An improved empirical model for diversity gain on Earth-space propagation paths

Science.gov (United States)

Hodge, D. B.

1981-01-01

An empirical model was generated to estimate diversity gain on Earth-space propagation paths as a function of Earth terminal separation distance, link frequency, elevation angle, and angle between the baseline and the path azimuth. The resulting model reproduces the entire experimental data set with an RMS error of 0.73 dB.

Doppler shift simulation of scattered HF signals during the Tromsø HF pumping experiment on 16 February 1996

Directory of Open Access Journals (Sweden)

T. D. Borisova

Full Text Available Comparisons between bistatic scatter measurements and simulation results during the Tromsø HF pumping experiment on 16 February 1996 are made. Doppler measurements of an HF diagnostic signal scattered from the field-aligned irregularities (FAIs in the auroral E-region were carried out on the London – Tromsø – St. Petersburg path at 9410 kHz from 21:00 to 22:00 UT. The scattered signals were observed both from natural and artificial ionospheric irregularities located in the vicinity of Tromsø. To simulate the Doppler frequency shifts, f_d , of scattered signals, a radio channel model, named CONE, was developed. The model allows for ray tracing, group and phase paths, and Doppler frequency shift calculations. The calculated Doppler shifts were analyzed for dependence on the magnitude and direction of plasma velocities in the scattering volume. It was found that the velocity components in the north-south direction are crucial for explaining the Doppler frequency shifts of the scattered diagnostic signals. To simulate f_d , real velocities obtained from the EISCAT UHF radar at an altitude of 278 km and from the digital all-sky imager during the experiment were employed. The simulation results of Doppler frequency shift variations with time are in reasonable agreement with the experimental Doppler shifts of scattered signals on the London – Tromsø – St. Petersburg path.

Key words. Ionosphere (active experiments; ionospheric irregularities Radio science (ionospheric propagation

Space weather effects on radio propagation: study of the CEDAR, GEM and ISTP storm events

Directory of Open Access Journals (Sweden)

D. V. Blagoveshchensky

2008-06-01

Full Text Available The impact of 14 geomagnetic storms from a list of CEDAR, GEM and ISTP storms, that occurred during 1997–1999, on radio propagation conditions has been investigated. The propagation conditions were estimated through variations of the MOF and LOF (the maximum and lowest operation frequencies on three high-latitude HF radio paths in north-west Russia. Geophysical data of Dst, Bz, AE as well as some riometer data from Sodankyla observatory, Finland, were used for the analysis. It was shown that the storm impact on the ionosphere and radio propagation for each storm has an individual character. Nevertheless, there are common patterns in variation of the propagation parameters for all storms. Thus, the frequency range Δ=MOF−LOF increases several hours before a storm, then it narrows sharply during the storm, and expands again several hours after the end of the storm. This regular behaviour should be useful for the HF radio propagation predictions and frequency management at high latitudes. On the trans-auroral radio path, the time interval when the signal is lost through a storm (tdes depends on the local time. For the day-time storms an average value tdes is 6 h, but for night storms tdes is only 2 h. The ionization increase in the F2 layer before storm onset is 3.5 h during the day-time and 2.4 h at night. Mechanisms to explain the observed variations are discussed including some novel possibilities involving energy input through the cusp.

Special Topics in HF Propagation

Science.gov (United States)

1979-11-01

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Impact of the magnetic superstorm on March 17-19, 2015 on subpolar HF radio paths: Experiment and modeling

Science.gov (United States)

Blagoveshchensky, D. V.; Maltseva, O. A.; Anishin, M. M.; Sergeeva, M. A.; Rogov, D. D.

2016-09-01

The ionospheric phenomena which significantly influenced radio propagation during March 17-19, 2015 are considered in the study. The data of oblique ionospheric sounding (OIS) were analyzed at six radio paths. These paths are located in the zone of North Siberia in Russia and have different lengths: from 1000 to 5000 km. The results are the following. The magnetic storm drastically changed the character of radio propagation at all the considered paths: in most cases the reflections from the ionospheric F2-layer were changed by the reflections only from the sporadic Es-layer. The parameters of movement of the disturbance front were estimated on the basis of OIS data of the paths. The average velocity of the front movements from east to west was about V = 440 m/s. Even the moderate growth of riometer absorption within the region of radio paths' locations, resulted in loss of multihop modes in the signal reflections from sporadic layers. It also resulted in a sharp decrease of signal strength at the paths. Real distance-frequency characteristics (DFC) of the paths were compared to DFC calculated on the basis of International Reference Ionosphere (IRI) model. It was revealed that on a quiet day of March, 15th, the real and the calculated DFC are similar or coincide in the majority of cases. During the disturbed days of March, 17-19, most commonly observed are the significant differences between the calculated and the experimental data. The most pronounced difference is revealed while estimating the character of OIS signals' reflections from Es-layers.

Fatigue crack propagation path across the dentinoenamel junction complex in human teeth.

Science.gov (United States)

Dong, X D; Ruse, N D

2003-07-01

The human tooth structures should be understood clearly to improve clinically used restorative materials. The dentinoenamel junction (DEJ) plays a key role in resisting crack propagation in teeth. The aim of this study was to determine the fracture toughness of the enamel-DEJ-dentin complex and to investigate the influence of the DEJ on the fatigue crack propagation path across it by characterizing fatigue-fractured enamel-DEJ-dentin complexes using optical and scanning electron microscopy. The results of this study showed that the fracture toughness of the enamel-DEJ-dentin complex was 1.50 +/- 0.28 Mpa x m(1/2). Based on the results of this investigation, it was concluded that the DEJ complex played a critical role in resisting crack propagation from enamel into dentin. The DEJ complex is, approximately, a 100 to 150 microm broad region at the interface between enamel and dentin. The toughening mechanism of the DEJ complex may be explained by the fact that crack paths were deflected as cracks propagated across it. Understanding the mechanism of crack deflection could help in improving dentin-composite as well as ceramic-cement interfacial qualities with the aim to decrease the risk of clinical failure of restorations. Both can be viewed as being composed from a layer of material of high strength and hardness bonded to a softer but tougher substratum (dentin). The bonding agent or the luting cement layer may play the critical role of the DEJ in improving the strength of these restorations in clinical situations. Copyright 2003 Wiley Periodicals, Inc.

Analysis of Crack Propagation Path on the Anisotropic Bi-Material Rock

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Chao-Shi Chen

2010-01-01

Full Text Available This paper presents a single-domain boundary element method (SDBEM for linear elastic fracture mechanics analysis in the 2D anisotropic bimaterial. In this formulation, the displacement integral equation is collocated on the uncracked boundary only, and the traction integral equation is collocated on one side of the crack surface only. The complete fundamental solution (Green's function for anisotropic bi-materials was also derived and implemented into the boundary integral formulation so the discretization along the interface can be avoided except for the interfacial crack part. A special crack-tip element was introduced to capture exactly the crack-tip behavior. A computer program with the FORTRAN code has been developed to effectively calculate the stress intensity factors, crack initiation angle, and propagation path of an anisotropic bi-material. This SDBEM program has been verified having a good accuracy with the previous researches. In addition, a rock of type (1/(2 disk specimen with a central crack was made to conduct the Brazilian test under diametrical loading. The result shows that the numerical analysis can predict relatively well the direction of crack initiation and the path of crack propagation.

Propagation Path Loss Models for 5G Urban Micro- and Macro-Cellular Scenarios

DEFF Research Database (Denmark)

Sun, Shu; Rappaport, Theodore S.; Rangan, Sundeep

2016-01-01

This paper presents and compares two candidate large-scale propagation path loss models, the alpha-beta-gamma (ABG) model and the close-in (CI) free space reference distance model, for the design of fifth generation (5G) wireless communication systems in urban micro- and macro-cellular scenarios....

Space weather effects on radio propagation: study of the CEDAR, GEM and ISTP storm events

Directory of Open Access Journals (Sweden)

D. V. Blagoveshchensky

2008-06-01

Full Text Available The impact of 14 geomagnetic storms from a list of CEDAR, GEM and ISTP storms, that occurred during 1997–1999, on radio propagation conditions has been investigated. The propagation conditions were estimated through variations of the MOF and LOF (the maximum and lowest operation frequencies on three high-latitude HF radio paths in north-west Russia. Geophysical data of D_st, B_z, AE as well as some riometer data from Sodankyla observatory, Finland, were used for the analysis. It was shown that the storm impact on the ionosphere and radio propagation for each storm has an individual character. Nevertheless, there are common patterns in variation of the propagation parameters for all storms. Thus, the frequency range Δ=MOF−LOF increases several hours before a storm, then it narrows sharply during the storm, and expands again several hours after the end of the storm. This regular behaviour should be useful for the HF radio propagation predictions and frequency management at high latitudes. On the trans-auroral radio path, the time interval when the signal is lost through a storm (t_des depends on the local time. For the day-time storms an average value t_des is 6 h, but for night storms t_des is only 2 h. The ionization increase in the F2 layer before storm onset is 3.5 h during the day-time and 2.4 h at night. Mechanisms to explain the observed variations are discussed including some novel possibilities involving energy input through the cusp.

Determining characteristics of HF communications links using SuperDARN

Directory of Open Access Journals (Sweden)

J. M. Hughes

2002-07-01

Full Text Available Space weather effects can strongly influence high-frequency (HF communications by changing the ionospheric environment through which the radio waves propagate. Since many systems utilize HF communications, the ability to make real-time assessments of propagation conditions is an important part of space weather monitoring systems. In this paper, we present new techniques for measuring high-latitude HF communications link parameters using data from SuperDARN radars. These techniques use ground-scatter returns to define the variation in skip distance with frequency. From these data, the maximum usable frequency (MUF as a function of range is determined and ionospheric critical frequencies are estimated. These calculations are made in near-real-time and the results are made available on the World Wide Web. F-region critical frequencies calculated using this method show good agreement with ionosonde data.Key words. Ionosphere (active experiments; instruments and techniques – Radio science (ionospheric propagation

Determining characteristics of HF communications links using SuperDARN

Directory of Open Access Journals (Sweden)

J. M. Hughes

Full Text Available Space weather effects can strongly influence high-frequency (HF communications by changing the ionospheric environment through which the radio waves propagate. Since many systems utilize HF communications, the ability to make real-time assessments of propagation conditions is an important part of space weather monitoring systems. In this paper, we present new techniques for measuring high-latitude HF communications link parameters using data from SuperDARN radars. These techniques use ground-scatter returns to define the variation in skip distance with frequency. From these data, the maximum usable frequency (MUF as a function of range is determined and ionospheric critical frequencies are estimated. These calculations are made in near-real-time and the results are made available on the World Wide Web. F-region critical frequencies calculated using this method show good agreement with ionosonde data.

Key words. Ionosphere (active experiments; instruments and techniques – Radio science (ionospheric propagation

NEW UPPER AND LOWER BOUNDS LINE OF SIGHT PATH LOSS MODELS FOR MOBILE PROPAGATION IN BUILDINGS

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Supachai Phaiboon

2017-11-01

Full Text Available This paper proposes a method to predict line-of-sight (LOS path loss in buildings. We performed measurements in two different type of buildings at a frequency of 1.8 GHz and propose new upper and lower bounds path loss models which depend on max and min values of sample path loss data. This makes our models limit path loss within the boundary lines. The models include time-variant effects such as people moving and cars in parking areas with their influence on wave propagation that is very high.  The results have shown that the proposed models will be useful for the system and cell design of indoor wireless communication systems.

Optical propagators in vector and spinor theories by path integral formalism

International Nuclear Information System (INIS)

Linares, J.

1993-01-01

The construction of an extended parabolic (wide-angle) vector and spinor wave theory is presented. For that, optical propagators in monochromatic vector light optics and monoenergetic spinor electron optics are evaluated by the path integral formalism. The auxiliary parameter method introduced by Fock and the Feynman-Dyson perturbative series are used. The proposed theory supplies, by a generalized Fermat's principle, the Mukunda-Simon-Sudarshan transformation for the passage from scalar to vector light (or spinor electron) optics in an asymptotic approximation. (author). 19 refs

Ionospheric propagation effects on spectral widths measured by SuperDARN HF radars

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X. Vallières

2004-06-01

Full Text Available SuperDARN HF radars provide a global survey of the large-scale convection transversely to the Earth's magnetic field in the high-latitude ionosphere. In addition to the mean plasma velocity, this network also provides measurements of spectral widths which are related to the level of turbulence of the sounded plasma. There is an increasing interest in using spectral widths in geophysical studies, since they are used to monitor the footprints of several magnetospheric regions. In the present paper, we show the effect of radio wave propagation through a typical turbulent ionosphere on spectral widths measured by SuperDARN radars. This effect has already been evidenced experimentally in a previous paper. Here, we model the effects of meso-scale structures on a radar wave front and study their impact on a typical measurement. Numerical simulations reproduce the effect evidenced experimentally and show the role of meso-scale structures (1-10km in the systematic bias that affects spectral width values. As in experimental data, this effect is shown to be increasing with decreasing radar frequency.

Ionospheric propagation effects on spectral widths measured by SuperDARN HF radars

Directory of Open Access Journals (Sweden)

X. Vallières

2004-06-01

Full Text Available SuperDARN HF radars provide a global survey of the large-scale convection transversely to the Earth's magnetic field in the high-latitude ionosphere. In addition to the mean plasma velocity, this network also provides measurements of spectral widths which are related to the level of turbulence of the sounded plasma. There is an increasing interest in using spectral widths in geophysical studies, since they are used to monitor the footprints of several magnetospheric regions. In the present paper, we show the effect of radio wave propagation through a typical turbulent ionosphere on spectral widths measured by SuperDARN radars. This effect has already been evidenced experimentally in a previous paper. Here, we model the effects of meso-scale structures on a radar wave front and study their impact on a typical measurement. Numerical simulations reproduce the effect evidenced experimentally and show the role of meso-scale structures (1-10km in the systematic bias that affects spectral width values. As in experimental data, this effect is shown to be increasing with decreasing radar frequency.

Coarse-grained representation of the quasi adiabatic propagator path integral for the treatment of non-Markovian long-time bath memory

Science.gov (United States)

Richter, Martin; Fingerhut, Benjamin P.

2017-06-01

The description of non-Markovian effects imposed by low frequency bath modes poses a persistent challenge for path integral based approaches like the iterative quasi-adiabatic propagator path integral (iQUAPI) method. We present a novel approximate method, termed mask assisted coarse graining of influence coefficients (MACGIC)-iQUAPI, that offers appealing computational savings due to substantial reduction of considered path segments for propagation. The method relies on an efficient path segment merging procedure via an intermediate coarse grained representation of Feynman-Vernon influence coefficients that exploits physical properties of system decoherence. The MACGIC-iQUAPI method allows us to access the regime of biological significant long-time bath memory on the order of hundred propagation time steps while retaining convergence to iQUAPI results. Numerical performance is demonstrated for a set of benchmark problems that cover bath assisted long range electron transfer, the transition from coherent to incoherent dynamics in a prototypical molecular dimer and excitation energy transfer in a 24-state model of the Fenna-Matthews-Olson trimer complex where in all cases excellent agreement with numerically exact reference data is obtained.

VLF modal interference distance and nighttime D region VLF reflection height for west-east and east-west propagation paths to Fiji

Science.gov (United States)

Chand, Atishnal Elvin; Kumar, Sushil

2017-08-01

Very low frequency (VLF) signals from navigational transmitters propagate through the Earth-ionosphere waveguide formed by the Earth and the lower conducting ionosphere and show the pronounced minima during solar terminator transition between transmitter and receiver. Pronounced amplitude minima observed on 19.8 kHz (NWC transmitter) and 24.8 kHz (NLK transmitter) signals recorded at Suva (18.149°S, 178.446°E), Fiji, during 2013-2014, have been used to estimate the VLF modal interference distance (DMS) and nighttime D region VLF reflection height (hN). The NWC transmitter signal propagates mostly in west-east direction, and the NLK transmitter follows a transequatorial path propagating significantly in the east-west direction. The values of DMS calculated using midpath terminator speed are 2103 ± 172 km and 2507 ± 373 km for these paths having west-east and east-west components of VLF subionospheric propagation, respectively, which agree with previously published results and within 10% with theoretical values. We have also compared the DMS estimated using a terminator time method with that calculated using terminator speed for a particular day and found both the values to be consistent. The hN values were found to be maximum during winter of Southern Hemisphere for NWC signal and winter of Northern Hemisphere for NLK signal VLF propagation paths to Suva. The hN also shows significant day-to-day and seasonal variabilities with a maximum of about 10 km and 23 km for NWC and NLK signal propagation paths, respectively, which could be due to the atmospheric gravity waves associated with solar terminator transition, as well as meteorological factors such as strong lightnings.

High Frequency Propagation modeling in a disturbed background ionosphere: Results from the Metal Oxide Space Cloud (MOSC) experiment

Science.gov (United States)

Joshi, D. R.; Groves, K. M.

2015-12-01

The Air Force Research Laboratory (AFRL) launched two sounding rockets in the Kwajalein Atoll, Marshall Islands, in May 2013 known as the Metal Oxide Space Cloud (MOSC) experiment to study the interactions of artificial ionization and the background plasma. The rockets released samarium metal vapor in the lower F-region of the ionosphere that ionized forming a plasma cloud. A host of diagnostic instruments were used to probe and characterize the cloud including the ALTAIR incoherent scatter radar, multiple GPS and optical instruments, satellite radio beacons, and a dedicated network of high frequency (HF) radio links. Data from ALTAIR incoherent scatter radar and HF radio links have been analyzed to understand the impacts of the artificial ionization on radio wave propagation. During the first release the ionosphere was disturbed, rising rapidly and spread F formed within minutes after the release. To address the disturbed conditions present during the first release, we have developed a new method of assimilating oblique ionosonde data to generate the background ionosphere that can have numerous applications for HF systems. The link budget analysis of the received signals from the HF transmitters explains the missing low frequencies in the received signals along the great circle path. Observations and modeling confirm that the small amounts of ionized material injected in the lower-F region resulted in significant changes to the natural propagation environment.

Off-great-circle paths in transequatorial propagation: 2. Nonmagnetic-field-aligned reflections

Science.gov (United States)

Tsunoda, Roland T.; Maruyama, Takashi; Tsugawa, Takuya; Yokoyama, Tatsuhiro; Ishii, Mamoru; Nguyen, Trang T.; Ogawa, Tadahiko; Nishioka, Michi

2016-11-01

There is considerable evidence that plasma structure in nighttime equatorial F layer develops from large-scale wave structure (LSWS) in bottomside F layer. However, crucial details of how this process proceeds, from LSWS to equatorial plasma bubbles (EPBs), remain to be sorted out. A major obstacle to success is the paucity of measurements that provide a space-time description of the bottomside F layer over a broad geographical region. The transequatorial propagation (TEP) experiment is one of few methods that can do so. New findings using a TEP experiment, between Shepparton (SHP), Australia, and Oarai (ORI), Japan, are presented in two companion papers. In Paper 1 (P1), (1) off-great-circle (OGC) paths are described in terms of discrete and diffuse types, (2) descriptions of OGC paths are generalized from a single-reflection to a multiple-reflection process, and (3) discrete type is shown to be associated with an unstructured but distorted upwelling, whereas the diffuse type is shown to be associated with EPBs. In Paper 2 (P2), attention is placed on differences in east-west (EW) asymmetry, found between OGC paths from the SHP-ORI experiment and those from another near-identical TEP experiment. Differences are reconciled by allowing three distinct sources for the EW asymmetries: (1) reflection properties within an upwelling (see P1), (2) OGC paths that depend on magnetic declination of geomagnetic field (B), and (3) OGC paths supported by non-B-aligned reflectors at latitudes where inclination of B is finite.

Excitation of Structures Near Railway Tracks-Analysis of the Wave Propagation Path

DEFF Research Database (Denmark)

Bucinskas, Paulius; Andersen, Lars Vabbersgaard

2017-01-01

High-speed rails are an attractive alternative to other forms of intercity transportation. It is a fast, cost-efficient and environmentally friendly solution, which is being developed in various countries across the world. However, in order to be successful, high-speed rails need to transport...... trains. Unfortunately, the prediction of vibrations in nearby structures is difficult, as wave propagation from the vibration source to the structure is a complex phenomenon. The behaviour of the structure is highly dependent on the path along which the vibrations travel between their source...

Application of small-size antennas for estimation of angles of arrival of HF signals scattered by ionospheric irregularities

Science.gov (United States)

Guo, Qiang; Galushko, Volodymyr G.; Zalizovski, Andriy V.; Kashcheyev, Sergiy B.; Zheng, Yu

2018-05-01

A modification of the Doppler Interferometry Technique is suggested to enable estimating angles of arrival of comparatively broadband HF signals scattered by random irregularities of the ionospheric plasma with the use of small-size weakly directional antennas. The technique is based on the measurements of cross-spectra phases of the probe radiation recorded at least in three spatially separated points. The developed algorithm has been used to investigate the angular and frequency-time characteristics of HF signals propagating at frequencies above the maximum usable one (MUF) for the direct radio path Moscow-Kharkiv. The received signal spectra show presence of three families of spatial components attributed, respectively, to scattering by plasma irregularities near the middle point of the radio path, ground backscatter signals and scattering of the sounding signals by the intense plasma turbulence associated with auroral activations. It has been shown that the regions responsible for the formation of the third family components are located well inside the auroral oval. The drift velocity and direction of the auroral ionosphere plasma have been determined. The obtained estimates are consistent with the classical conception of the ionospheric plasma convection at high latitudes and do not contradict the results of investigations of the auroral ionosphere dynamics using the SuperDARN network.

A Development of Common Cause Failure Propagation Paths Identification Method Using Coloured Petri Nets

International Nuclear Information System (INIS)

Yim, Ho Bin; Park, Jae Min; Lee, Chang Gyun; Huh, Jae Young; Lee, Gyu Cheon

2017-01-01

The concept of Common-Cause Failure (CCF) first appeared in the aerospace industry several decades ago, and nuclear power industry actively adopted the concept to the nuclear power plant (NPP) system analysis after the TMI accident. Since digital Instrumentation and Control (I and C) systems were applied to the NPP design, the CCF issues once again drew attention from the nuclear power industry in 90's. Identification of CCF has not been considered as a challenging issue because of its simplicity. However, as the systems become more complex and interconnected, demands are increasing to analyze CCF in more detail, for example, CCF with multiple initiating events or supporting situation awareness of the operation crew. The newly suggested CCF propagation paths identification method, CCF-SIREn, is expected to resolve path identification issue more practically and efficiently. CCF-SIREn uses general diagrams so that the compatibility and usability can be hugely increased. It also offers up-to-date CCF information with a least analysis effort whenever the ordinary NPP design change processes are made. A back-propagation technique is still under development to find out root-causes from the suspiciously responding signals, alarms and components. The probabilistic approach is also under consideration to prioritize defined CCF.

Path Integration on the Upper Half-Plane

OpenAIRE

Reijiro, KUBO; Research Institute for Theoretical Physics Hiroshima University

1987-01-01

Feynman's path integral is considered on the Poincare upper half-plane. It is shown that the fundamental solution to the heat equation ∂f/∂t=Δ_Hf can be expressed in terms of a path integral. A simple relation between the path integral and the Selberg trace formula is discussed briefly.

On the Comparative Performance Analysis of Turbo-Coded Non-Ideal Sigle-Carrier and Multi-Carrier Waveforms over Wideband Vogler-Hoffmeyer HF Channels

Directory of Open Access Journals (Sweden)

F. Genc

2014-09-01

Full Text Available The purpose of this paper is to compare the turbo-coded Orthogonal Frequency Division Multiplexing (OFDM and turbo-coded Single Carrier Frequency Domain Equalization (SC-FDE systems under the effects of Carrier Frequency Offset (CFO, Symbol Timing Offset (STO and phase noise in wide-band Vogler-Hoffmeyer HF channel model. In mobile communication systems multi-path propagation occurs. Therefore channel estimation and equalization is additionally necessary. Furthermore a non-ideal local oscillator generally is misaligned with the operating frequency at the receiver. This causes carrier frequency offset. Hence in coded SC-FDE and coded OFDM systems; a very efficient, low complex frequency domain channel estimation and equalization is implemented in this paper. Also Cyclic Prefix (CP based synchronization synchronizes the clock and carrier frequency offset.The simulations show that non-ideal turbo-coded OFDM has better performance with greater diversity than non-ideal turbo-coded SC-FDE system in HF channel.

Low-Frequency Waves in HF Heating of the Ionosphere

Science.gov (United States)

Sharma, A. S.; Eliasson, B.; Milikh, G. M.; Najmi, A.; Papadopoulos, K.; Shao, X.; Vartanyan, A.

2016-02-01

Ionospheric heating experiments have enabled an exploration of the ionosphere as a large-scale natural laboratory for the study of many plasma processes. These experiments inject high-frequency (HF) radio waves using high-power transmitters and an array of ground- and space-based diagnostics. This chapter discusses the excitation and propagation of low-frequency waves in HF heating of the ionosphere. The theoretical aspects and the associated models and simulations, and the results from experiments, mostly from the HAARP facility, are presented together to provide a comprehensive interpretation of the relevant plasma processes. The chapter presents the plasma model of the ionosphere for describing the physical processes during HF heating, the numerical code, and the simulations of the excitation of low-frequency waves by HF heating. It then gives the simulations of the high-latitude ionosphere and mid-latitude ionosphere. The chapter also briefly discusses the role of kinetic processes associated with wave generation.

Oxygen vacancy effects in HfO2-based resistive switching memory: First principle study

Directory of Open Access Journals (Sweden)

Yuehua Dai

2016-08-01

Full Text Available The work investigated the shape and orientation of oxygen vacancy clusters in HfO2-base resistive random access memory (ReRAM by using the first-principle method based on the density functional theory. Firstly, the formation energy of different local Vo clusters was calculated in four established orientation systems. Then, the optimized orientation and charger conductor shape were identified by comparing the isosurface plots of partial charge density, formation energy, and the highest isosurface value of oxygen vacancy. The calculated results revealed that the [010] orientation was the optimal migration path of Vo, and the shape of system D4 was the best charge conductor in HfO2, which effectively influenced the SET voltage, formation voltage and the ON/OFF ratio of the device. Afterwards, the PDOS of Hf near Vo and total density of states of the system D4_010 were obtained, revealing the composition of charge conductor was oxygen vacancy instead of metal Hf. Furthermore, the migration barriers of the Vo hopping between neighboring unit cells were calculated along four different orientations. The motion was proved along [010] orientation. The optimal circulation path for Vo migration in the HfO2 super-cell was obtained.

Semiclassical propagator of the Wigner function.

Science.gov (United States)

Dittrich, Thomas; Viviescas, Carlos; Sandoval, Luis

2006-02-24

Propagation of the Wigner function is studied on two levels of semiclassical propagation: one based on the Van Vleck propagator, the other on phase-space path integration. Leading quantum corrections to the classical Liouville propagator take the form of a time-dependent quantum spot. Its oscillatory structure depends on whether the underlying classical flow is elliptic or hyperbolic. It can be interpreted as the result of interference of a pair of classical trajectories, indicating how quantum coherences are to be propagated semiclassically in phase space. The phase-space path-integral approach allows for a finer resolution of the quantum spot in terms of Airy functions.

Influence of rotation on multiphoton processes in HF

International Nuclear Information System (INIS)

Broeckhove, J.; Feyen, B.; Van Leuven, P.

1994-01-01

In this contribution, the authors are concerned with the role of rotational motion in multiphoton processes induced by a laser field of high intensity. The authors use the pseudospectral split operator method for the propagation of the quantum wave-function. The rotation is treated by decomposition of the HF wave-function in its angular momentum components

Investigation of Prediction Accuracy, Sensitivity, and Parameter Stability of Large-Scale Propagation Path Loss Models for 5G Wireless Communications

DEFF Research Database (Denmark)

Sun, Shu; Rappaport, Theodore S.; Thomas, Timothy

2016-01-01

This paper compares three candidate large-scale propagation path loss models for use over the entire microwave and millimeter-wave (mmWave) radio spectrum: the alpha–beta–gamma (ABG) model, the close-in (CI) free-space reference distance model, and the CI model with a frequency-weighted path loss...... exponent (CIF). Each of these models has been recently studied for use in standards bodies such as 3rd Generation Partnership Project (3GPP) and for use in the design of fifth generation wireless systems in urban macrocell, urban microcell, and indoor office and shopping mall scenarios. Here, we compare...

Perfectly matched layers for radio wave propagation in inhomogeneous magnetized plasmas

International Nuclear Information System (INIS)

Gondarenko, Natalia A.; Guzdar, Parvez N.; Ossakow, Sidney L.; Bernhardt, Paul A.

2004-01-01

We present 1D and 2D numerical models of the propagation of high-frequency (HF) radio waves in inhomogeneous magnetized plasmas. The simulations allow one to describe the process of linear conversion of HF electromagnetic waves into electrostatic waves. The waves, launched from the lower boundary normally or at a specified angle on a layer of a magnetoactive plasma, can undergo linear conversion of the incident O-mode into a Z-mode at appropriate locations in an inhomogeneous prescribed plasma density. The numerical scheme for solving 2D HF wave propagation equations is described. The model employed the Maxwellian perfectly matched layers (PML) technique for approximating nonreflecting boundary conditions. Our numerical studies demonstrate the effectiveness of the PML technique for transparent boundary conditions for an open-domain problem

Assimilative model for ionospheric dynamics employing delay, Doppler, and direction of arrival measurements from multiple HF channels

Science.gov (United States)

Fridman, Sergey V.; Nickisch, L. J.; Hausman, Mark; Zunich, George

2016-03-01

We describe the development of new HF data assimilation capabilities for our ionospheric inversion algorithm called GPSII (GPS Ionospheric Inversion). Previously existing capabilities of this algorithm included assimilation of GPS total electron content data as well as assimilation of backscatter ionograms. In the present effort we concentrated on developing assimilation tools for data related to HF propagation channels. Measurements of propagation delay, angle of arrival, and the ionosphere-induced Doppler from any number of known propagation links can now be utilized by GPSII. The resulting ionospheric model is consistent with all assimilated measurements. This means that ray tracing simulations of the assimilated propagation links are guaranteed to be in agreement with measured data within the errors of measurement. The key theoretical element for assimilating HF data is the raypath response operator (RPRO) which describes response of raypath parameters to infinitesimal variations of electron density in the ionosphere. We construct the RPRO out of the fundamental solution of linearized ray tracing equations for a dynamic magnetoactive plasma. We demonstrate performance and internal consistency of the algorithm using propagation delay data from multiple oblique ionograms (courtesy of Defence Science and Technology Organisation, Australia) as well as with time series of near-vertical incidence sky wave data (courtesy of the Intelligence Advanced Research Projects Activity HFGeo Program Government team). In all cases GPSII produces electron density distributions which are smooth in space and in time. We simulate the assimilated propagation links by performing ray tracing through GPSII-produced ionosphere and observe that simulated data are indeed in agreement with assimilated measurements.

What can we learn from HF signal scattered from a discrete arc?

Directory of Open Access Journals (Sweden)

E. Séran

2009-05-01

Full Text Available We present observations of a discrete southward propagating arc which appeared in the mid-night sector at latitudes equatorward of main substorm activity. The arc observations were made simultaneously by the ALFA (Auroral Light Fine Analysis optical camera, the SuperDARN-CUTLASS HF radar and the Demeter satellite during a coordinated multi-instrumental campaign conducted at the KEOPS/ESRANGE site in December 2006. The SuperDARN HF signal which is often lost in the regions of strong electron precipitation yields in our case clear backscatter from an isolated arc of weak intensity. Consequently we are able to study arc dynamics, the formation of meso-scale irregularities of the electron density along the arc, compare the arc motion with the convection of surrounding plasma and discuss the contribution of ionospheric ions in the arc erosion and its propagation.

Photon propagation in heterogeneous optical media with spatial correlations: enhanced mean-free-paths and wider-than-exponential free-path distributions

International Nuclear Information System (INIS)

Davis, A.B.; Marshak, Alexander

2004-01-01

Beer's law of exponential decay in direct transmission is well-known but its break-down in spatially variable optical media has been discussed only sporadically in the literature. We document here this break-down in three-dimensional (3D) media with complete generality and explore its ramifications for photon propagation. We show that effective transmission laws and their associated free-path distributions (FPDs) are in fact never exactly exponential in variable media of any kind. Moreover, if spatial correlations in the extinction field extend at least to the scale of the mean-free-path (MFP), FPDs are necessarily wider-than-exponential in the sense that all higher-order moments of the relevant mean-field FPDs exceed those of the exponential FPD, even if it is tuned to yield the proper MFP. The MFP itself is always larger than the inverse of average extinction in a variable medium. In a vast and important class of spatially-correlated random media, the MFP is indeed the average of the inverse of extinction. We translate these theoretical findings into a practical method for deciding a priori when 3D effects become important. Finally, we discuss an obvious but limited analogy between our analysis of spatial variability and the well-known effects of strong spectral variability in gaseous media when observed or modeled at moderate resolution

Paths correlation matrix.

Science.gov (United States)

Qian, Weixian; Zhou, Xiaojun; Lu, Yingcheng; Xu, Jiang

2015-09-15

Both the Jones and Mueller matrices encounter difficulties when physically modeling mixed materials or rough surfaces due to the complexity of light-matter interactions. To address these issues, we derived a matrix called the paths correlation matrix (PCM), which is a probabilistic mixture of Jones matrices of every light propagation path. Because PCM is related to actual light propagation paths, it is well suited for physical modeling. Experiments were performed, and the reflection PCM of a mixture of polypropylene and graphite was measured. The PCM of the mixed sample was accurately decomposed into pure polypropylene's single reflection, pure graphite's single reflection, and depolarization caused by multiple reflections, which is consistent with the theoretical derivation. Reflection parameters of rough surface can be calculated from PCM decomposition, and the results fit well with the theoretical calculations provided by the Fresnel equations. These theoretical and experimental analyses verify that PCM is an efficient way to physically model light-matter interactions.

Nonequilibrium theory of flame propagation

International Nuclear Information System (INIS)

Merzhanov, A.G.

1995-01-01

The nonequilibrium theory of flame propagation is considered as applied to the following three processes of wave propagation: the combustion waves of the second kind, the combustion waves with broad reaction zones, and the combustion waves with chemical stages. Kinetic and combustion wave parameters are presented for different in composition mixtures of boron and transition metals, such as Zr, Hf, Ti, Nb, Ta, Mo, as well as for the Ta-N, Zr-C-H, Nb-B-O systems to illustrate specific features of the above-mentioned processes [ru

Space weather effects on airline communications in the high latitude regions

Science.gov (United States)

Stocker, Alan; Siddle, Dave; Warrington, Mike; Honary, Farideh; Zaalov, Nikolay; Homam, Mariyam; Boteler, David; Danskin, Donald; de Franceschi, Georgiana; Ascaneus, Svend

2013-04-01

In the polar regions, ground-based VHF facilities for air-traffic control are lacking (and non-existent on the Russian side of the pole) and satellite communication systems either not available or expensive to retrofit to current aircraft and hence there remains a need for HF communication systems. Unfortunately, at these latitudes space weather can significantly affect the propagation of HF radio signals and the forecasting techniques currently employed by the airline industry are somewhat crude. In this paper, a new project that aims to provide forecasting of HF propagation characteristics for use by civilian airlines operating over polar routes will be described and preliminary results presented. Previous work in this area [e.g. Stocker et al., 2007] has focussed on taking HF signal measurements (e.g. SNR, delay and Doppler spread, and direction of arrival) on a limited number of propagation paths and developing an ionospheric model that incorporates high latitude features (e.g. polar patches and arcs) which, when combined with raytracing, allows the broad characteristics of the observations to be reproduced [Warrington et al., 2012]. The new project will greatly extend this work and consists of a number of stages. Firstly, HF measurements from an extensive network of purpose built transmitters and receivers spanning the Arctic regions will be collected and analysed. In order to test a wide variety of scenarios, the propagation paths will have different characteristics, e.g. different lengths and covering different parts of the northern ionosphere (i.e. polar cap paths where both terminals are in the polar cap, trans-auroral paths, and sub-auroral paths) and observations will be taken at a range of HF frequencies for a period covering the current (so far weak) solar maximum and part of the declining phase. Simultaneously, high latitude absorption measurements utilising the Global Riometer Array (GLORIA) will be collected and analysed. Next, the observations of

Geometry, Heat Equation and Path Integrals on the Poincare Upper Half-Plane

OpenAIRE

Reijiro, KUBO; Research Institute for Theoretical Physics Hiroshima University

1988-01-01

Geometry, heat equation and Feynman's path integrals are studied on the Poincare upper half-plane. The fundamental solution to the heat equation ∂f/∂t=Δ_Hf is expressed in terms of a path integral defined on the upper half-plane. It is shown that Kac's statement that Feynman's path integral satisfies the Schrodinger equation is also valid for our case.

Propagation Effects in Space/Earth Paths.

Science.gov (United States)

1980-08-01

0 h In both integrals ds is a differential of curved ray path and includes refractive bending. In either integral, the factor aTar is, by the Rayleigh...interference. Ionospheric modification may also result from the emission of exhaust effluents from HLLV’s. The associated changes in ionospherio chemistry can

A representation independent propagator. Pt. 1. Compact Lie groups

International Nuclear Information System (INIS)

Tome, W.A.

1995-01-01

Conventional path integral expressions for propagators are representation dependent. Rather than having to adapt each propagator to the representation in question, it is shown that for compact Lie groups it is possible to introduce a propagator that is representation independent. For a given set of kinematical variables this propagator is a single function independent of any particular choice of fiducial vector, which monetheless, correctly propagates each element of the coherent state representation associated with these kinematical variables. Although the configuration space is in general curved, nevertheless the lattice phase-space path integral for the representation independent propagator has the form appropriate to flat space. To illustrate the general theory a representation independent propagator is explicitly constructed for the Lie group SU(2). (orig.)

Interaction of slow neutrons with the second isomeric level Kπ=16+ of the 178Hf isotope

International Nuclear Information System (INIS)

Pangault, Laurence

1999-01-01

In this work, we study the interaction of low energy neutrons (E≤ 10 eV) with the second isomeric level of 178 Hf (l π =K π =16 + , T 1/2 =31 y) in (n,γ) reactions which proceed through the formation of a compound nucleus. The radiative decay of high K states in 179 Hf is investigated using an isomeric I π =16 + 178 Hf target, 40 ng in weight. The first experiment, performed at the high flux reactor in the Laue Langevin Institute in Grenoble, consisted in γ-ray spectroscopy measurements. For this purpose, an experimental set-up has been built. lt consists of four large Ge detectors shielded against background using a specific F 6 Li collimations ensemble. The second experiments performed at the Fakel (Kurchatov lnstitute, Moscow) and Gelina (IRMM Geel, Belgium) linear accelerators consisted in the investigation of neutron resonances in the 178 Hf m2 (n,γ) reaction using time of flight technique and their γ-decay paths. A high efficiency spectrometer has been built and used for the measurements at bath sites. Two resonances located at 1.82 eV and 0.75 eV have been observed and unambiguously assigned to the (n+ 178 Hf m2 ) compound system. The γ-decay properties of these resonances are very different. Furthermore, the γ-decay path followed by the 0.75 eV resonance is at odd with that expected form statistical model predictions. (author) [fr

Observations by the CUTLASS radar, HF Doppler, oblique ionospheric sounding, and TEC from GPS during a magnetic storm

Directory of Open Access Journals (Sweden)

D. V. Blagoveshchensky

2005-07-01

Full Text Available Multi-diagnostic observations, covering a significant area of northwest Europe, were made during the magnetic storm interval (28–29 April 2001 that occurred during the High Rate SolarMax IGS/GPS-campaign. HF radio observations were made with vertical sounders (St. Petersburg and Sodankyla, oblique incidence sounders (OIS, on paths from Murmansk to St. Petersburg, 1050 km, and Inskip to Leicester, 170 km, Doppler sounders, on paths from Cyprus to St. Petersburg, 2800 km, and Murmansk to St. Petersburg, and a coherent scatter radar (CUTLASS, Hankasalmi, Finland. These, together with total electron content (TEC measurements made at GPS stations from the Euref network in northwest Europe, are presented in this paper. A broad comparison of radio propagation data with ionospheric data at high and mid latitudes, under quiet and disturbed conditions, was undertaken. This analysis, together with a geophysical interpretation, allow us to better understand the nature of the ionospheric processes which occur during geomagnetic storms. The peculiarity of the storm was that it comprised of three individual substorms, the first of which appears to have been triggered by a compression of the magnetosphere. Besides the storm effects, we have also studied substorm effects in the observations separately, providing an improved understanding of the storm/substorm relationship. The main results of the investigations are the following. A narrow trough is formed some 10h after the storm onset in the TEC which is most likely a result of enhanced ionospheric convection. An enhancement in TEC some 2–3 h after the storm onset is most likely a result of heating and upwelling of the auroral ionosphere caused by enhanced currents. The so-called main effect on ionospheric propagation was observed at mid-latitudes during the first two substorms, but only during the first substorm at high latitudes. Ionospheric irregularities observed by CUTLASS were clearly related to the

Spinor and isospinor structure of relativistic particle propagators

International Nuclear Information System (INIS)

Gitman, D.M.; Shvartsman, Sh.M.

1993-07-01

Representations by means of path integrals are used to find spinor and isospinor structure of relativistic particle propagators in external fields. For Dirac propagator in an external electromagnetic field all Grassmannian integrations are performed and a general result is presented via a bosonic path integral. The spinor structure of the integrand is given explicitly by its decomposition in the independent γ-matrix structures. A similar technique is used to get the isospinor structure of the scalar particle propagator in an external non-Abelian field. (author). 21 refs

Path diversity improves the identification of influential spreaders

Science.gov (United States)

Chen, Duan-Bing; Xiao, Rui; Zeng, An; Zhang, Yi-Cheng

2013-12-01

Identifying influential spreaders in complex networks is a crucial problem which relates to wide applications. Many methods based on the global information such as K-shell and PageRank have been applied to rank spreaders. However, most of the related previous works overwhelmingly focus on the number of paths for propagation, while whether the paths are diverse enough is usually overlooked. Generally, the spreading ability of a node might not be strong if its propagation depends on one or two paths while the other paths are dead ends. In this letter, we introduced the concept of path diversity and find that it can largely improve the ranking accuracy. We further propose a local method combining the information of path number and path diversity to identify influential nodes in complex networks. This method is shown to outperform many well-known methods in both undirected and directed networks. Moreover, the efficiency of our method makes it possible to apply it to very large systems.

Insights into the mechanisms on chemical reactions: reaction paths for chemical reactions

International Nuclear Information System (INIS)

Dunning, T.H. Jr.; Rosen, E.; Eades, R.A.

1987-01-01

We report reaction paths for two prototypical chemical reactions: Li + HF, an electron transfer reaction, and OH + H 2 , an abstraction reaction. In the first reaction we consider the connection between the energetic terms in the reaction path Hamiltonian and the electronic changes which occur upon reaction. In the second reaction we consider the treatment of vibrational effects in chemical reactions in the reaction path formalism. 30 refs., 9 figs

Updated climatological model predictions of ionospheric and HF propagation parameters

International Nuclear Information System (INIS)

Reilly, M.H.; Rhoads, F.J.; Goodman, J.M.; Singh, M.

1991-01-01

The prediction performances of several climatological models, including the ionospheric conductivity and electron density model, RADAR C, and Ionospheric Communications Analysis and Predictions Program, are evaluated for different regions and sunspot number inputs. Particular attention is given to the near-real-time (NRT) predictions associated with single-station updates. It is shown that a dramatic improvement can be obtained by using single-station ionospheric data to update the driving parameters for an ionospheric model for NRT predictions of f(0)F2 and other ionospheric and HF circuit parameters. For middle latitudes, the improvement extends out thousands of kilometers from the update point to points of comparable corrected geomagnetic latitude. 10 refs

Analysis of the Effect of Electron Density Perturbations Generated by Gravity Waves on HF Communication Links

Science.gov (United States)

Fagre, M.; Elias, A. G.; Chum, J.; Cabrera, M. A.

2017-12-01

In the present work, ray tracing of high frequency (HF) signals in ionospheric disturbed conditions is analyzed, particularly in the presence of electron density perturbations generated by gravity waves (GWs). The three-dimensional numerical ray tracing code by Jones and Stephenson, based on Hamilton's equations, which is commonly used to study radio propagation through the ionosphere, is used. An electron density perturbation model is implemented to this code based upon the consideration of atmospheric GWs generated at a height of 150 km in the thermosphere and propagating up into the ionosphere. The motion of the neutral gas at these altitudes induces disturbances in the background plasma which affects HF signals propagation. To obtain a realistic model of GWs in order to analyze the propagation and dispersion characteristics, a GW ray tracing method with kinematic viscosity and thermal diffusivity was applied. The IRI-2012, HWM14 and NRLMSISE-00 models were incorporated to assess electron density, wind velocities, neutral temperature and total mass density needed for the ray tracing codes. Preliminary results of gravity wave effects on ground range and reflection height are presented for low-mid latitude ionosphere.

Hf layer thickness dependence of resistive switching characteristics of Ti/Hf/HfO2/Au resistive random access memory device

Science.gov (United States)

Nakajima, Ryo; Azuma, Atsushi; Yoshida, Hayato; Shimizu, Tomohiro; Ito, Takeshi; Shingubara, Shoso

2018-06-01

Resistive random access memory (ReRAM) devices with a HfO2 dielectric layer have been studied extensively owing to the good reproducibility of their SET/RESET switching properties. Furthermore, it was reported that a thin Hf layer next to a HfO2 layer stabilized switching properties because of the oxygen scavenging effect. In this work, we studied the Hf thickness dependence of the resistance switching characteristics of a Ti/Hf/HfO2/Au ReRAM device. It is found that the optimum Hf thickness is approximately 10 nm to obtain good reproducibility of SET/RESET voltages with a small RESET current. However, when the Hf thickness was very small (∼2 nm), the device failed after the first RESET process owing to the very large RESET current. In the case of a very thick Hf layer (∼20 nm), RESET did not occur owing to the formation of a leaky dielectric layer. We observed the occurrence of multiple resistance states in the RESET process of the device with a Hf thickness of 10 nm by increasing the RESET voltage stepwise.

{A Review of Working Group 2 (Advanced Terrestrial Systems) of the COST 296 Action}

Science.gov (United States)

Warrington, E. M.; Tulunay, E.

2009-04-01

E.M. Warrington, E. Tulunay, N.M. Abbasi, J. Azevedo, L. Bertel, A. Bourdillon, E. Benito, C. Bianchi, A. Casimiro, L. Economou, Y. Erhel, S.M. Feeney, S.D. Gunashekar, H. Haralambous, D. Lemur, F. Marie, J.P. Monilie, M. Muriuki, M. Oger M. Pietrella, V. Rannou, H. Rothkaehl, S. Saillant, S. Salous, O. Sari, A.J. Stocker, H.J. Strangeways, Y. Tulunay and N.Y. Zaalov This paper deals with the research undertaken during the COST 296 Action in Working Group 2 on Advanced Terrestrial Systems. The Working Group comprised three work packages covering various topics: Radar and Radiolocation, HF/MF Communications, and Spectrum Management. Results from this Working Group are presented in this paper, and may be summarised as follows. Aspects of HF propagation The propagation characteristics of radio signals are important parameters to consider when designing and operating radio systems. From the point of view Working Group 2 of the COST-296 Action, interest lies with effects associated with propagation via the ionosphere of signals within the HF band. Several aspects were covered: The directions of arrival and times of flight of signals received over a path oriented along the trough have been examined and several types of propagation effects identified. Of particular note, combining the HF observations with satellite measurements has identified the presence of irregularities within the floor of the trough that result in propagation displaced from the great circle direction. An understanding of the propagation effects that result in deviations of the signal path from the great circle direction are of particular relevance to the operation of HF radiolocation systems. Inclusion of the results from the above mentioned measurements into a propagation model of the northerly ionosphere (i.e. those regions of the ionosphere located poleward of, and including, the mid-latitude trough) and the use of this model to predict the coverage expected from transmitters where the signals

Comparison of HfCl4, HfI4, TEMA-Hf, and TDMA-Hf as precursors in early growing stages of HfO2 films deposited by ALD: A DFT study

International Nuclear Information System (INIS)

Cortez-Valadez, M.; Fierro, C.; Farias-Mancilla, J.R.; Vargas-Ortiz, A.; Flores-Acosta, M.; Ramírez-Bon, R.; Enriquez-Carrejo, J.L.

2016-01-01

Highlights: • Hafnium oxide growth on Si(100) by atomic layer deposition was simulated. • The interface structure was considered as silicate and silicide. • The interface was studied employing DFT. • TDMA-Hf precursor show better interface stability. - Abstract: The final structure of HfO 2 films grown by atomic layer deposition (ALD) after reaction with OH − ions has been analyzed by DFT (density functional theory). The interaction of the precursors: HfCl 4 (hafnium tetrachloride), HfI 4 (hafnium tetraiodide), TEMA-Hf (tetrakis-ethylmethylamino hafnium), and TDMA-Hf (tetrakis-dimethylamino hafnium) with HO–H was studied employing the B3LYP (Becke 3-parameter, Lee–Yang–Parr) hybrid functional and the PBE (Perdew–Burke–Ernzerhof) generalized gradient functional. The structural evolution at the Si(100) surface has been analyzed by LDA (local density approximation). The structural parameters: bond length and bond angle, and the vibrational parameters for the optimized structures are also reported. The presence of hafnium silicate at the interface was detected. The infrared spectra and structural parameters obtained in this work agree with previously reported experimental results.

Comparison of HfCl4, HfI4, TEMA-Hf, and TDMA-Hf as precursors in early growing stages of HfO2 films deposited by ALD: A DFT study

Science.gov (United States)

Cortez-Valadez, M.; Fierro, C.; Farias-Mancilla, J. R.; Vargas-Ortiz, A.; Flores-Acosta, M.; Ramírez-Bon, R.; Enriquez-Carrejo, J. L.; Soubervielle-Montalvo, C.; Mani-Gonzalez, P. G.

2016-06-01

The final structure of HfO2 films grown by atomic layer deposition (ALD) after reaction with OH- ions has been analyzed by DFT (density functional theory). The interaction of the precursors: HfCl4 (hafnium tetrachloride), HfI4 (hafnium tetraiodide), TEMA-Hf (tetrakis-ethylmethylamino hafnium), and TDMA-Hf (tetrakis-dimethylamino hafnium) with HO-H was studied employing the B3LYP (Becke 3-parameter, Lee-Yang-Parr) hybrid functional and the PBE (Perdew-Burke-Ernzerhof) generalized gradient functional. The structural evolution at the Si(100) surface has been analyzed by LDA (local density approximation). The structural parameters: bond length and bond angle, and the vibrational parameters for the optimized structures are also reported. The presence of hafnium silicate at the interface was detected. The infrared spectra and structural parameters obtained in this work agree with previously reported experimental results.

Path integration on space times with symmetry

International Nuclear Information System (INIS)

Low, S.G.

1985-01-01

Path integration on space times with symmetry is investigated using a definition of path integration of Gaussian integrators. Gaussian integrators, systematically developed using the theory of projective distributions, may be defined in terms of a Jacobi operator Green function. This definition of the path integral yields a semiclassical expansion of the propagator which is valid on caustics. The semiclassical approximation to the free particle propagator on symmetric and reductive homogeneous spaces is computed in terms of the complete solution of the Jacobi equation. The results are used to test the validity of using the Schwinger-DeWitt transform to compute an approximation to the coincidence limit of a field theory Green function from a WKB propagator. The method is found not to be valid except for certain special cases. These cases include manifolds constructed from the direct product of flat space and group manifolds, on which the free particle WKB approximation is exact and two sphere. The multiple geodesic contribution to 2 > on Schwarzschild in the neighborhood of rho = 3M is computed using the transform

Depolarization on Earth-space paths

Science.gov (United States)

1981-01-01

Sources of depolarization effects on the propagation paths of orthogonally-polarized information channels are considered. The main sources of depolarization at millimeter wave frequencies are hydrometeor absorption and scattering in the troposphere. Terms are defined. Mathematical formulations for the effects of the propagation medium characteristics and antenna performance on signals in dual polarization Earth-space links are presented. Techniques for modeling rain and ice depolarization are discussed.

Crack initiation and propagation paths in small diameter FSW 6082-T6 aluminium tubes under fatigue loading

Directory of Open Access Journals (Sweden)

Roberto Tovo

2016-03-01

Full Text Available This paper reports results of fatigue tests of friction stir welded (FSW aluminium tubes. Relatively small 38 mm diameter tubes were used and hence an automated FSW process using a retracting tool was designed for this project, as the wall thickness of the aluminium tube was similar to the diameter of the FSW tool. This is a more complex joint geometry to weld than the more usual larger diameter tube reported in the literature. S-N fatigue testing was performed using load ratios of R = 0.1 and R = -1. Crack path analysis was performed using both low magnification stereo microscopy and scanning electron microscopy, in order to identify crack initiation sites and to determine the direction of crack propagation. Work is still in progress to follow the crack path through the various microstructural zones associated with the weld. A simple statistical analysis was used to characterize the most typical crack initiation site. This work forms part of a wider project directed at determining multiaxial fatigue design rules for small diameter 6082-T6 aluminium tubes that could be of use in the ground vehicle industry.

Perfect discretization of path integrals

International Nuclear Information System (INIS)

Steinhaus, Sebastian

2012-01-01

In order to obtain a well-defined path integral one often employs discretizations. In the case of General Relativity these generically break diffeomorphism symmetry, which has severe consequences since these symmetries determine the dynamics of the corresponding system. In this article we consider the path integral of reparametrization invariant systems as a toy example and present an improvement procedure for the discretized propagator. Fixed points and convergence of the procedure are discussed. Furthermore we show that a reparametrization invariant path integral implies discretization independence and acts as a projector onto physical states.

Perfect discretization of path integrals

Science.gov (United States)

Steinhaus, Sebastian

2012-05-01

In order to obtain a well-defined path integral one often employs discretizations. In the case of General Relativity these generically break diffeomorphism symmetry, which has severe consequences since these symmetries determine the dynamics of the corresponding system. In this article we consider the path integral of reparametrization invariant systems as a toy example and present an improvement procedure for the discretized propagator. Fixed points and convergence of the procedure are discussed. Furthermore we show that a reparametrization invariant path integral implies discretization independence and acts as a projector onto physical states.

The propagator of quantum gravity in minisuperspace

International Nuclear Information System (INIS)

Louko, J.

1985-04-01

We study the quantum gravitational propagation amplitude between two spacelike three-surfaces in minisuperspaces where the supermomentum constraints are identically satisfied. We derive a well-defined path integral formula for the propagator and show that the propagator is an inverse of the canonical Hamiltonian operator. In an exactly solvable deSitter minisuperspace model the propagator is found to obey semi-classically correct boundary conditions. We discuss the implications for the full theory and suggest an approach to unravelling the physical meaning of the propagator. (orig.)

Bosonic path integral for spin-1/2 particles

International Nuclear Information System (INIS)

Jacobson, T.

1989-01-01

The 3D Dirac propagator is expressed as a path integral over curves of commuting two-component spinors. This is related to the path integral recently employed by Polyakov to demonstrate Fermi-Bose transmutation for solitons in the gauged CP 1 model with Chern-Simons term. Several difficulties concerning the latter path integral are identified and corrected from our point of view. (orig.)

HF i dag

DEFF Research Database (Denmark)

Lindstrøm, Maria Duclos; Simonsen, Birgitte

2008-01-01

Notatet er lavet på baggrund af uddannelsesbiografiske dybdeinterviews med kursister på toårigt HF. Indenfor rammerne af en pilotundersøgelse identificerer notatet fire gennemgående profiler: De pragmatiske, de fagligt usikre, second chance-kursisterne, og de HF-kursister, som har HF som first...

Geospace ionosphere research with a MF/HF radio instrument on a cubesat

Science.gov (United States)

Kallio, E. J.; Aikio, A. T.; Alho, M.; Fontell, M.; van Gijlswijk, R.; Kauristie, K.; Kestilä, A.; Koskimaa, P.; Makela, J. S.; Mäkelä, M.; Turunen, E.; Vanhamäki, H.

2016-12-01

Modern technology provides new possibilities to study geospace and its ionosphere, using spacecraft and and computer simulations. A type of nanosatellites, CubeSats, provide a cost effective possibility to provide in-situ measurements in the ionosphere. Moreover, combined CubeSat observations with ground-based observations gives a new view on auroras and associated electromagnetic phenomena. Especially joint and active CubeSat - ground based observation campaigns enable the possibility of studying the 3D structure of the ionosphere. Furthermore using several CubeSats to form satellite constellations enables much higher temporal resolution. At the same time, increasing computation capacity has made it possible to perform simulations where properties of the ionosphere, such as propagation of the electromagnetic waves in the medium frequency, MF (0.3-3 MHz) and high frequency, HF (3-30 MHz), ranges is based on a 3D ionospheric model and on first-principles modelling. Electromagnetic waves at those frequencies are strongly affected by ionospheric electrons and, consequently, those frequencies can be used for studying the plasma. On the other hand, even if the ionosphere originally enables long-range telecommunication at MF and HF frequencies, the frequent occurrence of spatiotemporal variations in the ionosphere disturbs communication channels, especially at high latitudes. Therefore, study of the MF and HF waves in the ionosphere has both a strong science and technology interests. We present computational simulation results and measuring principles and techniques to investigate the arctic ionosphere by a polar orbiting CubeSat whose novel AM radio instrument measures HF and MF waves. The cubesat, which contains also a white light aurora camera, is planned to be launched in 2017 (http://www.suomi100satelliitti.fi/eng). We have modelled the propagation of the radio waves, both ground generated man-made waves and space formed space weather related waves, through the 3D

Mixed Messages from Garnet Lu-Hf and Sm-Nd Geochronology

Science.gov (United States)

Vervoort, J. D.; Wang, D.; Johnson, T. A.

