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Sample records for high conductivity fractures

  1. Interpretation of stress damage on fracture conductivity

    Energy Technology Data Exchange (ETDEWEB)

    Berumen, Sergio; Tiab, Djebbar [PEMEX E and P and The University of Oklahoma, School of Petroleum and Geological Engineering, Norman, OK (United States)

    1997-02-01

    This paper focuses on the investigation of pressure responses in a well producing through a composite system of a stress-sensitive vertical symmetric or asymmetric fracture interacting with a stress-sensitive permeable-porous medium. Results of this investigation demonstrate that when the fracture conductivity is stress dependent, the use of conventional techniques to evaluate fractured wells may lead to incorrect estimates of the fracture-formation properties. For finite conductivity fractures, the stress effects in the formation have a negligible influence on the absolute value of the slope that defines the pseudo-bilinear flow regime. During this flow regime only the pressure sensitivity in the fracture and the fracture conductivity govern this flow period. For cases that involve highly conductive fractures, it was found that the slope of 0.5 which defines the linear flow regime is not influenced by the stress effect of the fracture and formation. However, stress in highly conductive fractures has a measurable influence in the change of conductivity. The occurrence of the stress damage in finite and infinite conductivity fractures is due to the partial closure fracture or partial choke fracture effect and can be anticipated in terms of pressure or time level by using the equations provided in this work. The results derived from this research have a major impact in improving the analysis of fractured wells pressure responses, as well as in forecasting of fracture closure occurrence and in programming stimulation operations in fractured wells. An example with synthetic data is presented to illustrate these new findings

  2. Reflection seismic imaging of a hydraulically conductive fracture zone in a high noise area, Forsmark, Sweden

    Science.gov (United States)

    Juhlin, C.; Stephens, M. B.; Cosma, C.

    2007-05-01

    High resolution reflection seismic methods have proven to be useful tools for locating fracture zones in crystalline rock. Siting of potential high-level nuclear waste repositories is a particularly important application of these methods. By using small explosive sources (15-75 grams), high resolution images of the sub-surface have been obtained in the depth range 100 m to 2 km in Sweden, Canada and elsewhere. Although ambient noise conditions in areas such as the Fennoscandian and Canadian shields are generally low, industrial noise can be high in some areas, particularly at potential sites suitable for repositories, since these are often close to existing infrastructure. In addition, the presence of this infrastructure limits the choice of sources available to the geophysicist. Forsmark, located about 140 km north of Stockholm, is one such potential site where reflection seismics have been carried out. Existing infrastructure includes nuclear reactors for power generation and a low- level waste repository. In the vicinity of the reactors, it was not possible to use an explosive source due to permitting restrictions. Instead, a VIBSIST system consisting of a tractor mounted hydraulic hammer was used in the vicinity of the reactors. By repeatedly hitting the pavement, without breaking it, at predefined sweeps and then stacking the signals, shot records comparable to explosive data could be generated. These shot records were then processed using standard methods to produce stacked sections along 3 profiles within the reactor area. Clear reflections are seen in the uppermost 600 m along 3 of these profiles. Correlation of crossing profiles shows that the strongest reflection (B8) is generated by a gently east-southeast dipping interface. Prior to construction of the reactors, several boreholes were drilled to investigate the bedrock in the area. One of these boreholes was located close to where two of the profiles cross. Projection of the B8 reflection into the

  3. Estimating the hydraulic conductivity of two-dimensional fracture networks

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    Leung, C. T.; Zimmerman, R. W.

    2010-12-01

    Most oil and gas reservoirs, as well as most potential sites for nuclear waste disposal, are naturally fractured. In these sites, the network of fractures will provide the main path for fluid to flow through the rock mass. In many cases, the fracture density is so high as to make it impractical to model it with a discrete fracture network (DFN) approach. For such rock masses, it would be useful to have recourse to analytical, or semi-analytical, methods to estimate the macroscopic hydraulic conductivity of the fracture network. We have investigated single-phase fluid flow through stochastically generated two-dimensional fracture networks. The centres and orientations of the fractures are uniformly distributed, whereas their lengths follow either a lognormal distribution or a power law distribution. We have considered the case where the fractures in the network each have the same aperture, as well as the case where the aperture of each fracture is directly proportional to the fracture length. The discrete fracture network flow and transport simulator NAPSAC, developed by Serco (Didcot, UK), is used to establish the “true” macroscopic hydraulic conductivity of the network. We then attempt to match this conductivity using a simple estimation method that does not require extensive computation. For our calculations, fracture networks are represented as networks composed of conducting segments (bonds) between nodes. Each bond represents the region of a single fracture between two adjacent intersections with other fractures. We assume that the bonds are arranged on a kagome lattice, with some fraction of the bonds randomly missing. The conductance of each bond is then replaced with some effective conductance, Ceff, which we take to be the arithmetic mean of the individual conductances, averaged over each bond, rather than over each fracture. This is in contrast to the usual approximation used in effective medium theories, wherein the geometric mean is used. Our

  4. Hydraulic conductivities of fractures and matrix in Slovenian carbonate aquifers

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    Timotej Verbovšek

    2008-12-01

    Full Text Available Hydraulic conductivities and specific storage coefficients of fractures and matrix in Slovenian carbonate aquifers were determined by Barker’s method for pumping test analysis, based on fractional flow dimension. Values are presented for limestones and mainly for dolomites, and additionally for separate aquifers, divided by age andlithology in several groups. Data was obtained from hydrogeological reports for 397 water wells, and among these, 79 pumping tests were reinterpreted. Hydraulic conductivities of fractures are higher than the hydraulic conductivities of matrix, and the differences are highly statistically significant. Likewise, differences are significant for specific storage, and the values of these coefficients are higher in the matrix. Values of all coefficients vary in separate aquifers, and the differences can be explained by diagenetic effects, crystal size, degree of fracturing, andcarbonate purity. Comparison of the methods, used in the reports, and the Barker’s method (being more suitable for karstic and fractured aquifers, shows that the latter fits real data better.

  5. Measurement of Fracture Geometry for Accurate Computation of Hydraulic Conductivity

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    Chae, B.; Ichikawa, Y.; Kim, Y.

    2003-12-01

    Fluid flow in rock mass is controlled by geometry of fractures which is mainly characterized by roughness, aperture and orientation. Fracture roughness and aperture was observed by a new confocal laser scanning microscope (CLSM; Olympus OLS1100). The wavelength of laser is 488nm, and the laser scanning is managed by a light polarization method using two galvano-meter scanner mirrors. The system improves resolution in the light axis (namely z) direction because of the confocal optics. The sampling is managed in a spacing 2.5 μ m along x and y directions. The highest measurement resolution of z direction is 0.05 μ m, which is the more accurate than other methods. For the roughness measurements, core specimens of coarse and fine grained granites were provided. Measurements were performed along three scan lines on each fracture surface. The measured data were represented as 2-D and 3-D digital images showing detailed features of roughness. Spectral analyses by the fast Fourier transform (FFT) were performed to characterize on the roughness data quantitatively and to identify influential frequency of roughness. The FFT results showed that components of low frequencies were dominant in the fracture roughness. This study also verifies that spectral analysis is a good approach to understand complicate characteristics of fracture roughness. For the aperture measurements, digital images of the aperture were acquired under applying five stages of uniaxial normal stresses. This method can characterize the response of aperture directly using the same specimen. Results of measurements show that reduction values of aperture are different at each part due to rough geometry of fracture walls. Laboratory permeability tests were also conducted to evaluate changes of hydraulic conductivities related to aperture variation due to different stress levels. The results showed non-uniform reduction of hydraulic conductivity under increase of the normal stress and different values of

  6. High Thermal Conductivity Materials

    CERN Document Server

    Shinde, Subhash L

    2006-01-01

    Thermal management has become a ‘hot’ field in recent years due to a need to obtain high performance levels in many devices used in such diverse areas as space science, mainframe and desktop computers, optoelectronics and even Formula One racing cars! Thermal solutions require not just taking care of very high thermal flux, but also ‘hot spots’, where the flux densities can exceed 200 W/cm2. High thermal conductivity materials play an important role in addressing thermal management issues. This volume provides readers a basic understanding of the thermal conduction mechanisms in these materials and discusses how the thermal conductivity may be related to their crystal structures as well as microstructures developed as a result of their processing history. The techniques for accurate measurement of these properties on large as well as small scales have been reviewed. Detailed information on the thermal conductivity of diverse materials including aluminum nitride (AlN), silicon carbide (SiC), diamond, a...

  7. Highly Thermal Conductive Nanocomposites

    Science.gov (United States)

    Sun, Ya-Ping (Inventor); Connell, John W. (Inventor); Veca, Lucia Monica (Inventor)

    2015-01-01

    Disclosed are methods for forming carbon-based fillers as may be utilized in forming highly thermal conductive nanocomposite materials. Formation methods include treatment of an expanded graphite with an alcohol/water mixture followed by further exfoliation of the graphite to form extremely thin carbon nanosheets that are on the order of between about 2 and about 10 nanometers in thickness. Disclosed carbon nanosheets can be functionalized and/or can be incorporated in nanocomposites with extremely high thermal conductivities. Disclosed methods and materials can prove highly valuable in many technological applications including, for instance, in formation of heat management materials for protective clothing and as may be useful in space exploration or in others that require efficient yet light-weight and flexible thermal management solutions.

  8. Field experiments in a fractured clay till. 1. Hydraulic conductivity and fracture aperture

    Science.gov (United States)

    McKay, Larry D.; Cherry, John A.; Gillham, Robert W.

    1993-04-01

    Field values of horizontal hydraulic conductivity measured in the upper 1.5-5.5 m of a weathered and fractured clay-rich till were strongly influenced by smearing around piezometer intakes, which occurs during augering, and by the physical scale of the measuring device. Values measured in conventional augered piezometers were typically 1-2 orders of magnitude lower than those measured in piezometers designed to reduce smearing. Measurements of hydraulic conductivity in small-scale seepage collectors or piezometers, which typically intersect fewer than 10 fractures, vary over a much greater range, 10-10 to 10-6 m/s, than large-scale values based on infiltration into 5.5-m-deep trenches which intersect thousands of fractures (range 10-7 to 3×10-7 m/s). Values of hydraulic fracture aperture, 1-43 μm, and fracture porosity, 3×10-5 to 2×10-3, were calculated using the cubic law with fracture orientation/distribution measurements and the small-scale hydraulic conductivity measurements. This paper provides the first reliable determination of the magnitude and spatial distribution of hydraulically derived fracture parameters in a clay deposit. The absence of such data has, until now, severely limited the application of quantitative groundwater flow and contaminant transport models in this type of deposit.

  9. Method development for determining the hydraulic conductivity of fractured porous media

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    Dixon, Kenneth L. [Savannah River Site (SRS), Aiken, SC (United States). Savannah River National Lab. (SRNL)

    2013-09-30

    datasets suitable for analysis (sample types 3 and 4). The intact saltstone sample (sample type 1) did not yield any measureable outflow over the pressure range of the outflow test (0-1000 cm H2O). This was expected because the estimated air entry pressure for intact saltstone is on the order of 100,000 cm H2O (Dixon et al., 2009). The intact saltstone sample with a single saw cut smooth surface fracture (sample type 2) did not produce useable data because the fracture completely drained at less than 10 cm H2O applied pressure. The cumulative outflow data from sample types 3 and 4 were analyzed using an inverse solution of the Richard’s equation for water flow in variably saturated porous media. This technique was implemented using the computer code Hydrus-1D (Šimunek et al., 2008) and the resulting output included the van Genuchten-Mualem water retention and relative permeability parameters and predicted saturated hydraulic conductivity (Van Genuchten, 1980; Van Genuchten et al., 1991). Estimations of relative permeability and saturated conductivity are possible because the transient response of the sample to pressure changes is recorded during the multi-step outflow extraction test. Characteristic curves were developed for sample types 3 and 4 based on the results of the transient outflow method and compared to that of intact saltstone previously reported by Dixon et al. (2009). The overall results of this study indicate that the outflow extraction method is suitable for measuring the hydraulic properties of micro-fractured porous media. The resulting cumulative outflow data can be analyzed using the computer code Hydrus-1D to generate the van Genuchten curve fitting parameters that adequately describe fracture drainage. The resulting characteristic curves are consistent with blended characteristic curves that combine the behaviors of low pressure drainage associated with fracture flow with high pressure drainage from the bulk

  10. High Energy Gas Fracturing Test

    Energy Technology Data Exchange (ETDEWEB)

    Schulte, R.

    2001-02-27

    The Rocky Mountain Oilfield Testing Center (RMOTC) has recently completed two tests of a high-energy gas fracturing system being developed by Western Technologies of Crossville, Tennessee. The tests involved the use of two active wells located at the Naval Petroleum Reserve No. 3 (NPR-3), thirty-five miles north of Casper, Wyoming (See Figure 1). During the testing process the delivery and operational system was enhanced by RMOTC, Western Technologies, and commercial wireline subcontractors. RMOTC has assisted an industrial client in developing their technology for high energy gas fracturing to a commercial level. The modifications and improvements implemented during the technology testing process are instrumental in all field testing efforts at RMOTC. The importance of well selection can also be critical in demonstrating the success of the technology. To date, significant increases in well productivity have been clearly proven in well 63-TPX-10. Gross fluid production was initially raised by a factor of three. Final production rates increased by a factor of six with the use of a larger submersible pump. Well productivity (bbls of fluid per foot of drawdown) increased by a factor of 15 to 20. The above results assume that no mechanical damage has occurred to the casing or cast iron bridge plug which could allow well production from the Tensleep ''B'' sand. In the case of well 61-A-3, a six-fold increase in total fluid production was seen. Unfortunately, the increase is clouded by the water injection into the well that was necessary to have a positive fluid head on the propellant tool. No significant increase in oil production was seen. The tools which were retrieved from both 63-TPX-10 and 61-A-3 indicated a large amount of energy, similar to high gram perforating, had been expended downhole upon the formation face.

  11. Magnetic induction technique for mapping vertical conductive fractures: electronic design

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    Landt, J.A.; Koelle, A.R.; Trump, M.A.; Nickell, J.D. Jr.

    1978-09-01

    This report is the last in a series that describes the preliminary design of an instrument capable of mapping conductive fractures deep below the surface of the earth. Earlier reports dealt with theoretical analysis, the general status of the instrument development, and materials vendor searches. Here, attention is focused on the electronics design and prototype hardware to perform the mapping task. A phase-sensitive detector is described that has a sensitivity in the tens of nanovolts. Coil-switching circuitry is also described, as well as a downhole data link tailor-made for this particular instrument's needs.

  12. Simulated evolution of fractures and fracture networks subject to thermal cooling: A coupled discrete element and heat conduction model

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    Huang, Hai; Plummer, Mitchell; Podgorney, Robert

    2013-02-01

    Advancement of EGS requires improved prediction of fracture development and growth during reservoir stimulation and long-term operation. This, in turn, requires better understanding of the dynamics of the strongly coupled thermo-hydro-mechanical (THM) processes within fractured rocks. We have developed a physically based rock deformation and fracture propagation simulator by using a quasi-static discrete element model (DEM) to model mechanical rock deformation and fracture propagation induced by thermal stress and fluid pressure changes. We also developed a network model to simulate fluid flow and heat transport in both fractures and porous rock. In this paper, we describe results of simulations in which the DEM model and network flow & heat transport model are coupled together to provide realistic simulation of the changes of apertures and permeability of fractures and fracture networks induced by thermal cooling and fluid pressure changes within fractures. Various processes, such as Stokes flow in low velocity pores, convection-dominated heat transport in fractures, heat exchange between fluid-filled fractures and solid rock, heat conduction through low-permeability matrices and associated mechanical deformations are all incorporated into the coupled model. The effects of confining stresses, developing thermal stress and injection pressure on the permeability evolution of fracture and fracture networks are systematically investigated. Results are summarized in terms of implications for the development and evolution of fracture distribution during hydrofracturing and thermal stimulation for EGS.

  13. Effective-stress-law behavior of Austin chalk rocks for deformation and fracture conductivity

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    Warpinski, N.R.; Teufel, L.W.

    1994-08-01

    Austin chalk core has been tested to determine the effective law for deformation of the matrix material and the stress-sensitive conductivity of the natural fractures. For deformation behavior, two samples provided data on the variations of the poroelastic parameter, {alpha}, for Austin chalk, giving values around 0.4. The effective-stress-law behavior of a Saratoga limestone sample was also measured for the purpose of obtaining a comparison with a somewhat more porous carbonate rock. {alpha} for this rock was found to be near 0.9. The low {alpha} for the Austin chalk suggests that stresses in the reservoir, or around the wellbore, will not change much with changes in pore pressure, as the contribution of the fluid pressure is small. Three natural fractures from the Austin chalk were tested, but two of the fractures were very tight and probably do not contribute much to production. The third sample was highly conductive and showed some stress sensitivity with a factor of three reduction in conductivity over a net stress increase of 3000 psi. Natural fractures also showed a propensity for permanent damage when net stressed exceeded about 3000 psi. This damage was irreversible and significantly affected conductivity. {alpha} was difficult to determine and most tests were inconclusive, although the results from one sample suggested that {alpha} was near unity.

  14. Analysis of finite-conductivity fractures intercepting multilayer commingled reservoirs

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    Bennett, C.O.; Raghavan, R.; Reynolds, A.C.

    1986-06-01

    The response of a fractured well in a multilayered reservoir is the primary subject of this study. Both analytical approximations and numerical results are presented. The analytical solutions served three important functions: (1) they enabled us to verify the numerical solutions used in this study; (2) they provided information on the structure of the solution and thus increased physical understanding; and (3) most importantly, they suggested a method whereby we are able to correlate multilayer solutions with single-layer solutions. The authors introduce the concept of dimensionless reservoir conductivity and show that in most realistic cases this parameter can be used to correlate commingled-reservoir solutions with the single-layer solutions available in the literature throughout the infinite acting period. This concept and its utility in correlating solutions are the main contributions of this work. They also consider the analysis of buildup data following a short producing time. As in the drawdown case, they show that the multilayer buildup solutions can be correlated with single-layer solutions through the concept of dimensionless reservoir conductivity.

  15. Investigation of fracture conductivity under in situ conditions as a function of frac- and formation parameters

    Energy Technology Data Exchange (ETDEWEB)

    Meyn, V.; Lajcsak, I.

    1998-10-01

    Because of their low permeability, deep-lying gas fields are often developed by the fracturing technique. Essential for the economy of this measure is a high fracture conductivity which persists over a long period. The objective of the project was the investigation of the various factors influencing the fracture conductivity under reservoir conditions. Besides the breaking strength of proppants, which is decisive for the conductivity attainable at high confining pressure, the long-term stability, the embedment and the transport of fragments, which results in plugging, were examined. With the proppants Superprop and Carboprop HC, fracture conductivity exhibits only a slight dependence on the closure pressure. Transport of fragments and embedment play no important role. With resin-coated proppants, conductivity is not improved appreciably. The resin-coating doesn`t resist reservoir conditions. After only one week, aquathermolytic products were detected. (orig.) [Deutsch] Tiefliegende Erdgasfelder werden aufgrund ihrer niedrigen Permeabilitaet haeufig durch eine Frac-Behandlung erschlossen. Eine wesentliche Voraussetzung fuer die Wirtschaftlichkeit einer solchen Massnahme ist eine hohe Rissleitfaehigkeit, die ueber einen langen Zeitraum bestehen bleibt. Ziel des Projektes war die Untersuchung der verschiedenen Faktoren, die die Rissleitfaehigkeit unter Lagerstaettenbedingungen beeinflussen. Neben der Bruchfestigkeit des Stuetzmittels, die fuer die bei hohen Schliessdrucken erreichbaren Rissleitfaehigkeiten entscheidend ist, wurde die Langzeitstabilitaet, das Embedment und der zu Verstopfung fuehrende Transport von Bruchstuecken untersucht. Die Stuetzmittel Superprop und Carboprop HC weisen nur eine geringe Abhaengigkeit der Rissleitfaehigkeit vom Schliessdruck auf. Der Bruchstuecktransport sowie das Embedment spielen nur eine untergeordnete Rolle. Durch die Verwendung von beschichtetem Stuetzmittel wird die Rissleitfaehigkeit nicht wesentlich erhoeht. Die Beschichtung

  16. Comparison of Measured and Modelled Hydraulic Conductivities of Fractured Sandstone Cores

    Science.gov (United States)

    Baraka-Lokmane, S.; Liedl, R.; Teutsch, G.

    - A new method for characterising the detailed fracture geometry in sandstone cores is presented. This method is based on the impregnation of samples with coloured resin, without significant disturbance of the fractures. The fractures are made clearly visible by the resin, thus allowing the fracture geometry to be examined digitally. In order to model the bulk hydraulic conductivity, the samples are sectioned serially perpendicular to the flow direction. The hydraulic conductivity of individual sections is estimated by summing the contribution of the matrix and each fracture from the digital data. Finally, the hydraulic conductivity of the bulk sample is estimated by a harmonic average in series along the flow path. Results of this geometrical method are compared with actual physical conductivity values measured from fluid experiments carried out prior to sectioning. The predicted conductivity from the fracture geometry parameters (e.g., fracture aperture, fracture width, fracture length and fracture relative roughness all measured using an optical method) is in good agreement with the independent physical measurements, thereby validating the approach.

  17. A highly stretchable, transparent, and conductive polymer.

    Science.gov (United States)

    Wang, Yue; Zhu, Chenxin; Pfattner, Raphael; Yan, Hongping; Jin, Lihua; Chen, Shucheng; Molina-Lopez, Francisco; Lissel, Franziska; Liu, Jia; Rabiah, Noelle I; Chen, Zheng; Chung, Jong Won; Linder, Christian; Toney, Michael F; Murmann, Boris; Bao, Zhenan

    2017-03-01

    Previous breakthroughs in stretchable electronics stem from strain engineering and nanocomposite approaches. Routes toward intrinsically stretchable molecular materials remain scarce but, if successful, will enable simpler fabrication processes, such as direct printing and coating, mechanically robust devices, and more intimate contact with objects. We report a highly stretchable conducting polymer, realized with a range of enhancers that serve a dual function: (i) they change morphology and (ii) they act as conductivity-enhancing dopants in poly(3,4-ethylenedioxythiophene):poly(styrenesulfonate) (PEDOT:PSS). The polymer films exhibit conductivities comparable to the best reported values for PEDOT:PSS, with over 3100 S/cm under 0% strain and over 4100 S/cm under 100% strain-among the highest for reported stretchable conductors. It is highly durable under cyclic loading, with the conductivity maintained at 3600 S/cm even after 1000 cycles to 100% strain. The conductivity remained above 100 S/cm under 600% strain, with a fracture strain of 800%, which is superior to even the best silver nanowire- or carbon nanotube-based stretchable conductor films. The combination of excellent electrical and mechanical properties allowed it to serve as interconnects for field-effect transistor arrays with a device density that is five times higher than typical lithographically patterned wavy interconnects.

  18. High prevalence of simultaneous rib and vertebral fractures in patients with hip fracture.

    Science.gov (United States)

    Lee, Bong-Gun; Sung, Yoon-Kyoung; Kim, Dam; Choi, Yun Young; Kim, Hunchul; Kim, Yeesuk

    2017-02-01

    The purpose was to evaluate the prevalence and location of simultaneous fracture using bone scans in patients with hip fracture and to determine the risk factors associated with simultaneous fracture. One hundred eighty two patients with hip fracture were reviewed for this study. Clinical parameters and bone mineral density (BMD) of the lumbar vertebra and femoral neck were investigated. To identify acute simultaneous fracture, a bone scan was performed at 15.4±4.1days after hip fracture. The prevalence and location of simultaneous fracture were evaluated, and multivariate logistic regression analysis was performed to determine the risk factors. Simultaneous fracture was observed in 102 of 182 patients, a prevalence of 56.0%. Rib fracture was the most common type of simultaneous fracture followed by rib with vertebral fracture. The BMD of the lumbar vertebra was significantly lower in patients with simultaneous fracture (p=0.044) and was identified as an independent risk factor (odds ratio: OR 0.05, 95% confidence interval: CI 0.01-0.57). The prevalence of simultaneous fracture was relatively high among patients with hip fracture, and BMD was significantly lower in patients with simultaneous fracture than in patients without it. Surgeons should be aware of the possibility of simultaneous fracture in patients with hip fracture. Copyright © 2016 Elsevier Ltd. All rights reserved.

  19. Tibiofibula Transposition in High-Energy Fractures

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    Peter R. Loughenbury

    2016-01-01

    Full Text Available We report two cases of failed attempts at closed reduction of high-energy tibial fractures with an associated fibula fracture. The first case was a 39-year-old male involved in high-speed motorbike collision, while the second was a 14-year-old male who injured his leg following a fall of three metres. Emergency medical services at the scenes of the accidents reported a 90-degree valgus deformity of the injured limb and both limbs were realigned on scene and stabilized. Adequate alignment of the tibia could not be achieved by manipulation under sedation or anaesthesia. Open reduction and exposure of the fracture sites revealed that the distal fibula fragment was “transposed” and entrapped in the medulla of the proximal tibial fragment. Reduction required simulation of the mechanism of injury in order to disengage the fragments and allow reduction. Tibiofibula transposition is a rare complication of high-energy lower limb fractures which has not previously been reported and may prevent adequate closed reduction. Impaction of the distal fibula within the tibial medulla occurs as the limb is realigned by paramedic staff before transfer to hospital. We recommend that when this complication is identified the patient is transferred to the operating room for open reduction and stabilization of the fracture.

  20. High-energy gas fracturing in cased and perforated wellbores

    Energy Technology Data Exchange (ETDEWEB)

    Cuderman, J.F.

    1986-06-01

    A propellant-based technology, High-Energy Gas Fracturing (HEGF), has been applied to fracturing through perforations in cased boreholes. HEGF is a tailored-pulse fracturing technique originally developed by Sandia National Laboratories for application in uncased, liquid-free gas wells in Appalachian Devonian shales. Because most oil and gas wells are liquid filled as well as cased and perforated, the potential impact of present research is significantly broader. A number of commercial tailored-pulse fracturing services, using a variety of explosives or propellants, are currently available. Present research provides valuable insight into phenomena that occur in those stimulations. The use of propellants that deflagrate or burn rather than detonate, as do high-order explosives, permits controlled buildup of pressure in the wellbore. The key to successful stimulation in cased and perforated wellbores is to control the pressure buildup of the combustion gases to maximize fracturing without destroying the casing. Eight experiments using cased and perforated wellbore were conducted in a tunnel complex at the Department of Energy's Nevada Test Site, which provides a realistic in situ stress environment (4 to 10 MPa (600 to 1500 psi)) and provides access for mineback to directly observe fracturing obtained. Primary variables in the experiments include propellant burn rate and amount of propellant used, presence or absence of liquid in the wellbore, in situ stress orientation, and perforation diameter, density, and phasing. In general, the presence of liquid in the borehole results in a much faster pressure risetime and a lower peak pressure for the same propellant charge. Fracture surfaces proceed outward along lines of perforations as determined by phasing, then gradually turn toward the hydraulic fracture direction. 8 refs., 23 figs., 3 tabs.

  1. Analysis of finite conductivity fractures intercepting multilayer reservoirs

    Energy Technology Data Exchange (ETDEWEB)

    Bennett, C.; Raghavan, R.; Reynolds, A.C.

    1982-09-01

    This paper presents the analytical and numerical results of an examination into the response of a fractured well in a multi-layered reservoir. The analytical solutions derived are new and served three functions. First, they enabled the verification of the numerical solutions. Second, they provided information on the structure of the solution, and thus increased physical understanding. Third, they suggested a method whereby the authors were able to correlate multi-layer solutions with the single-layer solutions. The authors show that under certain circumstances the well response of wells draining multilayer reservoirs can be correlated with single-layer reservoirs. They also find that the ratio of the fracture height to the fracture length has an influence on well performance. This influence is discussed. The authors also consider the analysis of buildup data following a short producing time. They show that the multi-layer buildup solutions can be correlated with the single-layer buildup solutions.

  2. Analysis of finite conductivity fractures intercepting multilayer reservoirs

    Energy Technology Data Exchange (ETDEWEB)

    Bennett, C.O.; Reynolds, A.C.; Raghavan, R.

    1982-01-01

    The response of a fractured well in a multilayered reservoir is the primary subject of this study. Both analytic and numeric results are presented. The analytic solutions derived are new and served 3 important functions. First, they enable verification of the numeric solutions used in this study. Second, they provided information on the structure of the solution, and thus increased physical understanding. Third, they suggested a method for correlating multilayer solutions with the single-layer solutions. The well response of wells draining multilayer reservoirs can be correlated with single-layer reservoirs. It also was found that the ratio of the fracture height to fracture length has an influence on well performance. The analysis of buildup data following a short producing time is considered. It is shown that the multilayer buildup solutions can be correlated with the single-layer buildup solutions. 21 references.

  3. Development of high-thermal-conductivity silicon nitride ceramics

    Directory of Open Access Journals (Sweden)

    You Zhou

    2015-09-01

    Full Text Available Silicon nitride (Si3N4 with high thermal conductivity has emerged as one of the most promising substrate materials for the next-generation power devices. This paper gives an overview on recent developments in preparing high-thermal-conductivity Si3N4 by a sintering of reaction-bonded silicon nitride (SRBSN method. Due to the reduction of lattice oxygen content, the SRBSN ceramics could attain substantially higher thermal conductivities than the Si3N4 ceramics prepared by the conventional gas-pressure sintering of silicon nitride (SSN method. Thermal conductivity could further be improved through increasing the β/α phase ratio during nitridation and enhancing grain growth during post-sintering. Studies on fracture resistance behaviors of the SRBSN ceramics revealed that they possessed high fracture toughness and exhibited obvious R-curve behaviors. Using the SRBSN method, a Si3N4 with a record-high thermal conductivity of 177 Wm−1K−1 and a fracture toughness of 11.2 MPa m1/2 was developed. Studies on the influences of two typical metallic impurity elements, Fe and Al, on thermal conductivities of the SRBSN ceramics revealed that the tolerable content limits for the two impurities were different. While 1 wt% of impurity Fe hardly degraded thermal conductivity, only 0.01 wt% of Al caused large decrease in thermal conductivity.

  4. Analytical analysis of fracture conductivity for sparse distribution of proppant packs

    Science.gov (United States)

    Guo, Jianchun; Wang, Jiandong; Liu, Yuxuan; Chen, Zhangxin; Zhu, Haiyan

    2017-06-01

    Conductivity optimization is important for hydraulic fracturing due to its key roles in determining fractured well productivity. Proppant embedment is an important mechanism that could cause a remarkable reduction in fracture width and, thus, damage the fracture conductivity. In this work a new analytical model, based on contact mechanics and the Carman-Kozeny model, is developed to calculate the embedment and conductivity for the sparse distribution of proppant packs. Features and controlling factors of embedment, residual width and conductivity are analyzed. The results indicate an optimum distance between proppant packs that has the potential to maintain the maximum conductivity after proppant embedment under a sparse distribution condition. A change in the optimum distance is primarily controlled by closure pressure, the rock elastic modulus and the proppant elastic modulus. The proppant concentrations and the poroelastic effect do not influence this optimum distance.

  5. Estimation of the hydraulic conductivity of a two-dimensional fracture network using effective medium theory and power-law averaging

    Science.gov (United States)

    Zimmerman, R. W.; Leung, C. T.

    2009-12-01

    Most oil and gas reservoirs, as well as most potential sites for nuclear waste disposal, are naturally fractured. In these sites, the network of fractures will provide the main path for fluid to flow through the rock mass. In many cases, the fracture density is so high as to make it impractical to model it with a discrete fracture network (DFN) approach. For such rock masses, it would be useful to have recourse to analytical, or semi-analytical, methods to estimate the macroscopic hydraulic conductivity of the fracture network. We have investigated single-phase fluid flow through generated stochastically two-dimensional fracture networks. The centers and orientations of the fractures are uniformly distributed, whereas their lengths follow a lognormal distribution. The aperture of each fracture is correlated with its length, either through direct proportionality, or through a nonlinear relationship. The discrete fracture network flow and transport simulator NAPSAC, developed by Serco (Didcot, UK), is used to establish the “true” macroscopic hydraulic conductivity of the network. We then attempt to match this value by starting with the individual fracture conductances, and using various upscaling methods. Kirkpatrick’s effective medium approximation, which works well for pore networks on a core scale, generally underestimates the conductivity of the fracture networks. We attribute this to the fact that the conductances of individual fracture segments (between adjacent intersections with other fractures) are correlated with each other, whereas Kirkpatrick’s approximation assumes no correlation. The power-law averaging approach proposed by Desbarats for porous media is able to match the numerical value, using power-law exponents that generally lie between 0 (geometric mean) and 1 (harmonic mean). The appropriate exponent can be correlated with statistical parameters that characterize the fracture density.

  6. High-Thermal-Conductivity Fabrics

    Science.gov (United States)

    Chibante, L. P. Felipe

    2012-01-01

    Heat management with common textiles such as nylon and spandex is hindered by the poor thermal conductivity from the skin surface to cooling surfaces. This innovation showed marked improvement in thermal conductivity of the individual fibers and tubing, as well as components assembled from them. The problem is centered on improving the heat removal of the liquid-cooled ventilation garments (LCVGs) used by astronauts. The current design uses an extensive network of water-cooling tubes that introduces bulkiness and discomfort, and increases fatigue. Range of motion and ease of movement are affected as well. The current technology is the same as developed during the Apollo program of the 1960s. Tubing material is hand-threaded through a spandex/nylon mesh layer, in a series of loops throughout the torso and limbs such that there is close, form-fitting contact with the user. Usually, there is a nylon liner layer to improve comfort. Circulating water is chilled by an external heat exchanger (sublimator). The purpose of this innovation is to produce new LCVG components with improved thermal conductivity. This was addressed using nanocomposite engineering incorporating high-thermalconductivity nanoscale fillers in the fabric and tubing components. Specifically, carbon nanotubes were added using normal processing methods such as thermoplastic melt mixing (compounding twin screw extruder) and downstream processing (fiber spinning, tubing extrusion). Fibers were produced as yarns and woven into fabric cloths. The application of isotropic nanofillers can be modeled using a modified Nielsen Model for conductive fillers in a matrix based on Einstein s viscosity model. This is a drop-in technology with no additional equipment needed. The loading is limited by the ability to maintain adequate dispersion. Undispersed materials will plug filtering screens in processing equipment. Generally, the viscosity increases were acceptable, and allowed the filled polymers to still be

  7. SIMPLE ANALYTICAL MODEL FOR HEAT FLOW IN FRACTURES - APPLICATION TO STEAM ENHANCED REMEDIATION CONDUCTED IN FRACTURED ROCK

    Science.gov (United States)

    Remediation of fractured rock sites contaminated by non-aqueous phase liquids has long been recognized as the most difficult undertaking of any site clean-up. Recent pilot studies conducted at the Edwards Air Force Base in California and the former Loring Air Force Base in Maine ...

  8. Performance of finite conductivity vertically fractured wells in single-layer reservoirs

    Energy Technology Data Exchange (ETDEWEB)

    Bennett, C.O.; Elbel, J.L.; Raghavan, R.; Reynolds, A.C.

    1982-09-01

    Even a perfunctory survey of the literature suggests that considerable information is available on the response of finite-conductivity fractures in signel-layer systems. But correspondents have suggested that the influence of the settling of propping agents and the effect of fracture height on the well response needs to be examined. These topics are examined in detail in this paper. The authors suggest methods to analyze well performance when the fracture conductivity is a function of fracture height and fracture length. The performance of wells with fracture height greater than the formation thickness is documented. The consequences of not being able to contain the fracture within the pay zone are also examined. Although incidental to this study, the authors found that solutions presented by various authors are not in agreement for all time ranges. In this paper, the authors discuss a systematic procedure to obtain a grid (mesh), so that accurate results are obtained by a finite difference model. This procedure can be used for both two-dimensional and three-dimensional problems.

  9. Performance of finite-conductivity, vertically fractured wells in single-layer reservoirs

    Energy Technology Data Exchange (ETDEWEB)

    Bennett, C.O.; Reynolds, A.C.; Raghavan, R.; Elbel, J.L.

    1986-08-01

    Although even a perfunctory survey of the literature suggests that considerable information is available on the response of finite-conductivity fractures in single-layer systems, the influence of the settling of propping agents and the effect of fracture height on the well response need to be examined. These topics are examined in this paper. The authors suggest methods to analyze well performance when the fracture conductivity is a function of fracture height and fracture length. The performance of wells with fracture height greater than the formation thickness is documented. The consequences of being unable to contain the fracture within the pay zone are also examined. Although incidental to this study, the authors found that solutions presented by various authors are not in agreement for all time ranges. In this paper, they discuss a systematic procedure to obtain a grid (mesh) so that accurate results are obtained by a finite-difference model. This procedure can be used for both two-dimensional (2D) and three-dimensional (3D) problems.

  10. Triple Medium Physical Model of Post Fracturing High-Rank Coal Reservoir in Southern Qinshui Basin

    Institute of Scientific and Technical Information of China (English)

    Shiqi Liu; Shuxun Sang; Qipeng Zhu; Jiefang Zhang; Hefeng Gao; Huihu Liu; Lixing Lin

    2015-01-01

    In this paper, influences on the reservoir permeability, the reservoir architecture and the fluid flow pattern caused by hydraulic fracturing are analyzed. Based on the structure and production fluid flow model of post fracturing high-rank coal reservoir, Warren-Root Model is improved. A new physical model that is more suitable for post fracturing high-rank coal reser-voir is established. The results show that the width, the flow conductivity and the permeability of hydraulic fractures are much larger than natural fractures in coal bed reservoir. Hydraulic frac-ture changes the flow pattern of gas and flow channel to wellbore, thus should be treated as an independent medium. Warrant-Root Model has some limitations and can’t give a comprehensive interpretation of seepage mechanism in post fracturing high-rank coal reservoir. Modified War-rant-Root Model simplifies coal bed reservoir to an ideal system with hydraulic fracture, ortho-gonal macroscopic fracture and cuboid matrix. Hydraulic fracture is double wing, vertical and symmetric to wellbore. Coal bed reservoir is divided into cuboids by hydraulic fracture and fur-ther by macroscopic fractures. Flow behaviors in coal bed reservoir are simplified to three step flows of gas and two step flows of water. The swap mode of methane between coal matrix and macroscopic fractures is pseudo steady fluid channeling. The flow behaviors of methane to well-bore no longer follow Darcy’s Law and are mainly affected by inertia force. The flow pattern of water follows Darcy’s Law. The new physical model is more suitable for post fracturing high-rank coal reservoir.

  11. Fluid driven fracture mechanics in highly anisotropic shale: a laboratory study with application to hydraulic fracturing

    Science.gov (United States)

    Gehne, Stephan; Benson, Philip; Koor, Nick; Enfield, Mark

    2017-04-01

    The finding of considerable volumes of hydrocarbon resources within tight sedimentary rock formations in the UK led to focused attention on the fundamental fracture properties of low permeability rock types and hydraulic fracturing. Despite much research in these fields, there remains a scarcity of available experimental data concerning the fracture mechanics of fluid driven fracturing and the fracture properties of anisotropic, low permeability rock types. In this study, hydraulic fracturing is simulated in a controlled laboratory environment to track fracture nucleation (location) and propagation (velocity) in space and time and assess how environmental factors and rock properties influence the fracture process and the developing fracture network. Here we report data on employing fluid overpressure to generate a permeable network of micro tensile fractures in a highly anisotropic shale ( 50% P-wave velocity anisotropy). Experiments are carried out in a triaxial deformation apparatus using cylindrical samples. The bedding planes are orientated either parallel or normal to the major principal stress direction (σ1). A newly developed technique, using a steel guide arrangement to direct pressurised fluid into a sealed section of an axially drilled conduit, allows the pore fluid to contact the rock directly and to initiate tensile fractures from the pre-defined zone inside the sample. Acoustic Emission location is used to record and map the nucleation and development of the micro-fracture network. Indirect tensile strength measurements at atmospheric pressure show a high tensile strength anisotropy ( 60%) of the shale. Depending on the relative bedding orientation within the stress field, we find that fluid induced fractures in the sample propagate in two of the three principal fracture orientations: Divider and Short-Transverse. The fracture progresses parallel to the bedding plane (Short-Transverse orientation) if the bedding plane is aligned (parallel) with the

  12. Evaluation of Geochemical Fracture Conductivity Alterations in Shale under Laboratory Conditions

    Science.gov (United States)

    Radonjic, M.; Olabode, A.

    2015-12-01

    In large scale subsurface injection of carbondioxide as obtainable in carbon sequestration programs and in environmentally friendly hydraulic fracturing processes (using supercritical CO2), rock-fluid interaction can affect reservoir and seal rocks properties which are essential in monitoring the progress of these operations. The mineralogical components of sedimentary rocks are geochemically active particularly under enormous earth stresses. While geomechanical properties such as rock stiffness, Poisson's ratio and fracture geometry largely govern fluid flow characteristics in deep fractured formations, the effect of mineralization can lead to flow impedance in the presence of favorable geochemical and thermodynamic conditions. Experimental works which employed the use of analytical tools such as ICP-OES, XRD, SEM/EDS, TOC and BET techniques in investigating diagenetic and micro-structural properties of crushed shale caprock/CO2-brine system concluded that net precipitation reaction processes can affect the distribution of petrophysical nanopores in the shale as a result of rock-fluid interactions. Simulation results previously reported, suggest that influx-induced mineral dissolution/precipitation reactions within clay-based sedimentary rocks can continuously close micro-fracture networks, though injection pressure and effective-stress transformation first rapidly expand these fractures. This experimental modelling research investigated the impact of in-situ geochemical precipitation on conductivity of fractures under geomechanical stress conditions. Conductivity is measured as differential-pressure drop equivalence, using a pressure pulse-decay liquid permeametry/core flooding system, as geochemically saturated-fluid is transported through composite cores with embedded micro-tubings that mimic fractures. The reactive fluid is generated from crushed shale rocks of known mineralogical composition when flooded with aqueous CO2 at elevated temperature and pressure

  13. High energy gas fracture experiments in liquid-filled boreholes: potential geothermal application

    Energy Technology Data Exchange (ETDEWEB)

    Cuderman, J.F.; Chu, T.Y.; Jung, J.; Jacobson, R.D.

    1986-07-01

    High Energy Gas Fracturing is a tailored pulse fracturing technique which uses propellants to obtain controlled fracture initiation and extension. Borehole pressurization rates can be tailored, by suitable choice of propellants, to produce four or eight fractures radiating from the wellbore. High Energy Gas Fracture (HEGF) research is conducted at DOE's Nevada Test Site (NTS) in a tunnel complex where experiments can be done under realistic in situ stress conditions (1400 psi (9.7 MPa) overburden stress). Pressure measurements are made in the test borehole during all fracturing experiments. Experiments are mined back to provide direct observation of fracturing obtained. The initial objective of HEGF research was to develop multiple fracturing technology for application in gas well stimulation. HEGF research at NTS and in Devonian shale demonstration tests has resulted in a completed technology for multiple fracturing in uncased, liquid-free wellbores. Current resarch is directed toward extending the technique to liquid-filled boreholes for application in geothermal in addition to gas and oil wells. For liquid-free boreholes, multiple fracturing is specified in terms of pressure risetime required for a given borehole diameter. Propellants are mixed to achieve the desired risetime using a semiempirical mixing equation. The same techniques were successfully applied to fracturing in liquid-filled wellbores. However, the addition of liquid in the borehole results in a significantly more complicated fracturing behavior. Hydrodynamic effects are significant. Multiple fractures are initiated but only some propagated. Multiple- and hydraulic-type fracturing and wellbore crushing have been observed in the same experiment. The potential of using HEGB for geothermal well stimulation has been demonstrated through the present experiments. 18 refs., 40 figs., 4 tabs.

  14. Thrombin related peptide TP508 promoted fracture repair in a mouse high energy fracture model

    Directory of Open Access Journals (Sweden)

    Pan Xiao-Hua

    2009-01-01

    Full Text Available Abstract Background Thrombin related peptide (TP508 is a 23 amino-acid synthetic peptide that represents a portion of the receptor-binding domain of thrombin molecule. Previous studies have shown that TP508 can accelerate musculoskeletal tissue repair including fracture healing. Objectives The aim of this study was to investigate the effect of TP508 on fracture healing in a murine fracture model representing high energy fracture situation. Methods Eighty CD 1 mice underwent controlled quadriceps muscle crush and open transverse mid diaphyseal femoral fracture that was then fixed with an external fixator. Animals were randomised into four groups to receive an intra-operative dose of either 100 μg TP508 into the fracture gap; 100 μg TP508 into the surrounding damaged muscle tissues; 10 μg TP508 into the fracture gap, or control equal amount of saline into the fracture gap. Radiographic assessment was performed weekly for 5 weeks; histological analysis was at 3 and 5 weeks post fracture and biomechanical testing of the fractured bone was performed at 5 weeks post fracture. Results Mechanical testing data showed that the fracture stiffness was significantly higher in the group receiving 100 μg TP508 into the fracture gap than other groups. Histological and radiographic analysis revealed a trend of increase in bone formation in the 100 μg TP508 injected into the fracture gap group compared to the saline control group. It was noted that the scar tissues was significantly less in Group II comparing with the saline control group and there was increased blood vessel formation in the crushed muscles and fracture gap areas in the groups receiving TP508 comparing to the saline control group. Conclusion The results from this study demonstrated the use of thrombin related peptide TP508 in the situation of a high energy fracture can promote fracture healing and reduce the potential complications such as muscle fibrosis and fracture delayed or non-union.

  15. Pressure Transient Behavior of Horizontal Well with Time-Dependent Fracture Conductivity in Tight Oil Reservoirs

    Directory of Open Access Journals (Sweden)

    Qihong Feng

    2017-01-01

    Full Text Available This work presents a discussion on the pressure transient response of multistage fractured horizontal well in tight oil reservoirs. Based on Green’s function, a semianalytical model is put forward to obtain the behavior. Our proposed model accounts for fluid flow in four contiguous regions of the tight formation by using pressure continuity and mass conservation. The time-dependent conductivity of hydraulic fractures, which is ignored in previous models but highlighted by recent experiments, is also taken into account in our proposed model. We also include the effect of pressure drop along a horizontal wellbore. We substantiate the validity of our model and analyze the different flow regimes, as well as the effects of initial conductivity, fracture distribution, and geometry on the pressure transient behavior. Our results suggest that the decrease of fracture conductivity has a tremendous effect on the well performance. Finally, we compare our model results with the field data from a multistage fractured horizontal well in Jimsar sag, Xinjiang oilfield, and a good agreement is obtained.

  16. Fractured-rock hydrogeophysics with electrically conductive and neutrally buoyant tracers

    Science.gov (United States)

    Shakas, A.; Linde, N.; Baron, L.; Le Borgne, T.; Bour, O.; Lavenant, N.; Gerard, M. F.

    2016-12-01

    Artificial tracer tests help to characterize and understand the dynamics of groundwater systems. This remains a challenging task, especially when dealing with highly heterogeneous formations in which flow can be very localized and the interpretation of tracer breakthrough curves may be ambiguous. As a complement to tracer tests, ground-penetrating radar (GPR) and electrical resistivity tomography can map the space-time migration of electrically conductive tracers. In hydrogeophysics, the most common tracer is dissolved table salt in water. However, conventional salt tracers lead to density effects that are often ignored. Even less than 1% density variations can have a dramatic effect on transport behavior and affect tracer tests in complex ways. Such effects have been demonstrated in our previous experiments that used single-hole GPR to monitor saline push-pull tests in fractured granite. It is possible to model density effects, but this leads to computational complexity and field dynamics that are not necessarily representative of the natural responses of the system. To minimize density effects, we performed a new set of push-pull tests using a neutrally buoyant and electrically conductive tracer at the same test site located close to Ploemeur, France. This novel tracer consists of a mixture of salt (NaCl), water and pure ethanol. Ethanol has a density of 789 g/L at 20° C and is used to counter-act the salt-induced density increase. Our GPR time-lapse images and tracer breakthrough data indicate a largely reversible transport process that confirms the neutral buoyancy of the tracer. Ethanol is biodegradable and does not pose significant environmental issues. Furthermore, calibration of the neutral-buoyant mixture is straightforward to perform in the field using Archimedes principle. Based on these results, we argue that neutrally buoyant ethanol-salt-water mixtures are ideal for a wide variety of hydrogeophysical tracer tests in porous or fractured media.

  17. Estimating Hydraulic Conductivities in a Fractured Shale Formation from Pressure Pulse Testing and 3d Modeling

    Science.gov (United States)

    Courbet, C.; DICK, P.; Lefevre, M.; Wittebroodt, C.; Matray, J.; Barnichon, J.

    2013-12-01

    logging, porosity varies by a factor of 2.5 whilst hydraulic conductivity varies by 2 to 3 orders of magnitude. In addition, a 3D numerical reconstruction of the internal structure of the fault zone inferred from borehole imagery has been built to estimate the permeability tensor variations. First results indicate that hydraulic conductivity values calculated for this structure are 2 to 3 orders of magnitude above those measured in situ. Such high values are due to the imaging method that only takes in to account open fractures of simple geometry (sine waves). Even though improvements are needed to handle more complex geometry, outcomes are promising as the fault damaged zone clearly appears as the highest permeability zone, where stress analysis show that the actual stress state may favor tensile reopening of fractures. Using shale samples cored from the different internal structures of the fault zone, we aim now to characterize the advection and diffusion using laboratory petrophysical tests combined with radial and through-diffusion experiments.

  18. Analysis of short-time buildup data for finite-conductivity fractures

    Energy Technology Data Exchange (ETDEWEB)

    Rosato, N.D.; Bennett, C.O.; Raghavan, R.; Reynolds, A.C.

    1982-10-01

    A finite-conductivity vertical fracture intersecting a well is considered. The well is produced at a constant rate or at a constant pressure and then is shut in. The pressure response during the buildup period and the pressure or rate response during the production period are obtained from a numerical model. In this work the authors discuss the analysis of pressure buildup data following a short flow period. The authors present a buildup type curve to analyze pressure buildup data when the pressure (or rate) response is influenced by only the bilinear flow period. This type curve can be used to estimate the fracture flow capacity and a lower limit for the fracture half-length. It will be useful when the equivalent-time or the equivalent-drawdown concepts cannot be used. The authors discuss strengths and limitations of the equivalenttime method proposed in the literature. The theoretical basis for this procedure is provided.

  19. High frequency conductivity in carbon nanotubes

    Directory of Open Access Journals (Sweden)

    S. S. Abukari

    2012-12-01

    Full Text Available We report on theoretical analysis of high frequency conductivity in carbon nanotubes. Using the kinetic equation with constant relaxation time, an analytical expression for the complex conductivity is obtained. The real part of the complex conductivity is initially negative at zero frequency and become more negative with increasing frequency, until it reaches a resonance minimum at ω ∼ ωB for metallic zigzag CNs and ω < ωB for armchair CNs. This resonance enhancement is indicative for terahertz gain without the formation of current instabilities induced by negative dc conductivity. We noted that due to the high density of states of conduction electrons in metallic zigzag carbon nanotubes and the specific dispersion law inherent in hexagonal crystalline structure result in a uniquely high frequency conductivity than the corresponding values for metallic armchair carbon nanotubes. We suggest that this phenomenon can be used to suppress current instabilities that are normally associated with a negative dc differential conductivity.

  20. Characterization and Conduction Mechanism of Highly Conductive Vanadate Glass

    Directory of Open Access Journals (Sweden)

    Tetsuaki Nishida

    2015-12-01

    Full Text Available This paper reviews recent studies of highly conductive barium iron vanadate glass with a composition of 20 BaO ∙ 10 Fe2O3 ∙ 70 V2O5 (in mol %. Isothermal annealing of the vanadate glass for several ten minutes at a given temperature, higher than glass transition temperature or crystallization temperature, caused an increase in σ. Substitution of CuI (3d10, ZnII (3d10 and CuII (3d9 for FeIII (3d5 was investigated to elucidate the effect of electron configuration on the conductivity (σ. A marked decrease in the activation energy of conduction (Ea was also observed after the annealing. Values of Ea were correlated to the energy gap between the donor level and the conduction band (CB in the n-type semiconductor model. Isothermal annealing of ZnII-substituted vanadate glass (20 BaO ∙ 5 ZnO ∙ 5 Fe2O3 ∙ 70 V2O5 at 450 °C for 30 min showed an increase in σ from 2.5 × 10–6 to 2.1 × 10–1 S cm–1, which was one order of magnitude larger than that of non-substituted vanadate glass (3.4 × 10–2 S cm–1. Under the same annealing condition, σ’s of 2.0 × 10–1 and 3.2 × 10–1 S cm–1 were observed for 20 BaO ∙ 5 Cu2O ∙ 5 Fe2O3 ∙ 70 V2O5 and 20 BaO ∙ 5 CuO ∙ 5 Fe2O3 ∙ 70 V2O5 glasses, respectively. These results demonstrate an increase in the carrier (electron density in the CB, primarily composed of anti-bonding 4s-orbitals.

  1. Investigation of the plastic fracture of high strength steels

    Science.gov (United States)

    Cox, T. B.; Low, J. R., Jr.

    1972-01-01

    This investigation deals in detail with the three recognized stages of plastic fracture in high strength steels, namely, void initiation, void growth, and void coalescence. The particular steels under investigation include plates from both commercial purity and high purity heats of AISI 4340 and 18 Ni, 200 grade maraging steels. A scanning electron microscope equipped with an X-ray energy dispersive analyzer, together with observations made using light microscopy, revealed methods of improving the resistance of high strength steels to plastic fracture.

  2. Statistics of modelled conductive fractures based on Laxemar and Forsmark. Site descriptive model data

    Energy Technology Data Exchange (ETDEWEB)

    Stigsson, Martin

    2009-12-15

    The objectives of this report is to investigate the frequency of fractures assumed to be water conductive, i.e. open or partly open and directly or indirectly connected to a source. Also the distribution of total transmissivity in 100 m and 20 m horizontal sections and 8 m vertical sections is calculated. The report is only intended to serve as input to the SER, Site Engineering Report, at Laxemar and Forsmark. The input data for the analyses is taken, as is, from the Discrete Fracture Network sections in published reports. No evaluation that the model parameters are appropriate for the task or sensitivity analysis is performed. The tunnels and deposition holes are modelled as scanlines which is a very coarse approximation, but it may give some rough estimation of the frequency of the water bearing features, especially for the larger ones, and the total transmissivity in a section

  3. Fracture performance of high strength steels, aluminium and magnesium alloys during plastic deformation

    Directory of Open Access Journals (Sweden)

    Yu Haiyan

    2015-01-01

    Full Text Available A series of uniaxial tension tests were performed for 5052 and 6061 aluminum alloys, AZ31B magnesium alloy, TRIP600 and DP600 steels, to obtain a better understanding of their fracture performance. Scanning electron microscope (SEM observation of the microstructure evolution was conducted. The dimple structure, orientation relationship between the fracture surface and tensile direction, necking behavior were analyzed. The fracture mechanism and fracture mode of each material was discussed in detail. The results show that TRIP600 steel is subject to a typical inter-granular ductile fracture combined by shear fracture. DP600 steel belongs to mainly ductility mixed with normal fracture. Both 5052 and 6061 aluminum alloys are subject to a mixed ductility fracture and brittle fracture. AA5052 and AA6061 belong to a typical shear fracture and a normal fracture, respectively. Magnesium AZ31B is typical of a brittle fracture combined with normal fracture.

  4. High Energy Gas Fracturing in Deep Reservoir

    Institute of Scientific and Technical Information of China (English)

    Zhang Qiangde; Zhao Wanxiang; Wang Faxuan

    1994-01-01

    @@ Introduction The HEGF technology has many merits such as low cost, simple work conditions, treating the thin reservoir without layer dividing tools, no contamination to the reservoirs and connections with more natural fractures. So it is suitable to treat thin reservoirs,water and acid senstive reservoirs and the reserviors with natural fissures and also suitable to evaluate the production test of new wells, blocking removing treatment, increasing injection treatment and the treatment for the hydrofracturing well with some productivity.

  5. Estimating hydraulic conductivity of fractured rocks from high‐pressure packer tests with an Izbash's law‐based empirical model

    National Research Council Canada - National Science Library

    Chen, Yi‐Feng; Hu, Shao‐Hua; Hu, Ran; Zhou, Chuang‐Bing

    2015-01-01

    ...‐pressure groundwater flow conditions. The interpretation of the HPPT data, however, remains difficult due to the transition of flow conditions in the conducting structures and the hydraulic fracturing...

  6. Effect of tracer buoyancy on tracer experiments conducted in fractured crystalline bedrock

    Science.gov (United States)

    Becker, Matthew W.

    2003-02-01

    Tracer buoyancy has been shown to influence breakthrough from two-well tracer experiments conducted in porous media. Two-well tracer experiments are presented from fractured crystalline bedrock, in which the specific gravity of the tracer injectate varied from 1.0002 to 1.0133. Under the forced hydraulic conditions imposed, no difference in breakthrough was noted for the three experiments. These results show that even relatively dense tracer injectate solutions may have an insignificant effect on breakthrough when imposed gradients are sufficiently large.

  7. High Resolution Hydraulic Profiling and Groundwater Sampling using FLUTe™ System in a Fractured Limestone Setting

    DEFF Research Database (Denmark)

    Janniche, Gry Sander; Christensen, Anders G.; Grosen, Bernt;

    innovative investi-gation methods for characterization of the source zone hydrogeology and contamination, including FLUTe system hydraulic profiling and Water-FLUTe multilevel groundwater sampling, in fractured bryo-zoan limestone bedrock. High resolution hydraulic profiling was conducted in three cored......Characterization of the contaminant source zone architecture and the hydraulics is essential to develop accurate site specific conceptual models, delineate and quantify contaminant mass, perform risk as-sessment, and select and design remediation alternatives. This characterization is particularly...... challeng-ing in deposit types as fractured limestone. The activities of a bulk distribution facility for perchloroe-thene (PCE) and trichloroethene (TCE) at the Naverland site near Copenhagen, Denmark, has resulted in PCE and TCE DNAPL impacts to a fractured clay till and an underlying fractured limestone...

  8. Fractal Dimension of Fracture Surface in Rock Material after High Temperature

    Directory of Open Access Journals (Sweden)

    Z. Z. Zhang

    2015-01-01

    Full Text Available Experiments on granite specimens after different high temperature under uniaxial compression were conducted and the fracture surfaces were observed by scanning electron microscope (SEM. The fractal dimensions of the fracture surfaces with increasing temperature were calculated, respectively. The fractal dimension of fracture surface is between 1.44 and 1.63. Its value approximately goes up exponentially with the increase of temperature. There is a quadratic polynomial relationship between the rockburst tendency and fractal dimension of fracture surface; namely, a fractal dimension threshold can be obtained. Below the threshold value, a positive correlativity shows between rockburst tendency and fractal dimension; when the fractal dimension is greater than the threshold value, it shows an inverse correlativity.

  9. High-energy gas-fracturing development. Quarterly report, October-December 1982

    Energy Technology Data Exchange (ETDEWEB)

    Cuderman, J.F.

    1983-02-01

    The purpose of this study is to develop and optimize the High Energy Gas Fracturing (HEGF) technique to produce multiple fractures around a wellbore in order to stimulate natural-gas production in Devonian shale. The HEGF technique uses a wellbore charge of a propellant tailored to produce pressure loading in the borehole that avoids crushing yet produces multiple fractures radiating from the wellbore. The multiple-fracture regime has been characterized and releated to parameters such as borehole size, pressure risetime, and surface-wave velocity. Pressure risetimes and peak pressures, measured for different propellants in boreholes to specify a propellant for a desired peak pressure and pressure risetime. Semiempirical models, using results from previous experiments, successfully relate stress, acceleration, and fracture radii in surrounding rock to peak pressure and pressure risetime. A finite-element model also has been developed which predicts fracture type and direction of fractures as a function of pressure loading, in situ stress, and material properties. A full-scale HEGF system has been developed for application in gas-well-stimulation experiments in Devonian shale. During this quarter, a proof test of the full-scale HEGF was conducted at the Nevada Test Site (NTS). The designed pressure pulse of 0.5 ms risetime was achieved, and the tamp remained in place during the test. The borehole was successfully cleared posttest. Multiple fracturing was verified with a downhole TV camera. The test of the full-scale hardware and its operational capability was successful. As a result, the HEGF system is ready for application in gas-well-stimulation experiments in Devonian shale. Tests were conducted to determine worst-case accident scenarios to establish sensitivity to shock and fire. There appears to be no risk of initiation resulting from shock or breakage of the propellant-canister segments.

  10. An Innovative High Thermal Conductivity Fuel Design

    Energy Technology Data Exchange (ETDEWEB)

    PI: James S. Tulenko; Co-PI: Ronald H. Baney,

    2007-10-14

    Uranium dioxide (UO2) is the most common fuel material in commercial nuclear power reactors. UO2 has the advantages of a high melting point, good high-temperature stability, good chemical compatibility with cladding and coolant, and resistance to radiation. The main disadvantage of UO2 is its low thermal conductivity. During a reactor’s operation, because the thermal conductivity of UO2 is very low, for example, about 2.8 W/m-K at 1000 oC [1], there is a large temperature gradient in the UO2 fuel pellet, causing a very high centerline temperature, and introducing thermal stresses, which lead to extensive fuel pellet cracking. These cracks will add to the release of fission product gases after high burnup. The high fuel operating temperature also increases the rate of fission gas release and the fuel pellet swelling caused by fission gases bubbles. The amount of fission gas release and fuel swelling limits the life time of UO2 fuel in reactor. In addition, the high centerline temperature and large temperature gradient in the fuel pellet, leading to a large amount of stored heat, increase the Zircaloy cladding temperature in a lost of coolant accident (LOCA). The rate of Zircaloy-water reaction becomes significant at the temperature above 1200 oC [2]. The ZrO2 layer generated on the surface of the Zircaloy cladding will affect the heat conduction, and will cause a Zircaloy cladding rupture. The objective of this research is to increase the thermal conductivity of UO2, while not affecting the neutronic property of UO2 significantly. The concept to accomplish this goal is to incorporate another material with high thermal conductivity into the UO2 pellet. Silicon carbide (SiC) is a good candidate, because the thermal conductivity of single crystal SiC is 60 times higher than that of UO2 at room temperature and 30 times higher at 800 oC [3]. Silicon carbide also has the properties of low thermal neutron absorption cross section, high melting point, good chemical

  11. High fracture toughness in a hierarchical nanostructured zirconium

    Energy Technology Data Exchange (ETDEWEB)

    Li, Ming [State Key Laboratory of Metastable Materials Science and Technology, Yanshan University, 066004 Qinhuangdao (China); College of Mechanical Engineering, Yanshan University, 066004 Qinhuangdao (China); Guo, Defeng; Ma, Tengyun; Zhang, Guosheng; Shi, Yindong [State Key Laboratory of Metastable Materials Science and Technology, Yanshan University, 066004 Qinhuangdao (China); Zhang, Xiangyi, E-mail: xyzh66@ysu.edu.cn [State Key Laboratory of Metastable Materials Science and Technology, Yanshan University, 066004 Qinhuangdao (China)

    2014-06-01

    Nanocrystalline metals usually exhibit a high strength but a disappointingly low ductility and toughness, which limit their practical utility. Here, we report a high fracture toughness (K{sub IC}∼117 MPa m{sup 1/2}) in a hierarchical nanostructured Zr that consists of nano-, sub-micrometer- and micrometer-sized grains, which is much larger than that K{sub IC}∼78 MPa m{sup 1/2} in coarse-grained Zr. This hierarchical nanostructured Zr shows a good combination of yield strength (σ{sub s}∼550 MPa) and fracture toughness as compared with its coarse-grained counterpart. We expect that these results will have implications in the enhancement of fracture toughness of nanocrystalline materials and in the design of high-performance structural materials.

  12. Long-term Sustainability of Fracture Conductivity in Geothermal Systems using Proppants

    Energy Technology Data Exchange (ETDEWEB)

    Earl D Mattson; Ghanashyam Neupane; Mitchell Plummer; Clay Jones; Joe Moore

    2016-02-01

    Long-term sustainability of fracture conductivity is critical for commercial success of engineered geothermal system (EGS) and hydrogeothermal field sites. The injection of proppants has been suggested as a means to enhance the conductivity in these systems. Several studies have examined the chemical behavior of proppants that are not at chemical equilibrium with the reservoir rock and water. These studies have suggested that in geothermal systems, geochemical reactions can lead to enhance proppant dissolution and deposition alteration minerals. We hypothesize that proppant dissolution will decrease the strength of the proppant and can potentially reduce the conductivity of the fracture. To examine the geomechanical strength of proppants, we have performed modified crushing tests of proppants and reservoir rock material that was subjected to geothermal reservoir temperature conditions. The batch reactor experiments heated crushed quartz monzonite rock material, proppants (either quartz sand, sintered bauxite or kryptospheres) with Raft River geothermal water to 250 ºC for a period of 2 months. Solid and liquid samples were shipped to University of Utah for chemical characterization with ICP-OES, ICP-MS, and SEM. A separate portion of the rock/proppant material was subjected to a modified American Petroleum Institute ISO 13503-2 proppant crushing test. This test is typically used to determine the maximum stress level that can be applied to a proppant pack without the occurrence of unacceptable proppant crushing. We will use the test results to examine potential changes in proppant/reservoir rock geomechanical properties as compared to samples that have not been subjected to geothermal conditions. These preliminary results will be used to screen the proppants for long term use in EGS and hot hydrogeothermal systems.

  13. High H- ionic conductivity in barium hydride

    Science.gov (United States)

    Verbraeken, Maarten C.; Cheung, Chaksum; Suard, Emmanuelle; Irvine, John T. S.

    2015-01-01

    With hydrogen being seen as a key renewable energy vector, the search for materials exhibiting fast hydrogen transport becomes ever more important. Not only do hydrogen storage materials require high mobility of hydrogen in the solid state, but the efficiency of electrochemical devices is also largely determined by fast ionic transport. Although the heavy alkaline-earth hydrides are of limited interest for their hydrogen storage potential, owing to low gravimetric densities, their ionic nature may prove useful in new electrochemical applications, especially as an ionically conducting electrolyte material. Here we show that barium hydride shows fast pure ionic transport of hydride ions (H-) in the high-temperature, high-symmetry phase. Although some conductivity studies have been reported on related materials previously, the nature of the charge carriers has not been determined. BaH2 gives rise to hydride ion conductivity of 0.2 S cm-1 at 630 °C. This is an order of magnitude larger than that of state-of-the-art proton-conducting perovskites or oxide ion conductors at this temperature. These results suggest that the alkaline-earth hydrides form an important new family of materials, with potential use in a number of applications, such as separation membranes, electrochemical reactors and so on.

  14. Highly stretchable electrospun conducting polymer nanofibers

    Science.gov (United States)

    Boubée de Gramont, Fanny; Zhang, Shiming; Tomasello, Gaia; Kumar, Prajwal; Sarkissian, Andranik; Cicoira, Fabio

    2017-08-01

    Biomedical electronics research targets both wearable and biocompatible electronic devices easily adaptable to specific functions. To achieve such goals, stretchable organic electronic materials are some of the most intriguing candidates. Herein, we develop highly stretchable poly-(3,4-ethylenedioxythiphene) (PEDOT) doped with tosylate (PEDOT:Tos) nanofibers. A two-step process involving electrospinning of a carrier polymer (with oxidant) and vapor phase polymerization was used to produce fibers on a polydimethylsiloxane substrate. The fibers can be stretched up to 140% of the initial length maintaining high conductivity.

  15. Highly Conductive Multifunctional Graphene Polycarbonate Nanocomposites

    Science.gov (United States)

    Yoonessi, Mitra; Gaier, James R.

    2010-01-01

    Graphene nanosheet bisphenol A polycarbonate nanocomposites (0.027 2.2 vol %) prepared by both emulsion mixing and solution blending methods, followed by compression molding at 287 C, exhibited dc electrical percolation threshold of approx.0.14 and approx.0.38 vol %, respectively. The conductivities of 2.2 vol % graphene nanocomposites were 0.512 and 0.226 S/cm for emulsion and solution mixing. The 1.1 and 2.2 vol % graphene nanocomposites exhibited frequency-independent behavior. Inherent conductivity, extremely high aspect ratio, and nanostructure directed assembly of the graphene using PC nanospheres are the main factors for excellent electrical properties of the nanocomposites. Dynamic tensile moduli of nanocomposites increased with increasing graphene in the nanocomposite. The glass transition temperatures were decreased with increasing graphene for the emulsion series. High-resolution electron microscopy (HR-TEM) and small-angle neutron scattering (SANS) showed isolated graphene with no connectivity path for insulating nanocomposites and connected nanoparticles for the conductive nanocomposites. A stacked disk model was used to obtain the average particle radius, average number of graphene layers per stack, and stack spacing by simulation of the experimental SANS data. Morphology studies indicated the presence of well-dispersed graphene and small graphene stacking with infusion of polycarbonate within the stacks.

  16. Laser patterning of highly conductive flexible circuits

    Science.gov (United States)

    Ji, Seok Young; Muhammed Ajmal, C.; Kim, Taehun; Chang, Won Seok; Baik, Seunghyun

    2017-04-01

    There has been considerable attention paid to highly conductive flexible adhesive (CFA) materials as electrodes and interconnectors for future flexible electronic devices. However, the patterning technology still needs to be developed to construct micro-scale electrodes and circuits. Here we developed the selective laser sintering technology where the pattering and curing were accomplished simultaneously without making additional masks. The CFA was composed of micro-scale Ag flakes, multiwalled carbon nanotubes decorated with Ag nanoparticles, and a nitrile-butadiene-rubber matrix. The Teflon-coated polyethylene terephthalate film was used as a flexible substrate. The width of lines (50-500 μm) and circuit patterns were controlled by the programmable scanning of a focused laser beam (power = 50 mW, scanning speed = 1 mm s-1). The laser irradiation removed solvent and induced effective coalescence among fillers providing a conductivity as high as 25 012 S cm-1. The conductivity stability was excellent under the ambient air and humid environments. The normalized resistance change of the pattern was smaller than 1.2 at the bending radius of 5 mm. The cyclability and adhesion of the laser-sintered line pattern on the substrate was excellent. A flexible circuit was fabricated sequentially for operating light emitting diodes during the bending motion, demonstrating excellent feasibility for practical applications in flexible electronics.

  17. Highly conductive, printable pastes from capillary suspensions

    Science.gov (United States)

    Schneider, Monica; Koos, Erin; Willenbacher, Norbert

    2016-08-01

    We have used the capillary suspension phenomenon to design conductive pastes for printed electronic applications, such as front side metallization of solar cells, without non-volatile, organic additives that often deteriorate electrical properties. Adding a small amount of a second, immiscible fluid to a suspension creates a network of liquid bridges between the particles. This capillary force-controlled microstructure allows for tuning the flow behavior in a wide range. Yield stress and low-shear viscosity can be adjusted such that long-term stability is provided by inhibiting sedimentation, and, even more importantly, narrow line widths and high aspect ratios are accessible. These ternary mixtures, called capillary suspensions, exhibit a strong degree of shear thinning that allows for conventional coating or printing equipment to be used. Finally, the secondary fluid, beneficial for stability and processing of the wet paste, completely evaporates during drying and sintering. Thus, we obtained high purity silver and nickel layers with a conductivity two times greater than could be obtained with state-of-the-art, commercial materials. This revolutionary concept can be easily applied to other systems using inorganic or even organic conductive particles and represents a fundamental paradigm change to the formulation of pastes for printed electronics.

