Significance of the Capacity Recovery Effect in Pouch Lithium-Sulfur Battery Cells

DEFF Research Database (Denmark)

Knap, Vaclav; Zhang, Teng; Stroe, Daniel Loan

2016-01-01

Lithium-Sulfur (Li-S) batteries are an emerging energy storage technology, which is technically-attractive due to its high theoretical limits; practically, it is expected that Li-S batteries will result into lighter energy storage devices with higher capacities than traditional Lithium-ion...... batteries. One of the actual disadvantages for this technology is the highly pronounced rate capacity effect, which reduces the available capacity to be discharged when high currents are used. This drawback might be addressed by the use of the capacity recovery effect, which by introducing relaxation...... periods between consecutive pulse discharges of the battery, increases the available discharge capacity of the cell. The capacity recovery effect of the Li-S cell is studied in this paper using the pulse discharge technique, considering its dependence on the applied current, discharge step length...

Return to work after spinal cord injury: is it related to wheelchair capacity at discharge from clinical rehabilitation?

NARCIS (Netherlands)

van Velzen, Judith M.; de Groot, Sonja; Post, Marcel W. M.; Slootman, Johannes Hans R.; van Bennekom, Coen A. M.; van der Woude, Lucas H. V.

2009-01-01

To describe the number of people with spinal cord injury who returned to work (RTW) 1 yr after discharge from inpatient rehabilitation and to investigate whether RTW can be predicted from wheelchair capacity at discharge from inpatient rehabilitation, after correction for confounders. Prospective

Improved high-rate charge/discharge performances of LiFePO{sub 4}/C via V-doping

Energy Technology Data Exchange (ETDEWEB)

Sun, C.S.; Zhou, Z.; Xu, Z.G.; Wang, D.G.; Wei, J.P.; Bian, X.K.; Yan, J. [Institute of New Energy Material Chemistry, Nankai University, Tianjin 300071 (China)

2009-09-05

V-doped LiFePO{sub 4}/C cathode materials were prepared through a carbothermal reduction route. The microstructure was characterized by X-ray diffraction, X-ray photoelectron spectroscopy and scanning electron microscopy. The electrochemical Li{sup +} intercalation performances of V-doped LiFePO{sub 4}/C were compared with those of undoped one through galvanostatic intermittent titration technique, cyclic voltamperometry, and electrochemical impedance spectrum. V-doped LiFePO{sub 4}/C showed a high discharge capacity of {proportional_to}70 mAh g{sup -1} at the rate of 20 C (3400 mA g{sup -1}) at room temperature. The significantly improved high-rate charge/discharge capacity is attributed to the increase of Li{sup +} ion ''effective'' diffusion capability. (author)

Capacity Drop on Freeways: Traffic Dynamics, Theory and Modeling

NARCIS (Netherlands)

Yuan, K.

2016-01-01

Earlier studies on the traffic flow on freeways reveal that queue discharge rate cannot
reach as high as the free-flow capacity. This important phenomenon is called the
“Capacity drop”, which indicates that the potential freeway capacity cannot be fully
utilized when discharging traffic

Microwave-assisted preparation of Li3V2(PO4)3/C composite with high-rate capacity

International Nuclear Information System (INIS)

Yan, Ji; Mao, Wen-feng; Xie, Hui; Tang, Zhi-yuan; Yuan, Wei; Chen, Xue-cheng; Xu, Qiang; Ma, Li

2012-01-01

Highlights: ► High-rate Li 3 V 2 (PO 4 ) 3 /C is firstly reported via a microwave-assisted method. ► The reduced particle size is responsible for the improved high-rate performance. ► A discharge capacity of 100 mAh g −1 is obtained at 20 C charge–discharge rate. -- Abstract: A fast sol–gel assisted microwave heating approach has been developed for the synthesis of high-rate Li 3 V 2 (PO 4 ) 3 /C cathode material. This approach can synthesize Li 3 V 2 (PO 4 ) 3 /C particles with high purity and good crystallinity in 12 min at a low microwave power of 320 W. In the voltage range of 3.0–4.3 V, the obtained Li 3 V 2 (PO 4 ) 3 /C delivers a reversible discharge capacity of 100 mAh g −1 after 100 cycles at 20 °C, exhibiting excellent rate capability and cycling performance. The rate-recovery performance also suggests that the Li 3 V 2 (PO 4 ) 3 /C material possesses excellent structure stability after high-rate cycles, presenting excellent application value in high-power lithium ion batteries.

High-repetition-rate short-pulse gas discharge.

Science.gov (United States)

Tulip, J; Seguin, H; Mace, P N

1979-09-01

A high-average-power short-pulse gas discharge is described. This consists of a volume-preionized transverse discharge of the type used in gas lasers driven by a Blumlein energy storage circuit. The Blumlein circuit is fabricated from coaxial cable, is pulse-charged from a high-repetition-rate Marx-bank generator, and is switched by a high-repetition-rate segmented rail gap. The operation of this discharge under conditions typical of rare-gas halide lasers is described. A maximum of 900 pps was obtained, giving a power flow into the discharge of 30 kW.

Application of an antenna excited high pressure microwave discharge to compact discharge lamps

International Nuclear Information System (INIS)

Kando, M; Fukaya, T; Ohishi, Y; Mizojiri, T; Morimoto, Y; Shido, M; Serita, T

2008-01-01

A novel type of high pressure microwave discharge has been investigated to feed the microwave power at the centre of the compact high pressure discharge lamps using the antenna effect. This method of microwave discharge is named as the antenna excited microwave discharge (AEMD). The 2.45 GHz microwave of around 50 W from the solid state microwave generator can sustain a stable plasma column in the small gap between a couple of antennas fitted on the compact lamp filled with discharge gases at a pressure higher than atmosphere. The AEMD has been applied to a compact metal halide lamp and an extremely high pressure mercury discharge lamp. As a result, the metal halide lamp showed high luminous efficacy of around 130 lm W -1 . The excellent lamp properties obtained here can be explained by the low heating loss at the antennas and the lamp wall. The profiles of the microwave electric field in the lamp and the microwave launcher have been numerically calculated to consider the microwave power supply into the lamp

Flower-like SnO2/graphene composite for high-capacity lithium storage

International Nuclear Information System (INIS)

Liu Hongdong; Huang Jiamu; Li Xinlu; Liu Jia; Zhang Yuxin; Du Kun

2012-01-01

Flower-like SnO 2 /graphene composite is synthesized by a simple hydrothermal method for high-capacity lithium storage. The as-prepared products are characterized by XRD, FTIR, FESEM, TGA and Nitrogen adsorption/desorption. The electrochemical performance of the flower-like SnO 2 /graphene composite is measured by cyclic voltammetry and galvanostatic charge/discharge cycling. The results show that the flower-like SnO 2 nanorod clusters are 800 nm in size and homogeneously adhere on graphene sheets. The flower-like SnO 2 /graphene composite displays superior Li-battery performance with large reversible capacity, excellent cyclic performance and good rate capability.

Crystalline-Amorphous Core−Shell Silicon Nanowires for High Capacity and High Current Battery Electrodes

KAUST Repository

Cui, Li-Feng

2009-01-14

Silicon is an attractive alloy-type anode material for lithium ion batteries because of its highest known capacity (4200 mAh/g). However silicon\\'s large volume change upon lithium insertion and extraction, which causes pulverization and capacity fading, has limited its applications. Designing nanoscale hierarchical structures is a novel approach to address the issues associated with the large volume changes. In this letter, we introduce a core-shell design of silicon nanowires for highpower and long-life lithium battery electrodes. Silicon crystalline- amorphous core-shell nanowires were grown directly on stainless steel current collectors by a simple one-step synthesis. Amorphous Si shells instead of crystalline Si cores can be selected to be electrochemically active due to the difference of their lithiation potentials. Therefore, crystalline Si cores function as a stable mechanical support and an efficient electrical conducting pathway while amorphous shells store Li ions. We demonstrate here that these core-shell nanowires have high charge storage capacity (̃1000 mAh/g, 3 times of carbon) with ̃90% capacity retention over 100 cycles. They also show excellent electrochemical performance at high rate charging and discharging (6.8 A/g, ̃20 times of carbon at 1 h rate). © 2009 American Chemical Society.

High-Performance Na-O2 Batteries Enabled by Oriented NaO2 Nanowires as Discharge Products.

Science.gov (United States)

Khajehbashi, S Mohammad B; Xu, Lin; Zhang, Guobin; Tan, Shuangshuang; Zhao, Yan; Wang, Lai-Sen; Li, Jiantao; Luo, Wen; Peng, Dong-Liang; Mai, Liqiang

2018-06-13

Na-O 2 batteries are emerging rechargeable batteries due to their high theoretical energy density and abundant resources, but they suffer from sluggish kinetics due to the formation of large-size discharge products with cubic or irregular particle shapes. Here, we report the unique growth of discharge products of NaO 2 nanowires inside Na-O 2 batteries that significantly boosts the performance of Na-O 2 batteries. For this purpose, a high-spin Co 3 O 4 electrocatalyst was synthesized via the high-temperature oxidation of pure cobalt nanoparticles in an external magnetic field. The discharge products of NaO 2 nanowires are 10-20 nm in diameter and ∼10 μm in length, characteristics that provide facile pathways for electron and ion transfer. With these nanowires, Na-O 2 batteries have surpassed 400 cycles with a fixed capacity of 1000 mA h g -1 , an ultra-low over-potential of ∼60 mV during charging, and near-zero over-potential during discharging. This strategy not only provides a unique way to control the morphology of discharge products to achieve high-performance Na-O 2 batteries but also opens up the opportunity to explore growing nanowires in novel conditions.

Ca-doped LTO using waste eggshells as Ca source to improve the discharge capacity of anode material for lithium-ion battery

Science.gov (United States)

Setiawan, D.; Subhan, A.; Saptari, S. A.

2017-07-01

The necessity of high charge-discharge capacity lithium-ion battery becomes very urgent due to its applications demand. Several researches have been done to meet the demand including Ca doping on Li4Ti5O12 for anode material of lithium-ion batteries. Ca-doped Li4Ti5O12 (LTO) in the form of Li4-xCaxTi5O12 (x = 0, 0.05, 0.075, and 0.1) have been synthesized using simple solid state reaction. The materials preparation involved waste eggshells in the form of CaCO3 as Ca source. The structure and capacity of as-prepared samples were characterized using X-Ray Diffractometer and Cyclic Voltametry. X-Ray Diffractometer characterization revealed that all amount of dopant had entered the lattice structure of LTO successfully. The crystalline sizes were obtained by using Scherrer equation. No significant differences are detected in lattice parameters (˜8.35 Å) and crystalline sizes (˜27 nm) between all samples. Cyclic Voltametry characterization shows that Li4-xCaxTi5O12 (x = 0.05) has highest charge-discharge capacity of 177.14 mAh/g and 181.92 mAh/g, respectively. Redox-potentials of samples show no significant differences with the average of 1.589 V.

Unravelling the origin of irreversible capacity loss in NaNiO 2 for high voltage sodium ion batteries

Energy Technology Data Exchange (ETDEWEB)

Wang, Liguang; Wang, Jiajun; Zhang, Xiaoyi; Ren, Yang; Zuo, Pengjian; Yin, Geping; Wang, Jun

2017-04-01

Layered transition metal compounds have attracted much attention due to their high theoretical capacity and energy density for sodium ion batteries. However, this kind of material suffers from serious irreversible capacity decay during the charge and discharge process. Here, using synchrotron-based operando transmission X-ray microscopy and high-energy X-ray diffraction combined with electrochemical measurements, the visualization of the dissymmetric phase transformation and structure evolution mechanism of layered NaNiO2 material during initial charge and discharge cycles are clarified. Phase transformation and deformation of NaNiO2 during the voltage range of below 3.0 V and over 4.0 V are responsible for the irreversible capacity loss during the first cycling, which is also confirmed by the evolution of reaction kinetics behavior obtained by the galvanostatic intermittent titration technique. These findings reveal the origin of the irreversibility of NaNiO2 and offer valuable insight into the phase transformation mechanism, which will provide underlying guidance for further development of high-performance sodium ion batteries.

Investigation of the Self-Discharge Behavior of Lithium-Sulfur Batteries

DEFF Research Database (Denmark)

Knap, Vaclav; Stroe, Daniel Loan; Swierczynski, Maciej Jozef

2016-01-01

Lithium-Sulfur (Li-S) batteries represent a perspective energy storage technology, which reaches very high theoretical limits in terms of specific capacity, specific energy, and energy density. However, Li-S batteries are governed by the polysulfide shuttle mechanism, which causes fast capacity...... fade, low coulombic efficiency, and high self-discharge rate. The self-discharge is an important characteristic of Li-S batteries for both practical applications and laboratory testing, which is highly dependent on the operating conditions. Thus, to map and to understand the Li-S self...

Design of a 10 MJ fast discharging homopolar machine

International Nuclear Information System (INIS)

Stillwagon, R.E.; Thullen, P.

1977-01-01

The design of a fast discharging homopolar machine is described. The machine capacity is 10 MJ with a 30 ms energy delivery time. The salient features of the machine are relatively high terminal voltage, fast discharge time, high power density and high efficiency. The machine integrates several new technologies including high surface speeds, large superconducting magnets and current collection at high density

A study on the development of hypo-stoichiometric Zr-based hydrogen storage alloys with ultra-high capacity for anode material of Ni/MH secondary battery

Energy Technology Data Exchange (ETDEWEB)

Lee, S.-M.; Lee, H.; Kim, J.-H.; Lee, P.S.; Lee, J.-Y. [Korea Advanced Inst. of Science and Technology, Taejon (Korea). Dept. of Materials Science and Engineering

2000-08-10

Some hypo-stoichiometric Zr-based Laves phase alloys were prepared and studied from a viewpoint of discharge capacity for electrochemical application. After careful alloy design of ZrMn{sub 2}-based hydrogen storage alloys through changing their stoichiometry while substituting or adding some alloying elements, the Zr(Mn{sub 0.2}V{sub 0.2}Ni{sub 0.6}){sub 1.8} alloy reveals relatively good properties with regard to hydrogen storage capacity, hydrogen equilibrium pressure and electrochemical discharge capacity. In order to improve the discharge capacity and rate-capability, Zr is partially replaced by Ti. The discharge capacity of Zr{sub 1-x}Ti{sub x}(Mn{sub 0.2}V{sub 0.2}Ni{sub 0.6}){sub 1.8} (x=0.0, 0.2, 0.3, 0.4, 0.6) alloy electrodes at 30 C reaches a maximum value and decreases as the Ti fraction increases. In view of electrochemical and thermodynamic characteristics, the occurrence of a maximal phenomenon of the electrochemical discharge capacity of the alloy is attributed to a competition between decreasing hydrogen storage capacity and increasing rate-capability with Ti fraction. However, as the Ti fraction increases, the discharge capacity decreases drastically with repeated electrochemical cycling. Judging from the analysis of surface composition by Auger electron spectroscopy (AES), the rapid degradation with increasing Ti fraction in Zr-based alloy is ascribed to the fast growth of the oxygen-penetrated layer with cycling. Therefore, it is assured that the stoichiometry and Ti fraction should be optimized to obtain a good cycle life of the electrode maintaining high discharge capacity. On the basis of above results, the hydrogen storage capacity of the alloy with optimized composition (Zr{sub 0.65}Ti{sub 0.35}(Mn{sub 0.3}V{sub 0.14}Cr{sub 0.11}Ni{sub 0.65}){sub 1.76}) is about 1.68 wt% under 10 atm of equilibrium hydrogen pressure. (orig.)

High intensity discharge device containing oxytrihalides

Science.gov (United States)

Lapatovich, W.P.; Keeffe, W.M.; Liebermann, R.W.; Maya, J.

1987-06-09

A fill composition for a high intensity discharge device including mercury, niobium oxytrihalide, and a molecular stabilization agent is provided. The molar ratio of niobium oxytrihalide to the molecular stabilization agent in the fill is in the range of from about 5:1 to about 7.5:1. Niobium oxytrihalide is present in the fill in sufficient amount to produce, by dissociation in the discharge, atomic niobium, niobium oxide, NbO, and niobium dioxide, NbO[sub 2], with the molar ratio of niobium-containing vapor species to mercury in the fill being in the range of from about 0.01:1 to about 0.50:1; and mercury pressure of about 1 to about 50 atmospheres at lamp operating temperature. There is also provided a high intensity discharge device comprising a sealed light-transmissive arc tube; the arc tube including the above-described fill; and an energizing means for producing an electric discharge within the arc tube. 7 figs.

Cryogenic high current discharges

International Nuclear Information System (INIS)

Meierovich, B.E.

1994-01-01

Z-pinches formed from frozen deuterium fibers by a rapidly rising current have enhanced stability and high neutron yield. The efforts to understand the enhanced stability and neutron yield on the basis of classical picture of Bennett equilibrium of the current channel has not given satisfactory results. The traditional approach does not take into account the essential difference between the frozen deuterium fiber Z-pinches and the usual Z-pinches such as exploding wires or classical gas-puffed Z-pinches. The very low temperature of the fiber atoms (10 K), together with the rapidly rising current, result in the coexistence of a high current channel with unionized fiber atoms for a substantial period of time. This phenomena lasts during the risetime. This approach takes into account the difference of the breakdown in a dielectric deuterium fiber and the breakdown in a metallic wire. This difference is essential to the understanding of specific features of cryogenic high current discharges. Z-pinches in frozen deuterium fibers should be considered as a qualitatively new phenomenon on the boundary of cryogenic and high current physics. It is a start of a new branch in plasma physics: the physics of cryogenic high current discharges

High-current discharge channel contraction in high density gas

International Nuclear Information System (INIS)

Rutberg, Ph. G.; Bogomaz, A. A.; Pinchuk, M. E.; Budin, A. V.; Leks, A. G.; Pozubenkov, A. A.

2011-01-01

Research results for discharges at current amplitudes of 0.5-1.6 MA and current rise rate of ∼10 10 A/s are presented. The discharge is performed in the hydrogen environment at the initial pressure of 5-35 MPa. Initiation is implemented by a wire explosion. The time length of the first half-period of the discharge current is 70-150 μs. Under such conditions, discharge channel contraction is observed; the contraction is followed by soft x-ray radiation. The phenomena are discussed, which are determined by high density of the gas surrounding the discharge channel. These phenomena are increase of the current critical value, where the channel contraction begins and growth of temperature in the axis region of the channel, where the initial density of the gas increases.

Study on Self-discharge Behavior of Lithium-Sulfur Batteries

DEFF Research Database (Denmark)

Knap, Vaclav; Stroe, Daniel Loan; Swierczynski, Maciej Jozef

2015-01-01

Lithium-Sulfur (Li-S) batteries are a promising energy storage technology, which draws interest due to their high theoretical limits in terms of specific capacity, specific energy and energy density. However as a drawback, they suffer from a high self-discharge rate, which is mainly caused...... by ongoing polysulfide shuttle. In this paper, the self-discharge behavior of Li-S batteries is experimentally investigated, considering various conditions as depth-of-discharge, temperature and idling time. The self-discharge rate under different conditions is identified and quantified. Moreover...

Photo-preionization stabilized high-pressure glow-discharge lasers

International Nuclear Information System (INIS)

Von Bergmann, H.M.

1980-07-01

Simple nanosecond stabilization and pulsing techniques were developed to excite high-pressure gas-discharge lasers at high overvoltages and high specific power loadings. The techniques were applied to a variety of ultraviolet and visible laser systems employing fast transmission line pulsers and conventional LC generators. The stabilization procedures are evaluated and the parameters which control the geometry and uniformity of the high-pressure glow discharges are investigated. A detailed study of the formation, distribution and spectral characteristics of the fast surface corona discharges is provided. The stabilization and pulsing techniques were used for the corona and glow discharge excitation of high-pressure ultraviolet N 2 lasers. A detailed spectrally- and temporally-resolved study of the gain, fluorescence and energy extraction characteristics of the atmospheric pressure N 2 plasmas is provided

Cobalt Oxide Porous Nanofibers Directly Grown on Conductive Substrate as a Binder/Additive-Free Lithium-Ion Battery Anode with High Capacity.

Science.gov (United States)

Liu, Hao; Zheng, Zheng; Chen, Bochao; Liao, Libing; Wang, Xina

2017-12-01

In order to reduce the amount of inactive materials, such as binders and carbon additives in battery electrode, porous cobalt monoxide nanofibers were directly grown on conductive substrate as a binder/additive-free lithium-ion battery anode. This electrode exhibited very high specific discharging/charging capacities at various rates and good cycling stability. It was promising as high capacity anode materials for lithium-ion battery.

High Discharge Rate Electrodeposited Zinc Electrode for Use in Alkaline Microbattery

Directory of Open Access Journals (Sweden)

A. L. Nor Hairin

2012-01-01

Full Text Available High discharge rate zinc electrode is prepared from electrodeposition process. The electrolytic bath consists of zinc chloride as the metal source and ammonium chloride as the supporting electrolyte. The concentration of the supporting electrolyte is varied from zero until 4 M, while the concentration of zinc chloride is fixed at 2 M. The aim is to produce a porous zinc coating with an enhanced and intimate interfacial area per unit volume. These characteristics shall contribute towards reduced ohmic losses, improved active material utilization, and subsequently producing high rate capacity electrochemical cell. Nitrogen physisorption at 77 K is used to measure the BET surface area and pore volume density of the zinc electrodeposits. The electrodeposited zinc electrodes are then fabricated into alkaline zinc-air microbattery measuring 1 cm2 area x ca. 305 µm thick. The use of inorganic MCM-41 membrane separator enables the fabrication of a compact cell design. The quality of the electrodeposited zinc electrodes is gauged directly from the electrochemical performance of zinc-air cell. Zinc electrodeposits prepared from electrolytic bath of 2 M NH4Cl produces the highest discharge capacity.ABSTRAK: Elektrod zink dengan kadar discas tinggi telah dihasilkan dengan proses saduran elektrokimia. Takungan elektrolit terdiri daripada zink klorida sebagai sumber logam dan ammonium klorida sebagai elektrolit sokongan. Kepekatan elektrolit sokongan diubah daripada sifar hingga 4 M, sementara kepekatan zink klorida ditetapkan pada 2 M. Ini bertujuan untuk mendapatkan saduran zink yang poros dengan luas permukaan per unit isipadu dan sentuhan antaramuka yang dipertingkatkan. Ciri-ciri ini akan menyumbang terhadap pengurangan kehilangan disebabkan kerintangan, pertambahan dalam gunapakai bahan aktif dan akhirnya menghasilkan sel elektrokimia berprestasi tinggi. Physisorpsi nitrogen pada 77 K telah digunakan untuk mengukur luas permukaan BET dan isipadu liang

High lithium storage capacity achieved by regulating monodisperse C/In{sub 2}O{sub 3} nanosheet composite with double phases

Energy Technology Data Exchange (ETDEWEB)

Yue, Lu; Pan, Xueqian; Chen, Shangqian; Song, Jialing; Liu, Cheng [Key Laboratory for Advanced Technology in Environmental Protection of Jiangsu Province, Yancheng Institute of Technology, Jiangsu, 224051 (China); Luo, Gaixia [Department of Physics, Yancheng Institute of Technology, Jiangsu, 224051 (China); Guan, Rongfeng [Key Laboratory for Advanced Technology in Environmental Protection of Jiangsu Province, Yancheng Institute of Technology, Jiangsu, 224051 (China); Zhang, Wenhui, E-mail: zwhuizi000@sina.com [Key Laboratory for Advanced Technology in Environmental Protection of Jiangsu Province, Yancheng Institute of Technology, Jiangsu, 224051 (China)

2017-06-01

Monodisperse C/In{sub 2}O{sub 3} nanosheet composites are prepared by D-fructose-assisted solvothermal approach. The effects of carbon content on the morphological evolution and electrochemical performance of C/In{sub 2}O{sub 3} nanosheet composites are investigated. The SEM and TEM are used to study the morphological evolution. C/In{sub 2}O{sub 3} nanosheet composite electrode with 17.3% carbon content exhibits the highest reversible capacity of 1639 mAh g{sup -1} over 100 cycles at a current density of 100 mA g{sup -1} and maintains the best discharge capacity of 782 mAh g{sup -1} over 400 cycles at a current density of 400 mA g{sup -1} for reported In{sub 2}O{sub 3} based anode materials to date. - Highlights: • Monodisperse carbon/In{sub 2}O{sub 3} nanosheet composites have been synthesized via D-fructose-assisted solvothermal approach. • The prepared electrode exhibited high reversible discharge capacity of 1639 mAh g{sup -1} over 100 cycles. • The prepared electrode maintained the discharge capacity of 782 mAh g{sup -1} over 400 cycles at 400 mA g{sup -1}.

The effect of high charging rates activation on the specific discharge capacity and efficiency of a negative electrode based on a LaMgAlMnCoNi alloy

International Nuclear Information System (INIS)

Ferreira, E.A.; Zarpelon, L.M.C.; Casini, J.C.S.; Takiishi, H.; Faria, R.N.

2009-01-01

A nickel-metal hydride (Ni-MH) rechargeable battery has been prepared using a La 0.7 Mg 0.3 Al 0.3 Mn 0.4 Co 0.5 Ni 3.8 alloy as the negative electrode. The maximum discharge capacity of the La 0.7 Mg 0.3 Al 0.3 Mn 0.4 Co 0.5 Ni 3.8 alloy has been determined (350 mAh/g). Using a high starting charging rate (2857 mAg -1 ) an efficiency of 49% has been achieved in the 4 th cycle. The alloy and powders have been characterized by scanning electron microscopy (SEM), energy dispersive X-ray analysis (EDX) and X-ray diffraction (XRD). (author)

High pressure discharges in cavities formed by microfabrication techniques

International Nuclear Information System (INIS)

Khan, B.A.; Cammack, D.A.; Pinker, R.D.; Racz, J.

1997-01-01

High pressure discharges are the basis of small high intensity light sources. In this work, we demonstrate the formation of high pressure discharges, in cavities formed by applying micromachining and integrated circuit techniques to quartz substrates. Cavities containing varying amounts of mercury and argon were fabricated to obtain high pressure discharges. A high pressure mercury discharge was formed in the electrodeless cavities by exciting them with a microwave source, operating at 2.45 GHz and in the electroded cavities by applying a dc voltage. The contraction of the discharge into a high pressure arc was observed. A broad emission spectrum due to self-absorption and collisions between excited atoms and normal atoms, typical of high pressure mercury discharges, was measured. The light output and efficacy increased with increasing pressure. The measured voltage was used to estimate the pressure within the electroded cavities, which is as high as 127 atm for one of the two cavities discussed in this work. Efficacies over 40 lumens per watt were obtained for the electrodeless cavities and over 50 scr(l)m/W for the electroded cavities. copyright 1997 American Institute of Physics

Hollow Carbon Nanofiber-Encapsulated Sulfur Cathodes for High Specific Capacity Rechargeable Lithium Batteries

KAUST Repository

Zheng, Guangyuan

2011-10-12

Sulfur has a high specific capacity of 1673 mAh/g as lithium battery cathodes, but its rapid capacity fading due to polysulfides dissolution presents a significant challenge for practical applications. Here we report a hollow carbon nanofiber-encapsulated sulfur cathode for effective trapping of polysulfides and demonstrate experimentally high specific capacity and excellent electrochemical cycling of the cells. The hollow carbon nanofiber arrays were fabricated using anodic aluminum oxide (AAO) templates, through thermal carbonization of polystyrene. The AAO template also facilitates sulfur infusion into the hollow fibers and prevents sulfur from coating onto the exterior carbon wall. The high aspect ratio of the carbon nanofibers provides an ideal structure for trapping polysulfides, and the thin carbon wall allows rapid transport of lithium ions. The small dimension of these nanofibers provides a large surface area per unit mass for Li2S deposition during cycling and reduces pulverization of electrode materials due to volumetric expansion. A high specific capacity of about 730 mAh/g was observed at C/5 rate after 150 cycles of charge/discharge. The introduction of LiNO3 additive to the electrolyte was shown to improve the Coulombic efficiency to over 99% at C/5. The results show that the hollow carbon nanofiber-encapsulated sulfur structure could be a promising cathode design for rechargeable Li/S batteries with high specific energy. © 2011 American Chemical Society.

Three-dimensionally interconnected Si frameworks derived from natural halloysite clay: a high-capacity anode material for lithium-ion batteries.

Science.gov (United States)

Wan, Hao; Xiong, Hao; Liu, Xiaohe; Chen, Gen; Zhang, Ning; Wang, Haidong; Ma, Renzhi; Qiu, Guanzhou

2018-05-23

On account of its high theoretical capacity, silicon (Si) has been regarded as a promising anode material for Li-ion batteries. Extracting Si content from earth-abundant and low-cost aluminosilicate minerals, rather than from artificial silica (SiO2) precursors, is a more favorable and practical method for the large-scale application of Si anodes. In this work, three-dimensionally interconnected (3D-interconnected) Si frameworks with a branch diameter of ∼15 nm are prepared by the reduction of amorphous SiO2 nanotubes derived from natural halloysite clay. Benefiting from their nanostructure, the as-prepared 3D-interconnected Si frameworks yield high reversible capacities of 2.54 A h g-1 at 0.1 A g-1 after 50 cycles, 1.87 A h g-1 at 0.5 A g-1 after 200 cycles, and 0.97 A h g-1 at 2 A g-1 after a long-term charge-discharge process of 500 cycles, remarkably outperforming the commercial Si material. Further, when the as-prepared Si frameworks and commercial LiCoO2 cathodes are paired in full cells, a high anode capacity of 0.98 A h g-1 is achieved after 100 cycles of rapid charge/discharge at 2 A g-1. This work provides a new strategy for the synthesis of high-capacity Si anodes derived from natural aluminosilicate clay.

High-capacity lithium-ion battery conversion cathodes based on iron fluoride nanowires and insights into the conversion mechanism.

Science.gov (United States)

Li, Linsen; Meng, Fei; Jin, Song

2012-11-14

The increasing demands from large-scale energy applications call for the development of lithium-ion battery (LIB) electrode materials with high energy density. Earth abundant conversion cathode material iron trifluoride (FeF(3)) has a high theoretical capacity (712 mAh g(-1)) and the potential to double the energy density of the current cathode material based on lithium cobalt oxide. Such promise has not been fulfilled due to the nonoptimal material properties and poor kinetics of the electrochemical conversion reactions. Here, we report for the first time a high-capacity LIB cathode that is based on networks of FeF(3) nanowires (NWs) made via an inexpensive and scalable synthesis. The FeF(3) NW cathode yielded a discharge capacity as high as 543 mAh g(-1) at the first cycle and retained a capacity of 223 mAh g(-1) after 50 cycles at room temperature under the current of 50 mA g(-1). Moreover, high-resolution transmission electron microscopy revealed the existence of continuous networks of Fe in the lithiated FeF(3) NWs after discharging, which is likely an important factor for the observed improved electrochemical performance. The loss of active material (FeF(3)) caused by the increasingly ineffective reconversion process during charging was found to be a major factor responsible for the capacity loss upon cycling. With the advantages of low cost, large quantity, and ease of processing, these FeF(3) NWs are not only promising battery cathode materials but also provide a convenient platform for fundamental studies and further improving conversion cathodes in general.

ELMs IN DIII-D HIGH PERFORMANCE DISCHARGES

International Nuclear Information System (INIS)

TURNBULL, A.D; LAO, L.L; OSBORNE, T.H; SAUTER, O; STRAIT, E.J; TAYLOR, T.S; CHU, M.S; FERRON, J.R; GREENFIELD, C.M; LEONARD, A.W; MILLER, R.L; SNYDER, P.B; WILSON, H.R; ZOHM, H

2003-01-01

A new understanding of edge localized modes (ELMs) in tokamak discharges is emerging [P.B. Snyder, et al., Phys. Plasmas, 9, 2037 (2002)], in which the ELM is an essentially ideal magnetohydrodynamic (MHD) instability and the ELM severity is determined by the radial width of the linearly unstable MHD kink modes. A detailed, comparative study of the penetration into the core of the respective linear instabilities in a standard DIII-D ELMing, high confinement mode (H-mode) discharge, with that for two relatively high performance discharges shows that these are also encompassed within the framework of the new model. These instabilities represent the key, limiting factor in extending the high performance of these discharges. In the standard ELMing H-mode, the MHD instabilities are highly localized in the outer few percent flux surfaces and the ELM is benign, causing only a small temporary drop in the energy confinement. In contrast, for both a very high confinement mode (VH-mode) and an H-mode with a broad internal transport barrier (ITB) extending over the entire core and coalesced with the edge transport barrier, the linearly unstable modes penetrate well into the mid radius and the corresponding consequences for global confinement are significantly more severe. The ELM accordingly results in an irreversible loss of the high performance

Titanium oxynitride thin films as high-capacity and high-rate anode materials for lithium-ion batteries

International Nuclear Information System (INIS)

Chiu, Kuo-Feng; Su, Shih-Hsuan; Leu, Hoang-Jyh; Hsia, Chen-Hsien

2015-01-01

Titanium oxynitride (TiO_xN_y) was synthesized by reactive magnetron sputtering in a mixed N_2/O_2/Ar gas at ambient temperature. TiO_xN_y thin films with various amounts of nitrogen contents were deposited by varying the N_2/O_2 ratios in the background gas. The synthesized TiO_xN_y films with different compositions (TiO_1_._8_3_7N_0_._0_6_0_, TiO_1_._8_9_0N_0_._0_6_8_, TiO_1_._8_6_5N_0_._0_7_3, and TiO_1_._8_8_2N_0_._1_6_3) all displayed anatase phase, except TiO_1_._8_8_2N_0_._1_6_3. The impedances and grain sizes showed obvious variations with the nitrogen contents. A wide potential window from 3.0 V to 0.05 V, high-rate charge–discharge testing, and long cycle testing were applied to investigate the performances of synthesized TiO_xN_y and pure TiO_2 as anodes for lithium-ion batteries. These TiO_xN_y anodes can be cycled under high rates of 125 μA/cm"2 (10 °C) because of the lower charge–transfer resistance compared with the TiO_2 anode. At 10 °C the discharge capacity of the optimal TiO_xN_y composition is 1.5 times higher than that of pure TiO_2. An unexpectedly large reversible capacity of ~ 300 μAh/cm"2 μm (~ 800 mAh/g) between 1.0 V and 0.05 V was recorded for the TiO_xN_y anodes. The TiO_xN_y anode was cycled (3.0 V to 0.05 V) at 10 °C over 300 times without capacity fading while delivering a capacity of ~ 150 μAh/cm"2 μm (~ 400 mAh/g). - Highlights: • Titanium oxynitride (TiO_xN_y) thin films as anode materials were studied. • TiO_xN_y thin films with various amounts of nitrogen contents were studied_. • High rate capability of TiO_xN_y was studied.

Glow discharging device

International Nuclear Information System (INIS)

Maeno, Katsuki; Kawasaki, Kozo; Hiratsuka, Hajime; Kawashima, Shuichi.

1989-01-01

In a thermonuclear device, etc. impurities adsorbed to inner walls of a vacuum vessel by glow discharge are released to clean the vacuum vessel for preventing intrusion of the impurities into plasmas. The object of the present invention is to minimize the capacity of a power source equipment for the glow discharge device to the least extent. That is, a stabilization resistance is connected in series between each of a plurality of anodes which are inserted and arranged at the inside of a vacuum vessel as a cathode and a power source respectively. The resistance value R is selected so as to satisfy the relation: R < (Vi - Vm)/Ii, in which Vi: glow discharge starting voltage, Vm: glow discharge keeping voltage, Ii: glow discharge starting current. Accordingly, if a voltage is applied from a power source to a plurality of anodes, scattering of electric discharge between the anodes can be suppressed and the effect of voltage drop during discharge by the stabilization resistance can be eliminated. As a result, it is possible to provide an economically advantageous glow discharge device with the capacity for the power source facility being to the least extent. (K.M.)

Hydroxylamine hydrochloride: A novel anode material for high capacity lithium-ion batteries

Science.gov (United States)

Shao, Lianyi; Shu, Jie; Lao, Mengmeng; Lin, Xiaoting; Wu, Kaiqiang; Shui, Miao; Li, Peng; Long, Nengbing; Ren, Yuanlong

2014-12-01

H3NOHCl is used for the first time as anode material for lithium-ion batteries. Electrochemical results show that H3NOHCl with particle size of 4-12 μm can deliver an initial charge capacity of 1018.6 mAh g-1, which is much higher than commercial graphite. After 30 cycles, the reversible capacity can be kept at 676.1 mAh g-1 at 50 mA g-1. Up to 50 cycles, H3NOHCl still maintains a lithium storage capacity of 368.9 mAh g-1. Even cycled at 200 mA g-1, H3NOHCl can deliver a charge capacity of 715.7 mAh g-1. It suggests that H3NOHCl has high lithium storage capacity, excellent cycling stability and outstanding rate performance. Besides, the electrochemical reaction between H3NOHCl and Li is also investigated by various ex-situ techniques. It can be found that H3NOHCl irreversibly decomposes into Li3N and LiCl during the initial discharge process and LiNO2 can be formed after a reverse charge process.

1990s: High Capacity Backbones

Indian Academy of Sciences (India)

First page Back Continue Last page Overview Graphics. 1990s: High Capacity Backbones. Backbone capacities increased from 2.5 Gb/s to 100s of Gb/s during the 1990's. Wavelength division multiplexing with 160 waves of 10 Gb/s was commercially available. Several high-capacity backbones built in the US and Europe.

Comparative Analysis of Battery Behavior with Different Modes of Discharge for Optimal Capacity Sizing and BMS Operation

Directory of Open Access Journals (Sweden)

Mazhar Abbas

2016-10-01

Full Text Available Battery-operated systems are always concerned about the proper management and sizing of a battery. A Traditional Battery Management System (BMS only includes battery-aware task scheduling based on the discharge characteristics of a whole battery pack and do not take into account the mode of the load being served by the battery. On the other hand, an efficient and intelligent BMS should monitor the battery at a cell level and track the load with significant consideration of the load mode. Depending upon the load modes, the common modes of discharge (MOD of a battery identified so far are Constant Power Mode (CPM, Constant Current Mode (CCM and Constant Impedance Mode (CIM. This paper comparatively analyzes the discharging behavior of batteries at an individual cell level for different load modes. The difference in discharging behavior from mode to mode represents the study of the mode-dependent behavior of the battery before its deployment in some application. Based on simulation results, optimal capacity sizing and BMS operation of battery for an assumed situation in a remote microgrid has been proposed.

Phenol-Catalyzed Discharge in the Aprotic Lithium-Oxygen Battery.

Science.gov (United States)

Gao, Xiangwen; Jovanov, Zarko P; Chen, Yuhui; Johnson, Lee R; Bruce, Peter G

2017-06-01

Discharge in the lithium-O 2 battery is known to occur either by a solution mechanism, which enables high capacity and rates, or a surface mechanism, which passivates the electrode surface and limits performance. The development of strategies to promote solution-phase discharge in stable electrolyte solutions is a central challenge for development of the lithium-O 2 battery. Here we show that the introduction of the protic additive phenol to ethers can promote a solution-phase discharge mechanism. Phenol acts as a phase-transfer catalyst, dissolving the product Li 2 O 2 , avoiding electrode passivation and forming large particles of Li 2 O 2 product-vital requirements for high performance. As a result, we demonstrate capacities of over 9 mAh cm -2 areal , which is a 35-fold increase in capacity compared to without phenol. We show that the critical requirement is the strength of the conjugate base such that an equilibrium exists between protonation of the base and protonation of Li 2 O 2 . © 2017 The Authors. Published by Wiley-VCH Verlag GmbH & Co. KGaA.

Capacity extended bismuth-antimony cathode for high-performance liquid metal battery

Science.gov (United States)

Dai, Tao; Zhao, Yue; Ning, Xiao-Hui; Lakshmi Narayan, R.; Li, Ju; Shan, Zhi-wei

2018-03-01

Li-Bi based liquid metal batteries (LMBs) have attracted interest due to their potential for solving grid scale energy storage problems. In this study, the feasibility of replacing the bismuth cathode with a bismuth-antimony alloy cathode in lithium based LMBs is investigated. The influence of the Bi:Sb ratio on voltage characteristics is evaluated via the constant current discharge method and electrochemical titration. On observing the cross section of the electrode at various stages of discharge, it is determined that both Sb and Bi form solid intermetallics with Li on the cathode. Additionally, the addition of Bi not only reduces the melting temperature of the Bi:Sb intermetallic but also actively contributes to the electrode capacity. Thereafter, a Li|LiCl-LiF|Sb-Bi liquid metal battery with 3 A h nameplate capacity, assembled and cycled at 1 C rate, is found to possess a stable capacity for over 160 cycles. The overall performance of this battery is discussed in the context of cost effectiveness, energy and coulombic efficiencies.

Bivariate quadratic method in quantifying the differential capacitance and energy capacity of supercapacitors under high current operation

Science.gov (United States)

Goh, Chin-Teng; Cruden, Andrew

2014-11-01

Capacitance and resistance are the fundamental electrical parameters used to evaluate the electrical characteristics of a supercapacitor, namely the dynamic voltage response, energy capacity, state of charge and health condition. In the British Standards EN62391 and EN62576, the constant capacitance method can be further improved with a differential capacitance that more accurately describes the dynamic voltage response of supercapacitors. This paper presents a novel bivariate quadratic based method to model the dynamic voltage response of supercapacitors under high current charge-discharge cycling, and to enable the derivation of the differential capacitance and energy capacity directly from terminal measurements, i.e. voltage and current, rather than from multiple pulsed-current or excitation signal tests across different bias levels. The estimation results the author achieves are in close agreement with experimental measurements, within a relative error of 0.2%, at various high current levels (25-200 A), more accurate than the constant capacitance method (4-7%). The archival value of this paper is the introduction of an improved quantification method for the electrical characteristics of supercapacitors, and the disclosure of the distinct properties of supercapacitors: the nonlinear capacitance-voltage characteristic, capacitance variation between charging and discharging, and distribution of energy capacity across the operating voltage window.

High capacity Si/DC/MWCNTs nanocomposite anode materials for lithium ion batteries

International Nuclear Information System (INIS)

Zhou Zhibin; Xu Yunhua; Liu Wengang; Niu Libin

2010-01-01

Nanocomposites comprising nanocrystal silicon (Si), disordered carbon (DC), and multi-walled carbon nanotubes (MWCNTs) - denoted as Si/DC/MWCNTs - have been prepared by pyrolyzing the phenol-formaldehyde resin (PFR) mixed with Si and MWCNTs. This nanocomposite anode material showed a discharge capacity of 1216 mAh/g in the first cycle, and a charge capacity of 711 mAh/g after 20 charge-discharge, much higher than that of Si/DC composite. It can be observed that Si particles wrapped in MWCNTs were homogeneously embedded into the matrix of the DC. The improved electrochemical performance is hypothesized to be mainly attributed to the morphology stability of the composite due to the excellent resiliency and distinct electric conductivity of the MWCNTs.

Exercise Capacity and Functional Performance in Heart Failure Patients Supported by a Left Ventricular Assist Device at Discharge From Inpatient Rehabilitation.

Science.gov (United States)

Schmidt, Thomas; Bjarnason-Wehrens, Birna; Bartsch, Petra; Deniz, Ezin; Schmitto, Jan; Schulte-Eistrup, Sebastian; Willemsen, Detlev; Reiss, Nils

2018-01-01

Adequate physical and functional performance is an important prerequisite for renewed participation and integration in self-determined private and (where appropriate) professional lives following left ventricular assist device (LVAD) implantation. During cardiac rehabilitation (CR), individually adapted exercise programs aim to increase exercise capacity and functional performance. A retrospective analysis of cardiopulmonary exercise capacity and functional performance in LVAD patients at discharge from a cardiac rehabilitation program was conducted. The results from 68 LVAD patients (59 males, 9 females; 55.9 ± 11.7 years; 47 HVAD, 2 MVAD, 15 HeartMate II, 4 HeartMate 3, and 4 different implanting centers) were included in the analysis. Exercise capacity was assessed using a cardiopulmonary exercise test on a bicycle ergometer (ramp protocol; 10 W/min). The 6-min walk test was used to determine functional performance. At discharge from CR (53 ± 17 days after implantation), the mean peak work load achieved was 62.2 ± 19.3 W (38% of predicted values) or 0.79 ± 0.25 W/kg body weight. The mean cardiopulmonary exercise capacity (relative peak oxygen uptake) was 10.6 ± 5.3 mL/kg/min (37% of predicted values). The 6-min walk distance improved significantly during CR (325 ± 106 to 405 ± 77 m; P exercise capacity remains considerably restricted. In contrast, functional performance, measured by the 6-min walk distance, reaches an acceptable level. Light everyday tasks seem to be realistically surmountable for patients, making discharge from inpatient rehabilitation possible. Long-term monitoring is required in order to evaluate the situation and how it develops further. © 2017 International Center for Artificial Organs and Transplantation and Wiley Periodicals, Inc.

Technology of discharge and laser resonators for high power CO2 lasers. Koshutsuryoku CO2 laser ni tsukawareru hoden reiki laser kyoshinki gijutsu

Energy Technology Data Exchange (ETDEWEB)

Takenaka, Y.; Kuzumoto, M. (Mitsubishi Electric Corp., Tokyo (Japan))

1994-03-20

This paper describes discharge excitation technology and resonator technology as basic technologies for high power CO2 lasers. As a result of progress in high-frequency power element techniques, the discharge excitation technology now generally uses laser excitation using AC discharge of capacity coupling type. Its representative example is silent discharge (SD) excitation. This is a system to excite laser by applying high voltages with as high frequency as 100 kHz to 1 MHz across a pair of electrodes covered with a dielectric material. The system maintains stability in discharge even if power supply voltage amplitude is modulated, and easily provides pulse outputs. Discharge excitation for diffusion cooled type CO2 laser generates a discharge in a gap with a gap length of about 2 mm, and can perform gas cooling by means of thermal conduction of gas, whereas a compact resonator can be fabricated. A resonator for the diffusion cooled type CO2 laser eliminates gas circulation and cooling systems, hence the device can be made more compact. A report has been given that several of these compact resonators were combined, from which a laser output of 85W was obtained by using RF discharge of 2kW. 43 refs., 21 figs.

High pressure microwave discharge for electrodeless Xe-lamp

International Nuclear Information System (INIS)

Kudela, J.; Kando, M.

1998-01-01

Preliminary results are presented of the investigation into the high pressure Xe microwave discharge in bent tubes, sustained by electromagnetic surface wave. The research was aimed to help with the design of a new generation of high intensity light sources with generally more complex shapes than those commonly used. The results show that the electromagnetic surface wave can effectively sustain discharge in tubes with various bending radii within the large pressure range. The curved shapes of discharge tubes improve the cooling of the lamp which is one of the major technological difficulties. It was shown that under relatively lower powers and higher gas pressures (100 Torr) the discharge exhibits a streamer-like filamentation and the branching of filaments. The phenomena of the effective sustaining of the discharge by surface wave propagation along curved plasma columns will be investigated in more detail by measurements of the profiles of surface wave electric and magnetic field intensities. (author)

Titanium oxynitride thin films as high-capacity and high-rate anode materials for lithium-ion batteries

Energy Technology Data Exchange (ETDEWEB)

Chiu, Kuo-Feng [Department of Materials Science and Engineering, Feng Chia University, 100 Wenhwa Rd., Taichung 40724, Taiwan (China); Su, Shih-Hsuan, E-mail: minimono42@gmail.com [Department of Materials Science and Engineering, Feng Chia University, 100 Wenhwa Rd., Taichung 40724, Taiwan (China); Leu, Hoang-Jyh [Master' s Program of Green Energy Science and Technology, Feng Chia University, 100 Wenhwa Rd., Taichung 40724, Taiwan (China); Hsia, Chen-Hsien [Department of Materials Science and Engineering, Feng Chia University, 100 Wenhwa Rd., Taichung 40724, Taiwan (China)

2015-12-01

Titanium oxynitride (TiO{sub x}N{sub y}) was synthesized by reactive magnetron sputtering in a mixed N{sub 2}/O{sub 2}/Ar gas at ambient temperature. TiO{sub x}N{sub y} thin films with various amounts of nitrogen contents were deposited by varying the N{sub 2}/O{sub 2} ratios in the background gas. The synthesized TiO{sub x}N{sub y} films with different compositions (TiO{sub 1.837}N{sub 0.060,} TiO{sub 1.890}N{sub 0.068,} TiO{sub 1.865}N{sub 0.073}, and TiO{sub 1.882}N{sub 0.163}) all displayed anatase phase, except TiO{sub 1.882}N{sub 0.163}. The impedances and grain sizes showed obvious variations with the nitrogen contents. A wide potential window from 3.0 V to 0.05 V, high-rate charge–discharge testing, and long cycle testing were applied to investigate the performances of synthesized TiO{sub x}N{sub y} and pure TiO{sub 2} as anodes for lithium-ion batteries. These TiO{sub x}N{sub y} anodes can be cycled under high rates of 125 μA/cm{sup 2} (10 °C) because of the lower charge–transfer resistance compared with the TiO{sub 2} anode. At 10 °C the discharge capacity of the optimal TiO{sub x}N{sub y} composition is 1.5 times higher than that of pure TiO{sub 2}. An unexpectedly large reversible capacity of ~ 300 μAh/cm{sup 2} μm (~ 800 mAh/g) between 1.0 V and 0.05 V was recorded for the TiO{sub x}N{sub y} anodes. The TiO{sub x}N{sub y} anode was cycled (3.0 V to 0.05 V) at 10 °C over 300 times without capacity fading while delivering a capacity of ~ 150 μAh/cm{sup 2} μm (~ 400 mAh/g). - Highlights: • Titanium oxynitride (TiO{sub x}N{sub y}) thin films as anode materials were studied. • TiO{sub x}N{sub y} thin films with various amounts of nitrogen contents were studied{sub .} • High rate capability of TiO{sub x}N{sub y} was studied.

Achieving high fusion reactivity in high poloidal beta discharges in TFTR

International Nuclear Information System (INIS)

Manuel, M.E.; Navratil, G.A.; Sabbagh, S.A.; Batha, S.; Bell, M.G.; Bell, R.; Budny, R.V.; Bush, C.E.; Cavallo, A.; Chance, M.S.; Cheng, C.Z.; Efthimion, P.C.; Fredrickson, E.D.; Fu, G.Y.; Hawryluk, R.J.; Janos, A.C.; Jassby, D.L.; Levinton, F.; Mikkelsen, D.R.; Manickam, J.; McCune, D.C.; McGuire, K.M.; Medley, S.S.; Mueller, D.; Nagayama, Y.; Owens, D.K.; Park, H.K.; Ramsey, A.T.; Stratton, B.C.; Synakowski, E.J.; Taylor, G.; Wieland, R.M.; Yamada, M.; Zarnstorff, M.C.: Zweben, S.; Kesner, J.; Marmar, E.; Snipes, J.; Terry, J.

1993-04-01

High poloidal beta discharges have been produced in TFTR that achieved high fusion reactivities at low plasma currents. By rapidly decreasing the plasma current just prior to high-power neutral beam injection, relatively peaked current profiles were created having high l i > 2, high Troyon-normalized beta, βN > 3, and high poloidal beta. β p ≥ 0.7 R/a. The global energy confinement time after the current ramp was comparable to supershots, and the combination of improved MHD stability and good confinement produced a new high εβ p high Q DD operating mode for TFTR. Without steady-state current profile control, as the pulse lengths of high βp discharges were extended, l i decreased, and the improved stability produced immediately after by the current ramp deteriorated. In four second, high εβ p discharges, the current profile broadened under the influence of bootstrap and beam-drive currents. When the calculated voltage throughout the plasma nearly vanished, MHD instabilities were observed with β N as low as 1.4. Ideal MHD stability calculations showed this lower beta limit to be consistent with theoretical expectations

Faraday space in a high-frequency γ discharge and the influence of pressure on the normal current density effect of an α discharge and the nature of the α-γ transition

International Nuclear Information System (INIS)

Raizer, Yu.P.; Shneider, M.N.

1992-01-01

The essential differences between high-frequency capacative discharges at intermediate and low pressures are considered. A theory is developed for the negative emission region and the Faraday dark space in a γ discharge. It is based on the kinetic equation for electrons in the highly nonuniform field of an electrode sheath, which is solved in the forward-backward approximation. If a uniform positive column is formed in the middle of the gap of a γ discharge of average pressure which is not too short, then at low pressures the hf plasma acts as the equivalent of the negative emission or Faraday space of a glow discharge with a typical weak field and low electron temperature. A region of reversed average field also appears, which is characteristic of a glow discharge. The question of the normal current density effect in an α discharge is discussed. This effect is observed at average pressures. At low pressures the effect disappears, and even weak current covers the entire electrode; the pressures at which this occurs and the reasons for it are demonstrated. The nature of the α-γ transition, which takes place discontinuously at average pressures but continuously at lower pressures, is discussed. The reason for this behavior is discussed and the pressure at which the discontinuous mechanism changes into continuous is estimated

Stress Dispersed Cu Metal Anode by Laser Multiscale Patterning for Lithium-Ion Batteries with High Capacity

Directory of Open Access Journals (Sweden)

Jin-Young So

2018-06-01

Full Text Available Electric power production continues to increase as the industry advances, and the demand for high-capacity batteries for efficient operation of the electric power produced is higher than ever before. Si has been attracting a great deal of attention recently as an anode electrode material because of its high theoretical capacity. However, it suffers from significant capacity-loss, resulting from the volume-expansion of Si during charge and discharge cycles. Inspired by the multiscale structures commonly found in nature, we attempt to solve this problem by patterning the surface of the Cu current-collector. To this end, we develop a direct, one-step method using laser patterning to manufacture a multiscale structure on the surface of the current-collector. The inherent exfoliation characteristic of the Cu current-collector allows the spontaneous formation of the multiscale structure while being irradiated with a laser. A micro/nano structure, with a different surface area, is fabricated by varying the laser output at three levels, and the batteries prepared with the fabricated Cu current-collector are tested to evaluate their charge-discharge characteristics and electrochemical impedance. The results show that the multiscale structure reduces mechanical stress. The initial capacity of the Cu current-collector is proportional to the laser output, and the initial capacity of the coin cell prepared with the Cu current-collector, fabricated at the highest laser output, is 396.7% higher than that of the coin cell prepared with a bare Cu current-collector. The impedance is inversely proportional to the laser output. The charge transfer resistance of the coin cell prepared with the Cu current-collector and irradiated with the highest laser output is 190.2% lower than that of the coin cell prepared with the bare Cu current-collector.

