WorldWideScience

Sample records for high economic removal

  1. Economic Analysis of Installing Fixed and Removable Insulation for Pipe Wall Thinning Management

    Energy Technology Data Exchange (ETDEWEB)

    Hwang, Kyeongmo; Yun, Hun [KEPCO E and C, Gimcheon (Korea, Republic of)

    2016-12-15

    To perform ultrasonic testing (UT) thickness measurement of the secondary side piping installed in nuclear power plants, the insulation for preventing heat loss should be removed. The type of insulation can be divided into fixed and removable insulation. Fixed and removable insulation have their own strengths and weaknesses. Removable insulation has been installed in the components susceptible to wall thinning caused by FAC and erosion from Shin-Kori unit 1, which commenced its commercial operation in 2011. In this paper, the number of repeated inspections of components and the number of replacements of fixed insulation were estimated and a more economical way was identified based on the manufacturing and installation costs for fixed and removable insulation.

  2. Economic assessment of biogas-to-electricity generation system with H2S removal by activated carbon in small pig farm

    International Nuclear Information System (INIS)

    Pipatmanomai, Suneerat; Kaewluan, Sommas; Vitidsant, Tharapong

    2009-01-01

    This study was conducted to assess the economic feasibility of electricity generation from biogas in small pig farms with and without the H 2 S removal prior to biogas utilisation. The 2% potassium iodide (KI) impregnated activated carbon selected as H 2 S adsorbent was introduced to a biogas-to-electricity generation system in a small pig farm in Thailand as a case study. With the average inlet H 2 S concentration of about 2400 ppm to the adsorption unit, the H 2 S removal efficiency could reach 100% with the adsorption capacity of 0.062 kg of H 2 S/kg of adsorbent. Under the reference scenario (i.e., 45% subsidy on digester installation and fixed electricity price at 0.06 Euro/kWh) and based on an assumption that the biogas was fully utilised for electricity generation in the system, the payback period for the system without H 2 S removal was about 4 years. With H 2 S removal, the payback period was within the economic life of digester but almost twice that of the case without H 2 S removal. The impact of electricity price could be clearly seen for the case of treated biogas. At the electricity price fixed at 0.07 Euro/kWh, the payback period for the case of treated biogas was reduced to about 5.5 years, with a trend to decrease at higher electricity prices. For both treated and untreated biogas, the governmental subsidy was the important factor determining the economics of the biogas-to-electricity systems. Without subsidy, the payback period increased to almost 7 years and about 11 years for the case of untreated and treated biogas, respectively, at the reference electricity price. Although the H 2 S removal added high operation cost to the system, it is still highly recommended not only for preventing engine corrosion but also for the environment benefit in which air pollution by H 2 S/SO 2 emission and impact on human health could be potentially reduced. (author)

  3. Removal of trace organics from water by pervaporation : a technical and economic analysis

    NARCIS (Netherlands)

    Nijhuis, Herman Henk

    1990-01-01

    Volatile organic hydrocarbons in ground water, surface water or waste water are a continuous threat to the public health. Often traditional purification techniques cannot be applied to remove these components from aqueous solutions. In this thesis the technical and economic feasibility of

  4. The Economics of Carbon Dioxide Removal: The Case against Free Disposal

    Science.gov (United States)

    Keller, D. P.; Rickels, W.; Quaas, M.; Oschlies, A.; Reith, F.

    2016-12-01

    Facing the challenge to keep the average global temperature increase below 2°C and to limit long-term climate change, removing carbon dioxide from the atmosphere (Carbon Dioxide Removal, CDR) and disposing of it in non-atmospheric carbon reservoirs is becoming increasingly necessary. The social cost of removing carbon into the terrestrial biosphere (e.g. by afforestation) or the ocean (e.g. by spreading olivine in coastal areas) arises from carbon-cycle feedbacks and saturation effects. Yet they are ignored in existing economic studies on CDR. Neglecting non-atmospheric social cost results in inconsistent estimates with regard to the share and timing of CDR measures in climate policy. Here, we use an intermediate-complexity earth system model, the University of Victoria (UVic) model, to calibrate a dynamic economic model, capturing the temperature feedback and saturation effect of terrestrial carbon uptake and the saturation effect of oceanic carbon uptake to obtain an improved understanding of the net social carbon value of terrestrial and oceanic CDR. We show that planning horizons beyond the year 2100 are required to properly reflect long-term scarcity issues of non-atmospheric carbon reservoirs in current carbon prices and that neglecting non-atmospheric social cost results in too low abatement efforts and in turn in too large and earlier application of CDR measures than if applied optimally. The figure shows the carbon prices for the different carbon reservoirs in the year 2100 in dependence of the planning horizon (for a climate policy aiming to limit global mean temperature increase to 2°C). The difference between the atmospheric and the non-atmospheric carbon prices indicates the benefits of the different CDR options.

  5. Finnish Highly Skilled Migrants and the European Economic Crisis

    Directory of Open Access Journals (Sweden)

    Koikkalainen Saara

    2017-10-01

    Full Text Available Europe is home to a globally unique area where the barriers of transnational migration have been largely removed. This article focuses on Finnish highly skilled, intra-European migrants and their labour market situation immediately following the economic crisis of 2008. Based on two consecutive online surveys (carried out in spring 2008 and summer 2010 of tertiary educated Finns living in other EU countries, the article examines the effects of the global economic downturn on the careers of these highly skilled migrants. Only 16 per cent of the respondents report that their labour market situation had worsened. A higher percentage (24% felt that their situation had improved and the majority (54% had either experienced no change in their situation or stated that their reasons for changing jobs or moving had nothing to do with the crisis. The article concludes that these migrants were protected from the full force of the crisis by their high human capital, flexibility of alternating between studying and work, employment in international workplaces and their intra-European migrant status.

  6. Techno-economical optimization of Reactive Blue 19 removal by combined electrocoagulation/coagulation process through MOPSO using RSM and ANFIS models.

    Science.gov (United States)

    Taheri, M; Alavi Moghaddam, M R; Arami, M

    2013-10-15

    In this research, Response Surface Methodology (RSM) and Adaptive Neuro Fuzzy Inference System (ANFIS) models were applied for optimization of Reactive Blue 19 removal using combined electrocoagulation/coagulation process through Multi-Objective Particle Swarm Optimization (MOPSO). By applying RSM, the effects of five independent parameters including applied current, reaction time, initial dye concentration, initial pH and dosage of Poly Aluminum Chloride were studied. According to the RSM results, all the independent parameters are equally important in dye removal efficiency. In addition, ANFIS was applied for dye removal efficiency and operating costs modeling. High R(2) values (≥85%) indicate that the predictions of RSM and ANFIS models are acceptable for both responses. ANFIS was also used in MOPSO for finding the best techno-economical Reactive Blue 19 elimination conditions according to RSM design. Through MOPSO and the selected ANFIS model, Minimum and maximum values of 58.27% and 99.67% dye removal efficiencies were obtained, respectively. Copyright © 2013 Elsevier Ltd. All rights reserved.

  7. Use of financial and economic analyses by federal forest managers for woody biomass removal

    Science.gov (United States)

    Todd A. Morgan; Jason P. Brandt; John D. Baldridge; Dan R. Loeffler

    2011-01-01

    This study was sponsored by the Joint Fire Science Program to understand and enhance the ability of federal land managers to address financial and economic (F&E) aspects of woody biomass removal as a component of fire hazard reduction. Focus groups were conducted with nearly 100 federal land managers throughout the western United States. Several issues and...

  8. DEVELOPMENT OF DISPOSABLE SORBENTS FOR CHLORIDE REMOVAL FROM HIGH TEMPERATURE COAL-DERIVED GASES

    Energy Technology Data Exchange (ETDEWEB)

    Gopala Krishnan; Raghubir Gupta

    1999-09-01

    Advanced integrated-gasification combined-cycle (IGCC) and integrated-gasification fuel cell (IGFC) systems require the development of high temperature sorbents for the removal of hydrogen chloride (HCl) vapor to less than 1 parts-per-million (ppm) levels. HCl is a highly reactive, corrosive, and toxic gas which must be removed to meet environmental regulations, to protect power generation equipment, and to minimize deterioration of hot gas desulfurization sorbents. The objective of this program was to develop disposable, alkali-based sorbents capable of reducing HCl vapor levels to less than 1 ppm in the temperature range from 400 to 750 C and pressures in the range from 1 to 20 atm. The primary areas of focus of this program were to investigate different methods of sorbent fabrication, testing their suitability for different reactor configurations, obtaining reaction kinetics data, and conducting a preliminary economic feasibility assessment. This program was a joint effort between SRI International (SRI), Research Triangle Institute (RTI), and General Electric Corporate Research and Development (GE-CRD). SRI, the prime contractor and RTI, a major subcontractor, performed most of the work in this program. Thermochemical calculations indicated that sodium-based sorbents were capable of reducing HCl vapor levels to less than 1 ppm at temperatures up to 650 C, but the regeneration of spent sorbents would require complex process steps. Nahcolite (NaHCO{sub 3}), a naturally-occurring mineral, could be used as an inexpensive sorbent to remove HCl vapor in hot coal gas streams. In the current program, nahcolite powder was used to fabricate pellets suitable for fixed-bed reactors and granules suitable for fluidized-bed reactors. Pilot-scale equipment were used to prepare sorbents in large batches: pellets by disk pelletization and extrusion techniques, and granules by granulation and spray-drying techniques. Bench-scale fixed- and fluidized-bed reactors were assembled at

  9. The Influence of the Ratio of Nitrate to Ammonium Nitrogen on Nitrogen Removal in the Economical Growth of Vegetation in Hybrid Constructed Wetlands

    Directory of Open Access Journals (Sweden)

    Haq Nawaz Abbasi

    2017-03-01

    Full Text Available Growing vegetables economically in the use of constructed wetland for wastewater treatment can play a role in overcoming water and food scarcity. Allium porrum L., Solanum melongena L., Ipomoea aquatica Forsk., and Capsicum annuum L. plants were selected to grow in hybrid constructed wetland (CW under natural conditions. The impact of the ratio of nitrate to ammonium nitrogen on ammonium and nitrate nitrogen removal and on total nitrogen were studied in wastewater. Constructed wetland planted with Ipomoea aquatica Forsk. and Solanum melongena L. showed higher removal efficiency for ammonium nitrogen under higher ammonium concentration, whereas Allium porrum L.-planted CW showed higher nitrate nitrogen removal when NO3–N concentration was high in wastewater. Capsicum annuum L.-planted CW showed little efficiency for both nitrogen sources compared to other vegetables.

  10. Linking phytoremediated pollutant removal to biomass economic opportunities

    International Nuclear Information System (INIS)

    Licht, Louis A.; Isebrands, J.G.

    2005-01-01

    Phytoremediation (phyto) strategies employ trees, shrubs, and/or grasses for treating contaminated air, soil, or water. These strategies include buffers, vegetation filters, in situ phytoremediation plantings, and percolation controlling vegetative caps. The design parameter that separates phytoremediation from landscaping is purposefully placing and growing a root-zone reactor volume with predictable pollutant removal performance. This phyto reactor integrates with other engineered systems to cover landfills, treat petrochemical spills in soils, intercept a soluble subsurface plume, and capture non-point surface sediment entrained in urban or field runoff. There are many potential economic opportunities for biomass associated with phytoremediation, including bioenergy and traditional industrial products such as solid wood products and reconstituted products (i.e., paper, chip board, laminated beams, extruded trim). More intangibly, phyto creates environmental benefits such as soil erosion control, carbon sequestration, and wildlife habitat. Phyto also creates socio-economic benefits by diversify regional manufacturing into new products that employs local labor, thus building value-added industry. Alternative crops develop a greater diversity of products from the farmland, making the regional economy less exposed to global commodity crop price fluctuations. Thus, a strategic phyto treatment of non-point agricultural runoff would help diversify land use from annually tilled crops (corn, soybeans, wheat) into perennial, untilled tree crops. A landscape rebuilt using phyto would create diversity represented in business potential, healthier air and water, wildlife habitat, and aesthetics. Moreover, phyto provides local and current pollutant treatment. Such timely treatment of pollutants that would otherwise move to our downstream or downwind neighbors is key to the environmental justice concept. We present four case study summaries to illustrate installed commercial

  11. Linking phytoremediated pollutant removal to biomass economic opportunities

    International Nuclear Information System (INIS)

    Licht, Louis A.; Isebrands, J.G.

    2005-01-01

    Phytoremediation (phyto) strategies employ trees, shrubs, and/or grasses for treating contaminated air, soil, or water. These strategies include buffers, vegetation filters, in situ phytoremediation plantings, and percolation controlling vegetative caps. The design parameter that separates phytoremediation from landscaping is purposefully placing and growing a root-zone reactor volume with predictable pollutant removal performance. This phyto reactor integrates with other engineered systems to cover landfills, treat petrochemical spills in soils, intercept a soluble subsurface plume, and capture non-point surface sediment entrained in urban or field runoff. There are many potential economic opportunities for biomass associated with phytoremediation, including bioenergy and traditional industrial products such as solid wood products and reconstituted products (i.e., paper, chip board, laminated beams, extruded trim). More intangibly, phyto creates environmental benefits such as soil erosion control, carbon sequestration, and wildlife habitat. Phyto also creates socio-economic benefits by diversify regional manufacturing into new products that employs local labor, thus building value-added industry. Alternative crops develop a greater diversity of products from the farmland, making the regional economy less exposed to global commodity crop price fluctuations. Thus, a strategic phyto treatment of non-point agricultural runoff would help diversify land use from annually tilled crops (corn, soybeans, wheat) into perennial, untilled tree crops. A landscape rebuilt using phyto would create diversity represented in business potential, healthier air and water, wildlife habitat, and aesthetics. Moreover, phyto provides local and current pollutant treatment. Such timely treatment of pollutants that would otherwise move to our downstream or downwind neighbors is key to the environmental justice concept. We present four case study summaries to illustrate installed commercial

  12. A simple economic and quantitative method for the removal of uranium from Gogi mine water using powdered red brick

    International Nuclear Information System (INIS)

    Nathan, Usha; Cyriac, Bincy; Hegde, G.N.; Premadas, A.; Rai, A.K.

    2011-01-01

    A simple and economical method for the removal of uranium from Gogi mine water using the powdered red brick as a good adsorbent is discussed. Preliminary studies for the removal of uranium using brick showed encouraging results. Further studies were carried to find the amount and size of brick for the quantitative removal of uranium. The results of these studies showed that 50 g of brick with 10 mesh size was enough to remove uranium quantitatively from 100 ml of mine water containing 1800 μg/L of uranium. However the column studies indicated considerable decrease (∼ 5 g for 100 ml of mine water) in the amount of brick required to remove uranium from 100 ml of mine water

  13. Effects of Problem Based Economics on High School Economics Instruction

    Science.gov (United States)

    Finkelstein, Neal; Hanson, Thomas

    2011-01-01

    The primary purpose of this study is to assess student-level impacts of a problem-based instructional approach to high school economics. The curriculum approach examined here was designed to increase class participation and content knowledge for high school students who are learning economics. This study tests the effectiveness of Problem Based…

  14. High-efficiency SO2 removal in utility FGD systems

    International Nuclear Information System (INIS)

    Phillips, J.L.; Gray, S.; Dekraker, D.

    1995-01-01

    The U.S. Department of Energy (DOE) and the Electric Power Research Institute (EPRI) have contracted with Radian Corporation to conduct full-scale testing, process modeling, and economic evaluations of six existing utility flue gas desulfurization (FGD) systems. The project objective is to evaluate low capital cost upgrades for achieving up to 98% sulfur dioxide (SO 2 ) removal efficiency in a variety of FGD system types. The systems include dual-loop, packed absorbers at Tampa Electric Company's Big Bend Station; cocurrent, packed absorbers at Hoosier Energy's Merom Station; dual-loop absorbers with perforated-plate trays at Southwestern Electric Power Company's Pirkey Station; horizontal spray absorbers at PSI Energy's Gibson Station; venturi scrubbers at Duquesne Light's Elrama Station; and open stray absorbers at New york State Electric and Gas Corporations's (NYSEG's) Kintigh Station. All operate in an inhibited-oxidation mode except the system at Big Bend (forced oxidation), and all use limestone reagent except the Elrama system (Mg-lime). The program was conducted to demonstrate that upgrades such as performance additives and/or mechanical modifications can increase system SO 2 removal at low cost. The cost effectiveness of each upgrade has been evaluated on the basis of test results and/or process model predictions for upgraded performance and utility-specific operating and maintenance costs. Results from this upgraded performance and utility-specific operating and maintenance costs. Results from this program may lead some utilities to use SO 2 removal upgrades as an approach for compliance with phase 2 of Title IV of the Clean Air Act Amendments (CAAA) of 1990. This paper summarizes the results of testing, modeling, and economic evaluations that have been completed since July, 1994

  15. Experiments on aerosol removal by high-pressure water spray

    Energy Technology Data Exchange (ETDEWEB)

    Corno, Ada del, E-mail: delcorno@rse-web.it [RSE, Power Generation Technologies and Materials Dept, via Rubattino 54, I-20134 Milano (Italy); Morandi, Sonia, E-mail: morandi@rse-web.it [RSE, Power Generation Technologies and Materials Dept, via Rubattino 54, I-20134 Milano (Italy); Parozzi, Flavio, E-mail: parozzi@rse-web.it [RSE, Power Generation Technologies and Materials Dept, via Rubattino 54, I-20134 Milano (Italy); Araneo, Lucio, E-mail: lucio.araneo@polimi.it [Politecnico di Milano, Department of Energy, via Lambruschini 4A, I-20156 Milano (Italy); CNR-IENI, via Cozzi 53, I-20125 Milano (Italy); Casella, Francesco, E-mail: francesco2.casella@mail.polimi.it [Politecnico di Milano, Department of Energy, via Lambruschini 4A, I-20156 Milano (Italy)

    2017-01-15

    Highlights: • Experimental research to measure the efficiency of high-pressure sprays in capturing aerosols if applied to a filtered containment venting system in case of severe accident. • Cloud of monodispersed SiO{sub 2} particles with sizes 0.5 or 1.0 μm and initial concentration in the range 2–90 mg/m{sup 3}. • Carried out in a chamber 0.5 × 1.0 m and 1.5 m high, with transparent walls equipped with a high pressure water spray with single nozzle. • Respect to low-pressure sprays, removal efficiency turned out significant: the half-life for 1 μm particles with a removal high-pressure spray system is orders of magnitude shorter than that with a low-pressure sprays system. - Abstract: An experimental research was managed in the framework of the PASSAM European Project to measure the efficiency of high-pressure sprays in capturing aerosols when applied to a filtered containment venting system in case of severe accident. The campaign was carried out in a purposely built facility composed by a scrubbing chamber 0.5 × 1.0 m and 1.5 m high, with transparent walls to permit the complete view of the aerosol removal process, where the aerosol was injected to form a cloud of specific particle concentration. The chamber was equipped with a high pressure water spray system with a single nozzle placed on its top. The test matrix consisted in the combination of water pressure injections, in the range 50–130 bar, on a cloud of monodispersed SiO{sub 2} particles with sizes 0.5 or 1.0 μm and initial concentration ranging between 2 and 99 mg/m{sup 3}. The spray was kept running for 2 min and the efficiency of the removal was evaluated, along the test time, using an optical particle sizer. With respect to low-pressure sprays, the removal efficiency turned out much more significant: the half-life for 1 μm particles with a removal high-pressure spray system is orders of magnitude shorter than that with a low-pressure spray system. The highest removal rate was

  16. Experiments on aerosol removal by high-pressure water spray

    International Nuclear Information System (INIS)

    Corno, Ada del; Morandi, Sonia; Parozzi, Flavio; Araneo, Lucio; Casella, Francesco

    2017-01-01

    Highlights: • Experimental research to measure the efficiency of high-pressure sprays in capturing aerosols if applied to a filtered containment venting system in case of severe accident. • Cloud of monodispersed SiO_2 particles with sizes 0.5 or 1.0 μm and initial concentration in the range 2–90 mg/m"3. • Carried out in a chamber 0.5 × 1.0 m and 1.5 m high, with transparent walls equipped with a high pressure water spray with single nozzle. • Respect to low-pressure sprays, removal efficiency turned out significant: the half-life for 1 μm particles with a removal high-pressure spray system is orders of magnitude shorter than that with a low-pressure sprays system. - Abstract: An experimental research was managed in the framework of the PASSAM European Project to measure the efficiency of high-pressure sprays in capturing aerosols when applied to a filtered containment venting system in case of severe accident. The campaign was carried out in a purposely built facility composed by a scrubbing chamber 0.5 × 1.0 m and 1.5 m high, with transparent walls to permit the complete view of the aerosol removal process, where the aerosol was injected to form a cloud of specific particle concentration. The chamber was equipped with a high pressure water spray system with a single nozzle placed on its top. The test matrix consisted in the combination of water pressure injections, in the range 50–130 bar, on a cloud of monodispersed SiO_2 particles with sizes 0.5 or 1.0 μm and initial concentration ranging between 2 and 99 mg/m"3. The spray was kept running for 2 min and the efficiency of the removal was evaluated, along the test time, using an optical particle sizer. With respect to low-pressure sprays, the removal efficiency turned out much more significant: the half-life for 1 μm particles with a removal high-pressure spray system is orders of magnitude shorter than that with a low-pressure spray system. The highest removal rate was detected with 1

  17. The safety and effectiveness of different methods of earwax removal: a systematic review and economic evaluation.

    Science.gov (United States)

    Clegg, A J; Loveman, E; Gospodarevskaya, E; Harris, P; Bird, A; Bryant, J; Scott, D A; Davidson, P; Little, P; Coppin, R

    2010-06-01

    Build-up of earwax is a common reason for attendance in primary care. Current practice for earwax removal generally involves the use of a softening agent, followed by irrigation of the ear if required. However, the safety and benefits of the different methods of removal are not known for certain. To conduct evidence synthesis of the clinical effectiveness and cost-effectiveness of the interventions currently available for softening and/or removing earwax and any adverse events (AEs) associated with the interventions. Eleven electronic resources were searched from inception to November 2008, including: The Cochrane Library; MEDLINE (OVID), PREMEDLINE In-Process & Other Non-Indexed Citations (OVID), EMBASE (OVID); and CINAHL. Two reviewers screened titles and abstracts for eligibility. Inclusion criteria were applied to the full text or retrieved papers and data were extracted by two reviewers using data extraction forms developed a priori. Any differences were resolved by discussion or by a third reviewer. Study criteria included: interventions - all methods of earwax removal available and combinations of these methods; participants - adults/children presenting requiring earwax removal; outcomes - measures of hearing, adequacy of clearance of wax, quality of life, time to recurrence or further treatment, AEs and measures of cost-effectiveness; design - randomised controlled trials (RCTs) and controlled clinical trials (CCTs) for clinical effectiveness, cohort studies for AEs and cost-effectiveness, and costing studies for cost-effectiveness. For the economic evaluation, a deterministic decision tree model was developed to evaluate three options: (1) the use of softeners followed by irrigation in primary care; (2) softeners followed by self-irrigation; and (3) a 'no treatment' option. Outcomes were assessed in terms of benefits to patients and costs incurred, with costs presented by exploratory cost-utility analysis. Twenty-six clinical trials conducted in primary

  18. The Impact of High School Economics on the College Principles of Economics Course.

    Science.gov (United States)

    Brasfield, David W.

    1993-01-01

    Reports on a study of 1,119 students in introductory college economics courses to determine the impact of high school economics on student achievement. Finds that prior high school economics was positively and significantly related to students grades in both introductory microeconomics and macroeconomics courses. (CFR)

  19. Automatic residue removal for high-NA extreme illumination

    Science.gov (United States)

    Moon, James; Nam, Byong-Sub; Jeong, Joo-Hong; Kong, Dong-Ho; Nam, Byung-Ho; Yim, Dong Gyu

    2007-10-01

    An epidemic for smaller node has been that, as the device architecture shrinks, lithography process requires high Numerical Aperture (NA), and extreme illumination system. This, in turn, creates many lithography problems such as low lithography process margin (Depth of Focus, Exposure Latitude), unstable Critical Dimension (CD) uniformity and restricted guideline for device design rule and so on. Especially for high NA, extreme illumination such as immersion illumination systems, above all the related problems, restricted design rule due to forbidden pitch is critical and crucial issue. This forbidden pitch is composed of numerous optical effects but majority of these forbidden pitch compose of photo resist residue and these residue must be removed to relieve some room for already tight design rule. In this study, we propose automated algorithm to remove photo resist residue due to high NA and extreme illumination condition. This algorithm automatically self assembles assist patterns based on the original design layout, therefore insuring the safety and simplicity of the generated assist pattern to the original design and removes any resist residue created by extreme illumination condition. Also we tested our automated algorithm on full chip FLASH memory device and showed the residue removal effect by using commercial verification tools as well as on actual test wafer.

  20. Removal of high-molecular weight polycyclic aromatic hydrocarbons

    Directory of Open Access Journals (Sweden)

    Ulrich Vasconcelos

    2011-01-01

    Full Text Available Alternatives for the removal of high-molecular weight polycyclic aromatic hydrocarbons (HWM-PAH from soil were tested by adding fertilizer or glycerol, as well as the combination of both. Experiments were carried out for 60 days in reactors containing a HWM-PAH-contaminated soil (8030 μg kg-1, accompanied by pH monitoring, humidity control and quantification of total heterotrophic bacteria and total fungus. Fertilizer addition removed 41.6% of HWM-PAH. Fertilizer and glycerol in combination removed 46.2%. When glycerol was added individually, degradation reached 50.4%. Glycerol also promoted the increase of degradation rate during the first 30 days suggesting the HMW-PAH removal occurred through cometabolic pathways.

  1. High-efficiency SO{sub 2} removal in utility FGD systems

    Energy Technology Data Exchange (ETDEWEB)

    Phillips, J.L.; Gray, S.; Dekraker, D. [Radian Corporation, Austin, TX (United States)] [and others

    1995-11-01

    The U.S. Department of Energy (DOE) and the Electric Power Research Institute (EPRI) have contracted with Radian Corporation to conduct full-scale testing, process modeling, and economic evaluations of six existing utility flue gas desulfurization (FGD) systems. The project objective is to evaluate low capital cost upgrades for achieving up to 98% sulfur dioxide (SO{sub 2}) removal efficiency in a variety of FGD system types. The systems include dual-loop, packed absorbers at Tampa Electric Company`s Big Bend Station; cocurrent, packed absorbers at Hoosier Energy`s Merom Station; dual-loop absorbers with perforated-plate trays at Southwestern Electric Power Company`s Pirkey Station; horizontal spray absorbers at PSI Energy`s Gibson Station; venturi scrubbers at Duquesne Light`s Elrama Station; and open stray absorbers at New york State Electric and Gas Corporations`s (NYSEG`s) Kintigh Station. All operate in an inhibited-oxidation mode except the system at Big Bend (forced oxidation), and all use limestone reagent except the Elrama system (Mg-lime). The program was conducted to demonstrate that upgrades such as performance additives and/or mechanical modifications can increase system SO{sub 2} removal at low cost. The cost effectiveness of each upgrade has been evaluated on the basis of test results and/or process model predictions for upgraded performance and utility-specific operating and maintenance costs. Results from this upgraded performance and utility-specific operating and maintenance costs. Results from this program may lead some utilities to use SO{sub 2} removal upgrades as an approach for compliance with phase 2 of Title IV of the Clean Air Act Amendments (CAAA) of 1990. This paper summarizes the results of testing, modeling, and economic evaluations that have been completed since July, 1994.

  2. The economics of fishing the high seas.

    Science.gov (United States)

    Sala, Enric; Mayorga, Juan; Costello, Christopher; Kroodsma, David; Palomares, Maria L D; Pauly, Daniel; Sumaila, U Rashid; Zeller, Dirk

    2018-06-01

    While the ecological impacts of fishing the waters beyond national jurisdiction (the "high seas") have been widely studied, the economic rationale is more difficult to ascertain because of scarce data on the costs and revenues of the fleets that fish there. Newly compiled satellite data and machine learning now allow us to track individual fishing vessels on the high seas in near real time. These technological advances help us quantify high-seas fishing effort, costs, and benefits, and assess whether, where, and when high-seas fishing makes economic sense. We characterize the global high-seas fishing fleet and report the economic benefits of fishing the high seas globally, nationally, and at the scale of individual fleets. Our results suggest that fishing at the current scale is enabled by large government subsidies, without which as much as 54% of the present high-seas fishing grounds would be unprofitable at current fishing rates. The patterns of fishing profitability vary widely between countries, types of fishing, and distance to port. Deep-sea bottom trawling often produces net economic benefits only thanks to subsidies, and much fishing by the world's largest fishing fleets would largely be unprofitable without subsidies and low labor costs. These results support recent calls for subsidy and fishery management reforms on the high seas.

  3. Decision Document for Heat Removal from High-Level Waste Tanks

    International Nuclear Information System (INIS)

    WILLIS, W.L.

    2000-01-01

    This document establishes the combination of design and operational configurations that will be used to provide heat removal from high-level waste tanks during Phase 1 waste feed delivery to prevent the waste temperature from exceeding tank safety requirement limits. The chosen method--to use the primary and annulus ventilation systems to remove heat from the high-level waste tanks--is documented herein

  4. Techno-economic Analysis of Acid Gas Removal and Liquefaction for Pressurized LNG

    Science.gov (United States)

    Lee, S. H.; Seo, Y. K.; Chang, D. J.

    2018-05-01

    This study estimated the life cycle cost (LCC) of an acid gas removal and a liquefaction processes for Pressurized LNG (PLNG) production and compared the results with the cost of normal LNG production. PLNG is pressurized LNG that is liquefied at a higher pressure and temperature than normal LNG. Due to the high temperature, the energy for liquefaction is reduced. The allowable CO2 concentration in PLNG is increased up to 3 mol% when the product pressure 25 bar. An amine process with 35 wt% of diethanolamine (DEA) aqueous solution and a nitrogen expansion cycle were selected for the acid gas removal and the liquefaction processes, respectively. Two types of CO2 concentration in the feed gas were investigated to analyze their impacts on the acid gas removal unit. When the CO2 concentration was 5 mol%, the acid gas removal unit was required for both LNG and PLNG production. However, the acid gas removal unit was not necessary in PLNG when the concentration was 0.5 mol% and the pressure was higher than 15 bar. The results showed that the LCC of PLNG was reduced by almost 35% relative to that of LNG when the PLNG pressure was higher than 15 bar.

  5. Economic and health implications of routine CBCT examination before surgical removal of the mandibular third molar in the Danish population

    DEFF Research Database (Denmark)

    Petersen, L B; Rose Olsen, Kim; Matzen, L H

    2015-01-01

    representative dental clinics in the regions of Denmark were visited by two observers, who registered the total number of patients in each clinic, the number of removed mandibular third molars from patients' files together with the age and gender of these patients. The data were collected from 2008 to 2014......OBJECTIVES: This epidemiological study aimed to analyse economical and societal consequences in Denmark if CBCT is used routinely as a diagnostic method before removal of the mandibular third molar. Furthermore, the aim was to calculate the excess cancer incidence from this practice. METHODS: 17....... The total number of removed mandibular third molars in Denmark each year was derived from the collected data and information on patients' contacts with dentists from Statistics Denmark as a sum of contributions from each region. The contribution of a region was obtained as the number of removed mandibular...

  6. Iron and manganese removal from drinking water

    Directory of Open Access Journals (Sweden)

    Daniela-Elena Pascu

    2016-04-01

    Full Text Available The purpose of the present study is to find a suitable method for removal of iron and manganese from ground water, considering bothlocal economical and environmental aspects. Ground water is a highly important source of drinking water in Romania. Ground water is naturally pure from bacteria at a 25 m depth or more. However, solved metals may occur and if the levels are too high, the water is not drinkable. Different processes, such as electrochemical and combined electrochemical-adsorption methods have been applied to determine metals content in accordance to reports of National Water Agency from Romania (ANAR. Every water source contains dissolved or particulate compounds. The concentrations of these compounds can affect health, productivity, compliance requirements, or serviceability and cannot be economically removed by conventional filtration means. In this study, we made a comparison between the electrochemical and adsorption methods (using membranes. Both methods have been used to evaluate the efficiency of iron and manganese removal at various times and temperatures. We used two membrane types: composite and cellulose, respectively. Different approaches, including lowering the initial current density and increasing the initial pH were applied. Reaction kinetics was achieved using mathematical models: Jura and Temkin.

  7. Highly heat removing radiation shielding material

    International Nuclear Information System (INIS)

    Asano, Norio; Hozumi, Masahiro.

    1990-01-01

    Organic materials, inorganic materials or metals having excellent radiation shielding performance are impregnated into expanded metal materials, such as Al, Cu or Mg, having high heat conductivity. Further, the porosity of the expanded metals and combination of the expanded metals and the materials to be impregnated are changed depending on the purpose. Further, a plurality of shielding materials are impregnated into the expanded metal of the same kind, to constitute shielding materials. In such shielding materials, impregnated materials provide shielding performance against radiation rays such as neutrons and gamma rays, the expanded metals provide heat removing performance respectively and they act as shielding materials having heat removing performance as a whole. Accordingly, problems of non-informity and discontinuity in the prior art can be dissolved be provide materials having flexibility in view of fabrication work. (T.M.)

  8. Techno-economic analysis for incorporating a liquid-liquid extraction system to remove acetic acid into a proposed commercial scale biorefinery.

    Science.gov (United States)

    Aghazadeh, Mahdieh; Engelberth, Abigail S

    2016-07-08

    Mitigating the effect of fermentation inhibitors in bioethanol plants can have a great positive impact on the economy of this industry. Liquid-liquid extraction (LLE) using ethyl acetate is able to remove fermentation inhibitors-chiefly, acetic acid-from an aqueous solution used to produce bioethanol. The fermentation broth resulting from LLE has higher performance for ethanol yield and its production rate. Previous techno-economic analyses focused on second-generation biofuel production did not address the impact of removing the fermentation inhibitors on the economic performance of the biorefinery. A comprehensive analysis of applying a separation system to mitigate the fermentation inhibition effect and to provide an analysis on the economic impact of removal of acetic acid from corn stover hydrolysate on the overall revenue of the biorefinery is necessary. This study examines the pros and cons associated with implementing LLE column along with the solvent recovery system into a commercial scale bioethanol plant. Using details from the NREL-developed model of corn stover biorefinery, the capital costs associated with the equipment and the operating cost for the use of solvent were estimated and the results were compared with the profit gain due to higher ethanol production. Results indicate that the additional capital will add 1% to the total capital and manufacturing cost will increase by 5.9%. The benefit arises from the higher ethanol production rate and yield as a consequence of inhibitor extraction and results in a $0.35 per gallon reduction in the minimum ethanol selling price (MESP). © 2016 American Institute of Chemical Engineers Biotechnol. Prog., 32:971-977, 2016. © 2016 American Institute of Chemical Engineers.

  9. [Acrylic resin removable partial dentures].

    Science.gov (United States)

    de Baat, C; Witter, D J; Creugers, N H J

    2011-01-01

    An acrylic resin removable partial denture is distinguished from other types of removable partial dentures by an all-acrylic resin base which is, in principle, solely supported by the edentulous regions of the tooth arch and in the maxilla also by the hard palate. When compared to the other types of removable partial dentures, the acrylic resin removable partial denture has 3 favourable aspects: the economic aspect, its aesthetic quality and the ease with which it can be extended and adjusted. Disadvantages are an increased risk of caries developing, gingivitis, periodontal disease, denture stomatitis, alveolar bone reduction, tooth migration, triggering of the gag reflex and damage to the acrylic resin base. Present-day indications are ofa temporary or palliative nature or are motivated by economic factors. Special varieties of the acrylic resin removable partial denture are the spoon denture, the flexible denture fabricated of non-rigid acrylic resin, and the two-piece sectional denture. Furthermore, acrylic resin removable partial dentures can be supplied with clasps or reinforced by fibers or metal wires.

  10. Economics of coal-based electricity generation

    Energy Technology Data Exchange (ETDEWEB)

    Hemming, D F; Johnston, R; Teper, M

    1979-01-01

    The report deals with base-load electricity generation from coal and compares the economics of four alternative technologies: conventional pulverised-fuel (PF) boiler with steam cycle; atmospheric fluidised-bed (AFB) boiler with steam cycle; pressurised fluidised-bed (PFB) boiler with combined cycle; and integrated air-blown coal gasification with combined cycle systems are compared for both a high sulphur (3.5%) coal with environmental regulations requiring 85% sulphur removal, and for a low sulphur coal without sulphur removal. The results indicate that there is no single clear 'winner' among the advanced technologies. The optimum system depends on coal price, required rate-of-return, sulphur content of the coal, taxation regime etc. (34 refs.) (Available from IEA Coal Research, Economic Assessment Service)

  11. Optimization of high-rate TN removal in a novel constructed wetland integrated with microelectrolysis system treating high-strength digestate supernatant.

    Science.gov (United States)

    Guo, Luchen; He, Keli; Wu, Shubiao; Sun, Hao; Wang, Yanfei; Huang, Xu; Dong, Renjie

    2016-08-01

    The potential of high-rate TN removal in three aerated horizontal subsurface-flow constructed wetlands to treat high-strength anaerobic digestate supernatant was evaluated. Different strategies of intermittent aeration and effluent recirculation were applied to compare their effect on nitrogen depuration performance. Additional glucose supply and iron-activated carbon based post-treatment systems were established and examined, respectively, to further remove nitrate that accumulated in the effluents from aerated wetlands. The results showed that intermittent aeration (1 h on:1 h off) significantly improved nitrification with ammonium removal efficiency of 90% (18.1 g/(m(2)·d)), but limited TN removal efficiency (53%). Even though effluent recirculation (a ratio of 1:1) increased TN removal from 53% to 71%, the effluent nitrate concentration was still high. Additional glucose was used as a post-treatment option and further increased the TN removal to 82%; however, this implementation caused additional organic pollution. Furthermore, the iron-activated carbon system stimulated with a microelectrolysis process achieved greater than 85% effluent nitrate removal and resulted in 86% TN removal. Considering the high TN removal rate, aerated constructed wetlands integrated with a microelectrolysis-driven system show great potential for treating high-strength digestate supernatant. Copyright © 2016 Elsevier Ltd. All rights reserved.

  12. Enhanced removal of radioactive particles by fluorocarbon surfactant solutions

    International Nuclear Information System (INIS)

    Kaiser, R.; Harling, O.K.

    1993-08-01

    The proposed research addressed the application of ESI's particle removal process to the non-destructive decontamination of nuclear equipment. The cleaning medium used in this process is a solution of a high molecular weight fluorocarbon surfactant in an inert perfluorinated liquid which results in enhanced particle removal. The perfluorinated liquids of interest, which are recycled in the process, are nontoxic, nonflammable, and environmentally compatible, and do not present a hazard to the ozone layer. The information obtained in the Phase 1 program indicated that the proposed ESI process is technically effective and economically attractive. The fluorocarbon surfactant solutions used as working media in the ESI process survived exposure of up to 10 Mrad doses of gamma rays, and are considered sufficiently radiation resistant for the proposed process. Ultrasonic cleaning in perfluorinated surfactant solutions was found to be an effective method of removing radioactive iron (Fe 59) oxide particles from contaminated test pieces. Radioactive particles suspended in the process liquids could be quantitatively removed by filtration through a 0.1 um membrane filter. Projected economics indicate a pre-tax pay back time of 1 month for a commercial scale system

  13. Fuel removing method for high burnup fuel and device therefor

    International Nuclear Information System (INIS)

    Terakado, Shogo; Owada, Isao; Kanno, Yoshio; Aizawa, Sakue; Yamahara, Takeshi.

    1993-01-01

    A through hole is perforated at the center of a fuel rod in a cladding tube by a diamond drill in a water vessel. Further, the through hole is enlarged by the diamond drill. A pellet removing tool is attached to a drill chuck instead of the diamond drill. Then, the thin cylindrical fuel pellet remaining on the inner surface of the cladding tube is removed by using a pellet removing tool while applying vibrations. Subsequently, a wire brush having a slightly larger diameter than that of the inner diameter of the cladding tube is attached to the drill chuck and rotated to finish the inner surface, so that a small amount of pellets remained on the inner surface of the cladding tube is removed. Pellet powders in the water vessel are collected and recovered to the water container. This can remove high burnup fuels which are firmly sticked to the cladding tube, without giving thermal or mechanical influences on the cladding tube. (I.N.)

  14. Silica removal in industrial effluents with high silica content and low hardness.

    Science.gov (United States)

    Latour, Isabel; Miranda, Ruben; Blanco, Angeles

    2014-01-01

    High silica content of de-inked paper mill effluents is limiting their regeneration and reuse after membrane treatments such as reverse osmosis (RO). Silica removal during softening processes is a common treatment; however, the effluent from the paper mill studied has a low hardness content, which makes the addition of magnesium compounds necessary to increase silica removal. Two soluble magnesium compounds (MgCl₂∙6H₂O and MgSO₄∙7H₂O) were tested at five dosages (250-1,500 mg/L) and different initial pH values. High removal rates (80-90%) were obtained with both products at the highest pH tested (11.5). With these removal efficiencies, it is possible to work at high RO recoveries (75-85%) without silica scaling. Although pH regulation significantly increased the conductivity of the waters (at pH 11.5 from 2.1 to 3.7-4.0 mS/cm), this could be partially solved by using Ca(OH)₂ instead of NaOH as pH regulator (final conductivity around 3.0 mS/cm). Maximum chemical oxygen demand (COD) removal obtained with caustic soda was lower than with lime (15 vs. 30%). Additionally, the combined use of a polyaluminum coagulant during the softening process was studied; the coagulant, however, did not significantly improve silica removal, obtaining a maximum increase of only 10%.

  15. Iron and manganese removal from drinking water

    OpenAIRE

    Pascu, Daniela-Elena; Neagu (Pascu), Mihaela; Alina Traistaru, Gina; Nechifor, Aurelia Cristina; Raluca Miron, Alexandra

    2016-01-01

    The purpose of the present study is to find a suitable method for removal of iron and manganese from ground water, considering both local economical and environmental aspects. Ground water is a highly important source of drinking water in Romania. Ground water is naturally pure from bacteria at a 25 m depth or more. However, solved metals may occur and if the levels are too high, the water is not drinkable. Different processes, such as electrochemical and combined electrochemical-adsorption m...

  16. Bench scale evaluation and economic assessment of ion exchange resins for the removal of radionuclides from uranium mill tailings effluents

    International Nuclear Information System (INIS)

    Lakshmanan, V.I.; Itzkovitch, I.J.

    1981-07-01

    The removal of <0.45 m radium 226 (soluble) from acid and alkaline mill tailings effluents to meet the Canadian provincial (Ontario and Saskatchewan) objective of <3 pCi/L using ion exchange has been studied. Stirred tank tests were used to screen potential solid ion exchangers for detailed testing in columns. Column tests on selected exchangers were carried out to determine breakthrough curves as a function of column throughput. An economic assessment of the process was carried out. Results obtained indicate that removal of soluble radium 226 to <3 pCi/L by ion exchange is technically feasible. However, if the solid exchangers are to be used on a once through basis the process is prohibitively expensive

  17. Alternatives Generation and Analysis for Heat Removal from High Level Waste Tanks

    International Nuclear Information System (INIS)

    WILLIS, W.L.

    2000-01-01

    This document addresses the preferred combination of design and operational configurations to provide heat removal from high-level waste tanks during Phase 1 waste feed delivery to prevent the waste temperature from exceeding tank safety requirement limits. An interim decision for the preferred method to remove the heat from the high-level waste tanks during waste feed delivery operations is presented herein

  18. Alternatives Generation and Analysis for Heat Removal from High Level Waste Tanks

    Energy Technology Data Exchange (ETDEWEB)

    WILLIS, W.L.

    2000-06-15

    This document addresses the preferred combination of design and operational configurations to provide heat removal from high-level waste tanks during Phase 1 waste feed delivery to prevent the waste temperature from exceeding tank safety requirement limits. An interim decision for the preferred method to remove the heat from the high-level waste tanks during waste feed delivery operations is presented herein.

  19. FERRATE TREATMENT FOR REMOVING CHROMIUM FROM HIGH-LEVEL RADIOACTIVE TANK WASTE

    International Nuclear Information System (INIS)

    Sylvester, Paul; Rutherford, Andy; Gonzalez-Martin, Anuncia; Kim, J.; Rapko, Brian M.; Lumetta, Gregg J.

    2000-01-01

    A method has been developed for removing chromium from alkaline high-level radioactive tank waste. Removing chromium from these wastes is critical in reducing the volume of waste requiring expensive immobilization and deep geologic disposition. The method developed is based on the oxidation of insoluble chromium(III) compounds to soluble chromate using ferrate. The tests conducted with a simulated Hanford tank sludge indicate that the chromium removal with ferrate is more efficient at 5 M NaOH than at 3 M NaOH. Chromium removal increases with increasing Fe(VI)/Cr(III) molar ratio, but the chromium removal tends to level out for Fe(VI)/Cr(III) greater than 10. Increasing temperature leads to better chromium removal, but higher temperatures also led to more rapid ferrate decomposition. Tests with radioactive Hanford tank waste generally confirmed the simulant results. In all cases examined, ferrate enhanced the chromium removal, with a typical removal of around 60-70% of the total chromium present in the washed sludge solids. The ferrate leachate solutions did not contain significant concentrations of transuranic elements, so these solutions could be handled as low-activity waste

  20. Ferrate treatment for removing chromium from high-level radioactive tank waste.

    Science.gov (United States)

    Sylvester, P; Rutherford, L A; Gonzalez-Martin, A; Kim, J; Rapko, B M; Lumetta, G J

    2001-01-01

    A method has been developed for removing chromium from alkaline high-level radioactive tank waste. Removing chromium from these wastes is critical in reducing the volume of waste requiring expensive immobilization and deep geologic disposition. The method developed is based on the oxidation of insoluble chromium(III) compounds to soluble chromate using ferrate. This method could be generally applicable to removing chromium from chromium-contaminated solids, when coupled with a subsequent reduction of the separated chromate back to chromium(III). The tests conducted with a simulated Hanford tank sludge indicate that the chromium removal with ferrate is more efficient at 5 M NaOH than at 3 M NaOH. Chromium removal increases with increasing Fe(VI)/Cr(II) molar ratio, but the chromium removal tends to level out for Fe(VI)/ Cr(III) greaterthan 10. Increasingtemperature leadsto better chromium removal, but higher temperatures also led to more rapid ferrate decomposition. Tests with radioactive Hanford tank waste generally confirmed the simulant results. In all cases examined, ferrate enhanced the chromium removal, with a typical removal of around 60-70% of the total chromium present in the washed sludge solids. The ferrate leachate solutions did not contain significant concentrations of transuranic elements, so these solutions could be disposed as low-activity waste.

  1. Study of possible economical ways of removing radium from drinking water

    International Nuclear Information System (INIS)

    Valentine, R.L.; Splinter, R.C.; Mulholland, T.S.; Baker, J.M.; Nogaj, T.M.

    1988-01-01

    This study was undertaken to determine variables that control the incidental removal of radium that has been observed to occur as a consequence of treatment to remove iron by oxidation--sand filtration. The study also evaluated the possibility of exploiting these factors to provide an inexpensive means of removing radium using existing or modified iron removal facilities. Studies were also conducted to evaluate radium sorption to hydrous manganese oxides and to evaluate the potential of radium sorption to filter sand as a novel removal technology. Results showed that radium sorption to iron and manganese oxides and filter sand appear to be controlled primarily by the presence of calcium and magnesium, which are believed to compete for sorption sites

  2. Advanced High Temperature Reactor Systems and Economic Analysis

    Energy Technology Data Exchange (ETDEWEB)

    Holcomb, David Eugene [ORNL; Peretz, Fred J [ORNL; Qualls, A L [ORNL

    2011-09-01

    The Advanced High Temperature Reactor (AHTR) is a design concept for a large-output [3400 MW(t)] fluoride-salt-cooled high-temperature reactor (FHR). FHRs, by definition, feature low-pressure liquid fluoride salt cooling, coated-particle fuel, a high-temperature power cycle, and fully passive decay heat rejection. The AHTR's large thermal output enables direct comparison of its performance and requirements with other high output reactor concepts. As high-temperature plants, FHRs can support either high-efficiency electricity generation or industrial process heat production. The AHTR analysis presented in this report is limited to the electricity generation mission. FHRs, in principle, have the potential to be low-cost electricity producers while maintaining full passive safety. However, no FHR has been built, and no FHR design has reached the stage of maturity where realistic economic analysis can be performed. The system design effort described in this report represents early steps along the design path toward being able to predict the cost and performance characteristics of the AHTR as well as toward being able to identify the technology developments necessary to build an FHR power plant. While FHRs represent a distinct reactor class, they inherit desirable attributes from other thermal power plants whose characteristics can be studied to provide general guidance on plant configuration, anticipated performance, and costs. Molten salt reactors provide experience on the materials, procedures, and components necessary to use liquid fluoride salts. Liquid metal reactors provide design experience on using low-pressure liquid coolants, passive decay heat removal, and hot refueling. High temperature gas-cooled reactors provide experience with coated particle fuel and graphite components. Light water reactors (LWRs) show the potentials of transparent, high-heat capacity coolants with low chemical reactivity. Modern coal-fired power plants provide design experience

  3. High-rate oil removing scouring agent. Koyubun jokyoyo seirenzai ni tsuite

    Energy Technology Data Exchange (ETDEWEB)

    Ishihara, K.; Sato, Y. (Dai-Ichi Kogyo Seiyaku Co. Ltd., Kyoto (Japan))

    1991-11-01

    Fiber forming, scutching and knitting processes in recent years are performed three to five times faster than in the conventional processes. Associated therewith, oil solutions are taken importantly for their stability and workability, such as smoothing properties, heat resistance and abrasion resistance. On the other hand, difficulty is increasing in removing the oils after scutching and knitting. This paper explains basic rinsing activities required in oil removal, and describes various test characteristics and compatibility of various high-rate oil removing scouring agents. An oil-in-water rinsing mechanism relies upon comprehensive actions of a surfactant in wetting, permeation, emulsified dispersion and solubilization. The most importantly taken among them is the emulsifying action, which largely depends upon its chemical structure. Therefore, for a high-rate oil removing scouring agent, creation of activators is required that make the above basic characteristics and activities compatible for various applications. For example, the above product covers a great variety of kinds for diverse applications, based on non-ionic and anion-based activators. 6 figs., 20 tabs.

  4. Economic integration in the Americas

    OpenAIRE

    Uitdewilligen, G.

    1997-01-01

    This pioneering study shows that economic integration in the Americas is not simply a matter of removing trade barriers. Economic Integration in the Americas addresses the pervasive effects of economic integration on the economy as a whole.

  5. The Treatment of Wealth Distribution by High School Economics Textbooks

    Science.gov (United States)

    Neumann, Richard

    2014-01-01

    This article presents findings from an investigation of the treatment of wealth distribution by high school economics textbooks. The eight leading high school economics texts in the United States were examined.

  6. High-Energy Electron Beam Application to Air Pollutants Removal

    International Nuclear Information System (INIS)

    Ighigeanu, D.; Martin, D.; Manaila, E.; Craciun, G.; Calinescu, I.

    2009-01-01

    The advantage of electron beam (EB) process in pollutants removal is connected to its high efficiency to transfer high amount of energy directly into the matter under treatment. Disadvantage which is mostly related to high investment cost of accelerator may be effectively overcome in future as the result of use accelerator new developments. The potential use of medium to high-energy high power EB accelerators for air pollutants removal is demonstrated in [1]. The lower electrical efficiencies of accelerators with higher energies are partially compensated by the lower electron energy losses in the beam windows. In addition, accelerators with higher electron energies can provide higher beam powers with lower beam currents [1]. The total EB energy losses (backscattering, windows and in the intervening air space) are substantially lower with higher EB incident energy. The useful EB energy is under 50% for 0.5 MeV and about 95% above 3 MeV. In view of these arguments we decided to study the application of high energy EB for air pollutants removal. Two electron beam accelerators are available for our studies: electron linear accelerators ALIN-10 and ALID-7, built in the Electron Accelerator Laboratory, INFLPR, Bucharest, Romania. Both accelerators are of traveling-wave type, operating at a wavelength of 10 cm. They utilize tunable S-band magnetrons, EEV M 5125 type, delivering 2 MW of power in 4 μ pulses. The accelerating structure is a disk-loaded tube operating in the 2 mode. The optimum values of the EB peak current IEB and EB energy EEB to produce maximum output power PEB for a fixed pulse duration EB and repetition frequency fEB are as follows: for ALIN-10: EEB = 6.23 MeV; IEB =75 mA; PEB 164 W (fEB = 100 Hz, EB = 3.5 s) and for ALID-7: EEB 5.5 MeV; IEB = 130 mA; PEB = 670 W (fEB = 250 Hz, EB = 3.75 s). This paper presents a special designed installation, named SDI-1, and several representative results obtained by high energy EB application to SO 2 , NOx and VOCs

  7. Economic valuation of environmental benefits of removing pharmaceutical and personal care products from WWTP effluents by ozonation

    Energy Technology Data Exchange (ETDEWEB)

    Molinos-Senante, M., E-mail: maria.molinos@uv.es [Department of Mathematics for Economy, Universitat de Valencia, Campus dels Tarongers, 46022 Valencia (Spain); Reif, R., E-mail: rreif@icra.cat [Laboratory of Chemical and Environmental Engineering (LEQUIA), Universitat de Girona, Facultat Ciències, Campus Montilivi, 17071 Girona (Spain); Chemical Engineering Department, Universidade de Santiago de Compostela, Rua Lope Gomez de Marzoa s/n, 15782 Santiago de Compostela (Spain); Garrido-Baserba, M., E-mail: mgarrido@icra.cat [Catalan Institute for Water Research, Scientific and Technological Park, H2O Building, Emili Grahit 101, 17003 Girona (Spain); Laboratory of Chemical and Environmental Engineering (LEQUIA), Universitat de Girona, Facultat Ciències, Campus Montilivi, 17071 Girona (Spain); Hernández-Sancho, F., E-mail: francesc.hernandez@uv.es [Department of Applied Economics II, Universitat de Valencia, Campus dels Tarongers, 46022 Valencia (Spain); Omil, F., E-mail: francisco.omil@usc.es [Chemical Engineering Department, Universidade de Santiago de Compostela, Rua Lope Gomez de Marzoa s/n, 15782 Santiago de Compostela (Spain); Poch, M., E-mail: manel@lequia.udg.edu [Catalan Institute for Water Research, Scientific and Technological Park, H2O Building, Emili Grahit 101, 17003 Girona (Spain); Laboratory of Chemical and Environmental Engineering (LEQUIA), Universitat de Girona, Facultat Ciències, Campus Montilivi, 17071 Girona (Spain); Sala-Garrido, R., E-mail: ramon.sala@uv.es [Department of Mathematics for Economy, Universitat de Valencia, Campus dels Tarongers, 46022 Valencia (Spain)

    2013-09-01

    Continuous release of pharmaceutical and personal care products (PPCPs) present in effluents from wastewater treatment plants (WWTPs) is nowadays leading to the adoption of specific measures within the framework of the Directive 2000/60/EC (Water Framework Directive). The ozonation process, normally employed for drinking water production, has also proven its potential to eliminate PPCPs from secondary effluents in spite of their low concentrations. However, there is a significant drawback related with the costs associated with its implementation. This lack of studies is especially pronounced regarding the economic valuation of the environmental benefits associated to avoid the discharge of these pollutants into water bodies. For the first time the shadow prices of 5 PPCPs which are ethynilestradiol, sulfamethoxazole, diclofenac, tonalide and galaxolide from treated effluent using a pilot-scale ozonation reactor have been estimated. From non-sensitive areas their values are − 73.73; − 34.95; − 42.20; − 10.98; and − 8.67 respectively and expressed in €/kg. They represent a proxy to the economic value of the environmental benefits arisen from undischarged pollutants. This paper contributes to value the environmental benefits of implementing post-treatment processes aimed to achieve the quality standards required by the Priority Substances Directive. - Highlights: • Environmental Benefit Analysis of PPCPs • PPCPs' removal depends on their functional group and molecular structures. • Shadow prices as a proxy of the environmental benefits from ozonation process • HHCB and AHTN have the lowest shadow prices. • The greatest environmental benefit is associated with the removal of DCF.

  8. Economic valuation of environmental benefits of removing pharmaceutical and personal care products from WWTP effluents by ozonation

    International Nuclear Information System (INIS)

    Molinos-Senante, M.; Reif, R.; Garrido-Baserba, M.; Hernández-Sancho, F.; Omil, F.; Poch, M.; Sala-Garrido, R.

    2013-01-01

    Continuous release of pharmaceutical and personal care products (PPCPs) present in effluents from wastewater treatment plants (WWTPs) is nowadays leading to the adoption of specific measures within the framework of the Directive 2000/60/EC (Water Framework Directive). The ozonation process, normally employed for drinking water production, has also proven its potential to eliminate PPCPs from secondary effluents in spite of their low concentrations. However, there is a significant drawback related with the costs associated with its implementation. This lack of studies is especially pronounced regarding the economic valuation of the environmental benefits associated to avoid the discharge of these pollutants into water bodies. For the first time the shadow prices of 5 PPCPs which are ethynilestradiol, sulfamethoxazole, diclofenac, tonalide and galaxolide from treated effluent using a pilot-scale ozonation reactor have been estimated. From non-sensitive areas their values are − 73.73; − 34.95; − 42.20; − 10.98; and − 8.67 respectively and expressed in €/kg. They represent a proxy to the economic value of the environmental benefits arisen from undischarged pollutants. This paper contributes to value the environmental benefits of implementing post-treatment processes aimed to achieve the quality standards required by the Priority Substances Directive. - Highlights: • Environmental Benefit Analysis of PPCPs • PPCPs' removal depends on their functional group and molecular structures. • Shadow prices as a proxy of the environmental benefits from ozonation process • HHCB and AHTN have the lowest shadow prices. • The greatest environmental benefit is associated with the removal of DCF

  9. High-temperature radiation-induced removal of gaseous air pollutants

    International Nuclear Information System (INIS)

    Medina Rojas, I.; Thomson, M.J.

    2001-01-01

    This paper explores the use of high-temperature electron beam irradiation to simultaneous remove aromatic hydrocarbons, chlorinated hydrocarbons and nitrogen oxides. Detailed chemical kinetic modeling with validated mechanisms predicts that electron beam irradiation will simultaneously reduce NO with the thermal De-NO x process and oxidize benzene or ethyl chloride over a wide temperature range. Electron beam dosage of 2-10 kGy more than double the width of the temperature window over which the thermal De-NO x process is effective. At these dosages, the benzene and ethyl chloride removal efficiencies can exceed 90% within this temperature window. (author)

  10. Highly efficient removal of arsenic metal ions with high superficial area hollow magnetite nanoparticles synthetized by AACVD method

    Energy Technology Data Exchange (ETDEWEB)

    Monárrez-Cordero, B.; Amézaga-Madrid, P.; Antúnez-Flores, W.; Leyva-Porras, C.; Pizá-Ruiz, P. [Centro de Investigación en Materiales Avanzados S.C., and Laboratorio Nacional de Nanotecnología, Miguel de Cervantes 120, Chihuahua, Chih. C.P. 31109 (Mexico); Miki-Yoshida, M., E-mail: mario.miki@cimav.edu.mx [Centro de Investigación en Materiales Avanzados S.C., and Laboratorio Nacional de Nanotecnología, Miguel de Cervantes 120, Chihuahua, Chih. C.P. 31109 (Mexico)

    2014-02-15

    Highlights: ► Fast and high arsenic removal efficiency, almost 100% in one minute. ► Successful synthesis of high purity magnetite hollow nanoparticles is reported. ► They were synthesized by one step aerosol assisted CVD technique. ► Detailed microstructural characterization by electron microscopy was performed. -- Abstract: New nanotechnology alternatives and methodologies have been developed in order to overcome the limitations of conventional techniques for metal ions removal from water. Currently, the removal of heavy metals requires multiple steps which include the separation and post-treatment of the generated sludge. Usually, this sludge is composed of dangerous environmental pollutants mixed with the material used for removing the metal ion. Thus, the removal of these metals becomes a challenging task. Herein we report the synthesis of magnetite nanoparticles with high specific area by the aerosol assisted chemical vapour deposition method. Deposition temperature were fixed at 450 °C and a mixture of Ar–air were used as a carrier gas, a flow of 1.0 and 0.015 L min{sup −1} were used for Ar and air, respectively. The precursor solution was a dilution of Fe (II) chloride in methanol, with different concentration 0.01, 0.05 and 0.1 mol dm{sup −3}. The crystalline structure of the nanoparticles was characterized by grazing incidence X-ray diffraction. Morphology and microstructure were analyzed by field emission scanning electron microscopy, scanning probe microscopy and transmission electron microscopy. Magnetic properties were evaluated with a vibrating sample magnetometer and specific area was measured by the Brunauer–Emmett–Teller method. To determine the removal efficiency of arsenic ion from water, several tests were carried out at six exposition times 1, 3, 5, 10, 20 and 30 min. Results showed high removal efficiency, more than 99%, in less than 1 min.

  11. Conceptualizing an economically, legally, and politically viable active debris removal option

    Science.gov (United States)

    Emanuelli, M.; Federico, G.; Loughman, J.; Prasad, D.; Chow, T.; Rathnasabapathy, M.

    2014-11-01

    It has become increasingly clear in recent years that the issue of space debris, particularly in low-Earth orbit, can no longer be ignored or simply mitigated. Orbital debris currently threatens safe space flight for both satellites and humans aboard the International Space Station. Additionally, orbital debris might impact Earth upon re-entry, endangering human lives and damaging the environment with toxic materials. In summary, orbital debris seriously jeopardizes the future not only of human presence in space, but also of human safety on Earth. While international efforts to mitigate the current situation and limit the creation of new debris are useful, recent studies predicting debris evolution have indicated that these will not be enough to ensure humanity's access to and use of the near-Earth environment in the long-term. Rather, active debris removal (ADR) must be pursued if we are to continue benefiting from and conducting space activities. While the concept of ADR is not new, it has not yet been implemented. This is not just because of the technical feasibility of such a scheme, but also because of the host of economic, legal/regulatory, and political issues associated with debris remediation. The costs of ADR are not insignificant and, in today's restrictive fiscal climate, are unlikely/to be covered by any single actor. Similarly, ADR concepts bring up many unresolved questions about liability, the protection of proprietary information, safety, and standards. In addition, because of the dual use nature of ADR technologies, any venture will necessarily require political considerations. Despite the many unanswered questions surrounding ADR, it is an endeavor worth pursuing if we are to continue relying on space activities for a variety of critical daily needs and services. Moreover, we cannot ignore the environmental implications that an unsustainable use of space will imply for life on Earth in the long run. This paper aims to explore some of these

  12. Sulfur Removal by Adding Iron During the Digestion Process of High-sulfur Bauxite

    Science.gov (United States)

    Zhanwei, Liu; Hengwei, Yan; Wenhui, Ma; Keqiang, Xie; Dunyong, Li; Licong, Zheng; Pengfei, Li

    2018-04-01

    This paper proposes a novel approach to sulfur removal by adding iron during the digestion process. Iron can react with high-valence sulfur (S2O3 2-, SO3 2-, SO4 2-) to generate S2- at digestion temperature, and then S2- enter red mud in the form of Na3FeS3 to be removed. As iron dosage increases, high-valence sulfur concentration decreases, but the concentration of S2- increases; sulfur digestion rate decreases while sulfur content in red mud markedly increases; the alumina digestion rate, conversely, remains fairly stable. So sulfur can be removed completely by adding iron in digestion process, which provide a theoretical basis for the effective removal of sulfur in alumina production process.

  13. Wise Choices? The Economics Discourse of a High School Economics and Personal Finance Course

    Science.gov (United States)

    Sober, Tamara Leigh

    2017-01-01

    Today's high school students will face a host of economic problems such as the demise of the social safety net, mounting college student debt, and costly health care plans, as stated in the rationale for financial literacy provided by the Council for Economic Education's National Standards for Financial Literacy. These problems are compounded by…

  14. Tetracycline removal during wastewater treatment in high-rate algal ponds

    International Nuclear Information System (INIS)

    Godos, Ignacio de; Muñoz, Raúl; Guieysse, Benoit

    2012-01-01

    Highlights: ► Tetracycline removal was most likely caused by photodegradation and biosorption. ► Tetracycline presence was linked to biomass deflocculation and poor settleability. ► Deflocculation did not impact treatment efficiency. ► Deflocculation may hamper biomass recover during full-scale treatment. - Abstract: With the hypothesis that light supply can impact the removal of veterinary antibiotics during livestock wastewater treatment in high rate algal ponds (HRAPs), this study was undertaken to determine the mechanisms of tetracycline removal in these systems. For this purpose, two HRAPs were fed with synthetic wastewater for 46 days before tetracycline was added at 2 mg L −1 to the influent of one of the reactors (Te-HRAP). From day 62, dissolved tetracycline removal stabilized around 69 ± 1% in the Te-HRAP and evidence from batch assays suggests that this removal was mainly caused by photodegradation and biosorption. Tetracycline addition was followed by the deflocculation of the Te-HRAP biomass but had otherwise no apparent impact on the removal of the chemical oxygen demand (COD) and biomass productivity. The results from the batch assays also suggested that the light-shading and/or pollutant-sequestrating effects of the biomass limited tetracycline removal in the pond. For the first time, these results demonstrate that the shallow geometry of HRAPs is advantageous to support the photodegradation of antibiotics during wastewater biological treatment but that the presence of these pollutants could hamper biomass recovery. These findings have significant implications for algal-based environmental biotechnologies and must be confirmed under field conditions.

  15. Ozonation of hospital raw wastewaters for cytostatic compounds removal. Kinetic modelling and economic assessment of the process

    Energy Technology Data Exchange (ETDEWEB)

    Ferre-Aracil, J. [Universitat Politècnica de València – EPSA, Department of Chemical and Nuclear Engineering. Institute for Industrial, Radiophysical and Environmental Safety (ISIRYM), Pl. Ferrandiz i Carbonell, 03801 Alcoi, Alicante (Spain); Valcárcel, Y. [Environmental Health and Ecotoxicology Research Group, Universidad Rey Juan Carlos, Avd. Atenas s/n, Móstoles, 28922 Alcorcón (Spain); Negreira, N.; López de Alda, M. [Water and Soil Quality Research Group, Department of Environmental Chemistry, Institute of Environmental Assessment and Water Research (IDAEA-CSIC), C/ Jordi Girona 18-26, 08034 Barcelona (Spain); Barceló, D. [Water and Soil Quality Research Group, Department of Environmental Chemistry, Institute of Environmental Assessment and Water Research (IDAEA-CSIC), C/ Jordi Girona 18-26, 08034 Barcelona (Spain); Catalan Institute for Water Research (ICRA), H2O Building, Scientific and Technological Park of the University of Girona, Emili Grahit 101, 17003 Girona (Spain); Cardona, S.C. [Universitat Politècnica de València – EPSA, Department of Chemical and Nuclear Engineering. Institute for Industrial, Radiophysical and Environmental Safety (ISIRYM), Pl. Ferrandiz i Carbonell, 03801 Alcoi, Alicante (Spain); Navarro-Laboulais, J., E-mail: jnavarla@iqn.upv.es [Universitat Politècnica de València – EPSA, Department of Chemical and Nuclear Engineering. Institute for Industrial, Radiophysical and Environmental Safety (ISIRYM), Pl. Ferrandiz i Carbonell, 03801 Alcoi, Alicante (Spain)

    2016-06-15

    The kinetics of the ozone consumption for the pretreatment of hospital wastewater has been analysed in order to determine the reaction rate coefficients between the ozone and the readily oxidisabled organic matter and cytostatic compounds. The wastewater from a medium size hospital was treated with ozone and peroxone methodologies, varying the ozone concentration, the reaction time and the hydrogen peroxide doses. The analysis shows that there are four cytostatic compounds, i.e. irinotecan, ifosfamide, cyclophosphamide and capecitabine, detected in the wastewaters and they are completely removed with reasonably short times after the ozone treatment. Considering the reactor geometry, the gas hydrodynamics, the mass transfer of ozone from gas to liquid and the reaction of all oxidisable compounds of the wastewater it is possible to determine the chemical ozone demand, COzD, of the sample as 256 mg O{sub 3} L{sup −1} and the kinetic rate coefficient with the dissolved organic matter as 8.4 M{sup −1} s{sup −1}. The kinetic rate coefficient between the ozone and the cyclophosphamide is in the order of 34.7 M{sup −1} s{sup −1} and higher for the other cytostatics. The direct economic cost of the treatment was evaluated considering this reaction kinetics and it is below 0.3 €/m{sup 3} under given circumstances. - Highlights: • 17 cytostatic compounds were analysed and 4 detected by SPE-LC/MS-MS. • The ozonation is 100% effective on the removal of the detected cytostatics. • The kinetics of cytostatic ozonation reaction is modeled by competitive kinetics. • The economic cost of the treatment of hospital wastewater was assessed.

  16. Ozonation of hospital raw wastewaters for cytostatic compounds removal. Kinetic modelling and economic assessment of the process

    International Nuclear Information System (INIS)

    Ferre-Aracil, J.; Valcárcel, Y.; Negreira, N.; López de Alda, M.; Barceló, D.; Cardona, S.C.; Navarro-Laboulais, J.

    2016-01-01

    The kinetics of the ozone consumption for the pretreatment of hospital wastewater has been analysed in order to determine the reaction rate coefficients between the ozone and the readily oxidisabled organic matter and cytostatic compounds. The wastewater from a medium size hospital was treated with ozone and peroxone methodologies, varying the ozone concentration, the reaction time and the hydrogen peroxide doses. The analysis shows that there are four cytostatic compounds, i.e. irinotecan, ifosfamide, cyclophosphamide and capecitabine, detected in the wastewaters and they are completely removed with reasonably short times after the ozone treatment. Considering the reactor geometry, the gas hydrodynamics, the mass transfer of ozone from gas to liquid and the reaction of all oxidisable compounds of the wastewater it is possible to determine the chemical ozone demand, COzD, of the sample as 256 mg O 3 L −1 and the kinetic rate coefficient with the dissolved organic matter as 8.4 M −1 s −1 . The kinetic rate coefficient between the ozone and the cyclophosphamide is in the order of 34.7 M −1 s −1 and higher for the other cytostatics. The direct economic cost of the treatment was evaluated considering this reaction kinetics and it is below 0.3 €/m 3 under given circumstances. - Highlights: • 17 cytostatic compounds were analysed and 4 detected by SPE-LC/MS-MS. • The ozonation is 100% effective on the removal of the detected cytostatics. • The kinetics of cytostatic ozonation reaction is modeled by competitive kinetics. • The economic cost of the treatment of hospital wastewater was assessed.

  17. Using economic instruments to develop effective management of invasive species: insights from a bioeconomic model.

    Science.gov (United States)

    McDermott, Shana M; Irwin, Rebecca E; Taylor, Brad W

    2013-07-01

    Economic growth is recognized as an important factor associated with species invasions. Consequently, there is increasing need to develop solutions that combine economics and ecology to inform invasive species management. We developed a model combining economic, ecological, and sociological factors to assess the degree to which economic policies can be used to control invasive plants. Because invasive plants often spread across numerous properties, we explored whether property owners should manage invaders cooperatively as a group by incorporating the negative effects of invader spread in management decisions (collective management) or independently, whereby the negative effects of invasive plant spread are ignored (independent management). Our modeling approach used a dynamic optimization framework, and we applied the model to invader spread using Linaria vulgaris. Model simulations allowed us to determine the optimal management strategy based on net benefits for a range of invader densities. We found that optimal management strategies varied as a function of initial plant densities. At low densities, net benefits were high for both collective and independent management to eradicate the invader, suggesting the importance of early detection and eradication. At moderate densities, collective management led to faster and more frequent invader eradication compared to independent management. When we used a financial penalty to ensure that independent properties were managed collectively, we found that the penalty would be most feasible when levied on a property's perimeter boundary to control spread among properties. At the highest densities, the optimal management strategy was "do nothing" because the economic costs of removal were too high relative to the benefits of removal. Spatial variation in L. vulgaris densities resulted in different optimal management strategies for neighboring properties, making a formal economic policy to encourage invasive species removal

  18. Which trees should be removed in thinning?

    Directory of Open Access Journals (Sweden)

    Timo Pukkala

    2015-12-01

    Full Text Available Background: In economically optimal management, trees that are removed in a thinning treatment should be selected on the basis of their value, relative value increment and the effect of removal on the growth of remaining trees. Large valuable trees with decreased value increment should be removed, especially when they overtop smaller trees. Methods: This study optimized the tree selection rule in the thinning treatments of continuous cover management when the aim is to maximize the profitability of forest management. The weights of three criteria (stem value, relative value increment and effect of removal on the competition of remaining trees were optimized together with thinning intervals. Results and conclusions: The results confirmed the hypothesis that optimal thinning involves removing predominantly large trees. Increasing stumpage value, decreasing relative value increment, and increasing competitive influence increased the likelihood that removal is optimal decision. However, if the spatial distribution of trees is irregular, it is optimal to leave large trees in sparse places and remove somewhat smaller trees from dense places. However, the benefit of optimal thinning, as compared to diameter limit cutting is not usually large in pure one-species stands. On the contrary, removing the smallest trees from the stand may lead to significant (30–40 % reductions in the net present value of harvest incomes. Keywords: Continuous cover forestry, Tree selection, High thinning, Optimal management, Spatial distribution, Spatial growth model

  19. Hydrogen Peroxide Enhances Removal of NOx from Flue Gases

    Science.gov (United States)

    Collins, Michelle M.

    2005-01-01

    Pilot scale experiments have demonstrated a method of reducing the amounts of oxides of nitrogen (NOx) emitted by industrial boilers and powerplant combustors that involves (1) injection of H2O2 into flue gases and (2) treatment of the flue gases by caustic wet scrubbing like that commonly used to remove SO2 from combustion flue gases. Heretofore, the method most commonly used for removing NOx from flue gases has been selective catalytic reduction (SCR), in which the costs of both installation and operation are very high. After further development, the present method may prove to be an economically attractive alternative to SCR.

  20. Analysis of key variables controlling phosphorus removal in high ...

    African Journals Online (AJOL)

    This study evaluates the influence of hydraulic retention time (HRT), solar radiation, and water temperature on phosphorus removal from two experimental high rate oxidation ponds (HROP) with clarifiers. Both HROPs were operated for a period of one year with different HRTs (3 to 10 d), but under the same environmental ...