  18. Optimal Management of High-Energy Pilon Fractures.

    Science.gov (United States)

    Chan, Raymond; Taylor, Benjamin C; Gentile, John

    2015-08-01

    The ideal treatment method for fibular fractures associated with high-energy pilon injuries remains unknown. In this investigation, the authors reviewed a consecutive series of 137 patients who sustained high-energy pilon injuries and assessed the effect of fibular fixation and timing on radiographic and clinical outcomes. At a mean follow-up of 18.7 months, the authors found that the presence or lack of fibular fixation did not have an effect on the timing or rate of union of the pilon fractures; similarly, there was no significant difference between these groups regarding the presence or development of coronal or sagittal malalignment intraoperatively or at final follow-up. Fibular union rates were also not significantly different between groups, but fibular fixation increased operative time in a statistically significant manner. Interestingly, when comparing fibular fixation during the temporization stage vs the definitive fixation stage, the authors found that early fixation of the fibular fracture also had no effect on alignment, healing, or complication rates. Fixation of the fibula during external fixation placement statistically increased operative time during temporization but did not significantly decrease operative time during definitive stabilization. The authors cannot recommend fibular fixation with all associated pilon fractures because the presence or timing of fibular fixation does not significantly change the radiographic outcomes, complication rate, or need for future surgical interventions. Future clinical analysis is needed to further delineate the indication for fibular fixation in this scenario.

  19. Highly Conducting Graphite Epoxy Composite Demonstrated

    Science.gov (United States)

    Gaier, James R.

    1999-01-01

    Weight savings as high as 80 percent could be achieved if graphite polymer composites could replace aluminum in structures such as electromagnetic interference shielding covers and grounding planes. This could result in significant cost savings, especially for the mobile electronics found in spacecraft, aircraft, automobiles, and hand-held consumer electronics. However, such composites had not yet been fabricated with conductivity sufficient to enable these applications. To address this lack, a partnership of the NASA Lewis Research Center, Manchester College, and Applied Sciences, Inc., fabricated nonmetallic composites with unprecedented electrical conductivity. For these composites, heat-treated, vapor-grown graphite fibers were selected which have a resistivity of about 80 mW-cm, more than 20 times more conductive than typical carbon fibers. These fibers were then intercalated with iodine bromide (IBr). Intercalation is the insertion of guest atoms or molecules between the carbon planes of the graphite fibers. Since the carbon planes are not highly distorted in the process, intercalation has little effect on mechanical and thermal properties. Intercalation does, however, lower the carbon fiber resistivity to less than 10 mW-cm, which is comparable to that of metal fibers. Scaleup of the reaction was required since the initial intercalation experiments would be carried out on 20-mg quantities of fibers, and tens of grams of intercalated fibers would be needed to fabricate even small demonstration composites. The reaction was first optimized through a time and temperature study that yielded fibers with a resistivity of 8.7 2 mW-cm when exposed to IBr vapor at 114 C for 24 hours. Stability studies indicated that the intercalated fibers rapidly lost their conductivity when exposed to temperatures as low as 40 C in air. They were not, however, susceptible to degradation by water vapor in the manner of most graphite intercalation compounds. The 1000-fold scaleup

  20. Status of the art: hydraulic conductivity of acid- fractures; Condutividade hidraulica de fratura acida: estado da arte

    Energy Technology Data Exchange (ETDEWEB)

    Rodrigues, Valdo Ferreira [Universidade Estadual do Norte Fluminense Darcy Ribeiro (LENEP/UENF), Macae, RJ (Brazil). Centro de Ciencia e Tecnologia. Lab. de Engenharia e Exploracao de Petroleo; Campos, Wellington [PETROBRAS, RJ (Brazil). E and P Engenharia de Producao. Gerencia de Completacao e Avaliacao], e-mail: wcampos@petrobras.com.br

    2010-06-15

    This paper presents a review of the hydraulic conductivity models developed for acid fractures in almost four decades of studies in petroleum engineering. These studies have often benefited from theories and experiments carried out in areas of knowledge such as physics, geology, hydrology, fluid mechanics, rock mechanics and tribology. The review showed that the pioneer study of Nierode and Kruk (1973) is still used in commercial software and influences the current studies. There was significant evolution on the quantitative surface topography characterization of the fractures and their impact on the hydraulic conductivity. The same occurred for the effects of acid dissolution on the rock resistance. Improvements on correlations similar to the Nierode and Kruk can be applied at once on the acid fracturing project and evaluation practice for the cases of rough dissolution pattern. A method to consider the overall conductivity from heterogeneous channels and roughness pattern was recently proposed. The complexity of the theoretical fundaments, specially the range of validity of the equations in face of the simplifications assumed, the difficulty of performing representative laboratory and field experiments, the difficulty of characterizing quantitatively the fractures surface topography and its effects on the conductivity, and the large variety of rocks and acid systems keep this subject open for research. (author)

  1. Fracture behaviour and defect evaluation of larger diameter, HSLA steels, very high pressure linepipes

    Energy Technology Data Exchange (ETDEWEB)

    Demofonti, G.; Mannucci, G. [Centro Sviluppo materiali Via di Castel Romano, Rome (Italy); Barsanti, L.; Spinelli, C.M. [SNAM SPA, Milan (Italy); Hillenbrand, H.G. [Europipe GmbH Sornerstrasse, Ratengen (Germany)

    2000-07-01

    A joint venture research program by members of the European Union was conducted to examine the fracture behaviour of large diameter API X100 grade steel pipes at very high pressure (up to 150 bar). The impetus for this study has been the need to develop a larger diameter pipe to transport natural gas at high pressure for very long distances, thereby reducing transportation costs. The material examined in this study was the API X100 high strength low alloy steel grade pipe produced by Europipe for use in large diameter pipes. The current status of API X100 steel with respect to the combination of chemical composition, rolling variables and mechanical properties was presented. The ductile-brittle transition behaviour of the material was also examined in conjunction with the control of long shear propagation fracture and full scale crack propagation tests on lines operating at very high stress. The defect tolerance behaviour of the pipe was investigated with respect to axial surface defects and burst tests with water. The material showed full ductile fracture behaviour down to -20 degrees C. The toughness characteristics of the materials according to Charpy V energy tests was good enough to warrant the arrest of a long running shear fracture on a 56 inch diameter, at operating pressure over 12.6 MPa. 8 refs., 6 tabs., 7 figs.

  2. Exceptional electrical conductivity and fracture resistance of 3D interconnected graphene foam/epoxy composites.

    Science.gov (United States)

    Jia, Jingjing; Sun, Xinying; Lin, Xiuyi; Shen, Xi; Mai, Yiu-Wing; Kim, Jang-Kyo

    2014-06-24

    Cellular-structured graphene foam (GF)/epoxy composites are prepared based on a three-step fabrication process involving infiltration of epoxy into the porous GF. The three-dimensional (3D) GF is grown on a Ni foam template via chemical vapor deposition. The 3D interconnected graphene network serves as fast channels for charge carriers, giving rise to a remarkable electrical conductivity of the composite, 3 S/cm, with only 0.2 wt % GF. The corresponding flexural modulus and strength increase by 53 and 38%, respectively, whereas the glass transition temperature increases by a notable 31 °C, compared to the solid neat epoxy. The GF/epoxy composites with 0.1 wt % GF also deliver an excellent fracture toughness of 1.78 MPa·m(1/2), 34 and 70% enhancements against their "porous" epoxy and solid epoxy counterparts, respectively. These observations signify the unrivalled effectiveness of 3D GF relative to 1D carbon nanotubes or 2D functionalized graphene sheets as reinforcement for polymer composites without issues of nanofiller dispersion and functionalization prior to incorporation into the polymer.

  3. Mass transport in fracture media: impact of the random function model assumed for fractures conductivity; Transporte de masa en medio fracturado: impacto del modelo estocastico de conductividad en las fracturas

    Energy Technology Data Exchange (ETDEWEB)

    Capilla, J. E.; Rodrigo, J.; Gomez Hernandez, J. J.

    2003-07-01

    Characterizing the uncertainty of flow and mass transport models requires the definition of stochastic models to describe hydrodynamic parameters. Porosity and hydraulic conductivity (K) are two of these parameters that exhibit a high degree of spatial variability. K is usually the parameter whose variability influence to a more extended degree solutes movement. In fracture media, it is critical to properly characterize K in the most altered zones where flow and solutes migration tends to be concentrated. However, K measurements use to be scarce and sparse. This fact calls to consider stochastic models that allow quantifying the uncertainty of flow and mass transport predictions. This paper presents a convective transport problem solved in a 3D block of fractured crystalline rock. the case study is defined based on data from a real geological formation. As the scarcity of K data in fractures does not allow supporting classical multi Gaussian assumptions for K in fractures, the non multi Gaussian hypothesis has been explored, comparing mass transport results for alternative Gaussian and non-Gaussian assumptions. The latter hypothesis allows reproducing high spatial connectivity for extreme values of K. This feature is present in nature, might lead to reproduce faster solute pathways, and therefore should be modeled in order to obtain reasonably safe prediction of contaminants migration in a geological formation. The results obtained for the two alternative hypotheses show a remarkable impact of the K random function model in solutes movement. (Author) 9 refs.

  4. High pressure fracturing in Colombia: a quantum leap

    Energy Technology Data Exchange (ETDEWEB)

    Velasquez, Juan C. [BP Exploration (United Kingdom); Gutierrez, Jim; Ham, Ernesto; Castro, Alberto [BJ Services Company (United States)

    2004-07-01

    Fracturing has become one of the most common stimulation and well completion techniques in petroleum production. Due to the deeper depths and high frac gradients encountered in some areas, various treatments have resulted in early screen outs or aborted operations due to insufficient rate limited by the available treating pressures. A state of the art technology and high pressure equipment including the largest frac pumps (rated at 2,700 hhp) in the world, were used in Colombian fields to overcome these limitations. The reliability of this equipment has allowed the treatment of these wells to operating pressures of up to 18,000 psi and rates in excess of 40 bpm, placing up to 400,000 lbs of bauxite. Bottom hole treating pressures of 25,000 psi also were reached. This paper describes the development of the fracture campaign and relates the jobs performed to date, including the results and lessons learned (author)

  5. Highly conducting one-dimensional solids

    CERN Document Server

    Evrard, Roger; Doren, Victor

    1979-01-01

    Although the problem of a metal in one dimension has long been known to solid-state physicists, it was not until the synthesis of real one-dimensional or quasi-one-dimensional systems that this subject began to attract considerable attention. This has been due in part to the search for high­ temperature superconductivity and the possibility of reaching this goal with quasi-one-dimensional substances. A period of intense activity began in 1973 with the report of a measurement of an apparently divergent conduc­ tivity peak in TfF-TCNQ. Since then a great deal has been learned about quasi-one-dimensional conductors. The emphasis now has shifted from trying to find materials of very high conductivity to the many interesting problems of physics and chemistry involved. But many questions remain open and are still under active investigation. This book gives a review of the experimental as well as theoretical progress made in this field over the last years. All the chapters have been written by scientists who have ...

  6. Estimation of block conductivities from hydrologically calibrated fracture networks. Description of methodology and application to Romuvaara investigation area

    Energy Technology Data Exchange (ETDEWEB)

    Niemi, A. [Royal Institute of Technology, Stockholm (Sweden); Kontio, K.; Kuusela-Lahtinen, A.; Vaittinen, T. [VTT Communities and Infrastructure, Espoo (Finland)

    1999-03-01

    This study looks at heterogeneity in hydraulic conductivity at Romuvaara site. It concentrates on the average rock outside the deterministic fracture zones, especially in the deeper parts of the bedrock. A large number of stochastic fracture networks is generated based on geometrical data on fracture geometry from the site. The hydraulic properties of the fractures are determined by calibrating the networks against well test data. The calibration is done by starting from an initial estimate for fracture transmissivity distribution based on 2 m interval flow meter data, simulating the 10 m constant head injection test behaviour in a number of fracture network realisations and comparing the simulated well tests statistics to the measured ones. A large number of possible combinations of mean and standard deviation of fracture transmissivities are tested and the goodness-of-fit between the measured and simulated results determined by means of the bootstrapping method. As the result, a range of acceptable fracture transmissivity distribution parameters is obtained. In the accepted range, the mean of log transmissivity varies between -13.9 and -15.3 and standard deviation between 4.0 and 3.2, with increase in standard deviation compensating for decrease in mean. The effect of spatial autocorrelation was not simulated. The variogram analysis did, however, give indications that an autocorrelation range of the order of 10 m might be realistic for the present data. Based on the calibrated fracture networks, equivalent continuum conductivities of the calibrated 30 m x 30 m x 30 m conductivity blocks were determined. For each realisation, three sets of simulations was carried out with the main gradient in x, y and z directions, respectively. Based on these results the components of conductivity tensor were determined. Such data can be used e.g. for stochastic continuum type Monte Carlo simulations with larger scale models. The hydraulic conductivities in the direction of the

  7. High mortality and poor morbidity after hip fracture in patients with previous vertebral fractures.

    Science.gov (United States)

    Ha, Yong-Chan; Baek, Ji-Hoon; Ko, Young-Bong; Park, Sang-Min; Song, Sang-Heon

    2015-09-01

    Although vertebral fracture in patients is a predictor of subsequent hip fracture, no study has assessed the mortality and functional outcome in hip fracture patients with previous vertebral fracture. Between September 2009 and December 2012, we evaluated 246 patients over 50-years-of-age diagnosed with femoral neck or intertrochanteric fractures who underwent surgery. The patients were categorized into two groups and two subgroups. Group Ia comprised 150 patients with previous vertebral fracture at the time of hip fracture. Group Ib comprised 96 patients with no vertebral fracture. Group IIa consisted of 76 patients fracture. Group IIb comprised 69 patients fracture. The mortality rate and functional outcome of osteoporotic hip fracture patients with and without vertebral fractures were compared. The cumulative mortality rate at 6 and 12 months post-fracture was 19 and 23 % in Group Ia and 6 and 7 % in Group Ib, respectively. In subgroup analysis, the cumulative mortality rate at 6 and 12 months was 13 and 17 % in Group IIa and 3 and 4 % in Group IIb, respectively. Shut-in patients at the final follow-up included 51 of 103 (49.5 %) patients in Group Ia and 19 of 83 (22.9 %) patients in Group Ib. In subgroup analysis, the shut-in patients included 18 of 58 (31.0 %) patients in Group IIa and 10 of 62 (16.1 %) patients in Group IIb. Previous vertebral fracture was associated with a poor functional outcome and increased mortality in patients with hip fracture.

  8. A study of high-quality foamed fracturing fluid properties

    Energy Technology Data Exchange (ETDEWEB)

    Wheeler, R.S. [BJ Services Company, Houston, TX (United States)

    2010-07-01

    Successful stimulation and extraction of hydrocarbons from unconventional reservoirs have created different approaches to the stimulation process. Types of treatment vary from slickwater stimulations, low dosages of polyacrylamide, conventional crosslinked, or linear gelled fluids. There has also been successful treatments in implementing a high-quality foam stimulation in some shale formations. The advantage of using a high quality foam is its reduced environmental impact as it uses very small amounts of water as compared to high-rate slickwater stimulations. However, there is little published information on high-quality fluid foam properties. In order to examine the rheological properties of high-quality foamed fracturing fluids and compare it to other fluids that are common in fracturing treatments, this paper presented a study that examined the fluid characteristics of high-quality foams as compared to typical 50-70 quality foams. The study demonstrated trends of viscosity, foam stability and temperature sensitivity of high-quality foams using xanthan, guar-based gelling agents and viscoelastic base fluids. The paper described the test equipment and procedures, as well as the test results. The tests using guar as the base fluid gellant demonstrated increasing viscosity with increased foam quality. 2 tabs., 22 figs.

  9. High reliability of an algorithm for choice of implants in hip fracture patients

    DEFF Research Database (Denmark)

    Palm, Henrik; Posner, Eva; Ahler-Toftehøj, Hans-Ulrik;

    2013-01-01

    Hip fracture treatment is controversial, with high complication rates. An algorithm for hip fracture surgery has shown reduced reoperation rates, but choice of implant is based on the commonly used fracture classifications, which were previously evaluated to be unreliable. The purpose of this study...... was to investigate the reliability of the algorithm....

  10. Dyke propagation and tensile fracturing at high temperature and pressure, insights from experimental rock mechanics.

    Science.gov (United States)

    Bakker, Richard; Benson, Philip; Vinciguerra, Sergio

    2014-05-01

    It is well known that magma ascends trough the crust by the process of dyking. To enable dyke emplacement, basement rocks typically fail in a mode 1 fracture, which acts as conduits for magma transport. An overpressure of the ascending magma will further open/widen the fracture and permit the fracture to propagate. In order to further understand the emplacement and arrest of dykes in the subsurface, analogue and numerical studies have been conducted. However, a number of assumptions regarding rock mechanical behaviour frequently has to be made as such data are very hard to directly measure at the pressure/temperature conditions of interest: high temperatures at relatively shallow depths. Such data are key to simulating the magma intrusion dynamics through the lithologies that underlie the volcanic edifice. Here we present a new laboratory setup, which allows us to investigate the tensile fracturing properties under both temperature and confining pressure, and the emplacement of molten material within the newly formed fracture. We have modified a traditional tri-axial test assembly setup to be able to use a Paterson type High Pressure, High Temperature deformation apparatus. Sample setup consists of cylindrical rock samples with a 22 mm diameter and a 8 mm bore at their centre, filled with a material chosen as such that it's in a liquid state at the experimental temperature and solid at room temperature to enable post-experiment analysis. The top and lower parts of the rock sample are fitted with plugs, sealing in the melt. The assembly is then placed between ceramic pistons to ensure there are no thermal gradients across the sample. The assembly is jacketed to ensure the confining medium (Ar) cannot enter the assembly. A piston is driven into the sample such that the inner conduit materials pressure is slowly increased. At some point a sufficient pressure difference between the inner and outer surfaces causes the sample to deform and fail in the tensile regime

  11. Unconventional High Density Vertically Aligned Conducting Polymer

    Science.gov (United States)

    2014-08-21

    CNTs also provide a porous scaffold to deposit PEDOT via CVD. To fabricate PEDOT/ A-CNT electrodes, the conducting polymer was conformally deposited on...250μm long A-CNTs using oCVD, varying thickness from few to ten nm by controlling deoposition and polymerization times. Electron microscopy

  12. High serum adiponectin predicts incident fractures in elderly men: Osteoporotic fractures in men (MrOS) Sweden.

    Science.gov (United States)

    Johansson, Helena; Odén, Anders; Lerner, Ulf H; Jutberger, Hans; Lorentzon, Mattias; Barrett-Connor, Elizabeth; Karlsson, Magnus K; Ljunggren, Osten; Smith, Ulf; McCloskey, Eugene; Kanis, John A; Ohlsson, Claes; Mellström, Dan

    2012-06-01

    Adipocytes and osteoblasts share a common progenitor, and there is, therefore, potential for both autocrine and endocrine effects of adiponectin on skeletal metabolism. The aim of the present study was to determine whether high serum adiponectin was associated with an increased risk of fracture in elderly men. We studied the relationship between serum adiponectin and the risk of fracture in 999 elderly men drawn from the general population and recruited to the Osteoporotic Fractures in Men (MrOS) study in Gothenburg, Sweden. Baseline data included general health questionnaires, lifestyle questionnaires, body mass index (BMI), bone mineral density (BMD), serum adiponectin, osteocalcin, and leptin. Men were followed for up to 7.4 years (average, 5.2 years). Poisson regression was used to investigate the relationship between serum adiponectin, other risk variables and the time-to-event hazard function of fracture. Median levels of serum adiponectin at baseline were 10.4 µg/mL (interquartile range, 7.7-14.3). During follow-up, 150 men sustained one or more fractures. The risk of fracture increased in parallel with increasing serum adiponectin (hazard ratio [HR]/SD, 1.46; 95% confidence interval [CI], 1.23-1.72) and persisted after multivariate-adjusted analysis (HR/SD, 1.30; 95% CI, 1.09-1.55). Serum adiponectin shows graded stepwise association with a significant excess risk of fracture in elderly men that was independent of several other risk factors for fracture. Its measurement holds promise as a risk factor for fracture in men.

  13. Nanostructured diamond-TiC composites with high fracture toughness

    Science.gov (United States)

    Wang, Haikuo; He, Duanwei; Xu, Chao; Tang, Mingjun; Li, Yu; Dong, Haini; Meng, Chuanmin; Wang, Zhigang; Zhu, Wenjun

    2013-01-01

    We report the preparation of nanostructured diamond-TiC composites with high fracture toughness and high hardness starting from a ball-milled mixture of nano-sized Ti3SiC2 and submicron-sized diamond by simultaneously tuning the pressure-temperature conditions. The phase segregation of Ti3SiC2 at pressure of 5.5 GPa were investigated by X-ray diffraction and high resolution transmission electron microscopy, we found that the Ti3SiC2 could decompose into nanosized TiC and amorphous Ti-Si at 600-700 °C. The subsequent reaction between diamond and Ti-Si led to an amorphous Ti-Si-C matrix in which diamond and TiC crystals are embedded. With a loading force of 98 N, the measured fracture toughness KIC and Vicker's hardness HV of the synthesized composites reach up to 14 MPa m1/2 and 45.5 GPa, respectively. Our results demonstrate that the nanocrystalline/amorphous bonding matrix could largely enhance the toughness of the brittle composites.

  14. Measurement of fracture properties of concrete at high strain rates

    Science.gov (United States)

    Rey-De-Pedraza, V.; Cendón, D. A.; Sánchez-Gálvez, V.; Gálvez, F.

    2017-01-01

    An analysis of the spalling technique of concrete bars using the modified Hopkinson bar was carried out. A new experimental configuration is proposed adding some variations to previous works. An increased length for concrete specimens was chosen and finite-element analysis was used for designing a conic projectile to obtain a suitable triangular impulse wave. The aim of this initial work is to establish an experimental framework which allows a simple and direct analysis of concrete subjected to high strain rates. The efforts and configuration of these primary tests, as well as the selected geometry and dimensions for the different elements, have been focused to achieve a simple way of identifying the fracture position and so the tensile strength of tested specimens. This dynamic tensile strength can be easily compared with previous values published in literature giving an idea of the accuracy of the method and technique proposed and the possibility to extend it in a near future to obtain other mechanical properties such as the fracture energy. The tests were instrumented with strain gauges, accelerometers and high-speed camera in order to validate the results by different ways. Results of the dynamic tensile strength of the tested concrete are presented. This article is part of the themed issue 'Experimental testing and modelling of brittle materials at high strain rates'.

  15. Measurement of fracture properties of concrete at high strain rates.

    Science.gov (United States)

    Rey-De-Pedraza, V; Cendón, D A; Sánchez-Gálvez, V; Gálvez, F

    2017-01-28

    An analysis of the spalling technique of concrete bars using the modified Hopkinson bar was carried out. A new experimental configuration is proposed adding some variations to previous works. An increased length for concrete specimens was chosen and finite-element analysis was used for designing a conic projectile to obtain a suitable triangular impulse wave. The aim of this initial work is to establish an experimental framework which allows a simple and direct analysis of concrete subjected to high strain rates. The efforts and configuration of these primary tests, as well as the selected geometry and dimensions for the different elements, have been focused to achieve a simple way of identifying the fracture position and so the tensile strength of tested specimens. This dynamic tensile strength can be easily compared with previous values published in literature giving an idea of the accuracy of the method and technique proposed and the possibility to extend it in a near future to obtain other mechanical properties such as the fracture energy. The tests were instrumented with strain gauges, accelerometers and high-speed camera in order to validate the results by different ways. Results of the dynamic tensile strength of the tested concrete are presented.This article is part of the themed issue 'Experimental testing and modelling of brittle materials at high strain rates'.

  16. Fracture hydraulic conductivity in the Mexico City clayey aquitard: Field piezometer rising-head tests

    Science.gov (United States)

    Vargas, Carlos; Ortega-Guerrero, Adrián

    A regional lacustrine aquitard covers the main aquifer of the metropolitan area of Mexico City. The aquitard's hydraulic conductivity (K') is fundamental for evaluating the natural protection of the aquifer against a variety of contaminants present on the surface and its hydraulic response. This study analyzes the distribution and variation of K' in the plains of Chalco, Texcoco and Mexico City (three of the six former lakes that existed in the Basin of Mexico), on the basis of 225 field-permeability tests, in nests of existing piezometers located at depths of 2-85 m. Tests were interpreted using the Hvorslev method and some by the Bouwer-Rice method. Results indicate that the distribution of K' fits log-Gaussian regression models. Dominant frequencies for K' in the Chalco and Texcoco plains range between 1E-09 and 1E-08 m/s, with similar population means of 1.19E-09 and 1.7E-09 m/s, respectively, which are one to two orders of magnitude higher than the matrix conductivity. In the Mexico City Plain the population mean is near by one order of magnitude lower; K'=2.6E-10 m/s. The contrast between the measured K' and that of the matrix is attributed to the presence of fractures in the upper 25-40 m, which is consistent with the findings of previous studies on solute migration in the aquitard. Un imperméable régional d'origine lacustre recouvre le principal aquifère de la zone urbaine de la ville de Mexico. La conductivité hydraulique K' de cet imperméable est fondamentale pour évaluer la protection naturelle de l'aquifère, contre les différents contaminants présents en surface, et sa réponse hydraulique. Cette étude analyse et les variations de K' dans les plaines de Chalco, Texcoco et Mexico (trois des six anciens lacs qui existaient dans le Bassin de Mexico), sur la base de 225 essais de perméabilité sur le terrain, réalisés en grappes dans des piézomètres existants entre 2 et 85 m de profondeur. Les essais ont été interprétés avec la m

  17. Determination of hydraulic conductivity of fractured rock masses:A case study for a rock cavern project in Singapore

    Institute of Scientific and Technical Information of China (English)

    Zhipeng Xu; Zhiye Zhao; Jianping Sun; Ming Lu

    2015-01-01

    In order to reduce the risk associated with water seepage in an underground rock cavern project in Singapore, a reliable hydro-geological model should be established based on the in situ investigation data. The key challenging issue in the hydro-geological model building is how to integrate limited geological and hydro-geological data to determine the hydraulic conductivity of the fractured rock masses. Based on the data obtained from different stages (feasibility investigation stage, construction stage, and post-construction stage), suitable models and methods are proposed to determine the hy-draulic conductivities at different locations and depths, which will be used at other locations in the future.

  18. High-cycle Fatigue Fracture Behavior of Ultrahigh Strength Steels

    Institute of Scientific and Technical Information of China (English)

    Weijun HUI; Yihong NIE; Han DONG; Yuqing WENG; Chunxu WANG

    2008-01-01

    The fatigue fracture behavior of four ultrahigh strength steels with different melting processes and therefore different inclusion sizes were studied by using a rotating bar two-point bending fatigue machine in the high-cycle regime up to 107 cycles of loading. The fracture surfaces were observed by field emission scanning electron microscopy (FESEM). It was found that the size of inclusion has significant effect on the fatigue behavior.For AISI 4340 steel in which the inclusion size is smaller than 5.5 μm, all the fatigue cracks except one did not initiated from inclusion but from specimen surface and conventional S-N curve exists. For 65Si2MnWE and Aermet 100 steels in which the average inclusion sizes are 12.2 and 14.9 μm, respectively, fatigue cracks initiated from inclusions at lower stress amplitudes and stepwise S-N curves were observed. The S-N curvedisplays a continuous decline and fatigue failures originated from large oxide inclusion for 60Si2CrVA steel in which the average inclusion size is 44.4 μm. In the case of internal inclusion-induced fractures at cycles beyond about 1×106 for 65Si2MnWE and 60Si2CrVA steels, inclusion was always found inside the fish-eye and a granular bright facet (GBF) was observed in the vicinity around the inclusion. The GBF sizes increasewith increasing the number of cycles to failure Nf in the long-life regime. The values of stress intensity factor range at crack initiation site for the GBF are almost constant with Nf, and are almost equal to that for the surface inclusion and the internal inclusion at cycles lower than about 1×106. Neither fish-eye nor GBF was observed for Aermet 100 steel in the present study.

  19. Delivering high quality hip fracture rehabilitation: the perspective of occupational and physical therapy practitioners.

    Science.gov (United States)

    Leland, Natalie E; Lepore, Michael; Wong, Carin; Chang, Sun Hwa; Freeman, Lynn; Crum, Karen; Gillies, Heather; Nash, Paul

    2017-01-23

    The majority of post-acute hip fracture rehabilitation in the US is delivered in skilled nursing facilities (SNFs). Currently, there are limited guidelines that equip occupational and physical therapy practitioners with a summary of what constitutes evidence-based high quality rehabilitation. Thus, this study aimed to identify rehabilitation practitioners' perspectives on the practices that constitute high quality hip fracture rehabilitation. Focus groups were conducted with 99 occupational and physical therapy practitioners working in SNFs in southern California. Purposive sampling of facilities was conducted to capture variation in key characteristics known to impact care delivery for this patient population (e.g., financial resources, staffing, and patient case-mix). Questions aimed to elicit practitioners' perspectives on high quality hip fracture rehabilitation practices. Each session was audio-recorded and transcribed. Data were systematically analyzed using a modified grounded theory approach. Seven themes emerged: objectives of care; first 72 h; positioning, pain, and precautions; use of standardized assessments; episode of care practices; facilitating insight into progress; and interdisciplinary collaboration. Clinical guidelines are critical tools to facilitate clinical decision-making and achieve desired patient outcomes. The findings of this study highlight the practitioners' perspective on what constitutes high quality hip fracture rehabilitation. This work provides critical information to advance the development of stakeholder-driven rehabilitation clinical guidelines. Future research is needed to verify the findings from other stakeholders (e.g., patients), ensure the alignment of our findings with current evidence, and develop measures for evaluating their delivery and relationship to desired outcomes. Implications for Rehabilitation This study highlights occupational and physiotherapy therapy practitioners' perspectives on the cumulative best

  20. Highly Elastic and Conductive Human-Based Protein Hybrid Hydrogels.

    Science.gov (United States)

    Annabi, Nasim; Shin, Su Ryon; Tamayol, Ali; Miscuglio, Mario; Bakooshli, Mohsen Afshar; Assmann, Alexander; Mostafalu, Pooria; Sun, Jeong-Yun; Mithieux, Suzanne; Cheung, Louis; Tang, Xiaowu Shirley; Weiss, Anthony S; Khademhosseini, Ali

    2016-01-01

    A highly elastic hybrid hydrogel of methacryloyl-substituted recombinant human tropoelastin (MeTro) and graphene oxide (GO) nanoparticles are developed. The synergistic effect of these two materials significantly enhances both ultimate strain (250%), reversible rotation (9700°), and the fracture energy (38.8 ± 0.8 J m(-2) ) in the hybrid network. Furthermore, improved electrical signal propagation and subsequent contraction of the muscles connected by hybrid hydrogels are observed in ex vivo tests.

  1. Predicting Fracture Toughness of TRIP 800 using Phase Properties Characterized by In-Situ High Energy X-Ray Diffraction

    Energy Technology Data Exchange (ETDEWEB)

    Soulami, Ayoub; Choi, Kyoo Sil; Liu, Wenning N.; Sun, Xin; Khaleel, Mohammad A.; Ren, Yang; Wang, Yan-Dong

    2010-05-01

    TRansformation Induced Plasticity (TRIP) steel is a typical representative of 1st generation advanced high strength steel (AHSS) which exhibits a combination of high strength and excellent ductility due to its multiphase microstructure. In this paper, we study the crack propagation behavior and fracture resistance of a TRIP 800 steel using a microstructure-based finite element method with the various phase properties characterized by in-situ high energy Xray diffraction (HEXRD) technique. Uniaxial tensile tests on the notched TRIP 800 sheet specimens were also conducted, and the experimentally measured tensile properties and R-curves (Resistance curves) were used to calibrate the modeling parameters and to validate the overall modeling results. The comparison between the simulated and experimentally measured results suggests that the micromechanics based modeling procedure can well capture the overall complex crack propagation behaviors and the fracture resistance of TRIP steels. The methodology adopted here may be used to estimate the fracture resistance of various multiphase materials.

  2. The research on delayed fracture behavior of high-strength bolts in steel structure

    Science.gov (United States)

    Li, Guo dong; Li, Nan

    2017-07-01

    High-strength bolts have been widely used in power plants. However, the high-strength bolts which being employed in pumping station, steel structure and pipeline anti-whip structure have been found delayed fracture for many times in a power plant, this will affect the reliability of steel fracture and bring blow risk caused by falling objects. The high-strength bolt with delayed fracture was carried out fracture analysis, metallurgical analysis, chemical analysis, mechanical analysis, as well as bolts installation analysis, it can be comprehensively confirmed that the direct cause of high-strength bolts delayed fracture is the stress corrosion, and the root cause of high-strength bolts delayed fracture should be the improper installation at the initial and the imperfect routine anti-corrosion maintenance.

  3. Microstructure, tensile properties and fracture behavior of high temperature Al–Si–Mg–Cu cast alloys

    Energy Technology Data Exchange (ETDEWEB)

    Mohamed, A.M.A., E-mail: madel@uqac.ca [Center for Advanced Materials, Qatar University, Doha (Qatar); Department of Metallurgical and Materials Engineering, Faculty of Petroleum and Mining Engineering, Suez Canal University, Box 43721, Suez (Egypt); Samuel, F.H. [Université du Québec à Chicoutimi, Chicoutimi, QC, Canada G7H 2B1 (Canada); Al Kahtani, Saleh [Industrial Engineering Program, Mechanical Engineering Department, College of Engineering, Salman bin Abdulaziz University, Al Kharj (Saudi Arabia)

    2013-08-10

    The high temperature tensile behavior of 354 aluminum cast alloy was investigated in the presence of Zr and Ni. The cast alloys were given a solutionizing treatment followed by artificial aging at 190 °C for 2 h. High temperature tensile tests were conducted at various temperatures from 25 °C to 300 °C. Optical microscopy and electron probe micro-analyzer were used to study the microstructure of different intermetallic phases formed. The fractographic observations of fracture surface were analyzed by scanning electron microscopy to understand the fracture mechanism. The results revealed that the intermetallics phases of (Al, Si){sub 3}(Zr, Ti), Al{sub 3}CuNi and Al{sub 9}NiFe are the main feature in the microstructures of alloys with Zr and Ni additions. The results also indicated that the tensile strength of alloy decreases with an increase in temperature. The combined addition of 0.2 wt% Zr and 0.2 wt% Ni leads to a 30% increase in the tensile properties at 300 °C compared to the base alloy. Zr and Ni bearing phases played a vital role in the fracture mechanism of the alloys studied.

  4. Supplemental Perioperative Oxygen to Reduce Surgical Site Infection After High Energy Fracture Surgery

    Science.gov (United States)

    2016-10-01

    AWARD NUMBER: W81XWH-12-1-0588 TITLE: Supplemental Perioperative Oxygen to Reduce Surgical Site Infection After High Energy Fracture Surgery ...Infection After High Energy Fracture Surgery 5a. CONTRACT NUMBER W81XWH-12-1-0588 5b. GRANT NUMBER OR110123 5c. PROGRAM ELEMENT NUMBER 6. AUTHOR...prospective randomized treatment trial investigating if supplemental perioperative oxygen use will reduce surgical site infection after surgery on fractures

  5. Defining current facial fracture patterns in a quaternary institution following high-velocity blunt trauma

    Directory of Open Access Journals (Sweden)

    Senzwesihle C. Magagula

    2016-03-01

    Full Text Available Background: In the early 20th century, René Le Fort studied facial fractures resulting from blunt trauma and devised a classification system still in common use today. This classification, however, was based on low-velocity trauma. In modern practice, in a quaternary-level referral hospital, patients are often admitted following high-velocity injuries that mostly result from motor vehicle collisions.Objectives: A retrospective study to define facial bone fractures occurring subsequent to highvelocity trauma.Method: A retrospective study comprising the review of CT scans of 52 patients with highvelocity facial fractures was performed between April 2007 and March 2013. Injuries were classified using the Le Fort classification system. Deviations from the true Le Fort types, which are often depicted in the literature as occurring bilaterally and symmetrically, were documented; these included unilaterality, occurrence of several Le Fort fractures on one side of the face, occurrence of several Le Fort fractures on different levels and on different sides of the face, and occurrence of other fractures in addition to Le Fort fractures.Results: Of the 52 cases, 12 (23% had Le Fort injuries, with true Le Fort fractures occurring in only 1, and 11 deviating from the classic description. Nine patients had Le Fort fractures and additional fractures. Mandibular and zygomatic bone fractures were found to be common associations with Le Fort injuries, occurring in 58% and 33% of the cases respectively.Conclusion: Fractures occurring in modern practice often deviate from the traditional Le Fort classification. Precise recognition of these deviations and recognition of additional associated fractures is pivotal in their management, assisting the surgeon in determining the treatment plan, such as the surgical approach and the order in which to fix the various fractured components.

  6. Fracture Energy of High-Strength Concrete in Compression

    DEFF Research Database (Denmark)

    Dahl, H.; Brincker, Rune

    1989-01-01

    is essential for understanding the fracture mechanism of concrete in compression. In this paper a series of tests is reported, carried out for the purpose of studying the fracture mechanical properties of concrete in compression. Including the measurement and study of the descending branch, a new experimental...

  7. 页岩气网络压裂支撑剂导流特性评价%Evaluation on Conductivity Performance of Proppant in Shale Gas Network Fracturing

    Institute of Scientific and Technical Information of China (English)

    贾长贵

    2014-01-01

    In shale gas development from horizontal well ,network fracturing often has low sand con-centration and serious embedment damage ,w hich leads to different conductivity performance from conven-tional reservoirs and also it is different from short-medium hydraulic fracturing in North America .In order to obtain the conductivity performance of proppant in shale gas network fracturing ,experiments were done and those rock samples were from Longmaxi shale outcrop .By use of FCES 100 Fracture Conductivity E-valuation System ,three kinds of porppant(ceramic ,sand and resin coated sand)were tested under different conditions in terms of proppant size ,concentration and closure pressure .The results showed that sand con-centration ,closure pressure and proppant type had obvious effect on conductivity of propped fractures in shale .Under medium or high closure pressure and low sand concentration ,resin coated sand featured the highest conductivity ,followed by ceramic and sand .These evaluation results provided basis for optimizing conductivity in shale gas ESRV network fracturing ,porppant selection and stimulation design .%页岩气水平井长缝网络压裂支撑剂铺置浓度低,嵌入伤害大,导流特性与常规油气藏不同,与北美页岩气水平井中短缝压裂也有明显差异。为评价不同类型支撑剂在低铺砂浓度下的导流特性,采集龙马溪组地层页岩露头制作试验岩样,使用FCES 100裂缝导流仪对陶粒、石英砂、覆膜砂3种类型支撑剂在不同粒径、不同铺砂浓度和不同闭合压力条件下的导流特性进行了评价。结果表明:支撑剂类型、闭合压力和铺砂浓度对页岩支撑裂缝的导流能力影响较大;中高闭合压力和低铺砂浓度条件下,覆膜砂的导流能力最大,陶粒次之,石英砂最小。评价结果可为页岩气ESRV(effective stimulation reservoir volume)网络压裂裂缝导流能力的优化、支撑剂的优选和压裂设计提供依据。

  8. Method for detecting moment connection fracture using high-frequency transients in recorded accelerations

    Science.gov (United States)

    Rodgers, J.E.; Elebi, M.

    2011-01-01

    The 1994 Northridge earthquake caused brittle fractures in steel moment frame building connections, despite causing little visible building damage in most cases. Future strong earthquakes are likely to cause similar damage to the many un-retrofitted pre-Northridge buildings in the western US and elsewhere. Without obvious permanent building deformation, costly intrusive inspections are currently the only way to determine if major fracture damage that compromises building safety has occurred. Building instrumentation has the potential to provide engineers and owners with timely information on fracture occurrence. Structural dynamics theory predicts and scale model experiments have demonstrated that sudden, large changes in structure properties caused by moment connection fractures will cause transient dynamic response. A method is proposed for detecting the building-wide level of connection fracture damage, based on observing high-frequency, fracture-induced transient dynamic responses in strong motion accelerograms. High-frequency transients are short (Elsevier B.V. All rights reserved.

  9. High Resolution Geophysical Characterization of Fractures within a Granitic Pluton

    Science.gov (United States)

    Pérez-Estaún, A.; Carbonell, R.

    2007-12-01

    The FEBEX underground gallery was excavated in the Aar Granite (Switzerland), a heterogeneous granite containing from very leucocratic facies to granodiorites. The geology of the gallery shows the existence of various sets of fractures with different attributes: geometry, kinematics, fracture infilling, etc. The study of the structural data, new observations on the FEBEX gallery itself and borehole televiewer data acquired in the newly drilled boreholes, have allowed to identify four sets of fractures. The first group of fractures has a typical distribution and characteristics of en echelon tension fractures and were formed in late magmatic stages, according with the paragenesis of the minerals that filled the craks. The main strike is around 300 (280-300). These fractures are deformed and displaced by the other group of faults. The second group corresponds to the lamprophyre dikes, of mantelic origin, with an orientation oblique to the tunnel, and slightly oblique to the first group of fractures (strike, 310-330). They were formed during an extension event well evidenced by their irregular margins and flame structures into the granite. The margins of these dikes show several reactivations as strike slip faults. Geophysical data has been acquired to characterized the fracture network of the surrounding volume within the FEBEX gallery. The geophysic data include new borehole logging such as Natural Gamma and Borehole Ground Penetrating radar. The processing and integration of these different data sets indicates that the GPR record can provide images of a third set of fractures, which are probably fluid filled. This set of fractures a subparallel to the tunnel axis and appear to intersect older boreholes which are nearly perpendicular to the axis of the FEBEX gallery.

  10. Management of osteoporosis in patients hospitalized for hip fractures

    OpenAIRE

    Ip, T. P.; Leung, J.; Kung, A. W. C.

    2010-01-01

    Hip fracture is associated with high morbidity, mortality, and economic burden worldwide. It is also a major risk factor for a subsequent fracture. A literature search on the management of osteoporosis in patients with hip fracture was performed on the Medline database. Only one clinical drug trial was conducted in patients with a recent hip fracture. Further studies that specifically address post-fracture management of hip fracture are needed. The efficacy of anti-osteoporosis medication in ...

  11. High-Thermal Conductive Coating Used on Metal Heat Exchanger

    Institute of Scientific and Technical Information of China (English)

    李静; 梁剧; 刘业明

    2014-01-01

    Based on modified silicon polyester resin in addition to several functional fillers such as corro-sion-resistant fillers, heat-resistant fillers and thermal conductive fillers, a high thermal conductive coating can be made. On the basis of boronnitride (BN) and aluminum nitride (AIN) used as thermal conductive fillers and by means of the testing system of hot disk and heat transfer experiment, researches on the varieties of thermal conduc-tive fillers and the effects of the contents of high-thermal conductive coating have been done, which shows that the thermal conductivity of coating increases with the increase of the quality fraction and the coefficient of thermal conductivity of the thermal conductive fillers of coating. With guaranteeing better heat resistance, stronger corro-sion resistance and adhesive force, the coefficient of coating can reach a level as high as 3 W·m-1·K-1.

  12. Formability Prediction of Advanced High Strength Steel with a New Ductile Fracture Criterion

    Science.gov (United States)

    Lou, Yanshan; Lim, Sungjun; Huh, Jeehyang; Huh, Hoon

    2011-08-01

    A ductile fracture criterion is newly proposed to accurately predict forming limit diagrams (FLD) of sheet metals. The new ductile fracture criterion is based on the effect of the non-dimensional stress triaxiality, the stress concentration factor and the effective plastic strain on the nucleation, growth and coalescence of voids. The new ductile fracture criterion has been applied to estimate the formability of four kind advanced high strength steels (AHSS): DP780, DP980, TRIP590, and TWIP980. FLDs predicted are compared with experimental results and those predicted by other ductile fracture criteria. The comparison demonstrates that FLDs predicted by the new ductile fracture criterion are in better agreement with experimental FLDs than those predicted by other ductile fracture criteria. The better agreement of FLDs predicted by the new ductile fracture criterion is because conventional ductile fracture criteria were proposed for fracture prediction in bulk metal forming while the new one is proposed to predict the onset of fracture in sheet metal forming processes.

  13. High bone turnover is associated with low bone mass and spinal fracture in postmenopausal women

    DEFF Research Database (Denmark)

    Ravn, Pernille; Rix, M; Andreassen, H;

    1997-01-01

    -eight women had a lumbar spine bone mineral density (BMD) above 0.860 g/cm2, and 278 women had a BMD below 0.860 g/cm2. Spinal fracture was diagnosed from lateral spine X-ray studies and defined as at least 20% height reduction (wedge, compression, or endplate fracture) in at least one vertebra (T4-L4). Bone......, and prevalence of spinal fracture, which supports the theory that high bone turnover is a risk factor for spinal fracture and osteoporosis....

  14. Fracture in high performance fibre reinforced concrete pavement materials

    CSIR Research Space (South Africa)

    Denneman, E

    2011-05-01

    Full Text Available reliable predictions of the flexural capacity of full size pavement structures, 2.In contrast to the MOR parameter, the fracture mechanics damage models developed as part of this study do provide reliable predictions of the flexural behaviour...

  15. An investigation of the plastic fracture of high strength steels. Ph.D. Thesis

    Science.gov (United States)

    Cox, T. B.; Low, J. R., Jr.

    1973-01-01

    Three generally recognized stages of plastic fracture in high strength steels are considered in detail. These stages consist of void initiation, void growth, and void coalescence. A brief review of the existing literature on plastic fracture is included along with an outline of the experimental approach used in the investigation.

  16. STRESS FRACTURE OF THE FIRST RIB IN A HIGH SCHOOL WEIGHT LIFTER

    Directory of Open Access Journals (Sweden)

    Hiroyuki Fujioka

    2009-06-01

    Full Text Available A 17-year-old boy, who played a weight lifting in high school, sustained stress fracture of the first rib without any causes. We successfully treated first rib stress fracture with limitation of using the upper extremity and with using low-intensity pulsed ultrasound

  17. Fast rate fracture of aluminum using high intensity lasers

    Science.gov (United States)

    Dalton, Douglas Allen

    Laser induced shock experiments were performed to study the dynamics of various solid state material processes, including shock-induced melt, fast rate fracture, and elastic to plastic response. Fast rate fracture and dynamic yielding are greatly influenced by microstructural features such as grain boundaries, impurity particles and alloying atoms. Fast fracture experiments using lasers are aimed at studying how material microstructure affects the tensile fracture characteristics at strain rates above 106 s-1. We used the Z-Beamlet Laser at Sandia National Laboratories to drive shocks via ablation and we measured the maximum tensile stress of aluminum targets with various microstructures. Using a velocity interferometer and sample recovery, we are able to measure the maximum tensile stress and determine the source of fracture initiation in these targets. We have explored the role that grain size, impurity particles and alloying in aluminum play in dynamic yielding and spall fracture at tensile strain rates of ˜3x106 s-1. Preliminary results and analysis indicated that material grain size plays a vital role in the fracture morphology and spall strength results. In a study with single crystal aluminum specimens, velocity measurements and fracture analysis revealed that a smaller amplitude tensile stress was initiated by impurity particles; however, these particles served no purpose in dynamic yielding. An aluminum-magnesium alloy with various grain sizes presented the lowest spall strength, but the greatest dynamic yield strength. Fracture mode in this alloy was initiated by both grain boundaries and impurity particles. With respect to dynamic yielding, alloying elements such as magnesium serve to decrease the onset of plastic response. The fracture stress and yield stress showed no evidence of grain size dependence. Hydrodynamic simulations with material strength models are used to compare with our experiments. In order to study the strain rate dependence of spall

  18. Dynamic tensile fracture of mortar at ultra-high strain-rates

    Energy Technology Data Exchange (ETDEWEB)

    Erzar, B., E-mail: benjamin.erzar@cea.fr; Buzaud, E.; Chanal, P.-Y. [CEA, DAM, GRAMAT, F-46500 Gramat (France)

    2013-12-28

    During the lifetime of a structure, concrete and mortar may be exposed to highly dynamic loadings, such as impact or explosion. The dynamic fracture at high loading rates needs to be well understood to allow an accurate modeling of this kind of event. In this work, a pulsed-power generator has been employed to conduct spalling tests on mortar samples at strain-rates ranging from 2 × 10{sup 4} to 4 × 10{sup 4} s{sup −1}. The ramp loading allowed identifying the strain-rate anytime during the test. A power law has been proposed to fit properly the rate-sensitivity of tensile strength of this cementitious material over a wide range of strain-rate. Moreover, a specimen has been recovered damaged but unbroken. Micro-computed tomography has been employed to study the characteristics of the damage pattern provoked by the dynamic tensile loading.

  19. A NEW HIGH RESOLUTION OPTICAL METHOD FOR OBTAINING THE TOPOGRAPHY OF FRACTURE SURFACES IN ROCKS

    Directory of Open Access Journals (Sweden)

    Steven Ogilvie

    2011-05-01

    Full Text Available Surface roughness plays a major role in the movement of fluids through fracture systems. Fracture surface profiling is necessary to tune the properties of numerical fractures required in fluid flow modelling to those of real rock fractures. This is achieved using a variety of (i mechanical and (ii optical techniques. Stylus profilometry is a popularly used mechanical method and can measure surface heights with high precision, but only gives a good horizontal resolution in one direction on the fracture plane. This method is also expensive and simultaneous coverage of the surface is not possible. Here, we describe the development of an optical method which images cast copies of rough rock fractures using in-house developed hardware and image analysis software (OptiProf™ that incorporates image improvement and noise suppression features. This technique images at high resolutions, 15-200 μm for imaged areas of 10 × 7.5 mm and 100 × 133 mm, respectively and a similar vertical resolution (15 μm for a maximum topography of 4 mm. It uses in-house developed hardware and image analysis (OptiProf™ software and is cheap and non-destructive, providing continuous coverage of the fracture surface. The fracture models are covered with dye and fluid thicknesses above the rough surfaces converted into topographies using the Lambert-Beer Law. The dye is calibrated using 2 devices with accurately known thickness; (i a polycarbonate tile with wells of different depths and (ii a wedge-shaped vial made from silica glass. The data from each of the two surfaces can be combined to provide an aperture map of the fracture for the scenario where the surfaces touch at a single point or any greater mean aperture. The topography and aperture maps are used to provide data for the generation of synthetic fractures, tuned to the original fracture and used in numerical flow modelling.

  20. Analysis of the pressure response of high angle multiple (HAM) fractures intersecting a welbore; Kokeisha multi fracture (HAM) kosei ni okeru atsuryoku oto kaiseki ni tsuite

    Energy Technology Data Exchange (ETDEWEB)

    Ujo, S.; Osato, K. [Geothermal Energy Research and Development Co. Ltd., Tokyo (Japan); Arihara, N. [Waseda University, Tokyo (Japan); Schroeder, R.

    1996-05-01

    This paper reports pressure response analysis on wells piercing a high angle multi (HAM) fracture model. In this model which is defined on a three-dimensional space, a plurality of slanted fractures intersect with wells at high angles (however, intersection of fractures with each other is not considered). With respect to the pressure response analysis method using this model, the paper presents a basic differential equation on pressure drawdown and boundary conditions in the wells taking flows in the fractures pseudo-linear, as well as external boundary conditions in calculation regions (a reservoir spreads to an infinite distance, and its top and bottom are closed by non-water permeating beds). The paper also indicates that results of calculating a single vertical fracture model and a slanted fracture model by using a numerical computation program (MULFRAC) based on the above equations agree well respectively with the existing calculation results (calculations performed by Erlougher and Cinco et al). 5 refs., 6 figs.

  1. Improving electrical conductivity in polycarbonate nanocomposites using highly conductive PEDOT/PSS coated MWCNTs

    KAUST Repository

    Zhou, Jian

    2013-07-10

    We describe a strategy to design highly electrically conductive polycarbonate nanocomposites by using multiwalled carbon nanotubes (MWCNTs) coated with a thin layer of poly(3,4-ethylenedioxythiophene)/ poly(styrenesulfonate), a conductive polymer. We found that this coating method improves the electrical properties of the nanocomposites in two ways. First, the coating becomes the main electrical conductive path. Second, the coating promotes the formation of a percolation network at a low filler concentration (0.3 wt %). To tailor the electrical properties of the conductive polymer coating, we used a polar solvent ethylene glycol, and we can tune the final properties of the nanocomposite by controlling the concentrations of the elementary constituents or the intrinsic properties of the conductive polymer coating. This very flexible technique allows for tailoring the properties of the final product. © 2013 American Chemical Society.

  2. High incidence of chronic pain following surgery for pelvic fracture

    DEFF Research Database (Denmark)

    Meyhoff, Christian Sylvest; Thomsen, Camilla Højland; Rasmussen, Lars Simon

    2006-01-01

    OBJECTIVES: To determine the incidence of chronic pain after surgery for pelvic fracture using a strict definition and measures of intensity and health-related quality of life. METHODS: In April 2004, a questionnaire was sent to 221 patients who underwent surgery for pelvic fracture in the period...... 1996 to 2000. Chronic pain was defined as pain at present that related back to the pelvic fracture and was not a consequence of other disease. Health-related quality of life was measured using the 15D questionnaire. RESULTS: The response rate was 72.9% after a median follow-up of 5.6 years. Chronic...... pain was seen in 48.4% (95% confidence interval, 40.7%-56.2%). These patients had a combination of somatic nociceptive, visceral nociceptive, and neuropathic pain and had significantly lower health-related quality of life. Also, the use of opioids (14.1% vs. 4.8%) and nonsteroidal anti...

  3. Epidemiology of Pelvic Fractures in Germany: Considerably High Incidence Rates among Older People.

    Science.gov (United States)

    Andrich, Silke; Haastert, Burkhard; Neuhaus, Elke; Neidert, Kathrin; Arend, Werner; Ohmann, Christian; Grebe, Jürgen; Vogt, Andreas; Jungbluth, Pascal; Rösler, Grit; Windolf, Joachim; Icks, Andrea

    2015-01-01

    Epidemiological data about pelvic fractures are limited. Until today, most studies only analyzed inpatient data. The purpose of this study was to estimate incidence rates of pelvic fractures in the German population aged 60 years or older, based on outpatient and inpatient data. We conducted a retrospective population-based observational study based on routine data from a large health insurance company in Germany. Age and sex-specific incidence rates of first fractures between 2008 and 2011 were calculated. We also standardized incidence rates with respect to age and sex in the German population. Multiple Poisson regression models were used to evaluate the association between the risk of first pelvic fracture as outcome and sex, age, calendar year and region as independent variables. The total number of patients with a first pelvic fracture corresponded to 8,041 and during the study period 5,978 insured persons needed inpatient treatment. Overall, the standardized incidence rate of all first pelvic fractures was 22.4 [95% CI 22.0-22.9] per 10,000 person-years, and the standardized incidence rate of inpatient treated fractures 16.5 [16.1-16.9]. Our adjusted regression analysis confirmed a significant sex (RR 2.38 [2.23-2.55], p year (higher risk in later years compared to 2008, p = 0.0162) and first fracture risk and a further significant association with region (RR 0.92 [0.87-0.98], p = 0.006, Westfalen-Lippe as reference). The observed incidences are considerably higher than incidences described in the international literature, even if only inpatient treated pelvic fractures are regarded. Besides which, non-inclusion of outpatient data means that a relevant proportion of pelvic fractures are not taken into account. Prevention of low energy trauma among older people remains an important issue.

  4. Diagnosis of occult scaphoid fracture with high-spatial-resolution sonography: a prospective blind study.

    Science.gov (United States)

    Fusetti, C; Poletti, P A; Pradel, P H; Garavaglia, G; Platon, A; Della Santa, D R; Bianchi, S

    2005-09-01

    Evaluation of diagnostic accuracy of high-spatial-resolution sonography (HSR-S) in occult scaphoid fractures. HSR-S was performed in 24 patients with clinically suspected fracture and normal radiographs. Three levels of clinical suspicion were considered (high, intermediate, and low). Three levels of sonographic suspicion were defined on the basis of cortical interruption, radiocarpal effusion, and scapho-trapezium-trapezoid effusion. Three positive criteria were interpreted as being highly indicative of fracture. Data from sonograms were compared with computed tomography (CT) scans. CT scanning demonstrated a fracture of the scaphoid in five patients. The global sensitivity of HSR-S for detection of occult scaphoid fracture was 100% and the specificity 79%. All patients with demonstrated occult fracture had a high sonography index of suspicion. A high sonography index of suspicion was correlated with 100% sensitivity, specificity, positive predictive value, and negative predictive value. HSR-S is a reliable, available, and cost-effective method in early diagnosis of occult fractures of the scaphoid. The presence of three defined criteria is required to assess the diagnosis.

  5. RESORBABLE HIGH-STRENGTH ROD FOR FRACTURE INTERNAL FIXATION

    Institute of Scientific and Technical Information of China (English)

    杨团民; 刘淼; 杨爱玲; 石宗利; 邱希江; 李毅; 同志超; 韩月

    2004-01-01

    Objective To find an ideal biomaterial for internal fixation. Methods Forty rabbits with fracture of the femur diaphysis (superiorcondyle) were treated by intramedullary nailing of femur with composites rod of resorbable DL-polylactic acid (PDLLA)-calcium metaphosphate (CMP), while steinmann's pin as control. The fracture healing, the material degradation and its mechanical properties were studied by X-ray films, macroscopic, microscopic and electron microscopic observations. Results No significant inflammatory reaction was found, and all the osteotomies were healed, while material was resorbed. Conclusion The PDLLA-CMP has excellent biocompatibility and mechanical properties, and it can be a promising implant material in orthopaedics surgery.

  6. Humidifier for fuel cell using high conductivity carbon foam

    Science.gov (United States)

    Klett, James W.; Stinton, David P.

    2006-12-12

    A method and apparatus of supplying humid air to a fuel cell is disclosed. The extremely high thermal conductivity of some graphite foams lends itself to enhance significantly the ability to humidify supply air for a fuel cell. By utilizing a high conductivity pitch-derived graphite foam, thermal conductivity being as high as 187 W/m.dot.K, the heat from the heat source is more efficiently transferred to the water for evaporation, thus the system does not cool significantly due to the evaporation of the water and, consequently, the air reaches a higher humidity ratio.

  7. High hip fracture risk in men with severe aortic calcification: MrOS study.

    Science.gov (United States)

    Szulc, Pawel; Blackwell, Terri; Schousboe, John T; Bauer, Douglas C; Cawthon, Peggy; Lane, Nancy E; Cummings, Steven R; Orwoll, Eric S; Black, Dennis M; Ensrud, Kristine E

    2014-04-01

    A significant link between cardiovascular disease and osteoporosis is established in postmenopausal women, but data for men are scarce. We tested the hypothesis that greater severity of abdominal aortic calcification (AAC) was associated with an increased risk of nonspine fracture in 5994 men aged ≥ 65 years. AAC was assessed on 5400 baseline lateral thoracolumbar radiographs using a validated visual semiquantitative score. Total hip bone mineral density (BMD) was measured using dual-energy X-ray absorptiometry. Incident nonspine fractures were centrally adjudicated. After adjustment for age, body mass index (BMI), total hip BMD, fall history, prior fracture, smoking status, comorbidities, race, and clinical center, the risk of nonspine fracture (n=805) was increased among men with higher AAC (hazard ratio [HR] quartile 4 [Q4] [AAC score ≥ 9] versus quartile 1 [Q1] [0-1], 1.36; 96% confidence interval [CI], 1.10-1.68). This association was due to an increased risk of hip fracture (n=178) among men with higher AAC (HR Q4 versus Q1, 2.33; 95% CI, 1.41-3.87). By contrast, the association between AAC and the risk of nonspine, nonhip fracture was weaker and not significant (HR Q4 versus Q1, 1.22; 95% CI, 0.96-1.55). The findings regarding higher AAC and increased risk of fracture were not altered in additional analyses accounting for degree of trauma, estimated glomerular filtration rate, presence of lumbar vertebral fractures (which may bias AAC assessment), preexisting cardiovascular disease, ankle brachial index, or competing risk of death. Thus, in this large cohort of elderly men, greater AAC was independently associated with an increased risk of hip fracture, but not with other nonspine fractures. These findings suggest that AAC assessment may be a useful method for identification of older men at high risk of hip fracture.

  8. High prevalence of radiological vertebral fractures in adult patients with Ehlers-Danlos syndrome.

    Science.gov (United States)

    Mazziotti, G; Dordoni, C; Doga, M; Galderisi, F; Venturini, M; Calzavara-Pinton, P; Maroldi, R; Giustina, A; Colombi, M

    2016-03-01

    Previous studies have reported an increased prevalence of osteoporosis in Ehlers–Danlos syndrome (EDS), but these were limited by a small number of patients and lack of information on fragility fractures. In this crosssectional study, we evaluated the prevalence of radiological vertebral fractures (by quantitative morphometry) and bone mineral density (BMD, at lumbar spine, total hip and femoral neck by dual-energy X-ray absorptiometry) in 52 consecutive patientswith EDS (10 males, 42 females; median age 41 years, range: 21–71; 12with EDS classic type, 37 with EDS hypermobility type, 1 with classic vascular-like EDS, and 2 without specific classification) and 197 control subjects (163 females and 34 males; median age 49 years, range: 26–83) attending an outpatient bone clinic. EDS patients were also evaluated for back pain by numeric pain rating scale (NRS- 11).Vertebral fractures were significantly more prevalent in EDS as compared to the control subjects (38.5% vs. 5.1%; p b 0.001) without significant differences in BMD at either skeletal sites. In EDS patients, the prevalence of vertebral fractures was not significantly (p = 0.72) different between classic and hypermobility types. BMD was not significantly different between fractured and non-fractured EDS patients either at lumbar spine (p = 0.14), total hip (p=0.08), or femoral neck (p=0.21). Severe back pain(≥7 NRS)was more frequent in EDS patients with vertebral fractures as compared to thosewithout fractures (60% vs. 28%; p=0.04). Inconclusion, this is the first study showing high prevalence of vertebral fractures in a relatively large population of EDS patients. Vertebral fractures were associated with more severe back pain suggesting a potential involvement of skeletal fragility in determining poor quality of life. The lack of correlation between vertebral fractures and BMD is consistent with the hypothesis that bone quality may be impaired in EDS.

  9. High hip fracture risk in men with severe aortic calcification - MrOS study

    Science.gov (United States)

    Szulc, Pawel; Blackwell, Terri; Schousboe, John T.; Bauer, Douglas C.; Cawthon, Peggy; Lane, Nancy E.; Cummings, Steven R.; Orwoll, Eric S.; Black, Dennis M.; Ensrud, Kristine E.

    2013-01-01

    A significant link between cardiovascular disease and osteoporosis is established in postmenopausal women, but data in men are scarce. We tested the hypothesis that greater severity of abdominal aortic calcification (AAC) was associated with an increased risk of non-spine fracture in 5994 men aged ≥65 years. AAC wasassessed on 5400 baseline lateral thoraco-lumbar radiographs using a validated visual semi-quantitative score. Total hip bone mineral density (BMD) was measured using dual energy X-ray absorptiometry. Incident non-spine fractures were centrally adjudicated. After adjustment for age, BMI, total hip BMD, fall history, prior fracture, smoking status, co-morbidities, race and clinical center, the risk of non-spine fracture (n=805) was increased among men with higher AAC (HR Q4 (AAC score ≥9) vs Q1 (0-1): 1.36, 96%CI: 1.10-1.68). This association was due to an increased risk of hip fracture (n=178) among men with higher AAC (HR Q4 vs Q1: 2.33, 95%CI: 1.41-3.87). By contrast, the association between AAC and the risk of non-spine-non-hip fracture was weaker and not significant (HR Q4 vs Q1: 1.22, 95%CI: 0.96-1.55). The findings regarding higher AAC and increased risk of fracture were not altered in additional analyses accounting for degree of trauma, estimated glomerular filtration rate, presence of lumbar vertebral fractures (which may bias AAC assessment), preexisting cardiovascular disease, ankle brachial index or competing risk of death. Thus, in this large cohort of elderly men, greater AAC was independently associated with an increased risk of hip fracture, but not with other non-spine fractures. These findings suggest that AAC assessment may be a useful method for identification of older men at high risk of hip fracture. PMID:23983224

  10. Highly conductive single naphthalene and anthracene molecular junction with well-defined conductance

    Energy Technology Data Exchange (ETDEWEB)

    Liu, Chenyang [Department of Chemistry, Graduate School of Science and Engineering, Tokyo Institute of Technology, 2-12-1 W4-10, Ookayama, Meguro-ku, Tokyo 152-8551 (Japan); School of Materials Science and Engineering, Tsinghua University, Beijing 100084 (China); Kaneko, Satoshi; Komoto, Yuki; Fujii, Shintaro, E-mail: fujii.s.af@m.titech.ac.jp; Kiguchi, Manabu, E-mail: kiguti@chem.titech.ac.jp [Department of Chemistry, Graduate School of Science and Engineering, Tokyo Institute of Technology, 2-12-1 W4-10, Ookayama, Meguro-ku, Tokyo 152-8551 (Japan)

    2015-03-09

    We performed electronic investigation on single acene molecular junctions bridging Au-electrodes in ultra-high vacuum conditions using mechanically controllable break junction technique. While the molecular junctions displayed various conductance values at 100 K, they exhibited well-defined high conductance values (∼0.3 G{sub 0}) at 300 K, which is close to that of metal atomic contact. Direct π-binding of the molecules to the Au-electrodes leads to the high conductivities at the metal-molecule interface. At the elevated temperature, single molecular junctions trapped in local metastable structures can be fallen into energetically preferential more stable state and thus we fabricated structurally well-defined molecular junctions.

  11. Determination of the Height of the Water-Conducting Fractured Zone in Difficult Geological Structures: A Case Study in Zhao Gu No. 1 Coal Seam

    Directory of Open Access Journals (Sweden)

    Shuai Zhang

    2017-06-01

    Full Text Available The method for determining the upper limit for safe mining with regard to water and sand collapse prevention under thick alluvium and thin bedrock layers is a critical parameter for ensuring the sustainable development of a mine. The height of the water-conducting fractured zone (HWCFZ is an important index parameter in the prediction and prevention of water and sand collapse. This research was conducted based on the concrete geological condition of the Zhao Gu No. 1 coal mine. First, a field measurement method was used to observe the HWCFZ of a mined panel. The discrete element method was applied to establish a corresponding model, which was calibrated using the measurement data. Then, calculation models for different bedrock thicknesses were developed to analyze the evolution law of the water-conducting fractured zone at different bedrock thicknesses and mining heights. The safe mining upper limits for different bedrock thicknesses were obtained. The relationships between the developing HWCFZ and bedrock thickness/mining height were determined. Using the research results as the main indices, an industrial experiment was performed on the 11,191 panel. The partition limit mining height was implemented in the panel, and safe production was realized. On the basis of the research results, 40,199,336.3 t of coal resources were successfully released, increasing the resource recovery rate by 31.72% and extending the mine service life by 12.5 years. This study not only provided technical support for the sustainable development of the Zhao Gu No. 1 coal seam, but could also be used for safe and highly efficient mining in other coal mines under similar geological conditions.

  12. High conductivity Be-Cu alloys for fusion reactors

    Energy Technology Data Exchange (ETDEWEB)

    Lilley, E.A. [NGK Metals Corp., Reading, PA (United States); Adachi, Takao; Ishibashi, Yoshiki [NGK Insulators, Ltd., Aichi-ken (Japan)

    1995-09-01

    The optimum material has not yet been identified. This will result in heat from plasma to the first wall and divertor. That is, because of cracks and melting by thermal power and shock. Today, it is considered to be some kinds of copper, alloys, however, for using, it must have high conductivity. And it is also needed another property, for example, high strength and so on. We have developed some new beryllium copper alloys with high conductivity, high strength, and high endurance. Therefore, we are introducing these new alloys as suitable materials for the heat sink in fusion reactors.

  13. Effect of Boron on Delayed Fracture Resistance of Medium-Carbon High Strength Spring Steel

    Institute of Scientific and Technical Information of China (English)

    2007-01-01

    The delayed fracture behavior of medium-carbon high strength spring steel containing different amounts of boron (0. 000 5%, 0. 001 6%) was studied using sustained load delayed fracture test. The results show that delayed fracture resistance of boron containing steels is higher than that of conventional steel 60Si2MnA at the same strength level and it increases with the increase of boron content from 0. 000 5 % to 0. 001 6 %. The delayed fracture mode is mainly intergranular in the boron containing steels tempered at 350 ℃, which indicates that the addition of boron does not change the fracture character. However, the increase of boron content enlarges the size of the crack initiation area. Further study of phase analysis indicates that most boron is in solid solution, and only a very small quantity of boron is in the M3 (C, B) phase.

  14. Open Cell Conducting Foams for High Synchrotron Radiation Beam Liners

    CERN Document Server

    Petracca, Stefania

    2014-01-01

    The possible use of open-cell conductive foams in high synchrotron radiation particle accelerator beam liners is considered. Available materials and modeling tools are reviewed, potential pros and cons are discussed, and preliminary conclusions are drawn.

  15. Ability of High-Resolution Resistivity Tomography to Detect Fault and Fracture Zones: Application to the Tournemire Experimental Platform, France

    Science.gov (United States)

    Gélis, C.; Noble, M.; Cabrera, J.; Penz, S.; Chauris, H.; Cushing, E. M.

    2016-02-01

    The Experimental Platform of Tournemire (Aveyron, France) developed by IRSN (French Institute for Radiological Protection and Nuclear Safety) is composed of a tunnel excavated in an argillite formation belonging to a limestone-argillite-limestone subhorizontal sedimentary sequence. Subvertical secondary fault zones were intercepted in argillite using drifts and boreholes in the tunnel excavated at a depth of about 250 m located under the Larzac Plateau. A 2D 2.5 km baseline large-scale electrical resistivity survey conducted in 2007 allowed detecting in the upper limestones several significantly low electrical resistivity subvertical zones (G élis et al. Appl Geophys 167(11): 1405-1418, 2010). One of these discontinuities is consistent with the extension towards the surface of the secondary fault zones identified in the argillite formation from the tunnel. In an attempt to better characterize this zone, IRSN and MINES ParisTech conducted a high-resolution electrical resistivity survey located transversally to the fault and fracture zones. A 760-m-long profile was acquired using two array geometries and take-outs of 2, 4 and 8 m, requiring several roll-alongs. These data were first inverted independently for each take-out and then using all take-outs together for a given array geometry. Different inverted 2D electrical resistivity models display the same global features with high (higher than 5000 Ωm) to low (lower than 100 Ωm) electrical resistivity zones. These electrical resistivity models are finally compared with a geological cross-section based on independent data. The subvertical conductive zones are in agreement with the fault and fracture locations inferred from the geological cross-section. Moreover, the top of a more conductive zone, below a high electrical conductive zone and between two subvertical fault zones, is located in a more sandy and argillaceous layer. This conductive zone is interpreted as the presence of a more scattered fracture zone

  16. Supplemental Perioperative Oxygen to Reduce Surgical Site Infection After High Energy Fracture Surgery

    Science.gov (United States)

    2015-10-01

    1 AWARD NUMBER: W81XWH-12-1-0588 TITLE: Supplemental Perioperative Oxygen to Reduce Surgical Site Infection After High Energy Fracture Surgery...Operations and Reports (0704-0188), 1215 Jefferson Davis Highway, Suite 1204, Arlington, VA 22202-4302. Respondents should be aware that notwithstanding...Site Infection After High Energy Fracture Surgery 5a. CONTRACT NUMBER W81XWH-12-1-0588 5b. GRANT NUMBER OR110123 5c. PROGRAM ELEMENT NUMBER 6

  17. A flexible and highly pressure-sensitive graphene-polyurethane sponge based on fractured microstructure design.

    Science.gov (United States)

    Yao, Hong-Bin; Ge, Jin; Wang, Chang-Feng; Wang, Xu; Hu, Wei; Zheng, Zhi-Jun; Ni, Yong; Yu, Shu-Hong

    2013-12-10

    A fractured microstructure design: A new type of piezoresistive sensor with ultra-high-pressure sensitivity (0.26 kPa(-1) ) in low pressure range (<2 kPa) and minimum detectable pressure of 9 Pa has been fabricated using a fractured microstructure design in a graphene-nanosheet-wrapped polyurethane (PU) sponge. This low-cost and easily scalable graphene-wrapped PU sponge pressure sensor has potential application in high-spatial-resolution, artificial skin without complex nanostructure design.