2017-12-01

Garnet geochronology provides important information on the timing and conditions of metamorphism. As a major indicator mineral formed during metamorphism, its direct dating can not only help establish the timing of metamorphism, provide the "t" for P-T-t paths, but also, if the dated garnet can be placed in a textural context, can provide information on the timing of deformational features. With advances in chemistry and mass spectrometry, garnet Lu-Hf and Sm-Nd geochronology has become an important geochronological tool and we can now reliably (if not routinely) date a wide variety of garnet compositions formed under diverse conditions. In the course of dating a variety of lithologies using both Lu-Hf and Sm-Nd isotope systems, however, some intriguing results have emerged. Although there are many examples where the Lu-Hf and Sm-Nd systems give the same date within uncertainty, there are also many cases where these systems yield significantly different dates, and the differences between these dates can be considerable—many 10's of Ma of and even 100's of Ma. For example, in garnet-bearing Mesoproterozoic gneisses from across the Blue Ridge Province in Virginia, both Lu-Hf and Sm-Nd analyses (determined on the same solutions) define narrow time spans, but with the Sm-Nd dates systematically younger (for orthogneisses Lu-Hf dates are 1032 to 1019 Ma whereas Sm-Nd dates are 965 to 949 Ma—a difference of 67 to 80 Ma). There are many other examples of systematically younger Sm-Nd garnet dates in both the literature and with our ongoing research. Potential explanations for these differences include: 1) strong partitioning of Lu into garnet during growth yielding ages weighted toward the beginning of growth; 2) faster Lu diffusion from high Lu regions after garnet formation, potentially leading to isochron rotation and anomalously old Lu-Hf dates; and 3) differences in closure temperatures of the two isotope systems. We will review several examples of divergent Lu-Hf

Preliminary results from the Arecibo Heating Experiment (HEX): HF to GNSS

Science.gov (United States)

Jackson-Booth, N.; Penney, R.; Bernhardt, P. A.; Martin, P. L.; Buckland, R.; Morton-Orr, T.; Nossa, E.; Buckland, R.

2017-12-01

The ionosphere is subject to many solar and terrestrial influences that can generate disturbances, causing degradation to modern communication and navigational systems. Whilst the disturbances are normally caused by natural phenomena such as hurricanes, earthquakes and solar storms; they can also be generated by artificially modifying the ionosphere. Artificial Ionospheric Modification (AIM) attempts to alter a small region of the ionosphere in order to perturb the RF propagation environment. This can be achieved through injecting the ionosphere with aerosols, chemicals or radio signals. The effects of any such modification can be detected through the deployment of sensors, including ground based high-frequency (HF) sounders and dual-band Global Navigation Satellite System (GNSS) receivers. HF sounders allow measurements of the bottom-side of the ionosphere. GNSS receivers offer a convenient means of obtaining information about the ionosphere, including ionospheric disturbances through changes in the derived total electron content information. The Heating EXperiment (HEX), which took place in March and May 2017, was designed to further our understanding of the phenomena caused by artificially heating a small region of the ionosphere, using the Arecibo facility in Puerto Rico. This was achieved by utilizing a HF measurement experiment spread between Texas and Trinidad and the deployment of a small scale travelling ionospheric disturbance (TID) network near the heater. The TID network comprised three GNSS receivers along baselines of approximately 4 km, located 20 km north of the heater. This paper presents preliminary results from the HEX campaign, including evidence of heating-induced disturbances enhancing propagation between Virginia and Trinidad. The implications of generated irregularities on GNSS will also be discussed.

On the propagation of low-hybrid waves of finite amplitude

International Nuclear Information System (INIS)

Kozyrev, A.N.; Piliya, A.D.; Fedorov, V.I.

1979-01-01

Propagation of low-hybrid waves of a finite amplitude with allowance for variation in plasma density caused by HF field pressure is studied. Considered is wave ''overturning'' which takes place in the absence of space dispersion. With taking account of dispersion the wave propagation is described by the third-order nonlinear equation which differs in shape from the complex modified Korteweg-de-Vries (Hirota) equation. Solutions of this equation of the space solution type are found

Path Loss Analysis of WSN Wave Propagation in Vegetation

International Nuclear Information System (INIS)

Sabri, Naseer; Aljunid, S A; Ahmad, R B; Malek, M F; Salim, M S; Kamaruddin, R

2013-01-01

Deployment of a successful wireless sensor network requires precise prediction models that provide a reliable communication links of wireless nodes. Prediction models fused with foliage models provide sensible parameters of wireless nodes separation distance, antenna height, and power transmission which affect the reliability and communication coverage of a network. This paper review the line of sight and the two ray propagation models combined with the most known foliage models that cover the propagation of wireless communications in vegetative environments, using IEEE 802.15.4 standard. Simulation of models is presented and the impacts of the communication parameters, environment and vegetation have been reported.

Perfect discretization of path integrals

OpenAIRE

Steinhaus, Sebastian

2011-01-01

In order to obtain a well-defined path integral one often employs discretizations. In the case of General Relativity these generically break diffeomorphism symmetry, which has severe consequences since these symmetries determine the dynamics of the corresponding system. In this article we consider the path integral of reparametrization invariant systems as a toy example and present an improvement procedure for the discretized propagator. Fixed points and convergence of the procedure are discu...

Cluster Characteristics in a MIMO Indoor Propagation Environment

DEFF Research Database (Denmark)

Czink, Nicolai; Yin, Xuefeng; Ozcelik, Huseyin

2007-01-01

, strong (obstructed-)line-of-sight clusters show Rician fading, corresponding to few dominant propagation paths, whereas most clusters exhibit Rayleigh fading, corresponding to many paths with approximately equal powers and uncorrelated phases. Root-mean-square cluster azimuth spreads (CASs) were...

Eu-doped ZnO-HfO2 hybrid nanocrystal-embedded low-loss glass-ceramic waveguides

Science.gov (United States)

Ghosh, Subhabrata; N, Shivakiran Bhaktha B.

2016-03-01

We report on the sol-gel fabrication, using a dip-coating technique, of low-loss Eu-doped 70SiO2 -(30-x) HfO2-xZnO (x = 2, 5, 7 and 10 mol%) ternary glass-ceramic planar waveguides. Transmission electron microscopy and grazing incident x-ray diffraction experiments confirm the controlled growth of hybrid nanocrystals with an average size of 3 nm-25 nm, composed of ZnO encapsulated by a thin layer of nanocrystalline HfO2, with an increase of ZnO concentration from x = 2 mol% to 10 mol% in the SiO2-HfO2 composite matrix. The effect of crystallization on the local environment of Eu ions, doped in the ZnO-HfO2 hybrid nanocrystal-embedded glass-ceramic matrix, is studied using photoluminescence spectra, wherein an intense mixed-valence state (divalent as well as trivalent) emission of Eu ions is observed. The existence of Eu2+ and Eu3+ in the SiO2-HfO2-ZnO ternary matrix is confirmed by x-ray photoelectron spectroscopy. Importantly, the Eu{}2+,3+-doped ternary waveguides exhibit low propagation losses (0.3 ± 0.2 dB cm-1 at 632.8 nm) and optical transparency in the visible region of the electromagnetic spectrum, which makes ZnO-HfO2 nanocrystal-embedded SiO2-HfO2-ZnO waveguides a viable candidate for the development of on-chip, active, integrated optical devices.

Comparison of HfCl{sub 4}, HfI{sub 4}, TEMA-Hf, and TDMA-Hf as precursors in early growing stages of HfO{sub 2} films deposited by ALD: A DFT study

Energy Technology Data Exchange (ETDEWEB)

Cortez-Valadez, M. [Departamento de Investigación en Física, Universidad de Sonora, Apdo. Postal 5-88, 83190 Hermosillo, Son. (Mexico); Fierro, C.; Farias-Mancilla, J.R. [Instituto de Ingeniería y Tecnología, Departamento de Física y Matemáticas, Universidad Autónoma de Ciudad Juárez, Av. del Charro 450, Cd. Juárez C.P. 32310, Chihuahua (Mexico); Vargas-Ortiz, A. [Universidad Autónoma de Sinaloa, Facultad de Ingeniería Mochis, Ciudad Universitaria, C.P. 81223 Los Mochis, Sinaloa (Mexico); Flores-Acosta, M. [Departamento de Investigación en Física, Universidad de Sonora, Apdo. Postal 5-88, 83190 Hermosillo, Son. (Mexico); Ramírez-Bon, R. [Centro de Investigación y Estudios Avanzados del IPN, Unidad Querétaro, Apdo. Postal 1-798, 76001 Querétaro, Qro. (Mexico); Enriquez-Carrejo, J.L. [Instituto de Ingeniería y Tecnología, Departamento de Física y Matemáticas, Universidad Autónoma de Ciudad Juárez, Av. del Charro 450, Cd. Juárez C.P. 32310, Chihuahua (Mexico); and others

2016-06-15

Highlights: • Hafnium oxide growth on Si(100) by atomic layer deposition was simulated. • The interface structure was considered as silicate and silicide. • The interface was studied employing DFT. • TDMA-Hf precursor show better interface stability. - Abstract: The final structure of HfO{sub 2} films grown by atomic layer deposition (ALD) after reaction with OH{sup −} ions has been analyzed by DFT (density functional theory). The interaction of the precursors: HfCl{sub 4} (hafnium tetrachloride), HfI{sub 4} (hafnium tetraiodide), TEMA-Hf (tetrakis-ethylmethylamino hafnium), and TDMA-Hf (tetrakis-dimethylamino hafnium) with HO–H was studied employing the B3LYP (Becke 3-parameter, Lee–Yang–Parr) hybrid functional and the PBE (Perdew–Burke–Ernzerhof) generalized gradient functional. The structural evolution at the Si(100) surface has been analyzed by LDA (local density approximation). The structural parameters: bond length and bond angle, and the vibrational parameters for the optimized structures are also reported. The presence of hafnium silicate at the interface was detected. The infrared spectra and structural parameters obtained in this work agree with previously reported experimental results.

Wet etching characteristics of a HfSiON high-k dielectric in HF-based solutions

International Nuclear Information System (INIS)

Li Yongliang; Xu Qiuxia

2010-01-01

The wet etching properties of a HfSiON high-k dielectric in HF-based solutions are investigated. HF-based solutions are the most promising wet chemistries for the removal of HfSiON, and etch selectivity of HF-based solutions can be improved by the addition of an acid and/or an alcohol to the HF solution. Due to densification during annealing, the etch rate of HfSiON annealed at 900 0 C for 30 s is significantly reduced compared with as-deposited HfSiON in HF-based solutions. After the HfSiON film has been completely removed by HF-based solutions, it is not possible to etch the interfacial layer and the etched surface does not have a hydrophobic nature, since N diffuses to the interface layer or Si substrate formation of Si-N bonds that dissolves very slowly in HF-based solutions. Existing Si-N bonds at the interface between the new high-k dielectric deposit and the Si substrate may degrade the carrier mobility due to Coulomb scattering. In addition, we show that N 2 plasma treatment before wet etching is not very effective in increasing the wet etch rate for a thin HfSiON film in our case. (semiconductor technology)

Microhardness evaluation alloys Hf-Si-B; Avaliacao de microdureza de ligas Hf-Si-B

Energy Technology Data Exchange (ETDEWEB)

Gigolotti, Joao Carlos Janio; Costa, Eliane Fernandes Brasil [Centro Universitario de Volta Redonda (UNIFOA), Volta Redonda, RJ (Brazil); Nunes, Carlos Angelo; Rocha, Elisa Gombio; Coelho, Gilberto Carvalho, E-mail: carlosjanio@uol.com.br, E-mail: eliane-costabrasi@hotmail.com, E-mail: cnunes@demar.eel.usp.br, E-mail: elisarocha@alunos.eel.usp.br, E-mail: coelho@demar.eel.usp.br [Universidade de Sao Paulo (USP), Lorena, SP (Brazil)

2014-08-15

The technological advance has generated increasing demand for materials that can be used under high temperature, what includes intermetallic MR-Si-B (MR = refractory metal) alloys with multiphase structures, that can also be applied in oxide environments. Thus, this work had for objective the micro hardness study of the Hf-Si-B system alloys, heat treated at 1600 deg C, in the Hf rich region. Hf-Si-B alloys had been produced with blades of Hf (min. 99.8%), Si (min. 99.998%) and B (min. 99.5%), in the voltaic arc furnace and heat treated at 1600 deg C under argon atmosphere. The relationship of the phases had been previously identified by X-ray diffraction and contrast in backscattered electron imaging mode. The alloys had their hardness analyzed by method Vickers (micro hardness) with load of 0.05 kgf and 0.2 kgf and application time of 20 s. The results, obtained from the arithmetic mean of measurements for each alloy on the heterogeneous region, showed a mean hardness of 11.08 GPA, with small coefficient of variation of 3.8%. The borides HfB2 (19.34 GPa) e HfB - 11.76 GPa, showed the hardness higher than the silicides Hf2Si (8.57 GPa), Hf5Si3 (9.63 GPa), Hf3Si2 (11.66 GPa), Hf5Si4 (10.00 GPa), HfSi (10.02 GPa) e HfSi2 (8.61 GPa). (author)

Path integral discussion for Smorodinsky-Winternitz potentials. Pt. 1

International Nuclear Information System (INIS)

Grosche, C.; Pogosyan, G.S.; Sissakian, A.N.

1994-02-01

Path integral formulations for the Smorodinsky-Winternitz potentials in two- and three-dimensional Euclidean space are presented. We mention all coordinate systems which separate the Smorodinsky-Winternitz potentials and state the corresponding path integral formulations. Whereas in many coordinate systems an explicit path integralformulation is not possible, we list in all soluble cases the path integral evaluations explicity in terms of the propagators and the spectral expansions into the wave-functions. (orig.)

Comparison of UHF measurements with the propagation model of Recommendation ITU-R P.1546

NARCIS (Netherlands)

Witvliet, B.A.; Wijninga, P.W.; van Maanen, E.; Smith, B.

2010-01-01

This report describes a radio propagation measurement campaign that has been performed along paths between the Netherlands and the United Kingdom. The campaign focused on UHF propagation on mixed land/sea paths. Special attention was given to calibration accuracy and validation of the measurement

Evaluation of Acoustic Propagation Paths into the Human Head

National Research Council Canada - National Science Library

O'Brien, William D., Jr; Liu, Yuhui

2005-01-01

The overall goal of this research was to develop an acoustic wave propagation model using well-understood and documented computational techniques that track and quantify an air-borne incident acoustic...

HF/DF chemical labs

International Nuclear Information System (INIS)

Meinzer, R.A.

1987-01-01

This paper provides the essential details to understand and design HF/DF and related types of chemical lasers. The basic operation of the HF/DF chemical laser is described. The details of the excitation chemistry are presented and the pertinent laser physics is described. A description of the various laser components is given and the analytical models for the HF/DF chemical laser are discussed. A brief description of the chain reaction HF/DF chemical laser is offered

Path probabilities of continuous time random walks

International Nuclear Information System (INIS)

Eule, Stephan; Friedrich, Rudolf

2014-01-01

Employing the path integral formulation of a broad class of anomalous diffusion processes, we derive the exact relations for the path probability densities of these processes. In particular, we obtain a closed analytical solution for the path probability distribution of a Continuous Time Random Walk (CTRW) process. This solution is given in terms of its waiting time distribution and short time propagator of the corresponding random walk as a solution of a Dyson equation. Applying our analytical solution we derive generalized Feynman–Kac formulae. (paper)

HF laser

International Nuclear Information System (INIS)

Suzuki, Kazuya; Iwasaki, Matae

1977-01-01

A review is made of the research and development of HF chemical laser and its related work. Many gaseous compounds are used as laser media successfully; reaction kinetics and technological problems are described. The hybrid chemical laser of HF-CO 2 system and the topics related to the isotope separation are also included. (auth.)

Path integral for relativistic particle theory

International Nuclear Information System (INIS)

Fradkin, E.S.; Gitman, D.M.; Shvartsman, Sh.M.

1990-06-01

An action for a relativistic spinning particle interacting with external electromagnetic field is considered in reparametrization and local supergauge invariant form. It is shown that various path integral representations derived for the causal Green function correspond to the different forms of the relativistic particle action. The analogy of the path integral derived with the Lagrangian path integral of the field theory is discussed. It is shown that to obtain the causal propagator, the integration over the null mode of the Lagrangian multiplier corresponding to the reparametrization invariance, has to be performed in the (0,+infinity) limits. (author). 23 refs

Retarded Propagator Representation of Out-of-Equilibrium Thermal Field Theories

International Nuclear Information System (INIS)

Dadic, I.

2009-01-01

We represent out of equilibrium thermal field theories with finite time path in terms of retarded propagators exclusively. For the particle number, defined as the equal time limit of the Keldysh propagator, the time ordering of the diagrams contributing is particularly simple: all external end-points of propagators have maximal time, there are no internal vertices with locally maximal time, the property which guaranties causality), there is, at least one 'sink' vertex (vertex with locally minimal time). The diagram looks like fisher net hanging on external vertices. At the 'sink' vertices energy is not conserved, thus establishing realisation of uncertainty relations in out of equilibrium TFT. Even more, at the equal-time limit, the terms conserving energy at 'sink' vertices vanish. This fact eliminates pinching problem and enables safe time→∞ limit. The retarded propagator in higher orders is regularized only as a part of of the diagram connected to equal time limit of multi point Green function representing expectation value of the product of number operators. These properties indicate clear advantage of finite time path, in large time limit over the use of Keldysh time path.

Impacts of post-metallization annealing on the memory performance of Ti/HfO2-based resistive memory

International Nuclear Information System (INIS)

Chen, Pang-Shiu; Chen, Yu-Sheng; Lee, Heng-Yuan

2013-01-01

Impacts of post-metallization annealing (PMA) on bipolar resistance switching of Ti/HfO x stacked films were investigated. A Ti capping film as a scavenging layer with assistance of PMA is used to tune the dielectric strength of the 10-nm-thick HfO x layer. The polycrystalline microstructure of 10-nm-thick HfO x seems immune to the temperature of PMA in this work. The initial resistance and forming voltage in the Ti/HfO x devices mitigate as the increment of the annealing temperature. With enough annealing temperature (>450 °C), the device shows a good on/off ratio, high temperature operation ability and robust endurance (>10 6 cycles). Through the reaction between Ti and HfO x at 500 °C, the abundant oxygen ions are depleted from the insulator and the left charge-defects building conductive percolative paths in the dielectric layer. The operation-polarity independence of the form-free HfO x device in initial state is demonstrated. The forming-free memory with initial low resistance of 800 Ω at 0.1 V can be operated with stable bipolar resistance switching via initially positive or negative voltage sweep. The formless device with 10 nm thick HfO x also exhibits excellent nonvolatile memory performances, including enough on/off ratio, improved HRS uniformity and good high temperature retention (3 × 10 4 s at 200 °C). The results of this work suggest that the PMA temperature will affect the memory window and cycling reliability of the Ti/HfO x -based resistive memory. Optimum temperature (450 °C) will improve the memory performance of the Ti/HfO x stacked layer. (paper)

SEMICONDUCTOR TECHNOLOGY: Wet etching characteristics of a HfSiON high-k dielectric in HF-based solutions

Science.gov (United States)

Yongliang, Li; Qiuxia, Xu

2010-03-01

The wet etching properties of a HfSiON high-k dielectric in HF-based solutions are investigated. HF-based solutions are the most promising wet chemistries for the removal of HfSiON, and etch selectivity of HF-based solutions can be improved by the addition of an acid and/or an alcohol to the HF solution. Due to densification during annealing, the etch rate of HfSiON annealed at 900 °C for 30 s is significantly reduced compared with as-deposited HfSiON in HF-based solutions. After the HfSiON film has been completely removed by HF-based solutions, it is not possible to etch the interfacial layer and the etched surface does not have a hydrophobic nature, since N diffuses to the interface layer or Si substrate formation of Si-N bonds that dissolves very slowly in HF-based solutions. Existing Si-N bonds at the interface between the new high-k dielectric deposit and the Si substrate may degrade the carrier mobility due to Coulomb scattering. In addition, we show that N2 plasma treatment before wet etching is not very effective in increasing the wet etch rate for a thin HfSiON film in our case.

HF-laser program

International Nuclear Information System (INIS)

Anon.

1978-01-01

Sandia's HF-laser program for FY 77 and FY 78 was revised in June 1977 in order to meet several new program milestones. Research progress is reported on: objective of HF oscillator-amplifier studies using H 2 -F 2 gas mixtures; characteristics of large-volume oscillator using H 2 -F 2 mixtures; characteristics of large-volume amplifier using H 2 -F 2 mixtures; experimental results of the oscillator-amplifier study; objective of high-quality discharge-initiated SF 6 -HI oscillator-preamplifier system; pin-discharge-initiated oscillator and first beam expander; fast-discharge-initiated preamplifiers; reflecting beam expanders for oscillator-preamplifier system; beam quality of discharge-initiated oscillator-preamplifier system; short pulse option for discharge initiated SF 6 -HI system; H 2 -F 2 electron-beam-initiated oscillator-preamplifier system; chamber for HF-laser focusing experiments; computer study of parasitic oscillations in HF amplifiers and oscillators; kinetics upgrade of HF-laser code; repetitivey ignited flowing H 2 -F 2 -O 2 mixtures; spontaneous detonations in multiatmosphere H 2 -F 2 -O 2 mixtures; high-pressure H 2 -F 2 laser studies; and time sequenced energy extraction on the high xenon laser

High-aspect-ratio HfC nanobelts accompanied by HfC nanowires: Synthesis, characterization and field emission properties

Energy Technology Data Exchange (ETDEWEB)

Tian, Song, E-mail: tiansong22@126.com [State Key Laboratory of Solidification Processing, Northwestern Polytechnical University, Xi’an 710072 (China); School of Materials Science and Engineering, Chongqing Jiaotong University, Chongqing 400074 (China); Zhang, Yulei; Ren, Jincui; Qiang, Xinfa; Zhang, Shouyang [State Key Laboratory of Solidification Processing, Northwestern Polytechnical University, Xi’an 710072 (China); Li, Hejun, E-mail: lihejun@nwpu.edu.cn [State Key Laboratory of Solidification Processing, Northwestern Polytechnical University, Xi’an 710072 (China)

2017-04-30

Highlights: • HfC naobelts accompanied by HfC nanowires were synthesized by a catalytic CVD method. • HfC nanobelts as a novel structure of HfC ceramic are reported for the first time. • HfC nanobelts have 100–200 μm in lengths and reach up to 10 μm in widths. • The synthesized product is promising field nanoemitters. - Abstract: As a key refractory carbide, hafnium carbide (HfC) is commonly used as structural materials while the field emission (FE) application of HfC in the field of vacuum microelectronics is almost the only one for functional material purposes. Based on its outstanding physical and chemical characteristics, HfC is identified as a potential candidate with satisfactory mechanical properties and long-term and/or high-temperature FE stability for future applications in high-performance field emitters. However, the development of HfC in various FE applications is hindered because it is not facile to fabricate large-scale low-dimensional HfC field nanoemitters. Herein, High-aspect-ratio HfC nanobelts accompanied by HfC nanowires were synthesized on a large scale by a traditional and simple catalytic chemical vapor deposition (CVD) method. Classical vapor–liquid–solid (VLS) theory was employed to explain the growth of the HfC nanowires and nanobelts along axial direction. The thin HfO{sub 2} shell and thin C layer surrounding the nanostructures might give rise to the diameter fluctuation of HfC nanowires and the width increase of HfC nanobelts in lateral direction. Field emission results show that the high-aspect-ratio HfC nanobelts accompanied by the nanowires are promising field nanoemitters, which exhibit excellent field emission properties with a fairly low turn-on field of ∼1.5 V μm{sup −1} and a low current fluctuation less than ∼10%. This suggests that HfC ceramics with high-aspect-ratio nanostructures are ideal cathode material for various field emission applications.

Determination of the rate of HF hydration and the effects of HF on moisture condensation

International Nuclear Information System (INIS)

McCulla, W.H.

1982-01-01

There were four basic questions addressed in this report that relate to the HF interaction in the environment. As to whether HF hydrates in the vapor phase and what the rate of that hydration is, there seems ample evidence that HF hydrates readily in the vapor phase and the rate of that hydration is very fast, i.e., dHF/dt greater than or equal to 25 torr sec -1 . Concerning under what conditions condensation of the hydrate will occur and whether a third body is required for condensation, it was found that HF does effect the dew point or condensation of water and data was presented indicating the extent of that effect. It was also determined that condensation will occur without a third body present. Thus, in attempting to model an HF release for the Safety Analysis Report the hydration of HF and the subsequent heat released may be treated as occurring instantaneously; but the ultimate disposition of the HF will be strongly dependent upon the environmental conditions at the time of the release

Determination of the rate of HF hydration and the effects of HF on moisture condensation

Energy Technology Data Exchange (ETDEWEB)

McCulla, W H

1982-04-30

There were four basic questions addressed in this report that relate to the HF interaction in the environment. As to whether HF hydrates in the vapor phase and what the rate of that hydration is, there seems ample evidence that HF hydrates readily in the vapor phase and the rate of that hydration is very fast, i.e., dHF/dt greater than or equal to 25 torr sec/sup -1/. Concerning under what conditions condensation of the hydrate will occur and whether a third body is required for condensation, it was found that HF does effect the dew point or condensation of water and data was presented indicating the extent of that effect. It was also determined that condensation will occur without a third body present. Thus, in attempting to model an HF release for the Safety Analysis Report the hydration of HF and the subsequent heat released may be treated as occurring instantaneously; but the ultimate disposition of the HF will be strongly dependent upon the environmental conditions at the time of the release.

High-K rotational bands in {sup 174}Hf and {sup 175}Hf

Energy Technology Data Exchange (ETDEWEB)

Gjoerup, N L; Sletten, G [The Niels Bohr Institute, Roskilbe (Denmark); Walker, P M [Surrey Univ., Guildford (United Kingdom). Dept. of Physics; Bentley, M A [Daresbury Lab. (United Kingdom); Cullen, D M; Sharpey-Schafer, J F; Fallon, P; Smith, G [Liverpool Univ. (United Kingdom). Oliver Lodge Lab.

1992-08-01

High sensitivity experiments with {sup 48}Ca, {sup 18}O and {sup 9}Be induced reactions using the ESSA-30, TESSA-3 and NORDBALL arrays have provided extensive new information on the high spin level structures of {sup 174}Hf and {sup 175}Hf. During the series of experiments, several new bands have been found and most known bands have been extended considerably. Spin and excitation energy ranges for {sup 174}Hf are now {approx} 35 {Dirac_h} and {approx} 13 MeV, respectively, and for {sup 175}Hf ranges are {approx} 30 {Dirac_h} and {approx} 7 MeV. respectively. Several new high-K structures have been found in {sup 174}Hf and the structure of these and the already known high-K bands in both nuclei together with the new Tilted Axis Cranking approach might explain the small K-hindrances observed for K-isomers in this region. (author). 8 refs., 2 figs.

Fire Propagation Tracing Model in the Explicit Treatment of Events of Fire PSA

International Nuclear Information System (INIS)

Lim, Ho Gon; Han, Sang Hoon; Yang, Jun Eon

2010-01-01

The fire propagation model in a fire PSA has not been considered analytically instead a simplified analyst's intuition was used to consider the fire propagation path. A fire propagation equation is developed to trace all the propagation paths in the fire area in which a zone is defined to identify various fire ignition sources. An initiation of fire is assumed to take place in a zone. Then, the propagation is modeled with a Boolean equation. Since the explicit fire PSA modeling requires an exclusive event set to sum up the..., exclusive event sets are derived from the fire propagation equation. As an example, we show the exclusive set for a 2x3 rectangular fire zone. Also, the applicability the developed fire equation is discussed when the number of zone increases including the limitation of the explicit fire PSA modeling method

Beta decomposition processes in Hf-rich Hf--Nb alloys

International Nuclear Information System (INIS)

Jones, W.B.; Taggart, R.; Polonis, D.H.

1978-01-01

The decomposition of the bcc β-phase by both athermal and isothermal processes has been investigated in Hf-rich Hf--Nb alloys. An all β-phase structure is retained in chill-cast alloys containing 30 to 50 at.% Nb (Cb), although electron diffraction streaking effects and the behavior of the temperature coefficient of electrical resistivity indicate the presence of a bcc lattice instability similar to that reported in solute lean Ti and Zr alloys. Aging a Hf 0 . 65 Nb 0 . 35 alloy at 400 and 600 0 C resulted in the direct precipitation of a fine dispersion of α-phase needles; this morphology differs from the discs of transition α (α/sub t/) which Carpenter et al observed in Nb-rich Nb 0 . 68 Hf 0 . 32 . During continued aging, the needles grow selectively to form colonies or groups of needles in which both the individual needles and the groups of needles have major axes aligned along (110)/sub β/ type directions. The initial α-phase particles exhibit the Burgers orientation relationship with the parent matrix; continued aging changes the electron diffraction patterns in a way that is similar to that observed in aged Ti--Mo and Ti--Mo--Al alloys where they were attributed to the α-phase having a different crystallographic relationship to the β-phase (Type 2 α-phase). The observed changes in the electron diffraction patterns of aged Hf 0 . 65 Nb 0 . 35 cannot be described as resulting from strained Burgers α-phase

High resolution TDPAC measurements on 181Ta in Hf2Fe, Hf2Co and Hf2Rh at high temperature

International Nuclear Information System (INIS)

Cekic, B.; Koicki, S.; Ivanovic, N.; Manasijevic, M.; Koteski, V.; Marjanovic, D.

1998-01-01

The time differential perturbed angular correlation measurements (TDPAC-method ) on 181 Ta ion probe in Hf 2 Co, Hf 2 Fe and Hf 2 Rh intermetallic compounds have been performed at 1170 K, using a fast - slow time spectrometer consisting of two BaF 2 detectors. The results of the measurements show the presence of two independent electric quadrupole interactions, compatible with the crystalline structure of these polycrystalline compounds. (authors)

Isothermal cross-sections of Hf-Sc-Ga(800 deg C) and Hf-Ti-Ga (750 deg C) phase diagrams

International Nuclear Information System (INIS)

Markiv, V.Ya.; Belyavina, N.N.

1981-01-01

Isothermal cross sections of Hf-Sc-Ga (800 deg C) and Hf-Ti-Ga (750 deg C) state diagrams are plotted. The existence of two ternary Hfsub(0.1-0.8)Scsub(0.9)-sub(0.2)Ga and Hfsub(0.8)Scsub(0.2)Gasub(3) phases is stated in the Hf-Sc-Ga system. The crystal structure of these compounds investigated by the powder method belongs to the structural α-MoB and ZrAl 3 types respectively. Continuous rows of (Hf, Sc 5 Ga 5 , (Hf, Ti)Ga 3 and (Hf, Ti)Ga 2 solid solutions are formed in the investigated systems. Essential quantity of the third component dissolve binary Sc 5 Ga 4 , Sc 2 Ga 3 (15 and 30 at % Hf respectively), Hf 5 Ga 4 , HfGa 2 (20, 10 at. % Sc), Hf 5 Ga 4 , HfGa, Hf 5 Ga 3 , Hf 2 Ga 3 (48, 30, 46, 20 at. % Ti) gallides [ru

High-temperature x-ray diffraction study of HfTiO4-HfO2 solid solutions

International Nuclear Information System (INIS)

Carpenter, D.A.

1975-01-01

High-temperature x-ray diffraction techniques were used to determine the axial thermal expansion curves of HfTiO 4 -HfO 2 solid solutions as a function of composition. Data show increasing anisotropy with increasing HfO 2 content. An orthorhombic-to-monoclinic phase transformation was detected near room temperature for compositions near the high HfO 2 end of the orthorhombic phase field and for compositions within the two-phase region (HfTiO 4 solid solution plus HfO 2 solid solution). An orthorhombic-to-cubic phase transformation is indicated by data from oxygen-deficient materials at greater than 1873 0 K. (U.S.)

Correlated calculations of indirect nuclear spin-spin coupling constants using second-order polarization propagator approximations: SOPPA and SOPPA(CCSD)

DEFF Research Database (Denmark)

Enevoldsen, Thomas; Oddershede, Jens; Sauer, Stephan P. A.

1998-01-01

We present correlated calculations of the indirect nuclear spin-spin coupling constants of HD, HF, H2O, CH4, C2H2, BH, AlH, CO and N2 at the level of the second-order polarization propagator approximation (SOPPA) and the second-order polarization propagator approximation with coupled-cluster sing...

A path flux analysis method for the reduction of detailed chemical kinetic mechanisms

Energy Technology Data Exchange (ETDEWEB)

Sun, Wenting; Ju, Yiguang [Department of Mechanical and Aerospace Engineering, Princeton University, Princeton, NJ 08544 (United States); Chen, Zheng [State Key Laboratory for Turbulence and Complex Systems, College of Engineering, Peking University, Beijing 100871 (China); Gou, Xiaolong [School of Power Engineering, Chongqing University, Chongqing 400044 (China)

2010-07-15

A direct path flux analysis (PFA) method for kinetic mechanism reduction is proposed and validated by using high temperature ignition, perfect stirred reactors, and steady and unsteady flame propagations of n-heptane and n-decane/air mixtures. The formation and consumption fluxes of each species at multiple reaction path generations are analyzed and used to identify the important reaction pathways and the associated species. The formation and consumption path fluxes used in this method retain flux conservation information and are used to define the path indexes for the first and the second generation reaction paths related to a targeted species. Based on the indexes of each reaction path for the first and second generations, different sized reduced chemical mechanisms which contain different number of species are generated. The reduced mechanisms of n-heptane and n-decane obtained by using the present method are compared to those generated by the direct relation graph (DRG) method. The reaction path analysis for n-decane is conducted to demonstrate the validity of the present method. The comparisons of the ignition delay times, flame propagation speeds, flame structures, and unsteady spherical flame propagation processes showed that with either the same or significantly less number of species, the reduced mechanisms generated by the present PFA are more accurate than that of DRG in a broad range of initial pressures and temperatures. The method is also integrated with the dynamic multi-timescale method and a further increase of computation efficiency is achieved. (author)

Semiclassical propagation of Wigner functions.

Science.gov (United States)

Dittrich, T; Gómez, E A; Pachón, L A

2010-06-07

We present a comprehensive study of semiclassical phase-space propagation in the Wigner representation, emphasizing numerical applications, in particular as an initial-value representation. Two semiclassical approximation schemes are discussed. The propagator of the Wigner function based on van Vleck's approximation replaces the Liouville propagator by a quantum spot with an oscillatory pattern reflecting the interference between pairs of classical trajectories. Employing phase-space path integration instead, caustics in the quantum spot are resolved in terms of Airy functions. We apply both to two benchmark models of nonlinear molecular potentials, the Morse oscillator and the quartic double well, to test them in standard tasks such as computing autocorrelation functions and propagating coherent states. The performance of semiclassical Wigner propagation is very good even in the presence of marked quantum effects, e.g., in coherent tunneling and in propagating Schrodinger cat states, and of classical chaos in four-dimensional phase space. We suggest options for an effective numerical implementation of our method and for integrating it in Monte-Carlo-Metropolis algorithms suitable for high-dimensional systems.

Lifetime and Path Length of the Virtual Particle

International Nuclear Information System (INIS)

Lyuboshitz, V.L.; Lyuboshitz, V.V.

2005-01-01

The concepts of the lifetime and path length of a virtual particle are introduced. It is shown that, near the mass surface of the real particle, these quantities constitute a 4-vector. At very high energies, the virtual particle can propagate over considerable (even macroscopic) distances. The formulas for the lifetime and path length of an ultrarelativistic virtual electron in the process of bremsstrahlung in the Coulomb field of a nucleus are obtained. The lifetime and path length of the virtual photon at its conversion into an electron-positron pair are discussed. The connection between the path length of the virtual particle and the coherence length (formation length) is analyzed

Self-diffusion of Er and Hf inpure and HfO2-doped polycrystalline Er2O3

International Nuclear Information System (INIS)

Scheidecker, R.W.

1979-01-01

Using a tracer technique, self-diffusion of Er and Hf was measured over the approximate temperature interval of 1600 to 1970 0 C in pure and HfO 2 -doped polycryatalline Er 2 O 3 . Up to about 10 m/o HfO 2 dopant level, the Er self-diffusion coefficients followed a relationship based on cation vacancies. Above 10 m/o HfO 2 , deviation from this relationship occurred, apparently due to clustering of cation vacancies and oxygen interstitials around the dopant hafnia ion. The activation energy for the self-diffusion of Er in pure Er 2 O 3 was 82.2 Kcal/mole and increased with the HfO 2 dopant level present. Self-diffusion of Hf was measured in pure Er 2 O 3 having two impurity levels, and a separation of the grain boundary. The volume diffusion of Hf showed both extrinsic and intrinsic behavior with the transition temperature increasing with the impurity level present in Er 2 O 3 . The activation energy for Hf volume diffusion in the intrinsic region was high, i.e. 235 -+ 9.5 Kcal/mole. The grain boundary diffusion was apparently extrinsic over the entire temperature interval Very low Hf self diffusion rates were found in both pure and HfO 2 doped Er 2 O 3 compositions. Despite a clustering effect, the HfO 2 dopant increased the Hf volume diffusion coefficients

Propagator of a time-dependent unbound quadratic Hamiltonian system

International Nuclear Information System (INIS)

Yeon, K.H.; Kim, H.J.; Um, C.I.; George, T.F.; Pandey, L.N.

1996-01-01

The propagator for a time-dependent unbound quadratic Hamiltonian system is explicitly evaluated using the path integral method. Two time-invariant quantities of the system are found where these invariants determine whether or not the system is bound. Several examples are considered to illustrate that the propagator obtained for the unbound systems is correct

Propagation Analysis for Wireless Sensor Networks Applied to Viticulture

Directory of Open Access Journals (Sweden)

Felipe Pinheiro Correia

2017-01-01

Full Text Available Wireless sensor networks have been proposed as a solution to obtain soil and environment information in large distributed areas. The main economic activity of the São Francisco Valley region in the Northeast of Brazil is the irrigated fruit production. The region is one of the major agricultural regions of the country. Grape plantations receive large investments and provide good financial return. However, the region still lacks electronic sensing systems to extract adequate information from plantations. Considering these facts, this paper presents a study of path loss in grape plantations for a 2.4 GHz operating frequency. In order to determine the position of the sensor nodes, the research dealt with various environmental factors that influence the intensity of the received signal. It has been noticed that main plantation aisles favor the guided propagation, and the vegetation along the secondary plantation aisles compromises the propagation. Diffraction over the grape trees is the main propagation mechanism in the diagonal propagation path. Transmission carried out above the vineyard showed that reflection on the top of the trees is the main mechanism.

Numerical simulation of the temperature, electron density, and electric field distributions near the ionospheric reflection height after turn-on of a powerful HF wave

International Nuclear Information System (INIS)

Muldrew, D.B.

1986-01-01

The time variation of the electron temperature profile in the ionosphere following turn-on of a powerful 1-s HF pulse is determined numerically from the energy balance equation. Using this and the equations of motion and continuity for a plasma, the effect of heating and the pondermotive force of a powerful HF wave on the electron density and electric field distributions are determined by numerical simulation. The temperature variation and ponderomotive force modify the density distribution, and this new density distribution, in turn, modifies the electric field distribution of the HF wave. The density deviations grow for a few hundred milliseconds after HF turn-on and then begin to fluctuate in time. At all heights the wave number of the density deviations is approximately twice the wave number of the HF wave. For electric fields near reflection of about 6.0 V/m, the electric field distribution becomes complicated, apparently depending on Bragg scattering of the HF wave from the density deviations. Density impulses propagate away (up and down) from electric field maxima, at the ion thermal velocity, at both turn-on and turn-off of the HF wave

Spin factor and spinor structure of Dirac propagator in constant field

Energy Technology Data Exchange (ETDEWEB)

Gitman, D.M.; Cruz, W. da [Sao Paulo Univ., SP (Brazil). Inst. de Fisica; Zlatev, S.I. [Sergipe Univ., Aracaju, SE (Brazil). Dept. de Fisica

1996-06-01

We use bosonic path integral representation of Dirac propagator with a spin factor to calculate the propagator in a constant uniform electromagnetic field. Such a way of calculation allows us to get the explicit spinor structure of the propagator in the case under consideration. The representation obtained differs from the Schwinger`s one but the equivalence can be checked. (author). 21 refs.

Spin factor and spinor structure of Dirac propagator in constant field

International Nuclear Information System (INIS)

Gitman, D.M.; Cruz, W. da; Zlatev, S.I.

1996-01-01

We use bosonic path integral representation of Dirac propagator with a spin factor to calculate the propagator in a constant uniform electromagnetic field. Such a way of calculation allows us to get the explicit spinor structure of the propagator in the case under consideration. The representation obtained differs from the Schwinger's one but the equivalence can be checked. (author). 21 refs

Direct Position Determination of Unknown Signals in the Presence of Multipath Propagation

Directory of Open Access Journals (Sweden)

Jianping Du

2018-03-01

Full Text Available A novel geolocation architecture, termed “Multiple Transponders and Multiple Receivers for Multiple Emitters Positioning System (MTRE” is proposed in this paper. Existing Direct Position Determination (DPD methods take advantage of a rather simple channel assumption (line of sight channels with complex path attenuations and a simplified MUltiple SIgnal Classification (MUSIC algorithm cost function to avoid the high dimension searching. We point out that the simplified assumption and cost function reduce the positioning accuracy because of the singularity of the array manifold in a multi-path environment. We present a DPD model for unknown signals in the presence of Multi-path Propagation (MP-DPD in this paper. MP-DPD adds non-negative real path attenuation constraints to avoid the mistake caused by the singularity of the array manifold. The Multi-path Propagation MUSIC (MP-MUSIC method and the Active Set Algorithm (ASA are designed to reduce the dimension of searching. A Multi-path Propagation Maximum Likelihood (MP-ML method is proposed in addition to overcome the limitation of MP-MUSIC in the sense of a time-sensitive application. An iterative algorithm and an approach of initial value setting are given to make the MP-ML time consumption acceptable. Numerical results validate the performances improvement of MP-MUSIC and MP-ML. A closed form of the Cramér–Rao Lower Bound (CRLB is derived as a benchmark to evaluate the performances of MP-MUSIC and MP-ML.

Direct Position Determination of Unknown Signals in the Presence of Multipath Propagation.

Science.gov (United States)

Du, Jianping; Wang, Ding; Yu, Wanting; Yu, Hongyi

2018-03-17

A novel geolocation architecture, termed "Multiple Transponders and Multiple Receivers for Multiple Emitters Positioning System (MTRE)" is proposed in this paper. Existing Direct Position Determination (DPD) methods take advantage of a rather simple channel assumption (line of sight channels with complex path attenuations) and a simplified MUltiple SIgnal Classification (MUSIC) algorithm cost function to avoid the high dimension searching. We point out that the simplified assumption and cost function reduce the positioning accuracy because of the singularity of the array manifold in a multi-path environment. We present a DPD model for unknown signals in the presence of Multi-path Propagation (MP-DPD) in this paper. MP-DPD adds non-negative real path attenuation constraints to avoid the mistake caused by the singularity of the array manifold. The Multi-path Propagation MUSIC (MP-MUSIC) method and the Active Set Algorithm (ASA) are designed to reduce the dimension of searching. A Multi-path Propagation Maximum Likelihood (MP-ML) method is proposed in addition to overcome the limitation of MP-MUSIC in the sense of a time-sensitive application. An iterative algorithm and an approach of initial value setting are given to make the MP-ML time consumption acceptable. Numerical results validate the performances improvement of MP-MUSIC and MP-ML. A closed form of the Cramér-Rao Lower Bound (CRLB) is derived as a benchmark to evaluate the performances of MP-MUSIC and MP-ML.

Direct Position Determination of Unknown Signals in the Presence of Multipath Propagation

Science.gov (United States)

Yu, Hongyi

2018-01-01

A novel geolocation architecture, termed “Multiple Transponders and Multiple Receivers for Multiple Emitters Positioning System (MTRE)” is proposed in this paper. Existing Direct Position Determination (DPD) methods take advantage of a rather simple channel assumption (line of sight channels with complex path attenuations) and a simplified MUltiple SIgnal Classification (MUSIC) algorithm cost function to avoid the high dimension searching. We point out that the simplified assumption and cost function reduce the positioning accuracy because of the singularity of the array manifold in a multi-path environment. We present a DPD model for unknown signals in the presence of Multi-path Propagation (MP-DPD) in this paper. MP-DPD adds non-negative real path attenuation constraints to avoid the mistake caused by the singularity of the array manifold. The Multi-path Propagation MUSIC (MP-MUSIC) method and the Active Set Algorithm (ASA) are designed to reduce the dimension of searching. A Multi-path Propagation Maximum Likelihood (MP-ML) method is proposed in addition to overcome the limitation of MP-MUSIC in the sense of a time-sensitive application. An iterative algorithm and an approach of initial value setting are given to make the MP-ML time consumption acceptable. Numerical results validate the performances improvement of MP-MUSIC and MP-ML. A closed form of the Cramér–Rao Lower Bound (CRLB) is derived as a benchmark to evaluate the performances of MP-MUSIC and MP-ML. PMID:29562601

Modified multiblock partial least squares path modeling algorithm with backpropagation neural networks approach

Science.gov (United States)

Yuniarto, Budi; Kurniawan, Robert

2017-03-01

PLS Path Modeling (PLS-PM) is different from covariance based SEM, where PLS-PM use an approach based on variance or component, therefore, PLS-PM is also known as a component based SEM. Multiblock Partial Least Squares (MBPLS) is a method in PLS regression which can be used in PLS Path Modeling which known as Multiblock PLS Path Modeling (MBPLS-PM). This method uses an iterative procedure in its algorithm. This research aims to modify MBPLS-PM with Back Propagation Neural Network approach. The result is MBPLS-PM algorithm can be modified using the Back Propagation Neural Network approach to replace the iterative process in backward and forward step to get the matrix t and the matrix u in the algorithm. By modifying the MBPLS-PM algorithm using Back Propagation Neural Network approach, the model parameters obtained are relatively not significantly different compared to model parameters obtained by original MBPLS-PM algorithm.

Study on the impact of sudden stratosphere warming in the upper mesosphere-lower thermosphere regions using satellite and HF radar - [Article

CSIR Research Space (South Africa)

Mbatha, N

2010-01-01

Full Text Available . The mean zonal wind (from SANAE HF radar) at the MLT shows reversal in approximately 7 days before the reversal at 10 hPa (from NCEP). This indicates that there was a downwards propagation of circulation disturbance. Westerly zonal winds dominate the winter...

Reconciliation of the excess 176Hf conundrum in meteorites: Recent disturbances of the Lu-Hf and Sm-Nd isotope systematics

Science.gov (United States)

Bast, Rebecca; Scherer, Erik E.; Sprung, Peter; Mezger, Klaus; Fischer-Gödde, Mario; Taetz, Stephan; Böhnke, Mischa; Schmid-Beurmann, Hinrich; Münker, Carsten; Kleine, Thorsten; Srinivasan, Gopalan

2017-09-01

The long-lived 176Lu-176Hf and 147Sm-143Nd radioisotope systems are commonly used chronometers, but when applied to meteorites, they can reveal disturbances. Specifically, Lu-Hf isochrons commonly yield dates up to ∼300 Myr older than the solar system and varying initial 176Hf/177Hf values. We investigated this problem by attempting to construct mineral and whole rock isochrons for eucrites and angrites. Meteorites from different parent bodies exhibit similar disturbance features suggesting that a common process is responsible. Minerals scatter away from isochron regressions for both meteorite classes, with low-Hf phases such as plagioclase and olivine typically being most displaced above (or left of) reference isochrons. Relatively Hf-rich pyroxene is less disturbed but still to the point of steepening Lu-Hf errorchrons. Using our Lu-Hf and Sm-Nd data, we tested various Hf and Lu redistribution scenarios and found that decoupling of Lu/Hf from 176Hf/177Hf must postdate the accumulation of significant radiogenic 176Hf. Therefore early irradiation or diffusion cannot explain the excess 176Hf. Instead, disturbed meteorite isochrons are more likely caused by terrestrial weathering, contamination, or common laboratory procedures. The partial dissolution of phosphate minerals may predominantly remove rare earth elements including Lu, leaving relatively immobile and radiogenic Hf behind. Robust Lu-Hf (and improved Sm-Nd) meteorite geochronology will require the development of chemical or physical methods for removing unsupported radiogenic Hf and silicate-hosted terrestrial contaminants without disturbing parent-daughter ratios.

Clinical trials update from the Heart Failure Society of America Meeting 2009: FAST, IMPROVE-HF, COACH galectin-3 substudy, HF-ACTION nuclear substudy, DAD-HF, and MARVEL-1.

Science.gov (United States)

Lainscak, Mitja; Coletta, Alison P; Sherwi, Nasser; Cleland, John G F

2010-02-01

This article presents findings and a commentary on late-breaking trials presented during the meeting of the Heart Failure Society of America in September 2009. Unpublished reports should be considered as preliminary, since analyses may change in the final publication. The FAST trial showed somewhat better performance of intrathoracic impedance for prediction of deterioration in patients with heart failure (HF) when compared with daily weighing. The IMPROVE-HF study reported the benefits of education on the management of patients with systolic HF. Galectin-3 appeared a useful method for improving risk stratification of patients with chronic HF in a substudy of the COACH trial. A nuclear substudy of the HF-ACTION trial failed to demonstrate that resting myocardial perfusion imaging, a measure of myocardial scar and viability, was clinically useful. A small randomized controlled trial (DAD-HF) suggested that the use of low-dose dopamine in patients with acutely decompensated HF was associated with less deterioration in renal function and less hypokalaemia. The MARVEL-1 trial raises further concerns about the safety of myoblast transplantation in ischaemic HF.

Path integral quantization in the temporal gauge

International Nuclear Information System (INIS)

Scholz, B.; Steiner, F.

1983-06-01

The quantization of non-Abelian gauge theories in the temporal gauge is studied within Feynman's path integral approach. The standard asymptotic boundary conditions are only imposed on the transverse gauge fields. The fictituous longitudinal gauge quanta are eliminated asymptotically by modified boundary conditions. This abolishes the residual time-independent gauge transformations and leads to a unique fixing of the temporal gauge. The resulting path integral for the generating functional respects automatically Gauss's law. The correct gauge field propagator is derived. It does not suffer from gauge singularities at n x k = 0 present in the usual treatment of axial gauges. The standard principal value prescription does not work. As a check, the Wilson loop in temporal gauge is calculated with the new propagator. To second order (and to all orders in the Abelian case) the result agrees with the one obtained in the Feynman and Coulomb gauge. (orig.)

Ab initio theoretical study of dipole-bound anions of molecular complexes: (HF)3- and (HF)4- anions

Science.gov (United States)

Ramaekers, Riet; Smith, Dayle M. A.; Smets, Johan; Adamowicz, Ludwik

1997-12-01

Ab initio calculations have been performed to determine structures and vertical electron detachment energy (VDE) of the hydrogen fluoride trimer and tetramer anions, (HF)3- and (HF)4-. In these systems the excess electron is bound by the dipole field of the complex. It was determined that, unlike the neutral complexes which prefer the cyclic structures, the equilibrium geometries of the anions have "zig-zag" shapes. For both complexes the predicted VDEs are positive [210 meV and 363 meV for (HF)3- and (HF)4-, respectively], indicating that the anions are stable systems with respect to the vertical electron detachment. These results were obtained at the coupled-cluster level of theory with single, double and triple excitations [CCSD(T) method; the triple-excitation contribution in this method is calculated approximately using the perturbation approach] with the anion geometries obtained using the second-order Møller-Plesset perturbation theory (MP2) method. The same approach was also used to determine the adiabatic electron affinities (AEA) of (HF)3 and (HF)4. In addition to the electronic contribution, we also calculated the contributions (using the harmonic approximation) resulting from different zero-point vibration energies of the neutral and anionic clusters. The calculations predicted that while the AEA of (HF)3 is positive (44 meV), the AEA for (HF)4 is marginally negative (-16 meV). This suggests that the (HF)3- anion should be a stable system, while the (HF)4- is probably metastable.

Ionosphere research with a HF/MF cubesat radio instrument

Science.gov (United States)

Kallio, Esa; Aikio, Anita; Alho, Markku; Fontell, Mathias; Harri, Ari-Matti; Kauristie, Kirsti; Kestilä, Antti; Koskimaa, Petri; Mäkelä, Jakke; Mäkelä, Miika; Turunen, Esa; Vanhamäki, Heikki; Verronen, Pekka

2017-04-01

New technology provides new possibilities to study geospace and 3D ionosphere by using spacecraft and computer simulations. A type of nanosatellites, CubeSats, provide a cost effective possibility to provide in-situ measurements in the ionosphere. Moreover, combined CubeSat observations with ground-based observations gives a new view on auroras and associated electromagnetic phenomena. Especially joint and active CubeSat - ground based observation campaigns enable the possibility of studying the 3D structure of the ionosphere. Furthermore using several CubeSats to form satellite constellations enables much higher temporal resolution. At the same time, increasing computation capacity has made it possible to perform simulations where properties of the ionosphere, such as propagation of the electromagnetic waves in the medium frequency, MF (0.3-3 MHz) and high frequency, HF (3-30 MHz), ranges is based on a 3D ionospheric model and on first-principles modelling. Electromagnetic waves at those frequencies are strongly affected by ionospheric electrons and, consequently, those frequencies can be used for studying the plasma. On the other hand, even if the ionosphere originally enables long-range telecommunication at MF and HF frequencies, the frequent occurrence of spatiotemporal variations in the ionosphere disturbs communication channels, especially at high latitudes. Therefore, study of the MF and HF waves in the ionosphere has both a strong science and technology interests. We introduce recently developed simulation models as well as measuring principles and techniques to investigate the arctic ionosphere by a polar orbiting CubeSat whose novel AM radio instrument measures HF and MF waves. The cubesat, which contains also a white light aurora camera, is planned to be launched in late 2017 (http://www.suomi100satelliitti.fi/eng). The new models are (1) a 3D ray tracing model and (2) a 3D full kinetic electromagnetic simulation. We also introduce how combining of the

Feynman path integral application on deriving black-scholes diffusion equation for european option pricing

International Nuclear Information System (INIS)

Utama, Briandhika; Purqon, Acep

2016-01-01

Path Integral is a method to transform a function from its initial condition to final condition through multiplying its initial condition with the transition probability function, known as propagator. At the early development, several studies focused to apply this method for solving problems only in Quantum Mechanics. Nevertheless, Path Integral could also apply to other subjects with some modifications in the propagator function. In this study, we investigate the application of Path Integral method in financial derivatives, stock options. Black-Scholes Model (Nobel 1997) was a beginning anchor in Option Pricing study. Though this model did not successfully predict option price perfectly, especially because its sensitivity for the major changing on market, Black-Scholes Model still is a legitimate equation in pricing an option. The derivation of Black-Scholes has a high difficulty level because it is a stochastic partial differential equation. Black-Scholes equation has a similar principle with Path Integral, where in Black-Scholes the share's initial price is transformed to its final price. The Black-Scholes propagator function then derived by introducing a modified Lagrange based on Black-Scholes equation. Furthermore, we study the correlation between path integral analytical solution and Monte-Carlo numeric solution to find the similarity between this two methods. (paper)

Wavefront Propagation and Fuzzy Based Autonomous Navigation

Directory of Open Access Journals (Sweden)

Adel Al-Jumaily

2005-06-01

Full Text Available Path planning and obstacle avoidance are the two major issues in any navigation system. Wavefront propagation algorithm, as a good path planner, can be used to determine an optimal path. Obstacle avoidance can be achieved using possibility theory. Combining these two functions enable a robot to autonomously navigate to its destination. This paper presents the approach and results in implementing an autonomous navigation system for an indoor mobile robot. The system developed is based on a laser sensor used to retrieve data to update a two dimensional world model of therobot environment. Waypoints in the path are incorporated into the obstacle avoidance. Features such as ageing of objects and smooth motion planning are implemented to enhance efficiency and also to cater for dynamic environments.

Prediction of three-dimensional crack propagation paths taking high cycle fatigue into account

Directory of Open Access Journals (Sweden)

Guido Dhondt

2016-01-01

Full Text Available Engine components are usually subject to complex loading patterns such as mixed-mode Low Cycle Fatigue Loading due to maneuvering. In practice, this LCF Loading has to be superimposed by High Cyclic Fatigue Loading caused by vibrations. The changes brought along by HCF are twofold: first, the vibrational cycles which are superposed on the LCF mission increase the maximum loading of the mission and may alter the principal stress planes. Secondly, the HCF cycles themselves have to be evaluated on their own, assuring that no crack propagation occurs. Indeed, the vibrational frequency is usually so high that propagation leads to immediate failure. In the present paper it is explained how these two effects can be taken care of in a standard LCF crack propagation procedure. The method is illustrated by applying the Finite Element based crack propagation software CRACKTRACER3D on an engine blade.

MO-HF-C alloy composition

International Nuclear Information System (INIS)

Whelan, E.P.; Kalns, E.

1987-01-01

This patent describes, as an article of manufacture, a cast ingot of a molybdenum-hafnium-carbon alloy consisting essentially by weight of about 0.6% to about 1% Hf, about 0.045% to about 0.08% C, and the balance essentially molybdenum. The amount of Hf and C present are substantially stoichiometric with respect to HfC and within about +-15% of stoichiometry. The ingot is characterized in that it has a substantially less tendency to crack compared to alloys containing Hf in excess of about 1% by weight and carbon in excess of 0.08% by weight, without substantial diminution in strength properties of the alloy

On the path integral representation of the Wigner function and the Barker–Murray ansatz

International Nuclear Information System (INIS)

Sels, Dries; Brosens, Fons; Magnus, Wim

2012-01-01

The propagator of the Wigner function is constructed from the Wigner–Liouville equation as a phase space path integral over a new effective Lagrangian. In contrast to a paper by Barker and Murray (1983) , we show that the path integral can in general not be written as a linear superposition of classical phase space trajectories over a family of non-local forces. Instead, we adopt a saddle point expansion to show that the semiclassical Wigner function is a linear superposition of classical solutions for a different set of non-local time dependent forces. As shown by a simple example the specific form of the path integral makes the formulation ideal for Monte Carlo simulation. -- Highlights: ► We derive the quantum mechanical propagator of the Wigner function in the path integral representation. ► We show that the Barker–Murray ansatz is incomplete, explain the error and provide an alternative. ► An example of a Monte Carlo simulation of the semiclassical path integral is included.

Perfect discretization of reparametrization invariant path integrals

International Nuclear Information System (INIS)

Bahr, Benjamin; Dittrich, Bianca; Steinhaus, Sebastian

2011-01-01

To obtain a well-defined path integral one often employs discretizations. In the case of gravity and reparametrization-invariant systems, the latter of which we consider here as a toy example, discretizations generically break diffeomorphism and reparametrization symmetry, respectively. This has severe implications, as these symmetries determine the dynamics of the corresponding system. Indeed we will show that a discretized path integral with reparametrization-invariance is necessarily also discretization independent and therefore uniquely determined by the corresponding continuum quantum mechanical propagator. We use this insight to develop an iterative method for constructing such a discretized path integral, akin to a Wilsonian RG flow. This allows us to address the problem of discretization ambiguities and of an anomaly-free path integral measure for such systems. The latter is needed to obtain a path integral, that can act as a projector onto the physical states, satisfying the quantum constraints. We will comment on implications for discrete quantum gravity models, such as spin foams.