  1. Socio-Demographic and Economic Factors Affecting the Acceptance of Removable Dentures

    Science.gov (United States)

    Baran, İlgi; Ergün, Gülfem; Semiz, Mustafa

    2007-01-01

    Objectives The aim of this study was to evaluate relationships between the socio-demographic and economic factors of patients and the reasons of admission, usage periods of the two types of clinics, frequencies of denture changes, satisfaction levels and preferences of prosthetic dental treatment. Materials and Methods 510 partially and/or totally edentulous patients were studied using a questionnaire. The questionnaire consisted of questions; age, gender, education level, income status, problems with dentures, necessity for new dentures. Also asked was the place that the subjects would prefer to get their denture treatment, irrespective of their income level. In this study, Z-test was used to analyze two-sample proportions, T-test was used to determine two-sample means and Chi-square test was used to determine relationship between two classified variables. Results The number of male patients with complete dentures was more than the number of females, with an opposing trend for partial dentures. Irrespective of gender, each patient had had nearly two dentures by the time of questioning. It was also observed that the university clinics were generally preferred by patients from higher income levels with a higher educational level (x2=25.206, Pdenture treatment, regardless of cost, private practice was the preferred-choice. Conclusions With respect to dental condition and the acceptance of removable dentures, there were differences among gender, educational level and income status. PMID:19212485

  2. Denitrifying sulfide removal process on high-salinity wastewaters.

    Science.gov (United States)

    Liu, Chunshuang; Zhao, Chaocheng; Wang, Aijie; Guo, Yadong; Lee, Duu-Jong

    2015-08-01

    Denitrifying sulfide removal (DSR) process comprising both heterotrophic and autotrophic denitrifiers can simultaneously convert nitrate, sulfide, and acetate into nitrogen gas, elemental sulfur (S(0)), and carbon dioxide, respectively. Sulfide- and nitrate-laden wastewaters at 2-35 g/L NaCl were treated by DSR process. A C/N ratio of 3:1 was proposed to maintain high S(0) conversion rate. The granular sludge with a compact structure and smooth outer surface was formed. The microbial communities of DSR consortium via high-throughput sequencing method suggested that salinity shifts the predominating heterotrophic denitrifiers at 10 g/L NaCl.

  3. A highly efficient and selective polysilsesquioxane sorbent for heavy metal removal

    KAUST Repository

    Duan, Xiaonan; Qi, Genggeng; Wang, Peng; Giannelis, Emmanuel P.

    2012-01-01

    Suited for heavy stuff: An efficient mesoporous sorbent based on a pure ethylendiamine-bridged polysilsesquioxane is presented. This material, with both a high amine loading and a high surface area, is applied for heavy metal ion removal. Copyright © 2012 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

  4. A highly efficient and selective polysilsesquioxane sorbent for heavy metal removal

    KAUST Repository

    Duan, Xiaonan

    2012-02-29

    Suited for heavy stuff: An efficient mesoporous sorbent based on a pure ethylendiamine-bridged polysilsesquioxane is presented. This material, with both a high amine loading and a high surface area, is applied for heavy metal ion removal. Copyright © 2012 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

  5. Economic Analysis of a Nuclear Reactor Powered High-Temperature Electrolysis Hydrogen Production Plant

    International Nuclear Information System (INIS)

    E. A. Harvego; M. G. McKellar; M. S. Sohal; J. E. O'Brien; J. S. Herring

    2008-01-01

    A reference design for a commercial-scale high-temperature electrolysis (HTE) plant for hydrogen production was developed to provide a basis for comparing the HTE concept with other hydrogen production concepts. The reference plant design is driven by a high-temperature helium-cooled nuclear reactor coupled to a direct Brayton power cycle. The reference design reactor power is 600 MWt, with a primary system pressure of 7.0 MPa, and reactor inlet and outlet fluid temperatures of 540 C and 900 C, respectively. The electrolysis unit used to produce hydrogen includes 4,009,177 cells with a per-cell active area of 225 cm2. The optimized design for the reference hydrogen production plant operates at a system pressure of 5.0 MPa, and utilizes an air-sweep system to remove the excess oxygen that is evolved on the anode (oxygen) side of the electrolyzer. The inlet air for the air-sweep system is compressed to the system operating pressure of 5.0 MPa in a four-stage compressor with intercooling. The alternating-current, AC, to direct-current, DC, conversion efficiency is 96%. The overall system thermal-to-hydrogen production efficiency (based on the lower heating value of the produced hydrogen) is 47.12% at a hydrogen production rate of 2.356 kg/s. An economic analysis of this plant was performed using the standardized H2A Analysis Methodology developed by the Department of Energy (DOE) Hydrogen Program, and using realistic financial and cost estimating assumptions. The results of the economic analysis demonstrated that the HTE hydrogen production plant driven by a high-temperature helium-cooled nuclear power plant can deliver hydrogen at a competitive cost. A cost of $3.23/kg of hydrogen was calculated assuming an internal rate of return of 10%

  6. EXPERIMENTAL STUDY OF HIGH LEVELS OF SO2 REMOVAL IN ATMOSPHERIC-PRESSURE FUIDIZED-BED COMBUSTORS

    Science.gov (United States)

    The report describes tests conducted in an atmospheric-pressure-fluidized-bed combustor (FBC) with a cross-section of 1 x 1.6 m) to demonstrate high levels of S02 removal when burning a high-sulfur coal and feeding limestone sorbent for S02 removal. The goal was to achieve 90-plu...

  7. Antimony contamination, consequences and removal techniques: A review.

    Science.gov (United States)

    Li, Jiayu; Zheng, BoHong; He, Yangzhuo; Zhou, Yaoyu; Chen, Xiao; Ruan, Shan; Yang, Yuan; Dai, Chunhao; Tang, Lin

    2018-07-30

    A significant amount of antimony (Sb) enters into the environment every year because of the wide use of Sb compounds in industry and agriculture. The exposure to Sb, either direct consumption of Sb or indirectly, may be fatal to the human health because both antimony and antimonide are toxic. Firstly, the introduction of Sb chemistry, distribution and health threats are presented in this review, which is essential to the removal techniques. Then, we provide the recent and common techniques to remove Sb, including adsorption, coagulation/flocculation, membrane separation, electrochemical methods, ion exchange and extraction. Removal techniques concentrate on the advantages, drawbacks, economical efficiency and the recent achievements of each technique. We also take an overall consideration of experimental conditions, comparison criteria, and economic aspects. Copyright © 2018 Elsevier Inc. All rights reserved.

  8. Microbial electricity driven anoxic ammonium removal.

    Science.gov (United States)

    Vilajeliu-Pons, Anna; Koch, Christin; Balaguer, Maria D; Colprim, Jesús; Harnisch, Falk; Puig, Sebastià

    2018-03-01

    Removal of nitrogen, mainly in form of ammonium (NH 4 + ), in wastewater treatment plants (WWTPs) is a highly energy demanding process, mainly due to aeration. It causes costs of about half a million Euros per year in an average European WWTP. Alternative, more economical technologies for the removal of nitrogen compounds from wastewater are required. This study proves the complete anoxic conversion of ammonium (NH 4 + ) to dinitrogen gas (N 2 ) in continuously operated bioelectrochemical systems at the litre-scale. The removal rate is comparable to conventional WWTPs with 35 ± 10 g N m -3 d -1 with low accumulation of NO 2 - , NO 3 - , N 2 O. In contrast to classical aerobic nitrification, the energy consumption is considerable lower (1.16 ± 0.21 kWh kg -1 N, being more than 35 times less than for the conventional wastewater treatment). Biotic and abiotic control experiments confirmed that the anoxic nitrification was an electrochemical biological process mainly performed by Nitrosomonas with hydroxylamine as the main substrate (mid-point potential, E ox  = +0.67 ± 0.08 V vs. SHE). This article proves the technical feasibility and reduction of costs for ammonium removal from wastewater, investigates the underlying mechanisms and discusses future engineering needs. Copyright © 2017 Elsevier Ltd. All rights reserved.

  9. Application of Metal Oxide Heterostructures in Arsenic Removal from Contaminated Water

    Directory of Open Access Journals (Sweden)

    Lei Chen

    2014-01-01

    Full Text Available It has become one of the major environmental problems for people worldwide to be exposed to high arsenic concentrations through contaminated drinking water, and even the long-term intake of small doses of arsenic has a carcinogenic effect. As an efficient and economic approach for the purification of arsenic-containing water, the adsorbents in adsorption processes have been widely studied. Among a variety of adsorbents reported, the metal oxide heterostructures with high surface area and specific affinity for arsenic adsorption from aqueous systems have demonstrated a promising performance in practical applications. This review paper aims to summarize briefly the metal oxide heterostructures in arsenic removal from contaminated water, so as to provide efficient, economic, and robust solutions for water purification.

  10. Technical-economic evaluation of the utilization of closing resistor in CEMIG extra-high voltage circuit breakers

    Energy Technology Data Exchange (ETDEWEB)

    Rocha, Angelica C.O.; Pinto, Roberto del Giudice R.; Teixeira, Jose Cleber; Fonseca, Rodrigo Assuncao; F, Junior, Sebastiao V [Companhia Energetica de Minas Gerais (CEMIG), Belo Horizonte, MG (Brazil)

    1994-12-31

    This paper presents the technical and economic studies performed by CEMIG, Companhia Energetica de Minas Gerais, Brazil, concerning the use of closing resistor in its extra-high voltage (EHV) breakers. The analysis emphasizes the advantages which could be achieved with the elimination of the resistor as far as costs and reliability are concerned. This evaluation was motivated by two 500 kV breaker failures resulting from the breakdown of the closing resistor operation mechanism. These occurrences resulted in operative restriction for CEMIG EHV system. The analysis demanded a review of the capability criteria of silicon carbide (Si C) gap arresters, which are still greatly used in CEMIG EHV System, and of the procedures to be applied when carrying out the transient studies. The investigation resulted in the prompt removal of closing resistors from circuit breakers in CEMIG extra-high voltage system generating an economy of approximately U$ 840,00 and an improvement in safety and system reliability. (author) 13 refs., 4 figs., 1 tab.

  11. Rapid startup and high rate nitrogen removal from anaerobic sludge digester liquor using a SNAP process.

    Science.gov (United States)

    Qiao, Sen; Nishiyama, Takashi; Fujii, Tatsuo; Bhatti, Zafar; Furukawa, Kenji

    2012-02-01

    In this study, a single-stage autotrophic nitrogen removal reactor, packed with a novel acrylic fiber biomass carrier material (Biofix), was applied for nitrogen removal from sludge digester liquor. For rapid start-up, conventional activated sludge was added to the reactor soon after the attachment of anammox biomass on the Biofix carriers, which allowed conventional activated sludge to form a protective layer of biofilm around the anammox biomass. The Nitrogen removal efficiency reached 75% within 1 week at a nitrogen loading rate of 0.46 kg-N/m(3)/day for synthetic wastewater treatment. By the end of the synthetic wastewater treatment period, the maximum nitrogen removal rate had increased to 0.92 kg-N/m(3)/day at a nitrogen loading rate of 1.0 kg-N/m(3)/day. High nitrogen removal rate was also achieved during the actual raw digester liquor treatment with the highest nitrogen removal rate being 0.83 kg-N/m(3)/day at a nitrogen loading rate of 0.93 kg-N/m(3)/day. The thick biofilm on Biofix carriers allowed anammox bacteria to survive under high DO concentration of 5-6 mg/l resulting in stable and high nitrogen removal performance. FISH and CLSM analysis demonstrated that anammox bacteria coexisted and surrounded by ammonium oxidizing bacteria.

  12. THE PECULIARITIES OF THE ACCOUNTING OF CONSUMPTIONS CONCERNING GAPS REMOVAL IN VINEYARDS

    Directory of Open Access Journals (Sweden)

    Tatiana ŞEVCIUC

    2013-01-01

    Full Text Available Today’s methodology of the accounting of the economic operations concerning gaps removal in vineyards is imperfect; it generates numerous uncertainties and it doesn’t take into account some factors that directly influence gaps removal technology. In our opinion, the rationality of gaps removal in fruitful vineyards may be argued from both economic and biological points. Some authors suggest solving this problem by classifying current accounts that is doubtful as these suggestions don’t have a sound accounting basis and they neglect the fundamental principles of the accounting. That is why, this article suggests the economic way of solving this problem by determining the time of consumptions recovery when planting, caring and growing the cuttings till they give fruit.

  13. Rethinking Rice Preparation for Highly Efficient Removal of Inorganic Arsenic Using Percolating Cooking Water.

    Science.gov (United States)

    Carey, Manus; Jiujin, Xiao; Gomes Farias, Júlia; Meharg, Andrew A

    2015-01-01

    A novel way of cooking rice to maximize the removal of the carcinogen inorganic arsenic (Asi) is presented here. In conventional rice cooking water and grain are in continuous contact, and it is known that the larger the water:rice cooking ratio, the more Asi removed by cooking, suggesting that the Asi in the grain is mobile in water. Experiments were designed where rice is cooked in a continual stream of percolating near boiling water, either low in Asi, or Asi free. This has the advantage of not only exposing grain to large volumes of cooking water, but also physically removes any Asi leached from the grain into the water receiving vessel. The relationship between cooking water volume and Asi removal in conventional rice cooking was demonstrated for the rice types under study. At a water-to-rice cooking ratio of 12:1, 57±5% of Asi could be removed, average of 6 wholegrain and 6 polished rice samples. Two types of percolating technology were tested, one where the cooking water was recycled through condensing boiling water steam and passing the freshly distilled hot water through the grain in a laboratory setting, and one where tap water was used to cook the rice held in an off-the-shelf coffee percolator in a domestic setting. Both approaches proved highly effective in removing Asi from the cooking rice, with up to 85% of Asi removed from individual rice types. For the recycled water experiment 59±8% and 69±10% of Asi was removed, on average, compared to uncooked rice for polished (n=27) and wholegrain (n=13) rice, respectively. For coffee percolation there was no difference between wholegrain and polished rice, and the effectiveness of Asi removal was 49±7% across 6 wholegrain and 6 polished rice samples. The manuscript explores the potential applications and further optimization of this percolating cooking water, high Asi removal, discovery.

  14. System for removing contaminants from plastic resin

    Science.gov (United States)

    Bohnert, George W.; Hand, Thomas E.; DeLaurentiis, Gary M.

    2010-11-23

    A resin recycling system that produces essentially contaminant-free synthetic resin material in an environmentally safe and economical manner. The system includes receiving the resin in container form. A grinder grinds the containers into resin particles. The particles are exposed to a solvent in one or more solvent wash vessels, the solvent contacting the resin particles and substantially removing contaminants on the resin particles. A separator is used to separate the resin particles and the solvent. The resin particles are then placed in solvent removing element where they are exposed to a solvent removing agent which removes any residual solvent remaining on the resin particles after separation.

  15. Development of metal catalyst impregnation technology for membrane-based oxygen removal system

    International Nuclear Information System (INIS)

    Kim, Mun Soo; Lee, Doo Ho; Kang, Duk Won

    2005-01-01

    Dissolved oxygen(DO) is a primary cause of PWSCC and its content in reactor coolant system in NPPs has been strictly controlled by various DO removal methods. There are several removal methods of DO, such as vacuum degasification, thermal deaeration, and reductive removal by oxygen scavengers. Although the operation principles of vacuum degasification and thermal deaeration are simple, these methods require a lot of energy for operation and show lower efficiency. And these methods have a few handicaps such as temperature, pH, toxicity, high cost of installation and so on. For the purpose of developing the best method for DO removal from make-up water storage tank, it is necessary to overcome the disadvantages of hydrazine treatment. From this point of view, membrane-based oxygen removal system (MORS) has many advantages than other methods for example, friendly environmental process, versatility of operation conditions with high temperature and low pressure, small space, low cost, etc. Recently de-gassing membrane is widely used in power plant's feed water system for DO removal. De-gassing membrane has some advantages; it removes other dissolved gases such as CO2, N2, as well as O2, and is more economical than Catalytic resin-based Oxygen Removal System. In this study, to obtain better efficiency of MORS, we modified the polypropylene (PP) hollow fiber membrane by plasma treatment and ion beam irradiation supported platinum(Pt), palladium(Pd) as metal catalyst on the surface of the membrane

  16. Feasibility of turbidity removal by high-gradient superconducting magnetic separation.

    Science.gov (United States)

    Zeng, Hua; Li, Yiran; Xu, Fengyu; Jiang, Hao; Zhang, Weimin

    2015-01-01

    Several studies have focused on pollutant removal by magnetic seeding and high-gradient superconducting magnetic separation (HGSMS). However, few works reported the application of HGSMS for treating non-magnetic pollutants by an industrial large-scale system. The feasibility of turbidity removal by a 600 mm bore superconducting magnetic separation system was evaluated in this study. The processing parameters were evaluated by using a 102 mm bore superconducting magnetic separation system that was equipped with the same magnetic separation chamber that was used in the 600 mm bore system. The double-canister system was used to process water pollutants. Analytical grade magnetite was used as a magnetic seed and the turbidity of the simulated raw water was approximately 110 NTU, and the effects of polyaluminum chloride (PAC) and magnetic seeds on turbidity removal were evaluated. The use of more PAC and magnetic seeds had few advantages for the HGSMS at doses greater than 8 and 50 mg/l, respectively. A magnetic intensity of 5.0 T was beneficial for HGSMS, and increasing the flow rate through the steel wool matrix decreased the turbidity removal efficiency. In the breakthrough experiments, 90% of the turbidity was removed when 100 column volumes were not reached. The processing capacity of the 600 mm bore industry-scale superconducting magnetic separator for turbidity treatment was approximately 78.0 m(3)/h or 65.5 × 10(4) m(3)/a. The processing cost per ton of water for the 600 mm bore system was 0.1 $/t. Thus, the HGSMS separator could be used in the following special circumstances: (1) when adequate space is not available for traditional water treatment equipment, especially the sedimentation tank, and (2) when decentralized sewage treatment HGSMS systems are easier to transport and install.

  17. Impact of exogenous organic carbon on the removal of chemicals of concern in the high rate nitrifying trickling filters.

    Science.gov (United States)

    Mai, Lei; van den Akker, Ben; Du, Jun; Kookana, Rai S; Fallowfield, Howard

    2016-06-01

    The application of fixed bed high rate nitrifying trickling filters (NTFs) for the removal of track organic chemicals of concern (CoC) is less well known than their application to nutrient removal in water treatment. Particularly, the effect of exogenous organic carbon substrate (sucrose) loading on the performance of NTFs is not well understood. A laboratory-scale NTF system was operated in recirculation mode, with the objective of removing ammonia and CoC simultaneously. The efficiency of a high rate NTF for removal both of low concentration of ammonia (5 mg NH4-N L(-1)) and different concentrations of CoC in the presence of an exogenous organic carbon substrate (30 mg total organic carbon (TOC) L(-1)) was investigated. In the presence of exogenous organic carbon, the results demonstrated that the high rate NTF was able to successfully remove most of the CoCs investigated, with the removal ranging from 20.2% to 87.54%. High removal efficiencies were observed for acetaminophen (87.54%), bisphenol A (86.60%), trimethoprim (86.24%) and 17α-ethynylestradiol (80.60%). It was followed by the medium removal efficiency for N, N-diethyl-m-toluamide (61.31%) and atrazine (56.90%). In contrast, the removal of caffeine (28.43%) and benzotriazole (20.20%) was poorer in the presence of exogenous organic carbon. The removal efficiency for CoC was also compared with the results obtained in our previous study in the absence of exogenous organic carbon. The results showed that the addition of exogenous organic carbon was able to improve the removal of some of the CoC. Significant TOC percentage removals (45.68%-84.43%) and ammonia removal rate (mean value of 0.44 mg NH4-N L(-1) h(-1)) were also achieved in this study. The findings from this study provide valuable information for optimising the efficiency of high rate NTF for the removal of ammonia, CoC and TOC. Copyright © 2016 Elsevier Ltd. All rights reserved.

  18. Analysis of technology and seminar on economic trends about High-intensity LED

    International Nuclear Information System (INIS)

    2003-09-01

    This is divided into two parts. Contents of this report in the first part are technical trends on high-intensity LED which reports introduction of LED as compound semiconductor, white LED? patent issues, review on technology of High-intensity LED and Reliability of High-intensity LED. The second part deals with economic tends about High-intensity LED. This seminar was held to report analysis and economical trends about High-intensity LED by Korea Industrial Education Institute in 2003.

  19. Enteric virus removal inactivation by coal-based media

    Energy Technology Data Exchange (ETDEWEB)

    Gupta, A.; Chaudhuri, M. [Indian Institute of Technology, Kanpur (India). Dept. of Civil Engineering

    1995-02-01

    Four coal-based media, viz. alum-pretreated or ferric hydroxide-impregnated Giridih bituminous coal and lignite (alum-GBC, Fe-GBC; alum-lignite and Fe-Lignite) were laboratory tested to assess their potential in removing/inactivating enteric viruses in water. Batch-sorption screening tests, employing a poliovirus-spiked canal water, indicated high poliovirus sorption by Fe-GBC and alum-GBC in a short contact time of 5 min. Based on the results of further batch-sorption tests, using silver incorporated media (alum/Ag-GBC, alum-GBC-Ag and Fe-GBC-Ag), as well as aesthetic water quality consideration and previous findings on removal of coliforms and turbidity, alum/Ag-GBC, alum-GBC and alum-GBC-AG were included in downflow column studies employing poliovirus-spiked canal water. All three media showed potential in removing/inactivating enteric viruses. In a separate column study employing a joint challenge of poliovirus and rotavirus, alum/Ag-GBC removed 59.3-86.5% of the viruses along with more than 99% reduction in indigenous heterotrophic bacteria. Alum/silver-pretreated bituminous coal medium appears promising for use in household water filters in rural areas of the developing world. However, improved medium preparation to further enhance its efficiency is needed; also, its efficacy in removing/inactivating indigenous enteric bacteria, viruses and protozoa has to be ensured and practicalities or economics of application need to be considered.

  20. Estimation of characteristics on high temperature filtration system for particle removal in vitrification process

    International Nuclear Information System (INIS)

    Park, Seung Chul; Ryu, Bo Hyun; Park, Byoung Chul; Ryu, Chang Soo; Hwang, Tae Won; Ha, Jong Hyun

    2003-01-01

    High temperature filtration technology has been widely used in nuclear industry systems to remove particulate matter from air and gas streams. Air filters are defined as porous structures through which air is passed to separate out entrained particulate matter. Especially among of them, ceramic candle filters are suitable to gain efficient dust removal at high temperatures and achieve high collection efficiencies for (sub-)micron particles. The paper presents experimental results for their application in the pilot scale vitrification plant operations. Experimental results were transformed into design equations for (i) total pressure drop and the effect of face velocity; (ii) the prediction of the operating parameters

  1. Mercury reduction and removal during high-level radioactive waste processing and vitrification

    International Nuclear Information System (INIS)

    Eibling, R.E.; Fowler, J.R.

    1981-01-01

    A reference process for immobilizing the high-level radioactive waste in borosilicate glass has been developed at the Savannah River Plant. This waste contains a substantial amount of mercury from separations processing. Because mercury will not remain in borosilicate glass at the processing temperature, mercury must be removed before vitrification or must be handled in the off-gas system. A process has been developed to remove mercury by reduction with formic acid prior to vitrification. Additional benefits of formic acid treatment include improved sludge handling and glass melter redox control

  2. Influence of material removal programming on ion beam figuring of high-precision optical surfaces

    Science.gov (United States)

    Liao, Wenlin; Dai, Yifan; Xie, Xuhui

    2014-09-01

    Ion beam figuring (IBF) provides a nanometer/subnanometer precision fabrication technology for optical components, where the surface materials on highlands are gradually removed by the physical sputtering effect. In this deterministic method, the figuring process is usually divided into several iterations and the sum of the removed material in each iteration is expected to approach the ideally removed material as nearly as possible. However, we find that the material removal programming in each iteration would influence the surface error convergence of the figuring process. The influence of material removal programming on the surface error evolution is investigated through the comparative study of the contour removal method (CRM) and the geometric proportion removal method (PRM). The research results indicate that the PRM can maintenance the smoothness of the surface topography during the whole figuring process, which would benefit the stable operation of the machine tool and avoid the production of mid-to-high spatial frequency surface errors. Additionally, the CRM only has the corrective effect on the area above the contour line in each iteration, which would result in the nonuniform convergence of the surface errors in various areas. All these advantages distinguish PRM as an appropriate material removal method for ultraprecision optical surfaces.

  3. SLAG CHARACTERIZATION AND REMOVAL USING PULSE DETONATION TECHNOLOGY DURING COAL GASIFICATION

    Energy Technology Data Exchange (ETDEWEB)

    DR. DANIEL MEI; DR. JIANREN ZHOU; DR. PAUL O. BINEY; DR. ZIAUL HUQUE

    1998-07-30

    Pulse detonation technology for the purpose of removing slag and fouling deposits in coal-fired utility power plant boilers offers great potential. Conventional slag removal methods including soot blowers and water lances have great difficulties in removing slags especially from the down stream areas of utility power plant boilers. The detonation wave technique, based on high impact velocity with sufficient energy and thermal shock on the slag deposited on gas contact surfaces offers a convenient, inexpensive, yet efficient and effective way to supplement existing slag removal methods. A slight increase in the boiler efficiency, due to more effective ash/deposit removal and corresponding reduction in plant maintenance downtime and increased heat transfer efficiency, will save millions of dollars in operational costs. Reductions in toxic emissions will also be accomplished due to reduction in coal usage. Detonation waves have been demonstrated experimentally to have exceptionally high shearing capability, important to the task of removing slag and fouling deposits. The experimental results describe the parametric study of the input parameters in removing the different types of slag and operating condition. The experimental results show that both the single and multi shot detonation waves have high potential in effectively removing slag deposit from boiler heat transfer surfaces. The results obtained are encouraging and satisfactory. A good indication has also been obtained from the agreement with the preliminary computational fluid dynamics analysis that the wave impacts are more effective in removing slag deposits from tube bundles rather than single tube. This report presents results obtained in effectively removing three different types of slag (economizer, reheater, and air-heater) t a distance of up to 20 cm from the exit of the detonation tube. The experimental results show that the softer slags can be removed more easily. Also closer the slag to the exit of

  4. Removing arsenic from groundwater in Cambodia using high performance iron adsorbent.

    Science.gov (United States)

    Kang, Y; Takeda, R; Nada, A; Thavarith, L; Tang, S; Nuki, K; Sakurai, K

    2014-09-01

    In Cambodia, groundwater has been contaminated with arsenic, and purification of the water is an urgent issue. From 2010 to 2012, an international collaborative project between Japan and Cambodia for developing arsenic-removing technology from well water was conducted and supported by the foundation of New Energy and Industrial Technology Development Organization, Japan. Quality of well water was surveyed in Kandal, Prey Veng, and Kampong Cham Provinces, and a monitoring trial of the arsenic removal equipment using our patented amorphous iron (hydr)oxide adsorbent was performed. Of the 37 wells surveyed, arsenic concentration of 24 exceeded the Cambodian guideline value (50 μg L(-1)), and those of 27 exceeded the WHO guideline for drinking water (10 μg L(-1)). Levels of arsenic were extremely high in some wells (>1,000-6,000 μg L(-1)), suggesting that arsenic pollution of groundwater is serious in these areas. Based on the survey results, 16 arsenic removal equipments were installed in six schools, three temples, two health centers, four private houses, and one commune office. Over 10 months of monitoring, the average arsenic concentrations of the treated water were between 0 and 10 μg L(-1) at four locations, 10-50 μg L(-1) at eight locations, and >50 μg L(-1) at four locations. The arsenic removal rate ranged in 83.1-99.7%, with an average of 93.8%, indicating that the arsenic removal equipment greatly lower the risk of arsenic exposure to the residents. Results of the field trial showed that As concentration of the treated water could be reduced to condition. This is one of the succeeding As removal techniques that could reduce As concentration of water below the WHO guideline value for As in situ.

  5. Nitrate Removal from Ground Water: A Review

    OpenAIRE

    Archna; Sharma, Surinder K.; Sobti, Ranbir Chander

    2012-01-01

    Nitrate contamination of ground water resources has increased in Asia, Europe, United States, and various other parts of the world. This trend has raised concern as nitrates cause methemoglobinemia and cancer. Several treatment processes can remove nitrates from water with varying degrees of efficiency, cost, and ease of operation. Available technical data, experience, and economics indicate that biological denitrification is more acceptable for nitrate removal than reverse osmosis and ion ex...

  6. Overstory removal: stand factors related to success and failure

    Science.gov (United States)

    Robert J. Laacke; Gary O. Fiddler

    1986-01-01

    Overstory removal can offer economic and esthetic advantages over clearcutting and regeneration, but projecting success is difficult. Twenty-nine units on nine operational overstory removal cuts in northern California were studied to determine what factors are related to satisfactory or unsatisfactory stocking after harvest. Stocking determinations were based on number...

  7. Removal of trace organic contaminants from domestic wastewater: A meta-analysis comparison of sewage treatment technologies.

    Science.gov (United States)

    Melvin, Steven D; Leusch, Frederic D L

    2016-01-01

    Trace organic contaminants (TrOCs), such as endocrine disrupting compounds (EDCs) and pharmaceuticals and personal care products (PPCPs), represent global threats to aquatic animals and ecosystems. A major source of TrOCs in the aquatic environment is via the discharge of treated sewage, so there is an urgent need to evaluate the comparative efficiencies of the most widely used sewage treatment technologies as regards elimination of these compounds from wastewater. To address this need, 976 published articles were compiled focusing on estimates of removal (%) for 20 common environmental TrOCs, from five major sewage treatment technologies: conventional activated sludge (CAS), oxidation ditch (OD), membrane bioreactor (MBR), ponds and constructed wetlands (PCW), and trickling biological filters (TBF). A quantitative meta-analysis was performed to compare standardized relative removal efficiencies (SREs) of the compounds amongst these technologies, and where possible potential sources of heterogeneity were considered (e.g., flow rates and chemical sorption potential). The results indicate that the most widely used CAS treatment and the less common TBF provide comparatively poor overall removal of common organic micropollutants. Membrane bioreactors appear to be capable of achieving the greatest overall removal efficiencies, but the sustainability and economic viability of this option has been questioned. Treatment with OD systems may be more economical while still achieving comparatively high removal efficiencies, and the analysis revealed OD to be the best option for targeting highly potent estrogenic EDCs. This study offers a unique global assessment of TrOC removal via leading sewage treatment technologies, and is an important step in the identification of effective options for treating municipal sewage. Copyright © 2016 Elsevier Ltd. All rights reserved.

  8. High Test Scores: The Wrong Road to National Economic Success

    Science.gov (United States)

    Baker, Keith

    2011-01-01

    A widely held view is that good schools are essential to a nation's international economic success and that high test scores on international tests of academic skills and knowledge indicate how good a nation's schools are. The widespread belief that good schools are an important contributor to a nation's economic success in the world is supported…

  9. Economical evaluation on gas turbine high temperature reactor 300 (GTHTR300)

    International Nuclear Information System (INIS)

    Takei, Masanobu; Kosugiyama, Shinichi; Mouri, Tomoaki; Katanishi, Shoji; Kunitomi, Kazuhiko

    2006-01-01

    Japan Atomic Energy Research Institute (JAERI) has been developing a graphite moderate and helium cooled High Temperature Gas-cooled Reactor (HTGR) with gas turbine, the GTHTR300 based on experience gained in development and operations of the High Temperature Engineering Test Reactor (HTTR) in JAERI. The GTHTR300 is a simplified and economical power plant with a high level of safety characteristics and a high plant efficiency of approximately 46%. Cost evaluation for plant construction and power generation is studied in order to clarify the economical feasibility of the GTHTR300. The construction cost is estimated to be about 200 thousands Yen/kWe. The power generation cost is estimated to be about 3.8 Yen/kWh by the conditions of 90% load factor and 3% discount rate. The economical feasibility of the GTHTR300 is certified. The present study is entrusted from Ministry of Education, Culture, Sports, Science and Technology of Japan. (author)

  10. Nitrate Removal from Ground Water: A Review

    Directory of Open Access Journals (Sweden)

    Archna

    2012-01-01

    Full Text Available Nitrate contamination of ground water resources has increased in Asia, Europe, United States, and various other parts of the world. This trend has raised concern as nitrates cause methemoglobinemia and cancer. Several treatment processes can remove nitrates from water with varying degrees of efficiency, cost, and ease of operation. Available technical data, experience, and economics indicate that biological denitrification is more acceptable for nitrate removal than reverse osmosis and ion exchange. This paper reviews the developments in the field of nitrate removal processes which can be effectively used for denitrifying ground water as well as industrial water.

  11. High-efficiency plasma catalytic removal of dilute benzene from air

    International Nuclear Information System (INIS)

    Fan, Hong-Yu; Shi, Chuan; Li, Xiao-Song; Zhao, De-Zhi; Xu, Yong; Zhu, Ai-Min

    2009-01-01

    Achieving complete oxidation, good humidity tolerance and low energy cost is the key issue that needs to be addressed in plasma catalytic volatile organic compounds removal from air. For this purpose, Ag/HZSM-5 catalyst-packed dielectric barrier discharge using a cycled system composed of a storage stage and a discharge stage was studied. For dilute benzene removal from simulated air, Ag/HZSM-5 catalysts exhibit not only preferential adsorption of benzene in humid air at the storage stage but also almost complete oxidation of adsorbed benzene at the discharge stage. Five 'storage-discharge' cycles were examined, which suggests that Ag/HZSM-5 catalysts are very stable during the cycled 'storage-discharge' (CSD) plasma catalytic process. High oxidation rate of absorbed benzene as well as low energy cost can be achieved at a moderate discharge power. In an example of the CSD plasma catalytic remedy of simulated air containing 4.7 ppm benzene with 50% RH and 600 ml min -1 flow rate, the energy cost was as low as 3.7 x 10 -3 kWh m -3 air. This extremely low energy cost to remove low-concentration pollutants from air undoubtedly makes the environmental applications of the plasma catalytic technique practical.

  12. Fossil fuel subsidy removal and inadequate public power supply: Implications for businesses

    International Nuclear Information System (INIS)

    Bazilian, Morgan; Onyeji, Ijeoma

    2012-01-01

    We briefly consider the impact of fossil fuel subsidy removal policies in the context of inadequate power supply, with a focus on the implications for businesses. In doing so, we utilize the case of the early 2012 fuel subsidy removal in Nigeria. The rationale for such subsidy-removal policies is typically informed by analysis showing that they lead to an economically inefficient allocation of resources and market distortions, while often failing to meet intended objectives. However, often the realities of infrastructural and institutional deficiencies are not appropriately factored into the decision-making process. Businesses in many developing countries, already impaired by the high cost of power supply deficiencies, become even less competitive on an unsubsidized basis. We find that justifications for removal often do not adequately reflect the specific environments of developing country economies, resulting in poor recommendations – or ineffective policy. - Highlights: ► We consider the impact of fuel subsidy removal in the context of energy poverty. ► Calls for subsidy removal often do not reflect the developing country realities. ► Businesses impaired by power supply deficiencies, become even less competitive.

  13. Economic considerations/comparisons for the disposal of defense high-level waste

    International Nuclear Information System (INIS)

    Leclaire, D.B.; Lazur, E.G.

    1985-01-01

    This paper provides a summary, in a generic sense, of the economic considerations and comparisons of permanent isolation of defense high-level waste (DHLW) in a licensed geologic repository. Topics considered include underground disposal, economic analysis, comparative evaluations, national defense, radioactive waste facilities, and licensing

  14. A Review of High School Economics in the Philippines: 1902-2005

    OpenAIRE

    Abueg, Luisito C.

    2008-01-01

    Economics is an important component of social science instruction in secondary level education in the Philippines. This paper aims to trace the evolution of economics education in Philippine high school through a review of all available textbooks, from the very beginning of the institution of the subject. Analyzed are the changing context, the correctness of the concepts taught, the language used in the books, the way different contemporary Philippine issues in economic development is treated...

  15. Denitrifying sulfide removal process on high-salinity wastewaters in the presence of Halomonas sp.

    Science.gov (United States)

    Liu, Chunshuang; Zhao, Dongfeng; Ma, Wenjuan; Guo, Yadong; Wang, Aijie; Wang, Qilin; Lee, Duu-Jong

    2016-02-01

    Biological conversion of sulfide, acetate, and nitrate to, respectively, elemental sulfur (S(0)), carbon dioxide, and nitrogen-containing gas (such as N2) at NaCl concentration of 35-70 g/L was achieved in an expanded granular sludge bed (EGSB) reactor. A C/N ratio of 1:1 was noted to achieve high sulfide removal and S(0) conversion rate at high salinity. The extracellular polymeric substance (EPS) quantities were increased with NaCl concentration, being 11.4-mg/g volatile-suspended solids at 70 mg/L NaCl. The denitrifying sulfide removal (DSR) consortium incorporated Thauera sp. and Halomonas sp. as the heterotrophs and Azoarcus sp. being the autotrophs at high salinity condition. Halomonas sp. correlates with the enhanced DSR performance at high salinity.

  16. Materials removal by water jets with high relative velocity

    International Nuclear Information System (INIS)

    Schikorr, W.

    1986-01-01

    By way of introduction approaches to the systematic apprehension of the material removal by water jets up to 1000 bar are made. In drilling experiments the effects of jet dynamic are studied, using the controlled disintegration of the jet. Using model-layer-systems the removal of layers by the 'natural' disintegrating fluid-jet is examined. The mechanisms of material removal and the consequences on the praxis of cleaning are discussed. A concept to measure specially the effects of the dynamic jet components is developed. In conclusion aspects of progress in this methods of material removal are discussed. (orig.) [de

  17. Removing radio-active wastes from nuclear power stations by the STEAG system

    International Nuclear Information System (INIS)

    Baatz, H.

    1978-01-01

    The mobile STEAG System for conditioning radio-active wastes from nuclear power stations represents a particularly safe and economic method of removing them in present day conditions. Cementation by the FAFNIR System is used for the greater part of the waste, the liquid concentrate (evaporator concentrate and filter slurry). For the special case of the medium active resin balls from the primary circuits, embedding in plastic by the FAMA process has proved to be the only available successful process so far. The highly active solid waste from the reactor core is decomposed by the MOSAIK System, is packed in transportable and storable containers and is removed from the fuel element storage pond. The systems are so safe that faults or interruptions of power station operation due to faults in removing radio-active wastes can be excluded. (orig.) [de

  18. System Evaluation and Economic Analysis of a HTGR Powered High-Temperature Electrolysis Hydrogen Production Plant

    International Nuclear Information System (INIS)

    McKellar, Michael G.; Harvego, Edwin A.; Gandrik, Anastasia A.

    2010-01-01

    A design for a commercial-scale high-temperature electrolysis (HTE) plant for hydrogen production has been developed. The HTE plant is powered by a high-temperature gas-cooled reactor (HTGR) whose configuration and operating conditions are based on the latest design parameters planned for the Next Generation Nuclear Plant (NGNP). The current HTGR reference design specifies a reactor power of 600 MWt, with a primary system pressure of 7.0 MPa, and reactor inlet and outlet fluid temperatures of 322 C and 750 C, respectively. The power conversion unit will be a Rankine steam cycle with a power conversion efficiency of 40%. The reference hydrogen production plant operates at a system pressure of 5.0 MPa, and utilizes a steam-sweep system to remove the excess oxygen that is evolved on the anode (oxygen) side of the electrolyzer. The overall system thermal-to-hydrogen production efficiency (based on the higher heating value of the produced hydrogen) is 40.4% at a hydrogen production rate of 1.75 kg/s and an oxygen production rate of 13.8 kg/s. An economic analysis of this plant was performed with realistic financial and cost estimating assumptions. The results of the economic analysis demonstrated that the HTE hydrogen production plant driven by a high-temperature helium-cooled nuclear power plant can deliver hydrogen at a cost of $3.67/kg of hydrogen assuming an internal rate of return, IRR, of 12% and a debt to equity ratio of 80%/20%. A second analysis shows that if the power cycle efficiency increases to 44.4%, the hydrogen production efficiency increases to 42.8% and the hydrogen and oxygen production rates are 1.85 kg/s and 14.6 kg/s respectively. At the higher power cycle efficiency and an IRR of 12% the cost of hydrogen production is $3.50/kg.

  19. Colour removal and carbonyl by-production in high dose ozonation for effluent polishing.

    Science.gov (United States)

    Mezzanotte, V; Fornaroli, R; Canobbio, S; Zoia, L; Orlandi, M

    2013-04-01

    Experimental tests have been conducted to investigate the efficiency and the by-product generation of high dose ozonation (10-60 mg O3 L(-1)) for complete colour removal from a treated effluent with an important component of textile dyeing wastewater. The effluent is discharged into an effluent-dominated stream where no dilution takes place, and, thus, the quality requirement for the effluents is particularly strict. 30, 60 and 90 min contact times were adopted. Colour was measured as absorbance at 426, 558 and 660 nm wavelengths. pH was monitored throughout the experiments. The experimental work showed that at 50 mg L(-1) colour removal was complete and at 60 mg O3 L(-1) the final aldehyde concentration ranged between 0.72 and 1.02 mg L(-1). Glyoxal and methylglyoxal concentrations were directly related to colour removal, whereas formaldehyde, acetaldehyde, acetone and acrolein were not. Thus, the extent of colour removal can be used to predict the increase in glyoxal and methylglyoxal concentrations. As colour removal can be assessed by a simple absorbance measurement, in contrast to the analysis of specific carbonyl compounds, which is much longer and complex, the possibility of using colour removal as an indicator for predicting the toxic potential of ozone by-products for textile effluents is of great value. Copyright © 2013 Elsevier Ltd. All rights reserved.

  20. Synthesis Mechanism and Thermal Optimization of an Economical Mesoporous Material Using Silica: Implications for the Effective Removal or Delivery of Ibuprofen.

    Directory of Open Access Journals (Sweden)

    Shanmuga Kittappa

    Full Text Available Mesoporous silica materials (MSMs were synthesized economically using silica (SiO2 as a precursor via a modified alkaline fusion method. The MSM prepared at 500°C (MSM-500 had the highest surface area, pore size, and volume, and the results of isotherms and the kinetics of ibuprofen (IBP removal indicated that MSM-500 had the highest sorption capacity and fastest removal speed vs. SBA-15 and zeolite. Compared with commercial granular activated carbon (GAC, MSM-500 had a ~100 times higher sorption rate at neutral pH. IBP uptake by MSM-500 was thermodynamically favorable at room temperature, which was interpreted as indicating relatively weak bonding because the entropy (∆adsS, -0.07 J mol(-1 K(-1 was much smaller. Five times recycling tests revealed that MSM-500 had 83-87% recovery efficiencies and slower uptake speeds due to slight deformation of the outer pore structure. In the IBP delivery test, MSM-500 drug loading was 41%, higher than the reported value of SBA-15 (31%. The in vitro release of IBP was faster, almost 100%, reaching equilibrium within a few hours, indicating its effective loading and unloading characteristics. A cost analysis study revealed that the MSM was ~10-70 times cheaper than any other mesoporous silica material for the removal or delivery of IBP.

  1. Technical and economic considerations of extra high voltage power transmission

    Energy Technology Data Exchange (ETDEWEB)

    Kahnt, R

    1966-09-01

    The reasons for the employment of higher transmission voltages are listed and the points decisive for the selection of three phase ac or dc systems are reviewed. The technical and economic problems arising in three phase extra high voltage transmission are discussed. These include selection of voltage, economical design of power lines, insulation problems, power supply dependability, equipment rating and reactive power and stability problems.

  2. Impact of biological and economic variables on optimal parity for replacement in swine breed-to-wean herds.

    Science.gov (United States)

    Rodriguez-Zas, S L; Davis, C B; Ellinger, P N; Schnitkey, G D; Romine, N M; Connor, J F; Knox, R V; Southey, B R

    2006-09-01

    Voluntary and involuntary culling practices determine the average parity when sows are replaced in a herd. Underlying these practices is the economic effect of replacing a sow at different parities. A dynamic programming model was used to find the optimal parity and net present value in breed-to-wean swine herds. The model included income and costs per parity weighted by the discount rate and sow removal rate. Three scenarios that reflect a wide range of cases were considered: low removal rates per parity with no salvage value (LRNS), high removal rates per parity with no salvage value (HRNS), and high removal rates per parity with a percentage of the sows having a salvage value (HRYS). The optimal parity of replacement for the base biological and economic conditions was 4 and 5 parities in the high and low removal scenarios, respectively. Sensitivity analyses identified the variables influencing the optimal replacement parity. Optimal parity of replacement ranged from 3 to 7 parities in the low replacement scenario, compared with 1 to 5 parities in the high replacement scenarios. Sow replacement cost and salvage value had the greatest impact on optimal parity of replacement followed by revenues per piglet weaned. The discount rate and number of parities per year generally had little influence on optimal parity. For situations with high sow costs, low salvage values, and low revenues per piglet, the optimal parity at removal was as high as 6 to 10 parities, and for situations with low sow cost, high salvage values, and high revenues per piglet, the optimal parity at removal was as low as 1 to 2 parities depending on removal rates. The modified internal rate of return suggested that, for most LRNS and HRYS scenarios considered, investment in a swine breed-to-wean enterprise was favored over other investments involving a similar risk profile. Our results indicate that in US breeding herds, sows are culled on average near the optimal parity of 4. However, the

  3. High-temperature removal of H2S from syngas by means of zinc-contaminated soils

    International Nuclear Information System (INIS)

    Tzu-Hsing Ko; Hsin-Ta Hsueh

    2006-01-01

    Hydrogen sulfide (H 2 S) is one of the most common compounds and can be easily found in advanced power generation plants, such as integrated gasification combined cycle (IGCC) and molten-carbonate fuel cell (MCFC) plants. Generally, in these systems raw materials with high heating value (HHV) or biomass were gasified under high temperature and produced a useful mixture gas. During the gasification, hydrogen sulfide accompanies with a great quantity of reductive gases at high temperature including CO, H 2 , CH 4 and N 2 , etc. This mixture gas is so-call syngas. Syngas is a valuable resource for electric power generation. Prior to using, H 2 S needs to be removed because its harmful effect. In addition, H 2 S is not only the malodorous and corrosive gas but also is the sources of the acid rain when it is oxidized into SO 2 and reacted with water. It has been known for many years that certain soils have the ability to absorb reductive sulfur-containing species such as hydrogen sulfide (H 2 S), carbonyl sulfide (COS), carbon disulfide (CS 2 ), dimethyl sulfide (CH 3 SCH 3 ) and dimethyl disulfide (CH 3 SSCH 3 ) at room temperature. Therefore, soils could act as an important sorption media for the removal of waste gases before they are released into the atmosphere. In this study, we further use the contaminated soils as regenerable sorbent for the removal of H 2 S from syngas under high temperature. Results indicate that contaminated soils could be used to remove H 2 S as well as maintain at least 90% regeneration efficiency after regeneration cycles. Additionally, zinc and iron appeared to be the major active species to react with H 2 S. The chemical structure of zinc and iron after removal of H 2 S could be expressed as ZnS and FeS. In addition to removal of H 2 S, it is also established that contaminated soil can be used for application which reduce the problem of heavy metal contaminated soils (Full text of contribution)

  4. Chemical activation of gasification carbon residue for phosphate removal

    Science.gov (United States)

    Kilpimaa, Sari; Runtti, Hanna; Lassi, Ulla; Kuokkanen, Toivo

    2012-05-01

    Recycling of waste materials provides an economical and environmentally significant method to reduce the amount of waste. Bioash formed in the gasification process possesses a notable amount of unburned carbon and therefore it can be called a carbon residue. After chemical activation carbon residue could be use to replace activated carbon for example in wastewater purification processes. The effect of chemical activation process variables such as chemical agents and contact time in the chemical activation process were investigated. This study also explored the effectiveness of the chemically activated carbon residue for the removal of phosphate from an aqueous solution. The experimental adsorption study was performed in a batch reactor and the influence of adsorption time, initial phosphate concentration and pH was studied. Due to the carbon residue's low cost and high adsorption capacity, this type of waste has the potential to be utilised for the cost-effective removal of phosphate from wastewaters. Potential adsorbents could be prepared from these carbonaceous by-products and used as an adsorbent for phosphate removal.

  5. The effect of light supply on microalgal growth, CO2 uptake and nutrient removal from wastewater

    International Nuclear Information System (INIS)

    Gonçalves, A.L.; Simões, M.; Pires, J.C.M.

    2014-01-01

    Highlights: • Effect of irradiance and light:dark ratio on microalgal growth was analysed. • Microalgal growth, CO 2 capture, nitrogen and phosphorus uptake were evaluated. • Higher irradiances and light periods supported higher growth and CO 2 uptake rates. • All the studied microalgal strains have shown high nitrogen removal efficiencies. • The highest phosphorus removal efficiency was 67.6%. - Abstract: Microalgal based biofuels have been reported as an attractive alternative for fossil fuels, since they constitute a renewable energy source that reduces greenhouse gas emissions to the atmosphere. However, producing biofuels from microalgae is still not economically viable. Therefore, the integration of biofuel production with other microalgal applications, such as CO 2 capture and nutrient removal from wastewaters, would reduce the microalgal production costs (and the environmental impact of cultures), increasing the economic viability of the whole process. Additionally, producing biofuels from microalgae strongly depends on microalgal strain and culture conditions. This study evaluates the effect of culture conditions, namely light irradiance (36, 60, 120 and 180 μE m −2 s −1 ) and light:dark ratio (10:14, 14:10 and 24:0), on microalgal growth, atmospheric CO 2 uptake and nutrient (nitrogen and phosphorous) removal from culture medium. Four different microalgal strains, Chlorella vulgaris, Pseudokirchneriella subcapitata, Synechocystis salina and Microcystis aeruginosa, were studied to ascertain the most advantageous regarding the referred applications. This study has shown that higher light irradiance values and light periods resulted in higher specific growth rates and CO 2 uptake rates. C. vulgaris presented the highest specific growth rate and CO 2 uptake rate: 1.190 ± 0.041 d −1 and 0.471 ± 0.047 g CO2 L −1 d −1 , respectively. All the strains have shown high nitrogen removal efficiencies, reaching 100% removal percentages in

  6. Removal of actinides from high-level wastes generated in the reprocessing of commercial fuels

    International Nuclear Information System (INIS)

    Bond, W.D.; Leuze, R.E.

    1975-09-01

    Progress is reported on a technical feasibility study of removing the very long-lived actinides (uranium, neptunium, plutonium, americium, and curium) from high-level wastes generated in the commercial reprocessing of spent nuclear fuels. The study was directed primarily at wastes from the reprocessing of light water reactor (LWR) fuels and specifically to developing satisfactory methods for reducing the actinide content of these wastes to values that would make 1000-year-decayed waste comparable in radiological toxicity to natural uranium ore deposits. Although studies are not complete, results thus far indicate the most promising concept for actinide removal includes both improved recovery of actinides in conventional fuel reprocessing and secondary processing of the high-level wastes. Secondary processing will be necessary for the removal of americium and curium and perhaps some residual plutonium. Laboratory-scale studies of separations methods that appear most promising are reported and conceptual flowsheets are discussed. (U.S.)

  7. Dunaliella salina as marine microalga highly tolerant to but a poor remover of cadmium

    International Nuclear Information System (INIS)

    Folgar, S.; Torres, E.; Perez-Rama, M.; Cid, A.; Herrero, C.; Abalde, J.

    2009-01-01

    Cadmium tolerance and removal in the marine microalga Dunaliella salina were studied in cultures exposed to different metal concentrations (5-120 mg Cd l -1 ) for 96 h. This microalga can be included in the group of microalgal species most tolerant to cadmium due to the high value of EC50 that it possesses (48.9 mg Cd l -1 at 96 h of culture). The greater percentage of cadmium removed was obtained in cultures exposed to 5 mg Cd l -1 at 96 h, but removing only 11.3% of the added cadmium. In all cultures, the quantity of cadmium removed intracellularly was much lower than the bioadsorbed quantity and it was proportional to the sulfhydryl group levels. Both the Freundlich and Langmuir adsorption models were suitable for describing the short-term biosorption of cadmium by living cells of D. salina.

  8. Nutrient removal by apple, pear and cherry nursery trees

    OpenAIRE

    Giovambattista Sorrenti; Maurizio Quartieri; Silvia Salvi; Moreno Toselli

    2017-01-01

    Given that nursery is a peculiar environment, the amount of nutrients removed by nursery trees represents a fundamental acquisition to optimise fertilisation strategies, with economic and environmental implications. In this context, we determined nutrient removal by apple, pear and cherry nursery trees at the end of the nursery growing cycle. We randomly removed 5 leafless apple (Golden Delicious/EMLA M9; density of 30,000 trees ha–1), pear (Santa Maria/Adams; density of 30,000 trees ha–1) an...

  9. Technical and economic considerations of extra high voltage power transmission

    Energy Technology Data Exchange (ETDEWEB)

    Kahnt, R

    1966-09-01

    The reasons for the employment of higher transmission voltages are listed and the points decisive for the selection of three phase ac or dc systems are reviewed. This is followed by treatment of the technical and economic problems arising in three phase-extra high voltage transmission. These include selection of voltage, economical design of power lines, insulation problems, power supply dependability, equipment rating, and reactive power and stability problems.

  10. Possibility of a pressurized water reactor concept with highly inherent heat removal following capability

    International Nuclear Information System (INIS)

    Araya, Fumimasa; Murao, Yoshio

    1995-01-01

    If the core power inherently follows change in heat removal rate from the primary coolant system within small thermal expansion of the coolant which can be absorbed in a practical size of pressurizer, reactor systems may have more safety and load following capability. In order to know possibility and necessary conditions of a concept on reactor core and primary coolant system of a pressurized water reactor (PWR) with such 'highly inherent heat removal following capability', transient analyses on an ordinary two-loop PWR have been performed for a transient due to 50% change in heat removal with the RETRAN-02 code. The possibility of a PWR concept with the highly inherent heat removal following capability has been demonstrated under the conditions of the absolute value of ratio of the coolant density reactivity coefficient to the Doppler reactivity coefficient more than 10x10 3 kg·cm 3 which is two to three times larger than that at beginning of cycle (BOC) in an ordinary PWR and realized by elimination of the chemical shim, the 12% lower average linear heat generation rate of 17.9 kW/m, and the 1.5 times larger pressurizer volume than those of the ordinary PWR. (author)

  11. The microbial community in a high-temperature enhanced biological phosphorus removal (EBPR process

    Directory of Open Access Journals (Sweden)

    Ying Hui Ong

    2016-01-01

    Full Text Available An enhanced biological phosphorus removal (EBPR process operated at a relatively high temperature, 28 °C, removed 85% carbon and 99% phosphorus from wastewater over a period of two years. This study investigated its microbial community through fluorescent in situ hybridization (FISH and clone library generation. Through FISH, considerably more Candidatus “Accumulibacter phosphatis” (Accumulibacter-polyphosphate accumulating organisms (PAOs than Candidatus ‘Competibacter phosphatis’ (Competibacter-glycogen accumulating organisms were detected in the reactor, at 36 and 7% of total bacterial population, respectively. A low ratio of Glycogen/Volatile Fatty Acid of 0.69 further indicated the dominance of PAOs in the reactor. From clone library generated, 26 operational taxonomy units were retrieved from the sludge and a diverse population was shown, comprising Proteobacteria (69.6%, Actinobacteria (13.7%, Bacteroidetes (9.8%, Firmicutes (2.94%, Planctomycetes (1.96%, and Acidobacteria (1.47%. Accumulibacter are the only recognized PAOs revealed by the clone library. Both the clone library and FISH results strongly suggest that Accumulibacter are the major PAOs responsible for the phosphorus removal in this long-term EBPR at relatively high temperature.

  12. IAEA Helps Remove Highly Radioactive Material from Five South American Countries

    International Nuclear Information System (INIS)

    2018-01-01

    The International Atomic Energy Agency (IAEA) has helped remove 27 disused highly radioactive sources from five South American countries in a significant step forward for nuclear safety and security in the region. It was the largest such project ever facilitated by the IAEA. The material, mainly used for medical purposes such as treating cancer and sterilizing instruments, was transported to Germany and the United States for recycling. Canada, where some of the sources were manufactured, funded the project upon requests for IAEA support from Bolivia, Ecuador, Paraguay, Peru and Uruguay. The sealed Cobalt-60 and Caesium-137 sources pose safety and security risks when no longer in use, according to Raja Adnan, Director of the IAEA’s Division of Nuclear Security. “The removal of this large number of radioactive sources has significantly reduced those risks in the five countries,” Adnan said. In recent years, the IAEA has assisted Bosnia and Herzegovina, Cameroon, Costa Rica, Honduras, Lebanon, Morocco, Tunisia and Uzbekistan in the removal of disused sources. The South American operation was the largest the IAEA has so far coordinated in terms of both the number of highly radioactive sources and countries involved. While nuclear safety and security are national responsibilities, the IAEA helps Member States upon request to meet these responsibilities through training, technical advice, peer reviews and other advisory services. Such efforts may include support for Member States in implementing the safe and cost-effective recovery, conditioning, storage, disposal or transportation of disused sealed radioactive sources (DSRS).

  13. Factors influencing high socio-economic class mothers' decision ...

    African Journals Online (AJOL)

    why high socio-economic class women in the Cape Metropole decide ... as barriers to breast-feeding include a lack of knowledge and experience (38%) as well as a lack of facilities at public ... private practising paediatrician in Stellenbosch for face validity. .... While mothers (n = 39; 70.9%) indicated that the facilities at work.

  14. Factor Affecting Textile Dye Removal Using Adsorbent From Activated Carbon: A Review

    Directory of Open Access Journals (Sweden)

    Mohammad Razi Mohd Adib

    2017-01-01

    Full Text Available Industrial company such as textile, leather, cosmetics, paper and plastic generated wastewater containing large amount of dye colour. The removal of dye materials are importance as the presence of this kind of pollutant influence the quality of water and makes it aesthetically unpleasant. As their chemical structures are complicated, it is difficult to treat dyes with municipal waste treatment operations. Even a small quantity of dye does cause high visibility and undesirability. There have been various treatment technique reviewed for the removal of dye in wastewater. However, these treatment process has made it to another expensive treatment method. This review focus on the application of adsorbent in dye removal from textile wastewater as the most economical and effective method, adsorption has become the most preferred method to remove dye. The review provides literature information about different basis materials used to produce activated carbon like agricultural waste and industrial waste as well as the operational parameters factors in term of contact time, adsorbent dosage, pH solution and initial dye concentration that will affect the process in removing textile dye. This review approach the low cost and environmental friendly adsorbent for replacing conventional activated carbon.

  15. Enhancing Economic Stability Utilizing the High Technologies in Community Colleges: A Case Study.

    Science.gov (United States)

    Mehnert, Barbara H.; Kurki, Allan W.

    Strategies to enhance the economic stability of community colleges through high technology approaches are discussed in this paper. First, general economic problems facing higher education are identified, and the ways in which they influence community colleges are described. Next, 10 strategies to aid in the economic recovery of community colleges…

  16. Experimental study on scale removal from special-shaped conduits through underwater electrical discharge

    International Nuclear Information System (INIS)

    Cao, Y; Wang, Z Q; Li, G F; Wu, Y; Zhou, J J

    2013-01-01

    Underwater electrical discharge technology is an innovative technique that can be used to enhance the stress intensity of water and improve the load addition. The technique enlarges the section area and compresses the surrounding water using a high-powered shock wave, which is induced by an underwater electrical discharge. This paper investigates the effectiveness of scale removal for special-shaped conduits employing underwater electrical discharge. Experimental results show that the pressure wave generated by underwater electrical discharge is capable of eliminating scale in special-shaped conduits. The data indicates that when the capacitance of the parallel-pulsed capacitors was 4 μF, the high pulsed power voltage was 33 kV and the primary discharge gap was 48 mm, the result of scale removal was remarkable. In laboratory tests, the scale of special equipment was removed to a great extent by this method. Because of its effectiveness and low cost, this method improves the practice and extends the lifetime of such equipment, and thus has potential application and economic value.

  17. System Evaluation and Economic Analysis of a Nuclear Reactor Powered High-Temperature Electrolysis Hydrogen-Production Plant

    International Nuclear Information System (INIS)

    Harvego, E.A.; McKellar, M.G.; Sohal, M.S.; O'Brien, J.E.; Herring, J.S.

    2010-01-01

    A reference design for a commercial-scale high-temperature electrolysis (HTE) plant for hydrogen production was developed to provide a basis for comparing the HTE concept with other hydrogen production concepts. The reference plant design is driven by a high-temperature helium-cooled nuclear reactor coupled to a direct Brayton power cycle. The reference design reactor power is 600 MWt, with a primary system pressure of 7.0 MPa, and reactor inlet and outlet fluid temperatures of 540 C and 900 C, respectively. The electrolysis unit used to produce hydrogen includes 4,009,177 cells with a per-cell active area of 225 cm2. The optimized design for the reference hydrogen production plant operates at a system pressure of 5.0 MPa, and utilizes an air-sweep system to remove the excess oxygen that is evolved on the anode (oxygen) side of the electrolyzer. The inlet air for the air-sweep system is compressed to the system operating pressure of 5.0 MPa in a four-stage compressor with intercooling. The alternating current (AC) to direct current (DC) conversion efficiency is 96%. The overall system thermal-to-hydrogen production efficiency (based on the lower heating value of the produced hydrogen) is 47.1% at a hydrogen production rate of 2.356 kg/s. An economic analysis of this plant was performed using the standardized H2A Analysis Methodology developed by the Department of Energy (DOE) Hydrogen Program, and using realistic financial and cost estimating assumptions. The results of the economic analysis demonstrated that the HTE hydrogen production plant driven by a high-temperature helium-cooled nuclear power plant can deliver hydrogen at a competitive cost. A cost of $3.23/kg of hydrogen was calculated assuming an internal rate of return of 10%.

  18. Removal of high concentration p-nitrophenol in aqueous solution by zero valent iron with ultrasonic irradiation (US–ZVI)

    International Nuclear Information System (INIS)

    Lai, Bo; Chen, Zhaoyu; Zhou, Yuexi; Yang, Ping; Wang, Juling; Chen, Zhiqiang

    2013-01-01

    Highlights: ► High concentration PNP can be reduced into the nontoxic p-aminophenol by US–ZVI. ► High removal efficiency of PNP is resulted from the synergistic reaction of ZVI and US. ► The reaction pathway of PNP in the US–ZVI system is proposed. ► Processing parameters of the US–ZVI system were optimized seriously. -- Abstract: In this study, the US–ZVI system was used to produce the strong reductants including ·H and nascent Fe 2+ ions to eliminate the toxicity of the high concentration p-nitrophenol (PNP) wastewater. The effect of the reactor structure, initial pH, ZVI dosage, ultrasonic power and initial PNP concentration on the removal efficiency of PNP from water was investigated intensively. The results show that a higher removal rate can be obtained by using a conical structure reactor, and the lower initial pH can aid the acceleration of PNP removal rate by using US–ZVI system. Furthermore, the removal efficiencies of PNP increased obviously with the increase of initial ZVI concentration from 0 to 15 g L −1 . Also, the treatment capacity of ZVI was enhanced remarkably by the ultrasonic irradiation, and the US–ZVI system can maintain high treatment efficiency for the high concentration PNP wastewater (500–10,000 mg L −1 ). Meanwhile, the high removal efficiency of PNP was mainly resulted from the synergistic reaction of ZVI and US. At last, the main degradation product (i.e., p-aminophenol) was detected by gas chromatography–mass spectrum (GC–MS). Thus, the reaction pathway of PNP in the US–ZVI system is proposed as a reducing process by the ·H and nascent Fe 2+ ions

  19. Removal of high concentration p-nitrophenol in aqueous solution by zero valent iron with ultrasonic irradiation (US–ZVI)

    Energy Technology Data Exchange (ETDEWEB)

    Lai, Bo, E-mail: laibo1981@163.com [School of Architecture and Environment, Sichuan University, Chengdu 610065 (China); Chen, Zhaoyu [School of Architecture and Environment, Sichuan University, Chengdu 610065 (China); Zhou, Yuexi [Research Center of Water Pollution Control Technology, Chinese Research Academy of Environmental Sciences, Beijing 100012 (China); Yang, Ping [School of Architecture and Environment, Sichuan University, Chengdu 610065 (China); Wang, Juling [Research Center of Water Pollution Control Technology, Chinese Research Academy of Environmental Sciences, Beijing 100012 (China); Chen, Zhiqiang [State Key Laboratory of Urban Water Resource and Environment, Harbin Institute of Technology, Harbin 150090 (China)

    2013-04-15

    Highlights: ► High concentration PNP can be reduced into the nontoxic p-aminophenol by US–ZVI. ► High removal efficiency of PNP is resulted from the synergistic reaction of ZVI and US. ► The reaction pathway of PNP in the US–ZVI system is proposed. ► Processing parameters of the US–ZVI system were optimized seriously. -- Abstract: In this study, the US–ZVI system was used to produce the strong reductants including ·H and nascent Fe{sup 2+} ions to eliminate the toxicity of the high concentration p-nitrophenol (PNP) wastewater. The effect of the reactor structure, initial pH, ZVI dosage, ultrasonic power and initial PNP concentration on the removal efficiency of PNP from water was investigated intensively. The results show that a higher removal rate can be obtained by using a conical structure reactor, and the lower initial pH can aid the acceleration of PNP removal rate by using US–ZVI system. Furthermore, the removal efficiencies of PNP increased obviously with the increase of initial ZVI concentration from 0 to 15 g L{sup −1}. Also, the treatment capacity of ZVI was enhanced remarkably by the ultrasonic irradiation, and the US–ZVI system can maintain high treatment efficiency for the high concentration PNP wastewater (500–10,000 mg L{sup −1}). Meanwhile, the high removal efficiency of PNP was mainly resulted from the synergistic reaction of ZVI and US. At last, the main degradation product (i.e., p-aminophenol) was detected by gas chromatography–mass spectrum (GC–MS). Thus, the reaction pathway of PNP in the US–ZVI system is proposed as a reducing process by the ·H and nascent Fe{sup 2+} ions.

  20. Dual-Functional Ultrafiltration Membrane for Simultaneous Removal of Multiple Pollutants with High Performance.

    Science.gov (United States)

    Pan, Shunlong; Li, Jiansheng; Noonan, Owen; Fang, Xiaofeng; Wan, Gaojie; Yu, Chengzhong; Wang, Lianjun

    2017-05-02

    Simultaneous removal of multiple pollutants from aqueous solution with less energy consumption is crucial in water purification. Here, a novel concept of dual-functional ultrafiltration (DFUF) membrane is demonstrated by entrapment of nanostructured adsorbents into the finger-like pores of ultrafiltration (UF) membrane rather than in the membrane matrix in previous reports of blend membranes, resulting in an exceptionally high active content and simultaneous removal of multiple pollutants from water due to the dual functions of rejection and adsorption. As a demonstration, hollow porous Zr(OH) x nanospheres (HPZNs) were immobilized in poly(ether sulfone) (PES) UF membranes through polydopamine coating with a high content of 68.9 wt %. The decontamination capacity of DFUF membranes toward multiple model pollutants (colloidal gold, polyethylene glycol (PEG), Pb(II)) was evaluated against a blend membrane. Compared to the blend membrane, the DFUF membranes showed 2.1-fold increase in the effective treatment volume for the treatment of Pb(II) contaminated water from 100 ppb to below 10 ppb (WHO drinking water standard). Simultaneously, the DFUF membranes effectively removed the colloidal gold and PEG below instrument detection limit, however the blend membrane only achieved 97.6% and 96.8% rejection for colloidal gold and PEG, respectively. Moreover, the DFUF membranes showed negligible leakage of nanoadsorbents during testing; and the membrane can be easily regenerated and reused. This study sheds new light on the design of high performance multifunction membranes for drinking water purification.

  1. Removal of boron (B) from waste liquors.

    Science.gov (United States)

    Jiang, J Q; Xu, Y; Simon, J; Quill, K; Shettle, K

    2006-01-01

    This paper explores the use of electrocoagulation to remove boron from waste effluent in comparison with alum coagulation. In treating model test wastes, greater boron removals were achieved with electrocoagulation at low doses than conventional alum coagulation when reaction was undertaken for the same conditions (pH 8.5, and initial boron concentration was 500 mg/L). Al electrocoagulation can achieve good boron removal performance (68.3%) at a dose of 2.1 (as molar ratio of Al:B, and for current density of 62.1 A/m2), while alum coagulation can only achieve the maximum boron removal of 56% at a dose of 2.4. Also, Al electrocoagulation can remove 15-20% more boron than alum coagulation for the same dose compared in the treatment of both model test wastes and industry effluent. The estimation of running costs shows that to achieve 75% boron removal from industry waste effluent, i.e. removing 150 g of boron from 1 m3 of effluent, electrocoagulation was 6.2 times cheaper than alum coagulation. The economic advantage of electrocoagulation in the treatment of boron-containing waste effluent is thus significant.

  2. Ammonium removal from high-strength aqueous solutions by Australian zeolite

    DEFF Research Database (Denmark)

    Wijesinghe, D. Thushari N; Dassanayake, Kithsiri B.; Sommer, Sven G.

    2016-01-01

    Removal of ammonium nitrogen (NH4 +-N) particularly from sources which are highly rich in nitrogen is important for addressing environmental pollution. Zeolites, aluminosilicate minerals, are commonly used as commercial adsorbents and ion-exchange medium in number of commercial applications due...... to its high adsorption capacity of ammonium (NH4 +). However, detailed investigations on NH4 + adsorption and ion exchange capacities of Australian natural zeolites are rare, particularly under higher NH4 + concentrations in the medium. Therefore, this study was conducted to determine NH4 + adsorption...... characteristics of Australian natural zeolites at high NH4 + concentrations with and without other chemical compounds in an aqueous solution. Results showed that initial NH4 + concentration, temperature, reaction time, and pH of the solution had significant effects on NH4 + adsorption capacity of zeolite...

  3. Functionalized magnetic mesoporous silica nanoparticles for U removal from low and high pH groundwater

    Energy Technology Data Exchange (ETDEWEB)

    Li, Dien, E-mail: dien.li@srs.gov [Savannah River National Laboratory, Aiken, SC 29808 (United States); Egodawatte, Shani [Department of Chemistry, University of Iowa, Iowa City, IA 52242 (United States); Kaplan, Daniel I. [Savannah River National Laboratory, Aiken, SC 29808 (United States); Larsen, Sarah C. [Department of Chemistry, University of Iowa, Iowa City, IA 52242 (United States); Serkiz, Steven M. [Savannah River National Laboratory, Aiken, SC 29808 (United States); Department of Physics and Astronomy, Clemson University, Clemson, SC 29634 (United States); Seaman, John C. [Savannah River Ecology Laboratory, University of Georgia, Aiken, SC 29802 (United States)

    2016-11-05

    Highlights: • Magnetic mesoporous silica nanoparticles were functionalized with organic molecules. • The functionalized nanoparticles had high surface areas and consistent pore sizes. • The functionalized nanoparticles were easily separated due to their magnetism. • They exhibited high capacity for uranium removal from low- or high-pH groundwater. - Abstract: U(VI) species display limited adsorption onto sediment minerals and synthetic sorbents in pH <4 or pH >8 groundwater. In this work, magnetic mesoporous silica nanoparticles (MMSNs) with magnetite nanoparticle cores were functionalized with various organic molecules using post-synthetic methods. The functionalized MMSNs were characterized using N{sub 2} adsorption-desorption isotherms, thermogravimetric analysis (TGA), transmission electron microscopy (TEM), {sup 13}C cross polarization and magic angle spinning (CPMAS) nuclear magnetic resonance (NMR) spectroscopy, and powder X-ray diffraction (XRD), which indicated that mesoporous silica (MCM-41) particles of 100–200 nm formed around a core of magnetic iron oxide, and the functional groups were primarily grafted into the mesopores of ∼3.0 nm in size. The functionalized MMSNs were effective for U removal from pH 3.5 and 9.6 artificial groundwater (AGW). Functionalized MMSNs removed U from the pH 3.5 AGW by as much as 6 orders of magnitude more than unfunctionalized nanoparticles or silica and had adsorption capacities as high as 38 mg/g. They removed U from the pH 9.6 AGW as much as 4 orders of magnitude greater than silica and 2 orders of magnitude greater than the unfunctionalized nanoparticles with adsorption capacities as high as 133 mg/g. These results provide an applied solution for treating U contamination that occurs at extreme pH environments and a scientific foundation for solving critical industrial issues related to environmental stewardship and nuclear power production.

  4. High Temperature Gas-Cooled Reactor Projected Markets and Preliminary Economics

    Energy Technology Data Exchange (ETDEWEB)

    Larry Demick

    2011-08-01

    This paper summarizes the potential market for process heat produced by a high temperature gas-cooled reactor (HTGR), the environmental benefits reduced CO2 emissions will have on these markets, and the typical economics of projects using these applications. It gives examples of HTGR technological applications to industrial processes in the typical co-generation supply of process heat and electricity, the conversion of coal to transportation fuels and chemical process feedstock, and the production of ammonia as a feedstock for the production of ammonia derivatives, including fertilizer. It also demonstrates how uncertainties in capital costs and financial factors affect the economics of HTGR technology by analyzing the use of HTGR technology in the application of HTGR and high temperature steam electrolysis processes to produce hydrogen.

  5. Polyp Removal of a Bloom Forming Jellyfish, Aurelia coerulea, in Korean Waters and Its Value Evaluation

    Science.gov (United States)

    Yoon, Wonduk; Chae, Jinho; Koh, Byoung-Seol; Han, Changhoon

    2018-04-01

    Aurelia coerulea is a bloom forming jellyfish that first appeared before 1980 in the western and southern Korean seas and which has been blamed for huge economical losses in all fields of marine activities. As a preventive measure to reduce economical losses, polyp removal was undertaken at Lake Shihwa, Lake Saemangeum, and Masan Bay, Korea. In the course of efforts during 2 years to remove polyps, polyps were surveyed, quantified, and removed. In these areas, the initial total polyp abundance was 5.04 × 109 and 46.25% of them were removed; Lake Shihwa the highest rates of removal and Lake Saemangeum the lowest. These efforts to remove polyps prevented the appearance of 1.20 × 109 medusae, corresponding to 78.28 × 106 kg. The cost of polyp removal was evaluated and compared with that of medusae removal. The ratio between the cost of polyp removal and that of medusae removal ranged between 0.78-3.14%, indicating large cost savings for polyp removal undertakings. However, the effect of polyp removal varied from positive to none, and we assumed that the cleared surface for polyp removal, quantity of removed polyp, and existence of polyps' hotspots in neighboring areas were the causes of the non-effectiveness of polyp removal undertakings.

  6. Simultaneous removal of ammonia and N-nitrosamine precursors from high ammonia water by zeolite and powdered activated carbon.