  18. Process development for 9Cr nanostructured ferritic alloy (NFA) with high fracture toughness

    Science.gov (United States)

    Byun, Thak Sang; Yoon, Ji Hyun; Hoelzer, David T.; Lee, Yong Bok; Kang, Suk Hoon; Maloy, Stuart A.

    2014-06-01

    This article is to summarize the process development and key characterization results for the newly-developed Fe-9Cr based nanostructured ferritic alloys (NFAs) with high fracture toughness. One of the major drawbacks from pursuing ultra-high strength in the past development of NFAs is poor fracture toughness at high temperatures although a high fracture toughness is essential to prevent cracking during manufacturing and to mitigate or delay irradiation-induced embrittlement in irradiation environments. A study on fracture mechanism using the NFA 14YWT found that the low-energy grain boundary decohesion in fracture process at a high temperature (>200 °C) resulted in low fracture toughness. Lately, efforts have been devoted to explore an integrated process to enhance grain bonding. Two base materials were produced through mechanical milling and hot extrusion and designated as 9YWTV-PM1 and 9YWTV-PM2. Isothermal annealing (IA) and controlled rolling (CR) treatments in two phase region were used to enhance diffusion across the interfaces and boundaries. The PM2 alloy after CR treatments showed high fracture toughness (KJQ) at represented temperatures: 240-280 MPa √m at room temperature and 160-220 MPa √m at 500 °C, which indicates that the goal of 100 MPa √m over possible nuclear application temperature range has been well achieved. Furthermore, it is also confirmed by comparison that the CR treatments on 9YWTV-PM2 result in high fracture toughness similar to or higher than those of the conventional ferritic-martensitic steels such as HT9 and NF616.

  19. High-sensitivity CRP is an independent risk factor for all fractures and vertebral fractures in elderly men: the MrOS Sweden study.

    Science.gov (United States)

    Eriksson, Anna L; Movérare-Skrtic, Sofia; Ljunggren, Östen; Karlsson, Magnus; Mellström, Dan; Ohlsson, Claes

    2014-02-01

    Epidemiological studies have shown low-grade inflammation measured by high-sensitivity C-reactive protein (hs-CRP) to be associated with fracture risk in women. However, it is still unclear whether hs-CRP is also associated with fracture risk in men. We therefore measured serum levels of hs-CRP in 2910 men, mean age 75 years, included in the prospective population-based MrOS Sweden cohort. Study participants were divided into tertile groups based on hs-CRP level. Fractures occurring after the baseline visit were validated (average follow-up 5.4 years). The incidence for having at least one fracture after baseline was 23.9 per 1000 person-years. In Cox proportional hazard regression analyses adjusted for age, hs-CRP was related to fracture risk. The hazard ratio (HR) of fracture for the highest tertile of hs-CRP, compared with the lowest and the medium tertiles combined, was 1.48 (95% CI, 1.20-1.82). Multivariate adjustment for other risk factors for fractures had no major effect on the associations between hs-CRP and fracture. Results were essentially unchanged after exclusion of subjects with hs-CRP levels greater than 7.5 mg/L, as well as after exclusion of subjects with a first fracture within 3 years of follow-up, supporting that the associations between hs-CRP and fracture risk were not merely a reflection of a poor health status at the time of serum sampling. Femoral neck bone mineral density (BMD) was not associated with hs-CRP, and the predictive role of hs-CRP for fracture risk was essentially unchanged when femoral neck BMD was added to the model (HR, 1.37; 95% CI, 1.09-1.72). Exploratory subanalyses of fracture type demonstrated that hs-CRP was clearly associated with clinical vertebral fractures (HR, 1.61; 95% CI, 1.12-2.29). We demonstrate, using a large prospective population-based study, that elderly men with high hs-CRP have increased risk of fractures, and that these fractures are mainly vertebral. The association between hs-CRP and fractures was

  20. 3-D Experimental Fracture Analysis at High Temperature

    Energy Technology Data Exchange (ETDEWEB)

    John H. Jackson; Albert S. Kobayashi

    2001-09-14

    T*e, which is an elastic-plastic fracture parameter based on incremental theory of plasticity, was determined numerically and experimentally. The T*e integral of a tunneling crack in 2024-T3 aluminum, three point bend specimen was obtained through a hybrid analysis of moire interferometry and 3-D elastic-plastic finite element analysis. The results were verified by the good agreement between the experimentally and numerically determined T*e on the specimen surface.

  1. Fracture analysis of a transversely isotropic high temperature superconductor strip based on real fundamental solutions

    Science.gov (United States)

    Gao, Zhiwen; Zhou, Youhe

    2015-04-01

    Real fundamental solution for fracture problem of transversely isotropic high temperature superconductor (HTS) strip is obtained. The superconductor E-J constitutive law is characterized by the Bean model where the critical current density is independent of the flux density. Fracture analysis is performed by the methods of singular integral equations which are solved numerically by Gauss-Lobatto-Chybeshev (GSL) collocation method. To guarantee a satisfactory accuracy, the convergence behavior of the kernel function is investigated. Numerical results of fracture parameters are obtained and the effects of the geometric characteristics, applied magnetic field and critical current density on the stress intensity factors (SIF) are discussed.

  2. Ulnar nerve injury after a comminuted fracture of the humeral shaft from a high-velocity accident: a case report

    Directory of Open Access Journals (Sweden)

    Pathak Ritesh

    2012-07-01

    Full Text Available Abstract Introduction Injury to the ulnar nerve following humerus shaft fracture is a very rare entity because the ulnar nerve is well protected from the bone by muscle and soft tissue, and thus remains unaffected in these fractures. We report what is, to the best of our knowledge, the first case of ulnar nerve injury due to a comminuted humeral shaft fracture. The injury manifested and was diagnosed the day after a high-velocity accident. The paucity of related literature and the necessity for early diagnosis and subsequent treatment of such injuries in high-velocity accidents urged us to document this case. Case presentation A 30-year-old Indian man presented to our Emergency Department after a road traffic accident. Our patient complained of right arm pain and the inability to move his extremity. The following morning he developed clawing. Nerve conduction studies on the peripheral nerves of his arm in addition to an X-ray confirmed the diagnosis of a possible injury to the ulnar nerve. Our patient was taken to our Operating Room for surgery, during which a fragment of bone was found abutting the ulnar nerve after penetrating his triceps. This fragment of bone was replaced and the fracture was reduced by open reduction and internal fixation using a dynamic compression plate and screws. Postoperatively, our patient received physical therapy and was discharged two weeks after surgery with no neurological deficit. Conclusions This case emphasizes the urgency and importance of careful neurological examination of all the peripheral nerves supplying the arm in patients with a fracture of the shaft of the humerus. In the setting of injury to the arm in high-velocity accidents, a differential diagnosis of ulnar nerve injury should always be considered.

  3. HIGH PROTON CONDUCTIVITY OF MESOPOROUS Al2O3

    Science.gov (United States)

    Shen, Hangyan; Maekawa, Hideki; Fujimaki, Yutaka; Kawada, Koutaro; Yamamura, Tsutomu

    Mesoporous Al2O3 was synthesized by the sol-gel method and the pore size was controlled over the range of 3-15nm. Proton conductivity of these samples was examined, which was as high as 0.004 S·cm-1 at 25°C. A systematic dependence of conductivity upon pore size was observed, in which the conductivity increased with increasing the pore size. Meanwhile the conductivity increased with increasing the humidity. Two peaks were observed in 1H NMR spectra, assigned to a "mobile" and an "immobile" proton, respectively. It can be seen that the conductivity of mesoporous-Al2O3 increased with increasing the "mobile" proton concentration. From TG-DTA measurement, proton species were categorized into three groups. It is suggested the group II protons have close relation with the NMR observed "mobile" protons.

  4. A high conductivity oxide–sulfide composite lithium superionic conductor

    Energy Technology Data Exchange (ETDEWEB)

    Rangasamy, Ezhiylmurugan [Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States). Center for Nanophase Materials Science; Sahu, Gayatri [Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States). Center for Nanophase Materials Science; Keum, Jong Kahk [Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States). Center for Nanophase Materials Science; Rondinone, Adam J. [Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States). Center for Nanophase Materials Science; Dudney, Nancy J. [Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States). Materials Science and Technology Division; Liang, Chengdu [Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States). Center for Nanophase Materials Science

    2014-01-14

    We fabricated a hybrid superionic conductor using the space charge effect between the LLZO and LPS interfaces. This space-charge effect resulted in an improvement over the individual bulk conductivities of the two systems. Sample with higher weight fractions of LLZO are limited by the porosity and grain boundary resistance arising from non-sintered membranes. Furthermore, by combining the properties of LLZO and LPS, the high temperature sintering step has been avoided thus facilitating easier materials processing. The interfacial resistances were also measured to be minimal at ambient conditions. Our procedure thus opens a new avenue for improving the ionic conductivity and electrochemical properties of existing solid state electrolytes. High frequency impedance analyses could aid in resolving the ionic conductivity contributions from the space charge layer in the higher conducting composites while mechanical property investigations could illustrate an improvement in the composite electrolyte in comparison with the crystalline LPS membranes.

  5. Studies and Properties of Ceramics with High Thermal Conductivity

    Institute of Scientific and Technical Information of China (English)

    2006-01-01

    The sintering technology of the AlN ceramics power were discussed. It is discussed that the compound sintering aids is consistent with the enhancement of the the thermal conductivity of AlN ceramics, and sintering technics is helped to the improvement of density. It is analyzed how to sinter machinable AlN ceramics with high thermal conductivity. And the microstructure of compound ceramics based on AlN was studied.

  6. Conductance saturation in a series of highly transmitting molecular junctions

    Science.gov (United States)

    Yelin, T.; Korytár, R.; Sukenik, N.; Vardimon, R.; Kumar, B.; Nuckolls, C.; Evers, F.; Tal, O.

    2016-04-01

    Revealing the mechanisms of electronic transport through metal-molecule interfaces is of central importance for a variety of molecule-based devices. A key method for understanding these mechanisms is based on the study of conductance versus molecule length in molecular junctions. However, previous works focused on transport governed either by coherent tunnelling or hopping, both at low conductance. Here, we study the upper limit of conductance across metal-molecule-metal interfaces. Using highly conducting single-molecule junctions based on oligoacenes with increasing length, we find that the conductance saturates at an upper limit where it is independent of molecule length. With the aid of two prototype systems, in which the molecules are contacted by either Ag or Pt electrodes, we find two different possible origins for conductance saturation. The results are explained by an intuitive model, backed by ab initio calculations. Our findings shed light on the mechanisms that constrain the conductance of metal-molecule interfaces at the high-transmission limit.

  7. Nonoperative treatment of an os peroneum fracture in a high-level athlete: a case report.

    Science.gov (United States)

    Smith, Jeremy T; Johnson, Anne H; Heckman, James D

    2011-05-01

    The os peroneum is a sesamoid bone in the peroneus longus tendon. Fractures of the os peroneum are rare. Some authors recommend surgery for active patients. A 41-year-old male professional tennis coach sustained a minimally displaced fracture of the os peroneum. He was treated with restricted weightbearing for 2 weeks, followed by physical therapy and gradual return to activities. He returned to tennis 8 weeks after injury. Followup 7 years after the injury showed he had full strength, full motion, and a radiographically healed os peroneum. The American Orthopaedic Foot and Ankle Society (AOFAS) Ankle-Hindfoot Scale score was 100 and Ankle Activity Score and Tegner Activity Level Scale were unchanged from those before injury. Fracture of the os peroneum is a rare injury and treatment recommendations are based largely on very small series and case reports. Proposed treatment strategies for fracture of the os peroneum include nonoperative treatment, fixation of the fracture, excision of the bone with direct repair of the tendon, and tenodesis of the peroneus longus to the peroneus brevis. Although some surgeons suggest fracture of the os peroneum should be treated operatively in active patients, this case shows nonoperative treatment allowed pain-free return to activities in a high-level athlete with a minimally-displaced fracture.

  8. Fractal characteristics of fracture morphology of steels irradiated with high-energy ions

    Energy Technology Data Exchange (ETDEWEB)

    Xian, Yongqiang; Liu, Juan [Institute of Modern Physics, Chinese Academy of Science, Lanzhou 730000 (China); University of Chinese Academy of Science, Beijing 100049 (China); Zhang, Chonghong, E-mail: c.h.zhang@impcas.ac.cn [Institute of Modern Physics, Chinese Academy of Science, Lanzhou 730000 (China); Chen, Jiachao [Paul Scherrer Institute, Villigen PSI (Switzerland); Yang, Yitao; Zhang, Liqing; Song, Yin [Institute of Modern Physics, Chinese Academy of Science, Lanzhou 730000 (China)

    2015-06-15

    Highlights: • Fractal dimensions of fracture surfaces of steels before and after irradiation were calculated. • Fractal dimension can effectively describe change of fracture surfaces induced by irradiation. • Correlation of change of fractal dimension with embrittlement of irradiated steels is discussed. - Abstract: A fractal analysis of fracture surfaces of steels (a ferritic/martensitic steel and an oxide-dispersion-strengthened ferritic steel) before and after the irradiation with high-energy ions is presented. Fracture surfaces were acquired from a tensile test and a small-ball punch test (SP). Digital images of the fracture surfaces obtained from scanning electron microscopy (SEM) were used to calculate the fractal dimension (FD) by using the pixel covering method. Boundary of binary image and fractal dimension were determined with a MATLAB program. The results indicate that fractal dimension can be an effective parameter to describe the characteristics of fracture surfaces before and after irradiation. The rougher the fracture surface, the larger the fractal dimension. Correlation of the change of fractal dimension with the embrittlement of the irradiated steels is discussed.

  9. Inkjet Printing of High Conductivity, Flexible Graphene Patterns.

    Science.gov (United States)

    Secor, Ethan B; Prabhumirashi, Pradyumna L; Puntambekar, Kanan; Geier, Michael L; Hersam, Mark C

    2013-04-18

    The ability to print high conductivity, conformal, and flexible electrodes is an important technological challenge in printed electronics, especially for large-area formats with low cost considerations. In this Letter, we demonstrate inkjet-printed, high conductivity graphene patterns that are suitable for flexible electronics. The ink is prepared by solution-phase exfoliation of graphene using an environmentally benign solvent, ethanol, and a stabilizing polymer, ethyl cellulose. The inkjet-printed graphene features attain low resistivity of 4 mΩ·cm after a thermal anneal at 250 °C for 30 min while showing uniform morphology, compatibility with flexible substrates, and excellent tolerance to bending stresses.

  10. Highly Conductive Wire: Cu Carbon Nanotube Composite Ampacity and Metallic CNT Buckypaper Conductivity

    Science.gov (United States)

    de Groh, Henry C.

    2017-01-01

    NASA is currently working on developing motors for hybrid electric propulsion applications in aviation. To make electric power more feasible in airplanes higher power to weight ratios are sought for electric motors. One facet to these efforts is to improve (increase) the conductivity and (lower) density of the magnet wire used in motors. Carbon nanotubes (CNT) and composites containing CNT are being explored as a possible way to increase wire conductivity and lower density. Presented here are measurements of the current carrying capacity (ampacity) of a composite made from CNT and copper. The ability of CNT to improve the conductivity of such composites is hindered by the presence of semiconductive CNT (s-CNT) that exist in CNT supplies naturally, and currently, unavoidably. To solve this problem, and avoid s-CNT, various preferential growth and sorting methods are being explored. A supply of sorted 95 metallic CNT (m-CNT) was acquired in the form of thick film Buckypaper (BP) as part of this work and characterized using Raman spectroscopy, resistivity, and density measurements. The ampacity (Acm2) of the Cu-5volCNT composite was 3.8 lower than the same gauge pure Cu wire similarly tested. The lower ampacity in the composite wire is believed to be due to the presence of s-CNT in the composite and the relatively low (proper) level of longitudinal cooling employed in the test method. Although Raman spectroscopy can be used to characterize CNT, a strong relation between the ratios of the primary peaks GGand the relative amounts of m-CNT and s-CNT was not observed. The average effective conductivity of the CNT in the sorted, 95 m-CNT BP was 2.5 times higher than the CNT in the similar but un-sorted BP. This is an indication that improvements in the conductivity of CNT composites can be made by the use of sorted, highly conductive m-CNT.

  11. The plane strain shear fracture of the advanced high strength steels

    Science.gov (United States)

    Sun, Li

    2013-12-01

    The "shear fracture" which occurs at the high-curvature die radii in the sheet metal forming has been reported to remarkably limit the application of the advanced high strength steels (AHSS) in the automobile industry. However, this unusual fracture behavior generally cannot be predicted by the traditional forming limit diagram (FLD). In this research, a new experimental system was developed in order to simulate the shear fracture, especially at the plane strain state which is the most common state in the auto-industry and difficult to achieve in the lab due to sample size. Furthermore, the system has the capability to operate in a strain rate range from quasi-static state to the industrial forming state. One kinds of AHSS, Quenching-Partitioning (QP) steels have been performed in this test and the results show that the limiting fracture strain is related to the bending ratio and strain rate. The experimental data support that deformation-induced heating is an important cause of "shear fracture" phenomena for AHSS: a deformation-induced quasi-heating caused by smaller bending ratio and high strain rate produce a smaller limiting plane strain and lead a "shear fracture" in the component.

  12. Discrete modeling of hydraulic fracturing processes in a complex pre-existing fracture network

    Science.gov (United States)

    Kim, K.; Rutqvist, J.; Nakagawa, S.; Houseworth, J. E.; Birkholzer, J. T.

    2015-12-01

    Hydraulic fracturing and stimulation of fracture networks are widely used by the energy industry (e.g., shale gas extraction, enhanced geothermal systems) to increase permeability of geological formations. Numerous analytical and numerical models have been developed to help understand and predict the behavior of hydraulically induced fractures. However, many existing models assume simple fracturing scenarios with highly idealized fracture geometries (e.g., propagation of a single fracture with assumed shapes in a homogeneous medium). Modeling hydraulic fracture propagation in the presence of natural fractures and homogeneities can be very challenging because of the complex interactions between fluid, rock matrix, and rock interfaces, as well as the interactions between propagating fractures and pre-existing natural fractures. In this study, the TOUGH-RBSN code for coupled hydro-mechanical modeling is utilized to simulate hydraulic fracture propagation and its interaction with pre-existing fracture networks. The simulation tool combines TOUGH2, a simulator of subsurface multiphase flow and mass transport based on the finite volume approach, with the implementation of a lattice modeling approach for geomechanical and fracture-damage behavior, named Rigid-Body-Spring Network (RBSN). The discrete fracture network (DFN) approach is facilitated in the Voronoi discretization via a fully automated modeling procedure. The numerical program is verified through a simple simulation for single fracture propagation, in which the resulting fracture geometry is compared to an analytical solution for given fracture length and aperture. Subsequently, predictive simulations are conducted for planned laboratory experiments using rock-analogue (soda-lime glass) samples containing a designed, pre-existing fracture network. The results of a preliminary simulation demonstrate selective fracturing and fluid infiltration along the pre-existing fractures, with additional fracturing in part

  13. Silicon-graphene conductive photodetector with ultra-high responsivity

    Science.gov (United States)

    Liu, Jingjing; Yin, Yanlong; Yu, Longhai; Shi, Yaocheng; Liang, Di; Dai, Daoxin

    2017-01-01

    Graphene is attractive for realizing optoelectronic devices, including photodetectors because of the unique advantages. It can easily co-work with other semiconductors to form a Schottky junction, in which the photo-carrier generated by light absorption in the semiconductor might be transported to the graphene layer efficiently by the build-in field. It changes the graphene conduction greatly and provides the possibility of realizing a graphene-based conductive-mode photodetector. Here we design and demonstrate a silicon-graphene conductive photodetector with improved responsivity and response speed. An electrical-circuit model is established and the graphene-sheet pattern is designed optimally for maximizing the responsivity. The fabricated silicon-graphene conductive photodetector shows a responsivity of up to ~105 A/W at room temperature (27 °C) and the response time is as short as ~30 μs. The temperature dependence of the silicon-graphene conductive photodetector is studied for the first time. It is shown that the silicon-graphene conductive photodetector has ultra-high responsivity when operating at low temperature, which provides the possibility to detect extremely weak optical power. For example, the device can detect an input optical power as low as 6.2 pW with the responsivity as high as 2.4 × 107 A/W when operating at −25 °C in our experiment. PMID:28106084

  14. Silicon-graphene conductive photodetector with ultra-high responsivity

    Science.gov (United States)

    Liu, Jingjing; Yin, Yanlong; Yu, Longhai; Shi, Yaocheng; Liang, Di; Dai, Daoxin

    2017-01-01

    Graphene is attractive for realizing optoelectronic devices, including photodetectors because of the unique advantages. It can easily co-work with other semiconductors to form a Schottky junction, in which the photo-carrier generated by light absorption in the semiconductor might be transported to the graphene layer efficiently by the build-in field. It changes the graphene conduction greatly and provides the possibility of realizing a graphene-based conductive-mode photodetector. Here we design and demonstrate a silicon-graphene conductive photodetector with improved responsivity and response speed. An electrical-circuit model is established and the graphene-sheet pattern is designed optimally for maximizing the responsivity. The fabricated silicon-graphene conductive photodetector shows a responsivity of up to ~105 A/W at room temperature (27 °C) and the response time is as short as ~30 μs. The temperature dependence of the silicon-graphene conductive photodetector is studied for the first time. It is shown that the silicon-graphene conductive photodetector has ultra-high responsivity when operating at low temperature, which provides the possibility to detect extremely weak optical power. For example, the device can detect an input optical power as low as 6.2 pW with the responsivity as high as 2.4 × 107 A/W when operating at ‑25 °C in our experiment.

  15. Survey of Processing Methods for High Strength High Conductivity Wires for High Field Magnet Applications

    Energy Technology Data Exchange (ETDEWEB)

    Han, K.; Embury, J.D.

    1998-10-01

    This paper will deal with the basic concepts of attaining combination of high strength and high conductivity in pure materials, in-situ composites and macrocomposites. It will survey current attainments, and outline where some future developments may lie in developing wire products that are close to the theoretical strength of future magnet applications.

  16. Conductivity and entanglement entropy of high dimensional holographic superconductors

    CERN Document Server

    Romero-Bermúdez, Aurelio

    2015-01-01

    We investigate the dependence of the conductivity and the entanglement entropy on the space-time dimensionality $d$ in two holographic superconductors: one dual to a quantum critical point with spontaneous symmetry breaking, and the other modeled by a charged scalar that condenses at a sufficiently low temperature in the presence of a Maxwell field. In both cases the gravity background is asymptotically Anti de Sitter (AdS). In the large $d$ limit we obtain explicit analytical results for the conductivity at zero temperature and the entanglement entropy by a $1/d$ expansion. We show that the entanglement entropy is always smaller in the broken phase and identify a novel decay of the conductivity for intermediate frequencies. As dimensionality increases, the entanglement entropy decreases, the coherence peak in the conductivity becomes narrower and the ratio between the energy gap and the critical temperature decreases. These results suggest that the condensate interactions become weaker in high spatial dimens...

  17. High conductivity transparent carbon nanotube films deposited from superacid

    Energy Technology Data Exchange (ETDEWEB)

    Hecht, David S; Lee, Roland; Hu Liangbing [Unidym Incorporated, 1244 Reamwood Drive, Sunnyvale, CA 94089 (United States); Heintz, Amy M; Moore, Bryon; Cucksey, Chad; Risser, Steven, E-mail: dhecht@gmail.com [Battelle, 505 King Avenue, Columbus, OH 43201 (United States)

    2011-02-18

    Carbon nanotubes (CNTs) were deposited from a chlorosulfonic superacid solution onto PET substrates by a filtration/transfer method. The sheet resistance and transmission (at 550 nm) of the films were 60 {Omega}/sq and 90.9% respectively, which corresponds to a DC conductivity of 12 825 S cm{sup -1} and a DC/optical conductivity ratio of 64.1. This is the highest DC conductivity reported for CNT thin films to date, and attributed to both the high quality of the CNT material and the exfoliation/doping by the superacid. This work demonstrates that CNT transparent films have not reached the conductivity limit; continued improvements will enable these films to be used as the transparent electrode for applications in solid state lighting, LCD displays, touch panels, and photovoltaics.

  18. High conductivity transparent carbon nanotube films deposited from superacid.

    Science.gov (United States)

    Hecht, David S; Heintz, Amy M; Lee, Roland; Hu, Liangbing; Moore, Bryon; Cucksey, Chad; Risser, Steven

    2011-02-18

    Carbon nanotubes (CNTs) were deposited from a chlorosulfonic superacid solution onto PET substrates by a filtration/transfer method. The sheet resistance and transmission (at 550 nm) of the films were 60 Ω/sq and 90.9% respectively, which corresponds to a DC conductivity of 12,825 S cm(-1) and a DC/optical conductivity ratio of 64.1. This is the highest DC conductivity reported for CNT thin films to date, and attributed to both the high quality of the CNT material and the exfoliation/doping by the superacid. This work demonstrates that CNT transparent films have not reached the conductivity limit; continued improvements will enable these films to be used as the transparent electrode for applications in solid state lighting, LCD displays, touch panels, and photovoltaics.

  19. Minimally-invasive treatment of high velocity intra-articular fractures of the distal tibia.

    LENUS (Irish Health Repository)

    Leonard, M

    2012-02-01

    The pilon fracture is a complex injury. The purpose of this study was to evaluate the outcome of minimally invasive techniques in management of these injuries. This was a prospective study of closed AO type C2 and C3 fractures managed by early (<36 hours) minimally invasive surgical intervention and physiotherapist led rehabilitation. Thirty patients with 32 intra-articular distal tibial fractures were treated by the senior surgeon (GK). Our aim was to record the outcome and all complications with a minimum two year follow-up. There were two superficial wound infections. One patient developed a non-union which required a formal open procedure. Another patient was symptomatic from a palpable plate inferiorly. An excellent AOFAS result was obtained in 83% (20\\/24) of the patients. Early minimally invasive reduction and fixation of complex high velocity pilon fractures gave very satisfactory results at a minimum of two years follow-up.

  20. Numerical study on transient flow in the deep naturally fractured reservoir with high pressure

    Institute of Scientific and Technical Information of China (English)

    2009-01-01

    According to the experimental results and the characteristics of the pressure-sensitive fractured formation, a transient flow model is developed for the deep naturally-fractured reservoirs with different outer boundary conditions. The finite element equations for the model are derived. After generating the unstructured grids in the solution regions, the finite element method is used to calculate the pressure type curves for the pressure-sensitive fractured reservoir with different outer boundaries, such as the infinite boundary, circle boundary and combined linear boundaries, and the characteristics of the type curves are comparatively analyzed. The effects on the pressure curves caused by pressure sensitivity module and the effective radius combined parameter are determined, and the method for calculating the pressure-sensitive reservoir parameters is introduced. By analyzing the real field case in the high temperature and pressure reservoir, the perfect results show that the transient flow model for the pressure-sensitive fractured reservoir in this paper is correct.

  1. Numerical study on transient flow in the deep naturally fractured reservoir with high pressure

    Institute of Scientific and Technical Information of China (English)

    LIU YueWu; CHEN WeiLiang; LIU QingQuan

    2009-01-01

    According to the experimental results and the characteristics of the pressure-sensitive fractured for-mation, a transient flow model is developed for the deep naturally-fractured reservoirs with different outer boundary conditions. The finite element equations for the model are derived. After generating the unstructured grids in the solution regions, the finite element method is used to calculate the pressure type curves for the pressure-eensitive fractured reservoir with different outer boundaries, such as the infinite boundary, circle boundary and combined linear boundaries, and the characteristics of the type curves are comparatively analyzed. The effects on the pressure curves caused by pressure sensitivity module and the effective radius combined parameter are determined, and the method for calculating the pressure-sensitive reservoir parameters is introduced. By analyzing the real field case in the high temperature end pressure reservoir, the perfect results show that the transient flow model for the pressure-sensitive fractured reservoir in this paper is correct.

  2. Fracture analysis of a transversely isotropic high temperature superconductor strip based on real fundamental solutions

    Energy Technology Data Exchange (ETDEWEB)

    Gao, Zhiwen, E-mail: gaozhw@lzu.edu.cn; Zhou, Youhe

    2015-04-15

    Highlights: • We studied fracture problem in HTS based on real fundamental solutions. • When the thickness of HTS strip increases the SIF decrease. • A higher applied field leads to a larger stress intensity factor. • The greater the critical current density is, the smaller values of the SIF is. - Abstract: Real fundamental solution for fracture problem of transversely isotropic high temperature superconductor (HTS) strip is obtained. The superconductor E–J constitutive law is characterized by the Bean model where the critical current density is independent of the flux density. Fracture analysis is performed by the methods of singular integral equations which are solved numerically by Gauss–Lobatto–Chybeshev (GSL) collocation method. To guarantee a satisfactory accuracy, the convergence behavior of the kernel function is investigated. Numerical results of fracture parameters are obtained and the effects of the geometric characteristics, applied magnetic field and critical current density on the stress intensity factors (SIF) are discussed.

  3. Hybrid electrokinetic manipulation in high-conductivity media.

    Science.gov (United States)

    Gao, Jian; Sin, Mandy L Y; Liu, Tingting; Gau, Vincent; Liao, Joseph C; Wong, Pak Kin

    2011-05-21

    This study reports a hybrid electrokinetic technique for label-free manipulation of pathogenic bacteria in biological samples toward medical diagnostic applications. While most electrokinetic techniques only function in low-conductivity buffers, hybrid electrokinetics enables effective operation in high-conductivity samples, such as physiological fluids (∼1 S m(-1)). The hybrid electrokinetic technique combines short-range electrophoresis and dielectrophoresis, and long-range AC electrothermal flow to improve its effectiveness. The major technical hurdle of electrode instability for manipulating high conductivity samples is tackled by using a Ti-Au-Ti sandwich electrode and a 3-parallel-electrode configuration is designed for continuous isolation of bacteria. The device operates directly with biological samples including urine and buffy coats. We show that pathogenic bacteria and biowarfare agents can be concentrated for over 3 orders of magnitude using hybrid electrokinetics.

  4. High ionic conductivity in confined bismuth oxide-based heterostructures

    Science.gov (United States)

    Sanna, Simone; Esposito, Vincenzo; Christensen, Mogens; Pryds, Nini

    2016-12-01

    Bismuth trioxide in the cubic fluorite phase (δ -Bi2O3 ) exhibits the highest oxygen ionic conductivity. In this study, we were able to stabilize the pure δ -Bi2O3 at low temperature with no addition of stabilizer but only by engineering the interface, using highly coherent heterostructures made of alternative layers of δ -Bi2O3 and Yttria Stabilized Zirconia (YSZ), deposited by pulsed laser deposition. The resulting [δ -Bi2O3 /YSZ ] heterostructures are found to be stable over a wide temperature range (500-750 °C) and exhibits stable high ionic conductivity over a long time comparable to the value of the pure δ -Bi2O3 , which is approximately two orders of magnitude higher than the conductivity of YSZ bulk.

  5. High ionic conductivity in confined bismuth oxide-based heterostructures

    Directory of Open Access Journals (Sweden)

    Simone Sanna

    2016-12-01

    Full Text Available Bismuth trioxide in the cubic fluorite phase (δ-Bi2O3 exhibits the highest oxygen ionic conductivity. In this study, we were able to stabilize the pure δ-Bi2O3 at low temperature with no addition of stabilizer but only by engineering the interface, using highly coherent heterostructures made of alternative layers of δ-Bi2O3 and Yttria Stabilized Zirconia (YSZ, deposited by pulsed laser deposition. The resulting [δ-Bi2O3/YSZ] heterostructures are found to be stable over a wide temperature range (500-750 °C and exhibits stable high ionic conductivity over a long time comparable to the value of the pure δ-Bi2O3, which is approximately two orders of magnitude higher than the conductivity of YSZ bulk.

  6. Engineering Graphene Conductivity for Flexible and High-Frequency Applications.

    Science.gov (United States)

    Samuels, Alexander J; Carey, J David

    2015-10-14

    Advances in lightweight, flexible, and conformal electronic devices depend on materials that exhibit high electrical conductivity coupled with high mechanical strength. Defect-free graphene is one such material that satisfies both these requirements and which offers a range of attractive and tunable electrical, optoelectronic, and plasmonic characteristics for devices that operate at microwave, terahertz, infrared, or optical frequencies. Essential to the future success of such devices is therefore the ability to control the frequency-dependent conductivity of graphene. Looking to accelerate the development of high-frequency applications of graphene, here we demonstrate how readily accessible and processable organic and organometallic molecules can efficiently dope graphene to carrier densities in excess of 10(13) cm(-2) with conductivities at gigahertz frequencies in excess of 60 mS. In using the molecule 3,6-difluoro-2,5,7,7,8,8-hexacyanoquinodimethane (F2-HCNQ), a high charge transfer (CT) of 0.5 electrons per adsorbed molecule is calculated, resulting in p-type doping of graphene. n-Type doping is achieved using cobaltocene and the sulfur-containing molecule tetrathiafulvalene (TTF) with a CT of 0.41 and 0.24 electrons donated per adsorbed molecule, respectively. Efficient CT is associated with the interaction between the π electrons present in the molecule and in graphene. Calculation of the high-frequency conductivity shows dispersion-less behavior of the real component of the conductivity over a wide range of gigahertz frequencies. Potential high-frequency applications in graphene antennas and communications that can exploit these properties and the broader impacts of using molecular doping to modify functional materials that possess a low-energy Dirac cone are also discussed.

  7. High ionic conductivity in confined bismuth oxide-based heterostructures

    DEFF Research Database (Denmark)

    Sanna, Simone; Esposito, Vincenzo; Christensen, Mogens

    2016-01-01

    Bismuth trioxide in the cubic fluorite phase (δ-Bi2O3) exhibits the highest oxygen ionic conductivity. In this study, we were able to stabilize the pure -Bi2O3 at low temperature with no addition of stabilizer but only by engineering the interface, using highly coherent heterostructures made...

  8. Dynamics and sensitivity analysis of high-frequency conduction block

    Science.gov (United States)

    Ackermann, D. Michael; Bhadra, Niloy; Gerges, Meana; Thomas, Peter J.

    2011-10-01

    The local delivery of extracellular high-frequency stimulation (HFS) has been shown to be a fast acting and quickly reversible method of blocking neural conduction and is currently being pursued for several clinical indications. However, the mechanism for this type of nerve block remains unclear. In this study, we investigate two hypotheses: (1) depolarizing currents promote conduction block via inactivation of sodium channels and (2) the gating dynamics of the fast sodium channel are the primary determinate of minimal blocking frequency. Hypothesis 1 was investigated using a combined modeling and experimental study to investigate the effect of depolarizing and hyperpolarizing currents on high-frequency block. The results of the modeling study show that both depolarizing and hyperpolarizing currents play an important role in conduction block and that the conductance to each of three ionic currents increases relative to resting values during HFS. However, depolarizing currents were found to promote the blocking effect, and hyperpolarizing currents were found to diminish the blocking effect. Inward sodium currents were larger than the sum of the outward currents, resulting in a net depolarization of the nodal membrane. Our experimental results support these findings and closely match results from the equivalent modeling scenario: intra-peritoneal administration of the persistent sodium channel blocker ranolazine resulted in an increase in the amplitude of HFS required to produce conduction block in rats, confirming that depolarizing currents promote the conduction block phenomenon. Hypothesis 2 was investigated using a spectral analysis of the channel gating variables in a single-fiber axon model. The results of this study suggested a relationship between the dynamical properties of specific ion channel gating elements and the contributions of corresponding conductances to block onset. Specifically, we show that the dynamics of the fast sodium inactivation gate are

  9. HIgh-temperature electrical conductivity and thermal decomposition of Sylgard 184 and 184/GMB

    Energy Technology Data Exchange (ETDEWEB)

    Johnson, R.T. Jr.; Biefeld, R.M.

    1983-01-01

    These properties were determined to 600 to 700/sup 0/C in air and nitrogen environments. The material is a silicone-based dielectric and is used as an encapsulant for electronic components. The 184/GMB material contains glass microballoons. The thermal decomposition characteristics were determined from mass loss and vaporization species (mass spectroscopy) measurements. Results show only minor weight loss in air up to 300/sup 0/C and in nitrogen to 400/sup 0/C. There is a peak in the conductivity at approx. 300/sup 0/C which results from the volatilization of (Si (CH/sub 3/))/sub n/ with some dehydration. At and above 400/sup 0/C, weight loss is much more pronounced and the conductivity is dependent upon the atmosphere and upon the presence of glass microballoons. The conductivity characteristics in air are similar to those in nitrogen, except there is a peak in air at 490 to 530/sup 0/C due to combustion and there is a shift to lower temperatures. This indicates that the oxygen accelerates decomposition. 184/GMB exhibits an enhanced conductivity above approx. 500/sup 0/C. Similar results are observed for materials with islica microballoons (184/GMB-S) and ceramic microballoons (184/CMB). This suggests that the microballons may help form a network of interconnected conductive pathways in the residual material. The material without microballoons is highly fractured. 18 figures, 5 tables.

  10. High ion conducting polymer nanocomposite electrolytes using hybrid nanofillers.

    Science.gov (United States)

    Tang, Changyu; Hackenberg, Ken; Fu, Qiang; Ajayan, Pulickel M; Ardebili, Haleh

    2012-03-14

    There is a growing shift from liquid electrolytes toward solid polymer electrolytes, in energy storage devices, due to the many advantages of the latter such as enhanced safety, flexibility, and manufacturability. The main issue with polymer electrolytes is their lower ionic conductivity compared to that of liquid electrolytes. Nanoscale fillers such as silica and alumina nanoparticles are known to enhance the ionic conductivity of polymer electrolytes. Although carbon nanotubes have been used as fillers for polymers in various applications, they have not yet been used in polymer electrolytes as they are conductive and can pose the risk of electrical shorting. In this study, we show that nanotubes can be packaged within insulating clay layers to form effective 3D nanofillers. We show that such hybrid nanofillers increase the lithium ion conductivity of PEO electrolyte by almost 2 orders of magnitude. Furthermore, significant improvement in mechanical properties were observed where only 5 wt % addition of the filler led to 160% increase in the tensile strength of the polymer. This new approach of embedding conducting-insulating hybrid nanofillers could lead to the development of a new generation of polymer nanocomposite electrolytes with high ion conductivity and improved mechanical properties.

  11. Highly conductive paper for energy-storage devices

    KAUST Repository

    Hu, L.

    2009-12-07

    Paper, invented more than 2,000 years ago and widely used today in our everyday lives, is explored in this study as a platform for energy-storage devices by integration with 1D nanomaterials. Here, we show that commercially available paper can be made highly conductive with a sheet resistance as low as 1 ohm per square (Omega/sq) by using simple solution processes to achieve conformal coating of single-walled carbon nanotube (CNT) and silver nanowire films. Compared with plastics, paper substrates can dramatically improve film adhesion, greatly simplify the coating process, and significantly lower the cost. Supercapacitors based on CNT-conductive paper show excellent performance. When only CNT mass is considered, a specific capacitance of 200 F/g, a specific energy of 30-47 Watt-hour/kilogram (Wh/kg), a specific power of 200,000 W/kg, and a stable cycling life over 40,000 cycles are achieved. These values are much better than those of devices on other flat substrates, such as plastics. Even in a case in which the weight of all of the dead components is considered, a specific energy of 7.5 Wh/kg is achieved. In addition, this conductive paper can be used as an excellent lightweight current collector in lithium-ion batteries to replace the existing metallic counterparts. This work suggests that our conductive paper can be a highly scalable and low-cost solution for high-performance energy storage devices.

  12. Preceding and subsequent high- and low-trauma fracture patterns-a 13-year epidemiological study in females and males in Austria.

    Science.gov (United States)

    Muschitz, C; Kocijan, R; Baierl, A; Dormann, R; Feichtinger, X; Haschka, J; Szivak, M; Muschitz, G K; Schanda, J; Pietschmann, P; Resch, H; Dimai, H P

    2017-01-30

    This study investigated the implication of a preceding high-trauma fracture on subsequent high- and low-trauma fractures at different skeletal sites in postmenopausal women and similarly aged men at an age range of 54 to 70 years. A preceding high-trauma fracture increases the risk of future low-trauma non-vertebral fractures including hip.

  13. Direct tension and fracture resistance curves of ultra high performance marine composite materials

    Institute of Scientific and Technical Information of China (English)

    WU Xiang-guo; HAN Sang-mook

    2008-01-01

    Fracture behavior is one of the most important, yet still little understood properties of ultra-high performance cementitious composites (UHPCC), a new marine structural engineering material.Research on the fracture and direct tension behavior of UHPCC was carried out. The constitution law of UHPCC was divided into three phases: pre-partial debonding, partial debonding, and pullout phases. A direct tension constitution law was constructed based on the proposed fiber reinforcing parameter as a function of fiber volume fraction, fiber diameter and length, and fiber bonding strength. With the definition of linear crack shape, the energy release rate of UHPCC was derived and the R-curve equation was calculated from this. Loading tests of UHPCC using a three-point bending beam with an initial notch were carried out. The predictions from the proposed R-curve were in good agreement with the test results,indicating that the proposed R-curve accurately describes the fracture resistance of UHPCC. Introductionof a fiber reinforcement parameter bridges the fracture property R-curve and micro-composites mechanics parameters together. This has laid the foundation for further research into fracture properties based on micro-mechanics. The proposed tension constitution law and R-curve can be references for future UHPCC fracture evaluation.

  14. Electrical conductivity of rigid polyurethane foam at high temperature

    Science.gov (United States)

    Johnson, R. T., Jr.

    1982-08-01

    The electrical conductivity of rigid polyurethane foam, used for electronic encapsulation, was measured during thermal decomposition to 3400 C. At higher temperatures the conductance continues to increase. With pressure loaded electrical leads, sample softening results in eventual contact between electrodes which produces electrical shorting. Air and nitrogen environments show no significant dependence of the conductivity on the atmosphere over the temperature range. The insulating characteristics of polyurethane foam below approx. 2700 C are similar to those for silicone based materials used for electronic case housings and are better than those for phenolics. At higher temperatures (greater than or equal to 2700 C) the phenolics appear to be better insulators to approx. 5000 C and the silicones to approx. 6000 C. It is concluded that the Sylgard 184/GMB encapsulant is a significantly better insulator at high temperature than the rigid polyurethane foam.

  15. High-Sensitivity CRP Is an Independent Risk Factor for All Fractures and Vertebral Fractures in Elderly Men: The MrOS Sweden Study

    OpenAIRE

    Eriksson, Anna L; Movérare-Skrtic, Sofia; Ljunggren, Östen; Karlsson, Magnus; Mellström, Dan; Ohlsson, Claes

    2014-01-01

    Epidemiological studies have shown low-grade inflammation measured by high-sensitivity C-reactive protein (hs-CRP) to be associated with fracture risk in women. However, it is still unclear whether hs-CRP is also associated with fracture risk in men. We therefore measured serum levels of hs-CRP in 2910 men, mean age 75 years, included in the prospective population-based MrOS Sweden cohort. Study participants were divided into tertile groups based on hs-CRP level. Fractures occurring after the...

  16. Developing a High Thermal Conductivity Fuel with Silicon Carbide Additives

    Energy Technology Data Exchange (ETDEWEB)

    baney, Ronald; Tulenko, James

    2012-11-20

    The objective of this research is to increase the thermal conductivity of uranium oxide (UO{sub 2}) without significantly impacting its neutronic properties. The concept is to incorporate another high thermal conductivity material, silicon carbide (SiC), in the form of whiskers or from nanoparticles of SiC and a SiC polymeric precursor into UO{sub 2}. This is expected to form a percolation pathway lattice for conductive heat transfer out of the fuel pellet. The thermal conductivity of SiC would control the overall fuel pellet thermal conductivity. The challenge is to show the effectiveness of a low temperature sintering process, because of a UO{sub 2}-SiC reaction at 1,377°C, a temperature far below the normal sintering temperature. Researchers will study three strategies to overcome the processing difficulties associated with pore clogging and the chemical reaction of SiC and UO{sub 2} at temperatures above 1,300°C:

  17. Highly Conductive Polypropylene-Graphene Nonwoven Composite via Interface Engineering.

    Science.gov (United States)

    Pan, Qin; Shim, Eunkyoung; Pourdeyhimi, Behnam; Gao, Wei

    2017-08-01

    Here we report a highly conductive polypropylene-graphene nonwoven composite via direct coating of melt blown polypropylene (PP) nonwoven fabrics with graphene oxide (GO) dispersions in N,N-dimethylformamide (DMF), followed by the chemical reduction of GO with hydroiodic acid (HI). GO as an amphiphilic macromolecule can be dispersed in DMF homogeneously at a concentration of 5 mg/mL, which has much lower surface tension (37.5 mN/m) than that of GO in water (72.9 mN/m, at 5 mg/mL). The hydrophobic PP nonwoven has a surface energy of 30.1 mN/m, close to the surface tension of GO in DMF. Therefore, the PP nonwoven can be easily wetted by the GO/DMF dispersion without any pretreatment. Soaking PP nonwoven in a GO/DMF dispersion leads to uniform coatings of GO on PP-fiber surfaces. After chemical reduction of GO to graphene, the resulting PP/graphene nonwoven composite offers an electrical conductivity of 35.6 S m(-1) at graphene loading of 5.2 wt %, the highest among the existing conductive PP systems reported, indicating that surface tension of coating baths has significant impact on the coating uniformity and affinity. The conductivity of our PP/graphene nonwoven is also stable against stirring washing test. In addition, here we demonstrate a monolithic supercapacitor derived from the PP-GO nonwoven composite by using a direct laser-patterning process. The resulted sandwich supercapacitor shows a high areal capacitance of 4.18 mF/cm(2) in PVA-H2SO4 gel electrolyte. The resulting highly conductive or capacitive PP/graphene nonwoven carries great promise to be used as electronic textiles.

  18. Phase Transformation in a β-Ti Alloy with Good Balance Between High Strength and High Fracture Toughness

    Institute of Scientific and Technical Information of China (English)

    Li Yang; Wei Qiang; Ma Chaoli; Zheng Lijing; Li Huanxi; Ge Peng; Zhao Yongqing

    2009-01-01

    This article studies the phase transformation of the metastable (-Ti-Al-Mo-V-Cr-Zr alloy (Ti-1300) to disclose the morphological reason for its high strength and high fracture toughness. It has been found that its ultrahigh strength (ultimate tensile strength exceeds 1 400 MPa) owes mainly to the spheroidization of the (-phase, while the high fracture toughness (exceeds 81 MPa·m~(1/2)) to the special lath-shaped (-particles. Compared to the needle-shaped second (-articles, the coarser lath-shaped ones remove the stress concentration at the lath tips and consequently benefit improvement of fracture toughness. The article also describes shape evolution of the (-particles during aging thermodynamically and kinetically, and suggests an optimized aging processing to achieve an ideal balance between high strength and high toughness for this alloy.

  19. Interior Regularity Estimates in High Conductivity Homogenization and Application

    CERN Document Server

    Briane, Marc; Nguyen, Luc

    2011-01-01

    In this paper, uniform pointwise regularity estimates for the solutions of conductivity equations are obtained in a unit conductivity medium reinforced by a epsilon-periodic lattice of highly conducting thin rods. The estimates are derived only at a distance epsilon^{1+tau} (for some tau>0) away from the fibres. This distance constraint is rather sharp since the gradients of the solutions are shown to be unbounded locally in L^p as soon as p>2. One key ingredient is the derivation in dimension two of regularity estimates to the solutions of the equations deduced from a Fourier series expansion with respect to the fibres direction, and weighted by the high-contrast conductivity. The dependence on powers of epsilon of these two-dimensional estimates is shown to be sharp. The initial motivation for this work comes from imaging, and enhanced resolution phenomena observed experimentally in the presence of micro-structures. We use these regularity estimates to characterize the signature of low volume fraction heter...

  20. Interior Regularity Estimates in High Conductivity Homogenization and Application

    Science.gov (United States)

    Briane, Marc; Capdeboscq, Yves; Nguyen, Luc

    2013-01-01

    In this paper, uniform pointwise regularity estimates for the solutions of conductivity equations are obtained in a unit conductivity medium reinforced by an ɛ-periodic lattice of highly conducting thin rods. The estimates are derived only at a distance ɛ 1+ τ (for some τ > 0) away from the fibres. This distance constraint is rather sharp since the gradients of the solutions are shown to be unbounded locally in L p as soon as p > 2. One key ingredient is the derivation in dimension two of regularity estimates to the solutions of the equations deduced from a Fourier series expansion with respect to the fibres' direction, and weighted by the high-contrast conductivity. The dependence on powers of ɛ of these two-dimensional estimates is shown to be sharp. The initial motivation for this work comes from imaging, and enhanced resolution phenomena observed experimentally in the presence of micro-structures (L erosey et al., Science 315:1120-1124, 2007). We use these regularity estimates to characterize the signature of low volume fraction heterogeneities in the fibred reinforced medium, assuming that the heterogeneities stay at a distance ɛ 1+ τ away from the fibres.

  1. Treatment of Wastewater with High Conductivity by Pulsed Discharge Plasma

    Science.gov (United States)

    Wang, Zhaojun; Jiang, Song; Liu, Kefu

    2014-07-01

    A wastewater treatment system was established by means of pulsed dielectric barrier discharge (DBD). The main advantage of this system is that the wastewater is employed as one of the electrodes for the degradation of rhodamine B, which makes use of the high conductivity and lessenes its negative influence on the discharge process. At the same time, the reactive species like ozone and ultraviolet (UV) light generated by the DBD can be utilized for the treatment of wastewater. The effects of some factors like conductivity, peak pulse voltage, discharge frequency and pH values were investigated. The results show that the combination of these reactive species could enhance the degradation of the dye while the ozone played the most important role in the process. The degradation efficiency was enhanced with the increase of energy supplied. The reduction in the concentration of rhodamine B was much more effective with high solution conductivity; under the highest conductivity condition, the degradation rate could rise to 99%.

  2. Crack formation and fracture energy of normal and high strength concrete

    Indian Academy of Sciences (India)

    F H Wittmann

    2002-08-01

    The crack path through composite materials such as concrete depends on the mechanical interaction of inclusions with the cement-based matrix. Fracture energy depends on the deviations of a real crack from an idealized crack plane. Fracture energy and strain softening of normal, high strength, and self-compacting concrete have been determined by means of the wedge splitting test. In applying the numerical model called “numerical concrete” crack formation in normal and high strength concrete is simulated. Characteristic differences of the fracture process can be outlined. Finally results obtained are applied to predict shrinkage cracking under different boundary conditions. Crack formation of high strength concrete has to be seriously controlled in order to achieve the necessary durability of concrete structures.

  3. Fabrication of highly conductive carbon nanotube fibers for electrical application

    Science.gov (United States)

    Guo, Fengmei; Li, Can; Wei, Jinquan; Xu, Ruiqiao; Zhang, Zelin; Cui, Xian; Wang, Kunlin; Wu, Dehai

    2015-09-01

    Carbon nanotubes (CNTs) have great potential for use as electrical wires because of their outstanding electrical and mechanical properties. Here, we fabricate lightweight CNT fibers with electrical conductivity as high as that of stainless steel from macroscopic CNT films by drawing them through diamond wire-drawing dies. The entangled CNT bundles are straightened by suffering tension, which improves the alignment of the fibers. The loose fibers are squeezed by the diamond wire-drawing dies, which reduces the intertube space and contact resistance. The CNT fibers prepared by drawing have an electrical conductivity as high as 1.6 × 106 s m-1. The fibers are very stable when kept in the air and under cyclic tensile test. A prototype of CNT motor is demonstrated by replacing the copper wires with the CNT fibers.

  4. Effect laws and mechanisms of different temperatures on isothermal tensile fracture morphologies of high-strength boron steel

    Institute of Scientific and Technical Information of China (English)

    刘佳宁; 宋燕利; 路珏; 郭巍

    2015-01-01

    The fracture behaviour and morphologies of high-strength boron steel were investigated at different temperatures at a constant strain rate of 0.1 s−1 based on isothermal tensile tests. Fracture mechanisms were also analyzed based on the relationship between microstructure transformation and continuous cooling transformation (CCT) curves. It is found that 1) fractures of the investigated steel at high temperatures are dimple fractures; 2) the deformation of high-strength boron steel at high temperatures accelerates diffusion transformations;thus, to obtain full martensite, a higher cooling rate is needed;and 3) the investigated steel has the best plasticity when the deformation temperature is 750 °C.

  5. Method for producing highly conformal transparent conducting oxides

    Energy Technology Data Exchange (ETDEWEB)

    Elam, Jeffrey W.; Mane, Anil U.

    2016-07-26

    A method for forming a transparent conducting oxide product layer. The method includes use of precursors, such as tetrakis-(dimethylamino) tin and trimethyl indium, and selected use of dopants, such as SnO and ZnO for obtaining desired optical, electrical and structural properties for a highly conformal layer coating on a substrate. Ozone was also input as a reactive gas which enabled rapid production of the desired product layer.

  6. Recent Improvements in High-Frequency Eddy Current Conductivity Spectroscopy

    Science.gov (United States)

    Abu-Nabah, Bassam A.; Nagy, Peter B.

    2008-02-01

    Due to its frequency-dependent penetration depth, eddy current measurements are capable of mapping near-surface residual stress profiles based on the so-called piezoresistivity effect, i.e., the stress-dependence of electric conductivity. To capture the peak compressive residual stress in moderately shot-peened (Almen 4-8A) nickel-base superalloys, the eddy current inspection frequency has to go as high as 50-80 MHz. Recently, we have reported the development of a new high-frequency eddy current conductivity measuring system that offers an extended inspection frequency range up to 80 MHz. Unfortunately, spurious self- and stray-capacitance effects render the complex coil impedance variation with lift-off more nonlinear as the frequency increases, which makes it difficult to achieve accurate apparent eddy current conductivity (AECC) measurements with the standard four-point linear interpolation method beyond 25 MHz. In this paper, we will demonstrate that reducing the coil size reduces its sensitivity to capacitive lift-off variations, which is just the opposite of the better known inductive lift-off effect. Although reducing the coil size also reduces its absolute electric impedance and relative sensitivity to conductivity variations, a smaller coil still yields better overall performance for residual stress assessment. In addition, we will demonstrate the benefits of a semi-quadratic interpolation scheme that, together with the reduced lift-off sensitivity of the smaller probe coil, minimizes and in some cases completely eliminates the sensitivity of AECC measurements to lift-off uncertainties. These modifications allow us to do much more robust measurements up to as high as 80-100 MHz with the required high relative accuracy of +/-0.1%.

  7. The Dynamic Fracture Process in Rocks Under High-Voltage Pulse Fragmentation

    Science.gov (United States)

    Cho, Sang Ho; Cheong, Sang Sun; Yokota, Mitsuhiro; Kaneko, Katsuhiko

    2016-10-01

    High-voltage pulse technology has been applied to rock excavation, liberation of microfossils, drilling of rocks, oil and water stimulation, cleaning castings, and recycling products like concrete and electrical appliances. In the field of rock mechanics, research interest has focused on the use of high-voltage pulse technology for drilling and cutting rocks over the past several decades. In the use of high-voltage pulse technology for drilling and cutting rocks, it is important to understand the fragmentation mechanism in rocks subjected to high-voltage discharge pulses to improve the effectiveness of drilling and cutting technologies. The process of drilling rocks using high-voltage discharge is employed because it generates electrical breakdown inside the rocks between the anode and cathode. In this study, seven rock types and a cement paste were electrically fractured using high-voltage pulse discharge to investigate their dielectric breakdown properties. The dielectric breakdown strengths of the samples were compared with their physical and mechanical properties. The samples with dielectric fractured were scanned using a high-resolution X-ray computed tomography system to observe the fracture formation associated with mineral constituents. The fracture patterns of the rock samples were analyzed using numerical simulation for high-voltage pulse-induced fragmentation that adopts the surface traction and internal body force conditions.

  8. Thermal Activation Analyses of Dynamic Fracture Toughness of High Strength Low Alloy Steels

    Institute of Scientific and Technical Information of China (English)

    2001-01-01

    A formula is derived for determining the influence of temperatureand loading rate on dynamic fracture toughness of a high strength low alloy steel (HQ785C) from thermal activation analysis of the experimental results of three-point bend specimens as well as introducing an Arrhenius formula. lt is shown that the results obtained by the given formula are in good agreement with the experimental ones in the thermal activation region. The present method is also valuable to describe the relationship between dynamic fracture toughness and temperature and loading rate of other high strength low alloy steels.

  9. Nonlinear conductive properties and scaling behavior of conductive particle filled high-density polyethylene composites

    Institute of Scientific and Technical Information of China (English)

    ZHENG Qiang; SHEN Lie; LI Wenchun; SONG Yihu; YI Xiaosu

    2005-01-01

    The blends prepared by incorporation of carbon black (CB) or graphite powder (GP) inHto high-density polyethylene (HDPE) matrix have been novel and extensively applied polymeric positive temperature coefficient (PTC) composites. A phenomenological model was proposed on the basis of the GEM equation and the dilution effect of filler volume fraction due to the thermal volume expansion of the polymer matrix. Accordingly, the contribution of the thermal expansion of the matrix to the jump-like PTC transition of the composites was quantitatively estimated and a mechanical explanation was given. It was proved that the contribution of the volume expansion to PTC effect decreased for HDPE/CB composites crosslinked through electron-beam irradiation. Furthermore, the influences of the filler content, temperature and crosslinking on the self-heating behavior as well as the nonlinear conduction characteristics at electrical-thermal equilibrium state were examined. Based on the electric-field and initial resistivity dependence of the self-heating temperature and resistance dependence of the critical field, the mechanisms of the self-heating of the polymeric PTC materials were evaluated. The intrinsic relations between macroscopic electrical properties and microscopic percolation network at electrical-thermal equilibrium state were discussed according to the scaling relationship between the self-heating critical parameter and the conductivity of materials.

  10. High pressure differential conductance measurements of (Pb,Sn)Se

    Science.gov (United States)

    Paul, Tiffany; Vangennep, Derrick; Jackson, Daniel; Biswas, Amlan; Hamlin, James

    Topological transitions have been recognized as a new type of quantum phase transition. Recently, a number of papers have reported scanning tunneling microscope (STM) measurements of the Landau level spectra of topologically non-trivial materials. Such measurements can offer substantial insight into the nature of the transition between topologically distinct phases. Although applied pressure represents an attractive means to drive a topological quantum phase transition, STM measurements can not be performed under high pressure conditions. In this talk, I will discuss our recent attempts to observe Landau level spectra in compressed (Pb,Sn)Se using differential conductance measurements. Acknowledgements: TAP supported by REU NSF DMR-1461019. Pressure cell development and measurements at high magnetic fields supported by the National High Magnetic Field Laboratory User Collaboration Grants Program. Synthesis, characterization, and high pressure measurements supported by NSF DMR-1453752.

  11. Conductive MOF electrodes for stable supercapacitors with high areal capacitance

    Science.gov (United States)

    Sheberla, Dennis; Bachman, John C.; Elias, Joseph S.; Sun, Cheng-Jun; Shao-Horn, Yang; Dincă, Mircea

    2016-10-01

    Owing to their high power density and superior cyclability relative to batteries, electrochemical double layer capacitors (EDLCs) have emerged as an important electrical energy storage technology that will play a critical role in the large-scale deployment of intermittent renewable energy sources, smart power grids, and electrical vehicles. Because the capacitance and charge-discharge rates of EDLCs scale with surface area and electrical conductivity, respectively, porous carbons such as activated carbon, carbon nanotubes and crosslinked or holey graphenes are used exclusively as the active electrode materials in EDLCs. One class of materials whose surface area far exceeds that of activated carbons, potentially allowing them to challenge the dominance of carbon electrodes in EDLCs, is metal-organic frameworks (MOFs). The high porosity of MOFs, however, is conventionally coupled to very poor electrical conductivity, which has thus far prevented the use of these materials as active electrodes in EDLCs. Here, we show that Ni3(2,3,6,7,10,11-hexaiminotriphenylene)2 (Ni3(HITP)2), a MOF with high electrical conductivity, can serve as the sole electrode material in an EDLC. This is the first example of a supercapacitor made entirely from neat MOFs as active materials, without conductive additives or other binders. The MOF-based device shows an areal capacitance that exceeds those of most carbon-based materials and capacity retention greater than 90% over 10,000 cycles, in line with commercial devices. Given the established structural and compositional tunability of MOFs, these results herald the advent of a new generation of supercapacitors whose active electrode materials can be tuned rationally, at the molecular level.

  12. Conductive MOF electrodes for stable supercapacitors with high areal capacitance

    Science.gov (United States)

    Sheberla, Dennis; Bachman, John C.; Elias, Joseph S.; Sun, Cheng-Jun; Shao-Horn, Yang; Dincă, Mircea

    2017-02-01

    Owing to their high power density and superior cyclability relative to batteries, electrochemical double layer capacitors (EDLCs) have emerged as an important electrical energy storage technology that will play a critical role in the large-scale deployment of intermittent renewable energy sources, smart power grids, and electrical vehicles. Because the capacitance and charge-discharge rates of EDLCs scale with surface area and electrical conductivity, respectively, porous carbons such as activated carbon, carbon nanotubes and crosslinked or holey graphenes are used exclusively as the active electrode materials in EDLCs. One class of materials whose surface area far exceeds that of activated carbons, potentially allowing them to challenge the dominance of carbon electrodes in EDLCs, is metal-organic frameworks (MOFs). The high porosity of MOFs, however, is conventionally coupled to very poor electrical conductivity, which has thus far prevented the use of these materials as active electrodes in EDLCs. Here, we show that Ni3(2,3,6,7,10,11-hexaiminotriphenylene)2 (Ni3(HITP)2), a MOF with high electrical conductivity, can serve as the sole electrode material in an EDLC. This is the first example of a supercapacitor made entirely from neat MOFs as active materials, without conductive additives or other binders. The MOF-based device shows an areal capacitance that exceeds those of most carbon-based materials and capacity retention greater than 90% over 10,000 cycles, in line with commercial devices. Given the established structural and compositional tunability of MOFs, these results herald the advent of a new generation of supercapacitors whose active electrode materials can be tuned rationally, at the molecular level.

  13. Highly conductive and thermally stable self-doping propylthiosulfonated polyanilines

    Institute of Scientific and Technical Information of China (English)

    Han Chien-Chung

    2004-01-01

    A new type of highly conductive self-doping polyaniline, MPS-Pan, containing a sulfonic acid moiety covalently bonded to the polymer backbone through an electron-donating propylthio linkage has been successfully prepared via a novel concurrent reduction and substitution route. At a similar self-doping level, the resultant MPS-Pans displayed much higher conductivity than the corresponding sulfonated-polyaniline (S-Pan). Furthermore, for fully doped samples, contrary to the trend of decreasing conductivity with the sulfonation degree in S-Pan, the conductivity of MPS-Pan was found to increase with its substitution degree. These results agreed with the expectation that electron-deficient charge carriers (e.g. semiquinone radical cations) on acid-doped polyaniline chains will be better stabilized by the electron-donating alkylthio-substituent. Surprisingly, TG and XPS studies showed that MPS-Pan was thermally much more stable than S-Pan, with S-Pan started to lose its sulfonic acid dopant at 185 ℃, while MPS-Pan remained intact up to ca. 260 ℃.

  14. High thermal conductivity of chain-oriented amorphous polythiophene.

    Science.gov (United States)

    Singh, Virendra; Bougher, Thomas L; Weathers, Annie; Cai, Ye; Bi, Kedong; Pettes, Michael T; McMenamin, Sally A; Lv, Wei; Resler, Daniel P; Gattuso, Todd R; Altman, David H; Sandhage, Kenneth H; Shi, Li; Henry, Asegun; Cola, Baratunde A

    2014-05-01

    Polymers are usually considered thermal insulators, because the amorphous arrangement of the molecular chains reduces the mean free path of heat-conducting phonons. The most common method to increase thermal conductivity is to draw polymeric fibres, which increases chain alignment and crystallinity, but creates a material that currently has limited thermal applications. Here we show that pure polythiophene nanofibres can have a thermal conductivity up to ∼ 4.4 W m(-1) K(-1) (more than 20 times higher than the bulk polymer value) while remaining amorphous. This enhancement results from significant molecular chain orientation along the fibre axis that is obtained during electropolymerization using nanoscale templates. Thermal conductivity data suggest that, unlike in drawn crystalline fibres, in our fibres the dominant phonon-scattering process at room temperature is still related to structural disorder. Using vertically aligned arrays of nanofibres, we demonstrate effective heat transfer at critical contacts in electronic devices operating under high-power conditions at 200 °C over numerous cycles.

  15. Fabrication of setup for high temperature thermal conductivity measurement

    Science.gov (United States)

    Patel, Ashutosh; Pandey, Sudhir K.

    2017-01-01

    In this work, we report the fabrication of an experimental setup for high temperature thermal conductivity (κ) measurement. It can characterize samples with various dimensions and shapes. Steady state based axial heat flow technique is used for κ measurement. Heat loss is measured using parallel thermal conductance technique. Simple design, lightweight, and small size sample holder is developed by using a thin heater and limited components. Low heat loss value is achieved by using very low thermal conductive insulator block with small cross-sectional area. Power delivered to the heater is measured accurately by using 4-wire technique and for this, the heater is developed with 4 wires. This setup is validated by using Bi0.36Sb1.45Te3, polycrystalline bismuth, gadolinium, and alumina samples. The data obtained for these samples are found to be in good agreement with the reported data. The maximum deviation of 6% in the value κ is observed. This maximum deviation is observed with the gadolinium sample. We also report the thermal conductivity of polycrystalline tellurium from 320 K to 550 K and the nonmonotonous behavior of κ with temperature is observed.

  16. Economic Recovery of Oil Trapped at Fan Margins Using High Angle Wells and Multiple Hydraulic Fractures

    Energy Technology Data Exchange (ETDEWEB)

    Mike L. Laue

    1997-05-30

    The distal fan margin in the northeast portion of the Yowlumne field contains significant reserves but is not economical to develop using vertical wells. Numerous interbedded shales and deteriorating rock properties limit producibility. In addition, extreme depths (13,000 ft) present a challenging environment for hydraulic fracturing and artificial lift. Lastly, a mature waterflood increases risk because of the uncertainty with size and location of flood fronts. This project attempts to demonstrate the effectiveness of exploiting the distal fan margin of this slope-basin clastic reservoir through the use of a high-angle well completed with multiple hydraulic-fracture treatments. The combination of a high-angle (or horizontal) well and hydraulic fracturing will allow greater pay exposure than can be achieved with conventional vertical wells while maintaining vertical communication between thin interbedded layers and the wellbore. The equivalent production rate and reserves of three vertical wells are anticipated at one-half to two-thirds the cost.

  17. The effect of hydrogen on strain hardening and fracture mechanism of high-nitrogen austenitic steel

    Science.gov (United States)

    Maier, G. G.; Astafurova, E. G.; Melnikov, E. V.; Moskvina, V. A.; Vojtsik, V. F.; Galchenko, N. K.; Zakharov, G. N.

    2016-07-01

    High-nitrogen austenitic steels are perspective materials for an electron-beam welding and for producing of wear-resistant coatings, which can be used for application in aggressive atmospheres. The tensile behavior and fracture mechanism of high-nitrogen austenitic steel Fe-20Cr-22Mn-1.5V-0.2C-0.6N (in wt.%) after electrochemical hydrogen charging for 2, 10 and 40 hours have been investigated. Hydrogenation of steel provides a loss of yield strength, uniform elongation and tensile strength. The degradation of tensile properties becomes stronger with increase in charging duration - it occurs more intensive in specimens hydrogenated for 40 hours as compared to ones charged for 2-10 hours. Fracture analysis reveals a hydrogen-induced formation of brittle surface layers up to 6 μm thick after 40 hours of saturation. Hydrogenation changes fracture mode of steel from mixed intergranular-transgranular to mainly transgranular one.

  18. Method and apparatus for connecting high voltage leads to a high temperature super-conducting transformer

    Science.gov (United States)

    Golner, Thomas M.; Mehta, Shirish P.

    2005-07-26

    A method and apparatus for connecting high voltage leads to a super-conducting transformer is provided that includes a first super-conducting coil set, a second super-conducting coil set, and a third super-conducting coil set. The first, second and third super-conducting coil sets are connected via an insulated interconnect system that includes insulated conductors and insulated connectors that are utilized to connect the first, second, and third super-conducting coil sets to the high voltage leads.

  19. Probabilistic fracture mechanics analysis for the life extension estimate of the high flux isotope reactor vessel

    Energy Technology Data Exchange (ETDEWEB)

    Chang, S.J.

    1997-05-01

    The state of the vessel steel embrittlement as a result of neutron irradiation can be measured by its increase in the nil ductility temperature (NDT). This temperature is sometimes referred to as the brittle-ductile transition temperature (DBT) for fracture. The life extension of the High Flux Isotope Reactor (HFIR) vessel is calculated by using the method of fracture mechanics. A new method of fracture probability calculation is presented in this paper. The fracture probability as a result of the hydrostatic pressure test (hydrotest) is used to determine the life of the vessel. The hydrotest is performed in order to determine a safe vessel static pressure. It is then followed by using fracture mechanics to project the safe reactor operation time from the time of the satisfactory hydrostatic test. The life extension calculation provides the following information on the remaining life of the reactor as a function of the NDT increase: (1) the life of the vessel is determined by the probability of vessel fracture as a result of hydrotest at several hydrotest pressures and vessel embrittlement conditions, (2) the hydrotest time interval vs the NDT increase rate, and (3) the hydrotest pressure vs the NDT increase rate. It is understood that the use of a complete range of uncertainties of the NDT increase is equivalent to the entire range of radiation damage that can be experienced by the vessel steel. From the numerical values for the probabilities of the vessel fracture as a result of hydrotest, it is estimated that the reactor vessel life can be extended up to 50 EFPY (100 MW) with the minimum vessel operating temperature equal to 85{degrees}F.

  20. Mechanical property determination of high conductivity metals and alloys

    Science.gov (United States)

    Harrod, D. L.; Vandergrift, E.; France, L.

    1973-01-01

    Pertinent mechanical properties of three high conductivity metals and alloys; namely, vacuum hot pressed grade S-200E beryllium, OFHC copper and beryllium-copper alloy no. 10 were determined. These materials were selected based on their possible use in rocket thrust chamber and nozzle hardware. They were procured in a form and condition similar to that which might be ordered for actual hardware fabrication. The mechanical properties measured include (1) tension and compression stress strain curves at constant strain rate (2) tensile and compressive creep, (3) tensile and compressive stress-relaxation behavior and (4) elastic properties. Tests were conducted over the temperature range of from 75 F to 1600 F. The resulting data is presented in both graphical and tabular form.