Perfect discretization of reparametrization invariant path integrals

Science.gov (United States)

Bahr, Benjamin; Dittrich, Bianca; Steinhaus, Sebastian

2011-05-01

To obtain a well-defined path integral one often employs discretizations. In the case of gravity and reparametrization-invariant systems, the latter of which we consider here as a toy example, discretizations generically break diffeomorphism and reparametrization symmetry, respectively. This has severe implications, as these symmetries determine the dynamics of the corresponding system. Indeed we will show that a discretized path integral with reparametrization-invariance is necessarily also discretization independent and therefore uniquely determined by the corresponding continuum quantum mechanical propagator. We use this insight to develop an iterative method for constructing such a discretized path integral, akin to a Wilsonian RG flow. This allows us to address the problem of discretization ambiguities and of an anomaly-free path integral measure for such systems. The latter is needed to obtain a path integral, that can act as a projector onto the physical states, satisfying the quantum constraints. We will comment on implications for discrete quantum gravity models, such as spin foams.

Formation and disruption of conductive filaments in a HfO2/TiN structure

International Nuclear Information System (INIS)

Brivio, S; Tallarida, G; Cianci, E; Spiga, S

2014-01-01

The process of the formation and disruption of nanometric conductive filaments in a HfO 2 /TiN structure is investigated by conductive atomic force microscopy. The preforming state evidences nonhomogeneous conduction at high fields through conductive paths, which are associated with pre-existing defects and develop into conductive filaments with a forming procedure. The disruption of the same filaments is demonstrated as well, according to a bipolar operation. In addition, the conductive tip of the microscopy is exploited to perform electrical operations on single conductive spots, which evidences that neighboring conductive filaments are not electrically independent. We propose a picture that describes the evolution of the shape of the conductive filaments in the processes of their formation and disruption, which involves the development of conductive branches from a common root; this root resides in the pre-existing defects that lay at the HfO 2 /TiN interface. (paper)

Gauge-invariant approach and infrared behaviour of the spinor propagator

International Nuclear Information System (INIS)

Sisakyan, A.N.; Skachkov, N.B.; Solovtsov, I.L.; Shevchenko, O.Yu.

1989-01-01

Infrared behaviour of the gauge-invariant spinor propagator is studied. It is proved that infrared peculiarities of such a propagator can be factorized in a form of the Wilson loop that includes only the slowly varying component of electromagnetic field and accumulates all the dependence of the initial Green function of the form of the path

The rotational excitation of HF by H

Science.gov (United States)

Desrousseaux, Benjamin; Lique, François

2018-06-01

The HF molecule is a key tracer of molecular hydrogen in diffuse interstellar medium (ISM). Accurate modelling of the HF abundance in such media requires one to model its excitation by both radiation and collisions. In diffuse ISM, the dominant collisional partners are atomic and molecular hydrogen. We report quantum time-independent calculations of collisional cross-sections and rate coefficients for the rotational excitation of HF by H. The reactive hydrogen exchange channels are taken into account in the scattering calculations. For the first time, HF-H rate coefficients are provided for temperature ranging from 10 to 500 K. The strongest collision-induced rotational HF transitions are those with Δj = 1, and the order of magnitude of the new HF-H rate coefficients is similar to that of the HF-H2 ones previously computed. As a first application, we simulate the excitation of HF by both H and H2 in typical diffuse ISM. We show that, depending on the rotational transition, hydrogen atoms increase or decrease the simulated excitation temperatures compared to collisional excitation only due to H2 molecules. Such results suggest that the new HF-H collisional data have to be used for properly modelling the abundance of HF in diffuse ISM.

Simultaneous analysis of rotational and vibrational-rotational spectra of DF and HF to obtain irreducible molecular constants for HF

International Nuclear Information System (INIS)

Horiai, Koui; Uehara, Hiromichi

2011-01-01

Graphical abstract: Available rotational and vibrational-rotational spectral lines of DF and HF are analyzed simultaneously using a non-Born-Oppenheimer effective Hamiltonian. Research highlights: → Simultaneous analysis of DF and HF spectral data. → Application of a non-Born-Oppenheimer effective Hamiltonian. → Twenty irreducible molecular constants for HF have been determined. - Abstract: Analytic expressions of corrections for the breakdown of the Born-Oppenheimer approximation to Dunham's Y ij with optimal parameters, i.e., determinable clusters of expansion coefficients, are applied to a data analysis of the rotational and vibrational-rotational transitions of HF reported in the literature. All the available spectral lines of the two isotopologues, DF and HF, are simultaneously fitted to a single set of molecular parameters of HF within experimental errors. Fitting of a data set of 595 spectral transitions for DF and HF has generated only 20 minimal independent parameter values, i.e., 'irreducible' molecular constants of HF, that are sufficient to precisely generate 82 Y ij coefficients and 144 band constants in total: 41 Y ij and 72 band constants each for DF and HF.

Fluid-driven fracture propagation in heterogeneous media: Probability distributions of fracture trajectories.

Science.gov (United States)

Santillán, David; Mosquera, Juan-Carlos; Cueto-Felgueroso, Luis

2017-11-01

Hydraulic fracture trajectories in rocks and other materials are highly affected by spatial heterogeneity in their mechanical properties. Understanding the complexity and structure of fluid-driven fractures and their deviation from the predictions of homogenized theories is a practical problem in engineering and geoscience. We conduct a Monte Carlo simulation study to characterize the influence of heterogeneous mechanical properties on the trajectories of hydraulic fractures propagating in elastic media. We generate a large number of random fields of mechanical properties and simulate pressure-driven fracture propagation using a phase-field model. We model the mechanical response of the material as that of an elastic isotropic material with heterogeneous Young modulus and Griffith energy release rate, assuming that fractures propagate in the toughness-dominated regime. Our study shows that the variance and the spatial covariance of the mechanical properties are controlling factors in the tortuousness of the fracture paths. We characterize the deviation of fracture paths from the homogenous case statistically, and conclude that the maximum deviation grows linearly with the distance from the injection point. Additionally, fracture path deviations seem to be normally distributed, suggesting that fracture propagation in the toughness-dominated regime may be described as a random walk.

Magma paths at Piton de la Fournaise Volcano

OpenAIRE

Michon , Laurent; Ferrazzini , Valérie; Di Muro , Andrea

2016-01-01

International audience; Several patterns of magma paths have been proposed since the 1980s for Piton de la Fournaise volcano. Given the significant differences, which are presented here, we propose a reappraisal of the magma intrusion paths using a 17-years-long database of volcano-tectonic seismic events and a detailed mapping of the scoria cones. At the edifice scale, the magma propagates along two N120 trending rift zones. They are wide, linear, spotted by small to large scoria cones and r...

Within-Site Variation in Feather Stable Hydrogen Isotope (δ2Hf) Values of Boreal Songbirds: Implications for Assignment to Molt Origin.

Science.gov (United States)

Nordell, Cameron J; Haché, Samuel; Bayne, Erin M; Sólymos, Péter; Foster, Kenneth R; Godwin, Christine M; Krikun, Richard; Pyle, Peter; Hobson, Keith A

2016-01-01

Understanding bird migration and dispersal is important to inform full life-cycle conservation planning. Stable hydrogen isotope ratios from feathers (δ2Hf) can be linked to amount-weighted long-term, growing season precipitation δ2H (δ2Hp) surfaces to create δ2Hf isoscapes for assignment to molt origin. However, transfer functions linking δ2Hp with δ2Hf are influenced by physiological and environmental processes. A better understanding of the causes and consequences of variation in δ2Hf values among individuals and species will improve the predictive ability of geographic assignment tests. We tested for effects of species, land cover, forage substrate, nest substrate, diet composition, body mass, sex, and phylogenetic relatedness on δ2Hf from individuals at least two years old of 21 songbird species captured during the same breeding season at a site in northeastern Alberta, Canada. For four species, we also tested for a year × species interaction effect on δ2Hf. A model including species as single predictor received the most support (AIC weight = 0.74) in explaining variation in δ2Hf. A species-specific variance parameter was part of all best-ranked models, suggesting variation in δ2Hf was not consistent among species. The second best-ranked model included a forage substrate × diet interaction term (AIC weight = 0.16). There was a significant year × species interaction effect on δ2Hf suggesting that interspecific differences in δ2Hf can differ among years. Our results suggest that within- and among-year interspecific variation in δ2Hf is the most important source of variance typically not being explicitly quantified in geographic assignment tests using non-specific transfer functions to convert δ2Hp into δ2Hf. However, this source of variation is consistent with the range of variation from the transfer functions most commonly being propagated in assignment tests of geographic origins for passerines breeding in North America.

A model expansion criterion for treating surface topography in ray path calculations using the eikonal equation

International Nuclear Information System (INIS)

Ma, Ting; Zhang, Zhongjie

2014-01-01

Irregular surface topography has revolutionized how seismic traveltime is calculated and the data are processed. There are two main schemes for dealing with an irregular surface in the seismic first-arrival traveltime calculation: (1) expanding the model and (2) flattening the surface irregularities. In the first scheme, a notional infill medium is added above the surface to expand the physical space into a regular space, as required by the eikonal equation solver. Here, we evaluate the chosen propagation velocity in the infill medium through ray path tracking with the eikonal equation-solved traveltime field, and observe that the ray paths will be physically unrealistic for some values of this propagation velocity. The choice of a suitable propagation velocity in the infill medium is crucial for seismic processing of irregular topography. Our model expansion criterion for dealing with surface topography in the calculation of traveltime and ray paths using the eikonal equation highlights the importance of both the propagation velocity of the infill physical medium and the topography gradient. (paper)

Development of HF-systems for electron storage systems

International Nuclear Information System (INIS)

Androsov, V.P.; Karnaukhov, I.M.; Popkov, Yu.P.; Reva, S.N.; Telegin, Yu.N.

1999-01-01

Development of HF systems for electron storages is described. Its final task is construction of 100 kW HF station at 699,3 MHz frequency consisting from low-power HF system, klystron amplifier, wave line for HF power transmission and accelerating section. Functional parameters of HF station are given

The path integral formulation of fractional Brownian motion for the general Hurst exponent

International Nuclear Information System (INIS)

Calvo, I; Sanchez, R

2008-01-01

In 1995, Sebastian (1995 J. Phys. A: Math. Gen. 28 4305) gave a path integral computation of the propagator of subdiffusive fractional Brownian motion (fBm), i.e. fBm with a Hurst or self-similarity exponent H element of (0, 1/2). The extension of Sebastian's calculation to superdiffusion, H element of (1/2, 1], becomes however quite involved due to the appearance of additional boundary conditions on fractional derivatives of the path. In this communication, we address the construction of the path integral representation in a different fashion, which allows us to treat both subdiffusion and superdiffusion on an equal footing. The derivation of the propagator of fBm for the general Hurst exponent is then performed in a neat and unified way. (fast track communication)

Coulomb-nuclear interference measurements of 168Yb, 176Hf, 178Hf, and 180Hf and lifetime measurements in 186Hg

International Nuclear Information System (INIS)

Nettles, W.G.

1979-01-01

Alpha scattering measurements were performed at center-of-mass energies near the Coulomb barrier. These energies allow for nuclear as well as pure Coulomb forces to play a significant role in the excitation process. The interference of these two forces is very sensitive to the sign of the E4 ground-state moment, whereas pure Coulomb excitation is not. Systematics of the E4 moments of the rare earth mass region indicate a transition in the magnitude and sign of the reduced matrix element of the M(E4) operator between 0 + and 4 + states from small and positive to large and negative between Yb and W. Previous Coulomb-nuclear interference measurements show that this reduced matrix element for 180 Hf is large and negative. The present results agree with that conclusion. It is also shown that the above reduced matrix element for 178 Hf, like that of 180 Hf, is large and negative. The small and positive moment (matrix element) for 168 Yb is seen to be consistent with the experimental data. No conclusions are drawn for the E4 moment in 176 Hf. The measurement of nuclear lifetimes shorter than 500 ps requires the use of plastic scintilltor detectors. These detectors, however have very poor energy resolution. A system is described that uses plastic scintillators with a magnetic lens spectrometer for energy selection. The system was used to measure the lifetime of the 522-keV 0 + sate in 186 Hf. A data analysis method using higher-order distribution moments is also presented

comparative analysis of path loss prediction models for urban

African Journals Online (AJOL)

the acceptable minimum MSE value of 6dB for good signal propagation. Keywords: macrocellular areas ... itate high-speed data communications in ad- dition to voice calls. ... On the basis of the mobile radio environment, path loss predic-.

Stellar Neutron Capture Cross Sections of the Lu and Hf Isotopes

International Nuclear Information System (INIS)

Wisshak, K.; Voss, F.; Kaeppeler, F.; Kazakov, L.; Krticka, M.

2005-01-01

The neutron capture cross sections of 175,176Lu and 176,177,178,179,180Hf have been measured in the energy range from 3 to 225 keV at the Karlsruhe 3.7 MV Van de Graaff accelerator relative to the gold standard. Neutrons were produced by the 7Li(p,n)7Be reaction and capture events were detected by the Karlsruhe 4πBaF2 detector. The cross section ratios could be determined with uncertainties between 0.9 and 1.8% about a factor of five more accurate than previous data. A strong population of isomeric states was found in neutron capture of the Hf isotopes, which are only partially explained by CASINO/GEANT simulations based on the known level schemes.Maxwellian averaged neutron capture cross sections were calculated for thermal energies between kT = 8 keV and 100 keV. Severe differences up to40% were found to the data of a recent evaluation based on existing experimental results. The new data allow for a much more reliable analysis of the important branching in the s-process synthesis path at 176Lu which can be interpreted as an s-process thermometer

Effect of structural evolution of ZnO/HfO2 nanocrystals on Eu2+/Eu3+ emission in glass-ceramic waveguides for photonic applications.

Science.gov (United States)

Ghosh, Subhabrata; Bhaktha B N, Shivakiran

2018-06-01

Eu-doped 70SiO 2 -23HfO 2 -7ZnO (mol%) glass-ceramic waveguides have been fabricated by sol-gel method as a function of heat-treatment temperatures for on-chip blue-light emitting source applications. Structural evolution of spherical ZnO and spherical as well as rod-like HfO 2 nanocrystalline structures have been observed with heat-treatments at different temperatures. Initially, in the as-prepared samples at 900 ◦ C, both, Eu 2+ as well as Eu 3+ ions are found to be present in the ternary matrix. With controlled heat-treatments of up to 1000 ◦ C for 2 h, local environment of Eu-ions become more crystalline in nature and the reduction of Eu 3+ to Eu 2+ takes place in such ZnO/HfO 2 crystalline environments. In these ternary glass-ceramic waveguides, heat-treated at higher temperatures, the blue-light emission characteristic, which is the signature of 4f 6 5d [Formula: see text] 4f 7 energy level transition of Eu 2+ ions is found to be greatly enhanced. The as-prepared glass-ceramic waveguides exhibit a propagation loss of 0.4 ± 0.2 dB cm -1 at 632.8 nm. Though the propagation losses increase with the growth of nanocrystals, the added functionalities achieved in the optimally heat-treated Eu-doped 70SiO 2 -23HfO 2 -7ZnO (mol%) waveguides, make them a viable functional optical material for the fabrication of on-chip blue-light emitting sources for integrated optic applications.

Effect of structural evolution of ZnO/HfO2 nanocrystals on Eu2+/Eu3+ emission in glass-ceramic waveguides for photonic applications

Science.gov (United States)

Ghosh, Subhabrata; N, Shivakiran Bhaktha B.

2018-06-01

Eu-doped 70SiO2–23HfO2–7ZnO (mol%) glass-ceramic waveguides have been fabricated by sol-gel method as a function of heat-treatment temperatures for on-chip blue-light emitting source applications. Structural evolution of spherical ZnO and spherical as well as rod-like HfO2 nanocrystalline structures have been observed with heat-treatments at different temperatures. Initially, in the as-prepared samples at 900 ◦C, both, Eu2+ as well as Eu3+ ions are found to be present in the ternary matrix. With controlled heat-treatments of up to 1000 ◦C for 2 h, local environment of Eu-ions become more crystalline in nature and the reduction of Eu3+ to Eu2+ takes place in such ZnO/HfO2 crystalline environments. In these ternary glass-ceramic waveguides, heat-treated at higher temperatures, the blue-light emission characteristic, which is the signature of 4f 65d \\to 4f 7 energy level transition of Eu2+ ions is found to be greatly enhanced. The as-prepared glass-ceramic waveguides exhibit a propagation loss of 0.4 ± 0.2 dB cm‑1 at 632.8 nm. Though the propagation losses increase with the growth of nanocrystals, the added functionalities achieved in the optimally heat-treated Eu-doped 70SiO2–23HfO2–7ZnO (mol%) waveguides, make them a viable functional optical material for the fabrication of on-chip blue-light emitting sources for integrated optic applications.

A semi-empirical analysis of strong-motion peaks in terms of seismic source, propagation path, and local site conditions

Science.gov (United States)

Kamiyama, M.; Orourke, M. J.; Flores-Berrones, R.

1992-09-01

A new type of semi-empirical expression for scaling strong-motion peaks in terms of seismic source, propagation path, and local site conditions is derived. Peak acceleration, peak velocity, and peak displacement are analyzed in a similar fashion because they are interrelated. However, emphasis is placed on the peak velocity which is a key ground motion parameter for lifeline earthquake engineering studies. With the help of seismic source theories, the semi-empirical model is derived using strong motions obtained in Japan. In the derivation, statistical considerations are used in the selection of the model itself and the model parameters. Earthquake magnitude M and hypocentral distance r are selected as independent variables and the dummy variables are introduced to identify the amplification factor due to individual local site conditions. The resulting semi-empirical expressions for the peak acceleration, velocity, and displacement are then compared with strong-motion data observed during three earthquakes in the U.S. and Mexico.

Teleconnection Paths via Climate Network Direct Link Detection.

Science.gov (United States)

Zhou, Dong; Gozolchiani, Avi; Ashkenazy, Yosef; Havlin, Shlomo

2015-12-31

Teleconnections describe remote connections (typically thousands of kilometers) of the climate system. These are of great importance in climate dynamics as they reflect the transportation of energy and climate change on global scales (like the El Niño phenomenon). Yet, the path of influence propagation between such remote regions, and weighting associated with different paths, are only partially known. Here we propose a systematic climate network approach to find and quantify the optimal paths between remotely distant interacting locations. Specifically, we separate the correlations between two grid points into direct and indirect components, where the optimal path is found based on a minimal total cost function of the direct links. We demonstrate our method using near surface air temperature reanalysis data, on identifying cross-latitude teleconnections and their corresponding optimal paths. The proposed method may be used to quantify and improve our understanding regarding the emergence of climate patterns on global scales.

Hf på VUC

DEFF Research Database (Denmark)

Pless, Mette; Hansen, Niels-Henrik Møller

. Konkret har forskningsprojektet 3 mål: At afdække hf-kursisternes tidligere uddannelsesforløb og -erfaringer, før de starter på hf på VUC.At afdække, hvordan mødet med uddannelsens studiemiljø opleves af kursisterne, og ikke mindst kursisternes oplevelse af undervisningsformer, lærere mm.At afdække, hvad...

Faraday tarotion: new parameter for electromagnetic pulse propagation in magnetoplasma

International Nuclear Information System (INIS)

Bloch, S.C.; Lyons, P.W.

1976-01-01

Extreme distortion and time-dependent Faraday rotation occur for propagation of short electromagnetic pulses in magnetoplasma, for some ranges of plasma parameters. In order to relate pulse and monochromatic waves for propagation-path diagnostic purposes, a new parameter is introduced for the transmitted pulse train which has properties that correspond very accurately to results that would be expected for Faraday rotation of a continuous wave having the central frequency of the incident pulse spectrum. Results for 5-ns pulses (10 GHz) are presented for varying propagating length, static magnetic field, electron density, and collisional absorption

Quantum dynamics via Planck-scale-stepped action-carrying 'Graph Paths'

CERN Document Server

Chew, Geoffrey Foucar

2003-01-01

A divergence-free, parameter-free, path-based discrete-time quantum dynamics is designed to not only enlarge the achievements of general relativity and the standard particle model, by approximations at spacetime scales far above Planck scale while far below Hubble scale, but to allow tackling of hitherto inaccessible questions. ''Path space'' is larger than and precursor to Hilbert-space basis. The wave-function-propagating paths are action-carrying structured graphs-cubic and quartic structured vertices connected by structured ''fermionic'' or ''bosonic'' ''particle'' and ''nonparticle'' arcs. A Planck-scale path step determines the gravitational constant while controlling all graph structure. The basis of the theory's (zero-rest-mass) elementary-particle Hilbert space (which includes neither gravitons nor scalar bosons) resides in particle arcs. Nonparticle arcs within a path are responsible for energy and rest mass.

Beam propagation considerations in the Aurora laser system

International Nuclear Information System (INIS)

Rosoche, L.A.; Mc Leod, J.; Hanlon, J.A.

1987-01-01

Aurora is a high-power KrF laser system now being constructed for inertial confinement fusion (ICF) studies. It will use optical angular multiplexing and serial amplification by electron-beam-driven KrF amplifiers to deliver a stacked, multikilojoule 5-ns-duration laser pulse to ICF targets. The requirements of angular multiplexing KrF lasers at the multikilojoule level dictate path lengths on the order of 1 km. The inherent complicated path crossings produced by angular multiplexing and pulse stacking do not allow isolation of individual beam lines, so the optical quality of the long beam paths must be controlled. Propagation of the 248-nm light beams over long paths in air is affected by scattering, absorption thermal gradients and turbulence, beam alignment, and control and optical component figure errors

Electron dominated thermoelectric response in MNiSn (M: Ti, Zr, Hf) half-Heusler alloys

KAUST Repository

Gandi, Appala

2016-05-09

We solve the transport equations of the electrons and phonons to understand the thermoelectric behaviour of the technologically important half-Heusler alloys MNiSn (M: Ti, Zr, Hf). Doping is simulated within the rigid band approximation. We clarify the origin of the electron dominated thermoelectric response and determine the carrier concentrations with maximal figures of merit. The phonon mean free path is studied to calculate the grain size below which grain refinement methods can enforce ballistic heat conduction to enhance the figure of merit. © The Owner Societies 2016.

Study of antiferro – ferromagnetic phase coexistence in Ta doped HfFe{sub 2}

Energy Technology Data Exchange (ETDEWEB)

Bag, Pallab, E-mail: pallab@csr.res.in [UGC-DAE Consortium for Scientific Research, University Campus, Khandwa Road, Indore 452001, MP (India); Singh, Sanjay [Saha Institute of Nuclear Physics, 1/AF Bidhan Nagar, Kolkata 700064 (India); Babu, P.D.; Siruguri, Vasudeva [UGC-DAE Consortium for Scientific Research, Mumbai Centre, R-5 Shed, BARC, Mumbai 400085 (India); Rawat, Rajeev [UGC-DAE Consortium for Scientific Research, University Campus, Khandwa Road, Indore 452001, MP (India)

2014-09-01

First order antiferromagnetic (AFM) to ferromagnetic (FM) transition in Hf{sub 1−x}Ta{sub x}Fe{sub 2} with x∼0.225 compounds was studied by resistivity, magnetization and X-ray diffraction (XRD) measurements at low temperature. Magnetization measurements as a function of temperature and magnetic field show path dependent FM phase fraction at 5 K for x=0.225. XRD measurements at 15 K show co-existing AFM and FM phases for this composition with ∼0.9% unit cell volume difference of FM and AFM phase.

Electron dominated thermoelectric response in MNiSn (M: Ti, Zr, Hf) half-Heusler alloys

KAUST Repository

Gandi, Appala; Schwingenschlö gl, Udo

2016-01-01

We solve the transport equations of the electrons and phonons to understand the thermoelectric behaviour of the technologically important half-Heusler alloys MNiSn (M: Ti, Zr, Hf). Doping is simulated within the rigid band approximation. We clarify the origin of the electron dominated thermoelectric response and determine the carrier concentrations with maximal figures of merit. The phonon mean free path is studied to calculate the grain size below which grain refinement methods can enforce ballistic heat conduction to enhance the figure of merit. © The Owner Societies 2016.

An Empirical Study of Propagation Models for Wireless Communications in Open-pit Mines

DEFF Research Database (Denmark)

Portela Lopes de Almeida, Erika; Caldwell, George; Rodriguez Larrad, Ignacio

2018-01-01

—In this paper, we investigate the suitability of the propagation models ITU-R 526, Okumura Hata, COST Hata models and Standard Propagation Model (SPM) to predict the path loss in open-pit mines. The models are evaluated by comparing the predicted data with measurements obtained in two operational...

Prediction of crack paths in WC-Co alloys

International Nuclear Information System (INIS)

Spiegler, R.; Fischmeister, H.F.

1992-01-01

This paper reports on a crack propagating through the WC-o microstructure which has to choose between paths along the binder/carbide interface and paths across binder regions. The latter paths are selected when the crack enters a binder region at a large angle from the nearest carbide interface, while the interface paths are preferred by cracks entering at a small angle. A critical angle can be defined for the switch from one type of crack path to the other. Empirical data for the area fractions of the two crack paths in widely different WC-Co alloys can be accounted for by a single critical angle, var-phi c = 25 degrees. Finite element analysis of the stress field in a region of binder enclosed between carbide grains shows that the preferred site for the growth of stress-induced microvoids will move from the carbide grain flanks to the interior of the binder region when the entry angle of the crack exceeds 24 degrees. Thus the observation of a critical angle deciding the crack path is verified by the stress field analysis and given a physical explanation in terms of the most likely site for microvoid formation

Complementary and bipolar regimes of resistive switching in TiN/HfO{sub 2}/TiN stacks grown by atomic-layer deposition

Energy Technology Data Exchange (ETDEWEB)

Egorov, K.V.; Kirtaev, R.V.; Markeev, A.M.; Zablotskiy, A.V. [Moscow Institute of Physics and Technology, Institutskii per. 9, 141700, Dolgoprudny (Russian Federation); Lebedinskii, Yu.Yu.; Matveyev, Yu.A.; Zenkevich, A.V. [Moscow Institute of Physics and Technology, Institutskii per. 9, 141700, Dolgoprudny (Russian Federation); National Research Nuclear University MEPhI (Moscow Engineering Physics Institute), Kashirskoye shosse 31, 115409, Moscow (Russian Federation); Orlov, O.M. [Scientific Research Institute of Molecular Electronics and Plant ' ' Micron' ' , 124462, Zelenograd (Russian Federation)

2015-04-01

Atomic-layer deposition (ALD) technique in combination with in vacuo X-ray photoelectron spectroscopy (XPS) analysis has been successfully employed to obtain fully ALD-grown planar TiN/HfO{sub 2}/TiN metal-insulator-metal structures for resistive random access memory (ReRAM) memory elements. In vacuo XPS analysis of ALD-grown TiN/HfO{sub 2}/TiN stacks reveals the presence of the ultrathin oxidized layers consisting of TiON (∝0.5 nm) and TiO{sub 2} (∝0.6 nm) at the bottom TiN/HfO{sub 2} interface (i); the nonoxidized TiN at the top HfO{sub 2}/TiN interface (ii); the oxygen deficiency in the HfO{sub 2} layer does not exceed the XPS detection limit (iii). Electroformed ALD TiN/HfO{sub 2}/TiN stacks reveal both conventional bipolar and complementary types of resistive switching. In the complementary resistive switching regime, each programming sequence is terminated by a reset operation, leaving the TiN/HfO{sub 2}/TiN stack in a high-resistance state. The observed feature can avoid detrimental leaky paths during successive reading operation, which is useful in the passive ReRAM arrays without a selector element. The bipolar regime of resistive switching is found to reveal the gradual character of the SET and RESET switching processes. Long-term potentiation and depression tests performed on ALD-grown TiN/HfO{sub 2}/TiN stacks indicate that they can be used as electronic synapse devices for the implementation of emerging neuromorphic computation systems. (copyright 2015 WILEY-VCH Verlag GmbH and Co. KGaA, Weinheim)

Path integral for a relativistic-particle theory

International Nuclear Information System (INIS)

Fradkin, E.S.; Gitman, D.M.; Shvartsman, S.M.

1991-01-01

An action of a relativistic spinning particle written in reparametrization and local super-invariant form is consistently determined by using the path integral representation for the Green's function of the spinor field. It is shown that, to obtain the causal propagator, the integration over the null mode of the onebein variable must be performed in the (0, + ∞ limits

Path integral theory and deep inelastic scattering of nuclei

International Nuclear Information System (INIS)

Neto, J.L.

1981-10-01

A formalism, based on Feynman's path integral, is developed and used in the theory of deep inelastic collisions of nuclei. Having shown how to express the propagator of the Wigner function of an isolated system as a (double) path integral in phase space, random processes are considered and the influence functional in interacting systems is discussed. A semi-classical description for the reduced Wigner and a generalized Langevin equation are given. Finally, the formalism is used in a random matrix model for deep inelastic collisions. (U.K.)

A formalism for cosmic ray propagation studies

International Nuclear Information System (INIS)

Golden, R.L.; Badhwar, G.D.; Stephens, S.A.

1975-01-01

The continuity equation for cosmic ray propagation is used to derive a set of linear equations interrelating the fluxes of multiply charged nuclei as observed at any particular part of the galaxy. The derivation leads to model indepent definitions for cosmic ray storage time, mean density of target nuclei and effective mass traversed. The set of equations form a common framework for comparisons of theories and observations. As an illustration, it is shown that there exists a large class of propagation models which give the same result as the exponential path length model. (orig./BJ) [de

Ab initio study of mechanical and thermo-acoustic properties of tough ceramics: applications to HfO2 in its cubic and orthorhombic phase

International Nuclear Information System (INIS)

Ponce, C A; Casali, R A; Caravaca, M A

2008-01-01

By means of the ab initio all-electron new full-potential linear-muffin-tin orbitals method, calculations were made for elastic constants C 11 , C 12 and C 44 for Si, ZrO 2 and HfO 2 in their cubic phase, and constants C 11 , C 22 , C 33 , C 12 , C 13 , C 23 , C 44 , C 55 and C 66 for HfO 2 in its orthorhombic phase. Using the Voigt and Reuss theory, estimations were made for polycrystals of their bulk, shear and Young moduli, and Poisson coefficients. The speed of elastic wave propagations and Debye temperatures were estimated for polycrystals built from Si and the above mentioned compounds. The semicore 4f 14 electrons should be included in the valence set of Hf atom in this all-electron approach if accurate results for elastic properties under pressures are looked for

Path-sum calculations for rf current drive

International Nuclear Information System (INIS)

Belo, Jorge H.; Bizarro, Joao P.S.; Rodrigues, Paulo

2001-01-01

Path sums and Gaussian short-time propagators are used to solve two-dimensional Fokker-Planck models of lower-hybrid (LH) and electron-cyclotron (EC) current drive (CD), and are shown to be well suited to the two limiting situations where the rf quasilinear diffusion coefficient is either relatively small, D rf ≅0.1, or very large, D rf →∞, the latter case enabling a special treatment. Results are given for both LHCD and ECCD in the small D rf case, whereas the limiting situation is illustrated only for ECCD. To check the accuracy of path-sum calculations, comparisons with finite difference solutions are provided

Anion exchange behavior of Ti, Zr, Hf, Nb and Ta as homologues of Rf and Db in mixed HF-acetone solutions

International Nuclear Information System (INIS)

Aksenov, N.V.; Bozhikov, G.A.; Starodub, G.Ya.; Dmitriev, S.N.; Filosofov, D.V.; Jon Sun Jin; Radchenko, V.I.; Lebedev, N.A.; Novgorodov, A.F.

2009-01-01

We studied in detail the sorption behavior of Ti, Zr, Hf, Nb and Ta on AG 1 anion exchange resin in HF-acetone mixed solutions as a function of organic cosolvent and acid concentrations. Anion exchange behavior was found to be strongly acetone concentration dependent. The distribution coefficients of Ti, Zr, Hf and Nb increased and those of Ta decreased with increasing content of acetone in HF solutions. With increasing HF concentration, anion exchange equilibrium analysis indicated the formation of fluoride complexes of group-4 elements with charge -3 and Ta with charge -2. For Nb the slope of -2 increased up to -5. Optimal conditions for separation of the elements using AIX chromatography were found. Group-4 elements formed MF 7 3- (M = Ti, Zr, Hf) complexes whose sorption decreased Ti > Hf > Zr in reverse order of complex stability. This fact is of particular interest for studying ion exchange behavior of Rf compared to Ti. The advantages of studying chemical properties of Rf and Db in aqueous HF solutions mixed with organic solvents are briefly discussed

Quantum cosmology based on discrete Feynman paths

International Nuclear Information System (INIS)

Chew, Geoffrey F.

2002-01-01

Although the rules for interpreting local quantum theory imply discretization of process, Lorentz covariance is usually regarded as precluding time quantization. Nevertheless a time-discretized quantum representation of redshifting spatially-homogeneous universe may be based on discrete-step Feynman paths carrying causal Lorentz-invariant action--paths that not only propagate the wave function but provide a phenomenologically-promising elementary-particle Hilbert-space basis. In a model under development, local path steps are at Planck scale while, at a much larger ''wave-function scale'', global steps separate successive wave-functions. Wave-function spacetime is but a tiny fraction of path spacetime. Electromagnetic and gravitational actions are ''at a distance'' in Wheeler-Feynman sense while strong (color) and weak (isospin) actions, as well as action of particle motion, are ''local'' in a sense paralleling the action of local field theory. ''Nonmaterial'' path segments and ''trivial events'' collaborate to define energy and gravity. Photons coupled to conserved electric charge enjoy privileged model status among elementary fermions and vector bosons. Although real path parameters provide no immediate meaning for ''measurement'', the phase of the complex wave function allows significance for ''information'' accumulated through ''gentle'' electromagnetic events involving charged matter and ''soft'' photons. Through its soft-photon content the wave function is an ''information reservoir''

Long-Term Propagation Statistics and Availability Performance Assessment for Simulated Terrestrial Hybrid FSO/RF System

Directory of Open Access Journals (Sweden)

Fiser Ondrej

2011-01-01

Full Text Available Long-term monthly and annual statistics of the attenuation of electromagnetic waves that have been obtained from 6 years of measurements on a free space optical path, 853 meters long, with a wavelength of 850 nm and on a precisely parallel radio path with a frequency of 58 GHz are presented. All the attenuation events observed are systematically classified according to the hydrometeor type causing the particular event. Monthly and yearly propagation statistics on the free space optical path and radio path are obtained. The influence of individual hydrometeors on attenuation is analysed. The obtained propagation statistics are compared to the calculated statistics using ITU-R models. The calculated attenuation statistics both at 850 nm and 58 GHz underestimate the measured statistics for higher attenuation levels. The availability performance of a simulated hybrid FSO/RF system is analysed based on the measured data.

Modeling the effects of Multi-path propagation and scintillation on GPS signals

Science.gov (United States)

Habash Krause, L.; Wilson, S. J.

2014-12-01

GPS signals traveling through the earth's ionosphere are affected by charged particles that often disrupt the signal and the information it carries due to "scintillation", which resembles an extra noise source on the signal. These signals are also affected by weather changes, tropospheric scattering, and absorption from objects due to multi-path propagation of the signal. These obstacles cause distortion within information and fading of the signal, which ultimately results in phase locking errors and noise in messages. In this work, we attempted to replicate the distortion that occurs in GPS signals using a signal processing simulation model. We wanted to be able to create and identify scintillated signals so we could better understand the environment that caused it to become scintillated. Then, under controlled conditions, we simulated the receiver's ability to suppress scintillation in a signal. We developed a code in MATLAB that was programmed to: 1. Create a carrier wave and then plant noise (four different frequencies) on the carrier wave, 2. Compute a Fourier transform on the four different frequencies to find the frequency content of a signal, 3. Use a filter and apply it to the Fourier transform of the four frequencies and then compute a Signal-to-noise ratio to evaluate the power (in Decibels) of the filtered signal, and 4.Plot each of these components into graphs. To test the code's validity, we used user input and data from an AM transmitter. We determined that the amplitude modulated signal or AM signal would be the best type of signal to test the accuracy of the MATLAB code due to its simplicity. This code is basic to give students the ability to change and use it to determine the environment and effects of noise on different AM signals and their carrier waves. Overall, we were able to manipulate a scenario of a noisy signal and interpret its behavior and change due to its noisy components: amplitude, frequency, and phase shift.

Positron annihilation studies in Hf doped YBCO

International Nuclear Information System (INIS)

Gopalan, P.; Priya, E.R.; Premila, M.; Sundar, C.S.; Gopinathan, K.P.

1992-01-01

The variation of positron lifetime and oxygen stoichiometry as a function of quench temperature has been measured in undoped and 0.5at%, 0.75at%, and 1.0 at% Hf doped YBCO. In both the undoped and Hf doped samples, the lifetime decreases and the oxygen content increases as the quench temperature is lowered from 900degC to 300degC. The lifetime in the tetragonal phase (900degC) decreases with the increase in Hf content, whereas in the orthorhombic phase (450degC) it increases. The difference in lifetime between the tetragonal and orthorhombic phases decreases with the increase in the Hf content. These trends are discussed in terms of the influence of Hf doping on the oxygen content and the positron density distribution in YBCO

Path integral for a relativistic-particle theory

Energy Technology Data Exchange (ETDEWEB)

Fradkin, E.S. (AN SSSR, Moscow (SU)); Gitman, D.M. (Moskovskij Inst. Radiotekhniki, Ehlektroniki i Automatiki, Moscow (SU)); Shvartsman, S.M. (Tomskij Pedagogicheskij Inst., Tomsk (SU))

1991-06-01

An action of a relativistic spinning particle written in reparametrization and local super-invariant form is consistently determined by using the path integral representation for the Green's function of the spinor field. It is shown that, to obtain the causal propagator, the integration over the null mode of the onebein variable must be performed in the (0, + {infinity}) limits.

Ge interactions on HfO2 surfaces and kinetically driven patterning of Ge nanocrystals on HfO2

International Nuclear Information System (INIS)

Stanley, Scott K.; Joshi, Sachin V.; Banerjee, Sanjay K.; Ekerdt, John G.

2006-01-01

Germanium interactions are studied on HfO 2 surfaces, which are prepared through physical vapor deposition (PVD) and by atomic layer deposition. X-ray photoelectron spectroscopy and temperature-programed desorption are used to follow the reactions of germanium on HfO 2 . Germanium chemical vapor deposition at 870 K on HfO 2 produces a GeO x adhesion layer, followed by growth of semiconducting Ge 0 . PVD of 0.7 ML Ge (accomplished by thermally cracking GeH 4 over a hot filament) also produces an initial GeO x layer, which is stable up to 800 K. PVD above 2.0 ML deposits semiconducting Ge 0 . Temperature programed desorption experiments of ∼1.0 ML Ge from HfO 2 at 400-1100 K show GeH 4 desorption below 600 K and GeO desorption above 850 K. These results are compared to Ge on SiO 2 where GeO desorption is seen at 550 K. Exploiting the different reactivity of Ge on HfO 2 and SiO 2 allows a kinetically driven patterning scheme for high-density Ge nanoparticle growth on HfO 2 surfaces that is demonstrated

Electric Field Gradients at Hf and Fe Sites in Hf2Fe Recalculated

International Nuclear Information System (INIS)

Belosevic-Cavor, J.; Cekic, B.; Novakovic, N.; Koteski, V.; Milosevic, Z.

2004-01-01

The electric field gradients (EFG) of the Hf 2 Fe intermetallic compound were calculated using the full-potential linearized augmented plain-wave (FP-LAPW) method as embodied in the WIEN 97 code. The obtained values are compared with other ab-initio calculations and on a qualitative basis with the previously reported experimental data obtained from TDPAC. The calculated results, -23.1.10 21 V/m 2 and 2.7.10 21 V/m 2 for Hf 48f and Fe 32e position, respectively, are in excellent agreement with experimental data (23.4.10 21 V/m 2 and 2.7.10 21 V/m 2 ), better than those reported in earlier calculations. The calculated EFG for Hf 16c position (4.2.10 21 V/m 2 ) is stronger than the experimental one (1.1.10 21 V/m 2 ).

Microstructural characterization of as-cast hf-b alloys

Directory of Open Access Journals (Sweden)

João Carlos Jânio Gigolotti

2012-04-01

Full Text Available An accurate knowledge of several metal-boron phase diagrams is important to evaluation of higher order systems such as metal-silicon-boron ternaries. The refinement and reassessment of phase diagram data is a continuous work, thus the reevaluation of metal-boron systems provides the possibility to confirm previous data from an investigation using higher purity materials and better analytical techniques. This work presents results of rigorous microstructural characterization of as-cast hafnium-boron alloys which are significant to assess the liquid composition associated to most of the invariant reactions of this system. Alloys were prepared by arc melting high purity hafnium (minimum 99.8% and boron (minimum 99.5% slices under argon atmosphere in water-cooled copper crucible with non consumable tungsten electrode and titanium getter. The phases were identified by scanning electron microscopy, using back-scattered electron image mode and X-ray diffraction. In general, a good agreement was found between our data and those from the currently accepted Hafnium-Boron phase diagram. The phases identified are αHfSS and B-RhomSS, the intermediate compounds HfB and HfB2 and the liquide L. The reactions are the eutectic L ⇔ αHfSS + HfB and L ⇔ HfB2 + B-Rhom, the peritectic L + HfB2 ⇔ HfB and the congruent formation of HfB2.

Propagation Characteristics of International Space Station Wireless Local Area Network

Science.gov (United States)

Sham, Catherine C.; Hwn, Shian U.; Loh, Yin-Chung

2005-01-01

This paper describes the application of the Uniform Geometrical Theory of Diffraction (UTD) for Space Station Wireless Local Area Networks (WLANs) indoor propagation characteristics analysis. The verification results indicate good correlation between UTD computed and measured signal strength. It is observed that the propagation characteristics are quite different in the Space Station modules as compared with those in the typical indoor WLANs environment, such as an office building. The existing indoor propagation models are not readily applicable to the Space Station module environment. The Space Station modules can be regarded as oversized imperfect waveguides. Two distinct propagation regions separated by a breakpoint exist. The propagation exhibits the guided wave characteristics. The propagation loss in the Space Station, thus, is much smaller than that in the typical office building. The path loss model developed in this paper is applicable for Space Station WLAN RF coverage and link performance analysis.

The Thermodynamic Characterization of ZrCo–H, HfCo−H, HfNi−H and Zr{sub 1–x}HfxNi(Co) Alloy–H Systems

Energy Technology Data Exchange (ETDEWEB)

Flanagan, Ted B., E-mail: ted.flanagan@uvm.edu; Noh, Hak; Luo, Suifang

2016-08-25

ZrCo and HfCo intermetallic compounds have the same cubic (CsCl-type) structure and their ternary (Zr{sub 1−x}Hf{sub x})Co alloys are also cubic. ZrNi and HfNi intermetallic compounds have the orthorhombic structure (CrB-type) and the ternary (Zr{sub 1−x}Hf{sub x})Ni alloys also have this structure. Thermodynamic data for hydride formation and decomposition in ZrCo, HfCo and HfNi intermetallic compounds have been determined from reaction calorimetry and from pressure-composition isotherms. Thermodynamic data have been determined for the three ternary alloys: (Zr{sub 0.75}Hf{sub 0.25})Co, (Zr{sub 0.50}Hf{sub 0.50})Co, and (Zr{sub 0.25}Hf{sub 0.75})Co and the four ternary alloys: (Zr{sub 0.875}Hf{sub 0.125})Ni, (Zr{sub 0.75}Hf{sub 0.25})Ni, (Zr{sub 0.50}Hf{sub 0.50})Ni, and (Zr{sub 0.25}Hf{sub 0.75})Ni. This offers the opportunity to learn how the thermodynamic properties of the ternary alloy-H systems change with the stoichiometry of alloys with the same structure. - Highlights: • Calorimetric enthalpies determined for H absorption by ZrCo, HfCo, HfNi are determined. • Ternary alloys, e.g., Zr{sub 1−x}Hf{sub x}Ni, prepared and characterized by x-ray diffraction. • Isotherms for the ternary alloys give thermodynamic parameters for H solution.

Numerical and experimental study on the wave attenuation in bone--FDTD simulation of ultrasound propagation in cancellous bone.

Science.gov (United States)

Nagatani, Yoshiki; Mizuno, Katsunori; Saeki, Takashi; Matsukawa, Mami; Sakaguchi, Takefumi; Hosoi, Hiroshi

2008-11-01

In cancellous bone, longitudinal waves often separate into fast and slow waves depending on the alignment of bone trabeculae in the propagation path. This interesting phenomenon becomes an effective tool for the diagnosis of osteoporosis because wave propagation behavior depends on the bone structure. Since the fast wave mainly propagates in trabeculae, this wave is considered to reflect the structure of trabeculae. For a new diagnosis method using the information of this fast wave, therefore, it is necessary to understand the generation mechanism and propagation behavior precisely. In this study, the generation process of fast wave was examined by numerical simulations using elastic finite-difference time-domain (FDTD) method and experimental measurements. As simulation models, three-dimensional X-ray computer tomography (CT) data of actual bone samples were used. Simulation and experimental results showed that the attenuation of fast wave was always higher in the early state of propagation, and they gradually decreased as the wave propagated in bone. This phenomenon is supposed to come from the complicated propagating paths of fast waves in cancellous bone.

A Mid-Latitude Skywave Propagation Experiment: Overview and Results

Science.gov (United States)

Munton, D. C.; Calfas, R. S.; Gaussiran, T., II; Rainwater, D.; Flesichmann, A. M.; Schofield, J. R.

2016-12-01

We will describe a mid-latitude HF skywave propagation experiment conducted during 19-27 January, 2014. There were two primary goals to the experiment. First, we wanted to build an understanding of the impact that medium scale traveling ionospheric disturbances have on the angles of arrival of the HF signals. The second goal was to provide a diverse data set that could serve as a baseline for propagation model development and evaluation. We structured individual tests during the experiment to increase the knowledge of temporal and spatial length scales of various ionospheric features. The experiment was conducted during both day and night periods and spanned a wide range of ionospheric states. We conducted the experiment at White Sands Missile Range, New Mexico and in the surrounding area. As part of the experiment, we deployed a number of active HF transmitters, and an array of dipole antennas to provide angle of arrival measurements. We also deployed a smaller array of more novel compact electro-magnetic vector sensors (EMVSs). Other instrumentation specific to the remote sensing of the ionosphere included digisondes, GNSS receivers, beacon satellite receivers, and optical instruments. We will provide a complete description of the experiment configuration and the data products.Finally, we will provide a discussion of experimental results, focusing on ionospheric conditions during the angle-of-arrival determinations, and the impact ionospheric disturbances can have on these measurements. We use the angle-of-arrival determinations to estimate TID properties, including velocity and direction.This research is based upon work supported in part by the Office of the Director of National Intelligence (ODNI), Intelligence Advanced Research Projects Activity (IARPA), via US Navy Contract N00024-07-D-6200. The views and conclusions contained herein are those of the authors and should not be interpreted as necessarily representing the official policies or endorsements

High energy HF pulsed lasers

International Nuclear Information System (INIS)

Patterson, E.L.; Gerber, R.A.

1976-01-01

Recent experiments show that pulsed HF lasers are capable of producing high energy with good efficiency. Preliminary experiments show that the laser radiation from the high-gain medium can be controlled with a low-power probe laser beam or with low-level feedback. These results indicate that the HF laser may have potential for second-generation laser fusion experiments

LAPU2: a laser pulse propagation code with diffraction

International Nuclear Information System (INIS)

Goldstein, J.C.; Dickman, D.O.

1978-03-01

Complete descriptions of the mathematical models and numerical methods used in the code LAPU2 are presented. This code can be used to study the propagation with diffraction of a temporally finite pulse through a sequence of resonant media and simple optical components. The treatment assumes cylindrical symmetry and allows nonlinear refractive indices. An unlimited number of different media can be distributed along the propagation path of the pulse. A complete users guide to input data is given as well as a FORTRAN listing of the code

Contribution to the study of neutron propagation in cavities

International Nuclear Information System (INIS)

Hasselin, G.

1965-01-01

In large size cavities where the dimensions of the holes are greater than the mean free path of the radiations, the neutron propagation calculations are carried out by taking into account the effect of the medium surrounding the hole using a reflection coefficient or albedo. In this work the fast neutron albedos are obtained for various materials and these results are applied for a Monte-Carlo propagation calculation. A comparison of this calculation with experimental results shows the validity of the method. (author) [fr

Tracking magmatic processes through Zr/Hf ratios in rocks and Hf and Ti zoning in zircons: An example from the Spirit Mountain batholith, Nevada

Science.gov (United States)

Lowery, Claiborne L.E.; Miller, C.F.; Walker, B.A.; Wooden, J.L.; Mazdab, F.K.; Bea, F.

2006-01-01

Zirconium and Hf are nearly identical geochemically, and therefore most of the crust maintains near-chondritic Zr/Hf ratios of ???35-40. By contrast, many high-silica rhyolites and granites have anomalously low Zr/Hf (15-30). As zircon is the primary reservoir for both Zr and Hf and preferentially incorporates Zr, crystallization of zircon controls Zr/ Hf, imprinting low Zr/Hf on coexisting melt. Thus, low Zr/Hf is a unique fingerprint of effective magmatic fractionation in the crust. Age and compositional zonation in zircons themselves provide a record of the thermal and compositional histories of magmatic systems. High Hf (low Zr/ Hf) in zircon zones demonstrates growth from fractionated melt, and Ti provides an estimate of temperature of crystallization (TTiZ) (Watson and Harrison, 2005). Whole-rock Zr/Hf and zircon zonation in the Spirit Mountain batholith, Nevada, document repeated fractionation and thermal fluctuations. Ratios of Zr/Hf are ???30-40 for cumulates and 18-30 for high-SiO2 granites. In zircons, Hf (and U) are inversely correlated with Ti, and concentrations indicate large fluctuations in melt composition and TTiZ (>100??C) for individual zircons. Such variations are consistent with field relations and ion-probe zircon geochronology that indicate a >1 million year history of repeated replenishment, fractionation, and extraction of melt from crystal mush to form the low Zr/Hf high-SiO2 zone. ?? 2006 The Mineralogical Society.

Thermoelectric Properties of the XCoSb (X: Ti,Zr,Hf) Half-Heusler Alloys

KAUST Repository

Gandi, Appala

2017-09-18

We investigate the thermoelectric properties of the half-Heusler alloys XCoSb (X: Ti,Zr,Hf) by solving Boltzmann transport equations and discuss them in terms of the electronic band structure. The rigid band approximation is employed to address the effects of doping. While many half-Heuser alloys show excellent thermoelectric performance, the materials under study are special by supporting both n- and p-doping. We identify the reasons for this balanced thermoelectric transport and explain why experimentally p-doping is superior to n-doping. We also determine the spectrum of phonon mean free paths to guide grain refinement methods to enhance the thermoelectric figure of merit.

Study of Direct-Contact HfO2/Si Interfaces

Directory of Open Access Journals (Sweden)

Noriyuki Miyata

2012-03-01

Full Text Available Controlling monolayer Si oxide at the HfO2/Si interface is a challenging issue in scaling the equivalent oxide thickness of HfO2/Si gate stack structures. A concept that the author proposes to control the Si oxide interface by using ultra-high vacuum electron-beam HfO2 deposition is described in this review paper, which enables the so-called direct-contact HfO2/Si structures to be prepared. The electrical characteristics of the HfO2/Si metal-oxide-semiconductor capacitors are reviewed, which suggest a sufficiently low interface state density for the operation of metal-oxide-semiconductor field-effect-transistors (MOSFETs but reveal the formation of an unexpected strong interface dipole. Kelvin probe measurements of the HfO2/Si structures provide obvious evidence for the formation of dipoles at the HfO2/Si interfaces. The author proposes that one-monolayer Si-O bonds at the HfO2/Si interface naturally lead to a large potential difference, mainly due to the large dielectric constant of the HfO2. Dipole scattering is demonstrated to not be a major concern in the channel mobility of MOSFETs.

Valley-controlled propagation of pseudospin states in bulk metacrystal waveguides

Science.gov (United States)

Chen, Xiao-Dong; Deng, Wei-Min; Lu, Jin-Cheng; Dong, Jian-Wen

2018-05-01

Light manipulations such as spin-direction locking propagation, robust transport, quantum teleportation, and reconfigurable electromagnetic pathways have been investigated at the boundaries of photonic systems. Recently by breaking Dirac cones in time-reversal-invariant photonic crystals, valley-pseudospin coupled edge states have been employed to realize selective propagation of light. Here, we realize the controllable propagation of pseudospin states in three-dimensional bulk metacrystal waveguides by valley degree of freedom. Reconfigurable photonic valley Hall effect is achieved for frequency-direction locking propagation in such a way that the propagation path can be tunable precisely by scanning the working frequency. A complete transition diagram is illustrated on the valley-dependent pseudospin states of Dirac-cone-absent photonic bands. A photonic blocker is proposed by cascading two inversion asymmetric metacrystal waveguides in which pseudospin-direction locking propagation exists. In addition, valley-dependent pseudospin bands are also discussed in a realistic metamaterials sample. These results show an alternative way toward molding the pseudospin flow in photonic systems.

Directional maximum likelihood self-estimation of the path-loss exponent

NARCIS (Netherlands)

Hu, Y.; Leus, G.J.T.; Dong, Min; Zheng, Thomas Fang

2016-01-01

The path-loss exponent (PLE) is a key parameter in wireless propagation channels. Therefore, obtaining the knowledge of the PLE is rather significant for assisting wireless communications and networking to achieve a better performance. Most existing methods for estimating the PLE not only require

Laser beam trapping and propagation in cylindrical plasma columns

International Nuclear Information System (INIS)

Feit, M.D.; Fleck, J.A. Jr.

1976-01-01

An analysis of the scheme to heat magnetically confined plasma columns to kilovolt temperatures with a laser beam requires consideration of two propagation problems. The first question to be answered is whether stable beam trapping is possible. Since the laser beam creates its own density profile by heating the plasma, the propagation of the beam becomes a nonlinear phenomenon, but not necessarily a stable one. In addition, the electron density at a given time depends on the preceding history of both the medium and the laser pulse. A self-consistent time dependent treatment of the beam propagation and the medium hydrodynamics is consequently required to predict the behavior of the laser beam. Such calculations have been carried out and indicate that propagation of a laser beam in an initially uniform plasma can form a stable filament which alternately focuses and defocuses. An additional question that is discussed is whether diffractive losses associated with long propagation paths are significant

Thermoelectric properties of doped BaHfO_3

International Nuclear Information System (INIS)

Dixit, Chandra Kr.; Bhamu, K. C.; Sharma, Ramesh

2016-01-01

We have studied the structural stability, electronic structure, optical properties and thermoelectric properties of doped BaHfO_3 by full potential linearized augmented plane wave (FP-LAPW) method. The electronic structure of BaHfO_3 doped with Sr shows enhances the indirect band gaps of 3.53 eV, 3.58 eV. The charge density plots show strong ionic bonding in Ba-Hf, and ionic and covalent bonding between Hf and O. Calculations of the optical spectra, viz., the dielectric function, refractive index and extinction coefficient are performed for the energy range are calculated and analyzed. Thermoelectric properties of semi conducting are also reported first time. The doped BaHfO_3 is approximately wide band gap semiconductor with the large p-type Seebeck coefficient. The power factor of BaHfO_3 is increased with Sr doping, decreases because of low electrical resistivity and thermal conductivity.

Thermodynamics of HfCl4-KCl molten mixtures containing HfCl4 up to 33.3 mol. per cent

International Nuclear Information System (INIS)

Smirnov, M.V.; Salyulev, A.B.; Kudyakov, V.Ya.

1980-01-01

Based on measurements of saturated vapour pressure in components of melted mixtures of HfCl 4 -KCl, depending on temperature and concentration, calculated are the results of changes in activity coefficients of hafnium tetrachloride and potassium chloride on transition from diluted solutions, where the Henry law is met, to those concentrated where the law is disobeyed. Growth in the activity coefficient of HfCl 4 is due to dissociation of complex groups of HfCl 6 2- into complexes with a lesser number of ligands and decreasing relative binding energy of Hf 4+ -Cl - there. In this case, marked changes take place in partial enthalpy and entropy of hafnium tetrachloride mixing. Similar dependences are observed for potassium chloride, but they are expressed considerably weaker. Evaporation enthalpy and entropy are calculated for HfCl 4 and KCl monomers from their melted mixtures of various concentrations

Crack Propagation Calculations for Optical Fibers under Static Bending and Tensile Loads Using Continuum Damage Mechanics

Science.gov (United States)

Chen, Yunxia; Cui, Yuxuan; Gong, Wenjun

2017-01-01

Static fatigue behavior is the main failure mode of optical fibers applied in sensors. In this paper, a computational framework based on continuum damage mechanics (CDM) is presented to calculate the crack propagation process and failure time of optical fibers subjected to static bending and tensile loads. For this purpose, the static fatigue crack propagation in the glass core of the optical fiber is studied. Combining a finite element method (FEM), we use the continuum damage mechanics for the glass core to calculate the crack propagation path and corresponding failure time. In addition, three factors including bending radius, tensile force and optical fiber diameter are investigated to find their impacts on the crack propagation process and failure time of the optical fiber under concerned situations. Finally, experiments are conducted and the results verify the correctness of the simulation calculation. It is believed that the proposed method could give a straightforward description of the crack propagation path in the inner glass core. Additionally, the predicted crack propagation time of the optical fiber with different factors can provide effective suggestions for improving the long-term usage of optical fibers. PMID:29140284

Crystal structures of KM(AsF6)3 (M2+ = Mg, Co, Mn, Zn), KCu(SbF6)3 and [Co(HF)2]Sr[Sr(HF)]2-[Sr(HF)2]2[AsF6]12

International Nuclear Information System (INIS)

Mazej, Zoran; Goreshnik, Evgeny

2015-01-01

The KM(AsF 6 ) 3 (M 2+ = Mg, Co, Mn, Zn) and KCu(SbF 6 ) 3 compounds crystallize isotypically to previously known KNi(AsF 6 ) 3 . The main features of the structure of these compounds are rings of MF 6 octahedra sharing apexes with AsF 6 octahedra connected into infinite tri-dimensional frameworks. In this arrangement cavities are formed where K + cations are placed. Single crystals of CoSr 5 (AsF 6 ) 12 .8HF were obtained as one of the products after the crystallization of 3KF/CoF 2 /SrF 2 mixture in the presence of AsF 5 in anhydrous HF. The CoSr 5 (AsF 6 ) 12 .8HF is monoclinic, C/2c (No.15), with a = 26.773(5) Aa, b = 10.087(2) Aa, c = 21.141(5) Aa, β = 93.296(13) circle , V = 5699.9(19) Aa 3 at 200 K, and Z = 4. There are three crystallographically non-equivalent Sr 2+ cations in the crystal structure of CoSr 5 (AsF 6 ) 12 .8HF. The Sr1 is coordinated by ten fluorine atoms from eight different [AsF 6 ]- anions, meanwhile Sr2 and Sr3 are bound to nine fluorine atoms provided by one HF and eight AsF 6 units or by two HF and six AsF 6 units, respectively. The Co 2+ is coordinated distorted-octahedrally by six fluorine atoms from two HF molecules and four different AsF 6 units. All those moieties in the crystal structure of [Co(HF) 2 ]Sr[Sr(HF)] 2 [Sr(HF) 2 ] 2 [AsF 6 ] 12 are connected into tridimensional framework. The CoSr 5 (AsF 6 ) 12 .8HF is a unique example of compound where HF molecules are directly bound via fluorine atoms to two different metal centres.