    Science.gov (United States)

    Xue, Runmiao; Donovan, Ariel; Zhang, Haiting; Ma, Yinfa; Adams, Craig; Yang, John; Hua, Bin; Inniss, Enos; Eichholz, Todd; Shi, Honglan

    2018-02-01

    When adding sufficient chlorine to achieve breakpoint chlorination to source water containing high concentration of ammonia during drinking water treatment, high concentrations of disinfection by-products (DBPs) may form. If N-nitrosamine precursors are present, highly toxic N-nitrosamines, primarily N-nitrosodimethylamine (NDMA), may also form. Removing their precursors before disinfection should be a more effective way to minimize these DBPs formation. In this study, zeolites and activated carbon were examined for ammonia and N-nitrosamine precursor removal when incorporated into drinking water treatment processes. The test results indicate that Mordenite zeolite can remove ammonia and five of seven N-nitrosamine precursors efficiently by single step adsorption test. The practical applicability was evaluated by simulation of typical drinking water treatment processes using six-gang stirring system. The Mordenite zeolite was applied at the steps of lime softening, alum coagulation, and alum coagulation with powdered activated carbon (PAC) sorption. While the lime softening process resulted in poor zeolite performance, alum coagulation did not impact ammonia and N-nitrosamine precursor removal. During alum coagulation, more than 67% ammonia and 70%-100% N-nitrosamine precursors were removed by Mordenite zeolite (except 3-(dimethylaminomethyl)indole (DMAI) and 4-dimethylaminoantipyrine (DMAP)). PAC effectively removed DMAI and DMAP when added during alum coagulation. A combination of the zeolite and PAC selected efficiently removed ammonia and all tested seven N-nitrosamine precursors (dimethylamine (DMA), ethylmethylamine (EMA), diethylamine (DEA), dipropylamine (DPA), trimethylamine (TMA), DMAP, and DMAI) during the alum coagulation process. Copyright © 2017. Published by Elsevier B.V.

  7. Pollutant removal-oriented yeast biomass production from high-organic-strength industrial wastewater: A review

    International Nuclear Information System (INIS)

    Yang, Min; Zheng, Shaokui

    2014-01-01

    Microbial single-cell-protein (SCP) production from high-organic-strength industrial wastewaters is considered an attractive method for both wastewater purification and resource utilization. In the last two decades, pollutant removal-oriented yeast SCP production processes, i.e., yeast treatment processes, have attracted a great deal of attention from a variety of research groups worldwide. Different from conventional SCP production processes, yeast treatment processes are characterized by higher pollutant removal rates, lower production costs, highly adaptive yeast isolates from nature, no excess nutrient supplements, and are performed under non-sterile conditions. Furthermore, yeast treatment processes are similar to bacteria-dominated conventional activated sludge processes, which offer more choices for yeast SCP production and industrial wastewater treatment. This review discusses why highly adaptive yeast species isolated from nature are used in the yeast treatment process rather than commercial SCP producers. It also describes the application of yeast treatment processes for treating high-carboxyhydrate, oil-rich and high-salinity industrial wastewater, focusing primarily on high-strength biodegradable organic substances, which usually account for the major fraction of biochemical oxygen demand. Also discussed is the biodegradation of xenobiotics, such as color (including dye and pigment) and toxic substances (including phenols, chlorophenols, polycyclic aromatic hydrocarbons, etc.), present in industrial wastewater. Based on molecular information of yeast community structures and their regulation in yeast treatment systems, we also discuss how to maintain efficient yeast species in yeast biomass and how to control bacterial and mold proliferation in yeast treatment systems. - Highlights: • Pollutant removal-oriented yeast SCP production processes offer more choices. • Highly adaptive yeast isolates replace commercial SCP producers. • Yeasts degrade

  8. Performance of the prism reactor's passive decay heat removal system

    International Nuclear Information System (INIS)

    Magee, P.M.; Hunsbedt, A.

    1989-01-01

    The PRISM modular reactor concept has a totally passive safety-grade decay heat removal system referred to as the Reactor Vessel Auxiliary Cooling System (RVACS) that rejects heat from the reactor by radiation and natural convection of air. The system is inherently reliable and is not subject to the failure modes commonly associated with active cooling systems. The thermal performance of RVACS exceeds requirements and significant thermal margins exist. RVACS has been shown to perform its function under many postulated accident conditions. The PRISM power plant is equipped with three methods for shutdown: condenser cooling in conjunction with intermediate sodium and steam generator systems, and auxiliary cooling system (ACS) which removes heat from the steam generator by natural convection of air and transport of heat from the core by natural convection in the primary and intermediate systems, and a safety- grade reactor vessel auxiliary cooling system (RVACS) which removes heat passively from the reactor containment vessel by natural convection of air. The combination of one active and two passive systems provides a highly reliable and economical shutdown heat removal system. This paper provides a summary of the RVACS thermal performance for expected operating conditions and postulated accident events. The supporting experimental work, which substantiates the performance predictions, is also summarized

  9. Chitin/clay microspheres with hierarchical architecture for highly efficient removal of organic dyes.

    Science.gov (United States)

    Xu, Rui; Mao, Jie; Peng, Na; Luo, Xiaogang; Chang, Chunyu

    2018-05-15

    Numerous adsorbents have been reported for efficient removal of dye from water, but the high cost raw materials and complicated fabrication process limit their practical applications. Herein, novel nanocomposite microspheres were fabricated from chitin and clay by a simple thermally induced sol-gel transition. Clay nanosheets were uniformly embedded in a nanofiber weaved chitin microsphere matrix, leading to their hierarchical architecture. Benefiting from this unique structure, microspheres could efficiently remove methylene blue (MB) through a spontaneous physic-sorption process which fit well with pseudo-second-order and Langmuir isotherm models. The maximal values of adsorption capability obtained by calculation and experiment were 152.2 and 156.7 mg g -1 , respectively. Chitin/clay microspheres (CCM2) could remove 99.99% MB from its aqueous solution (10 mg g -1 ) within 20 min. These findings provide insight into a new strategy for fabrication of dye adsorbents with hierarchical structure from low cost raw materials. Copyright © 2018 Elsevier Ltd. All rights reserved.

  10. Low- and high-testosterone individuals exhibit decreased aversion to economic risk.

    Science.gov (United States)

    Stanton, Steven J; Mullette-Gillman, O'Dhaniel A; McLaurin, R Edward; Kuhn, Cynthia M; LaBar, Kevin S; Platt, Michael L; Huettel, Scott A

    2011-04-01

    Testosterone is positively associated with risk-taking behavior in social domains (e.g., crime, physical aggression). However, the scant research linking testosterone to economic risk preferences presents inconsistent findings. We examined the relationship between endogenous testosterone and individuals' economic preferences (i.e., risk preference, ambiguity preference, and loss aversion) in a large sample (N = 298) of men and women. We found that endogenous testosterone levels have a significant U-shaped association with individuals' risk and ambiguity preferences, but not loss aversion. Specifically, individuals with low or high levels of testosterone (more than 1.5 SD from the mean for their gender) were risk and ambiguity neutral, whereas individuals with intermediate levels of testosterone were risk and ambiguity averse. This relationship was highly similar in men and women. In contrast to received wisdom regarding testosterone and risk, the present data provide the first robust evidence for a nonlinear association between economic preferences and levels of endogenous testosterone.

  11. Highly Efficient Closed-Loop CO2 Removal System for Deep-Space ECLSS, Phase I

    Data.gov (United States)

    National Aeronautics and Space Administration — TDA Research Inc.(TDA) in collaboration with University of Puerto Rico ? Mayaguez (UPRM is proposing to develop a highly efficient CO2 removal system based on UPRM...

  12. Removal of Sb(III and Sb(V by Ferric Chloride Coagulation: Implications of Fe Solubility

    Directory of Open Access Journals (Sweden)

    Muhammad Ali Inam

    2018-04-01

    Full Text Available Coagulation and precipitation appear to be the most efficient and economical methods for the removal of antimony from aqueous solution. In this study, antimony removal from synthetic water and Fe solubility with ferric chloride (FC coagulation has been investigated. The effects of pH, FC dosage, initial antimony loading and mixed Sb(III, Sb(V proportions on Fe solubility and antimony removal were studied. The results showed that the Sb(III removal efficiency increased with the increase of solution pH particularly due to an increase in Fe precipitation. The Sb(V removal was influenced by the solution pH due to a change in Fe solubility. However, the Fe solubility was only impaired by the Sb(III species at optimum pH 7. The removal efficiencies of both Sb species were enhanced with an increase in FC dose. The quantitative analysis of the isotherm study revealed the strong adsorption potential of Sb(III on Fe precipitates as compared to Sb(V. Furthermore, the removal behavior of antimony was inhibited in mixed proportion with high Sb(V fraction. In conclusion, this study contributes to better understanding the fate of Sb species, their mobilities, and comparative removal behavior, with implications for Fe solubility using ferric chloride in different aqueous environments.

  13. High efficiency particulate removal with sintered metal filters

    International Nuclear Information System (INIS)

    Kirstein, B.E.; Paplawsky, W.J.; Pence, D.T.; Hedahl, T.G.

    1981-01-01

    Because of their particle removal efficiencies and durability, sintered metal filters have been chosen for high efficiency particulate air (HEPA) filter protection in the off-gas treatment system for the proposed Idaho National Engineering Laboratory Transuranic Waste Treatment Facility. Process evaluation of sintered metal filters indicated a lack of sufficient process design data to ensure trouble-free operation. Subsequence pilot scale testing was performed with flyash as the test particulate. The test results showed that the sintered metal filters can have an efficiency greater than 0.9999999 for the specific test conditions used. Stable pressure drop characteristics were observed in pulsed and reversed flow blowback modes of operation. Over 4900 hours of operation were obtained with operating conditions ranging up to approximately 90 0 C and 24 vol % water vapor in the gas stream

  14. Development and application of high performance resins for crud removal

    International Nuclear Information System (INIS)

    Deguchi, Tatsuya; Izumi, Takeshi; Hagiwara, Masahiro

    1998-01-01

    The development of crud removal technology has started with the finding of the resin aging effect that an old ion exchange resin, aged by long year of use in the condensate demineralizer, had an enhanced crud removal capability. It was confirmed that some physical properties such as specific surface area and water retention capacity were increased due to degradation caused by long year of contact with active oxygens in the condensate water. So, it was speculated that those degradation in the resin matrix enhanced the adsorption of crud particulate onto the resin surface, hence the crud removal capability. Based on this, crud removal resin with greater surface area was first developed. This resin has shown an excellent crud removal efficiency in an actual power plant, and the crud iron concentration in the condensate effluent was drastically reduced by this application. However, the cross-linkage of the cation resin had to be lowered in a delicate manner for that specific purpose, and this has caused higher organic leachables from the resin, and the sulfate level in the reactor was raised accordingly. Our major goals, therefore, has been to develop a crud resin of as little organic leachables as possible with keeping the original crud removal efficiency. It was revealed through the evaluation of the first generation crud resin and its improved version installed in the actual condensate demineralizers that there was a good correlation between crud removal efficiency and organic leaching rate. The bast one among a number of developmental resins has shown the organic leaching rate of 1/10 of that of the original crud resin (ETR-C), and the crud removal efficiency of 90%. So far as we understand, the resin was considered to have the best overall balance between crud removal and leaching characteristics. The result of six month evaluation of this developmental resin, ETR-C3, in one vessel of condensate demineralizer of a power plant will be presented. (J.P.N.)

  15. Pilot study points way to iron/manganese removal

    Energy Technology Data Exchange (ETDEWEB)

    Qureshi, N.; Barnes, A. [Progressive Consulting Engineers Inc., Minneapolis, MN (United States)

    1994-12-31

    The use of coal, greensand and sand in filters for removing iron and manganese from the Brooklyn Park, Minnesota, water supply was investigated. The most effective and economic treatment involved using a dual media filtration and potassium permanganate as the oxidant.

  16. Carbon dioxide removal with inorganic membranes

    Energy Technology Data Exchange (ETDEWEB)

    Judkins, R.R.; Fain, D.E. [Oak Ridge National Laboratory, TN (United States)

    1993-12-31

    The increasing concentrations of greenhouse gases, particularly carbon dioxide, in the atmosphere has sparked a great deal of interest in the removal of CO{sub 2} from flue gases of fossil fueled plants. Presently, several techniques for the removal of CO{sub 2} are considered to have potential, but are lacking in practicality. For example, amine scrubbing of flue gas streams is potential, but are lacking in practically. For example, amine scrubbing of flue gas streams is effective in removing CO{sub 2}, but costs are high; efficiency suffers; and other acid gases must be removed prior to amine stripping. Membrane systems for CO{sub 2} removal are held in high regard, and inorganic, particularly ceramic, membranes offer the potential for high temperature, thus energy saving, removal.

  17. Removal of actinide elements from high level radioactive waste by trialkylphosphine oxide (TRPO)

    International Nuclear Information System (INIS)

    Song Chongli; Yang Dazhu; He Longhai; Xu Jingming; Zhu Yongjun

    1992-03-01

    The modified TRPO process for removing actinide elements from synthetic solution, which was taken from reprocessing of power reactor nuclear fuel, was verified by cascade experiment. Neptunium valence was adjusted in the process for improving neptunium removing efficiency. At 1 mol/L concentration of HNO 3 of feed solution and after a few stages of extraction with 30% t=TRPO kerosene, over 99.9% of Am, Pu, Np and U could be removed from HAW (high level radioactive waste) solution. The stripping of actinides loaded in TRPO are accomplished by high concentration nitric acid, oxalic acid and sodium carbonate instead of amino carboxylic complexing agents used in previous process. The actinides stripped were divided into three groups, which are Am + RE, Np + Pu, and U, and the cross contamination between them is small. Behaviours of F.P. elements are divided into three types which are not extracted, little extracted and extracted elements. The extracted elements are rare earth and Pd, Zr and Mo which are co-extracted with actinides. The separation factor between actinides and other two types of F.P.elements will increase if more scrubbing sections are added in the process. The relative concentration profile of actinide elements and Tc in various stages as well as the distribution of actinides and F.P. elements in the process stream solutions are also presented

  18. IMF and economic reform in developing countries

    DEFF Research Database (Denmark)

    Abbott, Philip; Andersen, Thomas Barnebeck; Tarp, Finn

    2010-01-01

    approach is in order. However, the cross-country approach is unlikely to provide a sound basis for drawing clear conclusions, so we review IMF programs from a different perspective, involving a broader literature on development strategy. In particular, it is widely accepted that a common characteristic......In this paper we assess the IMF approach to economic reform in developing countries. The impact of IMF program participation on economic growth has been evaluated empirically in a cross-country literature, with little evidence of IMF programs having been successful. This suggests that a fresh...... of IMF programs is a high degree of policy rigidity. This is in contrast with studies which hold that unleashing an economy's growth potential hinges on a set of well-targeted policy interventions aimed at removing country-specific binding constraints. The process of locating constraints that bind...

  19. Banana Peel: A Green and Economical Sorbent for Cr(III Removal

    Directory of Open Access Journals (Sweden)

    Jamil R. Memon

    2008-06-01

    Full Text Available Banana peel, a common fruit waste has been investigated to remove and preconcentrate Cr(III from industrial wastewater. It was characterized by FT-IR spectroscopy. The parameters pH, contact time, initial metal ion concentration and temperature were investigated and the maximum sorption was found to be 95%. The binding of metal ions was found to be pH dependent with the optimal sorption occurring at pH 4. The retained species were eluted using 5mL of 2 M HNO3. The mechanism for the binding of Cr(III on the banana peel surface was also studied in detail. The Langmuir and Dubinin-Radushkevich (D-R isotherms were used to describe the partitioning behavior for the system at different temperatures. Kinetic and thermodynamic measurements of the banana peel for chromium ions were also studied. The method was applied for the removal and preconcentration of Cr(III from industrial wastewater.

  20. Banana peel: a green and economical sorbent for Cr(III) removal

    International Nuclear Information System (INIS)

    Memon, J.R.; Bhanger, M.I.; Memon, S.Q.

    2008-01-01

    Banana peel, a common fruit waste has been investigated to remove and preconcentrate Cr(III) from industrial wastewater. It was characterized by FT-IR spectroscopy. The parameters pH, contact time, initial metal ion concentration and temperature were investigated and the maximum sorption was found to be 95%. The binding of metal ions was found to be pH dependent with the optimal sorption occurring at pH 4. The retained species were eluted using 5 ml of 2 M HNO/sub 3/. The mechanism for the binding of Cr(III) on the banana peel surface was also studied in detail. The Langmuir and Dubinin-Radushkevich (D-R) isotherms were used to describe the partitioning behavior for the system at different temperatures. Kinetic and thermodynamic measurements of the banana peel for chromium ions were also studied. The method was applied for the removal and preconcentration of Cr(III) from industrial wastewater. (author)

  1. Electro-coagulation-flotation process for algae removal

    International Nuclear Information System (INIS)

    Gao Shanshan; Yang Jixian; Tian Jiayu; Ma Fang; Tu Gang; Du Maoan

    2010-01-01

    Algae in surface water have been a long-term issue all over the world, due to their adverse influence on drinking water treatment process as well as drinking water quality. The algae removal by electro-coagulation-flotation (ECF) technology was investigated in this paper. The results indicated that aluminum was an excellent electrode material for algae removal as compared with iron. The optimal parameters determined were: current density = 1 mA/cm 2 , pH = 4-7, water temperature = 18-36 deg. C, algae density = 0.55 x 10 9 -1.55 x 10 9 cells/L. Under the optimal conditions, 100% of algae removal was achieved with the energy consumption as low as 0.4 kWh/m 3 . The ECF performed well in acid and neutral conditions. At low initial pH of 4-7, the cell density of algae was effectively removed in the ECF, mainly through the charge neutralization mechanism; while the algae removal worsened when the pH increased (7-10), and the main mechanism shifted to sweeping flocculation and enmeshment. The mechanisms for algae removal at different pH were also confirmed by atomic force microscopy (AFM) analysis. Furthermore, initial cell density and water temperature could also influence the algae removal. Overall, the results indicated that the ECF technology was effective for algae removal, from both the technical and economical points of view.

  2. Platform decommissioning: Socio-economic impacts

    International Nuclear Information System (INIS)

    Scheelhaase, Janina D.

    1998-01-01

    The object of this presentation is to evaluate the socio-economic effects of the decommissioning of steel jacket platforms in the North Sea and in the North East Atlantic in the period up to 2020 in their entirety. It is focused on two different decommissioning options, namely total and partial removal of installations. Partial removal applies only to installations in water deeper than 75 meters. All other installations, i.e those in waters shallower than 75 meters, have to be totally removed and brought onshore for disposal. Areas being analyzed cover costs of different decommissioning options, effects of the different options on employment, fiscal aspects of the different options, and aspects of recycling onshore. 6 figs., 13 tabs

  3. Algae-facilitated chemical phosphorus removal during high-density Chlorella emersonii cultivation in a membrane bioreactor.

    Science.gov (United States)

    Xu, Meng; Bernards, Matthew; Hu, Zhiqiang

    2014-02-01

    An algae-based membrane bioreactor (A-MBR) was evaluated for high-density algae cultivation and phosphorus (P) removal. The A-MBR was seeded with Chlorella emersonii and operated at a hydraulic retention time of 1day with minimal biomass wastage for about 150days. The algae concentration increased from initially 385mg/L (or 315mg biomass COD/L) to a final of 4840mg/L (or 1664mg COD/L), yielding an average solids (algae biomass+minerals) production rate of 32.5gm(-3)d(-1) or 6.2gm(-2)d(-1). The A-MBR was able to remove 66±9% of the total P from the water while the algal biomass had an average of 7.5±0.2% extracellular P and 0.4% of intracellular P. The results suggest that algae-induced phosphate precipitation by algae is key to P removal and high-density algae cultivation produces P-rich algal biomass with excellent settling properties. Copyright © 2013 Elsevier Ltd. All rights reserved.

  4. Continuous phenol removal using Nocardia hydrocarbonoxydans in ...

    African Journals Online (AJOL)

    STORAGESEVER

    2009-02-18

    Feb 18, 2009 ... be removed from waste stream before discharge. Biodegradation of phenol is a widely used method as it is economical and easy to operate as compared to chemi- cal, physical, electrochemical or advanced oxidation process. Attached growth processes have advantage of retain- ing more biomass in the ...

  5. Mercury removal from liquid and solid mixed waste

    International Nuclear Information System (INIS)

    Gates, D.D.; Klasson, K.T.; Corder, S.L.; Cameron, P.A.; Perona, J.J.

    1995-01-01

    Based on bench-scale laboratory experiments, the following conclusions were reached: Sulfur-impregnated, activated, carbon pellets (Mersorb) can be used to remove mercury (Hg 2+ ) to below EPA's toxic characteristic level (0.2 mg/L). Mersorb works under acid conditions (pH 2) but its capacity is reduced by approximately 50% compared with neutral conditions. Competing ions present in the target waste stream reduced the Mersorb capacity by 50%. Mersorb appears to be economical compared with leading ion exchange resin. KI/I 2 leaching solution can be used to remove up to 99% of Hg in contaminated soil and glass. KI/I 2 leaching solution worked well with several mercury species, including Hg 0 , HgO, HgS, and HgCl 2 . KI/I 2 leaching solution worked well with a wide variety of initial mercury concentrations. Radionuclide surrogate studies suggested that uranium will not partition into KI/I 2 leaching solutions. Cesium may partition into the KI/I 2 leaching solution because of the high solubility of cesium salts

  6. Soil bacterial community shifts associated with sugarcane straw removal

    Science.gov (United States)

    Pimentel, Laisa; Gumiere, Thiago; Andreote, Fernando; Cerri, Carlos

    2017-04-01

    In Brazil, the adoption of the mechanical unburned sugarcane harvest potentially increase the quantity of residue left in the field after harvesting. Economically, this material has a high potential for second generation ethanol (2G) production. However, crop residues have an essential role in diverse properties and processes in the soil. The greater part of the uncertainties about straw removal for 2G ethanol production is based on its effects in soil microbial community. In this sense, it is important to identify the main impacts of sugarcane straw removal on soil microbial community. Therefore, we conducted a field study, during one year, in Valparaíso (São Paulo state - Brazil) to evaluate the effects of straw decomposition on soil bacterial community. Specifically, we wanted: i) to compare the rates of straw removal and ii) to evaluate the effects of straw decomposition on soil bacterial groups over one year. The experiment was in a randomized block design with treatments arranged in strip plot. The treatments are different rates of sugarcane straw removal, namely: no removal, 50, 75 and 100% of straw removal. Soil sampling was carried out at 0, 4, 8 and 12 months after the sugarcane harvest (August 2015). Total DNA was extracted from soil using the PowersoilTM DNA Isolation kit. And the abundance of bacterial in each soil sample was estimated via quantification of 16S rRNA gene. The composition of the bacterial communities was estimated via terminal restriction fragment length polymorphism (T-RFLP) analysis, and the T-RF sizes were performed on a 3500 Genetic Analyzer. Finally, the results were examined with GeneMapper 4.1 software. There was bacterial community shifts through the time and among the rates of sugarcane straw removal. Bacterial community was firstly determined by the time scale, which explained 29.16% of total variation. Rates of straw removal explained 11.55% of shifts on bacterial community. Distribution through the time is an important

  7. Rapid removal of bisphenol A on highly ordered mesoporous carbon.

    Science.gov (United States)

    Sui, Qian; Huang, Jun; Liu, Yousong; Chang, Xiaofeng; Ji, Guangbin; Deng, Shubo; Xie, Tao; Yu, Gang

    2011-01-01

    Bisphenol A (BPA) is of global concern due to its disruption of endocrine systems and ubiquity in the aquatic environment. It is important, therefore, that efforts are made to remove it from the aqueous phase. A novel adsorbent, mesoporous carbon CMK-3, prepared from hexagonal SBA-15 mesoporous silica was studied for BPA removal from aqueous phase, and compared with conventional powdered activated carbon (PAC). Characterization of CMK-3 by transmission electron microscopy (TEM), X-ray diffraction, and nitrogen adsorption indicated that prepared CMK-3 had an ordered mesoporous structure with a high specific surface area of 920 m2/g and a pore-size of about 4.9 nm. The adsorption of BPA on CMK-3 followed a pseudo second-order kinetic model. The kinetic constant was 0.00049 g/(mg x min), much higher than the adsorption of BPA on PAC. The adsorption isotherm fitted slightly better with the Freundlich model than the Langmuir model, and adsorption capacity decreased as temperature increased from 10 to 40 degrees C. No significant influence of pH on adsorption was observed at pH 3 to 9; however, adsorption capacity decreased dramatically from pH 9 to 13.

  8. Electrocoagulation (EC and Electrocoagulation/Flotation(ECF Processes for Removing High Turbidity from Surface Water Using Al and Fe Electrodes

    Directory of Open Access Journals (Sweden)

    Ghorban Asgari

    2013-08-01

    Full Text Available Electrocoagulation (EC and Electrocoagulation/flotation (ECF processes are simple and efficient in water and wastewater treatment. In recent years, many investigations have focused on the use of these processes for treating of polluted water. The purpose of this study was to investigate the efficiency of EC and ECF processes in removal of high turbidity water using different electrodes in different circumstances. In present study an electrocoagulation and electrocoagulation/ flotation reactor in a lab scale to an approximate volume of 6 liters which is equipped with four Al-AL and Fe-Fe electrodes (200 * 20 * 2 mm was used  for removing of high turbidity water. The effects of operating parameters such as type of electrodes, initial water turbidity, applied voltage (10 to 30 v, initial pH of the solution (3 to 12 and reaction times (5 to 30 minutes were evaluated. The batch experimental results showed that initial turbidity water, initial pH of the solution, different applied voltages up to %88 turbidity as initial turbidity of 1200 NTU have been removed when using Al-Al and Fe-Fe electrodes and reaction times highly effective on the turbidity removal efficiency in these processes. In ECF process, 84% in optimum condition. However, in EC  process the maximum removal was found  up to 68% of initial turbidity when using Al-Al and Fe-Fe electrodes in same operation. Based on the result obtained in this study, the type of electrodes in EC and ECF processes  significantly affect the removal rate of high turbid water. Also, it was found that much higher turbidity removal could be achieved by ECF process than that by EC process in the same condition.

  9. How does Socio-Economic Factors Influence Interest to Go to Vocational High Schools?

    Science.gov (United States)

    Utomo, N. F.; Wonggo, D.

    2018-02-01

    This study is aimed to reveal the interest of the students of junior high schools in Sangihe Islands, Indonesia, to go to vocational high schools and the affecting factors. This study used the quantitative method with the ex-post facto approach. The population consisted of 332 students, and the sample of 178 students was established using the proportional random sampling technique applying Isaac table’s 5% error standard. The results show that family’s socio-economic condition positively contributes 26% to interest to go to vocational high schools thus proving that family’s socio-economic condition is influential and contribute to junior high school students’ interest to go to vocational high schools.

  10. Removal of Aerosol Particles Generated from Vitrification Process for High-Level Liquid Wastes

    OpenAIRE

    加藤 功

    1990-01-01

    The vitrification technology has been developed for the high-level liquid waste (HLLW) from reprocessing nuclear spent fuel in PNC. The removal performance of the aerosol particles generated from the melting process was studied in a nonradioactive full-scale mock-up test facility (MTF). The off-gas treatment system consists of submerged bed scrubber (SBS), venturi scrubber, NOx absorber, high efficiency mist eliminater (HEME). Deoomtamination factors (DFs) were derived from the mass ratio of ...

  11. After-heat removing device

    International Nuclear Information System (INIS)

    Iwashige, Kengo; Otsuka, Masaya; Yokoyama, Iwao; Yamakawa, Masanori.

    1990-01-01

    The present invention concerns an after-heat removing device for first reactors. A heat accumulation portion provided in a cooling channel of an after-heat removing device is disposed before a coil-like heat conduction pipe for cooling of the after-heat removing device. During normal reactor operation, the temperature in the heat accumulation portion is near the temperature of the high temperature plenum due to heat conduction and heat transfer from the high temperature plenum. When the reactor is shutdown and the after-heat removing device is started, coolants cooled in the air cooler start circulation. The coolants arriving at the heat accumulation portion deprive heat from the heat accumulation portion and, ion turn, increase their temperature and then reach the cooling coil. Subsequently, the heat calorie possessed in the heat accumulation portion is reduced and the after-heat removing device is started for the operation at a full power. This can reduce the thermal shocks applied to the cooling coil or structures in a reactor vessel upon starting the after-heat removing device. (I.N.)

  12. Study on characteristics of high frequency dielectric barrier discharge for the removal of organic pollutant adsorbed on activated carbon

    Energy Technology Data Exchange (ETDEWEB)

    Qu, G.Z.; Li, G.F. [Dalian Univ. of Technology, Dalian (China). Inst. of Electrostatics and Special Power; Li, J.; Lu, N.; Wu, Y.; Li, D. [Dalian Univ. of Technology, Dalian (China). Inst. of Electrostatics and Special Power; Key Lab of Industrial Ecology and Environmental Engineering, Ministry of Education, Dalian (China)

    2010-07-01

    Advanced oxidation technologies such as photocatalysis, electrochemical degradation, Fenton oxidation, hydrogen peroxide oxidation, and plasma oxidation are increasingly being used to degrade refractory biodegradable organic contaminants. The plasma oxidation method has the advantage of direct in situ production of multiple types of high-reactive chemical species, including molecules and radicals that facilitate the degradation reaction. In addition, plasma oxidation does not produce any secondary pollution. Compared to other plasma technologies, the dielectric barrier discharge (DBD) plasma has been considered as a promising technology for removing toxic compounds because of its stability and its treatability property of biologically recalcitrant compounds in wastewater. However, the energy efficiency of DBD requires improvement for economic reasons. This paper reported on an experimental study that investigated the electrical characteristics of a parallel plate DBD reactor using a high frequency power supply for the removal of pentachlorophenol (PCP) adsorbed on activated carbon (AC). This study examined the effects of AC with different mass on discharge characteristics and compared the voltage and current waveforms, and discharge images of DBD reactors with different dielectric configurations. When the DBD reactor filled with AC, the applied voltage of discharge decreased regardless of the DBD reactor configuration in terms of having a single barrier or two barriers. The discharge characteristics had no significant change with AC mass increasing. The discharge images and current waveforms showed that DBD reactor configuration consisting of two dielectrics is more homogeneous and stable than the one consisting of a single dielectric. Under the same electric field condition, the degradation efficiency of PCP in two barriers reactor is higher than that in single barrier reactor. It was concluded that the findings from this study may be instrumental in treating

  13. Nitrogen removal from coal gasification wastewater by activated carbon technologies combined with short-cut nitrogen removal process.

    Science.gov (United States)

    Zhao, Qian; Han, Hongjun; Hou, Baolin; Zhuang, Haifeng; Jia, Shengyong; Fang, Fang

    2014-11-01

    A system combining granular activated carbon and powdered activated carbon technologies along with shortcut biological nitrogen removal (GAC-PACT-SBNR) was developed to enhance total nitrogen (TN) removal for anaerobically treated coal gasification wastewater with less need for external carbon resources. The TN removal efficiency in SBNR was significantly improved by introducing the effluent from the GAC process into SBNR during the anoxic stage, with removal percentage increasing from 43.8%-49.6% to 68.8%-75.8%. However, the TN removal rate decreased with the progressive deterioration of GAC adsorption. After adding activated sludge to the GAC compartment, the granular carbon had a longer service-life and the demand for external carbon resources became lower. Eventually, the TN removal rate in SBNR was almost constant at approx. 43.3%, as compared to approx. 20.0% before seeding with sludge. In addition, the production of some alkalinity during the denitrification resulted in a net savings in alkalinity requirements for the nitrification reaction and refractory chemical oxygen demand (COD) degradation by autotrophic bacteria in SBNR under oxic conditions. PACT showed excellent resilience to increasing organic loadings. The microbial community analysis revealed that the PACT had a greater variety of bacterial taxons and the dominant species associated with the three compartments were in good agreement with the removal of typical pollutants. The study demonstrated that pre-adsorption by the GAC-sludge process could be a technically and economically feasible method to enhance TN removal in coal gasification wastewater (CGW). Copyright © 2014. Published by Elsevier B.V.

  14. Comparison of coagulation, ozone and ferrate treatment processes for color, COD and toxicity removal from complex textile wastewater.

    Science.gov (United States)

    Malik, Sameena N; Ghosh, Prakash C; Vaidya, Atul N; Waindeskar, Vishal; Das, Sera; Mudliar, Sandeep N

    2017-09-01

    In this study, the comparative performance of coagulation, ozone, coagulation + ozone + coagulation and potassium ferrate processes to remove chemical oxygen demand (COD), color, and toxicity from a highly polluted textile wastewater were evaluated. Experimental results showed that ferrate alone had no effect on COD, color and toxicity removal. Whereas, in combination with FeSO 4 , it has shown the highest removal efficiency of 96.5%, 83% and 75% for respective parameters at the optimal dose of 40 mgL -1 + 3 ml FeSO 4 (1 M) in comparison with other processes. A seed germination test using seeds of Spinach (Spinacia oleracea) also indicated that ferrate was more effective in removing toxicity from contaminated textile wastewater. Potassium ferrate also produces less sludge with maximum contaminant removal, thereby making the process more economically feasible. Fourier transform infrared spectroscopy (FTIR) analysis also shows the cleavage of the chromophore group and degradation of textile wastewater during chemical and oxidation treatment processes.

  15. [Removal of high-abundance proteins in plasma of the obese by improved TCA/acetone precipitation method].

    Science.gov (United States)

    Wang, Jun; Feng, Liru; Yu, Wei; Xu, Jian; Yang, Hui; Liu, Xiaoli

    2013-09-01

    To develop an improved trichloroacetic acid (TCA)/acetone precipitation method for removal of high-abundance proteins in plasma of the obese. Volumes of TCA/acetone solution (1, 3, 4, 5, 6, 8, 10 and 20 times of the sample) and concentrations of TCA (10%, 30%, 50%, 60%, 70% TCA/acetone solution) have been investigated to optimize the conditions of sample preparation. SDS-PAGE were used to separate and tested proteins in the supernatant and sediment. The best concentration of the TCA/acetone solution was first determined by SDS-PAGE. The protein in precipitation from 10% TCA/acetone solution processing and the new determined concentration TCA/acetone solution processing were verified by 2-D-SDS-PAGE. And then the digested products of the protein in precipitation and supernatant by trypsin were analyzed by nano HPLC-Chip-MS/MS to verify which is the best concentration to process the plasma. The best volume of TCA/acetone is four times to sample, which less or more TCA/acetone would reduce the removal efficiency of high-abundance proteins. The concentration of TCA in acetone solution should be 60%, which may remove more high-abundance proteins in plasma than 10%, 30%, 50% TCA in acetone solution. If the TCA concentration is more than 60%, the reproducibility will be much poorer due to fast precipitation of proteins. The results of mass identification showed that human plasma prepared with 60% TCA/acetone (4 times sample volume) could be verified more low-abundance proteins than 10%. The most desirable conditions for removal of high-abundance proteins in plasma is 60% TCA/acetone (4 times sample volume), especially for the plasma of obesity.

  16. Environmental and economic assessment of the chemical absorption process in Korea using the LEAP model

    International Nuclear Information System (INIS)

    Song, Ho-Jun; Lee, Seungmoon; Maken, Sanjeev; Ahn, Se-Woong; Park, Jin-Won; Min, Byoungryul; Koh, Wongun

    2007-01-01

    CO 2 emission from fossil fuels is a major cause for the global warming effect, but it is hard to remove completely in actuality. Moreover, energy consumption is bound to increase for the continuous economic development of a country that has an industrial formation requiring high-energy demand. Therefore, we need to consider not only a device for CO 2 mitigation but also its impact when a CO 2 mitigation device is applied. The device for CO 2 emission mitigation can be classified into three fields: energy consumption reduction, development of CO 2 removal and recovery technology, and development of alternative energy technology. Among these options, CO 2 removal and recovery technology has a merit that can be applied to a process in the near future. Therefore, research for CO 2 removal and recovery is actively progressing in Korea. In this study, environmental and economic assessment according to the energy policy change for climate change agreement and increase of CO 2 mitigation technology is accomplished, on the bases of operating data for the CO 2 chemical absorption pilot plant that is installed in the Seoul coal steam power plant. The Long-range Energy Alternatives Planning system (LEAP) was used to analyze the alternative scenario, and results were shown quantitatively

  17. Demographic changes following mechanical removal of exotic brown trout in an Intermountain West (USA), high-elevation stream

    Science.gov (United States)

    Saunders, W. Carl; Budy, Phaedra E.; Thiede, Gary P.

    2015-01-01

    Exotic species present a great threat to native fish conservation; however, eradicating exotics is expensive and often impractical. Mechanical removal can be ineffective for eradication, but nonetheless may increase management effectiveness by identifying portions of a watershed that are strong sources of exotics. We used mechanical removal to understand processes driving exotic brown trout (Salmo trutta) populations in the Logan River, Utah. Our goals were to: (i) evaluate the demographic response of brown trout to mechanical removal, (ii) identify sources of brown trout recruitment at a watershed scale and (iii) evaluate whether mechanical removal can reduce brown trout densities. We removed brown trout from 2 km of the Logan River (4174 fish), and 5.6 km of Right Hand Fork (RHF, 15,245 fish), a low-elevation tributary, using single-pass electrofishing. We compared fish abundance and size distributions prior to, and after 2 years of mechanical removal. In the Logan River, immigration to the removal reach and high natural variability in fish abundances limited the response to mechanical removal. In contrast, mechanical removal in RHF resulted in a strong recruitment pulse, shifting the size distribution towards smaller fish. These results suggest that, before removal, density-dependent mortality or emigration of juvenile fish stabilised adult populations and may have provided a source of juveniles to the main stem. Overall, in sites demonstrating strong density-dependent population regulation, or near sources of exotics, short-term mechanical removal has limited effects on brown trout populations but may help identify factors governing populations and inform large-scale management of exotic species.

  18. An innovative pool with a passive heat removal system

    International Nuclear Information System (INIS)

    Vitale Di Maio, Damiano; Naviglio, Antonio; Giannetti, Fabio; Manni, Fabio

    2012-01-01

    Heat removal systems are of primary importance in several industrial processes. As heat sink, a water pool or atmospheric air may be selected. The first solution takes advantage of high heat transfer coefficient with water but it requires active systems to maintain a constant water level; the second solution takes benefit from the unlimited heat removal capacity by air, but it requires a larger heat exchanger to compensate the lower heat transfer coefficient. In NPPs (nuclear power plants) during a nuclear reactor shutdown, as well as in some chemical plants to control runaway reactions, it is possible to use an innovative heat sink that joins the advantages of the two previous solutions. This solution is based on a special heat exchanger submerged in a water pool designed so that when heat removal is requested, active systems are not required to maintain the water level; due to the special design, when the pool is empty, atmospheric air becomes the only heat sink. The special heat exchanger design allows to have a heat exchanger without being oversized and to have a system able to operate for unlimited period without external interventions. This innovative system provides an economic advantage as well as enhanced safety features.

  19. Economic efficiency of application of innovative materials and structures in high-rise construction

    Science.gov (United States)

    Golov, Roman; Dikareva, Varvara; Gorshkov, Roman; Agarkov, Anatoly

    2018-03-01

    The article is devoted to the analysis of technical and economic efficiency of application of tube confined concrete structures in high-rise construction. The study of comparative costs of materials with the use of different supporting columns was carried out. The main design, operational, technological and economic advantages of the tube confined concrete technology were evaluated, conclusions were drawn about the high strength and deformation properties of axial compression of steel tubes filled with high-strength concrete. The efficiency of the tube confined concrete use is substantiated, which depends mainly on the scale factor and percentage of reinforcement affecting its load-bearing capacity.

  20. Fluoroscopy-Guided Percutaneous Gallstone Removal Using a 12-Fr Sheath in High-Risk Surgical Patients with Acute Cholecystitis

    International Nuclear Information System (INIS)

    Kim, Young Hwan; Kim, Yong Joo; Shin, Tae Beom

    2011-01-01

    To evaluate the technical feasibility and clinical efficacy of percutaneous transhepatic cholecystolithotomy under fluoroscopic guidance in high-risk surgical patients with acute cholecystitis. Sixty-three consecutive patients of high surgical risk with acute calculous cholecystitis underwent percutaneous transhepatic gallstone removal under conscious sedation. The stones were extracted through the 12-Fr sheath using a Wittich nitinol stone basket under fluoroscopic guidance on three days after performing a percutaneous cholecystostomy. Large or hard stones were fragmented using either the snare guide wire technique or the metallic cannula technique. Gallstones were successfully removed from 59 of the 63 patients (94%). Reasons for stone removal failure included the inability to grasp a large stone in two patients, and the loss of tract during the procedure in two patients with a contracted gallbladder. The mean hospitalization duration was 7.3 days for acute cholecystitis patients and 9.4 days for gallbladder empyema patients. Bile peritonitis requiring percutaneous drainage developed in two patients. No symptomatic recurrence occurred during follow-up (mean, 608.3 days). Fluoroscopy-guided percutaneous gallstone removal using a 12-Fr sheath is technically feasible and clinically effective in high-risk surgical patients with acute cholecystitis

  1. Fluoroscopy-Guided Percutaneous Gallstone Removal Using a 12-Fr Sheath in High-Risk Surgical Patients with Acute Cholecystitis

    Energy Technology Data Exchange (ETDEWEB)

    Kim, Young Hwan [Keimyung University, College of Medicine, Daegu (Korea, Republic of); Kim, Yong Joo [Andong General Hospital, Andong (Korea, Republic of); Shin, Tae Beom [Gyeonsang National University, College of Medicine, Jinju (Korea, Republic of)

    2011-04-15

    To evaluate the technical feasibility and clinical efficacy of percutaneous transhepatic cholecystolithotomy under fluoroscopic guidance in high-risk surgical patients with acute cholecystitis. Sixty-three consecutive patients of high surgical risk with acute calculous cholecystitis underwent percutaneous transhepatic gallstone removal under conscious sedation. The stones were extracted through the 12-Fr sheath using a Wittich nitinol stone basket under fluoroscopic guidance on three days after performing a percutaneous cholecystostomy. Large or hard stones were fragmented using either the snare guide wire technique or the metallic cannula technique. Gallstones were successfully removed from 59 of the 63 patients (94%). Reasons for stone removal failure included the inability to grasp a large stone in two patients, and the loss of tract during the procedure in two patients with a contracted gallbladder. The mean hospitalization duration was 7.3 days for acute cholecystitis patients and 9.4 days for gallbladder empyema patients. Bile peritonitis requiring percutaneous drainage developed in two patients. No symptomatic recurrence occurred during follow-up (mean, 608.3 days). Fluoroscopy-guided percutaneous gallstone removal using a 12-Fr sheath is technically feasible and clinically effective in high-risk surgical patients with acute cholecystitis

  2. Economics (A High School One Semester Course). Instructional Materials/Resources for Social Studies.

    Science.gov (United States)

    Jackstadt, Stephen L.; And Others

    Designed to aid teachers of a high school economics course, this curriculum guide is presented in self-contained units of study. Thirteen units, each with specific lessons, cover economic problems, the market system, market structure, market imperfections, government regulation, the national economy, aggregate supply and demand, the business…

  3. Study of composite adsorbent synthesis and characterization for the removal of Cs in the high-salt and high-radioactive wastewater

    Energy Technology Data Exchange (ETDEWEB)

    Kim, Jimin; Lee, Keun Young; Kim, Kwang Wook; Lee, Eil Hee; Chung, Dong Yong; Moon, Jei Kwon [Korea Atomic Energy Research Institute, Daejeon (Korea, Republic of); Hyun, Jae Hyuk [Chungnam National University, Daejeon (Korea, Republic of)

    2017-03-15

    For the removal of cesium (Cs) from high radioactive/high salt-laden liquid waste, this study synthesized a highly efficient composite adsorbent (potassium cobalt ferrocyanide (PCFC)-loaded chabazite (CHA)) and evaluated its applicability. The composite adsorbent used CHA, which could accommodate Cs as well as other molecules, as a supporting material and was synthesized by immobilizing the PCFC in the pores of CHA through stepwise impregnation/precipitation with CoCl{sub 2} and K{sub 4}Fe (CN){sub 6} solutions. When CHA, with average particle size of more than 10 μm, is used in synthesizing the composite adsorbent, the PCFC particles were immobilized in a stable form. Also, the physical stability of the composite adsorbent was improved by optimizing the washing methodology to increase the purity of the composite adsorbent during the synthesis. The composite adsorbent obtained from the optimal synthesis showed a high adsorption rate of Cs in both fresh water (salt-free condition) and seawater (high-salt condition), and had a relatively high value of distribution coefficient (larger than 10{sup 4} mL·g{sup -1}) regardless of the salt concentration. Therefore, the composite adsorbent synthesized in this study is an optimized material considering both the high selectivity of PCFC on Cs and the physical stability of CHA. It is proved that this composite adsorbent can remove rapidly Cs contained in high radioactive/high salt-laden liquid waste with high efficiency.

  4. Medium-high frequency ultrasound and ozone based advanced oxidation for amoxicillin removal in water.

    Science.gov (United States)

    Kıdak, Rana; Doğan, Şifa

    2018-01-01

    In this study, treatment of an antibiotic compound amoxicillin by medium-high frequency ultrasonic irradiation and/or ozonation has been studied. Ultrasonic irradiation process was carried out in a batch reactor for aqueous amoxicillin solutions at three different frequencies (575, 861 and 1141kHz). The applied ultrasonic power was 75W and the diffused power was calculated as 14.6W/L. The highest removal was achieved at 575kHz ultrasonic frequency (>99%) with the highest pseudo first order reaction rate constant 0.04min -1 at pH 10 but the mineralization achieved was around 10%. Presence of alkalinity and humic acid species had negative effect on the removal efficiency (50% decrease). To improve the poor outcomes, ozonation had been applied with or without ultrasound. Ozone removed the amoxicillin at a rate 50 times faster than ultrasound. Moreover, due to the synergistic effect, coupling of ozone and ultrasound gave rise to rate constant of 2.5min -1 (625 times higher than ultrasound). In the processes where ozone was used, humic acid did not show any significant effect because the rate constant was so high that ozone has easily overcome the scavenging effects of natural water constituents. Furthermore, the intermediate compounds, after the incomplete oxidation mechanisms, has been analyzed to reveal the possible degradation pathways of amoxicillin through ultrasonic irradiation and ozonation applications. The outcomes of the intermediate compounds experiments and the toxicity was investigated to give a clear explanation about the safety of the resulting solution. The relevance of all the results concluded that hybrid advanced oxidation system was the best option for amoxicillin removal. Copyright © 2017 Elsevier B.V. All rights reserved.

  5. Biological phosphorus removal during high-rate, low-temperature, anaerobic digestion of wastewater

    Directory of Open Access Journals (Sweden)

    Ciara eKeating

    2016-03-01

    Full Text Available We report, for the first time, extensive biologically-mediated phosphate removal from wastewater during high-rate anaerobic digestion (AD. A hybrid sludge bed/fixed-film (packed pumice stone reactor was employed for low-temperature (12°C anaerobic treatment of synthetic sewage wastewater. Successful phosphate removal from the wastewater (up to 78% of influent phosphate was observed, mediated by biofilms in the reactor. Scanning electron microscopy and energy dispersive X-ray analysis revealed the accumulation of elemental phosphorus (~2% within the sludge bed and fixed-film biofilms. 4’, 6-diamidino-2-phenylindole (DAPI staining indicated phosphorus accumulation was biological in nature and mediated through the formation of intracellular inorganic polyphosphate (polyP granules within these biofilms. DAPI staining further indicated that polyP accumulation was rarely associated with free cells. Efficient and consistent chemical oxygen demand (COD removal was recorded, throughout the 732-day trial, at applied organic loading rates between 0.4-1.5 kg COD m-3 d-1 and hydraulic retention times of 8-24 hours, while phosphate removal efficiency ranged from 28-78% on average per phase. Analysis of protein hydrolysis kinetics and the methanogenic activity profiles of the biomass revealed the development, at 12˚C, of active hydrolytic and methanogenic populations. Temporal microbial changes were monitored using Illumina Miseq analysis of bacterial and archaeal 16S rRNA gene sequences. The dominant bacterial phyla present in the biomass at the conclusion of the trial were the Proteobacteria and Firmicutes and the dominant archaeal genus was Methanosaeta. Trichococcus and Flavobacterium populations, previously associated with low temperature protein degradation, developed in the reactor biomass. The presence of previously characterised polyphosphate accumulating organisms (PAOs such as Rhodocyclus, Chromatiales, Actinobacter and Acinetobacter was

  6. Organic Removal Efficiency of the Nanofiltration and Adsorption Hybrid System in High Strength Wastewater

    Directory of Open Access Journals (Sweden)

    Amir Hessam Hassani

    2011-03-01

    Full Text Available Surface and groundwater resources are increasingly jeopardized by discharges from pharmaceutical, chemical, and detergent plants. The high pollutant load of the effluents from these industries requires specific treatments. The objective of this research was to study and compare the nanofiltration and adsorption hybrid system with the plain nanofiltration system in wastewater treatment.For this purpose, a pilot nanofiltration system with a capacity of 7.6 m3/d using 1 and 5 micron filters and a FILMTEC NF90-4040 membrane was used in the first phase of the study. In the second phase, granular activated carbon cartridges were used. Inluent and effluent discharges as well as the COD removal were measured in both systems under variable times and organic load conditions. The results showed that COD removal efficiency was higher in the hybrid system than in the plain naonofiltration one. In the hybrid system, the Maximum in the hybrid system, the COD removal efficiencies achieved for organic loads of 1000, 2000, and 3000 mg/L were 99%, 95.86%, and 92.93%, respectively. The same values for the plain nanofiltration system were 87.34%, 50%, and 29.41%, respectively. It was found that polarization and membrane fouling decreased both the effluent flow and the COD removal efficiency with time. Fouling of the membrane was, however, lower in the hybrid system compared to the plain nanofiltration; thus, the hybrid system was associated with higher values of COD removal and delayed membrane fouling.

  7. Economic analysis of emerald ash borer (Coleoptera: Buprestidae) management options.

    Science.gov (United States)

    Vannatta, A R; Hauer, R H; Schuettpelz, N M

    2012-02-01

    Emerald ash borer, Agrilus planipennis (Fairmaire) (Coleoptera: Buprestidae), plays a significant role in the health and extent of management of native North American ash species in urban forests. An economic analysis of management options was performed to aid decision makers in preparing for likely future infestations. Separate ash tree population valuations were derived from the i-Tree Streets program and the Council of Tree and Landscape Appraisers (CTLA) methodology. A relative economic analysis was used to compare a control option (do-nothing approach, only removing ash trees as they die) to three distinct management options: 1) preemptive removal of all ash trees over a 5 yr period, 2) preemptive removal of all ash trees and replacement with comparable nonash trees, or 3) treating the entire population of ash trees with insecticides to minimize mortality. For each valuation and management option, an annual analysis was performed for both the remaining ash tree population and those lost to emerald ash borer. Retention of ash trees using insecticide treatments typically retained greater urban forest value, followed by doing nothing (control), which was better than preemptive removal and replacement. Preemptive removal without tree replacement, which was the least expensive management option, also provided the lowest net urban forest value over the 20-yr simulation. A "no emerald ash borer" scenario was modeled to further serve as a benchmark for each management option and provide a level of economic justification for regulatory programs aimed at slowing the movement of emerald ash borer.

  8. Graphene and graphene nanocomposites for the removal of aromatic organic compounds from the water: systematic review

    Science.gov (United States)

    Monsores Paixão, Monique; Tadeu Gomes Vianna, Marco; Marques, Marcia

    2018-01-01

    Aromatic organic pollutants are highly toxic to the human and environmental health and are considered as priority pollutants by regulatory agencies. Managing contaminated sites with organic pollutants is one of the major environmental challenges today. Of all technologies that have been proposed to remove contaminants, adsorption is recognized worldwide as an attractive option due to its versatility, wide applicability and economic viability. Recent studies report the use of graphene (GN), a recently carbon nanomaterial, and its derivatives in sorption processes for the removal of aromatic organic compounds. The present review has shown that GN structures are a promising alternative to traditional adsorbent materials, with excellent results in the removal of organic compounds from water, due to their unique structural characteristics and great adsorption capacity for organic compounds. Although, there is still a long way to go until that practical applications can be implemented.

  9. High frequency way of helium ash removal from stellarator-reactor

    International Nuclear Information System (INIS)

    Grekov, D.L.

    2005-01-01

    The paper deals with the problem of helium ash removal from stellarator-reactor. The lower hybrid heating of ash ions is proposed to solve this problem. The theory of ion stochastic heating, developed earlier by Karney, is generalized on the case of heating in stellarators. The features of the lower hybrid waves propagation and the ions motion in the stellarator confining field are taken into account. With proper choice of wave parameters (such as frequency, antenna position and initial spectrum of longitudinal refractive index) the slow mode of LH waves penetrates from the launching system to plasma core (and back) without conversion to kinetic plasma mode or to fast mode. With all these going on, the LH wave is absorbed by alpha particles only. The electron Landau damping is negligibly small, and there is no bulk ions stochastic heating. The motion of high energy (>100 keV) ions in the LHD heliotron with inwardly shifted magnetic axis, as an example of stellarator type device, is calculated numerically using the single particle simulation code which couples modified Karney's ion stochastic heating theory. The effect of collisions was taken into account through the Monte Carlo equivalent of the Lorentz collision operator. It is shown, that due to interaction with lower hybrid wave, initially well-confined alpha particles are expelled from the plasma during the time period less then collision time. At the same time, the low hybrid heating does not remove the ions with energy higher than 500 keV. Therefore, it is possible to use this method of RF heating for helium ash removal in stellarator-reactor. The required LH power is estimated to be of the order of 10 MW. (author)

  10. Synergic Adsorption–Biodegradation by an Advanced Carrier for Enhanced Removal of High-Strength Nitrogen and Refractory Organics

    KAUST Repository

    Ahmad, Muhammad; Liu, Sitong; Mahmood, Nasir; Mahmood, Asif; Ali, Muhammad; Zheng, Maosheng; Ni, Jinren

    2017-01-01

    Coking wastewater contains not only high-strength nitrogen but also toxic biorefractory organics. This study presents simultaneous removal of high-strength quinoline, carbon, and ammonium in coking wastewater by immobilized bacterial communities

  11. Removal of SO2 and NO/sub x/ from flue gas by means of a spray dryer/electron beam combination: a feasibility study

    International Nuclear Information System (INIS)

    Helfritch, D.J.; Feldman, P.L.; Ray, A.B.; Morgan, J.R.; Hildreth, G.A.

    1982-04-01

    This study examines the feasibility of adding an electron beam between the spray dryer and the fabric filter of dry scrubber flue gas desulfurization (FGD) systems. The beam promises effective removal of nitrogen oxides (NO/sub x/) and sulfur dioxide (SO 2 ), even at higher coal-sulfur levels than usually economic for dry scrubbers. The beam excites gas molecules, promoting reactions that convert SO 2 and NO/sub x/ to acids that then react with calcium compounds and are removed by the filter. Concerns examined here are feasibility and waste disposal. The cost findings are promising for both manufacture and operation. The system uses commercially available components. The relatively low temperatures and high humidity downstream of the spray dryer favor economic beam operation. The beam removes SO 2 , so the dryer can be run for economy, not high removal. The beam's incidental heating effect reduces reheat cost. Safe landfilling of the nitrate-rich waste appears practical, with leachate carrying no more nitrate than natural rain and dustfall. We expect natural pozzolanic reactions between alumina-silica compounds in the fly ash and lime compounds from the spray dryer to form an impermeable concrete-like material within 10 days after landfilling. Dry scrubber with electron beam appears competitive with commercial FGD systems, and we recommend a pilot scale operation

  12. Using Behavioral Economics to Design Physician Incentives That Deliver High-Value Care.

    Science.gov (United States)

    Emanuel, Ezekiel J; Ubel, Peter A; Kessler, Judd B; Meyer, Gregg; Muller, Ralph W; Navathe, Amol S; Patel, Pankaj; Pearl, Robert; Rosenthal, Meredith B; Sacks, Lee; Sen, Aditi P; Sherman, Paul; Volpp, Kevin G

    2016-01-19

    Behavioral economics provides insights about the development of effective incentives for physicians to deliver high-value care. It suggests that the structure and delivery of incentives can shape behavior, as can thoughtful design of the decision-making environment. This article discusses several principles of behavioral economics, including inertia, loss aversion, choice overload, and relative social ranking. Whereas these principles have been applied to motivate personal health decisions, retirement planning, and savings behavior, they have been largely ignored in the design of physician incentive programs. Applying these principles to physician incentives can improve their effectiveness through better alignment with performance goals. Anecdotal examples of successful incentive programs that apply behavioral economics principles are provided, even as the authors recognize that its application to the design of physician incentives is largely untested, and many outstanding questions exist. Application and rigorous evaluation of infrastructure changes and incentives are needed to design payment systems that incentivize high-quality, cost-conscious care.

  13. MENA Quarterly Economic Brief, July 2015

    OpenAIRE

    Devarajan, Shanta; Mottaghi, Lili

    2015-01-01

    Iran and the Permanent Members of the UN Security Council and Germany (P5+1) reached a deal on July 14, 2015 that limits Iranian nuclear activity in return for lifting all international sanctions that were placed on Iran (Box 1). This issue of the MENA Quarterly Economic Brief (QEB) traces the economic effects of this development—removing sanctions on Iran—on the world oil market, on Iran’s trading partners, and on the Iranian economy.

  14. Dam Removals and River Restoration in International Perspective

    Directory of Open Access Journals (Sweden)

    Chris S. Sneddon

    2017-10-01

    Full Text Available In the Anthropocene era, questions over institutions, economics, culture and politics are central to the promotion of water-society relations that enhance biophysical resilience and democratic modes of environmental governance. The removal of dams and weirs from river systems may well signal an important shift in how human actors value and utilize rivers. Yet the removal of water infrastructure is often lengthy, institutionally complex, and characterized by social conflict. This Special Issue draws insights from case studies of recent efforts in North America and Europe to restore river systems through dam and weir removal. These cases include both instances where removal has come to fruition in conjunction with efforts to rehabilitate aquatic systems and instances where removal has been stymied by a constellation of institutional, political and cultural factors. Drawing from diverse theoretical frames and methodological approaches, the authors present novel ways to conceptualize water-society relations using the lens of dam removal and river restoration, as well as crucial reminders of the multiple biophysical and social dimensions of restoration initiatives for water resource practitioners interested in the rehabilitation of socioecological systems.

  15. Large-scale treatment of high-salt, high-pH wastewater for 137Cs and 90Sr removal, using crystalline silicotitanate resin

    International Nuclear Information System (INIS)

    Taylor, P.A.; Walker, J.F.; Lee, D.D.

    1998-04-01

    A full-scale demonstration of cesium removal technology has been conducted at Oak Ridge National Laboratory (ORNL). This demonstration utilized a modular, mobile ion-exchange system and existing facilities for the off-gas system, secondary containment, and utilities. The ion-exchange material, crystalline silicotitanate (CST), was selected on the basis of its effectiveness in laboratory tests. The CST, which was developed through a Cooperative Research and Development Agreement between DOE and private industry, is highly selective for removing cesium from solutions containing high concentrations of other contaminants, such as sodium and potassium. Approximately 116,000 liters of supernate was processed during the demonstration with ∼ 1,142 Ci of 137 Cs removed from the supernate and loaded onto 266 liters of the CST sorbent. The supernate processed had a high salt content, about 4 M NaNO 3 and a pH of 12 to 13. The CST also loaded Ba, Pb, Sr, U and Zn. Analysis of the spent sorbent has shown that it is not hazardous under the Resource Conservation and Recovery Act (RCRA). The cesium breakthrough curves for the lab and full-scale columns agreed very well, suggesting that lab-scale tests can be used to predict the performance of larger systems. The cesium breakthrough curves for runs at different flowrates show that film diffusion is significant in controlling the mass transfer process. Operational factors that increase the effect of film diffusion include the small size and high porosity of the CST sorbent, and the relatively low liquid velocity through the sorbent

  16. Ongoing removals of invasive lionfish in Honduras and their effect on native Caribbean prey fishes.

    Science.gov (United States)

    Peiffer, Friederike; Bejarano, Sonia; Palavicini de Witte, Giacomo; Wild, Christian

    2017-01-01

    The invasion of Indo-Pacific lionfish is one of the most pressing concerns in the context of coral reef conservation throughout the Caribbean. Invasive lionfish threaten Caribbean fish communities by feeding on a wide range of native prey species, some of which have high ecological and economic value. In Roatan (Honduras) a local non-governmental organisation (i.e. Roatan Marine Park) trains residents and tourists in the use of spears to remove invasive lionfish. Here, we assess the effectiveness of local removal efforts in reducing lionfish populations. We ask whether reefs subject to relatively frequent removals support more diverse and abundant native fish assemblages compared to sites were no removals take place. Lionfish biomass, as well as density and diversity of native prey species were quantified on reefs subject to regular and no removal efforts. Reefs subject to regular lionfish removals (two to three removals month -1 ) with a mean catch per unit effort of 2.76 ± 1.72 lionfish fisher -1 h -1 had 95% lower lionfish biomass compared to non-removal sites. Sites subject to lionfish removals supported 30% higher densities of native prey-sized fishes compared to sites subject to no removal efforts. We found no evidence that species richness and diversity of native fish communities differ between removal and non-removal sites. We conclude that opportunistic voluntary removals are an effective management intervention to reduce lionfish populations locally and might alleviate negative impacts of lionfish predation. We recommend that local management and the diving industry cooperate to cost-effectively extend the spatial scale at which removal regimes are currently sustained.

  17. Ongoing removals of invasive lionfish in Honduras and their effect on native Caribbean prey fishes

    Directory of Open Access Journals (Sweden)

    Friederike Peiffer

    2017-10-01

    Full Text Available The invasion of Indo-Pacific lionfish is one of the most pressing concerns in the context of coral reef conservation throughout the Caribbean. Invasive lionfish threaten Caribbean fish communities by feeding on a wide range of native prey species, some of which have high ecological and economic value. In Roatan (Honduras a local non-governmental organisation (i.e. Roatan Marine Park trains residents and tourists in the use of spears to remove invasive lionfish. Here, we assess the effectiveness of local removal efforts in reducing lionfish populations. We ask whether reefs subject to relatively frequent removals support more diverse and abundant native fish assemblages compared to sites were no removals take place. Lionfish biomass, as well as density and diversity of native prey species were quantified on reefs subject to regular and no removal efforts. Reefs subject to regular lionfish removals (two to three removals month−1 with a mean catch per unit effort of 2.76 ± 1.72 lionfish fisher−1 h−1 had 95% lower lionfish biomass compared to non-removal sites. Sites subject to lionfish removals supported 30% higher densities of native prey-sized fishes compared to sites subject to no removal efforts. We found no evidence that species richness and diversity of native fish communities differ between removal and non-removal sites. We conclude that opportunistic voluntary removals are an effective management intervention to reduce lionfish populations locally and might alleviate negative impacts of lionfish predation. We recommend that local management and the diving industry cooperate to cost-effectively extend the spatial scale at which removal regimes are currently sustained.

  18. Extended sudden approximation model for high-energy nucleon removal reactions

    Energy Technology Data Exchange (ETDEWEB)

    Carstoiu, F.; Sauvan, E.; Orr, N.A. [Caen Univ., Lab. de Physique Corpusculaire, Institut des Sciences de la Matiere et du Rayonnement, IN2P3-CNRS ISMRA, 14 (France); Carstoiu, F. [IFIN-HH, Bucharest-Magurele (Romania); Bonaccorso, A. [Istituto Nazionale di Fisica Nucleare, Pisa (Italy)

    2004-04-01

    A model based on the sudden approximation has been developed to describe high energy single nucleon removal reactions. Within this approach, which takes as its starting point the formalism of Hansen, the nucleon-removal cross section and the full 3-dimensional momentum distributions of the core fragments including absorption, diffraction, Coulomb and nuclear-Coulomb interference amplitudes, have been calculated. The Coulomb breakup has been treated to all orders for the dipole interaction. The model has been compared to experimental data for a range of light, neutron-rich psd-shell nuclei. Good agreement was found for both the inclusive cross sections and momentum distributions. In the case of {sup 17}C, comparison is also made with the results of calculations using the transfer-to-the-continuum model. The calculated 3-dimensional momentum distributions exhibit longitudinal and transverse momentum components that are strongly coupled by the reaction for s-wave states, whilst no such effect is apparent for d-waves. Incomplete detection of transverse momenta arising from limited experimental acceptances thus leads to a narrowing of the longitudinal distributions for nuclei with significant s-wave valence neutron configurations, as confirmed by the data. Asymmetries in the longitudinal momentum distributions attributed to diffractive dissociation are also explored. (authors)

  19. Extended sudden approximation model for high-energy nucleon removal reactions

    International Nuclear Information System (INIS)

    Carstoiu, F.; Sauvan, E.; Orr, N.A.; Carstoiu, F.; Bonaccorso, A.

    2004-04-01

    A model based on the sudden approximation has been developed to describe high energy single nucleon removal reactions. Within this approach, which takes as its starting point the formalism of Hansen, the nucleon-removal cross section and the full 3-dimensional momentum distributions of the core fragments including absorption, diffraction, Coulomb and nuclear-Coulomb interference amplitudes, have been calculated. The Coulomb breakup has been treated to all orders for the dipole interaction. The model has been compared to experimental data for a range of light, neutron-rich psd-shell nuclei. Good agreement was found for both the inclusive cross sections and momentum distributions. In the case of 17 C, comparison is also made with the results of calculations using the transfer-to-the-continuum model. The calculated 3-dimensional momentum distributions exhibit longitudinal and transverse momentum components that are strongly coupled by the reaction for s-wave states, whilst no such effect is apparent for d-waves. Incomplete detection of transverse momenta arising from limited experimental acceptances thus leads to a narrowing of the longitudinal distributions for nuclei with significant s-wave valence neutron configurations, as confirmed by the data. Asymmetries in the longitudinal momentum distributions attributed to diffractive dissociation are also explored. (authors)

  20. Optimization of graffiti removal on natural stone by means of high repetition rate UV laser

    International Nuclear Information System (INIS)

    Fiorucci, M.P.; López, A.J.; Ramil, A.; Pozo, S.; Rivas, T.

    2013-01-01

    The use of laser for graffiti removal is a promising alternative to conventional cleaning methods, though irradiation parameters must be carefully selected in order to achieve the effective cleaning without damaging the substrate, especially when referring to natural stone. From a practical point of view, once a safe working window is selected, it is necessary to determine the irradiation conditions to remove large paint areas, with minimal time consumption. The aim of this paper is to present a systematic procedure to select the optimum parameters for graffiti removal by means of the 3rd harmonic of a high repetition rate nanosecond Nd:YVO 4 laser. Ablation thresholds of four spray paint colors were determined and the effect of pulse repetition frequency, beam diameter and line scan separation was analyzed, obtaining a set of values which optimize the ablation process.

  1. Optimization of graffiti removal on natural stone by means of high repetition rate UV laser

    Energy Technology Data Exchange (ETDEWEB)

    Fiorucci, M.P., E-mail: m.p.fiorucci@udc.es [Centro de Investigacións Tecnolóxicas, Universidade da Coruña, 15403 Ferrol (Spain); Dpto. Enxeñaría dos Recursos Naturais e Medio Ambiente, E.T.S.E. Minas, Universidade de Vigo, 36200 Vigo (Spain); López, A.J., E-mail: ana.xesus.lopez@udc.es [Centro de Investigacións Tecnolóxicas, Universidade da Coruña, 15403 Ferrol (Spain); Ramil, A., E-mail: alberto.ramil@udc.es [Centro de Investigacións Tecnolóxicas, Universidade da Coruña, 15403 Ferrol (Spain); Pozo, S., E-mail: ipozo@uvigo.es [Dpto. Enxeñaría dos Recursos Naturais e Medio Ambiente, E.T.S.E. Minas, Universidade de Vigo, 36200 Vigo (Spain); Rivas, T., E-mail: trivas@uvigo.es [Dpto. Enxeñaría dos Recursos Naturais e Medio Ambiente, E.T.S.E. Minas, Universidade de Vigo, 36200 Vigo (Spain)

    2013-08-01

    The use of laser for graffiti removal is a promising alternative to conventional cleaning methods, though irradiation parameters must be carefully selected in order to achieve the effective cleaning without damaging the substrate, especially when referring to natural stone. From a practical point of view, once a safe working window is selected, it is necessary to determine the irradiation conditions to remove large paint areas, with minimal time consumption. The aim of this paper is to present a systematic procedure to select the optimum parameters for graffiti removal by means of the 3rd harmonic of a high repetition rate nanosecond Nd:YVO{sub 4} laser. Ablation thresholds of four spray paint colors were determined and the effect of pulse repetition frequency, beam diameter and line scan separation was analyzed, obtaining a set of values which optimize the ablation process.

  2. High performance of nitrogen and phosphorus removal in an electrolysis-integrated biofilter.

    Science.gov (United States)

    Gao, Y; Xie, Y W; Zhang, Q; Yu, Y X; Yang, L Y

    A novel electrolysis-integrated biofilter system was developed in this study to evaluate the intensified removal of nitrogen and phosphorus from contaminated water. Two laboratory-scale biofilter systems were established, one with electrolysis (E-BF) and one without electrolysis (BF) as control. The dynamics of intensified nitrogen and phosphorus removal and the changes of inflow and outflow water qualities were also evaluated. The total nitrogen (TN) removal rate was 94.4% in our newly developed E-BF, but only 74.7% in the control BF. Ammonium removal rate was up to 95% in biofilters with or without electrolysis integration with an influent ammonium concentration of 40 mg/L, and the accumulation of nitrate and nitrite was much lower in the effluent of E-BF than that of BF. Thus electrolysis plays an important role in TN removal especially the nitrate and nitrite removal. Phosphorus removal was significantly enhanced, exceeding 90% in E-BF by chemical precipitation, physical adsorption, and flocculation of phosphorus because of the in situ formation of ferric ions by the anodizing of sacrificial iron anodes. Results from this study indicate that the electrolysis integrated biofilter is a promising solution for intensified nitrogen and phosphorus removal.

  3. Removing Bacillus subtilis from fermentation broth using alumina nanoparticles.

    Science.gov (United States)

    Mu, Dashuai; Mu, Xin; Xu, Zhenxing; Du, Zongjun; Chen, Guanjun

    2015-12-01

    In this study, an efficient separation technology using Al2O3 nanoparticles (NPs) was developed for removing Bacillus subtilis from fermentation broth. The dosage of alumina nanoparticles used for separating B. subtilis increased during the culture process and remained stable in the stationary phase of the culture process. The pH of the culture-broth was also investigated for its effects on flocculation efficiency, and showed an acidic pH could enhance the flocculation efficiency. The attachment mechanisms of Al2O3 NPs to the B. subtilis surface were investigated, and the zeta potential analysis showed that Al2O3 NPs could attach to B. subtilis via electrostatic attachment. Finally, the metabolite content and the antibacterial effect of the fermentation supernatants were detected and did not significantly differ between alumina nanoparticle separation and centrifugation separation. Together, these results indicate a great potential for a highly efficient and economical method for removing B. subtilis from fermentation broth using alumina nanoparticles. Copyright © 2015 Elsevier Ltd. All rights reserved.

  4. Protein-bound toxins: added value in their removal with high convective volumes.

    Science.gov (United States)

    Abad, Soraya; Vega, Almudena; Quiroga, Borja; Arroyo, David; Panizo, Nayara; Reque, Javier Eduardo; López-Gómez, Juan Manuel

    Chronic kidney disease is associated with an increased risk of cardiovascular events. In recent years, protein-bound toxins have become more important due to their association with increased morbidity and mortality, characterised by inadequate clearance during dialysis. The purpose of this study is to assess the influence of high convective volumes on postdilution online haemodiafiltration (OL-HDF) on the removal of medium-sized molecules, small molecules and protein-bound molecules. In forty postdilutional OL-HDF sessions, the reduction rates of toxins of different molecular weights were measured in 13 patients, including protein-bound molecules such as p-cresyl sulphate, indoxyl sulphate and homocysteine. Total convective volume was 28.3 (5.1) litres (range 16.3-38.0 litres). Mean reduction rate of protein-bound molecules was 44.4% (15.7%), 48.7% (14.1%) and 58.6% (8.8%) for p-cresyl sulphate, indoxyl sulphate and homocysteine, respectively. Moreover, a statistically significant direct association was found between the reduction rates of all three molecules, the replacement volume and the Kt/V. High convective volumes during postdilution OL-HDF are associated with increased removal of protein-bound uraemic toxins. Copyright © 2016 Sociedad Española de Nefrología. Published by Elsevier España, S.L.U. All rights reserved.

  5. Laboratory testing and economic analysis of high RAP warm mixed asphalt.

    Science.gov (United States)

    2009-03-24

    This report contains laboratory testing, economic analysis, literature review, and information obtained from multiple producers throughout the state of Mississippi regarding the use of high RAP (50 % to 100%) mixtures containing warm mix additives. T...

  6. High School Economics. Focus.

    Science.gov (United States)

    Watts, Michael; McCorkle, Sarapage; Meszaros, Bonnie; Smith, Robert F.; Highsmith, Robert J.

    This book opens with an exploration of the fundamental trilogy of economics - scarcity, choice, and cost. Students then examine the broad social goals of an economy in preparation for lessons treating many topics new to the precollege level such as the stock market, public choice, and aggregate supply and demand. The set of 20 lessons include: (1)…

  7. A new method of removing the high value feedback resistor in the charge sensitive preamplifier

    International Nuclear Information System (INIS)

    Xi Deming

    1993-01-01

    A new method of removing the high value feedback resistor in the charge sensitive preamplifier is introduced. The circuit analysis of this novel design is described and the measured performances of a practical circuit are provided

  8. Technetium removal column flow testing with alkaline, high salt, radioactive tank waste

    International Nuclear Information System (INIS)

    Blanchard, D.L. Jr.; Kurath, D.E.; Golcar, G.R.; Conradson, S.D.

