WorldWideScience

Sample records for high emission zones

  1. Use of Interface Treatment to Reduce Emissions from Residuals in Lower Permeability Zones to Groundwater flowing Through More Permeable Zones (Invited)

    Science.gov (United States)

    Johnson, P.; Cavanagh, B.; Clifton, L.; Daniels, E.; Dahlen, P.

    2013-12-01

    Many soil and groundwater remediation technologies rely on fluid flow for contaminant extraction or reactant delivery (e.g., soil vapor extraction, pump and treat, in situ chemical oxidation, air sparging, enhanced bioremediation). Given that most unconsolidated and consolidated settings have permeability contrasts, the outcome is often preferential treatment of more permeable zones and ineffective treatment of the lower permeability zones. When this happens, post-treatment contaminant emissions from low permeability zone residuals can cause unacceptable long-term impacts to groundwater in the transmissive zones. As complete remediation of the impacted lower permeability zones may not be practicable with conventional technologies, one might explore options that lead to reduction of the contaminant emissions to acceptable levels, rather than full remediation of the lower permeability layers. This could be accomplished either by creating a sustained emission reaction/attenuation zone at the high-low permeability interface, or by creating a clean soil zone extending sufficiently far into the lower permeability layer to cause the necessary reduction in contaminant concentration gradient and diffusive emission. These options are explored in proof-of-concept laboratory-scale physical model experiments. The physical models are prepared with two layers of contrasting permeability and either dissolved matrix storage or nonaqueous phase liquid (NAPL) in the lower permeability layer. A dissolved oxidant is then delivered to the interface via flow across the higher permeability layer and changes in contaminant emissions from the low permeability zone are monitored before, during, and after oxidant delivery. The use of three oxidants (dissolved oxygen, hydrogen peroxide and sodium persulfate) for treatment of emissions from petroleum hydrocarbon residuals is examined.

  2. Vehicle emission implications of drivers' smart advisory system for traffic operations in work zones.

    Science.gov (United States)

    Li, Qing; Qiao, Fengxiang; Yu, Lei

    2016-05-01

    . Transportation section is a significant source of greenhouse gas emissions. Many studies demonstrate that the wireless communication system dedicated for safety and mobility issues may contribute to the induction in vehicle emissions through changing driving behaviors. An insight into the correlation between the driving behaviors and the distribution of Operating Mode (OpMode) IDs is essential to enhance the emission reduction. The result of this study shows that with a Drivers Smart Advisory System (DSAS) drivers accelerated smoothly and stopped earlier for a hazardous situation, which induce the switch of the OpMode IDs from high emission zones to lower emission zones.

  3. Positron emission zone plate holography for particle tracking

    Energy Technology Data Exchange (ETDEWEB)

    Gundogdu, O. [University of Birmingham, School of Physics and Astronomy, Birmingham B15 2TT (United Kingdom)]. E-mail: o.gundogdu@surrey.ac.uk

    2006-01-15

    Positron Emission Particle Tracking (PEPT) is a powerful non-invasive technique that has been used extensively for tracking a single particle. In this paper, we present a study of zone plate holography method in order to track multiple particles, mainly two particles. The main aim is to use as small number of events as possible in the order to make it possible to track particles in fast moving industrial systems. A zone plate with 100% focal efficiency is simulated and applied to the Positron Emission Tomography (PET) data for multiple particle tracking. A simple trajectory code was employed to explore the effects of the nature of the experimental trajectories. A computer holographic reconstruction code that simulates optical reconstruction was developed. The different aspects of the particle location, particle activity ratios for enabling tagging of particles and zone plate and hologram locations are investigated. The effect of the shot noise is investigated and the limitations of the zone plate holography are reported.

  4. Positron emission zone plate holography for particle tracking

    International Nuclear Information System (INIS)

    Gundogdu, O.

    2006-01-01

    Positron Emission Particle Tracking (PEPT) is a powerful non-invasive technique that has been used extensively for tracking a single particle. In this paper, we present a study of zone plate holography method in order to track multiple particles, mainly two particles. The main aim is to use as small number of events as possible in the order to make it possible to track particles in fast moving industrial systems. A zone plate with 100% focal efficiency is simulated and applied to the Positron Emission Tomography (PET) data for multiple particle tracking. A simple trajectory code was employed to explore the effects of the nature of the experimental trajectories. A computer holographic reconstruction code that simulates optical reconstruction was developed. The different aspects of the particle location, particle activity ratios for enabling tagging of particles and zone plate and hologram locations are investigated. The effect of the shot noise is investigated and the limitations of the zone plate holography are reported

  5. Experimental investigation of aerodynamics, combustion, and emissions characteristics within the primary zone of a gas turbine combustor

    Science.gov (United States)

    Elkady, Ahmed M.

    2006-04-01

    The present work investigates pollutant emissions production, mainly nitric oxides and carbon monoxide, within the primary zone of a highly swirling combustion and methods with which to reduce their formation. A baseline study was executed at different equivalence ratios and different inlet air temperatures. The study was then extended to investigate the effects of utilizing transverse air jets on pollutant emission characteristics at different jet locations, jet mass ratio, and overall equivalence ratio as well as to investigate the jets' overall interactions with the recirculation zone. A Fourier Transform Infrared (FTIR) spectrometer was employed to measure emissions concentrations generated during combustion of Jet-A fuel in a swirl-cup assembly. Laser Doppler Velocimetry (LDV) was employed to investigate the mean flow aerodynamics within the combustor. Particle Image Velocimetry (PIV) was utilized to capture the instantaneous aerodynamic behavior of the non-reacting primary zone. Results illustrate that NOx production is a function of both the recirculation zone and the flame length. At low overall equivalence ratios, the recirculation zone is found to be the main producer of NOx. At near stoichiometric conditions, the post recirculation zone appears to be responsible for the majority of NOx produced. Results reveal the possibility of injecting air into the recirculation zone without altering flame stability to improve emission characteristics. Depending on the jet location and strength, nitric oxides as well as carbon monoxide can be reduced simultaneously. Placing the primary air jet just downstream of the fuel rich recirculation zone can lead to a significant reduction in both nitric oxides and carbon monoxide. In the case of fuel lean recirculation zone, reduction of nitric oxides can occur by placing the jets below the location of maximum radius of the recirculation zone.

  6. Nitrous oxide emissions from Phragmites australis-dominated zones in a shallow lake

    International Nuclear Information System (INIS)

    Yang Zhifeng; Zhao Ying; Xia Xinghui

    2012-01-01

    Nitrous oxide (N 2 O) emissions from Phragmites australis (reed) – dominated zones in Baiyangdian Lake, the largest shallow lake of Northern China, were investigated under different hydrological conditions with mesocosm experiments during the growing season of reeds. The daily and monthly N 2 O emissions were positively correlated with air temperature and the variation of aboveground biomass of reeds (p 2 O emissions from reeds were about 45.8–52.8% of that from the sediments. In terms of the effect of hydrological conditions, N 2 O emissions from the aquatic-terrestrial ecotone were 9.4–26.1% higher than the submerged zone, inferring that the variation of water level would increase N 2 O emissions. The annual N 2 O emission from Baiyangdian Lake was estimated to be about 114.2 t. This study suggested that N 2 O emissions from shallow lakes might be accelerated by the climate change as it has increased air temperature and changed precipitation, causing the variation of water level. - Highlights: ► The daily N 2 O emissions were significant positively correlated with air temperature. ► The monthly N 2 O emissions positively correlated with reed aboveground biomass variations. ► The N 2 O emissions from reeds contributed to 45.8–52.8% of that from the sediment. ► N 2 O emissions from the aquatic-terrestrial ecotone were 9.4–26.1% higher than the submerged zone. ► N 2 O emissions from shallow lakes might be accelerated by the climate change. - The increase of air temperature and water level variation would increase N 2 O emissions, suggesting N 2 O emissions from shallow lakes might be accelerated by climate change.

  7. Carbon Dioxide and Methane Emissions from Diverse Zones of a California Salt Marsh

    Science.gov (United States)

    Wang, F.; King, J. Y.

    2016-12-01

    With high primary productivity and low organic matter decomposition rates, salt marshes sequester carbon from the atmosphere and contribute to mitigation of climate change. However, the role of wetlands in carbon sequestration is offset by CO2 and CH4 emissions whose magnitudes remain coarsely constrained. To better understand the spatiotemporal dynamics of gaseous carbon fluxes from marsh soils in a Mediterranean climate, we collected air and soil samples over the course of 10 months at Carpinteria Salt Marsh Reserve (CSMR) located in the County of Santa Barbara, California. The CSMR consists of four distinct zones characterized by differences in elevation, tidal regime, and vegetation. Twelve static chambers were deployed among two lower marsh zones, a salt flat, and a marsh-upland transition zone for fortnightly flux measurements from September, 2015 to May, 2016. In August, 2015 and June, 2016, soil cores up to 50 cm deep were extracted near the chambers, segmented by depth, and analyzed for soil moisture, bulk density, EC, pH, organic/inorganic carbon, and total nitrogen content. The gaseous carbon fluxes showed significant spatiotemporal variability, and soil properties differed noticeably by zone and by depth. Integrated over the study period, the marsh-upland transition zone had the highest CO2 fluxes at 292 g C/m2, followed closely by the lower marsh zones (271 g C/m2 and 189 g C/m2), which were one order of magnitude higher than the CO2 fluxes from the salt flat (23 g C/m2). Seasonally, CO2 fluxes were 2.5 to 3.5 times higher during the warmer months (Sept - Oct, Mar - May) than the colder months (Nov - Feb) across all zones. The CH4 fluxes were more temporally heterogeneous, but overall the CH4 emissions from the lower marsh zones (1.37 g C/m2 and 0.41 g C/m2) surpassed those from the salt flat (0.054 g C/m2) by an order of magnitude, and the marsh-upland transition zone was a net methane sink (-0.029 g C/m2). Our results show that soil gaseous carbon

  8. Nitrous oxide emissions from the Gulf of Mexico Hypoxic Zone

    Science.gov (United States)

    The production of nitrous oxide (N2O), a potent greenhouse gas, in hypoxic coastal zones remains poorly characterized due to a lack of data, though large nitrogen inputs and deoxygenation typical of these systems create the potential for large N2O emissions. We report the first N...

  9. Inventory of conventional atmospheric pollutant emissions in the Cali-Yumbo zone

    International Nuclear Information System (INIS)

    Jaramillo, Mauricio; Nunez, Maria Eugenia; Ocampo, William; Perez, Diego; Portilla, Gloria

    2004-01-01

    This work presents the results of the emission inventory of criteria pollutants (VOC's, PM 1 0, CO, NO x and SO x ) from anthropogenic sources for the Cali-Yumbo urban area in Colombia in 1997. Area, point and mobile sources, were considered in the study. Four point sources; reports to environmental authorities from 108 industries in the area were analyzed. The method of emission factors was employed to relate production activity with pollutant emissions, and the MOBILE 6.0 model was applied to calculate vehicular emissions. This analysis will be useful to generate urban environmental management projects, to develop pollutant dispersion models, and to contribute criteria for improved air quality monitoring and prediction in the zone of interest

  10. Problems involved in sampling within and outside zones of emission

    Energy Technology Data Exchange (ETDEWEB)

    Oelschlaeger, W

    1973-01-01

    Problems involved in the sampling of plant materials both inside and outside emission zones are considered, especially in regard to trace element analysis. The basic problem revolves around obtaining as accurately as possible an average sample of actual composition. Elimination of error possibilities requires a knowledge of such factors as botanical composition, vegetation states, rains, mass losses in leaf and blossom parts, contamination through the soil, and gaseous or particulate emissions. Sampling and preparation of samples is also considered with respect to quantitative aspects of trace element analysis.

  11. Geostatistical modeling of the gas emission zone and its in-place gas content for Pittsburgh-seam mines using sequential Gaussian simulation

    Science.gov (United States)

    Karacan, C.O.; Olea, R.A.; Goodman, G.

    2012-01-01

    Determination of the size of the gas emission zone, the locations of gas sources within, and especially the amount of gas retained in those zones is one of the most important steps for designing a successful methane control strategy and an efficient ventilation system in longwall coal mining. The formation of the gas emission zone and the potential amount of gas-in-place (GIP) that might be available for migration into a mine are factors of local geology and rock properties that usually show spatial variability in continuity and may also show geometric anisotropy. Geostatistical methods are used here for modeling and prediction of gas amounts and for assessing their associated uncertainty in gas emission zones of longwall mines for methane control.This study used core data obtained from 276 vertical exploration boreholes drilled from the surface to the bottom of the Pittsburgh coal seam in a mining district in the Northern Appalachian basin. After identifying important coal and non-coal layers for the gas emission zone, univariate statistical and semivariogram analyses were conducted for data from different formations to define the distribution and continuity of various attributes. Sequential simulations performed stochastic assessment of these attributes, such as gas content, strata thickness, and strata displacement. These analyses were followed by calculations of gas-in-place and their uncertainties in the Pittsburgh seam caved zone and fractured zone of longwall mines in this mining district. Grid blanking was used to isolate the volume over the actual panels from the entire modeled district and to calculate gas amounts that were directly related to the emissions in longwall mines.Results indicated that gas-in-place in the Pittsburgh seam, in the caved zone and in the fractured zone, as well as displacements in major rock units, showed spatial correlations that could be modeled and estimated using geostatistical methods. This study showed that GIP volumes may

  12. Impact of a highly detailed emission inventory on modeling accuracy

    Science.gov (United States)

    Taghavi, M.; Cautenet, S.; Arteta, J.

    2005-03-01

    During Expérience sur Site pour COntraindre les Modèles de Pollution atmosphérique et de Transport d'Emissions (ESCOMPTE) campaign (June 10 to July 14, 2001), two pollution events observed during an intensive measurement period (IOP2a and IOP2b) have been simulated. The comprehensive Regional Atmospheric Modeling Systems (RAMS) model, version 4.3, coupled online with a chemical module including 29 species is used to follow the chemistry of a polluted zone over Southern France. This online method takes advantage of a parallel code and use of the powerful computer SGI 3800. Runs are performed with two emission inventories: the Emission Pre Inventory (EPI) and the Main Emission Inventory (MEI). The latter is more recent and has a high resolution. The redistribution of simulated chemical species (ozone and nitrogen oxides) is compared with aircraft and surface station measurements for both runs at regional scale. We show that the MEI inventory is more efficient than the EPI in retrieving the redistribution of chemical species in space (three-dimensional) and time. In surface stations, MEI is superior especially for primary species, like nitrogen oxides. The ozone pollution peaks obtained from an inventory, such as EPI, have a large uncertainty. To understand the realistic geographical distribution of pollutants and to obtain a good order of magnitude in ozone concentration (in space and time), a high-resolution inventory like MEI is necessary. Coupling RAMS-Chemistry with MEI provides a very efficient tool able to simulate pollution plumes even in a region with complex circulations, such as the ESCOMPTE zone.

  13. Effect of Hydrogen Addition on Methane HCCI Engine Ignition Timing and Emissions Using a Multi-zone Model

    Science.gov (United States)

    Wang, Zi-han; Wang, Chun-mei; Tang, Hua-xin; Zuo, Cheng-ji; Xu, Hong-ming

    2009-06-01

    Ignition timing control is of great importance in homogeneous charge compression ignition engines. The effect of hydrogen addition on methane combustion was investigated using a CHEMKIN multi-zone model. Results show that hydrogen addition advances ignition timing and enhances peak pressure and temperature. A brief analysis of chemical kinetics of methane blending hydrogen is also performed in order to investigate the scope of its application, and the analysis suggests that OH radical plays an important role in the oxidation. Hydrogen addition increases NOx while decreasing HC and CO emissions. Exhaust gas recirculation (EGR) also advances ignition timing; however, its effects on emissions are generally the opposite. By adjusting the hydrogen addition and EGR rate, the ignition timing can be regulated with a low emission level. Investigation into zones suggests that NOx is mostly formed in core zones while HC and CO mostly originate in the crevice and the quench layer.

  14. Assessment of soil GHG emission in different functional zones of Moscow urbanized areas

    Science.gov (United States)

    Vizirskaya, Maria; Epikhina, Anna; Vasenev, Ivan; Valentini, Riccardo; Mazirov, Il'ya

    2014-05-01

    Atmospheric greenhouse-gas concentrations are increasing rapidly, causing global climate changes. Growing concentrations of CO2, CH4 and N2O are occurring not only as a result of industry activity, but also from changes in land use and type of land management due to urbanization. Up to now there were not so many studies in Russia that dealt with urbanization effects (functional zoning, land-use type, soil contamination etc.) on GHG emission from the soil in spatial-temporal variability at the local and regional scale. The aim of our study is to provide the analysis of soil CO2, N2O and CH4 efflux's response to different biotic and abiotic factors, as well as to management activities and anthropogenic impact in different functional zones of the city. The principal objects of our study are representative urban landscapes with different land-use practices, typical for urbanized area. The varieties of urban ecosystems are represented by urban forest, green lawns with different functional subzoning and agro landscapes (16 sites in total). Forest sites have been studied during 7 years and they are differing in mezorelief (small hill summit and two slopes). Green lawns vary in level of human impact (normal, medium and high) and are represented by managed and non-managed lawns. Agro landscapes are represented by two crop types: barley and grass mixture (oats and vetch) with till and no-till cultivation. In each plot we measured: soil respiration in field conditions using system based on IR-gas analyzer Li- COR 820, CH4 and N2O emission using the method of exposition chamber. Samples were taken from soil exposition chamber by syringe, and then analyzed on gas chromatograph. The measurements with Li-COR have been done on 10 days base since June till October 2013, and till September by exposition chamber in 5 replicas per plot. The conducted research have shown high spatial and temporal variability of CO2, CH4 and N2O fluxes due to functional zoning, slope, vegetation type

  15. Intelligent emissions controller for substance injection in the post-primary combustion zone of fossil-fired boilers

    Science.gov (United States)

    Reifman, Jaques; Feldman, Earl E.; Wei, Thomas Y. C.; Glickert, Roger W.

    2003-01-01

    The control of emissions from fossil-fired boilers wherein an injection of substances above the primary combustion zone employs multi-layer feedforward artificial neural networks for modeling static nonlinear relationships between the distribution of injected substances into the upper region of the furnace and the emissions exiting the furnace. Multivariable nonlinear constrained optimization algorithms use the mathematical expressions from the artificial neural networks to provide the optimal substance distribution that minimizes emission levels for a given total substance injection rate. Based upon the optimal operating conditions from the optimization algorithms, the incremental substance cost per unit of emissions reduction, and the open-market price per unit of emissions reduction, the intelligent emissions controller allows for the determination of whether it is more cost-effective to achieve additional increments in emission reduction through the injection of additional substance or through the purchase of emission credits on the open market. This is of particular interest to fossil-fired electrical power plant operators. The intelligent emission controller is particularly adapted for determining the economical control of such pollutants as oxides of nitrogen (NO.sub.x) and carbon monoxide (CO) emitted by fossil-fired boilers by the selective introduction of multiple inputs of substances (such as natural gas, ammonia, oil, water-oil emulsion, coal-water slurry and/or urea, and combinations of these substances) above the primary combustion zone of fossil-fired boilers.

  16. Implant test and acoustic emission technique used to investigate hydrogen assisted cracking in the melted zone of a welded HSLA-80 steel

    International Nuclear Information System (INIS)

    Fals, H. C.; Trevisan, R. E.

    1999-01-01

    Weld metal hydrogen assisted cracking was studied using two flux cored wire (AWS E 70T-5 and AWS E 120 T5-K4) and a mixture gas of CO 2 +5% H 2 to induce values of diffusible hydrogen in high strength low alloy steel (HSLA-80) weldments. An acoustical Emission Measurement System (AEMS) RMS voltmeter was coupled to the implant test (NF 89-100) apparatus to determine energy, amplitude and event numbers of signal. All cracks were initiated in the partially melted zone and propagated into the coarse-grained region of the heat affected zone when E 70 T5 consumable was used, and the quasi-cleavage fracture mode was predominant. When E 120 T5 K4 consumable was used the cracks propagated vertically across the fusion zone, and a mixed fracture mode was the most important. A significant relationship between acoustic emission parameters and fracture modes was found. (Author) 12 refs

  17. $\\gamma$-Ray Pulsars: Emission Zones and Viewing Geometries

    OpenAIRE

    Romani, Roger W.; Yadigaroglu, I. -A.

    1994-01-01

    There are now a half dozen young pulsars detected in high energy photons by the Compton GRO, showing a variety of emission efficiencies and pulse profiles. We present here a calculation of the pattern of high energy emission on the sky in a model which posits $\\gamma$-ray production by charge depleted gaps in the outer magnetosphere. This model accounts for the radio to $\\gamma$-ray pulse offsets of the known pulsars, as well as the shape of the high energy pulse profiles. We also show that $...

  18. Gamma-ray pulsars: Emission zones and viewing geometries

    Science.gov (United States)

    Romani, Roger W.; Yadigaroglu, I.-A.

    1995-01-01

    There are now a half-dozen young pulsars detected in high-energy photons by the Compton Gamma-Ray Observatory (CGRO), showing a variety of emission efficiencies and pulse profiles. We present here a calculation of the pattern of high-energy emission on the sky in a model which posits gamma-ray production by charge-depleted gaps in the outer magnetosphere. This model accounts for the radio to gamma-ray pulse offsets of the known pulsars, as well as the shape of the high-energy pulse profiles. We also show that about one-third of emitting young radio pulsars will not be detected due to beaming effects, while approximately 2.5 times the number of radio-selected gamma-ray pulsars will be viewed only high energies. Finally we compute the polarization angle variation and find that the previously misunderstood optical polarization sweep of the Crab pulsar arises naturally in this picture. These results strongly support an outer magnetosphere location for the gamma-ray emission.

  19. Air quality assessment of low emission zones in Copenhagen. [Denmark]; Luftkvalitetsvurdering af ren-luftzone i Koebenhavn

    Energy Technology Data Exchange (ETDEWEB)

    Solvang Jensen, S.; Ketzel, M.; Brandt, J.; Winther, M.; Ellermann, T.

    2012-09-15

    According to the government agreement from 2011 improved low emission zones have been identified as a measure to improve the air quality in greater Danish cities, and to ensure compliance with air quality limit values for NO{sub 2} of 40 {mu}g/m{sup 3} as an annual mean. The limit value is violated at H.C. Andersens Boulevard in Copenhagen which is one of the busiest urban streets in Denmark and a fixed air quality monitor station is also located in the street. Air quality model calculations also shows that some other busy streets in Copenhagen violate the annual air quality limit values for NO{sub 2}. The objective of the project is to assess the impacts of a number of improved low emission zone measures in Copenhagen regarding emissions and air quality with focus on NO{sub 2}. The impact assessment of different scenarios includes assessment of emissions and air quality. The assessment is carried out in great details for NO{sub 2} and to a lesser degree for PM exhaust, PM{sub 2.5} and PM{sub 10}. Since air quality assessment is resource demanding only the main scenarios are carried out with the full air quality model whereas the air quality of the scenario variants are assessed based on regression analysis between emissions and air quality in scenarios calculated with the full air quality model. (LN)

  20. Analytical estimation of emission zone mean position and width in organic light-emitting diodes from emission pattern image-source interference fringes

    International Nuclear Information System (INIS)

    Epstein, Ariel; Tessler, Nir; Einziger, Pinchas D.; Roberts, Matthew

    2014-01-01

    We present an analytical method for evaluating the first and second moments of the effective exciton spatial distribution in organic light-emitting diodes (OLED) from measured emission patterns. Specifically, the suggested algorithm estimates the emission zone mean position and width, respectively, from two distinct features of the pattern produced by interference between the emission sources and their images (induced by the reflective cathode): the angles in which interference extrema are observed, and the prominence of interference fringes. The relations between these parameters are derived rigorously for a general OLED structure, indicating that extrema angles are related to the mean position of the radiating excitons via Bragg's condition, and the spatial broadening is related to the attenuation of the image-source interference prominence due to an averaging effect. The method is applied successfully both on simulated emission patterns and on experimental data, exhibiting a very good agreement with the results obtained by numerical techniques. We investigate the method performance in detail, showing that it is capable of producing accurate estimations for a wide range of source-cathode separation distances, provided that the measured spectral interval is large enough; guidelines for achieving reliable evaluations are deduced from these results as well. As opposed to numerical fitting tools employed to perform similar tasks to date, our approximate method explicitly utilizes physical intuition and requires far less computational effort (no fitting is involved). Hence, applications that do not require highly resolved estimations, e.g., preliminary design and production-line verification, can benefit substantially from the analytical algorithm, when applicable. This introduces a novel set of efficient tools for OLED engineering, highly important in the view of the crucial role the exciton distribution plays in determining the device performance.

  1. Analytical estimation of emission zone mean position and width in organic light-emitting diodes from emission pattern image-source interference fringes

    Energy Technology Data Exchange (ETDEWEB)

    Epstein, Ariel, E-mail: ariel.epstein@utoronto.ca; Tessler, Nir, E-mail: nir@ee.technion.ac.il; Einziger, Pinchas D. [Department of Electrical Engineering, Technion-Israel Institute of Technology, Haifa 32000 (Israel); Roberts, Matthew, E-mail: mroberts@cdtltd.co.uk [Cambridge Display Technology Ltd, Building 2020, Cambourne Business Park, Cambourne, Cambridgeshire CB23 6DW (United Kingdom)

    2014-06-14

    We present an analytical method for evaluating the first and second moments of the effective exciton spatial distribution in organic light-emitting diodes (OLED) from measured emission patterns. Specifically, the suggested algorithm estimates the emission zone mean position and width, respectively, from two distinct features of the pattern produced by interference between the emission sources and their images (induced by the reflective cathode): the angles in which interference extrema are observed, and the prominence of interference fringes. The relations between these parameters are derived rigorously for a general OLED structure, indicating that extrema angles are related to the mean position of the radiating excitons via Bragg's condition, and the spatial broadening is related to the attenuation of the image-source interference prominence due to an averaging effect. The method is applied successfully both on simulated emission patterns and on experimental data, exhibiting a very good agreement with the results obtained by numerical techniques. We investigate the method performance in detail, showing that it is capable of producing accurate estimations for a wide range of source-cathode separation distances, provided that the measured spectral interval is large enough; guidelines for achieving reliable evaluations are deduced from these results as well. As opposed to numerical fitting tools employed to perform similar tasks to date, our approximate method explicitly utilizes physical intuition and requires far less computational effort (no fitting is involved). Hence, applications that do not require highly resolved estimations, e.g., preliminary design and production-line verification, can benefit substantially from the analytical algorithm, when applicable. This introduces a novel set of efficient tools for OLED engineering, highly important in the view of the crucial role the exciton distribution plays in determining the device performance.

  2. Hot zone evolution and pre-equilibrium emission in interactions between nuclei

    International Nuclear Information System (INIS)

    Jakobsson, B.; Karlsson, L.

    1990-01-01

    The evolution of the hot- and cold zones in intermediate energy nucleus-nucleus collisions by means of spherically expanding volumes and transport equations based on the Fermi-Dirac equation of state is described. Though the dynamical evolution of the collision is similar to that in Vlasov-Uehling-Uhlenbeck (VUU) calculations, some differences in the spectral shapes of emitted nucleons are found. The pre-equilibrium particle emission, prior to the breakup- or to the evaporation stage is always found to be an important contribution to the nucleon spectra which show reasonable agreement with data. (orig.)

  3. Regional analysis of soil-atmosphere nitrous oxide emissions in the Northern Atlantic Zone of Costa Rica

    NARCIS (Netherlands)

    Plant, R.A.J.

    2000-01-01

    Regional analysis of greenhouse gas emissions is becoming increasingly important in answering questions related to environmental change, and typically employs a Geographic Information System (GIS) linked with a process-based simulation model. For the Northern Atlantic Zone (NAZ) in Costa Rica (281

  4. THE ROLE OF THE DIFFUSIVE PROTONS IN THE GAMMA-RAY EMISSION OF SUPERNOVA REMNANT RX J1713.7–3946—A TWO-ZONE MODEL

    Energy Technology Data Exchange (ETDEWEB)

    Zhang, Xiao; Chen, Yang [Department of Astronomy, Nanjing University, 163 Xianlin Avenue, Nanjing 210023 (China)

    2016-04-10

    RX J1713.7−3946 is a prototype in the γ-ray-bright supernova remnants (SNRs) and is in continuing debates on its hadronic versus leptonic origin of the γ-ray emission. We explore the role played by the diffusive relativistic protons that escape from the SNR shock wave in the γ-ray emission, apart from the high-energy particles’ emission from the inside of the SNR. In the scenario that the SNR shock propagates in a clumpy molecular cavity, we consider that the γ-ray emission from the inside of the SNR may arise either from the inverse Compton scattering or from the interaction between the trapped energetic protons and the shocked clumps. The dominant origin between them depends on the electron-to-proton number ratio. The diffusive protons that escaped from the shock wave during the expansion history can provide an outer hadronic γ-ray component by bombarding the surrounding dense matter. The broadband spectrum can be well explained by this two-zone model, in which the γ-ray emission from the inside governs the TeV band, while the outer emission component substantially contributes to the GeV γ-rays. The two-zone model can also explain the TeV γ-ray radial brightness profile that significantly stretches beyond the nonthermal X-ray-emitting region. In the calculation, we present a simplified algorithm for Li and Chen's “accumulative diffusion” model for escaping protons and apply the Markov Chain Monte Carlo method to constrain the physical parameters.

  5. Surface heat flow and CO2 emissions within the Ohaaki hydrothermal field, Taupo Volcanic Zone, New Zealand

    International Nuclear Information System (INIS)

    Rissmann, Clinton; Christenson, Bruce; Werner, Cynthia; Leybourne, Matthew; Cole, Jim; Gravley, Darren

    2012-01-01

    Carbon dioxide emissions and heat flow have been determined from the Ohaaki hydrothermal field, Taupo Volcanic Zone (TVZ), New Zealand following 20 a of production (116 MW e ). Soil CO 2 degassing was quantified with 2663 CO 2 flux measurements using the accumulation chamber method, and 2563 soil temperatures were measured and converted to equivalent heat flow (W m −2 ) using published soil temperature heat flow functions. Both CO 2 flux and heat flow were analysed statistically and then modelled using 500 sequential Gaussian simulations. Forty subsoil CO 2 gas samples were also analysed for stable C isotopes. Following 20 a of production, current CO 2 emissions equated to 111 ± 6.7 T/d. Observed heat flow was 70 ± 6.4 MW, compared with a pre-production value of 122 MW. This 52 MW reduction in surface heat flow is due to production-induced drying up of all alkali–Cl outflows (61.5 MW) and steam-heated pools (8.6 MW) within the Ohaaki West thermal area (OHW). The drying up of all alkali–Cl outflows at Ohaaki means that the soil zone is now the major natural pathway of heat release from the high-temperature reservoir. On the other hand, a net gain in thermal ground heat flow of 18 MW (from 25 MW to 43.3 ± 5 MW) at OHW is associated with permeability increases resulting from surface unit fracturing by production-induced ground subsidence. The Ohaaki East (OHE) thermal area showed no change in distribution of shallow and deep soil temperature contours despite 20 a of production, with an observed heat flow of 26.7 ± 3 MW and a CO 2 emission rate of 39 ± 3 T/d. The negligible change in the thermal status of the OHE thermal area is attributed to the low permeability of the reservoir beneath this area, which has limited production (mass extraction) and sheltered the area from the pressure decline within the main reservoir. Chemistry suggests that although alkali–Cl outflows once contributed significantly to the natural surface heat flow (∼50%) they

  6. Surface heat flow and CO2 emissions within the Ohaaki hydrothermal field, Taupo Volcanic Zone, New Zealand

    Science.gov (United States)

    Rissmann, C.; Christenson, B.; Werner, C.; Leybourne, M.; Cole, J.; Gravley, D.

    2012-01-01

    Carbon dioxide emissions and heat flow have been determined from the Ohaaki hydrothermal field, Taupo Volcanic Zone (TVZ), New Zealand following 20a of production (116MW e). Soil CO2 degassing was quantified with 2663 CO2 flux measurements using the accumulation chamber method, and 2563 soil temperatures were measured and converted to equivalent heat flow (Wm -2) using published soil temperature heat flow functions. Both CO2 flux and heat flow were analysed statistically and then modelled using 500 sequential Gaussian simulations. Forty subsoil CO 2 gas samples were also analysed for stable C isotopes. Following 20a of production, current CO2 emissions equated to 111??6.7T/d. Observed heat flow was 70??6.4MW, compared with a pre-production value of 122MW. This 52MW reduction in surface heat flow is due to production-induced drying up of all alkali-Cl outflows (61.5MW) and steam-heated pools (8.6MW) within the Ohaaki West thermal area (OHW). The drying up of all alkali-Cl outflows at Ohaaki means that the soil zone is now the major natural pathway of heat release from the high-temperature reservoir. On the other hand, a net gain in thermal ground heat flow of 18MW (from 25MW to 43.3??5MW) at OHW is associated with permeability increases resulting from surface unit fracturing by production-induced ground subsidence. The Ohaaki East (OHE) thermal area showed no change in distribution of shallow and deep soil temperature contours despite 20a of production, with an observed heat flow of 26.7??3MW and a CO 2 emission rate of 39??3T/d. The negligible change in the thermal status of the OHE thermal area is attributed to the low permeability of the reservoir beneath this area, which has limited production (mass extraction) and sheltered the area from the pressure decline within the main reservoir. Chemistry suggests that although alkali-Cl outflows once contributed significantly to the natural surface heat flow (~50%) they contributed little (99% of the original CO 2

  7. High emissivity coatings for high temperature application: Progress and prospect

    International Nuclear Information System (INIS)

    He Xiaodong; Li Yibin; Wang Lidong; Sun Yue; Zhang, Sam

    2009-01-01

    High emissivity coatings are widely used in many cases where heat transfers through electromagnetic radiation that arises due to the temperature of a body. Extensive theoretical and experimental efforts have been made to synthesize and investigate high emissivity coatings. The emissivity can be improved through various or combined mechanisms. The characterization of the emissivity is still a fully open problem. In this paper, we review the various mechanisms associated with the emissivity enhancement and emissivity characterization techniques. Based on these literature reviews, the prospect will be presented in the concluding remarks.

  8. High mobility emissive organic semiconductor

    Science.gov (United States)

    Liu, Jie; Zhang, Hantang; Dong, Huanli; Meng, Lingqiang; Jiang, Longfeng; Jiang, Lang; Wang, Ying; Yu, Junsheng; Sun, Yanming; Hu, Wenping; Heeger, Alan J.

    2015-01-01

    The integration of high charge carrier mobility and high luminescence in an organic semiconductor is challenging. However, there is need of such materials for organic light-emitting transistors and organic electrically pumped lasers. Here we show a novel organic semiconductor, 2,6-diphenylanthracene (DPA), which exhibits not only high emission with single crystal absolute florescence quantum yield of 41.2% but also high charge carrier mobility with single crystal mobility of 34 cm2 V−1 s−1. Organic light-emitting diodes (OLEDs) based on DPA give pure blue emission with brightness up to 6,627 cd m−2 and turn-on voltage of 2.8 V. 2,6-Diphenylanthracene OLED arrays are successfully driven by DPA field-effect transistor arrays, demonstrating that DPA is a high mobility emissive organic semiconductor with potential in organic optoelectronics. PMID:26620323

  9. The London low emission zone baseline study.

    Science.gov (United States)

    Kelly, Frank; Armstrong, Ben; Atkinson, Richard; Anderson, H Ross; Barratt, Ben; Beevers, Sean; Cook, Derek; Green, Dave; Derwent, Dick; Mudway, Ian; Wilkinson, Paul

    2011-11-01

    On February 4, 2008, the world's largest low emission zone (LEZ) was established. At 2644 km2, the zone encompasses most of Greater London. It restricts the entry of the oldest and most polluting diesel vehicles, including heavy-goods vehicles (haulage trucks), buses and coaches, larger vans, and minibuses. It does not apply to cars or motorcycles. The LEZ scheme will introduce increasingly stringent Euro emissions standards over time. The creation of this zone presented a unique opportunity to estimate the effects of a stepwise reduction in vehicle emissions on air quality and health. Before undertaking such an investigation, robust baseline data were gathered on air quality and the oxidative activity and metal content of particulate matter (PM) from air pollution monitors located in Greater London. In addition, methods were developed for using databases of electronic primary-care records in order to evaluate the zone's health effects. Our study began in 2007, using information about the planned restrictions in an agreed-upon LEZ scenario and year-on-year changes in the vehicle fleet in models to predict air pollution concentrations in London for the years 2005, 2008, and 2010. Based on this detailed emissions and air pollution modeling, the areas in London were then identified that were expected to show the greatest changes in air pollution concentrations and population exposures after the implementation of the LEZ. Using these predictions, the best placement of a pollution monitoring network was determined and the feasibility of evaluating the health effects using electronic primary-care records was assessed. To measure baseline pollutant concentrations before the implementation of the LEZ, a comprehensive monitoring network was established close to major roadways and intersections. Output-difference plots from statistical modeling for 2010 indicated seven key areas likely to experience the greatest change in concentrations of nitrogen dioxide (NO2) (at least 3

  10. Emission of Polycyclic Aromatic Hydrocarbons from the Exhalation Zones of Thermally Active Mine Waste Dumps

    Directory of Open Access Journals (Sweden)

    Patrycja Kuna-Gwoździewicz

    2013-01-01

    Full Text Available The article presents results of research carried out on the occurrence of polycyclic aromatic hydrocarbons (PAH in gases of exhalation zones, created on the surface of a thermally active coal mine waste dump. The oxidation and self-heating of mine waste are accompanied with the intensive emission of flue gases, including PAH group compounds. Taking into consideration the fact the hydrocarbons show strong genotoxic, mutagenic and carcinogenic properties, research was conducted to establish their content in the examined gases. The research object was a gangue dump located in Rybnik. The research was performed in 2012. In total, 24 samples of gas were collected with PUF (polyurethane foam sampling cartridges with a quartz fibre filter and an aspirator. The collected samples were analysed with the use of high performance liquid chromatography (HPLC and a fluorescence detector (FLD to evaluate the amount of PAH present.

  11. Implications of emission zone limits for the Ruderman-Sutherland pulsar model

    International Nuclear Information System (INIS)

    Matese, J.J.; Whitmire, D.P.

    1980-01-01

    In the Ruderman-Sutherland (RS) pulsar model the frequency at which coherent radiation is emitted depends upon the source location, v=v (r). In the oblique rotator version of this model the time-averaged tangential velocities of the magnetosphere sources must increase linearly with radius, and this leads to a frequency-dependent aberration and retardation time delay in which higher frequencies lag behind lower frequencies. As previously noted by Cordes, within the context of a given model which specifies v (r), the absence of any anomalous time delay in dispersion measurements allows limits to be placed on the radial position of the source of a given frequency. In this paper we (a) give a time-delay analysis (similar to that of Cordes) appropriate for the RS model and show that existing dispersion measurements are incompatible with RS emission mechanism. If the basic RS emission mechanism is applicable to pulsars, we find that the most plausible modification consistent with the dispersion data is a reduction in the low-energy plasma density by a factor approx.10 -4 to 10 -5 . This has the effect of bringing the radio emission zone closer to the stellar surface, thereby making the model consistent with the dispersion data. In addition, this modification results in a significant decrease in the predicted maximum cone angle and an increase in the predicted maximum frequency by factors which bring these predictions more in line with observation. We also consider implications of a reduced plasma density for radio luminosity

  12. Methane emission in a specific riparian-zone sediment decreased with bioelectrochemical manipulation and corresponded to the microbial community dynamics

    Directory of Open Access Journals (Sweden)

    Elliot S. Friedman

    2016-01-01

    Full Text Available Dissimilatory metal-reducing bacteria are widespread in terrestrial ecosystems, especially in anaerobic soils and sediments. Thermodynamically, dissimilatory metal reduction is more favorable than sulfate reduction and methanogenesis but less favorable than denitrification and aerobic respiration. It is critical to understand the complex relationships, including the absence or presence of terminal electron acceptors, that govern microbial competition and coexistence in anaerobic soils and sediments, because subsurface microbial processes can effect greenhouse gas emissions from soils, possibly resulting in impacts at the global scale. Here, we elucidated the effect of an inexhaustible, ferrous-iron and humic-substance mimicking terminal electron acceptor by deploying potentiostatically poised electrodes in the sediment of a very specific stream riparian zone in Upstate New York state. At two sites within the same stream riparian zone during the course of six weeks in the spring of 2013, we measured CH4 and N2/N2O emissions from soil chambers containing either poised or unpoised electrodes, and we harvested biofilms from the electrodes to quantify microbial community dynamics. At the upstream site, which had a lower vegetation cover and highest soil temperatures, the poised electrodes inhibited CH4 emissions by ~45% (when normalized to remove temporal effects. CH4 emissions were not significantly impacted at the downstream site. N2/N2O emissions were generally low at both sites and were not impacted by poised electrodes. We did not find a direct link between bioelectrochemical treatment and microbial community membership; however, we did find a correspondence between environment/function and microbial community dynamics.

  13. Color-tunable and high-efficiency organic light-emitting diode by adjusting exciton bilateral migration zone

    Science.gov (United States)

    Liu, Shengqiang; Wu, Ruofan; Huang, Jiang; Yu, Junsheng

    2013-09-01

    A voltage-controlled color-tunable and high-efficiency organic light-emitting diode (OLED) by inserting 16-nm N,N'-dicarbazolyl-3,5-benzene (mCP) interlayer between two complementary emitting layers (EMLs) was fabricated. The OLED emitted multicolor ranging from blue (77.4 cd/A @ 6 V), white (70.4 cd/A @ 7 V), to yellow (33.7 cd/A @ 9 V) with voltage variation. An equivalent model was proposed to reveal the color-tunable and high-efficiency emission of OLEDs, resulting from the swing of exciton bilateral migration zone near mCP/blue-EML interface. Also, the model was verified with a theoretical arithmetic using single-EML OLEDs to disclose the crucial role of mCP exciton adjusting layer.

  14. Characteristics of Biogenic VOCs Emission and its High-Resolution Emission Inventory in China

    Science.gov (United States)

    Li, L.; Li, Y.; Xie, S.

    2017-12-01

    Biogenic volatile organic compounds (BVOCs), with high emission and reactivity, can have substantial impacts on the haze and photochemical pollution. It is essential to establish an accurate high-resolution BVOC emission inventory in China for air quality simulation and decision making. Firstly, a semi-static enclosure technique is developed for the field measurements of BVOC emission rates from 50 plant species in China. Using the GC-MS/FID system, 103 VOC species for each plant species are measured. Based on the field measurements in our study and the reported emission rates at home and abroad, a methodology for determining the emission categories of BVOCs is developed using statistical analysis. The isoprene and monoterpene emission rates of 192 plant species/genera in China are determined based on the above emission categories. Secondly, a new vegetation classification with 82 plant functional types (PFTs) is developed based on the most detailed and latest vegetation investigations, China's official statistical data and Vegetation Atlas of China (1:1,000,000). The leaf biomass is estimated based on provincial vegetation volume and production with biomass-apportion models. The WRF model is used to determine meteorological variables at a high spatio-temporal resolution. Using MEAGNv2.1 and the determined emission rates in our study, the high-resolution emission inventories of isoprene, 37 monoterpene species, 32 sesquiterpene species, and other VOCs (OVOCs) from 82 PFTs in China for 1981-2013 are established. The total annual BVOC emissions in 2013 are 55.88 Tg, including 33.87 Tg isoprene, 6.36 Tg monoterpene, 1.29 Tg sesquiterpene, and 14.37 Tg OVOCs. The distribution of isoprene emission fluxes is consistent with the distribution of broadleaf trees, especially tree species with high or higher emission potential. During 1981-2013, China's BVOC emissions have increased by 47.48% at an average rate of 1.80% yr-1. Emissions of isoprene have the largest enhancement

  15. Carbonation by fluid-rock interactions at high-pressure conditions: Implications for carbon cycling in subduction zones

    Science.gov (United States)

    Piccoli, Francesca; Vitale Brovarone, Alberto; Beyssac, Olivier; Martinez, Isabelle; Ague, Jay J.; Chaduteau, Carine

    2016-07-01

    Carbonate-bearing lithologies are the main carbon carrier into subduction zones. Their evolution during metamorphism largely controls the fate of carbon, regulating its fluxes between shallow and deep reservoirs. Recent estimates predict that almost all subducted carbon is transferred into the crust and lithospheric mantle during subduction metamorphism via decarbonation and dissolution reactions at high-pressure conditions. Here we report the occurrence of eclogite-facies marbles associated with metasomatic systems in Alpine Corsica (France). The occurrence of these marbles along major fluid-conduits as well as textural, geochemical and isotopic data indicating fluid-mineral reactions are compelling evidence for the precipitation of these carbonate-rich assemblages from carbonic fluids during metamorphism. The discovery of metasomatic marbles brings new insights into the fate of carbonic fluids formed in subducting slabs. We infer that rock carbonation can occur at high-pressure conditions by either vein-injection or chemical replacement mechanisms. This indicates that carbonic fluids produced by decarbonation reactions and carbonate dissolution may not be directly transferred to the mantle wedge, but can interact with slab and mantle-forming rocks. Rock-carbonation by fluid-rock interactions may have an important impact on the residence time of carbon and oxygen in subduction zones and lithospheric mantle reservoirs as well as carbonate isotopic signatures in subduction zones. Furthermore, carbonation may modulate the emission of CO2 at volcanic arcs over geological time scales.

  16. Identification of emission sources of particle-bound polycyclic aromatic hydrocarbons in the vicinity of the industrial zone of the city of Novi Sad

    OpenAIRE

    Jovčić Nataša S.; Radonić Jelena R.; Turk-Sekulić Maja M.; Vojinović-Miloradov Mirjana B.; Popov Srđan B.

    2013-01-01

    Data on polycyclic aromatic hydrocarbons (PAHs) in ambient air accessed at selected locations in the vicinity of the industrial zone of the city of Novi Sad, Serbia, have been presented and analyzed in order to determine seasonal and spatial variations and to identify emission sources of particle-bound PAHs. Previous studies have demonstrated that the major contributors of PAHs in urban areas are the emissions from vehicle exhaust, and emissions releases from industrial processes like a...

  17. Predicting the emissive power of hydrocarbon pool fires

    International Nuclear Information System (INIS)

    Munoz, Miguel; Planas, Eulalia; Ferrero, Fabio; Casal, Joaquim

    2007-01-01

    The emissive power (E) of a flame depends on the size of the fire and the type of fuel. In fact, it changes significantly over the flame surface: the zones of luminous flame have high emittance, while those covered by smoke have low E values. The emissive power of each zone (that is, the luminous or clear flame and the non-luminous or smoky flame) and the portion of total flame area they occupy must be assessed when a two-zone model is used. In this study, data obtained from an experimental set-up were used to estimate the emissive power of fires and its behaviour as a function of pool size. The experiments were performed using gasoline and diesel oil as fuel. Five concentric circular pools (1.5, 3, 4, 5 and 6 m in diameter) were used. Appropriate instruments were employed to determine the main features of the fires. By superimposing IR and VHS images it was possible to accurately identify the luminous and non-luminous zones of the fire. Mathematical expressions were obtained that give a more accurate prediction of E lum , E soot and the average emissive power of a fire as a function of its luminous and smoky zones. These expressions can be used in a two-zone model to obtain a better prediction of the thermal radiation. The value of the radiative fraction was determined from the thermal flux measured with radiometers. An expression is also proposed for estimating the radiative fraction

  18. BVOC emission in Norway spruce: the effect of stand structure, high temperature and ozone levels.

    Science.gov (United States)

    Pallozzi, Emanuele; Guidolotti, Gabriele; Večeřová, Kristýna; Esposito, Raffaela; Lusini, Ilaria; Juráň, Stanislav; Urban, Otmar; Calfapietra, Carlo

    2015-04-01

    Norway spruce (Picea abies L.) is a widely distributed conifer species in the boreal zone and mountain areas of central Europe and is a moderate emitter of volatile organic compounds (BVOC). Although the vaporization and diffusion processes from resin ducts were generally considered to be the main processes for monoterpene emissions in conifers, recently it has been showed that a significant portion (up to one third) of monoterpene emissions of Norway spruce can originate from novel biosynthesis, thus depending on photosynthetic processes. For this reason, both biosynthesis and emission are strongly influenced by the environment and the stand structure. They increase with both increasing light and temperature during the warmer periods, although those are the periods with the higher ozone concentration that usually act as an inhibitor of both assimilation and isoprenoids synthesis and emission. On the other hand, stand structure can play an important role, because the photosynthetic capacity is influenced by temperature and light conditions through the canopy. In order to assess the effects of stand structure, temperature and ozone on isoprenoids emission of Norway spruce we carried out field and laboratory experiments. In the experimental field campaigns we measured: assimilation and BVOC emission from needles of sun and shade layers within the canopy of the spruce forest present at the Bily Kriz experimental research site (Moravian-Silesian Beskydy Mountains, 49° 33' N, 18° 32' E, NE of Czech Republic, 908 m a.s.l.). Moreover in the same layers we measured continuously concentration of BVOCs in the air using a PTR-TOF-MS. In laboratory we analyzed the effects of short-term exposure to high temperature and high ozone concentrations on branches of spruce trees collected at the Bily Kriz experimental research site. Preliminary results show that in Norway spruce both stand structure and environmental conditions influenced the gas exchange and BVOC emission rates

  19. Structure and properties of melt-spun high acrylonitrile copolymer fibers via continuous zone-drawing and zone-annealing processes

    International Nuclear Information System (INIS)

    Wu Zongquan; Zhang Anqiu; Percec, Simona; Jin Shi; Jing, Alexander J.; Ge, Jason J.; Cheng, Stephen Z.D.

    2003-01-01

    Continuous zone-drawing and zone-annealing processes have been utilized to probe improvements in mechanical performance of melt-spun high acrylonitrile copolymer fibers (AMLON TM ). The as-spun fibers were zone-drawn at different ratios in a narrow temperature range of 100-105 deg. C and then zone-annealed. As a result of these processes, the fibers show substantial increases in tensile strength and tensile modulus (about three times) and significant improvements in elongation-at-break (about two times) after zone annealing. The thermal transition behavior, dimensional stability and dynamic relaxation properties of the as-spun, zone-drawn and zone-annealed fibers have been studied using differential scanning calorimetry, thermal mechanical and dynamic mechanical experiments. Their mechanical and thermal property changes after the zone-drawing and zone-annealing processes can be associated with the microscopic structural evolution including crystallinity, crystal orientation and apparent crystallite size detected by wide angle X-ray diffraction experiments

  20. Experimental demonstration of producing high resolution zone plates by spatial-frequency multiplication

    International Nuclear Information System (INIS)

    Yun, W.B.; Howells, M.R.

    1987-01-01

    In an earlier publication, the possibility of producing high resolution zone plates for x-ray applications by spatial-frequency multiplication was analyzed theoretically. The theory predicted that for a daughter zone plate generated from the interference of mth and nth diffraction orders of a parent zone plate, its primary focal spot size and focal length are one (m + n)th of their counterparts of the parent zone plate, respectively. It was also shown that a zone plate with the outermost zone width of as small as 13.8 nm might be produced by this technique. In this paper, we report an experiment which we carried out with laser light (λ = 4166A) for demonstrating this technique. In addition, an outlook for producing high resolution zone plates for x-ray application is briefly discussed

  1. High resolution, topobathymetric LiDAR coastal zone characterization in Denmark

    DEFF Research Database (Denmark)

    Steinbacher, Frank; Baran, Ramona; Andersen, Mikkel S.

    2016-01-01

    Coastal and tidal environments are valuable ecosystems, which, however, are under pressure in many areas around the world due to globalization and/or climate change. Detailed mapping of these environments is required in order to manage the coastal zone in a sustainable way. However, historically...... locations with different environmental settings. We demonstrate the potential of using airborne topobathymetric LiDAR for seamless mapping of land-water transition zones in challenging coastal environments, e.g. in an environment with high water column turbidity and continuously varying water levels due...... these transition zones between land and water are difficult or even impossible to map and investigate in high spatial resolution due to the challenging environmental conditions. The new generation of airborne topobathymetric light detection and ranging (LiDAR) potentially enables full-coverage and high...

  2. A New High-Resolution N2O Emission Inventory for China in 2008

    Science.gov (United States)

    Shang, Z.; Zhou, F.; Ciais, P.; Tao, S.; Piao, S.; Raymond, P. A.; He, C.; Li, B.; Wang, R.; Wang, X.; Peng, S.; Zeng, Z.; Chen, H.; Ying, N.; Hou, X.; Xu, P.

    2014-12-01

    The amount and geographic distribution of N2O emissions over China remain largely uncertain. Most of existing emission inventories use uniform emission factors (EFs) and the associated parameters and apply spatial proxies to downscale national or provincial data, resulting in the introduction of spatial bias. In this study, county-level and 0.1° × 0.1° gridded anthropogenic N2O emission inventories for China (PKU-N2O) in 2008 are developed based on high-resolution activity data and regional EFs and parameters. These new estimates are compared with estimates from EDGAR v4.2, GAINS-China, National Development and Reform Commission of China (NDRC), and with two sensitivity tests: one that uses high-resolution activity data but the default IPCC methodology (S1) and the other that uses regional EFs and parameters but starts from coarser-resolution activity data. The total N2O emissions are 2150 GgN2O/yr (interquartile range from 1174 to 2787 GgN2O/yr). Agriculture contributes 64% of the total, followed by energy (17%), indirect emissions (12%), wastes (5%), industry (2.8%), and wildfires (0.2%). Our national emission total is 17% greater than that of the EDGAR v4.2 global product sampled over China and is also greater than the GAINS-China, NDRC, and S1 estimates by 10%, 50%, and 17%, respectively. We also found that using uniform EFs and parameters or starting from national/provincial data causes systematic spatial biases compared to PKU-N2O. In addition, the considerable differences between the relative contributions of the six sectors across the six Agro-Climate Zones primarily reflect the different distributions of industrial activities and land use. Eastern China (8.7% area of China) is the largest contributor of N2O emissions and accounts for nearly 25% of the total. Spatial analysis also shows nonlinear relationships between N2O emission intensities and urbanization. Per-capita and per-GDP N2O emissions increase gradually with an increase in the urban

  3. Soil CO2 emissions as a proxy for heat and mass flow assessment, Taupō Volcanic Zone, New Zealand

    Science.gov (United States)

    Bloomberg, S.; Werner, Cynthia A.; Rissmann, C.F.; Mazot, A.; Horton, Travis B.; Gravley, D; Kennedy, B.; Oze, C

    2014-01-01

    The quantification of heat and mass flow between deep reservoirs and the surface is important for understanding magmatic and hydrothermal systems. Here, we use high-resolution measurement of carbon dioxide flux (φCO2) and heat flow at the surface to characterize the mass (CO2 and steam) and heat released to the atmosphere from two magma-hydrothermal systems. Our soil gas and heat flow surveys at Rotokawa and White Island in the Taupō Volcanic Zone, New Zealand, include over 3000 direct measurements of φCO2 and soil temperature and 60 carbon isotopic values on soil gases. Carbon dioxide flux was separated into background and magmatic/hydrothermal populations based on the measured values and isotopic characterization. Total CO2 emission rates (ΣCO2) of 441 ± 84 t d−1 and 124 ± 18 t d−1were calculated for Rotokawa (2.9 km2) and for the crater floor at White Island (0.3 km2), respectively. The total CO2 emissions differ from previously published values by +386 t d−1 at Rotokawa and +25 t d−1 at White Island, demonstrating that earlier research underestimated emissions by 700% (Rotokawa) and 25% (White Island). These differences suggest that soil CO2 emissions facilitate more robust estimates of the thermal energy and mass flux in geothermal systems than traditional approaches. Combining the magmatic/hydrothermal-sourced CO2 emission (constrained using stable isotopes) with reservoir H2O:CO2mass ratios and the enthalpy of evaporation, the surface expression of thermal energy release for the Rotokawa hydrothermal system (226 MWt) is 10 times greater than the White Island crater floor (22.5 MWt).

  4. Identification of emission sources of particle-bound polycyclic aromatic hydrocarbons in the vicinity of the industrial zone of the city of Novi Sad

    Directory of Open Access Journals (Sweden)

    Jovčić Nataša S.

    2013-01-01

    Full Text Available Data on polycyclic aromatic hydrocarbons (PAHs in ambient air accessed at selected locations in the vicinity of the industrial zone of the city of Novi Sad, Serbia, have been presented and analyzed in order to determine seasonal and spatial variations and to identify emission sources of particle-bound PAHs. Previous studies have demonstrated that the major contributors of PAHs in urban areas are the emissions from vehicle exhaust, and emissions releases from industrial processes like aluminium production, creosote and wood preservation, waste incineration, cement manufacture, petrochemical and related industries, commercial heat/power production etc. The sampling campaigns have been conducted at three sampling sites, during the two 14-day periods. The first site was situated near industrial area, with a refinery, power plant and heavy-traffic road in the vicinity. The second site was located nearby the heavy traffic area, especially busy during the rush hour. The third site was residential district. Summer sampling period lasted from June 26th to July 10th 2008, while sampling of ambient air during the winter was undertaken from January 22nd to February 5th 2009. Eighty-four (84 air samples were collected using a high volume air sampler TCR Tecora H0649010/ECHO. 16 US EPA polycyclic aromatic hydrocarbons were determined in all samples using a gas chromatographer with a mass spectrometer as a detector (Shimatzu MDGC/GCMS-2010. The total average concentrations of PAHs ranged from 1.21 to 1.77 ng/m3 during the summer period and from 6.31 to 7.25 ng/m3 in the winter. Various techniques, including diagnostic ratio (DR and principal component analysis (PCA, have been used to define and evaluate potential emission sources of PAHs. Diagnostic ratio analysis indicated that vehicles, diesel or/and gasoline, industrial and combustion emissions were sources of PAHs in the vicinity of the industrial zone. Additionally, principal component analysis was used

  5. High Efficiency, Low Emission Refrigeration System

    Energy Technology Data Exchange (ETDEWEB)

    Fricke, Brian A [ORNL; Sharma, Vishaldeep [ORNL

    2016-08-01

    Supermarket refrigeration systems account for approximately 50% of supermarket energy use, placing this class of equipment among the highest energy consumers in the commercial building domain. In addition, the commonly used refrigeration system in supermarket applications is the multiplex direct expansion (DX) system, which is prone to refrigerant leaks due to its long lengths of refrigerant piping. This leakage reduces the efficiency of the system and increases the impact of the system on the environment. The high Global Warming Potential (GWP) of the hydrofluorocarbon (HFC) refrigerants commonly used in these systems, coupled with the large refrigerant charge and the high refrigerant leakage rates leads to significant direct emissions of greenhouse gases into the atmosphere. Methods for reducing refrigerant leakage and energy consumption are available, but underutilized. Further work needs to be done to reduce costs of advanced system designs to improve market utilization. In addition, refrigeration system retrofits that result in reduced energy consumption are needed since the majority of applications address retrofits rather than new stores. The retrofit market is also of most concern since it involves large-volume refrigerant systems with high leak rates. Finally, alternative refrigerants for new and retrofit applications are needed to reduce emissions and reduce the impact on the environment. The objective of this Collaborative Research and Development Agreement (CRADA) between the Oak Ridge National Laboratory and Hill Phoenix is to develop a supermarket refrigeration system that reduces greenhouse gas emissions and has 25 to 30 percent lower energy consumption than existing systems. The outcomes of this project will include the design of a low emission, high efficiency commercial refrigeration system suitable for use in current U.S. supermarkets. In addition, a prototype low emission, high efficiency supermarket refrigeration system will be produced for

  6. High-Resolution P'P' Precursor Imaging of Nazca-South America Plate Boundary Zones and Inferences for Transition Zone Temperature and Composition

    Science.gov (United States)

    Gu, Y. J.; Schultz, R.

    2013-12-01

    Knowledge of upper mantle transition zone stratification and composition is highly dependent on our ability to efficiently extract and properly interpret small seismic arrivals. A promising high-frequency seismic phase group particularly suitable for a global analysis is P'P' precursors, which are capable of resolving mantle structures at vertical and lateral resolution of approximately 5 and 200 km, respectively, owing to their shallow incidence angle and small, quasi-symmetric Fresnel zones. This study presents a simultaneous analysis of SS and P'P' precursors based on deconvolution, Radon transform and depth migration. Our multi-resolution survey of the mantle near Nazca-South America subduction zone reveals both olivine and garnet related transitions at depth below 400 km. We attribute a depressed 660 to thermal variations, whereas compositional variations atop the upper-mantle transition zone are needed to explain the diminished or highly complex reflected/scattered signals from the 410 km discontinuity. We also observe prominent P'P' reflections within the transition zone, especially near the plate boundary zone where anomalously high reflection amplitudes result from a sharp (~10 km thick) mineral phase change resonant with the dominant frequency of the P'P' precursors. Near the base of the upper mantle, the migration of SS precursors shows no evidence of split reflections near the 660-km discontinuity, but potential majorite-ilmenite (590-640 km) and ilmenite-perovskite transitions (740-750 km) are identified based on similarly processed high-frequency P'P' precursors. At nominal mantle temperatures these two phase changes may be seismically indistinguishable, but colder mantle conditions from the descending Nazca plate, the presence of water and variable Fe contents may cause sufficient separation for a reliable analysis. In addition, our preliminary results provide compelling evidence for multiple shallow lower-mantle reflections (at ~800 km) along the

  7. Two-zone model of coronal hole structure in the high corona

    International Nuclear Information System (INIS)

    Wang, Z.; Kundu, M.R.; Yoshimura, H.

    1988-01-01

    The two-zone coronal hole structure model presently proposed for the high corona at 1.5-1.7 solar radii emerges from a comparison of computation results for the potential magnetic fields of the corona and meter-decameter radio observations. The two zones of a coronal hole are defined by the configuration of magnetic field lines around a coronal hole: (1) the central hole of an open diverging magnetic field line system; and (2) the boundary zone between the central zone of the open field line system and the closed field line system or systems surrounding the open field line system. 19 references

  8. High efficiency x-ray nanofocusing by the blazed stacking of binary zone plates

    Science.gov (United States)

    Mohacsi, I.; Karvinen, P.; Vartiainen, I.; Diaz, A.; Somogyi, A.; Kewish, C. M.; Mercere, P.; David, C.

    2013-09-01

    The focusing efficiency of binary Fresnel zone plate lenses is fundamentally limited and higher efficiency requires a multi step lens profile. To overcome the manufacturing problems of high resolution and high efficiency multistep zone plates, we investigate the concept of stacking two different binary zone plates in each other's optical near-field. We use a coarse zone plate with π phase shift and a double density fine zone plate with π/2 phase shift to produce an effective 4- step profile. Using a compact experimental setup with piezo actuators for alignment, we demonstrated 47.1% focusing efficiency at 6.5 keV using a pair of 500 μm diameter and 200 nm smallest zone width. Furthermore, we present a spatially resolved characterization method using multiple diffraction orders to identify manufacturing errors, alignment errors and pattern distortions and their effect on diffraction efficiency.

  9. N2O emission hotspots at different spatial scales and governing factors for small scale hotspots

    International Nuclear Information System (INIS)

    Heuvel, R.N. van den; Hefting, M.M.; Tan, N.C.G.; Jetten, M.S.M.; Verhoeven, J.T.A.

    2009-01-01

    Chronically nitrate-loaded riparian buffer zones show high N 2 O emissions. Often, a large part of the N 2 O is emitted from small surface areas, resulting in high spatial variability in these buffer zones. These small surface areas with high N 2 O emissions (hotspots) need to be investigated to generate knowledge on the factors governing N 2 O emissions. In this study the N 2 O emission variability was investigated at different spatial scales. Therefore N 2 O emissions from three 32 m 2 grids were determined in summer and winter. Spatial variation and total emission were determined on three different scales (0.3 m 2 , 0.018 m 2 and 0.0013 m 2 ) at plots with different levels of N 2 O emissions. Spatial variation was high at all scales determined and highest at the smallest scale. To test possible factors inducing small scale hotspots, soil samples were collected for slurry incubation to determine responses to increased electron donor/acceptor availability. Acetate addition did increase N 2 O production, but nitrate addition failed to increase total denitrification or net N 2 O production. N 2 O production was similar in all soil slurries, independent of their origin from high or low emission soils, indicating that environmental conditions (including physical factors like gas diffusion) rather than microbial community composition governed N 2 O emission rates

  10. Zone refining high-purity germanium

    International Nuclear Information System (INIS)

    Hubbard, G.S.; Haller, E.E.; Hansen, W.L.

    1977-10-01

    The effects of various parameters on germanium purification by zone refining have been examined. These parameters include the germanium container and container coatings, ambient gas and other operating conditions. Four methods of refining are presented which reproducibly yield 3.5 kg germanium ingots from which high purity (vertical barN/sub A/ - N/sub D/vertical bar less than or equal to2 x 10 10 cm -3 ) single crystals can be grown. A qualitative model involving binary and ternary complexes of Si, O, B, and Al is shown to account for the behavior of impurities at these low concentrations

  11. Development of newly designed wood burning systems with low emissions and high efficiency; Tehokkaan ja vaehaepaeaestoeisen puulaemmitysjaerjestelmaen kehittaeminen

    Energy Technology Data Exchange (ETDEWEB)

    Hyytiaeinen, H [Tulisydaen Oy, Vantaa (Finland)

    1997-12-01

    The investigations in the project will focus on the combustion behaviour of wood burning systems of untreated wood fuels with batch-wise and quasi-continuous mechanical feeding. The objectives will be to minimise the pollutant release of these combustion systems during the different operational phases by a consequent optimisation of the fuel burning technique and to reduce the CO release by increasing the efficiency of the combustion. To reduce the pollutant release during the operation phases and to increase the efficiency, products of incomplete combustion i.e. carbon monoxide, toxic organic compounds like benzene, polycyclic aromatic hydrocarbons and soot have to be minimised in a further extent. For that the following goals will be attained: improvement of the mixing process of combustion gases in the reaction zones, averaging the residence time spectrum in the burnout zone reduction, of emissions during initial and burnout phase in firings with batch-wise feeding reduction of emissions under partial-load conditions in firings with quasi-continuous feeding, higher combustion stability even in case of changing fuel qualities, defining guidelines for the design of stoves and boilers with low emissions and high efficiency. By the foreseen reduction of the pollutant release and improved efficiency the environmental acceptance of wood combustion firings can be increased and for instance local restrictions can be removed. The project is funded in part by The European Commission in the framework of The Non Nuclear Energy Programme. (orig.)

  12. Modeling of photochemical air pollution in the Barcelona area with highly disaggregated anthropogenic and biogenic emissions

    International Nuclear Information System (INIS)

    Toll, I.; Baldasano, J.M.

    2000-01-01

    The city of Barcelona and its surrounding area, located in the western Mediterranean basin, can reach high levels of O 3 in spring and summertime. To study the origin of this photochemical pollution, a numerical modeling approach was adopted and the episode that took place between 3 and 5 August 1990 was chosen. The main meteorological mesoscale flows were reproduced with the meteorological non-hydrostatic mesoscale model MEMO for 5 August 1990, when weak pressure synoptic conditions took place. The emissions inventory was calculated with the EIM-LEM model, giving highly disaggregated anthropogenic and biogenic emissions in the zone studied, an 80 x 80 km 2 area around the city of Barcelona. Major sources of VOC were road traffic (51%) and vegetation (34%), while NO x were mostly emitted by road traffic (88%). However, emissions from some industrial stacks can be locally important and higher than those from road traffic. Photochemical simulation with the MARS model revealed that the combination of mesoscale wind flows and the above-mentioned local emissions is crucial in the production and transport of O 3 in the area. On the other hand, the geostrophic wind also played an important role in advecting the air masses away from the places O 3 had been generated. The model simulations were also evaluated by comparing meteorological measurements from nine surface stations and concentration measurements from five surface stations, and the results proved to be fairly satisfactory. (author)

  13. Pollution concentration estimates in ecologically important zones

    Energy Technology Data Exchange (ETDEWEB)

    Skiba, Y.N. [Mexico City Univ. (Mexico). Center for Atmospheric Sciences

    1995-12-31

    Method based on using the pollutant transport equation and the adjoint technique is described here for estimating the pollutant concentration level in ecologically important zones. The method directly relates the pollution level in such zones with the power of the pollution sources and the initial pollution field. Assuming that the wind or current velocities are known (from climatic data or dynamic model), the main and adjoint pollutant transport equations can be considered in a limited area to solve such theoretically and practically important problems as: (1) optimal location of new industries in a given region with the aim to minimize the pollution concentration in certain ecologically important zones, (2) optimization of emissions from operating industries, (3) detection of the plants violating sanitary regulations, (4) analysis of the emissions coming from the vehicle traffic (such emissions can be included in the model by means of the linear pollution sources located along the main roadways), (5) estimation of the oil pollution in various ecologically important oceanic (sea) zones in case of accident with the oil tanker, (6) evaluation of the sea water desalination level in estuary regions, and others. These equations considered in a spherical shell domain can also be applied to the problems of transporting the pollutants from a huge industrial complex, or from the zone of an ecological catastrophe similar to the Chernobyl one

  14. Pollution concentration estimates in ecologically important zones

    Energy Technology Data Exchange (ETDEWEB)

    Skiba, Y N [Mexico City Univ. (Mexico). Center for Atmospheric Sciences

    1996-12-31

    Method based on using the pollutant transport equation and the adjoint technique is described here for estimating the pollutant concentration level in ecologically important zones. The method directly relates the pollution level in such zones with the power of the pollution sources and the initial pollution field. Assuming that the wind or current velocities are known (from climatic data or dynamic model), the main and adjoint pollutant transport equations can be considered in a limited area to solve such theoretically and practically important problems as: (1) optimal location of new industries in a given region with the aim to minimize the pollution concentration in certain ecologically important zones, (2) optimization of emissions from operating industries, (3) detection of the plants violating sanitary regulations, (4) analysis of the emissions coming from the vehicle traffic (such emissions can be included in the model by means of the linear pollution sources located along the main roadways), (5) estimation of the oil pollution in various ecologically important oceanic (sea) zones in case of accident with the oil tanker, (6) evaluation of the sea water desalination level in estuary regions, and others. These equations considered in a spherical shell domain can also be applied to the problems of transporting the pollutants from a huge industrial complex, or from the zone of an ecological catastrophe similar to the Chernobyl one

  15. High-Power Laser Cutting of Steel Plates: Heat Affected Zone Analysis

    Directory of Open Access Journals (Sweden)

    Imed Miraoui

    2016-01-01

    Full Text Available The thermal effect of CO2 high-power laser cutting on cut surface of steel plates is investigated. The effect of the input laser cutting parameters on the melted zone depth (MZ, the heat affected zone depth (HAZ, and the microhardness beneath the cut surface is analyzed. A mathematical model is developed to relate the output process parameters to the input laser cutting parameters. Three input process parameters such as laser beam diameter, cutting speed, and laser power are investigated. Mathematical models for the melted zone and the heat affected zone depth are developed by using design of experiment approach (DOE. The results indicate that the input laser cutting parameters have major effect on melted zone, heat affected zone, and microhardness beneath cut surface. The MZ depth, the HAZ depth, and the microhardness beneath cut surface increase as laser power increases, but they decrease with increasing cutting speed. Laser beam diameter has a negligible effect on HAZ depth but it has a remarkable effect on MZ depth and HAZ microhardness. The melted zone depth and the heat affected zone depth can be reduced by increasing laser cutting speed and decreasing laser power and laser beam diameter.

  16. X-ray Emission from the Guitar Nebula

    OpenAIRE

    Romani, Roger W.; Cordes, James M.; Yadigaroglu, I. -A.

    1997-01-01

    We have detected weak soft X-ray emission from the Pulsar Wind Nebula trailing the high velocity star PSR 2224+65 (the `Guitar Nebula'). This X-ray flux gives evidence of \\gamma~10^7 eV particles in the pulsar wind and constrains the properties of the post-shock flow. The X-ray emission is most easily understood if the shocked pulsar wind is partly confined in the nebula and if magnetic fields in this zone can grow to near equipartition values.

  17. X-Ray Emission from the Guitar Nebula

    Science.gov (United States)

    Romani, Roger W.; Cordes, James M.; Yadigaroglu, I.-A.

    1997-01-01

    We have detected weak soft X-ray emission from the pulsar wind nebula trailing the high-velocity star PSR 2224+65 (the "Guitar Nebula"). This X-ray flux gives evidence of gamma approximately 10(exp 7) eV particles in the pulsar wind and constrains the properties of the postshock flow. The X-ray emission is most easily understood if the shocked pulsar wind is partly confined in the nebula and if magnetic fields in this zone can grow to near-equipartition values.

  18. X-ray microscopy with high resolution zone plates -- Recent developments

    International Nuclear Information System (INIS)

    Schneider, G.; Wilhein, T.; Niemann, B.; Guttmann, P.

    1995-01-01

    In order to expand the applications of X-ray microscopy, developments in the fields of zone plate technology, specimen preparation and imaging techniques have been made. A new cross-linked polymer chain electron beam resist allows to record zone plate pattern down to 19 nm outermost zone width. High resolution zone plates in germanium with outermost zone widths down to 19 nm have been developed. In addition, phase zone plates in nickel down to 30 nm zone width have been made by electroplating. In order to enhance the image contrast for weak absorbing objects, the phase contrast method for X-ray microscopy was developed and implemented on the Goettingen X-ray microscope at BESSY. The effects of X-ray absorption on the structure of biological specimen limits the maximum applicable radiation dose and therefore the achievable signal to noise ratio for an artifact-free X-ray image. To improve the stability especially of biological specimen, a cryogenic object chamber has been developed and tested. It turns out that at the operating temperature T ≤ 130 K unfixed biological specimen can be exposed to a radiation dose of 10 9 --10 10 Gy without any observable structural changes. A multiple-angle viewing stage allows to take stereoscopic images with the X-ray microscope, giving a 3D-impression of the object

  19. Using an ultra-thin non-doped orange emission layer to realize high efficiency white organic light-emitting diodes with low efficiency roll-off

    Energy Technology Data Exchange (ETDEWEB)

    Zhu, Liping; Chen, Jiangshan; Ma, Dongge, E-mail: mdg1014@ciac.ac.cn [State Key Laboratory of Polymer Physics and Chemistry, Changchun Institute of Applied Chemistry, Chinese Academy of Sciences, Graduate University of the Chinese Academy of Sciences, Changchun 130022 (China); Zhao, Yongbiao [Luminous Center of Excellence for Semiconductor Lighting and Displays, School of Electrical and Electronic Engineering, Nanyang Technological University, 50 Nanyang Avenue, Singapore, Singapore 639798 (Singapore); Zhang, Hongmei [Department of Materials Science and Engineering, Nanjing University of Posts and Telecommunications, Nanjing 210023 (China)

    2014-06-28

    By adopting an ultra-thin non-doped orange emission layer sandwiched between two blue emission layers, high efficiency white organic light-emitting diodes (WOLEDs) with reduced efficiency roll-off were fabricated. The optimized devices show a balanced white emission with Internationale de L'Eclairage of (0.41, 0.44) at the luminance of 1000 cd/m{sup 2}, and the maximum power efficiency, current efficiency (CE), and external quantum efficiency reach 63.2 lm/W, 59.3 cd/A, and 23.1%, which slightly shift to 53.4 lm/W, 57.1 cd/A, and 22.2% at 1000 cd/m{sup 2}, respectively, showing low efficiency roll-off. Detailed investigations on the recombination zone and the transient electroluminescence (EL) clearly reveal the EL processes of the ultra-thin non-doped orange emission layer in WOLEDs.

  20. Characterization of leached surface layers on simulated high-level waste glasses by sputter-induced optical emission

    International Nuclear Information System (INIS)

    Houser, C.; Tsong, I.S.T.; White, W.B.

    1979-01-01

    The leaching process in simulated waste encapsulant glasses was studied by measuring the compositional depth-profiles of H (from water), the glass framework formers Si and B, the alkalis Na and Cs, the alkaline earths Ca and Sr, the transition metals Mo and Fe, the rare-earths La, Ce, and Nd, using the technique of sputter-induced optical emission. The leaching process of these glasses is highly complex. In addition to alkali/hydrogen exchange, there is breakdown of the glass framework, build-up of barrier layers on the surface, and formation of layered reaction zones of distinctly different chemistry all within the outer micrometer of the glass

  1. High spatial resolution X-UV Fresnel zone plates imaging; Imagerie a haute resolution spatiale dans le domaine X-UV a l'aide de lentilles a zone de Fresnel

    Energy Technology Data Exchange (ETDEWEB)

    Pichet-Thomasset, M

    1999-07-01

    The goal of this work is to study the capabilities of imaging of Fresnel zone plates in the 1.5. and 2 keV X-ray range for the imaging of laser-produced plasmas. The diagnostic is composed of a Fresnel zone plate with good imaging capabilities and a multilayer mirror to select the spectral emission bandwidth of the plasma we want to study. This diagnostic was evaluated at the Centre d'Etudes de Limeil-Valenton experiments to study spatial resolution with this kind of X-ray source. The images we obtained showed that there is no geometric aberrations over an object field of several millimetre. Fresnen zone plates are often used for monochromatic biological objects imaging in the water window around 400 eV but they offer large prospects for laser produced plasma imaging. (author)

  2. The spatial distribution of commuting CO2 emissions and the influential factors: A case study in Xi'an, China

    Directory of Open Access Journals (Sweden)

    Yuan-Yuan Liu

    2015-03-01

    Full Text Available As the transport sector is a major source of greenhouse gas emissions, the effect of urbanization on transport CO2 emissions in developing cities has become a key issue under global climate change. Examining the case of Xi'an, this paper aims to explore the spatial distribution of commuting CO2 emissions and influencing factors in the new, urban industry zones and city centers considering Xi'an's transition from a monocentric to a polycentric city in the process of urbanization. Based on household survey data from 1501 respondents, there are obvious differences in commuting CO2 emissions between new industry zones and city centers: City centers feature lower household emissions of 2.86 kg CO2 per week, whereas new industry zones generally have higher household emissions of 3.20 kg CO2 per week. Contrary to previous research results, not all new industry zones have high levels of CO2 emissions; with the rapid development of various types of industries, even a minimum level of household emissions of 2.53 kg CO2 per week is possible. The uneven distribution of commuting CO2 emissions is not uniformly affected by spatial parameters such as job–housing balance, residential density, employment density, and land use diversity. Optimum combination of the spatial parameters and travel pattern along with corresponding transport infrastructure construction may be an appropriate path to reduction and control of emissions from commuting.

  3. Assessing the optimality of ASHRAE climate zones using high resolution meteorological data sets

    Science.gov (United States)

    Fils, P. D.; Kumar, J.; Collier, N.; Hoffman, F. M.; Xu, M.; Forbes, W.

    2017-12-01

    Energy consumed by built infrastructure constitutes a significant fraction of the nation's energy budget. According to 2015 US Energy Information Agency report, 41% of the energy used in the US was going to residential and commercial buildings. Additional research has shown that 32% of commercial building energy goes into heating and cooling the building. The American National Standards Institute and the American Society of Heating Refrigerating and Air-Conditioning Engineers Standard 90.1 provides climate zones for current state-of-practice since heating and cooling demands are strongly influenced by spatio-temporal weather variations. For this reason, we have been assessing the optimality of the climate zones using high resolution daily climate data from NASA's DAYMET database. We analyzed time series of meteorological data sets for all ASHRAE climate zones between 1980-2016 inclusively. We computed the mean, standard deviation, and other statistics for a set of meteorological variables (solar radiation, maximum and minimum temperature)within each zone. By plotting all the zonal statistics, we analyzed patterns and trends in those data over the past 36 years. We compared the means of each zone to its standard deviation to determine the range of spatial variability that exist within each zone. If the band around the mean is too large, it indicates that regions in the zone experience a wide range of weather conditions and perhaps a common set of building design guidelines would lead to a non-optimal energy consumption scenario. In this study we have observed a strong variation in the different climate zones. Some have shown consistent patterns in the past 36 years, indicating that the zone was well constructed, while others have greatly deviated from their mean indicating that the zone needs to be reconstructed. We also looked at redesigning the climate zones based on high resolution climate data. We are using building simulations models like EnergyPlus to develop

  4. High-Resolution X-ray Emission and X-ray Absorption Spectroscopy

    NARCIS (Netherlands)

    Groot, F.M.F. de

    2000-01-01

    In this review, high-resolution X-ray emission and X-ray absorption spectroscopy will be discussed. The focus is on the 3d transition-metal systems. To understand high-resolution X-ray emission and reso-nant X-ray emission, it is first necessary to spend some time discussing the X-ray absorption

  5. Multi-zone modeling of combustion and emissions formation in DI diesel engine operating on ethanol-diesel fuel blends

    International Nuclear Information System (INIS)

    Rakopoulos, C.D.; Antonopoulos, K.A.; Rakopoulos, D.C.; Hountalas, D.T.

    2008-01-01

    A multi-zone model for calculation of the closed cycle of a direct injection (DI) diesel engine is applied for the interesting case of its operation with ethanol-diesel fuel blends, the ethanol (bio-fuel) being considered recently as a promising extender to petroleum distillates. Although there are many experimental studies, there is an apparent scarcity of theoretical models scrutinizing the formation mechanisms of combustion generated emissions when using bio-fuels. This is a two dimensional, multi-zone model with the issuing fuel jets divided into several discrete volumes, called 'zones', formed along and across the direction of the fuel injection. The model follows each zone, with its own time history, as the spray penetrates into the swirling air environment of the combustion chamber. Droplet evaporation and jet mixing models are used to determine the amount of fuel and entrained air in each zone available for combustion. The mass, energy and state equations are applied in each zone to provide local temperatures and cylinder pressure histories. The concentrations of the various constituents are calculated by adopting a chemical equilibrium scheme for the C-H-O-N system of eleven species considered, together with chemical rate equations for calculation of nitric oxide (NO) and a model for net soot formation. The results from the computer program, implementing the analysis, for the in cylinder pressure, exhaust NO concentration and soot density compare well with the corresponding measurements from an experimental investigation conducted on a fully automated test bed, standard 'Hydra', DI diesel engine located at the authors' laboratory, which is operated with ethanol-diesel fuel blends containing 5%, 10% and 15% (by vol.) ethanol. Iso-contour plots of equivalence ratio, temperature, NO and soot inside the cylinder at various instants of time, when using these ethanol-diesel fuel blends against the diesel fuel (baseline fuel), shed light on the mechanisms

  6. Assessment of Eco-Environmental Stress in the Western Taiwan Straits Economic Zone

    Directory of Open Access Journals (Sweden)

    Longyu Shi

    2015-03-01

    Full Text Available Eco-environmental stress refers to the pressure borne by the environment in sustaining the pre-existing non-industrialized state and/or in counteracting adverse impacts caused by natural and human factors. The present article introduces the concept, research progress, and method for assessing eco-environmental stress. An eco-environmental stress index (ESI is established to assess the eco-environmental stress of 13 cities in the Western Taiwan Straits Economic Zone (hereafter referred to as the Economic Zone during the period from 2000 to 2010. The research provides a reference for the strategic planning of industrial development and environmental protection. The results show that the overall eco-environmental stress of the Economic Zone was slight and did not have significant change during the past 10 years. The cities with the most severe eco-environmental stress are distributed in the north and south of the Economic Zone. Most areas of Fujian Province have a low degree of eco-environmental stress, a situation that is being constantly improved. The regions with high atmospheric and water pollutant emissions are concentrated in the northern, middle, and southern coastal regions of the Economic Zone. The pollutant emissions of coastal cities are higher than those of inland cities. In the future, ecological restoration and compensation mechanisms should be established for regions where environmental protection and remediation is urgently needed.