Zirconium Zr and hafnium Hf

International Nuclear Information System (INIS)

Busev, A.I.; Tiptsova, V.G.; Ivanov, V.M.

1978-01-01

The basic methods for extracting and determining Zr(4) and Hf(4) are described. Diantipyrinemethane and its alkyl homologs selectively extract Zr and Hf from HNO 3 solutions in the presence of nitrates. Zr is selectively extracted with tetraethyldiamide of heptyl phosphoric acid (in benzene) as well as with 2-thenoyltrifluoroacetone (in an acid). The latter reagents is suitable for rapid determination of 95 Zr in a mixture with 95 Nb and other fragments. The complexometric determination of Zr is based on formation of a stable complex of Zr with EDTA. The titration is carried out in the presence of n-sulfobenzene-azo-pyrocatechol, eriochrome black T. The determination is hindered by Hf, fluoride-, phosphate-, oxalate- and tartrate-ions. The method is used for determining Zr in zircon and eudialyte ore. Zr is determined photometrically with the aid of xylenol orange, arsenazo 3 and pyrocatechol violet (in phosphorites). Hf is determined in the presence of Zr photometrically with the aid of xylenol orange or methyl-thymol blue. The method is based on Zr being masked with hydrogen peroxide in the presence of sulfate-ions

Second-Order Statistics for Wave Propagation through Complex Optical Systems

DEFF Research Database (Denmark)

Yura, H.T.; Hanson, Steen Grüner

1989-01-01

Closed-form expressions are derived for various statistical functions that arise in optical propagation through arbitrary optical systems that can be characterized by a complex ABCD matrix in the presence of distributed random inhomogeneities along the optical path. Specifically, within the second......-order Rytov approximation, explicit general expressions are presented for the mutual coherence function, the log-amplitude and phase correlation functions, and the mean-square irradiance that are obtained in propagation through an arbitrary paraxial ABCD optical system containing Gaussian-shaped limiting...

Phenomena induced by powerful HF pumping towards magnetic zenith with a frequency near the F-region critical frequency and the third electron gyro harmonic frequency

Directory of Open Access Journals (Sweden)

N. F. Blagoveshchenskaya

2009-01-01

Full Text Available Multi-instrument observational data from an experiment on 13 October 2006 at the EISCAT/HEATING facility at Tromsø, Norway are analysed. The experiment was carried out in the evening hours when the electron density in the F-region dropped, and the HF pump frequency fH was near and then above the critical frequency of the F2 layer. The distinctive feature of this experiment is that the pump frequency was just below the third electron gyro harmonic frequency, while both the HF pump beam and UHF radar beam were directed towards the magnetic zenith (MZ. The HF pump-induced phenomena were diagnosed with several instruments: the bi-static HF radio scatter on the London-Tromsø-St. Petersburg path, the CUTLASS radar in Hankasalmi (Finland, the European Incoherent Scatter (EISCAT UHF radar at Tromsø and the Tromsø ionosonde (dynasonde. The results show thermal electron excitation of the HF-induced striations seen simultaneously from HF bi-static scatter and CUTLASS radar observations, accompanied by increases of electron temperature when the heater frequency was near and then above the critical frequency of the F2 layer by up to 0.4 MHz. An increase of the electron density up to 25% accompanied by strong HF-induced electron heating was observed, only when the heater frequency was near the critical frequency and just below the third electron gyro harmonic frequency. It is concluded that the combined effect of upper hybrid resonance and gyro resonance at the same altitude gives rise to strong electron heating, the excitation of striations, HF ray trapping and extension of HF waves to altitudes where they can excite Langmuir turbulence and fluxes of electrons accelerated to energies that produce ionization.

Phenomena induced by powerful HF pumping towards magnetic zenith with a frequency near the F-region critical frequency and the third electron gyro harmonic frequency

Directory of Open Access Journals (Sweden)

N. F. Blagoveshchenskaya

2009-01-01

Full Text Available Multi-instrument observational data from an experiment on 13 October 2006 at the EISCAT/HEATING facility at Tromsø, Norway are analysed. The experiment was carried out in the evening hours when the electron density in the F-region dropped, and the HF pump frequency f_H was near and then above the critical frequency of the F2 layer. The distinctive feature of this experiment is that the pump frequency was just below the third electron gyro harmonic frequency, while both the HF pump beam and UHF radar beam were directed towards the magnetic zenith (MZ. The HF pump-induced phenomena were diagnosed with several instruments: the bi-static HF radio scatter on the London-Tromsø-St. Petersburg path, the CUTLASS radar in Hankasalmi (Finland, the European Incoherent Scatter (EISCAT UHF radar at Tromsø and the Tromsø ionosonde (dynasonde. The results show thermal electron excitation of the HF-induced striations seen simultaneously from HF bi-static scatter and CUTLASS radar observations, accompanied by increases of electron temperature when the heater frequency was near and then above the critical frequency of the F2 layer by up to 0.4 MHz. An increase of the electron density up to 25% accompanied by strong HF-induced electron heating was observed, only when the heater frequency was near the critical frequency and just below the third electron gyro harmonic frequency. It is concluded that the combined effect of upper hybrid resonance and gyro resonance at the same altitude gives rise to strong electron heating, the excitation of striations, HF ray trapping and extension of HF waves to altitudes where they can excite Langmuir turbulence and fluxes of electrons accelerated to energies that produce ionization.

Relationship between CCR and NT-proBNP in Chinese HF patients, and their correlations with severity of HF.

Science.gov (United States)

Lu, Zhigang; Wang, Bo; Wang, Yunliang; Qian, Xueqing; Zheng, Wei; Wei, Meng

2014-01-01

To evaluate the relationship between creatinine clearance rate (CCR) and the level of N-terminal pro-B-type natriuretic peptide (NT-proBNP) in heart failure (HF) patients and their correlations with HF severity. Two hundred and one Chinese patients were grouped according to the New York Heart Association (NYHA) classification as NYHA 1-2 and 3-4 groups and 135 cases out of heart failure patients as control group. The following variables were compared among these three groups: age, sex, body mass index (BMI), smoking status, hypertension, diabetes, NT-proBNP, creatinine (Cr), uric acid (UA), left ventricular end-diastolic diameter (LVEDD), and CCR. The biomarkers of NT-proBNP, Cr, UA, LVEDD, and CCR varied significantly in the three groups, and these variables were positively correlated with the NHYA classification. The levels of NT-proBNP and CCR were closely related to the occurrence of HF and were independent risk factors for HF. At the same time, there was a significant negative correlation between the levels of NT-proBNP and CCR. The area under the receiver operating characteristic curve suggested that the NT-proBNP and CCR have high accuracy for diagnosis of HF and have clinical diagnostic value. NT-proBNP and CCR may be important biomarkers in evaluating the severity of HF.

Ab initio study of mechanical and thermo-acoustic properties of tough ceramics: applications to HfO{sub 2} in its cubic and orthorhombic phase

Energy Technology Data Exchange (ETDEWEB)

Ponce, C A [Departamento de Fisica, Facultad de Ciencias Exactas, y Naturales y Agrimensura, UNNE, Campus Universitario, Avenida Libertad 5600, CP 3400, Corrientes (Argentina); Casali, R A [Departamento de Fisica, Facultad de Ciencias Exactas, y Naturales y Agrimensura, UNNE, Campus Universitario, Avenida Libertad 5600, CP 3400, Corrientes (Argentina); Caravaca, M A [Departamento de Fisico, Quimica, Facultad de Ingenieria, UNNE, Avenida Las Heras 727, CP 3500, Resistencia (Argentina)

2008-01-30

By means of the ab initio all-electron new full-potential linear-muffin-tin orbitals method, calculations were made for elastic constants C{sub 11}, C{sub 12} and C{sub 44} for Si, ZrO{sub 2} and HfO{sub 2} in their cubic phase, and constants C{sub 11}, C{sub 22}, C{sub 33}, C{sub 12}, C{sub 13}, C{sub 23}, C{sub 44}, C{sub 55} and C{sub 66} for HfO{sub 2} in its orthorhombic phase. Using the Voigt and Reuss theory, estimations were made for polycrystals of their bulk, shear and Young moduli, and Poisson coefficients. The speed of elastic wave propagations and Debye temperatures were estimated for polycrystals built from Si and the above mentioned compounds. The semicore 4f{sup 14} electrons should be included in the valence set of Hf atom in this all-electron approach if accurate results for elastic properties under pressures are looked for.

PEMISAHAN Zr – Hf SECARA SINAMBUNG MENGGUNAKAN MIXER SETTLER

Directory of Open Access Journals (Sweden)

Dwi Biyantoro

2017-01-01

Full Text Available ABSTRAK PEMISAHAN Zr – Hf SECARA SINAMBUNG MENGGUNAKANMIXER SETTLER. Telah dilakukan pemisahanZr – Hf secara sinambung menggunakan pengaduk pengenap (mixer settler 16 stage. Larutan umpan adalah zirkon nitrat dengan kadar Zr = 30786 ppm dan Hf = 499 ppm. Ekstraktan dipakai adalah solven 60 % TBP dalam kerosen dan larutan scrubbingyang dipakai adalah asam nitrat 1 M. Umpan masuk pada stageke 5 dikontakkan secara berlawanan arah dengan solven masuk pada stage ke 16 dan larutan scrubbing masuk pada stage ke 1. Tujuan penelitian ini adalah memisahkan unsur Zr dan Hf dari hasil olah pasir zirkon menggunakan solven TBP dengan alat mixer settler16 stage. Analisis umpan dan hasil proses pemisahan untuk zirkonium (Zr dilakukan dengan menggunakan alat pendar sinar-X, sedangkananalisis unsur hafnium (Hf menggunakan Analisis Pengaktifan Neutron (APN. Parameter penelitian dilakukan dengan variasi keasaman asam nitrat dalam umpan dan variasi waktu pada berbagai laju pengadukan. Hasil penelitian pemisahan unsur Zr dengan Hf diperolehkondisi optimum pada keasaman umpan 4 N HNO3, keseimbangan dicapai setelah 3jam dan laju pengadukan 3300 rpm. Hasil ekstrak  unsur zirkon (Zr diperoleh kadar sebesar 28577 ppm dengan efisiensi 92,76 % serta kadar pengotor hafnium (Hf sebesar 95 ppm. Kata Kunci: pemisahan Zr, Hf, ekstraksi, mixer settler, alat pendar sinar-X, APN. ABSTRACT SEPARATION of Zr - Hf CONTINUOUSLY USE THE MIXER SETTLER. Separation of Zr - Hf continuously using mixer settler 16 stage has been done. The feed solution is zircon nitrate concentration of Zr = 30786 ppm  and Hf = 499 ppm. As the solvent used extractant 60 % TBP in 40 % kerosene. Nitric acid solution used srubbing 1 M. The feed entered into stage to 5 is contacted with solvents direction on the stage to 16 and the scrubbing solution enter the stage to 1. The purpose of this study is to separate Zr and Hf of the results from the process of zircon sand using solvent TBP using 16 stage

Action mechanism of hydrogen gas on deposition of HfC coating using HfCl{sub 4}-CH{sub 4}-H{sub 2}-Ar system

Energy Technology Data Exchange (ETDEWEB)

Wang, Yalei, E-mail: yaleipm@csu.edu.cn [State Key Laboratory of Powder Metallurgy, Central South University, Changsha, 410083 (China); School of Metallurgy and Environment, Central South University, Changsha, 410083 (China); Li, Zehao [State Key Laboratory of Powder Metallurgy, Central South University, Changsha, 410083 (China); Xiong, Xiang, E-mail: xiongx@csu.edu.cn [State Key Laboratory of Powder Metallurgy, Central South University, Changsha, 410083 (China); Li, Xiaobin [School of Metallurgy and Environment, Central South University, Changsha, 410083 (China); Chen, Zhaoke; Sun, Wei [State Key Laboratory of Powder Metallurgy, Central South University, Changsha, 410083 (China)

2016-12-30

Highlights: • HfC coatings were deposited on C/C composites by LPCVD using HfCl4-CH4-H2-Ar system. • Action mechanism of H2 on structure and growth behavior of HfC coating was studied. • Increased H2 concentration leads to transformation in growth mechanism of coating. - Abstract: Hafnium carbide coatings were deposited on carbon/carbon composites by low pressure chemical vapor deposition using HfCl{sub 4}-CH{sub 4}-H{sub 2}-Ar system. The microstructure, mechanical and ablation resistance performance of HfC coatings deposited with various H{sub 2} concentrations were investigated. The effect of hydrogen gas on the deposition of HfC coating was also discussed. Results show that all of the deposited coatings are composed of single cubic HfC phase, the hydrogen gas acted as a crucial role in determining the preferred orientation, microstructure and growth behavior of HfC coatings. During the deposition process, the gas phase supersaturation of the reaction species can be controlled by adjusting the hydrogen gas concentration. When deposited with low hydrogen gas concentration, the coating growth was dominated by the nucleation of HfC, which results in the particle-stacked structure of HfC coating. Otherwise, the coating growth was dominated by the crystal growth at high hydrogen gas concentration, which leads to the column-arranged structure of HfC coating. Under the ablation environment, the coating C2 exhibits better configurational stability and ablation resistance. The coating structure has a significant influence on the mechanical and ablation resistance properties of HfC coating.

Spacecraft determination of energetic particle propagation parameters: the 1 January 1978 solar event

International Nuclear Information System (INIS)

Kecskemety, K.; Gombosi, T.I.; Somogyi, A.J.

1981-01-01

Intensity-time profiles in similar energy intervals measured by the longitudinally separated HELIOS 1/2 and PROGNOZ 6 spacecrafts are used to study coronal injection and interplanetary propagation. The scattering mean free path for the interplanetary propagation turns out to be essentially the same for the three locations. If the coronal propagation is described by a Reid-Axford type diffusion model, the diffusion coefficient is approximately constant below 200 MV (about 0.1 AU), while above this rigidity is exhibits a power law increase

Unified path integral approach to theories of diffusion-influenced reactions

Science.gov (United States)

Prüstel, Thorsten; Meier-Schellersheim, Martin

2017-08-01

Building on mathematical similarities between quantum mechanics and theories of diffusion-influenced reactions, we develop a general approach for computational modeling of diffusion-influenced reactions that is capable of capturing not only the classical Smoluchowski picture but also alternative theories, as is here exemplified by a volume reactivity model. In particular, we prove the path decomposition expansion of various Green's functions describing the irreversible and reversible reaction of an isolated pair of molecules. To this end, we exploit a connection between boundary value and interaction potential problems with δ - and δ'-function perturbation. We employ a known path-integral-based summation of a perturbation series to derive a number of exact identities relating propagators and survival probabilities satisfying different boundary conditions in a unified and systematic manner. Furthermore, we show how the path decomposition expansion represents the propagator as a product of three factors in the Laplace domain that correspond to quantities figuring prominently in stochastic spatially resolved simulation algorithms. This analysis will thus be useful for the interpretation of current and the design of future algorithms. Finally, we discuss the relation between the general approach and the theory of Brownian functionals and calculate the mean residence time for the case of irreversible and reversible reactions.

The magnetic properties of $^{\\rm 177}$Hf and $^{\\rm 180}$Hf in the strong coupling deformed model

OpenAIRE

Muto, S.; Stone, N. J.; Bingham, C. R.; Stone, J. R.; Walker, P. M.; Audi, G.; Gaulard, C.; Köster, U.; Nikolov, J.; Nishimura, K.; Ohtsubo, T.; Podolyak, Z.; Risegari, L.; Simpson, G. S.; Veskovic, M.

2014-01-01

This paper reports NMR measurements of the magnetic dipole moments of two high-K isomers, the 37/2$^-$, 51.4 m, 2740 keV state in $^{\\rm 177}$Hf and the 8$^-$, 5.5 h, 1142 keV state in $^{\\rm 180}$Hf by the method of on-line nuclear orientation. Also included are results on the angular distributions of gamma transitions in the decay of the $^{\\rm 177}$Hf isotope. These yield high precision E2/M1 multipole mixing ratios for transitions in bands built on the 23/2$^+$, 1.1 s, isomer at 1315 keV ...

Role of Off-Line-of-Sight Propagation in Geomagnetic EMP Formation

Energy Technology Data Exchange (ETDEWEB)

Kruger, Hans W. [Lawrence Livermore National Lab. (LLNL), Livermore, CA (United States)

2016-05-23

The author’s synchrotron radiation based 3D geomagnetic EMP code MACSYNC has been used to explore the impact on pulse rise time and air conductivity of EMP propagation paths to the observer that are located off the direct line-of-sight (LOS) between gamma source and observer. This geometry is always present because, for an isotropic source, most the gammas are emitted at an angle with respect to the LOS. Computations for a 1 kt near-surface burst observed from space yield two principal findings: 1. The rise time is generated by the combined actions of a) electron spreading along the LOS due to the Compton electron emission angular distribution folded with electron multiple scattering effects, and b) radiation arrival time spreading due to length differences for different off-LOS propagation paths. The pulse rise time does not depend on the rise time of the conductivity. The conductivity rise time determines the pulse amplitude. 2. One-dimensional legacy EMP codes are inherently incapable of producing the correct pulse shape because they cannot treat the dependence of the conductivity on two dimensions, i.e. the radius from the source and the angle of the propagation path with the LOS. This divergence from one-dimensionality begins at a small fraction of a nanosecond for a sea-level burst. This effect will also be present in high-altitude bursts, however, determination of its onset time and magnitude requires high-altitude computations which have not yet been done.

Path integration and separation of variables in spaces of constant curvature in two and three dimensions

International Nuclear Information System (INIS)

Grosche, C.

1993-10-01

In this paper path integration in two- and three-dimensional spaces of constant curvature is discussed: i.e. the flat spaces R 2 and R 3 , the two- and three-dimensional sphere and the two- and three dimensional pseudosphere. The Laplace operator in these spaces admits separation of variables in various coordinate systems. In all these coordinate systems the path integral formulation will be stated, however in most of them an explicit solution in terms of the spectral expansion can be given only on a formal level. What can be stated in all cases, are the propagator and the corresponding Green function, respectively, depending on the invariant distance which is a coordinate independent quantity. This property gives rise to numerous identities connecting the corresponding path integral representations and propagators in various coordinate systems with each other. (orig.)

Analytical, numerical and experimental investigations of transverse fracture propagation from horizontal wells

Energy Technology Data Exchange (ETDEWEB)

Rahman, M.M.; Hossain, M.M.; Crosby, D.G.; Rahman, M.K.; Rahman, S.S. [School of Petroleum Engineering, The University of New South Wales, 2052 Sydney (Australia)

2002-08-01

This paper presents results of a comprehensive study involving analytical, numerical and experimental investigations into transverse fracture propagation from horizontal wells. The propagation of transverse hydraulic fractures from horizontal wells is simulated and investigated in the laboratory using carefully designed experimental setups. Closed-form analytical theories for Mode I (opening) stress intensity factors for idealized fracture geometries are reviewed, and a boundary element-based model is used herein to investigate non-planar propagation of fractures. Using the mixed mode fracture propagation criterion of the model, a reasonable agreement is found with respect to fracture geometry, net fracture pressures and fracture propagation paths between the modeled fractures and the laboratory tested fractures. These results suggest that the propagation of multiple fractures requires higher net pressures than a single fracture, the underlying reason of which is theoretically justified on the basis of local stress distribution.

Hf isotope evidence for a hidden mantle reservoir

DEFF Research Database (Denmark)

Bizzarro, Martin; Simonetti, A.; Stevenson, R.K.

2002-01-01

High-precision Hf isotopic analyses and U-Pb ages of carbonatites and kimberlites from Greenland and eastern North America, including Earth's oldest known carbonatite (3 Ga), indicate derivation from an enriched mantle source. This previously unidentified mantle reservoir-marked by an unradiogenic...... Hf isotopic composition and preserved in the deep mantle for at least 3 b.y.-may account for the mass imbalance in Earth's Hf-Nd budget. The Hf isotopic data presented here support a common mantle source region and genetic link between carbonatite and some oceanic-island basalt volcanoes....

Transionospheric propagation predictions

Science.gov (United States)

Klobucher, J. A.; Basu, S.; Basu, S.; Bernhardt, P. A.; Davies, K.; Donatelli, D. E.; Fremouw, E. J.; Goodman, J. M.; Hartmann, G. K.; Leitinger, R.

1979-01-01

The current status and future prospects of the capability to make transionospheric propagation predictions are addressed, highlighting the effects of the ionized media, which dominate for frequencies below 1 to 3 GHz, depending upon the state of the ionosphere and the elevation angle through the Earth-space path. The primary concerns are the predictions of time delay of signal modulation (group path delay) and of radio wave scintillation. Progress in these areas is strongly tied to knowledge of variable structures in the ionosphere ranging from the large scale (thousands of kilometers in horizontal extent) to the fine scale (kilometer size). Ionospheric variability and the relative importance of various mechanisms responsible for the time histories observed in total electron content (TEC), proportional to signal group delay, and in irregularity formation are discussed in terms of capability to make both short and long term predictions. The data base upon which predictions are made is examined for its adequacy, and the prospects for prediction improvements by more theoretical studies as well as by increasing the available statistical data base are examined.

Magnetic properties of Hf177 and Hf180 in the strong-coupling deformed model

Science.gov (United States)

Muto, S.; Stone, N. J.; Bingham, C. R.; Stone, J. R.; Walker, P. M.; Audi, G.; Gaulard, C.; Köster, U.; Nikolov, J.; Nishimura, K.; Ohtsubo, T.; Podolyak, Z.; Risegari, L.; Simpson, G. S.; Veskovic, M.; Walters, W. B.

2014-04-01

This paper reports NMR measurements of the magnetic dipole moments of two high-K isomers, the 37/2-, 51.4 m, 2740 keV state in Hf177 and the 8-, 5.5 h, 1142 keV state in Hf180 by the method of on-line nuclear orientation. Also included are results on the angular distributions of γ transitions in the decay of the Hf177 isotope. These yield high precision E2/M1 multipole mixing ratios for transitions in bands built on the 23/2+, 1.1 s, isomer at 1315 keV and on the 9/2+, 0.663 ns, isomer at 321 keV. The new results are discussed in the light of the recently reported finding of systematic dependence of the behavior of the gR parameter upon the quasiproton and quasineutron make up of high-K isomeric states in this region.

Earth-Space Propagation Data Bases

Science.gov (United States)

Smith, Ernest K.

1996-01-01

This paper, designed for the newcomer rather than the expert, will take a rather broad view of what is meant by 'propagation data bases' in that it will take the term to mean both the actual measurements and models of Earth-space paths. The text will largely be drawn from International Radio Consultative Committee (CCIR) reports, now annexed to the Recommendations of the International Telecommunications Union-R Study Group 3, plus some experience with a course taught at the University of Colorado.

Theoretical predictions of hydrolysis and complex formation of group-4 elements Zr, Hf and Rf in HF and HCl solutions

International Nuclear Information System (INIS)

Pershina, V.; Trubert, D.; Le Naour, C.; Kratz, J.V.

2002-01-01

Fully relativistic molecular density-functional calculations of the electronic structures of hydrated, hydrolyzed and fluoride/chloride complexes have been performed for group-4 elements Zr, Hf, and element 104, Rf. Using the electronic density distribution data, relative values of the free energy change for hydrolysis and complex formation reactions were defined. The results show the following trend for the first hydrolysis step of the cationic species: Zr>Hf>Rf in agreement with experiments. For the complex formation in HF solutions, the trend to a decrease from Zr to Hf is continued with Rf, provided no hydrolysis takes place. At pH>0, further fluorination of hydrolyzed species or fluoro-complexes has an inversed trend in the group Rf≥Zr>Hf, with the difference between the elements being very small. For the complex formation in HCl solutions, the trend is continued with Rf, so that Zr>Hf>Rf independently of pH. A decisive energetic factor in hydrolysis or complex formation processes proved to be a predominant electrostatic metal-ligand interaction. Trends in the K d (distribution coefficient) values for the group-4 elements are expected to follow those of the complex formation

Oxidation behavior of Hf-modified platinum aluminide coatings during thermal cycling

Directory of Open Access Journals (Sweden)

Liya Ye

2018-02-01

Full Text Available Platinum aluminide coatings with different Hf contents were fabricated by using HfCl4. The oxidation kinetics and the rumpling behavior of oxide scale were investigated. After thermal cycling, the coating with 0.46 wt% Hf showed least weight gain. With the increase of Hf content, rumpling extent of the scale decreased. Meanwhile, HfO2 preferentially formed in the scale resulting in the increase of scale thickness. The oxidation of excessive Hf even caused the spallation of the scale. The results in the present study indicate that although Hf plays an important role in decreasing rumpling extent of TGO, the oxidation of Hf decreases the adhesion of the scale. Keywords: Pt-Al coating, Hf, Oxidation, Rumpling

Vulnerabilities, Influences and Interaction Paths: Failure Data for Integrated System Risk Analysis

Science.gov (United States)

Malin, Jane T.; Fleming, Land

2006-01-01

We describe graph-based analysis methods for identifying and analyzing cross-subsystem interaction risks from subsystem connectivity information. By discovering external and remote influences that would be otherwise unexpected, these methods can support better communication among subsystem designers at points of potential conflict and to support design of more dependable and diagnosable systems. These methods identify hazard causes that can impact vulnerable functions or entities if propagated across interaction paths from the hazard source to the vulnerable target. The analysis can also assess combined impacts of And-Or trees of disabling influences. The analysis can use ratings of hazards and vulnerabilities to calculate cumulative measures of the severity and importance. Identification of cross-subsystem hazard-vulnerability pairs and propagation paths across subsystems will increase coverage of hazard and risk analysis and can indicate risk control and protection strategies.

Effects of HfB2 and HfN Additions on the Microstructures and Mechanical Properties of TiB2-Based Ceramic Tool Materials

Science.gov (United States)

An, Jing; Song, Jinpeng; Liang, Guoxing; Gao, Jiaojiao; Xie, Juncai; Cao, Lei; Wang, Shiying; Lv, Ming

2017-01-01

The effects of HfB2 and HfN additions on the microstructures and mechanical properties of TiB2-based ceramic tool materials were investigated. The results showed that the HfB2 additive not only can inhibit the TiB2 grain growth but can also change the morphology of some TiB2 grains from bigger polygons to smaller polygons or longer ovals that are advantageous for forming a relatively fine microstructure, and that the HfN additive had a tendency toward agglomeration. The improvement of flexural strength and Vickers hardness of the TiB2-HfB2 ceramics was due to the relatively fine microstructure; the decrease of fracture toughness was ascribed to the formation of a weaker grain boundary strength due to the brittle rim phase and the poor wettability between HfB2 and Ni. The decrease of the flexural strength and Vickers hardness of the TiB2-HfN ceramics was due to the increase of defects such as TiB2 coarse grains and HfN agglomeration; the enhancement of fracture toughness was mainly attributed to the decrease of the pore number and the increase of the rim phase and TiB2 coarse grains. The toughening mechanisms of TiB2-HfB2 ceramics mainly included crack bridging and transgranular fracture, while the toughening mechanisms of TiB2-HfN ceramics mainly included crack deflection, crack bridging, transgranular fracture, and the core-rim structure. PMID:28772821

Effects of HfB2 and HfN Additions on the Microstructures and Mechanical Properties of TiB2-Based Ceramic Tool Materials

Directory of Open Access Journals (Sweden)

Jing An

2017-04-01

Full Text Available The effects of HfB2 and HfN additions on the microstructures and mechanical properties of TiB2-based ceramic tool materials were investigated. The results showed that the HfB2 additive not only can inhibit the TiB2 grain growth but can also change the morphology of some TiB2 grains from bigger polygons to smaller polygons or longer ovals that are advantageous for forming a relatively fine microstructure, and that the HfN additive had a tendency toward agglomeration. The improvement of flexural strength and Vickers hardness of the TiB2-HfB2 ceramics was due to the relatively fine microstructure; the decrease of fracture toughness was ascribed to the formation of a weaker grain boundary strength due to the brittle rim phase and the poor wettability between HfB2 and Ni. The decrease of the flexural strength and Vickers hardness of the TiB2-HfN ceramics was due to the increase of defects such as TiB2 coarse grains and HfN agglomeration; the enhancement of fracture toughness was mainly attributed to the decrease of the pore number and the increase of the rim phase and TiB2 coarse grains. The toughening mechanisms of TiB2-HfB2 ceramics mainly included crack bridging and transgranular fracture, while the toughening mechanisms of TiB2-HfN ceramics mainly included crack deflection, crack bridging, transgranular fracture, and the core-rim structure.

Beam wandering statistics of twin thin laser beam propagation under generalized atmospheric conditions.

Science.gov (United States)

Pérez, Darío G; Funes, Gustavo

2012-12-03

Under the Geometrics Optics approximation is possible to estimate the covariance between the displacements of two thin beams after they have propagated through a turbulent medium. Previous works have concentrated in long propagation distances to provide models for the wandering statistics. These models are useful when the separation between beams is smaller than the propagation path-regardless of the characteristics scales of the turbulence. In this work we give a complete model for these covariances, behavior introducing absolute limits to the validity of former approximations. Moreover, these generalizations are established for non-Kolmogorov atmospheric models.

High-order Path Integral Monte Carlo methods for solving strongly correlated fermion problems

Science.gov (United States)

Chin, Siu A.

2015-03-01

In solving for the ground state of a strongly correlated many-fermion system, the conventional second-order Path Integral Monte Carlo method is plagued with the sign problem. This is due to the large number of anti-symmetric free fermion propagators that are needed to extract the square of the ground state wave function at large imaginary time. In this work, I show that optimized fourth-order Path Integral Monte Carlo methods, which uses no more than 5 free-fermion propagators, in conjunction with the use of the Hamiltonian energy estimator, can yield accurate ground state energies for quantum dots with up to 20 polarized electrons. The correlations are directly built-in and no explicit wave functions are needed. This work is supported by the Qatar National Research Fund NPRP GRANT #5-674-1-114.

Query by Constraint Propagation in the Concept-Oriented Data Model

Directory of Open Access Journals (Sweden)

Alexandr Savinov

2006-09-01

Full Text Available The paper describes an approach to query processing in the concept-oriented data model. This approach is based on imposing constraints and specifying the result type. The constraints are then automatically propagated over the model and the result contains all related data items. The simplest constraint propagation strategy consists of two steps: propagating down to the most specific level using de-projection and propagating up to the target concept using projection. A more complex strategy described in the paper may consist of many de-projection/projection steps passing through some intermediate concepts. An advantage of the described query mechanism is that it does not need any join conditions because it uses the structure of the model for propagation. Moreover, this mechanism does not require specifying an access path using dimension names. Thus even rather complex queries can be expressed in simple and natural form because they are expressed by specifying what information is available and what related data we want to get.

The magnetic hyperfine field in the 181Ta site in the Co2HfAl and Co2HfGa Heusler alloys

International Nuclear Information System (INIS)

Silva, R. da.

1979-01-01

The hyperfine magnetic fields at 181 Ta nuclei in Heusler alloys Co 2 HfZ (Z=Al, Ga) have been measured using the time differential perturbed gamma-gamma angular correlation (TDPAC) method. The hyperfine fields obtained from these measurements at the liquid nitrogen temperature are -189 and +- 150 kOersted for Co 2 HfAl and Co 2 HfGa, respectively. The concept that the hyperfine field at the Y site is similar to the solute fields in Fe, Co, Ni and Gd matrices is corroborated. We have verified that ratios H sub(hf) sub(Ta)/T sub(c) and H sub(hf) sub(Ta)μ sub(Co) in Co 2 HfZ compounds (Z=Al, Ga, Sn) do not depend on the nature of Z element. However a dependence in the value of observed field with the s-p element in Z site was noticed. We feel that the samples are not completely ordered cubic as observed by the quadrupole interaction measurements. The results are interpreted in terms of the Campbell-Blandin formalism, and it is shown that the spin polarization of conduction electrons at Hf and Ta have opposite signs. (Author) [pt

Um estudo teórico de propriedades moleculares em complexos de hidrogênio trimoleculares C2H4···2HF, C2H2···2HF e C3h6···2HF A theoretical study of molecular properties of C2H4···2HF, C2H2···2HF AND C3H6···2HF trimolecular hydrogen-bonded complexes

Directory of Open Access Journals (Sweden)

Boaz G. Oliveira

2008-01-01

Full Text Available We present a theoretical study of molecular properties in C2H4···2HF, C2H2···2HF and C3H6···2HF trimolecular hydrogen-bonded complexes. From B3LYP/6-311++G(d,p calculations, the most important structural deformations are related to the C=C (C2H4, C≡C (C2H2, C-C (C3H6 and HF bond lengths. According to the Bader's atoms in molecules and CHELPG calculations, it was identified a tertiary interaction between the fluorine atom of the second hydrofluoric acid molecule and hydrogen atoms of the ethylene and acetylene within the C2H4···2HF and C2H2···2HF complexes, respectively. Additionally, the evaluation of the infrared spectrum characterized the new vibrational modes and bathochromic effect of the HF molecules.

Progress in Body-Worn Antennas for On-Body Propagation (invited)

DEFF Research Database (Denmark)

Jakobsen, Kaj Bjarne

2016-01-01

On-body propagation and on-body antennas for body-centric wireless communications are presented. The onbody communications rely on creeping waves launched and received by the antennas, respectively. Path gain and bandwidth at 2.4 GHz for different types of body-worn antennas for head-centric comm...

Path integral analysis of Jarzynski's equality: Analytical results

Science.gov (United States)

Minh, David D. L.; Adib, Artur B.

2009-02-01

We apply path integrals to study nonequilibrium work theorems in the context of Brownian dynamics, deriving in particular the equations of motion governing the most typical and most dominant trajectories. For the analytically soluble cases of a moving harmonic potential and a harmonic oscillator with a time-dependent natural frequency, we find such trajectories, evaluate the work-weighted propagators, and validate Jarzynski’s equality.

Adaptive numerical modeling of dynamic crack propagation

International Nuclear Information System (INIS)

Adouani, H.; Tie, B.; Berdin, C.; Aubry, D.

2006-01-01

We propose an adaptive numerical strategy that aims at developing reliable and efficient numerical tools to model dynamic crack propagation and crack arrest. We use the cohesive zone theory as behavior of interface-type elements to model crack. Since the crack path is generally unknown beforehand, adaptive meshing is proposed to model the dynamic crack propagation. The dynamic study requires the development of specific solvers for time integration. As both geometry and finite element mesh of the studied structure evolve in time during transient analysis, the stability behavior of dynamic solver becomes a major concern. For this purpose, we use the space-time discontinuous Galerkin finite element method, well-known to provide a natural framework to manage meshes that evolve in time. As an important result, we prove that the space-time discontinuous Galerkin solver is unconditionally stable, when the dynamic crack propagation is modeled by the cohesive zone theory, which is highly non-linear. (authors)

Large scale propagation intermittency in the atmosphere

Science.gov (United States)

Mehrabi, Ali

2000-11-01

Long-term (several minutes to hours) amplitude variations observed in outdoor sound propagation experiments at Disneyland, California, in February 1998 are explained in terms of a time varying index of refraction. The experimentally propagated acoustic signals were received and recorded at several locations ranging from 300 meters to 2,800 meters. Meteorological data was taken as a function of altitude simultaneously with the received signal levels. There were many barriers along the path of acoustic propagation that affected the received signal levels, especially at short ranges. In a downward refraction situation, there could be a random change of amplitude in the predicted signals. A computer model based on the Fast Field Program (FFP) was used to compute the signal loss at the different receiving locations and to verify that the variations in the received signal levels can be predicted numerically. The calculations agree with experimental data with the same trend variations in average amplitude.

Collision-Induced Dissociation Study of Strong Hydrogen-Bonded Cluster Ions Y-(HF) n (Y=F, O2) Using Atmospheric Pressure Corona Discharge Ionization Mass Spectrometry Combined with a HF Generator.

Science.gov (United States)

Sakamoto, Kenya; Sekimoto, Kanako; Takayama, Mitsuo

2017-01-01

Hydrogen fluoride (HF) was produced by a homemade HF generator in order to investigate the properties of strong hydrogen-bonded clusters such as (HF) n . The HF molecules were ionized in the form of complex ions associated with the negative core ions Y - produced by atmospheric pressure corona discharge ionization (APCDI). The use of APCDI in combination with the homemade HF generator led to the formation of negative-ion HF clusters Y - (HF) n (Y=F, O 2 ), where larger clusters with n ≥4 were not detected. The mechanisms for the formation of the HF, F - (HF) n , and O 2 - (HF) n species were discussed from the standpoints of the HF generator and APCDI MS. By performing energy-resolved collision-induced dissociation (CID) experiments on the cluster ions F - (HF) n ( n =1-3), the energies for the loss of HF from F - (HF) 3 , F - (HF) 2 , and F - (HF) were evaluated to be 1 eV or lower, 1 eV or higher, and 2 eV, respectively, on the basis of their center-of-mass energy ( E CM ). These E CM values were consistent with the values of 0.995, 1.308, and 2.048 eV, respectively, obtained by ab initio calculations. The stability of [O 2 (HF) n ] - ( n =1-4) was discussed on the basis of the bond lengths of O 2 H-F - (HF) n and O 2 - H-F(HF) n obtained by ab initio calculations. The calculations indicated that [O 2 (HF) 4 ] - separated into O 2 H and F - (HF) 3 .

On the collocation between dayside auroral activity and coherent HF radar backscatter

Directory of Open Access Journals (Sweden)

J. Moen

Full Text Available The 2D morphology of coherent HF radar and optical cusp aurora has been studied for conditions of predominantly southward IMF conditions, which favours low-latitude boundary layer reconnection. Despite the variability in shape of radar cusp Doppler spectra, the spectral width criterion of > 220 m s^–1 proves to be a robust cusp discriminator. For extended periods of well-developed radar backscatter echoes, the equatorward boundary of the > 220 m s^–1 spectral width enhancement lines up remarkably well with the equatorward boundary of the optical cusp aurora. The spectral width boundary is however poorly determined during development and fading of radar cusp backscatter. Closer inspection of radar Doppler profile characteristics suggests that a combination of spectral width and shape may advance boundary layer identification by HF radar. For the two December days studied the onset of radar cusp backscatter occurred within pre-existing 630.0 nm cusp auroral activity and appear to be initiated by sunrise, i.e. favourable radio wave propagation conditions had to develop. Better methods are put forward for analysing optical data, and for physical interpretation of HF radar data, and for combining these data, as applied to detection, tracking, and better understanding of dayside aurora. The broader motivation of this work is to develop wider use by the scientific community, of results of these techniques, to accelerate understanding of dynamic high-latitude boundary-processes. The contributions in this work are: (1 improved techniques of analysis of observational data, yielding meaningfully enhanced accuracy for deduced cusp locations; (2 a correspondingly more pronounced validation of correlation of boundary locations derived from the observational data set; and (3 a firmer physical rationale as to why the good correlation observed should theoretically be expected.

Key words: Ionosphere (ionospheric

Investigation of new type Cu-Hf-Al bulk glassy alloys

International Nuclear Information System (INIS)

Nagy, E; Ronto, V; Solyom, J; Roosz, A

2009-01-01

In the last years new type Cu-Hf-Al ternary alloys were developed with high glass forming ability and ductility. The addition of Al to Cu-Hf alloys results in improvements in glass formation, thermal stability and mechanical properties of these alloys. We have investigated new Cu-based bulk amorphous alloys in Cu-Hf-Al ternary system. The alloys with Cu 49 Hf 42 Al 9 , Cu 46 Hf 45 Al 9 , Cu 50 Hf 42.5 Al 7.5 and Cu 50 Hf 45 Al 5 compositions were prepared by arc melting. The samples were made by centrifugal casting and were investigated by X-ray diffraction method. Thermodynamic properties were examined by differential scanning calorimetry and the structure of the crystallising phases by scanning electron microscopy. The determination of liquidus temperatures of alloys were measured by differential thermal analysis.

Propagation effects on radio range and noise in earth-space telecommunications

Science.gov (United States)

Flock, W. L.; Slobin, S. D.; Smith, E. K.

1982-01-01

Attention is given to the propagation effects on radio range and noise in earth-space telecommunications. The use of higher frequencies minimizes ionospheric effects on propagation, but tropospheric effects often increase or dominate. For paths of geostationary satellites, and beyond, the excess range delay caused by the ionosphere and plasmasphere is proportional to the total electron content along the path and inversely proportional to frequency squared. The delay due to dry air is usually of the order of a few meters while the delay due to water vapor (a few tens of centimeters) is responsible for most of the temporal variation in the range delay for clean air. For systems such as that of the Voyager spacecraft, and for attenuation values up to about 10 dB, increased sky noise degrades the received signal-to-noise ratio more than does the reduction in signal level due to attenuation.

First Joint Observations of Radio Aurora by the VHF and HF Radars of the ISTP SB RAS

Science.gov (United States)

Berngardt, O. I.; Lebedev, V. P.; Kutelev, K. A.; Kushnarev, D. S.; Grkovich, K. V.

2018-01-01

Two modern radars for diagnosis of the ionosphere by the radio-wave backscattering method, namely, the Irkutsk incoherent scatter radar at VHF (IISR, 154-162 MHz) and the Ekaterinburg coherent radar at HF (EKB, 8-20 MHz) are operated at the Institute of Solar-Terrestrial Physics, Siberian Branch of the Russian Academy of Sciences (ISTP SB RAS). The paper analyzes the results of joint observations of strong scattering (radio aurora) on June 8, 2015. To determine the geographical position of the radio aurora, we developed original methods that take into account both the features of the radio-wave propagation and the features of the radar antenna systems. It is shown that there are areas where the spatial position of the HF and VHF radio aurora can coincide. This permits using the radars as a single complex for diagnosis of the characteristics of small-scale high-latitude irregularities in the ionospheric E and F layers. A comparative analysis of the characteristics and temporal dynamics of the radio-aurora region in the HF and VHF ranges is performed. Using the DMSP satellite data, it has been shown that the radio aurora dynamics during this experiment with the EKB radar can be related with the spatial dynamics of the localized area with high electric field, which moves from high to equatorial latitudes. It is found that due to the broader field of view, radio aurora at the HF radar was stably observed 6-12 min earlier than at the VHF radar. This permits using the EKB radar data for prediction of the radio-aurora detection by the IISR radar.

Enhanced resistive switching and multilevel behavior in bilayered HfAlO/HfAlO{sub x} structures for non-volatile memory applications

Energy Technology Data Exchange (ETDEWEB)

Faita, F. L., E-mail: fabriciofaita@gmail.com [Centre of Physics, University of Minho, Campus de Gualtar, 4710-057 Braga (Portugal); Departamento de Física, Universidade Federal de Santa Catarina, Campus Trindade, 88040-900 Florianópolis, SC (Brazil); Silva, J. P. B., E-mail: josesilva@fisica.uminho.pt [Centre of Physics, University of Minho, Campus de Gualtar, 4710-057 Braga (Portugal); IFIMUP and IN-Institute of Nanoscience and Nanotechnology, Departamento de Física e Astronomia, Faculdade de Ciências da Universidade do Porto, 4169-007 Porto (Portugal); Pereira, M.; Gomes, M. J. M. [Centre of Physics, University of Minho, Campus de Gualtar, 4710-057 Braga (Portugal)

2015-12-14

In this work, hafnium aluminum oxide (HfAlO) thin films were deposited by ion beam sputtering deposition technique on Si substrate. The presence of oxygen vacancies in the HfAlO{sub x} layer deposited in oxygen deficient environment is evidenced from the photoluminescence spectra. Furthermore, HfAlO(oxygen rich)/HfAlO{sub x}(oxygen poor) bilayer structures exhibit multilevel resistive switching (RS), and the switching ratio becomes more prominent with increasing the HfAlO layer thickness. The bilayer structure with HfAlO/HfAlO{sub x} thickness of 30/40 nm displays the enhanced multilevel resistive switching characteristics, where the high resistance state/intermediate resistance state (IRS) and IRS/low resistance state resistance ratios are ≈10{sup 2} and ≈5 × 10{sup 5}, respectively. The switching mechanisms in the bilayer structures were investigated by the temperature dependence of the three resistance states. This study revealed that the multilevel RS is attributed to the coupling of ionic conduction and the metallic conduction, being the first associated to the formation and rupture of conductive filaments related to oxygen vacancies and the second with the formation of a metallic filament. Moreover, the bilayer structures exhibit good endurance and stability in time.

Thermodynamics of HfCl/sub 4/-KCl molten mixtures containing HfCl/sub 4/ up to 33. 3 mol. per cent

Energy Technology Data Exchange (ETDEWEB)

Smirnov, M V; Salyulev, A B; Kudyakov, V Ya [AN SSSR, Sverdlovsk. Inst. Ehlektrokhimii

1980-05-01

Based on measurements of saturated vapour pressure in components of melted mixtures of HfCl/sub 4/-KCl, depending on temperature and concentration, calculated are the results of changes in activity coefficients of hafnium tetrachloride and potassium chloride on transition from diluted solutions, where the Henry law is met, to those concentrated where the law is disobeyed. Growth in the activity coefficient of HfCl/sub 4/ is due to dissociation of complex groups of HfCl/sub 6//sup 2 -/ into complexes with a lesser number of ligands and decreasing relative binding energy of Hf/sup 4 +/-Cl/sup -/ there. In this case, marked changes take place in partial enthalpy and entropy of hafnium tetrachloride mixing. Similar dependences are observed for potassium chloride, but they are expressed considerably weaker. Evaporation enthalpy and entropy are calculated for HfCl/sub 4/ and KCl monomers from their melted mixtures of various concentrations.

The impact of PMSE and NLC particles on VLF propagation

Directory of Open Access Journals (Sweden)

D. Nunn

2004-04-01

Full Text Available PMSE or Polar Mesosphere Summer Echoes are a well-known phenomenon in the summer northern polar regions, in which anomalous VHF/UHF radar echoes are returned from heights ~85km. Noctilucent clouds and electron density biteouts are two phenomena that sometimes occur together with PMSE. Electron density biteouts are electron density depletion layers of up to 90%, which may be several kms thick. Using the NOSC Modefndr code based on Wait's modal theory for subionospheric propagation, we calculate the shifts in received VLF amplitude and phase that occur as a result of electron density biteouts. The code assumes a homogeneous background ionosphere and a homogeneous biteout layer along the Great Circle Path (GCP corridor, for transmitter receiver path lengths in the range of 500–6000km.

For profiles during the 10h about midnight and under quiet geomagnetic conditions, where the electron density at 85km would normally be less than 500el/cc, it was found that received signal perturbations were significant, of the order of 1–4dB and 5–40° of phase. Perturbation amplitudes increase roughly as the square root of frequency. At short range perturbations are rather erratic, but more consistent at large ranges, readily interpretable in terms of the shifts in excitation factor, attenuation factor and v/c ratios for Wait's modes. Under these conditions such shifts should be detectable by a well constituted experiment involving multiple paths and multiple frequencies in the north polar region in summer. It is anticipated that VLF propagation could be a valuable diagnostic for biteout/PMSE when electron density at 85km is under 500el/cc, under which circumstances PMSE are not directly detectable by VHF/UHF radars.

Key words. Electromagnetism (wave propagation – Ionosphere (polar ionosphere – Radioscience (ionospheric propagation

Propagation Diagnostic Simulations Using High-Resolution Equatorial Plasma Bubble Simulations

Science.gov (United States)

Rino, C. L.; Carrano, C. S.; Yokoyama, T.

2017-12-01

In a recent paper, under review, equatorial-plasma-bubble (EPB) simulations were used to conduct a comparative analysis of the EPB spectra characteristics with high-resolution in-situ measurements from the C/NOFS satellite. EPB realizations sampled in planes perpendicular to magnetic field lines provided well-defined EPB structure at altitudes penetrating both high and low-density regions. The average C/NOFS structure in highly disturbed regions showed nearly identical two-component inverse-power-law spectral characteristics as the measured EPB structure. This paper describes the results of PWE simulations using the same two-dimensional cross-field EPB realizations. New Irregularity Parameter Estimation (IPE) diagnostics, which are based on two-dimensional equivalent-phase-screen theory [A theory of scintillation for two-component power law irregularity spectra: Overview and numerical results, by Charles Carrano and Charles Rino, DOI: 10.1002/2015RS005903], have been successfully applied to extract two-component inverse-power-law parameters from measured intensity spectra. The EPB simulations [Low and Midlatitude Ionospheric Plasma DensityIrregularities and Their Effects on Geomagnetic Field, by Tatsuhiro Yokoyama and Claudia Stolle, DOI 10.1007/s11214-016-0295-7] have sufficient resolution to populate the structure scales (tens of km to hundreds of meters) that cause strong scintillation at GPS frequencies. The simulations provide an ideal geometry whereby the ramifications of varying structure along the propagation path can be investigated. It is well known path-integrated one-dimensional spectra increase the one-dimensional index by one. The relation requires decorrelation along the propagation path. Correlated structure would be interpreted as stochastic total-electron-content (TEC). The simulations are performed with unmodified structure. Because the EPB structure is confined to the central region of the sample planes, edge effects are minimized. Consequently

In-situ atomic layer deposition growth of Hf-oxide

International Nuclear Information System (INIS)

Karavaev, Konstantin

2010-01-01

We have grown HfO 2 on Si(001) by atomic layer deposition (ALD) using HfCl 4 , TEMAHf, TDMAHf and H 2 O as precursors. The early stages of the ALD were investigated with high-resolution photoelectron spectroscopy and X-ray absorption spectroscopy. We observed the changes occurring in the Si 2p, O 1s, Hf 4f, Hf 4d, and Cl 2p (for HfCl 4 experiment) core level lines after each ALD cycle up to the complete formation of two layers of HfO 2 . The investigation was carried out in situ giving the possibility to determine the properties of the grown film after every ALD cycle or even after a half cycle. This work focused on the advantages in-situ approach in comparison with ex-situ experiments. The study provides to follow the evolution of the important properties of HfO 2 : contamination level, density and stoichiometry, and influence of the experimental parameters to the interface layer formation during ALD. Our investigation shows that in-situ XPS approach for ALD gives much more information than ex-situ experiments. (orig.)

In-situ atomic layer deposition growth of Hf-oxide

Energy Technology Data Exchange (ETDEWEB)

Karavaev, Konstantin

2010-06-17

We have grown HfO{sub 2} on Si(001) by atomic layer deposition (ALD) using HfCl{sub 4}, TEMAHf, TDMAHf and H{sub 2}O as precursors. The early stages of the ALD were investigated with high-resolution photoelectron spectroscopy and X-ray absorption spectroscopy. We observed the changes occurring in the Si 2p, O 1s, Hf 4f, Hf 4d, and Cl 2p (for HfCl{sub 4} experiment) core level lines after each ALD cycle up to the complete formation of two layers of HfO{sub 2}. The investigation was carried out in situ giving the possibility to determine the properties of the grown film after every ALD cycle or even after a half cycle. This work focused on the advantages in-situ approach in comparison with ex-situ experiments. The study provides to follow the evolution of the important properties of HfO{sub 2}: contamination level, density and stoichiometry, and influence of the experimental parameters to the interface layer formation during ALD. Our investigation shows that in-situ XPS approach for ALD gives much more information than ex-situ experiments. (orig.)

Thermoelectric properties of doped BaHfO{sub 3}

Energy Technology Data Exchange (ETDEWEB)

Dixit, Chandra Kr., E-mail: ckparadise@gmail.com, E-mail: sharmarameshfgiet@gmail.com [Dept. of Physics, Dr. Shakuntala Misra National Rehabilitation University, Lucknow-229001, U.P India (India); Bhamu, K. C. [Department of Physics, Goa University, Goa-403 206 (India); Sharma, Ramesh, E-mail: ckparadise@gmail.com, E-mail: sharmarameshfgiet@gmail.com [Dept. of Physics, Feroze Gandhi Institute of Engineering & Technology, Raebareli-229001, U.P India (India)

2016-05-06

We have studied the structural stability, electronic structure, optical properties and thermoelectric properties of doped BaHfO{sub 3} by full potential linearized augmented plane wave (FP-LAPW) method. The electronic structure of BaHfO{sub 3} doped with Sr shows enhances the indirect band gaps of 3.53 eV, 3.58 eV. The charge density plots show strong ionic bonding in Ba-Hf, and ionic and covalent bonding between Hf and O. Calculations of the optical spectra, viz., the dielectric function, refractive index and extinction coefficient are performed for the energy range are calculated and analyzed. Thermoelectric properties of semi conducting are also reported first time. The doped BaHfO{sub 3} is approximately wide band gap semiconductor with the large p-type Seebeck coefficient. The power factor of BaHfO{sub 3} is increased with Sr doping, decreases because of low electrical resistivity and thermal conductivity.

FEM Modeling of Crack Propagation in a Model Multiphase Alloy

Institute of Scientific and Technical Information of China (English)

Lihe QIAN; Seishi NISHIDO; Hiroyuki TODA; Tosliro KOBAYASHI

2006-01-01

In this paper, several widely applied fracture criteria were first numerically examined and the crack-tip-region Jintegral criterion was confirmed to be more applicable to predict fracture angle in an elastic-plastic multiphase material. Then, the crack propagation in an idealized dendritic two-phase Al-7%Si alloy was modeled using an elastic-plastic finite element method. The variation of crack growth driving force with crack extension was also demonstrated. It is found that the crack path is significantly influenced by the presence of α-phase near the crack tip, and the crack growth driving force varies drastically from place to place. Lastly, the simulated fracture path in the two-phase model alloy was compared with the experimentally observed fracture path.

DPFFs: C2MOS Direct Path Flip-Flops for Process-Resilient Ultradynamic Voltage Scaling

Directory of Open Access Journals (Sweden)

Myeong-Eun Hwang

2016-01-01

Full Text Available We propose two master-slave flip-flops (FFs that utilize the clocked CMOS (C2MOS technique with an internal direct connection along the main signal propagation path between the master and slave latches and adopt an adaptive body bias technique to improve circuit robustness. C2MOS structure improves the setup margin and robustness while providing full compatibility with the standard cell characterization flow. Further, the direct path shortens the logic depth and thus speeds up signal propagation, which can be optimized for less power and smaller area. Measurements from test circuits fabricated in 130 nm technology show that the proposed FF operates down to 60 mV, consuming 24.7 pW while improving the propagation delay, dynamic power, and leakage by 22%, 9%, and 13%, respectively, compared with conventional FFs at the iso-output-load condition. The proposed FFs are integrated into an 8×8 FIR filter which successfully operates all the way down to 85 mV.

Contribution to the study of neutron propagation in cavities; Contribution a l'etude de la propagation des neutrons dans les cavites

Energy Technology Data Exchange (ETDEWEB)

Hasselin, G [Commissariat a l' Energie Atomique, Fontenay-aux-Roses (France). Centre d' Etudes Nucleaires

1965-07-01

In large size cavities where the dimensions of the holes are greater than the mean free path of the radiations, the neutron propagation calculations are carried out by taking into account the effect of the medium surrounding the hole using a reflection coefficient or albedo. In this work the fast neutron albedos are obtained for various materials and these results are applied for a Monte-Carlo propagation calculation. A comparison of this calculation with experimental results shows the validity of the method. (author) [French] Dans les cavites de grandes dimensions, ou les dimensions des vides sont superieures au libre parcours moyen des rayonnements, le calcul de la propagation des neutrons se fait en essayant de rendre compte de l'effet du milieu entourant le vide, par un coefficient de reflexion ou albedo. Dans cette etude, sont d'une part obtenus des albedo en neutrons rapides sur divers materiaux, d'autre part ces resultats sont appliques pour un calcul de MONTE-CARLO de propagation. La comparaison entre le calcul et l'experience montre la validite de la methode. (auteur)

A path integral for heavy-quarks in a hot plasma

CERN Document Server

Beraudo, A.; Faccioli, P.; Garberoglio, G.; 10.1016/j.nuclphysa.2010.06.007

2010-01-01

We propose a model for the propagation of a heavy-quark in a hot plasma, to be viewed as a first step towards a full description of the dynamics of heavy quark systems in a quark-gluon plasma, including bound state formation. The heavy quark is treated as a non relativistic particle interacting with a fluctuating field, whose correlator is determined by a hard thermal loop approximation. This approximation, which concerns only the medium in which the heavy quark propagates, is the only one that is made, and it can be improved. The dynamics of the heavy quark is given exactly by a quantum mechanical path integral that is calculated in this paper in the Euclidean space-time using numerical Monte Carlo techniques. The spectral function of the heavy quark in the medium is then reconstructed using a Maximum Entropy Method. The path integral is also evaluated exactly in the case where the mass of the heavy quark is infinite; one then recovers known results concerning the complex optical potential that controls the ...

Comparison between the ionospheric plasma drift and the motion of artificially induced irregularities as observed by HF backscatter radars

International Nuclear Information System (INIS)

Hanuise, C.; Hedberg, A.; Oksman, J.; Nielsen, E.; Stubbe, P.; Kopka, H.

