steels are extensively used in dies, precision measuring instruments. This work comprises of study of measurement of electrical resistivity of AISI D2 steel at various stages of cryogenic treatment. Use of these measurements in order to assess the dimensional stability of these steels is discussed in this paper.

Determination of semi-empirical relationship between the manganese and hydrogen atoms ratio, physical density and concentration in an aqueous solution of manganese sulphate

Energy Technology Data Exchange (ETDEWEB)

Rodrigues Bittencourt, Guilherme, E-mail: bittencourt@ird.gov.b [Instituto de Radioprotecao e Dosimetria LNMRI/IRD/CNEN, Av. Salvador Allende, s/n Recreio dos Bandeirantes, CEP 22780-160, Rio de Janeiro, RJ (Brazil); Souza Patrao, Karla Cristina de, E-mail: karla@ird.gov.b [Instituto de Radioprotecao e Dosimetria LNMRI/IRD/CNEN, Av. Salvador Allende, s/n Recreio dos Bandeirantes, CEP 22780-160, Rio de Janeiro, RJ (Brazil); Passos Leite, Sandro, E-mail: sandro@ird.gov.b [Programa de Engenharia Nuclear/COPPE, Universidade Federal do Rio de Janeiro, Ilha do Fundao, Caixa Postal 68509, 21945-970, Rio de Janeiro, RJ (Brazil); Wagner Pereira, Walsan, E-mail: walsan@ird.gov.b [Instituto de Radioprotecao e Dosimetria LNMRI/IRD/CNEN, Av. Salvador Allende, s/n Recreio dos Bandeirantes, CEP 22780-160, Rio de Janeiro, RJ (Brazil); Simoes da Fonseca, Evaldo, E-mail: evaldo@ird.gov.b [Instituto de Radioprotecao e Dosimetria LNMRI/IRD/CNEN, Av. Salvador Allende, s/n Recreio dos Bandeirantes, CEP 22780-160, Rio de Janeiro, RJ (Brazil)

2010-12-15

The Manganese sulphate solution has been used for neutron metrology through the method of Manganese Bath. This method uses physical parameters of manganese sulphate solution to obtain its corrections. This work established a functional relationship, using the gravimetric method, between those physical parameters: density, concentration and hydrogen to manganese ratio. Comparisons were done between manganese sulphate solution concentration from the Manganese Bath system of Laboratory of Metrology of Ionising Radiation and estimated values from the functional relationship obtained, showing percentage difference of less than 0.1%. This result demonstrates the usefulness in the correlation of the physical values of the solution to the MB.

Alternative irradiation system for efficiency manganese bath determination

Energy Technology Data Exchange (ETDEWEB)

Passos Leite, Sandro, E-mail: sandro@ird.gov.b [Programa de Engenharia Nuclear/COPPE, Universidade Federal do Rio de Janeiro, Ilha do Fundao, Caixa Postal 68509, 21945-970, Rio de Janeiro, RJ (Brazil); Wagner Pereira, Walsan, E-mail: walsan@ird.gov.b [Instituto de Radioprotecao e Dosimetria LNMRI/IRD/CNEN, Av. Salvador Allende, s/no, Recreio dos Bandeirantes, CEP: 22780-160, Rio de Janeiro (Brazil); Xavier da Silva, Ademir, E-mail: ademir@con.ufrj.b [Programa de Engenharia Nuclear/COPPE, Universidade Federal do Rio de Janeiro, Ilha do Fundao, Caixa Postal 68509, 21945-970, Rio de Janeiro, RJ (Brazil); Simoes da Fonseca, Evaldo, E-mail: evaldo@ird.gov.b [Instituto de Radioprotecao e Dosimetria LNMRI/IRD/CNEN, Av. Salvador Allende, s/no, Recreio dos Bandeirantes, CEP: 22780-160, Rio de Janeiro (Brazil); Souza Patrao, Karla Cristina de, E-mail: karla@ird.gov.b [Instituto de Radioprotecao e Dosimetria LNMRI/IRD/CNEN, Av. Salvador Allende, s/no, Recreio dos Bandeirantes, CEP: 22780-160, Rio de Janeiro (Brazil)

2010-12-15

An alternative irradiation system, which works with a radionuclide neutron source and manganese sulphate solution volume have been proposed for efficiency determination of a Manganese Bath System (MBS). This irradiation system was designed by simulation with MCNP5 code, considering a californium neutron source in several manganese sulphate volumes and different neutron reflectors. Although its solution specific activity are less than those in nuclear reactors, the simulation results have showed that the irradiation system proposed takes a manganese neutron capture increase up to 200 times when it compared to manganese neutron capture from a MBS whose diameter is about 100 cm. That becomes possible to use those samples for some of the absolute specific activity measuring methods.

Synthesis and electrochemical properties of high performance polyhedron sphere like lithium manganese oxide for lithium ion batteries

International Nuclear Information System (INIS)

Guo, Donglei; Wei, Xiuge; Chang, Zhaorong; Tang, Hongwei; Li, Bao; Shangguan, Enbo; Chang, Kun; Yuan, Xiao-Zi; Wang, Haijiang

2015-01-01

Graphical abstract: Polyhedron structured sphere-like LiMn 2 O 4 synthesized from β-MnO 2 nanorod precursor via a solid state reaction at a temperature of 800 °C exhibits excellent rate capability and cycling performance at both 25 °C and 55 °C. - Highlights: • Polyhedron sphere-like LiMn 2 O 4 was synthesized from β-MnO 2 nanorod precursor. • The polyhedron sphere-like LiMn 2 O 4 exhibits excellent rate capability and cycling performance. • The polyhedron sphere-like structure spinel LiMn 2 O 4 suppresses the dissolution of manganese ions. • The polyhedron sphere-like LiMn 2 O 4 has high diffusion coefficient of Li + . - Abstract: Polyhedron structured sphere-like lithium manganese oxide (LiMn 2 O 4 ) is successfully synthesized from β-MnO 2 nanorod precursor via a solid state reaction at a temperature of 800 °C. For comparison, LiMn 2 O 4 materials with nanorod and octahedron structures are also obtained from β-MnO 2 nanorod precursor at temperatures of 700 °C and 900 °C, respectively. The galvanostatic charge–discharge result shows that the polyhedron sphere-like LiMn 2 O 4 sample exhibits the best electrochemical performance at high rate and high temperature. After 100 cycles at 5 C, this electrode is able to maintain 94% of its capacity at 25 °C and 81% at 55 °C. This is attributed to that the polyhedron sphere-like spinel LiMn 2 O 4 can suppress the dissolution of manganese ions. Based on Brunauer Emmett Teller (BET), cyclic voltammetry (CV) and electrochemical impedance spectroscopy (EIS), the polyhedron sphere-like LiMn 2 O 4 sample has the lowest BET surface area, largest diffusion coefficient of Li + and least charge transfer resistance. This study provides an insight into the capacity fading of LiMn 2 O 4 electrodes and the polyhedron structured sphere-like LiMn 2 O 4 can be a promising material for lithium ion batteries

Cryogenic Propellant Storage and Transfer Technology Demonstration For Long Duration In-Space Missions

Science.gov (United States)

Meyer, Michael L.; Motil, Susan M.; Kortes, Trudy F.; Taylor, William J.; McRight, Patrick S.

2012-01-01

The high specific impulse of cryogenic propellants can provide a significant performance advantage for in-space transfer vehicles. The upper stages of the Saturn V and various commercial expendable launch vehicles have used liquid oxygen and liquid hydrogen propellants; however, the application of cryogenic propellants has been limited to relatively short duration missions due to the propensity of cryogens to absorb environmental heat resulting in fluid losses. Utilizing advanced cryogenic propellant technologies can enable the efficient use of high performance propellants for long duration missions. Crewed mission architectures for beyond low Earth orbit exploration can significantly benefit from this capability by developing realistic launch spacing for multiple launch missions, by prepositioning stages and by staging propellants at an in-space depot. The National Aeronautics and Space Administration through the Office of the Chief Technologist is formulating a Cryogenic Propellant Storage and Transfer Technology Demonstration Mission to mitigate the technical and programmatic risks of infusing these advanced technologies into the development of future cryogenic propellant stages or in-space propellant depots. NASA is seeking an innovative path for human space exploration, which strengthens the capability to extend human and robotic presence throughout the solar system. This mission will test and validate key cryogenic technological capabilities and has the objectives of demonstrating advanced thermal control technologies to minimize propellant loss during loiter, demonstrating robust operation in a microgravity environment, and demonstrating efficient propellant transfer on orbit. The status of the demonstration mission concept development, technology demonstration planning and technology maturation activities in preparation for flight system development are described.

The pros and cons of cryogenic accelerators: An engineering point of view

International Nuclear Information System (INIS)

Fox, W.

1991-01-01

The design of cryogenic linacs is a challenging engineering task; however, significant improvements in accelerator performance are possible. Resistive power losses may be reduced by a factor of four or greater. Greater flexibility is possible in thermal management as a result of substantial increases in thermal conductivity for certain materials. Radio frequency structures may by an order of magnitude more stable in terms of frequency shifts due to thermal transients resulting form very small coefficients of thermal expansion at cryogenic temperatures. Significant engineering problems must be addressed, such as the design of effective rf contacts that will not be affected by thermal cycling and the design of cryogenic mechanisms and dynamic components, such as frequency tuners, that operate reliably at cryogenic operating temperatures. The areas of high-power sparking and multipactoring have not yet been experimentally addressed. Both Los Alamos, Grumman Aerospace Corporation, and Boeing Corporation have built or are building and testing cryogenic accelerator structures. This paper reviews the advances made in cryogenic technology applied to radio frequency quadrupole (RFQ) and drift tube linac (DTL) structures and will discuss the advantages and engineering challenges that these linacs present

Scanning Quantum Cryogenic Atom Microscope

Science.gov (United States)

Yang, Fan; Kollár, Alicia J.; Taylor, Stephen F.; Turner, Richard W.; Lev, Benjamin L.

2017-03-01

Microscopic imaging of local magnetic fields provides a window into the organizing principles of complex and technologically relevant condensed-matter materials. However, a wide variety of intriguing strongly correlated and topologically nontrivial materials exhibit poorly understood phenomena outside the detection capability of state-of-the-art high-sensitivity high-resolution scanning probe magnetometers. We introduce a quantum-noise-limited scanning probe magnetometer that can operate from room-to-cryogenic temperatures with unprecedented dc-field sensitivity and micron-scale resolution. The Scanning Quantum Cryogenic Atom Microscope (SQCRAMscope) employs a magnetically levitated atomic Bose-Einstein condensate (BEC), thereby providing immunity to conductive and blackbody radiative heating. The SQCRAMscope has a field sensitivity of 1.4 nT per resolution-limited point (approximately 2 μ m ) or 6 nT /√{Hz } per point at its duty cycle. Compared to point-by-point sensors, the long length of the BEC provides a naturally parallel measurement, allowing one to measure nearly 100 points with an effective field sensitivity of 600 pT /√{Hz } for each point during the same time as a point-by-point scanner measures these points sequentially. Moreover, it has a noise floor of 300 pT and provides nearly 2 orders of magnitude improvement in magnetic flux sensitivity (down to 10-6 Φ0/√{Hz } ) over previous atomic probe magnetometers capable of scanning near samples. These capabilities are carefully benchmarked by imaging magnetic fields arising from microfabricated wire patterns in a system where samples may be scanned, cryogenically cooled, and easily exchanged. We anticipate the SQCRAMscope will provide charge-transport images at temperatures from room temperature to 4 K in unconventional superconductors and topologically nontrivial materials.

Electrochemical oxidation of sulfites by DWCNTs, MWCNTs, higher fullerenes and manganese

Science.gov (United States)

Uzun, Dzhamal; Pchelarov, George; Dimitrov, Ognian; Vassilev, Sasho; Obretenov, Willi; Petrov, Konstantin

2018-03-01

Different electrocatalysts were tested for oxidation of sulfites to sulfates, namely, manganese thin films deposited on fullerenes and carbon nanotubes. The results presented clearly show that electrodes containing HFs (higher fullerenes), DWCNTs (double-wall carbon nanotubes) and manganese acetate are effective catalysts in S/O2 fuel cells. HFs and DWCNTs have high catalytic activity and can be employed as standalone catalysts. Manganese was deposited on DWCNTs, HFs and fullerenes C60/C70 by a thermal process. The electrocatalysts were characterized by scanning electron microscopy (SEM) and X-ray diffraction (XRD). The electrochemical testing was carried out by plotting the E/V polarization curve. The polarization curves of the electrodes composed of pristine DWCNTs showed the lowest overpotentials.

Chronic organic manganese administration in the rat does not damage dopaminergic nigrostriatal neurons.

Science.gov (United States)

Yong, V W; Perry, T L; Godolphin, W J; Jones, K A; Clavier, R M; Ito, M; Foulks, J G

1986-01-01

In an attempt to produce an animal model of Parkinson's disease, we injected rats repeatedly with high doses of methylcyclopentadienyl manganese tricarbonyl (MMT), a compound which has been reported to lower striatal dopamine content in mice. Chronic MMT administration for up to 5 months, even though it produced a substantial elevation in brain manganese content during the period of exposure, did not destroy dopaminergic nigrostriatal neurons. This was assessed by measurements of tyrosine hydroxylase activity and contents of dopamine and its metabolites in the striatum, and by histological examination of the substantia nigra. Our results differ from those of others who administered manganese chloride in drinking water to rats. This discrepancy is unlikely to be a consequence of differences in duration of exposure or route of administration. It could be due to our having used an organic rather than an inorganic manganese compound, or to a species difference in vulnerability to organic manganese between rats and mice.

Preparation of the electrochemically formed spinel-lithium manganese oxides

Energy Technology Data Exchange (ETDEWEB)

Katakura, Katsumi; Wada, Kohei; Kajiki, Yoshiyuki; Yamamoto, Akiko [Department of Chemical Engineering, Nara National College of Technology, 22 Yata-cho Yamotokoriyama, Nara 639-1080 (Japan); Ogumi, Zempachi [Graduate School of Engineering, Kyoto University, Nishikyo-ku, Kyoto 615-8510 (Japan)

2009-04-01

Electrochemically formed spinel-lithium manganese oxides were synthesized from manganese hydroxides prepared by a cathodic electrochemical precipitation from various concentrations of manganese nitrate solutions. Two types of manganese hydroxides were formed from diluted and concentrated Mn(NO{sub 3}){sub 2} aqueous solutions. Uniform and equi-sized disk shaped Mn(OH){sub 2} crystals of 0.2-5 {mu}m in diameter were obtained on a Pt substrate after the electrochemical precipitation from lower concentration of ranging from 2 mmol dm{sup -3} to 2 mol dm{sup -3} Mn(NO{sub 3}){sub 2} aq., while the grass blade-like precipitate which is ascribed to manganese hydroxide with 20-80 {mu}m long and 1-5 {mu}m wide were formed from concentrated Mn(NO{sub 3}){sub 2} aq. Both manganese hydroxides gave the electrochemically formed spinel-LiMn{sub 2}O{sub 4} onto a Pt sheet, which is ready for electrochemical measurement, after calcination of the Li incorporated precipitate at 750 C without any additives. While the shape and size of the secondary particle frameworks (aggregates) of the electrochemically formed spinel-LiMn{sub 2}O{sub 4} can be controlled by the electrolysis conditions, the nanostructured primary crystals of 200 nm in diameter were obtained in all cases except that the fiber-like nanostructured spinel-LiMn{sub 2}O{sub 4} crystals with 200 nm in diameter were obtained from concentrated Mn(NO{sub 3}){sub 2} aq. Though these two types of electrochemically formed spinel-LiMn{sub 2}O{sub 4} showed well-shaped CVs even in higher scan rates, it would be suitable for high power density battery applications. These behaviors are assumed to be ascribed to the crystal size and shape of the processed spinel-LiMn{sub 2}O{sub 4}. (author)

PIP-II Cryogenic System and the evolution of Superfluid Helium Cryogenic Plant Specifications

Energy Technology Data Exchange (ETDEWEB)

Chakravarty, Anindya [Fermilab; Rane, Tejas [Fermilab; Klebaner, Arkadiy [Fermilab

2017-07-06

The PIP-II cryogenic system consists of a Superfluid Helium Cryogenic Plant (SHCP) and a Cryogenic Distribution System (CDS) connecting the SHCP to the Superconducting (SC) Linac consisting of 25 cryomodules. The dynamic heat load of the SC cavities for continuous wave (CW) as well as pulsed mode of operation has been listed out. The static heat loads of the cavities along with the CDS have also been discussed. Simulation study has been carried out to compute the supercritical helium (SHe) flow requirements for each cryomodule. Comparison between the flow requirements of the cryomodules for the CW and pulsed modes of operation have also been made. From the total computed heat load and pressure drop values in the CDS, the basic specifications for the SHCP, required for cooling the SC Linac, have evolved.

Cryogenic receiver front-end with sharp skirt characteristics

Energy Technology Data Exchange (ETDEWEB)

Narahashi, S [RF Technology Laboratory, Wireless Laboratories, NTT DoCoMo, Inc, Yokosuka, Kanagawa 239-8536 (Japan); Satoh, K [RF Technology Laboratory, Wireless Laboratories, NTT DoCoMo, Inc, Yokosuka, Kanagawa 239-8536 (Japan); Kawai, K [RF Technology Laboratory, Wireless Laboratories, NTT DoCoMo, Inc, Yokosuka, Kanagawa 239-8536 (Japan); Koizumi, D [RF Technology Laboratory, Wireless Laboratories, NTT DoCoMo, Inc, Yokosuka, Kanagawa 239-8536 (Japan); Nojima, T [Graduate School of Information Science and Technology, Hokkaido University, Sapporo, Hokkaido 060-0808 (Japan)

2006-05-15

This paper presents an experimental cryogenic receiver front-end (CRFE) with sharp skirt characteristics for mobile base stations. The CRFE comprises a high-temperature superconducting filter, a cryogenic low-noise amplifier, and a highly reliable cryostat that is very compact. The major characteristics of the proposed CRFE measured at 70 K are a centre frequency of 1.95 GHz, passband width of 20 MHz, sharp selectivity of 20 dB/100 kHz, 1.4 dB ripple, 31.3 dB average passband gain, and average passband equivalent noise temperature of 47.9 K. The CRFE weighs 19 kg and occupies 35 l. Random failure of the cryostat is also evaluated by a continuous operation test using four identical ones simultaneously. The cryostat used in the CRFE has a high reliability level of over five years of continuous maintenance-free operation.

The LHC cryogenic operation for first collisions and physics run

CERN Document Server

Brodzinski, K; Benda, V; Bremer, J; Casas-Cubillos, J; Claudet, S; Delikaris, D; Ferlin, G; Fernandez Penacoba, G; Perin, A; Pirotte, O; Soubiran, M; Tavian, L; van Weelderen, R; Wagner, U

2011-01-01

The Large Hadron Collider (LHC) cryogenic system was progressively and successfully run for the LHC accelerator operation period starting from autumn 2009. The paper recalls the cryogenic system architecture and main operation principles. The system stability during magnets powering and availability periods for high energy beams with first collisions at 3.5 TeV are presented. Treatment of typical problems, weak points of the system and foreseen future consolidations will be discussed.

The Heidelberg CSR: Stored Ion Beams in a Cryogenic Environment

International Nuclear Information System (INIS)

Wolf, A.; Hahn, R. von; Grieser, M.; Orlov, D. A.; Fadil, H.; Welsch, C. P.; Andrianarijaona, V.; Diehl, A.; Schroeter, C. D.; Crespo Lopez-Urrutia, J. R.; Weber, T.; Mallinger, V.; Schwalm, D.; Ullrich, J.; Rappaport, M.; Urbain, X.; Haberstroh, Ch.; Quack, H.; Zajfman, D.

2006-01-01

A cryogenic electrostatic ion storage ring CSR is under development at the Max-Planck Institute for Nuclear Physics in Heidelberg, Germany. Cooling of the ultrahigh vacuum chamber is envisaged to lead to extremely low pressures as demonstrated by cryogenic ion traps. The ring will apply electron cooling with electron beams of a few eV up to 200 eV. Through long storage times of 1000 s as well as through the low wall temperature, internal cooling of infrared-active molecular ions to their rotational ground state will be possible and their collisions with merged collinear beams of electrons and neutral atoms can be detected with high energy resolution. In addition storage of slow highly charged ions is foreseen. Using a fixed in-ring gas target and a reaction microscope, collisions of the stored ions at a speed of the order of the atomic unit can be kinematically reconstructed. The layout and the cryogenic concept are introduced

Cryogenics bringing the temperature down, underground

CERN Multimedia

2005-01-01

The first 600m of the LHC cryogenic distribution line (QRL), which will feed the accelerator's superconducting magnets, has passed initial validating tests of its mechanical design at room and cryogenic temperatures.

High speed TV-towing system for exploration manganese nodules

International Nuclear Information System (INIS)

Hartmann, P.

1977-12-01

For the oceanographic, special for the manganese nodules exploration in the deep sea a high speed-TV-towing system is to design on base of existing TV-towing systems to get better efficiency during the exploration phase. It is planned to increase to towing speed at the time of 2 knots up to 6-8 knots. The essential points of developments in this direction are 1) to decrease the hydrodynamical drag of the long towing cable with fairings. 2) To seperate to towing system into two units the passiv controlled towing cable end point 'SEP' with negativ buoyancy (weight) and the activ controlled TV-fish. With this separation it is possible to tow the TV-fish within a defined accuracy parallel to the sea floor without an influence to the overall system. 3) To adapt the TV- and photo stobe light unit for these towing conditions (high speed). 4) To design the control concept, the operating equipment, the energy and data transmission system, the towed body concept, the hydrodynamical calculation of towing phase and the other towed components. The results of this study is the definition of a two body towing system which is able towed by a research vessel to make continously TV-observation of the sea floor in depth down to 6,000 meters. (orig.) [de

Cryogenics for HL-LHC

Science.gov (United States)

Tavian, L.; Brodzinski, K.; Claudet, S.; Ferlin, G.; Wagner, U.; van Weelderen, R.

The discovery of a Higgs boson at CERN in 2012 is the start of a major program of work to measure this particle's properties with the highest possible precision for testing the validity of the Standard Model and to search for further new physics at the energy frontier. The LHC is in a unique position to pursue this program. Europe's top priority is the exploitation of the full potential of the LHC, including the high-luminosity upgrade of the machine and detectors with an objective to collect ten times more data than in the initial design, by around 2030. To reach this objective, the LHC cryogenic system must be upgraded to withstand higher beam current and higher luminosity at top energy while keeping the same operation availability by improving the collimation system and the protection of electronics sensitive to radiation. This chapter will present the conceptual design of the cryogenic system upgrade with recent updates in performance requirements, the corresponding layout and architecture of the system as well as the main technical challenges which have to be met in the coming years.

Kodak AMSD Cryogenic Test Plans

Science.gov (United States)

Matthews, Gary; Hammon, John; Barrett, David; Russell, Kevin (Technical Monitor)

2002-01-01

NGST will be an IR based optical system that will operate at cryogenic temperatures. As part of the AMSD program, Kodak must demonstrate the ability of our system to perform at these very cold temperatures. Kodak will discuss the test approach that will be used for cryogenic testing at MSFC's XRCF.

[Factors affecting biological removal of iron and manganese in groundwater].

Science.gov (United States)

Xue, Gang; He, Sheng-Bing; Wang, Xin-Ze

2006-01-01

Factors affecting biological process for removing iron and manganese in groundwater were analyzed. When DO and pH in groundwater after aeration were 7.0 - 7.5 mg/L and 6.8 - 7.0 respectively, not only can the activation of Mn2+ oxidizing bacteria be maintained, but also the demand of iron and manganese removal can be satisfied. A novel inoculating approach of grafting mature filter material into filter bed, which is easier to handle than selective culture media, was employed in this research. However, this approach was only suitable to the filter material of high-quality manganese sand with strong Mn2+ adsorption capacity. For the filter material of quartz sand with weak adsorption capacity, only culturing and domesticating Mn2+ oxidizing bacteria by selective culture media can be adopted as inoculation in filter bed. The optimal backwashing rate of biological filter bed filled with manganese sand and quartz sand should be kept at a relatively low level of 6 - 9 L/(m2 x s) and 7 -11 L/( m2 x s), respectively. Then the stability of microbial phase in filter bed was not disturbed, and iron and manganese removal efficiency recovered in less than 5h. Moreover, by using filter material with uniform particle size of 1.0 - 1.2 mm in filter bed, the filtration cycle reached as long as 35 - 38h.

The application of cryogenics to high Reynolds number testing in wind tunnels. I - Evolution, theory, and advantages

Science.gov (United States)

Kilgore, R. A.; Dress, D. A.

1984-01-01

During the time which has passed since the construction of the first wind tunnel in 1870, wind tunnels have been developed to a high degree of sophistication. However, their development has consistently failed to keep pace with the demands placed on them. One of the more serious problems to be found with existing transonic wind tunnels is their inability to test subscale aircraft models at Reynolds numbers sufficiently near full-scale values to ensure the validity of using the wind tunnel data to predict flight characteristics. The Reynolds number capability of a wind tunnel may be increased by a number of different approaches. However, the best solution in terms of model, balance, and model support loads, as well as in terms of capital and operating cost appears to be related to the reduction of the temperature of the test gas to cryogenic temperatures. The present paper has the objective to review the evolution of the cryogenic wind tunnel concept and to describe its more important advantages.

Statistical Optimization of Synthesis of Manganese Carbonates Nanoparticles by Precipitation Methods

International Nuclear Information System (INIS)

Javidan, A.; Rahimi-Nasrabadi, M.; Davoudi, A.A.

2011-01-01

In this study, an orthogonal array design (OAD), OA9, was employed as a statistical experimental method for the controllable, simple and fast synthesis of manganese carbonate nanoparticle. Ultrafine manganese carbonate nanoparticles were synthesized by a precipitation method involving the addition of manganese ion solution to the carbonate reagent. The effects of reaction conditions, for example, manganese and carbonate concentrations, flow rate of reagent addition and temperature, on the diameter of the synthesized manganese carbonate nanoparticle were investigated. The effects of these factors on the width of the manganese carbonate nanoparticle were quantitatively evaluated by the analysis of variance (ANOVA). The results showed that manganese carbonate nanoparticle can be synthesized by controlling the manganese concentration, flow rate and temperature. Finally, the optimum conditions for the synthesis of manganese carbonate nanoparticle by this simple and fast method were proposed. The results of ANOVA showed that 0.001 mol/ L manganese ion and carbonate reagents concentrations, 2.5 mL/ min flow rate for the addition of the manganese reagent to the carbonate solution and 0 degree Celsius temperature are the optimum conditions for producing manganese carbonate nanoparticle with 75 ± 25 nm width. (author)

High signal in the adenohypophysis on T1-weighted images presumably due to manganese deposits in patients on long-term parenteral nutrition

International Nuclear Information System (INIS)

Dietemann, J.L.; Diniz, R.L.F.C.; Reis, M. Jr.; Neugroschl, C.; Soehsten, S. von; Reimund, J.M.; Baumann, R.; Warter, J.M.

1998-01-01

Hypermanganesaemia is reported in patients on long-term parenteral nutrition. Deposition of manganese, giving high signal on T1-weighted images, may involve the basal ganglia. MRI in nine patients (mean age 51 years, range 31-75 years) on long-term parenteral nutrition (mean duration 30 months, range 6-126 months), demonstrated high signal in the anterior pituitary gland on T1-weighted sagittal and coronal images. The gland appeared normal on T2-weighted images. Signal intensity in the basal ganglia on T1-weighted images was increased in all patients. Endocrine assessment showed no significant abnormality. Neurological examination showed a mild parkinsonian movement disorder in one patient. Hypermanganaesemia was present in all nine (1.3-2.8 μmol/l, mean 1.87 μmol/l). The high signal in the anterior pituitary gland was probably related to deposition of paramagnetic substances, especially manganese. (orig.)