High Capacity Cathode and Carbon Nanotube-Supported Anode for Enhanced Energy Density Batteries

Science.gov (United States)

2017-09-07

110-118, 2014. [15] J. B. Fei, et al., “Controlled preparation of MnO2 hierarchical hollow nanostructures and their application in water treatment ...and fixed load step ( grey shading) cell voltage and electrode potentials plotted vs. cell capacity, (b) 5th cycle discharge and fixed load step ( grey ...42  Figure 26. (a) 5th cycle discharge and fixed load step ( grey

Patterns of changes in wheelchair exercise capacity after spinal cord injury.

Science.gov (United States)

van Koppenhagen, Casper F; de Groot, Sonja; Post, Marcel W; Hoekstra, Trynke; van Asbeck, Floris W; Bongers, Helma; Lindeman, Eline; van der Woude, Luc H

2013-07-01

(1) To identify different patterns of changes in wheelchair exercise capacity in the period between the start of active spinal cord injury (SCI) rehabilitation and 5 years after discharge; (2) to examine the pattern determinants of the change in wheelchair exercise capacity. Prospective cohort study. Measurements were recorded at the start of active inpatient rehabilitation, 3 months after the start, at discharge of inpatient rehabilitation, 1 year after discharge, and 5 years after discharge. Eight rehabilitation centers. Persons with SCI (N=130; age range, 18-65y), who were wheelchair-dependent, at least for long distances. Not applicable. Wheelchair exercise capacity: peak power output (W). We found 4 different patterns of the change of peak power output (mean ± SD): (1) a pattern with high and progressive scores (33% of total study group): high progressive scores (start of rehabilitation: 49±15W to 5 years after discharge: 77±17.2W); (2) a pattern of improvement during inpatient rehabilitation and deterioration after inpatient rehabilitation (12%): progressive scores during inpatient rehabilitation with deteriorating scores after discharge (start of rehabilitation: 29±8.7W, to discharge: 60±8.4W, to 5 years after discharge: 39±13.1W); (3) a pattern with low and only slightly progressive scores (52%): low progressive scores (start of rehabilitation: 20±10.1W to 5 years after discharge: 31±15.9W); and (4) a pattern with low scores during inpatient rehabilitation and a sharp rise after discharge (3%): low inpatient scores with strong progressive scores after discharge (start of rehabilitation: 29±15.5W to 5 years after discharge: 82±10.6W). A logistic regression of factors that may distinguish between patterns with high and progressive scores and patterns with low and only slightly progressive scores revealed that older age, being a woman, having a tetraplegic lesion, and low functional status were associated with patterns with low and only slightly

Numerical investigation of a non-aqueous lithium-oxygen battery based on lithium superoxide as the discharge product

International Nuclear Information System (INIS)

Tan, Peng; Ni, Meng; Shao, Zongping; Chen, Bin; Kong, Wei

2017-01-01

Highlights: •A macroscopic model for Li-O 2 batteries based on LiO 2 is developed. •The electrode and electrolyte properties on discharge behaviors are investigated. •A thin cathode with a large porosity is favorable for a high specific capacity. •A high catalytic activity can lead to a high discharge voltage. •The oxygen solubility has larger impacts on the discharge performance. -- Abstract: It is reported lithium superoxide as the discharge product can largely decrease the charge voltage and enable a high round-trip efficiency of lithium-oxygen (Li-O 2 ) batteries. Here, we conduct a numerical investigation of the discharge behaviors of such batteries with LiO 2 as the discharge product. A mathematical model considering the mass transport and electrochemical reaction processes is first developed, which gives good agreement of the simulated discharge voltage with the experimental data. Then, with this model, the effects of electrode and electrolyte properties on the discharge performance are detailedly investigated. It is found that a thin cathode with a large porosity is favorable for a high specific capacity, and a high catalytic activity can lead to a high discharge voltage. For the cathode with different geometrical properties, it is found that the oxygen solubility and diffusivity have similar impacts on discharge capacities, but the oxygen solubility has a larger impact on energy densities. Besides, the limitations and further developments of the present model are also discussed. The results obtained from this work may give useful guidance for the discharge performance improvements of non-aqueous Li-O 2 batteries, and provide implications for other energy storage systems with solid product formation such as Na-O 2 batteries and Li-S batteries.

Improving Understanding of Glacier Melt Contribution to High Asian River Discharge through Collaboration and Capacity Building with High Asian CHARIS Partner Institutions

Science.gov (United States)

Armstrong, Richard; Brodzik, Mary Jo; Armstrong, Betsy; Barrett, Andrew; Fetterer, Florence; Hill, Alice; Jodha Khalsa, Siri; Racoviteanu, Adina; Raup, Bruce; Rittger, Karl; Williams, Mark; Wilson, Alana; Ye, Qinghua

2017-04-01

The Contribution to High Asia Runoff from Ice & Snow (CHARIS) project uses remote sensing data combined with modeling from 2000 to the present to improve proportional estimates of melt from glaciers and seasonal snow surfaces. Based at the National Snow and Ice Data Center (NSIDC), University of Colorado, Boulder, USA, the CHARIS project objectives are twofold: 1) capacity-building efforts with CHARIS partners from eight High Asian countries to better forecast future availability and vulnerability of water resources in the region, and 2) improving our ability to systematically assess the role of glaciers and seasonal snow in the freshwater resources of High Asia. Capacity-building efforts include working with CHARIS partners from Bhutan, Nepal, India, Pakistan, Afghanistan, Kazakhstan, Kyrgyzstan and Tajikistan. Our capacity-building activities include training, data sharing, supporting fieldwork, graduate student education and infrastructure development. Because of the scarcity of in situ data in this High Asian region, we are using the wealth of available remote sensing data to characterize digital elevation, daily maps of fractional snow-cover, annual maps of glacier and permanent snow cover area and downscaled reanalysis temperature data in snow melt models to estimate the relative proportions of river runoff from glacierized and seasonally snow-covered surfaces. Current collaboration with Qinghua Ye, visiting scientist at NSIDC from the Institute of Tibetan Plateau Research, CAS, focuses on remote sensing methods to detect changes in the mountain cryosphere. Collaboration with our Asian partners supports the systematic analysis of the annual cycle of seasonal snow and glacier ice melt across the High Mountain Asia region. With our Asian partners, we have derived reciprocal benefits, learning from their specialized local knowledge and obtaining access to their in situ data. We expect that the improved understanding of runoff from snow and glacier surfaces will

Electron beam generation in high voltage glow discharges

International Nuclear Information System (INIS)

Rocca, J.J.; Szapiro, B.; Murray, C.

1989-01-01

The generation of intense CW and pulsed electron beams in glow discharges in reviewed. Glow discharge electron guns operate at a pressure of the order of 1 Torr and often have an advantage in applications that require a broad area electron beam in a gaseous atmosphere, such as laser excitation and some aspects of materials processing. Aspects of electron gun design are covered. Diagnostics of the high voltage glow discharges including the electric field distribution mapped by Doppler free laser spectroscopy, and plasma density and electron temperature measurements of the electron yield of different cathode materials under glow discharge conditions are presented

Case Study on Justification: High Intensity Discharge Lamps. Annex II

International Nuclear Information System (INIS)

2016-01-01

High intensity discharge lamps produce bright white light of a high intensity in an energy efficient manner. These lamps are typically used in large numbers in public and professional settings such as shops, warehouses, hotels and offices. They are also used in outdoor applications to illuminate streets, buildings, statues, flags and gardens and further as architectural lighting. They also have applications associated with film projection in cinemas, manufacture of semiconductors, fluorescence endoscopy and microscopy, schlieren photography, hologram projection, ultraviolet curing, sky beamers and car headlights. Some types of high intensity discharge lamp, as well as certain other consumer products for lighting, contain radioactive substances for functional reasons. The radionuclides that are typically incorporated into high intensity discharge lamps are 85 Kr and 232 Th. Given the wide range of uses, specific decisions on justification may be required for different applications. A small number of safety assessments for high intensity discharge lamps have been carried out and published. No published decisions at the national level specifically addressing the justification of the use of high intensity discharge lamps have been identified

Inverse spinel transition metal oxides for lithium-ion storage with different discharge/charge conversion mechanisms

International Nuclear Information System (INIS)

Wang, Jiawei; Ren, Yurong; Huang, Xiaobing; Ding, Jianning

2016-01-01

Highlights: • Inverse spinel structure relieves the irreversible phase transition of electrodes. • Anodes with the same structure show different discharge/charge conversion mechanisms. • High reversible capacity confirms the potential feasibility of composites. - Abstract: Inverse spinel transition metal oxides (Fe 3 O 4 , MnFe 2 O 4 , Fe 3 O 4 /reduced graphene oxide and MnFe 2 O 4 /reduced graphene oxide) are prepared by a facile ethylene-glycol-assisted hydrothermal method. The stability of inverse spinel structure and the high specific surface area of nanoscale provide transition metal oxides with high specific capacity. And the surface modification with reduced graphene oxide improves the poor conductivity of pristine transition metal oxides. Pristine Fe 3 O 4 and MnFe 2 O 4 deliver the high initial discharge capacity of 1137.1 and 1088.9 mAh g −1 , respectively. Fe 3 O 4 /reduced graphene oxide and MnFe 2 O 4 /reduced graphene oxide get the reversible capacity of 645.8 and 720 mAh g −1 , respectively, even after 55 cycles. The different discharge/charge conversion mechanisms make them different capacity stability. The great electrochemical performances of composites offer electrodes with suitable characteristics for high-performance energy storage application.

Attainable high capacity in Li-excess Li-Ni-Ru-O rock-salt cathode for lithium ion battery

Science.gov (United States)

Wang, Xingbo; Huang, Weifeng; Tao, Shi; Xie, Hui; Wu, Chuanqiang; Yu, Zhen; Su, Xiaozhi; Qi, Jiaxin; Rehman, Zia ur; Song, Li; Zhang, Guobin; Chu, Wangsheng; Wei, Shiqiang

2017-08-01

Peroxide structure O2n- has proven to appear after electrochemical process in many lithium-excess precious metal oxides, representing extra reversible capacity. We hereby report construction of a Li-excess rock-salt oxide Li1+xNi1/2-3x/2Ru1/2+x/2O2 electrode, with cost effective and eco-friendly 3d transition metal Ni partially substituting precious 4d transition metal Ru. It can be seen that O2n- is formed in pristine Li1.23Ni0.155Ru0.615O2, and stably exists in subsequent cycles, enabling discharge capacities to 295.3 and 198 mAh g-1 at the 1st/50th cycle, respectively. Combing ex-situ X-ray absorption near edge spectroscopy, X-ray photoelectron spectroscopy, X-ray diffraction, high resolution transmission electron microscopy and electrochemical characterization, we demonstrate that the excellent electrochemical performance comes from both percolation network with disordered structure and cation/anion redox couples occurring in charge-discharge process. Li-excess and substitution of common element have been demonstrated to be a breakthrough for designing novel high performance commercial cathodes in rechargeable lithium ion battery field.

Binders and Hosts for High-Capacity Lithium-ion Battery Anodes

Science.gov (United States)

Dufficy, Martin Kyle

Lithium-ion batteries (LIBs) are universal electrochemical energy storage devices that have revolutionized our mobile society. Nonetheless, societal and technological advances drive consumer demand for LIBs with enhanced electrochemical performance, such as higher charge capacity and longer life, compared to conventional LIBs. One method to enhance LIB performance is to replace graphite, the industry standard anode since commercialization of LIBs in 1991, with high-charge capacity materials. Implementing high-capacity anode materials such as tin, silicon, and manganese vanadates, to LIBs presents challenges; Li-insertion is destructive to anode framework, and increasing capacity increases structural strains that pulverize anode materials and results in a short-cycle life. This thesis reports on various methods to extended the cycle life of high-capacity materials. Most of the work is conducted on nano-sized anode materials to reduce Li and electron transport pathway length (facilitating charge-transfer) and reduce strains from volume expansions (preserving anode structure). The first method involves encapsulating tin particles into a graphene-containing carbon nanofiber (CNF) matrix. The composite-CNF matrix houses tin particles to assume strains from tin-volume expansions and produces favorable surface-electrolyte chemistries for stable charge-discharge cycling. Before tin addition, graphene-containing CNFs are produced and assessed as anode materials for LIBs. Graphene addition to CNFs improves electronic and mechanical properties of CNFs. Furthermore, the 2-D nature of graphene provides Li-binding sites to enhance composite-CNF both first-cycle and high-rate capacities > 150% when compared to CNFs in the absence of graphene. With addition of Sn, we vary loadings and thermal production temperature to elucidate structure-composition relationships of tin and graphene-containing CNF electrodes that lead to increased capacity retention. Of note, electrodes containing

Environmentally benign and scalable synthesis of LiFePO4 nanoplates with high capacity and excellent rate cycling performance for lithium ion batteries

International Nuclear Information System (INIS)

Zhao, Chunsong; Wang, Lu-Ning; Chen, Jitao; Gao, Min

2017-01-01

Highlights: •LiFePO 4 precursors were successfully prepared in pure water phase under atmosphere. •LiFePO 4 nanostructures were also regenerated by recycling filtrate. •LiFePO 4 /C delivers high discharge capacity of 160 mAh g −1 at 0.2 C and high rate capacity of 107 mAh g −1 at 20C. •LiFePO 4 /C delivers a capacity retention rate closed to 97% after 240 cycles at 20C. -- Abstract: An economical and scalable synthesis route of LiFePO 4 nanoplate precursors is successfully prepared in pure water phase under atmosphere without employing environmentally toxic surfactants or high temperature and high pressure compared with traditional hydrothermal or solvothermal methods, which also involves recycling the filtrate to regenerate LiFePO 4 nanoplate precursors and collecting by-product Na 2 SO 4 . The LiFePO 4 precursors present a plate-like morphology with mean thickness and length of 50–100 and 100–300 nm, respectively. After carbon coating, the LiFePO 4 /C nanoparticles with particle size around 200 nm can be observed which exhibit a high discharge capacity of 160 mAh g −1 at 0.2 C and 107 mAh g −1 at 20 C. A high capacity retention closed to 91% can be reached after 500 cycles even at a high current rate of 20C with coulombic efficiency of 99.5%. This work suggests a simple, economic and environmentally benign method in preparation of LiFePO 4 /C cathode material for power batteries that would be feasible for large scale industrial production.

Li2C2, a High-Capacity Cathode Material for Lithium Ion Batteries.

Science.gov (United States)

Tian, Na; Gao, Yurui; Li, Yurong; Wang, Zhaoxiang; Song, Xiaoyan; Chen, Liquan

2016-01-11

As a typical alkaline earth metal carbide, lithium carbide (Li2C2) has the highest theoretical specific capacity (1400 mA h g(-1)) among all the reported lithium-containing cathode materials for lithium ion batteries. Herein, the feasibility of using Li2C2 as a cathode material was studied. The results show that at least half of the lithium can be extracted from Li2C2 and the reversible specific capacity reaches 700 mA h g(-1). The C≡C bond tends to rotate to form C4 (C≡C⋅⋅⋅C≡C) chains during lithium extraction, as indicated with the first-principles molecular dynamics (FPMD) simulation. The low electronic and ionic conductivity are believed to be responsible for the potential gap between charge and discharge, as is supported with density functional theory (DFT) calculations and Arrhenius fitting results. These findings illustrate the feasibility to use the alkali and alkaline earth metal carbides as high-capacity electrode materials for secondary batteries. © 2016 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

Structural originations of irreversible capacity loss from highly lithiated copper oxides

International Nuclear Information System (INIS)

Love, Corey T.; Dmowski, Wojtek; Johannes, Michelle D.; Swider-Lyons, Karen E.

2011-01-01

We use electrochemistry, high-energy X-ray diffraction (XRD) with pair-distribution function analysis (PDF), and density functional theory (DFT) to study the instabilities of Li 2 CuO 2 at varying state of charge. Rietveld refinement of XRD patterns revealed phase evolution from pure Li 2 CuO 2 body-centered orthorhombic (Immm) space group to multiphase compositions after cycling. The PDF showed CuO 4 square chains with varying packing during electrochemical cycling. Peaks in the G(r) at the Cu-O distance for delithiated, LiCuO 2 , showed CuO 4 square chains with reduced ionic radius for Cu in the 3+ state. At full depth of discharge to 1.5 V, CuO was observed in fractions greater than the initial impurity level which strongly affects the reversibility of the lithiation reactions contributing to capacity loss. DFT calculations showed electron removal from Cu and O during delithiation of Li 2 CuO 2 . - Graphical abstract: Structural transformation from Li 2 CuO 2 to delithiated LiCuO 2 . Highlights: → We use experimental techniques and theoretical calculation to study the instabilities of Li 2 CuO 2 . → After initial charge multiphase material persists through charge-discharge cycle. → Precipitation of CuO strongly affects electrode reversibility contributing to capacity loss. → Structural disorganization in Li 2 CuO 2 after cycling is the result of CuO 4 square chain packing. → DFT calculations show electron removal from both Cu and O during delithiation of Li 2 CuO 2 .

Modelling of pulsed RF corona discharges in high-pressure air

International Nuclear Information System (INIS)

Auzas, F; Makarov, M; Naidis, G V

2012-01-01

An approach to description of pulsed RF corona discharges in high-pressure air is developed, based on the model of a filamentary discharge sustained by an electromagnetic wave guided along the plasma filament. Results of numerical simulation of spatial-temporal discharge dynamics at the quasi-stationary stage are obtained for various values of gas pressure and wave frequency. Experimental data on the discharge length versus the power absorbed by the discharge are presented. Their comparison with simulation results is given. (paper)

High-frequency underwater plasma discharge application in antibacterial activity

International Nuclear Information System (INIS)

Ahmed, M. W.; Choi, S.; Lyakhov, K.; Shaislamov, U.; Mongre, R. K.; Jeong, D. K.; Suresh, R.; Lee, H. J.

2017-01-01

Plasma discharge is a novel disinfection and effectual inactivation approach to treat microorganisms in aqueous systems. Inactivation of Gram-negative Escherichia coli (E. coli) by generating high-frequency, high-voltage, oxygen (O_2) injected and hydrogen peroxide (H_2O_2) added discharge in water was achieved. The effect of H_2O_2 dose and oxygen injection rate on electrical characteristics of discharge and E. coli disinfection has been reported. Microbial log reduction dependent on H_2O_2 addition with O_2 injection was observed. The time variation of the inactivation efficiency quantified by the log reduction of the initial E. coli population on the basis of optical density measurement was reported. The analysis of emission spectrum recorded after discharge occurrence illustrated the formation of oxidant species (OH"•, H, and O). Interestingly, the results demonstrated that O_2 injected and H_2O_2 added, underwater plasma discharge had fabulous impact on the E. coli sterilization. The oxygen injection notably reduced the voltage needed for generating breakdown in flowing water and escalated the power of discharge pulses. No impact of hydrogen peroxide addition on breakdown voltage was observed. A significant role of oxidant species in bacterial inactivation also has been identified. Furthermore the E. coli survivability in plasma treated water with oxygen injection and hydrogen peroxide addition drastically reduced to zero. The time course study also showed that the retardant effect on E. coli colony multiplication in plasma treated water was favorable, observed after long time. High-frequency underwater plasma discharge based biological applications is technically relevant and would act as baseline data for the development of novel antibacterial processing strategies.

Long pulse KrCl laser with a high discharge quality

NARCIS (Netherlands)

Casper, L.C.; Bastiaens, Hubertus M.J.; Peters, P.J.M.; Boller, Klaus J.; Hofstra, R.M.

2007-01-01

The discharge quality and optimum pump parameters of a long-pulse high-pressure gas discharge excited KrCl laser are investigated. A three-electrode prepulse–mainpulse excitation circuit is employed as pump source. The discharge volume contains a gas mixture of HCl/Kr/Ne operated at a total pressure

Facile ultrasonic synthesis of CoO quantum dot/graphene nanosheet composites with high lithium storage capacity.

Science.gov (United States)

Peng, Chengxin; Chen, Bingdi; Qin, Yao; Yang, Shihe; Li, Chunzhong; Zuo, Yuanhui; Liu, Siyang; Yang, Jinhu

2012-02-28

In this paper, we report a facile ultrasonic method to synthesize well-dispersed CoO quantum dots (3-8 nm) on graphene nanosheets at room temperature by employing Co(4)(CO)(12) as cobalt precursor. The prepared CoO/graphene composites displayed high performance as an anode material for lithium-ion battery, such as high reversible lithium storage capacity (1592 mAh g(-1) after 50 cycles), high Coulombic efficiency (over 95%), excellent cycling stability, and high rate capability (1008 mAh g(-1) with a total retention of 77.6% after 50 cycles at a current density of 1000 mA g(-1), dramatically increased from the initial 50 mA g(-1)). The extraordinary performance arises from the structure advantages of the composites: the nanosized CoO quantum dots with high dispersity on conductive graphene substrates supply not only large quantity of accessible active sites for lithium-ion insertion but also good conductivity and short diffusion length for lithium ions, which are beneficial for high capacity and rate capability. Meanwhile, the isolated CoO quantum dots anchored tightly on the graphene nanosheets can effectively circumvent the volume expansion/contraction associated with lithium insertion/extraction during discharge/charge processes, which is good for high capacity as well as cycling stability. Moreover, regarding the anomalous behavior of capacity increase with cycles (activation effect) observed, we proposed a tentative hypothesis stressing the competition between the conductivity increase and the amorphorization of the composite electrodes during cycling in determining the trends of the capacity, in the hope to gain a fuller understanding of the inner working of the novel nanostructured electrode-based lithium-ion batteries.

Random oriented hexagonal nickel hydroxide nanoplates grown on graphene as binder free anode for lithium ion battery with high capacity

Science.gov (United States)

Du, Yingjie; Ma, Hu; Guo, Mingxuan; Gao, Tie; Li, Haibo

2018-05-01

In this work, two-step method has been employed to prepare random oriented hexagonal hydroxide nanoplates on graphene (Ni(OH)2@G) as binder free anode for lithium ion battery (LIB) with high capacity. The morphology, microstructure, crystal phase and elemental bonding have been characterized. When evaluated as anode for LIB, the Ni(OH)2@G exhibited high initial discharge capacity of 1318 mAh/g at the current density of 50 mA/g. After 80 cycles, the capacity was maintained at 834 mAh/g, implying 63.3% remaining. Even the charge rate was increased to 2000 mA/g, an impressive capacity of 141 mAh/g can be obtained, indicating good rate capability. The superior LIB behavior of Ni(OH)2@G is ascribed to the excellent combination between Ni(OH)2 nanoplates and graphene via both covalent chemical bonding and van der Waals interactions.

High-frequency underwater plasma discharge application in antibacterial activity

Energy Technology Data Exchange (ETDEWEB)

Ahmed, M. W.; Choi, S.; Lyakhov, K.; Shaislamov, U. [Jeju National University, Department of Nuclear and Energy Engineering (Korea, Republic of); Mongre, R. K.; Jeong, D. K. [Jeju National University, Faculty of Biotechnology (Korea, Republic of); Suresh, R.; Lee, H. J., E-mail: hjlee@jejunu.ac.kr [Jeju National University, Department of Nuclear and Energy Engineering (Korea, Republic of)

2017-03-15

Plasma discharge is a novel disinfection and effectual inactivation approach to treat microorganisms in aqueous systems. Inactivation of Gram-negative Escherichia coli (E. coli) by generating high-frequency, high-voltage, oxygen (O{sub 2}) injected and hydrogen peroxide (H{sub 2}O{sub 2}) added discharge in water was achieved. The effect of H{sub 2}O{sub 2} dose and oxygen injection rate on electrical characteristics of discharge and E. coli disinfection has been reported. Microbial log reduction dependent on H{sub 2}O{sub 2} addition with O{sub 2} injection was observed. The time variation of the inactivation efficiency quantified by the log reduction of the initial E. coli population on the basis of optical density measurement was reported. The analysis of emission spectrum recorded after discharge occurrence illustrated the formation of oxidant species (OH{sup •}, H, and O). Interestingly, the results demonstrated that O{sub 2} injected and H{sub 2}O{sub 2} added, underwater plasma discharge had fabulous impact on the E. coli sterilization. The oxygen injection notably reduced the voltage needed for generating breakdown in flowing water and escalated the power of discharge pulses. No impact of hydrogen peroxide addition on breakdown voltage was observed. A significant role of oxidant species in bacterial inactivation also has been identified. Furthermore the E. coli survivability in plasma treated water with oxygen injection and hydrogen peroxide addition drastically reduced to zero. The time course study also showed that the retardant effect on E. coli colony multiplication in plasma treated water was favorable, observed after long time. High-frequency underwater plasma discharge based biological applications is technically relevant and would act as baseline data for the development of novel antibacterial processing strategies.

CSTI High Capacity Power

International Nuclear Information System (INIS)

Winter, J.M.

1989-01-01

The SP-100 program was established in 1983 by DOD, DOE, and NASA as a joint program to develop the technology necessary for space nuclear power systems for military and civil application. During FY-86 and 87, the NASA SP-100 Advanced Technology Program was devised to maintain the momentum of promising technology advancement efforts started during Phase 1 of SP-100 and to strengthen, in key areas, the chances for successful development and growth capability of space nuclear reactor power systems for future space applications. In FY-88, the Advanced Technology Program was incorporated into NASA's new Civil Space Technology Initiative (CSTI). The CSTI Program was established to provide the foundation for technology development in automation and robotics, information, propulsion, and power. The CSTI High Capacity Power Program builds on the technology efforts of the SP-100 program, incorporates the previous NASA SP-100 Advanced Technology project, and provides a bridge to NASA Project Pathfinder. The elements of CSTI High Capacity Power development include Conversion Systems, Thermal Management, Power Management, System Diagnostics, and Environmental Interactions. Technology advancement in all areas, including materials, is required to assure the high reliability and 7 to 10 year lifetime demanded for future space nuclear power systems. The overall program will develop and demonstrate the technology base required to provide a wide range of modular power systems as well as allowing mission independence from solar and orbital attitude requirements. Several recent advancements in CSTI High Capacity power development will be discussed

Excited Atoms and Molecules in High Pressure Gas Discharges

International Nuclear Information System (INIS)

Vuskovic, L.; Popovic, S.

2003-01-01

Various types of high-pressure non-thermal discharges are increasingly drawing attention in view of many interesting applications. These, partially ionized media in non-equilibrium state, tend to generate complex effects that are difficult to interpret without a detailed knowledge of elementary processes involved. Electronically excited molecules and atoms may play an important role as intermediate states in a wide range of atomic and molecular processes, many of which are important in high-pressure discharges. They can serve also as reservoirs of energy or as sources of high energy electrons either through the energy pooling or through superelastic collisions. By presenting the analysis of current situation on the processes involving excited atoms and molecules of interest for high-pressure gas discharges, we will attempt to draw attention on the insufficiency of available data. In the same time we will show how to circumvent this situation and still be able to develop accurate models and interpretations of the observed phenomena

Modeling High Pressure Micro Hollow Cathode Discharges

National Research Council Canada - National Science Library

Boeuf, Jean-Pierre; Pitchford, Leanne

2004-01-01

This report results from a contract tasking CPAT as follows: The Grantee will perform theoretical modeling of point, surface, and volume high-pressure plasmas created using Micro Hollow Cathode Discharge sources...

Capacity Bounds and High-SNR Capacity of MIMO Intensity-Modulation Optical Channels

KAUST Repository

Chaaban, Anas

2018-02-19

The capacity of the intensity modulation direct detection multiple-input multiple-output channel is studied. Therein, the nonnegativity constraint of the transmit signal limits the applicability of classical schemes, including precoding. Thus, new ways are required for deriving capacity bounds for this channel. To this end, capacity lower bounds are developed in this paper by deriving the achievable rates of two precodingfree schemes: Channel inversion and QR decomposition. The achievable rate of a DC-offset SVD-based scheme is also derived as a benchmark. Then, capacity upper bounds are derived and compared against the lower bounds. As a result, the capacity at high signal-to-noise ratio (SNR) is characterized for the case where the number of transmit apertures is not larger than the number of receive apertures, and is shown to be achievable by the QR decomposition scheme. This is shown for a channel with average intensity or peak intensity constraints. Under both constraints, the high-SNR capacity is approximated within a small gap. Extensions to a channel with more transmit apertures than receive apertures are discussed, and capacity bounds for this case are derived.

Capacity Bounds and High-SNR Capacity of MIMO Intensity-Modulation Optical Channels

KAUST Repository

Chaaban, Anas; Rezki, Zouheir; Alouini, Mohamed-Slim

2018-01-01

The capacity of the intensity modulation direct detection multiple-input multiple-output channel is studied. Therein, the nonnegativity constraint of the transmit signal limits the applicability of classical schemes, including precoding. Thus, new ways are required for deriving capacity bounds for this channel. To this end, capacity lower bounds are developed in this paper by deriving the achievable rates of two precodingfree schemes: Channel inversion and QR decomposition. The achievable rate of a DC-offset SVD-based scheme is also derived as a benchmark. Then, capacity upper bounds are derived and compared against the lower bounds. As a result, the capacity at high signal-to-noise ratio (SNR) is characterized for the case where the number of transmit apertures is not larger than the number of receive apertures, and is shown to be achievable by the QR decomposition scheme. This is shown for a channel with average intensity or peak intensity constraints. Under both constraints, the high-SNR capacity is approximated within a small gap. Extensions to a channel with more transmit apertures than receive apertures are discussed, and capacity bounds for this case are derived.

Electrodeless discharge lamp is easily started, has high stability

Science.gov (United States)

Bell, W. E.; Bloom, A. L.

1966-01-01

Electrodeless discharge borosilicate glass lamp is used in various high-resolution optical systems. It is partially charged with krypton, contains small amounts of rubidium, and is enclosed in a hermetically sealed envelope that maintains the lamp at an optimum temperature during discharge. The lamp is quickly started by its excitation coil.

A three-dimensional interlayer composed of graphene and porous carbon for Long-life, High capacity Lithium-Iron Fluoride Battery

International Nuclear Information System (INIS)

Yang, Juan; Xu, Zhanglin; Sun, Hongxu; Zhou, Xiangyang

2016-01-01

We design a macroscopic structure composing of porous carbon and graphene sheets, which are coated onto a cellulose paper as an interlayer inserted between electrode and separator. The interlayer mainly acts as a divertor to accommodate the discharge products breaking away from the electrode by mechanical degradation or cathode dissolution during cycling and keeps the close contact with current collector. Iron fluoride is a new-type lithium storage material developed in recent years, which can act as a cathode material candidate for the rechargeable lithium ion battery due to their large theoretical capacity and relatively high operating potential. Specifically, FeF 3 ·0.33H 2 O, which possesses unusual tunnel structure, is attracting more and more attentions. However, FeF 3 ·0.33H 2 O suffers from the poor electronic conductivity and volume effect during cycling, causing the large capacity fading. In this study, we design a macroscopic structure composing of porous carbon and graphene sheets, which are coated onto a cellulose paper as an interlayer inserted between electrode and separator. The interlayer can not only enhance the electronic conductivity, but also absorb the FeF 3 ·0.33H 2 O nanoparticles breaking away from the Al foil due to the volume effect upon cycling. When the interlayer is applied in battery, discharge capacities of 600 and 460 mAh g −1 can be achieved at the rates of 100 and 600 mA g −1 after 60 cycles, respectively. Furthermore, the capacity of 435 mAh g −1 can be still retained at a high rate of 1000 mA g −1 after 250 cycles. The results demonstrate a potential feasibility for the porous carbon/graphene sheets to be applied to obtain a high-performance lithium-iron fluoride battery.

High output stomas: ensuring safe discharge from hospital to home.

Science.gov (United States)

Smith, Lisa

High-output stomas are a challenge for the patient and all health professionals involved. This article discusses safe discharge home for this patient group, encouraging collaborative working practices between acute care trust and the community services. The authors also discuss the management of a high-output stoma and preparation and education of the patient before discharge home.

Diagnostics and modeling of high pressure streamer induced discharges

International Nuclear Information System (INIS)

Marode, E.; Dessante, P.; Deschamps, N.; Deniset, C.

2001-01-01

A great variety of diagnostic has been applied to gain information on basic parameter governing high pressure nonthermal filamentary plasmas (and namely streamer induced filamentary discharges). Apart from electrical diagnostics, gas discharge, in contrast with solid state physics, can greatly benefit from all optical techniques owing to its ''transparent'' state. Emission and absorption spectroscopy, as well as LIF or CARS (talk are given during this meeting on these two techniques) are among such specific possibilities. The figures gained from these diagnostic measurements has generally no meaning by itself. They must be worked out, by means of calibrated former results, and/or by using them as input in high pressure plasma modeling. Mixing experimental and modeling approach is necessary for reaching relevant physical knowledge of the high pressure filamentary discharges processes. It is shown that diffusion, and thermal space and time distribution, must fully be taken into account

Evaluation of burnup credit for accommodating PWR spent nuclear fuel in high-capacity cask designs

International Nuclear Information System (INIS)

Wagner, John C.

2003-01-01

This paper presents an evaluation of the amount of burnup credit needed for high-density casks to transport the current U.S. inventory of commercial spent nuclear fuel (SNF) assemblies. A prototypic 32-assembly cask and the current regulatory guidance were used as bases for this evaluation. By comparing actual pressurized-water-reactor (PWR) discharge data (i.e., fuel burnup and initial enrichment specifications for fuel assemblies discharged from U.S. PWRs) with actinide-only-based loading curves, this evaluation finds that additional negative reactivity (through either increased credit for fuel burnup or cask design/utilization modifications) is necessary to accommodate the majority of SNF assemblies in high-capacity storage and transportation casks. The impact of varying selected calculational assumptions is also investigated, and considerable improvement in effectiveness is shown with the inclusion of the principal fission products (FPs) and minor actinides and the use of a bounding best-estimate approach for isotopic validation. Given sufficient data for validation, the most significant component that would improve accuracy, and subsequently enhance the utilization of burnup credit, is the inclusion of FPs. (author)

AIR ATMOSPHERIC-PRESSURE DISCHARGERS FOR OPERATION IN HIGH-FREQUENCY SWITCHING MODE.

Directory of Open Access Journals (Sweden)

L.S. Yevdoshenko

2013-10-01

Full Text Available Operation of two designs of compact multigap dischargers has been investigated in a high-frequency switching mode. It is experimentally revealed that the rational length of single discharge gaps in the designs is 0.3 mm, and the maximum switching frequency is 27000 discharges per second under long-term stable operation of the dischargers. It is shown that in pulsed corona discharge reactors, the pulse front sharpening results in increasing the operating electric field strength by 1.3 – 1.8 times.

Specific Localization of High-Voltage Discharge in Vicinity of Two Gases

Science.gov (United States)

Leonov, Sergey; Shurupov, Michail; Shneider, Michail; Napartovich, Anatoly; Kochetov, Igor

2011-10-01

A subject of paper is the appearance and dynamics of sub-microsecond long filamentary high-voltage discharge generated in atmosphere, and in non-homogeneous gaseous media. Typical discharge parameters are: maximal current 1-3kA, breakdown voltage >100 kV, duration 30-100 ns, gap distance 50-100mm. The effect of discharge specific localization within mixing layer of two gases is particularly discussed. The second discussed idea is the filamentary discharge movement within a region with concentration gradient of different components. For the short-pulse discharge the physical mechanism appears as the following. The first stage of the spark breakdown is the multiple streamers propagation from the high-voltage electrode toward the grounded one. In case of high-power electrical source those streamers occupy a huge volume of the gas, covering all possible paths for the further development. The next phase consists of the real selection of the discharge path among the multiple channels with non-zero conductivity. Experiments and calculations are presented for Air-CO2 and Air-C2H4 pairs. The effects found are supposed to be applied for lightning prediction/protection, and for high-speed mixing acceleration. The work was funded through EOARD-ISTC project #3793p. Some part of this work was supported by RFBR grant #10-08-00952.

High Capacity cylinder roller bearing; High Capacity Zylinderrollenlager. Ein vollrolliges Lager mit Kaefig

Energy Technology Data Exchange (ETDEWEB)

Reichert, J.; Baum, J. [SKF, Schweinfurt (Germany)

2007-07-15

The high capacity cylinder roller bearing is an example for continuous development of SKF products and does an effective contribution to increase operational safety and offers the possibility to reduce weight and compact design. (GL)

Investigation of Combined High-Frequency and Arc Discharges

International Nuclear Information System (INIS)

Taran, V.S.; Nezovibatko, Yu.N.; Marinin, V.G.; Shvets, O.M.; Ridozub, V.N.; Gasilin, V.V.

2001-01-01

In this paper we analyze experiment with arc and high-frequency (HF) plasma sources carried out in modified devise of the ''Bulat'' type. The HF-sources and combined discharges have attracted considerable attention for surface cleaning and coating. The utilization of such discharges allows decreasing droplet fraction formation and providing better adhesion and microhardness values. The existence of HF-field in plasma allows obtaining either conductive or dielectric coatings and they can be deposited on any substrates. (author)

High-Capacity Micrometer-Sized Li 2 S Particles as Cathode Materials for Advanced Rechargeable Lithium-Ion Batteries

KAUST Repository

Yang, Yuan

2012-09-19

Li 2S is a high-capacity cathode material for lithium metal-free rechargeable batteries. It has a theoretical capacity of 1166 mAh/g, which is nearly 1 order of magnitude higher than traditional metal oxides/phosphates cathodes. However, Li 2S is usually considered to be electrochemically inactive due to its high electronic resistivity and low lithium-ion diffusivity. In this paper, we discover that a large potential barrier (∼1 V) exists at the beginning of charging for Li 2S. By applying a higher voltage cutoff, this barrier can be overcome and Li 2S becomes active. Moreover, this barrier does not appear again in the following cycling. Subsequent cycling shows that the material behaves similar to common sulfur cathodes with high energy efficiency. The initial discharge capacity is greater than 800 mAh/g for even 10 μm Li 2S particles. Moreover, after 10 cycles, the capacity is stabilized around 500-550 mAh/g with a capacity decay rate of only ∼0.25% per cycle. The origin of the initial barrier is found to be the phase nucleation of polysulfides, but the amplitude of barrier is mainly due to two factors: (a) charge transfer directly between Li 2S and electrolyte without polysulfide and (b) lithium-ion diffusion in Li 2S. These results demonstrate a simple and scalable approach to utilizing Li 2S as the cathode material for rechargeable lithium-ion batteries with high specific energy. © 2012 American Chemical Society.

A high-voltage triggered pseudospark discharge experiment

International Nuclear Information System (INIS)

Ramaswamy, K.; Destler, W.W.; Rodgers, J.

1996-01-01

The design and execution of a pulsed high-voltage (350 endash 400 keV) triggered pseudospark discharge experiment is reported. Experimental studies were carried out to obtain an optimal design for stable and reliable pseudospark operation in a high-voltage regime (approx-gt 350 kV). Experiments were performed to determine the most suitable fill gas for electron-beam formation. The pseudospark discharge is initiated by a trigger mechanism involving a flashover between the trigger electrode and hollow cathode housing. Experimental results characterizing the electron-beam energy using the range-energy method are reported. Source size imaging was carried out using an x-ray pinhole camera and a novel technique using Mylar as a witness plate. It was experimentally determined that strong pinching occurred later in time and was associated with the lower-energy electrons. copyright 1996 American Institute of Physics

Computational Study of Anomalous Transport in High Beta DIII-D Discharges with ITBs

Science.gov (United States)

Pankin, Alexei; Garofalo, Andrea; Grierson, Brian; Kritz, Arnold; Rafiq, Tariq

2015-11-01

The advanced tokamak scenarios require a large bootstrap current fraction and high β. These large values are often outside the range that occurs in ``conventional'' tokamak discharges. The GLF23, TGLF, and MMM transport models have been previously validated for discharges with parameters associated with ``conventional'' tokamak discharges. It has been demonstrated that the TGLF model under-predicts anomalous transport in high β DIII-D discharges [A.M. Garofalo et al. 2015 TTF Workshop]. In this research, the validity of MMM7.1 model [T. Rafiq et al. Phys. Plasmas 20 032506 (2013)] is tested for high β DIII-D discharges with low and high torque. In addition, the sensitivity of the anomalous transport to β is examined. It is shown that the MMM7.1 model over-predicts the anomalous transport in the DIII-D discharge 154406. In particular, a significant level of anomalous transport is found just outside the internal transport barrier. Differences in the anomalous transport predicted using TGLF and MMM7.1 are reviewed. Mechanisms for quenching of anomalous transport in the ITB regions of high-beta discharges are investigated. This research is supported by US Department of Energy.

Lithium-ion battery performance improvement based on capacity recovery exploitation

International Nuclear Information System (INIS)

Eddahech, Akram; Briat, Olivier; Vinassa, Jean-Michel

2013-01-01

Highlights: •Experiments on combined power-cycling/calendar aging of high-power lithium battery. •Recovery phenomenon on battery capacity when we stop power-cycling. •Full discharge at rest time is a potential source for battery life prolongation. •Temperature impact on capacity recovery and battery aging. -- Abstract: In this work, the performance recovery phenomenon when aging high-power lithium-ion batteries used in HEV application is highlighted. This phenomenon consists in the increase on the battery capacity when power-cycling is stopped. The dependency of this phenomenon on the stop-SOC value is demonstrated. Keeping battery at a fully discharged state preserves a large amount of charge from the SEI-electrolyte interaction when they are in the positive electrode during rest time. Results from power cycling and combined aging, calendar/power-cycling, of a 12 A h-commercialized lithium-ion battery, at two temperatures (45 °C and 55 °C), are presented and obtained results are discussed

In Situ Synthesis of MnS Hollow Microspheres on Reduced Graphene Oxide Sheets as High-Capacity and Long-Life Anodes for Li- and Na-Ion Batteries.

Science.gov (United States)

Xu, Xijun; Ji, Shaomin; Gu, Mingzhe; Liu, Jun

2015-09-23

Uniform MnS hollow microspheres in situ crystallized on reduced graphene oxide (RGO) nanosheets via a facile hydrothermal method. The MnS/RGO composite material was used as the anode for Na-ion batteries for the first time and exhibited excellent cycling performance, superior specific capacity, and great cycle stability and rate capability for both Li- and Na-ion batteries. Compared with nonencapsulated pure MnS hollow microspheres, these MnS/RGO nanocomposites demonstrated excellent charge-discharge stability and long cycle life. Li-ion storage testing revealed that these MnS/RGO nanocomposites deliver high discharge-charge capacities of 640 mAh g(-1) at 1.0 A g(-1) after 400 cycles and 830 mAh g(-1) at 0.5 A g(-1) after 100 cycles. The MnS/RGO nanocomposites even retained a specific capacity of 308 mAh g(-1) at a current density of 0.1 A g(-1) after 125 cycles as the anode for Na-ion batteries. The outstanding electrochemical performance of the MnS/RGO composite attributed to the RGO nanosheets greatly improved the electronic conductivity and efficiently mitigated the stupendous volume expansion during the progress of charge and discharge.

High tension generator for corona barrier discharge

International Nuclear Information System (INIS)

Baltag, O.; Costandache, D.; Gheorghiu, M.; Paraschivescu, A.; Popa, G.

2001-01-01

Different types of high-voltage generators are in use for the study of low pressure (or atmospheric) discharges. Mostly used are the Tesla coils generators or the power generators working in linear or switching regime. The Tesla coils generators have the advantage of a simple bloc diagram. In exchange, they have a number of short-comings, such as: the difficulty in modifying the frequency of the high voltage pulses, generation of a high voltage and frequency pulse train, the amplitude is not constant.This paper presents a high-voltage generator meant to be used in the study of the dielectric barrier discharges (DBD). The bloc diagram is presented. Performances obtained are as follows: - Generated frequency: 10 Hz - 100 Hz, 100 Hz - 1 KHz, 1 KHz - 10 KHz; - High voltage pulses control: a single pulse from an internal or external generator; - Synchronization with the oscilloscope, variable delay: 5 μs - 0.1 s; - Output voltage: variable both smoothly and in steps: 1 kV -15 kV; - High voltage polarity: mono and bipolar; - Output power during the continuous duty: 300 VA (maximum 600 VA for a short time); - Pulse energy: 0.23 J; - Pulse duration: 4 μs - 50 μs

Analysis on the capacity degradation mechanism of a series lithium-ion power battery pack based on inconsistency of capacity

International Nuclear Information System (INIS)

Wang Zhen-Po; Liu Peng; Wang Li-Fang

2013-01-01

The lithium-ion battery has been widely used as an energy source. Charge rate, discharge rate, and operating temperature are very important factors for the capacity degradations of power batteries and battery packs. Firstly, in this paper we make use of an accelerated life test and a statistical analysis method to establish the capacity accelerated degradation model under three constant stress parameters according to the degradation data, which are charge rate, discharge rate, and operating temperature, and then we propose a capacity degradation model according to the current residual capacity of a Li-ion cell under dynamic stress parameters. Secondly, we analyze the charge and discharge process of a series power battery pack and interpret the correlation between the capacity degradations of the battery pack and its charge/discharge rate. According to this cycling condition, we establish a capacity degradation model of a series power battery pack under inconsistent capacity of cells, and analyze the degradation mechanism with capacity variance and operating temperature difference. The comparative analysis of test results shows that the inconsistent operating temperatures of cells in the series power battery pack are the main cause of its degradation; when the difference between inconsistent temperatures is narrowed by 5 °C, the cycle life can be improved by more than 50%. Therefore, it effectively improves the cycle life of the series battery pack to reasonably assemble the batteries according to their capacities and to narrow the differences in operating temperature among cells. (interdisciplinary physics and related areas of science and technology)

High-energy molecular lasers self-controlled volume-discharge lasers and applications

CERN Document Server

Apollonov, V V

2016-01-01

This book displays the physics and design of high-power molecular lasers. The lasers described are self-controlled volume-discharge lasers. The book explains self-sustained discharge lasers, self-initiated discharge lasers and technical approaches to laser design. Important topics discussed are laser efficiency, laser beam quality and electric field homogeneity. The book contains many new innovative applications.

Singlet oxygen generation in a high pressure non-self-sustained electric discharge

International Nuclear Information System (INIS)

Hicks, Adam; Norberg, Seth; Shawcross, Paul; Lempert, Walter R; Rich, J William; Adamovich, Igor V

2005-01-01

This paper presents results of singlet oxygen generation experiments in a high-pressure, non-self-sustained crossed discharge. The discharge consists of a high-voltage, short pulse duration, high repetition rate pulsed discharge, which produces ionization in the flow, and a low-voltage dc discharge which sustains current in a decaying plasma between the pulses. The sustainer voltage can be independently varied to maximize the energy input into electron impact excitation of singlet delta oxygen (SDO). The results demonstrate operation of a stable and diffuse crossed discharge in O 2 -He mixtures at static pressures of at least up to P 0 = 380 Torr and sustainer discharge powers of at least up to 1200 W, achieved at P 0 = 120 Torr. The reduced electric field in the positive column of the sustainer discharge varies from E/N = 0.3 x 10 -16 to 0.65 X 10 -16 V cm 2 , which is significantly lower than E/N in self-sustained discharges and close to the theoretically predicted optimum value for O 2 (a 1 Δ) excitation. Measurements of visible emission spectra O 2 (b 1 Σ → X 3 Σ) in the discharge afterglow show the O 2 (b 1 Σ) concentration to increase with the sustainer discharge power and to decrease as the O 2 fraction in the flow is increased. Rotational temperatures inferred from these spectra in 10% O 2 -90% He flows at P 0 = 120 Torr and mass flow rates of m-dot = 2.2 are 365-465 K. SDO yield at these conditions, 1.7% to 4.4%, was inferred from the integrated intensity of the (0, 0) band of the O 2 (a 1 Δ → X 3 Σ) infrared emission spectra calibrated using a blackbody source. The yield remains nearly constant in the discharge afterglow, up to at least 15 cm distance from the discharge. Kinetic modelling calculations using a quasi-one-dimensional nonequilibrium pulser-sustainer discharge model coupled with the Boltzmann equation for plasma electrons predict gas temperature rise in the discharge in satisfactory agreement with the experimental measurements

High-intensity discharge lamp and Duffing oscillator—Similarities and differences

Science.gov (United States)

Baumann, Bernd; Schwieger, Joerg; Stein, Ulrich; Hallerberg, Sarah; Wolff, Marcus

2017-12-01

The processes inside the arc tube of high-intensity discharge lamps are investigated using finite element simulations. The behavior of the gas mixture inside the arc tube is governed by differential equations describing mass, energy, and charge conservation, as well as the Helmholtz equation for the acoustic pressure and the Reynolds equations for the flow driven by buoyancy and Reynolds stresses. The model is highly nonlinear and requires a recursion procedure to account for the impact of acoustic streaming on the temperature and other fields. The investigations reveal the presence of a hysteresis and the corresponding jump phenomenon, quite similar to a Duffing oscillator. The similarities and, in particular, the differences of the nonlinear behavior of the high-intensity discharge lamp to that of a Duffing oscillator are discussed. For large amplitudes, the high-intensity discharge lamp exhibits a stiffening effect in contrast to the Duffing oscillator. It is speculated on how the stiffening might affect hysteresis suppression.

Capacity-coupled multidischarge for atmospheric plasma production

International Nuclear Information System (INIS)

Mase, Hiroshi; Fujiwara, Tamiya; Sato, Noriyoshi

2003-01-01

We propose a method of plasma production by capacity-coupled multidischarge (CCMD) at atmospheric pressure. The discharge gaps in the CCMD consist of a common electrode and a number of compact electrodes (CCE) which are directly coupled with small capacitors for quenching the discharge. A simple CCE structure is provided by a cylindrical capacitor, the inner conductor of which is used as a gap electrode. A short pulse discharge is observed to appear homogeneously at each CCE. A charge transfer for the single-pulsed discharge is 10-100 times as large as that of the conventional dielectric barrier discharge. A high efficiency of ozone production has been confirmed in the CCMD using O 2 gas. A device configuration of the CCMD is quite flexible with respect to its geometrical shape and size. The CCMD could be used to produce plasmas for various kinds of industrial applications at atmospheric pressure

Long pulse high performance discharges in the DIII-D tokamak

International Nuclear Information System (INIS)

Luce, T.C.; Wade, M.R.; Politzer, P.A.

2001-01-01

Significant progress in obtaining high performance discharges lasting many energy confinement times in the DIII-D tokamak has been realized in recent experimental campaigns. Normalized performance ∼10 has been sustained for more than 5τ E with q min >1.5. (The normalized performance is measured by the product β N H 89 , indicating the proximity to the conventional β limits and energy confinement quality, respectively.) These H mode discharges have an ELMing edge and β min >1. The global parameters were chosen to optimize the potential for fully non-inductive current sustainment at high performance, which is a key program goal for the DIII-D facility. Measurement of the current density and loop voltage profiles indicate that ∼75% of the current in the present discharges is sustained non-inductively. The remaining ohmic current is localized near the half-radius. The electron cyclotron heating system is being upgraded to replace this remaining current with ECCD. Density and β control, which are essential for operating advanced tokamak discharges, were demonstrated in ELMing H mode discharges with β N H 89 ∼ 7 for up to 6.3 s or ∼34τ E . These discharges appear to have stationary current profiles with q min ∼1.05, in agreement with the current profile relaxation time ∼1.8 s. (author)

Research of decreasing of the cesium radionuclides discharge in the course pouring of the liquid glass from furnace EhP-500/1

International Nuclear Information System (INIS)

Sadovskij, B.F.; Borisov, N.B.; Dzekun, E.G.; Skobtsov, A.S.

1996-01-01

Cesium radionuclides discharge from the furnace liquid-glass discharge unit are studied and estimates of cesium emission from the glass melt by the stream flow-out and filling the waste storage capacity are performed. The ways for decreasing cesium discharges are indicated and new additional aerosol protection system for high-active glass discharge, providing for high protection efficiency is proposed. 10 refs., 1 fig., 1 tab

Long-pulse high-performance discharges in the DIII-D tokamak

International Nuclear Information System (INIS)

Luce, T.C.; Wade, M.R.; Politzer, P.A.