1986-01-01

Theories of striation generation by powerful HF waves state that the irregularities should convect with the plasma, without propagating through the medium. This prediction has been checked by observing, with the two SAFARI radars, the backscatter from striations generated in the F-region by the HEATING facility at Tromso. The magnitude and direction of the Doppler velocity of the fluctuations is derived from the line-of-sight velocities measured by the two HF radar stations. The comparison between the electric field, derived from SAFARI, and the E-region current deduced from magnetometer data show that the magnitudes are well correlated. The directions of the velocity and this current are, however, not exactly antiparallel. Another comparison between the SAFARI F-region Doppler velocity and the E-region drift measured by STARE shows, on the average, a good agreement between the estimates. The experimental evidence therefore agrees with the theoretical suggestion that the irregularity motion should be the ExB drift

Blue functions: probability and current density propagators in non-relativistic quantum mechanics

International Nuclear Information System (INIS)

Withers, L P Jr

2011-01-01

Like a Green function to propagate a particle's wavefunction in time, a Blue function is introduced to propagate the particle's probability and current density. Accordingly, the complete Blue function has four components. They are constructed from path integrals involving a quantity like the action that we call the motion. The Blue function acts on the displaced probability density as the kernel of an integral operator. As a result, we find that the Wigner density occurs as an expression for physical propagation. We also show that, in quantum mechanics, the displaced current density is conserved bilocally (in two places at one time), as expressed by a generalized continuity equation. (paper)

Radio-wave propagation for space communications systems

Science.gov (United States)

Ippolito, L. J.

1981-01-01

The most recent information on the effects of Earth's atmosphere on space communications systems is reviewed. The design and reliable operation of satellite systems that provide the many applications in space which rely on the transmission of radio waves for communications and scientific purposes are dependent on the propagation characteristics of the transmission path. The presence of atmospheric gases, clouds, fog, precipitation, and turbulence causes uncontrolled variations in the signal characteristics. These variations can result in a reduction of the quality and reliability of the transmitted information. Models and other techniques are used in the prediction of atmospheric effects as influenced by frequency, geography, elevation angle, and type of transmission. Recent data on performance characteristics obtained from direct measurements on satellite links operating to above 30 GHz have been reviewed. Particular emphasis has been placed on the effects of precipitation on the Earth/space path, including rain attenuation, and ice particle depolarization. Other factors are sky noise, antenna gain degradation, scintillations, and bandwidth coherence. Each of the various propagation factors has an effect on design criteria for communications systems. These criteria include link reliability, power margins, noise contribution, modulation and polarization factors, channel cross talk, error rate, and bandwidth limitations.

Ferromagnetic characteristics of HfFe2

International Nuclear Information System (INIS)

Novakovic, N.; Belosevic-Cavor, J.; Cekic, B.; Manasijevic, M.; Milosevic, Z. . E-mail address of correspoding author: novnik@rt270.vin.bg.ac.yu; Novakovic, N.)

2003-01-01

The magnetic hyperfine fields at 181 Ta ion-probe sites in the HfFe 2 polycrystalline binary compound were measured using the time-differential perturbed angular correlation (TDPAC) method. Measurements were performed in the absence of polarizing external magnetic field, at room temperature. The existence of two different structures, dominant cubic MgCu 2 -type and hexagonal MgZn 2 -type in our HfFe 2 sample was refined. Both structures are ferromagnetic with Curie temperatures, which differ significantly (588 K for MgCu 2 and 427 K for MgZn 2 ). The corresponding values of hyperfine fields are H hf 13.8±0.1 T for MgCu 2 -type structure and H hf = 8.0±0.2 T for MgZn 2 -type structure. Calculations using LAPW-Wien 97 program package are in progress and preliminary results are in good agreement with experiment. The analysis includes qualitative explanation of the exchange interactions mechanism between magnetic dipole moment of the observed 181 Ta ion-probe and magnetic dipole moments of the nearest neighbours on the corresponding coordination polyhedra. All these results will be published recently. (author)

Reinforcement against crack propagation of PWR absorbers by development of boron-carbon-hafnium composites

International Nuclear Information System (INIS)

Provot, B.; Herter, P.

2000-01-01

In order to improve the mechanical behaviour of materials used as neutron absorbers in nuclear reactors, we have developed CERCER or CERMET composites with boron and hafnium. Thus a new composite B 4 C/HfB 2 has been especially studied. We have identified three kinds of degradation under irradiation (thermal gradient, swelling due to fission products and accidental corrosion) that induce imposed deformations cracking phenomena. Mechanical behaviour and crack propagation resistance have been studied by ball-on-three-balls and double torsion tests. A special device was developed to enable crack propagation and associated stress intensity factor measurements. Effects of structure and of a second phase are underline. First results show that these materials present crack initiation and propagation resistance much higher than pure boron carbide or hafnium diboride. We observe R-Curves effects, crack bridging or branching, crack arrests, and toughness increases that we can relate respectively to the composite structures. (author)

Nanosized Hydroxyapatite Precipitation on the Ti—30Ta—xHf Alloys.

Science.gov (United States)

Lee, Kang; Jang, Jae- In; Han-Cheol, Choe

2017-04-01

In this study, we prepared hydroxyapatite (HAp) layer on the alkali treated Ti–30Ta–xHf alloys using electrochemical deposition method. Ti–30Ta–xHf alloys was anodized in 5 M NaOH solution at 0.3 A for 10 min. Alkali treated Ti–30Ta–xHf surface formed by anodization step which acted as templates and anchorage for growth of the HAp during subsequent pulsed electrochemical deposition process at 85 °C. The phase and morphologies of deposited HAp layer were affected by the Hf contents of Ti–30Ta–xHf alloys. The nano-scale rod-like HAp layer was formed on untreated Ti–30Ta–xHf alloys with partially low crystallinity. In the case of alkali treated Ti–30Ta–xHf, nano-sized needle-like layers were transferred to nano-flake surface and denser morphology as Hf content increased.

HF-voltage testing of accelerating system functional model

International Nuclear Information System (INIS)

Gladkov, A.V.; Stepanov, V.B.

1989-01-01

Owing to ambiguity in interpreting the notion of the electron strength of the operating HF device in an acceleator a technique of measurements and result processing, based on statistical analysis of the data is suggested. Experimental testing on electric strength of structures with HF focusing was carried out using a bench in the form of a cylindrical vacuum container inside which a double H-resonator with HF quadrupole electrodes without surface modulation was installed. The dependences obtained permit to evaluate the bahaviour of the HF device from the viewpoint of electric strength and radiation hazard for the whole range of possible values of voltage on the basis of data on the frequency of breakdowns and radiation situation only in one experimental point. 12 refs.; 8 figs

The isobutylene-isobutane alkylation process in liquid HF revisited.

Science.gov (United States)

Esteves, P M; Araújo, C L; Horta, B A C; Alvarez, L J; Zicovich-Wilson, C M; Ramírez-Solís, A

2005-07-07

Details on the mechanism of HF catalyzed isobutylene-isobutane alkylation were investigated. On the basis of available experimental data and high-level quantum chemical calculations, a detailed reaction mechanism is proposed taking into account solvation effects of the medium. On the basis of our computational results, we explain why the density of the liquid media and stirring rates are the most important parameters to achieve maximum yield of alkylate, in agreement with experimental findings. The ab initio Car-Parrinello molecular dynamics calculations show that isobutylene is irreversibly protonated in the liquid HF medium at higher densities, leading to the ion pair formation, which is shown to be a minimum on the potential energy surface after optimization using periodic boundary conditions. The HF medium solvates preferentially the fluoride anion, which is found as solvated [FHF](-) or solvated F(-.)(HF)(3). On the other hand, the tert-butyl cation is weakly solvated, where the closest HF molecules appear at a distance of about 2.9 Angstrom with the fluorine termination of an HF chain.

Sequential sputtered Co-HfO{sub 2} granular films

Energy Technology Data Exchange (ETDEWEB)

Chadha, M.; Ng, V.

2017-03-15

A systematic study of magnetic, magneto-transport and micro-structural properties of Co-HfO{sub 2} granular films fabricated by sequential sputtering is presented. We demonstrate reduction in ferromagnetic-oxide formation by using HfO{sub 2} as the insulting matrix. Microstructure evaluation of the films showed that the film structure consisted of discrete hcp-Co grains embedded in HfO{sub 2} matrix. Films with varying compositions were prepared and their macroscopic properties were studied. We correlate the variation in these properties to the variation in film microstructure. Our study shows that Co-HfO{sub 2} films with reduced cobalt oxide and varying properties can be prepared using sequential sputtering technique. - Highlights: • Co-HfO{sub 2} granular films were prepared using sequential sputtering. • A reduction in ferromagnetic-oxide formation is observed. • Co-HfO{sub 2} films display superparamagnetism and tunnelling magneto-resistance. • Varying macroscopic properties were achieved by changing film composition. • Applications can be found in moderate MR sensors and high –frequency RF devices.

Asynchronous cracking with dissimilar paths in multilayer graphene.

Science.gov (United States)

Jang, Bongkyun; Kim, Byungwoon; Kim, Jae-Hyun; Lee, Hak-Joo; Sumigawa, Takashi; Kitamura, Takayuki

2017-11-16

Multilayer graphene consists of a stack of single-atomic-thick monolayer graphene sheets bound with π-π interactions and is a fascinating model material opening up a new field of fracture mechanics. In this study, fracture behavior of single-crystalline multilayer graphene was investigated using an in situ mode I fracture test under a scanning electron microscope, and abnormal crack propagation in multilayer graphene was identified for the first time. The fracture toughness of graphene was determined from the measured load-displacement curves and the realistic finite element modelling of specimen geometries. Nonlinear fracture behavior of the multilayer graphene is discussed based on nonlinear elastic fracture mechanics. In situ scanning electron microscope images obtained during the fracture test showed asynchronous crack propagation along independent paths, causing interlayer shear stress and slippages. We also found that energy dissipation by interlayer slippages between the graphene layers is the reason for the enhanced fracture toughness of multilayer graphene. The asynchronous cracking with independent paths is a unique cracking and toughening mechanism for single-crystalline multilayer graphene, which is not observed for the monolayer graphene. This could provide a useful insight for the design and development of graphene-based composite materials for structural applications.

HF Interference, Procedures and Tools (Interferences HF, procedures et outils)

Science.gov (United States)

2007-06-01

the actual ambient noise floor situation. Besides these HF radio links, special units such as crisis reaction forces are using low power radios for...the origin point on the ground. For ease of arithmetic and typography , the latter option is preferable. The dipole-modelled PLT is located at x = H1

Observations of an ionospheric perturbation arising from the Coalinga earthquake of May 2, 1983

International Nuclear Information System (INIS)

Wolcott, J.H.; Simons, D.J.; Lee, D.D.; Nelson, R.A.

1984-01-01

An ionospheric perturbation that was produced by the Coalinga earthquake of May 2, 1983, was detected by a network of high-frequency radio links in northern California. The ionospheric refraction regions of all five HF propagation paths, at distances between 160 and 285 km (horizontal range) from the epicenter, were affected by a ground-motion-induced acoustic pulse that propagated to ionospheric heights. The acoustic pulse was produced by the earthquake-induced seismic waves rather than the vertical ground motion above the epicenter. These observations appear to be the first ionospheric disturbances to be reported this close to an earthquake epicenter

Lateral propagation of MeV electrons generated by femtosecond laser irradiation

International Nuclear Information System (INIS)

Seely, J. F.; Szabo, C. I.; Audebert, P.; Brambrink, E.; Tabakhoff, E.; Hudson, L. T.

2010-01-01

The propagation of MeV electrons generated by intense (≅10 20 W/cm 2 ) femtosecond laser irradiation, in the lateral direction perpendicular to the incident laser beam, was studied using targets consisting of irradiated metal wires and neighboring spectator wires embedded in electrically conductive (aluminum) or resistive (Teflon) substrates. The K shell spectra in the energy range 40-60 keV from wires of Gd, Dy, Hf, and W were recorded by a transmission crystal spectrometer. The spectra were produced by 1s electron ionization in the irradiated wire and by energetic electron propagation through the substrate material to the spectator wire of a different metal. The electron range and energy were determined from the relative K shell emissions from the irradiated and spectator wires separated by varying substrate lateral distances of up to 1 mm. It was found that electron propagation through Teflon was inhibited, compared to aluminum, implying a relatively weak return current and incomplete space-charge neutralization. The energetic electron propagation in the direction parallel to the electric field of the laser beam was larger than perpendicular to the electric field. Energetic electron production was lower when directly irradiating aluminum or Teflon compared to irradiating the heavy metal wires. These experiments are important for the determination of the energetic electron production mechanism and for understanding lateral electron propagation that can be detrimental to fast-ignition fusion and hard x-ray backlighter radiography.

Contribution to the study of neutron propagation in cavities; Contribution a l'etude de la propagation des neutrons dans les cavites

Energy Technology Data Exchange (ETDEWEB)

Hasselin, G. [Commissariat a l' Energie Atomique, Fontenay-aux-Roses (France). Centre d' Etudes Nucleaires

1965-07-01

In large size cavities where the dimensions of the holes are greater than the mean free path of the radiations, the neutron propagation calculations are carried out by taking into account the effect of the medium surrounding the hole using a reflection coefficient or albedo. In this work the fast neutron albedos are obtained for various materials and these results are applied for a Monte-Carlo propagation calculation. A comparison of this calculation with experimental results shows the validity of the method. (author) [French] Dans les cavites de grandes dimensions, ou les dimensions des vides sont superieures au libre parcours moyen des rayonnements, le calcul de la propagation des neutrons se fait en essayant de rendre compte de l'effet du milieu entourant le vide, par un coefficient de reflexion ou albedo. Dans cette etude, sont d'une part obtenus des albedo en neutrons rapides sur divers materiaux, d'autre part ces resultats sont appliques pour un calcul de MONTE-CARLO de propagation. La comparaison entre le calcul et l'experience montre la validite de la methode. (auteur)

Search for chemical separations of the element 106 homologues in HF and HF-HCl media

International Nuclear Information System (INIS)

Trubert, D.; Monroy-Guzman, F.; Hussonnois, M.; Brillard, L.; Le Naour, C.; Constantinescu, O.

1996-01-01

In order to study the chemical properties of element 263 106 in aqueous media, fast, efficient and reproducible chromatographic separations were tested on its assumed homologous: Mo, W and U. Corroborative static and dynamic off-line experiments have shown that after fixation of these three elements on anion-exchange resin in HF medium, selective elution could be achieved by using suitable concentration of HCl - HF and HCl solutions. Separations of short-lived W isotopes, produced through heavy ion irradiation were also performed on-line. (author). 27 refs., 14 figs

Direct quantum mechanical calculation of the F + H{sub 2} {yields} HF + H thermal rate constant

Energy Technology Data Exchange (ETDEWEB)

Moix, Marc [Computer Simulation and Modeling (COSMO) Lab, Parc Cientific de Barcelona, Josep Samitier 5, 08028 Barcelona (Spain); Institut de Quimica Teorica i Computacional de la UB (IQTCUB), Universitat de Barcelona (Spain); Huarte-Larranaga, Fermin [Computer Simulation and Modeling (COSMO) Lab, Parc Cientific de Barcelona, Josep Samitier 5, 08028 Barcelona (Spain); Institut de Quimica Teorica i Computacional de la UB (IQTCUB), Universitat de Barcelona (Spain)], E-mail: fhuarte@pcb.ub.es

2008-07-03

Accurate full-dimensional quantum mechanical thermal rate constant values have been calculated for the F+H{sub 2}{yields}HF+H reaction on the Stark-Werner ab initio potential energy surface. These calculations are based on a flux correlation functions and employ a rigorous statistical sampling scheme to account for the overall rotation and the MCTDH scheme for the wave packet propagation. Our results shed some light on discrepancies on the thermal rate found for previous flux correlation based calculations with respect to accurate reactive scattering results. The resonance pattern of the all-J cumulative reaction probability is analyzed in terms of the partial wave contributions.

Integrating cell on chip—Novel waveguide platform employing ultra-long optical paths

Directory of Open Access Journals (Sweden)

Lena Simone Fohrmann

2017-09-01

Full Text Available Optical waveguides are the most fundamental building blocks of integrated optical circuits. They are extremely well understood, yet there is still room for surprises. Here, we introduce a novel 2D waveguide platform which affords a strong interaction of the evanescent tail of a guided optical wave with an external medium while only employing a very small geometrical footprint. The key feature of the platform is its ability to integrate the ultra-long path lengths by combining low propagation losses in a silicon slab with multiple reflections of the guided wave from photonic crystal (PhC mirrors. With a reflectivity of 99.1% of our tailored PhC-mirrors, we achieve interaction paths of 25 cm within an area of less than 10 mm2. This corresponds to 0.17 dB/cm effective propagation which is much lower than the state-of-the-art loss of approximately 1 dB/cm of single mode silicon channel waveguides. In contrast to conventional waveguides, our 2D-approach leads to a decay of the guided wave power only inversely proportional to the optical path length. This entirely different characteristic is the major advantage of the 2D integrating cell waveguide platform over the conventional channel waveguide concepts that obey the Beer-Lambert law.

Integrating cell on chip—Novel waveguide platform employing ultra-long optical paths

Science.gov (United States)

Fohrmann, Lena Simone; Sommer, Gerrit; Pitruzzello, Giampaolo; Krauss, Thomas F.; Petrov, Alexander Yu.; Eich, Manfred

2017-09-01

Optical waveguides are the most fundamental building blocks of integrated optical circuits. They are extremely well understood, yet there is still room for surprises. Here, we introduce a novel 2D waveguide platform which affords a strong interaction of the evanescent tail of a guided optical wave with an external medium while only employing a very small geometrical footprint. The key feature of the platform is its ability to integrate the ultra-long path lengths by combining low propagation losses in a silicon slab with multiple reflections of the guided wave from photonic crystal (PhC) mirrors. With a reflectivity of 99.1% of our tailored PhC-mirrors, we achieve interaction paths of 25 cm within an area of less than 10 mm2. This corresponds to 0.17 dB/cm effective propagation which is much lower than the state-of-the-art loss of approximately 1 dB/cm of single mode silicon channel waveguides. In contrast to conventional waveguides, our 2D-approach leads to a decay of the guided wave power only inversely proportional to the optical path length. This entirely different characteristic is the major advantage of the 2D integrating cell waveguide platform over the conventional channel waveguide concepts that obey the Beer-Lambert law.

HF band filter bank multi-carrier spread spectrum

Energy Technology Data Exchange (ETDEWEB)

Laraway, Stephen Andrew; Moradi, Hussein; Farhang-Boroujeny, Behrouz

2015-10-01

Abstract—This paper describes modifications to the filter bank multicarrier spread spectrum (FB-MC-SS) system, that was presented in [1] and [2], to enable transmission of this waveform in the HF skywave channel. FB-MC-SS is well suited for the HF channel because it performs well in channels with frequency selective fading and interference. This paper describes new algorithms for packet detection, timing recovery and equalization that are suitable for the HF channel. Also, an algorithm for optimizing the peak to average power ratio (PAPR) of the FBMC- SS waveform is presented. Application of this algorithm results in a waveform with low PAPR. Simulation results using a wide band HF channel model demonstrate the robustness of this system over a wide range of delay and Doppler spreads.

Nuclear quadrupole interactions in ferroelectric compounds of HF181

International Nuclear Information System (INIS)

Kunzler, J.V.

1971-01-01

Measurements of nuclear quadrupole interaction constants in perovkite-type compounds of PbHfO 3 , SnhfO 3 , CaHfO 3 e SrHfO 3 have been performed using the perturbed angular correlation technique. A range of fundamental frequencies from 150 to 550 Megaradians persecond was determined. The variation of quadrupole constants has been discussed through the molecular orbital theory

Lu-Hf and Sm-Nd garnet geochronology

DEFF Research Database (Denmark)

Smit, Matthijs Arjen; Scherer, Erik E.; Mezger, Klaus

2013-01-01

To investigate the systematics of the 176Lu–176Hf and 147Sm–143Nd garnet chronometers, we performed REE and isotope analyses on garnet crystals of different size (0.55–3.1 mm radius) from a single granulite specimen (Archean Pikwitonei Granulite Domain, Manitoba, Canada). The Lu–Hf dates are simi...

Ionospheric modification induced by high-power HF transmitters: a potential for extended range VHF--UHF communications and plasma physics research

International Nuclear Information System (INIS)

Utlaut, W.F.

1975-01-01

When the ionized upper atmosphere of the earth is illuminated by high-power HF radio waves at appropriate frequencies, the temperature of electrons in the ionosphere can be raised substantially. In addition, radio waves with sufficient energy cause parametric instabilities that generate a spectrum of intense plasma waves. Observations of these phenomena have produced new understanding of plasma processes. One consequence of heating and plasma wave generation is that irregularities are formed in the electron distribution which are aligned with the earth's magnetic field. Because of this, a scatterer of large radar cross section is produced, which scatters HF through UHF communication signals over long distance paths, that would not otherwise be normally possible by ionospheric means. Results of radio, radar, communication, and photometric experiments that explored the characteristics of the volume of ionosphere which has been intentionally modified, temporarily, above facilities near Boulder (Platteville), Colo., and at Arecibo, Puerto Rico are summarized

Infrared singularities of fermion propagator and their connection with the Wilson loop

International Nuclear Information System (INIS)

Sissakyan, A.N.; Skachkov, N.B.; Shevchenko, O.Yu.

1987-01-01

The factorization of infrared singularities of gauge-invariant spinor propagator is proved in the framework of QED. It turns out that this infrared factor coincides with the Wilson loop and accumulates all the dependence on the form of the path of the initial Green function

Thermoelectric and Structural Properties of Zr-/Hf-Based Half-Heusler Compounds Produced at a Large Scale

Science.gov (United States)

Zillmann, D.; Waag, A.; Peiner, E.; Feyand, M.-H.; Wolyniec, A.

2018-02-01

The half-Heusler (HH) systems are promising candidates for thermoelectric (TE) applications since they have shown high figures of merit ( zT) of ˜ 1, which are directly related to the energy conversion efficiency. To use HH compounds for TE devices, the materials must be phase-stable at operating temperatures up to 600°C. Currently, only a few HH compositions are available in large quantities. Hence, we focus on the TE and structural properties of three commercially available Zr-/Hf-based HH compounds in this publication. In particular, we evaluate the thermal conductivities and the figures of merit and critically discuss uncertainties and propagation error in the measurements. We find thermal conductivities of less than 6.0 W K^{-1}m^{-1} for all investigated materials and notably high figures of merit of 0.93 and 0.60 for n- and p-type compounds, respectively, at 600°C. Additionally, our investigations reveal that the grain structures of all materials also contain secondary phases like HfO2, Sn-Ni and Ti-Zr-Sn rich phases while an additional SnO_2 phase was found following several hours of harsh heat treatment at 800°C.

A method of signal transmission path analysis for multivariate random processes

International Nuclear Information System (INIS)

Oguma, Ritsuo

1984-04-01

A method for noise analysis called ''STP (signal transmission path) analysis'' is presentd as a tool to identify noise sources and their propagation paths in multivariate random proceses. Basic idea of the analysis is to identify, via time series analysis, effective network for the signal power transmission among variables in the system and to make use of its information to the noise analysis. In the present paper, we accomplish this through two steps of signal processings; first, we estimate, using noise power contribution analysis, variables which have large contribution to the power spectrum of interest, and then evaluate the STPs for each pair of variables to identify STPs which play significant role for the generated noise to transmit to the variable under evaluation. The latter part of the analysis is executed through comparison of partial coherence function and newly introduced partial noise power contribution function. This paper presents the procedure of the STP analysis and demonstrates, using simulation data as well as Borssele PWR noise data, its effectiveness for investigation of noise generation and propagation mechanisms. (author)

Experimental Investigation of Some Effects of Multipath Propagation on a Line-of-Sight Path at 14 GHz

DEFF Research Database (Denmark)

Stephansen, E.; Mogensen, G.

1979-01-01

A microwave line-of-sight propagation experiment is carried out in Denmark at frequencies around 14 GHz. Results from long term measurements of multipath propagation are presented. The multipath fade durations are shown to be log-normally distributed. The level dependence of the probability of fa...

Classical and quantum dynamics from classical paths to path integrals

CERN Document Server

Dittrich, Walter

2017-01-01

Graduate students who wish to become familiar with advanced computational strategies in classical and quantum dynamics will find in this book both the fundamentals of a standard course and a detailed treatment of the time-dependent oscillator, Chern-Simons mechanics, the Maslov anomaly and the Berry phase, to name just a few topics. Well-chosen and detailed examples illustrate perturbation theory, canonical transformations and the action principle, and demonstrate the usage of path integrals. The fifth edition has been revised and enlarged to include chapters on quantum electrodynamics, in particular, Schwinger’s proper time method and the treatment of classical and quantum mechanics with Lie brackets and pseudocanonical transformations. It is shown that operator quantum electrodynamics can be equivalently described with c-numbers, as demonstrated by calculating the propagation function for an electron in a prescribed classical electromagnetic field.

Path integral representations in noncommutative quantum mechanics and noncommutative version of Berezin-Marinov action

Energy Technology Data Exchange (ETDEWEB)

Gitman, D.M. [Universidade de Sao Paulo, Instituto de Fisica, Sao Paulo, SP (Brazil); Kupriyanov, V.G. [Universidade de Sao Paulo, Instituto de Fisica, Sao Paulo, SP (Brazil); Tomsk State University, Physics Department, Tomsk (Russian Federation)

2008-03-15

It is known that the actions of field theories on a noncommutative space-time can be written as some modified (we call them {theta}-modified) classical actions already on the commutative space-time (introducing a star product). Then the quantization of such modified actions reproduces both space-time noncommutativity and the usual quantum mechanical features of the corresponding field theory. In the present article, we discuss the problem of constructing {theta}-modified actions for relativistic QM. We construct such actions for relativistic spinless and spinning particles. The key idea is to extract {theta}-modified actions of the relativistic particles from path-integral representations of the corresponding noncommutative field theory propagators. We consider the Klein-Gordon and Dirac equations for the causal propagators in such theories. Then we construct for the propagators path-integral representations. Effective actions in such representations we treat as {theta}-modified actions of the relativistic particles. To confirm the interpretation, we canonically quantize these actions. Thus, we obtain the Klein-Gordon and Dirac equations in the noncommutative field theories. The {theta}-modified action of the relativistic spinning particle is just a generalization of the Berezin-Marinov pseudoclassical action for the noncommutative case. (orig.)

A Lightweight Radio Propagation Model for Vehicular Communication in Road Tunnels.

Directory of Open Access Journals (Sweden)

Muhammad Ahsan Qureshi

Full Text Available Radio propagation models (RPMs are generally employed in Vehicular Ad Hoc Networks (VANETs to predict path loss in multiple operating environments (e.g. modern road infrastructure such as flyovers, underpasses and road tunnels. For example, different RPMs have been developed to predict propagation behaviour in road tunnels. However, most existing RPMs for road tunnels are computationally complex and are based on field measurements in frequency band not suitable for VANET deployment. Furthermore, in tunnel applications, consequences of moving radio obstacles, such as large buses and delivery trucks, are generally not considered in existing RPMs. This paper proposes a computationally inexpensive RPM with minimal set of parameters to predict path loss in an acceptable range for road tunnels. The proposed RPM utilizes geometric properties of the tunnel, such as height and width along with the distance between sender and receiver, to predict the path loss. The proposed RPM also considers the additional attenuation caused by the moving radio obstacles in road tunnels, while requiring a negligible overhead in terms of computational complexity. To demonstrate the utility of our proposed RPM, we conduct a comparative summary and evaluate its performance. Specifically, an extensive data gathering campaign is carried out in order to evaluate the proposed RPM. The field measurements use the 5 GHz frequency band, which is suitable for vehicular communication. The results demonstrate that a close match exists between the predicted values and measured values of path loss. In particular, an average accuracy of 94% is found with R2 = 0.86.

Solid phase crystallisation of HfO2 thin films

International Nuclear Information System (INIS)

Modreanu, M.; Sancho-Parramon, J.; O'Connell, D.; Justice, J.; Durand, O.; Servet, B.

2005-01-01

In this paper, we report on the solid phase crystallisation of carbon-free HfO 2 thin films deposited by plasma ion assisted deposition (PIAD). After deposition, the HfO 2 films were annealed in N 2 ambient for 3 h at 350, 550 and 750 deg. C. Several characterisation techniques including X-ray reflectometry (XRR), X-ray diffraction (XRD), spectroscopic ellipsometry (SE) and atomic force microscopy (AFM) were used for the physical characterisation of as-deposited and annealed HfO 2 . XRD has revealed that the as-deposited HfO 2 film is in an amorphous-like state with only traces of crystalline phase and that the annealed films are in a highly crystalline state. These results are in good agreement with the SE results showing an increase of refractive index by increasing the annealing temperature. XRR results show a significant density gradient over the as-deposited film thickness, which is characteristic of the PIAD method. The AFM measurements show that the HfO 2 layers have a smooth surface even after annealing at 750 deg. C. The present study demonstrates that the solid phase crystallisation of HfO 2 PIAD thin films starts at a temperature as low as 550 deg. C

A Study on the Radio Propagation in the Korean Ionosphere

Directory of Open Access Journals (Sweden)

Seok-Hee Bae

1992-06-01

Full Text Available The effects of the ionosphere on the radio wave propagation are scattering of radio waves, attenuation, angle error, ranging error, and time delay. If ionospheric conditions are suitable, the charged particles can remove energy from radio waves and thus attenuate the signal. Also, a radio wave traveling a path along which the electron density is not constant undergoes changes in direction, position and time of propagation. The present study is based on Korean ionospheric data obtained at the AnYong Radio Research Institute from Jan. 1985 through Oct. 1989. The data are used to simulate the Korean ionosphere following the Chapman law. The effects of the model ionosphere on the radio wave propagation, such as the angle, position error, time delay, and the attenuation, are studies for the various cases of the wave frequency and the altitude.

Mechanical alloying of Hf and Fe powders

International Nuclear Information System (INIS)

Mendoza Zelis, L.; Crespo, E.; Creus, M.; Damonte, L.C.; Sanchez, F.H.; Punte, G.

1994-01-01

Pure crystalline Hf and Fe powders were mixed and milled under an argon atmosphere. The evolution of the system with milling time was followed with Moessbauer effect spectroscopy and X-ray diffraction. The results indicate that in the first stages an amorphous Fe-rich alloy was gradually formed together with a solid solution of Hf in Fe beyond the solubility limit. (orig.)

Polarity-specific high-level information propagation in neural networks.

Science.gov (United States)

Lin, Yen-Nan; Chang, Po-Yen; Hsiao, Pao-Yueh; Lo, Chung-Chuan

2014-01-01

Analyzing the connectome of a nervous system provides valuable information about the functions of its subsystems. Although much has been learned about the architectures of neural networks in various organisms by applying analytical tools developed for general networks, two distinct and functionally important properties of neural networks are often overlooked. First, neural networks are endowed with polarity at the circuit level: Information enters a neural network at input neurons, propagates through interneurons, and leaves via output neurons. Second, many functions of nervous systems are implemented by signal propagation through high-level pathways involving multiple and often recurrent connections rather than by the shortest paths between nodes. In the present study, we analyzed two neural networks: the somatic nervous system of Caenorhabditis elegans (C. elegans) and the partial central complex network of Drosophila, in light of these properties. Specifically, we quantified high-level propagation in the vertical and horizontal directions: the former characterizes how signals propagate from specific input nodes to specific output nodes and the latter characterizes how a signal from a specific input node is shared by all output nodes. We found that the two neural networks are characterized by very efficient vertical and horizontal propagation. In comparison, classic small-world networks show a trade-off between vertical and horizontal propagation; increasing the rewiring probability improves the efficiency of horizontal propagation but worsens the efficiency of vertical propagation. Our result provides insights into how the complex functions of natural neural networks may arise from a design that allows them to efficiently transform and combine input signals.

Degenerated graphite nodules influence on fatigue crack paths in a ferritic ductile cast iron

Directory of Open Access Journals (Sweden)

Francesco Iacoviello

2015-10-01

Full Text Available ferritic to a completely pearlitic matrix, and they are widely used for many applications (e.g. wheels, gears, crankshafts in cars, exhaust manifolds, valves, flywheels, boxes bearings, hubs, shafts, valves, flanges, pipelines .... Considering the graphite elements, their morphology can be considered as degenerated when its nodularity is too low and this can be due to different causes (e.g., a partially failed nodularization process or a wrong inoculant. In this work, a ferritic DCI with degenerated nodules was obtained by means of an annealing treatment and the fatigue crack propagation resistance was investigated by means of fatigue crack propagation tests performed according to ASTM E647, focusing on the influence of degenerated graphite nodules on the fatigue crack paths. This analysis was performed both analysing the crack path profile by means of a scanning electron microscope (SEM and by means of a SEM fracture surfaces analysis

Fatigue crack propagation in aluminum-lithium alloys

Science.gov (United States)

Rao, K. T. V.; Ritchie, R. O.; Piascik, R. S.; Gangloff, R. P.

1989-01-01

The principal mechanisms which govern the fatigue crack propagation resistance of aluminum-lithium alloys are investigated, with emphasis on their behavior in controlled gaseous and aqueous environments. Extensive data describe the growth kinetics of fatigue cracks in ingot metallurgy Al-Li alloys 2090, 2091, 8090, and 8091 and in powder metallurgy alloys exposed to moist air. Results are compared with data for traditional aluminum alloys 2024, 2124, 2618, 7075, and 7150. Crack growth is found to be dominated by shielding from tortuous crack paths and resultant asperity wedging. Beneficial shielding is minimized for small cracks, for high stress ratios, and for certain loading spectra. While water vapor and aqueous chloride environments enhance crack propagation, Al-Li-Cu alloys behave similarly to 2000-series aluminum alloys. Cracking in water vapor is controlled by hydrogen embrittlement, with surface films having little influence on cyclic plasticity.

Validation of the CUTLASS HF radar gravity wave observing capability using EISCAT CP-1 data

Directory of Open Access Journals (Sweden)

N. F. Arnold

1998-10-01

Full Text Available Quasi-periodic fluctuations in the returned ground-scatter power from the SuperDARN HF radars have been linked to the passage of medium-scale gravity waves. We have applied a technique that extracts the first radar range returns from the F-region to study the spatial extent and characteristics of these waves in the CUTLASS field-of-view. Some ray tracing was carried out to test the applicability of this method. The EISCAT radar facility at Tromsø is well within the CUTLASS field-of-view for these waves and provides a unique opportunity to assess independently the ability of the HF radars to derive gravity wave information. Results from 1st March, 1995, where the EISCAT UHF radar was operating in its CP-1 mode, demonstrate that the radars were in good agreement, especially if one selects the electron density variations measured by EISCAT at around 235 km. CUTLASS and EISCAT gravity wave observations complement each other; the former extends the spatial field of view considerably, whilst the latter provides detailed vertical information about a range of ionospheric parameters.Key words. Ionosphere (ionosphere – atmosphere interactions · Meteorology and atmospheric dynamics (thermospheric dynamics · Radio science (ionospheric propagations

Validation of the CUTLASS HF radar gravity wave observing capability using EISCAT CP-1 data

Directory of Open Access Journals (Sweden)

N. F. Arnold

Full Text Available Quasi-periodic fluctuations in the returned ground-scatter power from the SuperDARN HF radars have been linked to the passage of medium-scale gravity waves. We have applied a technique that extracts the first radar range returns from the F-region to study the spatial extent and characteristics of these waves in the CUTLASS field-of-view. Some ray tracing was carried out to test the applicability of this method. The EISCAT radar facility at Tromsø is well within the CUTLASS field-of-view for these waves and provides a unique opportunity to assess independently the ability of the HF radars to derive gravity wave information. Results from 1st March, 1995, where the EISCAT UHF radar was operating in its CP-1 mode, demonstrate that the radars were in good agreement, especially if one selects the electron density variations measured by EISCAT at around 235 km. CUTLASS and EISCAT gravity wave observations complement each other; the former extends the spatial field of view considerably, whilst the latter provides detailed vertical information about a range of ionospheric parameters.

Key words. Ionosphere (ionosphere – atmosphere interactions · Meteorology and atmospheric dynamics (thermospheric dynamics · Radio science (ionospheric propagations

Local time distribution of the SSC-associated HF-Doppler frequency shifts

International Nuclear Information System (INIS)

Kikuchi, T.; Sugiuchi, H.; Ishimine, T.

1985-01-01

The HF-Doppler frequency shift observed at the storm's sudden commencement is composed of a frequency increase (+) and decrease (-), and classified into four types, SCF(+ -), SCF(- +), SCF(+) and SCF(-). Since the latter two types are special cases of the former two types, two different kinds of electrical field exist in the F region and cause the ExB drift motion of plasma. HUANG (1976) interpreted the frequency increase of SCF(+ -) as due to the westward induction electric field proportional to delta H/ delta t and the succeeding frequency decrease due to the eastward conduction electric field which produces ionospheric currents responsible for the magnetic increase on the ground. In spite of his success in interpreting the SCF(+ -), some other interpretations are needed for the explanation of the whole set of SCF's, particularly SCF(- +). Local time distributions of the SCF's are derived from 41 SCF's which are observed on the HF standard signal (JJY) as received in Okinawa (path length =1600 km) and Kokubunji (60 km). It is shown that the SCF(+ -) appears mainly during the day, whereas the SCF(- +) is observed during the night. The results indicate that the preliminary frequency shift (+) of SCF(+ -) and (-) of SCF(- +) is caused by a westward electric field in the dayside hemisphere, while by an eastward electric field in the nightside hemisphere. The main frequency shift (-) of SCF(+ -) and (+) of SCF(- +) is caused by the reversed electric field. Consequently, the preliminary frequency shift is caused by the dusk-to-dawn electric field, while the main frequency shift by the dawn-to-dusk electric field

Local time distribution of the SSC-associated HF-Doppler frequency shifts

Science.gov (United States)

Kikuchi, T.; Sugiuchi, H.; Ishimine, T.

1985-01-01

The HF-Doppler frequency shift observed at the storm's sudden commencement is composed of a frequency increase (+) and decrease (-), and classified into four types, SCF(+ -), SCF(- +), SCF(+) and SCF(-). Since the latter two types are special cases of the former two types, two different kinds of electrical field exist in the F region and cause the ExB drift motion of plasma. HUANG (1976) interpreted the frequency increase of SCF(+ -) as due to the westward induction electric field proportional to delta H/ delta t and the succeeding frequency decrease due to the eastward conduction electric field which produces ionospheric currents responsible for the magnetic increase on the ground. In spite of his success in interpreting the SCF(+ -), some other interpretations are needed for the explanation of the whole set of SCF's, particularly SCF(- +). Local time distributions of the SCF's are derived from 41 SCF's which are observed on the HF standard signal (JJY) as received in Okinawa (path length =1600 km) and Kokubunji (60 km). It is shown that the SCF(+ -) appears mainly during the day, whereas the SCF(- +) is observed during the night. The results indicate that the preliminary frequency shift (+) of SCF(+ -) and (-) of SCF(- +) is caused by a westward electric field in the dayside hemisphere, while by an eastward electric field in the nightside hemisphere. The main frequency shift (-) of SCF(+ -) and (+) of SCF(- +) is caused by the reversed electric field. Consequently, the preliminary frequency shift is caused by the dusk-to-dawn electric field, while the main frequency shift by the dawn-to-dusk electric field.

Beaconless operation for optimal laser beam propagation through turbulent atmosphere

Science.gov (United States)

Khizhnyak, Anatoliy; Markov, Vladimir

2016-09-01

Corruption of the wavefront, beam wondering and power density degradation at the receiving end are the effects typically observed at laser beam propagation through turbulent atmosphere. Compensation of these effects can be achieved if the reciprocal conditions for the propagating wave are satisfied along the propagation range. Practical realization of these conditions requires placing a localized beacon at the receiving end of the range and high-performance adaptive optics system (AOS). The key condition for an effective performance of AOS is a high value of the reciprocal component in the outgoing wave, since only this component is getting compensated after propagating turbulence perturbed path. The nonreciprocal components that is present in the wave directed toward the target is caused by three factors (detailed in this paper) that determine the partial restoration of the structure of the beacon beam. Thus solution of a complex problem of focusing the laser beam propagating through turbulent media can be achieved for the share of the outgoing wave that has a reciprocal component. This paper examines the ways and means that can be used in achieving the stated goal of effective laser power delivery on the distant image-resolved object.

Modeling of temporal variation of very low frequency radio waves over long paths as observed from Indian Antarctic stations

Science.gov (United States)

Sasmal, Sudipta; Basak, Tamal; Chakraborty, Suman; Palit, Sourav; Chakrabarti, Sandip K.

2017-07-01

Characteristics of very low frequency (VLF) signal depends on solar illumination across the propagation path. For a long path, solar zenith angle varies widely over the path and this has a significant influence on the propagation characteristics. To study the effect, Indian Centre for Space Physics participated in the 27th and 35th Scientific Expedition to Antarctica. VLF signals transmitted from the transmitters, namely, VTX (18.2 kHz), Vijayanarayanam, India, and NWC (19.8 kHz), North West Cape, Australia, were recorded simultaneously at Indian permanent stations Maitri and Bharati having respective geographic coordinates 70.75°S, 11.67°E, and 69.4°S, 76.17°E. A very stable diurnal variation of the signal has been obtained from both the stations. We reproduced the signal variations of VLF signal using solar zenith angle model coupled with long wavelength propagation capability (LWPC) code. We divided the whole path into several segments and computed the solar zenith angle (χ) profile. We assumed a linear relationship between the Wait's exponential model parameters effective reflection height (h'), steepness parameter (β), and solar zenith angle. The h' and β values were later used in the LWPC code to obtain the VLF signal amplitude at a particular time. The same procedure was repeated to obtain the whole day signal. Nature of the whole day signal variation from the theoretical modeling is also found to match with our observation to some extent.

HF Radar observations of the Dardanelles outflow current in North Eastern Aegean using validated WERA HF radar data

Directory of Open Access Journals (Sweden)

Z. KOKKINI

2014-12-01

Full Text Available A two-site WERA HF radar station was installed in November 2009 at the eastern coast of Lemnos Island in North Aegean Sea, aiming to monitor the surface inflow of Black Sea waters exiting from the Dardanelles Strait, as well as to constitute a coastal management tool for incidents of oil-pollution or save-and-rescue operations. Strong interference by foreign transmissions is a source of noise deteriorating the quality of the backscattered signal, thus significantly reducing the HF radar’s effective data return rate. In order to ameliorate this problem, further quality-control and data gap interpolating procedures have been developed and applied, to be used in addition to the procedures incorporated and used by the manufacturer’s signal processing software. The second-level processing involves traditional despiking in the temporal domain, preceding Empirical Orthogonal Function analysis. The latter is used not only to filter high-frequency noise but also to fill data gaps in time and space. The data reconstruction procedure has been assessed via comparison of (a HF radial with CODE-type drifter radial velocities as well as (b HF-derived virtual drifter tracks with actual drifter tracks. The main circulation features and their variability, as revealed by the reconstructed fields, are presented.

One-particle reducible contribution to the one-loop spinor propagator in a constant field

Directory of Open Access Journals (Sweden)

N. Ahmadiniaz

2017-11-01

Full Text Available Extending work by Gies and Karbstein on the Euler–Heisenberg Lagrangian, it has recently been shown that the one-loop propagator of a charged scalar particle in a constant electromagnetic field has a one-particle reducible contribution in addition to the well-studied irreducible one. Here we further generalize this result to the spinor case, and find the same relation between the reducible term, the tree-level propagator and the one-loop Euler–Heisenberg Lagrangian as in the scalar case. Our demonstration uses a novel worldline path integral representation of the photon-dressed spinor propagator in a constant electromagnetic field background.

HF-laser program

International Nuclear Information System (INIS)

Anon.

1978-01-01

The HF laser is an attractive candidate driver for a large-system ICF scientific demonstration facility, for an ICF experimental power reactor and for a commercial laser--fusion power reactor. Previous accomplishments of the program have included demonstrations of high efficiency and high energy capability, efficient energy extraction from HF amplifiers, good beam quality and focusability, and short-pulse generation and amplification. In the reporting period, beam quality has been determined to be near-diffraction limited for a short pulsewidth (6 ns to 25 ns) oscillator-amplifier chain, suppression of amplified spontaneous emission has been demonstrated on an individual spectral line, high-pressure characteristics have been determined for the Phoenix I amplifier, and detailed comparisions between the kinetic code and experiments have been made. Details of two major upcoming experiments are also included. The first is energy extraction and beam quality measurements on the Phoenix I amplifier operating under saturated output power conditions. The second experiment, using a newly designed amplifier (Phoenix II), is designed to demonstrate the concept of angular-multiplexing: a pulse width-compression scheme

Light propagation analysis in nervous tissue for wireless optogenetic nanonetworks

Science.gov (United States)

Wirdatmadja, Stefanus; Johari, Pedram; Balasubramaniam, Sasitharan; Bae, Yongho; Stachowiak, Michal K.; Jornet, Josep M.

2018-02-01

In recent years, numerous methods have been sought for developing novel solutions to counter neurodegenerative diseases. An objective that is being investigated by researchers is to develop cortical implants that are able to wirelessly stimulate neurons at the single cell level. This is a major development compared to current solutions that use electrodes, which are only able to target a population of neurons, or optogenetics, which requires optical fiber-leads to be embedded deep into the brain. In this direction, the concept of wireless optogenetic nanonetworks has been recently introduced. In such architecture, miniature devices are implanted in the cortex for neuronal stimulation through optogenetics. One of the aspects that will determine the topology and performance of wireless optogenetic nanonetworks is related to light propagation in genetically-engineered neurons. In this paper, a channel model that captures the peculiarities of light propagation in neurons is developed. First, the light propagation behavior using the modified Beer-Lambert law is analyzed based on the photon transport through the nervous tissue. This includes analyzing the scattering light diffraction and diffusive reflection that results from the absorption of neural cell chromophores, as well as validating the results by means of extensive multiphysics simulations. Then, analysis is conducted on the path loss through cells at different layers of the cortex by taking into account the multi-path phenomenon. Results show that there is a light focusing effect in the soma of neurons that can potentially help the to stimulate the target cells.

Ab initio computational study of reaction mechanism of peptide bond formation on HF/6-31G(d,p) level

Science.gov (United States)

Siahaan, P.; Lalita, M. N. T.; Cahyono, B.; Laksitorini, M. D.; Hildayani, S. Z.

2017-02-01

Peptide plays an important role in modulation of various cell functions. Therefore, formation reaction of the peptide is important for chemical reactions. One way to probe the reaction of peptide synthesis is a computational method. The purpose of this research is to determine the reaction mechanism for peptide bond formation on Ac-PV-NH2 and Ac-VP-NH2 synthesis from amino acid proline and valine by ab initio computational approach. The calculations were carried out by theory and basis set HF/6-31G(d,p) for four mechanisms (path 1 to 4) that proposed in this research. The results show that the highest of the rate determining step between reactant and transition state (TS) for path 1, 2, 3, and 4 are 163.06 kJ.mol-1, 1868 kJ.mol-1, 5685 kJ.mol-1, and 1837 kJ.mol-1. The calculation shows that the most preferred reaction of Ac-PV-NH2 and Ac-VP-NH2 synthesis from amino acid proline and valine are on the path 1 (initiated with the termination of H+ in proline amino acid) that produce Ac-PV-NH2.

Chemical stability and defect formation in CaHfO3

KAUST Repository

Alay-E-Abbas, Syed Muhammad

2014-04-01

Defects in CaHfO3 are investigated by ab initio calculations based on density functional theory. Pristine and anion-deficient CaHfO 3 are found to be insulating, whereas cation-deficient CaHfO 3 is hole-doped. The formation energies of neutral and charged cation and anion vacancies are evaluated to determine the stability in different chemical environments. Moreover, the energies of the partial and full Schottky defect reactions are computed. We show that clustering of anion vacancies in the HfO layers is energetically favorable for sufficiently high defect concentrations and results in metallicity. © 2014 EPLA.

Chemical stability and defect formation in CaHfO3

KAUST Repository

Alay-E-Abbas, Syed Muhammad; Nazir, Safdar; Mun Wong, Kin; Shaukat, Ali; Schwingenschlö gl, Udo

2014-01-01

Defects in CaHfO3 are investigated by ab initio calculations based on density functional theory. Pristine and anion-deficient CaHfO 3 are found to be insulating, whereas cation-deficient CaHfO 3 is hole-doped. The formation energies of neutral and charged cation and anion vacancies are evaluated to determine the stability in different chemical environments. Moreover, the energies of the partial and full Schottky defect reactions are computed. We show that clustering of anion vacancies in the HfO layers is energetically favorable for sufficiently high defect concentrations and results in metallicity. © 2014 EPLA.

Transfer and dissipation of energy during wave group propagation on a gentle beach slope

Science.gov (United States)

Padilla, Enrique M.; Alsina, José M.

2017-08-01

The propagation of bichromatic wave groups over a constant 1:100 beach slope and the influence of the group modulation is presented. The modulation is controlled by varying the group frequency, fg, which is shown to remarkably affect the energy transfer to high and low frequency components. The growth of the high frequency (hf) wave skewness increases when fg decreases. This is explained by nonlinear coupling between the primary frequencies, which results in a larger growth of hf components as fg decreases, causing the hf waves to break earlier. Due to high spatial resolution, wave tracking has provided an accurate measurement of the varying breakpoint. These breaking locations are very well described (R2>0.91) by the wave-height to effective-depth ratio (γ). However, for any given Iribarren number, this γ is shown to increase with fg. Therefore, a modified Iribarren number is proposed to include the grouping structure, leading to a considerable improvement in reproducing the measured γ-values. Within the surf zone, the behavior of the Incident Long Wave also depends on the group modulation. For low fg conditions, the lf wave decays only slightly by transferring energy back to the hf wave components. However, for high fg wave conditions, strong dissipation of low frequency (lf) components occurs close to the shoreline associated with lf wave breaking. This mechanism is explained by the growth of the lf wave height, induced partly by the self-self interaction of fg, and partly by the nonlinear coupling between the primary frequencies and fg.

Maximally-localized position, Euclidean path-integral, and thermodynamics in GUP quantum mechanics

Science.gov (United States)

Bernardo, Reginald Christian S.; Esguerra, Jose Perico H.

2018-04-01

In dealing with quantum mechanics at very high energies, it is essential to adapt to a quasiposition representation using the maximally-localized states because of the generalized uncertainty principle. In this paper, we look at maximally-localized states as eigenstates of the operator ξ = X + iβP that we refer to as the maximally-localized position. We calculate the overlap between maximally-localized states and show that the identity operator can be expressed in terms of the maximally-localized states. Furthermore, we show that the maximally-localized position is diagonal in momentum-space and that the maximally-localized position and its adjoint satisfy commutation and anti-commutation relations reminiscent of the harmonic oscillator commutation and anti-commutation relations. As application, we use the maximally-localized position in developing the Euclidean path-integral and introduce the compact form of the propagator for maximal localization. The free particle momentum-space propagator and the propagator for maximal localization are analytically evaluated up to quadratic-order in β. Finally, we obtain a path-integral expression for the partition function of a thermodynamic system using the maximally-localized states. The partition function of a gas of noninteracting particles is evaluated. At temperatures exceeding the Planck energy, we obtain the gas' maximum internal energy N / 2 β and recover the zero heat capacity of an ideal gas.

Development of Cu-Hf-Al ternary systems and tungsten wire/particle reinforced Cu48Hf43Al9 bulk metallic glass composites for strengthening

International Nuclear Information System (INIS)

Park, Joyoung; An, Jihye; Choi-Yim, Haein

2010-01-01

Stable bulk glass forming alloys can be developed over a wide range of compositions in Cu-Hf-Al ternary systems starting from the Cu 49 Hf 42 Al 9 bulk metallic glass. Ternary Cu-Hf-Al alloys can be cast directly from the melt into copper molds to form fully amorphous strips with thicknesses of 1 to 6 mm. The maximum critical diameter of the new Cu-Hf-Al ternary alloy was 6 mm. X-ray diffraction patterns were used to confirm the amorphous nature of the ternary Cu-Hf-Al alloys. To increase the toughness of these metallic glasses, we reinforced the Cu 48 Hf 43 Al 9 bulk metallic glass-forming liquid with a 50% volume fraction of tungsten particles and an 80% volume fraction of tungsten wires with diameters of 242.4 μm. Composites with a critical diameter of 7 mm and length 70 mm were synthesized. The structure of the composites was confirmed by using X-ray diffraction (XRD), and the scanning electron microscopy (SEM). The mechanical properties of the composites were studied in compression tests. The thermal stability and the crystallization processes of the Cu-Hf-Al alloys and composites were investigated by using differential scanning calorimetry (DSC). Values of the glass transition temperature (T g ), the crystallization temperature (T x ), and the supercooled liquid region (ΔT = T x - T g ) are given in this paper.

Do Hf isotopes in magmatic zircons represent those of their host rocks?

Science.gov (United States)

Wang, Di; Wang, Xiao-Lei; Cai, Yue; Goldstein, Steven L.; Yang, Tao

2018-04-01

Lu-Hf isotopic system in zircon is a powerful and widely used geochemical tracer in studying petrogenesis of magmatic rocks and crustal evolution, assuming that zircon Hf isotopes can represent initial Hf isotopes of their parental whole rock. However, this assumption may not always be valid. Disequilibrium partial melting of continental crust would preferentially melt out non-zircon minerals with high time-integrated Lu/Hf ratios and generate partial melts with Hf isotope compositions that are more radiogenic than those of its magma source. Dissolution experiments (with hotplate, bomb and sintering procedures) of zircon-bearing samples demonstrate this disequilibrium effect where partial dissolution yielded variable and more radiogenic Hf isotope compositions than fully dissolved samples. A case study from the Neoproterozoic Jiuling batholith in southern China shows that about half of the investigated samples show decoupled Hf isotopes between zircons and the bulk rocks. This decoupling could reflect complex and prolonged magmatic processes, such as crustal assimilation, magma mixing, and disequilibrium melting, which are consistent with the wide temperature spectrum from ∼630 °C to ∼900 °C by Ti-in-zircon thermometer. We suggest that magmatic zircons may only record the Hf isotopic composition of their surrounding melt during crystallization and it is uncertain whether their Hf isotopic compositions can represent the primary Hf isotopic compositions of the bulk magmas. In this regard, using zircon Hf isotopic compositions to trace crustal evolution may be biased since most of these could be originally from disequilibrium partial melts.

Lu{sub 2}O{sub 3}:Tb,Hf storage phosphor

Energy Technology Data Exchange (ETDEWEB)

Kulesza, Dagmara; Trojan-Piegza, Joanna [Faculty of Chemistry, University of Wroclaw, 14 F. Joliot-Curie Street, 50-383 Wroclaw (Poland); Zych, Eugeniusz, E-mail: zych@wchuwr.p [Faculty of Chemistry, University of Wroclaw, 14 F. Joliot-Curie Street, 50-383 Wroclaw (Poland)

2010-03-15

Lu{sub 2}O{sub 3}:Tb,Hf ceramics containing 0.1% of Tb and 0-1.5% of Hf were prepared in reducing atmosphere at 1700 {sup o}C and their thermoluminescence properties were systematically studied. For comparison Tb,Ca co-doped specimen was also fabricated and investigated. The Tb,Hf ceramics shows basically a single TL band located around 180 {sup o}C as found with heating rate of 15 {sup o}C/min. Ceramics singly doped with Tb show complex TL glow curves indicating the presence of traps of very different depths. On the other hand Tb,Ca co-doping is beneficial for the development of shallow traps with the main TL band around 70 {sup o}C. Hence, the aliovalent impurities, Ca{sup 2+} and Hf{sup 4+}, strongly influenced the traps structure in Lu{sub 2}O{sub 3}:Tb ceramics, each of them in its own specific way. Isothermal decay of Lu{sub 2}O{sub 3}:Tb,Hf at 185 {sup o}C was recorded and its shape suggest that multiple hole trapping occurs in the Lu{sub 2}O{sub 3}:Tb,Hf ceramics. Due to the different traps depths the Lu{sub 2}O{sub 3}:Tb,Hf ceramics possess properties typical for storage phosphors, while Lu{sub 2}O{sub 3}:Tb,Ca is a persistent luminescent material rather.

Stochastic Models for Laser Propagation in Atmospheric Turbulence.

Science.gov (United States)

Leland, Robert Patton

In this dissertation, stochastic models for laser propagation in atmospheric turbulence are considered. A review of the existing literature on laser propagation in the atmosphere and white noise theory is presented, with a view toward relating the white noise integral and Ito integral approaches. The laser beam intensity is considered as the solution to a random Schroedinger equation, or forward scattering equation. This model is formulated in a Hilbert space context as an abstract bilinear system with a multiplicative white noise input, as in the literature. The model is also modeled in the Banach space of Fresnel class functions to allow the plane wave case and the application of path integrals. Approximate solutions to the Schroedinger equation of the Trotter-Kato product form are shown to converge for each white noise sample path. The product forms are shown to be physical random variables, allowing an Ito integral representation. The corresponding Ito integrals are shown to converge in mean square, providing a white noise basis for the Stratonovich correction term associated with this equation. Product form solutions for Ornstein -Uhlenbeck process inputs were shown to converge in mean square as the input bandwidth was expanded. A digital simulation of laser propagation in strong turbulence was used to study properties of the beam. Empirical distributions for the irradiance function were estimated from simulated data, and the log-normal and Rice-Nakagami distributions predicted by the classical perturbation methods were seen to be inadequate. A gamma distribution fit the simulated irradiance distribution well in the vicinity of the boresight. Statistics of the beam were seen to converge rapidly as the bandwidth of an Ornstein-Uhlenbeck process was expanded to its white noise limit. Individual trajectories of the beam were presented to illustrate the distortion and bending of the beam due to turbulence. Feynman path integrals were used to calculate an

Effects of HfO{sub 2}/Co interface and Co/HfO{sub 2} interface on anomalous Hall behavior in perpendicular Co/Pt multilayers

Energy Technology Data Exchange (ETDEWEB)

Jiang, Shao-Long [Department of Materials Science and Engineering, College of Engineering, Peking University, Beijing 100871 (China); Yang, Guang [Department of Materials Physics and Chemistry, University of Science and Technology Beijing, Beijing 100083 (China); Teng, Jiao, E-mail: tengjiao@mater.ustb.edu.cn [Department of Materials Physics and Chemistry, University of Science and Technology Beijing, Beijing 100083 (China); Guo, Qi-Xun; Liu, Yi-Wei; Li, Xu-Jing [Department of Materials Physics and Chemistry, University of Science and Technology Beijing, Beijing 100083 (China); Yu, Guang-Hua, E-mail: ghyu@mater.ustb.edu.cn [Department of Materials Physics and Chemistry, University of Science and Technology Beijing, Beijing 100083 (China)

2017-07-01

Highlights: • Anomalous Hall effect in perpendicular Co/Pt multilayers is studied. • Thermally stable AHE feature is obtained in [Pt/Co]{sub 3}/HfO{sub 2}/Pt multilayers. • Good thermal stability is due to enhanced intrinsic and side-jump contributions. - Abstract: Effects of the HfO{sub 2}/Co interface and the Co/HfO{sub 2} interface on thermal stability of anomalous Hall effect (AHE) in perpendicular Co/Pt multilayers have been studied. It is observed that thermally stable AHE behavior cannot be obtained in perpendicular Co/Pt multilayers with the HfO{sub 2}/Co interface, mainly due to Co-Pt interdiffusion during annealing. In contrast, thermally stable AHE feature is observed in perpendicular Co/Pt multilayers with the Co/HfO{sub 2} interface despite Co-Pt interdiffusion, which is owing to the enhancement of the side jump and intrinsic contributions to the AHE through interfacial modification after annealing.