The cryogenic control system of BEPCⅡ

Institute of Scientific and Technical Information of China (English)

LI Gang; WANG Ke-Xiang; ZHAO Ji-Jiu; YUE Ke-Juan; DAI Ming-Sui; HUANG Yi-Ling; JIANG Bo

2008-01-01

A superconducting cryogenic system has been designed and deployed in the Beijing Electron-Positron Collider Upgrade Project(BEPCⅡ).The system consists of a Siemens PLC(ST-PLC,Programmable Logic Controller)for the compressor control,an Allen Bradley(AB)PLC for the cryogenic equipments,and the Experimental Physics and Industrial Control System(EPICS)that integrates the PLCs.The system fully automates the superconducting cryogenic control with process control,PID(Proportional-Integral-Differential)control loops,real-time data access and data storage,alarm handler and human machine interface.It is capable of automatic recovery as well.This paper describes the BEPCⅡ cryogenic control system,data communication between ST-PLC and EPICS Input/Output Controllers(IOCs),and the integration of the flow control,the low level interlock,the AB-PLC,and EPICS.

Magnesium and manganese content of halophilic bacteria

International Nuclear Information System (INIS)

de Medicis, E.; Paquette, J.; Gauthier, J.J.; Shapcott, D.

1986-01-01

Magnesium and manganese contents were measured by atomic absorption spectrophotometry in bacteria of several halophilic levels, in Vibrio costicola, a moderately halophilic eubacterium growing in 1 M NaCl, Halobacterium volcanii, a halophilic archaebacterium growing in 2.5 NaCl, Halobacterium cutirubrum, an extremely halophilic archaebacterium growing in 4 M NaCl, and Escherichia coli, a nonhalophilic eubacterium growing in 0.17 M NaCl. Magnesium and manganese contents varied with the growth phase, being maximal at the early log phase. Magnesium and manganese molalities in cell water were shown to increase with the halophilic character of the logarithmically growing bacteria, from 30 mmol of Mg per kg of cell water and 0.37 mmol of Mn per kg of cell water for E. coli to 102 mmol of Mg per kg of cell water and 1.6 mmol of Mn per kg of cell water for H cutirubrum. The intracellular concentrations of manganese were determined independently by a radioactive tracer technique in V. costicola and H. volcanii. The values obtained by 54 Mn loading represented about 70% of the values obtained by atomic absorption. The increase of magnesium and manganese contents associated with the halophilic character of the bacteria suggests that manganese and magnesium play a role in haloadaptation

High-resolution recording of particle tracks with in-line holography in a large cryogenic bubble chamber

CERN Document Server

Harigel, G G

2000-01-01

Holography has been used successfully in combination with conventional optics for the first time in a large cryogenic bubble chamber, the 15-Foot Bubble Chamber at the Fermi National Accelerator Laboratory (FNAL), during a physics run in a high-energy neutrino beam. The innovative system combined the reference beam with the object beam, irradiating a conical volume of ~1.5 m/sup 3/. Bubble tracks from neutrino interactions with a width of ~120 mu m have been recorded with good contrast. The ratio of intensities of the object light to the reference light striking the film is called the beam branching ratio (BBR). We obtained in our experiment an exceedingly small minimum-observable ratio of BBR=(0.54/0.21)*10/sup -7/. The technology has the potential for a wide range of applications. This paper describes the various difficulties in achieving the success. It required the development of laser pulse stretching via enhanced closed loop control with slow Q-switching, to overcome excessive heating of the cryogenic l...

The HSOB GAIA: a cryogenic high stability cesic optical bench for missions requiring sub-nanometric optical stability

Science.gov (United States)

Courteau, Pascal; Poupinet, Anne; Kroedel, Mathias; Sarri, Giuseppe

2017-11-01

Global astrometry, very demanding in term of stability, requires extremely stable material for optical bench. CeSiC developed by ECM and Alcatel Alenia Space for mirrors and high stability structures, offers the best compromise in term of structural strength, stability and very high lightweight capability, with characteristics leading to be insensitive to thermo-elastic at cryogenic T°. The HSOB GAIA study realised by Alcatel Alenia Space under ESA contract aimed to design, develop and test a full scale representative High Stability Optical Bench in CeSiC. The bench has been equipped with SAGEIS-CSO laser metrology system MOUSE1, Michelson interferometer composed of integrated optics with a nm resolution. The HSOB bench has been submitted to an homogeneous T° step under vacuum to characterise the homothetic behaviour of its two arms. The quite negligible inter-arms differential measured with a nm range reproducibility, demonstrates that a complete 3D structure in CeSiC has the same CTE homogeneity as characterisation samples, fully in line with the GAIA need (1pm at 120K). This participates to the demonstration that CeSiC properties at cryogenic T° is fully appropriate to the manufacturing of complex highly stable optical structures. This successful study confirms ECM and Alcatel Alenia Space ability to define and manufacture monolithic lightweight highly stable optical structures, based on inner cells triangular design made only possible by the unique CeSiC manufacturing process.

Diffusion abnormalities of the globi pallidi in manganese neurotoxicity

Energy Technology Data Exchange (ETDEWEB)

McKinney, Alexander M.; Filice, Ross W.; Teksam, Mehmet; Casey, Sean; Truwit, Charles; Clark, H. Brent; Woon, Carolyn; Liu, Hai Ying [Department of Radiology, Medical School, Box 292, 420 Delaware Street S.E., 55455, Minneapolis, MN (United States)

2004-04-01

Manganese is an essential trace metal required for normal central nervous system function, which is toxic when in excess amounts in serum. Manganese neurotoxicity has been demonstrated in patients with chronic liver/biliary failure where an inability to excrete manganese via the biliary system causes increased serum levels, and in patients on total parenteral nutrition (TPN), occupational/inhalational exposure, or other source of excess exogenous manganese. Manganese has been well described in the literature to deposit selectively in the globi pallidi and to induce focal neurotoxicity. We present a case of a 53-year-old woman who presented for a brain MR 3 weeks after liver transplant due to progressively decreasing level of consciousness. The patient had severe liver failure by liver function tests and bilirubin levels, and had also been receiving TPN since the transplant. The MR demonstrated symmetric hyperintensity on T1-weighted images in the globi pallidi. Apparent diffusion coefficient (ADC) map indicated restricted diffusion in the globi pallidi bilaterally. The patient eventually succumbed to systemic aspergillosis 3 days after the MR. The serum manganese level was 195 mcg/l (micrograms per liter) on postmortem exam (over 20 times the upper limits of normal). The patient was presumed to have suffered from manganese neurotoxicity since elevated serum manganese levels have been shown in the literature to correlate with hyperintensity on T1-weighted images, neurotoxicity symptoms, and focal concentration of manganese in the globi pallidi. Neuropathologic sectioning of the globi pallidi at autopsy was also consistent with manganese neurotoxicity. (orig.)

The design of models for cryogenic wind tunnels. [mechanical properties and loads

Science.gov (United States)

Gillespie, V. P.

1977-01-01

Factors to be considered in the design and fabrication of models for cryogenic wind tunnels include high model loads imposed by the high operating pressures, the mechanical and thermodynamic properties of materials in low temperature environments, and the combination of aerodynamic loads with the thermal environment. Candidate materials are being investigated to establish criteria for cryogenic wind tunnel models and their installation. Data acquired from these tests will be provided to users of the National Transonic Facility.

High levels of hair manganese in children living in the vicinity of a ferro-manganese alloy production plant.

Science.gov (United States)

Menezes-Filho, José A; Paes, Ciro R; Pontes, Angela M de C; Moreira, Josino C; Sarcinelli, Paula N; Mergler, Donna

2009-11-01

Manganese (Mn) is an essential element, but an effective toxic at high concentrations. While there is an extensive literature on occupational exposure, few studies have examined adults and children living near important sources of airborne Mn. The objective of this study was to analyze hair Mn of children living in the vicinity of a ferro-manganese alloy production plant in the Great Salvador region, State of Bahia, Brazil and examine factors that influence this bioindicator of exposure. We examined 109 children in the age range of 1-10 years, living near the plant. Four separate housing areas were identified a priori on the bases of proximity to the emission sources and downwind location. A non-exposed group (n=43) of similar socio-economic status was also evaluated. Mn hair (MnH) concentration was measured by graphite atomic absorption spectrometry (GFAAS). Possible confounding hematological parameters were also assessed. Mean MnH concentration was 15.20 microg/g (1.10-95.50 microg/g) for the exposed children and 1.37 microg/g (0.39-5.58 microg/g) for the non-exposed. For the former, MnH concentrations were 7.95+/-1.40 microg/g (farthest from the plant), 11.81+/-1.11 microg/g (mid-region), 34.43+/-8.66 microg/g (closest to the plant) and 34.22+/-9.15 microg/g (directly downwind). Multiple regression analysis on log transformed MnH concentrations for the exposed children derived a model that explained 36.8% of the variability. In order of importance, area of children's residence, gender (girls>boys) and time of mother's residence in the area at the birth of the child, were significantly associated with MnH. Post hoc analyses indicated two groupings for exposure areas, with those living closest to and downwind of the plant displaying higher MnH concentrations compared to the others. The contribution of the time the mother lived in the community prior to the child's birth to the children's current MnH suggests that in utero exposure may play a role. A study of

Removal of Iron and Manganese Using Cascade Aerator and Limestone Roughing Filter

Directory of Open Access Journals (Sweden)

Mohd Sanusi Azrin

2016-01-01

Full Text Available Combination between oxidation and filtration can be used for removing iron and manganese from groundwater especially when the concentrations of these metals were high. This study focused on the effectiveness of the cascade aerator and the size of the limestone filter media to remove iron and manganese from groundwater. Water samples used for this study were collected from orphanage home, Rumah Nur Kasih, Taiping. Universiti Sains Malaysia (USM has provided a tube well of 15 m depth and 150 mm diameter for the orphanage home. However, the water cannot be used for domestic consumption due to high amount of iron and manganese at 6.48 and 1.9 mg/L which exceeded the drinking water standard of 0.3 and 0.1 mg/L respectively. Using laboratory physical model, the study has shown that the removals of iron and manganese have reduce the concentration until 0.17 and 0.2 mg/L respectively. Thus, the results from this study which utilize cascade aerator and limestone roughing filter could be implemented on site for the community to use the ground water for domestic purposes.

Hydrothermal manganese oxide deposits from the Izu-Ogasawara (Bonin)-Mariana Arc and adjacent areas

Energy Technology Data Exchange (ETDEWEB)

Usui, A.; Nishimura, A. (Geological Survey of Japan, Tsukuba (Japan))

1992-04-27

Modern and fossil hydrothermal manganese oxide deposits were discovered from a number of locations in the Izu-Ogasawara(Bonin)-Mariana Arc and adjacent areas during the Hakurei-Maru cruises from 1984 to 1989. This paper describes the occurrence and characteristics of these manganese deposits and their geological significance. It was found that the mineralogical and chemical composition and microstructure of the deposits are typically different from manganese nodules and crusts of hydrogenetic or diagenetic origin. Hardpans, veinlets, sheets, and irregular mass of the hydrothermal manganese deposits often cover a large area of sea bed, which suggests possible high-temperature hydrothermal sulfide deposits in their vicinity. On the other hand, the manganese minerals sometimes occur as substrate of younger hydrogenetic crusts and as nucleus of hydrogenetic nodules, which can provide a geological history of low-temperature hydrothermal activity on the past island arcs. 45 refs., 19 figs., 3 tabs.

Manganese oxide nanoparticles, methods and applications

Science.gov (United States)

Abruna, Hector D.; Gao, Jie; Lowe, Michael A.

2017-08-29

Manganese oxide nanoparticles having a chemical composition that includes Mn.sub.3O.sub.4, a sponge like morphology and a particle size from about 65 to about 95 nanometers may be formed by calcining a manganese hydroxide material at a temperature from about 200 to about 400 degrees centigrade for a time period from about 1 to about 20 hours in an oxygen containing environment. The particular manganese oxide nanoparticles with the foregoing physical features may be used within a battery component, and in particular an anode within a lithium battery to provide enhanced performance.

Efficacies of manganese chloride and Ca-DTPA for the elimination of incorporated manganese-54 in mice

International Nuclear Information System (INIS)

Sato, Itaru; Matsusaka, Naonori; Shinagawa, Kunihiro; Kobayashi, Haruo; Nishimura, Yoshikazu.

1993-01-01

Efficacies of manganese chloride and Ca-DTPA (calcium diethylenetriaminepentaacetic acid) for the elimination of incorporated 54 Mn were investigated in mice. Each mouse was given an intraperitoneal injection of 54 Mn and initial whole-body radioactivity was measured immediately. Manganese chloride (10 mg-Mn/kg) or Ca-DTPA (10 or 100 mg/kg) was injected intraperitoneally once or repeatedly at various times after 54 Mn injection. Efficacies for elimination were estimated by measuring the whole body retention of 54 Mn for 14 or 21 days. A single injection of manganese chloride eliminated more than 80% of the incorporated 54 Mn when it was injected within 24 h after the injection of 54 Mn. Although the efficacy was decreased with the passage of time after the injection of 54 Mn, about 50% was still eliminated after 14 days. Repeated injection of this agent raised the efficacy, but the second or later injection was less effective than the first injection. Ca-DTPA eliminated the incorporated 54 Mn by 57% for 100 mg/kg and by 19% for 10 mg/kg when it was injected after 3 h. But after 6 h or later, Ca-DTPA had little efficacy. These results indicate that manganese chloride is very effective to eliminate the 54 Mn from accidentally contaminated persons and the efficacy of Ca-DTPA is less than that of manganese chloride. (author)

Ricor's anniversary of 50 innovative years in cryogenic technology

Science.gov (United States)

Filis, Avishai; Segal, Victor; Pundak, Nachman; Bar Haim, Zvi; Danziger, Menachem

2017-05-01

Ricor cryogenics was founded in 1967 and since then it has focused on innovative technologies in the cryogenic field. The paper reviews the initial research and development efforts invested in various technologies that have yielded products such as Cryostats for Mossbauer Effect measurement, Liquid gas Dewar containers, Liquid helium vacuum transfer tubes, Cryosurgery and other innovative products. The major registered patents that matured to products such as a magnetic vacuum valve operator, pumped out safety valve and other innovations are reviewed here. As a result of continuous R and D investment, over the years a new generation of innovative Stirling cryogenic products has developed. This development began with massive split slip-on coolers and has progressed as far as miniature IDDCA coolers mainly for IR applications. The accumulated experience in Stirling technology is used also as a platform for developing self-contained water vapor pumps known as MicroStar and NanoStar. These products are also used in collaboration with a research institute in the field of High Temperature Superconductors. The continuous growth in the cryogenic products range and the need to meet market demands have motivated the expansion, of Ricor's manufacturing facility enabling it to become a world leader in the cryocooler field. To date Ricor has manufactured more than 120,000 cryocoolers. The actual cryogenic development efforts and challenges are also reviewed, mainly in the field of long life cryocoolers, ruggedized products, miniaturization and products for space applications.

A breath of fresh air for cryogenics training

CERN Multimedia

HSE Unit

2014-01-01

Whether you work full-time in a cryogenic installation or are required to handle cryogenic substances temporarily, you need to have followed the appropriate safety training.   Photo: Christoph Balle. Two new training courses are now available in English and French at CERN: “Cryogenic Safety – Fundamentals” (at the Prévessin Training Centre) and “Cryogenic Safety – Helium Transfer” (at the Cryolab). The first covers the content of levels 1 and 2 of the old “Cryogenic Safety” course. The second is a completely new course for CERN: it covers specific aspects of the transfer of liquid helium, such as the evaporation process of helium and the associated risks to human health (asphyxia due to displacement of oxygen), the colour code for gas bottles, etc. These training modules have been rewritten in response to the increase in the number of projects involving cryogenics and following various related incident...

Influence of high doses of manganese, copper, zinc and boron on some legumes

Energy Technology Data Exchange (ETDEWEB)

Vogel, G

1973-01-01

Macroscopic and microscopic examinations showed the following symptoms of an excess in trace elements: (1) High doses of manganese (50-150 ppm) cause dark patches (chloroplast accumulation) in young leaves, and necrosis of the leaf margin (MnO/sub 2/ accumulation) in older leaves. The roots become brown and die off. Roots newly formed in compensation are strikingly light-colored. (2) High doses of copper (5-40 ppm) cause iron deficiency chlorosis. A large number of side roots develop in quick succession as a result of damage to the root apex, so that a thick tangle of roots is formed. (3) High doses of zinc (50-150 ppm) bring about dark green, very brittle young leaves with very high ZnO content. The older leaves become red and then yellow. The roots remain stunted because of inhibited growth in length. (4) High doses of boron (30-90 ppm) cause a leaf necrosis which proceeds in the sequence tip, margin, lamina. The roots are not affected in any characteristic way. They become brown and die off.

Interferometric study on the mass transfer in cryogenic distillation under magnetic field

Science.gov (United States)

Bao, S. R.; Zhang, R. P.; Y Rong, Y.; Zhi, X. Q.; Qiu, L. M.

2017-12-01

Cryogenic distillation has long been used for the mass production of industrial gases because of its features of high efficiency, high purity, and capability to produce noble gases. It is of great theoretical and practical significance to explore methods to improve the mass transfer efficiency in cryogenic distillation. The negative correlation between the susceptibility of paramagnetic oxygen and temperature provides a new possibility of comprehensive utilization of boiling point and susceptibility differences in cryogenic distillation. Starting from this concept, we proposed a novel distillation intensifying method by using gradient magnetic field, in which the magnetic forces enhance the transport of the oxygen molecules to the liquid phase in the distillation. In this study, a cryogenic testbed was designed and fabricated to study the diffusion between oxygen and nitrogen under magnetic field. A Mach-Zehnder interferometer was used to visualize the concentration distribution during the diffusion process. The mass transfer characteristics with and without magnetic field, in the chamber filled with the magnetized medium, were systematically studied. The concentration redistribution of oxygen was observed, and the stable stratified diffusion between liquid oxygen and nitrogen was prolonged by the non-uniform magnetic field. The experimental results show that the magnetic field can efficiently influence the mass transfer in cryogenic distillation, which can provide a new mechanism for the optimization of air separation process.

Determination of manganese content in aqueous solutions

International Nuclear Information System (INIS)

Reeder, S.D.; Smith, J.R.

1977-01-01

The three analytical methods used in the hydrogen-to-manganese cross-section ratio measurement were: volumetric determination of manganese, gravimetric analysis of manganous sulfate; and densimetric determination of manganous sulfate

Irradiation effect of the insulating materials for fusion superconducting magnets at cryogenic temperature

Science.gov (United States)

Kobayashi, Koji; Akiyama, Yoko; Nishijima, Shigehiro

2017-09-01

In ITER, superconducting magnets should be used in such severe environment as high fluence of fast neutron, cryogenic temperature and large electromagnetic forces. Insulating material is one of the most sensitive component to radiation. So radiation resistance on mechanical properties at cryogenic temperature are required for insulating material. The purpose of this study is to evaluate irradiation effect of insulating material at cryogenic temperature by gamma-ray irradiation. Firstly, glass fiber reinforced plastic (GFRP) and hybrid composite were prepared. After irradiation at room temperature (RT) or liquid nitrogen temperature (LNT, 77 K), interlaminar shear strength (ILSS) and glass-transition temperature (Tg) measurement were conducted. It was shown that insulating materials irradiated at room temperature were much degraded than those at cryogenic temperature.

Infrared detectors and test technology of cryogenic camera

Science.gov (United States)

Yang, Xiaole; Liu, Xingxin; Xing, Mailing; Ling, Long

2016-10-01

Cryogenic camera which is widely used in deep space detection cools down optical system and support structure by cryogenic refrigeration technology, thereby improving the sensitivity. Discussing the characteristics and design points of infrared detector combined with camera's characteristics. At the same time, cryogenic background test systems of chip and detector assembly are established. Chip test system is based on variable cryogenic and multilayer Dewar, and assembly test system is based on target and background simulator in the thermal vacuum environment. The core of test is to establish cryogenic background. Non-uniformity, ratio of dead pixels and noise of test result are given finally. The establishment of test system supports for the design and calculation of infrared systems.

Manganese Research Health Project (MHRP)

Science.gov (United States)

2009-02-01

green nucleic acid staining further confirmed the neurotoxic effect of cadmium in this cell model (Fig 10C). Next, we examined the enzymatic activity...Quantification of Nissl bodies revealed a widespread reduction in SNpc cell numbers. Other areas of the basal ganglia were also altered by manganese as...the substantia nigra pars compacta (SNpc) following manganese treatment. Quantification of Nissl bodies revealed a widespread reduction in SNpc

A comparison of the iraddiated tensile properties of a high-manganese austenitic steel and type 316 stainless steel

International Nuclear Information System (INIS)

Klueh, R.L.; Grossbeck, M.L.

1984-01-01

The USSR steel EP-838 is a high-manganese, low-nickel steel that also has lower chromium and molybdenum than type 316 stainless steel. Tensile specimens of 20%-cold-worked EP-838 and type 316 stainless steel were irradiated in the High Flux Isotope Reactor (HFIR) at the coolant temperature (approx.=50 0 C). A displacement damage level of 5.2 dpa was reached for the EP-838 and up to 9.5 dpa for the type 316 stainless steel. Tensile tests at room temperature and 300 0 C on the two steels indicated that the irradiation led to increased strength and decreased ductility compared to the unirradiated steels. Although the 0.2% yield stress of the type 316 stainless steel in the unirradiated condition was greater than that for the EP-838, after irradiation there was essentially no difference between the strength or ductility of the two steels. The results indicate that the replacement of the majority of the nickel by manganese and a reduction of chromium and molybdenum in an austenitic stainless steel of composition near that for type 316 stainless steel has little effect on the irradiated and unirradiated tensile properties at low temperatures. (orig.)

Thermodynamic Properties of Manganese and Molybdenum

International Nuclear Information System (INIS)

Desai, P.D.

1987-01-01

This work reviews and discusses the data on the various thermodynamic properties of manganese and molybdenum available through March 1985. These include heat capacity, enthalpy, enthalpy of transitions and melting, vapor pressure, and enthalpy of vaporization. The existing data have been critically evaluated and analyzed. The recommended values for the heat capacity, enthalpy, entropy, and Gibbs energy function from 0.5 to 2400 K for manganese and from 0.4 to 5000 K for molybdenum have been generated, as have heat capacity values for supercooled β-Mn and for γ-Mn below 298.15 K. The recommended values for vapor pressure cover the temperature range from 298.15 to 2400 K for manganese and from 298.15 to 5000 K for molybdenum. These values are referred to temperatures based on IPTS-1968. The uncertainties in the recommended values of the heat capacity range from +-3% to +-5% for manganese and from +-1.5% to +-3% for molybdenum

SURFACE ROUGHNESS AND CUTTING FORCES IN CRYOGENIC TURNING OF CARBON STEEL

Directory of Open Access Journals (Sweden)

T. C. YAP

2015-07-01

Full Text Available The effect of cryogenic liquid nitrogen on surface roughness, cutting forces, and friction coefficient of the machined surface when machining of carbon steel S45C in wet, dry and cryogenic condition was studied through experiments. The experimental results show that machining with liquid nitrogen increases the cutting forces, reduces the friction coefficient, and improves the chips produced. Beside this, conventional machining with cutting fluid is still the most suitable method to produce good surface in high speed machining of carbon steel S45C whereas dry machining produced best surface roughness in low speed machining. Cryogenic machining is not able to replace conventional cutting fluid in turning carbon steel.

Cyclic deformation and fatigue behaviors of Hadfield manganese steel

Energy Technology Data Exchange (ETDEWEB)

Kang, J. [State Key Laboratory of Metastable Materials Science and Technology, Yanshan University, Qinhuangdao 066004 (China); Zhang, F.C., E-mail: zfc@ysu.edu.cn [State Key Laboratory of Metastable Materials Science and Technology, Yanshan University, Qinhuangdao 066004 (China); Long, X.Y. [State Key Laboratory of Metastable Materials Science and Technology, Yanshan University, Qinhuangdao 066004 (China); Lv, B. [School of Environmental and Chemical Engineering, Yanshan University, Qinhuangdao 066004 (China)

2014-01-03

The cyclic deformation characteristics and fatigue behaviors of Hadfield manganese steel have been investigated by means of its ability to memorize strain and stress history. Detailed studies were performed on the strain-controlled low cycle fatigue (LCF) and stress-controlled high cycle fatigue (HCF). Initial cyclic hardening to saturation or peak stress followed by softening to fracture occurred in LCF. Internal stress made the dominant contribution to the fatigue crack propagation until failure. Effective stress evolution revealed the existence of C–Mn clusters with short-range ordering in Hadfield manganese steel and demonstrated that the interaction between C atoms in the C–Mn cluster and dislocation was essential for its cyclic hardening. The developing/developed dislocation cells and stacking faults were the main cyclic deformation microstructures on the fractured sample surface in LCF and HCF, which manifested that fatigue failure behavior of Hadfield manganese steel was induced by plastic deformation during strain-controlled or stress-controlled testing.

Cryogenic Hazard at ESS – strategy, safety studies and lessons learned

CERN Multimedia

CERN. Geneva

2016-01-01

The European Spallation Source (ESS) is building a linear accelerator (linac) aiming at delivering a 2 GeV proton beam on a tungsten target wheel at 5 MW nominal power. The entire accelerator will be housed in an underground tunnel and will be fully operational by 2023. The superconducting section of the linac is composed of 21 High Beta cryomodules, 9 Medium Beta cryomodules and 13 Spoke cryomodules, as well as a Cryogenic Distribution System (CDS) that will be provided with liquid helium. A total of 146 superconducting radio frequency (SRF) cavities operating at 2 K will be housed in those cryomodules. Additionally, cryogenic fluids will also be used for the cold hydrogen moderator surrounding the target as well as for several neutron instruments. In order to achieve a proper cooling, different facilities are being built to house the future cryogenic installation and therefore will be subject to Oxygen Deficiency Hazard (ODH). In order to address cryogenic safety issues ESS wide, a long-term strategy has ...

JACoW Online analysis for anticipated failure diagnostics of the CERN cryogenic systems

CERN Document Server

Gayet, Philippe; Bradu, Benjamin; Cirillo, Roberta

2018-01-01

The cryogenic system is one of the most critical component of the CERN Large Hadron Collider (LHC) and its associated experiments ATLAS and CMS. In the past years, the cryogenic team has improved the maintenance plan and the operation procedures and achieved a very high reliability. However, as the recovery time after failure remains the major issue for the cryogenic availability new developments must take place. A new online diagnostic tool is developed to identify and anticipate failures of cryogenics field equipment, based on the acquired knowledge on dynamic simulation for the cryogenic equipment and on previous data analytic studies. After having identified the most critical components, we will develop their associated models together with the signature of their failure modes. The proposed tools will detect deviation between the actual systems and their model or identify preliminary failure signatures. This information will allow the operation team to take early mitigating actions before the failure occu...

Room temperature cryogenic test interface

International Nuclear Information System (INIS)

Faris, S. M.; Davidson, A.; Moskowitz, P. A.; Sai-Halasz, G. A.

1985-01-01

This interface permits the testing of high speed semiconductor devices (room-temperature chips) by a Josephson junction sampling device (cryogenic chip) without intolerable loss of resolution. The interface comprises a quartz pass-through plug which includes a planar transmission line interconnecting a first chip station, where the cryogenic chip is mounted, and a second chip station, where the semiconductor chip to be tested is temporarily mounted. The pass-through plug has a cemented long half-cylindrical portion and short half-cylindrical portion. The long portion carries the planar transmission line, the ends of which form the first and second chip mounting stations. The short portion completes the cylinder with the long portion for part of its length, where a seal can be achieved, but does not extend over the chip mounting stations. Sealing is by epoxy cement. The pass-through plug is sealed in place in a flange mounted to the chamber wall. The first chip station, with the cryogenic chip attached, extends into the liquid helium reservoir. The second chip station is in the room temperature environment required for semiconductor operation. Proper semiconductor operating temperature is achieved by a heater wire and control thermocouple in the vicinity of each other and the second chip mounting station. Thermal isolation is maintained by vacuum and seals. Connections for power and control, for test result signals, for temperature control and heating, and for vacuum complete the test apparatus

A Reference Guide for Cryogenic Properties of Materials

Energy Technology Data Exchange (ETDEWEB)

Weisend, John G

2003-09-16

A thorough knowledge of the behavior of materials at cryogenic temperatures is critical for the design of successful cryogenic systems. Over the past 50 years, a tremendous amount of material properties at cryogenic temperatures have been measured and published. This guide lists resources for finding these properties. It covers online databases, computer codes, conference proceedings, journals, handbooks, overviews and monographs. It includes references for finding reports issued by government laboratories and agencies. Most common solids and fluids used in cryogenics are covered.

