WorldWideScience

Sample records for hf column abundances

  1. Observed and simulated time evolution of HCl, ClONO2, and HF total column abundances

    Directory of Open Access Journals (Sweden)

    B.-M. Sinnhuber

    2011-12-01

    Full Text Available Time series of total column abundances of hydrogen chloride (HCl, chlorine nitrate (ClONO2, and hydrogen fluoride (HF were determined from ground-based Fourier transform infrared (FTIR spectra recorded at 17 sites belonging to the Network for the Detection of Atmospheric Composition Change (NDACC and located between 80.05° N and 77.82° S. These measurements are compared with calculations from five different models: the two-dimensional Bremen model, the two chemistry-transport models KASIMA and SLIMCAT, and the two chemistry-climate models EMAC and SOCOL. The overall agreement between the measurements and models for the total column abundances and the seasonal cycles is good. Trends of HCl, ClONO2, and HF are calculated from both measurement and model time series data, with a focus on the time range 2000–2009. Their precision is estimated with the bootstrap resampling method. The sensitivity of the trend results with respect to the fitting function, the time of year chosen and time series length is investigated, as well as a bias due to the irregular sampling of the measurements. For the two chlorine species, a decrease is expected during this period because the emission of their prominent anthropogenic source gases (solvents, chlorofluorocarbons (CFCs was restricted by the Montreal Protocol 1987 and its amendments and adjustments. As most of the restricted source gases also contain fluorine, the HF total column abundance was also influenced by the above-mentioned regulations in the time period considered. The measurements and model results investigated here agree qualitatively on a decrease of the chlorine species by around −1 % yr−1. The models simulate an increase of HF of around +1 % yr−1. This also agrees well with most of the measurements, but some of the FTIR series in the Northern Hemisphere show a stabilisation or even a decrease in the last few years. In general, for all three gases, the measured trends vary more strongly with

  2. Observed and simulated time evolution of HCl, ClONO2, and HF total column abundances

    Directory of Open Access Journals (Sweden)

    B.-M. Sinnhuber

    2012-04-01

    Full Text Available Time series of total column abundances of hydrogen chloride (HCl, chlorine nitrate (ClONO2, and hydrogen fluoride (HF were determined from ground-based Fourier transform infrared (FTIR spectra recorded at 17 sites belonging to the Network for the Detection of Atmospheric Composition Change (NDACC and located between 80.05° N and 77.82° S. By providing such a near-global overview on ground-based measurements of the two major stratospheric chlorine reservoir species, HCl and ClONO2, the present study is able to confirm the decrease of the atmospheric inorganic chlorine abundance during the last few years. This decrease is expected following the 1987 Montreal Protocol and its amendments and adjustments, where restrictions and a subsequent phase-out of the prominent anthropogenic chlorine source gases (solvents, chlorofluorocarbons were agreed upon to enable a stabilisation and recovery of the stratospheric ozone layer. The atmospheric fluorine content is expected to be influenced by the Montreal Protocol, too, because most of the banned anthropogenic gases also represent important fluorine sources. But many of the substitutes to the banned gases also contain fluorine so that the HF total column abundance is expected to have continued to increase during the last few years. The measurements are compared with calculations from five different models: the two-dimensional Bremen model, the two chemistry-transport models KASIMA and SLIMCAT, and the two chemistry-climate models EMAC and SOCOL. Thereby, the ability of the models to reproduce the absolute total column amounts, the seasonal cycles, and the temporal evolution found in the FTIR measurements is investigated and inter-compared. This is especially interesting because the models have different architectures. The overall agreement between the measurements and models for the total column abundances and the seasonal cycles is good. Linear trends of HCl, ClONO2, and HF are calculated from both

  3. Hf Transition Probabilities and Abundances

    CERN Document Server

    Lawler, J E; Labby, Z E; Sneden, C; Cowan, J J; Ivans, I I

    2006-01-01

    Radiative lifetimes from laser-induced fluorescence measurements, accurate to about +/- 5 percent, are reported for 41 odd-parity levels of Hf II. The lifetimes are combined with branching fractions measured using Fourier transform spectrometry to determine transition probabilities for 150 lines of Hf II. Approximately half of these new transition probabilities overlap with recent independent measurements using a similar approach. The two sets of measurements are found to be in good agreement for measurements in common. Our new laboratory data are applied to refine the hafnium photospheric solar abundance and to determine hafnium abundances in 10 metal-poor giant stars with enhanced r-process abundances. For the Sun we derive log epsilon (Hf) = 0.88 +/- 0.08 from four lines; the uncertainty is dominated by the weakness of the lines and their blending by other spectral features. Within the uncertainties of our analysis, the r-process-rich stars possess constant Hf/La and Hf/Eu abundance ratios, log epsilon (Hf...