    1996-01-01

    This report describes two bench-scale column tests conducted to demonstrate the removal of Tc-99 from actual alkaline high salt radioactive waste. The waste used as feed for these tests was obtained from the Hanford double shell tank AW-101, which contains double shell slurry feed (DSSF). The tank sample was diluted to approximately 5 M Na with water, and most of the Cs-137 was removed using crystalline silicotitanates. The tests were conducted with two small columns connected in series, containing, 10 mL of either a sorbent, ABEC 5000 (Eichrom Industries, Inc.), or an anion exchanger Reillex trademark-HPQ (Reilly Industries, Inc.). Both materials are selective for pertechnetate anion (TcO 4 - ). The process steps generally followed those expected in a full-scale process and included (1) resin conditioning, (2) loading, (3) caustic wash to remove residual feed and prevent the precipitation of Al(OH) 3 , and (4) elution. A small amount of Tc-99m tracer was added as ammonium pertechnetate to the feed and a portable GEA counter was used to closely monitor the process. Analyses of the Tc-99 in the waste was performed using ICP-MS with spot checks using radiochemical analysis. Technetium x-ray absorption spectroscopy (XAS) spectra of 6 samples were also collected to determine the prevalence of non-pertechnetate species [e.g. Tc(IV)

  9. Catalysts with Cerium in a Membrane Reactor for the Removal of Formaldehyde Pollutant from Water Effluents

    Directory of Open Access Journals (Sweden)

    Mirella Gutiérrez-Arzaluz

    2016-05-01

    Full Text Available We report the synthesis of cerium oxide, cobalt oxide, mixed cerium, and cobalt oxides and a Ce–Co/Al2O3 membrane, which are employed as catalysts for the catalytic wet oxidation (CWO reaction process and the removal of formaldehyde from industrial effluents. Formaldehyde is present in numerous waste streams from the chemical industry in a concentration low enough to make its recovery not economically justified but high enough to create an environmental hazard. Common biological degradation methods do not work for formaldehyde, a highly toxic but refractory, low biodegradability substance. The CWO reaction is a recent, promising alternative that also permits much lower temperature and pressure conditions than other oxidation processes, resulting in economic benefits. The CWO reaction employing Ce- and Co-containing catalysts was carried out inside a slurry batch reactor and a membrane reactor. Experimental results are reported. Next, a mixed Ce–Co oxide film was supported on an γ-alumina membrane used in a catalytic membrane reactor to compare formaldehyde removal between both types of systems. Catalytic materials with cerium and with a relatively large amount of cerium favored the transformation of formaldehyde. Cerium was present as cerianite in the catalytic materials, as indicated by X-ray diffraction patterns.

  10. Fast adsorption kinetics of highly dispersed ultrafine nickel/carbon nanoparticles for organic dye removal

    Science.gov (United States)

    Kim, Taek-Seung; Song, Hee Jo; Dar, Mushtaq Ahmad; Lee, Hack-Jun; Kim, Dong-Wan

    2018-05-01

    Magnetic metal/carbon nano-materials are attractive for pollutant adsorption and removal. In this study, ultrafine nickel/carbon nanoparticles are successfully prepared via electrical wire explosion processing in ethanol media for the elimination of pollutant organic dyes such as Rhodamine B and methylene blue in aqueous solutions. High specific surface areas originating from both the nano-sized particles and the existence of carbon on the surface of Ni nanoparticles enhance dye adsorption capacity. In addition to this, the excellent dispersity of Ni/C nanoparticles in aqueous dye solutions leads to superior adsorption rates. The adsorption kinetics for the removal of organic dyes by Ni/C nanoparticles agree with a pseudo-second-order model and follow Freundlich adsorption isotherm behavior.

  11. Substrate removal kinetics in high-rate upflow anaerobic filters packed with low-density polyethylene media treating high-strength agro-food wastewaters.

    Science.gov (United States)

    Rajagopal, Rajinikanth; Torrijos, Michel; Kumar, Pradeep; Mehrotra, Indu

    2013-02-15

    The process kinetics for two upflow anaerobic filters (UAFs) treating high strength fruit canning and cheese-dairy wastewaters as feed were investigated. The experimental unit consisted of a 10-L (effective volume) reactor filled with low-density polyethylene media. COD removal efficiencies of about 80% were recorded at the maximum OLRs of 19 and 17 g COD L(-1) d(-1) for the fruit canning and cheese-dairy wastewaters, respectively. Modified Stover-Kincannon and second-order kinetic models were applied to data obtained from the experimental studies in order to determine the substrate removal kinetics. According to Stover-Kincannon model, U(max) and K(B) values were estimated as 109.9 and 109.7 g L(-1) d(-1) for fruit canning, and 53.5 and 49.7 g L(-1) d(-1) for cheese dairy wastewaters, respectively. The second order substrate removal rate k(2(s)) was found to be 5.0 and 1.93 d(-1) respectively for fruit canning and cheese dairy wastewaters. As both these models gave high correlation coefficients (R(2) = 98-99%), they could be used in predicting the behaviour or design of the UAF. Copyright © 2012 Elsevier Ltd. All rights reserved.

  12. Pentachlorophenol removal from aqueous matrices by sorption with almond shell residues

    International Nuclear Information System (INIS)

    Estevinho, B.N.; Ratola, N.; Alves, A.; Santos, L.

    2006-01-01

    Sorption with activated carbon has been the technique preferred for pentachlorophenol (PCP) removal from contaminated waters, but regeneration needs and high operation costs are supporting a renewed interest in the search for alternative sorbents. Among them, almond shell, an agricultural by-product, provides interesting economical advantages, once shells account for 50% (in mass) of the whole almond. In this work, the capacity of almond shells to remove PCP from waters without previous activation was studied in batch conditions. While PCP analysis was performed solid-phase microextraction (SPME) followed by gas chromatography with electron capture detection (GC-ECD), mercury porosimetry and Fourier transform infrared spectroscopy (FTIR) provided a preliminary physical and chemical characterization of the sorbent. Almond shells were essentially a macroporous material, with an average surface area of 12.9 ± 2.8 m 2 /g. The efficiency of PCP removal was 93 ± 14%, in 24 h, with an initial concentration of 100 μg/l PCP and 5 μg PCP/g shell. Isotherm data adjusted better to Freundlich equation, where K F and 1/n were 0.075 ± 0.081 mg 1-1/n l 1/n and 1.882 ± 0.289, respectively. Average desorption efficiency was 7%, indicating strong adsorption capacity. Results proved that almond shells may be an excellent low-cost alternative for PCP removal from contaminated waters

  13. Arsenic Removal from Aqueous Solutions Using Modified and Unmodified Oak Sawdust

    Directory of Open Access Journals (Sweden)

    Ali Reza Rahmani

    2016-01-01

    Full Text Available In this research, oak sawdust, in both modified and unmodified forms, was used as an economical and low-cost material for the removal of arsenic from aqueous solutions. For this purpose, arsenic synthetic samples were prepared using NaAsO2 in distilled water and the effects of pH, adsorbent dosage, contact time, and initial As(V concentration were investigated on As(V adsorption using the adsorbents prepared. The results showed that modified sawdust achieved the highest efficiency (>91% over a contact time of 60 min and at pH 7 when the adsorbent dosage was 4gr/L and the initial As(V concentration was 150 µg/L. The data from both adsorbents fitted well to the Langmuir isotherm. Under optimum conditions (an initial As(V concentration of 150 µg/L and optimal absorption pH, contact time, and adsorbent dosage, maximum As(V removal efficiencies were 93.85% and 91.034% with the modified  and unmodified sawdust adsorbents, respectively. Given the availability and low cost of the adsorbent used and the high removal efficiency obtained at  lower adsorbent dosages and contact times, the modified oak sawdust may be recommended as an effective adsorbent for the removal of arsenic (v from aqueous solutions, especially since it requires no need for pH modification.

  14. Techno-economical Analysis of High Level Waste Storage and Disposal Options

    International Nuclear Information System (INIS)

    Bace, M.; Trontl, K.; Vrankic, K.

    2002-01-01

    Global warming and instability of gas and oil prices are redefining the role of nuclear energy in electrical energy production. A production of high-level radioactive waste (HLW), during the nuclear power plant operation and a danger of high level waste mitigation to the environment are considered by the public as a main obstacle of accepting the nuclear option. As economical and technical aspects of the back end of fuel cycle will affect the nuclear energy acceptance the techno-economical analysis of different methods for high level waste storage and disposal has to be performed. The aim of this paper is to present technical and economical characteristics of different HLW storage and disposal technologies. The final choice of a particular HLW management method is closely connected to the selection of a fuel cycle type: open or closed. Wet and dry temporary storage has been analyzed including different types of spent fuel pool capacity increase methods, different pool location (at reactor site and away from reactor site) as well as casks and vault system of dry storage. Since deep geological deposition is the only disposal method with a realistic potential, we focused our attention on that disposal technology. Special attention has been given to the new idea of international and regional disposal location. The analysis showed that a coexistence of different storage methods and deep geological deposition is expected in the future, regardless of the fuel cycle type. (author)

  15. Hollow fiber contractors for simultaneous SOx/NOx removal

    International Nuclear Information System (INIS)

    Bhown, A.S.; Pakala, N.R.; Riggs, T.

    1995-01-01

    Control of SO x and NO x emissions from coal-fired utility and industrial boilers is a topic of growing national and international importance. Whereas a host of commercial and semicommercial processes exist, increasingly stringent emission standards mandate that processes be low cost, highly efficient, and, ideally, produce marketable byproducts. Although a wide range of site-specific economic factors dictate the best choice of SO x and NO x control, removal of SO 2 by wet limestone scrubbing and removal of NO x by selective catalytic reduction (SCR) are regarded as the best commercialized technologies for this application. A typical wet limestone plant requires approximately $100 to $120 of capital investment per kilowatt of electric power generating capacity and has power and miscellaneous operating costs in the range of 5 to 6 mils per kilowatt hour (kWh). The SCR process requires approximately $70 to $100 of capital investment per kilowatt of electric power generating capacity. Its operating costs, including ammonia consumption, is in the range of 1.8 to 2.2 mils per kWh. These costs can add approximately 20% to the final cost of generated electricity, a significant burden on rate payers

  16. Phosphorus removal from aquaculture wastewater and latex by ...

    African Journals Online (AJOL)

    Water pollution has always been a major problem in the environment. Polluted water is harmful for human health, thus, there is the need to clean water from polluting factors. One of the economical and rapid methods for removing elements is displacement of metals by biosorption. Three treatments in four replications for ...

  17. Effective and highly recyclable ceramic membrane based on amorphous nanosilica for dye removal from t

    Directory of Open Access Journals (Sweden)

    Gehan M.K. Tolba

    2016-03-01

    Full Text Available In this study, an adsorptive ceramic membrane was prepared by a simple dry pressing of a mixture of nanosilica produced from low cost rice husk by hydrothermal technique at sub-critical water conditions, calcium phosphate, and ammonium acetate together and then calcined at 600 °C in air. Optimization of the raw materials ratio was found to be necessary to avoid crack formation during sintering process. The membrane microstructure, dye removal efficiency and the permeation flux of the membranes were investigated. The membrane was tested to remove the methylene blue from aqueous solution. Results show that the removal of the dye increases as the silica content increases in the all given membranes and it decreases with an increase in the ammonium acetate. Moreover, the water flux decreases with an increase in the silica content. The methylene blue adsorbed onto the silica membrane can be removed by calcination and the membrane could be recycled several times without any obvious loss in the adsorption performance. In conclusion, this study demonstrates a convenient strategy to prepare an effective adsorptive membrane, which can be applied as a highly recyclable membrane for the adsorption of organic maters.

  18. Highly efficient removal of pathogenic bacteria with magnetic graphene composite.

    Science.gov (United States)

    Zhan, Sihui; Zhu, Dandan; Ma, Shuanglong; Yu, Wenchao; Jia, Yanan; Li, Yi; Yu, Hongbing; Shen, Zhiqiang

    2015-02-25

    Magnetic Fe3O4/graphene composite (abbreviated as G-Fe3O4) was synthesized successfully by solvothermal method to effectively remove both bacteriophage and bacteria in water, which was tested by HRTEM, XRD, BET, XPS, FTIR, CV, magnetic property and zeta-potential measurements. Based on the result of HRTEM, the single-sheet structure of graphene oxide and the monodisperse Fe3O4 nanoparticles on the surface of graphene can be observed obviously. The G-Fe3O4 composite were attractive for removing a wide range of pathogens including not only bacteriophage ms2, but also various bacteria such as S. aureus, E. coli, Salmonella, E. Faecium, E. faecalis, and Shigella. The removal efficiency of E. coli for G-Fe3O4 composite can achieve 93.09%, whereas it is only 54.97% with pure Fe3O4 nanoparticles. Moreover, a detailed verification test of real water samples was conducted and the removal efficiency of bacteria in real water samples with G-Fe3O4 composite can also reach 94.8%.

  19. Key drivers and economic consequences of high-end climate scenarios: uncertainties and risks

    DEFF Research Database (Denmark)

    Halsnæs, Kirsten; Kaspersen, Per Skougaard; Drews, Martin

    2015-01-01

    The consequences of high-end climate scenarios and the risks of extreme events involve a number of critical assumptions and methodological challenges related to key uncertainties in climate scenarios and modelling, impact analysis, and economics. A methodological framework for integrated analysis...... of extreme events increase beyond scaling, and in combination with economic assumptions we find a very wide range of risk estimates for urban precipitation events. A sensitivity analysis addresses 32 combinations of climate scenarios, damage cost curve approaches, and economic assumptions, including risk...... aversion and equity represented by discount rates. Major impacts of alternative assumptions are investigated. As a result, this study demonstrates that in terms of decision making the actual expectations concerning future climate scenarios and the economic assumptions applied are very important...

  20. Radon removal using point-of-entry water-treatment techniques. Final report, October 1988-June 1990

    International Nuclear Information System (INIS)

    Kinner, N.E.; Malley, J.P.; Clement, J.A.

    1990-10-01

    The purpose of the EPA Cooperative Agreement was to evaluate the performance of POE granular activated carbon (GAC), and diffused bubble and bubble place aeration systems treating a ground water supply containing radon (35,620 + or - 6,717 pCi/L). The pattern of loading to the units was designed to simulate daily demand in a household. Each of the systems was evaluated with respect to three primary factors: radon removal efficiency, potential problems, and economics. The radon removal efficiencies of the POE GAC units gradually deteriorated over time from 99.7% to 79% for the GAC without pretreatment and 99.7% to 85% for the units preceded by ion exchange. The bubble plate and diffused bubble POE units were very efficient (99%) at removing radon from the water. The resilience is primarly due to the high air to water ratios supplied by the aeration blowers. One major problem associated with the aeration techniques is iron oxidation/precipitation

  1. Enhanced removal of arsenic from a highly laden industrial effluent using a combined coprecipitation/nano-adsorption process.

    Science.gov (United States)

    Jiang, Yingnan; Hua, Ming; Wu, Bian; Ma, Hongrui; Pan, Bingcai; Zhang, Quanxing

    2014-05-01

    Effective arsenic removal from highly laden industrial wastewater is an important but challenging task. Here, a combined coprecipitation/nano-adsorption process, with ferric chloride and calcium chloride as coprecipitation agents and polymer-based nanocomposite as selective adsorbent, has been validated for arsenic removal from tungsten-smelting wastewater. On the basis of operating optimization, a binary FeCl3 (520 mg/L)-CaCl2 (300 mg/L) coprecipitation agent could remove more than 93% arsenic from the wastewater. The resulting precipitate has proved environmental safety based on leaching toxicity test. Fixed-bed column packed with zirconium or ferric-oxide-loaded nanocomposite was employed for further elimination of arsenic in coprecipitated effluent, resulting in a significant decrease of arsenic (from 0.96 to less than 0.5 mg/L). The working capacity of zirconium-loaded nanocomposite was 220 bed volumes per run, much higher than that of ferric-loaded nanocomposite (40 bed volumes per run). The exhausted zirconium-loaded nanocomposite could be efficiently in situ regenerated with a binary NaOH-NaCl solution for reuse without any significant capacity loss. The results validated the combinational coprecipitation/nano-adsorption process to be a potential alternative for effective arsenic removal from highly laden industrial effluent.

  2. High Performance Nanofiltration Membrane for Effective Removal of Perfluoroalkyl Substances at High Water Recovery.

    Science.gov (United States)

    Boo, Chanhee; Wang, Yunkun; Zucker, Ines; Choo, Youngwoo; Osuji, Chinedum O; Elimelech, Menachem

    2018-05-31

    We demonstrate the fabrication of a loose, negatively charged nanofiltration (NF) membrane with tailored selectivity for the removal of perfluoroalkyl substances with reduced scaling potential. A selective polyamide layer was fabricated on top of a polyethersulfone support via interfacial polymerization of trimesoyl chloride and a mixture of piperazine and bipiperidine. Incorporating high molecular weight bipiperidine during the interfacial polymerization enables the formation of a loose, nanoporous selective layer structure. The fabricated NF membrane possessed a negative surface charge and had a pore diameter of ~1.2 nm, much larger than a widely used commercial NF membrane (i.e., NF270 with pore diameter of ~0.8 nm). We evaluated the performance of the fabricated NF membrane for the rejection of different salts (i.e., NaCl, CaCl2, and Na2SO4) and perfluorooctanoic acid (PFOA). The fabricated NF membrane exhibited a high retention of PFOA (~90%) while allowing high passage of scale-forming cations (i.e., calcium). We further performed gypsum scaling experiments to demonstrate lower scaling potential of the fabricated loose porous NF membrane compared to NF membranes having a dense selective layer under solution conditions simulating high water recovery. Our results demonstrate that properly designed NF membranes are a critical component of a high recovery NF system, which provide an efficient and sustainable solution for remediation of groundwater contaminated with perfluoroalkyl substances.

  3. Highly efficient removal of perfluorooctanoic acid from aqueous solution by H2O2-enhanced electrocoagulation-electroflotation technique

    Directory of Open Access Journals (Sweden)

    Bo Yang

    2016-03-01

    Full Text Available Electrocoagulation (EC technique was used to investigate the removal performance of aqueous perfluorooctanoic acid (PFOA with relatively high concentration as simulating the wastewater from organic fluorine industry. A comparison was done with the similar amount of coagulant between EC and chemical coagulation process. PFOA removal obtained was higher with EC process, especially for Fe anode. Several factors were studied to optimize the EC process. At the optimal operating parameters including 37.5 mA/cm2 of current density, initial pH 3.77, and 180 rpm of mixing speed, 93% of PFOA could be removed with 100 mg/L of initial concentration after 90-min electrolysis. Furthermore, the remove efficiency could be obviously improved by H2O2 intermittent addition, which removed more than 99% of PFOA within 40-min EC. It could be attributed to that H2O2 facilitated the oxidative transformation from ferrous to ferric ion. In addition, the adsorptive removal of aqueous PFOA on Fe flocs during EC was also verified by fourier transform infrared spectra.

  4. Solute removal capacity of high cut-off membrane plasma separators.

    Science.gov (United States)

    Ohkubo, Atsushi; Kurashima, Naoki; Nakamura, Ayako; Miyamoto, Satoko; Iimori, Soichiro; Rai, Tatemitsu

    2013-10-01

    In vitro blood filtration was performed by a closed circuit using high cut-off membrane plasma separators, EVACURE EC-2A10 (EC-2A) and EVACURE EC-4A10 (EC-4A). Samples were obtained from sampling sites before the plasma separator, after each plasma separator, and from the ultrafiltrate of each separator. The sieving coefficient (S.C.) of total protein (TP), albumin (Alb), IgG, interleukin-6 (IL-6), interleukin-8 (IL-8), tumor necrosis factor-α (TNF-α), fibrinogen (Fib), antithrombin III (AT-III), and coagulation factor XIII (FXIII) were calculated. The S.C. of each solute using EC-2A and EC-A4 were as follows; TP: 0.25 and 0.56, Alb: 0.32 and 0.73, IgG: 0.16 and 0.50, IL-6:0.73 and 0.95, IL-8:0.85 and 0.82, TNF-α: 1.07 and 0.99, Fib: 0 and 0, FXIII: 0.07 and 0.17, respectively. When compared with the conventional type of membrane plasma separators, EVACURE could efficiently remove cytokines while retaining coagulation factors such as fibrinogen. Moreover, EC-2A prevented protein loss, whereas EC-4A could remove approximately 50% of IgG. © 2013 The Authors. Therapeutic Apheresis and Dialysis © 2013 International Society for Apheresis.

  5. High speed diesel consumption and economic growth in India

    Energy Technology Data Exchange (ETDEWEB)

    Ghosh, Sajal [Management Development Institute (MDI), Gurgaon 122001 (India)

    2010-04-15

    This study probes the long-term equilibrium relationship among High Speed Diesel (HSD) consumption, real GDP and price of HSD in India using autoregressive distributed lag (ARDL) bounds testing approach of cointegration for the time span 1972-1973 to 2005-2006. Empirical results reveal that the series are cointegrated and long term income elasticity for HSD demand in India is 1.27 while that for short-run is 0.46. Both long-run and short-run price elasticities are found to be statistically insignificant. The study also establishes a short-run bi-directional causality between economic growth and HSD consumption and the existence of a long-run unidirectional causality running from economic growth to HSD consumption. Finally, a set of policy prescriptions have been suggested to reduce the consumption of HSD, which should have no adverse impact on economy in the long-run. (author)

  6. A High-Fidelity Haze Removal Method Based on HOT for Visible Remote Sensing Images

    Directory of Open Access Journals (Sweden)

    Hou Jiang

    2016-10-01

    Full Text Available Spatially varying haze is a common feature of most satellite images currently used for land cover classification and mapping and can significantly affect image quality. In this paper, we present a high-fidelity haze removal method based on Haze Optimized Transformation (HOT, comprising of three steps: semi-automatic HOT transform, HOT perfection and percentile based dark object subtraction (DOS. Since digital numbers (DNs of band red and blue are highly correlated in clear sky, the R-squared criterion is utilized to search the relative clearest regions of the whole scene automatically. After HOT transform, spurious HOT responses are first masked out and filled by means of four-direction scan and dynamic interpolation, and then homomorphic filter is performed to compensate for loss of HOT of masked-out regions with large areas. To avoid patches and halo artifacts, a procedure called percentile DOS is implemented to eliminate the influence of haze. Scenes including various land cover types are selected to validate the proposed method, and a comparison analysis with HOT and Background Suppressed Haze Thickness Index (BSHTI is performed. Three quality assessment indicators are selected to evaluate the haze removed effect on image quality from different perspective and band profiles are utilized to analyze the spectral consistency. Experiment results verify the effectiveness of the proposed method for haze removal and the superiority of it in preserving the natural color of object itself, enhancing local contrast, and maintaining structural information of original image.

  7. Analysis of pollution removal from wastewater by Ceratophyllum ...

    African Journals Online (AJOL)

    Water is one of the most stable and abundant complexes on nature that can be polluted with natural and human factors. Polluted water is harmful to human health and need to purify. One of the economic and rapid methods for elements removal is displacement of metals by biosorption. Two treatments in four replications for ...

  8. Phosphate removal by refined aspen wood fiber treated with carboxymethyl cellulose and ferrous chloride

    Science.gov (United States)

    Thomas L. Eberhardt; Soo-Hong Min; James S. Han

    2006-01-01

    Biomass-based filtration media are of interest as an economical means to remove pollutants and nutrients found in stormwater runoff. Refined aspen wood fiber samples treated with iron salt solutions demonstrated limited capacities to remove (ortho)phosphate from test solutions. To provide additional sites for iron complex formation, and thereby impart a greater...

  9. Highly efficient removal of chromium(VI) by Fe/Ni bimetallic nanoparticles in an ultrasound-assisted system.

    Science.gov (United States)

    Zhou, Xiaobin; Jing, Guohua; Lv, Bihong; Zhou, Zuoming; Zhu, Runliang

    2016-10-01

    Highly active Fe/Ni bimetallic nanocomposites were prepared by using the liquid-phase reduction method, and they were proven to be effective for Cr(VI) removal coupled with US irradiation. The US-assisted Fe/Ni bimetallic system could maintain a good performance for Cr(VI) removal at a wide pH range of 3-9. Based on the characterization of the Fe/Ni nanoparticles before and after reaction, the high efficiency of the mixed system could attribute to the synergistic effects of the catalysis of Ni(0) and US cavitation. Ni(0) could facilitate the Cr(VI) reduction through electron transfer and catalytic hydrogenation. Meanwhile, US could fluidize the Fe/Ni nanoparticles to increase the actual reactive surface area and clean off the co-precipitated Fe(III)-Cr(III) hydroxides to maintain the active sites on the surface of the Fe/Ni nanoparticles. Thus, compared with shaking, the US-assisted Fe/Ni system was more efficient on Cr(VI) removal, which achieved 94.7% removal efficiency of Cr(VI) within 10 min. The pseudo-first-order rate constant (kobs) in US-assisted Fe/Ni system (0.5075 min(-1)) was over 5 times higher than that under shaking (0.0972 min(-1)). Moreover, the Fe/Ni nanoparticles still have a good performance under US irradiation after 26 days aging as well as regeneration. Copyright © 2016 Elsevier Ltd. All rights reserved.

  10. Ion Exchange Distribution Coefficient Tests and Computer Modeling at High Ionic Strength Supporting Technetium Removal Resin Maturation

    Energy Technology Data Exchange (ETDEWEB)

    Nash, Charles A. [Savannah River Site (SRS), Aiken, SC (United States). Savannah River National Lab. (SRNL); Hamm, L. Larry [Savannah River Site (SRS), Aiken, SC (United States). Savannah River National Lab. (SRNL); Smith, Frank G. [Savannah River Site (SRS), Aiken, SC (United States). Savannah River National Lab. (SRNL); McCabe, Daniel J. [Savannah River Site (SRS), Aiken, SC (United States). Savannah River National Lab. (SRNL)

    2014-12-19

    The primary treatment of the tank waste at the DOE Hanford site will be done in the Waste Treatment and Immobilization Plant (WTP) that is currently under construction. The baseline plan for this facility is to treat the waste, splitting it into High Level Waste (HLW) and Low Activity Waste (LAW). Both waste streams are then separately vitrified as glass and poured into canisters for disposition. The LAW glass will be disposed onsite in the Integrated Disposal Facility (IDF). There are currently no plans to treat the waste to remove technetium, so its disposition path is the LAW glass. Due to the water solubility properties of pertechnetate and long half-life of 99Tc, effective management of 99Tc is important to the overall success of the Hanford River Protection Project mission. To achieve the full target WTP throughput, additional LAW immobilization capacity is needed, and options are being explored to immobilize the supplemental LAW portion of the tank waste. Removal of 99Tc, followed by off-site disposal, would eliminate a key risk contributor for the IDF Performance Assessment (PA) for supplemental waste forms, and has potential to reduce treatment and disposal costs. Washington River Protection Solutions (WRPS) is developing some conceptual flow sheets for supplemental LAW treatment and disposal that could benefit from technetium removal. One of these flowsheets will specifically examine removing 99Tc from the LAW feed stream to supplemental immobilization. To enable an informed decision regarding the viability of technetium removal, further maturation of available technologies is being performed. This report contains results of experimental ion exchange distribution coefficient testing and computer modeling using the resin SuperLig® 639a to selectively remove perrhenate from high ionic strength simulated LAW. It is advantageous to operate at higher concentration in order to treat the waste

  11. Removal of arsenic from potable water by adsorptive media treatment techniques

    International Nuclear Information System (INIS)

    Yousuf, S.; Khan, S.; Aslam, M.T.; Khan, A.R.

    2012-01-01

    Summary: This study was conducted to investigate the arsenic removal efficiency of different adsorptive media from water. Different naturally occurring materials such as bauxite, plastic clay, plaster of Paris, lime, alum, and alumina etc. were used for the development of media to remove arsenic As/sup +5/ present in the artificially contaminated water. Different ratios of the selected materials were combined and ignited at 9000 C to enhance its arsenic removing efficiency. It was found that the media bauxite, plastic clay, lime (1:1:1) has a maximum removal (99%) of As +5 species from aqueous media and can be used on- site to reduce the arsenic contamination of potable water. Furthermore, the materials used in this experiment were cheaply and abundantly available within the country. The method is very simple and economically viable, for removal of arsenic from potable water. (author)

  12. Ultra-high pressure water jetting for coating removal and surface preparation

    Science.gov (United States)

    Johnson, Spencer T.

    1995-01-01

    This paper shall examine the basics of water technology with particular attention paid to systems currently in use and some select new applications. By providing an overview of commercially available water jet systems in the context of recent case histories, potential users may evaluate the process for future applications. With the on going introduction of regulations prohibiting the use of chemical paint strippers, manual scrapping and dry abrasive media blasting, the need for an environmentally compliant coating removal process has been mandated. Water jet cleaning has been a traditional part of many industrial processed for year, although it has only been in the last few years that reliable pumping equipment capable of ultra-high pressure operation have become available. With the advent of water jet pumping equipment capable of sustaining pressures in excess of 36,000 psi. there has been shift away from lower pressure, high water volume systems. One of the major factors in driving industry to seek higher pressures is the ability to offer higher productivity rates while lowering the quantity of water used and subsequently reprocessed. Among benefits of the trend toward higher pressure/lower volume systems is the corresponding reduction in water jet reaction forces making hand held water jetting practical and safe. Other unique applications made possible by these new generation pumping systems include the use of alternative fluids including liquid ammonia for specialized and hazardous material removal applications. A review of the equipment used and the required modifications will be presented along with the conclusions reached reached during this test program.

  13. Removal of Hydrogen Sulfide from Septic Tank by Vermicomposting Bio Filter

    Directory of Open Access Journals (Sweden)

    Abdol Kazem Neisi

    2016-09-01

    Full Text Available Background & Aims of the Study: Hydrogen sulfide (H2S is a colorless and highly toxic, easily dissolved in water, flammable and explosive gas. Hydrogen sulfide gas is the main cause of odor emissions from municipal sewage plants. One method for removal of hydrogen sulfide gas is the use of biological systems, biofilter. The aim of this study was to survey removal hydrogen sulfide provide in septic tank by vermicomposting biofilter. Materials and Methods: In this study pilot-scale biofilter has been made of bed vermicompost and wood trash. To survey biofilter performance under real condition, the pilot installed in one wastewater pumping station of Ahwaz city, Iran. The study was carried out over 80 days. Inlet and outlet H2S concentration were measured on regular basis. To provide an optimal condition for bacterial growth, moisture was adjusted between 40% and 60% throughout the experiment. Results: Results showed that H2S concentration emitted from the pumping station during the study varied greatly between 33 and 54ppm .The maximum adsorption capacity of the biological bedding was recorded at 22.4 g/m3.hr and the mean efficiency of H2S removal account the startup time was 89.31% .The mean performance efficiency during the biological activity after the startup was recorded at 96.88%. Conclusion: use up biofilter with vermicompost bed and woodchip is an economic method for H2S removal of septic tanks. Removal efficiency of more than 96% is expected with this method.

  14. Boron Removal in Seawater Reverse Osmosis System

    KAUST Repository

    Rahmawati, Karina

    2011-07-01

    Reverse osmosis successfully proves to remove more than 99% of solute in seawater, providing fresh water supply with satisfied quality. Due to some operational constraints, however, some trace contaminants removal, such as boron, cannot be achieved in one pass system. The stringent criterion for boron from World Health Organization (WHO) and Saudi Arabia local standard (0.5 mg/l) is hardly fulfilled by single pass sea water reverse osmosis (SWRO) plants. Some design processes have been proposed to deal with boron removal, but they are not economically efficient due to high energy and chemical consumption. The objective of this study was to study boron removal by different reverse osmosis membranes in two pH conditions, with and without antiscalant addition. Thus, it was expected to observe the possibility of operating single pass system and necessity to operate two pass system using low energy membrane. Five membrane samples were obtained from two different manufacturers. Three types of feed water pH were used, pH 8, pH 10, and pH 10 with antiscalant addition. Experiment was conducted in parallel to compare membrane performance from two manufacturers. Filtration was run with fully recycle mode for three days. Sample of permeate and feed were taken every 12 hours, and analyzed for their boron and TDS concentration. Membrane samples were also tested for their surface charge. The results showed that boron rejection increases as the feed pH increases. This was caused by dissociation of boric acid to negatively charged borate ion and more negatively charged membrane surface at elevated pH which enhance boron rejection. This study found that single pass reverse osmosis system, with and without elevating the pH, may not be possible to be applied because of two reasons. First, permeate quality in term of boron, does not fulfill WHO and local Saudi Arabia regulations. Second, severe scaling occurs due to operation in alkaline condition, since Ca and Mg concentration are

  15. Ultrasound-guided removal of Implanon devices.

    LENUS (Irish Health Repository)

    Persaud, T

    2008-11-01

    Our study has shown that ultrasound-guided localisation and removal of Implanon rods is safe, practical and highly successful. Over a 4-year period, 119 patients had successful, uncomplicated removal of their subdermal devices.The technique is particularly useful for removal of the device when it is not palpable or when an attempt at removal of a palpable device has not been successful.

  16. Removal of regulatory controls for materials and sites

    International Nuclear Information System (INIS)

    2004-01-01

    Issues with the removal of regulatory controls are very important on the agenda of the regulatory authorities dealing with radioactive waste management (RWM). These issues arise prominently in decommissioning and in site remediation, and decisions can be very wide ranging having potentially important economic impacts and reaching outside the RWM area. The RWMC Regulators Forum started to address these issues by holding a topical discussion at its meeting in March 2003. Ths present document collates the national regulatory positions in the area of removal of regulatory controls. A summary of the national positions is also provided. The document is up to date to April 2004. (authors)

  17. The Budget and Economic Outlook: 2017 to 2027

    Science.gov (United States)

    2017-01-01

    creditworthiness and access to credit. Overall, households’ debt and debt-service payments are currently low, as are delinquency rates on consumer...differences in the economic news available when the forecasts were completed and differences in the economic and statistical models used. Appendix A... Statistics , and the Federal Reserve. Real GDP is the output of the economy adjusted to remove the effects of inflation. The unemployment rate is a measure

  18. The Influence of Various Factors on High School Football Helmet Face Mask Removal: A Retrospective, Cross-Sectional Analysis

    Science.gov (United States)

    Swartz, Erik E; Decoster, Laura C; Norkus, Susan A; Cappaert, Thomas A

    2007-01-01

    Context: Most research on face mask removal has been performed on unused equipment. Objective: To identify and compare factors that influence the condition of helmet components and their relationship to face mask removal. Design: A cross-sectional, retrospective study. Setting: Five athletic equipment reconditioning/recertification facilities. Participants: 2584 helmets from 46 high school football teams representing 5 geographic regions. Intervention(s): Helmet characteristics (brand, model, hardware components) were recorded. Helmets were mounted and face mask removal was attempted using a cordless screwdriver. The 2004 season profiles and weather histories were obtained for each high school. Main Outcome Measure(s): Success and failure (including reason) for removal of 4 screws from the face mask were noted. Failure rates among regions, teams, reconditioning year, and screw color (type) were compared. Weather histories were compared. We conducted a discriminant analysis to determine if weather variables, region, helmet brand and model, reconditioning year, and screw color could predict successful face mask removal. Metallurgic analysis of screw samples was performed. Results: All screws were successfully removed from 2165 (84%) helmets. At least 1 screw could not be removed from 419 (16%) helmets. Significant differences were found for mean screw failure per helmet among the 5 regions, with the Midwest having the lowest failure rate (0.08 ± 0.38) and the Southern (0.33 ± 0.72), the highest. Differences were found in screw failure rates among the 46 teams (F1,45 = 9.4, P < .01). Helmets with the longest interval since last reconditioning (3 years) had the highest failure rate, 0.47 ± 0.93. Differences in success rates were found among 4 screw types (χ21,4 = 647, P < .01), with silver screws having the lowest percentage of failures (3.4%). A discriminant analysis (Λ = .932, χ214,n=2584 = 175.34, P < .001) revealed screw type to be the strongest predictor of

  19. Modeling of a Large-Scale High Temperature Regenerative Sulfur Removal Process

    DEFF Research Database (Denmark)

    Konttinen, Jukka T.; Johnsson, Jan Erik

    1999-01-01

    model that does not account for bed hydrodynamics. The pilot-scale test run results, obtained in the test runs of the sulfur removal process with real coal gasifier gas, have been used for parameter estimation. The validity of the reactor model for commercial-scale design applications is discussed.......Regenerable mixed metal oxide sorbents are prime candidates for the removal of hydrogen sulfide from hot gasifier gas in the simplified integrated gasification combined cycle (IGCC) process. As part of the regenerative sulfur removal process development, reactor models are needed for scale......-up. Steady-state kinetic reactor models are needed for reactor sizing, and dynamic models can be used for process control design and operator training. The regenerative sulfur removal process to be studied in this paper consists of two side-by-side fluidized bed reactors operating at temperatures of 400...

  20. Economic feasibility of EBFGT technology for removal of pollutants from combustion of liquid fuels

    International Nuclear Information System (INIS)

    Basfar, A. A.; Fageeha, O.I.; Kunnummal, N.; Al-Ghamdi, S.; Pawelec, A.; Chmielewski, A.G.; Tyminski, B.; Zimek, Z.; Licki, J.

    2011-01-01

    A project on feasibility of electron beam flue gas treatment (EBFGT) technology at oil fired boiler was conducted for Saudi Arabian Oil Company (Saudi Aramco). As part of this project, economic feasibility of EBFGT technology was performed for heavy oil fired boilers in Saudi Arabia. Economic evaluation was performed for two options of EBFGT installation; the first for 65 000 Nm3/h and the second for 130 000 Nm 3 /h. The main factors affecting investment and operation costs were discussed and costs were compared to conventional methods. The results of the evaluation showed that EBFGT method is economically attractive. (author)

  1. Economic feasibility of EBFGT technology for removal of pollutants from combustion of liquid fuels

    Energy Technology Data Exchange (ETDEWEB)

    Basfar, A. A. [King Abdulaziz City for Science and Technology, Atomic Energy Research Institute, Radiation Technology Center, Riyadh (Saudi Arabia); Fageeha, O. I.; Kunnummal, N.; Al-Ghamdi, S. [Saudi Arabian Oil Company (Saudi Aramco), Environmental Protection Department, Dhahran (Saudi Arabia); Pawelec, A.; Chmielewski, A. G.; Tyminski, B.; Zimek, Z. [Institute of Nuclear Chemistry and Technology, Warsaw (Poland); Licki, J. [Institute of Atomic Energy, Otwock-Świerk (Poland)

    2011-07-01

    A project on feasibility of electron beam flue gas treatment (EBFGT) technology at oil fired boiler was conducted for Saudi Arabian Oil Company (Saudi Aramco). As part of this project, economic feasibility of EBFGT technology was performed for heavy oil fired boilers in Saudi Arabia. Economic evaluation was performed for two options of EBFGT installation; the first for 65 000 Nm3/h and the second for 130 000 Nm{sup 3}/h. The main factors affecting investment and operation costs were discussed and costs were compared to conventional methods. The results of the evaluation showed that EBFGT method is economically attractive. (author)

  2. Low-cost route for synthesis of mesoporous silica materials with high silanol groups and their application for Cu(II) removal

    International Nuclear Information System (INIS)

    Wang Yangang; Huang Sujun; Kang Shifei; Zhang Chengli; Li Xi

    2012-01-01

    Graphical abstract: A simple and low-cost route to synthesize mesoporous silica materials with high silanol groups has been demonstrated by means of a sol–gel process using citric acid as the template and acid catalyst, further studies on the adsorption of Cu(II) onto the representative amine-functionalized mesoporous silica showed that it had a high Cu(II) removal efficiency. Highlights: ► A low-cost route to synthesize mesoporous silica with high silanol groups was demonstrated. ► Citric acid as the template and acid catalyst for the reaction of tetraethylorthosilicate. ► Water extraction method was an effective technique to remove template which can be recycled. ► The mesoporous silica with high silanol groups was easily modified by functional groups. ► A high Cu(II) removal efficiency on the amine-functionalized mesoporous silica. - Abstract: We report a simple and low-cost route for the synthesis of mesoporous silica materials with high silanol groups by means of a sol–gel process using citric acid as the template, tetraethylorthosilicate (TEOS) as the silica source under aqueous solution system. The citric acid can directly work as an acid catalyst for the hydrolysis of TEOS besides the function as a pore-forming agent in the synthesis. It was found that by using a water extraction method the citric acid template in as-prepared mesoporous silica composite can be easily removed and a high degree of silanol groups were retained in the mesopores, moreover, the citric acid template in the filtrate can be recycled after being dried. The structural properties of the obtained mesoporous silica materials were characterized by X-ray diffraction (XRD), scanning electron microscopy (SEM), transmission electron microscopy (TEM), Fourier transform infrared spectroscopy (FT-IR), and nitrogen adsorption–desorption analysis. Furthermore, an adsorption of Cu(II) from aqueous solution on the representative amine-functionalized mesoporous silica was investigated

  3. The Social, Historical, and Institutional Contingencies of Dam Removal

    Science.gov (United States)

    Magilligan, F. J.; Sneddon, C. S.; Fox, C. A.

    2017-06-01

    Environmental managers in the United States and elsewhere are increasingly perceiving dam removal as a critical tool for river restoration and enhancing watershed resilience. In New England, over 125 dams have been dismantled for ecological and economic rationales. A surprising number of these removals, including many that are ongoing, have generated heated conflicts between restoration proponents and local communities who value their dammed landscapes. Using a comparative case study approach, we examine the environmental conflict around efforts to remove six dams in New England. Each of these removal efforts followed quite different paths and resultant outcomes: successful removal, stalled removal, and failure despite seemingly favorable institutional conditions. Lengthy conflicts often transpired in instances where removals occurred, but these were successfully arbitrated by paying attention to local historical-geographical conditions conducive to removal and by brokering effective compromises between dam owners and the various local actors and stakeholders involved in the removal process. Yet our results across all cases suggest that these are necessary, but not sufficient conditions for restoration through dam removal since a similar set of conditions typified cases where removals are continuously stalled or completely halted. Scholars examining the intersection between ecological restoration and environmental politics should remain vigilant in seeking patterns and generalities across cases of environmental conflict in order to promote important biophysical goals, but must also remain open to the ways in which those goals are thwarted and shaped by conflicts that are deeply contingent on historical-geographical conditions and broader institutional networks of power and influence.

  4. The Social, Historical, and Institutional Contingencies of Dam Removal.

    Science.gov (United States)

    Magilligan, F J; Sneddon, C S; Fox, C A

    2017-06-01

    Environmental managers in the United States and elsewhere are increasingly perceiving dam removal as a critical tool for river restoration and enhancing watershed resilience. In New England, over 125 dams have been dismantled for ecological and economic rationales. A surprising number of these removals, including many that are ongoing, have generated heated conflicts between restoration proponents and local communities who value their dammed landscapes. Using a comparative case study approach, we examine the environmental conflict around efforts to remove six dams in New England. Each of these removal efforts followed quite different paths and resultant outcomes: successful removal, stalled removal, and failure despite seemingly favorable institutional conditions. Lengthy conflicts often transpired in instances where removals occurred, but these were successfully arbitrated by paying attention to local historical-geographical conditions conducive to removal and by brokering effective compromises between dam owners and the various local actors and stakeholders involved in the removal process. Yet our results across all cases suggest that these are necessary, but not sufficient conditions for restoration through dam removal since a similar set of conditions typified cases where removals are continuously stalled or completely halted. Scholars examining the intersection between ecological restoration and environmental politics should remain vigilant in seeking patterns and generalities across cases of environmental conflict in order to promote important biophysical goals, but must also remain open to the ways in which those goals are thwarted and shaped by conflicts that are deeply contingent on historical-geographical conditions and broader institutional networks of power and influence.

  5. Efficient Total Nitrogen Removal in an Ammonia Gas Biofilter through High-Rate OLAND

    DEFF Research Database (Denmark)

    De Clippeleir, Haydée; Courtens, Emilie; Mosquera, Mariela

    2012-01-01

    Ammonia gas is conventionally treated in nitrifying biofilters; however, addition of organic carbon to perform post-denitrification is required to obtain total nitrogen removal. Oxygen-limited autotrophic nitrification/denitrification (OLAND), applied in full-scale for wastewater treatment, can...... offer a cost-effective alternative for gas treatment. In this study, the OLAND application thus was broadened toward ammonia loaded gaseous streams. A down flow, oxygen-saturated biofilter (height of 1.5 m; diameter of 0.11 m) was fed with an ammonia gas stream (248 ± 10 ppmv) at a loading rate of 0...... at water flow rates of 1.3 ± 0.4 m3 m–2 biofilter section d–1. Profile measurements revealed that 91% of the total nitrogen activity was taking place in the top 36% of the filter. This study demonstrated for the first time highly effective and sustainable autotrophic ammonia removal in a gas biofilter...

  6. Technical and economic aspects of the transmission of energy at extra high voltages

    Energy Technology Data Exchange (ETDEWEB)

    Kahnt, R

    1967-01-01

    The reasons for the employment of higher transmission voltages are listed and the points decisive for the selection of three phase ac or dc systems are reviewed. A treatment of the technical and economic problems arising in three phase extra high voltage transmission is presented. These include selection of voltage, economical design of power lines, insulation problems, power supply dependability, equipment rating and reactive power and stability problems.

  7. Thermo-Economic Assessment of Advanced,High-Temperature CANDU Reactors

    International Nuclear Information System (INIS)

    Spinks, Norman J.; Pontikakis, Nikos; Duffey, Romney B.

    2002-01-01

    Research underway on the advanced CANDU examines new, innovative, reactor concepts with the aim of significant cost reduction and resource sustainability through improved thermodynamic efficiency and plant simplification. The so-called CANDU-X concept retains the key elements of the current CANDU designs, including heavy-water moderator that provides a passive heat sink and horizontal pressure tubes. Improvement in thermodynamic efficiency is sought via substantial increases in both pressure and temperature of the reactor coolant. Following on from the new Next Generation (NG) CANDU, which is ready for markets in 2005 and beyond, the reactor coolant is chosen to be light water but at supercritical operating conditions. Two different temperature regimes are being studied, Mark 1 and Mark 2, based respectively on continued use of zirconium or on stainless-steel-based fuel cladding. Three distinct cycle options have been proposed for Mark 1: the High-Pressure Steam Generator (HPSG) cycle, the Dual cycle, and the Direct cycle. For Mark 2, the focus is on simplification via a Direct cycle. This paper presents comparative thermo-economic assessments of the CANDU-X cycle options, with the ultimate goal of ascertaining which particular cycle option is the best overall in terms of thermodynamics and economics. A similar assessment was already performed for the NG CANDU. The economic analyses entail obtaining cost estimates of major plant components, such as heat exchangers, turbines and pumps. (authors)

  8. Nitrogen removal from sludge digester liquids by nitrification/denitrification or partial nitritation/anammox: environmental and economical considerations.

    Science.gov (United States)

    Fux, C; Siegrist, H

    2004-01-01

    In wastewater treatment plants with anaerobic sludge digestion, 15-20% of the nitrogen load is recirculated to the main stream with the return liquors from dewatering. Separate treatment of this ammonium-rich digester supernatant significantly reduces the nitrogen load of the activated sludge system. Two biological applications are considered for nitrogen elimination: (i) classical autotrophic nitrification/heterotrophic denitrification and (ii) partial nitritation/autotrophic anaerobic ammonium oxidation (anammox). With both applications 85-90% nitrogen removal can be achieved, but there are considerable differences in terms of sustainability and costs. The final gaseous products for heterotrophic denitrification are generally not measured and are assumed to be nitrogen gas (N2). However, significant nitrous oxide (N2O) production can occur at elevated nitrite concentrations in the reactor. Denitrification via nitrite instead of nitrate has been promoted in recent years in order to reduce the oxygen and the organic carbon requirements. Obviously this "achievement" turns out to be rather disadvantageous from an overall environmental point of view. On the other hand no unfavorable intermediates are emitted during anaerobic ammonium oxidation. A cost estimate for both applications demonstrates that partial nitritation/anammox is also more economical than classical nitrification/denitrification. Therefore autotrophic nitrogen elimination should be used in future to treat ammonium-rich sludge liquors.

  9. Assessment of commercially available ion exchange materials for cesium removal from highly alkaline wastes

    International Nuclear Information System (INIS)

    Brooks, K.P.; Kim, A.Y.; Kurath, D.E.

    1996-04-01

    Approximately 61 million gallons of nuclear waste generated in plutonium production, radionuclide removal campaigns, and research and development activities is stored on the Department of Energy's Hanford Site, near Richland, Washington. Although the pretreatment process and disposal requirements are still being defined, most pretreatment scenarios include removal of cesium from the aqueous streams. In many cases, after cesium is removed, the dissolved salt cakes and supernates can be disposed of as LLW. Ion exchange has been a leading candidate for this separation. Ion exchange systems have the advantage of simplicity of equipment and operation and provide many theoretical stages in a small space. The organic ion exchange material Duolite trademark CS-100 has been selected as the baseline exchanger for conceptual design of the Initial Pretreatment Module (IPM). Use of CS-100 was chosen because it is considered a conservative, technologically feasible approach. During FY 96, final resin down-selection will occur for IPM Title 1 design. Alternate ion exchange materials for cesium exchange will be considered at that time. The purpose of this report is to conduct a search for commercially available ion exchange materials which could potentially replace CS-100. This report will provide where possible a comparison of these resin in their ability to remove low concentrations of cesium from highly alkaline solutions. Materials which show promise can be studied further, while less encouraging resins can be eliminated from consideration

  10. Assessment of commercially available ion exchange materials for cesium removal from highly alkaline wastes

    Energy Technology Data Exchange (ETDEWEB)

    Brooks, K.P.; Kim, A.Y.; Kurath, D.E.

    1996-04-01

    Approximately 61 million gallons of nuclear waste generated in plutonium production, radionuclide removal campaigns, and research and development activities is stored on the Department of Energy`s Hanford Site, near Richland, Washington. Although the pretreatment process and disposal requirements are still being defined, most pretreatment scenarios include removal of cesium from the aqueous streams. In many cases, after cesium is removed, the dissolved salt cakes and supernates can be disposed of as LLW. Ion exchange has been a leading candidate for this separation. Ion exchange systems have the advantage of simplicity of equipment and operation and provide many theoretical stages in a small space. The organic ion exchange material Duolite{trademark} CS-100 has been selected as the baseline exchanger for conceptual design of the Initial Pretreatment Module (IPM). Use of CS-100 was chosen because it is considered a conservative, technologically feasible approach. During FY 96, final resin down-selection will occur for IPM Title 1 design. Alternate ion exchange materials for cesium exchange will be considered at that time. The purpose of this report is to conduct a search for commercially available ion exchange materials which could potentially replace CS-100. This report will provide where possible a comparison of these resin in their ability to remove low concentrations of cesium from highly alkaline solutions. Materials which show promise can be studied further, while less encouraging resins can be eliminated from consideration.

  11. Management of agricultural waste for removal of heavy metals from aqueous solution: adsorption behaviors, adsorption mechanisms, environmental protection, and techno-economic analysis.

    Science.gov (United States)

    Elhafez, S E Abd; Hamad, H A; Zaatout, A A; Malash, G F

    2017-01-01

    In the last decades, Egypt has been suffering from the phenomenon of black cloud resulting from burning rice husk and increasing the demand for water leading to the water crisis. An alternative, low-value and surplus agricultural byproduct (rice husk, RH) has an enormous potential for the removal of Cu(II) ions from water. The present study focuses on the chance of the use of rice husk as a bio-adsorbent without any chemical treatment instead of burning it and soiling the environment. The elemental, structural, morphological, surface functional, thermal, and textural characteristics of RH are determined by XRF, XRD, SEM, FT-IR, TGA, and BET surface area, respectively, and contributed to the understanding of the adsorption mechanism of Cu(II) ions in aqueous solution. Also, the performance analysis, adsorption mechanism, influencing factors, favorable conditions, etc. are discussed in this article. The results obtained from optimization by batch mode are achieved under the following conditions: initial concentration, 150 ppm; amount of rice husk, 1 g; average particle size, 0.25 mm; temperature, 25 °C; pH, 4; agitation rate, 180 rpm; and contact time, 60 min. RH exhibits a high degree of selectivity for Cu(II) adsorption. The adsorption isotherm is fitted well with Langmuir and Freundlich models with R 2 0.998 and 0.997, respectively. The adsorption is well governed by the pseudo-second-order kinetics. It is observed that the rate of adsorption improves with decreasing temperature, and the process is exothermic and non-spontaneous. Particular attention has being paid to factors as production processes, fixed/operational cost, production cost, and profit. The techno-economical analysis is presented in this study that provides precise demands on capital for a fixed investment, provisions for operational capital, and finally provisions for revenue. The social, economical, and environmental benefits by industrial point of view using low-cost adsorbent are also

  12. Geochemistry of Toxic Elements and Their Removal via the Preparation of High-Uranium Coal in Southwestern China

    Directory of Open Access Journals (Sweden)

    Piaopiao Duan

    2018-02-01

    Full Text Available High-uranium (U coal is the dominant form of coal in Southwestern China. However, directly utilizing this resource can also harm the environment because this element is radioactive; it is, therefore, necessary to clean this kind of coal before burning. This research studied the geochemistry of toxic elements and their partitioning during the preparation of high-U coal in China. The results show that high-U coals are mainly distributed in Southwestern China and are characterized by a high organic sulfur (S content and vanadium (V-chromium (Cr-molybdenum (Mo-U element assemblage. These elements are well-correlated with one another, but are all negatively related to ash yield, indicating that all four are syngenetic in origin and associated with organic materials. A mineralogical analysis shows that U in Ganhe and Rongyang coal occurs within fine-grained anatase, clay minerals, guadarramite, and pyrite, while V occurs in clay minerals, pyrite, and dolomite, and Cr occurs in dolomite. Other elements, such as fluorine (F, lead (Pb, selenium (Se, and mercury (Hg, mainly occur in pyrite. By applying a gravity separation method to separate minerals from coal, the content of the enrichment element assemblage of V-Cr-Mo-U in Rongyang coal is still shown to be higher than, or close to, that of the original feed because this element assemblage is derived from hydrothermal fluids during syngenetic or early diagenetic phases, but other elements (beryllium [Be], F, manganese [Mn], zinc [Zn], Pb, arsenic [As], Se, Hg can be efficiently removed. Once cleaned, the coal obtained by gravity separation was subject to a flotation test to separate minerals; these results indicate that while a portion of V and Cr can be removed, Mo and U remain difficult to extract. It is evident that the two most commonly utilized industrialized coal preparation methods, gravity separation and flotation, cannot effectively remove U from coal where this element occurs in large

  13. High surface area mesoporous activated carbon-alginate beads for efficient removal of methylene blue.

    Science.gov (United States)

    Nasrullah, Asma; Bhat, A H; Naeem, Abdul; Isa, Mohamed Hasnain; Danish, Mohammed

    2018-02-01

    High surface area mesoporous activated carbon-alginate (AC-alginate) beads were successfully synthesized by entrapping activated carbon powder derived from Mangosteen fruit peel into calcium-alginate beads for methylene blue (MB) removal from aqueous solution. The structure and surface characteristics of AC-alginate beads were analyzed using Fourier transform infra-red (FTIR) spectroscopy, scanning electron microscopy (SEM) and surface area analysis (S BET ), while thermal properties were tested using thermogravimetric analysis (TGA). The effect of AC-alginate dose, pH of solution, contact time, initial concentration of MB solution and temperature on MB removal was elucidated. The results showed that the maximum adsorption capacity of 230mg/g was achieved for 100mg/L of MB solution at pH 9.5 and temperature 25°C. Furthermore, the adsorption of MB on AC-alginate beads followed well pseudo-second order equation and equilibrium adsorption data were better fitted by the Freundlich isotherm model. The findings reveal the feasibility of AC-alginate beads composite to be used as a potential and low cost adsorbent for removal of cationic dyes. Copyright © 2017 Elsevier B.V. All rights reserved.

  14. High economic inequality leads higher-income individuals to be less generous

    Science.gov (United States)

    Côté, Stéphane; House, Julian; Willer, Robb

    2015-01-01

    Research on social class and generosity suggests that higher-income individuals are less generous than poorer individuals. We propose that this pattern emerges only under conditions of high economic inequality, contexts that can foster a sense of entitlement among higher-income individuals that, in turn, reduces their generosity. Analyzing results of a unique nationally representative survey that included a real-stakes giving opportunity (n = 1,498), we found that in the most unequal US states, higher-income respondents were less generous than lower-income respondents. In the least unequal states, however, higher-income individuals were more generous. To better establish causality, we next conducted an experiment (n = 704) in which apparent levels of economic inequality in participants’ home states were portrayed as either relatively high or low. Participants were then presented with a giving opportunity. Higher-income participants were less generous than lower-income participants when inequality was portrayed as relatively high, but there was no association between income and generosity when inequality was portrayed as relatively low. This research finds that the tendency for higher-income individuals to be less generous pertains only when inequality is high, challenging the view that higher-income individuals are necessarily more selfish, and suggesting a previously undocumented way in which inequitable resource distributions undermine collective welfare. PMID:26598668

  15. High economic inequality leads higher-income individuals to be less generous.

    Science.gov (United States)

    Côté, Stéphane; House, Julian; Willer, Robb

    2015-12-29

    Research on social class and generosity suggests that higher-income individuals are less generous than poorer individuals. We propose that this pattern emerges only under conditions of high economic inequality, contexts that can foster a sense of entitlement among higher-income individuals that, in turn, reduces their generosity. Analyzing results of a unique nationally representative survey that included a real-stakes giving opportunity (n = 1,498), we found that in the most unequal US states, higher-income respondents were less generous than lower-income respondents. In the least unequal states, however, higher-income individuals were more generous. To better establish causality, we next conducted an experiment (n = 704) in which apparent levels of economic inequality in participants' home states were portrayed as either relatively high or low. Participants were then presented with a giving opportunity. Higher-income participants were less generous than lower-income participants when inequality was portrayed as relatively high, but there was no association between income and generosity when inequality was portrayed as relatively low. This research finds that the tendency for higher-income individuals to be less generous pertains only when inequality is high, challenging the view that higher-income individuals are necessarily more selfish, and suggesting a previously undocumented way in which inequitable resource distributions undermine collective welfare.

  16. New Technologys in Atrazine Removal from Environment with Emphasis on Biodegradation: A Review

    Directory of Open Access Journals (Sweden)

    Z Derakhshan

    2016-09-01

    Full Text Available Introduction:Considering the lack of agricultural lands and the loss of products by pests, utilization of pesticides like atrazine has increased. Due to low vapor pressure, high half-life, and high mobility, this herbicide results in pollution of different ecosystems. In regard with its toxicity, US Environmental Protection Agency has ranked atrazine in III class. Due to its potential capacity in polluting groundwater, it is highly significant. Methods: Many chemical and physical methods have been introduced to remove this herbicide from soil and water environments; however, these methods involve high expenses and cause the creation of other toxic products. Due to development of the science of interaction between man and nature, nowadays biological treatment is uniquely significant. Biological treatment is a process in which microorganisms are utilized to convert and decompose pollutants existing in the environment. Conclusion: Biodegradation is economically and environmentally the best approach to remove long-standing pollutants from the environment. Nowadays, genetic engineering extensively utilizes local or modified microorganisms in treating the environments polluted with pesticides. Finally, in order to further utilize this green technology, it is necessary to specify the soil properties and also conduct ecotoxicological studies in order to identify the capacity of local microorganisms of water and soil.

  17. Space debris removal using a high-power ground-based laser

    Energy Technology Data Exchange (ETDEWEB)

    Monroe, D.K.

    1993-12-31

    The feasibility and practicality of using a ground-based laser (GBL) to remove artificial space debris is examined. Physical constraints indicate that a reactor-pumped laser (RPL) may be best suited for this mission, because of its capabilities for multimegawatt output long run-times, and near-diffraction-limited initial beams. Simulations of a laser-powered debris removal system indicate that a 5-MW RPL with a 10-meter-diameter beam director and adaptive optics capabilities can deorbit 1-kg debris from space station altitudes. Larger debris can be deorbited or transferred to safer orbits after multiple laser engagements. A ground-based laser system may be the only realistic way to access and remove some 10,000 separate objects, having velocities in the neighborhood of 7 km/sec, and being spatially distributed over some 10{sup 10} km{sup 3} of space.

  18. High performance maleated lignocellulose epicarp fibers for copper ion removal

    Directory of Open Access Journals (Sweden)

    A. P. Vieira

    2014-03-01

    Full Text Available Natural lignocellulosic fiber epicarp extracted from the babassu coconut (Orbignya speciosa was chemically modified through reaction with molten maleic anhydride without solvent, with incorporation of 189.34 mg g-1 of carboxylic acid groups into the biopolymer structure. The success of this reaction was also confirmed by the presence of carboxylic acid bands at 1741 and 1164 cm-1 in the infrared spectrum. Identically, the same group is observed through 13C NMR CP/MAS in the solid state, via high field signals in the 167 pm region. Both the precursor and the immobilized maleated biopolymers presented nearly the same thermal stability and similar crystallinity to cellulose. However, the pendant carboxylic groups have the ability to remove copper with maximum sorption through a batchwise process at pH 6.0, as expected from the point of zero charge, determined to be 6.45. The sorption kinetic data were fitted to pseudo-first order, pseudo-second order, Elovich-chemisorption and intra-particle diffusion models and the equilibrium data were fitted to the Langmuir, the Freundlich and Tenkim isotherm models. Taking into account a statistical error function and determination coefficients, the data were fit to the pseudo-first and pseudo-second order kinetic and Langmuir isotherm models, with a maximum sorption capacity of copper ions of 55.09 mg g-1. This value suggests the application of this biopolymer with incorporated carboxylate groups as a favorable agent for copper removal from appropriate systems.

  19. Fracture of fusion mass after hardware removal in patients with high sagittal imbalance.

    Science.gov (United States)

    Sedney, Cara L; Daffner, Scott D; Stefanko, Jared J; Abdelfattah, Hesham; Emery, Sanford E; France, John C

    2016-04-01

    patients who underwent surgery for ASD after a remote fusion. These patients later developed a fracture of the fusion mass after hardware removal from their previously successfully fused segment. All patients had a high sagittal imbalance and had previously undergone multiple spinal operations. The development of a spontaneous fracture of the fusion mass may be related to sagittal imbalance. Consideration should be given to reimplanting hardware for these patients, even across good fusions, to prevent spontaneous fracture of these areas if the sagittal imbalance is not corrected.

  20. Removal of Arsenic Using Acid/Metal-Tolerant Sulfate Reducing Bacteria: A New Approach for Bioremediation of High-Arsenic Acid Mine Waters

    Directory of Open Access Journals (Sweden)

    Jennyfer Serrano

    2017-12-01

    Full Text Available Fluvial sediments, soils, and natural waters in northern Chile are characterized by high arsenic (As content. Mining operations in this area are potential sources of As and other metal contaminants, due to acid mine drainage (AMD generation. Sulfate Reducing Bacteria (SRB has been used for the treatment of AMD, as they allow for the reduction of sulfate, the generation of alkalinity, and the removal of dissolved heavy metals and metalloids by precipitation as insoluble metal sulfides. Thus, SRB could be used to remove As and other heavy metals from AMD, however the tolerance of SRB to high metal concentrations and low pH is limited. The present study aimed to quantify the impact of SRB in As removal under acidic and As-Fe-rich conditions. Our results show that SRB tolerate low pH (up to 3.5 and high concentrations of As (~3.6 mg·L−1. Batch experiments showed As removal of up to 73%, Iron (Fe removal higher than 78% and a neutralization of pH from acidic to circum-neutral conditions (pH 6–8. In addition, XRD analysis showed the dominance of amorphous minerals, while Scanning Electron Microscopy/Energy Dispersive X-ray Spectroscopy (SEM-EDX analysis showed associations between As, Fe, and sulfur, indicating the presence of Fe-S-As compounds or interaction of As species with amorphous and/or nanocrystalline phases by sorption processes. These results indicate that the As removal was mediated by acid/metal-tolerant SRB and open the potential for the application of new strains of acid/metal-tolerant SRB for the remediation of high-As acid mine waters.

  1. The removal of plutonium contaminants from Rocky Flats Plant soil

    International Nuclear Information System (INIS)

    Sunderland, N.R.

    1987-01-01

    This research was undertaken to determine if the TRUclean process could effectively remove radioactive elements from soils other than derived coral. This is an interim report prior to the project report and discusses the outcome of the tests of the Rocky Flats Plant (RFP) soil. The soil tested contained plutonium particulates in the micron and submicron range. Volume reduction and activity removal were accomplished with an overall efficiency of greater than 90%. The TRUclean process is a very practical and economical solution to soil contamination problems at the Rocky Flats Plant

  2. Large-scale treatment of high-salt, high-pH wastewater for {sup 137}Cs and {sup 90}Sr removal, using crystalline silicotitanate resin

    Energy Technology Data Exchange (ETDEWEB)

    Taylor, P.A.; Walker, J.F.; Lee, D.D.

    1998-04-01

    A full-scale demonstration of cesium removal technology has been conducted at Oak Ridge National Laboratory (ORNL). This demonstration utilized a modular, mobile ion-exchange system and existing facilities for the off-gas system, secondary containment, and utilities. The ion-exchange material, crystalline silicotitanate (CST), was selected on the basis of its effectiveness in laboratory tests. The CST, which was developed through a Cooperative Research and Development Agreement between DOE and private industry, is highly selective for removing cesium from solutions containing high concentrations of other contaminants, such as sodium and potassium. Approximately 116,000 liters of supernate was processed during the demonstration with {approximately} 1,142 Ci of {sup 137}Cs removed from the supernate and loaded onto 266 liters of the CST sorbent. The supernate processed had a high salt content, about 4 M NaNO{sub 3} and a pH of 12 to 13. The CST also loaded Ba, Pb, Sr, U and Zn. Analysis of the spent sorbent has shown that it is not hazardous under the Resource Conservation and Recovery Act (RCRA). The cesium breakthrough curves for the lab and full-scale columns agreed very well, suggesting that lab-scale tests can be used to predict the performance of larger systems. The cesium breakthrough curves for runs at different flowrates show that film diffusion is significant in controlling the mass transfer process. Operational factors that increase the effect of film diffusion include the small size and high porosity of the CST sorbent, and the relatively low liquid velocity through the sorbent.

  3. Arsenic removal in solution using non living bio masses of aquatic weed

    International Nuclear Information System (INIS)

    Marin A, M. J.

    2010-01-01

    Arsenic is a metalloid considered among the most dangerous to health. The As maximum level allowed of drinkable water is 0.01 mg/L established by the Who. Several techniques have been proposed to remove arsenic from water, among which are the sorption processes in economic biological materials, which has advantages for its high efficiency in dilute toxic removing from contaminated water, for these reason it is necessary to study new bio sorbents materials which are economic, simple and easy to apply in the treatment of contaminated areas. The aim of this project was evaluate the removal of As (V) in solution using two non living aquatic plants: water hyacinth (Eichhornia crassipes) and lesser duckweed (Lemna minor), characterize these materials and compare the efficiency between both; the parameters evaluated were the As (V) initial concentration in solution, contact time, ph value and the amount of biomass in contact with them. It describes the method to prepare the non living plants. The physicochemical characterization by scanning electron microscopy, X-ray diffraction, Fourier transform infrared spectroscopy, thermogravimetric analysis was made. The results shown that cellulose is the main component confirmed by the techniques above mentioned. Surface characterization of Eichhornia crassipes and Lemna minor by specific surface area, shown 1.3521 m 2 /g and 0.6395 m 2 /g respectively, the hydration kinetic indicates that 24 h was the maximum hydration time for both plants; the point of zero charge determination by mass titration gives a ph=6.1 for the first plant and ph=7.1 for the second plant, finally the active site density obtained for the plants were of 8.57 sites/nm 2 and 12.47 sites/nm 2 . The point of zero charge was analyzed for know the ph from which the As (V) species are removal preferably. Tested contact processes between bio sorbent-As (V) were performed to assess the ability of bio masses to removal As (V) from aqueous solutions, investigated

  4. Potential and costs of carbon dioxide removal by enhanced weathering of rocks

    Science.gov (United States)

    Strefler, Jessica; Amann, Thorben; Bauer, Nico; Kriegler, Elmar; Hartmann, Jens

    2018-03-01

    The chemical weathering of rocks currently absorbs about 1.1 Gt CO2 a-1 being mainly stored as bicarbonate in the ocean. An enhancement of this slow natural process could remove substantial amounts of CO2 from the atmosphere, aiming to offset some unavoidable anthropogenic emissions in order to comply with the Paris Agreement, while at the same time it may decrease ocean acidification. We provide the first comprehensive assessment of economic costs, energy requirements, technical parameterization, and global and regional carbon removal potential. The crucial parameters defining this potential are the grain size and weathering rates. The main uncertainties about the potential relate to weathering rates and rock mass that can be integrated into the soil. The discussed results do not specifically address the enhancement of weathering through microbial processes, feedback of geogenic nutrient release, and bioturbation. We do not only assess dunite rock, predominantly bearing olivine (in the form of forsterite) as the mineral that has been previously proposed to be best suited for carbon removal, but focus also on basaltic rock to minimize potential negative side effects. Our results show that enhanced weathering is an option for carbon dioxide removal that could be competitive already at 60 US  t-1 CO2 removed for dunite, but only at 200 US  t-1 CO2 removed for basalt. The potential carbon removal on cropland areas could be as large as 95 Gt CO2 a-1 for dunite and 4.9 Gt CO2 a-1 for basalt. The best suited locations are warm and humid areas, particularly in India, Brazil, South-East Asia and China, where almost 75% of the global potential can be realized. This work presents a techno-economic assessment framework, which also allows for the incorporation of further processes.

  5. Removal of methadone by extended dialysis using a high cut-off dialyzer: implications for the treatment of overdose and for pain management in patients undergoing light chain removal.

    Science.gov (United States)

    Arelin, Viktor; Schmidt, Julius J; Kayser, Nathalie; Kühn-Velten, W Nikolaus; Suhling, Hendrik; Eden, Gabriele; Kielstein, Jan T

    2016-06-01

    The synthetic opioid methadone hydrochloride has a low molecular weight of 346 D, a high volume of distribution (4 - 7 L/kg), and is lipophilic. It is used as an analgesic and for the maintenance treatment of opiate dependence. In drug addicts, methadone is frequently involved in mixed intoxications that can lead to death. Here we present the case of a drug addict in whom a high cut-off dialysis membrane together with extended dialysis was used in the setting of suspected overdose and acute kidney injury. Although the observed dialyzer plasma clearance (31.5 mL/min) and reduction ratio (38%) were higher than previously reported for standard hemodialysis, the total amount of methadone in the spent dialysate after 1 extended dialysis session was quite low. Hence, even extended dialysis with a high cut-off membrane does not seem to offer a clinically relevant benefit in the setting of overdose for enhanced methadone removal. On the other hand, in patients undergoing high cut-off dialysis for the removal of light chains, methadone could still be used as an analgesic without an additional dose after high cut-off hemodialysis.

  6. Synergistic effect of manganese dioxide and diatomite for fast decolorization and high removal capacity of methyl orange.

    Science.gov (United States)

    Peng, Hui Hua; Chen, Jie; Jiang, De Yi; Li, Min; Feng, Li; Losic, Dusan; Dong, Fan; Zhang, Yu Xin

    2016-12-15

    MnO 2 nanostructures with two different morphologies (nanowires and nanosheets) were uniformly deposited on diatomite via a one-pot hydrothermal method. The fast decolorization and high removal capacity for anionic dye-MO over synthesized composites had been clarified. The results revealed that the equilibrium time was shortened to as low as 10-30min, and the maximum adsorption capacities were 325mgg -1 and 420mgg -1 for nanowires and nanosheets composites, respectively, under the condition of initial pH 3 and ambient temperature. Indeed, the proposed decolorization mechanism was considered to be simultaneous multi-processes during the dye removal, including physical, physicochemical and chemical process. In principle, well-controlled cost-effective composites have promising ability to remove anionic dye pollutants for environmental remediation. Copyright © 2016 Elsevier Inc. All rights reserved.

  7. The Value Chains of High-Technology Products as Factor of formation the Regional Comprehensive Economic Partnership

    Directory of Open Access Journals (Sweden)

    Irina A. Safronova

    2016-01-01

    Full Text Available This article analyzes the value chain of high-tech products in Asia and the role of this phenomenon in the further consolidation of trade blocs and alliances in the region. The presence of these chains and their gradual transition from a vertically integrated model to a system of horizontal linkages and interdependence leads to the formation of mechanisms of economic de-facto integration (so-called regionalization process. The East Asian region has demonstrated unprecedented high rates of economic growth in recent decades. The countries are actively developing mechanisms of multilateral cooperation, involving partners from across the Asia-Pacific region. Particular features of a new regional architecture of economic relations are becoming more tangible, and the essential element of this architecture is the intra-regional integration. The author presents an assessment of further developments of the Regional comprehensive economic partnership (RCEP using the structural-functional approach and analytical instruments of the international political economy, The creation of this trade block will help less advanced countries of ASEAN to accelerate economic growth and improve the conditions for integration into global value chains. For advanced economies, participation in the RCEP seems controversial, because production chains have well-established formats within the framework of ASEAN +. The political standoff between Washington and Beijing has an impact on dynamics of regional integration. The split among the East Asian countries was galvanized by the Trans-Pacific Partnership Project (TTP, because TPP has objectives that are very similar to those of RCEP (trade liberalization and economic integration. The author concludes that the extension of this partnership in the ASEAN countries can seriously complicate the operation RVEP and enhance the impact of political factors on economic cooperation. In this case, the value of production and supply chains

  8. Techniques for removing contaminated concrete surfaces

    International Nuclear Information System (INIS)

    Halter, J.M.; Sullivan, R.G.