2001-01-01

Significant progress in obtaining high performance discharges for many energy confinement times in the DIII-D tokamak has been realized since the previous IAEA meeting. In relation to previous discharges, normalized performance ∼10 has been sustained for >5τ E with q min >1.5. (The normalized performance is measured by the product β N H 89 indicating the proximity to the conventional β limits and energy confinement quality, respectively.) These H-mode discharges have an ELMing edge and β≤5%. The limit to increasing β is a resistive wall mode, rather than the tearing modes previously observed. Confinement remains good despite the increase in q. The global parameters were chosen to optimize the potential for fully non-inductive current sustainment at high performance, which is a key program goal for the DIII-D facility in the next two years. Measurement of the current density and loop voltage profiles indicate ∼75% of the current in the present discharges is sustained non-inductively. The remaining ohmic current is localized near the half radius. The electron cyclotron heating system is being upgraded to replace this remaining current with ECCD. Density and β control, which are essential for operating advanced tokamak discharges, were demonstrated in ELMing H-mode discharges with β N H 89 ∼7 for up to 6.3 s or ∼34 τ E . These discharges appear to be in resistive equilibrium with q min ∼1.05, in agreement with the current profile relaxation time of 1.8 s. (author)

LONG-PULSE, HIGH-PERFORMANCE DISCHARGES IN THE DIII-D TOKAMAK

International Nuclear Information System (INIS)

T.C. LUCE; M.R. WADE; P.A. POLITZER; S.L. ALLEN; M E. AUSTIN; D.R. BAKER; B.D. BRAY; D.P. BRENNAN; K.H. BURRELL; T.A. CASPER; M.S. CHU; J.D. De BOO; E.J. DOYLE; J.R. FERRON; A.M. GAROFALO; P.GOHIL; I.A. GORELOV; C.M. GREENFIELD; R.J. GROEBNER; W.W. HEIBRINK; C.-L. HSIEH; A.W. HYATT; R.JAYAKUMAR; J.E.KINSEY; R.J. LA HAYE; L.L. LAO; C.J. LASNIER; E.A. LAZARUS; A.W. LEONARD; Y.R. LIN-LIU; J. LOHR; M.A. MAKOWSKI; M. MURAKAMI; C.C. PETTY; R.I. PINSKER; R. PRATER; C.L. RETTIG; T.L. RHODES; B.W. RICE; E.J. STRAIT; T.S. TAYLOR; D.M. THOMAS; A.D. TURNBULL; J.G. WATKINS; W.P.WEST; K.-L. WONG

2000-01-01

Significant progress in obtaining high performance discharges for many energy confinement times in the DIII-D tokamak has been realized since the previous IAEA meeting. In relation to previous discharges, normalized performance ∼10 has been sustained for >5 τ E with q min >1.5. (The normalized performance is measured by the product β N H 89 indicating the proximity to the conventional β limits and energy confinement quality, respectively.) These H-mode discharges have an ELMing edge and β ∼(le) 5%. The limit to increasing β is a resistive wall mode, rather than the tearing modes previously observed. Confinement remains good despite the increase in q. The global parameters were chosen to optimize the potential for fully non-inductive current sustainment at high performance, which is a key program goal for the DIII-D facility in the next two years. Measurement of the current density and loop voltage profiles indicate ∼75% of the current in the present discharges is sustained non-inductively. The remaining ohmic current is localized near the half radius. The electron cyclotron heating system is being upgraded to replace this remaining current with ECCD. Density and β control, which are essential for operating advanced tokamak discharges, were demonstrated in ELMing H-mode discharges with β N H 89 ∼ 7 for up to 6.3 s or ∼ 34 τ E . These discharges appear to be in resistive equilibrium with q min ∼ 1.05, in agreement with the current profile relaxation time of 1.8 s

Discharge Coefficient of Rectangular Short-Crested Weir with Varying Slope Coefficients

Directory of Open Access Journals (Sweden)

Yuejun Chen

2018-02-01

Full Text Available Rectangular short-crested weirs are widely used for simple structure and high discharge capacity. As one of the most important and influential factors of discharge capacity, side slope can improve the hydraulic characteristics of weirs at special conditions. In order to systemically study the effects of upstream and downstream slope coefficients S1 and S2 on overflow discharge coefficient in a rectangular short-crested weir the Volume of Fluid (VOF method and the Renormalization Group (RNG κ-ε turbulence model are used. In this study, the slope coefficient ranges from V to 3H:1V and each model corresponds to five total energy heads of H0 ranging from 8.0 to 24.0 cm. Comparisons of discharge coefficients and free surface profiles between simulated and laboratory results display a good agreement. The simulated results show that the difference of discharge coefficients will decrease with upstream slopes and increase with downstream slopes as H0 increases. For a given H0, the discharge coefficient has a convex parabolic relation with S1 and a piecewise linearity relation with S2. The maximum discharge coefficient is always obtained at S2 = 0.8. There exists a difference between upstream and downstream slope coefficients in the influence range of free surface curvatures. Furthermore, a proposed discharge coefficient equation by nonlinear regression is a function of upstream and downstream slope coefficients.

Nonlinear behavior in high-intensity discharge lamps

NARCIS (Netherlands)

Baumann, Bernd; Schwieger, Joerg; Wolff, Marcus; Manders, Freddy; Suijker, Jos

2016-01-01

The light flicker problem of high intensity discharge lamps is studied numerically and experimentally. It is shown that in some respects the systems behave very similar to the forced Duffing oscillator with a softening spring. In particular, the jump phenomenon and hysteresis are observed in the

Rapid formation of electric field profiles in repetitively pulsed high-voltage high-pressure nanosecond discharges

International Nuclear Information System (INIS)

Ito, Tsuyohito; Kobayashi, Kazunobu; Hamaguchi, Satoshi; Czarnetzki, Uwe

2010-01-01

Rapid formation of electric field profiles has been observed directly for the first time in nanosecond narrow-gap parallel-plate discharges at near-atmospheric pressure. The plasmas examined here are of hydrogen, and the field measurement is based on coherent Raman scattering (CRS) by hydrogen molecules. Combined with the observation of spatio-temporal light emission profiles by a high speed camera, it has been found that the rapid formation of a high-voltage thin cathode sheath is accompanied by fast propagation of an ionization front from a region near the anode. Unlike well-known parallel-plate discharges at low pressure, the discharge formation process at high pressure is almost entirely driven by electron dynamics as ions and neutral species are nearly immobile during the rapid process. (fast track communication)

Physics of mercury-free high-pressure discharge lamps

International Nuclear Information System (INIS)

Born, M

2002-01-01

This paper gives a summary of recent results about the replacement of mercury in high-pressure discharge lamps by metallic zinc. Actually, this topic is of high relevance for the lighting industry due to the need of more environmentally friendly products. The work presented here is supported by the German government under contract no 13N8072 and 13N8264. Due to upcoming European legislations which are expected for the year 2003, the replacement of mercury in lighting products is a high priority task. For example, mercury-free headlight discharge lamps are requested by the automotive industry. Pure zinc/argon discharges as well as lamps including zinc or mercury and metal halide additives are investigated. Experimental data are compared with model calculations of the energy balance involving the transport of heat and radiation. Since the excitation energies of relevant zinc transitions are lower than for mercury, axis temperatures of pure zinc lamps are about 300 K below the value of mercury arcs. In addition, the thermal conductivity of zinc including the contribution of radiation diffusion is larger than compared to mercury. From lamp voltage measurements it is found that the cross section for elastical electron scattering by zinc atoms is about the same than for mercury. When adding metal halides to a pure zinc discharge with argon as a starting gas, i.e. NaI, TlI, DyI 3 , axis temperatures decrease to about 5100 K due to strong radiation cooling. In order to obtain sufficiently large lamp voltages, wall temperatures of more than 1300 K are adjusted by means of polycrystalline aluminaoxide (Al 2 O 3 ) as a wall material. Electric field strengths of 6.0 and 8.6 V mm -1 are measured for metal halide lamps containing zinc or mercury, respectively. The light technical data of the discharges are very close, since mercury and zinc do not contribute significantly to the radiation in the visible range. Efficacies of up to 93 and 100 lm W -1 are found in metal halide

Nonlinear behavior in high-intensity discharge lamps

Science.gov (United States)

Baumann, Bernd; Schwieger, Joerg; Wolff, Marcus; Manders, Freddy; Suijker, Jos

2016-06-01

The light flicker problem of high intensity discharge lamps is studied numerically and experimentally. It is shown that in some respects the systems behave very similar to the forced Duffing oscillator with a softening spring. In particular, the jump phenomenon and hysteresis are observed in the simulations and in the experiments.

High Power laser power conditioning system new discharge circuit research

CERN Document Server

Li Yi; Peng Han Sheng; Zhou Pei Zhang; Zheng Wan Guo; Guo Lang Fu; Chen Li Hua; Chen De Hui; Lai Gui You; Luan Yong Ping

2002-01-01

The new discharge circuit of power conditioning system for high power laser is studied. The theoretical model of the main discharge circuit is established. The pre-ionization circuit is studied in experiment. In addition, the explosion energy of the new large xenon lamp is successfully measured. The conclusion has been applied to 4 x 2 amplifier system

High-intensity xenon plasma discharge lamp for bulk-sensitive high-resolution photoemission spectroscopy.

Science.gov (United States)

Souma, S; Sato, T; Takahashi, T; Baltzer, P

2007-12-01

We have developed a highly brilliant xenon (Xe) discharge lamp operated by microwave-induced electron cyclotron resonance (ECR) for ultrahigh-resolution bulk-sensitive photoemission spectroscopy (PES). We observed at least eight strong radiation lines from neutral or singly ionized Xe atoms in the energy region of 8.4-10.7 eV. The photon flux of the strongest Xe I resonance line at 8.437 eV is comparable to that of the He Ialpha line (21.218 eV) from the He-ECR discharge lamp. Stable operation for more than 300 h is achieved by efficient air-cooling of a ceramic tube in the resonance cavity. The high bulk sensitivity and high-energy resolution of PES using the Xe lines are demonstrated for some typical materials.

High-order harmonic generation in a capillary discharge

Science.gov (United States)

Rocca, Jorge J.; Kapteyn, Henry C.; Mumane, Margaret M.; Gaudiosi, David; Grisham, Michael E.; Popmintchev, Tenio V.; Reagan, Brendan A.

2010-06-01

A pre-ionized medium created by a capillary discharge results in more efficient use of laser energy in high-order harmonic generation (HHG) from ions. It extends the cutoff photon energy, and reduces the distortion of the laser pulse as it propagates down the waveguide. The observed enhancements result from a combination of reduced ionization energy loss and reduced ionization-induced defocusing of the driving laser as well as waveguiding of the driving laser pulse. The discharge plasma also provides a means to spectrally tune the harmonics by tailoring the initial level of ionization of the medium.

High voltage and high specific capacity dual intercalating electrode Li-ion batteries

Science.gov (United States)

West, William C. (Inventor); Blanco, Mario (Inventor)

2010-01-01

The present invention provides high capacity and high voltage Li-ion batteries that have a carbonaceous cathode and a nonaqueous electrolyte solution comprising LiF salt and an anion receptor that binds the fluoride ion. The batteries can comprise dual intercalating electrode Li ion batteries. Methods of the present invention use a cathode and electrode pair, wherein each of the electrodes reversibly intercalate ions provided by a LiF salt to make a high voltage and high specific capacity dual intercalating electrode Li-ion battery. The present methods and systems provide high-capacity batteries particularly useful in powering devices where minimizing battery mass is important.

The electric strength of high-voltage transformers insulation at effect of partial dischargers

International Nuclear Information System (INIS)

Khoshravan, E.; Zeraatparvar, A.; Gashimov, A.M.; Mehdizadeh, R.N.

2001-01-01

Full text : In paper the change of electric strength of high-voltage transformers insulation at the effect of partial discharges with space charge accumulation was investigated. It is revealed that the effect of partial discharges of insulation materials results the reduction of their pulsing electric strength which can restore the own initial value at releasing of saved charge the volume of a material under condition of absence the ineversible structural changes in it. Researches of high-voltage transformers insulation's non-failure operation conditions show, that at increasing of insulation work time in a strong electrical field the reduction of average breakdown voltages with simultaneous increasing of spread in discharge voltage values takes place. It authentically testifies to reduction of short-time discharge voltage of insulation materials during their electrical aging. As the basic reason of insulation electrical aging the partial discharges occurring in gas cavities inside insulation were considered. It is known that the space charges will be formed in insulation elements of high-voltage devices which effects in dielectrical property of these elements including the electric strength and the space charge formation can occur also at partial discharges in an alternating voltage while the service of high-voltage transformers. In the given work the experiments in revealing separate influence partial discharges in pulsing electric strength of insulation materials at presence and at absence inside them the space charge were spent

High capacity getter pump for UHV operation

International Nuclear Information System (INIS)

Manini, P.; Marino, M.; Belloni, F.; Porro, M.

1993-01-01

UHV pumps based on non-evaporable getter coated strips find widespread use in particle accelerators, synchrotron radiation machines and nuclear fusion experimental devices. Depending on the geometric constraints, pressure operation conditions and the foreseen gas loads, optimized getter structures, such as modules and cartridges, can be designed and assembled into a high-efficiency pump. In the present paper, the design and performance of a newly conceived High Capacity Getter Pump (HCGP) based on sintered getter bodies, in the shape of blades instead of strips, is illustrated. The porosity and the specific surface area of the blades and their arrangement in the cartridge have been optimized to significantly increase sorption capacity at a given speed. These pumps are well suited for those applications where a very high gas load is expected during the machine operation. The sintered getter bodies increase surface area and capacity, requiring less frequent reactivation and facilitating greater overall life of the pump. A discussion of the experimental results in terms of sorption speed and capacity for various gases is presented

The Effect of High Frequency Pulse on the Discharge Probability in Micro EDM

Science.gov (United States)

Liu, Y.; Qu, Y.; Zhang, W.; Ma, F.; Sha, Z.; Wang, Y.; Rolfe, B.; Zhang, S.

2017-12-01

High frequency pulse improves the machining efficiency of micro electric discharge machining (micro EDM), while it also brings some changes in micro EDM process. This paper focuses on the influence of skin-effect under the high frequency pulse on energy distribution and transmission in micro EDM, based on which, the rules of discharge probability of electrode end face are also analysed. On the basis of the electrical discharge process under the condition of high frequency pulse in micro EDM, COMSOL Multiphysics software is used to establish energy transmission model in micro electrode. The discharge energy distribution and transmission within tool electrode under different pulse frequencies, electrical currents, and permeability situation are studied in order to get the distribution pattern of current density and electric field intensity in the electrode end face under the influence of electrical parameters change. The electric field intensity distribution is regarded as the influencing parameter of discharge probability on the electrode end. Finally, MATLAB is used to fit the curve and obtain the distribution of discharge probability of electrode end face.

High-Resolution Discharge Forecasting for Snowmelt and Rainfall Mixed Events

Directory of Open Access Journals (Sweden)

Tomasz Berezowski

2018-01-01

Full Text Available Discharge events induced by mixture of snowmelt and rainfall are strongly nonlinear due to consequences of rain-on-snow phenomena and snowmelt dependence on energy balance. However, they received relatively little attention, especially in high-resolution discharge forecasting. In this study, we use Random Forests models for 24 h discharge forecasting in 1 h resolution in a 105.9 km 2 urbanized catchment in NE Poland: Biala River. The forcing data are delivered by Weather Research and Forecasting (WRF model in 1 h temporal and 4 × 4 km spatial resolutions. The discharge forecasting models are set in two scenarios with snowmelt and rainfall and rainfall only predictors in order to highlight the effect of snowmelt on the results (both scenarios use also pre-forecast discharge based predictors. We show that inclusion of snowmelt decrease the forecast errors for longer forecasts’ lead times. Moreover, importance of discharge based predictors is higher in the rainfall only models then in the snowmelt and rainfall models. We conclude that the role of snowmelt for discharge forecasting in mixed snowmelt and rainfall environments is in accounting for nonlinear physical processes, such as initial wetting and rain on snow, which cannot be properly modelled by rainfall only.

Activation and discharge kinetics of metal hydride electrodes

Energy Technology Data Exchange (ETDEWEB)

Johnsen, Stein Egil

2003-07-01

this activation procedure. Studies of the activity of single metal hydride particles show that each particle has different properties after activation, by hot polarisation, in a porous electrode. The differences in activation among single particles may be due to differences in contact resistance between the individual metal hydride particle and the current collector in the porous electrode, which would result in a current distribution. Annealing of the gas atomised AB{sub 5} type alloy increases the discharge capacity but does not otherwise affect the activation. The corrosion and passivation of metal hydride electrodes of AB{sub 5} type alloys was studied. A high depth of discharge (DOD) decreases the discharge rate capability of the metal hydride electrodes and this is explained by passivation. A surface passivation may enhance particle cracking, which would make the electrode more susceptible to corrosion. The passivation of metal hydride electrodes increases for increasing cut-off-potential (COP) during discharging. This can be explained by an increasing corrosion of the particle surfaces. A corrosion phenomenon was measured at high DOD and correlated to the passivation of the metal hydride particle surface. Lowering the COP can reduce the negative effect of this phenomenon. The cycle life of the gas-atomised material is slightly improved by decreasing the COP but is independent of hot-polarisation activation treatment. Annealing this material significantly improves both discharge capacity and cycle life. A change of surface morphology due to the annealing has been identified and may contribute to the decreased electrode degradation. The formation of hydroxides on the particle surfaces is in general regarded to be negative for the electrode kinetics and is probably responsible for the long time degradation of metal hydride electrodes.

High speed photography for investigating kiloampere discharges in supersonic air flows

International Nuclear Information System (INIS)

Jones, G.R.; Strachan, D.

1975-01-01

Examples of the use of conventional high speed photographic techniques are given for obtaining information about the behaviour of high current arc discharges in different gas flow fields. The photographic records yield information about the extent of both the luminous arc core and the surrounding heated volume of gas. A knowledge of these parameters leads to a better understanding of arc discharges which occur in gas blast circuit breakers. (author)

Sounding experiments of high pressure gas discharge

International Nuclear Information System (INIS)

Biele, Joachim K.

1998-01-01

A high pressure discharge experiment (200 MPa, 5·10 21 molecules/cm 3 , 3000 K) has been set up to study electrically induced shock waves. The apparatus consists of the combustion chamber (4.2 cm 3 ) to produce high pressure gas by burning solid propellant grains to fill the electrical pump chamber (2.5 cm 3 ) containing an insulated coaxial electrode. Electrical pump energy up to 7.8 kJ at 10 kV, which is roughly three times of the gas energy in the pump chamber, was delivered by a capacitor bank. From the current-voltage relationship the discharge develops at rapidly decreasing voltage. Pressure at the combustion chamber indicating significant underpressure as well as overpressure peaks is followed by an increase of static pressure level. These data are not yet completely understood. However, Lorentz forces are believed to generate pinching with subsequent pinch heating, resulting in fast pressure variations to be propagated as rarefaction and shock waves, respectively. Utilizing pure axisymmetric electrode initiation rather than often used exploding wire technology in the pump chamber, repeatable experiments were achieved

The development and application of high-capacity thickening techniques

International Nuclear Information System (INIS)

Ji Zhenwan; Song Yuejie

1995-01-01

On the basis of sedimentation theory and comparison between the high-capacity and conventional thickening techniques, the authors analyse the ways to increase capacity and to improve technological parameters of thickeners, describes the construction features, development, application, automatic control and test installations of high-capacity thickeners at home and abroad

The free recovery of a short duration, high current discharge

International Nuclear Information System (INIS)

Piejak, R.

1984-01-01

The hold-off voltage between stainless steel electrodes has been measured as a function of time after an initial discharge. The hold-off voltage is the highest voltage that the gap will withstand without appreciable current flow. A high current (600-1200 amp), short duration (170 nsec) discharge was initiated between Rogowski profile electrodes. After a pre-determined time delay, a second pulse was applied to the discharge gap. The hold-off voltage as a function to time was determined up to the Paschen breakdown voltage. Background gas pressure between 30 and 100 torr and electrode separation of 2mm and 4mm were employed. UV preionization was introduced in some tests to create various discharge modes (glow/arc). The findings indicate significantly higher recovery rates in air than in N 2 , presumably due to attachment processes. In addition, the presence of pre-breakdown UV was found to influence the discharge mode, thus affecting the recovery rate of the gap. Hold-off voltage curves for the previously mentioned gases, background pressures and electrode spacing will be presented along with open shutter photographs of the various discharge modes

Time-Series Approaches for Forecasting the Number of Hospital Daily Discharged Inpatients.

Science.gov (United States)

Ting Zhu; Li Luo; Xinli Zhang; Yingkang Shi; Wenwu Shen

2017-03-01

For hospitals where decisions regarding acceptable rates of elective admissions are made in advance based on expected available bed capacity and emergency requests, accurate predictions of inpatient bed capacity are especially useful for capacity reservation purposes. As given, the remaining unoccupied beds at the end of each day, bed capacity of the next day can be obtained by examining the forecasts of the number of discharged patients during the next day. The features of fluctuations in daily discharges like trend, seasonal cycles, special-day effects, and autocorrelation complicate decision optimizing, while time-series models can capture these features well. This research compares three models: a model combining seasonal regression and ARIMA, a multiplicative seasonal ARIMA (MSARIMA) model, and a combinatorial model based on MSARIMA and weighted Markov Chain models in generating forecasts of daily discharges. The models are applied to three years of discharge data of an entire hospital. Several performance measures like the direction of the symmetry value, normalized mean squared error, and mean absolute percentage error are utilized to capture the under- and overprediction in model selection. The findings indicate that daily discharges can be forecast by using the proposed models. A number of important practical implications are discussed, such as the use of accurate forecasts in discharge planning, admission scheduling, and capacity reservation.

Electrical and optical characteristics of dielectric-barrier discharge driven by high voltage nanosecond generator

International Nuclear Information System (INIS)

Ahmadeev, V.V.; Kost'yuchenko, S.V.; Kudryavtsev, N.N.; Kurkin, G.A.; Vasilyak, L.M.

1998-01-01

Electrical and optical characteristics of the dielectric-barrier discharge in the pressure range of 10-400 Torr were investigated experimentally, particular attention being paid to the discharge homogeneity and to the energy dissipation in the discharge volume. The discharge was driven by a high-voltage pulse generator producing nanosecond high-voltage pulses with an amplitude of 20-30 kV. Air, nitrogen, and helium were used as working gases. The discharge was found to be homogeneous within a wide range of gas pressure. A power density of up to 250 mW/cm 3 has been achieved. (J.U.)

Comparative studies of high-frequency and direct current molecular gas discharges

International Nuclear Information System (INIS)

Goichman, V.H.; Goldfarb, V.M.; Tendler, M.B.

1975-01-01

Electron gas parameters, gas temperatures, ionization and thermal instability are found to be markedly different in direct current glow discharges from capactive electrodless high frequency discharge even when equal net power input is provided. It is reasonable to expect that the combined discharge containing both types of discharges mentioned above may be expected to improve significantly both the steady-state and transient characteristics of the plasma. The characteristics of different discharges in air, nitrogen air-CO 2 -He mixture have been compared. Because of the lack of the direct electrical methods for measurements of the hf plasma, exphasis in this investigation has been laid on both theoretical) based on the analytical expression for electron energy distribution function received previously and experimental spectroscopic evaluations of the plasma parameters. (Auth.)

High efficiency-large capacity circulating water pump for Hamaoka Nuclear Power Station unit No.3

International Nuclear Information System (INIS)

Ito, Akihiko; Sasamuro, Takemi; Takeda, Hirohisa.

1988-01-01

No.3 plant in the Hamaoka Nuclear Power Station, Chube Electric Power Co., Inc. is the latest plant of 1100 MW class BWR type, which began the commercial operation in August, 1987. The seawater intake and discharge system of this plant is composed of the channel exceeding 2 km in the total length from the intake tower to the discharge port. The circulating water pump installed in this system has the capacity of 1620 m 3 /min and the total head of 16.5 m, which are the largest in the world. It attained the efficiency as high as more than 90%. Three pumps supply seawater to three-body condensers. The design of the impeller and the casing for obtaining high efficiency, the structural design for facilitating maintenance, the manufacture of a model pump and the performance test using it and so on are reported. The most important item in the manufacture was the form of the onebody impeller weighing 4.5t. The confirmation of the performance of the actual machines was carried out as a part of the synthetic function confirmation test at the power station, and the flow rate was measured with Pitot tubes and ultrasonic flowmeters. (Kako, I.)

Pulsed high voltage electric discharge disinfection of microbially contaminated liquids.

Science.gov (United States)

Anpilov, A M; Barkhudarov, E M; Christofi, N; Kop'ev, V A; Kossyi, I A; Taktakishvili, M I; Zadiraka, Y

2002-01-01

To examine the use of a novel multielectrode slipping surface discharge (SSD) treatment system, capable of pulsed plasma discharge directly in water, in killing micro-organisms. Potable water containing Escherichia coli and somatic coliphages was treated with pulsed electric discharges generated by the SSD. The SSD system was highly efficient in the microbial disinfection of water with a low energy utilization (eta approximately 10-4 kW h l-1). The SSD treatment was effective in the destruction of E. coli and its coliphages through the generation of u.v. radiation, ozone and free radicals. The non-thermal treatment method can be used for the eradication of micro-organisms in a range of contaminated liquids, including milk, negating the use of pasteurization. The method utilizes multipoint electric discharges capable of treating large volumes of liquid under static and flowing regimes.

High energy XeBr electric discharge laser

Science.gov (United States)

Sze, Robert C.; Scott, Peter B.

1981-01-01

A high energy XeBr laser for producing coherent radiation at 282 nm. The XeBr laser utilizes an electric discharge as the excitation source to minimize formation of molecular ions thereby minimizing absorption of laser radiation by the active medium. Additionally, HBr is used as the halogen donor which undergoes harpooning reactions with Xe.sub.M * to form XeBr*.

Determination of line broadening constants in high pressure discharge lamps

International Nuclear Information System (INIS)

Weiss, M; Schubert, H; Meier, S; Born, M; Reiter, D; Stroesser, M

2005-01-01

A numerical model of the radiative transfer in high pressure metal halide discharge lamps is used to determine line broadening parameters for atomic scandium lines. The determined broadening constants are in qualitative agreement with theoretical estimates in many cases, but significant deviations exist. The data obtained from this paper can, therefore, be used to further improve modelling of radiative contributions to the energy balance in such types of discharge lamps

[Degradation of p-nitrophenol by high voltage pulsed discharge and ozone processes].

Science.gov (United States)

Pan, Li-li; Yan, Guo-qi; Zheng, Fei-yan; Liang, Guo-wei; Fu, Jian-jun

2005-11-01

The vigorous oxidation by ozone and the high energy by pulsed discharge are utilized to degrade the big hazardous molecules. And these big hazardous molecules become small and less hazardous by this process in order to improve the biodegradability. When pH value is 8-9, the concentration of p-nitrophenol solution can be degraded by 96.8% and the degradation efficiency of TOC is 38.6% by ozone and pulsed discharge treatment for 30 mins. The comparison results show that the combination treatment efficiency is higher than the separate, so the combination of ozone and pulsed discharge has high synergism. It is approved that the phenyl degradation efficiency is high and the degradation efficiency of linear molecules is relative low.

Treatment of Wastewater with High Conductivity by Pulsed Discharge Plasma

Science.gov (United States)

Wang, Zhaojun; Jiang, Song; Liu, Kefu

2014-07-01

A wastewater treatment system was established by means of pulsed dielectric barrier discharge (DBD). The main advantage of this system is that the wastewater is employed as one of the electrodes for the degradation of rhodamine B, which makes use of the high conductivity and lessenes its negative influence on the discharge process. At the same time, the reactive species like ozone and ultraviolet (UV) light generated by the DBD can be utilized for the treatment of wastewater. The effects of some factors like conductivity, peak pulse voltage, discharge frequency and pH values were investigated. The results show that the combination of these reactive species could enhance the degradation of the dye while the ozone played the most important role in the process. The degradation efficiency was enhanced with the increase of energy supplied. The reduction in the concentration of rhodamine B was much more effective with high solution conductivity; under the highest conductivity condition, the degradation rate could rise to 99%.

Treatment of Wastewater with High Conductivity by Pulsed Discharge Plasma

International Nuclear Information System (INIS)

Wang Zhaojun; Jiang Song; Liu Kefu

2014-01-01

A wastewater treatment system was established by means of pulsed dielectric barrier discharge (DBD). The main advantage of this system is that the wastewater is employed as one of the electrodes for the degradation of rhodamine B, which makes use of the high conductivity and lessenes its negative influence on the discharge process. At the same time, the reactive species like ozone and ultraviolet (UV) light generated by the DBD can be utilized for the treatment of wastewater. The effects of some factors like conductivity, peak pulse voltage, discharge frequency and pH values were investigated. The results show that the combination of these reactive species could enhance the degradation of the dye while the ozone played the most important role in the process. The degradation efficiency was enhanced with the increase of energy supplied. The reduction in the concentration of rhodamine B was much more effective with high solution conductivity; under the highest conductivity condition, the degradation rate could rise to 99%. (plasma technology)

High performance experiments in JT-60U reversed shear discharges

International Nuclear Information System (INIS)

Fujita, T.; Kamada, Y.; Ishida, S.

2001-01-01

The operation of JT-60U reversed shear discharges has been extended to a high plasma current, low-q regime keeping a large radius of the internal transport barrier (ITB) and the record value of equivalent fusion multiplication factor in JT-60U, Q DT eq =1.25, has been achieved at 2.6 MA. Operational schemes to reach the low-q regime with good reproducibility have been developed. The reduction of Z eff was obtained in the newly installed W-shaped pumped divertor. The beta limit in the low-q min regime, which limited the performance of L-mode edge discharges, has been improved in H-mode edge discharges with a broader pressure profile, which was obtained by power flow control with ITB degradation. Sustainment of ITB and improved confinement for 5.5 seconds has been demonstrated in an ELMy H reversed shear discharge. (author)

Clarification of Solvent Effects on Discharge Products in Li-O2 Batteries through a Titration Method.

Science.gov (United States)

Lee, Young Joo; Kwak, Won-Jin; Sun, Yang-Kook; Lee, Yun Jung

2018-01-10

As a substitute for the current lithium-ion batteries, rechargeable lithium oxygen batteries have attracted much attention because of their theoretically high energy density, but many challenges continue to exist. For the development of these batteries, understanding and controlling the main discharge product Li 2 O 2 (lithium peroxide) are of paramount importance. Here, we comparatively analyzed the amount of Li 2 O 2 in the cathodes discharged at various discharge capacities and current densities in dimethyl sulfoxide (DMSO) and tetraethylene glycol dimethyl ether (TEGDME) solvents. The precise assessment entailed revisiting and revising the UV-vis titration analysis. The amount of Li 2 O 2 electrochemically formed in DMSO was less than that formed in TEGDME at the same capacity and even at a much higher full discharge capacity in DMSO than in TEGDME. On the basis of our analytical experimental results, this unexpected result was ascribed to the presence of soluble LiO 2 -like intermediates that remained in the DMSO solvent and the chemical transformation of Li 2 O 2 to LiOH, both of which originated from the inherent properties of the DMSO solvent.

Fluorescent and high intensity discharge lamp use in chambers and greenhouses

Science.gov (United States)

Langhans, Robert W.

1994-01-01

Fluorescent and High Intensity Discharge lamps have opened up great opportunities for researchers to study plant growth under controlled environment conditions and for commercial growers to increase plant production during low/light periods. Specific technical qualities of fluorescent and HID lamps have been critically reviewed. I will direct my remarks to fluorescent and high intensity discharge (HID) lamps in growth chambers, growth rooms, and greenhouses. I will discuss the advantages and disadvantages of using each lamp in growth chambers, growth rooms and greenhouses.

Transport modelling and gyrokinetic analysis of advanced high performance discharges

International Nuclear Information System (INIS)

Kinsey, J.E.; Imbeaux, F.; Staebler, G.M.; Budny, R.; Bourdelle, C.; Fukuyama, A.; Garbet, X.; Tala, T.; Parail, V.

2005-01-01

Predictive transport modelling and gyrokinetic stability analyses of demonstration hybrid (HYBRID) and advanced tokamak (AT) discharges from the International Tokamak Physics Activity (ITPA) profile database are presented. Both regimes have exhibited enhanced core confinement (above the conventional ITER reference H-mode scenario) but differ in their current density profiles. Recent contributions to the ITPA database have facilitated an effort to study the underlying physics governing confinement in these advanced scenarios. In this paper, we assess the level of commonality of the turbulent transport physics and the relative roles of the transport suppression mechanisms (i.e. E x B shear and Shafranov shift (α) stabilization) using data for select HYBRID and AT discharges from the DIII-D, JET and AUG tokamaks. GLF23 transport modelling and gyrokinetic stability analysis indicate that E x B shear and Shafranov shift stabilization play essential roles in producing the improved core confinement in both HYBRID and AT discharges. Shafranov shift stabilization is found to be more important in AT discharges than in HYBRID discharges. We have also examined the competition between the stabilizing effects of E x B shear and Shafranov shift stabilization and the destabilizing effects of higher safety factors and parallel velocity shear. Linear and nonlinear gyrokinetic simulations of idealized low and high safety factor cases reveal some interesting consequences. A low safety factor (i.e. HYBRID relevant) is directly beneficial in reducing the transport, and E x B shear stabilization can dominate parallel velocity shear destabilization allowing the turbulence to be quenched. However, at low-q/high current, Shafranov shift stabilization plays less of a role. Higher safety factors (as found in AT discharges), on the other hand, have larger amounts of Shafranov shift stabilization, but parallel velocity shear destabilization can prevent E x B shear quenching of the turbulent

Transport modeling and gyrokinetic analysis of advanced high performance discharges

International Nuclear Information System (INIS)

Kinsey, J.; Imbeaux, F.; Bourdelle, C.; Garbet, X.; Staebler, G.; Budny, R.; Fukuyama, A.; Tala, T.; Parail, V.

2005-01-01

Predictive transport modeling and gyrokinetic stability analyses of demonstration hybrid (HYBRID) and Advanced Tokamak (AT) discharges from the International Tokamak Physics Activity (ITPA) profile database are presented. Both regimes have exhibited enhanced core confinement (above the conventional ITER reference H-mode scenario) but differ in their current density profiles. Recent contributions to the ITPA database have facilitated an effort to study the underlying physics governing confinement in these advanced scenarios. In this paper, we assess the level of commonality of the turbulent transport physics and the relative roles of the transport suppression mechanisms (i.e. ExB shear and Shafranov shift (α) stabilization) using data for select HYBRID and AT discharges from the DIII-D, JET, and AUG tokamaks. GLF23 transport modeling and gyrokinetic stability analysis indicates that ExB shear and Shafranov shift stabilization play essential roles in producing the improved core confinement in both HYBRID and AT discharges. Shafranov shift stabilization is found to be more important in AT discharges than in HYBRID discharges. We have also examined the competition between the stabilizing effects of ExB shear and Shafranov shift stabilization and the destabilizing effects of higher safety factors and parallel velocity shear. Linear and nonlinear gyrokinetic simulations of idealized low and high safety factor cases reveals some interesting consequences. A low safety factor (i.e. HYBRID relevant) is directly beneficial in reducing the transport, and ExB shear stabilization can win out over parallel velocity shear destabilization allowing the turbulence to be quenched. However, at low-q/high current, Shafranov shift stabilization plays less of a role. Higher safety factors (as found in AT discharges), on the other hand, have larger amounts of Shafranov shift stabilization, but parallel velocity shear destabilization can prevent ExB shear quenching of the turbulent

High capacity photonic integrated switching circuits

NARCIS (Netherlands)

Albores Mejia, A.

2011-01-01

As the demand for high-capacity data transfer keeps increasing in high performance computing and in a broader range of system area networking environments; reconfiguring the strained networks at ever faster speeds with larger volumes of traffic has become a huge challenge. Formidable bottlenecks

High visual working memory capacity in trait social anxiety.

Science.gov (United States)

Moriya, Jun; Sugiura, Yoshinori

2012-01-01

Working memory capacity is one of the most important cognitive functions influencing individual traits, such as attentional control, fluid intelligence, and also psychopathological traits. Previous research suggests that anxiety is associated with impaired cognitive function, and studies have shown low verbal working memory capacity in individuals with high trait anxiety. However, the relationship between trait anxiety and visual working memory capacity is still unclear. Considering that people allocate visual attention more widely to detect danger under threat, visual working memory capacity might be higher in anxious people. In the present study, we show that visual working memory capacity increases as trait social anxiety increases by using a change detection task. When the demand to inhibit distractors increased, however, high visual working memory capacity diminished in individuals with social anxiety, and instead, impaired filtering of distractors was predicted by trait social anxiety. State anxiety was not correlated with visual working memory capacity. These results indicate that socially anxious people could potentially hold a large amount of information in working memory. However, because of an impaired cognitive function, they could not inhibit goal-irrelevant distractors and their performance decreased under highly demanding conditions.

Understanding the role of lithium polysulfide solubility in limiting lithium-sulfur cell capacity

International Nuclear Information System (INIS)

Shen, Chao; Xie, Jianxin; Zhang, Mei; Andrei, Petru; Hendrickson, Mary; Plichta, Edward J.; Zheng, Jim P.

2017-01-01

Highlights: •At normal rate, LiPS soluble reaction pathway dominates the discharge process. •Reduction of sulfur to Li 2 S 8 is not inhibited by high Li 2 S 8 concentration. •Subsequent LiPS electrochemical reactions are restricted by LiPS solubility. •Specific energy of the Li-S cell was reevaluated considering LiPS solubility. -- Abstract: Although the cathode of lithium-sulfur (Li-S) batteries has a theoretical specific capacity of 1,672 mAh g −1 , its practical capacity is much smaller than this value and depends on the electrolyte/sulfur ratio. The operation of Li-S batteries under lean electrolyte conditions can be challenging, especially in the case when the solubility of lithium polysulfide (LiPS) sets an upper bound for polysulfide dissolution. In this work, specially designed cathode structures and electrolyte configurations were built in order to analyze the effects of LiPS solubility on cell capacity. Two reaction pathways involving the reduction of LiPS in liquid and solid phase are proposed and analyzed. We show that at discharge rates above 0.4 mA cm −2 the reaction in the liquid phase dominates the discharge process. Once the electrolyte becomes saturated, the solid phase LiPS cannot be further reduced and does not contribute to the capacity of the cells. This phenomenon prevents Li-S batteries from achieving their high theoretical specific capacity. Finally, the specific energy of the Li-S cell is reevaluated and discussed considering the limitation imposed by LiPS solubility.

The suitability of using dissolved gases to determine groundwater discharge to high gradient streams

Science.gov (United States)

Gleeson, Tom; Manning, Andrew H.; Popp, Andrea; Zane, Matthew; Clark, Jordan F.

2018-02-01

Determining groundwater discharge to streams using dissolved gases is known to be useful over a wide range of streamflow rates but the suitability of dissolved gas methods to determine discharge rates in high gradient mountain streams has not been sufficiently tested, even though headwater streams are critical as ecological habitats and water resources. The aim of this study is to test the suitability of using dissolved gases to determine groundwater discharge rates to high gradient streams by field experiments in a well-characterized, high gradient mountain stream and a literature review. At a reach scale (550 m) we combined stream and groundwater radon activity measurements with an in-stream SF6 tracer test. By means of numerical modeling we determined gas exchange velocities and derived very low groundwater discharge rates (∼15% of streamflow). These groundwater discharge rates are below the uncertainty range of physical streamflow measurements and consistent with temperature, specific conductance and streamflow measured at multiple locations along the reach. At a watershed-scale (4 km), we measured CFC-12 and δ18O concentrations and determined gas exchange velocities and groundwater discharge rates with the same numerical model. The groundwater discharge rates along the 4 km stream reach were highly variable, but were consistent with the values derived in the detailed study reach. Additionally, we synthesized literature values of gas exchange velocities for different stream gradients which show an empirical relationship that will be valuable in planning future dissolved gas studies on streams with various gradients. In sum, we show that multiple dissolved gas tracers can be used to determine groundwater discharge to high gradient mountain streams from reach to watershed scales.

The suitability of using dissolved gases to determine groundwater discharge to high gradient streams

Science.gov (United States)

Gleeson, Tom; Manning, Andrew H.; Popp, Andrea; Zane, Mathew; Clark, Jordan F.

2018-01-01

Determining groundwater discharge to streams using dissolved gases is known to be useful over a wide range of streamflow rates but the suitability of dissolved gas methods to determine discharge rates in high gradient mountain streams has not been sufficiently tested, even though headwater streams are critical as ecological habitats and water resources. The aim of this study is to test the suitability of using dissolved gases to determine groundwater discharge rates to high gradient streams by field experiments in a well-characterized, high gradient mountain stream and a literature review. At a reach scale (550 m) we combined stream and groundwater radon activity measurements with an in-stream SF6 tracer test. By means of numerical modeling we determined gas exchange velocities and derived very low groundwater discharge rates (∼15% of streamflow). These groundwater discharge rates are below the uncertainty range of physical streamflow measurements and consistent with temperature, specific conductance and streamflow measured at multiple locations along the reach. At a watershed-scale (4 km), we measured CFC-12 and δ18O concentrations and determined gas exchange velocities and groundwater discharge rates with the same numerical model. The groundwater discharge rates along the 4 km stream reach were highly variable, but were consistent with the values derived in the detailed study reach. Additionally, we synthesized literature values of gas exchange velocities for different stream gradients which show an empirical relationship that will be valuable in planning future dissolved gas studies on streams with various gradients. In sum, we show that multiple dissolved gas tracers can be used to determine groundwater discharge to high gradient mountain streams from reach to watershed scales.

High capacity anode materials for lithium ion batteries

Science.gov (United States)

Lopez, Herman A.; Anguchamy, Yogesh Kumar; Deng, Haixia; Han, Yongbon; Masarapu, Charan; Venkatachalam, Subramanian; Kumar, Suject

2015-11-19

High capacity silicon based anode active materials are described for lithium ion batteries. These materials are shown to be effective in combination with high capacity lithium rich cathode active materials. Supplemental lithium is shown to improve the cycling performance and reduce irreversible capacity loss for at least certain silicon based active materials. In particular silicon based active materials can be formed in composites with electrically conductive coatings, such as pyrolytic carbon coatings or metal coatings, and composites can also be formed with other electrically conductive carbon components, such as carbon nanofibers and carbon nanoparticles. Additional alloys with silicon are explored.

Optimum Discharge Burnup and Cycle Length for PWRs

International Nuclear Information System (INIS)

Secker, Jeffrey R.; Johansen, Baard J.; Stucker, David L.; Ozer, Odelli; Ivanov, Kostadin; Yilmaz, Serkan; Young, E.H.

2005-01-01

This paper discusses the results of a pressurized water reactor fuel management study determining the optimum discharge burnup and cycle length. A comprehensive study was performed considering 12-, 18-, and 24-month fuel cycles over a wide range of discharge burnups. A neutronic study was performed followed by an economic evaluation. The first phase of the study limited the fuel enrichments used in the study to 235 U consistent with constraints today. The second phase extended the range of discharge burnups for 18-month cycles by using fuel enriched in excess of 5 wt%. The neutronic study used state-of-the-art reactor physics methods to accurately determine enrichment requirements. Energy requirements were consistent with today's high capacity factors (>98%) and short (15-day) refueling outages. The economic evaluation method considers various component costs including uranium, conversion, enrichment, fabrication and spent-fuel storage costs as well as the effect of discounting of the revenue stream. The resulting fuel cycle costs as a function of cycle length and discharge burnup are presented and discussed. Fuel costs decline with increasing discharge burnup for all cycle lengths up to the maximum discharge burnup considered. The choice of optimum cycle length depends on assumptions for outage costs

Mechanics of high-capacity electrodes in lithium-ion batteries

International Nuclear Information System (INIS)

Zhu, Ting

2016-01-01

Rechargeable batteries, such as lithium-ion batteries, play an important role in the emerging sustainable energy landscape. Mechanical degradation and resulting capacity fade in high-capacity electrode materials critically hinder their use in high-performance lithium-ion batteries. This paper presents an overview of recent advances in understanding the electrochemically-induced mechanical behavior of the electrode materials in lithium-ion batteries. Particular emphasis is placed on stress generation and facture in high-capacity anode materials such as silicon. Finally, we identify several important unresolved issues for future research. (topical review)

The development of shock wave overpressure driven by channel expansion of high current impulse discharge arc

Science.gov (United States)

Xiong, Jia-ming; Li, Lee; Dai, Hong-yu; Wu, Hai-bo; Peng, Ming-yang; Lin, Fu-chang

2018-03-01

During the formation of a high current impulse discharge arc, objects near the discharge arc will be strongly impacted. In this paper, a high power, high current gas switch is used as the site of the impulse discharge arc. The explosion wave theory and the arc channel energy balance equation are introduced to analyze the development of the shock wave overpressure driven by the high current impulse discharge arc, and the demarcation point of the arc channel is given, from which the energy of the arc channel is no longer converted into shock waves. Through the analysis and calculation, it is found that the magnitude of the shock wave overpressure caused by impulse discharge arc expansion is closely related to the arc current rising rate. The arc shock wave overpressure will undergo a slow decay process and then decay rapidly. The study of this paper will perform the function of deepening the understanding of the physical nature of the impulse arc discharge, which can be used to explain the damage effect of the high current impulse discharge arc.

Towards Stable Lithium-Sulfur Batteries with a Low Self-Discharge Rate: Ion Diffusion Modulation and Anode Protection.

Science.gov (United States)

Xu, Wen-Tao; Peng, Hong-Jie; Huang, Jia-Qi; Zhao, Chen-Zi; Cheng, Xin-Bing; Zhang, Qiang

2015-09-07

The self-discharge of a lithium-sulfur cell decreases the shelf-life of the battery and is one of the bottlenecks that hinders its practical applications. New insights into both the internal chemical reactions in a lithium-sulfur system and effective routes to retard self-discharge for highly stable batteries are crucial for the design of lithium-sulfur cells. Herein, a lithium-sulfur cell with a carbon nanotube/sulfur cathode and lithium-metal anode in lithium bis(trifluoromethanesulfonyl)imide/1,3-dioxolane/dimethyl ether electrolyte was selected as the model system to investigate the self-discharge behavior. Both lithium anode passivation and polysulfide anion diffusion suppression strategies are applied to reduce self-discharge of the lithium-sulfur cell. When the lithium-metal anode is protected by a high density passivation layer induced by LiNO3 , a very low shuttle constant of 0.017 h(-1) is achieved. The diffusion of the polysulfides is retarded by an ion-selective separator, and the shuttle constants decreased. The cell with LiNO3 additive maintained a discharge capacity of 97 % (961 mAh g(-1) ) of the initial capacity after 120 days at open circuit, which was around three times higher than the routine cell (32 % of initial capacity, corresponding to 320 mAh g(-1) ). It is expected that lithium-sulfur batteries with ultralow self-discharge rates may be fabricated through a combination of anode passivation and polysulfide shuttle control, as well as optimization of the lithium-sulfur cell configuration. © 2015 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

Collisional and radiative processes in high-pressure discharge plasmas

Science.gov (United States)

Becker, Kurt H.; Kurunczi, Peter F.; Schoenbach, Karl H.

2002-05-01

Discharge plasmas at high pressures (up to and exceeding atmospheric pressure), where single collision conditions no longer prevail, provide a fertile environment for the experimental study of collisions and radiative processes dominated by (i) step-wise processes, i.e., the excitation of an already excited atomic/molecular state and by (ii) three-body collisions leading, for instance, to the formation of excimers. The dominance of collisional and radiative processes beyond binary collisions involving ground-state atoms and molecules in such environments allows for many interesting applications of high-pressure plasmas such as high power lasers, opening switches, novel plasma processing applications and sputtering, absorbers and reflectors for electromagnetic waves, remediation of pollutants and waste streams, and excimer lamps and other noncoherent vacuum-ultraviolet light sources. Here recent progress is summarized in the use of hollow cathode discharge devices with hole dimensions in the range 0.1-0.5 mm for the generation of vacuum-ultraviolet light.

Powerful highly efficient KrF lamps excited by surface and barrier discharges

International Nuclear Information System (INIS)

Borisov, V M; Vodchits, V A; El'tsov, A V; Khristoforov, O B

1998-01-01

An investigation was made of the characteristics of KrF lamps with different types of excitation by surface and barrier discharges in which the dielectric material was sapphire. The conditions were determined for the attainment of an extremely high yield of the KrF* fluorescence with the internal efficiency η in ∼30 % and 22% for pulsed surface and barrier discharges, respectively. A homogeneous surface discharge was maintained without gas circulation when the pulse repetition rate was 5 x 10 4 Hz. Quasicontinuous excitation of a surface discharge at near-atmospheric pressure made it possible to reach a KrF* fluorescence power density of about 80 W cm -3 , which was close to the limit set by the kinetics of the gaseous medium. Under prolonged excitation conditions the intensity of the UV output radiation was limited by the permissible heating of the gas to a temperature above which the operating life of the gaseous mixture containing fluorine fell steeply. This was the reason for the advantage of surface over barrier discharges: the former were characterised by a high thermal conductivity of a thin (∼0.2 mm) plasma layer on the surface of the cooled dielectric, which made it possible to construct powerful highly efficient KrF and ArF lamps emitting UV radiation of up to 1 W cm -2 intensity. (laser system components)

Diagnostics of Argon Injected Hydrogen Peroxide Added High Frequency Underwater Capillary Discharge

Directory of Open Access Journals (Sweden)

Muhammad Waqar Ahmed

2016-05-01

Full Text Available The effects of hydrogen peroxide addition and Argon injection on electrical and spectral characteristics of underwater capillary discharge were investigated. The flowing water discharge was created in a quartz tube (Φ = 4mm outer; Φ = 2mm inner; thickness 1mm by applying high frequency (25 kHz alternating current voltage (0-15kV across the tungsten electrodes (Φ=0.5mm, in pin-pin electrode configuration, separated by a gap distance of 10 mm. The results of no hydrogen peroxide addition and no Argon gas injection were compared with addition of hydrogen peroxide and Argon injection for different values. The emission spectrum was taken to present the increase in concentration of •OH radicals with and without hydrogen peroxide addition under different argon injection rates. The results demonstrated that addition of hydrogen peroxide do not remarkably affected the conductivity of water, but its addition increased the yield rate of •OH radicals generated by plasma discharge. The addition of Argon generated bubbles and gas channels reduced the high power consumption required for inducing flowing water long gap discharge. The results showed large concentration of •OH radicals due to hydrogen peroxide addition, less required input power for generating flowing water discharge by using high frequency input voltage and due to Argon injection.

Fabrication of high-aspect-ratio microgrooves using an electrochemical discharge micromilling process

International Nuclear Information System (INIS)

Han, Min-Seop; Chae, Ki Woon; Min, Byung-Kwon

2017-01-01

In this study, we created high-aspect-ratio microgrooves in hard, brittle materials using an electrochemical discharge machining (ECDM) process by introducing microtextured machining tool. To enhance the electrical discharge activity, the morphology of the tool side surface was treated via micro-electrical discharge machining to produce fine microprotrusive patterns. The resulting microtextured surface morphology enhanced the electric field and played a key role in improving the step milling depth in the ECDM process. Using the FEM analysis, the evaluation of the field enhancement factor is also addressed. Our experimental investigation revealed microgrooves having an aspect ratio of 1:4, with high geometric accuracy and crack-free surfaces, using one-step ECDM. (paper)

High energy KrCl electric discharge laser

Science.gov (United States)

Sze, Robert C.; Scott, Peter B.

1981-01-01

A high energy KrCl laser for producing coherent radiation at 222 nm. Output energies on the order of 100 mJ per pulse are produced utilizing a discharge excitation source to minimize formation of molecular ions, thereby minimizing absorption of laser radiation by the active medium. Additionally, HCl is used as a halogen donor which undergoes a harpooning reaction with metastable Kr.sub.M * to form KrCl.

High Input Voltage Hall Thruster Discharge Converter, Phase I

Data.gov (United States)

National Aeronautics and Space Administration — The overall scope of this Phase I/II effort is the development of a high efficiency 15kW (nominal) Hall thruster discharge converter. In Phase I, Busek Co. Inc. will...

The Role of Electronegative Impurities in Ozone Generation by High Pressure Discharges

International Nuclear Information System (INIS)

Skalny, J.

2000-01-01

The high pressure discharges (pulsed or D C corona, barrier, gliding and the others), have been studied both experimentally and theoretically as sources of low temperature plasma for pollution control technologies. The potential of electrical discharge methods has been demonstrated for the decomposition of many types of VOC. The air or oxygen are used as a feed gas in which pollutant is diluted. The ozone production in air or oxygen in such discharges is also discussed

High-efficiency dielectric barrier Xe discharge lamp: theoretical and experimental investigations

International Nuclear Information System (INIS)

Beleznai, Sz; Mihajlik, G; Agod, A; Maros, I; Juhasz, R; Nemeth, Zs; Jakab, L; Richter, P

2006-01-01

A dielectric barrier Xe discharge lamp producing vacuum-ultraviolet radiation with high efficiency was investigated theoretically and experimentally. The cylindrical glass body of the lamp is equipped with thin strips of metal electrodes applied to diametrically opposite sides of the outer surface. We performed a simulation of discharge plasma properties based on one-dimensional fluid dynamics and also assessed the lamp characteristics experimentally. Simulation and experimental results are analysed and compared in terms of voltage and current characteristics, power input and discharge efficiency. Using the proposed lamp geometry and fast rise-time short square pulses of the driving voltage, an intrinsic discharge efficiency around 56% was predicted by simulation, and more than 60 lm W -1 lamp efficacy (for radiation converted into visible green light by phosphor coating) was demonstrated experimentally

Investigation of high-current low pressure quasistationary volume discharge in cross-field ExH

International Nuclear Information System (INIS)

Bashutin, O.A.; Vovchenko, E.D.; Kirnev, G.S.