THE STATE OF MANGANESE IN THE PHOTOSYNTHETIC APPARATUS. I. EXAFS STUDIES ON CHLOROPLASTS AND di-u-oxo BRIDGED di-MANGANESE MODEL COMPOUNDS

Energy Technology Data Exchange (ETDEWEB)

Kirby, J. A.; Robertson, A. S.; Smith, J. P.; Thompson, A. C.; Thompson, A. C.; Klein, M. P.

1980-11-01

Extended X-ray Absorption Fine Structure (EXAFS) studies on the manganese contained in spinach chloroplasts and on certain di-u-oxo bridged manganese dimers of the form (X{sub 2}Mn)O{sub 2}(MnX{sub 2} (X=2,2'-bypyridine and 1,10-phenanthroline) are reported. From these studies, the manganese associated with photosynthetic oxygen evolution is suggested to occur as a bridged transition metal dimer with most likely another manganese. Extensive details on the analysis are included.

Cryogenic system options for a superconducting aircraft propulsion system

International Nuclear Information System (INIS)

Berg, F; Dodds, Graham; Palmer, J; Bertola, L; Miller, Paul

2015-01-01

There is a perceived need in the future for a move away from traditional aircraft designs in order to meet ambitious emissions and fuel burn targets. High temperature superconducting distributed propulsion may be an enabler for aircraft designs that have better propulsive efficiency and lower drag. There has been significant work considering the electrical systems required, but less on the cryogenics to enable it. This paper discusses some of the major choices to be faced in cryocooling for aircraft. The likely need for a disposable cryogen to reduce power demand is explained. A set of cryocooling methods are considered in a sensitivity study, which shows that the feasibility of the cryogenic system will depend strongly on the superconducting technology and the aircraft platform. It is argued that all three aspects must be researched and designed in close collaboration to reach a viable solution. (paper)

Hybrid ternary rice paper-manganese oxide-carbon nanotube nanocomposites for flexible supercapacitors

Science.gov (United States)

Jiang, Wenchao; Zhang, Kaixi; Wei, Li; Yu, Dingshan; Wei, Jun; Chen, Yuan

2013-10-01

Modern portable electronic devices create a strong demand for flexible energy storage devices. Paper based nanocomposites are attractive as sustainable materials for such applications. Here, we directly explored the hydroxyl chemistry of cellulose fibers to synthesize hybrid ternary nanocomposites, comprised of rice paper, single-walled carbon nanotubes (SWCNTs) and manganese oxide nanoparticles. The functional groups on cellulose fibers can react with adsorbed permanganate ions, resulting in uniform deposition of manganese oxide nanoparticles. SWCNTs coated on top of manganese oxide nanoparticles form a highly conductive network connecting individual manganese oxide particles. By using the hybrid ternary composites as electrodes, the assembled two-electrode supercapacitors demonstrated high capacitance (260.2 F g-1), energy (9.0 W h kg-1), power (59.7 kW kg-1), and cycle stability (12% drop after 3000 cycles). In addition, the nanocomposites show good strength and excellent mechanical flexibility, and their capacitance shows negligible changes after bending more than 100 times. These findings suggest that opportunities exist to further explore the rich chemistry of cellulose fibers for innovative energy applications.Modern portable electronic devices create a strong demand for flexible energy storage devices. Paper based nanocomposites are attractive as sustainable materials for such applications. Here, we directly explored the hydroxyl chemistry of cellulose fibers to synthesize hybrid ternary nanocomposites, comprised of rice paper, single-walled carbon nanotubes (SWCNTs) and manganese oxide nanoparticles. The functional groups on cellulose fibers can react with adsorbed permanganate ions, resulting in uniform deposition of manganese oxide nanoparticles. SWCNTs coated on top of manganese oxide nanoparticles form a highly conductive network connecting individual manganese oxide particles. By using the hybrid ternary composites as electrodes, the assembled two

A High-Pressure Study of Manganese Metal and its Reactions with CO2 at 6, 23, and 44 GPa

Science.gov (United States)

Sawchuk, K. L. S.; McGuire, C. P.; Greenburg, A.; Makhluf, A.; Kavner, A.

2017-12-01

The free energies of formation of oxides and carbonates at the extreme pressures and temperatures of Earth's interior provides some of the thermodynamic constrains for models of mantle/core formation and subsequent chemical evolution. The broad goal of our research program is to measure the pressure- and temperature-dependence of free energies of formation of transition metal oxides and carbonates. This requires measurements of the phase stability, density, and thermoelastic properties of metals, oxides, and carbonates at deep-Earth and planetary conditions. Manganese is of interest because it is one of the most abundant transition metal geochemical tracers, it readily forms a carbonate at ambient pressure, and its high-pressure carbonate and oxide densities and equation of state parameters are relatively unknown. Here we report new data on the pressure/volume equation of state and structure of manganese metal as well as its reactions with CO2. These measurements were made using a laser heated diamond anvil cell in conjunction with synchrotron-based X-ray diffraction at beamline 12.2.2 at the Advanced Light Source. Three samples of manganese metal were gas-loaded in a CO2 pressure medium and pressurized to 6, 23, and 44 GPa. Upon laser heating, the CO2 reacted with the Mn metal generating new phases. To analyze the diffraction patterns, we we use a python-based program developed in-house for extracting high resolution 2-dimensional diffraction peak position and intensity information from two-dimensional X-ray diffraction patterns. At each pressure step, the structure and density of the quenched Mn metal phase was determined. At 6 GPa, Mn metal adopts a BCC structure, and at 23 GPa a tetragonal distortion is observed in the lattice. The measured equation of state is in good agreement with an existing meaurement by Fujihisa and Takemura (1995). MnCO3 rhodochrosite is observed in the sample quenched after heating at 6 GPa. Additional high pressure phases are evident

Large Cryogenic Infrastructure for LHC Superconducting Magnet and Cryogenic Component Tests: Layout, Commissioning and Operational Experience

International Nuclear Information System (INIS)

Calzas, C.; Chanat, D.; Knoops, S.; Sanmarti, M.; Serio, L.

2004-01-01

The largest cryogenic test facility at CERN, located at Zone 18, is used to validate and to test all main components working at cryogenic temperature in the LHC (Large Hadron Collider) before final installation in the machine tunnel. In total about 1300 main dipoles, 400 main quadrupoles, 5 RF-modules, eight 1.8 K refrigeration units will be tested in the coming years.The test facility has been improved and upgraded over the last few years and the first 18 kW refrigerator for the LHC machine has been added to boost the cryogenic capacity for the area via a 25,000 liter liquid helium dewar. The existing 6 kW refrigerator, used for the LHC Test String experiments, will also be employed to commission LHC cryogenic components.We report on the design and layout of the test facility as well as the commissioning and the first 10,000 hours operational experience of the test facility and the 18 kW LHC refrigerator

A Serializer ASIC for High Speed Data Transmission in Cryogenic and HiRel Environment

CERN Document Server

Liu, T; The ATLAS collaboration

2010-01-01

A high speed 16:1 serializer ASIC has been developed using a commercial 0.25 μm silicon-on-sapphire CMOS technology. At room temperature the ASIC operates from 4.0 to 5.7 Gbps with power consumption of 463 mW. The total jitter is 62 ps at the bit error rate of 10-12 at 5 Gbps. A 200-MeV proton beam test indicates that the ASIC is suitable for high energy physics applications. A liquid nitrogen temperature test indicates that the ASIC may be used at cryogenic temperature applications. The reliability of the serializer at liquid nitrogen temperature is to be studied. A 6-lane serializer array with 10 Gbps/lane with redundancy capability is under development.

High signal in the adenohypophysis on T1-weighted images presumably due to manganese deposits in patients on long-term parenteral nutrition

Energy Technology Data Exchange (ETDEWEB)

Dietemann, J.L.; Diniz, R.L.F.C.; Reis, M. Jr.; Neugroschl, C.; Soehsten, S. von [Department of Radiology 2, University Hospital of Strasbourg (France); Reimund, J.M.; Baumann, R. [Department of Hepatogastroenterology, University Hospital of Strasbourg (France); Warter, J.M. [Department of Neurology, University Hospital of Strasbourg (France)

1998-12-01

Hypermanganesaemia is reported in patients on long-term parenteral nutrition. Deposition of manganese, giving high signal on T1-weighted images, may involve the basal ganglia. MRI in nine patients (mean age 51 years, range 31-75 years) on long-term parenteral nutrition (mean duration 30 months, range 6-126 months), demonstrated high signal in the anterior pituitary gland on T1-weighted sagittal and coronal images. The gland appeared normal on T2-weighted images. Signal intensity in the basal ganglia on T1-weighted images was increased in all patients. Endocrine assessment showed no significant abnormality. Neurological examination showed a mild parkinsonian movement disorder in one patient. Hypermanganaesemia was present in all nine (1.3-2.8 {mu}mol/l, mean 1.87 {mu}mol/l). The high signal in the anterior pituitary gland was probably related to deposition of paramagnetic substances, especially manganese. (orig.) With 2 figs., 1 tab., 17 refs.

Kinetics of manganese in MAG/MIG welding with a 18/8/6 wire

International Nuclear Information System (INIS)

Tusek, J.

2001-01-01

The paper deals with a study of MAG/MIG welding of low-alloy ferritic steel and high-alloy austenitic steel with a 18/8/6 wire. Manganese burn-off from the wire in welding a single-V butt weld was studied. It was found that manganese burns off in the arc during melting of a droplet at the wire end, and from the weld pool during weld formation. The range of manganese burn-of-depends mainly on the type of shielding gas used and the arc length,i. e., from the arc voltage. The manganese burn-off increases with an increase of the content of active gases, i.e., CO 2 and O 2 in the neutral gas i. e., argon. It also increases with an increase in arc voltage. The longer the welding arc, the longer exposition of the filler materials to the welding arc and the wider the penetration, Which allows manganese vapours to evaporate from the weld pool. The most important finding is that manganese burn-off from the 18/8/6 wire during welding of austenitic stainless steel with low-alloy ferritic steel is considerably strong, i.e., from 20% to 30%; nevertheless the wire concerned is perfectly suitable for welding of different types of steel. (Author) 23 refs

Hybrid Electrostatic/Flextensional Mirror for Lightweight, Large-Aperture, and Cryogenic Space Telescopes

Science.gov (United States)

Patrick, Brian; Moore, James; Hackenberger, Wesley; Jiang, Xiaoning

2013-01-01

A lightweight, cryogenically capable, scalable, deformable mirror has been developed for space telescopes. This innovation makes use of polymer-based membrane mirror technology to enable large-aperture mirrors that can be easily launched and deployed. The key component of this innovation is a lightweight, large-stroke, cryogenic actuator array that combines the high degree of mirror figure control needed with a large actuator influence function. The latter aspect of the innovation allows membrane mirror figure correction with a relatively low actuator density, preserving the lightweight attributes of the system. The principal components of this technology are lightweight, low-profile, high-stroke, cryogenic-capable piezoelectric actuators based on PMN-PT (piezoelectric lead magnesium niobate-lead titanate) single-crystal configured in a flextensional actuator format; high-quality, low-thermal-expansion polymer membrane mirror materials developed by NeXolve; and electrostatic coupling between the membrane mirror and the piezoelectric actuator assembly to minimize problems such as actuator print-through.

Cryogenic support member

International Nuclear Information System (INIS)

Niemann, R.C.; Gonczy, J.D.; Nicol, T.H.

1987-01-01

A cryogenic support member is described for restraining a cryogenic system comprising; a rod having a depression at a first end. The rod is made of non-metallic material. The non-metallic material has an effectively low thermal conductivity; a metallic plug; and a metallic sleeve. The plug and the sleeve are shrink-fitted to the depression in the rod and assembled thereto such that the plug is disposed inside the depression of the rod. The sleeve is disposed over the depression in the rod and the rod is clamped therebetween. The shrink-fit clamping the rod is generated between the metallic plug and the metallic sleeve

Hydrogen isotope separation by cryogenic distillation method

International Nuclear Information System (INIS)

Hayakawa, Nobuo; Mitsui, Jin

1987-01-01

Hydrogen isotope separation in fusion fuel cycle and tritium recovery from heavy water reactor are very important, and therefore the early establishment of these separation techniques are desired. The cryogenic distillation method in particular is promising for the separation of hydrogen isotope and the recovery of high concentrated tritium. The studies of hydrogen isotope separation by cryogenic distillation method have been carried out by using the experimental apparatus made for the first time in Japan. The separation of three components (H 2 -HD-D 2 ) under total reflux conditions was got by using the packing tower of 500 mm height. It was confirmed that the Height Equivalent Theoretical Plate (HETP) was 20 - 30 mm for the vapor's line velocity of 20 - 80 mm/s. (author)

Manganese exposure in foundry furnacemen and scrap recycling workers

DEFF Research Database (Denmark)

Lander, F; Kristiansen, J; Lauritsen, Jens

1999-01-01

Cast iron products are alloyed with small quantities of manganese, and foundry furnacemen are potentially exposed to manganese during tapping and handling of smelts. Manganese is a neurotoxic substance that accumulates in the central nervous system, where it may cause a neurological disorder...

Status of the LBNF Cryogenic System

CERN Document Server

Montanari, D; Bremer, J; Delany, M; Diaz, A; Doubnik, R; Haaf, K; Henstchel, S; Norris, B; Voirin, E

2017-01-01

The Sanford Underground Research Facility (SURF) will host the Deep Underground Neutrino Experiment (DUNE), an international multi-kiloton Long-Baseline neutrino experiment that will be installed about a mile underground in Lead, SD. In the current configuration four cryostats will contain a modular detector and a total of 68,400 tons of ultrapure liquid argon, with a level of impurities lower than 100 parts per trillion of oxygen equivalent contamination. The Long-Baseline Neutrino Facility (LBNF) provides the conventional facilities and the cryogenic infrastructure to support DUNE. The system is comprised of three sub-systems: External/Infrastructure, Proximity and Internal cryogenics. An international engineering team will design, manufacture, commission, and qualify the LBNF cryogenic system. This contribution presents the modes of operations, layout and main features of the LBNF cryogenic system. The expected performance, the functional requirements and the status of the design are also highlighted.

Status of the LBNF Cryogenic System

Science.gov (United States)

Montanari, D.; Adamowski, M.; Bremer, J.; Delaney, M.; Diaz, A.; Doubnik, R.; Haaf, K.; Hentschel, S.; Norris, B.; Voirin, E.

2017-12-01

The Sanford Underground Research Facility (SURF) will host the Deep Underground Neutrino Experiment (DUNE), an international multi-kiloton Long-Baseline neutrino experiment that will be installed about a mile underground in Lead, SD. In the current configuration four cryostats will contain a modular detector and a total of 68,400 tons of ultrapure liquid argon, with a level of impurities lower than 100 parts per trillion of oxygen equivalent contamination. The Long-Baseline Neutrino Facility (LBNF) provides the conventional facilities and the cryogenic infrastructure to support DUNE. The system is comprised of three sub-systems: External/Infrastructure, Proximity and Internal cryogenics. An international engineering team will design, manufacture, commission, and qualify the LBNF cryogenic system. This contribution presents the modes of operations, layout and main features of the LBNF cryogenic system. The expected performance, the functional requirements and the status of the design are also highlighted.

49 CFR 173.316 - Cryogenic liquids in cylinders.

Science.gov (United States)

2010-10-01

... filling density for hydrogen, cryogenic liquid is defined as the percent ratio of the weight of lading in... 49 Transportation 2 2010-10-01 2010-10-01 false Cryogenic liquids in cylinders. 173.316 Section... REQUIREMENTS FOR SHIPMENTS AND PACKAGINGS Gases; Preparation and Packaging § 173.316 Cryogenic liquids in...

Analysis of material flow in a utillzation technology of low grade manganese ore and sulphur coal complementary

Science.gov (United States)

Wang, Bo-Zhi; Deng, Biao; Su, Shi-Jun; Ding, Sang-Lan; Sun, Wei-Yi

2018-03-01

Electrolytic manganese is conventionally produced through low-grade manganese ore leaching in SO2, with the combustion of high sulfur coal. Subsequently the coal ash and manganese slag, produced by the combustion of high sulfur coal and preparation of electrolytic manganese, can be used as raw ingredients for the preparation of sulphoaluminate cement. In order to realize the `coal-electricity-sulfur-manganese-building material' system of complementary resource utilization, the conditions of material inflow and outflow in each process were determined using material flow analysis. The material flow models in each unit and process can be obtained by analyzed of material flow for new technology, and the input-output model could be obtained. Through the model, it is possible to obtain the quantity of all the input and output material in the condition of limiting the quantity of a substance. Taking one ton electrolytic manganese as a basis, the quantity of other input material and cements can be determined with the input-output model. The whole system had thusly achieved a cleaner production level. Therefore, the input-output model can be used for guidance in practical production.

A new manganese-based oral contrast agent (CMC-001) for liver MRI. Pharmacological and pharmaceutical aspects

International Nuclear Information System (INIS)

Joergensen, Jan Troest; Rief, Matthias; Wagner, Moritz; Brismar, Torkel B.; Albiin, Nils

2012-01-01

Manganese is one of the most abundant metals on earth and is found as a component of more than 100 different minerals. Besides being an essential trace element in relation to the metabolic processes in the body, manganese is also a paramagnetic metal that possesses similar characteristics to gadolinium with regards to T1-weighted (T1-w) magnetic resonance imaging (MRI). Manganese, in the form of manganese (II) chloride tetrahydrate, is the active substance in a new targeted oral contrast agent, currently known as CMC-001, indicated for hepatobiliary MRI. Under physiological circumstances manganese is poorly absorbed from the intestine after oral intake, but by the use of specific absorption promoters, L-alanine and vitamin D3, it is possible to obtain a sufficiently high concentration in the liver in order to achieve a significant signal enhancing effect. In the liver manganese is exposed to a very high first-pass effect, up to 98 %, which prevents the metal from reaching the systemic circulation, thereby reducing the number of systemic side-effects. Manganese is one of the least toxic trace elements, and due to its favorable safety profile it may be an attractive alternative to gadolinium-based contrast agents for patients undergoing an MRI evaluation for liver metastases in the future. In this review the basic pharmacological and pharmaceutical aspects of this new targeted oral hepatobiliary specific contrast agent will be discussed

Status and Role of Manganese in the Environment

Directory of Open Access Journals (Sweden)

RK Kamble

2014-09-01

Full Text Available Manganese is the second most abundant heavy metal, and in frequency list of elements it occupies 12th place. The Earth’s core contains about 1.5% manganese. According to Indian Standards for Drinking water (IS 10500:2012 manganese concentration in drinking water is 0.1 ppm (acceptable limit and 0.3 ppm as permissible limit. An attempt has been made to record the presence of manganese in different environmental matrices such as air, water, soil, food, its effects on plants, animals including human beings. DOI: http://dx.doi.org/10.3126/ije.v3i3.11081 International Journal of Environment Vol.3(3 2014: 222-234

The Future with Cryogenic Fluid Dynamics

Science.gov (United States)

Scurlock, R. G.

The applications of cryogenic systems have expanded over the past 50 years into many areas of our lives. During this time, the impact of the common features of Cryogenic Fluid Dynamics, CryoFD, on the economic design of these cryogenic systems, has grown out of a long series of experimental studies carried out by teams of postgraduate students at Southampton University.These studies have sought to understand the heat transfer and convective behavior of cryogenic liquids and vapors, but they have only skimmed over the many findings made, on the strong convective motions of fluids at low temperatures. The convection takes place in temperature gradients up to 10,000 K per meter, and density gradients of 1000% per meter and more, with rapid temperature and spatially dependent changes in physical properties like viscosity and surface tension, making software development and empirical correlations almost impossible to achieve. These temperature and density gradients are far larger than those met in other convecting systems at ambient temperatures, and there is little similarity. The paper will discuss the likely impact of CryoFD on future cryogenic systems, and hopefully inspire further research to support and expand the use of existing findings, and to improve the economy of present-day systems even more effectively. Particular examples to be mentioned include the following. Doubling the cooling power of cryo-coolers by a simple use of CryoFD. Reducing the boil-off rate of liquid helium stored at the South Pole, such that liquid helium availability is now all-the-year-round. Helping to develop the 15 kA current leads for the LHC superconducting magnets at CERN, with much reduced refrigeration loads. Improving the heat transfer capability of boiling heat transfer surfaces by 10 to 100 fold. This paper is an edited text of an invited plenary presentation at ICEC25/ICMC2014 by Professor Scurlock on the occasion of his being presented with the ICEC Mendelssohn Award for his

Development and testing of immersed-Bz diodes with cryogenic anodes

International Nuclear Information System (INIS)

Bruner, Nichelle Lee; Cordova, Steve Ray; Oliver, Bryan Velten; Portillo, Salvador; Cooper, Graham; Puetz, Elizabeth A.; Johnston, Mark D.; Hahn, Kelly Denise; McLean, John; Molina, Isidro; Droemer, Darryl W.; Welch, Dale R.; Rovang, Dean Curtis; Van De Valde, David M.; Gregerson, Darryl; Maenchen, John Eric; O'Malley, John

2005-01-01

Sandia National Laboratories is investigating and developing high-dose, high-brightness flash radiographic sources. The immersed-B z diode employs large-bore, high-field solenoid magnets to help guide and confine an intense electron beam from a needle-like cathode 'immersed' in the axial field of the magnet. The electron beam is focused onto a high-atomic-number target/anode to generate an intense source of bremsstrahlung X-rays. Historically, these diodes have been unable to achieve high dose (> 500 rad (at) m) from a small spot (< 3 mm diameter). It is believed that this limitation is due in part to undesirable effects associated with the interaction of the electron beam with plasmas formed at either the anode or the cathode. Previous research concentrated on characterizing the behavior of diodes, which used untreated, room temperature (RT) anodes. Research is now focused on improving the diode performance by modifying the diode behavior by using cryogenic anodes that are coated in-situ with frozen gases. The objective of these cryogenically treated anodes is to control and limit the ion species of the anode plasma formed and hence the species of the counter-streaming ions that can interact with the electron beam. Recent progress in the development, testing and fielding of the cryogenically cooled immersed diodes at Sandia is described.

Composite materials for cryogenic structures

International Nuclear Information System (INIS)

Kasen, M.B.

1978-01-01

The paper is concerned with the composition, mechanical properties and capabilities of various types of composite materials for cryogenic structures. Attention is given to high-pressure plastic laminates, low-pressure plastic laminates, metal-matrix laminates, and aggregates (low-temperature concretes). The ability of these materials to match the strength and modulus of stainless steels suggests that their usage will substantially increase as alloying elements become scarce and more expensive

Manganese and acute paranoid psychosis: a case report

Directory of Open Access Journals (Sweden)

Egger Jos I

2011-04-01

Full Text Available Abstract Introduction Manganese regulates many enzymes and is essential for normal development and body function. Chronic manganese intoxication has an insidious and progressive course and usually starts with complaints of headache, fatigue, sleep disturbances, irritability and emotional instability. Later, several organ systems may be affected and, due to neurotoxicity, an atypical parkinsonian syndrome may emerge. With regard to neuropsychiatry, an array of symptoms may develop up to 30 years after intoxication, of which gait and speech abnormalities, cognitive and motor slowing, mood changes and hallucinations are the most common. Psychotic phenomena are rarely reported. Case presentation We describe the case of a 49-year-old Caucasian man working as a welder who was referred to our facility for evaluation of acute paranoid psychotic behavior. Our patient's medical history made no mention of any somatic complaints or psychiatric symptoms, and he had been involved in a professional career as a metalworker. On magnetic resonance imaging scanning of his brain, a bilateral hyperdensity of the globus pallidus, suggestive for manganese intoxication, was found. His manganese serum level was 52 to 97 nmol/L (range: 7 to 20 nmol/L. A diagnosis of organic psychotic disorder due to manganese overexposure was made. His psychotic symptoms disappeared within two weeks of treatment with low-dose risperidone. At three months later, serum manganese was decreased to slightly elevated levels and the magnetic resonance imaging T1 signal intensity was reduced. No signs of Parkinsonism were found and a definite diagnosis of manganese-induced apathy syndrome was made. Conclusion Although neuropsychiatric and neurological symptoms caused by (chronic manganese exposure have been reported frequently in the past, in the present day the disorder is rarely diagnosed. In this report we stress that manganese intoxication can still occur, in our case in a confined

Thermal stress state of cryogenic HP vessels under freezing and pressurization

International Nuclear Information System (INIS)

Tsybenko, A.S.; Kuranov, B.A.; Chepurnoj, A.D.; Shaposhnikov, V.A.; Krishchuk, N.G.

1986-01-01

A mathematical model is developed for thermomechanical processes in cryogenic HP vessels under freezing either by liquid and (or) gaseous cryogen and under pressurization. Equations of nonlinear nonstationary thermal conductivity and nonisothermal thermoelastoplasticity are used for the case of the theory off low with isotropic hardening. Semiempiricaldependences of nonstationary heat exchange for gaseous medium, experimental curves of cryogenic liquid boiling, mass exchange relationships are allowed for when formulating boundary conditions. The mathematical modelis realized on the basi of the finite element method in the form of highly automated program complex TERSOD (heat resistanceof vessels), oriented for computer of the Unified System. Heat and stress-strained states for three constructions of vessels are thoroughly studied under different conditions of gaseous, liquid and combined freezing with subsequent pressurization

A cryogenic system design for the international thermonuclear experimental reactor (ITER)

International Nuclear Information System (INIS)

Slack, D.S.

1991-01-01

A conceptual design for ITER was completed last year. The author developed a suitable cryogenic system for ITER as part of this conceptual design effort. An overview of the design is reported. Emphasis is on the fact that cryogenics is a mature science, and a system supporting ITER needs can be made from time-proven components without loss of efficiency or reliability. Because of the large size of the ITER cryogenic system, large numbers of compressors and expanders must be used. Very high reliability is assured by arranging these components in parallel banks where servicing of individual components can be done without interruption of operations. This and other ideas based on the author's experience with Mirror Fusion Test Facility (MFTF) operations are described. 5 refs., 3 figs

Evacuation apparatus with cryogenic pump and trap assembly

International Nuclear Information System (INIS)

Mahl, G.

1980-01-01

An evacuation apparatus comprising a vessel defining a vacuum chamber therein, vacuumizing means communicating with an opening to said vacuum chamber for selectively drawing a vacuum therein comprising cryogenic pump means disposed closely adjacent to said opening and defined by substantial cryogenically cooled trap surfaces for freezing-out water vapor from air evacuated from said vacuum chamber, said opening being common to said vacuum chamber and to said cryogenic pump means, valve means for selectively opening or closing the opening to said vacuum chamber and movable from a first position within said cryogenic pump means closing said opening to a second position within said cryogenic pump means directly exposing said vacuum chamber to said cryogenic pump means, through said opening, baffle means disposed closely adjacent to the opening to said vacuum chamber for providing substantial open communication to said vacuum chamber and for substantially preventing ingress of contaminants into said vacuum chamber, said baffle means being positioned to provide an optically dense view of said opening when viewed from a downstream side of said baffle means, and a plurality of longitudinally spaced and cryogenically cooled fins mounted in nested relationship within said baffle means and disposed in out-of-contact relationship therewith, said fins being positioned to provide an optically dense view of the downstream side of said baffle means when viewed from said openings. The cryogenic pump is adapted for use in an evacuation apparatus comprising a housing defining an opening to a vacuum chamber, a plurality of metallic plates defining a first chamber therein communicating with said vacuum chamber through said opening and further defining a second chamber at least partially surrounding said first chamber and adapted to be at least partially filled with a cryogenic liqui.d

Cryogen free low temperature sample environment for neutron scattering experiments

International Nuclear Information System (INIS)

Kirichek, O; Evans, B E; Down, R B E; Bowden, Z A

2009-01-01

Recent increase in liquid helium cost caused by global helium supply problems rose significant concern about affordability of conventional cryogenic equipment. Luckily the progress in cryo-cooler technology offers a new generation of cryogenic systems with significantly reduced consumption and in some cases nearly complete elimination of cryogens. These cryogen-free systems also offer the advantage of operational simplicity and require less space than conventional cryogen-cooled systems. The ISIS facility carries on an internal development program intended to substitute gradually all conventional cryogenic systems with cryogen free systems preferably based on pulse tube refrigerators. A unique feature of this cryo-cooler is the absence of cold moving parts. This considerably reduces vibrations and increases the reliability of the cold head. The program includes few development projects which are aiming to deliver range of cryogen free equipment including top-loading cryostat, superconducting magnets and dilution refrigerators. Here we are going to describe the design of these systems and discuss the results of prototypes testing.