  7. Volcanic gas emissions and degassing dynamics at Ubinas and Sabancaya volcanoes; implications for the volatile budget of the central volcanic zone

    Science.gov (United States)

    Moussallam, Yves; Tamburello, Giancarlo; Peters, Nial; Apaza, Fredy; Schipper, C. Ian; Curtis, Aaron; Aiuppa, Alessandro; Masias, Pablo; Boichu, Marie; Bauduin, Sophie; Barnie, Talfan; Bani, Philipson; Giudice, Gaetano; Moussallam, Manuel

    2017-09-01

    Emission of volcanic gas is thought to be the dominant process by which volatiles transit from the deep earth to the atmosphere. Volcanic gas emissions, remain poorly constrained, and volcanoes of Peru are entirely absent from the current global dataset. In Peru, Sabancaya and Ubinas volcanoes are by far the largest sources of volcanic gas. Here, we report the first measurements of the compositions and fluxes of volcanic gases emitted from these volcanoes. The measurements were acquired in November 2015. We determined an average SO2 flux of 15.3 ± 2.3 kg s- 1 (1325-ton day- 1) at Sabancaya and of 11.4 ± 3.9 kg s- 1 (988-ton day- 1) at Ubinas using scanning ultraviolet spectroscopy and dual UV camera systems. In-situ Multi-GAS analyses yield molar proportions of H2O, CO2, SO2, H2S and H2 gases of 73, 15, 10 1.15 and 0.15 mol% at Sabancaya and of 96, 2.2, 1.2 and 0.05 mol% for H2O, CO2, SO2 and H2S at Ubinas. Together, these data imply cumulative fluxes for both volcanoes of 282, 30, 27, 1.2 and 0.01 kg s- 1 of H2O, CO2, SO2, H2S and H2 respectively. Sabancaya and Ubinas volcanoes together contribute about 60% of the total CO2 emissions from the Central Volcanic zone, and dominate by far the total revised volatile budget of the entire Central Volcanic Zone of the Andes.

  8. Small scale denitrification variability in riparian zones: Results from a high-resolution dataset

    Science.gov (United States)

    Gassen, Niklas; Knöller, Kay; Musolff, Andreas; Popp, Felix; Lüders, Tillmann; Stumpp, Christine

    2017-04-01

    Riparian zones are important compartments at the interface between groundwater and surface water where biogeochemical processes like denitrification are often enhanced. Nitrate loads of either groundwater entering a stream through the riparian zone or streamwater infiltrating into the riparian zone can be substantially reduced. These processes are spatially and temporally highly variable, making it difficult to capture solute variabilities, estimate realistic turnover rates and thus to quantify integral mass removal. A crucial step towards a more detailed characterization is to monitor solutes on a scale which adequately resemble the highly heterogeneous distribution and on a scale where processes occur. We measured biogeochemical parameters in a spatial high resolution within a riparian corridor of a German lowland river system over the course of one year. Samples were taken from three newly developed high-resolution multi-level wells with a maximum vertical resolution of 5 cm and analyzed for major ions, DOC and N-O isotopes. Sediment derived during installation of the wells was analyzed for specific denitrifying enzymes. Results showed a distinct depth zonation of hydrochemistry within the shallow alluvial aquifer, with a 1 m thick zone just below the water table with lower nitrate concentrations and EC values similar to the nearby river. Conservative parameters were consistent inbetween the three wells, but nitrate was highly variable. In addition, spots with low nitrate concentrations showed isotopic and microbial evidence for higher denitrification activities. The depth zonation was observed throughout the year, with stronger temporal variations of nitrate concentrations just below the water table compared to deeper layers. Nitrate isotopes showed a clear seasonal trend of denitrification activities (high in summer, low in winter). Our dataset gives new insight into river-groundwater exchange processes and shows the highly heterogeneous distribution of

  9. Particulate and carbon monoxide emissions from small scale firewood combustion

    International Nuclear Information System (INIS)

    Todd, J.J.

    1990-01-01

    One of the serious adverse effects of residential firewood use is the deterioration in air quality caused by wood-smoke. Low combustion zone temperatures, flame quenching, poor gas mixing, and lack of oxygen all contribute to relatively high emissions of particulates and CO. Average emission rates for particulates of 11 g/h for modern woodheaters can certainly be improved upon. More research effort is needed to reduce emissions from cooking stoves used in developing countries and more public information on correct heater use is needed in the developed countries. (author)

  10. Study of shifting of recombination zone in multi-emissive layer organic light emitting devices and its effect on color stability

    International Nuclear Information System (INIS)

    Tyagi, Priyanka; Srivastava, Ritu; Kumar, Arunandan; Tuli, Suneet; Kamalasanan, M.N.

    2013-01-01

    Color stability in multi-emissive layer organic light emitting devices (Me-OLEDs) has been investigated. Me-OLEDs were based on multiple emitters with a common host CBP doped with three dopants, BCzVBi, Ir(ppy) 3 and Ir(btp) 2 acac for blue, green and red emission. A major variation in CIE coordinates were found from (0.312, 0.294) to (0.236, 0.267) with increase in voltage from 6 to 9 V. This coordinate shift in Me-OLEDs has been attributed to the shifting of recombination zone with increase in voltage. In order to support our experimental observation, the EL spectrum of Me-OLEDs has been expressed as a linear combination of EL intensities of OLEDs with its individual constituting layers as emitters. In this way, the contribution of each layer in the EL spectrum of Me-OLEDs has been evaluated at each voltage. It has been observed from these calculations that the contribution of red emitter decreases from 47% to 33.33% and blue emitter increases from 38% to 51.67% with the increase in voltage from 6 to 9 V. This supports our hypothesis of shifting of recombination zone with the change in voltage. This shifting has been attributed to the field dependency of electron mobility in CBP. Me-OLED with CBP layers between the emitters was fabricated to improve the color stability. Significant improvement in color stability was achieved without changes in current efficiency in Me-OLED with interlayers. Highlights: ► Me-OLEDs have been fabricated by using three primary colors (RGB). ► CIE coordinates of these Me-OLEDs were voltage dependent. ► Analytical fitting has been performed to study the shifting of recombination zone. ► CBP interlayers have been introduced to improve the color stability. ► Color stability has been improved without any change in current efficiency

  11. High-resolution mapping of motor vehicle carbon dioxide emissions

    Science.gov (United States)

    McDonald, Brian C.; McBride, Zoe C.; Martin, Elliot W.; Harley, Robert A.

    2014-05-01

    A fuel-based inventory for vehicle emissions is presented for carbon dioxide (CO2) and mapped at various spatial resolutions (10 km, 4 km, 1 km, and 500 m) using fuel sales and traffic count data. The mapping is done separately for gasoline-powered vehicles and heavy-duty diesel trucks. Emission estimates from this study are compared with the Emissions Database for Global Atmospheric Research (EDGAR) and VULCAN. All three inventories agree at the national level within 5%. EDGAR uses road density as a surrogate to apportion vehicle emissions, which leads to 20-80% overestimates of on-road CO2 emissions in the largest U.S. cities. High-resolution emission maps are presented for Los Angeles, New York City, San Francisco-San Jose, Houston, and Dallas-Fort Worth. Sharp emission gradients that exist near major highways are not apparent when emissions are mapped at 10 km resolution. High CO2 emission fluxes over highways become apparent at grid resolutions of 1 km and finer. Temporal variations in vehicle emissions are characterized using extensive day- and time-specific traffic count data and are described over diurnal, day of week, and seasonal time scales. Clear differences are observed when comparing light- and heavy-duty vehicle traffic patterns and comparing urban and rural areas. Decadal emission trends were analyzed from 2000 to 2007 when traffic volumes were increasing and a more recent period (2007-2010) when traffic volumes declined due to recession. We found large nonuniform changes in on-road CO2 emissions over a period of 5 years, highlighting the importance of timely updates to motor vehicle emission inventories.

  12. High-Energy Emission from Rotation-Powered Pulsars

    Science.gov (United States)

    Harding, Alice K.

    2007-01-01

    Thirty-five years after the discovery of rotation-powered pulsars, we still do not understand their pulsed emission at any wavelength. In the last few years there have been some fundamental developments in acceleration and emission models. I will review both the basic physics of the models as well as the latest developments in understanding the high-energy emission of rotation-powered pulsars. Special and general relativistic effects play important roles in pulsar emission, from inertial frame-dragging near the stellar surface to aberration, time-of-flight and retardation of the magnetic field near the light cylinder. Understanding how these effects determine what we observe at different wavelengths is critical to unraveling the emission physics. Fortunately two new gamma-ray telescopes, AGILE and GLAST, with launches expected this year will detect many new gamma-ray pulsars and test the predictions of these models with unprecedented sensitivity and energy resolution for gamma-rays in the range of 30 MeV to 300 GeV.

  13. In-cylinder visualization and engine out emissions from CI to PPC for fuels with different properties

    KAUST Repository

    An, Yanzhao

    2018-02-27

    This study investigated the transition from conventional Compression Ignition (CI) to Partially Premixed Combustion (PPC) in an optical engine for fuels with differing properties. Combustion stratification and emissions were measured with diesel, naphtha and their corresponding surrogate fuels, N-heptane and PRF50. The aim of the study is to link the combustion images with engine out emissions and mixture homogeneity. Single injection strategy with the change of start of injection (SOI) from late to early injections was employed. Results show that combustion phasing trend is similar for diesel/N-heptane as well as for naphtha/PRF50 as the SOI moved from late injection timing to early injection timing. However, there is a significant difference in combustion phasing behavior for gasoline like fuels (naphtha and PRF50) and diesel fuels (diesel and N-heptane). CO emissions show an inverted V-shaped trend with one single peak in the transition zone. A “W” shape trend, with two bottoms at various dilution rates is observed for the UHC emissions. NOX emissions are high in the transition zone and decreased to lower levels in CI and PPC zones. NOX emissions are significantly reduced by reducing the intake O2 concentration with nitrogen. Except for diesel, the other three fuels show lower soot emissions. When compared to diesel like fuels, the natural luminosity of the images are lower for gasoline like fuels, indicating better premixed combustion. As the SOI is changed from CI to PPC mode, the combustion stratification increases towards a peak value in the transition zone and then decreases to a low level in PPC zone. A competition exists between the intake temperature and the dilution rate for the combustion stratification. The level of stratification is higher for real fuels (diesel and naphtha) when compared to surrogate fuel (N-heptane and PRF50).

  14. Reduced emissions from inexpensive high-sulphur coal briquettes

    International Nuclear Information System (INIS)

    Gammage, R.B.; Wachter, E.A.; Wade, J.; Wilson, D.L.; Haas, J.W.; Ahmad, N.; Siltain, F.; Raza, M.Z.

    1992-01-01

    Airborne emissions were measured during the combustion of Pakistani high-sulphur coal, cold briquetted with lime and clay; comparison was made to emissions from raw coal and traditional fuels burnt in a native, mud-lined Angethi stove. Compared to raw coal, the amended coal gave fourfold reduced emission of respirable-size particles (RSP) and threefold reduced total releases of SO 2 . In domestic cooking, substitution of the amended coal briquettes for traditional fuels will not worsen indoor air quality with respect to CO, SO 2 , NO x , and RSP. The high peak amounts of CO (100--250 ppm), SO 2 (2--5 ppm), and NO x (1--5 ppm) were limited to the early phase of burning. The high thermal value of the coal briquettes together with a simple briquetting technology, make this fuel an attractive energy alternative in countries that are underdeveloped, developing, or experiencing major restructuring

  15. Benzo(a)pyrene accumulation in soils of technogenic emission zone by subcritical water extraction method

    Science.gov (United States)

    Sushkova, Svetlana; Minkina, Tatiana; Kizilkaya, Ridvan; Mandzhieva, Saglara; Batukaev, Abdulmalik; Bauer, Tatiana; Gulser, Coskun

    2016-04-01

    The purpose of research is the assessment of main marker of polycyclic aromatic hydrocarbons contamination, benzo[a]pyrene (BaP) content in soils of emission zone of the power complex plant in soils with use of ecologically clean and effective subcritical water extraction method. Studies were conducted on the soils of monitoring plots subjected to Novocherkassk Power Plant emissions from burning coal. In 2000, monitoring plots were established at different distances from the NPS (1.0-20.0 km). Soil samples for the determination of soil properties and the contents of BaP were taken from a depth of 0-20 cm. The soil cover in the region under study consisted of ordinary chernozems, meadow-chernozemic soils, and alluvial meadow soils. This soil revealed the following physical and chemical properties: Corg-3.1-5.0%, pH-7.3-7.6, ECE-31.2-47.6 mmol(+)/100g; CaCO3-0.2-1.0%, the content of physical clay - 51-67% and clay - 3-37%. BaP extraction from soils was carried out by a subcritical water extraction method. Subcritical water extraction of BaP from soil samples was conducted in a specially developed extraction cartridge made of stainless steel and equipped with screw-on caps at both ends. It was also equipped with a manometer that included a valve for pressure release to maintain an internal pressure of 100 atm. The extraction cartridge containing a sample and water was placed into an oven connected to a temperature regulator under temperature 250oC and pressure 60 atm. The BaP concentration in the acetonitrile extract was determined by HPLC. The efficiency of BaP extraction from soil was determined using a matrix spike. The main accumulation of pollutant in 20 cm layer of soils is noted directly in affected zone on the plots situated at 1.2, 1.6, 5.0, 8.0 km from emission source in the direction of prevailing winds. The maximum quantity of a pollutant was founded in the soil of the plot located mostly close to a source of pollution in the direction of prevailing winds

  16. CONSTRAINTS ON VERY HIGH ENERGY EMISSION FROM GRB 130427A

    International Nuclear Information System (INIS)

    Aliu, E.; Errando, M.; Aune, T.; Barnacka, A.; Beilicke, M.; Buckley, J. H.; Bugaev, V.; Benbow, W.; Cerruti, M.; Berger, K.; Biteau, J.; Byrum, K.; Cardenzana, J. V; Dickinson, H. J.; Eisch, J. D.; Chen, X.; Ciupik, L.; Connaughton, V.; Cui, W.; Falcone, A.

    2014-01-01

    Prompt emission from the very fluent and nearby (z = 0.34) gamma-ray burst GRB 130427A was detected by several orbiting telescopes and by ground-based, wide-field-of-view optical transient monitors. Apart from the intensity and proximity of this GRB, it is exceptional due to the extremely long-lived high-energy (100 MeV to 100 GeV) gamma-ray emission, which was detected by the Large Area Telescope on the Fermi Gamma-Ray Space Telescope for ∼70 ks after the initial burst. The persistent, hard-spectrum, high-energy emission suggests that the highest-energy gamma rays may have been produced via synchrotron self-Compton processes though there is also evidence that the high-energy emission may instead be an extension of the synchrotron spectrum. VERITAS, a ground-based imaging atmospheric Cherenkov telescope array, began follow-up observations of GRB 130427A ∼71 ks (∼20 hr) after the onset of the burst. The GRB was not detected with VERITAS; however, the high elevation of the observations, coupled with the low redshift of the GRB, make VERITAS a very sensitive probe of the emission from GRB 130427A for E > 100 GeV. The non-detection and consequent upper limit derived place constraints on the synchrotron self-Compton model of high-energy gamma-ray emission from this burst

  17. High-redshift SDSS Quasars with Weak Emission Lines

    DEFF Research Database (Denmark)

    Diamond-Stanic, Aleksandar M.; Fan, Xiaohui; Brandt, W. N.

    2009-01-01

    We identify a sample of 74 high-redshift quasars (z > 3) with weak emission lines from the Fifth Data Release of the Sloan Digital Sky Survey and present infrared, optical, and radio observations of a subsample of four objects at z > 4. These weak emission-line quasars (WLQs) constitute a promine...

  18. Inventory of natural emissions in the Mediterranean region: application to the establishment of detailed cadastral surveys of the Marseille-Berre area in the framework of the Escompte project. On-site determination of emission factors specific of the studied area; Inventaire des emissions naturelles en region mediterraneenne: application a l'etablissement de cadastres detailles de la zone Marseille-Berre dans le cadre du projet Escompte. Determination sur site de facteurs d'emission specifiques a la zone d'etude

    Energy Technology Data Exchange (ETDEWEB)

    Dumergues, L.

    2003-12-01

    The natural emissions, which gather Volatile Organic compounds (VOC) as well as nitrogen and sulphur compounds, take part in the physico-chemistry of the atmosphere. Qualitative and quantitative knowledge such emissions are essential to understand phenomena of pollution such as the tropospheric ozone formation. The work carried out in the frame of the ESCOMPTE project, provide a series of results as for example: - the inventory of the main natural sources of organic and inorganic compounds in a Mediterranean zone and the development of suitable algorithms of emission for each sources. - the daily and annual estimate of the natural emissions in the Marseille area by application of mathematical models. - the validation of the results and the sensitivity of algorithmic factors of one of the most important biotic sources: the forest. - the determination, during campaigns on Mediterranean sites, of rates and flows of terpenic emission of Quercus pubescens, Pinus halepensis and garrigue from the Cuvette and the aerodynamic gradient method. (author)

  19. High Arctic Nitrous Oxide Emissions Found on Large Spatial Scales

    Science.gov (United States)

    Wilkerson, J. P.; Sayres, D. S.; Dobosy, R.; Anderson, J. G.

    2017-12-01

    As the planet warms, greenhouse gas emissions from thawing permafrost can potentially increase the net radiative forcing in our climate structure. However, knowledge about Arctic N2O emissions is particularly sparse. Increasing evidence suggests emissions from permafrost thaw may be a significant natural source of N2O. This evidence, though, is either based on lab experiments or in situ chamber studies, which have extremely limited spatial coverage. Consequently, it has not been confirmed to what extent these high emissions are representative of broader arctic regions. Using an airborne eddy covariance flux technique, we measured N2O fluxes over large regions of Alaska in August 2013. From these measurements, we directly show that large areas of this Arctic region have high N2O emissions.

  20. High exhaust temperature, zoned, electrically-heated particulate matter filter

    Science.gov (United States)

    Gonze, Eugene V.; Paratore, Jr., Michael J.; Bhatia, Garima

    2015-09-22

    A system includes a particulate matter (PM) filter, an electric heater, and a control circuit. The electric heater includes multiple zones, which each correspond to longitudinal zones along a length of the PM filter. A first zone includes multiple discontinuous sub-zones. The control circuit determines whether regeneration is needed based on an estimated level of loading of the PM filter and an exhaust flow rate. In response to a determination that regeneration is needed, the control circuit: controls an operating parameter of an engine to increase an exhaust temperature to a first temperature during a first period; after the first period, activates the first zone; deactivates the first zone in response to a minimum filter face temperature being reached; subsequent to deactivating the first zone, activates a second zone; and deactivates the second zone in response to the minimum filter face temperature being reached.

  1. High-frequency and time resolution rocket observations of structured low- and medium-frequency whistler mode emissions in the auroral ionosphere

    Science.gov (United States)

    LaBelle, J.; McAdams, K. L.; Trimpi, M. L.

    High bandwidth electric field waveform measurements on a recent auroral sounding rocket reveal structured whistler mode signals at 400-800 kHz. These are observed intermittently between 300 and 500 km with spectral densities 0-10 dB above the detection threshold of 1.5×10-11V2/m2Hz. The lack of correlation with local particle measurements suggests a remote source. The signals are composed of discrete structures, in one case having bandwidths of about 10 kHz and exhibiting rapid frequency variations of the order of 200 kHz per 100 ms. In one case, emissions near the harmonic of the whistler mode signals are detected simultaneously. Current theories of auroral zone whistler mode emissions have not been applied to explain quantitatively the fine structure of these signals, which resemble auroral kilometric radiation (AKR) rather than auroral hiss.

  2. 33 CFR 165.121 - Safety and Security Zones: High Interest Vessels, Narragansett Bay, Rhode Island.

    Science.gov (United States)

    2010-07-01

    ... 33 Navigation and Navigable Waters 2 2010-07-01 2010-07-01 false Safety and Security Zones: High... COAST GUARD, DEPARTMENT OF HOMELAND SECURITY (CONTINUED) PORTS AND WATERWAYS SAFETY REGULATED NAVIGATION... Guard District § 165.121 Safety and Security Zones: High Interest Vessels, Narragansett Bay, Rhode...

  3. Mechanical Properties of Heat Affected Zone of High Strength Steels

    Science.gov (United States)

    Sefcikova, K.; Brtnik, T.; Dolejs, J.; Keltamaki, K.; Topilla, R.

    2015-11-01

    High Strength Steels became more popular as a construction material during last decade because of their increased availability and affordability. On the other hand, even though general use of Advanced High Strength Steels (AHSS) is expanding, the wide utilization is limited because of insufficient information about their behaviour in structures. The most widely used technique for joining steels is fusion welding. The welding process has an influence not only on the welded connection but on the area near this connection, the so-called heat affected zone, as well. For that reason it is very important to be able to determine the properties in the heat affected zone (HAZ). This area of investigation is being continuously developed in dependence on significant progress in material production, especially regarding new types of steels available. There are currently several types of AHSS on the world market. Two most widely used processes for AHSS production are Thermo-Mechanically Controlled Processing (TMCP) and Quenching in connection with Tempering. In the presented study, TMCP and QC steels grade S960 were investigated. The study is focused on the changes of strength, ductility, hardness and impact strength in heat affected zone based on the used amount of heat input.

  4. Localities With Elevated Radiation Background in the High Karst Zone of Montenegro

    International Nuclear Information System (INIS)

    Vukotic, P.; Svrkota, R.; Andjelic, T.; Zekic, R.; Antovic, N.

    2011-01-01

    Research aimed to find localities in Montenegro with an elevated terrestrial gamma background was conducted during the period 2008-2009. For this purpose, 138 localities which have geological formations known to contain minerals with potentially high concentrations of U, Th and K, were selected throughout the country for a dosimetric survey. There are four distinctive geotectonic units in Montenegro: the Adriatic-Ionian Zone (JZ), the Budva-Cukali Zone (BZ), the High Karst Zone (VK), and the Durmitor Tectonic Unit (DTJ). The central and southern parts of Montenegro belong to the VK zone, whose geological structure is predominated by Mesozoic carbonate sediments, with occurrences of red and white bauxite formations, Triassic volcanic rocks, Paleogene flysch sediments and Quaternary sediments. In total, 38 localities belonging to the VK zone were selected for field investigations of terrestrial radiation. Knowing from earlier investigations that in Montenegro the average absorbed dose-rate in the air, 1 m above the ground, is 55 nGy/h, it was arbitrarily adopted that only localities with absorbed doses at least 50 % above this average value would be considered as having a relatively elevated radiation background. Field measurements have shown that 12 of the surveyed localities in the VK zone have such elevated dose values, five of them being with the highest dose rates in Montenegro. Among these five sites, the highest dose rate (192 nGy/h) was found at a locality which lies on andesite volcanic rock, while the other four localities (131 - 149 nGy/h) lie on bauxite deposits. Compared to the other areas in the world known to have a high natural radiation background, all of these localities in Montenegro have a moderately elevated radiation level. From the 12 localities with a relatively elevated radiation background, soil samples have been collected and analyzed by gamma spectrometry to determine activity concentrations of 40K, 232Th, 235U, 238U, 226Ra and 137Cs

  5. Development of biogenic VOC emission inventories for the boreal forest

    Energy Technology Data Exchange (ETDEWEB)

    Tarvainen, V.

    2008-07-01

    The volatile organic compounds (VOCs) emitted by vegetation, especially forests, can affect local and regional atmospheric photochemistry through their reactions with atmospheric oxidants. Their reaction products may also participate in the formation and growth of new particles which affect the radiation balance of the atmosphere, and thus climate, by scattering and absorbing shortwave and longwave radiation and by modifying the radiative properties, amount and lifetime of clouds. Globally, anthropogenic VOC emissions are far surpassed by the biogenic ones, making biogenic emission inventories an integral element in the development of efficient air quality and climate strategies. The inventories are typically constructed based on landcover information, measured emissions of different plants or vegetation types, and empirical dependencies of the emissions on environmental variables such as temperature and light. This thesis is focused on the VOC emissions from the boreal forest, the largest terrestrial biome with characteristic vegetation patterns and strong seasonality. The isoprene, monoterpene and sesquiterpene emissions of the most prevalent boreal tree species in Finland, Scots pine, have been measured and their seasonal variation and dependence on temperature and light have been studied. The measured emission data and other available observations of the emissions of the principal boreal trees have been used in a biogenic emission model developed for the boreal forests in Finland. The model utilizes satellite landcover information, Finnish forest classification and hourly meteorological data to calculate isoprene, monoterpene, sesquiterpene and other VOC emissions over the growing season. The principal compounds emitted by Scots pine are DELTA3-carene and alpha-pinene in the south boreal zone and alpha- and beta-pinene in the north boreal zone. The monoterpene emissions are dependent on temperature and have a clear seasonal cycle with high emissions in spring

  6. Zone-plate coded imaging of thermonuclear burn

    International Nuclear Information System (INIS)

    Ceglio, N.M.

    1978-01-01

    The first high-resolution, direct images of the region of thermonuclear burn in laser fusion experiments have been produced using a novel, two-step imaging technique called zone-plate coded imaging. This technique is extremely versatile and well suited for the microscopy of laser fusion targets. It has a tomographic capability, which provides three-dimensional images of the source distribution. It is equally useful for imaging x-ray and particle emissions. Since this technique is much more sensitive than competing imaging techniques, it permits us to investigate low-intensity sources

  7. Water sources accessed by arid zone riparian trees in highly saline environments, Australia.

    Science.gov (United States)

    Costelloe, Justin F; Payne, Emily; Woodrow, Ian E; Irvine, Elizabeth C; Western, Andrew W; Leaney, Fred W

    2008-05-01

    The flow regimes of arid zone rivers are often highly variable, and shallow groundwater in the alluvial aquifers can be very saline, thus constraining the availability and quality of the major water sources available to riparian trees-soil water, shallow groundwater and stream water. We have identified water sources and strategies used by riparian trees in more highly saline and arid conditions than previously studied for riparian trees of arid zone rivers. Our research focused on the riparian species Eucalyptus coolabah, one of the major riparian trees of ephemeral arid zone rivers in Australia. The water sources available to this riparian tree were examined using delta(18)O isotope data from xylem, soil water, groundwater and surface water. Additionally, soil chloride and matric potential data were used to infer zones of water availability for root uptake. Despite the saline conditions, the trees used a mixture of soil water and groundwater sources, but they did not use surface water directly. The study identified three strategies used to cope with typically high groundwater and soil water salinities. Firstly, the trees preferentially grow in zones of most frequent flushing by infiltrating streamflow, such as the bank-tops of channels. Secondly, the trees limit water use by having low transpiration rates. Thirdly, the trees are able to extract water at very low osmotic potentials, with water uptake continuing at chloride concentrations of at least 20,000-30,000 mg L(-1).

  8. Amplified spontaneous emission and laser emission from a high optical-gain medium of dye-doped dendrimer

    International Nuclear Information System (INIS)

    Yokoyama, Shiyoshi; Nakahama, Tatsuo; Mashiko, Shinro

    2005-01-01

    We measured the amplified spontaneous emission and laser emission from high-gain media of laser-dye encapsulated dendrimers. A highly branched poly(amidoamine) (PAMAM-OH) dendrimer formed a guest-host complex with a conventional laser-dye (DCM), resulting in a high optical-gain. Of particular note was the appearance of a laser threshold, above which a super-narrowed laser spectrum was observed, although laser feedback was caused without any mirror cavity devices. The optical feedback was attributed to spatial confinement of the light due to gain guiding under optical excitation. The laser spectrum clearly indicated a resonant laser-mode with a spectrum linewidth of less than 0.1 nm. This order of spectrum narrowing is comparable to that seen in the laser emission from ordinary laser devices

  9. Nitrous oxide emissions from wastewater treatment processes

    Science.gov (United States)

    Law, Yingyu; Ye, Liu; Pan, Yuting; Yuan, Zhiguo

    2012-01-01

    Nitrous oxide (N2O) emissions from wastewater treatment plants vary substantially between plants, ranging from negligible to substantial (a few per cent of the total nitrogen load), probably because of different designs and operational conditions. In general, plants that achieve high levels of nitrogen removal emit less N2O, indicating that no compromise is required between high water quality and lower N2O emissions. N2O emissions primarily occur in aerated zones/compartments/periods owing to active stripping, and ammonia-oxidizing bacteria, rather than heterotrophic denitrifiers, are the main contributors. However, the detailed mechanisms remain to be fully elucidated, despite strong evidence suggesting that both nitrifier denitrification and the chemical breakdown of intermediates of hydroxylamine oxidation are probably involved. With increased understanding of the fundamental reactions responsible for N2O production in wastewater treatment systems and the conditions that stimulate their occurrence, reduction of N2O emissions from wastewater treatment systems through improved plant design and operation will be achieved in the near future. PMID:22451112

  10. Heat affected zone and fatigue crack propagation behavior of high performance steel

    International Nuclear Information System (INIS)

    Choi, Sung Won; Kang, Dong Hwan; Kim, Tae Won; Lee, Jong Kwan

    2009-01-01

    The effect of heat affected zone in high performance steel on fatigue crack propagation behavior, which is related to the subsequent microstructure, was investigated. A modified Paris-Erdogan equation was presented for the analysis of fatigue crack propagation behavior corresponding to the heat affected zone conditions. Fatigue crack propagation tests under 0.3 stress ratio and 0.1 load frequency were conducted for both finegrained and coarse-grained heat affected zones, respectively. As shown in the results, much higher crack growth rate occurred in a relatively larger mean grain size material under the same stress intensity range of fatigue crack propagation process for the material.

  11. RE Data Explorer: Supporting Renewable Energy Zones to Enable Low Emission Development

    Energy Technology Data Exchange (ETDEWEB)

    Cox, Sadie

    2016-10-01

    This fact sheet overviews the benefits of using the RE Data Explorer tool to analyze and develop renewable energy zones. Renewable energy zones are developed through a transmission planning and approval process customized for renewable energy. RE Data Explorer analysis can feed into broader stakeholder discussions and allow stakeholders to easily visualize potential zones. Stakeholders can access pertinent data to inform transmission planning and enable investment.

  12. A hybrid nanoantenna for highly enhanced directional spontaneous emission

    Energy Technology Data Exchange (ETDEWEB)

    Chou, R. Yuanying; Lu, Guowei, E-mail: guowei.lu@pku.edu.cn; Shen, Hongming; He, Yingbo; Cheng, Yuqing [State Key Laboratory for Mesoscopic Physics, Department of Physics, Peking University, Beijing 100871 (China); Perriat, Pascal [MATEIS, UMR 5510 CNRS, INSA-Lyon, Université de Lyon, Villeurbanne Cedex 69621 (France); Martini, Matteo; Tillement, Olivier [ILM, UMR 5306 CNRS, Université de Lyon, Villeurbanne Cedex 69622 (France); Gong, Qihuang [State Key Laboratory for Mesoscopic Physics, Department of Physics, Peking University, Beijing 100871 (China); Collaborative Innovation Center of Quantum Matter, Beijing 100871 (China)

    2014-06-28

    Spontaneous emission modulated by a hybrid plasmonic nanoantenna has been investigated by employing finite-difference time-domain method. The hybrid nanoantenna configurations constituted by a gap hot-spot and of a plasmonic corrugated grating and a metal reflector sandwiching a SiO{sub 2} thin layer which appears promising for high spontaneous emission enhancement devices. Simulation assays show that the coupling between the gap-antenna and plasmonic corrugations reaches an ultra-high near-field enhancement factor in the excitation process. Moreover, concerning the emission process, the corrugations concentrate the far-field radiated power within a tiny angular volume, offering unprecedented collection efficiency. In the past decades, many kinds of optical antennas have been proposed and optimized to enhance single molecule detection. However, the excitation enhancement effect for single individual or dimmer plasmonic nanostructure is limited due to intrinsic nonradiative decay of the nanoparticle plasmon and quantum tunneling effect. The proposed hybrid configuration overwhelms the enhancement limit of single individual plasmonic structure. The findings provide an insight into spontaneous emission high enhancement through integrating the functions of different metallic nanostructures.

  13. A hybrid nanoantenna for highly enhanced directional spontaneous emission

    International Nuclear Information System (INIS)

    Chou, R. Yuanying; Lu, Guowei; Shen, Hongming; He, Yingbo; Cheng, Yuqing; Perriat, Pascal; Martini, Matteo; Tillement, Olivier; Gong, Qihuang

    2014-01-01

    Spontaneous emission modulated by a hybrid plasmonic nanoantenna has been investigated by employing finite-difference time-domain method. The hybrid nanoantenna configurations constituted by a gap hot-spot and of a plasmonic corrugated grating and a metal reflector sandwiching a SiO 2 thin layer which appears promising for high spontaneous emission enhancement devices. Simulation assays show that the coupling between the gap-antenna and plasmonic corrugations reaches an ultra-high near-field enhancement factor in the excitation process. Moreover, concerning the emission process, the corrugations concentrate the far-field radiated power within a tiny angular volume, offering unprecedented collection efficiency. In the past decades, many kinds of optical antennas have been proposed and optimized to enhance single molecule detection. However, the excitation enhancement effect for single individual or dimmer plasmonic nanostructure is limited due to intrinsic nonradiative decay of the nanoparticle plasmon and quantum tunneling effect. The proposed hybrid configuration overwhelms the enhancement limit of single individual plasmonic structure. The findings provide an insight into spontaneous emission high enhancement through integrating the functions of different metallic nanostructures.

  14. Black hole emission process in the high energy limit

    Energy Technology Data Exchange (ETDEWEB)

    Carter, B [Observatoire de Paris, Section de Meudon, 92 (France). Groupe d' Astrophysique Relativiste; Gibbons, G W; Lin, D N.C.; Perry, M J [Cambridge Univ. (UK). Dept. of Applied Mathematics and Theoretical Physics; Cambridge Univ. (UK). Inst. of Astronomy)

    1976-11-01

    The ultimate outcome of the Hawking process of particle emission by small black holes is discussed in terms of the various conceivable theories of the behaviour of matter in the ultra-high temperature limit. It is shown that if high temperature matter is described by a relatively hard equation of state with an adiabatic index GAMMA greater than 6/5 then interactions between particles can probably be ignored so that the rate of creation will continue to be describable by Hawking's method. On the other hand for softer equations of state (including those of the ultra soft Hagedorn type) the created matter will almost certainly be highly opaque and a hydrodynamic model of the emission process will be more appropriate. Actual astronomical detection of the final emission products might in principle have provided valuable information about the correct theory of ultra high energy physics but it is shown that in practice the black hole death rate is so low that observational distinction of the resulting high energy decay products from the background would require high resolution detectors.

  15. Evolution and application of a pseudo-multi-zone model for the prediction of NOx emissions from large-scale diesel engines at various operating conditions

    International Nuclear Information System (INIS)

    Savva, Nicholas S.; Hountalas, Dimitrios T.

    2014-01-01

    Highlights: • Development of a simplified simulation model for NO x formation during combustion. • Application of the proposed model on large-scale two and four-stroke diesel engines. • Experimental data from stationary and ship main and auxiliary engines were used. • The model captures the trend of NO x as engine power and fuel injection timing varies. • The model is recommended for research and practical use in maritime and power industry. - Abstract: Emissions regulations for heavy-duty diesel units used in maritime and power generation applications have become very strict the last years. Hence, the industry is enforced to limit specific gaseous and particulate emissions (NO x , SO x , CO x , PM and HC) depending on the regulations. Among numerous methods, simulation models are extensively used to support the development of techniques used for the control of emitted pollutants. This is very important for large-scale engines due to the extremely high cost of the experimental investigation resulting from the size of the engines and the test equipment involved. Beyond this, simulation models can also be used to support NO x monitoring, since on-board verification techniques are to become mandatory for the marine industry in the near future. Last but not least, simulation models can also be used for model-based control applications to support the operation of both in-cylinder and after-treatment techniques. Currently, the major controlled pollutant for both marine and stationary applications is NO x . For this reason, in the present work, authors focus on the development and application of a simplified NO x model with special emphasis on its ability to predict the effect of operating conditions on NO x for both two and four-stroke diesel engines. To accomplish this, an existing well validated simplified NO x model has been modified to enhance its physical background and applied on 16 different large-scale diesel engines utilizing 18 different sets of

  16. Allowable carbon emissions for medium-to-high mitigation scenarios

    Energy Technology Data Exchange (ETDEWEB)

    Tachiiri, Kaoru; Hargreaves, Julia C.; Annan, James D.; Kawamiya, Michio [Research Inst. for Global Change, Japan Agency for Marine-Earth Science and Technology, Yokohama, (Japan)], e-mail: tachiiri@jamstec.go.jp; Huntingford, Chris [Centre for Ecology and Hydrology, Wallingford (United Kingdom)

    2013-11-15

    Using an ensemble of simulations with an intermediate complexity climate model and in a probabilistic framework, we estimate future ranges of carbon dioxide (CO{sub 2}) emissions in order to follow three medium-high mitigation concentration pathways: RCP2.6, RCP4.5 and SCP4.5 to 2.6. Uncertainty is first estimated by allowing modelled equilibrium climate sensitivity, aerosol forcing and intrinsic physical and biogeochemical processes to vary within widely accepted ranges. Results are then constrained by comparison against contemporary measurements. For both constrained and unconstrained projections, our calculated allowable emissions are close to the standard (harmonised) emission scenarios associated with these pathways. For RCP4.5, which is the most moderate scenario considered in terms of required emission abatement, then after year 2100 very low net emissions are needed to maintain prescribed year 2100 CO{sub 2} concentrations. As expected, RCP2.6 and SCP4.5 to 2.6 require more strict emission reductions. The implication of this is that direct sequestration of carbon dioxide is likely to be required for RCP4.5 or higher mitigation scenarios, to offset any minimum emissions for society to function (the 'emissions floor'). Despite large uncertainties in the physical and biogeochemical processes, constraints from model-observational comparisons support a high degree of confidence in predicting the allowable emissions consistent with a particular concentration pathway. In contrast the uncertainty in the resulting temperature range remains large. For many parameter sets, and especially for RCP2.6, the land will turn into a carbon source within the twenty first century, but the ocean will remain as a carbon sink. For land carbon storage and our modelling framework, major reductions are seen in northern high latitudes and the Amazon basin even after atmospheric CO{sub 2} is stabilised, while for ocean carbon uptake, the tropical ocean regions will be a

  17. High-energy gamma-ray emission in compact binaries

    International Nuclear Information System (INIS)

    Cerutti, Benoit

    2010-01-01

    Four gamma-ray sources have been associated with binary systems in our Galaxy: the micro-quasar Cygnus X-3 and the gamma-ray binaries LS I +61 degrees 303, LS 5039 and PSR B1259-63. These systems are composed of a massive companion star and a compact object of unknown nature, except in PSR B1259-63 where there is a young pulsar. I propose a comprehensive theoretical model for the high-energy gamma-ray emission and variability in gamma-ray emitting binaries. In this model, the high-energy radiation is produced by inverse Compton scattering of stellar photons on ultra-relativistic electron-positron pairs injected by a young pulsar in gamma-ray binaries and in a relativistic jet in micro-quasars. Considering anisotropic inverse Compton scattering, pair production and pair cascade emission, the TeV gamma-ray emission is well explained in LS 5039. Nevertheless, this model cannot account for the gamma-ray emission in LS I +61 degrees 303 and PSR B1259-63. Other processes should dominate in these complex systems. In Cygnus X-3, the gamma-ray radiation is convincingly reproduced by Doppler-boosted Compton emission of pairs in a relativistic jet. Gamma-ray binaries and micro-quasars provide a novel environment for the study of pulsar winds and relativistic jets at very small spatial scales. (author)

  18. Characterizing the structural maturity of fault zones using high-resolution earthquake locations.

    Science.gov (United States)

    Perrin, C.; Waldhauser, F.; Scholz, C. H.

    2017-12-01

    We use high-resolution earthquake locations to characterize the three-dimensional structure of active faults in California and how it evolves with fault structural maturity. We investigate the distribution of aftershocks of several recent large earthquakes that occurred on immature faults (i.e., slow moving and small cumulative displacement), such as the 1992 (Mw7.3) Landers and 1999 (Mw7.1) Hector Mine events, and earthquakes that occurred on mature faults, such as the 1984 (Mw6.2) Morgan Hill and 2004 (Mw6.0) Parkfield events. Unlike previous studies which typically estimated the width of fault zones from the distribution of earthquakes perpendicular to the surface fault trace, we resolve fault zone widths with respect to the 3D fault surface estimated from principal component analysis of local seismicity. We find that the zone of brittle deformation around the fault core is narrower along mature faults compared to immature faults. We observe a rapid fall off of the number of events at a distance range of 70 - 100 m from the main fault surface of mature faults (140-200 m fault zone width), and 200-300 m from the fault surface of immature faults (400-600 m fault zone width). These observations are in good agreement with fault zone widths estimated from guided waves trapped in low velocity damage zones. The total width of the active zone of deformation surrounding the main fault plane reach 1.2 km and 2-4 km for mature and immature faults, respectively. The wider zone of deformation presumably reflects the increased heterogeneity in the stress field along complex and discontinuous faults strands that make up immature faults. In contrast, narrower deformation zones tend to align with well-defined fault planes of mature faults where most of the deformation is concentrated. Our results are in line with previous studies suggesting that surface fault traces become smoother, and thus fault zones simpler, as cumulative fault slip increases.

  19. High resolution and high speed positron emission tomography data acquisition

    International Nuclear Information System (INIS)

    Burgiss, S.G.; Byars, L.G.; Jones, W.F.; Casey, M.E.

    1986-01-01

    High resolution positron emission tomography (PET) requires many detectors. Thus, data collection systems for PET must have high data rates, wide data paths, and large memories to histogram the events. This design uses the VMEbus to cost effectively provide these features. It provides for several modes of operation including real time sorting, list mode data storage, and replay of stored list mode data

  20. Magnetic Field Emissions for Ferrite and Non-Ferrite Geometries for Wireless Power Transfer to Vehicles

    DEFF Research Database (Denmark)

    Batra, Tushar; Schaltz, Erik

    2014-01-01

    Minimizing magnetic field emissions to surroundings is one of the most challenging design criteria for wireless power transfer to vehicles. In this paper, concept of division of the emissions into three zones (primary, secondary, and combined zone) in the vertical direction is introduced. For geo......Minimizing magnetic field emissions to surroundings is one of the most challenging design criteria for wireless power transfer to vehicles. In this paper, concept of division of the emissions into three zones (primary, secondary, and combined zone) in the vertical direction is introduced...... for vertical separation between the coils in range of 100-180 mm. It is observed that lower vertical separation results in higher overlapping of the zones and the coils behave as they are effectively placed close to center of air gap. The analysis in this work provides a better understanding of the space...... profile of magnetic field emissions (with and without ferrite) for wireless power transfer to vehicles....

  1. Highly Efficient Spontaneous Emission from Self-Assembled Quantum Dots

    DEFF Research Database (Denmark)

    Johansen, Jeppe; Lund-Hansen, Toke; Hvam, Jørn Märcher

    2006-01-01

    We present time resolved measurements of spontaneous emission (SE) from InAs/GaAs quantum dots (QDs). The measurements are interpreted using Fermi's Golden Rule and from this analysis we establish the parameters for high quantum efficiency.......We present time resolved measurements of spontaneous emission (SE) from InAs/GaAs quantum dots (QDs). The measurements are interpreted using Fermi's Golden Rule and from this analysis we establish the parameters for high quantum efficiency....

  2. Control of surplus oxygen in the combustion zone reduces fuel costs and NO{sub x} emissions; Verringerung der Brennstoffkosten und NO{sub X}-Emissionen durch Regelung des Sauerstoffueberschusses in der Brennzone

    Energy Technology Data Exchange (ETDEWEB)

    Boltz, Eric S. [Marathon Sensors Inc. (Germany); Baumann, Jens [Process Electronic GmbH (Germany)

    2009-06-15

    Real time in-situ measurement of oxygen content and temperature in the combustion zone of a heating boiler or furnace permits monitoring of combustion conditions at source. Measurements of oxygen surplus and of temperature at strategic points supply us with instantaneous information for optimum control of the combustion process. Accurate and rapid measurement of oxygen surplus is vital in view of the cost explosion in the case of fuels, and also for reduction of NO{sub x} emissions. Locally available commercial high-temperature oxygen sensors make it possible to solve problems of combustion control and burner regulation with only short amortization periods and high annual financial benefits in power generating plant, petrochemicals, refinery and glassworks applications. (orig.)

  3. 40 CFR Table 4 to Subpart Lllll of... - Initial Compliance With Emission Limitations

    Science.gov (United States)

    2010-07-01

    ... efficiency was at least 95.8 percent. d. Route emissions to a boiler or process heater with a design heat... capacity. e. Introduce the emissions into the flame zone of a boiler or process heater You have a record that shows the emissions are being introduced into the boiler or process heater flame zone. f. Route...

  4. NOx emissions from high swirl turbulent spray flames with highly oxygenated fuels

    KAUST Repository

    Bohon, Myles

    2013-01-01

    Combustion of fuels with fuel bound oxygen is of interest from both a practical and a fundamental viewpoint. While a great deal of work has been done studying the effect of oxygenated additives in diesel and gasoline engines, much less has been done examining combustion characteristics of fuels with extremely high mass fractions of fuel bound oxygen. This work presents an initial investigation into the very low NOx emissions resulting from the combustion of a model, high oxygen mass fraction fuel. Glycerol was chosen as a model fuel with a fuel bound oxygen mass fraction of 52%, and was compared with emissions measured from diesel combustion at similar conditions in a high swirl turbulent spray flame. This work has shown that high fuel bound oxygen mass fractions allow for combustion at low global equivalence ratios with comparable exhaust gas temperatures due to the significantly lower concentrations of diluting nitrogen. Despite similar exhaust gas temperatures, NOx emissions from glycerol combustion were up to an order of magnitude lower than those measured using diesel fuel. This is shown to be a result not of specific burner geometry, but rather is influenced by the presence of higher oxygen and lower nitrogen concentrations at the flame front inhibiting NOx production. © 2012 The Combustion Institute.

  5. Rf Gun with High-Current Density Field Emission Cathode

    International Nuclear Information System (INIS)

    Jay L. Hirshfield

    2005-01-01

    High current-density field emission from an array of carbon nanotubes, with field-emission-transistor control, and with secondary electron channel multiplication in a ceramic facing structure, have been combined in a cold cathode for rf guns and diode guns. Electrodynamic and space-charge flow simulations were conducted to specify the cathode configuration and range of emission current density from the field emission cold cathode. Design of this cathode has been made for installation and testing in an existing S-band 2-1/2 cell rf gun. With emission control and modulation, and with current density in the range of 0.1-1 kA/cm2, this cathode could provide performance and long-life not enjoyed by other currently-available cathodes

  6. Study on growth of highly pure uranium compounds

    International Nuclear Information System (INIS)

    Shikama, Tatsuo; Ochiai, Akira; Suzuki, Kenji.

    1992-01-01

    We developed the systems for growing highly pure uranium compounds to study their intrinsic physical properties. Uranium metal was zone refined under low contamination conditions as far as possible. Chemical analysis of the purified uranium was performed using the inductive coupled plasma emission spectrometry (ICP). The problem that emission spectra of the uranium conceal those of analyzed impurities was settled by extraction of the uranium using tri-n-butyl-phosphate (TBP). The result shows that some metallic impurities such as Pb, Mn, Cu etc. evaporated by the r.f. heating and other usual metallic impurities moved to the end of rod with molten zone. Therefore, we conclude that the zone refining technique is much effective to the removal of metallic impurities and we obtained highly purified uranium metal of 99.99 % up with regard to metallic impurities. Using the purified uranium, we attempted to grow a highly pure uranium-titanium single crystals. (author)

  7. Monitoring of high temperature zone by resistivity tomography during in-situ heater test in sedimentary soft rocks

    International Nuclear Information System (INIS)

    Kubota, Kenji; Suzuki, Koichi; Ikenoya, Takafumi; Takakura, Nozomu; Tani, Kazuo

    2008-01-01

    In-situ heater test has been conducted to evaluate the influence of high temperature in an underground facility at a depth of 50 m. Resistivity monitoring is thought to be effective to map the extent of the high temperature zone. So we have conducted resistivity tomography during the heater test. As a result, low resistivity zone was appeared near the heated area as starting the heating, and the zone was expanded. Resistivity of rock is proportional to resistivity of pore water. It is known that pore water resistivity decreases as the temperature rise. This suggests that high temperature zone is detected and spatial distribution of temperature can be mapped by resistivity tomography. (author)

  8. Pulsar high energy emission due to inverse Compton scattering

    Energy Technology Data Exchange (ETDEWEB)

    Lyutikov, Maxim

    2013-06-15

    We discuss growing evidence that pulsar high energy is emission is generated via Inverse Compton mechanism. We reproduce the broadband spectrum of Crab pulsar, from UV to very high energy gamma-rays - nearly ten decades in energy, within the framework of the cyclotron-self-Compton model. Emission is produced by two counter-streaming beams within the outer gaps, at distances above ∼ 20 NS radii. The outward moving beam produces UV-X-ray photons via Doppler-booster cyclotron emission, and GeV photons by Compton scattering the cyclotron photons produced by the inward going beam. The scattering occurs in the deep Klein-Nishina regime, whereby the IC component provides a direct measurement of particle distribution within the magnetosphere. The required plasma multiplicity is high, ∼10{sup 6} – 10{sup 7}, but is consistent with the average particle flux injected into the pulsar wind nebula.

  9. Neutron emission and fragment yield in high-energy fission

    International Nuclear Information System (INIS)

    Grudzevich, O. T.; Klinov, D. A.

    2013-01-01

    The KRIS special library of spectra and emission probabilities in the decays of 1500 nuclei excited up to energies between 150 and 250 MeV was developed for correctly taking into account the decay of highly excited nuclei appearing as fission fragments. The emission of neutrons, protons, and photons was taken into account. Neutron emission fromprimary fragments was found to have a substantial effect on the formation of yields of postneutron nuclei. The library was tested by comparing the calculated and measured yields of products originating from the fission of nuclei that was induced by high-energy protons. The method for calculating these yields was tested on the basis of experimental data on the thermal-neutroninduced fission of 235 U nuclei

  10. High temperature effect on microflora of radish root-inhabited zone and nutrient solutions for radish growth

    Science.gov (United States)

    Borodina, E. V.; Tirranen, L. S.

    The effect of high temperatures (35 and 45 °C) on microflora of the root zone of radish plants grown in phytotron was evaluated by the response of microorganisms from 9 indicator groups. Phytotron air temperature elevated to 35 °C for 20 hours caused no significant changes in qualitative and quantitative composition of the root microflora in experimental plants. By the end of the experiment, the species diversity of microflora had changed. The amount of phytopathogenic microorganisms decreased which can be interpreted as more stable co-existence of microflora with plants. The numbers of microbes from other indicator groups was in dynamic equilibrium. The plants' condition did not deteriorate either. Exposure to the temperature of 45 °C for 7 hours have been found to change the numbers and species diversity in the radish root zone microflora. The microorganisms were observed to increase their total numbers at the expense of certain indicator groups. Bacteria increased spore forms at the stage of spores. Colon bacillus bacteria of increased their numbers by the end of experiment by an order. By the end of experiment the roots of experiment plants had microscopic fungi from Mucor, Aspergillus, Trichoderma, Cladosporium genera. The observed changes in the microbial complex seem to be associated with the changes of root emissions and general deterioration of the plants' condition. It is suggested that the response of the microorganisms can be indicative of the condition of plants under investigation.

  11. Estimating CH4 emission from paddy managed soils in southern guinea savanna zone of Nigeria using an integrated approach

    Science.gov (United States)

    Akpeokhai, Agatha; Menz, Gunter; Thonfeld, Frank; Akinluyi, Francis

    2016-04-01

    ESTIMATING CH4 EMISSION FROM PADDY MANAGED SOILS IN SOUTHERN GUINEA SAVANNA ZONE OF NIGERIA USING AN INTEGRATED APPROACH Akpeokhai Agatha 1, Menz Gunter 1, Thonfeld Frank 1, Akinluyi Francis 2 1 Remote Sensing Research Group (RSRG), Geography Institute, University of Bonn, Germany. 2 Department Remote Sensing and Geo-Science Information System, School of Earth and Mineral Science, Federal University of Technology, Akure Nigeria. Methane is one of the most important greenhouse gases as it has the second greatest climate forcing potential. Paddy fields have been identified to be sources of methane and Nigerian paddies are not left out. In Nigeria, the guinea savanna region is regarded as the bread basket of the nation and this area is one of the major rice producing regions in Nigeria. Its location in the food basket region of the country makes this part a very important study site. However, since Nigerian paddies contribute to methane emission by how much do these paddies contribute to the emissions? Also, so far, there limited studies on methane from rice fields in West Africa thus making this study a very important start off point. To answer this huge question, methane emission will be estimated using an integrated approach in the North Central part of Nigeria. Land use change cultivated to rice was analysed using Remote sensing techniques to determine the changes in land cultivated to rice. Methane emission from these identified rice fields will be estimated using the IPCC Tier 1 set of equations. First relevant indices (Normalized Differential Moisture Index, Normalized Differential Wetness Index and Rice Growth Vegetation Index) were generated to aid classification of rice fields using LANDSAT data from the USGS. Next the LANDSAT datasets were analyzed for land use change cultivated to rice from 1990 to 2014 to generate rice field maps. ERDAS Imagine, ARCGIS and ENVI tools were used to meet these spatial needs. Methane emissions from this region will be

  12. High energy effects on D-brane and black hole emission rates

    International Nuclear Information System (INIS)

    Das, S.; Dasgupta, A.; Sarkar, T.

    1997-01-01

    We study the emission of scalar particles from a class of near-extremal five-dimensional black holes and the corresponding D-brane configuration at high energies. We show that the distribution functions and the black hole greybody factors are modified in the high energy tail of the Hawking spectrum in such a way that the emission rates exactly match. We extend the results to charged scalar emission and to four dimensions. copyright 1997 The American Physical Society

  13. HIGH-REDSHIFT SDSS QUASARS WITH WEAK EMISSION LINES

    International Nuclear Information System (INIS)

    Diamond-Stanic, Aleksandar M.; Fan Xiaohui; Jiang Linhua; Kim, J. Serena; Schmidt, Gary D.; Smith, Paul S.; Vestergaard, Marianne; Young, Jason E.; Brandt, W. N.; Shemmer, Ohad; Gibson, Robert R.; Schneider, Donald P.; Strauss, Michael A.; Shen Yue; Anderson, Scott F.; Carilli, Christopher L.; Richards, Gordon T.

    2009-01-01

    We identify a sample of 74 high-redshift quasars (z > 3) with weak emission lines from the Fifth Data Release of the Sloan Digital Sky Survey and present infrared, optical, and radio observations of a subsample of four objects at z > 4. These weak emission-line quasars (WLQs) constitute a prominent tail of the Lyα + N v equivalent width distribution, and we compare them to quasars with more typical emission-line properties and to low-redshift active galactic nuclei with weak/absent emission lines, namely BL Lac objects. We find that WLQs exhibit hot (T ∼ 1000 K) thermal dust emission and have rest-frame 0.1-5 μm spectral energy distributions that are quite similar to those of normal quasars. The variability, polarization, and radio properties of WLQs are also different from those of BL Lacs, making continuum boosting by a relativistic jet an unlikely physical interpretation. The most probable scenario for WLQs involves broad-line region properties that are physically distinct from those of normal quasars.

  14. Stereotyped high-frequency oscillations discriminate seizure onset zones and critical functional cortex in focal epilepsy.

    Science.gov (United States)

    Liu, Su; Gurses, Candan; Sha, Zhiyi; Quach, Michael M; Sencer, Altay; Bebek, Nerses; Curry, Daniel J; Prabhu, Sujit; Tummala, Sudhakar; Henry, Thomas R; Ince, Nuri F

    2018-01-30

    High-frequency oscillations in local field potentials recorded with intracranial EEG are putative biomarkers of seizure onset zones in epileptic brain. However, localized 80-500 Hz oscillations can also be recorded from normal and non-epileptic cerebral structures. When defined only by rate or frequency, physiological high-frequency oscillations are indistinguishable from pathological ones, which limit their application in epilepsy presurgical planning. We hypothesized that pathological high-frequency oscillations occur in a repetitive fashion with a similar waveform morphology that specifically indicates seizure onset zones. We investigated the waveform patterns of automatically detected high-frequency oscillations in 13 epilepsy patients and five control subjects, with an average of 73 subdural and intracerebral electrodes recorded per patient. The repetitive oscillatory waveforms were identified by using a pipeline of unsupervised machine learning techniques and were then correlated with independently clinician-defined seizure onset zones. Consistently in all patients, the stereotypical high-frequency oscillations with the highest degree of waveform similarity were localized within the seizure onset zones only, whereas the channels generating high-frequency oscillations embedded in random waveforms were found in the functional regions independent from the epileptogenic locations. The repetitive waveform pattern was more evident in fast ripples compared to ripples, suggesting a potential association between waveform repetition and the underlying pathological network. Our findings provided a new tool for the interpretation of pathological high-frequency oscillations that can be efficiently applied to distinguish seizure onset zones from functionally important sites, which is a critical step towards the translation of these signature events into valid clinical biomarkers.awx374media15721572971001. © The Author(s) (2018). Published by Oxford University Press on

  15. The clinical study on high intensity zone of magnetic resonance imaging using Scolopendrid Aquacupuncture.

    Directory of Open Access Journals (Sweden)

    Jeong-a Lim

    2006-12-01

    Full Text Available Objective : This study was designed to find out the effect of scolopendrid aquacupuncture on low back pain with or without sciatica showing high intensity zone of magnetic resonance imaging. Methods : The 30 patients who had a diagnosis of high intensity zone by lumbar-MRI and admitted to Gwangju oriental medical hospital in wonkwang university from January 2005 to August 2004 were observed. The symptom of inpatients is low back pain with or without sciatica. We treated 30 patients by scolopendrid aquacupuncture besides the general conservative treatment of oriental medicine. Results and Conclusion : The scolopendrid aquacupuncture treatment led to improvement in the pain and symptom of disability as determined by all efficacy measures. After scolopendrid aquacupuncture treatment, there was improvement in VAS, ROM and SLRT. This results suggest that scolopendrid aquacupuncture is good method for treatment of low back pain with or without sciatica showing high intensity zone of magnetic resonance imaging.

  16. Emissions trading stalls

    International Nuclear Information System (INIS)

    Milne, R.

    1998-01-01

    A brief article examines prospects for emission trading of greenhouse gas emissions in the UK. Topics covered include a checklist of principles for any trading system, plans for oil companies to do it internally, the possibility for carbon sinks as well as emissions and developments around the world. (UK) alt. Directly northward of the Sigsbee Escarpment, there is a relatively thin, low-velocity zone known as a ''gumbo zone''. Here two other pressure compartments are proposed. The origin of them is two-fold. First, initial sedimentation consists of pelagic clay draped over oceanic and transitional crust. Later, as the continental margin progrades nearer sedimentation becomes hemipelagic and coarser as gravity-driven sediments predominate. Secondly, as the salt wedge overrides a given spot of the basement, it is possible to develop a shear couple between the migrating salt and the stationary basement. The resultant shear (the site of the next strike-slip fault) may change pressures beneath the salt such that the shear may create two pressure compartments. The differences between the two compartments may be accentuated by lithologic changes caused by depositional mechanisms. (author)

  17. Long-lived Dust Asymmetries at Dead Zone Edges in Protoplanetary Disks

    Energy Technology Data Exchange (ETDEWEB)

    Miranda, Ryan [Cornell Center for Astrophysics and Planetary Science, Department of Astronomy, Cornell University, Ithaca, NY 14853 (United States); Li, Hui; Li, Shengtai; Jin, Sheng, E-mail: rjm456@cornell.edu [Theoretical Division, Los Alamos National Laboratory, Los Alamos, NM 87545 (United States)

    2017-02-01

    A number of transition disks exhibit significant azimuthal asymmetries in thermal dust emission. One possible origin for these asymmetries is dust trapping in vortices formed at the edges of dead zones. We carry out high-resolution, two-dimensional hydrodynamic simulations of this scenario, including the effects of dust feedback. We find that, although feedback weakens the vortices and slows down the process of dust accumulation, the dust distribution in the disk can nonetheless remain asymmetric for many thousands of orbits. We show that even after 10{sup 4} orbits, or 2.5 Myr when scaled to the parameters of Oph IRS 48 (a significant fraction of its age), the dust is not dispersed into an axisymmetric ring, in contrast to the case of a vortex formed by a planet. This is because accumulation of mass at the dead zone edge constantly replenishes the vortex, preventing it from being fully destroyed. We produce synthetic dust emission images using our simulation results. We find that multiple small clumps of dust may be distributed azimuthally. These clumps, if not resolved from one another, appear as a single large feature. A defining characteristic of a disk with a dead zone edge is that an asymmetric feature is accompanied by a ring of dust located about twice as far from the central star.

  18. Investigation of Energy Use Pattern and Emission Discharge in Nigeria: A Case Study of South West Zone

    Directory of Open Access Journals (Sweden)

    Olufemi Abimbola

    2015-01-01

    Full Text Available Electricity demand has increased with population growth, industrialization and civilization. Most householders are barely conscious of the conservative measures for available limited supply, while the environmental impact has rarely been taken into cognizance by consumers. The study examines end-users attitude to energy consumption in Nigeria based on four scenarios. Gaseous emissions data obtained from prepaid and post-paid metering systems usage in low-income and high-income housing types were analyzed. Results obtained indicate strong relationship between energy use and emissions with significantly different emission generation. About 38% and 23% reduction in global warming and acidification potential is achieved by a switch to prepaid meters for both income earners. Post-paid low-income earners utilized the highest energy (59.8kW/hr while the prepaid high-income earners had the minimum (31.1kW/hr. Energy use and greenhouse gas emissions from both earners followed similar trend. Prepaid metering system usage improves energy consumption, thereby offsetting global warming and acidification impacts.

  19. Fatigue crack propagation behavior and acoustic emission characteristics of the heat affected zone of super duplex stainless steel

    International Nuclear Information System (INIS)

    Do, Jae Yoon; Kim, Jin Hwan; Ahn, Seok Hwan; Park, In Duck; Kang, Chang Yong; Nam, Ki Woo

    2002-01-01

    Because duplex stainless steel shows the good strength and corrosion resistance properties, the necessity of duplex stainless steel, which has long life in severe environments, has been increased with industrial development. The fatigue crack propagation behavior of Heat Affected Zone(HAZ) has been investigated in super duplex stainless steel. The fatigue crack propagation rate of HAZ of super duplex stainless steel was faster than that of base metal of super duplex stainless steel. We also analysed acoustic emission signals during the fatigue test with time-frequency analysis method. According to the results of time-frequency analysis, the frequency ranges of 200-400 kHz were obtained by striation and the frequency range of 500 kHz was obtained due to dimple and separate of inclusion

  20. LONG-TERM MONITORING OF MRK 501 FOR ITS VERY HIGH ENERGY {gamma} EMISSION AND A FLARE IN 2011 OCTOBER

    Energy Technology Data Exchange (ETDEWEB)

    Bartoli, B.; Catalanotti, S. [Dipartimento di Fisica dell' Universita di Napoli ' Federico II' , Complesso Universitario di Monte Sant' Angelo, via Cinthia, I-80126 Napoli (Italy); Bernardini, P.; Bleve, C. [Dipartimento di Matematica e Fisica ' E. De Giorgi' dell' Universita del Salento, via per Arnesano, I-73100 Lecce (Italy); Bi, X. J.; Cao, Z.; Chen, S. Z.; Chen, Y. [Key Laboratory of Particle Astrophysics, Institute of High Energy Physics, Chinese Academy of Sciences, P.O. Box 918, 100049 Beijing (China); Bolognino, I. [Dipartimento di Fisica Nucleare e Teorica dell' Universita di Pavia, via Bassi 6, I-27100 Pavia (Italy); Branchini, P.; Budano, A. [Istituto Nazionale di Fisica Nucleare, Sezione di Roma Tre, via della Vasca Navale 84, I-00146 Roma (Italy); Calabrese Melcarne, A. K. [Istituto Nazionale di Fisica Nucleare-CNAF, Viale Berti-Pichat 6/2, I-40127 Bologna (Italy); Camarri, P. [Dipartimento di Fisica dell' Universita di Roma ' Tor Vergata' , via della Ricerca Scientifica 1, I-00133 Roma (Italy); Cardarelli, R. [Istituto Nazionale di Fisica Nucleare, Sezione di Roma Tor Vergata, via della Ricerca Scientifica 1, I-00133 Roma (Italy); Cattaneo, C. [Istituto Nazionale di Fisica Nucleare, Sezione di Pavia, via Bassi 6, I-27100 Pavia (Italy); Chen, T. L. [Tibet University, 850000 Lhasa, Xizang (China); Creti, P. [Istituto Nazionale di Fisica Nucleare, Sezione di Lecce, via per Arnesano, I-73100 Lecce (Italy); Cui, S. W. [Hebei Normal University, Shijiazhuang 050016, Hebei (China); Dai, B. Z. [Yunnan University, 2 North Cuihu Rd., 650091 Kunming, Yunnan (China); D' Ali Staiti, G., E-mail: chensz@ihep.ac.cn [Dipartimento di Fisica e Tecnologie Relative, Universita degli Studi di Palermo, Viale delle Scienze, Edificio 18, I-90128 Palermo (Italy); Collaboration: ARGO-YBJ Collaboration; and others

    2012-10-10

    As one of the brightest active blazars in both X-ray and very high energy {gamma}-ray bands, Mrk 501, is very useful for physics associated with jets from active galactic nuclei. The ARGO-YBJ experiment has monitored Mrk 501 for {gamma}-rays above 0.3 TeV since 2007 November. The largest flare since 2005 was observed from 2011 October and lasted until about 2012 April. In this paper, a detailed analysis of this event is reported. During the brightest {gamma}-ray flaring episodes from 2011 October 17 to November 22, an excess of the event rate over 6{sigma} is detected by ARGO-YBJ in the direction of Mrk 501, corresponding to an increase of the {gamma}-ray flux above 1 TeV by a factor of 6.6 {+-} 2.2 from its steady emission. In particular, the {gamma}-ray flux above 8 TeV is detected with a significance better than 4{sigma}. Based on time-dependent synchrotron self-Compton (SSC) processes, the broadband energy spectrum is interpreted as the emission from an electron energy distribution parameterized with a single power-law function with an exponential cutoff at its high-energy end. The average spectral energy distribution for the steady emission is well described by this simple one-zone SSC model. However, the detection of {gamma}-rays above 8 TeV during the flare challenges this model due to the hardness of the spectra. Correlations between X-rays and {gamma}-rays are also investigated.

  1. A vacuum sealed high emission current and transmission efficiency carbon nanotube triode

    Energy Technology Data Exchange (ETDEWEB)

    Di, Yunsong [School of Electronic Science & Engineering, Southeast University, Nanjing 210096 (China); Jiangsu Key Laboratory of Optoelectronic Technology, Nanjing Normal University, Nanjing 210023 (China); Wang, Qilong; Zhang, Xiaobing, E-mail: bell@seu.edu.cn; Lei, Wei; Du, Xiaofei; Yu, Cairu [School of Electronic Science & Engineering, Southeast University, Nanjing 210096 (China)

    2016-04-15

    A vacuum sealed carbon nanotubes (CNTs) triode with a concave and spoke-shaped Mo grid is presented. Due to the high aperture ratio of the grid, the emission current could be modulated at a relatively high electric field. Totally 75 mA emission current has been obtained from the CNTs cathode with the average applied field by the grid shifting from 8 to 13 V/μm. Whilst with the electron transmission efficiency of the grid over 56%, a remarkable high modulated current electron beam over 42 mA has been collected by the anode. Also contributed by the high aperture ration of the grid, desorbed gas molecules could flow away from the emission area rapidly when the triode has been operated at a relative high emission current, and finally collected by a vacion pump. The working pressure has been maintained at ∼1 × 10{sup −7} Torr, seldom spark phenomena occurred. Nearly perfect I-V curve and corresponding Fowler-Nordheim (FN) plot confirmed the accuracy of the measured data, and the emission current was long term stable and reproducible. Thusly, this kind of triode would be used as a high-power electron source.

  2. HIGH-CURRENT COLD CATHODE FIELD EMISSION ARRAY FOR ELECTRON LENS APPLICATION

    Energy Technology Data Exchange (ETDEWEB)

    Hirshfield, Jay L

    2012-12-28

    During Phase I, the following goals were achieved: (1) design and fabrication of a novel, nano-dimensional CNT field emitter assembly for high current density application, with high durability; (2) fabrication of a ceramic based micro channel plate (MCP) and characterization of its secondary electron emission; and (3) characterizing the CNT/MCP cathode for high field emission and durability. As a result of these achievements, a relatively high current density of ~ 1.2 A/cm2 from a CNT cathode and single channel MCP were measured. The emission current was also extremely stable with a peak-to-peak variation of only 1.8%. The emission current could be further enhanced to meet requirements for electron lens applications by increasing the number of MCP channels. A calculation for maximum possible current density with a 1200 channel/cm2 MCP, placed over a cathode with 1200 uniformly functioning CNTs, would be ~1.46 kA/cm2, neglecting space charge limitations. Clearly this level of emission is far greater than what is needed for the electron lens application, but it does offer a highly comforting margin to account for sub-standard emitters and/or to allow the lesser challenge of building a cathode with fewer channels/cm2. A satisfactory goal for the electron lens application would be a controllable emission of 2-4 mA per channel in an ensemble of 800-1200 uniformly-functioning channels/cm2, and a cathode with overall area of about 1 cm2.

  3. Biogenic volatile organic compound emissions along a high arctic soil moisture gradient.

    Science.gov (United States)

    Svendsen, Sarah Hagel; Lindwall, Frida; Michelsen, Anders; Rinnan, Riikka

    2016-12-15

    Emissions of biogenic volatile organic compounds (BVOCs) from terrestrial ecosystems are important for the atmospheric chemistry and the formation of secondary organic aerosols, and may therefore influence the climate. Global warming is predicted to change patterns in precipitation and plant species compositions, especially in arctic regions where the temperature increase will be most pronounced. These changes are potentially highly important for the BVOC emissions but studies investigating the effects are lacking. The aim of this study was to investigate the quality and quantity of BVOC emissions from a high arctic soil moisture gradient extending from dry tundra to a wet fen. Ecosystem BVOC emissions were sampled five times in the July-August period using a push-pull enclosure technique, and BVOCs trapped in absorbent cartridges were analyzed using gas chromatography-mass spectrometry. Plant species compositions were estimated using the point intercept method. In order to take into account important underlying ecosystem processes, gross ecosystem production, ecosystem respiration and net ecosystem production were measured in connection with chamber-based BVOC measurements. Highest emissions of BVOCs were found from vegetation communities dominated by Salix arctica and Cassiope tetragona, which had emission profiles dominated by isoprene and monoterpenes, respectively. These results show that emissions of BVOCs are highly dependent on the plant cover supported by the varying soil moisture, suggesting that high arctic BVOC emissions may affect the climate differently if soil water content and plant cover change. Copyright © 2016 Elsevier B.V. All rights reserved.

  4. Evolution of the fracture process zone in high-strength concrete under different loading rates

    Directory of Open Access Journals (Sweden)

    Cámara M.

    2010-06-01

    Full Text Available For cementitious materials, the inelastic zone around a crack tip is termed as fracture process zone (FPZ and dominated by complicated mechanism, such as microcracking, crack deflection, bridging, crack face friction, crack tip blunting by voids, crack branching, and so on. Due to the length of the FPZ is related with the characteristic length of the cementitious materials, the size, extent and location of the FPZ has been the object of countless research efforts for several decades. For instance, Cedolin et al. [1] have used an optical method based on the moiré interferometry to determine FPZ in concrete. Castro-Montero et al. [2] have applied the method of holographic interferometry to mortar to study the extension of the FPZ. The advantage of the interferometry method is that the complete FPZ can be directly observed on the surface of the sample. Swartz et al. [3] has adopted the dye penetration technique to illustrate the changing patterns observed as the crack progress from the tensile side to the compression side of the beam. Moreover, acoustic emission (AE is also an experimental technique well suited for monitoring fracture process. Haidar et al. [4] and Maji et al. [5] have studied the relation between acoustic emission characteristics and the properties of the FPZ. Compared with the extensive research on properties of the FPZ under quasi-static loading conditions, much less information is available on its dynamic characterization, especially for high-strength concrete (HSC. This paper presents the very recent results of an experimental program aimed at disclosing the loading rate effect on the size and velocity of the (FPZ in HSC. Eighteen three-point bending specimens were conducted under a wide range of loading rates from from 10-4 mm/s to 103 mm/s using either a servo-hydraulic machine or a self-designed drop-weight impact device. The beam dimensions were 100 mm 100 mm in cross section, and 420 mm in length. The initial notch

  5. Non-equilibrium thermionic electron emission for metals at high temperatures

    Science.gov (United States)

    Domenech-Garret, J. L.; Tierno, S. P.; Conde, L.

    2015-08-01

    Stationary thermionic electron emission currents from heated metals are compared against an analytical expression derived using a non-equilibrium quantum kappa energy distribution for the electrons. The latter depends on the temperature decreasing parameter κ ( T ) , which decreases with increasing temperature and can be estimated from raw experimental data and characterizes the departure of the electron energy spectrum from equilibrium Fermi-Dirac statistics. The calculations accurately predict the measured thermionic emission currents for both high and moderate temperature ranges. The Richardson-Dushman law governs electron emission for large values of kappa or equivalently, moderate metal temperatures. The high energy tail in the electron energy distribution function that develops at higher temperatures or lower kappa values increases the emission currents well over the predictions of the classical expression. This also permits the quantitative estimation of the departure of the metal electrons from the equilibrium Fermi-Dirac statistics.

  6. Multi-wavelength emission from 3C 66A: clues to its redshift and gamma-ray emission location

    International Nuclear Information System (INIS)

    Yan Da-Hai; Fan Zhong-Hui; Zhou Yao; Dai Ben-Zhong

    2013-01-01

    The quasi-simultaneous multi-wavelength emission of TeV blazar 3C 66A is studied by using a one-zone multi-component leptonic jet model. It is found that the quasi-simultaneous spectral energy distribution of 3C 66A can be well reproduced; in particular, the first three months of its average Fermi-LAT spectrum can be well reproduced by the synchrotron self-Compton component plus external Compton component of the broad line region (BLR). Clues to its redshift and gamma-ray emission location are obtained. The results indicate the following. (i) On the redshift: The theoretical intrinsic TeV spectra can be predicted by extrapolating the reproduced GeV spectra. Through comparing these extrapolated TeV spectra with the corrected observed TeV spectra from extragalactic background light, it is suggested that the redshift of 3C 66A could be between 0.1 and 0.3, with the most likely value being ∼ 0.2. (ii) On the gamma-ray emission location: To well reproduce the GeV emission of 3C 66A under different assumptions on the BLR, the gamma-ray emission region is always required to be beyond the inner zone of the BLR. The BLR absorption effect on gamma-ray emission confirms this point.

  7. High estimates of supply constrained emissions scenarios for long-term climate risk assessment

    International Nuclear Information System (INIS)

    Ward, James D.; Mohr, Steve H.; Myers, Baden R.; Nel, Willem P.

    2012-01-01

    The simulated effects of anthropogenic global warming have become important in many fields and most models agree that significant impacts are becoming unavoidable in the face of slow action. Improvements to model accuracy rely primarily on the refinement of parameter sensitivities and on plausible future carbon emissions trajectories. Carbon emissions are the leading cause of global warming, yet current considerations of future emissions do not consider structural limits to fossil fuel supply, invoking a wide range of uncertainty. Moreover, outdated assumptions regarding the future abundance of fossil energy could contribute to misleading projections of both economic growth and climate change vulnerability. Here we present an easily replicable mathematical model that considers fundamental supply-side constraints and demonstrate its use in a stochastic analysis to produce a theoretical upper limit to future emissions. The results show a significant reduction in prior uncertainty around projected long term emissions, and even assuming high estimates of all fossil fuel resources and high growth of unconventional production, cumulative emissions tend to align to the current medium emissions scenarios in the second half of this century. This significant finding provides much-needed guidance on developing relevant emissions scenarios for long term climate change impact studies. - Highlights: ► GHG emissions from conventional and unconventional fossil fuels modelled nationally. ► Assuming worst-case: large resource, high growth, rapid uptake of unconventional. ► Long-term cumulative emissions align well with the SRES medium emissions scenario. ► High emissions are unlikely to be sustained through the second half of this century. ► Model designed to be easily extended to test other scenarios e.g. energy shortages.

  8. Maser Emission Associated with Young High Mass Stars

    Science.gov (United States)

    Mahmoud, Khaled Abdalla Edris

    In this work the maser emission has been used to study the very early stage evolution of the young stars. The maser emission of OH molecule was searched for towards a sample of high mass protostellar objects using the Nançay and GBT telescopes. The sample of objects searched was selected to contain very young forming high mass stars. The results of this survey have been compared with previous H2O and CH3OH masers observations. Then MERLIN has been used to map the OH as well as H2O and CH3OH masers towards one of these sources in high angular resolution. The survey detected OH maser emission towards 63 objects with 37 new detections. There are 56 star forming regions and 7 OH/IR candidates. The detection of OH masers towards 26% of a sample of 217 sources should remove any doubt about the existence of OH maser emission towards these objects of this early evolutionary stage. Nearly half of the detected sources have OH fluxes rates and velocity range support the spatial association of OH and class II CH3OH masers as suggested by Caswell et al. [1995] and modelled by Cragg et al. [2002]. IRAS20126+4104 was mapped in the OH, water and methanol masers using MERLIN. The 1665-MHz OH, 22-GHz H2O and 6.7-GHz CH3OH masers are detected and all originate very close to the central source. The OH and methanol masers appear to trace part of the circumstellar disk around the central source. The positions and velocities of the OH masers are consistent with Keplerian rotation around a central mass of ˜5Msun. The water masers are offset from the OH and CH3OH masers and have significantly changed since they were last observed, but still appear to be associated outflow from the source. All the OH masers components are circular polarized, in some cases reaching 100 percent while some OH components also have low levels of linear polarization. We identified one Zeeman pair and the splitting of this pair indicate the presence of a magnetic field of strength ˜11 mG within ˜0.5" (850 AU

  9. Spectral emissivity measurements of candidate materials for very high temperature reactors

    Energy Technology Data Exchange (ETDEWEB)

    Cao, G.; Weber, S.J.; Martin, S.O.; Anderson, M.H. [Department of Engineering Physics, University of Wisconsin, 1500 Engineering Drive, Madison, WI (United States); Sridharan, K., E-mail: kumars@cae.wisc.edu [Department of Engineering Physics, University of Wisconsin, 1500 Engineering Drive, Madison, WI (United States); Allen, T.R. [Department of Engineering Physics, University of Wisconsin, 1500 Engineering Drive, Madison, WI (United States)

    2012-10-15

    Heat dissipation by radiation is an important consideration in VHTR components, particularly the reactor pressure vessel (RPV), because of the fourth power temperature dependence of radiated heat. Since emissivity is the material property that dictates the ability to radiate heat, measurements of emissivities of materials that are being specifically considered for the construction of VHTR become important. Emissivity is a surface phenomenon and therefore compositional, structural, and topographical changes that occur at the surfaces of these materials as a result of their interactions with the environment at high temperatures will alter their emissivities. With this background, an experimental system for the measurement of spectral emissivity has been designed and constructed. The system has been calibrated in conformance with U.S. DoE quality assurance standards using inert ceramic materials, boron nitride, silicon carbide, and aluminum oxide. The results of high temperature emissivity measurements of potential VHTR materials such as ferritic steels SA 508, T22, T91 and austenitic alloys IN 800H, Haynes 230, IN 617, and 316 stainless steel have been presented.

  10. High emissivity TiC coatings for a first wall

    International Nuclear Information System (INIS)

    Groot, P.

    1991-08-01

    Part of the First Wall of the conceptual design of Next European Torus NET consist of radiation cooled carbon tiles. Tile temperature is determined by the optical properties of facing surfaces. Heat transfer to the 316 stainless steel structure can be improved by applying a high emissivity coating. For this purpose ceramic coatings can be applied. This paper deals with development and characterization of atmospheric and vacuum plasma sprayed titanium carbide as high emissivity coatings. Microstructural evaluation of these coatings includes X-ray diffraction and light microscopy of cross-sections. Total emissivities of vacuum and atmospheric plasma sprayed TiC coatings were measured at 525 K at PTB Braunschweig. Reflection measurements were performed at ECN Petten by using a YAG laser with wavelength 1.06 μm at room temperature. The effects of compositional differences on optical properties are discussed. (author). 9 refs.; 5 figs.; 1 tab

  11. Low emission turbulent technology for fuel combustion

    International Nuclear Information System (INIS)

    Finker, F. Z.; Kubyshkin, I. B.; Zakharov, B. Yu.; Akhmedov, D. B.; Sobchuk, Ch.

    1997-01-01

    The company 'POLITEKHENERGO' in co-operation and the Russian-Poland firm 'EnergoVIR' have performed investigations for modernization of the current existing boilers. A low emission turbulent technology has been used for the modernization of 10 industrial boilers. The reduction of NO x emissions is based on the following processes: 1) multistage combustion assured by two counter-deviated fluxes; 2) Some of the combustion facilities have an abrupt slope and a reduced air supply which leads to an intense separation of the fuel in the bottom part and a creation of a low-temperature combustion zone where the active restoration of the NO x takes part; 3) The influence of the top high-temperature zone on the NO x formation is small. Thus the 'sandwich' consisting of 'cold' and'hot' combustion layers provides a full rate combustion. This technique permits to: decrease of the NO x and CO x down to the European standard values;increase of the efficiency in 1-2%; obtain a stable coal combustion up to 97-98%; assure the large loading range (30 -100%); modernize and use the old boilers

  12. Garnet Yield Strength at High Pressures and Implications for Upper Mantle and Transition Zone Rheology

    International Nuclear Information System (INIS)

    Kavner, A.

    2008-01-01

    Garnet helps control the mechanical behavior of the Earth's crust, mantle, and transition zone. Here, measurements are presented suggesting that garnet, long considered to be a high-viscosity phase, is actually weaker than the other dominant components in the transition zone. The mechanical behavior of garnet at high pressures was examined using radial diffraction techniques in the diamond anvil cell. The yield strength of grossular garnet was inferred from synchrotron X-ray measurements of differential lattice strains. The differential stress was found to increase from 1.3 (±0.6) GPa at a hydrostatic pressure 5.8 (±1.1) GPa to 4.1 (±0.4) GPa at 15.7 (±1.0) GPa, where it was level to 19 GPa. The strength results are consistent with inferred strength values for majorite garnet from measurements in the diamond cell normal geometry, bolstering the idea that garnet-structured materials may all have similar strengths. In this low-temperature, high differential stress regime, garnet is shown to be significantly weaker than anhydrous ringwoodite and to have a strength similar to hydrous ringwoodite. This result suggests that the presence of water in the transition zone may not be required to explain a weak rheology, and therefore models of transition zone behavior built assuming that garnet is the high-strength phase may need to be revised.

  13. Offset, tilted dipole models of Uranian smooth high-frequency radio emission

    International Nuclear Information System (INIS)

    Schweitzer, A.E.; Romig, J.H.; Evans, D.R.; Sawyer, C.B.; Warwick, J.W.