1995-01-01

Different types of high current discharge permitted to create large volume of high density homogeneous plasma are widely used in modern technique. Such discharges are applied as plasma emitters of charged particles and also in various technologies for sputtering, implantation and etching of materials. The results of a plasma electron density dynamics investigation of low pressure quasistationary volume discharge in cross-field E x H is described in this paper. The discharge was created in a quadrupole magnetic system with special form electrodes and has following characteristics current up to 1,8 kA, voltage on the interval 80-120 V, existence time up to 1,5 ms. The discharge conserves diffusive character of plasma and cathode layer on all current range. On a first research stage plasma parameters of discharge were determined by means of Langmuir probe, that could been used in central discharge region only, where magnetic field was equal to zero. An obtained plasma density was reached 1,5*10 15 cm -3 with electron temperature T e =10 eV. The research of discharge plasma in regions with magnetic field had required to use interferometric measurement technique

Spent nuclear fuel discharges from U.S. reactors 1994

International Nuclear Information System (INIS)

1996-02-01

Spent Nuclear Fuel Discharges from US Reactors 1994 provides current statistical data on fuel assemblies irradiated at commercial nuclear reactors operating in the US. This year's report provides data on the current inventories and storage capacities at these reactors. Detailed statistics on the data are presented in four chapters that highlight 1994 spent fuel discharges, storage capacities and inventories, canister and nonfuel component data, and assembly characteristics. Five appendices, a glossary, and bibliography are also included. 10 figs., 34 tabs

Research on High Current Pulse Discharges at IPP ASci CR

Czech Academy of Sciences Publication Activity Database

Koláček, Karel; Schmidt, Jiří; Prukner, Václav; Štraus, Jaroslav; Frolov, Oleksandr; Martínková, M.

2006-01-01

Roč. 56, suppl. B (2006), s. 259-266 ISSN 0011-4626. [Symposium on Plasma Physics and Technology/22nd./. Praha, 26.6.2006-29.6.2006] R&D Projects: GA ČR GA202/06/1324; GA MŠk 1P04LA235 Institutional research plan: CEZ:AV0Z20430508 Keywords : Pulsed high current capillary discharge * amplified spontaneous emission * soft X-ray laser Subject RIV: BL - Plasma and Gas Discharge Physics Impact factor: 0.568, year: 2006

Charge–discharge properties of tin dioxide for sodium-ion battery

Energy Technology Data Exchange (ETDEWEB)

Park, Jinsoo [Department of Materials and Energy Engineering, Kyungwoon University, 730 Gangdong-ro, Sandong-meon, Gumi-si, Gyeongbuk 730-739 (Korea, Republic of); Park, Jin-Woo; Han, Jeong-Hui [School of Materials Science and Engineering, RIGET, Gyeongsang National University, 900 Gajwa-dong, Jinju 660-701 (Korea, Republic of); Lee, Sang-Won [R and D 2 Team, COSMO AM and T CO., LTD., 315 Mokhaeng-dong, Chungju (Korea, Republic of); Lee, Ki-Young [Jeonyoung ECP, 637-1, Sunggok-dong, Danwon-gu, Ansan cilt, Kyunggi-do (Korea, Republic of); Ryu, Ho-Suk; Kim, Ki-Won [School of Materials Science and Engineering, RIGET, Gyeongsang National University, 900 Gajwa-dong, Jinju 660-701 (Korea, Republic of); Wang, Guoxiu [School of Chemistry and Forensic Science, University of Technology Sydney, Sydney, NSW 2007 (Australia); Ahn, Jou-Hyeon [Department of Chemical and Biological Engineering, Gyeongsang National University, 900 Gajwa-dong, Jinju 660-701 (Korea, Republic of); Ahn, Hyo-Jun, E-mail: ahj@gnu.ac.kr [School of Materials Science and Engineering, RIGET, Gyeongsang National University, 900 Gajwa-dong, Jinju 660-701 (Korea, Republic of)

2014-10-15

Highlights: • The electrochemical reaction of SnO2 as an anode for Na-ion batteries was studied. • The SnO2 electrode delivered the initial discharge capacity of 747 mAh/g. • Alarge irreversible capacity (597 mAh/g)was observedin the first cycle. • The in-plain crack in the electrode caused the incompletereduction of SnO{sub 2}. - Abstract: Tin dioxide was investigated as an anode material for sodium-ion batteries. The Na/SnO{sub 2} cell delivered a first discharge capacity of 747 mAh/g, but the first charge capacity was 150 mAh/g. The irreversible capacity in the first cycle was examined through characterization by X-ray diffraction and scanning electron microscopy. X-ray diffraction analysis revealed that the SnO{sub 2} active material was not reduced fully to metallic Sn. Furrows and wrinkles were formed on the electrode surface owing to the volumetric expansion upon first discharge, which led to a deterioration of the electrode structure and a loss of electrical contact between the active materials. The analysis is summarized in the schematic drawing.

High Input Voltage Discharge Supply for High Power Hall Thrusters Using Silicon Carbide Devices

Science.gov (United States)

Pinero, Luis R.; Scheidegger, Robert J.; Aulsio, Michael V.; Birchenough, Arthur G.

2014-01-01

A power processing unit for a 15 kW Hall thruster is under development at NASA Glenn Research Center. The unit produces up to 400 VDC with two parallel 7.5 kW discharge modules that operate from a 300 VDC nominal input voltage. Silicon carbide MOSFETs and diodes were used in this design because they were the best choice to handle the high voltage stress while delivering high efficiency and low specific mass. Efficiencies in excess of 97 percent were demonstrated during integration testing with the NASA-300M 20 kW Hall thruster. Electromagnet, cathode keeper, and heater supplies were also developed and will be integrated with the discharge supply into a vacuum-rated brassboard power processing unit with full flight functionality. This design could be evolved into a flight unit for future missions that requires high power electric propulsion.

Synthesis and characterization of advanced high capacity cathode active nanomaterials with three integrated spinel-layered phases for Li-ion batteries

Energy Technology Data Exchange (ETDEWEB)

Bulut, Emrah, E-mail: ebulut@sakarya.edu.tr [Department of Chemistry, Sakarya University, 54187 Serdivan, Sakarya (Turkey); Can, Mustafa, E-mail: mstfacan@gmail.com [Vocational School of Arifiye, Sakarya University, 54580 Arifiye, Sakarya (Turkey); Özacar, Mahmut, E-mail: nmozacart@hotmail.com [Department of Chemistry, Sakarya University, 54187 Serdivan, Sakarya (Turkey); Akbulut, Hatem, E-mail: akbulut@Sakarya.edu.tr [Department of Metallurgical and Materials Engineering, Sakarya University, 54187 Serdivan, Sakarya (Turkey)

2016-06-15

Mesoporous cathode active materials that included undoped and separated Cu{sup 2+} and Co{sup 3+} doped spinels were prepared. The “doped spinel-Layered-Li-rich spinel” composite nanoparticles within the three integrated phased (LiM{sub 0,02}Mn{sub 1,98}O{sub 4}–Li{sub 2}MnO{sub 3}–Li{sub 1,27}Mn{sub 1,73}O{sub 4}; where M is Cu{sup 2+} and Co{sup 3+}) were synthesized by a microwave assisted hydrothermal synthesis. These materials were investigated with X-Ray powder Diffraction spectroscopy (XRD), Scanning Electron Microscopy (SEM and FE-SEM), High Resolution Transmission Electron Microscopy (HR-TEM), galvanostatic cycling at 0.1C and 0.5C rates, Cyclic Voltammetry (CV), and Electrochemical Impedance Spectroscopy (EIS). The effects of the calcination temperature and the partial substitution of Mn{sup 3+} in the spinel by Cu{sup 2+} and Co{sup 3+}, and onto the spinel structure were investigated with XRD. The lattice parameters of the spinel structured compounds were calculated from the XRD data using the Williamson-Hall equation. However, the morphological changes, which depended on the calcination temperature, were examined by SEM, FE-SEM and HRTEM. Furthermore, the two other phases which were different from LiM{sub 0,02}Mn{sub 1,98}O{sub 4} had a great impact on the electrochemical performance over the potential range of the 3–5 V. At the 0.1C rate, the first discharge capacities of undoped and Cu{sup 2+}, Co{sup 3+} doped materials were 577, 285, 560 mAh/g respectively. After 50 cycles at 0.5C rate, we achieved 96.2%; 52.5%; 95.4% capacity retention for the undoped and Cu{sup 2+}, Co{sup 3+} doped materials respectively. - Highlights: • Mesoporous cathode active nanomaterials with three integrated phase were synthesized. • The materials were characterized structurally by XRD, FE-SEM, HR-TEM. • Integrated phases provide an additional 400 mAh/g discharge capacity at low rate. • Higher specific capacities than literature values were achieved at 0

Estimated radiological effects of the normal discharge of radioactivity from nuclear power plants in the Netherlands with a total capacity of 3500 MWe

International Nuclear Information System (INIS)

Lugt, G. van der; Wijker, H.; Kema, N.V.

1977-01-01

In the Netherlands discussions are going on about the installation of three nuclear power plants, leading with the two existing plants to a total capacity of 3500 MWe. To have an impression of the radiological impact of this program, calculations were carried out concerning the population doses due to the discharge of radioactivity from the plants during normal operation. The discharge via the ventilation stack gives doses due to noble gases, halogens and particulate material. The population dose due to the halogens in the grass-milk-man chain is estimated using the real distribution of grass-land around the reactor sites. It could be concluded that the population dose due to the contamination of crops and fruit is negligeable. A conservative estimation is made for the dose due to the discharge of tritium. The population dose due to the discharge in the cooling water is calculated using the following pathways: drinking water; consumption of fish; consumption of meat from animals fed with fish products. The individual doses caused by the normal discharge of a 1000 MWe plant appeared to be very low, mostly below 1 mrem/year. The population dose is in the order of some tens manrems. The total dose of the 5 nuclear power plants to the dutch population is not more than 70 manrem. Using a linear dose-effect relationship the health effects to the population are estimated and compared with the normal frequency

Evaluation of deterioration of insulators in high-voltage motors by partial discharge

International Nuclear Information System (INIS)

Mikami, Masao

2003-01-01

For the purpose of early detection of deterioration of insulators in high-voltage motors which are widely utilized in nuclear power stations, a new type on-line partial discharge monitor developed at INSS was applied to test the deterioration of about 150 sets of high-voltage motors running in nuclear power stations practically. From the results, it is shown that (1) tendency of the deterioration can be obtained by this method in general, (2) the magnitude of the on-line partial discharge hardly correlates with that of off-line measurement, but depends on temperature and other environmental conditions, and (3) by observing phase characteristics of partial discharge, it is possible to make a diagnosis of phase-to-phase tracking in end-winding coils of a stator. (author)

Novel high-frequency energy-efficient pulsed-dc generator for capacitively coupled plasma discharge

Science.gov (United States)

Mamun, Md Abdullah Al; Furuta, Hiroshi; Hatta, Akimitsu

2018-03-01

The circuit design, assembly, and operating tests of a high-frequency and high-voltage (HV) pulsed dc generator (PDG) for capacitively coupled plasma (CCP) discharge inside a vacuum chamber are reported. For capacitive loads, it is challenging to obtain sharp rectangular pulses with fast rising and falling edges, requiring intense current for quick charging and discharging. The requirement of intense current generally limits the pulse operation frequency. In this study, we present a new type of PDG consisting of a pair of half-resonant converters and a constant current-controller circuit connected with HV solid-state power switches that can deliver almost rectangular high voltage pulses with fast rising and falling edges for CCP discharge. A prototype of the PDG is assembled to modulate from a high-voltage direct current (HVdc) input into a pulsed HVdc output, while following an input pulse signal and a set current level. The pulse rise time and fall time are less than 500 ns and 800 ns, respectively, and the minimum pulse width is 1 µs. The maximum voltage for a negative pulse is 1000 V, and the maximum repetition frequency is 500 kHz. During the pulse on time, the plasma discharge current is controlled steadily at the set value. The half-resonant converters in the PDG perform recovery of the remaining energy from the capacitive load at every termination of pulse discharge. The PDG performed with a high energy efficiency of 85% from the HVdc input to the pulsed dc output at a repetition rate of 1 kHz and with stable plasma operation in various discharge conditions. The results suggest that the developed PDG can be considered to be more efficient for plasma processing by CCP.

Novel high-frequency energy-efficient pulsed-dc generator for capacitively coupled plasma discharge.

Science.gov (United States)

Mamun, Md Abdullah Al; Furuta, Hiroshi; Hatta, Akimitsu

2018-03-01

The circuit design, assembly, and operating tests of a high-frequency and high-voltage (HV) pulsed dc generator (PDG) for capacitively coupled plasma (CCP) discharge inside a vacuum chamber are reported. For capacitive loads, it is challenging to obtain sharp rectangular pulses with fast rising and falling edges, requiring intense current for quick charging and discharging. The requirement of intense current generally limits the pulse operation frequency. In this study, we present a new type of PDG consisting of a pair of half-resonant converters and a constant current-controller circuit connected with HV solid-state power switches that can deliver almost rectangular high voltage pulses with fast rising and falling edges for CCP discharge. A prototype of the PDG is assembled to modulate from a high-voltage direct current (HVdc) input into a pulsed HVdc output, while following an input pulse signal and a set current level. The pulse rise time and fall time are less than 500 ns and 800 ns, respectively, and the minimum pulse width is 1 µs. The maximum voltage for a negative pulse is 1000 V, and the maximum repetition frequency is 500 kHz. During the pulse on time, the plasma discharge current is controlled steadily at the set value. The half-resonant converters in the PDG perform recovery of the remaining energy from the capacitive load at every termination of pulse discharge. The PDG performed with a high energy efficiency of 85% from the HVdc input to the pulsed dc output at a repetition rate of 1 kHz and with stable plasma operation in various discharge conditions. The results suggest that the developed PDG can be considered to be more efficient for plasma processing by CCP.

MIMO Intensity-Modulation Channels: Capacity Bounds and High SNR Characterization

KAUST Repository

Chaaban, Anas

2016-10-01

The capacity of MIMO intensity modulation channels is studied. The nonnegativity of the transmit signal (intensity) poses a challenge on the precoding of the transmit signal, which limits the applicability of classical schemes in this type of channels. To resolve this issue, capacity lower bounds are developed by using precoding-free schemes. This is achieved by channel inversion or QR decomposition to convert the MIMO channel to a set of parallel channels. The achievable rate of a DC-offset SVD based scheme is also derived as a benchmark. Then, a capacity upper bound is derived and is shown to coincide with the achievable rate of the QR decomposition based scheme at high SNR, consequently characterizing the high-SNR capacity of the channel. The high-SNR gap between capacity and the achievable rates of the channel inversion and the DC-offset SVD based schemes is also characterized. Finally, the ergodic capacity of the channel is also briefly discussed.

Highly Conductive, Mechanically Robust, and Electrochemically Inactive TiC/C Nanofiber Scaffold for High-Performance Silicon Anode Batteries

KAUST Repository

Yao, Yan; Huo, Kaifu; Hu, Liangbing; Liu, Nian; Cha, Judy J.; McDowell, Matthew T.; Chu, Paul K.; Cui, Yi

2011-01-01

Silicon has a high specific capacity of 4200 mAh/g as lithium-ion battery anodes, but its rapid capacity fading due to >300% volume expansion and pulverization presents a significant challenge for practical applications. Here we report a core-shell TiC/C/Si inactive/active nanocomposite for Si anodes demonstrating high specific capacity and excellent electrochemical cycling. The amorphous silicon layer serves as the active material to store Li+, while the inactive TiC/C nanofibers act as a conductive and mechanically robust scaffold for electron transport during the Li-Si alloying process. The core-shell TiC/C/Si nanocomposite anode shows ∼3000 mAh g-1 discharge capacity and 92% capacity retention after 100 charge/discharge cycles. The excellent cycling stability and high rate performance could be attributed to the tapering of the nanofibers and the open structure that allows facile Li ion transport and the high conductivity and mechanical stability of the TiC/C scaffold. © 2011 American Chemical Society.

Highly Conductive, Mechanically Robust, and Electrochemically Inactive TiC/C Nanofiber Scaffold for High-Performance Silicon Anode Batteries

KAUST Repository

Yao, Yan

2011-10-25

Silicon has a high specific capacity of 4200 mAh/g as lithium-ion battery anodes, but its rapid capacity fading due to >300% volume expansion and pulverization presents a significant challenge for practical applications. Here we report a core-shell TiC/C/Si inactive/active nanocomposite for Si anodes demonstrating high specific capacity and excellent electrochemical cycling. The amorphous silicon layer serves as the active material to store Li+, while the inactive TiC/C nanofibers act as a conductive and mechanically robust scaffold for electron transport during the Li-Si alloying process. The core-shell TiC/C/Si nanocomposite anode shows ∼3000 mAh g-1 discharge capacity and 92% capacity retention after 100 charge/discharge cycles. The excellent cycling stability and high rate performance could be attributed to the tapering of the nanofibers and the open structure that allows facile Li ion transport and the high conductivity and mechanical stability of the TiC/C scaffold. © 2011 American Chemical Society.

High-rate capability of lithium-ion batteries after storing at elevated temperature

International Nuclear Information System (INIS)

Wu, Mao-Sung; Chiang, Pin-Chi Julia

2007-01-01

High-rate performances of a lithium-ion battery after storage at elevated temperature are investigated electrochemically by means of three-electrode system. The high-rate capability is decreased significantly after high-temperature storage. A 3 C discharge capacities after room-temperature storage and 60 o C storage are 650 and 20 mAh, respectively. Lithium-ion diffusion in lithium cobalt oxide cathode limits the battery's capacity and the results show that storage temperature changes this diffusion behavior. Transmission electron microscopy (TEM) images show that many defects are directly observed in the cathode after storage compared with the fresh cathode; the structural defects block the diffusion within the particles. Electrochemical impedance and polarization curve indicate that mass-transfer (diffusion) dominates the discharge capacity during high-rate discharge

Development of high power pumping system for capillary discharge EUV laser

International Nuclear Information System (INIS)

Sakai, Yusuke; Komatsu, Takanori; Watanabe, Masato; Okino, Akitoshi; Hotta, Eiki

2008-01-01

Development of high power pumping system for capillary discharge soft X-ray laser is reported. The pulsed power system consists of a 2.2 μF LC generator, a 2:54 step-up transformer and a 3 nF water capacitor. Taking advantage of high efficiency configuration, step-up ratio of water capacitor voltage to LC generator initial voltage is about 40 times. Consequently, obtained water capacitor voltage reaches about 450 kV when LC generator was charged to 12.5 kV. As a consequent, possibility of charging a water capacitor to 1 MV is demonstrated. With this extremely compact system, discharge current could be increased to nearly 100 kA through moderately long capillary, which leads to generation of high-density and high-temperature plasma column in order to realize EUV laser. (author)

Implications of electron attachment to highly-excited states in pulsed-power discharges

International Nuclear Information System (INIS)

Pinnaduwage, L.A.; Univ. of Tennessee, Knoxville, TN

1997-01-01

The author points out the possible implications of electron attachment to highly-excited states of molecules in two pulsed power technologies. One involves the pulsed H 2 discharges used for the generation of H ion beams for magnetic fusion energy and particle accelerators. The other is the power modulated plasma discharges used for material processing

Origin of Capacity Fading in Nano-Sized Co3O4Electrodes: Electrochemical Impedance Spectroscopy Study

Directory of Open Access Journals (Sweden)

Kang Jin-Gu

2008-01-01

Full Text Available Abstract Transition metal oxides have been suggested as innovative, high-energy electrode materials for lithium-ion batteries because their electrochemical conversion reactions can transfer two to six electrons. However, nano-sized transition metal oxides, especially Co3O4, exhibit drastic capacity decay during discharge/charge cycling, which hinders their practical use in lithium-ion batteries. Herein, we prepared nano-sized Co3O4with high crystallinity using a simple citrate-gel method and used electrochemical impedance spectroscopy method to examine the origin for the drastic capacity fading observed in the nano-sized Co3O4anode system. During cycling, AC impedance responses were collected at the first discharged state and at every subsequent tenth discharged state until the 100th cycle. By examining the separable relaxation time of each electrochemical reaction and the goodness-of-fit results, a direct relation between the charge transfer process and cycling performance was clearly observed.

Heart attack - discharge

Science.gov (United States)

... and lifestyle Cholesterol - drug treatment Controlling your high blood pressure Deep vein thrombosis - discharge Dietary fats explained Fast food tips Heart attack - discharge Heart attack - what to ask your doctor Heart bypass ... pacemaker - discharge High blood pressure - what to ask your doctor How to read ...

Construction and Capacity Analysis of High-Rank LoS MIMO Channels in High Speed Railway Scenarios

Directory of Open Access Journals (Sweden)

Jingya Yang

2012-01-01

Full Text Available The validity of the maximum capacity criterion applied to realize high-rank line-of-sight (LoS multiple-input multiple-output (MIMO channels is investigated for high speed railway scenarios. Performance is evaluated by ergodic capacity. Numerical results demonstrate that by simply adjusting antenna spacing according to the maximum capacity criterion, significant capacity gains are achievable. We find relatively low sensitivity of the system to displacements from the optimal point and angle in relatively short range. Thus, we present two proposals to reconfigure antenna arrays so as to maximize LoS MIMO capacity in the high speed railway scenarios

On-line Monitoring Device for High-voltage Switch Cabinet Partial Discharge Based on Pulse Current Method

Science.gov (United States)

Y Tao, S.; Zhang, X. Z.; Cai, H. W.; Li, P.; Feng, Y.; Zhang, T. C.; Li, J.; Wang, W. S.; Zhang, X. K.

2017-12-01

The pulse current method for partial discharge detection is generally applied in type testing and other off-line tests of electrical equipment at delivery. After intensive analysis of the present situation and existing problems of partial discharge detection in switch cabinets, this paper designed the circuit principle and signal extraction method for partial discharge on-line detection based on a high-voltage presence indicating systems (VPIS), established a high voltage switch cabinet partial discharge on-line detection circuit based on the pulse current method, developed background software integrated with real-time monitoring, judging and analyzing functions, carried out a real discharge simulation test on a real-type partial discharge defect simulation platform of a 10KV switch cabinet, and verified the sensitivity and validity of the high-voltage switch cabinet partial discharge on-line monitoring device based on the pulse current method. The study presented in this paper is of great significance for switch cabinet maintenance and theoretical study on pulse current method on-line detection, and has provided a good implementation method for partial discharge on-line monitoring devices for 10KV distribution network equipment.

Synthesis of structure of device for the technical diagnosticating of high-voltage discharge

OpenAIRE

Грабко, В. В.; Ковальчук, Венедикт Петрович

2010-01-01

The paper presents a device for control of the technical state of high-voltage discharge, which allows, not disconnecting him from power grid, to take into account a size and duration of interconnect current of discharge, and also size of remaining voltage.

Pushing the Limits: 3D Layer-by-Layer-Assembled Composites for Cathodes with 160 C Discharge Rates.

Science.gov (United States)

Mo, Runwei; Tung, Siu On; Lei, Zhengyu; Zhao, Guangyu; Sun, Kening; Kotov, Nicholas A

2015-05-26

Deficiencies of cathode materials severely limit cycling performance and discharge rates of Li batteries. The key problem is that cathode materials must combine multiple properties: high lithium ion intercalation capacity, electrical/ionic conductivity, porosity, and mechanical toughness. Some materials revealed promising characteristics in a subset of these properties, but attaining the entire set of often contrarian characteristics requires new methods of materials engineering. In this paper, we report high surface area 3D composite from reduced graphene oxide loaded with LiFePO4 (LFP) nanoparticles made by layer-by-layer assembly (LBL). High electrical conductivity of the LBL composite is combined with high ionic conductivity, toughness, and low impedance. As a result of such materials properties, reversible lithium storage capacity and Coulombic efficiency were as high as 148 mA h g(-1) and 99%, respectively, after 100 cycles at 1 C. Moreover, these composites enabled unusually high reversible charge-discharge rates up to 160 C with a storage capacity of 56 mA h g(-1), exceeding those of known LFP-based cathodes, some of them by several times while retaining high content of active cathode material. The study demonstrates that LBL-assembled composites enable resolution of difficult materials engineering tasks.

Characterization of a high-power/current pulsed magnetized arc discharge

NARCIS (Netherlands)

Zielinski, J. J.; van der Meiden, H. J.; Morgan, T. W.; D.C. Schram,; De Temmerman, G.

2012-01-01

A high-power pulsed magnetized arc discharge has been developed to allow the superimposition of a dc plasma and a high-power plasma impulse with a single plasma source. A capacitor bank (8400 mu F) is parallel-coupled to the current regulated power supply. The current is transiently increased from

Characterization of a high-power/current pulsed magnetized arc discharge

NARCIS (Netherlands)

Zielinski, J.J.; Meiden, van der H.J.; Morgan, T.W.; Schram, D.C.; De Temmerman, G.C.

2012-01-01

A high-power pulsed magnetized arc discharge has been developed to allow the superimposition of a dc plasma and a high-power plasma impulse with a single plasma source. A capacitor bank (8400 µF) is parallel-coupled to the current regulated power supply. The current is transiently increased from its

HIGH PERFORMANCE STATIONARY DISCHARGES IN THE DIII-D TOKAMAK

International Nuclear Information System (INIS)

Luce, T.C.; Wade, M.R.; Ferron, J.R.; Politzer, P.A.; Hyatt, A.W.; Sips, A.C.C.; Murakami, M.

2003-01-01

Recent experiments in the DIII-D tokamak [J.L. Luxon, Nucl. Fusion 42,614 (2002)] have demonstrated high β with good confinement quality under stationary conditions. Two classes of stationary discharges are observed--low q 95 discharges with sawteeth and higher q 95 without sawteeth. The discharges are deemed stationary when the plasma conditions are maintained for times greater than the current profile relaxation time. In both cases the normalized fusion performance (β N H 89P /q 95 2 ) reaches or exceeds the value of this parameter projected for Q fus = 10 in the International Thermonuclear Experimental Reactor (ITER) design [R. Aymar, et al., Plasma Phys. Control. Fusion 44, 519 (2002)]. The presence of sawteeth reduces the maximum achievable normalized β, while confinement quality (confinement time relative to scalings) is largely independent of q 95 . Even with the reduced β limit, the normalized fusion performance maximizes at the lowest q 95 . Projections to burning plasma conditions are discussed, including the methodology of the projection and the key physics issues which still require investigation

High rate capacity nanocomposite lanthanum oxide coated lithium zinc titanate anode for rechargeable lithium-ion battery

International Nuclear Information System (INIS)

Tang, Haoqing; Zan, Lingxing; Zhu, Jiangtao; Ma, Yiheng; Zhao, Naiqin; Tang, Zhiyuan

2016-01-01

Lithium zinc titanate (Li_2ZnTi_3O_8) is an important titanium material of promising candidates for anode materials with superior electrochemical performance and thus has attracted extensive attention. Herein, high capacity, stable Li_2ZnTi_3O_8/La_2O_3 nanocomposite for lithium-ion battery anode is prepared by a facile strategy. Compared to unmodified Li_2ZnTi_3O_8, the Li_2ZnTi_3O_8/La_2O_3 electrode display a high specific capacity of 188.6 mAh g"−"1 and remain as high as 147.7 mAh g"−"1 after 100 cycles at 2.0 A g"−"1. Moreover, a reversible capacity of 76.3 mAh g"−"1 can be obtained after 1000 cycles at 2.0 A g"−"1 and the retention is 42.7% for Li_2ZnTi_3O_8/La_2O_3, which is much higher than un-coated Li_2ZnTi_3O_8. The superior lithium storage performances of the Li_2ZnTi_3O_8/La_2O_3 can be ascribed to the stable layer of protection, small particle size and large surface area. Cyclic voltammograms result reveals that the La_2O_3 coating layer reduces the polarization and improves the electrochemical activity of anode. - Highlights: • Nano layer La_2O_3 coated Li_2ZnTi_3O_8 particles have been prepared via a suspension mixing process followed by heat treatment. • Coated Li_2ZnTi_3O_8 has enhanced high rate capability, cyclic stability and long lifespan performance. • Electrochemical properties were tested in a charge/discharge voltage range of 3.0–0.05 V (vs. Li/Li"+).

Experimental observation of the inductive electric field and related plasma nonuniformity in high frequency capacitive discharge

International Nuclear Information System (INIS)

Ahn, S. K.; Chang, H. Y.

2008-01-01

To elucidate plasma nonuniformity in high frequency capacitive discharges, Langmuir probe and B-dot probe measurements were carried out in the radial direction in a cylindrical capacitive discharge driven at 90 MHz with argon pressures of 50 and 400 mTorr. Through the measurements, a significant inductive electric field (i.e., time-varying magnetic field) was observed at the radial edge, and it was found that the inductive electric field creates strong plasma nonuniformity at high pressure operation. The plasma nonuniformity at high pressure operation is physically similar to the E-H mode transition typically observed in inductive discharges. This result agrees well with the theories of electromagnetic effects in large area and/or high frequency capacitive discharges

Electrical capacity and resistance determination of emitting electric transducer

International Nuclear Information System (INIS)

Alba Fernandez, J.; Ramis Soriano, J.

2000-01-01

In this work we calculate the electrical resistance and capacity of emitting electric transducer, which is mainly formed, in direct relationship with its properties, by a ceramic capacitor. Our aim is to motivate the students with an attractive element in order to carry out traditional measurements of the charge and discharge transients of a capacitor, implementing high resistance setups. (Author) 5 refs

Dependence of recycling and edge profiles on lithium evaporation in high triangularity, high performance NSTX H-mode discharges

Energy Technology Data Exchange (ETDEWEB)

Maingi, R., E-mail: rmaingi@pppl.gov [Princeton Plasma Physics Laboratory, Receiving 3, Route 1 North, Princeton, NJ 08543 (United States); Osborne, T.H. [General Atomics, 3550 General Atomics Ct., San Diego, CA 92121 (United States); Bell, M.G.; Bell, R.E.; Boyle, D.P. [Princeton Plasma Physics Laboratory, Receiving 3, Route 1 North, Princeton, NJ 08543 (United States); Canik, J.M. [Oak Ridge National Laboratory, PO Box 2008, Oak Ridge, TN 37831 (United States); Diallo, A.; Kaita, R.; Kaye, S.M.; Kugel, H.W.; LeBlanc, B.P. [Princeton Plasma Physics Laboratory, Receiving 3, Route 1 North, Princeton, NJ 08543 (United States); Sabbagh, S.A. [Applied Physics and Applied Math Dept., Columbia University, New York, NY 10027 (United States); Skinner, C.H. [Princeton Plasma Physics Laboratory, Receiving 3, Route 1 North, Princeton, NJ 08543 (United States); Soukhanovskii, V.A. [Lawrence Livermore National Laboratory, 7000 East Ave, PO Box 808, Livermore, CA 94551 (United States)

2015-08-15

In this paper, the effects of a pre-discharge lithium evaporation variation on highly shaped discharges in the National Spherical Torus Experiment (NSTX) are documented. Lithium wall conditioning (‘dose’) was routinely applied onto graphite plasma facing components between discharges in NSTX, partly to reduce recycling. Reduced D{sub α} emission from the lower and upper divertor and center stack was observed, as well as reduced midplane neutral pressure; the magnitude of reduction increased with the pre-discharge lithium dose. Improved energy confinement, both raw τ{sub E} and H-factor normalized to scalings, with increasing lithium dose was also observed. At the highest doses, we also observed elimination of edge-localized modes. The midplane edge plasma profiles were dramatically altered, comparable to lithium dose scans at lower shaping, where the strike point was farther from the lithium deposition centroid. This indicates that the benefits of lithium conditioning should apply to the highly shaped plasmas planned in NSTX-U.

Development of high capacity, high rate lithium ion batteries utilizing metal fiber conductive additives

Science.gov (United States)

Ahn, Soonho; Kim, Youngduk; Kim, Kyung Joon; Kim, Tae Hyung; Lee, Hyungkeun; Kim, Myung H.

As lithium ion cells dominate the battery market, the performance improvement is an utmost concern among developers and researchers. Conductive additives are routinely employed to enhance electrode conductivity and capacity. Carbon particulates—graphite or carbon black powders—are conventional and popular choices as conductive fillers. However, percolation requirements of particles demand significant volumetric content of impalpable, and thereby high area conductive fillers. As might be expected, the electrode active surface area escalates unnecessarily, resulting in overall increase in reaction with electrolytes and organic solvents. The increased reactions usually manifest as an irreversible loss of anode capacity, gradual oxidation and consumption of electrolyte on the cathode—which causes capacity decline during cycling—and an increased threat to battery safety by gas evolution and exothermic solvent oxidation. In this work we have utilized high aspect ratio, flexible, micronic metal fibers as low active area and high conductivity additives. The metal fibers appear well dispersed within the electrode and to satisfy percolation requirements very efficiently at very low volumetric content compared to conventional carbon-based conductive additives. Results from 18650-type cells indicate significant enhancements in electrode capacity and high rate capability while the irreversible capacity loss is negligible.

Estimating Discharge in Low-Order Rivers With High-Resolution Aerial Imagery

OpenAIRE

King, Tyler V.; Neilson, Bethany T.; Rasmussen, Mitchell T.

2018-01-01

Remote sensing of river discharge promises to augment in situ gauging stations, but the majority of research in this field focuses on large rivers (>50 m wide). We present a method for estimating volumetric river discharge in low-order (wide) rivers from remotely sensed data by coupling high-resolution imagery with one-dimensional hydraulic modeling at so-called virtual gauging stations. These locations were identified as locations where the river contracted under low flows, exposing a substa...

When High-Capacity Readers Slow Down and Low-Capacity Readers Speed Up: Working Memory and Locality Effects.

Science.gov (United States)

Nicenboim, Bruno; Logačev, Pavel; Gattei, Carolina; Vasishth, Shravan

2016-01-01

We examined the effects of argument-head distance in SVO and SOV languages (Spanish and German), while taking into account readers' working memory capacity and controlling for expectation (Levy, 2008) and other factors. We predicted only locality effects, that is, a slowdown produced by increased dependency distance (Gibson, 2000; Lewis and Vasishth, 2005). Furthermore, we expected stronger locality effects for readers with low working memory capacity. Contrary to our predictions, low-capacity readers showed faster reading with increased distance, while high-capacity readers showed locality effects. We suggest that while the locality effects are compatible with memory-based explanations, the speedup of low-capacity readers can be explained by an increased probability of retrieval failure. We present a computational model based on ACT-R built under the previous assumptions, which is able to give a qualitative account for the present data and can be tested in future research. Our results suggest that in some cases, interpreting longer RTs as indexing increased processing difficulty and shorter RTs as facilitation may be too simplistic: The same increase in processing difficulty may lead to slowdowns in high-capacity readers and speedups in low-capacity ones. Ignoring individual level capacity differences when investigating locality effects may lead to misleading conclusions.

When high-capacity readers slow down and low-capacity readers speed up: Working memory and locality effects

Directory of Open Access Journals (Sweden)

Bruno eNicenboim

2016-03-01

Full Text Available We examined the effects of argument-head distance in SVO and SOV languages (Spanish and German, while taking into account readers’ working memory capacity and controlling for expectation (Levy, 2008 and other factors. We predicted only locality effects, that is, a slow-down produced by increased dependency distance (Gibson, 2000; Lewis & Vasishth, 2005. Furthermore, we expected stronger locality effects for readers with low working memory capacity. Contrary to our predictions, low-capacity readers showed faster reading with increased distance, while high-capacity readers showed locality effects. We suggest that while the locality effects are compatible with memory-based explanations, the speedup of low-capacity readers can be explained by an increased probability of retrieval failure. We present a computational model based on ACT-R built under the previous assumptions, which is able to give a qualitative account for the present data and can be tested in future research. Our results suggest that in some cases, interpreting longer RTs as indexing increased processing difficulty and shorter RTs as facilitation may be too simplistic: The same increase in processing difficulty may lead to slowdowns in high-capacity readers and speedups in low-capacity ones. Ignoring individual level capacity differences when investigating locality effects may lead to misleading conclusions.

Experimental and theoretical investigations on the warm-up of a high-pressure mercury discharge lamp

International Nuclear Information System (INIS)

Zalach, J.; Franke, St.; Schoepp, H.; Araoud, Z.; Charrada, K.; Zissis, G.

2011-01-01

Modern high-pressure discharge lamps are forced to provide instant light and hot relight capabilities - if possible at lower power units. A detailed understanding of the warm-up of high-pressure discharge lamps is therefore required. Complex fluid model codes were developed for the past years including more and more processes like two-dimensional treatment of convection trying to provide a more comprehensive and consistent description of high-pressure discharge lamps. However, there is a lack of experimental data to examine the performance of these models. This work provides a very complete set of geometrical, electrical, spectroscopic, and thermographic data according to the warm-up of a high-pressure mercury discharge lamp that is compared to the results of a state of the art fluid code. Quantitative agreement is achieved for single parameters like wall temperatures. But the paper also reveals the need for further investigations and improvements of the code.

The acceleration intermediate phase (NiS and Ni3S2) evolution by nanocrystallization in Li/NiS2 thermal batteries with high specific capacity

Science.gov (United States)

Jin, Chuanyu; Zhou, Lingping; Fu, Licai; Zhu, Jiajun; Li, Deyi; Yang, Wulin

2017-06-01

The intermediate phase of NiS2 is thought to be a bottleneck currently to improve the overall performance of Li/NiS2 thermal batteries because of its low conductivity and close formation enthalpy between NiS2 and the intermediate phase (NiS, Ni3S2, etc). For improving the discharge performances of Li/NiS2 thermal batteries, the nano NiS2 with an average size of 85 ± 5 nm is designated as a cathode material. The electrochemical measurements show that the specific capacity of nano NiS2 cathode is higher than micro NiS2. The nano NiS2 cathode exhibits excellent electrochemical performances with high specific capacities of 794 and 654 mAh g-1 at current density of 0.1 and 0.5 A cm-2 under a cut-off voltage of 0.5 V, respectively. These results show that the rapid intermediate phase evolution from the nanocrystallization can obviously enhance use efficiency of NiS2 and improve discharge performances of thermal batteries.

Environmental and biotechnological applications of high-voltage pulsed discharges in water

International Nuclear Information System (INIS)

Sato, Masayuki

2008-01-01

A high-voltage pulse has wide application in fields such as chemistry, physics and biology and their combinations. The high-voltage pulse forms two kinds of physical processes in water, namely (a) a pulsed electric field (PEF) in the parallel electrode configuration and (b) plasma generation by a pulsed discharge in the water phase with a concentrated electric field. The PEF can be used for inactivation of bacteria in liquid foods as a non-thermal process, and the underwater plasma is applicable not only for the decomposition of organic materials in water but also for biological treatment of wastewater. These discharge states are controlled mainly by the applied pulse voltage and the electrode shape. Some examples of environmental and biotechnological applications of a high-voltage pulse are reviewed.

High-capacity FeTiO3/C negative electrode for sodium-ion batteries with ultralong cycle life

Science.gov (United States)

Ding, Changsheng; Nohira, Toshiyuki; Hagiwara, Rika

2018-06-01

The development of electrode materials which improve both the energy density and cycle life is one of the most challenging issues facing the practical application of sodium-ion batteries today. In this work, FeTiO3/C nanoparticles are synthesized as negative electrode materials for sodium-ion batteries. The electrochemical performance and charge-discharge mechanism of the FeTiO3/C negative electrode are investigated in an ionic liquid electrolyte at 90 °C. The FeTiO3/C negative electrode delivers a high reversible capacity of 403 mAh g-1 at a current rate of 10 mA g-1, and exhibits high rate capability and excellent cycling stability for up to 2000 cycles. The results indicate that FeTiO3/C is a promising negative electrode material for sodium-ion batteries.

Fishbone mode in high-β discharges of spherical tokamaks

International Nuclear Information System (INIS)

Kolesnichenko, Ya.I.; Lutsenko, V.V.; Marchenko, V.S.

2000-01-01

Using Hamiltonian formalism, it has been shown that well-trapped energetic ions moving outwards consume the energy of MHD perturbations through the precessional resonance provided that the plasma pressure is sufficiently high. This supports the conclusion of recent publication that the fishbone mode is stabilized in high-β discharges of spherical tokamaks. It has also been found that the presence of the velocity anisotropy of energetic ions does not change this conclusion. (author)

The influence of flood frequency, riparian vegetation and threshold on long-term river transport capacity

Science.gov (United States)

Croissant, Thomas; Lague, Dimitri; Davy, Philippe

2016-04-01

Climate fluctuations at geological timescales control the capacity of rivers to transport sediment with consequences on geochemical cycles, sedimentary basins dynamics and sedimentation/tectonics interactions. While the impact of differential friction generated by riparian vegetation has been studied for individual flood events, its impact on the long-term sediment transport capacity of rivers, modulated by the frequency of floods remains unknown. Here, we investigate this effect on a simplified river-floodplain configuration obeying observed hydraulic scaling laws. We numerically integrate the full-frequency magnitude distribution of discharge events and its impact on the transport capacity of bedload and suspended material for various level of vegetation-linked differential friction. We demonstrate that riparian vegetation by acting as a virtual confinement of the flow i) increases significantly the instantaneous transport capacity of the river independently of the transport mode and ii) increases the long term bedload transport rates as a function of discharge variability. Our results expose the dominance of flood frequency rather than riparian vegetation on the long term sediment transport capacity. Therefore, flood frequency has to be considered when evaluating long-term bedload transport capacity while floodplain vegetation is important only in high discharge variability regimes. By comparing the transport capacity of unconfined alluvial rivers and confined bedrock gorges, we demonstrate that the latter always presents the highest long term transport capacity at equivalent width and slope. The loss of confinement at the transition between bedrock and alluvial river must be compensated by a widening or a steepening of the alluvial channel to avoid infinite storage. Because steepening is never observed in natural system, we compute the alluvial widening factor value that varies between 3 to 11 times the width of the bedrock channel depending on riparian

High-speed micro-electro-discharge machining.

Energy Technology Data Exchange (ETDEWEB)

Chandrasekar, Srinivasan Dr. (.School of Industrial Engineering, West Lafayette, IN); Moylan, Shawn P. (School of Industrial Engineering, West Lafayette, IN); Benavides, Gilbert Lawrence

2005-09-01

When two electrodes are in close proximity in a dielectric liquid, application of a voltage pulse can produce a spark discharge between them, resulting in a small amount of material removal from both electrodes. Pulsed application of the voltage at discharge energies in the range of micro-Joules results in the continuous material removal process known as micro-electro-discharge machining (micro-EDM). Spark erosion by micro-EDM provides significant opportunities for producing small features and micro-components such as nozzle holes, slots, shafts and gears in virtually any conductive material. If the speed and precision of micro-EDM processes can be significantly enhanced, then they have the potential to be used for a wide variety of micro-machining applications including fabrication of microelectromechanical system (MEMS) components. Toward this end, a better understanding of the impacts the various machining parameters have on material removal has been established through a single discharge study of micro-EDM and a parametric study of small hole making by micro-EDM. The main avenues for improving the speed and efficiency of the micro-EDM process are in the areas of more controlled pulse generation in the power supply and more controlled positioning of the tool electrode during the machining process. Further investigation of the micro-EDM process in three dimensions leads to important design rules, specifically the smallest feature size attainable by the process.

Light and Light Sources High-Intensity Discharge Lamps

CERN Document Server

Flesch, Peter G

2006-01-01

Light and Light Sources gives an introduction to the working principles of high-intensity discharge (HID) lamps and points out challenges and problems associated with the development and operation of HID lamps. The state-of-the-art in electrode and plasma diagnostics as well as numerical methods used for the understanding of HID lamps are described. This volume addresses students as well as scientists and researchers at universities and in industry.

Plasma Perturbations in High-Speed Probing of Hall Thruster Discharge Chambers: Quantification and Mitigation

Science.gov (United States)

Jorns, Benjamin A.; Goebel, Dan M.; Hofer, Richard R.

2015-01-01

An experimental investigation is presented to quantify the effect of high-speed probing on the plasma parameters inside the discharge chamber of a 6-kW Hall thruster. Understanding the nature of these perturbations is of significant interest given the importance of accurate plasma measurements for characterizing thruster operation. An array of diagnostics including a high-speed camera and embedded wall probes is employed to examine in real time the changes in electron temperature and plasma potential induced by inserting a high-speed reciprocating Langmuir probe into the discharge chamber. It is found that the perturbations onset when the scanning probe is downstream of the electron temperature peak, and that along channel centerline, the perturbations are best characterized as a downstream shift of plasma parameters by 15-20% the length of the discharge chamber. A parametric study is performed to investigate techniques to mitigate the observed probe perturbations including varying probe speed, probe location, and operating conditions. It is found that the perturbations largely disappear when the thruster is operated at low power and low discharge voltage. The results of this mitigation study are discussed in the context of recommended methods for generating unperturbed measurements of the discharge chamber plasma.

Three-dimensional graphene sheets with NiO nanobelt outgrowths for enhanced capacity and long term high rate cycling Li-ion battery anode material

Science.gov (United States)

Shi, Waipeng; Zhang, Yingmeng; Key, Julian; Shen, Pei Kang

2018-03-01

An efficient synthesis method to grow well attached NiO nanobelts from 3D graphene sheets (3DGS) is reported herein. Ni-ion exchanged resin provides the initial Ni reactant portion, which serves both as a catalyst to form 3DGS and then as a seeding agent to grow the NiO nanobelts. The macroporous structure of 3DGS provides NiO containment to achieve a high cycling stability of up to 445 mAh g-1 after 360 cycles (and >112% capacity retention after 515 cycles) at a high current density of 2 A g-1. With a 26.8 wt.% content of NiO on 3DGS, increases in specific and volumetric capacity were 41.6 and 75.7% respectively over that of 3DGS at matching current densities. Therefore, the seeded growth of NiO nanobelts from 3DGS significantly boosts volumetric capacity, while 3DGS enables high rate long term cycling of the NiO. The high rate cycling stability of NiO on 3DGS can be attributed to (i) good attachment and contact to the large surface of 3DGS, (ii) high electron conductivity and rapid Li-ion transfer (via the interconnected, highly conductive graphitized walls of 3DGS) and (iii) buffering void space in 3DGS to contain volume expansion of NiO during charge/discharge.

Application to the system of insulated of diagnosis in high-voltage motors by partial discharge

International Nuclear Information System (INIS)

Mikami, M.

2005-01-01

In order to detect electric insulators degradation of high-voltage electric motors at an early stage, measurements of partial discharge of operating high-voltage electric motors (about 150 units) in the nuclear power plants were conducted from 2001 to 2004 by the use of on-line monitoring systems that could measure partial discharge of electric insulators. Influencing factors for measured values were identified from measured data and evaluation criteria of electric insulators integrity were established based on variations of partial discharge values. (T. Tanaka)

Comparison of high-voltage ac and pulsed operation of a surface dielectric barrier discharge

Science.gov (United States)

Williamson, James M.; Trump, Darryl D.; Bletzinger, Peter; Ganguly, Biswa N.

2006-10-01

A surface dielectric barrier discharge (DBD) in atmospheric pressure air was excited either by low frequency (0.3-2 kHz) high-voltage ac or by short, high-voltage pulses at repetition rates from 50 to 600 pulses s-1. The short-pulse excited discharge was more diffuse and did not have the pronounced bright multiple cathode spots observed in the ac excited discharge. The discharge voltage, current and average power deposited into the discharge were calculated for both types of excitation. As a measure of plasma-chemical efficiency, the ozone number density was measured by UV absorption as a function of average deposited power. The density of ozone produced by ac excitation did not increase so rapidly as that produced by short-pulse excitation as a function of average power, with a maximum measured density of ~3 × 1015 cm-3 at 25 W. The maximum ozone production achieved by short-pulse excitation was ~8.5 × 1015 cm-3 at 20 W, which was four times greater than that achieved by ac excitation at the same power level.

High performance discharges and capabilities in Alcator C-Mod

International Nuclear Information System (INIS)

Porkolab, M.

1996-01-01

Alcator C-Mod is a compact, diverted, shaped, high magnetic field (B = 9 T) tokamak operating at the Massachusetts Institute of Technology Plasma Fusion Center. The machine interior is all metallic, and the walls and divertor region are covered with molybdenum tiles. The vacuum vessel is a continuous, thick wall stainless steel construction, prototypical of future fusion devices (e.g., ITER). Typical discharge cleaning utilizes ECDC, or electron-cyclotron discharge cleaning, in the steady state at low magnetic field (0.0875 T). While its dimensions are compact (R = 0.67 m, a = 0.22 m, K = 1.8), C-Mod is designed to operate up to 2.5 MA at 9.0 T magnetic field. To present date the machine has operated at currents up to 1.5 MA at B = 5.3 T, and magnetic fields up to 8.0 T at I p = 1.2 MA. Due to the high current density, line average densities of 4.0 x 10 20 m -3 are obtained with gas fueling, and peak densities in excess of 1.0 x 10 21 m -3 have been obtained with pellet fueling. Typical pulse lengths are up to 2.0 seconds, with a flat-top of typically 1.0 sec. Presently the device is equipped with 4.0 MW of ICRF heating power operating at 80 MHz, but this capability is being upgraded to 8.0 MW with the addition of 4.0 MW of tunable ICRF power operating at 40.80 MHz. A 20 pellet/pulse deuterium injector is operational, and a 4 pellet Li injector is also operational. To reduce the influx of metallic impurities during high power operation, recently boronization of the machine interior was begun prior to plasma discharges, this allowed plasma operation with full auxiliary power capability without excessive radiative power losses from the plasma core. 7 refs

Physical aspects of mercury-free high pressure discharge lamps

International Nuclear Information System (INIS)

Born, M.

2002-01-01

This paper gives a summary of recent results about the replacement of mercury in high pressure discharge lamps by metallic zinc. Actually, this topic is of high relevance for the lighting industry due to the need of more environmentally friendly products. The work presented here is supported by the German government under contract no. 13N8072. Pure zinc/argon discharges as well as lamps including zinc or mercury and metal halide additives are investigated. Experimental data are compared with model calculations of the energy balance involving the transport of heat and radiation. Since the excitation energies of relevant zinc transistions are lower than for mercury, axis temperatures of pure zinc lamps are about 300 K below the value of mercury arcs. In addition, the thermal conductivity of zinc including the contribution of radiation diffusion is larger than compared to mercury. From lamp voltage measurements it is found that the cross section for elastical electron scattering by zinc atoms is about the same as for mercury. When adding metal halides to a pure zinc discharge with argon as a starting gas, i.e. NaI, TlI, DyI3, axis temperatures decrease to about 5100 K due to strong radiation cooling. In order to obtain sufficiently large lamp voltages, wall temperatures of more than 1300 K are adjusted by means of polycrystalline aluminaoxide (Al2O3) as a wall material. Electrical field strenghts of 6.0 V/mm and 8.6 V/mm are measured for metal halide lamps containing zinc or mercury, respectively. The light technical data of the discharges are very close, since mercury and zinc do not contribute significantly to the radiation in the visible range. Efficacies of up to 93 lm/W and 100 lm/W are found in metal halide lamps with zinc and mercury, respectively. Consequently, zinc turns out to be an attractive replacer for mercury in this type of lamp not only from an environmental point of view

Free-space optical communications with peak and average constraints: High SNR capacity approximation

KAUST Repository

Chaaban, Anas

2015-09-07

The capacity of the intensity-modulation direct-detection (IM-DD) free-space optical channel with both average and peak intensity constraints is studied. A new capacity lower bound is derived by using a truncated-Gaussian input distribution. Numerical evaluation shows that this capacity lower bound is nearly tight at high signal-to-noise ratio (SNR), while it is shown analytically that the gap to capacity upper bounds is a small constant at high SNR. In particular, the gap to the high-SNR asymptotic capacity of the channel under either a peak or an average constraint is small. This leads to a simple approximation of the high SNR capacity. Additionally, a new capacity upper bound is derived using sphere-packing arguments. This bound is tight at high SNR for a channel with a dominant peak constraint.

Reactor-specific spent fuel discharge projections, 1987-2020

International Nuclear Information System (INIS)

Walling, R.C.; Heeb, C.M.; Purcell, W.L.

1988-03-01

The creation of five reactor-specific spent fuel data bases that contain information on the projected amounts of spent fuel to be discharged from U.S. commercial nuclear reactors through the year 2020 is described. The data bases contain detailed spent fuel information from existing, planned, and projected pressurized water reactors (PWR) and boiling water eactors (BWR), and one existing high temperature gas reactor (HTGR). The projections are based on individual reactor information supplied by the U.S. reactor owners. The basic information is adjusted to conform to Energy Information Administration (EIA) forecasts for nuclear installed capacity, generation, and spent fuel discharged. The EIA cases considered are: No New Orders (assumes increasing burnup), No New Orders with No Increased Burnup, Upper Reference (assumes increasing burnup), Upper Reference with No Increased Burnup, and Lower Reference (assumes increasing burnup). Detailed, by-reactor tables are provided for annual discharged amounts of spent fuel, for storage requirements assuming maximum at-reactor storage, and for storage requirements assuming maximum at-reactor storage plus intra-utility transshipment of spent fuel. 8 refs., 8 figs., 10 tabs

Voluntary Running Aids to Maintain High Body Temperature in Rats Bred for High Aerobic Capacity

Science.gov (United States)

Karvinen, Sira M.; Silvennoinen, Mika; Ma, Hongqiang; Törmäkangas, Timo; Rantalainen, Timo; Rinnankoski-Tuikka, Rita; Lensu, Sanna; Koch, Lauren G.; Britton, Steven L.; Kainulainen, Heikki

2016-01-01

The production of heat, i.e., thermogenesis, is a significant component of the metabolic rate, which in turn affects weight gain and health. Thermogenesis is linked to physical activity (PA) level. However, it is not known whether intrinsic exercise capacity, aging, and long-term voluntary running affect core body temperature. Here we use rat models selectively bred to differ in maximal treadmill endurance running capacity (Low capacity runners, LCR and High capacity Runners, HCR), that as adults are divergent for aerobic exercise capacity, aging, and metabolic disease risk to study the connection between PA and body temperature. Ten high capacity runner (HCR) and ten low capacity runner (LCR) female rats were studied between 9 and 21 months of age. Rectal body temperature of HCR and LCR rats was measured before and after 1-year voluntary running/control intervention to explore the effects of aging and PA. Also, we determined whether injected glucose and spontaneous activity affect the body temperature differently between LCR and HCR rats at 9 vs. 21 months of age. HCRs had on average 1.3°C higher body temperature than LCRs (p temperature level of HCRs to similar levels with LCRs. The opportunity to run voluntarily had a significant impact on the body temperature of HCRs (p temperature at a similar level as when at younger age. Compared to LCRs, HCRs were spontaneously more active, had higher relative gastrocnemius muscle mass and higher UCP2, PGC-1α, cyt c, and OXPHOS levels in the skeletal muscle (p temperature of LCRs. However, glucose injection resulted in a lowering of the body temperature of LCRs (p temperature compared to rats born with low exercise capacity and disease risk. Voluntary running allowed HCRs to maintain high body temperature during aging, which suggests that high PA level was crucial in maintaining the high body temperature of HCRs. PMID:27504097

Bifunctional composite catalysts using Co3O4 nanofibers immobilized on nonoxidized graphene nanoflakes for high-capacity and long-cycle Li-O2 batteries.