  1. Suppression of Electron Thermal Conduction in High $\\beta$ Plasma

    CERN Document Server

    Roberg-Clark, G T; Reynolds, C S; Swisdak, M

    2016-01-01

    Electron heat conduction is explored with particle-in-cell simulations and analytic modeling in a high $\\beta$ system relevant to galaxy clusters. Linear wave theory reveals that whistler waves are driven unstable by electron heat flux even when the heat flux is weak. The resonant interaction of electrons with these waves plays a critical role in controlling the impact of the waves on the heat flux. In a 1D model only electrons moving opposite in direction to the heat flux resonate with the waves and electron heat flux is only modestly reduced. In a 2D system transverse whistlers also resonate with electrons propagating in the direction of the heat flux and resonant overlap leads to strong suppression of electron heat flux. The results suggest that electron heat conduction might be strongly suppressed in galaxy clusters.

  2. Advanced Liquid-Cooling Garment Using Highly Thermally Conductive Sheets

    Science.gov (United States)

    Ruemmele, Warren P.; Bue, Grant C.; Orndoff, Evelyne; Tang, Henry

    2010-01-01

    This design of the liquid-cooling garment for NASA spacesuits allows the suit to remove metabolic heat from the human body more effectively, thereby increasing comfort and performance while reducing system mass. The garment is also more flexible, with fewer restrictions on body motion, and more effectively transfers thermal energy from the crewmember s body to the external cooling unit. This improves the garment s performance in terms of the maximum environment temperature in which it can keep a crewmember comfortable. The garment uses flexible, highly thermally conductive sheet material (such as graphite), coupled with cooling water lines of improved thermal conductivity to transfer the thermal energy from the body to the liquid cooling lines more effectively. The conductive sheets can be layered differently, depending upon the heat loads, in order to provide flexibility, exceptional in-plane heat transfer, and good through-plane heat transfer. A metal foil, most likely aluminum, can be put between the graphite sheets and the external heat source/sink in order to both maximize through-plane heat transfer at the contact points, and to serve as a protection to the highly conductive sheets. Use of a wicking layer draws excess sweat away from the crewmember s skin and the use of an outer elastic fabric ensures good thermal contact of the highly conductive underlayers with the skin. This allows the current state of the art to be improved by having cooling lines that can be more widely spaced to improve suit flexibility and to reduce weight. Also, cooling liquid does not have to be as cold to achieve the same level of cooling. Specific areas on the human body can easily be targeted for greater or lesser cooling to match human physiology, a warmer external environment can be tolerated, and spatial uniformity of the cooling garment can be improved to reduce vasoconstriction limits. Elements of this innovation can be applied to other embodiments to provide effective heat

  3. Flux-freezing breakdown in high-conductivity magnetohydrodynamic turbulence.

    Science.gov (United States)

    Eyink, Gregory; Vishniac, Ethan; Lalescu, Cristian; Aluie, Hussein; Kanov, Kalin; Bürger, Kai; Burns, Randal; Meneveau, Charles; Szalay, Alexander

    2013-05-23

    The idea of 'frozen-in' magnetic field lines for ideal plasmas is useful to explain diverse astrophysical phenomena, for example the shedding of excess angular momentum from protostars by twisting of field lines frozen into the interstellar medium. Frozen-in field lines, however, preclude the rapid changes in magnetic topology observed at high conductivities, as in solar flares. Microphysical plasma processes are a proposed explanation of the observed high rates, but it is an open question whether such processes can rapidly reconnect astrophysical flux structures much greater in extent than several thousand ion gyroradii. An alternative explanation is that turbulent Richardson advection brings field lines implosively together from distances far apart to separations of the order of gyroradii. Here we report an analysis of a simulation of magnetohydrodynamic turbulence at high conductivity that exhibits Richardson dispersion. This effect of advection in rough velocity fields, which appear non-differentiable in space, leads to line motions that are completely indeterministic or 'spontaneously stochastic', as predicted in analytical studies. The turbulent breakdown of standard flux freezing at scales greater than the ion gyroradius can explain fast reconnection of very large-scale flux structures, both observed (solar flares and coronal mass ejections) and predicted (the inner heliosheath, accretion disks, γ-ray bursts and so on). For laminar plasma flows with smooth velocity fields or for low turbulence intensity, stochastic flux freezing reduces to the usual frozen-in condition.

  4. Tensile deformation and fracture behavior of CuZn5 brass alloy at high temperature

    Energy Technology Data Exchange (ETDEWEB)

    Sharififar, M., E-mail: m.sharififar@ut.ac.ir; Akbari Mousavi, S.A.A., E-mail: akbarimusavi@ut.ac.ir

    2014-01-31

    Alpha brass alloys are widely used for production of rectangular waveguides because of their low bulk resistivity. In this paper, the microstructure, tensile deformation and fracture behavior of CuZn5 brass alloy were investigated. The strain rate sensitivity and its relation to post-uniform deformation in tensile test and correlation between strain hardening exponent (n) and temperature were examined. The results show that strain hardening exponent decreases from 0.5 to 0.4 with increase in test temperature from 250 to 450 °C. Tensile fracture mechanisms of as-extruded CuZn5 brass alloy were studied over a range of temperatures from 300 to 450 °C and range of strain rates from 0.01 to 0.4 1/s by means of scanning electron microscope (SEM) and Atomic Force Microscope (AFM). The results show that different fracture mechanisms operate in different temperature and strain rate ranges. While transgranular dimple fracture is dominant at 300 °C and 0.4 1/s, the dominant fracture mechanism at 450 °C and 0.01 1/s is cleavage facets. Precipitations and grain boundary sliding at high temperature may be the mechanism of ductility drop. Dynamic strain ageing (DSA) did not occur since none of the manifestations of DSA are observed.

  5. Fatigue Performance of Microalloyed High-strength Rebar and Analysis of Fracture Mechanism

    Institute of Scientific and Technical Information of China (English)

    Peng-yan LU; Yu LIU; Hua-jie WU; Gang LIU; Xiang MENG; Yang XU

    2015-01-01

    Fatigue performance of hot-rolled ribbed-steel bar with the yield strength of 500 MPa (HRB500)was stud-ied with bend-rotating fatigue test at a stress ratio of R=-1 .It is determined by staircase method that its fatigue strength for 107 cycles is 451 MPa,which is higher than that of common carbon structural steel.This should be at-tributed to the fine-grain strengthening resulting from the high content of alloy element V and Thermo-Mechanical Control Process (TMCP).The S-N curve function is also obtained by nonlinear regression with three parameters power function.The fatigue fractures of the specimen were further analyzed with Scanning Electron Microscopy (SEM)and Energy Disperse Spectroscopy (EDS)to study the fracture mechanism.Taking into account microstruc-ture,hardness and cleanliness of the material,it implies that the fatigue fractures of HRB500 rebar all arise from surface substrates in which many brittle inclusions are contained,and that the fatigue crack propagation is principally based on the mechanism of quasi-cleavage fracture,because of the intracrystalline hard spots leading to stress con-centration and thus to the cracks.Moreover,the transient breaking area exhibits microvoid coalescence of ductile fracture due to the existing abundant inclusions.

  6. Use of High-Speed X ray and Video to Analyze Distal Radius Fracture Pathomechanics.

    Science.gov (United States)

    Gutowski, Christina; Darvish, Kurosh; Liss, Frederic E; Ilyas, Asif M; Jones, Christopher M

    2015-10-01

    The purpose of this study is to investigate the failure sequence of the distal radius during a simulated fall onto an outstretched hand using cadaver forearms and high-speed X ray and video systems. This apparatus records the beginning and propagation of bony failure, ultimately resulting in distal radius or forearm fracture. The effects of 3 different wrist guard designs are investigated using this system. Serving as a proof-of-concept analysis, this study supports this imaging technique to be used in larger studies of orthopedic trauma and protective devices and specifically for distal radius fractures.

  7. A cold plasma plume with a highly conductive liquid electrode

    Institute of Scientific and Technical Information of China (English)

    Chen Guang-Liang; Chen Shi-gua; Chen Wen-Xing; Yang Si-Ze

    2008-01-01

    A cold dielectric barrier discharge (DBD) plasma plume with one highly conductive liquid electrode has been developed to treat thermally sensitive materials, and its preliminary discharging characteristics have been studied. The averaged electron temperature and density is estimated to be 0.6eV and 1011/cm3, respectively. The length of plasma plume can reach 5cm with helium gas (He), and the conductivity of the outer electrode affects the plume length obviously. This plasma plume could be touched by bare hand without causing any burning or painful sensation,which may provide potential application for safe aseptic skin care. Moreover, the oxidative particles (e.g., OH, O*03) in the downstream oxygen (02) gas of the plume have been applied to treat the landfill leachate. The results show that the activated 02 gas can degrade the landfill leachate effectively, and the chemical oxygen demand (COD),conductivity, biochemical oxygen demand (BOD), and suspended solid (SS) can be decreased by 52%, 57%, 76% and 92%, respectively.

  8. Fabrication of highly uniform conductive polypyrrole nanowires with DNA template.

    Science.gov (United States)

    Moon, Hock Key; Kim, Hyung Jin; Kim, Nam-Hoon; Roh, Yonghan

    2010-05-01

    Deoxyribonucleic acid (DNA) is considered as one of the alternative materials for electronic device applications; however, DNA has critical limitation to electronic device applications due to its low electrical conductivity and unreliability. Therefore, it is required for electronic devices to prepare the well defined conductive polymer nanowires with DNA as a template. Polypyrrole (PPy) is an attractive polymer due to its high conductivity and environmental stability in bulk; although it is well known that ammonium persulfate (APS) used for the polymerization of pyrrole causes the deformation of DNA molecules. We minimized the damage of immobilized DNA strands on (3-aminopropyl) triethoxysilane (APTES) modified silicon wafer during APS polymerization. Atomic force microscopy (AFM) images from different APS treatment times and from using the vortex process obviously showed the effect on the synthesis of individual and continuous polypyrrole nanowires (PPy NWs). The PPy NWs at various pyrrole concentrations had similar height; however, the higher concentration gave more residues. Fourier transform-infrared spectroscopy (FT-IR) spectroscopy provided the strong evidence that PPy NWs were successfully synthesized on the DNA strands.

  9. 1300 MPa High Strength Steel for Bolt with Superior Delayed Fracture Resistance

    Institute of Scientific and Technical Information of China (English)

    2002-01-01

    By the increase in Mo content, the addition of microalloying elements V and Nb and by reducing the contents of Mn, P and S based on the composition of steel 42CrMo, we have developed a 1300 MPa-grade high strength steel (ADF1) for bolts. The sustained load bending test, sustained load tensile test and stress corrosion cracking test have been carried out to evaluate the delayed fracture resistance of steel ADF1 and commercial steel 42CrMo. The results showed that steel ADF1 has superior delayed fracture resistance to that of 42CrMo steel. It's concluded that the superior delayed fracture resistance of ADF1 is mainly due to the increase of tempering temperature, fine homogeneously distributed MC carbide and fine prior austenite grain size.

  10. Delayed Fracture Resistance and Mechanical Properties of 30MnSi High Strength Steel

    Institute of Scientific and Technical Information of China (English)

    XIAO Gui-zhi; DI Hong-shuang

    2009-01-01

    To investigate the effect of heat treatment on mechanical properties and delayed fracture resistance of high strength steel,30MnSi prestressed concrete (PC) steel bars are quenched and tempered.Tensile results show that,after 950 ℃ quenching and about 430 ℃ tempering,30MnSi PC steel bars have superior mechanical properties and delayed fracture resistance.Microstructursl observation shows that 30MnSi steel bar is mainly composed of fine tempered sorbite (troostite) with carbide distributed along the lath martensite boundaries.It can be concluded that thermal refining is an effective way to improve mechanical properties and delayed fracture resistance of 30MnSi PC steel bar.

  11. Fracture problem of a nonhomogeneous high temperature superconductor slab based on real fundamental solutions

    Science.gov (United States)

    Gao, Zhiwen; Zheng, Zhiye; Li, Xueyi

    2015-12-01

    To analyze the fracture problem of the nonhomogeneous high temperature superconductor (HTS) slab under electromagnetic force, we derive the real fundamental solutions based on eigenvalue and eigenvector analyses. The superconductor E-J constitutive law is characterized by the Bean model where the critical current density is independent of the flux density. Fracture analysis is performed by the methods of singular integral equations which are solved numerically by Lobatto-Chybeshev collocation method. Numerical results of the stress intensity factor (SIF) are obtained. Moreover, the crack opening displacement (COD) can be obtained by numerical integration dislocation density functions. The effects of the thickness ratio, HTS material nonhomogeneous parameters, applied magnetic field and critical current density on SIF and COD are discussed. The present work could theoretically provide quantitative predictions of the fracture mechanism of the nonhomogeneous HTS.

  12. Unusually High and Anisotropic Thermal Conductivity in Amorphous Silicon Nanostructures.

    Science.gov (United States)

    Kwon, Soonshin; Zheng, Jianlin; Wingert, Matthew C; Cui, Shuang; Chen, Renkun

    2017-03-28

    Amorphous Si (a-Si) nanostructures are ubiquitous in numerous electronic and optoelectronic devices. Amorphous materials are considered to possess the lower limit to the thermal conductivity (κ), which is ∼1 W·m(-1) K(-1) for a-Si. However, recent work suggested that κ of micrometer-thick a-Si films can be greater than 3 W·m(-1) K(-1), which is contributed to by propagating vibrational modes, referred to as "propagons". However, precise determination of κ in a-Si has been elusive. Here, we used structures of a-Si nanotubes and suspended a-Si films that enabled precise in-plane thermal conductivity (κ∥) measurement within a wide thickness range of 5 nm to 1.7 μm. We showed unexpectedly high κ∥ in a-Si nanostructures, reaching ∼3.0 and 5.3 W·m(-1) K(-1) at ∼100 nm and 1.7 μm, respectively. Furthermore, the measured κ∥ is significantly higher than the cross-plane κ on the same films. This unusually high and anisotropic thermal conductivity in the amorphous Si nanostructure manifests the surprisingly broad propagon mean free path distribution, which is found to range from 10 nm to 10 μm, in the disordered and atomically isotropic structure. This result provides an unambiguous answer to the century-old problem regarding mean free path distribution of propagons and also sheds light on the design and performance of numerous a-Si based electronic and optoelectronic devices.

  13. Conducting polymer nanofibers for high sensitivity detection of chemical analytes.

    Science.gov (United States)

    Kumar, Abhishek; Leshchiner, Ignaty; Nagarajan, Subhalakshmi; Nagarajan, Ramaswamy; Kumar, Jayant

    2008-03-01

    Possessing large surface area materials is vital for high sensitivity detection of analyte. We report a novel, inexpensive and simple technique to make high surface area sensing interfaces using electrospinning. Conducting polymers (CP) nanotubes were made by electrospinning a solution of a catalyst (ferric tosylate) along with poly (lactic acid), which is an environment friendly biodegradable polymer. Further vapor deposition polymerization of the monomer ethylenedioxy thiophene (EDOT) on the nanofiber surface yielded poly (EDOT) covered fibers. X-ray photo electron spectroscopy (XPS) study reveals the presence of PEDOT predominantly on the surface of nanofibers. Conducting nanotubes had been received by dissolving the polymer in the fiber core. By a similar technique we had covalently incorporated fluorescent dyes on the nanofiber surface. The materials obtained show promise as efficient sensing elements. UV-Vis characterization confirms the formation of PEDOT nanotubes and incorporation of chromophores on the fiber surface. The morphological characterization was carried out using scanning electron microscopy (SEM) and transmission electron microscopy (TEM).

  14. High pressure gas flow, storage, and displacement in fractured rock-Experimental setup development and application.

    Science.gov (United States)

    Hadi Mosleh, M; Turner, M; Sedighi, M; Vardon, P J

    2017-01-01

    This paper presents the design, development, and application of a laboratory setup for the experimental investigations of gas flow and reactions in a fractured rock. The laboratory facility comprises (i) a high pressure manometric sorption apparatus, where equilibrium and kinetic phenomena of adsorption and desorption can be examined, (ii) a high pressure triaxial core flooding system where the chemical reactive transport properties or processes can be explored, and (iii) an ancillary system including pure and mixed gas supply and analysis units. Underground conditions, in terms of pore pressure, confining pressure, and temperature, can be replicated using the triaxial core flooding system developed for depths up to 2 km. Core flooding experiments can be conducted under a range of gas injection pressures up to 20 MPa and temperatures up to 338 K. Details of the design considerations and the specification for the critical measuring instruments are described. The newly developed laboratory facility has been applied to study the adsorption of N2, CH4, and CO2 relevant to applications in carbon sequestration in coal and enhanced coalbed methane recovery. Under a wide range of pressures, the flow of helium in a core sample was studied and the evolution of absolute permeability at different effective stress conditions has been investigated. A comprehensive set of high resolution data has been produced on anthracite coal samples from the South Wales coalfield, using the developed apparatus. The results of the applications provide improved insight into the high pressure flow and reaction of various gas species in the coal samples from the South Wales coalfield.

  15. High pressure gas flow, storage, and displacement in fractured rock—Experimental setup development and application

    Science.gov (United States)

    Hadi Mosleh, M.; Turner, M.; Sedighi, M.; Vardon, P. J.

    2017-01-01

    This paper presents the design, development, and application of a laboratory setup for the experimental investigations of gas flow and reactions in a fractured rock. The laboratory facility comprises (i) a high pressure manometric sorption apparatus, where equilibrium and kinetic phenomena of adsorption and desorption can be examined, (ii) a high pressure triaxial core flooding system where the chemical reactive transport properties or processes can be explored, and (iii) an ancillary system including pure and mixed gas supply and analysis units. Underground conditions, in terms of pore pressure, confining pressure, and temperature, can be replicated using the triaxial core flooding system developed for depths up to 2 km. Core flooding experiments can be conducted under a range of gas injection pressures up to 20 MPa and temperatures up to 338 K. Details of the design considerations and the specification for the critical measuring instruments are described. The newly developed laboratory facility has been applied to study the adsorption of N2, CH4, and CO2 relevant to applications in carbon sequestration in coal and enhanced coalbed methane recovery. Under a wide range of pressures, the flow of helium in a core sample was studied and the evolution of absolute permeability at different effective stress conditions has been investigated. A comprehensive set of high resolution data has been produced on anthracite coal samples from the South Wales coalfield, using the developed apparatus. The results of the applications provide improved insight into the high pressure flow and reaction of various gas species in the coal samples from the South Wales coalfield.

  16. Theory and application of rock burst prevention using deep hole high pressure hydraulic fracturing

    Institute of Scientific and Technical Information of China (English)

    Shan-Kun ZHAO; Jun LIU; Xiang-Zhi WEI; Chuan-Hong DING; Yu-Lei LV; Gang-Feng LI

    2013-01-01

    In order to analyze the mechanism of deep hole high pressure hydraulic fracturing,nonlinear dynamic theory,damage mechanics,elastic-plastic mechanics are used,and the law of crack propagation and stress transfer under two deep hole hydraulic fracturing in tectonic stress areas is studied using seepage-stress coupling models with RFPA simulation software.In addition,the effects of rock burst control are tested using multiple methods,either in the stress field or in the energy field.The research findings show that with two deep holes hydraulic fracturing in tectonic stress areas,the direction of the main crack propagation under shear-tensile stress is parallel to the greatest principal stress direction.High-pressure hydraulic fracturing water seepage can result in the destruction of the coal structure,while also weakening the physical and mechanical properties of coal and rock.Therefore the impact of high stress concentration in hazardous areas will level off,which has an effect on rock burst prevention and control in the region.

  17. Measurement of field-saturated hydraulic conductivity on fractured rock outcrops near Altamura (Southern Italy) with an adjustable large ring infiltrometer

    Science.gov (United States)

    Caputo, M.C.; de Carlo, L.; Masciopinto, C.; Nimmo, J.R.

    2010-01-01

    Up to now, field studies set up to measure field-saturated hydraulic conductivity to evaluate contamination risks, have employed small cylinders that may not be representative of the scale of measurements in heterogeneous media. In this study, a large adjustable ring infiltrometer was designed to be installed on-site directly on rock to measure its field-saturated hydraulic conductivity. The proposed device is inexpensive and simple to implement, yet also very versatile, due to its large adjustable diameter that can be fixed on-site. It thus allows an improved representation of the natural system's heterogeneity, while also taking into consideration irregularities in the soil/rock surface. The new apparatus was tested on an outcrop of karstic fractured limestone overlying the deep Murge aquifer in the South of Italy, which has recently been affected by untreated sludge disposal, derived from municipal and industrial wastewater treatment plants. The quasi-steady vertical flow into the unsaturated fractures was investigated by measuring water levels during infiltrometer tests. Simultaneously, subsurface electrical resistivity measurements were used to visualize the infiltration of water in the subsoil, due to unsaturated water flow in the fractures. The proposed experimental apparatus works well on rock outcrops, and allows the repetition of infiltration tests at many locations in order to reduce model uncertainties in heterogeneous media. ?? 2009 Springer-Verlag.

  18. Sports fractures.

    OpenAIRE

    DeCoster, T. A.; Stevens, M. A.; Albright, J. P.

    1994-01-01

    Fractures occur in athletes and dramatically influence performance during competitive and recreational activities. Fractures occur in athletes as the result of repetitive stress, acute sports-related trauma and trauma outside of athletics. The literature provides general guidelines for treatment as well as a variety of statistics on the epidemiology of fractures by sport and level of participation. Athletes are healthy and motivated patients, and have high expectations regarding their level o...

  19. Design of a conductivity meter for highly insulating liquids

    Energy Technology Data Exchange (ETDEWEB)

    Medrano, M; Perez, A T; Soria-Hoyo, C [Dep. Electronica y Electromagnetismo, Facultad de Fisica, Universidad de Sevilla, Avda. Reina Mercedes s/n, 41012 Sevilla (Spain)

    2007-03-07

    The accurate measurement of the electrical conductivity of low conducting liquids is an important issue in many industrial applications. The lack of repeatability is a common problem to the available procedures and commercial techniques. In this paper, we present a device to measure the electrical conductivity of low conducting liquids. The variable inter-electrode gap allows us to assure the existence of an ohmic regime, since only under ohmic regime conditions is the value of the conductivity meaningful.

  20. Stable high conductivity ceria/bismuth oxide bilayered electrolytes

    Energy Technology Data Exchange (ETDEWEB)

    Wachsman, E.D.; Jayaweera, P.; Jiang, N.; Lowe, D.M.; Pound, B.G. [SRI international, Menlo Park, CA (United States). Materials Research Center

    1997-01-01

    The authors have developed a high conductivity bilayered ceria/bismuth oxide anolyte/electrolyte that uses the Po{sub 2} gradient to obtain stability at the anolyte-electrolyte interface and reduced electronic conduction due to the electrolyte region. Results in terms of solid oxide fuel cell (SOFC) performance and stability are presented. These results include a 90 to 160 mV increase in open-circuit potential, depending on temperature, with the bilayered structure as compared to SOFCs fabricated from a single ceria layer. An open-circuit potential of >1.0 V was obtained at 500 C with the bilayered structure. This increase in open-circuit potential is obtained without any measurable increase in cell resistance and is stable for over 1,400 h of testing, under both open-circuit and maximum power conditions. Moreover, SOFCs fabricated from the bilayered structure result in a 33% greater power density as compared to cells with a single ceria electrolyte layer.

  1. Thermal Conductance Engineering for High-Speed TES Microcalorimeters

    Science.gov (United States)

    Hays-Wehle, J. P.; Schmidt, D. R.; Ullom, J. N.; Swetz, D. S.

    2016-07-01

    Many current and future applications for superconducting transition-edge sensor (TES) microcalorimeters require significantly faster pulse response than is currently available. X-ray spectroscopy experiments at next-generation synchrotron light sources need to successfully capture very large fluxes of photons, while detectors at free-electron laser facilities need pulse response fast enough to match repetition rates of the source. Additionally, neutrino endpoint experiments such as HOLMES need enormous statistics, yet are extremely sensitive to pile-up effects that can distort spectra. These issues can be mitigated only by fast rising and falling edges. To address these needs, we have designed high-speed TES detectors with novel geometric enhancements to increase the thermal conductance of pixels suspended on silicon nitride membranes. This paper shows that the thermal conductivity can be precisely engineered to values spanning over an order of magnitude to achieve fast thermal relaxation times tailored to the relevant applications. Using these pixel prototypes, we demonstrate decay time constants faster than 100 μ s, while still maintaining spectral resolution of 3 eV FWHM at 1.5 keV. This paper also discusses the trade-offs inherent in reducing the pixel time constant, such as increased bias current leading to degradation in energy resolution, and potential modifications to improve performance.

  2. Variable amplitude corrosion fatigue and fracture mechanics of weldable high strength jack-up steels

    Science.gov (United States)

    Etube, Linus Sone

    The tubular welded joints used in the construction of Offshore structures can experience millions of variable amplitude wave induced stress cycles during their operational life. Fatigue has been identified as the main cause of degradation of structural integrity in these structures. As a result, fatigue is an important consideration in their design. Jack-up legs are made from a range of high strength steels with yield strengths up to TOOMPa. These steels are thought to exhibit fatigue resistance properties which are different when compared with conventional fixed platform steels such as BS 4360 50D and BS 7191 355D. The difference in their behaviour was heightened by the discovery, in the late 80s and early 90s, of extensive cracking around the spud can regions of several Jack-ups operating in the North Sea. It was thought that these steels may be more susceptible to hydrogen cracking and embrittlement. There was the additional requirement to study their behaviour under realistic loading conditions typical of the North Sea environment. This thesis contains results of an investigation undertaken to assess the performance of a typical high strength weldable Jack-up steel under realistic loading and environmental conditions. Details of the methodology employed to develop a typical Jack-up Offshore Standard load History (JOSH) are presented. The factors which influence fatigue resistance of structural steels used in the construction of Jack-up structures are highlighted. The methods used to model the relevant factors for inclusion in JOSH are presented with particular emphasis on loading and structural response interaction. Results and details of experimental variable amplitude corrosion fatigue (VACF) tests conducted using JOSH are reported and discussed with respect to crack growth mechanisms in high strength weldable Jack-up steels. Different fracture mechanics models for VACF crack growth prediction are compared and an improved generalised methodology for fast

  3. Treatment of open tibial fracture with bone defect caused by high velocity missiles: a case report.

    Science.gov (United States)

    Golubović, Zoran; Vukajinović, Zoran; Stojiljković, Predrag; Golubović, Ivan; Visnjić, Aleksandar; Radovanović, Zoran; Najman, Stevo

    2013-01-01

    Tibia fracture caused by high velocity missiles is mostly comminuted and followed by bone defect which makes their healing process extremely difficult and prone to numerous complications. A 34-year-old male was wounded at close range by a semi-automatic gun missile. He was wounded in the distal area of the left tibia and suffered a massive defect of the bone and soft tissue. After the primary treatment of the wound, the fracture was stabilized with an external fixator type Mitkovic, with convergent orientation of the pins. The wound in the medial region of the tibia was closed with the secondary stitch, whereas the wound in the lateral area was closed with the skin transplant after Thiersch. Due to massive bone defect in the area of the rifle-missile wound six months after injury, a medical team placed a reconstructive external skeletal fixator type Mitkovic and performed corticotomy in the proximal metaphyseal area of the tibia. By the method of bone transport (distractive osteogenesis), the bone defect of the tibia was replaced. After the fracture healing seven months from the secondary surgery, the fixator was removed and the patient was referred to physical therapy. Surgical treatment of wounds, external fixation, performing necessary debridement, adequate antibiotic treatment and soft and bone tissue reconstruction are essential in achieving good results in patients with the open tibial fracture with bone defect caused by high velocity missiles. Reconstruction of bone defect can be successfully treated by reconstructive external fixator Mitkovic.

  4. High frequency conductivity of hot electrons in carbon nanotubes

    Energy Technology Data Exchange (ETDEWEB)

    Amekpewu, M., E-mail: mamek219@gmail.com [Department of Applied Physics, University for Development Studies, Navrongo (Ghana); Mensah, S.Y. [Department of Physics, College of Agriculture and Natural Sciences, U.C.C. (Ghana); Musah, R. [Department of Applied Physics, University for Development Studies, Navrongo (Ghana); Mensah, N.G. [Department of Mathematics, College of Agriculture and Natural Sciences, U.C.C. (Ghana); Abukari, S.S.; Dompreh, K.A. [Department of Physics, College of Agriculture and Natural Sciences, U.C.C. (Ghana)

    2016-05-01

    High frequency conductivity of hot electrons in undoped single walled achiral Carbon Nanotubes (CNTs) under the influence of ac–dc driven fields was considered. We investigated semi-classically Boltzmann's transport equation with and without the presence of the hot electrons’ source by deriving the current densities in CNTs. Plots of the normalized current density versus frequency of ac-field revealed an increase in both the minimum and maximum peaks of normalized current density at lower frequencies as a result of a strong injection of hot electrons. The applied ac-field plays a twofold role of suppressing the space-charge instability in CNTs and simultaneously pumping an energy for lower frequency generation and amplification of THz radiations. These have enormous promising applications in very different areas of science and technology.

  5. High frequency conductivity of hot electrons in carbon nanotubes

    Science.gov (United States)

    Amekpewu, M.; Mensah, S. Y.; Musah, R.; Mensah, N. G.; Abukari, S. S.; Dompreh, K. A.

    2016-05-01

    High frequency conductivity of hot electrons in undoped single walled achiral Carbon Nanotubes (CNTs) under the influence of ac-dc driven fields was considered. We investigated semi-classically Boltzmann's transport equation with and without the presence of the hot electrons' source by deriving the current densities in CNTs. Plots of the normalized current density versus frequency of ac-field revealed an increase in both the minimum and maximum peaks of normalized current density at lower frequencies as a result of a strong injection of hot electrons. The applied ac-field plays a twofold role of suppressing the space-charge instability in CNTs and simultaneously pumping an energy for lower frequency generation and amplification of THz radiations. These have enormous promising applications in very different areas of science and technology.

  6. High thermal conductivity of a hydrogenated amorphous silicon film.

    Science.gov (United States)

    Liu, Xiao; Feldman, J L; Cahill, D G; Crandall, R S; Bernstein, N; Photiadis, D M; Mehl, M J; Papaconstantopoulos, D A

    2009-01-23

    We measured the thermal conductivity kappa of an 80 microm thick hydrogenated amorphous silicon film prepared by hot-wire chemical-vapor deposition with the 3omega (80-300 K) and the time-domain thermo-reflectance (300 K) methods. The kappa is higher than any of the previous temperature dependent measurements and shows a strong phonon mean free path dependence. We also applied a Kubo based theory using a tight-binding method on three 1000 atom continuous random network models. The theory gives higher kappa for more ordered models, but not high enough to explain our results, even after extrapolating to lower frequencies with a Boltzmann approach. Our results show that this material is more ordered than any amorphous silicon previously studied.

  7. Avoiding vacuum arcs in high gradient normal conducting RF structures

    CERN Document Server

    Sjøbæk, Kyrre Ness; Adli, Erik; Grudiev, Alexej; Wuensch, Walter

    In order to build the Compact LInear Collider (CLIC), accelerating structures reaching extremely high accelerating gradients are needed. Such structures have been built and tested using normal-conducting copper, powered by X-band RF power and reaching gradients of 100 MV/m and above. One phenomenon that must be avoided in order to reliably reach such gradients, is vacuum arcs or “breakdowns”. This can be accomplished by carefully designing the structure geometry such that high surface fields and large local power flows are avoided. The research presented in this thesis presents a method for optimizing the geometry of accelerating structures so that these breakdowns are made less likely, allowing the structure to operate reliably at high gradients. This was done primarily based on a phenomenological scaling model, which predicted the maximum gradient as a function of the break down rate, pulse length, and field distribution in the structure. The model is written in such a way that it allows direct comparis...

  8. Fractures of modern high nitrogen stainless steel cemented stems: cause, mechanism, and avoidance in 14 cases.

    Science.gov (United States)

    Yates, Piers J; Quraishi, Nasir A; Kop, Allan; Howie, Donald W; Marx, Clare; Swarts, Eric

    2008-02-01

    We present 14 cases of fracture of modern, high-nitrogen, stainless steel stems. Our clinical and radiological data suggest that heavy patients with small stems and poor proximal support are at risk for fracturing their implants. "Champagne-glass" canals can lead to the use of smaller stems often placed in varus, which can lead to cantilever bending and fatigue failure in the distal half of the stem. Metallurgical assessment of the retrieved high-nitrogen, stainless steel stems reveals microstructural inconsistencies that may contribute to their failure. Based on our findings, careful consideration and attention to technique is required when using stainless steel stems in patients with high body mass index or high weight. Technique is particularly important in femurs with champagne-glass canals.

  9. Evolution of the fracture process zone in high-strength concrete under different loading rates

    Directory of Open Access Journals (Sweden)

    Cámara M.

    2010-06-01

    Full Text Available For cementitious materials, the inelastic zone around a crack tip is termed as fracture process zone (FPZ and dominated by complicated mechanism, such as microcracking, crack deflection, bridging, crack face friction, crack tip blunting by voids, crack branching, and so on. Due to the length of the FPZ is related with the characteristic length of the cementitious materials, the size, extent and location of the FPZ has been the object of countless research efforts for several decades. For instance, Cedolin et al. [1] have used an optical method based on the moiré interferometry to determine FPZ in concrete. Castro-Montero et al. [2] have applied the method of holographic interferometry to mortar to study the extension of the FPZ. The advantage of the interferometry method is that the complete FPZ can be directly observed on the surface of the sample. Swartz et al. [3] has adopted the dye penetration technique to illustrate the changing patterns observed as the crack progress from the tensile side to the compression side of the beam. Moreover, acoustic emission (AE is also an experimental technique well suited for monitoring fracture process. Haidar et al. [4] and Maji et al. [5] have studied the relation between acoustic emission characteristics and the properties of the FPZ. Compared with the extensive research on properties of the FPZ under quasi-static loading conditions, much less information is available on its dynamic characterization, especially for high-strength concrete (HSC. This paper presents the very recent results of an experimental program aimed at disclosing the loading rate effect on the size and velocity of the (FPZ in HSC. Eighteen three-point bending specimens were conducted under a wide range of loading rates from from 10-4 mm/s to 103 mm/s using either a servo-hydraulic machine or a self-designed drop-weight impact device. The beam dimensions were 100 mm 100 mm in cross section, and 420 mm in length. The initial notch

  10. Preparation and investigation of ultrafine-grained tungsten carbide with high hardness and fracture toughness

    Science.gov (United States)

    Chuvil'deev, V. N.; Blagoveshchenskii, Yu. V.; Sakharov, N. V.; Boldin, M. S.; Nokhrin, A. V.; Isaeva, N. V.; Shotin, S. V.; Lopatin, Yu. G.; Smirnova, E. S.

    2015-07-01

    High-density samples of ultrafine-grained tungsten carbide with high hardness (up to 31-34 GPa) and increased fracture toughness (up to 5.2-6.4 MPa m1/2) are obtained using the technology of electropulse plasma sintering. The influence of the initial size of nanoparticles of α-WC prepared by plasmachemical synthesis on the density, structural parameters, and mechanical properties of tungsten carbide is investigated.

  11. Survival and Functional Outcomes after Hip Fracture among Nursing Home Residents

    National Research Council Canada - National Science Library

    Cho, Hong Man; Lee, Kyujung; Min, Woongbae; Choi, Yong Suk; Lee, Hyun Suk; Mun, Hyoung Jin; Shim, Hye Young; Lee, Da Geon; Yoo, Mi Joung

    2016-01-01

    .... Despite the fact that this is a high-risk group vulnerable to hip fractures, no study has yet been conducted in Korea on hip fracture incidence rates and prognoses among patients residing at nursing homes...

  12. Toward nanofluids of ultra-high thermal conductivity.

    Science.gov (United States)

    Wang, Liqiu; Fan, Jing

    2011-02-18

    The assessment of proposed origins for thermal conductivity enhancement in nanofluids signifies the importance of particle morphology and coupled transport in determining nanofluid heat conduction and thermal conductivity. The success of developing nanofluids of superior conductivity depends thus very much on our understanding and manipulation of the morphology and the coupled transport. Nanofluids with conductivity of upper Hashin-Shtrikman (H-S) bound can be obtained by manipulating particles into an interconnected configuration that disperses the base fluid and thus significantly enhancing the particle-fluid interfacial energy transport. Nanofluids with conductivity higher than the upper H-S bound could also be developed by manipulating the coupled transport among various transport processes, and thus the nature of heat conduction in nanofluids. While the direct contributions of ordered liquid layer and particle Brownian motion to the nanofluid conductivity are negligible, their indirect effects can be significant via their influence on the particle morphology and/or the coupled transport.

  13. Simultaneous bilateral fractures of the femoral neck caused by high energy:A case report and literature review

    Institute of Scientific and Technical Information of China (English)

    You-Shui Gao; Zhen-Hong Zhu; Chang-Qing Zhang

    2015-01-01

    Simultaneous bilateral fractures of the femoral neck are rare injuries,which are reportedly induced by low-speed energy with predisposing factors including systemic diseases,medications and eclamptic seizures.Those caused by high energy are even rarer.High energy-induced bilateral fractures of the femoral neck conceive of high incidence of mortality and present great challenges in the early management.We report one case of a 52-year-old man with simultaneous bilateral fractures of the femoral neck which resulted from a motor pedestrian accident.One-stage closed reduction and internal fixation was done following the emergent resuscitation and neurosurgical management for concomitant brain injuries.The fractures united.There was no pain in the hips,and they had a normal range of motion.The treatment protocol,mechanism of the injury and possible postoperative complications were discussed to expand a comprehensive understanding about these infrequent types of fractures.

  14. Highly Transparent Conducting Nanopaper for Solid State Foldable Electrochromic Devices.

    Science.gov (United States)

    Kang, Wenbin; Lin, Meng-Fang; Chen, Jingwei; Lee, Pooi See

    2016-12-01

    It is of great challenge to develop a transparent solid state electrochromic device which is foldable at the device level. Such devices require delicate designs of every component to meet the stringent requirements for transparency, foldability, and deformation stability. Meanwhile, nanocellulose, a ubiquitous natural resource, is attracting escalating attention recently for foldable electronics due to its extreme flexibility, excellent mechanical strength, and outstanding transparency. In this article, transparent conductive nanopaper delivering the state-of-the-art electro-optical performance is achieved with a versatile nanopaper transfer method that facilitates junction fusing for high-quality electrodes. The highly compliant nanopaper electrode with excellent electrode quality, foldability, and mechanical robustness suits well for the solid state electrochromic device that maintains good performance through repeated folding, which is impossible for conventional flexible electrodes. A concept of camouflage wearables is demonstrated using gloves with embedded electrochromics. The discussed strategies here for foldable electrochromics serve as a platform technology for futuristic deformable electronics. © 2016 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

  15. Highly Electrically Conducting Glass-Graphene Nanoplatelets Hybrid Coatings.

    Science.gov (United States)

    Garcia, E; Nistal, A; Khalifa, A; Essa, Y; Martín de la Escalera, F; Osendi, M I; Miranzo, P

    2015-08-19

    Hybrid coatings consisting of a heat resistant Y2O3-Al2O3-SiO2 (YAS) glass containing 2.3 wt % of graphene nanoplatelets (GNPs) were developed by flame spraying homogeneous ceramic powders-GNP granules. Around 40% of the GNPs survived the high spraying temperatures and were distributed along the splat-interfaces, forming a percolated network. These YAS-GNP coatings are potentially interesting in thermal protection systems and electromagnetic interference shields for aerospace applications; therefore silicon carbide (SiC) materials at the forefront of those applications were employed as substrates. Whereas the YAS coatings are nonconductive, the YAS-GNP coatings showed in-plane electrical conductivity (∼10(2) S·m(-1)) for which a low percolation limit (below 3.6 vol %) is inferred. Indentation tests revealed the formation of a highly damaged indentation zone showing multiple shear displacements between adjacent splats probably favored by the graphene sheets location. The indentation radial cracks typically found in brittle glass coatings are not detected in the hybrid coatings that are also more compliant.

  16. High-power laser shock-induced dynamic fracture of aluminum and microscopic observation of samples

    Directory of Open Access Journals (Sweden)

    Fan Zhang

    2015-01-01

    Full Text Available High-power laser induced shocks generated by “ShenGuang II” laser facility has been used to study spall fracture of polycrystalline aluminum at strain rates more than 106/s. The free surface velocity histories of shock-loaded samples, 150 μm thick and with initial temperature from 293 K to 873 K, have been recorded using velocity interferometer system for any reflector (VISAR. From the free surface velocity profile, spall strength and yield stress are calculated, it demonstrates that spall strength will decline and yield strength increase with initial temperature. The loaded samples are recovered to obtain samples' section and free surface metallographic pictures through Laser Scanning Confocal Microscopy. It is found that there are more micro-voids and more opportunity to appear bigger voids near the spall plane and the grain size increases with temperature slowly but smoothly except the sharply change at 893 K (near melting point. Besides, the fracture mechanisms change from mainly intergranular fracture to transgranular fracture with the increase of initial temperature.

  17. Delayed Fracture Behavior of CrMo-Type High Strength Steel Containing Titanium

    Institute of Scientific and Technical Information of China (English)

    HUI Wei-jun; DONG Han; WENG Yu-qing; WANG Mao-qiu; CHEN Si-lian; SHI Jie

    2005-01-01

    The delayed fracture behaviors of CrMo-type high strength steels containing different amount of titanium (0 to 0. 10%) were studied. The steels were quenched at 880 ℃ and tempered from 400 ℃ to 650 ℃, and a wide range of tensile strength was obtained. The sustained load tensile test was carried out by using notched tensile specimens in Walpole solution. The experimental results showed that with higher strength, the Ti-microalloyed steels show higher resistance to delayed fracture compared with non-microalloyed steel due to titanium beneficial role and microstructure changes. The undissolved TiC is uniformly distributed as strong hydrogen traps, retarding or preventing the diffusion and accumulation of hydrogen to lower-interaction energy sites, such as prior austenite and martensite lath boundaries in stress concentration area. Meanwhile, the grain refining effect of titanium is also an important factor to improve the delayed fracture resistance of Ti-microalloyed steels. The characteristics of delayed fracture remain nearly the same with titanium addition.

  18. Fracture problem of a nonhomogeneous high temperature superconductor slab based on real fundamental solutions

    Energy Technology Data Exchange (ETDEWEB)

    Gao, Zhiwen, E-mail: gaozhw@lzu.edu.cn; Zheng, Zhiye; Li, Xueyi

    2015-12-15

    Highlights: • We studied firstly nonhomogeneity fracture in HTS base on real fundamental solutions. • The SIF of nonhomogeneity HTS decrease with nonhomogeneity parameters increasing. • The greater the applied field, the higher the SIF value. • The greater critical current density of the nonhomogeneity HTS is, the smaller values of the SIF. - Abstract: To analyze the fracture problem of the nonhomogeneous high temperature superconductor (HTS) slab under electromagnetic force, we derive the real fundamental solutions based on eigenvalue and eigenvector analyses. The superconductor E-J constitutive law is characterized by the Bean model where the critical current density is independent of the flux density. Fracture analysis is performed by the methods of singular integral equations which are solved numerically by Lobatto–Chybeshev collocation method. Numerical results of the stress intensity factor (SIF) are obtained. Moreover, the crack opening displacement (COD) can be obtained by numerical integration dislocation density functions. The effects of the thickness ratio, HTS material nonhomogeneous parameters, applied magnetic field and critical current density on SIF and COD are discussed. The present work could theoretically provide quantitative predictions of the fracture mechanism of the nonhomogeneous HTS.

  19. A New Method to Calculate Threshold Values of Ductile Fracture Criteria for Advanced High-Strength Sheet Blanking

    Science.gov (United States)

    Wang, Changsheng; Chen, Jun; Xia, Cedric; Ren, Feng; Chen, Jieshi

    2014-04-01

    A new approach is presented in this paper to calculate the critical threshold value of fracture initiation. It is based on the experimental data for forming limit curves and fracture forming limit curves. The deformation path for finally a fractured material point is assumed as two-stage proportional loading: biaxial loading from the beginning to the onset of incipient necking, followed plane strain deformation within the incipient neck until the final fracture. The fracture threshold value is determined by analytical integration and validated by numerical simulation. Four phenomenological models for ductile fracture are selected in this study, i.e., Brozzo, McClintock, Rice-Tracey, and Oyane models. The threshold value for each model is obtained through best-fitting of experimental data. The results are compared with each other and test data. These fracture criteria are implemented in ABAQUS/EXPLICIT through user subroutine VUMAT to simulate the blanking process of advanced high-strength steels. The simulated fracture surfaces are examined to determine the initiation of ductile fracture during the process, and compared with experimental results for DP780 sheet steel blanking. The comparisons between FE simulated results coupled with different fracture models and experimental one show good agreements on punching edge quality. The study demonstrates that the proposed approach to calculate threshold values of fracture models is efficient and reliable. The results also suggest that the McClintock and Oyane fracture models are more accurate than the Rice-Tracey or Brozzo models in predicting load-stroke curves. However, the predicted blanking edge quality does not have appreciable differences.

  20. Scratch-resistant, highly conductive, and high-strength carbon nanotube-based composite yarns.

    Science.gov (United States)

    Liu, Kai; Sun, Yinghui; Lin, Xiaoyang; Zhou, Ruifeng; Wang, Jiaping; Fan, Shoushan; Jiang, Kaili

    2010-10-26

    High-strength and conductive carbon nanotube (CNT) yarns are very attractive in many potential applications. However, there is a difficulty when simultaneously enhancing the strength and conductivity of CNT yarns. Adding some polymers into CNT yarns to enhance their strength will decrease their conductivity, while treating them in acid or coating them with metal nanoparticles to enhance their conductivity will reduce their strength. To overcome this difficulty, here we report a method to make high-strength and highly conductive CNT-based composite yarns by using a continuous superaligned CNT (SACNT) yarn as a conductive framework and then inserting polyvinyl alcohol (PVA) into the intertube spaces of the framework through PVA/dimethyl sulphoxide solution to enhance the strength of yarns. The as-produced CNT/PVA composite yarns possess very high tensile strengths up to 2.0 GPa and Young's moduli more than 120 GPa, much higher than those of the CNT/PVA yarns reported. The electric conductivity of as-produced composite yarns is as high as 9.2 × 10(4) S/m, comparable to HNO(3)-treated or Au nanoparticle-coated CNT yarns. These composite yarns are flexible, lightweight, scratch-resistant, very stable in the lab environment, and resistant to extremely humid ambient and as a result can be woven into high-strength and heatable fabrics, showing potential applications in flexible heaters, bullet-proof vests, radiation protection suits, and spacesuits.

  1. Fracture characteristics of bulk metallic glass under high speed impact

    Institute of Scientific and Technical Information of China (English)

    Sun Bao-Ru; Zhan Zai-Ji; Liang Bo; Zhang Rui-Jun; Wang Wen-Kui

    2012-01-01

    High speed impact experiments of rectangular plate-shaped Zr41Ti14Cu12.5Ni10Be22.5 bulk metallic glass(BMG)were performed using a two-stage light gas gun.Under spherical shock waves with impact velocities ranging from 0.503 km/s to 4.917 km/s,obvious traces of laminated spallation at the back(free)surface and melting(liquid droplets)at the impact point were observed.The angles about 0°,17°,36°,and 90° to the shocking direction were shown in the internal samples because of the interaction between the compressive shock waves and the rarefaction waves.The compressive normal stress was found to induce the consequent temperature rise in the core of the shear band.

  2. Irradiation dose and temperature dependence of fracture toughness in high dose HT9 steel from the fuel duct of FFTF

    Energy Technology Data Exchange (ETDEWEB)

    Byun, Thak Sang; Toloczko, Mychailo B.; Saleh, Tarik A.; Maloy, Stuart A.

    2013-01-14

    To expand the knowledge base for fast reactor core materials, fracture toughness has been evaluated for high dose HT9 steel using miniature disk compact tension (DCT) specimens. The HT9 steel DCT specimens were machined from the ACO-3 fuel duct of the Fast Flux Test Facility (FFTF), which achieved high doses in the range of 3–148 dpa at 378–504 C. The static fracture resistance (J-R) tests have been performed in a servohydraulic testing machine in vacuum at selected temperatures including room temperature, 200 C, and each irradiation temperature. Brittle fracture with a low toughness less than 50 MPa pm occurred in room temperature tests when irradiation temperature was below 400 C, while ductile fracture with stable crack growth was observed when irradiation temperature was higher. No fracture toughness less than 100 MPa pm was measured when the irradiation temperature was above 430 C. It was shown that the influence of irradiation temperature was dominant in fracture toughness while the irradiation dose has only limited influence over the wide dose range 3–148 dpa. A slow decrease of fracture toughness with test temperature above room temperature was observed for the nonirradiated and high temperature (>430 *C) irradiation cases, which indicates that the ductile–brittle transition temperatures (DBTTs) in those conditions are lower than room temperature. A comparison with the collection of existing data confirmed the dominance of irradiation temperature in the fracture toughness of HT9 steels.

  3. Method of forming macro-structured high surface area transparent conductive oxide electrodes

    Energy Technology Data Exchange (ETDEWEB)

    Forman, Arnold J.; Chen, Zhebo; Jaramillo, Thomas F.

    2016-01-05

    A method of forming a high surface area transparent conducting electrode is provided that includes depositing a transparent conducting thin film on a conductive substrate, where the transparent conducting thin film includes transparent conductive particles and a solution-based transparent conducting adhesive layer which serves to coat and bind together the transparent conducting particles, and heat treating the transparent conducting adhesion layer on the conductive substrate, where an increased surface area transparent conducting electrode is formed.

  4. Combined Lumbar-Sacral Plexus Block in High Surgical Risk Geriatric Patients undergoing Early Hip Fracture Surgery

    Directory of Open Access Journals (Sweden)

    Petchara S

    2015-11-01

    Full Text Available Objective: To evaluate the postoperative outcome after using combined lumbar and sacral plexus block (CLSB, as a sole anesthetic method in hip fracture (HF surgery in highrisk geriatric patients. Materials and Methods: A single-center retrospective study was conducted, between 2010 and 2012, on 70 elderly HF patients with American Society of Anesthesiologists grading III-IV who underwent early surgical intervention with our CLSB protocol. Perioperative data, outcome, and complications were recorded. Results: Forty-eight patients (69% had ongoing anticoagulant medication. Postoperatively, all patients were hemodynamically stable and awake. None of them required general anesthesia conversion. Minor anesthetic-related complications were found in nine patients. One patient (1% died from sepsis due to pneumonia. Patients’ satisfactions were all rated as very good or excellent. Conclusion: CLSB is an interesting anesthetic option in HF surgery, especially in high surgical risk geriatric patients. This method offers an excellent clinical efficiency and high patients’ satisfaction without serious complications.

  5. Dynamic tensile deformation and fracture of a highly particle-filled composite using SHPB and high-speed DIC method

    OpenAIRE

    Huang F; Guo B.; Chen P; Zhou Z

    2012-01-01

    In this work, various tensile tests, including Brazilian disc test (BDT), flattened Brazilian disc (FBD) test and semi-circular bending (SCB) test, were carried out on a highly particle-filled composite by using a split Hopkinson pressure bar (SHPB). With the consideration of low strength and low wave impedance of the materials, a quartz crystal transducer was embedded in SHPB to measure the loading forces. A high-speed camera was used to capture the deformation and fracture process of materi...

  6. Inkjet printed organic electrochemical transistors with highly conducting polymer electrolytes

    Science.gov (United States)

    Afonso, Mónica; Morgado, Jorge; Alcácer, Luís

    2016-10-01

    Organic Electrochemical Transistors (OECTs) were fabricated with two kinds of highly conducting polymer electrolytes, one with cations of small dimensions (Li+) and the other with cations of large dimensions (1-ethyl-3-methylimidazolium, EMI+). All OECTs exhibit transconductance values in the millisiemens range. Those with the larger EMI+ cations reach higher transconductance values and the saturated region of their I(V) characteristics extends to drain negative voltages of the order of -2 V without breakdown. These OECTs aim at potential applications for which it is relevant to use a solid polymer electrolyte instead of an aqueous electrolyte, namely, for integration in complex devices or in sensors and transducers where the electrolyte film may act as a membrane to prevent direct contact of the active material (PEDOT:PSS) with the biological media. The choice of electrolytes with cations of disparate sizes aims at assessing the nature (Faradaic or capacitive) of the processes occurring at the electrolyte/channel interface. The results obtained are consistent with a Faradaic-based operation mechanism.

  7. Development of Highly-Conductive Polyelectrolytes for Lithium Batteries

    Science.gov (United States)

    Shriver, D. F.; Ratner, M. A.; Vaynman, S.; Annan, K. O.; Snyder, J. F.

    2003-01-01

    Future NASA and Air Force missions require reliable and safe sources of energy with high specific energy and energy density that can provide thousands of charge-discharge cycles at more than 40% depth- of-discharge and that can operate at low temperatures. All solid-state batteries have substantial advantages with respect to stability, energy density, storage fife and cyclability. Among all solid-state batteries, those with flexible polymer electrolytes offer substantial advantages in cell dimensionality and commensurability, low temperature operation and thin film design. The above considerations suggest that lithium-polymer electrolyte systems are promising for high energy density batteries and should be the systems of choice for NASA and US Air Force applications. Polyelectrolytes (single ion conductors) are among most promising avenues for achieving a major breakthrough 'in the applicability of polymer- based electrolyte systems. Their major advantages include unit transference number for the cation, reduced cell polarization, minimal salt precipitation, and favorable electrolyte stability at interfaces. Our research is focused on synthesis, modeling and cell testing of single ion carriers, polyelectrolytes. During the first year of this project we attempted the synthesis of two polyelectrolytes. The synthesis of the first one, the poly(ethyleneoxide methoxy acrylateco-lithium 1,1,2-trifluorobutanesulfonate acrylate, was attempted few times and it was unsuccessful. We followed the synthetic route described by Cowie and Spence. The yield was extremely low and the final product could not be separated from the impurities. The synthesis of this polyelectrolyte is not described in this report. The second polyelectrolyte, comb polysiloxane polyelectrolyte containing oligoether and perfluoroether sidechains, was synthesized in sufficient quantity to study the range of properties such as thermal stability, Li- ion- conductivity and stability toward lithium metal. Also

  8. High conducting oxide--sulfide composite lithium superionic conductor

    Energy Technology Data Exchange (ETDEWEB)

    Liang, Chengdu; Rangasamy, Ezhiylmurugan; Dudney, Nancy J.; Keum, Jong Kahk; Rondinone, Adam Justin

    2017-01-17

    A solid electrolyte for a lithium-sulfur battery includes particles of a lithium ion conducting oxide composition embedded within a lithium ion conducting sulfide composition. The lithium ion conducting oxide composition can be Li.sub.7La.sub.3Zr.sub.2O.sub.12 (LLZO). The lithium ion conducting sulfide composition can be .beta.-Li.sub.3PS.sub.4 (LPS). A lithium ion battery and a method of making a solid electrolyte for a lithium ion battery are also disclosed.

  9. Physical chemistry of glass fracture

    Energy Technology Data Exchange (ETDEWEB)

    Michalske, T.A. [Sandia National Laboratories, Albuquerque, NM (United States)

    1993-12-31

    Since silica glass is a brittle material, its susceptibility to fracture often limits its use in technological applications. Previous studies have demonstrated that the fracture resistance of silica glass is decreased greatly by the presence of chemically reactive species such as water. By studying the effect of controlled amounts of reactive gases on the fracture rate in silica glass, the authors have developed chemical kinetics based models to describe the molecular level processes that lead to stress corrosion fracture of glass. A key aspect of our chemical kinetics based model is the measurement of the stress dependence for the hydrolysis of siloxane bonds. The authors derive the stress dependence for hydrolysis from reaction rate studies that are conducted on strained cyclosiloxane model compounds. The chemical kinetic parameter derived from model compounds is used to successfully predict the fracture behavior of bulk silica glass and the mechanical fatigue of high-strength silica glass fibers in various reactive chemical environments.

  10. Deformation and fracture of low alloy steels at high temperature

    Energy Technology Data Exchange (ETDEWEB)

    Marriott, D.L.; Stubbins, J.F.; Leckie, F.A.; Muddle, B.

    1988-12-01

    This project formed part of the initiative in the AR TD program to characterize high temperature, time-dependent damage processes in low alloy steels, for use in the construction of coal-gasification plant. This project was broadly aimed at adding to the knowledge base for this bainitic form of 2.25Cr 1Mo steel, as it related to time-dependent performance at elevated temperature. Its original intention was to obtain information in specific grades of 2.25Cr 1Mo steel, in particular those containing reduced residual elements and microalloyed modifications, which were being considered as candidate materials at the time. This objective was subsequently modified, in the course of the contract period, to a more generic study of bainitic steel, using the 2.25Cr 1Mo material as a representative of the class. The main thrust of the project was directed initially at the detrimental effect of cyclic loading on creep resistance and manifesting itself in an apparently severe creep-fatigue interaction. Three subtasks were eventually identified. These are: a study of the evolution of microstructural changes in bainitic materials during steady load creep and under constant amplitude cyclic deformation, investigation of the effect of cyclic softening on the fatigue and creep strength of complex geometries, focusing on circumferentially notched bars, and investigation of the influence of environment as a possible cause of observed fatigue/elevated temperature interaction through its effects on crack initiation and propagation, using EDM notched specimens tested in air and vacuum. Results are discussed. 24 refs., 40 figs., 5 tabs.

  11. High Thermal Conductivity Functionally Graded Heat Sinks for High Power Packaging Project

    Data.gov (United States)

    National Aeronautics and Space Administration — This NASA SBIR Phase I program proposes the development of a high thermal conductivity (400 W/mK), low coefficient of thermal expansion (7-10 ppm/?K), and light...

  12. The Electrical Conductivity of Gabbro at High Temperature and High Pressure

    Institute of Scientific and Technical Information of China (English)

    2002-01-01

    The electric conductivity of gabbro has been measured at 1.0-2.0 Gpa and 320-700℃,and the conduction mechanism has been analyzed in terms of the impedance spectra.Experimental results indicated that the electric conductivity depends on the frequency of alter-native current.Impedance arcs representing the conduction mechanism of grain interiors are displayed in the complex impedance plane ,and the mechanism is dominated at high pressure.These arcs occur over the range of 102-k×105Hz(k is the positive integer from 1 to 9) .On the basis of our results and previous work,it is concluded that gabbro cannot form any high conductivity layer (HCL) in the middle-lower crust.

  13. The Electrical Conductivity of Gabbro at High Temperature and High Pressure

    Institute of Scientific and Technical Information of China (English)

    王多君; 李和平; 易丽; 张卫刚; 刘丛强; 苏根利; 丁东业

    2002-01-01

    The electric conductivity of gabbro has been measured at 1.0 - 2.0 GPa and 320-700℃, and the conduction mechanism has been analyzed in terms of the impedance spectra.Experimental results indicated that the electric conductivity depends on the frequency of alternative current. Impedance arcs representing the conduction mechanism of grain interiors are displayed in the complex impedance plane, and the mechanism is dominated at high pressure.These arcs occur over the range of 102 - k× 105 Hz (k is the positive integer from 1 to 9). On the basis of our results and previous work, it is concluded that gabbro cannot form any high conductivity layer (HCL) in the middle-lower crust.

  14. High and low thermal conductivity of amorphous macromolecules

    Science.gov (United States)

    Xie, Xu; Yang, Kexin; Li, Dongyao; Tsai, Tsung-Han; Shin, Jungwoo; Braun, Paul V.; Cahill, David G.

    2017-01-01

    We measure the thermal conductivity, heat capacity and sound velocity of thin films of five polymers, nine polymer salts, and four caged molecules to advance the fundamental understanding of the lower and upper limits to heat conduction in amorphous macromolecules. The thermal conductivities vary by more than one order of magnitude, from 0.06 W m-1K-1 for [6,6]-phenyl-C71-butyric acid methyl ester to 0.67 W m-1K-1 for poly(vinylphosphonic acid calcium salt). Minimum thermal conductivity calculated from the measured sound velocity and effective atomic density is in good agreement with the thermal conductivity of macromolecules with various molecular structures and intermolecular bonding strength.

  15. Electrical Conductivity of HgTe at High Temperatures

    Science.gov (United States)

    Li, C.; Lehoczky, S. L.; Su, C.-H.; Scripa, R. N.

    2004-01-01

    The electrical conductivity of HgTe was measured using a rotating magnetic field method from 300 K to the melting point (943 K). A microscopic theory for electrical conduction was used to calculate the expected temperature dependence of the HgTe conductivity. A comparison between the measured and calculated conductivities was used to obtain the estimates of the temperature dependence of Gamma(sub 6)-Gamma(sub 8) energy gap from 300 K to 943 K. The estimated temperature coefficient for the energy gap was comparable to the previous results at lower temperatures (less than or equal to 300 K). A rapid increase in the conductivity just above 300 K and a subsequent decrease at 500 K is attributed to band crossover effects. This paper describes the experimental approach and some of the theoretical calculation details.

  16. The plane strain shear fracture of the advanced high strength steels

    Energy Technology Data Exchange (ETDEWEB)

    Sun, Li, E-mail: li.sun@gm.com [General Motors China Science Lab, No.56 Jinwan Road, Shanghai, 201206 (China)

    2013-12-16

    The “shear fracture” which occurs at the high-curvature die radii in the sheet metal forming has been reported to remarkably limit the application of the advanced high strength steels (AHSS) in the automobile industry. However, this unusual fracture behavior generally cannot be predicted by the traditional forming limit diagram (FLD). In this research, a new experimental system was developed in order to simulate the shear fracture, especially at the plane strain state which is the most common state in the auto-industry and difficult to achieve in the lab due to sample size. Furthermore, the system has the capability to operate in a strain rate range from quasi-static state to the industrial forming state. One kinds of AHSS, Quenching-Partitioning (QP) steels have been performed in this test and the results show that the limiting fracture strain is related to the bending ratio and strain rate. The experimental data support that deformation-induced heating is an important cause of “shear fracture” phenomena for AHSS: a deformation-induced quasi-heating caused by smaller bending ratio and high strain rate produce a smaller limiting plane strain and lead a “shear fracture” in the component.

  17. Technical Project Plan for The Enhanced Thermal Conductivity of Oxide Fuels Through the Addition of High Thermal Conductivity Fibers and Microstructural Engineering

    Energy Technology Data Exchange (ETDEWEB)

    Hollenbach, Daniel F [ORNL; Ott, Larry J [ORNL; Besmann, Theodore M [ORNL; Armstrong, Beth L [ORNL; Wereszczak, Andrew A [ORNL; Lin, Hua-Tay [ORNL; Ellis, Ronald James [ORNL; Becher, Paul F [ORNL; Jubin, Robert Thomas [ORNL; Voit, Stewart L [ORNL

    2010-09-01

    The commercial nuclear power industry is investing heavily in advanced fuels that can produce higher power levels with a higher safety margin and be produced at low cost. Although chemically stable and inexpensive to manufacture, the in-core performance of UO{sub 2} fuel is limited by its low thermal conductivity. There will be enormous financial benefits to any utility that can exploit a new type of fuel that is chemically stable, has a high thermal conductivity, and is inexpensive to manufacture. At reactor operating temperatures, UO{sub 2} has a very low thermal conductivity (<5 W/m {center_dot}K), which decreases with temperature and fuel burnup. This low thermal conductivity limits the rate at which energy can be removed from the fuel, thus limiting the total integrated reactor power. If the fuel thermal conductivity could be increased, nuclear reactors would be able to operate at higher powers and larger safety margins thus decreasing the overall cost of electricity by increasing the power output from existing reactors and decreasing the number of new electrical generating plants needed to meet base load demand. The objective of the work defined herein is to produce an advanced nuclear fuel based on the current UO{sub 2} fuel with superior thermal conductivity and structural integrity that is suitable for current and future nuclear reactors, using the existing fuel fabrication infrastructure with minimal modifications. There are two separate components to the research: (1) Enhanced Thermal Conductivity (ETC) - adding high conductivity fibers to the UO{sub 2} prior to sintering, which act as conduits for moving the heat energy generated within the pellet to the outer surface, (2) Microstructural Engineering (ME) - adding second phase particulates to UO{sub 2} bodies to retard grain growth and to increase thermal conductivity, as well as improve fracture and creep resistance. Different groups will perform the laboratory work for each of these research

  18. A systematic review on the use of daily subcutaneous administration of teriparatide for treatment of patients with osteoporosis at high risk for fracture in Asia.

    Science.gov (United States)

    Chen, J F; Yang, K H; Zhang, Z L; Chang, H C; Chen, Y; Sowa, H; Gürbüz, S

    2015-01-01

    This systematic review aimed to examine the evidence for teriparatide in Asia for osteoporosis with a high fracture risk and for exploratory (unapproved) bone-related indications. MEDLINE (1946+), EMBASE (1966+), and ClinicalTrials.gov (2008+) were searched (16 August 2013); all studies of daily subcutaneous teriparatide 20 μg for bone-related conditions from China, Hong Kong, Japan, Republic of Korea, Philippines, Singapore, and Taiwan were included. Evidence on efficacy/safety was retrieved primarily from randomized controlled trials (10 publications) of postmenopausal women from Japan and China. In these studies, teriparatide was well tolerated; subjects had significantly greater increases in lumbar spine bone mineral density (BMD) from baseline compared with placebo, antiresorptive agents, or elcatonin/calcitonin; bone turnover markers increased from baseline and were sustained at elevated levels during teriparatide treatment. Few studies reported fracture risk, pain, or quality of life; one study showed a lower incidence of new-onset vertebral fracture with teriparatide versus antiresorptive agents. Nonrandomized studies (nine publications, one unpublished trial) conducted mainly in Taiwan, Japan, and the Republic of Korea provided supporting data for efficacy. The exploratory (unapproved) use of teriparatide (17 publications) for fracture healing and osteonecrosis of the jaw was described primarily in case reports. The clinical effectiveness of teriparatide for treatment of postmenopausal women with osteoporosis who are at high risk of fracture in Asia is focused primarily on improvements in BMD and tolerability. Recommended additional studies may include assessment of fracture risk and the effect of teriparatide on pain, quality of life, and mortality in Asia.

  19. The contribution of high-resolution multiplanar reformats of the skull base to the detection of skull-base fractures

    Energy Technology Data Exchange (ETDEWEB)

    Connor, S.E.J. [Neuroradiology Department, Kings College Hospital, Denmark Hill, London (United Kingdom)]. E-mail: steve.connor@kch.nhs.uk; Flis, C. [Neuroradiology Department, Kings College Hospital, Denmark Hill, London (United Kingdom)

    2005-08-01

    AIM: To investigate the contribution of routine review of submillimetric multiplanar reformats to the diagnosis of skull-base fractures. METHODS: A prospective analysis was performed of 407 cases referred over a 6-month period for CT of the skull following cranial trauma. The reformatted 5-mm axial sections and subsequently the high-resolution multiplanar reformats (HRMPRs) were viewed on an ADW 4.1 workstation using bone windows and algorithm. All skull-base fractures and related features, recorded by the consensus of two radiologists, were classified as anatomically significant or non-significant on the basis of eight criteria. The clinical features of skull-base injury and any subsequent treatment were noted in all cases of skull-base fracture. RESULTS: HRMPRs detected 80 separate skull-base fractures in 36/407 cases. Of these 80 fractures, 57 were visible on 5-mm axial sections. In 8 of the 36 cases, the significant anatomical features were only evident on review of the HRMPRs. In 6 of the 36 cases, none of the skull-base fractures was visible on 5-mm sections, but these individuals had only minor associated clinical features and no therapeutic requirements. Review of HRMPRs could have been confined to patients with skull-base fractures, abnormal intracranial and extracranial air collections or opacified mastoid air cells revealed by 5-mm axial sections. This policy would have led to the detection of 79/80 (99%) of skull-base fractures and all significant anatomical features. CONCLUSION: The 5-mm axial sections demonstrated 71% of skull-base fractures and 78% of skull-base fractures with significant anatomical features, using HRMPRs as a gold standard. There were no significant clinical sequelae at short-term follow-up of those fractures only evident on HRMPRs.

  20. Transmission eigenvalue distributions in highly conductive molecular junctions

    Directory of Open Access Journals (Sweden)

    Justin P. Bergfield

    2012-01-01

    Full Text Available Background: The transport through a quantum-scale device may be uniquely characterized by its transmission eigenvalues τn. Recently, highly conductive single-molecule junctions (SMJ with multiple transport channels (i.e., several τn > 0 have been formed from benzene molecules between Pt electrodes. Transport through these multichannel SMJs is a probe of both the bonding properties at the lead–molecule interface and of the molecular symmetry.Results: We use a many-body theory that properly describes the complementary wave–particle nature of the electron to investigate transport in an ensemble of Pt–benzene–Pt junctions. We utilize an effective-field theory of interacting π-electrons to accurately model the electrostatic influence of the leads, and we develop an ab initio tunneling model to describe the details of the lead–molecule bonding over an ensemble of junction geometries. We also develop a simple decomposition of transmission eigenchannels into molecular resonances based on the isolated resonance approximation, which helps to illustrate the workings of our many-body theory, and facilitates unambiguous interpretation of transmission spectra.Conclusion: We confirm that Pt–benzene–Pt junctions have two dominant transmission channels, with only a small contribution from a third channel with τn << 1. In addition, we demonstrate that the isolated resonance approximation is extremely accurate and determine that transport occurs predominantly via the HOMO orbital in Pt–benzene–Pt junctions. Finally, we show that the transport occurs in a lead–molecule coupling regime where the charge carriers are both particle-like and wave-like simultaneously, requiring a many-body description.

  1. Potential Dependence of the Conductivity of Highly Oxidized Polythiophenes, Polypyrroles, and Polyaniline: Finite Windows of High Conductivity

    Science.gov (United States)

    1990-05-16

    protonation/deprotonation mechanism . Conductivity increases by at least 108 upon oxidizing polyani-ine from neutral to maximally conducting, and decreases...reversible, potential dependent changes in conductivity in liquid S02/electrolyte in the apparent absence of a protonation/deprotonation mechanism ...polyaniline is similar in 0.5 M H2SO4 ,1 liquid S02 /electrolyte, and poly(vinyl alchohol )/H 3PO4.nH20.8 However, the positive potential limit in aqueous

  2. Electrical conductivity of rocks at high pressures and temperatures

    Science.gov (United States)

    Parkhomenko, E. I.; Bondarenko, A. T.

    1986-01-01

    The results of studies of the electrical conductivity in the most widely distributed types of igneous rocks, at temperatures of up to 1200 C, at atmospheric pressure, and also at temperatures of up to 700 C and at pressures of up to 20,000 kg/sq cm are described. The figures of electrical conductivity, of activaation energy and of the preexponential coefficient are presented and the dependence of these parameters on the petrochemical parameters of the rocks are reviewed. The possible electrical conductivities for the depository, granite and basalt layers of the Earth's crust and of the upper mantle are presented, as well as the electrical conductivity distribution to the depth of 200 to 240 km for different geological structures.

  3. Hall Effect Influence on a Highly Conducting Fluid

    Energy Technology Data Exchange (ETDEWEB)

    Witalis, E.A.