    1990-01-01

    During the Voyager 2 encounter with Uranus in January 1986, the Planetary Radio Astronomy (PRA) experiment detected a complex pattern of radio emissions. Two types of emissions were seen: smooth and bursty. The smooth emission has been divided into smooth high-frequency (SHF) and smooth low-frequency (SLF) components which are presumed to come from different sources because of their distinctly different characteristics. The SHF component is considered in this paper. The SHF emission has been modeled by many authors on OTD (offset, tilted dipole (Ness et al., 1986)) L shells ranging from 5 to 40. However, the bursts have been modeled at much higher L shells. The authors complete an OTD investigation of the SHF emission at high L shells within the range of the bursty source locations, and present a viable high L shell model. This model has fundamentally the same longitudinally symmetric net emission pattern in space as the L shell 5 model presented in Romig et al. (1987) and Barbosa (1988). However, they were unable to produce an acceptable model on intermediate L shells without restricting source longitude. They discuss the similarities and distinctions between their two models and the models of other authors. They believe that the high L shell model (and others similar to it) cannot account for the observed smoothness and periodicity of the SHF emissions because it has open field lines containing untrapped particles, which should produce more variable emission than that seen in the SHF data. Therefore, the authors prefer models at L shells less than 18, the boundary for closed field lines (Ness et al., 1986). They then discuss and contrast two models within this boundary: the L = 5 model and an L ∼ 12 model by Kaiser et al. (1987) and Farrell and Calvert (1989b). The main distinction between these two models is the longitudinal extent of the source location

  14. Assessing fugitive emissions of CH4 from high-pressure gas pipelines

    Science.gov (United States)

    Worrall, Fred; Boothroyd, Ian; Davies, Richard

    2017-04-01

    The impact of unconventional natural gas production using hydraulic fracturing methods from shale gas basins has been assessed using life-cycle emissions inventories, covering areas such as pre-production, production and transmission processes. The transmission of natural gas from well pad to processing plants and its transport to domestic sites is an important source of fugitive CH4, yet emissions factors and fluxes from transmission processes are often based upon ver out of date measurements. It is important to determine accurate measurements of natural gas losses when compressed and transported between production and processing facilities so as to accurately determine life-cycle CH4 emissions. This study considers CH4 emissions from the UK National Transmission System (NTS) of high pressure natural gas pipelines. Mobile surveys of CH4 emissions using a Picarro Surveyor cavity-ring-down spectrometer were conducted across four areas in the UK, with routes bisecting high pressure pipelines and separate control routes away from the pipelines. A manual survey of soil gas measurements was also conducted along one of the high pressure pipelines using a tunable diode laser. When wind adjusted 92 km of high pressure pipeline and 72 km of control route were drive over a 10 day period. When wind and distance adjusted CH4 fluxes were significantly greater on routes with a pipeline than those without. The smallest leak detectable was 3% above ambient (1.03 relative concentration) with any leaks below 3% above ambient assumed ambient. The number of leaks detected along the pipelines correlate to the estimated length of pipe joints, inferring that there are constant fugitive CH4 emissions from these joints. When scaled up to the UK's National Transmission System pipeline length of 7600 km gives a fugitive CH4 flux of 4700 ± 2864 kt CH4/yr - this fugitive emission from high pressure pipelines is 0.016% of the annual gas supply.

  15. Audio-frequency noise emissions from high-voltage overhead power lines

    International Nuclear Information System (INIS)

    Semmler, M.; Straumann, U.; Roero, C.; Teich, T. H.

    2005-01-01

    This article discusses the noise-emissions caused by high-voltage overhead power lines that can occur under certain atmospheric conditions. These emissions, caused by electric discharges around the conductors, can achieve disturbing values, depending on the conditions prevailing at the time in question. The causes of the discharges are examined and the ionisation processes involved are looked at. The parameters influencing the discharges are discussed and measures that can be taken to reduce such audio-frequency emissions are looked at. The authors note that a reduction of peripheral field strengths can reduce emissions and that hydrophilic coatings can lead to faster reduction of such effects after rainfall

  16. Estimating NOx emissions and surface concentrations at high spatial resolution using OMI

    Science.gov (United States)

    Goldberg, D. L.; Lamsal, L. N.; Loughner, C.; Swartz, W. H.; Saide, P. E.; Carmichael, G. R.; Henze, D. K.; Lu, Z.; Streets, D. G.

    2017-12-01

    In many instances, NOx emissions are not measured at the source. In these cases, remote sensing techniques are extremely useful in quantifying NOx emissions. Using an exponential modified Gaussian (EMG) fitting of oversampled Ozone Monitoring Instrument (OMI) NO2 data, we estimate NOx emissions and lifetimes in regions where these emissions are uncertain. This work also presents a new high-resolution OMI NO2 dataset derived from the NASA retrieval that can be used to estimate surface level concentrations in the eastern United States and South Korea. To better estimate vertical profile shape factors, we use high-resolution model simulations (Community Multi-scale Air Quality (CMAQ) and WRF-Chem) constrained by in situ aircraft observations to re-calculate tropospheric air mass factors and tropospheric NO2 vertical columns during summertime. The correlation between our satellite product and ground NO2 monitors in urban areas has improved dramatically: r2 = 0.60 in new product, r2 = 0.39 in operational product, signifying that this new product is a better indicator of surface concentrations than the operational product. Our work emphasizes the need to use both high-resolution and high-fidelity models in order to re-calculate vertical column data in areas with large spatial heterogeneities in NOx emissions. The methodologies developed in this work can be applied to other world regions and other satellite data sets to produce high-quality region-specific emissions estimates.

  17. Microstructures for high-energy x-ray and particle-imaging applications

    International Nuclear Information System (INIS)

    Ceglio, N.M.; Stone, G.F.; Hawryluk, A.M.

    1981-05-01

    Coded imaging techniques using thick, micro-Fresnel zone plates as coded apertures have been used to image x-ray emissions (2-20 keV) and 3.5 MeV Alpha particle emissions from laser driven micro-implosions. Image resolution in these experiments was 3-8 μm. Extension of this coded imaging capability to higher energy x-rays (approx. 100 keV) and more penetrating charged particles (e.g. approx. 15 MeV protons) requires the fabrication of very thick (50-200 μm), high aspect ratio (10:1), gold Fresnel zone plates with narrow linewidths (5-25 μm) for use as coded aperatures. A reactive ion etch technique in oxygen has been used to produce thick zone plate patterns in polymer films. The polymer patterns serve as electroplating molds for the subsequent fabrication of the free-standing gold zone plate structures

  18. Numerical Simulation of a Non-volcanic Hydrothermal System Caused by Formation of a High Permeability Fracture Zone

    Science.gov (United States)

    Oka, Daisuke; Ehara, Sachio; Fujimitsu, Yasuhiro

    2010-05-01

    Because in the Japanese islands the earth crust activity is very active, a disposal stratum for high-level radioactive waste produced by reprocessing the spent nuclear fuel from nuclear power plants will be selected in the tectonically stable areas in which the waste can be disposed underground safely for a long term and there is no influence of earthquakes, seismic activities, volcanic activities, upheaval, sedimentation, erosion, climate and global sea level change and so on, which causes the risk of the inflow of the groundwater to destroy the disposal site or the outflow to the ground surface. However, even if the disposal stratum in such condition will be chosen, in case that a new high permeability fracture zone is formed by the earthquake, and a new hydrothermal system may be formed for a long term (thousands or millions years) and the system may affect the disposal site. Therefore, we have to understand the feature of the non-volcanic hydrothermal system through the high permeability fracture zone. We estimated such influence by using HYDROTHERM Ver2.2 (Hayba & Ingebritsen, 1994), which is a three-dimensional numerical reservoir simulator. The model field is the northwestern part of Kego Fault, which was formed by a series of earthquakes called "the 2005 Fukuoka Prefecture Western Offshore Earthquakes" (the main shock of Mjma 7.0 on 20 March 2005) in Kyushu, Japan. The results of the numerical simulations show the development of a low temperature hydrothermal system as a new fracture zone is formed, in case that there is no volcanic heat source. The results of the simulations up to 100,000 years after formation of the fracture zone show that the higher heat flow and the wider and more permeable fracture zone accelerate the development of the hydrothermal system in the fracture zone. As a result of calculation of up to10 million years, we clarified the evolutional process of the non-volcanic hydrothermal system through the high permeability fracture zone. At

  19. Biogenic volatile organic compound emissions along a high arctic soil moisture gradient

    DEFF Research Database (Denmark)

    Svendsen, Sarah Hagel; Lindwall, Frida; Michelsen, Anders

    2016-01-01

    emissions of BVOCs were found from vegetation communities dominated by Salix arctica and Cassiope tetragona, which had emission profiles dominated by isoprene and monoterpenes, respectively. These results show that emissions of BVOCs are highly dependent on the plant cover supported by the varying soil...

  20. Parapapillary atrophy: histological gamma zone and delta zone.

    Directory of Open Access Journals (Sweden)

    Jost B Jonas

    Full Text Available BACKGROUND: To examine histomorphometrically the parapapillary region in human eyes. METHODOLOGY/PRINCIPAL FINDINGS: The histomorphometric study included 65 human globes (axial length:21-37 mm. On anterior-posterior histological sections, we measured the distance Bruch's membrane end (BME-optic nerve margin ("Gamma zone", BME-retinal pigment epithelium (RPE ("Beta zone", BME-beginning of non-occluded choriocapillaris, and BME-beginning of photoreceptor layer. "Delta zone" was defined as part of gamma zone in which blood vessels of at least 50 µm diameter were not present over a length of >300 µm. Beta zone (mean length:0.35±0.52 mm was significantly (P = 0.01 larger in the glaucoma group than in the non-glaucomatous group. It was not significantly (P = 0.28 associated with axial length. Beta zone was significantly (P = 0.004 larger than the region with occluded choriocapillaris. Gamma zone (mean length:0.63±1.25 mm was associated with axial length (P50 µm diameter within gamma zone was present only in highly axially elongated globes and was not related with glaucoma. Beta zone (Bruch's membrane without RPE was correlated with glaucoma but not with globe elongation. Since the region with occluded choriocapillaris was smaller than beta zone, complete loss of RPE may have occurred before complete choriocapillaris closure.

  1. High-gain bipolar detector on float-zone silicon

    Science.gov (United States)

    Han, D. J.; Batignani, G.; Del Guerra, A.; Dalla Betta, G.-F.; Boscardin, M.; Bosisio, L.; Giorgi, M.; Forti, F.

    2003-10-01

    Since the float-zone (FZ) silicon has lower contaminations and longer minority-carrier lifetime than those in Czochralski silicon and other semiconductor materials, it has potential advantages to fabricate bipolar detectors on the high-purity FZ silicon substrate to achieve a high gain at ultra-low-signal levels. The authors present preliminary experimental results on a bipolar detector fabricated on an unusual high-purity FZ silicon substrate. A backside gettering layer of phosphorus-doped polysilicon was employed to preserve the long carrier lifetime of the high-purity FZ silicon. The device has been investigated in the detection of a continuous flux of X-ray and infrared light. The bipolar detector with a circular emitter of 2 mm diameter has demonstrated high gains up to 3820 for 22 keV X-ray from a 1 mCi Cd radioactive source (the X-ray photon flux, received by the detector is estimated to be ˜7.77×10 4/s). High gain up to 4400 for 0.17 nW light with a wavelength of 0.83 μm has been observed for the same device.

  2. High-gain bipolar detector on float-zone silicon

    International Nuclear Information System (INIS)

    Han, D.J.; Batignani, G.; Guerra, A.D.A. Del; Dalla Betta, G.-F.; Boscardin, M.; Bosisio, L.; Giorgi, M.; Forti, F.

    2003-01-01

    Since the float-zone (FZ) silicon has lower contaminations and longer minority-carrier lifetime than those in Czochralski silicon and other semiconductor materials, it has potential advantages to fabricate bipolar detectors on the high-purity FZ silicon substrate to achieve a high gain at ultra-low-signal levels. The authors present preliminary experimental results on a bipolar detector fabricated on an unusual high-purity FZ silicon substrate. A backside gettering layer of phosphorus-doped polysilicon was employed to preserve the long carrier lifetime of the high-purity FZ silicon. The device has been investigated in the detection of a continuous flux of X-ray and infrared light. The bipolar detector with a circular emitter of 2 mm diameter has demonstrated high gains up to 3820 for 22 keV X-ray from a 1 mCi Cd radioactive source (the X-ray photon flux, received by the detector is estimated to be ∼7.77x10 4 /s). High gain up to 4400 for 0.17 nW light with a wavelength of 0.83 μm has been observed for the same device

  3. Progress in the fabrication of high aspect ratio zone plates by soft x-ray lithography

    International Nuclear Information System (INIS)

    Divan, R.; Mancini, D. C.; Moldovan, N. A.; Lai, B.; Assoufid, L.; Leondard, Q.; Cerrina, F.

    2002-01-01

    Fabrication of Fresnel zone plates for the hard x-ray spectral region combines the challenge of high lateral resolution (∼100 nm) with a large thickness requirement for the phase-shifting material (0.5-3 (micro)m). For achieving a high resolution, the initial mask was fabricated by e-beam lithography and gold electroforming. To prevent the collapse of the structures between the developing and electroforming processes, drying was completely eliminated. Fabrication errors, such as nonuniform gold electroplating and collapse of structures, were systematically analyzed and largely eliminated. We optimized the exposure and developing processes for 950k and 2200k polymethylmethacrylate of different thicknesses and various adhesion promoters. We discuss the effects of these fabrication steps on the zone plate's resolution and aspect ratio. Fresnel zone plates with 110 nm outermost zone width, 150 (micro)m diameter, and 1.3 (micro)m gold thickness were fabricated. Preliminary evaluation of the FZPs was done by scanning electron microscopy and atomic force microscopy. The FZP focusing performance was characterized at the Advanced Photon Source at Argonne National Laboratory

  4. High performance bulk metallic glass/carbon nanotube composite cathodes for electron field emission

    International Nuclear Information System (INIS)

    Hojati-Talemi, Pejman; Gibson, Mark A.; East, Daniel; Simon, George P.

    2011-01-01

    We report the preparation of new nanocomposites based on a combination of bulk metallic glass and carbon nanotubes for electron field emission applications. The use of bulk metallic glass as the matrix ensures high electrical and thermal conductivity, high thermal stability, and ease of processing, whilst the well dispersed carbon nanotubes act as highly efficient electron emitters. These advantages, alongside excellent electron emission properties, make these composites one of the best reported options for electron emission applications to date.

  5. High performance bulk metallic glass/carbon nanotube composite cathodes for electron field emission

    Energy Technology Data Exchange (ETDEWEB)

    Hojati-Talemi, Pejman [Department of Materials Engineering, Monash University, Clayton, Vic 3800 (Australia); Mawson Institute, University of South Australia, Mawson Lakes, SA 5095 (Australia); Gibson, Mark A. [Process Science and Engineering, Commonwealth Scientific and Industrial Research Organisation, Clayton, Vic 3168 (Australia); East, Daniel; Simon, George P. [Department of Materials Engineering, Monash University, Clayton, Vic 3800 (Australia)

    2011-11-07

    We report the preparation of new nanocomposites based on a combination of bulk metallic glass and carbon nanotubes for electron field emission applications. The use of bulk metallic glass as the matrix ensures high electrical and thermal conductivity, high thermal stability, and ease of processing, whilst the well dispersed carbon nanotubes act as highly efficient electron emitters. These advantages, alongside excellent electron emission properties, make these composites one of the best reported options for electron emission applications to date.

  6. Time-resolved analysis of particle emissions from residential biomass combustion - Emissions of refractory black carbon, PAHs and organic tracers

    Science.gov (United States)

    Nielsen, Ingeborg E.; Eriksson, Axel C.; Lindgren, Robert; Martinsson, Johan; Nyström, Robin; Nordin, Erik Z.; Sadiktsis, Ioannis; Boman, Christoffer; Nøjgaard, Jacob K.; Pagels, Joakim

    2017-09-01

    Time-resolved particle emissions from a conventional wood stove were investigated with aerosol mass spectrometry to provide links between combustion conditions, emission factors, mixing state of refractory black carbon and implications for organic tracer methods. The addition of a new batch of fuel results in low temperature pyrolysis as the fuel heats up, resulting in strong, short-lived, variable emission peaks of organic aerosol-containing markers of anhydrous sugars, such as levoglucosan (fragment at m/z 60). Flaming combustion results in emissions dominated by refractory black carbon co-emitted with minor fractions of organic aerosol and markers of anhydrous sugars. Full cycle emissions are an external mixture of larger organic aerosol-dominated and smaller thinly coated refractory black carbon particles. A very high burn rate results in increased full cycle mass emission factors of 66, 2.7, 2.8 and 1.3 for particulate polycyclic aromatic hydrocarbons, refractory black carbon, total organic aerosol and m/z 60, respectively, compared to nominal burn rate. Polycyclic aromatic hydrocarbons are primarily associated with refractory black carbon-containing particles. We hypothesize that at very high burn rates, the central parts of the combustion zone become air starved, leading to a locally reduced combustion temperature that reduces the conversion rates from polycyclic aromatic hydrocarbons to refractory black carbon. This facilitates a strong increase of polycyclic aromatic hydrocarbons emissions. At nominal burn rates, full cycle emissions based on m/z 60 correlate well with organic aerosol, refractory black carbon and particulate matter. However, at higher burn rates, m/z 60 does not correlate with increased emissions of polycyclic aromatic hydrocarbons, refractory black carbon and organic aerosol in the flaming phase. The new knowledge can be used to advance source apportionment studies, reduce emissions of genotoxic compounds and model the climate impacts of

  7. High-resolution forest carbon stocks and emissions in the Amazon.

    Science.gov (United States)

    Asner, Gregory P; Powell, George V N; Mascaro, Joseph; Knapp, David E; Clark, John K; Jacobson, James; Kennedy-Bowdoin, Ty; Balaji, Aravindh; Paez-Acosta, Guayana; Victoria, Eloy; Secada, Laura; Valqui, Michael; Hughes, R Flint

    2010-09-21

    Efforts to mitigate climate change through the Reduced Emissions from Deforestation and Degradation (REDD) depend on mapping and monitoring of tropical forest carbon stocks and emissions over large geographic areas. With a new integrated use of satellite imaging, airborne light detection and ranging, and field plots, we mapped aboveground carbon stocks and emissions at 0.1-ha resolution over 4.3 million ha of the Peruvian Amazon, an area twice that of all forests in Costa Rica, to reveal the determinants of forest carbon density and to demonstrate the feasibility of mapping carbon emissions for REDD. We discovered previously unknown variation in carbon storage at multiple scales based on geologic substrate and forest type. From 1999 to 2009, emissions from land use totaled 1.1% of the standing carbon throughout the region. Forest degradation, such as from selective logging, increased regional carbon emissions by 47% over deforestation alone, and secondary regrowth provided an 18% offset against total gross emissions. Very high-resolution monitoring reduces uncertainty in carbon emissions for REDD programs while uncovering fundamental environmental controls on forest carbon storage and their interactions with land-use change.

  8. Identification and quantification of shipping emissions in Bohai Rim, China

    International Nuclear Information System (INIS)

    Zhang, Fan; Chen, Yingjun; Tian, Chongguo; Wang, Xiaoping; Huang, Guopei; Fang, Yin; Zong, Zheng

    2014-01-01

    Rapid development of port and shipbuilding industry in China has badly affected the ambient air quality of coastal zone due to shipping emissions. A total of 60 ambient air samples were collected from background site of Tuoji Island in Bohai Sea strait. The air samples were analyzed for PM 2.5 , organic carbon (OC), element carbon (EC), inorganic elements, and water-soluble ions. The maximum concentration of PM 2.5 was observed during spring (73.6 μg·m −3 ) compared to winter (39.0 μg·m −3 ) with mean of 54.6 μg·m −3 . Back trajectory air mass analysis together with temporal distribution of vanadium (V) showed that V could be the typical tracer of shipping emissions at Tuoji Island. Furthermore, the ratios of vanadium to nickel (V/Ni), vanadium to lead (V/Pb) and vanadium to zinc (V/Zn) also suggest shipping emissions at Tuoji Island. The annual average primary PM 2.5 estimate of shipping emissions was 0.65 μg·m −3 at Tuoji Island, accounting for 2.94% of the total primary PM 2.5 , with a maximum of 3.16% in summer and a minimum of 2.39% in autumn. - Highlights: • Tracers of shipping emissions in coastal zone of northern China were identified. • Contributions of shipping emissions on primary PM 2.5 were estimated. • Shipping emissions accounted for 2.94% of primary PM 2.5 apart from fishing boats. • Impact of shipping emissions on coastal zone increased rapidly in recent years

  9. Recombination region improvement for reduced efficiency roll-off in phosphorescent OLEDs with dual emissive layers

    Energy Technology Data Exchange (ETDEWEB)

    Ma, Zhu; Zhou, Shunliang [State Key Laboratory of Electronic Thin Films and Integrated Devices, School of Optoelectronic Information, University of Electronic Science and Technology of China (UESTC), Chengdu 610054 (China); Hu, Song [Chengdu Institute of Optics and Electronics, Chinese Academy of Sciences, Chengdu 610209 (China); Yu, Junsheng, E-mail: jsyu@uestc.edu.cn [State Key Laboratory of Electronic Thin Films and Integrated Devices, School of Optoelectronic Information, University of Electronic Science and Technology of China (UESTC), Chengdu 610054 (China)

    2014-10-15

    High-performance phosphorescent organic light-emitting diodes (PhOLEDs) by using dual-emissive-layer (DEL) structure to reduce efficiency roll-off were fabricated. The DEL was comprised of a hole-transport-type host of N, N′-bis(naphthalen-1-yl)-N, N′-bis(phenyl)-benzidine (NPB) and a bipolar host of 4,4′-bis(carbazol-9-yl)biphenyl (CBP), which were both doped with an orange phosphorescent dopant of bis[2-(4-tert-butylphenyl)-benzothiazolato-N,C2′]iridium (acetylacetonate) [(t-bt){sub 2}Ir(acac)]. After the optimization of doping concentration of the first emissive layer (FEL), the device with DEL exhibited 11% lower roll-off power efficiency than single emissive layer devices (SED) when the luminance increased from 1000 cd/m{sup 2} to 10,000 cd/m{sup 2}. The hole–electron recombination zone in DEL was illuminated by inserting an ultrathin fluorescent probe of 4-(dicyanomethylene)-2-tert-butyl-6 (1,1,7,7-tetramethyljulolidin-4-yl-vinyl)-4H-pyran (DCJTB) in different emissive regions. The performance improvement was attributed to the optimization of energy barrier and the expansion of exciton formation zone within the DEL. - Highlights: • PhOLEDs by using a dual-emissive-layer structure to reduce efficiency roll-off were fabricated. • The DED exhibited 11% lower efficiency roll-off, 57% lower turn-on voltage, and 174% higher brightness than SED. • A DCJTB fluorescent probe was inserted at different positions of DED to investigate the expansion of exciton formation zone.

  10. High performance field emission of silicon carbide nanowires and their applications in flexible field emission displays

    Science.gov (United States)

    Cui, Yunkang; Chen, Jing; Di, Yunsong; Zhang, Xiaobing; Lei, Wei

    2017-12-01

    In this paper, a facile method to fabricate the flexible field emission devices (FEDs) based on SiC nanostructure emitters by a thermal evaporation method has been demonstrated. The composition characteristics of SiC nanowires was characterized by X-ray diffraction (XRD), selected area electron diffraction (SAED) and energy dispersive X-ray spectrometer (EDX), while the morphology was revealed by field emission scanning electron microscopy (SEM) and high resolution transmission electron microscopy (HRTEM). The results showed that the SiC nanowires grew along the [111] direction with the diameter of ˜110 nm and length of˜30 μm. The flexible FEDs have been fabricated by transferring and screen-printing the SiC nanowires onto the flexible substrates exhibited excellent field emission properties, such as the low turn-on field (˜0.95 V/μm) and threshold field (˜3.26 V/μm), and the high field enhancement factor (β=4670). It is worth noting the current density degradation can be controlled lower than 2% per hour during the stability tests. In addition, the flexible FEDs based on SiC nanowire emitters exhibit uniform bright emission modes under bending test conditions. As a result, this strategy is very useful for its potential application in the commercial flexible FEDs.

  11. High performance field emission of silicon carbide nanowires and their applications in flexible field emission displays

    Directory of Open Access Journals (Sweden)

    Yunkang Cui

    2017-12-01

    Full Text Available In this paper, a facile method to fabricate the flexible field emission devices (FEDs based on SiC nanostructure emitters by a thermal evaporation method has been demonstrated. The composition characteristics of SiC nanowires was characterized by X-ray diffraction (XRD, selected area electron diffraction (SAED and energy dispersive X-ray spectrometer (EDX, while the morphology was revealed by field emission scanning electron microscopy (SEM and high resolution transmission electron microscopy (HRTEM. The results showed that the SiC nanowires grew along the [111] direction with the diameter of ∼110 nm and length of∼30 μm. The flexible FEDs have been fabricated by transferring and screen-printing the SiC nanowires onto the flexible substrates exhibited excellent field emission properties, such as the low turn-on field (∼0.95 V/μm and threshold field (∼3.26 V/μm, and the high field enhancement factor (β=4670. It is worth noting the current density degradation can be controlled lower than 2% per hour during the stability tests. In addition, the flexible FEDs based on SiC nanowire emitters exhibit uniform bright emission modes under bending test conditions. As a result, this strategy is very useful for its potential application in the commercial flexible FEDs.

  12. Detection of formaldehyde emissions from an industrial zone in the Yangtze River Delta region of China using a proton transfer reaction ion-drift chemical ionization mass spectrometer

    Science.gov (United States)

    Ma, Yan; Diao, Yiwei; Zhang, Bingjie; Wang, Weiwei; Ren, Xinrong; Yang, Dongsen; Wang, Ming; Shi, Xiaowen; Zheng, Jun

    2016-12-01

    A proton transfer reaction ion-drift chemical ionization mass spectrometer (PTR-ID-CIMS) equipped with a hydronium (H3+O) ion source was developed and deployed near an industrial zone in the Yangtze River Delta (YRD) region of China in spring 2015 to investigate industry-related emissions of volatile organic compounds (VOCs). Air pollutants including formaldehyde (HCHO), aromatics, and other trace gases (O3 and CO) were simultaneously measured. Humidity effects on the sensitivity of the PTR-ID-CIMS for HCHO detection were investigated and quantified. The performances of the PTR-ID-CIMS were also validated by intercomparing with offline HCHO measurement technique using 2,4-dinitrophenylhydrazone (DNPH) cartridges and the results showed fairly good agreement (slope = 0.81, R2 = 0.80). The PTR-ID-CIMS detection limit of HCHO (10 s, three-duty-cycle averages) was determined to be 0.9-2.4 (RH = 1-81.5 %) parts per billion by volume (ppbv) based on 3 times the standard deviations of the background signals. During the field study, observed HCHO concentrations ranged between 1.8 and 12.8 ppbv with a campaign average of 4.1 ± 1.6 ppbv, which was comparable with previous HCHO observations in other similar locations of China. However, HCHO diurnal profiles showed few features of secondary formation. In addition, time series of both HCHO and aromatic VOCs indicated strong influence from local emissions. Using a multiple linear regression fit model, on average the observed HCHO can be attributed to secondary formation (13.8 %), background level (27.0 %), and industry-related emissions, i.e., combustion sources (43.2 %) and chemical productions (16.0 %). Moreover, within the plumes the industry-related emissions can account for up to 69.2 % of the observed HCHO. This work has provided direct evidence of strong primary emissions of HCHO from industry-related activities. These primary HCHO sources can potentially have a strong impact on local and regional air pollution formation

  13. Emission spectroscopy of highly ionized high-temperature plasma jets

    Energy Technology Data Exchange (ETDEWEB)

    Belevtsev, A A; Chinnov, V F; Isakaev, E Kh [Associated Institute for High Temperatures, Russian Academy of Sciences Izhorskaya 13/19, Moscow, 125412 (Russian Federation)

    2006-08-01

    This paper deals with advanced studies on the optical emission spectroscopy of atmospheric pressure highly ionized high-temperature argon and nitrogen plasma jets generated by a powerful arc plasmatron. The emission spectra are taken in the 200-1000 nm range with a spectral resolution of {approx}0.01-0.02 nm. The exposure times are 6 x 10{sup -6}-2 x 10{sup -2} s, the spatial resolution is 0.02-0.03 mm. The recorded jet spectra are abundant in spectral lines originating from different ionization stages. In nitrogen plasmas, tens of vibronic bands are also observed. To interpret and process these spectra such that plasma characteristics can be derived, a purpose-developed automated processing system is applied. The use of a CCD camera at the spectrograph output allows a simultaneous recording of the spectral and chord intensity distributions of spectral lines, which can yet belong to the overlapped spectra of the first and second orders of interference. The modern optical diagnostic means and methods used permit the determination of spatial distributions of electron number densities and temperatures and evaluation of rotational temperatures. The radial profiles of the irradiating plasma components can also be obtained. Special attention is given to the method of deriving rotational temperatures using vibronic bands with an incompletely identified rotational structure.

  14. EMISSION AND COMBUSTION CHARACTERISTICS OF DIFFERENT FUELS IN A HCCI ENGINE

    Directory of Open Access Journals (Sweden)

    S. Sendilvelan

    2011-06-01

    Full Text Available Different intake valve timings and fuel injection amounts were tested in order to identify their effects on exhaust emissions and combustion characteristics using variable valve actuation (VVA in a Homogeneous Charge Compression Ignition (HCCI engine. The HCCI engine is a promising concept for future automobile engines and stationary power plants. The two-stage ignition process in a HCCI engine creates advanced ignition and stratified combustion, which makes the ignition timing and combustion rate controllable. Meanwhile, the periphery of the fuel-rich zone leads to fierce burning, which results in slightly high NOx emissions. The experiments were conducted in a modified single cylinder water-cooled diesel engine. In this experiment we use diesel, bio-diesel (Jatropha and gasoline as the fuel at different mixing ratios. HCCI has advantages in high thermal efficiency and low emissions and could possibly become a promising combustion method in internal combustion engines.

  15. Methane emissions from a high arctic valley: findings and challenges

    DEFF Research Database (Denmark)

    Mastepanov, Mikhail; Sigsgaard, Charlotte; Ström, Lena

    2008-01-01

    Wet tundra ecosystems are well-known to be a significant source of atmospheric methane. With the predicted stronger effect of global climate change on arctic terrestrial ecosystems compared to lower-latitudes, there is a special obligation to study the natural diversity and the range of possible...... feedback effects on global climate that could arise from Arctic tundra ecosystems. One of the prime candidates for such a feedback mechanism is a potential change in the emissions of methane. Long-term datasets on methane emissions from high arctic sites are almost non-existing but badly needed...... for analyses of controls on interannual and seasonal variations in emissions. To help fill this gap we initiated a measurement program in a productive high arctic fen in the Zackenberg valley, NE Greenland. Methane flux measurements have been carried out at the same location since 1997. Compared...

  16. Determination of pumper truck intervention ratios in zones with high fire potential by using geographical information system

    Science.gov (United States)

    Aricak, Burak; Kucuk, Omer; Enez, Korhan

    2014-01-01

    Fighting forest fires not only depends on the forest type, topography, and weather conditions, but is also closely related to the technical properties of fire-fighting equipment. Firefighting is an important part of fire management planning. However, because of the complex nature of forests, creating thematic layers to generate potential fire risk maps is difficult. The use of remote sensing data has become an efficient method for the discrete classification of potential fire risks. The study was located in the Central District of the Kastamonu Regional Forest Directorate, covering an area of 24,320 ha, 15,685 ha of which is forested. On the basis of stand age, crown closure, and tree species, the sizes and distributions of potential fire risk zones within the study area were determined using high-resolution GeoEye satellite imagery and geographical information system data. The status of pumper truck intervention in zones with high fire risk and the sufficiency of existing forest roads within an existing forest network were discussed based on combustible matter characteristics. Pumper truck intervention was 83% for high-risk zones, 79% for medium-risk zones, and 78% for low-risk zones. A pumper truck intervention area map along existing roads was also created.

  17. Aspects related to 'emission trading'

    International Nuclear Information System (INIS)

    Tutuianu, Ovidiu

    1999-01-01

    The paper presents the aspects of international GHG (greenhouse gases) emission trading, such as: quality of GHG emission data, possible partners, monitoring activity, market mechanisms and difficulties. The following conclusions are drown: - debates on international trade with GHG emissions are currently in a very early stage; - actions are possible and feasible, particularly after Kyoto Conference, as versatile mechanism (besides the Joint Implementation Projects) which have in view the lowering of the global emission costs in different zones of the planet; - difficulties concerning monitoring, reporting and verification, practically preclude implementing a system of emission trading covering all the GHG, all the sources and reservoirs; - an international viable system of emission trading could initiate with a limited number of participants and consideration of only emission categories easy to be confined and surveyed; - existence of a national market and corresponding institutions for monitoring which could booster an international system development

  18. Dynamical observations on the crack tip zone and stress corrosion of two-dimensional MoS2

    KAUST Repository

    Ly, Thuc Hue

    2017-01-18

    Whether and how fracture mechanics needs to be modified for small length scales and in systems of reduced dimensionality remains an open debate. Here, employing in situ transmission electron microscopy, atomic structures and dislocation dynamics in the crack tip zone of a propagating crack in two-dimensional (2D) monolayer MoS2 membrane are observed, and atom-to-atom displacement mapping is obtained. The electron beam is used to initiate the crack; during in situ observation of crack propagation the electron beam effect is minimized. The observed high-frequency emission of dislocations is beyond previous understanding of the fracture of brittle MoS2. Strain analysis reveals dislocation emission to be closely associated with the crack propagation path in nanoscale. The critical crack tip plastic zone size of nearly perfect 2D MoS2 is between 2 and 5 nm, although it can grow to 10 nm under corrosive conditions such as ultraviolet light exposure, showing enhanced dislocation activity via defect generation.

  19. Effect of inserted metal at anode tip on formation of pulsed X-ray emitting zone of plasma focus device

    Science.gov (United States)

    Miremad, Seyed Milad; Shirani Bidabadi, Babak

    2018-04-01

    The effect of the anode's insert material of a plasma focus device on the properties of X-ray emission zone was studied. Inserts were fabricated out of six different materials including aluminum, copper, zinc, tin, tungsten, and lead to cover a wide range of atomic numbers. For each anode's insert material at different gas pressures and different voltages, the shape of X-ray emission zone was recorded by three pinhole cameras, which were installed on sidewall and roof of the chamber of plasma focus device. The results indicated that by changing the gas pressure and the charge voltage of capacitor, the X-ray source of plasma focus emerges with different forms as a concentrated column or conical shape with sharp or cloudy edges. These structures are in the form of a combination of plasma emission and anode-tip emission with different intensities. These observations indicate that the material of the anode-tip especially affects the structure of X-ray emission zone.

  20. High-resolution atmospheric emission inventory of the argentine energy sector. Comparison with edgar global emission database

    Directory of Open Access Journals (Sweden)

    S. Enrique Puliafito

    2017-12-01

    Full Text Available This study presents a 2014 high-resolution spatially disaggregated emission inventory (0.025° × 0.025° horizontal resolution, of the main activities in the energy sector in Argentina. The sub-sectors considered are public generation of electricity, oil refineries, cement production, transport (maritime, air, rail and road, residential and commercial. The following pollutants were included: greenhouse gases (CO2, CH4, N2O, ozone precursors (CO, NOx, VOC and other specific air quality indicators such as SO2, PM10, and PM2.5. This work could contribute to a better geographical allocation of the pollutant sources through census based population maps. Considering the sources of greenhouse gas emissions, the total amount is 144 Tg CO2eq, from which the transportation sector emits 57.8 Tg (40%; followed by electricity generation, with 40.9 Tg (28%; residential + commercial, with 31.24 Tg (22%; and cement and refinery production, with 14.3 Tg (10%. This inventory shows that 49% of the total emissions occur in rural areas: 31% in rural areas of medium population density, 13% in intermediate urban areas and 7% in densely populated urban areas. However, if emissions are analyzed by extension (per square km, the largest impact is observed in medium and densely populated urban areas, reaching more than 20.3 Gg per square km of greenhouse gases, 297 Mg/km2 of ozone precursors gases and 11.5 Mg/km2 of other air quality emissions. A comparison with the EDGAR global emission database shows that, although the total country emissions are similar for several sub sectors and pollutants, its spatial distribution is not applicable to Argentina. The road and residential transport emissions represented by EDGAR result in an overestimation of emissions in rural areas and an underestimation in urban areas, especially in more densely populated areas. EDGAR underestimates 60 Gg of methane emissions from road transport sector and fugitive emissions from refining

  1. High-Velocity Ly(Alpha) Emission from SMR 1987A

    Science.gov (United States)

    Michael, Eli; McCray, Richard; Borkowski, Kazimierz J.; Pun, Chu S. J.; Sonneborn, George

    1998-01-01

    The high-velocity Ly(Alpha) emission from SN 1987A observed with the Space Telescope Imaging Spectrograph (STIS) evidently comes from a reverse shock formed where the outer envelope of SN 1987A strikes ionized gas inside the inner circumstellar ring. The observations can be explained by a simple kinematic model, in which the Ly(Alpha) emission comes from hydrogen atoms with radial velocity approximately 15,000 km s(exp -1) crossing a reverse shock in the shape of a slightly prolate ellipsoid with equatorial radius 4.8 x 10(exp 17) cm or approximately 80% of the distance to the inner surface of the inner ring. N v double Lambda 1239, 1243 emission, if present, has a net luminosity approximately less than 30% times that of the Ly(Alpha) emission. Future STIS observations should enable us to predict the time of impact with the inner ring and to determine unambiguously whether or not N v emission is present. These observations will offer a unique opportunity to probe the structure of SN 1987A's circumstellar environment and the hydrodynamics and kinetics of very fast shocks.

  2. Ecological risk caused by land use change in the coastal zone: a case study in the Yellow River Delta High-Efficiency Ecological Economic Zone

    International Nuclear Information System (INIS)

    Di, X H; Wang, Y D; Hou, X Y

    2014-01-01

    China's coastal zone plays an important role in ecological services production and social-economic development; however, extensive and intensive land resource utilization and land use change have lead to high ecological risk in this area during last decade. Regional ecological risk assessment can provide fundamental knowledge and scientific basis for better understanding of the relationship between regional landscape ecosystem and human activities or climate changes, facilitating the optimization strategy of land use structure and improving the ecological risk prevention capability. In this paper, the Yellow River Delta High-Efficiency Ecological Economic Zone is selected as the study site, which is undergoing a new round of coastal zone exploitation and has endured substantial land use change in the past decade. Land use maps of 2000, 2005 and 2010 were generated based on Landsat images by visual interpretation method, and the ecological risk index was then calculated. The index was 0.3314, 0.3461 and 0.3176 in 2000, 2005 and 2010 respectively, which showed a positive transition of regional ecological risk in 2005

  3. Highly charged ion based time-of-flight emission microscope

    International Nuclear Information System (INIS)

    Hamza, Alex V.; Barnes, Alan V.; Magee, Ed; Newman, Mike; Schenkel, Thomas; McDonald, Joseph W.; Schneider, Dieter H.

    2000-01-01

    An emission microscope using highly charged ions as the excitation source has been designed, constructed, and operated. A novel ''acorn'' objective lens has been used to simultaneously image electron and secondary ion emission. A resistive anode-position sensitive detector is used to determine the x-y position and time of arrival of the secondary events at the microscope image plane. Contrast in the image can be based on the intensity of the electron emission and/or the presence of particular secondary ions. Spatial resolution of better than 1 μm and mass resolution m/Δm of better than 400 were demonstrated. Background rejection from uncorrelated events of greater than an order of magnitude is also achieved. (c) 2000 American Institute of Physics

  4. Identification and quantification of shipping emissions in Bohai Rim, China

    Energy Technology Data Exchange (ETDEWEB)

    Zhang, Fan [Key Laboratory of Coastal Zone Environmental Processes and Ecological Remediation, Yantai Institute of Coastal Zone Research, Chinese Academy of Sciences, Yantai, Shandong 264003 (China); University of Chinese Academy of Sciences, Beijing 100049 (China); Chen, Yingjun, E-mail: yjchen@yic.ac.cn [Key Laboratory of Coastal Zone Environmental Processes and Ecological Remediation, Yantai Institute of Coastal Zone Research, Chinese Academy of Sciences, Yantai, Shandong 264003 (China); Tian, Chongguo, E-mail: cgtian@yic.ac.cn [Key Laboratory of Coastal Zone Environmental Processes and Ecological Remediation, Yantai Institute of Coastal Zone Research, Chinese Academy of Sciences, Yantai, Shandong 264003 (China); Wang, Xiaoping [University of Chinese Academy of Sciences, Beijing 100049 (China); State Key Laboratory of Organic Geochemistry, Guangzhou Institute of Geochemistry, Chinese Academy of Sciences, Guangzhou, Guangdong 510640 (China); Huang, Guopei; Fang, Yin; Zong, Zheng [Key Laboratory of Coastal Zone Environmental Processes and Ecological Remediation, Yantai Institute of Coastal Zone Research, Chinese Academy of Sciences, Yantai, Shandong 264003 (China); University of Chinese Academy of Sciences, Beijing 100049 (China)

    2014-11-01

    Rapid development of port and shipbuilding industry in China has badly affected the ambient air quality of coastal zone due to shipping emissions. A total of 60 ambient air samples were collected from background site of Tuoji Island in Bohai Sea strait. The air samples were analyzed for PM{sub 2.5}, organic carbon (OC), element carbon (EC), inorganic elements, and water-soluble ions. The maximum concentration of PM{sub 2.5} was observed during spring (73.6 μg·m{sup −3}) compared to winter (39.0 μg·m{sup −3}) with mean of 54.6 μg·m{sup −3}. Back trajectory air mass analysis together with temporal distribution of vanadium (V) showed that V could be the typical tracer of shipping emissions at Tuoji Island. Furthermore, the ratios of vanadium to nickel (V/Ni), vanadium to lead (V/Pb) and vanadium to zinc (V/Zn) also suggest shipping emissions at Tuoji Island. The annual average primary PM{sub 2.5} estimate of shipping emissions was 0.65 μg·m{sup −3} at Tuoji Island, accounting for 2.94% of the total primary PM{sub 2.5}, with a maximum of 3.16% in summer and a minimum of 2.39% in autumn. - Highlights: • Tracers of shipping emissions in coastal zone of northern China were identified. • Contributions of shipping emissions on primary PM{sub 2.5} were estimated. • Shipping emissions accounted for 2.94% of primary PM{sub 2.5} apart from fishing boats. • Impact of shipping emissions on coastal zone increased rapidly in recent years.

  5. Femtosecond envelope of the high-harmonic emission from ablation plasmas

    International Nuclear Information System (INIS)

    Haessler, S; Gobert, O; Hergott, J-F; Lepetit, F; Perdrix, M; Carré, B; Salières, P; Bom, L B Elouga; Ozaki, T

    2012-01-01

    We characterize the temporal profile of the high-order harmonic emission from ablation plasma plumes using cross-correlations with the infrared (IR) laser beam provided by two-photon harmonic+IR ionization of rare gas atoms. We study both non-resonant plasmas (lead, gold and chrome) and resonant plasmas (indium and tin), i.e. plasmas presenting in the singly charged ions a strong radiative transition coinciding with a harmonic order. The cross-correlation traces are found to be very similar for all harmonic orders and all plasma targets. The recovered harmonic pulse durations are very similar to the driving laser, with a tendency towards being shorter, demonstrating that the emission is a directly laser-driven process even in the case of resonant harmonics. This provides a valuable input for theories describing resonant-harmonic emission and opens the perspective of a very high flux tabletop XUV source for applications. (paper)

  6. Field emission from the surface of highly ordered pyrolytic graphite

    Energy Technology Data Exchange (ETDEWEB)

    Knápek, Alexandr, E-mail: knapek@isibrno.cz [Institute of Scientific Instruments of the ASCR, v.v.i., Královopolská 147, Brno (Czech Republic); Sobola, Dinara; Tománek, Pavel [Department of Physics, FEEC, Brno University of Technology, Technická 8, Brno (Czech Republic); Pokorná, Zuzana; Urbánek, Michal [Institute of Scientific Instruments of the ASCR, v.v.i., Královopolská 147, Brno (Czech Republic)

    2017-02-15

    Highlights: • HOPG shreds were created and analyzed in the UHV conditions. • Current-voltage measurements have been done to confirm electron tunneling, based on the Fowler-Nordheim theory. • Surface was characterized by other surface evaluation methods, in particular by: SNOM, SEM and AFM. - Abstract: This paper deals with the electrical characterization of highly ordered pyrolytic graphite (HOPG) surface based on field emission of electrons. The effect of field emission occurs only at disrupted surface, i.e. surface containing ripped and warped shreds of the uppermost layers of graphite. These deformations provide the necessary field gradients which are required for measuring tunneling current caused by field electron emission. Results of the field emission measurements are correlated with other surface characterization methods such as scanning near-field optical microscopy (SNOM) or atomic force microscopy.

  7. Field emission from the surface of highly ordered pyrolytic graphite

    International Nuclear Information System (INIS)

    Knápek, Alexandr; Sobola, Dinara; Tománek, Pavel; Pokorná, Zuzana; Urbánek, Michal

    2017-01-01

    Highlights: • HOPG shreds were created and analyzed in the UHV conditions. • Current-voltage measurements have been done to confirm electron tunneling, based on the Fowler-Nordheim theory. • Surface was characterized by other surface evaluation methods, in particular by: SNOM, SEM and AFM. - Abstract: This paper deals with the electrical characterization of highly ordered pyrolytic graphite (HOPG) surface based on field emission of electrons. The effect of field emission occurs only at disrupted surface, i.e. surface containing ripped and warped shreds of the uppermost layers of graphite. These deformations provide the necessary field gradients which are required for measuring tunneling current caused by field electron emission. Results of the field emission measurements are correlated with other surface characterization methods such as scanning near-field optical microscopy (SNOM) or atomic force microscopy.

  8. High-resolution ammonia emissions inventories in Fujian, China, 2009-2015

    Science.gov (United States)

    Wu, Shui-Ping; Zhang, Yin-Ju; Schwab, James J.; Li, Yang-Fan; Liu, Yuan-Long; Yuan, Chung-Shin

    2017-08-01

    A high-resolution NH3 emission inventory was developed based on the corrected emission factors and county-level activity data. To provide model-ready emission input, the NH3 emission inventory was gridded for the modeling domain at 1 × 1 km resolution using source-based spatial surrogates and a GIS system. The best estimate of total NH3 emission for the province was 228.02 kt in 2015 with a percentage uncertainty of ±16.3%. Four major contributors were farmland ecosystem, livestock wastes, humans and waste treatment, which contributed 39.4%, 43.1%, 4.9%, and 4.2% of the total emissions, respectively. The averaged NH3 emission density for the whole region was 1.88 t km-2 yr-1 and the higher values were found in coastal areas with higher dense populations. The seasonal patterns, with higher emissions in summer, were consistent with the patterns of temperature and planting practices. From 2009 to 2015, annual NH3 emissions increased from 218.49 kt to 228.02 kt. All of these changes are insignificant compared to the estimated overall uncertainties in the analysis, but indicative of changes in the source categories over this period. Between 2009 and 2015, the largest changes occurred in human emissions and waste treatment plants, which were consistent with the process of rapid urbanization. Meanwhile, the decrease of emissions from pigs was slightly higher than the increased emissions from broilers and the increased emissions from meat goats and beef cattle due to the combine effects of increasingly stringent environmental requirements for pig farms and shift away from pork consumption to beef, chicken and mutton. The validity of the estimates was further evaluated using uncertainty analysis, comparison with previous studies, and correlation analysis between emission density and observed ground ammonia. The inventories reflect the changes in economic progress and environmental protection and can provide scientific basis for the establishment of effective PM2.5 control

  9. Highly efficient white top-emitting organic light-emitting diodes with forward directed light emission

    Energy Technology Data Exchange (ETDEWEB)

    Freitag, Patricia; Reineke, Sebastian; Furno, Mauro; Luessem, Bjoern; Leo, Karl [Institut fuer Angewandte Photophysik, TU Dresden (Germany)

    2010-07-01

    The demand for highly efficient and energy saving illumination has increased considerably during the last decades. Organic light emitting diodes (OLEDs) are promising candidates for future lighting technologies. They offer high efficiency along with excellent color quality, allowing substantially lower power consumption than traditional illuminants. Recently, especially top-emitting devices have attracted high interest due to their compatibility with opaque substrates like metal sheets. In this contribution, we demonstrate top-emitting OLEDs with white emission spectra employing a multilayer hybrid cavity structure with two highly efficient phosphorescent emitter materials for orange-red (Ir(MDQ)2(acac)) and green (Ir(ppy)3) emission as well as the stable fluorescent blue emitter TBPe. To improve the OLED performance and modify the color quality, two different electron blocking layers and anode material combinations are tested. Compared to Lambertian emission, our devices show considerably enhanced forward emission, which is preferred for most lighting applications. Besides broadband emission and angle independent emission maxima, power efficiencies of 13.3 lm/W at 3 V and external quantum efficiencies of 5.3% are achieved. The emission shows excellent CIE coordinates of (0.420,0.407) at approx. 1000 cd/m{sup 2} and color rendering indices up to 77.

  10. Quasi-kinoform type multilayer zone plate with high diffraction efficiency for high-energy X-rays

    International Nuclear Information System (INIS)

    Tamura, S; Yasumoto, M; Kamijo, N; Uesugi, K; Takeuchi, A; Terada, Y; Suzuki, Y

    2009-01-01

    Fresnel zone plate (FZP) with high diffraction efficiency leads to high performance X-ray microscopy with the reduction of the radiation damage to biological specimens. In order to attain high diffraction efficiency in high energy X-ray region, we have developed multilevel-type (6-step) multilayer FZPs with the diameter of 70 micron. The efficiencies of two FZPs were evaluated at the BL20XU beamline of SPring-8. For one FZP, the peak efficiency for the 1st-order diffraction of 51% has been obtained at 70 keV. The efficiencies higher than 40% have been achieved in the wide energy range of 70-90 keV. That for the 2nd-order diffraction of 46% has been obtained at 37.5 keV.

  11. Source limitation of carbon gas emissions in high-elevation mountain streams and lakes

    Science.gov (United States)

    Crawford, John T.; Dornblaser, Mark M.; Stanley, Emily H.; Clow, David W.; Striegl, Robert G.

    2015-01-01

    Inland waters are an important component of the global carbon cycle through transport, storage, and direct emissions of CO2 and CH4 to the atmosphere. Despite predictions of high physical gas exchange rates due to turbulent flows and ubiquitous supersaturation of CO2—and perhaps also CH4—patterns of gas emissions are essentially undocumented for high mountain ecosystems. Much like other headwater networks around the globe, we found that high-elevation streams in Rocky Mountain National Park, USA, were supersaturated with CO2 during the growing season and were net sources to the atmosphere. CO2concentrations in lakes, on the other hand, tended to be less than atmospheric equilibrium during the open water season. CO2 and CH4 emissions from the aquatic conduit were relatively small compared to many parts of the globe. Irrespective of the physical template for high gas exchange (high k), we found evidence of CO2 source limitation to mountain streams during the growing season, which limits overall CO2emissions. Our results suggest a reduced importance of aquatic ecosystems for carbon cycling in high-elevation landscapes having limited soil development and high CO2 consumption via mineral weathering.

  12. CO{sub 2} and N{sub 2}O emissions in a soil chronosequence at a glacier retreat zone in Maritime Antarctica

    Energy Technology Data Exchange (ETDEWEB)

    Thomazini, A., E-mail: andre.thz@gmail.com [Department of Plant Production, Federal University of Espírito Santo, 29500-000 Alegre, Espírito Santo (Brazil); Mendonça, E.S., E-mail: eduardo.mendonca@ufes.br [Department of Plant Production, Federal University of Espírito Santo, 29500-000 Alegre, Espírito Santo (Brazil); Teixeira, D.B., E-mail: daniel.dbt@hotmail.com [FCAV/UNESP, Via de Acesso, Prof. Paulo Donato Castellane s/n, 14884-900 Jaboticabal, SP (Brazil); Almeida, I.C.C., E-mail: ivancarreiro@yahoo.com.br [Instituto Federal do Norte de Minas Gerais, Fazenda São Geraldo, s/n km. 06, 39480-000 Januária, Minas Gerais (Brazil); La Scala, N., E-mail: lascala@fcav.unesp.br [FCAV/UNESP, Via de Acesso, Prof. Paulo Donato Castellane s/n, 14884-900 Jaboticabal, SP (Brazil); Canellas, L.P., E-mail: lucianocanellas@gmail.com [UENF — Universidade Estadual do Norte Fluminense Darcy Ribeiro, Núcleo de Desenvolvimento de Insumos Biológicos para a Agricultura (NUDIBA), Av. Alberto Lamego, 2000, Campos dos Goytacazes 28013-602, Rio de Janeiro (Brazil); Spokas, K.A., E-mail: kurt.Spokas@ars.usda.gov [USDA-ARS, Soil and Water Management Unit, University of Minnesota — St. Paul, MN 55108 (United States); Milori, D.M.B.P., E-mail: debora.milori@embrapa.br [Embrapa Instrumentation Brazilian Agricultural Research Corporation, São Carlos, SP (Brazil); Turbay, C.V.G., E-mail: cturbay@gmail.com [Department of Geology, Federal University of Espírito Santo, 29500-000 Alegre, Espírito Santo (Brazil); and others

    2015-07-15

    Studies of C cycle alterations are extremely important to identify changes due to climate change, especially in the polar ecosystem. The objectives of this study were to (i) examine patterns of soil CO{sub 2}-C and N{sub 2}O-N emissions, and (ii) evaluate the quantity and quality of soil organic matter across a glacier retreat chronosequence in the Maritime Antarctica. Field measurements were carried out during January and February 2010 (summer season) along a retreating zone of the White Eagle Glacier, at King George Island, Maritime Antarctica. Soil samples (0–10 cm) were collected along a 500-m transect at regular intervals to determine changes in soil organic matter. Field CO{sub 2}-C emission measurements and soil temperature were carried out at regular intervals. In addition, greenhouse gas production potentials were assessed through 100 days laboratory incubations. Soils exposed for a longer time tended to have greater concentrations of soluble salts and possess sandier textures. Total organic C (3.59 g kg{sup −1}), total N (2.31 g kg{sup −1}) and labile C (1.83 g kg{sup −1}) tended to be lower near the glacier front compared with sites away from it, which is correlated with decreasing degree of humification of the soil organic matter with exposure time. Soil CO{sub 2}-C emissions tended to increase with distance from the glacier front. On average, the presence of vegetation increased CO{sub 2}-C emissions by 440%, or the equivalent of 0.633 g of CO{sub 2}-C m{sup −2} h{sup −1}. Results suggest that newly exposed landsurfaces undergo soil formation with increasing labile C input from vegetation, accompanied by increasing soil CO{sub 2}-C emissions. Despite the importance of exposure time on CO{sub 2}-C production and emissions, there was no similar trend in soil N{sub 2}O-N production potentials as a function of glacial retreat. For N{sub 2}O, instead, the maximum production occurred in sites with the first stages of vegetation growth

  13. Dose estimation for nuclear power plant 4 accident in Taiwan at Fukushima nuclear meltdown emission level

    International Nuclear Information System (INIS)

    Tang, Mei-Ling; Tsuang, Ben-Jei; Kuo, Pei-Hsuan

    2016-01-01

    An advanced Gaussian trajectory dispersion model is used to evaluate the evacuation zone due to a nuclear meltdown at the Nuclear Power Plant 4 (NPP4) in Taiwan, with the same emission level as that occurred at Fukushima nuclear meltdown (FNM) in 2011. Our study demonstrates that a FNM emission level would pollute 9% of the island's land area with annual effective dose ≥50 mSv using the meteorological data on 11 March 2011 in Taiwan. This high dose area is also called permanent evacuation zone (denoted as PEZ). The PEZ as well as the emergency-planning zone (EPZ) are found to be sensitive to meteorological conditions on the event. In a sunny day under the dominated NE wind conditions, the EPZ can be as far as 100 km with the first 7-day dose ≥20 mSv. Three hundred sixty-five daily events using the meteorological data from 11 March 2011 to 9 March 2012 are evaluated. It is found that the mean land area of Taiwan in becoming the PEZ is 11%. Especially, the probabilities of the northern counties/cities (Keelung, New Taipei, Taipei, Taoyuan, Hsinchu City, Hsinchu County and Ilan County) to be PEZs are high, ranging from 15% in Ilan County to 51% in Keelung City. Note that the total population of the above cities/counties is as high as 10 million people. Moreover, the western valleys of the Central Mountain Range are also found to be probable being PEZs, where all of the reservoirs in western Taiwan are located. For example, the probability can be as high as 3% in the far southern-most tip of Taiwan Island in Pingtung County. This shows that the entire populations in western Taiwan can be at risk due to the shortage of clean water sources under an event at FNM emission level, especially during the NE monsoon period. - Highlights: • An advanced Gaussian-type trajectory model to evaluate the evacuation zone at Nuclear Power Plant 4 in Taiwan. • Mean land area of Taiwan in becoming the permanent evacuation zone is 11%. • The probabilities of the northern

  14. Diesel Combustion and Emission Using High Boost and High Injection Pressure in a Single Cylinder Engine

    Science.gov (United States)

    Aoyagi, Yuzo; Kunishima, Eiji; Asaumi, Yasuo; Aihara, Yoshiaki; Odaka, Matsuo; Goto, Yuichi

    Heavy-duty diesel engines have adopted numerous technologies for clean emissions and low fuel consumption. Some are direct fuel injection combined with high injection pressure and adequate in-cylinder air motion, turbo-intercooler systems, and strong steel pistons. Using these technologies, diesel engines have achieved an extremely low CO2 emission as a prime mover. However, heavy-duty diesel engines with even lower NOx and PM emission levels are anticipated. This study achieved high-boost and lean diesel combustion using a single cylinder engine that provides good engine performance and clean exhaust emission. The experiment was done under conditions of intake air quantity up to five times that of a naturally aspirated (NA) engine and 200MPa injection pressure. The adopted pressure booster is an external supercharger that can control intake air temperature. In this engine, the maximum cylinder pressure was increased and new technologies were adopted, including a monotherm piston for endurance of Pmax =30MPa. Moreover, every engine part is newly designed. As the boost pressure increases, the rate of heat release resembles the injection rate and becomes sharper. The combustion and brake thermal efficiency are improved. This high boost and lean diesel combustion creates little smoke; ISCO and ISTHC without the ISNOx increase. It also yields good thermal efficiency.

  15. Assessment of high precision, high accuracy Inductively Coupled Plasma-Optical Emission Spectroscopy to obtain concentration uncertainties less than 0.2% with variable matrix concentrations

    International Nuclear Information System (INIS)

    Rabb, Savelas A.; Olesik, John W.

    2008-01-01

    The ability to obtain high precision, high accuracy measurements in samples with complex matrices using High Performance Inductively Coupled Plasma-Optical Emission Spectroscopy (HP-ICP-OES) was investigated. The Common Analyte Internal Standard (CAIS) procedure was incorporated into the High Performance Inductively Coupled Plasma-Optical Emission Spectroscopy method to correct for matrix-induced changes in emission intensity ratios. Matrix matching and standard addition approaches to minimize matrix-induced errors when using High Performance Inductively Coupled Plasma-Optical Emission Spectroscopy were also assessed. The High Performance Inductively Coupled Plasma-Optical Emission Spectroscopy method was tested with synthetic solutions in a variety of matrices, alloy standard reference materials and geological reference materials

  16. High temperature spectral emissivity measurement using integral blackbody method

    Science.gov (United States)

    Pan, Yijie; Dong, Wei; Lin, Hong; Yuan, Zundong; Bloembergen, Pieter

    2016-10-01

    Spectral emissivity is a critical material's thermos-physical property for heat design and radiation thermometry. A prototype instrument based upon an integral blackbody method was developed to measure material's spectral emissivity above 1000 °. The system was implemented with an optimized commercial variable-high-temperature blackbody, a high speed linear actuator, a linear pyrometer, and an in-house designed synchronization circuit. A sample was placed in a crucible at the bottom of the blackbody furnace, by which the sample and the tube formed a simulated blackbody which had an effective total emissivity greater than 0.985. During the measurement, the sample was pushed to the end opening of the tube by a graphite rod which was actuated through a pneumatic cylinder. A linear pyrometer was used to monitor the brightness temperature of the sample surface through the measurement. The corresponding opto-converted voltage signal was fed and recorded by a digital multi-meter. A physical model was proposed to numerically evaluate the temperature drop along the process. Tube was discretized as several isothermal cylindrical rings, and the temperature profile of the tube was measurement. View factors between sample and rings were calculated and updated along the whole pushing process. The actual surface temperature of the sample at the end opening was obtained. Taking advantages of the above measured voltage profile and the calculated true temperature, spectral emissivity under this temperature point was calculated.

  17. The importance of high vehicle power for passenger car emissions

    Science.gov (United States)

    Carslaw, David C.; Williams, Martin L.; Tate, James E.; Beevers, Sean D.

    2013-04-01

    In this paper we use a quantile regression technique to explore the emissions characteristics of petrol and diesel passenger cars to reveal the importance of high vehicle power on exhaust emissions. A large database of ≈67,000 passenger cars from vehicle emission remote sensing data was used from surveys from several campaigns around the UK. Most previous remote sensing studies have focused on presenting mean emission estimates by vehicle type over time. However, as shown in the current work, considerably more insight can be gained into vehicle emission characteristics if techniques are used that can describe and model the full distribution of vehicle emissions as a function of important explanatory variables. For post-2000 model year (Euro 3-5) diesel cars it is shown that there is a strong dependence of vehicle specific power for emissions of NOx that was absent in earlier models and is absent for other pollutants such as CO, hydrocarbons and 'smoke'. Furthermore, we also find a stronger dependence on vehicle specific power for older catalyst-equipped petrol vehicles (Euro 1/2) on emissions of NOx that is less important for other emissions such as CO and hydrocarbons. Moreover, it is shown that while the rated maximum power output of petrol cars has remained almost constant over the past 15-20 years, the power output from diesel cars has increased markedly by about 50%. These results suggest that changes to vehicle technology, driving conditions and driver behaviour have become more important determinants of passenger car NOx emissions in recent years and may help explain why urban ambient concentrations of NOx have not decreased as much as anticipated.

  18. Efficient light emitting devices based on phosphorescent partially doped emissive layers

    KAUST Repository

    Yang, Xiaohui; Jabbour, Ghassan E.

    2013-01-01

    We report efficient organic light emitting devices employing an ultrathin phosphor emissive layer. The electroluminescent spectra of these devices can be tuned by introducing a low-energy emitting phosphor layer into the emission zone. Devices

  19. Development of the methodology of exhaust emissions measurement under RDE (Real Driving Emissions) conditions for non-road mobile machinery (NRMM) vehicles

    Science.gov (United States)

    Merkisz, J.; Lijewski, P.; Fuc, P.; Siedlecki, M.; Ziolkowski, A.

    2016-09-01

    The paper analyzes the exhaust emissions from farm vehicles based on research performed under field conditions (RDE) according to the NTE procedure. This analysis has shown that it is hard to meet the NTE requirements under field conditions (engine operation in the NTE zone for at least 30 seconds). Due to a very high variability of the engine conditions, the share of a valid number of NTE windows in the field test is small throughout the entire test. For this reason, a modification of the measurement and exhaust emissions calculation methodology has been proposed for farm vehicles of the NRMM group. A test has been developed composed of the following phases: trip to the operation site (paved roads) and field operations (including u-turns and maneuvering). The range of the operation time share in individual test phases has been determined. A change in the method of calculating the real exhaust emissions has also been implemented in relation to the NTE procedure.

  20. Denitrifiers in the surface zone are primarily responsible for the nitrous oxide emission of dairy manure compost

    Energy Technology Data Exchange (ETDEWEB)

    Maeda, Koki, E-mail: k_maeda@affrc.go.jp [Dairy Research Division, National Agricultural Research Center for Hokkaido Region, National Agricultural and Food Research Organization, 1 Hitsujigaoka, Sapporo 062-8555 (Japan); Department of Environmental Chemistry and Engineering, Tokyo Institute of Technology, 4259 Nagatsuta, Midori-ku, Yokohama 226-8502 (Japan); Toyoda, Sakae [Department of Environmental Chemistry and Engineering, Tokyo Institute of Technology, 4259 Nagatsuta, Midori-ku, Yokohama 226-8502 (Japan); Hanajima, Dai [Dairy Research Division, National Agricultural Research Center for Hokkaido Region, National Agricultural and Food Research Organization, 1 Hitsujigaoka, Sapporo 062-8555 (Japan); Yoshida, Naohiro [Department of Environmental Chemistry and Engineering, Tokyo Institute of Technology, 4259 Nagatsuta, Midori-ku, Yokohama 226-8502 (Japan)

    2013-03-15

    Highlights: ► Nitrous oxide (N{sub 2}O) productions of each compost zones were compared. ► The pile surface emitted significant fluxes of N{sub 2}O. ► The isotopic signature of N{sub 2}O from surface and NO{sub 2}{sup −} amended core were different. ► The denitrifying gene abundance was significantly higher in pile surface than the pile core. -- Abstract: During the dairy manure composting process, significant nitrous oxide (N{sub 2}O) emissions occur just after the pile turnings. To understand the characteristics of this N{sub 2}O emission, samples were taken from the compost surface and core independently, and the N{sub 2}O production was monitored in laboratory incubation experiments. Equal amounts of surface and core samples were mixed to simulate the turning, and the {sup 15}N isotope ratios within the molecules of produced N{sub 2}O were analyzed by isotopomer analysis. The results showed that the surface samples emitted significant levels of N{sub 2}O, and these emissions were correlated with NO{sub x}{sup −}-N accumulation. Moreover, the surface samples and surface-core mixed samples incubated at 30 °C produced N{sub 2}O with a low site preference (SP) value (−0.9 to 7.0‰) that was close to bacteria denitrification (0‰), indicating that denitrifiers in the surface samples are responsible for this N{sub 2}O production. On the other hand, N{sub 2}O produced by NO{sub 2}{sup −}-amended core samples and surface samples incubated at 60 °C showed unrecognized isotopic signatures (SP = 11.4–20.3‰). From these results, it was revealed that the N{sub 2}O production occurring just after the turnings was mainly derived from bacterial denitrification (including nitrifier denitrification) of NO{sub x}{sup −}-N under mesophilic conditions, and surface denitrifying bacteria appeared to be the main contributor to this process.

  1. High resolution krypton M/sub 4,5/ x-ray emission spectra

    International Nuclear Information System (INIS)

    Perera, R.C.C.; Hettrick, M.C.; Lindle, D.W.

    1987-10-01

    High resolution M/sub 4,5/ (3d → 4p) x-ray emission spectra from a krypton plasma were measured using a recently developed grazing-incidence reflection-grating monochromator/spectrometer with very high flux rates at extreme ultraviolet and soft x-ray wave lengths. The nominal resolving power of the instrument, E/ΔE, is about 300 in this energy range (∼80 eV). Three dipole-allowed 3d → 4p emission lines were observed at 80.98 eV, 80.35 eV and 79.73 eV. A broad peak at about 82.3 eV is tentatively assigned to transitions resulting from Kr 2+ , and effects of excitation energy on M/sub 4,5/ x-ray emission were observed. 9 refs., 3 figs., 1 tab

  2. Greenhouse gas emissions and energy efficiencies for soybeans and maize cultivated in different agronomic zones: A case study of Argentina.

    Science.gov (United States)

    Arrieta, E M; Cuchietti, A; Cabrol, D; González, A D

    2018-06-01

    Of all human activities, agriculture has one of the highest environmental impacts, particularly related to Greenhouse Gas (GHG) emissions, energy use and land use change. Soybean and maize are two of the most commercialized agricultural commodities worldwide. Argentina contributes significantly to this trade, being the third major producer of soybeans, the first exporter of soymeal and soybean oil, and the third exporter of maize. Despite the economic importance of these crops and the products derived, there are very few studies regarding GHG emissions, energy use and efficiencies associated to Argentinean soybean and maize production. Therefore, the aim of this work is to determine the carbon and energy footprint, as well as the carbon and energy efficiencies, of soybeans and maize produced in Argentina, by analyzing 18 agronomic zones covering an agricultural area of 1.53millionkm 2 . Our results show that, for both crops, the GHG and energy efficiencies at the Pampean region were significantly higher than those at the extra-Pampean region. The national average for production of soybeans in Argentina results in 6.06ton/ton CO 2 -eq emitted to the atmosphere, while 0.887ton of soybean were produced per GJ of energy used; and for maize 5.01ton/ton CO 2 -eq emitted to the atmosphere and 0.740ton of maize were produced per each GJ of energy used. We found that the large differences on yields, GHGs and energy efficiencies between agronomic regions for soybean and maize crop production are mainly driven by climate, particularly mean annual precipitation. This study contributes for the first time to understand the carbon and energy footprint of soybean and maize production throughout several agronomic zones in Argentina. The significant differences found in the productive efficiencies questions on the environmental viability of expanding the agricultural frontier to less suitable lands for crop production. Copyright © 2017 Elsevier B.V. All rights reserved.

  3. Dynamics of the solar transition zone

    Science.gov (United States)

    Bruner, E. C., Jr.

    1978-01-01

    Time-resolved profiles of the 1548-A C IV line arising from the solar transition region are analyzed in order to determine whether the 300-sec oscillations characteristic of the photosphere and chromosphere penetrate into the transition zone and to measure the rms amplitude of transition-zone disturbances as well as their dependence on solar activity. The rms velocity amplitude is used to set limits on the mechanical energy flux available for solar heating. A power-spectrum analysis indicates that acoustic waves appear to have been detected in the transition zone, that at least one case of a strong 200- to 300-sec oscillation was observed, but that strong periodicities are not found on the average in either the intensity or the velocity field. It is suggested that the rms velocity that may be attributed to directly observable wave motion is between 3 and 7 km/s, depending on whether the individual emission elements seen in rocket spectra are coherent or independent in phase.

  4. Compositional Approach to Designing Fcc High-Entropy Alloys that Have an Enlarged Equiaxed Zone

    Directory of Open Access Journals (Sweden)

    Minju Kang

    2018-01-01

    Full Text Available A compositional approach to designing alloys that have an enlarged equiaxed zone is suggested in this study. The partitioning of elements during the solidification of CoCrFeMnNi high-entropy alloy (HEA was confirmed through a directional solidification quenching experiment. Several HEAs were designed to maximize the effects of constitutional and thermal undercooling by considering factors including solute enrichment at the columnar front and the melting temperatures and thermal conductivities of the individual elements. The newly designed HEAs were shown to have successfully enlarged equiaxed zones, and improved anisotropic properties.

  5. Measurement of high-temperature spectral emissivity using integral blackbody approach

    Science.gov (United States)

    Pan, Yijie; Dong, Wei; Lin, Hong; Yuan, Zundong; Bloembergen, Pieter

    2016-11-01

    Spectral emissivity is one of the most critical thermophysical properties of a material for heat design and analysis. Especially in the traditional radiation thermometry, normal spectral emissivity is very important. We developed a prototype instrument based upon an integral blackbody method to measure material's spectral emissivity at elevated temperatures. An optimized commercial variable-high-temperature blackbody, a high speed linear actuator, a linear pyrometer, and an in-house designed synchronization circuit was used to implemented the system. A sample was placed in a crucible at the bottom of the blackbody furnace, by which the sample and the tube formed a simulated reference blackbody which had an effective total emissivity greater than 0.985. During the measurement, a pneumatic cylinder pushed a graphite rode and then the sample crucible to the cold opening within hundreds of microseconds. The linear pyrometer was used to monitor the brightness temperature of the sample surface, and the corresponding opto-converted voltage was fed and recorded by a digital multimeter. To evaluate the temperature drop of the sample along the pushing process, a physical model was proposed. The tube was discretized into several isothermal cylindrical rings, and the temperature of each ring was measurement. View factors between sample and rings were utilized. Then, the actual surface temperature of the sample at the end opening was obtained. Taking advantages of the above measured voltage signal and the calculated actual temperature, normal spectral emissivity under the that temperature point was obtained. Graphite sample at 1300°C was measured to prove the validity of the method.

  6. Experimental and numerical analysis for high intensity swirl based ultra-low emission flameless combustor operating with liquid fuels

    KAUST Repository

    Vanteru, Mahendra Reddy; Katoch, Amit; Roberts, William L.; Kumar, Sudarshan

    2014-01-01

    Flameless combustion offers many advantages over conventional combustion, particularly uniform temperature distribution and lower emissions. In this paper, a new strategy is proposed and adopted to scale up a burner operating in flameless combustion mode from a heat release density of 5.4-21 MW/m(3) (thermal input 21.5-84.7 kW) with kerosene fuel. A swirl flow based configuration was adopted for air injection and pressure swirl type nozzle with an SMD 35-37 lm was used to inject the fuel. Initially, flameless combustion was stabilized for a thermal input of 21.5 kW ((Q) over dot '''= 5.37 MW/m(3)). Attempts were made to scale this combustor to higher intensities i.e. 10.2, 16.3 and 21.1 MW/m(3). However, an increase in fuel flow rate led to incomplete combustion and accumulation of unburned fuel in the combustor. Two major difficulties were identified as possible reasons for unsustainable flameless combustion at the higher intensities. (i) A constant spray cone angle and SMD increases the droplet number density. (ii) Reactants dilution ratio (R-dil) decreased with increased thermal input. To solve these issues, a modified combustor configuration, aided by numerical computations was adopted, providing a chamfer near the outlet to increase the R-dil. Detailed experimental investigations showed that flameless combustion mode was achieved at high intensities with an evenly distributed reaction zone and temperature in the combustor at all heat intensities. The emissions of CO, NOx and HC for all heat intensities (Phi = 1-0.6) varied between 11-41, 6-19 and 0-9 ppm, respectively. These emissions are well within the range of emissions from other flameless combustion systems reported in the literature. The acoustic emission levels were also observed to be reduced by 8-9 dB at all conditions. (C) 2014 The Combustion Institute. Published by Elsevier Inc. All rights reserved.

  7. Experimental and numerical analysis for high intensity swirl based ultra-low emission flameless combustor operating with liquid fuels

    KAUST Repository

    Vanteru, Mahendra Reddy

    2014-06-21

    Flameless combustion offers many advantages over conventional combustion, particularly uniform temperature distribution and lower emissions. In this paper, a new strategy is proposed and adopted to scale up a burner operating in flameless combustion mode from a heat release density of 5.4-21 MW/m(3) (thermal input 21.5-84.7 kW) with kerosene fuel. A swirl flow based configuration was adopted for air injection and pressure swirl type nozzle with an SMD 35-37 lm was used to inject the fuel. Initially, flameless combustion was stabilized for a thermal input of 21.5 kW ((Q) over dot \\'\\'\\'= 5.37 MW/m(3)). Attempts were made to scale this combustor to higher intensities i.e. 10.2, 16.3 and 21.1 MW/m(3). However, an increase in fuel flow rate led to incomplete combustion and accumulation of unburned fuel in the combustor. Two major difficulties were identified as possible reasons for unsustainable flameless combustion at the higher intensities. (i) A constant spray cone angle and SMD increases the droplet number density. (ii) Reactants dilution ratio (R-dil) decreased with increased thermal input. To solve these issues, a modified combustor configuration, aided by numerical computations was adopted, providing a chamfer near the outlet to increase the R-dil. Detailed experimental investigations showed that flameless combustion mode was achieved at high intensities with an evenly distributed reaction zone and temperature in the combustor at all heat intensities. The emissions of CO, NOx and HC for all heat intensities (Phi = 1-0.6) varied between 11-41, 6-19 and 0-9 ppm, respectively. These emissions are well within the range of emissions from other flameless combustion systems reported in the literature. The acoustic emission levels were also observed to be reduced by 8-9 dB at all conditions. (C) 2014 The Combustion Institute. Published by Elsevier Inc. All rights reserved.

  8. CO2 emission inventories for Chinese cities in highly urbanized areas compared with European cities

    International Nuclear Information System (INIS)

    Yu Wei; Pagani, Roberto; Huang Lei

    2012-01-01

    The international literature has paid significant attention to presenting China as the largest emitter of greenhouse gases (GHGs) in the world, despite having much lower per-capita emissions than the global average. In fact, the imbalance of economic development leads to diversity in GHG emissions profiles in different areas of China. This paper employs a common methodology, consistent with the Sustainable Energy Action Plan (SEAP) approved by the Covenant of Mayors (CoM), to estimate CO 2 emissions of four Chinese cities in highly urbanized areas from 2004 to 2010. The results show that the CO 2 emissions of all four cities are still rising and that secondary industries emit the most CO 2 in these cities. By comparing these data with the inventory results of two European cities, this paper further reveals that Chinese cities in highly urbanized areas contribute much higher per-capita emissions than their European competitors. Furthermore, the per-capita CO 2 emissions of the residential sector and private transport in these Chinese cities are growing rapidly, some of them approaching the levels of European cities. According to these findings, several policy suggestions considering regional disparities are provided that aim to reduce the CO 2 emissions of highly urbanized areas in China. - Highlights: ► An exemplary study of GHG emission inventory for Chinese cities. ► Estimate CO 2 emissions of Chinese city in highly urbanized areas from 2004 to 2010. ► The studied Chinese cities contribute higher per-capita emissions than European’s. ► Emissions of residential sector and private transport in China are growing rapidly. ► Several policy suggestions considering regional disparities are provided.

  9. Time dependent photon and neutrino emission from Mkr 421 in the context of the one-zone leptohadronic model

    Directory of Open Access Journals (Sweden)

    Mastichiadis Apostolos

    2013-12-01

    Full Text Available We apply a recently developed time-dependent one-zone leptohadronic model to study the emission of the blazar Mrk 421. Both processes involving proton-photon interactions, i.e. photopair (Bethe-Heitler and photopion, have been modeled in great detail using the results of Monte Carlo simulations, like the SOPHIA event generator, in a self-consistent scheme that couples energy losses and secondary injection. We find that TeV gamma-rays can be attributed to synchrotron radiation either from relativistic protons or, alternatively, from secondary leptons produced via photohadronic processes. We also study the variability patterns that each scenario predicts and we find that while the former is more energetically favored, it is the latter that produces, in a more natural way, the usual quadratic behavior between X-rays and TeV gamma-rays. We also use the obtained SEDs to calculate in detail the expected neutron and neutrino fluxes that each model predicts.

  10. A novel approach to obtain highly intense self-activated photoluminescence emissions in hydroxyapatite nanoparticles

    Energy Technology Data Exchange (ETDEWEB)

    Machado, Thales R. [CDMF-UFSCar, Universidade Federal de São Carlos, P.O. Box 676, 13565-905 São Carlos, São Paulo (Brazil); QIO-UJI, Universitat Jaume I, 12071 Castellón (Spain); Sczancoski, Júlio C. [CDMF-UFSCar, Universidade Federal de São Carlos, P.O. Box 676, 13565-905 São Carlos, São Paulo (Brazil); Beltrán-Mir, Héctor [QIO-UJI, Universitat Jaume I, 12071 Castellón (Spain); Nogueira, Içamira C. [PPGEM-IFMA, Instituto Federal de Educação, Ciência e Tecnologia do Maranhão, 65030-005 São Luís, MA (Brazil); Li, Máximo S. [IFSC-USP, Universidade de São Paulo, P.O. Box 369, 13560-970 São Carlos, SP (Brazil); Andrés, Juan [QFA-UJI, Universitat Jaume I, 12071 Castellón (Spain); Cordoncillo, Eloisa [QIO-UJI, Universitat Jaume I, 12071 Castellón (Spain); Longo, Elson, E-mail: elson.liec@gmail.com [CDMF-UFSCar, Universidade Federal de São Carlos, P.O. Box 676, 13565-905 São Carlos, São Paulo (Brazil)

    2017-05-15

    Defect-related photoluminescence (PL) in materials have attracted interest for applications including near ultraviolet (NUV) excitable light-emitting diodes and in biomedical field. In this paper, hydroxyapatite [Ca{sub 10}(PO{sub 4}){sub 6}(OH){sub 2}] nanorods with intense PL bands (bluish- and yellowish-white emissions) were obtained when excited under NUV radiation at room temperature. These nanoparticles were synthesized via chemical precipitation at 90 °C followed by distinct heat treatments temperatures (200–800 °C). Intense and broad emission profiles were achieved at 350 °C (380–750 nm) and 400 °C (380–800 nm). UV–Vis spectroscopy revealed band gap energies (5.58–5.78 eV) higher than the excitation energies (~3.54 and ~2.98 eV at 350 and 415 nm, respectively), confirming the contribution of defect energy levels within the forbidden zone for PL emissions. The structural features were characterized by X-ray diffraction, Rietveld refinement, thermogravimetric analysis, and Fourier transform infrared spectroscopy. By means of these techniques, the relation between structural order-disorder induced by defects, chemical reactions at both lattice and surface of the materials as well as the PL, without activator centers, was discussed in details. - Graphical abstract: The self-activated photoluminescence emissions of chemically precipitated hydroxyapatite nanorods were improved by different heat treatment temperatures. - Highlights: • HA nanorods were synthesized with improved self-activated PL at room temperature. • PL profile and intensity dependents on the temperature of posterior heat treatments. • Bluish- and yellowish-white emissions under NUV excitation (350 and 415 nm). • Broad and intense profiles achieved at 350 °C (380–750 nm) and 400 °C (380–800 nm). • PL from the e′–h{sup •} recombination between defect energy levels within the band gap.

  11. Combustion Homogeneity and Emission Analysis during the Transition from CI to HCCI for FACE I Gasoline

    KAUST Repository

    Vedharaj, S.

    2017-10-10

    Low temperature combustion concepts are studied recently to simultaneously reduce NOX and soot emissions. Optical studies are performed to study gasoline PPC in CI engines to investigate in-cylinder combustion and stratification. It is imperative to perform emission measurements and interpret the results with combustion images. In this work, we attempt to investigate this during the transition from CI to HCCI mode for FACE I gasoline (RON = 70) and its surrogate, PRF70. The experiments are performed in a single cylinder optical engine that runs at a speed of 1200 rpm. Considering the safety of engine, testing was done at lower IMEP (3 bar) and combustion is visualized using a high-speed camera through a window in the bottom of the bowl. From the engine experiments, it is clear that intake air temperature requirement is different at various combustion modes to maintain the same combustion phasing. While a fixed intake air temperature is required at HCCI condition, it varies at PPC and CI conditions between FACE I gasoline and PRF70. Three zones are identified 1) SOI = -180 to -80 CAD (aTDC) is HCCI zone 2) SOI = -40 to -20 CAD (aTDC) is PPC zone 3) After SOI = -15 CAD (aTDC) is CI zone. Combustion duration, ignition delay, start of combustion and CA90 (crank angle at which 90% of fuel burnt) are comparable between FACE I gasoline and PRF70. The combustion images show a prominent soot flame at CI condition, while only blue coloured premixed flames are visible at PPC condition for both the fuels. PRF70 seems to have a pronounced premixed effect when compared to FACE I gasoline at early injections, showing a decreased level of stratification. NOX emission and soot concentration decreases from CI condition and attains a constant zero value at HCCI condition for both FACE I gasoline and PRF70. CO and CO2 emissions matches between FACE I gasoline and PRF70 at PPC and CI condition, while CO emission is lower for PRF70 at HCCI condition.