A routine high-precision method for Lu-Hf isotope geochemistry and chronology

Science.gov (United States)

Patchett, P.J.; Tatsumoto, M.

1981-01-01

A method for chemical separation of Lu and Hf from rock, meteorite and mineral samples is described, together with a much improved mass spectrometric running technique for Hf. This allows (i) geo- and cosmochronology using the176Lu???176Hf+??- decay scheme, and (ii) geochemical studies of planetary processes in the earth and moon. Chemical yields for the three-stage ion-exchange column procedure average 90% for Hf. Chemical blanks are international mass spectrometric standard; suitable aliquots, prepared from a single batch of JMC 475, are available from Denver. Lu-Hf analyses of the standard rocks BCR-1 and JB-1 are given. The potential of the Lu-Hf method in isotope geochemistry is assessed. ?? 1980 Springer-Verlag.

A novel process for preparation of titanium dioxide from Ti-bearing electric furnace slag: NH4HF2-HF leaching and hydrolyzing process.

Science.gov (United States)

Zheng, Fuqiang; Guo, Yufeng; Qiu, Guanzhou; Chen, Feng; Wang, Shuai; Sui, Yulei; Jiang, Tao; Yang, Lingzhi

2018-02-15

A novel process to prepare titanium dioxide from Ti-bearing electric furnace slag by NH 4 HF 2 -HF leaching and hydrolyzing process has been developed. In this present study, the effects of [NH 4 + ]/[F] mXolar ratio, leaching temperature, [F] concentration, liquid/solid mass ratio, leaching time on the Ti extraction, and the phase transformations have been investigated to reveal the leaching mechanism of Ti-bearing electric furnace slag in NH 4 HF 2 -HF solution. In the NH 4 HF 2 -HF leaching process, the MgTi 2 O 5 and Al 2 TiO 5 are converted to TiF 6 2- and Mg-Al-bearing precipitate. Ti extraction rate reached 98.84% under the optimal conditions. In addition, 98.25% iron ions can be removed in the presence of NaCl prior to hydrolysis process. The effects of pH and temperature on the selective hydrolysis of TiF 6 2- during hydrolysis process were also studied. In the hydrolysis process, the TiF 6 2- is converted to (NH 4 ) 2 TiOF 4 . By calcination, high grade TiO 2 powder with its purity of 99.88% was obtained, using which the products, well crystallized anatase and rutile, were obtained through roasting at 800°C and 1000°C, respectively. Copyright © 2017 Elsevier B.V. All rights reserved.

Lifetime of the first excited 2{sup +} state in {sup 172}Hf and {sup 174}Hf

Energy Technology Data Exchange (ETDEWEB)

Gerst, Rosa-Belle; Stegemann, Simon; Jolie, Jan; Regis, Jean-Marc; Rudigier, Matthias; Saed-Samii, Nima; Zell, Karl Oskar [Institut fuer Kernphysik, Universitaet zu Koeln, Zuelpicher Str. 77, 50937 Koeln (Germany)

2014-07-01

Using the {sup 170}Yb(α,2n) and {sup 172}Yb(α,2n) reactions the lifetimes of the first excited 2{sup +} state in {sup 172}Hf and {sup 174}Hf have been measured in fast-timing experiments using the Cologne Orange-Spectrometer and 6 LaBr{sub 3}(Ce)-Detectors. The lifetimes were obtained analyzing e{sup -}-γ-coincidence time-spectra with the slope method. The new and more precise lifetimes correct existing, outdated lifetimes in nuclear databases. Additionally, the systematics of the B(E2,2{sub 1}{sup +}→0{sub 1}{sup +}) is studied.

The temperature pulse propagation in interacting nuclear slabs

International Nuclear Information System (INIS)

Kozlowski, M.; Zurich Univ.

1989-01-01

Following the method developed by R.J. Swenson a non-Fourier equation for heat transfer in nuclear matter is obtained. The velocity of heat propagation is calculated and the value υ s = υ F /√3 is obtained. For two interacting nuclear slabs the temperature as a function of time is calculated. For a nucleon mean free path λ ≅ 3 fm the temperature saturation time is calculated and the value ≅ 160 fm/c is obtained. (orig.)

Insulin resistance and carotid intima-media thickness mediate the association between resting-state heart rate variability and executive function: A path modelling study.

Science.gov (United States)

Kemp, Andrew H; López, Santiago Rodríguez; Passos, Valeria M A; Bittencourt, Marcio S; Dantas, Eduardo M; Mill, José G; Ribeiro, Antonio L P; Thayer, Julian F; Bensenor, Isabela M; Lotufo, Paulo A

2016-05-01

Research has linked high-frequency heart rate variability (HF-HRV) to cognitive function. The present study adopts a modern path modelling approach to understand potential causal pathways that may underpin this relationship. Here we examine the association between resting-state HF-HRV and executive function in a large sample of civil servants from Brazil (N=8114) recruited for the Brazilian Longitudinal Study of Adult Health (ELSA-Brasil). HF-HRV was calculated from 10-min resting-state electrocardiograms. Executive function was assessed using the trail-making test (version B). Insulin resistance (a marker of type 2 diabetes mellitus) and carotid intima-media thickness (subclinical atherosclerosis) mediated the relationship between HRV and executive function in seriatim. A limitation of the present study is its cross-sectional design; therefore, conclusions must be confirmed in longitudinal study. Nevertheless, findings support that possibility that HRV provides a 'spark' that initiates a cascade of adverse downstream effects that subsequently leads to cognitive impairment. Copyright © 2016 Elsevier B.V. All rights reserved.

Draft revision of human factors guideline HF-010

International Nuclear Information System (INIS)

Lee, Hyun Chul; Lee, Yong Hee; Oh, In Seok; Lee, Jung Woon; Cha, Woo Chang; Lee, Dhong Ha

2003-05-01

The Application of Human Factors to the design of Man-Machine Interfaces System(MMIS) in the nuclear power plant is essential to the safety and productivity of the nuclear power plants, human factors standards and guidelines as well as human factors analysis methods and experiments are weightily used to the design application. A Korean engineering company has developed a human factors engineering guideline, so-call HF-010, and has used it for human factors design, however the revision of HF-010 is necessary owing to lack of the contents related to the advanced MMI(Man-Machine Interfaces). As the results of the reviews of HF-010, it is found out that the revision of Section 9. Computer Displays of HF-010 is urgent, thus the revision was drafted on the basis of integrated human factors design guidelines for VDT, human factors design guidelines for PMAS SPADES display, human factors design guidelines for PMAS alarm display, and human factors design guidelines for electronic displays developed by the surveillance and operation support project of KOICS. The draft revision of HF-010 Section 9 proposed in this report can be utilized for the human factors design of the advanced MMI, and the high practical usability of the draft can be kept up through the continuous revision according to the advancement of digital technology

An in-depth description of bipolar resistive switching in Cu/HfOx/Pt devices, a 3D kinetic Monte Carlo simulation approach

Science.gov (United States)

Aldana, S.; Roldán, J. B.; García-Fernández, P.; Suñe, J.; Romero-Zaliz, R.; Jiménez-Molinos, F.; Long, S.; Gómez-Campos, F.; Liu, M.

2018-04-01

A simulation tool based on a 3D kinetic Monte Carlo algorithm has been employed to analyse bipolar conductive bridge RAMs fabricated with Cu/HfOx/Pt stacks. Resistive switching mechanisms are described accounting for the electric field and temperature distributions within the dielectric. The formation and destruction of conductive filaments (CFs) are analysed taking into consideration redox reactions and the joint action of metal ion thermal diffusion and electric field induced drift. Filamentary conduction is considered when different percolation paths are formed in addition to other conventional transport mechanisms in dielectrics. The simulator was tuned by using the experimental data for Cu/HfOx/Pt bipolar devices that were fabricated. Our simulation tool allows for the study of different experimental results, in particular, the current variations due to the electric field changes between the filament tip and the electrode in the High Resistance State. In addition, the density of metallic atoms within the CF can also be characterized along with the corresponding CF resistance description.

Thermodynamic modeling of the Co–Hf system supported by key experiments and first-principles calculations

Energy Technology Data Exchange (ETDEWEB)

Lu, Xingxu [School of Materials Science and Engineering, Central South University, Changsha, Hunan 410083 (China); State Key Laboratory of Powder Metallurgy, Central South University, Changsha, Hunan 410083 (China); Liu, Shuhong, E-mail: shhliu@csu.edu.cn [State Key Laboratory of Powder Metallurgy, Central South University, Changsha, Hunan 410083 (China); Sino-German Cooperation Group “Microstructure in Al alloys”, Central South University, Changsha, Hunan 410083 (China); Cheng, Kaiming; Tang, Ying [State Key Laboratory of Powder Metallurgy, Central South University, Changsha, Hunan 410083 (China); Ou, Pengfei [School of Materials Science and Engineering, Central South University, Changsha, Hunan 410083 (China); State Key Laboratory of Powder Metallurgy, Central South University, Changsha, Hunan 410083 (China); Nash, Philip [Thermal Processing Technology Center, Illinois Institute of Technology (IIT), 10 West 32nd Street, Chicago, IL 60616 (United States); Sundman, Bo [INSTN, CEA Saclay, 91191 Gif-Sur-Yvette Cedex (France); Du, Yong [State Key Laboratory of Powder Metallurgy, Central South University, Changsha, Hunan 410083 (China); Sino-German Cooperation Group “Microstructure in Al alloys”, Central South University, Changsha, Hunan 410083 (China); Zheng, Feng [School of Materials Science and Engineering, Central South University, Changsha, Hunan 410083 (China)

2015-05-20

Highlights: • Heat contents of Co{sub 2}Hf and CoHf{sub 2} were measured by drop calorimetry. • Enthalpy of formation for Co{sub 23}Hf{sub 6} was computed via first-principles calculations. • Co–Hf system was assessed by means of CALPHAD approach. • Order–disorder model is used to describe B2 (CoHf) and A2 (βHf). • Glass forming range of the Co–Hf amorphous alloys was predicted. - Abstract: Phase equilibria and thermodynamic properties of the Co–Hf system were investigated via calorimetric measurements, first-principles calculations and thermodynamic modeling. Heat contents of Co{sub 2}Hf and CoHf{sub 2} were measured by drop calorimetry from 300 to 1200 °C. The enthalpy of formation for Co{sub 23}Hf{sub 6} at 0 K was computed via first-principles calculations. Based on the experimental measurements and first-principles calculations from the present work and the literature, the Co–Hf system was assessed by means of CALPHAD (CALculation of PHAse Diagram) approach. The excess Gibbs energy of solution phases was modeled with Redlich–Kister polynomial. Sublattice models were employed to describe the homogeneity ranges of Co{sub 2}Hf, CoHf and CoHf{sub 2}. The order–disorder transition between B2 (CoHf) and A2 (βHf) phases was taken into account in the current optimization. Using the optimized parameters, glass forming range (GFR) of the Co–Hf amorphous alloys was predicted to be 15–75 at.% Hf, which is in satisfactory agreement with the experimental observation.

Estimation of Atmospheric Path Delays in TerraSAR-X Data using Models vs. Measurements

Directory of Open Access Journals (Sweden)

Donat Perler

2008-12-01

Full Text Available Spaceborne synthetic aperture radar (SAR measurements of the Earth’s surface depend on electromagnetic waves that are subject to atmospheric path delays, in turn affecting geolocation accuracy. The atmosphere influences radar signal propagation by modifying its velocity and direction, effects which can be modeled. We use TerraSAR-X (TSX data to investigate improvements in the knowledge of the scene geometry. To precisely estimate atmospheric path delays, we analyse the signal return of four corner reflectors with accurately surveyed positions (based on differential GPS, placed at different altitudes yet with nearly identical slant ranges to the sensor. The comparison of multiple measurements with path delay models under these geometric conditions also makes it possible to evaluate the corrections for the atmospheric path delay made by the TerraSAR processor and to propose possible improvements.

Nuclear quadrupole interactions in ferroelectric compounds of HF/sup 181/

Energy Technology Data Exchange (ETDEWEB)

Kunzler, J V

1971-01-01

Measurements of nuclear quadrupole interaction constants in perovkite-type compounds of PbHfO/sub 3/, SnhfO/sub 3/, CaHfO/sub 3/ e SrHfO/sub 3/ have been performed using the perturbed angular correlation technique. A range of fundamental frequencies from 150 to 550 Megaradians per second was determined. The variation of quadrupole constants has been discussed through the molecular orbital theory.

Reliability assessment of ultra-thin HfO2 films deposited on silicon wafer

International Nuclear Information System (INIS)

Fu, Wei-En; Chang, Chia-Wei; Chang, Yong-Qing; Yao, Chih-Kai; Liao, Jiunn-Der

2012-01-01

Highlights: ► Nano-mechanical properties on annealed ultra-thin HfO 2 film are studied. ► By AFM analysis, hardness of the crystallized HfO 2 film significantly increases. ► By nano-indention, the film hardness increases with less contact stiffness. ► Quality assessment on the annealed ultra-thin films can thus be achieved. - Abstract: Ultra-thin hafnium dioxide (HfO 2 ) is used to replace silicon dioxide to meet the required transistor feature size in advanced semiconductor industry. The process integration compatibility and long-term reliability for the transistors depend on the mechanical performance of ultra-thin HfO 2 films. The criteria of reliability including wear resistance, thermal fatigue, and stress-driven failure rely on film adhesion significantly. The adhesion and variations in mechanical properties induced by thermal annealing of the ultra-thin HfO 2 films deposited on silicon wafers (HfO 2 /SiO 2 /Si) are not fully understood. In this work, the mechanical properties of an atomic layer deposited HfO 2 (nominal thickness ≈10 nm) on a silicon wafer were characterized by the diamond-coated tip of an atomic force microscope and compared with those of annealed samples. The results indicate that the annealing process leads to the formation of crystallized HfO 2 phases for the atomic layer deposited HfO 2 . The HfSi x O y complex formed at the interface between HfO 2 and SiO 2 /Si, where the thermal diffusion of Hf, Si, and O atoms occurred. The annealing process increases the surface hardness of crystallized HfO 2 film and therefore the resistance to nano-scratches. In addition, the annealing process significantly decreases the harmonic contact stiffness (or thereafter eliminate the stress at the interface) and increases the nano-hardness, as measured by vertically sensitive nano-indentation. Quality assessments on as-deposited and annealed HfO 2 films can be thereafter used to estimate the mechanical properties and adhesion of ultra-thin HfO 2

Chemical reaction at the interface between pentacene and HfO2

International Nuclear Information System (INIS)

Kang, S.J.; Yi, Y.; Kim, K.H.; Yoo, C.Y.; Moewes, A.; Cho, M.H.; Denlinger, J.D.; Whang, C.N.; Chang, G.S.

2005-01-01

The electronic structure and the interface formation at the interface region between pentacene and HfO2 are investigated using x-ray photoelectron spectroscopy (XPS), ultraviolet photoelectron spectroscopy (UPS), and x-ray emission spectroscopy (XES). The measured C 1s XPS spectra of pentacene indicate that chemical bonding occurs at the interface between pentacene and HfO2. The carbon of pentacene reacts with oxygen belonging to HfO2 and band bending occurs at the interface due to a redistribution of charge. The determined interface dipole and band bending between pentacene and HfO2 are 0.04 and 0.1 eV, respectively. The highest occupied molecular orbital (HOMO) level is observed at 0.68 eV below the Fermi level. This chemical reaction allows us to grow a pentacene film with large grains onto HfO2. We conclude that high performance pentacene thin film transistors can be obtained by inserting an ultrathin HfO2 layer between pentacene and a gate insulator

Uniform Self-rectifying Resistive Switching Behavior via Preformed Conducting Paths in a Vertical-type Ta2O5/HfO2-x Structure with a Sub-μm(2) Cell Area.

Science.gov (United States)

Yoon, Jung Ho; Yoo, Sijung; Song, Seul Ji; Yoon, Kyung Jean; Kwon, Dae Eun; Kwon, Young Jae; Park, Tae Hyung; Kim, Hye Jin; Shao, Xing Long; Kim, Yumin; Hwang, Cheol Seong

2016-07-20

To replace or succeed the present NAND flash memory, resistive switching random access memory (ReRAM) should be implemented in the vertical-type crossbar array configuration. The ReRAM cell must have a highly reproducible resistive switching (RS) performance and an electroforming-free, self-rectifying, low-power-consumption, multilevel-switching, and easy fabrication process with a deep sub-μm(2) cell area. In this work, a Pt/Ta2O5/HfO2-x/TiN RS memory cell fabricated in the form of a vertical-type structure was presented as a feasible contender to meet the above requirements. While the fundamental RS characteristics of this material based on the electron trapping/detrapping mechanisms have been reported elsewhere, the influence of the cell scaling size to 0.34 μm(2) on the RS performance by adopting the vertical integration scheme was carefully examined in this work. The smaller cell area provided much better switching uniformity while all the other benefits of this specific material system were preserved. Using the overstressing technique, the nature of RS through the localized conducting path was further examined, which elucidated the fundamental difference between the present material system and the general ionic-motion-related bipolar RS mechanism.

Daytime tropical D region parameters from short path VLF phase and amplitude

Science.gov (United States)

Thomson, Neil R.

2010-09-01

Observed phases and amplitudes of VLF radio signals, propagating on a short (˜300-km) path, are used to find improved parameters for the lowest edge of the (D region of the) Earth's ionosphere. The phases, relative to GPS 1-s pulses, and the amplitudes were measured both near (˜100 km from) the transmitter, where the direct ground wave is very dominant, and at distances of ˜300 km near where the ionospherically reflected waves form a (modal) minimum with the (direct) ground wave. The signals came from the 19.8 kHz, 1 MW transmitter, NWC, on the North West Cape of Australia, propagating ˜300 km ENE, mainly over the sea, to the vicinity of Karratha/Dampier on the N.W. coast of Australia. The bottom edge of the mid-day tropical/equatorial ionosphere was thus found to be well-modeled by H‧ = 70.5 ± 0.5 km and β = 0.47 ± 0.03 km-1 where H‧ and β are the traditional height and sharpness parameters as used by Wait and by the U.S. Navy in their Earth-ionosphere VLF radio waveguide programs. U.S. Navy modal waveguide code calculations are also compared with those from the wave hop code of Berry and Herman (1971). At least for the vertical electric fields on the path studied here, the resulting phase and amplitude differences (between the ˜100-km and ˜300-km sites) agree very well after just a small adjustment of ˜0.2 km in H‧ between the two codes. Such short paths also allow more localization than the usual long paths; here this localization is to low latitudes.

Lateral propagation of fast electrons at the laser-irradiated target surfaces

International Nuclear Information System (INIS)

Li, Y T; Lin, X X; Liu, B C; Du, F; Wang, S J; Li, C; Zhou, M L; Zhang, L; Liu, X; Wang, J; Liu, X L; Chen, L M; Wang, Z H; Ma, J L; Wei, Z Y; Zhang, J; Liu, F; Liu, F

2010-01-01

Lateral propagation of fast electrons at the target surfaces irradiated by femtosecond intense laser pulses is measured by k α x-ray imaging technique when a preplasma is presented. An annular halo surrounding a bright spot is observed in the x-ray images when the scale length of the electron density is large. For an incidence angle of 70 0 the x-ray images show a non-symmetrical distribution peaked to the laser propagation direction. The x-ray photons in the halo are mainly excited by the fast electrons that flow in the preplasma when their paths intersect the high density regions near the target surface.

Large Magnetic Anisotropy in HfMnP

Science.gov (United States)

Parker, David; Lamichhane, Tej; Taufour, Valentin; Masters, Morgan; Thimmaiah, Srinivasa; Bud'Ko, Ser'gey; Canfield, Paul

We present a theoretical and experimental study of two little-studied manganese phosphide ferromagnets, HfMnP and ZrMnP, with Curie temperatures above room temperature. We find an anisotropy field in HfMnP approaching 10 T - larger than that of the permanent magnet workhorse NdFeB magnets. From theory we determine the source of this anisotropy. Our results show the potential of 3d-element-based magnetic materials for magnetic applications.

Optically reconfigurable patterning for control of the propagation characteristics of a planar waveguide

Science.gov (United States)

Wang, Y.; Klittnick, A.; Clark, N. A.; Keller, P.

2008-10-01

We demonstrate an easily fabricated all-optical and freely reconfigurable method of controlling the propagating characteristics of the optic path within a planar waveguide with low insertion losses by employing the optical patterning of the refractive index of an erasable and rewriteable photosensitive liquid crystal polymer cladding layer.

Propagation of dikes at Vesuvio (Italy) and the effect of Mt. Somma

Science.gov (United States)

Acocella, V.; Porreca, M.; Neri, M.; Massimi, E.; Mattei, M.

2006-04-01

Dikes provide crucial information on how magma propagates within volcanoes. Somma-Vesuvio (Italy) consists of the active Vesuvio cone, partly bordered by the older Mt. Somma edifice. Historical chronicles on the fissure eruptions in 1694-1944 are matched with an analytical solution to define the propagation path of the related dikes and to study any control of the Mt. Somma relief. The fissures always consisted of the downslope migration of vents from an open summit conduit, indicating lateral propagation as the predominant mechanism for shallow dike emplacement. No fissure emplaced beyond Mt. Somma, suggesting that its buttressing hinders the propagation of the radial dikes. An analytical solution is defined to describe the mechanism of formation of the laterally propagating dikes and to evaluate the effect of topography. The application to Somma-Vesuvio suggests that, under ordinary excess magmatic pressures, the dikes should not propagate laterally at depths >240-480 m below the surface, as the increased lithostatic pressure requires magmatic pressures higher than average. This implies that, when the conduit is open, the lateral emplacement of dikes is expectable on the S, W and E slopes. The lack of fissures N of Mt. Somma is explained by its buttressing, which hinders dike propagation.

Measurement and Analysis of Multiple Output Transient Propagation in BJT Analog Circuits

Science.gov (United States)

Roche, Nicolas J.-H.; Khachatrian, A.; Warner, J. H.; Buchner, S. P.; McMorrow, D.; Clymer, D. A.

2016-08-01

The propagation of Analog Single Event Transients (ASETs) to multiple outputs of Bipolar Junction Transistor (BJTs) Integrated Circuits (ICs) is reported for the first time. The results demonstrate that ASETs can appear at several outputs of a BJT amplifier or comparator as a result of a single ion or single laser pulse strike at a single physical location on the chip of a large-scale integrated BJT analog circuit. This is independent of interconnect cross-talk or charge-sharing effects. Laser experiments, together with SPICE simulations and analysis of the ASET's propagation in the s-domain are used to explain how multiple-output transients (MOTs) are generated and propagate in the device. This study demonstrates that both the charge collection associated with an ASET and the ASET's shape, commonly used to characterize the propagation of SETs in devices and systems, are unable to explain quantitatively how MOTs propagate through an integrated analog circuit. The analysis methodology adopted here involves combining the Fourier transform of the propagating signal and the current-source transfer function in the s-domain. This approach reveals the mechanisms involved in the transient signal propagation from its point of generation to one or more outputs without the signal following a continuous interconnect path.

A comparative study of amorphous InGaZnO thin-film transistors with HfOxNy and HfO2 gate dielectrics

International Nuclear Information System (INIS)

Zou, Xiao; Tong, Xingsheng; Fang, Guojia; Yuan, Longyan; Zhao, Xingzhong

2010-01-01

High-κ HfO x N y and HfO 2 films are applied to amorphous InGaZnO (a-IGZO) devices as gate dielectric using radio-frequency reactive sputtering. The electrical characteristics and reliability of a-IGZO metal–insulator–semiconductor (MIS) capacitors and thin-film transistors (TFTs) are then investigated. Experimental results indicate that the nitrogen incorporation into HfO 2 can effectively improve the interface quality and enhance the reliability of the devices. Electrical properties with an interface-state density of 5.2 × 10 11 eV −1 cm −2 , capacitance equivalent thickness of 1.65 nm, gate leakage current density of 3.4 × 10 −5 A cm −2 at V fb +1 V, equivalent permittivity of 23.6 and hysteresis voltage of 110 mV are obtained for an Al/HfO x N y /a-IGZO MIS capacitor. Superior performance of HfO x N y /a-IGZO TFTs has also been achieved with a low threshold voltage of 0.33 V, a high saturation mobility of 12.1 cm 2 V −1 s −1 and a large on–off current ratio up to 7 × 10 7 (W/L = 500/20 µm) at 3 V

Ti-catalyzed HfSiO4 formation in HfTiO4 films on SiO2 studied by Z-contrast scanning electron microscopy

Directory of Open Access Journals (Sweden)

Elizabeth Ellen Hoppe

2013-08-01

Full Text Available Hafnon (HfSiO4 as it is initially formed in a partially demixed film of hafnium titanate (HfTiO4 on fused SiO2 is studied by atomic number (Z contrast high resolution scanning electron microscopy, x-ray diffraction, and Raman spectroscopy and microscopy. The results show exsoluted Ti is the catalyst for hafnon formation by a two-step reaction. Ti first reacts with SiO2 to produce a glassy Ti-silicate. Ti is then replaced by Hf in the silicate to produce HfSiO4. The results suggest this behavior is prototypical of other Ti-bearing ternary or higher order oxide films on SiO2 when film thermal instability involves Ti exsolution.

Path integral methods via the use of the central limit theorem and application

International Nuclear Information System (INIS)

Thrapsaniotis, E G

2008-01-01

We consider a path integral in the phase space possibly with an influence functional in it and we use a method based on the use of the central limit theorem on the phase of the path integral representation to extract an equivalent expression which can be used in numerical calculations. Moreover we give conditions under which we can extract closed analytical results. As a specific application we consider a general system of two coupled and forced harmonic oscillators with coupling of the form x 1 x α 2 and we derive the relevant sign solved propagator

Solidification Rate Dependence of Microstructures and Transformation Behavior of Ti-Ni-Hf Alloys.

Science.gov (United States)

Kim, Dong-Jo; Kim, Yeon-Wook; Nam, Tae-Hyun

2018-09-01

The microstructures and transformation behavior of Ti-49Ni-20Hf, Ti-49.5Ni-20Hf and Ti-50.3Ni- 20Hf alloys, when prepared by conventional casting, were investigated and compared with the properties of the alloys prepared by melt spinning. The area fraction of (Ti,Hf)2Ni in Ti-Ni-Hf alloys decreased to 3.9% from 9.4% as Ni content rose to 50.3 at% from 49 at%. Several cracks were observed in the hot-rolled Ti-49Ni-20Hf alloy sheet but none were found in the Ti-50.3Ni-20Hf alloy sheet. The B2-B19' transformation start temperature (Ms) decreased to 476 K from 580 K as Ni content increased to 50.3 at% from 49 at%. All the as-spun ribbons were amorphous, and the activation energy for crystallization ranged from 167.8 kJ/mol to 182.7 kJ/mol based on Ni content. When annealing temperature ranged from 810 K to 873 K, crystalline Ti-Ni-Hf alloys without (Ti,Hf)2Ni particles were obtained. At annealing temperatures higher than 873 K, very fine (Ti,Hf)2Ni particles, less than 20 nm in size, were found embedded in a crystalline matrix.

Hf-Nd Isotopic Correlation in the Deccan Flood Basalt Province

Science.gov (United States)

Saha, A.; Basu, A. R.; Barling, J.; Anbar, A. D.; Hooper, P. R.

2001-12-01

Hafnium isotopes along with other isotopic and geochemical characteristics, including incompatible trace elements, of several of the lower formations of the Deccan Flood Basalt Province were analyzed to characterize petrogenesis of different tholeiitic lava suites, especially with respect to potential mantle and crustal sources. The rare earth elements of the different formations (from top to bottom- Mahabaleshwar, Ambenali, Bushe, Khandala and Neral) all show an LREE-enriched signature, concentrations varying between 30 to 60 times chondrite for La. (La/Lu)n values range from 4.1 to above 8 with the exception of Ambenali, which has a less LREE-enriched signature with (La/Lu)n values ranging between 3.6 to 5.3. Hafnium isotopic data of the lower formations of the Deccan show initial \\epsilonHf(T) values covering a range from -3 to -28. 176Lu/177Hf varies between 0.20 to 0.70. f(Lu/Hf) varies within a narrow range, between -0.90 to -0.97 while f(Sm/Nd) ranges from -0.84 to -0.86. Bushe gives the lowest range of \\epsilonHf(T) from -21 to -28 with the corresponding \\epsilonNd(T) varying between -4.0 and -16.9, while Khandala for almost the same range of neodymium isotopic values has \\epsilonHf(T) between -11 and -15. The \\epsilonHf(T) values of Neral is in between those of Khandala and Bushe, around -19. Ambenali, has the narrowest range with \\epsilonHf(T) of -3 and \\epsilonNd(T) between 3 and 5. The Ambenali suite reflects the least contaminated of the Deccan suite of lavas as analyzed here and previously confirmed by other isotopic studies. In Hf-Nd isotope correlation plot, the lower Deccan formations of Neral, Khandala and Bushe define individual subparallel arrays that are shallower than the oceanic basalt array and the overall terrestrial array, including the crustal array, although the bulk of the lower formation data fall within the crustal array of Vervoort et al (1999). From these subparallel Hf-Nd arrays, it is evident that the other end

QAPP for Hydraulic Fracturing (HF) Surface Spills Data Analysis

Science.gov (United States)

This QAPP provides information concerning the analysis of spills associated with hydraulic fracturing. This project is relevant to both the chemical mixing and flowback and produced water stages of the HF water cycle as found in the HF Study Plan.

Comparison of Estimation Techniques for Vibro-Acoustic Transfer Path Analysis

Directory of Open Access Journals (Sweden)

Paulo Eduardo França Padilha

2006-01-01

Full Text Available Vibro-acoustic Transfer Path Analysis (TPA is a tool to evaluate the contribution of different energy propagation paths between a source and a receiver, linked to each other by a number of connections. TPA is typically used to quantify and rank the relative importance of these paths in a given frequency band, determining the most significant one to the receiver. Basically, two quantities have to be determined for TPA: the operational forces at each transfer path and the Frequency Response Functions (FRF of these paths. The FRF are obtained either experimentally or analytically, and the influence of the mechanical impedance of the source can be taken into account or not. The operational forces can be directly obtained from measurements using force transducers or indirectly estimated from auxiliary response measurements. Two methods to obtain the operational forces indirectly – the Complex Stiffness Method (CSM and the Matrix Inversion Method (MIM – associated with two possible configurations to determine the FRF – including and excluding the source impedance – are presented and discussed in this paper. The effect of weak and strong coupling among the paths is also commented considering the techniques previously presented. The main conclusion is that, with the source removed, CSM gives more accurate results. On the other hand, with the source present, MIM is preferable. In the latter case, CSM should be used only if there is a high impedance mismatch between the source and the receiver. Both methods are not affected by a higher or lower degree of coupling among the transfer paths.

Direct currents produced by hf heating of plasma

International Nuclear Information System (INIS)

Klima, R.

1974-01-01

In addition to the well-known diffusion currents, toroidal direct currents arise in h.f. heated plasmas as a result of a momentum transfer from the h.f. field to plasma particles. The estimates of steady-state conditions are given for these currents. Particularly, the possibility of stationary operation of a Tokamak device is analyzed. (author)

Comparison of 14 MeV isomer production of 178m2Hf and 179m2Hf using Feshbach-Kerman-Koonin and exciton preequilibrium models

International Nuclear Information System (INIS)

Chadwick, M.B.; Young, P.G.

1993-01-01

The 178m2 Hf(16+) isomeric state has a 31-yr half life and could pose serious radioactive problems in nuclear fusion reactors if its production in 14 MeV neutron-induced reactions is significant. We present statistical/preequilibrium model calculations for the production of this isomer in the 179 Hf(n, 2n) 178m2 Hf reaction, as well as the 25-days 12.5 - isomer in the 179 Hf(n,n') 179m2 Hf reaction, using two different preequilibrium models: the exciton model and the Feshbach-Kerman-Koonin (FKK) theory. Our calculations which use the exciton model agree well with measurements, but those with the FKK theory underestimate measurements. Our calculations axe the first to probe angular momentum transfer effects in the FKK theory and suggest that, as it is presently applied, high spin-transfer reactions are underestimated. We suggest modifications to the FKK statistical averaging procedure which may result in an improved agreement with experiment

Electric field gradients at 181Ta sites in HfOx

International Nuclear Information System (INIS)

Darriba, G.N.; Rodriguez, A.M.; Saitovitch, H.; Silva, P.R.J.; Pasquevich, A.F.

2007-01-01

In the present work we report preliminary results about the possibility to study properties of the order-disorder transition in HfO x solid solutions via the determination of the electric field gradient (EFG) at 181 Ta radioactive probes. Oxygen solution into the metal was achieved by arc melting stoichiometric amounts of metallic Hf and HfO 2 under argon atmosphere. Samples of HfO x with x=0.1 and 0.2 were prepared. Two types of samples were used for the perturbed angular correlation (PAC) experiments by doping alternatively with 181 Ta, by neutron irradiation, the metallic Hf or the hafnium oxide. The PAC results on both samples were identical, with disappearing hyperfine signals of the metal and the oxide, showing a complete diffusion of the probes independent of the way of doping. The PAC signal of the HfO x solid solution consisted in a wide distribution of EFGs due to the oxygen disorder. This scheme held even after long thermal treatments at high temperature (several days at 1273K). Annealing treatments at moderate temperature (600K) were also made. In these cases the samples were cooling at a very low rate. These results, together with those obtained by measuring samples below and above the order temperature are reported

Atomic scale engineering of HfO2-based dielectrics for future DRAM applications

International Nuclear Information System (INIS)

Dudek, Piotr

2011-01-01

Modern dielectrics in combination with appropriate metal electrodes have a great potential to solve many difficulties associated with continuing miniaturization process in the microelectronic industry. One significant branch of microelectronics incorporates dynamic random access memory (DRAM) market. The DRAM devices scaled for over 35 years starting from 4 kb density to several Gb nowadays. The scaling process led to the dielectric material thickness reduction, resulting in higher leakage current density, and as a consequence higher power consumption. As a possible solution for this problem, alternative dielectric materials with improved electrical and material science parameters were intensively studied by many research groups. The higher dielectric constant allows the use of physically thicker layers with high capacitance but strongly reduced leakage current density. This work focused on deposition and characterization of thin insulating layers. The material engineering process was based on Si cleanroom compatible HfO 2 thin films deposited on TiN metal electrodes. A combined materials science and dielectric characterization study showed that Ba-added HfO 2 (BaHfO 3 ) films and Ti-added BaHfO 3 (BaHf 0.5 Ti 0.5 O 3 ) layers are promising candidates for future generation of state-of-the-art DRAMs. In especial a strong increase of the dielectric permittivity k was achieved for thin films of cubic BaHfO 3 (k∝38) and BaHf 0.5 Ti 0.5 O 3 (k∝90) with respect to monoclinic HfO 2 (k∝19). Meanwhile the CET values scaled down to 1 nm for BaHfO 3 and ∝0.8 nm for BaHf 0.5 Ti 0.5 O 3 with respect to HfO 2 (CET=1.5 nm). The Hf 4+ ions substitution in BaHfO 3 by Ti 4+ ions led to a significant decrease of thermal budget from 900 C for BaHfO 3 to 700 C for BaHf 0.5 Ti 0.5 O 3 . Future studies need to focus on the use of appropriate metal electrodes (high work function) and on film deposition process (homogeneity) for better current leakage control. (orig.)

HF doppler sounder measurements of the ionospheric signatures of small scale ULF waves

Directory of Open Access Journals (Sweden)

L. J. Baddeley

2005-07-01

Full Text Available An HF Doppler sounder, DOPE (DOppler Pulsation Experiment with three azimuthally-separated propagation paths is used to provide the first statistical examination of small scale-sized, high m waves where a direct measurement of the azimuthal wavenumber m, is made in the ionosphere. The study presents 27 events, predominantly in the post-noon sector. The majority of events are Pc4 waves with azimuthal m numbers ranging from –100 to –200, representing some of the smallest scale waves ever observed in the ionosphere. 4 Pc5 waves are observed in the post-noon sector. The fact that measurements for the wave azimuthal m number and the wave angular frequency are available allows the drift-bounce resonance condition to be used to hypothesise potential particle populations which could drive the waves through either a drift or drift-bounce resonance interaction mechanism. These results are compared with the statistical study presented by Baddeley et al. (2004 which investigated the statistical likelihood of such driving particle populations occurring in the magnetospheric ring current. The combination of these two studies indicates that any wave which requires a possible drift resonance interaction with particles of energies >60 keV, is statistically unlikely to be generated by such a mechanism. The evidence presented in this paper therefore suggests that in the pre-noon sector the drift-bounce resonance mechanism is statistically more likely implying an anti-symmetric standing wave structure while in the post-noon sector both a drift or drift-bounce resonance interaction is statistically possible, indicating both symmetric and anti-symmetric standing mode structures. A case study is also presented investigating simultaneous observations of a ULF wave in ground magnetometer and DOPE data. The event is in the lower m range of the statistical study and displays giant pulsation (Pg characteristics.

Keywords

HF doppler sounder measurements of the ionospheric signatures of small scale ULF waves

Directory of Open Access Journals (Sweden)

L. J. Baddeley

2005-07-01

Full Text Available An HF Doppler sounder, DOPE (DOppler Pulsation Experiment with three azimuthally-separated propagation paths is used to provide the first statistical examination of small scale-sized, high m waves where a direct measurement of the azimuthal wavenumber m, is made in the ionosphere. The study presents 27 events, predominantly in the post-noon sector. The majority of events are Pc4 waves with azimuthal m numbers ranging from –100 to –200, representing some of the smallest scale waves ever observed in the ionosphere. 4 Pc5 waves are observed in the post-noon sector. The fact that measurements for the wave azimuthal m number and the wave angular frequency are available allows the drift-bounce resonance condition to be used to hypothesise potential particle populations which could drive the waves through either a drift or drift-bounce resonance interaction mechanism. These results are compared with the statistical study presented by Baddeley et al. (2004 which investigated the statistical likelihood of such driving particle populations occurring in the magnetospheric ring current. The combination of these two studies indicates that any wave which requires a possible drift resonance interaction with particles of energies >60 keV, is statistically unlikely to be generated by such a mechanism. The evidence presented in this paper therefore suggests that in the pre-noon sector the drift-bounce resonance mechanism is statistically more likely implying an anti-symmetric standing wave structure while in the post-noon sector both a drift or drift-bounce resonance interaction is statistically possible, indicating both symmetric and anti-symmetric standing mode structures. A case study is also presented investigating simultaneous observations of a ULF wave in ground magnetometer and DOPE data. The event is in the lower m range of the statistical study and displays giant pulsation (Pg characteristics. Keywords. Ionosphere (Ionosphere

Heavy ion studies with CMS HF calorimeter

International Nuclear Information System (INIS)

Damgov, I.; Genchev, V.; Kolosov, V.A.; Lokhtin, I.P.; Petrushanko, S.V.; Sarycheva, L.I.; Teplov, S.Yu.; Shmatov, S.V.; Zarubin, P.I.

2001-01-01

The capability of the very forward (HF) calorimeter of the CMS detector at LHC to be applied to specific studies with heavy ion beams is discussed. The simulated responses of the HF calorimeter to nucleus-nucleus collisions are used for the analysis of different problems: reconstruction of the total energy flow in the forward rapidity region, accuracy of determination of the impact parameter of collision, study of fluctuations of the hadronic-to-electromagnetic energy ratio, fast inelastic event selection

Evolution of branch points for a laser beam propagating through an uplink turbulent atmosphere.

Science.gov (United States)

Ge, Xiao-Lu; Liu, Xuan; Guo, Cheng-Shan

2014-03-24

Evolution of branch points in the distorted optical field is studied when a laser beam propagates through turbulent atmosphere along an uplink path. Two categories of propagation events are mainly explored for the same propagation height: fixed wavelength with change of the turbulence strength and fixed turbulence strength with change of the wavelength. It is shown that, when the beam propagates to a certain height, the density of the branch-points reaches its maximum and such a height changes with the turbulence strength but nearly remains constant with different wavelengths. The relationship between the density of branch-points and the Rytov number is also given. A fitted formula describing the relationship between the density of branch-points and propagation height with different turbulence strength and wavelength is found out. Interestingly, this formula is very similar to the formula used for describing the Blackbody radiation in physics. The results obtained may be helpful for atmospheric optics, astronomy and optical communication.

Hf{sub 3}Fe{sub 4}Sn{sub 4} and Hf{sub 9}Fe{sub 4−x}Sn{sub 10+x}: Two stannide intermetallics with low-dimensional iron sublattices

Energy Technology Data Exchange (ETDEWEB)

Calta, Nicholas P. [Department of Chemistry, Northwestern University (United States); Kanatzidis, Mercouri G., E-mail: m-kanatzidis@northwestern.edu [Department of Chemistry, Northwestern University (United States); Materials Science Division, Argonne National Laboratory (United States)

2016-04-15

This article reports two new Hf-rich intermetallics synthesized using Sn flux: Hf{sub 3}Fe{sub 4}Sn{sub 4} and Hf{sub 9}Fe{sub 4−x}Sn{sub 10+x}. Hf{sub 3}Fe{sub 4}Sn{sub 4} adopts an ordered variant the Hf{sub 3}Cu{sub 8} structure type in orthorhombic space group Pnma with unit cell edges of a=8.1143(5) Å, b=8.8466(5) Å, and c=10.6069(6) Å. Hf{sub 9}Fe{sub 4−x}Sn{sub 10+x}, on the other hand, adopts a new structure type in Cmc2{sub 1} with unit cell edges of a=5.6458(3) Å, b=35.796(2) Å, and c=8.88725(9) Å for x=0. It exhibits a small amount of phase width in which Sn substitutes on one of the Fe sites. Both structures are fully three-dimensional and are characterized by pseudo one- and two-dimensional networks of Fe–Fe homoatomic bonding. Hf{sub 9}Fe{sub 4−x}Sn{sub 10+x} exhibits antiferromagnetic order at T{sub N}=46(2) K and its electrical transport behavior indicates that it is a normal metal with phonon-dictated resistivity. Hf{sub 3}Fe{sub 4}Sn{sub 4} is also an antiferromagnet with a rather high ordering temperature of T{sub N}=373(5) K. Single crystal resistivity measurements indicate that Hf{sub 3}Fe{sub 4}Sn{sub 4} behaves as a Fermi liquid at low temperatures, indicating strong electron correlation. - Graphical abstract: Slightly different growth conditions in Sn flux produce two new intermetallic compounds: Hf{sub 3}Fe{sub 4}Sn{sub 4} and Hf{sub 9}Fe{sub 4−x}Sn{sub 10+x}. - Highlights: • Single crystals of both Hf{sub 3}Fe{sub 4}Sn{sub 4} and Hf{sub 9}Fe{sub 4−x}Sn{sub 10+x} were grown using Sn flux. • The crystal structures were determined using single crystal X-ray diffraction. • The Fe moments in Hf{sub 3}Fe{sub 4}Sn{sub 4} display AFM order below T{sub N}=373 K. • The Fe moments in Hf{sub 9}Fe{sub 4−x}Sn{sub 10+x} display AFM order below T{sub N}=46 K.

Comparison of HF radar measurements with Eulerian and Lagrangian surface currents

Science.gov (United States)

Röhrs, Johannes; Sperrevik, Ann Kristin; Christensen, Kai Håkon; Broström, Göran; Breivik, Øyvind

2015-05-01

High-frequency (HF) radar-derived ocean currents are compared with in situ measurements to conclude if the radar observations include effects of surface waves that are of second order in the wave amplitude. Eulerian current measurements from a high-resolution acoustic Doppler current profiler and Lagrangian measurements from surface drifters are used as references. Directional wave spectra are obtained from a combination of pressure sensor data and a wave model. Our analysis shows that the wave-induced Stokes drift is not included in the HF radar-derived currents, that is, HF radars measure the Eulerian current. A disputed nonlinear correction to the phase velocity of surface gravity waves, which may affect HF radar signals, has a magnitude of about half the Stokes drift at the surface. In our case, this contribution by nonlinear dispersion would be smaller than the accuracy of the HF radar currents, hence no conclusion can be made. Finally, the analysis confirms that the HF radar data represent an exponentially weighted vertical average where the decay scale is proportional to the wavelength of the transmitted signal.

Nanotube formation and morphology change of Ti alloys containing Hf for dental materials use

International Nuclear Information System (INIS)

Jeong, Yong-Hoon; Lee, Kang; Choe, Han-Cheol; Ko, Yeong-Mu; Brantley, William A.

2009-01-01

In this paper, Ti-Hf (10, 20, 30 and 40 wt.%) alloys were prepared by arc melting, and subjected to heat treatment for 24 h at 1000 o C in an argon atmosphere. Formation of surface nanotubes was achieved by anodizing a Ti-Hf alloy in 1.0 M H 3 PO 4 electrolytes with small amounts of NaF at room temperature. Microstructures of the alloys and nanotube morphology were examined by field-emission scanning electron microscopy (FE-SEM) and X-ray diffraction (XRD). The homogenized Ti-Hf alloys had a needle-like microstructure of α phase, and nanotubes formed on Ti-xHf alloys had the anatase phase after treatment that promoted crystallization. Uniform nanotubes formed for Hf contents up to 20 wt.%. Irregular nanotubes formed on the Ti-30Hf and Ti-40Hf alloys. The structure of the irregular layers on the Ti-30Hf and Ti-40Hf alloys had nanotubes of two sizes. Increasing the Hf content in Ti led to the formation of nanotubes with more narrow size. The pores in the nanotubes typically had a diameter ranging from 80-120 nm and a length of approximately 1.7 μm. It is concluded that nanotube morphology on Ti-Hf alloys can controlled by varying the amount of Hf.

Focused proton beams propagating in reactor of fusion power plant

Energy Technology Data Exchange (ETDEWEB)

Niu, K [Teikyo Heisei Univ., Uruido, Ichihara, Chiba (Japan)

1997-12-31

One of the difficult tasks of light ion beam fusion is to propagate the beam in the reactor cavity and to focus the beam on the target. The light ion beam has a certain local divergence angle because there are several causes for divergence at the diode. The electrostatic force induced at the leading edge causes beam divergence during propagation. To confine the beam within a small radius during propagation, the magnetic field must be employed. Here the electron beam is proposed to be launched simultaneously with the launching of the proton beam. If the electron beam has the excess current, the beam induces a magnetic field in the negative azimuthal direction, which confines the ion beam within a small radius by the electrostatic field as well as the electron beam by the Lorentz force. The metal guide around the beam path helps the beam confinement and reduces the total amount of magnetic field energy induced by the electron current. (author). 2 figs., 15 refs.

A Study of Solar Flare Effects on Mid and High Latitude Radio Wave Propagation using SuperDARN.

Science.gov (United States)

Ruohoniemi, J. M.; Chakraborty, S.; Baker, J. B.

2017-12-01

Over the Horizon (OTH) communication is strongly dependent on the state of the ionosphere, which is sensitive to solar X-ray flares. The Super Dual Auroral Radar Network (SuperDARN), whose working principle is dependent on trans-ionospheric radio communication, uses HF radio waves to remotely sense the ionosphere. The backscatter returns from the terrestrial surface (also known as ground-scatter) transit the ionosphere four times and simulate the operation of an HF communications link. SuperDARN backscatter signal properties are altered (strongly attenuated and changes apparent phase) during a sudden ionospheric disturbance following a solar flare, commonly known as Short-Wave Fadeout or SWF. During an SWF the number of SuperDARN backscatter echoes drops suddenly (≈1 min) and sharply, often to near zero, and recovers within 30 minutes to an hour. In this study HF propagation data (SuperDARN backscatter) obtained during SWF events are analyzed for the purpose of validating and improving the performance of HF absorption models, such as, Space Weather Prediction Center (SWPC) D-region Absorption model (DRAP) and CCMC physics based AbbyNormal model. We will also present preliminary results from a physics based model for the mid and high latitude ionospheric response to flare-driven space weather anomalies, which can be used to estimate different physical parameters of the ionosphere such as electron density, collision frequency, absorption coefficients, response time of D-region etc.

Oxidation behavior of TiC, ZrC, and HfC dispersed in oxide matrices

International Nuclear Information System (INIS)

Arun, R.; Subramanian, M.; Mehrotra, G.M.

1990-01-01

The oxidation behavior of hot pressed TiC-Al 2 O 3 , TiC-ZrO 2 , ZrC-ZrO 2 , and HfC-HfO 2 composites has been investigated at 1273 K. The oxidation of TiC, ZrC, and HfC in hot-pressed composites containing ZrO 2 and HfO 2 has been found to be extremely rapid. The kinetics of oxidation of TiC and a 90 wt% TiC-Al 2 O 3 composite appear to be faster compared to that of pure TiC. X-ray diffraction results for hot-pressed ZrC-HfO 2 and HfC-HfO 2 composites indicate partial stabilization of tetragonal ZrO 2 and HfO 2 phases in these composites

[Effect of a multifunctional instrument (HF scissors) in parotis surgery].

Science.gov (United States)

Strauss, G; Schaller, S; Gollnick, I

2014-03-01

Lateral parotidectomy is a demanding surgical procedure and requires a large number of instruments with a high frequency (HF) of alternating. Many functions, such as preparing, spreading, coagulating and cutting could be combined by using scissors with an integrated function of bipolar coagulation. This study has targeted an investigation of technical application, influence on surgery time, frequency of HF application and change of instruments. In the period between 01 April 2011 and 30 September 2012 (18 months) 35 procedures of lateral parotidectomy in 35 patients were investigated. In all cases lateral parotidectomy was carried out with a similar technique (modified extracapsular preparation). Workflow data were used from a control group in the period between 01 January 2009 and 31 December 2010 (24 months). The following parameters from both groups were documented and evaluated: incision-suture times (subdivided into nine sections of the procedure), change of instruments, period of application for HF function and early facial nerve function (6 h and 6 days after surgery according to House-Brackmann). Additionally, in the HF+ group a questionnaire that facilitated subjective evaluation of instruments was analyzed. It was possible to perform the surgery in both groups with neither technical nor surgical intraoperative complications. Incision-suture times showed an average reduction of 31.6 min (34.8 %) in the HF+ group. There was a reduction in the change of instruments compared to a conventional group (CONV) by up to 62.7 %. With the deployment of HF scissors there was a clear increase in the use of HF surgery by more than 100 % when comparing incision-suture times. Evaluation of both groups according to House-Brackmann showed a similar postoperative facial nerve function. The surgeons involved were of the opinion that in all 35 surgeries with HF scissors the intervention was easier and more comfortable. The use of HF scissors is appropriate for parotid gland

Proof of the path integral representation of the nonlinear Fokker-Planck equation by means of Fourier series

International Nuclear Information System (INIS)

Dekker, H.

1978-01-01

The lagrangian for the action occurring in the path integral solution of the nonlinear Fokker-Planck equation with constant diffusion function is derived by means of a straightforward Fourier series analysis. In this manner the path between the prepoint and the postpoint in the short time propagator is not restricted a priori to the usually considered straight line. Earlier results by Graham, Stratonovich, Horsthemke and Back, and the author's are recovered and thus put on much safer ground. (Auth.)

Medium-scale traveling ionospheric disturbances over Taiwan observed with HF Doppler sounding

Czech Academy of Sciences Publication Activity Database

Fišer, Jiří; Chum, Jaroslav; Liu, J. Y.

2017-01-01

Roč. 69, č. 1 (2017), č. článku 131. ISSN 1880-5981 R&D Projects: GA ČR(CZ) GC15-07281J Institutional support: RVO:68378289 Keywords : Ionosphere * MSTIDs * HF Doppler sounding * atmospheric gravity-waves * f-region * radar * midlatitudes * GPS * thermosphere * typhoon * propagation * origin * model Subject RIV: DG - Athmosphere Sciences, Meteorology OBOR OECD: Meteorology and atmospheric sciences Impact factor: 2.243, year: 2016 https://link.springer.com/epdf/10.1186/s40623-017-0719-y?author_access_token=2ZsbOK__dXYBPg3JeUnMRG_BpE1tBhCbnbw3BuzI2RPoX9yp_OQ2oidt3ZsPeTu1PzUzaEkwP-1WNoKL6B1OXd0-5E40nSdNe-QGMtoHWSkJ1GBaHrp-FbkCnI1e0lljqxm3v0C2G-fVOGqiWs7_OQ%3D%3D

OBSERVATION OF FATIGUE CRACK PATHS IN NODULAR CAST IRON AND ADI MICROSTRUCTURES

Directory of Open Access Journals (Sweden)

Lukáš Bubenko

2009-07-01

Full Text Available When speaking about quality of construction materials, fatigue crack propagation resistance is one of the most important considered properties. That is essentially influenced by character of matrix. Here presented contribution deals with the fatigue crack propagation mode through the matrix of as-cast nodular cast iron (NCI and austempered ductile iron (ADI, whereas influence of microstructure has been considered and discussed. Experimental materials used in presented contribution were pearlitc-ferritic NCI and heat treated ADI 800. Pearlitic-ferritic NCI was used as the base for ADI production. Experiments were performed on mini round compact tension (RCT specimens using an Amsler vibrophore. Fatigue crack paths in both materials were investigated and compared. Light microscopy was used to analyze the microstructure, crack initiation and propagation within broken specimens. In both tested materials fatigue cracks always initiated at graphite-matrix interface, while graphite nodules remained generally unbroken, eventually only surface of nodules was damaged. Though, comparing two materials with different microstructures, the diversity of fatigue crack propagation modes at high deltaK and low deltaK was observed.

Burning velocity of the heterogeneous flame propagation in the SHS process expressed in explicit form

International Nuclear Information System (INIS)

Makino, A.; Law, C.K.

1995-01-01

The combustion behavior of the self-propagating high-temperature synthesis (SHS) process has been the subject of many analytical and experimental investigations. Recently, a theory based on spray combustion was proposed for the SHS flame structure and propagation. In contrast to previous studies based on the homogeneous premixed flame, this theory accounts for the premixed-mode of propagation of the bulk flame and the non-premixed reaction of the dispersed nonmetal (or higher melting-point metal) particles which supports the bulk flame. Finite-rate reaction at the particle surface and the temperature-dependent, Arrhenius nature of mass diffusion are both incorporated. The heterogeneous nature of the theory has satisfactorily captured the effects of particle size on the flame propagation speed. The final solution of Makino and Law was obtained numerically and hence presented parametrically. The authors have since then derived an approximate analytical expression for the burning velocity, which explicitly displays the functional dependence of the burning velocity on the various system parameters. This result is presented herein. Applicability of this expression is examined by comparing it with the numerical results for Ti-C, Ti-B, Zr-B, Hf-B, and Co-Ti systems. A fair degree of agreement has been shown as far as the general trend and approximate magnitude are concerned

Particle propagation and acceleration in the heliosphere

International Nuclear Information System (INIS)

Valdes-Galicia, J.F.; Quenby, J.J.; Mousas, X.

1988-01-01

A realistic model of interplanetary magnetic field perturbations has been constructed based on data taken on board spacecraft. The model has been used to study numerically pitch angle scattering suffered by energetic particles (1-100 MeV) as they propagate in the Heliosphere. These numerical experiments allow the determination of the pitch angle diffusion coefficient Dμ and the associated mean free path λ. Dμ is found to be always smaller than implied by quasi linear theory, leading to radial mean free paths (λ r ≅ 0.015 AU) that are at least 3 times larger. Inclusion of solar wind velocity measurements in the model producing V x B random electric fields permits the study of stochastic acceleration caused by these fields. Initial results show that these processes might be able to overcome the effects of adiabatic cooling caused by the expansion of the solar wind and thus be of some influence in cosmic ray acceleration when extrapolated to other astrophysical environments

CUTLASS HF radar observations of high-latitude azimuthally propagating vortical currents in the nightside ionosphere during magnetospheric substorms

Directory of Open Access Journals (Sweden)

J. A. Wild

Full Text Available High-time resolution CUTLASS observations and ground-based magnetometers have been employed to study the occurrence of vortical flow structures propagating through the high-latitude ionosphere during magnetospheric substorms. Fast-moving flow vortices (~800 m s^-1 associated with Hall currents flowing around upward directed field-aligned currents are frequently observed propagating at high speed (~1 km s^-1 azimuthally away from the region of the ionosphere associated with the location of the substorm expansion phase onset. Furthermore, a statistical analysis drawn from over 1000 h of high-time resolution, nightside radar data has enabled the characterisation of the bulk properties of these vortical flow systems. Their occurrence with respect to substorm phase has been investigated and a possible generation mechanism has been suggested.

Key words: Ionosphere (auroral ionosphere; electric fields and currents · Magnetospheric physics (storms and substorms

A microstructural study of dynamic crack propagation in nuclear graphites

International Nuclear Information System (INIS)

Burchell, T.D.; McEnaney, B.; Tucker, M.O.; Rose, A.P.G.