    1966-11-15

    The properties of an incompressible perfect fluid exhibiting Hall effect is investigated in the limit of infinite electrical conductivity and mobility. The magnetic field strength and the fluid velocity are found to obey the equations B = {mu}{rho}/{sigma} x curlV and V -{mu}/({sigma}{mu}{sub 0}) x curlB (MKS units) where {rho}, {sigma} and {mu} denote mass density, conductivity and charge carrier mobility. Some physical interpretations and applications are given.

  4. Fracture toughness measurements on a glass bonded sodalite high-level waste form.

    Energy Technology Data Exchange (ETDEWEB)

    DiSanto, T.; Goff, K. M.; Johnson, S. G.; O' Holleran, T. P.

    1999-05-19

    The electrometallurgical treatment of metallic spent nuclear fuel produces two high-level waste streams; cladding hulls and chloride salt. Argonne National Laboratory is developing a glass bonded sodalite waste form to immobilize the salt waste stream. The waste form consists of 75 Vol.% crystalline sodalite (containing the salt) with 25 Vol.% of an ''intergranular'' glassy phase. Microindentation fracture toughness measurements were performed on representative samples of this material using a Vickers indenter. Palmqvist cracking was confirmed by post-indentation polishing of a test sample. Young's modulus was measured by an acoustic technique. Fracture toughness, microhardness, and Young's modulus values are reported, along with results from scanning electron microscopy studies.

  5. Fracture behavior of neutron-irradiated high-manganese austenitic steels

    Science.gov (United States)

    Yoshida, H.; Miyata, K.; Narui, M.; Kayano, H.

    1991-03-01

    The instrumented Charpy impact test was applied to study the fracture behavior of high-manganese austenitic steels before and after neutron irradiations. Quarter-size specimens of a commercial high-manganese steel (18% Mn-5% Ni-16% Cr), three reference steels (21% Mn-1% Ni-9% Cr, 20% Mn-1% Ni-11% Cr, 15% Mn-1% Ni-13% Cr) and two model steels (17% Mn-4.5% Si-6.5% Cr, 22% Mn-4.5% Si-6.5% Cr-0.2% N) were used for the impact tests at temperatures between 77 and 523 K. The load-deflection curves showed typical features corresponding to characteristics of the fracture properties. The temperature dependences of fracture energy and failure deflection obtained from the curves clearly demonstrate only small effects up to 2 × 10 23 n/m 2 ( E > 0.1 MeV) and brittleness at room temperature in 17% Mn-Si-Cr steel at 1.6 × 10 25 n/m 2 ( E > 0.1 MeV), while ductility still remains in 22%Mn-Si-Cr steel.

  6. Evaluation of susceptibility of high strength steels to delayed fracture by using cyclic corrosion test and slow strain rate test

    Energy Technology Data Exchange (ETDEWEB)

    Li Songjie [School of Materials Science and Engineering, University of Science and Technology Beijing, No. 30 Xueyuan Road, Hidian Zone, Beijing 100083 (China); Structural Metals Center, National Institute for Materials Science, 1-2-1 Sengen, Tsukuba, Ibaraki 305-0047 (Japan); Zhang Zuogui [Structural Metals Center, National Institute for Materials Science, 1-2-1 Sengen, Tsukuba, Ibaraki 305-0047 (Japan); Akiyama, Eiji [Structural Metals Center, National Institute for Materials Science, 1-2-1 Sengen, Tsukuba, Ibaraki 305-0047 (Japan)], E-mail: AKIYAMA.Eiji@nims.go.jp; Tsuzaki, Kaneaki [Structural Metals Center, National Institute for Materials Science, 1-2-1 Sengen, Tsukuba, Ibaraki 305-0047 (Japan); Zhang Boping [School of Materials Science and Engineering, University of Science and Technology Beijing, No. 30 Xueyuan Road, Hidian Zone, Beijing 100083 (China)

    2010-05-15

    To evaluate susceptibilities of high strength steels to delayed fracture, slow strain rate tests (SSRT) of notched bar specimens of AISI 4135 with tensile strengths of 1300 and 1500 MPa and boron-bearing steel with 1300 MPa have been performed after cyclic corrosion test (CCT). During SSRT the humidity around the specimen was kept high to keep absorbed diffusible hydrogen. The fracture stresses of AISI 4135 steels decreased with increment of diffusible hydrogen content which increased with CCT cycles. Their delayed fracture susceptibilities could be successfully evaluated in consideration of both influence of hydrogen content on mechanical property and hydrogen entry.

  7. Treatment of open tibial fracture with bone defect caused by high velocity missiles: A case report

    Directory of Open Access Journals (Sweden)

    Golubović Zoran

    2013-01-01

    Full Text Available Introduction .Tibia fracture caused by high velocity missiles is mostly comminuted and followed by bone defect which makes their healing process extremely difficult and prone to numerous complications. Case Outline. A 34-year-old male was wounded at close range by a semi-automatic gun missile. He was wounded in the distal area of the left tibia and suffered a massive defect of the bone and soft tissue. After the primary treatment of the wound, the fracture was stabilized with an external fixator type Mitkovic, with convergent orientation of the pins. The wound in the medial region of the tibia was closed with the secondary stitch, whereas the wound in the lateral area was closed with the skin transplant after Thiersch. Due to massive bone defect in the area of the rifle-missile wound six months after injury, a medical team placed a reconstructive external skeletal fixator type Mitkovic and performed corticotomy in the proximal metaphyseal area of the tibia. By the method of bone transport (distractive osteogenesis, the bone defect of the tibia was replaced. After the fracture healing seven months from the secondary surgery, the fixator was removed and the patient was referred to physical therapy. Conclusion. Surgical treatment of wounds, external fixation, performing necessary debridement, adequate antibiotic treatment and soft and bone tissue reconstruction are essential in achieving good results in patients with the open tibial fracture with bone defect caused by high velocity missiles. Reconstruction of bone defect can be successfully treated by reconstructive external fixator Mitkovic. [Projekat Ministarstva nauke Republike Srbije, br. III 41017 i br. III 41004

  8. Patients with eating disorders. A high-risk group for fractures

    DEFF Research Database (Denmark)

    Vestergaard, Peter; Emborg, Charlotte; Støving, René K;

    2003-01-01

    PURPOSE: To analyze fracture risk and bone mineral density in patients with eating disorders (anorexia nervosa, bulimia nervosa, and other eating disorders). DESIGN: Clinical overview. FINDINGS: Bone mineral density is decreased and fracture risk increased in patients with anorexia nervosa....... In patients with bulimia nervosa, bone mineral is only marginally decreased and fracture risk marginally increased. In patients with other eating disorders (eating disorders not otherwise specified), bone mineral density is decreased and fracture risk increased. CONCLUSIONS: Fracture risk is increased...... in patients with eating disorders. An eating disorder should be suspected in severely underweight young individuals (primarily girls) presenting with fractures, especially low-energy fractures....

  9. Dynamic tensile deformation and fracture of a highly particle-filled composite using SHPB and high-speed DIC method

    Directory of Open Access Journals (Sweden)

    Huang F.

    2012-08-01

    Full Text Available In this work, various tensile tests, including Brazilian disc test (BDT, flattened Brazilian disc (FBD test and semi-circular bending (SCB test, were carried out on a highly particle-filled composite by using a split Hopkinson pressure bar (SHPB. With the consideration of low strength and low wave impedance of the materials, a quartz crystal transducer was embedded in SHPB to measure the loading forces. A high-speed camera was used to capture the deformation and fracture process of materials. Digital image correlation (DIC method was used to process these digital images to obtain the dynamic deformation information. Based on the measured strain fields, the crack growth path was determined and the failure mechanism of samples was analyzed. Combining SHPB and DIC method, the indirect tensile stress strain plots of disc samples were obtained, and the dynamic fracture toughness of materials was measured using both FBD and SCB tests. The results show that the tensile failure strength and fracture toughness increases with the increase of strain rates, exhibiting strain rate dependence. The high-speed DIC method combined with SHPB is effective to study the dynamic tensile behaviour of brittle materials with low strengths.

  10. Dynamic tensile deformation and fracture of a highly particle-filled composite using SHPB and high-speed DIC method

    Science.gov (United States)

    Zhou, Z.; Chen, P.; Guo, B.; Huang, F.

    2012-08-01

    In this work, various tensile tests, including Brazilian disc test (BDT), flattened Brazilian disc (FBD) test and semi-circular bending (SCB) test, were carried out on a highly particle-filled composite by using a split Hopkinson pressure bar (SHPB). With the consideration of low strength and low wave impedance of the materials, a quartz crystal transducer was embedded in SHPB to measure the loading forces. A high-speed camera was used to capture the deformation and fracture process of materials. Digital image correlation (DIC) method was used to process these digital images to obtain the dynamic deformation information. Based on the measured strain fields, the crack growth path was determined and the failure mechanism of samples was analyzed. Combining SHPB and DIC method, the indirect tensile stress strain plots of disc samples were obtained, and the dynamic fracture toughness of materials was measured using both FBD and SCB tests. The results show that the tensile failure strength and fracture toughness increases with the increase of strain rates, exhibiting strain rate dependence. The high-speed DIC method combined with SHPB is effective to study the dynamic tensile behaviour of brittle materials with low strengths.

  11. Patients with eating disorders. A high-risk group for fractures

    DEFF Research Database (Denmark)

    Vestergaard, Peter; Emborg, Charlotte; Støving, René K

    2003-01-01

    PURPOSE: To analyze fracture risk and bone mineral density in patients with eating disorders (anorexia nervosa, bulimia nervosa, and other eating disorders). DESIGN: Clinical overview. FINDINGS: Bone mineral density is decreased and fracture risk increased in patients with anorexia nervosa....... In patients with bulimia nervosa, bone mineral is only marginally decreased and fracture risk marginally increased. In patients with other eating disorders (eating disorders not otherwise specified), bone mineral density is decreased and fracture risk increased. CONCLUSIONS: Fracture risk is increased...

  12. Bismuth-lead oxide, a new highly conductive oxygen materials

    NARCIS (Netherlands)

    Honnart, F.; Boivin, J.C.; Thomas, D.; Vries, de K.J.

    1983-01-01

    The transport properties of an oxygen-deficient solid solution containing lead and bismuth oxides have been investigated. The conductivity is larger than 1 (ω× cm)−1 at 600 °C. Thermogalvanic measurements confirm that no significant electronic contribution occurs in the range 1–10−3atm p O2. The hea

  13. Highly conductive self-assembled nanoribbons of coordination polymers.

    Science.gov (United States)

    Welte, Lorena; Calzolari, Arrigo; Di Felice, Rosa; Zamora, Felix; Gómez-Herrero, Julio

    2010-02-01

    Organic molecules can self-assemble into well-ordered structures, but the conductance of these structures is limited, which is a disadvantage for applications in molecular electronics. Conductivity can be improved by using coordination polymers-in which metal centres are incorporated into a molecular backbone-and such structures have been used as molecular wires by self-assembling them into ordered films on metal surfaces. Here, we report electrically conductive nanoribbons of the coordination polymer [Pt(2)I(S(2)CCH(3))(4)](n) self-assembled on an insulating substrate by direct sublimation of polymer crystals. Conductance atomic force microscopy is used to probe the electrical characteristics of a few polymer chains ( approximately 10) within the nanoribbons. The observed currents exceed those previously sustained in organic and metal-organic molecules assembled on surfaces by several orders of magnitude and over much longer distances. These results, and the results of theoretical calculations based on density functional theory, confirm coordination polymers as candidate materials for applications in molecular electronics.

  14. Modelling and measurement of high switching frequency conducted EMI

    CSIR Research Space (South Africa)

    Grobler, Inus

    2013-11-01

    Full Text Available to perform the analyses of the model, presented as a very easy and reliable tool. The common mode effect of electrically non-conductive polymer heatsinks was presented and tested as a remedy to reduce the increased common mode noise levels due to higher...

  15. Study on Productivity Numerical Simulation of Highly Deviated and Fractured Wells in Deep Oil and Gas Reservoirs

    Directory of Open Access Journals (Sweden)

    Li Liangchuan

    2016-01-01

    Full Text Available This paper establishes the model of sandstone, porosity and permeability on single well in allusion to 10 highly deviated and fractured wells in deep oil and gas reservoirs of Jidong Oilfield, which forms a numerical simulation method of highly deviated and fractured wells in deep oil and gas reservoirs of Jidong Oilfield. The numerical simulation results of highly deviated and fractured wells productivity in deep oil and gas reservoirs are given out under different layers (layer ES1, layer ES3, layer ED2,and layer ED3, different deviation angles(60° and 75°, different fracture parameters and producing pressure drops. Through the comparison with testing data getting from exploration wells, we know that the calculation results of numerical simulation are consistent with practical testing results.

  16. Galeazzi fractures and dislocations.

    Science.gov (United States)

    Giannoulis, Filippos S; Sotereanos, Dean G

    2007-05-01

    In 1934, fractures of the middle and distal third of the radius associated with instability of the distal radial ulnar joint (DRUJ) were described by Galeazzi. This type of lesion is characterized by its unstable nature and the need for open reduction and internal fixation to achieve a satisfactory functional outcome. A high index of suspicion should be maintained by the surgeon, and a thorough examination for instability of the DRUJ must be conducted. The marked instability of this fracture-dislocation complex is further enhanced by the disruption of the triangular fibrocartilage complex, either with or without ulna styloid fracture. Treatment in adults is surgical, and both bone and soft tissue injuries should be addressed.

  17. Economic viability of geriatric hip fracture centers.

    Science.gov (United States)

    Clement, R Carter; Ahn, Jaimo; Mehta, Samir; Bernstein, Joseph

    2013-12-01

    Management of geriatric hip fractures in a protocol-driven center can improve outcomes and reduce costs. Nonetheless, this approach has not spread as broadly as the effectiveness data would imply. One possible explanation is that operating such a center is not perceived as financially worthwhile. To assess the economic viability of dedicated hip fracture centers, the authors built a financial model to estimate profit as a function of costs, reimbursement, and patient volume in 3 settings: an average US hip fracture program, a highly efficient center, and an academic hospital without a specific hip fracture program. Results were tested with sensitivity analysis. A local market analysis was conducted to assess the feasibility of supporting profitable hip fracture centers. The results demonstrate that hip fracture treatment only becomes profitable when the annual caseload exceeds approximately 72, assuming costs characteristic of a typical US hip fracture program. The threshold of profitability is 49 cases per year for high-efficiency hip fracture centers and 151 for the urban academic hospital under review. The largest determinant of profit is reimbursement, followed by costs and volume. In the authors’ home market, 168 hospitals offer hip fracture care, yet 85% fall below the 72-case threshold. Hip fracture centers can be highly profitable through low costs and, especially, high revenues. However, most hospitals likely lose money by offering hip fracture care due to inadequate volume. Thus, both large and small facilities would benefit financially from the consolidation of hip fracture care at dedicated hip fracture centers. Typical US cities have adequate volume to support several such centers.

  18. Cluster analysis of bone microarchitecture from high resolution peripheral quantitative computed tomography demonstrates two separate phenotypes associated with high fracture risk in men and women.

    Science.gov (United States)

    Edwards, M H; Robinson, D E; Ward, K A; Javaid, M K; Walker-Bone, K; Cooper, C; Dennison, E M

    2016-07-01

    Osteoporosis is a major healthcare problem which is conventionally assessed by dual energy X-ray absorptiometry (DXA). New technologies such as high resolution peripheral quantitative computed tomography (HRpQCT) also predict fracture risk. HRpQCT measures a number of bone characteristics that may inform specific patterns of bone deficits. We used cluster analysis to define different bone phenotypes and their relationships to fracture prevalence and areal bone mineral density (BMD). 177 men and 159 women, in whom fracture history was determined by self-report and vertebral fracture assessment, underwent HRpQCT of the distal radius and femoral neck DXA. Five clusters were derived with two clusters associated with elevated fracture risk. "Cluster 1" contained 26 women (50.0% fractured) and 30 men (50.0% fractured) with a lower mean cortical thickness and cortical volumetric BMD, and in men only, a mean total and trabecular area more than the sex-specific cohort mean. "Cluster 2" contained 20 women (50.0% fractured) and 14 men (35.7% fractured) with a lower mean trabecular density and trabecular number than the sex-specific cohort mean. Logistic regression showed fracture rates in these clusters to be significantly higher than the lowest fracture risk cluster [5] (pcluster 5 in women in cluster 1 and 2 (pcluster 2 (pclusters in both men and women which may differ in etiology and response to treatment. As cluster 1 in men does not have low areal BMD, these men may not be identified as high risk by conventional DXA alone. Copyright © 2016. Published by Elsevier Inc.

  19. Conductively cooled high-power high-brightness bars and fiber-coupled arrays

    Science.gov (United States)

    Zhou, Hailong; Mondry, Mark; Fouksman, Michael; Weiss, Eli; Anikitchev, Serguei; Kennedy, Keith; Li, Jun; Zucker, Erik; Rudy, Paul; Kongas, Jukka; Haapamaa, Jouko; Lehkonen, Sami

    2005-03-01

    Solid-state-laser and fiber laser pumping, reprographics, medical and materials processing applications require high power, high-brightness bars and fiber-coupled arrays. Conductively cooled laser diode bars allow customers to simplify system design and reduce operational size, weight, and costs. We present results on next generation high brightness, high reliability bars and fiber-coupled arrays at 790-830 nm, 940 nm and 980 nm wavelengths. By using novel epitaxial structures, we have demonstrated highly reliable 808 nm, 30% fill-factor conductively cooled bars operating at 60W CW mode, corresponding to a linear power density (LPD) of 20 mW/&mum. At 25°C, the bars have shown greater than 50% wall-plug-efficiency (WPE) when operating at 60W. Our novel approach has also reduced the fast-axis divergence FWHM from 31° to less than 24°. These bars have a 50% brightness improvement compared to our standard products with this geometry. At 980nm, we have demonstrated greater than 100W CW from 20% fill-factor conductively cooled bars, corresponding to a LPD of 50 mW/μm. At 25°C, the WPE for 976nm bars consistently peaks above 65% and remains greater than 60% at 100W. We coupled the beam output from those high-brightness bars into fiber-array-packages ("FAPs"), and we also achieved high-brightness and high-efficiency FAPs. We demonstrated 60W from a 600μm core-diameter fiber-bundle with a high WPE of 55%, and a low numerical aperture of 0.115. The brightness of such FAPs is four times higher than our standard high-power 40W FAP products at Coherent. Ongoing life test data suggests an extrapolated lifetime greater than 10,000 hours at 80W CW operating-condition based on 30%FF conductively cooled bar geometry.

  20. Measurement of Thermal Conductivity of Liquids at High Temperature

    Science.gov (United States)

    Schick, V.; Remy, B.; Degiovanni, A.; Demeurie, F.; Meulemans, J.; Lombard, P.

    2012-11-01

    The goal purchased in this paper is to implement a pulse method to measure the thermal conductivity of liquid silica glass above 1200°C until 1600°C. A heat flux stimulation controlled in energy and in time is generated on the front face of an experimental cell. The temperature rise is measured on the rear face of this cell face by using a fast cooled infrared camera. The choice of the measurement cell geometry is fundamental to be able to estimate at the same time the thermal diffusivity and the specific heat of the liquid by an inverse technique. The parameters estimation problem takes into account the optimization of the cell wall thickness. The theoretical model used for the inversion takes into account the coupled heat transfer modes (conduction, convection and radiation) that can occur during the experiment, particularly the thermal conductive short-cut through metallic lateral walls of the cell and radiative transfer within the semi-transparent and participating medium. First measurements are performed on a cell filled with water at ambient temperature in order to validate the parameters estimation procedure.

  1. Alteration of Fractured Rocks Due to Coupled Chemical and Mechanical Processes: High-Resolution Simulations and Experimental Observations

    Science.gov (United States)

    Ameli, Pasha

    Engineering activities such as enhanced geothermal energy production and improved oil recovery techniques are heavily dependent on the permeability of the subsurface, while others such as CO2 sequestration and nuclear waste disposal rely on the efficiency of rock formations as transport barriers. In either case fractures provide the main pathways for fluid flow and transport, especially in rocks with lower matrix porosity. Laboratory experiments aimed at quantifying the chemo-mechanical responses of fractures have shown a range of results, some of which contradict simple conceptual models. For example, under conditions favoring mineral dissolution, where one would expect an overall increase in permeability, experiments show that permeability increases under some conditions and decreases under others. Recent experiments have attempted to link these core-scale observations to the relevant small-scale processes occurring within fractures. Results suggest that the loss of mechanical strength in asperities due to chemical alteration may cause non-uniform deformation and alteration of fracture apertures. However, due to the lack of direct micro-scale measurements of the coupled chemical and mechanical processes that lead to alteration of contacting fracture surfaces, our ability to predict the long-term evolution of fractures is still limited. To explore the processes that control permeability evolution, I developed a computational model that uses micro-scale surface roughness and explicitly couples dissolution and elastic deformation to calculate local alterations in fracture aperture under chemical and mechanical stresses. A depth-averaged algorithm of fracture flow is used to model reactive transport and chemical alteration of the fracture surfaces. Then, I deform the resulting altered fracture-surfaces using an algorithm that calculates the elastic deformation. The results of the model are compared with flow-through experiments conducted on fractured limestone. The

  2. Highly conductive, capacitive, flexible and soft electrodes based on a 3D graphene-nanotube-palladium hybrid and conducting polymer.

    Science.gov (United States)

    Kim, Hyun-Jun; Randriamahazaka, Hyacinthe; Oh, Il-Kwon

    2014-12-29

    Highly conductive, capacitive and flexible electrodes are fabricated by employing 3D graphene-nanotube-palladium nanostructures and a PEDOT:PSS conducting polymer. The fabricated flexible electrodes, without any additional metallic current collectors, exhibit increased charge mobility and good mechanical properties; they also allow greater access to the electrolyte ions and hence are suitable for flexible energy storage applications. © 2014 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

  3. Temperature and strain rate effects in high strength high conductivity copper alloys tested in air

    Energy Technology Data Exchange (ETDEWEB)

    Edwards, D.J. [Pacific Northwest National Lab., Richland, WA (United States)

    1998-03-01

    The tensile properties of the three candidate alloys GlidCop{trademark} Al25, CuCrZr, and CuNiBe are known to be sensitive to the testing conditions such as strain rate and test temperature. This study was conducted on GlidCop Al25 (2 conditions) and Hycon 3HP (3 conditions) to ascertain the effect of test temperature and strain rate when tested in open air. The results show that the yield strength and elongation of the GlidCop Al25 alloys exhibit a strain rate dependence that increases with temperature. Both the GlidCop and the Hycon 3 HP exhibited an increase in strength as the strain rate increased, but the GlidCop alloys proved to be the most strain rate sensitive. The GlidCop failed in a ductile manner irrespective of the test conditions, however, their strength and uniform elongation decreased with increasing test temperature and the uniform elongation also decreased dramatically at the lower strain rates. The Hycon 3 HP alloys proved to be extremely sensitive to test temperature, rapidly losing their strength and ductility when the temperature increased above 250 C. As the test temperature increased and the strain rate decreased the fracture mode shifted from a ductile transgranular failure to a ductile intergranular failure with very localized ductility. This latter observation is based on the presence of dimples on the grain facets, indicating that some ductile deformation occurred near the grain boundaries. The material failed without any reduction in area at 450 C and 3.9 {times} 10{sup {minus}4} s{sup {minus}1}, and in several cases failed prematurely.

  4. Survival of ceramic bearings in total hip replacement after high-energy trauma and periprosthetic acetabular fracture.

    Science.gov (United States)

    Salih, S; Currall, V A; Ward, A J; Chesser, T J S

    2009-11-01

    Surgeons remain concerned that ceramic hip prostheses may fail catastrophically if either the head or the liner is fractured. We report two patients, each with a ceramic-on-ceramic total hip replacement who sustained high-energy trauma sufficient to cause a displaced periprosthetic acetabular fracture in whom the ceramic bearings survived intact. Simultaneous fixation of the acetabular fracture, revision of the cementless acetabular prosthesis and exchange of the ceramic bearings were performed successfully in both patients. Improved methods of manufacture of new types of alumina ceramic with a smaller grain size, and lower porosity, have produced much stronger bearings. Whether patients should be advised to restrict high-impact activities in order to protect these modern ceramic bearings from fracture remains controversial.

  5. High throughput thermal conductivity of high temperature solid phases: The case of oxide and fluoride perovskites

    CERN Document Server

    van Roekeghem, Ambroise; Oses, Corey; Curtarolo, Stefano; Mingo, Natalio

    2016-01-01

    Using finite-temperature phonon calculations and machine-learning methods, we calculate the mechanical stability of about 400 semiconducting oxides and fluorides with cubic perovskite structures at 0 K, 300 K and 1000 K. We find 92 mechanically stable compounds at high temperatures -- including 36 not mentioned in the literature so far -- for which we calculate the thermal conductivity. We demonstrate that the thermal conductivity is generally smaller in fluorides than in oxides, largely due to a lower ionic charge, and describe simple structural descriptors that are correlated with its magnitude. Furthermore, we show that the thermal conductivities of most cubic perovskites decrease more slowly than the usual $T^{-1}$ behavior. Within this set, we also screen for materials exhibiting negative thermal expansion. Finally, we describe a strategy to accelerate the discovery of mechanically stable compounds at high temperatures.

  6. Conductive fracture mapping. A study on the correlation between borehole TV- and radar images and difference flow logging results in borehole KLX02

    Energy Technology Data Exchange (ETDEWEB)

    Carlsten, S.; Straahle, A.; Ludvigson, Jan-Erik [GEOSIGMA AB, Uppsala (Sweden)

    2001-10-01

    angle and the recorded borehole length were used as the most important parameters. The accuracy of the recorded length (depth) of the interpreted radar reflectors is rather poor compared to the BIPS-logging. A total number of 6 radar reflectors (of the 12 identified) could be correlated with BIPS-features and DIFF-flow anomalies. As above, the correlated BIPS-features were classified as open fractures or in some cases as veins in the rock. The correlation study indicates that the number of features mapped as 'open fractures' together with 'fractures with cavities' in the BIPS characterisation, correspond to almost 70% of the total number of interpreted flow anomalies from the DIFF-logging in this borehole interval. This figure increases to almost 80% if uncertain flow anomalies below the measurement limit are excluded. The remainder of the flow anomalies correspond to features mapped as 'altered fractures or veins' and 'dull fractures or veins 'in the BIPS- characterisation. The estimated lateral extent of the correlated radar reflectors is about 10-30 m. The latter figure corresponds to the estimated persistence (depth of penetration)of the radar images in this case. The dominant strike of the interpreted flow anomalies is towards WNW-NW as determined from the BIPS- and radar characterisation. This result is in good agreement with previous investigations of the orientation of water-conductive fractures at Aespoe. Thus, it is concluded that the interpreted flow anomalies from the DIFF-log are representative for the dominating hydraulic conditions in the rock. The accuracy of the depth recording is one of the most important parameter and also the one that, in this study, contributes to the largest error when comparing different methods. One of the conclusions of this study is to diminish the error by using efficient measuring wheels in order to avoid sliding of the cable during logging. A new method for making length registration

  7. Conductive fracture mapping. A study on the correlation between borehole TV- and radar images and difference flow logging results in borehole KLX02

    Energy Technology Data Exchange (ETDEWEB)

    Carlsten, S.; Straahle, A.; Ludvigson, Jan-Erik [GEOSIGMA AB, Uppsala (Sweden)

    2001-10-01

    angle and the recorded borehole length were used as the most important parameters. The accuracy of the recorded length (depth) of the interpreted radar reflectors is rather poor compared to the BIPS-logging. A total number of 6 radar reflectors (of the 12 identified) could be correlated with BIPS-features and DIFF-flow anomalies. As above, the correlated BIPS-features were classified as open fractures or in some cases as veins in the rock. The correlation study indicates that the number of features mapped as 'open fractures' together with 'fractures with cavities' in the BIPS characterisation, correspond to almost 70% of the total number of interpreted flow anomalies from the DIFF-logging in this borehole interval. This figure increases to almost 80% if uncertain flow anomalies below the measurement limit are excluded. The remainder of the flow anomalies correspond to features mapped as 'altered fractures or veins' and 'dull fractures or veins 'in the BIPS- characterisation. The estimated lateral extent of the correlated radar reflectors is about 10-30 m. The latter figure corresponds to the estimated persistence (depth of penetration)of the radar images in this case. The dominant strike of the interpreted flow anomalies is towards WNW-NW as determined from the BIPS- and radar characterisation. This result is in good agreement with previous investigations of the orientation of water-conductive fractures at Aespoe. Thus, it is concluded that the interpreted flow anomalies from the DIFF-log are representative for the dominating hydraulic conditions in the rock. The accuracy of the depth recording is one of the most important parameter and also the one that, in this study, contributes to the largest error when comparing different methods. One of the conclusions of this study is to diminish the error by using efficient measuring wheels in order to avoid sliding of the cable during logging. A new method for making length registration

  8. Open-wedge high tibial osteotomy: incidence of lateral cortex fractures and influence of fixation device on osteotomy healing.

    Science.gov (United States)

    Dexel, Julian; Fritzsche, Hagen; Beyer, Franziska; Harman, Melinda K; Lützner, Jörg

    2017-03-01

    Open-wedge high tibial osteotomy (HTO) is an established treatment for young and middle-aged patients with medial compartment knee osteoarthritis and varus malalignment. Although not intended, a lateral cortex fracture might occur during this procedure. Different fixation devices are available to repair such fractures. This study was performed to evaluate osteotomy healing after fixation with two different locking plates. Sixty-nine medial open-wedge HTO without bone grafting were followed until osteotomy healing. In patients with an intact lateral hinge, no problems were noted with either locking plate. A fracture of the lateral cortex occurred in 21 patients (30.4 %). In ten patients, the fracture was not recognized during surgery but was visible on the radiographs at the 6-week follow-up. Lateral cortex fracture resulted in non-union with the need for surgical treatment in three out of eight (37.5 %) patients using the newly introduced locking plate (Position HTO Maxi Plate), while this did not occur with a well-established locking plate (TomoFix) (0 out of 13, p = 0.023). With regard to other adverse events, no differences between both implants were observed. In cases of lateral cortex fracture, fixation with a smaller locking plate resulted in a relevant number of non-unions. Therefore, it is recommended that bone grafting, another fixation system, or an additional lateral fixation should be used in cases with lateral cortex fracture. III.

  9. High-Work-Function Transparent Conductive Oxides with Multilayer Films

    Science.gov (United States)

    Song, Chunyan; Chen, Hong; Fan, Yi; Luo, Jinsong; Guo, Xiaoyang; Liu, Xingyuan

    2012-04-01

    Transparent conductive oxide (TCO) films using WO3/Ag/WO3 (WAW) were fabricated under room temperature conditions. WAW has a low sheet resistance of 12 Ω/sq and a work function of 6.334 eV. This is one of the TCOs with the highest work function. These properties make it useful for application in electroluminescent devices and solar cells. Both theoretical calculation and experimental results show that the two WO3 layers strongly affect transparency, while the Ag layer determines transmittance and electrical performances. These rules can be applied in all dielectric/metal/dielectric structures.

  10. Dynamic model of normal behavior of rock fractures

    Institute of Scientific and Technical Information of China (English)

    YANG Wen-yi; KONG Guang-ya; CAI Jun-gang

    2005-01-01

    Based on laboratory tests of artificial fractures in mortar material, established the dynamic constitutive model of normal behaviour of rock fracture,. The tests were systematically conducted under quasi-static and dynamic monotonic loading conditions. The fractures were of different numbers of asperities in contact and were subsequently of different initial contact areas, which imitated the natural rock fractures. The rate of compressive load applied normal to the fractures covers a wide range from 10-1 MPa/s (quasi-static) up to 103 MPa/s (highly dynamic). The normal stress-closure responses of fractures were measured for different loading rates. Based on the stress-closure relation curves measured, a nonlinear (hyperbolic) dynamic model of fracture, normal behaviour, termed as dynamic BB model, was proposed, which was modified from the existing BB model of static normal behaviour of fractures by taking into account the effect of loading rate.

  11. EFFECTS OF HIGH TEMPERATURE PRETREATMENTS ON HIGH TEMPERATURE FRACTURE BEHAVIOR OF SiC-C/SiC

    Institute of Scientific and Technical Information of China (English)

    X.G. Luan; L.F. Cheng; S.R. Qiao; J. Zhang

    2004-01-01

    The samples made from a SiC-C/SiC composite were pretreated in Ar under creep,fatigue, creep and fatigue interaction, as well as in dry oxygen and wet oxygen under fatigue at 1300℃ for 15 hours. The fracture behaviors of the pretreated samples were investigated at 1300℃. The loading-strain curves and the microstructures of the sample were compared with each other. The various of high temperature tensile behaviors was attributed to the different microstructures resulted from different high temperature pretreatments.

  12. Scaphoid Stress Fracture in High-Level Gymnast: A Case Report

    Directory of Open Access Journals (Sweden)

    J. C. Nakamoto

    2011-01-01

    Full Text Available We present the case of an 18-year-old high-level gymnast who sustained a stress fracture of the scaphoid associated with a distal radial epiphysiolysis. Clinical evaluation demonstrated decreased range of motion of the affected wrist and insidious pain on the snuffbox and tenderness on the distal radial physis. He was submitted to surgical treatment with scaphoid percutaneous fixation and radial styloid process in situ fixation. Clinical features improved, and he got back to competition 6 months after surgery without symptoms and with complete range of motion.

  13. In-Situ Conductivity Measurement of BaF2 under High Pressure and High Temperature

    Institute of Scientific and Technical Information of China (English)

    HAO Ai-Min; LI Xiao-Dong; LIU Jing; GAO Chun-Xiao; LI Ming; HE Chun-Yuan; HUANG Xiao-Wei; ZHANG Dong-Mei; YU Cui-Ling; ZOU Guang-Tian; LI Yan-Chun

    2006-01-01

    @@ We perform the in-situ conductivity measurement on BaF2 at high pressure using a microcircuit fabricated on a diamond anvil cell. The results show that BaF2 initially exhibits the electrical property of an insulator at pressure below 25 Gpa, it transforms to a wide energy gap semiconductor at pressure from 25 to 30 Gpa, and the conductivity increases gradually with increasing pressure from 30 Gpa. However, the metallization predicted by theoretical calculation at 30-33 Gpa cannot be observed. In addition, we measure the temperature dependence of the conductivity at several pressures and obtain the relationship between the energy gap and pressure. Based on the experimental data, it is predicted that BaF2 would transform to a metal at about 87 Gpa and ambient temperature. The conductivity of BaF2 reaches the order of 10-3Ω-1 cm-1 at 37 Gpa and 2400 K, the superionic conduction is not observed during the experiments, indicating the application of pressure elevates greatly the transition temperature of the superionic conduction.

  14. New family of lithium salts for highly conductive nonaqueous electrolytes.

    Science.gov (United States)

    Barbarich, Thomas J; Driscoll, Peter F; Izquierdo, Suzette; Zakharov, Lev N; Incarvito, Christopher D; Rheingold, Arnold L

    2004-11-29

    New lithium salts of weakly coordinating anions were prepared by treating lithium imidazolates or LiN(CH3)2 with 2 equiv of BF(3). They are LiIm(BF3)2, Li 2-MeIm(BF3)2, Li 4-MeIm(BF3)2, LiBenzIm(BF3)2, Li 2-iPrIm(BF3)2, and LiN(CH3)2(BF3)2 (Im=imidazolate, Me=methyl, iPr=isopropyl, BenzIm=benzoimidazolate). The salts were characterized by NMR spectroscopy and mass spectrometry. The structure of LiBenzIm(BF3)2 consists of a dimeric centrosymmetric unit with each lithium atom forming a bridge between the two anions through one fluorine contact to each anion. The structure of a hydrate of LiN(CH3)2(BF3)2 consists of an infinite chain in which each anion chelates two different lithium atoms through Li-F bonds. The conductivities of electrolyte solutions of these salts were measured and are discussed in terms of different ion-pairing modes determined from the solid-state structures, the anion's ability to distribute charge, and solution viscosity. Organic carbonate solutions of LiIm(BF3)2 partially disproportionate at 85 degrees C forming LiBF4, LiBF2[Im(BF3)]2, and Li[(BF3)ImBF2ImBF2Im(BF3)], reaching equilibrium by 3 months at 85 degrees C but not disproportionating at room temperature after 9 months. A mechanism for the formation of these disproportionation products is proposed. The lower conductivity of the 1 M LiIm(BF3)2 solution that has undergone disproportionation is attributed to the formation LiBF4, which is less conductive, and LiBF2[Im(BF3)]2 and Li[(BF3)ImBF2ImBF2Im(BF3)], which increase solution viscosity.

  15. High-Conductance Thermal Interfaces Based on Carbon Nanotubes Project

    Data.gov (United States)

    National Aeronautics and Space Administration — We propose to develop a novel thermal interface material (TIM) that is based on an array of vertical carbon nanotubes (CNTs) for high heat flux applications. For...

  16. Highly Confined Electronic and Ionic Conduction in Oxide Heterostructures

    DEFF Research Database (Denmark)

    Pryds, Nini

    2015-01-01

    . “Enhancement of the chemical stability in confined δ-Bi2O3”. Nature Materials (2015) doi:10.1038/nmat4266 [2] Y. Z. Chen et al. “A high-mobility two-dimensional electron gas at the spinel/perovskite interface of γ-Al2O3/SrTiO3”. Nature Commun. 4, 1371 (2013) [3] Y. Z. Chen et al. “Creation of High Mobility Two...

  17. A Study on the Fracture Control of Rock Bolts in High Ground Pressure Roadways of Deep Mines

    Directory of Open Access Journals (Sweden)

    Wen Jinglin

    2015-01-01

    Full Text Available According to the frequent fractures of rock bolts in high ground pressure roadways of deep mines, this paper analyzes the mechanism of fractures and concludes that high ground pressure and material de-fects are main reasons for the fracture of rock bolts. The basic idea of fracture control of rock bolts in high ground pressure roadways of deep mines is to increase the yield load and the limit load of rock bolt materials and reduce the actual load of rock bolts. There are four ways of controlling rock bolt fracture: increasing the rock bolt diameter, strengthening bolt materials, weakening support rigidity and the implementation of double supporting. With the roadway support of the 2302 working face of a coal mine as the project background, this paper carries out a study on the effect of two schemes, increasing the rock bolt diameter and the double supporting technique through methods of theoretical analysis, numerical simulation and so on. It determines the most reasonable diam-eter of rock bolts and the best delay distance of secondary support. Practices indicate that rock bolt fracture can be effectively controlled through the double supporting technique, which strengthens the roof and two sides through the first supporting technique and strengthens side angles through the secondary supporting technique.

  18. Synthesis and sintering of ceramic nanocomposites with high mixed conductivity

    Directory of Open Access Journals (Sweden)

    Zyryanov V.V.

    2005-01-01

    Full Text Available Metastable solid solutions of complex oxides with fluorite and perovskite structures are obtained by mechanosynthesis. Dense ceramics on the base of these metastable phases was obtained by thermal sintering of nanopowders due to kinetic stabilization. Different degrees of a chemical interaction (interdiffusion are observed during sintering of "perovskite+fluorite" and "perovskite+perovskite" composites. It is shown, that optimization of the composition, mixing conditions of individual phases and their sintering, preparation of ceramic composites with mixed conductivity for use in catalytic membrane reactors is possible. Unusual behavior of complex perovskites and fluorites is discovered during sintering, enabling determination of an optimum sintering temperature and time for which a qualitative explanation is given. It is established that rearrangement of fine crystalline particles as a whole plays a key role in shrinkage.

  19. Development of high performance proton-conducting solid electrolytes

    Energy Technology Data Exchange (ETDEWEB)

    Linkous, C.A.; Kopitzke, R.W. [Florida Solar Energy Center, Cocoa, FL (United States)

    1998-08-01

    This work seeks to improve the efficiency of fuel cell and electrolyzer operation by developing solid electrolytes that will function at higher temperatures. Two objectives were pursued: (1) determine the mechanism of hydrolytic decomposition of aromatic sulfonic acid ionomers, with the intent of identifying structural weaknesses that can be avoided in future materials; and (2) identify new directions in solid electrolyte development. After evaluating a number of aromatic sulfonates, it became apparent that no common mechanism was going to be found; instead, each polymer had its own sequence of degradation steps, involving some combination of desulfonation and/or chain scission. For electrochemical cell operation at temperatures > 200 C, it will be necessary to develop solid electrolytes that do not require sulfonic acids and do not require water to maintain its conductivity mechanism.

  20. [Prevalence of hip, femur and knee fractures at the High Specialty Medical Unit, Hospital de Traumatología y Ortopedia "Lomas Verdes", Instituto Mexicano del Seguro Social].

    Science.gov (United States)

    Lovato-Salas, F; Luna-Pizarro, D; Oliva-Ramírez, S A; Flores-Lujano, J; Núñez-Enríquez, J C

    2015-01-01

    Lower limb fractures are more frequent among older patients with osteopenia after a low energy fall and/or among young patients who sustain a high energy trauma. The prevalence of hip, femur and knee fractures at the High Specialty Medical Unit, Hospital de Traumatología y Ortopedia "Lomas Verdes" is unknown. Cross-sectional study, descriptive and retrospective design. Cases with low extremity fractures treated from January 1st, 2012 to December 31st, 2013 at the Hip, Femur and Knee Service, High Specialty Medical Unit, Hospital de Traumatología y Ortopedia "Lomas Verdes", were reviewed. Most patients (52.2%) were females; 64.1% of patients were over 60 years of age. Fracture distribution according to the segment involved was as follows: 73.4% (n = 1,327) were femur fractures, 13.5% (n = 244) tibial plateau fractures, and 13.2% (n = 238) patellar fractures. 66.8% (n = 1,209) of patients had a long hospital stay (more than 10 days). According to the anatomical location of fractures, transtrochanteric fractures (49.1%) were the most frequent ones, followed by patellar fractures (13.2%), and femur shaft fractures (12.7%). The prevalence of lower limb fractures at our hospital corresponds to what has been reported internationally.

  1. A methodology to constrain the parameters of a hydrogeological discrete fracture network model for sparsely fractured crystalline rock, exemplified by data from the proposed high-level nuclear waste repository site at Forsmark, Sweden

    Science.gov (United States)

    Follin, Sven; Hartley, Lee; Rhén, Ingvar; Jackson, Peter; Joyce, Steven; Roberts, David; Swift, Ben

    2014-03-01

    The large-scale geological structure of the crystalline rock at the proposed high-level nuclear waste repository site at Forsmark, Sweden, has been classified in terms of deformation zones of elevated fracture frequency. The rock between deformation zones was divided into fracture domains according to fracture frequency. A methodology to constrain the geometric and hydraulic parameters that define a discrete fracture network (DFN) model for each fracture domain is presented. The methodology is based on flow logging and down-hole imaging in cored boreholes in combination with DFN realizations, fracture connectivity analysis and pumping test simulations. The simulations suggest that a good match could be obtained for a power law size distribution where the value of the location parameter equals the borehole radius but with different values for the shape parameter, depending on fracture domain and fracture set. Fractures around 10-100 m in size are the ones that typically form the connected network, giving inflows in the simulations. The report also addresses the issue of up-scaling of DFN properties to equivalent continuous porous medium (ECPM) bulk flow properties. Comparisons with double-packer injection tests provide confidence that the derived DFN formulation of detailed flows within individual fractures is also suited to simulating mean bulk flow properties and their spatial variability.

  2. Mesoscale modeling of grain fracturing in high porosity rocks using the strong discontinuity approach

    Science.gov (United States)

    Tjioe, M.; Choo, J.; Borja, R. I.

    2013-12-01

    In previous studies, it has been found that two dominant micro-mechanisms play important roles in the deformation of high-porosity rocks. They are grain fracturing and crystal plasticity. Grain fracturing is a phenomenon where larger grains cleave to their smaller constituents as they respond to the stress concentration exerted on them close to the open pore spaces. Specimen-scale modeling cannot reflect such mechanism so our investigation is carried out in the next smaller scale, namely the mesoscopic scale. We model a solid matrix microstructure using finite element in which displacement discontinuity is introduced in each element where the slip condition has been exceeded. Such discontinuity is termed strong discontinuity and is characterized by zero band thickness and localized strain in the band that reaches infinity. For grains under compression, this slip condition is the cohesive-frictional law governing the behavior on the surface of discontinuity. The strong discontinuity in the grain scale is modeled via an Assumed Enhanced Strain (AES) method formulated within the context of nonlinear finite elements. Through this method, we can model grain-splitting as well as halos of cataclastic damage that are usually observed before a macropore collapses. The overall stress-strain curve and plastic slip of the mesoscopic element are then obtained and comparison to the crystal plasticity behavior is made to show the differences between the two mechanisms. We demonstrate that the incorporation of grain-fracturing and crystal plasticity can shed light onto the pore-scale deformation of high-porosity rocks.

  3. Combined Microwave Ablation and Cementoplasty in Patients with Painful Bone Metastases at High Risk of Fracture

    Energy Technology Data Exchange (ETDEWEB)

    Pusceddu, Claudio, E-mail: clapusceddu@gmail.com [Regional Referral Center for Oncologic Diseases, Division of Interventional Radiology, Department of Oncological Radiology, Ocological Hospital “A. Businco” (Italy); Sotgia, Barbara, E-mail: barbara.sotgia@gmail.com; Fele, Rosa Maria, E-mail: rosellafele@tiscali.it [Regional Referral Center for Oncological Diseases, Department of Oncological Radiology, Oncological Hospital “A. Businco” (Italy); Ballicu, Nicola, E-mail: nicolaballicu77@gmail.com [Regional Referral Center for Oncologic Diseases, Division of Interventional Radiology, Department of Oncological Radiology, Ocological Hospital “A. Businco” (Italy); Melis, Luca, E-mail: doclucamelis@tiscali.it [Regional Referral Center for Oncological Diseases, Department of Oncological Radiology, Oncological Hospital “A. Businco” (Italy)

    2016-01-15

    PurposeTo retrospectively evaluate the effectiveness of computed tomography-guided percutaneous microwave ablation (MWA) and cementoplasty in patients with painful bone metastases at high risk of fracture.Materials and MethodsThirty-five patients with 37 metastatic bone lesions underwent computed tomography-guided MWA combined with cementoplasty (polymethylmethacrylate injection). Vertebrae, femur, and acetabulum were the intervention sites and the primary end point was pain relief. Pain severity was estimated by visual analog scale (VAS) before treatment; 1 week post-treatment; and 1, 6, and 12 months post-treatment. Functional outcome was assessed by improved patient walking ability. Radiological evaluation was performed at baseline and 3 and 12 months post-procedure.ResultsIn all patients, pain reduction occurred from the first week after treatment. The mean reduction in the VAS score was 84, 90, 90 % at week 1, month 1, and month 6, respectively. Improved walking ability occurred in 100 and 98 % of cases at the 1- and 6-month functional outcome evaluations, respectively. At the 1-year evaluation, 25 patients were alive, and 10 patients (28 %) had died because of widespread disease. The mean reduction in the VAS score and improvement in surviving patients’ walking ability were 90 and 100 %, respectively. No patients showed evidence of local tumor recurrence or progression and pathological fracture in the treated sites.ConclusionOur results suggest that MWA combined with osteoplasty is safe and effective when treating painful bone metastases at high risk of fracture. The number of surviving patients at the 1-year evaluation confirms the need for an effective and long-lasting treatment.

  4. Irradiation dose and temperature dependence of fracture toughness in high dose HT9 steel from the fuel duct of FFTF

    Energy Technology Data Exchange (ETDEWEB)

    Byun, Thak Sang, E-mail: byunts@ornl.gov [Oak Ridge National Laboratory, Oak Ridge, TN 37831 (United States); Toloczko, Mychailo B. [Pacific Northwest National Laboratory, Richland, WA 99352 (United States); Saleh, Tarik A.; Maloy, Stuart A. [Los Alamos National Laboratory, Los Alamos, NM 87545 (United States)

    2013-01-15

    To expand the knowledge base for fast reactor core materials, fracture toughness has been evaluated for high dose HT9 steel using miniature disk compact tension (DCT) specimens. The HT9 steel DCT specimens were machined from the ACO-3 fuel duct of the Fast Flux Test Facility (FFTF), which achieved high doses in the range of 3-148 dpa at 378-504 Degree-Sign C. The static fracture resistance (J-R) tests have been performed in a servohydraulic testing machine in vacuum at selected temperatures including room temperature, 200 Degree-Sign C, and each irradiation temperature. Brittle fracture with a low toughness less than 50 MPa {radical}m occurred in room temperature tests when irradiation temperature was below 400 Degree-Sign C, while ductile fracture with stable crack growth was observed when irradiation temperature was higher. No fracture toughness less than 100 MPa {radical}m was measured when the irradiation temperature was above 430 Degree-Sign C. It was shown that the influence of irradiation temperature was dominant in fracture toughness while the irradiation dose has only limited influence over the wide dose range 3-148 dpa. A slow decrease of fracture toughness with test temperature above room temperature was observed for the nonirradiated and high temperature (>430 Degree-Sign C) irradiation cases, which indicates that the ductile-brittle transition temperatures (DBTTs) in those conditions are lower than room temperature. A comparison with the collection of existing data confirmed the dominance of irradiation temperature in the fracture toughness of HT9 steels.

  5. Geothermal fracture stimulation technology. Volume II. High-temperature proppant testing

    Energy Technology Data Exchange (ETDEWEB)

    1980-07-01

    Data were obtained from a newly built proppant tester, operated at actual geothermal temperatures. The short term test results show that most proppants are temperature sensitive, particularly at the higher closure stresses. Many materials have been tested using a standard short-term test, i.e., fracture-free sand, bauxite, and a resin-coated sand retained good permeability at the high fluid temperatures in brine over a range of closure stresses. The tests were designed to simulate normal closure stress ranges for geothermal wells which are estimated to be from 2000 to 6000 psi. Although the ultra high closure stresses in oil and gas wells need not be considered with present geothermal resources, there is a definite need for chemically inert proppants that will retain high permeability for long time periods in the high temperature formations.

  6. Thermal Conductivity of Foam Glasses Prepared using High Pressure Sintering

    DEFF Research Database (Denmark)

    Østergaard, Martin Bonderup; Petersen, Rasmus Rosenlund; König, Jakob

    with open or closed pores. If only open pores exist, air is the dominating medium for the insulating effect. However, closed pores make it possible to trap gases inside the foam. The gas can be introduced either chemically, through foaming agents, or physically, by gas compression-decompression at high...... using helium, nitrogen, or argon. The sintering result in closed-porous body with high pressure bubbles. Subsequent reheating above the glass transition temperature resulted in an expansion of the bubbles. The entrapped gas composition was analysed by gas chromatography. Furthermore, we investigated how...

  7. Profile and procedures for fractures among 1323 fracture patients from the 2010 Yushu earthquake, China.

    Science.gov (United States)

    Kang, Peng; Tang, Bihan; Liu, Yuan; Liu, Xu; Shen, Yan; Liu, Zhipeng; Yang, Hongyang; Zhang, Lulu

    2016-11-01

    The injuries caused by earthquakes are often complex and of various patterns. Our study included all fracture inpatients from the Yushu earthquake (1323 in total), to learn more about the incidence and distribution of fractures during earthquakes. A retrospective study of the clinical characteristics of hospitalized fracture patients after the 2010 Yushu earthquake was conducted from December 20 to 25, 2010.We reviewed medical records of hospitalized patients who had been evacuated from the Yushu earthquake area between April 14 and June 15, 2010, from 57 hospitals, and also reviewed more than 100 documents assembled from daily medical rescue and disease prevention reports submitted by the frontline rescue organizations. In total, 78.0% of fracture patients were admitted to the hospital within 3 days after the earthquake. There were 1323 patients who presented with 1539 fractures. The most common fracture occurred in the lower limbs, followed by spinal, pelvic, and shoulder-upper limb fractures. The end of the thoracic vertebra and the lumbar vertebra were the high-risk sites for vertebral fractures. A total of 38 patients became paraplegic. A 2-level spatial clustering was detected among the 193 patients presenting with 2 fractures. Analysis profiles of the injuries and clinical features of patients with earthquake-related fractures will positively impact rescue efforts and the treatment of fracture injuries caused by possible future natural disasters. We should assemble orthopedic-related medications and surgical equipment, and allocate them promptly after a major earthquake. Copyright © 2016 Elsevier Inc. All rights reserved.

  8. Electrochemical Properties for Co-Doped Pyrite with High Conductivity

    Directory of Open Access Journals (Sweden)

    Yongchao Liu

    2015-09-01

    Full Text Available In this paper, the hydrothermal method was adopted to synthesize nanostructure Co-doped pyrite (FeS2. The structural properties and morphology of the synthesized materials were characterized using X-ray diffraction (XRD and scanning electron microscopy (SEM, respectively. Co in the crystal lattice of FeS2 could change the growth rate of different crystal planes of the crystal particles, which resulted in various polyhedrons with clear faces and sharp outlines. In addition, the electrochemical performance of the doping pyrite in Li/FeS2 batteries was evaluated using the galvanostatic discharge test, cyclic voltammetry and electrochemical impedance spectroscopy. The results showed that the discharge capacity of the doped material (801.8 mAh·g−1 with a doping ratio of 7% was significantly higher than that of the original FeS2 (574.6 mAh·g−1 because of the enhanced conductivity. Therefore, the doping method is potentially effective for improving the electrochemical performance of FeS2.

  9. High rechargeable sodium metal-conducting polymer batteries

    Science.gov (United States)

    Guerfi, A.; Trottier, J.; Gagnon, C.; Barray, F.; Zaghib, K.

    2016-12-01

    Rechargeable lithium batteries accelerated the wireless revolution over the last two decades, and they are now a mature technology for transportation applications in electric vehicles (EV). However, numerous studies have concluded that the proven lithium reserves can hardly absorb the growth in demand. Therefore, sustainable sodium batteries are being considered to overcome the lithium resource shortages that may arise from large-scale application in EVs and stationary energy storage. It is difficult to find a suitable host material for reversible Na-ion storage due to the size of the Na+ ion (0.102 nm) compared to the Li+ ion (0.076 nm). Here we report a low cost and simple sodium technology that is based on a metal-free cathode material. Sodium metal was used as the anode with a conducting polymer cathode and electrochemically tested in a liquid electrolyte. With this technology, a host material for Na intercalation is not required, and because a polymer conductor is used, the size of the Na ion is not an issue.

  10. Scapular fractures and concomitant injuries

    Directory of Open Access Journals (Sweden)

    Akaraborworn Osaree

    2012-11-01

    Full Text Available 【Abstract】 Objective: The association of scapular fractures with other life-threatening injuries including blunt thoracic aortic injury is widely recognized. Few studies have investigated this presumed association. In this study, we investigated the incidence of significant associated injuries with scapular fracture and their outcomes. Methods: A retrospective study was conducted from 2005 to 2009 in a level I trauma center in Thailand. All blunt trauma patients were identified. Patients’ demographics, injury mechanism, associated injuries, Injury Severity Score (ISS, and survival outcomes were recorded. The manage-ment of associated injuries with scapular fracture was reviewed, and the risk factors for mortality were identified. Results: Among the 7 345 trauma patients admitted, scapular fractures occurred in 84 cases (1.1%. The mean age was (37.98±15.21 years. Motorcycle crash was the most fre-quent mechanism of injury, occurring in 51 cases (60.7%. Seventy-four patients (88.1% suffering from scapular frac-tures had associated injuries: 5 (6.0% had significant chest injuries, but none of them had blunt thoracic aortic injury. Two patients (2.4% with scapular fractures died. Factors determining the likelihood of mortality were: (1 ISS>25 (LR=8.5, P<0.05; (2 significant associated chest injury (AIS>3, LR=5.3, P<0.05 and (3 significant associated ab-dominal injury (AIS>3, LR=5.3, P<0.05. Conclusion: A blunt scapular fracture may not accom-pany a blunt thoracic aortic injury but it is strongly related to other injuries like chest injury, extremity injury, head injury, etc. If a scapular fracture is found with a high ISS score, high chest or abdomen AIS score, the patient would have a high risk of mortality. Key words: Aortic rupture; Shoulder fractures; Mul-tiple trauma; Mortality

  11. Damage-control orthopedics versus early total care in the treatment of borderline high-energy pelvic fractures.

    Science.gov (United States)

    Han, Gengfen; Wang, Ziming; Du, Quanyin; Xiong, Yan; Wang, Yu; Wu, Siyu; Zhang, Bo; Wang, Aimin

    2014-12-01

    The purpose of this study was to compare the effectiveness of damage-control orthopedics (DCO) vs early total care (ETC) in the treatment of borderline high-energy pelvic fractures. Seventy-two patients with borderline high-energy pelvic fractures were retrospectively reviewed; 39 received DCO and 33 received ETC. Demographic data and initial injury severities were comparable between groups, except for Abbreviated Injury Scale (AIS) head scores and Glasgow Coma Scale (GCS) scores. Regarding postoperative complications, the incidence rates of acute lung injury and acute respiratory distress syndrome and the mean Acute Physiology and Chronic Health Evaluation II (APACHE II) score were significantly lower in the DCO group compared with the ETC group. Similar results were also observed in subgroups stratified by age (younger than 40 years and 40 years and older). Regarding patients with Tile B fractures, there was no significant difference between groups in incidence rates of overall postoperative complications. However, in patients with Tile C fractures, especially in those 40 years and older, the DCO group had a lower incidence rate of ALI and had lower APACHE II scores than did the ETC group. This study's findings indicate that DCO is the most suitable therapeutic option for patients with Tile C fractures, especially for those 40 years and older, whereas ETC is preferred for patients with Tile B fractures, provided that it is possible to avoid a second operation as well as any delays in patient mobilization.

  12. Crushing and Fracture of Lightweight Structures

    DEFF Research Database (Denmark)

    Urban, Jesper

    2003-01-01

    . Crushing experiments conducted on full-scale aluminum plate intersections reveal that the crushing behaviour is highly affected by material fracture during the deformation. Several fracture criteria from the literature have been reviewed and three fracture models have been compared with material...... criteria for first-ply failure of unidirectional composites (UD), from the literature, are compared with experiments conducted on composite specimens. It is found that a failure criterion by Chang and Chang (1987) agrees well with the experiments on UD. A progressive failure procedure by Chang and Chang...

  13. Influence of dehydration on the electrical conductivity of epidote and implications for high-conductivity anomalies in subduction zones

    Science.gov (United States)

    Hu, Haiying; Dai, Lidong; Li, Heping; Hui, Keshi; Sun, Wenqing

    2017-04-01

    The anomalously high electrical conductivities ( 0.1 to 1 S/m) in deep mantle wedge regions extensively detected by magnetotelluric studies are often associated with the presence of fluids released from the progressive dehydration of subducting slabs. Epidote minerals are the Ca-Al-rich hydrous silicates with huge stability fields exceeding those of amphibole (>70-80 km) in subducting oceanic crust, and they may therefore be transported to greater depth than amphibole and release water to the mantle wedge. In this study, the electrical conductivities of epidote were measured at 0.5-1.5 GPa and 573-1273 K by using a Solartron-1260 Impedance/Gain-Phase Analyzer in a YJ-3000t multianvil pressure within the frequency range of 0.1-106 Hz. The results demonstrate that the influence of pressure on electrical conductivity of epidote is relatively small compared to that of temperature. The dehydration reaction of epidote is observed through the variation of electrical conductivity around 1073 K, and electrical conductivity reaches up to 1 S/m at 1273 K, which can be attributed to aqueous fluid released from epidote dehydration. After sample dehydration, electrical conductivity noticeably decreases by as much as nearly a log unit compared with that before dehydration, presumably due to a combination of the presence of coexisting mineral phases and aqueous fluid derived from the residual epidote. Taking into account the petrological and geothermal structures of subduction zones, it is suggested that the aqueous fluid produced by epidote dehydration could be responsible for the anomalously high conductivities in deep mantle wedges at depths of 70-120 km, particularly in hot subduction zones.

  14. Incidence and Predictors of Multiple Fractures Despite High Adherence to Oral Bisphosphonates

    DEFF Research Database (Denmark)

    Hawley, Samuel; Javaid, M Kassim; Rubin, Katrine H

    2016-01-01

    with high adherence. Fractures were considered after six months from treatment initiation and up to six months after discontinuation. Data from computerized records and pharmacy invoices were obtained from Sistema d'Informació per al Desenvolupament de l'Investigació en Atenció Primària (SIDIAP) (Catalonia...... predictors of ≥2 FWOT among patients having persisted with treatment ≥6months with overall medication possession ratio (MPR) ≥80%. Incidence of ≥2 FWOT was 2.4 (95% Confidence Interval (CI): 1.8-3.2) and 1.7 (95% CI: 1.2-2.2) per 1000 Person Years (PYs) within Catalonia and Denmark respectively. Older age...... of ≥2 FWOT identified within only one cohort were dementia, SHR = 4.46 (95% CI: 1.02-19.4) (SIDIAP) and history of recent or older fracture, SHR = 3.40 (95% CI: 1.50-7.68) and SHR = 2.08 (95% CI: 1.04-4.15) respectively (Denmark). Even among highly adherent users of oral BP therapy, a minority sustain...

  15. [FRAX® thresholds to identify people with high or low risk of osteoporotic fracture in Spanish female population].

    Science.gov (United States)

    Azagra, Rafael; Roca, Genís; Martín-Sánchez, Juan Carlos; Casado, Enrique; Encabo, Gloria; Zwart, Marta; Aguyé, Amada; Díez-Pérez, Adolf

    2015-01-06

    To detect FRAX(®) threshold levels that identify groups of the population that are at high/low risk of osteoporotic fracture in the Spanish female population using a cost-effective assessment. This is a cohort study. Eight hundred and sixteen women 40-90 years old selected from the FRIDEX cohort with densitometry and risk factors for fracture at baseline who received no treatment for osteoporosis during the 10 year follow-up period and were stratified into 3 groups/levels of fracture risk (low20%) according to the real fracture incidence. The thresholds of FRAX(®) baseline for major osteoporotic fracture were: low riskrisk (3.6%; 95% CI 2.2-5.9), intermediate risk (13.7%; 95% CI 7.1-24.2) and high risk (21.4%; 95% CI12.9-33.2). The most cost-effective option was to refer to dual energy X-ray absorptiometry (DXA-scan) for FRAX(®)≥ 5 (Intermediate and high risk) to reclassify by FRAX(®) with DXA-scan at high/low risk. These thresholds select 17.5% of women for DXA-scan and 10% for treatment. With these thresholds of FRAX(®), compared with the strategy of opportunistic case finding isolated risk factors, would improve the predictive parameters and reduce 82.5% the DXA-scan, 35.4% osteoporosis prescriptions and 28.7% cost to detect the same number of women who suffer fractures. The use of FRAX ® thresholds identified as high/low risk of osteoporotic fracture in this calibration (FRIDEX model) improve predictive parameters in Spanish women and in a more cost-effective than the traditional model based on the T-score ≤ -2.5 of DXA scan. Copyright © 2013 Elsevier España, S.L.U. All rights reserved.

  16. Preparation and Property Study of Graphene Oxide Reinforced Epoxy Resin Insulation Nanocomposites with High Heat Conductivity

    Science.gov (United States)

    Shan, Xinran; Liu, Yongchang; Wu, Zhixiong; Liu, Huiming; Zhang, Zhong; Huang, Rongjin; Huang, Chuanjun; Liu, Zheng; Li, Laifeng

    2017-02-01

    In this paper, graphene oxide reinforced epoxy resin nanocomposites were successfully prepared. Compared with unmodified epoxy resin, the heat conductivity of the graphene oxide reinforced epoxy resin nanocomposites had been improved while keeping the insulation performance. The tensile strength was investigated at both room temperature (300 K) and liquid nitrogen temperature (77 K). And the fracture surfaces were examined by scanning electron microscopy (SEM). Results showed that the materials had excellent mechanical properties, which could be advantages for the applications as insulating layer in low temperature superconducting magnets.

  17. On the intergranular fracture behavior of high-temperature plastic deformation of 1420 Al-Li alloy

    Institute of Scientific and Technical Information of China (English)

    2002-01-01

    The tensile deformation hot simulation test of as-cast 1420 Al-Li alloy was performed on Gleeble-1500 Thermal Simulator in the deformation temperature range from 350 to 450 ℃, and the strain rate range from 0.01 to 10.0 s-1.The tensile fracture behavior of the 1420 Al-Li alloy at high temperature was studied experimently. The results show that the tensile fracture mode of the 1420 Al-Li alloy at high temperature is changed from typical transgranular ductile fracture to intergranular brittle fracture with the increase of the deformation temperature and the strain rate. It is made out that the precipitation of LiH is the fundamental reason for the intergranular brittle fracture of the 1420 Al-Li alloy at high temperature. The mechanism of hydrogen embrittlement of the 1420 Al-Li alloy at high temperature was discussed, and it was proposed that the hydrogen embrittlement at high temperature is an integrated function of the dynamic and the static force, which enrichs the theories of hydrogen embrittlement.

  18. High quality transparent conductive electrodes in organic photovoltaic devices

    Energy Technology Data Exchange (ETDEWEB)

    Chakaroun, M. [XLIM Institute, UMR 6172, Universite de Limoges/CNRS, 123 Avenue Albert Thomas, 87060 Limoges (France); Lucas, B., E-mail: bruno.lucas@unilim.f [XLIM Institute, UMR 6172, Universite de Limoges/CNRS, 123 Avenue Albert Thomas, 87060 Limoges (France); Ratier, B. [XLIM Institute, UMR 6172, Universite de Limoges/CNRS, 123 Avenue Albert Thomas, 87060 Limoges (France); Defranoux, C.; Piel, J.P. [SOPRA-SA, 26 rue Pierre Joigneaux, 92270 Bois-Colombes (France); Aldissi, M. [XLIM Institute, UMR 6172, Universite de Limoges/CNRS, 123 Avenue Albert Thomas, 87060 Limoges (France)

    2009-12-15

    The use of indium tin oxide (ITO) in conjunction with polymeric substrates requires deposition at low temperatures or room temperature, and with a limited or no thermal treatment. This process results in high resistivity materials. To achieve practical resistivity levels, we replaced ITO, the workhorse in organic optoelectronic devices, with an ITO/Ag/ITO tri-layer anode. This material yielded the desired electrical properties without a significant effect on its optical properties. For example, a sheet resistance of 15 {Omega}/{open_square} and an optical transmission of 90% at 550 nm were obtained for a tri-layer film in which thickness of each ITO layer is 50 nm and the Ag layer thickness is 8 nm. The use of these tri-layer anodes in CuPc-C{sub 60}-based organic solar cells led to an increase in the fill factor under illumination, and thus an improvement of the external power conversion efficiency.

  19. Field fracturing multi-sites project. Annual report, August 1, 1995--July 31, 1996

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1996-12-31

    The objective of the Field Fracturing Multi-Sites Project (M-Site) is to conduct experiments to definitively determine hydraulic fracture dimensions using remote well and treatment well diagnostic techniques. In addition, experiments are to be conducted to provide data that will resolve significant unknowns with regard to hydraulic fracture modeling, fracture fluid rheology and fracture treatment design. These experiments will be supported by a well-characterized subsurface environment, as well as surface facilities and equipment conducive to acquiring high-quality data. The primary Project goal is to develop a fully characterized, tight reservoir-typical, field-scale hydraulic fracturing test site to diagnose, characterize, and test hydraulic fracturing technology and performance. It is anticipated that the research work being conducted by the multi-disciplinary team of GRI and DOE contractors will lead to the development of a commercial fracture mapping tool/service.

  20. Investigation of temperature dependence of fracture toughness in high-dose HT9 steel using small-specimen reuse technique

    Energy Technology Data Exchange (ETDEWEB)

    Baek, Jong-Hyuk [KAERI; Byun, Thak Sang [ORNL; Maloy, S [Los Alamos National Laboratory (LANL); Toloczko, M [Pacific Northwest National Laboratory (PNNL)

    2014-01-01

    The temperature dependence of fracture toughness in HT9 steel irradiated to 3 145 dpa at 380 503 C was investigated using miniature three-point bend (TPB) fracture specimens. A miniature-specimen reuse technique has been established: the tested halves of subsize Charpy impact specimens with dimensions of 27 mm 3mm 4 mm were reused for this fracture test campaign by cutting a notch with a diamond-saw in the middle of each half, and by fatigue-precracking to generate a sharp crack tip. It was confirmed that the fracture toughness of HT9 steel in the dose range depends more strongly on the irradiation temperature than the irradiation dose. At an irradiation temperature <430 C, the fracture toughness of irradiated HT9 increased with the test temperature, reached an upper shelf of 180 200 MPa ffiffiffiffiffi m p at 350 450 C, and then decreased with the test temperature. At an irradiation temperatureP430 C, the fracture toughness was nearly unchanged up to about 450 C and decreased slowly with test temperatures in a higher temperature range. Such a rather monotonic test temperature dependence after high-temperature irradiation is similar to that observed for an archive material generally showing a higher degree of toughness. A brittle fracture without stable crack growth occurred in only a few specimens with relatively lower irradiation and test temperatures. In this discussion, these TPB fracture toughness data are compared with previously published data from 12.7 mm diameter disc compact tension (DCT) specimens.

  1. Investigation of temperature dependence of fracture toughness in high-dose HT9 steel using small-specimen reuse technique

    Energy Technology Data Exchange (ETDEWEB)

    Baek, Jong-Hyuk, E-mail: jhbaek@kaeri.re.kr [Korea Atomic Energy Research Institute, Daejeon 305-353 (Korea, Republic of); Oak Ridge National Laboratory, Oak Ridge, TN 37831 (United States); Byun, Thak Sang [Oak Ridge National Laboratory, Oak Ridge, TN 37831 (United States); Maloy, Start A. [Los Alamos National Laboratory, Los Alamos, NM 87545 (United States); Toloczko, Mychailo B. [Pacific Northwest National Laboratory, Richland, WA 99352 (United States)

    2014-01-15

    The temperature dependence of fracture toughness in HT9 steel irradiated to 3–145 dpa at 380–503 °C was investigated using miniature three-point bend (TPB) fracture specimens. A miniature-specimen reuse technique has been established: the tested halves of subsize Charpy impact specimens with dimensions of 27 mm × 3 mm × 4 mm were reused for this fracture test campaign by cutting a notch with a diamond-saw in the middle of each half, and by fatigue-precracking to generate a sharp crack tip. It was confirmed that the fracture toughness of HT9 steel in the dose range depends more strongly on the irradiation temperature than the irradiation dose. At an irradiation temperature <430 °C, the fracture toughness of irradiated HT9 increased with the test temperature, reached an upper shelf of 180–200MPa√(m) at 350–450 °C, and then decreased with the test temperature. At an irradiation temperature ⩾430 °C, the fracture toughness was nearly unchanged up to about 450 °C and decreased slowly with test temperatures in a higher temperature range. Such a rather monotonic test temperature dependence after high-temperature irradiation is similar to that observed for an archive material generally showing a higher degree of toughness. A brittle fracture without stable crack growth occurred in only a few specimens with relatively lower irradiation and test temperatures. In this discussion, these TPB fracture toughness data are compared with previously published data from 12.7 mm diameter disc compact tension (DCT) specimens.

  2. Investigation of temperature dependence of fracture toughness in high-dose HT9 steel using small-specimen reuse technique

    Energy Technology Data Exchange (ETDEWEB)

    Baek, Jong-Hyuk; Byun, Thak Sang; Maloy, Stuart A.; Toloczko, Mychailo B.