Oxidative Precipitation of Manganese from Acid Mine Drainage by Potassium Permanganate

Directory of Open Access Journals (Sweden)

Regeane M. Freitas

2013-01-01

Full Text Available Although oxidative precipitation by potassium permanganate is a widely recognised process for manganese removal, research dealing with highly contaminated acid mine drainage (AMD has yet to be performed. The present study investigated the efficiency of KMnO4 in removing manganese from AMD effluents. Samples of AMD that originated from inactive uranium mine in Brazil were chemically characterised and treated by KMnO4 at pH 3.0, 5.0, and 7.0. Analyses by Raman spectroscopy and geochemical modelling using PHREEQC code were employed to assess solid phases. Results indicated that the manganese was rapidly oxidised by KMnO4 in a process enhanced at higher pH. The greatest removal, that is, 99%, occurred at pH 7.0, when treated waters presented manganese levels as low as 1.0 mg/L, the limit established by the Brazilian legislation. Birnessite (MnO2, hausmannite (Mn3O4, and manganite (MnOOH were detected by Raman spectroscopy. These phases were consistently identified by the geochemical model, which also predicted phases containing iron, uranium, manganese, and aluminium during the correction of the pH as well as bixbyite (Mn2O3, nsutite (MnO2, pyrolusite (MnO2, and fluorite (CaF2 following the KMnO4 addition.

Cryogenics for LDR

Science.gov (United States)

Kittel, Peter

1988-01-01

Three cryogenic questions of importance to Large Deployable Reflector (LDR) are discussed: the primary cooling requirement, the secondary cooling requirement, and the instrument changeout requirement.

Development of bonding techniques for cryogenic components (2). HIP bonding between Cu Alloys and Ti, cryogenic stainless steels

Energy Technology Data Exchange (ETDEWEB)

Saito, Shigeru; Ouchi, Nobuo [Japan Atomic Energy Research Inst., Tokai, Ibaraki (Japan). Tokai Research Establishment; Fukaya, Kiyoshi [Nihon Advanced Technology Ltd., Tokai, Ibaraki (Japan); Ishiyama, Shintaro [Japan Atomic Energy Research Inst., Oarai, Ibaraki (Japan). Oarai Research Establishment; Tsuchiya, Yoshinori; Nakajima, Hideo [Japan Atomic Energy Research Inst., Naka, Ibaraki (Japan). Naka Fusion Research Establishment

2003-03-01

Several joints between dissimilar materials are required in the superconducting (SC) magnet system of SC linear accelerator or fusion reactor, Pure titanium (Ti) is one of candidate materials for a jacket of SC coil of fusion reactor because Ti is non-magnetic material and has a feature that its thermal expansion is similar to SC material in addition to good corrosion resistance and workability. Also, Ti does not require strict control of environment during reaction heat treatment of SC material. Copper (Cu) or Cu-alloy is used in electrical joints and cryogenic stainless steel (SS) is used in cryogenic pipes. Therefore, it is necessary to develop new bonding techniques for joints between Ti, Cu, and SS because jacket, electrical joint and cryogenic pipe have to be bonded each other to cool SC coils. Japan Atomic Energy Research Institute (JAERI) has started to develop dissimilar material joints bonded by hot isostatic pressing (HIP), which can bring a high strength joint with good tolerance and can applied to a large or complex geometry device. HIP conditions for Cu-Ti, Cu alloy-Ti, Cu alloy-SS were investigated in this study and most stable HIP condition were evaluated by microscopic observation, tensile and bending tests at room temperature. (author)

Cryogenic foam insulation: Abstracted publications

Science.gov (United States)

Williamson, F. R.

1977-01-01

A group of documents were chosen and abstracted which contain information on the properties of foam materials and on the use of foams as thermal insulation at cryogenic temperatures. The properties include thermal properties, mechanical properties, and compatibility properties with oxygen and other cryogenic fluids. Uses of foams include applications as thermal insulation for spacecraft propellant tanks, and for liquefied natural gas storage tanks and pipelines.

High-resolution parallel electron energy-loss spectroscopy of MnL2,3-edges in inorganic manganese compounds

International Nuclear Information System (INIS)

Garvie, L.A.J.; Craven, A.J.

1994-01-01

Parallel electron energy-loss spectroscopy (PEELS) in a scanning transmission electron microscope (STEM) was used to record the Mn L 2,3 -edges from a range of natural and synthetic manganese containing materials, covering valences 0, II, III, IV and VII, with an energy resolution of ca. 0.5 eV. The Mn L 2,3 electron-loss near-edge structure (ELNES) of these edges provided a sensitive fingerprint of its valence. The Mn 2+ L 2,3 -edges show little sensitivity to the local site symmetry of the ligands surrounding the manganese. This is illustrated by comparing the Mn L 2,3 -edges from 4-, 6-and 8-fold coordinated Mn 2+ . In contrast, the Mn L 3 -edges from Mn 3+ and Mn 4+ containing minerals exhibited ELNES that are interpreted in terms of a crystals-field splitting of the 3d electrons, governed by the symmetry of the surrounding ligands. The Mn L 3 -edges for octahedrally coordinated Mn 2+ , Mn 3+ and Mn 4+ showed variations in their ELNES that were sensitive to the crystal-field strength. The crystal-field strength (10Q) was measured from these edges and compared very well with published optically determinted values. The magnitude of 10Dq measured from the Mn L 3 -edges and their O K-edge prepeaks of the manganese oxides were almost identical. This further confirms that the value of 10Dq measured at the Mn L 3 -edge is correct. Selected spectra are compared with theoretical 2p atomic multiplet spectra and the differences and similarities are explained in terms of the covalency and site symmetry of the manganese. The Mn L 3 -edges allow the valence of the manganese to be ascertained, even in multivalent state materials, and can also be used to dtermin 10Dq. (orig.)

Cryogenics Testbed Laboratory Flange Baseline Configuration

Science.gov (United States)

Acuna, Marie Lei Ysabel D.

2013-01-01

As an intern at Kennedy Space Center (KSC), I was involved in research for the Fluids and Propulsion Division of the NASA Engineering (NE) Directorate. I was immersed in the Integrated Ground Operations Demonstration Units (IGODU) project for the majority of my time at KSC, primarily with the Ground Operations Demonstration Unit Liquid Oxygen (GODU L02) branch of IGODU. This project was established to develop advancements in cryogenic systems as a part of KSC's Advanced Exploration Systems (AES) program. The vision of AES is to develop new approaches for human exploration, and operations in and beyond low Earth orbit. Advanced cryogenic systems are crucial to minimize the consumable losses of cryogenic propellants, develop higher performance launch vehicles, and decrease operations cost for future launch programs. During my internship, I conducted a flange torque tracking study that established a baseline configuration for the flanges in the Simulated Propellant Loading System (SPLS) at the KSC Cryogenics Test Laboratory (CTL) - the testing environment for GODU L02.

A zinc-resistant human epithelial cell line is impaired in cadmium and manganese import

International Nuclear Information System (INIS)

Rousselet, Estelle; Richaud, Pierre; Douki, Thierry; Chantegrel, Jocelyne Garcia; Favier, Alain; Bouron, Alexandre; Moulis, Jean-Marc

2008-01-01

A human epithelial cell line (HZR) growing with high zinc concentrations has been analyzed for its ability to sustain high cadmium concentrations. Exposure to up to 200 μM of cadmium acetate for 24 h hardly impacted viability, whereas most of parental HeLa cells were killed by less than 10 μM of cadmium. Upon challenge by 35 fold higher cadmium concentrations than HeLa cells, HZR cells did not display increased DNA damage, increased protein oxidation, or changed intracellular cadmium localization. Rather, the main cause of resistance against cadmium was by avoiding cadmium entry into cells, which differs from that against zinc as the latter accumulates inside cells. The zinc-resistant phenotype of these cells was shown to also impair extracellular manganese uptake. Manganese and cadmium competed for entry into HeLa cells. Probing formerly identified cadmium or manganese transport systems in different animal cells did not evidence any significant change between HeLa and HZR cells. These results reveal zinc adaptation influences manganese and cadmium cellular traffic and they highlight previously unknown connections among homeostasis of divalent metals

Conceptual Design of the Cryogenic System for the High-luminosity Upgrade of the Large Hadron Collider (LHC)

Science.gov (United States)

Brodzinski, K.; Claudet, S.; Ferlin, G.; Tavian, L.; Wagner, U.; Van Weelderen, R.

The discovery of a Higgs boson at CERN in 2012 is the start of a major program of work to measure this particle's properties with the highest possible precision for testing the validity of the Standard Model and to search for further new physics at the energy frontier. The LHC is in a unique position to pursue this program. Europe's top priority is the exploitation of the full potential of the LHC, including the high-luminosity upgrade of the machine and detectors with an objective to collect ten times more data than in the initial design, by around 2030. To reach this objective, the LHC cryogenic system must be upgraded to withstand higher beam current and higher luminosity at top energy while keeping the same operation availability by improving the collimation system and the protection of electronics sensitive to radiation. This paper will present the conceptual design of the cryogenic system upgrade with recent updates in performance requirements, the corresponding layout and architecture of the system as well as the main technical challenges which have to be met in the coming years.

Effect of cryogenic treatment on tensile behavior of case carburized steel-815M17

International Nuclear Information System (INIS)

Bensely, A.; Senthilkumar, D.; Mohan Lal, D.; Nagarajan, G.; Rajadurai, A.

2007-01-01

The crown wheel and pinion represent the most highly stressed parts of a heavy vehicle; these are typically made of 815M17 steel. The reasons for the frequent failure of these components are due to tooth bending impact, wear and fatigue. The modern processes employed to produce these as high, durable components include cryogenic treatment as well as conventional heat treatment. It helps to convert retained austenite into martensite as well as promote carbide precipitation. This paper deals with the influence of cryogenic treatment on the tensile behavior of case carburized steel 815M17. The impetus for studying the tensile properties of gear steels is to ensure that steels used in gears have sufficient tensile strength to prevent failure when gears are subjected to tensile or fatigue loads, and to provide basic design information on the strength of 815M17 steel. A comparative study on the effects of deep cryogenic treatment (DCT), shallow cryogenic treatment (SCT) and conventional heat treatment (CHT) was made by means of tension testing. This test was conducted as per ASTM standard designation E 8M. The present results confirm that the tensile behavior is marginally reduced after cryogenic treatment (i.e. both shallow and deep cryogenic treatment) for 815M17 when compared with conventional heat treatment. Scanning electron microscopic (SEM) analysis of the fracture surface indicates the presence of dimples and flat fracture regions are more common in SCT specimens than for CHT and DCT-processed material

National Ignition Facility Cryogenic Target Systems Interim Management Plan

International Nuclear Information System (INIS)

Warner, B

2002-01-01

Restricted availability of funding has had an adverse impact, unforeseen at the time of the original decision to projectize the National Ignition Facility (NIF) Cryogenic Target Handling Systems (NCTS) Program, on the planning and initiation of these efforts. The purpose of this document is to provide an interim project management plan describing the organizational structure and management processes currently in place for NCTS. Preparation of a Program Execution Plan (PEP) for NCTS has been initiated, and a current draft is provided as Attachment 1 to this document. The National Ignition Facility is a multi-megajoule laser facility being constructed at Lawrence Livermore National Laboratory (LLNL) by the National Nuclear Security Administration (NNSA) in the Department of Energy (DOE). Its primary mission is to support the Stockpile Stewardship Program (SSP) by performing experiments studying weapons physics, including fusion ignition. NIF also supports the missions of weapons effects, inertial fusion energy, and basic science in high-energy-density physics. NIF will be operated by LLNL under contract to the University of California (UC) as a national user facility. NIF is a low-hazard, radiological facility, and its operation will meet all applicable federal, state, and local Environmental Safety and Health (ES and H) requirements. The NCTS Interim Management Plan provides a summary of primary design criteria and functional requirements, current organizational structure, tracking and reporting procedures, and current planning estimates of project scope, cost, and schedule. The NIF Director controls the NIF Cryogenic Target Systems Interim Management Plan. Overall scope content and execution schedules for the High Energy Density Physics Campaign (SSP Campaign 10) are currently undergoing rebaselining and will be brought into alignment with resources expected to be available throughout the NNSA Future Years National Security Plan (FYNSP). The revised schedule for

Process simulations for the LCLS-II cryogenic systems

Science.gov (United States)

Ravindranath, V.; Bai, H.; Heloin, V.; Fauve, E.; Pflueckhahn, D.; Peterson, T.; Arenius, D.; Bevins, M.; Scanlon, C.; Than, R.; Hays, G.; Ross, M.

2017-12-01

Linac Coherent Light Source II (LCLS-II), a 4 GeV continuous-wave (CW) superconducting electron linear accelerator, is to be constructed in the existing two mile Linac facility at the SLAC National Accelerator Laboratory. The first light from the new facility is scheduled to be in 2020. The LCLS-II Linac consists of thirty-five 1.3 GHz and two 3.9 GHz superconducting cryomodules. The Linac cryomodules require cryogenic cooling for the super-conducting niobium cavities at 2.0 K, low temperature thermal intercept at 5.5-7.5 K, and a thermal shield at 35-55 K. The equivalent 4.5 K refrigeration capacity needed for the Linac operations range from a minimum of 11 kW to a maximum of 24 kW. Two cryogenic plants with 18 kW of equivalent 4.5 K refrigeration capacity will be used for supporting the Linac cryogenic cooling requirements. The cryogenic plants are based on the Jefferson Lab’s CHL-II cryogenic plant design which uses the “Floating Pressure” design to support a wide variation in the cooling load. In this paper, the cryogenic process for the integrated LCLS-II cryogenic system and the process simulation for a 4.5 K cryoplant in combination with a 2 K cold compressor box, and the Linac cryomodules are described.

Environmental Exposure to Manganese in Air: Associations with Cognitive Functions

Science.gov (United States)

Manganese (Mn), an essential element, can be neurotoxic in high doses. This cross-sectional study explored the oognitive function of adults residing in two towns (Marietta and East Liverpool, Ohio, USA) identified as having high levels of environmental airborne Mn from indu...

Fatigue crack growth-Microstructure relationships in a high-manganese austenitic TWIP steel

Energy Technology Data Exchange (ETDEWEB)

Niendorf, T., E-mail: niendorf@mail.uni-paderborn.de [University of Paderborn, Lehrstuhl fuer Werkstoffkunde (Materials Science), 33095 Paderborn (Germany); Rubitschek, F.; Maier, H.J. [University of Paderborn, Lehrstuhl fuer Werkstoffkunde (Materials Science), 33095 Paderborn (Germany); Niendorf, J.; Richard, H.A. [University of Paderborn, Fachgruppe Angewandte Mechanik (Applied Mechanics), 33095 Paderborn (Germany); Frehn, A. [Benteler Automotive, Product Group Chassis Systems, An der Talle 27-31, 33102 Paderborn (Germany)

2010-04-15

The crack growth behavior of a high-manganese austenitic steel, which exhibits the twinning-induced plasticity (TWIP) effect, was investigated under positive stress ratios. An experimental study making use of miniature compact tension (CT) specimens and thorough microstructural analyses including transmission electron microscopy and fracture analyses demonstrated that the microstructural evolution in the plastic zone of the fatigued TWIP CT specimens is substantially different as compared to the monotonic plastic deformation case. Specifically, the twin density in the plastic zone of the CT specimens is very low, leading to the conclusion that the deformation mechanisms depend drastically on the loading conditions. The absence of twinning under cyclic loading in the plastic zone of the CT specimens indicates that even large accumulated plastic strains are not sufficient to cause substantial twinning in the TWIP steel. This lack of hardening preserves the ductile character of the TWIP steel in the plastic zone ahead of the crack tip and provides for a crack growth rate in the Paris regime lower than reported for other high strength steels.

Cryogenic cooling of x-ray crystals using a porous matrix

International Nuclear Information System (INIS)

Kuzay, T.M.

1992-01-01

It is well established that Si and SiC have very desirable thermophysical properties (principally, high thermal conductivity, and low thermal expansion) at cryogenic temperatures. Thus, cryocooled optics are a potentially good candidate for the first optical crystal of the third generation synchrotron machines, which will have very high heat flux levels. Currently, there is a great deal of interest, both experimental and analytical in such cryocooled crystals. The analytical studies involve cut micro- or capillary channel crystals. As opposed to machined channels, porous matrices provide significant advantages. Such matrices are known to effect superior heat transfer. They operate very quietly. Data available in the open literature suggest that surface heat flux levels up to ∼8 kW/cm 2 are possible. For cryogens for which the boiling heat transfer heat flux is a rather low value in conventional geometries, the enhancement available with such matrices is very significant. Cryogens are poor thermal conductors themselves. At cryogenic temperatures, the Si and/or SiC matrix itself becomes highly conductive: Thus, the matrix distributes the surface heat flux into the full volume effectively offsetting the poor conductivity of the coolant. In addition, the tortuous path of the coolant through the matrix increases the dwell time resulting in better heat transfer, however, at the expense of an increased pressure drop. In this study, a first optics crystal model of Si with a Si and/or SiC porous matrix as its heat exchanger and subject to prototypic synchrotron loads is analyzed, and the feasibility limits of the cooling possible with liquid nitrogen in single phase are delineated

Cryogenic Safety Rules and Guidelines at CERN

CERN Multimedia

CERN. Geneva

2016-01-01

CERN defines and implements a Safety Policy that sets out the general principles governing safety at CERN. As an intergovernmental organisation, CERN further establishes its own Safety Rules as necessary for its proper functioning. In this process, it takes into account the laws and regulation of the Host States (France and Switzerland), EU regulations and directives, as well as international regulations, standards and directives. For the safety of cryogenic equipment, this is primarily covered by the Safety Regulation for Mechanical Equipment and the General Safety Instruction for Cryogenic Equipment. In addition, CERN has also developed Safety Guidelines to support the implementation of these safety rules, covering cryogenic equipment and oxygen deficiency hazard assessment and mitigation. An overview of the cryogenic safety rules and these safety guidelines will be presented.

Arsenic, chromium, copper, iron, manganese, lead, selenium and ...

African Journals Online (AJOL)

2014-05-20

May 20, 2014 ... Arsenic, chromium, copper, iron, manganese, lead, selenium and zinc in the ... and sediment were collected and trace element concentrations were measured with an ICP-MS. ..... Clay minerals are known to have high sorption affinities ..... sediment/water quality interaction with particular reference to the.

The DAΦNE cryogenic system

International Nuclear Information System (INIS)

Modena, M.

1997-12-01

The DAΦNE Project utilises superconductivity technology for a total of six superconducting magnets: the two Experiment magnets (KLOE and FINUDA) and the four Compensator Solenoid magnets needed to compensate the magnetic effect of the Experiment magnets on the electron and positron beams. This effect, on beams of 510 MeV (nominal DAΦNE Energy), is expected to be relevant, especially with the aim of achieving a very high luminosity, which is the main target of the Project. The KLOE superconducting magnet has two possible working positions: the first in the DAΦNE Hall, when the Experiment will be in operation, and the second one in the KLOE Assembly Hall. This second position is the first to be utilised for the KLOE magnet Acceptance Test and magnetic field mapping, prior to the mounting of all the experimental apparatus inside the magnet. This note intends to present the DAΦNE Cryogenic System and how the authors have converged to the definition of a common Cryogenic System compatible with all the six superconducting magnets

Influence of Ti on the Hot Ductility of High-manganese Austenitic Steels

Science.gov (United States)

Liu, Hongbo; Liu, Jianhua; Wu, Bowei; Su, Xiaofeng; Li, Shiqi; Ding, Hao

2017-07-01

The influence of Ti addition ( 0.10 wt%) on hot ductility of as-cast high-manganese austenitic steels has been examined over the temperature range 650-1,250 °C under a constant strain rate of 10-3 s-1 using Gleeble3500 thermal simulation testing machine. The fracture surfaces and particles precipitated at different tensile temperatures were characterized by means of scanning electron microscope and X-ray energy dispersive spectrometry (SEM-EDS). Hot ductility as a function of reduction curves shows that adding 0.10 wt% Ti made the ductility worse in the almost entire range of testing temperatures. The phases' equilibrium diagrams of precipitates in Ti-bearing high-Mn austenitic steel were calculated by the Thermo-Calc software. The calculation result shows that 0.1 wt% Ti addition would cause Ti(C,N) precipitated at 1,499 °C, which is higher than the liquidus temperature of high-Mn austenitic steel. It indicated that Ti(C,N) particles start forming in the liquid high-Mn austenitic steel. The SEM-EDS results show that Ti(C,N) and TiC particles could be found along the austenite grain boundaries or at triple junction, and they would accelerate the extension of the cracks along the grain boundaries.

Permanganate-based synthesis of manganese oxide nanoparticles in ferritin

Science.gov (United States)

Olsen, Cameron R.; Smith, Trevor J.; Embley, Jacob S.; Maxfield, Jake H.; Hansen, Kameron R.; Peterson, J. Ryan; Henrichsen, Andrew M.; Erickson, Stephen D.; Buck, David C.; Colton, John S.; Watt, Richard K.

2017-05-01

This paper investigates the comproportionation reaction of MnII with {{{{MnO}}}4}- as a route for manganese oxide nanoparticle synthesis in the protein ferritin. We report that {{{{MnO}}}4}- serves as the electron acceptor and reacts with MnII in the presence of apoferritin to form manganese oxide cores inside the protein shell. Manganese loading into ferritin was studied under acidic, neutral, and basic conditions and the ratios of MnII and permanganate were varied at each pH. The manganese-containing ferritin samples were characterized by transmission electron microscopy, UV/Vis absorption, and by measuring the band gap energies for each sample. Manganese cores were deposited inside ferritin under both the acidic and basic conditions. All resulting manganese ferritin samples were found to be indirect band gap materials with band gap energies ranging from 1.01 to 1.34 eV. An increased UV/Vis absorption around 370 nm was observed for samples formed under acidic conditions, suggestive of MnO2 formation inside ferritin.

A Fully Transparent Flexible Sensor for Cryogenic Temperatures Based on High Strength Metallurgical Graphene

Directory of Open Access Journals (Sweden)

Ryszard Pawlak

2016-12-01

Full Text Available Low-temperature electronics operating in below zero temperatures or even below the lower limit of the common −65 to 125 °C temperature range are essential in medical diagnostics, in space exploration and aviation, in processing and storage of food and mainly in scientific research, like superconducting materials engineering and their applications—superconducting magnets, superconducting energy storage, and magnetic levitation systems. Such electronic devices demand special approach to the materials used in passive elements and sensors. The main goal of this work was the implementation of a fully transparent, flexible cryogenic temperature sensor with graphene structures as sensing element. Electrodes were made of transparent ITO (Indium Tin Oxide or ITO/Ag/ITO conductive layers by laser ablation and finally encapsulated in a polymer coating. A helium closed-cycle cryostat has been used in measurements of the electrical properties of these graphene-based temperature sensors under cryogenic conditions. The sensors were repeatedly cooled from room temperature to cryogenic temperature. Graphene structures were characterized using Raman spectroscopy. The observation of the resistance changes as a function of temperature indicates the potential use of graphene layers in the construction of temperature sensors. The temperature characteristics of the analyzed graphene sensors exhibit no clear anomalies or strong non-linearity in the entire studied temperature range (as compared to the typical carbon sensor.

Commissioning of cryogenic system for China Spallation Neutron Source

Science.gov (United States)

Ye, Bin; He, Chongchao; Li, Na; Ding, Meiying; Wang, Yaqiong; Yu, Zhang; He, Kun

2017-12-01

China Spallation Neutron Source(CSNS) cryogenic system provides supercritical cryogenic hydrogen to neutron moderators, including a helium refrigerator, hydrogen loop and hydrogen safety equipment. The helium refrigerator is provided by Linde with cooling capacity of 2200 W at 20 K. Hydrogen loop system mainly includes cryogenic hydrogen pipes, hydrogen circulator cold-box and accumulator cold-box. Cryogenic hydrogen pump, ortho-para convertor, helium-hydrogen heat-exchanger, hydrogen heater and accumulator are integrated in hydrogen circulation cold-box, and accumulator cold-box. Hydrogen safety equipment includes safety valves, rupture disk, hydrogen sensor, flame detector and other equipment to ensure that cryogenic system in dangerous situations will go down, vents, or takes other measures. The cryogenic system commissioning work includes four steps. First, in order to test the refrigerating capacity of refrigerator, when acceptance testing, refrigerator internal heater was used as thermal load. Second, using simulation load as heat load of moderator, hydrogen loop use helium instead of hydrogen, and cooled down to 20 K, then re-warming and test the leak detection of hydrogen loop system. Third, base on the step 2, using hydrogen as working medium, and optimized the control logic. Forth, cryogenic system with the moderators joint commissioning. Now, cryogenic system is connected with the moderators, and the forth step will be carried out in the near future.

A Review on the Synthesis of Manganese Oxide Nanomaterials and Their Applications on Lithium-Ion Batteries

Directory of Open Access Journals (Sweden)

Xiaodi Liu

2013-01-01

Full Text Available Most recently, manganese oxides nanomaterials, including MnO and MnO2, have attracted great interest as anode materials in lithium-ion batteries (LIBs for their high theoretical capacity, environmental benignity, low cost, and special properties. Up to now, manganese oxides nanostructures with excellent properties and various morphologies have been successfully synthesized. Herein, we provide an in-depth discussion of recent development of the synthesis of manganese oxides nanomaterials and their application in the field of LIBs.