1986-01-01

This paper reports a new microstructural study of dynamic crack propagation in three nuclear graphites: (i) PGA, the moderator material in UK Magnox reactors; (ii) IMl-24, the moderator material in UK Advanced gas cooled reactors (AGR); and (iii) a pitch coke graphite, which is used in the fabrication of AGR fuel sleeves. The fracture mechanisms in nuclear graphites are initiated by microcrack formation at low stresses. Typically, microcracks form in regions of well-aligned binder or at favourably-oriented pores, where stress is concentrated. With increasing applied loads, microcracks propagate taking advantage of easy cleavage paths or linking with pores. Eventually, coalescence of such cracks and inherent porosity produces a crack of critical length for fast fracture. (orig./MM)

Crystal structures of KM(AsF{sub 6}){sub 3} (M{sup 2+} = Mg, Co, Mn, Zn), KCu(SbF{sub 6}){sub 3} and [Co(HF){sub 2}]Sr[Sr(HF)]{sub 2}-[Sr(HF){sub 2}]{sub 2}[AsF{sub 6}]{sub 12}

Energy Technology Data Exchange (ETDEWEB)

Mazej, Zoran; Goreshnik, Evgeny [Jozef Stefan Institute, Ljubljana (Slovakia). Dept. of Inorganic Chemisrty and Technology

2015-05-01

The KM(AsF{sub 6}){sub 3} (M{sup 2+} = Mg, Co, Mn, Zn) and KCu(SbF{sub 6}){sub 3} compounds crystallize isotypically to previously known KNi(AsF{sub 6}){sub 3}. The main features of the structure of these compounds are rings of MF{sub 6} octahedra sharing apexes with AsF{sub 6} octahedra connected into infinite tri-dimensional frameworks. In this arrangement cavities are formed where K{sup +} cations are placed. Single crystals of CoSr{sub 5}(AsF{sub 6}){sub 12}.8HF were obtained as one of the products after the crystallization of 3KF/CoF{sub 2}/SrF{sub 2} mixture in the presence of AsF{sub 5} in anhydrous HF. The CoSr{sub 5}(AsF{sub 6}){sub 12}.8HF is monoclinic, C/2c (No.15), with a = 26.773(5) Aa, b = 10.087(2) Aa, c = 21.141(5) Aa, β = 93.296(13) {sup circle}, V = 5699.9(19) Aa{sup 3} at 200 K, and Z = 4. There are three crystallographically non-equivalent Sr{sup 2+} cations in the crystal structure of CoSr{sub 5}(AsF{sub 6}){sub 12}.8HF. The Sr1 is coordinated by ten fluorine atoms from eight different [AsF{sub 6}]- anions, meanwhile Sr2 and Sr3 are bound to nine fluorine atoms provided by one HF and eight AsF{sub 6} units or by two HF and six AsF{sub 6} units, respectively. The Co{sup 2+} is coordinated distorted-octahedrally by six fluorine atoms from two HF molecules and four different AsF{sub 6} units. All those moieties in the crystal structure of [Co(HF){sub 2}]Sr[Sr(HF)]{sub 2}[Sr(HF){sub 2}]{sub 2}[AsF{sub 6}]{sub 12} are connected into tridimensional framework. The CoSr{sub 5}(AsF{sub 6}){sub 12}.8HF is a unique example of compound where HF molecules are directly bound via fluorine atoms to two different metal centres.

Space-time picture of relativistic propagation of medium energy hadrons through nuclei

International Nuclear Information System (INIS)

Bleszynski, M.; Jaroszewicz, T.

1985-01-01

Relativistic virtual pair creation effects in hadron-nucleus scattering at medium energies are discussed. A close analogy is found between these effects (particle propagation backwards in time) and some of noneikonal correlations to the Glauber theory, arising from particle propagation backwards in space. In multiple scattering both effects appear only for configurations involving overlapping scatterers and lead to the non-additivity of phase shifts. The proper-time path-integral formalism is found to provide an intuitive geometrical picture of these phenomena. The relativistic corrections are estimated to be of the order k/(aE/sup 2/), k being the particle momentum, E its energy, and a the target size. At medium energies they are comparable to noneikonal corrections, of order 1/(ak). Both effects vanish at high energy, when particle propagation in space-time can be described by means of geometrical optics

Investigation on electrical tree propagation in polyethylene based on etching method

Directory of Open Access Journals (Sweden)

Zexiang Shi

2017-11-01

Full Text Available To investigate the characteristic of electrical tree propagation in semi-crystalline polymers, the low-density polyethylene (LDPE samples containing electrical trees are cut into slices by using ultramicrotome. Then the slice samples are etched by potassium permanganate etchant. Finally, the crystalline structure and the electrical tree propagation path in samples are observed by polarized light microscopy (PLM. According to the observation, the LDPE spherocrystal structure model is established on the basis of crystallization kinetics and morphology of polymers. And the electrical tree growth process in LDPE is discussed based on the free volume breakdown theory, the molecular chain relaxation theory, the electromechanical force theory, the thermal expansion effect and the space charge shielding effect.

Study of bulk Hafnium oxide (HfO2) under compression

Science.gov (United States)

Pathak, Santanu; Mandal, Guruprasad; Das, Parnika

2018-04-01

Hafnium oxide (HfO2) is a technologically important material. This material has K-value of 25 and band gap 5.8 eV. A k value of 25-30 is preferred for a gate dielectric [1]. As it shows good insulating and capacitive properties, HfO2 is being considered as a replacement to SiO2 in microelectronic devices as gate dielectrics. On the other hand because of toughening mechanism due to phase transformation induced by stress field observed in these oxides, HFO2 has been a material of investigations in various configurations for a very long time. However the controversies about phase transition of HfO2 under pressure still exists. High quality synchrotron radiation has been used to study the structural phase transition of HfO2 under pressure.

Metal-assisted chemical etching in HF/Na2S2O8 OR HF/KMnO4 produces porous silicon

NARCIS (Netherlands)

Hadjersi, T.; Gabouze, N.; Kooij, Ernst S.; Zinine, A.; Zinine, A.; Ababou, A.; Chergui, W.; Cheraga, H.; Belhousse, S.; Djeghri, A.

2004-01-01

A new metal-assisted chemical etching method using Na2S2O8 or KMnO4 as an oxidizing agent was proposed to form a porous silicon layer on a highly resistive p-type silicon. A thin layer of Ag or Pd is deposited on the Si(100) surface prior to immersion in a solution of HF and Na2S2O8 or HF and KMnO4.

Integral propagator solvers for Vlasov-Fokker-Planck equations

International Nuclear Information System (INIS)

Donoso, J M; Rio, E del

2007-01-01

We briefly discuss the use of short-time integral propagators on solving the so-called Vlasov-Fokker-Planck equation for the dynamics of a distribution function. For this equation, the diffusion tensor is singular and the usual Gaussian representation of the short-time propagator is no longer valid. However, we prove that the path-integral approach on solving the equation is, in fact, reliable by means of our generalized propagator, which is obtained through the construction of an auxiliary solvable Fokker-Planck equation. The new representation of the grid-free advancing scheme describes the inherent cross- and self-diffusion processes, in both velocity and configuration spaces, in a natural manner, although these processes are not explicitly depicted in the differential equation. We also show that some splitting methods, as well as some finite-difference schemes, could fail in describing the aforementioned diffusion processes, governed in the whole phase space only by the velocity diffusion tensor. The short-time transition probability offers a stable and robust numerical algorithm that preserves the distribution positiveness and its norm, ensuring the smoothness of the evolving solution at any time step. (fast track communication)

Small signal gain measurements in a small scale HF overtone laser

Energy Technology Data Exchange (ETDEWEB)

Wisniewski, C.F.; Hewett, K.B.; Manke, G.C. II; Hager, G.D. [Air Force Research Laboratory, Directed Energy Directorate, 3550 Aberdeen Ave SE, Kirtland AFB, NM 87117-5776 (United States); Crowell, P.G. [Northrup Grumman Information Technology, Science and Technology Operating Unit, Advanced Technology Division, P.O. Box 9377, Albuquerque, NM 87119-9377 (United States); Truman, C.R. [Mechanical Engineering Department, University of New Mexico, Albuquerque, NM 87131 (United States)

2003-07-01

The overtone gain medium of a small-scale HF overtone laser was probed using a sub-Doppler tunable diode laser. Two-dimensional spatially resolved small signal gain and temperature maps were generated for several ro-vibrational transitions in the HF (v=2{yields}v=0) overtone band. Our results compare well with previous measurements of the overtone gain in a similar HF laser device. (orig.)

Suspended HfO2 photonic crystal slab on III-nitride/Si platform

International Nuclear Information System (INIS)

Wang, Yongjin; Feng, Jiao; Cao, Ziping; Zhu, Hongbo

2014-01-01

We present here the fabrication of suspended hafnium oxide (HfO 2 ) photonic crystal slab on a III-nitride/Si platform. The calculations are performed to model the suspended HfO 2 photonic crystal slab. Aluminum nitride (AlN) film is employed as the sacrificial layer to form air gap. Photonic crystal patterns are defined by electron beam lithography and transferred into HfO 2 film, and suspended HfO 2 photonic crystal slab is achieved on a III-nitride/Si platform through wet-etching of AlN layer in the alkaline solution. The method is promising for the fabrication of suspended HfO 2 nanostructures incorporating into a III-nitride/Si platform, or acting as the template for epitaxial growth of III-nitride materials. (orig.)

Integrated magnetics design for HF-link power converters

Energy Technology Data Exchange (ETDEWEB)

Ljusev, P.; Andersen, Michael A.E.

2005-07-01

This paper deals with the design of integrated magnetics for HF-link converters, where the two integrated magnetic components on the same core do not necessarily belong to the same voltage loop. Depending on the specific HF-link converter topology, the proposed integrated magnetics can either alleviate the derivation of independent auxiliary supply voltages from the main transformer or integrate other magnetic structures, thus saving board space and cutting costs. (au)

Fretting wear of ZrN and Zr(21% Hf)N coatings

Energy Technology Data Exchange (ETDEWEB)

Atar, E. [Gebze Inst. of Tech., Material Science and Engineering Dept., Kocaeli (Turkey); Cimenoglu, H.; Kayali, E.S. [Istanbul Technical Univ., Dept. of Metallurgy and Materials Engineering, Istanbul (Turkey)

2004-07-01

In this study, the wear behaviours of ZrN and Zr(21% Hf)N coatings, deposited on hardened AISI D2 cold work tool steel were examined by a fretting wear tester. The hardness of ZrN and Zr(21% Hf)N coatings were almost the same, where as they exhibited different wear resistance. Addition of 21% Hf to ZrN coating achieved about 25% increase in the wear resistance. (orig.)

Fretting wear of ZrN and Zr(21% Hf)N coatings

International Nuclear Information System (INIS)

Atar, E.; Cimenoglu, H.; Kayali, E.S.

2004-01-01

In this study, the wear behaviours of ZrN and Zr(21% Hf)N coatings, deposited on hardened AISI D2 cold work tool steel were examined by a fretting wear tester. The hardness of ZrN and Zr(21% Hf)N coatings were almost the same, where as they exhibited different wear resistance. Addition of 21% Hf to ZrN coating achieved about 25% increase in the wear resistance. (orig.)

Reliability assessment of ultra-thin HfO{sub 2} films deposited on silicon wafer

Energy Technology Data Exchange (ETDEWEB)

Fu, Wei-En [Center for Measurement Standards, Industrial Technology Research Institute, Room 216, Building 8, 321 Kuang Fu Road Sec. 2, Hsinchu, Taiwan (China); Chang, Chia-Wei [Department of Materials Science and Engineering, National Cheng Kung University, 1 University Road, Tainan 70101, Taiwan (China); Chang, Yong-Qing [Center for Measurement Standards, Industrial Technology Research Institute, Room 216, Building 8, 321 Kuang Fu Road Sec. 2, Hsinchu, Taiwan (China); Yao, Chih-Kai [Department of Materials Science and Engineering, National Cheng Kung University, 1 University Road, Tainan 70101, Taiwan (China); Liao, Jiunn-Der, E-mail: jdliao@mail.ncku.edu.tw [Department of Materials Science and Engineering, National Cheng Kung University, 1 University Road, Tainan 70101, Taiwan (China)

2012-09-01

Highlights: Black-Right-Pointing-Pointer Nano-mechanical properties on annealed ultra-thin HfO{sub 2} film are studied. Black-Right-Pointing-Pointer By AFM analysis, hardness of the crystallized HfO{sub 2} film significantly increases. Black-Right-Pointing-Pointer By nano-indention, the film hardness increases with less contact stiffness. Black-Right-Pointing-Pointer Quality assessment on the annealed ultra-thin films can thus be achieved. - Abstract: Ultra-thin hafnium dioxide (HfO{sub 2}) is used to replace silicon dioxide to meet the required transistor feature size in advanced semiconductor industry. The process integration compatibility and long-term reliability for the transistors depend on the mechanical performance of ultra-thin HfO{sub 2} films. The criteria of reliability including wear resistance, thermal fatigue, and stress-driven failure rely on film adhesion significantly. The adhesion and variations in mechanical properties induced by thermal annealing of the ultra-thin HfO{sub 2} films deposited on silicon wafers (HfO{sub 2}/SiO{sub 2}/Si) are not fully understood. In this work, the mechanical properties of an atomic layer deposited HfO{sub 2} (nominal thickness Almost-Equal-To 10 nm) on a silicon wafer were characterized by the diamond-coated tip of an atomic force microscope and compared with those of annealed samples. The results indicate that the annealing process leads to the formation of crystallized HfO{sub 2} phases for the atomic layer deposited HfO{sub 2}. The HfSi{sub x}O{sub y} complex formed at the interface between HfO{sub 2} and SiO{sub 2}/Si, where the thermal diffusion of Hf, Si, and O atoms occurred. The annealing process increases the surface hardness of crystallized HfO{sub 2} film and therefore the resistance to nano-scratches. In addition, the annealing process significantly decreases the harmonic contact stiffness (or thereafter eliminate the stress at the interface) and increases the nano-hardness, as measured by vertically

Simultaneous measurements of HF-enhanced plasma waves and artificial field-aligned irregularities at Arecibo

International Nuclear Information System (INIS)

Noble, S.T.; Djuth, F.T.

1990-01-01

Two radar systems with beams intersecting in the HF-modified F region were used to simultaneously measure HF-enhanced plasma lines (HFPLs) and artificial geomagnetic field-aligned irregularities (AFAIs). The Arecibo 430-MHz radar was used for the HFPL observations, and a portable 49.92-MHz backscatter radar was deployed on the island of Guadeloupe to monitor the AFAIs. The experiment was desgined to examine the degree to which HF-induced plasma turbulence influences the development of AFAIs. When the HF beam is stepped up in power, sustained HFPLs and AFAIs are first observed at the same HF power level, indicating that ponderomotively driven instabilities may be involved in the early time development of AFAIs. As the HF power is increased, the HFPL backscatter power begins to saturate at ∼70 MW effective radiated power (ERP). However, the backscatter from AFAIs is linearly dependent on HF power, even at the highest (120 MW ERP) HF power levels available at Arecibo. This suggests that additional processes may contribute to the development of AFAIs. For example, ponderomotively driven instabilities may give rise to weak geomagnetic field-aligned irregularities that are subsequently driven unstable by processes excited near the upper hybrid resonance. It is also likely that AFAIs greatly impact the development of HF-induced plasma turbulence at late times (>1 s) following HF turn-on. Once the ionosphere is preconditioned by high-power HF modifications, AFAIs and HFPLs can be simultaneously sustained at a much lower HF power level than that needed to originally excite them. The nature of the preconditioning process is currently not well understood. New theoretical initiatives are clearly needed to guide future experimental activity in this area

Pulsed inductive HF laser

Energy Technology Data Exchange (ETDEWEB)

Razhev, A M; Kargapol' tsev, E S [Institute of Laser Physics, Siberian Branch, Russian Academy of Sciences, Novosibirsk (Russian Federation); Churkin, D S; Demchuk, S V [Novosibirsk State University, Novosibirsk (Russian Federation)

2016-03-31

We report the results of experimentally investigated dependences of temporal, spectral and spatial characteristics of an inductive HF-laser generation on the pump conditions. Gas mixtures H{sub 2} – F{sub 2}(NF{sub 3} or SF6{sub 6}) and He(Ne) – H{sub 2} – F{sub 2}(NF{sub 3} or SF{sub 6}) were used as active media. The FWHM pulse duration reached 0.42 μs. This value corresponded to a pulsed power of 45 kW. For the first time, the emission spectrum of an inductive HF laser was investigated, which consisted of seven groups of bands with centres around the wavelengths of 2732, 2736, 2739, 2835, 2837, 2893 and 2913 nm. The cross section profile of the laser beam was a ring with a diameter of about 20 mm and width of about 5 mm. Parameters of laser operation in the repetitively pulsed regime were sufficiently stable. The amplitude instability of light pulses was no greater than 5% – 6%. (lasers)

Relationships between GPS-signal propagation errors and EISCAT observations

Directory of Open Access Journals (Sweden)

N. Jakowski

1996-12-01

Full Text Available When travelling through the ionosphere the signals of space-based radio navigation systems such as the Global Positioning System (GPS are subject to modifications in amplitude, phase and polarization. In particular, phase changes due to refraction lead to propagation errors of up to 50 m for single-frequency GPS users. If both the L1 and the L2 frequencies transmitted by the GPS satellites are measured, first-order range error contributions of the ionosphere can be determined and removed by difference methods. The ionospheric contribution is proportional to the total electron content (TEC along the ray path between satellite and receiver. Using about ten European GPS receiving stations of the International GPS Service for Geodynamics (IGS, the TEC over Europe is estimated within the geographic ranges -20°≤ λ ≤40°E and 32.5°≤ Φ ≤70°N in longitude and latitude, respectively. The derived TEC maps over Europe contribute to the study of horizontal coupling and transport proces- ses during significant ionospheric events. Due to their comprehensive information about the high-latitude ionosphere, EISCAT observations may help to study the influence of ionospheric phenomena upon propagation errors in GPS navigation systems. Since there are still some accuracy limiting problems to be solved in TEC determination using GPS, data comparison of TEC with vertical electron density profiles derived from EISCAT observations is valuable to enhance the accuracy of propagation-error estimations. This is evident both for absolute TEC calibration as well as for the conversion of ray-path-related observations to vertical TEC. The combination of EISCAT data and GPS-derived TEC data enables a better understanding of large-scale ionospheric processes.

Solvent Effects on Nuclear Magnetic Resonance 2J(C,Hf and 1J(C,Hf Spin–Spin Coupling Constants in Acetaldehyde

Directory of Open Access Journals (Sweden)

Angel Esteban

2003-02-01

Full Text Available Abstract: The known solvent dependence of 1J(Cc,Hf and 2J(C1,Hf couplings in acetaldehyde is studied from a theoretical viewpoint based on the density functional theory approach where the dielectric solvent effect is taken into account with the polarizable continuum model. The four terms of scalar couplings, Fermi contact, paramagnetic spin orbital, diamagnetic spin orbital and spin dipolar, are calculated but the solvent effect analysis is restricted to the first term since for both couplings it is by far the dominant contribution. Experimental trends of Δ1J(Cc,Hf and Δ2J(C1,Hf Vs ε (the solvent dielectric constant are correctly reproduced although they are somewhat underestimated. Specific interactions between solute and solvent molecules are studied for dimethylsulfoxide, DMSO, solutions considering two different one-to-one molecular complexes between acetaldehyde and DMSO. They are determined by interactions of type C=O---H---C and S=O---H---C, and the effects of such interactions on 1J(Cc,Hf and 2J(C1,Hf couplings are analyzed. Even though only in a semiquantitative way, it is shown that the effect of such interactions on the solvent effects, of Δ1J(Cc,Hf and Δ2J(C1,Hf, tend to improve the agreement between calculated and experimental values. These results seem to indicate that a continuum dielectric model has not enough flexibility for describing quantitatively solvent effects on spin-spin couplings. Apparently, even for relatively weak hydrogen bonding, the contribution from “direct” interactions is of the same order of magnitude as the “dielectric” effect.

Shoot cuttings propagation of giant reed (Arundo donax L.) in water and moist soil: The path forward?

Energy Technology Data Exchange (ETDEWEB)

Ceotto, Enrico; Di Candilo, Mario [C.R.A. - Centro di Ricerca per le Colture Industriali, Via di Corticella 133, 40128 Bologna (Italy)

2010-11-15

Giant reed (Arundo donax L.) is a perennial rhizomatous grass that can be regarded as an ideal crop for bioenergy production, owing to several intrinsic characteristics. Despite to the promising yield results obtained in many plot experiments, the cultivation of giant reed at field scale is still a challenge. Owing to the floral sterility of the species, rhizome propagation has been predominantly used to establish field plots experiments, although this method is unpractical and monetarily expensive. Giant reed is a hydrophytic plant that typically spread in riparian systems by flood-mediated fragmentation and dispersal of vegetative propagules. Since giant reed propagation is strictly dependent on temporary abundance of water, this plant characteristic might be exploited for fostering the diffusion of giant reed as a bioenergy field crop. The objectives of this paper were: i) to disseminate some techniques for shoot cutting propagation of giant reed in water and in moist soil; ii) to address the critical points that remain to be solved for a widespread diffusion of this species as a bioenergy field crop. (author)

Lu-Hf isotope systematics of fossil biogenic apatite and their effects on geochronology

Science.gov (United States)

Herwartz, Daniel; Münker, Carsten; Tütken, Thomas; Hoffmann, J. Elis; Wittke, Andreas; Barbier, Bruno

2013-01-01

Reliable methods for direct dating of biogenic apatite from pre-Pleistocene fossils are currently not available, and recent attempts using the Lu-Hf decay system yielded highly inaccurate ages for both bones and teeth. The geological processes accounting for this poor accuracy of Lu-Hf chronometry are not yet understood. Here we explore Lu-Hf systematics in fossil bones and teeth in detail, by applying five different sample digestion techniques that are tested on bones and composites of bone and sediment. Our current dataset implies that dissolution methods only slightly affect the resulting Lu-Hf ages, while clear differences between the individual digestion techniques became apparent for element concentrations. By analysing the insoluble leftovers from incomplete sample dissolution, four main reservoirs of Hf in fossil bones were identified: (1) a radiogenic end-member associated with apatite; (2) an unradiogenic end-member represented by the authigenic minerals or the embedding sediment; (3) a highly unradiogenic end-member that can be attributed to detrital zircon; and (4) a moderately soluble phase (probably a Zr(Hf)-phosphate) that yielded very low Lu/Hf but a highly radiogenic Hf isotope composition at the same time. This Zr(Hf)-phase must have been precipitated within the fossil bone sample at a late stage of burial history, thereby incorporating radiogenic 176Hf released from apatite surfaces over geological timescales. A second focus of our study is the effect of different sediment matrices and of crystal size on the preservation of pristine Lu-Hf isotope compositions in bioapatite. Because near-depositional Lu-Hf ages of phosphate fossils have previously been reported for the London Clay (England) and a calcareous marl from Tendaguru (Tanzania), we herein investigate specimens fossilised in carbonate matrices (calcareous marl from Oker, Germany; carbonate concretions from the Santana Formation, Brazil; carbonate from the Eifel, Germany) and argillaceous

Hydrogen fluoride (HF) substance flow analysis for safe and sustainable chemical industry.

Science.gov (United States)

Kim, Junbeum; Hwang, Yongwoo; Yoo, Mijin; Chen, Sha; Lee, Ik-Mo

2017-11-01

In this study, the chemical substance flow of hydrogen fluoride (hydrofluoric acid, HF) in domestic chemical industries in 2014 was analyzed in order to provide a basic material and information for the establishment of organized management system to ensure safety during HF applications. A total of 44,751 tons of HF was made by four domestic companies (in 2014); import amount was 95,984 tons in 2014 while 21,579 tons of HF was imported in 2005. The export amount of HF was 2180 tons, of which 2074 ton (China, 1422 tons, U.S. 524 tons, and Malaysia, 128 tons) was exported for the manufacturing of semiconductors. Based on the export and import amounts, it can be inferred that HF was used for manufacturing semiconductors. The industries applications of 161,123 tons of HF were as follows: manufacturing of basic inorganic chemical substance (27,937 tons), manufacturing of other chemical products such as detergents (28,208 tons), manufacturing of flat display (24,896 tons), and manufacturing of glass container package (22,002 tons). In this study, an analysis of the chemical substance flow showed that HF was mainly used in the semiconductor industry as well as glass container manufacturing. Combined with other risk management tools and approaches in the chemical industry, the chemical substance flow analysis (CSFA) can be a useful tool and method for assessment and management. The current CSFA results provide useful information for policy making in the chemical industry and national systems. Graphical abstract Hydrogen fluoride chemical substance flows in 2014 in South Korea.

Preparation and enhanced oxidation performance of a Hf-doped single-phase Pt-modified aluminide coating

International Nuclear Information System (INIS)

Yang, Y.F.; Jiang, C.Y.; Yao, H.R.; Bao, Z.B.; Zhu, S.L.; Wang, F.H.

2016-01-01

Graphical abstract: Tiny Hf particles were successfully incorporated into Pt plating via simple electro-plating method. The hafnium particles were either nipped at Pt grain boundaries or wrapped inside Pt grains, and most of them were below 3 μm in size, showing a uniform distribution within the Pt plating. - Highlights: • A Hf-rich belt formed between outer (Ni,Pt)Al and IDZ after aluminisation. • Hf-doped coating showed much decreased mass gain and oxidation rate constant k_p. • Hf-rich belt acted as diffusion barrier by restraining diffusions of Al and W. • Degradation of β was effectively postponed by the unique Hf addition. • Hf-doped coating exhibited lighter oxide scale rumpling tendency. - Abstract: A Hf-doped β-(Ni,Pt)Al coating was prepared by co-deposition of a Pt-Hf composite plating and successive aluminisation. Then, a distinct Hf-rich belt was formed internally between the outer additive (Ni,Pt)Al coating and interdiffusion zone. An isothermal oxidation test at 1100 °C revealed a relatively lower oxidation rate constant and decreased oxide scale rumpling tendency for the Hf-doped coating during which the Hf-rich belt partly acted as an effective diffusion barrier. The unique addition of Hf into a β-(Ni,Pt)Al coating can delay the transitional oxidation period from transient alumina to stable one and postpone the degradation from β to γ'.

Hard paths, soft paths or no paths? Cross-cultural perceptions of water solutions

Science.gov (United States)

Wutich, A.; White, A. C.; White, D. D.; Larson, K. L.; Brewis, A.; Roberts, C.

2014-01-01

In this study, we examine how development status and water scarcity shape people's perceptions of "hard path" and "soft path" water solutions. Based on ethnographic research conducted in four semi-rural/peri-urban sites (in Bolivia, Fiji, New Zealand, and the US), we use content analysis to conduct statistical and thematic comparisons of interview data. Our results indicate clear differences associated with development status and, to a lesser extent, water scarcity. People in the two less developed sites were more likely to suggest hard path solutions, less likely to suggest soft path solutions, and more likely to see no path to solutions than people in the more developed sites. Thematically, people in the two less developed sites envisioned solutions that involve small-scale water infrastructure and decentralized, community-based solutions, while people in the more developed sites envisioned solutions that involve large-scale infrastructure and centralized, regulatory water solutions. People in the two water-scarce sites were less likely to suggest soft path solutions and more likely to see no path to solutions (but no more likely to suggest hard path solutions) than people in the water-rich sites. Thematically, people in the two water-rich sites seemed to perceive a wider array of unrealized potential soft path solutions than those in the water-scarce sites. On balance, our findings are encouraging in that they indicate that people are receptive to soft path solutions in a range of sites, even those with limited financial or water resources. Our research points to the need for more studies that investigate the social feasibility of soft path water solutions, particularly in sites with significant financial and natural resource constraints.

Results of Time-of-Flight Neutron Capture Measurements of 176,177,178,179 Hf-enriched and nat Hf samples at 10 m, 30 m and 60 m stations of GELINA

International Nuclear Information System (INIS)

Ware, T.C.; Dean, C.J.; Borella, A.; Kopecky, S.; Moens, A.; Schillebeeckx, P.; Janeva, N.; Moxon, M.C.

2014-04-01

Neutron capture measurements have been performed at the time-offlight facility GELINA to determine neutron resonance parameters for 174,176,177,178,179,180 Hf. In total, 16 distinct experiments were conducted at the 12 m, 28 m and 58 m capture stations using C 6 D 6 detectors with a moderated neutron beam and the accelerator operating at 50 Hz or 800 Hz. Measurements were performed with nat Hf metallic samples and oxide samples enriched in 176 Hf, 177 Hf, 178 Hf and 179 Hf. This report describes the experimental details required to deliver the experimental capture yields to the EXFOR data library which is maintained by the Nuclear Energy Agency of the OECD and the Nuclear Data Section of the IAEA. The experimental conditions and data reduction procedures are described. In addition, the full covariance information based on the AGS concept is given, such that resonance parameters together with their covariances can be derived in a least squares adjustment to the data. (author)

Path coupling and aggregate path coupling

CERN Document Server

Kovchegov, Yevgeniy

2018-01-01

This book describes and characterizes an extension to the classical path coupling method applied to statistical mechanical models, referred to as aggregate path coupling. In conjunction with large deviations estimates, the aggregate path coupling method is used to prove rapid mixing of Glauber dynamics for a large class of statistical mechanical models, including models that exhibit discontinuous phase transitions which have traditionally been more difficult to analyze rigorously. The book shows how the parameter regions for rapid mixing for several classes of statistical mechanical models are derived using the aggregate path coupling method.

Study of UO{sub 2}F{sub 2} - H{sub 2}O - HF compounds; Etude des composes UO{sub 2}F{sub 2} - H{sub 2}O - HF

Energy Technology Data Exchange (ETDEWEB)

Neveu, G [Commissariat a l' Energie Atomique, Saclay (France). Centre d' Etudes Nucleaires

1961-07-01

We study various compounds resulting from the interaction of UO{sub 2}F{sub 2} with H{sub 2}O and HF (gas), and various triple compounds UO{sub 2}F{sub 2} - H{sub 2}O - HF; the conditions of decomposition and the thermodynamic limits of stability are specified. (author) [French] Nous etudions divers composes formes par reaction de UO{sub 2}F{sub 2} avec H{sub 2}O et HF (gaz) et divers composes triples UO{sub 2}F{sub 2} - H{sub 2}O - HF, en essayant de preciser les decompositions et domaines d'exisfence thermodynamiques de ces corps. (auteur)

Constant external fields in gauge theory and the spin 0, 1/2, 1 path integrals

International Nuclear Information System (INIS)

Reuter, M.; Schmidt, M.G.

1996-10-01

We investigate the usefulness of the ''string-inspired technique'' for gauge theory calculations in a constant external field background. Our approach is based on Strassler's worldline path integral approach to the Bern-Kosower formalism, and on the construction of worldline (super-) Green's functions incorporating external fields as well as internal propagators. The worldline path integral representation of the gluon loop is reexamined in detail. We calculate the two-loop effective actions induced for a constant external field by a scalar and spinor loop, and the corresponding one-loop effective action in the gluon loop case. (orig.)

Theoretical and numerical studies of crack initiation and propagation in rock masses under freezing pressure and far-field stress

Directory of Open Access Journals (Sweden)

Yongshui Kang

2014-10-01

Full Text Available Water-bearing rocks exposed to freezing temperature can be subjected to freeze–thaw cycles leading to crack initiation and propagation, which are the main causes of frost damage to rocks. Based on the Griffith theory of brittle fracture mechanics, the crack initiation criterion, propagation direction, and crack length under freezing pressure and far-field stress are analyzed. Furthermore, a calculation method is proposed for the stress intensity factor (SIF of the crack tip under non-uniformly distributed freezing pressure. The formulae for the crack/fracture propagation direction and length of the wing crack under freezing pressure are obtained, and the mechanism for coalescence of adjacent cracks is investigated. In addition, the necessary conditions for different coalescence modes of cracks are studied. Using the topology theory, a new algorithm for frost crack propagation is proposed, which has the capability to define the crack growth path and identify and update the cracked elements. A model that incorporates multiple cracks is built by ANSYS and then imported into FLAC3D. The SIFs are then calculated using a FISH procedure, and the growth path of the freezing cracks after several calculation steps is demonstrated using the new algorithm. The proposed method can be applied to rocks containing fillings such as detritus and slurry.

Luminescence and scintillation properties of Rb2HfCl6 crystals

International Nuclear Information System (INIS)

Saeki, Keiichiro; Wakai, Yuki; Fujimoto, Yutaka; Koshimizu, Masanori; Asai, Keisuke; Yanagida, Takayuki; Nakauchi, Daisuke

2016-01-01

We developed a scintillator based on a Rb 2 HfCl 6 crystal as a ternary halide crystal with intrinsic luminescence. In the photoluminescence spectra, two emission bands are observed at 383 and 434 nm. The 434 nm emission band for Rb 2 HfCl 6 may be attributed to [HfCl 6 ] 2- complex ion or [ZrCl 6 ] 2- impurity, since the Rb 2 HfCl 6 contained Zr as impurity at 0.62 mol %. The radioluminescence band is observed at 420 nm and can be attributed to the same origin as the photoluminescence band at 434 nm. The scintillation decay-time constants were 0.84 and 5.4 μs. The light yield was estimated to be 24,100 photons/MeV. (author)

Atomic scale engineering of HfO{sub 2}-based dielectrics for future DRAM applications

Energy Technology Data Exchange (ETDEWEB)

Dudek, Piotr

2011-02-14

Modern dielectrics in combination with appropriate metal electrodes have a great potential to solve many difficulties associated with continuing miniaturization process in the microelectronic industry. One significant branch of microelectronics incorporates dynamic random access memory (DRAM) market. The DRAM devices scaled for over 35 years starting from 4 kb density to several Gb nowadays. The scaling process led to the dielectric material thickness reduction, resulting in higher leakage current density, and as a consequence higher power consumption. As a possible solution for this problem, alternative dielectric materials with improved electrical and material science parameters were intensively studied by many research groups. The higher dielectric constant allows the use of physically thicker layers with high capacitance but strongly reduced leakage current density. This work focused on deposition and characterization of thin insulating layers. The material engineering process was based on Si cleanroom compatible HfO{sub 2} thin films deposited on TiN metal electrodes. A combined materials science and dielectric characterization study showed that Ba-added HfO{sub 2} (BaHfO{sub 3}) films and Ti-added BaHfO{sub 3} (BaHf{sub 0.5}Ti{sub 0.5}O{sub 3}) layers are promising candidates for future generation of state-of-the-art DRAMs. In especial a strong increase of the dielectric permittivity k was achieved for thin films of cubic BaHfO{sub 3} (k{proportional_to}38) and BaHf{sub 0.5}Ti{sub 0.5}O{sub 3} (k{proportional_to}90) with respect to monoclinic HfO{sub 2} (k{proportional_to}19). Meanwhile the CET values scaled down to 1 nm for BaHfO{sub 3} and {proportional_to}0.8 nm for BaHf{sub 0.5}Ti{sub 0.5}O{sub 3} with respect to HfO{sub 2} (CET=1.5 nm). The Hf{sup 4+} ions substitution in BaHfO{sub 3} by Ti{sup 4+} ions led to a significant decrease of thermal budget from 900 C for BaHfO{sub 3} to 700 C for BaHf{sub 0.5}Ti{sub 0.5}O{sub 3}. Future studies need to focus

Helium implanted AlHf as studied by 181 Ta TDPAC

Indian Academy of Sciences (India)

Measurements on helium implanted sample indicate the binding of helium associated defects by Hf solute clusters. Isochronal annealing measurements indicate the dissociation of the helium implantation induced defects from Hf solute clusters for annealing treatments beyond 650 K. On comparison of the present results ...

Filtered backprojection proton CT reconstruction along most likely paths

Energy Technology Data Exchange (ETDEWEB)

Rit, Simon; Dedes, George; Freud, Nicolas; Sarrut, David; Letang, Jean Michel [Universite de Lyon, CREATIS, CNRS UMR5220, Inserm U1044, INSA-Lyon, Universite Lyon 1, Centre Leon Berard, 69008 Lyon (France)

2013-03-15

Purpose: Proton CT (pCT) has the potential to accurately measure the electron density map of tissues at low doses but the spatial resolution is prohibitive if the curved paths of protons in matter is not accounted for. The authors propose to account for an estimate of the most likely path of protons in a filtered backprojection (FBP) reconstruction algorithm. Methods: The energy loss of protons is first binned in several proton radiographs at different distances to the proton source to exploit the depth-dependency of the estimate of the most likely path. This process is named the distance-driven binning. A voxel-specific backprojection is then used to select the adequate radiograph in the distance-driven binning in order to propagate in the pCT image the best achievable spatial resolution in proton radiographs. The improvement in spatial resolution is demonstrated using Monte Carlo simulations of resolution phantoms. Results: The spatial resolution in the distance-driven binning depended on the distance of the objects from the source and was optimal in the binned radiograph corresponding to that distance. The spatial resolution in the reconstructed pCT images decreased with the depth in the scanned object but it was always better than previous FBP algorithms assuming straight line paths. In a water cylinder with 20 cm diameter, the observed range of spatial resolutions was 0.7 - 1.6 mm compared to 1.0 - 2.4 mm at best with a straight line path assumption. The improvement was strongly enhanced in shorter 200 Degree-Sign scans. Conclusions: Improved spatial resolution was obtained in pCT images with filtered backprojection reconstruction using most likely path estimates of protons. The improvement in spatial resolution combined with the practicality of FBP algorithms compared to iterative reconstruction algorithms makes this new algorithm a candidate of choice for clinical pCT.

Efficient Geometric Sound Propagation Using Visibility Culling

Science.gov (United States)

Chandak, Anish

2011-07-01

Simulating propagation of sound can improve the sense of realism in interactive applications such as video games and can lead to better designs in engineering applications such as architectural acoustics. In this thesis, we present geometric sound propagation techniques which are faster than prior methods and map well to upcoming parallel multi-core CPUs. We model specular reflections by using the image-source method and model finite-edge diffraction by using the well-known Biot-Tolstoy-Medwin (BTM) model. We accelerate the computation of specular reflections by applying novel visibility algorithms, FastV and AD-Frustum, which compute visibility from a point. We accelerate finite-edge diffraction modeling by applying a novel visibility algorithm which computes visibility from a region. Our visibility algorithms are based on frustum tracing and exploit recent advances in fast ray-hierarchy intersections, data-parallel computations, and scalable, multi-core algorithms. The AD-Frustum algorithm adapts its computation to the scene complexity and allows small errors in computing specular reflection paths for higher computational efficiency. FastV and our visibility algorithm from a region are general, object-space, conservative visibility algorithms that together significantly reduce the number of image sources compared to other techniques while preserving the same accuracy. Our geometric propagation algorithms are an order of magnitude faster than prior approaches for modeling specular reflections and two to ten times faster for modeling finite-edge diffraction. Our algorithms are interactive, scale almost linearly on multi-core CPUs, and can handle large, complex, and dynamic scenes. We also compare the accuracy of our sound propagation algorithms with other methods. Once sound propagation is performed, it is desirable to listen to the propagated sound in interactive and engineering applications. We can generate smooth, artifact-free output audio signals by applying

Path Creation, Path Dependence and Breaking Away from the Path

OpenAIRE

Wang, Jens; Hedman, Jonas; Tuunainen, Virpi Kristiina

2016-01-01

The explanation of how and why firms succeed or fail is a recurrent research challenge. This is particularly important in the context of technological innovations. We focus on the role of historical events and decisions in explaining such success and failure. Using a case study of Nokia, we develop and extend a multi-layer path dependence framework. We identify four layers of path dependence: technical, strategic and leadership, organizational, and external collaboration. We show how path dep...

Equivalence of massive propagator distance and mathematical distance on graphs

International Nuclear Information System (INIS)

Filk, T.

1992-01-01

It is shown in this paper that the assignment of distance according to the massive propagator method and according to the mathematical definition (length of minimal path) on arbitrary graphs with a bound on the degree leads to equivalent large scale properties of the graph. Especially, the internal scaling dimension is the same for both definitions. This result holds for any fixed, non-vanishing mass, so that a really inequivalent definition of distance requires the limit m → 0

Oxidation behavior of laser-clad NiAlCrHf alloys

International Nuclear Information System (INIS)

Ribaudo, C.R.

1991-01-01

Laser cladding is the process where a mechanical mixture of powders is rapidly melted and fused to a solid substrate using a CO 2 laser. The effects of laser cladding upon scale retention on NiAlCrHf alloys after cyclic and isothermal exposure to air were investigated. The stress developed in the scale during cooling after exposure was estimated using a thermoelastic model. Additions of up to ∼2 1/2 wt % Hf increasingly promote retention of scales grown at 1,200C. Laser-clad samples containing ∼2 1/2 wt % Hf retained almost-intact scales. The improvement in scale retention is due to improved toughness in scales containing hafnia-rich polycrystallites possibly via microcracking initiated by anisotropic thermal contraction of the hafnia. Laser cladding provides a large concentration of ∼1 μm Hf-rich particles that are precursors of the hafnia in the scale as well as a fine-dendrite spacing that reduced the mean free distance between particles

Chemical states and electronic structure of a HfO(-2)/Ge(001) interface

International Nuclear Information System (INIS)

Seo, Kang-ill; McIntyre, Paul C.; Stanford U., Materials Sci. Dept.; Sun, Shiyu; Lee, Dong-Ick; Pianetta, Piero; SLAC, SSRL; Saraswat, Krishna C.; Stanford U., Elect. Eng. Dept.

2005-01-01

We report the chemical bonding structure and valence band alignment at the HfO 2 /Ge (001) interface by systematically probing various core level spectra as well as valence band spectra using soft x-rays at the Stanford Synchrotron Radiation Laboratory. We investigated the chemical bonding changes as a function of depth through the dielectric stack by taking a series of synchrotron photoemission spectra as we etched through the HfO 2 film using a dilute HF-solution. We found that a very non-stoichiometric GeO x layer exists at the HfO 2 /Ge interface. The valence band spectra near the Fermi level in each different film structure were carefully analyzed, and as a result, the valence band offset between Ge and GeO x was determined to be ΔE v (Ge-GeO x ) = 2.2 ± 0.15 eV, and that between Ge and HfO 2 , ΔE v (Ge-HfO 2 ) = 2.7 ± 0.15 eV

Theoretical and experimental investigation of near-infrared light propagation in a model of the adult head.

Science.gov (United States)

Okada, E; Firbank, M; Schweiger, M; Arridge, S R; Cope, M; Delpy, D T

1997-01-01

Near-infrared light propagation in various models of the adult head is analyzed by both time-of-flight measurements and mathematical prediction. The models consist of three- or four-layered slabs, the latter incorporating a clear cerebrospinal fluid (CSF) layer. The most sophisticated model also incorporates slots that imitate sulci on the brain surface. For each model, the experimentally measured mean optical path length as a function of source-detector spacing agrees well with predictions from either a Monte Carlo model or a finite-element method based on diffusion theory or a hybrid radiosity-diffusion theory. Light propagation in the adult head is shown to be highly affected by the presence of the clear CSF layer, and both the optical path length and the spatial sensitivity profile of the models with a CSF layer are quite different from those without the CSF layer. However, the geometry of the sulci and the boundary between the gray and the white matter have little effect on the detected light distribution.

HF-induced airglow at magnetic zenith: theoretical considerations

Directory of Open Access Journals (Sweden)

E. V. Mishin

2005-01-01

Full Text Available Observations of airglow at 630nm (red line and 557.7nm (green line during HF modification experiments at the High Frequency Active Auroral Research Program (HAARP heating facility are analyzed. We propose a theoretical framework for understanding the generation of Langmuir and ion acoustic waves during magnetic zenith injections. We show that observations of HF-induced airglow in an underdense ionosphere as well as a decrease in the height of the emitting volume are consistent with this scenario.

Path Loss, Shadow Fading, and Line-Of-Sight Probability Models for 5G Urban Macro-Cellular Scenarios

DEFF Research Database (Denmark)

Sun, Shu; Thomas, Timothy; Rappaport, Theodore S.

2015-01-01

This paper presents key parameters including the line-of-sight (LOS) probability, large-scale path loss, and shadow fading models for the design of future fifth generation (5G) wireless communication systems in urban macro-cellular (UMa) scenarios, using the data obtained from propagation...... measurements in Austin, US, and Aalborg, Denmark, at 2, 10, 18, and 38 GHz. A comparison of different LOS probability models is performed for the Aalborg environment. Both single-slope and dual-slope omnidirectional path loss models are investigated to analyze and contrast their root-mean-square (RMS) errors...

Interacciones hiperfinas en BaxSr1-xHfO3

Directory of Open Access Journals (Sweden)

López García, A.

1999-10-01

Full Text Available In order to determine the microscopic role of cation A in ABO3 perovskites the hyperfine interaction in the Sr1-xBaxHfO3 system using Perturbed Angular Correlation spectroscopy (PAC is studied. As a previous result the compositions x = 0.50 and 0.25 are shown. The PAC spectra were obtained in the temperature range from 20 to 1000ºC. In both compounds a phase transition to higher symmetry structure was observed at T≈400 and 200ºC, respectively. This structure is proposed to be cubic in both compositions. The results are compared with those obtained in SrHfO3 and BaHfO3.Con el fin de determinar el papel microscópico que juega el catión A en las perovskitas ABO3 se estudia la interacción hiperfina el sistema Sr1-xBaxHfO3 usando la espectroscopia Correlaciones Angulares Perturbadas (PAC en función de la temperatura y la composición. Como resultado previo se muestra en este trabajo, el estudio de las composiciones x = 0.5 y 0.75. Las medidas PAC se realizaron en el intervalo de temperaturas que va desde 20 a 1000ºC. Para x=0.50 y 0.75 se determinó una transición a una fase de mayor simetría a T≈400 y 200ºC, respectivamente. Se propone que esta fase de mayor simetría es cúbica en ambas composiciones. Los resultados obtenidos son comparados con los compuestos puros SrHfO3 y BaHfO3.

HF Parameters of Induction Motor

Directory of Open Access Journals (Sweden)

M. N. Benallal

2017-09-01

Full Text Available This article describes the results of experimental studies of HF input and primary parameters. A simulation model in Matlab SimulinkTM of multiphase windings as ladder circuit of coils is developed. A method for determining the primary parameters of ladder equivalent circuits is presented.

Estimation of stepwise crack propagation in ceramic laminates with strong interfaces

Czech Academy of Sciences Publication Activity Database

Náhlík, Luboš; Štegnerová, Kateřina; Hutař, Pavel

2015-01-01

Roč. 9, č. 34 (2015), s. 116-124 ISSN 1971-8993. [International Conference on Crack Paths /5./. Ferrara, 16.09.2015-18.09.2015] R&D Projects: GA ČR(CZ) GA15-09347S Institutional support: RVO:68081723 Keywords : Ceramic laminates * Crack behaviour * Residual stresses * Strain energy density factor * Crack propagation direction Subject RIV: JL - Materials Fatigue, Friction Mechanics http://www.fracturae.com/index.php/fis/article/view/IGF-ESIS.34.12

European coordination for coastal HF radar data in EMODnet Physics

Science.gov (United States)

Mader, Julien; Novellino, Antonio; Gorringe, Patrick; Griffa, Annalisa; Schulz-Stellenfleth, Johannes; Montero, Pedro; Montovani, Carlo; Ayensa, Garbi; Vila, Begoña; Rubio, Anna; Sagarminaga, Yolanda

2015-04-01

Historically, joint effort has been put on observing open ocean, organizing, homogenizing, sharing and reinforcing the impact of the acquired information based on one technology: ARGO with profilers Argo floats, EuroSites, ESONET-NoE, FixO3 for deep water platforms, Ferrybox for stations in ships of opportunities, and GROOM for the more recent gliders. This kind of networking creates synergies and makes easier the implementation of this source of data in the European Data exchange services like EMODnet, ROOSs portals, or any applied services in the Blue economy. One main targeted improvement in the second phase of EMODnet projects is the assembling of data along coastline. In that sense, further coordination is recommended between platform operators around a specific technology in order to make easier the implementation of the data in the platforms (4th EuroGOOS DATAMEQ WG). HF radar is today recognized internationally as a cost-effective solution to provide high spatial and temporal resolution current maps (depending on the instrument operation frequency, covering from a few kilometres offshore up to 200 km) that are needed for many applications for issues related to ocean surface drift or sea state characterization. Significant heterogeneity still exists in Europe concerning technological configurations, data processing, quality standards and data availability. This makes more difficult the development of a significant network for achieving the needed accessibility to HF Radar data for a pan European use. EuroGOOS took the initiative to lead and coordinate activities within the various observation platforms by establishing a number of Ocean Observing Task Teams such as HF-Radars. The purpose is to coordinate and join the technological, scientific and operational HF radar communities at European level. The goal of the group is on the harmonization of systems requirements, systems design, data quality, improvement and proof of the readiness and standardization of

Densification and properties of HfB2 based materials

International Nuclear Information System (INIS)

Sonber, J.K.; Ch Murthy, T.S.R.; Bedse, R.D.; Subramanian, C.; Kumar, Sunil; Fotedar, R.K.; Krishnamurthy, N.; Suri, A.K.

2011-01-01

This paper presents the results of investigation carried out on densification and properties of HfB 2 based materials. Densification study of HfB 2 with and without sinter additive was carried out by hot pressing. TiSi 2 and CrSi 2 were used as sinter additive. Monolithic HfB 2 was densified to only 80%ρ th at 1850 deg C with a pressure of 35 MPa. Addition of 10 wt% TiSi 2 resulted in a density of 95% TD at a relatively low temperature of 1650 deg C and a low pressure of 20 MPa. Addition of 10% CrSi 2 resulted in a density of 99% TD at the same operating conditions. All the samples were characterized by SEM/EDS and mechanical property measurement. (author)

Microwave Propagation Attenuation due to Earth's Atmosphere and Weather at SHF Band

Science.gov (United States)

Ho, Christian; Wang, Charles; Gritton, Kelly; Angkasa, Kris

2004-01-01

In this study we have estimated radio wave propagation losses at super high frequency (SHF) band by applying available propagation models into several Air Force benchmark scenarios. The study shows that dominantly additional losses over the free space loss are atmospheric absorption, clouds, fog, and precipitation, as well as scintillation /multipath at low elevation angles. The free space loss equation has been modified to include all atmospheric attenuation and fading effects that cannot be neglected over the range of frequency of interest. Terrain profiles along all directions of interest within the coastal areas and inland areas for four benchmark cases have been analyzed in detail. We find that while the atmospheric gaseous absorption plays a significant role under a clear weather, heavy rainfalls can cause several tens of dB loss for a 100- km path through the rain. At very low elevation angles (propagation between the east and the west coastal receiving stations.

Definition of Scatterer in Electromagnetic Wave Propagation Environment Using Image Processing Based on FDTD Method

Directory of Open Access Journals (Sweden)

Mahmood Falah

2015-01-01

Full Text Available In this paper, we implement real irregular terrain model in computer program by using image processing. We show how this approach can be used in simulation of E.M. wave propagation on irregular earth’s surface in a realistic manner. Some simulations are performed for implementation of longitudinal height differences over the propagation path as PEC surface .We also describe that how this approach can be used for any boundary condition in computational space. The results observed in Snapshots of the field profiles taken at different simulation times, validates capability of this method.

Sr-Nd-Hf isotopic fingerprinting of transatlantic dust derived from North Africa

Science.gov (United States)

Zhao, Wancang; Balsam, William; Williams, Earle; Long, Xiaoyong; Ji, Junfeng

2018-03-01

Long-range transport of African dust plays an important role in understanding dust-climate relationships including dust source areas, dust pathways and associated atmospheric and/or oceanic processes. Clay-sized Sr-Nd-Hf isotopic compositions can be used as geochemical fingerprints to constrain dust provenance and the pathways of long-range transported mineral dust. We investigated the clay-sized Sr-Nd-Hf isotopic composition of surface samples along four transects bordering the Sahara Desert. The transects are from Mali, Niger/Benin/Togo, Egypt and Morocco. Our results show that the Mali transect on the West African Craton (WAC) produces lower εNd (εNd-mean = -16.38) and εHf (εHf-mean = -9.59) values than the other three transects. The Egyptian transect exhibits the lowest 87Sr/86Sr ratios (87Sr/86Srmean = 0.709842), the highest εHf (εHf-mean = -0.34) and εNd values of the four transects. Comparison of the clay-sized Sr-Nd-Hf isotopic values from our North African samples to transatlantic African dust collected in Barbados demonstrates that the dust's provenance is primarily the western Sahel and Sahara as well as the central Sahel. Summer emission dust is derived mainly from the western Sahel and Sahara regions. The source of transatlantic dust in spring and autumn is more varied than in the summer and includes dust not only from western areas, but also south central areas. Comparison of the Sr-Nd-Hf isotopic fingerprints between the source and sink of transatlantic dust also suggests that a northwestward shift in dust source occurs from the winter, through the spring and into the summer. The isotopic data we develop here provide another tool for discriminating changes in dust archives resulting from paleoenvironmental evolution of source regions.

Quantum propagator approach to heavy-ion fusion

International Nuclear Information System (INIS)

Bao, J.D.

2002-01-01

The real-time path integral propagator approach is used to study the fusion probability of massive nuclei including quantum effect. An analytical expression of the probability to pass over barrier of an inverted harmonic potential is obtained, in which both height and curvature of the barrier are controlled by the neck degree of freedom. The fusion probability of three systems in central collision as a function of the center of mass energy are calculated and compared to experimental results. It is shown that the quantum fluctuation enhances the fusion probability at low energies, and the neck fluctuation makes the slope of the fusion probability curve become flatter. (author)

Temporal evolution of the HF-enhanced plasma line in sporadic E

International Nuclear Information System (INIS)

Djuth, F.T.; Gonzales, C.A.

1988-01-01

The high-power, high-frequency (HF) facility at Arecibo, Puerto Rico, has been used to study the excitation of Langmuir waves in mid-latitude sporadic E. Measurements of the temporal evolution of so-called HF-enhanced plasma line (HFPL) were made using the Arecibo 430-MHz radar. After HF turn-on in the plasma the HFPL exhibits a rapid growth phase followed by a quick overshoot. During periods of strong HFPL excitation the e-folding growth time of the HFPL power is typically approx-lt 20 μs, and the total overshoot period is ∼1 ms. On the basis of the current observations, mode conversion of the HF wave into Langmuir waves near HF reflection appears to be a promising mechanism for the production of Langmuir waves in sporadic E. Caviton formation at the critical layer is expected to accompany this process, and there is some evidence that the 430-MHz radar is probing the plasma in a region where density cavities of this nature form. While no specific explanation is offered for the HFPL overshoot, it appears that this phenomenon is fundamental to the Langmuir wave excitation process

Crack propagation and arrest simulation of X90 gas pipe

International Nuclear Information System (INIS)

Yang, Fengping; Huo, Chunyong; Luo, Jinheng; Li, He; Li, Yang

2017-01-01

To determine whether X90 steel pipe has enough crack arrest toughness or not, a damage model was suggested as crack arrest criterion with material parameters of plastic uniform percentage elongation and damage strain energy per volume. Fracture characteristic length which characterizes fracture zone size was suggested to be the largest mesh size on expected cracking path. Plastic uniform percentage elongation, damage strain energy per volume and fracture characteristic length of X90 were obtained by five kinds of tensile tests. Based on this criterion, a length of 24 m, Φ1219 × 16.3 mm pipe segment model with 12 MPa internal gas pressure was built and computed with fluid-structure coupling method in ABAQUS. Ideal gas state equation was used to describe lean gas behavior. Euler grid was used to mesh gas zone inside the pipe while Lagrangian shell element was used to mesh pipe. Crack propagation speed and gas decompression speed were got after computation. The result shows that, when plastic uniform percentage elongation is equal to 0.054 and damage strain energy per volume is equal to 0.64 J/mm"3, crack propagation speed is less than gas decompression speed, which means the simulated X90 gas pipe with 12 MPa internal pressure can arrest cracking itself. - Highlights: • A damage model was suggested as crack arrest criterion. • Plastic uniform elongation and damage strain energy density are material parameters. • Fracture characteristic length is suggested to be largest mesh size in cracking path. • Crack propagating simulation with coupling of pipe and gas was realized in ABAQUS. • A Chinese X90 steel pipe with 12 MPa internal pressure can arrest cracking itself.

An inter-hemispheric, statistical study of nightside spectral width distributions from coherent HF scatter radars

Directory of Open Access Journals (Sweden)

E. E. Woodfield

2002-12-01

Full Text Available A statistical investigation of the Doppler spectral width parameter routinely observed by HF coherent radars has been conducted between the Northern and Southern Hemispheres for the nightside ionosphere. Data from the SuperDARN radars at Thykkvibær, Iceland and Syowa East, Antarctica have been employed for this purpose. Both radars frequently observe regions of high (>200 ms-1 spectral width polewards of low (<200 ms-1 spectral width. Three years of data from both radars have been analysed both for the spectral width and line of sight velocity. The pointing direction of these two radars is such that the flow reversal boundary may be estimated from the velocity data, and therefore, we have an estimate of the open/closed field line boundary location for comparison with the high spectral widths. Five key observations regarding the behaviour of the spectral width on the nightside have been made. These are (i the two radars observe similar characteristics on a statistical basis; (ii a latitudinal dependence related to magnetic local time is found in both hemispheres; (iii a seasonal dependence of the spectral width is observed by both radars, which shows a marked absence of latitudinal dependence during the summer months; (iv in general, the Syowa East spectral width tends to be larger than that from Iceland East, and (v the highest spectral widths seem to appear on both open and closed field lines. Points (i and (ii indicate that the cause of high spectral width is magnetospheric in origin. Point (iii suggests that either the propagation of the HF radio waves to regions of high spectral width or the generating mechanism(s for high spectral width is affected by solar illumination or other seasonal effects. Point (iv suggests that the radar beams from each of the radars are subject either to different instrumental or propagation effects, or different geophysical conditions due to their locations, although we suggest that this result is more likely to

DIRECT DETERMINATION OF THE HF/H{sub 2} ABUNDANCE RATIO IN INTERSTELLAR GAS

Energy Technology Data Exchange (ETDEWEB)

Indriolo, Nick; Neufeld, D. A. [Department of Physics and Astronomy, Johns Hopkins University, Baltimore, MD 21218 (United States); Seifahrt, A. [Department of Astronomy and Astrophysics, University of Chicago, Chicago, IL 60637 (United States); Richter, M. J. [Department of Physics, University of California Davis, Davis, CA 95616 (United States)

2013-02-20

We report the first detection of the v = 1-0, R(0) ro-vibrational transition of HF at 2.499385 {mu}m arising from interstellar gas. The line is seen in absorption toward three background sources-HD 154368, Elias 29, and AFGL 2136 IRS 1-all of which have reported H{sub 2} column densities determined from observations of H{sub 2}. This allows for the first direct determination of the HF/H{sub 2} abundance ratio. We find values of N(HF)/N(H{sub 2}) = 1.15 Multiplication-Sign 10{sup -8} and 0.69 Multiplication-Sign 10{sup -8} for HD 154368 and Elias 29, respectively. The sight line toward AFGL 2136 IRS 1 also shows absorption from the v = 1-0, R(1) transition of HF, indicating warm, dense (n {sub H} {approx}> 10{sup 9} cm{sup -3}) gas, likely very close to the central protostar. Ascribing portions of the HF absorption to warm and cold gas, we find N(HF)/N(H{sub 2}) = (1.7-2.9) Multiplication-Sign 10{sup -8} and (0.33-0.58) Multiplication-Sign 10{sup -8} for the two components, respectively. Except for the warm component toward AFGL 2136 IRS 1, all observed HF/H{sub 2} ratios are well below N(HF)/N(H{sub 2}) = 3.6 Multiplication-Sign 10{sup -8}, the value predicted if nearly all gas phase fluorine is in the form of HF. Models of fluorine chemistry that account for depletion onto grains are able to reproduce the results toward HD 154368, but not in the cold, dense gas toward AFGL 2136 IRS 1 and Elias 29. Most likely, some combinations of simplifying assumptions made in the chemical models are responsible for these discrepancies.