  4. Trends of HCl, ClONO 2 and HF column abundances from ground-based FTIR measurements in Kiruna (Sweden in comparison with KASIMA model calculations

    Directory of Open Access Journals (Sweden)

    U. Raffalski

    2011-01-01

    Full Text Available Trends of hydrogen chloride (HCl, chlorine nitrate (ClONO2 and hydrogen fluoride (HF column abundances above Kiruna (Northern Sweden, 67.84° N, 20.41° E derived from nearly 14 years (1996–2009 of measurement and model data are presented. The measurements have been performed with a Bruker 120 HR (later Bruker 125 HR Fourier transform infrared (FTIR spectrometer and the model used was KASIMA (KArlsruhe SImulation model of the Middle Atmosphere. To calculate the long-term trends, a linear function combined with an annual cycle was fitted to the data using a least squares method. The precision of the resulting trends was estimated with the so-called bootstrap resampling method. The relative trends were calculated on the basis of the linear fit result on 1 January 2000, 12:00 UTC. For hydrogen fluoride, both model and measurements show a positive trend that seems to decrease in the last few years. This suggests a stabilisation of the HF total column abundance. For the summer data (August to November, the FTIR trend of (+1.25 ± 0.28%/yr agrees within errors with the KASIMA one of (+1.55 ± 0.11%/yr. The trends determined for HCl and ClONO2 are significantly negative over the time period considered here. This corresponds to the expectations because the emission of their precursors (chlorofluorocarbons and hydrochlorofluorocarbons has been restricted in the Montreal Protocol in 1987 and its amendments and adjustments. The relative trend for ClONO2 from the FTIR measurements amounts to (−3.28 ± 0.56%/yr and the one for HCl to (−0.81± 0.23%/yr. KASIMA simulates a weaker decrease: For ClONO2, the result is (−0.90 ± 0.10%/yr and for HCl (−0.17± 0.06%/yr. Part of the difference between measurement and model data can be explained by sampling and the stronger annual cycle indicated by the measurements. There is a factor of about four between the trends of HCl and ClONO2 above Kiruna for both measurement and model data. The absolute values of

  5. Diurnal variation of midlatitudinal NO3 column abundance over table mountain facility, California

    Directory of Open Access Journals (Sweden)

    Q. Li

    2011-02-01

    Full Text Available The column abundance of NO3 was measured over Table Mountain Facility, CA (34.4° N, 117.7° W from May 2003 through September 2004, using lunar occultation near full moon with a grating spectrometer. The NO3 column retrieval was performed with the differential optical absorption spectroscopy (DOAS technique using both the 623 and 662 nm NO3 absorption bands. Other spectral features such as Fraunhofer lines and absorption from water vapor and oxygen were removed using solar spectra obtained at different airmass factors. We observed a seasonal variation, with nocturnally averaged NO3 columns between 5−7 × 1013 molec cm−2 during October through March, and 5−22 × 1013 molec cm−2 during April through September. A subset of the data, with diurnal variability vastly different from the temporal profile obtained from one-dimensional stratospheric model calculations, clearly has boundary layer contributions; this was confirmed by simultaneous long-path DOAS measurements. However, even the NO3 columns that did follow the modeled time evolution were often much larger than modeled stratospheric partial columns constrained by realistic temperatures and ozone concentrations. This discrepancy is attributed to substantial tropospheric NO3 in the free troposphere, which may have the same time dependence as stratospheric NO3.