Science.gov (United States)

Ryu, Won-Hee; Yoon, Taek-Han; Song, Sung Ho; Jeon, Seokwoo; Park, Yong-Joon; Kim, Il-Doo

2013-09-11

Designing a highly efficient catalyst is essential to improve the electrochemical performance of Li-O2 batteries for long-term cycling. Furthermore, these batteries often show significant capacity fading due to the irreversible reaction characteristics of the Li2O2 product. To overcome these limitations, we propose a bifunctional composite catalyst composed of electrospun one-dimensional (1D) Co3O4 nanofibers (NFs) immobilized on both sides of the 2D nonoxidized graphene nanoflakes (GNFs) for an oxygen electrode in Li-O2 batteries. Highly conductive GNFs with noncovalent functionalization can facilitate a homogeneous dispersion in solution, thereby enabling simple and uniform attachment of 1D Co3O4 NFs on GNFs without restacking. High first discharge capacity of 10 500 mAh/g and superior cyclability for 80 cycles with a limited capacity of 1000 mAh/g were achieved by (i) improved catalytic activity of 1D Co3O4 NFs with large surface area, (ii) facile electron transport via interconnected GNFs functionalized by Co3O4 NFs, and (iii) fast O2 diffusion through the ultrathin GNF layer and porous Co3O4 NF networks.

The Implementation Of Solid State Switches In A Parallel Configuration To Gain Output Current Capacity In A High Current Capacitive Discharge Unit (CDU).

Energy Technology Data Exchange (ETDEWEB)

Chaves, Mario Paul [Univ. of New Mexico, Albuquerque, NM (United States)

2017-07-01

For my project I have selected to research and design a high current pulse system, which will be externally triggered from a 5V pulse. The research will be conducted in the region of paralleling the solid state switches for a higher current output, as well as to see if there will be any other advantages in doing so. The end use of the paralleled solid state switches will be used on a Capacitive Discharge Unit (CDU). For the first part of my project, I have set my focus on the design of the circuit, selection of components, and simulation of the circuit.

Three-dimensional hierarchical porous flower-like nickel-cobalt oxide/multi-walled carbon nanotubes nanocomposite for high-capacity supercapacitors

Energy Technology Data Exchange (ETDEWEB)

Liu, Peipei; Hu, Zhonghua, E-mail: huzh@tongji.edu.cn; Liu, Yafei; Yao, Mingming; Zhang, Qiang

2015-02-15

Highlights: • 3D hierarchical porous flower-like Ni-Co oxide/MWCNTs was synthesized. • The electrode shows a large specific surface area and desirable mesoporosity. • High specific capacitances and outstanding stability were obtained. • The content of MWCNTs affects the electrochemical properties of the electrode. - Abstract: Three-dimensional (3D) hierarchical porous flower-like nickel-cobalt oxide/multi-walled carbon nanotubes (Ni-Co oxide/MWCNTs) nanocomposites were fabricated by a facile and template-free hydrothermal method as electrodes for high-capacity supercapacitors. The samples were characterized by energy dispersive spectroscopy (EDS), X-ray diffraction (XRD), X-ray photoelectron spectroscopy (XPS), scanning electron microscopy (SEM), transmission electron microscopy (TEM), nitrogen adsorption-desorption and thermal gravimetric analysis (TGA). The electrochemical performance was investigated by cyclic voltammetry (CV), galvanostatic charge-discharge, and cycle life. It was found that Ni-Co oxide/MWCNTs nanocomposites displayed a high specific capacitance (1703 F g{sup −1} at a discharge current density of 1 A g{sup −1}) and, additionally, an excellent cycling performance, retaining 97% of the maximum capacitance after 2000 cycles at 10 A g{sup −1}. Even at a high current density (20 A g{sup −1}), the specific capacitance was still up to 1309 F g{sup −1}. This outstanding capacitive performance may be attributed to the ideal composition of the material and to its unique 3D hierarchical porous flower-like architecture.

Three-dimensional hierarchical porous flower-like nickel-cobalt oxide/multi-walled carbon nanotubes nanocomposite for high-capacity supercapacitors

International Nuclear Information System (INIS)

Liu, Peipei; Hu, Zhonghua; Liu, Yafei; Yao, Mingming; Zhang, Qiang

2015-01-01

Highlights: • 3D hierarchical porous flower-like Ni-Co oxide/MWCNTs was synthesized. • The electrode shows a large specific surface area and desirable mesoporosity. • High specific capacitances and outstanding stability were obtained. • The content of MWCNTs affects the electrochemical properties of the electrode. - Abstract: Three-dimensional (3D) hierarchical porous flower-like nickel-cobalt oxide/multi-walled carbon nanotubes (Ni-Co oxide/MWCNTs) nanocomposites were fabricated by a facile and template-free hydrothermal method as electrodes for high-capacity supercapacitors. The samples were characterized by energy dispersive spectroscopy (EDS), X-ray diffraction (XRD), X-ray photoelectron spectroscopy (XPS), scanning electron microscopy (SEM), transmission electron microscopy (TEM), nitrogen adsorption-desorption and thermal gravimetric analysis (TGA). The electrochemical performance was investigated by cyclic voltammetry (CV), galvanostatic charge-discharge, and cycle life. It was found that Ni-Co oxide/MWCNTs nanocomposites displayed a high specific capacitance (1703 F g −1 at a discharge current density of 1 A g −1 ) and, additionally, an excellent cycling performance, retaining 97% of the maximum capacitance after 2000 cycles at 10 A g −1 . Even at a high current density (20 A g −1 ), the specific capacitance was still up to 1309 F g −1 . This outstanding capacitive performance may be attributed to the ideal composition of the material and to its unique 3D hierarchical porous flower-like architecture

Investigation of Ozone Yield of Air Fed Ozonizer by High Pressure Homogeneous Dielectric Barrier Discharge

Science.gov (United States)

2013-07-01

around 2 ms and 12 ms in this figure, and during the discharge period, the current was continuous without any pulse . Once a discharge generated in...electron avalanches [10]. Fig. 1. High pressure ozone generator. (a) Top view (b) Side view Fig. 2. Barrier discharge device. Table 1... discharge N. Osawa P1 P, UY. Yoshioka UP2 P, R. Hanaoka P1 P 1 Center for Electric, Optic and Energy applications, Department of Electric and

The effect of solvent component on the discharge performance of Lithium-sulfur cell containing various organic electrolytes

International Nuclear Information System (INIS)

Kim, Seok; Jung, Yongju; Lim, Hong S.

2004-01-01

The effect of solvent component on the discharge performance of lithium-sulfur (Li/S) cell and the optimal composition of ternary electrolyte for the improved discharge performance of the cell have been investigated. The capacity value and capacity stability with cycle are dependent on the nature of solvent as well as the composition of mixed solvent. The change trend of discharge performance as a function of content of each solvent component is studied. Capacity value increases as the 1,3-dioxolane (DOX) content decreases. Average discharge voltage shows larger value when the 1,2-dimethoxy ethane (DME) content is small. Finally, we have obtained the optimal solvent composition by using a statistical method

High-k shallow traps observed by charge pumping with varying discharging times

International Nuclear Information System (INIS)

Ho, Szu-Han; Chen, Ching-En; Tseng, Tseung-Yuen; Chang, Ting-Chang; Lu, Ying-Hsin; Lo, Wen-Hung; Tsai, Jyun-Yu; Liu, Kuan-Ju; Wang, Bin-Wei; Cao, Xi-Xin; Chen, Hua-Mao; Cheng, Osbert; Huang, Cheng-Tung; Chen, Tsai-Fu

2013-01-01

In this paper, we investigate the influence of falling time and base level time on high-k bulk shallow traps measured by charge pumping technique in n-channel metal-oxide-semiconductor field-effect transistors with HfO 2 /metal gate stacks. N T -V high level characteristic curves with different duty ratios indicate that the electron detrapping time dominates the value of N T for extra contribution of I cp traps. N T is the number of traps, and I cp is charge pumping current. By fitting discharge formula at different temperatures, the results show that extra contribution of I cp traps at high voltage are in fact high-k bulk shallow traps. This is also verified through a comparison of different interlayer thicknesses and different Ti x N 1−x metal gate concentrations. Next, N T -V high level characteristic curves with different falling times (t falling time ) and base level times (t base level ) show that extra contribution of I cp traps decrease with an increase in t falling time . By fitting discharge formula for different t falling time , the results show that electrons trapped in high-k bulk shallow traps first discharge to the channel and then to source and drain during t falling time . This current cannot be measured by the charge pumping technique. Subsequent measurements of N T by charge pumping technique at t base level reveal a remainder of electrons trapped in high-k bulk shallow traps

Infrared gas phase study on plasma-polymer interactions in high-current diffuse dielectric barrier discharge

NARCIS (Netherlands)

Liu, Y.; Welzel, S.; Starostin, S. A.; van de Sanden, M. C. M.; Engeln, R.; de Vries, H. W.

2017-01-01

A roll-to-roll high-current diffuse dielectric barrier discharge at atmospheric pressure was operated in air and Ar/N2/O2 gas mixtures. The exhaust gas from the discharge was studied using a high-resolution Fourier-transform infrared spectrometer in the range from 3000 to 750?cm-1 to unravel the

On the High Altitude Platform (HAP W-CDMA System Capacity

Directory of Open Access Journals (Sweden)

L. de Haro-Ariet

2004-06-01

Full Text Available The performance of a downlink power control model, based on a n-thpower distance law, is evaluated for high altitude platform station(HAPS W-CDMA systems. The downlink capacity using this model iscompared with the uplink capacity. It is shown that the uplink capacityis higher than the downlink capacity.

High-current magnetron discharge with magnetic insulation of anode

International Nuclear Information System (INIS)

Bizyukov, A.A.; Sereda, K.N.; Sleptsov, V.V.

2008-01-01

In magnetron discharge at currents higher then critical which magnitude is in the range of 15...30 A the transition from glow discharge in transverse magnetic field to arc discharge occurs. In the present time the problem of arc blowout is solved at the expense of pulse and HF power supply applying. In this paper the alternative method of limiting current of magnetron discharge increasing at the expense of increasing of discharge gap resistance by means of additional anode layer transverse magnetic field and arc current interruption by sectioning of current collector of anode surface is carrying out

Applying the welfare model to at-own-risk discharges.

Science.gov (United States)

Krishna, Lalit Kumar Radha; Menon, Sumytra; Kanesvaran, Ravindran

2017-08-01

"At-own-risk discharges" or "self-discharges" evidences an irretrievable breakdown in the patient-clinician relationship when patients leave care facilities before completion of medical treatment and against medical advice. Dissolution of the therapeutic relationship terminates the physician's duty of care and professional liability with respect to care of the patient. Acquiescence of an at-own-risk discharge by the clinician is seen as respecting patient autonomy. The validity of such requests pivot on the assumptions that the patient is fully informed and competent to invoke an at-own-risk discharge and that care up to the point of the at-own-risk discharge meets prevailing clinical standards. Palliative care's use of a multidisciplinary team approach challenges both these assumptions. First by establishing multiple independent therapeutic relations between professionals in the multidisciplinary team and the patient who persists despite an at-own-risk discharge. These enduring therapeutic relationships negate the suggestion that no duty of care is owed the patient. Second, the continued employ of collusion, familial determinations, and the circumnavigation of direct patient involvement in family-centric societies compromises the patient's decision-making capacity and raises questions as to the patient's decision-making capacity and their ability to assume responsibility for the repercussions of invoking an at-own-risk discharge. With the validity of at-own-risk discharge request in question and the welfare and patient interest at stake, an alternative approach to assessing at-own-risk discharge requests are called for. The welfare model circumnavigates these concerns and preserves the patient's welfare through the employ of a multidisciplinary team guided holistic appraisal of the patient's specific situation that is informed by clinical and institutional standards and evidenced-based practice. The welfare model provides a robust decision-making framework for

The influence of different parameters on the discharge capacity and cycling performance of an S/C-composite cathode

OpenAIRE

Eberle, Anna-Marietta

2017-01-01

Lithium Sulfur batteries are thought to be the next generation energy storage device, because of their high theoretical capacity and energy density. At the moment, their practical application is hindered by several issues, for example fast degradation, low Sulfur (S) utilization or the often too low S loadings to give high areal capacities. Here, a Sulfur/Carbon-composite (S/C-composite) is introduced, which can be synthesised by an easy bottom-up approach with a high S-content in the resulti...

Comparison of high-voltage ac and pulsed operation of a surface dielectric barrier discharge

Energy Technology Data Exchange (ETDEWEB)

Williamson, James M [Innovative Scientific Solutions, Inc., 2766 Indian Ripple Road, Dayton, Ohio 45440-3638 (United States); Trump, Darryl D [Innovative Scientific Solutions, Inc., 2766 Indian Ripple Road, Dayton, Ohio 45440-3638 (United States); Bletzinger, Peter [Innovative Scientific Solutions, Inc., 2766 Indian Ripple Road, Dayton, Ohio 45440-3638 (United States); Ganguly, Biswa N [Air Force Research Laboratory, Wright-Patterson Air Force Base, Ohio 45433-7919 (United States)

2006-10-21

A surface dielectric barrier discharge (DBD) in atmospheric pressure air was excited either by low frequency (0.3-2 kHz) high-voltage ac or by short, high-voltage pulses at repetition rates from 50 to 600 pulses s{sup -1}. The short-pulse excited discharge was more diffuse and did not have the pronounced bright multiple cathode spots observed in the ac excited discharge. The discharge voltage, current and average power deposited into the discharge were calculated for both types of excitation. As a measure of plasma-chemical efficiency, the ozone number density was measured by UV absorption as a function of average deposited power. The density of ozone produced by ac excitation did not increase so rapidly as that produced by short-pulse excitation as a function of average power, with a maximum measured density of {approx}3 x 10{sup 15} cm{sup -3} at 25 W. The maximum ozone production achieved by short-pulse excitation was {approx}8.5 x 10{sup 15} cm{sup -3} at 20 W, which was four times greater than that achieved by ac excitation at the same power level.

Comparison of high-voltage ac and pulsed operation of a surface dielectric barrier discharge

International Nuclear Information System (INIS)

Williamson, James M; Trump, Darryl D; Bletzinger, Peter; Ganguly, Biswa N

2006-01-01

A surface dielectric barrier discharge (DBD) in atmospheric pressure air was excited either by low frequency (0.3-2 kHz) high-voltage ac or by short, high-voltage pulses at repetition rates from 50 to 600 pulses s -1 . The short-pulse excited discharge was more diffuse and did not have the pronounced bright multiple cathode spots observed in the ac excited discharge. The discharge voltage, current and average power deposited into the discharge were calculated for both types of excitation. As a measure of plasma-chemical efficiency, the ozone number density was measured by UV absorption as a function of average deposited power. The density of ozone produced by ac excitation did not increase so rapidly as that produced by short-pulse excitation as a function of average power, with a maximum measured density of ∼3 x 10 15 cm -3 at 25 W. The maximum ozone production achieved by short-pulse excitation was ∼8.5 x 10 15 cm -3 at 20 W, which was four times greater than that achieved by ac excitation at the same power level

The interval high rate discharge behavior of Li3V2(PO4)3/C cathode based on in situ polymerization method

International Nuclear Information System (INIS)

Mao, Wen-feng; Yan, Ji; Xie, Hui; Tang, Zhi-yuan; Xu, Qiang

2013-01-01

An in situ polymerization assisted fast sol–gel method was introduced to synthesize high performance Li 3 V 2 PO 4 /C (LVP/C) cathode material. The crystal structure, surface morphology and electrochemical performances of the LVP/C samples sintered at different temperatures were investigated. The composite sintered at 750 °C exhibits the highest specific discharge capacity of 119.02 mAh g −1 (440.35 Wh g −1 ) at 10 C rate. The Li + diffusion coefficient ranges from 10 −6 to 10 −8 cm 2 s −1 based on different scanning rates and the electronic conductivity is about 10 −5 S cm −1 . For comparison, an ex situ polymerization method was also employed to obtain the LVP/C composite. A novel charge/discharge testing mode was designed to investigate the electrochemical behavior of the as-prepared LVP/C composite for practical application in electric vehicle cells. The obtained high power density and the special testing mode prove the LVP/C composite would be a promising candidate for the electric vehicle application and deserves further investigation

Does visual short-term memory have a high-capacity stage?

Science.gov (United States)

Matsukura, Michi; Hollingworth, Andrew

2011-12-01

Visual short-term memory (VSTM) has long been considered a durable, limited-capacity system for the brief retention of visual information. However, a recent work by Sligte et al. (Plos One 3:e1699, 2008) reported that, relatively early after the removal of a memory array, a cue allowed participants to access a fragile, high-capacity stage of VSTM that is distinct from iconic memory. In the present study, we examined whether this stage division is warranted by attempting to corroborate the existence of an early, high-capacity form of VSTM. The results of four experiments did not support Sligte et al.'s claim, since we did not obtain evidence for VSTM retention that exceeded traditional estimates of capacity. However, performance approaching that observed in Sligte et al. can be achieved through extensive practice, providing a clear explanation for their findings. Our evidence favors the standard view of VSTM as a limited-capacity system that maintains a few object representations in a relatively durable form.

3-dimensional porous NiCo2O4 nanocomposite as a high-rate capacity anode for lithium-ion batteries

International Nuclear Information System (INIS)

Mo, Yudi; Ru, Qiang; Song, Xiong; Hu, Shejun; Guo, Lingyun; Chen, Xiaoqiu

2015-01-01

Highlights: • D-glucose molecules as organic carbon source, have a crucial effect on the morphology and pore distribution of the synthetic products. • Facile synthesis: solvothermal method. • High rate capacity: 625 mAh g −1 at 4.4 C. • Improved long-term cycling stability: 1389 mAh g −1 after 180 cycles at 0.55 C. - Abstract: In this work, organic carbon modified NiCo 2 O 4 (NCO@C) nanocomposite with porous 3-dimensional (3D) structure was successfully synthesized by a facile hydrothermal method in D-glucose-mediated processes. A detailed research reveals that D-glucose molecules play an important role in the formation of the porous 3D structure and also provide a conductive carbon network within the NCO@C nanocomposite materials. Such a porous 3D interconnected carbonaceous nanostructure applied as electrode material for lithium-ion batteries (LIBs) shows that its reversible capacity, cycling stability, and rate capability are significantly enhanced in comparison with those of pure NiCo 2 O 4 (NCO) electrode. The as-prepared NCO@C composite electrode with porous 3D nanostructure displays a higher discharge specific capacity of 1389 mAh g −1 even after 180 cycles at a current rate of 0.55 C. Furthermore, this composite material also presents a high rate capacity, when the current rate gradually increases to 0.55 C, 1.1 C, 2.2 C, and 4.4 C, the reversible capacity can still render about 1082, 1029, 850, and 625 mAh g −1 , respectively. The enhanced electrochemical performance indicated that the NCO@C nanocomposite might be a very promising candidate to replace conventional graphite-based anode materials for LIBs

High performance discharges near the operational limit in HT-7

International Nuclear Information System (INIS)

Li Jiangang; Wan Baonian; Luo Jiarong; Gao Xiang; Zhao Yanping; Kuang Guangli; Zhang Xiaodong; Yang Yu; Yi Bao; Bojiang Ding; Jikang Xie; Yuanxi Wan

2001-01-01

Efforts have been made on the HT-7 tokamak to extend the stable operation boundaries. Extensive RF boronization and siliconization have been used and a wider operational Hugill diagram has been obtained. The transit density reached 1.3 times the Greenwald density limit in ohmic discharges. A stationary high performance discharge with q a =2.1 has been obtained after siliconization. Confinement improvement was obtained as a result of the significant reduction of electron thermal diffusivity χ e in the outer region of the plasma. An improved confinement phase was also observed with LHCD in the density range of 70-120% of the Greenwald density limit. Off-axis LH wave power deposition was attributed to the weak hollow current density profile. Code simulations and measurements showed good agreement with the off-axis LH wave deposition. Supersonic molecular beam injection has been successfully used to achieve stable high density operation in the region of the Greenwald density limit. (author)

Developing Leadership Capacity in Others: An Examination of High School Principals' Personal Capacities for Fostering Leadership

Science.gov (United States)

Huggins, Kristin Shawn; Klar, Hans W.; Hammonds, Hattie L.; Buskey, Frederick C.

2017-01-01

In this multisite case study, we examine the personal capacities of six high school principals who have developed the leadership capacities of other leaders in their respective schools. Participants were purposefully selected by two teams of researchers in two states of the United States, one on the east coast and one on the west coast, who…

Analysis of high-pressure safety valves

NARCIS (Netherlands)

Beune, A.

2009-01-01

In presently used safety valve sizing standards the gas discharge capacity is based on a nozzle flow derived from ideal gas theory. At high pressures or low temperatures real gas effects can no longer be neglected, so the discharge coefficient corrected for flow losses cannot be assumed constant

Low levels of serum total antioxidant capacity and presence at admission and absence at discharge of a day/night change as a marker of acute paranoid schizophrenia relapse.

Science.gov (United States)

Morera-Fumero, Armando L; Díaz-Mesa, Estefanía; Abreu-Gonzalez, Pedro; Fernandez-Lopez, Lourdes; Cejas-Mendez, Maria Del Rosario

2017-03-01

An oxidant-antioxidant system dysregulation has been described as a schizophrenia pathophysiological base. The total antioxidant capacity (TAC) is one measure of the antioxidant capacity of a system. Day/night concentration changes is a biological characteristic of hormones such as melatonin or cortisol. There is no information about TAC day/night changes in schizophrenia. Studying the existence of a day/night TAC change in schizophrenia. Forty-three DSM-IV paranoid schizophrenia inpatients participated in the study. Thirty healthy subjects matched by age and gender acted as control group. Blood was sampled at 12:00 and 00:00h the day after admission and the day before discharge. Serum TAC was measured by the ABTS radical cation technique and expressed in Trolox mmol/L. Patients had significantly lower TAC levels at admission and discharge (12:00 and 00:00) than controls. At admission patients had a TAC day/night change, with higher day-time than night-time levels (0.66±0.14 vs 0.60±0.15) as well as healthy subjects (0.83±0.07 vs 0.77±0.11). At discharge patients had a similar TAC level at 12:00 and 00:00 (0.64±0.15 vs 0.63±0.14). Schizophrenic patients present a deficit of the antioxidant system. The initial presence and the later absence of a day/night change deserves future studies. Copyright © 2017 Elsevier Ireland Ltd. All rights reserved.

OTDM Networking for Short Range High-Capacity Highly Dynamic Networks

DEFF Research Database (Denmark)

Medhin, Ashenafi Kiros

This PhD thesis aims at investigating the possibility of designing energy-efficient high-capacity (up to Tbit/s) optical network scenarios, leveraging on the effect of collective switching of many bits simultaneously, as is inherent in high bit rate serial optical data signals. The focus...... is on short range highly dynamic networks, catering to data center needs. The investigation concerns optical network scenarios, and experimental implementations of high bit rate serial data packet generation and reception, scalable optical packet labeling, simple optical label extraction and stable ultra...

High-voltage high-current triggering vacuum switch

International Nuclear Information System (INIS)

Alferov, D.F.; Bunin, R.A.; Evsin, D.V.; Sidorov, V.A.

2012-01-01

Experimental investigations of switching and breaking capacities of the new high current triggered vacuum switch (TVS) are carried out at various parameters of discharge current. It has been shown that the high current triggered vacuum switch TVS can switch repeatedly a current from units up to ten kiloampers with duration up to ten millisecond [ru

Reactor-specific spent fuel discharge projections, 1984 to 2020

International Nuclear Information System (INIS)

Heeb, C.M.; Libby, R.A.; Holter, G.M.

1985-04-01

The original spent fuel utility data base (SFDB) has been adjusted to produce agreement with the EIA nuclear energy generation forecast. The procedure developed allows the detail of the utility data base to remain intact, while the overall nuclear generation is changed to match any uniform nuclear generation forecast. This procedure adjusts the weight of the reactor discharges as reported on the SFDB and makes a minimal (less than 10%) change in the original discharge exposures in order to preserve discharges of an integral number of fuel assemblies. The procedure used in developing the reactor-specific spent fuel discharge projections, as well as the resulting data bases themselves, are described in detail in this report. Discussions of the procedure cover the following topics: a description of the data base; data base adjustment procedures; addition of generic power reactors; and accuracy of the data base adjustments. Reactor-specific discharge and storage requirements are presented. Annual and cumulative discharge projections are provided. Annual and cumulative requirements for additional storage are shown for the maximum at-reactor (AR) storage assumption, and for the maximum AR with transshipment assumption. These compare directly to the storage requirements from the utility-supplied data, as reported in the Spent Fuel Storage Requirements Report. The results presented in this report include: the disaggregated spent fuel discharge projections; and disaggregated projections of requirements for additional spent fuel storage capacity prior to 1998. Descriptions of the methodology and the results are included in this report. Details supporting the discussions in the main body of the report, including descriptions of the capacity and fuel discharge projections, are included. 3 refs., 6 figs., 12 tabs

STATIONARY HIGH-PERFORMANCE DISCHARGES IN THE DIII-D TOKAMAK

International Nuclear Information System (INIS)

LUCE, TC; WADE, MR; FERRON, JR; HYATT, AW; KELLMAN, AG; KINSEY, JE; LAHAYE, RJ; LASNIER, CJ; MURAKAMI, M; POLITZER, PA; SCOVILLE, JT

2002-01-01

A271 STATIONARY HIGH-PERFORMANCE DISCHARGES IN THE DII-D TOKAMAK. Discharges which can satisfy the high gain goals of burning plasma experiments have been demonstrated in the DIII-D tokamak under stationary conditions at relatively low plasma current (q 95 > 4). A figure of merit for fusion gain (β N H 89 /q 95 2 ) has been maintained at values corresponding to | = 10 operation in a burning plasma for > 6 s or 36τ E and 2τ R . The key element is the relaxation of the current profile to a stationary state with q min > 1. In the absence of sawteeth and fishbones, stable operation has been achieved up to the estimated no-wall β limit. Feedback control of the energy content and particle inventory allow reproducible, stationary operation. The particle inventory is controlled by gas fueling and active pumping; the wall plays only a small role in the particle balance. The reduced current lessens significantly the potential for structural damage in the event of a major disruption. In addition, the pulse length capability is greatly increased, which is essential for a technology testing phase of a burning plasma experiment where fluence (duty cycle) is important

Hollow-cathode electrode for high-power, high-pressure discharge devices

Science.gov (United States)

Chang, J.J.; Alger, T.W.

1995-08-22

Several different cold cathode configurations are disclosed for a gas discharge device each having a plurality of grooves of selected spacing, depth and width to improve the emission of electrons in a gas discharge device. Each of the cold cathode configurations can be machined from a single piece of a selected material. Several of the configurations can be assembled with individual elements which is easily seen from the various figures. 8 figs.

Synthesis of Poly (Butyl Methacrylate/Butyl Acrylate) Highly Absorptive Resin Using Glow Discharge Electrolysis

International Nuclear Information System (INIS)

Li Yan; Yao Mengqi; Liao Ruirui; Yang Wu; Gao Jinzhang; Ren Jie

2014-01-01

A highly absorptive resin poly (butyl methacrylate (BMA)-co-butyl acrylate (BA)) was prepared by emulsion polymerization, which was initiated by glow discharge electrolysis plasma (GDEP). The effects of discharge voltage, discharge time, monomer ratio and the amounts of cross-linking agent were examined and discussed in detail. The chemical structure of the obtained resin was characterized by means of attenuated total reflectance Fourier transform infrared spectroscopy, thermogravimetric analysis, and scanning electron microscopy. The optimal conditions were obtained as: discharge voltage was 600 V, discharge time was 8 min, the ratios of BMA:BA being 2:1 for chloroform and 3:1 for xylene, with 2% N, N'-methylenebis. Under optimal conditions, the oil absorbency was 70 g/g for chloroform and 46 g/g for xylene. Moreover, the absorptive dynamical behavior of the resulting resin was also investigated

Energy efficiency and capacity retention of Ni–MH batteries for storage applications

International Nuclear Information System (INIS)

Zhu, Wenhua H.; Zhu, Ying; Davis, Zenda; Tatarchuk, Bruce J.

2013-01-01

Highlights: ► Ni–MH battery energy efficiency was evaluated at full and partial state-of-charge. ► State-of-charge and state-of-recharge were studied by voltage changes and capacity measurement. ► Capacity retention of the NiMH-B2 battery was 70% after fully charge and 1519 h of storage. ► The inefficient charge process started at ca. 90% of rated capacity when charged at ⩽0.2 C rate. ► Battery durability and low self-discharge strategies are analyzed and discussed for energy storage needs. - Abstract: The Ni–MH batteries were tested for battery energy storage characteristics, including the effects of battery charge or discharge at different rates. The battery energy efficiency and capacity retention were evaluated through measuring the charge/discharge capacities and energies during full and partial state-of-charge (SoC) operations. Energy efficiency results were obtained at various charge input levels and different charge and discharge rates. The inefficient charging process started to take place at ca. 90% state-of-recharge (SoR) when charged at no more than 0.2 C rate. For the NiMH-B2 battery after an approximately full charge (∼100% SoC at 120% SoR and a 0.2 C charge/discharge rate), the capacity retention was obtained as 83% after 360 h of storage, and 70% after 1519 h of storage. The energy efficiency was decreased from 74.0% to 50% after 1519 h of storage time. The Coulomb efficiency was initially 83.34%, and was reduced to 57.95% after 1519 h of storage. The battery has relatively higher energy efficiency at approximately 50% SoC. The energy efficiency was calculated to be more than 92% when the NiMH-C3 battery was charged to 30–70% SoC then discharged to 0% SoC at a 0.2 C charge/discharge rate. In consideration of energy efficiency, charge acceptance, capacity retention rate, and power output needs, as well as Nelson’s analysis on HEV power requirements, the Ni–MH battery is appropriate to work at ca. 50 ± 10% SoC with an

Controlled synthesis of porous anhydrous cobalt oxalate nanorods with high reversible capacity and excellent cycling stability

International Nuclear Information System (INIS)

Xu, Junmin; He, Lei; Liu, Hui; Han, Tao; Wang, Yongjian; Zhang, Changjin; Zhang, Yuheng

2015-01-01

Graphical abstract: Display Omitted -- Abstract: One-dimensional porous anhydrous cobalt oxalate nanorods are prepared via a facile water-controlled coprecipitate method followed by thermal annealing treatment under N 2 at 300 °C. The nanorods are characterized by using X-ray diffraction, scanning electron microscopy and transmission electron microscopy. When evaluated as an anode material for lithium ion batteries, the nanorods exhibit high reversible specific capacity and excellent cycling stability (924 mA h g −1 at 50 mA g −1 after 100 cycles and 709 mA h g −1 at 200 mA g −1 after 220 cycles). This remarkable electrochemical performance is attributed to the one-dimensional porous nanostructure that can provide large electrode/electrolyte contact area and short lithium-ion diffusion pathway, meanwhile reduce the volume expansion during the repeated discharge/charge process

The formation of metallic plasmas in transient capillary discharges at high current

International Nuclear Information System (INIS)

Wyndham, E S; Favre, M; Aliaga-Rossel, R

2006-01-01

We report observations of the formation of a metallic plasma in a high aspect ratio z-pinch confined within a ceramic capillary. A series of experiments on different capillary geometries was undertaken in which titanium metal rings were used to promote the formation of a titanium plasma through preferential ablation. In an initial vacuum a titanium seed plasma is formed in the hollow cathode (HC) volume by a low energy laser spark. This pre-ionizing plasma is assisted in its expansion into the z-pinch volume by the electron beams generated by a pre-ionizing discharge in the capillary, due to the HC effect. Further intense e-beam activity occurs on applying the main driver current to the capillary electrodes before the discharge impedance abruptly drops to give rise to an ensuing high current z-pinch. A segmented titanium ring structure within the capillary promotes metal ablation. The discharges are performed in tubes of 60 to 110 mm length and 3 and 5 mm effective internal diameter. The main discharge current is provided from a small pulsed power switched coaxial line, at up to 150 kA. The generator may be configured to deliver two different rates of current rise and this is found to have a significant effect on the plasma dynamics. The plasma properties are obtained from observations of the axial x-ray emission. The diagnostics used are filtered Si diodes, filtered time-resolved multi-pinhole camera images and the time resolved soft x-ray spectrum from 3 to 20 nm. While a single species metal plasma is not obtained, a very significant proportion of Ti is achieved in the higher rate of current rise configuration. The fraction of Ti diminishes for the longest length discharges and for the larger diameter tube diameter, as does the observed z-pinch uniformity. There is a weak dependance of the electron temperature with tube geometry, but the plasma density falls substantially in the longer discharges. This coincides with diminished effectiveness of the transient HC

Reversible anionic redox chemistry in high-capacity layered-oxide electrodes

Science.gov (United States)

Sathiya, M.; Rousse, G.; Ramesha, K.; Laisa, C. P.; Vezin, H.; Sougrati, M. T.; Doublet, M.-L.; Foix, D.; Gonbeau, D.; Walker, W.; Prakash, A. S.; Ben Hassine, M.; Dupont, L.; Tarascon, J.-M.

2013-09-01

Li-ion batteries have contributed to the commercial success of portable electronics and may soon dominate the electric transportation market provided that major scientific advances including new materials and concepts are developed. Classical positive electrodes for Li-ion technology operate mainly through an insertion-deinsertion redox process involving cationic species. However, this mechanism is insufficient to account for the high capacities exhibited by the new generation of Li-rich (Li1+xNiyCozMn(1-x-y-z)O2) layered oxides that present unusual Li reactivity. In an attempt to overcome both the inherent composition and the structural complexity of this class of oxides, we have designed structurally related Li2Ru1-ySnyO3 materials that have a single redox cation and exhibit sustainable reversible capacities as high as 230 mA h g-1. Moreover, they present good cycling behaviour with no signs of voltage decay and a small irreversible capacity. We also unambiguously show, on the basis of an arsenal of characterization techniques, that the reactivity of these high-capacity materials towards Li entails cumulative cationic (Mn+→M(n+1)+) and anionic (O2-→O22-) reversible redox processes, owing to the d-sp hybridization associated with a reductive coupling mechanism. Because Li2MO3 is a large family of compounds, this study opens the door to the exploration of a vast number of high-capacity materials.

High rates of relapse in adolescents crack users after inpatient clinic discharge

Directory of Open Access Journals (Sweden)

Rosemeri Siqueira Pedroso

Full Text Available ABSTRACT Objective The objective of the present study was to evaluate 88 adolescent crack users referred to hospitalization and to follow them up after discharge to investigate relapse and factors associated with treatment. Methods Cohort (30 and 90 days after discharge from a psychiatric hospital and a rehab clinic for treatment for chemical dependency in Porto Alegre between 2011 and 2012. Instruments: Semi-structured interview, conducted to evaluate the sociodemographic profile of the sample and describe the pattern of psychoactive substance use; Crack Use Relapse Scale/CURS; Questionnaire Tracking Users to Crack/QTUC; K-SADS-PL. Results In the first follow-up period (30 days after discharge, 65.9% of participants had relapsed. In the second follow-up period (90 days after discharge, 86.4% of participants had relapsed. Conclusion This is one of the first studies that show the extremely high prevalence of early relapse in adolescent crack users after discharge, questioning the cost/benefit of inpatient treatment for this population. Moreover, these results corroborate studies which suggested, young psychostimulants users might need tailored intensive outpatient treatment with contingency management and other behavioral strategies, in order to increase compliance and reduce drug or crime relapse, but this specific therapeutic modality is still scarce and must be developed in Brazil.

Process for the generation of high capacity pulses from an inductive energy storage device

International Nuclear Information System (INIS)

Maier, F.; Maier, S.

1984-01-01

An inductive storage circuit for generating high voltage pulses includes a quenching circuit and a discharge circuit each connected in parallel with a storage inductor. One branch of the quenching circuit includes a quenching capacitor and one branch of the discharge circuit includes a resistor and a diode in series. These two branches have a common junction, to which is connected a quenching thyristor that forms the second branch of each of the quenching and discharge circuits. Thus, the quenching thyristor is in series with each of the quenching capacitor and the discharge resistor

Charge-Discharge Properties of the Surface-Modified ZrNi Alloy Electrode with Different Degrees of Boiling Alkaline Treatment

Directory of Open Access Journals (Sweden)

Akihiro Matsuyama

2016-09-01

Full Text Available Charge-discharge properties of the surface-modified ZrNi negative electrodes with different degrees of boiling alkaline treatment were investigated. The boiling alkaline treatment was performed by immersing the ZrNi electrode in a boiling 6 M KOH aqueous solution for 2 h or 4 h. The initial discharge capacity for the untreated ZrNi negative electrode was 21 mAh·g−1, but it was increased to 114 mAh·g−1 and 308 mAh·g−1 after the boiling alkaline treatments for 2 h and 4 h, respectively. The discharge capacity for the ZrNi negative electrode after the treatment for 2 h steadily increased with repeating charge-discharge cycles as well as that of the untreated electrode, whereas that for the ZrNi negative electrode after the 4 h treatment greatly decreased. The high rate of dischargeability was improved with an increase in the treatment period of time, and the charge-transfer resistance was drastically decreased. Scanning electron microscopy (SEM and electron dispersive X-ray spectroscopy demonstrated the ZrO2 passive layer on the ZrNi alloy surface was removed by the boiling alkaline treatment to form a porous morphology containing Ni(OH2, which can be reduced to Ni during charging, leading to the reduction of a barrier for the charge-discharge reactions.

High-k shallow traps observed by charge pumping with varying discharging times

Energy Technology Data Exchange (ETDEWEB)

Ho, Szu-Han; Chen, Ching-En; Tseng, Tseung-Yuen [Department of Electronics Engineering, National Chiao Tung University, Hsinchu 300, Taiwan (China); Chang, Ting-Chang, E-mail: tcchang@mail.phys.nsysu.edu.tw [Department of Physics, National Sun Yat-Sen University, Kaohsiung 804, Taiwan (China); Advanced Optoelectronics Technology Center, National Cheng Kung University, Tainan, Taiwan (China); Lu, Ying-Hsin; Lo, Wen-Hung; Tsai, Jyun-Yu; Liu, Kuan-Ju [Department of Physics, National Sun Yat-Sen University, Kaohsiung 804, Taiwan (China); Wang, Bin-Wei; Cao, Xi-Xin [Department of Embedded System Engineering, Peking University, Beijing, P.R.China (China); Chen, Hua-Mao [Department of Photonics and Institute of Electro-Optical Engineering, National Chiao Tung University, Hsinchu, Taiwan (China); Cheng, Osbert; Huang, Cheng-Tung; Chen, Tsai-Fu [Device Department, United Microelectronics Corporation, Tainan Science Park, Taiwan (China)

2013-11-07

In this paper, we investigate the influence of falling time and base level time on high-k bulk shallow traps measured by charge pumping technique in n-channel metal-oxide-semiconductor field-effect transistors with HfO{sub 2}/metal gate stacks. N{sub T}-V{sub high} {sub level} characteristic curves with different duty ratios indicate that the electron detrapping time dominates the value of N{sub T} for extra contribution of I{sub cp} traps. N{sub T} is the number of traps, and I{sub cp} is charge pumping current. By fitting discharge formula at different temperatures, the results show that extra contribution of I{sub cp} traps at high voltage are in fact high-k bulk shallow traps. This is also verified through a comparison of different interlayer thicknesses and different Ti{sub x}N{sub 1−x} metal gate concentrations. Next, N{sub T}-V{sub high} {sub level} characteristic curves with different falling times (t{sub falling} {sub time}) and base level times (t{sub base} {sub level}) show that extra contribution of I{sub cp} traps decrease with an increase in t{sub falling} {sub time}. By fitting discharge formula for different t{sub falling} {sub time}, the results show that electrons trapped in high-k bulk shallow traps first discharge to the channel and then to source and drain during t{sub falling} {sub time}. This current cannot be measured by the charge pumping technique. Subsequent measurements of N{sub T} by charge pumping technique at t{sub base} {sub level} reveal a remainder of electrons trapped in high-k bulk shallow traps.

Reduced Graphene Oxide-Wrapped FeS2 Composite as Anode for High-Performance Sodium-Ion Batteries

Science.gov (United States)

Wang, Qinghong; Guo, Can; Zhu, Yuxuan; He, Jiapeng; Wang, Hongqiang

2018-06-01

Iron disulfide is considered to be a potential anode material for sodium-ion batteries due to its high theoretical capacity. However, its applications are seriously limited by the weak conductivity and large volume change, which results in low reversible capacity and poor cycling stability. Herein, reduced graphene oxide-wrapped FeS2 (FeS2/rGO) composite was fabricated to achieve excellent electrochemical performance via a facile two-step method. The introduction of rGO effectively improved the conductivity, BET surface area, and structural stability of the FeS2 active material, thus endowing it with high specific capacity, good rate capability, as well as excellent cycling stability. Electrochemical measurements show that the FeS2/rGO composite had a high initial discharge capacity of 1263.2 mAh g-1 at 100 mA g-1 and a high discharge capacity of 344 mAh g-1 at 10 A g-1, demonstrating superior rate performance. After 100 cycles at 100 mA g-1, the discharge capacity remained at 609.5 mAh g-1, indicating the excellent cycling stability of the FeS2/rGO electrode.

Diffuse mode and diffuse-to-filamentary transition in a high pressure nanosecond scale corona discharge under high voltage

International Nuclear Information System (INIS)

Tardiveau, P; Moreau, N; Bentaleb, S; Postel, C; Pasquiers, S

2009-01-01

The dynamics of a point-to-plane corona discharge induced in high pressure air under nanosecond scale high overvoltage is investigated. The electrical and optical properties of the discharge can be described in space and time with fast and precise current measurements coupled to gated and intensified imaging. Under atmospheric pressure, the discharge exhibits a diffuse pattern like a multielectron avalanche propagating through a direct field ionization mechanism. The diffuse regime can exist since the voltage rise time is much shorter than the characteristic time of the field screening effects, and as long as the local field is higher than the critical ionization field in air. As one of these conditions is not fulfilled, the discharge turns into a multi-channel regime and the diffuse-to-filamentary transition strongly depends on the overvoltage, the point-to-plane gap length and the pressure. When pressure is increased above atmospheric pressure, the diffuse stage and its transition to streamers seem to satisfy similarity rules as the key parameter is the reduced critical ionization field only. However, above 3 bar, neither diffuse avalanche nor streamer filaments are observed but a kind of streamer-leader regime, due to the fact that mechanisms such as photoionization and heat diffusion are not similar to pressure.

Investigation of Peculiarities of a High-Voltage Pulsing Corona Discharge in Carbonic Gas and an Feature Using of Such Discharge for CO2 Dissociation

International Nuclear Information System (INIS)

Berezina, G.P.; Mirny, V.I.; Omelaenko, O.L.; Us, V.S.

2006-01-01

On laboratory stand of plasmochemical reactor the feature of CO 2 dissociation with the purpose of CO production in high-voltage pulsing corona discharge is investigated at a voltage up to 120 kV, a pulse length of a current 0,5 μs a repetition rate up to 100 Hz. Peculiarities of volt-ampere characteristics of such discharge are studied at different pressures of air and carbonic gas in the discharge chamber and construction of an interior electrode. It is established that in conditions of the carried out experiments a maximum efficiency of CO accretion does not exceed 3,5%

The Effect of High-Pressure Arc Discharge Plasma on the Degradation of Chlorpyrifos

International Nuclear Information System (INIS)

Yin Meiqiang; Ma Tengcai; Zhang Jialiang; Huang Mingjing; Ma Buzhou

2006-01-01

A study is conducted to determine the effect of a kind of high-pressure arc discharge plasma on the degradation rate and kinetic equations of chlorpyrifos in different solvents with the treated times and concentrations as variables. The degradation rate was sorted in different solvents as water, methanol, acetone and then acetoacetate. The tendencies of the degradation rates with treated time in water and methanol were optimally fitted with first-order kinetics equations while those in acetone and acetoacetate were fitted with zeroth-order kinetics equations. The difference was attributed to the stronger polarity of water and methanol. The weak correlation of the degradation rates with time was mainly because the high-temperature of the arc discharge tube and the chemically-active species generated by the discharge. The degradation half-life was extended with increase of chlorpyrifos concentration. A degradation half-life less than 3 min was achieved for chlorpyrifos in water and methanol when the initial concentration was less than 300 μg/ml

Axial segregation in high intensity discharge lamps measured by laser absorption spectroscopy

NARCIS (Netherlands)

Flikweert, A.J.; Nimalasuriya, T.; Groothuis, C.H.J.M.; Kroesen, G.M.W.; Stoffels, W.W.

2005-01-01

High intensity discharge lamps have a high efficiency. These lamps contain rare-earth additives (in our case dysprosium iodide) which radiate very efficiently. A problem is color separation in the lamp because of axial segregation of the rare-earth additives, caused by diffusion and convection. Here

CARS diagnostics of high pressure discharges

International Nuclear Information System (INIS)

Uhlenbusch, J.

2001-01-01

After a short description of the principles of the CARS, RECARS and POLCARS techniques and a discussion of setups for CARS experiments some experimental results are summarized. The results concern mainly plasma under atmospheric pressure, in particular the determination of temperature in a CO 2 laser-induced pyrolysis flame burning in a silane-acetylene gas mixture, the measurements of N 2 vibrational and rotational temperatures as well as the electron density by CARS and of an NO minority by POLCARS in an atmospheric microwave discharge, and finally RECARS experiments on indium iodide, Which is present in metal halide discharge lamps. Guided by these examples some problems and difficulties arising when performing CARS measurements are discussed

Completion of a high efficiency ultralarge capacity three-phase transformer

International Nuclear Information System (INIS)

Maejima, Masaaki; Maruyama, Katsuya; Fukuda, Teruo.

1986-01-01

As for the boosting transformers for thermal and nuclear power stations, at present the ultralarge capacity transformers of 1000 - 1200 MVA class are the main, and particularly in nuclear power, accompanying the development of improved type BWRs and the rise of system stability, there is the tendency toward further large capacity and large size. Consequently, reflecting the recent rise of energy cost, the demand of energy conservation and the reduction of required sites heightened largely as well as the high reliability. In order to meet these demands, Hitachi Ltd. has established the technology of changing to iron machines such as ultralarge iron cores and ultralarge capacity undivided disk windings using the latest design and manufacture techniques were applied to the 525 kV, 1200 MVA transformer for No.4 plant in Fukushima No.2 Nuclear Power Station, Tokyo Electric Power Co., Inc., thus a three-phase transformer of the highest level, high efficiency and ultralarge capacity was completed. In this paper, the outline of this transformer and the test for verifying its reliability are described. The technical change of large capacity three-phase transformers, the specifications, construction, manufacture, reliability test and the effect of modification of this transformer, and the expansion of application to the next generation ultralarge capacity transformers are reported. (Kako, I.)

Spent nuclear fuel discharges from US reactors 1993

International Nuclear Information System (INIS)

1995-02-01

The Energy Information Administration (EIA) of the U.S. Department of Energy (DOE) administers the Nuclear Fuel Data Survey, Form RW-859. This form is used to collect data on fuel assemblies irradiated at commercial nuclear reactors operating in the United States, and the current inventories and storage capacities of those reactors. These data are important to the design and operation of the equipment and facilities that DOE will use for the future acceptance, transportation, and disposal of spent fuels. The data collected and presented identifies trends in burnup, enrichment, and spent nuclear fuel discharged form commercial light-water reactor as of December 31, 1993. The document covers not only spent nuclear fuel discharges; but also site capacities and inventories; canisters and nonfuel components; and assembly type characteristics

Prediction of lithium-ion battery capacity with metabolic grey model

International Nuclear Information System (INIS)

Chen, Lin; Lin, Weilong; Li, Junzi; Tian, Binbin; Pan, Haihong

2016-01-01

Given the popularity of Lithium-ion batteries in EVs (electric vehicles), predicting the capacity quickly and accurately throughout a battery's full life-time is still a challenging issue for ensuring the reliability of EVs. This paper proposes an approach in predicting the varied capacity with discharge cycles based on metabolic grey theory and consider issues from two perspectives: 1) three metabolic grey models will be presented, including MGM (metabolic grey model), MREGM (metabolic Residual-error grey model), and MMREGM (metabolic Markov-residual-error grey model); 2) the universality of these models will be explored under different conditions (such as various discharge rates and temperatures). Furthermore, the research findings in this paper demonstrate the excellent performance of the prediction depending on the three models; however, the precision of the MREGM model is inferior compared to the others. Therefore, we have obtained the conclusion in which the MGM model and the MMREGM model have excellent performances in predicting the capacity under a variety of load conditions, even using few data points for modeling. Also, the universality of the metabolic grey prediction theory is verified by predicting the capacity of batteries under different discharge rates and different temperatures. - Highlights: • The metabolic mechanism is introduced in a grey system for capacity prediction. • Three metabolic grey models are presented and studied. • The universality of these models under different conditions is assessed. • A few data points are required for predicting the capacity with these models.

Role of secondary emission on discharge dynamics in an atmospheric pressure dielectric barrier discharge

Energy Technology Data Exchange (ETDEWEB)

Tay, W. H.; Kausik, S. S.; Yap, S. L.; Wong, C. S., E-mail: cswong@um.edu.my [Plasma Technology Research Centre, Department of Physics, Faculty of Science, University of Malaya, 50603 Kuala Lumpur (Malaysia)

2014-04-15

The discharge dynamics in an atmospheric pressure dielectric barrier discharge (DBD) is studied in a DBD reactor consisting of a pair of stainless steel parallel plate electrodes. The DBD discharge has been generated by a 50 Hz ac high voltage power source. The high-speed intensified charge coupled device camera is used to capture the images of filaments occurring in the discharge gap. It is observed that frequent synchronous breakdown of micro discharges occurs across the discharge gap in the case of negative current pulse. The experimental results reveal that secondary emissions from the dielectric surface play a key role in the synchronous breakdown of plasma filaments.

Rotational and magnetic shear stabilization of magnetohydrodynamic modes and turbulence in DIII-D high performance discharges

International Nuclear Information System (INIS)

Lao, L.L.; Burrell, K.H.; Casper, T.S.

1996-08-01

The confinement and the stability properties of the DIII-D tokamak high performance discharges are evaluated in terms of rotational and magnetic shear with emphasis on the recent experimental results obtained from the negative central magnetic shear (NCS) experiments. In NCS discharges, a core transport barrier is often observed to form inside the NCS region accompanied by a reduction in core fluctuation amplitudes. Increasing negative magnetic shear contributes to the formation of this core transport barrier, but by itself is not sufficient to fully stabilize the toroidal drift mode (trapped- electron-η i mode) to explain this formation. Comparison of the Doppler shift shear rate to the growth rate of the η i mode suggests that the large core E x B flow shear can stabilize this mode and broaden the region of reduced core transport . Ideal and resistive stability analysis indicates the performance of NCS discharges with strongly peaked pressure profiles is limited by the resistive interchange mode to low Β N < 2.3. This mode is insensitive to the details of the rotational and the magnetic shear profiles. A new class of discharges which has a broad region of weak or slightly negative magnetic shear (WNS) is described. The WNS discharges have broader pressure profiles and higher values than the NCS discharges together with high confinement and high fusion reactivity

Colloidal silica films for high-capacity DNA arrays

Science.gov (United States)

Glazer, Marc Irving

The human genome project has greatly expanded the amount of genetic information available to researchers, but before this vast new source of data can be fully utilized, techniques for rapid, large-scale analysis of DNA and RNA must continue to develop. DNA arrays have emerged as a powerful new technology for analyzing genomic samples in a highly parallel format. The detection sensitivity of these arrays is dependent on the quantity and density of immobilized probe molecules. We have investigated substrates with a porous, "three-dimensional" surface layer as a means of increasing the surface area available for the synthesis of oligonucleotide probes, thereby increasing the number of available probes and the amount of detectable bound target. Porous colloidal silica films were created by two techniques. In the first approach, films were deposited by spin-coating silica colloid suspensions onto flat glass substrates, with the pores being formed by the natural voids between the solid particles (typically 23nm pores, 35% porosity). In the second approach, latex particles were co-deposited with the silica and then pyrolyzed, creating films with larger pores (36 nm), higher porosity (65%), and higher surface area. For 0.3 mum films, enhancements of eight to ten-fold and 12- to 14-fold were achieved with the pure silica films and the films "templated" with polymer latex, respectively. In gene expression assays for up to 7,000 genes using complex biological samples, the high-capacity films provided enhanced signals and performed equivalently or better than planar glass on all other functional measures, confirming that colloidal silica films are a promising platform for high-capacity DNA arrays. We have also investigated the kinetics of hybridization on planar glass and high-capacity substrates. Adsorption on planar arrays is similar to ideal Langmuir-type adsorption, although with an "overshoot" at high solution concentration. Hybridization on high-capacity films is

Effect of secondary electron emission on subnanosecond breakdown in high-voltage pulse discharge

Science.gov (United States)

Schweigert, I. V.; Alexandrov, A. L.; Gugin, P.; Lavrukhin, M.; Bokhan, P. A.; Zakrevsky, Dm E.