Thermal Stabilization of Cryogenic System in Superconducting Cyclotron

International Nuclear Information System (INIS)

Shin, Seung Jae; Kim, Kyung Min; Cho, Hyung Hee; Hong, Bong Hwan; Kang, Joon Sun; Ahn, Dong Hyun

2011-01-01

Radiology has some useful applications for medical purpose. For cancer therapy, the superconducting cyclotron should generate heavy ion beams. It radiates heavy ion beams to cancer patients. In order to make cyclotron system stable, the cryogenic system which makes superconducting state should work constantly. However, radiation heat transfer of cryogenic system should be considered because liquid helium's boiling point is extremely low and there is huge temperature difference between the cryogenic system and ambient temperature. Accordingly, thermal analysis should be carried out. In this paper, the numerical analysis of the cryogenic system in practical superconducting cyclotron show temperature distribution and suggest the number of coolers using ANSYS Workbench program

Mercury distribution characteristics in primary manganese smelting plants

International Nuclear Information System (INIS)

Back, Seung-Ki; Sung, Jin-Ho; Moon, Young-Hoon; Kim, Young-Hee; Seok, Kwang-Seol; Song, Geum-Ju; Seo, Yong-Chil

2017-01-01

The mercury (Hg) distribution characteristics were investigated in three primary manganese smelting plants in Korea for the assessment of anthropogenic Hg released. Input and output materials were sampled from each process, and Hg concentrations in the samples were analyzed. Among the input materials, the most mercury was found in the manganese ore (83.1–99.7%) and mercury was mainly released through fly ash or off gas, depending on the condition of off gas cleaning system. As off gas temperature decreases, proportion and concentration of emitted gaseous elemental mercury (Hg 0 ) in off gas decreases. Based on mass balance study from these three plants and national manganese production data, the total amount of mercury released from those Korean plants was estimated to 644 kg/yr. About half of it was emitted into the air while the rest was released to waste as fly ash. With the results of this investigation, national inventory for Hg emission and release could be updated for the response to Minamata Convention on Mercury. - Graphical abstract: 1. Lack of data on mercury (Hg) distribution in manganese smelters. 2. Mass distribution of Hg released from 3 plants (as normalized values) were made as follows by measurements. 3. Information of distribution of Hg in Manganese smelters would be used for emission in to air and releases to other streams for the nation and globe in UNEP mercury report. - Highlights: • The mass balance study by on-site measurement from primary manganese smelting plants was made at first time in the world. • Hg distribution and main input and release pathways of Hg from primary manganese smelting plants could be found as the first time. • Gas temperature in bag filter affects Hg behavior and speciation changes in APCDs. • National inventory of Hg emssion has been updated with new data. - Mercury distribution in manganese smelting plant was investigated as the first measurements at commercial plants in the world. National Hg release

Sorbents based on xerogels of zirconium, aluminum and manganese oxyhydroxides

Directory of Open Access Journals (Sweden)

R.V. Smotraiev

2016-05-01

Full Text Available The actual problem of water supply in the world and in Ukraine, in particular, is a high level of pollution in water resources and an insufficient level of drinking water purification. With industrial wastewater, a significant amount of pollutants falls into water bodies, including suspended particles, sulfates, iron compounds, heavy metals, etc. Aim: The aim of this work is to determine the impact of aluminum and manganese ions additives on surface and sorption properties of zirconium oxyhydroxide based sorbents during their production process. Materials and Methods: The sorbents based on xerogels of zirconium, aluminum and manganese oxyhydroxides were prepared by sol-gel method during the hydrolysis of metal chlorides (zirconium oxychloride ZrOCl2, aluminum chloride AlCl3 and manganese chloride MnCl2 with carbamide. Results: The surface and sorption properties of sorbents based on xerogels of zirconium, aluminum and manganese oxyhydroxides were investigated. X-ray amorphous structure and evolved hydroxyl-hydrate cover mainly characterize the obtained xerogels. The composite sorbents based on xerogels of zirconium oxyhydroxide doped with aluminum oxyhydroxide (aS = 537 m2/g and manganese oxyhydroxide (aS = 356 m2/g have more developed specific surface area than single-component xerogels of zirconium oxyhydroxide (aS = 236 m2/g and aluminum oxyhydroxide (aS = 327 m2/g. The sorbent based on the xerogel of zirconium and manganese oxyhydroxides have the maximum SO42--ions sorption capacity. It absorbs 1.5 times more SO42–-ions than the industrial anion exchanger AN-221. The sorbents based on xerogels of zirconium oxyhydroxide has the sorption capacity of Fe3+-ions that is 1.5…2 times greater than the capacity of the industrial cation exchanger KU-2-8. The Na+-ions absorption capacity is 1.47…1.56 mmol/g for each sorbent. Conclusions: Based on these data it can be concluded that the proposed method is effective for sorbents production based on

Towards the conceptual design of the cryogenic system of the Future Circular Collider (FCC)

Science.gov (United States)

Chorowski, M.; Correia Rodrigues, H.; Delikaris, D.; Duda, P.; Haberstroh, C.; Holdener, F.; Klöppel, S.; Kotnig, C.; Millet, F.; Polinski, J.; Quack, H.; Tavian, L.

2017-12-01

Following the update of the European strategy in particle physics, CERN has undertaken an international study of possible future circular colliders beyond the LHC. The study considers several options for very high-energy hadron-hadron, electron-positron and hadron-electron colliders. From the cryogenics point of view, the most challenging option is the hadron-hadron collider (FCC-hh) for which the conceptual design of the cryogenic system is progressing. The FCC-hh cryogenic system will have to produce up to 120 kW at 1.8 K for the superconducting magnet cooling, 6 MW between 40 and 60 K for the beam-screen and thermal-shield cooling as well as 850 g/s between 40 and 290 K for the HTS current-lead cooling. The corresponding total entropic load represents about 1 MW equivalent at 4.5 K and this cryogenic system will be by far the largest ever designed. In addition, the total mass to be cooled down is about 250’000 t and an innovative cool-down process must be proposed. This paper will present the proposed cryogenic layout and architecture, the cooling principles of the main components, the corresponding cooling schemes, as well as the cryogenic plant arrangement and proposed process cycles. The corresponding required development plan for such challenging cryogenic system will be highlighted.

Cryogenic Safety HSE Seminar | 21 - 23 September 2016

CERN Multimedia

2016-01-01

With the LHC being the world’s largest superconducting installation, it’s not surprising that CERN is a world leader in cryogenic safety. On 21 and 22 September, over 100 experts in cryogenic safety will be coming to CERN to take part in CERN’s first Cryogenic Safety Seminar, which aims to stimulate collaboration and further the state of the art in this increasingly important field.  

Cryogenic refrigeration. (Latest citations from the Aerospace database). Published Search

International Nuclear Information System (INIS)

1993-09-01

The bibliography contains citations concerning cryogenic refrigeration or cryocooling. Design, development, testing, and evaluation of cryogenic cooling systems are discussed. Design applications in spacecraft, magnet cooling, superconductors, liquid fuel storage, radioastronomy, and medicine are presented. Material properties at cryogenic temperatures and cryogenic rocket propellants are considered in separate bibliographies. (Contains 250 citations and includes a subject term index and title list.)

Proposal for a cryogenic magnetic field measurement system for SSC dipole magnets

International Nuclear Information System (INIS)

Green, M.I.; Hansen, L.

1991-03-01

This proposal describes the research and development required, and the subsequent fabrication of, a system capable of making integrated magnetic multipole measurements of cryogenic 40-mm-bore SSC dipole magnets utilizing a cryogenic probe. Our experience and some preliminary studies indicate that it is highly unlikely that a 16-meter-long probe can be fabricated that will have a twist below several milliradians at cryogenic temperatures. We would anticipate a twist of several milliradians just as a result of cooldown stresses. Consequently, this proposal describes a segmented 16-meter-long probe, for which we intend to calibrate the phase of each segment to within 0.1 milliradians. The data for all segments will be acquired simultaneously, and integrated data will be generated from the vector sums of the individual segments. The calibration techniques and instrumentation required to implement this system will be described. The duration of an integral measurement at one current is expected to be under 10 seconds. The system is based on an extrapolation of the techniques used at LBL to measure cryogenic 1-meter models of SSC magnets with a cryogenic probe. It should be noted that the expansion of the dipole bore from 40 to 50 mm may make a warm-finger device practical at a cost of approximately one quarter of the cryogenic probe. A warm quadrupole measurement system can be based upon the same principles. 5 refs., 9 figs., 1 tab

Flexible cryogenic conduit

International Nuclear Information System (INIS)

Brindza, P.D.; Wines, R.R.; Takacs, J.J.

1999-01-01

A flexible and relatively low cost cryogenic conduit is described. The flexible cryogenic conduit of the present invention comprises a first inner corrugated tube with single braided serving, a second outer corrugated tube with single braided serving concentric with the inner corrugated tube, and arranged outwardly about the periphery of the inner corrugated tube and between the inner and outer corrugated tubes: a superinsulation layer; a one half lap layer of polyester ribbon; a one half lap layer of copper ribbon; a spirally wound refrigeration tube; a second one half lap layer of copper ribbon; a second one half lap layer of polyester ribbon; a second superinsulation layer; a third one half lap layer of polyester ribbon; and a spirally wound stretchable and compressible filament

Application of routine MRI and 1H-MRS in evaluating the central neurological damages caused by occupational manganese exposure

International Nuclear Information System (INIS)

Li Xiangrong; Long Liling; Jiang Muliang

2010-01-01

Objective: MRI and MR hydrogen proton spectroscopy ( 1 H-MRS) were used to detect the abnormal signal and alteration of metabolites, in order to explore the efficacy of these method in evaluating the damages of central nervous system (CNS) induced by occupational manganese exposure. Methods: Eighteen workers exposed to manganese without any manganism symptoms, 12 workers with slightly chronic manganese poisoning, and 19 healthy workers were scanned using routine MRI sequence and 1 H-MRS. The blood manganese concentration was also collected for each subject. On cerebral axial T 1 WI, the signal intensities of ipsilateral globus pallidus and frontal white matter were measured in the visually brightest area (try to select the signal homogeneous region), and the globus pallidus index (PI) was then calculated. The 1 H-MRS data was calculated to get the values of the peak height of N-acetylaspartate (NAA), choline (Cho), inositol (mI) and creatine (Cr) and the ratios of NAA/Cr, Cho/Cr, and mL/Cr were also calculated. One way ANOVA was used to compare the values of PI, NAA/Cr, Cho/Cr, mI/Cr and MnB among the three groups, and the correlations between PI and the time span of manganese exposure or blood manganese concentration were analyzed by Pearson correlation analysis. Eight workers exposed to manganese were followed up one year, and their PI, NAA/Cr before and after follow-up were compared by t test. Results: Fourteen of 18 cases exposed to manganese without any manganism symptoms showed symmetrically high intensity signal on T 1 WI, while the T 2 WI were normal. No high signal intensity was obseerved on T 1 WI in any of the healthy workers or manganese poisoning workers. We found that the average PI in manganese exposed group (1.16 ± 0.09) was significantly higher (F=24.79,P=0.000) than those of the poisoning (1.05±0.07) and control groups (1.01±0.05). The blood manganese concentration in manganese exposed group, the poisoning group and the control group were (0

Cryogenic target formation using cold gas jets

International Nuclear Information System (INIS)

Hendricks, C.D.

1980-01-01

A method and apparatus using cold gas jets for producing a substantially uniform layer of cryogenic materials on the inner surface of hollow spherical members having one or more layers, such as inertially imploded targets, are described. By vaporizing and quickly refreezing cryogenic materials contained within a hollow spherical member, a uniform layer of the materials is formed on an inner surface of the spherical member. Basically the method involves directing cold gas jets onto a spherical member having one or more layers or shells and containing the cryogenic material, such as a deuterium-tritium (DT) mixture, to freeze the contained material, momentarily heating the spherical member so as to vaporize the contained material, and quickly refreezing the thus vaporized material forming a uniform layer of cryogenic material on an inner surface of the spherical member

New application of superconductors: High sensitivity cryogenic light detectors

Energy Technology Data Exchange (ETDEWEB)

Cardani, L., E-mail: laura.cardani@roma1.infn.it [Dipartimento di Fisica, Sapienza Università di Roma, Piazzale Aldo Moro 2, 00185 Roma (Italy); Physics Department, Princeton University, Washington Road, 08544 Princeton, NJ (United States); Bellini, F.; Casali, N. [Dipartimento di Fisica, Sapienza Università di Roma, Piazzale Aldo Moro 2, 00185 Roma (Italy); INFN – Sezione di Roma, Piazzale Aldo Moro 2, 00185 Roma, Italy (Italy); Castellano, M.G. [Istituto di Fotonica e Nanotecnologie – CNR, Via Cineto Romano 42, 00156 Roma (Italy); Colantoni, I.; Coppolecchia, A. [Dipartimento di Fisica, Sapienza Università di Roma, Piazzale Aldo Moro 2, 00185 Roma (Italy); Cosmelli, C.; Cruciani, A. [Dipartimento di Fisica, Sapienza Università di Roma, Piazzale Aldo Moro 2, 00185 Roma (Italy); INFN – Sezione di Roma, Piazzale Aldo Moro 2, 00185 Roma, Italy (Italy); D' Addabbo, A. [INFN – Laboratori Nazionali del Gran Sasso, Assergi (L' Aquila) 67010 (Italy); Di Domizio, S. [INFN – Sezione di Genova, Via Dodecaneso 33, 16146 Genova (Italy); Dipartimento di Fisica, Università degli Studi di Genova, Via Dodecaneso 33, 16146 Genova (Italy); Martinez, M. [Dipartimento di Fisica, Sapienza Università di Roma, Piazzale Aldo Moro 2, 00185 Roma (Italy); INFN – Sezione di Roma, Piazzale Aldo Moro 2, 00185 Roma, Italy (Italy); Laboratorio de Fisica Nuclear y Astroparticulas, Universidad de Zaragoza, Zaragoza 50009 (Spain); Tomei, C. [INFN – Sezione di Roma, Piazzale Aldo Moro 2, 00185 Roma, Italy (Italy); and others

2017-02-11

In this paper we describe the current status of the CALDER project, which is developing ultra-sensitive light detectors based on superconductors for cryogenic applications. When we apply an AC current to a superconductor, the Cooper pairs oscillate and acquire kinetic inductance, that can be measured by inserting the superconductor in a LC circuit with high merit factor. Interactions in the superconductor can break the Cooper pairs, causing sizable variations in the kinetic inductance and, thus, in the response of the LC circuit. The continuous monitoring of the amplitude and frequency modulation allows to reconstruct the incident energy with excellent sensitivity. This concept is at the basis of Kinetic Inductance Detectors (KIDs) that are characterized by natural aptitude to multiplexed read-out (several sensors can be tuned to different resonant frequencies and coupled to the same line), resolution of few eV, stable behavior over a wide temperature range, and ease in fabrication. We present the results obtained by the CALDER collaboration with 2×2 cm{sup 2} substrates sampled by 1 or 4 Aluminum KIDs. We show that the performances of the first prototypes are already competitive with those of other commonly used light detectors, and we discuss the strategies for a further improvement.

New application of superconductors: High sensitivity cryogenic light detectors

International Nuclear Information System (INIS)

Cardani, L.; Bellini, F.; Casali, N.; Castellano, M.G.; Colantoni, I.; Coppolecchia, A.; Cosmelli, C.; Cruciani, A.; D'Addabbo, A.; Di Domizio, S.; Martinez, M.; Tomei, C.

2017-01-01

In this paper we describe the current status of the CALDER project, which is developing ultra-sensitive light detectors based on superconductors for cryogenic applications. When we apply an AC current to a superconductor, the Cooper pairs oscillate and acquire kinetic inductance, that can be measured by inserting the superconductor in a LC circuit with high merit factor. Interactions in the superconductor can break the Cooper pairs, causing sizable variations in the kinetic inductance and, thus, in the response of the LC circuit. The continuous monitoring of the amplitude and frequency modulation allows to reconstruct the incident energy with excellent sensitivity. This concept is at the basis of Kinetic Inductance Detectors (KIDs) that are characterized by natural aptitude to multiplexed read-out (several sensors can be tuned to different resonant frequencies and coupled to the same line), resolution of few eV, stable behavior over a wide temperature range, and ease in fabrication. We present the results obtained by the CALDER collaboration with 2×2 cm"2 substrates sampled by 1 or 4 Aluminum KIDs. We show that the performances of the first prototypes are already competitive with those of other commonly used light detectors, and we discuss the strategies for a further improvement.

Surface modifications induced by yttrium implantation on low manganese-carbon steel

Energy Technology Data Exchange (ETDEWEB)

Caudron, E.; Buscail, H. [Univ. Blaise Pascal Clermont-Fd II, Le Puy en Velay (France). Lab. Vellave d' Elaboration et d' Etude des Materiaux; Haanapel, V.A.C.; Jacob, Y.P.; Stroosnijder, M.F. [Institute for Health and Consumer Protection, Joint Research Center, The European Commission, 21020, Ispra (Italy)

1999-12-15

Low manganese-carbon steel samples were ion implanted with yttrium. Sample compositions and structures were investigated before and after yttrium implantations to determine the yttrium distribution in the sample. Yttrium implantation effects were characterized using several analytical and structural techniques such as X-ray photoelectron spectroscopy, reflection high energy electron diffraction, X-ray diffraction, glancing angle X-ray diffraction and Rutherford backscattering spectrometry. In this paper it is shown that correlation between composition and structural analyses provides an understanding of the main compounds induced by yttrium implantation in low manganese-carbon steel. (orig.)

Effects of electrochemical-deposition method and microstructure on the capacitive characteristics of nano-sized manganese oxide

International Nuclear Information System (INIS)

Shinomiya, Takuya; Gupta, Vinay; Miura, Norio

2006-01-01

The amorphous nano-structured manganese oxide was electrochemically deposited onto a stainless-steel electrode. The structure and surface morphology of the obtained manganese oxide were studied by means of X-ray diffraction analysis and scanning electron microscopy. The capacitive characteristics of the manganese oxide electrodes were investigated by means of cyclic voltammetry and constant current charge-discharge cycling. The morphological and capacitive characteristics of the hydrous manganese oxide was found to be strongly influenced by the electrochemical deposition conditions. The highest specific capacitance value of ca. 410 F g -1 and the specific power of ca. 54 kW kg -1 were obtained at 400 mV s -1 sweep rate of potentiodynamic deposition condition. The cyclic-life data showed that the specific capacitance was highly stable up to 10,000 cycles examined. This suggests the excellent cyclic stability of the obtained amorphous hydrous manganese oxide for supercapacitor application

Effects of electrochemical-deposition method and microstructure on the capacitive characteristics of nano-sized manganese oxide

Energy Technology Data Exchange (ETDEWEB)

Shinomiya, Takuya; Gupta, Vinay; Miura, Norio [Art, Science and Technology Center for Cooperative Research, Kyushu University, Kasuga-shi, Fukuoka 816-8580 (Japan)

2006-06-01

The amorphous nano-structured manganese oxide was electrochemically deposited onto a stainless-steel electrode. The structure and surface morphology of the obtained manganese oxide were studied by means of X-ray diffraction analysis and scanning electron microscopy. The capacitive characteristics of the manganese oxide electrodes were investigated by means of cyclic voltammetry and constant current charge-discharge cycling. The morphological and capacitive characteristics of the hydrous manganese oxide was found to be strongly influenced by the electrochemical deposition conditions. The highest specific capacitance value of ca. 410Fg{sup -1} and the specific power of ca. 54kWkg{sup -1} were obtained at 400mVs{sup -1} sweep rate of potentiodynamic deposition condition. The cyclic-life data showed that the specific capacitance was highly stable up to 10,000 cycles examined. This suggests the excellent cyclic stability of the obtained amorphous hydrous manganese oxide for supercapacitor application. (author)

Cryogenic system for production testing and measurement of Fermilab energy saver superconducting magnets

International Nuclear Information System (INIS)

Cooper, W.E.; Bianchi, A.J.; Barger, R.K.; Johnson, F.B.; McGuire, K.J.; Pinyan, K.D.; Wilson, F.R.

1983-03-01

The cryogenic system of the Fermilab Magnet Test Facility has been used to provide cooling for the testing of approximately 1200 Energy Saver superconducting magnets. The system provides liquid helium, liquid nitrogen, gas purification, and vacuum support for six magnet test stands. It provides for simultaneous high current testing of two superconducting magnets and non-high current cold testing of two additional magnets. The cryogenic system has been in operation for about 32000 hours. The 1200 magnets have taken slightly more than three years to test

A regional mineralogical study of the manganese-bearing Voelwater subgroup in the northern Cape Province

International Nuclear Information System (INIS)

Kleyenstueber, A.S.E.

1985-11-01

The Voelwater Subgroup, of the Proterozoic Transvaal Sequence, in the Hotazel area, is preserved in five structurally controlled basins, on the eastern side of the Dimoten syncline. The Subgroup represents a relatively undisturbed unit of mixed volcanogenic - chemical sedimentary rocks. The Hotazel Formation within the Voelwater Subgroup, consists of a finely banded carbonate - silicate - hematite - manganese lutite sequence of banded iron-formation and must be unique in that it contains the world's largest land-based repository of manganese. Twenty-one drill cores, sampled lithologically at intervals of approximately one metre through the total sedimentary sequence, were studied by microscopic, X-ray diffraction and electron microprobe methods. The mineralogy of the Voelwater Subgroup was studied on a regional scale, with the emphasis on the minerals within the manganese beds of the Hotazel Formation. The objective of the study was: a. To study the variation and distrubution of minerals in the various manganese ores on a regional scale. b. To compare the mineralogical differences of the different ores mined, in order to gain a better understanding of their metallurgical behaviour. c. To try to locate high-grade manganese ore target areas for future exploration, with the aid of mineralogical information. d. To try to establish the origin of the manganese in the Voelwater Formation. e. To study the relationship of the manganese units with the adjacent chemical sediments of the Hotazel Formation

Cryogenic wind tunnel technology. A way to measurement at higher Reynolds numbers

Science.gov (United States)

Beck, J. W.

1984-01-01

The goals, design, problems, and value of cryogenic transonic wind tunnels being developed in Europe are discussed. The disadvantages inherent in low-Reynolds-number (Re) wind tunnel simulations of aircraft flight at high Re are reviewed, and the cryogenic tunnel is shown to be the most practical method to achieve high Re. The design proposed for the European Transonic Wind tunnel (ETW) is presented: parameters include cross section. DISPLAY 83A46484/2 = 4 sq m, operating pressure = 5 bar, temperature = 110-120 K, maximum Re = 40 x 10 to the 6th, liquid N2 consumption = 40,000 metric tons/year, and power = 39,5 MW. The smaller Cologne subsonic tunnel being adapted to cryogenic use for preliminary studies is described. Problems of configuration, materials, and liquid N2 evaporation and handling and the research underway to solve them are outlined. The benefits to be gained by the construction of these costly installations are seen more in applied aerodynamics than in basic research in fluid physics. The need for parallel development of both high Re tunnels and computers capable of performing high-Re numerical analysis is stressed.

Cryogenics system: strategy to achieve nominal performance and reliable operation

CERN Document Server

Bremer, J; Casas, J; Claudet, S; Delikaris, D; Delruelle, N; Ferlin, G; Fluder, C; Perin, A; Perinic, G; Pezzetti, M; Pirotte, O; Tavian, L; Wagner, U

2012-01-01

During the LHC operation in 2010 and 2011, the cryogenic system has achieved an availability level fulfilling the overall requirement. To reach this level, the cryogenic system has profited like many other beam-dependent systems from the reduced beam parameters. Therefore, impacts of some failures occurred during the LHC operation were mitigated by using the overcapacity margin, the existing built-in redundancy in between adjacent sector cryogenic plants and the "cannibalization" of spares on two idle cryogenic plants. These two first years of operation were also crucial to identify the weaknesses of the present cryogenic maintenance plan and new issues like SEUs. After the LS1, nominal beam parameters are expected and the mitigated measures will be less effective or not applicable at all. Consequently, a consolidation plan to improve the MTBF and the MTTR of the LHC cryogenic system is under definition. Concerning shutdown periods, the present cryogenic sectorization imposes some restrictions in the type of ...

SiPM properties at cryogenic temperatures

Energy Technology Data Exchange (ETDEWEB)

Biroth, Maik; Achenbach, Patrick; Thomas, Andreas [Institut fuer Kernphysik, Johannes Gutenberg-Universitaet, Mainz (Germany); Downie, Evangeline [George Washington University, DC (United States); Collaboration: A2-Collaboration

2015-07-01

At the electron accelerator Mainzer Mikrotron (MAMI) an active target build of polarizable scintillators will be operated at approximately 25 mK. To read out the scintillation light, the photodetectors have to withstand cryogenic temperatures of 4 K and high count rates. Therefore the properties of different types of silicon photomultipliers (SiPMs) were studied at cryogenic temperatures. In liquid nitrogen at 77 K, problems with quenching in Hamamatsu SiPMs and with the protective epoxy layer covering Zecotek SiPMs were observed. Tests with one Zecotek SiPM were successful after removal of the epoxy layer in liquid helium at 4 K and no after-pulses could be observed. Fundamental parameters like break-down voltage, single-pixel gain, crosstalk probability and the dark-count rate were measured and compared to room temperature. The photon detection efficiency was estimated by SiPMs response to short LED pulses. All these parameters were extracted by curve-fitting of SiPM charge spectra with a new analytical function.

Occupational neurotoxicology due to heavy metals-especially manganese poisoning

International Nuclear Information System (INIS)

Inoue, Naohide

2007-01-01

The most hazardous manganese exposures occur in mining and smelting of ore. Recently, the poisoning has been frequently reported to be associated with welding. In occupational exposure, manganese is absorbed mainly by inhalation. Manganese preferentially accumulates in tissues rich in mitochondria. It also penetrates the blood brain barrior and accumulate in the basal ganglia, especially the globus pallidus, but also the striatum. Manganese poisoning is clinically characterized by the central nervous system involvement including psychiatric symptomes, extrapyramidal signs, and less frequently other neurological manifestations. Psychiatric symptomes are well described in the manganese miners and incrude sleep disturbance, disorientation, emotional lability, compulsive acts, hallucinations, illusions, and delusions. The main characteristic manifestations usually begin shortly after the appearance of these psychiatric symptomes. The latter neurological signs are progressive bradykinesia, dystonia, and disturbance of gait. Bradykinesia is one of the most important findings. There is a remarkable slowing of both active and passive movements of the extremities. Micrographia is frequently observed and a characteristic finding. The patients may show some symmetrical tremor, which usually not so marked. The dystonic posture of the limbs is often accompanied by painfull cramps. This attitudal hypertonia has a tendency to decrease or disappear in the supine position and to increase in orthostation. Cog-wheel rigidity is also elisited on the passive movement of all extremities. Gait disturbance is also characteristic in this poisoning. In the severe cases, cook gait has been reported. The patient uses small steps, but has a tendency to elevate the heels and to rotate them outward. He progress without pressing on the flat of his feet, but only upon the metatarsophalangeal articulations, mainly of the fourth and fifth toes. Increased signal in T1-weighted image in the basal

A magnetic route to measure the average oxidation state of mixed-valent manganese in manganese oxide octahedral molecular sieves (OMS).

Science.gov (United States)

Shen, Xiong-Fei; Ding, Yun-Shuang; Liu, Jia; Han, Zhao-Hui; Budnick, Joseph I; Hines, William A; Suib, Steven L

2005-05-04

A magnetic route has been applied for measurement of the average oxidation state (AOS) of mixed-valent manganese in manganese oxide octahedral molecular sieves (OMS). The method gives AOS measurement results in good agreement with titration methods. A maximum analysis deviation error of +/-7% is obtained from 10 sample measurements. The magnetic method is able to (1) confirm the presence of mixed-valent manganese and (2) evaluate AOS and the spin states of d electrons of both single oxidation state and mixed-valent state Mn in manganese oxides. In addition, the magnetic method may be extended to (1) determine AOS of Mn in manganese oxide OMS with dopant "diamagnetic" ions, such as reducible V5+ (3d0) ions, which is inappropriate for the titration method due to interference of redox reactions between these dopant ions and titration reagents, such as KMnO4, (2) evaluate the dopant "paramagnetic" ions that are present as clusters or in the OMS framework, and (3) determine AOS of other mixed-valent/single oxidation state ion systems, such as Mo3+(3d3)-Mo4+(3d2) systems and Fe3+ in FeCl3.

A high field and cryogenic test facility for neutron irradiated superconducting wire

Science.gov (United States)

Nishimura, A.; Miyata, H.; Yoshida, M.; Iio, M.; Suzuki, K.; Nakamoto, T.; Yamazaki, M.; Toyama, T.

2017-12-01

A 15.5 T superconducting magnet and a variable temperature insert (VTI) system were installed at a radiation control area in Oarai center in Tohoku University to investigate the superconducting properties of activated superconducting materials by fast neutron. The superconductivity was measured at cryogenic temperature and high magnetic field. During these tests, some inconvenient problems were observed and the additional investigation was carried out. The variable temperature insert was designed and assembled to perform the superconducting property tests. without the liquid helium. To remove the heat induced by radiation and joule heating, high purity aluminum rod was used in VTI. The thermal contact was checked by FEM analysis and an additional support was added to confirm the decreasing the stress concentration and the good thermal contact. After the work for improvement, it was affirmed that the test system works well and all troubles were resolved. In this report, the improved technical solution is described and the first data set on the irradiation effect on Nb3Sn wire is presented.

Feasibility Study of Cryogenic Cutting Technology by Using a Computer Simulation and Manufacture of Main Components for Cryogenic Cutting System

International Nuclear Information System (INIS)

Kim, Sung Kyun; Lee, Dong Gyu; Lee, Kune Woo; Song, Oh Seop

2009-01-01

Cryogenic cutting technology is one of the most suitable technologies for dismantling nuclear facilities due to the fact that a secondary waste is not generated during the cutting process. In this paper, the feasibility of cryogenic cutting technology was investigated by using a computer simulation. In the computer simulation, a hybrid method combined with the SPH (smoothed particle hydrodynamics) method and the FE (finite element) method was used. And also, a penetration depth equation, for the design of the cryogenic cutting system, was used and the design variables and operation conditions to cut a 10 mm thickness for steel were determined. Finally, the main components of the cryogenic cutting system were manufactures on the basis of the obtained design variables and operation conditions.