  6. Airborne Measurements of Atmospheric Methane Column Abundance Made Using a Pulsed IPDA Lidar

    Science.gov (United States)

    Riris, Haris; Numata, Kenji; Li, Steve; Wu, Stewart; Ramanathan, Anamd; Dawsey, Martha; Mao, Jianping; Kawa, Randolph; Abshire, James B.

    2012-01-01

    We report airborne measurements of the column abundance of atmospheric methane made over an altitude range of 3-11 km using a direct detection IPDA lidar with a pulsed laser emitting at 1651 nm. The laser transmitter was a tunable, seeded optical parametric amplifier (OPA) pumped by a Nd:YAG laser and the receiver used a photomultiplier detector and photon counting electronics. The results follow the expected changes with aircraft altitude and the measured line shapes and optical depths show good agreement with theoretical calculations.

  7. Daily global mapping of Mars ozone column abundances with MARCI UV band imaging

    Science.gov (United States)

    Todd Clancy, R.; Wolff, Michael J.; Lefèvre, Franck; Cantor, Bruce A.; Malin, Michael C.; Smith, Michael D.

    2016-03-01

    Since November of 2006, The Mars Color Imager (MARCI) onboard the Mars Reconnaissance Orbiter (MRO) has obtained multiple-filter daily global images of Mars centered upon a local time (LT) of 3 pm. Ultraviolet imaging bands placed within (260 nm) and longward (320 nm) of Hartley band (240-300 nm) ozone (O3) absorption support retrievals of atmospheric ozone columns, with detection limits (∼1 μm-atm) appropriate to mapping elevated O3 abundances at low latitudes around Mars aphelion, and over mid-to-high latitudes during fall/winter/spring seasons. MARCI O3 maps for these regions reveal the detailed spatial (∼1° lat/long, for 8 × 8 pixel binned resolution) and temporal (daily, with substantial LT coverage at pole) behaviors of water vapor saturation conditions that force large variations in water vapor photolysis products (HOx-OH, HO2, and H) responsible for the catalytic destruction of O3 in the Mars atmosphere. A detailed description of the MARCI O3 data set, including measurement and retrieval characteristics, is provided in conjunction with comparisons to Mars Express SPICAM ozone measurements (Perrier, S. et al. [2006]. J. Geophys. Res. (Planets) 111) and LMD GCM simulated O3 abundances (Lefèvre, F. [2004]. J. Geophys. Res. (Planets) 109). Presented aspects of the MARCI ozone mapping data set include aphelion increases in low latitude O3, dynamically evolving high latitude O3 maxima associated with planetary waves and weather fronts during northern early spring, and distinctive winter/spring O3 and CO increases within the Hellas Basin associated with transport of condensation-enhanced south polar air mass. Comparisons of coincident MARCI measurements and LMD simulations for ice cloud and O3 columns are considered in the context of potential heterogeneous photochemical processes (Lefèvre, F. [2008]. Nature 454, 971-975), which are not strongly evidenced in the MARCI observations. Modest interannual variations are exhibited, most notably a 20% reduction

  8. Elemental Abundances in Two High Column Density Damped Lyman Alpha Systems at z < 1.5

    CERN Document Server

    Rao, S M; Howk, J C; Wolfe, A M; Rao, Sandhya M.; Prochaska, Jason X.; Wolfe, Arthur M.

    2004-01-01

    We present Keck/HIRES abundance measurements and metal-line kinematic profiles of the damped Lyman alpha systems (DLAs) towards the quasars Q0933+733 (z_abs=1.479) and Q0948+433 (z_abs=1.233). These two DLAs have among the five highest HI column densities at any redshift: N(HI)=4.2E21 cm^{-2}. The metal-line data, presented here for the first time, reveal that these DLAs are noteworthy for several other reasons as well. 1) The Q0933+733 DLA exhibits simple kinematic structure with unusually narrow velocity widths as measured from its unsaturated metal lines (delta v=16 km/s). At 2.6% solar, it has the second lowest metallicity at z -1) and a significant alpha-enhancement. The strong metal lines of this DLA have made possible the detection of TiII1910, CoII2012, and MgI2026. 3) We find that the relative gas-phase abundances of both DLAs follow the general trend seen at high redshift, e.g., enhanced Zn/Fe and Si/Fe, and sub-solar Mn/Fe, indicating that there is little evolution in the nucleosynthetic patterns o...