  12. Combustion Homogeneity and Emission Analysis during the Transition from CI to HCCI for FACE I Gasoline

    KAUST Repository

    Vedharaj, S.; Vallinayagam, R; An, Yanzhao; Izadi Najafabadi, Mohammad; Somers, Bart; Chang, Junseok; Johansson, Bengt

    2017-01-01

    Low temperature combustion concepts are studied recently to simultaneously reduce NOX and soot emissions. Optical studies are performed to study gasoline PPC in CI engines to investigate in-cylinder combustion and stratification. It is imperative to perform emission measurements and interpret the results with combustion images. In this work, we attempt to investigate this during the transition from CI to HCCI mode for FACE I gasoline (RON = 70) and its surrogate, PRF70. The experiments are performed in a single cylinder optical engine that runs at a speed of 1200 rpm. Considering the safety of engine, testing was done at lower IMEP (3 bar) and combustion is visualized using a high-speed camera through a window in the bottom of the bowl. From the engine experiments, it is clear that intake air temperature requirement is different at various combustion modes to maintain the same combustion phasing. While a fixed intake air temperature is required at HCCI condition, it varies at PPC and CI conditions between FACE I gasoline and PRF70. Three zones are identified 1) SOI = -180 to -80 CAD (aTDC) is HCCI zone 2) SOI = -40 to -20 CAD (aTDC) is PPC zone 3) After SOI = -15 CAD (aTDC) is CI zone. Combustion duration, ignition delay, start of combustion and CA90 (crank angle at which 90% of fuel burnt) are comparable between FACE I gasoline and PRF70. The combustion images show a prominent soot flame at CI condition, while only blue coloured premixed flames are visible at PPC condition for both the fuels. PRF70 seems to have a pronounced premixed effect when compared to FACE I gasoline at early injections, showing a decreased level of stratification. NOX emission and soot concentration decreases from CI condition and attains a constant zero value at HCCI condition for both FACE I gasoline and PRF70. CO and CO2 emissions matches between FACE I gasoline and PRF70 at PPC and CI condition, while CO emission is lower for PRF70 at HCCI condition.

  13. OUTFLOW AND HOT DUST EMISSION IN HIGH-REDSHIFT QUASARS

    International Nuclear Information System (INIS)

    Wang, Huiyuan; Xing, Feijun; Wang, Tinggui; Zhou, Hongyan; Zhang, Kai; Zhang, Shaohua

    2013-01-01

    Correlations of hot dust emission with outflow properties are investigated, based on a large z ∼ 2 non-broad absorption line quasar sample built from the Wide-field Infrared Survey and the Sloan Digital Sky Survey data releases. We use the near-infrared slope and the infrared to UV luminosity ratio to indicate the hot dust emission relative to the emission from the accretion disk. In our luminous quasars, these hot dust emission indicators are almost independent of the fundamental parameters, such as luminosity, Eddington ratio and black hole mass, but moderately dependent on the blueshift and asymmetry index (BAI) and FWHM of C IV lines. Interestingly, the latter two correlations dramatically strengthen with increasing Eddington ratio. We suggest that, in high Eddington ratio quasars, C IV regions are dominated by outflows so the BAI and FWHM (C IV) can reliably reflect the general properties and velocity of outflows, respectively. In low Eddington ratio quasars, on the other hand, C IV lines are primarily emitted by virialized gas so the BAI and FWHM (C IV) become less sensitive to outflows. Therefore, the correlations for the highest Eddington ratio quasars are more likely to represent the true dependence of hot dust emission on outflows and the correlations for the entire sample are significantly diluted by the low Eddington ratio quasars. Our results show that an outflow with a large BAI or velocity can double the hot dust emission on average. We suggest that outflows either contain hot dust in themselves or interact with the dusty interstellar medium or torus

  14. Search for emission of ultra high energy radiation from active galactic nuclei

    International Nuclear Information System (INIS)

    1993-01-01

    A search for emission of ultra-high energy gamma radiation from 13 active galactic nuclei that were detected by EGRET, using the CYGNUS extensive air-shower array, is described. The data set has been searched for continuous emission, emission on the time scale of one week, and for on the time scale of out day. No evidence for emission from any of the AGN on any of the time scales examined was found. The 90% C.L. upper limit to the continuous flux from Mrk 421 above 50 TeV is 7.5 x 10 -14 cm -2 s -1

  15. Canadian critical environmental zones: Concepts, goals and resources

    International Nuclear Information System (INIS)

    Meredith, T.C.; Moore, C.; Gartner, L.; Smith, W.

    1994-02-01

    Critical environmental zones are those ecosystems that are so degraded that the health or well-being of human inhabitants is threatened. A conceptual framework is presented for considering criticality and a rationale for a Canadian research project on critical zones. A model of pathways to criticality is outlined and some examples of environmental degradation in Canada are presented, including acid rain and greenhouse gas emissions. Societal response to, and public perception of, critical environmental zones is described. Media, format, and target audiences for output from a Canadian project are considered and some central scientific and policy questions are identified under such categories as environmental stresses, buffering capacity, indicators, human driving forces, and societal responses. An inventory of pertinent international and national activities is included. 53 refs., 8 figs., 3 tabs

  16. Effects of emission reductions from the smelters in Sudbury on recovery of lakes within the metal deposition zone

    Energy Technology Data Exchange (ETDEWEB)

    Keller, W.; Heneberry, J.; Clark, M.; Malette, M.; Gunn, J. [Laurentian Univ., Sudbury, ON (Canada) Dept. of Biology

    1999-07-01

    Recent trends are examined in the chemistry of Sudbury lakes for evidence of further chemical recovery, as well as some of the biological characteristics of recovering Sudbury lakes. Preliminary results are provided from studies investigating physical, chemical and biological factors that may influence the lake recovery process with a focus on the lakes close to Sudbury that were historically the most severely affected. Smelter emission reductions in the Sudbury area have led to substantial changes in the water quality of area lakes, and decreases in acidity, sulfate, and copper and nickel concentrations followed the substantial decreases in emissions during the 1970s and similar trends are continuing after the implementation of large additional smelter emission reductions in the 1990s. Some of the most highly affected lakes close to the Sudbury smelters have showed very dramatic reductions in acidity and metal concentrations during the 1990s. Evaluation of the direct effects of the recent emissions reductions is confounded by the potential continuing effects of previous emission reductions and the effects of weather variations on chemistry time trends in Sudbury lakes. Continued monitoring of Sudbury lakes is essential to evaluate the ultimate effect of emission reduction programs, to develop an understanding of the recovery process, and to determine the need for any additional emission reduction requirements. 38 refs., 7 figs.

  17. High-Performance Field Emission from a Carbonized Cork.

    Science.gov (United States)

    Lee, Jeong Seok; Lee, Hak Jun; Yoo, Jae Man; Kim, Taewoo; Kim, Yong Hyup

    2017-12-20

    To broaden the range of application of electron beams, low-power field emitters are needed that are miniature and light. Here, we introduce carbonized cork as a material for field emitters. The light natural cork becomes a graphitic honeycomb upon carbonization, with the honeycomb cell walls 100-200 nm thick and the aspect ratio larger than 100, providing an ideal structure for the field electron emission. Compared to nanocarbon field emitters, the cork emitter produces a high current density and long-term stability with a low turn-on field. The nature of the cork material makes it quite simple to fabricate the emitter. Furthermore, any desired shape of the emitter tailored for the final application can easily be prepared for point, line, or planar emission.

  18. [Development of biogenic VOC emissions inventory with high temporal and spatial resolution].

    Science.gov (United States)

    Hu, Y; Zhang, Y; Xie, S; Zeng, L

    2001-11-01

    A new method was developed to estimate biogenic VOC emissions with high temporal and spatial resolution by use of Mesoscale Meteorology Modeling System Version5 (MM5). In this method, the isoprene and monoterpene standard emission factors for some types of tree in China were given and the standard VOC emission factors and seasonally average densities of leaf biomass for all types of vegetation were determined. A biogenic VOC emissions inventory in South China was established which could meet the requirement of regional air quality modeling. Total biogenic VOC emissions in a typical summer day were estimated to be 1.12 x 10(4) metric tons in an area of 729 km x 729 km of South China. The results showed the temporal and spatial distributions of biogenic VOC emission rates in this area. The results also showed that the geographical distribution of biogenic VOC emission rates depended on vegetation types and their distributions and the diurnal variation mainly depended on the solar radiation and temperature. The uncertainties of estimating biogenic VOC emissions were also discussed.

  19. Exploring the origin of broad-band emissions of Mrk 501 with a two-zone model

    Science.gov (United States)

    Lei, Maichang; Yang, Chuyuan; Wang, Jiancheng; Yang, Xiaolin

    2018-04-01

    We propose a two-zone synchrotron self-Compton (SSC) model, including an inner gamma-ray emitting region with spherical shape and a conical radio emitting region located at the extended jet, to alleviate the long-standing "bulk Lorentz factor crisis" in blazars. In this model, the spectral energy distributions (SEDs) of blazars are produced by considering the gamma-ray emitting region inverse Compton scattering of both the synchrotron photons itself and the ambient photons from the radio emitting region. Applying the model to Mrk 501, we obtain that the radio emitting region has a comoving length of ˜0.15 pc and is located at sub-parsec scale from the central engine by modeling the radio data; the flux of the Compton scattering of the ambient photons is so low that it can be neglected safely. The characteristic hard gamma-ray spectrum can be explained by the superposition of two SSC processes, and the model can approximately explain the very high energy (VHE) data. The insights into the spectral shape and the inter-band correlations under the flaring state will provide us with a diagnostic for the bulk Lorentz factor of radio emitting region, where the low and upper limits of 8 and 15 are preferred, and for the two-zone SSC model itself. In addition, our two-zone SSC model shows that the gamma-ray emitting region creates flare on the timescale of merely a few hours, and the long time outbursts more likely originate from the extended radio emitting region.

  20. Greenhouse gas emission reduction by means of fuel switching in electricity generation: Addressing the potentials

    International Nuclear Information System (INIS)

    Delarue, Erik; D'haeseleer, William

    2008-01-01

    Many countries committed themselves in the Kyoto protocol to reduce greenhouse gas (GHG) emissions. Some of these targeted emission reductions could result from a switch from coal-fired to gas-fired electricity generation. The focus in this work lies on Western Europe, with the presence of the European Union Emission Trading Scheme (EU ETS). For the switching to occur, several conditions have to be fulfilled. First, an economical incentive must be present, i.e. a sufficiently high European Union Allowance (EUA) price together with a sufficiently low natural gas price. Second, the physical potential for switching must exist, i.e. at a given load, there must remain enough power plants not running to make switching possible. This paper investigates what possibilities exist for switching coal-fired plants for gas-fired plants, dependent on the load level (the latter condition above). A fixed allowance cost and a variable natural gas price are assumed. The method to address GHG emission reduction potentials is first illustrated in a methodological case. Next, the GHG emission reduction potentials are addressed for several Western European countries together with a relative positioning of their electricity generation. GHG emission reduction potentials are also compared with simulation results. GHG emission reduction potentials tend to be significant. The Netherlands have a very widespread switching zone, so GHG emission reduction is practically independent of electricity generation. Other counties, like Germany, Spain and Italy could reduce GHG emissions significantly by switching. With an allowance cost following the switch level of a 50% efficient gas-fired plant and a 40% efficient coal-fired plant in the summer season (like in 2005), the global GHG emission reduction (in the electricity generating sector) for the eight modeled zones could amount to 19%

  1. Emission analysis of the best available wood-fired central heating boilers on the market

    International Nuclear Information System (INIS)

    Axell, M.; Gustavsson, Lennart; Persson, Henrik; Leckner, B.

    1998-01-01

    The purpose of the present project is to study the emissions from some of the best available wood-fired central heating boilers on the market. The aim is to identify the critical factors which determine the emission levels by means of emission measurements as well as temperature measurements in the combustion chamber. Four boilers with different design characteristics have been included in the project. All boilers use reversed combustion and fan-assisted combustion air supply, and have shown low tar emissions in earlier environmental tests. Boiler A is a boiler with a rather large mass of ceramics in the grate and in the burn-out zone, and a large volume of water. Boiler B has a smaller mass in the cast-iron grate and in the burn-out zone and a small water volume. Boiler C is a boiler with tertiary air and an incorporated accumulator tank. Boiler D has a zirconia-cell probe for continuous control of the air-excess ratio. The measurements have been made with the boilers in accumulator operation, i.e. at maximum heat output, since they are intended for this type of operation. Tests have, in addition to normal operating conditions, been made with high fuel moisture contents, high draught and a low boiler temperature at the start of the test. Measurements have been made of excess-air ratios, contents of CO, total hydrocarbons (THC), NO x and a number of volatile organic compounds (VOC) in the flue gases as well as of combustion temperatures below the grate

  2. Tunneling emission of electrons from semiconductors' valence bands in high electric fields

    International Nuclear Information System (INIS)

    Kalganov, V. D.; Mileshkina, N. V.; Ostroumova, E. V.

    2006-01-01

    Tunneling emission currents of electrons from semiconductors to vacuum (needle-shaped GaAs photodetectors) and to a metal (silicon metal-insulator-semiconductor diodes with a tunneling-transparent insulator layer) are studied in high and ultrahigh electric fields. It is shown that, in semiconductors with the n-type conductivity, the major contribution to the emission current is made by the tunneling emission of electrons from the valence band of the semiconductor, rather than from the conduction band

  3. Time and position resolution of high granularity, high counting rate MRPC for the inner zone of the CBM-TOF wall

    CERN Document Server

    Petriş, M.

    2016-09-13

    Multi-gap RPC prototypes with readout on a multi-strip electrode were developed for the small polar angle region of the CBM-TOF subdetector, the most demanding zone in terms of granularity and counting rate. The prototypes are based on low resistivity ($\\sim$10$^{10}$ $\\Omega$cm) glass electrodes for performing in high counting rate environment. The strip width/pitch size was chosen such to fulfill the impedance matching with the front-end electronics and the granularity requirements of the innermost zone of the CBM-TOF wall. The in-beam tests using secondary particles produced in heavy ion collisions on a Pb target at SIS18 - GSI Darmstadt and SPS - CERN were focused on the performance of the prototype in conditions similar to the ones expected at SIS100/FAIR. An efficiency larger than 98\\% and a system time resolution in the order of 70~-~80~ps were obtained in high counting rate and high multiplicity environment.

  4. Impacts and Policy Implications of Metals Effluent Discharge into Rivers within Industrial Zones: A Sub-Saharan Perspective from Ethiopia

    Science.gov (United States)

    Zinabu, E.; Kelderman, P.; van der Kwast, J.; Irvine, K.

    2018-04-01

    Kombolcha, a city in Ethiopia, exemplifies the challenges and problems of the sub-Saharan countries where industrialization is growing fast but monitoring resources are poor and information on pollution unknown. This study monitored metals Cr, Cu, Zn, and Pb concentrations in five factories' effluents, and in the effluent mixing zones of two rivers receiving discharges during the rainy seasons of 2013 and 2014. The results indicate that median concentrations of Cr in the tannery effluents and Zn in the steel processing effluents were as high as 26,600 and 155,750 µg/L, respectively, much exceeding both the USEPA and Ethiopian emission guidelines. Cu concentrations were low in all effluents. Pb concentrations were high in the tannery effluent, but did not exceed emission guidelines. As expected, no metal emission guidelines were exceeded for the brewery, textile and meat processing effluents. Median Cr and Zn concentrations in the Leyole river in the effluent mixing zones downstream of the tannery and steel processing plant increased by factors of 52 (2660 compared with 51 µg Cr/L) and 5 (520 compared with 110 µg Zn/L), respectively, compared with stations further upstream. This poses substantial ecological risks downstream. Comparison with emission guidelines indicates poor environmental management by industries and regulating institutions. Despite appropriate legislation, no clear measures have yet been taken to control industrial discharges, with apparent mismatch between environmental enforcement and investment policies. Effluent management, treatment technologies and operational capacity of environmental institutions were identified as key improvement areas to adopt progressive sustainable development.

  5. [The study of electroplex emission based on PVK/BCP].

    Science.gov (United States)

    Teng, Feng; Wang, Yuan-Min; Xu, Zheng; Wang, Yong-Sheng

    2005-05-01

    Electroplex emission based on poly(N-vinylcarbazole) (PVK) and 2,9-dimethyl-4,7-diphenyl-1,10-phenanthroline (BCP) has been studied. A emission peak at 595 nm was observed in EL spectrum but not in PL spectra in the devices. The emission originates from the transition between the excited state of BCP and the ground state of PVK. Because of the increase of emission zone, the device of PVK: BCP blend exhibited stronger electroplex emission. The emission of electronplex was enhanced for both of PVK/BCP double layer device and PVK:BCP blend device, and it is stronger for blend devices. At higher drive voltage, only electroplex emission was observed in the blend device.

  6. Revisiting factors controlling methane emissions from high-Arctic tundra

    DEFF Research Database (Denmark)

    Mastepanov, M.; Sigsgaard, Charlotte; Tagesson, Håkan Torbern

    2013-01-01

    The northern latitudes are experiencing disproportionate warming relative to the mid-latitudes, and there is growing concern about feedbacks between this warming and methane production and release from high-latitude soils. Studies of methane emissions carried out in the Arctic, particularly those...

  7. Validation and sensitivity analysis of a two zone Diesel engine model for combustion and emissions prediction

    International Nuclear Information System (INIS)

    Rakopoulos, C.D.; Rakopoulos, D.C.; Giakoumis, E.G.; Kyritsis, D.C.

    2004-01-01

    The present two zone model of a direct injection (DI) Diesel engine divides the cylinder contents into a non-burning zone of air and another homogeneous zone in which fuel is continuously supplied from the injector and burned with entrained air from the air zone. The growth of the fuel spray zone, which comprises a number of fuel-air conical jets equal to the injector nozzle holes, is carefully modelled by incorporating jet mixing, thus determining the amount of oxygen available for combustion. The mass, energy and state equations are applied in each of the two zones to yield local temperatures and cylinder pressure histories. The concentration of the various constituents in the exhaust gases are calculated by adopting a chemical equilibrium scheme for the C-H-O system of the 11 species considered, together with chemical rate equations for the calculation of nitric oxide (NO). A model for evaluation of the soot formation and oxidation rates is included. The theoretical results from the relevant computer program are compared very favourably with the measurements from an experimental investigation conducted on a fully automated test bed, standard 'Hydra', DI Diesel engine installed at the authors' laboratory. In-cylinder pressure and temperature histories, nitric oxide concentration and soot density are among the interesting quantities tested for various loads and injection timings. As revealed, the model is sensitive to the selection of the constants of the fuel preparation and reaction sub-models, so that a relevant sensitivity analysis is undertaken. This leads to a better understanding of the physical mechanisms governed by these constants and also paves the way for construction of a reliable and relatively simple multi-zone model, which incorporates in each zone (packet) the philosophy of the present two zone model

  8. Validation and sensitivity analysis of a two zone diesel engine model for combustion and emissions prediction

    Energy Technology Data Exchange (ETDEWEB)

    Rakopoulos, C.D.; Rakopoulos, D.C.; Giakoumis, E.G. [National Technical University of Athens (Greece). Mechanical Engineering Dept.; Kyritsis, D.C. [University of Illinois at Urbana-Champaign, Urbana, IL (United States). Dept. of Mechanical and Industrial Engineering

    2004-06-01

    The present two zone model of a direct injection (DI) diesel engine divides the cylinder contents into a non-burning zone of air and another homogeneous zone in which fuel is continuously supplied from the injector and burned with entrained air from the air zone. The growth of the fuel spray zone, which comprises a number of fuel-air conical jets equal to the injector nozzle holes, is carefully modelled by incorporating jet mixing, thus determining the amount of oxygen available for combustion. The mass, energy and state equations are applied in each of the two zones to yield local temperatures and cylinder pressure histories. The concentration of the various constituents in the exhaust gases are calculated by adopting a chemical equilibrium scheme for the C-H-O system of the 11 species considered, together with chemical rate equations for the calculation of nitric oxide (NO). A model for evaluation of the soot formation and oxidation rates is included. The theoretical results from the relevant computer program are compared very favourably with the measurements from an experimental investigation conducted on a fully automated test bed, standard ''Hydra'', DI diesel engine installed at the authors' laboratory. In-cylinder pressure and temperature histories, nitric oxide concentration and soot density are among the interesting quantities tested for various loads and injection timings. As revealed, the model is sensitive to the selection of the constants of the fuel preparation and reaction sub-models, so that a relevant sensitivity analysis is undertaken. This leads to a better understanding of the physical mechanisms governed by these constants and also paves the way for construction of a reliable and relatively simple multi-zone model, which incorporates in each zone (packet) the philosophy of the present two zone model. (author)

  9. Physical properties of fault zone rocks from SAFOD: Tying logging data to high-pressure measurements on drill core

    Science.gov (United States)

    Jeppson, T.; Tobin, H. J.

    2013-12-01

    In the summer of 2005, Phase 2 of the San Andreas Fault Observatory at Depth (SAFOD) borehole was completed and logged with wireline tools including a dipole sonic tool to measure P- and S-wave velocities. A zone of anomalously low velocity was detected from 3150 to 3414 m measured depth (MD), corresponding with the subsurface location of the San Andreas Fault Zone (SAFZ). This low velocity zone is 5-30% slower than the surrounding host rock. Within this broad low-velocity zone, several slip surfaces were identified as well as two actively deforming shear zones: the southwest deformation zone (SDZ) and the central deformation zone (CDZ), located at 3192 and 3302 m MD, respectively. The SAFZ had also previously been identified as a low velocity zone in seismic velocity inversion models. The anomalously low velocity was hypothesized to result from either (a) brittle deformation in the damage zone of the fault, (b) high fluid pressures with in the fault zone, or (c) lithological variation, or a combination of the above. We measured P- and S-wave velocities at ultrasonic frequencies on saturated 2.5 cm diameter core plug samples taken from SAFOD core obtained in 2007 from within the low velocity zone. The resulting values fall into two distinct groups: foliated fault gouge and non-gouge. Samples of the foliated fault gouge have P-wave velocities between 2.3-3.5 km/s while non-gouge samples lie between 4.1-5.4 km/s over a range of effective pressures from 5-70 MPa. There is a good correlation between the log measurements and laboratory values of P-and S wave velocity at in situ pressure conditions especially for the foliated fault gouge. For non-gouge samples the laboratory values are approximately 0.08-0.73 km/s faster than the log values. This difference places the non-gouge velocities within the Great Valley siltstone velocity range, as measured by logs and ultrasonic measurements performed on outcrop samples. As a high fluid pressure zone was not encountered during

  10. Highly oxidising fluids generated during serpentinite breakdown in subduction zones.

    Science.gov (United States)

    Debret, B; Sverjensky, D A

    2017-09-04

    Subduction zones facilitate chemical exchanges between Earth's deep interior and volcanism that affects habitability of the surface environment. Lavas erupted at subduction zones are oxidized and release volatile species. These features may reflect a modification of the oxidation state of the sub-arc mantle by hydrous, oxidizing sulfate and/or carbonate-bearing fluids derived from subducting slabs. But the reason that the fluids are oxidizing has been unclear. Here we use theoretical chemical mass transfer calculations to predict the redox state of fluids generated during serpentinite dehydration. Specifically, the breakdown of antigorite to olivine, enstatite, and chlorite generates fluids with high oxygen fugacities, close to the hematite-magnetite buffer, that can contain significant amounts of sulfate. The migration of these fluids from the slab to the mantle wedge could therefore provide the oxidized source for the genesis of primary arc magmas that release gases to the atmosphere during volcanism. Our results also show that the evolution of oxygen fugacity in serpentinite during subduction is sensitive to the amount of sulfides and potentially metal alloys in bulk rock, possibly producing redox heterogeneities in subducting slabs.

  11. The Effects of Combustion Parameters on Pollutant Emissions in a Porous Burner

    Directory of Open Access Journals (Sweden)

    Negin Moallemi Khiavi

    2014-06-01

    Full Text Available This paper reports a two-dimensional numerical prediction of premixed methane/air combustion in inert porous media. The two dimensional Navier-stokes equations, the two separate energy equations for solid and gas and conservation equations for chemical species are solved using finite volume method based on SIMPLE algorithm. The burner under study is a rectangular one with two different regions. First region is a preheating zone (low porosity matrix that followed by the actual combustion region (high porosity matrix. For simulating the chemical reactions, skeletal mechanism (26 species and 77 reactions is used. For studying the pollutant emissions in this porous burner, the effects of porous matrix properties, excess air ratio and inlet velocity are studied. The predicted gas temperature contour and pollutant formations are in good agreement with the available experimental data. The results indicate that the downstream of the burner should be constructed from materials with high conductivity, high convective heat transfer coefficient and high porosity in order to decrease the CO and NO emissions. Also, with increasing the inlet velocity of gas mixture and the excess air ratio, the pollutant emissions are decreased.

  12. New detector developments for high resolution positron emission tomography

    International Nuclear Information System (INIS)

    Ziegler, S.I.; Pichler, B.; Lorenz, E.

    1998-01-01

    The strength of quantitative, functional imaging using positron emission tomography, specially in small animals, is limited due to the spatial resolution. Therefore, various tomograph designs employing new scintillators, light sensors, or coincidence electronic are investigated to improve resolution without losses in sensitivity. Luminous scintillators with short light decay time in combination with novel readout schemes using photomultipliers or semiconductor detectors are currently tested by several groups and are implemented in tomographs for small animals. This review summarises the state of development in high resolution positron emission tomography with a detailed description of a system incorporating avalanche photodiode arrays and small scintillation crystals. (orig.) [de

  13. The practicality of high magnification imaging by positron emission

    International Nuclear Information System (INIS)

    Hulett, L.D. Jr.; Pendyala, S.

    1988-01-01

    The positron emission microscope has the capability of contrasting areas having high concentrations of monatomic vacancies and other defects. Since the positrons traveling through the specimen will have energies of the same magnitude as that of valence electrons, image contrast will be sensitive to the chemistry of the specimen. In the near future resolutions of 10 nm or lower will be achieved. Whether or not optical aberrations will permit one atom resolution is not clear. For one atom resolution to be obtained positron emission fluxes must be brightness enhanced to 10 11 sec/sup/minus/1/cm/sup/minus/2/ or greater. 5 refs., 1 fig

  14. Development and validation of a multi-zone combustion model for performance and nitric oxide formation in syngas fueled spark ignition engine

    International Nuclear Information System (INIS)

    Rakopoulos, C.D.; Michos, C.N.

    2008-01-01

    The development of a zero-dimensional, multi-zone combustion model is presented for predicting the performance and nitric oxide (NO) emissions of a spark ignition (SI) engine. The model is validated against experimental data from a multi-cylinder, four-stroke, turbocharged and aftercooled, SI gas engine running with syngas fuel. This alternative fuel, the combustible part of which consists mainly of CO and H 2 with the rest containing non-combustible gases, has been recently identified as a promising substitute of fossil fuels in view of environmentally friendly engine operation. The basic concept of the model is the division of the burned gas into several distinct zones, unlike the simpler two-zone models, for taking into account the temperature stratification of the burned mixture during combustion. This is especially important for accurate NO emissions predictions, since NO formation is strongly temperature dependent. The multi-zone formulation provides the chemical species concentrations gradient existing in the burned zones, as well as the relative contribution of each burned zone to the total in-cylinder NO formation. The burning rate required as input to the model is expressed as a Wiebe function, fitted to experimentally derived burn rates. All model's constants are calibrated at one operating point and then kept unchanged. Zone-resolved combustion related information is obtained, assisting in the understanding of the complex phenomena occurring during combustion in SI engines. Combustion characteristics of the lean-burn gas engine tested are provided for the complete load range, aiding the interpretation of its performance and knocking tendency. Computed NO emissions from the multi-zone model for various values of the engine load (i.e. air-fuel ratios) are presented and found to be in good agreement with the respective experimental ones, providing confidence for the predictive capability of the model. The superiority of the multi-zone model over its two-zone

  15. Aggregate-cement paste transition zone properties affecting the salt-frost damage of high-performance concretes

    International Nuclear Information System (INIS)

    Cwirzen, Andrzej; Penttala, Vesa

    2005-01-01

    The influence of the cement paste-aggregate interfacial transition zone (ITZ) on the frost durability of high-performance silica fume concrete (HPSFC) has been studied. Investigation was carried out on eight non-air-entrained concretes having water-to-binder (W/B) ratios of 0.3, 0.35 and 0.42 and different additions of condensed silica fume. Studies on the microstructure and composition of the cement paste have been made by means of environmental scanning electron microscope (ESEM)-BSE, ESEM-EDX and mercury intrusion porosimetry (MIP) analysis. The results showed that the transition zone initiates and accelerates damaging mechanisms by enhancing movement of the pore solution within the concrete during freezing and thawing cycles. Cracks filled with ettringite were primarily formed in the ITZ. The test concretes having good frost-deicing salt durability featured a narrow transition zone and a decreased Ca/Si atomic ratio in the transition zone compared to the bulk cement paste. Moderate additions of silica fume seemed to densify the microstructure of the ITZ

  16. Oxygen minimum zones harbour novel viral communities with low diversity

    NARCIS (Netherlands)

    Cassman, N.; Prieto-Davo, A.; Walsh, K.; Silva, G.G.; Angly, F.; Akhter, S.; Barott, K.; Busch, J.; McDole, T.; Haggerty, J.M.; Willner, D.; Alarcon, G.; Ulloa, O.; DeLong, E.F.; Dutilh, B.E.; Rohwer, F.; Dinsdale, E.A.

    2012-01-01

    Oxygen minimum zones (OMZs) are oceanographic features that affect ocean productivity and biodiversity, and contribute to ocean nitrogen loss and greenhouse gas emissions. Here we describe the viral communities associated with the Eastern Tropical South Pacific (ETSP) OMZ off Iquique, Chile for the

  17. Investigations into NOx emissions and burnout for coals with high ash content in a bench scale test facility

    Energy Technology Data Exchange (ETDEWEB)

    Greul, U.; Kluger, F.; Peter, G.; Spliethoff, H.; Hein, K.R.G. [University of Stuttgart, Stuttgart (Germany). Inst. fuer Verfahrenstechnik und Dampfkesselwesen

    2000-07-01

    At the Stuttgart University's Institute of Process Engineering and Power Plant Technology (IVD) investigations of in-furnace DeNOx technologies with regard to their NOx reduction efficiency are carried out using an electrically heated bench-scale test facility to evaluate the effect of different process parameters independently. The DeNOx technologies of air and fuel staging have been demonstrated to be effective control techniques to reduce NOx from stationary sources. For a wide range of brown and hard coals from Europe, South Africa and Australia test runs with air-staged combustion have been carried out. The ash content of the hard coals used was in the range between 8 and 28%. The investigated parameters were temperature (1000-1300{degree}C), stoichiometry (1.25-0.55), and residence time (1-6 s) in the fuel rich primary zone. With increasing temperatures and residence times in fuel-rich conditions in air-staged combustion NOx emissions below 300 mg/m{sup 3} can be achieved even with hard coals. For a few brown coals NOx values lower than 100 mg/m{sup 3} are possible. Dependent on the coal rank individual parameters are more important than others. For low and medium volatile hard coals the increasing of the residence time is more effective than higher temperature or lower air ratios in the primary zone. However, with high volatile hard coal or brown coal as primary fuel the influence of temperature and stoichiometry in the primary zone plays a key role for NOx reduction effectiveness. The burnout led to restrictions in large scale applications for air-staged combustion especially with hard coals as primary fuel. Investigations at different primary air ratios and temperatures show the effect of these parameters on the burnout values along the course of combustion. 7 refs., 14 figs., 2 tabs.

  18. High-Impact Actions for Individuals to Reduce Greenhouse Gas Emissions

    Science.gov (United States)

    Nicholas, K. A.; Wynes, S. C.

    2015-12-01

    Climate change is the result of greenhouse gas accumulation in the atmosphere, which records the aggregation of billions of individual decisions. While systemic and structural changes receive great attention for addressing climate change, the contribution that individual citizens can make is often overlooked, especially in developed countries where per-capita emissions are highest. Here we consider a broad range of individual lifestyle choices and calculate their potential to reduce greenhouse gas emissions. We find that four widely applicable high-impact actions have the potential to reduce personal emissions by more than 1 tonne CO2-equivalent per year: having one fewer child (59.2 tonnes of reductions), living car-free (2.3 tonnes), avoiding airplane travel (1.5 tonnes per flight) and eating a plant-based diet (0.82 tonnes). These actions have much greater potential to reduce emissions than commonly promoted strategies like recycling (4 times less effective than a plant-based diet) or changing lightbulbs (8 times). However, high school textbooks from Canada and government resources from the EU, USA, Canada, and Australia largely fail to mention these actions, instead focusing on incremental changes with much smaller potential impact. We conclude that climate policy should focus not only on national and international targets, but also on encouraging responsible behaviour, especially for adolescents who will grow up in the era of climate change and are poised to establish a lifelong pattern of sustainable lifestyle choices.

  19. NOx Emission Reduction by Oscillating Combustion

    Energy Technology Data Exchange (ETDEWEB)

    John C. Wagner

    2004-03-31

    High-temperature, natural gas-fired furnaces, especially those fired with preheated air, produce large quantities of NO{sub x} per ton of material processed. Regulations on emissions from industrial furnaces are becoming increasingly more stringent. In addition, competition is forcing operators to make their furnaces more productive and/or efficient. Switching from preheated air to industrial oxygen can increase efficiency and reduce NO{sub x}, but oxygen is significantly more costly than air and may not be compatible with the material being heated. What was needed, and what was developed during this project, is a technology that reduces NO{sub x} emissions while increasing furnace efficiency for both air- and oxy-fired furnaces. Oscillating combustion is a retrofit technology that involves the forced oscillation of the fuel flow rate to a furnace. These oscillations create successive, fuel-rich and fuel-lean zones within the furnace. Heat transfer from the flame to the load increases due to the more luminous fuel-rich zones, a longer overall flame length, and the breakup of the thermal boundary layer. The increased heat transfer shortens heat up times, thereby increasing furnace productivity, and reduces the heat going up the stack, thereby increasing efficiency. The fuel-rich and fuel-lean zones also produce substantially less NO{sub x} than firing at a constant excess air level. The longer flames and higher heat transfer rate reduces overall peak flame temperature and thus reduces additional NO{sub x} formation from the eventual mixing of the zones and burnout of combustibles from the rich zones. This project involved the development of hardware to implement oscillating combustion on an industrial scale, the laboratory testing of oscillating combustion on various types of industrial burners, and the field testing of oscillating combustion on several types of industrial furnace. Before laboratory testing began, a market study was conducted, based on the

  20. NOx Emission Reduction by Oscillating combustion

    Energy Technology Data Exchange (ETDEWEB)

    Institute of Gas Technology

    2004-01-30

    High-temperature, natural gas-fired furnaces, especially those fired with preheated air, produce large quantities of NO{sub x} per ton of material processed. Regulations on emissions from industrial furnaces are becoming increasingly more stringent. In addition, competition is forcing operators to make their furnaces more productive and/or efficient. Switching from preheated air to industrial oxygen can increase efficiency and reduce NO{sub x}, but oxygen is significantly more costly than air and may not be compatible with the material being heated. What was needed, and what was developed during this project, is a technology that reduces NO{sub x} emissions while increasing furnace efficiency for both air- and oxy-fired furnaces. Oscillating combustion is a retrofit technology that involves the forced oscillation of the fuel flow rate to a furnace. These oscillations create successive, fuel-rich and fuel-lean zones within the furnace. Heat transfer from the flame to the load increases due to the more luminous fuel-rich zones, a longer overall flame length, and the breakup of the thermal boundary layer. The increased heat transfer shortens heat up times, thereby increasing furnace productivity, and reduces the heat going up the stack, thereby increasing efficiency. The fuel-rich and fuel-lean zones also produce substantially less NO{sub x} than firing at a constant excess air level. The longer flames and higher heat transfer rate reduces overall peak flame temperature and thus reduces additional NO{sub x} formation from the eventual mixing of the zones and burnout of combustibles from the rich zones. This project involved the development of hardware to implement oscillating combustion on an industrial scale, the laboratory testing of oscillating combustion on various types of industrial burners, and the field testing of oscillating combustion on several types of industrial furnace. Before laboratory testing began, a market study was conducted, based on the

  1. Denuded zone in Czochralski silicon wafer with high carbon content

    International Nuclear Information System (INIS)

    Chen Jiahe; Yang Deren; Ma Xiangyang; Que Duanlin

    2006-01-01

    The thermal stability of the denuded zone (DZ) created by high-low-high-temperature annealing in high carbon content (H[C]) and low carbon content (L[C]) Czochralski silicon (Cz-Si) has been investigated in a subsequent ramping and isothermal 1050 deg. C annealing. The tiny oxygen precipitates which might occur in the DZ were checked. It was found in the L[C] Cz-Si that the DZ shrank and the density of bulk micro-defects (BMDs) reduced with the increase of time spent at 1050 deg. C. Also, the DZs above 15 μm of thickness present in the H[C] Cz-Si wafers continuously and the density and total volume of BMDs first decreased then increased and finally decreased again during the treatments. Moreover, tiny oxygen precipitates were hardly generated inside the DZs, indicating that H[C] Cz-Si wafers could support the fabrication of integrated circuits

  2. Denuded zone in Czochralski silicon wafer with high carbon content

    Science.gov (United States)

    Chen, Jiahe; Yang, Deren; Ma, Xiangyang; Que, Duanlin

    2006-12-01

    The thermal stability of the denuded zone (DZ) created by high-low-high-temperature annealing in high carbon content (H[C]) and low carbon content (L[C]) Czochralski silicon (Cz-Si) has been investigated in a subsequent ramping and isothermal 1050 °C annealing. The tiny oxygen precipitates which might occur in the DZ were checked. It was found in the L[C] Cz-Si that the DZ shrank and the density of bulk micro-defects (BMDs) reduced with the increase of time spent at 1050 °C. Also, the DZs above 15 µm of thickness present in the H[C] Cz-Si wafers continuously and the density and total volume of BMDs first decreased then increased and finally decreased again during the treatments. Moreover, tiny oxygen precipitates were hardly generated inside the DZs, indicating that H[C] Cz-Si wafers could support the fabrication of integrated circuits.

  3. Cutting zone area and chip morphology in high-speed cutting of titanium alloy Ti-6Al-4V

    International Nuclear Information System (INIS)

    Ke, Qing Chan; Xu, Daochun; Xiong, Dan Ping

    2017-01-01

    The titanium alloy Ti-6Al-4V has superior properties but poor machinability, yet is widely used in aerospace and biomedical industries. Chip formation and cutting zone area are important factors that have received limited attention. Thus, we propose a high-speed orthogonal cutting model for serrated chip formation. The high speed orthogonal cutting of Ti-6Al-4V was studied with a cutting speed of 10-160 m/min and a feed of 0.07-0.11 mm/r. Using theoretical models and experimental results, parameters such as chip shape, serration level, slip angle, and shear slip distance were investigated. Cutting zone boundaries (tool-chip contact length, length of shear plane, and critical slip plane) and cutting zone area were obtained. The results showed that discontinuous, long-curling, and continuous chips were formed at low, medium, and high speeds, respectively. Serration level, shear slip distance, and slip angle rose with increasing cutting speed. The length of shear plane, tool-chip contact, and critical slip plane varied subtly with increased cutting speed, and rose noticeably with increased feed. Cutting zone area grew weakly with increased cutting speed, levelling off at high cutting speed; however, it rose noticeably with increased feed. This study furthers our understanding of the shear slip phenomenon and the mechanism of serrated chip formation

  4. Cutting zone area and chip morphology in high-speed cutting of titanium alloy Ti-6Al-4V

    Energy Technology Data Exchange (ETDEWEB)

    Ke, Qing Chan; Xu, Daochun; Xiong, Dan Ping [School of Technology, Beijing Forestry University, Beijing (China)

    2017-01-15

    The titanium alloy Ti-6Al-4V has superior properties but poor machinability, yet is widely used in aerospace and biomedical industries. Chip formation and cutting zone area are important factors that have received limited attention. Thus, we propose a high-speed orthogonal cutting model for serrated chip formation. The high speed orthogonal cutting of Ti-6Al-4V was studied with a cutting speed of 10-160 m/min and a feed of 0.07-0.11 mm/r. Using theoretical models and experimental results, parameters such as chip shape, serration level, slip angle, and shear slip distance were investigated. Cutting zone boundaries (tool-chip contact length, length of shear plane, and critical slip plane) and cutting zone area were obtained. The results showed that discontinuous, long-curling, and continuous chips were formed at low, medium, and high speeds, respectively. Serration level, shear slip distance, and slip angle rose with increasing cutting speed. The length of shear plane, tool-chip contact, and critical slip plane varied subtly with increased cutting speed, and rose noticeably with increased feed. Cutting zone area grew weakly with increased cutting speed, levelling off at high cutting speed; however, it rose noticeably with increased feed. This study furthers our understanding of the shear slip phenomenon and the mechanism of serrated chip formation.

  5. K-α emission form medium and high-Z materials irradiated by femtosecond laser pulses

    International Nuclear Information System (INIS)

    Limpouch, J.; Klimo, O.; Zhavoronkov, N.; Andreev, A.A.

    2006-01-01

    Complete test of publication follows. Fast electrons are created at the target surface during the interaction of high intensity ultra short laser pulses with solids. Fast electrons penetrate deep into the target where they generate K-α and Bremsstrahlung radiation. Generated high brightness K-α pulses offer the prospect of creating a cheap and compact X-ray source, posing a promising alternative to synchrotron radiation, e.g. in medical application and in material science. With an increase in laser intensity, efficient X-ray emission in the multi-keV range with pulse duration shorter than few picoseconds is expected. This short incoherent but monochromatic X-ray emission synchronized with laser pulses may be used for time-resolved measurements. Acceleration of fast electrons, their transport and K-α photon generation and emission from the target surface in both forward and backward directions are studied here numerically. The results are compared to recent experiments studying K-α emission from the front and rear surface of copper foil targets of various thicknesses and for various parameters of the laser plasma interaction. One-dimensional PIC simulations coupled with 3D time-resolved Monte Carlo simulations show that account of ionization processes and of density profile formed by laser ASE emission is essential for reliable explanation of experimental data. While sub-relativistic intensities are optimum for laser energy transformation into K-α emission for medium-Z targets, relativistic laser intensities have to be used for hard X-ray generation in high-Z materials. The cross-section for K-α shell ionization of high-Z elements by electrons increases or remains approximately constant within a factor of two at relativistic electron energies up to electron energies in the 100-MeV range. Moreover, the splitting ratio of K-α photon emission to Auger electron emission is favorable for high-Z materials, and thus efficient K-α emission is possible. In our

  6. Towards stacked zone plates

    International Nuclear Information System (INIS)

    Werner, S; Rehbein, S; Guttman, P; Heim, S; Schneider, G

    2009-01-01

    Fresnel zone plates are the key optical elements for soft and hard x-ray microscopy. For short exposure times and minimum radiation load of the specimen the diffraction efficiency of the zone plate objectives has to be maximized. As the efficiency strongly depends on the height of the diffracting zone structures the achievable aspect ratio of the nanostructures determines these limits. To reach aspect ratios ≥ 20:1 for high efficient optics we propose to superimpose zone plates on top of each other. With this multiplication approach the final aspect ratio is only limited by the number of stacked zone plate layers. For the stack process several nanostructuring process steps have to be developed and/or improved. Our results show for the first time two layers of zone plates stacked on top of each other.

  7. Simulating three-dimensional nonthermal high-energy photon emission in colliding-wind binaries

    Energy Technology Data Exchange (ETDEWEB)

    Reitberger, K.; Kissmann, R.; Reimer, A.; Reimer, O., E-mail: klaus.reitberger@uibk.ac.at [Institut für Astro- und Teilchenphysik and Institut für Theoretische Physik, Leopold-Franzens-Universität Innsbruck, A-6020 Innsbruck (Austria)

    2014-07-01

    Massive stars in binary systems have long been regarded as potential sources of high-energy γ rays. The emission is principally thought to arise in the region where the stellar winds collide and accelerate relativistic particles which subsequently emit γ rays. On the basis of a three-dimensional distribution function of high-energy particles in the wind collision region—as obtained by a numerical hydrodynamics and particle transport model—we present the computation of the three-dimensional nonthermal photon emission for a given line of sight. Anisotropic inverse Compton emission is modeled using the target radiation field of both stars. Photons from relativistic bremsstrahlung and neutral pion decay are computed on the basis of local wind plasma densities. We also consider photon-photon opacity effects due to the dense radiation fields of the stars. Results are shown for different stellar separations of a given binary system comprising of a B star and a Wolf-Rayet star. The influence of orbital orientation with respect to the line of sight is also studied by using different orbital viewing angles. For the chosen electron-proton injection ratio of 10{sup –2}, we present the ensuing photon emission in terms of two-dimensional projections maps, spectral energy distributions, and integrated photon flux values in various energy bands. Here, we find a transition from hadron-dominated to lepton-dominated high-energy emission with increasing stellar separations. In addition, we confirm findings from previous analytic modeling that the spectral energy distribution varies significantly with orbital orientation.

  8. Quantifying greenhouse gas emissions from municipal solid waste dumpsites in Cameroon.

    Science.gov (United States)

    Ngwabie, N Martin; Wirlen, Yvette L; Yinda, Godwin S; VanderZaag, Andrew C

    2018-03-02

    Open dumpsites that receive municipal solid waste are potentially significant sources of greenhouse gas (GHG) emissions into the atmosphere. There is little data available on emissions from these sources, especially in the unique climate and management of central Africa. This research aimed at quantifying CH 4 , N 2 O and CO 2 emissions from two open dumpsites in Cameroon, located in Mussaka-Buea, regional headquarters of the South West Region and in Mbellewa-Bamenda, regional headquarters of the North West Region. Emissions were measured during the wet season (May 2015 and August 2016) at the Mussaka and Mbellewa dumpsites respectively. Dumpsite surfaces were partitioned into several zones for emission measurements, based on the current activity and the age of the waste. Static flux chambers were used to quantify gas emission rates thrice a day (mornings, afternoons and evenings). Average emissions were 96.80 ± 144 mg CH 4 m -2  min -1 , 0.20 ± 0.43 mg N 2 O m -2  min -1 and 224.78 ± 312 mg CO 2 m -2  min -1 in the Mussaka dumpsite, and 213.44 ± 419 mg CH 4 m -2  min -1 , 0.15 ± 0.15 mg N 2 O m -2  min -1 and 1103.82 ± 1194 mg CO 2 m -2  min -1 at the Mbellewa dumpsite. Emissions as high as 1784 mg CH 4 m -2  min -1 , 2.3 mg N 2 O m -2  min -1 and 5448 mg CO 2 m -2  min -1 were measured from both dumpsites. Huge variations observed in emissions between the different zones on the waste surface were likely a result of the heterogeneous nature of the waste, different stages in waste decomposition and different environmental conditions within the waste. Management activities that disturb waste, such as spreading and compressing potentially increase gas emissions, while covering waste with a layer of soil potentially mitigate gas emissions. Recommendations were for dumpsites to be upgraded to sanitary landfills, and biogas production from such landfills should be exploited to reduce CH 4 emissions

  9. Exploring stop-go decision zones at rural high-speed intersections with flashing green signal and insufficient yellow time in China.

    Science.gov (United States)

    Tang, Keshuang; Xu, Yanqing; Wang, Fen; Oguchi, Takashi

    2016-10-01

    The objective of this study is to empirically analyze and model the stop-go decision behavior of drivers at rural high-speed intersections in China, where a flashing green signal of 3s followed by a yellow signal of 3s is commonly applied to end a green phase. 1, 186 high-resolution vehicle trajectories were collected at four typical high-speed intersection approaches in Shanghai and used for the identification of actual stop-go decision zones and the modeling of stop-go decision behavior. Results indicate that the presence of flashing green significantly changed the theoretical decision zones based on the conventional Dilemma Zone theory. The actual stop-go decision zones at the study intersections were thus formulated and identified based on the empirical data. Binary Logistic model and Fuzzy Logic model were then developed to further explore the impacts of flashing green on the stop-go behavior of drivers. It was found that the Fuzzy Logic model could produce comparably good estimation results as compared to the traditional Binary Logistic models. The findings of this study could contribute the development of effective dilemma zone protection strategies, the improvement of stop-go decision model embedded in the microscopic traffic simulation software and the proper design of signal change and clearance intervals at high-speed intersections in China. Copyright © 2016 Elsevier Ltd. All rights reserved.

  10. Oceanic N2O emissions in the 21st century

    Science.gov (United States)

    Martinez-Rey, J.; Bopp, L.; Gehlen, M.; Tagliabue, A.; Gruber, N.

    2014-12-01

    The ocean is a substantial source of nitrous oxide (N2O) to the atmosphere, but little is known on how this flux might change in the future. Here, we investigate the potential evolution of marine N2O emissions in the 21st century in response to anthropogenic climate change using the global ocean biogeochemical model NEMO-PISCES. We implemented two different parameterizations of N2O production, which differ primarily at low oxygen (O2) conditions. When forced with output from a climate model simulation run under the business-as-usual high CO2 concentration scenario (RCP8.5), our simulations suggest a decrease of 4 to 12% in N2O emissions from 2005 to 2100, i.e., a reduction from 4.03/3.71 to 3.54/3.56 Tg N yr-1 depending on the parameterization. The emissions decrease strongly in the western basins of the Pacific and Atlantic oceans, while they tend to increase above the Oxygen Minimum Zones (OMZs), i.e., in the Eastern Tropical Pacific and in the northern Indian Ocean. The reduction in N2O emissions is caused on the one hand by weakened nitrification as a consequence of reduced primary and export production, and on the other hand by stronger vertical stratification, which reduces the transport of N2O from the ocean interior to the ocean surface. The higher emissions over the OMZ are linked to an expansion of these zones under global warming, which leads to increased N2O production associated primarily with denitrification. From the perspective of a global climate system, the averaged feedback strength associated with the projected decrease in oceanic N2O emissions amounts to around -0.009 W m-2 K-1, which is comparable to the potential increase from terrestrial N2O sources. However, the assesment for a compensation between the terrestrial and marine feedbacks calls for an improved representation of N2O production terms in fully coupled next generation of Earth System Models.

  11. Defects of diamond single crystal grown under high temperature and high pressure

    Energy Technology Data Exchange (ETDEWEB)

    Su, Qingcai, E-mail: suqc@sdu.edu.cn [Key Laboratory of Liquid Structure and Heredity of Materials (Ministry of Education), Shandong University, Jinan, P. R. China, 250061 (China); School of Materials Science and Engineering, Shandong University, Jinan, P. R. China, 250061 (China); Shandong Engineering Research Center for Superhard Materials, Zoucheng, P. R. China 273500 (China); Zhang, Jianhua [School of Mechanical Engineering, Shandong University, Jinan, P. R. China, 250061 (China); Li, Musen [Key Laboratory of Liquid Structure and Heredity of Materials (Ministry of Education), Shandong University, Jinan, P. R. China, 250061 (China); School of Materials Science and Engineering, Shandong University, Jinan, P. R. China, 250061 (China); Shandong Engineering Research Center for Superhard Materials, Zoucheng, P. R. China 273500 (China)

    2013-11-01

    The diamond single crystal, synthesized with Fe–Ni–C–B system of catalyst under high temperature and high pressure, had been observed by field emission scanning electron microscope and transmission electron microscope. The presence of a cellular structure suggested that the diamond grew from melted catalyst solution and there existed a zone of component supercooling zone in front of the solid–liquid interface. The main impurities in the diamond crystal was (FeNi){sub 23}C{sub 6}. The triangle screw pit revealed on the (111) plane was generated by the screw dislocation meeting the diamond (111) plane at the points of emergence of dislocations. A narrow twin plane was formed between the two (111) plane. - Highlights: • High pressure, high temperature synthesis of diamond single crystal. • Fe–Ni–C–B used as catalyst, graphite as carbon source. • The main impurity in the diamond crystal was (FeNi){sub 23}C{sub 6}. • Surface defects arose from screw dislocations and stacking faults.

  12. The High-Temperature Resistance Properties of Polysiloxane/Al Coatings with Low Infrared Emissivity

    Directory of Open Access Journals (Sweden)

    Jun Zhao

    2018-03-01

    Full Text Available High-temperature-resistant coatings with low infrared emissivity were prepared using polysiloxane resin and flake aluminum as the adhesive and pigment, respectively. The heat resistance mechanisms of the polysiloxane/Al coating were systematically investigated. The composition, surface morphology, infrared reflectance spectra, and thermal expansion dimension (ΔL of the coatings were characterized by X-ray photoelectron spectroscopy (XPS, field emission scanning electron microscopy (FE-SEM, Fourier transform infrared spectroscopy, and thermal mechanical analysis (TMA, respectively. The results show that thermal decomposition of the resin and mismatch of ΔL between the coating and the substrate facilitate the high temperature failure of the coating. A suitable amount of flake aluminum pigments could restrain the thermal decomposition of the resin and could increase the match degree of ΔL between the coating and substrate, leading to an enhanced thermal resistance of the coating. Our results find that a coating with a pigment to binder ratio (P/B ratio of 1.0 could maintain integrity until 600 °C, and the infrared emissivity was as low as 0.27. Hence, a coating with high-temperature resistance and low emissivity was obtained. Such coatings can be used for infrared stealth technology or energy savings in high-temperature equipment.

  13. Recombination dominated hydrogenic emission from the detached plasmas in W7-AS

    International Nuclear Information System (INIS)

    Ramasubramanian, N.; Koenig, R.; Wenzel, U.; Thomsen, H.; McCormick, K.; Grigull, P.; Feng, Y.; Klinger, T.; John, A.

    2003-01-01

    Beyond a certain threshold average density in the High-Density H-Mode the island divertor plasma in the stellarator W7-AS undergoes partial detachment. The tomographic reconstruction of the radiated power density from the detached pulses show that the radiation profile in the triangular plane is also asymmetric. In the detached phase, the spectrometer viewing tangentially to the target tiles in the top divertor region manifests that the impurity radiation layer is close to the X-points. The spectral analysis also demonstrates the presence of a hydrogen radiation zone dominated by recombination emission close to the target tiles. This papers presents the emission from the deeply detached locations including the volume recombination in a stable discharge. (orig.)

  14. Acoustic and Emission Characteristics of Small, High-Speed Internal Combustion Engines

    Science.gov (United States)

    1981-07-01

    The intent of this study is to obtain information on small high-speed engines so that their effect on the urban environment may be assessed, and if necessary, programs devised to reduce the noise and other emissions from vehicles using these highly d...

  15. Energy Intensity and Greenhouse Gas Emissions from Oil Production in the Eagle Ford Shale

    Energy Technology Data Exchange (ETDEWEB)

    Yeh, Sonia; Ghandi, Abbas; Scanlon, Bridget R.; Brandt, Adam R.; Cai, Hao; Wang, Michael Q.; Vafi, Kourosh; Reedy, Robert C.

    2017-01-30

    A rapid increase in horizontal drilling and hydraulic fracturing in shale and “tight” formations that began around 2000 has resulted in record increases in oil and natural gas production in the U.S. This study examines energy consumption and greenhouse gas (GHG) emissions from crude oil and natural gas produced from ~8,200 wells in the Eagle Ford Shale in southern Texas from 2009 to 2013. Our system boundary includes processes from primary exploration wells to the refinery entrance gate (henceforth well-to-refinery or WTR). The Eagle Ford includes four distinct production zones—black oil (BO), volatile oil (VO), condensate (C), and dry gas (G) zones—with average monthly gas-to-liquids ratios (thousand cubic feet per barrel—Mcf/bbl) varying from 0.91 in the BO zone to 13.9 in the G zone. Total energy consumed in drilling, extracting, processing, and operating an Eagle Ford well is ~1.5% of the energy content of the produced crude and gas in the BO and VO zones, compared with 2.2% in the C and G zones. On average, the WTR GHG emissions of gasoline, diesel, and jet fuel derived from crude oil produced in the BO and VO zones in the Eagle Ford play are 4.3, 5.0, and 5.1 gCO2e/MJ, respectively. Comparing with other known conventional and unconventional crude production where upstream GHG emissions are in the range 5.9–30 gCO2e/MJ, oil production in the Eagle Ford has lower WTR GHG emissions.

  16. Dose estimation for nuclear power plant 4 accident in Taiwan at Fukushima nuclear meltdown emission level.

    Science.gov (United States)

    Tang, Mei-Ling; Tsuang, Ben-Jei; Kuo, Pei-Hsuan

    2016-05-01

    An advanced Gaussian trajectory dispersion model is used to evaluate the evacuation zone due to a nuclear meltdown at the Nuclear Power Plant 4 (NPP4) in Taiwan, with the same emission level as that occurred at Fukushima nuclear meltdown (FNM) in 2011. Our study demonstrates that a FNM emission level would pollute 9% of the island's land area with annual effective dose ≥50 mSv using the meteorological data on 11 March 2011 in Taiwan. This high dose area is also called permanent evacuation zone (denoted as PEZ). The PEZ as well as the emergency-planning zone (EPZ) are found to be sensitive to meteorological conditions on the event. In a sunny day under the dominated NE wind conditions, the EPZ can be as far as 100 km with the first 7-day dose ≥20 mSv. Three hundred sixty-five daily events using the meteorological data from 11 March 2011 to 9 March 2012 are evaluated. It is found that the mean land area of Taiwan in becoming the PEZ is 11%. Especially, the probabilities of the northern counties/cities (Keelung, New Taipei, Taipei, Taoyuan, Hsinchu City, Hsinchu County and Ilan County) to be PEZs are high, ranging from 15% in Ilan County to 51% in Keelung City. Note that the total population of the above cities/counties is as high as 10 million people. Moreover, the western valleys of the Central Mountain Range are also found to be probable being PEZs, where all of the reservoirs in western Taiwan are located. For example, the probability can be as high as 3% in the far southern-most tip of Taiwan Island in Pingtung County. This shows that the entire populations in western Taiwan can be at risk due to the shortage of clean water sources under an event at FNM emission level, especially during the NE monsoon period. Copyright © 2016 The Authors. Published by Elsevier Ltd.. All rights reserved.

  17. Complex fragment emission at low and high excitation energy

    International Nuclear Information System (INIS)

    Moretto, L.G.

    1986-08-01

    Complex fragment emission has been certified as a compound nucleus process at low energies. An extension of the measurements to heavy ion reactions up to 50 MeV/u shows that most complex fragments are emitted by highly excited compound nuclei formed in incomplete fusion reactions. 12 refs., 26 figs

  18. High-resolution mapping of biomass burning emissions in tropical regions across three continents

    Science.gov (United States)

    Shi, Yusheng; Matsunaga, Tsuneo; Saito, Makoto

    2015-04-01

    Biomass burning emissions from open vegetation fires (forest fires, savanna fires, agricultural waste burning), human waste and biofuel combustion contain large amounts of trace gases (e.g., CO2, CH4, and N2O) and aerosols (BC and OC), which significantly impact ecosystem productivity, global atmospheric chemistry, and climate . With the help of recently released satellite products, biomass density based on satellite and ground-based observation data, and spatial variable combustion factors, this study developed a new high-resolution emissions inventory for biomass burning in tropical regions across three continents in 2010. Emissions of trace gases and aerosols from open vegetation burning are estimated from burned areas, fuel loads, combustion factors, and emission factors. Burned areas were derived from MODIS MCD64A1 burned area product, fuel loads were mapped from biomass density data sets for herbaceous and tree-covered land based on satellite and ground-based observation data. To account for spatial heterogeneity in combustion factors, global fractional tree cover (MOD44B) and vegetation cover maps (MCD12Q1) were introduced to estimate the combustion factors in different regions by using their relationship with tree cover under less than 40%, between 40-60% and above 60% conditions. For emission factors, the average values for each fuel type from field measurements are used. In addition to biomass burning from open vegetation fires, the emissions from human waste (residential and dump) burning and biofuel burning in 2010 were also estimated for 76 countries in tropical regions across the three continents and then allocated into each pixel with 1 km grid based on the population density (Gridded Population of the World v3). Our total estimates for the tropical regions across the three continents in 2010 were 17744.5 Tg CO2, 730.3 Tg CO, 32.0 Tg CH4, 31.6 Tg NOx, 119.2 Tg NMOC, 6.3 Tg SO2, 9.8 NH3 Tg, 81.8 Tg PM2.5, 48.0 Tg OC, and 5.7 Tg BC, respectively. Open

  19. A new method to compare vehicle emissions measured by remote sensing and laboratory testing: high-emitters and potential implications for emission inventories.

    Science.gov (United States)

    Smit, Robin; Bluett, Jeff

    2011-06-01

    A new method is presented which is designed to investigate whether laboratory test data used in the development of vehicle emission models adequately reflects emission distributions, and in particular the influence of high-emitting vehicles. The method includes the computation of a 'high-emitter' or 'emission distribution' correction factor for use in emission inventories. In order to make a valid comparison we control for a number of factors such as vehicle technology, measurement technique and driving conditions and use a variable called 'Pollution Index' (g/kg). Our investigation into one vehicle class has shown that laboratory and remote sensing data are substantially different for CO, HC and NO(x) emissions, both in terms of their distributions as well as in their mean and 99-percentile values. Given that the remote sensing data has larger mean values for these pollutants, the analysis suggests that high-emitting vehicles may not be adequately captured in the laboratory test data. The paper presents two different methods for the computation of weighted correction factors for use in emission inventories based on laboratory test data: one using mean values for six 'power bins' and one using multivariate regression functions. The computed correction factors are substantial leading to an increase for laboratory-based emission factors with a factor of 1.7-1.9 for CO, 1.3-1.6 for HC and 1.4-1.7 for NO(x) (actual value depending on the method). However, it also clear that there are points that require further examination before these correction factors should be applied. One important step will be to include a comparison with other types of validation studies such as tunnel studies and near-road air quality assessments to examine if these correction factors are confirmed. If so, we would recommend using the correction factors in emission inventories for motor vehicles. Copyright © 2011 Elsevier B.V. All rights reserved.

  20. High-resolution MR imaging of the proximal zone of the lunotriquetral ligament with a microscopy coil

    International Nuclear Information System (INIS)

    Yoshioka, Hiroshi; Carrino, John A.; Lang, Philipp; Winalski, Carl S.; Tanaka, Toshikazu; Ueno, Teruko; Shindo, Masashi

    2006-01-01

    To evaluate high-resolution MRI of the proximal zone of the lunotriquetral ligament (LTL) using a microscopy surface coil with a 1.5 T scanner. The proximal zone of the LTL was reviewed in 90 subjects (23 asymptomatic normal volunteers and 67 patients with suspicion of triangular fibrocartilage complex injury) with high-resolution MRI using a 47-mm microscopy surface coil. High-resolution MR images were obtained with gradient recalled echo (GRE) T2*-weighted sequence and short tau inversion recovery imaging, with a 1- to 1.5-mm slice thickness, a 50-mm field of view, an imaging matrix of 140-224 x 512 using zero fill interpolation, and 3-4 excitations. As a qualitative analysis, the LTL was classified in shape and signal intensity. The triangle-shaped low-signal-intensity LTL was identified in 77 of 90 subjects (85.6%) on GRE images. The triangle was classified as regular (41.1%), broad-based (20.0%), narrow-based (6.7%), or asymmetrical (17.8%). The bar-shaped ligament was seen in one patient, and unclassified ligaments were seen in 12 patients. All volunteers showed triangle-shaped LTL. The MR signal intensity of the proximal zone in the LTL was characterized as homogeneously low intensity (type 1; 33.8%). (orig.)

  1. High-resolution MR imaging of the proximal zone of the lunotriquetral ligament with a microscopy coil

    Energy Technology Data Exchange (ETDEWEB)

    Yoshioka, Hiroshi; Carrino, John A.; Lang, Philipp; Winalski, Carl S. [Brigham and Women' s Hospital, Department of Radiology, Boston, MA (United States); Tanaka, Toshikazu [Tsukuba Memorial Hospital, Department of Orthopedic Surgery, Tsukuba (Japan); Ueno, Teruko [University of Tsukuba, Department of Radiology, Tsukuba (Japan); Shindo, Masashi [Tsukuba University Hospital, Tsukuba (Japan)

    2006-05-15

    To evaluate high-resolution MRI of the proximal zone of the lunotriquetral ligament (LTL) using a microscopy surface coil with a 1.5 T scanner. The proximal zone of the LTL was reviewed in 90 subjects (23 asymptomatic normal volunteers and 67 patients with suspicion of triangular fibrocartilage complex injury) with high-resolution MRI using a 47-mm microscopy surface coil. High-resolution MR images were obtained with gradient recalled echo (GRE) T2*-weighted sequence and short tau inversion recovery imaging, with a 1- to 1.5-mm slice thickness, a 50-mm field of view, an imaging matrix of 140-224 x 512 using zero fill interpolation, and 3-4 excitations. As a qualitative analysis, the LTL was classified in shape and signal intensity. The triangle-shaped low-signal-intensity LTL was identified in 77 of 90 subjects (85.6%) on GRE images. The triangle was classified as regular (41.1%), broad-based (20.0%), narrow-based (6.7%), or asymmetrical (17.8%). The bar-shaped ligament was seen in one patient, and unclassified ligaments were seen in 12 patients. All volunteers showed triangle-shaped LTL. The MR signal intensity of the proximal zone in the LTL was characterized as homogeneously low intensity (type 1; 33.8%). (orig.)

  2. Study of the high energy emission of accreting compact objects with SPI/INTEGRAL

    International Nuclear Information System (INIS)

    Droulans, R.

    2011-01-01

    The study of the high energy emission is essential for understanding the radiative processes inherent to accretion flows onto compact objects (black holes and neutron stars). The X/γ-ray continuum of these systems is successfully interpreted in terms of two components. The first component corresponds to blackbody emission from a geometrically thin optically thick accretion disk while the second component is generally associated to Compton scattering of the thermal disk flux off hot electrons. Despite considerable advances throughout the years, the heating mechanisms as well as the structure of the hot Comptonizing plasma remain poorly understood. In order to shed light on the physical processes that govern the innermost regions of the accretion flow, we take advantage of the data archive accumulated by the SPI instrument, a high energy spectrometer (20 keV - 8 MeV) developed at the CESR (now IRAP, Toulouse, France) for the INTEGRAL mission. Above 150 keV, SPI combines a unique spectral resolution with unequalled sensitivity, being thus an ideal tool to study the high energy emission of accreting compact objects. The thesis manuscript reports on the results of timing and spectral studies of three particular systems. First, I address the high energy emission of the enigmatic micro-quasar GRS 1915+105, a source characterized by colossal luminosity and strong chaotic variability in X-rays. On a timescale of about one day, the photon index of the 20 - 200 keV spectrum varies between 2.7 and 3.5; at higher energies (≥150 keV), SPI unveils the systematic presence of an additional emission component, extending without folding energy up to ∼ 500 keV. Second, I study the high energy emission of GX 339-4, a source whose spectral properties are representative of black hole transients. The spectrum of the luminous hard state of this system shows a variable high energy tail (≥150 keV), with significant flux changes on a short timescale (several hours). I explain the

  3. Slip Zone versus Damage Zone Micromechanics, Arima-Takasuki Tectonic Line, Japan

    Science.gov (United States)

    White, J. C.; Lin, A.

    2017-12-01

    The Arima-Takasuki Tectonic Line (ATTL) of southern Honshu, Japan is defined by historically active faults and multiple splays producing M7 earthquakes. The damage zone of the ATTL comprises a broad zone of crushed, comminuted and pulverized granite/rhyolite1,2containing cm-scale slip zones and highly comminuted injection veins. In this presentation, prior work on the ATTL fault rocks is extending to include microstructural characterization by transmission electron microscopy (TEM) from recent trenching of the primary slip zone, as well as secondary slip zones. This is necessary to adequately characterize the extremely fine-grained material (typically less than 1mm) in both damage and core zones. Damage zone material exhibits generally random textures3 whereas slip zones are macroscopically foliated, and compositionally layered, notwithstanding a fairly homogeneous protolith. The latter reflects fluid-rock interaction during both coseismic and interseismic periods. The slip zones are microstructurally heterogeneous at all scales, comprising not only cataclasites and phyllosilicate (clay)-rich gouge zones, but Fe/Mn pellets or clasts that are contained within gouge. These structures appear to have rolled and would suggest rapid recrystallization and/or growth. A central question related to earthquake recurrence along existing faults is the nature of the gouge. In both near-surface exposures and ongoing drilling at depth, "plastic" or "viscous" gouge zones comprise ultra-fine-grained clay-siliciclastic particles that would not necessarily respond in a simple frictional manner. Depending on whether the plastic nature of these slip zones develops during or after slip, subsequent focusing of slip within them could be complicated. 1 Mitchell, T.A., Ben-Zion, Y., Shimamoto, T., 2011. Ear. Planet. Sci. Lett. 308, 284-297. 2 Lin, A., Yamashita, K, Tanaka, M. J., 2013. Struc. Geol. 48, 3-13. 3 White, J.C., Lin, A. 2016. Proc. AGU Fall Mtg., T42-02 San Francisco.

  4. Changes in the world rivers' discharge projected from an updated high resolution dataset of current and future climate zones

    Science.gov (United States)

    Santini, Monia; di Paola, Arianna

    2015-12-01

    In this paper, an updated global map of the current climate zoning and of its projections, according to the Köppen-Geiger classification, is first provided. The map at high horizontal resolution (0.5° × 0.5°), representative of the current (i.e. 1961-2005) conditions, is based on the Climate Research Unit dataset holding gridded series of historical observed temperature and precipitation, while projected conditions rely on the simulated series, for the same variables, by the General Circulation Model CMCC-CM. Modeled variables were corrected for their bias and then projections of climate zoning were generated for the medium term (2006-2050) and long term (2056-2100) future periods, under RCP 4.5 and RCP 8.5 emission scenarios. Results show that Equatorial and Arid climates will spread at the expenses of Snow and Polar climates, with the Warm Temperate experiencing more moderate increase. Maps of climate zones are valuable for a wide range of studies on climate change and its impacts, especially those regarding the water cycle that is strongly regulated by the combined conditions of precipitation and temperature. As example of large scale hydrological applications, in this work we tested and implemented a spatial statistical procedure, the geographically weighted regression among climate zones' surface and mean annual discharge (MAD) at hydrographic basin level, to quantify likely changes in MAD for the main world rivers monitored through the Global Runoff Data Center database. The selected river basins are representative of more than half of both global superficial freshwater resources and world's land area. Globally, a decrease in MAD is projected both in the medium term and long term, while spatial differences highlight how some areas require efforts to avoid consequences of amplified water scarcity, while other areas call for strategies to take the opportunity from the expected increase in water availability. Also the fluctuations of trends between the

  5. Very high-energy gamma-ray signature of ultrahigh-energy cosmic-ray acceleration in Centaurus A

    Science.gov (United States)

    Joshi, Jagdish C.; Miranda, Luis Salvador; Razzaque, Soebur; Yang, Lili

    2018-04-01

    The association of at least a dozen ultrahigh-energy cosmic-ray (UHECR) events with energy ≳ 55 EeV detected by the Pierre Auger Observatory (PAO) from the direction of Centaurus-A, the nearest radio galaxy, supports the scenario of UHECR acceleration in the jets of radio galaxies. In this work, we model radio to very high energy (VHE,≳ 100 GeV) γ-ray emission from Cen A, including GeV hardness detected by Fermi-LAT and TeV emission detected by HESS. We consider two scenarios: (i) Two zone synchrotron self-Compton (SSC) and external-Compton (EC) models, (ii) Two zone SSC, EC and photo-hadronic emission from cosmic ray interactions. The GeV hardness observed by Fermi-LAT can be explained using these two scenarios, where zone 2 EC emission is very important. Hadronic emission in scenario (ii) can explain VHE data with the same spectral slope as obtained through fitting UHECRs from Cen A. The peak luminosity in cosmic ray proton at 1 TeV, to explain the VHE γ-ray data is ≈2.5 × 1046 erg/s. The bolometric luminosity in cosmic ray protons is consistent with the luminosity required to explain the origin of 13 UHECR signal events that are correlated with Cen A.

  6. Los Angeles megacity: a high-resolution land–atmosphere modelling system for urban CO2 emissions

    Directory of Open Access Journals (Sweden)

    S. Feng

    2016-07-01

    Full Text Available Megacities are major sources of anthropogenic fossil fuel CO2 (FFCO2 emissions. The spatial extents of these large urban systems cover areas of 10 000 km2 or more with complex topography and changing landscapes. We present a high-resolution land–atmosphere modelling system for urban CO2 emissions over the Los Angeles (LA megacity area. The Weather Research and Forecasting (WRF-Chem model was coupled to a very high-resolution FFCO2 emission product, Hestia-LA, to simulate atmospheric CO2 concentrations across the LA megacity at spatial resolutions as fine as  ∼  1 km. We evaluated multiple WRF configurations, selecting one that minimized errors in wind speed, wind direction, and boundary layer height as evaluated by its performance against meteorological data collected during the CalNex-LA campaign (May–June 2010. Our results show no significant difference between moderate-resolution (4 km and high-resolution (1.3 km simulations when evaluated against surface meteorological data, but the high-resolution configurations better resolved planetary boundary layer heights and vertical gradients in the horizontal mean winds. We coupled our WRF configuration with the Vulcan 2.2 (10 km resolution and Hestia-LA (1.3 km resolution fossil fuel CO2 emission products to evaluate the impact of the spatial resolution of the CO2 emission products and the meteorological transport model on the representation of spatiotemporal variability in simulated atmospheric CO2 concentrations. We find that high spatial resolution in the fossil fuel CO2 emissions is more important than in the atmospheric model to capture CO2 concentration variability across the LA megacity. Finally, we present a novel approach that employs simultaneous correlations of the simulated atmospheric CO2 fields to qualitatively evaluate the greenhouse gas measurement network over the LA megacity. Spatial correlations in the atmospheric CO2 fields reflect the coverage of

  7. Modification of combustion behaviour and NO emissions by coal blending

    Energy Technology Data Exchange (ETDEWEB)

    Rubiera, Fernando; Arenillas, Ana; Arias, Borja; Pis, Jose J. [Department of Energy and Environment, Instituto Nacional del Carbon, CSIC, Apartado 73, 33080 Oviedo (Spain)

    2002-06-20

    Combustion profiles determined by TGA and experiments in a laminar entrained flow reactor (EFR) were used in this work to assess the relative combustion reactivities of different rank coals and their binary coal blends. The combustion behaviour of coal blends in TGA was greatly influenced by coal rank and the proportion of each component in the blend. Higher volatile coals exerted more influence in the low-temperature region and less reactive coals in the char combustion zone. The results in the EFR indicated that coal blends burnout and NO emissions show additivity in the case of similar nature coals. When one of the components was a high-rank coal, the burnout of the blend exhibited, in some cases, positive synergistic effects, while a clear deviation from linearity was found in NO emissions.

  8. Facile Route to Vertically Aligned High-Aspect Ratio Block Copolymer Films via Dynamic Zone Annealing

    Science.gov (United States)

    Singh, Gurpreet; Kulkarni, Manish; Yager, Kevin; Smilgies, Detlef; Bucknall, David; Karim, Alamgir

    2012-02-01

    Directed assembly of block copolymers (BCP) can be used to fabricate a diversity of nanostructures useful for nanotech applications. The ability to vertically orient etchable high aspect ratio (˜30) ordered BCP domains on flexible substrates via continuous processing methods are particularly attractive for nanomanufacturing. We apply sharp dynamic cold zone annealing (CZA-S) to create etchable, and predominantly vertically oriented 30nm cylindrical domains in 1 μm thick poly(styrene-b-methylmethacrylate) films on low thermal conductivity rigid (quartz) and flexible (PDMS & Kapton) substrates. Under similar static conditions, temporally stable vertical cylinders form within a narrow zone above a critical temperature gradient. Primary ordering mechanism of CZA-S involves sweeping this vertically orienting zone created at maximum thermal gradient. An optimal speed is needed since the process competes with preferential surface wetting dynamics that favors parallel orientation. GISAXS of etched BCP films confirms internal morphology.

  9. Soil monitoring in agro-ecosystems of high mountain zone in Quindio

    International Nuclear Information System (INIS)

    Sadeghian, Siavosh; Orozco, O l; Murgueitio, E

    2001-01-01

    Were evaluated soil characteristics in 4 common agro-ecosystems of high mountain zone of Quindio department, soil forest exhibit better indicators that others systems. Low macro porosity and hydraulic conductivity were consequences more important of cattle ranching systems. In pinus plantations were registered lower value of organic matter, pH, interchanging bases, gravimetric moisture and microbial activity CO 2 . As a result of pinus establishment on pasture ground increase drainable porosity and hydraulic conductivity. In granadilla cultivation were lower organism diversity and structural stability

  10. Geochemical evolution of highly alkaline and saline tank waste plumes during seepage through vadose zone sediments

    International Nuclear Information System (INIS)

    Wan, Jiamin; Tokunaga, Tetsu K.; Larsen, Joern T.; Serne, R. JEFFREY

    2004-01-01

    Leakage of highly saline and alkaline radioactive waste from storage tanks into underlying sediments is a serious environmental problem at the Hanford Site in Washington State. This study focuses on geochemical evolution of tank waste plumes resulting from interactions between the waste solution and sediment. A synthetic tank waste solution was infused into unsaturated Hanford sediment columns (0.2, 0.6, and 2 m) maintained at 70C to simulate the field contamination process. Spatially and temporally resolved geochemical profiles of the waste plume were obtained. Thorough OH neutralization (from an initial pH 14 down to 6.3) was observed. Three broad zones of pore solutions were identified to categorize the dominant geochemical reactions: the silicate dissolution zone (pH > 10), pH-neutralized zone (pH 10 to 6.5), and displaced native sediment pore water (pH 6.5 to 8). Elevated concentrations of Si, Fe, and K in plume fluids and their depleted concentrations in plume sediments reflected dissolution of primary minerals within the silicate dissolution zone. The very high Na concentrations in the waste solution resulted in rapid and complete cation exchange, reflected in high concentrations of Ca and Mg at the plume front. The plume-sediment profiles also showed deposition of hydrated solids and carbonates. Fair correspondence was obtained between these results and analyses of field borehole samples from a waste plume at the Hanford Site. Results of this study provide a well-defined framework for understanding waste plumes in the more complex field setting and for understanding geochemical factors controlling transport of contaminant species carried in waste solutions that leaked from single-shell storage tanks in the past

  11. Dynamical evolution of space debris on high-elliptical orbits near high-order resonance zones

    Science.gov (United States)

    Kuznetsov, Eduard; Zakharova, Polina

    Orbital evolution of objects on Molniya-type orbits is considered near high-order resonance zones. Initial conditions correspond to high-elliptical orbits with the critical inclination 63.4 degrees. High-order resonances are analyzed. Resonance orders are more than 5 and less than 50. Frequencies of perturbations caused by the effect of sectorial and tesseral harmonics of the Earth's gravitational potential are linear combinations of the mean motion of a satellite, angular velocities of motion of the pericenter and node of its orbit, and the angular velocity of the Earth. Frequencies of perturbations were calculated by taking into account secular perturbations from the Earth oblateness, the Moon, the Sun, and a solar radiation pressure. Resonance splitting effect leads to three sub-resonances. The study of dynamical evolution on long time intervals was performed on the basis of the results of numerical simulation. We used "A Numerical Model of the Motion of Artificial Earth's Satellites", developed by the Research Institute of Applied Mathematics and Mechanics of the Tomsk State University. The model of disturbing forces taken into account the main perturbing factors: the gravitational field of the Earth, the attraction of the Moon and the Sun, the tides in the Earth’s body, the solar radiation pressure, taking into account the shadow of the Earth, the Poynting-Robertson effect, and the atmospheric drag. Area-to-mass ratio varied from small values corresponding to satellites to big ones corresponding to space debris. The locations and sizes of resonance zones were refined from numerical simulation. The Poynting-Robertson effect results in a secular decrease in the semi-major axis of a spherically symmetrical satellite. In resonance regions the effect weakens slightly. Reliable estimates of secular perturbations of the semi-major axis were obtained from the numerical simulation. Under the Poynting-Robertson effect objects pass through the regions of high

  12. Chemically and size-resolved particulate matter dry deposition on stone and surrogate surfaces inside and outside the low emission zone of Milan: application of a newly developed "Deposition Box".

    Science.gov (United States)

    Ferrero, Luca; Casati, Marco; Nobili, Lara; D'Angelo, Luca; Rovelli, Grazia; Sangiorgi, Giorgia; Rizzi, Cristiana; Perrone, Maria Grazia; Sansonetti, Antonio; Conti, Claudia; Bolzacchini, Ezio; Bernardi, Elena; Vassura, Ivano

    2018-04-01

    The collection of atmospheric particles on not-filtering substrates via dry deposition, and the subsequent study of the particle-induced material decay, is trivial due to the high number of variables simultaneously acting on the investigated surface. This work reports seasonally resolved data of chemical composition and size distribution of particulate matter deposed on stone and surrogate surfaces obtained using a new method, especially developed at this purpose. A "Deposition Box" was designed allowing the particulate matter dry deposition to occur selectively removing, at the same time, variables that can mask the effect of airborne particles on material decay. A pitched roof avoided rainfall and wind variability; a standardised gentle air exchange rate ensured a continuous "sampling" of ambient air leaving unchanged the sampled particle size distribution and, at the same time, leaving quite calm condition inside the box, allowing the deposition to occur. Thus, the "Deposition Box" represents an affordable tool that can be used complementary to traditional exposure systems. With this system, several exposure campaigns, involving investigated stone materials (ISMs) (Carrara Marble, Botticino limestone, Noto calcarenite and Granite) and surrogate (Quartz, PTFE, and Aluminium) substrates, have been performed in two different sites placed in Milan (Italy) inside and outside the low emission zone. Deposition rates (30-90 μg cm -2  month -1 ) showed significant differences between sites and seasons, becoming less evident considering long-period exposures due to a positive feedback on the deposition induced by the deposited particles. Similarly, different stone substrates influenced the deposition rates too. The collected deposits have been observed with optical and scanning electron microscopes and analysed by ion chromatography. Ion deposition rates were similar in the two sites during winter, whereas it was greater outside the low emission zone during summer and

  13. The assessment of waters ecological state of the Crimea coastal near high-rise construction zones

    Science.gov (United States)

    Vetrova, Natalya; Ivanenko, Tatyana; Mannanov, Emran

    2018-03-01

    The relevance of our study is determined by the significant level of coastal sea waters pollution by sewage near high-rise construction zones, which determines the violation of the sanitary and hygienic of sea waters `characteristics and limits the possibilities for organizing recreational activities. The purpose of this study is to identify the ecological state of the marine aquatic area by the example of the Western Crimea near high-rise construction zones. The studies confirmed that the recreational and coastal area wastewater is intensely mixed with seawater, as a result, the pollution in the coastal strip of the sea in the area of deep water discharges sharply decrease. This happens because of water rapid rise to the surface and under the influence of the continuous movement of sea water huge masses with deep-water discharge, fresh wastewater is actively mixed with sea water. However, with no doubt, it is inadmissible to discharge sewage into the sea directly from the shore, but only at the estimated distance from the coast. The materials of the article can be useful for the management bodies and organizations involved in monitoring the quality of the coastal zone of the sea, teachers and students of higher educational institutions when assessing the ecological situation of the territories.

  14. Bursts of the Crab Nebula gamma-ray emission at high and ultra-high energies

    Directory of Open Access Journals (Sweden)

    Lidvansky A.S.

    2017-01-01

    Full Text Available Characteristics of the flares of gamma rays detected from the Crab Nebula by the AGILE and Fermi-LAT satellite instruments are compared with those of a gamma ray burst recorded by several air shower arrays on February 23, 1989 and with one recent observation made by the ARGO-YBJ array. It is demonstrated that though pulsar-periodicity and energy spectra of emissions at 100 MeV (satellite gamma ray telescopes and 100 TeV (EAS arrays are different, their time structures seem to be similar. Moreover, maybe the difference between “flares” and “waves” recently found in the Crab Nebula emission by the AGILE team also exists at ultra-high energies.

  15. Assessment of nitrogen oxide emission for designing boilers fired with coal dust

    Energy Technology Data Exchange (ETDEWEB)

    Kotler, V.R.; Gusev, L.N.; Babii, V.I.