    2014-01-01

    The temperature dependence of fracture toughness in HT9 steel irradiated to 3–145 dpa at 380–503 degrees*C was investigated using miniature three-point bend (TPB) fracture specimens. A miniature-specimen reuse technique has been established: the tested halves of subsize Charpy impact specimens with dimensions of 27 mm *3mm* 4 mm were reused for this fracture test campaign by cutting a notch with a diamond-saw in the middle of each half, and by fatigue-precracking to generate a sharp crack tip. It was confirmed that the fracture toughness of HT9 steel in the dose range depends more strongly on the irradiation temperature than the irradiation dose. At an irradiation temperature <430 *degreesC, the fracture toughness of irradiated HT9 increased with the test temperature, reached an upper shelf of 180—200 MPa*m^.5 at 350–450 degrees*C, and then decreased with the test temperature. At an irradiation temperature >430 degrees*C, the fracture toughness was nearly unchanged up to about 450 *degreesC and decreased slowly with test temperatures in a higher temperature range. Such a rather monotonic test temperature dependence after high-temperature irradiation is similar to that observed for an archive material generally showing a higher degree of toughness. A brittle fracture without stable crack growth occurred in only a few specimens with relatively lower irradiation and test temperatures. In this discussion, these TPB fracture toughness data are compared with previously published data from 12.7 mm diameter disc compact tension (DCT) specimens.

  3. Estimation of Fracture Porosity in an Unsaturated Fractured Welded Tuff Using Gas Tracer Testing

    Energy Technology Data Exchange (ETDEWEB)

    B.M. Freifeild

    2001-10-18

    Kinematic fracture porosity is an important hydrologic transport parameter for predicting the potential of rapid contaminant migration through fractured rock. The transport velocity of a solute moving within a fracture network is inversely related to the fracture porosity. Since fracture porosity is often one or two orders of magnitude smaller than matrix porosity, and fracture permeability is often orders of magnitude greater than matrix permeability, solutes may travel significantly faster in the fracture network than in the surrounding matrix. This dissertation introduces a new methodology for conducting gas tracer tests using a field portable mass spectrometer along with analytical tools for estimating fracture porosity using the measured tracer concentration breakthrough curves. Field experiments were conducted at Yucca Mountain, Nevada, consisting of air-permeability transient testing and gas-tracer-transport tests. The experiments were conducted from boreholes drilled within an underground tunnel as part of an investigation of rock mass hydrological behavior. Air-permeability pressure transients, recorded during constant mass flux injections, have been analyzed using a numerical inversion procedure to identify fracture permeability and porosity. Dipole gas tracer tests have also been conducted from the same boreholes used for air-permeability testing. Mass breakthrough data has been analyzed using a random walk particle-tracking model, with a dispersivity that is a function of the advective velocity. The estimated fracture porosity using the tracer test and air-injection test data ranges from .001 to .015. These values are an order of magnitude greater than the values estimated by others using hydraulically estimated fracture apertures. The estimates of porosity made using air-permeability test data are shown to be highly sensitive to formation heterogeneity. Uncertainty analyses performed on the gas tracer test results show high confidence in the parameter

  4. Glass ceramic of high hardness and fracture toughness developed from iron-rich wastes

    Institute of Scientific and Technical Information of China (English)

    Weixin HAN

    2009-01-01

    A study has been carried out on the feasibility of using high iron content wastes, gen-erated during steel making, as a raw material for the production of glass ceramic. The iron-rich wastes were mixed and melted in different proportions with soda-lime glass cullet and sand. The devitrification of the parent glasses produced from the different mixtures was investigated using differential thermal analysis, X-ray diffraction, and scanning electron microscopy. The mechanical properties of the glass-ceramic were assessed by hardness and indentation fracture toughness measurement. A glass ce-ramic with mixture of 60 wt pct iron-rich wastes, 25 wt pct sand, and 15 wt pct glass cullet exhibited the best combination of properties, namely, hardness 7.9 GPa and fracture toughness 3.75 MPa.m1/2, for the sake of containing magnetite in marked dendritic morphology. These new hard glass ceramics are candidate materials for wear resistant tiles and paving for heavy industrial floors.

  5. A Failure Analysis Conducted on a Fractured AISI 5160 Steel Blade Which Separated from an Agricultural Rotary Cutter

    Energy Technology Data Exchange (ETDEWEB)

    Johnson, Alan A [Metals Research Inc., 101 West Chestnut St., Louisville, Kentucky, 40202 (United States); Storey, Randall J, E-mail: barbalan@bellsouth.net [Deptartment of Industrial Engineering, University of Louisville, Louisville, Kentucky, 40292 (United States)

    2011-07-19

    One of the six blades of an agricultural rotary cutter used for cutting down small trees and bushes broke into two pieces while the blades were rotating. One piece was hurled from the cutter and struck a young farmer, who had been operating the machine, causing a near fatal leg injury. In the ensuing litigation against the manufacturers and marketer of the machine each litigant retained a metallurgist and other experts. The metallurgists jointly directed laboratory work on the broken blade conducted at an independent laboratory according to a protocol which they developed and which was approved by the court. As a result of the laboratory work the present authors, working for the Plaintiffs, concluded that failure of the blade occurred because it contained quench cracks introduced when it was manufactured. The Defendants' metallurgists concluded that the blade had been misassembled onto the machine and, as a result, had failed by fatigue. Eventually, the case was set for a jury trial in a Circuit Court in rural Kentucky. The jury found for the Plaintiffs and awarded them $5.9 million in damages. Part of this judgement was later reversed by the Kentucky Court of Appeals and the case was then settled without a second trial under terms which were not revealed.

  6. Laboratory Research on Fracture-Supported Shielding Temporary Plugging Drill-In Fluid for Fractured and Fracture-Pore Type Reservoirs

    Directory of Open Access Journals (Sweden)

    Dawei Liu

    2017-01-01

    Full Text Available Based on fractures stress sensitivity, this paper experimentally studies fracture-supported shielding temporary plugging drill-in fluid (FSDIF in order to protect fractured and fracture-pore type formation. Experimental results show the FSDIF was better than the CDIF for protecting fractured and fracture-pore type reservoir and the FSDIF temporary plugging rate was above 99%, temporary plugging ring strength was greater than 15 MPa, and return permeability was 91.35% and 120.83% before and after acidizing, respectively. The reasons for the better reservoir protection effect were analyzed. Theoretical and experiment studies conducted indicated that the FSDIF contained acid-soluble and non-acid-soluble temporary shielding agents; non-acid-soluble temporary shielding agents had high hardness and temporary plugging particles size was matched to the formation fracture width and pore throat size.

  7. Study on fracture characteristic of welded high-density polyethylene pipe

    Institute of Scientific and Technical Information of China (English)

    齐芳娟; 霍立兴; 张玉凤; 荆洪阳; 杨新岐

    2002-01-01

    Crack opening displacement(COD) was applied to characterize the fracture initiation of the tough high density polyethylene. Normal single side notched three-point bend specimens and silica rubber replica techniques were used to study the characteristic COD of high-density polyethylene pipe and its butt-fusion joints including the weld fusion zone and heat affected zone at different temperature from -78℃ to 20℃ . Testing results show that the characteristic COD appears to depend on the structural features that are determined by welding process and the testing temperature. As the temperature is lowered, the characteristic COD of all zones studied decreases. Because the welding process significantly changes some structural feature of the material, characteristic COD of the weld fusion zone is the smallest one among those of the three zones. The results can be used for the engineering design and failure analysis of HDPE pipe.

  8. Self-resonant Coil for Contactless Electrical Conductivity Measurement under Pulsed Ultra-high Magnetic Fields

    CERN Document Server

    Nakamura, Daisuke; Takeyama, Shojiro

    2014-01-01

    In this study, we develop experimental apparatus for contactless electrical conductivity measurements under pulsed high magnetic fields over 100 T using a self-resonant-type high-frequency circuit. The resonant power spectra were numerically analyzed, and the conducted simulations showed that the apparatus is optimal for electrical conductivity measurements of materials with high electrical conductivity. The newly developed instruments were applied to a high-temperature cuprate superconductor La$_{2-x}$Sr$_x$CuO$_4$ to show conductivity changes in magnetic fields up to 102 T with a good signal-to-noise ratio. The upper critical field was determined with high accuracy.

  9. Advanced Hydraulic Fracturing Technology for Unconventional Tight Gas Reservoirs

    Energy Technology Data Exchange (ETDEWEB)

    Stephen Holditch; A. Daniel Hill; D. Zhu

    2007-06-19

    The objectives of this project are to develop and test new techniques for creating extensive, conductive hydraulic fractures in unconventional tight gas reservoirs by statistically assessing the productivity achieved in hundreds of field treatments with a variety of current fracturing practices ranging from 'water fracs' to conventional gel fracture treatments; by laboratory measurements of the conductivity created with high rate proppant fracturing using an entirely new conductivity test - the 'dynamic fracture conductivity test'; and by developing design models to implement the optimal fracture treatments determined from the field assessment and the laboratory measurements. One of the tasks of this project is to create an 'advisor' or expert system for completion, production and stimulation of tight gas reservoirs. A central part of this study is an extensive survey of the productivity of hundreds of tight gas wells that have been hydraulically fractured. We have been doing an extensive literature search of the SPE eLibrary, DOE, Gas Technology Institute (GTI), Bureau of Economic Geology and IHS Energy, for publicly available technical reports about procedures of drilling, completion and production of the tight gas wells. We have downloaded numerous papers and read and summarized the information to build a database that will contain field treatment data, organized by geographic location, and hydraulic fracture treatment design data, organized by the treatment type. We have conducted experimental study on 'dynamic fracture conductivity' created when proppant slurries are pumped into hydraulic fractures in tight gas sands. Unlike conventional fracture conductivity tests in which proppant is loaded into the fracture artificially; we pump proppant/frac fluid slurries into a fracture cell, dynamically placing the proppant just as it occurs in the field. From such tests, we expect to gain new insights into some of the critical

  10. High Modulus, High Conductivity Nanostructured Polymer Electrolyte Membranes via Polymerization-Induced Phase Separation

    Science.gov (United States)

    McIntosh, Lucas; Schulze, Morgan; Hillmyer, Marc; Lodge, Timothy

    2014-03-01

    Solvent-free, solid-state polymer electrolyte membranes (PEMs) will play a vital role in next-generation electrochemical devices such as Li-metal batteries and high- T fuel cells. The primary challenge is that these applications require PEMs with substantial mechanical robustness, as well as high ionic conductivity. The key to optimizing orthogonal macroscopic properties is to use a heterogeneous composite with well-defined nanoscopic morphology--specifically, long-range co-continuity of high modulus and ion transport domains, which has proven difficult to achieve in commonly-studied diblock copolymer-based electrolytes. We report a simple synthetic strategy to generate PEMs via polymerization-induced phase separation, where the delicate balance between controlled addition of styrene onto a poly(ethylene oxide) macro-chain transfer agent and simultaneous chemical crosslinking by divinylbenzene results in a disordered structure with domain size of order 10 nm. Crucially, both domains exhibit long-range continuity, which results in PEMs that are glassy solids (modulus ~ 1 GPa) owing to the isotropic network of stiff, crosslinked polystyrene, and are highly conductive (> 1 mS/cm at 70 °C) because ions migrate in channels of low Tg poly(ethylene oxide).

  11. Extremely high thermal conductivity anisotropy of double-walled carbon nanotubes

    Directory of Open Access Journals (Sweden)

    Zhaoji Ma

    2017-06-01

    Full Text Available Based on molecular dynamics simulations, we reveal that double-walled carbon nanotubes can possess an extremely high anisotropy ratio of radial to axial thermal conductivities. The mechanism is basically the same as that for the high thermal conductivity anisotropy of graphene layers - the in-plane strong sp2 bonds lead to a very high intralayer thermal conductivity while the weak van der Waals interactions to a very low interlayer thermal conductivity. However, different from flat graphene layers, the tubular structures of carbon nanotubes result in a diameter dependent thermal conductivity. The smaller the diameter, the larger the axial thermal conductivity but the smaller the radial thermal conductivity. As a result, a DWCNT with a small diameter may have an anisotropy ratio of thermal conductivity significantly higher than that for graphene layers. The extremely high thermal conductivity anisotropy allows DWCNTs to be a promising candidate for thermal management materials.

  12. Extremely high thermal conductivity anisotropy of double-walled carbon nanotubes

    Science.gov (United States)

    Ma, Zhaoji; Guo, Zhengrong; Zhang, Hongwei; Chang, Tienchong

    2017-06-01

    Based on molecular dynamics simulations, we reveal that double-walled carbon nanotubes can possess an extremely high anisotropy ratio of radial to axial thermal conductivities. The mechanism is basically the same as that for the high thermal conductivity anisotropy of graphene layers - the in-plane strong sp2 bonds lead to a very high intralayer thermal conductivity while the weak van der Waals interactions to a very low interlayer thermal conductivity. However, different from flat graphene layers, the tubular structures of carbon nanotubes result in a diameter dependent thermal conductivity. The smaller the diameter, the larger the axial thermal conductivity but the smaller the radial thermal conductivity. As a result, a DWCNT with a small diameter may have an anisotropy ratio of thermal conductivity significantly higher than that for graphene layers. The extremely high thermal conductivity anisotropy allows DWCNTs to be a promising candidate for thermal management materials.

  13. Processable 3-nm thick graphene platelets of high electrical conductivity and their epoxy composites.

    Science.gov (United States)

    Meng, Qingshi; Jin, Jian; Wang, Ruoyu; Kuan, Hsu-Chiang; Ma, Jun; Kawashima, Nobuyuki; Michelmore, Andrew; Zhu, Shenmin; Wang, Chun H

    2014-03-28

    Graphene platelets (GnPs) are a class of novel 2D nanomaterials owing to their very small thickness (∼3 nm), high mechanical strength and electric conductivity (1460 S cm(-1)), and good compatibility with most polymers as well as cost-effectiveness. In this paper we present a low-cost processing technique for producing modified GnPs and an investigation of the electrical and mechanical properties of the resulting composites. After dispersing GnPs in solvent N-methyl-2-pyrrolidone, a long-chain surfactant (Jeffamine D 2000, denoted J2000) was added to covalently modify GnPs, yielding J2000-GnPs. By adjusting the ratio of GnPs to the solvent, the modified GnPs show different average thickness and thus electrical conductivity ranging from 694 to 1200 S cm(-1). To promote the exfoliation and dispersion of J2000-GnPs in a polymeric matrix, they were dispersed in the solvent again and further modified using diglycidyl ether of bisphenol A (DGEBA) producing m-GnPs, which were then compounded with an epoxy resin for the development of epoxy/m-GnP composites. A percolation threshold of electrical volume resistivity for the resulting composites was observed at 0.31 vol%. It was found that epoxy/m-GnP composites demonstrated far better mechanical properties than those of unmodified GnPs of the same volume fraction. For example, m-GnPs at 0.25 vol% increased the fracture energy release rate G1c from 0.204 ± 0.03 to 1.422 ± 0.24 kJ m(-2), while the same fraction of unmodified GnPs increased G1c to 1.01 ± 0.24 kJ m(-2). The interface modification also enhanced the glass transition temperature of neat epoxy from 58.9 to 73.8 °C.

  14. Processable 3-nm thick graphene platelets of high electrical conductivity and their epoxy composites

    Science.gov (United States)

    Meng, Qingshi; Jin, Jian; Wang, Ruoyu; Kuan, Hsu-Chiang; Ma, Jun; Kawashima, Nobuyuki; Michelmore, Andrew; Zhu, Shenmin; Wang, Chun H.

    2014-03-01

    Graphene platelets (GnPs) are a class of novel 2D nanomaterials owing to their very small thickness (˜3 nm), high mechanical strength and electric conductivity (1460 S cm-1), and good compatibility with most polymers as well as cost-effectiveness. In this paper we present a low-cost processing technique for producing modified GnPs and an investigation of the electrical and mechanical properties of the resulting composites. After dispersing GnPs in solvent N-methyl-2-pyrrolidone, a long-chain surfactant (Jeffamine D 2000, denoted J2000) was added to covalently modify GnPs, yielding J2000-GnPs. By adjusting the ratio of GnPs to the solvent, the modified GnPs show different average thickness and thus electrical conductivity ranging from 694 to 1200 S cm-1. To promote the exfoliation and dispersion of J2000-GnPs in a polymeric matrix, they were dispersed in the solvent again and further modified using diglycidyl ether of bisphenol A (DGEBA) producing m-GnPs, which were then compounded with an epoxy resin for the development of epoxy/m-GnP composites. A percolation threshold of electrical volume resistivity for the resulting composites was observed at 0.31 vol%. It was found that epoxy/m-GnP composites demonstrated far better mechanical properties than those of unmodified GnPs of the same volume fraction. For example, m-GnPs at 0.25 vol% increased the fracture energy release rate G1c from 0.204 ± 0.03 to 1.422 ± 0.24 kJ m-2, while the same fraction of unmodified GnPs increased G1c to 1.01 ± 0.24 kJ m-2. The interface modification also enhanced the glass transition temperature of neat epoxy from 58.9 to 73.8 °C.

  15. Multi-rate mass transfer modeling of two-phase flow in highly heterogeneous fractured and porous media

    Science.gov (United States)

    Tecklenburg, Jan; Neuweiler, Insa; Carrera, Jesus; Dentz, Marco

    2016-05-01

    We study modeling of two-phase flow in highly heterogeneous fractured and porous media. The flow behaviour is strongly influenced by mass transfer between a highly permeable (mobile) fracture domain and less permeable (immobile) matrix blocks. We quantify the effective two-phase flow behavior using a multirate rate mass transfer (MRMT) approach. We discuss the range of applicability of the MRMT approach in terms of the pertinent viscous and capillary diffusion time scales. We scrutinize the linearization of capillary diffusion in the immobile regions, which allows for the formulation of MRMT in the form of a non-local single equation model. The global memory function, which encodes mass transfer between the mobile and the immobile regions, is at the center of this method. We propose two methods to estimate the global memory function for a fracture network with given fracture and matrix geometry. Both employ a scaling approach based on the known local memory function for a given immobile region. With the first method, the local memory function is calculated numerically, while the second one employs a parametric memory function in form of truncated power-law. The developed concepts are applied and tested for fracture networks of different complexity. We find that both physically based parameter estimation methods for the global memory function provide predictive MRMT approaches for the description of multiphase flow in highly heterogeneous porous media.

  16. High-strength high-conductivity Cu-Nb microcomposite sheet fabricated via multiple roll bonding

    Science.gov (United States)

    Jha, S. C.; Delagi, R. G.; Forster, J. A.; Krotz, P. D.

    1993-01-01

    Copper-niobium microcomposites are a new class of high-strength high-conductivity materials that have attractive properties for room- and elevated-temperature applications. Since Nb has little solid solubility in Cu, addition of Nb to Cu does not affect its conductivity. Copper-niobium microcomposites are melted and cast so that the microstructure of cast Cu-Nb ingots consists of 1-to 10 μm Nb dendrites uniformly distributed within the copper matrix. Extensive wire drawing with a true processing strain ( η > 12) of Cu-Nb alloy leads to refinement and elongation of Nb dendrites into 1-to 10 nm-thick filaments. The presence of such fine Nb filaments causes a significant increase in the strength of Cu-Nb wires. The tensile strength of heavily drawn Cu-Nb wires was determined to be significantly higher than the values predicted by the rule of mixtures. This article reports the fabrication of high-strength Cu-Nb micro-composite sheet by multiple roll bonding. It is difficult and impractical to attain high processing strains ( η > 3) by simple cold rolling. In most practical cold-rolling operation, the thickness reduction does not exceed 90 pct ( η ≅ 2). Therefore, innovative processing is required to generate high strength in Cu-Nb microcomposite sheet. Multiple roll bonding of Cu-Nb has been utilized to store high processing strain ( η > 10) in the material and refine the Nb particle size within the copper matrix. This article describes the microstructure, mechanical properties, and thermal stability of roll-bonded Cu-Nb microcomposite sheet.

  17. Novel high refractive index, thermally conductive additives for high brightness white LEDs

    Science.gov (United States)

    Hutchison, Richard Stephen

    In prior works the inclusion of nanoparticle fillers has typically been shown to increase the thermal conductivity or refractive index of polymer nanocomposites separately. High refractive index zirconia nanoparticles have already proved their merit in increasing the optical efficiency of encapsulated light emitting diodes. However, the thermal properties of zirconia-silicone nanocomposites have yet to be investigated. While phosphor-converted light emitting diodes are at the forefront of solid-state lighting technologies for producing white light, they are plagued by efficiency losses due to excessive heating at the semiconductor die and in and around the phosphor particles, as well as photon scattering losses in the phosphor layer. It would then be of great interest if the high refractive index nanoparticles were found to both be capable of increasing the refractive index, thus reducing the optical scattering, and also the thermal conductivity, channeling more heat away from the LED die and phosphors, mitigating efficiency losses from heat. Thermal conductance measurements on unfilled and nanoparticle loaded silicone samples were conducted to quantify the effect of the zirconia nanoparticle loading on silicone nanocomposite thermal conductivity. An increase in thermal conductivity from 0.27 W/mK to 0.49 W/mK from base silicone to silicone with 33.5 wt% zirconia nanoparticles was observed. This trend closely mirrored a basic rule of mixtures prediction, implying a further enhancement in thermal conductivity could be achieved at higher nanoparticle loadings. The optical properties of transparency and light extraction efficiency of these composites were also investigated. While overall the zirconia nanocomposite showed good transparency, there was a slight decrease at the shorter wavelengths with increasing zirconia content. For longer wavelength LEDs, such as green or red, this might not matter, but phosphor-converted white LEDs use a blue LED as the photon source

  18. Stable high conductivity functionally gradient compositionally layered solid state electrolytes and membranes

    Energy Technology Data Exchange (ETDEWEB)

    Wachsman, E.D.; Jayaweera, P.; Lowe, D.M.; Pound, B.C.

    1997-11-06

    Stable high conductivity functionally gradient compositionally layered solid bodies suitable for use as electrolytes and membranes and providing improved oxygen-ion conductivity for electrolytes and improved mixed oxygen-ion and electronic conductivity for membranes. The electrolytes provide solid oxide fuel cells with high efficiency operation at 300{sup o}C to 800{sup o}C. (author) figs.

  19. Highly conductive free standing polypyrrole films prepared by freezing interfacial polymerization.

    Science.gov (United States)

    Qi, Guijin; Huang, Liyan; Wang, Huiliang

    2012-08-25

    Highly conductive free standing polypyrrole (PPy) films were prepared by a novel freezing interfacial polymerization method. The films exhibit metallic luster and electrical conductivity up to 2000 S cm(-1). By characterizing with SEM, FTIR, Raman and XRD, the high conductivity is attributed to the smooth surface, higher conjugation length and more ordered molecular structure of PPy.

  20. High-resolution and high-conductive electrode fabrication on a low thermal resistance flexible substrate

    Science.gov (United States)

    Kang, Bongchul; Kno, Jinsung; Yang, Minyang

    2011-07-01

    Processes based on the liquid-state pattern transfer, like inkjet printing, have critical limitations including low resolution and low electrical conductivity when fabricating electrodes on low thermal resistance flexible substrates such as polyethylene terephthalate (PET). Those are due to the nonlinear transfer mechanism and the limit of the sintering temperature. Although the laser direct curing (LDC) of metallic inks is an alternative process to improve the resolution, it is also associated with the disadvantages of causing thermal damage to the polymer substrate. This paper suggests the laser induced pattern adhesion transfer method to fabricate electrodes of both high electrical conductivity and high resolution on a PET substrate. First, solid patterns are cost-effectively created by the LDC of the organometallic silver ink on a glass that is optically and thermally stable. The solid patterns sintered on the glass are transferred to the PET substrate by the photo-thermally generated adhesion force of the substrate. Therefore, we achieved electrodes with a minimum line width of 10 µm and a specific resistance of 3.6 μΩcm on the PET substrate. The patterns also showed high mechanical reliability.

  1. Generation of High-Frequency P and S Wave Energy by Rock Fracture During a Buried Explosion

    Science.gov (United States)

    2015-07-20

    AFRL-RV -PS- TR-2015-0145 AFRL-RV -PS- TR-2015-0145 GENERATION OF HIGH-FREQUENCY P AND S WAVE ENERGY BY ROCK FRACTURE DURING A BURIED EXPLOSION ...SUBTITLE Generation of High-Frequency P and S Wave Energy by Rock Fracture During a Buried Explosion 5a. CONTRACT NUMBER FA9453-12-C-0210 5b...underground nuclear explosions . This model predicts the generation of strong S wave radiation in the non-linear source region whenever spherical

  2. Hydrogen fracture toughness tester completion

    Energy Technology Data Exchange (ETDEWEB)

    Morgan, Michael J. [Savannah River Site (SRS), Aiken, SC (United States). Savannah River National Lab. (SRNL)

    2015-09-30

    The Hydrogen Fracture Toughness Tester (HFTT) is a mechanical testing machine designed for conducting fracture mechanics tests on materials in high-pressure hydrogen gas. The tester is needed for evaluating the effects of hydrogen on the cracking properties of tritium reservoir materials. It consists of an Instron Model 8862 Electromechanical Test Frame; an Autoclave Engineering Pressure Vessel, an Electric Potential Drop Crack Length Measurement System, associated computer control and data acquisition systems, and a high-pressure hydrogen gas manifold and handling system.

  3. Pressure oscillations caused by momentum on shut in of a high rate well in a fractured formation

    Energy Technology Data Exchange (ETDEWEB)

    Bhatnagar, S.

    1989-06-01

    Pressure transient testing techniques are an important part of reservoir and production testing procedures. These techniques are frequently used to determine practical information about underground reservoirs such as the permeability, porosity, liquid content, reservoir and liquid discontinuities and other related data. This information is valuable in helping to analyze, improve and forecast reservoir performance. This report is concerned with developing models for pressure transient well testing in high permeability, high flow rate, naturally fractured reservoirs. In the present work, a study was made of the effects of liquid inertia in the fractures and the wellbore on the pressure response obtained during a well test. The effects of turbulent flow and multi-phase flow effects such as gravitational segregation or anisotropic porous media effects were not considered. The scope of the study was limited to studying inertial effects on the pressure response of a fractured reservoir.

  4. Community-based risk assessment of water contamination from high-volume horizontal hydraulic fracturing.

    Science.gov (United States)

    Penningroth, Stephen M; Yarrow, Matthew M; Figueroa, Abner X; Bowen, Rebecca J; Delgado, Soraya

    2013-01-01

    The risk of contaminating surface and groundwater as a result of shale gas extraction using high-volume horizontal hydraulic fracturing (fracking) has not been assessed using conventional risk assessment methodologies. Baseline (pre-fracking) data on relevant water quality indicators, needed for meaningful risk assessment, are largely lacking. To fill this gap, the nonprofit Community Science Institute (CSI) partners with community volunteers who perform regular sampling of more than 50 streams in the Marcellus and Utica Shale regions of upstate New York; samples are analyzed for parameters associated with HVHHF. Similar baseline data on regional groundwater comes from CSI's testing of private drinking water wells. Analytic results for groundwater (with permission) and surface water are made publicly available in an interactive, searchable database. Baseline concentrations of potential contaminants from shale gas operations are found to be low, suggesting that early community-based monitoring is an effective foundation for assessing later contamination due to fracking.

  5. Properties of polyacrylic acid-coated silver nanoparticle ink for inkjet printing conductive tracks on paper with high conductivity

    Energy Technology Data Exchange (ETDEWEB)

    Huang, Qijin [Ningbo Institute of Material Technology and Engineering, Chinese Academy of Sciences, Ningbo, Zhejiang 315201 (China); Shen, Wenfeng, E-mail: wfshen@nimte.ac.cn [Ningbo Institute of Material Technology and Engineering, Chinese Academy of Sciences, Ningbo, Zhejiang 315201 (China); Xu, Qingsong [Ningbo Institute of Material Technology and Engineering, Chinese Academy of Sciences, Ningbo, Zhejiang 315201 (China); Tan, Ruiqin [Faculty of Information Science and Engineering, Ningbo University, Ningbo, Zhejiang 315211 (China); Song, Weijie, E-mail: weijiesong@nimte.ac.cn [Ningbo Institute of Material Technology and Engineering, Chinese Academy of Sciences, Ningbo, Zhejiang 315201 (China)

    2014-10-15

    Silver nanoparticles with a mean diameter of approximately 30 nm were synthesized by reduction of silver nitrate with triethanolamine in the presence of polyacrylic acid. Silver nanoparticle-based ink was prepared by dispersing silver nanoparticles into a mixture of water and ethylene glycol. The mechanism for the dispersion and aggregation of silver nanoparticles in ink is discussed. The strong electrostatic repulsions of the carboxylate anions of the adsorbed polyacrylic acid molecules disturbed the aggregation of metal particles in solutions with a high pH value (pH > 5). An inkjet printer was used to deposit this silver nanoparticle-based ink to form silver patterns on photo paper. The actual printing qualities of the silver tracks were then analyzed by variation of printing passes, sintering temperature and time. The results showed that sintering temperature and time are associated strongly with the conductivity of the inkjet-printed conductive patterns. The conductivity of printed patterns sintered at 150 °C increased to 2.1 × 10{sup 7} S m{sup −1}, which was approximately one third that of bulk silver. In addition, silver tracks on paper substrate also showed better electrical performance after folding. This study demonstrated that the resulting ink-jet printed patterns can be used as conductive tracks in flexible electronic devices. - Highlights: • An ink from silver nanoparticles coated with polyacrylic acid was prepared. • The ink was used for inkjet-printed tracks at varying printing parameters. • The conductivity of printed tracks sintered at 150 °C increased to 2.1 × 10{sup 7} S/m. • Mechanism for dispersion and aggregation of the nanoparticles in ink is discussed.

  6. Tensile and electrical properties of high-strength high-conductivity copper alloys

    Energy Technology Data Exchange (ETDEWEB)

    Zinkle, S.J.; Eatherly, W.S. [Oak Ridge National Lab., TN (United States)

    1998-09-01

    Electrical conductivity and tensile properties have been measured on an extruded and annealed CuCrNb dispersion strengthened copper alloy which has been developed for demanding aerospace high heat flux applications. The properties of this alloy are somewhat inferior to GlidCop dispersion strengthened copper and prime-aged CuCrZr over the temperature range of 20--500 C. However, if the property degradation in CuCrZr due to joining operations and the anisotropic properties of GlidCop in the short transverse direction are taken into consideration, CuCrNb may be a suitable alternative material for high heat flux structural applications in fusion energy devices. The electrical conductivity and tensile properties of CuCrZr that was solution annealed and then simultaneously aged and diffusion bonded are also summarized. A severe reduction in tensile elongation is observed in the diffusion bonded joint, particularly if a thin copper shim is not placed in the diffusion bondline.

  7. Irradiation effects on fracture toughness of two high-copper submerged-arc welds, HSSI Series 5. Volume 1, Main report and Appendices A, B, C, and D

    Energy Technology Data Exchange (ETDEWEB)

    Nanstad, R.K.; Haggag, F.M.; McCabe, D.E.; Iskander, S.K.; Bowman, K.O. [Oak Ridge National Lab., TN (United States); Menke, B.H. [Materials Engineering Associates, Inc., Lanham, MD (United States)

    1992-10-01

    The Fifth Irradiation Series in the Heavy-Section Steel Irradiation Program obtained a statistically significant fracture toughness data base on two high-copper (0.23 and 0.31 wt %) submerged-arc welds to determine the shift and shape of the K{sub Ic} curve as a consequence of irradiation. Compact specimens with thicknesses to 101.6 mm (4 in) in the irradiated condition and 203.2 mm (8 in) in the unirradiated condition were tested, in addition to Charpy impact, tensile, and drop-weight specimens. Irradiations were conducted at a nominal temperature of 288{degree}C and an average fluence of 1.5 {times} 10{sup 19} neutrons/cm{sup 2} (>l MeV). The Charpy 41-J temperature shifts are about the same as the corresponding drop-weight NDT temperature shifts. The irradiated welds exhibited substantial numbers of cleavage pop-ins. Mean curve fits using two-parameter (with fixed intercept) nonlinear and linearized exponential regression analysis revealed that the fracture toughness 100 MPa{lg_bullet}{radical}m shifts exceeded the Charpy 41-J shifts for both welds. Analyses of curve shape changes indicated decreases in the slopes of the fracture toughness curves, especially for the higher copper weld. Weibull analyses were performed to investigate development of lower bound curves to the data, including the use of a variable K{sub min} parameter which affects the curve shape.

  8. Effect of microstructure on the fracture response of advanced high strength steels

    Science.gov (United States)

    Taylor, Mark D.

    2013-01-01

    The materials selected to observe microstructural effects on formability included four 780 MPa strength, and four 980 MPa strength AHSS grades produced with varying processing conditions. The grades were an uncoated DP780, a high yield DP780, a galvanized DP780, a TRIP780, a galvannealed DP980, a galvanized DP980, an uncoated DP980, and a fine grained DP980. All AHSS grades were tensile tested to obtain values for ultimate tensile strength, yield strength, percent uniform and total elongation. An analysis was performed to quantify the average grain size of the primary and second phase constituents, as well as the second phase volume fraction present in each AHSS grade. Nanoindentation was performed for each AHSS grade to determine the average hardness of the primary and second phase constituents present. Evolution of microstructural damage in response to deformation was analyzed using a plane strain tensile method developed to impose a localized through-thickness shear fracture. Samples of each AHSS grade were strained to progressively higher percentages of their failure displacement, and microstructural damage was observed using a scanning electron microscope on a metallographic section removed from the localized shear deformation region. Micrographs were analyzed using ImageJ®, and the resulting void percent and number of voids were determined for each test performed. A direct correlation was observed between the number of voids and hardness ratio. The strength of the microstructural constituents affected mechanical properties, suggesting that constituent strength values should be considered when predicting formability limits for higher strength AHSS grades. Since all AHSS grades experienced some critical number of voids before fracture, it was concluded that suppression of void formation can extend the formability limits to higher strains. After observing a percent failure displacement value of 95%, it was determined that the final stage of fracture (void

  9. Numerical study for enhancing the thermal conductivity of phase change material (PCM) storage using high thermal conductivity porous matrix

    Energy Technology Data Exchange (ETDEWEB)

    Mesalhy, O.; Lafdi, K.; Elgafy, A.; Bowman, K. [Dayton University Research Inst., OH (United States)

    2005-04-01

    In this paper, the melting process inside an irregular geometry filled with high thermal conductivity porous matrix saturated with phase change material PCM is investigated numerically. The numerical model is resting on solving the volume averaged conservation equations for mass, momentum and energy with phase change (melting) in the porous medium. The convection motion of the liquid phase inside the porous matrix is solved considering the Darcy, Brinkman and Forchiemer effects. A local thermal non-equilibrium assumption is considered due to the large difference in thermal properties between the solid matrix and PCM by applying a two energy equation model. The numerical code shows good agreement for pure PCM melting with another published numerical work. Through this study it is found that the presence of the porous matrix has a great effect on the heat transfer and melting rate of the PCM energy storage. Decreasing the porosity of the matrix increases the melting rate, but it also damps the convection motion. It is also found that the best technique to enhance the response of the PCM storage is to use a solid matrix with high porosity and high thermal conductivity. (author)

  10. Highly Porous, Rigid-Rod Polyamide Aerogels with Superior Mechanical Properties and Unusually High Thermal Conductivity.

    Science.gov (United States)

    Williams, Jarrod C; Nguyen, Baochau N; McCorkle, Linda; Scheiman, Daniel; Griffin, Justin S; Steiner, Stephen A; Meador, Mary Ann B

    2017-01-18

    We report here the fabrication of polyamide aerogels composed of poly-p-phenylene-terephthalamide, the same backbone chemistry as DuPont's Kevlar. The all-para-substituted polymers gel without the use of cross-linker and maintain their shape during processing-an improvement over the meta-substituted cross-linked polyamide aerogels reported previously. Solutions containing calcium chloride (CaCl2) and para-phenylenediamine (pPDA) in N-methylpyrrolidinone (NMP) at low temperature are reacted with terephthaloyl chloride (TPC). Polymerization proceeds over the course of 5 min resulting in gelation. Removal of the reaction solvent via solvent exchange followed by extraction with supercritical carbon dioxide provides aerogels with densities ranging from 0.1 to 0.3 g/cm(3), depending on the concentration of calcium chloride, the formulated number of repeat units, n, and the concentration of polymer in the reaction mixture. These variables were assessed in a statistical experimental study to understand their effects on the properties of the aerogels. Aerogels made using at least 30 wt % CaCl2 had the best strength when compared to aerogels of similar density. Furthermore, aerogels made using 30 wt % CaCl2 exhibited the lowest shrinkage when aged at elevated temperatures. Notably, whereas most aerogel materials are highly insulating (thermal conductivities of 10-30 mW/m K), the polyamide aerogels produced here exhibit remarkably high thermal conductivities (50-80 mW/(m K)) at the same densities as other inorganic and polymer aerogels. These high thermal conductivities are attributed to efficient phonon transport by the rigid-rod polymer backbone. In conjunction with their low cost, ease of fabrication with respect to other polymer aerogels, low densities, and high mass-normalized strength and stiffness properties, these aerogels are uniquely valuable for applications such as lightweighting in consumer electronics, automobiles, and aerospace where weight reduction is

  11. New propant schedule in hydralic fracturing

    Energy Technology Data Exchange (ETDEWEB)

    Wang, H.; Fan, C.

    1981-01-01

    A new proppant schedule is suggested to obtain maximum propping surface area and maximum fracture conductivity near the borehole. The small and middle size sands are suspended in the fracturing fluids under fracturing condition to prop the total fracture surface area created by fracturing. The coarse sands pumped into fracture later deposit in the fracture at the dynamic width near the borehole during fracturing and reach the equilibrium height in the time interval of pumping coarse sands. Thus, fracture conductivity near the borehole is increased. Computer calculation of the sand program, the corresponding fluid program and pumping rates are presented also.

  12. The development of in situ fracture toughness evaluation techniques in hydrogen environment

    Energy Technology Data Exchange (ETDEWEB)

    Wang, Jy-An John [ORNL; Ren, Fei [ORNL; Tan, Ting [ORNL; Liu, Ken C [ORNL

    2014-01-01

    Fracture behavior and fracture toughness are of great interest regarding reliability of hydrogen pipelines and storage tanks, however, many conventional fracture testing techniques are difficult to be realized under the presence of hydrogen, in addition to the inherited specimen size effect. Thus it is desired to develop novel in situ fracture toughness evaluation techniques to study the fracture behavior of structural materials in hydrogen environments. In this study, a torsional fixture was developed to utilize an emerging fracture testing technique, Spiral Notch Torsion Test (SNTT). The in situ testing results indicated that the exposure to H2 significantly reduces the fracture toughness of 4340 high strength steels by up to 50 percent. Furthermore, SNTT tests conducted in air demonstrated a significant fracture toughness reduction in samples subject to simulated welding heat treatment using Gleeble, which illustrated the effect of welding on the fracture toughness of this material.

  13. Injection through fractures

    Energy Technology Data Exchange (ETDEWEB)

    Johns, R.A.

    1987-05-01

    Tracer tests are conducted in geothermal reservoirs as an aid in forecasting thermal breakthrough of reinjection water. To interpret tracer tests, mathematical models have been developed based on the various transport mechanisms in these highly fractured reservoirs. These tracer flow models have been applied to interpret field tests. The resulting matches between the model and field data were excellent and the model parameters were used to estimate reservoir properties. However, model fitting is an indirect process and the model's ability to estimate reservoir properties cannot be judged solely on the quality of the match between field data and model predictions. The model's accuracy in determining reservoir characteristics must be independently verified in a closely controlled environment. In this study, the closely controlled laboratory environment was chosen to test the validity and accuracy of tracer flow models developed specifically for flow in fractured rocks. The laboratory tracer tests were performed by flowing potassium iodide (KI) through artificially fractured core samples. The tracer test results were then analyzed with several models to determine which best fit the measured data. A Matrix Diffusion model was found to provide the best match of the tracer experiments. The core properties, as estimated by the Matrix Diffusion model parameters generated from the indirect matching process, were then determined. These calculated core parameters were compared to the measured core properties and were found to be in agreement. This verifies the use of the Matrix Diffusion flow model in estimating fracture widths from tracer tests.

  14. Fabrication of high thermal conductive Al-cBN ceramic sinters by high temperature high pressure method

    Science.gov (United States)

    Wang, P. F.; Li, Zh. H.; Zhu, Y. M.

    2011-05-01

    Al-cBN ceramic sinters were fabricated by sintering micro-powder mixture of Al and cBN under high temperature and high pressure condition. Differential scanning calorimetry (DSC), X-ray diffraction (XRD), scanning electronic microscopy (SEM) and energy-dispersive X-ray spectroscopy (EDS) elemental mapping analyses and laser flashing thermal conductivity measurements were performed to investigate the sintering properties and thermal conductivity of the Al-cBN ceramic sinters. XRD analysis revealed these Al-cBN ceramic sinters were composed of a large portion of cBN and of a small portion of AlN, and very little amount of AlB 12 and hBN. Formation of boundary phase resulted in the rapid densification of the sinters, as well as the increase of their relative density with increasing Al additions. The Al-cBN ceramic sinters have a maximum thermal conductivity of about 1.94 W/cm K at room temperature and a much higher value of about 2.04 W/cm K at 200 °C. Their high thermal conductivity over that of AlN-hBN composites promise Al-cBN ceramic sinters favorite candidates as high efficiency heat sink materials for wide band gap semiconductors.

  15. Fracture mechanisms in biopolymer films using coupling of mechanical analysis and high speed visualization technique

    NARCIS (Netherlands)

    Paes, S.S.; Yakimets, I.; Wellner, N.; Hill, S.E.; Wilson, R.H.; Mitchell, J.R.

    2010-01-01

    The aim of this study was to provide a detailed description of the fracture mechanisms in three different biopolymer thin materials: gelatin, hydroxypropyl cellulose (HPC) and cassava starch films. That was achieved by using a combination of fracture mechanics methodology and in situ visualization w

  16. High inter-tester reliability of the new mobility score in patients with hip fracture

    DEFF Research Database (Denmark)

    Kristensen, M.T.; Bandholm, T.; Foss, N.B.;

    2008-01-01

    OBJECTIVE: To assess the inter-tester reliability of the New Mobility Score in patients with acute hip fracture. DESIGN: An inter-tester reliability study. SUBJECTS: Forty-eight consecutive patients with acute hip fracture at a median age of 84 (interquartile range, 76-89) years; 40 admitted from...

  17. Quasi-static tensile deformation and fracture behavior of a highly particle-filled composite using digital image correlation method

    Institute of Scientific and Technical Information of China (English)

    2011-01-01

    Polymer bonded explosives (PBXs) are highly particle-filled composite materials.This paper experimentally studies the tensile deformation and fracture behavior of a PBX simulation by using the semi-circular bending (SCB) test.The deformation and fracture process of a pre-notched SCB sample with a random speckle pattern is recorded by a charge coupled device camera.The displacement and strain fields on the observed surface during the loading process are obtained by using the digital image correlation method....

  18. Stress fractures in runners.

    Science.gov (United States)

    McCormick, Frank; Nwachukwu, Benedict U; Provencher, Matthew T

    2012-04-01

    Stress fractures are a relatively common entity in athletes, in particular, runners. Physicians and health care providers should maintain a high index of suspicion for stress fractures in runners presenting with insidious onset of focal bone tenderness associated with recent changes in training intensity or regimen. It is particularly important to recognize “high-risk” fractures, as these are associated with an increased risk of complication. A patient with confirmed radiographic evidence of a high-risk stress fracture should be evaluated by an orthopedic surgeon. Runners may benefit from orthotics, cushioned sneakers, interval training, and vitamin/calcium supplementation as a means of stress fracture prevention.

  19. High-impact poly(L/D-lactide) for fracture fixation: in vitro degradation and animal pilot study.

    Science.gov (United States)

    Tams, J; Joziasse, C A; Bos, R R; Rozema, F R; Grijpma, D W; Pennings, A J

    1995-12-01

    The impact strength of amorphous lactide copolymers can be significantly improved by blending with biodegradable rubbers. Rubber toughening of amorphous poly(85L/15D -lactide) with the copolymer poly (50/50-trimethylenecarbonate-co-epsilon-caprolactone) results in a high-impact polymer (PDLLA/P(TMC-CL)). In vitro, the PDLLA/P(TMC-CL) blend retained its tensile and impact strength for a long period of time. Up to 45 weeks, the amount of water absorbed by the blend remained very low and no significant mass loss was observed. To test the suitability for fracture fixation, in a dog study mandibular fractures were fixated with PDLLA/P(TMC-CL) bone plates and screws. Bone healing was uneventful without premature failure of the implants. Although long-term degradation studies have to be carried out, PDLLA/P(TMC-CL) seems to be promising for application in fracture fixation.

  20. Fatigue fracture of high-strength Al-Zn-Mg-Cu alloy

    Institute of Scientific and Technical Information of China (English)

    JIAN Hai-gen; JIANG Feng; WEN Kang; JIANG Long; HUANG Hong-feng; WEI Li-li

    2009-01-01

    X-ray diffractometry(XRD), optical microscopy(OM), scanning electron microscopy(SEM) were used to study the fatigue fracture of the T7451 Al-Zn-Mg-Cu alloy (470 ℃, 60 min+115 ℃, 8 h+165 ℃, 16 h). The study reveals mainly the microscopic structure of the alloy in the process of crack formation and crack growth. The fatigue fracture is characterized by three zones: fatigue crack source zone, fatigue crack propagation zone and fatigue fracture zone. The fatigue damage preferably incubates at the fractured inclusion particles at or near (about 25 μm) the specimen free surfaces, and these brittle Fe-rich intermetallic inclusion particles are (7-10) μm×(11-14) μm in size. Some features such as "feather-like", "river and range" and boundary extrusions can be observed in the fatigue propagation zone, and in the fatigue fracture zone the surface is rough and uneven.

  1. Simulation of Hydraulic Fracture in Unsaturated Soils with High Degree of Saturation

    Directory of Open Access Journals (Sweden)

    Tielin Chen

    2014-01-01

    Full Text Available A numerical simulation approach of hydraulic fracture process, considering the couplings of the stress distribution, the fluid flow of the water-air mixture, the compression and dissolution of air, and the element damage evolution, has been developed to investigate the mechanisms of crack initiation and propagation in porous media during hydraulic fracturing. The concept of homogenized pore fluid has been adopted to represent the water air mixture. A large number of numerical analysis on hydraulic fracturing in clay with incipient injection slot have been carried out to study the mechanism of hydraulic fracturing in unsaturated soil with the characteristic of critical model I type of crack loading using stress intensity factor KIc. The results provide a numerical picture depicting the mechanisms of crack initiation and propagation during hydraulic fracturing. The numerical results are in good agreement with the experimental results, which confirms the adequacy and the power of the numerical approach.

  2. A lattice-particle approach for the simulation of fracture processes in fiber-reinforced high-performance concrete

    NARCIS (Netherlands)

    Montero-Chacón, F.; Schlangen, H.E.J.G.; Medina, F.

    2013-01-01

    The use of fiber-reinforced high-performance concrete (FRHPC) is becoming more extended; therefore it is necessary to develop tools to simulate and better understand its behavior. In this work, a discrete model for the analysis of fracture mechanics in FRHPC is presented. The plain concrete matrix,

  3. Temperature-dependent fracture mechanisms in gel-spun hot-drawn ultra-high molecular weight polyethylene fibres

    NARCIS (Netherlands)

    Pras, E; Pennings, AJ

    1998-01-01

    Tensile testing of gel-spun hot-drawn ultra-high molecular weight polyethylene (UHMWPE) fibres reveal a ductile-brittle transition temperature. Ductile fracture above the transition temperature is believed to be initiated by a stress-induced orthorhombic-hexagonal phase transition, whereas at lower

  4. High Complication Rate With Anterior Total Hip Arthroplasties on a Fracture Table

    Science.gov (United States)

    Collis, Dennis K.

    2010-01-01

    Background Recent attention in THA has focused on minimally invasive techniques and their short-term outcomes. Despite much debate over the outcomes and complications of the two-incision and the mini-lateral and mini-posterior approaches, complications arising from use of the anterior THA on a fracture table are not well documented. Questions/purposes We determined the intraoperative and postoperative complications with the anterior approach to THA through an extended single-surgeon patient series. Methods We reviewed 800 primary THAs performed anteriorly with the aid of a fracture table over 5 years and recorded all intraoperative and postoperative complications up to latest followup (average, 1.8 years; range, 0–5 years). Patients with severe acetabular deformity or severe flexion contractures were excluded and those surgeries were performed with a lateral approach during the time period of this study. Results Intraoperative complications included 19 trochanteric fractures, three femoral perforations, one femoral fracture, one acetabular fracture, one bleeding complication, and one case of cardiovascular collapse. There were no ankle fractures. Postoperative complications included seven patients with dislocations; seven with deep infections; one with delayed femur fracture; 37 with wound complications, among which 13 had reoperation for local débridement; 14 with deep venous thrombosis; and two with pulmonary embolism; and 31 other nonfatal medical complications. Conclusions The main intraoperative complications of trochanteric fractures and perforations occurred mostly early in the series, while the main postoperative complications related to wound healing were prevalent throughout the entire series. Despite potential advantages of use of a fracture table, surgeons should be aware of the potential complications of trochanteric fractures, perforations, and wound-healing problems associated with this technique. Level of Evidence Level IV, therapeutic study

  5. Effects of bonding temperature on microstructure, fracture behavior and joint strength of Ag nanoporous bonding for high temperature die attach

    Energy Technology Data Exchange (ETDEWEB)

    Kim, Min-Su, E-mail: mskim927@gmail.com [Joining and Welding Research Institute, Osaka University, 11-1 Mihogaoka, Ibaraki, Osaka 567-0047 (Japan); Graduate School of Engineering, Osaka University, 2-1 Yamadaoka, Suita, Osaka 565-0871 (Japan); Nishikawa, Hiroshi [Joining and Welding Research Institute, Osaka University, 11-1 Mihogaoka, Ibaraki, Osaka 567-0047 (Japan)

    2015-10-01

    Ag nanoparticle sintering has received much attention as an alternative joining method to lead-based soldering for high temperature electronic applications. However, there are still certain issues with this method, such as difficulties of in controlling the joining layer thickness and the occurrence of unexpected voids resulting from solvent evaporation. In this study, the effect of bonding temperature (200–400 °C) and environment (air and N{sub 2}) on the joint strength of Ag nanoporous bonding (NPB) on electroless nickel/immersion gold finished Cu disks was investigated. A nanoporous Ag sheet fabricated using dealloying method from an Al–Ag precursor was adopted as the insert material. The NPB was conducted at various temperatures (200–400 °C) for 30 min at a pressure of 20 MPa in both air and N{sub 2} environments. The joint strength of NPB was closely related with the microstructure of the Ag layer and the fracture mode of the joint, and increased with increasing bonding temperature through the formation of strong interface and a coarsened Ag layer. The effect of the bonding environment was not significant, except in the case of bonding temperature of 400 °C.

  6. Electrical conduction mechanism in bulk ceramic insulators at high voltages until dielectric breakdown

    Science.gov (United States)

    Neusel, C.; Jelitto, H.; Schneider, G. A.

    2015-04-01

    In order to develop and verify a dielectric breakdown model for bulk insulators thicker than 100 μm, the knowledge of the dominating conduction mechanism at high electric fields, or respectively voltages, is necessary. The dielectric breakdown is the electrical failure of an insulator. In some existing breakdown models, ohmic conduction is assumed as dominating conduction mechanism. For verification, the dominating dc conduction mechanism of bulk insulators at room temperature was investigated by applying high voltages up to 70 kV to the insulator until dielectric breakdown occurs. Four conduction models, namely, ohmic, space charge limited, Schottky, and Poole-Frenkel conduction, were employed to identify the dominating conduction mechanism. Comparing the calculated permittivities from the Schottky and Poole-Frenkel coefficients with experimentally measured permittivity, Schottky and Poole-Frenkel conduction can be excluded as dominating conduction mechanism. Based on the current density voltage characteristics (J-V-curve) and the thickness-dependence of the current density, space charge limited conduction (SCLC) was identified to be the dominating conduction mechanism at high voltages leading to dielectric breakdown. As a consequence, breakdown models based on ohmic conduction are not appropriate to explain the breakdown of the investigated bulk insulators. Furthermore, the electrical failure of the examined bulk insulators can only be described correctly by a breakdown model which includes SCLC as conduction mechanism.

  7. High yield sample preconcentration using a highly ion-conductive charge-selective polymer.

    Science.gov (United States)

    Chun, Honggu; Chung, Taek Dong; Ramsey, J Michael

    2010-07-15

    The development and analysis of a microfluidic sample preconcentration system using a highly ion-conductive charge-selective polymer [poly-AMPS (2-acrylamido-2-methyl-1-propanesulfonic acid)] is reported. The preconcentration is based on the phenomenon of concentration polarization which develops at the boundaries of the poly-AMPS with buffer solutions. A negatively charged polymer, poly-AMPS, positioned between two microchannels efficiently extracts cations through its large cross section, resulting in efficient anion sample preconcentration. The present work includes the development of a robust polymer that is stable over a wide range of buffers with varying chemical compositions. The sample preconcentration effect remains linear to over 3 mM (0.15 pmol) and 500 microM (15 fmol) for fluorescein and TRITC-tagged albumin solutions, respectively. The system can potentially be used for concentrating proteins on microfluidic devices with subsequent analysis for proteomic applications.

  8. Double-shot inkjet printing for high-conductivity polymer electrode

    Energy Technology Data Exchange (ETDEWEB)

    Yoon, Sejeong [The School of Interdisciplinary Bioscience and Bioengineering, Pohang University of Science and Technology, Pohang 37673 (Korea, Republic of); Sohn, Sunyoung; Kwon, Jimin; Park, Ju An [Department of Creative IT Engineering, Pohang University of Science and Technology, Pohang 37673 (Korea, Republic of); Jung, Sungjune, E-mail: sjjung@postech.ac.kr [The School of Interdisciplinary Bioscience and Bioengineering, Pohang University of Science and Technology, Pohang 37673 (Korea, Republic of); Department of Creative IT Engineering, Pohang University of Science and Technology, Pohang 37673 (Korea, Republic of)

    2016-05-31

    This paper presents a printing method to form a high-conductivity patterned poly(3,4-ethylenedioxythiophene):poly(styrenesulfonate) (PEDOT:PSS) film. A modified PEDOT:PSS ink containing a secondary dopant (dimethyl sulfoxide) and fluorosurfactant (Zonyl FS-300) was inkjet-printed to form a uniform conducting layer, and the dimethyl sulfoxide, conductivity enhancer, was over-printed onto it to further enhance its conductivity. We achieved high-conductivity greater than 1000 S cm{sup −1} by only using inkjet-printing technique. The mechanism of conductivity enhancement was investigated with X-ray photoelectron spectroscopy and atomic force microscopy analyses. The printing process for high-conductivity PEDOT:PSS was applied to pattern a transparent anode for the fabrication of an organic light emitting diode. - Highlights: • Demonstrated a double-shot inkjet printing process for high-conductivity electrodes • Achieved high-conductivity greater than 1000 S cm{sup −1} only by inkjet-printing • Fabricated OLEDs with high-conductivity inkjet-printed anodes.

  9. MULTI-PHASE FRACTURE-MATRIX INTERACTIONS UNDER STRESS CHANGES

    Energy Technology Data Exchange (ETDEWEB)

    A.S. Grader; D. Elsworth; P.M. Halleck; F. Alvarado; A. Alajmi; Z. Karpyn; N. Mohammed; S. Al-Enezi

    2005-06-15

    The main objectives of this project are to quantify the changes in fracture porosity and multiphase transport properties as a function of confining stress. These changes will be integrated into conceptual and numerical models that will improve our ability to predict and optimize fluid transport in fractured system. This report details our progress on: (a) developing the direct experimental measurements of fracture aperture and topology and fluid occupancy using high-resolution x-ray micro-tomography, (b) quantifying the effect of confining stress on the distribution of fracture aperture, and (c) characterization of shear fractures and their impact on multi-phase flow. The three-dimensional surface that describes the large-scale structure of the fracture in the porous medium can be determined using x-ray micro-tomography with significant accuracy. Several fractures have been scanned and the fracture aperture maps have been extracted. The success of the mapping of fracture aperture was followed by measuring the occupancy of the fracture by two immiscible phases, water and decane, and water and kerosene. The distribution of fracture aperture depends on the effective confining stress on the nature of the rock and the type and distribution of the asperities that keep the fracture open. Fracture apertures at different confining stresses were obtained by micro-tomography covering a range of about two thousand psig. Initial analysis of the data shows a significant aperture closure with increase in effective confining stress. Visual descriptions of the process are shown in the report while detailed analysis of the behavior of the distribution of fracture aperture is in progress. Both extensional and shear fractures are being considered. The initial multi-phase flow tests were done in extensional fractures. Several rock samples with induced shear fracture are being studies, and some of the new results are presented in this report. These samples are being scanned in order to

  10. Influence of Reservoir Mineralogical Composition on Acid Fracture Conductivity%储层岩石矿物成分对酸蚀裂缝导流能力的影响

    Institute of Scientific and Technical Information of China (English)

    李沁; 伊向艺; 卢渊; 宋毅

    2013-01-01

    储层岩石矿物成分是酸压改造效果影响因素之一.研究认为,在储层岩石矿物成分中易溶物的含量及分布方式决定了酸蚀裂缝导流能力大小,易溶蚀物的含量越多,岩石溶蚀速率越快.室内测试了不同溶蚀速率下的灰岩和白云岩的酸蚀裂缝导流能力,研究了岩石溶蚀速率、易溶蚀物含量对酸蚀裂缝导流能力的影响,对酸压工艺设计方案提出了指导性建议.研究结果表明,储层岩石溶蚀速率与酸蚀裂缝导流能力增加倍比存在抛物线关系,易溶蚀物占30%~40%时酸蚀裂缝导流能力保持较好.%The formation rock mineral composition is one of the factors affecting the effect of acid fracturing.This research indicates that the content and distribution of easy dissolution in mineral composition of the reservoir rock determines the value of conductivity in etching fracture,and the more content of easy dissolution there is,the faster the speed of dissolution is.In this paper,the conductivity of etching fracture have been tested with different dissolution rates of limestone and dolomite.The effect of conductivity of etching fracture with content of easy dissolution and dissolution rate has been researched.Some guidance advice to design proposal of acid fracturing treatment is presented.The results show that the fracture conductivity between the corrosion rate and the acid etching is the parabolic relationship.When easy dissolution accounts for 30% to 40%,the conductivity of etching fracture stays good.

  11. Ultrahigh Oxidation Resistance and High Electrical Conductivity in Copper-Silver Powder

    Science.gov (United States)

    Li, Jiaxiang; Li, Yunping; Wang, Zhongchang; Bian, Huakang; Hou, Yuhang; Wang, Fenglin; Xu, Guofu; Liu, Bin; Liu, Yong

    2016-12-01

    The electrical conductivity of pure Cu powder is typically deteriorated at elevated temperatures due to the oxidation by forming non-conducting oxides on surface, while enhancing oxidation resistance via alloying is often accompanied by a drastic decline of electrical conductivity. Obtaining Cu powder with both a high electrical conductivity and a high oxidation resistance represents one of the key challenges in developing next-generation electrical transferring powder. Here, we fabricate a Cu-Ag powder with a continuous Ag network along grain boundaries of Cu particles and demonstrate that this new structure can inhibit the preferential oxidation in grain boundaries at elevated temperatures. As a result, the Cu-Ag powder displays considerably high electrical conductivity and high oxidation resistance up to approximately 300 °C, which are markedly higher than that of pure Cu powder. This study paves a new pathway for developing novel Cu powders with much enhanced electrical conductivity and oxidation resistance in service.

  12. Normal-conducting RF cavity of high current photoinjector for high power CW FEL.

    Energy Technology Data Exchange (ETDEWEB)

    Kurennoy, S. (Sergey); Schrage, D. L. (Dale L.); Wood R. L. (Richard L.); Schultheiss, T. (Thomas); Rathke, J. (John); Young, L. M. (Lloyd M.)

    2004-01-01

    An RF photoinjector capable of producing high continuous average current with low emittance and energy spread is a key enabling technology for high power CW FEL. The design of a 2.5-cell, {pi}-mode, 700-MHz normal-conducting RF photoinjector cavity with magnetic emittance compensation is completed. With the electric field gradients of 7.7, and 5 MV/m in the three cells, the photoinjector will produce a 2.5-MeV electron beam with 3-nC charge per bunch and the transverse rms emittance 7 mm-mrad. Electromagnetic modeling was used extensively to optimize ridge-loaded tapered waveguides and RF couplers, which led to a new, improved coupler iris design. The results, combined with a thermal and stress analysis, show that the challenging problem of cavity cooling can be successfully solved. The manufacturing of a demo 100-mA (at 35 MHz bunch repetition rate) photoinjector is underway. The design is scalable to higher power levels by increasing the electron bunch repetition rate, and provides a path to a MW-class amplifier FEL. This paper presents the cavity design and details of RF coupler modeling.

  13. Normal conducting RF cavity of high current photoinjector for high power CW FEL.

    Energy Technology Data Exchange (ETDEWEB)

    Kurennoy, S. (Sergey); Schrage, D. L. (Dale L.); Wood R. L. (Richard L.); Schultheiss, T. (Thomas); Rathke, J. (John); Christina, V.; Young, L. M. (Lloyd M.)

    2004-01-01

    An RF photoinjector capable of producing high continuous average current with low emittance and energy spread is a key enabling technology for high power CW FEL. The design of a 2.5-cell {pi}-mode 700-MHz normal-conducting RF photoinjector cavity with magnetic emittance compensation is completed. With the electric field gradients of 7, 7, and 5 MV/m in the three cells, the photoinjector will produce a 2.5-MeV electron beam with 3-nC charge per bunch and 7 mm-mrad transverse rms emittance. Electromagnetic modeling was used extensively to optimize ridge-loaded tapered waveguides and RF couplers, which led to a new improved coupler-iris design. The results, combined with a thermal/stress analysis, show that the challenging problem of cavity cooling can be successfully solved. A demo 100-mA (at 35-MHz bunch-repetition rate) photoinjector is being manufactured. The design is scalable to higher power levels by increasing the bunch repetition rate, and provides a path to a MW-class amplifier FEL. The cavity design and details of RF coupler modeling are presented.

  14. Normal-Conducting High Current RF Photoinjector for High Power CW FEL

    CERN Document Server

    Kurennoy, Sergey; Nguyen, Dinh C; Rathke, John; Schrage, Dale L; Schultheiss, Tom; Wood, Richard L; Young, Lloyd M

    2005-01-01

    An RF photoinjector capable of producing high average current with low emittance and energy spread is a key enabling technology for high power CW FEL. The design of a 2.5-cell, pi-mode, 700-MHz normal-conducting RF photoinjector cavity with magnetic emittance compensation is completed. With average gradients of 7, 7, and 5 MV/m in its three accelerating cells, the photoinjector will produce a 2.5-MeV electron beam with 3-nC charge per bunch and transverse rms emittance below 7 mm-mrad. Electromagnetic modeling has been used extensively to optimize ridge-loaded tapered waveguides and RF couplers, and led to a new, improved coupler iris design. The results, combined with a thermal and stress analysis, show that the challenging problem of cavity cooling can be successfully solved. Fabrication of a demo 100-mA (at 35 MHz bunch repetition rate) photoinjector is underway. The design is scalable to higher average currents by increasing the electron bunch repetition rate, and provides a path to a MW-class FEL. This p...

  15. Highly Conductive Aromatic Functionalized Multi-Walled Carbon Nanotube for Inkjet Printable High Performance Supercapacitor Electrodes.

    Directory of Open Access Journals (Sweden)

    Sanjeev K Ujjain

    Full Text Available We report the functionalization of multiwalled carbon nanotubes (MWCNT via the 1,3-dipolar [3+2] cycloaddition of aromatic azides, which resulted in a detangled CNT as shown by transmission electron microscopy (TEM. Carboxylic moieties (-COOH on aromatic azide result in highly stable aqueous dispersion (max. conc. ~ 10 mg/mL H2O, making the suitable for inkjet printing. Printed patterns on polyethylene terephthalate (PET flexible substrate exhibit low sheet resistivity ~65 Ω. cm, which is attributed to enhanced conductivity. Fabricated Supercapacitors (SC assembled using these printed substrates exhibit good electrochemical performance in organic as well as aqueous electrolytes. High energy and power density (57.8 Wh/kg and 0.85 kW/kg in 1M H2SO4 aqueous electrolyte demonstrate the excellent performance of the proposed supercapacitor. Capacitive retention varies from ~85-94% with columbic efficiency ~95% after 1000 charge/discharge cycles in different electrolytes, demonstrating the excellent potential of the device for futuristic power applications.

  16. Design of instantaneous liquid film thickness measurement system for conductive or non-conductive fluid with high viscosity

    Directory of Open Access Journals (Sweden)

    Yongxin Yu

    2017-06-01

    Full Text Available In the paper, a new capacitive sensor with a dielectric film coating was designed to measure the thickness of the liquid film on a flat surface. The measured medium can be conductive or non-conductive fluid with high viscosity such as silicone oil, syrup, CMC solution and melt. With the dielectric film coating, the defects caused by the humidity in a capacitor can be avoided completely. With a excitation frequency 0-20kHz, the static permittivity of capacitive sensor is obtained and stable when small thicknesses are monitored within the frequency of 0-3kHz. Based on the measurement principle, an experimental system was designed and verified including calibration and actual measurement for different liquid film thickness. Experimental results showed that the sensitivity, the resolution, repeatability and linear range of the capacitive sensor are satisfied to the liquid film thickness measurement. Finally, the capacitive measuring system was successfully applied to the water, silicone oil and syrup film thickness measurement.

  17. Hot-Pressed BN-AlN Ceramic Composites of High Thermal Conductivity

    Science.gov (United States)

    Kanai, Takao; Tanemoto, Kei; Kubo, Hiroshi

    1990-04-01

    Hexagonal boron nitride-aluminum nitride (75-25 wt%) ceramic composites are synthesized by uniaxial hot pressing. High thermal conductivity, 247 W/(m\\cdotK), is attained for the perpendicular direction of the hot-pressing axis of the sintered body, by optimizing the amount of added sintering aid, calcium carbide. The composites have remarkable anisotropy with respect to structure and thermal conductivity. The revelation mechanism of high thermal conductivity is discussed.

  18. Effects of High Rate Shear on the Microstructure and Deformation and Fracture Behavior of Two High Strength Steels

    Science.gov (United States)

    1989-04-01

    Nickel (Ni) content between the steels. As shown in Table 1, the Q&T steel had 5% Ni while the DQ steel had only 1% Ni. Nickel in alpha iron has been...Yield and Fracture Behavior of Alpha Iron ," Trans. Met. Soc. of AIME, Vol. 242, pp. 306 - 314, February, 1968 Kalthoff, J.F. and Winkler, S., "Fracture

  19. Egyptian diatomite as high fluid loss squeeze slurry in sealing fractures and

    Directory of Open Access Journals (Sweden)

    A.M. Al-Sabagh

    2016-09-01

    Full Text Available Lost circulation is the most costly mud related drilling problem, and induced fracture. Water slurry of diatomite is used as the high fluid loss squeeze slurry in the treatment of lost circulation and in decreasing fluid loss. Egypt has diatomite deposits, especially in El-Fayuom Depression. Fourteen samples were collected from Qasr El-Sagha at the northern shore of Birket Qarun. Samples were examined to identify the diatom species then subjected to X-ray fluorescence, XRD and grain size distribution tests. A total of 38 species related to 13 diatom genera were identified. Cocconeis, Epithemia and Rhopalodia were the predominant genera. The diatomaceous earth which acts as a filter aid material was tested with different additives; bentonite, lime, finely divided paper, polymer, barite and different concentrations with different types of lost circulation materials (LCM to form a high fluid loss squeeze slurry. As a result the required time for collecting the filtrate was decreased to be in the range of 50 s to 1 min and 49 s comparing with the international standard which recommended the filtrate should be collected maximum within 2–3 min.

  20. Incidence of low- and high-energy fractures in persons with and without HIV-infection: a Danish population-based cohort study

    DEFF Research Database (Denmark)

    Hansen, Ann-Brit E; Gerstoft, Jan; Kronborg, Gitte;

    2012-01-01

    OBJECTIVE:: To compare fracture risk in persons with and without HIV-infection and to examine the influence of HAART initiation on risk of fracture. DESIGN:: Population-based nationwide cohort study using Danish registries. METHODS:: Outcome measures were time to first fracture at any site, time....../HCV-coinfected patients had increased risk of low-energy fracture, IRR of 1.6 (95% CI; 1.4-1.8) and 3.8 (95% CI; 3.0-4.9). However, only HIV/HCV-coinfected patients had increased risk of high-energy fracture, IRR of 2.4 (95 %CI; 2.0-2.9). Among HIV-monoinfected patients the risk of low-energy fracture was only...

  1. High-resolution-cone beam tomography analysis of bone microarchitecture in patients with acromegaly and radiological vertebral fractures.

    Science.gov (United States)

    Maffezzoni, Filippo; Maddalo, Michele; Frara, Stefano; Mezzone, Monica; Zorza, Ivan; Baruffaldi, Fabio; Doglietto, Francesco; Mazziotti, Gherardo; Maroldi, Roberto; Giustina, Andrea

    2016-11-01

    Vertebral fractures are an emerging complication of acromegaly but their prediction is still difficult occurring even in patients with normal bone mineral density. In this study we evaluated the ability of high-resolution cone-beam computed tomography to provide information on skeletal abnormalities associated with vertebral fractures in acromegaly. 40 patients (24 females, 16 males; median age 57 years, range 25-72) and 21 healthy volunteers (10 females, 11 males; median age 60 years, range: 25-68) were evaluated for trabecular (bone volume/trabecular volume ratio, mean trabecular separation, and mean trabecular thickness) and cortical (thickness and porosity) parameters at distal radius using a high-resolution cone-beam computed tomography system. All acromegaly patients were evaluated for morphometric vertebral fractures and for mineral bone density by dual-energy X-ray absorptiometry at lumbar spine, total hip, femoral neck, and distal radius. Acromegaly patients with vertebral fractures (15 cases) had significantly (p cone-beam computed tomography at the distal radius may be useful to evaluate and predict the effects of acromegaly on bone microstructure.

  2. Multi-rate mass transfer modeling of two-phase flow in highly heterogeneous fractured and porous media

    CERN Document Server

    Tecklenburg, Jan; Carrera, Jesus; Dentz, Marco

    2016-01-01

    We study modeling of two-phase flow in highly heterogeneous fractured and porous media. The flow behaviour is strongly influenced by mass transfer between a highly permeable (mobile) fracture domain and less permeable (immobile) matrix blocks. We quantify the effective two-phase flow behaviour using a multirate rate mass transfer (MRMT) approach. We discuss the range of applicability of the MRMT approach in terms of the pertinent viscous and capillary diffusion time scales. We scrutinize the linearization of capillary diffusion in the immobile regions, which allows for the formulation of MRMT in the form of a non-local single equation model. The global memory function, which encodes mass transfer between the mobile and the immobile regions, is at the center of this method. We propose two methods to estimate the global memory function for a fracture network with given fracture and matrix geometry. Both employ a scaling approach based on the known local memory function for a given immobile region. With the firs...