  9. Improved ground-based FTS measurement for column abundance CO2 retrievals(Conference Presentation)

    Science.gov (United States)

    Goo, Tae-Young

    2016-10-01

    The National Institute of Meteorological Sciences has operated a ground-based Fourier Transform Spectrometer (FTS) at Anmyeondo, Korea since December 2012. Anmyeondo FTS site is a designated operational station of Total Carbon Column Observing Network (TCCON) and belongs to regional Global Atmosphere Watch observatory. A Bruker IFS-125HR model, which has a significantly high spectral resolution by 0.02 cm-1, is employed and instrument specification is almost same as the TCCON configuration. such as a spectrum range of 3,800 16,000 cm-1, a resolution of 1 cm-1, InGaAs and Si-Diode detectors and CaF2 beam splitter. It is found that measured spectra have a good agreement with simulated spectra. In order to improve the spectral accuracy and stability, The Operational Automatic System for Intensity of Sunray (OASIS) has been developed. The OASIS can provide consistent photon energy optimized to detector range by controlling the diameter of solar beam reflected from the mirror of suntracker. As a result, monthly modulation efficiency (ME), which indicates the spectral accuracy of FTS measurement, has been recorded the vicinity of 99.9% since Feb 2015. The ME of 98% is regarded as the error of 0.1% in the ground-based in-situ CO2 measurement. Total column abundances of CO2 and CH4 during 2015 are estimated by using GGG v14 and compared with ground-based in-situ CO2 and CH4 measurements at the height of 86 m above sea level. The seasonality of CO2 is well captured by both FTS and in-situ measurements while there is considerable difference on the amplitude of CO2 seasonal variation due to the insensitivity of column CO2 to the surface carbon cycle dynamics in nature as well as anthropogenic sources. Total column CO2 and CH4 approximately vary from 395 ppm to 405 ppm and from 1.82 ppm to 1.88 ppm, respectively. It should be noted that few measurements obtained in July to August because of a lot of cloud and fog. It is found that enhancement of CH4 from the FTS at Anmyeondo

  10. An Empirical Approach to Determining the Boundary Layer Bromine Monoxide (BrO) Abundance from Satellite Total Column Measurements

    Science.gov (United States)

    Simpson, W. R.; Donohoue, D.; Carlson, D. A.

    2009-12-01

    Unique chemistry in the Arctic boundary layer during springtime liberates bromine from sea salt, producing reactive halogen gases (e.g. atomic bromine and bromine monoxide radicals) that then drastically alter atmospheric oxidation pathways. This phenomenon causes ozone depletion events and affects mercury deposition to the snowpack. Satellite remote sensing (e.g. OMI and GOME2 observations) techniques can detect the total column abundance of BrO, which is generally the primary species of the reactive bromine family. However, BrO is also present in the stratosphere, so it is necessary to partition the satellite-observed BrO column abundance into boundary layer and non-boundary layer (primarily stratospheric) partial columns to be able to infer boundary layer abundances and hence chemical affects near the Earth's surface (i.e. ozone and mercury impacts). In this presentation, we describe an empirical method for partitioning the BrO total column and apply it globally during spring 2008. The method indicates that some BrO total column enhancements ("hotspots") are not actually enhancements in the boundary layer BrO abundance but occur aloft. Movies and a statistical analysis of the inferred boundary layer BrO abundance are presented. The method has been tested and performs well at the Barrow field site. However, in areas that lack routine ground truth BrO measurements (e.g. Hudson Bay, Canada), large tropospheric BrO abundances are indicated. It is not clear if these inferred boundary layer BrO events are real or if the simple empirical method described here is failing in those locations. Verification of this method over large spatial regions of the Arctic is needed.