Operational present status and reliability analysis of the upgraded EAST cryogenic system

Science.gov (United States)

Zhou, Z. W.; Y Zhang, Q.; Lu, X. F.; Hu, L. B.; Zhu, P.

2017-12-01

Since the first commissioning in 2005, the cryogenic system for EAST (Experimental Advanced Superconducting Tokamak) has been cooled down and warmed up for thirteen experimental campaigns. In order to promote the refrigeration efficiencies and reliability, the EAST cryogenic system was upgraded gradually with new helium screw compressors and new dynamic gas bearing helium turbine expanders with eddy current brake to improve the original poor mechanical and operational performance from 2012 to 2015. Then the totally upgraded cryogenic system was put into operation in the eleventh cool-down experiment, and has been operated for the latest several experimental campaigns. The upgraded system has successfully coped with various normal operational modes during cool-down and 4.5 K steady-state operation under pulsed heat load from the tokamak as well as the abnormal fault modes including turbines protection stop. In this paper, the upgraded EAST cryogenic system including its functional analysis and new cryogenic control networks will be presented in detail. Also, its operational present status in the latest cool-down experiments will be presented and the system reliability will be analyzed, which shows a high reliability and low fault rate after upgrade. In the end, some future necessary work to meet the higher reliability requirement for future uninterrupted long-term experimental operation will also be proposed.

A Scanning Quantum Cryogenic Atom Microscope

Science.gov (United States)

Lev, Benjamin

Microscopic imaging of local magnetic fields provides a window into the organizing principles of complex and technologically relevant condensed matter materials. However, a wide variety of intriguing strongly correlated and topologically nontrivial materials exhibit poorly understood phenomena outside the detection capability of state-of-the-art high-sensitivity, high-resolution scanning probe magnetometers. We introduce a quantum-noise-limited scanning probe magnetometer that can operate from room-to-cryogenic temperatures with unprecedented DC-field sensitivity and micron-scale resolution. The Scanning Quantum Cryogenic Atom Microscope (SQCRAMscope) employs a magnetically levitated atomic Bose-Einstein condensate (BEC), thereby providing immunity to conductive and blackbody radiative heating. The SQCRAMscope has a field sensitivity of 1.4 nT per resolution-limited point (2 um), or 6 nT / Hz1 / 2 per point at its duty cycle. Compared to point-by-point sensors, the long length of the BEC provides a naturally parallel measurement, allowing one to measure nearly one-hundred points with an effective field sensitivity of 600 pT / Hz1 / 2 each point during the same time as a point-by-point scanner would measure these points sequentially. Moreover, it has a noise floor of 300 pT and provides nearly two orders of magnitude improvement in magnetic flux sensitivity (down to 10- 6 Phi0 / Hz1 / 2) over previous atomic probe magnetometers capable of scanning near samples. These capabilities are for the first time carefully benchmarked by imaging magnetic fields arising from microfabricated wire patterns and done so using samples that may be scanned, cryogenically cooled, and easily exchanged. We anticipate the SQCRAMscope will provide charge transport images at temperatures from room to \\x9D4K in unconventional superconductors and topologically nontrivial materials.

Aquatic environmental risk assessment of manganese processing industries.

Science.gov (United States)

Marks, Becky; Peters, Adam; McGough, Doreen

2017-01-01

An environmental risk assessment (ERA) has been conducted for sites producing and processing manganese and its inorganic compounds, focussing on potential risks to freshwater. A site specific questionnaire was used to collect information. Sites fall into three broad categories: mining sites, refining sites, and sites producing chemicals and pigments. Waste disposal is principally carried out by the treatment of liquid wastes to separate solids for disposal off-site with a consented wastewater discharge, or disposal on-site using evaporation or settlement ponds in order to maintain the waste materials in a suitable manner following site closure. The main source of emissions from refining and alloying sites is from the treatment of emissions to air using wet scrubber air filters. There is also the potential for fugitive environmental emissions of manganese from stockpiles of raw material held on-site. Data provided from the questionnaires were both site-specific and also commercially sensitive. Therefore, this paper has undertaken the manganese exposure assessment, using a probabilistic approach to reflect the distribution of emissions of manganese and also to maintain the confidentiality of site specific data. An inverse correlation was observed between the total annual tonnage of manganese processed at the site and the emission factor, such that sites processing larger quantities resulted in lower emissions of manganese per tonne processed. The hazard assessment determined a Predicted No Effect Concentration (PNEC) for freshwater using a species sensitivity distribution approach, resulting in a freshwater PNEC of 0.075mgL -1 for soluble manganese. Based on the exposure data and the freshwater PNEC derived for this study, the distributions of risk characterisation ratios using the probabilistic approach indicates that two thirds of manganese processing sites would not be expected to pose a potential risk to the local aquatic environment due to wastewater emissions

Secondary cell with orthorhombic alkali metal/manganese oxide phase active cathode material

Science.gov (United States)

Doeff, Marca M.; Peng, Marcus Y.; Ma, Yanping; Visco, Steven J.; DeJonghe, Lutgard C.

1996-01-01

An alkali metal manganese oxide secondary cell is disclosed which can provide a high rate of discharge, good cycling capabilities, good stability of the cathode material, high specific energy (energy per unit of weight) and high energy density (energy per unit volume). The active material in the anode is an alkali metal and the active material in the cathode comprises an orthorhombic alkali metal manganese oxide which undergoes intercalation and deintercalation without a change in phase, resulting in a substantially linear change in voltage with change in the state of charge of the cell. The active material in the cathode is an orthorhombic structure having the formula M.sub.x Z.sub.y Mn.sub.(1-y) O.sub.2, where M is an alkali metal; Z is a metal capable of substituting for manganese in the orthorhombic structure such as iron, cobalt or titanium; x ranges from about 0.2 in the fully charged state to about 0.75 in the fully discharged state, and y ranges from 0 to 60 atomic %. Preferably, the cell is constructed with a solid electrolyte, but a liquid or gelatinous electrolyte may also be used in the cell.

Characterization of titanium alloys for cryogenic applications

International Nuclear Information System (INIS)

Reytier, M.; Kircher, F.; Levesy, B.

2002-01-01

Titanium alloys are employed in the design of superconducting magnet support systems for their high mechanical strength associated with their low thermal conductivity. But their use requires a careful attention to their crack tolerance at cryogenic temperature. Measurements have been performed on two extra low interstitial materials (Ti-5Al-2.5Sn ELI and Ti-6Al-4V ELI) with different thickness and manufacturing process. The investigation includes the tensile properties at room and liquid helium temperatures using smooth and notched samples. Moreover, the fracture toughness has been determined at 4.2 K using Compact Tension specimens. The microstructure of the different alloys and the various fracture surfaces have also been studied. After a detailed description of the experimental procedures, practical engineering characteristics are given and a comparison of the different titanium alloys is proposed for cryogenic applications

Compositional changes of surface sediments and variability of manganese nodules in the Peru Basin

Science.gov (United States)

Marchig, Vesna; von Stackelberg, Ulrich; Hufnagel, Heinz; Durn, Goran

Two types of manganese nodules were observed in the Peru Basin: large botryoidal nodules in basins and small ellipsoidal nodules on slope positions. The sediment in areas with large botryoidal nodules contains a thinner and weaker oxidation zone than the sediment under small ellipsoidal nodules, indicating that diagenetic processes in the sediment, which supply manganese nodules with metals for their growth, are stronger in sediments on which large botryoidal nodules grow. Organic matter, which activates remobilization of metals, occurs mostly in the form of refractory lipidic compounds in the inner capsule of radiolaria. This material needs bacterial degradation to act as a reducing agent. Easily oxidizable organic components could not be found in the sediments. Other changes in sediment composition do not have a link to manganese nodule growth. Biogenous components (radiolarians, organogenic barite and apatite) increase towards the equatorial high-productivity zone. Authigenous clay minerals (nontronite as well as montmorillonite with high Fe +3 incorporation on positions of ochtaedral Al) increase with distance from the continent. The assessment of environmental impacts will have to take into account the regional differences in sediment composition and the small-scale variability of manganese nodules.

Influence of iron supply on toxic effects of manganese, molybdenum and vanadium on soybean, peas, and flax

Energy Technology Data Exchange (ETDEWEB)

Warington, K

1954-01-01

The investigations were carried out in nutrient solution with iron as ferric citrate and nitrogen in the form of nitrate. The addition of 2.5 ppm vanadium to plants in which iron chlorosis was already established, either by a lack of iron or by excess manganese, failed to counteract the condition, and caused toxic symptoms. The reduction of the standard iron supply to 1/2 or 1/3 accentuated the toxicity of 2.5 or 5 ppm V to soybean and flax, but a similar reduction in phosphorus had no influence. The toxicity to peas, however, was increased when the phosphorus was reduced to 1/10, provided the iron level was high (20 ppm Fe). Raising the iron supply to 20 or 30 ppm counteracted the toxicity of manganese (10 ppm), molybdenum (40 ppm) and vanadium (2.5 ppm), but the result was less marked when these three elements were combined. Iron supplied in successive, small doses proved less efficient in overcoming molybdenum or vanadium, but not manganese excess, than the same amount of iron supplied in fewer and larger quantities. Varying the iron supply had little effect when the concentration of the three elements was low. When increased iron supply had reduced the chlorosis caused by high manganese or vanadium, it also reduced the manganese and vanadium contents of the shoot (ppm/dm), but the molybdenum content was only lowered by high iron when given in non-toxic concentrations (0.1 ppm Mo) combined with excess manganese. Yield data for soybean and flax indicated an interaction between manganese with both molybdenum and vanadium if the iron supply was low, but none between molybdenum and vanadium. The effect of all three metals was additive in respect to iron.

Lupines, manganese, and devil-sickness: an Anglo-Saxon medical response to epilepsy.

Science.gov (United States)

Dendle, P

2001-01-01

The most frequently prescribed herb for "devil-sickness" in the vernacular medical books from Anglo-Saxon England, the lupine, is exceptionally high in manganese. Since manganese depletion has been linked with recurring seizures in both clinical and experimental studies, it is possible that lupine administration responded to the particular pathophysiology of epilepsy. Lupine is not prescribed for seizures in classical Mediterranean medical sources, implying that the Northern European peoples (if not the Anglo-Saxons themselves) discovered whatever anticonvulsive properties the herb may exhibit.

Cryogenic technology review of cold neutron source facility for localization

Energy Technology Data Exchange (ETDEWEB)

Lee, Hun Cheol; Park, D. S.; Moon, H. M.; Soon, Y. P. [Daesung Cryogenic Research Institute, Ansan (Korea); Kim, J. H. [United Pacific Technology, Inc., Ansan (Korea)

1998-02-01

This Research is performed to localize the cold neutron source(CNS) facility in HANARO and the report consists of two parts. In PART I, the local and foreign technology for CNS facility is investigated and examined. In PART II, safety and licensing are investigated. CNS facility consists of cryogenic and warm part. Cryogenic part includes a helium refrigerator, vacuum insulated pipes, condenser, cryogenic fluid tube and moderator cell. Warm part includes moderator gas control, vacuum equipment, process monitoring system. Warm part is at high level as a result of the development of semiconductor industries and can be localized. However, even though cryogenic technology is expected to play a important role in developing the 21st century's cutting technology, it lacks of specialists and the research facility since the domestic market is small and the research institutes and government do not recognize the importance. Therefore, it takes a long research time in order to localize the facility. The safety standard of reactor for hydrogen gas in domestic nuclear power regulations is compared with that of the foreign countries, and the licensing method for installation of CNS facility is examined. The system failure and its influence are also analyzed. 23 refs., 59 figs., 26 tabs. (Author)

CEBAF cryogenic system

International Nuclear Information System (INIS)

Brindza, P.; Rode, C.

1986-01-01

The Continuous Electron Beam Accelerator Facility (CEBAF) is a standing wave superconducting linear accelerator with a maximum energy of 4 GeV and 200 μA beam current. The 418 Cornell/CEBAF superconducting niobium accelerating cavities are arranged in two 0.5 GeV linacs with magnetic recirculating arcs at each end. These accelerating cavities are arranged in pairs in a cryounit. The ensemble of four cryounits (8 cavities) together with their end caps makes up a complete cryostat called a cryogenic module. The four cryounit helium vessels are cross connected to each other and share a common cryogen supply, radiation shield and insulating vacuum. The cryogenics system for CEBAF consists of a 5kW central helium refrigerator and a transfer line system to supply 2.2 K 2.8 ATM helium to the cavity cryostats, 40 K helium at 3.5 ATM to the radiation shields and 4.5K helium at 2.8 ATM to the superconducting magnetic spectrometers in the experimental halls. Both the 2.2 K and the 4.5 K helium are expanded by Joule-Thompson (JT) valves in the individual cryostats yielding 2.0 K at .031 ATM and 4.4 K at 1.2 ATM respectively. The Central Helium Refrigerator is located in the center of the CEBAF racetrack with the transfer lines located in the linac tunnels

Thermodynamic properties of cryogenic fluids

CERN Document Server

Leachman, Jacob; Lemmon, Eric; Penoncello, Steven

2017-01-01

This update to a classic reference text provides practising engineers and scientists with accurate thermophysical property data for cryogenic fluids. The equations for fifteen important cryogenic fluids are presented in a basic format, accompanied by pressure-enthalpy and temperature-entropy charts and tables of thermodynamic properties. It begins with a chapter introducing the thermodynamic relations and functional forms for equations of state, and goes on to describe the requirements for thermodynamic property formulations, needed for the complete definition of the thermodynamic properties of a fluid. The core of the book comprises extensive data tables and charts for the most commonly-encountered cryogenic fluids. This new edition sees significant updates to the data presented for air, argon, carbon monoxide, deuterium, ethane, helium, hydrogen, krypton, nitrogen and xenon. The book supports and complements NIST’s REFPROP - an interactive database and tool for the calculation of thermodynamic propertie...

Removal of Iron and Manganese in Groundwater using Natural Biosorbent

Science.gov (United States)

Baharudin, F.; Tadza, M. Y. Mohd; Imran, S. N. Mohd; Jani, J.

2018-04-01

This study was conducted to measure and compare the concentration of iron, manganese and hardness of the river and groundwater and to determine the effectiveness of iron and manganese removal by using natural biosorbent which is banana peels. The samples of river and groundwater were collected at riverbank filtration site at Jenderam Hilir, Dengkil. Based on the water quality investigation, the concentration of iron and manganese in the samples of groundwater have exceeded the drinking water quality standard which are 0.3 mg/L for iron and 0.1 mg/L for manganese. The removal process of the iron and manganese in the groundwater was done by using 2, 4 and 8 grams of banana peels activated carbon. It is found that with higher amount of activated banana peels, the removal of iron and manganese is more effective. The ranges of percentage of iron and manganese removal are between 82.25% to 90.84% and 98.79% to 99.43% respectively. From the result, banana peels activated carbon can be concluded as a one of the most effective low-cost adsorbent for groundwater treatment.

Manganese-enhanced magnetic resonance imaging (MEMRI).

Science.gov (United States)

Koretsky, Alan P; Silva, Afonso C

2004-12-01

Manganese ion (Mn2+) is an essential metal that participates as a cofactor in a number of critical biological functions, such as electron transport, detoxification of free radicals and synthesis of neurotransmitters. Mn2+ can enter excitable cells using some of the same transport systems as Ca2+ and it can bind to a number of intracellular sites because it has high affinity for Ca2+ and Mg2+ binding sites on proteins and nucleic acids. Paramagnetic forms of manganese ions are potent MRI relaxation agents. Indeed, Mn2+ was the first contrast agent proposed for use in MRI. Recently, there has been renewed interest in combining the strong MRI relaxation effects of Mn2+ with its unique biology, in order to further expand the already broad assortment of useful information that can be measured by MRI. Such an approach has been continuously developed in the past several years to provide unique tissue contrast, to assess tissue viability, to act as a surrogate marker of calcium influx into cells and to trace neuronal connections. This special issue of NMR in Biomedicine on manganese-enhanced MRI (MEMRI) is aimed at providing the readers of this journal with an extensive review of some of the most prominent applications of MEMRI in biological systems. Written by several of the leaders in the field, the reviews and original research articles featured in this special issue are likely to offer an exciting and inspiring view of the broad range of applications of MEMRI. Copyright 2004 John Wiley & Sons, Ltd.

[Expression of heat shock protein 70 and its mRNA in career exposure to manganese].

Science.gov (United States)

Chen, Wenwen; Shao, Hua; Chi, Mingfeng; Zhang, Zhihu; Shan, Yongle; Zou, Wei

2015-10-01

To analyze the expression levels of heat shock protein70 (HSPs70) and HSPs70 mRNA in different exposure to manganese, and research the neuroprotective effect on the career exposure to manganese. From 2008 to 2009, with cross-sectional study design, and in a locomotive and rolling stock works, by stratified random sampling method, the exposed sample consisted of 180 welders from different welding shops and 100 unexposed in the last three years, non-welder controls with age-matched workers of similar socioeconomic status from the same industry. The control workers had not been exposed to neurotoxic chemicals. The mRNA expressions of four different metabolic enzyme were detected by SYBR Green I quantitative real-time polymerase chain reaction. The expression levels of the two enzymes mRNA in different exposure to manganese were analyzed. The expressions of HSPs70 were detected by Western blot. The concentration of air manganese was determined by GFAAS. The average concentration of 8 h time (8h-TWA) was used to express the level of individual exposure to manganese, according to the air manganese workplace occupational exposure limit (8h-TWA=0.15 mg/m3), the exposed group is divided into high exposed group (>0.15 mg/m3) and low exposure group (<0.15 mg/m3). The individuals exposed to manganese dose of exposed group ((0.25±0.31) mg/m3) was higher than the control group ((0.06±0.02) mg/m3) (t=6.15, P=0.001); individuals exposed to manganese dose of high exposure group for (0.42±0.34) mg/m3, which was higher than low exposure group (0.09±0.07) mg/m3 (t=9.80, P=0.001). HSPs70 mRNA and protein of exposure group (5.65±0.21, 3.26±0.15) were higher than the reference group (0.41±0.03, 1.32±0.12) (t=18.91, t=8.68, P=0.001). HSP70 mRNA and protein of high exposure group (6.48±0.37, 3.67±0.26) were higher than the low exposure group (5.15±0.23, 3.02±0.19) (t=3.24, t=2.01, P=0.003, P=0.043). The expression of peripheral blood lymphocytes HSPs70 level and HSPs70 m

Cryogenically cooled monochromators for the Advanced Photon Source

International Nuclear Information System (INIS)

Mills, D.M.

1996-01-01

The use of cryogenically cooled monochromators looks to be a very promising possibility for the Advanced Photon Source. This position has recently been bolstered by several experiments performed on beamlines at the ESRF and CHESS. At the ESRF, several crystal geometries have been tested that were designed for high power densities (approx-gt 150 W/mm 2 ) and moderate total absorbed powers (<200 W). These geometries have proven to be very successful at handling these power parameters with measured strains on the arc-second level. The experiments performed at CHESS were focused on high total power (approx-gt 1000 W) but moderate power densities. As with the previously mentioned experiments, the crystals designed for this application performed superbly with no measurable broadening of the rocking curves on the arc-second level. These experiments will be summarized and, based on these results, the performance of cryogenic monochromators for the APS will be assessed. copyright 1996 American Institute of Physics

Development of multifunctional electronic modules for cryogenic applications

Energy Technology Data Exchange (ETDEWEB)

Gust, Norbert; Kade, Andreas; Klier, Juergen [Institut fuer Luft- und Kaeltetechnik (ILK) gemeinuetzige Gesellschaft mbH, Dresden (Germany)

2017-07-01

A new universal cryogenic measurement system has been developed which can measure resistance and voltages with high precision (< 0.025 %) and low noise (-88 dB) at low powers (< 1 nW) in a high electromagnetic interference environment. The system is effectively designed and equipped with noise and distortion suppressing electronics and algorithms. It can be extended with cryogenic multiplexers for up to 80 sensors, which can be directly mounted inside cryostats for reduced wiring. The size of the devices is relatively small (handheld), low power (< 2 W), can operate on battery and has easy access to calibration and sensor data. Sensor types are not limited and it can be used to measure, e.g., temperature, voltage, magnetic field, pressure and level simultaneously. Within this paper we present our developments and first measurement results. The key components which we describe in detail are cold multiplexers and smart measurement bridges for a wide field of applications.

Evidence for polaron conduction in nanostructured manganese ferrite

International Nuclear Information System (INIS)

Gopalan, E Veena; Anantharaman, M R; Malini, K A; Saravanan, S; Kumar, D Sakthi; Yoshida, Yasuhiko

2008-01-01

Nanoparticles of manganese ferrite were prepared by the chemical co-precipitation technique. The dielectric parameters, namely, real and imaginary dielectric permittivity (ε' and ε-prime), ac conductivity (σ ac ) and dielectric loss tangent (tanδ), were measured in the frequency range of 100 kHz-8 MHz at different temperatures. The variations of dielectric dispersion (ε') and dielectric absorption (ε-prime) with frequency and temperature were also investigated. The variation of dielectric permittivity with frequency and temperature followed the Maxwell-Wagner model based on interfacial polarization in consonance with Koops phenomenological theory. The dielectric loss tangent and hence ε-prime exhibited a relaxation at certain frequencies and at relatively higher temperatures. The dispersion of dielectric permittivity and broadening of the dielectric absorption suggest the possibility of a distribution of relaxation time and the existence of multiple equilibrium states in manganese ferrite. The activation energy estimated from the dielectric relaxation is found to be high and is characteristic of polaron conduction in the nanosized manganese ferrite. The ac conductivity followed a power law dependence σ ac = Bω n typical of charge transport assisted by a hopping or tunnelling process. The observed minimum in the temperature dependence of the frequency exponent n strongly suggests that tunnelling of the large polarons is the dominant transport process

Ion Acceleration by Laser Plasma Interaction from Cryogenic Microjets

Energy Technology Data Exchange (ETDEWEB)

Propp, Adrienne [Harvard Univ., Cambridge, MA (United States)

2015-08-16

Processes that occur in extreme conditions, such as in the center of stars and large planets, can be simulated in the laboratory using facilities such as SLAC National Accelerator Laboratory and the Jupiter Laser Facility (JLF) at Lawrence Livermore National Laboratory (LLNL). These facilities allow scientists to investigate the properties of matter by observing their interactions with high-power lasers. Ion acceleration from laser plasma interaction is gaining greater attention today due to its widespread potential applications, including proton beam cancer therapy and fast ignition for energy production. Typically, ion acceleration is achieved by focusing a high power laser on thin foil targets through a mechanism called Target Normal Sheath Acceleration. However, this mechanism is not ideal for creating the high-energy proton beams needed for future applications. Based on research and recent experiments, we hypothesized that a pure liquid cryogenic jet would be an ideal target for exploring new regimes of ion acceleration. Furthermore, it would provide a continuous, pure target, unlike metal foils which are consumed in the interaction and easily contaminated. In an effort to test this hypothesis, we used the 527 nm split beam, frequency-doubled TITAN laser at JLF. Data from the cryogenic jets was limited due to the flow of current up the jet into the nozzle during the interaction, heating the jet and damaging the orifice. However, we achieved a pure proton beam with evidence of a monoenergetic feature. Furthermore, data from gold and carbon wires showed surprising and interesting results. Preliminary analysis of data from two ion emission diagnostics, Thomson parabola spectrometers (TPs) and radio chromic films (RCFs), suggests that shockwave acceleration occurred rather than target normal sheath acceleration, the standard mechanism of ion acceleration. Upon completion of the experiment at TITAN, I researched the possibility of transforming our liquid cryogenic

Ion Acceleration by Laser Plasma Interaction from Cryogenic Microjets

International Nuclear Information System (INIS)

Propp, Adrienne

2015-01-01

Processes that occur in extreme conditions, such as in the center of stars and large planets, can be simulated in the laboratory using facilities such as SLAC National Accelerator Laboratory and the Jupiter Laser Facility (JLF) at Lawrence Livermore National Laboratory (LLNL). These facilities allow scientists to investigate the properties of matter by observing their interactions with high-power lasers. Ion acceleration from laser plasma interaction is gaining greater attention today due to its widespread potential applications, including proton beam cancer therapy and fast ignition for energy production. Typically, ion acceleration is achieved by focusing a high power laser on thin foil targets through a mechanism called Target Normal Sheath Acceleration. However, this mechanism is not ideal for creating the high-energy proton beams needed for future applications. Based on research and recent experiments, we hypothesized that a pure liquid cryogenic jet would be an ideal target for exploring new regimes of ion acceleration. Furthermore, it would provide a continuous, pure target, unlike metal foils which are consumed in the interaction and easily contaminated. In an effort to test this hypothesis, we used the 527 nm split beam, frequency-doubled TITAN laser at JLF. Data from the cryogenic jets was limited due to the flow of current up the jet into the nozzle during the interaction, heating the jet and damaging the orifice. However, we achieved a pure proton beam with evidence of a monoenergetic feature. Furthermore, data from gold and carbon wires showed surprising and interesting results. Preliminary analysis of data from two ion emission diagnostics, Thomson parabola spectrometers (TPs) and radio chromic films (RCFs), suggests that shockwave acceleration occurred rather than target normal sheath acceleration, the standard mechanism of ion acceleration. Upon completion of the experiment at TITAN, I researched the possibility of transforming our liquid cryogenic

Manganese and acute paranoid psychosis: A case report

NARCIS (Netherlands)

W.M.A. Verhoeven (Wim); J.I.M. Egger (Jos); H.J. Kuijpers (Harold)

2011-01-01

textabstractIntroduction: Manganese regulates many enzymes and is essential for normal development and body function. Chronic manganese intoxication has an insidious and progressive course and usually starts with complaints of headache, fatigue, sleep disturbances, irritability and emotional

Highly Simple Deep Eutectic Solvent Extraction of Manganese in Vegetable Samples Prior to Its ICP-OES Analysis.

Science.gov (United States)

Bağda, Esra; Altundağ, Hüseyin; Soylak, Mustafa

2017-10-01

In the present work, simple and sensitive extraction methods for selective determination of manganese have been successfully developed. The methods were based on solubilization of manganese in deep eutectic solvent medium. Three deep eutectic solvents with choline chloride (vitamin B4) and tartaric/oxalic/citric acids have been prepared. Extraction parameters were optimized with using standard reference material (1573a tomato leaves). The quantitative recovery values were obtained with 1.25 g/L sample to deep eutectic solvent (DES) volume, at 95 °C for 2 h. The limit of detection was found as 0.50, 0.34, and 1.23 μg/L for DES/tartaric, DES/oxalic, and DES/citric acid, respectively. At optimum conditions, the analytical signal was linear for the range of 10-3000 μg/L for all studied DESs with the correlation coefficient >0.99. The extraction methods were applied to different real samples such as basil herb, spinach, dill, and cucumber barks. The known amount of manganese was spiked to samples, and good recovery results were obtained.

Long-term cryogenic space storage system

Science.gov (United States)

Hopkins, R. A.; Chronic, W. L.

1973-01-01

Discussion of the design, fabrication and testing of a 225-cu ft spherical cryogenic storage system for long-term subcritical applications under zero-g conditions in storing subcritical cryogens for space vehicle propulsion systems. The insulation system design, the analytical methods used, and the correlation between the performance test results and analytical predictions are described. The best available multilayer insulation materials and state-of-the-art thermal protection concepts were applied in the design, providing a boiloff rate of 0.152 lb/hr, or 0.032% per day, and an overall heat flux of 0.066 Btu/sq ft hr based on a 200 sq ft surface area. A six to eighteen month cryogenic storage is provided by this system for space applications.

Manganese content of Orosi valley fodder and its effect on hair concentration and reproduction in dairy cows

International Nuclear Information System (INIS)

Fonseca, H.; Lang, C.