2017-11-01

The subnanosecond breakdown in open discharge may be applied for producing superfast high power switches. Such fast breakdown in high-voltage pulse discharge in helium was explored both in experiment and in kinetic simulations. The kinetic model of electron avalanche development was developed using PIC-MCC technique. The model simulates motion of electrons, ions and fast helium atoms, appearing due to ions scattering. It was shown that the mechanism responsible for ultra-fast breakdown development is the electron emission from cathode. The photoemission and emission by ions or fast atoms impact is the main reason of current growth at the early stage of breakdown, but at the final stage, when the voltage on discharge gap drops, the secondary electron emission (SEE) is responsible for subnanosecond time scale of current growth. It was also found that the characteristic time of the current growth τS depends on the SEE yield of the cathode material. Three types of cathode material (titanium, SiC, and CuAlMg-alloy) were tested. It is shown that in discharge with SiC and CuAlMg-alloy cathodes (which have enhanced SEE) the current can increase with a subnanosecond characteristic time as small as τS = 0.4 ns, for the pulse voltage amplitude of 5- 12 kV..

Capacitor discharge engineering

CERN Document Server

Früngel, Frank B A

1976-01-01

High Speed Pulse Technology, Volume III: Capacitor Discharge Engineering covers the production and practical application of capacitor dischargers for the generation and utilization of high speed pulsed of energy in different forms. This nine-chapter volume discusses the principles of electric current, voltage, X-rays, gamma rays, heat, beams of electrons, neutrons and ions, magnetic fields, sound, and shock waves in gases and liquids. Considerable chapters consider the applications of capacitor discharges, such as impulse hardening of steel, ultrapulse welding of precision parts, X-ray flash t

Calculation of radiation losses in cylinder symmetric high pressure discharges by means of a digital computer

International Nuclear Information System (INIS)

Andriessen, F.J.; Boerman, W.; Holtz, I.F.E.M.

1973-08-01

Computer calculations have been made of radiative energy losses in a cylindrically symmetric high pressure discharge. The calculations show that the radiation losses which occur in discharges at pressures of a few atmospheres and central temperatures of about 20000degK when compared with the electrical energy supplied, are only of importance in the neighbourhood of the centre of discharge

High-voltage electrode optimization towards uniform surface treatment by a pulsed volume discharge

International Nuclear Information System (INIS)

Ponomarev, A V; Pedos, M S; Scherbinin, S V; Mamontov, Y I; Ponomarev, S V

2015-01-01

In this study, the shape and material of the high-voltage electrode of an atmospheric pressure plasma generation system were optimised. The research was performed with the goal of achieving maximum uniformity of plasma treatment of the surface of the low-voltage electrode with a diameter of 100 mm. In order to generate low-temperature plasma with the volume of roughly 1 cubic decimetre, a pulsed volume discharge was used initiated with a corona discharge. The uniformity of the plasma in the region of the low-voltage electrode was assessed using a system for measuring the distribution of discharge current density. The system's low-voltage electrode - collector - was a disc of 100 mm in diameter, the conducting surface of which was divided into 64 radially located segments of equal surface area. The current at each segment was registered by a high-speed measuring system controlled by an ARM™-based 32-bit microcontroller. To facilitate the interpretation of results obtained, a computer program was developed to visualise the results. The program provides a 3D image of the current density distribution on the surface of the low-voltage electrode. Based on the results obtained an optimum shape for a high-voltage electrode was determined. Uniformity of the distribution of discharge current density in relation to distance between electrodes was studied. It was proven that the level of non-uniformity of current density distribution depends on the size of the gap between electrodes. Experiments indicated that it is advantageous to use graphite felt VGN-6 (Russian abbreviation) as the material of the high-voltage electrode's emitting surface. (paper)

An all-fiber partial discharge monitoring system based on both intrinsic fiber optic interferometry sensor and fluorescent fiber

Science.gov (United States)

Yin, Zelin; Zhang, Ruirui; Tong, Jie; Chen, Xi

2013-12-01

Partial discharges (PDs) are an electrical phenomenon that occurs within a transformer whenever the voltage stress is sufficient to produce ionization in voids or inclusions within a solid dielectric, at conductor/dielectric interfaces, or in bubbles within liquid dielectrics such as oil; high-frequency transient current discharges will then appear repeatedly and will progressively deteriorate the insulation, ultimately leading to breakdown. Fiber sensor has great potential on the partial discharge detection in high-voltage equipment for its immunity to electromagnetic interference and it can take direct measurement in the high voltage equipment. The energy released in PDs produces a number of effects, resulting in flash, chemical and structural changes and electromagnetic emissions and so on. Acoustic PD detection is based on the mechanical pressure wave emitted from the discharge and fluorescent fiber PD detection is based on the emitted light produced by ionization, excitation and recombination processes during the discharge. Both of the two methods have the shortage of weak anti-interference capacity in the physical environment, like thunder or other sound source. In order to avoid the false report, an all-fiber combined PD detection system of the two methods is developed in this paper. In the system the fluorescent fiber PD sensor is considered as a reference signal, three F-P based PD detection sensors are used to both monitor the PD intensity and calculate the exact position of the discharge source. Considering the wave band of the F-P cavity and the fluorescent probe are quite different, the reflection spectrum of the F-P cavity is in the infrared region, however the fluorescent probe is about 600nm to 700nm, thus the F-P sensor and fluorescent fiber probe can be connected in one fiber and the reflection light can be detected by two different detectors without mutual interference. The all-fiber partial discharge monitoring system not only can detect the PDs

Reassembling and testing of a high-precision heat capacity drop calorimeter. Heat capacity of some polyphenyls at T = 298.15 K

Energy Technology Data Exchange (ETDEWEB)

Santos, Luis M.N.B.F., E-mail: lbsantos@fc.up.pt [Centro de Investigacao em Quimica, Departamento de Quimica e Bioquimica, Faculdade de Ciencias, Universidade do Porto, Rua do Campo Alegre, 687, 4169-007 Porto (Portugal); Rocha, Marisa A.A.; Rodrigues, Ana S.M.C. [Centro de Investigacao em Quimica, Departamento de Quimica e Bioquimica, Faculdade de Ciencias, Universidade do Porto, Rua do Campo Alegre, 687, 4169-007 Porto (Portugal); Stejfa, Vojtech; Fulem, Michal [Department of Physical Chemistry, Institute of Chemical Technology, Technicka 5, CZ-166 28 Prague 6 (Czech Republic); Bastos, Margarida [Centro de Investigacao em Quimica, Departamento de Quimica e Bioquimica, Faculdade de Ciencias, Universidade do Porto, Rua do Campo Alegre, 687, 4169-007 Porto (Portugal)

2011-12-15

Graphical abstract: Highlights: > We present the reassembling, improvement and testing of a high-precision C{sub p} drop calorimeter. > The apparatus was tested, using benzoic acid and hexafluorobenzene. > The high sensitivity of the apparatus is comparable to the one obtained in adiabatic calorimetry. > Heat capacities at T = 298.15 K of some polyphenyls were measured. > Subtle heat capacity differences among position isomers (ortho, meta, para) were detected. - Abstract: The description of the reassembling and testing of a twin heat conduction, high-precision, drop microcalorimeter for the measurement of heat capacities of small samples are presented. The apparatus, originally developed and used at the Thermochemistry Laboratory, Lund, Sweden, has now been reassembled and modernized, with changes being made as regarding temperature sensors, electronics and data acquisition system. The apparatus was thereafter thoroughly tested, using benzoic acid and hexafluorobenzene as test substances. The accuracy of the C{sub p,m}{sup 0} (298.15 K) data obtained with this apparatus is comparable to that achieved by high-precision adiabatic calorimetry. Here we also present the results of heat capacity measurements on of some polyphenyls (1,2,3-triphenylbenzene, 1,3,5-triphenylbenzene, p-terphenyl, m-terphenyl, o-terphenyl, p-quaterphenyl) at T = 298.15 K, measured with the renewed high precision heat capacity drop calorimeter system. The high resolution and accuracy of the obtained heat capacity data enabled differentiation among the ortho-, meta-, and para-phenyl isomers.

A high-capacity, low-cost layered sodium manganese oxide material as cathode for sodium-ion batteries.

Science.gov (United States)

Guo, Shaohua; Yu, Haijun; Jian, Zelang; Liu, Pan; Zhu, Yanbei; Guo, Xianwei; Chen, Mingwei; Ishida, Masayoshi; Zhou, Haoshen

2014-08-01

A layered sodium manganese oxide material (NaMn3 O5 ) is introduced as a novel cathode materials for sodium-ion batteries. Structural characterizations reveal a typical Birnessite structure with lamellar stacking of the synthetic nanosheets. Electrochemical tests reveal a particularly large discharge capacity of 219 mAh g(-1) in the voltage rang of 1.5-4.7 V vs. Na/Na(+) . With an average potential of 2.75 V versus sodium metal, layered NaMn3 O5 exhibits a high energy density of 602 Wh kg(-1) , and also presents good rate capability. Furthermore, the diffusion coefficient of sodium ions in the layered NaMn3 O5 electrode is investigated by using the galvanostatic intermittent titration technique. The results greatly contribute to the development of room-temperature sodium-ion batteries based on earth-abundant elements. © 2014 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

Demonstration of high performance negative central magnetic shear discharges on the DIII-D tokamak

International Nuclear Information System (INIS)

Rice, B.W.; Burrell, K.H.; Lao, L.L.

1996-01-01

Reliable operation of discharges with negative central magnetic shear has led to significant increases in plasma performance and reactivity in both low confinement, L-mode, and high confinement, H-mode, regimes in the DIII-D tokamak. Using neutral beam injection early in the initial current ramp, a large range of negative shear discharges have been produced with durations lasting up to 3.2 s. The total non- inductive current (beam plus bootstrap) ranges from 50% to 80% in these discharges. In the region of shear reversal, significant peaking of the toroidal rotation [f φ ∼ 30-60 kHz] and ion temperature [T i (0) ∼ 15-22 keV] profiles are observed. In high power discharges with an L-mode edge, peaked density profiles are also observed. Confinement enhancement factors up to H ≡ τ E /τ ITER-89P ∼ 2.5 with an L-mode edge, and H ∼ 3.3 in an Edge Localized Mode (ELM)-free H-mode, are obtained. Transport analysis shows both ion thermal diffusivity and particle diffusivity to be near or below standard neoclassical values in the core. Large pressure peaking in L- mode leads to high disruptivity with Β N ≡ Β T /(I/aB) ≤ 2.3, while broader pressure profiles in H- mode gives low disruptivity with Β N ≤ 4.2

Response surface method optimization of V-shaped fin assisted latent heat thermal energy storage system during discharging process

Directory of Open Access Journals (Sweden)

Sina Lohrasbi

2016-09-01

Full Text Available Latent Heat Thermal Energy Storage Systems (LHTESS containing Phase Change Material (PCM are used to establish balance between energy supply and demand. PCMs have high latent heat but low thermal conductivity, which affects their heat transfer performance. In this paper, a novel fin array has been optimized by multi-objective Response Surface Method (RSM based on discharging process of PCM, and then this fin configuration is applied on LHTESS, and comparison between full discharging time by applying this fin array and LHTESS with other fin structures has been carried out. The employed numerical method in this paper is Standard Galerkin Finite Element Method. Adaptive grid refinement is used to solve the equations. Since the enhancement technique, which has been employed in the present study reduces the employed PCM mass, maximum energy storage capacity variations have been considered. Therefore phase change expedition and maximum energy storage capacity have been considered as the objectives of optimization and the importance of second objective is indicated which is proposed as the novelty here. Results indicate that considering maximum energy storage capacity as the objective of optimization procedure leads to efficient shape design of LHTESS. Also employing optimized V-shaped fin in LHTESS, expedites discharging process considerably in comparison with the LHTESS without fin.

Development of a method of partial discharge detection in extra-high voltage cross-linked polyethylene insulated cable lines

International Nuclear Information System (INIS)

Katsuta, G.; Toya, A.; Muraoka, K.; Endoh, T.; Sekii, Y.; Ikeda, C.

1992-01-01

This paper reports that deterioration in the insulation performance of extra-high voltage XLPE cables is believed to be attributable to the deterioration caused by partial discharges. In the authors study, after using an XLPE cable to investigate the behavior of partial discharges under various adverse conditions, we succeeded in developing a highly sensitive new method of measuring partial discharge in XLPE cable lines. Partial discharges in a 275 kV XLPE cable live line has been measured using this newly developed method. As a result, a detection sensitivity of 1 pC has been achieved

Ignition of mercury-free high intensity discharge lamps

International Nuclear Information System (INIS)

Czichy, M; Mentel, J; Awakowicz, P; Hartmann, T

2008-01-01

To achieve a better understanding of the ignition behaviour of D4 lamps for automotive headlights the ignition of mercury-free metal iodide test lamps characterized by a high xenon pressure, a small electrode distance and small electrode-wall distances is investigated. The ignition of these lamps is dominated by a high voltage requirement. Nevertheless lamps are found that show a surprisingly low ignition voltage. Electrical measurements and simultaneous optical observations of the ultra-fast streamer processes show that the breakdown takes place in two different modes. One of the ignition modes which requires a high ignition voltage is characterized by a breakdown in the volume between the electrode tips. The other mode is characterized by streamer discharges along the wall. In this case the cathode, its base and the wall around is involved in the ignition process and the lamp breaks down at low voltages

The energy spectrum of the 'runaway' electrons from a high voltage pulsed discharge

International Nuclear Information System (INIS)

Ruset, C.

1985-01-01

Some experimental results are presented on the influence of the pressure upon the energy spectrum of the runaway electrons generated into a pulsed high voltage argon discharge. These electrons enter a state of continuous acceleration between two collisions with rapidly increasing free path. The applied discharge current varies from 10 to 300 A, the pulse time is about 800 ns. Relativistic effects are taken into consideration. Theoretical explanation is based on the pnenomenon of electron spreading on plasma oscillations. (D.Gy.)

The formation of ozone and UV radiation from high-power pulsed electric discharges

Science.gov (United States)

Piskarev, I. M.; Ushkanov, V. A.; Selemir, V. D.; Spirov, G. M.; Malevannaya Pikar', I. A.; Zuimach, E. A.

2008-09-01

High-power electric discharges with pulse energies of from 0.15 J to 4 kJ were studied. The yields of UV photons and ozone were found to be approximately equal, which led us to conclude that discharge conditions under which UV radiation and ozone fully destroyed each other were possible. If ozone formation was suppressed, as when a negative volume charge was created in the spark gap region, the flux of UV photons reached 3 × 1023 photons/(cm2 s).

The influence of Lampblack on capacity retention in Pb/PbSO/sub 4/ electrodes with forced flow of electrolyte

Energy Technology Data Exchange (ETDEWEB)

Borger, W.; Hullmeine, U.

1984-10-01

High active material utilization of Pb/PbSO/sub 4/ electrodes after formation in the range of 170 - 120 Ah/kg is obtained when these electrodes are discharged at 50-200 A/kg current density with forced flow of electrolyte. Decline of capacity was observed on further cycling at high current density and forced flow of electrolyte. The extent of capacity decline in these electrodes is largely influenced by the amount of additives in the active material, e.g. lampblack and expander.

Kinetics of charged particles in a high-voltage gas discharge in a nonuniform electrostatic field

Energy Technology Data Exchange (ETDEWEB)

Kolpakov, V. A., E-mail: kolpakov683@gmail.com; Krichevskii, S. V.; Markushin, M. A. [Korolev Samara National Research University (Russian Federation)

2017-01-15

A high-voltage gas discharge is of interest as a possible means of generating directed flows of low-temperature plasma in the off-electrode space distinguished by its original features [1–4]. We propose a model for calculating the trajectories of charges particles in a high-voltage gas discharge in nitrogen at a pressure of 0.15 Torr existing in a nonuniform electrostatic field and the strength of this field. Based on the results of our calculations, we supplement and refine the extensive experimental data concerning the investigation of such a discharge published in [1, 2, 5–8]; good agreement between the theory and experiment has been achieved. The discharge burning is initiated and maintained through bulk electron-impact ionization and ion–electron emission. We have determined the sizes of the cathode surface regions responsible for these processes, including the sizes of the axial zone involved in the discharge generation. The main effect determining the kinetics of charged particles consists in a sharp decrease in the strength of the field under consideration outside the interelectrode space, which allows a free motion of charges with specific energies and trajectories to be generated in it. The simulation results confirm that complex electrode systems that allow directed plasma flows to be generated at a discharge current of hundreds or thousands of milliamperes and a voltage on the electrodes of 0.3–1 kV can be implemented in practice [3, 9, 10].

Transparent hydrogel with enhanced water retention capacity by introducing highly hydratable salt

Energy Technology Data Exchange (ETDEWEB)

Bai, Yuanyuan; Xiang, Feng; Wang, Hong, E-mail: hwang@mail.xjtu.edu.cn, E-mail: suo@seas.harvard.edu [Electronic Materials Research Laboratory, School of Electronics and Information Engineering, Xi' an Jiaotong University, Xi' an 710049 (China); Chen, Baohong; Zhou, Jinxiong [State Key Laboratory for Strength and Vibration of Mechanical Structures, International Center for Applied Mechanics and School of Aerospace, Xi' an Jiaotong University, Xi' an 710049 (China); Suo, Zhigang, E-mail: hwang@mail.xjtu.edu.cn, E-mail: suo@seas.harvard.edu [School of Engineering and Applied Sciences, Kavli Institute of Bionano Science and Technology, Harvard University, Cambridge, Massachusetts 02138 (United States)

2014-10-13

Polyacrylamide hydrogels containing salt as electrolyte have been used as highly stretchable transparent electrodes in flexible electronics, but those hydrogels are easy to dry out due to water evaporation. Targeted, we try to enhance water retention capacity of polyacrylamide hydrogel by introducing highly hydratable salts into the hydrogel. These hydrogels show enhanced water retention capacity in different level. Specially, polyacrylamide hydrogel containing high content of lithium chloride can retain over 70% of its initial water even in environment with relative humidity of only 10% RH. The excellent water retention capacities of these hydrogels will make more applications of hydrogels become possible.

Transparent hydrogel with enhanced water retention capacity by introducing highly hydratable salt

International Nuclear Information System (INIS)

Bai, Yuanyuan; Xiang, Feng; Wang, Hong; Chen, Baohong; Zhou, Jinxiong; Suo, Zhigang

2014-01-01

Polyacrylamide hydrogels containing salt as electrolyte have been used as highly stretchable transparent electrodes in flexible electronics, but those hydrogels are easy to dry out due to water evaporation. Targeted, we try to enhance water retention capacity of polyacrylamide hydrogel by introducing highly hydratable salts into the hydrogel. These hydrogels show enhanced water retention capacity in different level. Specially, polyacrylamide hydrogel containing high content of lithium chloride can retain over 70% of its initial water even in environment with relative humidity of only 10% RH. The excellent water retention capacities of these hydrogels will make more applications of hydrogels become possible.

Capacity loss and faradaic efficiency of lithium thionyl chloride cells

Energy Technology Data Exchange (ETDEWEB)

Hoier, S. [Sandia National Labs., Albuquerque, NM (United States); Schlaikjer, C.; Johnson, A.; Riley, S. [Battery Engineering, Inc., Boston, MA (United States)

1996-05-01

In lithium/thionyl chloride (Li/TC) cells, a lithium limited design was thought to be safer than a cathode limited design because the amount of lithium left in discharged cells would be minimal. However, lithium corrosion reduces the capacity faster than does cathode degradation during storage. The optimization of the ratio of lithium to carbon was studied, considering storage time and temperature. The efficiency of converting chemical energy into electrical energy has been studied for the case of D cells with surface area from 45 to 345 cm{sup 2}, under constant and various pulsed loads. Microcalorimetric monitoring of the heat output during discharge allowed the direct measurement of faradaic efficiency, and showed that self discharge is far more pervasive that previously acknowledged. Typical faradaic efficiencies for constant load varied from 30% at low current density to 90% at moderate and 75 % at high current density. Pulsed current further depresses these efficiencies, except at very low average current density.

Abuse resistant high rate lithium/thionyl chloride cells

Science.gov (United States)

Surprenant, J.; Snuggerud, D.

A compact, disk shaped lithium/thionyl chloride cell has been developed. The cell has a 6 Amphr capacity and is capable of high rate discharge at high voltage. Discharge data are presented over the range of 0.07 to 1.1 amperes. The cell is operable over the temperature range of -40 C to +70 C, and has a 10 year shelf life at 20 C. Safety features allow the cells to withstand fire, puncture, shock, spin, forced discharge or forced charge without dangerous reactions.

Pulsed discharges produced by high-power surface waves

Science.gov (United States)

Böhle, A.; Ivanov, O.; Kolisko, A.; Kortshagen, U.; Schlüter, H.; Vikharev, A.

1996-02-01

The mechanisms of the ionization front advance in surface-wave-produced discharges are investigated using two experimental set-ups. The high-power surface waves are excited in a 3 cm wavelength band by a surfaguide and a novel type of launcher (an E-plane junction). The ionization front velocity of the surface wave is measured for a wide range of gas pressures, incident microwave power and initial pre-ionization. The experimental results are compared with theoretical ones based on three different models. The comparison between theory and experiment allows one to suggest a new interpretation of the ionization front's advance. The ionization front velocity is determined by a breakdown wave or an ionization wave in the electric field of a high-power surface wave in the zone near the ionization front.

Self-discharge characteristics of lithium/sulfur batteries using TEGDME liquid electrolyte

International Nuclear Information System (INIS)

Ryu, H.S.; Ahn, H.J.; Kim, K.W.; Ahn, J.H.; Cho, K.K.; Nam, T.H.

2006-01-01

We investigated self-discharge characteristics of Li/S batteries using tetra ethylene glycol dimethylether (TEGDME) electrolyte. The open circuit voltages (OCV) and discharge curves were measured as a function of storage time. The self-discharge of the Li/S battery depended on current collectors. Li/TEGDME/S batteries with stainless steel (SUS) current collector showed the highest self-discharge rate of 59% per month. The self-discharge rate of Li/TEGDME/S battery using Al current collector is 34% during initial 80 days, but only 36% after 360 days storage. The discharge capacity decreases only 2% from 80 to 360 days. The self-discharge of Li/S battery using Al current collector is severe during initial 80 days, but is not an important factor after 80 days. Average self-discharge rate of Li/TEGDME/S battery using Al current collector is 3% per month for 1 year

High rate capacity nanocomposite lanthanum oxide coated lithium zinc titanate anode for rechargeable lithium-ion battery

Energy Technology Data Exchange (ETDEWEB)

Tang, Haoqing, E-mail: tanghaoqing@tju.edu.cn [School of Materials Science and Engineering, Tianjin University, Tianjin 300072 (China); Department of Applied Chemistry, School of Chemical Engineering and Technology, Tianjin University, Tianjin 300072 (China); Zan, Lingxing [Institute of Physical and Theoretical Chemistry, University of Bonn, Bonn 53117 (Germany); Zhu, Jiangtao; Ma, Yiheng [Department of Applied Chemistry, School of Chemical Engineering and Technology, Tianjin University, Tianjin 300072 (China); Zhao, Naiqin [School of Materials Science and Engineering, Tianjin University, Tianjin 300072 (China); Tang, Zhiyuan, E-mail: zytang46@163.com [Department of Applied Chemistry, School of Chemical Engineering and Technology, Tianjin University, Tianjin 300072 (China)

2016-05-15

Lithium zinc titanate (Li{sub 2}ZnTi{sub 3}O{sub 8}) is an important titanium material of promising candidates for anode materials with superior electrochemical performance and thus has attracted extensive attention. Herein, high capacity, stable Li{sub 2}ZnTi{sub 3}O{sub 8}/La{sub 2}O{sub 3} nanocomposite for lithium-ion battery anode is prepared by a facile strategy. Compared to unmodified Li{sub 2}ZnTi{sub 3}O{sub 8}, the Li{sub 2}ZnTi{sub 3}O{sub 8}/La{sub 2}O{sub 3} electrode display a high specific capacity of 188.6 mAh g{sup −1} and remain as high as 147.7 mAh g{sup −1} after 100 cycles at 2.0 A g{sup −1}. Moreover, a reversible capacity of 76.3 mAh g{sup −1} can be obtained after 1000 cycles at 2.0 A g{sup −1} and the retention is 42.7% for Li{sub 2}ZnTi{sub 3}O{sub 8}/La{sub 2}O{sub 3}, which is much higher than un-coated Li{sub 2}ZnTi{sub 3}O{sub 8}. The superior lithium storage performances of the Li{sub 2}ZnTi{sub 3}O{sub 8}/La{sub 2}O{sub 3} can be ascribed to the stable layer of protection, small particle size and large surface area. Cyclic voltammograms result reveals that the La{sub 2}O{sub 3} coating layer reduces the polarization and improves the electrochemical activity of anode. - Highlights: • Nano layer La{sub 2}O{sub 3} coated Li{sub 2}ZnTi{sub 3}O{sub 8} particles have been prepared via a suspension mixing process followed by heat treatment. • Coated Li{sub 2}ZnTi{sub 3}O{sub 8} has enhanced high rate capability, cyclic stability and long lifespan performance. • Electrochemical properties were tested in a charge/discharge voltage range of 3.0–0.05 V (vs. Li/Li{sup +}).

Evaporation and discharge dynamics of highly charged multicomponent droplets generated by electrospray ionization.

Science.gov (United States)

Grimm, Ronald L; Beauchamp, J L

2010-01-28

We investigate the Rayleigh discharge and evaporation dynamics of highly charged two-component droplets consisting principally of methanol with 2-methoxyethanol, tert-butanol, or m-nitrobenzyl alcohol. A phase Doppler anemometer (PDA) characterizes droplets generated by electrospray ionization (ESI) according to size, velocity, and charge as they move through a uniform electric field within an ion mobility spectrometer (IMS). Repeated field reversals result in droplet "ping-pong" through the PDA. This generates individual droplet histories of solvent evaporation behavior and the dynamics of charge loss to progeny droplets during Rayleigh discharge events. On average, methanol droplets discharge at 127% their Rayleigh limit of charge, q(R), and release 25% of the net charge. Charge loss from methanol/2-methoxyethanol droplets behaves similarly to pure 2-methoxyethanol droplets which release approximately 28% of their net charge. Binary methanol droplets containing up to 50% tert-butanol discharge at a lower percent q(R) than pure methanol and release a greater fraction of their net charge. Mixed 99% methanol/1% m-nitrobenzyl alcohol droplets possess discharge characteristics similar to those of methanol. However, droplets of methanol containing 2% m-nitrobenzyl evaporate down to a fixed size and charge that remains constant with no observable discharges. Quasi-steady-state evaporation models accurately describe observed evaporation phenomena in which methanol/tert-butanol droplets evaporate at a rate similar to that of pure methanol and methanol/2-methoxyethanol droplets evaporate at a rate similar to that of 2-methoxyethanol. We compare these results to previous Rayleigh discharge experiments and discuss the implications for binary solvents in electrospray mass spectrometry (ESI-MS) and field-induced droplet ionization mass spectrometry (FIDI-MS).

NIPPLE DISCHARGE

Directory of Open Access Journals (Sweden)

T. N. Bukharova

2008-01-01

Full Text Available According to the data available in the literature, as high as 50% of women have benign breast tumors frequently accompanied by nip- ple discharge. Nipple discharge may be serous, bloody, purulent, and colostric. The most common causes are breast abscess, injury, drugs, prolactinoma, intraductal pappiloma, ductal ectasia, intraductal cancer (not more than 10%.

Volume generation of negative ions in high density hydrogen discharges

International Nuclear Information System (INIS)

Hiskes, J.R.; Karo, A.M.

1983-01-01

A parametric survey is made of a high-density tandem two-chamber hydrogen negative ion system. The optimum extracted negative ion current densities are sensitive to the atom concentration in the discharge and to the system scale length. For scale lengths ranging from 10 cm to 0.1 cm optimum current densities range from of order 1 to 100 mA cm -2 , respectively

The influence of electric discharge on the properties of high-temperature superconductors

International Nuclear Information System (INIS)

Parashchuk, V.V.

1990-01-01

The influence is studied of pulse voltage with amplitude 100 kV and duration 100 to 200 ns on the temperature dependence of diamagnetic susceptibility of yttrium ceramics. As a result of the action of spark discharge on the ceramics, the superconducting transition parameters change. As the number of voltage pulses is increased, the diamagnetic susceptibility and the critical temperature determined by it first increase rapidly, then drop slowly. At the same time the transition in the optimum becomes more sharp. In the case of treatment in the air, Tc increases by 15 K and at discharge in liquid nitrogen by 25 K. It is found that the atmospheric air under certain conditions affects the temperature dependence of the diamagnetic susceptibility of HTSC ceramics. Treatment by a high-voltage spark decreases the susceptibility of the ceramics due to atmospheric effects. The highest efficiency of spark treatment is achieved at discharge in liquid nitrogen. (orig.)

High-power CO laser with RF discharge for isotope separation employing condensation repression

Science.gov (United States)

Baranov, I. Ya.; Koptev, A. V.

2008-10-01

High-power CO laser can be the effective tool in such applications as isotope separation using the free-jet CRISLA method. The way of transfer from CO small-scale experimental installation to industrial high-power CO lasers is proposed through the use of a low-current radio-frequency (RF) electric discharge in a supersonic stream without an electron gun. The calculation model of scaling CO laser with RF discharge in supersonic stream was developed. The developed model allows to calculate parameters of laser installation and optimize them with the purpose of reception of high efficiency and low cost of installation as a whole. The technical decision of industrial CO laser for isotope separation employing condensation repression is considered. The estimated cost of laser is some hundred thousand dollars USA and small sizes of laser head give possibility to install it in any place.

3D Fe{sub 2}(MoO{sub 4}){sub 3} microspheres with nanosheet constituents as high-capacity anode materials for lithium-ion batteries

Energy Technology Data Exchange (ETDEWEB)

Zheng, Hao; Wang, Shiqiang [Hubei University, Key Laboratory for Synthesis and Applications of Organic Functional Molecules (China); Wang, Jiazhao; Wang, Jun [University of Wollongong, Institute for Superconducting and Electronic Materials (Australia); Li, Lin; Yang, Yun; Feng, Chuanqi, E-mail: cfeng@hubu.edu.cn [Hubei University, Key Laboratory for Synthesis and Applications of Organic Functional Molecules (China); Sun, Ziqi, E-mail: ziqi.sun@qut.edu.au [Queensland University of Technology, School of Chemistry, Physics and Mechanical Engineering, Science and Engineering Faculty (Australia)

2015-11-15

Three-dimensional (3D) Fe{sub 2}(MoO{sub 4}){sub 3} microspheres with ultrathin nanosheet constituents are first synthesized as anode materials for the lithium-ion battery. It is interesting that the single-crystalline nanosheets allow rapid electron/ion transport on the inside, and the high porosity ensures fast diffusion of liquid electrolyte in energy storage applications. The electrochemical properties of Fe{sub 2}(MoO{sub 4}){sub 3} as anode demonstrates that 3D Fe{sub 2}(MoO{sub 4}){sub 3} microspheres deliver an initial capacity of 1855 mAh/g at a current density of 100 mA/g. Particularly, when the current density is increased to 800 mA/g, the reversible capacity of Fe{sub 2}(MoO{sub 4}){sub 3} anode still arrived at 456 mAh/g over 50 cycles. The large and reversible capacities and stable charge–discharge cycling performance indicate that Fe{sub 2}(MoO{sub 4}){sub 3} is a promising anode material for lithium battery applications.Graphical abstractThe electrochemical properties of Fe{sub 2}(MoO{sub 4}){sub 3} as anode demonstrates that 3D Fe{sub 2}(MoO{sub 4}){sub 3} microspheres delivered an initial capacity of 1855 mAh/g at a current density of 100 mA/g. When the current density was increased to 800 mA/g, the Fe{sub 2}(MoO{sub 4}){sub 3} still behaved high reversible capacity and good cycle performance.

Lithium-manganese dioxide cells for implantable defibrillator devices - Discharge voltage models

Energy Technology Data Exchange (ETDEWEB)

Root, Michael J. [Cardiac Rhythm Management Research and Development, Boston Scientific Corp., 4100 Hamline Ave. N., St. Paul, MN 55112 (United States)

2010-08-01

The discharge potential behavior of lithium-manganese dioxide cells designed for implantable cardiac defibrillators was characterized as a function of extent of cell depletion for tests designed to discharge the cells for times between 1 and 7 years. The discharge potential curves may be separated into two segments from 0 {<=} x {<=} {proportional_to}0.51 and {proportional_to}0.51 {<=} x {<=} 1.00, where x is the dimensionless extent of discharge referenced to the rated cell capacity. The discharge potentials conform to Tafel kinetics in each segment. This behavior allows the discharge potential curves to be predicted for an arbitrary discharge load and long term discharge performance may be predicted from short term test results. The discharge potentials may subsequently be modeled by fitting the discharge curves to empirical functions like polynomials and Pade approximants. A function based on the Nernst equation that includes a term accounting for nonideal interactions between lithium ions and the cathode host material, such as the Redlich-Kister relationship, also may be used to predict discharge behavior. (author)

Integrated discharge scenario for high-temperature helical plasma on LHD

International Nuclear Information System (INIS)

Nagaoka, K.; Takahashi, H.; Murakami, S.

2014-10-01

Discharge scenario of high temperature plasma with helical configuration has been significantly progressed. The increase of central ion temperature due to reduction of wall recycling was clearly observed. The neutral particle profile was measured with a high-dynamic range of Balmer-α spectroscopy, and the reduction of neutral density was identified after helium conditioning main discharges. The peaking of ion heating profile and the reduction of charge exchange loss of energetic ions play an important role for improvement of ion heat transport in the core. The ion ITB and electron ITB have been successfully integrated due to superposition of centrally focused electron cyclotron heating to the ion ITB plasma, and the high temperature regime of T i ∼T e has been significantly extended. The normalized temperature gradient of ion and electron (R/L T ) were observed to exceed 10, indicating the significant improvement of both ion and electron heat transports at the barrier position. The positive radial electric field was observed by heavy ion beam probe, while the negative radial electric field was observed in ion ITB plasmas. The ion temperature gradient was observed to decrease with the increase of temperature ratio (T e /T i ). This experiment demonstrated that the profile control is a key to combine ion ITB and electron ITB and have a potential to improve the performance of helical plasmas. (author)

Travelling-wave-sustained discharges

International Nuclear Information System (INIS)

Schlueter, Hans; Shivarova, Antonia

2007-01-01

This review is on discharges maintained by travelling waves: new plasma sources, discovered in 1974 and considered as a prototype of the gas discharges according to their definition as nonlinear systems which unify in a self-consistent manner plasmas and fields. In the presentation here of the fluid-plasma models of the diffusion-controlled regime of the travelling-wave-sustained discharges (TWSDs), the basic features of the discharge maintenance-the discharge self-consistency and the electron heating in the high-frequency field-are stressed. Operation of stationary and pulsed discharges, discharge maintenance without and in external magnetic fields as well as discharge production in different gases (argon, helium, helium-argon gas mixtures and hydrogen) are covered. Modulation instability of diffusion-controlled discharges and discharge filamentation at higher gas pressures are also included in the review. Experimental findings which motivate aspects of the reported modelling are pointed out

Mortality after discharge from the intensive care unit during the early weekend period

DEFF Research Database (Denmark)

Obel, N; Schierbeck, J; Pedersen, L

2007-01-01

BACKGROUND: As a result of a shortage of intensive care capacity, patients may be discharged prematurely early during weekends which may lead to an increased mortality and risk of readmission to intensive care units (ICU). We examined whether discharge from the ICU during the first part...

A note on high Schmidt number laminar buoyant jets discharged horizontally

International Nuclear Information System (INIS)

Dewan, A.; Arakeri, J.H.; Srinivasan, J.

1992-01-01

This paper reports on a new model, developed for the integral analysis of high Schmidt number (or equivalently high Prandtl number) laminar buoyant jets discharged horizontally. This model assumes top-hat density profile across the inner core of jet and Gaussian velocity profile. Entrainment coefficient corresponding to pure laminar jet has been taken in the analysis. The prediction of the jet trajectory agree well with experimental data in the regions where the jet remains laminar

Free-space optical communications with peak and average constraints: High SNR capacity approximation

KAUST Repository

Chaaban, Anas; Morvan, Jean-Marie; Alouini, Mohamed-Slim

2015-01-01

. Numerical evaluation shows that this capacity lower bound is nearly tight at high signal-to-noise ratio (SNR), while it is shown analytically that the gap to capacity upper bounds is a small constant at high SNR. In particular, the gap to the high

Assessing submarine groundwater discharge (SGD) and nitrate fluxes in highly heterogeneous coastal karst aquifers: Challenges and solutions

Science.gov (United States)

Montiel, Daniel; Dimova, Natasha; Andreo, Bartolomé; Prieto, Jorge; García-Orellana, Jordi; Rodellas, Valentí

2018-02-01

Groundwater discharge in coastal karst aquifers worldwide represents a substantial part of the water budget and is a main pathway for nutrient transport to the sea. Groundwater discharge to the sea manifests under different forms, making its assessment very challenging particularly in highly heterogeneous coastal systems karst systems. In this study, we present a methodology approach to identify and quantify four forms of groundwater discharge in a mixed lithology system in southern Spain (Maro-Cerro Gordo) that includes an ecologically protected coastal area comprised of karstic marble. We found that groundwater discharge to the sea occurs via: (1) groundwater-fed creeks, (2) coastal springs, (3) diffuse groundwater seepage through seabed sediments, and (4) submarine springs. We used a multi-method approach combining tracer techniques (salinity, 224Ra, and 222Rn) and direct measurements (seepage meters and flowmeters) to evaluate the discharge. Groundwater discharge via submarine springs was the most difficult to assess due to their depth (up to 15 m) and extensive development of the springs conduits. We determined that the total groundwater discharge over the 16 km of shoreline of the study area was at least 11 ± 3 × 103 m3 d-1 for the four types of discharge assessed. Groundwater-derived nitrate (NO3-) fluxes to coastal waters over ∼3 km (or 20%) in a highly populated and farmed section of Maro-Cerro Gordo was 641 ± 166 mol d-1, or ∼75% of the total NO3- loading in the study area. We demonstrate in this study that a multi-method approach must be applied to assess all forms of SGD and derived nutrient fluxes to the sea in highly heterogeneous karst aquifer systems.

Recycling rice husks for high-capacity lithium battery anodes.

Science.gov (United States)

Jung, Dae Soo; Ryou, Myung-Hyun; Sung, Yong Joo; Park, Seung Bin; Choi, Jang Wook

2013-07-23

The rice husk is the outer covering of a rice kernel and protects the inner ingredients from external attack by insects and bacteria. To perform this function while ventilating air and moisture, rice plants have developed unique nanoporous silica layers in their husks through years of natural evolution. Despite the massive amount of annual production near 10(8) tons worldwide, so far rice husks have been recycled only for low-value agricultural items. In an effort to recycle rice husks for high-value applications, we convert the silica to silicon and use it for high-capacity lithium battery anodes. Taking advantage of the interconnected nanoporous structure naturally existing in rice husks, the converted silicon exhibits excellent electrochemical performance as a lithium battery anode, suggesting that rice husks can be a massive resource for use in high-capacity lithium battery negative electrodes.

Transparent hydrogel with enhanced water retention capacity by introducing highly hydratable salt

OpenAIRE

Bai, Yuanyuan; Chen, Baohong; Xiang, Feng; Zhou, Jinxiong; Wang, Hong; Suo, Zhigang

2014-01-01

Polyacrylamide hydrogels containing salt as electrolyte have been used as highly stretchable transparent electrodes in flexible electronics, but those hydrogels are easy to dry out due to water evaporation. Targeted, we try to enhance water retention capacity of polyacrylamide hydrogel by introducing highly hydratable salts into the hydrogel. These hydrogels show enhanced water retention capacity in different level. Specially, polyacrylamide hydrogel containing high content of lithium chlorid...

Time-dependent simulation of plasma and electrodes in high-intensity discharge lamps with different electrode shapes

CERN Document Server

Flesch, P

2003-01-01

The subject of this paper is the modelling of d.c. and a.c. high-intensity Hg-discharge lamps with differently shaped electrodes. Different arc attachments on the electrodes are studied and insight for the development of new electrodes is gained. The model includes the entire discharge plasma (plasma column, hot plasma spots in front of electrodes, near-electrode non-LTE-plasma) as well as anode and cathode. No subdivision of the discharge space into different regions is necessary (like space charge layer, ionization zone, plasma column). This is achieved by using a differential equation for a non-LTE electrical conductivity which is applicable for local thermal equilibrium (LTE-)regions as well as for non-LTE plasma regions close to the electrodes in a high pressure plasma. Modelling results for a 0.6 MPa mercury discharge considering six different electrode shapes (anode and cathode) are presented and compared with experimental results. The electrodes have different diameters and different electrode tips, s...

Abuse resistant high rate lithium/thionyl chloride cells

Energy Technology Data Exchange (ETDEWEB)

Surprenant, J.; Snuggerud, D.

1982-08-01

A compact, disc shaped lithium/thionyl chloride cell has been developed by Altus Corporation. The cell has a 6 Amphr capacity and is capable of high rate discharge at high voltage. Discharge data is presented over the range of 0.07 to 1.1 Amperes. The cell is operable over the temperature range of -40/sup 0/C to +70/sup 0/C, and has a 10 year shelf life at 20/sup 0/C. Safety features allow the cells to withstand fire, puncture, shock, spin, forced discharge or forced charge without dangerous reactions.

Influence of current and temperature on discharge characteristics of electrochemical nickel−cadmium system

Directory of Open Access Journals (Sweden)

Todorović Andreja

2010-01-01

Full Text Available The paper elaborates determination of characteristic values in the discharging process of non-hermetic nickel-cadmium galvanic battery with nominal voltage Un = 60 V and nominal capacity qn = C5 = 190 Ah and its dependence from current and temperature. Study has been performed with the set of experimental metering of voltages, electromotive force, current from discharge time range and electromotive force in steady state regime before and after battery charging. Electromotive force characteristics are obtained by using the Nernst’s equation, while the least square method was used to determine the average values of internal electrical resistivity, power losses and efficiency level. These results were used in the approximate exponential functions to determine the range dependence of the efficiency level from the internal electrical resistance of discharge current in reliance from the temperature range. Obtained results show that, in accordance to the given voltage variation of 10% Un, this type of battery holds maximal full load current of one hour capacity at the temperature of 25°C and maximal full load current of two hours capacity at the temperature of −30°C. The methodology used in the case study covers determination of the electromotive force in time range based on the metered results of values during complete battery fullness and emptiness with prior determination of equilibrium constants of galvanic battery reaction through method suggested by the author of this paper. Further process, using the electromotive force values obtained through the aforementioned process, the metered current, and approximate polynomial function of the nominal discharge voltage characteristic determines range of battery internal electric resistance from time, followed by the selection of discharge cases with average values for: voltage, electromotive force, internal electrical resistance, available and utilized power, power losses, and battery efficiency

High-capacity composite adsorbents for nucleic acids.

Science.gov (United States)

Tiainen, Peter; Rokebul Anower, M; Larsson, Per-Olof

2011-08-05

Cytopore™ is a bead-shaped, macroporous and easily compressible cellulose-based anion-exchange material intended for cultivation of anchor-dependent animal cells. Reticulated vitreous carbon (RVC) is a strong, non-compressible, high voidage (97%) matrix material that can be cut to desired geometrical shapes. Cytopore and RVC were combined to cylindrical composites (25 mm × 10 mm) fitted inside chromatography columns. The composite combined the advantageous properties of both its constituents, making it suitable for column chromatography. The composite could withstand very high flow rates without compaction of the bed (>25 column volumes/min; 4000 cm h(-1)). Chromatography runs with tracers showed a low HETP value (0.3mm), suggesting that pore flow was in operation. The dynamic binding capacities (10% breakthrough) per gram of dry weight Cytopore were determined for several compounds including DNA and RNA and were found to be 240-370 mg/g. The composite was used to isolate pUC 18-type plasmids from a cleared alkaline lysate in a good yield. Confocal microscopy studies showed that plasmids were bound not only to the surface of the Cytopore material but also within the matrix walls, thus offering an explanation to the very high binding capacities observed. The concept of using a composite prepared from a mechanically weak, high-binding material and a strong scaffold material may be applied to other systems as well. Copyright © 2011 Elsevier B.V. All rights reserved.

Heat capacity of iron, aluminum, and chromium vanadates at high temperatures

Energy Technology Data Exchange (ETDEWEB)

Cheshnitskii, S.M.; Fotiev, A.A.; Ignashin, V.P.; Kesler, Y.A.

1985-09-01

The thermodynamic characteristics of compounds participating in the processing of vanadium-containing raw materials have not been sufficiently investigated. In this paper the authors report on measurements of the heat capacities of the compounds FeVO/sub 4/, CrVO/sub 4/, AIVO/sub 4/, Fe/sub 2/V/sub 4/O/sub 13/ and FeCr(VO/sub 4/)/sub 2/ at high temperatures. The obtained experimental data on the high-temperature heat capacity of iron, aluminum, and chromium vanadates makes it possible to calculate the thermodynamic functions of these compounds at high temperatures.

Radio and television interference caused by corona discharges from high-voltage transmission lines

International Nuclear Information System (INIS)

Sarmadi, M.

1996-01-01

Increase in power utility loads in industrialized countries, as well as developing countries, demands a higher level of transmission line voltage. Radio interference (RI) problems have been determined to be a limiting factor in selecting the size of transmission line conductors. Transmission line noise is primarily caused by corona discharges in the immediate vicinity of the conductor. It has been observed that discharges occur during both half-cycles of the applied voltage, but positive corona is usually predominant at AM radio frequencies range with practical high-voltage and extra high-voltage transmission lines. The corona radio noise effect is highly dependent upon the presence of particles on the surface of the conductor and the increase of the electrical gradient beyond the breakdown value of the air. Therefore, corona radio noise varies significantly with the weather and atmospheric conditions and generally increases by 10 to 30 dB in foul weather

Estimating cell capacity for multi-cell electrical energy system

Science.gov (United States)

Hashemi, Iman Ahari

A Multi-Cell Electrical Energy System is a set of batteries that are connected in series. The series batteries provide the required voltage necessary for the contraption. After using the energy that is provided by the batteries, some cells within the system tend to have a lower voltage than the other cells. Also, other factors, such as the number of times a battery has been charged or discharged, how long it has been within the system and many other factors, result in some cells having a lesser capacity compared to the other cells within the system. The outcome is that it lowers the required capacity that the electrical energy system is required to provide. By having an unknown cell capacity within the system, it is unknown how much of a charge can be provided to the system so that the cells are not overcharged or undercharged. Therefore, it is necessary to know the cells capacity within the system. Hence, if we were dealing with a single cell, the capacity could be obtained by a full charge and discharge of the cell. In a series system that contains multiple cells a full charging or discharging cannot happen as it might result in deteriorating the structure of some cells within the system. Hence, to find the capacity of a single cell within an electrical energy system it is required to obtain a method that can estimate the value of each cell within the electrical energy system. To approach this method an electrical energy system is required. The electrical energy system consists of rechargeable non-equal capacity batteries to provide the required energy to the system, a battery management system (BMS) board to monitor the cells voltages, an Arduino board that provides the required communication to BMS board, and the PC, and a software that is able to deliver the required data obtained from the Arduino board to the PC. The outcome, estimating the capacity of a cell within a multi-cell system, can be used in many battery related technologies to obtain unknown

High-confinement NBI discharges in the W7-AS stellarator

International Nuclear Information System (INIS)

Stroth, U.; Baldzuhn, J.; Geiger, J.; Geist, T.; Giannone, L.; Hartfuss, H.-J.; Hirsch, M.; Jaenicke, R.; Kick, M.; Koponen, J.P.; Kuehner, G.; Penningsfeld, F.-P.; Wagner, F.

1998-01-01

In W7-AS, the longest energy confinement times were achieved in neutral beam injection heated (NBI-heated) discharges under low wall-recycling conditions. Low recycling is needed to control the density at line-averaged values of n-bar e approx. 10 20 m -3 . Under these conditions, confinement was improved by a factor of two above the common scaling estimate. The reduction of radial transport is concentrated into a layer at about two-thirds of the plasma radius. In this region steep pressure gradients and a strong gradient in the radial electric field develop. Specific for the discharges is the slow transition to improved confinement, lasting up to three energy confinement times. Since the measured electric field is consistent with the neoclassical ambipolar field, this high-confinement mode could be an example where sheared plasma flow as created by the neoclassical radial electric field leads to a suppression of anomalous transport. (author)

High-confinement NBI discharges in the W7-AS stellarator

Energy Technology Data Exchange (ETDEWEB)

Stroth, U; Baldzuhn, J; Geiger, J; Geist, T; Giannone, L.; Hartfuss, H -J; Hirsch, M; Jaenicke, R; Kick, M; Koponen, J P; Kuehner, G; Penningsfeld, F -P; Wagner, F [Max-Planck-Institut fuer Plasmaphysik, EURATOM Association, D-85748 Garching (Germany)

1998-08-01

In W7-AS, the longest energy confinement times were achieved in neutral beam injection heated (NBI-heated) discharges under low wall-recycling conditions. Low recycling is needed to control the density at line-averaged values of n-bar{sub e} approx. 10{sup 20}m{sup -3}. Under these conditions, confinement was improved by a factor of two above the common scaling estimate. The reduction of radial transport is concentrated into a layer at about two-thirds of the plasma radius. In this region steep pressure gradients and a strong gradient in the radial electric field develop. Specific for the discharges is the slow transition to improved confinement, lasting up to three energy confinement times. Since the measured electric field is consistent with the neoclassical ambipolar field, this high-confinement mode could be an example where sheared plasma flow as created by the neoclassical radial electric field leads to a suppression of anomalous transport. (author)

Experimental characterization of plasma formation and shockwave propagation induced by high power pulsed underwater electrical discharge.

Science.gov (United States)

Claverie, A; Deroy, J; Boustie, M; Avrillaud, G; Chuvatin, A; Mazanchenko, E; Demol, G; Dramane, B

2014-06-01

High power pulsed electrical discharges into liquids are investigated for new industrial applications based on the efficiency of controlled shock waves. We present here new experimental data obtained by combination of detailed high speed imaging equipments. It allows the visualization of the very first instants of plasma discharge formation, and then the pulsations of the gaseous bubble with an accurate timing of events. The time history of the expansion/compression of this bubble leads to an estimation of the energy effectively transferred to water during the discharge. Finally, the consecutive shock generation driven by this pulsating bubble is optically monitored by shadowgraphs and schlieren setup. These data provide essential information about the geometrical pattern and chronometry associated with the shock wave generation and propagation.

High power, high brightness electron beam generation in a pulse-line driven pseudospark discharge

International Nuclear Information System (INIS)

Destler, W.W.; Segalov, Z.; Rodgers, J.; Ramaswamy, K.; Reiser, M.

1993-01-01

High brightness (∼10 10 A/m 2 rad 2 ), high power density (∼10 10 W/cm 2 ) electron beams have been generated by the mating of a hollow-cathode discharge device operating in the pseudospark regime to the output of a high power pulse line accelerator. Very small diameter (∼1 mm) electron beams with currents in the range 500--1000 A and energies in the range 150--300 keV have been generated with effective emittances estimated to be at or below 170 mm mrad. Such emittances are comparable to those achieved in conventional electron beam sources at current densities several orders of magnitude lower than those observed in these experiments

Patterns of changes in wheelchair exercise capacity after spinal cord injury

NARCIS (Netherlands)

van Koppenhagen, C.F.; de Groot, S.; Post, M.W.; Hoekstra, T.; van Asbeck, F.W.; Bongers, H.; Lindeman, E.; van der Woude, L.H.

2013-01-01

Objectives: (1) To identify different patterns of changes in wheelchair exercise capacity in the period between the start of active spinal cord injury (SCI) rehabilitation and 5 years after discharge; (2) to examine the pattern determinants of the change in wheelchair exercise capacity. Design:

Patterns of Changes in Wheelchair Exercise Capacity After Spinal Cord Injury

NARCIS (Netherlands)

van Koppenhagen, Casper F.; de Groot, Sonja; Post, Marcel W.; Hoekstra, Trynke; van Asbeck, Floris W.; Bongers, Helma; Lindeman, Eline; van der Woude, Luc H.

Objectives: (1) To identify different patterns of changes in wheelchair exercise capacity in the period between the start of active spinal cord injury (SCI) rehabilitation and 5 years after discharge; (2) to examine the pattern determinants of the change in wheelchair exercise capacity. Design:

Silicon oxide based high capacity anode materials for lithium ion batteries

Science.gov (United States)

Deng, Haixia; Han, Yongbong; Masarapu, Charan; Anguchamy, Yogesh Kumar; Lopez, Herman A.; Kumar, Sujeet

2017-03-21

Silicon oxide based materials, including composites with various electrical conductive compositions, are formulated into desirable anodes. The anodes can be effectively combined into lithium ion batteries with high capacity cathode materials. In some formulations, supplemental lithium can be used to stabilize cycling as well as to reduce effects of first cycle irreversible capacity loss. Batteries are described with surprisingly good cycling properties with good specific capacities with respect to both cathode active weights and anode active weights.