  11. Identification of low abundance polyA-binding proteins in Arabidopsis chloroplast using polyA-affinity column.

    Science.gov (United States)

    Ni, Rui-Juan; Shen, Zhuo; Yang, Chuan-Ping; Wu, Ya-Dan; Bi, Ying-Dong; Wang, Bai-Chen

    2010-02-01

    Proteins could be well separated and further identified by the use of 2-DE and related techniques. Yet, there are many proteins could not be detected even by more effective dyes because of their inherent low abundance or their low resolution. As a result, polyA-affinity column was used as a method to enrich polyA-binding proteins and then identified by MALDI-TOF-MS. In this study, 23 Arabidopsis chloroplast protein spots coded by 18 genes were identified, and majority of these proteins were classified into three related categories according to their annotations in the Swiss-Prot database, including NAD-, RNA-, and ATP-binding motifs, respectively. The major goal of the present Arabidopsis chloroplast proteomics project was to identify novel polyA-binding proteins or protein isoforms located in Arabidopsis chloroplasts and the specific research of cellular proteins with extremely low transcription levels could be fulfilled.

  12. Retrieval algorithm for CO2 and CH4 column abundances from short-wavelength infrared spectral observations by the Greenhouse Gases Observing Satellite

    Directory of Open Access Journals (Sweden)

    I. Morino

    2010-11-01

    Full Text Available The Greenhouse gases Observing SATellite (GOSAT was launched on 23 January 2009 to monitor the global distributions of carbon dioxide and methane from space. It has operated continuously since then. Here we describe a retrieval algorithm for column abundances of these gases from the short-wavelength infrared spectra obtained by the Thermal And Near infrared Sensor for carbon Observation-Fourier Transform Spectrometer (TANSO-FTS. The algorithm consists of three steps. First, cloud-free observational scenes are selected by several cloud-detection methods. Then, column abundances of carbon dioxide and methane are retrieved based on the optimal estimation method. Finally, the retrieval quality is examined to exclude low-quality and/or aerosol-contaminated results. Most of the retrieval random errors come from the instrumental noise. The interferences by auxiliary parameters retrieved simultaneously with gas abundances are small. The evaluated precisions of the retrieved column abundances for single observations are less than 1% in most cases. The interhemispherical differences and the temporal variation patterns of the retrieved column abundances agree well with the current state of knowledge.

  13. Retrieval algorithm for CO2 and CH4 column abundances from short-wavelength infrared spectral observations by the Greenhouse gases observing satellite

    Directory of Open Access Journals (Sweden)

    I. Morino

    2011-04-01

    Full Text Available The Greenhouse gases Observing SATellite (GOSAT was launched on 23 January 2009 to monitor the global distributions of carbon dioxide and methane from space. It has operated continuously since then. Here, we describe a retrieval algorithm for column abundances of these gases from the short-wavelength infrared spectra obtained by the Thermal And Near infrared Sensor for carbon Observation-Fourier Transform Spectrometer (TANSO-FTS. The algorithm consists of three steps. First, cloud-free observational scenes are selected by several cloud-detection methods. Then, column abundances of carbon dioxide and methane are retrieved based on the optimal estimation method. Finally, the retrieval quality is examined to exclude low-quality and/or aerosol-contaminated results. Most of the retrieval random errors come from instrumental noise. The interferences due to auxiliary parameters retrieved simultaneously with gas abundances are small. The evaluated precisions of the retrieved column abundances for single observations are less than 1% in most cases. The interhemispherical differences and temporal variation patterns of the retrieved column abundances show features similar to those of an atmospheric transport model.

  14. HfS, Hyperfine Structure Fitting Tool

    CERN Document Server

    Estalella, Robert

    2016-01-01

    HfS is a tool to fit the hyperfine structure of spectral lines, with multiple velocity components. The HfS_nh3 procedures included in HfS fit simultaneously the hyperfine structure of the NH$_3$ (J,K)= (1,1) and (2,2) transitions, and perform a standard analysis to derive $T_\\mathrm{ex}$, NH$_3$ column density, $T_\\mathrm{rot}$, and $T_\\mathrm{k}$. HfS uses a Monte Carlo approach for fitting the line parameters. Especial attention is paid to the derivation of the parameter uncertainties. HfS includes procedures that make use of parallel computing for fitting spectra from a data cube.

  15. Linking isoprenoidal GDGT membrane lipid distributions with gene abundances of ammonia-oxidizing Thaumarchaeota and uncultured crenarchaeotal groups in the water column of a tropical lake (Lake Challa, East Africa).