    1981-01-01

    This discussion compares various techniques that have been used to clean concrete surfaces by removing the surface. Three techniques which have been investigated by the Pacific Northwest Laboratory for removing surfaces are also described: the water cannon, the concrete spaller, and high-pressure water jet. The equipment was developed with the assumption that removal of the top 1/8 to 1/4 in. of surface would remove most of the contamination. If the contamination has gone into cracks or deep voids in the surface, the removal processes can be repeated until the surface is acceptable

  9. High-energy two-neutron removal from Be{sup 10}

    Energy Technology Data Exchange (ETDEWEB)

    Ashwood, N.I.; Freer, M.; Ahmed, S.; Clarke, N.M.; Curtis, N.; Soic, N.; Ziman, V.A. [Birmingham Univ., School of Physics and Astronomy, (United Kingdom); Millener, D.J. [Brookhaven National Lab., Upton, NY (United States); Orr, N.A.; Carstoiu, F.; Angelique, J.C.; Catford, W.N.; Lecouey, J.L.; Marques, F.M.; Normand, G.; Timis, C. [Caen Univ., Lab. de Physique Corpusculaire, ISMRA, IN2P3-CNRS, 14 (France); Carsoiu, F. [Horia Hulubei National institute of Physics and Nuclear Engineering (IFIN-HH), Bucharest-Magurele (Romania); Bouchat, V.; Hanappe, F.; Kerckx, Y.; Materna, T. [Universite Libre de Bruxelles (Belgium); Catford, W.N.; Pain, S.; Timis, C. [Surrey Univ., School of Electronics and Physical Sciences, Guildford (United Kingdom); Horoi, M. [Central Michigan Univ., Physics Dept., Mount Pleasant, MI (United States); Unshakova, A. [Joint Institute for Nuclear Research Dubna (Russian Federation)

    2005-09-15

    A kinetically complete measurement of the {sup 12}C({sup 10}Be, {alpha}+{alpha}+n) and ({sup 10}Be, {alpha}+{alpha}) reactions has been performed at a beam energy of 30 MeV/nucleon. The charged beam velocity particles were detected in an array of Si-CsI detectors placed at zero degrees, and the neutrons in an 81-element neutron array. The coincident detection of the final-state particles, produced in the breakup of {sup 10}Be, allowed the reconstruction of the excitation energy in the {sup 8}Be and {sup 9}Be systems. States in {sup 8}Be were identified, in particular the ground and first-excited states; and in {sup 9}Be, states at 1.68, 2.43, and (2.78, 3.05) MeV were observed. The population of these levels, in particular the 2.43 MeV 5/2- level, suggests that collective excitations play an important role in the neutron removal process. Distorted wave Born approximation and Glauber-type calculations have been used to model the direct neutron removal from the {sup 10}Be ground state and the two-step removal via inelastic excitations of the {sup 10}Be(2{sup +}) and {sup 9}Be(5/2{sup -}) excited states. (authors)

  10. Removal of Organic Pollutants from Municipal Wastewater by Applying High-Rate Algal Pond in Addis Ababa, Ethiopia

    Science.gov (United States)

    Alemu, Keneni; Assefa, Berhanu; Kifle, Demeke; Kloos, Helmut

    2018-05-01

    The discharge of inadequately treated municipal wastewater has aggravated the pollution load in developing countries including Ethiopia. Conventional wastewater treatment methods that require high capital and operational costs are not affordable for many developing nations, including Ethiopia. This study aimed to investigate the performance of two high-rate algal ponds (HRAPs) in organic pollutant removal from primary settled municipal wastewater under highland tropical climate conditions in Addis Ababa. The experiment was done for 2 months at hydraulic retention times (HRTs) ranging from 2 to 8 days using an organic loading rates ranging 333-65 kg {BOD}5 /ha/day using two HRAPs, 250 and 300 mm deep, respectively. In this experiment, Chlorella sp., Chlamydomonas sp., and Scenedesmus sp., the class of Chlorophyceae, were identified as the dominant species. Chlorophyll-a production was higher in the shallower ponds (250 mm) throughout the course of the study, whereas the deeper HRAP (300 mm) showed better dissolved oxygen production. The maximum COD and {BOD}5 removal of 78.03 and 81.8% was achieved at a 6-day HRT operation in the 250-mm-deep HRAP. Therefore, the 300-mm-deep HRAP is promising for scaling up organic pollutant removal from municipal wastewater at a daily average organic loading rate of 109.3 kg {BOD}5 /ha/day and a 6-day HRT. We conclude that the removal of organic pollutants in HRAP can be controlled by pond depth, organic loading rate, and HRT.

  11. Use of ionizing radiation for color removal and increased biodegradability in tannery wastes

    International Nuclear Information System (INIS)

    Hyfantis, G.J. Jr.

    1977-01-01

    The special problems associated with the treatment of waste-waters generated by the vegetable leather tanning process have been studied to determine their treatability utilizing ionizing radiation. Conventional treatment schemes do not provide an effective means for the removal of color from vegetable tanning wastes. Radiation treatment is an advanced treatment method that does effectively remove the color. In addition to color removal, radiation treatment of vegetable tanning wastes increases the biodegradability. The results of this study show that radiation treatment of wastes offers a viable method for removing color and increasing biodegradability. An economic analysis, which is also included, indicates that in the near future radiation treatment will be competitive with other advanced waste treatment methods

  12. Removing high-level contaminants

    International Nuclear Information System (INIS)

    Wallace, Paula

    2013-01-01

    Full text: Using biomimicry, an Australian cleantech innovation making inroads intoChinas's industrial sector offers multiple benefits to miners and processors in Australia. Stephen Shelley, the executive chairman of Creative Water Technology (CWT), was on hand at a recent trade show to explain how his Melbourne company has developed world-class techniques in zero liquid discharge and fractional crystallization of minerals to apply to a wide range of water treatment and recycling applications. “Most existing technologies operate with high energy distillation, filters or biological processing. CWT's appliance uses a low temperature, thermal distillation process known as adiabatic recovery to desalinate, dewater and/or recycle highly saline and highly contaminated waste water,” said Shelley. The technology has been specifically designed to handle the high levels of contaminant that alternative technologies struggle to process, with proven water quality results for feed water samples with TDS levels over 300,000ppm converted to clean water with less than 20ppm. Comparatively, reverse osmosis struggles to process contaminant levels over 70,000ppm effectively. “CWT is able to reclaim up to 97% clean usable water and up to 100% of the contaminants contained in the feed water,” said Shelley, adding that soluble and insoluble contaminants are separately extracted and dried for sale or re-use. In industrial applications CWT has successfully processed feed water with contaminant levels over 650,000 mg/1- without the use of chemicals. “The technology would be suitable for companies in oil exploration and production, mining, smelting, biofuels, textiles and the agricultural and food production sectors,” said Shelley. When compared to a conventional desalination plant, the CWT system is able to capture the value in the brine that most plants discard, not only from the salt but the additional water it contains. “If you recover those two commodities... then you

  13. Zirconium-based metal organic frameworks: Highly selective adsorbents for removal of phosphate from water and urine

    Energy Technology Data Exchange (ETDEWEB)

    Lin, Kun-Yi Andrew, E-mail: linky@nchu.edu.tw [Department of Environmental Engineering, National Chung Hsing University, 250 Kuo-Kuang Road, Taichung, Taiwan (China); Chen, Shen-Yi [Department of Environmental Engineering, National Chung Hsing University, 250 Kuo-Kuang Road, Taichung, Taiwan (China); Jochems, Andrew P. [New Mexico Bureau of Geology & Mineral Resources and New Mexico Institute of Mining & Technology, Socorro, NM (United States)

    2015-06-15

    Phosphate is one of the most concerning compounds in wastewater streams and a main nutrient that causes eutrophication. To eliminate the phosphate pollution, Metal Organic Frameworks (MOFs) are proposed in this study as adsorbents to remove phosphate from water. The zirconium-based MOF, UiO-66, was selected as representative MOF given its exceptional stability in water. To investigate the effect of an amine functional group, UiO-66-NH2 was also prepared using an amine-substituted ligand. The adsorption kinetics and isotherm reveal that UiO-66-NH2 exhibited higher adsorption capacities than UiO-66 possibly due to the amine group. However, the interaction between phosphate and zirconium sites of UiO MOFs might be the primary factor accounting for the phosphate adsorption to UiO MOFs. UiO MOFs also exhibited a high selectivity towards phosphate over other anions such as bromate, nitrite and nitrate. Furthermore, UiO MOFs were found to adsorb phosphate and to completely remove diluted phosphate in urine. We also found that UiO MOFs could be easily regenerated and re-used for phosphate adsorption. These findings suggest that UiO MOFs can be effective and selective adsorbents to remove phosphate from water as well as urine. - Highlights: • UiO-66 as the first type of MOFs was used to remove phosphate from water and urine. • The amine group in UiO MOFs was found to enhance the phosphate adsorption. • UiO-66 exhibited a high adsorption selectivity towards phosphate over other anions. • UiO-66 could be easily regenerated and re-used with 85% regeneration efficiency.

  14. Techno-economic analysis of seawater desalination using high temperature gas cooled reactor

    International Nuclear Information System (INIS)

    Wu Linchun; Qin Zhenya

    2001-01-01

    Our world, including China (especially in big cities and foreland), is facing the increased global shortage of potable water and pollution of water. It is ideal to promote seawater desalination to satisfy the potable water demand in these areas. Among the various processes, MED, RO and VC have proven well developed and promising. Due to the inherent safety and its vapor produced with high parameters and features of small size and modular design, HTGR (High Temperature Gas-cooled Reactor) of 2x200MW is chosen as the energy source for the desalination in dual production of clean water and power. This paper discusses the techno-economic feasibility of different seawater desalting systems using 2x200MW HTGR in the areas mentioned above, that is, ST-MED (Steam Turbine Cycle), RO, MED/TVC, RO/MED and GT-MED (Gas Turbine Cycle). The exergy concept is used in calculating availability to get cost of energy in desalination, and power credit method is used in economic assessment of different systems to get reasonable evaluating, while economic-life levelized cost method is adopted for calculating electricity cost of referred HTGR plant. In addition, sensitivity analysis on ST-MED economy is also presented. (author)

  15. High Efficient Nanocomposite for Removal of Heavy Metals (Hg2+ and Pb2+ from Aqueous Solution

    Directory of Open Access Journals (Sweden)

    M. Ebadi

    2016-01-01

    Full Text Available In current work, CdS/black carbon nanocomposites were successfully synthesized with the aid of chestnut and cadmium nitrate as the starting reagents. Besides, the effects of preparation parameters such as reaction time, and precursor concentration on the morphology of products and removal of heavy metals (Hg+2, Pb+2 were studied by scanning electron microscopy images and batch adsorption mode. CdS/black carbon nanocomposite introduced as new and high efficient system for removal of heavy metal ions. The as-synthesized products were characterized by powder X-ray diffraction, scanning electron microscopy, and spectra energy dispersive analysis of X-ray.

  16. Economic appraisal of deployment schedules for high-level radioactive waste repositories

    International Nuclear Information System (INIS)

    Hoai Linh Doan, Phuong; Duquesnoy, T.; Devezeaux de Lavergne, J.G.

    2017-01-01

    The deep geological repository (DGR) is considered as the definitive management solution for high-level radioactive waste (HLW). Countries defined different DGR implementation schedules, depending on their national context and political choices. We raise the question of the economic grounds of such political decisions by providing an economic analysis of different DGR schedules. We investigate the optimal timing for DGR commissioning based on available Nuclear Energy Agency (NEA) data (2013). Two scenarios are considered: -1) rescheduling the deployment of a DGR with the same initial operational period, and -2) rescheduling the deployment of a DGR with a shorter operational period, i.e. initial closure date. Given the long timescales of such projects, we also take into account the discounting effect. The first finding is that it appears more economically favorable to extend the interim storage than to dispose of the HLW immediately. Countries which chose 'immediate' disposal are willing to accept higher costs to quickly solve the problem. Another interesting result is that there is an optimal solution with respect to the length of DGR operational period and the waste flow for disposal. Based on data provided by the Organisation for Economic Cooperation and Development (OECD)/Nuclear Energy Agency (NEA), we find an optimal operating period of about 15 years with a flow of 2000 tHM/year. (authors)

  17. Economic appraisal of deployment schedules for high-level radioactive waste repositories

    Directory of Open Access Journals (Sweden)

    Doan Phuong Hoai Linh

    2017-01-01

    Full Text Available The deep geological repository (DGR is considered as the definitive management solution for high-level waste (HLW. Countries defined different DGR implementation schedules, depending on their national context and political choices. We raise the question of the economic grounds of such political decisions by providing an economic analysis of different DGR schedules. We investigate the optimal timing for DGR commissioning based on available Nuclear Energy Agency (NEA data (2013. Two scenarios are considered: (1 rescheduling the deployment of a DGR with the same initial operational period, and (2 rescheduling the deployment of a DGR with a shorter operational period, i.e. initial closure date. Given the long timescales of such projects, we also take into account the discounting effect. The first finding is that it appears more economically favorable to extend the interim storage than to dispose of the HLW immediately. Countries which chose “immediate” disposal are willing to accept higher costs to quickly solve the problem. Another interesting result is that there is an optimal solution with respect to the length of DGR operational period and the waste flow for disposal. Based on data provided by the Organisation for Economic Cooperation and Development (OECD/Nuclear Energy Agency (NEA, we find an optimal operating period of about 15 years with a flow of 2000 tHM/year.

  18. Coal upgrading based on the high temperature reactor - engineering and economic aspects

    International Nuclear Information System (INIS)

    Barnert, H.; Neis, H.

    1987-01-01

    The development of the high temperature reactor in the FRG was opened with the aim of economically producing electricity which might be achieved with the next project works. Moreover, the HTR supplies process heat of very high temperature which may be used with metallic heat exchangers in the range up to 1000 0 C. From these reasons and regarding the world power prospects and the special power situation in our own country, the FRG began to develop methods of upgrading fossil primary energy sources using high-temperature heat from the HTR about 15 years ago. Meanwhile great progress has been achieved in research, development and test works; the modules are developed to a great extent. Economical service is expected for future utilization of selected processes. Problems to be still accomplished are first of all related to system testing as well as further exhaustion of the HTR's temperature potential. The proposed extension of the AVR to some process heat facility offers the possibility of testing the system in a low-cost and accelerated manner. (author)

  19. Physical abrasion method using submerged spike balls to remove algal biofilm from photobioreactors.

    Science.gov (United States)

    Nawar, Azra; Khoja, Asif Hussain; Akbar, Naveed; Ansari, Abeera Ayaz; Qayyum, Muneeb; Ali, Ehsan

    2017-12-02

    A major factor in practical application of photobioreactors (PBR) is the adhesion of algal cells onto their inner walls. Optimized algal growth requires an adequate sunlight for the photosynthesis and cell growth. Limitation in light exposure adversely affects the algal biomass yield. The removal of the biofilm from PBR is a challenging and expansive task. This study was designed to develop an inexpensive technique to prevent adhesion of algal biofilm on tubular PBR to ensure high efficiency of light utilization. Rubber balls with surface projections were introduced into the reactor, to remove the adherent biofilm by physical abrasion technique. The floatation of spike balls created a turbulent flow, thereby inhibiting further biofilm formation. The parameters such as, specific growth rate and doubling time of the algae before introducing the balls were 0.451 day -1 and 1.5 days respectively. Visible biofilm impeding light transmission was formed by 15-20 days. The removal of the biofilm commenced immediately after the introduction of the spike balls with visibly reduced deposits in 3 days. This was also validated by enhance cell count (6.95 × 106 cells mL -1 ) in the medium. The employment of spike balls in PBR is an environmental friendly and economical method for the removal of biofilm.

  20. Human trafficking for organ removal in India: a victim-centered, evidence-based report.

    Science.gov (United States)

    Budiani-Saberi, Debra A; Raja, Kallakurichi Rajendiran; Findley, Katie C; Kerketta, Ponsian; Anand, Vijay

    2014-02-27

    Enhancements in the national transplant law to prohibit commercial transplants in India have curbed the trade. Yet, the human rights abuse of human trafficking for organ removal (HTOR) continues in various transplant centers throughout India. Beginning in September 2010 until May 2012, in-depth interviews were conducted with 103 victims of HTOR in India in which victims described their experiences of a commercial kidney removal in compelling detail. Victims were located in Tamil Nadu, and reference is made to the broader study that included 50 additional victims in small towns and villages in West Bengal and Karnataka. Fourteen cases (14%) in Tamil Nadu and an additional 20 cases (40%) from West Bengal and Karnataka occurred between 2009 to May 2012. The cases in Tamil Nadu ranged in age from 19 to 55 years, with an average age of 33 years in Erode and 36 years in Chennai. Fifty-seven percent of the victims in Erode are female, and 87% of the victims in Chennai are female. Twelve percent of the individuals were widowed or abandoned, 79% were married, and 91% were parents with an average of two kids. Of those interviewed, 28% had no formal education, 19% had some primary schooling, 22% had some secondary schooling, and no individuals reported schooling above high school. All victims interviewed lived in abject poverty with monthly income levels well below the national average. The majority of victims reported long lasting health, economic, social, and psychological consequences. No matter the reason expressed for an organ sale, all victims reported that they would not have agreed to the organ removal if their economic circumstances were not so dire. One hundred percent of the victims interviewed expressed that they need assistance to cope with these consequences. Human trafficking for an organ removal continues in private transplant centers throughout India, service to foreign patients is ongoing, and victims' consequences are long lasting. A rights-based response

  1. Recovery of reactor electrical assemblies using differential de-encapsulation to remove dielectric insulation systems

    International Nuclear Information System (INIS)

    Hubrig, J.G.; Hammerstone, E.B.

    1986-01-01

    State-of-the-art de-encapsulation technologies associated with the conventional dielectric insulation systems employed in the construction of electrical coils and power distribution systems do not allow for accurate fatigue/failure analysis or reliable recovery of costly assembly components. Differential de-encapsulation allows for the selective removal of contemporary thermoset resin based insulation systems to allow non-destructive penetration of insulation wall thicknesses to both examine critical areas and recover high performance metallic and non-metallic inserts for remanufacture; significantly reducing replacement costs and reactor downtime. The authors' analysis describes how the availability of engineering data from the selective and non-destructive removal of insulation materials will aid in the evaluation of original manufacture, materials and procedures; enabling redesign to enhance subsequent on line performance. They also discuss why the ability to recover coil and core assemblies for remanufacture will have a major economic impact on reactor management costs

  2. Technical and economical aspects of SO2 and NOx removal from flue gas by electron beam irradiation

    International Nuclear Information System (INIS)

    Turhan, S.; Karadeniz, S.; Tugluoglu, N.; Eken, M.; Oktar, O.; Ercan, I.

    2001-01-01

    The emission of sulfur dioxide (SO 2 , also SO 3 ) and nitrogen oxides (NO, NO 2 , called NO x ) from fossil fuel burning power and industrial plants is one of the major sources of environmental pollution. These pollutants are named as acid gases causing acid rain and also indirect greenhouse gases contributing greenhouse effect. Acid rain damages forest, agriculture fields and flora, and cause public health concerns in regions having a number of industrial plants. Today, many countries have started to impose industrial emission limits and this movement has generated renewed interest in finding viable and cost effective solutions to SO 2 and NO x pollution control. The conventional technologies, wet scrubbing de-SO 2 and de-NO x , now reached their full potential therefore these methods are not expected to provide further improvements in terms of efficiency or reduction in construction costs. However, new technologies are being investigated for industrial scale commercial viability. One of them is electron beam process, which is dry scrubbing process and simultaneously removes SO 2 and NO x , and useful by-product for agriculture fertilizer. In this study, the economical and technical aspects of electron beam flue gas treatment process are discussed. Because an electron accelerator facility with electron beam energy of 500 KeV and electron beam current of 20 mA will be installed at ANRTC in TURKEY

  3. Benefits of integrating chemical and mechanical cleaning processes for steam generator sludge removal

    International Nuclear Information System (INIS)

    Varrin, R.D.; Ferriter, A.M.; Oliver, T.W.; Le Surf, J.E.

    1992-01-01

    This paper discusses the benefits of performing in-bundle tubesheet lancing in conjunction with chemical cleaning of PWR and PHWR steam generators in which a hard sludge pile is known to exist. The primary benefits of in-bundle lancing are to: (1) increase the exposed area of the sludge pile by cutting furrows in the surface thereby enhancing dissolution of sludge, (2) reduce the volume of solvents required since material removed by lancing does not have to be dissolved chemically, (3) improve rinsing and removal of residual solvent between iron and copper dissolution steps, and (4) allow for verification of process effectiveness by providing high quality in-bundle visual inspection. The reduction in solvent volumes can lead to a significant reduction in solvent costs and waste processing. A case study which includes an economic evaluation for a combined chemical and mechanical cleaning shows a potential cost saving of up to US$ 300,000 over use of chemical cleaning alone. 14 refs., 2 tabs., 2 figs

  4. Growth promoting antibiotics in food animal production: an economic analysis.

    Science.gov (United States)

    Graham, Jay P; Boland, John J; Silbergeld, Ellen

    2007-01-01

    Considerable controversy persists regarding the use of human antibiotics to promote growth in animals raised for food. The authors examined the economic effect of removing antibiotics used for growth promotion in commercial broiler chickens. The authors utilized data published by the Perdue company, the fourth largest poultry producer in the United States, in which a non-randomized controlled trial of growth-promoting antibiotic (GPA) use was conducted with seven million broiler chickens to evaluate the impact of removing GPAs on production. Positive production changes were associated with GPA use, but were insufficient to offset the cost of the antibiotics. The net effect of using GPAs was a lost value of 0.0093 dollars per chicken (about 0.45% of total cost). Based upon these data, the authors found no basis for the claim that the use of GPAs lowers the cost of production. Note that this study does not include veterinary cost changes or changes in performance variability associated with the removal of GPAs. This economic analysis is the first study to the authors' knowledge utilizing large-scale empirical data collected by U.S. industry, in which it is demonstrated that the use of GPAs in poultry production is associated with economic losses to the producers. These data are of considerable importance in the ongoing national debate concerning the continued use of antibiotics for growth promotion of food animals. Based on the industry study and the resulting economic impact, the use of GPAs in U.S. poultry production should be reconsidered.

  5. Structural vibration passive control and economic analysis of a high-rise building in Beijing

    Science.gov (United States)

    Chen, Yongqi; Cao, Tiezhu; Ma, Liangzhe; Luo, Chaoying

    2009-12-01

    Performance analysis of the Pangu Plaza under earthquake and wind loads is described in this paper. The plaza is a 39-story steel high-rise building, 191 m high, located in Beijing close to the 2008 Olympic main stadium. It has both fluid viscous dampers (FVDs) and buckling restrained braces or unbonded brace (BRB or UBB) installed. A repeated iteration procedure in its design and analysis was adopted for optimization. Results from the seismic response analysis in the horizontal and vertical directions show that the FVDs are highly effective in reducing the response of both the main structure and the secondary system. A comparative analysis of structural seismic performance and economic impact was conducted using traditional methods, i.e., increased size of steel columns and beams and/or use of an increased number of seismic braces versus using FVD. Both the structural response and economic analysis show that using FVD to absorb seismic energy not only satisfies the Chinese seismic design code for a “rare” earthquake, but is also the most economical way to improve seismic performance both for one-time direct investment and long term maintenance.

  6. Laboratory Experiments as a Tool in the Empirical Economic Analysis of High-Expectation Entrepreneurship

    Science.gov (United States)

    Curley, Martin; Formica, Piero

    2008-01-01

    High-expectation start-ups are firms launched by entrepreneurs with high ambitions for growth. The encounter between new technology and entrepreneurship that characterizes such new ventures has a significant impact on the nature and speed of economic development, driving the growth of high-technology industries and helping to make the economic…

  7. Chromium removal from tannery wastewater by using of flying ash

    International Nuclear Information System (INIS)

    Gil P, E.; Saldarriaga M, C.

    1998-01-01

    A simple and economic method to chromium removal from tannery wastewater by means of flying ash is presented. The chromium removal operation is a discontinuous process that involve the mass of flying ash, time of contact and temperature or ph as variables, their which are optimized through Box-Wilson type experimental design. The results were successful: From an initial fluid whit chromium concentration of 1850m ppm, final concentrations of 0.008 ppm and 0.5 ppm of Cr+3 and Cr+6 respectively were achieved. These post-treatment concentrations are into the approved range definite by Government's Laws to this waste type

  8. Coal-fueled high-speed diesel engine development: Task 2, Market assessment and economic analysis

    Energy Technology Data Exchange (ETDEWEB)

    Kakwani, R. M.; Wilson, Jr., R. P.; Winsor, R. E.

    1991-12-01

    Based on the preliminary coal engine design developed, this task was conducted to identify the best opportunity(s) to enter the market with the future coal-fueled, high-speed diesel engine. The results of this market and economic feasibility assessment will be used to determine what specific heavy duty engine application(s) are most attractive for coal fuel, and also define basic economic targets for the engine to be competitive.

  9. Enhanced nitrogen removal from piggery wastewater with high NH4+ and low COD/TN ratio in a novel upflow microaerobic biofilm reactor.

    Science.gov (United States)

    Meng, Jia; Li, Jiuling; Li, Jianzheng; Antwi, Philip; Deng, Kaiwen; Nan, Jun; Xu, Pianpian

    2018-02-01

    To enhance nutrient removal more cost-efficiently in microaerobic process treating piggery wastewater characterized by high ammonium (NH 4 + -N) and low chemical oxygen demand (COD) to total nitrogen (TN) ratio, a novel upflow microaerobic biofilm reactor (UMBR) was constructed and the efficiency in nutrient removal was evaluated with various influent COD/TN ratios and reflux ratios. The results showed that the biofilm on the carriers had increased the biomass in the UMBR and enhanced the enrichment of slow-growth-rate bacteria such as nitrifiers, denitrifiers and anammox bacteria. The packed bed allowed the microaerobic biofilm process perform well at a low reflux ratio of 35 with a NH 4 + -N and TN removal as high as 93.1% and 89.9%, respectively. Compared with the previously developed upflow microaerobic sludge reactor, the UMBR had not changed the dominant anammox approach to nitrogen removal, but was more cost-efficiently in treating organic wastewater with high NH 4 + -N and low COD/TN ratio. Copyright © 2017 Elsevier Ltd. All rights reserved.

  10. Estimating the economic impact of subclinical ketosis in dairy cattle using a dynamic stochastic simulation model.

    Science.gov (United States)

    Mostert, P F; Bokkers, E A M; van Middelaar, C E; Hogeveen, H; de Boer, I J M

    2018-01-01

    The objective of this study was to estimate the economic impact of subclinical ketosis (SCK) in dairy cows. This metabolic disorder occurs in the period around calving and is associated with an increased risk of other diseases. Therefore, SCK affects farm productivity and profitability. Estimating the economic impact of SCK may make farmers more aware of this problem, and can improve their decision-making regarding interventions to reduce SCK. We developed a dynamic stochastic simulation model that enables estimating the economic impact of SCK and related diseases (i.e. mastitis, metritis, displaced abomasum, lameness and clinical ketosis) occurring during the first 30 days after calving. This model, which was applied to a typical Dutch dairy herd, groups cows according to their parity (1 to 5+), and simulates the dynamics of SCK and related diseases, and milk production per cow during one lactation. The economic impact of SCK and related diseases resulted from a reduced milk production, discarded milk, treatment costs, costs from a prolonged calving interval and removal (culling or dying) of cows. The total costs of SCK were €130 per case per year, with a range between €39 and €348 (5 to 95 percentiles). The total costs of SCK per case per year, moreover, increased from €83 per year in parity 1 to €175 in parity 3. Most cows with SCK, however, had SCK only (61%), and costs were €58 per case per year. Total costs of SCK per case per year resulted for 36% from a prolonged calving interval, 24% from reduced milk production, 19% from treatment, 14% from discarded milk and 6% from removal. Results of the sensitivity analysis showed that the disease incidence, removal risk, relations of SCK with other diseases and prices of milk resulted in a high variation of costs of SCK. The costs of SCK, therefore, might differ per farm because of farm-specific circumstances. Improving data collection on the incidence of SCK and related diseases, and on consequences of

  11. Device for removing impurities from liquid metals

    International Nuclear Information System (INIS)

    Naito, Kesahiro; Yokota, Norikatsu; Shimoyashiki, Shigehiro; Takahashi, Kazuo; Ishida, Tomio.

    1984-01-01

    Purpose: To attain highly reliable and efficient impurity removal by forming temperature distribution the impurity removing device thereby providing the function of corrosion product trap, nuclear fission product trap and cold trap under the conditions suitable to the impurity removing materials. Constitution: The impurity removing device comprises a container containing impurity removing fillers. The fillers comprise material for removing corrosion products, material for removing nuclear fission products and material for removing depositions from liquid sodium. The positions for the respective materials are determined such that the materials are placed under the temperature conditions easy to attain their function depending on the temperature distribution formed in the removing device, whereby appropriate temperature condition is set to each of the materials. (Yoshino, Y.)

  12. On the relationship between economic freedom and economic growth

    NARCIS (Netherlands)

    Haan, Jakob de; Sturm, Jan-Egbert

    1999-01-01

    Often it is maintained that economic freedom may further high levels of economic growth. This paper compares various indicators for economic freedom. It is concluded that although these measures differ somewhat in their coverage, they show similar rankings for the countries covered. Some elements in

  13. Controlling highly pathogenic avian influenza outbreaks : An epidemiological and economic model analysis

    NARCIS (Netherlands)

    Backer, J. A.; van Roermund, H. J W; Fischer, Egil; van Asseldonk, M. A P M; Bergevoet, R. H M

    2015-01-01

    Outbreaks of highly pathogenic avian influenza (HPAI) can cause large losses for the poultry sector and for animal disease controlling authorities, as well as risks for animal and human welfare. In the current simulation approach epidemiological and economic models are combined to compare different

  14. Preparation of surface modified zinc oxide nanoparticle with high capacity dye removal ability

    International Nuclear Information System (INIS)

    Mahmoodi, Niyaz Mohammad; Najafi, Farhood

    2012-01-01

    Highlights: ► Amine-functionalized zinc oxide nanoparticle (AFZON) was synthesized. ► Isotherm and kinetics data followed Langmuir isotherm and pseudo-second order kinetic model, respectively. ► Q 0 of ZON for AB25, DR23 and DR31 was 20, 12 and 15 mg/g, respectively. ► Q 0 of AFZON for AB25, DR23 and DR31 was 1250, 1000 and 1429 mg/g, respectively. ► AFZON was regenerated at pH 12. -- Abstract: In this paper, the surface modification of zinc oxide nanoparticle (ZON) by amine functionalization was studied to prepare high capacity adsorbent. Dye removal ability of amine-functionalized zinc oxide nanoparticle (AFZON) and zinc oxide nanoparticle (ZON) was also investigated. The physical characteristics of AFZON were studied using Fourier transform infrared (FTIR), scanning electron microscopy (SEM) and X-ray diffraction (XRD). Acid Blue 25 (AB25), Direct Red 23 (DR23) and Direct Red 31 (DR31) were used as model compounds. The effect of operational parameters such as dye concentration, adsorbent dosage, pH and salt on dye removal was evaluated. The isotherm and kinetic of dye adsorption were studied. The maximum dye adsorption capacity (Q 0 ) was 20 mg/g AB25, 12 mg/g DR23 and 15 mg/g DR31 for ZON and 1250 mg/g AB25, 1000 mg/g DR23 and 1429 mg/g DR31 for AFZON. It was found that dye adsorption followed Langmuir isotherm. Adsorption kinetic of dyes was found to conform to pseudo-second order kinetics. Dye desorption tests (adsorbent regeneration) showed that the maximum dye release of 90% AB25, 86% for DR23 and 90% for DR31 were achieved in aqueous solution at pH 12. Based on the data of the present investigation, it can be concluded that the AFZON being an adsorbent with high dye adsorption capacity might be a suitable alternative to remove dyes from colored aqueous solutions.

  15. Enhanced Nutrients Removal Using Reeds Straw as Carbon Source in a Laboratory Scale Constructed Wetland

    Directory of Open Access Journals (Sweden)

    Tong Wang

    2018-05-01

    Full Text Available The low carbon/nitrogen (C/N ratio and high nitrate content characteristics of agricultural runoff restricted the nitrogen removal in constructed wetlands (CWs. To resolve such problems, the economically- and easily-obtained Phragmites Australis (reeds litters were applied and packed in the surface layer of a surface flow CW as external carbon sources. The results demonstrated that the introduction of the reeds straw increased the C concentration as a result of their decomposition during the CW operation, which will help the denitrification in the ensuing operation of an entire 148 days. The total nitrogen (TN and Chemical Oxygen Demand (COD ( in the effluent reached the peak level of 63.2 mg/L and 83 mg/L at the fourth and the second day, respectively. Subsequently, the pollutants in the CW that were filled with straw decreased rapidly and achieved a stable removal after 13 days of operation. Moreover, the present study showed that the N removal efficiency increased with the increase of the hydraulic retention time (HRT. Under the HRT of four days, the CW presented 74.1 ± 6%, 87.4 ± 6% and 56.0 ± 6% removal for TN, NO3-, and TP, respectively.

  16. The production and use of citric acid for the removal of potassium from the iron ore concentrate of the Sishen Iron Ore Mine, South Africa

    Directory of Open Access Journals (Sweden)

    Peter J. Williams

    2010-04-01

    Full Text Available The depletion of the richer iron ore worldwide has made it necessary to process lower quality iron ore. Certain substances, such as potassium, contained within the lower quality iron ore, have a detrimental effect on the smelting process during steel manufacturing. Therefore, international steel-making companies charge penalties when purchasing iron ore concentrates containing high concentrations of potassium. To date, lower quality iron ore has been blended with high quality iron ore in an attempt to alleviate the potassium concentrations in the export iron ore; however, the ratio of low quality iron ore to high quality iron ore is increasing, thereby becoming an escalating problem within the economic functioning of the Sishen Iron Ore Mine. It has, therefore, become necessary to develop an economically viable and environmentally friendly process to reduce the high potassium concentrations contained in the iron ore concentrate of the Sishen Iron Ore Mine. In this study, we compared solid substrate and submerged fermentation using Aspergillus niger for the production of citric acid, which is used for the chemical leaching of potassium from the iron ore concentrate. It was found that submerged fermentation proved to be more economical and efficient, producing a maximum citric acid concentration of 102.3 g/L in 96 h of fermentation. ‘Heap leaching’ simulation experiments were found to be uneconomical, due to the required addition of fungal growth medium every 5 days as a result of growth factor depletion within this time; however, this process removed 17.65% of the potassium from the iron ore concentrate. By contrast, chemical leaching of potassium from the iron ore concentrate proved to be most efficient when using a 1 mol citric acid leaching solution at 60 ºC, removing 23.53% of the potassium contained within the iron ore concentrate. Therefore, the most economical and efficient process for the removal of potassium from the iron

  17. Optimized biofilm-based systems for removal of pharmaceuticals from hospital waste water

    DEFF Research Database (Denmark)

    Andersen, Henrik R; Chhetri, Ravi; Hansen, Kamilla

    Discharge of hospital wastewater is of increasing concern, as hospitals are identified as chemical pollution source due to pharmaceutical content. This project seeks to develop the most efficient and economically feasible technology to remove pharmaceuticals from wastewater, regardless of the poi...

  18. Comparisons Study of Phosphate Removal in Unaerated and Aerated High Calcium Steel Slag Filter System of Different pH Feed

    Directory of Open Access Journals (Sweden)

    Ahmad Siti Zu Nurain

    2017-01-01

    Full Text Available Excess phosphorus in water body will lead to eutrophication. This study investigated the phosphate removal efficiencies of unaerated and aerated filter systems using high composition of Calcium (Ca steel slag as the filter media at different pH values of the wastewater influents. Lab-scale filters were developed using 25 mg/L synthetic wastewater and weekly sampling was done to monitor the phosphate removal efficiencies together with the concentration of metals (Calcium (Ca and Magnesium (Mg. The results show that both unaerated and aerated systems have excellent phosphate removal efficiency at all acidic, neutral and alkaline pH feed, though unaerated systems removed slightly better compared to aerated systems; 76-98% and 69-97% respectively. The dominant phosphate removal mechanism for aerated systems was adsorption, meanwhilefor unaerated systems; both adsorption and precipitation for acidic and neutral pH, whileprecipitation was more dominant at basic pH. The performance of unaerated systems are slightly better compared to aerated systems, however, aerated systems are recommended to be applied when simultaneous removal of nutrients (phosphorus and nitrogen are concerned.

  19. Treatment of highly polluted groundwater by novel iron removal process.

    Science.gov (United States)

    Sim, S J; Kang, C D; Lee, J W; Kim, W S

    2001-01-01

    The removal of ferrous iron (Fe(II)) in groundwater has been generally achieved by simple aeration, or the addition of an oxidizing agent. Aeration has been shown to be very efficient in insolubilization ferrous iron at a pH level greater than 6.5. In this study, pH was maintained over 6.5 using limestone granules under constant aeration to oxidize ferrous iron in groundwater in a limestone packed column. A sedimentation unit coupled with a membrane filtration was also developed to precipitate and filtrate the oxidized ferric compound simultaneously. Several bench-scale studies, including the effects of the limestone granule sizes, amounts and hydraulic retention time on iron removal in the limestone packed column were investigated. It was found that 550 g/L of the 7-8 mesh size limestone granules, and 20 min of hydraulic retention time in the limestone packed column, were necessary for the sufficient oxidation of 40 mg/L of iron(II) in groundwater. Long-term operation was successfully achieved in contaminated waters by removing the iron deposits on the surface of the limestone granule by continuous aeration from the bottom of the column. Periodic reverse flow helped to remove caking and fouling of membrane surface caused by the continuous filtration. Recycling of the treated water from the membrane right after reverse flow operation made possible an admissible limit of iron concentration of the treated water for drinking. The pilot-scale process was constructed and has been tested in the rural area of Korea.

  20. "New Economics"?

    DEFF Research Database (Denmark)

    Nielsen, Jørgen Ulff-Møller

    1999-01-01

    The United States, the United Kingdom and Denmark have all enjoyed a long period of high stable growth and low inflation in the 1990s. Attempts to determine the implications of this have led to the so-called "New Economics", whose advocates claim that the relationship between economic growth and ...... and inflation has fundamentally changes. The following article tests this thesis against current data for the USA.......The United States, the United Kingdom and Denmark have all enjoyed a long period of high stable growth and low inflation in the 1990s. Attempts to determine the implications of this have led to the so-called "New Economics", whose advocates claim that the relationship between economic growth...

  1. Efficient pollutants removal by amino-modified nanocellulose impregnated with iron oxide

    Directory of Open Access Journals (Sweden)

    Taleb Khaled A.

    2016-01-01

    Full Text Available A novel adsorbents NC-PEG, obtained by the modification of nanocellulose (NC with PEG-6-arm amino polyethylene glycol (PEG-NH2 via maleic anhydride (MA linker, was used for the removal of Cd2+ and Ni2+ from water. Subsequent precipitation of goethite (FO on NC-PEG produced NC-PEG/FO adsorbent which was used for As(V and As(III removal. In a batch test, the influence of pH, contact time, initial ion concentration and temperature on adsorption efficiency were studied. The maximum adsorption capacities found for Cd2+ and Ni2+, obtained by the use of Langmuir model, were 37.9 and 32.4 mg g−1 at 25 °C, respectively. Also, high As(V and As(III removal capacity of 26.0 and 23.6 mg g-1 were obtained. Thermodynamic parameters indicate endothermic, feasible and spontaneous nature of adsorption process. Kinetic study, i.e. fitting by Weber-Morris model predicted intra-particle diffusion as a rate-controlling step. Multi-cycle reusability of both NC-PEG and NC-PEG/FO, significantly affects the affordability of techno-economic indicators for consideration of their possible application. [Ministry of Education, Science and Technological developments of the Republic of Serbia, Project No. 172013, and University of Defence, Republic of Serbia, project VA-TT/4/16-18

  2. Removal of heavy metals from aluminum anodic oxidation wastewaters by membrane filtration.

    Science.gov (United States)

    Ates, Nuray; Uzal, Nigmet

    2018-05-27

    Aluminum manufacturing has been reported as one of the largest industries and wastewater produced from the aluminum industry may cause significant environmental problems due to variable pH, high heavy metal concentration, conductivity, and organic load. The management of this wastewater with a high pollution load is of great importance for practitioners in the aluminum sector. There are hardly any studies available on membrane treatment of wastewater originated from anodic oxidation. The aim of this study is to evaluate the best treatment and reuse alternative for aluminum industry wastewater using membrane filtration. Additionally, the performance of chemical precipitation, which is the existing treatment used in the aluminum facility, was also compared with membrane filtration. Wastewater originated from anodic oxidation coating process of an aluminum profile manufacturing facility in Kayseri (Turkey) was used in the experiments. The characterization of raw wastewater was in very low pH (e.g., 3) with high aluminum concentration and conductivity values. Membrane experiments were carried out with ultrafiltration (PTUF), nanofiltration (NF270), and reverse osmosis (SW30) membranes with MWCO 5000, 200-400, and 100 Da, respectively. For the chemical precipitation experiments, FeCl 3 and FeSO 4 chemicals presented lower removal performances for aluminum and chromium, which were below 35% at ambient wastewater pH ~ 3. The membrane filtration experimental results show that, both NF and RO membranes tested could effectively remove aluminum, total chromium and nickel (>90%) from the aluminum production wastewater. The RO (SW30) membrane showed a slightly higher performance at 20 bar operating pressure in terms of conductivity removal values (90%) than the NF 270 membrane (87%). Although similar removal performances were observed for heavy metals and conductivity by NF270 and SW30, significantly higher fluxes were obtained in NF270 membrane filtration at any pressure

  3. Conceptual design and economic evaluation about the coupling of high power PWRs and desalination system

    Energy Technology Data Exchange (ETDEWEB)

    Kim, Sang Ho; Chang, Soon Heung [Korea Advanced Institute of Science and Technology, Daejeon (Korea, Republic of); Kim, Hyeon Min; Heo, Gyun Young [Kyung Hee Univ., Yongin (Korea, Republic of)

    2012-03-15

    Both electricity and fresh water become basic human needs in modern days. This paper describes the coupling methods of high power pressurized water reactors and desalination system, and evaluates the economics of coupling systems. OPR1000 designed by Korea was chosen for the reference reactor. Because MED (Mulct-Effect Distillation) with TVC (Thermal Vapor Compressor) have been evaluated as an effective desalination system for high power reactors, it was used for the reference desalination method in simulation. In order to simulate the secondary circuit of PWRs with heat exchangers for MED-TVC, PEPSE program which is normally used for performance evaluation of power system efficiencies was used. The coupling of OPR1000 and desalination systems were set under the restriction it had to make as small changes as possible. From the results PEPSE simulation, the economics of the coupling systems were calculates using equations form DEEP4.0 (Desalination Economic Evaluation Program) which was developed by IAEA because Deep simulates just two simple couplings which are back pressure and condensation/extraction. In the secondary circuit simulation seven coupling cases were set and outlet powers to heat exchanger for desalination were varied to be dependent on the thermohydraulic conditions on each part. The results of changed electrical power generation were calculated with the thermal outputs for desalination. It is concluded that two coupling method using the steam from high-pressure turbine have high performance and are economical among the simulated cases. The first one is to add a heat exchanger on the branch from high-pressure turbine into moisture separator and the other is on the branch into feedwater heating parts. It proves desalination plants can be added to current high power PWRs.

  4. Process for the removal of acid forming gases from exhaust gases

    Science.gov (United States)

    Chang, S.G.; Liu, D.K.

    1992-11-17

    Exhaust gases are treated to remove NO or NO[sub x] and SO[sub 2] by contacting the gases with an aqueous emulsion or suspension of yellow phosphorus preferably in a wet scrubber. The pressure is not critical, and ambient pressures are used. Hot water temperatures are best, but economics suggest about 50 C is attractive. The amount of yellow phosphorus used will vary with the composition of the exhaust gas, less than 3% for small concentrations of NO, and 10% or higher for concentrations above say 1000 ppm. Similarly, the pH will vary with the composition being treated, and it is adjusted with a suitable alkali. For mixtures of NO[sub x] and SO[sub 2], alkalis that are used for flue gas desulfurization are preferred. With this process, 100% of the by-products created are usable, and close to 100% of the NO or NO[sub x] and SO[sub 2] can be removed in an economic fashion. 9 figs.

  5. Kinetic studies for the use of fermented agricultural byproduct by fungi in removal of some toxic metals from their waste solutions

    International Nuclear Information System (INIS)

    Moloukhia, H.; Ouda, S.

    2010-01-01

    A new sorbent material has been developed that sesame stalks as agricultural byproduct which are available at very little or no cost was fermented by fungi to produce high quality sorbent material. Microbial biomass offers an economical option for removing heavy metals by the phenomenon of bio sorption. Fermented sesame stalks by the fungal biomass Aspergillus terreus (Thom), was tested for its ability to remove chromium and cadmium ions from waste solutions. Some significant parameters i.e., contact time, solution ph, mass of sorbent material and the effect of metal concentrations were investigated. Desorption studies were also performed. The kinetic of sorption was evaluated by applying the Lagergren equation. Results showed that the ph of the solution strongly affected the degree of bio sorption of metal ions by biomass. The metal ion sorption obeyed Freundlich isotherm. It was found that the exponent 1/n is in the range of 1> 1/n > 0, which signify that strong adsorptive forces are operative on the surface of the fermented sesame stalks by fungal biomass. The kinetics of sorption indicated that the removal of both chromium and cadmium ions from solution follows a first-order reaction with fast rate. It could be concluded that fermented sesame stalks by the fungal biomass Aspergillus terreus (Thom), can be considered as an economical alternative sorbent material for the removal of heavy metals from wastewater by the phenomenon of bio sorption

  6. Economic Evaluations for the Carbon Dioxide-involved Production of High-value Chemicals

    Energy Technology Data Exchange (ETDEWEB)

    Lee, Ji Hyun; Lee, Dong Woog; Jang, Se Gyu; Kwak, No-Sang; Lee, In Young; Jang, Kyung Ryoung; Shim, Jae-Goo [KEPCO Research Institute, Daejon (Korea, Republic of); Choi, Jong Shin [Korea East-West Power Co. LTD, Seoul (Korea, Republic of)

    2014-06-15

    Economic evaluation of the manufacturing technology of high-value chemicals through the carbonation reaction of carbon dioxide contained in the flue gas was performed, and analysis of the IRR (Internal Rate of Return) and whole profit along the production plan of the final product was conducted. Through a carbonation reaction with sodium hydroxide that is generated from electrolysis and by using carbon dioxide in the combustion gas that is generated in the power plant, it is possible to get a high value products such as sodium bicarbonate compound and also to reduce the carbon dioxide emission simultaneously. The IRR (Internal Rate of Return) and NPV (Net Present Value) methods were used for the economic evaluation of the process which could handle carbon dioxide of 100 tons per day in the period of the 20 years of plant operation. The results of economic evaluation showed that the IRR of baseline case of technology was 67.2% and the profit that obtained during the whole operation period (20 years) was 346,922 million won based on NPV value. When considering ETS due to the emissions trading enforcement that will be activated in 2015, the NPV was improved to a 6,000 million won. Based on this results, it could be concluded that this CO2 carbonation technology is an cost-effective technology option for the reduction of greenhouse gas.

  7. Economic Evaluations for the Carbon Dioxide-involved Production of High-value Chemicals

    International Nuclear Information System (INIS)

    Lee, Ji Hyun; Lee, Dong Woog; Jang, Se Gyu; Kwak, No-Sang; Lee, In Young; Jang, Kyung Ryoung; Shim, Jae-Goo; Choi, Jong Shin

    2014-01-01

    Economic evaluation of the manufacturing technology of high-value chemicals through the carbonation reaction of carbon dioxide contained in the flue gas was performed, and analysis of the IRR (Internal Rate of Return) and whole profit along the production plan of the final product was conducted. Through a carbonation reaction with sodium hydroxide that is generated from electrolysis and by using carbon dioxide in the combustion gas that is generated in the power plant, it is possible to get a high value products such as sodium bicarbonate compound and also to reduce the carbon dioxide emission simultaneously. The IRR (Internal Rate of Return) and NPV (Net Present Value) methods were used for the economic evaluation of the process which could handle carbon dioxide of 100 tons per day in the period of the 20 years of plant operation. The results of economic evaluation showed that the IRR of baseline case of technology was 67.2% and the profit that obtained during the whole operation period (20 years) was 346,922 million won based on NPV value. When considering ETS due to the emissions trading enforcement that will be activated in 2015, the NPV was improved to a 6,000 million won. Based on this results, it could be concluded that this CO2 carbonation technology is an cost-effective technology option for the reduction of greenhouse gas

  8. Three-dimensionally porous graphene: A high-performance adsorbent for removal of albumin-bonded bilirubin.

    Science.gov (United States)

    Ma, Chun Fang; Gao, Qiang; Xia, Kai Sheng; Huang, Zhi Yuan; Han, Bo; Zhou, Cheng Gang

    2017-01-01

    The development of bilirubin adsorbents with high adsorption efficiencies towards albumin-bonded bilirubin is still a considerable challenge. In this work, a three-dimensionally porous graphene (3D-pGR) has been fabricated through a simple carbon dioxide (CO 2 ) activation of thermally exfoliated graphite oxide (EGO). Intriguingly, the resultant 3D-pGR material showed hierarchically micro-meso-macroporous structure, high specific surface area of up to 843m 2 g -1 , and large pore volume as high as 2.71cm 3 g -1 . Besides, the large planar π-configuration structure of 3D-pGR made it possible to compete effectively with albumin for bilirubin binding. Taking advantages of these fantastic characteristics, the 3D-pGR was demonstrated to be extraordinarily efficient for bilirubin removal from a bovine serum albumin (BSA)-rich solution. Under optimized conditions, the maximum adsorption capacity of 3D-pGR for BSA-bonded bilirubin was up to 126.1mgg -1 , which is not only significantly higher than the adsorption capacities of currently available adsorbents towards albumin-bonded bilirubin, but also superior to those of many reported adsorbents towards free bilirubin. In addition, the hemolysis assay of 3D-pGR indicated that this material had negligible hemolysis effect. Findings from this study may open up important new possibilities for removal of protein-bonded toxins. Copyright © 2016 Elsevier B.V. All rights reserved.

  9. Evaluation of secondary electron filter for removing contaminant electrons from high-energy 6 MV x-ray beam

    International Nuclear Information System (INIS)

    Kumagai, Kozo

    1988-01-01

    When using high energy X-rays, the dose increases at the skin surface and build-up region of beam contamination of secondary electrons coming out from the inner surface of the lineac head. At our radiotherapy department, many cases of external otitis from severe skin reactions, particularly resulting from whole brain irradiation of primary and metastatic brain tumors with a 6 MV X-ray lineac, have been encountered. An investigation was made of the physical aspects of a 6 MV X-ray beam using three electron filters, lead lucite, lead glass and lucite to remove secondary electrons. Transparent materials for filters should be preferable for locating the light field. The following results were obtained: 1) For removing secondary electrons, a lead lucite filter was found best. 2) The lead lucite filter proved most effective for removing secondary electrons from the area of treatment. It reduced the dose of irradiation to the skin surface and build-up region, and furthermore improved the depth dose relative to that without filters. 3) From a clinical standpoint, skin reactions such as external otitis remarkably decreased using a lead lucite filter. 4) It thus appears necessary to use a high energy X-ray with newly designed filters to reduce beam contamination of secondary electrons. (author)

  10. Stock Market and Sustainable Economic Growth in Nigeria

    Directory of Open Access Journals (Sweden)

    Erasmus L Owusu

    2016-11-01

    Full Text Available This paper examines the relationship between stock market evolution and sustainable economic growth in Nigeria. The study employs Auto-Regressive Distributed Lag (ARDL-bounds testing approach and a combined stock market indicators index to examine the relationship. The paper finds that, in the long run, stock markets have no positive and at best mixed effect on economic growth in Nigeria. This finding supports the numerous past studies, which have reported negative/mixed or inconclusive results on the effects of stock markets on economic growth. The paper, therefore, concludes that, there is the need for increasing financial deepening and the removal of bottlenecks in the financial sectors of the economy by providing further public and institutional education on the value of stock markets for economic development.

  11. Investigating the removal of body piercings.

    Science.gov (United States)

    Armstrong, Myrna L; Roberts, Alden E; Koch, Jerome R; Saunders, Jana C; Owen, Donna C

    2007-05-01

    Although body piercing procurement continues to increase, 13% to 18% of them are removed. Reasons for piercing removal in college students were examined with three groups: (a) those who kept all their piercings, (b) those who removed some, or (c) those who removed all of their body piercings. Of the sample, 41% were still pierced; 50% in their lifetime. Their major purpose for the body piercing was "helped them feel unique." Females obtained more (in high school) and then removed more, usually as upperclassmen. Males and females reported themselves as risk takers at procedure time and currently; however, only 10% cited deviancy as a reason for the body piercing(s). Only removal elements of "I just got tired of it" and "I just decided to remove it" were present, especially with the Some Removed Group. Further examination of body piercing building personal distinctiveness and self-identity to promote their need of uniqueness is suggested.

  12. Removal of chromium(III) from tannery wastewater using activated carbon from sugar industrial waste.

    Science.gov (United States)

    Fahim, N F; Barsoum, B N; Eid, A E; Khalil, M S

    2006-08-21

    Chromium is commonly found in huge quantities in tannery wastewaters. For this reason, the removal and recovery of the chromium content of tannery wastewaters is crucial for environmental protection and economic reasons. Removal and recovery of chromium were carried out by using low-cost potential adsorbents. For this purpose three types of activated carbon; C1, the waste generated from sugar industry as waste products and the others (C2, C3) are commercial granular activated carbon, were used. The adsorption process and extent of adsorption are dependent on the physical and chemical characteristics of the adsorbent, adsorbate and experimental condition. The effect of pH, particle size and different adsorbent on the adsorption isotherm of Cr(III) was studied in batch system. The sorption data fitted well with Langmuir adsorption model. The efficiencies of activated carbon for the removal of Cr(III) were found to be 98.86, 98.6 and 93 % for C1, C2 and C3, respectively. The order of selectivity is C1>C2>C3 for removal of Cr(III) from tannery wastewater. Carbon "C1" of the highest surface area (520.66 m(2)/g) and calcium content (333.3 mg/l) has the highest adsorptive capacity for removal of Cr(III). The results revealed that the trivalent chromium is significantly adsorbed on activated carbon collected from sugar industry as waste products and the method could be used economically as an efficient technique for removal of Cr(III) and purification of tannery wastewaters.

  13. Evaluating the Economic Performance of High-Technology Industry and Energy Efficiency: A Case Study of Science Parks in Taiwan

    Directory of Open Access Journals (Sweden)

    Min-Ren Yan

    2013-02-01

    Full Text Available High-technology industries provide opportunities for economic growth, but also raise concerns because of their energy-demanding nature. This paper provides an integrated evaluation of both economic benefits and energy efficiency of high-technology industries based on the real data from one of the globally recognized high-technology industrial clusters, the national science parks in Taiwan. A nation-wide industrial Input-Output Analysis is conducted to demonstrate the positive effects of science parks on national economic developments and industrial upgrades. The concept of energy intensity and an energy-efficient economy index are applied to an integrated assessment of the relationship between economic growth and energy consumption. The proposed case study suggests that economic and energy efficiency objectives can be simultaneously achieved by the development of high-technology industries, while three energy policy implications are considered. First, a nation-wide macro viewpoint is needed and high-technology industries should be considered as parts of the national/regional economies by governmental agencies. Second, a proper industrial clustering mechanism and the shared environmental facilities supported by the government, such as planned land and road usage, electricity and water supply, telecommunications system, sewerage system and wastewater treatments, can improve energy efficiency of high-technology industries. Third, the governmental policies on the taxing and management system in science parks would also direct energy-efficient economy of high-technology industries.

  14. The impacts of removing energy subsidies on economy-wide rebound effects in China: An input-output analysis

    International Nuclear Information System (INIS)

    Li, Ke; Jiang, Zhujun

    2016-01-01

    Facing with the increasing contradiction of economic growth, energy scarcity and environmental deterioration, energy conservation and emissions abatement have been ambitious targets for the Chinese government. Improving energy efficiency through technological advancement is a primary measure to achieve these targets. However, the existence of energy rebound effects may completely or partially offset energy savings associated with technological advancement. This paper adopted a modified input-output model to estimate the economy-wide energy rebound effects across China's economic sectors with the consideration of energy subsidies. The empirical results show that the aggregate rebound effect of China is about 1.9% in 2007–2010, thus technological advancement significantly restrains energy consumption increasing. Removing energy subsidies will cause the aggregate rebound effect declines to 1.53%. Specifically, removing subsidies for coal and nature gas can reduce the rebound effects signifcantly, while removing the subsidies for oil products has a small impact on rebound effect. The existence of rebound effects implies that technological advancement should be cooperated with energy price reform so as to achieve the energy saving target. In addition, the government should consider the diversity of economic sectors and energy types when design the reform schedule. - Highlights: • Rebound effects with the consideration of energy subsidies are estimated in China. • When considering the interactions among sectors, the aggregate rebound effect become small. • Removing subsidies will reduce energy consumption, thereby declining the rebound effects. • Removing subsidies for different energy types has varies effects on rebound effect.

  15. High SO{sub 2} removal duct injection: A low-cost FGD alternative

    Energy Technology Data Exchange (ETDEWEB)

    Nelson, S.G. [Sorbent Technologies Corp., Twinsburg, OH (United States)

    1995-12-01

    Sorbent Technologies Corporation, of the United States, is currently developing and demonstrating a new waste free, retrofitable, high-SO{sub 2} removal duct-injection process. Up to 85 percent SO{sub 2} removal is achieved by simply injecting a new dry lime-based sorbent into the flue-gas duct, collecting the sorbent downstream in a particulate collector, and then recycling the sorbent. By avoiding large, expensive components, the process can have low capital costs, making it especially appropriate for smaller, older, less-utilized plants. The key to the new technology is the use of sorbent supports. Supported sorbents are produced by coating hydrated lime onto inexpensive mineral supports, such as exfoliated vermiculite or perlite. Consequently, there are no liquid, sludge, or solid wastes with the new technology. Once saturated with SO{sub 2}, the spent sorbent can be easily pelletized into a valuable soil-conditioning agricultural by-product, for the sustainable development that the future requires. This paper describes Sorbent Technologies` pilot demonstration of supported sorbent injection at the Ohio Edison Company`s R.E. Burger station. The Burger effort is also the first demonstration of the Electric Power Research Institute`s new {open_quotes}COHPAC{close_quotes} baghouse technology in a sorbent-injection desulfurization application.

  16. Near-Zero Emissions Oxy-Combustion Flue Gas Purification Task 2: SOx/Nox/Hg Removal for High Sulfur Coal

    Energy Technology Data Exchange (ETDEWEB)

    Nick Degenstein; Minish Shah; Doughlas Louie

    2012-05-01

    The goal of this project is to develop a near-zero emissions flue gas purification technology for existing PC (pulverized coal) power plants that are retrofitted with oxy-combustion technology. The objective of Task 2 of this project was to evaluate an alternative method of SOx, NOx and Hg removal from flue gas produced by burning high sulfur coal in oxy-combustion power plants. The goal of the program was not only to investigate a new method of flue gas purification but also to produce useful acid byproduct streams as an alternative to using a traditional FGD and SCR for flue gas processing. During the project two main constraints were identified that limit the ability of the process to achieve project goals. 1) Due to boiler island corrosion issues >60% of the sulfur must be removed in the boiler island with the use of an FGD. 2) A suitable method could not be found to remove NOx from the concentrated sulfuric acid product, which limits sale-ability of the acid, as well as the NOx removal efficiency of the process. Given the complexity and safety issues inherent in the cycle it is concluded that the acid product would not be directly saleable and, in this case, other flue gas purification schemes are better suited for SOx/NOx/Hg control when burning high sulfur coal, e.g. this project's Task 3 process or a traditional FGD and SCR.

  17. Aquatic environmental monitoring and removal efficiency of detergents

    Directory of Open Access Journals (Sweden)

    Hanan S. Abd El-Gawad

    2014-10-01

    The results showed wide variations observed between surface (0.07–0.38 mg LAS/l and bottom water (0.05–0.17 mg LAS/l due to increase in population density and human activities that recorded highest concentration along rural area (surface: 1.24–2.45 and bottom: 0.93–1.083 mg LAS/l. Low concentration of surfactants was found in drinking water (0.005–0.007 mg LAS/l compared to the concentration of the corresponding water samples along the River Nile. In conclusion, the study indicated that the treatment processes for drinking water production were insufficient for the complete removal of surfactants and adsorption process by using zeolite as low cost, most beneficial, economically feasible method as well as easy to operate for producing high quality of water.

  18. Economic Analysis of the Reference Design for a Nuclear-Driven High-Temperature-Electrolysis Hydrogen Production Plant

    International Nuclear Information System (INIS)

    E. A. Harvego; M. G. McKellar; M. S. Sohal; J. E. O'Brien; J. S. Herring

    2008-01-01

    A reference design for a commercial-scale high-temperature electrolysis (HTE) plant for hydrogen production was developed to provide a basis for comparing the HTE concept with other hydrogen production concepts. The reference plant design is driven by a high-temperature helium-cooled reactor coupled to a direct Brayton power cycle. The reference design reactor power is 600 MWt, with a primary system pressure of 7.0 MPa, and reactor inlet and outlet fluid temperatures of 540 C and 900 C, respectively. The electrolysis unit used to produce hydrogen consists of 4,009,177 cells with a per-cell active area of 225 cm2. A nominal cell area-specific resistance, ASR, value of 0.4 Ohm-cm2 with a current density of 0.25 A/cm2 was used, and isothermal boundary conditions were assumed. The optimized design for the reference hydrogen production plant operates at a system pressure of 5.0 MPa, and utilizes an air-sweep system to remove the excess oxygen that is evolved on the anode side of the electrolyzer. The inlet air for the air-sweep system is compressed to the system operating pressure of 5.0 MPa in a four-stage compressor with intercooling. The alternating current, AC, to direct current, DC, conversion is 96%. The overall system thermal-to-hydrogen production efficiency (based on the low heating value of the produced hydrogen) is 47.12% at a hydrogen production rate of 2.356 kg/s. An economic analysis of the plant was also performed using the H2A Analysis Methodology developed by the Department of Energy (DOE) Hydrogen Program. The results of the economic analysis demonstrated that the HTE hydrogen production plant driven by a high-temperature helium-cooled nuclear power plant can deliver hydrogen at a competitive cost using realistic financial and cost estimating assumptions. A required cost of $3.23 per kg of hydrogen produced was calculated assuming an internal rate of return of 10%. Approximately 73% of this cost ($2.36/kg) is the result of capital costs associated with

  19. Highly efficient removal of trace thallium from contaminated source waters with ferrate: Role of in situ formed ferric nanoparticle.

    Science.gov (United States)

    Liu, Yulei; Wang, Lu; Wang, Xianshi; Huang, Zhuangsong; Xu, Chengbiao; Yang, Tao; Zhao, Xiaodan; Qi, Jingyao; Ma, Jun

    2017-11-01

    Thallium (Tl) is highly toxic to mammals and relevant pollution cases are increasing world-widely. Convenient and efficient method for the removal of trace Tl from contaminated source water is imperative. Here, the removal of trace Tl by K 2 FeO 4 [Fe(VI)] was investigated for the first time, with the exploration of reaction mechanisms. Six different types of water treatment agents (powdered activated carbon, Al 2 (SO 4 ) 3 , FeCl 3 , δ-MnO 2 , MnO 2 nano-particles, and K 2 FeO 4 ) were used for the removal of Tl in spiked river water, and K 2 FeO 4 showed excellent removal performance. Over 92% of Tl (1 μg/L) was removed within 5 min by applying 2.5 mg/L of K 2 FeO 4 (pH 7.0, 20 °C). XPS analysis revealed that in the reaction of Tl(I) with K 2 FeO 4 , Tl(I) was oxidized to Tl(III), and removed by the K 2 FeO 4 reduced ferric particles. The removal of Tl by in situ formed and ex situ formed ferric particle was examined respectively, and the results revealed that the removal of trace Tl could be attributed to the combination of adsorption and coprecipitation processes. The hydrodynamic size of the reduced particle from K 2 FeO 4 ranged from 10 nm to 100 nm, and its surface was negatively charged under neutral pH condition. These factors were conducive for the efficient removal of Tl by K 2 FeO 4 . The effects of solution pH, coexisting ions (Na + , Ca 2+ , and HCO 3 - ), humic acid, solution temperature, and reductive environment on the removal and desorption of Tl were investigated, and the elimination of Tl in polluted river water and reservoir water was performed. These results suggest that K 2 FeO 4 could be an efficient and convenient agent on trace Tl removal. Copyright © 2017. Published by Elsevier Ltd.

  20. Novel MBR_based main stream biological nutrient removal process: high performance and microbial community.

    Science.gov (United States)

    Zhang, Chuanyi; Xu, Xinhai; Zhao, Kuixia; Tang, Lianggang; Zou, Siqi; Yuan, Limei

    2018-02-01

    For municipal wastewater treatment, main stream biological nutrient removal (BNR) process is becoming more and more important. This lab-scale study, novel MBR_based BNR processes (named A 2 N-MBR and A 2 NO-MBR) were built. Comparison of the COD removal, results obtained demonstrated that COD removal efficiencies were almost the same in three processes, with effluent concentration all bellowed 30 mg L -1 . However, the two-sludge systems (A 2 N-MBR and A 2 NO-MBR) had an obvious advantage over the A 2 /O for denitrification and phosphorus removal, with the average TP removal rates of 91.20, 98.05% and TN removal rates of 73.00, 79.49%, respectively, higher than that of 86.45 and 61.60% in A 2 /O process. Illumina Miseq sequencing revealed that Candidatus_Accumulibacter, which is capable of using nitrate as an electron acceptor for phosphorus and nitrogen removal simultaneously, was the dominant phylum in both A 2 N-MBR and A 2 NO-MBR process, accounting for 28.74 and 23.98%, respectively. Distinguishingly, major organism groups related to nitrogen and phosphorus removal in A 2 /O system were Anaerolineaceae_uncultured, Saprospiraceae_uncultured and Thauera, with proportions of 11.31, 8.56 and 5.00%, respectively. Hence, the diversity of dominant PAOs group was likely responsible for the difference in nitrogen and phosphorus removal in the three processes.

  1. Watershed restoration: planning and implementing small dam removals to maximize ecosystem services

    Science.gov (United States)

    Tonitto, C.; Riha, S. J.

    2016-12-01

    River restoration and enhancing watershed connectivity is of growing concern in industrialized nations. The past two decades have seen a number of small dam removals, though many removals remain unstudied and poorly documented. We summarize socio-economic and biophysical lessons learned during the past two decades of accelerated activity regarding small dam removals throughout the United States. We present frameworks for planning and implementing removals developed by interdisciplinary engagement. Toward the goal of achieving thorough dam removal planning, we present outcomes from well-documented small dam removals covering ecological, chemical, and physical change in rivers post-dam removal, including field observation and modeling methodologies. Guiding principles of a dam removal process should include: 1) stakeholder engagement to navigate the complexity of watershed landuse, 2) an impacts assessment to inform the planning process, 3) pre- and post-dam removal observations of ecological, chemical and physical properties, 4) the expectation that there are short- and long-term ecological dynamics with population recovery depending on whether dam impacts were largely related to dispersion or to habitat destruction, 5) an expectation that changes in watershed chemistry are dependent on sediment type, sediment transport and watershed landuse, and 6) rigorous assessment of physical changes resulting from dam removal, understanding that alteration in hydrologic flows, sediment transport, and channel evolution will shape ecological and chemical dynamics, and shape how stakeholders engage with the watershed.

  2. Highly effective removal of heavy metals by polymer-based zirconium phosphate: a case study of lead ion.

    Science.gov (United States)

    Pan, B C; Zhang, Q R; Zhang, W M; Pan, B J; Du, W; Lv, L; Zhang, Q J; Xu, Z W; Zhang, Q X

    2007-06-01

    Zirconium phosphate (ZrP) has recently been demonstrated as an excellent sorbent for heavy metals due to its high selectivity, high thermal stability, and absolute insolubility in water. However, it cannot be readily adopted in fixed beds or any other flowthrough system due to the excessive pressure drop and poor mechanical strength resulting from its fine submicrometer particle sizes. In the present study a hybrid sorbent, i.e., polymer-supported ZrP, was prepared by dispersing ZrP within a strongly acidic cation exchanger D-001 and used for enhanced lead removal from contaminated waters. D-001 was selected as a host material for sorbent preparation mainly because of the Donnan membrane effect resulting from the nondiffusible negatively charged sulfonic acid group on the exchanger surface, which would enhance permeation of the targeted metal ions. The hybrid sorbent (hereafter denoted ZrP-001) was characterized using a nitrogen adsorption technique, scanning electron microscope (SEM), and X-ray diffraction (XRD). Lead sorption onto ZrP-001 was found to be pH dependent due to the ion-exchange mechanism, and its sorption kinetics onto ZrP-001 followed the pseudo-first-order model. Compared to D-001, ZrP-001 exhibited more favorable lead sorption particularly in terms of high selectivity, as indicated by its substantially larger distribution coefficients when other competing cations Na(+), Ca(2+), and Mg(2+) coexisted at a high level in solution. Fixed-bed column runs showed that lead sorption on ZrP-001 resulted in a conspicuous decrease of this toxic metal from 40 mg/L to below 0.05 mg/L. By comparison with D-001 and ZrP-CP (ZrP dispersion within a neutrally charged polymer CP), enhanced removal efficiency of ZrP-001 resulted from the Donnan membrane effect of the host material D-001. Moreover, its feasible regeneration by diluted acid solution and negligible ZrP loss during operation also helps ZrP-001 to be a potential candidate for lead removal from water. Thus

  3. Understanding cost drivers and economic potential of two variants of ionic liquid pretreatment for cellulosic biofuel production

    Science.gov (United States)

    2014-01-01

    Background Ionic liquid (IL) pretreatment could enable an economically viable route to produce biofuels by providing efficient means to extract sugars and lignin from lignocellulosic biomass. However, to realize this, novel IL-based processes need to be developed in order to minimize the overall production costs and accelerate commercial viability. In this study, two variants of IL-based processes are considered: one based on complete removal of the IL prior to hydrolysis using a water-wash (WW) step and the other based on a “one-pot” (OP) process that does not require IL removal prior to saccharification. Detailed techno-economic analysis (TEA) of these two routes was carried out to understand the cost drivers, economic potential (minimum ethanol selling price, MESP), and relative merits and challenges of each route. Results At high biomass loading (50%), both routes exhibited comparable economic performance with an MESP of $6.3/gal. With the possible advances identified (reduced water or acid/base consumption, improved conversion in pretreatment, and lignin valorization), the MESP could be reduced to around $3/gal ($3.2 in the WW route and $2.8 in the OP route). Conclusions It was found that, to be competitive at industrial scale, lowered cost of ILs used and higher biomass loadings (50%) are essential for both routes, and in particular for the OP route. Overall, while the economic potential of both routes appears to be comparable at higher biomass loadings, the OP route showed the benefit of lower water consumption at the plant level, an important cost and sustainability consideration for biorefineries. PMID:24932217

  4. Phenols removal by immobilized tyrosinase reactor in on-line high performance liquid chromatography

    International Nuclear Information System (INIS)

    Girelli, Anna Maria; Mattei, Enrico; Messina, Antonella

    2006-01-01

    The development of an immobilized enzyme reactor (IMER) based on tyrosinase immobilized on aminopropyl-controlled pore glass (AP-CPG) for the removal of phenols from model aqueous solutions was reported. To elucidate the influence of the substrate nature, the apparent (V ' max , K ' m ) and the inherent (V max , K m ) Michaelis-Menten constants were determined by Lineweaver-Burk method and the external diffusional contributions on measured enzyme activities were removed by a graphical method. The dephenolization process was realized by recycling the phenol solutions through the bioreactor connected to a chitosan trap in order to remove the colored quinone-type products of the tyrosinase reactions. The results indicated that a complete removal of phenol derivatives in the range of 150-300min, with the exception of 60% removal for phenol reached in 400min, was obtained. The observed sequence: cresol>4-methylcathecol>catechol>4-Cl-phenol-bar phenol was in accordance to the V ' max /K ' m values

  5. Modelling the economic losses of historic and present-day high-impact winter storms in Switzerland

    Science.gov (United States)

    Welker, Christoph; Stucki, Peter; Bresch, David; Dierer, Silke; Martius, Olivia; Brönnimann, Stefan

    2014-05-01

    Severe winter storms such as "Vivian" in February 1990 and "Lothar" in December 1999 are among the most destructive meteorological hazards in Switzerland. Disaster severity resulting from such windstorms is attributable, on the one hand, to hazardous weather conditions such as high wind gust speeds; and on the other hand to socio-economic factors such as population density, distribution of values at risk, and damage susceptibility. For present-day winter storms, the data basis is generally good to describe the meteorological development and wind forces as well as the associated socio-economic impacts. In contrast, the information on historic windstorms is overall sparse and the available historic weather and loss reports mostly do not provide quantitative information. This study illustrates a promising technique to simulate the economic impacts of both historic and present winter storms in Switzerland since end of the 19th century. Our approach makes use of the novel Twentieth Century Reanalysis (20CR) spanning 1871-present. The 2-degree spatial resolution of the global 20CR dataset is relatively coarse. Thus, the complex orography of Switzerland is not realistically represented, which has considerable ramifications for the representation of wind systems that are strongly influenced by the local orography, such as Föhn winds. Therefore, a dynamical downscaling of the 20CR to 3 km resolution using the Weather Research and Forecasting (WRF) model was performed, for in total 40 high-impact winter storms in Switzerland since 1871. Based on the downscaled wind gust speeds and the climada loss model, the estimated economic losses were calculated at municipality level for current economic and social conditions. With this approach, we find an answer to the question what would be the economic losses of e.g. a hazardous Föhn storm - which occurred in northern Switzerland in February 1925 - today, i.e. under current socio-economic conditions. Encouragingly, the pattern of

  6. Microporous metal–organic framework with dual functionalities for highly efficient removal of acetylene from ethylene/acetylene mixtures

    KAUST Repository

    Hu, Tong-Liang

    2015-06-04

    The removal of acetylene from ethylene/acetylene mixtures containing 1% acetylene is a technologically very important, but highly challenging task. Current removal approaches include the partial hydrogenation over a noble metal catalyst and the solvent extraction of cracked olefins, both of which are cost and energy consumptive. Here we report a microporous metal–organic framework in which the suitable pore/cage spaces preferentially take up much more acetylene than ethylene while the functional amine groups on the pore/cage surfaces further enforce their interactions with acetylene molecules, leading to its superior performance for this separation. The single X-ray diffraction studies, temperature dependent gas sorption isotherms, simulated and experimental column breakthrough curves and molecular simulation studies collaboratively support the claim, underlying the potential of this material for the industrial usage of the removal of acetylene from ethylene/acetylene mixtures containing 1% acetylene at room temperature through the cost- and energy-efficient adsorption separation process.

  7. ECOLOGICAL ECONOMICS VS ECONOMIC(AL ECOLOGY

    Directory of Open Access Journals (Sweden)

    G. Kharlamova

    2015-10-01

    Full Text Available Currently world faces the dilemma – ecological economy or economic(al ecology. The researchers produce hundreds of surveys on the topic. However the analyses of recent most cited simulations had shown the diversity of results. Thus, for some states the Kuznets environmental curve has place, for others – no. Same could be said about different years for the same state. It provokes the necessity of drawing new group analyses to reveal the tendencies and relationships between economic and environmental factors. Most flexible and mirror factor of environmental sustainability is the volume of CO2 emissions. The econometric analysis was used for detecting the economic impact on this indicator at the global level and in the spectra of group of states depending on their income. The hypothesis of the existence of environmental Kuznets curve for the analysed data is rejected. Real GDP per capita impact on carbon dioxide emissions is considered only at the global level. The impact of openness of the economy is weak. Rejection happened also to the hypothesis that for the developed countries there is a reverse dependence between the environmental pollution and economic openness. Indicator “energy consumption per capita” impacts on greenhouse gas emissions only in countries with high income. Whereby it should be noted that the more developed a country is, the more elastic is this influence. These results have a potential usage for environmental policy regulation and climate strategy.