    1983-09-01

    A method for forecasting emission of nitrogen oxides from steam boilers fired with coal is described. The method produces accurate results when nitrogen oxide emission from furnaces with straight-flow burners and turbulent-type burners fired with coal dusts is forecast. Oxides formed by decomposition of chemical compounds in coal (so-called 'fuel' nitrogen oxides) and nitrogen oxides formed by oxidation of molecular nitrogen by atomic oxygen (so-called 'thermal' nitrogen oxides) are evaluated. Zones in which the two types of nitrogen oxide are formed in flames are characterized. Factors which influence formation of nitrogen oxides in a furnace are evaluated: excess air, flue gas recirculation, design of a furnace and burners, movement of air and coal dust mixture in a furnace, temperature, methods for coal dust preparation, coal dust properties. Equations for forecasting emission of nitrogen oxides from furnaces are derived. Nomograms for easy calculation of emission are also given. Examples of using the method for forecasting emission of nitrogen oxides from furnaces fired with coal from the Kuzbass, the Donbass and Ehkibastuz are discussed. Comparisons of emission of nitrogen oxides calculated on the basis of the method and emission determined experimentally show that forecasting accuracy is high and errors do not exceed 10%. 5 references.

  16. An experimental study on the effects of high-pressure and multiple injection strategies on DI diesel engine emissions

    KAUST Repository

    Yang, Seung Yeon

    2013-03-25

    An experimental study on effects of high-pressure injections in conjunction with split fuel injections were conducted on an AVL single cylinder DI diesel engine. Various injection schemes were studied through the use of an electronically controlled, common rail injection system capable of injection pressures up to 200 MPa and a maximum of six injections per combustion event. Up to 100 MPa of the fuel injection pressure, the higher injection pressures create faster combustion rates that result in the higher in-cylinder gas temperatures as compared to conventional low-pressure fuel injection systems. When applying high-pressure injections, particulate emission reductions of up to 50% were observed with no change in hydrocarbon emissions, reductions of CO emissions and only slightly higher NOx emissions. Over 100 MPa, on the other hand, the higher injection pressures still reduced up to almost zero-level of particulate emission, at the same time that the NO emission is reduced greatly. Under these high-pressure injection conditions, strong correlations between soot and CO emissions were observed, which compete for the oxidizing OH species. Multiple or split high-pressure injections also investigated as a means to decrease particulate emissions. As a result, a four-split injection strategy resulted in a 55% reduction in particulates and with little or no penalty on NOx emissions. The high pressure split injection strategy with EGR was more effective in reducing particulate and CO emissions simultaneously. Copyright © 2013 SAE International and Copyright © 2013 TSAE.

  17. Technology Roadmap: High-Efficiency, Low-Emissions Coal-Fired Power Generation

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    2012-07-01

    Coal is the largest source of power globally and, given its wide availability and relatively low cost, it is likely to remain so for the foreseeable future. The High-Efficiency, Low-Emissions Coal-Fired Power Generation Roadmap describes the steps necessary to adopt and further develop technologies to improve the efficiency of the global fleet of coal. To generate the same amount of electricity, a more efficient coal-fired unit will burn less fuel, emit less carbon, release less local air pollutants, consume less water and have a smaller footprint. High-efficiency, low emissions (HELE) technologies in operation already reach a thermal efficiency of 45%, and technologies in development promise even higher values. This compares with a global average efficiency for today’s fleet of coal-fired plants of 33%, where three-quarters of operating units use less efficient technologies and more than half is over 25 years old. A successful outcome to ongoing RD&D could see units with efficiencies approaching 50% or even higher demonstrated within the next decade. Generation from older, less efficient technology must gradually be phased out. Technologies exist to make coal-fired power generation much more effective and cleaner burning. Of course, while increased efficiency has a major role to play in reducing emissions, particularly over the next 10 years, carbon capture and storage (CCS) will be essential in the longer term to make the deep cuts in carbon emissions required for a low-carbon future. Combined with CCS, HELE technologies can cut CO2 emissions from coal-fired power generation plants by as much as 90%, to less than 100 grams per kilowatt-hour. HELE technologies will be an influential factor in the deployment of CCS. For the same power output, a higher efficiency coal plant will require less CO2 to be captured; this means a smaller, less costly capture plant; lower operating costs; and less CO2 to be transported and stored.

  18. The impact of biogenic VOC emissions on photochemical ozone formation during a high ozone pollution episode in the Iberian Peninsula in the 2003 summer season

    Directory of Open Access Journals (Sweden)

    N. Castell

    2008-04-01

    Full Text Available Throughout Europe the summer of 2003 was exceptionally warm, especially July and August. The European Environment Agency (EEA reported several ozone episodes, mainly in the first half of August. These episodes were exceptionally long-lasting, spatially extensive, and associated to high temperatures. In this paper, the 10$ndash;15 August 2003 ozone pollution event has been analyzed using meteorological and regional air quality modelling. During this period the threshold values of the European Directive 2002/3/EC were exceeded in various areas of the Iberian Peninsula.

    The aim of this paper is to computationally understand and quantify the influence of biogenic volatile organic compound (BVOC emissions in the formation of tropospheric ozone during this high ozone episode. Being able to differentiate how much ozone comes from biogenic emissions alone and how much comes from the interaction between anthropogenic and biogenic emissions would be helpful to develop a feasible and effective ozone control strategy. The impact on ozone formation was also studied in combination with various anthropogenic emission reduction strategies, i.e., when anthropogenic VOC emissions and/or NOx emissions are reduced. The results show a great dependency of the BVOC contribution to ozone formation on the antropoghenic reduction scenario. In rural areas, the impact due to a NOx and/or VOC reduction does not change the BVOC impact. Nevertheless, within big cities or industrial zones, a NOx reduction results in a decrease of the biogenic impact in ozone levels that can reach 85 μg/m3, whereas an Anthropogenic Volatile Organic Compound (AVOC reduction results in a decrease of the BVOC contribution on ozone formation that varies from 0 to 30 μg/m3 with respect to the contribution at the same points in the 2003 base scenario. On the other hand, downwind of the big cities, a decrease in NOx produces

  19. Ion induced high energy electron emission from copper

    International Nuclear Information System (INIS)

    Ruano, G.; Ferron, J.

    2008-01-01

    We present measurements of secondary electron emission from Cu induced by low energy bombardment (1-5 keV) of noble gas (He + , Ne + and Ar + ) and Li + ions. We identify different potential and kinetic mechanisms and find the presence of high energetic secondary electrons for a couple of ion-target combinations. In order to understand the presence of these fast electrons we need to consider the Fermi shuttle mechanism and the different ion neutralization efficiencies.

  20. High resolution of black carbon and organic carbon emissions in the Pearl River Delta region, China.

    Science.gov (United States)

    Zheng, Junyu; He, Min; Shen, Xingling; Yin, Shasha; Yuan, Zibing

    2012-11-01

    A high-resolution regional black carbon (BC) and organic carbon (OC) emission inventory for the year 2009 was developed for the Pearl River Delta (PRD) region, China, based on the collected activity data and the latest emission factors. PM(2.5), BC and OC emissions were estimated to be 303 kt, 39 kt and 31 kt, respectively. Industrial processes were major contributing sources to PM(2.5) emissions. BC emissions were mainly from mobile sources, accounting for 65.0%, while 34.1% of OC emissions were from residential combustion. The primary OC/BC ratios for individual cities in the PRD region were dependent on the levels of economic development due to differences in source characteristics, with high ratios in the less developed cities and low ratios in the central and southern developed areas. The preliminary temporal profiles were established, showing the highest OC emissions in winter and relatively constant BC emissions throughout the year. The emissions were spatially allocated into grid cells with a resolution of 3 km × 3 km. Large amounts of BC emissions were distributed over the central-southern PRD city clusters, while OC emissions exhibited a relatively even spatial distribution due to the significant biomass burning emissions from the outlying area of the PRD region. Uncertainties in carbonaceous aerosol emissions were usually higher than in other primary pollutants like SO(2), NO(x), and PM(10). One of the key uncertainty sources was the emission factor, due to the absence of direct measurements of BC and OC emission rates. Copyright © 2012 Elsevier B.V. All rights reserved.

  1. Very high energy emission sources beyond the Galaxy

    Directory of Open Access Journals (Sweden)

    Sinitsyna V.G.

    2017-01-01

    Full Text Available Active Galactic Nuclei (AGN are considered as potential extragalactic sources of very and ultra high energy cosmic rays. According to theoretical predictions cosmic ray acceleration can take place at the shock created by the expanding cocoons around active galactic nuclei as well as at AGN jets. The measurements of AGN TeV spectra, the variability time scale of TeV emission can provide essential information on the dynamics of AGN jets, the localization of acceleration region and an estimation of its size. SHALON observations yielded data on extragalactic sources of different AGN types in the energy range of 800 GeV–100 TeV. The data from SHALON observations are compared with those from other experiments at high and very high energies.

  2. Efficient light emitting devices based on phosphorescent partially doped emissive layers

    KAUST Repository

    Yang, Xiaohui

    2013-05-29

    We report efficient organic light emitting devices employing an ultrathin phosphor emissive layer. The electroluminescent spectra of these devices can be tuned by introducing a low-energy emitting phosphor layer into the emission zone. Devices with the emissive layer consisting of multiple platinum-complex/spacer layer cells show a peak external quantum efficiency of 18.1%, which is among the best EQE values for platinum-complex based light emitting devices. Devices with an ultrathin phosphor emissive layer show stronger luminance decay with the operating time compared to the counterpart devices having a host-guest emissive layer.

  3. Real-time, high frequency QRS electrocardiograph with reduced amplitude zone detection

    Science.gov (United States)

    Schlegel, Todd T. (Inventor); DePalma, Jude L. (Inventor); Moradi, Saeed (Inventor)

    2009-01-01

    Real time cardiac electrical data are received from a patient, manipulated to determine various useful aspects of the ECG signal, and displayed in real time in a useful form on a computer screen or monitor. The monitor displays the high frequency data from the QRS complex in units of microvolts, juxtaposed with a display of conventional ECG data in units of millivolts or microvolts. The high frequency data are analyzed for their root mean square (RMS) voltage values and the discrete RMS values and related parameters are displayed in real time. The high frequency data from the QRS complex are analyzed with imbedded algorithms to determine the presence or absence of reduced amplitude zones, referred to herein as ''RAZs''. RAZs are displayed as ''go, no-go'' signals on the computer monitor. The RMS and related values of the high frequency components are displayed as time varying signals, and the presence or absence of RAZs may be similarly displayed over time.

  4. Key issues of ultraviolet radiation of OH at high altitudes

    Energy Technology Data Exchange (ETDEWEB)

    Zhang, Yuhuai; Wan, Tian; Jiang, Jianzheng; Fan, Jing [State Key Laboratory of High Temperature Gasdynamics, Institute of Mechanics, Chinese Academy of Sciences, Beijing 100190 (China)

    2014-12-09

    Ultraviolet (UV) emissions radiated by hydroxyl (OH) is one of the fundamental elements in the prediction of radiation signature of high-altitude and high-speed vehicle. In this work, the OH A{sup 2}Σ{sup +}→X{sup 2}Π ultraviolet emission band behind the bow shock is computed under the experimental condition of the second bow-shock ultraviolet flight (BSUV-2). Four related key issues are discussed, namely, the source of hydrogen element in the high-altitude atmosphere, the formation mechanism of OH species, efficient computational algorithm of trace species in rarefied flows, and accurate calculation of OH emission spectra. Firstly, by analyzing the typical atmospheric model, the vertical distributions of the number densities of different species containing hydrogen element are given. According to the different dominating species containing hydrogen element, the atmosphere is divided into three zones, and the formation mechanism of OH species is analyzed in the different zones. The direct simulation Monte Carlo (DSMC) method and the Navier-Stokes equations are employed to compute the number densities of the different OH electronically and vibrationally excited states. Different to the previous work, the trace species separation (TSS) algorithm is applied twice in order to accurately calculate the densities of OH species and its excited states. Using a non-equilibrium radiation model, the OH ultraviolet emission spectra and intensity at different altitudes are computed, and good agreement is obtained with the flight measured data.

  5. New experimental device for high-temperature normal spectral emissivity measurements of coatings

    International Nuclear Information System (INIS)

    Honnerová, Petra; Martan, Jiří; Kučera, Martin; Honner, Milan; Hameury, Jacques

    2014-01-01

    A new experimental device for normal spectral emissivity measurements of coatings in the infrared spectral range from 1.38 μm to 26 μm and in the temperature range from 550 K to 1250 K is presented. A Fourier transform infrared spectrometer (FTIR) is used for the detection of sample and blackbody spectral radiation. Sample heating is achieved by a fiber laser with a scanning head. Surface temperature is measured by two methods. The first method uses an infrared camera and a reference coating with known effective emissivity, the second method is based on the combination of Christiansen wavelength with contact and noncontact surface temperature measurement. Application of the method is shown on the example of a high-temperature high-emissivity coating. Experimental results obtained with this apparatus are compared with the results performed by a direct method of Laboratoire National d’Essais (LNE) in France. The differences in the spectra are analyzed. (paper)

  6. High-resolution PET [Positron Emission Tomography] for Medical Science Studies

    Science.gov (United States)

    Budinger, T. F.; Derenzo, S. E.; Huesman, R. H.; Jagust, W. J.; Valk, P. E.

    1989-09-01

    One of the unexpected fruits of basic physics research and the computer revolution is the noninvasive imaging power available to today's physician. Technologies that were strictly the province of research scientists only a decade or two ago now serve as the foundations for such standard diagnostic tools as x-ray computer tomography (CT), magnetic resonance imaging (MRI), magnetic resonance spectroscopy (MRS), ultrasound, single photon emission computed tomography (SPECT), and positron emission tomography (PET). Furthermore, prompted by the needs of both the practicing physician and the clinical researcher, efforts to improve these technologies continue. This booklet endeavors to describe the advantages of achieving high resolution in PET imaging.

  7. NOx Emissions Performance and Correlation Equations for a Multipoint LDI Injector

    Science.gov (United States)

    He, Zhuohui J.; Chang, Clarence T.; Follen, Caitlin E.

    2015-01-01

    Lean Direct Injection (LDI) is a combustor concept that reduces nitrogen oxides (NOx) emissions. This paper looks at a 3-zone multipoint LDI concept developed by Parker Hannifin Corporation. The concept was tested in a flame-tube test facility at NASA Glenn Research Center. Due to test facility limitations, such as inlet air temperature and pressure, the flame-tube test was not able to cover the full set of engine operation conditions. Three NOx correlation equations were developed based on assessing NOx emissions dependencies on inlet air pressure (P3), inlet air temperature (T3), and fuel air equivalence ratio (?) to estimate the NOx emissions at the unreachable high engine power conditions. As the results, the NOx emissions are found to be a strong function of combustion inlet air temperature and fuel air equivalence ratio but a weaker function of inlet air pressure. With these three equations, the NOx emissions performance of this injector concept is calculated as a 66% reduction relative to the ICAO CAEP-6 standard using a 55:1 pressure-ratio engine cycle. Uncertainty in the NOx emissions estimation increases as the extrapolation range departs from the experimental conditions. Since maximum inlet air pressure tested was less than 50% of the full power engine inlet air pressure, a future experiment at higher inlet air pressure conditions is needed to confirm the NOx emissions dependency on inlet air pressure.

  8. Quantitative estimation of viable myocardium in the infarcted zone by infarct-redistribution map from images of exercise thallium-201 emission computed tomography

    International Nuclear Information System (INIS)

    Sekiai, Yasuhiro

    1988-01-01

    To evaluate, quantitatively, the viable myocardium in the infarcted zone, we invented the infarct-redistribution map which is produced from images of exercise thallium-201 emission computed tomography performed on 10 healthy subjects and 20 patients with myocardial infarction. The map displayed a left ventricle in which the infarcted area both with and without redistribution, the redistribution area without infarction, and normal perfusion area were shown separated in same screen. In these circumstances, the nonredistribution infarct lesion was found as being surrounded by the redistribution area. Indices of infarct and redistribution extent (defect score, % defect, redistribution ratio (RR) and redistribution index (RI)), were induced from the map and were used for quantitative analysis of the redistribution area and as the basis for comparative discussion regarding regional wall motion of the left ventricle. The quantitative indices of defect score, % defect, RR and RI were consistent with the visual assessment of planar images in detecting the extent of redistribution. Furthermore, defect score and % defect had an inverted linear relationship with % shortening (r = -0.573; p < 0.05, r = -0.536; p < 0.05, respectively), and RI had a good linear relationship with % shortening (r = 0.669; p < 0.01). We conclude that the infarct-redistribution map accurately reflects the myocardial viability and therefore may be useful for quantitative estimation of viable myocardium in the infarcted zone. (author)

  9. Impurity line emission due to thermal charge exchange in JET edge plasmas

    Energy Technology Data Exchange (ETDEWEB)

    Maggi, C F; Horton, L D; Koenig, R; Stamp, M [Commission of the European Communities, Abingdon (United Kingdom). JET Joint Undertaking; Summers, H P [Strathclyde Univ., Glasgow (United Kingdom)

    1994-07-01

    High n-shell emission from hydrogen-like carbon (C VI, n=8-7) has been routinely observed from the plasma edge of JET. By comparing the measured spectral line intensities with the signals predicted by advanced atomic physics modelling of carbon and hydrogen radiation, integrated with modelling of the divertor and edge plasma, it is concluded that charge transfer from excited state hydrogen donors into fully stripped carbon ions can account for the observed spectral emission, but that the hydrogen distribution and to a lesser extent the carbon distribution away from the strike zone predicted by the transport model are too low. Data presented are those of three upper X-point discharges, where the target material was carbon. 5 refs., 1 fig., 3 tabs.

  10. Unexpected high-energy γ emission from decaying exotic nuclei

    Directory of Open Access Journals (Sweden)

    A. Gottardo

    2017-09-01

    Full Text Available The N=52 Ga83 β decay was studied at ALTO. The radioactive 83Ga beam was produced through the ISOL photofission technique and collected on a movable tape for the measurement of γ-ray emission following β decay. While β-delayed neutron emission has been measured to be 56–85% of the decay path, in this experiment an unexpected high-energy 5–9 MeV γ-ray yield of 16(4% was observed, coming from states several MeVs above the neutron separation threshold. This result is compared with cutting-edge QRPA calculations, which show that when neutrons deeply bound in the core of the nucleus decay into protons via a Gamow–Teller transition, they give rise to a dipolar oscillation of nuclear matter in the nucleus. This leads to large electromagnetic transition probabilities which can compete with neutron emission, thus affecting the β-decay path. This process is enhanced by an excess of neutrons on the nuclear surface and may thus be a common feature for very neutron-rich isotopes, challenging the present understanding of decay properties of exotic nuclei.

  11. Soil water content drives spatiotemporal patterns of CO2 and N2O emissions from a Mediterranean riparian forest soil

    Directory of Open Access Journals (Sweden)

    S. Poblador

    2017-09-01

    Full Text Available Riparian zones play a fundamental role in regulating the amount of carbon (C and nitrogen (N that is exported from catchments. However, C and N removal via soil gaseous pathways can influence local budgets of greenhouse gas (GHG emissions and contribute to climate change. Over a year, we quantified soil effluxes of carbon dioxide (CO2 and nitrous oxide (N2O from a Mediterranean riparian forest in order to understand the role of these ecosystems on catchment GHG emissions. In addition, we evaluated the main soil microbial processes that produce GHG (mineralization, nitrification, and denitrification and how changes in soil properties can modify the GHG production over time and space. Riparian soils emitted larger amounts of CO2 (1.2–10 g C m−2 d−1 than N2O (0.001–0.2 mg N m−2 d−1 to the atmosphere attributed to high respiration and low denitrification rates. Both CO2 and N2O emissions showed a marked (but antagonistic spatial gradient as a result of variations in soil water content across the riparian zone. Deep groundwater tables fueled large soil CO2 effluxes near the hillslope, while N2O emissions were higher in the wet zones adjacent to the stream channel. However, both CO2 and N2O emissions peaked after spring rewetting events, when optimal conditions of soil water content, temperature, and N availability favor microbial respiration, nitrification, and denitrification. Overall, our results highlight the role of water availability on riparian soil biogeochemistry and GHG emissions and suggest that climate change alterations in hydrologic regimes can affect the microbial processes that produce GHG as well as the contribution of these systems to regional and global biogeochemical cycles.

  12. Nitrous oxide emission hotspots and acidic soil denitrification in a riparian buffer zone

    NARCIS (Netherlands)

    van den Heuvel, R.N.

    2010-01-01

    Nitrous oxide (N2O) is a greenhouse gas with a global warming potential of 296 CO2 equivalents and is involved in the depletion of the ozone layer. Through studies on emission sources it was revealed that natural and agricultural soils are important sources of N2O emissions and are responsible for

  13. Emission of high-energy, light particles from intermediate-energy heavy-ion reactions

    International Nuclear Information System (INIS)

    Ball, J.B.; Auble, R.L.

    1982-01-01

    One of the early surprises in examining reaction products from heavy ion reactions at 10 MeV/nucleon and above was the large yield of light particles emitted and the high energies to which the spectra of these particles extended. The interpretation of the origin of the high energy light ions has evolved from a picture of projectile excitation and subsequent evaporation to one of pre-equilibrium (or nonequilibrium) emission. The time scale for particle emission has thus moved from one that occurs following the initial collision to one that occurs at the very early stages of the collision. Research at ORNL on this phenomenon is reviewed

  14. A Strong Limit on the Very-high-energy Emission from GRB 150323A

    Science.gov (United States)

    Abeysekara, A. U.; Archer, A.; Benbow, W.; Bird, R.; Brose, R.; Buchovecky, M.; Bugaev, V.; Connolly, M. P.; Cui, W.; Errando, M.; Falcone, A.; Feng, Q.; Finley, J. P.; Flinders, A.; Fortson, L.; Furniss, A.; Gillanders, G. H.; Hütten, M.; Hanna, D.; Hervet, O.; Holder, J.; Hughes, G.; Humensky, T. B.; Johnson, C. A.; Kaaret, P.; Kar, P.; Kelley-Hoskins, N.; Kertzman, M.; Kieda, D.; Krause, M.; Krennrich, F.; Lang, M. J.; Lin, T. T. Y.; Maier, G.; McArthur, S.; Moriarty, P.; Mukherjee, R.; O’Brien, S.; Ong, R. A.; Park, N.; Perkins, J. S.; Petrashyk, A.; Pohl, M.; Popkow, A.; Pueschel, E.; Quinn, J.; Ragan, K.; Reynolds, P. T.; Richards, G. T.; Roache, E.; Rulten, C.; Sadeh, I.; Santander, M.; Sembroski, G. H.; Shahinyan, K.; Tyler, J.; Wakely, S. P.; Weiner, O. M.; Weinstein, A.; Wells, R. M.; Wilcox, P.; Wilhelm, A.; Williams, D. A.; Zitzer, B.; VERITAS Collaboration; Vurm, Indrek; Beloborodov, Andrei

    2018-04-01

    On 2015 March 23, the Very Energetic Radiation Imaging Telescope Array System (VERITAS) responded to a Swift-Burst Alert Telescope (BAT) detection of a gamma-ray burst, with observations beginning 270 s after the onset of BAT emission, and only 135 s after the main BAT emission peak. No statistically significant signal is detected above 140 GeV. The VERITAS upper limit on the fluence in a 40-minute integration corresponds to about 1% of the prompt fluence. Our limit is particularly significant because the very-high-energy (VHE) observation started only ∼2 minutes after the prompt emission peaked, and Fermi-Large Area Telescope observations of numerous other bursts have revealed that the high-energy emission is typically delayed relative to the prompt radiation and lasts significantly longer. Also, the proximity of GRB 150323A (z = 0.593) limits the attenuation by the extragalactic background light to ∼50% at 100–200 GeV. We conclude that GRB 150323A had an intrinsically very weak high-energy afterglow, or that the GeV spectrum had a turnover below ∼100 GeV. If the GRB exploded into the stellar wind of a massive progenitor, the VHE non-detection constrains the wind density parameter to be A ≳ 3 × 1011 g cm‑1, consistent with a standard Wolf–Rayet progenitor. Alternatively, the VHE emission from the blast wave would be weak in a very tenuous medium such as the interstellar medium, which therefore cannot be ruled out as the environment of GRB 150323A.

  15. H.E.S.S. discovery of very high energy γ-ray emission from PKS 0625-354

    Science.gov (United States)

    H.E.S.S. Collaboration; Abdalla, H.; Abramowski, A.; Aharonian, F.; Ait Benkhali, F.; Akhperjanian, A. G.; Andersson, T.; Angüner, E. O.; Arrieta, M.; Aubert, P.; Backes, M.; Balzer, A.; Barnard, M.; Becherini, Y.; Becker Tjus, J.; Berge, D.; Bernhard, S.; Bernlöhr, K.; Blackwell, R.; Böttcher, M.; Boisson, C.; Bolmont, J.; Bordas, P.; Bregeon, J.; Brun, F.; Brun, P.; Bryan, M.; Bulik, T.; Capasso, M.; Carr, J.; Casanova, S.; Cerruti, M.; Chakraborty, N.; Chalme-Calvet, R.; Chaves, R. C. G.; Chen, A.; Chevalier, J.; Chrétien, M.; Colafrancesco, S.; Cologna, G.; Condon, B.; Conrad, J.; Cui, Y.; Davids, I. D.; Decock, J.; Degrange, B.; Deil, C.; Devin, J.; deWilt, P.; Dirson, L.; Djannati-Ataï, A.; Domainko, W.; Donath, A.; Drury, L. O'C.; Dubus, G.; Dutson, K.; Dyks, J.; Dyrda, M.; Edwards, T.; Egberts, K.; Eger, P.; Ernenwein, J.-P.; Eschbach, S.; Farnier, C.; Fegan, S.; Fernandes, M. V.; Fiasson, A.; Fontaine, G.; Förster, A.; Funk, S.; Füßling, M.; Gabici, S.; Gajdus, M.; Gallant, Y. A.; Garrigoux, T.; Giavitto, G.; Giebels, B.; Glicenstein, J. F.; Gottschall, D.; Goyal, A.; Grondin, M.-H.; Hadasch, D.; Hahn, J.; Haupt, M.; Hawkes, J.; Heinzelmann, G.; Henri, G.; Hermann, G.; Hervet, O.; Hinton, J. A.; Hofmann, W.; Hoischen, C.; Holler, M.; Horns, D.; Ivascenko, A.; Jacholkowska, A.; Jamrozy, M.; Janiak, M.; Jankowsky, D.; Jankowsky, F.; Jingo, M.; Jogler, T.; Jouvin, L.; Jung-Richardt, I.; Kastendieck, M. A.; Katarzyński, K.; Katz, U.; Kerszberg, D.; Khélifi, B.; Kieffer, M.; King, J.; Klepser, S.; Klochkov, D.; Kluźniak, W.; Kolitzus, D.; Komin, Nu; Kosack, K.; Krakau, S.; Kraus, M.; Krayzel, F.; Krüger, P. P.; Laffon, H.; Lamanna, G.; Lau, J.; Lees, J.-P.; Lefaucheur, J.; Lefranc, V.; Lemière, A.; Lemoine-Goumard, M.; Lenain, J.-P.; Leser, E.; Lohse, T.; Lorentz, M.; Liu, R.; López-Coto, R.; Lypova, I.; Marandon, V.; Marcowith, A.; Mariaud, C.; Marx, R.; Maurin, G.; Maxted, N.; Mayer, M.; Meintjes, P. J.; Meyer, M.; Mitchell, A. M. W.; Moderski, R.; Mohamed, M.; Mohrmann, L.; Morâ, K.; Moulin, E.; Murach, T.; de Naurois, M.; Niederwanger, F.; Niemiec, J.; Oakes, L.; O'Brien, P.; Odaka, H.; Öttl, S.; Ohm, S.; Ostrowski, M.; Oya, I.; Padovani, M.; Panter, M.; Parsons, R. D.; Pekeur, N. W.; Pelletier, G.; Perennes, C.; Petrucci, P.-O.; Peyaud, B.; Piel, Q.; Pita, S.; Poon, H.; Prokhorov, D.; Prokoph, H.; Pühlhofer, G.; Punch, M.; Quirrenbach, A.; Raab, S.; Reimer, A.; Reimer, O.; Renaud, M.; de los Reyes, R.; Rieger, F.; Romoli, C.; Rosier-Lees, S.; Rowell, G.; Rudak, B.; Rulten, C. B.; Sahakian, V.; Salek, D.; Sanchez, D. A.; Santangelo, A.; Sasaki, M.; Schlickeiser, R.; Schüssler, F.; Schulz, A.; Schwanke, U.; Schwemmer, S.; Settimo, M.; Seyffert, A. S.; Shafi, N.; Shilon, I.; Simoni, R.; Sol, H.; Spanier, F.; Spengler, G.; Spies, F.; Stawarz, Ł.; Steenkamp, R.; Stegmann, C.; Stinzing, F.; Stycz, K.; Sushch, I.; Tavernet, J.-P.; Tavernier, T.; Taylor, A. M.; Terrier, R.; Tibaldo, L.; Tiziani, D.; Tluczykont, M.; Trichard, C.; Tuffs, R.; Uchiyama, Y.; van der Walt, D. J.; van Eldik, C.; van Rensburg, C.; van Soelen, B.; Vasileiadis, G.; Veh, J.; Venter, C.; Viana, A.; Vincent, P.; Vink, J.; Voisin, F.; Völk, H. J.; Vuillaume, T.; Wadiasingh, Z.; Wagner, S. J.; Wagner, P.; Wagner, R. M.; White, R.; Wierzcholska, A.; Willmann, P.; Wörnlein, A.; Wouters, D.; Yang, R.; Zabalza, V.; Zaborov, D.; Zacharias, M.; Zanin, R.; Zdziarski, A. A.; Zech, A.; Zefi, F.; Ziegler, A.; Żywucka, N.

    2018-05-01

    PKS 0625-354 (z = 0.055) was observed with the four High Energy Stereoscopic System (H.E.S.S.) telescopes in 2012 during 5.5 h. The source was detected above an energy threshold of 200 GeV at a significance level of 6.1σ. No significant variability is found in these observations. The source is well described with a power-law spectrum with photon index Γ = 2.84 ± 0.50stat ± 0.10syst and normalization (at E0 = 1.0 TeV) N0(E0) = (0.58 ± 0.22stat ± 0.12syst) × 10-12 TeV-1 cm-2 s-1. Multiwavelength data collected with Fermi-LAT, Swift-XRT, Swift-UVOT, ATOM and WISE are also analysed. Significant variability is observed only in the Fermi-LAT γ-ray and Swift-XRT X-ray energy bands. Having a good multiwavelength coverage from radio to very high energy, we performed a broad-band modelling from two types of emission scenarios. The results from a one zone lepto-hadronic and a multizone leptonic models are compared and discussed. On the grounds of energetics, our analysis favours a leptonic multizone model. Models associated to the X-ray variability constraint support previous results, suggesting a BL Lac nature of PKS 0625-354 with, however, a large-scale jet structure typical of a radio galaxy.

  16. Detectors for high resolution dynamic positron emission tomography

    International Nuclear Information System (INIS)

    Derenzo, S.E.; Budinger, T.F.; Huesman, R.H.

    1985-01-01

    Tomography is the technique of producing a photographic image of an opaque specimen by transmitting a beam of x-rays or gamma rays through the specimen onto an adjacent photographic film. The image results from variations in thickness, density, and chemical composition, of the specimen. This technique is used to study the metabolism of the human brain. This article examines the design of equipment used for high resolution dynamic positron emission tomography. 27 references, 5 figures, 3 tables

  17. Ion induced high energy electron emission from copper

    Energy Technology Data Exchange (ETDEWEB)

    Ruano, G. [Instituto de Desarrollo Tecnologico para la Industria Quimica, Consejo Nacional de Investigaciones Cientificas y Tecnicas and Universidad Nacional del Litoral Gueemes 3450 CC 91, 3000 Santa Fe (Argentina)], E-mail: gdruano@ceride.gov.ar; Ferron, J. [Instituto de Desarrollo Tecnologico para la Industria Quimica, Consejo Nacional de Investigaciones Cientificas y Tecnicas and Universidad Nacional del Litoral Gueemes 3450 CC 91, 3000 Santa Fe (Argentina); Departamento de Ingenieria de Materiales, Facultad de Ingenieria Quimica, Consejo Nacional de Investigaciones Cientificas y Tecnicas and Universidad Nacional del Litoral Gueemes 3450 CC 91, 3000 Santa Fe (Argentina)

    2008-11-15

    We present measurements of secondary electron emission from Cu induced by low energy bombardment (1-5 keV) of noble gas (He{sup +}, Ne{sup +} and Ar{sup +}) and Li{sup +} ions. We identify different potential and kinetic mechanisms and find the presence of high energetic secondary electrons for a couple of ion-target combinations. In order to understand the presence of these fast electrons we need to consider the Fermi shuttle mechanism and the different ion neutralization efficiencies.

  18. High energy photon emission from wakefields

    Energy Technology Data Exchange (ETDEWEB)

    Farinella, D. M., E-mail: dfarinel@uci.edu; Lau, C. K.; Taimourzadeh, S.; Hwang, Y.; Abazajian, K.; Canac, N.; Taborek, P.; Tajima, T. [Department of Physics and Astronomy, University of California, Irvine, California 92697 (United States); Zhang, X. M., E-mail: zhxm@siom.ac.cn [Department of Physics and Astronomy, University of California, Irvine, California 92697 (United States); Shanghai Institute of Optics and Fine Mechanics, Chinese Academy of Sciences, Shanghai 201800 (China); Koga, J. K., E-mail: koga.james@qst.go.jp [Kansai Photon Science Institute, Japan Atomic Energy Agency (JAEA), Kizugawa, Kyoto 619-0215 (Japan); Ebisuzaki, T., E-mail: ebisu@riken.jp [RIKEN, Wako, Saitama 351-0198 (Japan)

    2016-07-15

    Experimental evidence has accumulated to indicate that wakefield acceleration (WFA) accompanies intense and sometimes coherent emission of radiation such as from betatron radiation. The investigation of this issue has additional impetus nowadays because we are learning (1) there is an additional acceleration process of the ponderomotive acceleration; (2) WFA may become relevant in much higher density regimes; (3) WFA has been proposed as the mechanism for extreme high energy cosmic ray acceleration and gamma ray bursts for active galactic nuclei. These require us to closely examine the radiative mechanisms in WFA anew. We report studies of radiation from wakefield (self-injected betatron) and ponderomotive (laser field) mechanisms in scalings of the frequency and intensity of the driver, as well as the plasma density.

  19. High-global warming potential F-gas emissions in California: comparison of ambient-based versus inventory-based emission estimates, and implications of refined estimates.

    Science.gov (United States)

    Gallagher, Glenn; Zhan, Tao; Hsu, Ying-Kuang; Gupta, Pamela; Pederson, James; Croes, Bart; Blake, Donald R; Barletta, Barbara; Meinardi, Simone; Ashford, Paul; Vetter, Arnie; Saba, Sabine; Slim, Rayan; Palandre, Lionel; Clodic, Denis; Mathis, Pamela; Wagner, Mark; Forgie, Julia; Dwyer, Harry; Wolf, Katy

    2014-01-21

    To provide information for greenhouse gas reduction policies, the California Air Resources Board (CARB) inventories annual emissions of high-global-warming potential (GWP) fluorinated gases, the fastest growing sector of greenhouse gas (GHG) emissions globally. Baseline 2008 F-gas emissions estimates for selected chlorofluorocarbons (CFC-12), hydrochlorofluorocarbons (HCFC-22), and hydrofluorocarbons (HFC-134a) made with an inventory-based methodology were compared to emissions estimates made by ambient-based measurements. Significant discrepancies were found, with the inventory-based emissions methodology resulting in a systematic 42% under-estimation of CFC-12 emissions from older refrigeration equipment and older vehicles, and a systematic 114% overestimation of emissions for HFC-134a, a refrigerant substitute for phased-out CFCs. Initial, inventory-based estimates for all F-gas emissions had assumed that equipment is no longer in service once it reaches its average lifetime of use. Revised emission estimates using improved models for equipment age at end-of-life, inventories, and leak rates specific to California resulted in F-gas emissions estimates in closer agreement to ambient-based measurements. The discrepancies between inventory-based estimates and ambient-based measurements were reduced from -42% to -6% for CFC-12, and from +114% to +9% for HFC-134a.

  20. Greenhouse gas (CO2 and CH4) emissions from a high altitude hydroelectric reservoir in the tropics (Riogrande II, Colombia)

    Science.gov (United States)

    Guérin, Frédéric; Leon, Juan

    2015-04-01

    Tropical hydroelectric reservoirs are considered as very significant source of methane (CH4) and carbon dioxide (CO2), especially when flooding dense forest. We report emissions from the Rio Grande II Reservoir located at 2000 m.a.s.l. in the Colombian Andes. The dam was built at the confluence of the Rio Grande and Rio Chico in 1990. The reservoir has a surface of 12 km2, a maximum depth of 40m and a residence time of 2.5 month. Water quality (temperature, oxygen, pH, conductivity), nitrate, ammonium, dissolved and particulate organic carbon (DOC and POC), CO2 and CH4 were monitored bi-monthly during 1.5 year at 9 stations in the reservoir. Diffusive fluxes of CO2 and CH4 and CH4 ebullition were measured at 5 stations. The Rio grande II Reservoir is weakly stratified thermally with surface temperature ranging from 20 to 24°C and a constant bottom temperature of 18°C. The reservoir water column is well oxygenated at the surface and usually anoxic below 10m depth. At the stations close to the tributaries water inputs, the water column is well mixed and oxygenated from the surface to the bottom. As reported for other reservoirs located in "clear water" watersheds, the concentrations of nutrients are low (NO3-10 mmol m-2 d-1) were observed during the dry season. Close to the tributaries water inputs where the water column is well mixed, the average diffusive flux is 8 mmol m-2 d-1. CH4 ebullition was 3.5 mmol m-2 d-1 and no ebullition was observed for a water depth higher than 5m. The zone under the influence of the water inputs from tributaries represents 25% of the surface of the reservoir but contributed half of total CH4 emissions from the reservoir (29MgC month-1). Ebullition contributed only to 12% of total CH4 emissions over a year but it contributed up to 60% during the dry season. CH4 emissions from the Rio Grande Reservoir contributed 30% of the total GHG emissions (38GgCO2eq y-1). Overall, this study show that the majority of CH4 emissions from this

  1. POLARIMETRY AND THE HIGH-ENERGY EMISSION MECHANISMS IN QUASAR JETS: THE CASE OF PKS 1136-135

    Energy Technology Data Exchange (ETDEWEB)

    Cara, Mihai; Perlman, Eric S. [Department of Physics and Space Sciences, Florida Institute of Technology, 150 W. University Blvd., Melbourne, FL 32901 (United States); Uchiyama, Yasunobu [SLAC/KIPAC, Stanford University, 2575 Sand Hill Road, M/S 209, Menlo Park, CA 94025 (United States); Cheung, Chi C. [Space Science Division, Naval Research Laboratory, Washington, DC 20375 (United States); Coppi, Paolo S. [Yale University, Department of Astronomy, P.O. Box 208101, New Haven, CT 06520-8101 (United States); Georganopoulos, Markos [Department of Physics, University of Maryland, Baltimore County, 1000 Hilltop Circle, Baltimore, MD 21250 (United States); Worrall, Diana M.; Birkinshaw, Mark [Department of Physics, University of Bristol, Bristol, BS8 1TL (United Kingdom); Sparks, William B. [Space Telescope Science Institute, 3700 San Martin Drive, Baltimore, MD 21218 (United States); Marshall, Herman L. [Kavli Institute for Astrophysics and Space Research, Massachusetts Institute of Technology, Cambridge, MA 02139 (United States); Stawarz, Lukasz [Institute of Space Astronautical Science, JAXA, 3-1-1 Yoshinodai, Chuo-Ku, Sagamihara, Kanagawa 252-5210 (Japan); Begelman, Mitchell C. [Department of Astrophysical and Planetary Sciences, UCB 391, University of Colorado, Boulder, CO 80309-0391 (United States); O' Dea, Christopher P. [Laboratory for Multiwavelength Astrophysics, School of Physics and Astronomy, Rochester Institute of Technology, 84 Lomb Memorial Dr., Rochester, NY 14623-5603 (United States); Baum, Stefi A. [Chester F. Carlson Center for Imaging Science, Rochester Institute of Technology, 54 Lomb Memorial Dr., Rochester, NY 14623-5604 (United States)

    2013-08-20

    Since the discovery of kiloparsec-scale X-ray emission from quasar jets, the physical processes responsible for their high-energy emission have been poorly defined. A number of mechanisms are under active debate, including synchrotron radiation, inverse-Comptonized cosmic microwave background (IC/CMB) emission, and other Comptonization processes. In a number of cases, the optical and X-ray emission of jet regions are inked by a single spectral component, and in those, high-resolution multi-band imaging and polarimetry can be combined to yield a powerful diagnostic of jet emission processes. Here we report on deep imaging photometry of the jet of PKS 1136-135 obtained with the Hubble Space Telescope. We find that several knots are highly polarized in the optical, with fractional polarization {Pi} > 30%. When combined with the broadband spectral shape observed in these regions, this is very difficult to explain via IC/CMB models, unless the scattering particles are at the lowest-energy tip of the electron energy distribution, with Lorentz factor {gamma} {approx} 1, and the jet is also very highly beamed ({delta} {>=} 20) and viewed within a few degrees of the line of sight. We discuss both the IC/CMB and synchrotron interpretation of the X-ray emission in the light of this new evidence, presenting new models of the spectral energy distribution and also the matter content of this jet. The high polarizations do not completely rule out the possibility of IC/CMB optical-to-X-ray emission in this jet, but they do strongly disfavor the model. We discuss the implications of this finding, and also the prospects for future work.

  2. Nonrandom community assembly and high temporal turnover promote regional coexistence in tropics but not temperate zone.

    Science.gov (United States)

    Freestone, Amy L; Inouye, Brian D

    2015-01-01

    A persistent challenge for ecologists is understanding the ecological mechanisms that maintain global patterns of biodiversity, particularly the latitudinal diversity gradient of peak species richness in the tropics. Spatial and temporal variation in community composition contribute to these patterns of biodiversity, but how this variation and its underlying processes change across latitude remains unresolved. Using a model system of sessile marine invertebrates across 25 degrees of latitude, from the temperate zone to the tropics, we tested the prediction that spatial and temporal patterns of taxonomic richness and composition, and the community assembly processes underlying these patterns, will differ across latitude. Specifically, we predicted that high beta diversity (spatial variation in composition) and high temporal turnover contribute to the high species richness of the tropics. Using a standardized experimental approach that controls for several confounding factors that hinder interpretation of prior studies, we present results that support our predictions. In the temperate zone, communities were more similar across spatial scales from centimeters to tens of kilometers and temporal scales up to one year than at lower latitudes. Since the patterns at northern latitudes were congruent with a null model, stochastic assembly processes are implicated. In contrast, the communities in the tropics were a dynamic spatial and temporal mosaic, with low similarity even across small spatial scales and high temporal turnover at both local and regional scales. Unlike the temperate zone, deterministic community assembly processes such as predation likely contributed to the high beta diversity in the tropics. Our results suggest that community assembly processes and temporal dynamics vary across latitude and help structure and maintain latitudinal patterns of diversity.

  3. Correlation Between Intercritical Heat-Affected Zone and Type IV Creep Damage Zone in Grade 91 Steel

    Science.gov (United States)

    Wang, Yiyu; Kannan, Rangasayee; Li, Leijun

    2018-04-01

    A soft zone in Cr-Mo steel weldments has been reported to accompany the infamous Type IV cracking, the highly localized creep damage in the heat-affected zone of creep-resistant steels. However, the microstructural features and formation mechanism of this soft zone are not well understood. In this study, using microhardness profiling and microstructural verification, the initial soft zone in the as-welded condition was identified to be located in the intercritical heat-affected zone of P91 steel weldments. It has a mixed structure, consisting of Cr-rich re-austenitized prior austenite grains and fine Cr-depleted, tempered martensite grains retained from the base metal. The presence of these further-tempered retained grains, originating from the base metal, is directly responsible for the hardness reduction of the identified soft zone in the as-welded condition. The identified soft zone exhibits a high location consistency at three thermal stages. Local chemistry analysis and thermodynamic calculation show that the lower chromium concentrations inside these retained grains thermodynamically decrease their potentials for austenitic transformation during welding. Heterogeneous grain growth is observed in the soft zone during postweld heat treatment. The mismatch of strengths between the weak Cr-depleted grains and strong Cr-rich grains enhances the creep damage. Local deformation of the weaker Cr-depleted grains accelerates the formation of creep cavities.

  4. Highly concentrated zinc oxide nanocrystals sol with strong blue emission

    International Nuclear Information System (INIS)

    Vafaee, M.; Sasani Ghamsari, M.; Radiman, S.

    2011-01-01

    Highly concentrated ZnO sol was synthesized by an improved sol-gel method. Water was used as a modifier to control the sol-gel reaction and provide a way to increase the sol concentration. Concentration of ZnO in the prepared sol is higher than from other methods. Optical absorption and photoluminescence were used to investigate optical properties of the prepared sol. FTIR test was performed to study the influence of water on the compounds of as-prepared sol. The size and morphology of ZnO nanoparticles have been studied by HRTEM. The prepared colloidal ZnO nanocrystals have narrow size distribution (5-8 nm) and showed strong blue emission. The prepared sol has enough potential for optoelectronic applications. - Research highlights: → Novel sol-gel route has been employed to prepare highly concentrated ZnO colloidal nanocrystals. → Water has been used to control the sources of emission in synthesized material. → A strong blue luminescent material has been obtained.

  5. The effect of welding line heat-affected-zone on the formability of tube hydroforming process

    Science.gov (United States)

    ChiuHuang, Cheng-Kai; Hsu, Cheng-En; Lee, Ping-Kun

    2016-08-01

    Tube hydroforming has been used as a lightweight design approach to reduce CO2 emission for the automotive industry. For the high strength steel tube, the strength and quality of the welding line is very important for a successful tube hydroforming process. This paper aims to investigate the effect of the welding line's strength and the width of the heat-affected zone on the tube thinning during the hydroforming process. The simulation results show that both factors play an important role on the thickness distribution during the tube expansion.

  6. The effect of welding line heat-affected-zone on the formability of tube hydroforming process

    International Nuclear Information System (INIS)

    ChiuHuang, Cheng-Kai; Hsu, Cheng-En; Lee, Ping-Kun

    2016-01-01

    Tube hydroforming has been used as a lightweight design approach to reduce CO_2 emission for the automotive industry. For the high strength steel tube, the strength and quality of the welding line is very important for a successful tube hydroforming process. This paper aims to investigate the effect of the welding line's strength and the width of the heat-affected zone on the tube thinning during the hydroforming process. The simulation results show that both factors play an important role on the thickness distribution during the tube expansion. (paper)

  7. NOx Emission Reduction by Oscillating Combustion

    Energy Technology Data Exchange (ETDEWEB)

    None

    2005-09-01

    This project focuses on a new technology that reduces NOx emissions while increasing furnace efficiency for both air- and oxygen-fired furnaces. Oscillating combustion is a retrofit technology that involves the forced oscillation of the fuel flow rate to a furnace. These oscillations create successive, fuel-rich and fuel-lean zones within the furnace.

  8. Experimental study of a high-efficiency low-emission surface combustor-heater

    International Nuclear Information System (INIS)

    Xiong, Tian-yu; Khinkis, M.J.; Fish, F.F.

    1991-01-01

    The surface combustor-heater is a combined combustion/heat-transfer device in which the heat-exchange surfaces are embedded in a stationary bed of refractory material where gaseous fuel is burned. Because of intensive heat radiation from the hot solid particles and enhanced heat convection from the gas flow to the heat-exchange tubes, heat transfer is significantly intensified. Removing heat simultaneously with the combustion process has the benefit of reducing the combustion temperature, which suppresses NO x formation. A basic experimental study was conducted on a 60-kW bench-scale surface combustor-heater with two rows of water-cooled tube coils to evaluate its performance and explore the mechanism of combined convective-radiative heat transfer and its interaction with combustion in the porous matrix. Combustion stability in the porous matrix, heat-transfer rates, emissions, and pressure drop through the unit have been investigated for the variable parameters of operation and unit configurations. Experimental results have demonstrated that high combustion intensity (up to 2.5 MW/m 2 ), high heat-transfer rates (up to 310 kW/m 2 ), high density of energy conversion (up to 8 MW/m 3 ), as well as ultra-low emissions (NO x and CO as low as 15 vppm*) have been achieved. The excellent performance of the test unit and the extensive data obtained from the present experimental study provide the basis for further development of high-efficiency and ultra low-emission water heaters, boilers, and process heaters based on the surface combustor-heater concept. 4 refs., 16 figs

  9. Study of nanometric thin pyrolytic carbon films for explosive electron emission cathode in high-voltage planar diode

    Energy Technology Data Exchange (ETDEWEB)

    Baryshevsky, Vladimir; Belous, Nikolai; Gurinovich, Alexandra; Gurnevich, Evgeny [Research Institute for Nuclear Problems, Belarusian State University, Bobruiskaya Str. 11, Minsk 220030 (Belarus); Kuzhir, Polina, E-mail: polina.kuzhir@gmail.com [Research Institute for Nuclear Problems, Belarusian State University, Bobruiskaya Str. 11, Minsk 220030 (Belarus); National Research Tomsk State University, 36 Lenin Prospekt, Tomsk 634050 (Russian Federation); Maksimenko, Sergey [Research Institute for Nuclear Problems, Belarusian State University, Bobruiskaya Str. 11, Minsk 220030 (Belarus); National Research Tomsk State University, 36 Lenin Prospekt, Tomsk 634050 (Russian Federation); Molchanov, Pavel; Shuba, Mikhail [Research Institute for Nuclear Problems, Belarusian State University, Bobruiskaya Str. 11, Minsk 220030 (Belarus); Roddatis, Vladimir [CIC energiGUNE, Albert Einstein 48, 01510 Minano, Alava (Spain); Institut für Materialphysik of Universität Göttingen, Friedrich-Hund-Platz 1, 37077 Göttingen (Germany); Kaplas, Tommi; Svirko, Yuri [Institute of Photonics, University of Eastern Finland, P.O. Box 111, Joensuu FI-80101 (Finland)

    2015-04-30

    We report on an experimental study of explosive electron emission properties of cathode made by nanometric thin pyrolytic carbon (PyC) films (2–150 nm) deposited on Cu substrate via methane-based chemical vapor deposition. High current density at level of 300 A/cm{sup 2} in 5 · 10{sup −5} Pa vacuum has been observed together with very stable explosive emission from the planar cathode. The Raman spectroscopy investigation proves that the PyC films remain the same after seven shots. According to the optical image analysis of the cathode before and after one and seven shots, we conclude that the most unusual and interesting feature of using the PyC films/Cu cathode for explosive emission is that the PyC layer on the top of the copper target prevents its evaporation and oxidation, which leads to higher emission stability compared to conventional graphitic/Cu cathodes, and therefore results in longer working life. - Highlights: • Explosive electron emission from pyrolytic carbon (PyC) cathode is reported. • We observe high current density, 300 A/cm{sup 2}, and stable emission parameters. • PyC integrity ensures a high application potential for high current electronics.

  10. Characteristics of extreme ultraviolet emission from high-Z plasmas

    International Nuclear Information System (INIS)

    Ohashi, H.; Higashiguchi, T.; Suzuki, Y.; Kawasaki, M.; Suzuki, C.; Tomita, K.; Nishikino, M.; Fujioka, S.; Endo, A.; Li, B.; Otsuka, T.; Dunne, P.; O'Sullivan, G.

    2016-01-01

    We demonstrate the extreme ultraviolet (EUV) and soft x-ray sources in the 2 to 7 nm spectral region related to the beyond EUV (BEUV) question at 6.x nm and the water window source based on laser-produced high-Z plasmas. Resonance emission from multiply charged ions merges to produce intense unresolved transition arrays (UTAs), extending below the carbon K edge (4.37 nm). An outline of a microscope design for single-shot live cell imaging is proposed based on high-Z plasma UTA source, coupled to multilayer mirror optics. (paper)

  11. Characteristics of extreme ultraviolet emission from high-Z plasmas

    Science.gov (United States)

    Ohashi, H.; Higashiguchi, T.; Suzuki, Y.; Kawasaki, M.; Suzuki, C.; Tomita, K.; Nishikino, M.; Fujioka, S.; Endo, A.; Li, B.; Otsuka, T.; Dunne, P.; O'Sullivan, G.

    2016-03-01

    We demonstrate the extreme ultraviolet (EUV) and soft x-ray sources in the 2 to 7 nm spectral region related to the beyond EUV (BEUV) question at 6.x nm and the water window source based on laser-produced high-Z plasmas. Resonance emission from multiply charged ions merges to produce intense unresolved transition arrays (UTAs), extending below the carbon K edge (4.37 nm). An outline of a microscope design for single-shot live cell imaging is proposed based on high-Z plasma UTA source, coupled to multilayer mirror optics.

  12. The Combined ASTER MODIS Emissivity over Land (CAMEL Part 1: Methodology and High Spectral Resolution Application

    Directory of Open Access Journals (Sweden)

    E. Eva Borbas

    2018-04-01

    Full Text Available As part of a National Aeronautics and Space Administration (NASA MEaSUREs (Making Earth System Data Records for Use in Research Environments Land Surface Temperature and Emissivity project, the Space Science and Engineering Center (UW-Madison and the NASA Jet Propulsion Laboratory (JPL developed a global monthly mean emissivity Earth System Data Record (ESDR. This new Combined ASTER (Advanced Spaceborne Thermal Emission and Reflection Radiometer and MODIS (Moderate Resolution Imaging Spectroradiometer Emissivity over Land (CAMEL ESDR was produced by merging two current state-of-the-art emissivity datasets: the UW-Madison MODIS Infrared emissivity dataset (UW BF and the JPL ASTER Global Emissivity Dataset Version 4 (GEDv4. The dataset includes monthly global records of emissivity and related uncertainties at 13 hinge points between 3.6–14.3 µm, as well as principal component analysis (PCA coefficients at 5-km resolution for the years 2000 through 2016. A high spectral resolution (HSR algorithm is provided for HSR applications. This paper describes the 13 hinge-points combination methodology and the high spectral resolutions algorithm, as well as reports the current status of the dataset.

  13. Mathematical modelling of NO emissions from high-temperature air combustion with nitrous oxide mechanism

    International Nuclear Information System (INIS)

    Yang, Weihong; Blasiak, Wlodzimierz

    2005-01-01

    A study of the mathematical modelling of NO formation and emissions in a gas-fired regenerative furnace with high-preheated air was performed. The model of NO formation via N 2 O-intermediate mechanism was proposed because of the lower flame temperature in this case. The reaction rates of this new model were calculated basing on the eddy-dissipation-concept. This model accompanied with thermal-NO, prompt-NO and NO reburning models were used to predict NO emissions and formations. The sensitivity of the furnace temperature and the oxygen availability on NO generation rate has been investigated. The predicted results were compared with experimental values. The results show that NO emission formed by N 2 O-intermediate mechanism is of outstanding importance during the high-temperature air combustion (HiTAC) condition. Furthermore, it shows that NO models with N 2 O-route model can give more reasonable profile of NO formation. Additionally, increasing excess air ratio leads to increasing of NO emission in the regenerative furnace. (author)

  14. Assessing fugitive emissions of CH4 from high-pressure gas pipelines in the UK

    Science.gov (United States)

    Clancy, S.; Worrall, F.; Davies, R. J.; Almond, S.; Boothroyd, I.

    2016-12-01

    Concern over the greenhouse gas impact of the exploitation of unconventional natural gas from shale deposits has caused a spotlight to be shone on to the entire hydrocarbon industry. Numerous studies have developed life-cycle emissions inventories to assess the impact that hydraulic fracturing has upon greenhouse gas emissions. Incorporated within life-cycle assessments are transmission and distribution losses, including infrastructure such as pipelines and compressor stations that pressurise natural gas for transport along pipelines. Estimates of fugitive emissions from transmission, storage and distribution have been criticized for reliance on old data from inappropriate sources (1970s Russian gas pipelines). In this study, we investigate fugitive emissions of CH4 from the UK high pressure national transmission system. The study took two approaches. Firstly, CH4 concentration is detected by driving along roads bisecting high pressure gas pipelines and also along an equivalent distance along a route where no high pressure gas pipeline was nearby. Five pipelines and five equivalent control routes were driven and the test was that CH4 measurements, when adjusted for distance and wind speed, should be greater on any route with a pipe than any route without a pipe. Secondly, 5 km of a high pressure gas pipeline and 5 km of equivalent farmland, were walked and soil gas (above the pipeline where present) was analysed every 7 m using a tunable diode laser. When wind adjusted 92 km of high pressure pipeline and 72 km of control route were drive over a 10 day period. When wind and distance adjusted CH4 fluxes were significantly greater on routes with a pipeline than those without. The smallest leak detectable was 3% above ambient (1.03 relative concentration) with any leaks below 3% above ambient assumed ambient. The number of leaks detected along the pipelines correlate to the estimated length of pipe joints, inferring that there are constant fugitive CH4 emissions from

  15. Prompt High Energy Dipole γ Emission

    International Nuclear Information System (INIS)

    Corsi, A.; Giaz, A; Bracco, A.

    2011-01-01

    The study of the collective properties of a nuclear system is a powerful tool to understand the structure which lies inside the nucleus. A successful technique which has been used in this field is the measurement of the γ-decay of the highly collective Giant Dipole Resonance (GDR). In fact, GDR can be used as a probe for the internal structure of hot nuclei and, in addition, constitutes a clock for the thermalization process. Using the fusion-evaporation reaction, it has been recently possible to study (i) the yield of the high-energy γ-ray emission of the Dynamical Dipole which takes place during the fusion process and (ii) the degree of isospin mixing at high temperature in the decay of 80 Zr. In the first case it is important to stress the fact that the predictions of the theoretical models might differ depending on the type of nuclear equation of state (EOS) and on the N-N in-medium cross-section used in the calculations while, in the second physics case, the data are relative to the heaviest N = Z nucleus which has been possible to populate in the I = 0 channel using fusion-evaporation reaction. Both experiments were performed at the Laboratori Nazionali di Legnaro using the HECTOR-GARFIELD array. The high-energy γ-rays were measured in coincidence with light charged particles and fusion-evaporation residues. (author)

  16. Very High Cycle Fatigue Crack Initiation Mechanism in Nugget Zone of AA 7075 Friction Stir Welded Joint

    Directory of Open Access Journals (Sweden)

    Chao He

    2017-01-01

    Full Text Available Very high cycle fatigue behavior of nugget zone in AA 7075 friction stir welded joint was experimentally investigated using ultrasonic fatigue testing system (20 kHz to clarify the crack initiation mechanism. It was found that the fatigue strength of nugget zone decreased continuously even beyond 107 cycles with no traditional fatigue limits. Fatigue cracks initiated from the welding defects located at the bottom side of the friction stir weld. Moreover, a special semicircular zone could be characterized around the crack initiation site, of which the stress intensity factor approximately equaled the threshold of fatigue crack propagation rate. Finally, a simplified model was proposed to estimate the fatigue life by correlating the welding defect size and applied stress. The predicted results are in good agreement with the experimental results.

  17. Application of High Resolution Air-Borne Remote Sensing Observations for Monitoring NOx Emissions

    Science.gov (United States)

    Souri, A.; Choi, Y.; Pan, S.; Curci, G.; Janz, S. J.; Kowalewski, M. G.; Liu, J.; Herman, J. R.; Weinheimer, A. J.

    2017-12-01

    Nitrogen oxides (NOx=NO+NO2) are one of the air pollutants, responsible for the formation of tropospheric ozone, acid rain and particulate nitrate. The anthropogenic NOx emissions are commonly estimated based on bottom-up inventories which are complicated by many potential sources of error. One way to improve the emission inventories is to use relevant observations to constrain them. Fortunately, Nitrogen dioxide (NO2) is one of the most successful detected species from remote sensing. Although many studies have shown the capability of using space-borne remote sensing observations for monitoring emissions, the insufficient sample number and footprint of current measurements have introduced a burden to constrain emissions at fine scales. Promisingly, there are several air-borne sensors collected for NASA's campaigns providing high spatial resolution of NO2 columns. Here, we use the well-characterized NO2 columns from the Airborne Compact Atmospheric Mapper (ACAM) onboard NASA's B200 aircraft into a 1×1 km regional model to constrain anthropogenic NOx emissions in the Houston-Galveston-Brazoria area. Firstly, in order to incorporate the data, we convert the NO2 slant column densities to vertical ones using a joint of a radiative transfer model and the 1x1 km regional model constrained by P3-B aircraft measurements. After conducting an inverse modeling method using the Kalman filter, we find the ACAM observations are resourceful at mitigating the overprediction of model in reproducing NO2 on regular days. Moreover, the ACAM provides a unique opportunity to detect an anomaly in emissions leading to strong air quality degradation that is lacking in previous works. Our study provides convincing evidence that future geostationary satellites with high spatial and temporal resolutions will give us insights into uncertainties associated with the emissions at regional scales.

  18. A parametric investigation of hydrogen hcci combustion using a multi-zone model approach

    International Nuclear Information System (INIS)

    Komninos, N.P.; Hountalas, D.T.; Rakopoulos, C.D.

    2007-01-01

    The purpose of the present study is to examine the effect of various operating variables of a homogeneous charge compression ignition (HCCI) engine fueled with hydrogen, using a multi-zone model developed by the authors. The multi-zone model consists of zones, which are allotted spatial locations within the combustion chamber. The model takes into account heat transfer between the zones and the combustion chamber walls, providing a spatial temperature distribution during the closed part of the engine cycle, i.e. compression, combustion and expansion. Mass transfer between zones is also accounted for, based on the geometric configuration of the zones, and includes the flow of mass in and out of the crevice regions, represented by the crevice zone. Combustion is incorporated using chemical kinetics based on a chemical reaction mechanism for the oxidation of hydrogen. This chemical reaction mechanism also includes the reactions for nitrogen oxides formation. Using the multi-zone model a parametric investigation is conducted, in order to determine the effect of engine speed, equivalence ratio, compression ratio, inlet pressure and inlet temperature, on the performance, combustion characteristics and emissions of an HCCI engine fueled with hydrogen

  19. Geochemical Processes Controlling Migration of High Level Wastes in Hanford's Vadose Zone

    International Nuclear Information System (INIS)

    Zachara, John M.; Serne, R. Jeffrey; Freshley, Mark D.; Mann, Frederick M.; Anderson, Frank J.; Wood, Marcus I.; Jones, Thomas E.; Myers, David A.

    2007-01-01

    High level nuclear wastes (HLW) from Hanford's plutonium reprocessing are stored in massive, buried, single-shell tanks in eighteen tank farms. The wastes were initially hot because of radioactive decay, and many exhibited extreme chemical character in terms of pH, salinity, and radionuclide concentration. At present, 67 of the 149 single shell tanks are suspected to have released over 1.9 million L of tank waste to the vadose zone, with most leak events occurring between 1950 and 1975. Boreholes have been placed through the largest vadose zone plumes to define the extent of contaminant migration, and to develop conceptual models of processes governing the transformation, retardation, and overall transport of tank waste residuals. Laboratory studies with sediments so collected have shown that ion exchange, precipitation and dissolution, and surface complexation reactions have occurred between the HLW and subsurface sediments moderating their chemical character, and retarding the migration of select contaminants. Processes suspected to facilitate the far-field migration of immobile radionuclides including stable aqueous complex formation and mobile colloids were found to be potentially operative, but unlikely to occur in the field, with the exception of cyanide-facilitated migration of 60Co. Fission product oxyanions are the most mobile of tank waste constituents because their adsorption is suppressed by large concentrations of waste anions; the vadose zone clay fraction is negative in surface charge; and, unlike Cr, their reduced forms are unstable in oxidizing environments. Reaction/process-based transport modeling is beginning to be used for predictions of future contaminant mobility and plume evolution

  20. High-Power and High-Efficiency 1.3- µm Superluminescent Diode With Flat-Top and Ultrawide Emission Bandwidth

    KAUST Repository

    Khan, Mohammed Zahed Mustafa; Alhashim, Hala H.; Ng, Tien Khee; Ooi, Boon S.

    2015-01-01

    We report on a flat-top and ultrawide emission bandwidth of 125 nm from InGaAsP/InP multiple quantum-well (MQW) superluminescent diode with antireflection coated and tilted ridge-waveguide device configuration. A total output power in excess of 70 mW with an average power spectral density of 0.56 mW/nm and spectral ripple ≤ 1.2 ± 0.5 dB is measured from the device. Wall-plug efficiency and output power as high as 14% and 80 mW, respectively, is demonstrated from this batch of devices. We attribute the broad emission to the inherent inhomogeneity of the electron-heavy-hole (e-hh) and electron-light-hole (e-lh) recombination of the ground state and the first excited state of the MQWs and their simultaneous emission.

  1. High-Power and High-Efficiency 1.3- µm Superluminescent Diode With Flat-Top and Ultrawide Emission Bandwidth

    KAUST Repository

    Khan, Mohammed Zahed Mustafa

    2015-02-01

    We report on a flat-top and ultrawide emission bandwidth of 125 nm from InGaAsP/InP multiple quantum-well (MQW) superluminescent diode with antireflection coated and tilted ridge-waveguide device configuration. A total output power in excess of 70 mW with an average power spectral density of 0.56 mW/nm and spectral ripple ≤ 1.2 ± 0.5 dB is measured from the device. Wall-plug efficiency and output power as high as 14% and 80 mW, respectively, is demonstrated from this batch of devices. We attribute the broad emission to the inherent inhomogeneity of the electron-heavy-hole (e-hh) and electron-light-hole (e-lh) recombination of the ground state and the first excited state of the MQWs and their simultaneous emission.

  2. Flame Structure and Emissions of Strongly-Pulsed Turbulent Diffusion Flames with Swirl

    Science.gov (United States)

    Liao, Ying-Hao

    This work studies the turbulent flame structure, the reaction-zone structure and the exhaust emissions of strongly-pulsed, non-premixed flames with co-flow swirl. The fuel injection is controlled by strongly-pulsing the fuel flow by a fast-response solenoid valve such that the fuel flow is completely shut off between pulses. This control strategy allows the fuel injection to be controlled over a wide range of operating conditions, allowing the flame structure to range from isolated fully-modulated puffs to interacting puffs to steady flames. The swirl level is controlled by varying the ratio of the volumetric flow rate of the tangential air to that of the axial air. For strongly-pulsed flames, both with and without swirl, the flame geometry is strongly impacted by the injection time. Flames appear to exhibit compact, puff-like structures for short injection times, while elongated flames, similar in behaviors to steady flames, occur for long injection times. The flames with swirl are found to be shorter for the same fuel injection conditions. The separation/interaction level between flame puffs in these flames is essentially governed by the jet-off time. The separation between flame puffs decreases as swirl is imposed, consistent with the decrease in flame puff celerity due to swirl. The decreased flame length and flame puff celerity are consistent with an increased rate of air entrainment due to swirl. The highest levels of CO emissions are generally found for compact, isolated flame puffs, consistent with the rapid quenching due to rapid dilution with excess air. The imposition of swirl generally results in a decrease in CO levels, suggesting more rapid and complete fuel/air mixing by imposing swirl in the co-flow stream. The levels of NO emissions for most cases are generally below the steady-flame value. The NO levels become comparable to the steady-flame value for sufficiently short jet-off time. The swirled co-flow air can, in some cases, increase the NO

  3. Total emissivity and spectral emissivity of high-temperature materials; Gesamtemissionsgrad und spektraler Emissionsgrad von Hochtemperaturmaterialien

    Energy Technology Data Exchange (ETDEWEB)

    Neuer, G.; Pohlmann, P.; Schreiber, E.

    1998-05-01

    A new emissivity measurement device with inductive sample heating is described. The disc shaped samples can be measured between 800 C and 2000 C in vacuum or in each available gas atmosphere. Two kinds of surface temperature measurement methods are described, one by measuring in a blackbody hole and one by measuring at the surface without additional measures to correct emissivity. Total normal and spectral emissivity at wavelengths between 0,5 {mu}m and 8,3 {mu}m of various high temperature materials like platinum and Pt-Rh-alloys, siliconcarbide and molybdenum disilicide have been measured. From the investigated materials a few have been selected as reference samples for comparative emissivity measurements fullfilling the requirement of stability on air up to 400 C to 1000 C in order to ensure reproducibility of the results at different measurement conditions in air and in vacuum. (orig.) [Deutsch] Der Aufbau einer neuen Messapparatur fuer Emissionsgradmessungen bei Temperaturen zwischen 1000 C und 2000 C wird beschrieben. Die scheibenfoermigen Proben werden induktiv beheizt, und die Messungen koennen entweder in Vakuum oder einer beliebigen Gasatmosphaere durchgefuehrt werden. Es werden zwei verschiedene Verfahren zur Bestimmung der Oberflaechentemperatur bechrieben, wobei entweder in einer oder direkt an der Oberflaeche ohne zusaetzliche Massnahmen zur Emissionsgradkorrektur gemessen wird. An verschiedenen Hochtemperaturwerkstoffen wie Platin und Platin-Rhodium-Legierungen, Siliziumkarbid mit unterschiedlichen Herstellungsarten und Molybdaen-Disilizid wurden der Gesamtemissionsgrad und der spektrale Emissionsgrad bei Wellenlaengen von 0,5 {mu}m bis 8,3 {mu}m senkrecht zur Oberflaeche gemessen. Aus den untersuchten Materialien wurden solche als Referenzmaterialien fuer vergleichende Emissionsgradmessungen ausgewaehlt, die sowohl im Vakuum als auch in Luft und bei Temperaturen von 1400 C bis 1600 C unter verschiedenen Messbedingungen reproduzierbare Ergebnisse

  4. Quantifying the Variation in Shear Zone Character with Depth: a Case Study from the Simplon Shear Zone, Central Alps

    Science.gov (United States)

    Cawood, T. K.; Platt, J. P.

    2017-12-01

    A widely-accepted model for the rheology of crustal-scale shear zones states that they comprise distributed strain at depth, in wide, high-temperature shear zones, which narrow to more localized, high-strain zones at lower temperature and shallower crustal levels. We test and quantify this model by investigating how the width, stress, temperature and deformation mechanisms change with depth in the Simplon Shear Zone (SSZ). The SSZ marks a major tectonic boundary in the central Alps, where normal-sense motion and rapid exhumation of the footwall have preserved evidence of older, deeper deformation in rocks progressively further into the currently-exposed footwall. As such, microstructures further from the brittle fault (which represents the most localized, most recently-active part of the SSZ) represent earlier, higher- temperature deformation from deeper crustal levels, while rocks closer to the fault have been overprinted by successively later, cooler deformation at shallower depths. This study uses field mapping and microstructural studies to identify zones representing deformation at various crustal levels, and characterize each in terms of zone width (representing width of the shear zone at that time and depth) and dominant deformation mechanism. In addition, quartz- (by Electron Backscatter Diffraction, EBSD) and feldspar grain size (measured optically) piezometry are used to calculate the flow stress for each zone, while the Ti-in-quartz thermometer (TitaniQ) is used to calculate the corresponding temperature of deformation. We document the presence of a broad zone in which quartz is recrystallized by the Grain Boundary Migration (GBM) mechanism and feldspar by Subgrain Rotation (SGR), which represents the broad, deep zone of deformation occurring at relatively high temperatures and low stresses. In map view, this transitions to successively narrower zones, respectively characterized by quartz SGR and feldspar Bulge Nucleation (BLG); quartz BLG and brittle

  5. Surface elevation change and susceptibility of different mangrove zones to sea-level rise on Pacific high islands of Micronesia

    Science.gov (United States)

    Krauss, K.W.; Cahoon, D.R.; Allen, J.A.; Ewel, K.C.; Lynch, J.C.; Cormier, N.

    2010-01-01

    Mangroves on Pacific high islands offer a number of important ecosystem services to both natural ecological communities and human societies. High islands are subjected to constant erosion over geologic time, which establishes an important source of terrigeneous sediment for nearby marine communities. Many of these sediments are deposited in mangrove forests and offer mangroves a potentially important means for adjusting surface elevation with rising sea level. In this study, we investigated sedimentation and elevation dynamics of mangrove forests in three hydrogeomorphic settings on the islands of Kosrae and Pohnpei, Federated States of Micronesia (FSM). Surface accretion rates ranged from 2.9 to 20.8 mm y-1, and are high for naturally occurring mangroves. Although mangrove forests in Micronesian high islands appear to have a strong capacity to offset elevation losses by way of sedimentation, elevation change over 61/2 years ranged from -3.2 to 4.1 mm y-1, depending on the location. Mangrove surface elevation change also varied by hydrogeomorphic setting and river, and suggested differential, and not uniformly bleak, susceptibilities among Pacific high island mangroves to sea-level rise. Fringe, riverine, and interior settings registered elevation changes of -1.30, 0.46, and 1.56 mm y-1, respectively, with the greatest elevation deficit (-3.2 mm y-1) from a fringe zone on Pohnpei and the highest rate of elevation gain (4.1 mm y-1) from an interior zone on Kosrae. Relative to sea-level rise estimates for FSM (0.8-1.8 mm y-1) and assuming a consistent linear trend in these estimates, soil elevations in mangroves on Kosrae and Pohnpei are experiencing between an annual deficit of 4.95 mm and an annual surplus of 3.28 mm. Although natural disturbances are important in mediating elevation gain in some situations, constant allochthonous sediment deposition probably matters most on these Pacific high islands, and is especially helpful in certain hydrogeomorphic zones

  6. Estimating Biogenic Non-Methane Hydrocarbon Emissions for the Wasatch Front Through a High-Resolution. Gridded, Biogenic Vola Tile Organic Compound Emissions Inventory

    Science.gov (United States)

    2002-01-01

    1-hour and proposed 8-hour National Ambient Air Quality Standards. Reactive biogenic (natural) volatile organic compounds emitted from plants have...uncertainty in predicting plant species composition and frequency. Isoprene emissions computed for the study area from the project’s high-resolution...Landcover Database (BELD 2), while monoterpene and other reactive volatile organic compound emission rates were almost 26% and 28% lower, respectively

  7. 40 CFR Appendix III to Part 1042 - Not-to-Exceed Zones

    Science.gov (United States)

    2010-07-01

    ... CONTROLS CONTROL OF EMISSIONS FROM NEW AND IN-USE MARINE COMPRESSION-IGNITION ENGINES AND VESSELS Pt. 1042... engines certified using the duty cycle specified in § 1042.505(b)(1), except for variable-speed propulsion... Appendix illustrates the default NTE zone for variable-speed marine engines used with controllable-pitch...

  8. Growing season methane emission from a boreal peatland in the continuous permafrost zone of Northeast China: effects of active layer depth and vegetation

    Directory of Open Access Journals (Sweden)

    Y. Miao

    2012-11-01

    Full Text Available Boreal peatlands are significant natural sources of methane and especially vulnerable to abrupt climate change. However, the controlling factors of CH4 emission in boreal peatlands are still unclear. In this study, we investigated CH4 fluxes and abiotic factors (temperature, water table depth, active layer depth, and dissolved CH4 concentrations in pore water during the growing seasons in 2010 and 2011 in both shrub-sphagnum- and sedge-dominated plant communities in the continuous permafrost zone of Northeast China. The objective of our study was to examine the effects of vegetation types and abiotic factors on CH4 fluxes from a boreal peatland. In an Eriophorum-dominated community, mean CH4 emissions were 1.02 and 0.80 mg m−2 h−1 in 2010 and 2011, respectively. CH4 fluxes (0.38 mg m−2 h−1 released from the shrub-mosses-dominated community were lower than that from Eriophorum-dominated community. Moreover, in the Eriophorum-dominated community, CH4 fluxes showed a significant temporal pattern with a peak value in late August in both 2010 and 2011. However, no distinct seasonal variation was observed in the CH4 flux in the shrub-mosses-dominated community. Interestingly, in both Eriophorum- and shrub-sphagnum-dominated communities, CH4 fluxes did not show close correlation with air or soil temperature and water table depth, whereas CH4 emissions correlated well to active layer depth and CH4 concentration in soil pore water, especially in the Eriophorum-dominated community. Our results suggest that CH4 released from the thawed CH4-rich permafrost layer may be a key factor controlling CH4 emissions in boreal peatlands, and highlight that CH4 fluxes vary with vegetation type in boreal peatlands. With

  9. Acoustic emission technique and its applications

    International Nuclear Information System (INIS)

    Sato, Ichiya; Sasaki, Soji

    1976-01-01

    Acoustic emission technique is described. The characteristics of acoustic emission signal, measurement techniques, and its application are explained. The acoustic signals are grouped into continuous and burst types. The continuous signal is due to plastic deformation, and the burst type is due to the generation and growth of cracks. The latter can be used for the identification of the position of cracks. The frequency of the acoustic emission is in the range from several tens of KHz to two MHz. Piezoelectric ceramics are used as the oscillators of sensors. The dynamic behavior of acoustic emission can be observed with a two-channel acoustic emission measuring apparatus. Multi-channel method was developed at Hitachi, Ltd., and is used for large structures. General computer identification method and simple zone identification method are explained. Noise elimination is important for the measurement, and the methods were studied. Examples of application are the observation of acoustic emission in the plastic deformation of steel, the tensile test of large welded material with natural defects, and others. The method will be used for the diagnosis and observation of large structures, the test and quality control of products. (Kato, T.)

  10. Highly efficient greenish-blue platinum-based phosphorescent organic light-emitting diodes on a high triplet energy platform

    Energy Technology Data Exchange (ETDEWEB)

    Chang, Y. L., E-mail: yilu.chang@mail.utoronto.ca; Gong, S., E-mail: sgong@chem.utoronto.ca; White, R.; Lu, Z. H., E-mail: zhenghong.lu@utoronto.ca [Department of Materials Science and Engineering, University of Toronto, 184 College St., Toronto, Ontario M5S 3E4 (Canada); Wang, X.; Wang, S., E-mail: wangs@chem.queensu.ca [Department of Chemistry, Queen' s University, 90 Bader Lane, Kingston, Ontario K7L 3N6 (Canada); Yang, C. [Department of Chemistry, Wuhan University, Wuhan 430072 (China)

    2014-04-28

    We have demonstrated high-efficiency greenish-blue phosphorescent organic light-emitting diodes (PHOLEDs) based on a dimesitylboryl-functionalized C^N chelate Pt(II) phosphor, Pt(m-Bptrz)(t-Bu-pytrz-Me). Using a high triplet energy platform and optimized double emissive zone device architecture results in greenish-blue PHOLEDs that exhibit an external quantum efficiency of 24.0% and a power efficiency of 55.8 lm/W. This record high performance is comparable with that of the state-of-the-art Ir-based sky-blue organic light-emitting diodes.

  11. Highly-controlled, reproducible measurements of aerosol emissions from African biomass combustion

    Science.gov (United States)

    Haslett, Sophie; Thomas, J. Chris; Morgan, William; Hadden, Rory; Liu, Dantong; Allan, James; Williams, Paul; Sekou, Keïta; Liousse, Catherine; Coe, Hugh

    2017-04-01

    Particulate emissions from biomass burning can alter the atmosphere's radiative balance and cause significant harm to human health. However, the relationship between these emissions and fundamental combustion processes is, to date, poorly characterised. In atmospheric models, aerosol emissions are represented by emission factors based on mass loss, which are averaged over an entire combustion event for each particulate species. This approach, however, masks huge variability in emissions during different phases of the combustion period. Laboratory tests have shown that even small changes to the burning environment can lead to huge variation in observed aerosol emission factors (Akagi et al., 2011). In order to address this gap in understanding, in this study, small wood samples sourced from Côte D'Ivoire were burned in a highly-controlled laboratory environment. The shape and mass of samples, available airflow and surrounding heat were carefully regulated. Organic aerosol and refractory black carbon emissions were measured in real-time using an Aerosol Mass Spectrometer and a Single Particle Soot Photometer, respectively. Both of these instruments are used regularly to measure aerosol concentrations in the field. This methodology produced remarkably repeatable results, allowing three different phases of combustion to be identified by their emissions. Black carbon was emitted predominantly during flaming combustion; organic aerosols were emitted during pyrolysis before ignition and from smouldering-dominated behaviour near the end of combustion. During the flaming period, there was a strong correlation between the emission of black carbon and the rate of mass loss, which suggests there is value in employing a mass-based emission factor for this species. However, very little correlation was seen between organic aerosol and mass loss throughout the tests. As such, results here suggest that emission factors averaged over an entire combustion event are unlikely to be

  12. Carbon emission from global hydroelectric reservoirs revisited.

    Science.gov (United States)

    Li, Siyue; Zhang, Quanfa

    2014-12-01

    Substantial greenhouse gas (GHG) emissions from hydropower reservoirs have been of great concerns recently, yet the significant carbon emitters of drawdown area and reservoir downstream (including spillways and turbines as well as river reaches below dams) have not been included in global carbon budget. Here, we revisit GHG emission from hydropower reservoirs by considering reservoir surface area, drawdown zone and reservoir downstream. Our estimates demonstrate around 301.3 Tg carbon dioxide (CO2)/year and 18.7 Tg methane (CH4)/year from global hydroelectric reservoirs, which are much higher than recent observations. The sum of drawdown and downstream emission, which is generally overlooked, represents 42 % CO2 and 67 % CH4 of the total emissions from hydropower reservoirs. Accordingly, the global average emissions from hydropower are estimated to be 92 g CO2/kWh and 5.7 g CH4/kWh. Nonetheless, global hydroelectricity could currently reduce approximate 2,351 Tg CO2eq/year with respect to fuel fossil plant alternative. The new findings show a substantial revision of carbon emission from the global hydropower reservoirs.

  13. Improving combustion characteristics and NO(x) emissions of a down-fired 350 MW(e) utility boiler with multiple injection and multiple staging.

    Science.gov (United States)

    Kuang, Min; Li, Zhengqi; Xu, Shantian; Zhu, Qunyi

    2011-04-15

    Within a Mitsui Babcock Energy Limited down-fired pulverized-coal 350 MW(e) utility boiler, in situ experiments were performed, with measurements taken of gas temperatures in the burner and near the right-wall regions, and of gas concentrations (O(2) and NO) from the near-wall region. Large combustion differences between zones near the front and rear walls and particularly high NO(x) emissions were found in the boiler. With focus on minimizing these problems, a new technology based on multiple-injection and multiple-staging has been developed. Combustion improvements and NO(x) reductions were validated by investigating three aspects. First, numerical simulations of the pulverized-coal combustion process and NO(x) emissions were compared in both the original and new technologies. Good agreement was found between simulations and in situ measurements with the original technology. Second, with the new technology, gas temperature and concentration distributions were found to be symmetric near the front and rear walls. A relatively low-temperature and high-oxygen-concentration zone formed in the near-wall region that helps mitigate slagging in the lower furnace. Third, NO(x) emissions were found to have decreased by as much as 50%, yielding a slight decrease in the levels of unburnt carbon in the fly ash.