    Science.gov (United States)

    Buckles, Laura K; Villanueva, Laura; Weijers, Johan W H; Verschuren, Dirk; Damsté, Jaap S Sinninghe

    2013-09-01

    Stratified lakes are important reservoirs of microbial diversity and provide habitats for niche differentiation of Archaea. In this study, we used a lipid biomarker/DNA-based approach to reveal the diversity and abundance of Archaea in the water column of Lake Challa (East Africa). Concentrations of intact polar lipid (IPL) crenarchaeol, a specific biomarker of Thaumarchaeota, were enhanced (1 ng l(-1) ) at the oxycline/nitrocline. The predominance of the more labile IPL hexose-phosphohexose crenarchaeol indicated the presence of an actively living community of Thaumarchaeota. Archaeal 16S rRNA clone libraries revealed the presence of thaumarchaeotal groups 1.1a and 1.1b at and above the oxycline. In the anoxic deep water, amoA gene abundance was an order of magnitude lower than at the oxycline and high abundance (∼90 ng l(-1) ) of an IPL with the acyclic glycerol dialkyl glycerol tetraether (GDGT-0) was evident. The predominance of archaeal 16S rRNA sequences affiliated to the uncultured crenarchaeota groups 1.2 and miscellaneous crenarchaeotic group (MCG) points to an origin of GDGT-0 from uncultured crenarchaeota. This study demonstrates the importance of thermal stratification and nutrient availability in the distribution of archaeal groups in lakes, which is relevant to constrain and validate temperature proxies based on archaeal GDGTs (i.e. TEX86 ).

  16. ExtraHF survey

    DEFF Research Database (Denmark)

    Piepoli, Massimo F; Binno, Simone; Corrà, Ugo

    2015-01-01

    AIMS: In heart failure (HF), exercise training programmes (ETPs) are a well-recognized intervention to improve symptoms, but are still poorly implemented. The Heart Failure Association promoted a survey to investigate whether and how cardiac centres in Europe are using ETPs in their HF patients...... of evidence on safety or benefit was cited. When implemented, an ETP was proposed to all HF patients in only 55% of the centres, with restriction according to severity or aetiology. CONCLUSIONS: With respect to previous surveys, there is evidence of increased availability of ETPs in HF in Europe, although too...

  17. Column flotation

    Energy Technology Data Exchange (ETDEWEB)

    Kohmuench, J.N.; Norrgran, D.A.; Luttrell, E.; Luttrell, G.H. [Virginia Tech. (United States)

    2008-04-15

    Over the last decade, column flotation has been recognised in the industry to be most efficient and economical means of recovering fine coal while maximizing product grade. When designed properly, flotation columns provide a high combustible recovery while maintaining a low product ash. The paper looks at the benefits of using column flotation for fine coal recovery. 2 refs., 5 figs.

  18. Reading Columns

    OpenAIRE

    Coutts, Marion

    2008-01-01

    Reading Columns are twin permanent public sculptures commissioned as part of a £245m scheme for the redevelopment of the Chatham Place area in Reading. Dimensions: 3.5m high x 1.3m diameter each Field of knowledge: The work consists of twin bespoke columns of stainless steel and glass over digital colour transparencies. The piece revisits and reworks the idea of the Morris Column, a 19th C feature characteristic of major European metropolitan centres. A wraparound image on each of ...

  19. Frederiksberg HF kursus

    DEFF Research Database (Denmark)

    Lindstrøm, Maria Duclos

    2008-01-01

    Notatet bygger på et interviewmateriale med dimitterede HF-kursister 3 måneder efter endt eksamen. Notatet undersøger dels, hvad der har hjulpet til at gennemføre, dels hvad der har været negativt og vanskeligt ved uddannelsen. Endvidere belyser notatet hvad kursisterne oplever at tage med fra de...

  20. PULSE COLUMN

    Science.gov (United States)

    Grimmett, E.S.