  8. Research progress of siloxane removal from biogas

    Directory of Open Access Journals (Sweden)

    Gao Ruiling

    2017-01-01

    Full Text Available Siloxanes in biogas are detrimental to engine, turbine, fuel cell, etc., thus it is necessary to remove siloxanes from biogas before biogas high-value utilization. At present, there are few domestic researches and related reports in view of siloxanes removal from biogas. This paper introduces the property of siloxanes as well as sampling and analysis method, and then presents the research progress of siloxanes removal from biogas. Three commercial technologies overseas are adsorption, absorption and cryogenic condensation. Among them, adsorption on activated carbon is the most widely used method. Other technologies, such as biological removal, catalytic processes, membranes, source controlling, etc. are under exploration and development. At last, this paper summarizes the advantages and disadvantages of siloxanes removal technologies as well as the applicability and analyzes the future research trend and emphasis. This paper could provide a reference in the field of biogas high-value utilization.

  9. Impact of high-risk conjunctions on Active Debris Removal target selection

    OpenAIRE

    Lidtke, Aleksander A.; Lewis, Hugh G.; Armellin, Roberto

    2015-01-01

    All rights reserved.Space debris simulations show that if current space launches continue unchanged, spacecraft operations might become difficult in the congested space environment. It has been suggested that Active Debris Removal (ADR) might be necessary in order to prevent such a situation. Selection of objects to be targeted by ADR is considered important because removal of non-relevant objects will unnecessarily increase the cost of ADR. One of the factors to be used in this ADR target se...

  10. Economic and environmental sustainability of submerged anaerobic MBR-based (AnMBR-based) technology as compared to aerobic-based technologies for moderate-/high-loaded urban wastewater treatment.

    Science.gov (United States)

    Pretel, R; Robles, A; Ruano, M V; Seco, A; Ferrer, J

    2016-01-15

    The objective of this study was to assess the economic and environmental sustainability of submerged anaerobic membrane bioreactors (AnMBRs) in comparison with aerobic-based technologies for moderate-/high-loaded urban wastewater (UWW) treatment. To this aim, a combined approach of steady-state performance modelling, life cycle analysis (LCA) and life cycle costing (LCC) was used, in which AnMBR (coupled with an aerobic-based post-treatment) was compared to aerobic membrane bioreactor (AeMBR) and conventional activated sludge (CAS). AnMBR with CAS-based post-treatment for nutrient removal was identified as a sustainable option for moderate-/high-loaded UWW treatment: low energy consumption and reduced sludge production could be obtained at given operating conditions. In addition, significant reductions can be achieved in different aspects of environmental impact (global warming potential (GWP), abiotic depletion, acidification, etc.) and LCC over existing UWW treatment technologies. Copyright © 2015 Elsevier Ltd. All rights reserved.

  11. Organically modified clay removes oil from water

    International Nuclear Information System (INIS)

    Alther, G.R.

    1995-01-01

    When bentonite or other clays and zeolite are modified with quaternary amines, they become organophilic. Such modified bentonites are used to remove mechanically emulsified oil and grease, and other sparingly soluble organics. Types of oil found in water can include fats, lubricants, cutting fluids, heavy hydrocarbons such as tars, grease, crude oil, diesel oils; and light hydrocarbons such as kerosene, jet fuel, and gasoline. If the organoclay is granulated, it is placed into a liquid phase carbon filter vessel to remove FOGs (Free Oil and Grease) and chlorinated hydrocarbons. In this application the clay is mixed with anthrazite to prevent early plugging of the filter by oil or grease droplets. In batch systems a powdered organoclay is employed. Organoclay removes mechanically emulsified oil and grease at 5--7 times the rate of activated carbon, or 50% of its dry weight. Oil and grease and other large sparingly soluble chlorinated hydrocarbons and NOMs (Natural Organic Matter) blind the pores of activated carbon (and ion-exchange resins), reducing its effectiveness significantly. It is therefore economically advantageous for the end user to prepolish the water before it enters carbon vessels. Operating costs can often be reduced by 50% or more

  12. The health economics of cholera: A systematic review.

    Science.gov (United States)

    Hsiao, Amber; Hall, Angela H; Mogasale, Vittal; Quentin, Wilm

    2018-06-12

    Vibrio cholera is a major contributor of diarrheal illness that causes significant morbidity and mortality globally. While there is literature on the health economics of diarrheal illnesses more generally, few studies have quantified the cost-of-illness and cost-effectiveness of cholera-specific prevention and control interventions. The present systematic review provides a comprehensive overview of the literature specific to cholera as it pertains to key health economic measures. A systematic review was performed with no date restrictions up through February 2017 in PubMed, Econlit, Embase, Web of Science, and Cochrane Review to identify relevant health economics of cholera literature. After removing duplicates, a total of 1993 studies were screened and coded independently by two reviewers, resulting in 22 relevant studies. Data on population, methods, and results (cost-of-illness and cost-effectiveness of vaccination) were compared by country/region. All costs were adjusted to 2017 USD for comparability. Costs per cholera case were found to be rather low: $1000/case. There is adequate evidence to support the economic value of vaccination for the prevention and control of cholera when vaccination is targeted at high-incidence populations and/or areas with high case fatality rates due to cholera. When herd immunity is considered, vaccination also becomes a cost-effective option for the general population and is comparable in cost-effectiveness to other routine immunizations. Cholera vaccination is a viable short-to-medium term option, especially as the upfront costs of building water, sanitation, and hygiene (WASH) infrastructure are considerably higher for countries that face a significant burden of cholera. While WASH may be the more cost-effective solution in the long-term when implemented properly, cholera vaccination can still be a feasible, cost-effective strategy. Copyright © 2018 Elsevier Ltd. All rights reserved.

  13. Synergic Adsorption–Biodegradation by an Advanced Carrier for Enhanced Removal of High-Strength Nitrogen and Refractory Organics

    KAUST Repository

    Ahmad, Muhammad

    2017-03-29

    Coking wastewater contains not only high-strength nitrogen but also toxic biorefractory organics. This study presents simultaneous removal of high-strength quinoline, carbon, and ammonium in coking wastewater by immobilized bacterial communities composed of a heterotrophic strain Pseudomonas sp. QG6 (hereafter referred as QG6), ammonia-oxidizing bacteria (AOB), and anaerobic ammonium oxidation bacteria (anammox). The bacterial immobilization was implemented with the help of a self-designed porous cubic carrier that created structured microenvironments including an inner layer adapted for anaerobic bacteria, a middle layer suitable for coaggregation of certain aerobic and anaerobic bacteria, and an outer layer for heterotrophic bacteria. By coating functional polyurethane foam (FPUF) with iron oxide nanoparticles (IONPs), the biocarrier (IONPs-FPUF) could provide a good outer-layer barrier for absorption and selective treatment of aromatic compounds by QG6, offer a conducive environment for anammox in the inner layer, and provide a mutualistic environment for AOB in the middle layer. Consequently, simultaneous nitrification and denitrification were reached with the significant removal of up to 322 mg L (98%) NH, 311 mg L (99%) NO, and 633 mg L (97%) total nitrogen (8 mg L averaged NO concentration was recorded in the effluent), accompanied by an efficient removal of chemical oxygen demand by 3286 mg L (98%) and 350 mg L (100%) quinoline. This study provides an alternative way to promote synergic adsorption and biodegradation with the help of a modified biocarrier that has great potential for treatment of wastewater containing high-strength carbon, toxic organic pollutants, and nitrogen.

  14. Synergic Adsorption-Biodegradation by an Advanced Carrier for Enhanced Removal of High-Strength Nitrogen and Refractory Organics.

    Science.gov (United States)

    Ahmad, Muhammad; Liu, Sitong; Mahmood, Nasir; Mahmood, Asif; Ali, Muhammad; Zheng, Maosheng; Ni, Jinren

    2017-04-19

    Coking wastewater contains not only high-strength nitrogen but also toxic biorefractory organics. This study presents simultaneous removal of high-strength quinoline, carbon, and ammonium in coking wastewater by immobilized bacterial communities composed of a heterotrophic strain Pseudomonas sp. QG6 (hereafter referred as QG6), ammonia-oxidizing bacteria (AOB), and anaerobic ammonium oxidation bacteria (anammox). The bacterial immobilization was implemented with the help of a self-designed porous cubic carrier that created structured microenvironments including an inner layer adapted for anaerobic bacteria, a middle layer suitable for coaggregation of certain aerobic and anaerobic bacteria, and an outer layer for heterotrophic bacteria. By coating functional polyurethane foam (FPUF) with iron oxide nanoparticles (IONPs), the biocarrier (IONPs-FPUF) could provide a good outer-layer barrier for absorption and selective treatment of aromatic compounds by QG6, offer a conducive environment for anammox in the inner layer, and provide a mutualistic environment for AOB in the middle layer. Consequently, simultaneous nitrification and denitrification were reached with the significant removal of up to 322 mg L -1 (98%) NH 4 , 311 mg L -1 (99%) NO 2 , and 633 mg L -1 (97%) total nitrogen (8 mg L -1 averaged NO 3 concentration was recorded in the effluent), accompanied by an efficient removal of chemical oxygen demand by 3286 mg L -1 (98%) and 350 mg L -1 (100%) quinoline. This study provides an alternative way to promote synergic adsorption and biodegradation with the help of a modified biocarrier that has great potential for treatment of wastewater containing high-strength carbon, toxic organic pollutants, and nitrogen.

  15. Cellulase retention and sugar removal by membrane ultrafiltration during lignocellulosic biomass hydrolysis.

    Science.gov (United States)

    Knutsen, Jeffrey S; Davis, Robert H

    2004-01-01

    Technologies suitable for the separation and reuse of cellulase enzymes during the enzymatic saccharification of pretreated corn stover are investigated to examine the economic and technical viability of processes that promote cellulase reuse while removing inhibitory reaction products such as glucose and cellobiose. The simplest and most suitable separation is a filter with relatively large pores on the order of 20-25 mm that retains residual corn stover solids while passing reaction products such as glucose and cellobiose to form a sugar stream for a variety of end uses. Such a simple separation is effective because cellulase remains bound to the residual solids. Ultrafiltration using 50-kDa polyethersulfone membranes to recover cellulase enzymes in solution was shown not to enhance further the saccharification rate or overall conversion. Instead, it appears that the necessary cellulase enzymes, including beta-glucosidase, are tightly bound to the substrate; when fresh corn stover is contacted with highly washed residual solids, without the addition of fresh enzymes, glucose is generated at a high rate. When filtration was applied multiple times, the concentration of inhibitory reaction products such as glucose and cellobiose was reduced from 70 to 10 g/L. However, an enhanced saccharification performance was not observed, most likely because the concentration of the inhibitory products remained too high. Further reduction in the product concentration was not investigated, because it would make the reaction unnecessarily complex and result in a product stream that is much too dilute to be useful. Finally, an economic analysis shows that reuse of cellulase can reduce glucose production costs, especially when the enzyme price is high. The most economic performance is shown to occur when the cellulase enzyme is reused and a small amount of fresh enzyme is added after each separation step to replace lost or deactivated enzyme.

  16. Nanofluids and chemical highly retentive hydrogels for controlled and selective removal of overpaintings and undesired graffiti from street art.

    Science.gov (United States)

    Giorgi, Rodorico; Baglioni, Michele; Baglioni, Piero

    2017-06-01

    One of the main problems connected to the conservation of street art is the selective removal of overlying undesired graffiti, i.e., drawings and tags. Unfortunately, selective and controlled removal of graffiti and overpaintings from street art is almost unachievable using traditional methodologies. Recently, the use of nanofluids confined in highly retentive pHEMA/PVP semi-interpenetrated polymer networks was proposed. Here, we report on the selective removal of acrylic overpaintings from a layer of acrylic paint on mortar mockups in laboratory tests. The results of the cleaning tests were characterized by visual and photographic observation, optical microscopy, and FT-IR microreflectance investigation. It was shown that this methodology represents a major advancement with respect to the use of nonconfined neat solvents.

  17. Enhanced removal of Methylene Blue by electrocoagulation using iron electrodes

    Directory of Open Access Journals (Sweden)

    Mohamed S. Mahmoud

    2013-06-01

    Full Text Available The removal of pollutants from effluents by electrocoagulation has become an attractive method in recent years. The study deals with the enhancement of removal of Methylene Blue dye by using an electromagnetic field during the electrocoagulation process. Effects of electrolyte concentration, dye concentration, intensity and the direction of the electromagnet on the decolorization efficiency have been investigated. The formed ferric hydroxide flocs trap colloidal particles and make solid–liquid separation easier during the next stage. The electrocoagulation stages must be optimized in order to design an economically feasible process. The results showed that the optimum electrolysis was 10–20 min at a current density of 8 mA/cm2, while the optimum concentration of the electrolyte (NaOH was found to be 2 wt.% when the dye concentration was 50 mg/L. The utilization of an electromagnetic field enhanced the dye removal due to the induced motion of paramagnetic ions inside the solution. The power consumption required to remove the dye was reduced by 45% in the case of applying an electromagnetic field.

  18. Enabling fast charging - Infrastructure and economic considerations

    Science.gov (United States)

    Burnham, Andrew; Dufek, Eric J.; Stephens, Thomas; Francfort, James; Michelbacher, Christopher; Carlson, Richard B.; Zhang, Jiucai; Vijayagopal, Ram; Dias, Fernando; Mohanpurkar, Manish; Scoffield, Don; Hardy, Keith; Shirk, Matthew; Hovsapian, Rob; Ahmed, Shabbir; Bloom, Ira; Jansen, Andrew N.; Keyser, Matthew; Kreuzer, Cory; Markel, Anthony; Meintz, Andrew; Pesaran, Ahmad; Tanim, Tanvir R.

    2017-11-01

    The ability to charge battery electric vehicles (BEVs) on a time scale that is on par with the time to fuel an internal combustion engine vehicle (ICEV) would remove a significant barrier to the adoption of BEVs. However, for viability, fast charging at this time scale needs to also occur at a price that is acceptable to consumers. Therefore, the cost drivers for both BEV owners and charging station providers are analyzed. In addition, key infrastructure considerations are examined, including grid stability and delivery of power, the design of fast charging stations and the design and use of electric vehicle service equipment. Each of these aspects have technical barriers that need to be addressed, and are directly linked to economic impacts to use and implementation. This discussion focuses on both the economic and infrastructure issues which exist and need to be addressed for the effective implementation of fast charging at 400 kW and above. In so doing, it has been found that there is a distinct need to effectively manage the intermittent, high power demand of fast charging, strategically plan infrastructure corridors, and to further understand the cost of operation of charging infrastructure and BEVs.

  19. Removing Fe, Zn and Mn from steel making plant wastewater using RO and NF membranes

    Directory of Open Access Journals (Sweden)

    Seyed Ahmad Mirbagheri

    2016-12-01

    Full Text Available Background and purpose: Excessive amount of heavy metals in industrial wastewater is a seriously crucial issue and requires efficient methods to be introduced and dealt with. Meanwhile, steel making plants as productive units in every country release large amounts of fluid into surface and underground sources. Typically, this wastewater contains heavy metals in minor amounts, while this amount could cause severe damages to the living organisms. Materials and methods: In this study, removing iron, manganese, zinc and total dissolved solid in a typical wastewater resulted from steel making plant was considered using reverse osmosis (RO and nanofiltration (NF membranes. At first, different pH values and operating pressures were applied to the wastewater. Then, these parameters were evaluated for a wastewater only containing iron to compare the interaction of other elements in iron removal. Results: The results indicated that RO and NF membranes could successfully treat industrial wastewater containing several heavy metals with high concentrations of Fe, Zn and Mn, especially at optimum pH and pressure. Moreover, the interaction of other heavy metals and components in the influent decreased the efficiency of RO but improved the NF efficiency to remove iron. To have a better image, a formula was proposed for each method to represent the influence of the parameters on removal rates. Finally, cost estimation for both procedures showed that RO was not economically-technically efficient in comparison with NF. Conclusion: NF showed an acceptable performance with high water flow which made it more suitable for industries. At the end, the relative cost analysis showed that even if the initial price of NF is high, the energy consumption and total cost of RO will be higher.

  20. Technetium in alkaline, high-salt, radioactive tank waste supernate: Preliminary characterization and removal

    International Nuclear Information System (INIS)

    Blanchard, D.L. Jr.; Brown, G.N.; Conradson, S.D.

    1997-01-01

    This report describes the initial work conducted at Pacific Northwest National Laboratory to study technetium (Tc) removal from Hanford tank waste supernates and Tc oxidation state in the supernates. Filtered supernate samples from four tanks were studied: a composite double shell slurry feed (DSSF) consisting of 70% from Tank AW-101, 20% from AP-106, and 10% from AP-102; and three complexant concentrate (CC) wastes (Tanks AN-107, SY-101, ANS SY-103) that are distinguished by having a high concentration of organic complexants. The work included batch contacts of these waste samples with Reillex trademark-HPQ (anion exchanger from Reilly Industries) and ABEC 5000 (a sorbent from Eichrom Industries), materials designed to effectively remove Tc as pertechnetate from tank wastes. A short study of Tc analysis methods was completed. A preliminary identification of the oxidation state of non-pertechnetate species in the supernates was made by analyzing the technetium x-ray absorption spectra of four CC waste samples. Molybdenum (Mo) and rhenium (Re) spiked test solutions and simulants were tested with electrospray ionization-mass spectrometry to evaluate the feasibility of the technique for identifying Tc species in waste samples

  1. Economic development and environmental protection: an ecological economics perspective.

    Science.gov (United States)

    Rees, William E

    2003-01-01

    This paper argues on both theoretical and empirical grounds that, beyond a certain point, there is an unavoidable conflict between economic development (generally taken to mean 'material economic growth') and environmental protection. Think for a moment of natural forests, grasslands, marine estuaries, salt marshes, and coral reefs; and of arable soils, aquifers, mineral deposits, petroleum, and coal. These are all forms of 'natural capital' that represent highly-ordered self-producing ecosystems or rich accumulations of energy/matter with high use potential (low entropy). Now contemplate despoiled landscapes, eroding farmlands, depleted fisheries, anthropogenic greenhouse gases, acid rain, poisonous mine tailings and toxic synthetic compounds. These all represent disordered systems or degraded forms of energy and matter with little use potential (high entropy). The main thing connecting these two states is human economic activity. Ecological economics interprets the environment-economy relationship in terms of the second law of thermodynamics. The second law sees economic activity as a dissipative process. From this perspective, the production of economic goods and services invariably requires the consumption of available energy and matter. To grow and develop, the economy necessarily 'feeds' on sources of high-quality energy/matter first produced by nature. This tends to disorder and homogenize the ecosphere, The ascendance of humankind has consistently been accompanied by an accelerating rate of ecological degradation, particularly biodiversity loss, the simplification of natural systems and pollution. In short, contemporary political rhetoric to the contrary, the prevailing growth-oriented global development paradigm is fundamentally incompatible with long-term ecological and social sustainability. Unsustainability is not a technical nor economic problem as usually conceived, but rather a state of systemic incompatibility between a economy that is a fully

  2. Eurasian Economic Union: A Regional Economic Hegemony Initiative

    Directory of Open Access Journals (Sweden)

    Serdar YILMAZ

    2017-11-01

    Full Text Available It can be assumed that international relations terminology has not mentioned enough about the significance of the Eurasian Economic Union in territorial as well as in economic terms during a period of growing geopolitical risks and high interdependence between the member countries and the rest. According to Kazakhstan’s President Nursultan Nazarbayev, it is truly difficult for states to overcome economic, political and security issues and therefore, states need to act together against the problems in a globalizing world by establishing regional and international organisations. This article thus examines the Eurasian Economic Union integration proces, which is driven by political and economic factors that consolidate regional security and create an effective economic system, whether it in the long term will become successful or not. The author also analyses the Kazakh economic and strategic interests in the region as well as the motivation, power and influence of other members in deepening the cooperation with international arena and the limits in the economic-security integration.

  3. Phenols removal by immobilized tyrosinase reactor in on-line high performance liquid chromatography

    Energy Technology Data Exchange (ETDEWEB)

    Girelli, Anna Maria [Dipartimento di Chimica, Universita degli Studi di Roma ' La Sapienza' , P.le Aldo Moro 5, 00185 Rome (Italy)]. E-mail: annamaria.girelli@uniroma1.it; Mattei, Enrico [Dipartimento di Chimica, Universita degli Studi di Roma ' La Sapienza' , P.le Aldo Moro 5, 00185 Rome (Italy); Messina, Antonella [Dipartimento di Chimica, Universita degli Studi di Roma ' La Sapienza' , P.le Aldo Moro 5, 00185 Rome (Italy)

    2006-11-24

    The development of an immobilized enzyme reactor (IMER) based on tyrosinase immobilized on aminopropyl-controlled pore glass (AP-CPG) for the removal of phenols from model aqueous solutions was reported. To elucidate the influence of the substrate nature, the apparent (V{sup '}{sub max}, K{sup '}{sub m}) and the inherent (V{sub max}, K{sub m}) Michaelis-Menten constants were determined by Lineweaver-Burk method and the external diffusional contributions on measured enzyme activities were removed by a graphical method. The dephenolization process was realized by recycling the phenol solutions through the bioreactor connected to a chitosan trap in order to remove the colored quinone-type products of the tyrosinase reactions. The results indicated that a complete removal of phenol derivatives in the range of 150-300min, with the exception of 60% removal for phenol reached in 400min, was obtained. The observed sequence: cresol>4-methylcathecol>catechol>4-Cl-phenol-bar phenol was in accordance to the V{sup '}{sub max}/K{sup '}{sub m} values.

  4. Purifying Synthetic High-Strength Wastewater by Microalgae Chlorella Vulgaris Under Various Light Emitting Diode Wavelengths and Intensities

    Directory of Open Access Journals (Sweden)

    Zhigang Ge

    2013-06-01

    Full Text Available The high-strength wastewater is now well known as a threat to the natural water since it is highly possible to arouse water eutrophication or algal blooms. The effects of various light emitting diode wavelengths and intensities on the microalgae biological wastewater treatment system was studied in this research. The various nutrient removals and economic efficiencies represented similar variation trends, and these variations under both high C and N loading treatments were similar too. The order for microalgae C. vulgaris reproduction in terms of dry weight and nutrient removal efficiency both were red > white > yellow > blue, under high carbon and nitrogen loading treatments, indicating that the red light was the optimum light wavelength. Furthermore, considering the optimal light intensity in terms of nutrient removal efficiency was 2500 and 2000 μmol/m2•s, while in terms of economic efficiency was 1000, 1500 and 2000 μmol/m2•s. Therefore, the optimum light intensity was found to be 2000 μmol/m2•s. In addition, the optimal experimental illumination time was determined as 120 h. The Chlorella vulgaris microalgae biological wastewater treatment system utilized in this research was able to purify the high-strength carbon and nitrogen wastewater effectively under optimum light wavelength and intensity.

  5. Synthesis, characterization and dye removal ability of high capacity polymeric adsorbent: Polyaminoimide homopolymer

    International Nuclear Information System (INIS)

    Mahmoodi, Niyaz Mohammad; Najafi, Farhood; Khorramfar, Shooka; Amini, Farrokhlegha; Arami, Mokhtar

    2011-01-01

    Highlights: ► Polyaminoimide homopolymer (PAIHP) was synthesized and characterized. ► Kinetics data followed pseudo-second order kinetic model. ► Isotherm data followed Langmuir isotherm. ► Q 0 for DR31, DR23, DB22 and AB25 was 6667, 5555, 9090 and 5882 mg/g, respectively. ► PAIHP was regenerated at pH 12. - Abstract: In this paper, polyaminoimide homopolymer (PAIHP) was synthesized and its dye removal ability was investigated. Physical characteristics of PAIHP were studied using Fourier transform infrared (FTIR) and scanning electron microscopy (SEM). Direct Red 31 (DR31), Direct Red 23 (DR23), Direct Black 22 (DB22) and Acid Blue 25 (AB25) were used as model compounds. The kinetic and isotherm of dye adsorption were studied. The effect of operational parameter such as adsorbent dosage, pH and salt on dye removal was evaluated. Adsorption kinetic of dyes followed pseudo-second order kinetics. The maximum dye adsorption capacity (Q 0 ) of PAIHP was 6667 mg/g, 5555 mg/g, 9090 mg/g and 5882 mg/g for DR31, DR23, DB22 and AB25, respectively. It was found that adsorption of DR31, DR23, DB22 and AB25 onto PAIHP followed with Langmuir isotherm. Dye desorption tests (adsorbent regeneration) showed that the maximum dye release of 90% for DR31, 86% for DR23, 87% for DB22 and 90% for AB25 were achieved in aqueous solution at pH 12. The results showed that the PAIHP as a polymeric adsorbent with high dye adsorption capacity might be a suitable alternative to remove dyes from colored wastewater.

  6. Removal of fouling species from brackish water reverse osmosis reject stream.

    Science.gov (United States)

    Ayoub, G M; Korban, L; Al-Hindi, M; Zayyat, R

    2018-03-01

    Brine disposal from reverse osmosis (RO) systems remains a major challenge for the desalination industry especially in inland areas where discharge options are very limited. Solutions will entail the introduction of economic treatment processes that will alleviate the brine's negative impact on the environment and reduce its discharge volume. Such processes could act as an intermediary treatment process for the recycling of the brine through an additional RO stage which, for brackish water (BW) desalination, could lead to saving valuable water while reducing the amount of brine discharge. In this context, the study at hand attempts to evaluate the effectiveness of a one-step chemical process for the treatment of BWRO brine. This study seeks to determine optimal operating conditions relative to type, ratio, and dosage of alkalizing chemicals, pH and temperature, for substantially reducing the concentrations of scaling parameters such as calcium, magnesium, silica, and strontium. The results indicate that precipitation softening at pH = 11.5 using combined chemical dosages of NaOH and Na 2 CO 3 in a ratio of 2:1 leads to substantial removal of calcium and magnesium (>95%) and moderately high removal of strontium and silica (>71%).

  7. Environmental and economic evaluation of selective non-catalytic reduction of nitrogen oxides

    Science.gov (United States)

    Parchevskii, V. M.; Shchederkina, T. E.; Proshina, A. O.

    2017-11-01

    There are two groups of atmosphere protecting measures: technology (primary) and treatment (secondary). When burning high-calorie low-volatile brands of coals in the furnaces with liquid slag removal to achieve emission standards required joint use of these two methods, for example, staged combustion and selective non-catalytic reduction recovery (SNCR). For the economically intelligent combination of these two methods it is necessary to have information not only about the environmental performance of each method, but also the operating costs per unit of reduced emission. The authors of this report are made an environmental-economic analysis of SNCR on boiler Π-50P Kashirskaya power station. The obtained results about the dependence of costs from the load of the boiler and the mass emissions of nitrogen oxides then approximates into empirical formulas, is named as environmental and economic characteristics, which is suitable for downloading into controllers and other control devices for subsequent implementation of optimal control of emissions to ensure compliance with environmental regulations at the lowest cost at any load of the boiler.

  8. Small zeolite column tests for removal of cesium from high radioactive contaminated water in Fukushima Daiichi Nuclear Power Station

    International Nuclear Information System (INIS)

    Hijikata, Takatoshi; Uozumi, Koichi; Tukada, Takeshi; Koyama, Tadafumi; Ishikawa, Keiji; Ono, Shoichi; Suzuki, Shunichi; Denton, Mark; Raymont, John

    2011-01-01

    After the earthquake on March 11th 2011, a large amount (more than 0.12 million m 3 ) of highly radioactive contaminated water had pooled in Fukushima Daiichi nuclear power station. As an urgent issue, highly radioactive nuclides should be removed from this contaminated water to reduce radioactivity in the turbine buildings and nuclear reactor buildings. Removal of Cs from this contaminated water is a key issue, because 134 Cs and 137 Cs are highly radioactive γ-emitting nuclides. The zeolite column system was used for Cs and Sr removal from the radioactive water of Three-Mile Island Unit 2, and modified columns were then developed as a Cs removal method for high-level radioactive water in US national laboratories (WRSC, ORNL, PNNL, Hanford, etc.). In order to treat Fukushima's highly contaminated water with a similar system, it was necessary to understand the properties of zeolite to remove Cs from sea salt as well as the applicability of the column system to a high throughput of around 1200 m 3 /d. The kinetic characteristics of the column were another property to be understood before actual operation. Hence, a functional small-scale zeolite column system was installed in CRIEPI for conducting the experiments to understand decontamination behaviors. Each column has a 2- or 3-cm inner diameter and a 12-cm height, and 12 g of zeolite-type media was packed into the column. The column experiments were carried out with Kurion-zeolite, Herschelite, at different feed rates of simulated water with different concentrations of Cs and sea salt. As for the water with 4 ppm Cs and 0 ppm sea salt, only a 10% Cs concentration was observed in the effluent after 20,000 bed volumes were fed at a rate of 33 cm/min, which corresponds to the actual system. On the other hand, a 40% Cs concentration was observed in the effluent after only 50 bed volumes were passed for water with 2 ppm Cs and 3.4 wt.% sea salt at a feed rate of 34 cm/min. As the absorption of Cs is hampered by the

  9. Economic efficiency of high-rise construction in the Moscow program of renovation of housing stock

    Science.gov (United States)

    Misailovov, Andrey

    2018-03-01

    The article considers a new initiative of the regional authorities of updating the housing stock designated as the renovation of housing. Its main aspects are analyzed, including the nature of program, economic efficiency of its implementation due to high-rise construction and the regulatory and legislative framework, the procedure for implementing the program, and the time frame for its implementation. The role of the program for regions in which high depreciation of the housing stock is combined with a limited number of sites for a new housing construction is disclosed. The high-rise construction in the renovation program is presented as a variant of a successful solution not only of the tasks of renovating the housing stock, but also of filling the regional budget. The social and economic orientation of the high-rise construction and the involvement of residents in the process of making town-planning decisions in the field of high-rise construction at all stages of implementing the program are shown.

  10. Ground water pollution by arsenic and its effects on health. Removal of arsenic from water; Suichu karano hiso no jokyo gijutsu

    Energy Technology Data Exchange (ETDEWEB)

    Tokunaga, S.

    1997-07-10

    Recently environmental standard for ground water is established. It is pointed out that the need of arsenic`s removal from water is expected in high level. Present condition of removal techniques of inorganic nitrogen and problems are explained. For example, ferro (III) chloride method is effective in As(V) and most suitable range is pH4{approx}5. Removal is possible until 0.005 when initial concentration is 0.2 mg{center_dot}l{sup -1}. As far as secondary problems are, there are dry treatment of generated sludge and disposal. Earth adsorbent as a new adsorbent is adsorption method is expected. Lanthanum and yttrium compounds possess adsorption for As(III) and As(V) and re-generation use is also possible. For example, removal of As(V) with initial concentration 19 mg{center_dot}l{sup -1} until 0.01 is possible at pH5{approx}77 range when hydroxide lanthanum is used as an adsorbent. Further special characteristics of each method are explained. It is concluded that a good removal method should be selected by considering raw water`s quality, capacity of treatment water, use of treatment water and economics. 29 refs., 2 figs.

  11. In-situ product removal from fermentations by membrane extraction: conceptual process design and economics

    NARCIS (Netherlands)

    Heerema, L.; Roelands, C.P.M.; Goetheer, E.L.V.; Verdoes, D.; Keurentjes, J.

    2011-01-01

    This paper describes a conceptual process design for the production of the model component phenol by a recombinant strain of the micro-organism Pseudomonas putida S12. The (bio)production of the inhibiting component phenol in a bioreactor is combined with direct product removal by membrane

  12. Radon-removal techniques for small community public water supplies

    International Nuclear Information System (INIS)

    Kinner, N.E.; Malley, J.P.; Clement, J.A.; Quern, P.A.; Schell, G.S.

    1990-08-01

    The report presents the results of an evaluation, performed by the University of New Hampshire--Environmental Research Group (ERG), of radon removal in small community water supplies using full-scale granular activated carbon adsorption, diffused bubble aeration and packed tower aeration. Various low technology alternatives, such as loss in a distribution system and addition of coarse bubble aeration to a pilot-scale atmospheric storage tank were also evaluated. The report discusses each of the treatment alternatives with respect to their radon removal efficiency, potential problems (i.e., waste disposal, radiation exposure and intermedia pollution), and economics in small community applications. In addition, several sampling methods, storage times, scintillation cocktails and extraction procedures currently used in the liquid scintillation technique for analysis of radon in water were compared

  13. Environment-friendly approach for the removal of toxic metals

    International Nuclear Information System (INIS)

    Zahra, N.; Mehmood, F.; Sheikh, S.T.; Javed, K.; Amin, A.

    2006-01-01

    Water pollution is serious economical problem and the presence of toxic metals like lead causes contamination of plants and then through nutritional chain it affects the health of humans and animals. This research work describes the removal of lead from wastewater using natural bentonites taken from various areas of Pakistan. The batch adsorption process was applied to remove this toxic metal. The quantities of lead metal before and after the treatment of standard solutions with different samples of bentonite were determined by atomic absorption spectroscopic method. The studies were carried out at room temperature, pH 7 and -200 mesh particle size using 50 ml of metal solutions. The time taken to maintain equilibrium was one hour. Then percentage adsorption was estimated on bentonite samples. (author)

  14. Heat transfer augmentation for high heat flux removal in rib-roughened narrow channels

    International Nuclear Information System (INIS)

    Islam, M.S.; Hino, Ryutaro; Haga, Katsuhiro; Sudo, Yukio; Monde, Masanori.

    1997-03-01

    Heat transfer augmentation in narrow rectangular channels in a target system is a very important method to remove high heat flux up to 12 MW/m 2 generated at target plates of a high-intensity proton accelerator of 1.5 GeV and 1 mA with a proton beam power of 1.5 MW. In this report, heat transfer coefficients and friction factors in narrow rectangular channels with one-sided rib-roughened surface were evaluated for fully developed flows in the range of the Reynolds number from 6,000 to 1,00,000; the rib pitch-to-height ratios (p/k) were 10,20 and 30; the rib height-to-equivalent diameter ratios (k/De) were 0.025, 0.03 and 0.1 by means of previous existing experimental correlations. The rib-roughened surface augmented heat transfer coefficients approximately 4 times higher than the smooth surface at Re=10,000, p/k=10 and k/De=0.1; friction factors increase around 22 times higher. In this case, higher heat flux up to 12 MW/m 2 could be removed from the rib-roughened surface without flow boiling which induces flow instability; but pressure drop reaches about 1.8 MPa. Correlations obtained by air-flow experiments have showed lower heat transfer performance with the water-flow conditions. The experimental apparatus was proposed for further investigation on heat transfer augmentation in very narrow channels under water-flow conditions. This report presents the evaluation results and an outline of the test apparatus. (author)

  15. Synthesis of Highly Effective Novel Graphene Oxide-Polyethylene Glycol-Polyvinyl Alcohol Nanocomposite Hydrogel For Copper Removal

    Directory of Open Access Journals (Sweden)

    Eman Serag

    2017-10-01

    Full Text Available A novel Graphene oxide-polyethylene glycol and polyvinyl alcohol (GO-PEG-PVA triple network hydrogel were prepared to remove Copper(II ion from its aqueous solution. The structures, morphologies, and properties of graphene oxide (GO, the composite GO-PEG-PVA and PEG-PVA were characterized using FTIR, X-ray diffraction, Scanning Electronic Microscope and Thermal Gravimetric analysis. A series of systematic batch adsorption experiments were conducted to study the adsorption property of GO, GO-PEG-PVA hydrogel and PEG-PVA hydrogel under different conditions (e.g. pH, contact time and Cu2+ ions concentration. The high adsorption capacity, easy regeneration, and effective adsorption–desorption results proved that the prepared GO-PEG-PVA composite hydrogel could be an effective adsorbent in removing Cu2+ ion from its aqueous solution. The maximum adsorption capacities were found to be 917, 900 and 423 mg g–1 for GO-PEG-PVA hydrogel, GO and PEG-PVA hydrogel, respectively at pH 5, 25 °C and Cu2+ ions’ concentration 500 mg l–1. The removal efficiency of the recycled GO-PEG-PVA hydrogel were 83, 81, 80 and 79% for the first four times, which proved efficient reusability.

  16. Eurasian Economic Union: A Regional Economic Hegemony Initiative

    OpenAIRE

    Serdar YILMAZ

    2017-01-01

    It can be assumed that international relations terminology has not mentioned enough about the significance of the Eurasian Economic Union in territorial as well as in economic terms during a period of growing geopolitical risks and high interdependence between the member countries and the rest. According to Kazakhstan’s President Nursultan Nazarbayev, it is truly difficult for states to overcome economic, political and security issues and therefore, states need to act together against the pro...

  17. Recent development on the synthesis of calixcrowns and their application for cesium removal from high-level liquid waste

    International Nuclear Information System (INIS)

    Zhu Xiaowen; Gao Jianxun; Wang Jianchen; Yu Bo; Song Chongli

    2002-01-01

    The synthesis, extraction properties and molecular modeling of calixcrowns in concern of cesium removal is reviewed briefly. In particular, calix [4] crown-6 and some of its derivatives have been shown to be highly selective extractants for cesium ions

  18. Highly stable and magnetically separable alginate/Fe3O4 composite for the removal of strontium (Sr) from seawater.

    Science.gov (United States)

    Hong, Hye-Jin; Jeong, Hyeon Su; Kim, Byoung-Gyu; Hong, Jeongsik; Park, In-Su; Ryu, Taegong; Chung, Kang-Sup; Kim, Hyuncheol; Ryu, Jungho

    2016-12-01

    In this study, a highly stable alginate/Fe 3 O 4 composite was synthesized, and systematically investigated for the practical application of strontium (Sr) removal in complex media, such as seawater and radioactive wastewater. To overcome the drawbacks of the use of alginate microspheres, high contents of alginic acid and Fe 3 O 4 were used to provide a more rigid structure with little swelling and facile separation, respectively. The synthesized composite was optimized for particle sizes of seawater spiked with 50 mg/L of Sr, the alginate/Fe 3 O 4 composite showed 12.5 mg/g of Sr uptake, despite the highly concentrated ions in seawater. The adsorption experiment for radio-active 90 Sr revealed a removal efficiency of 67% in real seawater, demonstrating the reliability of the alginate/Fe 3 O 4 composite. Copyright © 2016 Elsevier Ltd. All rights reserved.

  19. Efficiency of lead removal from drinking water using cationic resin Purolite

    Directory of Open Access Journals (Sweden)

    Ashour Mohammad Merganpour

    2015-01-01

    Full Text Available Background: Today, issues such as water shortage, difficulties and costs related to supplying safe water, and anomalous concentrations of heavy metals in groundwater and surface water resources, doubled the necessity of access to technical methods on removing these pollutants from water resources. Methods: In this lab study, cationic resin Purolite S-930 (with co-polymer styrene di-vinyl benzene structure was used for lead removal from drinking water containing up to 22 μg/L. Using statistical analysis and designing a full factorial experiment are the most important effective parameters on lead removal obtained through ion exchange process. Results: Analysis of response and interaction parameters of ion exchange showed that the resin column height has maximum and pH value has minimum effect on the efficiency of lead removal from aquatic environment. Trinary interaction of “effective size, flow rate, resin column high” has the most important for lead removal efficiency in this system. So the maximum efficiency was obtained at the mesh = 40, bed height =1.6 meter, and pH= 6.5. At the best operation conditions, ability to remove 95.42% of lead concentration can be achieved. Conclusion: Using the resin Purolite S-930 during 21-day service with 91.12% of mean lead removal ratio from drinking water is an economic and technical feasibility.

  20. The influence of removing sizing on strength and stiffness of conventional and high modulus E-glass fibres

    DEFF Research Database (Denmark)

    Petersen, Helga Nørgaard; Kusano, Yukihiro; Brøndsted, Povl

    2016-01-01

    Two types of E-glass fibres, a conventional and a high modulus where the last one in the following will be denoted as ECR-glass fibre, were investigated regarding density, diameter, stiffness and strength. The fibres were analysed as pristine and after sizing removal treatments. The sizing was re...

  1. Technology assessment HTR. Part 3. Economics of new concept of the modular High Temperature Reactor

    International Nuclear Information System (INIS)

    Lako, P.

    1996-06-01

    In this study the economic feasibility of new concepts of the High Temperature Reactor were investigated. These new concepts are characterized as inherently safe. The different concepts were used as industrial heat/power reactors and compared with a gas fired Steam and Gas turbine installation. The best economic advantages are offered by a HTR with a Thorium/Uranium cycle as compared with a gas fired steam- and gas turbine. 6 figs, 9 tabs, 21 refs

  2. Economic incentives for oak woodland preservation and conservation

    Science.gov (United States)

    Rosi Dagit; Cy Carlberg; Christy Cuba; Thomas Scott

    2015-01-01

    Numerous ordinances and laws recognize the value of oak trees and woodlands, and dictate serious and expensive consequences for removing or harming them. Unfortunately, the methods used to calculate these values are equally numerous and often inconsistent. More important, these ordinances typically lack economic incentives to avoid impacts to oak woodland values...

  3. Boron removal from geothermal waters by electrocoagulation

    Energy Technology Data Exchange (ETDEWEB)

    Yilmaz, A. Erdem [Atatuerk University, Faculty of Engineering, Department of Environmental Engineering., 25240 Erzurum (Turkey)], E-mail: aerdemy@atauni.edu.tr; Boncukcuoglu, Recep [Atatuerk University, Faculty of Engineering, Department of Environmental Engineering., 25240 Erzurum (Turkey); Kocakerim, M. Muhtar [Atatuerk University, Faculty of Engineering, Department of Chemical Engineering, 25240 Erzurum (Turkey); Yilmaz, M. Tolga; Paluluoglu, Cihan [Atatuerk University, Faculty of Engineering, Department of Environmental Engineering., 25240 Erzurum (Turkey)

    2008-05-01

    Most of the geothermal waters in Turkey contain extremely high concentration of boron when they are used for irrigation. The use of geothermal waters for irrigation can results in excess amount deposition of boron in soil. On the other hand, a minimal boron concentration is required for irrigational waters. In this study, electrocoagulation (EC) was selected as a treatment process for the removal of boron from thermal waters obtained from Ilica-Erzurum in Turkey. Current density (CD), pH of solution and temperature of solution were selected as operational parameters. The results showed that boron removal efficiency increased from pH 4.0 to 8.0 and decreased at pH 10.0. Although boron removal efficiency was highest at pH 8.0, energy consumption was very high at this pH value compared to other pH intervals. Boron removal efficiency reached to 95% with increasing current density from 1.5 to 6.0 mA/cm{sup 2}, but energy consumption was also increased in this interval. At higher temperatures of solution, such as 313 and 333 K, boron removal efficiency increased. At optimum conditions, boron removal efficiency in geothermal water reached up to 95%.

  4. Boron removal from geothermal waters by electrocoagulation

    International Nuclear Information System (INIS)

    Yilmaz, A. Erdem; Boncukcuoglu, Recep; Kocakerim, M. Muhtar; Yilmaz, M. Tolga; Paluluoglu, Cihan

    2008-01-01

    Most of the geothermal waters in Turkey contain extremely high concentration of boron when they are used for irrigation. The use of geothermal waters for irrigation can results in excess amount deposition of boron in soil. On the other hand, a minimal boron concentration is required for irrigational waters. In this study, electrocoagulation (EC) was selected as a treatment process for the removal of boron from thermal waters obtained from Ilica-Erzurum in Turkey. Current density (CD), pH of solution and temperature of solution were selected as operational parameters. The results showed that boron removal efficiency increased from pH 4.0 to 8.0 and decreased at pH 10.0. Although boron removal efficiency was highest at pH 8.0, energy consumption was very high at this pH value compared to other pH intervals. Boron removal efficiency reached to 95% with increasing current density from 1.5 to 6.0 mA/cm 2 , but energy consumption was also increased in this interval. At higher temperatures of solution, such as 313 and 333 K, boron removal efficiency increased. At optimum conditions, boron removal efficiency in geothermal water reached up to 95%

  5. Enhanced Biological Phosphorus Removal: Metabolic Insights and Salinity Effects

    OpenAIRE

    Welles, L.

    2015-01-01

    Enhanced biological phosphorus removal (EBPR) is a biological process for efficient phosphate removal from wastewaters through intracellular storage of polyphosphate by polyphosphate-accumulating organisms (PAO) and subsequent removal of PAO from the system through wastage of sludge. In comparison to physical and chemical phosphorus removal processes, the biological process has several advantages such as high removal efficiency, low cost, and no chemical sludge production, but disturbances an...

  6. DOE/NETL's phase II mercury control technology field testing program: preliminary economic analysis of activated carbon injection.

    Science.gov (United States)

    Jones, Andrew P; Hoffmann, Jeffrey W; Smith, Dennis N; Feeley, Thomas J; Murphy, James T

    2007-02-15

    Based on results of field testing conducted by the U.S. Department of Energy's National Energy Technology Laboratory (DOE/NETL), this article provides preliminary costs for mercury control via conventional activated carbon injection (ACI), brominated ACI, and conventional ACI coupled with the application of a sorbent enhancement additive (SEA) to coal prior to combustion. The economic analyses are reported on a plant-specific basis in terms of the cost required to achieve low (50%), mid (70%), and high (90%) levels of mercury removal "above and beyond" the baseline mercury removal achieved by existing emission control equipment. In other words, the levels of mercury control are directly attributable to ACI. Mercury control costs via ACI have been amortized on a current dollar basis. Using a 20-year book life, levelized costs for the incremental increase in cost of electricity (COE), expressed in mills per kilowatt-hour (mills/kWh), and the incremental cost of mercury control, expressed in dollars per pound of mercury removed ($/lb Hg removed), have been calculated for each level of ACI mercury control. For this analysis, the increase in COE varied from 0.14 mills/kWh to 3.92 mills/kWh. Meanwhile, the incremental cost of mercury control ranged from $3810/lb Hg removed to $166000/lb Hg removed.

  7. Adsorption removal of Sr by Barium impregnated 4A Zeolite(BaA) from high radioactive seawater waste

    Energy Technology Data Exchange (ETDEWEB)

    Lee, Eil Hee; Lee, Keun Young; Kim, Kwang Wook; Kim, Ik Soo; Chung, Dong Yong; Moon, Jei Kwon; Choi, Jong Won [Korea Atomic Energy Research Institute, Daejeon (Korea, Republic of)

    2016-06-15

    This study investigated the removal of Sr, which was one of the high radioactive nuclides, by adsorption with Barium (Ba) impregnated 4A zeolite (BaA) from high-radioactive seawater waste (HSW). Adsorption of Sr by BaA (BaA-Sr), in the impregnated Ba concentration of above 20.2wt%, was decreased by increasing the impregnated Ba concentration, and the impregnated Ba concentration was suitable at 20.2wt%. The BaA-Sr adsorption was added to the co-precipitation of Sr with BaSO4 precipitation in the adsorption of Sr by 4A (4A-Sr) within BaA. Thus, it was possible to remove Sr more than 99% at m/V (adsorbent weight/solution volume)=5 g/L for BaA and m/V >20 g/L for 4A, respectively, in the Sr concentration of less than 0.2 mg/L (actual concentration level of Sr in HSW). It shows that BaA-Sr adsorption is better than 4A-Sr adsorption in for the removal capacity of Sr per unit gram of adsorbent, and the reduction of the secondary solid waste generation (spent adsorbent etc.). Also, BaA-Sr adsorption was more excellent removal capacity of Sr in the seawater waste than distilled water. Therefore, it seems to be effective for the direct removal of Sr from HSW. On the other hand, the adsorption of Cs by BaA (BaA-Cs) was mainly performed by 4A within BaA. Accordingly, it seems to be little effect of impregnated Ba into BaA. Meanwhile, BaA-Sr adsorption kinetics could be expressed the pseudosecond order rate equation. By increasing the initial Sr concentrations and the ratios of V/m, the adsorption rate constants (k2) were decreased, but the equilibrium adsorption capacities (qe) were increasing. However, with increasing the temperature of solution, k2 was conversely increased, and qe was decreased. The activation energy of BaA-Sr adsorption was 38 kJ/mol. Thus, the chemical adsorption seems to be dominant rather than physical adsorption, although it is not a chemisorption with strong bonding form.

  8. Further evidence on the relationship between economic freedom and economic growth

    NARCIS (Netherlands)

    De Haan, J; Siermann, CLJ

    Often it is maintained that economic freedom may further high levels of economic growth. Using various measures of economic freedom constructed by Scully and Slottje, the robustness of this relationship is examined. Both direct and indirect effects of lack of liberties are analysed. Our main

  9. Economic Justification of Concentrating Solar Power in High Renewable Energy Penetrated Power Systems

    Energy Technology Data Exchange (ETDEWEB)

    Hodge, Brian S [National Renewable Energy Laboratory (NREL), Golden, CO (United States); Kroposki, Benjamin D [National Renewable Energy Laboratory (NREL), Golden, CO (United States); Du, Ershun [Tsinghua University; Zhang, Ning [Tsinghua University; Kang, Chongqing [Tsinghua University; Xia, Qing [Tsinghua University

    2018-04-24

    Concentrating solar power (CSP) plants are able to provide both renewable energy and operational flexibility at the same time due to its thermal energy storage (TES). It is ideal generation to power systems lacking in flexibility to accommodate variable renewable energy (VRE) generation such as wind power and photovoltaics. However, its investment cost currently is too high to justify its benefit in terms of providing renewable energy only. In this paper we evaluate the economic benefit of CSP in high renewable energy penetrated power systems from two aspects: generating renewable energy and providing operational flexibility to help accommodating VRE. In order to keep the same renewable energy penetration level during evaluation, we compare the economic costs between the system with a high share of VRE and another in which some part of the VRE generation is replaced by CSP generation. The generation cost of a power system is analyzed through chronological operation simulation over a whole year. The benefit of CSP is quantified into two parts: (1) energy benefit - the saving investment of substituted VRE generation and (2) flexibility benefit - the reduction in operating cost due to substituting VRE with CSP. The break-even investment cost of CSP is further discussed. The methodology is tested on a modified IEEE RTS-79 system. The economic justifications of CSP are demonstrated in two practical provincial power systems with high penetration of renewable energy in northwestern China, Qinghai and Gansu, where the former province has massive inflexible thermal power plants but later one has high share of flexible hydro power. The results suggest that the CSP is more beneficial in Gansu system than in Qinghai. The levelized benefit of CSP, including both energy benefit and flexibility benefit, is about 0.177-0.191 $/kWh in Qinghai and about 0.238-0.300 $/kWh in Gansu, when replacing 5-20% VRE generation with CSP generation.

  10. Phosphorous removal from aqueous solution can be enhanced through the calcination of lime sludge.

    Science.gov (United States)

    Bal Krishna, K C; Niaz, Mohamed R; Sarker, Dipok C; Jansen, Troy

    2017-09-15

    Water treatment plants generate an enormous amount of the sludge which is normally treated as waste. In the recent past, many investigations have been focused on developing an economical adsorbent using water treatment sludge to remove phosphorous (P) from aqueous solutions. However, the great extents of the studies have been limited in the use of alum- and iron-based sludges. This study, therefore, investigated the P removal performance of the calcined lime sludge. Calcined lime sludge at 700 °C significantly enhanced the P removal efficiency whereas marginal improvement was noted when the sludge calcined at 400 °C was tested. With increase P removal efficiency, final pH values of the solution also significantly increased. P removal efficiency of the calcined sludge decreased with increasing the initial P concentrations. However, the removal efficiency could be improved by increasing the weight of the sludge. Further analysis demonstrated that P removal trend followed both pseudo-second order and diffusion-chemisorption kinetics signifying the P removal is potentially due to a multi-mechanistic reaction in which, the process is controlled by intra-particle diffusion followed by chemisorptions. Copyright © 2017 Elsevier Ltd. All rights reserved.

  11. [Influence of removing iodized salt on children's goiter status in areas with high iodine in drinking water].

    Science.gov (United States)

    Lu, Shengmin; Xu, Dong; Wang, Yuchun; Du, Yonggui; Jia, Lihui; Liang, Suoli

    2015-05-01

    To explore the changes of goiter prevalence of children living in areas with high iodine in drinking water after removing iodized salt from their diet. Three towns with median water iodine of 150 - 300 μg/L were selected randomly in Hengshui city of Hebei province of China. A total of 452 and 459 children in the 3 towns were randomly selected to measure thyroid volume by ultrasound before and after removing iodized salt, respectively. Their goiter status was judged using the criteria of age-specific thyroid volume recommended by the WHO. After removing iodized salt, the overall goiter prevalence in the three towns significantly decreased from 24.56% (111/452) to 5.88% (27/459) (P < 0.01). The goiter prevalence in 8, 9 and 10 year-old children decreased respectively from 33.70% (31/92), 23.32% (45/193) and 20.96% (35/167) to 6.10% (10/164), 5.52% (9/163) and 6.06% (8/132). The goiter prevalence in boys and girls decreased from 27.05% (66/244) and 21.63% (45/208 ) to 6.66% (15/226 ) and 5.15% (12/233), respectively. The decreases in children's goiter prevalence across gender and age group were all significant. Children's goiter prevalence decreased significantly after removing iodized salt from their diet for about one and half years in the HIA in Hebei province.

  12. Synthesis, characterization and dye removal ability of high capacity polymeric adsorbent: Polyaminoimide homopolymer

    Energy Technology Data Exchange (ETDEWEB)

    Mahmoodi, Niyaz Mohammad, E-mail: nm_mahmoodi@aut.ac.ir [Department of Environmental Research, Institute for Color Science and Technology, Tehran (Iran, Islamic Republic of); Najafi, Farhood [Department of Resin and Additives, Institute for Color Science and Technology, Tehran (Iran, Islamic Republic of); Khorramfar, Shooka [Department of Environmental Research, Institute for Color Science and Technology, Tehran (Iran, Islamic Republic of); Textile Engineering Department, Amirkabir University of Technology, Tehran (Iran, Islamic Republic of); Amini, Farrokhlegha [Department of Environmental Research, Institute for Color Science and Technology, Tehran (Iran, Islamic Republic of); Arami, Mokhtar [Textile Engineering Department, Amirkabir University of Technology, Tehran (Iran, Islamic Republic of)

    2011-12-30

    Highlights: Black-Right-Pointing-Pointer Polyaminoimide homopolymer (PAIHP) was synthesized and characterized. Black-Right-Pointing-Pointer Kinetics data followed pseudo-second order kinetic model. Black-Right-Pointing-Pointer Isotherm data followed Langmuir isotherm. Black-Right-Pointing-Pointer Q{sub 0} for DR31, DR23, DB22 and AB25 was 6667, 5555, 9090 and 5882 mg/g, respectively. Black-Right-Pointing-Pointer PAIHP was regenerated at pH 12. - Abstract: In this paper, polyaminoimide homopolymer (PAIHP) was synthesized and its dye removal ability was investigated. Physical characteristics of PAIHP were studied using Fourier transform infrared (FTIR) and scanning electron microscopy (SEM). Direct Red 31 (DR31), Direct Red 23 (DR23), Direct Black 22 (DB22) and Acid Blue 25 (AB25) were used as model compounds. The kinetic and isotherm of dye adsorption were studied. The effect of operational parameter such as adsorbent dosage, pH and salt on dye removal was evaluated. Adsorption kinetic of dyes followed pseudo-second order kinetics. The maximum dye adsorption capacity (Q{sub 0}) of PAIHP was 6667 mg/g, 5555 mg/g, 9090 mg/g and 5882 mg/g for DR31, DR23, DB22 and AB25, respectively. It was found that adsorption of DR31, DR23, DB22 and AB25 onto PAIHP followed with Langmuir isotherm. Dye desorption tests (adsorbent regeneration) showed that the maximum dye release of 90% for DR31, 86% for DR23, 87% for DB22 and 90% for AB25 were achieved in aqueous solution at pH 12. The results showed that the PAIHP as a polymeric adsorbent with high dye adsorption capacity might be a suitable alternative to remove dyes from colored wastewater.

  13. Microporous nano-MgO/diatomite ceramic membrane with high positive surface charge for tetracycline removal.

    Science.gov (United States)

    Meng, Xian; Liu, Zhimeng; Deng, Cheng; Zhu, Mengfu; Wang, Deyin; Li, Kui; Deng, Yu; Jiang, Mingming

    2016-12-15

    A novel microporous nano-MgO/diatomite ceramic membrane with high positive surface charge was prepared, including synthesis of precursor colloid, dip-coating and thermal decomposition. Combined SEM, EDS, XRD and XPS studies show the nano-MgO is irregularly distributed on the membrane surface or pore walls and forms a positively charged nano coating. And the nano-MgO coating is firmly attached to the diatomite membrane via SiO chemical bond. Thus the nano-MgO/diatomite membrane behaves strong electropositivity with the isoelectric point of 10.8. Preliminary filtration tests indicate that the as-prepared nano-MgO/diatomite membrane could remove approximately 99.7% of tetracycline in water through electrostatic adsorption effect. The desirable electrostatic property enables the nano-MgO/diatomite membrane to be a candidate for removal of organic pollutants from water. And it is convinced that there will be a great application prospect of charged ceramic membrane in water treatment field. Copyright © 2016 Elsevier B.V. All rights reserved.

  14. ECONOMIC REASONING MAXIMUM SLOPE IN DESIGN HIGH-SPEED LINES

    Directory of Open Access Journals (Sweden)

    CHERNYSHOVA O. S.

    2016-04-01

    Full Text Available Raising of problem The worldwide design standards high-speed lines are somewhat different. This is due to several reasons: different levels of design speed, differences of characteristics of rolling stock and, in particular, the features of the design plan and longitudinal profile, that are associated primarily with the conditions of the relief. In the design of high-speed railways in Ukraine should take into account these features and determine what the maximum slope values can be used in difficult conditions, as well as how it will affect the operational and capital costs. Purpose. To determine the optimal design parameters of the longitudinal profile. Conclusion. The results are based not only on technical, but also economic indicators and allow the assessment of the necessary capital expenditures and expected cost of the railway in the future. Analytical dependences, to predict the expected operating costs of the railway, depending on the maximum slope, its length and the total length of the section.

  15. Study on engineering economics of China high-level radioactive waste geological disposal

    International Nuclear Information System (INIS)

    Qu Jun; Guo Zongzhi; Yang Lirong; Hu Jiang

    2012-01-01

    In this paper, based on the research and analysis about the repository construction cost of the European, US and Japan, together with the concept design pattern of China's high level radioactive waste repository, the preliminary economic analysis of China is presented. Meanwhile, combining with China's nuclear power development layout and picking-up policy of spent fuel fund, the preliminary measurement concerning the capital resource of high level radioactive waste disposal is implemented, which contribute to the conclusion initiatively that the spent fuel fund could meet the need of the financial demand of disposal cost. (authors)

  16. TMI-2 reactor-vessel head removal and damaged-core-removal planning

    International Nuclear Information System (INIS)

    Logan, J.A.; Hultman, C.W.; Lewis, T.J.

    1982-01-01

    A major milestone in the cleanup and recovery effort at TMI-2 will be the removal of the reactor vessel closure head, planum, and damaged core fuel material. The data collected during these operations will provide the nuclear power industry with valuable information on the effects of high-temperature-dissociated coolant on fuel cladding, fuel materials, fuel support structural materials, neutron absorber material, and other materials used in reactor structural support components and drive mechanisms. In addition, examination of these materials will also be used to determine accident time-temperature histories in various regions of the core. Procedures for removing the reactor vessel head and reactor core are presented

  17. Hydroxyl-Containing Aromatic Polyimides for Carbon Dioxide Removal from Natural Gas

    KAUST Repository

    Alaslai, Nasser Y.

    2017-10-01

    Natural gas is among the most dominant resources to provide energy supplies and Saudi Arabia ranks among the top 5 producers worldwide. However, prior to use of methane, natural gas has to be treated to remove other feed gas components, such as H2O, CO2, H2S, N2 and C2+ hydrocarbons. Most NG fields in KSA contain about 10 mol% carbon dioxide that has to be reduced to less than 2 mol% for pipeline delivery. The conventional unit operations for natural gas separations, that is, molecular sieves, amine absorption, cryogenic distillation, and turbo expansion exhibit some disadvantages in terms of economics, operational flexibility or system footprint. One of the most attractive alternative is membrane technology in either standalone- or hybrid system configuration. Currently, the only two membrane materials used in industrial natural gas applications are cellulose acetate and polyimide, which have moderate permeability and fairly low selectivity when tested under realistic industrial conditions. The goal for future research is to develop unique polymeric membranes, which can at least partially replace conventional gas processing in future natural gas projects. This will support global economics and specifically the economy of Saudi Arabia. Newly developed polymeric materials must meet certain criteria to be used on a commercial scale. These criteria include: (i) high permeability and selectivity, (ii) processability into thin films, (iii) mechanical and thermal stability, and (iv) chemical stability against feed gas components. This project focused on the removal of carbon dioxide from natural gas by developing and characterizing functionalized aromatic polyimide membrane materials that exhibit very high selectivity under aggressive mixed-gas conditions. 6FDA-DAR demonstrated a mixed-gas CO2/CH4 selectivity of 78 at a CO2 partial pressure of 10 bar with no pronounced indication of plasticization. Combining hydroxyl- and carboxyl groups in a miscible polyimide blend led

  18. Potential use of maize waste for the removal of Pb(II) from aqueous solution

    CSIR Research Space (South Africa)

    Okonkwo, J

    2006-09-01

    Full Text Available batch adsorption procedures. The utilization of tassels for the removal of toxic heavy metals from effluent solutions would, however, attach some economic value to this waste material. Tassel flowers were collected just prior to harvest, dried under...

  19. Preferable removal of phosphate from water using hydrous zirconium oxide-based nanocomposite of high stability

    International Nuclear Information System (INIS)

    Chen, Liang; Zhao, Xin; Pan, Bingcai; Zhang, Weixian; Hua, Ming; Lv, Lu; Zhang, Weiming

    2015-01-01

    Highlights: • The nanocomposite HZO-201 was stable under varying solution chemistry. • HZO-201 exhibited preferable phosphate removal over other ubiquitous anions. • Selective sorption mechanism was probed and discussed. • HZO-201 could be regenerated for cyclic use with constant efficiency. - Abstract: In this study, we employed a new nanocomposite adsorbent HZO-201, which featured high stability under varying solution chemistry, for preferable removal of phosphate from synthetic solution and a real effluent. An anion exchange resin (D-201) was employed as the host of HZO-201, where nano-hydrous zirconium oxide (HZO) was encapsulated as the active species. D-201 binds phosphate through nonspecific electrostatic affinity, whereas the loaded HZO nanoparticles capture phosphate through formation of the inner-sphere complexes. Quantitative contribution of both species to phosphate adsorption was predicted based on the double-Langmuir model. Preferable removal of phosphate by HZO-201 was observed in the presence of the competing anions at higher levels (Cl − , NO 3 − , SO 4 2− , HCO 3 − ). Fixed-bed adsorption indicated that the effective volume capacity of a synthetic water (2.0 mg P-PO 4 3− /L) by using HZO-201 was ∼1600 BV in the first run (<0.5 mg P-PO 4 3− /L), comparable to Fe(III)-based nanocomposite HFO-201 (∼1500 BV) and much larger than D-201 (<250 BV). The exhausted HZO-201 can be in situ regenerated by using a binary NaOH–NaCl solution for cyclic runs, whether fed with the synthetic solution or real effluent. In general, HZO-201 is a promising alternative to Fe(III)-based adsorbents for trace phosphate removal from effluent particularly at acidic pH

  20. Boron removal efficiency from Red Sea water using different SWRO/BWRO membranes

    KAUST Repository

    Rahmawati, Karina; Ghaffour, NorEddine; Aubry, Cyril; Amy, Gary L.

    2012-01-01

    Seawater reverse osmosis (SWRO) desalination process provides high quality of fresh water. However, due to some operational constraints mainly scaling control some trace contaminant removal, such as acceptable boron concentration, cannot be achieved in a single pass SWRO system. The objective of this study was to investigate the efficiency of five difference reverse osmosis (RO) membranes (seawater SW and brackish water BW) provided by different manufacturers for boron removal. RO experiments using pretreated real Red Sea water were conducted in parallel to compare membrane performance under the same operating conditions. As expected, results showed that boron rejection increased as the feed pH increased. This was caused by dissociation of boric acid to negatively charged borate ions and more negatively charged membrane surface at elevated pH which enhanced boron rejection. Single pass RO system, with and without elevating the pH, may not be sufficient for two reasons. First, boron concentration in permeate does not fulfill local regulations (<0.5ppm). Second, severe scaling occurs due to operation in alkaline condition, since Ca 2+ and Mg 2+ concentrations are still high to cause salts precipitation. Techno-economical study was performed to select the best configuration and membrane giving the highest performance in terms of boron and TDS rejections and energy consumption. © 2012 Elsevier B.V.

  1. Boron removal efficiency from Red Sea water using different SWRO/BWRO membranes

    KAUST Repository

    Rahmawati, Karina

    2012-12-01

    Seawater reverse osmosis (SWRO) desalination process provides high quality of fresh water. However, due to some operational constraints mainly scaling control some trace contaminant removal, such as acceptable boron concentration, cannot be achieved in a single pass SWRO system. The objective of this study was to investigate the efficiency of five difference reverse osmosis (RO) membranes (seawater SW and brackish water BW) provided by different manufacturers for boron removal. RO experiments using pretreated real Red Sea water were conducted in parallel to compare membrane performance under the same operating conditions. As expected, results showed that boron rejection increased as the feed pH increased. This was caused by dissociation of boric acid to negatively charged borate ions and more negatively charged membrane surface at elevated pH which enhanced boron rejection. Single pass RO system, with and without elevating the pH, may not be sufficient for two reasons. First, boron concentration in permeate does not fulfill local regulations (<0.5ppm). Second, severe scaling occurs due to operation in alkaline condition, since Ca 2+ and Mg 2+ concentrations are still high to cause salts precipitation. Techno-economical study was performed to select the best configuration and membrane giving the highest performance in terms of boron and TDS rejections and energy consumption. © 2012 Elsevier B.V.

  2. Measurement and removal of cladding light in high power fiber systems

    Science.gov (United States)

    Walbaum, Till; Liem, Andreas; Schreiber, Thomas; Eberhardt, Ramona; Tünnermann, Andreas

    2018-02-01

    The amount of cladding light is important to ensure longevity of high power fiber components. However, it is usually measured either by adding a cladding light stripper (and thus permanently modifying the fiber) or by using a pinhole to only transmit the core light (ignoring that there may be cladding mode content in the core area). We present a novel noninvasive method to measure the cladding light content in double-clad fibers based on extrapolation from a cladding region of constant average intensity. The method can be extended to general multi-layer radially symmetric fibers, e.g. to evaluate light content in refractive index pedestal structures. To effectively remove cladding light in high power systems, cladding light strippers are used. We show that the stripping efficiency can be significantly improved by bending the fiber in such a device and present respective experimental data. Measurements were performed with respect to the numerical aperture as well, showing the dependency of the CLS efficiency on the NA of the cladding light and implying that efficiency data cannot reliably be given for a certain fiber in general without regard to the properties of the guided light.

  3. Carbon dioxide removal and the futures market

    Science.gov (United States)

    Coffman, D.'Maris; Lockley, Andrew

    2017-01-01

    Futures contracts are exchange-traded financial instruments that enable parties to fix a price in advance, for later performance on a contract. Forward contracts also entail future settlement, but they are traded directly between two parties. Futures and forwards are used in commodities trading, as producers seek financial security when planning production. We discuss the potential use of futures contracts in Carbon Dioxide Removal (CDR) markets; concluding that they have one principal advantage (near-term price security to current polluters), and one principal disadvantage (a combination of high price volatility and high trade volume means contracts issued by the private sector may cause systemic economic risk). Accordingly, we note the potential for the development of futures markets in CDR, but urge caution about the prospects for market failure. In particular, we consider the use of regulated markets: to ensure contracts are more reliable, and that moral hazard is minimised. While regulation offers increased assurances, we identify major insufficiencies with this approach—finding it generally inadequate. In conclusion, we suggest that only governments can realistically support long-term CDR futures markets. We note existing long-term CDR plans by governments, and suggest the use of state-backed futures for supporting these assurances.

  4. Removal of Pharmaceutical Compounds from Hospital Wastewaters Using Nanomaterials: A Review

    Directory of Open Access Journals (Sweden)

    Hasan Bagheri

    2016-06-01

    Full Text Available Over the past few years, residual pharmaceuticals (antibiotics, anticonvulsants, antipyretics drugs, hormones have begun to be considered as emerging environmental pollutants due to their continuous input and persistence to aquatic ecosystem even at low concentrations. Therefore, the development of efficient, cost-effective, and stable methods and materials for the wastewaters treatment have gained more recognition in recent years. In the path of meeting these developments, nanomaterials have attracted much attention as economical, convenient and ecofriendly tools for removing of pharmaceuticals from the hospital wastewaters because of their unique properties. The present review deals with recent advances in removal and/or destruction of residual pharmaceutical in wastewater samples using nanomaterials including metal nanoparticles, carbon nanotubes and nanofilters. In spite of using a variety of nanomaterials to remove the residual of pharmaceuticals, there is still a dearth of successful applicability of them in industrial processes. Therefore, some defects of nanomaterials to be used for the removal of pharmaceutical contaminate in environmental samples and their impacts on human health and environment is briefly discussed.

  5. Milk removal

    OpenAIRE

    Ferneborg, Sabine

    2016-01-01

    Milk from dairy cows is a staple dietary component for humans all over the world. Regardless of whether milk is consumed in its purest, unaltered form or as high-end products such as fine cheese or ice cream, it needs to be of high quality when taken from the cow, produced at a low price and produced in a system that consider aspects such as animal health, animal welfare and sustainability. This thesis investigated the role of milk removal and the importance of residual milk on milk yield...

  6. Plant for removing radioactive rare gases

    International Nuclear Information System (INIS)

    An, Buzai; Kanazawa, Toshio

    1977-01-01

    The outline of the pilot plant to remove and recover radioactive rare gases generated from nuclear power plants, reprocessing installations for nuclear fuel, nuclear research installations, etc. is described below. Among the studies of various processes such as liquefaction and distillation, absorption into solvents, active carbon adsorption, diaphragm method, etc., the liquefaction and distillation process by rectification at low temperature has been positively developed. It is in the stage of practical application for removing rare gases in waste gases from reprocessing and nuclear power plants. This is the process with high safety and excellent rare gas removing capability. Further research and development have been also made for selective adsorption and desorption method at low temperature which is very efficient as there is no release of long life nuclides such as Krypton-85. Rare gases recovered by the above mentioned removal systems must be stored safely for a long time as their half lives are long and specific radioactivities are high. The study has been made continuously on the storage methods including adsorption in cylinders and remotely automatically sealing storing system. (Kobatake, H.)

  7. Arsenic removal from a high-arsenic wastewater using in situ formed Fe-Mn binary oxide combined with coagulation by poly-aluminum chloride

    International Nuclear Information System (INIS)

    Wu Kun; Wang Hongjie; Liu Ruiping; Zhao Xu; Liu Huijuan; Qu Jiuhui

    2011-01-01

    In this study, in situ formed Fe-Mn binary oxide (FMBO) was applied to treat a practical high-arsenic wastewater (5.81 mg/L). FMBO exhibited a remarkable removal capacity towards both As(III) and As(V), achieving a removal efficiency over 99.5%. However, the FMBO-As particles could not be sufficiently separated by gravitational sedimentation due to their low sizes and negative charges, as being indicated from laser particle size and zeta-potential analysis. Thus, poly-aluminum chloride (PACl) was introduced as a coagulant to facilitate the solid-liquid separation, and it remarkably improved As removal efficiencies. Results of scanning electron microscope (SEM) revealed that PACl contributed to the formation of precipitates with larger sizes and compact surfaces, which was favorable to sedimentation. Moreover, residual soluble As was removed by PACl hydroxides. The optimum dosages of FMBO and PACl were determined to be 60 mg/L and 80 mg/L, respectively. Additionally, the secondary pollution was minimized in FMBO-PACl process. Based on these bench-scale results, a full-scale treatment process was proposed to successfully treat 40,000 m 3 of high-arsenic wastewater in a municipal wastewater treatment plant (MWWTP). The average As concentration in the effluent was about 0.015 mg/L. FMBO-PACl process showed the advantages of high effectiveness, low cost, safety, and ease for operation.

  8. Optimizing nitrate removal in woodchip beds treating aquaculture effluents

    DEFF Research Database (Denmark)

    von Ahnen, Mathis; Pedersen, Per Bovbjerg; Hoffmann, Carl Christian

    2016-01-01

    Nitrate is typically removed from aquaculture effluents using heterotrophic denitrification reactors. Heterotrophic denitrification reactors, however, require a constant input of readily available organic carbon (C) sources which limits their application in many aquaculture systems for practical...... and/or economic reasons.A potential alternative technology for removing nitrate currently applied for treating surface and drainage water is based on using wood by-products as a carbon source for denitrification. Using lab-scale horizontal-flow woodchip filters, the current study investigated...... the potential of optimizing woodchip reactors for treating aquaculture effluent. A central composite design (CCD) was applied to assess the effects of simultaneously changing the empty bed contact time (EBCTs of 5.0-15.0 h; corresponding to theoretical hydraulic retention times of 3.3-9.9 h) and bicarbonate...

  9. High-performance workplace practices in nursing homes: an economic perspective.

    Science.gov (United States)

    Bishop, Christine E

    2014-02-01

    To develop implications for research, practice and policy, selected economics and human resources management research literature was reviewed to compare and contrast nursing home culture change work practices with high-performance human resource management systems in other industries. The organization of nursing home work under culture change has much in common with high-performance work systems, which are characterized by increased autonomy for front-line workers, self-managed teams, flattened supervisory hierarchy, and the aspiration that workers use specific knowledge gained on the job to enhance quality and customization. However, successful high-performance work systems also entail intensive recruitment, screening, and on-going training of workers, and compensation that supports selective hiring and worker commitment; these features are not usual in the nursing home sector. Thus despite many parallels with high-performance work systems, culture change work systems are missing essential elements: those that require higher compensation. If purchasers, including public payers, were willing to pay for customized, resident-centered care, productivity gains could be shared with workers, and the nursing home sector could move from a low-road to a high-road employment system.

  10. Removal of highly elevated nitrate from drinking water by pH-heterogenized heterotrophic denitrification facilitated with ferrous sulfide-based autotrophic denitrification.

    Science.gov (United States)

    Huang, Bin; Chi, Guangyu; Chen, Xin; Shi, Yi

    2011-11-01

    The performance of acetic acid-supported pH-heterogenized heterotrophic denitrification (HD) facilitated with ferrous sulfide-based autotrophic denitrification (AD) was investigated in upflow activated carbon-packed column reactors for reliable removal of highly elevated nitrate (42 mg NO(3)-Nl(-1)) in drinking water. The use of acetic acid as substrate provided sufficient internal carbon dioxide to completely eliminate the need of external pH adjustment for HD, but simultaneously created vertically heterogenized pH varying from 4.8 to 7.8 in the HD reactor. After 5-week acclimation, the HD reactor developed a moderate nitrate removal capacity with about one third of nitrate removal occurring in the acidic zone (pH 4.8-6.2). To increase the treatment reliability, acetic acid-supported HD was operated under 10% carbon limitation to remove >85% of nitrate, and ferrous sulfide-based AD was supplementally operated to remove residual nitrate and formed nitrite without excess of soluble organic carbon, nitrite or sulfate in the final effluent. Copyright © 2011 Elsevier Ltd. All rights reserved.