Trace Detection of Organophosphorus Chemical Warfare Agents in Wastewater and Plants by Luminescent UIO-67(Hf) and Evaluating the Bioaccumulation of Organophosphorus Chemical Warfare Agents.

Science.gov (United States)

Lian, Xiao; Yan, Bing

2018-05-02

Organophosphorus chemical warfare agents (OPCWAs) are a group of organic pollutants characterized by high toxicity and chemical stability, and they are very difficult to be degraded. The trace quality of OPCWAs in water and food will cause great harm to the human body. Therefore, the detection of OPCWAs is a difficult challenge, which has become the research hotspot over the world. In this work, a Hf-based luminescent metal-organic framework (Eu@1) is prepared, and the reactivity of Hf 12 results in a methanephosphonic acid (MPA)-induced luminescence quenching and the charge transfer from MPA to Hf(IV) and generated exciplexes which are responsible for this quenching effect. The excellent performance of Eu@1 in the detection of MPA, with its finer selectivity, high sensitivity (LOD = 0.4 ppm), and large linear range (10 -7 to 10 -3 M), is encouraging for application in wastewater detection. Importantly, MPA is a pollutant that can be absorbed by plants and causes the bioaccumulation effect, and thus, the detection of MPA in real plant samples is a purposeful topic. Eu@1 also achieved satisfactory results in actual plant sample testing, and the bioaccumulation of MPA in onions, turnips, and cabbages is determined via our sensor. This fabricated detector provides a feasible path for the detection of ppm-level OPCWAs in a complex environment, which will help humans to avoid OPCWA-contaminated foods.

Analysis of foliage effects on mobile propagation in dense urban environments

Science.gov (United States)

Bronshtein, Alexander; Mazar, Reuven; Lu, I.-Tai

2000-07-01

Attempts to reduce the interference level and to increase the spectral efficiency of cellular radio communication systems operating in dense urban and suburban areas lead to the microcellular approach with a consequent requirement to lower antenna heights. In large metropolitan areas having high buildings this requirement causes a situation where the transmitting and receiving antennas are both located below the rooftops, and the city street acts as a type of a waveguiding channel for the propagating signal. In this work, the city street is modeled as a random multislit waveguide with randomly distributed regions of foliage parallel to the building boundaries. The statistical propagation characteristics are expressed in terms of multiple ray-fields approaching the observer. Algorithms for predicting the path-loss along the waveguide and for computing the transverse field structure are presented.

HfO2 as gate dielectric on Ge: Interfaces and deposition techniques

International Nuclear Information System (INIS)

Caymax, M.; Van Elshocht, S.; Houssa, M.; Delabie, A.; Conard, T.; Meuris, M.; Heyns, M.M.; Dimoulas, A.; Spiga, S.; Fanciulli, M.; Seo, J.W.; Goncharova, L.V.

2006-01-01

To fabricate MOS gate stacks on Ge, one can choose from a multitude of metal oxides as dielectric material which can be deposited by many chemical or physical vapor deposition techniques. As a few typical examples, we will discuss here the results from atomic layer deposition (ALD), metal organic CVD (MOCVD) and molecular beam deposition (MBD) using HfO 2 /Ge as materials model system. It appears that a completely interface layer free HfO 2 /Ge combination can be made in MBD, but this results in very bad capacitors. The same bad result we find if HfGe y (Hf germanides) are formed like in the case of MOCVD on HF-dipped Ge. A GeO x interfacial layer appears to be indispensable (if no other passivating materials are applied), but the composition of this interfacial layer (as determined by XPS, TOFSIMS and MEIS) is determining for the C/V quality. On the other hand, the presence of Ge in the HfO 2 layer is not the most important factor that can be responsible for poor C/V, although it can still induce bumps in C/V curves, especially in the form of germanates (Hf-O-Ge). We find that most of these interfacial GeO x layers are in fact sub-oxides, and that this could be (part of) the explanation for the high interfacial state densities. In conclusion, we find that the Ge surface preparation is determining for the gate stack quality, but it needs to be adapted to the specific deposition technique

Formation of Al2O3-HfO2 Eutectic EBC Film on Silicon Carbide Substrate

Directory of Open Access Journals (Sweden)

Kyosuke Seya

2015-01-01

Full Text Available The formation mechanism of Al2O3-HfO2 eutectic structure, the preparation method, and the formation mechanism of the eutectic EBC layer on the silicon carbide substrate are summarized. Al2O3-HfO2 eutectic EBC film is prepared by optical zone melting method on the silicon carbide substrate. At high temperature, a small amount of silicon carbide decomposed into silicon and carbon. The components of Al2O3 and HfO2 in molten phase also react with the free carbon. The Al2O3 phase reacts with free carbon and vapor species of AlO phase is formed. The composition of the molten phase becomes HfO2 rich from the eutectic composition. HfO2 phase also reacts with the free carbon and HfC phase is formed on the silicon carbide substrate; then a high density intermediate layer is formed. The adhesion between the intermediate layer and the substrate is excellent by an anchor effect. When the solidification process finished before all of HfO2 phase is reduced to HfC phase, HfC-HfO2 functionally graded layer is formed on the silicon carbide substrate and the Al2O3-HfO2 eutectic structure grows from the top of the intermediate layer.

Yang-Mills theory in null path space

International Nuclear Information System (INIS)

Kent, S.L.

1982-01-01

A reformulation of classical GL(n,c) Yang-Mills theory is presented. The reformulation is in terms of a single matrix-valued function G on a six-dimensional subspace of the space of paths in Minkowski space, M. This subspace is defined as the null paths beginning at each point, (X/sup a/), of M and ending at future null infinity. A convenient parametrization of these paths is to give the Minkowski coordinates x/sup a/ of the starting point and the (complex) stereographic coordinates (xi, antixi) on S 2 which label the light cone generators of x/sup a/. A path is thus labeled by (x/sup a/,xi, antixi). The function G(x/sup a/,xi, antixi) is defined by the parallel propagation (with a given connection) of n linearly independent fiber vectors from x/sup a/ to null infinity along the (xi, antixi) generator. From knowledge of G(x/sup a/,xi, antixi) the connection one-form γ/sub a/ at the point x/sup a/ can be obtained is shown. Furthermore how the vacuum Yang-Mills equations can be imposed on the G is shown. This results in a rather complicated integro-differential equation for G which involves the characteristic initial data (essentially the radiation field) acting as the driving term. Two simple special cases are immediately obtainable; in the case of self-dual (or anti-self dual) fields the author obtains a simple derivation of the Sparling equation, namely delta G = -GA, while for Abelian (Maxwell) theories obtained the equation delta anti delta log G = -anti delta A-anti delta A, where A and its conjugate anti A are the characteristic free data given on null infinity. The latter equation is equivalent to the vacuum Maxwell equations

Design for human factors (DfHF): a grounded theory for integrating human factors into production design processes.

Science.gov (United States)

Village, Judy; Searcy, Cory; Salustri, Filipo; Patrick Neumann, W

2015-01-01

The 'design for human factors' grounded theory explains 'how' human factors (HF) went from a reactive, after-injury programme in safety, to being proactively integrated into each step of the production design process. In this longitudinal case study collaboration with engineers and HF Specialists in a large electronics manufacturer, qualitative data (e.g. meetings, interviews, observations and reflections) were analysed using a grounded theory methodology. The central tenet in the theory is that when HF Specialists acclimated to the engineering process, language and tools, and strategically aligned HF to the design and business goals of the organisation, HF became a means to improve business performance. This led to engineers 'pulling' HF Specialists onto their team. HF targets were adopted into engineering tools to communicate HF concerns quantitatively, drive continuous improvement, visibly demonstrate change and lead to benchmarking. Senior management held engineers accountable for HF as a key performance indicator, thus integrating HF into the production design process. Practitioner Summary: Research and practice lack explanations about how HF can be integrated early in design of production systems. This three-year case study and the theory derived demonstrate how ergonomists changed their focus to align with design and business goals to integrate HF into the design process.

EURObservational Research Programme: the Heart Failure Pilot Survey (ESC-HF Pilot)

DEFF Research Database (Denmark)

Maggioni, Aldo P; Dahlström, Ulf; Filippatos, Gerasimos

2010-01-01

The primary objective of the new ESC-HF Pilot Survey was to describe the clinical epidemiology of outpatients and inpatients with heart failure (HF) and the diagnostic/therapeutic processes applied across 12 participating European countries. This pilot study was specifically aimed at validating...

Hop-by-HopWorm Propagation with Carryover Epidemic Model in Mobile Sensor Networks

Directory of Open Access Journals (Sweden)

Jun-Won Ho

2015-10-01

Full Text Available In the internet, a worm is usually propagated in a random multi-hop contact manner. However, the attacker will not likely select this random multi-hop propagation approach in a mobile sensor network. This is because multi-hop worm route paths to random vulnerable targets can be often breached due to node mobility, leading to failure of fast worm spread under this strategy. Therefore, an appropriate propagation strategy is needed for mobile sensor worms. To meet this need, we discuss a hop-by-hop worm propagation model in mobile sensor networks. In a hop-by-hop worm propagation model, benign nodes are infected by worm in neighbor-to-neighbor spread manner. Since worm infection occurs in hop-by-hop contact, it is not substantially affected by a route breach incurred by node mobility. We also propose the carryover epidemic model to deal with the worm infection quota deficiency that might occur when employing an epidemic model in a mobile sensor network. We analyze worm infection capability under the carryover epidemic model. Moreover, we simulate hop-by-hop worm propagation with carryover epidemic model by using an ns-2 simulator. The simulation results demonstrate that infection quota carryovers are seldom observed where a node’s maximum speed is no less than 20 m/s.

The effect of constraint level on a crack path

Czech Academy of Sciences Publication Activity Database

Ševčík, Martin; Hutař, Pavel; Náhlík, Luboš; Seitl, Stanislav

2013-01-01

Roč. 29, APR (2013), s. 83-92 ISSN 1350-6307. [Crack paths 2012. Gaeta, 19.09.2012-21.09.2012] R&D Projects: GA ČR GA106/09/1954; GA MŠk(CZ) ED1.1.00/02.0068; GA MŠk EE2.3.30.0063 Grant - others:Rada Programu interní podpory projektů mezinárodní spolupráce AV ČR(CZ) M100420901 Institutional support: RVO:68081723 Keywords : Fracture mechanics * Constraint effect * Crack propagation * MTS criterion * Gear rim Subject RIV: JL - Materials Fatigue, Friction Mechanics Impact factor: 1.130, year: 2013

Preparation and study of the critical-mass-free plutonium ceramics with neutron poisons Hf, Gd and Li

International Nuclear Information System (INIS)

Timoefeeva, L.F.; Orlov, V.K.; Malyukov, E.E.; Molomin, V.I.; Zhmak, V.A.; Semova, E.A.; Shishkov, N.V.; Nadykto, B.A.

2002-01-01

Powder sintering was used to produce homogeneous type oxide ceramics of Pu with Hf, Gd and Li 6 . In all the ceramics, there is the number of neutron poison (Hf, Gd and Li) atoms per plutonium atom needed, according to the physical calculation, for them to be free of critical mass. PuO 2 stabilizers high-temperature modifications of cubic HfO 2 or hexagonal Gd 2 O 3 , however, at the ratio given by the physical calculation, the plutonium is insufficient for their full stabilization. Addition of yttrium oxide as an additive stabilizing the fcc phase of HfO 2 resulted in cubic solid solution (Pu, Hf, Y)O 2-x . Pu/Li/Hf and Pu/Li/Si ceramics produced by sintering of PuO 2 and compound Li 2 HfO 3 or 6 Li 4 SiO 4 powders is characterized with presence of two phases. The method of differential thermal analysis demonstrated the phase stability of (Pu-Hf, Pu-Gd, Pu-Li-Hf) oxide ceramics in the 20-1500degC temperature range. Ceramic (Pu/Li/Si) has several endothermal effects. Tests in boiling water solutions of various composition suggest that the specimens of Pu, Hf oxides and ternary oxides (Pu, Hf, Y)O 2 are less stable in weakly acidic media than in weakly alkaline medium and distilled water. The obtained results were used as a basis to estimate the assumed solid solution region boundaries for binary Hf, Pu and ternary Hf, Pu, Y oxides on the side of HfO 2 . (author)

Mechanical properties of ultra-thin HfO2 films studied by nano scratches tests

International Nuclear Information System (INIS)

Fu, Wei-En; Chang, Yong-Qing; Chang, Chia-Wei; Yao, Chih-Kai; Liao, Jiunn-Der

2013-01-01

10-nm-thick atomic layer deposited HfO 2 films were characterized in terms of wear resistance and indentation hardness to investigate the thermal annealing induced impacts on mechanical properties. The wear resistance of ultra-thin films at low loads was characterized using nano-scratch tests with an atomic force microscope. The depth of the nano-scratches decreases with increasing annealing temperature, indicating that the hardness of the annealed films increases with the annealing temperatures. Surface nanoindentation was also performed to confirm the nanoscratch test results. The hardness variation of the annealed films is due to the generation of HfSi x O y induced by the thermal annealing. X-ray photoelectron spectroscopy measurements proved that the hardness of formed HfSi x O y with increasing annealing temperatures. The existence of HfSi x O y broadens the interface, and causes the increase of the interfacial layer thickness. As a result, the surface hardness increases with the increasing HfSi x O y induced by the thermal annealing. - Highlights: ► Mechanical properties of HfO 2 films were assessed by nano-scratch and indentation. ► Scratch depth of HfO 2 films decreased with the increase of annealing temperatures. ► Nano-hardness of HfO 2 films increased with the increase of annealing temperatures

In-situ investigation of crack propagation in {gamma}-TiAl alloys using atomic force, focus ion beam and scanning electron microscopy

Energy Technology Data Exchange (ETDEWEB)

Iqbal, Farasat; Goeken, Mathias [Lehrstuhl Allgemeine Werkstoffeigenschaften, Friedrich-Alexander-Universitaet Erlangen-Nuernberg (Germany); Pyczak, Florian [GKSS Research Centre Geesthacht, Geesthacht (Germany)

2009-07-01

The present study is focused on crack propagation mechanism in Ti-45Al-1Cr and Ti-45Al-5Nb alloys with lamellar microstructure. Atomic force microscopy (AFM) is a versatile technique to study the crack propagation in-situ. AFM was employed to investigate the local deformations near the crack tip. Scanning electron microscopy (SEM) supplements the in-situ observations and was used to get a basic understanding of the crack propagation path over larger distances.A focused ion beam (FIB) was used to investigate the structures and deformation traces underneath the surface. It is concluded that the {gamma}/{alpha}2 interfaces act as favorable sites for new interfacial crack nucleation and also for interlamellar crack propagation. Nucleation of new cracks was often preceded by the interaction of deformation twins with interfaces and also by strong shear band activity in the {gamma}-TiAl lamellae visible as significant surface topography in AFM.Mostly the underneath crack path follows the {gamma}/{alpha}2 interface similar to the situation observed at the surface. The local misorientation measured with electron backscattered diffraction (EBSD) shows {gamma}-lamellae as the region of high deformation as compare to neighboring {alpha}2 -lamellae around the crack tip and its surroundings.

Comparing LCZ696 with enalapril according to baseline risk using the MAGGIC and EMPHASIS-HF risk scores: an analysis of mortality and morbidity in PARADIGM-HF.

Science.gov (United States)

Simpson, Joanne; Jhund, Pardeep S; Silva Cardoso, Jose; Martinez, Felipe; Mosterd, Arend; Ramires, Felix; Rizkala, Adel R; Senni, Michele; Squire, Iain; Gong, Jianjian; Lefkowitz, Martin P; Shi, Victor C; Desai, Akshay S; Rouleau, Jean L; Swedberg, Karl; Zile, Michael R; McMurray, John J V; Packer, Milton; Solomon, Scott D

2015-11-10

Although most patients in the PARADIGM-HF (Prospective Comparison of ARNI With ACEI to Determine Impact on Global Mortality and Morbidity in Heart Failure) trial had mild symptoms, there is a poor correlation between reported functional limitation and prognosis in heart failure. The aim of this study was to examine the spectrum of risk in PARADIGM-HF and the effect of LCZ696 across that spectrum. This study analyzed rates of the primary composite outcome of cardiovascular death or heart failure hospitalization, its components, and all-cause mortality using the MAGGIC (Meta-Analysis Global Group in Chronic Heart Failure) and EMPHASIS-HF (Eplerenone in Mild Patients Hospitalization and Survival Study in Heart Failure) risk scores to categorize patients. The authors determined whether risk, on the basis of these scores, modified the treatment effect of LCZ696. The complete MAGGIC risk score was available for 8,375 of the 8,399 patients in PARADIGM-HF. The median MAGGIC score was 20 (IQR: 16 to 24). An increase of 1 point was associated with a 6% increased risk for the primary endpoint (p PARADIGM-HF patients had mild symptoms, many were at high risk for adverse outcomes and obtained a large absolute benefit from LCZ696, compared with enalapril, over a relatively short treatment period. LCZ696's benefit was consistent across the spectrum of risk. (PARADIGM-HF trial [Prospective Comparison of ARNI With ACEI to Determine Impact on Global Mortality and Morbidity in Heart Failure]; NCT01035255). Copyright © 2015 American College of Cardiology Foundation. Published by Elsevier Inc. All rights reserved.

Path Dependency

OpenAIRE

Mark Setterfield

2015-01-01

Path dependency is defined, and three different specific concepts of path dependency – cumulative causation, lock in, and hysteresis – are analyzed. The relationships between path dependency and equilibrium, and path dependency and fundamental uncertainty are also discussed. Finally, a typology of dynamical systems is developed to clarify these relationships.

EURObservational Research Programme : The Heart Failure Pilot Survey (ESC-HF Pilot)

NARCIS (Netherlands)

Maggioni, Aldo P.; Dahlstrom, Ulf; Filippatos, Gerasimos; Chioncel, Ovidiu; Crespo Leiro, Marisa; Drozdz, Jaroslaw; Fruhwald, Friedrich; Gullestad, Lars; Logeart, Damien; Metra, Marco; Parissis, John; Persson, Hans; Ponikowski, Piotr; Rauchhaus, Mathias; Voors, Adriaan A.; Nielsen, Olav Wendelboe; Zannad, Faiez; Tavazzi, Luigi

2010-01-01

The primary objective of the new ESC-HF Pilot Survey was to describe the clinical epidemiology of outpatients and inpatients with heart failure (HF) and the diagnostic/therapeutic processes applied across 12 participating European countries. This pilot study was specifically aimed at validating the

Thermoluminescence in HfO_2:Eu"3"+ powders irradiated in UV

International Nuclear Information System (INIS)

Ceron R, P. V.; Montes R, E.; Rivera M, T.; Diaz G, J. A. I.; Guzman M, J.

2016-10-01

Various inorganic compounds synthesized for photo luminescent applications have also presented a thermoluminescent (Tl) response, for example the metal oxides doped with rare earths. This property extends the use of these materials to the radiation dosimetry. For this reason, in this work the Tl response is presented in HfO_2:Eu"3"+ powders synthesized by the hydrothermal path, exposed to ultraviolet (UV) radiation of 254 nm. The kinetic parameters of its brightness curve were also calculated using the Chen expressions and the analysis method based on the shape of the curve. For the powders irradiated for 10 min the highest Tl response corresponds to the sample with 5% of the impurity, which is 6.5 times higher than the signal corresponding to the intrinsic sample. Its bright curve shows a main peak with a maximum in 148 degrees Celsius and a second order kinetics. Another test with the same material shows the Tl response against the exposure time, with a maximum in the 3 minutes. These calculations and tests constitute a first approach for the study of these powders as Tl dosimeter for UV radiation. (Author)

Suppression of interfacial reaction for HfO2 on silicon by pre-CF4 plasma treatment

International Nuclear Information System (INIS)

Lai, C.S.; Wu, W.C.; Chao, T.S.; Chen, J.H.; Wang, J.C.; Tay, L.-L.; Rowell, Nelson

2006-01-01

In this letter, the effects of pre-CF 4 plasma treatment on Si for sputtered HfO 2 gate dielectrics are investigated. The significant fluorine was incorporated at the HfO 2 /Si substrate interface for a sample with the CF 4 plasma pretreatment. The Hf silicide was suppressed and Hf-F bonding was observed for the CF 4 plasma pretreated sample. Compared with the as-deposited sample, the effective oxide thickness was much reduced for the pre-CF 4 plasma treated sample due to the elimination of the interfacial layer between HfO 2 and Si substrate. These improved characteristics of the HfO 2 gate dielectrics can be explained in terms of the fluorine atoms blocking oxygen diffusion through the HfO 2 film into the Si substrate

Probing the effect of neutron excess on the dynamics of Hf compound system

Science.gov (United States)

Sharma, Ishita; Kumar, Raj; Sharma, Manoj K.

2018-05-01

The reaction dynamics of 170Hf* and 174Hf* compound systems formed in 46,50Ti +124Sn reactions have been analyzed within the framework of Dynamical Cluster-decay Model (DCM) over an energy range of Ec.m.=115-156 MeV. The experimental data of fusion evaporation cross sections for 170,174Hf* systems is successfully addressed by optimizing the value of neck length ΔR. It is to be noted that calculations are performed by taking quadrupole deformations β2 with the optimum orientation of decaying fragments. Here, the effect of neutron excess has been examined on the structural properties of decaying fragments via fragmentation potential and preformation probability. The observation depicts that the isotopic effect prevails at fission region and as we move from lighter nucleus i.e. 170Hf* to heavier nucleus i.e. 174Hf*, the heavy mass fragments (HMF) start contributing along with fission fragments which are equally evident for 170Hf* as well. The ΔR values so obtained are compared at center of mass-energies which consequently provides information regarding the relative time scale of decaying fragments.

Charmonium propagation through a dense medium

Directory of Open Access Journals (Sweden)

Kopeliovich B.Z.

2015-01-01

Full Text Available Attenuation of a colourless c̄c dipole propagating with a large momentum through a hot medium originates from two sources, Debye screening (melting, and inelastic collisions with surrounding scattering centres (absorption. The former never terminates completely production of a bound charmonium in heavy ion collisions, even at very high temperatures. The latter, is controlled my the magnitude of the dipole cross section, related to the transport coefficient, which is the rate of transverse momentum broadening in the medium. A novel procedure of Lorentz boosting of the Schrödinger equation is developed, which allows to calculate the charmonium survival probability employing the path-integral technique, incorporating both melting and absorption. A novel mechanism of charmonium regeneration in a dense medium is proposed.

Real-time, high frequency (1 Hz), in situ measurement of HCl and HF gases in volcanic plumes with a novel cavity-enhanced, laser-based instrument

Science.gov (United States)

Kelly, P. J.; Sutton, A. J.; Elias, T.; Kern, C.; Clor, L. E.; Baer, D. S.

2017-12-01

Primary magmatic halogen-containing gases (HCl, HF, HBr, HI in characteristic order of abundance) are of great interest for volcano monitoring and research because, in general, they are more soluble in magma than other commonly-monitored volcanic volatiles (e.g. CO2, SO2, H2S) and thereby can offer unique insights into shallow magmatic processes. Nevertheless, difficulties in obtaining observations of primary volcanic halogens in gas plumes with traditional methods (e.g. direct sampling, Open-Path Fourier Transform Infrared spectroscopy, filter packs) have limited the number of observations reported worldwide, especially from explosive arc volcanoes. With this in mind, the USGS and Los Gatos Research, Inc. collaborated to adapt a commercially-available industrial in situ HCl-HF analyzer for use in airborne and ground-based measurements of volcanic gases. The new, portable instrument is based around two near-IR tunable diode lasers and uses a vibration-tolerant, enhanced-cavity approach that is well-suited for rugged field applications and yields fast (1 Hz) measurements with a wide dynamic range (0 -2 ppm) and sub-ppb precision (1σ: HCl: <0.4 ppb; HF: <0.1 ppb). In spring 2017 we conducted field tests at Kīlauea Volcano, Hawaii, to benchmark the performance of the new instrument and to compare it with an accepted method for halogen measurements (OP-FTIR). The HCl-HF instrument was run in parallel with a USGS Multi-GAS to obtain in situ H2O-CO2-SO2-H2S-HCl-HF plume compositions. The results were encouraging and quasi-direct comparisons of the in situ and remote sensing instruments showed good agreement (e.g. in situ SO2/HCl = 72 vs. OP-FTIR SO2/HCl = 88). Ground-based and helicopter-based measurements made 0 - 12 km downwind from the vent (plume age 0 - 29 minutes) show that plume SO2/HCl ratios increase rapidly from 60 to 300 around the plume edges, possibly due to uptake of HCl onto aerosols.

Centrifugal stretching along the ground state band of 168Hf

International Nuclear Information System (INIS)

Costin, A.; Pietralla, N.; Reese, M.; Moeller, O.; Ai, H.; Casten, R. F.; Heinz, A.; McCutchan, E. A.; Meyer, D. A.; Qian, J.; Werner, V.; Dusling, K.; Fitzpatrick, C. R.; Guerdal, G.; Petkov, P.; Rainovski, G.

2009-01-01

The lifetimes of the J π =4 + , 6 + , 8 + , and 10 + levels along the ground state band in 168 Hf were measured by means of the recoil distance Doppler shift (RDDS) method using the New Yale Plunger Device (NYPD) and the SPEEDY detection array at Wright Nuclear Structure Laboratory of Yale University. Excited states in 168 Hf were populated using the 124 Sn( 48 Ti,4n) fusion evaporation reaction. The new lifetime values are sufficiently precise to clearly prove the increase of quadrupole deformation as a function of angular momentum in the deformed nucleus 168 Hf. The data agree with the predictions from the geometrical confined β-soft (CBS) rotor model that involves centrifugal stretching in a soft potential

Effects of C and Hf concentration on phase relations and microstructure of a wrought powder-metallurgy superalloy

Science.gov (United States)

Miner, R. V., Jr.

1977-01-01

NASA IIB-11, a candidate alloy for advanced temperature turbine engine disks, and four modifications with varying C and Hf concentrations were produced from prealloyed powders. Several notable effects of C and Hf concentration in the alloys were observed. Both the amount of the gamma-prime phase and its solvus temperature increased with decreasing C, but only the gamma-prime solvus was affected by Hf, increasing with increasing Hf. Hf also promoted a cellular gamma-prime precipitation. Hf was, however, about equally distributed between gamma-prime and gamma. Hf and C both affected the carbides formed. Increasing both promoted formation of an MC relative to that of an M6C.

Turbulence scales in the high-latitude ionosphere and their signatures upon echoes detected by SuperDARN HF radars

International Nuclear Information System (INIS)

Vallieres, Xavier

2002-01-01

SuperDARN is a coherent HF radar network dedicated to the study of high-latitude ionospheric plasma convection and finds its major applications in the field of Sun/Earth connection. This work deals with the interactions between a transmitted radar wave and ionisation gradients at different scales and their impact on measurements. Studies are performed in order to detect the ion cyclotron signature, superimposed to turbulent motions, in observed spectra. On the other hand, the role of intermediate scales (from hundreds of meters to kilometers) on spectral width estimation is evidenced. Statistical studies show that the value of this parameter depends upon transmitted frequency and echo range. We propose an interpretation in terms of a wave front de-correlation during propagation and validate it with numerical simulations based upon realistic ionospheric parameters. (author) [fr

Reducing the stoichiometric excess of HF in the hydrofluorination of UO2

International Nuclear Information System (INIS)

Zhao Jun; Qiu Lufu; Zhong Xing; Xu Heqing

1989-11-01

In a fluidized bed, UO 2 obtained from the decomposition-reduction of AUC (Ammonium Uranyl Carbonate) was fed to absorb HF remaining in the exhaust gas of UF 4 production process. In the case of 60% conversion of UO 2 and the reaction temperature in the region of 300 deg C, HF remaining in the exhaust gas in absorbing fluidized bed was less than 7 ∼ 8% (w/w), i.e. apparent stoichiometric excess of HF had reduced to 0% more or less. Hence, with the high hydrofluorination reactivity of UO 2 obtained from the decomposition-reduction of AUC, it is possible to reduce evidently the stoichiometric excess of HF in the hydrofluorination process by two fluidized beds in series in which solids move against the gas flow

Progress in Root Cause and Fault Propagation Analysis of Large-Scale Industrial Processes

Directory of Open Access Journals (Sweden)

Fan Yang

2012-01-01

Full Text Available In large-scale industrial processes, a fault can easily propagate between process units due to the interconnections of material and information flows. Thus the problem of fault detection and isolation for these processes is more concerned about the root cause and fault propagation before applying quantitative methods in local models. Process topology and causality, as the key features of the process description, need to be captured from process knowledge and process data. The modelling methods from these two aspects are overviewed in this paper. From process knowledge, structural equation modelling, various causal graphs, rule-based models, and ontological models are summarized. From process data, cross-correlation analysis, Granger causality and its extensions, frequency domain methods, information-theoretical methods, and Bayesian nets are introduced. Based on these models, inference methods are discussed to find root causes and fault propagation paths under abnormal situations. Some future work is proposed in the end.

Comparisons of Measurements and Modeling of Solar Eclipse Effects on VLF Transmissions

Science.gov (United States)

Eccles, J. V.; Rice, D. D.; Sojka, J. J.; Marshall, R. A.; Drob, D. P.; Decena, J. C.

2017-12-01

The solar eclipse of 2017 August 21 provides an excellent opportunity to examine Very Low Frequency (VLF) radio signal propagation through the path of the solar eclipse between Navy VLF transmitters and several VLF receivers. The VLF transmitters available for this study radio signal propagation study are NLK in Jim Creek, Washington (24.8 kHz, 192 kW, 48.20N, 121.90W), NML in LaMour, North Dakota (25.2 kHz, 500 kW 46.37N, 93.34W), and NAA in Cutler, Maine (24.0 kHz, 1000 kW, 44.65N, 67.29W). These VLF transmitters provide propagation paths to three VLF receivers at Utah State University (41.75N, 111.76W), Bear Lake Observatory (41.95N, 111.39W), Salt Lake City (40.76N, 111.89W) and one receiver in Boulder, Colorado (40.02N, 105.27W). The solar eclipse shadow will cross all propagations paths during the day and will modify the D region electron density within the solar shadow. The week prior to the solar eclipse will be used to generate a diurnal baseline of VLF single strength for each transmitter-receiver pair. These will be compared to the day of the solar eclipse to identify VLF propagation differences through the solar eclipse shawdow. Additionally, the electron density effects of the week prior and of the solar eclipse day will be modeled using the Data-Driven D Region (DDDR) model [Eccles et al., 2005] with a detailed eclipse solar flux mask. The Long-Wave Propagation Code and the HASEL RF ray-tracing code will be used to generate VLF signal strength for each measured propagation path through the days prior and the solar eclipse day. Model-measurement comparisons will be presented and the D region electron density effects of the solar eclipse will be examined. The DDDR is a time-dependent D region model, which makes it very suitable for the solar eclipse effects on the electron density for the altitude range of 36 to 130 km. Eccles J. V., R. D. Hunsucker, D. Rice, J. J. Sojka (2005), Space weather effects on midlatitude HF propagation paths: Observations and

Ray-Based Statistical Propagation Modeling for Indoor Corridor Scenarios at 15 GHz

Directory of Open Access Journals (Sweden)

Qi Wang

2016-01-01

Full Text Available According to the demands for fifth-generation (5G communication systems, high frequency bands (above 6 GHz need to be adopted to provide additional spectrum. This paper investigates the characteristics of indoor corridor channels at 15 GHz. Channel measurements with a vector network analyzer in two corridors were conducted. Based on a ray-optical approach, a deterministic channel model covering both antenna and propagation characteristic is presented. The channel model is evaluated by comparing simulated results of received power and root mean square delay spread with the corresponding measurements. By removing the impact of directional antennas from the transmitter and receiver, a path loss model as well as small-scale fading properties for typical corridors is presented based on the generated samples from the deterministic model. Results show that the standard deviation of path loss variation is related to the Tx height, and placing the Tx closer to the ceiling leads to a smaller fluctuation of path loss.

HF-DLLME

OpenAIRE

Simão, Vanessa

2015-01-01

Tese (doutorado) - Universidade Federal de Santa Catarina, Centro de Ciências Físicas e Matemáticas, Programa de Pós-Graduação em Química, Florianópolis, 2015. Neste trabalho foi proposto, pela primeira vez, a combinação simultânea das técnicas de microextração em fase líquida suportada em fibra oca (HF-LPME) e microextração líquido-líquido dispersiva (DLLME) para aplicação em amostras líquidas. Dois estudos foram desenvolvidos utilizando a metodologia proposta, a qua...

Phase transformation and precipitation in aged Ti-Ni-Hf high-temperature shape memory alloys

International Nuclear Information System (INIS)

Meng, X.L.; Cai, W.; Zheng, Y.F.; Zhao, L.C.

2006-01-01

More attention has been paid to ternary Ti-Ni-Hf high-temperature shape memory alloys (SMAs) due to their high phase transformation temperatures, good thermal stability and low cost. However, the Ti-Ni-Hf alloys have been found to have low ductility and only about 3% shape memory effect and these have hampered their applications. It is well known that there are three methods to improve the shape memory properties of high-temperature SMAs: (a) cold rolling + annealing; (b) adding another element to the alloy; (c) aging. These methods are not suitable to improve the properties of Ti-Ni-Hf alloys. In this paper, a method of conditioning Ni-rich Ti-Ni-Hf alloys as high-temperature SMAs by aging is presented. For Ni-rich Ti 80-x Ni x Hf 20 alloys (numbers indicate at.%) the phase transformation temperatures are on average increased by more than 100 K by aging at 823 K for 2 h. Especially for those alloys with Ni contents less than 50.6 at.%, the martensitic transformation start temperatures (M s ) are higher than 473 K after aging. Transmission electron microscopy shows the presence of (Ti + Hf) 3 Ni 4 precipitates after aging. Compared with the precipitation of Ti 3 Ni 4 particles in Ni-rich Ti-Ni alloys, the precipitation of (Ti + Hf) 3 Ni 4 particles in Ni-rich Ti-Ni-Hf alloys needs higher temperatures and longer times

NASA Lunar Base Wireless System Propagation Analysis

Science.gov (United States)

Hwu, Shian U.; Upanavage, Matthew; Sham, Catherine C.

2007-01-01

There have been many radio wave propagation studies using both experimental and theoretical techniques over the recent years. However, most of studies have been in support of commercial cellular phone wireless applications. The signal frequencies are mostly at the commercial cellular and Personal Communications Service bands. The antenna configurations are mostly one on a high tower and one near the ground to simulate communications between a cellular base station and a mobile unit. There are great interests in wireless communication and sensor systems for NASA lunar missions because of the emerging importance of establishing permanent lunar human exploration bases. Because of the specific lunar terrain geometries and RF frequencies of interest to the NASA missions, much of the published literature for the commercial cellular and PCS bands of 900 and 1800 MHz may not be directly applicable to the lunar base wireless system and environment. There are various communication and sensor configurations required to support all elements of a lunar base. For example, the communications between astronauts, between astronauts and the lunar vehicles, between lunar vehicles and satellites on the lunar orbits. There are also various wireless sensor systems among scientific, experimental sensors and data collection ground stations. This presentation illustrates the propagation analysis of the lunar wireless communication and sensor systems taking into account the three dimensional terrain multipath effects. It is observed that the propagation characteristics are significantly affected by the presence of the lunar terrain. The obtained results indicate the lunar surface material, terrain geometry and antenna location are the important factors affecting the propagation characteristics of the lunar wireless systems. The path loss can be much more severe than the free space propagation and is greatly affected by the antenna height, surface material and operating frequency. The

Decolourization and degradation of azo Dye, Synozol Red HF6BN ...

African Journals Online (AJOL)

Decolourization and degradation of azo Dye, Synozol Red HF6BN, by Pleurotus ostreatus. Sidra Ilyas, Skinder Sultan Sultan, Abdul Rehman. Abstract. The present paper focuses on the use of fungus, Pleurotus ostreatus, to decolorize and degrade azo dye, Synazol Red HF6BN. Decolorization study showed that P.

The effect of subionospheric propagation on whistlers recorded by the DEMETER satellite – observation and modelling

Directory of Open Access Journals (Sweden)

O. E. Ferencz

2007-06-01

Full Text Available During a routine analysis of whistlers on the wide-band VLF recording of the DEMETER satellite, a specific signal structure of numerous fractional-hop whistlers, termed the "Spiky Whistler" (SpW was identified. These signals appear to be composed of a conventional whistler combined by the compound mode-patterns of guided wave propagation, suggesting a whistler excited by a lightning "tweek" spheric. Rigorous, full-wave modelling of tweeks, formed by the long subionospheric guided spheric propagation and of the impulse propagation across an arbitrarily inhomogeneous ionosphere, gave an accurate description of the SpW signals. The electromagnetic impulses excited by vertical, preferably CG lightning discharge, exhibited the effects of guided behaviour and of the dispersive ionospheric plasma along their paths. This modelling and interpretation provides a consistent way to determine the generation and propagation characteristics of the recorded SpW signals, as well as to describe the traversed medium.

Very high latitude F-region irregularities observed by HF-radar backscatter

International Nuclear Information System (INIS)

Baker, K.B.; Greenwald, R.A.; Tsunoda, R.T.

1983-01-01

In February and March, 1982, a coherent scatter HF radar was operated from Cleary, Alaska to observe 7- to 15-m wavelength F-region plasma irregularities near the poleward edge of the auroral zone and in the polar cap. The radar operated for five days from February 25 to March 1 and produced approximately 700,000 Doppler spectra during that time. Of those nearly 700,000 spectra, approximately 10% showed backscattered power 3 dB or more above the noise level. A ray tracing technique using electron densities determined by the Chatanika incoherent scatter radar was used to predict locations where the HF waves were approximately normal to the magnetic field. If those locations were also to contain small scale electron density structure, then one would expect them to backscatter the HF waves. Several comparisons were made between predicted and observed locations of radiowave backscatter and excellent agreement was obtained. In addition, comparisons of the Doppler velocities observed by the coherent scatter HF radar and those observed by the Chatanika radar showed good agreement, suggesting that the plasma irregularities observed by the HF radar drift with the ambient plasma. In addition, average vector velocities calculated for the entire 5-day period show a flow pattern consistent with polar cap convection models. This again indicates that the irregularities drift with the plasma, as is predicted by a number of theories of F-region plasma irregularities. In the summer of 1983, the research program begun with those measurements will be continued with a steerable phased-array HF radar located at Goose Bay, Labrador, that will view the same ionospheric region as does the Sondre Stromfjord incoherent scatter radar

Mining the Temporal Dimension of the Information Propagation

Science.gov (United States)

Berlingerio, Michele; Coscia, Michele; Giannotti, Fosca

In the last decade, Social Network Analysis has been a field in which the effort devoted from several researchers in the Data Mining area has increased very fast. Among the possible related topics, the study of the information propagation in a network attracted the interest of many researchers, also from the industrial world. However, only a few answers to the questions “How does the information propagates over a network, why and how fast?” have been discovered so far. On the other hand, these answers are of large interest, since they help in the tasks of finding experts in a network, assessing viral marketing strategies, identifying fast or slow paths of the information inside a collaborative network. In this paper we study the problem of finding frequent patterns in a network with the help of two different techniques: TAS (Temporally Annotated Sequences) mining, aimed at extracting sequential patterns where each transition between two events is annotated with a typical transition time that emerges from input data, and Graph Mining, which is helpful for locally analyzing the nodes of the networks with their properties. Finally we show preliminary results done in the direction of mining the information propagation over a network, performed on two well known email datasets, that show the power of the combination of these two approaches.

Quivers of Bound Path Algebras and Bound Path Coalgebras

Directory of Open Access Journals (Sweden)

Dr. Intan Muchtadi

2010-09-01

Full Text Available bras and coalgebras can be represented as quiver (directed graph, and from quiver we can construct algebras and coalgebras called path algebras and path coalgebras. In this paper we show that the quiver of a bound path coalgebra (resp. algebra is the dual quiver of its bound path algebra (resp. coalgebra.

Fractional path planning and path tracking

International Nuclear Information System (INIS)

Melchior, P.; Jallouli-Khlif, R.; Metoui, B.

2011-01-01

This paper presents the main results of the application of fractional approach in path planning and path tracking. A new robust path planning design for mobile robot was studied in dynamic environment. The normalized attractive force applied to the robot is based on a fictitious fractional attractive potential. This method allows to obtain robust path planning despite robot mass variation. The danger level of each obstacles is characterized by the fractional order of the repulsive potential of the obstacles. Under these conditions, the robot dynamic behavior was studied by analyzing its X - Y path planning with dynamic target or dynamic obstacles. The case of simultaneously mobile obstacles and target is also considered. The influence of the robot mass variation is studied and the robustness analysis of the obtained path shows the robustness improvement due to the non integer order properties. Pre shaping approach is used to reduce system vibration in motion control. Desired systems inputs are altered so that the system finishes the requested move without residual vibration. This technique, developed by N.C. Singer and W.P.Seering, is used for flexible structure control, particularly in the aerospace field. In a previous work, this method was extended for explicit fractional derivative systems and applied to second generation CRONE control, the robustness was also studied. CRONE (the French acronym of C ommande Robuste d'Ordre Non Entier ) control system design is a frequency-domain based methodology using complex fractional integration.

Preparation, structure and properties of hafnium compounds in the system Hf-C-N-O

International Nuclear Information System (INIS)

Brundiers, G.D.

1975-08-01

Highly dense, homogenous and single phase hafnium carbonitride samples (with low oxygen content) were prepared in the whole concentration range of the ternary cubic carbonitrides. Stoichiometric hafnium oxicarbides were also prepared within the range of solubility. The procedure involved the hot pressing of powders of HfC, HfN, Hf, Hf-Oxide and carbon at temperatures of 3,000 0 C and pressures up to 550 kpf/cm 2 using a novel technique. Small single crystals of slightly substoichiometric HfN were also repared. The densification of the powders was studied as a function of the non-metal concentration. Carbonitrides with N/Hf ratio of 0.37 were prepared in a high temperature autoclave operating at medium pressures by the reaction of HfC with nitrogen. All the samples were characterized by density measurements, chemical, X-ray and metallographic analysis and in some cases with the aid of quantitative metallography and microprobe analysis. Typical properties investigated were lattice parameter, thermal expansion, microhardness and electrical resistivity as function of the non-metal content. For specific concentrations extreme values in the properties are attained. With the aid of the valence electron concentration (VEC) parameter, the properties can be correlated with the density of states of electrons at the Fermi level. (orig./HK) [de

Charge storage characteristics and tunneling mechanism of amorphous Ge-doped HfO{sub x} films

Energy Technology Data Exchange (ETDEWEB)

Qiu, X.Y.; Zhang, S.Y.; Zhang, T.; Wang, R.X.; Li, L.T.; Zhang, Y. [Southwest University, School of Physical Science and Technology, Chongqing (China); Dai, J.Y. [The Hong Kong Polytechnic University, Department of Applied Physics, Hong Kong (China)

2016-09-15

Amorphous Ge-doped HfO{sub x} films have been deposited on p-Si(100) substrates by means of RF magnetron sputtering. Microstructural investigations reveal the partial oxidation of doped Ge atoms in the amorphous HfO{sub x} matrix and the existence of HfSiO{sub x} interfacial layer. Capacitance-voltage hysteresis of the Ag-/Ge-doped HfO{sub x}/Si/Ag memory capacitor exhibits a memory window of 3.15 V which can maintain for >5 x 10{sup 4} cycles. Current-voltage characteristics reveal that Poole-Frenkel tunneling is responsible for electron transport in the Ge-doped HfO{sub x} film. (orig.)

The effects of sacubitril/valsartan on coronary outcomes in PARADIGM-HF

DEFF Research Database (Denmark)

Mogensen, Ulrik M.; Køber, Lars; Kristensen, Søren L.

2017-01-01

Background Angiotensin converting enzyme inhibitors (ACE-I), are beneficial both in heart failure with reduced ejection fraction (HF-REF) and after myocardial infarction (MI). We examined the effects of the angiotensin-receptor neprilysin inhibitor sacubitril/valsartan, compared with the ACE......-I enalapril, on coronary outcomes in PARADIGM-HF. Methods and results We examined the effect of sacubitril/valsartan compared with enalapril on the following outcomes: i) the primary composite endpoint of cardiovascular (CV) death or HF hospitalization, ii) a pre-defined broader composite including...... patients, compared with enalapril, sacubitril/valsartan reduced the risk of the primary outcome (HR 0.80 [0.73–0.87], P 

Assembly of the CMS HF (hadron forward) calorimeter, April 2003 to June 2005

CERN Multimedia

Tejinder S. Virdee, CERN

2005-01-01

The forward calorimeters (HF) of the CMS hadron calorimeter system are located 11.2 m from the interaction point. Each HF module is composed by 18 wedges, made of steel absorbers and radiation-hard quartz fibers. The photogallery shows the wedges (Figs. 1-3, April 2003), the assembly of one HF module (Figs. 4-9, May and June 2004) and the assembly of the other (Figs. 10-11, June 2005)

Causality and matter propagation in 3D spin foam quantum gravity

International Nuclear Information System (INIS)

Oriti, Daniele; Tlas, Tamer

2006-01-01

In this paper we tackle the issue of causality in quantum gravity, in the context of 3d spin foam models. We identify the correct procedure for implementing the causality/orientation dependence restriction that reduces the path integral for BF theory to that of quantum gravity in first order form. We construct explicitly the resulting causal spin foam model. We then add matter degrees of freedom to it and construct a causal spin foam model for 3d quantum gravity coupled to matter fields. Finally, we show that the corresponding spin foam amplitudes admit a natural approximation as the Feynman amplitudes of a noncommutative quantum field theory, with the appropriate Feynman propagators weighting the lines of propagation, and that this effective field theory reduces to the usual quantum field theory in flat space in the no-gravity limit

Numerical study of the generation and propagation of ultralow-frequency waves by artificial ionospheric F region modulation at different latitudes

Directory of Open Access Journals (Sweden)

X. Xu

2016-09-01

Full Text Available Powerful high-frequency (HF radio waves can be used to efficiently modify the upper-ionospheric plasmas of the F region. The pressure gradient induced by modulated electron heating at ultralow-frequency (ULF drives a local oscillating diamagnetic ring current source perpendicular to the ambient magnetic field, which can act as an antenna radiating ULF waves. In this paper, utilizing the HF heating model and the model of ULF wave generation and propagation, we investigate the effects of both the background ionospheric profiles at different latitudes in the daytime and nighttime ionosphere and the modulation frequency on the process of the HF modulated heating and the subsequent generation and propagation of artificial ULF waves. Firstly, based on a relation among the radiation efficiency of the ring current source, the size of the spatial distribution of the modulated electron temperature and the wavelength of ULF waves, we discuss the possibility of the effects of the background ionospheric parameters and the modulation frequency. Then the numerical simulations with both models are performed to demonstrate the prediction. Six different background parameters are used in the simulation, and they are from the International Reference Ionosphere (IRI-2012 model and the neutral atmosphere model (NRLMSISE-00, including the High Frequency Active Auroral Research Program (HAARP; 62.39° N, 145.15° W, Wuhan (30.52° N, 114.32° E and Jicamarca (11.95° S, 76.87° W at 02:00 and 14:00 LT. A modulation frequency sweep is also used in the simulation. Finally, by analyzing the numerical results, we come to the following conclusions: in the nighttime ionosphere, the size of the spatial distribution of the modulated electron temperature and the ground magnitude of the magnetic field of ULF wave are larger, while the propagation loss due to Joule heating is smaller compared to the daytime ionosphere; the amplitude of the electron temperature

Structural, morphological, optical and photoluminescence properties of HfO2 thin films

International Nuclear Information System (INIS)

Ma, C.Y.; Wang, W.J.; Wang, J.; Miao, C.Y.; Li, S.L.; Zhang, Q.Y.

2013-01-01

Nanocrystalline monoclinic HfO 2 films with an average crystal size of 4.2–14.8 nm were sputter deposited under controlled temperatures and their structural characteristics and optical and photoluminescence properties have been evaluated. Structural investigations indicate that monoclinic HfO 2 films grown at higher temperatures above 400 °C are highly oriented along the (− 111) direction. The lattice expansion increases with diminishing HfO 2 crystalline size below 6.8 nm while maximum lattice expansion occurs with highly oriented monoclinic HfO 2 of crystalline size about 14.8 nm. The analysis of atomic force microscopy shows that the film growth at 600 °C can be attributed to the surface-diffusion-dominated growth. The intensity of the shoulderlike band that initiates at ∼ 5.7 eV and saturates at 5.94 eV shows continued increase with increasing crystalline size, which is intrinsic to nanocrystalline monoclinic HfO 2 films. Optical band gap varies in the range 5.40 ± 0.03–5.60 ± 0.03 eV and is slightly decreased with the increase in crystalline size. The luminescence band at 4.0 eV of HfO 2 films grown at room temperature can be ascribed to the vibronic transition of excited OH · radical while the emission at 3.2–3.3 eV for the films grown at all temperatures was attributed to the radiative recombination at impurity and/or defect centers. - Highlights: • Nanocrystalline monoclinic HfO 2 films were sputter deposited. • Structural, optical and photoluminescence properties were studied. • To analyze the scaling behavior using the power spectral density • Optical and photoluminescence properties strongly depend on film growth temperature

Temperature dependence of the resistivity and tunneling magnetoresistance of sputtered FeHf(Si)O cermet films

NARCIS (Netherlands)

Strijkers, G.J.; Swagten, H.J.M.; Rulkens, B.; Bitter, R.H.J.N.; Jonge, de W.J.M.; Bloemen, P.J.H.; Schep, K.M.

1998-01-01

We have studied the tunneling resistivity and magnetoresistance of reactive sputter deposited FeHfO and FeHfSiO thin granular films. Maximum magnetoresistance ratios at room temperature of 2% and 3.2% were observed for films with compositions of Fe47Hf10O43 and Fe40Hf6Si6O48, respectively. The

Efficacy of Sacubitril/Valsartan Relative to a Prior Decompensation: The PARADIGM-HF Trial.

Science.gov (United States)

Solomon, Scott D; Claggett, Brian; Packer, Milton; Desai, Akshay; Zile, Michael R; Swedberg, Karl; Rouleau, Jean; Shi, Victor; Lefkowitz, Martin; McMurray, John J V

2016-10-01

This study assessed whether the benefit of sacubtril/valsartan therapy varied with clinical stability. Despite the benefit of sacubitril/valsartan therapy shown in the PARADIGM-HF (Prospective Comparison of ARNI with ACEI to Determine Impact on Global Mortality and Morbidity in Heart Failure) trial, it has been suggested that switching from an angiotensin-converting enzyme inhibitor or an angiotensin receptor blocker should be delayed until occurrence of clinical decompensation. Outcomes were compared among patients who had prior hospitalization within 3 months of screening (n = 1,611 [19%]), between 3 and 6 months (n = 1,009 [12%]), between 6 and 12 months (n = 886 [11%]), >12 months (n = 1,746 [21%]), or who had never been hospitalized (n = 3,125 [37%]). Twenty percent of patients without prior HF hospitalization experienced a primary endpoint of cardiovascular death or heart failure (HF) hospitalization during the course of the trial. Despite the increased risk associated with more recent hospitalization, the efficacy of sacubitril/valsartan therapy did not differ from that of enalapril according to the occurrence of or time from hospitalization for HF before screening, with respect to the primary endpoint or with respect to cardiovascular or all-cause mortality. Patients with recent HF decompensation requiring hospitalization were more likely to experience cardiovascular death or HF hospitalization than those who had never been hospitalized. Patients who were clinically stable, as shown by a remote HF hospitalization (>3 months prior to screening) or by lack of any prior HF hospitalization, were as likely to benefit from sacubitril/valsartan therapy as more recently hospitalized patients. (Prospective Comparison of ARNI with ACEI to Determine Impact on Global Mortality and Morbidity in Heart Failure [PARADIGM-HF]; NCT01035255). Copyright © 2016 American College of Cardiology Foundation. Published by Elsevier Inc. All rights reserved.

Evolution of Zr/Hf/Zr trilayers during annealing studied by RBS

International Nuclear Information System (INIS)

Kling, A.; Soares, J.C.

2010-01-01

The Zr/Hf system is highly interesting due its various applications, e.g. formation of amorphous ternary alloys, superconductive properties and production of gate oxide layers with high dielectric coefficients by oxidation of Zr/Hf multilayers. In this work Zr/Hf/Zr trilayers with an individual layer thickness of approximately 50 nm were deposited by electron gun evaporation on a substrate consisting of silicon covered by a micrometer thick thermal oxide layer. Samples were subjected to annealing procedures at 500 and 1200 o C in flowing air atmosphere to promote oxidation and Zr/Hf interdiffusion effects. RBS studies of the as-deposited and annealed samples were performed at the van-de-Graaff accelerator of ITN using He + and H + beams with energies between 2.0 and 2.525 MeV in order to study compositional changes induced by the heat treatment. In the case of low-temperature annealing the layer system appears, besides the oxidation process starting from the surface, to be stable. On the other hand, high-temperature annealing leads to an asymmetric Hf-diffusion into the surface and interior Zr-layer provoked by anomalous diffusion due to a phase transition in Zr accompanied by an almost complete oxidation of the layer structure Oxygen and metal depth distributions obtained by RBS in the as-deposited and treated samples are provided.

Enhancement of organic light-emitting device performances with Hf-doped indium tin oxide anodes

International Nuclear Information System (INIS)

Chen, T.-H.; Liou, Y.; Wu, T.J.; Chen, J.Y.

2004-01-01

We have enhanced the luminance and the power efficiency of organic light-emitting devices with Hf-doped indium tin oxide (ITO) anodes instead of a CuPc layer. The Hf-doped ITO layer with a thickness of 15 nm was deposited on top of the ITO anode. Less than 10 mol. % of Hf was doped in ITO films by adjusting the sputtering rates of both sources. The highest work function of the Hf-doped ITO layers was 5.4 eV at the Hf concentrations about 10 mol. %. The driving voltages of the device have been reduced by 1 V. A luminance of 1000 cd/m 2 at 7 mA/cm 2 , a current efficiency of 14 cd/A, and a power efficiency of 6 lm/W at 6 mA/cm 2 have been achieved in the device with a 4 mol. % Hf-doped ITO layer (work function=5.2 eV). In general, the performance was about 50% better than the device with a CuPc buffer layer

Characteristics of domain wall chirality and propagation in a Y-junction nanowire

Energy Technology Data Exchange (ETDEWEB)

Kwak, W.-Y.; Yoon, Seungha; Kwon, J.-H. [School of Materials Science and Engineering, Gwangju Institute of Science and Technology (GIST), Gwangju 61005 (Korea, Republic of); Grünberg, P. [Gruenberg Center for Magnetic Nanomaterials, Gwangju Institute of Science and Technology (GIST), Gwangju 61005 (Korea, Republic of); Cho, B. K., E-mail: chobk@gist.ac.kr [School of Materials Science and Engineering, Gwangju Institute of Science and Technology (GIST), Gwangju 61005 (Korea, Republic of); Gruenberg Center for Magnetic Nanomaterials, Gwangju Institute of Science and Technology (GIST), Gwangju 61005 (Korea, Republic of)

2016-01-14

Chirality-dependent propagation of transverse wall along a nanowire was investigated using a Y-junction with spin-valve structure. It was found that the Y-junction can be used for convenient and effective electric detection of transverse domain wall chirality, especially in a nanowire with sub-200 nm width, where it is difficult to electrically detect chirality using conventional artificial defect, such as a notch, due to small resistance change. Domain wall propagation path in the Y-junction was found to be determined by the wall chirality, whether clockwise or counterclockwise. Using the Y-junction nanowire, characteristics of domain wall chirality that was nucleated in a nucleation pad, attached at the end of a nanowire, were studied and found to be in good agreement with the results of theoretical simulation.

Wideband propagation measurements at 30.3 GHz through a pecan orchard in Texas

Science.gov (United States)

Papazian, Peter B.; Jones, David L.; Espeland, Richard H.

1992-09-01

Wideband propagation measurements were made in a pecan orchard in Texas during April and August of 1990 to examine the propagation characteristics of millimeter-wave signals through vegetation. Measurements were made on tree obstructed paths with and without leaves. The study presents narrowband attenuation data at 9.6 and 28.8 GHz as well as wideband impulse response measurements at 30.3 GHz. The wideband probe (Violette et al., 1983), provides amplitude and delay of reflected and scattered signals and bit-error rate. This is accomplished using a 500 MBit/sec pseudo-random code to BPSK modulate a 28.8 GHz carrier. The channel impulse response is then extracted by cross correlating the received pseudo-random sequence with a locally generated replica.

SIMS study of oxygen diffusion in monoclinic HfO2

Science.gov (United States)

Mueller, Michael P.; De Souza, Roger A.

2018-01-01

The diffusion of oxygen in dense ceramics of monoclinic HfO2 was studied by means of (18O/16O) isotope exchange annealing and subsequent determination of isotope depth profiles by Secondary Ion Mass Spectrometry. Anneals were performed in the temperature range of 573 ≤T /K ≤ 973 at an oxygen partial pressure of p O2=200 mbar . All measured isotope profiles exhibited two features: the first feature, closer to the surface, was attributed mainly to slow oxygen diffusion in an impurity silicate phase; the second feature, deeper in the sample, was attributed to oxygen diffusion in bulk monoclinic HfO2 . The activation enthalpy of oxygen tracer diffusion in bulk HfO2 was found to be ΔHD∗≈0.5 eV .