    1964-01-01

    This patent covers a continuous countercurrent liquidsolids contactor column having a number of contactor states each comprising a perforated plate, a layer of balls, and a downcomer tube; a liquid-pulsing piston; and a solids discharger formed of a conical section at the bottom of the column, and a tubular extension on the lowest downcomer terminating in the conical section. Between the conical section and the downcomer extension is formed a small annular opening, through which solids fall coming through the perforated plate of the lowest contactor stage. This annular opening is small enough that the pressure drop thereacross is greater than the pressure drop upward through the lowest contactor stage. (AEC)

  1. Column: lef

    NARCIS (Netherlands)

    Reep, Frans van der

    2012-01-01

    1e alinea column: Ook in je beleggingsbeslissingen is het voor echte performance wellicht tijd om eens voorbij best practices (dan word je namelijk hoogstens tweede) te kijken naar next practices. Als je op zeker speelt, verdien je weinig geld. Want anderen gingen je al voor. Maar kun je nog meer op

  2. Process Simulation Analysis of HF Stripping

    Directory of Open Access Journals (Sweden)

    Thaer A. Abdulla

    2013-05-01

    Full Text Available    HYSYS process simulator is used for the analysis of existing HF stripping column in LAB plant (Arab Detergent Company, Baiji-Iraq. Simulated column performance and profiles curves are constructed. The variables considered are the thermodynamic model option, bottom temperature, feed temperature, and column profiles for the temperature, vapor flow rate, liquid flow rate and composition. The five thermodynamic models options used (Margules, UNIQUAC, van laar, Antoine, and Zudkevitch-Joffee, affecting the results within (0.1-58% variation for the most cases.        The simulated results show that about 4% of paraffin (C10 & C11 presents at the top stream, which may cause a problem in the LAB production plant. The major variations were noticed for the total top vapor flow rate with bottom temperature and with feed composition. The column profiles maintain fairly constants from tray 5 to tray 18. The study gives evidence about a successful simulation with HYSYS because the results correspond with the real plant operation data.

  3. Pulsed inductive HF laser

    Energy Technology Data Exchange (ETDEWEB)

    Razhev, A M; Kargapol' tsev, E S [Institute of Laser Physics, Siberian Branch, Russian Academy of Sciences, Novosibirsk (Russian Federation); Churkin, D S; Demchuk, S V [Novosibirsk State University, Novosibirsk (Russian Federation)

    2016-03-31

    We report the results of experimentally investigated dependences of temporal, spectral and spatial characteristics of an inductive HF-laser generation on the pump conditions. Gas mixtures H{sub 2} – F{sub 2}(NF{sub 3} or SF6{sub 6}) and He(Ne) – H{sub 2} – F{sub 2}(NF{sub 3} or SF{sub 6}) were used as active media. The FWHM pulse duration reached 0.42 μs. This value corresponded to a pulsed power of 45 kW. For the first time, the emission spectrum of an inductive HF laser was investigated, which consisted of seven groups of bands with centres around the wavelengths of 2732, 2736, 2739, 2835, 2837, 2893 and 2913 nm. The cross section profile of the laser beam was a ring with a diameter of about 20 mm and width of about 5 mm. Parameters of laser operation in the repetitively pulsed regime were sufficiently stable. The amplitude instability of light pulses was no greater than 5% – 6%. (lasers)

  4. Hf isotopic compositions of the standard zircons for U-Pb dating

    Institute of Scientific and Technical Information of China (English)

    XU Ping; WU Fuyuan; XIE Liewen; YANG Yueheng

    2004-01-01

    Using the newly published Yb isotopic abundances and the mass bias relationship between Yb and Hf, we carried out an analysis of Hf isotopes in the standard zircon 91500 by means of 193 nm laser attached to Neptune multi-collector ICP-MS (LA-MC-ICPMS). The obtained Hf isotopic data, in either in situ or line scan modes, are not only identical for different spot sizes, but also are consistent with previously published results obtained on TIMS or other MC-ICPMS machines within errors. This indicates that it is possible to obtain reliable 176Hf/177Hf isotopic ratios for zircon in either in situ or line scan conditions on LA-MC-ICPMS machine, and the applied procedures in our study for elemental interfering correction are appropriate for the purpose of acquiring satisfactory accuracy for Hf isotope analyses. The Hf isotopic compositions of four zircon standards in high spatial resolution U-Pb dating, 91500, CZ3,CN92-1 and TEMORA, are measured, respectively. The obtained 176Hf/177Hf ratios are 0.282316+4 (n = 34, 2σ) for 91500, 0.281704±6 (n = 16, 2σ) for CZ3, 0.282200±6 (n = 20,2σ-) for CN92-1 and 0.282684±14 (n = 24, 2σ) for TEMORA,respectively, with 176Lu/177Hf ratios of ~0.00031, 0.000036,0.00083 and 0.00127. Zircons 91500 and CZ3 show narrower variations in 176Hf/177Hf and 176Lu/177Hf ratios than those of zircons CN92-1 and TEMORA, and thus are appropriate standards for the Hf isotope analysis.