  3. Effect of Carbon on Grain Boundary Segregation of Phosphorus and Phosphorus-Induced Intergranular Fracture in High Purity Iron with Phosphorus

    Institute of Scientific and Technical Information of China (English)

    2003-01-01

    The segregation of carbon at grain boundaries and its effect on phosphorus segregation and phosphorus-induced intergranular fracture in the alloy of high purity iron with phosphorus were investigated by scanning Auger electron spectroscopy, impact test and SEM observation of fractured surface. The experimental results showed that the carbon segregation at grain boundaries decreases the phosphorus segregation, and a change of fracture mode from intergranular fracture to transgranular one, hence a decrease of ductile-brittle transition temperature is observed. The mechanism of these effects was discussed.

  4. Cryogenic Fracturing: Laboratory Visualization Experiments and Numerical Simulations Using Peridynamics

    Science.gov (United States)

    Martin-Short, R.; Edmiston, J. K.

    2015-12-01

    Typical hydraulic fracturing operations involve the use of a large quantity of water, which can be problematic for several reasons including possible formation (permeability) damage, disposal of waste water, and the use of precious local water resource. An alternate reservoir permeability enhancing technology not requiring water is cryogenic fracturing. This method induces controlled fracturing of rock formations by thermal shock and has potentially important applications in the geothermal and hydrocarbon industries. In this process, cryogenic fluid—such as liquid nitrogen—is injected into the subsurface, causing fracturing due to thermal gradients. These fractures may improve the formation permeability relative to that achievable by hydraulic fracturing alone. We conducted combined laboratory visualization and numerical simulations studies of thermal-shock-induced fracture initiation and propagation resulting from liquid nitrogen injection in rock and analog materials. The experiment used transparent soda-lime glass cubes to facilitate real-time visualization of fracture growth and the fracture network geometry. In this contribution, we report the effect of overall temperature difference between cryogenic fluid and solid material on the produced fracture network, by pre-heating the glass cubes to several temperatures and injecting liquid nitrogen. Temperatures are monitored at several points by thermocouple and the fracture evolution is captured visually by camera. The experiment was modeled using a customized, thermoelastic, fracture-capable numerical simulation code based on peridynamics. The performance of the numerical code was validated by the results of the laboratory experiments, and then the code was used to study the different factors affecting a cryogenic fracturing operation, including the evolution of residual stresses and constitutive relationships for material failure. In complex rock such as shale, understanding the process of cryogenic

  5. High-resolution Fracture Characterization Using Elastic Full-waveform Inversion

    KAUST Repository

    Zhang, Z.

    2017-05-26

    Current methodologies to characterize fractures at the reservoir scale have serious limitations in spatial resolution. Here, we propose to estimate both the spatial distribution and physical properties of fractures using full waveform inversion (FWI) of multicomponent surface seismic data. An effective orthorhombic medium with five clusters of vertical fractures distributed in a checkboard fashion is used to test the algorithm. To better understand the inversion results, we analyze the FWI radiation patterns of the fracture weaknesses. A shape regularization term is added to the objective function to improve the inversion for the horizontal weakness, which is otherwise poorly constrained. Alternatively, a simplified model of penny-shaped cracks is used to reduce the nonuniqueness in the inverted weaknesses and achieve a faster convergence.

  6. Directly patternable, highly conducting polymers for broad applications in organic electronics.

    Science.gov (United States)

    Yoo, Joung Eun; Lee, Kwang Seok; Garcia, Andres; Tarver, Jacob; Gomez, Enrique D; Baldwin, Kimberly; Sun, Yangming; Meng, Hong; Nguyen, Thuc-Quyen; Loo, Yueh-Lin

    2010-03-30

    Postdeposition solvent annealing of water-dispersible conducting polymers induces dramatic structural rearrangement and improves electrical conductivities by more than two orders of magnitude. We attain electrical conductivities in excess of 50 S/cm when polyaniline films are exposed to dichloroacetic acid. Subjecting commercially available poly(ethylene dioxythiophene) to the same treatment yields a conductivity as high as 250 S/cm. This process has enabled the wide incorporation of conducting polymers in organic electronics; conducting polymers that are not typically processable can now be deposited from solution and their conductivities subsequently enhanced to practical levels via a simple and straightforward solvent annealing process. The treated conducting polymers are thus promising alternatives for metals as source and drain electrodes in organic thin-film transistors as well as for transparent metal oxide conductors as anodes in organic solar cells and light-emitting diodes.

  7. Facile Method to Fabricate Highly Thermally Conductive Graphite/PP Composite with Network Structures.

    Science.gov (United States)

    Feng, Changping; Ni, Haiying; Chen, Jun; Yang, Wei

    2016-08-03

    Thermally conductive polymer composites have aroused significant academic and industrial interest for several decades. Herein, we report a novel fabrication method of graphite/polypropylene (PP) composites with high thermal conductivity in which graphite flakes construct a continuous thermally conductive network. The thermal conductivity coefficient of the graphite/PP composites is markedly improved to be 5.4 W/mK at a graphite loading of 21.2 vol %. Such a great improvement of the thermal conductivity is ascribed to the occurrence of orientations of crystalline graphite flakes with large particles around PP resin particles and the formation of a perfect thermally conductive network. The model of Hashin-Shtrikman (HS) is adopted to interpret the outstanding thermally conductive property of the graphite/PP composites. This work provides a guideline for the easy fabrication of thermally conductive composites with network structures.

  8. Pelvic fractures and mortality.

    OpenAIRE

    K.H. Chong; DeCoster, T.; Osler, T.; Robinson, B.

    1997-01-01

    A retrospective study of all patients (N = 343) with pelvic fractures admitted to our trauma service was conducted to evaluate the impact of pelvic fractures on mortality. All patients sustained additional injuries with an average Injury Severity Score (ISS) of twenty. Thirty-six patients died. This group had more severe pelvic fractures as graded by the Tile classification as well as a greater number and severity of associated injuries. Six patients died as a direct result of pelvic hemorrha...

  9. High Serum 25-hydroxyvitamin D is Associated with Low Incidence of Stress Fractures

    Science.gov (United States)

    2011-06-01

    of Family and Preventive Medicine, School of Medicine, University of California, San Diego, La Jolla, California 3 Osteoporosis Research Center...group (p 0.01) (9). Amenorrhea and age older than 25 years were also predictors of increased risk of stress fracture, while history of exercise was... exercise were independently associated with risk of fractures (9). In this study, it was not possible to include amenorrhea and exercise history (prior to

  10. Low incidence of flexion-type supracondylar humerus fractures but high rate of complications.

    Science.gov (United States)

    Kuoppala, Eira; Parviainen, Roope; Pokka, Tytti; Sirviö, Minna; Serlo, Willy; Sinikumpu, Juha-Jaakko

    2016-08-01

    Background and purpose - Supracondylar humerus fractures are the most common type of elbow fracture in children. A small proportion of them are flexion-type fractures. We analyzed their current incidence, injury history, clinical and radiographic findings, treatment, and outcomes. Patients and methods - We performed a population-based study, including all children <16 years of age. Radiographs were re-analyzed to include only flexion-type supracondylar fractures. Medical records were reviewed and outcomes were evaluated at a mean of 9 years after the injury. In addition, we performed a systematic literature review of all papers published on the topic since 1990 and compared the results with the findings of the current study. Results - During the study period, the rate of flexion-type fractures was 1.2% (7 out of 606 supracondylar humeral fractures). The mean annual incidence was 0.8 per 105. 4 fractures were multidirectionally unstable, according to the Gartland-Wilkins classification. All but 1 were operatively treated. Reduced range of motion, changed carrying angle, and ulnar nerve irritation were the most frequent short-term complications. Finally, in the long-term follow-up, mean carrying angle was 50% more in injured elbows (21°) than in uninjured elbows (14°). 4 patients of the 7 achieved a satisfactory long-term outcome according to Flynn's criteria. Interpretation - Supracondylar humeral flexion-type fractures are rare. They are usually severe injuries, often resulting in short-term and long-term complications regardless of the original surgical fixation used.

  11. Tensile fracture and shear localization under high loading rate in tungsten alloys

    OpenAIRE

    Couque, H.; Lankford, J.; Bose, A

    1992-01-01

    The influence of loading rate and microstructure on the tensile and compressive failure properties of three microstructurally dissimilar tungsten alloys has been investigated. Dynamic tensile fracture properties were characterized through fracture toughness tests performed at a stress intensity loading rate of 106 MPa $\\sqrt{{\\rm m}}$ s-1, and by tensile testing at a strain rate of 103 s-1. Shear banding phenomena were investigated by means of compression tests performed at strain rates of 5 ...

  12. High-pressure injection of dissolved oxygen for hydrocarbon remediation in a fractured dolostone aquifer

    Science.gov (United States)

    Greer, K. D.; Molson, J. W.; Barker, J. F.; Thomson, N. R.; Donaldson, C. R.

    2010-10-01

    A field experiment was completed at a fractured dolomite aquifer in southwestern Ontario, Canada, to assess the delivery of supersaturated dissolved oxygen (supersaturated with respect to ambient conditions) for enhanced bioremediation of petroleum hydrocarbons in groundwater. The injection lasted for 1.5 h using iTi's gPro® oxygen injection technology at pressures of up to 450 kPa and at concentrations of up to 34 mg O 2/L. A three-dimensional numerical model for advective-dispersive transport of dissolved oxygen within a discretely-fractured porous medium was calibrated to the observed field conditions under a conservative (no-consumption) scenario. The simulation demonstrated that oxygen rapidly filled the local intersecting fractures as well as the porous matrix surrounding the injection well. Following injection, the local fractures were rapidly flushed by the natural groundwater flow system but slow back-diffusion ensured a relatively longer residence time in the matrix. A sensitivity analysis showed significant changes in behaviour with varying fracture apertures and hydraulic gradients. Applying the calibrated model to a 7-day continuous injection scenario showed oxygen residence times (at the 3 mg/L limit), within a radius of 2-4 m from the injection well, of up to 100 days. This study has demonstrated that supersaturated dissolved oxygen can be effectively delivered to this type of a fractured and porous bedrock system at concentrations and residence times potentially sufficient for enhanced aerobic biodegradation.

  13. High Prevalence of Sarcopenia in Korean Patients after Hip Fracture: a Case-Control Study.

    Science.gov (United States)

    Yoo, Jun Il; Ha, Yong Chan; Kwon, Hyeok Bin; Lee, Young Kyun; Koo, Kyung Hoi; Yoo, Moon Jib

    2016-09-01

    Sarcopenia-related falls and fractures are increasing worldwide due to the aging population. The purpose of this study was to 1) evaluate anthropometric characteristics related to hip fracture in Korean patients, 2) investigate sarcopenia prevalence in hip fracture (HF) and non-hip fracture (NF) groups, and 3) investigate the correlation between sarcopenia and osteoporosis. This case-control study examined 359 HF and 1,614 NF normal populations using Korea National Health and Nutrition Examination Survey data. We performed whole-body dual energy X-ray absorptiometry to analyze body composition using the skeletal muscle mass index (SMI: lean mass/height²) and bone mineral density (BMD). In the HF group, using the AWGS definition, the prevalence of sarcopenia in women and men was 44.3% and 68.2%, respectively; in the NF group, it was 7.1% and 16.1%, respectively. Lower appendicular SMI (P sarcopenia (P sarcopenia (OR = 6.52; 95% CI = 4.67-9.09), age (OR = 1.15; 95% CI = 1.13-1.17), and osteoporosis (OR = 1.87; 95% CI = 1.35-2.58) were associated with the occurrence of a hip fracture. This study showed a higher prevalence of sarcopenia in patients with hip fractures compared with a normal population, and higher prevalence of sarcopenia in men.

  14. Hydraulic Fracture Containment in Sand

    NARCIS (Netherlands)

    Dong, Y.

    2010-01-01

    The mechanism of hydraulic fracturing in soft, high permeability material is considered fundamentally different from that in hard, low permeability rock, where a tensile fracture is created and conventional linear elastic fracture mechanics (LEFM) applies. The fracturing and associated modeling work

  15. Is it possible to infer the frequency-dependent seismic attenuation of fractured materials from high-strain creep tests?

    Science.gov (United States)

    mallet, celine; quintal, beatriz; caspari, eva; holliger, klaus

    2016-04-01

    The seismic and hydraulic characterization of fractured rocks is an important objective for reservoir development in general and the production of geothermal energy in particular. The attenuation of seismic waves in saturated fractured media is governed by local displacements of the fluid relative to the solid induced by the compressions and extensions associated with the passing wavefield. This phenomenon is generally referred to as wave-induced fluid flow (WIFF). Recent evidence suggests that this energy dissipation mechanism is sensitive to the interconnectivity of the fractures, which offers the perspective of linking seismic observations to the hydraulic properties of fractured rocks. Here, we consider the results of laboratory experiments, which are referred to as creep tests. Such tests consist of applying a constant stress to a water-saturated thermally cracked glass sample and recording the resulting strain response as a function of time. The primary advantages of the considered material are (i) that the fracture network is well documented and (ii) that the homogeneous and non-porous glass matrix limits WIFF to the fracture network. Due to the high stress levels as well as other technical issues, creep tests are not commonly used for laboratory-based measurements of energy dissipation. Therefore, an objective of this study is to explore whether and to what extent such data can be interpreted in terms of the seismic attenuation characteristics of the probed samples, as this might open access to a vast reservoir of corresponding data, notably for cracked materials. Transforming the observed time-dependent stress-strain relation into the Fourier domain, allows us to infer the corresponding frequency-dependent attenuation characteristics, which we then seek to interpret through numerical simulations based on Biot's quasi-static poroelastic equations. The 2D geometry of the fracture network considered in these simulations is derived from a scanning electron

  16. Effect of linear sorption on solute transport in a coupled fracture-matrix system with sinusoidal fracture geometry

    Directory of Open Access Journals (Sweden)

    N.Natarajan

    2010-10-01

    Full Text Available Modeling of solute transport through fractured rock is an important component of in many disciplines especially groundwater contamination and nuclear waste disposal. Several studies have been conducted on single rock fracture using parallel plate model and recently solute and thermal transport has been numerically modeled in the sinusoidal fracture matrix coupled system. The effect of linear sorption has been studied on the same. Results suggest the high matrix porosity and matrix diffusion coefficient enhance the sorption process and reduce the matrix diffusion of solutes. The velocity of the fluid reduces with increment in fracture aperture.

  17. Effects of Precipitates in Cu upon Impact Fracture : An Ultra-High-Vacuum Study with Local Probe Scanning Auger/Electron Microscopy

    NARCIS (Netherlands)

    Agterveld, D.T.L. van; Palasantzas, G.; Hosson, J.Th.M. De

    2000-01-01

    In situ fracture under ultra-high vacuum (UHV) conditions of copper-alloys containing copper sulfide precipitates exhibits areas in the form of pits. The wide variety of morphologies depends significantly on the size of the existing precipitate. For large precipitates, the fractured surface reveals

  18. Imaging of insufficiency fractures

    Energy Technology Data Exchange (ETDEWEB)

    Krestan, Christian [Department of Radiology, Medical University of Vienna, Vienna General Hospital, Waehringerstr. 18-20, 1090 Vienna (Austria)], E-mail: christian.krestan@meduniwien.ac.at; Hojreh, Azadeh [Department of Radiology, Medical University of Vienna, Vienna General Hospital, Waehringerstr. 18-20, 1090 Vienna (Austria)

    2009-09-15

    This review focuses on the occurrence, imaging and differential diagnosis of insufficiency fractures. Prevalence, the most common sites of insufficiency fractures and their clinical implications are discussed. Insufficiency fractures occur with normal stress exerted on weakened bone. Postmenopausal osteoporosis is the most common cause of insufficiency fractures. Other conditions which affect bone turnover include osteomalacia, hyperparathyroidism, chronic renal failure and high-dose glucocorticoid therapy. It is a challenge for the radiologist to detect and diagnose insufficiency fractures, and to differentiate them from other bone lesions. Radiographs are still the most widely used imaging method for identification of insufficiency fractures, but sensitivity is limited, depending on the location of the fractures. Magnetic resonance imaging (MRI) is a very sensitive tool to visualize bone marrow abnormalities associated with insufficiency fractures. Thin section, multi-detector computed tomography (MDCT) depicts subtle fracture lines allowing direct visualization of cortical and trabecular bone. Bone scintigraphy still plays a role in detecting fractures, with good sensitivity but limited specificity. The most important differential diagnosis is underlying malignant disease leading to pathologic fractures. Bone densitometry and clinical history may also be helpful in confirming the diagnosis of insufficiency fractures.

  19. Potential Dependence of the conductivity of Poly(3-Methylthiophene) in Liquid So2/Electrolyte: A Finite Potential Window of High Conductivity

    Science.gov (United States)

    1988-08-15

    conductivity is somewhat less. The observation of lowered conductivity in highly oxidized polythiophenes is consistent with theoretical expectations1 𔄂 and...TITLE (include Secunty lafication) Potential Dependence of the Conductivity of Poly(3-methylthiophen in Liquid S02/Electrolyte: A Finite Potential...Window of High Conductivity 12. PERSONAL AUTHOR(S) David Ofer and Mark S. Wrighton 13a. TYPE OF REPORT 13b. TIME COVERED 114. DAT F Ofg𔃻 (Y%6onth, Oay

  20. Modeling Atmospheric Emissions and Calculating Mortality Rates Associated with High Volume Hydraulic Fracturing Transportation

    Science.gov (United States)

    Mathews, Alyssa

    Emissions from the combustion of fossil fuels are a growing pollution concern throughout the global community, as they have been linked to numerous health issues. The freight transportation sector is a large source of these emissions and is expected to continue growing as globalization persists. Within the US, the expanding development of the natural gas industry is helping to support many industries and leading to increased transportation. The process of High Volume Hydraulic Fracturing (HVHF) is one of the newer advanced extraction techniques that is increasing natural gas and oil reserves dramatically within the US, however the technique is very resource intensive. HVHF requires large volumes of water and sand per well, which is primarily transported by trucks in rural areas. Trucks are also used to transport waste away from HVHF well sites. This study focused on the emissions generated from the transportation of HVHF materials to remote well sites, dispersion, and subsequent health impacts. The Geospatial Intermodal Freight Transport (GIFT) model was used in this analysis within ArcGIS to identify roadways with high volume traffic and emissions. High traffic road segments were used as emissions sources to determine the atmospheric dispersion of particulate matter using AERMOD, an EPA model that calculates geographic dispersion and concentrations of pollutants. Output from AERMOD was overlaid with census data to determine which communities may be impacted by increased emissions from HVHF transport. The anticipated number of mortalities within the impacted communities was calculated, and mortality rates from these additional emissions were computed to be 1 in 10 million people for a simulated truck fleet meeting stricter 2007 emission standards, representing a best case scenario. Mortality rates due to increased truck emissions from average, in-use vehicles, which represent a mixed age truck fleet, are expected to be higher (1 death per 341,000 people annually).

  1. Experimental Study on the Electrical Conductivity of Pyroxene Andesite at High Temperature and High Pressure

    Science.gov (United States)

    Hui, KeShi; Dai, LiDong; Li, HePing; Hu, HaiYing; Jiang, JianJun; Sun, WenQing; Zhang, Hui

    2016-09-01

    The electrical conductivity of pyroxene andesite was in situ measured under conditions of 1.0-2.0 GPa and 673-1073 K using a YJ-3000t multi-anvil press and Solartron-1260 Impedance/Gain-phase analyzer. Experimental results indicate that the electrical conductivities of pyroxene andesite increase with increasing temperature, and the electrical conductivities decrease with the rise of pressure, and the relationship between electrical conductivity (σ) and temperature (T) conforms to an Arrhenius relation within a given pressure and temperature range. When temperature rises up to 873-923 K, the electrical conductivities of pyroxene andesite abruptly increase, and the activation enthalpy increases at this range, which demonstrates that pyroxene andesite starts to dehydrate. By the virtue of the activation enthalpy (0.35-0.42 eV) and the activation volume (-6.75 ± 1.67 cm3/mole) which characterizes the electrical properties of sample after dehydration, we consider that the conduction mechanism is the small polaron conduction before and after dehydration, and that the rise of carrier concentration is the most important reason of increased electrical conductivity.

  2. An overview of high thermal conductive hot press forming die material development

    Directory of Open Access Journals (Sweden)

    A.R. Zulhishamuddin

    2015-12-01

    Full Text Available Most of the automotive industries are using high strength steel components, which are produced via hot press forming process. This process requires die material with high thermal conductivity that increases cooling rate during simultaneous quenching and forming stage. Due to the benefit of high quenching rate, thermal conductive die materials were produced by adding carbide former elements. This paper presents an overview of the modification of alloying elements in tool steel for high thermal conductivity properties by transition metal elements addition. Different types of manufacturing processes involved in producing high thermal conductive materials were discussed. Methods reported were powder metallurgy hot press, direct metal deposition, selective laser melting, direct metal laser sintering and spray forming. Elements likes manganese, nickel, molybdenum, tungsten and chromium were proven to increase thermal conductivity properties. Thermal conductivity properties resulted from carbide network presence in the steel microstructure. To develop feasible and low cost hot press forming die material, casting of Fe-based alloy with carbide former composition can be an option. Current thermal conductivity properties of hot press forming die material range between 25 and 66 W/m.K. The wide range of thermal conductivity varies the mechanical properties of the resulting components and lifetime of HPF dies.

  3. Highly electrically conductive nanocomposites based on polymer-infused graphene sponges.

    Science.gov (United States)

    Li, Yuanqing; Samad, Yarjan Abdul; Polychronopoulou, Kyriaki; Alhassan, Saeed M; Liao, Kin

    2014-04-11

    Conductive polymer composites require a three-dimensional 3D network to impart electrical conductivity. A general method that is applicable to most polymers for achieving a desirable graphene 3D network is still a challenge. We have developed a facile technique to fabricate highly electrical conductive composite using vacuum-assisted infusion of epoxy into graphene sponge GS scaffold. Macroscopic GSs were synthesized from graphene oxide solution by a hydrothermal method combined with freeze drying. The GS/epoxy composites prepared display consistent isotropic electrical conductivity around 1 S/m, and it is found to be close to that of the pristine GS. Compared with neat epoxy, GS/epoxy has a 12-orders-of-magnitude increase in electrical conductivity, attributed to the compactly interconnected graphene network constructed in the polymer matrix. This method can be extended to other materials to fabricate highly conductive composites for practical applications such as electronic devices, sensors, actuators, and electromagnetic shielding.

  4. Bilateral Mandibular Condylar Fractures with Associated External Auditory Canal Fractures and Otorrhagia

    OpenAIRE

    Dang, David

    2016-01-01

    A rare case of bilateral mandibular condylar fractures associated with bilateral external auditory canal fractures and otorrhagia is reported. The more severe external auditory canal fracture was present on the side of high condylar fracture, and the less severe external auditory canal fracture was ipsilateral to the condylar neck fracture. A mechanism of injury is proposed to account for such findings.

  5. Bilateral Mandibular Condylar Fractures with Associated External Auditory Canal Fractures and Otorrhagia.

    Science.gov (United States)

    Dang, David

    2007-01-01

    A rare case of bilateral mandibular condylar fractures associated with bilateral external auditory canal fractures and otorrhagia is reported. The more severe external auditory canal fracture was present on the side of high condylar fracture, and the less severe external auditory canal fracture was ipsilateral to the condylar neck fracture. A mechanism of injury is proposed to account for such findings.

  6. Stability of Conductive Carbon Additives for High-voltage Li-ion Battery Cathodes

    OpenAIRE

    Nilssen, Benedicte Eikeland

    2014-01-01

    Conductive carbon additives are important constituents of the current state-of-the-art Li-ion battery cathodes, as the traditional active cathode materials are characterized by too low electronic conductivities. In high-voltage Li-ion batteries, these additives are subject for anion intercalation and electrolyte oxidation, which might cause changes in the conductive carbon network in the cathode, and hence the overall cycling performance of the electrode. This thesis has focused on study the ...

  7. A Novel Method for Measuring Electrical Conductivity of High Insulating Oil Using Charge Decay

    Science.gov (United States)

    Wang, Z. Q.; Qi, P.; Wang, D. S.; Wang, Y. D.; Zhou, W.

    2016-05-01

    For the high insulating oil, it is difficult to measure the conductivity precisely using voltammetry method. A high-precision measurementis proposed for measuring bulk electrical conductivity of high insulating oils (about 10-9--10-15S/m) using charge decay. The oil is insulated and charged firstly, and then grounded fully. During the experimental procedure, charge decay is observed to show an exponential law according to "Ohm" theory. The data of time dependence of charge density is automatically recorded using an ADAS and a computer. Relaxation time constant is fitted from the data using Gnuplot software. The electrical conductivity is calculated using relaxation time constant and dielectric permittivity. Charge density is substituted by electric potential, considering charge density is difficult to measure. The conductivity of five kinds of oils is measured. Using this method, the conductivity of diesel oil is easily measured to beas low as 0.961 pS/m, as shown in Fig. 5.

  8. Layered conductive polymer on nylon membrane templates for high performance, thin-film supercapacitor electrodes

    Science.gov (United States)

    Shi, HaoTian Harvey; Naguib, Hani E.

    2016-04-01

    Flexible Thin-film Electrochemical Capacitors (ECs) are emerging technology that plays an important role as energy supply for various electronics system for both present era and the future. Intrinsically conductive polymers (ICPs) are promising pseudo-capacitive materials as they feature both good electrical conductivity and high specific capacitance. This study focuses on the construction and characterization of ultra-high surface area porous electrodes based on coating of nano-sized conductive polymer materials on nylon membrane templates. Herein, a novel nano-engineered electrode material based on nylon membranes was presented, which allows the creation of super-capacitor devices that is capable of delivering competitive performance, while maintaining desirable mechanical characteristics. With the formation of a highly conductive network with the polyaniline nano-layer, the electrical conductivity was also increased dramatically to facilitate the charge transfer process. Cyclic voltammetry and specific capacitance results showed promising application of this type of composite materials for future smart textile applications.

  9. Mechanoassisted Synthesis of Sulfonated Covalent Organic Frameworks with High Intrinsic Proton Conductivity.

    Science.gov (United States)

    Peng, Yongwu; Xu, Guodong; Hu, Zhigang; Cheng, Youdong; Chi, Chenglong; Yuan, Daqiang; Cheng, Hansong; Zhao, Dan

    2016-07-20

    It is challenging to introduce pendent sulfonic acid groups into modularly built crystalline porous frameworks for intrinsic proton conduction. Herein, we report the mechanoassisted synthesis of two sulfonated covalent organic frameworks (COFs) possessing one-dimensional nanoporous channels decorated with pendent sulfonic acid groups. These COFs exhibit high intrinsic proton conductivity as high as 3.96 × 10(-2) S cm(-1) with long-term stability at ambient temperature and 97% relative humidity (RH). In addition, they were blended with nonconductive polyvinylidene fluoride (PVDF) affording a series of mixed-matrix membranes (MMMs) with proton conductivity up to 1.58 × 10(-2) S cm(-1) and low activation energy of 0.21 eV suggesting the Grotthuss mechanism for proton conduction. Our study has demonstrated the high intrinsic proton conductivity of COFs shedding lights on their wide applications in proton exchange membranes.

  10. Manufacture of iron-based, amorphous coatings with high fracture toughness

    Science.gov (United States)

    Bobzin, K.; Öte, M.; Königstein, T.

    2017-03-01

    Amorphous iron-based material have excellent corrosion behaviour, show good tribological performances and exhibit interesting thermophysical properties. The deposition as a coating system by thermal spraying technology is an innovative approach to manufacture these materials. In this study, the mechanical properties of three iron-based amorphous coatings with different chromium content xCr = 0, 5 and 15 at.% are presented deposited by means of High Velocity Oxygen Fuel Spraying. For the determination of the amorphous content the linear relationship between crystallization energy and amount of amorphous structures is used. Comparing the crystallization energies of amorphous ribbons manufactured by melt spinning to those of feedstock materials and free standing coatings, assumptions regarding the amorphous contents are drawn. The results show that the amorphous content in the feedstock material is influenced by the amount of chromium content. Furthermore, the amorphous content of all coatings do not exceed those of the feedstock materials. Powder xCr = 15 at.% and the corresponding coating exhibit smallest amount of amorphous structure, presumably due to a not fully melted state of the impacting particles. The values of fracture toughness of the coatings are determined by means of indentation and subsequent measurement of the crack lengths. Furthermore, values of indentation modulus and hardness are measured and compared to each other. While length of indentation cracks decreases with increasing chromium content, an increase in indention modulus and hardness is observed. In comparison to ceramic reference YSZ and the steel reference 1.4404, all amorphous coatings show promising properties such as low indentation crack lengths and high hardness.

  11. The effects of particle size and content on the thermal conductivity and mechanical properties of Al2O3/high density polyethylene (HDPE composites

    Directory of Open Access Journals (Sweden)

    2011-07-01

    Full Text Available The influences of filler size and content on the properties (thermal conductivity, impact strength and tensile strength of Al2O3/high density polyethylene (HDPE composites are studied. Thermal conductivity and tensile strength of the composites increase with the decrease of particle size. The dependence of impact strength on the particle size is more complicated. The SEM micrographs of the fracture surface show that Al2O3 with small particle size is generally more efficient for the enhancement of the impact strength, while the 100 nm particles prone to aggregation due to their high surface energy deteriorate the impact strength. Composite filled with Al2O3 of 0.5 µm at content of 25 vol% show the best synthetic properties. It is suggested that the addition of nano-Al2O3 to HDPE would lead to good performance once suitably dispersed.

  12. Electrical conductivity of molten SnCl{sub 2} at temperature as high as 1314 K

    Energy Technology Data Exchange (ETDEWEB)

    Salyulev, Alexander B.; Potapov, Alexei M. [Ural Branch of RAS, Ekaterinburg (Russian Federation). Inst. of High-Temperature Electrochemistry

    2015-07-01

    The electrical conductivity of molten SnCl{sub 2} was measured in a wide temperature range (ΔT=763 K), from 551 K to temperature as high as 1314 K, that is, 391 above the boiling point of the salt. The specific electrical conductance was found to reach its maximum at 1143 K, after that it decreases with the temperature rising.

  13. A Simplified Method for Upscaling Composite Materials with High Contrast of the Conductivity

    KAUST Repository

    Ewing, R.

    2009-01-01

    A large class of industrial composite materials, such as metal foams, fibrous glass materials, mineral wools, and the like, are widely used in insulation and advanced heat exchangers. These materials are characterized by a substantial difference between the thermal properties of the highly conductive materials (glass or metal) and the insulator (air) as well as low volume fractions and complex network-like structures of the highly conductive components. In this paper we address the important issue for the engineering practice of developing fast, reliable, and accurate methods for computing the macroscopic (upscaled) thermal conductivities of such materials. We assume that the materials have constant macroscopic thermal conductivity tensors, which can be obtained by upscaling techniques based on the postprocessing of a number of linearly independent solutions of the steady-state heat equation on representative elementary volumes (REVs). We propose, theoretically justify, and computationally study a numerical method for computing the effective conductivities of materials for which the ratio δ of low and high conductivities satisfies δ ≪ 1. We show that in this case one needs to solve the heat equation in the region occupied by the highly conductive media only. Further, we prove that under certain conditions on the microscale geometry the proposed method gives an approximation that is O(δ)-close to the upscaled conductivity. Finally, we illustrate the accuracy and the limitations of the method on a number of numerical examples. © 2009 Society for Industrial and Applied Mathematics.

  14. Highly conductive and stretchable polymer composites based on graphene/MWCNT network.

    Science.gov (United States)

    Chen, Mengting; Tao, Tao; Zhang, Ling; Gao, Wei; Li, Chunzhong

    2013-02-25

    We have manufactured a highly conductive and stretchable composite by backfilling a preformed graphene/MWCNT aerogel with poly(dimethylsiloxane) (PDMS). The electrical conductivity of our product can reach 2.8 S cm(-1) with only 1.3 wt% graphene/MWCNT loading, and remains constant after 100 times repeated stretching by 20% and 5000 times bending.

  15. A promising structure for fabricating high strength and high electrical conductivity copper alloys.

    Science.gov (United States)

    Li, Rengeng; Kang, Huijun; Chen, Zongning; Fan, Guohua; Zou, Cunlei; Wang, Wei; Zhang, Shaojian; Lu, Yiping; Jie, Jinchuan; Cao, Zhiqiang; Li, Tingju; Wang, Tongmin

    2016-02-09

    To address the trade-off between strength and electrical conductivity, we propose a strategy: introducing precipitated particles into a structure composed of deformation twins. A Cu-0.3%Zr alloy was designed to verify our strategy. Zirconium was dissolved into a copper matrix by solution treatment prior to cryorolling and precipitated in the form of Cu5Zr from copper matrix via a subsequent aging treatment. The microstructure evolutions of the processed samples were investigated by transmission electron microscopy and X-ray diffraction analysis, and the mechanical and physical behaviours were evaluated through tensile and electrical conductivity tests. The results demonstrated that superior tensile strength (602.04 MPa) and electrical conductivity (81.4% IACS) was achieved. This strategy provides a new route for balancing the strength and electrical conductivity of copper alloys, which can be developed for large-scale industrial application.

  16. Effects of a high magnetic field on fracture toughness at 4. 2 K for austenitic stainless steels

    Energy Technology Data Exchange (ETDEWEB)

    Murase, S.; Kobatake, S.; Tanaka, M.; Tashiro, I.; Horigami, O.; Ogiwara, H. (Toshiba R and D Center, Kawasaki (Japan)); Shibata, K. (Univ. Tokyo, Bunkyo (Japan)); Nagai, K.; Ishikawa, K. (National Research Inst. for Metals, Sengen, Tsukuba (Japan))

    1993-01-01

    Structural stainless steels for cryogenic use in superconducting magnets for fusion reactors are used under high magnetic field and stress. The authors have performed fracture thoughness tests, using the unloading compliance method at 4.2 K on SUS304, 316LN and 304L stainless steels precracked at 77 K, in a varying magnetic field (0 and 8 T). Fracture toughness values (J[sub IC]) for 304 and 316LN steels at 8 T decreased by 17 and 20%, respectively, as compared with the 0 T condition. On the other hand, J[sub IC] for 304L steel was 30% increased by applying a high magnetic field of 8 T. Details of martensite formation and austenite stability are considered in discussion. (orig.).

  17. HIGH-TEMPERATURE TENSILE FRACTURE BEHAVIOR OF DIRECTIONALLY SOLIDIFIED Ni,Cr,Al-TaC EUTECTIC SUPERALLOY

    Institute of Scientific and Technical Information of China (English)

    J.Zhang; J.J.Yu; H.Z.Fu

    2004-01-01

    The high-temperature tensile fracture behavior of the Ni, Cr, Al-TaC eutectic superalloy directionally solidified under high temperature gradient is investigated. The hightemperature tensile fracture of this in situ composite has ductile character with lots of ductile nests whose diameters decrease with the increasing solidification rates. The maximum σb and δ are respectively 668.5MPa and 19.6%. There is a TaC whisker in the center of each nest, and the deformation of γ' and TaC is uneven. The hightemperature tensile behavior cannot be explained by the rule of mixtures but is decided by the formation of the plastic deforrmation band. The crack extension model is given.

  18. Measurements of Hydrogen Thermal Conductivity at High Pressure and High Temperature

    Science.gov (United States)

    Moroe, S.; Woodfield, P. L.; Kimura, K.; Kohno, M.; Fukai, J.; Fujii, M.; Shinzato, K.; Takata, Y.

    2011-09-01

    The thermal conductivity for normal hydrogen gas was measured in the range of temperatures from 323 K to 773 K at pressures up to 99 MPa using the transient short hot-wire method. The single-wire platinum probes had wire lengths of 10 mm to 15 mm with a nominal diameter of 10 μm. The volume-averaged transient temperature rise of the wire was calculated using a two-dimensional numerical solution to the unsteady heat conduction equation. A non-linear least-squares fitting procedure was employed to obtain the values of the thermal conductivity required for agreement between the measured temperature rise and the calculation. The experimental uncertainty in the thermal-conductivity measurements was estimated to be 2.2 % ( k = 2). An existing thermal-conductivity equation of state was modified to include the expanded range of conditions covered in the present study. The new correlation is applicable from 78 K to 773 K with pressures to 100 MPa and is in agreement with the majority of the present thermal-conductivity measurements within ±2 %.

  19. Research and practice of the impulse sand fracturing technology

    Directory of Open Access Journals (Sweden)

    Bin Qian

    2015-10-01

    Full Text Available With the deep development of tight sand gas reservoirs, problems such as short stable production period and quick production decline of gas wells after fracturing have become increasingly prominent. Consequently, there is an increasing demand for the effective penetration and conductivity of artificial fractures. Impulse sand fracturing technology introduces a concept of discrete multilayer sanding inside fractures; joint application of pulse blender which can be switched at high frequency, intensive multi-cluster perforation and special fibrous material made it possible to ensure the flow stability of proppant slug, and placement of nonuniformly-laid sand pinnacles and grooves, which markedly upgraded the capacity of the fracture conductivity to several orders of magnitude more than the conventional method. Laboratory engineering simulation evaluation and field test show that pre-fracturing reservoir evaluation, pulse time design and the optimization of degradable fiber and support equipment are the keys to the success of impulse sand fracturing. Compared with the conventional fracturing, this technique can effectively increase well production, decrease the volume of fracturing proppant, and lower sand plugging risks. An independent sand fracturing pilot test has been conducted in 6 layers of 3 wells for the first time in Block Tao 7 of the Sulige Gasfield, Ordos Basin, as a result, the average volume of fracturing proppant dropped by 28.3%, the average sand intensity dropped by 21.88%, and the post-fracturing average daily gas output increased by 26.8%. This technology provides an efficient and environmentally friendly reservoir stimulation option for tight sand gas reservoirs in China.

  20. Hip Fracture

    Science.gov (United States)

    Diseases and Conditions Hip fracture By Mayo Clinic Staff A hip fracture is a serious injury, with complications that can be life-threatening. The risk of hip fracture rises with age. Older people are at a ...

  1. CTE-Matched, Liquid-Cooled, High Thermal Conductivity Heat Sink Project

    Data.gov (United States)

    National Aeronautics and Space Administration — We propose the development of a CTE-matched, liquid-cooled, high thermal conductivity heat sink for use in spacecraft thermal management applications. The material...

  2. Assesment risk of fracture in thin-walled fiber reinforced and regular High Performance Concretes sandwich elements

    DEFF Research Database (Denmark)

    Hodicky, Kamil; Hulin, Thomas; Schmidt, Jacob Wittrup

    2013-01-01

    High Performance Concrete Sandwich Elements (HPCSE) are an interesting option for future low or plus energy building construction. Recent research and development work, however, indicate that such elements are prone to structural cracking due to the combined effect of shrinkage and high temperature...... load. Due to structural restraints, autogenous shrinkage may lead to high self-induced stresses. Therefore autogenous shrinkage plays important role in design of HPCSE. The present paper assesses risk of fracture due to autogenous shrinkage-induced stresses in three fiber reinforced and regular High...

  3. OPTIMAL SURGICAL MANAGEMENT OF HIGH VELOCITY POSTERIOR TIBIAL PLATEAU FRACTURE SUBLUXATIONS (DUPARC, REVISED CLASSIFICATION, GROUP – V: POSTERO - MEDIAL FRACTURE BY DIRECT, DORSAL APPROACH – A CHANGING TREND: A PROSPECTIVE STUDY

    Directory of Open Access Journals (Sweden)

    Pardhasaradhi

    2015-10-01

    Full Text Available INTRODUCTION : High - energy tibial plateau fractures are infrequent and technically demanding to treat especially if those are shearing type, coronal plane, displaced fractures. The most widely used the Schatzker system of classification , [1] ( B ased on the AP radiograph is more than likely to miss postero - medial and postero - lateral shear fractures, best visible on the lateral, than the AP radiograph. These fractures have recently been characterised by two studies, highlighti ng their clinical relevance [ 2,3] and showing that less invasive surgery and indirect reduction techniques are often inadequate. Hohl described unicondylar c oronal plane splitting fractures of the medial tibial plateau, noted that these injuries be considered as fracture - dislocations. Connolly and others have suggested that the mechanism involved in this fracture pattern is one of knee flexion, varus, and inter nal rotation of the medial femoral condyle . [4,5,6 ] Consistent among these and other authors is that the occurrence of this fragment is relatively unusual and that the use of a posteriorly based exposure with direct fracture visualization, anatomic reductio n and absolute stability appears to result in satisfactory outcomes. Though variations of a postero - medial approach been previously described ( by Trickey et al and also by Burks et al.,, more recently, Lobenhoffer et al described direct posterior exposure , Wang et al described postero - medial approach and Luo et al. described the approach for the management of posterior bicondylar tibial plateau fractures . [7,8] These approaches have been used in isolation or as a dual - incision approach for treating tibial plateau fractures . [9,10,11,12,13,14, 15] PURPOSE : The purpose of this study is to describe this unfamiliar direct posterior surgical (Medial Gastrocnemius approach to a general orthopod, highlighting the relevant anatomy and presenting our experience using this approach in treating a

  4. Treating osteoporotic vertebral compression fractures with intraosseous vacuum phenomena using high-viscosity bone cement via bilateral percutaneous vertebroplasty.

    Science.gov (United States)

    Guo, Dan; Cai, Jun; Zhang, Shengfei; Zhang, Liang; Feng, Xinmin

    2017-04-01

    Osteoporotic vertebral compression fractures with intraosseous vacuum phenomena could cause persistent back pains in patients, even after receiving conservative treatment. The aim of this study was to evaluate the efficacy of using high-viscosity bone cement via bilateral percutaneous vertebroplasty in treating patients who have osteoporotic vertebral compression fractures with intraosseous vacuum phenomena.Twenty osteoporotic vertebral compression fracture patients with intraosseous vacuum phenomena, who received at least 2 months of conservative treatment, were further treated by injecting high-viscosity bone cement via bilateral percutaneous vertebroplasty due to failure of conservative treatment. Treatment efficacy was evaluated by determining the anterior vertebral compression rates, visual analog scale (VAS) scores, and Oswestry disability index (ODI) scores at 1 day before the operation, on the first day of postoperation, at 1-month postoperation, and at 1-year postoperation.Three of 20 patients had asymptomatic bone cement leakage when treated via percutaneous vertebroplasty; however, no serious complications related to these treatments were observed during the 1-year follow-up period. A statistically significant improvement on the anterior vertebral compression rates, VAS scores, and ODI scores were achieved after percutaneous vertebroplasty. However, differences in the anterior vertebral compression rate, VAS score, and ODI score in the different time points during the 1-year follow-up period was not statistically significant (P > 0.05).Within the limitations of this study, the injection of high-viscosity bone cement via bilateral percutaneous vertebroplasty for patients who have osteoporotic vertebral compression fractures with intraosseous vacuum phenomena significantly relieved their back pains and improved their daily life activities shortly after the operation, thereby improving their life quality. In this study, the use of high-viscosity bone

  5. Incidence and Predictors of Multiple Fractures Despite High Adherence to Oral Bisphosphonates: A Binational Population-Based Cohort Study.

    Science.gov (United States)

    Hawley, Samuel; Javaid, M Kassim; Rubin, Katrine H; Judge, Andrew; Arden, Nigel K; Vestergaard, Peter; Eastell, Richard; Diez-Perez, Adolfo; Cooper, Cyrus; Abrahamsen, Bo; Prieto-Alhambra, Daniel

    2016-01-01

    Oral bisphosphonates (BPs) are highly effective in preventing fractures and are recommended first-line therapies for patients with osteoporosis. We identified the incidence and predictors of oral BP treatment failure, defined as the incidence of two or more fractures while on treatment (≥2 FWOT) among users with high adherence. Fractures were considered from 6 months after treatment initiation and up to 6 months after discontinuation. Data from computerized records and pharmacy invoices were obtained from Sistema d'Informació per al Desenvolupament de l'Investigació en Atenció Primària (SIDIAP; Catalonia, Spain) and Danish Health Registries (Denmark) for all incident users of oral BPs in 2006-2007 and 2000-2001, respectively. Fine and Gray survival models using backward-stepwise selection (p-entry 0.049; p- exit 0.10) and accounting for the competing risk of therapy cessation were used to identify predictors of ≥2 FWOT among patients having persisted with treatment ≥6 months with overall medication possession ratio (MPR) ≥80%. Incidence of ≥2 FWOT was 2.4 (95% confidence interval [CI], 1.8 to 3.2) and 1.7 (95% CI, 1.2 to 2.2) per 1000 patient-years (PYs) within Catalonia and Denmark, respectively. Older age was predictive of ≥2 FWOT in both Catalonian and Danish cohorts: subhazard ratio (SHR) = 2.28 (95% CI, 1.11 to 4.68) and SHR = 2.61 (95% CI, 0.98 to 6.95), respectively, for 65 to history of recent or older fracture, SHR = 3.40 (95% CI, 1.50 to 7.68) and SHR = 2.08 (95% CI: 1.04-4.15), respectively (Denmark). Even among highly adherent users of oral BP therapy, a minority sustain multiple fractures while on treatment. Older age was predictive of increased risk within both study populations, as was history of recent/old fracture and dementia within one but not both populations. Additional and/or alternative strategies should be investigated for these patients. © 2015 American Society for Bone and Mineral Research.

  6. Fatigue fracture of cutter blade made of high-speed steel

    Directory of Open Access Journals (Sweden)

    Beata Letkowska

    2015-04-01

    Full Text Available The quality of the surface of cyclically loaded components is very important. Many observations confirm that the root cause of the micro cracks (causing the fatigue fracture are primarily a surface's defects appearing during production process. These surface defects can be also caused by engraving processes used to perform identification marks. This paper presents the failure analysis of broken blade of the cutter Ku 500VX. The blade was subject of standard metallographic examination, hardness measurements, fractography analysis and metallographic studies using stereoscopic, light and scanning electron microscopes. The damage of the blade was caused by changes of the structure (formation of the brittle micro dendritic structure that occurred during manual electric engraving process when the material was heated till its melting point. As a result the stresses occurred in surface what provided to micro cracking and to propagate the fatigue fracture. The origin of this fatigue fracture was in the place where the inscription was made.

  7. Water-free Alkaline Polymer-inorganic Acid Complexes with High Conductivity at Ambient Temperature

    Institute of Scientific and Technical Information of China (English)

    O.V.Chervakov; M.V.Andriianova; V.V.Riabenko; A.V.Markevich; E.M.Shembel; D.Meshri

    2007-01-01

    1 Results Recently increased interest is shown to proton conducting materials based on the alkaline polymer-inorganic acid complexes that is caused by a possibility of their application as the high-temperature electrolyte systems for various electrochemical devices (fuel cells,sensors,lithium power sources etc.).Complexes of inorganic acids with the alkaline polymers (polybenzimidazoles[1],polyvinylpyridines[2]) are characterized by high ionic conductivity at ambient temperatures (up to 10-2 Ω-1·cm-1) a...

  8. Enhanced charge transport in highly conducting PEDOT-PSS films after acid treatment

    Science.gov (United States)

    Shiva, V. Akshaya; Bhatia, Ravi; Menon, Reghu

    The high electrical conductivity, good stability, high strength, flexibility and good transparency of poly(3,4-ethylenedioxythiophene)-poly(styrenesulfonate) (PEDOT-PSS), make it useful for many applications including polymeric anodes for organic photovoltaics, light-emitting diodes, flexible electrodes, supercapacitors, electrochromic devices, field-effect transistors and antistatic-coatings. However, the electrical conductivity of PEDOT-PSS has to be increased significantly for replacement of indium tin oxide (ITO) as the transparent electrode in optoelectronic devices. The as prepared (pristine) PEDOT-PSS film prepared from the PEDOT-PSS aqueous solution usually has conductivity below 1Scm-1, remarkably lower than ITO. Significant conductivity enhancement has been observed on transparent and conductive PEDOT-PSS films after a treatment with inorganic acids. Our study investigates the charge transport in pristine and H2SO4, HNO3, HCl treated PEDOT-PSS films. We have treated the films with various concentrations of acids to probe the effect of the acid treatment on the conduction mechanism. The study includes the measurement of dc and electric field dependent conductivity of films in the temperature range of 4.2K-300K. We have also performed magneto-resistance measurements in the range of 0-5T. An enhancement by a factor of~103 has been observed in the room temperature conductivity. The detailed magneto-transport studies explain the various mechanisms for the conductivity enhancement observed.

  9. A laboratory acoustic emission experiment and numerical simulation of rock fracture driven by a high-pressure fluid source

    Directory of Open Access Journals (Sweden)

    Xinglin Lei

    2016-02-01

    Full Text Available In order to improve our understanding of rock fracture and fault instability driven by high-pressure fluid sources, the authors carried out rock fracture tests using granite under a confining pressure of 80 MPa with fluid injection in the laboratory. Furthermore, we tested a number of numerical models using the FLAC3D modeling software to find the best model to represent the experimental results. The high-speed multichannel acoustic emission (AE waveform recording system used in this study made it possible to examine the total fracture process through detailed monitoring of AE hypocenters and seismic velocity. The experimental results show that injecting high-pressure oil into the rock sample can induce AE activity at very low stress levels and can dramatically reduce the strength of the rock. The results of the numerical simulations show that major experimental results, including the strength, the temporal and spatial patterns of the AE events, and the role of the fluid can be represented fairly well by a model involving (1 randomly distributed defect elements to model pre-existing cracks, (2 random modification of rock properties to represent inhomogeneity introduced by different mineral grains, and (3 macroscopic inhomogeneity. Our study, which incorporates laboratory experiments and numerical simulations, indicates that such an approach is helpful in finding a better model not only for simulating experimental results but also for upscaling purposes.

  10. NanoCapillary Network Proton Conducting Membranes for High Temperature Hydrogen/Air Fuel Cells

    Energy Technology Data Exchange (ETDEWEB)

    Pintauro, Peter [Vanderbilt Univ., Nashville, TN (United States)

    2012-07-09

    The objective of this proposal is to fabricate and characterize a new class of NanoCapillary Network (NCN) proton conducting membranes for hydrogen/air fuel cells that operate under high temperature, low humidity conditions. The membranes will be intelligently designed, where a high density interconnecting 3-D network of nm-diameter electrospun proton conducting polymer fibers is embedded in an inert (uncharged) water/gas impermeable polymer matrix. The high density of fibers in the resulting mat and the high ion-exchange capacity of the fiber polymer will ensure high proton conductivity. To further enhance water retention, molecular silica will be added to the sulfonated polymer fibers. The uncharged matrix material will control water swelling of the high ion-exchange capacity proton conducting polymer fibers and will impart toughness to the final nanocapillary composite membrane. Thus, unlike other fuel cell membranes, the role of the polymer support matrix will be decoupled from that of the proton-conducting channels. The expected final outcome of this 5-year project is the fabrication of fuel cell membranes with properties that exceed the DOE’s technical targets, in particular a proton conductivity of 0.1 S/cm at a temperature less than or equal to120°C and 25-50% relative humidity.

  11. High incidence of osteoporosis and fractures in an aging post-polio population.

    LENUS (Irish Health Repository)

    Mohammad, Ausaf F

    2009-01-01

    Since the polio epidemic in Ireland in the 1950s, most polio survivors are approaching into the 6th and 7th decade of their lives. There is little data about bone density and risk of fractures in these patients. In 2006, we undertook an audit of post-polio patients attending rheumatology and neurology outpatient clinics in a university teaching hospital. Our aim was to determine the prevalence of osteoporosis (OP), falls and fractures and to evaluate the association of bone density with other potential contributing factors to OP.

  12. High-energy bilateral talar neck fractures secondary to motocross injury.

    Science.gov (United States)

    White, S L; Harpaz, N T; Jolly, G P; Gorecki, G A

    1999-01-01

    The authors present a case of bilateral Hawkins type II talar neck fractures sustained during a motocross race in a 23 year old man. Due to the complexity of the injuries, open reduction with internal fixation and primary subtalar joint arthrodesis was performed bilaterally. This is one of the few cases of bilateral talar neck fractures reported in the literature in the past 15 years and one of the first utilizing open reduction and internal fixation with concomitant subtalar joint arthrodesis as a primary treatment.

  13. Conductivity of I2-Doped High trans-1,4-Polybutadiene

    Institute of Scientific and Technical Information of China (English)

    史辰君; 薛怀国; 沈之荃; 张一烽; 李永舫; 杨春和

    2001-01-01

    High trans-1,4-polybutadiene ( ~ 96% (trans)) was prepared by lanthanum naphthenate catalytic systern. The conductivity of obtained polybutadiene doped with iodine reaches about ~10-3 s/cm, which is 2 orders of magnitude higher than the value reported.4,5 During the I2-doping, the conjugated sequence was formed through double bond shifting reaction. According to the relationship between conductivity and temperature, conducting mechanism of doped high trans-1,4-polybutadiene is fit on variable range hoping (VRH) model.

  14. Nanostructured Cu-Cr alloy with high strength and electrical conductivity

    Energy Technology Data Exchange (ETDEWEB)

    Islamgaliev, R. K., E-mail: saturn@mail.rb.ru; Nesterov, K. M. [Institute of Physics of Advanced Materials, Ufa State Aviation Technical University, Ufa 450000 (Russian Federation); Bourgon, J.; Champion, Y. [ICMPE-CNRS, Université Paris 12, 6-8 rue Henri Dunant, 94320 Thiais, cedex (France); Valiev, R. Z. [Institute of Physics of Advanced Materials, Ufa State Aviation Technical University, Ufa 450000 (Russian Federation); Laboratory for Mechanics of Bulk Nanostructured Materials, Saint Petersburg State University, 198504 Peterhof, Saint Petersburg (Russian Federation)

    2014-05-21

    The influence of nanostructuring by high pressure torsion (HPT) on strength and electrical conductivity in the Cu-Cr alloy has been investigated. Microstructure of HPT samples was studied by transmission electron microscopy with special attention on precipitation of small chromium particles after various treatments. Effect of dynamic precipitation leading to enhancement of strength and electrical conductivity was observed. It is shown that nanostructuring leads to combination of high ultimate tensile strength of 790–840 MPa, enhanced electrical conductivity of 81%–85% IACS and thermal stability up to 500 °C. The contributions of grain refinement and precipitation to enhanced properties of nanostructured alloy are discussed.

  15. Oblique Axis Body Fracture

    DEFF Research Database (Denmark)

    Takai, Hirokazu; Konstantinidis, Lukas; Schmal, Hagen;

    2016-01-01

    was uneventful. Conclusions. Oblique type axis body fractures resemble a highly unstable subtype of Anderson type III fractures with the potential of severe secondary deformity following conservative treatment, irrespective of initial grade of displacement. The authors therefore warrant a high index of suspicion......Purpose. Anderson type III odontoid fractures have traditionally been considered stable and treated conservatively. However, unstable cases with unfavorable results following conservative treatment have been reported. Methods. We present the cases of two patients who sustained minimally displaced...

  16. Case History: Merging the Tools of DC Resistivity and Fracture Trace Analysis for Locating High Yield Domestic Water Wells in Karst Terrain, Shenandoah Valley, Virginia, USA

    Science.gov (United States)

    Frangos, W.; Eaton, L. S.

    2004-05-01

    The karstic eastern margin of Virginia's Shenandoah Valley hosts large volumes of high quality ground water in discrete zones or pockets. Industrial and culinary exploitation poses a challenging exploration problem. Recent work by the authors using geophysical and aerial photogrammetric techniques resulted in the successful location of three high- yield water wells. This indirect methodology increases the probability of locating valuable wells by locating geologic features that may harbor water-bearing zones. The eastern Shenandoah Valley is geologically complex. The underlying bedrock is dominantly limestones, dolomites, and shales of Cambrian age that have been extensively folded, fractured, and faulted. Geomorphologic features such as solution cavities, caves, disappearing streams, and sinkholes are common. Extensive alluvial fan and river terrace deposits, comprised dominantly of quartzite gravel and sand, cover much of the land surface, and fill surface depressions. The combination of sand and gravel filtering and large storage capacity in the voids makes this region ideal for producing a large quantity of high quality groundwater. Two sites were investigated for karst aquifers near the town of Stuarts Draft. Interbedded limestones and dolomites underlie Barth Farm, situated on the north bank of the South River. The owners attempted to installed a water well to service an active vineyard. The drilling located a previously unknown, water-filled cavern ~5 m below the surface; subsequent high pumping rates in finishing the well resulted in a surface collapse and the creation of a sinkhole. A second effort, offset by ~30 meters, resulted in a catastrophic collapse, and seriously endangered the lives of the drillers. A subsequent dipole-dipole DC resistivity survey delineated a conductive zone coincident with the two sinkholes. Fracture trace analysis of pre-drilling aerial photographs indicates the presence of lineaments that pass through this drilling site

  17. A new evaluation method for micro-fracture plugging in high-temperature deep wells and its application: A case study of the Xushen Gas Field, Songliao Basin

    Directory of Open Access Journals (Sweden)

    Yonggui Liu

    2016-03-01

    Full Text Available Micro-fractures are developed in volcanic layers of Cretaceous Yingcheng Fm in the deep part of Xujiaweizi fault depression, Songliao Basin. In the process of well drilling, various complex problems happen, such as borehole wall slabbing and collapse and serious fluid leakage. Based on conventional drilling fluid plugging evaluation methods, the real situations cannot be presented accurately, especially in fracture feature simulation and plugging effect evaluation. Therefore, a specific micro-fracture plugging evaluation method was put forward especially for high-temperature deep wells in the paper. It is a new type of micro-fracture core model with the fracture apertures in the range of 1–50 μm. It is made of aluminosilicate that is compositionally close to natural rocks. It is good in repeatability with fracture-surface roughness, pore development and fracture-surface morphology close to natural fractures. Obviously, this new model makes up for the deficiencies of the conventional methods. A new micro-fracture plugging evaluation instrument was independently designed with operating temperature of 200 °C and operating pressure of 3.5–5.0 MPa. It can be used to simulate the flow regime of downhole operating fluids, with the advantages of low drilling fluid consumption, convenient operation and low cost. The plugging capacity of the organo-silicone drilling fluid system was evaluated by using this instrument. It is shown that the grain size distribution of the drilling fluid is improved and its anti-collapse capacity is enhanced. Based on the field test in Well XSP-3, the safe drilling problems in volcanic layers with developed micro-fractures are effectively solved by using the drilling fluid formula which is optimized by means of this evaluation method. And the safe drilling is guaranteed in the deep fractured formations in this area.

  18. Deep Fracturing of the Hard Rock Surrounding a Large Underground Cavern Subjected to High Geostress: In Situ Observation and Mechanism Analysis

    Science.gov (United States)

    Feng, Xia-Ting; Pei, Shu-Feng; Jiang, Quan; Zhou, Yang-Yi; Li, Shao-Jun; Yao, Zhi-Bin

    2017-08-01

    Rocks that are far removed from caverns or tunnels peripheries and subjected to high geostress may undergo `deep fracturing'. Deep fracturing of hard rock can cause serious hazards that cause delays and increase the cost of construction of underground caverns with high sidewalls and large spans (especially when subjected to high geostress). To extensively investigate the mechanism responsible for deep fracturing, and the relationship between fracturing and the excavation & support of caverns, this paper presents a basic procedure for making in situ observations on the deep fracturing process in hard rock. The basic procedure involves predicting the stress concentration zones in the surrounding rocks of caverns induced by excavation using geomechanical techniques. Boreholes are then drilled through these stress concentration zones from pre-existing tunnels (such as auxiliary galleries) toward the caverns before its excavation. Continuous observations of the fracturing of the surrounding rocks are performed during excavation using a borehole camera in the boreholes in order to analyze the evolution of the fracturing process. The deep fracturing observed in a large underground cavern (high sidewalls and large span) in southwest China excavated in basalt under high geostress is also discussed. By continuously observing the hard rock surrounding the arch on the upstream side of the cavern during the excavation of the first three layers, it was observed that the fracturing developed into the surrounding rocks with downward excavation of the cavern. Fracturing was found at distances up to 8-9 m from the cavern periphery during the excavation of Layer III. Also, the cracks propagated along pre-existing joints or at the interfaces between quartz porphyry and the rock matrix. The relationship between deep fracturing of the surrounding rocks and the advance of the cavern working faces was analyzed during excavation of Layer Ib. The results indicate that the extent of the

  19. Experimental studies of electrical conductivities and P-wave velocities of gabbro at high pressures and high temperatures

    Institute of Scientific and Technical Information of China (English)

    白利平; 杜建国; 刘巍; 周文戈

    2003-01-01

    The P-wave velocities and electrical conductivities of gabbro were measured using ultrasonic transmission method and impedance spectroscopy from room temperature to 1100℃ at 1-2 GPa, and the factors controlling the P-wave velocity and the microscopic conductance mechanisms of the rock were analyzed. The experimental results show that the P-wave velocities of gabbro drop abruptly at temperatures of 800-850℃ and under pressures of 1-2 GPa due to the occurrence of grain boundary phases and dehydration melting; however, the electrical conductivities and electronic conduction mechanisms have not changed obviously at temperatures of 800-850℃. At temperatures Below 680℃, only one impedance arc (I) corresponding to grain interior conduction occurs at frequencies between 12 Hz and 105 Hz, the second arc (II) corresponding to grain boundary conduction occurs at temperatures above 680℃. The total conductivity of this rock is dominated by the grain interior conductivity as the occurrence of grain boundary conduction has a small effect on the total conductivity. The laboratory-measured velocities are consistent with the average P-wave velocity observations of lower crust and upper mantle. The conductivity values correspond well with the gabbroite composition of the lower crust and upper mantle; however, they are about 1-2 orders of magnitude lower than MT data from the high conductive layers. The experiments confirm that the dehydration of hydrous minerals can induce the partial melting, and the low seismic velocity zones might be correlated with the high conductive layers if partial melting occurs.

  20. Highly conductive graphene by low-temperature thermal reduction and in situ preparation of conductive polymer nanocomposites.

    Science.gov (United States)

    Yang, Liping; Kong, Junhua; Yee, Wu Aik; Liu, Wanshuang; Phua, Si Lei; Toh, Cher Ling; Huang, Shu; Lu, Xuehong

    2012-08-21

    Polydopamine-coated graphene oxide (DGO) films exhibit electrical conductivities of 11,000 S m(-1) and 30,000 S m(-1) upon vacuum annealing at 130 °C and 180 °C, respectively. Conductive poly(vinyl alcohol)/graphene and epoxy/graphene nanocomposites show low percolation thresholds due to the excellent dispersibility of the DGO sheets and their effective in situ reduction.

  1. Printable elastic conductors with a high conductivity for electronic textile applications

    Science.gov (United States)

    Matsuhisa, Naoji; Kaltenbrunner, Martin; Yokota, Tomoyuki; Jinno, Hiroaki; Kuribara, Kazunori; Sekitani, Tsuyoshi; Someya, Takao

    2015-06-01

    The development of advanced flexible large-area electronics such as flexible displays and sensors will thrive on engineered functional ink formulations for printed electronics where the spontaneous arrangement of molecules aids the printing processes. Here we report a printable elastic conductor with a high initial conductivity of 738 S cm-1 and a record high conductivity of 182 S cm-1 when stretched to 215% strain. The elastic conductor ink is comprised of Ag flakes, a fluorine rubber and a fluorine surfactant. The fluorine surfactant constitutes a key component which directs the formation of surface-localized conductive networks in the printed elastic conductor, leading to a high conductivity and stretchability. We demonstrate the feasibility of our inks by fabricating a stretchable organic transistor active matrix on a rubbery stretchability-gradient substrate with unimpaired functionality when stretched to 110%, and a wearable electromyogram sensor printed onto a textile garment.

  2. Extraordinarily High Conductivity of Stretchable Fibers of Polyurethane and Silver Nanoflowers.

    Science.gov (United States)

    Ma, Rujun; Kang, Byeongguk; Cho, Suik; Choi, Minjun; Baik, Seunghyun

    2015-11-24

    Stretchable conductive composites have received considerable attention recently, and they should have high conductivity and mechanical strength. Here we report highly conductive stretchable fibers synthesized by the scalable wet spinning process using flower-shaped silver nanoparticles with nanodisc-shaped petals (Ag nanoflowers) and polyurethane. An extraordinarily high conductivity (41,245 S cm(-1)) was obtained by Ag nanoflowers, which is 2 orders of magnitude greater than that of fibers synthesized using spherical Ag nanoparticles. This was due to the enhanced surface area and vigorous coalescence of nanodisc-shaped petals during the curing process. There was a trade-off relationship between conductivity and stretchability, and the maximum rupture strain was 776%. An analytical model revealed that the enhanced adhesion between Ag nanoflowers and polyurethane provided a high Young's modulus (731.5 MPa) and ultimate strength (39.6 MPa) of the fibers. The fibers exhibited an elastic property after prestretching, and the resistance change of weft-knitted fabric was negligible up to 200% strain. The fibers with extraordinarily high conductivity, stretchability, and mechanical strength may be useful for wearable electronics applications.

  3. Mechanisms and modeling of cleavage fracture in simulated heat-affected zone microstructures of a high-strength low alloy steel

    Science.gov (United States)

    Lambert-Perlade, A.; Sturel, T.; Gourgues, A. F.; Besson, J.; Pineau, A.

    2004-03-01

    The effect of the welding cycle on the fracture toughness properties of high-strength low alloy (HSLA) steels is examined by means of thermal simulation of heat-affected zone (HAZ) microstructures. Tensile tests on notched bars and fracture toughness tests at various temperatures are performed together with fracture surface observations and cross-sectional analyses. The influence of martensite-austenite (M-A) constituents and of “crystallographic” bainite packets on cleavage fracture micromechanisms is, thus, evidenced as a function of temperature. Three weakest-link probabilistic models (the “Master-curve” (MC) approach, the Beremin model, and a “double-barrier” (DB) model) are applied to account for the ductile-to-brittle transition (DBT) fracture toughness curve. Some analogy, but also differences, are found between the MC approach and the Beremin model. The DB model, having nonfitted, physically based scatter parameters, is applied to the martensite-containing HAZ microstructures and gives promising results.

  4. Effect of microstructure on the fracture response of advanced high strength steels

    Science.gov (United States)

    Taylor, Mark David

    steels showed that, whether by cold-rolling or tensile deformation, a DP microstructure heterogeneously accommodates strains imparted by plastic deformation. Strain maps generated using digital image correlation on deformed tensile specimens for both DP steels showed that strains heterogeneously develop in the microstructure at locations consistent with preferential fracture sites in DP steels, such as ferrite/martensite interfaces. The hardness ratio primarily affected the magnitude of the strain gradients, with a larger hardness ratio yielding a greater strain gradient. With further deformation, isolated regions of high strain linked to form bands of strain localization throughout the microstructure. A plane strain tensile analysis showed the DP steel with lower hardness ratio to have a lower void population, a finding consistent with results established in the M.Sc. thesis of M. D. Taylor. Using fractured tensile specimens, a lower void area pct at equivalent stress and strain was observed for the DP steel with lower hardness ratio, confirming a lower hardness ratio suppresses microstructural damage.

  5. Microstructural features in fractured high nitrogen stainless steel hip prostheses: a retrieval study of polished, tapered femoral stems.

    Science.gov (United States)

    Swarts, Eric; Kop, Alan; Jones, Noel; Keogh, Cathie; Miller, Susan; Yates, Piers

    2008-03-01

    Six fractured high nitrogen stainless steel (HNSS), polished, tapered hip stems have been reviewed for analysis. Clinical data suggests that poor proximal support (loosening), varus positioning, and canal morphology are implicated in the failure of these stems. Metallurgical assessment reveals a number of microstructural deficiencies contributing to failure. Of significance is poor grain homogeneity and larger grain size near the surface of the fractured stems. It appears some polished, tapered HNSS stems are at risk when combinations of these clinical and metallurgical features occur. As the control of grain size, microstructural uniformity, and inclusion content are critical for optimum mechanical performance, it is important the manufacturers review processing methods to further minimize the risk of component failure.

  6. Fabrication of Aligned-Carbon-Nanotube-Composite Paper with High and Anisotropic Conductivity

    Directory of Open Access Journals (Sweden)

    Yuki Fujitsuka

    2012-01-01

    Full Text Available A functional carbon-nanotube (CNT-composite paper is described in which the CNTs are aligned. This “aligned-CNT composite paper” is a flexible composite material that has CNT functionality (e.g., electrical conductivity despite being a paper. An advanced fabrication method was developed to overcome the problem of previous CNT-composite papers, that is, reduced conductivity due to random CNT alignment. Aligning the CNTs by using an alternating current (AC field was hypothesized to increase the electrical conductivity and give the paper an anisotropic characteristic. Experimental results showed that a nonionic surfactant was not suitable as a CNT dispersant for fabricating aligned-CNT composite paper and that catechin with its six-membered rings and hydrophilic groups was suitable. Observation by scanning electron microscopy of samples prepared using catechin showed that the CNTs were aligned in the direction of the AC field on the paper fibers. Measurement of the electric conductivity showed that the surface resistance was different between the direction of the aligned CNTs (high conductivity and that of verticality (low. The conductivity of the aligned-CNT-composite paper samples was higher than that of nonaligned samples. This unique and functional paper, which has high and anisotropic conductivity, is applicable to a conductive material to control the direction of current.

  7. Microstructural features of intergranular brittle fracture and cold cracking in high strength aluminum alloys

    NARCIS (Netherlands)

    Lalpoor, M.; Eskin, D. G.; ten Brink, Gert; Katgerman, L.

    2010-01-01

    Intergranular brittle fracture has been mainly observed and reported in steel alloys and precipitation hardened At-alloys where intergranular precipitates cover a major fraction of the grain boundary area. 7xxx series aluminum alloys suffer from this problem in the as-cast condition when brittle

  8. High prevalence of fractures and osteoporosis in patients with indolent systemic mastocytosis

    NARCIS (Netherlands)

    van der Veer, E.; de Monchy, J. G. R.; Kluin-Nelemans, H. C.; van Doormaal, J. J.; van der Goot, W.

    2012-01-01

    Background: Indolent systemic mastocytosis (ISM) is a rare disease characterized by accumulation of abnormal mast cells in various tissues, including bone marrow. Symptoms are usually related to release of mast cell mediators. The aims are to establish the prevalence of osteoporotic fractures in ISM

  9. Structural and Phase State of Fractured Rotor of High-Pressure Steam Turbine

    Science.gov (United States)

    Smirnov, A. N.; Ababkov, N. V.; Kozlov, E. V.; Koneva, N. A.; Popova, N. A.

    2016-03-01

    The structural and phase state of the metal of a fractured rotor of a steam turbine is studied with the use of modern methods of physical research. The metal is shown to contain gradient structures. The cause of the failure of the rotor is established. The gradient structures are determined by the developed method of acoustic scanning.

  10. Structural Reliability of Ceramics at High Temperature: Mechanisms of Fracture and Fatigue Crack Growth

    Energy Technology Data Exchange (ETDEWEB)

    Reinhold H. Dauskardt

    2005-08-01

    Final report of our DOE funded research program. Aim of the research program was to provide a fundamental basis from which the mechanical reliability of layered structures may be understood, and to provide guidelines for the development of technologically relevant layered material structures with optimum resistance to fracture and subcritical debonding. Progress in the program to achieve these goals is described.