  14. Highly Efficient Defect Emission from ZnO:Zn and ZnO:S Powders

    Science.gov (United States)

    Everitt, Henry

    2013-03-01

    Bulk Zinc Oxide (ZnO) is a wide band gap semiconductor with an ultraviolet direct band gap energy of 3.4 eV and a broad, defect-related visible wavelength emission band centered near 2 eV. We have shown that the external quantum efficiency can exceed 50% for this nearly white emission band that closely matches the human dark-adapted visual response. To explore the potential of ZnO as a rare earth-free white light phosphor, we investigated the mechanism of efficient defect emission in three types of ZnO powders: unannealed, annealed, and sulfur-doped. Annealing and sulfur-doping of ZnO greatly increase the strength of defect emission while suppressing the UV band edge emission. Continuous wave and ultrafast one- and two-photon excitation spectroscopy are used to examine the defect emission mechanism. Low temperature photoluminescence (PL) and PL excitation (PLE) spectra were measured for all three compounds, and it was found that bound excitons mediate the defect emission. Temperature-dependent PLE spectra for the defect and band edge emission were measured to estimate trapping and activation energies of the bound excitons and clarify the role they play in the defect emission. Time-resolved techniques were used to ascertain the role of exciton diffusion, the effects of reabsorption, and the spatial distributions of radiative and non-radiative traps. In unannealed ZnO we find that defect emission is suppressed and UV band edge emission is inefficient (reduced, and a high density of defects responsible for the broad visible emission are created near the surface. Interestingly, nearly identical PLE spectra are found for both the band edge and the defect emission, one of many indications that the defect emission is deeply connected to bound excitons. Quantum efficiency, also measured as a function of excitation wavelength, closely mirrors the PLE spectra for both emission bands. Sulfur-doped ZnO exhibits additional PLE and X-ray features indicative of a ZnS-rich surface

  15. Methods for Characterization of the Diesel Combustion and Emission Formation Processes

    Energy Technology Data Exchange (ETDEWEB)

    Lindstroem, Mikael

    2011-07-01

    In this thesis various aspects of the diesel engine fuel injection, combustion and emission formation processes have been evaluated. Several types of evaluation tools and methods have been applied. Fuel spray momentum was used to characterize injection rate and hole-to-hole variations in fuel injectors. Using both instantaneous fuel impulse rates and instantaneous mass flow measurements, spray velocity and nozzle flow parameters were evaluated. Several other hole-to-hole resolved injector characterization methods were used to characterize a set of fuel injectors subjected to long term testing. Fuel injector nozzle hole-to-hole variations were found to have a large influence on engine efficiency and emissions. The degree of hole-to-hole variations for an injector has been shown to correlate well with the performance deterioration of that injector. The formation and atomization of fuel sprays, ignition onset and the development of diffusion flames were studied using an optical engine. Flame temperature evaluations have been made using two different methods. NO-formation depends strongly on flame temperature. By applying a NO-formation evaluation method based on both heat release rate and flame and gas temperature it was possible to achieve a reasonable degree of correlation with measured exhaust emissions for very varying operating conditions. The prediction capability of the NO-formation evaluation method was utilized to evaluate spatially and temporally resolved NO-formation from flame temperature distributions. This made it possible to pinpoint areas with a high degree of NO-formation. It was found that small hot zones in the flames can be responsible for a large part of the total amount of NO that is produced, especially in combustion cases where no EGR is used to lower the flame temperature. By applying optical diagnostics methods the combustion and emission formation phenomena encountered during production engine transients were evaluated. The transient

  16. Acoustic emission monitoring from a lab scale high shear granulator--a novel approach.

    Science.gov (United States)

    Watson, N J; Povey, M J W; Reynolds, G K; Xu, B H; Ding, Y

    2014-04-25

    A new approach to the monitoring of granulation processes using passive acoustics together with precise control over the granulation process has highlighted the importance of particle-particle and particle-bowl collisions in acoustic emission. The results have shown that repeatable acoustic results could be obtained but only when a spray nozzle water addition system was used. Acoustic emissions were recorded from a transducer attached to the bowl and an airborne transducer. It was found that the airborne transducer detected very little from the granulation and only experienced small changes throughout the process. The results from the bowl transducer showed that during granulation the frequency content of the acoustic emission shifted towards the lower frequencies. Results from the discrete element model indicate that when larger particles are used the number of collisions the particles experience reduces. This is a result of the volume conservation methodology used in this study, therefore larger particles results in less particles. These simulation results coupled with previous theoretical work on the frequency content of an impacting sphere explain why the frequency content of the acoustic emissions reduces during granule growth. The acoustic system used was also clearly able to identify when large over-wetted granules were present in the system, highlighting its benefit for detecting undesirable operational conditions. High-speed photography was used to study if visual changes in the granule properties could be linked with the changing acoustic emissions. The high speed photography was only possible towards the latter stages of the granulation process and it was found that larger granules produced a higher magnitude of acoustic emission across a broader frequency range. Copyright © 2014 Elsevier B.V. All rights reserved.

  17. Highly efficient and stable white organic light emitting diode base on double recombination zones of phosphorescent blue/orange emitters.

    Science.gov (United States)

    Lee, Seok Jae; Koo, Ja Ryong; Lim, Dong Hwan; Park, Hye Rim; Kim, Young Kwan; Ha, Yunkyoung

    2011-08-01

    We demonstrated efficient and stable white phosphorescent organic light-emitting diodes (OLEDs) with double-emitting layers (D-EMLs), which were comprised of two emissive layers with a hole transport-type host of N,N'-dicarbazolyl-3,5-benzene (mCP) and a electron transport-type host of 2,2',2"-(1,3,5-benzenetryl)tris(1-phenyl)-1H-benzimidazol (TPBi) with blue/orange emitters, respectively. We fabricated two type white devices with single emitting layer (S-EML) and D-EML of orange emitter, maintaining double recombination zone of blue emitter. In addition, the device architecture was developed to confine excitons inside the D-EMLs and to manage triplet excitons by controlling the charge injection. As a result, light-emitting performances of white OLED with D-EMLs were improved and showed the steady CIE coordinates compared to that with S-EML of orange emitter, which demonstrated the maximum luminous efficiency and external quantum efficiency were 21.38 cd/A and 11.09%. It also showed the stable white emission with CIE(x,y) coordinates from (x = 0.36, y = 0.37) at 6 V to (x = 0.33, y = 0.38) at 12 V.

  18. X-ray emission in slow highly charged ion-surface collisions

    International Nuclear Information System (INIS)

    Watanabe, H; Abe, T; Fujita, Y; Sun, J; Takahashi, S; Tona, M; Yoshiyasu, N; Nakamura, N; Sakurai, M; Yamada, C; Ohtani, S

    2007-01-01

    X-rays emitted in the collisions of highly charged ions with a surface have been measured to investigate dissipation schemes of their potential energies. While 8.1% of the potential energy was dissipated in the collisions of He-like I ions with a W surface, 29.1% has been dissipated in the case of He-like Bi ions. The x-ray emissions play significant roles in the dissipation of the potential energies in the interaction of highly charged heavy ions with the surface

  19. Frequencies of micronuclei in bank voles from zones of high radiation at Chernobyl, Ukraine

    Energy Technology Data Exchange (ETDEWEB)

    Rodgers, B.E.; Baker, R.J.

    2000-06-01

    A population of Clethrionomys glareolus (bank vole) from a highly radioactive area within the Chernobyl, Ukraine exclusion zone was sampled in June 1997 and in June and October 1998. Internal radiation doses from radiocesium were estimated to be as high as 8 rads/d. Total dose, which takes into account the internal dose form radiostrontium and the surrounding environment, was estimated to be 15 to 20 rads/d. In contrast, individuals from a reference population lying outside of the exclusion zone registered negligible levels of contamination. The authors used the micronucleus test in a double-blind study to analyze blood samples from 58 individuals. They scored more than 600,000 polychromatic erythrocytes (PCEs) but could not reject the null hypothesis that the frequency of micronucleated PCEs in voles exposed to radiation was equal to the frequency in unexposed voles. Results of their study stand in sharp contrast to earlier reports of increased frequencies of micronuclei in rodents exposed to fallout of the Chernobyl accident, but with radiation doses that were orders of magnitude lower than those reported here. Radio resistance and experimental methods are possible explanations for these differences in the results.

  20. POLARIMETRY AND THE HIGH-ENERGY EMISSION MECHANISMS IN QUASAR JETS: THE CASE OF PKS 1136–135

    International Nuclear Information System (INIS)

    Cara, Mihai; Perlman, Eric S.; Uchiyama, Yasunobu; Cheung, Chi C.; Coppi, Paolo S.; Georganopoulos, Markos; Worrall, Diana M.; Birkinshaw, Mark; Sparks, William B.; Marshall, Herman L.; Stawarz, Lukasz; Begelman, Mitchell C.; O'Dea, Christopher P.; Baum, Stefi A.

    2013-01-01

    Since the discovery of kiloparsec-scale X-ray emission from quasar jets, the physical processes responsible for their high-energy emission have been poorly defined. A number of mechanisms are under active debate, including synchrotron radiation, inverse-Comptonized cosmic microwave background (IC/CMB) emission, and other Comptonization processes. In a number of cases, the optical and X-ray emission of jet regions are inked by a single spectral component, and in those, high-resolution multi-band imaging and polarimetry can be combined to yield a powerful diagnostic of jet emission processes. Here we report on deep imaging photometry of the jet of PKS 1136–135 obtained with the Hubble Space Telescope. We find that several knots are highly polarized in the optical, with fractional polarization Π > 30%. When combined with the broadband spectral shape observed in these regions, this is very difficult to explain via IC/CMB models, unless the scattering particles are at the lowest-energy tip of the electron energy distribution, with Lorentz factor γ ∼ 1, and the jet is also very highly beamed (δ ≥ 20) and viewed within a few degrees of the line of sight. We discuss both the IC/CMB and synchrotron interpretation of the X-ray emission in the light of this new evidence, presenting new models of the spectral energy distribution and also the matter content of this jet. The high polarizations do not completely rule out the possibility of IC/CMB optical-to-X-ray emission in this jet, but they do strongly disfavor the model. We discuss the implications of this finding, and also the prospects for future work

  1. An optimized chemical kinetic mechanism for HCCI combustion of PRFs using multi-zone model and genetic algorithm

    International Nuclear Information System (INIS)

    Neshat, Elaheh; Saray, Rahim Khoshbakhti

    2015-01-01

    Highlights: • A new chemical kinetic mechanism for PRFs HCCI combustion is developed. • New mechanism optimization is performed using genetic algorithm and multi-zone model. • Engine-related combustion and performance parameters are predicted accurately. • Engine unburned HC and CO emissions are predicted by the model properly. - Abstract: Development of comprehensive chemical kinetic mechanisms is required for HCCI combustion and emissions prediction to be used in engine development. The main purpose of this study is development of a new chemical kinetic mechanism for primary reference fuels (PRFs) HCCI combustion, which can be applied to combustion models to predict in-cylinder pressure and exhaust CO and UHC emissions, accurately. Hence, a multi-zone model is developed for HCCI engine simulation. Two semi-detailed chemical kinetic mechanisms those are suitable for premixed combustion are used for n-heptane and iso-octane HCCI combustion simulation. The iso-octane mechanism contains 84 species and 484 reactions and the n-heptane mechanism contains 57 species and 296 reactions. A simple interaction between iso-octane and n-heptane is considered in new mechanism. The multi-zone model is validated using experimental data for pure n-heptane and iso-octane. A new mechanism is prepared by combination of these two mechanisms for n-heptane and iso-octane blended fuel, which includes 101 species and 594 reactions. New mechanism optimization is performed using genetic algorithm and multi-zone model. Mechanism contains low temperature heat release region, which decreases with increasing octane number. The results showed that the optimized chemical kinetic mechanism is capable of predicting engine-related combustion and performance parameters. Also after implementing the optimized mechanism, engine unburned HC and CO emissions predicted by the model are in good agreement with the corresponding experimental data

  2. Comparative estimation of soil and plant pollution in the impact area of air emissions from an aluminium plant after technogenic load reduction.

    Science.gov (United States)

    Evdokimova, Galina A; Mozgova, Natalya P

    2015-01-01

    The work provides a comparative analysis of changes in soil properties in the last 10-13 years along the pollution gradient of air emissions from Kandalaksha aluminium plant in connection with the reduction of their volume. The content of the priority pollutant fluorine (F) in atmospheric precipitation and in the organic horizon of soil in the plant impact zone significantly decreased in 2011-2013 compared to 2001. The aluminium concentrations reduced only in immediate proximity to the plant (2 km). The fluorine, calcium (Ca) and magnesium (Mg) concentrations are higher in liquid phase compared to solid phase thus these elements can migrated to greater distances from the pollution source (up to 15-20 km). Silicon (Si), aluminium (Al), iron (Fe) and phosphorus (P) can be found only in solid phases and in fall-out within the 5 km. The acidity of soil litter reduced by 2 pH units in the proximity to the plot within the 2 km. The zone of maximum soil contamination decreased from 2.5 km to 1.5 km from the emission source, the zones of heavy and moderate pollution reduced by 5 km in connection with the reduction of pollutant emissions in the plant. A high correlation between the fluorine concentrations in vegetables and litter was found. Higher fluorine concentrations in the soil result in its accumulation in plants. Mosses accumulate fluorine most intensively.

  3. A high-resolution air pollutants emission inventory in 2013 for the Beijing-Tianjin-Hebei region, China

    Science.gov (United States)

    Qi, Ji; Zheng, Bo; Li, Meng; Yu, Fang; Chen, Chuchu; Liu, Fei; Zhou, Xiafei; Yuan, Jing; Zhang, Qiang; He, Kebin

    2017-12-01

    We developed a high-resolution Beijing-Tianjin-Hebei (BTH) regional air pollutants emission inventory for the year 2013. The inventory was established using a bottom-up approach based on facility-level activity data obtained from multiple data sources. The estimates from the BTH 2013 emission inventory show that the total emissions of SO2, NOX, PM2.5, PM10, CO, NMVOC, NH3, BC, and OC were 2,305, 2,686, 1,090, 1,494, 20,567, 2,207, 623, 160, and 254 Gg, respectively. The industry sector is the largest emissions source for SO2, NOX, PM2.5, PM10, CO, and NMVOC in the BTH region, contributing 72.6%, 43.7%, 59.6%, 64.7%, 60.3%, and 70.4% of the total emissions, respectively. Power plants contributed 11.8% and 23.3% of the total SO2 and NOX emissions, respectively. The transportation sector contributed 28.9% of the total NOX emissions. Emissions from the residential sector accounted for 31.3%, 21.5%, 46.6% and 71.7% of the total PM2.5, NMVOC, BC and OC emissions, respectively. In addition, more than 90% of the total NH3 emissions originate from the agriculture sector, with 44.2% from fertilizer use and 47.7% from livestock. The spatial distribution results illustrate that air pollutant emissions are mainly distributed over the eastern and southern BTH regions. Beijing, Tianjin, Shijiazhuang, Tangshan and Handan are the major contributors of air pollutants. The major NMVOC species in the BTH region are ethylene, acetylene, ethane and toluene. Ethylene is the biggest contributor in Tianjin and Hebei. The largest contributor in Beijing is toluene. There is relatively low uncertainty in SO2 and NOX emission estimates, medium uncertainty in PM2.5, PM10 and CO emission estimates, and high uncertainties in VOC, NH3, BC and OC emission estimates. The proposed policy recommendations, based on the BTH 2013 emission inventory, would be helpful to develop strategies for air pollution control.

  4. Spectroscopic investigations of hard x-ray emission from 120 ps laser-produced plasmas at intensities near 1017 W cm-2

    International Nuclear Information System (INIS)

    Dunn, J.; Young, B.K.F.; Osterheld, A.L.; Foord, M.E.; Walling, R.S.; Stewart, R.E.; Faenov, A.Y.

    1995-11-01

    Spectroscopic investigations of the x-ray emission of plasmas heated by 120 ps, frequency doubled pulses from the JANUS Nd: glass laser are presented. High Z K-shell spectra emitted from slab targets heated to near 10 17 W cm -2 intensity are investigated. High resolution (γ/Δγ>5000) x-ray spectra of multicharged ions of H-like Ti, Co, Ni, Cu, and also H-like Sc in the spectral range 1.5--3.0 angstrom are obtained in single laser shots using a spherically bent Mica crystal spectrograph with a 186 mm radius of curvature. The spectra- have one dimensional spatial resolution of about 25μm and indicate that the size of the emission zone of the resonance, transitions is 2 keV and density∼10 22 cm -3 . These experiments demonstrate that with modest laser energy, plasmas heated by high-intensity 120 ps lasers provide a very bright source of hard ∼8 keV x-ray emission

  5. Investigation into some regularities in acoustic emission during deformation of the 16 GNMA steel

    International Nuclear Information System (INIS)

    Chelyshev, N.A.; Chervov, G.A.; Petrov, V.I.; Yakovenko, V.S.; Kazakov, V.V.

    1981-01-01

    A device with variable band of transmission and regulated width of emission band (3-20 kHz) is the most optimal variant of acoustic emission recorder. Change of signal registration frequency of acoustic emission results in change of both qualitative and quantitative peculiarities of summary emission during deformation. A zone of elastic deformation transition to elastic-plastic for the given steel is well marked out according to the data of summary acoustic emission and intensity of signals. Application of devices with variable registration frequency requires usage of wide-band transformers [ru

  6. High Energy Emission of Symbiotic Recurrent Novae: RS Oph and V407 Cyg

    Directory of Open Access Journals (Sweden)

    Hernanz M.

    2012-06-01

    Full Text Available Recurrent novae occurring in symbiotic binaries are candidate sources of high energy photons, reaching GeV energies. Such emission is a consequence of particle acceleration leading to pion production. the shock between matter ejected by the white dwarf, undergoing a nova explosion, and the wind from the red giant companion are responsible for such a process, which mimics a supernova remnant but with much smaller energetic output and much shorter time scales. Inverse Compton can also be responsible for high energy emission. Recent examples are V407 Cyg, detected by Fermi, and RS Oph, which unfortunately exploded in 2006, before Fermi was launched.

  7. Electromagnetic exploration in high-salinity groundwater zones: case studies from volcanic and soft sedimentary sites in coastal Japan

    Science.gov (United States)

    Suzuki, Koichi; Kusano, Yukiko; Ochi, Ryota; Nishiyama, Nariaki; Tokunaga, Tomochika; Tanaka, Kazuhiro

    2017-01-01

    Estimating the spatial distribution of groundwater salinity in coastal plain regions is becoming increasingly important for site characterisation and the prediction of hydrogeological environmental conditions resulting from radioactive waste disposal and underground CO2 storage. In previous studies of the freshwater-saltwater interface, electromagnetic methods were used for sites characterised by unconsolidated deposits or Neocene soft sedimentary rocks. However, investigating the freshwater-saltwater interface in hard rock sites (e.g. igneous areas) is more complex, with the permeability of the rocks greatly influenced by fractures. In this study, we investigated the distribution of high-salinity groundwater at two volcanic rock sites and one sedimentary rock site, each characterised by different hydrogeological features. Our investigations included (1) applying the controlled source audio-frequency magnetotelluric (CSAMT) method and (2) conducting laboratory tests to measure the electrical properties of rock core samples. We interpreted the 2D resistivity sections by referring to previous data on geology and geochemistry of groundwater. At the Tokusa site, an area of inland volcanic rocks, low resistivity zones were detected along a fault running through volcanic rocks and shallow sediments. The results suggest that fluids rise through the Tokusa-Jifuku Fault to penetrate shallow sediments in a direction parallel to the river, and some fluids are diluted by rainwater. At the Oki site, a volcanic island on a continental shelf, four resistivity zones (in upward succession: low, high, low and high) were detected. The results suggest that these four zones were formed during a transgression-regression cycle caused by the last glacial period. At the Saijo site, located on a coastal plain composed of thick sediments, we observed a deep low resistivity zone, indicative of fossil seawater remnant from a transgression after the last glacial period. The current coastal

  8. Emissions from heavy current carrying high density plasma and their diagnostics

    International Nuclear Information System (INIS)

    Hirano, Katsumi

    1987-06-01

    Workshop on ''Emissions from heavy current carrying high density plasma and diagnostics'' was held at Institute of Plasma Physics, Nagoya University on 3. and 4. December 1986 under a collaborating research Program. The workshop was attended by 43 researchers from 19 labolatories. A total of 22 papers were submitted and are presented in these proceedings. The largest group of papers was that on soft X-ray emission. It seems this topic is a foremost interest for groups which engaged in research of the Z pinch and the plasma focus. A variety of problems in pinched dense plasmas, namely spectroscopy, diagnostics, pinch dynamics, and related engineering aspects were also discussed. (author)

  9. Achieving Tier 4 Emissions in Biomass Cookstoves

    Energy Technology Data Exchange (ETDEWEB)

    Marchese, Anthony [Colorado State Univ., Fort Collins, CO (United States); DeFoort, Morgan [Colorado State Univ., Fort Collins, CO (United States); Gao, Xinfeng [Colorado State Univ., Fort Collins, CO (United States); Tryner, Jessica [Colorado State Univ., Fort Collins, CO (United States); Dryer, Frederick L. [Princeton Univ., Princeton, NJ (United States); Haas, Francis [Princeton Univ., Princeton, NJ (United States); Lorenz, Nathan [Envirofit International, Fort Collins, CO (United States)

    2018-03-13

    Previous literature on top-lit updraft (TLUD) gasifier cookstoves suggested that these stoves have the potential to be the lowest emitting biomass cookstove. However, the previous literature also demonstrated a high degree of variability in TLUD emissions and performance, and a lack of general understanding of the TLUD combustion process. The objective of this study was to improve understanding of the combustion process in TLUD cookstoves. In a TLUD, biomass is gasified and the resulting producer gas is burned in a secondary flame located just above the fuel bed. The goal of this project is to enable the design of a more robust TLUD that consistently meets Tier 4 performance targets through a better understanding of the underlying combustion physics. The project featured a combined modeling, experimental and product design/development effort comprised of four different activities: Development of a model of the gasification process in the biomass fuel bed; Development of a CFD model of the secondary combustion zone; Experiments with a modular TLUD test bed to provide information on how stove design, fuel properties, and operating mode influence performance and provide data needed to validate the fuel bed model; Planar laser-induced fluorescence (PLIF) experiments with a two-dimensional optical test bed to provide insight into the flame dynamics in the secondary combustion zone and data to validate the CFD model; Design, development and field testing of a market ready TLUD prototype. Over 180 tests of 40 different configurations of the modular TLUD test bed were performed to demonstrate how stove design, fuel properties and operating mode influences performance, and the conditions under which Tier 4 emissions are obtainable. Images of OH and acetone PLIF were collected at 10 kHz with the optical test bed. The modeling and experimental results informed the design of a TLUD prototype that met Tier 3 to Tier 4 specifications in emissions and Tier 2 in efficiency. The

  10. A WRF-Chem model study of the impact of VOCs emission of a huge petro-chemical industrial zone on the summertime ozone in Beijing, China

    Science.gov (United States)

    Wei, Wei; Lv, Zhao Feng; Li, Yue; Wang, Li Tao; Cheng, Shuiyuan; Liu, Huan

    2018-02-01

    In China, petro-chemical manufacturing plants generally gather in the particular industrial zone defined as PIZ in some cities, and distinctly influence the air quality of these cities for their massive VOCs emissions. This study aims to quantify the local and regional impacts of PIZ VOCs emission and its relevant reduction policy on the surface ozone based on WRF-Chem model, through the case study of Beijing. Firstly, the model simulation under the actual precursors' emissions over Beijing region for July 2010 is conducted and evaluated, which meteorological and chemical predictions both within the thresholds for satisfactory model performance. Then, according to simulated H2O2/HNO3 ratio, the nature of photochemical ozone formation over Beijing is decided, the VOCs-sensitive regime over the urban areas, NOx-sensitive regime over the northern and western rural areas, and both VOCssbnd and NOx-mixed sensitive regime over the southern and eastern rural areas. Finally, a 30% VOCs reduction scenario (RS) and a 100% VOCs reduction scenario (ZS) for Beijing PIZ are additional simulated by WRF-Chem. The sensitivity simulations imply that the current 30% reduction policy would bring about an O3 increase in the southern and western areas (by +4.7 ppb at PIZ site and +2.1 ppb at LLH station), and an O3 decrease in the urban center (by -1.7 ppb at GY station and -2.5 ppb at DS station) and in the northern and eastern areas (by -1.2 ppb at MYX station), mainly through interfering with the circulation of atmospheric HOx radicals. While the contribution of the total VOCs emission of PIZ to ozone is greatly prominent in the PIZ and its surrounding areas along south-north direction (12.7% at PIZ site on average), but slight in the other areas of Beijing (<3% in other four stations on average).

  11. 33 CFR 165.1141 - Safety Zone; San Clemente 3 NM Safety Zone, San Clemente Island, CA.

    Science.gov (United States)

    2010-07-01

    ...) Location. The following area is a safety zone: All waters of the Pacific Ocean surrounding San Clemente Island, from surface to bottom, extending from the high tide line on the island seaward 3 NM. The zone... 3 NM from the high tide line to 33°02.82′ N, 118°30.65′ W; thence 33°01.29′ N, 118°33.88′ W; thence...

  12. Corrosion behavior in high heat input welded heat-affected zone of Ni-free high-nitrogen Fe–18Cr–10Mn–N austenitic stainless steel

    International Nuclear Information System (INIS)

    Moon, Joonoh; Ha, Heon-Young; Lee, Tae-Ho

    2013-01-01

    The pitting corrosion and interphase corrosion behaviors in high heat input welded heat-affected zone (HAZ) of a metastable high-nitrogen Fe–18Cr–10Mn–N austenitic stainless steel were explored through electrochemical tests. The HAZs were simulated using Gleeble simulator with high heat input welding condition of 300 kJ/cm and the peak temperature of the HAZs was changed from 1200 °C to 1350 °C, aiming to examine the effect of δ-ferrite formation on corrosion behavior. The electrochemical test results show that both pitting corrosion resistance and interphase corrosion resistance were seriously deteriorated by δ-ferrite formation in the HAZ and their aspects were different with increasing δ-ferrite fraction. The pitting corrosion resistance was decreased by the formation of Cr-depleted zone along δ-ferrite/austenite (γ) interphase resulting from δ-ferrite formation; however it didn't depend on δ-ferrite fraction. The interphase corrosion resistance depends on the total amount of Cr-depleted zone as well as ferrite area and thus continuously decreased with increasing δ-ferrite fraction. The different effects of δ-ferrite fraction on pitting corrosion and interphase corrosion were carefully discussed in terms of alloying elements partitioning in the HAZ based on thermodynamic consideration. - Highlights: • Corrosion behavior in the weld HAZ of high-nitrogen austenitic alloy was studied. • Cr 2 N particle was not precipitated in high heat input welded HAZ of tested alloy. • Pitting corrosion and interphase corrosion show a different behavior. • Pitting corrosion resistance was affected by whether or not δ-ferrite forms. • Interphase corrosion resistance was affected by the total amount of δ-ferrite

  13. Isoprenoid emission variation of Norway spruce across a European latitudinal transect

    Science.gov (United States)

    van Meeningen, Ylva; Wang, Min; Karlsson, Tomas; Seifert, Ana; Schurgers, Guy; Rinnan, Riikka; Holst, Thomas

    2017-12-01

    Norway spruce (Picea abies) is one of the dominant tree species in the European boreal zone with the capacity to grow over large areas within Europe. It is an important emitter of biogenic volatile organic compounds (BVOCs), which can act as precursors of photochemical smog and ozone and contribute to the formation and growth of secondary organic aerosols (SOA) in the atmosphere. Isoprenoid emissions were measured from Norway spruce trees at seven different sites, distributed from Ljubljana in Slovenia to Piikkiö in Finland. Four of the sites were part of a network of genetically identical spruce trees and contained two separate provenances. The remaining three sites were part of other networks which have been used to conduct studies in the European boreal zone. There were minimal differences in the standardized emission rates between sites and across latitudes. The emission profile differed between provenances and sites, but there were not any distinct patterns which could be connected to a change in latitude. By using genetically identical trees and comparing the emission rates between sites and with genetically different trees, it was observed that the emission patterns were mostly influenced by genetics. But in order to confirm this possible stability of the relative emission profile based on genetics, more studies need to be performed. The effects of branch height, season and variation between years on observed emission pattern variations were also investigated. There were indications of potential influences of all three factors. However, due to different experimental setups between measurement campaigns, it is difficult to draw any robust conclusions.

  14. The Sorong Fault Zone, Indonesia: Mapping a Fault Zone Offshore

    Science.gov (United States)

    Melia, S.; Hall, R.

    2017-12-01

    The Sorong Fault Zone is a left-lateral strike-slip fault zone in eastern Indonesia, extending westwards from the Bird's Head peninsula of West Papua towards Sulawesi. It is the result of interactions between the Pacific, Caroline, Philippine Sea, and Australian Plates and much of it is offshore. Previous research on the fault zone has been limited by the low resolution of available data offshore, leading to debates over the extent, location, and timing of movements, and the tectonic evolution of eastern Indonesia. Different studies have shown it north of the Sula Islands, truncated south of Halmahera, continuing to Sulawesi, or splaying into a horsetail fan of smaller faults. Recently acquired high resolution multibeam bathymetry of the seafloor (with a resolution of 15-25 meters), and 2D seismic lines, provide the opportunity to trace the fault offshore. The position of different strands can be identified. On land, SRTM topography shows that in the northern Bird's Head the fault zone is characterised by closely spaced E-W trending faults. NW of the Bird's Head offshore there is a fold and thrust belt which terminates some strands. To the west of the Bird's Head offshore the fault zone diverges into multiple strands trending ENE-WSW. Regions of Riedel shearing are evident west of the Bird's Head, indicating sinistral strike-slip motion. Further west, the ENE-WSW trending faults turn to an E-W trend and there are at least three fault zones situated immediately south of Halmahera, north of the Sula Islands, and between the islands of Sanana and Mangole where the fault system terminates in horsetail strands. South of the Sula islands some former normal faults at the continent-ocean boundary with the North Banda Sea are being reactivated as strike-slip faults. The fault zone does not currently reach Sulawesi. The new fault map differs from previous interpretations concerning the location, age and significance of different parts of the Sorong Fault Zone. Kinematic

  15. High-Color-Quality White Top-Emitting Organic Electroluminescent Devices Based on Both Exciton and Electroplex Emission

    Science.gov (United States)

    Zhang, Mingxiao; Chen, Zhijian; Xiao, Lixin; Qu, Bo; Gong, Qihuang

    2011-08-01

    A high-color-quality white top-emitting organic electroluminescent device (TOLED) with a simple structure was fabricated using both exciton and electroplex emission. White emission was achieved by combining the exciton emission of 4,4'-bis(2,2'-diphenylvinyl)-1,1'-biphenyl (DPVBi) and the broad band emission of electroplex generated between DPVBi and 2,9-dimethyl-4,7-diphenyl-1,10-phenanthroline (BCP). The white emission spectra showed excellent stability at different bias voltages. By inserting a blend film of DPVBi:BCP and adjusting the ratio of DPVBi to BCP in the blend film, the CIE coordinates of the white emission can be tuned to (0.30, 0.33) and the electroluminescence efficiency can also be enhanced.

  16. Reactivity and neutron emission measurements of highly burnt PWR fuel rod samples

    International Nuclear Information System (INIS)

    Murphy, M.F.; Jatuff, F.; Grimm, P.; Seiler, R.; Brogli, R.; Meier, G.; Berger, H.-D.; Chawla, R.

    2006-01-01

    Fuel rods with burnup values beyond 50 GWd/t are characterised by relatively large amounts of fission products and a high abundance of major and minor actinides. Of particular interest is the change in the reactivity of the fuel as a function of burnup and the capability of modern codes to predict this change. In addition, the neutron emission from burnt fuel has important implications for the design of transport and storage facilities. Measurements have been made of the reactivity effects and the neutron emission rates of highly burnt uranium oxide and mixed oxide fuel rod samples coming from a pressurised water reactor (PWR). The reactivity measurements have been made in a PWR lattice in the PROTEUS zero-energy reactor moderated in turn with: water, a water and heavy water mixture and water containing boron. A combined transport flask and sample changer was used to insert the 400 mm long burnt fuel rod segments into the reactor. Both control rod compensation and reactor period methods were used to determine the reactivities of the samples. For the range of burnup values investigated, an interesting exponential relationship has been found between the neutron emission rate and the measured reactivity

  17. Fully Premixed Low Emission, High Pressure Multi-Fuel Burner

    Science.gov (United States)

    Nguyen, Quang-Viet (Inventor)

    2012-01-01

    A low-emissions high-pressure multi-fuel burner includes a fuel inlet, for receiving a fuel, an oxidizer inlet, for receiving an oxidizer gas, an injector plate, having a plurality of nozzles that are aligned with premix face of the injector plate, the plurality of nozzles in communication with the fuel and oxidizer inlets and each nozzle providing flow for one of the fuel and the oxidizer gas and an impingement-cooled face, parallel to the premix face of the injector plate and forming a micro-premix chamber between the impingement-cooled face and the in injector face. The fuel and the oxidizer gas are mixed in the micro-premix chamber through impingement-enhanced mixing of flows of the fuel and the oxidizer gas. The burner can be used for low-emissions fuel-lean fully-premixed, or fuel-rich fully-premixed hydrogen-air combustion, or for combustion with other gases such as methane or other hydrocarbons, or even liquid fuels.

  18. ZONING OF COASTAL AREA FOR MARINE AQUACULTURE Š PRESENT SITUATIONS AND PROBLEMS

    Directory of Open Access Journals (Sweden)

    Lav Bavčević

    2001-12-01

    Full Text Available We already acepted that Croatian economical and geopolitical possition can bee improved only with better utilization of coastal area. Under these conditions mariculture also makes a part od sea master plan because demands for mariculture are focused on clean environmental conditions to obtain economic benefits. Increased pressure to the coastal area is global trend and if not planed and organized can provoke conflicts and can affect further development. Under these condition, marine aquaculture is frequent subject of many discussion focused on the environmental impact. Conflict of different interest in coastal area with no argumentation is putting marine aquaculture in worst position related with tourism and industry. Hard argumentations is laying in noneadequate frame of work in some facilities and to take advantake competitors are preasenting marine aquaculture in worst picture. Marine aquaculture product has to be health product, which can be completely damaged because of non-responsible approach of other activity. Mariculture also can suffer from self-pollution as for example tourism and must be well planed and managed. Fecal pollution from towns, pollution from bad controlled tourists activity, industry, influence of intensive and non controlled agriculture in coast line, are also potential danger for quality of all sea products and also cultured products from marine aquaculture. High quality of marine products can be obtained by zoning of coastal area, and in concept of these zoning it is necessary to define the zones for marine aquaculture. Procedure of zoning has to be divided in three steps: deetrmination of present status of area, definition of shore land for making mariculture related shore infrastructure and definitions of areas suitable for mariculture with limits of production. These can make positive situations with avoiding conflicts in exploitation of common resources in future. Zone for marine aquaculture has to be controlled

  19. Component, Disperse and Morphological Composition of Ambient Air Dust Contamination in the Zones of Mining-Processing Enterprises

    Science.gov (United States)

    Zagorodnov, S. Y.; Kokoulina, A. A.; Klein, S. V.

    2017-07-01

    The article presents the results of complex studies of dust emissions of the mining and processing complex. The main technological processes and the sources operation that produce intense dust emissions are determined. It has been proved that dust emissions of the investigated enterprise contain fine dust dangerous for human health. The results of the studies allowed us to detect precisely the dispersed composition of dust emissions, with the separation of PM10 and PM2.5 fractions, the chemical composition of the dust, and the shape of the particles. Thus, operating with obtained data on dispersed composition of the dust emissions and the specified sedimentation coefficient, we were able to calculate the dispersion of all solid particles and separately the PM10 and PM2.5 at the location of the enterprise. The dust exposure of the population at the targeted zones has been also determined. The obtained concentration values were used for assess health risk level to population living at the border of sanitary protection zone of the enterprise. Due to the obtained results, the enterprise was provided with recommendations on the inclusion of fine particles PM 10 and PM 2.5 in the production control program. In the case of increasing its production capacity was recommended to introduce the environmental measures for the reduction of emission of the finely dispersed fractions PM10 and PM 2.5.

  20. Field emission and high voltage cleaning of particulate contaminants on extended metallic surfaces

    International Nuclear Information System (INIS)

    Tan, J.; Bonin, B.; Safa, H.

    1996-01-01

    The vacuum insulation properties of extended metallic surfaces depends strongly on their cleanliness. The usual technique to reduce electronic field emission from such surfaces consists in exposing them to very high electric fields during limited periods of time. This kind of processing also reduces the occurrence of vacuum breakdown. The processing of the surface is generally believed to be due to a thermomechanical destruction of the emitting sites, initiated by the emission itself. Comparison of the electric forces vs adherence forces which act on dust particles lying on the surface shows that the processing could also be due simply to the mechanical removal of the dust particles, with a subsequent reduction of field emission from the contaminated surface. (author)

  1. Fracto-mechanoluminescent light emission of EuD4TEA-PDMS composites subjected to high strain-rate compressive loading

    Science.gov (United States)

    Ryu, Donghyeon; Castaño, Nicolas; Bhakta, Raj; Kimberley, Jamie

    2017-08-01

    The objective of this study is to understand light emission characteristics of fracto-mechanoluminescent (FML) europium tetrakis(dibenzoylmethide)-triethylammonium (EuD4TEA) crystals under high strain-rate compressive loading. As a sensing material that can play a pivotal role for the self-powered impact sensor technology, it is important to understand transformative light emission characteristics of the FML EuD4TEA crystals under high strain-rate compressive loading. First, EuD4TEA crystals were synthesized and embedded into polydimethylsiloxane (PDMS) elastomer to fabricate EuD4TEA-PDMS composite test specimens. Second, the prepared EuD4TEA-PDMS composites were tested using the modified Kolsky bar setup equipped with a high-speed camera. Third, FML light emission was captured to yield 12 bit grayscale video footage, which was processed to quantify the FML light emission. Finally, quantitative parameters were generated by taking into account pixel values and population of pixels of the 12 bit grayscale images to represent FML light intensity. The FML light intensity was correlated with high strain-rate compressive strain and strain rate to understand the FML light emission characteristics under high strain-rate compressive loading that can result from impact occurrences.

  2. Origin of fine dust in urban environmental zones - Evidence from element patterns received by dichotomous collection and INAA

    International Nuclear Information System (INIS)

    Weckwerth, G.

    2010-01-01

    In order to fulfil the EU-limitations of fine dust and traffic-produced gases Cologne installed 2008 one of the first German environmental zones, from which stepwise vehicles with too high emissions will be locked out. Verification of effectiveness and the research on further strategies to reduce fine dust are studied as promising applications of a method on discrimination of aerosol components from different origins (). New measurements in Cologne gave several implications on supports, especially in connection with traffic abrasion from brakes, tires and rails.

  3. Measuring the coherence properties of light emission from laser-plasma interactions. Final report

    International Nuclear Information System (INIS)

    Batha, S.H.

    1998-01-01

    Several detrimental instabilities can be excited when a high-intensity laser interacts with plasma. The temporal evolution and spectra of the scattered light emitted by many of these instabilities are used to characterize the instabilities and to benchmark theories. It has been difficult to image the emission region with sufficient resolution to make quantitative comparisons with theory. Direct measurement of the emission region would yield information on ponderomotive steepening phenomena, the true emission zone of convective instabilities, and on the saturation of absolute instabilities. The increase in laser intensity caused by the filamentation instability is conjectured to elevate the levels of parametric instabilities found in high-energy laser-plasma interactions. Because the diameter of the filaments is very small (on the order of 10 microm), it is impossible to image the emission sites directly and either to prove or to disprove this conjecture. The research reported here examines an alternate method of measuring the emission region of scattered light from parametric instabilities. This report provides a brief background of coherence theory by defining the relevant parameters in Section 2. A concrete example of the effect that multiple scattering sites would have on the proposed measurement is provided in Section 3. The following section briefly describes experiments that might be able to demonstrate the proposed technique. The conclusion raises the issue of coherence and its effect on the expected angular distribution of scattering light from parametric instabilities

  4. High resolution Fresnel zone plate laser alignment system

    International Nuclear Information System (INIS)

    Bressler, V.E.; Fischer, G.E.; Ruland, R.E.; Wang, T.

    1992-03-01

    The existing Fresnel zone plate laser alignment system is currently being extended and upgraded for the Final Focus Test Beam (FFTB). Previously, the resolution of this system has been several tens of micrometers. After the upgrade, the resolution will be a few micrometers. Details of the upgrade as well as simulation and experimental results will be presented

  5. Infrared emission high spectral resolution atlas of the stratospheric limb

    Science.gov (United States)

    Maguire, William C.; Kunde, Virgil G.; Herath, Lawrence W.

    1989-01-01

    An atlas of high resolution infrared emission spectra identifies a number of gaseous atmospheric features significant to stratospheric chemistry in the 770-900/cm and 1100-1360/cm regions at six zenith angles from 86.7 to 95.1 deg. A balloon-borne Michelson interferometer was flown to obtain about 0.03/cm resolution spectra. Two 10/cm extracts are presented here.

  6. Subnanosecond breakdown development in high-voltage pulse discharge: Effect of secondary electron emission

    Science.gov (United States)

    Alexandrov, A. L.; Schweigert, I. V.; Zakrevskiy, Dm. E.; Bokhan, P. A.; Gugin, P.; Lavrukhin, M.

    2017-10-01

    A subnanosecond breakdown in high-voltage pulse discharge may be a key tool for superfast commutation of high power devices. The breakdown in high-voltage open discharge at mid-high pressure in helium was studied in experiment and in kinetic simulations. The kinetic model of electron avalanche development was constructed, based on PIC-MCC simulations, including dynamics of electrons, ions and fast helium atoms, produced by ions scattering. Special attention was paid to electron emission processes from cathode, such as: photoemission by Doppler-shifted resonant photons, produced in excitation processes involving fast atoms; electron emission by ions and fast atoms bombardment of cathode; the secondary electron emission (SEE) by hot electrons from bulk plasma. The simulations show that the fast atoms accumulation is the main reason of emission growth at the early stage of breakdown, but at the final stage, when the voltage on plasma gap diminishes, namely the SEE is responsible for subnanosecond rate of current growth. It was shown that the characteristic time of the current growth can be controlled by the SEE yield. The influence of SEE yield for three types of cathode material (titanium, SiC, and CuAlMg-alloy) was tested. By changing the pulse voltage amplitude and gas pressure, the area of existence of subnanosecond breakdown is identified. It is shown that in discharge with SiC and CuAlMg-alloy cathodes (which have enhanced SEE) the current can increase with a subnanosecond characteristic time value as small as τs = 0.4 ns, for the pulse voltage amplitude of 5÷12 kV. An increase of gas pressure from 15 Torr to 30 Torr essentially decreases the time of of current front growth, whereas the pulse voltage variation weakly affects the results.

  7. Application value of different transformation zone types and its genetic relationship with high-risk HPV type in diagnosis and therapy of cervical disease.

    Science.gov (United States)

    Chen, Yan; Zhou, Jia-De

    2015-01-01

    This study aims to discuss the influence of different types of transformation zone (TZ) on positive surgical margin of loop electrosurgical excision procedure (LEEP) and the significance of infection of different genetic high-risk HPV for cervical intraepithelial neoplasm. The clinical data of patients who had CIN2+ and received LEEP during January to December 2013 was investigated. The conditions of positive surgical margin of patients of different transformation zone (type I, II, III) were analyzed. The clinical high-risk types of HPV were divided into three groups, including A5/6, A7 and A9, compared with the pathological conditions of pre-operation and post-operation of the patients in respective group. The results indicated that type III transformation zone is more likely to cause positive cutting margin. For CIN2+ patients, sensitivity and specificity are 0.89% and 79.56% in group A5/6, and negative and positive predicted value (NPV, PPV) are 40% and 5%. The sensitivity, specificity, NPV, PPV in group A7 is 12.5%, 44.08%, 29.49% and 21.21%, respectively. The sensitivity, specificity, NPV, PPV in group A9 is 88.99%, 87.09%, 85.26%, 81.51%, respectively. Transformation zone type was correlated positively with positive cutting margin percentage (r = 0.8732, P zone is more likely to cause pathological upgrades. In conclusion, different types of transformation zone and high-risk HPV have clinical significance in causing positive cutting margin of surgery and disease extent.

  8. High stresses stored in fault zones: example of the Nojima fault (Japan)

    Science.gov (United States)

    Boullier, Anne-Marie; Robach, Odile; Ildefonse, Benoît; Barou, Fabrice; Mainprice, David; Ohtani, Tomoyuki; Fujimoto, Koichiro

    2018-04-01

    During the last decade pulverized rocks have been described on outcrops along large active faults and attributed to damage related to a propagating seismic rupture front. Questions remain concerning the maximal lateral distance from the fault plane and maximal depth for dynamic damage to be imprinted in rocks. In order to document these questions, a representative core sample of granodiorite located 51.3 m from the Nojima fault (Japan) that was drilled after the Hyogo-ken Nanbu (Kobe) earthquake is studied by using electron backscattered diffraction (EBSD) and high-resolution X-ray Laue microdiffraction. Although located outside of the Nojima damage fault zone and macroscopically undeformed, the sample shows pervasive microfractures and local fragmentation. These features are attributed to the first stage of seismic activity along the Nojima fault characterized by laumontite as the main sealing mineral. EBSD mapping was used in order to characterize the crystallographic orientation and deformation microstructures in the sample, and X-ray microdiffraction was used to measure elastic strain and residual stresses on each point of the mapped quartz grain. Both methods give consistent results on the crystallographic orientation and show small and short wavelength misorientations associated with laumontite-sealed microfractures and alignments of tiny fluid inclusions. Deformation microstructures in quartz are symptomatic of the semi-brittle faulting regime, in which low-temperature brittle plastic deformation and stress-driven dissolution-deposition processes occur conjointly. This deformation occurred at a 3.7-11.1 km depth interval as indicated by the laumontite stability domain. Residual stresses are calculated from deviatoric elastic strain tensor measured using X-ray Laue microdiffraction using the Hooke's law. The modal value of the von Mises stress distribution is at 100 MPa and the mean at 141 MPa. Such stress values are comparable to the peak strength of a

  9. High stresses stored in fault zones: example of the Nojima fault (Japan

    Directory of Open Access Journals (Sweden)

    A.-M. Boullier

    2018-04-01

    Full Text Available During the last decade pulverized rocks have been described on outcrops along large active faults and attributed to damage related to a propagating seismic rupture front. Questions remain concerning the maximal lateral distance from the fault plane and maximal depth for dynamic damage to be imprinted in rocks. In order to document these questions, a representative core sample of granodiorite located 51.3 m from the Nojima fault (Japan that was drilled after the Hyogo-ken Nanbu (Kobe earthquake is studied by using electron backscattered diffraction (EBSD and high-resolution X-ray Laue microdiffraction. Although located outside of the Nojima damage fault zone and macroscopically undeformed, the sample shows pervasive microfractures and local fragmentation. These features are attributed to the first stage of seismic activity along the Nojima fault characterized by laumontite as the main sealing mineral. EBSD mapping was used in order to characterize the crystallographic orientation and deformation microstructures in the sample, and X-ray microdiffraction was used to measure elastic strain and residual stresses on each point of the mapped quartz grain. Both methods give consistent results on the crystallographic orientation and show small and short wavelength misorientations associated with laumontite-sealed microfractures and alignments of tiny fluid inclusions. Deformation microstructures in quartz are symptomatic of the semi-brittle faulting regime, in which low-temperature brittle plastic deformation and stress-driven dissolution-deposition processes occur conjointly. This deformation occurred at a 3.7–11.1 km depth interval as indicated by the laumontite stability domain. Residual stresses are calculated from deviatoric elastic strain tensor measured using X-ray Laue microdiffraction using the Hooke's law. The modal value of the von Mises stress distribution is at 100 MPa and the mean at 141 MPa. Such stress values are comparable to

  10. First Top-Down Estimates of Anthropogenic NOx Emissions Using High-Resolution Airborne Remote Sensing Observations

    Science.gov (United States)

    Souri, Amir H.; Choi, Yunsoo; Pan, Shuai; Curci, Gabriele; Nowlan, Caroline R.; Janz, Scott J.; Kowalewski, Matthew G.; Liu, Junjie; Herman, Jay R.; Weinheimer, Andrew J.

    2018-03-01

    A number of satellite-based instruments have become an essential part of monitoring emissions. Despite sound theoretical inversion techniques, the insufficient samples and the footprint size of current observations have introduced an obstacle to narrow the inversion window for regional models. These key limitations can be partially resolved by a set of modest high-quality measurements from airborne remote sensing. This study illustrates the feasibility of nitrogen dioxide (NO2) columns from the Geostationary Coastal and Air Pollution Events Airborne Simulator (GCAS) to constrain anthropogenic NOx emissions in the Houston-Galveston-Brazoria area. We convert slant column densities to vertical columns using a radiative transfer model with (i) NO2 profiles from a high-resolution regional model (1 × 1 km2) constrained by P-3B aircraft measurements, (ii) the consideration of aerosol optical thickness impacts on radiance at NO2 absorption line, and (iii) high-resolution surface albedo constrained by ground-based spectrometers. We characterize errors in the GCAS NO2 columns by comparing them to Pandora measurements and find a striking correlation (r > 0.74) with an uncertainty of 3.5 × 1015 molecules cm-2. On 9 of 10 total days, the constrained anthropogenic emissions by a Kalman filter yield an overall 2-50% reduction in polluted areas, partly counterbalancing the well-documented positive bias of the model. The inversion, however, boosts emissions by 94% in the same areas on a day when an unprecedented local emissions event potentially occurred, significantly mitigating the bias of the model. The capability of GCAS at detecting such an event ensures the significance of forthcoming geostationary satellites for timely estimates of top-down emissions.

  11. X-ray emission in collisions of highly charged I, Pr, Ho, and Bi ions with a W surface

    International Nuclear Information System (INIS)

    Watanabe, H.; Tona, M.; Ohtani, S.; Sun, J.; Nakamura, N.; Yamada, C.; Yoshiyasu, N.; Sakurai, M.

    2007-01-01

    X-ray emission yields, which are defined as the total number of emitted x-ray photons per incident ion, and dissipated fractions of potential energies through x-ray emission have been measured for slow highly charged ions of I, Pr, Ho, and Bi colliding with a W surface. A larger amount of potential energy was consumed for the x-ray emission with increasing the atomic number and the charge state. The present measurements show that x-ray emission is one of the main decay channels of hollow atoms produced in collisions of very highly charged ions of heavy elements

  12. Emission Modeling of an Interturbine Burner Based on Flameless Combustion

    NARCIS (Netherlands)

    Perpignan, A.A.V.; Talboom, M.G.; Levy, Yeshayahou; Gangoli Rao, A.

    2018-01-01

    Since its discovery, the flameless combustion (FC) regime has been a promising alternative to reduce pollutant emissions of gas turbine engines. This combustion mode is characterized by well-distributed reaction zones, which potentially decreases temperature gradients, acoustic oscillations, and

  13. High-spatiotemporal-resolution ship emission inventory of China based on AIS data in 2014.

    Science.gov (United States)

    Chen, Dongsheng; Wang, Xiaotong; Li, Yue; Lang, Jianlei; Zhou, Ying; Guo, Xiurui; Zhao, Yuehua

    2017-12-31

    Ship exhaust emissions have been considered a significant source of air pollution, with adverse impacts on the global climate and human health. China, as one of the largest shipping countries, has long been in great need of in-depth analysis of ship emissions. This study for the first time developed a comprehensive national-scale ship emission inventory with 0.005°×0.005° resolution in China for 2014, using the bottom-up method based on Automatic Identification System (AIS) data of the full year of 2014. The emission estimation involved 166,546 unique vessels observed from over 15billion AIS reports, covering OGVs (ocean-going vessels), CVs (coastal vessels) and RVs (river vessels). Results show that the total estimated ship emissions for China in 2014 were 1.1937×10 6 t (SO 2 ), 2.2084×10 6 t (NO X ), 1.807×10 5 t (PM 10 ), 1.665×10 5 t (PM 2.5 ), 1.116×10 5 t (HC), 2.419×10 5 t (CO), and 7.843×10 7 t (CO 2 , excluding RVs), respectively. OGVs were the main emission contributors, with proportions of 47%-74% of the emission totals for different species. Vessel type with the most emissions was container (~43.6%), followed by bulk carrier (~17.5%), oil tanker (~5.7%) and fishing ship (~4.9%). Monthly variations showed that emissions from transport vessels had a low point in February, while fishing ship presented two emission peaks in May and September. In terms of port clusters, ship emissions in BSA (Bohai Sea Area), YRD (Yangtze River Delta) and PRD (Pearl River Delta) accounted for ~13%, ~28% and ~17%, respectively, of the total emissions in China. On the contrast, the average emission intensities in PRD were the highest, followed by the YRD and BSA regions. The establishment of this high-spatiotemporal-resolution ship emission inventory fills the gap of national-scale ship emission inventory of China, and the corresponding ship emission characteristics are expected to provide certain reference significance for the management and control of the ship

  14. Dead zone characteristics of a gas counter

    International Nuclear Information System (INIS)

    Nohtomi, Akihiro; Sakae, Takeji; Matoba, Masaru; Koori, Norihiko.

    1990-01-01

    The dead zone was recently defined as the product of dead length and dead time in order to describe the characteristics of the self-quenching streamer (SQS) mode of a gas counter. Investigation of the dead zone characteristics has been extended for the proportional and GM modes, and the measured dead zone has been compared with that of the SQS mode. Accurate values for the dead zone could be determined by means of a newly developed method with a pulse interval time to amplitude converter. Each operation mode indicates distinct dead zone characteristics. Properties of gas counters for high counting rates may be improved on the basis of measurements of the dead zone. (author)

  15. High-performance field emission device utilizing vertically aligned carbon nanotubes-based pillar architectures

    Science.gov (United States)

    Gupta, Bipin Kumar; Kedawat, Garima; Gangwar, Amit Kumar; Nagpal, Kanika; Kashyap, Pradeep Kumar; Srivastava, Shubhda; Singh, Satbir; Kumar, Pawan; Suryawanshi, Sachin R.; Seo, Deok Min; Tripathi, Prashant; More, Mahendra A.; Srivastava, O. N.; Hahm, Myung Gwan; Late, Dattatray J.

    2018-01-01

    The vertical aligned carbon nanotubes (CNTs)-based pillar architectures were created on laminated silicon oxide/silicon (SiO2/Si) wafer substrate at 775 °C by using water-assisted chemical vapor deposition under low pressure process condition. The lamination was carried out by aluminum (Al, 10.0 nm thickness) as a barrier layer and iron (Fe, 1.5 nm thickness) as a catalyst precursor layer sequentially on a silicon wafer substrate. Scanning electron microscope (SEM) images show that synthesized CNTs are vertically aligned and uniformly distributed with a high density. The CNTs have approximately 2-30 walls with an inner diameter of 3-8 nm. Raman spectrum analysis shows G-band at 1580 cm-1 and D-band at 1340 cm-1. The G-band is higher than D-band, which indicates that CNTs are highly graphitized. The field emission analysis of the CNTs revealed high field emission current density (4mA/cm2 at 1.2V/μm), low turn-on field (0.6 V/μm) and field enhancement factor (6917) with better stability and longer lifetime. Emitter morphology resulting in improved promising field emission performances, which is a crucial factor for the fabrication of pillared shaped vertical aligned CNTs bundles as practical electron sources.

  16. High-performance field emission device utilizing vertically aligned carbon nanotubes-based pillar architectures

    Directory of Open Access Journals (Sweden)

    Bipin Kumar Gupta

    2018-01-01

    Full Text Available The vertical aligned carbon nanotubes (CNTs-based pillar architectures were created on laminated silicon oxide/silicon (SiO2/Si wafer substrate at 775 °C by using water-assisted chemical vapor deposition under low pressure process condition. The lamination was carried out by aluminum (Al, 10.0 nm thickness as a barrier layer and iron (Fe, 1.5 nm thickness as a catalyst precursor layer sequentially on a silicon wafer substrate. Scanning electron microscope (SEM images show that synthesized CNTs are vertically aligned and uniformly distributed with a high density. The CNTs have approximately 2–30 walls with an inner diameter of 3–8 nm. Raman spectrum analysis shows G-band at 1580 cm−1 and D-band at 1340 cm−1. The G-band is higher than D-band, which indicates that CNTs are highly graphitized. The field emission analysis of the CNTs revealed high field emission current density (4mA/cm2 at 1.2V/μm, low turn-on field (0.6 V/μm and field enhancement factor (6917 with better stability and longer lifetime. Emitter morphology resulting in improved promising field emission performances, which is a crucial factor for the fabrication of pillared shaped vertical aligned CNTs bundles as practical electron sources.

  17. Double seismic zone for deep earthquakes in the izu-bonin subduction zone.

    Science.gov (United States)

    Iidaka, T; Furukawa, Y

    1994-02-25

    A double seismic zone for deep earthquakes was found in the Izu-Bonin region. An analysis of SP-converted phases confirms that the deep seismic zone consists of two layers separated by approximately 20 kilometers. Numerical modeling of the thermal structure implies that the hypocenters are located along isotherms of 500 degrees to 550 degrees C, which is consistent with the hypothesis that deep earthquakes result from the phase transition of metastable olivine to a high-pressure phase in the subducting slab.

  18. New perspectives in vacuum high voltage insulation. I. The transition to field emission

    CERN Document Server

    Diamond, W T

    1998-01-01

    Vacuum high-voltage insulation has been investigated for many years. Typically, electrical breakdown occurs between two broad-area electrodes at electric fields 100-1000 times lower than the breakdown field (about 5000 MV/m) between a well-prepared point cathode and a broad-area anode. Explanations of the large differences remain unsatisfactory, usually evoking field emission from small projections on the cathode that are subject to higher peak fields. The field emission then produces secondary effects that lead to breakdown. This article provides a significant resolution to this long standing problem. Field emission is not present at all fields, but typically starts after some process occurs at the cathode surface. Three effects have been identified that produce the transition to field emission: work function changes; mechanical changes produced by the strong electrical forces on the electrode surfaces; and gas desorption from the anode with sufficient density to support an avalanche discharge. Material adso...

  19. Electron field emission from sp -induced insulating to metallic ...

    Indian Academy of Sciences (India)

    Administrator

    Materials Research Centre, Indian Institute of Science, Bangalore 560 012, India. MS received 20 ... emissions of amorphous carbon films have been investigated. The observed ... water followed by acetone was positioned at the centre of first zone ..... clusters islands, surface geometry, and internal structures of the films.

  20. Estimates of greenhouse gas and black carbon emissions from a major Australian wildfire with high spatiotemporal resolution

    Science.gov (United States)

    Surawski, N. C.; Sullivan, A. L.; Roxburgh, S. H.; Polglase, P. J.

    2016-08-01

    Estimates of greenhouse gases and particulate emissions are made with a high spatiotemporal resolution from the Kilmore East fire in Victoria, Australia, which burnt approximately 100,000 ha over a 12 h period. Altogether, 10,175 Gigagrams (Gg) of CO2 equivalent (CO2-e) emissions occurred, with CO2 (˜68%) being the dominant chemical species emitted followed by CH4 (˜17%) and black carbon (BC) (˜15%). About 63% of total CO2-e emissions were estimated to be from coarse woody debris, 22% were from surface fuels, 7% from bark, 6% from elevated fuels, and less than 2% from tree crown consumption. To assess the quality of our emissions estimates, we compared our results with previous estimates which used the Global Fire Emissions Database version 3.1 (GFEDv3.1) and the Fire INventory from the National Center for Atmospheric Research version 1.0 (FINNv1), as well as Australia's National Inventory System (and its revision). The uncertainty in emission estimates was addressed using truncated Monte Carlo analysis, which derived a probability density function for total emissions from the uncertainties in each input. The distribution of emission estimates from Monte Carlo analysis was lognormal with a mean of 10,355 Gigagrams (Gg) and a ±1 standard deviation (σ) uncertainty range of 7260-13,450 Gg. Results were in good agreement with the global data sets (when using the same burnt area), although they predicted lower total emissions by 15-37% due to underestimating fuel consumed. Emissions estimates can be improved by obtaining better estimates of fuel consumed and BC emission factors. Overall, this study presents a methodological template for high-resolution emissions accounting and its uncertainty, enabling a step toward process-based emissions accounting to be achieved.

  1. Zone separator for multiple zone vessels

    Science.gov (United States)

    Jones, John B.

    1983-02-01

    A solids-gas contact vessel, having two vertically disposed distinct reaction zones, includes a dynamic seal passing solids from an upper to a lower zone and maintaining a gas seal against the transfer of the separate treating gases from one zone to the other, and including a stream of sealing fluid at the seal.

  2. High-Mobility Aligned Pentacene Films Grown by Zone-Casting

    DEFF Research Database (Denmark)

    Duffy, Claudia M.; Andreasen, Jens Wenzel; Breiby, Dag W.

    2008-01-01

    We investigate the growth and field-effect transistor performance of aligned pentacene thin films deposited by zone-casting from a solution of unsubstituted pentacene molecules in a chlorinated solvent. Polarized optical microscopy shows that solution processed pentacene films grow as large...

  3. The morphology of the Anomalous Microwave Emission in the Planck 2015 data release

    Energy Technology Data Exchange (ETDEWEB)

    Hausegger, Sebastian von; Liu, Hao, E-mail: s.vonhausegger@nbi.dk, E-mail: liuhao@nbi.dk [The Niels Bohr Institute and Discovery Center, Blegdamsvej 17, 2100 Copenhagen Ø (Denmark)

    2015-08-01

    We calculate weighted mosaic correlations between the recently published Planck 2015 foreground maps— both anomalous microwave emission (AME) maps, free-free emission, synchrotron radiation and thermal dust emission. The weighting coefficients are constructed taking account of the signal-to-error ratio given by the data product. Positive correlation is found for AME compared with thermal dust emission as well as synchrotron radiation. We find AME and free-free emission tending to be anti-correlated, however, when investigating different scales, their relationship appears to be more complex. We argue that dust particles responsible for AME are pushed out of hot zones in the interstellar medium (ISM)

  4. Search for continuous and single day emission from ultra-high-energy sources

    International Nuclear Information System (INIS)

    Chen, Mei-Li.

    1993-01-01

    Data from the CYGNUS experiment has been used to search the northern sky for point sources of continuous ultra-high-energy gamma radiation and to examine 51 candidate sources on a daily basis to search for episodic emission. In this paper, we make use of our most recent data to update our previously published results from these searches. The data sample is approximately twice as large as the published data set for continuous emission, and contains an additional year for the daily search. The latest results, up to the time of the conference, will be presented at the meeting

  5. Spatially resolved emission spectroscopic investigation of microwave-induced reactive low-power plasma jets

    International Nuclear Information System (INIS)

    Arnold, Thomas; Grabovski, Sergey; Schindler, Axel; Wagner, Hans-Erich

    2004-01-01

    A microwave-induced Ar/SF 6 plasma jet is characterized by means of optical emission spectroscopy. Rotational temperatures from unresolved N 2 bands and excitation temperatures from Fe lines as well as electron densities (H β Stark broadening) have been estimated along the plasma jet axis using a side-on configuration. The SF 6 gas flow rate and chamber pressure were varied from 10 to 250 sccm and 20 to 500 mbar, respectively. Three characteristic jet regions have been observed: the plasma ignition zone, followed by the gas mixing zone and a relaxing zone

  6. Greenhouse gas emissions from managed peat soils: is the IPCC reporting guidance realistic?

    Directory of Open Access Journals (Sweden)

    J. Couwenberg

    2011-03-01

    Full Text Available Drainage of peatlands leads to the decomposition of peat, resulting in substantial losses of carbon and nitrogen to the atmosphere. The conservation and restoration of peatlands can provide a major contribution to the mitigation of climate change. Improvements to guidance and capacity for reporting of greenhouse gas emissions from peatlands will be valuable in the context of the current negotiations towards a post-2012 climate agreement. This article evaluates IPCC approaches to greenhouse gas emissions from managed organic (peat soils and presents a summary table comparing IPCC default values with best estimates based on recent literature. Inconsistencies are pointed out with regard to the IPCC definitions of organic soils and climate zones. The 2006 IPCC Guidelines use a definition of organic soil that is not totally consistent with FAO definitions, use climate zones that are not fully compatible, present default CO2 values that are substantially (often an order of magnitude too low, and present a default N2O value for tropical cropland that is also an order of magnitude too low. An update of IPCC default values is desirable. The IPCC Emission Factor Database offers a platform for establishing more accurate emission factors, but so far contains little information about emissions from peat soils.

  7. Eu{sup 3+} emission in phosphate glasses with high UV transparency

    Energy Technology Data Exchange (ETDEWEB)

    Silva, G.H. [Laboratório de Espectroscopia de Materiais (LEM), Departamento de Física, Universidade Federal de Juiz de Fora, CEP 36036-900 Juiz de Fora, MG (Brazil); Anjos, V., E-mail: virgilio@fisica.ufjf.br [Laboratório de Espectroscopia de Materiais (LEM), Departamento de Física, Universidade Federal de Juiz de Fora, CEP 36036-900 Juiz de Fora, MG (Brazil); Bell, M.J.V. [Laboratório de Espectroscopia de Materiais (LEM), Departamento de Física, Universidade Federal de Juiz de Fora, CEP 36036-900 Juiz de Fora, MG (Brazil); Carmo, A.P. [Instituto Federal Fluminense-Campus Cabo Frio, CP 112015, CEP 28909-971 Cabo Frio, RJ (Brazil); Pinheiro, A.S.; Dantas, N.O. [Laboratório de Novos Materiais Isolantes e Semicondutores (LNMIS), Instituto de Física, Universidade Federal de Uberlândia, CP 593, CEP 38400-902 Uberlândia, MG (Brazil)

    2014-10-15

    We report a study of the phosphate glass PZABP (P{sub 2}O{sub 5}–ZnO–Al{sub 2}O{sub 3}–BaO–PbO) doped with europium (Eu{sup 3+}) in different concentrations. Absorption, photoluminescence and time resolved photoluminescence were used to investigate the influence of increasing Eu{sup 3+} concentrations. The present glass exhibits Eu{sup 3+} absorption bands in the ultraviolet region (about 300 nm) due to the high transparency of the system compared to other phosphate glasses. In this way, it was possible to obtain the Judd–Ofelt parameters from the emission and absorption spectra. Moreover, a strong red emission attributed to the transition {sup 5}D{sub 0}→{sup 7}F{sub 2} of Eu{sup 3+} (611 nm) was observed. It was found that the radiative lifetime and the quantum efficiency of the Eu{sup 3+} level, {sup 5}D{sub 0}, do not suffer a significant change as the concentration of Eu{sup 3+} ions increases. - Highlights: • UV transparent glass matrix is used for Eu{sup 3+} doping. • Judd–Ofelt parameters from the emission and absorption spectra were obtained. • Red emission attributed to the transition {sup 5}D{sub 0}→{sup 7}F{sub 2} of Eu{sup 3+} (611 nm) was observed.

  8. Spatial and temporal disaggregation of the on-road vehicle emission inventory in a medium-sized Andean city. Comparison of GIS-based top-down methodologies

    Science.gov (United States)

    Gómez, C. D.; González, C. M.; Osses, M.; Aristizábal, B. H.

    2018-04-01

    Emission data is an essential tool for understanding environmental problems associated with sources and dynamics of air pollutants in urban environments, especially those emitted from vehicular sources. There is a lack of knowledge about the estimation of air pollutant emissions and particularly its spatial and temporal distribution in South America, mainly in medium-sized cities with population less than one million inhabitants. This work performed the spatial and temporal disaggregation of the on-road vehicle emission inventory (EI) in the medium-sized Andean city of Manizales, Colombia, with a spatial resolution of 1 km × 1 km and a temporal resolution of 1 h. A reported top-down methodology, based on the analysis of traffic flow levels and road network distribution, was applied. Results obtained allowed the identification of several hotspots of emission at the downtown zone and the residential and commercial area of Manizales. Downtown exhibited the highest percentage contribution of emissions normalized by its total area, with values equal to 6% and 5% of total CO and PM10 emissions per km2 respectively. These indexes were higher than those obtained in residential-commercial area with values of 2%/km2 for both pollutants. Temporal distribution showed strong relationship with driving patterns at rush hours, as well as an important influence of passenger cars and motorcycles in emissions of CO both at downtown and residential-commercial areas, and the impact of public transport in PM10 emissions in the residential-commercial zone. Considering that detailed information about traffic counts and road network distribution is not always available in medium-sized cities, this work compares other simplified top-down methods for spatially assessing the on-road vehicle EI. Results suggested that simplified methods could underestimate the spatial allocation of downtown emissions, a zone dominated by high traffic of vehicles. The comparison between simplified methods

  9. Development and application of network virtual instrument for emission spectrum of pulsed high-voltage direct current discharge

    Science.gov (United States)

    Gong, X.; Wu, Q.

    2017-12-01

    Network virtual instrument (VI) is a new development direction in current automated test. Based on LabVIEW, the software and hardware system of VI used for emission spectrum of pulsed high-voltage direct current (DC) discharge is developed and applied to investigate pulsed high-voltage DC discharge of nitrogen. By doing so, various functions are realized including real time collection of emission spectrum of nitrogen, monitoring operation state of instruments and real time analysis and processing of data. By using shared variables and DataSocket technology in LabVIEW, the network VI system based on field VI is established. The system can acquire the emission spectrum of nitrogen in the test site, monitor operation states of field instruments, realize real time face-to-face interchange of two sites, and analyze data in the far-end from the network terminal. By employing the network VI system, the staff in the two sites acquired the same emission spectrum of nitrogen and conducted the real time communication. By comparing with the previous results, it can be seen that the experimental data obtained by using the system are highly precise. This implies that the system shows reliable network stability and safety and satisfies the requirements for studying the emission spectrum of pulsed high-voltage discharge in high-precision fields or network terminals. The proposed architecture system is described and the target group gets the useful enlightenment in many fields including engineering remote users, specifically in control- and automation-related tasks.

  10. Research of biofuels on performance, emission and noise of diesel engine under high-altitude area

    Science.gov (United States)

    Xu, Kai; Huang, Hua

    2018-05-01

    At high altitudes and with no any adjustment for diesel engine, comparative experiments on a diesel engine about the engine's performance, emission and exhaust noise, are carried out by combusting different biofuels (pure diesel (D100), biodiesel (B100), and ethanol-biodiesel (E20)). The test results show that: compared with D100, the power performance of combusting B100 and E20 decreases, and the average drop of the torque at full-load are 4.5% and 5.7%. The equivalent fuel consumption is lower than that of diesel fuel, The decline of oil consumption rate 3˜10g/ (kW • h); At low load the emission of NOx decreases, Hat high loads, equal and higher than D100; the soot emissions decreases heavier, among them, E20 carbon dioxide emissions improved considerably; An full-load exhaust noise of B100 decreases average 3.6dB(A), E20 decreases average 4.8dB(A); In road simulation experiments exhaust noise max decreases 8.5dB(A).

  11. An X-ray survey of the central molecular zone: Variability of the Fe Kα emission line

    Science.gov (United States)

    Terrier, R.; Clavel, M.; Soldi, S.; Goldwurm, A.; Ponti, G.; Morris, M. R.; Chuard, D.

    2018-05-01

    There is now abundant evidence that the luminosity of the Galactic super-massive black hole (SMBH) has not always been as low as it is nowadays. The observation of varying non-thermal diffuse X-ray emission in molecular complexes in the central 300 pc has been interpreted as delayed reflection of a past illumination by bright outbursts of the SMBH. The observation of different variability timescales of the reflected emission in the Sgr A molecular complex can be well explained if the X-ray emission of at least two distinct and relatively short events (i.e. about 10 yr or less) is currently propagating through the region. The number of such events or the presence of a long-duration illumination are open questions. Variability of the reflected emission all over of the central 300 pc, in particular in the 6.4 keV Fe Kα line, can bring strong constraints. To do so we performed a deep scan of the inner 300 pc with XMM-Newton in 2012. Together with all the archive data taken over the course of the mission, and in particular a similar albeit more shallow scan performed in 2000-2001, this allows for a detailed study of variability of the 6.4 keV line emission in the region, which we present here. We show that the overall 6.4 keV emission does not strongly vary on average, but variations are very pronounced on smaller scales. In particular, most regions showing bright reflection emission in 2000-2001 significantly decrease by 2012. We discuss those regions and present newly illuminated features. The absence of bright steady emission argues against the presence of an echo from an event of multi-centennial duration and most, if not all, of the emission can likely be explained by a limited number of relatively short (i.e. up to 10 yr) events. Images of the Fe Kα emission as FITS files are only available at the CDS via anonymous ftp to cdsarc.u-strasbg.fr (130.79.128.5) or via http://cdsarc.u-strasbg.fr/viz-bin/qcat?J/A+A/612/A102

  12. White Light Photorefractive Phase Zone Plates

    International Nuclear Information System (INIS)

    Yuan-Mei, Gao; Si-Min, Liu

    2008-01-01

    Incoherent white light from an incandescent source is employed to fabricate volume phase zone plates in LiNbO 3 : Fe, for the first time to our knowledge, which can guide and modulate the input white light or laser light. The diffractive efficiency of the white light volume phase zone plates fabricated can reach as high as 12%. In addition, we test the volume phase zone plates by a probe beam and find that the volume phase zone plate is present in the direction perpendicular to the c-axis and absent in the direction parallel to the c-axis. This directly proves the existence of photovoltaic photorefractive anisotropy of white light

  13. Pinhole diffraction holography for fabrication of high-resolution Fresnel zone plates.

    Science.gov (United States)

    Sarkar, Sankha S; Solak, Harun H; David, Christian; van der Veen, J Friso

    2014-01-27

    Fresnel zone plates (FZPs) play an essential role in high spatial resolution x-ray imaging and analysis of materials in many fields. These diffractive lenses are commonly made by serial writing techniques such as electron beam or focused ion beam lithography. Here we show that pinhole diffraction holography has potential to generate FZP patterns that are free from aberrations and imperfections that may be present in alternative fabrication techniques. In this presented method, FZPs are fabricated by recording interference pattern of a spherical wave generated by diffraction through a pinhole, illuminated with coherent plane wave at extreme ultraviolet (EUV) wavelength. Fundamental and practical issues involved in formation and recording of the interference pattern are considered. It is found that resolution of the produced FZP is directly related to the diameter of the pinhole used and the pinhole size cannot be made arbitrarily small as the transmission of EUV or x-ray light through small pinholes diminishes due to poor refractive index contrast found between materials in these spectral ranges. We also find that the practical restrictions on exposure time due to the light intensity available from current sources directly imposes a limit on the number of zones that can be printed with this method. Therefore a trade-off between the resolution and the FZP diameter exists. Overall, we find that this method can be used to fabricate aberration free FZPs down to a resolution of about 10 nm.

  14. Modulated High-Energy Gamma-Ray Emission from the Micro-quasar Cygnus X-3

    International Nuclear Information System (INIS)

    Abdo, A.A.; Cheung, C.C.; Dermer, C.D.; Grove, J.E.; Johnson, W.N.; Lovellette, M.N.; Makeev, A.; Ray, P.S.; Strickman, M.S.; Wood, K.S.; Abdo, A.A.; Cheung, C.C.; Ackermann, M.; Ajello, M.; Bechtol, K.; Berenji, B.; Blandford, R.D.; Bloom, E.D.; Borgland, A.W.; Cameron, R.A.; Chiang, J.; Claus, R.; Digel, S.W.; Silva, E.D.E.; Drell, P.S.; Dubois, R.; Focke, W.B.; Glanzman, T.; Godfrey, G.; Hayashida, M.; Johannesson, G.; Johnson, A.S.; Kamae, T.; Kocian, M.L.; Lande, J.; Madejski, G.M.; Michelson, P.F.; Mitthumsiri, W.; Monzani, M.E.; Moskalenko, I.V.; Murgia, S.; Nolan, P.L.; Paneque, D.; Reimer, A.; Reimer, O.; Rochester, L.S.; Romani, R.W.; Tanaka, T.; Thayer, J.B.; Tramacere, A.; Uchiyama, Y.; Usher, T.L.; Waite, A.P.; Wang, P.; Ackermann, M.; Ajello, M.; Bechtol, K.; Berenji, B.; Blandford, R.D.; Bloom, E.D.; Borgland, A.W.; Cameron, R.A.; Chiang, J.; Claus, R.; Digel, S.W.; Silva, E.D.E.; Drell, P.S.; Dubois, R.; Focke, W.B.; Glanzman, T.; Godfrey, G.; Hayashida, M.; Johannesson, G.; Johnson, A.S.; Kamae, T.; Kocian, M.L.; Lande, J.; Madejski, G.M.; Michelson, P.F.; Mitthumsiri, W.; Monzani, M.E.; Moskalenko, I.V.; Murgia, S.; Nolan, P.L.; Paneque, D.; Reimer, A.; Reimer, O.; Rochester, L.S.; Romani, R.W.; Tanaka, T.; Thayer, J.B.; Tramacere, A.; Uchiyama, Y.; Usher, T.L.; Waite, A.P.; Wang, P.; Axelsson, M.; Hjalmarsdotter, L.; Axelsson, M.; Conrad, J.; Hjalmarsdotter, L.; Jackson, M.S.; Meurer, C.; Ryde, F.; Ylinen, T.; Baldini, L.; Bellazzini, R.; Brez, A.; Kuss, M.; Latronico, L.; Omodei, N.; Pesce-Rollins, M.; Razzano, M.; Sgro, C.; Ballet, J.; Casandjian, J.M.; Chaty, S.; Corbel, S.; Grenier, I.A.; Koerding, E.; Rodriguez, J.; Starck, J.L.; Tibaldo, L.

    2009-01-01

    Micro-quasars are accreting black holes or neutron stars in binary systems with associated relativistic jets. Despite their frequent outburst activity, they have never been unambiguously detected emitting high-energy gamma rays. The Fermi Large Area Telescope (LAT) has detected a variable high-energy source coinciding with the position of the x-ray binary and micro-quasar Cygnus X-3. Its identification with Cygnus X-3 is secured by the detection of its orbital period in gamma rays, as well as the correlation of the LAT flux with radio emission from the relativistic jets of Cygnus X-3. The gamma-ray emission probably originates from within the binary system, opening new areas in which to study the formation of relativistic jets. (authors)

  15. Use of a high density lead glass tubing projection chamber in positron emission tomography and in high energy physics

    International Nuclear Information System (INIS)

    Conti, M.; Guerra, A.D.; Habel, R.; Mulera, T.; Perez-Mendez, V.; Schwartz, G.

    1985-10-01

    We describe the principle of operation of a high density Projection Chamber, in which the converter/radiator and drift field shaping structures are combined in the form of high density (5 to 6 g/cm 3 ) lead glass tubing. The main applications of this type of detector to Medical Physics (Positron Emission Tomography) and High Energy Physics (Electromagnetic Calorimetry) are discussed

  16. Occasional large emissions of nitrous oxide and methane observed in stormwater biofiltration systems

    International Nuclear Information System (INIS)

    Grover, Samantha P.P.; Cohan, Amanda; Chan, Hon Sen; Livesley, Stephen J.; Beringer, Jason; Daly, Edoardo

    2013-01-01

    Designed, green infrastructures are becoming a customary feature of the urban landscape. Sustainable technologies for stormwater management, and biofilters in particular, are increasingly used to reduce stormwater runoff volumes and peaks as well as improve the water quality of runoff discharged into urban water bodies. Although a lot of research has been devoted to these technologies, their effect in terms of greenhouse gas fluxes in urban areas has not been yet investigated. We present the first study aimed at quantifying greenhouse gas fluxes between the soil of stormwater biofilters and the atmosphere. N 2 O, CH 4 , and CO 2 were measured periodically over a year in two operational vegetated biofiltration cells at Monash University in Melbourne, Australia. One cell had a saturated zone at the bottom, and compost and hardwood mulch added to the sandy loam filter media. The other cell had no saturated zone and was composed of sandy loam. Similar sedges were planted in both cells. The biofilter soil was a small N 2 O source and a sink for CH 4 for most measurement events, with occasional large emissions of both N 2 O and CH 4 under very wet conditions. Average N 2 O fluxes from the cell with the saturated zone were almost five-fold greater (65.6 μg N 2 O–N m −2 h −1 ) than from the other cell (13.7 μg N 2 O–N m −2 h −1 ), with peaks up to 1100 μg N 2 O–N m −2 h −1 . These N 2 O fluxes are of similar magnitude to those measured in other urban soils, but with larger peak emissions. The CH 4 sink strength of the cell with the saturated zone (− 3.8 μg CH 4 –C m −2 h −1 ) was lower than the other cell (− 18.3 μg CH 4 –C m −2 h −1 ). Both cells of the biofilter appeared to take up CH 4 at similar rates to other urban lawn systems; however, the biofilter cells displayed occasional large CH 4 emissions following inflow events, which were not seen in other urban systems. CO 2 fluxes increased with soil temperature in both cells, and

  17. Carbon dioxide emission and bio-capacity indexing for transportation activities: A methodological development in determining the sustainability of vehicular transportation systems.

    Science.gov (United States)

    Labib, S M; Neema, Meher Nigar; Rahaman, Zahidur; Patwary, Shahadath Hossain; Shakil, Shahadat Hossain

    2018-06-09

    CO 2 emissions from urban traffic are a major concern in an era of increasing ecological disequilibrium. Adding to the problem net CO 2 emissions in urban settings are worsened due to the decline of bio-productive areas in many cities. This decline exacerbates the lack of capacity to sequestrate CO 2 at the micro and meso-scales resulting in increased temperatures and decreased air quality within city boundaries. Various transportation and environmental strategies have been implemented to address traffic related CO 2 emissions, however current literature identifies difficulties in pinpointing these critical areas of maximal net emissions in urban transport networks. This study attempts to close this gap in the literature by creating a new lay-person friendly index that combines CO 2 emissions from vehicles and the bio-capacity of specific traffic zones to identify these areas at the meso-scale within four ranges of values with the lowest index values representing the highest net CO 2 levels. The study used traffic volume, fuel types, and vehicular travel distance to estimate CO 2 emissions at major links in Dhaka, Bangladesh's capital city's transportation network. Additionally, using remote-sensing tools, adjacent bio-productive areas were identified and their bio-capacity for CO 2 sequestration estimated. The bio-productive areas were correlated with each traffic zone under study resulting in an Emission Bio-Capacity index (EBI) value estimate for each traffic node. Among the ten studied nodes in Dhaka City, nine had very low EBI values, correlating to very high CO 2 emissions and low bio-capacity. As a result, the study considered these areas unsustainable as traffic nodes going forward. Key reasons for unsustainability included increasing use of motorized traffic, absence of optimized signal systems, inadequate public transit options, disincentives for fuel free transport (FFT), and a decline in bio-productive areas. Copyright © 2018 Elsevier Ltd. All rights

  18. Detailed seismotectonic analysis of Sumatra subduction zone revealed by high precision earthquake location

    Science.gov (United States)

    Sagala, Ricardo Alfencius; Harjadi, P. J. Prih; Heryandoko, Nova; Sianipar, Dimas

    2017-07-01

    Sumatra was one of the most high seismicity regions in Indonesia. The subduction of Indo-Australian plate beneath Eurasian plate in western Sumatra contributes for many significant earthquakes that occur in this area. These earthquake events can be used to analyze the seismotectonic of Sumatra subduction zone and its system. In this study we use teleseismic double-difference method to obtain more high precision earthquake distribution in Sumatra subduction zone. We use a 3D nested regional-global velocity model. We use a combination of data from both of ISC (International Seismological Center) and BMKG (Agency for Meteorology Climatology and Geophysics, Indonesia). We successfully relocate about 6886 earthquakes that occur on period of 1981-2015. We consider that this new location is more precise than the regular bulletin. The relocation results show greatly reduced of RMS residual of travel time. Using this data, we can construct a new seismotectonic map of Sumatra. A well-built geometry of subduction slab, faults and volcano arc can be obtained from the new bulletin. It is also showed that at a depth of 140-170 km, there is many events occur as moderate-to-deep earthquakes, and we consider about the relation of the slab's events with volcanic arc and inland fault system. A reliable slab model is also built from regression equation using new relocated data. We also analyze the spatial-temporal of seismotectonic using b-value mapping that inspected in detail horizontally and vertically cross-section.