1976-01-01

An integrated study has been made of the relationship - which has been established separately by the various authors whose names are listed - existing between the content of manganese in fodder, its concentration in the hair of dairy cattle and its effects on the reproductive behaviour of these animals. The study was carried out in Orosi valley (Costa Rica) and included: determination of the manganese content of eight types of fodder from 48 sampling points distributed over five sectors; determination of the concentration of this mineral in the hair of 14 and 16 cows, respectively, from two dairy farms (A and B); and, lastly, an analytical evaluation of the reproduction indices obtained, to check on the findings of other authors. For comparison purposes use was made of the fodder and hair indices obtained at another large dairy farm (C) located in an area that is considered normal as far as manganese content of fodder is concerned and in which the fertility index was high. These studies show that each type of fodder studied has its own manganese uptake properties; that the manganese content of the hair (91, 73 and 18 ppm respectively) in farms A, B and C is related directly to the content of this element in forage (210, 130 and 74 ppm respectively); lastly, they show that a manganese content of more than 100 ppm in fodder can be one of the factors affecting the reproductive capacity of dairy cattle herds: 2.30 and 2.18 couplings per live birth and parturition indices of 57.8 and 64.2% in farms A and B with a high manganese content in the fodder, as against 1.49 couplings per birth and parturition indices of 90% in farm C with a normal manganese content in fodder. (author)

Cryogenics for SMES

International Nuclear Information System (INIS)

McIntosh, G.E.

1981-01-01

A wide-ranging study of superconducting magnetic energy storage (SMES) structural and cryogenic requirements was made. Concepts and computational methods have been developed for all of the major problems in these areas. Design analyses have been made to provide more detailed information on some items and experimental work has been performed to create data bases in the areas of superfluid heat transfer, superfluid dielectric properties, heat transfer from conductors, and in the thermal and mechanical properties of materials at low temperatures. In most cases optimum solutions have not been made because of the developing nature of the overall study but methodology for optimization has been worked out for essentially all SMES cryogenic and structural elements. The selection of 1.8 K cooling and all aluminum systems in bedrock continues to be the best choice

Preparation and performance of manganese-oxide-coated zeolite for the removal of manganese-contamination in groundwater.

Science.gov (United States)

Lyu, Cong; Yang, Xuejiao; Zhang, Shengyu; Zhang, Qihui; Su, Xiaosi

2017-12-29

A promising and easily prepared catalytic filler media, manganese-oxide-coated zeolite (MOCZ), for the removal of Mn (II) contamination in groundwater was studied. The optimal condition for MOCZ preparation was given as follows: acid activation of zeolite with 5% HCl mass percent for 12 h, then soaking of acid-activated zeolite with 7% KMnO 4 mass percent for 8 h, and finally calcination at 300°C for 5 h. Acid activation significantly enlarged the specific surface area of the zeolite (>79 m 2  g -1 ), subsequently enhancing the coating of manganese oxides onto the surface of the zeolite. This was further supported by the manganese-to-zeolite ratio (γ Mn ) and Energy dispersive analysis-mapping. The γ Mn was over 12.26 mg Mn g -1 zeolite, representing more active sites for the adsorption and catalytic-oxidation of Mn (II). As such, great performance of Mn (II) removal by MOCZ was obtained in the filter experiment. An estimated 98-100% removal efficiency of Mn (II) was achieved in a greatly short startup time (only 2 h). During the filtration process, newborn flocculent manganese oxides with a mixed-valence of manganese (Mn (II) and Mn (IV)) were generated on the MOCZ surface, further facilitating the adsorption and catalytic-oxidation of Mn (II). The filter with MOCZ as adsorbent had a great performance on the Mn (II) removal in a wide range of hydraulic retention time (HRT) (4-40 min), particularly in a short HRT. Besides, the filter prolonged the filtration period (60 days), which would significantly reduce the frequency of backwash. Thus, it could be concluded that MOCZ prepared in this study showed a good performance in terms of Mn (II) removal in waterworks, especially small waterworks in the villages/towns.

Cryogenic system for TRISTAN superconducting RF cavity

International Nuclear Information System (INIS)

Hosoyama, K.; Hara, K.; Kabe, A.; Kojima, Yuuji; Ogitsu, T.; Sakamoto, Y.; Kawamura, S.; Ishimaru, Y.

1990-01-01

A cryogenic system consisting of a helium refrigerator (4 kW at 4.4 K) and a liquid helium distribution transfer system for TRISTAN 508 MHz 32 x 5-cell superconducting RF cavities was designed and constructed. After the performance test of the cryogenic system, 16 x 5-cell superconducting RF cavities in 8 cryostats were installed in underground TRISTAN electron-positron collider and connected to the helium refrigerator on the ground level through the transfer line (total length about 330 m) and cooled by liquid helium pool boiling in parallel. The cryogenic system and its operation experience are described. (author)

A Piezoelectric Cryogenic Heat Switch

Science.gov (United States)

Jahromi, Amir E.; Sullivan, Dan F.

2014-01-01

We have measured the thermal conductance of a mechanical heat switch actuated by a piezoelectric positioner, the PZHS (PieZo electric Heat Switch), at cryogenic temperatures. The thermal conductance of the PZHS was measured between 4 K and 10 K, and on/off conductance ratios greater than 100 were achieved when the positioner applied its maximum force of 8 N. We discuss the advantages of using this system in cryogenic applications, and estimate the ultimate performance of an optimized PZHS.

Manganese Sesquioxide as Cathode Material for Multivalent Zinc Ion Battery with High Capacity and Long Cycle Life

International Nuclear Information System (INIS)

Jiang, Baozheng; Xu, Chengjun; Wu, Changle; Dong, Liubing; Li, Jia; Kang, Feiyu

2017-01-01

Highlights: • Manganese oxides with Mn(III) state is firstly reported to store zinc ion. • Zinc ion battery with α-Mn 2 O 3 cathode is assembled. • Storage mechanism of zinc ion in α-Mn 2 O 3 is investigated. - Abstract: Rechargeable zinc ion battery is considered as one of the most potential energy storage devices for large-scale energy storage system due to its safety, low-cost, high capacity and nontoxicity. However, only a few cathode materials have been studied for rechargeable zinc ion batteries. Here, we firstly report manganese sesquioxide (Mn 2 O 3 ) with Mn(III) state as cathode material for rechargeable zinc ion battery. The α-Mn 2 O 3 cathode displays a reversible capacity of 148 mAh g −1 , which is relatively high among all the reported cathode materials for ZIB. The cathode also exhibits good rate capability and excellent cycling stability with a long cycle life up to 2000 times. The ion storage mechanism of α-Mn 2 O 3 in zinc ion battery was also revealed. The pristine α-Mn 2 O 3 undergoes a reversible phase transition from bixbyite structure to layered-type zinc birnessite during the electrochemical zinc ion insertion and extraction. The results not only benefit for the practical application of rechargeable zinc ion battery, but also broaden the horizons of understanding the electrochemical behavior and mechanism of rechargeable zinc ion batteries.

Explosive Evaporating Phenomena of Cryogenic Fluids by Direct Contacting Normal Temperature Fluids

Directory of Open Access Journals (Sweden)

T Watanabe

2016-09-01

Full Text Available Cryogenic fluids have characteristics such as thermal stratification and flashing by pressure release in storage vessel. The mixture of the extreme low temperature fluid and the normal temperature fluid becomes the cause which causes pressure vessel and piping system crush due to explosive boiling and rapid freezing. In recent years in Japan, the demand of cryogenic fluids like a LH2, LNG is increasing because of the advance of fuel cell device technology, hydrogen of engine, and stream of consciousness for environmental agreement. These fuel liquids are cryogenic fluids. On the other hand, as for fisheries as well, the use of a source of energy that environment load is small has been being a pressing need. And, the need of the ice is high, as before, for keeping freshness of marine products in fisheries. Therefore, we carried out the experiments related to promotion of evaporating cryogenic fluids and generation of ice, in the contact directly of the water and liquid nitrogen. From the results of visualization, phenomena of explosive evaporating and ice forming were observed by using video camera.

Flextensional Microactuators for Large-Aperture Lightweight Cryogenic Deformable Mirrors, Phase I

Data.gov (United States)

National Aeronautics and Space Administration — TRS Technologies proposes large stroke and high precision single crystal flextensional piezoelectric microactuators for cryogenic optic devices such as large...

Manganese and acute paranoid psychosis: a case report

NARCIS (Netherlands)

Verhoeven, W.M.A.; Egger, J.I.M.; Kuijpers, H.J.H.

2011-01-01

Introduction Manganese regulates many enzymes and is essential for normal development and body function. Chronic manganese intoxication has an insidious and progressive course and usually starts with complaints of headache, fatigue, sleep disturbances, irritability and emotional instability. Later,

Cryogenic cooling of x-ray crystals using porous matrix

International Nuclear Information System (INIS)

Kuzay, T.M.

1991-01-01

It is well established that Si and SiC have very desirable thermophysical properties at cryogenic temperatures. This feature makes cryo-cooled optics potentially a good candidate for the first optical crystal of the presently built third generation synchrotron machines with very high heat flux levels. Currently, there is a great deal of interest in such cryo-cooled crystals pursued both experimentally and analytically. The analytical studies involve cut micro or capillary channel crystals. As opposed to the machined channels, porous matrices provide significant advantages. They operate very quietly. Such matrices are known to affect superior heat transfer enhancement. Data available in open literature suggest that surface heat flux levels up to ∼8 kW/cm 2 are possible. For cryogens for which the boiling heat transfer heat flux is rather a low value in conventional geometries, the enhancement available with such matrices is a very significant characteristic. Cryogens are poor thermal conductors themselves. The fact that at the cryogenic temperatures the Si and/or SiC matrix itself becomes highly conductive, the matrix distributes the surface heat flux into the full volume effectively offsetting the poor conductivity of the coolant. In addition the tortuous path of the coolant through the matrix increases the dwell time for better heat transfer, however, at the expense of increased pressure drop. In this study, thermal conductivity of such composite matrices and the effective heat transfer coefficient obtainable using them are investigated. A first optics crystal model of Si with Si and/or Sic porous matrix as its heat exchanger and subject to prototype synchrotron level heat flux is analyzed and limits of the cooling possible with liquid nitrogen in single phase and subcooled boiling heat transfer modes are delineated

Use of PROFIBUS for cryogenic instrumentation at XFEL

Science.gov (United States)

Boeckmann, T.; Bolte, J.; Bozhko, Y.; Clausen, M.; Escherich, K.; Korth, O.; Penning, J.; Rickens, H.; Schnautz, T.; Schoeneburg, B.; Zhirnov, A.

2017-12-01

The European X-ray Free Electron Laser (XFEL) is a research facility and since December 2016 under commissioning at DESY in Hamburg. The XFEL superconducting accelerator is 1.5 km long and contains 96 superconducting accelerator modules. The control system EPICS (Experimental Physics and Industrial Control System) is used to control and operate the XFEL cryogenic system consisting of the XFEL refrigerator, cryogenic distribution systems and the XFEL accelerator. The PROFIBUS fieldbus technology is the key technology of the cryogenic instrumentation and the link to the control system. More than 650 PROFIBUS nodes are implemented in the different parts of the XFEL cryogenic facilities. The presentation will give an overview of PROFIBUS installation in these facilities regarding engineering, possibilities of diagnostics, commissioning and the first operating experience.

High-accuracy X-ray detector calibration based on cryogenic radiometry

Science.gov (United States)

Krumrey, M.; Cibik, L.; Müller, P.

2010-06-01

Cryogenic electrical substitution radiometers (ESRs) are absolute thermal detectors, based on the equivalence of electrical power and radiant power. Their core piece is a cavity absorber, which is typically made of copper to achieve a short response time. At higher photon energies, the use of copper prevents the operation of ESRs due to increasing transmittance. A new absorber design for hard X-rays has been developed at the laboratory of the Physikalisch-Technische Bundesanstalt (PTB) at the electron storage ring BESSY II. The Monte Carlo simulation code Geant4 was applied to optimize its absorptance for photon energies of up to 60 keV. The measurement of the radiant power of monochromatized synchrotron radiation was achieved with relative standard uncertainties of less than 0.2 %, covering the entire photon energy range of three beamlines from 50 eV to 60 keV. Monochromatized synchrotron radiation of high spectral purity is used to calibrate silicon photodiodes against the ESR for photon energies up to 60 keV with relative standard uncertainties below 0.3 %. For some silicon photodiodes, the photocurrent is not linear with the incident radiant power.

High-accuracy X-ray detector calibration based on cryogenic radiometry

International Nuclear Information System (INIS)

Krumrey, M.; Cibik, L.; Mueller, P.

2010-01-01

Cryogenic electrical substitution radiometers (ESRs) are absolute thermal detectors, based on the equivalence of electrical power and radiant power. Their core piece is a cavity absorber, which is typically made of copper to achieve a short response time. At higher photon energies, the use of copper prevents the operation of ESRs due to increasing transmittance. A new absorber design for hard X-rays has been developed at the laboratory of the Physikalisch-Technische Bundesanstalt (PTB) at the electron storage ring BESSY II. The Monte Carlo simulation code Geant4 was applied to optimize its absorptance for photon energies of up to 60 keV. The measurement of the radiant power of monochromatized synchrotron radiation was achieved with relative standard uncertainties of less than 0.2 %, covering the entire photon energy range of three beamlines from 50 eV to 60 keV. Monochromatized synchrotron radiation of high spectral purity is used to calibrate silicon photodiodes against the ESR for photon energies up to 60 keV with relative standard uncertainties below 0.3 %. For some silicon photodiodes, the photocurrent is not linear with the incident radiant power.

In-Space Cryogenic VOST Connect/Disconnect, Phase II

Data.gov (United States)

National Aeronautics and Space Administration — Two novel cryogenic couplings will be designed, fabricated and tested. Intended for in-space use at cryogenic propellant depots, the couplings are based on patented...

Cryogenic safety organisation at CERN

CERN Multimedia

CERN. Geneva

2016-01-01

With Safety being a top priority of CERN’s general policy, the Organisation defines and implements a Policy that sets out the general principles governing Safety at CERN. To the end of the attainment of said Safety objectives, the organic units (owners/users of the equipment) are assigned the responsibility for the implementation of the CERN Safety Policy at all levels of the organization, whereas the Health and Safety and Environmental Protection Unit (HSE) has the role of providing assistance for the implementation of the Safety Policy, and a monitoring role related to the implementation of continuous improvement of Safety, compliance with the Safety Rules and the handling of emergency situations. This talk will elaborate on the roles, responsibilities and organisational structure of the different stakeholders within the Organization with regards to Safety, and in particular to cryogenic safety. The roles of actors of particular importance such as the Cryogenic Safety Officers (CSOs) and the Cryogenic Sa...

Cryogenic Fuel Tank Draining Analysis Model

Science.gov (United States)

Greer, Donald

1999-01-01

One of the technological challenges in designing advanced hypersonic aircraft and the next generation of spacecraft is developing reusable flight-weight cryogenic fuel tanks. As an aid in the design and analysis of these cryogenic tanks, a computational fluid dynamics (CFD) model has been developed specifically for the analysis of flow in a cryogenic fuel tank. This model employs the full set of Navier-Stokes equations, except that viscous dissipation is neglected in the energy equation. An explicit finite difference technique in two-dimensional generalized coordinates, approximated to second-order accuracy in both space and time is used. The stiffness resulting from the low Mach number is resolved by using artificial compressibility. The model simulates the transient, two-dimensional draining of a fuel tank cross section. To calculate the slosh wave dynamics the interface between the ullage gas and liquid fuel is modeled as a free surface. Then, experimental data for free convection inside a horizontal cylinder are compared with model results. Finally, cryogenic tank draining calculations are performed with three different wall heat fluxes to demonstrate the effect of wall heat flux on the internal tank flow field.

Properties of strain gages at cryogenic temperature

International Nuclear Information System (INIS)

Shibata, Nobuo; Fujiyoshi, Toshimitsu.

1978-01-01

At the time of developing superconduction generators, the stress measurement for rotor parts is required to grasp the safety and performance of the rotor at cryogenic temperature, which is cooled with liquid helium. In case of carrying out the stress measurement with strain gages, the problems are as follows. The strain gages and lead wires are exposed to cryogenic temperature from 4 to 10 K and strong magnetic field of about 3T, and subjected to high centrifugal acceleration of about 500G. In order to establish the techniques of the stress measurement under such conditions, the adhesives and damp-proof coatings for strain gages and strain gages themselves in Japan and foreign countries were examined on the properties at cryogenic temperature. As for the properties of strain gages, mainly the apparent strain owing to temperature change was investigated, and the change of the gage factors was studies only at liquid nitrogen temperature. The stress measurement with strain gages at low temperature had been studied in detail down to liquid nitrogen temperature concerning LNG tanks. The experimental apparatus, the samples, the testing methods and the test results of cooling tests on adhesives and damp-proof coatings, and the temperature characteristics of strain gages are reported. The usable adhesives and coatings were found, and correction by accurate temperature measurement is required for apparent strain. (Kako, I.)

A cryogenic axial-centrifugal compressor for superfluid helium refrigeration

CERN Document Server

Decker, L; Schustr, P; Vins, M; Brunovsky, I; Lebrun, P; Tavian, L

1997-01-01

CERN's new project, the Large Hadron Collider (LHC), will use superfluid helium as coolant for its high-field superconducting magnets and therefore require large capacity refrigeration at 1.8 K. This may only be achieved by subatmospheric compression of gaseous helium at cryogenic temperature. To stimulate development of this technology, CERN has procured from industry prototype Cold Compressor Units (CCU). This unit is based on a cryogenic axial-centrifugal compressor, running on ceramic ball bearings and driven by a variable-frequency electrical motor operating under low-pressure helium at ambient temperature. The machine has been commissioned and is now in operation. After describing basic constructional features of the compressor, we report on measured performance.

Manganese in the litter fall-forest floor continuum of boreal and temperate pine and spruce forest ecosystems

DEFF Research Database (Denmark)

Berg, Björn; Erhagen, Björn; Johansson, Maj-Britt

2015-01-01

We have reviewed the literature on the role of manganese (Mn) in the litter fall-to-humus subsystem. Available data gives a focus on North European coniferous forests. Manganese concentrations in pine (Pinus spp.) foliar litter are highly variable both spatially and temporally within the same lit...

Cooling pipeline disposing structure for large-scaled cryogenic structure

International Nuclear Information System (INIS)

Takahashi, Hiroyuki.

1996-01-01

The present invention concerns an electromagnetic force supporting structure for superconductive coils. As the size of a cryogenic structure is increased, since it takes much cooling time, temperature difference between cooling pipelines and the cryogenic structure is increased over a wide range, and difference of heat shrinkage is increased to increase thermal stresses. Then, in the cooling pipelines for a large scaled cryogenic structure, the cooling pipelines and the structure are connected by way of a thin metal plate made of a material having a heat conductivity higher than that of the material of the structure by one digit or more, and the thin metal plate is bent. The displacement between the cryogenic structure and the cooling pipelines caused by heat shrinkage is absorbed by the elongation/shrinkage of the bent structure of the thin metal plate, and the thermal stresses due to the displacement is reduced. In addition, the heat of the cryogenic structures is transferred by way of the thin metal plate. Then, the cooling pipelines can be secured to the cryogenic structure such that cooling by heat transfer is enabled by absorbing a great deviation or three dimensional displacement due to the difference of the temperature distribution between the cryogenic structure enlarged in the scale and put into the three dimensional shape, and the cooling pipelines. (N.H.)

Measurement of high-pressure shock waves in cryogenic deuterium-tritium ice layered capsule implosions on NIF.

Science.gov (United States)

Robey, H F; Moody, J D; Celliers, P M; Ross, J S; Ralph, J; Le Pape, S; Berzak Hopkins, L; Parham, T; Sater, J; Mapoles, E R; Holunga, D M; Walters, C F; Haid, B J; Kozioziemski, B J; Dylla-Spears, R J; Krauter, K G; Frieders, G; Ross, G; Bowers, M W; Strozzi, D J; Yoxall, B E; Hamza, A V; Dzenitis, B; Bhandarkar, S D; Young, B; Van Wonterghem, B M; Atherton, L J; Landen, O L; Edwards, M J; Boehly, T R

2013-08-09

The first measurements of multiple, high-pressure shock waves in cryogenic deuterium-tritium (DT) ice layered capsule implosions on the National Ignition Facility have been performed. The strength and relative timing of these shocks must be adjusted to very high precision in order to keep the DT fuel entropy low and compressibility high. All previous measurements of shock timing in inertial confinement fusion implosions [T. R. Boehly et al., Phys. Rev. Lett. 106, 195005 (2011), H. F. Robey et al., Phys. Rev. Lett. 108, 215004 (2012)] have been performed in surrogate targets, where the solid DT ice shell and central DT gas regions were replaced with a continuous liquid deuterium (D2) fill. This report presents the first experimental validation of the assumptions underlying this surrogate technique.

Neutron detection with cryogenics and semiconductors

International Nuclear Information System (INIS)

Bell, Zane W.; Carpenter, D.A.; Cristy, S.S.; Lamberti, V.E.; Burger, Arnold; Woodfield, Brian F.; Niedermayr, Thomas; Dragos Hau, I.; Labov, Simon E.; Friedrich, Stephan; Geoffrey West, W.; Pohl, Kenneth R.; Berg, Lodewijk van den

2005-01-01

The common methods of neutron detection are reviewed with special attention paid to the application of cryogenics and semiconductors to the problem. The authors' work with LiF- and boron-based cryogenic instruments is described as well as the use of CdTe and HgI 2 for direct detection of neutrons. (copyright 2005 WILEY-VCH Verlag GmbH and Co. KGaA, Weinheim) (orig.)

Manganese-Enhanced MRI for Preclinical Evaluation of Retinal Degeneration Treatments.

Science.gov (United States)

Schur, Rebecca M; Sheng, Li; Sahu, Bhubanananda; Yu, Guanping; Gao, Songqi; Yu, Xin; Maeda, Akiko; Palczewski, Krzysztof; Lu, Zheng-Rong

2015-07-01

Apply manganese-enhanced magnetic resonance imaging (MEMRI) to assess ion channel activity and structure of retinas from mice subject to light-induced retinal degeneration treated with prophylactic agents. Abca4(-/-)Rdh8(-/-) double knockout mice with and without prophylactic retinylamine (Ret-NH2) treatment were illuminated with strong light. Manganese-enhanced MRI was used to image the retina 2 hours after intravitreous injection of MnCl2 into one eye. Contrast-enhanced MRIs of the retina and vitreous humor in each experimental group were assessed and correlated with the treatment. Findings were compared with standard structural and functional assessments of the retina by optical coherence tomography (OCT), histology, and electroretinography (ERG). Manganese-enhanced MRI contrast in the retina was high in nonilluminated and illuminated Ret-NH2-treated mice, whereas no enhancement was evident in the retina of the light-illuminated mice without Ret-NH2 treatment (P treatment based on the measurement of ion channel activity. This approach could be used as a complementary tool in preclinical development of new prophylactic therapies for retinopathies.

Iron and manganese removal from drinking water

OpenAIRE

Pascu, Daniela-Elena; Neagu (Pascu), Mihaela; Alina Traistaru, Gina; Nechifor, Aurelia Cristina; Raluca Miron, Alexandra

2016-01-01

The purpose of the present study is to find a suitable method for removal of iron and manganese from ground water, considering both local economical and environmental aspects. Ground water is a highly important source of drinking water in Romania. Ground water is naturally pure from bacteria at a 25 m depth or more. However, solved metals may occur and if the levels are too high, the water is not drinkable. Different processes, such as electrochemical and combined electrochemical-adsorption m...

High-performance binder-free supercapacitor electrode by direct growth of cobalt-manganese composite oxide nansostructures on nickel foam

OpenAIRE

Jiang, Shulan; Shi, Tielin; Long, Hu; Sun, Yongming; Zhou, Wei; Tang, Zirong

2014-01-01

A facile approach composed of hydrothermal process and annealing treatment is proposed to directly grow cobalt-manganese composite oxide ((Co,Mn)3O4) nanostructures on three-dimensional (3D) conductive nickel (Ni) foam for a supercapacitor electrode. The as-fabricated porous electrode exhibits excellent rate capability and high specific capacitance of 840.2 F g-1 at the current density of 10 A g-1, and the electrode also shows excellent cycling performance, which retains 102% of its initial d...

Gold, iron and manganese in central Amapá, Brazil

Directory of Open Access Journals (Sweden)

Wilson Scarpelli

Full Text Available ABSTRACT: Greenstone belts with deposits of gold, iron and manganese are common in the Paleoproterozoic Maroni-Itacaiunas Tectonic Province of the Guiana Shield. In Brazil, in the State of Amapá and northwest of Pará, they are represented by the Vila Nova Group, constituted by a basal unit of metabasalts, covered by metasediments of clastic and chemical origin. The basal metasediments, the Serra do Navio Formation, are made of a cyclothem with lenses of manganese marbles at the top of each cycle. Under the intense weathering of the Amazon, these lenses were oxidized to large deposits of high-grade manganese oxides. The exploitation of these oxides left behind the manganese carbonates and low-grade oxides. The overlaying Serra da Canga Formation presents a calcium and magnesium domain grading to an iron domain with banded silicate and oxide iron formations, mined for iron ores. Overlapping structures and superposed metamorphic crystallizations indicate two phases of dynamothermal metamorphism, the first one with axis to north-northeast and the second one to northwest, with an intermediate phase of thermal metamorphism related to syntectonic granitic intrusions. Shears oriented north-south, possibly formed during the first dynamothermal metamorphism and reactivated in the second, are ideal sites for hydrothermalism and gold mineralization, which is greater when occurs in iron formation and carbonate-bearing rocks, as it happened at the Tucano mine. Layered mafic-ultramafic intrusions in the greenstones represent a potential for chromite and platinum group elements. Pegmatites are source of cassiterite and tantalite exploited from alluvial deposits.

Cryogenic fluid management program flight concept definition

Science.gov (United States)

Kroeger, Erich

1987-01-01

The Lewis Research Center's cryogenic fluid management program flight concept definition is presented in viewgraph form. Diagrams are given of the cryogenic fluid management subpallet and its configuration with the Delta launch vehicle. Information is given in outline form on feasibility studies, requirements definition, and flight experiments design.

Engineered Surface Properties of Porous Tungsten from Cryogenic Machining

Science.gov (United States)

Schoop, Julius Malte

Porous tungsten is used to manufacture dispenser cathodes due to it refractory properties. Surface porosity is critical to functional performance of dispenser cathodes because it allows for an impregnated ceramic compound to migrate to the emitting surface, lowering its work function. Likewise, surface roughness is important because it is necessary to ensure uniform wetting of the molten impregnate during high temperature service. Current industry practice to achieve surface roughness and surface porosity requirements involves the use of a plastic infiltrant during machining. After machining, the infiltrant is baked and the cathode pellet is impregnated. In this context, cryogenic machining is investigated as a substitutionary process for the current plastic infiltration process. Along with significant reductions in cycle time and resource use, surface quality of cryogenically machined un-infiltrated (as-sintered) porous tungsten has been shown to significantly outperform dry machining. The present study is focused on examining the relationship between machining parameters and cooling condition on the as-machined surface integrity of porous tungsten. The effects of cryogenic pre-cooling, rake angle, cutting speed, depth of cut and feed are all taken into consideration with respect to machining-induced surface morphology. Cermet and Polycrystalline diamond (PCD) cutting tools are used to develop high performance cryogenic machining of porous tungsten. Dry and pre-heated machining were investigated as a means to allow for ductile mode machining, yet severe tool-wear and undesirable smearing limited the feasibility of these approaches. By using modified PCD cutting tools, high speed machining of porous tungsten at cutting speeds up to 400 m/min is achieved for the first time. Beyond a critical speed, brittle fracture and built-up edge are eliminated as the result of a brittle to ductile transition. A model of critical chip thickness ( hc ) effects based on cutting

Modified-Collins cryocooler for zero-boiloff storage of cryogenic fuels in space

Science.gov (United States)

Hannon, Charles L.; Krass, Brady; Hogan, Jake; Brisson, John

2012-06-01

Future lunar and planetary explorations will require the storage of cryogenic propellants, particularly liquid oxygen (LOX) and liquid hydrogen (LH2), in low earth orbit (LEO) for periods of time ranging from days to months, and possibly longer. Without careful thermal management, significant quantities of stored liquid cryogens can be lost due to boil-off. Boil-off can be minimized by a variety of passive means including insulation, sun shades and passive radiational cooling. However, it has been shown that active cooling using space cryocoolers has the potential to result in Zero Boil-Off (ZBO) and the launch-mass savings using active cooling exceeds that of passive cooling of LOX for mission durations in LEO of less than 1 week, and for LH2 after about 2 months in LEO. Large-scale DC-flow cryogenic refrigeration systems operate at a fraction of the specific power levels required by small-scale AC-flow cryocoolers. The efficiency advantage of DC-flow cryogenic cycles motivates the current development of a cryocooler based on a modification of the Collins Cycle. The modified Collins cycle design employs piston type expanders that support high operating pressure ratios, electromagnetic valves that enable "floating pistons", and recuperative heat transfer. This paper will describe the design of a prototype Modified-Collins cryocooler for ZBO storage of cryogenic fuels in space.