  11. Experimental measurement of the electrical conductivity of single crystal olivine at high temperature and high pressure under different oxygen fugacities

    Institute of Scientific and Technical Information of China (English)

    2006-01-01

    At 1.0-4.0 GPa and 1123-1473 K and under oxygen fugacity-controlled conditions (Ni + NiO, Fe + Fe3O4, Fe +FeO and Mo + MoO2 buffers), a YJ-3000t Model six-anvil solid high-pressure apparatus and a Sarltron-1260 Impedance/Gain-Phase analyzer were employed to conduct an in situ measurement of the electrical conductivity of single crystal olivine. Experimental results showed that: (1) within the range of experimentally selected frequencies (103-106 Hz), the electrical conductivity of the sample is of great dependence on the frequency; (2) with the rise of temperature (T), the electrical conductivity (σ) will increase, and the Arrenhius linear relationship is established between lgσ and 1/T; (3) under the control of oxygen buffer Fe + Fe3O4, with the rise of pressure, the electrical conductivity tends to decrease whereas the activation enthalpy and independent-of-temperature preexponential factor tend to increase,with the activation energy and activation volume of the sample estimated at ( 1.25 ± 0.08) eV and (0. 105 ± 0. 025) cm3/mol, respectively; (4) under given pressure and temperature conditions, the electrical conductivity tends to increase whereas the activation energy tends to decrease with increasing oxygen fugacity; and (5) the mechanism of electrical conduction of small polarons can provide insight into the behavior of electrical conduction of olivine under high pressure and high temperature.

  12. A Self-Consistent Approach for Calculating the Effective Hydraulic Conductivity of a Bimodal, Heterogeneous Medium

    Energy Technology Data Exchange (ETDEWEB)

    Pozdniakov, Sergey; Tsang, Chin-Fu

    2004-01-02

    In this paper, we consider an approach for estimating the effective hydraulic conductivity of a 3D medium with a binary distribution of local hydraulic conductivities. The medium heterogeneity is represented by a combination of matrix medium conductivity with spatially distributed sets of inclusions. Estimation of effective conductivity is based on a self-consistent approach introduced by Shvidler (1985). The tensor of effective hydraulic conductivity is calculated numerically by using a simple system of equations for the main diagonal elements. Verification of the method is done by comparison with theoretical results for special cases and numerical results of Desbarats (1987) and our own numerical modeling. The method was applied to estimating the effective hydraulic conductivity of a 2D and 3D fractured porous medium. The medium heterogeneity is represented by a combination of matrix conductivity and a spatially distributed set of highly conductive fractures. The tensor of effective hydraulic conductivity is calculated for parallel- and random-oriented sets of fractures. The obtained effective conductivity values coincide with Romm's (1966) and Snow's (1969) theories for infinite fracture length. These values are also physically acceptable for the sparsely-fractured-medium case with low fracture spatial density and finite fracture length. Verification of the effective hydraulic conductivity obtained for a fractured porous medium is done by comparison with our own numerical modeling for a 3D case and with Malkovsky and Pek's (1995) results for a 2D case.

  13. A robust, highly stretchable supramolecular polymer conductive hydrogel with self-healability and thermo-processability

    Science.gov (United States)

    Wu, Qian; Wei, Junjie; Xu, Bing; Liu, Xinhua; Wang, Hongbo; Wang, Wei; Wang, Qigang; Liu, Wenguang

    2017-01-01

    Dual amide hydrogen bond crosslinked and strengthened high strength supramolecular polymer conductive hydrogels were fabricated by simply in situ doping poly (N-acryloyl glycinamide-co-2-acrylamide-2-methylpropanesulfonic) (PNAGA-PAMPS) hydrogels with PEDOT/PSS. The nonswellable conductive hydrogels in PBS demonstrated high mechanical performances—0.22–0.58 MPa tensile strength, 1.02–7.62 MPa compressive strength, and 817–1709% breaking strain. The doping of PEDOT/PSS could significantly improve the specific conductivities of the hydrogels. Cyclic heating and cooling could lead to reversible sol-gel transition and self-healability due to the dynamic breakup and reconstruction of hydrogen bonds. The mending hydrogels recovered not only the mechanical properties, but also conductivities very well. These supramolecular conductive hydrogels could be designed into arbitrary shapes with 3D printing technique, and further, printable electrode can be obtained by blending activated charcoal powder with PNAGA-PAMPS/PEDOT/PSS hydrogel under melting state. The fabricated supercapacitor via the conducting hydrogel electrodes possessed high capacitive performances. These cytocompatible conductive hydrogels have a great potential to be used as electro-active and electrical biomaterials.

  14. A robust, highly stretchable supramolecular polymer conductive hydrogel with self-healability and thermo-processability

    Science.gov (United States)

    Wu, Qian; Wei, Junjie; Xu, Bing; Liu, Xinhua; Wang, Hongbo; Wang, Wei; Wang, Qigang; Liu, Wenguang

    2017-01-01

    Dual amide hydrogen bond crosslinked and strengthened high strength supramolecular polymer conductive hydrogels were fabricated by simply in situ doping poly (N-acryloyl glycinamide-co-2-acrylamide-2-methylpropanesulfonic) (PNAGA-PAMPS) hydrogels with PEDOT/PSS. The nonswellable conductive hydrogels in PBS demonstrated high mechanical performances—0.22–0.58 MPa tensile strength, 1.02–7.62 MPa compressive strength, and 817–1709% breaking strain. The doping of PEDOT/PSS could significantly improve the specific conductivities of the hydrogels. Cyclic heating and cooling could lead to reversible sol-gel transition and self-healability due to the dynamic breakup and reconstruction of hydrogen bonds. The mending hydrogels recovered not only the mechanical properties, but also conductivities very well. These supramolecular conductive hydrogels could be designed into arbitrary shapes with 3D printing technique, and further, printable electrode can be obtained by blending activated charcoal powder with PNAGA-PAMPS/PEDOT/PSS hydrogel under melting state. The fabricated supercapacitor via the conducting hydrogel electrodes possessed high capacitive performances. These cytocompatible conductive hydrogels have a great potential to be used as electro-active and electrical biomaterials. PMID:28134283

  15. Dehydration of chlorite explains anomalously high electrical conductivity in the mantle wedges.

    Science.gov (United States)

    Manthilake, Geeth; Bolfan-Casanova, Nathalie; Novella, Davide; Mookherjee, Mainak; Andrault, Denis

    2016-05-01

    Mantle wedge regions in subduction zone settings show anomalously high electrical conductivity (~1 S/m) that has often been attributed to the presence of aqueous fluids released by slab dehydration. Laboratory-based measurements of the electrical conductivity of hydrous phases and aqueous fluids are significantly lower and cannot readily explain the geophysically observed anomalously high electrical conductivity. The released aqueous fluid also rehydrates the mantle wedge and stabilizes a suite of hydrous phases, including serpentine and chlorite. In this present study, we have measured the electrical conductivity of a natural chlorite at pressures and temperatures relevant for the subduction zone setting. In our experiment, we observe two distinct conductivity enhancements when chlorite is heated to temperatures beyond its thermodynamic stability field. The initial increase in electrical conductivity to ~3 × 10(-3) S/m can be attributed to chlorite dehydration and the release of aqueous fluids. This is followed by a unique, subsequent enhancement of electrical conductivity of up to 7 × 10(-1) S/m. This is related to the growth of an interconnected network of a highly conductive and chemically impure magnetite mineral phase. Thus, the dehydration of chlorite and associated processes are likely to be crucial in explaining the anomalously high electrical conductivity observed in mantle wedges. Chlorite dehydration in the mantle wedge provides an additional source of aqueous fluid above the slab and could also be responsible for the fixed depth (120 ± 40 km) of melting at the top of the subducting slab beneath the subduction-related volcanic arc front.

  16. High Thermal Conductivity NARloy-Z-Diamond Composite Combustion Chamber Liner For Advanced Rocket Engines

    Science.gov (United States)

    Bhat, Biliyar N.; Ellis, David; Singh, Jogender

    2014-01-01

    Advanced high thermal conductivity materials research conducted at NASA Marshall Space Flight Center (MSFC) with state of the art combustion chamber liner material NARloy-Z showed that its thermal conductivity can be increased significantly by adding diamond particles and sintering it at high temperatures. For instance, NARloy-Z containing 40 vol. percent diamond particles, sintered at 975C to full density by using the Field assisted Sintering Technology (FAST) showed 69 percent higher thermal conductivity than baseline NARloy-Z. Furthermore, NARloy-Z-40vol. percent D is 30 percent lighter than NARloy-Z and hence the density normalized thermal conductivity is 140 percent better. These attributes will improve the performance and life of the advanced rocket engines significantly. By one estimate, increased thermal conductivity will directly translate into increased turbopump power up to 2X and increased chamber pressure for improved thrust and ISP, resulting in an expected 20 percent improvement in engine performance. Follow on research is now being conducted to demonstrate the benefits of this high thermal conductivity NARloy-Z-D composite for combustion chamber liner applications in advanced rocket engines. The work consists of a) Optimizing the chemistry and heat treatment for NARloy-Z-D composite, b) Developing design properties (thermal and mechanical) for the optimized NARloy-Z-D, c) Fabrication of net shape subscale combustion chamber liner, and d) Hot fire testing of the liner for performance. FAST is used for consolidating and sintering NARlo-Z-D. The subscale cylindrical liner with built in channels for coolant flow is also fabricated near net shape using the FAST process. The liner will be assembled into a test rig and hot fire tested in the MSFC test facility to determine performance. This paper describes the development of this novel high thermal conductivity NARloy-Z-D composite material, and the advanced net shape technology to fabricate the combustion

  17. Hydrologic Mechanisms Governing Fluid Flow in a Partially Saturated, Fractured, Porous Medium

    Science.gov (United States)

    Wang, J. S. Y.; Narasimhan, T. N.

    1985-12-01

    In contrast to the saturated zone within which fluid moves rapidly along fractures, the fractures (with apertures large relative to the size of matrix pores) will desaturate first during the drainage process, and the bulk of fluid flow would be through interconnected pores in the matrix. Within a partially drained fracture, the presence of a relatively continuous air phase will produce practically an infinite resistance to liquid flow in the direction parallel to the fracture. The residual liquid will be held by capillary force, in regions around fracture contact areas where the apertures are small. Normal to the fracture surfaces, the drained portion of the fractures will reduce the effective area for liquid flow from one matrix block to another matrix block. A general statistical theory is constructed for flow along the fracture and for flow between the matrix blocks to the fractures under partially saturated conditions. Results are obtained from an aperture distribution model for fracture saturation, hydraulic conductivity, and effective matrix-fracture flow areas as functions of pressure. The effects of distortion of flow paths by the air pockets are taken into account by a phase-separation constriction factor in a generalized cubic law for fracture flow under a partially saturated condition. The reduction of matrix-fracture flow area is taken into account by summing the aperture distribution function to a saturation cutoff aperture, which is inversely proportional to the suction head. Drainage from a column of fractured tuff is simulated using available parameters for the densely welded tuff of the Topopah Spring Member at Yucca Mountain, southern Nevada. The column is bounded by discrete vertical fractures and dissected by horizontal fractures with the fracture spacings determined by the frequencies and orientations of fractured cores. The fraction of fracture surfaces with coatings is assumed to correspond to the fraction of in situ fracture contact area

  18. Protection of Conductive and Non-conductive Advanced Polymer-based Paints from Highly Aggressive Oxidative Environments

    Science.gov (United States)

    Gudimenko, Y.; Ng, R.; Iskanderova, Z.; Kleiman, J.; Grigorevsky, A.; Kiseleva, L.; Finckenor, M.; Edwards, D.

    2005-01-01

    Research has been continued to further improve the space durability of conductive and non-conductive polymer-based paints and of conductive thermal control paints for space applications. Efforts have been made to enhance the space durability and stability of functional Characteristics in ground-based space environment imitating conditions, using specially developed surface modification treatment. The results of surface modification of new conductive paints, including the ground-based testing in aggressive oxidative environments, such as atomic oxygen/UV and oxygen plasma, and performance evaluation are presented. Functional properties and performance characteristics, such as thermal optical properties (differential solar absorptance and thermal emittance representing the thermal optical performance of thermal control paints) and surface resistivity characteristics of pristine, surface modified, and tested materials were verified. Extensive surface analysis studies have been performed using complementary surface analyses including SEM/EDS and XPS. Test results revealed that the successfully treated materials exhibit reduced mass loss and no surface morphology change, thus indicating good protection from the severe oxidative environment. It was demonstrated that the developed surface modification treatment could be applied successfully to charge dissipative and conductive paints.

  19. Are the High Hip Fracture Rates Among Norwegian Women Explained by Impaired Bone Material Properties?

    Science.gov (United States)

    Duarte Sosa, Daysi; Vilaplana, Laila; Güerri, Roberto; Nogués, Xavier; Wang-Fagerland, Morten; Diez-Perez, Adolfo; F Eriksen, Erik

    2015-10-01

    Hip fracture rates in Norway rank among the highest in the world, more than double that of Spanish women. Previous studies were unable to demonstrate significant differences between the two populations with respect to bone mass or calcium metabolism. In order to test whether the difference in fracture propensity between both populations could be explained by differences in bone material quality we assessed bone material strength using microindentation in 42 Norwegian and 46 Spanish women with normal BMD values, without clinical or morphometric vertebral fractures, no clinical or laboratory signs of secondary osteoporosis, and without use of drugs with known influence on bone metabolism. Bone material properties were assessed by microindentation of the thick cortex of the mid tibia following local anesthesia of the area using the Osteoprobe device (Active Life Scientific, Santa Barbara, CA, USA). Indentation distance was standardized against a calibration phantom of methylmethacrylate and results, as percentage of this reference value, expressed as bone material strength index units (BMSi). We found that the bone material properties reflected in the BMSi value of Norwegian women was significantly inferior when compared to Spanish women (77 ± 7.1 versus 80.7 ± 7.8, p hip BMD was significantly higher in Norwegian women (1.218 g/cm(2) versus 0.938 g/cm(2) , p fracture after such falls. These ethnic differences in bone material properties may partly explain the higher propensity for fracture in Norwegian women. © 2015 American Society for Bone and Mineral Research.

  20. High-performance electrically conductive silver paste prepared by silver-containing precursor

    Energy Technology Data Exchange (ETDEWEB)

    Liu, Jianguo; Cao, Yu; Li, Xiangyou; Wang, Xiaoye; Zeng, Xiaoyan [Huazhong University of Science and Technology, Wuhan National Laboratory for Optoelectronics, College of Optoelectronics Science and Engineering, Wuhan (China)

    2010-09-15

    A high-performance electrically conductive silver paste with no solid particles before drying and/or sintering is developed, in which silver-containing precursor is employed as conductive functional phase. Thermogravimetry analysis, volume electrical resistivity tests and sintering experiments show that the paste with about 14 wt.% silver pristine content is able to achieve the volume electrical resistivity of (2-3) x 10{sup -5} {omega} cm after it is sintered at 220 C. A micro-pen direct-writing process indicates that it is very suitable for the fabrication of high-resolution (25 {mu}m) and high-integration devices and apparatus. (orig.)

  1. High-performance electrically conductive silver paste prepared by silver-containing precursor

    Science.gov (United States)

    Liu, Jianguo; Cao, Yu; Li, Xiangyou; Wang, Xiaoye; Zeng, Xiaoyan

    2010-09-01

    A high-performance electrically conductive silver paste with no solid particles before drying and/or sintering is developed, in which silver-containing precursor is employed as conductive functional phase. Thermogravimetry analysis, volume electrical resistivity tests and sintering experiments show that the paste with about 14 wt.% silver pristine content is able to achieve the volume electrical resistivity of (2-3) ×10-5 Ω cm after it is sintered at 220°C. A micro-pen direct-writing process indicates that it is very suitable for the fabrication of high-resolution (25 μm) and high-integration devices and apparatus.

  2. Net-shape forming of composite packages with high thermal conductivity

    Institute of Scientific and Technical Information of China (English)

    2009-01-01

    The continuing miniaturization of electronic devices in microelectronics and semiconductors drives the development of new packaging materials with enhanced thermal conductivity to dissipate the heat generated in electronic packages. In recent years, several promising composite materials with high thermal conductivity have been developed successfully for high performance electronic equipment to replace the traditional Kovar and Cu/W or Cu/Mo alloys, such as SiCp/Al, SICp/Cu, diamond/Al and diamond/Cu. However, these materials with high content of reinforcements have not been widely used in packaging field because they are hard to be machined into complex-shaped parts due to their greater hardness and brittleness. So, it is necessary to explore a near-net shape forming technology for these composites. In this paper, a novel technology of powder injection molding-infiltration is introduced to realize the near-net shaped preparation of the composite packages with high thermal conductivity.

  3. Net-shape forming of composite packages with high thermal conductivity

    Institute of Scientific and Technical Information of China (English)

    HE XinBo; QU XuanHui; REN ShuBin; JIA ChengGhang

    2009-01-01

    The continuing miniaturization of electronic devices in microelectronics and semiconductors drives the development of new packaging materials with enhanced thermal conductivity to dissipate the heat generated in electronic packages. In recent years, several promising composite materials with high thermal conductivity have been developed successfully for high performance electronic equipment to replace the traditional Kovar and Cu/W or Cu/Mo alloys, such as SiCp/AI, SICp/Cu, diamond/Al and diamond/Cu. However, these materials with high content of reinforcements have not been widely used in packaging field because they are hard to be machined into complex-shaped parts due to their greater hardness and brittleness. So, it is necessary to explore a near-net shape forming technology for these composites. In this paper, a novel technology of powder injection molding-infiltration is introduced to realize the near-net shaped preparation of the composite packages with high thermal conductivity.

  4. Heat Pipe Embedded AlSiC Plates for High Conductivity - Low CTE Heat Spreaders

    Energy Technology Data Exchange (ETDEWEB)

    Johnson, Matthew (DOE/NNSA Kansas City Plant (United States)); Weyant, J.; Garner, S. (Advanced Cooling Technologies, Inc. (Lancaster, PA (United States)); Occhionero, M. (CPS Technologies Corporation, Norton, MA (United States))

    2010-01-07

    Heat pipe embedded aluminum silicon carbide (AlSiC) plates are innovative heat spreaders that provide high thermal conductivity and low coefficient of thermal expansion (CTE). Since heat pipes are two phase devices, they demonstrate effective thermal conductivities ranging between 50,000 and 200,000 W/m-K, depending on the heat pipe length. Installing heat pipes into an AlSiC plate dramatically increases the plate’s effective thermal conductivity. AlSiC plates alone have a thermal conductivity of roughly 200 W/m-K and a CTE ranging from 7-12 ppm/ deg C, similar to that of silicon. An equivalent sized heat pipe embedded AlSiC plate has effective thermal conductivity ranging from 400 to 500 W/m-K and retains the CTE of AlSiC.

  5. Electrical Conductivity of Synthetic Quartz Crystals at High Temperature and Pressure from Complex Impedance Measurements

    Institute of Scientific and Technical Information of China (English)

    王多君; 李和平; 刘丛强; 易丽; 丁东业; 苏根利; 张卫刚

    2002-01-01

    An electrical conductivity measurement system under high-pressure conditions with a multi-anvil high-pressure apparatus by an ac complex impedance method was set up. With this system, we have successfully measured the electrical conductivity of synthetic quartz under pressure up to approximately 1.0 GPa in the temperature range 661-987K. The values of electrical conductivity decrease with the increasing pressure and increase with the increasing temperature. The activation enthalpies for the α-quartz crystals are 1.10-1.28eV. The electrical conductivity of α-quartz is ionic, with Na ions moving in channels parallel to the c-axis being the predominant current carrier.

  6. Highly Conductive Water-Based Polymer/Graphene Nanocomposites for Printed Electronics.

    Science.gov (United States)

    Koutsioukis, Apostolos; Georgakilas, Vasilios; Belessi, Vassiliki; Zboril, Radek

    2017-06-16

    The preparation and characterization of highly conductive carbon inks is described based on nanocomposites that combine a polystyrene-acrylic resin or water-soluble polymers with a hydrophilic graphene/carbon nanotube hybrid. The water-based carbon inks showed high electrical conductivity and could be effectively used in advanced technologies such as gravure printing for printed electronics. Moreover, the conductivity was shown to be increased with a power law of the nanohybrid volume fraction, with an exponent close to that predicted from the percolation theory, indicating a limited impact of the polymer tunneling barrier on the electrical conductivity of such nanocomposites. © 2017 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim.

  7. Characterization of rock thermal conductivity by high-resolution optical scanning

    Science.gov (United States)

    Popov, Y.A.; Pribnow, D.F.C.; Sass, J.H.; Williams, C.F.; Burkhardt, H.

    1999-01-01

    We compared thress laboratory methods for thermal conductivity measurements: divided-bar, line-source and optical scanning. These methods are widely used in geothermal and petrophysical studies, particularly as applied to research on cores from deep scientific boreholes. The relatively new optical scanning method has recently been perfected and applied to geophysical problems. A comparison among these methods for determining the thermal conductivity tensor for anisotropic rocks is based on a representative collection of 80 crystalline rock samples from the KTB continental deep borehole (Germany). Despite substantial thermal inhomogeneity of rock thermal conductivity (up to 40-50% variation) and high anisotropy (with ratios of principal values attaining 2 and more), the results of measurements agree very well among the different methods. The discrepancy for measurements along the foliation is negligible (conductivity normal to the foliation reveals somewhat larger differences (3-4%). Optical scanning allowed us to characterize the thermal inhomogeneity of rocks and to identify a three-dimensional anisotropy in thermal conductivity of some gneiss samples. The merits of optical scanning include minor random errors (1.6%), the ability to record the variation of thermal conductivity along the sample, the ability to sample deeply using a slow scanning rate, freedom from constraints for sample size and shape, and quality of mechanical treatment of the sample surface, a contactless mode of measurement, high speed of operation, and the ability to measure on a cylindrical sample surface. More traditional methods remain superior for characterizing bulk conductivity at elevated temperature.Three laboratory methods including divided-bar, line-source and optical scanning are widely applied in geothermal and petrophysical studies. In this study, these three methods were compared for determining the thermal conductivity tensor for anisotropic rocks. For this study, a

  8. Minimized thermal conductivity in highly stable thermal barrier W/ZrO2 multilayers

    Science.gov (United States)

    Döring, Florian; Major, Anna; Eberl, Christian; Krebs, Hans-Ulrich

    2016-10-01

    Nanoscale thin-film multilayer materials are of great research interest since their large number of interfaces can strongly hinder phonon propagation and lead to a minimized thermal conductivity. When such materials provide a sufficiently small thermal conductivity and feature in addition also a high thermal stability, they would be possible candidates for high-temperature applications such as thermal barrier coatings. For this article, we have used pulsed laser deposition in order to fabricate thin multilayers out of the thermal barrier material ZrO2 in combination with W, which has both a high melting point and high density. Layer thicknesses were designed such that bulk thermal conductivity is governed by the low value of ZrO2, while ultrathin W blocking layers provide a high number of interfaces. By this phonon scattering, reflection and shortening of mean free path lead to a significant reduction in overall thermal conductivity even below the already low value of ZrO2. In addition to this, X-ray reflectivity measurements were taken showing strong Bragg peaks even after annealing such multilayers at 1300 K. Those results identify W/ZrO2 multilayers as desired thermally stable, low-conductivity materials.

  9. Minimized thermal conductivity in highly stable thermal barrier W/ZrO{sub 2} multilayers

    Energy Technology Data Exchange (ETDEWEB)

    Doering, Florian; Major, Anna; Eberl, Christian; Krebs, Hans-Ulrich [University of Goettingen, Institut fuer Materialphysik, Goettingen (Germany)

    2016-10-15

    Nanoscale thin-film multilayer materials are of great research interest since their large number of interfaces can strongly hinder phonon propagation and lead to a minimized thermal conductivity. When such materials provide a sufficiently small thermal conductivity and feature in addition also a high thermal stability, they would be possible candidates for high-temperature applications such as thermal barrier coatings. For this article, we have used pulsed laser deposition in order to fabricate thin multilayers out of the thermal barrier material ZrO{sub 2} in combination with W, which has both a high melting point and high density. Layer thicknesses were designed such that bulk thermal conductivity is governed by the low value of ZrO{sub 2}, while ultrathin W blocking layers provide a high number of interfaces. By this phonon scattering, reflection and shortening of mean free path lead to a significant reduction in overall thermal conductivity even below the already low value of ZrO{sub 2}. In addition to this, X-ray reflectivity measurements were taken showing strong Bragg peaks even after annealing such multilayers at 1300 K. Those results identify W/ZrO{sub 2} multilayers as desired thermally stable, low-conductivity materials. (orig.)

  10. Effect of isolated fractures on accelerated flow in unsaturated porous rock

    Science.gov (United States)

    Su, G.W.; Nimmo, J.R.; Dragila, M.I.

    2003-01-01

    Fractures that begin and end in the unsaturated zone, or isolated fractures, have been ignored in previous studies because they were generally assumed to behave as capillary barriers and remain nonconductive. We conducted a series of experiments using Berea sandstone samples to examine the physical mechanisms controlling flow in a rock containing a single isolated fracture. The input fluxes and fracture orientation were varied in these experiments. Visualization experiments using dyed water in a thin vertical slab of rock were conducted to identify flow mechanisms occurring due to the presence of the isolated fracture. Two mechanisms occurred: (1) localized flow through the rock matrix in the vicinity of the isolated fracture and (2) pooling of water at the bottom of the fracture, indicating the occurrence of film flow along the isolated fracture wall. These mechanisms were observed at fracture angles of 20 and 60 degrees from the horizontal, but not at 90 degrees. Pooling along the bottom of the fracture was observed over a wider range of input fluxes for low-angled isolated fractures compared to high-angled ones. Measurements of matrix water pressures in the samples with the 20 and 60 degree fractures also demonstrated that preferential flow occurred through the matrix in the fracture vicinity, where higher pressures occurred in the regions where faster flow was observed in the visualization experiments. The pooling length at the terminus of a 20 degree isolated fracture was measured as a function of input flux. Calculations of the film flow rate along the fracture were made using these measurements and indicated that up to 22% of the flow occurred as film flow. These experiments, apparently the first to consider isolated fractures, demonstrate that such features can accelerate flow through the unsaturated zone and should be considered when developing conceptual models.

  11. Fuzzy logic structure analysis of trabecular bone of the calcaneus to estimate proximal femur fracture load and discriminate subjects with and without vertebral fractures using high-resolution magnetic resonance imaging at 1.5 T and 3 T.

    Science.gov (United States)

    Patel, Priyesh V; Eckstein, Felix; Carballido-Gamio, Julio; Phan, Catherine; Matsuura, Maiko; Lochmüller, Eva-Maria; Majumdar, Sharmila; Link, Thomas M

    2007-10-01

    Newly developed fuzzy logic-derived structural parameters were used to characterize trabecular bone architecture in high-resolution magnetic resonance imaging (HR-MRI) of human cadaver calcaneus specimens. These parameters were compared to standard histomorphological structural measures and analyzed concerning performance in discriminating vertebral fracture status and estimating proximal femur fracture load. Sets of 60 sagittal 1.5 T and 3.0 T HR-MRI images of the calcaneus were obtained in 39 cadavers using a fast gradient recalled echo sequence. Structural parameters equivalent to bone histomorphometry and fuzzy logic-derived parameters were calculated using two chosen regions of interest. Calcaneal, spine, and hip bone mineral density (BMD) measurements were also obtained. Fracture status of the thoracic and lumbar spine was assessed on lateral radiographs. Finally, mechanical strength testing of the proximal femur was performed. Diagnostic performance in discriminating vertebral fracture status and estimating femoral fracture load was calculated using regression analyses, two-tailed t-tests of significance, and receiver operating characteristic (ROC) analyses. Significant correlations were obtained at both field strengths between all structural and fuzzy logic parameters (r up to 0.92). Correlations between histomorphological or fuzzy logic parameters and calcaneal BMD were mostly significant (r up to 0.78). ROC analyses demonstrated that standard structural parameters were able to differentiate persons with and without vertebral fractures (area under the curve [A(Z)] up to 0.73). However, none of the parameters obtained in the 1.5-T images and none of the fuzzy logic parameters discriminated persons with and without vertebral fractures. Significant correlations were found between fuzzy or structural parameters and femoral fracture load. Using multiple regression analysis, none of the structural or fuzzy parameters were found to add discriminative value to BMD

  12. Fracture toughness and reliability in high-temperature structural ceramics and composites: Prospects and challenges for the 21st Century

    Indian Academy of Sciences (India)

    Sunil Dutta

    2001-04-01

    The importance of high fracture toughness and reliability in Si3N4, and SiC-based structural ceramics and ceramic matrix composites is reviewed. The potential of these ceramics and ceramic matrix composites for high temperature applications in defence and aerospace applications such as gas turbine engines, radomes, and other energy conversion hardware have been well recognized. Numerous investigations were pursued to improve fracture toughness and reliability by incorporating various reinforcements such as particulate-, whisker-, and continuous fibre into Si3N4 and SiC matrices. All toughening mechanisms, e.g. crack deflection, crack branching, crack bridging, etc essentially redistribute stresses at the crack tip and increase the energy needed to propagate a crack through the composite material, thereby resulting in improved fracture toughness and reliability. Because of flaw insensitivity, continuous fibre reinforced ceramic composite (CFCC) was found to have the highest potential for higher operating temperature and longer service conditions. However, the ceramic fibres should display sufficient high temperature strength and creep resistance at service temperatures above 1000°C. The greatest challenge to date is the development of high quality ceramic fibres with associate coatings able to maintain their high strength in oxidizing environment at high temperature. In the area of processing, critical issues are preparation of optimum matrix precursors, precursor infiltration into fibre array, and matrix densification at a temperature, where grain crystallization and fibre degradation do not occur. A broad scope of effort is required for improved processing and properties with a better understanding of all candidate composite systems.

  13. Electrical conductivity of molten CdCl{sub 2} at temperatures as high as 1474 K

    Energy Technology Data Exchange (ETDEWEB)

    Salyulev, Alexander B.; Potapov, Alexei M. [Russian Academy of Sciences, Ekaterinburg (Russian Federation). Inst. of High-Temperature Electrochemistry

    2016-11-01

    The electrical conductivity of molten CdCl{sub 2} was measured across a wide temperature range (ΔT=628 K), from 846 K to as high as 1474 K, i.e. 241 above the normal boiling point of the salt. In previous studies, a maximum temperature of 1201 K was reached, this being 273 lower than in the present work. The activation energy of electrical conductivity was calculated.

  14. Chain-Growth Methods for the Synthesis of High Molecular Weight Conducting and Semiconducting Polymers

    Science.gov (United States)

    2013-08-25

    AFOSR-Final Report Award FA9550-10-1-0395, "Chain-Growth Methods for the Synthesis of High Molecular Weight Conducting and Semiconducting...blocked with further substitution of the fulvene ring systems and we conducted detailed characterization of these systems (X-ray crystal structures...Living Chain-Growth Polymerization for Polythiophenes We have also developed a powerful new method for the synthesis of polythiophenes through the

  15. Method for producing high carrier concentration p-Type transparent conducting oxides

    Science.gov (United States)

    Li, Xiaonan; Yan, Yanfa; Coutts, Timothy J.; Gessert, Timothy A.; Dehart, Clay M.

    2009-04-14

    A method for producing transparent p-type conducting oxide films without co-doping plasma enhancement or high temperature comprising: a) introducing a dialkyl metal at ambient temperature and a saturated pressure in a carrier gas into a low pressure deposition chamber, and b) introducing NO alone or with an oxidizer into the chamber under an environment sufficient to produce a metal-rich condition to enable NO decomposition and atomic nitrogen incorporation into the formed transparent metal conducting oxide.

  16. Silver Nanoparticle-Deposited Boron Nitride Nanosheets as Fillers for Polymeric Composites with High Thermal Conductivity.

    Science.gov (United States)

    Wang, Fangfang; Zeng, Xiaoliang; Yao, Yimin; Sun, Rong; Xu, Jianbin; Wong, Ching-Ping

    2016-01-19

    Polymer composites with high thermal conductivity have recently attracted much attention, along with the rapid development of the electronic devices toward higher speed and performance. However, a common method to enhance polymer thermal conductivity through an addition of high thermally conductive fillers usually cannot provide an expected value, especially for composites requiring electrical insulation. Here, we show that polymeric composites with silver nanoparticle-deposited boron nitride nanosheets as fillers could effectively enhance the thermal conductivity of polymer, thanks to the bridging connections of silver nanoparticles among boron nitride nanosheets. The thermal conductivity of the composite is significantly increased from 1.63 W/m-K for the composite filled with the silver nanoparticle-deposited boron nitride nanosheets to 3.06 W/m-K at the boron nitride nanosheets loading of 25.1 vol %. In addition, the electrically insulating properties of the composite are well preserved. Fitting the measured thermal conductivity of epoxy composite with one physical model indicates that the composite with silver nanoparticle-deposited boron nitride nanosheets outperforms the one with boron nitride nanosheets, owning to the lower thermal contact resistance among boron nitride nanosheets' interfaces. The finding sheds new light on enhancement of thermal conductivity of the polymeric composites which concurrently require the electrical insulation.

  17. Differential heating: A versatile method for thermal conductivity measurements in high-energy-density matter

    Energy Technology Data Exchange (ETDEWEB)

    Ping, Y.; Fernandez-Panella, A.; Correa, A.; Shepherd, R.; Landen, O.; London, R. A.; Sterne, P. A.; Whitley, H. D.; Fratanduono, D.; Collins, G. W. [Lawrence Livermore National Laboratory, Livermore, California 94550 (United States); Sio, H. [Plasma Science and Fusion Center, Massachusetts Institute of Technology, Cambridge, Massachusetts 02139 (United States); Boehly, T. R. [Laboratory for Laser Energetics, University of Rochester, Rochester, New York 14623 (United States)

    2015-09-15

    We propose a method for thermal conductivity measurements of high energy density matter based on differential heating. A temperature gradient is created either by surface heating of one material or at an interface between two materials by different energy deposition. The subsequent heat conduction across the temperature gradient is observed by various time-resolved probing techniques. Conceptual designs of such measurements using laser heating, proton heating, and x-ray heating are presented. The sensitivity of the measurements to thermal conductivity is confirmed by simulations.

  18. High-temperature electrical conductivity and electromechanical properties of stoichiometric lithium niobate

    OpenAIRE

    Ohlendorf, Gerd; Richter, Denny; Sauerwald, Jan; Fritze, Holger

    2016-01-01

    High temperature properties such as electrical conductivity (σ) and resonance behaviour of stoichiometric lithium niobate (LiNbO3) are determined in the temperature range from 20 to 950 °C. The activation energy of the conductivity is found to be 0.9 and 1.7 eV in the temperature range from 500 to 750 °C and from 800 to 950 °C, respectively. During thermal treatments in ambient air up to 950 °C and back, the conductivity remains unchanged at a given temperature, i.e., the crystal is st...

  19. Monitoring percolation of a conductive tracer, as a proxy for nitrate transport, through glacial till and fractured sandstone in the vadose zone underlying a potato field, using 3D cross-hole electrical resistivity imaging

    Science.gov (United States)

    Wang, S.; Butler, K. E.; Serban, D.; Petersen, B.; Grimmett, M.

    2016-12-01

    Nitrate is a necessary nutrient for crops, but high surface water and groundwater concentrations can negatively affect aquatic ecosystem and human health. At AAFC-AAC Harrington Research Farm (PEI, Canada), 3D cross-hole electrical resistivity imaging (ERI) is being used to investigate the percolation of a conductive tracer (KCl) through a 17 m thick vadose zone as a proxy for the transport of nitrate under natural recharge conditions. The objectives are to investigate the effect of heterogeneity on transport pathways and infer how long it would take for changes in farming practices at the surface to affect nitrate loading to the underlying aquifer. The resistivity array consists of 96 permanently installed electrodes - 24 at 0.68 m spacing in each of three 16 m deep boreholes arranged in a triangle with 9 m sides, and 24 at 1 m spacing buried in shallow trenches connecting the boreholes. A background survey revealed five sub-horizontal layers of alternating resistivity in general agreement with the geology of 6 m soil and glacial till overburden overlying interbedded sandstone and shaley sandstone layers. On March 27th, 2015, 1.1 m of snow was removed from a 15.2 m2 area positioned symmetrically inside the triangular array and 100 kg of granular KCl was distributed on the ground surface. The removed snow was immediately replaced to await the spring thaw. Post-tracer surveys indicate tracer had percolated to depths of 1 m, 1.2 m, 3.0 m and 3.5 m by the 4th, 26th, 30th, and 46th days after tracer application. Its movement slowed significantly by early May, 2015, with the end of snow melt. Tracer spread laterally very slowly through the summer and early fall, 2015, but has remained within the triangular array. The shallow conductivity anomaly produced by the tracer diminished significantly over the winter and spring of 2016 but showed little evidence of bulk matrix flow below 3.5 m depth. It is speculated that fractures in the glacial till, too thin to be resolved by

  20. A promising approach to conductive patterns with high efficiency for flexible electronics

    Energy Technology Data Exchange (ETDEWEB)

    Tai Yanlong [Department of Materials Science, Fudan University, Shanghai 200433 (China); Yang Zhenguo, E-mail: zgyang@fudan.edu.cn [Department of Materials Science, Fudan University, Shanghai 200433 (China); Li Zhidong [Shenzhen Fastprint Circuit Technology Co. Ltd., Shenzhen 518057 (China)

    2011-06-01

    A promising approach for conductive patterns with high efficiency for flexible electronics was developed by direct-writing, silver(I) solution (silver nitrate, acetate silver, etc.) with no solid particles as a conductive ink, conductive pen as a writing implement, and polyimide (PI) film as a substrate. The physical properties of the conductive ink were investigated by a dynamic contact angle system, ubbelohde viscometer and surface tension instrument. Conductive properties of silver ink film were investigated by 4-point probe, scanning electron microscope (SEM) and surface profilometer. It is demonstrated how the design of solvent composition in conductive ink affects surface morphology, and conductivity of silver ink films. It can be obtained that conductive patterns drawn on PI substrate not only have good mechanical/electrical fatigue properties, but also have low resistivity. Especially, when the sintering condition is 200 deg. C for 60 min, the resistivity can be down to 6.6 {mu}{Omega} cm, 4.25 times the silver bulk resistivity.

  1. A promising approach to conductive patterns with high efficiency for flexible electronics

    Science.gov (United States)

    Tai, Yan-Long; Yang, Zhen-Guo; Li, Zhi-Dong

    2011-06-01

    A promising approach for conductive patterns with high efficiency for flexible electronics was developed by direct-writing, silver(I) solution (silver nitrate, acetate silver, etc.) with no solid particles as a conductive ink, conductive pen as a writing implement, and polyimide (PI) film as a substrate. The physical properties of the conductive ink were investigated by a dynamic contact angle system, ubbelohde viscometer and surface tension instrument. Conductive properties of silver ink film were investigated by 4-point probe, scanning electron microscope (SEM) and surface profilometer. It is demonstrated how the design of solvent composition in conductive ink affects surface morphology, and conductivity of silver ink films. It can be obtained that conductive patterns drawn on PI substrate not only have good mechanical/electrical fatigue properties, but also have low resistivity. Especially, when the sintering condition is 200 °C for 60 min, the resistivity can be down to 6.6 μΩ cm, 4.25 times the silver bulk resistivity.

  2. A Study of the Preparation and Properties of Antioxidative Copper Inks with High Electrical Conductivity.

    Science.gov (United States)

    Tsai, Chia-Yang; Chang, Wei-Chen; Chen, Guan-Lin; Chung, Cheng-Huan; Liang, Jun-Xiang; Ma, Wei-Yang; Yang, Tsun-Neng

    2015-12-01

    Conductive ink using copper nanoparticles has attracted much attention in the printed electronics industry because of its low cost and high electrical conductivity. However, the problem of easy oxidation under heat and humidity conditions for copper material limits the wide applications. In this study, antioxidative copper inks were prepared by dispersing the nanoparticles in the solution, and then conductive copper films can be obtained after calcining the copper ink at 250 °C in nitrogen atmosphere for 30 min. A low sheet resistance of 47.6 mΩ/□ for the copper film was measured by using the four-point probe method. Importantly, we experimentally demonstrate that the electrical conductivity of copper films can be improved by increasing the calcination temperature. In addition, these highly conductive copper films can be placed in an atmospheric environment for more than 6 months without the oxidation phenomenon, which was verified by energy-dispersive X-ray spectroscopy (EDS). These observations strongly show that our conductive copper ink features high antioxidant properties and long-term stability and has a great potential for many printed electronics applications, such as flexible display systems, sensors, photovoltaic cells, and radio frequency identification.

  3. Optimizing amorphous indium zinc oxide film growth for low residual stress and high electrical conductivity

    Energy Technology Data Exchange (ETDEWEB)

    Kumar, Mukesh [Department of Metallurgical and Materials Engineering, Colorado School of Mines, Golden, CO 80401 (United States); Sigdel, A.K. [Department of Physics and Astronomy, University of Denver, Denver, CO 80208 (United States); National Center for Photovoltaics, National Renewal Energy Laboratory, 1617 Cole Boulevard, Golden, CO 80401 (United States); Gennett, T.; Berry, J.J.; Perkins, J.D.; Ginley, D.S. [National Center for Photovoltaics, National Renewal Energy Laboratory, 1617 Cole Boulevard, Golden, CO 80401 (United States); Packard, C.E., E-mail: cpackard@mines.edu [Department of Metallurgical and Materials Engineering, Colorado School of Mines, Golden, CO 80401 (United States); National Center for Photovoltaics, National Renewal Energy Laboratory, 1617 Cole Boulevard, Golden, CO 80401 (United States)

    2013-10-15

    With recent advances in flexible electronics, there is a growing need for transparent conductors with optimum conductivity tailored to the application and nearly zero residual stress to ensure mechanical reliability. Within amorphous transparent conducting oxide (TCO) systems, a variety of sputter growth parameters have been shown to separately impact film stress and optoelectronic properties due to the complex nature of the deposition process. We apply a statistical design of experiments (DOE) approach to identify growth parameter–material property relationships in amorphous indium zinc oxide (a-IZO) thin films and observed large, compressive residual stresses in films grown under conditions typically used for the deposition of highly conductive samples. Power, growth pressure, oxygen partial pressure, and RF power ratio (RF/(RF + DC)) were varied according to a full-factorial test matrix and each film was characterized. The resulting regression model and analysis of variance (ANOVA) revealed significant contributions to the residual stress from individual growth parameters as well as interactions of different growth parameters, but no conditions were found within the initial growth space that simultaneously produced low residual stress and high electrical conductivity. Extrapolation of the model results to lower oxygen partial pressures, combined with prior knowledge of conductivity–growth parameter relationships in the IZO system, allowed the selection of two promising growth conditions that were both empirically verified to achieve nearly zero residual stress and electrical conductivities >1480 S/cm. This work shows that a-IZO can be simultaneously optimized for high conductivity and low residual stress.

  4. High proton conductivity in the molecular interlayer of a polymer nanosheet multilayer film.

    Science.gov (United States)

    Sato, Takuma; Hayasaka, Yuta; Mitsuishi, Masaya; Miyashita, Tokuji; Nagano, Shusaku; Matsui, Jun

    2015-05-12

    High proton conductivity was achieved in a polymer multilayer film with a well-defined two-dimensional lamella structure. The multilayer film was prepared by deposition of poly(N-dodecylacryamide-co-acrylic acid) (p(DDA/AA)) monolayers onto a solid substrate using the Langmuir-Blodgett technique. Grazing-angle incidence X-ray diffraction measurement of a 30-layer film of p(DDA/AA) showed strong diffraction peaks in the out-of-plane direction at 2θ = 2.26° and 4.50°, revealing that the multilayer film had a highly uniform layered structure with a monolayer thickness of 2.0 nm. The proton conductivity of the p(DDA/AA) multilayer film parallel to the layer plane direction was 0.051 S/cm at 60 °C and 98% relative humidity with a low activation energy of 0.35 eV, which is comparable to perfluorosulfonic acid membranes. The high conductivity and low activation energy resulted from the formation of uniform two-dimensional proton-conductive nanochannels in the hydrophilic regions of the multilayer film. The proton conductivity of the multilayer film perpendicular to the layer plane was determined to be 2.1 × 10(-13) S/cm. Therefore, the multilayer film showed large anisotropic conductivity with an anisotropic ratio of 2.4 × 10(11).

  5. A new methodology for automating acoustic emission detection of metallic fatigue fractures in highly demanding aerospace environments: An overview

    Science.gov (United States)

    Holford, Karen M.; Eaton, Mark J.; Hensman, James J.; Pullin, Rhys; Evans, Sam L.; Dervilis, Nikolaos; Worden, Keith

    2017-04-01

    The acoustic emission (AE) phenomenon has many attributes that make it desirable as a structural health monitoring or non-destructive testing technique, including the capability to continuously and globally monitor large structures using a sparse sensor array and with no dependency on defect size. However, AE monitoring is yet to fulfil its true potential, due mainly to limitations in location accuracy and signal characterisation that often arise in complex structures with high levels of background noise. Furthermore, the technique has been criticised for a lack of quantitative results and the large amount of operator interpretation required during data analysis. This paper begins by introducing the challenges faced in developing an AE based structural health monitoring system and then gives a review of previous progress made in addresing these challenges. Subsequently an overview of a novel methodology for automatic detection of fatigue fractures in complex geometries and noisy environments is presented, which combines a number of signal processing techniques to address the current limitations of AE monitoring. The technique was developed for monitoring metallic landing gear components during pre-flight certification testing and results are presented from a full-scale steel landing gear component undergoing fatigue loading. Fracture onset was successfully identify automatically at 49,000 fatigue cycles prior to final failure (validated by the use of dye penetrant inspection) and the fracture position was located to within 10 mm of the actual location.

  6. Enhancement of Impact Toughness by Delamination Fracture in a Low-Alloy High-Strength Steel with Al Alloying

    Science.gov (United States)

    Sun, Junjie; Jiang, Tao; Liu, Hongji; Guo, Shengwu; Liu, Yongning

    2016-09-01

    The effect of delamination toughening of martensitic steel was investigated both at room and low temperatures [253 K and 233 K (-20 °C and -40 °C)]. Two low-alloy martensitic steels with and without Al alloying were both prepared. Layered structure with white band and black matrix was observed in Al alloyed steel, while a homogeneous microstructure was displayed in the steel without Al. Both steels achieved high strength (tensile strength over 1600 MPa) and good ductility (elongation over 11 pct), but they displayed stark contrasts on impact fracture mode and Charpy impact energy. Delamination fracture occurred in Al alloyed steel and the impact energies were significantly increased both at room temperature (from 75 to 138 J, i.e., nearly improved up to 2 times) and low temperatures [from 47.9 to 71.3 J at 233 K (-40 °C)] compared with the one without Al. Alloying with Al promotes the segregation of Cr, Mn, Si and C elements to form a network structure, which is martensite with higher carbon content and higher hardness than that of the matrix. And this network structure evolved into a band structure during the hot rolling process. The difference of yield stress between the band structure and the matrix gives rise to a delamination fracture during the impact test, which increases the toughness greatly.

  7. Geostatistical estimation of the transmissivity in a highly fractured metamorphic and crystalline aquifer (Man-Danane Region, Western Ivory Coast)

    Science.gov (United States)

    Razack, Moumtaz; Lasm, Théophile

    2006-06-01

    This work is aimed at estimating the transmissivity of highly fractured hard rock aquifers using a geostatistical approach. The studied aquifer is formed by the crystalline and metamorphic rocks of the Western Ivory Coast (West Africa), in the Man Danané area. The study area covers 7290 km 2 (90 km×81 km). The fracturing network is dense and well connected, without a marked fracture direction. A data base comprising 118 transmissivity ( T) values and 154 specific capacity ( Q/ s) values was compiled. A significant empirical relationship between T and Q/ s was found, which enabled the transmissivity data to be supplemented. The variographic analysis of the two variables showed that the variograms of T and Q/ s (which are lognormal variables) are much more structured than those of log T and log Q/ s (which are normal variables). This result is contrary to what was previously published and raises the question whether normality is necessary in geostatistical analysis. Several input and geostatistical estimations of the transmissivity were tested using the cross validation procedure: measured transmissivity data; supplemented transmissivity data; kriging; cokriging. The cross validation results showed that the best estimation is provided using the kriging procedure, the transmissivity field represented by the whole data sample (measured+estimated using specific capacity) and the structural model evaluated solely on the measured transmissivity. The geostatistical approach provided in fine a reliable estimation of the transmissivity of the Man Danané aquifer, which will be used as an input in forthcoming modelling.

  8. Enhancement of Impact Toughness by Delamination Fracture in a Low-Alloy High-Strength Steel with Al Alloying

    Science.gov (United States)

    Sun, Junjie; Jiang, Tao; Liu, Hongji; Guo, Shengwu; Liu, Yongning

    2016-12-01

    The effect of delamination toughening of martensitic steel was investigated both at room and low temperatures [253 K and 233 K (-20 °C and -40 °C)]. Two low-alloy martensitic steels with and without Al alloying were both prepared. Layered structure with white band and black matrix was observed in Al alloyed steel, while a homogeneous microstructure was displayed in the steel without Al. Both steels achieved high strength (tensile strength over 1600 MPa) and good ductility (elongation over 11 pct), but they displayed stark contrasts on impact fracture mode and Charpy impact energy. Delamination fracture occurred in Al alloyed steel and the impact energies were significantly increased both at room temperature (from 75 to 138 J, i.e., nearly improved up to 2 times) and low temperatures [from 47.9 to 71.3 J at 233 K (-40 °C)] compared with the one without Al. Alloying with Al promotes the segregation of Cr, Mn, Si and C elements to form a network structure, which is martensite with higher carbon content and higher hardness than that of the matrix. And this network structure evolved into a band structure during the hot rolling process. The difference of yield stress between the band structure and the matrix gives rise to a delamination fracture during the impact test, which increases the toughness greatly.

  9. Fluid-loss control for high-permeability rocks in hydraulic fracturing under realistic shear conditions

    Energy Technology Data Exchange (ETDEWEB)

    Navarrete, R.C.; Mitchell, J.P.

    1995-12-31

    A study is presented on the effectiveness of different combinations of fluid and fluid-loss additives to control fluid loss in high-permeability formations under high shear rates. The impact on matrix damage and proppant-pack damage is also studied. Borate-crosslinked guars, hydroxyethylcellulose (HEC) and a surfactant water-base gravel packing fluid were investigated. The fluid-loss additive considered was silica flour. All fluid-loss tests were run in dynamic fluid-loss cells. To properly test high-permeability cores, new long core dynamic fluid-loss cells were used. The matrix damage caused by the invasion of the fluid was determined using pressure taps along the core. Conductivity tests were also run to determine the damage to the proppant pack. Results show that the effectiveness of particulate fluid-loss additives under dynamic conditions is strongly dependent on the initial leakoff rate, which depends on the pressure gradient across the core, permeability of the core and viscosity of the invading fluid. The use of silica flour helps matrix flowback, and it has a minimal effect on proppant-pack conductivity in clean fluids (e.g., surfactant water-base gravel packing fluid). With the exception of the borate-crosslinked guar with no fluid-loss additive, the variety of fluids used in these tests (with and without silica flour) have a negligible effect on postproduction.

  10. The effect of non-metallic inclusions on the fracture toughness master curve in high copper reactor pressure vessel welds

    Science.gov (United States)

    Oh, Yong-Jun; Lee, Bong-Sang; Hong, Jun-Hwa

    2002-03-01

    The fracture toughness of two high copper reactor pressure vessel welds having low upper shelf energy was evaluated in accordance with the master curve method of ASTM E1921. The resultant data were correlated to the metallurgical factors involved in the brittle fracture initiation to provide a metallurgical-based understanding of the master curve. The tests were performed using pre-cracked Charpy V-notched specimens and the master curve was made with an average of T0 values determined at different temperatures. In all specimens, the cleavage fracture initiated at non-metallic inclusion ranging from 0.7 to 3.5 μm in diameter showing a scatter with the specimens and testing temperatures. Temperature dependency of the triggering particle size was not found. The fracture toughness ( KJC) was inversely proportional to the square root of the triggering inclusion diameter ( di) at respective temperatures. From this relationship, we determined median KJC values which correspond to the average value of triggering inclusion diameter of all tested specimens and defined them as a modified median KJC ( K'JC(med) ). The obtained K'JC(med) values showed quite smaller deviation from the master curve at different temperatures than the experimental median KJC values. This suggests that the master curve is on the premise of a constant dimension of key microstructural factor in a material regardless of the testing temperature. But the inclusion size at trigger point played an important role in the absolute position of the master curve with temperature and the consequent T0 value.

  11. The effect of non-metallic inclusions on the fracture toughness master curve in high copper reactor pressure vessel welds

    Energy Technology Data Exchange (ETDEWEB)

    Oh, Yong-Jun E-mail: yjoh@kaeri.re.kr; Lee, Bong-Sang; Hong, Jun-Hwa

    2002-03-01

    The fracture toughness of two high copper reactor pressure vessel welds having low upper shelf energy was evaluated in accordance with the master curve method of ASTM E1921. The resultant data were correlated to the metallurgical factors involved in the brittle fracture initiation to provide a metallurgical-based understanding of the master curve. The tests were performed using pre-cracked Charpy V-notched specimens and the master curve was made with an average of T{sub 0} values determined at different temperatures. In all specimens, the cleavage fracture initiated at non-metallic inclusion ranging from 0.7 to 3.5 {mu}m in diameter showing a scatter with the specimens and testing temperatures. Temperature dependency of the triggering particle size was not found. The fracture toughness (K{sub J{sub C}}) was inversely proportional to the square root of the triggering inclusion diameter (d{sub i}) at respective temperatures. From this relationship, we determined median K{sub J{sub C}} values which correspond to the average value of triggering inclusion diameter of all tested specimens and defined them as a modified median K{sub J{sub C}} (K{sup '}{sub J{sub C}}{sub (med)}). The obtained K{sup '}{sub J{sub C}}{sub (med)} values showed quite smaller deviation from the master curve at different temperatures than the experimental median K{sub J{sub C}} values. This suggests that the master curve is on the premise of a constant dimension of key microstructural factor in a material regardless of the testing temperature. But the inclusion size at trigger point played an important role in the absolute position of the master curve with temperature and the consequent T{sub 0} value.

  12. Limited magnetic resonance imaging of the lumbar spine has high sensitivity for detection of acute fractures, infection, and malignancy

    Energy Technology Data Exchange (ETDEWEB)

    Wang, Benjamin; Fintelmann, Florian J.; Kamath, Ravi S.; Kattapuram, Susan V.; Rosenthal, Daniel I. [Massachusetts General Hospital, Department of Radiology, Boston, MA (United States)

    2016-12-15

    The objective of this study is to determine how a limited protocol MR examination compares to a full conventional MR examination for the detection of non-degenerative pathology such as acute fracture, infection, and malignancy. A sample of 349 non-contrast MR exams was selected retrospectively containing a 3:1:1:1 distribution of negative/degenerative change only, acute fracture, infection, and malignancy. This resulted in an even distribution of pathology and non-pathology. A limited protocol MR exam was simulated by extracting T1-weighted sagittal and T2-weighted fat-saturated (or STIR) sagittal sequences from each exam and submitting them for blinded review by two experienced musculoskeletal radiologists. The exams were evaluated for the presence or absence of non-degenerative pathology. Interpretation of the limited exam was compared to the original report of the full examination. If either reader disagreed with the original report, the case was submitted for an unblinded adjudication process with the participation of a third musculoskeletal radiologist to establish a consensus diagnosis. There were five false negatives for a sensitivity of 96.9 % for the limited protocol MR exam. Infection in the psoas, paraspinal muscles, and sacroiliac joint, as well as acute fractures in transverse processes and sacrum were missed by one or more readers. No cases of malignancy were missed. Overall diagnostic accuracy was 96.0 % (335/349). MR imaging of the lumbar spine limited to sagittal T1-weighted and sagittal T2 fat-saturated (or STIR) sequences has high sensitivity for the detection of acute fracture, infection, or malignancy compared to a conventional MR examination. (orig.)

  13. Reduction of Temperature in Concentrator Photovoltaic Module Using Coating with High Thermal Emissivity and Conductivity

    Directory of Open Access Journals (Sweden)

    Nakamura Satoshi

    2016-01-01

    Full Text Available The temperature of solar cells considerably increases under light-concentrating operations, and the conversion efficiency of solar cells decreases with increasing temperature. It is very important to reduce the cell temperature in concentrator photovoltaic modules. The thermal radiation layers with high thermal emissivity and thermal conductivity was coated on the aluminum samples which is used for the chassis of concentrator photovoltaic and the effect was evaluated under the conditions with wind. The temperature of sample with coating showed lower temperature than that without coating. In the condition with wind, the coated sample with high thermal emissivity and high thermal conductivity showed the lowest temperature due to the effect of thermal radiation and thermal conduction.

  14. Low temperature platinum atomic layer deposition on nylon-6 for highly conductive and catalytic fiber mats

    Energy Technology Data Exchange (ETDEWEB)

    Mundy, J. Zachary; Shafiefarhood, Arya; Li, Fanxing; Khan, Saad A.; Parsons, Gregory N., E-mail: gnp@ncsu.edu [Department of Chemical and Biomolecular Engineering, North Carolina State University, Engineering Building I, 911 Partners Way, Raleigh, North Carolina 27695-7905 (United States)

    2016-01-15

    Low temperature platinum atomic layer deposition (Pt-ALD) via (methylcyclopentadienyl)trimethyl platinum and ozone (O{sub 3}) is used to produce highly conductive nonwoven nylon-6 (polyamide-6, PA-6) fiber mats, having effective conductivities as high as ∼5500–6000 S/cm with only a 6% fractional increase in mass. The authors show that an alumina ALD nucleation layer deposited at high temperature is required to promote Pt film nucleation and growth on the polymeric substrate. Fractional mass gain scales linearly with Pt-ALD cycle number while effective conductivity exhibits a nonlinear trend with cycle number, corresponding to film coalescence. Field-emission scanning electron microscopy reveals island growth mode of the Pt film at low cycle number with a coalesced film observed after 200 cycles. The metallic coating also exhibits exceptional resistance to mechanical flexing, maintaining up to 93% of unstressed conductivity after bending around cylinders with radii as small as 0.3 cm. Catalytic activity of the as-deposited Pt film is demonstrated via carbon monoxide oxidation to carbon dioxide. This novel low temperature processing allows for the inclusion of highly conductive catalytic material on a number of temperature-sensitive substrates with minimal mass gain for use in such areas as smart textiles and flexible electronics.

  15. Interfacial Engineering of Silicon Carbide Nanowire/Cellulose Microcrystal Paper toward High Thermal Conductivity.

    Science.gov (United States)

    Yao, Yimin; Zeng, Xiaoliang; Pan, Guiran; Sun, Jiajia; Hu, Jiantao; Huang, Yun; Sun, Rong; Xu, Jian-Bin; Wong, Ching-Ping

    2016-11-16

    Polymer composites with high thermal conductivity have attracted much attention, along with the rapid development of electronic devices toward higher speed and better performance. However, high interfacial thermal resistance between fillers and matrix or between fillers and fillers has been one of the primary bottlenecks for the effective thermal conduction in polymer composites. Herein, we report on engineering interfacial structure of silicon carbide nanowire/cellulose microcrystal paper by generating silver nanostructures. We show that silver nanoparticle-deposited silicon carbide nanowires as fillers can effectively enhance the thermal conductivity of the matrix. The in-plane thermal conductivity of the resultant composite paper reaches as high as 34.0 W/m K, which is one order magnitude higher than that of conventional polymer composites. Fitting the measured thermal conductivity with theoretical models qualitatively demonstrates that silver nanoparticles bring the lower interfacial thermal resistances both at silicon carbide nanowire/cellulose microcrystal and silicon carbide nanowire/silicon carbide nanowire interfaces. This interfacial engineering approach provides a powerful tool for sophisticated fabrication of high-performance thermal-management materials.

  16. In situ observation of fracture processes in high-strength concretes and limestone using high-speed X-ray phase-contrast imaging

    Science.gov (United States)

    Parab, Niranjan D.; Guo, Zherui; Hudspeth, Matthew; Claus, Benjamin; Lim, Boon Him; Sun, Tao; Xiao, Xianghui; Fezzaa, Kamel; Chen, Weinong W.

    2017-01-01

    The mechanical properties and fracture mechanisms of geomaterials and construction materials such as concrete are reported to be dependent on the loading rates. However, the in situ cracking inside such specimens cannot be visualized using traditional optical imaging methods since the materials are opaque. In this study, the in situ sub-surface failure/damage mechanisms in Cor-Tuf (a reactive powder concrete), a high-strength concrete (HSC) and Indiana limestone under dynamic loading were investigated using high-speed synchrotron X-ray phase-contrast imaging. Dynamic compressive loading was applied using a modified Kolsky bar and fracture images were recorded using a synchronized high-speed synchrotron X-ray imaging set-up. Three-dimensional synchrotron X-ray tomography was also performed to record the microstructure of the specimens before dynamic loading. In the Cor-Tuf and HSC specimens, two different modes of cracking were observed: straight cracking or angular cracking with respect to the direction of loading. In limestone, cracks followed the grain boundaries and voids, ultimately fracturing the specimen. Cracks in HSC were more tortuous than the cracks in Cor-Tuf specimens. The effects of the microstructure on the observed cracking behaviour are discussed. This article is part of the themed issue 'Experimental testing and modelling of brittle materials at high strain rates'.

  17. In situ observation of fracture processes in high-strength concretes and limestone using high-speed X-ray phase-contrast imaging

    Energy Technology Data Exchange (ETDEWEB)

    Parab, Niranjan D.; Guo, Zherui; Hudspeth, M.; Claus, Benjamin; Lim, Boon Him; Sun, Tao; Xiao, Xianghui; Fezzaa, Kamel; Chen, Weinong W.

    2017-01-01

    The mechanical properties and fracture mechanisms of geomaterials and construction materials such as concrete are reported to be dependent on the loading rates. However, the in situ cracking inside such specimens cannot be visualized using traditional optical imaging methods since the materials are opaque. In this study, the in situ sub-surface failure/damage mechanisms in Cor-Tuf (a reactive powder concrete), a high-strength concrete (HSC) and Indiana limestone under dynamic loading were investigated using high-speed synchrotron X-ray phase-contrast imaging. Dynamic compressive loading was applied using a modified Kolsky bar and fracture images were recorded using a synchronized high-speed synchrotron X-ray imaging set-up. Three-dimensional synchrotron X-ray tomography was also performed to record the microstructure of the specimens before dynamic loading. In the Cor-Tuf and HSC specimens, two different modes of cracking were observed: straight cracking or angular cracking with respect to the direction of loading. In limestone, cracks followed the grain boundaries and voids, ultimately fracturing the specimen. Cracks in HSC were more tortuous than the cracks in Cor-Tuf specimens. The effects of the microstructure on the observed cracking behaviour are discussed. This article is part of the themed issue ‘Experimental testing and modelling of brittle materials at high strain rates’.

  18. Challenges and opportunities for fractured rock imaging using 3D cross-borehole electrical resistivity

    Energy Technology Data Exchange (ETDEWEB)

    Robinson, Judith; Johnson, Timothy C.; Slater, Lee D.

    2015-02-02

    There is an increasing need to characterize discrete fractures away from boreholes to better define fracture distributions and monitor solute transport. We performed a 3D evaluation of static and time-lapse cross-borehole electrical resistivity tomography (ERT) data sets from a limestone quarry in which flow and transport are controlled by a bedding-plane feature. Ten boreholes were discretized using an unstructured tetrahedral mesh, and 2D panel measurements were inverted for a 3D distribution of conductivity. We evaluated the benefits of 3D versus 2.5D inversion of ERT data in fractured rock while including the use of borehole regularization disconnects (BRDs) and borehole conductivity constraints. High-conductivity halos (inversion artifacts) surrounding boreholes were removed in static images when BRDs and borehole conductivity constraints were implemented. Furthermore, applying these constraints focused transient changes in conductivity resulting from solute transport on the bedding plane, providing a more physically reasonable model for conductivity changes associated with solute transport at this fractured rock site. Assuming bedding-plane continuity between fractures identified in borehole televiewer data, we discretized a planar region between six boreholes and applied a fracture regularization disconnect (FRD). Although the FRD appropriately focused conductivity changes on the bedding plane, the conductivity distribution within the discretized fracture was nonunique and dependent on the starting homogeneous model conductivity. Synthetic studies performed to better explain field observations showed that inaccurate electrode locations in boreholes resulted in low-conductivity halos surrounding borehole locations. These synthetic studies also showed that the recovery of the true conductivity within an FRD depended on the conductivity contrast between the host rock and fractures. Our findings revealed that the potential exists to improve imaging of fractured

  19. Lustrous copper nanoparticle film: Photodeposition with high quantum yield and electric conductivity

    Science.gov (United States)

    Miyagawa, Masaya; Yonemura, Mari; Tanaka, Hideki

    2016-11-01

    Cu nanoparticle (NP) film has attracted much attention due to its high electric conductivity. In the present study, we prepared a Cu NP film on a TiO2-coated substrate by photoreduction of copper acetate solution. The obtained film showed high electric conductivity and metallic luster by the successive deposition of Cu NP. Moreover, the film was decomposed on exposure to fresh air, and its decomposition reaction mechanisms were proposed. Hence, we concluded that the obtained lustrous film was composed of Cu NP, even though its physical properties was similar to bulk copper.

  20. Fractal Characteristics of Rock Fracture Surface under Triaxial Compression after High Temperature

    Directory of Open Access Journals (Sweden)

    X. L. Xu

    2016-01-01

    Full Text Available Scanning Electron Microscopy (SEM test on 30 pieces of fractured granite has been researched by using S250MK III SEM under triaxial compression of different temperature (25~1000°C and confining pressure (0~40 MPa. Research results show that (1 the change of fractal dimension (FD of rock fracture with temperature is closely related to confining pressure, which can be divided into two categories. In the first category, when confining pressure is in 0~30 MPa, FD fits cubic polynomial fitting curve with temperature, reaching the maximum at 600°C. In the second category, when confining pressure is in 30~40 MPa, FD has volatility with temperature. (2 The FD of rock fracture varies with confining pressure and is also closely related to the temperature, which can be divided into three categories. In the first category, FD has volatility with confining pressure at 25°C, 400°C, and 800°C. In the second category, it increases exponentially at 200°C and 1000°C. In the third category, it decreases exponentially at 600°C. (3 It is found that 600°C is the critical temperature and 30 MPa is the critical confining pressure of granite. The rock transfers from brittle to plastic phase transition when temperature exceeds 600°C and confining pressure exceeds 30 MPa.

  1. Highly conductive NiCo2S4 urchin-like nanostructures for high-rate pseudocapacitors

    Science.gov (United States)

    Chen, Haichao; Jiang, Jianjun; Zhang, Li; Wan, Houzhao; Qi, Tong; Xia, Dandan

    2013-09-01

    A 3D highly conductive urchin-like NiCo2S4 nanostructure has been successfully prepared using a facile precursor transformation method. Remarkably, the NiCo2S4 electroactive material demonstrates superior electrochemical performance with ultrahigh high-rate capacitance, very high specific capacitance, and excellent cycling stability.A 3D highly conductive urchin-like NiCo2S4 nanostructure has been successfully prepared using a facile precursor transformation method. Remarkably, the NiCo2S4 electroactive material demonstrates superior electrochemical performance with ultrahigh high-rate capacitance, very high specific capacitance, and excellent cycling stability. Electronic supplementary information (ESI) available: Experimental details, and the electrochemical performances of NiCo2O4, Co9S8 and NiS. See DOI: 10.1039/c3nr02958a

  2. Atomistic simulations of highly conductive molecular transport junctions under realistic conditions

    KAUST Repository

    French, William R.

    2013-01-01

    We report state-of-the-art atomistic simulations combined with high-fidelity conductance calculations to probe structure-conductance relationships in Au-benzenedithiolate (BDT)-Au junctions under elongation. Our results demonstrate that large increases in conductance are associated with the formation of monatomic chains (MACs) of Au atoms directly connected to BDT. An analysis of the electronic structure of the simulated junctions reveals that enhancement in the s-like states in Au MACs causes the increases in conductance. Other structures also result in increased conductance but are too short-lived to be detected in experiment, while MACs remain stable for long simulation times. Examinations of thermally evolved junctions with and without MACs show negligible overlap between conductance histograms, indicating that the increase in conductance is related to this unique structural change and not thermal fluctuation. These results, which provide an excellent explanation for a recently observed anomalous experimental result [Bruot et al., Nat. Nanotechnol., 2012, 7, 35-40], should aid in the development of mechanically responsive molecular electronic devices. © 2013 The Royal Society of Chemistry.

  3. The thermal conductivity of high modulus Zylon fibers between 400 mK and 4 K

    Science.gov (United States)

    Wikus, Patrick; Figueroa-Feliciano, Enectalí; Hertel, Scott A.; Leman, Steven W.; McCarthy, Kevin A.; Rutherford, John M.

    2008-11-01

    Zylon is a synthetic polyurethane polymer fiber featuring very high mechanical strength. Measurements of the thermal conductivity λZ(T) of high modulus Zylon fibers at temperatures between 400 mK and 4 K were performed to assess if they can be successfully employed in the design of high performance suspension systems for cold stages of adiabatic demagnetization refrigerators. The linear mass density of the yarn used in these measurements amounts to 3270 dtex, which is also a measure for the yarn's cross section. The experimental data for the thermal conductivity was fitted to a function of the form λZ=(1010±30)·TpWmmdtexK. This result was normalized to the breaking strength of the fibers and compared with Kevlar. It shows that Kevlar outperforms Zylon in the investigated temperature range. At 1.5 K, the thermal conductivity integral of Zylon yarn is twice as high as the thermal conductivity integral of Kevlar yarn with the same breaking strength. A linear mass density of 1 tex is equivalent to a yarn mass of 1 g/km. High modulus Zylon has a density of 1.56 g/cm 3.

  4. Irregular Firing and High-Conductance States in Spinal Motoneurons during Scratching and Swimming

    DEFF Research Database (Denmark)

    Guzulaitis, Robertas; Hounsgaard, Jorn; Alaburda, Aidas

    2016-01-01

    UNLABELLED: Intense synaptic transmission during scratch network activity increases conductance and induces irregular firing in spinal motoneurons. It is not known whether this high-conductance state is a select feature for scratching or a property that goes with spinal motor network activity...... in general. Here we compare conductance and firing patterns in spinal motoneurons during network activity for scratching and swimming in an ex vivo carapace-spinal cord preparation from adult turtles (Trachemys scripta elegans). The pattern and relative engagement of motoneurons are distinctly different...... in scratching and swimming. Nevertheless, we found increased synaptic fluctuations in membrane potential, irregular firing, and increased conductance in spinal motoneurons during scratch and swim network activity. Our finding indicates that intense synaptic activation of motoneurons is a general feature...

  5. Numerical investigation of conductive heat transfer in high-porosity foams

    Energy Technology Data Exchange (ETDEWEB)

    Coquard, R., E-mail: remi.coquard@ec2-ms.fr [Societe ' Etude Conseils Calcul en Mecanique des Structures' (EC2MS), 66, boulevard Niels Bohr, 69603 Villeurbanne Cedex (France); Baillis, D. [Centre Thermique de Lyon (CETHIL), UMR CNRS 5008, Domaine Scientifique de la Doua, INSA de Lyon, Batiment Sadi Carnot, 9 rue de la physique, 69621 Villeurbanne Cedex (France)

    2009-10-15

    The conductive heat transfer in heterogeneous cellular materials is generally treated by defining the homogeneous effective thermal conductivity. For high-porosity foams, a very large number of empirical or semi-empirical models have already been proposed to evaluate this conductivity. Each approach considered different cellular morphologies and used different solution methods, leading to noticeable discrepancies. In o