  19. UV-induced N2O emission from plants

    Science.gov (United States)

    Bruhn, Dan; Albert, Kristian R.; Mikkelsen, Teis N.; Ambus, Per

    2014-12-01

    Nitrous oxide (N2O) is an important long-lived greenhouse gas and precursor of stratospheric ozone-depleting mono-nitrogen oxides. The atmospheric concentration of N2O is persistently increasing; however, large uncertainties are associated with the distinct source strengths. Here we investigate for the first time N2O emission from terrestrial vegetation in response to natural solar ultra violet radiation. We conducted field site measurements to investigate N2O atmosphere exchange from grass vegetation exposed to solar irradiance with and without UV-screening. Further laboratory tests were conducted with a range of species to study the controls and possible loci of UV-induced N2O emission from plants. Plants released N2O in response to natural sunlight at rates of c. 20-50 nmol m-2h-1, mostly due to the UV component. The emission response to UV-A is of the same magnitude as that to UV-B. Therefore, UV-A is more important than UV-B given the natural UV-spectrum at Earth's surface. Plants also emitted N2O in darkness, although at reduced rates. The emission rate is temperature dependent with a rather high activation energy indicative for an abiotic process. The prevailing zone for the N2O formation appears to be at the very surface of leaves. However, only c. 26% of the UV-induced N2O appears to originate from plant-N. Further, the process is dependent on atmospheric oxygen concentration. Our work demonstrates that ecosystem emission of the important greenhouse gas, N2O, may be up to c. 30% higher than hitherto assumed.

  20. Purification by using the zone melting technique; Purification par la technique de la zone fondue

    Energy Technology Data Exchange (ETDEWEB)

    Clerc, Michel

    1962-06-22

    The zone melting technique has first been used in metallurgy, and has been developed for the preparation of silicon and germanium for semiconductors, and then for the preparation of organic bodies of high purity. In this research thesis, the author first presents the principle of this technique, and then discusses the influence of agitation in liquid phase, and the influence of the number of passages over the zone. He discusses issues related to matter transport, and some technical details which intervene in the design of an apparatus for purification by zone melting. He finally presents examples.

  1. FERMI OBSERVATIONS OF HIGH-ENERGY GAMMA-RAY EMISSION FROM GRB 090217A

    International Nuclear Information System (INIS)

    Ackermann, M.; Ajello, M.; Bechtol, K.; Berenji, B.; Blandford, R. D.; Borgland, A. W.; Bouvier, A.; Baldini, L.; Bellazzini, R.; Bregeon, J.; Brez, A.; Ballet, J.; Barbiellini, G.; Baring, M. G.; Bastieri, D.; Bhat, P. N.; Briggs, M. S.; Bissaldi, E.; Bonamente, E.; Brigida, M.

    2010-01-01

    The Fermi observatory is advancing our knowledge of gamma-ray bursts (GRBs) through pioneering observations at high energies, covering more than seven decades in energy with the two on-board detectors, the Large Area Telescope (LAT) and the Gamma-ray Burst Monitor (GBM). Here, we report on the observation of the long GRB 090217A which triggered the GBM and has been detected by the LAT with a significance greater than 9σ. We present the GBM and LAT observations and on-ground analyses, including the time-resolved spectra and the study of the temporal profile from 8 keV up to ∼1 GeV. All spectra are well reproduced by a Band model. We compare these observations to the first two LAT-detected, long bursts GRB 080825C and GRB 080916C. These bursts were found to have time-dependent spectra and exhibited a delayed onset of the high-energy emission, which are not observed in the case of GRB 090217A. We discuss some theoretical implications for the high-energy emission of GRBs.

  2. Cost reduction for large turbine generator Pedestal in high seismic zone

    International Nuclear Information System (INIS)

    Sawhney, P.S.; Irani, P.; Pusheck, B.N.

    1985-01-01

    Turbine Generator Pedestals have generally been designed using reinforced concrete. For present day large turbine generators (1100 MWe class and above) with tall (about 80 feet) pedestals, the amount of reinforcing steel becomes quite large, especially for plants in high seismic zones. With the prime objective of cost reduction, an approach using steel/concrete composite design has been studied for a large BWR Turbine Generator pedestal with 0.3g peak ground acceleration. Large prefabricated steel modules were adopted for composite design and simplified construction. Design was based on the ACI and AISC codes. Costs and schedules were developed and compared with those for a conventionally designed reinforced concrete pedestal. Composite design was found to give considerable cost and schedule advantage over the conventional reinforced concrete design

  3. A comprehensive biomass burning emission inventory with high spatial and temporal resolution in China

    Science.gov (United States)

    Zhou, Ying; Xing, Xiaofan; Lang, Jianlei; Chen, Dongsheng; Cheng, Shuiyuan; Wei, Lin; Wei, Xiao; Liu, Chao

    2017-02-01

    . As for the straw burning emission of various crops, corn straw burning has the largest contribution to all of the pollutants considered, except for CH4; rice straw burning has highest contribution to CH4 and the second largest contribution to other pollutants, except for SO2, OC, and Hg; wheat straw burning is the second largest contributor to SO2, OC, and Hg and the third largest contributor to other pollutants. Heilongjiang, Shandong, and Henan provinces located in the north-eastern and central-southern regions of China have higher emissions compared to other provinces in China. Gridded emissions, which were obtained through spatial allocation based on the gridded rural population and fire point data from emission inventories at county resolution, could better represent the actual situation. High biomass burning emissions are concentrated in the areas with more agricultural and rural activity. The months of April, May, June, and October account for 65 % of emissions from in-field crop residue burning, while, regarding EC, the emissions in January, February, October, November, and December are relatively higher than other months due to biomass domestic burning in heating season. There are regional differences in the monthly variations of emissions due to the diversity of main planted crops and climatic conditions. Furthermore, PM2.5 component results showed that OC, Cl-, EC, K+, NH4+, elemental K, and SO42- are the main PM2.5 species, accounting for 80 % of the total emissions. The species with relatively high contribution to NMVOC emission include ethylene, propylene, toluene, mp-xylene, and ethyl benzene, which are key species for the formation of secondary air pollution. The detailed biomass burning emission inventory developed by this study could provide useful information for air-quality modelling and could support the development of appropriate pollution-control strategies.

  4. Acoustic emission linear pulse holography

    International Nuclear Information System (INIS)

    Collins, H.D.; Busse, L.J.; Lemon, D.K.

    1983-01-01

    This paper describes the emission linear pulse holography which produces a chronological linear holographic image of a flaw by utilizing the acoustic energy emitted during crack growth. A thirty two point sampling array is used to construct phase-only linear holograms of simulated acoustic emission sources on large metal plates. The concept behind the AE linear pulse holography is illustrated, and a block diagram of a data acquisition system to implement the concept is given. Array element spacing, synthetic frequency criteria, and lateral depth resolution are specified. A reference timing transducer positioned between the array and the inspection zone and which inititates the time-of-flight measurements is described. The results graphically illustrate the technique using a one-dimensional FFT computer algorithm (ie. linear backward wave) for an AE image reconstruction

  5. Assessment of high to low frequency variations of isoprene emission rates using a neural network approach

    Science.gov (United States)

    Boissard, C.; Chervier, F.; Dutot, A. L.

    2007-08-01

    Using a statistical approach based on artificial neural networks, an emission algorithm (ISO_LF) accounting for high (instantaneous) to low (seasonal) frequency variations was developed for isoprene. ISO_LF was optimised using an isoprene emission data base (ISO-DB) specifically designed for this work. ISO-DB consists of 1321 emission rates collected in the literature, together with 34 environmental variables, measured or assessed using NCDC (National Climatic Data Center) or NCEP (National Centers for Environmental Predictions) meteorological databases. ISO-DB covers a large variety of emitters (25 species) and environmental conditions (10° S to 60° N). When only instantaneous environmental regressors (air temperature and photosynthetic active radiation, PAR) were used, a maximum of 60% of the overall isoprene variability was assessed and the highest emissions were underestimated. Considering a total of 9 high (instantaneous) to low (up to 3 weeks) frequency regressors, ISO_LF accounts for up to 91% of the isoprene emission variability, whatever the emission range, species or climate. Diurnal and seasonal variations are correctly reproduced for textit{Ulex europaeus} with a maximum factor of discrepancy of 4. ISO-LF was found to be mainly sensitive to air temperature cumulated over 3 weeks T21 and to instantaneous light L0 and air temperature T0 variations. T21, T0 and L0 only accounts for 76% of the overall variability. The use of ISO-LF for non stored monoterpene emissions was shown to give poor results.

  6. Properties and Applications of High Emissivity Composite Films Based on Far-Infrared Ceramic Powder.

    Science.gov (United States)

    Xiong, Yabo; Huang, Shaoyun; Wang, Wenqi; Liu, Xinghai; Li, Houbin

    2017-11-29

    Polymer matrix composite materials that can emit radiation in the far-infrared region of the spectrum are receiving increasing attention due to their ability to significantly influence biological processes. This study reports on the far-infrared emissivity property of composite films based on far-infrared ceramic powder. X-ray fluorescence spectrometry, Fourier transform infrared spectroscopy, thermogravimetric analysis, and X-ray powder diffractometry were used to evaluate the physical properties of the ceramic powder. The ceramic powder was found to be rich in aluminum oxide, titanium oxide, and silicon oxide, which demonstrate high far-infrared emissivity. In addition, the micromorphology, mechanical performance, dynamic mechanical properties, and far-infrared emissivity of the composite were analyzed to evaluate their suitability for strawberry storage. The mechanical properties of the far-infrared radiation ceramic (cFIR) composite films were not significantly influenced ( p ≥ 0.05) by the addition of the ceramic powder. However, the dynamic mechanical analysis (DMA) properties of the cFIR composite films, including a reduction in damping and shock absorption performance, were significant influenced by the addition of the ceramic powder. Moreover, the cFIR composite films showed high far-infrared emissivity, which has the capability of prolonging the storage life of strawberries. This research demonstrates that cFIR composite films are promising for future applications.

  7. Evaluation of the Contribution of the Building Sector to PM2.5 Emissions in China

    Energy Technology Data Exchange (ETDEWEB)

    Khanna, Nina [Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States); Zhou, Nan [Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States); Ke, Jing [Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States); Fridley, David [Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States)

    2014-11-01

    In this study, we quantify the current and potential contribution of China’s building sector to direct primary and indirect PM2.5 emissions and co-benefits of key pollution reduction strategies of energy efficiency, fuel switching and pollution control technologies on PM2.5 emissions reduction. We use a bottom-up end-use accounting model to model residential and commercial buildings’ coal demand for heating and electricity demand in China’s Northern and Transition climate zones from 2010 to 2030. The model is then used to characterize the current coal-based heating (e.g., district heating, combined heat and power generation, small-scale coal-fired boilers) and power generation technologies to estimate direct and indirect PM2.5 emissions. Model scenarios are developed to evaluate and compare the potential co-benefits of efficiency improvements, fuel switching and pollution control technologies in reducing building-related direct and indirect PM2.5 emissions. An alternative pathway of development in which district heating is introduced to China’s Transition zone to meet growing demand for heat is also modeled to evaluate and quantify the potential impact on PM2.5 emissions.

  8. The CO/NOx emissions of swirled, strongly pulsed jet diffusion flames

    KAUST Repository

    Liao, Ying-Hao; Hermanson, James C.

    2014-01-01

    recirculation within the swirl-induced recirculation zone. Scaling relations, when taking into account the impact of air dilution over an injection cycle on the flame length, reveal a strong correlation between the CO emissions and the global residence time

  9. Parametric study of the relaxation zone behind strong normal shock waves in a dusty ionized monatomic gas

    International Nuclear Information System (INIS)

    Igra, O.; Ben-Dor, G.

    1982-01-01

    The conservation equations appropriate to a steady, one-dimensional flow of dusty ionized argon were solved numerically. The specific effect of each of the physical parameters of the dust upon the flow properties in the relaxation zone is studied. It is found that increasing the dust particle mass causes an increase in both the kinematic and thermal relaxation lengths. In addition to these changes, the flow field inside the relaxation zone is also affected. An increase in the dust mass (caused either by an increase in the dust density or its diameter) causes an increase in the plasma velocity, temperature and electron number density and a decrease in its density and pressure. Similar effects are encountered when the specific heat capacity of the dust is changed. An increase in the emissivity of the dust causes an increase in the plasma density and pressure and a decrease in its velocity, temperature and electron number density. Increasing the emissivity of the dust results in a decrease in the relaxation zone length. (author)

  10. Emission measurement of diesel vehicles in Hong Kong through on-road remote sensing: Performance review and identification of high-emitters.

    Science.gov (United States)

    Huang, Yuhan; Organ, Bruce; Zhou, John L; Surawski, Nic C; Hong, Guang; Chan, Edward F C; Yam, Yat Shing

    2018-06-01

    A two-year remote sensing measurement program was carried out in Hong Kong to obtain a large dataset of on-road diesel vehicle emissions. Analysis was performed to evaluate the effect of vehicle manufacture year (1949-2015) and engine size (0.4-20 L) on the emission rates and high-emitters. The results showed that CO emission rates of larger engine size vehicles were higher than those of small vehicles during the study period, while HC and NO were higher before manufacture year 2006 and then became similar levels between manufacture years 2006 and 2015. CO, HC and NO of all vehicles showed an unexpectedly increasing trend during 1998-2004, in particular ≥6001 cc vehicles. However, they all decreased steadily in the last decade (2005-2015), except for NO of ≥6001 cc vehicles during 2013-2015. The distributions of CO and HC emission rates were highly skewed as the dirtiest 10% vehicles emitted much higher emissions than all the other vehicles. Moreover, this skewness became more significant for larger engine size or newer vehicles. The results indicated that remote sensing technology would be very effective to screen the CO and HC high-emitters and thus control the on-road vehicle emissions, but less effective for controlling NO emissions. No clear correlation was observed between the manufacture year and percentage of high-emitters for ≤3000 cc vehicles. However, the percentage of high-emitters decreased with newer manufacture year for larger vehicles. In addition, high-emitters of different pollutants were relatively independent, in particular NO emissions, indicating that high-emitter screening criteria should be defined on a CO-or-HC-or-NO basis, rather than a CO-and-HC-and-NO basis. Copyright © 2018 Elsevier Ltd. All rights reserved.

  11. Fabrication techniques of X-ray spiral zone plates

    International Nuclear Information System (INIS)

    Gao Nan; Zhu Xiaoli; Li Hailiang; Xie Changqing

    2010-01-01

    The techniques to make X-ray spiral zone plates using electron beam and X-ray lithography were studied. A master mask was fabricated on polyimide membrane by E-beam lithography and micro-electroplating. Spiral zone plates were efficiently replicated by X-ray lithography and micro-electroplating. By combining the techniques, spiral zone plates at 1 keV were successfully fabricate. With an outermost zone width of the 200 nm, and the gold absorbers thickness of 700 nm, the high quality zone plates can be used for X-ray phase contrast microscopy.(authors)

  12. High-resolution inventory of NO emissions from agricultural soils over the Ile-de-France region

    Energy Technology Data Exchange (ETDEWEB)

    Rolland, M.-N. [INRA, AgroParisTech, UMR 1091 Environnement et Grandes Cultures, F-78850 Grignon (France); Gabrielle, B., E-mail: Benoit.Gabrielle@agroparistech.f [INRA, AgroParisTech, UMR 1091 Environnement et Grandes Cultures, F-78850 Grignon (France); Laville, P.; Cellier, P. [INRA, AgroParisTech, UMR 1091 Environnement et Grandes Cultures, F-78850 Grignon (France); Beekmann, M. [Laboratoire Inter-universitaire des Systemes Atmospheriques - CNRS, Universites Paris-Est and Paris 7, F-94 010 Creteil (France); Gilliot, J.-M.; Michelin, J.; Hadjar, D. [INRA, AgroParisTech, UMR 1091 Environnement et Grandes Cultures, F-78850 Grignon (France); Curci, G. [Dipartimento di Fisica - CETEMPS, Universita' degli Studi dell' Aquila, 67010 Coppito, L' Aquila (Italy)

    2010-03-15

    Arable soils are a significant source of nitric oxide (NO), a precursor of tropospheric ozone, and thereby contribute to ozone pollution. However, their actual impact on ozone formation is strongly related to their spatial and temporal emission patterns, which warrant high-resolution estimates. Here, we combined an agro-ecosystem model and geo-referenced databases to map these sources over the 12 000 km{sup 2} administrative region surrounding Paris, France, with a kilometric level resolution. The six most frequent arable crop species were simulated, with emission rates ranging from 1.4 kg N-NO ha{sup -1} yr{sup -1} to 11.1 kg N-NO ha{sup -1} yr{sup -1}. The overall emission factor for fertilizer-derived NO emissions was 1.7%, while background emissions contributed half of the total NO efflux. Emissions were strongly seasonal, being highest in spring due to fertilizer inputs. They were mostly sensitive to soil type, crops' growing season and fertilizer N rates. - The use of an agro-ecosystem model at regional scale makes it possible to map the emissions of nitric oxide from arable soils at a resolution compatible with tropospheric ozone models.

  13. Southward shift of the global wind energy resource under high carbon dioxide emissions

    Science.gov (United States)

    Karnauskas, Kristopher B.; Lundquist, Julie K.; Zhang, Lei

    2018-01-01

    The use of wind energy resource is an integral part of many nations' strategies towards realizing the carbon emissions reduction targets set forth in the Paris Agreement, and global installed wind power cumulative capacity has grown on average by 22% per year since 2006. However, assessments of wind energy resource are usually based on today's climate, rather than taking into account that anthropogenic greenhouse gas emissions continue to modify the global atmospheric circulation. Here, we apply an industry wind turbine power curve to simulations of high and low future emissions scenarios in an ensemble of ten fully coupled global climate models to investigate large-scale changes in wind power across the globe. Our calculations reveal decreases in wind power across the Northern Hemisphere mid-latitudes and increases across the tropics and Southern Hemisphere, with substantial regional variations. The changes across the northern mid-latitudes are robust responses over time in both emissions scenarios, whereas the Southern Hemisphere changes appear critically sensitive to each individual emissions scenario. In addition, we find that established features of climate change can explain these patterns: polar amplification is implicated in the northern mid-latitude decrease in wind power, and enhanced land-sea thermal gradients account for the tropical and southern subtropical increases.

  14. High-energy Neutrino Emission from Short Gamma-Ray Bursts: Prospects for Coincident Detection with Gravitational Waves

    Energy Technology Data Exchange (ETDEWEB)

    Kimura, Shigeo S.; Murase, Kohta; Mészáros, Peter [Department of Physics, Pennsylvania State University, University Park, PA 16802 (United States); Kiuchi, Kenta [Center for Gravitational Physics, Yukawa Institute for Theoretical Physics, Kyoto, Kyoto 606-8502 (Japan)

    2017-10-10

    We investigate current and future prospects for coincident detection of high-energy neutrinos and gravitational waves (GWs). Short gamma-ray bursts (SGRBs) are believed to originate from mergers of compact star binaries involving neutron stars. We estimate high-energy neutrino fluences from prompt emission, extended emission (EE), X-ray flares, and plateau emission, and we show that neutrino signals associated with the EE are the most promising. Assuming that the cosmic-ray loading factor is ∼10 and the Lorentz factor distribution is lognormal, we calculate the probability of neutrino detection from EE by current and future neutrino detectors, and we find that the quasi-simultaneous detection of high-energy neutrinos, gamma-rays, and GWs is possible with future instruments or even with current instruments for nearby SGRBs having EE. We also discuss stacking analyses that will also be useful with future experiments such as IceCube-Gen2.

  15. The safe operation zone of the spark ignition engine working with dual renewable supplemented fuels (hydrogen+ethyl alcohol)

    Energy Technology Data Exchange (ETDEWEB)

    Al-Baghdadi, Maher Abdul-Resul Sadiq [Babylon Univ., Dept. of Mechanical Engineering, Babylon (Iraq)

    2001-04-01

    The effect of the amount of hydrogen/ethyl alcohol addition on the performance and pollutant emission of a four-stroke spark ignition engine has been studied. The results of the study show that all engine performance parameters have been improved when operating the gasoline spark ignition engine with dual addition of hydrogen and ethyl alcohol. The important improvements of alcohol addition are to reduce the NOx emission while increasing the higher useful compression ratio and output power of hydrogen-supplemented engine. An equation has been derived from experimental data to specify the least quantity of ethyl alcohol blended with gasoline and satisfying constant NOx emission when hydrogen is added. A chart limiting the safe operation zone of the engine fueled with dual renewable supplemented fuel, (hydrogen and ethyl alcohol) has been produced. The safe zone provides lower NOx and CO emission, lower s.f.c. and higher brake power compared to an equivalent gasoline engine. When ethyl alcohol is increased over 30%, it causes unstable engine operation which can be related to the fact that the fuel is not vaporized, and this causes a reduction in both brake power and efficiency. (Author)

  16. The response of the climate system to very high greenhouse gas emission scenarios

    International Nuclear Information System (INIS)

    Sanderson, Benjamin M; O'Neill, Brian C; Kiehl, Jeffrey T; Meehl, Gerald A; Knutti, Reto; Washington, Warren M

    2011-01-01

    Well informed decisions on climate policy necessitate simulation of the climate system for a sufficiently wide range of emissions scenarios. While recent literature has been devoted to low emissions futures, the potential for very high emissions has not been thoroughly explored. We specify two illustrative emissions scenarios that are significantly higher than the A1FI scenario, the highest scenario considered in past IPCC reports, and simulate them in a global climate model to investigate their climate change implications. Relative to the A1FI scenario, our highest scenario results in an additional 2 K of global mean warming above A1FI levels by 2100, a complete loss of arctic summer sea-ice by 2070 and an additional 43% sea level rise due to thermal expansion above A1FI levels by 2100. Regional maximum temperature increases from late 20th century values are 50-100% greater than A1FI increases, with some regions such as the Central US, the Tibetan plateau and Alaska showing a 300-400% increase above A1FI levels.

  17. The response of the climate system to very high greenhouse gas emission scenarios

    Energy Technology Data Exchange (ETDEWEB)

    Sanderson, Benjamin M; O' Neill, Brian C; Kiehl, Jeffrey T; Meehl, Gerald A [National Center for Atmospheric Research, Boulder, CO (United States); Knutti, Reto; Washington, Warren M, E-mail: bsander@ucar.edu [Institute for Atmospheric and Climate Science, ETH Zurich (Switzerland)

    2011-07-15

    Well informed decisions on climate policy necessitate simulation of the climate system for a sufficiently wide range of emissions scenarios. While recent literature has been devoted to low emissions futures, the potential for very high emissions has not been thoroughly explored. We specify two illustrative emissions scenarios that are significantly higher than the A1FI scenario, the highest scenario considered in past IPCC reports, and simulate them in a global climate model to investigate their climate change implications. Relative to the A1FI scenario, our highest scenario results in an additional 2 K of global mean warming above A1FI levels by 2100, a complete loss of arctic summer sea-ice by 2070 and an additional 43% sea level rise due to thermal expansion above A1FI levels by 2100. Regional maximum temperature increases from late 20th century values are 50-100% greater than A1FI increases, with some regions such as the Central US, the Tibetan plateau and Alaska showing a 300-400% increase above A1FI levels.

  18. Green Leaf Volatile Emissions during High Temperature and Drought Stress in a Central Amazon Rainforest.

    Science.gov (United States)

    Jardine, Kolby J; Chambers, Jeffrey Q; Holm, Jennifer; Jardine, Angela B; Fontes, Clarissa G; Zorzanelli, Raquel F; Meyers, Kimberly T; de Souza, Vinicius Fernadez; Garcia, Sabrina; Gimenez, Bruno O; Piva, Luani R de O; Higuchi, Niro; Artaxo, Paulo; Martin, Scot; Manzi, Antônio O

    2015-09-15

    Prolonged drought stress combined with high leaf temperatures can induce programmed leaf senescence involving lipid peroxidation, and the loss of net carbon assimilation during early stages of tree mortality. Periodic droughts are known to induce widespread tree mortality in the Amazon rainforest, but little is known about the role of lipid peroxidation during drought-induced leaf senescence. In this study, we present observations of green leaf volatile (GLV) emissions during membrane peroxidation processes associated with the combined effects of high leaf temperatures and drought-induced leaf senescence from individual detached leaves and a rainforest ecosystem in the central Amazon. Temperature-dependent leaf emissions of volatile terpenoids were observed during the morning, and together with transpiration and net photosynthesis, showed a post-midday depression. This post-midday depression was associated with a stimulation of C₅ and C₆ GLV emissions, which continued to increase throughout the late afternoon in a temperature-independent fashion. During the 2010 drought in the Amazon Basin, which resulted in widespread tree mortality, green leaf volatile emissions (C₆ GLVs) were observed to build up within the forest canopy atmosphere, likely associated with high leaf temperatures and enhanced drought-induced leaf senescence processes. The results suggest that observations of GLVs in the tropical boundary layer could be used as a chemical sensor of reduced ecosystem productivity associated with drought stress.

  19. Long term monitoring of Gamma-Ray emission from the BL Lacertae object (1ES 2200+420)

    Science.gov (United States)

    Gunawardhana, Isuru; VERITAS Collaboration

    2016-03-01

    Blazars are a class of Active Galactic Nuclei (AGN) that have relativistic jets pointing along the observer line of sight. Blazars exhibit variable emission extending from radio to TeV energies. The variability timescale of the TeV flux is a key component of understanding the location of the very high energy emission zones. Deep observations of the quiescent state measurements are also required to disentangle the flaring state emission from quiescent state emission, a prerequisite for understanding the origin of blazar spectral variability. BL Lacertae (also known as 1ES 2200+420), as the namesake for all BL Lac objects, is a prime example of one such blazar. The VERITAS Observatory, an Imaging Atmospheric Cherenkov Telescope (IACT) array sensitive to gamma rays in the range from 85 GeV to 30 TeV, dedicates approximately 110 hours per year on deep observations of known gamma-ray blazars. In this talk, I will describe the TeV photon flux variability of BL Lacertae measured by VERITAS from 2013 to 2015.

  20. Radio emission from Supernovae and High Precision Astrometry

    Science.gov (United States)

    Perez-Torres, M. A.

    1999-11-01

    The present thesis work makes contributions in two scientific fronts: differential astrometry over the largest angular scales ever attempted (approx. 15 arcdegrees) and numerical simulations of radio emission from very young supernovae. In the first part, we describe the results of the use of very-long-baseline interferometry (VLBI) in one experiment designed to measure with very high precision the angular distance between the radio sources 1150+812 (QSO) and 1803+784 (BL Lac). We observed the radio sources on 19 November 1993 using an intercontinental array of radio telescopes, which simultaneously recorded at 2.3 and 8.4 GHz. VLBI differential astrometry is capable, Nature allowing, of yielding source positions with precisions well below the milliarcsecond level. To achieve this precision, we first had to accurately model the rotation of the interferometric fringes via the most precise models of Earth Orientation Parameters (EOP; precession, polar motion and UT1, nutation). With this model, we successfully connected our phase delay data at both frequencies and, using difference astrometric techniques, determined the coordinates of 1803+784 relative to those of 1150+812-within the IERS reference frame--with an standard error of about 0.6 mas in each coordinate. We then corrected for several effects including propagation medium (mainly the atmosphere and ionosphere), and opacity and source-structure effects within the radio sources. We stress that our dual-frequency measurements allowed us to accurately subtract the ionosphere contribution from our data. We also used GPS-based TEC measurements to independently find the ionosphere contribution, and showed that these contributions agree with our dual-frequency measurements within about 2 standard deviations in the less favorables cases (the longest baselines), but are usually well within one standard deviation. Our estimates of the relative positions, whether using dual-frequency-based or GPS-based ionosphere

  1. Extreme pollution of soils by emissions of the copper-nickel industrial complex in the Kola Peninsula

    Science.gov (United States)

    Kashulina, G. M.

    2017-07-01

    The distribution of the total Ni, Cu, Co, Cd, Pb, and Zn contents was studied in the soil profiles of six catenas in the zone subjected to emissions of the copper-nickel industrial complex, which is the largest source of SO2 and heavy metals in northern Europe. The results show that, at present, the concentrations of Ni and Cu in the upper organic soil horizons in the impact zone reach extreme levels of 9000 and 6000 mg/kg, respectively. Under conditions of the long-term intense multi-element industrial emissions, the modern levels of the accumulation of polluting substances in soils greatly depend on the indirect factors, such as the degree of the technogenic degradation of soils with the loss of a significant part of soil organic matter, the reaching of threshold saturation of the topsoil with polluting metals, and competitive relationships between chemical elements. The state of the ecosystems in the impact zone varied greatly and did not always agree with the contents of the main metals-pollutants in the soils. The moisture conditions determined by the landscape position affected significantly the resistance of the ecosystems to emissions.

  2. Thermal and nonthermal electron cyclotron emission by high-temperature tokamak plasmas

    International Nuclear Information System (INIS)

    Airoldi, A.; Ramponi, G.

    1997-01-01

    An analysis of the electron cyclotron emission (ECE) spectra emitted by a high-temperature tokamak plasma in the frequency range of the second and third harmonic of the electron cyclotron frequency is made, both in purely Maxwellian and in non-Maxwellian cases (i.e., in the presence of a current-carrying superthermal tail). The work is motivated mainly by the experimental observations made in the supershot plasmas of the Tokamak Fusion Test Reactor (TFTR), where a systematic disagreement is found between the T e measurements by second-harmonic ECE and Thomson scattering. We show that, by properly taking into account the overlap of superthermals-emitted third harmonic with second-harmonic bulk emission, the radiation temperature observed about the central frequency of the second harmonic may be enhanced up to 30%endash 40% compared to the corresponding thermal value. Moreover we show that, for parameters relevant to the International Thermonuclear Experimental Reactor (ITER) with T e (0)>7 keV, the overlap between the second and the downshifted third harmonic seriously affects the central plasma region, so that the X-mode emission at the second harmonic becomes unsuitable for local T e measurements. copyright 1997 American Institute of Physics

  3. Ammonia, hydrogen sulfide, carbon dioxide and particulate matter emissions from California high-rise layer houses

    Science.gov (United States)

    Lin, X.-J.; Cortus, E. L.; Zhang, R.; Jiang, S.; Heber, A. J.

    2012-01-01

    Ammonia and hydrogen sulfide are hazardous substances that are regulated by the U.S. Environmental Protection Agency through community right-to-know legislation (EPCRA, EPA, 2011). The emissions of ammonia and hydrogen sulfide from large commercial layer facilities are of concern to legislators and nearby neighbors. Particulate matter (PM 10 and PM 2.5) released from layer houses are two of seven criteria pollutants for which EPA has set National Ambient Air Quality Standards as required by the Clean Air Act. Therefore, it is important to quantify the baseline emissions of these pollutants. The emissions of ammonia, hydrogen sulfide, carbon dioxide and PM from two California high-rise layer houses were monitored for two years from October 2007 to October 2009. Each house had 32,500 caged laying hens. The monitoring site was setup in compliance with a U.S. EPA-approved quality assurance project plan. The results showed the average daily mean emission rates of ammonia, hydrogen sulfide and carbon dioxide were 0.95 ± 0.67 (standard deviation) g d -1 bird -1, 1.27 ± 0.78 mg d -1 bird -1 and 91.4 ± 16.5 g d -1 bird -1, respectively. The average daily mean emission rates of PM 2.5, PM 10 and total suspended particulate (TSP) were 5.9 ± 12.6, 33.4 ± 27.4, and 78.0 ± 42.7 mg d -1 bird -1, respectively. It was observed that ammonia emission rates in summer were lower than in winter because the high airflow stabilized the manure by drying it. The reductions due to lower moisture content were greater than the increases due to higher temperature. However, PM 10 emission rates in summer were higher than in winter because the drier conditions coupled with higher internal air velocities increased PM 10 release from feathers, feed and manure.

  4. Systematic search for very-high-energy gamma-ray emission from bow shocks of runaway stars

    Science.gov (United States)

    H.E.S.S. Collaboration; Abdalla, H.; Abramowski, A.; Aharonian, F.; Ait Benkhali, F.; Akhperjanian, A. G.; Andersson, T.; Angüner, E. O.; Arakawa, M.; Arrieta, M.; Aubert, P.; Backes, M.; Balzer, A.; Barnard, M.; Becherini, Y.; Becker Tjus, J.; Berge, D.; Bernhard, S.; Bernlöhr, K.; Blackwell, R.; Böttcher, M.; Boisson, C.; Bolmont, J.; Bordas, P.; Bregeon, J.; Brun, F.; Brun, P.; Bryan, M.; Büchele, M.; Bulik, T.; Capasso, M.; Carr, J.; Casanova, S.; Cerruti, M.; Chakraborty, N.; Chalme-Calvet, R.; Chaves, R. C. G.; Chen, A.; Chevalier, J.; Chrétien, M.; Coffaro, M.; Colafrancesco, S.; Cologna, G.; Condon, B.; Conrad, J.; Cui, Y.; Davids, I. D.; Decock, J.; Degrange, B.; Deil, C.; Devin, J.; deWilt, P.; Dirson, L.; Djannati-Ataï, A.; Domainko, W.; Donath, A.; Drury, L. O.'C.; Dutson, K.; Dyks, J.; Edwards, T.; Egberts, K.; Eger, P.; Ernenwein, J.-P.; Eschbach, S.; Farnier, C.; Fegan, S.; Fernandes, M. V.; Fiasson, A.; Fontaine, G.; Förster, A.; Funk, S.; Füßling, M.; Gabici, S.; Gajdus, M.; Gallant, Y. A.; Garrigoux, T.; Giavitto, G.; Giebels, B.; Glicenstein, J. F.; Gottschall, D.; Goyal, A.; Grondin, M.-H.; Hahn, J.; Haupt, M.; Hawkes, J.; Heinzelmann, G.; Henri, G.; Hermann, G.; Hervet, O.; Hinton, J. A.; Hofmann, W.; Hoischen, C.; Holler, M.; Horns, D.; Ivascenko, A.; Iwasaki, H.; Jacholkowska, A.; Jamrozy, M.; Janiak, M.; Jankowsky, D.; Jankowsky, F.; Jingo, M.; Jogler, T.; Jouvin, L.; Jung-Richardt, I.; Kastendieck, M. A.; Katarzyński, K.; Katsuragawa, M.; Katz, U.; Kerszberg, D.; Khangulyan, D.; Khélifi, B.; Kieffer, M.; King, J.; Klepser, S.; Klochkov, D.; Kluźniak, W.; Kolitzus, D.; Komin, Nu.; Kosack, K.; Krakau, S.; Kraus, M.; Krüger, P. P.; Laffon, H.; Lamanna, G.; Lau, J.; Lees, J.-P.; Lefaucheur, J.; Lefranc, V.; Lemière, A.; Lemoine-Goumard, M.; Lenain, J.-P.; Leser, E.; Lohse, T.; Lorentz, M.; Liu, R.; López-Coto, R.; Lypova, I.; Marandon, V.; Marcowith, A.; Mariaud, C.; Marx, R.; Maurin, G.; Maxted, N.; Mayer, M.; Meintjes, P. J.; Meyer, M.; Mitchell, A. M. W.; Moderski, R.; Mohamed, M.; Mohrmann, L.; Morå, K.; Moulin, E.; Murach, T.; Nakashima, S.; de Naurois, M.; Niederwanger, F.; Niemiec, J.; Oakes, L.; O'Brien, P.; Odaka, H.; Öttl, S.; Ohm, S.; Ostrowski, M.; Oya, I.; Padovani, M.; Panter, M.; Parsons, R. D.; Pekeur, N. W.; Pelletier, G.; Perennes, C.; Petrucci, P.-O.; Peyaud, B.; Piel, Q.; Pita, S.; Poon, H.; Prokhorov, D.; Prokoph, H.; Pühlhofer, G.; Punch, M.; Quirrenbach, A.; Raab, S.; Reimer, A.; Reimer, O.; Renaud, M.; de los Reyes, R.; Richter, S.; Rieger, F.; Romoli, C.; Rowell, G.; Rudak, B.; Rulten, C. B.; Sahakian, V.; Saito, S.; Salek, D.; Sanchez, D. A.; Santangelo, A.; Sasaki, M.; Schlickeiser, R.; Schüssler, F.; Schulz, A.; Schwanke, U.; Schwemmer, S.; Seglar-Arroyo, M.; Settimo, M.; Seyffert, A. S.; Shafi, N.; Shilon, I.; Simoni, R.; Sol, H.; Spanier, F.; Spengler, G.; Spies, F.; Stawarz, Ł.; Steenkamp, R.; Stegmann, C.; Stycz, K.; Sushch, I.; Takahashi, T.; Tavernet, J.-P.; Tavernier, T.; Taylor, A. M.; Terrier, R.; Tibaldo, L.; Tiziani, D.; Tluczykont, M.; Trichard, C.; Tsuji, N.; Tuffs, R.; Uchiyama, Y.; van der Walt, D. J.; van Eldik, C.; van Rensburg, C.; van Soelen, B.; Vasileiadis, G.; Veh, J.; Venter, C.; Viana, A.; Vincent, P.; Vink, J.; Voisin, F.; Völk, H. J.; Vuillaume, T.; Wadiasingh, Z.; Wagner, S. J.; Wagner, P.; Wagner, R. M.; White, R.; Wierzcholska, A.; Willmann, P.; Wörnlein, A.; Wouters, D.; Yang, R.; Zabalza, V.; Zaborov, D.; Zacharias, M.; Zanin, R.; Zdziarski, A. A.; Zech, A.; Zefi, F.; Ziegler, A.; Żywucka, N.

    2018-04-01

    Context. Runaway stars form bow shocks by ploughing through the interstellar medium at supersonic speeds and are promising sources of non-thermal emission of photons. One of these objects has been found to emit non-thermal radiation in the radio band. This triggered the development of theoretical models predicting non-thermal photons from radio up to very-high-energy (VHE, E ≥ 0.1 TeV) gamma rays. Subsequently, one bow shock was also detected in X-ray observations. However, the data did not allow discrimination between a hot thermal and a non-thermal origin. Further observations of different candidates at X-ray energies showed no evidence for emission at the position of the bow shocks either. A systematic search in the Fermi-LAT energy regime resulted in flux upper limits for 27 candidates listed in the E-BOSS catalogue. Aim. Here we perform the first systematic search for VHE gamma-ray emission from bow shocks of runaway stars. Methods: Using all available archival H.E.S.S. data we search for very-high-energy gamma-ray emission at the positions of bow shock candidates listed in the second E-BOSS catalogue release. Out of the 73 bow shock candidates in this catalogue, 32 have been observed with H.E.S.S. Results: None of the observed 32 bow shock candidates in this population study show significant emission in the H.E.S.S. energy range. Therefore, flux upper limits are calculated in five energy bins and the fraction of the kinetic wind power that is converted into VHE gamma rays is constrained. Conclusions: Emission from stellar bow shocks is not detected in the energy range between 0.14 and 18 TeV.The resulting upper limits constrain the level of VHE gamma-ray emission from these objects down to 0.1-1% of the kinetic wind energy.

  5. High rates of organic carbon processing in the hyporheic zone of intermittent streams.

    Science.gov (United States)

    Burrows, Ryan M; Rutlidge, Helen; Bond, Nick R; Eberhard, Stefan M; Auhl, Alexandra; Andersen, Martin S; Valdez, Dominic G; Kennard, Mark J

    2017-10-16

    Organic carbon cycling is a fundamental process that underpins energy transfer through the biosphere. However, little is known about the rates of particulate organic carbon processing in the hyporheic zone of intermittent streams, which is often the only wetted environment remaining when surface flows cease. We used leaf litter and cotton decomposition assays, as well as rates of microbial respiration, to quantify rates of organic carbon processing in surface and hyporheic environments of intermittent and perennial streams under a range of substrate saturation conditions. Leaf litter processing was 48% greater, and cotton processing 124% greater, in the hyporheic zone compared to surface environments when calculated over multiple substrate saturation conditions. Processing was also greater in more saturated surface environments (i.e. pools). Further, rates of microbial respiration on incubated substrates in the hyporheic zone were similar to, or greater than, rates in surface environments. Our results highlight that intermittent streams are important locations for particulate organic carbon processing and that the hyporheic zone sustains this fundamental process even without surface flow. Not accounting for carbon processing in the hyporheic zone of intermittent streams may lead to an underestimation of its local ecological significance and collective contribution to landscape carbon processes.

  6. Development and evaluation of high-resolution regional emission inventory: A case study for Jiangsu Province, China

    Science.gov (United States)

    Zhao, Y.; Mao, P.; Zhou, Y.

    2017-12-01

    Improved emission inventories are crucial for better understanding atmospheric chemistry with air quality simulation at regional or local scales. Using the bottom-up approach, a high-resolution emission inventory was developed for Jiangsu China. Key parameters for over 6000 industrial sources were investigated, compiled and revised at plant level based on various data sources and on-site survey. Totally 56 NMVOCs samples were collected in 9 chemical plants and analyzed with a gas chromatography-mass spectrometry system. Source profiles of stack emissions from synthetic rubber, acetate fiber, polyether, vinyl acetate, and ethylene production, and those of fugitive emissions from ethylene, butanol and octanol, propylene epoxide, polyethylene and glycol production were obtained. Improvement of this provincial inventory was evaluated through comparisons with other inventories at larger spatial scales, using satellite observation and air quality modeling. Three inventories (national, regional, and provincial by this work) were applied in the Models-3/Community Multi-scale Air Quality (CMAQ) system to evaluate the model performances with different emission inputs. The best agreement between available ground observation and simulation was found when the provincial inventory was applied, indicated by the smallest normalized mean bias (NMB) and normalized mean errors (NME) for all the concerned species SO2, NO2, O3 and PM2.5. The result thus implied the advantage of improved emission inventory at local scale for high resolution air quality modeling. Under the unfavorable meteorology in which horizontal and vertical movement of atmosphere was limited, the simulated SO2 concentrations at downtown Nanjing (the capital city of Jiangsu) using the regional or national inventories were much higher than observation, implying overestimated urban emissions when economy or population densities were applied to downscale or allocate the emissions. With more accurate spatial distribution

  7. A High-Performance VME-Based Acquisition System for Positron Emission Mammography

    International Nuclear Information System (INIS)

    Abbott, D.J.; Weisenberger, A.; Majewski, S.; Kieper, D.; Kross, B.; Popov, V.; Wojcik, R.; Raylman, R.R.

    2001-01-01

    A prototype for a practical and economical breast imaging system for cancer detection is currently under development at Jefferson Lab. The latest advances in bright, fast, crystal scintillators, compact position-sensitive photomultipliers (PSPMT), and high-performance digitizing and readout electronics are being used to develop a compact imager based on Positron Emission Tomography (PET). To facilitate the performance demands of the detector as well as the high number of readout channels, the data acquisition system is built around an intelligent, self-contained, VME form-factor

  8. SURFACE FILMS TO SUPPRESS FIELD EMISSION IN HIGH-POWER MICROWAVE COMPONENTS

    Energy Technology Data Exchange (ETDEWEB)

    Hirshfield, Jay l

    2014-02-07

    Results are reported on attempts to reduce the RF breakdown probability on copper accelerator structures by applying thin surface films that could suppress field emission of electrons. Techniques for application and testing of copper samples with films of metals with work functions higher than copper are described, principally for application of platinum films, since platinum has the second highest work function of any metal. Techniques for application of insulating films are also described, since these can suppress field emission and damage on account of dielectric shielding of fields at the copper surface, and on account of the greater hardness of insulating films, as compared with copper. In particular, application of zirconium oxide films on high-field portions of a 11.424 GHz SLAC cavity structure for breakdown tests are described.

  9. Highly stable colloidal TiO2 nanocrystals with strong violet-blue emission

    International Nuclear Information System (INIS)

    Ghamsari, Morteza Sasani; Gaeeni, Mohammad Reza; Han, Wooje; Park, Hyung-Ho

    2016-01-01

    Improved sol–gel method has been applied to prepare highly stable colloidal TiO 2 nanocrystals. The synthesized titania nanocrystals exhibit strong emission in the violet-blue wavelength region. Very long evolution time was obtained by preventing the sol to gel conversion with reflux process. FTIR, XRD, UV–vis absorption, photoluminescence and high resolution transmission electron microscope (HRTEM) were used to study the optical properties, crystalline phase, morphology, shape and size of prepared TiO 2 colloidal nanocrystals. HRTEM showed that the diameter of TiO 2 colloidal nanocrystals is about 5 nm. Although the PL spectra show similar spectral features upon excitation wavelengths at 280, 300 and 350 nm, but their emission intensities are significantly different from each other. Photoluminescence quantum yield for TiO 2 colloidal nanocrystals is estimated to be 49% with 280 nm excitation wavelength which is in agreement and better than reported before. Obtained results confirm that the prepared colloidal TiO 2 sample has enough potential for optoelectronics applications.

  10. Visualization of the heat release zone of highly turbulent premixed jet flames

    Science.gov (United States)

    Lv, Liang; Tan, Jianguo; Zhu, Jiajian

    2017-10-01

    Visualization of the heat release zone (HRZ) of highly turbulent flames is significantly important to understand the interaction between turbulence and chemical reactions, which is the foundation to design and optimize engines. Simultaneous measurements of OH and CH2O using planar laser-induced fluorescence (PLIF) were performed to characterize the HRZ. A well-designed piloted premixed jet burner was employed to generate four turbulent premixed CH4/air jet flames, with different jet Reynolds numbers (Rejet) ranging from 4900 to 39200. The HRZ was visualized by both the gradient of OH and the pixel-by-pixel product of OH and CH2O. It is shown that turbulence has an increasing effect on the spatial structure of the flame front with an increasing height above the jet exit for the premixed jet flames, which results in the broadening of the HRZ and the increase of the wrinkling. The HRZ remains thin as the Rejet increases, whereas the preheat zone is significantly broadened and thickened. This indicates that the smallest turbulent eddies can only be able to enter the flame front rather than the HRZ in the present flame conditions. The flame quenching is observed with Rejet = 39200, which may be due to the strong entrainment of the cold air from outside of the burned gas region.

  11. A highly spatially resolved GIS-based model to assess the isoprenoid emissions from key Italian ecosystems

    Science.gov (United States)

    Pacheco, Claudia Kemper; Fares, Silvano; Ciccioli, Paolo

    2014-10-01

    The amount of Biogenic Volatile Organic Compounds (BVOC) emitted from terrestrial vegetation is of great importance in atmospheric reactivity, particularly for ozone-forming reactions and as condensation nuclei in aerosol formation and growth. This work presents a detailed inventory of isoprenoid emissions from vegetation in Italy using an original approach which combines state of the art models to estimate the species-specific isoprenoid emissions and a Geographic Information System (GIS) where emissions are spatially represented. Isoprenoid species and basal emission factors were obtained by combining results from laboratory experiments with those published in literature. For the first time, our investigation was not only restricted to isoprene and total monoterpenes, but our goal was to provide maps of isoprene and individual monoterpenes at a high-spatial (∼1 km2) and temporal resolution (daily runs, monthly trends in emissions are discussed in the text). Another novelty in our research was the inclusion of the effects of phenology on plant emissions. Our results show that: a) isoprene, a-pinene, sabinene and b-pinene are the most important compounds emitted from vegetation in Italy; b) annual biogenic isoprene and monoterpene fluxes for the year 2006 were ∼31.30 Gg and ∼37.70 Gg, respectively; and c) Quercus pubescens + Quercus petrea + Quercus robur, Quercus ilex, Quercus suber and Fagus sylvatica are the principal isoprenoid emitting species in the country. The high spatial and temporal resolution, combined with the species-specific emission output, makes the model particularly suitable for assessing local budgets, and for modeling photochemical pollution in Italy.

  12. Acoustic emission analysis coupled with thermogravimetric experiments dedicated to high temperature corrosion studies on metallic alloys

    International Nuclear Information System (INIS)

    Serris, Eric; Al Haj, Omar; Peres, Veronique; Cournil, Michel; Kittel, Jean; Grosjean, Francois; Ropital, Francois

    2014-01-01

    High temperature corrosion of metallic alloys (like iron, nickel, zirconium alloys) can damage equipment of many industrial fields (refinery, petrochemical, nuclear..). Acoustic emission (AE) is an interesting method owing to its sensitivity and its non-destructive aspect to quantify the level of damage in use of these alloys under various environmental conditions. High temperature corrosive phenomena create stresses in the materials; the relaxation by cracks of these stresses can be recorded and analyzed using the AE system. The goal of our study is to establish an acoustic signals database which assigns the acoustic signals to the specific corrosion phenomena. For this purpose, thermogravimetric analysis (TGA) is coupled with acoustic emission (AE) devices. The oxidation of a zirconium alloy, zircaloy-4, is first studied using thermogravimetric experiment coupled to acoustic emission analysis at 900 C. An inward zirconium oxide scale, preliminary dense, then porous, grow during the isothermal isobaric step. The kinetic rate increases significantly after a kinetic transition (breakaway). This acceleration occurs with an increase of acoustic emission activity. Most of the acoustic emission bursts are recorded after the kinetic transition. Acoustic emission signals are also observed during the cooling of the sample. AE numerical treatments (using wavelet transform) completed by SEM microscopy characterizations allows us to distinguish the different populations of cracks. Metal dusting represents also a severe form of corrosive degradation of metal alloy. Iron metal dusting corrosion is studied by AE coupled with TGA at 650 C under C 4 H 10 + H 2 + He atmosphere. Acoustic emission signals are detected after a significant increase of the sample mass.

  13. Near UV-visible line emission from tungsten highly-charged ions in Large Helical Device

    International Nuclear Information System (INIS)

    Kato, D.; Sakaue, H.A.; Murakami, I.; Goto, M.; Oishi, T.; Morita, S.; Fujii, K.; Nakamura, N.; Koike, F.; Sasaki, Akira; Ding, X.-B.; Dong, C.-Z.

    2015-01-01

    Wavelengths of emission lines from tungsten highly-charged ions have been precisely measured in near UV-visible range (320 - 356 nm and 382 - 402 nm) at Large Helical Device (LHD) by tungsten pellet injection. The tungsten emission lines were assigned based on its line-integrated intensity profiles on a poloidal cross section. The ground-term magnetic-dipole (M1) lines of W 26+,27+ and an M1 line of a metastable excited state of W 28+ , whose wavelengths have been determined by measurements using electron-beam-ion-traps (EBITs), are identified in the LHD spectra. The present results partially compliment wavelength data of tungsten highly-charged ions in the near UV-visible range. (author)

  14. Achieving high-efficiency emission depletion nanoscopy by employing cross relaxation in upconversion nanoparticles.

    Science.gov (United States)

    Zhan, Qiuqiang; Liu, Haichun; Wang, Baoju; Wu, Qiusheng; Pu, Rui; Zhou, Chao; Huang, Bingru; Peng, Xingyun; Ågren, Hans; He, Sailing

    2017-10-20

    Stimulated emission depletion microscopy provides a powerful sub-diffraction imaging modality for life science studies. Conventionally, stimulated emission depletion requires a relatively high light intensity to obtain an adequate depletion efficiency through only light-matter interaction. Here we show efficient emission depletion for a class of lanthanide-doped upconversion nanoparticles with the assistance of interionic cross relaxation, which significantly lowers the laser intensity requirements of optical depletion. We demonstrate two-color super-resolution imaging using upconversion nanoparticles (resolution ~ 66 nm) with a single pair of excitation/depletion beams. In addition, we show super-resolution imaging of immunostained cytoskeleton structures of fixed cells (resolution ~ 82 nm) using upconversion nanoparticles. These achievements provide a new perspective for the development of photoswitchable luminescent probes and will broaden the applications of lanthanide-doped nanoparticles for sub-diffraction microscopic imaging.

  15. New geometrical compactness measures for zones design

    Directory of Open Access Journals (Sweden)

    Eric Alfredo Rincón-García

    2012-07-01

    Full Text Available The design of compact zones has been studied because of its influence in the creation of zones with regular forms, which are easier to analyze, to investigate or to administer. This paper propose a new method to measure compactness,by means of the transformation of the original geographical spaces, into figures formed with square cells, which are used to measure the similarity between the original zone and an ideal zone with straight forms. The proposed method was applied to design electoral zones, which must satisfy constraints of compactness, contiguity and population balance, in a topographical configuration that favors the creation of twisted and diffuse shapes. The results show that the new method favors the creation of zones with straight forms, without an important effect to the population balance, which are considered zones of high quality. Keywords: Redistricting, compactness, simulated annealing, GIS. Mathematics Subject Classification: 90C59, 90C29, 68T20.

  16. Workstation studies and radiological zoning in a temporary PET/CT installation; Etudes de poste et zonage radiologique dans une installation provisoire TEP/TDM

    Energy Technology Data Exchange (ETDEWEB)

    Vrigneaud, J.M.; Lombardo, J.; Hassoun, S.; Riu, J.L.; Leguludec, D. [Service de Medecine Nucleaire, groupe hospitalier Bichat-Claude Bernard, AP-HP, 46, rue Henri Huchard, 75877 Paris Cedex 18 (France); Hassoun, S. [Service de Pharmacie, unite de Radiopharmacie, groupe hospitalier Bichat-Claude (France)

    2008-07-01

    Within the frame of a complete restructuring of the 'Hopital Bichat' nuclear medicine department, a temporary building will host the high energy activity (PET/CT, Positron emission tomography - computed tomography) during these restructuring works. The authors summarize the study performed in terms of radioprotection, dose rate and dose. A radiological zoning has been defined and the different circulations (personnel, patients, wastes, medicines, supplies, and so on) have been optimized. A risk predictive analysis has also been performed

  17. Riparian zone hydrology and biogeochemistry as a function of stream evolution stage in glaciated landscapes of the US Northeast

    Science.gov (United States)

    Rook, S. P.; Vidon, P.; Walter, M. T.

    2011-12-01

    direction in the riparian zones. Owing to more prolonged saturation, we expect that the oxbow setting will exhibit anoxic conditions, and associated biogeochemistry. Finally, we hypothesize clear relationships among N, P, Fe, and GHG dynamics. In areas of significant denitrification, we expect to see an increase in Fe reduction, PO43- release, N2O emission, and CH4 emission, and a decrease in CO2 emission. Quantifying these interactions will enhance our ability to model riparian biogeochemical processes, promote water quality, and comprehend to what extent the promotion of riparian zones for nitrate removal is done at the expense of air quality (with respect to GHG emissions) and/or water quality (with respect to P).

  18. Characterization of microstructure and local deformation in 316NG weld heat-affected zone and stress corrosion cracking in high temperature water

    International Nuclear Information System (INIS)

    Lu Zhanpeng; Shoji, Tetsuo; Meng Fanjiang; Xue He; Qiu Yubing; Takeda, Yoichi; Negishi, Koji

    2011-01-01

    Research highlights: → Away from the fusion line, kernel average misorientation and hardness decrease. → Away from the fusion line, the fraction of Σ3 boundaries increases. → Crack growth in high temperature water correlates to kernel average misorientation and hardness. → SCC along random boundaries as well as extensive intergranular branching near the fusion line. - Abstract: Microstructure and local deformation in 316NG weld heat-affected zones were measured by electron-back scattering diffraction and hardness measurements. With increasing the distance from the fusion line, kernel average misorientation decreases and the fraction of Σ3 boundaries increases. Stress corrosion cracking growth rates in high temperature water were measured at different locations in the heat-affected zones that correspond to different levels of strain-hardening represented by kernel average misorientation and hardness distribution. Intergranular cracking along random boundaries as well as extensive intergranular crack branching is observed in the heat-affected zone near the weld fusion line.

  19. Fiber optics spectrochemical emission sensors

    Science.gov (United States)

    Griffin, Jeffrey W.; Olsen, Khris B.

    1992-01-01

    A method of in situ monitoring of a body of a fluid stored in a tank or groundwater or vadose zone gases in a well for the presence of selected chemical species uses a probe insertable into the well or tank via a cable and having electrical apparatus for exciting selected chemical species in the body of fluid. The probe can have a pair of electrodes for initiating a spark or a plasma cell for maintaining a plasma to excite the selected chemical species. The probe also has optical apparatus for receiving optical emissions emitted by the excited species and optically transmitting the emissions via the cable to an analysis location outside the well. The analysis includes detecting a selected wavelength in the emissions indicative of the presence of the selected chemical species. A plurality of probes can be suspended at an end of a respective cable, with the transmitting and analyzing steps for each probe being synchronized sequentially for one set of support equipment and instrumentation to monitor at multiple test points. The optical apparatus is arranged about the light guide axis so that the selected chemical species are excited the fluid in alignment with the light guide axis and optical emissions are received from the excited chemical species along such axis.

  20. Denitrification capacity and greenhouse gas emissions of soils in channelized and restored reaches along an Alpine river corridor

    Science.gov (United States)

    Shrestha, Juna; Niklaus, Pascal; Samaritani, Emanuela; Frossard, Emmanuel; Tockner, Klement; Luster, Jörg

    2010-05-01

    , willow bush and mixed forest exhibited intermediate levels. Spatial variability was higher in the grass zone compared to other FPZs especially during the flooding events when denitrification hot spots occurred in this zone. In the gravel zone DEA was high when saturated slowly - as during a minor flood -, while it was low under dry conditions as well as during saturation following a major flood. The N2O emission rate was low in all FPZ throughout the year, except during few hot moments (i.e. in grass FPZ two weeks after major summer flood events and in grass and willow bush zone during winter. In conclusion, replacing a rather homogeneous floodplain by a spatially complex and temporally dynamic mosaic of FPZ of different succession stages (gravel bars with a varying degree of plant colonization and cover by fresh overbank sediments) has not led to fundamental changes in denitrification potential of the river floodplain. It is rather the shift from a homogeneously distributed filter function to a filter function mainly located in spatially and temporally defined hot spots. However, this change appears to be coupled to increased trace greenhouse gas emissions (methane and nitrous oxide) from certain hot spots. In addition, the study confirms the high denitrification potential of advanced stable wetlands as represented by the willow forest.

  1. Optical emission from a high-refractive-index waveguide excited by a traveling electron beam

    International Nuclear Information System (INIS)

    Kuwamura, Yuji; Yamada, Minoru; Okamoto, Ryuichi; Kanai, Takeshi; Fares, Hesham

    2008-01-01

    An optical emission scheme was demonstrated, in which a high-refractive-index waveguide is excited by a traveling electron beam in a vacuum environment. The waveguide was made of Si-SiO 2 layers. The velocity of light propagating in the waveguide was slowed down to 1/3 of that in free space due to the high refractive index of Si. The light penetrated partly into the vacuum in the form of a surface wave. The electron beam was emitted from an electron gun and propagated along the surface of the waveguide. When the velocity of the electron coincided with that of the light, optical emission was observed. This emission is a type of Cherenkov radiation and is not conventional cathode luminescence from the waveguide materials because Si and SiO 2 are transparent to light at the emitted wavelength. This type of emission was observed in an optical wavelength range from 1.2 to 1.6 μm with an electron acceleration voltage of 32-42 kV. The characteristics of the emitted light, such as the polarization direction and the relation between the acceleration voltage of the electron beam and the optical wavelength, coincided well with the theoretical results. The coherent length of an electron wave in the vacuum was confirmed to be equal to the electron spacing, as found by measuring the spectral profile of the emitted light

  2. High-resolution simulation of link-level vehicle emissions and concentrations for air pollutants in a traffic-populated eastern Asian city

    Directory of Open Access Journals (Sweden)

    S. Zhang

    2016-08-01

    Full Text Available Vehicle emissions containing air pollutants created substantial environmental impacts on air quality for many traffic-populated cities in eastern Asia. A high-resolution emission inventory is a useful tool compared with traditional tools (e.g. registration data-based approach to accurately evaluate real-world traffic dynamics and their environmental burden. In this study, Macau, one of the most populated cities in the world, is selected to demonstrate a high-resolution simulation of vehicular emissions and their contribution to air pollutant concentrations by coupling multimodels. First, traffic volumes by vehicle category on 47 typical roads were investigated during weekdays in 2010 and further applied in a networking demand simulation with the TransCAD model to establish hourly profiles of link-level vehicle counts. Local vehicle driving speed and vehicle age distribution data were also collected in Macau. Second, based on a localized vehicle emission model (e.g. the emission factor model for the Beijing vehicle fleet – Macau, EMBEV–Macau, this study established a link-based vehicle emission inventory in Macau with high resolution meshed in a temporal and spatial framework. Furthermore, we employed the AERMOD (AMS/EPA Regulatory Model model to map concentrations of CO and primary PM2.5 contributed by local vehicle emissions during weekdays in November 2010. This study has discerned the strong impact of traffic flow dynamics on the temporal and spatial patterns of vehicle emissions, such as a geographic discrepancy of spatial allocation up to 26 % between THC and PM2.5 emissions owing to spatially heterogeneous vehicle-use intensity between motorcycles and diesel fleets. We also identified that the estimated CO2 emissions from gasoline vehicles agreed well with the statistical fuel consumption in Macau. Therefore, this paper provides a case study and a solid framework for developing high-resolution environment assessment tools for other

  3. Ankaramite: A New Type of High-Magnesium and High-Calcium Primitive Melt in the Magnitogorsk Island-Arc Zone (Southern Urals)

    Science.gov (United States)

    Pushkarev, E. V.; Ryazancev, A. V.; Gottman, I. A.; Degtyarev, K. E.; Kamenetsky, V. S.

    2018-04-01

    This work describes the geological position, mineral and chemical composition of high-Mg effusive ankaramites occurring as dykes and lava flows. They were found in the mélange zone of the western margin of the Magnitogorsk island arc zone in the Southern Urals. Data on the liquidus association of phenocrysts and on the composition of the matrix of effusives are given. According to the data obtained, the conclusion was drawn that the ankaramites studied can be attributed to the primary island arc melts, which were not subject to essential differentiation. This type of effusives has not been distinguished previously among island arc volcanogenic formations of the Urals. It is shown that ankaramites can be considered to be primary melts parental for dunite-clinopyroxenites-gabbro complexes of Ural-Alaskan type. The occurrence of ankaramites in the Paleozoic island arc formations of the Urals indicates the wehrlite composition of the mantle as the reason for the extremely wide development of wehrlites and clinopyroxenites in different mafic-ultramafic complexes of the Urals.

  4. Interaction of 14 MeV neutrons with hydrogenated target proton emission calculation

    International Nuclear Information System (INIS)

    Martin, G.; Perez, N.; Desdin.

    1996-01-01

    Using neutron emission data of a 14 MeV neutron generator, a paraffin target, and based on the n + H 1 → n '+ p reaction, have been obtained the characteristics of the proton emission in a proton-neutron mixed field. It was used Monte Carlo simulation and it was obtained the proton output as function of the converter width and the energy spectrum of protons corresponding to different converter thickness. Among 0.07 and 0.2 cm there is a maximum zone for the proton emission. The energy spectrum agrees with obtained on previous papers. Figures showing these results are provided

  5. Experiential study on temperature and emission performance of micro burner during porous media combustion

    Science.gov (United States)

    Janvekar, Ayub Ahmed; Abdullah, M. Z.; Ahmad, Z. A.; Abas, A.; Ismail, A. K.; Hussien, A. A.; Kataraki, P. S.; Ishak, M. H. H.; Mazlan, M.; Zubair, A. F.

    2018-05-01

    Addition of porous materials in reaction zone give rise to significant improvements in combustion performance. In this work, a dual layered micro porous media burner was tested for stable flame and emissions. Reaction and preheat layer was made up of discrete (zirconia) and foam (porcelain) type of materials respectively. Three different thickness of reaction zone was tested, each with 10, 20 and 30mm. Interestingly, only 20mm thick layer can able to show better thermal efficiency of 72% as compared to 10 and 30mm. Best equivalence ratio came out to be 0.7 for surface and 0.6 for submerged flame conditions. Moreover, emission was continuously monitored to detect presence of NOx and CO, which were under controlled limits.

  6. Understanding the emission impacts of high-occupancy vehicle (HOV) to high-occupancy toll (HOT) lane conversions: Experience from Atlanta, Georgia.

    Science.gov (United States)

    Xu, Yanzhi Ann; Liu, Haobing; Rodgers, Michael O; Guin, Angshuman; Hunter, Michael; Sheikh, Adnan; Guensler, Randall

    2017-08-01

    Converting a congested high-occupancy vehicle (HOV) lane into a high-occupancy toll (HOT) lane is a viable option for improving travel time reliability for carpools and buses that use the managed lane. However, the emission impacts of HOV-to-HOT conversions are not well understood. The lack of emission impact quantification for HOT conversions creates a policy challenge for agencies making transportation funding choices. The goal of this paper is to evaluate the case study of before-and-after changes in vehicle emissions for the Atlanta, Georgia, I-85 HOV/HOT lane conversion project, implemented in October 2011. The analyses employed the Motor Vehicle Emission Simulator (MOVES) for project-level analysis with monitored changes in vehicle activity data collected by Georgia Tech researchers for the Georgia Department of Transportation (GDOT). During the quarterly field data collection from 2010 to 2012, more than 1.5 million license plates were observed and matched to vehicle class and age information using the vehicle registration database. The study also utilized the 20-sec, lane-specific traffic operations data from the Georgia NaviGAtor intelligent transportation system, as well as a direct feed of HOT lane usage data from the State Road and Tollway Authority (SRTA) managed lane system. As such, the analyses in this paper simultaneously assessed the impacts associated with changes in traffic volumes, on-road operating conditions, and fleet composition before and after the conversion. Both greenhouse gases and criteria pollutants were examined. A straight before-after analysis showed about 5% decrease in air pollutants and carbon dioxide (CO 2 ). However, when the before-after calendar year of analysis was held constant (to account for the effect of 1 yr of fleet turnover), mass emissions at the analysis site during peak hours increased by as much as 17%, with little change in CO 2 . Further investigation revealed that a large percentage decrease in criteria

  7. How does conversion from peat swamp forest to oil palm plantation affect emissions of nitrous oxide from the soil? A case study in Jambi, Indonesia

    Science.gov (United States)

    Hartill, Jodie; Hergoualc'h, Kristell; Comeau, Louis-Pierre; Jo, Smith; Lou, Verchot

    2017-04-01

    Half of the peatlands across Peninsular Malaysia, Borneo and Sumatra are 'managed'. Conversion of peat swamp forest to workable oil palm plantation requires a drastic, potentially irreversible, change to the landscape, to which fertilizers are then routinely applied. A combination of these factors is now widely thought to increase soil nitrous oxide (N2O) emissions, although there is high uncertainty due to gaps in the knowledge, both regionally and nationally. Despite the widespread use of fertilizers in plantations on peats, studies observing their effects remain very limited. Therefore, there is a need for in situ studies to evaluate how environmental parameters (edaphic properties, climate, soil moisture and N availability indicators) influence soil emissions. This 18 month study was located in plots local to each other, representing the start, intermediate and end of the land conversion process; namely mixed peat swamp forest, drained and logged forest and industrial oil palm plantation. Spatial variability was taken into account by differentiating the hollows and hummocks in the mixed peat swamp forest, and the fertilized zone and the zone without fertilizer addition in the oil palm plantation. Gas samples were collected each month from static chambers at the same time as key environmental parameters were measured. Intensive sampling was performed during a 35 day period following two fertilizer applications, in which urea was applied to palms at rates of 0.5 and 1 kg urea palm-1. Soil N2O emissions (kg N ha-1 y-1 ± SE) were low overall, but they were greater in the oil palm plantation (0.8 ± 0.1) than in the mixed peat swamp forest (0.3 ± 0.0) and the drained/logged forest (0.2 ± 0.0). In the mixed peat swamp forest, monthly average fluxes of N2O (g N ha-1 d-1 ± SE) were similar in the hollows (0.6 ± 0.2) and the hummocks (0.3 ± 0.1), whereas in the oil palm plantation they were consistently higher in the zone without fertilizer (2.5 ± 0.4) than in

  8. Radially converging tracer test in a low-angle fracture zone at the Finnsjoen site, central Sweden. The fracture zone project - phase 3

    International Nuclear Information System (INIS)

    Gustafsson, E.; Nordqvist, R.

    1993-10-01

    The performance and results of a radially converging tracer test in a low-angle major fracture zone in crystalline rock are described. The extensive, about 100 m thick, zone 2 was encountered by means of borehole investigations at depths ranging from 100 to 250 metres at the Finnsjon site, central eastern Sweden. The zone studied (zone 2) consists of highly conductive, metre thick interconnected minor shear and fracture zones (sub-zones) with low conductive rock in between. The objective of the tracer test was primarily to determine flow and transport characteristics in a major fracture zone. Secondly new equipment, experimental design and methods of interpretation were developed, tested and improved. The converging flow field was created by pumping in a central borehole from a packed-off interval enclosing the whole thickness of zone 2. Tracer breakthrough was registered from all nine injection points, with first arrivals ranging from 24 to 3200 hours. Evaluated flow and transport parameters included; flow porosity, dispersivity, flow wetted surface, fracture aperture and hydraulic conductivity in fracture flow paths. Directional variations were found in the flow and transport parameters determined, which is concluded to be due to heterogeneity and/or anisotropy. This conditions is more pronounced at depth in zone 2. The results from the tracer test also clearly show that the upper boundary of zone 2 is highly conductive and consistent over hundreds of metres. Within zone 2, and between upper and lower margins, interconnected discrete minor shear and fracture zones (sub-zones) constitute flow paths of considerable variable residence times. The dispersion within the sub-zones of zone 2, expressed as Peclet numbers ranged from 16 to 40. Flow porosity was determined to be 0.001-0.05 in the upper sub-zone and 0.01-0.1 in the intermediate and lower ones and flow wetted surface area per volume of rock was calculated to be within 1-92 m 2 /m 3 . 68 refs, 61 figs, 40 tabs

  9. Biogenic emissions of isoprenoids and NO in China and comparison to anthropogenic emissions

    International Nuclear Information System (INIS)

    Tie Xuexi; Li Guohui; Ying, Zhuming; Guenther, Alex; Madronich, Sasha

    2006-01-01

    In this study, a regional dynamical model (WRF) is used to drive biogenic emission models to calculate high resolution (10 x 10 km) biogenic emissions of isoprene (C 5 H 8 ), monoterpenes (C 1 H 16 ), and nitric oxide (NO) in China. This high resolution biogenic inventory will be available for the community to study the effect of biogenic emissions on photochemical oxidants in China. The biogenic emissions are compared to anthropogenic emissions to gain insight on the potential impact of the biogenic emissions on tropospheric chemistry, especially ozone production in this region. The results show that the biogenic emissions in China exhibit strongly diurnal, seasonal, and spatial variations. The isoprenoid (including both isoprene and monoterpenes) emissions are closely correlated to tree density and strongly vary with season and local time. During winter (January), the biogenic isoprenoid emissions are the lowest, resulting from lower temperature and solar radiation, and highest in summer (July) due to higher temperature and solar radiation. The biogenic NO emissions are also higher during summer and lower during winter, but the magnitude of the seasonal variation is smaller than the emissions of isoprene and monoterpenes. The biogenic emissions of NO are widely spread out in the northern, eastern, and southern China regions, where high-density agricultural soil lands are located. Both biogenic NO and isoprenoid emissions are very small in western China. The calculated total biogenic emission budget is smaller than the total anthropogenic VOC emission budget in China. The biogenic isoprenoid and anthropogenic VOC emissions are 10.9 and 15.1 Tg year -1 , respectively. The total biogenic and anthropogenic emissions of NO are 5.9 and 11.5 Tg(NO) year -1 , respectively. The study shows that in central eastern China, the estimated biogenic emissions of isoprenoids are very small, and the anthropogenic emissions of VOCs are dominant in this region. However, in

  10. Biogenic emissions of isoprenoids and NO in China and comparison to anthropogenic emissions.

    Science.gov (United States)

    Tie, Xuexi; Li, Guohui; Ying, Zhuming; Guenther, Alex; Madronich, Sasha

    2006-12-01

    In this study, a regional dynamical model (WRF) is used to drive biogenic emission models to calculate high resolution (10x10 km) biogenic emissions of isoprene (C(5)H(8)), monoterpenes (C(10)H(16)), and nitric oxide (NO) in China. This high resolution biogenic inventory will be available for the community to study the effect of biogenic emissions on photochemical oxidants in China. The biogenic emissions are compared to anthropogenic emissions to gain insight on the potential impact of the biogenic emissions on tropospheric chemistry, especially ozone production in this region. The results show that the biogenic emissions in China exhibit strongly diurnal, seasonal, and spatial variations. The isoprenoid (including both isoprene and monoterpenes) emissions are closely correlated to tree density and strongly vary with season and local time. During winter (January), the biogenic isoprenoid emissions are the lowest, resulting from lower temperature and solar radiation, and highest in summer (July) due to higher temperature and solar radiation. The biogenic NO emissions are also higher during summer and lower during winter, but the magnitude of the seasonal variation is smaller than the emissions of isoprene and monoterpenes. The biogenic emissions of NO are widely spread out in the northern, eastern, and southern China regions, where high-density agricultural soil lands are located. Both biogenic NO and isoprenoid emissions are very small in western China. The calculated total biogenic emission budget is smaller than the total anthropogenic VOC emission budget in China. The biogenic isoprenoid and anthropogenic VOC emissions are 10.9 and 15.1 Tg year(-1), respectively. The total biogenic and anthropogenic emissions of NO are 5.9 and 11.5 Tg(NO) year(-1), respectively. The study shows that in central eastern China, the estimated biogenic emissions of isoprenoids are very small, and the anthropogenic emissions of VOCs are dominant in this region. However, in

  11. Effect of dissolved oxygen manipulation on diffusive emissions from NAPL-impacted low permeability soil layers.

    Science.gov (United States)

    Clifton, Lisa M; Dahlen, Paul R; Johnson, Paul C

    2014-05-06

    Aquifer physical model experiments were performed to investigate if diffusive emissions from nonaqueous phase liquid (NAPL)-impacted low-permeability layers into groundwater moving through adjacent NAPL-free high-permeability layers can be reduced by creating an aerobic biotreatment zone at the interface between the two, and if over time that leads to reduced emissions after treatment ceases. Experiments were performed in two 1.2-m long × 1.2-m high × 5.4 cm wide stainless steel tanks; each with a high-permeability sand layer overlying a low-permeability crushed granite layer containing a NAPL mixture of indane and benzene. Each tank was water-saturated with horizontal flow primarily through the sand layer. The influent water was initially deoxygenated and the emissions and concentration distributions were allowed to reach near-steady conditions. The influent dissolved oxygen (DO) level was increased stepwise to 6.5-8.5 mg/L and 17-20 mg/L, and then decreased back to deoxygenated conditions. Each condition was maintained for at least 45 days. Relative to the near-steady benzene emission at the initial deoxygenated condition, the emission was reduced by about 70% when the DO was 6.5-8.5 mg/L, 90% when the DO was 17-20 mg/L, and ultimately 60% when returning to low DO conditions. While the reductions were substantial during treatment, longer-term reductions after 120 d of elevated DO treatment, relative to an untreated condition predicted by theory, were low: 29% and 6% in Tank 1 and Tank 2, respectively. Results show a 1-2 month lag between the end of DO delivery and rebound to the final near-steady emissions level. This observation has implications for post-treatment performance monitoring sampling at field sites.

  12. Occasional large emissions of nitrous oxide and methane observed in stormwater biofiltration systems

    Energy Technology Data Exchange (ETDEWEB)

    Grover, Samantha P.P., E-mail: samantha.grover@monash.edu [Department of Civil Engineering, Monash University, Clayton, Victoria, 3800 (Australia); Cohan, Amanda, E-mail: acoh5@student.monash.edu [Department of Civil Engineering, Monash University, Clayton, Victoria, 3800 (Australia); Chan, Hon Sen, E-mail: hon.sen.chan@gmail.com [Department of Civil Engineering, Monash University, Clayton, Victoria, 3800 (Australia); Livesley, Stephen J., E-mail: sjlive@unimelb.edu.au [Department of Resource Management and Geography, The University of Melbourne, Richmond, Victoria, 3121 (Australia); Beringer, Jason, E-mail: jason.beringer@monash.edu [School of Geography and Environmental Science, Monash University, Clayton, Victoria, 3800 (Australia); Monash Water for Liveability, Monash University, Clayton, Victoria, 3800 (Australia); Daly, Edoardo, E-mail: edoardo.daly@monash.edu [Department of Civil Engineering, Monash University, Clayton, Victoria, 3800 (Australia); Monash Water for Liveability, Monash University, Clayton, Victoria, 3800 (Australia)

    2013-11-01

    Designed, green infrastructures are becoming a customary feature of the urban landscape. Sustainable technologies for stormwater management, and biofilters in particular, are increasingly used to reduce stormwater runoff volumes and peaks as well as improve the water quality of runoff discharged into urban water bodies. Although a lot of research has been devoted to these technologies, their effect in terms of greenhouse gas fluxes in urban areas has not been yet investigated. We present the first study aimed at quantifying greenhouse gas fluxes between the soil of stormwater biofilters and the atmosphere. N{sub 2}O, CH{sub 4}, and CO{sub 2} were measured periodically over a year in two operational vegetated biofiltration cells at Monash University in Melbourne, Australia. One cell had a saturated zone at the bottom, and compost and hardwood mulch added to the sandy loam filter media. The other cell had no saturated zone and was composed of sandy loam. Similar sedges were planted in both cells. The biofilter soil was a small N{sub 2}O source and a sink for CH{sub 4} for most measurement events, with occasional large emissions of both N{sub 2}O and CH{sub 4} under very wet conditions. Average N{sub 2}O fluxes from the cell with the saturated zone were almost five-fold greater (65.6 μg N{sub 2}O–N m{sup −2} h{sup −1}) than from the other cell (13.7 μg N{sub 2}O–N m{sup −2} h{sup −1}), with peaks up to 1100 μg N{sub 2}O–N m{sup −2} h{sup −1}. These N{sub 2}O fluxes are of similar magnitude to those measured in other urban soils, but with larger peak emissions. The CH{sub 4} sink strength of the cell with the saturated zone (− 3.8 μg CH{sub 4}–C m{sup −2} h{sup −1}) was lower than the other cell (− 18.3 μg CH{sub 4}–C m{sup −2} h{sup −1}). Both cells of the biofilter appeared to take up CH{sub 4} at similar rates to other urban lawn systems; however, the biofilter cells displayed occasional large CH{sub 4} emissions following

  13. Atmospheric pollution reduction effect and regional predicament: An empirical analysis based on the Chinese provincial NOx emissions.

    Science.gov (United States)

    Ding, Lei; Liu, Chao; Chen, Kunlun; Huang, Yalin; Diao, Beidi

    2017-07-01

    Atmospheric pollution emissions have become a matter of public concern in recent years. However, most of the existing researches on NOx pollution are from the natural science and technology perspective, few studies have been conducted from an economic point, and regional differences have not been given adequate attention. This paper adopts provincial panel data from 2006 to 2013 and the LMDI model to analyze the key driving factors and regional dilemmas of NOx emissions. The results show that significant regional disparities still exit on NO x emissions and its reduction effect 27 provinces didn't accomplish their corresponding reduction targets. Economic development factor is the dominating driving factor of NO x emissions during the study period, while energy efficiency and technology improvement factors offset total NO x emissions in the majority of provinces. In addition, the industrial structure factor plays a more significant role in reducing the NO x emissions after 2011. Therefore, the government should consider all these factors as well as regional heterogeneity in developing appropriate pollution mitigating policies. It's necessary to change NOx emissions control attitude from original key areas control to divided-zone control, not only attaches great importance to the reduction of the original key areas, but also emphasizes the new potential hotspots with high NO x emissions. Copyright © 2017 Elsevier Ltd. All rights reserved.

  14. The use of high vacuum soil vapor extraction to improve contaminant recovery from ground water zones of low transmissivity

    International Nuclear Information System (INIS)

    Brown, A.; Farrow, J.R.C.; Burgess, W.

    1996-01-01

    This study examines the potential for enhancing hydrocarbon contaminant mass recovery from ground water using high vacuum soil vapor extraction (SVE). The effectiveness of this form of remediation is compared with the effectiveness of conventional pump-and-treat. This study focuses on the performance of a high vacuum SVE system at two ground water monitoring wells (MW-17 and MW-65b) at a site in Santa Barbara, California, US. The site is a highly characterized site with vadose zone and ground water petroleum hydrocarbon contamination (gasoline). The ground water wells are located beyond a defined area of vadose zone soil contamination. Ground water hydrocarbon contamination [light non-aqueous phase liquid (LNAPL) and dissolved phase] is present at each of the wells. the ground water wells have been part of a low-flow, pump-and-treat, ground water treatment system (GWTS) since August, 1986. The low transmissivity of the aquifer sediments prevent flow rates above approximately 0.02 gpm (0.01 l/min) per well

  15. Steep Hard-X-ray Spectra Indicate Extremely High Accretion Rates in Weak Emission-Line Quasars

    Science.gov (United States)

    Marlar, Andrea; Shemmer, Ohad; Anderson, Scott F.; Brandt, W. Niel; Diamond-Stanic, Aleksandar M.; Fan, Xiaohui; Luo, Bin; Plotkin, Richard; Richards, Gordon T.; Schneider, Donald P.; Wu, Jianfeng

    2018-06-01

    We present XMM-Newton imaging spectroscopy of ten weak emission-line quasars (WLQs) at 0.928 ≤ z ≤ 3.767, six of which are radio quiet and four which are radio intermediate. The new X-ray data enabled us to measure the hard-X-ray power-law photon index (Γ) in each source with relatively high accuracy. These measurements allowed us to confirm previous reports that WLQs have steeper X-ray spectra, therefore indicating higher accretion rates with respect to "typical" quasars. A comparison between the Γ values of our radio-quiet WLQs and those of a carefully-selected, uniform sample of 84 quasars shows that the first are significantly higher, at the ≥ 3σ level. Collectively, the four radio-intermediate WLQs have lower Γ values with respect to the six radio-quiet WLQs, as may be expected if the spectra of the first group are contaminated by X-ray emission from a jet. These results suggest that, in the absence of significant jet emission along our line of sight, WLQs constitute the extreme high end of the accretion rate distribution in quasars. We detect soft excess emission in our lowest-redshift radio-quiet WLQ, in agreement with previous findings suggesting that the prominence of this feature is associated with a high accretion rate. We have not detected signatures of Compton reflection, Fe Kα lines, or strong variability between two X-ray epochs in any of our WLQs.

  16. Anthropogenic and volcanic emission impacts on SO2 dynamics and acid rain profiles. Numerical study using WRF-Chem in a high-resolution modeling

    Science.gov (United States)

    Vela, A. V.; González, C. M.; Ynoue, R.; Rojas, N. Y.; Aristizábal, B. H.; Wahl, M.