  11. Technical-economic modelling of an aluminium high pressure die casting system for automotive parts fabrication

    International Nuclear Information System (INIS)

    Faura, F.

    1997-01-01

    In the present paper a technical-economic model for an aluminium high pressure die casting system has been developed. In order to obtain the necessary data for correlations utilized by the model, has been analyzed the production systems of companies that use these processes. This has allowed to determine the most important technological variables that affect to the economical aspect of the process. A computer application has been developed which allows to explore easily the influence of different system parameters. (Author) 12 refs

  12. Enabling fast charging – Infrastructure and economic considerations

    International Nuclear Information System (INIS)

    Burnham, Andrew; Dufek, Eric J.; Stephens, Thomas; Francfort, James; Michelbacher, Christopher

    2017-01-01

    The ability to charge battery electric vehicles (BEVs) on a time scale that is on par with the time to fuel an internal combustion engine vehicle (ICEV) would remove a significant barrier to the adoption of BEVs. However, for viability, fast charging at this time scale needs to also occur at a price that is acceptable to consumers. Therefore, the cost drivers for both BEV owners and charging station providers are analyzed. In addition, key infrastructure considerations are examined, including grid stability and delivery of power, the design of fast charging stations and the design and use of electric vehicle service equipment. Each of these aspects have technical barriers that need to be addressed, and are directly linked to economic impacts to use and implementation. Here, this discussion focuses on both the economic and infrastructure issues which exist and need to be addressed for the effective implementation of fast charging up to 350 kW. In doing so, it has been found that there is a distinct need to effectively manage the intermittent, high power demand of fast charging, strategically plan infrastructure corridors, and to further understand the cost of operation of charging infrastructure and BEVs.

  13. A Single-Molecule Propyne Trap: Highly Efficient Removal of Propyne from Propylene with Anion-Pillared Ultramicroporous Materials.

    Science.gov (United States)

    Yang, Lifeng; Cui, Xili; Yang, Qiwei; Qian, Siheng; Wu, Hui; Bao, Zongbi; Zhang, Zhiguo; Ren, Qilong; Zhou, Wei; Chen, Banglin; Xing, Huabin

    2018-03-01

    Propyne/propylene (C 3 H 4 /C 3 H 6 ) separation is a critical process for the production of polymer-grade C 3 H 6 . However, optimization of the structure of porous materials for the highly efficient removal of C 3 H 4 from C 3 H 6 remains challenging due to their similar structures and ultralow C 3 H 4 concentration. Here, it is first reported that hybrid ultramicroporous materials with pillared inorganic anions (SiF 6 2- = SIFSIX, NbOF 5 2- = NbOFFIVE) can serve as highly selective C 3 H 4 traps for the removal of trace C 3 H 4 from C 3 H 6 . Especially, it is revealed that the pyrazine-based ultramicroporous material with square grid structure for which the pore shape and functional site disposition can be varied in 0.1-0.5 Å scale to match both the shape and interacting sites of guest molecule is an interesting single-molecule trap for C 3 H 4 molecule. The pyrazine-based single-molecule trap enables extremely high C 3 H 4 uptake under ultralow concentration (2.65 mmol g -1 at 3000 ppm, one C 3 H 4 per unit cell) and record selectivity over C 3 H 6 at 298 K (>250). The single-molecule binding mode for C 3 H 4 within ultramicroporous material is validated by X-ray diffraction experiments and modeling studies. The breakthrough experiments confirm that anion-pillared ultramicroporous materials set new benchmarks for the removal of ultralow concentration C 3 H 4 (1000 ppm on SIFSIX-3-Ni, and 10 000 ppm on SIFSIX-2-Cu-i) from C 3 H 6 . © 2018 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

  14. Impacts of removing fuel import subsidies in Nigeria on poverty

    International Nuclear Information System (INIS)

    Siddig, Khalid; Aguiar, Angel; Grethe, Harald; Minor, Peter; Walmsley, Terrie

    2014-01-01

    The petroleum sector contributes substantially to the Nigerian economy; however, the potential benefits are diminished due to the existence of significant subsidies on imports of petroleum products. Subsidies on imported petroleum products are considered to be an important instrument for keeping fuel prices, and hence the cost of living, low. The costs of these subsidies, however, has risen dramatically in recent years due to increased volatility in world petroleum and petroleum product prices and increased illegal exportation of subsidized petroleum products into neighboring countries. Removing the subsidy on fuel is one of the most contentious socio-economic policy issues in Nigeria today. In this paper, an economy-wide framework is used to identify the impact of removing the fuel subsidy on the Nigerian economy and investigates how alternative policies might be used to meet socio-economic objectives related to fuel subsidies. The results show that while a reduction in the subsidy generally results in an increase in Nigerian GDP, it can have a detrimental impact on household income, and in particular on poor households. Accompanying the subsidy reduction with income transfers aimed at poor households or domestic production of petroleum products can alleviate the negative impacts on household income. - Highlights: • Subsidies on imported fuel compromise the contribution of crude oil in Nigeria. • Fuel subsidies benefit households, but harm the economy. • We use an economy-wide model to identify the impact of removing the fuel subsidy. • We simulate scenarios that target the poor and promote fuel's domestic production

  15. "New Economics"?

    DEFF Research Database (Denmark)

    Nielsen, Jørgen Ulff-Møller

    1999-01-01

    The United States, the United Kingdom and Denmark have all enjoyed a long period of high stable growth and low inflation in the 1990s. Attempts to determine the implications of this have led to the so-called "New Economics", whose advocates claim that the relationship between economic growth...

  16. Socio-economic analysis for the authorisation of chemicals under REACH: A case of very high concern?

    NARCIS (Netherlands)

    Gabbert, S.G.M.; Scheringer, M.; Ng, C.A.; Stolzenberg, H.C.

    2014-01-01

    Under the European chemicals’ legislation, REACH, substances that are identified to be of “very high concern” will de facto be removed from the market unless the European Commission grants authorisations permitting specific uses. Companies who apply for an authorisation without demonstrating

  17. Heat removal tests on dry storage facilities for nuclear spent fuels

    International Nuclear Information System (INIS)

    Wataru, M.; Saegusa, T.; Koga, T.; Sakamoto, K.; Hattori, Y.

    1999-01-01

    In Japan, spent fuel generated in NPP is controlled and stored in dry storage facility away-from reactor. Natural convection cooling system of the storage facility is considered advantageous from both safety and economic point of view. In order to realize this type of facility it is necessary to develop an evaluation method for natural convection characteristics and to make a rational design taking account safety and economic factors. Heat removal tests with the reduces scale models of storage facilities (cask, vault and silo) identified the the flow pattern in the test modules. The temperature and velocity distributions were obtained and the heat transfer characteristics were evaluated

  18. Preferable removal of phosphate from water using hydrous zirconium oxide-based nanocomposite of high stability.

    Science.gov (United States)

    Chen, Liang; Zhao, Xin; Pan, Bingcai; Zhang, Weixian; Hua, Ming; Lv, Lu; Zhang, Weiming

    2015-03-02

    In this study, we employed a new nanocomposite adsorbent HZO-201, which featured high stability under varying solution chemistry, for preferable removal of phosphate from synthetic solution and a real effluent. An anion exchange resin (D-201) was employed as the host of HZO-201, where nano-hydrous zirconium oxide (HZO) was encapsulated as the active species. D-201 binds phosphate through nonspecific electrostatic affinity, whereas the loaded HZO nanoparticles capture phosphate through formation of the inner-sphere complexes. Quantitative contribution of both species to phosphate adsorption was predicted based on the double-Langmuir model. Preferable removal of phosphate by HZO-201 was observed in the presence of the competing anions at higher levels (Cl(-), NO3(-), SO4(2-), HCO3(-)). Fixed-bed adsorption indicated that the effective volume capacity of a synthetic water (2.0 mg P-PO4(3-)/L) by using HZO-201 was ∼1600 BV in the first run (<0.5mg P-PO4(3-)/L), comparable to Fe(III)-based nanocomposite HFO-201 (∼1500 BV) and much larger than D-201 (<250 BV). The exhausted HZO-201 can be in situ regenerated by using a binary NaOH-NaCl solution for cyclic runs, whether fed with the synthetic solution or real effluent. In general, HZO-201 is a promising alternative to Fe(III)-based adsorbents for trace phosphate removal from effluent particularly at acidic pH. Copyright © 2014 Elsevier B.V. All rights reserved.

  19. Skill-based immigration, economic integration, and economic performance

    OpenAIRE

    Aydemir, Abdurrahman

    2014-01-01

    Studies for major immigrant-receiving countries provide evidence on the comparative economic performance of immigrant classes (skill-, kinship-, and humanitarian-based). Developed countries are increasingly competing for high-skilled immigrants, who perform better in the labor market. However, there are serious challenges to their economic integration, which highlights a need for complementary immigration and integration policies.

  20. Optimized biological nitrogen removal of high-strength ammonium wastewater by activated sludge modeling

    Directory of Open Access Journals (Sweden)

    Abdelsalam Elawwad

    2018-09-01

    Full Text Available Wastewater containing high ammonium concentrations is produced from various industrial activities. In this study, the author used a complex activated sludge model, improved by utilizing BioWin© (EnviroSim, Hamilton, Canada simulation software, to gain understanding of the problem of instability in biological nitrogen removal (BNR. Specifically, the study focused on BNR in an industrial wastewater treatment plant that receives high-strength ammonium wastewater. Using the data obtained from a nine-day sampling campaign and routinely measured data, the model was successfully calibrated and validated, with modifications to the sensitive stoichiometric and kinetic parameters. Subsequently, the calibrated model was employed to study various operating conditions in order to optimize the BNR. These operating conditions include alkalinity addition, sludge retention time, and the COD/N ratio. The addition of a stripping step and modifications to the configuration of the aerators are suggested by the author to increase the COD/N ratio and therefore enhance denitrification. It was found that the calibrated model could successfully represent and optimize the treatment of the high-strength ammonium wastewater.

  1. Characterization of landfill leachates and studies on heavy metal removal.

    Science.gov (United States)

    Ceçen, F; Gürsoy, G

    2000-10-01

    This study covers a thorough characterisation of landfill leachates emerging from a sanitary landfill area. The landfill leachates were obtained in the acidic stage of landfill stabilisation. Their organic content was high as reflected by the high BOD5 (5 day biological oxygen demand) and COD (chemical oxygen demand) values. They were also highly polluted in terms of the parameters TKN (total Kjeldahl nitrogen), NH4-N, alkalinity, hardness and heavy metals. Nickel was present in these wastewaters at a significant concentration. With regard to the high heavy metal content of these wastewaters, several physicochemical removal alternatives for the heavy metals Cu, Pb, Zn, Ni, Cd, Cr, Mn and Fe were tested using coagulation, flocculation, precipitation, base addition and aeration. Additionally, COD removal and ammonia stripping were examined. Co-precipitation with either alum or iron salts did not usually lead to significantly higher heavy metal removal than lime alone. The major methods leading to an effective heavy metal removal were aeration and lime addition. Nickel and cadmium seemed to be strongly complexed and were not removed by any method. Also lead removal proved to be difficult. The results are also discussed in terms of compliance with standards.

  2. High temperature fluidized bed zero valent iron process for flue gas nitrogen monoxide removal

    International Nuclear Information System (INIS)

    Cheng, C.Y.; Chen, S.S.; Tang, C.H.; Chang, Y.M.; Cheng, H.H.; Liu, H.L.

    2008-01-01

    Nitrogen oxides (NO x ) are generated from a variety of sources, and are critical components of photochemical smog. Zero valent iron (ZVI) has been used to remove NO x in a number of studies. The ZVI process requires no extra chemicals or catalysts. In this study, a fluidized ZVI process for removing NO x from flue gases was proposed. The study examined the effects of temperature, ZVI dosage and influent NO concentrations, and observed the kinetic effects between the fluidized ZVI and NO x . A life cycle analysis of the process was also provided. The parametric analysis was conducted in a series of column studies using a continuous emissions monitoring system. Minimum fluidization velocity equations were provided, and the drag coefficient was determined. Capacities of ZVI for NO removal at different temperatures were calculated. Results of the study suggested that temperature, influent concentrations, and flow rates all influenced kinetic coefficients. Different temperatures resulted in different rates of NO removal. It was concluded that between 673 K and 773 K, almost complete NO removals were achieved. 14 refs., 2 tabs., 9 figs

  3. Monopolar Electro-Coagulation Process for Azo Dye C.I. Acid Red 18 Removal from Aqueous Solutions

    Directory of Open Access Journals (Sweden)

    Ghasem Azarian

    2014-12-01

    Full Text Available The discharge of wastewaters containing an untreated dye results in aesthetic problems and an increase in gases solubility, which causes light transmission inhibition into water bodies. In spite of advantages of physicochemical and biological methods, these processes produce huge amounts of sludge, toxic by-products and require several oxidant chemicals. By contrast, electrochemical processes because of their high versatility, high efficiency and eco-friendly properties are more acceptable. In the present study, the removal of azo dye Acid Red 18 and chemical oxygen demand (COD from synthetic wastewater by monopolar (EC process was investigated and key parameters such as operating time, current density (CD, initial pH and energy, and electrode consumption were optimized. It was found that the process had a very good efficiency in the removal of both COD and color; for the iron electrode, the maximum amounts of color and COD removal were 99.5% and 59.0%, respectively. An operating time of 45 min, pH of 7 and CD of 1.2 mA/cm2 was selected as the optimized condition. The optimization of variables is extremely crucial as it results in a decrease in costs, energy and electrode consumption. Overall, the iron electrode used less energy than the aluminum electrode and was more acceptable for use in this process due to economical reasons. The findings of UV/vis spectra illustrated that the structures of this dye were removed by the process. In comparison with traditional methods such as aerobic and anaerobic systems, the EC process is a suitable alternative for the treatment of wastewaters containing dye pollutants.

  4. Removal of radionuclides from household water

    International Nuclear Information System (INIS)

    Vesterbacka, P.; Turtiainen, T.; Haemaelaeinen, K.; Salonen, L.; Arvela, H.

    2007-02-01

    Research upon methods for removing radionuclides from household water was initiated in Finland in 1995. Three research projects, of which two were carried out with National Technology Agency of Finland and one with CEC, have been completed by the end of 2002. One of the main objectives of the research was to compose a guidebook for consumers and water treatment companies. Radon can be removed from household water by aeration and by activated carbon filtration. Aerators that are well designed and set up can remove over 90% of waterborne radon. The best aerators have achieved removal efficiencies that are nearly 100%. However, setting up an aeration system requires thorough planning. Also, activated carbon filtration removes radon efficiently. The removal efficiencies have been over 90%, often nearly 100%. Depending on the water quality and usage, the carbon batch inside the filter needs to be changed every 2 - 3 years. Since activated carbon filters emit gamma radiation while in use, they should not be installed inside the dwelling but in a separate building or by the well. It is recommended that uranium be removed from drinking water by anion exchange, which is the most efficient removal method for this purpose. Typically, the removal efficiencies are nearly 100%. The one exception is the so called tap filter, the removal efficiency of which depends on uranium concentration in raw water and the rate of water flow. High saline concentration in water may extricate uranium from ion exchange resin. Changes in plumbing pressure or pH-value do not have any significant influence in uranium retention. Removal efficiencies of lead and polonium vary a lot depending on the chemical form in which they occur in water. They can be reliably removed from water by reverse osmosis only. Other treatment methods, such as ion exchange and activated carbon filtration, remove lead and polonium partly. Lead and polonium are removed more efficiently when they are bound onto smaller

  5. Comparison of toxin removal outcomes in online hemodiafiltration and intra-dialytic exercise in high-flux hemodialysis: A prospective randomized open-label clinical study protocol

    Directory of Open Access Journals (Sweden)

    Maheshwari Vaibhav

    2012-11-01

    Full Text Available Abstract Background Maintenance hemodialysis (HD patients universally suffer from excess toxin load. Hemodiafiltration (HDF has shown its potential in better removal of small as well as large sized toxins, but its efficacy is restricted by inter-compartmental clearance. Intra-dialytic exercise on the other hand is also found to be effective for removal of toxins; the augmented removal is apparently obtained by better perfusion of skeletal muscles and decreased inter-compartmental resistance. The aim of this trial is to compare the toxin removal outcome associated with intra-dialytic exercise in HD and with post-dilution HDF. Methods/design The main hypothesis of this study is that intra-dialytic exercise enhances toxin removal by decreasing the inter-compartmental resistance, a major impediment for toxin removal. To compare the HDF and HD with exercise, the toxin rebound for urea, creatinine, phosphate, and β2-microglobulin will be calculated after 2 hours of dialysis. Spent dialysate will also be collected to calculate the removed toxin mass. To quantify the decrease in inter-compartmental resistance, the recently developed regional blood flow model will be employed. The study will be single center, randomized, self-control, open-label prospective clinical research where 15 study subjects will undergo three dialysis protocols (a high flux HD, (b post-dilution HDF, (c high flux HD with exercise. Multiple blood samples during each study session will be collected to estimate the unknown model parameters. Discussion This will be the first study to investigate the exercise induced physiological change(s responsible for enhanced toxin removal, and compare the toxin removal outcome both for small and middle sized toxins in HD with exercise and HDF. Successful completion of this clinical research will give important insights into exercise effect on factors responsible for enhanced toxin removal. The knowledge will give confidence for implementing

  6. Removal of Na+ from Ionic Liquids by Zeolite for High Quality Electrolyte Manufacture

    International Nuclear Information System (INIS)

    Cho, Wonje; Seo, Yongseong; Jung, Soon Jae; Lee, Won Gil; Kim, Byung Chul; Yu, Kookhyun

    2013-01-01

    This study develops a novel method to remove the free cations created during the synthesis of ionic liquid. The cations are removed from the ionic liquid by size-selective adsorption onto chemically surface-modified Zeolite. The porous crystal nano-structure of Zeolite has several electron-rich Al sites to attract cations. While large cations of an ionic liquid cannot access the Zeolite nano-structure, small cations like Na + have ready access and are adsorbed. This study confirms that: Na + can be removed from ionic liquid effectively using Zeolite; and, in contrast to the conventional and extensively applied ion exchange resin method or solvent extraction methods, this can be done without changing the nature of the ionic liquid

  7. Methanol removal efficiency and bacterial diversity of an activated carbon biofilter.

    Science.gov (United States)

    Babbitt, Callie W; Pacheco, Adriana; Lindner, Angela S

    2009-12-01

    Motivated by the need to establish an economical and environmentally friendly methanol control technology for the pulp and paper industry, a bench-scale activated carbon biofiltration system was developed. This system was evaluated for its performance in removing methanol from an artificially contaminated air stream and characterized for its bacterial diversity over time, under varied methanol loading rates, and in different spatial regions of the filter. The biofilter system, composed of a novel packing mixture, provided an excellent support for growth and activity of methanol-degrading bacteria, resulting in approximately 100% methanol removal efficiency for loading rates of 1-17 g/m(3) packing/h, when operated both with and without inoculum containing enriched methanol-degrading bacteria. Although bacterial diversity and abundance varied over the length of the biofilter, the populations present rapidly formed a stable community that was maintained over the entire 138-day operation of the system and through variable operating conditions, as observed by PCR-DGGE methods that targeted all bacteria as well as specific methanol-oxidizing microorganisms. Phylogenetic analysis of bands excised and sequenced from DGGE gels indicated that the biofilter system supported a diverse community of methanol-degrading bacteria, with high similarity to species in the genera Methylophilus (beta-proteobacteria), Hyphomicrobium and Methylocella (both alpha-proteobacteria).

  8. Comparative Cost of Colour Removal from Textile Effluents Using Agriculture Wastes

    International Nuclear Information System (INIS)

    Afifi, T.H.; Aboul Fetouh, M.S.; Nassar, F.A.; Riyad, Y.M.

    1999-01-01

    In recent years, investigations have been oriented towards practical use of low cost materials in the treatment of wastewater polluted by dyestuffs. The use of bagasse pith and maize cob as agricultural wastes for the colour removal of dyestuffs, namely, Direct Orange 34, Direct Red 23, Reactive Violet 2 and Reactive Blue 19 from aqueous solution at different concentrations has been investigated. The adsorption capacity for each dye- adsorbent system has been determined. The relative costs of dye removal were reported based on adsorption capacity only. The aim of the present work is to assess the feasibility of two low-cost agriculture-wastes materials to adsorb both direct and reactive dyestuffs on economic basis

  9. Process and system for removing tritium

    International Nuclear Information System (INIS)

    Ridgely, J.N.

    1976-01-01

    A process and system for removing tritium, particularly from high temperature gas cooled atomic reactors (HTGR), is disclosed. Portions of the reactor coolant, which is permeated with the pervasive tritium atom, are processed to remove the tritium. Under conditions of elevated temperature and pressure, the reactor coolant is combined with gaseous oxygen, resulting in the formation of tritiated water vapor from the tritium in the reactor coolant and the gaseous oxygen. The tritiated water vapor and the remaining gaseous oxygen are then successively removed by fractional liquefaction steps. The reactor coolant is then recirculated to the reactor

  10. Linezolid extracorporeal removal during haemodialysis with high cut-off membrane in critically ill patients.

    Science.gov (United States)

    Villa, Gianluca; Cassetta, Maria Iris; Tofani, Lorenzo; Valente, Serafina; Chelazzi, Cosimo; Falsini, Silvia; De Gaudio, Angelo Raffaele; Novelli, Andrea; Ronco, Claudio; Adembri, Chiara

    2015-10-01

    Continuous venovenous haemodialysis with high cut-off membrane (HCO-CVVHD) is often used in critically ill septic patients with acute kidney injury (AKI) to sustain renal function and to remove circulating inflammatory mediators. The aim of this study was to analyse the extracorporeal removal of linezolid and related alterations in pharmacokinetic/pharmacodynamic (PK/PD) parameters during HCO-CVVHD. Three critically ill septic patients with AKI, treated with linezolid and HCO-CVVHD, were prospectively observed. To calculate the extracorporeal clearance of linezolid and the PK parameters, effluent, pre-filter and post-filter samples were contemporaneously collected before linezolid infusion, just after 1-h infusion (maximum serum concentration; C(max)), at 3 h and 6 h after dosing, and before the next dose (trough serum concentration; C(min)). Linezolid C(max) and C(min) (pre-filter) ranged from 10.4-23.5 mg/L and from 2.9-10.3 mg/L. The dialysate saturation coefficient was 0.66-0.85 and the extracorporeal clearance with a diffusive dose of 35 m L/kg/h ranged from 2.1-2.5 L/h. Total linezolid clearance was between 1.7 L/h and 6.3 L/h. The total area under the plasma concentration-time curve (AUC0-∞) ranged from 95.1 mgh/L to 352.9 mgh/L, in accordance with the different clinical conditions. AUCfree/MIC ratios were always linezolid total clearance, the clinical features of critically ill septic patients appear to be mainly responsible for the high variability of linezolid serum concentrations. Copyright © 2015. Published by Elsevier B.V.

  11. The acclimation of Chlorella to high-level nitrite for potential application in biological NOx removal from industrial flue gases.

    Science.gov (United States)

    Li, Tianpei; Xu, Gang; Rong, Junfeng; Chen, Hui; He, Chenliu; Giordano, Mario; Wang, Qiang

    2016-05-20

    Nitrogen oxides (NOx) are the components of fossil flue gas that give rise to the greatest environmental concerns. This study evaluated the ability of the green algae Chlorella to acclimate to high level of NOx and the potential utilization of Chlorella strains in biological NOx removal (DeNOx) from industrial flue gases. Fifteen Chlorella strains were subject to high-level of nitrite (HN, 176.5 mmolL(-1) nitrite) to simulate exposure to high NOx. These strains were subsequently divided into four groups with respect to their ability to tolerate nitrite (excellent, good, fair, and poor). One strain from each group was selected to evaluate their photosynthetic response to HN condition, and the nitrite adaptability of the four Chlorella strains were further identified by using chlorophyll fluorescence. The outcome of our experiments shows that, although high concentrations of nitrite overall negatively affect growth and photosynthesis of Chlorella strains, the degree of nitrite tolerance is a strain-specific feature. Some Chlorella strains have an appreciably higher ability to acclimate to high-level of nitrite. Acclimation is achieved through a three-step process of restrict, acclimate, and thriving. Notably, Chlorella sp. C2 was found to have a high tolerance and to rapidly acclimate to high concentrations of nitrite; it is therefore a promising candidate for microalgae-based biological NOx removal. Copyright © 2016 Elsevier GmbH. All rights reserved.

  12. Membrane adsorber for endotoxin removal

    Directory of Open Access Journals (Sweden)

    Karina Moita de Almeida

    Full Text Available ABSTRACT The surface of flat-sheet nylon membranes was modified using bisoxirane as the spacer and polyvinyl alcohol as the coating polymer. The amino acid histidine was explored as a ligand for endotoxins, aiming at its application for endotoxin removal from aqueous solutions. Characterization of the membrane adsorber, analysis of the depyrogenation procedures and the evaluation of endotoxin removal efficiency in static mode are discussed. Ligand density of the membranes was around 7 mg/g dry membrane, allowing removal of up to 65% of the endotoxins. The performance of the membrane adsorber prepared using nylon coated with polyvinyl alcohol and containing histidine as the ligand proved superior to other membrane adsorbers reported in the literature. The lack of endotoxin adsorption on nylon membranes without histidine confirmed that endotoxin removal was due to the presence of the ligand at the membrane surface. Modified membranes were highly stable, exhibiting a lifespan of approximately thirty months.

  13. Removal of congo red and methylene blue from waste water using coagulation

    International Nuclear Information System (INIS)

    Ghaffar, S.; Nosheen, S.; Ahmad, N.

    2011-01-01

    The textile industry has been condemned as being one of the world's worst offenders in terms of pollution Because of increasing population and industrial developments, a huge amount of wastewater is discharged to the environment above the level that the nature can eliminate. Many techniques like oxidation, reduction, physical treatment and biological method are available for removal of colored dyes from wastewater. The work presented here involved the decolorisation of wastewater containing congo red and methylene blue using various coagulants such as alum, bentonite and lime. The effect of various experimental factors such as dosage of coagulants, contact time between coagulant and dye and concentration of dyes and working environment like shaking and static was studied. Under static condition alum give almost 43% removal of congo red while with 10 minutes shaking 74 % removal of 80 dye was achieved with same coagulant. The highest removal of congo red was found to be 99.5 % by using alum after 30 minutes of shaking but in case of methylene blue it intensified the color and gave negative results. Lime gave only 33 % color removal of congo red under static conditions while 57% color was removed under shaking conditions. Maximum color removal achieved by lime was 89% at 40 minutes with shaking condition. Lime gave 60% removal of methylene blue in static condition and 90% removal in shaking condition and maximum absorbance at 80 ppm was 90%. Bentonite also used for the removal of methylene blue and gave 89% removal in shaking condition. By increasing shaking time %age removal increased to 100% at 40 min. And amount of coagulant increased the removal efficiency it attained 100% in both lime and bentonite coagulant for methylene blue Overall alum was found to be better coagulant for the removal of congo red from its aqueous solution. Lime and bentonite both proved better and economical for removal of methylene blue from aqueous solution at lab scale. (author)

  14. Arsenic Removal by Liquid Membranes

    Directory of Open Access Journals (Sweden)

    Tiziana Marino

    2015-03-01

    Full Text Available Water contamination with harmful arsenic compounds represents one of the most serious calamities of the last two centuries. Natural occurrence of the toxic metal has been revealed recently for 21 countries worldwide; the risk of arsenic intoxication is particularly high in Bangladesh and India but recently also Europe is facing similar problem. Liquid membranes (LMs look like a promising alternative to the existing removal processes, showing numerous advantages in terms of energy consumption, efficiency, selectivity, and operational costs. The development of different LM configurations has been a matter of investigation by several researching groups, especially for the removal of As(III and As(V from aqueous solutions. Most of these LM systems are based on the use of phosphine oxides as carriers, when the metal removal is from sulfuric acid media. Particularly promising for water treatment is the hollow fiber supported liquid membrane (HFSLM configuration, which offers high selectivity, easy transport of the targeted metal ions, large surface area, and non-stop flow process. The choice of organic extractant(s plays an essential role in the efficiency of the arsenic removal. Emulsion liquid membrane (ELM systems have not been extensively investigated so far, although encouraging results have started to appear in the literature. For such LM configuration, the most relevant step toward efficiency is the choice of the surfactant type and its concentration.

  15. The synthesis, characterization and application of iron oxide nanocrystals in magnetic separations for arsenic and uranium removal

    Science.gov (United States)

    Mayo, John Thomas

    Arsenic and uranium in the environment are hazardous to human health and require better methods for detection and remediation. Nanocrystalline iron oxides offer a number of advantages as sorbents for water purification and environmental remediation. First, highly uniform and crystalline iron oxide nanocrystals (nMAG) were prepared using thermal decomposition of iron salts in organic solutions; for the applications of interest in this thesis, a central challenge was the adaptation of these conventional synthetic methods to the needs of low infrastructure and economically disadvantaged settings. We show here that it is possible to form highly uniform and magnetically responsive nanomaterials using starting reagents and equipment that are readily available and economical. The products of this approach, termed the 'Kitchen Synthesis', are of comparable quality and effectiveness to laboratory materials. The narrow size distributions of the iron oxides produced in the laboratory synthesis made it possible to study the size-dependence of the magnetic separation efficiency of nanocrystals; generally as the diameter of particles increased they could be removed under lower applied magnetic fields. In this work we take advantage of this size-dependence to use magnetic separation as a tool to separate broadly distributed populations of magnetic materials. Such work makes it possible to use these materials in multiplexed separation and sensing schemes. With the synthesis and magnetic separation studies of these materials completed, it was possible to optimize their applications in water purification and environmental remediation. These materials removed both uranium and arsenic from contaminated samples, and had remarkably high sorption capacities --- up to 12 wt% for arsenic and 30 wt% for uranium. The contaminated nMAG is removed from the drinking water by either retention in a sand column, filter, or by magnetic separation. The uranium adsorption process was also utilized

  16. Techniques for removing contaminants from optical surfaces

    International Nuclear Information System (INIS)

    Stowers, I.F.; Patton, H.G.

    1978-01-01

    Particle removal procedures such as plasma cleaning, ultrasonic agitation of solvents, detergents, solvent wiping, mild abrasives, vapor degreasing, high pressure solvent spraying and others have been evaluated and the results are reported here. Wiping with a lens tissue wetted with an organic solvent and high pressure fluid spraying are the only methods by which particles as small as 5 μm can be effectively removed. All of the other methods tested were found to be at least two orders of magnitude less effective at removing small insoluble particles. An additional and as yet unresolved problem is the development of a reliable method for evaluating particulate surface cleanliness. Without such a reproducible monitoring technique, the large diversity of cleaning methods currently available cannot be quantitatively evaluated

  17. Removal of phosphorus, fluoride and metals from a gypsum mining leachate using steel slag filters.

    Science.gov (United States)

    Claveau-Mallet, Dominique; Wallace, Scott; Comeau, Yves

    2013-03-15

    The objective of this work was to evaluate the capacity of steel slag filters to treat a gypsum mining leachate containing 11-107 mg P/L ortho-phosphates, 9-37 mg/L fluoride, 0.24-0.83 mg/L manganese, 0.20-3.3 zinc and 1.7-8.2 mg/L aluminum. Column tests fed with reconstituted leachates were conducted for 145-222 days and sampled twice a week. Two types of electric arc furnace (EAF) slags and three filter sequences were tested. The voids hydraulic retention time (HRT(v)) of columns ranged between 4.3 and 19.2 h. Precipitates of contaminants present in columns were sampled and analyzed with X-ray diffraction at the end of tests. The best removal efficiencies over a period of 179 days were obtained with sequential filters that were composed of Fort Smith EAF slag operated at a total HRT(v) of 34 h which removed 99.9% of phosphorus, 85.3% of fluoride, 98.0% of manganese and 99.3% of zinc. Mean concentration at this system's effluent was 0.04 mg P/L ortho-phosphates, 4 mg/L fluoride, 0.02 mg/L manganese, 0.02 zinc and 0.5 mg/L aluminum. Thus, slag filters are promising passive and economical systems for the remediation of mining effluents. Phosphorus was removed by the formation of apatite (hydroxyapatite, Ca(5)(PO(4))(3)OH or fluoroapatite, Ca(5)(PO(4))(3)F) as confirmed by visual and X-ray diffraction analyses. The growth rate of apatite was favored by a high phosphorus concentration. Calcite crystals were present in columns and appeared to be competing for calcium and volume needed for apatite formation. The calcite crystal growth rate was higher than that of apatite crystals. Fluoride was removed by precipitation of fluoroapatite and its removal was favored by a high ratio of phosphorus to fluoride in the wastewater. Copyright © 2012 Elsevier Ltd. All rights reserved.

  18. ARSENIC REMOVAL BY IRON REMOVAL PROCESSES

    Science.gov (United States)

    Presentation will discuss the removal of arsenic from drinking water using iron removal processes that include oxidation/filtration and the manganese greensand processes. Presentation includes results of U.S. EPA field studies conducted in Michigan and Ohio on existing iron remo...

  19. Process for removing and installing the side reflector of a high temperature reactor

    International Nuclear Information System (INIS)

    Fritz, R.; Kalden, B.; Kissel, K.F.; Schoening, J.

    1979-01-01

    The pressure of the HTR is released and the absorber rods in the side reflector region are removed from their armoured tubes. Manipulators are inserted in the empty armoured tubes. Using these, metal inserts can be removed, a bulkhead can be built up near the pebble bed and the square blocks of the side reflector can be taken out. (DG) [de

  20. Comparison of nutrient removal capacity and biomass settleability of four high-potential microalgal species.

    Science.gov (United States)

    Su, Yanyan; Mennerich, Artur; Urban, Brigitte

    2012-11-01

    Four common used microalgae species were compared in terms of settleability, nutrient removal capacity and biomass productivity. After 1 month training, except cyanobacteria Phormidium sp., three green microalgae species, Chlamydomonas reinhardtii, Chlorella vulgaris and Scenedesmus rubescens, showed good settleability. The N and P removal efficiency was all above 99% within 7, 4, 6 and 6 days for N and 4, 2, 3 and 4 days for P, resulting in the N removal rates of 3.66±0.17, 6.39±0.20, 4.39±0.06 and 4.31±0.18 mg N/l/d and P removal rates of 0.56±0.07, 0.89±0.05, 0.76±0.09 and 0.60±0.05 mg P/l/d for Phormidium sp., C. reinhardtii, C. vulgaris and S. rubescens, respectively. Phormidium sp. had the lowest algal biomass productivity (2.71±0.7 g/m(2)/d) and the other three green microalgae showed higher algal biomass productivity (around 6 g/m(2)/d). Assimilation into biomass was the main removal mechanism for N and P. Copyright © 2012 Elsevier Ltd. All rights reserved.

  1. A novel vanadosilicate with hexadeca-coordinated Cs+ ions as a highly effective Cs+ remover

    International Nuclear Information System (INIS)

    Datta, Shuvo Jit; Moon, Won Kyung; Choi, Do Young; Hwang, In Chul; Yoon, Kyung Byung

    2014-01-01

    The effective removal of 137 Cs + ions from contaminated groundwater and seawater and from radioactive nuclear waste solutions is crucial for public health and for the continuous operation of nuclear power plants. Various 137 Cs + removers have been developed, but more effective 137 Cs + removers are still needed. A novel microporous vanadosilicate with mixed-valence vanadium (V 4+ and V 5+ ) ions is now reported, which shows an excellent ability for Cs + capture and immobilization from groundwater, seawater, and nuclear waste solutions. This material is superior to other known materials in terms of selectivity, capacity, and kinetics, and at very low Cs + concentrations, it was found to be the most effective material for the removal of radioactive Cs + ions under the test conditions. This novel vanadosilicate also contains hexadeca-coordinated Cs + ions, which corresponds to the highest coordination number ever described.

  2. Sulfur rich microporous polymer enables rapid and efficient removal of mercury(II) from water.

    Science.gov (United States)

    Xu, Dan; Wu, Winston Duo; Qi, Hao-Jun; Yang, Rui-Xia; Deng, Wei-Qiao

    2018-04-01

    Design and synthesis of adsorbents for efficient decontamination of hazardous contaminants Hg 2+ from wastewater, based on a facile and economical strategy, is an attractive target. Here, a novel sulfur rich microporous polymer (sulfur content of 31.4 wt %) with high surface area as well as densely populated sulfur atom with fast accessibility was reported to remove mercury (II) from water. The as prepared polymer (SMP) exhibited high binding affinity, high adsorption capacities, rapid adsorption kinetics, and good recyclability for Hg 2+ . The adsorption capacity of SMP was 595.2 mg g -1 . Furthermore, SMP could reduce trace concentrations of Hg 2+ from 200 p. p. b. to a level below drinking water standards (2 p. p. b.) within 3 min. This work allows large-scale production of sulfur rich porous materials for the practical application in water treatment. Copyright © 2017 Elsevier Ltd. All rights reserved.

  3. The economic cost of low domestic product prices in OPEC Member Countries

    International Nuclear Information System (INIS)

    Guerer, N.; Ban, J.

    2000-01-01

    The present state of subsidies on major oil products (gasoline, kerosene, diesel and fuel oil) in OPEC Member Countries is analysed, in order to quantify their economic cost, keeping in mind the importance of reforming or gradually removing subsidies as one of the crucial economic challenges facing many Member Countries. The paper begins with a general definition and description of subsidies, then discusses briefly the key issues in reforming/removing them, with the potential benefits. Following a section on subsidy level estimations in recent years, the subsidy implications in terms of the accruing budget burden and foregone revenues from additional export potential are presented. This is together with some arguments supporting the process of adjustment towards internationally competitive prices for oil products as an inescapable development for Member Countries; this should progress in gradual, but firm steps. (author)

  4. Feasibility of atmospheric methane removal using methanotrophic biotrickling filters.

    Science.gov (United States)

    Yoon, Sukhwan; Carey, Jeffrey N; Semrau, Jeremy D

    2009-07-01

    Methane is a potent greenhouse gas with a global warming potential ~23 times that of carbon dioxide. Here, we describe the modeling of a biotrickling filtration system composed of methane-consuming bacteria, i.e., methanotrophs, to assess the utility of these systems in removing methane from the atmosphere. Model results indicate that assuming the global average atmospheric concentration of methane, 1.7 ppmv, methane removal is ineffective using these methanotrophic biofilters as the methane concentration is too low to enable cell survival. If the concentration is increased to 500-6,000 ppmv, however, similar to that found above landfills and in concentrated animal feeding operations (factory farms), 4.98-35.7 tons of methane can be removed per biofilter per year assuming biotrickling filters of typical size (3.66 m in diameter and 11.5 m in height). Using reported ranges of capital, operational, and maintenance costs, the cost of the equivalent ton of CO(2) removal using these systems is $90-$910 ($2,070-$20,900 per ton of methane), depending on the influent concentration of methane and if heating is required. The use of methanotrophic biofilters for controlling methane emissions is technically feasible and, provided that either the costs of biofilter construction and operation are reduced or the value of CO(2) credits is increased, can also be economically attractive.

  5. Removal of radionuclides from household water

    International Nuclear Information System (INIS)

    Vesterbacka, P.; Turtiainen, T.; Haemaelaeinen, K.; Salonen, L.; Arvela, H.

    2003-10-01

    Research upon methods for removing radionuclides from household water was initiated in Finland in 1995. Three research projects, of which two were carried out with National Technology Agency of Finland and one with CEC, have been completed by the end of 2002. One of the main objectives of the research was to compose a guidebook for consumers and water treatment companies. Radon can be removed from household water by aeration and by activated carbon filtration. Aerators that are well designed and set up can remove over 90% of waterborne radon. The best aerators have achieved removal efficiencies that are nearly 100%. However, setting up an aeration system requires thorough planning. Also, activated carbon filtration removes radon efficiently. The removal efficiencies have been over 90%, often nearly 100%. Depending on the water quality and usage, the carbon batch inside the filter needs to be changed every 2-3 years. Since activated carbon filters emit gamma radiation while in use, they should not be installed inside the dwelling but in a separate building or by the well. It is recommended that uranium be removed from drinking water by anion exchange, which is the most efficient removal method for this purpose. Typically, the removal efficiencies are nearly 100%. The one exception is the so called tap filter, the removal efficiency of which depends on uranium concentration in raw water and the rate of water flow. High saline concentration in water may extricate uranium from ion exchange resin. Changes in plumbing pressure or pH-value do not have any significant influence in uranium retention. Removal efficiencies of lead and polonium vary a lot depending on the chemical form in which they occur in water. They can be reliably removed from water by reverse osmosis only. Other treatment methods, such as ion exchange and activated carbon filtration, remove lead and polonium partly. Lead and polonium are removed more efficiently when they are bound onto smaller particles

  6. Cyanide removal from industrial wastewater by cross-flow nanofiltration: transport modeling and economic evaluation.

    Science.gov (United States)

    Pal, Parimal; Bhakta, Pamela; Kumar, Ramesh

    2014-08-01

    A modeling and simulation study, along with an economic analysis, was carried out for the separation of cyanide from industrial wastewater using a flat sheet cross-flow nanofiltration membrane module. With the addition of a pre-microfiltration step, nanofiltration was carried out using real coke wastewater under different operating conditions. Under the optimum operating pressure of 13 bars and a pH of 10.0, a rate of more than 95% separation of cyanide was achieved. That model predictions agreed very well with the experimental findings, as is evident in the Willmott d-index value (> 0.95) and relative error (economic analysis was also done, considering the capacity of a running coking plant. The findings are likely to be very useful in the scale-up and design of industrial plants for the treatment of cyanide-bearing wastewater.

  7. Ozonation of a pretreated landfill leachate: evaluation of recalcitrance removal

    OpenAIRE

    Van Aken, Pieter; Lambert, Nico; Luyten, Jan; Degrève, Jan; Liers, Sven

    2010-01-01

    The sanitary landfill method for the ultimate disposal of solid waste material continues to be widely accepted and used due to its economic advantages. However, water infiltrates through the solid waste and a variety of organic and inorganic pollutants will be dissolved and transported. These leachates may contain large amounts of organic matter, as well as ammonia-nitrogen, heavy metals, chlorinated organic and inorganic salts. The removal of organic material is usual the prerequisite before...

  8. Electricity generation and nutrients removal from high-strength liquid manure by air-cathode microbial fuel cells.

    Science.gov (United States)

    Lin, Hongjian; Wu, Xiao; Nelson, Chad; Miller, Curtis; Zhu, Jun

    2016-01-01

    Air-cathode microbial fuel cells (MFCs) are widely tested to recover electrical energy from waste streams containing organic matter. When high-strength wastewater, such as liquid animal manure, is used as a medium, inhibition on anode and cathode catalysts potentially impairs the effectiveness of MFC performance in power generation and pollutant removal. This study evaluated possible inhibitive effects of liquid swine manure components on MFC power generation, improved liquid manure-fed MFCs performance by pretreatment (dilution and selective adsorption), and modeled the kinetics of organic matter and nutrients removal kinetics. Parameters monitored included pH, conductivity, chemical oxygen demand (COD), volatile fatty acids (VFAs), total ammoniacal nitrogen (TAN), nitrite, nitrate, and phosphate concentrations. The removals of VFA and TAN were efficient, indicated by the short half-life times of 4.99 and 7.84 d, respectively. The mechanism for phosphate decrease was principally the salt precipitation on cathode, but the removal was incomplete after 42-d operation. MFC with an external resistor of 2.2 kΩ and fed with swine wastewater generated relatively small power (28.2 μW), energy efficiency (0.37%) and Coulombic efficiency (1.5%). Dilution of swine wastewater dramatically improved the power generation as the inhibitory effect was decreased. Zeolite and granular activated carbon were effective in the selective adsorption of ammonia or organic matter in swine wastewater, and so substantially improved the power generation, energy efficiency, and Coulombic efficiency. A smaller external resistor in the circuit was also observed to promote the organic matter degradation and thus to shorten the treatment time. Overall, air-cathode MFCs are promising for generating electrical power from livestock wastewater and meanwhile reducing the level of organic matter and nutrients.

  9. Ultra-fast and highly efficient removal of cadmium ions by magnetic layered double hydroxide/guargum bionanocomposites.

    Science.gov (United States)

    Dinari, Mohammad; Tabatabaeian, Reyhane

    2018-07-15

    Finding effective methodologies for the removal of heavy metals from contaminated water are really significant. Facile and "green" techniques for adsorbents fabrication are in high demand to satisfy a wide range of practical applications. This report presents of an efficient method for preparing Fe 3 O 4 @ layered double hydroxide@ guargum bionanocomposites (GLF-BNCs). First of all, the LDH coated Fe 3 O 4 nanoparticles were simply synthesized, using ultrasonic irradiation. The citrate coated Fe 3 O 4 nanoparticles which were under negative charging and LDH nanocrystals which were charged positively make electrostatic interaction which formed a stable self-assembly component, and then guargum as a biopolymer were linked onto Fe 3 O 4 @LDH via an in situ growth method. Furthermore, the GLF-BNCs had the ability to remove cadmium ions (Cd 2+ ) from the aqueous solutions. Adsorption studies indicate that the Langmuir isotherm model and the kinetic model in pseudo-second order were appropriate for Cd(II) removal. The maximum Cd(II) adsorption capacity of the GLF8% was 258 mg g -1 . The Cd(II) was adsorbed from aqueous solutions very quickly with the contact time of 5 min by the GLF 8%, suggesting that GLF-BNCs may be a promising adsorbent for removing Cd(II) from wastewater. The effect of Fe 3 O 4 @LDH contents (2, 4 and 8 wt.%) on the thermal, physicomechanical, and morphological properties of guargum were investigated by Fourier transform infrared spectroscopy, X-ray diffraction (XRD), thermal gravimetric analysis (TGA), field emission scanning electron microscopy, transmission electron microscopy (TEM), Energy-dispersive X-ray spectroscopy and Brunauer-Emmett-Teller (BET) specific surface area techniques. The TEM results indicated that the LDH platelets are distributed within the polymer matrix. Copyright © 2018 Elsevier Ltd. All rights reserved.

  10. Medical application of laser hair removal

    International Nuclear Information System (INIS)

    Fadlalla, Alwalled Hussein Ataalmannan

    2015-12-01

    The use of laser in medical treatment has become of paramount importance proportional to what has high therapeutic privileges such as speed and accuracy in penetrating tissues and high quality especially when used in hair removal which is the subject of our study, this laser operates cards may cause some change in the color of the skin when used in a manner that is correct ratio of the thermal impact force in the laser hair removal process, or if it is exposed directly to his eye. This study is a comparison between the physical properties of laser of lasers used in hair removal, according to previous studies to be the basis for the benefit of doctors who use lasers for hair removal. The aim of this study was to study the effect of laser hair removal using the Nd: YAG laser with a wavelength 1064 nm as well as the risks airing from the assessment. The aim of this study was to identify the appropriate laser energy that absorbed in the hair follicle with a dark color and the appropriate thermal effect occurs to vaporize the follicle cell, a 40 J/cm"2 is to be significant without side effects for healthy tissue. In this study doses for a few laser beam is considered when compared to previous studies. Laser danger to the patient during the operation increases with increasing laser energy emitted during treatment. Laser hair removal by the user and energy emitted by wavelength of the laser device also depends on the hair color and roughness as well as skin color. (Author)

  11. High School Dropouts: Implications in the Economic Development of West Virginia. Research Paper 9909.

    Science.gov (United States)

    De Sousa, Semoa C. B.; Gebremedhin, Tesfa

    Despite increased government investments in education, West Virginia continues to have one of the nation's highest high school dropout rates and is among the states with the highest unemployment rates. Human capital theory provides the conceptual basis for evaluating the relationship between investment in education and economic development. An…

  12. Hair Removal

    Science.gov (United States)

    ... Staying Safe Videos for Educators Search English Español Hair Removal KidsHealth / For Teens / Hair Removal What's in ... you need any of them? Different Types of Hair Before removing hair, it helps to know about ...

  13. Salt removal from tanks containing high-level radioactive waste

    International Nuclear Information System (INIS)

    Kiser, D.L.

    1981-01-01

    At the Savannah River Plant (SRP), there are 23 waste storage tanks containing high-level radioactive wastes that are to be retired. These tanks contain about 23 million liters of salt and about 10 million liters of sludge, that are to be relocated to new Type III, fully stress-relieved tanks with complete secondary containment. About 19 million liters of salt cake are to be dissolved. Steam jet circulators were originally proposed for the salt dissolution program. However, use of steam jet circulators raised the temperature of the tank contents and caused operating problems. These included increased corrosion risk and required long cooldown periods prior to transfer. Alternative dissolution concepts were investigated. Examination of mechanisms affecting salt dissolution showed that the ability of fresh water to contact the cake surface was the most significant factor influencing dissolution rate. Density driven and mechanical agitation techniques were developed on a bench scale and then were demonstrated in an actual waste tank. Actual waste tank demonstrations were in good agreement with bench-scale experiments at 1/85 scale. The density driven method utilizes simple equipment, but leaves a cake heel in the tank and is hindered by the presence of sludge or Zeolite in the salt cake. Mechanical agitation overcomes the problems found with both steam jet circulators and the density driven technique and is the best method for future waste tank salt removal

  14. Banana peel: a green and economical sorbent for the selective removal of Cr(VI) from industrial wastewater.

    Science.gov (United States)

    Memon, Jamil R; Memon, Saima Q; Bhanger, Muhammad I; El-Turki, Adel; Hallam, Keith R; Allen, Geoffrey C

    2009-05-01

    This study describes the use of banana peel, a commonly produced fruit waste, for the removal of Cr(VI) from industrial wastewater. The parameters pH, contact time, initial metal ion concentration, and temperature were investigated and the conditions resulting in rapid and efficient adsorption (95% within 10 min) were determined. The binding of metal ions was found to be pH dependent with the optimal sorption occurring at pH 2. The retained species were eluted with 5 mL of 2M H(2)SO(4). To elucidate the mechanism of the process, total amounts of chromium and Cr(VI) were analyzed using flame atomic absorption and ultraviolet-visible (UV-vis) spectroscopic techniques, respectively. The Langmuir and Dubinin-Radushkevich (D-R) isotherms were used to describe the partitioning behavior for the system at different temperatures. Kinetics and thermodynamics of Cr(VI) removal by banana peel were also studied. The influence of diverse ions on the sorption behavior revealed that only Fe(II) ions (of those tested) suppressed the sorption of Cr(VI) ions to some extent. The method was applied for the removal of Cr(VI) from industrial wastewater.

  15. The Use of Electrocoagulation Process for Removal of Turbidity, COD, Detergent and Phosphorus from Carwash Effluent

    Directory of Open Access Journals (Sweden)

    Afshin Takdastan

    2011-10-01

    Full Text Available This study evaluated the efficiency of Electrical coagulation process in removal of COD, turbidity, detergent and phosphate from carwash effluent. An experimental study in laboratory scale was carried out and a glass tank with volume of 3 liters (effective volume of 2 liters containing 4 electrode-page iron and aluminum (AL-AL, AL-Fe, Fe-Fe were used. Electrodes were connected to a power supply with using bipolar method to convert alternative electricity to direct current. Daily samples were collected from different carwash effluents. Initial pH of samples were reported between 7 to 9.At first different tests were performed on primary samples. Percentage of removal was calculated in range pH and electrical potential of 11, 7, 3 and 30, 20, 10 volts respectively. Reaction times were set 90, 60, 30 minutes with middle intervals of 2 cm. The results showed the efficiency of COD removal in the optimum range of  pH=3, voltage of 30 and retention time of 90 minutes removal efficiency in pH of 7 after 90 minutes retention time, voltage of 30, with aluminum electrode reached more than 99%. According to the results obtained electrical energy consumption in aluminum electrodes was less than others. However aluminum is more expensive than iron and the difference in energy consumption between iron and aluminum can be ingnored. Apart from that COD and detergent removal efficiency of iron electrodes is higher than aluminum electrodes therefore, using iron as the electrode is more economical and recommended. Altogether it was found that this method can be use as a safe and convenient method for treating carwash effluent and according to the high removal efficiency of process, effluent can be discharged safely into the environment.

  16. Aqueous phosphate removal using nanoscale zero-valent iron

    International Nuclear Information System (INIS)

    Almeelbi, Talal; Bezbaruah, Achintya

    2012-01-01

    Nanoscale zero-valent iron (NZVI) particles have been used for the remediation of a wide variety of contaminants. NZVI particles have high reactivity because of high reactive surface area. In this study, NZVI slurry was successfully used for phosphate removal and recovery. Batch studies conducted using different concentrations of phosphate (1, 5, and 10 mg PO 4 3− -P/L with 400 mg NZVI/L) removed ∼96 to 100 % phosphate in 30 min. Efficacy of the NZVI in phosphate removal was found to 13.9 times higher than micro-ZVI (MZVI) particles with same NZVI and MZVI surface area concentrations used in batch reactors. Ionic strength, sulfate, nitrate, and humic substances present in the water affected in phosphate removal by NZVI but they may not have any practical significance in phosphate removal in the field. Phosphate recovery batch study indicated that better recovery is achieved at higher pH and it decreased with lowering of the pH of the aqueous solution. Maximum phosphate recovery of ∼78 % was achieved in 30 min at pH 12. The successful rapid removal of phosphate by NZVI from aqueous solution is expected to have great ramification for cleaning up nutrient rich waters.

  17. Cascading costs: an economic nitrogen cycle.

    Science.gov (United States)

    Moomaw, William R; Birch, Melissa B L

    2005-09-01

    The chemical nitrogen cycle is becoming better characterized in terms of fluxes and reservoirs on a variety of scales. Galloway has demonstrated that reactive nitrogen can cascade through multiple ecosystems causing environmental damage at each stage before being denitrified to N(2). We propose to construct a parallel economic nitrogen cascade (ENC) in which economic impacts of nitrogen fluxes can be estimated by the costs associated with each stage of the chemical cascade. Using economic data for the benefits of damage avoided and costs of mitigation in the Chesapeake Bay basin, we have constructed an economic nitrogen cascade for the region. Since a single ton of nitrogen can cascade through the system, the costs also cascade. Therefore evaluating the benefits of mitigating a ton of reactive nitrogen released needs to consider the damage avoided in all of the ecosystems through which that ton would cascade. The analysis reveals that it is most cost effective to remove a ton of nitrogen coming from combustion since it has the greatest impact on human health and creates cascading damage through the atmospheric, terrestrial, aquatic and coastal ecosystems. We will discuss the implications of this analysis for determining the most cost effective policy option for achieving environmental quality goals.

  18. PROJECT-SPECIFIC TYPE A VERIFICATION FOR THE HIGH FLUX BEAM REACTOR UNDERGROUND UTILITIES REMOVAL PHASE 2 D/F WASTE LINE REMOVAL, BROOKHAVEN NATIONAL LABORATORY UPTON, NEW YORK

    International Nuclear Information System (INIS)

    Weaver, P.C.

    2010-01-01

    Oak Ridge Institute for Science and Education (ORISE) has reviewed the project documentation and data for the High Flux Beam Reactor (HFBR) Underground Utilities removal Phase 2; the D/F Waste Line removal at Brookhaven National Laboratory (BNL) in Upton, New York. The Brookhaven Survey Group (BSG) has completed removal and performed the final status survey (FSS) of the D/F Waste Line that provided the conduit for pumping waste from Building 750 to Building 801. Sample results have been submitted as required to demonstrate that the cleanup goals of 15 mrem/yr above background to a resident in 50 years have been met. Four rounds of sampling, from pre-excavation to final status survey (FSS), were performed as specified in the Field Sampling Plan (FSP) (BNL 2010a). It is the policy of the US Departmental of Energy (DOE) to perform independent verifications of decontamination and decomissioning activities conducted at DOE facilities. ORISE has been designated as the organization responsible for this task at the HFBR. ORISE together with DOE determined that a Type A verification of the D/F Waste Line was appropriate based on its method of construction and upon the minimal potential for residual radioactivity in the area. The removal of underground utilities is being performed in three stages in the process to decommission the HFBR facility and support structures. Phase 2 of this project included the grouting and removal of 1100 feet of 2-inch pipe and 640 feet of 4-inch pipe that served as the D/F Waste Line. Based on the pre-excavation sample results of the soil overburden, the potential for contamination of the soil surrounding the pipe is minimal (BNL 2010a). ORISE reviewed the BNL FSP and identified comments for consideration (ORISE 2010). BNL prepared a revised FSP that addressed each ORISE comment adequately (BNL 2010a). ORISE referred to the revised Phase 2 D/F Waste Line removal FSP FSS data to conduct the Type A verification and determine whether the intent odf

  19. Development of a new decay heat removal system for a high temperature gas-cooled reactor

    International Nuclear Information System (INIS)

    Sim, Yoon Sub; Park, Rae Young; Kim, Seyun

    2007-01-01

    The heat removal capacity of a RCCS is one of the major parameters limiting the capacity of a HTGR based on a passive safety system. To improve the plant economy of a HTGR, the decay heat removal capacity needs to be improved. For this, a new analysis system of an algebraic method for the performance of various RCCS designs was set up and the heat transfer characteristics and performance of the designs were analyzed. Based on the analysis results, a new passive decay heat removal system with a substantially improved performance, LFDRS was developed. With the new system, one can have an expectation that the heat removal capacity of a HTGR could be doubled

  20. Alternatives for biodigester effluent treatment: economic impact; Impacto economico de um sistema de tratamento dos efluentes de biodigestores

    Energy Technology Data Exchange (ETDEWEB)

    Miele, Marcelo; Kunz, Airton; Correa, Juliano Corulli; Steinmetz, Ricardo [EMBRAPA Suinos e Aves, Concordia, SC (Brazil)], email: marcelo@cnpsa.embrapa.br; Bortoli, Marcelo [Universidade Federal de Santa Catarina, (UFSC), Florianopolis, SC (Brazil)

    2011-07-01

    The aim of this study was to present a prospective economic impact assessment of a biodigester liquid effluent treatment system. This system developed by Embrapa Swine and Poultry is composed by a N removal module and a P one, which can be attached to a biodigester, technology widely diffused in Brazil. Biodigesters do not remove nutrients (NPK) with high pollution potential of water resources and demanding high effluent transport costs. The analysis was based on Net Present Value (NPV) technique, using prototype performance information, market prices and wastewater analysis. The N module reduces more than ten times the surface needed to spread effluents. The P module attains the standard for discharge in water resources and makes this element available as fertilizer. The system has a significant impact on swine production costs, what can be reduced in farms which produces its own energy from manure. High effluent distribution costs also turn treatment more attractive. The study concludes that this is a promising technology which has to be validated. Financial support is needed to implement a real scale prototype to validate it. (author)

  1. Passive heat removal in CANDU

    International Nuclear Information System (INIS)

    Hart, R.S.

    1997-01-01

    CANDU has a tradition of incorporating passive systems and passive components whenever they are shown to offer performance that is equal to or better than that of active systems, and to be economic. Examples include the two independent shutdown systems that employ gravity and stored energy respectively, the dousing subsystem of the CANDU 6 containment system, and the ability of the moderator to cool the fuel in the event that all coolant is lost from the fuel channels. CANDU 9 continues this tradition, incorporating a reserve water system (RWS) that increases the inventory of water in the reactor building and profiles a passive source of makeup water and/or heat sinks to various key process systems. The key component of the CANDU 9 reserve water system is a large (2500 cubic metres) water tank located at a high elevation in the reactor building. The reserve water system, while incorporating the recovery system functions, and the non-dousing functions of the dousing tank in CANDU 6, embraces other key systems to significantly extend the passive makeup/heat sink capability. The capabilities of the reserve water system include makeup to the steam generators secondary side if all other sources of water are lost; makeup to the heat transport system in the event of a leak in excess of the D 2 O makeup system capability; makeup to the moderator in the event of a moderator leak when the moderator heat sink is required; makeup to the emergency core cooling (ECC) system to assure NPSH to the ECC pumps during a loss of coolant accident (LOCA), and provision of a passive heat sink for the shield cooling system. Other passive designs are now being developed by AECL. These will be incorporated in future CANDU plants when their performance has been fully proven. This paper reviews the passive heat removal systems and features of current CANDU plants and the CANDU 9, and briefly reviews some of the passive heat removal concepts now being developed. (author)

  2. Innovative Highly Selective Removal of Cesium and Strontium Utilizing a Newly Developed Class of Inorganic Ion Specific Media - 16221

    International Nuclear Information System (INIS)

    Denton, Mark S.; Kanatzidis, Mercouri G.

    2009-01-01

    Highly selective removal of Cesium and Strontium is critical for waste treatment and environmental remediation. Cesium-137 is a beta-gamma emitter and Strontium-90 is a beta emitter with respective half-lives of 30 and 29 years. Both elements are present at many nuclear sites. Cesium and Strontium can be found in wastewaters at Washington State's Hanford Site, as well as in waste streams of many Magnox reactor sites. Cesium and Strontium are found in the Reactor Coolant System of light water reactors at nuclear power plants. Both elements are also found in spent nuclear fuel and in high-level waste (HLW) at DOE sites. Cesium and Strontium are further major contributors to the activity and the heat load. Therefore, technologies to extract Cesium and Strontium are critical for environmental remediation waste treatment and dose minimization. Radionuclides such as Cesium-137 and Strontium-90 are key drivers of liquid waste classification at light water reactors and within the DOE tank farm complexes. The treatment, storage, and disposal of these wastes represents a major cost for nuclear power plant operators, and comprises one of the most challenging technology-driven projects for the DOE Environmental Management (EM) program. Extraction technologies to remove Cesium and Strontium have been an active field of research. Four notable extraction technologies have been developed so far for HLW: solvent extraction, prussian blue, crystalline silico-titanate (CST) and organic ion-exchangers (e.g., resorcinol formaldehyde and SuperLig). The use of one technology over another depends on the specific application. For example, the waste treatment plant (WTP) at Hanford is planning on using a highly-selective organic ion-exchange resin to remove Cesium and Strontium. Such organic ion-exchangers use molecular recognition to selectively bind to Cesium and Strontium. However, these organic ion-exchangers are synthesized using multi-step organic synthesis. The associated cost to

  3. Removal of Cr{sup 6+} from wastewater via adsorption with high-specific-surface-area nitrogen-doped hierarchical porous carbon derived from silkworm cocoon

    Energy Technology Data Exchange (ETDEWEB)

    Sun, Junting; Zhang, Zhengping; Ji, Jing; Dou, Meiling, E-mail: douml@mail.buct.edu.cn; Wang, Feng, E-mail: wangf@mail.buct.edu.cn

    2017-05-31

    Highlights: • The nitrogen-doped hierarchical porous carbon was prepared from silkworm cocoon. • The NHPC possesses a unique porous structure and a high specific surface area. • The NHPC presents superior adsorption performance for Cr (VI). • The NHPC exhibits an excellent recyclability for the removal of Cr (VI). - Abstract: The development of highly efficient adsorbents is an effective way to remove Cr{sup 6+} from wastewater for environment protection. Herein, a high-specific-surface-area nitrogen-doped hierarchical porous carbon (NHPC) derived from silkworm cocoon was synthesized and applied as an efficient adsorbent for the removal of Cr{sup 6+} from wastewater. The resultant NHPC possesses a specific surface area as high as 3134 m{sup 2} g{sup −1} and a unique hierarchical porous structure with a large number of small mesopores (2–4 nm) and micropores (0.8–2 nm) embedded in the sidewall of bowl-like macropores (200–300 nm), in which sufficient exposure of adsorption sites and high-flow transfer of Cr{sup 6+} ions can be achieved. As a result, the NHPC exhibits a remarkable adsorption performance with a larger adsorption capacity (366.3 mg g{sup −1}), a higher adsorption rate (4 × 10{sup −2} g mg{sup −1} min{sup −1}) and a superior recyclability in comparison with the commercial adsorbent (Norit CGP). Thermodynamic and kinetic analyses indicate that the adsorption process is spontaneous and endothermic, which fits well with the pseudo-second-order kinetic model and Langmuir isotherm model. This biomass-based porous carbon with well-defined hierarchical porous structure can be applied as a promising adsorbent for the removal of Cr{sup 6+} from wastewater.

  4. Hollow fiber contractors for simultaneous SO{sub x}/NO{sub x} removal

    Energy Technology Data Exchange (ETDEWEB)

    Bhown, A.S.; Pakala, N.R.; Riggs, T. [SRI International, Menlo Park, CA (United States)] [and others

    1995-11-01

    Control of SO{sub x} and NO{sub x} emissions from coal-fired utility and industrial boilers is a topic of growing national and international importance. Whereas a host of commercial and semicommercial processes exist, increasingly stringent emission standards mandate that processes be low cost, highly efficient, and, ideally, produce marketable byproducts. Although a wide range of site-specific economic factors dictate the best choice of SO{sub x} and NO{sub x} control, removal of SO{sub 2} by wet limestone scrubbing and removal of NO{sub x} by selective catalytic reduction (SCR) are regarded as the best commercialized technologies for this application. A typical wet limestone plant requires approximately $100 to $120 of capital investment per kilowatt of electric power generating capacity and has power and miscellaneous operating costs in the range of 5 to 6 mils per kilowatt hour (kWh). The SCR process requires approximately $70 to $100 of capital investment per kilowatt of electric power generating capacity. Its operating costs, including ammonia consumption, is in the range of 1.8 to 2.2 mils per kWh. These costs can add approximately 20% to the final cost of generated electricity, a significant burden on rate payers.

  5. The Use of Reverse Osmosis for the Removal of As(III) and As(V) in Drinking Water

    OpenAIRE

    Garcia Ortiz, Christian Adriana

    2012-01-01

    The following thesis project was designed to collect data on the use of reverse osmosis for arsenic removal in drinking water and to explore economic methods for sample analysis with emphasis on the use of an ion exchange resin for arsenic speciation. The data collected was meant for verification of existing results, finding an optimal operating point for the reverse osmosis unit provided by Malthe Winje DWS, and to determine whether double filtration by reverse osmosis increases the removal ...

  6. Cost effectiveness of methods for removing radium and thorium in uranium mining

    International Nuclear Information System (INIS)

    Rogers, V.C.; Nielson, K.K.

    1981-01-01

    The potential health impact from uranium milling operations is mainly associated with long-term releases of radioactive contaminants from the mill tailings. The major mechanisms for mitigating these potential releases focus on increasing the tailings containment with the addition of migration barriers such as thick earthern covers and clay liners. Some limited investigation has also focused on reducing the radionuclide source terms. This alternative approach has some desirable features, but stringent cost requirements are placed upon source removal methods in order for them to be economically favorable. A cost effectiveness evaluation is presented herein, in which costs for containment methods are used to establish maximum cost guidelines for the source removal methods

  7. Organic contaminant removal efficiency of sodium bentonite/clay (BC) mixtures in high permeability regions utilizing reclaimed wastewater: A meso-scale study

    Science.gov (United States)

    Xiao, Yang; Li, Yunkai; Ning, Zigong; Li, Pengxiang; Yang, Peiling; Liu, Chengcheng; Liu, Zhongwei; Xu, Feipeng; Hynds, Paul Dylan

    2018-03-01

    Wastewater reclamation now represents an effective measure for sustainable water resource management in arid regions, however wastewater components (organic micropollutants) may potentially impact local ecological and/or human health. Previous studies have shown that sodium bentonite/natural clay (BC) mixes may be used to effectively reduce riverbed infiltration in regions characterized by excessively high hydraulic conductivity. Accordingly, the current study sought to investigate the contaminant removal efficiency (Re) of several BC mass ratios in simulated dry riverbeds. Results indicate that the measured Re of NH4+-N, CODcr and BOD5 increased in concurrence with an increasing sodium bentonite ratio, up to a maximum Re of 97.4% (NH4+-N), 55.2% (CODcr), and 51.5% (BOD5). The primary contaminant removal site was shown to be the infiltration-reducing (BC) layer, accounting for approximately 40%, 60%, and 70% of NH4+-N, CODcr and BOD5 removal, respectively. Conversely, the removal efficiency of NO3-N was found to be low (managing recharge of non-potable aquifers with reclaimed wastewater.

  8. A hardware architecture for real-time shadow removal in high-contrast video

    Science.gov (United States)

    Verdugo, Pablo; Pezoa, Jorge E.; Figueroa, Miguel

    2017-09-01

    Broadcasting an outdoor sports event at daytime is a challenging task due to the high contrast that exists between areas in the shadow and light conditions within the same scene. Commercial cameras typically do not handle the high dynamic range of such scenes in a proper manner, resulting in broadcast streams with very little shadow detail. We propose a hardware architecture for real-time shadow removal in high-resolution video, which reduces the shadow effect and simultaneously improves shadow details. The algorithm operates only on the shadow portions of each video frame, thus improving the results and producing more realistic images than algorithms that operate on the entire frame, such as simplified Retinex and histogram shifting. The architecture receives an input in the RGB color space, transforms it into the YIQ space, and uses color information from both spaces to produce a mask of the shadow areas present in the image. The mask is then filtered using a connected components algorithm to eliminate false positives and negatives. The hardware uses pixel information at the edges of the mask to estimate the illumination ratio between light and shadow in the image, which is then used to correct the shadow area. Our prototype implementation simultaneously processes up to 7 video streams of 1920×1080 pixels at 60 frames per second on a Xilinx Kintex-7 XC7K325T FPGA.

  9. Calcium carbonate in the removal of iron and lead from dilute waste water

    Energy Technology Data Exchange (ETDEWEB)

    Hautala, E; Randall, J; Goodban, A; Waiss, A Jr

    1977-01-01

    The utility of powdered CaCO/sub 3/ in the removal of lead and iron from dilute aqueous waste waters has been demonstrated and the results successfully applied to treat industrial waste water from a lead battery plant. The reclaimed water is suitable for recycling to the plant and is now being utilized with consequent economic advantages.

  10. Adsorption combined with superconducting high gradient magnetic separation technique used for removal of arsenic and antimony.

    Science.gov (United States)

    Qi, Zenglu; Joshi, Tista Prasai; Liu, Ruiping; Li, Yiran; Liu, Huijuan; Qu, Jiuhui

    2018-02-05

    Manganese iron oxide (MnFe 2 O 4 ), an excellent arsenic(As)/antimony(Sb) removal adsorbent, is greatly restricted for the solid-liquid separation. Through the application of superconducting high gradient magnetic separation (HGMS) technique, we herein constructed a facility for the in situ solid-liquid separation of micro-sized MnFe 2 O 4 adsorbent in As/Sb removal process. To the relative low initial concentration 50.0μgL -1 , MnFe 2 O 4 material sorbent can still decrease As or Sb below US EPA's drinking water standard limit. The separation of MnFe 2 O 4 was mainly relied on the flow rate and the amount of steel wools in the HGMS system. At a flow rate 1Lmin -1 and 5% steel wools filling rate, the removal efficacies of As and Sb in natural water with the system were achieved to be 94.6% and 76.8%, respectively. At the meantime, nearly 100% micro-sized MnFe 2 O 4 solid in the continuous field was readily to be separated via HGMS system. In a combination with the experiment results and finite element simulation, the separation was seemed to be independent on the magnetic field intensity, and the maximum separation capacities in various conditions were well predicted using the Thomas model (R 2 =0.87-0.99). Copyright © 2017 Elsevier B.V. All rights reserved.

  11. REMOVAL OF REACTIVE DYES FROM WASTEWATER OF TEXTILE INDUSTRIES BY USING ENVIRONMENTAL FRIENDLY ADSORBENTS

    Directory of Open Access Journals (Sweden)

    ALAM Md Shamim

    2016-05-01

    Full Text Available This paper is aimed at developing a method to treat wastewater by using inexpensive adsorbents. Textile industries produce wastewater, otherwise known as effluent, as a bi-product of their production. The effluent contains several pollutants. Among the various stages of textile production, the operations in the dyeing plant, which include pre-treatments, dyeing, printing and finishing, produce the most pollution. The textile dyeing wastes contain unused or partially used organic compounds, and high level of different pollutants. They are often of strong color and may also be of high temperature. When disposed into water bodies or onto land these effluents will result in the deterioration of ecology and damage to aquatic life. Furthermore they may cause damage to fisheries and economic loss to fishermen and farmer, there may be impacts on human health which can be removed with the help of an effluent treatment plant (ETP. The “clean” water can then be safely discharged into the environment and ultimately save our environment from pollution. In this study, rice husk and cotton dust were used as an adsorbent. In this research work waste water was characterized with this useless adsorbents. The parameters which were tested in this study are DO, BOD, COD, TS, TDS and TSS. The results showed that the selected bio adsorbents have good potential for removal of reactive dyes from textile effluent.

  12. Economic analysis of multiple-module high temperature gas-cooled reactor (MHTR) nuclear power plants

    International Nuclear Information System (INIS)

    Liu Yu; Dong Yujie

    2011-01-01

    In recent years, as the increasing demand of energy all over the world, and the pressure on greenhouse emissions, there's a new opportunity for the development of nuclear energy. Modular High Temperature Gas-cooled Reactor (MHTR) received recognition for its inherent safety feature and high outlet temperature. Whether the Modular High Temperature Gas-cooled Reactor would be accepted extensively, its economy is a key point. In this paper, the methods of qualitative analysis and the method of quantitative analysis, the economic models designed by Economic Modeling Working Group (EMWG) of the Generation IV International Forum (GIF), as well as the HTR-PM's main technical features, are used to analyze the economy of the MHTR. A prediction is made on the basis of summarizing High Temperature Gas-cooled Reactor module characteristics, construction cost, total capital cost, fuel cost and operation and maintenance (O and M) cost and so on. In the following part, comparative analysis is taken measures to the economy and cost ratio of different designs, to explore the impacts of modularization and standardization on the construction of multiple-module reactor nuclear power plant. Meanwhile, the analysis is also adopted in the research of key factors such as the learning effect and yield to find out their impacts on the large scale development of MHTR. Furthermore, some reference would be provided to its wide application based on these analysis. (author)

  13. Evaluation and comparison of aluminum-coated pumice and zeolite in arsenic removal from water resources

    Directory of Open Access Journals (Sweden)

    Heidari Masoumeh

    2012-12-01

    Full Text Available Abstract In this research the potential of aluminum-coated pumice and zeolite in arsenic, As (V removal was investigated and compared. Scanning Electron Microscopy (SEM, X-Ray Diffraction (XRD and X-Ray Flaorescence Spectrometry (XRF were carried out to determine the properties of the adsorbents. Several parameters including adsorbent dosage] pH, contact time, and initial As(V concentration were studied. The optimum pH obtained for both adsorbents was pH = 7. As(V adsorption by both adsorbents followed the Freundlich isotherm (for aluminum-coated pumice and zeolite respectively with R2 > 0.98 and R2 > 0.99. The obtained data from kinetics showed that the pseudo-second order model could better explain As(V adsorption for both aluminum-coated pumice and zeolite (R2 > 0.98 and R2 > 0.99 respectively. Because of low cost, both adsorbents may be economically used, but aluminum-coated zeolite showed high efficiency of, due to its porosity and surface area. More than 96% of As(V with initial concentration of 250 μg/L was removed by 10 g/L aluminum-coated zeolite at pH = 7 and in 60 minutes to achieve As(V concentration of 10 μg/L, while only 71% of As(V could be removed by aluminum-coated pumice.