Production of ceramic-metal joints for high-vacuum applications and development of simulation program for discharge tube

Energy Technology Data Exchange (ETDEWEB)

Kang, S. H.; Chung, K. H. [Seoul National University, Seoul (Korea)

2000-04-01

To develop a ceramic-metal jointed tube for high-vacuum applications, metalizing process and active metal brazing were investigated. Active metal brazing was adopted as a joining process to produce a high-vacuum tube which had high joint strength and reliability. A possibility for the development of new composition of Mo-Mn paste was studied. Also, to improve the strength and reliability of active metal brazed joint, TiN coating was introduced as a diffusion barrier. It was revealed that TiN coating could improve the joint strength and reliability. 100mm {phi} tube joint was produced using incusil ABA brazing alloy. The strength and reliability of manufactured tube showed higher value than commercial one. The electric field distribution in ceramic tube under high voltage was analyzed. Two dimensional electric field distribution was investigated under the existence of charged particles. From this result, electric field distribution at the surface of ceramic tube and the location of high electric field was predicted. Finally, Arc discharge was simulated to analyze the effect of arc discharge on the discharge tube wall. The maximum temperature of arc was 12000-13000K. The wall temperature was increased 100-170K by the arc discharge. 45 refs., 57 figs., 4 tabs. (Author)

Seasonal Arsenic Accumulation in Stream Sediments at a Groundwater Discharge Zone

DEFF Research Database (Denmark)

MacKay, Allison A.; Gan, Ping; Yu, Ran

2014-01-01

Seasonal changes in arsenic and iron accumulation rates were examined in the sediments of a brook that receives groundwater discharges of arsenic and reduced iron. Clean glass bead columns were deployed in sediments for known periods over the annual hydrologic cycle to monitor changes in arsenic...... and iron concentrations in bead coatings. The highest accumulation rates occurred during the dry summer period (July-October) when groundwater discharges were likely greatest at the sample locations. The intermediate flow period (October-March), With higher surface water: levels, was associated with losses...... of arsenic and iron from bead column coatings at. depths below 2-6 cm. Batch incubations indicated iron releases from solids to be induced by biological reduction of iron (oxy)hydroxide solids. Congruent arsenic releases during incubation were limited by the high arsenic sorption capacity (0.536 mg...

High intensity Discharge lighting; Alumbrado de alta intensidad de descarga

Energy Technology Data Exchange (ETDEWEB)

Mendoza E, Ernesto J [Manufacturera de Reactores, S. A., Mexico, D. F. (Mexico)

1994-12-31

This paper gets into contact with some fundamentals in the operation of high discharge intensity lamps. There are useful definitions, as well as the study of the operation of high pressure sodium lamps and of metallic additives operating at less than nominal power. [Espanol] Este trabajo pone al lector en contacto con algunos fundamentos de la operacion de las lamparas de alta intensidad de descarga (HID). Se encuentra con definiciones utiles, asi como el estudio de la operacion de las lamparas de sodio en alta presion y de aditivos metalicos operando a una potencia menor que la nominal.

High intensity Discharge lighting; Alumbrado de alta intensidad de descarga

Energy Technology Data Exchange (ETDEWEB)

Mendoza E, Ernesto J. [Manufacturera de Reactores, S. A., Mexico, D. F. (Mexico)

1993-12-31

This paper gets into contact with some fundamentals in the operation of high discharge intensity lamps. There are useful definitions, as well as the study of the operation of high pressure sodium lamps and of metallic additives operating at less than nominal power. [Espanol] Este trabajo pone al lector en contacto con algunos fundamentos de la operacion de las lamparas de alta intensidad de descarga (HID). Se encuentra con definiciones utiles, asi como el estudio de la operacion de las lamparas de sodio en alta presion y de aditivos metalicos operando a una potencia menor que la nominal.

Magnesium stannide as a high-capacity anode for magnesium-ion batteries

Science.gov (United States)

Nguyen, Dan-Thien; Song, Seung-Wan

2017-11-01

Driven by the limited global resources of lithium, magnesium metal batteries are considered as potential energy storage systems. The battery chemistry of magnesium metal anode, however, limits the selection of electrolytes, cathode materials and working temperature, making the realization of magnesium metal batteries complicated. Herein, we report the development of a new magnesium-insertion anode, magnesium stannide (Mg2Sn), and demonstrate reversible electrochemical Mg2+-extraction and insertion of Mg2Sn anode at 0.2 V versus Mg, delivering discharge capacity of 270 mAhg-1 in a half-cell with the electrolyte of PhMgCl/THF and enabling of room temperature magnesium-ion batteries with Mg2Sn anode combined with Mg-free oxide cathode and conventional-type electrolyte of Mg(TFSI)2/diglyme. The combination of Mg2Sn anode with various cathodes and electrolytes holds great promise for enabling room temperature magnesium-ion batteries.

Peak capacity, peak-capacity production rate, and boiling point resolution for temperature-programmed GC with very high programming rates

Science.gov (United States)

Grall; Leonard; Sacks

2000-02-01

Recent advances in column heating technology have made possible very fast linear temperature programming for high-speed gas chromatography. A fused-silica capillary column is contained in a tubular metal jacket, which is resistively heated by a precision power supply. With very rapid column heating, the rate of peak-capacity production is significantly enhanced, but the total peak capacity and the boiling-point resolution (minimum boiling-point difference required for the separation of two nonpolar compounds on a nonpolar column) are reduced relative to more conventional heating rates used with convection-oven instruments. As temperature-programming rates increase, elution temperatures also increase with the result that retention may become insignificant prior to elution. This results in inefficient utilization of the down-stream end of the column and causes a loss in the rate of peak-capacity production. The rate of peak-capacity production is increased by the use of shorter columns and higher carrier gas velocities. With high programming rates (100-600 degrees C/min), column lengths of 6-12 m and average linear carrier gas velocities in the 100-150 cm/s range are satisfactory. In this study, the rate of peak-capacity production, the total peak capacity, and the boiling point resolution are determined for C10-C28 n-alkanes using 6-18 m long columns, 50-200 cm/s average carrier gas velocities, and 60-600 degrees C/min programming rates. It was found that with a 6-meter-long, 0.25-mm i.d. column programmed at a rate of 600 degrees C/min, a maximum peak-capacity production rate of 6.1 peaks/s was obtained. A total peak capacity of about 75 peaks was produced in a 37-s long separation spanning a boiling-point range from n-C10 (174 degrees C) to n-C28 (432 degrees C).

Acid-base status of soils in groundwater discharge zones — relation to surface water acidification

Science.gov (United States)

Norrström, Ann Catrine

1995-08-01

Critical load calculations have suggested that groundwater at depth of 2 m in Sweden is very sensitive to acid load. As environmental isotope studies have shown that most of the runoff in streams has passed through the soil, there is a risk in the near future of accelerated acidification of surface waters. To assess the importance of the last soil horizon of contact before discharge, the upper 0-0.2m of soils in seven discharge zones were analysed for pools of base cations, acidity and base saturation. The sites were about 3-4 m 2 in size and selected from two catchments exposed to different levels of acid deposition. The soils in the seven sites had high concentrations of exchangeable base cations and consequently high base saturation. The high correlation ( r2 = 0.74) between base saturation in the soils of the discharge zones and mean pH of the runoff waters suggested that the discharge zone is important for surface water acidification. The high pool of exchangeable base cations will buffer initially against the acid load. As the cation exchange capacity (meq dm -3) and base saturation were lower in the sites from the catchment receiving lower deposition, these streams may be more vulnerable to acidification in the near future. The high concentration of base cations in non-exchangeable fractions may also buffer against acidification as it is likely that some of these pools will become exchangeable with time.

CO-AXIAL DISCHARGES

Science.gov (United States)

Luce, J.S.; Smith, L.P.

1960-11-22

A method and apparatus are given for producing coaxial arc discharges in an evacuated enclosure and within a strong, confining magnetic field. The arcs are maintained at a high potential difference. Electrons will diffuse to the more positive arc from the negative arc, and positive ions will diffuse from the more positive arc to the negative arc. Coaxial arc discharges have the advantage that ions which return to strike the positive arc discharge will lose no energy since they do not strike a solid wall or electrode. Those discharges are useful in confining an ionized plasma between the discharges, and have the advantage of preventing impurities from the walls of the enclosure from entering ihe plasma area because of the arc barrier set up bv the cylindrical outer arc.

Synthesis and characterization of high-density LiFePO4/C composites as cathode materials for lithium-ion batteries

International Nuclear Information System (INIS)

Chang Zhaorong; Lv Haojie; Tang Hongwei; Li Huaji; Yuan Xiaozi; Wang Haijiang

2009-01-01

To achieve a high-energy-density lithium electrode, high-density LiFePO 4 /C composite cathode material for a lithium-ion battery was synthesized using self-produced high-density FePO 4 as a precursor, glucose as a C source, and Li 2 CO 3 as a Li source, in a pipe furnace under an atmosphere of 5% H 2 -95% N 2 . The structure of the synthesized material was analyzed and characterized by X-ray diffraction (XRD) and scanning electron microscope (SEM). The electrochemical properties of the synthesized LiFePO 4 /carbon composite were investigated by cyclic voltammetry (CV) and the charge/discharge process. The tap-density of the synthesized LiFePO 4 /carbon composite powder with a carbon content of 7% reached 1.80 g m -3 . The charge/discharge tests show that the cathode material has initial charge/discharge capacities of 190.5 and 167.0 mAh g -1 , respectively, with a volume capacity of 300.6 mAh cm -3 , at a 0.1C rate. At a rate of 5C, the LiFePO 4 /carbon composite shows a high discharge capacity of 98.3 mAh g -1 and a volume capacity of 176.94 mAh cm -3 .

Concept of a large-capacity irradiated-fuel-reprocessing plant

International Nuclear Information System (INIS)

Buck, C.; Couture, J.; Issel, W.; Mamelle, J.

The processing of LWR fuels in recent years has run into difficulties due to the adaptation of the Purex process to these fuels with a high irradiation rate. This has led to development of new technological techniques. High-capacity plants should, in the future, limit their discharge of liquid and gaseous effluents to values comparable to those of nuclear electric stations. Investment costs necessary for processing the effluents and for temporary storage of the wastes are part of the total cost of these plants. However, the investments remain within acceptable limits. The 1500-ton/year plant presented is an example of what can be done in the 1980's

Source of high-voltage power supply for ozone generators at glow discharge

International Nuclear Information System (INIS)

Bruev, A.A.; Golota, V.I.; Zavada, L.M.; Taran, G.V.

2000-01-01

High-voltage power supply source on quasi-resonance inverter base which works at direct current regime is described. This source forms 20 kV voltage with 0 - 10 mA current regulation. It protects the source from current break-downs and feeds ozone generators at glow discharge

State Capacity and Democratic Administration: South Africa’s Post- Democracy View

Directory of Open Access Journals (Sweden)

Mashele Rapatsa

2016-09-01

Full Text Available State capacity and democratic administration are conceptually distinct, but theoretically interdependent notions whose significance concerning fulfilment of developmental objectives cannot be understated in any democratic dispensation. Thus, this article discusses how the notion of state capacity affect the pursuit of human development and the enforcement and realization of socioeconomic rights under South Africa’s post 1994 democratic dispensation. It is considerate of the fact a progressive fulfilment of people’s socio-economic entitlements largely depends on having a state which has adequate administrative, economic and technical capabilities to discharge its constitutional obligations. Without these capacities, citizens’ legitimate expectations of state fulfilling its obligations as imposed by the Constitution and essential international legal norms diminishes. State capacity is concerned with state’s competence to discharge its governance obligations in pursuit of the goal of regulating and protecting rights and interests of private persons and entities. Weakened state lack capacity to control its functionaries and private agents, consequently depriving citizens of their deserved protection. It is argued that the post 1994 transformative democratic dispensation is caught in a quagmire owing to diminishing fiscal capacity, and is inherently struggling to ward off socioeconomic deprivations inherited from the past.

High density low-q discharges with D-shaped plasmas in Doublet III

International Nuclear Information System (INIS)

Nagami, Masayuki; Yoshida, Hidetoshi; Shinya, Kichiro; Yokomizo, Hideaki; Shimada, Michiya; Ioki, Kimihiro; Izumi, Shigeru; Kitsunezaki, Masao; Jahns, G.

1981-07-01

The maximum plasma current in Doublet III is found to be limited by disruptions when the limiter safety factor is approximately 2. However, due to the strong toroidal and shaping field effect on rotational transform at the outer plasma edge associated with a D-shape formation having a vertical elongation of 1.5, the safety factor q sub(a) * estimated from simple geometric considerations for D-shaped plasmas corresponds to values as low as 1.5. These discharges operate stably with considerably higher plasma current than most reactor design studies assume. These low-q discharges show excellent plasma performance: very flat spatial electron temperature progiles, high density operation with anti n sub(e)R/B sub(T) up to 7.8, and good energy confinement producing a volume average β of up to 1% with ohmic heating only. This operational regime appears to be applicable to future high β tokamaks with D-shaped cross section. (author)

Thermal storage/discharge performances of Cu-Si alloy for solar thermochemical process

Science.gov (United States)

Gokon, Nobuyuki; Yamaguchi, Tomoya; Cho, Hyun-seok; Bellan, Selvan; Hatamachi, Tsuyoshi; Kodama, Tatsuya

2017-06-01

The present authors (Niigata University, Japan) have developed a tubular reactor system using novel "double-walled" reactor/receiver tubes with carbonate molten-salt thermal storage as a phase change material (PCM) for solar reforming of natural gas and with Al-Si alloy thermal storage as a PCM for solar air receiver to produce high-temperature air. For both of the cases, the high heat capacity and large latent heat (heat of solidification) of the PCM phase circumvents the rapid temperature change of the reactor/receiver tubes at high temperatures under variable and uncontinuous characteristics of solar radiation. In this study, we examined cyclic properties of thermal storage/discharge for Cu-Si alloy in air stream in order to evaluate a potentiality of Cu-Si alloy as a PCM thermal storage material. Temperature-increasing performances of Cu-Si alloy are measured during thermal storage (or heat-charge) mode and during cooling (or heat-discharge) mode. A oxidation state of the Cu-Si alloy after the cyclic reaction was evaluated by using electron probe micro analyzer (EPMA).

The n-by-T Target Discharge Strategy for Inpatient Units.

Science.gov (United States)

Parikh, Pratik J; Ballester, Nicholas; Ramsey, Kylie; Kong, Nan; Pook, Nancy

2017-07-01

Ineffective inpatient discharge planning often causes discharge delays and upstream boarding. While an optimal discharge strategy that works across all units at a hospital is likely difficult to identify and implement, a strategy that provides a reasonable target to the discharge team appears feasible. We used observational and retrospective data from an inpatient trauma unit at a Level 2 trauma center in the Midwest US. Our proposed novel n-by-T strategy-discharge n patients by the Tth hour-was evaluated using a validated simulation model. Outcome measures included 2 measures: time-based (mean discharge completion and upstream boarding times) and capacity-based (increase in annual inpatient and upstream bed hours). Data from the pilot implementation of a 2-by-12 strategy at the unit was obtained and analyzed. The model suggested that the 1-by-T and 2-by-T strategies could advance the mean completion times by over 1.38 and 2.72 h, respectively (for 10 AM ≤ T ≤ noon, occupancy rate = 85%); the corresponding mean boarding time reductions were nearly 11% and 15%. These strategies could increase the availability of annual inpatient and upstream bed hours by at least 2,469 and 500, respectively. At 100% occupancy rate, the hospital-favored 2-by-12 strategy reduced the mean boarding time by 26.1%. A pilot implementation of the 2-by-12 strategy at the unit corroborated with the model findings: a 1.98-h advancement in completion times (Pstrategies, such as the n-by-T, can help substantially reduce discharge lateness and upstream boarding, especially during high unit occupancy. To sustain implementation, necessary commitment from the unit staff and physicians is vital, and may require some training.

A kinematic wave model in Lagrangian coordinates incorporating capacity drop: Application to homogeneous road stretches and discontinuities

Science.gov (United States)

Yuan, Kai; Knoop, Victor L.; Hoogendoorn, Serge P.

2017-01-01

On freeways, congestion always leads to capacity drop. This means the queue discharge rate is lower than the pre-queue capacity. Our recent research findings indicate that the queue discharge rate increases with the speed in congestion, that is the capacity drop is strongly correlated with the congestion state. Incorporating this varying capacity drop into a kinematic wave model is essential for assessing consequences of control strategies. However, to the best of authors' knowledge, no such a model exists. This paper fills the research gap by presenting a Lagrangian kinematic wave model. "Lagrangian" denotes that the new model is solved in Lagrangian coordinates. The new model can give capacity drops accompanying both of stop-and-go waves (on homogeneous freeway section) and standing queues (at nodes) in a network. The new model can be applied in a network operation. In this Lagrangian kinematic wave model, the queue discharge rate (or the capacity drop) is a function of vehicular speed in traffic jams. Four case studies on links as well as at lane-drop and on-ramp nodes show that the Lagrangian kinematic wave model can give capacity drops well, consistent with empirical observations.

Spectrographic observations of high intensity discharges

International Nuclear Information System (INIS)

Breton, C.; Charon, J.; Hubert, P.; Yvon, P.

1957-01-01

During straight discharges in deuterium at low pressure, the production of X-rays and neutrons has been observed. Spectroscopic observation of the light emitted reveals a broadening of the Balmer lines. From this a mean ionic density of the order of several 10 16 ions/cm 3 is deduced. (author) [fr

Modelling the Dynamic Interaction Power System Lamp - Application to High Pressure Mercury Gas Discharge Lamps

Directory of Open Access Journals (Sweden)

ZIANE, M.

2007-11-01

Full Text Available The aim of this paper is to study the dynamic behaviour of a plant constituted by an electrical power system and a gas discharge lamp, this latter, increasingly used in street lighting, remains a nonlinear load element. Various approaches are used to represent it, one is the approximation of the discharge represented by a hot "channel", which verifies the assumption of local thermodynamic equilibrium [LTE] or the polynomial form of the conductance variation. A calculation procedure, based on "channel" approximation of the high pressure mercury (HPM gas-discharge lamp, is developed to determine the physical and electric magnitudes, which characterize the dynamic behavior of the couple "lamp-electrical power system". The evolution of the lamp properties when principal parameters of the discharge (pressure of mercury, voltage supply, frequency are varying were studied and analyzed. We show the concordance between simulation, calculations and measurements for electric, energetic or irradiative characteristics. The model reproduces well the evolution of properties of the supply when principal parameters of the discharge vary.

Enhanced performance on high current discharges in JET produced by ICRF heating during the current rise

International Nuclear Information System (INIS)

Bures, M.; Bhatnagar, V.; Cotrell, G.; Corti, S.; Christiansen, J.P.; Hellsten, T.; Jacquinot, J.; Lallia, P.; Lomas, P.; O'Rourke, J.; Taroni, A.; Tibone, F.; Start, D.F.H.

1989-01-01

The performance of high current discharges can be increased by applying central ICRF heating before or shortly after the onset of sawtooth activity in the plasma current rise phase. Sawtooth-free periods have been obtained resulting in the enhanced discharge performance. High T e (0) 9 - 10.5 keV with peaked profiles T e (0)/ e > = 3 - 4 were obtained giving values of n e (0)T e (0) up to 6x10 20 (keV m -3 ). Improvements in T i (0) and neutron production are observed. A 60 % enhancement in D-D reaction rate from 2nd harmonic deuterium (2ω CD ) heating appears to be present. In all current rise (CR) discharges radiation amounts to 25-50 % of total power. (author) 4 refs., 6 figs

Longitudinal Plasmoid in High-Speed Vortex Gas Flow Created by Capacity HF Discharge

Science.gov (United States)

2010-10-28

interferometer with high space resolution, PIV method, FTIR spectrometer, optical spectrometer, pressure sensors with high time resolution, IR pyrometer and...of strong LP-vortex interaction. Intensive acoustic waves are created by CHFD in swirl flow in this regime. 38. Study of control of a longitudinal...quartz tube, 4- HF ball electrode, 5- Tesla’s transformer, 6- microwave interferometer, 7- video camera, 8-optical pyrometer , 9-pressure sensor, 10

Improved high-intensity microwave discharge lamp for atomic resonance absorption and fluorescence spectrometry

International Nuclear Information System (INIS)

Lifshitz, A.; Skinner, G.B.; Wood, D.R.

1978-01-01

An unusually good combination of high intensity and narrow line has been achieved in a microwave discharge lamp by placing the optical window in the center of the microwave cavity. Construction details and performance characteristics are described

Improved high-intensity microwave discharge lamp for atomic resonance absorption and fluorescence spectrometry.

Science.gov (United States)

Lifshitz, A; Skinner, G B; Wood, D R

1978-09-01

An unusually good combination of high intensity and narrow line has been achieved in a microwave discharge lamp by placing the optical window in the center of the microwave cavity. Construction details and performance characteristics are described.

High-capacity NO2 denuder systems operated at various temperatures (298-473 K).

Science.gov (United States)

Wolf, Jan-Christoph; Niessner, Reinhard

2012-12-01

In this study, we investigated several coatings for high-temperature, high-capacity, and high-efficiency denuder-based NO(2) removal, with the scope to face the harsh conditions and requirements of automotive exhaust gas sampling. As first coating, we propose a potassium iodide (KI)/polyethylene glycol coating with a high removal efficiency (ε > 98%) for about 2 h and 50 ppm NO(2) at room temperature (298 K). At elevated temperatures (423 K), the initial capacity (100 ppmh) is decreased to 15 ppmh. Furthermore, this is the first proposal of the ionic liquid methyl-butyl-imidazolium iodide ([BMIm(+)][I(-)]) as denuder coating material. At room temperature, this ionic liquid exhibits far greater capacity (300 ppmh) and NO(2) removal efficiency (ε > 99.9%) than KI. Nevertheless, KI exhibits a slightly (~10%) higher capacity at elevated temperatures than [BMIm(+)][I(-)]. Both coatings presented are suitable for applications requiring selective denuding of NO(2) at temperatures up to 423 K.

Crystallographic Habit Tuning of Li2MnSiO4 Nanoplates for High-Capacity Lithium Battery Cathodes.

Science.gov (United States)

Ding, Zhengping; Feng, Yiming; Zhang, Datong; Ji, Ran; Chen, Libao; Ivey, Douglas G; Wei, Weifeng

2018-02-21

Li 2 MnSiO 4 has attracted significant attention as a cathode material for lithium ion batteries because of its high theoretical capacity (330 mA h g -1 with two Li + ions per formula unit), low cost, and environmentally friendly nature. However, its intrinsically poor Li diffusion, low electronic conductivity, and structural instability preclude its use in practical applications. Herein, elongated hexagonal prism-shaped Li 2 MnSiO 4 nanoplates with preferentially exposed {001} and {210} facets have been successfully synthesized via a solvothermal method. Density functional theory calculations and experimental characterization reveal that the formation mechanism involves the decomposition of solid precursors to nanosheets, self-assembly into nanoplates, and Ostwald ripening. Hydroxyl-containing solvents such as ethylene glycol and diethylene glycol play a crucial role as capping agents in tuning the preferential growth. Li 2 MnSiO 4 @C nanoplates demonstrate a near theoretical discharge capacity of 326.7 mA h g -1 at 0.05 C (1 C = 160 mA h g -1 ), superior rate capability, and good cycling stability. The enhanced electrochemical performance is ascribed to the electrochemically active {001} and {210} exposed facets, which provide short and fast Li + diffusion pathways along the [001] and [100] axes, a conformal carbon nanocoating, and a nanoscaled platelike structure, which offers a large electrode/electrolyte contact interface for Li + extraction/insertion processes.

Multiwalled carbon nanotube@a-C@Co9S8 nanocomposites: a high-capacity and long-life anode material for advanced lithium ion batteries

Science.gov (United States)

Zhou, Yanli; Yan, Dong; Xu, Huayun; Liu, Shuo; Yang, Jian; Qian, Yitai

2015-02-01

A one-dimensional MWCNT@a-C@Co9S8 nanocomposite has been prepared via a facile solvothermal reaction followed by a calcination process. The amorphous carbon layer between Co9S8 and MWCNT acts as a linker to increase the loading of sulfides on MWCNT. When evaluated as anode materials for lithium ion batteries, the MWCNT@a-C@Co9S8 nanocomposite shows the advantages of high capacity and long life, superior to Co9S8 nanoparticles and MWCNT@Co9S8 nanocomposites. The reversible capacity could be retained at 662 mA h g-1 after 120 cycles at 1 A g-1. The efficient synthesis and excellent performances of this nanocomposite offer numerous opportunities for other sulfides as a new anode for lithium ion batteries.A one-dimensional MWCNT@a-C@Co9S8 nanocomposite has been prepared via a facile solvothermal reaction followed by a calcination process. The amorphous carbon layer between Co9S8 and MWCNT acts as a linker to increase the loading of sulfides on MWCNT. When evaluated as anode materials for lithium ion batteries, the MWCNT@a-C@Co9S8 nanocomposite shows the advantages of high capacity and long life, superior to Co9S8 nanoparticles and MWCNT@Co9S8 nanocomposites. The reversible capacity could be retained at 662 mA h g-1 after 120 cycles at 1 A g-1. The efficient synthesis and excellent performances of this nanocomposite offer numerous opportunities for other sulfides as a new anode for lithium ion batteries. Electronic supplementary information (ESI) available: Infrared spectrogram (IR) of glucose treated MWCNT; TEM images of MWCNT@a-C treated by different concentrations of glucose; SEM and TEM images of the intermediate product obtained from the solvothermal reaction between thiourea and Co(Ac)2; EDS spectrum of MWCNT@a-C@Co9S8 composites; SEM and TEM images of MWCNT@Co9S8 nanocomposites obtained without the hydrothermal treatment by glucose; SEM and TEM images of Co9S8 nanoparticles; Galvanostatic discharge-charge profiles and cycling performance of MWCNT@a-C; TEM images

Aerobic Capacities of Early College High School Students

Science.gov (United States)

Loflin, Jerry W.

2014-01-01

The Early College High School Initiative (ECHSI) was introduced in 2002. Since 2002, limited data, especially student physical activity data, have been published pertaining to the ECHSI. The purpose of this study was to examine the aerobic capacities of early college students and compare them to state and national averages. Early college students…

Determination of soluble bromine in an extra-high-pressure mercury discharge lamp by sodium hydroxide decomposition-suppressed ion chromatography.

Science.gov (United States)

Mitsumata, Hiroshi; Mori, Toshio; Maeda, Tatsuo; Kita, Yoshiyuki; Kohatsu, Osamu

2006-02-01

We have established a simple method for assaying the quantity of soluble bromine in the discharge tubes of an extra-high-pressure mercury discharge lamp. Each discharge tube is destroyed in 5 ml of 10 mM sodium hydroxide, and the recovered sodium hydroxide solution is analyzed by suppressed-ion chromatography using gradient elution. We have clarified that this method can assay less than 1 microg of soluble bromine in a discharge tube.

High-capacity neutron activation analysis facility

International Nuclear Information System (INIS)

Hochel, R.C.

1979-01-01

A high-capacity neutron activation analysis facility, the Reactor Activation Facility, was designed and built and has been in operation for about a year at one of the Savannah River Plant's production reactors. The facility determines uranium and about 19 other trace elements in hydrogeochemical samples collected in the National Uranium Resource Evaluation program. The facility has a demonstrated average analysis rate of over 10,000 samples per month, and a peak rate of over 16,000 samples per month. Uranium is determined by cyclic activation and delayed neutron counting of the U-235 fission products; other elements are determined from gamma-ray spectra recorded in subsequent irradiation, decay, and counting steps. The method relies on the absolute activation technique and is highly automated for round-the-clock unattended operation

Expansion of a nitrogen discharge by sound

International Nuclear Information System (INIS)

Antinyan, M.A.; Galechyan, G.A.; Tavakalyan, L.B.

1992-01-01

When the background pressure and the discharge current in a gas discharge are raised the plasma column is tightened up into a filament. Then the discharge occupies a region of the discharge tube whose transverse dimensions are substantially less than those of the tube. This contraction phenomenon in discharges restricts the range of parameters used in various devices to the range of relatively low discharge currents and low gas pressures. This contraction interferes with creating high-power gas lasers, since it acts destructively on the lasing process. In order to suppress filamentation of discharges the working gas has been pumped through the system at high speed, with considerable success. The turbulent mixing in the stream plays an important role in creating an uncontracted discharge at high pressures. The purpose of the present work is to study the possibility of undoing the contraction of a nitrogen discharge, which is one of the main components in the operation of a CO 2 laser, by introducing an intense sound wave in the discharge tube. Discharge contraction and the effect of a sound wave propagating along the plasma column have been investigated experimentally in nitrogen by studying the current-voltage characteristics of a contracted discharge. 6 refs., 3 figs

Enhanced capacity and stability of K_2FeO_4 cathode with poly(3-hexylthiophene) coating for alkaline super-iron battery

International Nuclear Information System (INIS)

Wang, Suqin; Wang, Yaoyao; Chen, Shuiliang; Hou, Haoqing; Li, Hongbo

2016-01-01

Highlights: • Conductive polymer coating allows improving capacity and stability of K_2FeO_4. • P3HT-coated K_2FeO_4 is prepared. • High capacity is recorded after storing 6 h (314 mAh g"−"1) for P3HT-coated K_2FeO_4. • Partly oxidized P3HT coating is formed due to the reaction between P3HT and K_2FeO_4. • The mechanism of improving capacity and stability of K_2FeO_4 is proposed. - Abstract: Poly(3-hexylthiophene)-coated K_2FeO_4 (K_2FeO_4@P3HT) was prepared to enhance capacity and stability of K_2FeO_4. Scanning electron microscopy (SEM), Fourier transform infrared spectrum (FT-IR) and X-ray photoelectron spectra (XPS) were performed to characterize K_2FeO_4@P3HT. Discharge performance results showed that the Poly(3-hexylthiophene) (P3HT) coating layer enhanced the capacity of the K_2FeO_4 in 10 mol L"−"1 KOH electrolyte. K_2FeO_4@P3HT-1% electrode showed a high discharge capacity of 351 mAh g"−"1, about 13% increase comparing to the K_2FeO_4 electrode. Moreover, the stability of K_2FeO_4 electrode was obviously enhanced by P3HT coating, and the discharge capacity of the electrode which was stored in electrolyte for 6 h was improved to 314 mAh g"−"1, increasing about 22.6% compared to that of 314 mAh g"−"1. These desirable properties can be attributed to the in-situ formation of two-layer film on the surface of K_2FeO_4 crystal, which keep electrolyte from directly contacting with K_2FeO_4 and reduce the resistance of charge transfer.

Novel graphene papers with sporadic alkyl brushes on the basal plane as a high-capacity flexible anode for lithium ion batteries

International Nuclear Information System (INIS)

Oh, Kyung Min; Cho, Sung-Woo; Kim, Gyeong-Ok; Ryu, Kwang-Sun; Jeong, Han Mo

2014-01-01

Graphene paper that exhibits an excellent stabilized capacity, as high as 1300 mAh g −1 at a current rate of 60 mA g −1 , as a lithium ion battery anode is fabricated and evaluated. The few-layer graphene used to make the graphene paper is prepared via the thermal reduction of graphite oxide. The graphene is then modified by a novel method utilizing inherent defects, namely epoxy groups, on the graphene as active sites for a reaction with methanol, 1-butanol, 1-hexanol, and 1-octanol. The density values and X-ray diffraction patterns obtained for the graphene paper demonstrate that the alkyl brushes on the graphene sheets expand the d-spacing and hinder close restacking of the sheets, thereby inducing the formation of extra cavities within the paper. This loose packing due to the alkyl brushes increases sensitively as the alkyl chain length of the alcohol becomes longer. The lithium ion insertion capacity of a graphene paper electrode at the first cycle also increases with the alkyl chain length. However, fading of the capacity at early charge/discharge cycles is accelerated by the modification process because of electrolyte penetration into the gallery and the acceleration of protective solid electrolyte interface film formation due to looser packing. The paper composed of graphene modified with 1-butanol rather than shorter or longer alcohols exhibits the best reversible storage capacity, more than two-fold higher when compared to that of pristine graphene paper, due to a compromise between two conflicting effects on the reversible storage capacity by long alkyl brushes. The tensile properties and electrical conductivity of the graphene papers are also examined

Why do Electrons with "Anomalous Energies" appear in High-Pressure Gas Discharges?

Science.gov (United States)

Kozyrev, Andrey; Kozhevnikov, Vasily; Semeniuk, Natalia

2018-01-01

Experimental studies connected with runaway electron beams generation convincingly shows the existence of electrons with energies above the maximum voltage applied to the discharge gap. Such electrons are also known as electrons with "anomalous energies". We explain the presence of runaway electrons having so-called "anomalous energies" according to physical kinetics principles, namely, we describe the total ensemble of electrons with the distribution function. Its evolution obeys Boltzmann kinetic equation. The dynamics of self-consistent electromagnetic field is taken into the account by adding complete Maxwell's equation set to the resulting system of equations. The electrodynamic mechanism of the interaction of electrons with a travelling-wave electric field is analyzed in details. It is responsible for the appearance of electrons with high energies in real discharges.

An AC impedance study of self-discharge mechanism of nickel-metal hydride (Ni-MH) battery using Mg{sub 2}Ni-type hydrogen storage alloy anode

Energy Technology Data Exchange (ETDEWEB)

Cui, N.; Luo, J.L. [University of Alberta, Edmonton, Alberta (Canada). Department of Chemical and Materials Engineering

2000-07-01

The self-discharge mechanism during storage in open-circuit states of a Ni-MH battery using a Mg{sub 2}Ni-type hydrogen storage alloy anode was investigated by electrochemical impedance spectroscopy (EIS) and X-ray diffraction (XRD). The loss of discharge capacity for this battery can be ascribed to two causes: (i) desorption of hydrogen from the Mg{sub 1.95}Y{sub 0.05}Ni{sub 0.92}Al{sub 0.08} hydride anode; and (ii) anode surface degradation resulting from oxidation of the magnesium alloy in the electrolyte. At the higher open-circuit voltages (OCV), the former was mainly responsible for a high self-discharge rate, while the latter might dominate the loss of capacity at the lower OCV. XRD results confirmed that Mg(OH){sub 2} formed on the magnesium alloy anode after storage in an open-circuit condition for 20 days. (author)

Waste water discharges into natural waters

International Nuclear Information System (INIS)

Marri, P.; Barsanti, P.; Mione, A.; Posarelli, M.

1996-12-01

The aqueous discharges into natural waters is a very technical solution expecially for surface buoyant discharges. It is not only convenient to limit the concentration levels of the discharges, but also to improve the turbolent processes that diluite the discharge. Mostly these processes depend by some geometric parameters of the discharge and by some physical parameters of the effluent and of the receiving water body. An appropriate choice of some parameters, using also suitable mathematical models, allows to design discharges with a very high dilution; so the decreasing of the pollutant levels is improved and the environmental impact can be reduced versus a not diluted effluent. The simulations of a mathematical model, here described, prove that in some circumstances, expecially in case of discharges of fresh water into saline water bodies with a low velocity of the current, the dilution is poor; the effluent can be trapped in a narrow water surface layer where the pollutant concentrations remain high. also far away from the discharge point

Sulfate passivation in the lead-acid system as a capacity limiting process

Science.gov (United States)

Kappus, W.; Winsel, A.

1982-10-01

Calculations of the discharge capacity of Pb and PbO 2 electrodes as a function of various parameters are presented. They are based on the solution-precipitation mechanism for the discharge reaction and its formulation by Winsel et al. A logarithmic pore size distribution is used to fit experimental porosigrams of Pb and PbO 2 electrodes. Based on this pore size distribution the capacity is calculated as a function of current, BET surface, and porosity of the PbSO 4 diaphragm. The PbSO 4 supersaturation as the driving force of the diffusive transport is chosen as a free parameter.

Estimating Discharge in Low-Order Rivers With High-Resolution Aerial Imagery

Science.gov (United States)

King, Tyler V.; Neilson, Bethany T.; Rasmussen, Mitchell T.

2018-02-01

Remote sensing of river discharge promises to augment in situ gauging stations, but the majority of research in this field focuses on large rivers (>50 m wide). We present a method for estimating volumetric river discharge in low-order (standard deviation of 6%). Sensitivity analyses were conducted to determine the influence of inundated channel bathymetry and roughness parameters on estimated discharge. Comparison of synthetic rating curves produced through sensitivity analyses show that reasonable ranges of parameter values result in mean percent errors in predicted discharges of 12%-27%.

Predictive validity of the Suicide Trigger Scale (STS-3 for post-discharge suicide attempt in high-risk psychiatric inpatients.

Directory of Open Access Journals (Sweden)

Zimri S Yaseen

Full Text Available BACKGROUND: The greatly increased risk of suicide after psychiatric hospitalization is a critical problem, yet we are unable to identify individuals who would attempt suicide upon discharge. The Suicide Trigger Scale v.3 (STS-3, was designed to measure the construct of an affective 'suicide trigger state' hypothesized to precede a suicide attempt (SA. This study aims to test the predictive validity of the STS-3 for post-discharge SA on a high-risk psychiatric-inpatient sample. METHODS: The STS-3, and a psychological test battery measuring suicidality, mood, impulsivity, trauma history, and attachment style were administered to 161 adult psychiatric patients hospitalized following suicidal ideation (SI or SA. Receiver Operator Characteristic and logistic regression analyses were used to assess prediction of SA in the 6-month period following discharge from hospitalization. RESULTS: STS-3 scores for the patients who made post-discharge SA followed a bimodal distribution skewed to high and low scores, thus a distance from median transform was applied to the scores. The transformed score was a significant predictor of post-discharge SA (AUC 0.731, and a subset of six STS-3 scale items was identified that produced improved prediction of post-discharge SA (AUC 0.814. Scores on C-SSRS and BSS were not predictive. Patients with ultra-high (90(th percentile STS-3 scores differed significantly from ultra-low (10(th percentile scorers on measures of affective intensity, depression, impulsiveness, abuse history, and attachment security. CONCLUSION: STS-3 transformed scores at admission to the psychiatric hospital predict suicide attempts following discharge among the high-risk group of suicidal inpatients. Patients with high transformed scores appear to comprise two clinically distinct groups; an impulsive, affectively intense, fearfully attached group with high raw STS-3 scores and a low-impulsivity, low affect and low trauma-reporting group with low raw

Pending laboratory tests and the hospital discharge summary in patients discharged to sub-acute care.

Science.gov (United States)

Walz, Stacy E; Smith, Maureen; Cox, Elizabeth; Sattin, Justin; Kind, Amy J H

2011-04-01

Previous studies have noted a high (41%) prevalence and poor discharge summary communication of pending laboratory (lab) tests at the time of hospital discharge for general medical patients. However, the prevalence and communication of pending labs within a high-risk population, specifically those patients discharged to sub-acute care (i.e., skilled nursing, rehabilitation, long-term care), remains unknown. To determine the prevalence and nature of lab tests pending at hospital discharge and their inclusion within hospital discharge summaries, for common sub-acute care populations. Retrospective cohort study. Stroke, hip fracture, and cancer patients discharged from a single large academic medical center to sub-acute care, 2003-2005 (N = 564) Pending lab tests were abstracted from the laboratory information system (LIS) and from each patient's discharge summary, then grouped into 14 categories and compared. Microbiology tests were sub-divided by culture type and number of days pending prior to discharge. Of sub-acute care patients, 32% (181/564) were discharged with pending lab tests per the LIS; however, only 11% (20/181) of discharge summaries documented these. Patients most often left the hospital with pending microbiology tests (83% [150/181]), particularly blood and urine cultures, and reference lab tests (17% [30/181]). However, 82% (61/74) of patients' pending urine cultures did not have 24-hour preliminary results, and 19% (13/70) of patients' pending blood cultures did not have 48-hour preliminary results available at the time of hospital discharge. Approximately one-third of the sub-acute care patients in this study had labs pending at discharge, but few were documented within hospital discharge summaries. Even after considering the availability of preliminary microbiology results, these omissions remain common. Future studies should focus on improving the communication of pending lab tests at discharge and evaluating the impact that this improved

Future High Capacity Backbone Networks

DEFF Research Database (Denmark)

Wang, Jiayuan

are proposed. The work focuses on energy efficient routing algorithms in a dynamic optical core network environment, with Generalized MultiProtocol Label Switching (GMPLS) as the control plane. Energy ef- ficient routing algorithms for energy savings and CO2 savings are proposed, and their performance...... aiming for reducing the dynamic part of the energy consumption of the network may increase the fixed part of the energy consumption meanwhile. In the second half of the thesis, the conflict between energy efficiency and Quality of Service (QoS) is addressed by introducing a novel software defined......This thesis - Future High Capacity Backbone Networks - deals with the energy efficiency problems associated with the development of future optical networks. In the first half of the thesis, novel approaches for using multiple/single alternative energy sources for improving energy efficiency...

Characterization of electron beams generated in a high-voltage pulse-line-driven pseudospark discharge

International Nuclear Information System (INIS)

Ramaswamy, K.; Destler, W.W.; Segalov, Z.; Rodgers, J.

1994-01-01

Emittance and energy measurements have been performed on a high-brightness electron beam (>10 10 A/m 2 rad 2 ) with diameter in the range 1--3 mm and energy in the range 150--170 keV. This electron beam is generated by the mating of a hollow-cathode discharge device operating in the pseudospark regime to the output of a high-power pulse line accelerator. The measured effective emittance lies in the range between 30 and 90 mm mrad and increases with axial distance. Electron energy measurements indicate that the high-energy electrons are generated during the first 20--30 ns of the discharge. Both the emittance and energy experiments were performed at two different ambient argon gas pressures (92 and 152 mtorr). Beam expansion as a function of axial position has also been studied and a lower bound on the beam brightness has been obtained

The NASA CSTI High Capacity Power Program

International Nuclear Information System (INIS)

Winter, J.M.

1991-09-01

The SP-100 program was established in 1983 by DOD, DOE, and NASA as a joint program to develop the technology necessary for space nuclear power systems for military and civil applications. During 1986 and 1987, the NASA Advanced Technology Program was responsible for maintaining the momentum of promising technology advancement efforts started during Phase 1 of SP-100 and to strengthen, in key areas, the chances for successful development and growth capability of space nuclear reactor power systems for future space applications. In 1988, the NASA Advanced Technology Program was incorporated into NASA's new Civil Space Technology Initiative (CSTI). The CSTI program was established to provide the foundation for technology development in automation and robotics, information, propulsion, and power. The CSTI High Capacity Power Program builds on the technology efforts of the SP-100 program, incorporates the previous NASA advanced technology project, and provides a bridge to the NASA exploration technology programs. The elements of CSTI high capacity power development include conversion systems: Stirling and thermoelectric, thermal management, power management, system diagnostics, and environmental interactions. Technology advancement in all areas, including materials, is required to provide the growth capability, high reliability, and 7 to 10 year lifetime demanded for future space nuclear power systems. The overall program will develop and demonstrate the technology base required to provide a wide range of modular power systems while minimizing the impact of day/night operations as well as attitudes and distance from the Sun. Significant accomplishments in all of the program elements will be discussed, along with revised goals and project timelines recently developed

Impurity transport of high performance discharges in JET

Energy Technology Data Exchange (ETDEWEB)

Lauro-Taroni, L; Alper, B; Giannella, R; Marcus, F; Smeulders, P; Von Hellermann, M [Commission of the European Communities, Abingdon (United Kingdom). JET Joint Undertaking; Lawson, K [UKAEA Culham Lab., Abingdon (United Kingdom); Mattioli, M [Association Euratom-CEA, Centre d` Etudes Nucleaires de Cadarache, 13 - Saint-Paul-lez-Durance (France). Dept. de Recherches sur la Fusion Controlee

1994-07-01

Experimental data show that in the Pellet Enhanced Performance (PEP) H-mode discharges, the light impurities are dominant and accumulate. Furthermore, strong fuel depletion may occur in the plasma centre with n{sub D}/n{sub e} falling to about 0.3 in some cases. On the other hand, in Hot-Ion discharges hollow profiles are measured for C: it is present in lower concentrations and has little effect on fuel dilution. The different behaviour of carbon in the two cases is in agreement with neoclassical predictions for the convection in the plasma core. 6 refs., 6 figs.

Impurity transport of high performance discharges in JET

International Nuclear Information System (INIS)

Lauro-Taroni, L.; Alper, B.; Giannella, R.; Marcus, F.; Smeulders, P.; Von Hellermann, M.; Mattioli, M.

1994-01-01

Experimental data show that in the Pellet Enhanced Performance (PEP) H-mode discharges, the light impurities are dominant and accumulate. Furthermore, strong fuel depletion may occur in the plasma centre with n D /n e falling to about 0.3 in some cases. On the other hand, in Hot-Ion discharges hollow profiles are measured for C: it is present in lower concentrations and has little effect on fuel dilution. The different behaviour of carbon in the two cases is in agreement with neoclassical predictions for the convection in the plasma core. 6 refs., 6 figs

Mesoporous Silicon-Based Anodes for High Capacity, High Performance Li-ion Batteries, Phase I

Data.gov (United States)

National Aeronautics and Space Administration — A new high capacity anode composite based on mesoporous silicon is proposed. By virtue of a structure that resembles a pseudo one-dimensional phase, the active anode...

A new battery capacity indicator for nickel-metal hydride battery powered electric vehicles using adaptive neuro-fuzzy inference system

International Nuclear Information System (INIS)

Chau, K.T.; Wu, K.C.; Chan, C.C.; Shen, W.X.

2003-01-01

This paper describes a new approach to estimate accurately the battery residual capacity (BRC) of the nickel-metal hydride (Ni-MH) battery for modern electric vehicles (EVs). The key to this approach is to model the Ni-MH battery in EVs by using the adaptive neuro-fuzzy inference system (ANFIS) with newly defined inputs and output. The inputs are the temperature and the discharged capacity distribution describing the discharge current profile, while the output is the state of available capacity (SOAC) representing the BRC. The estimated SOAC from ANFIS model and the measured SOAC from experiments are compared, and the results confirm that the proposed approach can provide an accurate estimation of the SOAC under variable discharge currents

Discharge runaway in high power impulse magnetron sputtering of carbon: the effect of gas pressure, composition and target peak voltage

Science.gov (United States)

Vitelaru, Catalin; Aijaz, Asim; Constantina Parau, Anca; Kiss, Adrian Emil; Sobetkii, Arcadie; Kubart, Tomas

2018-04-01

Pressure and target voltage driven discharge runaway from low to high discharge current density regimes in high power impulse magnetron sputtering of carbon is investigated. The main purpose is to provide a meaningful insight of the discharge dynamics, with the ultimate goal to establish a correlation between discharge properties and process parameters to control the film growth. This is achieved by examining a wide range of pressures (2–20 mTorr) and target voltages (700–850 V) and measuring ion saturation current density at the substrate position. We show that the minimum plasma impedance is an important parameter identifying the discharge transition as well as establishing a stable operating condition. Using the formalism of generalized recycling model, we introduce a new parameter, ‘recycling ratio’, to quantify the process gas recycling for specific process conditions. The model takes into account the ion flux to the target, the amount of gas available, and the amount of gas required for sustaining the discharge. We show that this parameter describes the relation between the gas recycling and the discharge current density. As a test case, we discuss the pressure and voltage driven transitions by changing the gas composition when adding Ne into the discharge. We propose that standard Ar HiPIMS discharges operated with significant gas recycling do not require Ne to increase the carbon ionization.

Thromboprophylaxis for Patients with High-risk Atrial Fibrillation and Flutter Discharged from the Emergency Department

Directory of Open Access Journals (Sweden)

E. Margaret Warton

2018-02-01

Full Text Available Introduction: Many patients with atrial fibrillation or atrial flutter (AF/FL who are high risk for ischemic stroke are not receiving evidence-based thromboprophylaxis. We examined anticoagulant prescribing within 30 days of receiving dysrhythmia care for non-valvular AF/FL in the emergency department (ED. Methods: This prospective study included non-anticoagulated adults at high risk for ischemic stroke (ATRIA score ≥7 who received emergency AF/FL care and were discharged home from seven community EDs between May 2011 and August 2012. We characterized oral anticoagulant prescribing patterns and identified predictors of receiving anticoagulants within 30 days of the index ED visit. We also describe documented reasons for withholding anticoagulation. Results: Of 312 eligible patients, 128 (41.0% were prescribed anticoagulation at ED discharge or within 30 days. Independent predictors of anticoagulation included age (adjusted odds ratio [aOR] 0.89 per year, 95% confidence interval [CI] 0.82–0.96; ED cardiology consultation (aOR 1.89, 95% CI [1.10–3.23]; and failure of sinus restoration by time of ED discharge (aOR 2.65, 95% CI [1.35–5.21]. Reasons for withholding anticoagulation at ED discharge were documented in 139 of 227 cases (61.2%, the most common of which were deferring the shared decision-making process to the patient’s outpatient provider, perceived bleeding risk, patient refusal, and restoration of sinus rhythm. Conclusion: Approximately 40% of non-anticoagulated AF/FL patients at high risk for stroke who presented for emergency dysrhythmia care were prescribed anticoagulation within 30 days. Physicians were less likely to anticoagulate older patients and those with ED sinus restoration. Opportunities exist to improve rates of thromboprophylaxis in this high-risk population.

Impurity transport model for the normal confinement and high density H-mode discharges in Wendelstein 7-AS

International Nuclear Information System (INIS)

Ida, K; Burhenn, R; McCormick, K; Pasch, E; Yamada, H; Yoshinuma, M; Inagaki, S; Murakami, S; Osakabe, M; Liang, Y; Brakel, R; Ehmler, H; Giannone, L; Grigull, P; Knauer, J P; Maassberg, H; Weller, A

2003-01-01

An impurity transport model based on diffusivity and the radial convective velocity is proposed as a first approach to explain the differences in the time evolution of Al XII (0.776 nm), Al XI (55 nm) and Al X (33.3 nm) lines following Al-injection by laser blow-off between normal confinement discharges and high density H-mode (HDH) discharges. Both discharge types are in the collisional regime for impurities (central electron temperature is 0.4 keV and central density exceeds 10 20 m -3 ). In this model, the radial convective velocity is assumed to be determined by the radial electric field, as derived from the pressure gradient. The diffusivity coefficient is chosen to be constant in the plasma core but is significantly larger in the edge region, where it counteracts the high local values of the inward convective velocity. Under these conditions, the faster decay of aluminium in HDH discharges can be explained by the smaller negative electric field in the bulk plasma, and correspondingly smaller inward convective velocity, due to flattening of the density profiles

The Sensory Components of High-Capacity Iconic Memory and Visual Working Memory

OpenAIRE

Bradley, Claire; Pearson, Joel

2012-01-01

Early visual memory can be split into two primary components: a high-capacity, short-lived iconic memory followed by a limited-capacity visual working memory that can last many seconds. Whereas a large number of studies have investigated visual working memory for low-level sensory features, much research on iconic memory has used more “high-level” alphanumeric stimuli such as letters or numbers. These two forms of memory are typically examined separately, despite an intrinsic overlap in their...

The sensory components of high-capacity iconic memory and visual working memory

OpenAIRE

Claire eBradley; Claire eBradley; Joel ePearson

2012-01-01

Early visual memory can be split into two primary components: a high-capacity, short-lived iconic memory followed by a limited-capacity visual working memory that can last many seconds. Whereas a large number of studies have investigated visual working memory for low-level sensory features, much research on iconic memory has used more high-level alphanumeric stimuli such as letters or numbers. These two forms of memory are typically examined separately, despite an intrinsic overlap in their c...

Closed cycle electric discharge laser design investigation

Science.gov (United States)

Baily, P. K.; Smith, R. C.

1978-01-01

Closed cycle CO2 and CO electric discharge lasers were studied. An analytical investigation assessed scale-up parameters and design features for CO2, closed cycle, continuous wave, unstable resonator, electric discharge lasing systems operating in space and airborne environments. A space based CO system was also examined. The program objectives were the conceptual designs of six CO2 systems and one CO system. Three airborne CO2 designs, with one, five, and ten megawatt outputs, were produced. These designs were based upon five minute run times. Three space based CO2 designs, with the same output levels, were also produced, but based upon one year run times. In addition, a conceptual design for a one megawatt space based CO laser system was also produced. These designs include the flow loop, compressor, and heat exchanger, as well as the laser cavity itself. The designs resulted in a laser loop weight for the space based five megawatt system that is within the space shuttle capacity. For the one megawatt systems, the estimated weight of the entire system including laser loop, solar power generator, and heat radiator is less than the shuttle capacity.

Combustion of methane-oxygen and methane-oxygen-CFC mixtures initiated by a high-current slipping surface discharge

International Nuclear Information System (INIS)

Kossyi, I.A.; Silakov, V.P.; Tarasova, N.M.

2001-01-01

Results are presented from experimental studies of the destruction of chlorofluorocarbon (CF 2 Cl 2 ) molecules in a methane-oxygen (air) gas mixture whose combustion is initiated by a high-current slipping surface discharge. It is found that a three-component CH 4 + O 2 (air)+ CF 2 Cl 2 gas mixture (even with a considerable amount of the third component) demonstrates properties of explosive combustion involving chain reactions that are typical of two-component CH 4 + O 2 mixtures. Experiments show the high degree of destruction (almost complete decomposition) of chlorofluorocarbons contained in the mixture during one combustion event. The combustion dynamics is studied. It is shown that the combustion initiated by a slipping surface discharge has a number of characteristic features that make it impossible to identify the combustion dynamics with the formation of a combustion or detonation wave. The features of the effects observed can be related to intense UV radiation produced by a pulsed high-current surface discharge

High-Capacity, High-Voltage Composite Oxide Cathode Materials

Science.gov (United States)

Hagh, Nader M.