    2017-12-01

    Eulerian 3-D chemistry transport models (CTM) have been widely used for the study of air quality in urban environments, becoming an essential tool for studying the impacts and dynamics of gases and aerosols on air quality. However, their use in Colombia is scarce, especially in medium-sized cities, which are experimenting a fast urban growth, increasing the risk associated with possible air pollution episodes. In the densely populated medium-sized Andean city of Manizales, Colombia - a city located on the western slopes of the central range of the Andes (urban population 368000; 2150 m.a.s.l), there is an influence of the active Nevado del Ruiz volcano, located 28 km to the southwest. This natural source emits daily gas and particle fluxes, which could influence the atmospheric chemistry of the city and neighboring towns. Hence, the zone presents a unique combination of anthropogenic and volcanic sulfur gas emissions, which affects SO2 dynamics in the urban area, influencing also in the formation of acid rain phenomenon in the city. Therefore, studies analyzing the relative contribution of anthropogenic and volcanic emission could contribute with a deep understanding about causes and dynamics of both acid rain phenomenon and ambient SO2 levels in Manizales. This work aimed to analyze the influence of anthropogenic (on-road vehicular and industrial point-sources) and volcanic sulfur emissions in SO2 atmospheric chemistry dynamics, evaluating its possible effects on acid rain profiles. Ambient SO2 levels and day-night rain samples were measured and used to analyze results obtained from the application of the fully-coupled on-line WRF-Chem model. Two high-resolution simulations were performed during two dry and wet one-week periods in 2015. Analysis of SO2 dispersion patterns and comparison with SO2 observations in the urban area were performed for three different scenarios in which natural and anthropogenic emissions were simulated separately. Results suggest that

  17. The Zoning of Forest Fire Potential of Gulestan Province Forests Using Granular Computing and MODIS Images

    Directory of Open Access Journals (Sweden)

    A. Jalilzadeh Shadlouei

    2013-09-01

    Full Text Available There are many vegetation in Iran. This is because of extent of Iran and its width. One of these vegetation is forest vegetation most prevalent in Northern provinces named Guilan, Mazandaran, Gulestan, Ardebil as well as East Azerbaijan. These forests are always threatened by natural forest fires so much so that there have been reports of tens of fires in recent years. Forest fires are one of the major environmental as well as economic, social and security concerns in the world causing much damages. According to climatology, forest fires are one of the important factors in the formation and dispersion of vegetation. Also, regarding the environment, forest fires cause the emission of considerable amounts of greenhouse gases, smoke and dust into the atmosphere which in turn causes the earth temperature to rise up and are unhealthy to humans, animals and vegetation. In agriculture droughts are the usual side effects of these fires. The causes of forest fires could be categorized as either Human or Natural Causes. Naturally, it is impossible to completely contain forest fires; however, areas with high potentials of fire could be designated and analysed to decrease the risk of fires. The zoning of forest fire potential is a multi-criteria problem always accompanied by inherent uncertainty like other multi-criteria problems. So far, various methods and algorithm for zoning hazardous areas via Remote Sensing (RS and Geospatial Information System (GIS have been offered. This paper aims at zoning forest fire potential of Gulestan Province of Iran forests utilizing Remote Sensing, Geospatial Information System, meteorological data, MODIS images and granular computing method. Granular computing is part of granular mathematical and one way of solving multi-criteria problems such forest fire potential zoning supervised by one expert or some experts , and it offers rules for classification with the least inconsistencies. On the basis of the experts’ opinion

  18. Effect of secondary electron emission on subnanosecond breakdown in high-voltage pulse discharge

    Science.gov (United States)

    Schweigert, I. V.; Alexandrov, A. L.; Gugin, P.; Lavrukhin, M.; Bokhan, P. A.; Zakrevsky, Dm E.

    2017-11-01

    The subnanosecond breakdown in open discharge may be applied for producing superfast high power switches. Such fast breakdown in high-voltage pulse discharge in helium was explored both in experiment and in kinetic simulations. The kinetic model of electron avalanche development was developed using PIC-MCC technique. The model simulates motion of electrons, ions and fast helium atoms, appearing due to ions scattering. It was shown that the mechanism responsible for ultra-fast breakdown development is the electron emission from cathode. The photoemission and emission by ions or fast atoms impact is the main reason of current growth at the early stage of breakdown, but at the final stage, when the voltage on discharge gap drops, the secondary electron emission (SEE) is responsible for subnanosecond time scale of current growth. It was also found that the characteristic time of the current growth τS depends on the SEE yield of the cathode material. Three types of cathode material (titanium, SiC, and CuAlMg-alloy) were tested. It is shown that in discharge with SiC and CuAlMg-alloy cathodes (which have enhanced SEE) the current can increase with a subnanosecond characteristic time as small as τS = 0.4 ns, for the pulse voltage amplitude of 5- 12 kV..

  19. Low Emissions Burner Technology for Metal Processing Industry using Byproducts and Biomass Derived Liquid Fuels

    Energy Technology Data Exchange (ETDEWEB)

    Agrawal, Ajay; Taylor, Robert

    2013-09-30

    path forward to utilize both fossil and alternative liquid fuels in the same combustion system. In particular, experiments show that straight VO can be cleanly combusted without the need for chemical processing or preheating steps, which can result in significant economic and environmental benefits. Next, low-emission combustion of glycerol/methane was achieved by utilizing FB injector to yield fine droplets of highly viscous glycerol. Heat released from methane combustion further improves glycerol pre-vaporization and thus its clean combustion. Methane addition results in an intensified reaction zone with locally high temperatures near the injector exit. Reduction in methane flow rate elongates the reaction zone, which leads to higher CO emissions and lower NOx emissions. Similarly, higher air to liquid (ALR) mass ratio improves atomization and fuel pre-vaporization and shifts the flame closer to the injector exit. In spite of these internal variations, all fuel mixes of glycerol with methane produced similar CO and NOx emissions at the combustor exit. Results show that FB concept provides low emissions with the flexibility to utilize gaseous and highly viscous liquid fuels, straight VO and glycerol, without preheating or preprocessing the fuels. Following these initial experiments in quartz combustor, we demonstrated that glycerol combustion can be stably sustained in a metal combustor. Phase Doppler Particle Analyzer (PDPA) measurements in glycerol/methane flames resulted in flow-weighted Sauter Mean Diameter (SMD) of 35 to 40 μm, depending upon the methane percentage. This study verified that lab-scale dual-fuel burner using FB injector can successfully atomize and combust glycerol and presumably other highly viscous liquid fuels at relatively low HRR (<10 kW). For industrial applications, a scaled-up glycerol burner design thus seemed feasible.

  20. Biogenic volatile organic compound emissions from the Eurasian taiga: current knowledge and future directions

    Energy Technology Data Exchange (ETDEWEB)

    Rinne, J. (Dept. of Physics, Univ. of Helsinki (Finland)); Baeck, J. (Dept. of Forest Ecology, Univ. of Helsinki (Finland)); Hakola, H. (Finnish Meteorological Institute, Air Quality Research, Helsinki (Finland))

    2009-07-01

    n this paper, the research conducted on the emissions of the biogenic volatile organic compounds (BVOCs) from the European boreal zone, or taiga, is reviewed. We highlight the main findings and the key gaps in our knowledge. Ecosystem scale BVOC emissions from the Eurasian taiga are observed to be relatively low as compared with those from some forest ecosystems in warmer climates. One of the distinctive features of the Eurasian taiga is the predominance of monoterpene emitting coniferous trees. Recent research indicates that in addition to evaporation from storage structures, part of the monoterpene emission of conifers originates directly from synthesis. Monoterpene emission from boreal deciduous trees originates mainly directly from synthesis. The boreal trees exhibit distinct intra-species variation in the monoterpene mixtures they emit. Important sources of isoprene in the Eurasian taiga include Norway spruce, open wetland ecosystems and some non-dominant woody species, such as European aspen and willows. Many boreal tree species also emit non-terpenoid compounds and highly reactive sesquiterpenes. The future challenges in the research on BVOC emissions from the Eurasian taiga include (i) quantification and understanding the non-terpenoid VOC emissions from the taiga ecosystems, (ii) bringing ecosystems in the eastern Eurasian taiga into the sphere of BVOC emission studies, (iii) establishing long-term ecosystem flux studies combined with plant physiological measurements, and (iv) integrating knowledge and research skills on BVOC synthesis, storages and emissions, land cover changes and atmospheric processes in different spatial and temporal scales in order to better understand the impact of biosphere on atmospheric chemistry and composition in changing climate. (orig.)

  1. Effects of Temperature and Residence Time on the Emissions of PIC and Fine Particles during Fixed Bed Combustion of Conifer Stemwood Pellets

    Energy Technology Data Exchange (ETDEWEB)

    Boman, Christoffer; Lindmark, Fredrik; Oehman, Marcus; Nordin, Anders [Umeaa Univ. (Sweden). Energy Technology and Thermal Process Chemistry; Pettersson, Esbjoern [Energy Technology Centre, Piteaa (Sweden); Westerholm, Roger [Stockholm Univ., Arrhenius Laboratory (Sweden). Dept. of Analytical Chemistry

    2006-07-15

    The use of wood fuel Pellets has proved to be well suited for the small-scale market enabling controlled and efficient combustion with low emission of products of incomplete combustion (PIC). Still a potential for further emission reduction exists and a thorough understanding of the influence of combustion conditions on the emission characteristics of air pollutants like PAH and particulate matter (PM) is important. The objective was to determine the effects of temperature and residence time on the emission performance and characteristics with focus on hydrocarbons and PM during combustion of conifer stemwood Pellets in a laboratory fixed bed reactor (<5 kW). Temperature and residence time after the bed section were varied according to statistical experimental designs (650-970 deg C and 0.5-3.5 s) with the emission responses; CO, organic gaseous carbon, NO, 20 VOC compounds, 43 PAH compounds, PM{sub tot}, fine particle mass/count median diameter (MMD and CMD) and number concentration. Temperature was negatively correlated with the emissions of all studied PIC with limited effects of residence time. The PM{sub tot} emissions of 15-20 mg/MJ was in all cases dominated by fine (<1 {mu}m) particles of K, Na, S, Cl, C, O and Zn. Increased residence time resulted in increased fine particle sizes (i.e. MMD and CMD) and decreased number concentrations. The importance of high temperature (>850 deg C) in the bed zone with intensive, air rich and well mixed isothermal conditions for 0.5-1.0 s in the post combustion zone was illustrated for wood Pellets combustion with almost a total depletion of all studied PIC. The results emphasize the need for further verification studies and technology development work.

  2. High Frequency Electromagnetic Impedance Imaging for Vadose Zone and Groundwater Characterization

    International Nuclear Information System (INIS)

    Newman, Greory A.; Alumbaugh, David L.; Hoversten, Michael; Nichols, Edward

    2003-01-01

    A geophysical experiment is described for characterizing the clastic dike systems, which are ubiquitous within the vadose zone at the Hanford Nuclear Reservation. because the dikes possess a significant electrical contrast from the insulating host medium, we have applied controlled source audio magnetotelluric (CSAMT) measurements to map their geometric extent and to further clarify if the dike complex acts as a conduit for contaminant transport within the vadose zone. Because of cost and weak natural field signal levels, we employed controlled field sourcing using the STRATGEM acquisition system. Use of artificial fields often goes with the assumption that the data required in the far-field of the transmitter

  3. Development and application of methods and models for the calculation of spatially and temporally highly resolved emissions in Europe

    International Nuclear Information System (INIS)

    Thiruchittampalam, Balendra

    2014-01-01

    High spatial and temporal resolution models are essential for answering many questions of air quality management and climate modeling. High-resolution emission models are required to determine the concentration of pollutants using chemical transport models, and to quantify the impacts on health and environment and in particular to develop adequate countermeasures. The aim of this work is to develop methods for the calculation of spatially and temporally high-resolved emissions and to apply these exemplarily on a 1 km x 1 km and hourly resolution for the year 2008 in the EU-27 and EFTA countries. The derivation of methods for the spatial and temporal resolution of emissions with corresponding detailed equations is one of the major improvements that have been carried out in the course of this work. The improvement of the spatial distribution of emissions from the point source relevant sectors like energy supply, industry and waste management is achieved by considering sector specific diffuse emission shares. The progress of the spatial distribution of emissions from households is in particular the development of a fuel type weighted distribution over Europe. Another main focus is the development of the spatial distribution of road transport emissions. Due to the restricted access to traffic count data at the European level, methods have been established to provide reliable emissions on grid level for Europe. The progress in the spatial distribution of agricultural emissions is achieved by the consideration of diffuse shares similar to the other point source relevant sectors like energy supply or industry. In addition to the spatial distribution of the emissions the temporal resolution is a main focus of this work, since the state of knowledge of the temporal resolution of emissions in Europe is still rudimentary. Therefore, it was necessary to develop in particular time curves for the hourly resolution of emissions for the main sectors, namely electricity and heat

  4. Improving Dryer and Press Efficiencies Through Combustion of Hydrocarbon Emissions

    Energy Technology Data Exchange (ETDEWEB)

    Sujit Banerjee

    2005-10-31

    Emission control devices on dryers and presses have been legislated into the industry, and are now an integral part of the drying system. These devices consume large quantities of natural gas and electricity and down-sizing or eliminating them will provide major energy savings. The principal strategy taken here focuses on developing process changes that should minimize (and in some cases eliminate) the need for controls. A second approach is to develop lower-cost control options. It has been shown in laboratory and full-scale work that Hazardous Air Pollutants (HAPs) emerge mainly at the end of the press cycle for particleboard, and, by extension, to other prod-ucts. Hence, only the air associated with this point of the cycle need be captured and treated. A model for estimating terpene emissions in the various zones of veneer dryers has been developed. This should allow the emissions to be concentrated in some zones and minimized in others, so that some of the air could be directly released without controls. Low-cost catalysts have been developed for controlling HAPs from dryers and presses. Catalysts conventionally used for regenerative catalytic oxidizers can be used at much lower temperatures for treating press emissions. Fluidized wood ash is an especially inexpensive mate-rial for efficiently reducing formaldehyde in dryer emissions. A heat transfer model for estimating pinene emissions from hot-pressing strand for the manufacture of flakeboard has been constructed from first principles and validated. The model shows that most of the emissions originate from the 1-mm layer of wood adjoining the platen surface. Hence, a simple control option is to surface a softwood mat with a layer of hardwood prior to pressing. Fines release a disproportionate large quantity of HAPs, and it has been shown both theo-retically and in full-scale work that particles smaller than 400 µm are principally responsible. Georgia-Pacific is considering green

  5. Design Optimization of a Small-Scale Polygeneration Energy System in Different Climate Zones in Iran

    Directory of Open Access Journals (Sweden)

    Sara Ghaem Sigarchian

    2018-05-01

    Full Text Available Design and performance of polygeneration energy systems are highly influenced by several variables, including the climate zone, which can affect the load profile as well as the availability of renewable energy sources. To investigate the effects, in this study, the design of a polygeneration system for identical residential buildings that are located in three different climate zones in Iran has been investigated. To perform the study, a model has previously developed by the author is used. The performance of the polygeneration system in terms of energy, economy and environment were compared to each other. The results show significant energetic and environmental benefits of the implementation of polygeneration systems in Iran, especially in the building that is located in a hot climate, with a high cooling demand and a low heating demand. Optimal polygeneration system for an identical building has achieved a 27% carbon dioxide emission reduction in the cold climate, while this value is around 41% in the hot climate. However, when considering the price of electricity and gas in the current energy market in Iran, none of the systems are feasible and financial support mechanisms or other incentives are required to promote the application of decentralized polygeneration energy systems.

  6. Radiation danger of exclusion zone objects

    International Nuclear Information System (INIS)

    Kholosha, V.I.; Proskura, N.I.; Ivanov, Yu.A.; Kazakov, S.V.; Arkhipov, A.N.

    2001-01-01

    The analysis of radiation danger of the Exclusion Zone objects was made. Here, the Zone is defined as the territory from which the population has been evacuated in 1986 owing to the Chernobyl accident and possible outflow of the contaminated substances out of the borders is potentially dangerous to the Ukraine. In the present work were analyzed such problems as sources of radiation danger in the Zone, ways of radionuclide migration out of the borders of the Zone in normal and emergency situations, the non-radiation (ecological) danger factors of the Zone objects, doses (individual and collective) from various sources and on separate ways of their formation, and the characteristics of radiation danger of the Zone objects. The conclusions are: (1) Radionuclide flows both from technologic and natural sources exceed those from Shelter objects, (2) Under emergency conditions, radionuclide flows and doze loading remain comparable with those from emergency sources, (3) To solve some management tasks in radiation situation, the basic works on the Shelter objects should be oriented to decrease probability of emergency occurrence and to reduce radiation influence (prevention wash-outs during high waters, fire-prevention measures in forests and strengthening of the control behind non-authorized use of objects in the Zone). (S. Ohno)

  7. Particulate matter emission modelling based on soot and SOF from direct injection diesel engines

    International Nuclear Information System (INIS)

    Tan, P.Q.; Hu, Z.Y.; Deng, K.Y.; Lu, J.X.; Lou, D.M.; Wan, G.

    2007-01-01

    Particulate matter (PM) emission is one of the major pollutants from diesel engines, and it is harmful for human health and influences the atmospheric visibility. In investigations for reducing PM emission, a simulation model for PM emission is a useful tool. In this paper, a phenomenological, composition based PM model of direct injection (DI) diesel engines has been proposed and formulated to simulate PM emission. The PM emission model is based on a quasi-dimensional multi-zone combustion model using the formation mechanisms of the two main compositions of PM: soot and soluble organic fraction (SOF). First, the quasi-dimensional multi-zone combustion model is given. Then, two models for soot and SOF emissions are established, respectively, and after that, the two models are integrated into a single PM emission model. The soot emission model is given by the difference between a primary formation model and an oxidation model of soot. The soot primary formation model is the Hiroyasu soot formation model, and the Nagle and Strickland-Constable model is adopted for soot oxidation. The SOF emission model is based on an unburned hydrocarbons (HC) emission model, and the HC emission model is given by the difference between a HC primary formation model and a HC oxidation model. The HC primary formation model considers fuel injected and mixed beyond the lean combustion limit during ignition delay and fuel effusing from the nozzle sac volume at low pressure and low velocity. In order to validate the PM emission model, experiments were performed on a six cylinder, turbocharged and intercooled DI diesel engine. The simulation results show good agreement with the experimental data, which indicates the validity of the PM emission model. The calculation results show that the distinctions between PM and soot formation rates are mainly in the early combustion stage. The SOF formation has an important influence on the PM formation at lower loads, and soot formation dominates the

  8. Radiation protection zoning

    International Nuclear Information System (INIS)

    2015-01-01

    Radiation being not visible, the zoning of an area containing radioactive sources is important in terms of safety. Concerning radiation protection, 2 work zones are defined by regulations: the monitored zone and the controlled zone. The ministerial order of 15 may 2006 settles the frontier between the 2 zones in terms of radiation dose rates, the rules for access and the safety standards in both zones. Radioprotection rules and the name of the person responsible for radiation protection must be displayed. The frontier between the 2 zones must be materialized and marked with adequate equipment (specific danger signs and tapes). Both zones are submitted to selective entrance, the access for the controlled zone is limited because of the radiation risk and of the necessity of confining radioactive contamination while the limitation of the access to the monitored zone is due to radiation risk only. (A.C.)

  9. Fighting over forest: interactive governance of conflicts over forest and tree resources in Ghana’s high forest zone

    NARCIS (Netherlands)

    Derkyi, M.A.A.

    2012-01-01

    Based on eight case studies, this book analyses conflicts over forests and trees in Ghana’s high forest zone and ways of dealing with them. It thereby addresses the full range of forest and tree-based livelihoods. Combining interactive governance theory with political ecology and conflict theories,

  10. High-energy gamma-ray emission from solar flares: Constraining the accelerated proton spectrum

    Science.gov (United States)

    Alexander, David; Dunphy, Philip P.; Mackinnon, Alexander L.

    1994-01-01

    Using a multi-component model to describe the gamma-ray emission, we investigate the flares of December 16, 1988 and March 6, 1989 which exhibited unambiguous evidence of neutral pion decay. The observations are then combined with theoretical calculations of pion production to constrain the accelerated proton spectra. The detection of pi(sup 0) emission alone can indicate much about the energy distribution and spectral variation of the protons accelerated to pion producing energies. Here both the intensity and detailed spectral shape of the Doppler-broadened pi(sup 0) decay feature are used to determine the spectral form of the accelerated proton energy distribution. The Doppler width of this gamma-ray emission provides a unique diagnostic of the spectral shape at high energies, independent of any normalisation. To our knowledge, this is the first time that this diagnostic has been used to constrain the proton spectra. The form of the energetic proton distribution is found to be severely limited by the observed intensity and Doppler width of the pi(sup 0) decay emission, demonstrating effectively the diagnostic capabilities of the pi(sup 0) decay gamma-rays. The spectral index derived from the gamma-ray intensity is found to be much harder than that derived from the Doppler width. To reconcile this apparent discrepancy we investigate the effects of introducing a high-energy cut-off in the accelerated proton distribution. With cut-off energies of around 0.5-0.8 GeV and relatively hard spectra, the observed intensities and broadening can be reproduced with a single energetic proton distribution above the pion production threshold.

  11. Comparable Monoterpene emission from pine forests across 500 mm precipitation gradient in the semi-arid transition zone

    Science.gov (United States)

    Seco, Roger; Karl, Thomas; Turnipseed, Andrew; Greenberg, Jim; Guenther, Alex; Llusia, Joan; Penuelas, Josep; Dicken, Uri; Rotenberg, Eyal; Rohatyn, Shani; Preisler, Yakir; Yakir, Dan

    2014-05-01

    Atmospheric volatile organic compounds (VOCs) have key environmental and biological roles, and can affect atmospheric chemistry, secondary aerosol formation, and as a consequence also climate. At the same time, global changes in climate arising from human activities can modify the VOC emissions of vegetation in the coming years. Monoterpene emission fluxes were measured during April 2013 at two forests in the semi-arid climate of Israel. Both forests were dominated by Pinus halepensis trees of similar age, but differed in the amount of annual average precipitation received (~276 and ~760 mm at the Yatir and Birya sites, respectively). Measurements performed included leaf-level sampling and gas exchange, as well as canopy-level flux calculations. Leaf level monoterpene emissions were sampled from leaf cuvettes with adsorbent cartridges and later analyzed by GC-MS. Canopy scale fluxes were calculated with the Disjunct Eddy Covariance technique by means of a Quadrupole PTRMS and eddy-covariance system. We report the differences observed between the two forests in terms of photosynthetic activity and monoterpene emissions, aiming to see the effect of the different climatic regimes at each location. Significantly higher emission rates of monoterpenes were observed in the wetter site during mid-day, in both the leaf scale and canopy scale measurements. Remarkably, however, normalized to 30C and corrected for tree density differences between the sites indicated comparable emission rates for both sites, with higher emission rated in the evening hours in the dry site at the edge of the Negev Desert. Modeling the monoterpene emission rates using MEGAN v2.1 indicated better agreement with observations in the wetter site then in the dry site, especially with respect to fluxes during the evening hours.

  12. Highly controlled, reproducible measurements of aerosol emissions from combustion of a common African biofuel source

    Science.gov (United States)

    Haslett, Sophie L.; Thomas, J. Chris; Morgan, William T.; Hadden, Rory; Liu, Dantong; Allan, James D.; Williams, Paul I.; Keita, Sekou; Liousse, Cathy; Coe, Hugh

    2018-01-01

    Particulate emissions from biomass burning can both alter the atmosphere's radiative balance and cause significant harm to human health. However, due to the large effect on emissions caused by even small alterations to the way in which a fuel burns, it is difficult to study particulate production of biomass combustion mechanistically and in a repeatable manner. In order to address this gap, in this study, small wood samples sourced from Côte D'Ivoire in West Africa were burned in a highly controlled laboratory environment. The shape and mass of samples, available airflow and surrounding thermal environment were carefully regulated. Organic aerosol and refractory black carbon emissions were measured in real time using an Aerosol Mass Spectrometer and a Single Particle Soot Photometer, respectively. This methodology produced remarkably repeatable results, allowing aerosol emissions to be mapped directly onto different phases of combustion. Emissions from pyrolysis were visible as a distinct phase before flaming was established. After flaming combustion was initiated, a black-carbon-dominant flame was observed during which very little organic aerosol was produced, followed by a period that was dominated by organic-carbon-producing smouldering combustion, despite the presence of residual flaming. During pyrolysis and smouldering, the two phases producing organic aerosol, distinct mass spectral signatures that correspond to previously reported variations in biofuel emissions measured in the atmosphere are found. Organic aerosol emission factors averaged over an entire combustion event were found to be representative of the time spent in the pyrolysis and smouldering phases, rather than reflecting a coupling between emissions and the mass loss of the sample. Further exploration of aerosol yields from similarly carefully controlled fires and a careful comparison with data from macroscopic fires and real-world emissions will help to deliver greater constraints on the

  13. Formation of Neutral Disk-Like Zone Around the Active Hot Stars in Symbiotic Binaries

    Directory of Open Access Journals (Sweden)

    Cariková Z.

    2012-06-01

    Full Text Available In this contribution we present the ionization structure in the enhanced wind from the hot star in symbiotic binaries during active phases. Rotation of the hot star leads to the compression of the outflowing material towards its equatorial plane. As a result, a neutral disk-like zone around the active hot star near the orbital plane is created. We modeled the compression of the wind and calculated the neutral disk-like zone in the enhanced wind from the hot star using the equation of the photoionization equilibrium. the presence of such neutral disk-like zones was also suggested on the basis of the modeling the spectral energy distribution of symbiotic binaries. We confront the calculated ionization structures in the enhanced wind from the hot star with the observations. the calculated column density of the neutral hydrogen atoms in the neutral disk-like zone and the emission measure of the ionized part of the wind from the hot star are in a good agreement with the quantities derived from observations during active phases. the presence of such neutral disk-like zones is transient, being connected with the active phases of symbiotic binaries. During quiescent phases, such neutral disk-like zones cannot be created because of insufficient mass-loss rate from the hot star.

  14. DETECTION OF HIGH-ENERGY GAMMA-RAY EMISSION DURING THE X-RAY FLARING ACTIVITY IN GRB 100728A

    International Nuclear Information System (INIS)

    Abdo, A. A.; Ackermann, M.; Ajello, M.; Bechtol, K.; Berenji, B.; Blandford, R. D.; Borgland, A. W.; Baldini, L.; Bellazzini, R.; Bregeon, J.; Ballet, J.; Barbiellini, G.; Baring, M. G.; Bastieri, D.; Bhat, P. N.; Bissaldi, E.; Bonamente, E.; Bonnell, J.; Bouvier, A.; Brigida, M.

    2011-01-01

    We present the simultaneous Swift and Fermi observations of the bright GRB 100728A and its afterglow. The early X-ray emission is dominated by a vigorous flaring activity continuing until 1 ks after the burst. In the same time interval, high-energy emission is significantly detected by the Fermi/Large Area Telescope. Marginal evidence of GeV emission is observed up to later times. We discuss the broadband properties of this burst within both the internal and external shock scenarios, with a particular emphasis on the relation between X-ray flares, the GeV emission, and a continued long-duration central engine activity as their power source.

  15. U.S. regional greenhouse gas emissions analysis comparing highly resolved vehicle miles traveled and CO2 emissions: mitigation implications and their effect on atmospheric measurements

    Science.gov (United States)

    Mendoza, D. L.; Gurney, K. R.

    2010-12-01

    Carbon dioxide (CO2) is the most abundant anthropogenic greenhouse gas and projections of fossil fuel energy demand show CO2 concentrations increasing indefinitely into the future. After electricity production, the transportation sector is the second largest CO2 emitting economic sector in the United States, accounting for 32.3% of the total U.S. emissions in 2002. Over 80% of the transport sector is composed of onroad emissions, with the remainder shared by the nonroad, aircraft, railroad, and commercial marine vessel transportation. In order to construct effective mitigation policy for the onroad transportation sector and more accurately predict CO2 emissions for use in transport models and atmospheric measurements, analysis must incorporate the three components that determine the CO2 onroad transport emissions: vehicle fleet composition, average speed of travel, and emissions regulation strategies. Studies to date, however, have either focused on one of these three components, have been only completed at the national scale, or have not explicitly represented CO2 emissions instead relying on the use of vehicle miles traveled (VMT) as an emissions proxy. National-level projections of VMT growth is not sufficient to highlight regional differences in CO2 emissions growth due to the heterogeneity of vehicle fleet and each state’s road network which determines the speed of travel of vehicles. We examine how an analysis based on direct CO2 emissions and an analysis based on VMT differ in terms of their emissions and mitigation implications highlighting potential biases introduced by the VMT-based approach. This analysis is performed at the US state level and results are disaggregated by road and vehicle classification. We utilize the results of the Vulcan fossil fuel CO2 emissions inventory which quantified emissions for the year 2002 across all economic sectors in the US at high resolution. We perform this comparison by fuel type,12 road types, and 12 vehicle types

  16. HIGH-ENERGY NON-THERMAL AND THERMAL EMISSION FROM GRB 141207A DETECTED BY FERMI

    Energy Technology Data Exchange (ETDEWEB)

    Arimoto, Makoto [Research Institute for Science and Engineering, Waseda University, 3-4-1, Ohkubo, Shinjuku, Tokyo, 169-8555 (Japan); Asano, Katsuaki [Institute for Cosmic Ray Research, The University of Tokyo, 5-1-5 Kashiwanoha, Kashiwa, Chiba, 277-8582 (Japan); Ohno, Masanori [Department of Physical Sciences, Hiroshima University, 1-3-1 Kagamiyama, Higashi-Hiroshima, Hiroshima, 739-8526 (Japan); Veres, Péter [Center for Space Plasma and Aeronomic Research (CSPAR), University of Alabama in Huntsville, Huntsville, AL 35899 (United States); Axelsson, Magnus [KTH Royal Institute of Technology, Department of Physics, SE-106 91 Stockholm (Sweden); Bissaldi, Elisabetta [Istituto Nazionale di Fisica Nucleare, Sezione di Bari, I-70126 Bari (Italy); Tachibana, Yutaro; Kawai, Nobuyuki, E-mail: m.arimoto@aoni.waseda.jp [Tokyo Institute of Technology, 2-12-1 Ookayama, Meguro, Tokyo, 152-8551 (Japan)

    2016-12-20

    A bright long gamma-ray burst GRB 141207A was observed by the Fermi Gamma-ray Space Telescope and detected by both instruments onboard. The observations show that the spectrum in the prompt phase is not well described by the canonical empirical Band function alone, and that an additional power-law component is needed. In the early phase of the prompt emission, a modified blackbody with a hard low-energy photon index ( α  = +0.2 to +0.4) is detected, which suggests a photospheric origin. In a finely time-resolved analysis, the spectra are also well fitted by the modified blackbody combined with a power-law function. We discuss the physical parameters of the photosphere such as the bulk Lorentz factor of the relativistic flow and the radius. We also discuss the physical origin of the extra power-law component observed during the prompt phase in the context of different models such as leptonic and hadronic scenarios in the internal shock regime and synchrotron emission in the external forward shock. In the afterglow phase, the temporal and spectral behaviors of the temporally extended high-energy emission and the fading X-ray emission detected by the X-Ray Telescope on-board Swift are consistent with synchrotron emission in a radiative external forward shock.

  17. High efficiency processing for reduced amplitude zones detection in the HRECG signal

    Science.gov (United States)

    Dugarte, N.; Álvarez, A.; Balacco, J.; Mercado, G.; Gonzalez, A.; Dugarte, E.; Olivares, A.

    2016-04-01

    Summary - This article presents part of a more detailed research proposed in the medium to long term, with the intention of establishing a new philosophy of electrocardiogram surface analysis. This research aims to find indicators of cardiovascular disease in its early stage that may go unnoticed with conventional electrocardiography. This paper reports the development of a software processing which collect some existing techniques and incorporates novel methods for detection of reduced amplitude zones (RAZ) in high resolution electrocardiographic signal (HRECG).The algorithm consists of three stages, an efficient processing for QRS detection, averaging filter using correlation techniques and a step for RAZ detecting. Preliminary results show the efficiency of system and point to incorporation of techniques new using signal analysis with involving 12 leads.

  18. Distribution of nonionic organic compounds (highly volatile chlorinated hydrocarbons) in the unsaturated zone

    Energy Technology Data Exchange (ETDEWEB)

    Grathwohl, P.

    1988-01-01

    Nonpolar pollutants, e.g. highly volatile chlorinated hydrocarbons (HVCH) are more or less equally distributed among all three soil phases (solids, water, air) in the unsaturated zone. The sorption of HVCH on soil solids depends on the amount and type of organic matter in the soil. For wet material an additional sorption on mineral surfaces can be neglected, since all possible sites for sorption are occupied by water. Provided the partition-coefficients or sorption-constants are known the contamination of the whole system can be evaluated from the pollutant concentration in the soil air; in addition it is possible to estimate a groundwater risk.

  19. High-resolution forest carbon stocks and emissions in the Amazon

    Science.gov (United States)

    G. P. Asner; George V. N. Powell; Joseph Mascaro; David E. Knapp; John K. Clark; James Jacobson; Ty Kennedy-Bowdoin; Aravindh Balaji; Guayana Paez-Acosta; Eloy Victoria; Laura Secada; Michael Valqui; R. Flint. Hughes

    2010-01-01

    Efforts to mitigate climate change through the Reduced Emissions from Deforestation and Degradation (REDD) depend on mapping and monitoring of tropical forest carbon stocks and emissions over large geographic areas. With a new integrated use of satellite imaging, airborne light detection and ranging, and field plots, we mapped aboveground carbon stocks and emissions at...

  20. X-ray emission from a high-atomic-number z-pinch plasma created from compact wire arrays

    International Nuclear Information System (INIS)

    Sanford, T.W.L.; Mosher, D.; De Groot, J.S.

    1996-01-01

    Thermal and nonthermal x-ray emission from the implosion of compact tungsten wire arrays in 5-MA Saturn discharges is reported. The timing of multiple implosions and the thermal x-ray spectra (1 to 10 keV) agree with 2D radiation-hydrocode simulations. Nonthermal x-ray emission (10 to 100 keV) correlates with pinch spots distributed along the z-axis. The similarities of the measured nonthermal spectrum, yield, and pinch-spot emission with those of 0.8-MA, single-exploded-wire discharges on Gamble-II suggest a common nonthermal-production mechanism. Nonthermal x-ray yields are lower than expected from current scaling of Gamble II results, suggesting that implosion geometries are not as efficient as single-wire geometries for nonthermal x-ray production. The instabilities, azimuthal asymmetries, and inferred multiple implosions that accompany the implosion geometry lead to larger, more irregular pinch spots, a likely reason for reduced nonthermal efficiency. A model for nonthermal-electron acceleration across magnetic fields in highly-collisional, high-atomic-number plasmas combined with 1D hydrocode simulations of Saturn compact loads predicts weak nonthermal x-ray emission. (author). 3 figs., 10 refs

  1. X-ray emission from a high-atomic-number z-pinch plasma created from compact wire arrays

    International Nuclear Information System (INIS)

    Sanford, T.W.L.; Mosher, D.; De Groot, J.S.

    1996-01-01

    Thermal and nonthermal x-ray emission from the implosion of compact tungsten wire arrays in 5-MA Saturn discharges is reported. The timing of multiple implosions and the thermal x-ray spectra (1 to 10 keV) agree with 2D radiation-hydrocode simulations. Nonthermal x-ray emission (10 to 100 keV) correlates with pinch spots distributed along the z-axis. The similarities of the measured nonthermal spectrum, yield, and pinch-spot emission with those of 0.8-MA, single- exploded-wire discharges on Gamble-II suggest a common nonthermal- production mechanism. Nonthermal x-ray yields are lower than expected from current scaling of Gamble II results, suggesting that implosion geometries are not as efficient as single-wire geometries for nonthermal x-ray production. The instabilities, azimuthal asymmetries, and inferred multiple implosions that accompany the implosion geometry lead to larger, more irregular pinch spots, a likely reason for reduced nonthermal efficiency. A model for nonthermal-electron acceleration across magnetic fields in highly- collisional, high-atomic-number plasmas combined with 1D hydrocode simulations of Saturn compact loads predicts weak nonthermal x-ray emission

  2. Very High Radiation Detector for the LHC BLM System Based on Secondary Electron Emission

    CERN Document Server

    Dehning, B; Holzer, EB; Kramer, D

    2007-01-01

    Beam Loss Monitoring (BLM) system plays a vital role in the active protection of the LHC accelerators elements. It should provide the number of particles lost from the primary hadron beam by measuring the radiation field induced by their interaction with matter surrounding the beam pipe. The LHC BLM system will use ionization chambers as standard detectors but in the areas where very high dose rates are expected, the Secondary Emission Monitor (SEM) chambers will be employed because of their high linearity, low sensitivity and fast response. The SEM needs a high vacuum for proper operation and has to be functional for up to 20 years, therefore all the components were designed according to the UHV requirements and a getter pump was included. The SEM electrodes are made of Ti because of its Secondary Emission Yield (SEY) stability. The sensitivity of the SEM was modeled in Geant4 via the Photo-Absorption Ionization module together with custom parameterization of the very low energy secondary electron production...

  3. Constraining the High-Energy Emission from Gamma-Ray Bursts with Fermi

    Science.gov (United States)

    Gehrels, Neil; Harding, A. K.; Hays, E.; Racusin, J. L.; Sonbas, E.; Stamatikos, M.; Guirec, S.

    2012-01-01

    We examine 288 GRBs detected by the Fermi Gamma-ray Space Telescope's Gamma-ray Burst Monitor (GBM) that fell within the field-of-view of Fermi's Large Area Telescope (LAT) during the first 2.5 years of observations, which showed no evidence for emission above 100 MeV. We report the photon flux upper limits in the 0.1-10 GeV range during the prompt emission phase as well as for fixed 30 s and 100 s integrations starting from the trigger time for each burst. We compare these limits with the fluxes that would be expected from extrapolations of spectral fits presented in the first GBM spectral catalog and infer that roughly half of the GBM-detected bursts either require spectral breaks between the GBM and LAT energy bands or have intrinsically steeper spectra above the peak of the nuF(sub v) spectra (E(sub pk)). In order to distinguish between these two scenarios, we perform joint GBM and LAT spectral fits to the 30 brightest GBM-detected bursts and find that a majority of these bursts are indeed softer above E(sub pk) than would be inferred from fitting the GBM data alone. Approximately 20% of this spectroscopic subsample show statistically significant evidence for a cut-off in their high-energy spectra, which if assumed to be due to gamma gamma attenuation, places limits on the maximum Lorentz factor associated with the relativistic outflow producing this emission. All of these latter bursts have maximum Lorentz factor estimates that are well below the minimum Lorentz factors calculated for LAT-detected GRBs, revealing a wide distribution in the bulk Lorentz factor of GRB outflows and indicating that LAT-detected bursts may represent the high end of this distribution.

  4. Characterization of Future Caribbean Rainfall and Temperature Extremes across Rainfall Zones

    Directory of Open Access Journals (Sweden)

    Natalie Melissa McLean

    2015-01-01

    Full Text Available End-of-century changes in Caribbean climate extremes are derived from the Providing Regional Climate for Impact Studies (PRECIS regional climate model (RCM under the A2 and B2 emission scenarios across five rainfall zones. Trends in rainfall, maximum temperature, and minimum temperature extremes from the RCM are validated against meteorological stations over 1979–1989. The model displays greater skill at representing trends in consecutive wet days (CWD and extreme rainfall (R95P than consecutive dry days (CDD, wet days (R10, and maximum 5-day precipitation (RX5. Trends in warm nights, cool days, and warm days were generally well reproduced. Projections for 2071–2099 relative to 1961–1989 are obtained from the ECHAM5 driven RCM. Northern and eastern zones are projected to experience more intense rainfall under A2 and B2. There is less consensus across scenarios with respect to changes in the dry and wet spell lengths. However, there is indication that a drying trend may be manifest over zone 5 (Trinidad and northern Guyana. Changes in the extreme temperature indices generally suggest a warmer Caribbean towards the end of century across both scenarios with the strongest changes over zone 4 (eastern Caribbean.

  5. Critical emission from a high-spin black hole

    Science.gov (United States)

    Lupsasca, Alexandru; Porfyriadis, Achilleas P.; Shi, Yichen

    2018-03-01

    We consider a rapidly spinning black hole surrounded by an equatorial, geometrically thin, slowly accreting disk that is stationary and axisymmetric. We analytically compute the broadening of electromagnetic line emissions from the innermost part of the disk, which resides in the near-horizon region. The result is independent of the disk's surface emissivity and therefore universal. This is an example of critical behavior in astronomy that is potentially observable by current or future telescopes.

  6. Universal Approach to Estimate Perfluorocarbons Emissions During Individual High-Voltage Anode Effect for Prebaked Cell Technologies

    Science.gov (United States)

    Dion, Lukas; Gaboury, Simon; Picard, Frédéric; Kiss, Laszlo I.; Poncsak, Sandor; Morais, Nadia

    2018-04-01

    Recent investigations on aluminum electrolysis cell demonstrated limitations to the commonly used tier-3 slope methodology to estimate perfluorocarbon (PFC) emissions from high-voltage anode effects (HVAEs). These limitations are greater for smelters with a reduced HVAE frequency. A novel approach is proposed to estimate the specific emissions using a tier 2 model resulting from individual HVAE instead of estimating monthly emissions for pot lines with the slope methodology. This approach considers the nonlinear behavior of PFC emissions as a function of the polarized anode effect duration but also integrates the change in behavior attributed to cell productivity. Validation was performed by comparing the new approach and the slope methodology with measurement campaigns from different smelters. The results demonstrate a good agreement between measured and estimated emissions as well as more accurately reflect individual HVAE dynamics occurring over time. Finally, the possible impact of this approach for the aluminum industry is discussed.

  7. Thermodynamic Temperatures of High-Temperature Fixed Points: Uncertainties Due to Temperature Drop and Emissivity

    Science.gov (United States)

    Castro, P.; Machin, G.; Bloembergen, P.; Lowe, D.; Whittam, A.

    2014-07-01

    This study forms part of the European Metrology Research Programme project implementing the New Kelvin to assign thermodynamic temperatures to a selected set of high-temperature fixed points (HTFPs), Cu, Co-C, Pt-C, and Re-C. A realistic thermal model of these HTFPs, developed in finite volume software ANSYS FLUENT, was constructed to quantify the uncertainty associated with the temperature drop across the back wall of the cell. In addition, the widely applied software package, STEEP3 was used to investigate the influence of cell emissivity. The temperature drop, , relates to the temperature difference due to the net loss of heat from the aperture of the cavity between the back wall of the cavity, viewed by the thermometer, defining the radiance temperature, and the solid-liquid interface of the alloy, defining the transition temperature of the HTFP. The actual value of can be used either as a correction (with associated uncertainty) to thermodynamic temperature evaluations of HTFPs, or as an uncertainty contribution to the overall estimated uncertainty. In addition, the effect of a range of furnace temperature profiles on the temperature drop was calculated and found to be negligible for Cu, Co-C, and Pt-C and small only for Re-C. The effective isothermal emissivity is calculated over the wavelength range from 450 nm to 850 nm for different assumed values of surface emissivity. Even when furnace temperature profiles are taken into account, the estimated emissivities change only slightly from the effective isothermal emissivity of the bare cell. These emissivity calculations are used to estimate the uncertainty in the temperature assignment due to the uncertainty in the emissivity of the blackbody.

  8. The role of the hyporheic zone across stream networks

    Science.gov (United States)

    Steven M. Wondzell

    2011-01-01

    Many hyporheic papers state that the hyporheic zone is a critical component of stream ecosystems, and many of these papers focus on the biogeochemical effects of the hyporheic zone on stream solute loads. However, efforts to show such relationships have proven elusive, prompting several questions: Are the effects of the hyporheic zone on stream ecosystems so highly...

  9. Effect of Construction Land Expansion on Energy-Related Carbon Emissions: Empirical Analysis of China and Its Provinces from 2001 to 2011

    Directory of Open Access Journals (Sweden)

    Xuankai Deng

    2015-06-01

    Full Text Available Construction land expansion significantly affects energy-related carbon emissions. This paper analyzed the effect of construction land expansion on energy-related carbon emissions in China and its provinces from 2001 to 2011 by using the logarithmic mean Divisia index method. We divided the study into two intervals (2001–2006 and 2006–2011 and categorized the 30 provinces of China into eight zones. Results indicated that construction land expansion exerted the second largest positive effect on carbon emission growth in China and in the 30 provinces from 2001 to 2011. The north, east, and south coastal regions as well as the middle Yellow River region, were the highly affected regions in the same period. Between the two study intervals, the effect of construction land expansion on carbon emissions decreased in China and in the coastal regions, but increased in inland regions. The Hebei, Shandong, Jiangsu, Zhejiang, Fujian, Guangdong, Yunnan, Chongqing, Ningxia, and Xinjiang provinces, which are concentrated in the north, east, and south coastal regions, were selected for the reduction of carbon emissions by controlling construction land expansion.

  10. Fuel conditioning facility zone-to-zone transfer administrative controls

    International Nuclear Information System (INIS)

    Pope, C. L.

    2000-01-01

    The administrative controls associated with transferring containers from one criticality hazard control zone to another in the Argonne National Laboratory (ANL) Fuel Conditioning Facility (FCF) are described. FCF, located at the ANL-West site near Idaho Falls, Idaho, is used to remotely process spent sodium bonded metallic fuel for disposition. The process involves nearly forty widely varying material forms and types, over fifty specific use container types, and over thirty distinct zones where work activities occur. During 1999, over five thousand transfers from one zone to another were conducted. Limits are placed on mass, material form and type, and container types for each zone. Ml material and containers are tracked using the Mass Tracking System (MTG). The MTG uses an Oracle database and numerous applications to manage the database. The database stores information specific to the process, including material composition and mass, container identification number and mass, transfer history, and the operators involved in each transfer. The process is controlled using written procedures which specify the zone, containers, and material involved in a task. Transferring a container from one zone to another is called a zone-to-zone transfer (ZZT). ZZTs consist of four distinct phases, select, request, identify, and completion

  11. Mechanism of formation of a zone without vacancy pores along a surface under electron irradiation of a metal in the high-volt electron microscope

    International Nuclear Information System (INIS)

    Golubov, S.I.; Konobeev, Yu.V.; Ryabov, V.A.

    1981-01-01

    Formation mechanism of zones free of vacancy pores near the vacant surface of a metal preliminary irradiated at a high neutron dose when irradiating with electrons in a high-voltage electron microscope has been suggested. It was assumed to explain experimentally observed values of width and time of such zone formation that interstitial atoms are reflected from foil surface while boundary serves as an ideal sink for the vacancies. The carried out calculation of stationary equations of vacancy and interstitial diffusion with the mentioned boundary condition has shown that determination of a stable zone width is possible only in assumption on a variable in a depth of dislocation density. Theoretical evaluations of a zone width being in good agreement with an experiment and with the results of numerical calculations have been obtained in negligence of recombination of point defects as well as for the case of total reflection of interstitials. Discussed are different mechanisms of weak capture of proper interstitial atoms diffusing to it with the metal surface [ru

  12. Research of the Electron Cyclotron Emission with Vortex Property excited by high power high frequency Gyrotron

    Science.gov (United States)

    Goto, Yuki; Kubo, Shin; Tsujimura, Tohru; Takubo, Hidenori

    2017-10-01

    Recently, it has been shown that the radiation from a single electron in cyclotron motion has vortex property. Although the cyclotron emission exists universally in nature, the vortex property has not been featured because this property is normally cancelled out due to the randomness in gyro-phase of electrons and the development of detection of the vortex property has not been well motivated. In this research, we are developing a method to generate the vortex radiation from electrons in cyclotron motion with controlled gyro-phase. Electron that rotates around the uniform static magnetic field is accelerated by right-hand circular polarized (RHCP) radiation resonantly when the cyclotron frequency coincides with the applied RHCP radiation frequency. A large number of electrons can be coherently accelerated in gyro-phase by a RHCP high power radiation so that these electrons can radiate coherent emission with vortex feature. We will show that vortex radiation created by purely rotating electrons for the first time.

  13. Control of Emission Color of High Quantum Yield CH3NH3PbBr3 Perovskite Quantum Dots by Precipitation Temperature.

    Science.gov (United States)

    Huang, He; Susha, Andrei S; Kershaw, Stephen V; Hung, Tak Fu; Rogach, Andrey L

    2015-09-01

    Emission color controlled, high quantum yield CH 3 NH 3 PbBr 3 perovskite quantum dots are obtained by changing the temperature of a bad solvent during synthesis. The products for temperatures between 0 and 60 °C have good spectral purity with narrow emission line widths of 28-36 nm, high absolute emission quantum yields of 74% to 93%, and short radiative lifetimes of 13-27 ns.

  14. Intelligent Heat System - High-Energy Efficient Wood Stoves with Low Emissions. Field Tests

    DEFF Research Database (Denmark)

    Illerup, Jytte Boll; Nickelsen, Joachim; Hansen, Brian Brun

    2014-01-01

    Wood stoves have the potential of providing CO2-neutral energy without transmission loss—but with the significant drawbacks of high emissions of pollutants and particulate matter at low altitude close to private homes, and with an uneven heat release profile which produces non-optimal heating...

  15. Molecular differences in transition zone and peripheral zone prostate tumors

    Science.gov (United States)

    Sinnott, Jennifer A.; Rider, Jennifer R.; Carlsson, Jessica; Gerke, Travis; Tyekucheva, Svitlana; Penney, Kathryn L.; Sesso, Howard D.; Loda, Massimo; Fall, Katja; Stampfer, Meir J.; Mucci, Lorelei A.; Pawitan, Yudi; Andersson, Sven-Olof; Andrén, Ove

    2015-01-01

    Prostate tumors arise primarily in the peripheral zone (PZ) of the prostate, but 20–30% arise in the transition zone (TZ). Zone of origin may have prognostic value or reflect distinct molecular subtypes; however, it can be difficult to determine in practice. Using whole-genome gene expression, we built a signature of zone using normal tissue from five individuals and found that it successfully classified nine tumors of known zone. Hypothesizing that this signature captures tumor zone of origin, we assessed its relationship with clinical factors among 369 tumors of unknown zone from radical prostatectomies (RPs) and found that tumors that molecularly resembled TZ tumors showed lower mortality (P = 0.09) that was explained by lower Gleason scores (P = 0.009). We further applied the signature to an earlier study of 88 RP and 333 transurethral resection of the prostate (TURP) tumor samples, also of unknown zone, with gene expression on ~6000 genes. We had observed previously substantial expression differences between RP and TURP specimens, and hypothesized that this might be because RPs capture primarily PZ tumors, whereas TURPs capture more TZ tumors. Our signature distinguished these two groups, with an area under the receiver operating characteristic curve of 87% (P zones. Zone of origin may be important to consider in prostate tumor biomarker research. PMID:25870172

  16. Coupling creep and damage in concrete under high sustained loading: Experimental investigation on bending beams and application of Acoustic Emission technique

    Directory of Open Access Journals (Sweden)

    Grondin F.

    2010-06-01

    had a strengthening effect on concrete, probably because of the consolidation of the hardened cement paste. The influence of creep on fracture energy, fracture toughness, and characteristic length of concrete is also studied. The fracture energy and the characteristic length of concrete increases slightly when creep occurs prior to failure and the size of the fracture process zone increases too. The load-CMOD relationship is linear in the ascending portion and gradually drops off after the peak value in the descending portion. The length of the tail end portion of the softening curve increases with beams subjected to creep. Relatively more ductile fracture behavior was observed with beams subjected to creep. The contribution of non-destructive and instrumental investigation methods is currently exploited to check and measure the evolution of some negative structural phenomena, such as micro-and macro-cracking, finally resulting in a creep-like behaviour. Among these methods, the non-destructive technique based on acoustic Emission proves to be very effective, especially to check and measure micro-cracking that takes place inside a structure under mechanical loading. Thus as a part of the investigation quantitative acoustic emission techniques were applied to investigate microcracking and damage localization in concrete beams. The AE signals were captured with the AE WIN software and further analyzed with Noesis software analysis of acoustic emission data. AE waveforms were generated as elastic waves in concrete due to crack nucleation. And a multichannel data acquisition system was used to record the AE waveforms. During the three point bending tests, quantitative acoustic emission (AE techniques were used to monitor crack growth and to deduce micro fracture mechanics in concrete beams before and after creep. Several specimens are experimented in order to match each cluster with corresponding damage mechanism of the material under loading. At the same time acoustic

  17. Coupling creep and damage in concrete under high sustained loading: Experimental investigation on bending beams and application of Acoustic Emission technique

    Science.gov (United States)

    Saliba, J.; Loukili, A.; Grondin, F.

    2010-06-01

    effect on concrete, probably because of the consolidation of the hardened cement paste. The influence of creep on fracture energy, fracture toughness, and characteristic length of concrete is also studied. The fracture energy and the characteristic length of concrete increases slightly when creep occurs prior to failure and the size of the fracture process zone increases too. The load-CMOD relationship is linear in the ascending portion and gradually drops off after the peak value in the descending portion. The length of the tail end portion of the softening curve increases with beams subjected to creep. Relatively more ductile fracture behavior was observed with beams subjected to creep. The contribution of non-destructive and instrumental investigation methods is currently exploited to check and measure the evolution of some negative structural phenomena, such as micro-and macro-cracking, finally resulting in a creep-like behaviour. Among these methods, the non-destructive technique based on acoustic Emission proves to be very effective, especially to check and measure micro-cracking that takes place inside a structure under mechanical loading. Thus as a part of the investigation quantitative acoustic emission techniques were applied to investigate microcracking and damage localization in concrete beams. The AE signals were captured with the AE WIN software and further analyzed with Noesis software analysis of acoustic emission data. AE waveforms were generated as elastic waves in concrete due to crack nucleation. And a multichannel data acquisition system was used to record the AE waveforms. During the three point bending tests, quantitative acoustic emission (AE) techniques were used to monitor crack growth and to deduce micro fracture mechanics in concrete beams before and after creep. Several specimens are experimented in order to match each cluster with corresponding damage mechanism of the material under loading. At the same time acoustic emission was used to

  18. Natural analogues for processes affecting disposal of high-level radioactive waste in the vadose zone

    Science.gov (United States)

    Stuckless, J. S.

    2003-04-01

    Natural analogues can contribute to understanding and predicting the performance of subsystems and processes affecting a mined geologic repository for high-level radioactive waste in several ways. Most importantly, analogues provide tests for various aspects of systems of a repository at dimensional scales and time spans that cannot be attained by experimental study. In addition, they provide a means for the general public to judge the predicted performance of a potential high-level nuclear waste repository in familiar terms such that the average person can assess the anticipated long-term performance and other scientific conclusions. Hydrologists working on the Yucca Mountain Project (currently the U.S. Department of Energy's Office of Repository Development) have modeled the flow of water through the vadose zone at Yucca Mountain, Nevada and particularly the interaction of vadose-zone water with mined openings. Analogues from both natural and anthropogenic examples confirm the prediction that most of the water moving through the vadose zone will move through the host rock and around tunnels. This can be seen both quantitatively where direct comparison between seepage and net infiltration has been made and qualitatively by the excellent degree of preservation of archaeologic artifacts in underground openings. The latter include Paleolithic cave paintings in southwestern Europe, murals and artifacts in Egyptian tombs, painted subterranean Buddhist temples in India and China, and painted underground churches in Cappadocia, Turkey. Natural analogues also suggest that this diversion mechanism is more effective in porous media than in fractured media. Observations from natural analogues are also consistent with the modeled decrease in the percentage of infiltration that becomes seepage with a decrease in amount of infiltration. Finally, analogues, such as tombs that have ben partially filled by mud flows, suggest that the same capillary forces that keep water in the

  19. [Effects of exogenous high mobility group protein box 1 on angiogenesis in ischemic zone of early scald wounds of rats].

    Science.gov (United States)

    Dai, L; Guo, X; Huang, H J; Liao, X M; Luo, X Q; Li, D; Zhou, H; Gao, X C; Tan, M Y

    2018-04-20

    Objective: To observe effects of exogenous high mobility group protein box 1 (HMGB1) on angiogenesis in ischemic zone of early scald wounds of rats. Methods: Thirty-six Sprague-Dawley rats were divided into HMGB1 group and simple scald (SS) group according to the random number table, with 18 rats in each group. Comb-like copper mould was placed on the back of rats for 20 s after being immersed in 100 ℃ hot water for 3 to 5 min to make three ischemic zones of wound. Immediately after scald, rats in HMGB1 group were subcutaneously injected with 0.4 μg HMGB1 and 0.1 mL phosphate buffer solution (PBS), and rats in SS group were subcutaneously injected with 0.1 mL PBS from boarders of ischemic zone of scald wound. At post scald hour (PSH) 24, 48, and 72, 6 rats in each group were collected. Protein expressions of vascular endothelial growth factor (VEGF) in ischemic zone of wound at PSH 24, 48, and 72 and protein expressions of CD31 in ischemic zone of wound at PSH 48 and 72 were detected by immunohistochemistry. The number of microvessel in CD31 immunohistochemical sections of ischemic zone of wound at PSH 48 and 72 was calculated after observing by the microscope. The mRNA expressions of VEGF and CD31 in ischemic zone of wound were detected by real-time fluorescence quantitative reverse transcription polymerase chain reaction at PSH 24, 48, and 72. Data were processed with analysis of variance of factorial design, t test, and Bonferroni correction. Results: (1) At PSH 24, 48, and 72, protein expressions of VEGF in ischemic zone of wound of rats in HMGB1 group were significantly higher than those of rats in SS group ( t =7.496, 4.437, 5.402, P zone of wound of rats in HMGB1 group were 0.038 8±0.007 9 and 0.057 7±0.001 2 respectively, significantly higher than 0.013 4±0.004 9 and 0.030 3±0.004 0 of rats in SS group ( t =10.257, 15.055, P zone of wound of rats in HMGB1 group was obviously more than that of rats in SS group ( t =3.536, 4.000, P zone of wound of

  20. Irradiation damage 'displacement zone'; Dommages sous irradiation zone de deplacements

    Energy Technology Data Exchange (ETDEWEB)

    Genthon, J P [Commissariat a l' Energie Atomique, Saclay (France). Centre d' Etudes Nucleaires

    1969-07-01

    It is well known that a charged particle (ion, primary atom, etc...) moving in a solid slows down and can cause a cascade of displacements of the atoms in the solid. A study is made here of the extent to which the cascade is made up, or not, of independent collisions, as a function of the energy of the initial charged particle. When the distance between the collisions is small, these latter are no longer independent; the cascade, which then has to be considered as a whole, perturbs and locates, in the irradiated solid , a zone which has been named a 'displacement zone'. It is shown that the proportion of displacement zones increases with increasing atom size (high atomic number Z), with decreasing atomic distance D in the substance considered and with decreasing energy of the ion undergoing the slowing down process (although always remaining above a few hundred eV). The proportions obtained are higher than those corresponding to the calculations of J. A. Brinkman [3]. An interatomic potential required for this work has also been determined. (author) [French] On sait qu'une particule chargee (ions, atomes primaires, etc...) en mouvement dans un solide se ralentit, avec eventuellement deplacement en cascade d'atomes du solide. On etudie ici dans quelle proportion, en fonction de l'energie de la particule chargee initiale, la cascade est constituee, ou non, de 'chocs independants'. Lorsque la distance entre chocs est petite, ceux-ci ne sont plus independants; la cascade, qui doit alors etre consideree dans son ensemble, perturbe et definit dans le solide irradie, une zone qu'on a appele zone de deplacements. On montre que la proportion de zones de deplacements est d'autant plus grande que les atomes sont gros (nombre atomique Z grand), que la distance interatomique D est petite dans le corps considere, et que l'energie de l'ion en ralentissement est petite (tout en restant superieure a quelques centaines d'eV). Les proportions obtenues sont superieures a celles qui

  1. High-resolution inversion of OMI formaldehyde columns over the Southeast US to infer isoprene emissions

    Science.gov (United States)

    Kaiser, J.; Zhu, L.; Travis, K.; Jacob, D.

    2017-12-01

    In the South East United States, biogenic isoprene fuels tropospheric ozone formation, and its oxidation products contribute significantly to organic aerosol. Bottom-up emission inventories rely on very limited isoprene emission and land-cover data, yielding uncertainties of a factor of 2 or more. Here, we use formaldehyde columns from the Ozone Monitoring Instrument in a high-resolution (0.25 x 0.325o) adjoint-based inversion to constrain isoprene emissions over the SE US during Aug-Sept of 2013. We find that the MEGANv2.1 inventory is biased high over most of the SE US. Our derived scaling factors show significant spatial variability, with the largest corrections applied to Louisiana and the Edwards Plateau in Texas. We test our inversion results against a comprehensive set of isoprene oxidation product observations from the NASA SEAC4RS flight campaign. The SEAC4RS data provides new confidence in the satellite retrievals and in mechanism linking isoprene oxidation to formaldehyde production. Finally, we relate the posterior scaling factors to the underlying land-type, and examine potential sources of observed biases.

  2. Sensor transition failure in the high flow sampler: Implications for methane emission inventories of natural gas infrastructure.

    Science.gov (United States)

    Howard, Touché; Ferrara, Thomas W; Townsend-Small, Amy

    2015-07-01

    Quantification of leaks from natural gas (NG) infrastructure is a key step in reducing emissions of the greenhouse gas methane (CH4), particularly as NG becomes a larger component of domestic energy supply. The U.S. Environmental Protection Agency (EPA) requires measurement and reporting of emissions of CH4 from NG transmission, storage, and processing facilities, and the high-flow sampler (or high-volume sampler) is one of the tools approved for this by the EPA. The Bacharach Hi-Flow Sampler (BHFS) is the only commercially available high-flow instrument, and it is also used throughout the NG supply chain for directed inspection and maintenance, emission factor development, and greenhouse gas reduction programs. Here we document failure of the BHFS to transition from a catalytic oxidation sensor used to measure low NG (~5% or less) concentrations to a thermal conductivity sensor for higher concentrations (from ~5% to 100%), resulting in underestimation of NG emission rates. Our analysis includes both our own field testing and analysis of data from two other studies (Modrak et al., 2012; City of Fort Worth, 2011). Although this failure is not completely understood, and although we do not know if all BHFS models are similarly affected, sensor transition failure has been observed under one or more of these conditions: (1) Calibration is more than ~2 weeks old; (2) firmware is out of date; or (3) the composition of the NG source is less than ~91% CH4. The extent to which this issue has affected recent emission studies is uncertain, but the analysis presented here suggests that the problem could be widespread. Furthermore, it is critical that this problem be resolved before the onset of regulations on CH4 emissions from the oil and gas industry, as the BHFS is a popular instrument for these measurements. An instrument commonly used to measure leaks in natural gas infrastructure has a critical sensor transition failure issue that results in underestimation of leaks, with

  3. Enhanced Field Emission Studies on Niobium Surfaces Relevant to High Field Superconducting Radio-Frequency Devices

    Energy Technology Data Exchange (ETDEWEB)

    Wang, Tong [Virginia Polytechnic Inst. and State Univ. (Virginia Tech), Blacksburg, VA (United States)

    2002-09-18

    Enhanced field emission (EFE) presents the main impediment to higher acceleration gradients in superconducting niobium (Nb) radiofrequency cavities for particle accelerators. The strength, number and sources of EFE sites strongly depend on surface preparation and handling. The main objective of this thesis project is to systematically investigate the sources of EFE from Nb, to evaluate the best available surface preparation techniques with respect to resulting field emission, and to establish an optimized process to minimize or eliminate EFE. To achieve these goals, a scanning field emission microscope (SFEM) was designed and built as an extension to an existing commercial scanning electron microscope (SEM). In the SFEM chamber of ultra high vacuum, a sample is moved laterally in a raster pattern under a high voltage anode tip for EFE detection and localization. The sample is then transferred under vacuum to the SEM chamber equipped with an energy-dispersive x-ray spectrometer for individual emitting site characterization. Compared to other systems built for similar purposes, this apparatus has low cost and maintenance, high operational flexibility, considerably bigger scan area, as well as reliable performance. EFE sources from planar Nb have been studied after various surface preparation, including chemical etching and electropolishing, combined with ultrasonic or high-pressure water rinse. Emitters have been identified, analyzed and the preparation process has been examined and improved based on EFE results. As a result, field-emission-free or near field-emission-free surfaces at ~140 MV/m have been consistently achieved with the above techniques. Characterization on the remaining emitters leads to the conclusion that no evidence of intrinsic emitters, i.e., no fundamental electric field limit induced by EFE, has been observed up to ~140 MV/m. Chemically etched and electropolished Nb are compared and no significant difference is observed up to ~140 MV/m. To

  4. Enhanced Field Emission Studies on Niobium Surfaces Relevant to High Field Superconducting Radio-Frequency Devices

    International Nuclear Information System (INIS)

    Tong Wang

    2002-01-01

    Enhanced field emission (EFE) presents the main impediment to higher acceleration gradients in superconducting niobium (Nb) radio frequency cavities for particle accelerators. The strength, number and sources of EFE sites strongly depend on surface preparation and handling. The main objective of this thesis project is to systematically investigate the sources of EFE from Nb, to evaluate the best available surface preparation techniques with respect to resulting field emission, and to establish an optimized process to minimize or eliminate EFE. To achieve these goals, a scanning field emission microscope (SFEM) was designed and built as an extension to an existing commercial scanning electron microscope (SEM). In the SFEM chamber of ultra high vacuum, a sample is moved laterally in a raster pattern under a high voltage anode tip for EFE detection and localization. The sample is then transferred under vacuum to the SEM chamber equipped with an energy-dispersive x-ray spectrometer for individual emitting site characterization. Compared to other systems built for similar purposes, this apparatus has low cost and maintenance, high operational flexibility, considerably bigger scan area, as well as reliable performance. EFE sources from planar Nb have been studied after various surface preparation, including chemical etching and electropolishing, combined with ultrasonic or high-pressure water rinse. Emitters have been identified, analyzed and the preparation process has been examined and improved based on EFE results. As a result, field-emission-free or near field-emission-free surfaces at ∼140 MV/m have been consistently achieved with the above techniques. Characterization on the remaining emitters leads to the conclusion that no evidence of intrinsic emitters, i.e., no fundamental electric field limit induced by EFE, has been observed up to ∼140 MV/m. Chemically etched and electropolished Nb are compared and no significant difference is observed up to ∼140 MV

  5. Atmospheric emission of NOx from mining explosives: A critical review

    Science.gov (United States)

    Oluwoye, Ibukun; Dlugogorski, Bogdan Z.; Gore, Jeff; Oskierski, Hans C.; Altarawneh, Mohammednoor

    2017-10-01

    High-energy materials such as emulsions, slurries and ammonium-nitrate fuel-oil (ANFO) explosives play crucial roles in mining, quarrying, tunnelling and many other infrastructure activities, because of their excellent transport and blasting properties. These explosives engender environmental concerns, due to atmospheric pollution caused by emission of dust and nitrogen oxides (NOx) from blasts, the latter characterised by the average emission factor of 5 kg (t AN explosive)-1. This first-of-its-kind review provides a concise literature account of the formation of NOx during blasting of AN-based explosives, employed in surface operations. We estimate the total NOx emission rate from AN-based explosives as 0.05 Tg (i.e., 5 × 104 t) N per annum, compared to the total global annual anthropogenic NOx emissions of 41.3 × 106 t N y-1. Although minor in the global sense, the large localised plumes from blasting exhibit high NOx concentration (500 ppm) exceeding up to 3000 times the international standards. This emission has profound consequences at mining sites and for adjacent atmospheric environment, necessitating expensive management of exclusion zones. The review describes different types of AN energetic materials for civilian applications, and summarises the essential properties and terminologies pertaining to their use. Furthermore, we recapitulate the mechanisms that lead to the formation of the reactive nitrogen species in blasting of AN-based explosives, review their implications to atmospheric air pollution, and compare the mechanisms with those experienced in other thermal and combustion operations. We also examine the mitigation approaches, including guidelines and operational-control measures. The review discusses the abatement technologies such as the formulation of new explosive mixtures, comprising secondary fuels, spin traps and other additives, in light of their effectiveness and efficiency. We conclude the review with a summary of unresolved problems

  6. Particulate emissions from new heavy duty vehicles (Euro IV and V); Partikeludslip fra nye tunge koeretoejer (Euronorm IV og V)

    Energy Technology Data Exchange (ETDEWEB)

    Jordal-Joergensen, J.; Ohm, A.; Willumsen, E. (COWI A/S, Kgs. Lyngby (DK))

    2008-07-01

    The new Danish act on environmental zones allows local authorities to define zones where EURO III or older heavy duty vehicles should be equipped with a particulate filter. The introduction of EURO IV and V has reduced particulate emissions from heavy duty vehicles by approximately 80 % based on the mass of particles. There is, however, substantial uncertainty about the impact on the number of ultrafine particles, since they are not covered by Euronorm standards. When passing the bill, the Danish Minister for the Environment of the time stated that all relevant knowledge about particle emission from heavy duty vehicles needed to be collected for subsequent publication. To this end, the Danish Environmental Protection Agency (DEPA) commissioned a literature survey. The purpose of the survey is to provide an overview of the latest knowledge in the field of particle emissions from heavy duty vehicles, with special focus on the average size of the particle emissions. Another objective of the study is to analyse the direct emissions of NO{sub 2} from heavy duty vehicles classified under EURO IV and V. (au)

  7. Dust emission and soil loss due to anthropogenic activities by wind erosion simulations

    Science.gov (United States)

    Katra, Itzhak; Swet, Nitzan; Tanner, Smadar

    2017-04-01

    Wind erosion is major process of soil loss and air pollution by dust emission of clays, nutrients, and microorganisms. Many soils throughout the world are currently or potentially associated with dust emissions, especially in dryland zones. The research focuses on wind erosion in semi-arid soils (Northern Negev, Israel) that are subjected to increased human activities of urban development and agriculture. A boundary-layer wind tunnel has been used to study dust emission and soil loss by simulation and quantification of high-resolution wind processes. Field experiments were conducted in various surface types of dry loess soils. The experimental plots represent soils with long-term and short term influences of land uses such as agriculture (conventional and organic practices), grazing, and natural preserves. The wind tunnel was operated under various wind velocities that are above the threshold velocity of aeolian erosion. Total soil sediment and particulate matter (PM) fluxes were calculated. Topsoil samples from the experimental plots were analysed in the laboratory for physical and chemical characteristics including aggregation, organic matter, and high-resolution particle size distribution. The results showed variations in dust emission in response to surface types and winds to provide quantitative estimates of soil loss over time. Substantial loss of particulate matter that is < 10 micrometer in diameter, including clays and nutrients, was recorded in most experimental conditions. Integrative analyses of the topsoil properties and dust experiment highlight the significant implications for soil nutrient resources and management strategies as well as for PM loading to the atmosphere and air pollution.

  8. Steady-state emission of blazars at very high energies

    Energy Technology Data Exchange (ETDEWEB)

    Hoehne-Moench, Daniel

    2010-07-01

    One key scientific program of the MAGIC telescope project is the discovery and detection of blazars. They constitute the most prominent extragalactic source class in the very high energy (VHE) {gamma}-ray regime with 29 out of 34 known objects. Therefore a major part of the available observation time was spent in the last years on high-frequency peaked blazars. The selection criteria were chosen to increase the detection probability. As the X-ray flux is believed to be correlated to the VHE {gamma}-ray flux, only X-ray selected sources with a flux F{sub X}>2 {mu}Jy at 1 keV were considered. To avoid strong attenuation of the -rays in the extragalactic infrared background, the redshift was restricted to values between z<0.15 and z<0.4, depending on the declination of the objects. The latter determines the zenith distance during culmination which should not exceed 30 (for z<0.4) and 45 (for z<0.15), respectively. Between August 2005 and April 2009, a sample of 24 X-ray selected high-frequency peaked blazars has been observed with the MAGIC telescope. Three of them were detected including 1ES 1218+304 being the first high-frequency peaked BL Lacertae object (HBL) to be discovered with MAGIC in VHE {gamma}-rays. One previously detected object was not confirmed as VHE emitter in this campaign by MAGIC. A set of 20 blazars previously not detected is treated more closely in this work. In this campaign, during almost four years {proportional_to}450 hrs or {proportional_to}22% of the available observation time for extragalactic objects were dedicated to investigate the baseline emission of blazars and their broadband spectral properties in this emission state. For the sample of 20 objects in a redshift range of 0.018

  9. Elements for the expected mechanisms on 'reduced emissions from deforestation and degradation, REDD' under UNFCCC

    Science.gov (United States)

    Mollicone, D.; Freibauer, A.; Schulze, E. D.; Braatz, S.; Grassi, G.; Federici, S.

    2007-10-01

    Carbon emissions from deforestation and degradation account for about 20% of global anthropogenic emissions. Strategies and incentives for reduced emissions from deforestation and degradation (REDD) have emerged as one of the most active areas in the international climate change negotiations under the United Nations Framework Convention on Climate Change (UNFCCC). While the current negotiations focus on a REDD mechanism in developing countries, it should be recognized that risks of carbon losses from forests occur in all climate zones and also in industrialized countries. A future climate change agreement would be more effective if it included all carbon losses and gains from land use in all countries and climate zones. The REDD mechanism will be an important step towards reducing emissions from land use change in developing countries, but needs to be followed by steps in other land use systems and regions. A national approach to REDD and significant coverage globally are needed to deal with the risk that deforestation and degradation activities are displaced rather than avoided. Favourable institutional and governance conditions need to be established that guarantee in the long-term a stable incentive and control system for maintaining forest carbon stocks. Ambitious emission reductions from deforestation and forest degradation need sustained financial incentives, which go beyond positive incentives for reduced emissions but also give incentives for sustainable forest management. Current data limitations need—and can be—overcome in the coming years to allow accurate accounting of reduced emissions from deforestation and degradation. A proper application of the conservativeness approach in the REDD context could allow a simplified reporting of emissions from deforestation in a first phase, consistent with the already agreed UNFCCC reporting principles.

  10. Elements for the expected mechanisms on 'reduced emissions from deforestation and degradation, REDD' under UNFCCC

    International Nuclear Information System (INIS)

    Mollicone, D; Freibauer, A; Schulze, E D; Braatz, S; Grassi, G; Federici, S

    2007-01-01

    Carbon emissions from deforestation and degradation account for about 20% of global anthropogenic emissions. Strategies and incentives for reduced emissions from deforestation and degradation (REDD) have emerged as one of the most active areas in the international climate change negotiations under the United Nations Framework Convention on Climate Change (UNFCCC). While the current negotiations focus on a REDD mechanism in developing countries, it should be recognized that risks of carbon losses from forests occur in all climate zones and also in industrialized countries. A future climate change agreement would be more effective if it included all carbon losses and gains from land use in all countries and climate zones. The REDD mechanism will be an important step towards reducing emissions from land use change in developing countries, but needs to be followed by steps in other land use systems and regions. A national approach to REDD and significant coverage globally are needed to deal with the risk that deforestation and degradation activities are displaced rather than avoided. Favourable institutional and governance conditions need to be established that guarantee in the long-term a stable incentive and control system for maintaining forest carbon stocks. Ambitious emission reductions from deforestation and forest degradation need sustained financial incentives, which go beyond positive incentives for reduced emissions but also give incentives for sustainable forest management. Current data limitations need-and can be-overcome in the coming years to allow accurate accounting of reduced emissions from deforestation and degradation. A proper application of the conservativeness approach in the REDD context could allow a simplified reporting of emissions from deforestation in a first phase, consistent with the already agreed UNFCCC reporting principles

  11. Development of a high-resolution electron-beam profile monitor using Fresnel zone plates

    International Nuclear Information System (INIS)

    Nakamura, Norio; Sakai, Hiroshi; Muto, Toshiya; Hayano, Hitoshi

    2004-01-01

    We present a high-resolution and real-time beam profile monitor using Fresnel zone plates (FZPs) developed in the KEK-ATF damping ring. The monitor system has an X-ray imaging optics with two FZPs. In this monitor, the synchrotron radiation from the electron beam at the bending magnet is monochromatized by a crystal monochromator and the transverse electron beam image is twenty-times magnified by the two FZPs and detected on an X-ray CCD camera. The expected spatial resolution for the selected photon energy of 3.235 keV is less than 1 μm. With the beam profile monitor, we succeeded in obtaining a clear electron-beam image and measuring the extremely small beam size less than 10 μm. It is greatly expected that the beam profile monitor will be used in high-brilliance light sources and low-emittance accelerators. (author)

  12. Surface charge compensation for a highly charged ion emission microscope

    International Nuclear Information System (INIS)

    McDonald, J.W.; Hamza, A.V.; Newman, M.W.; Holder, J.P.; Schneider, D.H.G.; Schenkel, T.

    2003-01-01

    A surface charge compensation electron flood gun has been added to the Lawrence Livermore National Laboratory (LLNL) highly charged ion (HCI) emission microscope. HCI surface interaction results in a significant charge residue being left on the surface of insulators and semiconductors. This residual charge causes undesirable aberrations in the microscope images and a reduction of the Time-Of-Flight (TOF) mass resolution when studying the surfaces of insulators and semiconductors. The benefits and problems associated with HCI microscopy and recent results of the electron flood gun enhanced HCI microscope are discussed

  13. White emission via electroplex emission from two blue materials.

    Science.gov (United States)

    Li, Junming; Song, Dandan; Zhao, Suling; Zhang, Fujun; Xu, Zheng; Song, Jinglu; Lu, Lifang; Liu, Xiaodong; Wang, Yongsheng

    2010-03-01

    Influences of electric fields on the emission from organic light-emitting diodes (OLEDs) based on poly (N-vinylcarbazole) (PVK); 2, 9-dimethyl-4, 7-diphenyl-1, 10-phenanthroline (BCP); and tris (8-hydroxyquinoline) aluminum (Alq3) were studied. There are three emission peaks at 420 nm, 520 nm, and 620 nm of the device ITO/PEDOT: PSS/PVK/BCP/LiF/Al under different driving voltages. The emissions at 420 nm and 520 nm should be from the exciton emission of PVK and Alq3, respectively. The last emission at 620 nm could be attributed to electroplex emission at the interface between the PVK and BCP layers. A high intensity white emission via electroplex formation was obtained with Commission International d'Eclairage (CIE) coordinates (0.33, 0.34) at 15 V, which is very close to the equienergy white point (0.33, 0.33).

  14. Construction Guide to Next-Generation High-Performance Walls in Climate Zones 3-5 - Part 1: 2x6 Walls

    Energy Technology Data Exchange (ETDEWEB)

    Kochkin, V. [Home Innovation Research Labs, Upper Marlboro, MD (United States); Wiehagen, J. [Home Innovation Research Labs, Upper Marlboro, MD (United States)

    2017-08-31

    Part 1 of this Construction Guide to High-Performance Walls in Climate Zones 3-5 provides time-proven, practical, and cost-effective strategies for constructing durable, energy-efficient walls. It addresses walls constructed with 2x6 wood frame studs, wood structural panel (WSP) exterior sheathing, and a cladding system installed over WSP sheathing in low-rise residential buildings up to three stories high.

  15. Extracting chemical information from high-resolution Kβ X-ray emission spectroscopy

    Science.gov (United States)

    Limandri, S.; Robledo, J.; Tirao, G.

    2018-06-01

    High-resolution X-ray emission spectroscopy allows studying the chemical environment of a wide variety of materials. Chemical information can be obtained by fitting the X-ray spectra and observing the behavior of some spectral features. Spectral changes can also be quantified by means of statistical parameters calculated by considering the spectrum as a probability distribution. Another possibility is to perform statistical multivariate analysis, such as principal component analysis. In this work the performance of these procedures for extracting chemical information in X-ray emission spectroscopy spectra for mixtures of Mn2+ and Mn4+ oxides are studied. A detail analysis of the parameters obtained, as well as the associated uncertainties is shown. The methodologies are also applied for Mn oxidation state characterization of double perovskite oxides Ba1+xLa1-xMnSbO6 (with 0 ≤ x ≤ 0.7). The results show that statistical parameters and multivariate analysis are the most suitable for the analysis of this kind of spectra.

  16. Linking carbon and hydrologic fluxes in the critical zone: Observations from high-frequency monitoring of a weathered bedrock vadose zone

    Science.gov (United States)

    Tune, A. K.; Druhan, J. L.; Wang, J.; Cargill, S.; Murphy, C.; Rempe, D. M.

    2017-12-01

    A principle challenge in quantifying feedbacks between continental weathering and atmospheric CO2 is to improve understanding of how biogeochemical processes in the critical zone influence the distribution and mobility of organic and inorganic carbon. In particular, in landscapes characterized by thin soils and heterogeneous weathered and fractured bedrock, little data exist to inform and constrain predictive models for carbon dynamics. Here, we present the results of an intensive water and gas sampling campaign across an 18 m thick, variably saturated argillite weathering profile in the Eel River CZO. We monitor water content in situ and regularly collect samples of freely-draining water, tightly-held water, and gas through wet and dry seasons using a novel Vadose-zone Monitoring System (VMS) consisting of sensors and samplers distributed across a 20 m long inclined borehole. This novel approach facilitates the interception of gas and water during transport across the entire variably saturated weathering profile. The data demonstrate that seasonal changes in saturation control the vertical distribution and mobility of carbon in the fractured critical zone. Concentrations of gaseous CO2, O2, and dissolved organic and inorganic carbon fluctuate significantly and repeatably with seasonal additions of water infiltrating the weathered bedrock. A persistent vertical structure in the concentrations of dissolved phases and gas concentrations broadly corresponds to depths associated with unsaturated, seasonally saturated, and chronically saturated zones. Associated variations in the vertical structure of mineralogy and elemental composition, including solid phase organic carbon content, are observed in core obtained during drilling. Together, our observations indicate significant respiration of organic carbon at depths greater than the base of the soil, and thus motivate further investigation of the role of heterogeneous weathered, bedrock environments, which are needed to

  17. 78 FR 27033 - Safety Zone; High Water Conditions; Illinois River

    Science.gov (United States)

    2013-05-09

    ... Children from Environmental Health Risks and Safety Risks. This rule is not an economically significant rule and would not create an environmental risk to health or risk to safety that might... the Captain of the Port Lake Michigan. The safety zone has been effective and enforced since April 18...

  18. Wildland fire emissions, carbon, and climate: U.S. emissions inventories

    Science.gov (United States)

    Narasimhan K. Larkin; Sean M. Raffuse; Tara M. Strand

    2014-01-01

    Emissions from wildland fire are both highly variable and highly uncertain over a wide range of temporal and spatial scales. Wildland fire emissions change considerably due to fluctuations from year to year with overall fire season severity, from season to season as different regions pass in and out of wildfire and prescribed fire periods, and from day to day as...

  19. Dual-zone boiling process

    International Nuclear Information System (INIS)

    Bennett, D.L.; Schwarz, A.; Thorogood, R.M.

    1987-01-01

    This patent describes a process for boiling flowing liquids in a heat exchanger wherein the flowing liquids is heated in a single heat exchanger to vaporize the liquid. The improvement described here comprises: (a) passing the boiling flowing liquid through a first heat transfer zone of the heat exchanger comprising a surface with a high-convective-heat-transfer characteristic and a higher pressure drop characteristic; and then (b) passing the boiling flowing liquid through a second heat transfer zone of the heat exchanger comprising an essentially open channel with only minor obstructions by secondary surfaces, with an enhanced nucleate boiling heat transfer surface and a lower pressure drop characteristic

  20. Comparing exposure zones by different exposure metrics using statistical parameters: contrast and precision.

    Science.gov (United States)

    Park, Ji Young; Ramachandran, Gurumurthy; Raynor, Peter C; Eberly, Lynn E; Olson, Greg

    2010-10-01

    Recently, the appropriateness of using the 'mass concentration' metric for ultrafine particles has been questioned and surface area (SA) or number concentration metrics has been proposed as alternatives. To assess the abilities of various exposure metrics to distinguish between different exposure zones in workplaces with nanoparticle aerosols, exposure concentrations were measured in preassigned 'high-' and 'low-'exposure zones in a restaurant, an aluminum die-casting factory, and a diesel engine laboratory using SA, number, and mass concentration metrics. Predetermined exposure classifications were compared by each metric using statistical parameters and concentration ratios that were calculated from the different exposure concentrations. In the restaurant, SA and fine particle number concentrations showed significant differences between the high- and low-exposure zones and they had higher contrast (the ratio of between-zone variance to the sum of the between-zone and within-zone variances) than mass concentrations. Mass concentrations did not show significant differences. In the die cast facility, concentrations of all metrics were significantly greater in the high zone than in the low zone. SA and fine particle number concentrations showed larger concentration ratios between the high and low zones and higher contrast than mass concentrations. None of the metrics were significantly different between the high- and low-exposure zones in the diesel engine laboratory. The SA and fine particle number concentrations appeared to be better at differentiating exposure zones and finding the particle generation sources in workplaces generating nanoparticles. Because the choice of an exposure metric has significant implications for epidemiologic studies and industrial hygiene practice, a multimetric sampling approach is recommended for nanoparticle exposure assessment.