  14. Manganese-Loaded Activated Carbon for the Removal of Organosulfur Compounds from High-Sulfur Diesel Fuels

    OpenAIRE

    Al-Ghouti, M.A.; Al-Degs, Y.S.

    2014-01-01

    The adsorptive capacity of activated carbon (AC) is significantly enhanced toward weakly interacting organosulfur compounds (OSC) from sulfur-rich diesel fuel. Sulfur compounds are selectively removed from diesel after surface modification by manganese dioxide (MnO2). A selective surface for OSC removal was created by loading MnO2 on the surface; π-complexation between the partially filled d-orbitals of Mn4+ and the S atom is the controlling mechanism for OSC removal. Principal component anal...

  15. Investigating the Visual-Motor Integration Skills of 60-72-Month-Old Children at High and Low Socio-Economic Status as Regard the Age Factor

    Science.gov (United States)

    Ercan, Zülfiye Gül; Ahmetoglu, Emine; Aral, Neriman

    2011-01-01

    This study aims to define whether age creates any differences in the visual-motor integration skills of 60-72 months old children at low and high socio-economic status. The study was conducted on a total of 148 children consisting of 78 children representing low socio-economic status and 70 children representing high socio-economic status in the…

  16. Technology in the Aid of Delivering Economic Content to Teachers: Virtual Economics v. 3

    Directory of Open Access Journals (Sweden)

    John R. Swinton

    2012-01-01

    Full Text Available We examine the impact on student achievement of a face-to-face teacher workshop that also provides economics instructors with access to an electronic library of instructional and reference material for their economics classroom—Virtual Economics v. 3 (VE3, offered by the Council for Economic Education. Based on evidence using student and teacher-level administrative data from the Georgia Department of Education and controlling for students’ prior achievement in mathematics, we find evidence that the VE3 workshop experience increases student achievement in high school economics. Our difference-in-differences estimates suggest that teacher participation in the VE3 workshop increases student achievement by 0.061 standard deviations on Georgia’s high stakes economics end-of-course test. Future research should seek estimating the effect of treatments in education such as the VE3 workshop using randomized controlled trials (RCT.

  17. Advanced Hydraulic Studies on Enhancing Particle Removal

    DEFF Research Database (Denmark)

    He, Cheng

    clarifier. The inlet zone of an existing rectangular storm water clarifier was redesigned to improve the fluid flow conditions and reduce the hydraulic head loss in order to remove the lamellar plates and adapt the clarifier to the needs of high-rate clarification of storm water with flocculant addition...... excessive local head losses and helped to select structural changes to reduce such losses. The analysis of the facility showed that with respect to hydraulic operation, the facility is a complex, highly non-linear hydraulic system. Within the existing constraints, a few structural changes examined......The removal of suspended solids and attached pollutants is one of the main treatment processes in wastewater treatment. This thesis presents studies on the hydraulic conditions of various particle removal facilities for possible ways to increase their treatment capacity and performance by utilizing...

  18. Efficient removal of cesium from low-level radioactive liquid waste using natural and impregnated zeolite minerals.

    Science.gov (United States)

    Borai, E H; Harjula, R; Malinen, Leena; Paajanen, Airi

    2009-12-15

    The objective of the proposed work was focused to provide promising solid-phase materials that combine relatively inexpensive and high removal capacity of some radionuclides from low-level radioactive liquid waste (LLRLW). Four various zeolite minerals including natural clinoptilolite (NaNCl), natural chabazite (NaNCh), natural mordenite (NaNM) and synthetic mordenite (NaSM) were investigated. The effective key parameters on the sorption behavior of cesium (Cs-134) were investigated using batch equilibrium technique with respect to the waste solution pH, contacting time, potassium ion concentration, waste solution volume/sorbent weight ratio and Cs ion concentration. The obtained results revealed that natural chabazite (NaNCh) has the higher distribution coefficients and capacity towards Cs ion rather than the other investigated zeolite materials. Furthermore, novel impregnated zeolite material (ISM) was prepared by loading Calix [4] arene bis(-2,3 naphtho-crown-6) onto synthetic mordenite to combine the high removal uptake of the mordenite with the high selectivity of Calix [4] arene towards Cs radionuclide. Comparing the obtained results for both NaSM and the impregnated synthetic mordenite (ISM-25), it could be observed that the impregnation process leads to high improvement in the distribution coefficients of Cs+ ion (from 0.52 to 27.63 L/g). The final objective in all cases was aimed at determining feasible and economically reliable solution to the management of LLRLW specifically for the problems related to the low decontamination factor and the effective recovery of monovalent cesium ion.

  19. Efficient removal of cesium from low-level radioactive liquid waste using natural and impregnated zeolite minerals

    International Nuclear Information System (INIS)

    Borai, E.H.; Harjula, R.; Malinen, Leena; Paajanen, Airi

    2009-01-01

    The objective of the proposed work was focused to provide promising solid-phase materials that combine relatively inexpensive and high removal capacity of some radionuclides from low-level radioactive liquid waste (LLRLW). Four various zeolite minerals including natural clinoptilolite (NaNCl), natural chabazite (NaNCh), natural mordenite (NaNM) and synthetic mordenite (NaSM) were investigated. The effective key parameters on the sorption behavior of cesium (Cs-134) were investigated using batch equilibrium technique with respect to the waste solution pH, contacting time, potassium ion concentration, waste solution volume/sorbent weight ratio and Cs ion concentration. The obtained results revealed that natural chabazite (NaNCh) has the higher distribution coefficients and capacity towards Cs ion rather than the other investigated zeolite materials. Furthermore, novel impregnated zeolite material (ISM) was prepared by loading Calix [4] arene bis(-2,3 naphtho-crown-6) onto synthetic mordenite to combine the high removal uptake of the mordenite with the high selectivity of Calix [4] arene towards Cs radionuclide. Comparing the obtained results for both NaSM and the impregnated synthetic mordenite (ISM-25), it could be observed that the impregnation process leads to high improvement in the distribution coefficients of Cs + ion (from 0.52 to 27.63 L/g). The final objective in all cases was aimed at determining feasible and economically reliable solution to the management of LLRLW specifically for the problems related to the low decontamination factor and the effective recovery of monovalent cesium ion.

  20. Nitrogen Removal by Anammox Biofilm Column Reactor at Moderately Low Temperature

    Directory of Open Access Journals (Sweden)

    Tuty Emilia Agustina

    2017-10-01

    Full Text Available The anaerobic ammonium oxidation (anammox as a new biological approach for nitrogen removal has been considered to be more cost-effective compared with the combination of nitrification and denitrification process. However, the anammox bioreactors are mostly explored at high temperature (>300C in which temperature controlling system is fully required. This research was intended to develop and to apply anammox process for high nitrogen concentration removal at ambient temperature used for treating wastewater in tropical countries. An up-flow biofilm column reactor, which the upper part constructed with a porous polyester non-woven fabric material as a carrier to attach the anammox bacteria was operated without heating system. A maximum nitrogen removal rate (NRR of 1.05 kg-N m3 d-1 was reached in the operation days of 178 with a Total Nitrogen (TN removal efficiency of 74%. This showed the biofilm column anammox reactor was successfully applied to moderate high nitrogen removal from synthetic wastewater at moderately low temperature. Keywords: Anammox, biofilm column reactor, ambient temperature, nitrogen removal

  1. Usefulness of ANN-based model for copper removal from aqueous solutions using agro industrial waste materials

    Directory of Open Access Journals (Sweden)

    Petrović Marija S.

    2015-01-01

    Full Text Available The purpose of this study was to investigate the adsorption properties of locally available lignocelluloses biomaterials as biosorbents for the removal of copper ions from aqueous solution. Materials are generated from juice production (apricot stones and from the corn milling process (corn cob. Such solid wastes have little or no economic value and very often present a disposal problem. Using batch adsorption techniques the effects of initial Cu(II ions concentration (Ci, amount of biomass (m and volume of metal solution (V, on biosorption efficiency and capacity were studied for both materials, without any pre-treatments. The optimal parameters for both biosorbents were selected depending on a highest sorption capability of biosorbent, in removal of Cu(II. Experimental data were compared with second order polynomial regression models (SOPs and artificial neural networks (ANNs. SOPs showed acceptable coefficients of determination (0.842 - 0.997, while ANNs performed high prediction accuracy (0.980-0.986 in comparison to experimental results. [Projekat Ministarstva nauke Republike Srbije, br. TR 31003, TR 31055

  2. Removable Thin Films used for the Abatement and Mitigation of Beryllium

    International Nuclear Information System (INIS)

    Lumia, M.; Gentile, C.; Creek, K.; Sandoval, R.

    2003-01-01

    The use of removable thin films for the abatement of hazardous particulates has many advantages. Removable thin films are designed to trap and fix particulates in the film's matrix by adhesion. Thin films can be applied to an existing contaminated area to fix and capture the particulates for removal. The nature of the removable thin films, after sufficient cure time, is such that it can typically be removed as one continuous entity. The removable thin films can be applied to almost any surface type with a high success rate of removal

  3. Membrane Characteristics for Removing Particulates in PFC Wastes

    International Nuclear Information System (INIS)

    Kim, Gye Nam; Lee, Sung Yeol; Won, Hui Jun; Jung, Chong Hun; Oh, Won Zin; Park, Jin Ho

    2005-01-01

    Pc (Per fluorocarbon) decontamination process is one of best methods to remove hot particulate adhered at inside surface of hot cell and surface of equipment in hot cell. It was necessary to develop a particulate filtration equipment to reuse Pc solution used on Pc decontamination due to its high cost and to minimize the volume of second wastewater. Contamination characteristics of hot particulate were investigated and then a filtration process was presented to remove hot particulate in Pc solution generated through Pc decontamination process. The removal efficiency of Pvdf (Poly vinylidene fluoride), Pp (Polypropylene), Ceramic (Al 2 O 3 ) filter showed more than 95%. The removal efficiency of Pvdf filter was a little lower than those of other kiters at same pressure (3 psi). A ceramic filter showed a higher removal efficiency with other filters, while a little lower flux rate than other filters. Due to inorganic composition, a ceramic filter was highly stable against radio nuclides in comparison with Pvdf and Pp membrane, which generate H 2 gas in α-radioactivity atmosphere. Therefore, the adoption of ceramic filter is estimated to be suitable for the real nitration process.

  4. Application of agricultural fibers in pollution removal from aqueous solution

    International Nuclear Information System (INIS)

    Mahvi, A. H.

    2008-01-01

    Discharging different kinds of wastewater and polluted waters such as domestic, industrial and agricultural wastewaters into environment, especially to surface water, can cause heavy pollution of this body sources. With regard to increasing effluent discharge standards to the environment, high considerations should be made when selecting proper treatment processes. Any of chemical, biological and physical treatment processes have its own advantages and disadvantages. It should be kept in mind that economical aspects are important, too. In addition, employing environment friendly methods for treatment is emphasized much more these days. Application of some waste products that could help in this regard, in addition to reuse of these waste materials, can be an advantage, Agricultural fibers are agricultural wastes and are generated in high amounts. The majority of such materials is generated in developing countries and, since they are very cheap, they can be employed as bio sorbents in water and wastewater applications. Polluted surface waters, different wastewaters and partially treated wastewater may be contaminated by heavy metals or some organic matters and these waters should be treated to reduce pollution. The results of investigations show high efficiency of agricultural fibers in heavy metal and phenol removal. In this paper, some studies conducted by the author of this article and other investigators are reviewed

  5. Rapid Preparation of Biosorbents with High Ion Exchange Capacity from Rice Straw and Bagasse for Removal of Heavy Metals

    Directory of Open Access Journals (Sweden)

    Supitcha Rungrodnimitchai

    2014-01-01

    Full Text Available This work describes the preparation of the cellulose phosphate with high ion exchange capacity from rice straw and bagasse for removal of heavy metals. In this study, rice straw and bagasse were modified by the reaction with phosphoric acid in the presence of urea. The introduced phosphoric group is an ion exchangeable site for heavy metal ions. The reaction by microwave heating yielded modified rice straw and modified bagasse with greater ion exchange capacities (∼3.62 meq/g and shorter reaction time (1.5–5.0 min than the phosphorylation by oil bath heating. Adsorption experiments towards Pb2+, Cd2+, and Cr3+ ions of the modified rice straw and the modified bagasse were performed at room temperature (heavy metal concentration 40 ppm, adsorbent 2.0 g/L. The kinetics of adsorption agreed with the pseudo-second-order model. It was shown that the modified rice straw and the modified bagasse could adsorb heavy metal ions faster than the commercial ion exchange resin (Dowax. As a result of Pb2+ sorption test, the modified rice straw (RH-NaOH 450W removed Pb2+ much faster in the initial step and reached 92% removal after 20 min, while Dowax (commercial ion exchange resin took 90 min for the same removal efficiency.

  6. Economic evaluation of operational concepts for electrolysers with high proportions of renewable energies

    International Nuclear Information System (INIS)

    Michaelis, Julia; Wietschel, Martin

    2015-01-01

    This article examines different modes of electrolyzers in two future scenarios of the German energy system. It turns out that hydrolyzers need a high utilization to pay for themselves. An economic operation in 2030 in the scenario of moderate expansion of renewable energies is not possible. At strong expansion the investment is profitable when high revenues from secondary control power provision can be achieved. Generally it is clear that the secondary control power provision and also the direct sales of hydrogen in industry or in the transport sector allows higher revenues than the storage and reconversion. [de

  7. Evaluation of Macronet polymeric adsorbents for removal of PAHs from contaminated soil and groundwater

    International Nuclear Information System (INIS)

    Valderrama, C.; Gamisans, X.; Lao, C.; Farran, A.; Cortina, J.L.

    2005-01-01

    problem is the use of improved polymeric adsorbents as Hypersol Macronet resins that could be chemically regenerated. Hypersol Macronet resins present a hyper-reticulated structure that provides to the solid macro-porosity and micro-porosity at the same time. This means to have a control on the size pores and relatively high surface areas (1000-2000 m 2 /g). Then sorption barriers have been used as containment technology for PAHs. Groundwater velocity, barrier reactivity, and contaminant concentration among other factors affect the required size of the barrier. The reactivity of the barrier media should be determined from laboratory tests The present work describes the sorption properties (loading capacity and kinetic parameters) of Macronet polymeric adsorbent MN200. Batch experiments were performed to determine both equilibrium and kinetic parameters on the removal of different PAHs (Naphthalene, Acenaphthene Pyrene, Anthracene, Fluoranthene and Fluorene). Sorption parameters have been use to determine design parameters on the application of MN200 as reactive material in extractable PRBs. It is recognised that a fixed bed sorption process is operationally simple, however in order to be able and economically competitive, the adsorbent must exhibit high selectivity toward the target contaminant, be amenable to efficient regeneration and durable. MN200 has shown to be an excellent sorption material for PAH removal. The sorption process could be achieved with high values of loading capacities (35-220 mg/g). The experimental data was adjusted to adsorption isotherm models (Langmuir, Freundlich and Redlich-Peterson). Langmuir isotherm showed good fitting for adsorption on activated carbon, meanwhile Redlich-Peterson describe better adsorption on Macronet resin MN200. The sorption process could be described by a first order kinetic model as has been obtained in previous studies when studying the sorption of PAH using activated carbon. The possibility of efficient chemical

  8. Doctrines and Contemporary Economic Theories in the Economic Development

    Directory of Open Access Journals (Sweden)

    Gheorghe Stefan

    2011-04-01

    Full Text Available Contemporary economic theories justify economic polarization, both before and after thesecond world war, through enhanced differences between the rich countries and those in course ofdevelopment. The instrument quantifying this economic gap is represented by the high price forindustrial products and a very low one for essentials thus maintaining at minimal level the purchasingpower of the agrarian countries (of the under-developed states. Through the agency of someinstitutions and specialized organizations like U.N., U.N.E.S.C.O. or the E.U., there are conductedinternational programs for the sectorial support mainly aiming the resolution of all kinds of problems.

  9. Diatomaceous earth and activated bauxite used as granular sorbents for the removal of sodium chloride vapor from hot flue gas

    Energy Technology Data Exchange (ETDEWEB)

    Lee, S.H.D.; Swift, W.M.; Johnson, I.

    1980-01-01

    Diatomaceous earth and activated bauxite were tested as granular sorbents for use as filter media in granular-bed filters for the removal of gaseous alkali metal compounds from the hot (800/sup 0/C) flue gas of PFBC. Tests were performed at atmospheric pressure, using NaCl vapor transported in relatively dry simulated flue gas of PFBC. Either a fixed-bed combustor or a high-temperature sorption test rig was used. The effects of sorbent bed temperature, superficial gas velocity, gas hourly space velocity, and NaCl-vapor concentration in flue gas on the sorption behavior of these two sorbents and their ultimate sorption capacities were determined. Both diatomaceous earth and activated bauxite were found to be very effective in removing NaCl vapor from flue gas. Preliminary cost evaluations showed that they are economically attractive as granular sorbents for cleaning alkali vapor from simulated flue gas.

  10. Removal of gasoline vapors from air streams by biofiltration

    Energy Technology Data Exchange (ETDEWEB)

    Apel, W.A.; Kant, W.D.; Colwell, F.S.; Singleton, B.; Lee, B.D.; Andrews, G.F.; Espinosa, A.M.; Johnson, E.G.

    1993-03-01

    Research was performed to develop a biofilter for the biodegradation of gasoline vapors. The overall goal of this effort was to provide information necessary for the design, construction, and operation of a commercial gasoline vapor biofilter. Experimental results indicated that relatively high amounts of gasoline vapor adsorption occur during initial exposure of the biofilter bed medium to gasoline vapors. Biological removal occurs over a 22 to 40{degrees}C temperature range with removal being completely inhibited at 54{degrees}C. The addition of fertilizer to the relatively fresh bed medium used did not increase the rates of gasoline removal in short term experiments. Microbiological analyses indicated that high levels of gasoline degrading microbes are naturally present in the bed medium and that additional inoculation with hydrocarbon degrading cultures does not appreciably increase gasoline removal rates. At lower gasoline concentrations, the vapor removal rates were considerably lower than those at higher gasoline concentrations. This implies that system designs facilitating gasoline transport to the micro-organisms could substantially increase gasoline removal rates at lower gasoline vapor concentrations. Test results from a field scale prototype biofiltration system showed volumetric productivity (i.e., average rate of gasoline degradation per unit bed volume) values that were consistent with those obtained with laboratory column biofilters at similar inlet gasoline concentrations. In addition, total benzene, toluene, ethyl-benzene, and xylene (BTEX) removal over the operating conditions employed was 50 to 55%. Removal of benzene was approximately 10 to 15% and removal of the other members of the BTEX group was much higher, typically >80%.

  11. Removal of gasoline vapors from air streams by biofiltration

    Energy Technology Data Exchange (ETDEWEB)

    Apel, W.A.; Kant, W.D.; Colwell, F.S.; Singleton, B.; Lee, B.D.; Andrews, G.F.; Espinosa, A.M.; Johnson, E.G.

    1993-03-01

    Research was performed to develop a biofilter for the biodegradation of gasoline vapors. The overall goal of this effort was to provide information necessary for the design, construction, and operation of a commercial gasoline vapor biofilter. Experimental results indicated that relatively high amounts of gasoline vapor adsorption occur during initial exposure of the biofilter bed medium to gasoline vapors. Biological removal occurs over a 22 to 40[degrees]C temperature range with removal being completely inhibited at 54[degrees]C. The addition of fertilizer to the relatively fresh bed medium used did not increase the rates of gasoline removal in short term experiments. Microbiological analyses indicated that high levels of gasoline degrading microbes are naturally present in the bed medium and that additional inoculation with hydrocarbon degrading cultures does not appreciably increase gasoline removal rates. At lower gasoline concentrations, the vapor removal rates were considerably lower than those at higher gasoline concentrations. This implies that system designs facilitating gasoline transport to the micro-organisms could substantially increase gasoline removal rates at lower gasoline vapor concentrations. Test results from a field scale prototype biofiltration system showed volumetric productivity (i.e., average rate of gasoline degradation per unit bed volume) values that were consistent with those obtained with laboratory column biofilters at similar inlet gasoline concentrations. In addition, total benzene, toluene, ethyl-benzene, and xylene (BTEX) removal over the operating conditions employed was 50 to 55%. Removal of benzene was approximately 10 to 15% and removal of the other members of the BTEX group was much higher, typically >80%.

  12. Economics of dry storage systems

    International Nuclear Information System (INIS)

    Moore, G.R.; Winders, R.C.

    1980-01-01

    This paper postulates a dry storage application suitable as a regional away-from-reactor storage (AFR), develops an economical system design concept and estimates system costs. The system discussed uses the experience gained in the dry storage research activities and attempts to present a best foot forward system concept. The major element of the system is the Receiving and Packaging Building. In this building fuel assemblies are removed from transportation casks and encapsulated for storage. This facility could be equally applicable to silo, vault, or caisson storage. However the caisson storage concept has been chosen for discussion purposes

  13. Synthesis of anion clay starting from flying ash and its application in the removal of Chromium VI

    International Nuclear Information System (INIS)

    Gil, E.

    1998-01-01

    The present study shows a simple and economic method for the removal of Cr (VI) of the liquid waste. The study was carried out in two stages, a first stage consisted on the synthesis of the anion clay, using fly ash as matter prevails, which is a waste material coming from the ovens of combustion of the coal; in the other stage it was carried out the process of removal of Cr (VI), using the anion clay like absorption, throwing satisfactory results

  14. Evaluation of Heat Removal Performance of Passive Decay Heat Removal system for S-CO{sub 2} Cooled Micro Modular Reactor

    Energy Technology Data Exchange (ETDEWEB)

    Moon, Jangsik; Lee, Jeong Ik; Jeong, Yong Hoon [KAIST, Daejeon (Korea, Republic of)

    2015-05-15

    The modular systems is able to be transported by large trailer. Moreover, dry cooling system is applied for waste heat removal. The characteristics of MMR takes wide range of construction area from coast to desert, isolated area and disaster area. In MMR, Passive decay heat removal system (PDHRS) is necessary for taking the advantage on selection of construction area where external support cannot be offered. The PDHRS guarantees to protect MMR without external support. In this research, PDHRS of MMR is introduced and decay heat removal performance is analyzed. The PDHRS guarantees integrity of reactor coolant system. The high level of decay heat (2 MW) can be removed by PDHRS without offsite power.

  15. Recalcitrance removal of pretreated landfill leachate by ozone-based oxidation processes

    OpenAIRE

    Van Aken, Pieter; Van Eyck, Kwinten; Luyten, Jan; Degrève, Jan; Liers, Sven

    2010-01-01

    The sanitary landfill method for the ultimate disposal of solid waste material continues to be widely accepted and used due to its economic advantages. However, water infiltrates through the solid waste and a variety of organic and inorganic pollutants will be dissolved and transported. These leachates may contain large amounts of organic matter, as well as ammonia-nitrogen, heavy metals, chlorinated organic and inorganic salts. The removal of organic material is usual the prerequisite before...

  16. Behavioral economics

    OpenAIRE

    Camerer, Colin F.

    2014-01-01

    Economics, like behavioral psychology, is a science of behavior, albeit highly organized human behavior. The value of economic concepts for behavioral psychology rests on (1) their empirical validity when tested in the laboratory with individual subjects and (2) their uniqueness when compared to established behavioral concepts. Several fundamental concepts are introduced and illustrated by reference to experimental data: open and closed economies, elastic and inelastic demand, and substitutio...

  17. Oxy-Combustion Burner and Integrated Pollutant Removal Research and Development Test Facility

    Energy Technology Data Exchange (ETDEWEB)

    Mark Schoenfield; Manny Menendez; Thomas Ochs; Rigel Woodside; Danylo Oryshchyn

    2012-09-30

    A high flame temperature oxy-combustion test facility consisting of a 5 MWe equivalent test boiler facility and 20 KWe equivalent IPR® was constructed at the Hammond, Indiana manufacturing site. The test facility was operated natural gas and coal fuels and parametric studies were performed to determine the optimal performance conditions and generated the necessary technical data required to demonstrate the technologies are viable for technical and economic scale-up. Flame temperatures between 4930-6120F were achieved with high flame temperature oxy-natural gas combustion depending on whether additional recirculated flue gases are added to balance the heat transfer. For high flame temperature oxy-coal combustion, flame temperatures in excess of 4500F were achieved and demonstrated to be consistent with computational fluid dynamic modeling of the burner system. The project demonstrated feasibility and effectiveness of the Jupiter Oxygen high flame temperature oxy-combustion process with Integrated Pollutant Removal process for CCS and CCUS. With these technologies total parasitic power requirements for both oxygen production and carbon capture currently are in the range of 20% of the gross power output. The Jupiter Oxygen high flame temperature oxy-combustion process has been demonstrated at a Technology Readiness Level of 6 and is ready for commencement of a demonstration project.

  18. Denitration of simulated high-level liquid wastes and selective removal of cesium with zeolites

    Energy Technology Data Exchange (ETDEWEB)

    Mimura, Hitoshi; Kanno, Takuji [Tohoku Univ., Sendai (Japan). Research Inst. of Mineral Dressing and Metallurgy; Kimura, Toshiya

    1982-03-01

    Denitration of high-level liquid wastes (HLW) from nuclear fuel reprocessing has been studied. Selective removal of Cs has been also examined with various types of zeolites. The following zeolites were used in this study; Na-synthetic mordenite (NaSM), Na-natural mordenite (NaNM), Na-natural clinoptilolite (NaCP) and H-synthetic mordenites (HSM). The effective denitration is found in the simulated HLW (15 components, 2N HNO/sub 3/ soln.) containing platinum group elements in the case of the addition of formic acid, and the pH of the solution shows the value of 5.4 when the excess formic acid ((HCOOH)/(HNO/sub 3/) = 2.0) was added. Platinum group elements may react as a catalyst for the decomposition of nitric acid and the excess formic acid. The break-through properties of NaSM column are poor for the simulated HLW, and the selective removal of Cs appears to be difficult. On the other hand, good results are obtained in the denitrated HLW, i.e., break-through capacity, total capacity and column utilization are 59.4 (meq./100 g zeolite), 147 (meq./100 g zeolite) and 40.4 (%), respectively. The break-through properties of NaSM and NaNM are superior to those of HSM. The break-through capacity and column utilization increase with an increase in column temperature.

  19. Denitration of simulated high-level liquid wastes and selective removal of cesium with zeolites

    International Nuclear Information System (INIS)

    Mimura, Hitoshi; Kanno, Takuji; Kimura, Toshiya.

    1982-01-01

    Denitration of high-level liquid wastes (HLW) from nuclear fuel reprocessing has been studied. Selective removal of Cs has been also examined with various types of zeolites. The following zeolites were used in this study; Na-synthetic mordenite (NaSM), Na-natural mordenite (NaNM), Na-natural clinoptilolite (NaCP) and H-synthetic mordenites (HSM). The effective denitration is found in the simulated HLW (15 components, 2N HNO 3 soln.) containing platinum group elements in the case of the addition of formic acid, and the pH of the solution shows the value of 5.4 when the excess formic acid ([HCOOH]/[HNO 3 ] = 2.0) was added. Platinum group elements may react as a catalyst for the decomposition of nitric acid and the excess formic acid. The break-through properties of NaSM column are poor for the simulated HLW, and the selective removal of Cs appears to be difficult. On the other hand, good results are obtained in the denitrated HLW, i.e., break-through capacity, total capacity and column utilization are 59.4 (meq./100 g zeolite), 147 (meq./100 g zeolite) and 40.4 (%), respectively. The break-through properties of NaSM and NaNM are superior to those of HSM. The break-through capacity and column utilization increase with an increase in column temperature. (author)

  20. Removal of palladium precipitate from a simulated high-level radioactive liquid waste by reduction by ascorbic acid

    International Nuclear Information System (INIS)

    Kim, Eung Ho; Yoo, Jae Hyung; Choi, Cheong Song

    1998-01-01

    A study of the selective removal of Palladium from a simulated solution of high-level radioactive liquid waste (HLLW) was carried out. The simulated solution contained 7 representative elements (Pd 2+ , Cs + , Sr 2+ , Fe 3+ , MoO 2 2+ , Ru 4+ , and Nd 3+ ) typical of HLLW, ascorbic acid was added to the solution at room temperature. Pd 2+ in the simulated solution was easily reduced to Pd metal by the ascorbic acid and then the metal precipitate could be removed from the solution, whereas other elements remained mainly in solution. When the resulting Pd metal was left in solution, it was reoxidized to Pb 2+ ion and redissolved in a nitric acid medium. The oxidation rate of Pd 2+ depended on the presence of a transition metal such as ferric ion, and was also in proportion to the concentration of nitric acid and in inverse proportion to the concentration of ascrobic acid. (orig.)

  1. Residual heat removal pump retrofit program

    International Nuclear Information System (INIS)

    Dudiak, J.G.; McKenna, J.M.

    1990-01-01

    Residual Heat Removal (RHR) pumps installed in pressurized water reactor power plants are used to provide the removal of decay heat from the reactor and to provide low head safety injection in the event of loss of coolant in the reactor coolant system. These pumps are subjected to rather severe temperature and pressure transients, therefore, the majority of pumps installed in the RHR service are vertical pumps with a single stage impeller. RHR pumps have traditionally been a significant maintenance item for many utilities. The close-coupled pump design requires disassembly of the casing cover from the lower pump casing while performing these routine maintenance tasks. The casing separation requires the loosening of numerous highly torqued studs. Once the casing is separated, the impeller is dropped from the motor shaft to allow removal of the mechanical seal and casing cover from the motor shaft. Galling of the impeller to the motor shaft is not uncommon. The RHR pump internals are radioactive and the separation of the pump casing to perform routine maintenance exposes the maintenance personnel to high radiation levels. The handling of the impeller also exposes the maintenance personnel to high radiation levels. This paper introduces a design modification developed to convert the close-coupled RHR pumps to a coupled configuration

  2. Protein removal from waste brines generated during ham salting through acidification and centrifugation.

    Science.gov (United States)

    Gutiérrez-Martínez, Maria del Rosario; Muñoz-Guerrero, Hernán; Alcaína-Miranda, Maria Isabel; Barat, José Manuel

    2014-03-01

    The salting step in food processes implies the production of large quantities of waste brines, having high organic load, high conductivity, and other pollutants with high oxygen demand. Direct disposal of the residual brine implies salinization of soil and eutrophication of water. Since most of the organic load of the waste brines comes from proteins leaked from the salted product, precipitation of dissolved proteins by acidification and removal by centrifugation is an operation to be used in waste brine cleaning. The aim of this study is optimizing the conditions for carrying out the separation of proteins from waste brines generated in the pork ham salting operation, by studying the influence of pH, centrifugal force, and centrifugation time. Models for determining the removal of proteins depending on the pH, centrifugal force, and time were obtained. The results showed a high efficacy of the proposed treatment for removing proteins, suggesting that this method could be used for waste brine protein removal. The best pH value to be used in an industrial process seems to be 3, while the obtained results indicate that almost 90% of the proteins from the brine can be removed by acidification followed by centrifugation. A further protein removal from the brine should have to be achieved using filtrating techniques, which efficiency could be highly improved as a consequence of the previous treatment through acidification and centrifugation. Waste brines from meat salting have high organic load and electrical conductivity. Proteins can be removed from the waste brine by acidification and centrifugation. The total protein removal can be up to 90% of the initial content of the waste brine. Protein removal is highly dependent on pH, centrifugation rate, and time. © 2014 Institute of Food Technologists®

  3. IVO's nuclide removal system takes to the road

    International Nuclear Information System (INIS)

    Tusa, E.H.

    1995-01-01

    The successful and routine use of IVO's treatment system for the removal of cesium from the evaporator concentrates at the Loviisa WER plant in Finland is described. The system uses a granular inorganic hexacyanoferate-based ion exchanger to separate cesium from liquid radioactive wastes. The compactness of the original systems at Loviisa suggested the development of a transportable unit. A combined nuclide removal system was created which included a highly efficient ultrafiltration unit to separate nearly all particulate material carrying radionuclides, as well as the cesium removal capability. A 20ft long container carrying the removal package was completed in 1994. This NUclide REmoval System (NURES) was used for the first time in January 1995 to purify liquid waste accumulating at training reactors in Estonia and has performed well. As an extension of nuclide removal, a process has been created to recover boron from liquid wastes. A system for boron recovery and nuclide removal has been designed for use at the Paks plant in Hungary. The removal process has been shown to improve the safety of final waste disposal compared with the alternative treatment by cementation because the cesium is very tightly bound into the ion exchange material. (UK)

  4. Water Recycling removal using temperature-sensitive hydronen

    Energy Technology Data Exchange (ETDEWEB)

    Rana B. Gupta

    2002-10-30

    The overall objective of this project was to study the proposed Water Recycling/Removal Using Temperature-Sensitive Hydrogels. The main element of this technology is the design of a suitable hydrogel that can perform needed water separation for pulp and paper industry. The specific topics studied are to answer following questions: (a) Can water be removed using hydrogel from large molecules such as lignin? (b) Can the rate of separation be made faster? (c) What are the molecular interactions with hydrogel surface? (d) Can a hydrogel be designed for a high ionic strength and high temperature? Summary of the specific results are given.

  5. Evaluation of process costs for small-scale carbon dioxide removal from natural gas. Topical report, September 1989-December 1989

    International Nuclear Information System (INIS)

    Changela, M.K.; Reading, G.J.; Echterhoff, L.W.

    1991-08-01

    The report establishes the cost of producing pipeline quality gas on a small scale from high carbon dioxide subquality natural gas. Two processing technologies are evaluated: conventional diethanolamine (DEA) absorption and membrane separation. Comparison of the established costs shows both capital and operating cost advantages for small-scale membrane applications. Membranes offer higher cost savings at low feed flow rates and high carbon dioxide feed contents. Membranes are produced in modules, thus they do not exhibit economies of scale. This works to their advantage for removing carbon dioxide on a small scale. Processing costs for amine systems are more sensitive to economies of scale, and thus decrease more rapidly than for membranes at higher feed flow rates. The report shows that membranes have a definite market niche within the natural gas processing arena. For economic reasons, membranes will likely become the technology of choice for small-scale systems that treat high carbon dioxide content natural gas streams. However, amines will continue to service large-scale systems and applications where deep carbon dioxide removal is required. A related report (GRI Report No. GRI-91/0093 entitled, 'Technical Evaluation of Hybrid Membrane/DEA Modeling') shows that hybrid systems, the integration of membranes and amines, also offer the potential to lower processing costs

  6. Selective removal of cesium and strontium using porous frameworks from high level nuclear waste.

    Science.gov (United States)

    Aguila, Briana; Banerjee, Debasis; Nie, Zimin; Shin, Yongsoon; Ma, Shengqian; Thallapally, Praveen K

    2016-05-01

    Efficient and cost-effective removal of radioactive (137)Cs and (90)Sr found in spent fuel is an important step for safe, long-term storage of nuclear waste. Solid-state materials such as resins and titanosilicate zeolites have been assessed for the removal of Cs and Sr from aqueous solutions, but there is room for improvement in terms of capacity and selectivity. Herein, we report the Cs(+) and Sr(2+) exchange potential of an ultra stable MOF, namely, MIL-101-SO3H, as a function of different contact times, concentrations, pH levels, and in the presence of competing ions. Our preliminary results suggest that MOFs with suitable ion exchange groups can be promising alternate materials for cesium and strontium removal.

  7. Ultra-high adsorption capacity of zeolitic imidazole framework-67 (ZIF-67) for removal of malachite green from water.

    Science.gov (United States)

    Lin, Kun-Yi Andrew; Chang, Hsuan-Ang

    2015-11-01

    Zeolitic imidazole frameworks (ZIFs), a new class of adsorbents, are proposed to adsorb Malachite Green (MG) in water. Particularly, ZIF-67 was selected owing to its stability in water and straightforward synthesis. The as-synthesized ZIF-67 was characterized and used to adsorb MG from water. Factors affecting the adsorption capacity were investigated including mixing time, temperature, the presence of salts and pH. The kinetics, adsorption isotherm and thermodynamics of the MG adsorption to ZIF-67 were also studied. The adsorption capacity of ZIF-67 for MG could be as high as 2430mgg(-1) at 20°C, which could be improved at the higher temperatures. Such an ultra-high adsorption capacity of ZIF-67 was almost 10-times of those of conventional adsorbents, including activated carbons and biopolymers. A mechanism for the high adsorption capacity was proposed and possibly attributed to the π-π stacking interaction between MG and ZIF-67. ZIF-67 also could be conveniently regenerated by washing with ethanol and the regeneration efficiency could remain 95% up to 4 cycles of the regeneration. ZIF-67 was also able to remove MG from the aquaculture wastewater, in which MG can be typically found. These features enable ZIF-67 to be one of the most effective and promising adsorbent to remove MG from water. Copyright © 2015 Elsevier Ltd. All rights reserved.

  8. High renesting rates in arctic-breeding Dunlin (Calidris alpina): A clutch-removal experiment

    Science.gov (United States)

    Gates, H. River; Lanctot, Richard B.; Powell, Abby N.

    2013-01-01

    The propensity to replace a clutch is a complex component of avian reproduction and poorly understood. We experimentally removed clutches from an Arctic-breeding shorebird, the Dunlin (Calidris alpina arcticola), during early and late stages of incubation to investigate replacement clutch rates, renesting interval, and mate and site fidelity between nesting attempts. In contrast to other Arctic studies, we documented renesting by radiotracking individuals to find replacement clutches. We also examined clutch size and mean egg volume to document changes in individual females’ investment in initial and replacement clutches. Finally, we examined the influence of adult body mass, clutch volume, dates of clutch initiation and nest loss, and year on the propensity to renest. We found high (82–95%) and moderate (35–50%) rates of renesting for early and late incubation treatments. Renesting intervals averaged 4.7–6.8 days and were not different for clutches removed early or late in incubation. Most pairs remained together for renesting attempts. Larger females were more likely to replace a clutch; female body mass was the most important parameter predicting propensity to renest. Clutches lost later in the season were less likely to be replaced. We present evidence that renesting is more common in Arctic-breeding shorebirds than was previously thought, and suggest that renesting is constrained by energetic and temporal factors as well as mate availability. Obtaining rates of renesting in species breeding at different latitudes will help determine when this behavior is likely to occur; such information is necessary for demographic models that include individual and population-level fecundity estimates.

  9. Economic model of pipeline transportation systems

    Energy Technology Data Exchange (ETDEWEB)

    Banks, W. F.

    1977-07-29

    The objective of the work reported here was to develop a model which could be used to assess the economic effects of energy-conservative technological innovations upon the pipeline industry. The model is a dynamic simulator which accepts inputs of two classes: the physical description (design parameters, fluid properties, and financial structures) of the system to be studied, and the postulated market (throughput and price) projection. The model consists of time-independent submodels: the fluidics model which simulates the physical behavior of the system, and the financial model which operates upon the output of the fluidics model to calculate the economics outputs. Any of a number of existing fluidics models can be used in addition to that developed as a part of this study. The financial model, known as the Systems, Science and Software (S/sup 3/) Financial Projection Model, contains user options whereby pipeline-peculiar characteristics can be removed and/or modified, so that the model can be applied to virtually any kind of business enterprise. The several dozen outputs are of two classes: the energetics and the economics. The energetics outputs of primary interest are the energy intensity, also called unit energy consumption, and the total energy consumed. The primary economics outputs are the long-run average cost, profit, cash flow, and return on investment.

  10. Economic Studies

    Directory of Open Access Journals (Sweden)

    A. V. Kholopov

    2014-01-01

    Full Text Available The establishment of the School of Economic Science at MGIMO was due to the necessity of the world economy research, and the need to prepare highly skilled specialists in international economics. The school is developing a number of areas, which reflect the Faculty structure. - Economic theory is one of the most important research areas, a kind of foundation of the School of Economic Science at MGIMO. Economic theory studies are carried out at the chair of Economic theory. "The course of economic theory" textbook was published in 1991, and later it was reprinted seven times. Over the past few years other textbooks and manuals have been published, including "Economics for Managers" by Professor S.N. Ivashkovskaya, which survived through five editions; "International Economics" - four editions and "History of Economic Thought" - three editions. - International Economic Relations are carried out by the Department of International Economic Relations and Foreign Economic Activity. Its establishment is associated with the prominent economist N.N. Lyubimov. In 1957 he with his colleagues published the first textbook on the subject which went through multiple republications. The editorial team of the textbook subsequently formed the pride of Soviet economic science - S.M. Menshikov, E.P. Pletnev, V.D. Schetinin. Since 2007, the chair of Foreign Economic Activities led by Doctor of Economics, Professor I. Platonova has been investigating the problems of improving the architecture of foreign economic network and the international competitiveness of Russia; - The history of the study of problems of the world economy at MGIMO begins in 1958 at the chair baring the same name. Since 1998, the department has been headed by Professor A. Bulatov; - The study of international monetary relations is based on the chair of International Finance, and is focused on addressing the fundamental scientific and practical problems; - The chair "Banks, monetary circulation

  11. How do operating conditions affect As(III) removal by iron electrocoagulation?

    Science.gov (United States)

    Delaire, Caroline; Amrose, Susan; Zhang, Minghui; Hake, James; Gadgil, Ashok

    2017-04-01

    Iron electrocoagulation (Fe-EC) has been shown to effectively remove arsenic from contaminated groundwater at low cost and has the potential to improve access to safe drinking water for millions of people. Understanding how operating conditions, such as the Fe dosage rate and the O 2 recharge rate, affect arsenic removal at different pH values is crucial to maximize the performance of Fe-EC under economic constraints. In this work, we improved upon an existing computational model to investigate the combined effects of pH, Fe dosage rate, and O 2 recharge rate on arsenic removal in Fe-EC. We showed that the impact of the Fe dosage rate strongly depends on pH and on the O 2 recharge rate, which has important practical implications. We identified the process limiting arsenic removal (As(III) oxidation versus As(V) adsorption) at different pH values, which allowed us to interpret the effect of operating conditions on Fe-EC performance. Finally, we assessed the robustness of the trends predicted by the model, which assumes a constant pH, against lab experiments reproducing more realistic conditions where pH is allowed to drift during treatment as a result of equilibration with atmospheric CO 2 . Our results provide a nuanced understanding of how operating conditions impact arsenic removal by Fe-EC and can inform decisions regarding the operation of this technology in a range of groundwaters. Copyright © 2017 Elsevier Ltd. All rights reserved.

  12. Material removal and surface figure during pad polishing of fused silica

    Energy Technology Data Exchange (ETDEWEB)

    Suratwala, T I; Feit, M D; Steele, W A

    2009-05-04

    The material removal and surface figure after ceria pad polishing of fused silica glass have been measured and analyzed as a function of kinematics, loading conditions, and polishing time. Also, the friction at the workpiece/lap interface, the slope of the workpiece relative to the lap plane, and lap viscoelastic properties have been measured and correlated to material removal. The results show that the relative velocity between the workpiece & lap (determined by the kinematics) and the pressure distribution determine the spatial and temporal material removal and hence the final surface figure of the workpiece. In the case where the applied loading and relative velocity distribution over the workpiece are spatially uniform, a significant non-uniform spatial material removal from the workpiece surface is observed. This is due to a non-uniform pressure distribution resulting from: (1) a moment caused by a pivot point and interface friction forces; (2) viscoelastic relaxation of the polyurethane lap; and (3) a physical workpiece/lap interface mismatch. Both the kinematics and these contributions to the pressure distribution are quantitatively described, and then combined to form a spatial and temporal Preston model & code for material removal (called Surface Figure or SurF{copyright}). The surface figure simulations are consistent with the experiment for a wide variety of polishing conditions. This study is an important step towards deterministic full-aperture polishing, which would allow optical glass fabrication to be performed in a more repeatable, less iterative, and hence more economical manner.

  13. Cadmium (II) removal mechanisms in microbial electrolysis cells

    Energy Technology Data Exchange (ETDEWEB)

    Colantonio, Natalie; Kim, Younggy, E-mail: younggy@mcmaster.ca

    2016-07-05

    Highlights: • Rapid removal of Cd(II) was achieved in 24 h using microbial electrolysis cells. • Cathodic reduction (electrodeposition) of Cd(II) cannot explain the rapid removal. • H{sub 2} evolution in microbial electrolysis cells increases local pH near the cathode. • High local pH induces Cd(OH){sub 2} and CdCO{sub 3} precipitation only with electric current. • Neutral pH caused by low current and depleted substrate dissolves the precipitated Cd. - Abstract: Cadmium is a toxic heavy metal, causing serious environmental and human health problems. Conventional methods for removing cadmium from wastewater are expensive and inefficient for low concentrations. Microbial electrolysis cells (MECs) can simultaneously treat wastewater, produce hydrogen gas, and remove heavy metals with low energy requirements. Lab-scale MECs were operated to remove cadmium under various electric conditions: applied voltages of 0.4, 0.6, 0.8, and 1.0 V; and a fixed cathode potential of −1.0 V vs. Ag/AgCl. Regardless of the electric condition, rapid removal of cadmium was demonstrated (50–67% in 24 h); however, cadmium concentration in solution increased after the electric current dropped with depleted organic substrate under applied voltage conditions. For the fixed cathode potential, the electric current was maintained even after substrate depletion and thus cadmium concentration did not increase. These results can be explained by three different removal mechanisms: cathodic reduction; Cd(OH){sub 2} precipitation; and CdCO{sub 3} precipitation. When the current decreased with depleted substrates, local pH at the cathode was no longer high due to slowed hydrogen evolution reaction (2H{sup +} + 2e{sup −} → H{sub 2}); thus, the precipitated Cd(OH){sub 2} and CdCO{sub 3} started dissolving. To prevent their dissolution, sufficient organic substrates should be provided when MECs are used for cadmium removal.

  14. [Alternatives to presently established forms of animal body removal-- tolerated, intended and feared?].

    Science.gov (United States)

    Kamphues, J

    1997-07-01

    The removal and disposal of dead animals and slaughterhouse offalls by rendering plants to produce meat and bone meal (high nutritive value due to the protein and mineral content) is a model for a successful concept of recycling organic matter. Especially since the discussion on BSE and on the role of meat meal in distribution of this disease the products--inspite of their nutritive value--came under criticism. Besides this development more and more owners of companion animals refuse the removal of their animals by rendering plants, increasing their demand of other kinds of disposal (crematorium, burial-grounds). The image of meat and bone meal has been reduced in the last years, although the animal production causes the mass of mortalities and slaughterhouse offals there is a trend to renounce on the use of meat and bone meal in food producing animals. From the ecological and economical point of view it is irresponsible to use a meat and bone meal--produced under specified conditions concerning temperature, pressure and duration of heat treatment--as fuel. Alternative kinds of disposal of dead animals (for example composting) are presented and discussed with their advantages and drawbacks, especially their risks from spreading infectious organisms and diseases.

  15. Iron and manganese removal from a groundwater supply

    Energy Technology Data Exchange (ETDEWEB)

    Lorenz, W.; Seifert, K.; Kasch, O.K. (Arber Richard P. Associates, Inc., Denver, CO (USA))

    1988-11-01

    The treatment options and planning techniques used by the town of Castle Rock (Colorado) for a new water treatment facility are described. Castle Rock officials assessed the available treatment options for dissolved iron and manganese removal and selected potassium permanganate as the primary oxidant to be followed by manganese greensand. A backup prechlorination system for oxidation was also installed. In addition, to prevent excess headloss buildup in the manganese greensand filter media, an anthracite carbon cap was used as the top filter medium for precipitate removal. It is recommended that a treatability study be performed to determine individual design criteria to allow for specific site conditions. The town also assessed the capital and operation and maintenance costs for both treatment at individual well fields and a centralized location for treatment of a cluster of well fields. The results indicate that it is more economical to provide centralized water treatment even though there are capital costs associated with piping raw water from the individual well fields to the central facility. 3 refs.

  16. An economic assessment of local farm multi-purpose surface water retention systems in a Canadian Prairie setting

    Science.gov (United States)

    Berry, Pamela; Yassin, Fuad; Belcher, Kenneth; Lindenschmidt, Karl-Erich

    2017-12-01

    There is a need to explore more sustainable approaches to water management on the Canadian Prairies. Retention pond installation schemes designed to capture surface water may be a viable option that would reduce water stress during drought periods by providing water for irrigation. The retention systems would serve to capture excess spring runoff and extreme rainfall events, reducing flood potential downstream. Additionally, retention ponds may be used for biomass production and nutrient retention. The purpose of this research was to investigate the economic viability of adopting local farm surface water retention systems as a strategic water management strategy. A retention pond was analyzed using a dynamic simulation model to predict its storage capacity, installation and upkeep cost, and economic advantage to farmers when used for irrigation. While irrigation application increased crop revenue, the cost of irrigation and reservoir infrastructure and installation costs were too high for the farmer to experience a positive net revenue. Farmers who harvest cattails from retention systems for biomass and available carbon offset credits can gain 642.70/hectare of harvestable cattail/year. Cattail harvest also removes phosphorus and nitrogen, providing a monetized impact of 7014/hectare of harvestable cattail/year. The removal of phosphorus, nitrogen, carbon, and avoided flooding damages of the retention basin itself provide an additional 17,730-18,470/hectare of retention system/year. The recommended use of retention systems is for avoided flood damages, nutrient retention, and biomass production. The revenue gained from these functions can support farmers wanting to invest in irrigation while providing economic and environmental benefits to the region.

  17. Sequential Aeration of Membrane-Aerated Biofilm Reactors for High-Rate Autotrophic Nitrogen Removal: Experimental Demonstration

    DEFF Research Database (Denmark)

    Pellicer i Nàcher, Carles; Sun, Sheng-Peng; Lackner, Susanne

    2010-01-01

    One-stage autotrophic nitrogen (N) removal, requiring the simultaneous activity of aerobic and anaerobic ammonium oxidizing bacteria (AOB and AnAOB), can be obtained in spatially redox-stratified biofilms. However, previous experience with Membrane-Aerated Biofilm Reactors (MABRs) has revealed...... a difficulty in reducing the abundance and activity of nitrite oxidizing bacteria (NOB), which drastically lowers process efficiency. Here we show how sequential aeration is an effective strategy to attain autotrophic N removal in MABRs: Two separate MABRs, which displayed limited or no N removal under...... continuous aeration, could remove more than 5.5 g N/m2/day (at loads up to 8 g N/m2/day) by controlled variation of sequential aeration regimes. Daily averaged ratios of the surficial loads of O2 (oxygen) to NH4+ (ammonium) (LO2/LNH4) were close to 1.73 at this optimum. Real-time quantitative PCR based on 16...

  18. Economics of defense high-level waste management in the United States

    International Nuclear Information System (INIS)

    Slate, S.C.; McDonell, W.R.

    1987-01-01

    The Department of Energy (DOE) is responsible for managing defense high-level wastes (DHLW) from U.S. defense activities using environmentally safe and cost-effective methods. In parallel with its technical programs, the DOE is performing economic studies to ensure that costs are minimized. To illustrate the cost estimating techniques and to provide a sense of cost magnitude, the DHLW costs for the Savannah River Plant (SRP) are calculated. Since operations at SRP must be optimized within relatively fixed management practices, the estimation of incremental costs is emphasized. Treatment and disposal costs are shown to equally contribute to the incremental cost of almost $400,000/canister

  19. Assessing the economic effects of Latin American independence

    OpenAIRE

    Prados de la Escosura, Leandro

    2003-01-01

    This paper discusses the economic consequences of independence in Latin America. Grand interpretations that assess Nineteenth Century Latin America by comparison to the U.S. performance are examined and the alternative approach of using African and Asian post-colonial experiences as the yardstick is explored. Empirical evidence on the consequences of removing the colonial burden and opening up to the international economy is, then, examined. The paper concludes with discussion of when Latin A...

  20. Cascade air stripping: Techno-economic evaluation of a new ground water treatment process

    International Nuclear Information System (INIS)

    Nirmalakhandan, N.; Peace, G.L.; Shanbhag, A.R.; Speece, R.E.

    1992-01-01

    A simple modification of the conventional air-stripping process introduced as cascade air stripping is proposed for efficient and economical removal of semivolatile and low volatility contaminants from ground water. The technical feasibility and economic viability of this process are evaluated using field test results and cost model simulations. The field tests enabled the process model to be verified at various water flow rates ranging from 150 gpm to 400 gpm. The field study also demonstrated the feasibility of the proposed system at a near full-scale level. Cost models were used to compare the proposed process to conventional air stripping and granular-activated carbon adsorption in removing a range of contaminants. This analysis showed that the treatment cost (cents/1,000 gal) of cascade air stripping is about 15% lower than conventional air stripping and about 40% lower than granular-activated carbon adsorption

  1. Nutrient removal by apple, pear and cherry nursery trees

    Directory of Open Access Journals (Sweden)

    Giovambattista Sorrenti

    2017-06-01

    Full Text Available Given that nursery is a peculiar environment, the amount of nutrients removed by nursery trees represents a fundamental acquisition to optimise fertilisation strategies, with economic and environmental implications. In this context, we determined nutrient removal by apple, pear and cherry nursery trees at the end of the nursery growing cycle. We randomly removed 5 leafless apple (Golden Delicious/EMLA M9; density of 30,000 trees ha–1, pear (Santa Maria/Adams; density of 30,000 trees ha–1 and cherry (AlexTM/Gisela 6®; density of 40,000 trees ha–1 trees from a commercial nursery. Trees were divided into roots (below the root collar, rootstock (above-ground wood between root collar and grafting point and variety (1-year-old wood above the grafting point. For each organ we determined biomass, macro- (N, P, K, Ca, Mg, S, and micro- (Fe, Mn, Zn, Cu, and B nutrient concentration. Pear trees were the most developed (650 g (dw tree–1, equal to 1.75 and 2.78 folds than apple and cherry trees, respectively whereas, independently of the species, variety mostly contributed (>50% to the total tree biomass, followed by roots and then above-ground rootstock. However, the dry biomass and nutrient amount measured in rootstocks (including roots represent the cumulative amount of 2 and 3 seasons, for Gisela® 6 (tissue culture and pome fruit species (generated by mound layering, respectively. Macro and micronutrients were mostly concentrated in roots, followed by variety and rootstock, irrespective of the species. Independently of the tissue, macronutrients concentration hierarchy was N>Ca>K> P>Mg>S. Removed N by whole tree accounted for 6.58, 3.53 and 2.49 g tree–1 for pear, apple and cherry, respectively, corresponding to almost 200, 107 and 100 kg N ha–1, respectively. High amounts of K and Ca were used by pear (130-140 kg ha–1 and apple trees (~50 and 130 kg ha–1 of K and Ca, respectively, while ~25 kg K ha–1 and 55 kg Ca ha–1 were

  2. Removal of nonorthogonality in the Born theory used for study of electron capture in high energy ion-atom collisions

    International Nuclear Information System (INIS)

    Kimura, M.

    1989-01-01

    We show the complete removal of the nonorthogonality of wave functions between initial and final states in the Born theory. Hence, this treatment offers more realistic electron capture cross sections in high energy ion-atom collisions. Representative results for resonant electron capture in H + + H collision are discussed in conjunction with other perturbative results. 10 refs., 1 fig

  3. Creation of a gilded trap by the high economic value of the Maine lobster fishery.

    Science.gov (United States)

    Steneck, R S; Hughes, T P; Cinner, J E; Adger, W N; Arnold, S N; Berkes, F; Boudreau, S A; Brown, K; Folke, C; Gunderson, L; Olsson, P; Scheffer, M; Stephenson, E; Walker, B; Wilson, J; Worm, B

    2011-10-01

    Unsustainable fishing simplifies food chains and, as with aquaculture, can result in reliance on a few economically valuable species. This lack of diversity may increase risks of ecological and economic disruptions. Centuries of intense fishing have extirpated most apex predators in the Gulf of Maine (United States and Canada), effectively creating an American lobster (Homarus americanus) monoculture. Over the past 20 years, the economic diversity of marine resources harvested in Maine has declined by almost 70%. Today, over 80% of the value of Maine's fish and seafood landings is from highly abundant lobsters. Inflation-corrected income from lobsters in Maine has steadily increased by nearly 400% since 1985. Fisheries managers, policy makers, and fishers view this as a success. However, such lucrative monocultures increase the social and ecological consequences of future declines in lobsters. In southern New England, disease and stresses related to increases in ocean temperature resulted in more than a 70% decline in lobster abundance, prompting managers to propose closing that fishery. A similar collapse in Maine could fundamentally disrupt the social and economic foundation of its coast. We suggest the current success of Maine's lobster fishery is a gilded trap. Gilded traps are a type of social trap in which collective actions resulting from economically attractive opportunities outweigh concerns over associated social and ecological risks or consequences. Large financial gain creates a strong reinforcing feedback that deepens the trap. Avoiding or escaping gilded traps requires managing for increased biological and economic diversity. This is difficult to do prior to a crisis while financial incentives for maintaining the status quo are large. The long-term challenge is to shift fisheries management away from single species toward integrated social-ecological approaches that diversify local ecosystems, societies, and economies. ©2011 Society for Conservation

  4. Iron oxide inside SBA-15 modified with amino groups as reusable adsorbent for highly efficient removal of glyphosate from water

    Science.gov (United States)

    Fiorilli, Sonia; Rivoira, Luca; Calì, Giada; Appendini, Marta; Bruzzoniti, Maria Concetta; Coïsson, Marco; Onida, Barbara

    2017-07-01

    Iron oxide clusters were incorporated into amino-functionalized SBA-15 in order to obtain a magnetically recoverable adsorbent. The physical-chemical properties of the material were characterized by FE-SEM, STEM, XRD, TGA, XPS, FT-IR and acid-base titration analysis. Iron oxide nanoparticles were uniformly dispersed into the pore of mesoporous silica and that the adsorbent is characterized high specific surface area (177 m2/g) and accessible porosity. The sorbent was successfully tested for the removal of glyphosate in real water matrices. Despite the significant content of inorganic ions, a quantitative removal of the contaminant was found. The complete regeneration of the sorbent after the adsorption process through diluted NaOH solution was also proved.

  5. The Competence Readiness of the Electrical Engineering Vocational High School Teachers in Manado towards the ASEAN Economic Community Blueprint in 2025

    OpenAIRE

    Fid Jantje Tasiam; Djoko Kustono; Purnomo Purnomo; Hakkun Elmunsyah

    2017-01-01

    This paper presents the competence readiness of the electrical engineering vocational high school teachers in Manado towards ASEAN Economic Community blueprint in 2025. The objective of this study is to get the competencies readiness description of the electrical engineering vocational high school teachers in Manado towards ASEAN Economic Community blueprint in 2025. Method used quantitative and qualitative approach which the statistical analysis in quantitative and the inductive analysis use...

  6. Randomized Controlled Trial of Teaching Methods: Do Classroom Experiments Improve Economic Education in High Schools?

    Science.gov (United States)

    Eisenkopf, Gerald; Sulser, Pascal A.

    2016-01-01

    The authors present results from a comprehensive field experiment at Swiss high schools in which they compare the effectiveness of teaching methods in economics. They randomly assigned classes into an experimental and a conventional teaching group, or a control group that received no specific instruction. Both teaching treatments improve economic…

  7. Removal of americium and curium from high-level wastes

    International Nuclear Information System (INIS)

    Bond, W.D.; Leuze, R.E.

    1979-01-01

    The DHDECMP process was demonstrated to give a 99.5% removal of actinides from actual HLLW in small-scale, batch extraction tests. Results from cold tests indicate that it may be possible to carry out the oxalate precipitation step of the OPIX process continuously. About 90% recovery of the trivalent actinides and lanthanides can be achieved in the continuous precipitation. the presence of zirconium impurity in feed solutions to Talspeak process at concentrations of 10 -4 M (0.5% of the Zr in the original waste) affected phase separations but equipment could be operated satisfactory in cold tests. Zirconium concentrations of 10 -3 M seriously affected phase separations and substantial quantities of interfacial cruds were formed. Modest concentrations (0.006 M or less) of H 2 MEHP, a suspected degradation product of HDEHP, did not effect separation factors. The presence of impurities derived from the thermal degradation of DHDECMP did not inhibit the loading of the trivalent actinide and lanthanide elements in the cation exchange chromatographic process for their separation. It appears that the biodentate (DHDECMP) solvent extraction process and the OPIX process are the leading candidate process for the co-removal of trivalent actinide and lanthanide elements from HLLW. The cation exchange chromatography and the Talspeak processes, are the leading candidate processes for the subsequent separation of actinides and lanthanides. The bidentate and cation exchange processes are further along in their development than the other processes and are currently considered the reference processes for the partitioning of Am-Cm from HLLW. 4 figures, 4 tables

  8. Biotechnological sulphide removal with oxygen

    NARCIS (Netherlands)

    Buisman, C.

    1989-01-01

    This thesis deals with the development of a new process for biotechnological sulphide removal from wastewater, in which it is attempted to convert sulphide into elemental sulphur by colourless sulphur bacteria. The toxicity, corrosive properties, unpleasant odor and high oxygen demand of sulphide

  9. Removal of trace organic chemical contaminants by a membrane bioreactor.

    Science.gov (United States)

    Trinh, T; van den Akker, B; Stuetz, R M; Coleman, H M; Le-Clech, P; Khan, S J

    2012-01-01

    Emerging wastewater treatment processes such as membrane bioreactors (MBRs) have attracted a significant amount of interest internationally due to their ability to produce high quality effluent suitable for water recycling. It is therefore important that their efficiency in removing hazardous trace organic contaminants be assessed. Accordingly, this study investigated the removal of trace organic chemical contaminants through a full-scale, package MBR in New South Wales, Australia. This study was unique in the context of MBR research because it characterised the removal of 48 trace organic chemical contaminants, which included steroidal hormones, xenoestrogens, pesticides, caffeine, pharmaceuticals and personal care products (PPCPs). Results showed that the removal of most trace organic chemical contaminants through the MBR was high (above 90%). However, amitriptyline, carbamazepine, diazepam, diclofenac, fluoxetine, gemfibrozil, omeprazole, sulphamethoxazole and trimethoprim were only partially removed through the MBR with the removal efficiencies of 24-68%. These are potential indicators for assessing MBR performance as these chemicals are usually sensitive to changes in the treatment systems. The trace organic chemical contaminants detected in the MBR permeate were 1 to 6 orders of magnitude lower than guideline values reported in the Australian Guidelines for Water Recycling. The outcomes of this study enhanced our understanding of the levels and removal of trace organic contaminants by MBRs.

  10. COD removal characteristics in air-cathode microbial fuel cells

    KAUST Repository

    Zhang, Xiaoyuan

    2015-01-01

    © 2014 Elsevier Ltd. Exoelectrogenic microorganisms in microbial fuel cells (MFCs) compete with other microorganisms for substrate. In order to understand how this affects removal rates, current generation, and coulombic efficiencies (CEs), substrate removal rates were compared in MFCs fed a single, readily biodegradable compound (acetate) or domestic wastewater (WW). Removal rates based on initial test conditions fit first-order kinetics, but rate constants varied with circuit resistance. With filtered WW (100Ω), the rate constant was 0.18h- 1, which was higher than acetate or filtered WW with an open circuit (0.10h- 1), but CEs were much lower (15-24%) than acetate. With raw WW (100Ω), COD removal proceeded in two stages: a fast removal stage with high current production, followed by a slower removal with little current. While using MFCs increased COD removal rate due to current generation, secondary processes will be needed to reduce COD to levels suitable for discharge.

  11. A Multistage Fluidized Bed for the Deep Removal of Sour Gases : Proof of Concept and Tray Efficiencies

    NARCIS (Netherlands)

    Driessen, Rick T.; Bos, Martin J.; Brilman, Derk W. F.

    2018-01-01

    Currently there are significant amounts of natural gas that cannot be produced and treated to meet pipeline specifications, because that would not be economically viable. This work investigates a bench scale multistage fluidized bed (MSFB) with shallow beds for sour gas removal from natural gas

  12. High efficiency particulate removal with sintered metal filters

    International Nuclear Information System (INIS)

    Kirstein, B.E.; Paplawsky, W.J.; Pence, D.T.; Hedahl, T.G.

    1981-01-01

    Because of their particle removal efficiencies and durability, sintered metal filters have been chosen for HEPA filter protection in the off-gas treatment system for the proposed Idaho National Engineering Laboratory Transuranic Waste Treatment Facility. Process evaluation of sintered metal filters indicated a lack of sufficient process design data to assume trouble-free operation. Subsequent pilot-scale testing was performed with fly ash as the test particulate. The test results showed that the sintered metal filters can have an efficiency greater than 0.9999999 for the specific test conditions used. Stable pressure drop characteristics were observed in pulsed and reversed flow blowback modes of operation. Over 4900 hours of operation were obtained with operating conditions ranging up to approximately 90 0 C and 24 volume percent water vapor in the gas stream

  13. The Impact of Various Quizzing Patterns on the Test Performance of High School Economics Students

    Science.gov (United States)

    Robertson, William L.

    2010-01-01

    Presenting college students, in a wide variety of content areas, with frequent announced and unannounced quizzes appears to correlate positively with enhanced test performance. The purpose of this quantitative study was to examine if similar results can be achieved with high school students in a standard economics class. Based on a theoretical…

  14. High economical aplliances 2006/07. A consumer information; Besonders sparsame Haushaltsgeraete 2006/07. Eine Verbraucherinformation

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    2006-07-01

    This brochure covers specially high economical appliances in different size and dimensions and directs on people, which are interrested in lower power- and water consumption. This Information bases on market data until Autumn 2006. The mentioned appliances are: Freezers, washing machines, dryers, dishwashers and some information on energy saving and Euro-Label. (GL)

  15. The utilization of waste by-products for removing silicate from mineral processing wastewater via chemical precipitation.

    Science.gov (United States)

    Kang, Jianhua; Sun, Wei; Hu, Yuehua; Gao, Zhiyong; Liu, Runqing; Zhang, Qingpeng; Liu, Hang; Meng, Xiangsong

    2017-11-15

    This study investigates an environmentally friendly technology that utilizes waste by-products (waste acid and waste alkali liquids) to treat mineral processing wastewater. Chemical precipitation is used to remove silicate from scheelite (CaWO 4 ) cleaning flotation wastewater and the waste by-products are used as a substitute for calcium chloride (CaCl 2 ). A series of laboratory experiments is conducted to explain the removal of silicate and the characterization and formation mechanism of calcium silicate. The results show that silicate removal reaches 90% when the Ca:Si molar ratio exceeds 1.0. The X-ray diffraction (XRD) results confirm the characterization and formation of calcium silicate. The pH is the key factor for silicate removal, and the formation of polysilicic acid with a reduction of pH can effectively improve the silicate removal and reduce the usage of calcium. The economic analysis shows that the treatment costs with waste acid (0.63 $/m 3 ) and waste alkali (1.54 $/m 3 ) are lower than that of calcium chloride (2.38 $/m 3 ). The efficient removal of silicate is confirmed by industrial testing at a plant. The results show that silicate removal reaches 85% in the recycled water from tailings dam. Copyright © 2017 Elsevier Ltd. All rights reserved.

  16. Electrochemical removal of phenol from oil refinery wastewater.

    Science.gov (United States)

    Abdelwahab, O; Amin, N K; El-Ashtoukhy, E-S Z

    2009-04-30

    This study explores the possibility of using electrocoagulation to remove phenol from oil refinery waste effluent using a cell with horizontally oriented aluminum cathode and a horizontal aluminum screen anode. The removal of phenol was investigated in terms of various parameters namely: pH, operating time, current density, initial phenol concentration and addition of NaCl. Removal of phenol during electrocoagulation was due to combined effect of sweep coagulation and adsorption. The results showed that, at high current density and solution pH 7, remarkable removal of 97% of phenol after 2h can be achieved. The rate of electrocoagulation was observed to increase as the phenol concentration decreases; the maximum removal rate was attained at 30 mg L(-1) phenol concentration. For a given current density using an array of closely packed Al screens as anode was found to be more effective than single screen anode, the percentage phenol removal was found to increase with increasing the number of screens per array. After 2h of electrocoagulation, 94.5% of initial phenol concentration was removed from the petroleum refinery wastewater. Energy consumption and aluminum Electrode consumption were calculated per gram of phenol removed. The present study shows that, electrocoagulation of phenol using aluminum electrodes is a promising process.

  17. Removal of overburden soils from buried waste sites

    International Nuclear Information System (INIS)

    Rice, P.M.

    1994-01-01

    Transuranic (TRU) waste buried in pits and trenches is covered with a soil cap, or overburden, to shed water. During retrieval operations, the overburden (expected to be clean) must be removed carefully to avoid breaching the soil/waste matrix within a pit or trench and to confine any possible local spot contamination. This necessitates removal in precise (7.6- to 15.25-cm) increments with a high degree of accuracy. In addition, during overburden removal the overburden must be characterized to a depth that exceeds each cut of soil. A field demonstration was conducted to evaluate a technology for removing overburden soils a the Radioactive Waste Management Complex (RWMC), Subsurface Disposal Area (SDA) at the Idaho National Engineering Laboratory (INEL). The demonstration evaluated equipment performance and techniques for removing overburden soil and controlling contamination and dust. To evaluate the performance of these techniques during removal operations, personnel took air particulate samples, physical measurements of the soil cuts, maneuverability measurements, and rate of soil removal data. The overburden was spiked at specific locations and depths with rare earth tracers to provide a medium for evaluating samples. Analysis to determine the precision and accuracy of the soil removal, amount of dust generated, and potential spread of contamination was performed

  18. Electrically enhanced MBR system for total nutrient removal in remote northern applications.

    Science.gov (United States)

    Wei, V; Elektorowicz, M; Oleszkiewicz, J A

    2012-01-01

    Thousands of sparsely populated communities scatter in the remote areas of northern Canada. It is economically preferable to adopt the decentralized systems to treat the domestic wastewater because of the vast human inhabitant distribution and cold climatic conditions. Electro-technologies such as electrofiltration, elctrofloatation, electrocoagulation and electrokinetic separation have been applied in water and conventional wastewater treatment for decades due to the minimum requirements of chemicals as well as ease of operation. The membrane bioreactor (MBR) is gaining popularity in recent years as an alternative water/wastewater treatment technology. However, few studies have been conducted to hyphenate these two technologies. The purpose of this work is to design a novel electrically enhanced membrane bioreactor (EMBR) as an alternative decentralized wastewater treatment system with improved nutrient removal and reduced membrane fouling. Two identical submerged membranes (GE ZW-1 hollow fiber module) were used for the experiment, with one as a control. The EMBR and control MBR were operated for 4 months at room temperature (20 ± 2 °C) with synthetic feed and 2 months at 10 °C with real sewage. The following results were observed: (1) the transmembrane pressure (TMP) increased significantly more slowly in the EMBR and the interval between the cleaning cycles of the EMBR increased at least twice; (2) the dissolved chemical oxygen demand (COD) or total organic carbon (TOC) in the EMBR biomass was reduced from 30 to 51%, correspondingly, concentrations of the extracellular polymeric substances (EPS), the major suspicious membrane foulants, decreased by 26-46% in the EMBR; (3) both control and EMBR removed >99% of ammonium-N and >95% of dissolved COD, in addition, ortho-P removal in the EMBR was >90%, compared with 47-61% of ortho-P removal in the MBR; and (4) the advantage of the EMBR over the conventional MBR in terms of membrane fouling retardation and

  19. Arsenic removal by magnetic nanocrystalline barium hexaferrite

    Energy Technology Data Exchange (ETDEWEB)

    Patel, Hasmukh A.; Byun, Jeehye; Yavuz, Cafer T., E-mail: yavuz@kaist.ac.kr [Graduate School of EEWS, Korea Advanced Institute of Science and Technology (KAIST) (Korea, Republic of)

    2012-07-15

    Nanoscale magnetite (Fe{sub 3}O{sub 4}) (<15 nm) is known to remove arsenic efficiently but is very difficult to separate or require high magnetic fields to separate out from the waste water after treatment. Anisotropic hexagonal ferrite (BaFe{sub 12}O{sub 19}, BHF) is a well-known permanent magnet (i.e., fridge magnets) and attractive due to its low cost in making large quantities. BHF offers a viable alternative to magnetite nanocrystals for arsenic removal since it features surfaces similar to iron oxides but with much enhanced magnetism. Herein, we employ BHF nanocrystalline materials for the first time in arsenic removal from wastewater. Our results show better (75 %) arsenic removal than magnetite of the similar sizes. The BHF nanoparticles, 6.06 {+-} 0.52 nm synthesized by thermolysis method at 320 Degree-Sign C do not show hexagonal phase, however, subsequent annealing at 750 Degree-Sign C produced pure hexagonal BHF in >200 nm assemblies. By using BHF, we demonstrate that nanoparticle removal is more efficient and fixed bed type cartridge applications are more possible.

  20. Highly atom-economic synthesis of graphene/Mn3O4 hybrid composites for electrochemical supercapacitors

    Science.gov (United States)

    Jiangying, Qu; Feng, Gao; Quan, Zhou; Zhiyu, Wang; Han, Hu; Beibei, Li; Wubo, Wan; Xuzhen, Wang; Jieshan, Qiu

    2013-03-01

    A highly atom-economic procedure for the preparation of reduced graphene oxide/Mn3O4 (rGO/Mn3O4) composites is reported. Pristine graphene oxide/manganese sulfate (GO/MnSO4) suspension produced by modified Hummers method is utilized with high efficiency, which has been in situ converted into GO/Mn3O4 hybrid composite by air oxidation, then into rGO/Mn3O4 composite by means of dielectric barrier discharge (DBD) plasma-assisted deoxygenation. The Mn3O4 content of the rGO/Mn3O4 composites can be readily tailored. It is observed that Mn3O4 nanoparticles of 15-24 nm are well-dispersed on graphene sheets with Mn3O4 loading as high as 90%. The specific capacitance of the as-prepared rGO/Mn3O4 hybrids with 90% Mn3O4 reaches 193 F g-1 when employed as the electrode material in neutral Na2SO4 electrolyte solutions (76 F g-1 for pristine graphene and 95 F g-1 for pure Mn3O4), which indicates the positive synergetic effects from both graphene and attached Mn3O4. The method developed in this study should offer a new technique for the large scale and highly atom-economic production of graphene/MnOx composites for many applications.