2015-01-01

This SBIR project integrates theoretical and experimental work to enable a new generation of high-capacity, high-voltage cathode materials that will lead to high-performance, robust energy storage systems. At low operating temperatures, commercially available electrode materials for lithium-ion (Li-ion) batteries do not meet energy and power requirements for NASA's planned exploration activities. NEI Corporation, in partnership with the University of California, San Diego, has developed layered composite cathode materials that increase power and energy densities at temperatures as low as 0 degC and considerably reduce the overall volume and weight of battery packs. In Phase I of the project, through innovations in the structure and morphology of composite electrode particles, the partners successfully demonstrated an energy density exceeding 1,000 Wh/kg at 4 V at room temperature. In Phase II, the team enhanced the kinetics of Li-ion transport and electronic conductivity at 0 degC. An important feature of the composite cathode is that it has at least two components that are structurally integrated. The layered material is electrochemically inactive; however, upon structural integration with a spinel material, the layered material can be electrochemically activated and deliver a large amount of energy with stable cycling.

Moisture buffering capacity of highly absorbing materials

Energy Technology Data Exchange (ETDEWEB)

Cerolini, S.; D' Orazio, M.; Stazi, A. [Department of Architecture, Construction and Structures (DACS), Faculty of Engineering, Polytechnic University of Marche, Via Brecce Bianche, 60100 Ancona (Italy); Di Perna, C. [Department of Energetics, Faculty of Engineering, Polytechnic University of Marche, Via Brecce Bianche, 60100 Ancona (Italy)

2009-02-15

This research investigates the possibility to use highly absorbing materials to dampen indoor RH% variations. The practical MBV of sodium polyacrylate, cellulose-based material, perlite and gypsum is evaluated for a daily cyclic exposure that alternates high (75%) and low (33%) RH% levels for 8 h and 16 h, respectively. The adjustment velocity to RH% variations and the presence of hysteretic phenomena are also presented. The cellulose-based material proves to be the most suitable for moisture buffering applications. Starting from this material's properties, the effect of thickness, vapour resistance factor ({mu}) and mass surface exchange coefficient (Z{sub v}) on sorption capacity is evaluated by the use of a numerical model. (author)

Subnanosecond breakdown development in high-voltage pulse discharge: Effect of secondary electron emission

Science.gov (United States)

Alexandrov, A. L.; Schweigert, I. V.; Zakrevskiy, Dm. E.; Bokhan, P. A.; Gugin, P.; Lavrukhin, M.

2017-10-01

A subnanosecond breakdown in high-voltage pulse discharge may be a key tool for superfast commutation of high power devices. The breakdown in high-voltage open discharge at mid-high pressure in helium was studied in experiment and in kinetic simulations. The kinetic model of electron avalanche development was constructed, based on PIC-MCC simulations, including dynamics of electrons, ions and fast helium atoms, produced by ions scattering. Special attention was paid to electron emission processes from cathode, such as: photoemission by Doppler-shifted resonant photons, produced in excitation processes involving fast atoms; electron emission by ions and fast atoms bombardment of cathode; the secondary electron emission (SEE) by hot electrons from bulk plasma. The simulations show that the fast atoms accumulation is the main reason of emission growth at the early stage of breakdown, but at the final stage, when the voltage on plasma gap diminishes, namely the SEE is responsible for subnanosecond rate of current growth. It was shown that the characteristic time of the current growth can be controlled by the SEE yield. The influence of SEE yield for three types of cathode material (titanium, SiC, and CuAlMg-alloy) was tested. By changing the pulse voltage amplitude and gas pressure, the area of existence of subnanosecond breakdown is identified. It is shown that in discharge with SiC and CuAlMg-alloy cathodes (which have enhanced SEE) the current can increase with a subnanosecond characteristic time value as small as τs = 0.4 ns, for the pulse voltage amplitude of 5÷12 kV. An increase of gas pressure from 15 Torr to 30 Torr essentially decreases the time of of current front growth, whereas the pulse voltage variation weakly affects the results.

A report on the aquatic dilution experiment carried out at discharge canal, KGS site

International Nuclear Information System (INIS)

Reji, T.K.; Nayak, P.D.; Sudhakar, J.; Ajith, T.L.; Vishnu, M.S.; Ravi, P.M.; James, J.P.; Joshi, R.M.; Naik, S.B.; Kudtharkar, A.M.; Gaonkar, S.M.; Verma, P.C.; Datta, D.; Dahiya, Sudhir; Brijkumar; Datta, Maduparna; Sajeevan, G.

2009-08-01

Under Nuclear Power Corporation of India Limited (NPCIL), three units of (each of capacity 220MWe) Nuclear Power Stations are operational and one unit of similar capacity is under advanced stage of construction at Kaiga site. The radioactive liquid effluents generated in the plant are diluted with Condenser Coolant Water Stream (CCW) which is then discharged into Kadra reservoir through an artificially made discharge canal. The basic objective of the present study is to estimate the Dilution Factors at various locations of discharge canal and to understand the process of dilution and dispersion of radioactive effluent in the discharge canal. The strategy of the experiment involved the collection of samples from discharge canal lengthwise, breadth wise and depth wise immediately after the routine release of one of the batches of effluent stream into the CCW stream. No additional activity was released for the purpose of this experiment. The study compared the experimentally obtained Dilution Factor with that calculated based on the flow rates of CCW pumps and active liquid effluent discharge pumps. In the present conditions of experiment, Dilution Factor, based on flow rates of CCW pumps and Liquid Effluent Discharge pump, works out to be 8.11 E -05 while experimentally observed Mean Dilution Factor in the discharge canal works out to be (7.75±2.15) E-05. Hence this experiment clearly demonstrate the validity of the method of calculating dilution factor based on the flow rates of CCW line and that of Effluent discharge pump. The data analysis indicates that mass flow seems to be the major process of dispersion in the discharge canal. The tritium activity was found to be moving faster in the midstream as compared to that near the shore. The conclusions are drawn purely based on experimental results. This experimental data can be used for validation of aquatic dispersion models. (author)

Synthesis and characterization of high-density LiFePO{sub 4}/C composites as cathode materials for lithium-ion batteries

Energy Technology Data Exchange (ETDEWEB)

Chang Zhaorong [College of Chemistry and Environmental Science, Henan Normal University, Xinxiang 453007 (China)], E-mail: czr_56@163.com; Lv Haojie; Tang Hongwei; Li Huaji [College of Chemistry and Environmental Science, Henan Normal University, Xinxiang 453007 (China); Yuan Xiaozi; Wang Haijiang [Institute for Fuel Cell Innovation, National Research Council of Canada, Vancouver, BC, V6T 1W5 (Canada)

2009-08-01

To achieve a high-energy-density lithium electrode, high-density LiFePO{sub 4}/C composite cathode material for a lithium-ion battery was synthesized using self-produced high-density FePO{sub 4} as a precursor, glucose as a C source, and Li{sub 2}CO{sub 3} as a Li source, in a pipe furnace under an atmosphere of 5% H{sub 2}-95% N{sub 2}. The structure of the synthesized material was analyzed and characterized by X-ray diffraction (XRD) and scanning electron microscope (SEM). The electrochemical properties of the synthesized LiFePO{sub 4}/carbon composite were investigated by cyclic voltammetry (CV) and the charge/discharge process. The tap-density of the synthesized LiFePO{sub 4}/carbon composite powder with a carbon content of 7% reached 1.80 g m{sup -3}. The charge/discharge tests show that the cathode material has initial charge/discharge capacities of 190.5 and 167.0 mAh g{sup -1}, respectively, with a volume capacity of 300.6 mAh cm{sup -3}, at a 0.1C rate. At a rate of 5C, the LiFePO{sub 4}/carbon composite shows a high discharge capacity of 98.3 mAh g{sup -1} and a volume capacity of 176.94 mAh cm{sup -3}.

High-capacity, selective solid sequestrants for innovative chemical separation: Inorganic ion exchange approach

International Nuclear Information System (INIS)

Bray, L.

1995-01-01

The approach of this task is to develop high-capacity, selective solid inorganic ion exchangers for the recovery of cesium and strontium from nuclear alkaline and acid wastes. To achieve this goal, Pacific Northwest Laboratories (PNL) is collaborating with industry and university participants to develop high capacity, selective, solid ion exchangers for the removal of specific contaminants from nuclear waste streams

Discharge lamp technologies

Energy Technology Data Exchange (ETDEWEB)

Dakin, J. [GE Lighting, Cleveland, OH (United States)

1994-12-31

This talk is an overview of discharge lamp technology commonly employed in general lighting, with emphasis on issues pertinent to lighting for plant growth. Since the audience is primarily from the plant growth community, and this begins the light source part of the program, we will start with a brief description of the discharge lamps. Challenges of economics and of thermal management make lamp efficiency a prime concern in controlled environment agriculture, so we will emphasize science considerations relating to discharge lamp efficiency. We will then look at the spectra and ratings of some representative lighting products, and conclude with a discussion of technological advance. A general overview of discharge lighting technology can be found in the book of Waymouth (1971). A recent review of low pressure lighting discharge science is found in Dakin (1991). The pioneering paper of Reiling (1964) provides a good introduction to metal halide discharges. Particularly relevant to lighting for plant growth, a recent and thorough treatment of high pressure Na lamps is found in the book by deGroot and vanVliet (1986). Broad practical aspects of lighting application are thoroughly covered in the IES Lighting Handbook edited by Kaufman (1984).

High current capacity electrical connector

International Nuclear Information System (INIS)

Bettis, E.S.; Watts, H.L.

1976-01-01

An electrical connector is provided for coupling high current capacity electrical conductors such as copper busses or the like. The connector is arranged in a ''sandwiched'' configuration in which a conductor plate contacts the busses along major surfaces clamped between two stainless steel backing plates. The conductor plate is provided with contact buttons in a spaced array such that the caps of the buttons extend above the conductor plate surface to contact the busses. When clamping bolts provided through openings in the sandwiched arrangement are tightened, Belleville springs provided under the rim of each button cap are compressed and resiliently force the caps into contact with the busses' contacting surfaces to maintain a predetermined electrical contact area provided by the button cap tops. The contact area does not change with changing thermal or mechanical stresses applied to the coupled conductors

On transition from diffuse mode to the constricted one with high-current cathode spot in overvoltage open discharge in D2

Science.gov (United States)

Akishev, Yu S.; Karalnik, V. B.; Medvedev, M. A.; Petryakov, A. V.; Trushkin, N. I.; Shafikov, A. G.

2017-11-01

So called “open discharges” in a narrow gap between the solid cathode and grid anode are widely used for generation of the pulsed high-current electron beams with energy up to 100 keV. The need to get high-energy e-beams leads to the necessity in using of strong overvoltage of the short gas gap with the reduced electric field of the order of 105 Td or higher. The discharge under strong overvoltage is unstable and tends to transit into high-current regime with low voltage. In the case of the open discharge in D2 at low pressure (about 0.5-2 Torr) and powered by stepwise voltage with amplitude up to 25 kV we revealed that this discharge exhibits two diffuse regimes which follow one by one and finally transits into the constricted mode with formation of high-current spots on the cathode. The physical properties of these gas discharge regimes have been explored in detail with the usage of the fast multi-frame camera synchronized with the current and voltage of discharge. Our findings promote more insight into physics of the overvoltage open discharge generating the e-beams with energy up to 25 keV.

High-capacity neutron activation analysis facility

International Nuclear Information System (INIS)

Hochel, R.C.; Bowman, W.W.; Zeh, C.W.

1980-01-01

A high-capacity neutron activation analysis facility, the Reactor Activation Facility, was designed and built and has been in operation for about a year at one of the Savannah River Plant's production reactors. The facility determines uranium and about 19 other elements in hydrogeochemical samples collected in the National Uranium Resource Evaluation program, which is sponsored and funded by the United States Department of Energy, Grand Junction Office. The facility has a demonstrated average analysis rate of over 10,000 samples per month, and a peak rate of over 16,000 samples per month. Uranium is determined by cyclic activation and delayed neutron counting of the U-235 fission products; other elements are determined from gamma-ray spectra recorded in subsequent irradiation, decay, and counting steps. The method relies on the absolute activation technique and is highly automated for round-the-clock unattended operation

Discharge cleaning for a tokamak

International Nuclear Information System (INIS)

Ishii, Shigeyuki

1983-01-01

Various methods of discharge cleaning for tokamaks are described. The material of the first walls of tokamaks is usually stainless steel, inconel, titanium and so on. Hydrogen is exclusively used as the discharge gas. Glow discharge cleaning (GDC), Taylor discharge cleaning (TDC), and electron cyclotron resonance discharge cleaning (ECR-DC) are discussed in this paper. The cleaning by GDC is made by moving a movable anode to the center of a tokamak vassel. Taylor found the good cleaning effect of induced discharge by high pressure and low power discharge. This is called TDC. When the frequency of high frequency discharge in a magnetic field is equal to that of the electron cyclotron resonance, the break down potential is lowered if the pressure is sufficiently low. The ECR-CD is made by using this effect. In TDC and ECR-DC, the electron temperature, which has a close relation to the production rate of H 0 , can be controlled by the pressure. In GDC, the operating pressure was improved by the radio frequency glow (RG) method. However, there is still the danger of arcing. In case of GDC and ECR-DC, the position of plasma can be controlled, but not in case of TDC. The TDC is accepted by most of takamak devices in the world. (Kato, T.)

High Reversibility of Soft Electrode Materials in All-solid-state Batteries

Directory of Open Access Journals (Sweden)

Atsushi eSakuda

2016-05-01

Full Text Available All-solid-state batteries using inorganic solid electrolytes (SEs are considered to be ideal batteries for electric vehicles (EVs and plug-in hybrid electric vehicles (PHEVs because they are potentially safer than conventional lithium-ion batteries (LIBs. In addition, all-solid-state batteries are expected to have long battery lives owing to the inhibition of chemical side reactions because only lithium ions move through the typically used inorganic SEs. The development of high-energy (more than 300 Wh kg-1 secondary batteries has been eagerly anticipated for years. The application of high-capacity electrode active materials is essential for fabricating such batteries. Recently, we proposed metal polysulfides as new electrode materials. These materials show higher conductivity and density than sulfur, which is advantageous for fabricating batteries with relatively higher energy density. Lithium niobium sulfides, such as Li3NbS4, have relatively high density, conductivity, and rate capability among metal polysulfide materials, and batteries with these materials have capacities high enough to potentially exceed the gravimetric energy density of conventional LIBs.Favorable solid-solid contact between the electrode and electrolyte particles is a key factor for fabricating high performance all-solid-state batteries. Conventional oxide-based positive electrode materials tend to be given rise to cracks during fabrication and/or charge-discharge processes. Here we report all-solid-state cells using lithium niobium sulfide as a positive electrode material, where favorable solid-solid contact was established by using lithium sulfide electrode materials because of their high processability. Cracks were barely observed in the electrode particles in the all-solid-state cells before or after charging and discharging with a high capacity of approx. 400 mAh g-1, suggesting that the lithium niobium sulfide electrode charged and discharged without experiencing

Sulfate passivation in the lead-acid system as a capacity limiting process

Energy Technology Data Exchange (ETDEWEB)

Kappus, W.; Winsel, A.

1982-09-15

Calculations of the discharge capacity of Pb and PbO/sub 2/ electrodes as a function of various parameters are presented. They are based on the solution-precipitation mechanism for the discharge reaction and its formulation by Winsel et al. A logarithmic pore size distribution is used to fit experimental porosigrams of Pb and PbO/sub 2/ electrodes. Based on this pore size distribution the capacity is calculated as a function of current, BET surface, and porosity of the PbSO/sub 4/ diaphragm. The PbSO/sub 4/ supersaturation as the driving force of the diffusive transport is chosen as a free parameter.

Improvement of ozone yield by a multi-discharge type ozonizer using superposition of silent discharge plasma

International Nuclear Information System (INIS)

Song, Hyun-Jig; Chun, Byung-Joon; Lee, Kwang-Sik

2004-01-01

In order to improve ozone generation, we experimentally investigated the silent discharge plasma and ozone generation characteristics of a multi-discharge type ozonizer. Ozone in a multi-discharge type ozonizer is generated by superposition of a silent discharge plasma, which is simultaneously generated in separated discharge spaces. A multi-discharge type ozonizer is composed of three different kinds of superposed silent discharge type ozonizers, depending on the method of applying power to each electrode. We observed that the discharge period of the current pulse for a multi discharge type ozonizer can be longer than that of silent discharge type ozonizer with two electrodes and one gap. Hence, ozone generation is improved up to 17185 ppm and 783 g/kwh in the case of the superposed silent discharge type ozonizer for which an AC high voltages with a 180 .deg. phase difference were applied to the internal electrode and the external electrode, respectively, with the central electrode being grounded.

Li-rich layer-structured cathode materials for high energy Li-ion batteries

Science.gov (United States)

Li, Liu; Lee, Kim Seng; Lu, Li

2014-08-01

Li-rich layer-structured xLi2MnO3 ṡ (1 - x)LiMO2 (M = Mn, Ni, Co, etc.) materials have attracted much attention due to their extraordinarily high reversible capacity as the cathode material in Li-ion batteries. To better understand the nature of this type of materials, this paper reviews history of development of the Li-rich cathode materials, and provides in-depth study on complicated crystal structures and reaction mechanisms during electrochemical charge/discharge cycling. Despite the fabulous capability at low rate, several drawbacks still gap this type of high-capacity cathode materials from practical applications, for instance the large irreversible capacity loss at first cycle, poor rate capability, severe voltage decay and capacity fade during electrochemical charge/discharge cycling. This review will also address mechanisms for these inferior properties and propose various possible solutions to solve above issues for future utilization of these cathode materials in commercial Li-ion batteries.

Effects of discharge parameters on the micro-hollow cathode sustained glow discharge

Science.gov (United States)

Shoujie, HE; Peng, WANG; Jing, HA; Baoming, ZHANG; Zhao, ZHANG; Qing, LI

2018-05-01

The effects of parameters such as pressure, first anode radius, and the cavity diameter on the micro-hollow cathode sustained glow discharge are investigated by using a two-dimensional self-consistent fluid model in pure argon. The results indicate that the three parameters influence the discharge in the regions inside and outside of the cavity. Under a fixed voltage on each electrode, a larger volume of high density plasma can be produced in the region between the first and the second anodes by selecting the appropriate pressure, the higher first anode, and the appropriate cavity diameter. As the pressure increases, the electron density inside the hollow cathode, the high density plasma volume between the first anode and second anodes, and the radial electric field in the cathode cavity initially increase and subsequently decrease. As the cavity diameter increases, the high-density plasma volume between the first and second anodes initially increases and subsequently decreases; whereas the electron density inside the hollow cathode decreases. As the first anode radius increases, the electron density increases both inside and outside of the cavity. Moreover, the increase of the electron density is more obvious in the microcathode sustained region than in the micro cavity region. The results reveal that the discharge inside the cavity interacts with that outside the cavity. The strong hollow cathode effect and the high-density plasma inside the cavity favor the formation of a sustained discharge between the first anode and the second anodes. Results also show that the radial boundary conditions exert a considerably weaker influence on the discharge except for a little change in the region close to the radial boundary.

Definition of a high intensity metal halide discharge reference lamp

NARCIS (Netherlands)

Stoffels, W.W.; Baede, A.H.F.M.; Mullen, van der J.J.A.M.; Haverlag, M.; Zissis, G.

2006-01-01

The design of a ref. metal halide discharge lamp is presented. This lamp is meant as a common study object for researchers working on metal halide discharge lamps, who by using the same design will be able to compare results between research groups, diagnostic techniques and numerical models. The

Three-dimensional carbon network confined antimony nanoparticle anodes for high-capacity K-ion batteries.

Science.gov (United States)

Han, Chunhua; Han, Kang; Wang, Xuanpeng; Wang, Chenyang; Li, Qi; Meng, Jiashen; Xu, Xiaoming; He, Qiu; Luo, Wen; Wu, Liming; Mai, Liqiang

2018-04-19

Antimony (Sb) represents a promising anode for K-ion batteries (KIBs) due to its high theoretical capacity and suitable working voltage. However, the large volume change that occurs in the potassiation/depotassiation process can lead to severe capacity fading. Herein, we report a high-capacity anode material by in situ confining Sb nanoparticles in a three-dimensional carbon framework (3D SbNPs@C) via a template-assisted freeze-drying treatment and subsequent carbothermic reduction. The as-prepared 3D SbNPs@C hybrid material delivers high reversible capacity and good cycling stability when used as the anode for KIBs. Furthermore, cyclic voltammetry and in situ X-ray diffraction analysis were performed to reveal the intrinsic mechanism of a K-Sb alloying reaction. Therefore, this work is of great importance to understand the electrochemical process of the Sb-based alloying reaction and will pave the way for the exploration of high performance KIB anode materials.

Angina - discharge

Science.gov (United States)

Chest pain - discharge; Stable angina - discharge; Chronic angina - discharge; Variant angina - discharge; Angina pectoris - discharge; Accelerating angina - discharge; New-onset angina - discharge; Angina-unstable - discharge; ...

Chaos in gas discharges

International Nuclear Information System (INIS)

Piel, A.

1993-01-01

Many gas discharges exhibit natural oscillations which undergo a transition from regular to chaotic behavior by changing an experimental parameter or by applying external modulation. Besides several isolated investigations, two classes of discharge phenomena have been studied in more detail: ionization waves in medium pressure discharges and potential relaxation oscillations in filament cathode discharges at very low pressure. The latter phenomenon will be discussed by comparing experimental results from different discharge arrangements with particle-in-cell simulations and with a model based on the van-der-Pol equation. The filament cathode discharge has two stable modes of operation: the low current anode-glow-mode and the high current temperature-limited-mode, which form the hysteresis curve in the I(U) characteristics. Close to the hysteresis point of the AGM periodic relaxation oscillations occur. The authors demonstrate that the AGM can be understood by ion production in the anode layer, stopping of ions by charge exchange, and trapping in the virtual cathode around the filament. The relaxation oscillations consist of a slow filling phase and a rapid phase that invokes formation of an unstable double-layer, current-spiking, and ion depletion from the cathodic plasma. The relaxation oscillations can be mode-locked by external modulation. Inside a mode-locked state, a period doubling cascade is observed at high modulation degree

High Capacity Radio over Fiber Transmission Links

DEFF Research Database (Denmark)

Caballero Jambrina, Antonio

. This achievement has satisfied the requirements on transmission robustness and high capacity of next generation hybrid optical fibre-wireless networks. One important contribution of this thesis is the novel concept of photonic downconversion with free-running pulsed laser source for phase modulated Radio-over-Fiber......This thesis expands the state-of-the-art on the detection of high speed wireless signals using optics. Signal detection at speeds over 1 Gbps at carrier Radio Frequency (RF) ranging from 5 GHz to 100 GHz have been achieved by applying novel concepts on optical digital coherent receivers......-wave frequencies at carrier frequencies exceeding 60 GHz, using photonic baseband technologies. For signal generation, high spectral-efficient optical modulation technologies are used together with optical heterodyning. In the detection side, the mm-wave signal is modulated in the optical domain and received using...

Analysis of experimental routines of high enthalpy steam discharge in subcooled water

Energy Technology Data Exchange (ETDEWEB)

Pacheco, Rafael R., E-mail: Rafael.rade@ctmsp.mar.mil.br [Centro Tecnologico da Marinha em Sao Paulo (CTMSP), SP (Brazil); Andrade, Delvonei A., E-mail: delvonei@ipen.br [Instituto de Pesquisas Energeticas e Nucleares (IPEN/CNEN-SP), Sao Paulo, SP (Brazil)

2015-07-01

The discharge of high enthalpy steam through safety release valves out from pressurizers in PWR's needs to be condensed in order to allow the treatment of possibly present radwaste within. The Direct Contact Condensation is used in a relief tank to achieve the condensation. Care must be taken to avoid the bypass of the steam through the subcooled water, what would increase the peak of pressure and the necessity of structural reinforcement of the relief tank. An experiment to determine the optimal set up of the relief tank components and their characteristics (type of sprinkler, level of water, volume of tank, discharge direction, pressure in the pressurizer among others) was executed in 2000, in the CTE 150 facility, in CTMSP. In a total, 144 routines varying its components and characteristics were made, although no comprehensive analysis of its results were yet made, since the mass of data was too big to be readily analyzed. In order to comprehensively analyze it, a VBA program is being made to compile and graphically represent the mass of data. The current state of this program allowed conclusions over the peak pressure, adiabatic assumption of the experiment, and the quality of the steam generated due to the discharge. (author)

Analysis of experimental routines of high enthalpy steam discharge in subcooled water

International Nuclear Information System (INIS)

Pacheco, Rafael R.; Andrade, Delvonei A.

2015-01-01

The discharge of high enthalpy steam through safety release valves out from pressurizers in PWR's needs to be condensed in order to allow the treatment of possibly present radwaste within. The Direct Contact Condensation is used in a relief tank to achieve the condensation. Care must be taken to avoid the bypass of the steam through the subcooled water, what would increase the peak of pressure and the necessity of structural reinforcement of the relief tank. An experiment to determine the optimal set up of the relief tank components and their characteristics (type of sprinkler, level of water, volume of tank, discharge direction, pressure in the pressurizer among others) was executed in 2000, in the CTE 150 facility, in CTMSP. In a total, 144 routines varying its components and characteristics were made, although no comprehensive analysis of its results were yet made, since the mass of data was too big to be readily analyzed. In order to comprehensively analyze it, a VBA program is being made to compile and graphically represent the mass of data. The current state of this program allowed conclusions over the peak pressure, adiabatic assumption of the experiment, and the quality of the steam generated due to the discharge. (author)

Ion transport analysis of a high beta-poloidal JT-60U discharge

International Nuclear Information System (INIS)

Horton, W.; Tajima, T.; Dong, J.-Q.; Kim, J.-Y.; Kishimoto, Y.

1997-01-01

The high beta-poloidal discharge number 17110 in JT-60U (JT-60 Team, IAEA, Vienna, 1993) that developes an internal transport barrier is analysed for the transport of ion energy and momentum. First, the classical ion temperature gradient stability properties are calculated in the absence of sheared plasma flows to establish the L-mode transport level prior to the emergence of the transport barrier. Then the evolving toroidal and poloidal velocity profiles reported by Koide et al (1994 Phys. Rev. Lett. 72 3662) are used to show how the sheared mass flows control the stability and transport. Coupled energy-momentum transport equations predict the creation of a transport barrier. The balance of the steep ion temperature gradient against the magnetic shear and sheared mass flow is calculated for the profiles in the 17110 discharge. (Author)

High current density toroidal pinch discharges with weak toroidal fields

International Nuclear Information System (INIS)

Brunsell, P.; Brzozowski, J.; Drake, J.R.; Hellblom, G.; Kaellne, E.; Mazur, S.; Nordlund, P.

1990-01-01

Toroidal discharges in the ultralow q regime (ULQ) have been studied in the rebuilt Extrap TI device. ULQ discharges are sustained for pulse lengths exceeding 1 ms, which corresponds to more than 10 resistiv shell times. Values for the safety factor at the vacuum vessel wall are between rational values: 1/(n+1) -2 . The magnetic fluctuation level increases during the transition between rational values of q(a). For very low values of q(a), the loop voltage increases and the toroidal field development in the discharge exhibits the characteristic behaviour of the setting-up phase of a field reversed pinch. (author) 1 ref., 2 figs., 1 tab

High performance Li3V2(PO4)3/C composite cathode material for lithium ion batteries studied in pilot scale test

International Nuclear Information System (INIS)

Chen Zhenyu; Dai Changsong; Wu Gang; Nelson, Mark; Hu Xinguo; Zhang Ruoxin; Liu Jiansheng; Xia Jicai

2010-01-01

Li 3 V 2 (PO 4 ) 3 /C composite cathode material was synthesized via carbothermal reduction process in a pilot scale production test using battery grade raw materials with the aim of studying the feasibility for their practical applications. XRD, FT-IR, XPS, CV, EIS and battery charge-discharge tests were used to characterize the as-prepared material. The XRD and FT-IR data suggested that the as-prepared Li 3 V 2 (PO 4 ) 3 /C material exhibits an orderly monoclinic structure based on the connectivity of PO 4 tetrahedra and VO 6 octahedra. Half cell tests indicated that an excellent high-rate cyclic performance was achieved on the Li 3 V 2 (PO 4 ) 3 /C cathodes in the voltage range of 3.0-4.3 V, retaining a capacity of 95% (96 mAh/g) after 100 cycles at 20C discharge rate. The low-temperature performance of the cathode was further evaluated, showing 0.5C discharge capacity of 122 and 119 mAh/g at -25 and -40 o C, respectively. The discharge capacity of graphite//Li 3 V 2 (PO 4 ) 3 batteries with a designed battery capacity of 14 Ah is as high as 109 mAh/g with a capacity retention of 92% after 224 cycles at 2C discharge rates. The promising high-rate and low-temperature performance observed in this work suggests that Li 3 V 2 (PO 4 ) 3 /C is a very strong candidate to be a cathode in a next-generation Li-ion battery for electric vehicle applications.

Hollow Carbon Nanofiber-Encapsulated Sulfur Cathodes for High Specific Capacity Rechargeable Lithium Batteries

KAUST Repository

Zheng, Guangyuan; Yang, Yuan; Cha, Judy J.; Hong, Seung Sae; Cui, Yi

2011-01-01

Sulfur has a high specific capacity of 1673 mAh/g as lithium battery cathodes, but its rapid capacity fading due to polysulfides dissolution presents a significant challenge for practical applications. Here we report a hollow carbon nanofiber

Activation of peroxydisulfate by gas-liquid pulsed discharge plasma to enhance the degradation of p-nitrophenol

Science.gov (United States)

Shang, Kefeng; Wang, Hao; Li, Jie; Lu, Na; Jiang, Nan; Wu, Yan

2017-06-01

Pulsed discharge in water and over water surfaces generates ultraviolet radiation, local high temperature, shock waves, and chemical reactive species, including hydroxyl radicals, hydrogen peroxide, and ozone. Pulsed discharge plasma (PDP) can oxidize and mineralize pollutants very efficiently, but high energy consumption restricts its application for industrial wastewater treatment. A novel method for improving the energy efficiency of wastewater treatment by PDP was proposed, in which peroxydisulfate (PDS) was added to wastewater and PDS was activated by PDP to produce more strong oxidizing radicals, including sulfate radicals and hydroxyl radicals, leading to a higher oxidation capacity for the PDP system. The experimental results show that the increase in solution conductivity slightly decreased the discharge power of the pulse discharge over the water surface. An increase in the discharge intensity improved the activation of PDS and therefore the degradation efficiency and energy efficiency of p-nitrophenol (PNP). An increase in the addition dosage of PDS greatly facilitated the degradation of PNP at a molar ratio of PDS to PNP of lower than 80:1, but the performance enhancement was no longer obvious at a dosage of more than 80:1. Under an applied voltage of 20 kV and a gas discharge gap of 2 mm, the degradation efficiency and energy efficiency of the PNP reached 90.7% and 45.0 mg kWh-1 for the plasma/PDS system, respectively, which was 34% and 18.0 mg kWh-1 higher than for the discharge plasma treatment alone. Analysis of the physical and chemical effects indicated that ozone and hydrogen peroxide were important for PNP degradation and UV irradiation and heat from the discharge plasma might be the main physical effects for the activation of PDS.

Comparing sulfur and oxygen isotope variability of sulfate in the Mississippi River during high and low discharge from 2009-2011

Science.gov (United States)

Killingsworth, B.; Kohl, I. E.; Bao, H.

2011-12-01

S and O isotope compositions of ocean and river sulfate, SO42-, reflect Earth surface processes and can thus be used to understand the Earth's dynamic past. It has been estimated that riverine SO42- is 22% evaporite (SO42-riv-evap), 11% oxidative weathering (SO42-riv-ow), and 54% atmospheric and agricultural pollution [1]. Two parameters are poorly constrained: 1) the ratio of SO42-riv-evap to SO42-riv-ow, and 2) the extent of human influence on SO42- flux. Furthermore, for isotopic modeling, natural riverine SO42- O and S isotope compositions, δ18OSO4-riv and δ34SSO4-riv, have large measured ranges (e.g. δ18OSO4-riv from -2% to +7% [2]) that are based on limited empirical data with variable and unconstrained influence from human activities. In the lower Mississippi River Basin (MRB) we have sampled river water SO42- biweekly since 2009. Our isotope dataset is used in conjunction with US Geological Survey and US Army Corps of Engineers SO42- concentration and river discharge data. In comparison to MRB low discharge periods, the periods of annual high water discharge are characterized by 1) a doubling in water discharge 2) a concomitant high MRB SO42- flux (>1100 kg/s) 3) an average SO42- concentration at 85% of the low discharge concentrations and 4) a more constrained variability of SO42- isotope composition. The δ18OSO4-riv ranges from +3.2% to +5.5% at high discharge and from +2.6% to +8.8% at low discharge. The δ34SSO4-riv ranges from -4.3% to -0.4 at high discharge and from -6.3% to -0.2% at low discharge. Atmospheric SO42- is estimated from 2009 National Atmospheric Deposition Program maps to contribute only ~10% of total MRB SO42-. We conclude that during annual high discharge a large river basin such as the MRB is less sensitive to variable sub-basin input and that average MRB SO42- isotope composition is best represented by a δ18OSO4-riv value of ~+4.0% and δ34SSO4-riv value of ~-3.0%. MRB SO42- concentration during high discharge is diluted less

High Discharge Energy Density at Low Electric Field Using an Aligned Titanium Dioxide/Lead Zirconate Titanate Nanowire Array.

Science.gov (United States)

Zhang, Dou; Liu, Weiwei; Guo, Ru; Zhou, Kechao; Luo, Hang

2018-02-01

Polymer-based capacitors with high energy density have attracted significant attention in recent years due to their wide range of potential applications in electronic devices. However, the obtained high energy density is predominantly dependent on high applied electric field, e.g., 400-600 kV mm -1 , which may bring more challenges relating to the failure probability. Here, a simple two-step method for synthesizing titanium dioxide/lead zirconate titanate nanowire arrays is exploited and a demonstration of their ability to achieve high discharge energy density capacitors for low operating voltage applications is provided. A high discharge energy density of 6.9 J cm -3 is achieved at low electric fields, i.e., 143 kV mm -1 , which is attributed to the high relative permittivity of 218.9 at 1 kHz and high polarization of 23.35 µC cm -2 at this electric field. The discharge energy density obtained in this work is the highest known for a ceramic/polymer nanocomposite at such a low electric field. The novel nanowire arrays used in this work are applicable to a wide range of fields, such as energy harvesting, energy storage, and photocatalysis.

Confinement and gas fueling in LHD limiter discharges

International Nuclear Information System (INIS)

Nishimura, K.; Kawahata, K.; Narihara, K.; Morisaki, T.; Masuzaki, S.; Sakakibara, S.; Tanaka, K.

2003-01-01

Plasma discharges in the Large Helical Device are normally open helical divertor discharges. To compare limiter discharges with open divertor discharges and to examine the role of the peripheral region, a radial movable limiter, whose head was made of carbon with high heat conductivity, was inserted into the plasma from the high field side (near the helical coil). The electron temperature was bounded well by the limiter. A high temperature gradient at the edge region was observed in both open divertor and limiter discharges. Formation of such a high temperature gradient led to good energy confinement even in the limiter discharges and an enhancement factor of 1.1±0.3 for International Stellarator Scaling 95 (ISS95) scaling was observed at every limiter position (0.75 ax =3.75 m prevents gas fueling by puffing

Lithiation Kinetics in High-Performance Porous Vanadium Nitride Nanosheet Anode

International Nuclear Information System (INIS)

Peng, Xiang; Li, Wan; Wang, Lei; Hu, Liangsheng; Jin, Weihong; Gao, Ang; Zhang, Xuming; Huo, Kaifu; Chu, Paul K.

2016-01-01

Vanadium nitride (VN) is promising in lithium ion battery (LIB) anode due to its high energy density, chemical stability, and corrosion resistivity. Herein, porous VN nanosheets are synthesized hydrothermally followed by an ammonia treatment. The porous nanosheets offer a large interfacial area between the electrode and electrolyte as well as short Li + diffusion path and consequently, the VN nanosheets electrode has high capacity and rate capability as an anode in LIB. The VN anode delivers a high reversible capacity of 455 mAh g −1 at a current density of 100 mA g −1 and it remains at 341 mAh g −1 when the current density is increased to 1 A g −1 . The charge transfer and Li + diffusion kinetics during the lithiation process is studied systematically. A highly stable SEI film is formed during the initial discharging-charging cycles to achieve a long cycle life and sustained capacity at a high level for 250 discharging-charging cycles without deterioration. This work demonstrates the preparation of high-performance LIB anode materials by a simple method and elucidates the lithiation kinetics.

Improvements on high voltage capacity and high temperature performances of Si-based Schottky potential barrier diode

International Nuclear Information System (INIS)

Wang Yongshun; Rui Li; Adnan Ghaffar; Wang Zaixing; Liu Chunjuan

2015-01-01

In order to improve the reverse voltage capacity and low junction temperature characteristics of the traditional silicon-based Schottky diode, a Schottky diode with high reverse voltage capacity and high junction temperature was fabricated using ion implantation, NiPt60 sputtering, silicide-forming and other major technologies on an N-type silicon epitaxial layer of 10.6–11.4 μm and (2.2–2.4) × 10 15 cm −3 doping concentration. The measurement results show that the junction temperature of the Schottky diode fabricated can reach 175 °C, that is 50 °C higher than that of the traditional one; the reverse voltage capacity V R can reach 112 V, that is 80 V higher than that of the traditional one; the leakage current is only 2 μA and the forward conduction voltage drop is V F = 0.71 V at forward current I F = 3 A. (semiconductor devices)

Missouri Work Zone Capacity : Results of Field Data Analysis

Science.gov (United States)

2011-06-01

This report presents the results of work zone field data analyzed on interstate highways in Missouri to determine : the mean breakdown and queue-discharge flow rates as measures of capacity. Several days of traffic data : collected at a work zone nea...

Dynamically Determining the Toll Plaza Capacity by Monitoring Approaching Traffic Conditions in Real-Time

Directory of Open Access Journals (Sweden)

Cheolsun Kim

2016-03-01

Full Text Available This study presents an analytical method for dynamically adjusting toll plaza capacity to cope with a sudden shift in demand. The proposed method uses a proxy measure developed using discharge rate observed at toll plazas and segment travel times measured by probe vehicles. The effectiveness of the method has been evaluated by analyzing the empirical data obtained from toll plazas in the San Francisco Bay Area before and after toll plaza capacity changed. Findings indicate that the estimated number of vehicles stored near the upstream of toll plaza based on discharge rate and their travel times can be used as a proxy measure for predicting the effect of changes in toll plaza capacity. The proposed model can aid government agencies to dynamically adjust the toll plaza capacity in response to a sudden shift in demand due to various situations of failure.

High Reversibility of “Soft” Electrode Materials in All-Solid-State Batteries

Energy Technology Data Exchange (ETDEWEB)

Sakuda, Atsushi, E-mail: a.sakuda@aist.go.jp; Takeuchi, Tomonari, E-mail: a.sakuda@aist.go.jp; Shikano, Masahiro; Sakaebe, Hikari; Kobayashi, Hironori [Department of Energy and Environment, Research Institute for Electrochemical Energy, National Institute of Advanced Industrial Science and Technology (AIST), Ikeda (Japan)

2016-05-10

All-solid-state batteries using inorganic solid electrolytes (SEs) are considered to be ideal batteries for electric vehicles and plug-in hybrid electric vehicles because they are potentially safer than conventional lithium-ion batteries (LIBs). In addition, all-solid-state batteries are expected to have long battery life owing to the inhibition of chemical side reactions because only lithium ions move through the typically used inorganic SEs. The development of high-energy density (more than 300 Wh kg{sup −1}) secondary batteries has been eagerly anticipated for years. The application of high-capacity electrode active materials is essential for fabricating such batteries. Recently, we proposed metal polysulfides as new electrode materials. These materials show higher conductivity and density than sulfur, which is advantageous for fabricating batteries with relatively higher energy density. Lithium niobium sulfides, such as Li{sub 3}NbS{sub 4}, have relatively high density, conductivity, and rate capability among metal polysulfide materials, and batteries with these materials have capacities high enough to potentially exceed the gravimetric-energy density of conventional LIBs. Favorable solid–solid contact between the electrode and electrolyte particles is a key factor for fabricating high performance all-solid-state batteries. Conventional oxide-based positive electrode materials tend to give rise to cracks during fabrication and/or charge–discharge processes. Here, we report all-solid-state cells using lithium niobium sulfide as a positive electrode material, where favorable solid–solid contact was established by using lithium sulfide electrode materials because of their high processability. Cracks were barely observed in the electrode particles in the all-solid-state cells before or after charging and discharging with a high capacity of approximately 400 mAh g{sup −1} suggesting that the lithium niobium sulfide electrode charged and discharged without

High Reversibility of “Soft” Electrode Materials in All-Solid-State Batteries

International Nuclear Information System (INIS)

Sakuda, Atsushi; Takeuchi, Tomonari; Shikano, Masahiro; Sakaebe, Hikari; Kobayashi, Hironori

2016-01-01

All-solid-state batteries using inorganic solid electrolytes (SEs) are considered to be ideal batteries for electric vehicles and plug-in hybrid electric vehicles because they are potentially safer than conventional lithium-ion batteries (LIBs). In addition, all-solid-state batteries are expected to have long battery life owing to the inhibition of chemical side reactions because only lithium ions move through the typically used inorganic SEs. The development of high-energy density (more than 300 Wh kg −1 ) secondary batteries has been eagerly anticipated for years. The application of high-capacity electrode active materials is essential for fabricating such batteries. Recently, we proposed metal polysulfides as new electrode materials. These materials show higher conductivity and density than sulfur, which is advantageous for fabricating batteries with relatively higher energy density. Lithium niobium sulfides, such as Li 3 NbS 4 , have relatively high density, conductivity, and rate capability among metal polysulfide materials, and batteries with these materials have capacities high enough to potentially exceed the gravimetric-energy density of conventional LIBs. Favorable solid–solid contact between the electrode and electrolyte particles is a key factor for fabricating high performance all-solid-state batteries. Conventional oxide-based positive electrode materials tend to give rise to cracks during fabrication and/or charge–discharge processes. Here, we report all-solid-state cells using lithium niobium sulfide as a positive electrode material, where favorable solid–solid contact was established by using lithium sulfide electrode materials because of their high processability. Cracks were barely observed in the electrode particles in the all-solid-state cells before or after charging and discharging with a high capacity of approximately 400 mAh g −1 suggesting that the lithium niobium sulfide electrode charged and discharged without experiencing

Wheelchair batteries. II: Capacity, sizing, and life.

Science.gov (United States)

Kauzlarich, J J

1990-01-01

The characteristics of lead-acid batteries for wheelchairs in terms of a new empirical equation for the capacity, application of the Palmgren-Miner Rule for sizing the battery, and the effect of depth of discharge on the life cycles is presented. A brief section about selecting an economical battery for an electric wheelchair is included.

Phase-pure β-NiMoO4 yolk-shell spheres for high-performance anode materials in lithium-ion batteries

International Nuclear Information System (INIS)

Ahn, Jee Hyun; Park, Gi Dae; Kang, Yun Chan; Lee, Jong-Heun

2015-01-01

Phase-pure β-NiMoO 4 yolk-shell spheres for lithium-ion battery anodes were prepared for the first time by one-pot spray pyrolysis, and their electrochemical properties were investigated. The yolk-shell-structured β-NiMoO 4 powders exhibited high initial discharge/charge capacities (1634/1253 mA h g −1 ) at a current density of 1000 mA g −1 . After 200 cycles, these powders exhibited a high discharge capacity of 1292 mA h g −1 , whereas the initial discharge capacity (1341 mA h g −1 ) of the filled structured NiMoO 4 powders was dramatically decreased to 479 mA h g −1 . The significant enhancement of the cycling performance of the β-NiMoO 4 powders with ultrafine crystallite size was attributed to the structural stability of the yolk-shell structure

Radio frequency glow discharge source with integrated voltage and current probes used for evaluation of discharge parameters

International Nuclear Information System (INIS)

Wilken, L.; Hoffmann, V.; Wetzig, K.

2006-01-01

A radio frequency (rf) Grimm-type glow discharge source for the chemical analysis of solid samples, with integrated voltage and current probes, was developed. All elements of a plasma equivalent circuit are determined from the measured current-voltage characteristics. The procedure is based on the independent evaluation of the ion current and electron current region. The physical meaning of the parameters is investigated by comparisons with measurements from dc glow discharges. We found that the reduced rf current of the powered electrode is comparable to the reduced current in dc discharges. A formula is developed that corrects the reduced current due to gas heating. The sheath thickness at the powered rf electrode is evaluated and is between 75 and 1100 μm. The voltage of the bulk plasma is in the range 2-15 V, and the resistance is between 30 and 400 Ω. The bulk plasma consumes about 3% of the total power, and the reduced voltage is comparable to the reduced electrical field in the positive column of direct current discharges. The sheath voltage at the grounded electrode is in the range 25-100 V, the capacities are between 10 and 400 pF, and the resistances are in the range 100 Ω-5000 Ω. We also found invariants for the evaluated sheath parameters

Classification of electrical discharges in DC Accelerators

Energy Technology Data Exchange (ETDEWEB)

Banerjee, Srutarshi, E-mail: sruban.stephens@gmail.com [Accelerator and Pulse Power Division, Bhabha Atomic Research Centre, Trombay, Mumbai 400085 (India); Deb, A.K. [Department of Electrical Engineering, Indian Institute of Technology Kharagpur, Kharagpur 721302 (India); Rajan, Rehim N. [Accelerator and Pulse Power Division, Bhabha Atomic Research Centre, Trombay, Mumbai 400085 (India); Kishore, N.K. [Department of Electrical Engineering, Indian Institute of Technology Kharagpur, Kharagpur 721302 (India)

2016-08-11

Controlled electrical discharge aids in conditioning of the system while uncontrolled discharges damage its electronic components. DC Accelerator being a high voltage system is no exception. It is useful to classify electrical discharges according to the severity. Experimental prototypes of the accelerator discharges are developed. Photomultiplier Tubes (PMTs) are used to detect the signals from these discharges. Time and Frequency domain characteristics of the detected discharges are used to extract features. Machine Learning approaches like Fuzzy Logic, Neural Network and Least Squares Support Vector Machine (LSSVM) are employed to classify the discharges. This aids in detecting the severity of the discharges.

Development of high-capacity antimatter storage

International Nuclear Information System (INIS)

Howe, Steven D.; Smith, Gerald A.

2000-01-01

Space is vast. Over the next few decades, humanity will strive to send probes farther and farther into space to establish long baselines for interferometry, to visit the Kuiper Belt, to identify the heliopause, or to map the Oort cloud. In order to solve many of the mysteries of the universe or to explore the solar system and beyond, one single technology must be developed--high performance propulsion. In essence, future missions to deep space will require specific impulses between 50,000 and 200,000 seconds and energy densities greater than 10 14 j/kg in order to accomplish the mission within the career lifetime of an individual, 40 years. Only two technologies available to mankind offer such performance--fusion and antimatter. Currently envisioned fusion systems are too massive. Alternatively, because of the high energy density, antimatter powered systems may be relatively compact. The single key technology that is required to enable the revolutionary concept of antimatter propulsion is safe, reliable, high-density storage. Under a grant from the NASA Institute of Advanced Concepts, we have identified two potential mechanisms that may enable high capacity antimatter storage systems to be built. We will describe planned experiments to verify the concepts. Development of a system capable of storing megajoules per gram will allow highly instrumented platforms to make fast missions to great distances. Such a development will open the universe to humanity

Achieving precision in high density batch mode micro-electro-discharge machining

International Nuclear Information System (INIS)

Richardson, Mark T; Gianchandani, Yogesh B

2008-01-01

This paper reports a parametric study of batch mode micro-electro-discharge machining (µEDM) of high density features in stainless steel. Lithographically fabricated copper tools with single cross, parallel line and 8 × 8 circle/square array features of 5–100 µm width and 5–75 µm spacing were used to quantify trends in machining tolerance and the impact of debris accumulation. As the tool feature density is increased, debris accumulation effects begin to dominate, eventually degrading both tool and workpiece. Two independent techniques for mitigating this debris buildup are separately investigated. The first is a passivation coating which suppresses spurious discharges triggered from the sidewalls of the machining tool. By this method, the mean tool wear rate decreases from a typical of about 34% to 1.7% and machining non-uniformity reduces from 4.9 µm to 1.1 µm across the workpiece. The second technique involves a two-step machining process that enhances the hydrodynamic removal of machining debris compared to standard methods. This improves surface and edge finish, machining time and tool wear

Sandwich-structured polymer nanocomposites with high energy density and great charge–discharge efficiency at elevated temperatures

Science.gov (United States)

Li, Qi; Liu, Feihua; Yang, Tiannan; Gadinski, Matthew R.; Zhang, Guangzu; Chen, Long-Qing; Wang, Qing

2016-01-01

The demand for a new generation of high-temperature dielectric materials toward capacitive energy storage has been driven by the rise of high-power applications such as electric vehicles, aircraft, and pulsed power systems where the power electronics are exposed to elevated temperatures. Polymer dielectrics are characterized by being lightweight, and their scalability, mechanical flexibility, high dielectric strength, and great reliability, but they are limited to relatively low operating temperatures. The existing polymer nanocomposite-based dielectrics with a limited energy density at high temperatures also present a major barrier to achieving significant reductions in size and weight of energy devices. Here we report the sandwich structures as an efficient route to high-temperature dielectric polymer nanocomposites that simultaneously possess high dielectric constant and low dielectric loss. In contrast to the conventional single-layer configuration, the rationally designed sandwich-structured polymer nanocomposites are capable of integrating the complementary properties of spatially organized multicomponents in a synergistic fashion to raise dielectric constant, and subsequently greatly improve discharged energy densities while retaining low loss and high charge–discharge efficiency at elevated temperatures. At 150 °C and 200 MV m−1, an operating condition toward electric vehicle applications, the sandwich-structured polymer nanocomposites outperform the state-of-the-art polymer-based dielectrics in terms of energy density, power density, charge–discharge efficiency, and cyclability. The excellent dielectric and capacitive properties of the polymer nanocomposites may pave a way for widespread applications in modern electronics and power modules where harsh operating conditions are present. PMID:27551101

The Decline of Soil Infiltration Capacity Due To High Elevation Groundwater

OpenAIRE

Isri Ronald Mangangka

2008-01-01

Infiltration capacity of soil mainly depends on two factors; the particle size and the moisture content of the soil. Groundwater increases the soil moisture, not only below the water table but also within the capillary zone, above the water table. Field experiment in a high groundwater area was conducted to understand the relationship among the groundwater, soil moisture and infiltration capacity. Using a single ring infiltrometer, the effect of groundwater in the infiltration rate was observ...

Methods and techniques for obtaining significant discharge measurements on high-voltage bushings

Energy Technology Data Exchange (ETDEWEB)

Jolley, H E.W.

1965-05-01

Forms of discharge tests are described and compared. The use of the Arman and Starr discharge bridge with cathode-ray-tube display is shown to be practicable for bushing testing up to 600 kV. Spurious discharge effects and the precautions necessary to eliminate them are discussed. Consideration is given to calibration methods and to the errors to be expected with various practical circuits. The problem of establishing safe discharge limits for bushings is considered on the basis of a large number of test results and on service experience.

Estimated discharge of treated wastewater in Florida, 1990

Science.gov (United States)

Marella, R.L.

1994-01-01

According to the Florida Department of Environ- mental Protection, 5,100 wastewater treatment systems were in operation during 1990. Of this total, 72 percent were domestic wastewater facilities and 28 percent were industrial waste- water facilities. The number of wastewater systems inventoried for 1990 was 1,062 (systems that treated and discharged more than 0.01 Mgal/d or had a plant capacity of greater than 0.04 Mgal/d. Based on this inventory, the estimated discharge of treated wastewater in Florida during 1990 totaled 1,638 million gallons per day. Approxi- mately 65 percent of this water was discharged to surface water during 1990 and the remaining 35 percent was discharged to ground water. Discharge to surface water includes effluent outfalls into the Atlantic Ocean (32 percent), while the re- maining (68 percent) is discharged into the Gulf of Mexico, bays, rivers, wetlands, and other surface water bodies throughout Florida. Discharge to ground-water includes treated effluent outfalls to land application systems (reuse systems and spray fields), drain fields, percolation ponds (51 percent), and to injection wells (49 percent). An estimated 322 million gallons per day of the treated domestic and industrial wastewater was reused during 1990. Discharge of treated domestic wastewater from the 994 systems inventoried in Florida during 1990 totaled 1,353 million gallons per day and served an estimated 8.58 million people (66 percent of the population of Florida in 1990). The remaining 34 percent of the popu- lation (4.36 million) are served by the 2,700 smaller domestic wastewater systems or have individual septic tanks. In 1990, there were 1.56 million septic tanks in Florida. Discharge of industrial wastewater was inventoried for 68 systems in 1990 and totaled 285 million gallons per day. Discharge of domestic wastewater in- creased more than 20 percent and industrial wastewater discharge increased 5 percent from 1985 to 1990. (USGS)

Capacity Decay Mitigation by Asymmetric Positive/Negative Electrolyte Volumes in Vanadium Redox Flow Batteries.