Cryogenics system: strategy to achieve nominal performance and reliable operation

International Nuclear Information System (INIS)

Bremer, J.; Brodzinski, K.; Casas, J.; Claudet, S.; Delikaris, D.; Delruelle, N.; Ferlin, G.; Fluder, C.; Perin, A.; Perinic, G.; Pezzetti, M.; Pirotte, O.; Tavian, L.; Wagner, U.

2012-01-01

During the LHC operation in 2010 and 2011, the cryogenic system has achieved an availability level fulfilling the overall requirement. To reach this level, the cryogenic system has profited like many other beam-dependent systems from the reduced beam parameters. Therefore, impacts of some failures occurred during the LHC operation were mitigated by using the over-capacity margin, the existing built-in redundancy in between adjacent sector cryogenic plants and the 'cannibalization' of spares on two idle cryogenic plants. These two first years of operation were also crucial to identify the weaknesses of the present cryogenic maintenance plan and new issues like SEUs. After the LS1, nominal beam parameters are expected and the mitigated measures will be less effective or not applicable at all. Consequently, a consolidation plan to improve the MTBF and the MTTR of the LHC cryogenic system is under definition. Concerning shutdown periods, the present cryogenic sectorization imposes some restrictions in the type of interventions (e.g. cryo-magnet removal) which can be done without affecting the operating conditions of the adjacent sector. This creates additional constrains and possible extra down-time in the schedule of the shutdowns including the hardware commissioning. This presentation focuses on the consolidation plan foreseen during the LS1 to improve the performance of the LHC cryogenic system in terms of availability and sectorization. (authors)

Instrumentation, Field Network and Process Automation for the Cryogenic System of the LHC Test String

CERN Document Server

Suraci, A; Balle, C; Blanco-Viñuela, E; Casas-Cubillos, J; Gomes, P; Pelletier, S; Serio, L; Vauthier, N; Balle, Ch.

2001-01-01

CERN is now setting up String 2, a full-size prototype of a regular cell of the LHC arc. It is composed of two quadrupole, six dipole magnets, and a separate cryogenic distribution line (QRL) for the supply and recovery of the cryogen. An electrical feed box (DFB), with up to 38 High Temperature Superconducting (HTS) leads, powers the magnets. About 700 sensors and actuators are distributed along four Profibus DP and two Profibus PA field buses. The process automation is handled by two controllers, running 126 Closed Control Loops (CCL). This paper describes the cryogenic control system, associated instrumentation, and their commissioning.

Mechanical Tensile Testing of Titanium 15-3-3-3 and Kevlar 49 at Cryogenic Temperatures

Science.gov (United States)

James, Bryan L.; Martinez, Raul M.; Shirron, Peter; Tuttle, Jim; Galassi, Nicholas M.; Mcguinness, Daniel S.; Puckett, David; Francis, John J.; Flom, Yury

2011-01-01

Titanium 15-3-3-3 and Kevlar 49 are highly desired materials for structural components in cryogenic applications due to their low thennal conductivity at low temperatures. Previous tests have indicated that titanium 15-3-3-3 becomes increasingly brittle as the temperature decreases. Furthermore, little is known regarding the mechanical properties of Kevlar 49 at low temperatures, most specifically its Young's modulus. This testing investigates the mechanical properties of both materials at cryogenic temperatures through cryogenic mechanical tensile testing to failure. The elongation, ultimate tensile strength, yield strength, and break strength of both materials are provided and analyzed here.

Imaging of High-Energy X-Ray Emission from Cryogenic Thermonuclear Fuel Implosions on the NIF

International Nuclear Information System (INIS)

Ma, T.

2012-01-01

Accurately assessing and optimizing the implosion performance of inertial confinement fusion capsules is a crucial step to achieving ignition on the NIF. We have applied differential filtering (matched Ross filter pairs) to provide spectrally resolved time-integrated absolute x-ray self-emission images of the imploded core of cryogenic layered targets. Using bremsstrahlung assumptions, the measured absolute x-ray brightness allows for the inference of electron temperature, electron density, hot spot mass, mix mass, and pressure. Current inertial confinement fusion (ICF) experiments conducted on the National Ignition Facility (NIF) seek to indirectly drive a spherical implosion, compressing and igniting a deuterium-tritium fuel. This DT fuel capsule is cryogenically prepared as a solid ice layer surrounded by a low-Z ablator material. Ignition will occur when the hot spot approaches sufficient temperature (∼3-4 keV) and ρR (∼0.3 g/cm 2 ) such that alpha deposition can further heat the hot spot and generate a self-sustaining burn wave. During the implosion, the fuel mass becomes hot enough to emit large amounts of x-ray radiation, the spectra and spatial variation of which contains key information that can be used to evaluate the implosion performance. The Ross filter diagnostic employs differential filtering to provide spectrally resolved, time-integrated, absolute x-ray self-emission images of the imploded core of cryogenic layered targets.

High-Performance Cryogenic Designs for OMEGA and the National Ignition Facility

Science.gov (United States)

Goncharov, V. N.; Collins, T. J. B.; Marozas, J. A.; Regan, S. P.; Betti, R.; Boehly, T. R.; Campbell, E. M.; Froula, D. H.; Igumenshchev, I. V.; McCrory, R. L.; Myatt, J. F.; Radha, P. B.; Sangster, T. C.; Shvydky, A.

2016-10-01

The main advantage of laser symmetric direct drive (SDD) is a significantly higher coupled drive laser energy to the hot-spot internal energy at stagnation compared to that of laser indirect drive. Because of coupling losses resulting from cross-beam energy transfer (CBET), however, reaching ignition conditions on the NIF with SDD requires designs with excessively large in-flight aspect ratios ( 30). Results of cryogenic implosions performed on OMEGA show that such designs are unstable to short-scale nonuniformity growth during shell implosion. Several CBET reduction strategies have been proposed in the past. This talk will discuss high-performing designs using several CBET-mitigation techniques, including using drive laser beams smaller than the target size and wavelength detuning. Designs that are predicted to reach alpha burning regimes as well as a gain of 10 to 40 at the NIF-scale will be presented. Hydrodynamically scaled OMEGA designs with similar CBET-reduction techniques will also be discussed. This material is based upon work supported by the Department Of Energy National Nuclear Security Administration under Award Number DE-NA0001944.

Cryogenic refractive index of Heraeus homosil glass

Science.gov (United States)

Miller, Kevin H.; Quijada, Manuel A.; Leviton, Douglas B.

2017-08-01

This paper reports measurements of the refractive index of Homosil (Heraeus) over the wavelength range of 0.34—3.16 μm and temperature range of 120—335 K. These measurements were performed by using the Cryogenic High Accuracy Refraction Measuring System (CHARMS) facility at the NASA's Goddard Space Flight Center. These measurements were in support of an integrated Structural-Thermal-Optical-Performance (STOP) model that was developed for a fieldwidened Michelson interferometer that is being built and tested for the High Spectral Resolution Lidar (HSRL) project at the NASA Langley Research Center (LaRC). The cryogenic refractive index measurements were required in order to account for the highly sensitive performance of the HSRL instrument to changes in refractive index with temperature, temperature gradients, thermal expansion, and deformation due to mounting stresses. A dense coverage of the absolute refractive index over the aforementioned wavelength and temperature ranges was used to determine the thermo-optic coefficient (dn/dT) and dispersion relation (dn/dλ) as a function of wavelength and temperature. Our measurements of Homosil will be compared with measurements of other glasses from the fused silica family studied in CHARMS as well as measurements reported elsewhere in the literature.

Gastroprotective Properties of Manganese Chloride on Acetic Acid

African Journals Online (AJOL)

Dr Olaleye

Drugs with multiple mechanisms of protective action may be effective in minimizing ... that Manganese had dose and treatment duration dependent effect on healing of ulcerated stomach. .... The stomach was bathed with normal saline ..... Arnaud, J., and Favier, A. (1995): "Copper, iron, manganese ... Experimental Toxic.

Method and apparatus for conducting structural health monitoring in a cryogenic, high vibration environment

Science.gov (United States)

Qing, Xinlin (Inventor); Beard, Shawn J. (Inventor); Li, Irene (Inventor)

2013-01-01

Sensors affixed to various such structures, where the sensors can withstand, remain affixed, and operate while undergoing both cryogenic temperatures and high vibrations. In particular, piezoelectric single crystal transducers are utilized, and these sensors are coupled to the structure via a low temperature, heat cured epoxy. This allows the transducers to monitor the structure while the engine is operating, even despite the harsh operating conditions. Aspects of the invention thus allow for real time monitoring and analysis of structures that operate in conditions that previously did not permit such analysis. A further aspect of the invention relates to use of piezoelectric single crystal transducers. In particular, use of such transducers allows the same elements to be used as both sensors and actuators.

A Cryogenic Magnetostrictive Actuator Using a Persistent High Temperature Superconducting Magnet. Part 1; Concept and Design

Science.gov (United States)

Horner, Garnett; Bromberg, Leslie; Teter, J. P.

2000-01-01

Cryogenic magnetostrictive materials, such as rare earth zinc crystals, offer high strains and high forces with minimally applied magnetic fields, making the material ideally suited for deformable optics applications. For cryogenic temperature applications the use of superconducting magnets offer the possibility of a persistent mode of operation, i.e., the magnetostrictive material will maintain a strain field without power. High temperature superconductors (HTS) are attractive options if the temperature of operation is higher than 10 degrees Kelvin (K) and below 77 K. However, HTS wires have constraints that limit the minimum radius of winding, and even if good wires can be produced, the technology for joining superconducting wires does not exist. In this paper, the design and capabilities of a rare earth zinc magnetostrictive actuator using bulk HTS is described. Bulk superconductors can be fabricated in the sizes required with excellent superconducting properties. Equivalent permanent magnets, made with this inexpensive material, are persistent, do not require a persistent switch as in HTS wires, and can be made very small. These devices are charged using a technique which is similar to the one used for charging permanent magnets, e.g., by driving them into saturation. A small normal conducting coil can be used for charging or discharging. Because of the magnetic field capability of the superconductor material, a very small amount of superconducting magnet material is needed to actuate the rare earth zinc. In this paper, several designs of actuators using YBCO and BSCCO 2212 superconducting materials are presented. Designs that include magnetic shielding to prevent interaction between adjacent actuators will also be described. Preliminary experimental results and comparison with theory for BSCCO 2212 with a magnetostrictive element will be discussed.

Silver manganese oxide electrodes for lithium batteries

Science.gov (United States)

Thackeray, Michael M.; Vaughey, John T.; Dees, Dennis W.

2006-05-09

This invention relates to electrodes for non-aqueous lithium cells and batteries with silver manganese oxide positive electrodes, denoted AgxMnOy, in which x and y are such that the manganese ions in the charged or partially charged electrodes cells have an average oxidation state greater than 3.5. The silver manganese oxide electrodes optionally contain silver powder and/or silver foil to assist in current collection at the electrodes and to improve the power capability of the cells or batteries. The invention relates also to a method for preparing AgxMnOy electrodes by decomposition of a permanganate salt, such as AgMnO4, or by the decomposition of KMnO4 or LiMnO4 in the presence of a silver salt.

Effect of increased manganese addition and mould type on the ...

Indian Academy of Sciences (India)

The wear resistance of high chromium iron is well recorded. However, the same is not the case as regards the use of manganese at higher percentages in high chromium irons and its influence on wear behaviour. Hence, this work highlights the slurry wear characteristics of chromium (□ ◻ 16–19%) iron following the ...

Parametric studies on floating pad journal bearing for high speed cryogenic turboexpanders

Science.gov (United States)

Jain, A.; Jadhav, M. M.; Karimulla, S.; Chakravarty, A.

2017-12-01

Most modern medium and large capacity helium liquefaction/refrigeration plants employ high speed cryogenic turboexpanders in their refrigeration/liquefaction cycles as active cooling devices. The operating speed of these turboexpanders is in the range of 3000-5000 Hz and hence specialized types of bearings are required. Floating pad journal bearing, which is a special type of tilting pad journal bearing, where mechanical pivots are absent and pads are fully suspended in gas, can be a good solution for stable operation of these high speed compact rotors. The pads are separated from shaft as well as from housing by fluid film between them, and both these sides of pad are interconnected by a network of feed holes. The work presented in this article aims to characterize floating pad journal bearings through parametric studies. The steady state performance characteristics of the bearing are represented by load capacity, stiffness coefficients and heat generation rate of the bearing. The geometrical parameters such as bearing clearances, preload of pads, etc. are varied and performance characteristics of the floating pad journal bearing are studied and presented. The dependence of stiffness coefficients on rotational speed of shaft is also analyzed.

Optimisation of thermo mechanical treatments using cryogenic rolling and aging of the high strength aluminium alloy AlZn5.5MgCu (AA7075)

Energy Technology Data Exchange (ETDEWEB)

Hunger, S.; Scholze, M.; Hockauf, M.; Wagner, M.F.X. [Chemnitz University of Technology, Institute of Materials Science and Engineering, Chemnitz (Germany); Fritsch, S.

2011-07-15

In this study, we consider the optimisation of mechanical properties and the microstructure of the high strength and difficult-to-work aluminium alloy AA7075 by cryogenic rolling. In order to reduce the grain size into the (ultra)fine-grained regime, cryogenic rolling is used to introduce different amount of plastic strain. We discuss how rolling at lower temperatures allows the introduction of higher strains on the one hand, and suppresses dynamic recovery and aging effectively on the other hand. Our results demonstrate that, in combination with an appropriate post-processing aging treatment, an outstanding combination of strength and ductility can be achieved. (Copyright copyright 2011 WILEY-VCH Verlag GmbH and Co. KGaA, Weinheim)

Bioconcentration of manganese and iron in Panaeoloideae Sing

NARCIS (Netherlands)

Stijve, T.; Blake, C.

1994-01-01

According to literature, the manganese content of most basidiomycetes fluctuates between 10 and 60 mg/kg, whereas the iron levels range from 100-500 mg/kg (both expressed on dry weight). The present authors report that bioconcentration of manganese is a distinguishing feature of the Panaeoloideae,

High-performance binder-free supercapacitor electrode by direct growth of cobalt-manganese composite oxide nansostructures on nickel foam

Science.gov (United States)

Jiang, Shulan; Shi, Tielin; Long, Hu; Sun, Yongming; Zhou, Wei; Tang, Zirong

2014-09-01

A facile approach composed of hydrothermal process and annealing treatment is proposed to directly grow cobalt-manganese composite oxide ((Co,Mn)3O4) nanostructures on three-dimensional (3D) conductive nickel (Ni) foam for a supercapacitor electrode. The as-fabricated porous electrode exhibits excellent rate capability and high specific capacitance of 840.2 F g-1 at the current density of 10 A g-1, and the electrode also shows excellent cycling performance, which retains 102% of its initial discharge capacitance after 7,000 cycles. The fabricated binder-free hierarchical composite electrode with superior electrochemical performance is a promising candidate for high-performance supercapacitors.

Cryogenic systems for large superconducting accelerators/storage rings

International Nuclear Information System (INIS)

Brown, D.P.

1981-01-01

Particle accelerators and storage rings which utilize superconducting magnets have presented cryogenic system designers, as well as magnet designers, with many new challenges. When such accelerators were first proposed, little operational experience existed to guide the design. Two superconducting accelerators, complete with cryogenic systems, have been designed and are now under construction. These are the Fermilab Doubler Project and the Brookhaven National Laboratory ISABELLE Project. The cryogenic systems which developed at these two laboratories share many common characteristics, especially as compared to earlier cryogenic systems. Because of this commonality, these characteristics can be reasonably taken as also being representative of future systems. There are other areas in which the two systems are dissimilar. In those areas, it is not possible to state which, if either, will be chosen by future designers. Some of the design parameters for the two systems are given

Research of the cold shield in cryogenic liquid storage

Science.gov (United States)

Chen, L. B.; Zheng, J. P.; Wu, X. L.; Cui, C.; Zhou, Y.; Wang, J. J.

2017-12-01

To realize zero boil-off storage of cryogenic liquids, a cryocooler that can achieve a temperature below the boiling point temperature of the cryogenic liquid is generally needed. Taking into account that the efficiency of the cryocooler will be higher at a higher operating temperature, a novel thermal insulation system using a sandwich container filled with cryogenic liquid with a higher boiling point as a cold radiation shield between the cryogenic tank and the vacuum shield in room temperature is proposed to reduce the electricity power consumption. A two-stage cryocooler or two separate cryocoolers are adopted to condense the evaporated gas from the cold shield and the cryogenic tank. The calculation result of a 55 liter liquid hydrogen tank with a liquid nitrogen shield shows that only 14.4 W of electrical power is needed to make all the evaporated gas condensation while 121.7 W will be needed without the liquid nitrogen shield.

Some General Principles in Cryogenic Design, Implementation, and Testing

Science.gov (United States)

Dipirro, Michael James

2015-01-01

Brief Course Description: In 2 hours only the most basic principles of cryogenics can be presented. I will concentrate on the differences between a room temperature thermal analysis and cryogenic thermal analysis, namely temperature dependent properties. I will talk about practical materials for thermal contact and isolation. I will finish by describing the verification process and instrumentation used that is unique to cryogenic (in general less than 100K) systems.

Design of spiral fin type condenser for hydrogen cryogenic distillation column

International Nuclear Information System (INIS)

Iwai, Yasunori; Nishi, Masataka; Yamanishi, Toshihiko

2005-08-01

The purpose of this paper is the proposal of new concept condenser for hydrogen cryogenic distillation column of Hydrogen Isotope Separation System (ISS) in a fusion reactor, and the establishment of numerical evaluation method of the hydrogen isotope inventory in the condenser. A large amount of hydrogen isotopes including high concentration of tritium, radioactive hydrogen isotope, has been handled in the cryogenic distillation column. Therefore, from the safety point of view, cryogenic coolant tube was commonly arranged to surround the condensed area to prevent the mixing of tritium into the coolant. This inevitable arrangement leads the difficulty in the minimization of the condenser. The scale of condenser has influence on the scale of the ISS and its earthquake-resistance. The spiral fin type condenser, which introduces fins inside it and in coolant tube to enhance heat exchange, is proposed as a new concept condenser for hydrogen cryogenic distillation column to miniaturize the condenser. The volume of spiral fin type condenser is estimated to become less than half of that of coil tube type condenser currently in use. Accordingly, it is found that the adoption of spiral fin type condenser realizes the significant miniaturization of the ISS. Moreover, the numerical evaluation method of the hydrogen isotope inventory in the condenser is proposed. The validity of this method was confirmed by the experimental data. The synthetic design of the condenser for the hydrogen cryogenic distillation column is achieved by the combination of the proposed new concept condenser with the numerical evaluation method of the hydrogen isotope inventory. (author)

Spatial mapping of mineralization with manganese-enhanced magnetic resonance imaging

Science.gov (United States)

Chesnick, I.E.; Centeno, J.A.; Todorov, T.I.; Koenig, A.E.; Potter, K.

2011-01-01

Paramagnetic manganese can be employed as a calcium surrogate to sensitize the magnetic resonance imaging (MRI) technique to the processing of calcium during the bone formation process. At low doses, after just 48h of exposure, osteoblasts take up sufficient quantities of manganese to cause marked reductions in the water proton T1 values compared with untreated cells. After just 24h of exposure, 25??M MnCl2 had no significant effect on cell viability. However, for mineralization studies 100??M MnCl2 was used to avoid issues of manganese depletion in calvarial organ cultures and a post-treatment delay of 48h was implemented to ensure that manganese ions taken up by osteoblasts is deposited as mineral. All specimens were identified by their days in vitro (DIV). Using inductively coupled plasma optical emission spectroscopy (ICP-OES), we confirmed that Mn-treated calvariae continued to deposit mineral in culture and that the mineral composition was similar to that of age-matched controls. Notably there was a significant decrease in the manganese content of DIV18 compared with DIV11 specimens, possibly relating to less manganese sequestration as a result of mineral maturation. More importantly, quantitative T1 maps of Mn-treated calvariae showed localized reductions in T1 values over the calvarial surface, indicative of local variations in the surface manganese content. This result was verified with laser ablation inductively coupled plasma mass spectrometry (LA-ICP-MS). We also found that ??R1 values, calculated by subtracting the relaxation rate of Mn-treated specimens from the relaxation rate of age-matched controls, were proportional to the surface manganese content and thus mineralizing activity. From this analysis, we established that mineralization of DIV4 and DIV11 specimens occurred in all tissue zones, but was reduced for DIV18 specimens because of mineral maturation with less manganese sequestration. In DIV25 specimens, active mineralization was observed for

The DFBX cryogenic distribution boxes for the LHC straight sections

International Nuclear Information System (INIS)

Zbasnik, Jon P.; Corradi, Carol A.; Green, Michael A.; Kajiyama, Y.; Knolls, Michael J.; LaMantia, Roberto F.; Rasson, Joseph E.; Reavill, Dulie; Turner, William C.

2002-01-01

The DFBX distribution boxes are designed to connect the LHC cryogenic distribution system to the interaction region quadrupoles [1] and dipoles for the Large Hadron Collider (LHC). The DFBX distribution boxes also have the current leads for the superconducting interaction region magnets and the LHC interaction region correction coils. The DFBX boxes also connect the magnet and cryogenic instrumentation to the CERN data collection system. The DFBX boxes serve as the cryogenic circulation center and the nerve center for four of the LHC straight sections. This report describes primarily the cryogenic function of the DFBXs

Iron and manganese oxides modified maize straw to remove tylosin from aqueous solutions.

Science.gov (United States)

Yin, Yongyuan; Guo, Xuetao; Peng, Dan

2018-08-01

Maize straw modified by iron and manganese oxides was synthesized via a simple and environmentally friendly method. Three maize straw materials, the original maize straw, maize straw modified by manganese oxides and maize straw modified by iron and manganese oxides, were detected by SEM, BET, XPS, XRD and FTIR. The results showed that maize straw was successfully modified and maize straw modified by iron and manganese oxides has a larger surface area than MS. According to the experimental data, the sorption trend could conform to the pseudo-second-order kinetic model well, and the sorption ability of tylosin on sorbents followed the order of original maize straw oxides iron and manganese oxides. The study indicated that manganese oxides and iron-manganese oxides could significantly enhance the sorption capacity of original maize straw. The sorption isotherm data of tylosin on original maize straw fit a linear model well, while Freundlich models were more suitable for maize straw modified by manganese oxides and maize straw modified by iron and manganese oxides. The pH, ionic strength and temperature can affect the sorption process. The sorption mechanisms of tylosin on iron and manganese oxides modified maize straw were attribute to the surface complexes, electrostatic interactions, H bonding and hydrophobic interactions. Copyright © 2018 Elsevier Ltd. All rights reserved.

Effect of Manganese Content on the Fabrication of Porous Anodic Alumina

Directory of Open Access Journals (Sweden)

C. H. Voon

2012-01-01

Full Text Available The influence of manganese content on the formation of well-ordered porous anodic alumina was studied. Porous anodic alumina has been produced on aluminium substrate of different manganese content by single-step anodizing at 50 V in 0.3 M oxalic acid at 15°C for 60 minutes. The well-ordered pore and cell structure was revealed by subjecting the porous anodic alumina to oxide dissolution treatment in a mixture of chromic acid and phosphoric acid. It was found that the manganese content above 1 wt% impaired the regularity of the cell and pore structure significantly, which can be attributed to the presence of secondary phases in the starting material with manganese content above 1 wt%. The pore diameter and interpore distance decreased with the addition of manganese into the substrates. The time variation of current density and the thickness of porous anodic alumina also decreased as a function of the manganese content in the substrates.

The scavenging of silver by manganese and iron oxides in stream sediments collected from two drainage areas of Colorado

Science.gov (United States)

Chao, T.T.; Anderson, B.J.

1974-01-01

Stream sediments of two well-weathered and aerated drainage areas of Colorado containing anomalous amounts of silver were allowed to react by shaking with nitric acid of different concentrations (1-10M). Silver, manganese, and iron simultaneously dissolved were determined by atomic absorption. The relationship between silver dissolution and the dissolution of manganese and/or iron was evaluated by linear and multiple regression analyses. The highly significant correlation coefficient (r = 0.913) between silver and manganese dissolution suggests that manganese oxides are the major control on the scavenging of silver in these stream sediments, whereas iron oxides only play a secondary role in this regard. ?? 1974.

Manganese dipyridoxyl diphosphate:

DEFF Research Database (Denmark)

H, Brurok; Ardenkjær-Larsen, Jan Henrik; G, Hansson

1999-01-01

Manganese dipyridoxyl diphosphate (MnDPDP) is a contrast agent for magnetic resonance imaging (MRI) of the liver. Aims of the study were to examine if MnDPDP possesses superoxide dismutase (SOD) mimetic activity in vitro, and if antioxidant protection can be demonstrated in an ex vivo rat heart...

Nickel--chromium strain gages for cryogenic stress analysis of superconducting structures in high magnetic fields

International Nuclear Information System (INIS)

Freynik, H.S. Jr.; Roach, D.R.; Deis, D.W.; Hirzel, D.G.

1977-01-01

Evaluation and calibration measurements were performed on commercial nickel-chromium metal-foil strain gages in a high-magnetic-field (12 T), liquid-helium (4.2 K) environment. The purpose was to fully characterize strain gages for use at cryogenic temperatures in high magnetic fields. In this study, the magnetoresistance of a number of strain gages was measured in three orthogonal directions at mechanical strain levels to 8900 μm/m. As a result, a unique calibration curve was defined for magnetoresistance strain errors that is independent of strain level and field direction to 12 T at 4.2 K. A current strain-gage application is the measurement of superconductor mechanical properties. These gages will soon be used in the stress analysis of superconducting fusion magnets during cooldown from ambient temperatures and during operation at 4.2 K with magnetic fields to 12 T

Cryogen spray cooling: Effects of droplet size and spray density on heat removal.

Science.gov (United States)

Pikkula, B M; Torres, J H; Tunnell, J W; Anvari, B

2001-01-01

Cryogen spray cooling (CSC) is an effective method to reduce or eliminate non-specific injury to the epidermis during laser treatment of various dermatological disorders. In previous CSC investigations, fuel injectors have been used to deliver the cryogen onto the skin surface. The objective of this study was to examine cryogen atomization and heat removal characteristics of various cryogen delivery devices. Various cryogen delivery device types including fuel injectors, atomizers, and a device currently used in clinical settings were investigated. Cryogen mass was measured at the delivery device output orifice. Cryogen droplet size profiling for various cryogen delivery devices was estimated by optically imaging the droplets in flight. Heat removal for various cryogen delivery devices was estimated over a range of spraying distances by temperature measurements in an skin phantom used in conjunction with an inverse heat conduction model. A substantial range of mass outputs were measured for the cryogen delivery devices while heat removal varied by less than a factor of two. Droplet profiling demonstrated differences in droplet size and spray density. Results of this study show that variation in heat removal by different cryogen delivery devices is modest despite the relatively large difference in cryogen mass output and droplet size. A non-linear relationship between heat removal by various devices and droplet size and spray density was observed. Copyright 2001 Wiley-Liss, Inc.