  5. HF Interference, Procedures and Tools (Interferences HF, procedures et outils)

    Science.gov (United States)

    2007-06-01

    such sources. The existing HF background noise possibly may be increased via ground wave and/or sky wave propagation. Increase of the existing HF...télécommunications filaires à large bande. Les télécommunications via le réseau électrique courant, dites PowerLine Communications (PLT ou PLC) et diverses...cumulative de nombreuses sources de même type. Le bruit de fond HF existant risque d’être augmenté par propagation de l’onde terrestre et/ou aérienne

  6. Marburg Hemorrhagic Fever (Marburg HF)

    Science.gov (United States)

    ... CDC Cancel Submit Search The CDC Marburg hemorrhagic fever (Marburg HF) Note: Javascript is disabled or is ... first recognized in 1967, when outbreaks of hemorrhagic fever occurred simultaneously in laboratories in Marburg and Frankfurt, ...

  7. Bacterioplankton abundance and production and nanozooplankton abundance in Kenyan coastal waters (Western Indian Ocean)

    NARCIS (Netherlands)

    Goosen, N.K.; Van Rijswijk, P.; De Bie, M.J.M.; Peene, J.; Kromkamp, J.C.

    1997-01-01

    Bacterial abundance, [H-3]thymidine incorporation rate and heterotrophic nanoflagellate abundance were measured in the water column along transects perpendicular to the Kenyan coast (western Indian Ocean) during June-July (SE monsoon) and November-December (intermonsoon) 1992. Bacterial abundance wa

  8. Automated Composite Column Wrapping

    OpenAIRE

    ECT Team, Purdue

    2007-01-01

    The Automated Composite Column Wrapping is performed by a patented machine known as Robo-Wrapper. Currently there are three versions of the machine available for bridge retrofit work depending on the size of the columns being wrapped. Composite column retrofit jacket systems can be structurally just as effective as conventional steel jacketing in improving the seismic response characteristics of substandard reinforced concrete columns.

  9. Linear Trimeric Hafnium Clusters in Hf0.86(1I3

    Directory of Open Access Journals (Sweden)

    Jan Beekhuizen

    2011-05-01

    Full Text Available The reduction of hafnium tetraiodide, HfI4, with aluminum at 600 °C or 850 °C in the presence of a NaI flux resulted in black single crystals of Hf0.86(1I3. This composition corresponds well to the upper end of the non-stoichiometry range 0.89 ≤ x ≤ 1.00 previously reported for HfxI3. The crystal structure (a = 1250.3(2, c = 1999.6(3 pm, R-3m, Z = 18 is made up of hexagonal closest packed layers of iodide ions. One third of the octahedral holes would be filled as in TiI3 or ZrI3 if it were Hf1.00I3. In Hf0.86(1I3, one out of six octahedral holes along [001] are, however, only occupied by 16%. In contrast to TiI3-I and ZrI3, one striking structural feature is in the formation of linear hafnium trimers with identical Hf―Hf distances of 318.3(2 pm rather than the formation of dimers. These may be associated with Hf―Hf bonding although only 2.64 electrons are available for one Hf5.16I18 column.

  10. Modeling Stone Columns

    Directory of Open Access Journals (Sweden)

    Jorge Castro

    2017-07-01

    Full Text Available This paper reviews the main modeling techniques for stone columns, both ordinary stone columns and geosynthetic-encased stone columns. The paper tries to encompass the more recent advances and recommendations in the topic. Regarding the geometrical model, the main options are the “unit cell”, longitudinal gravel trenches in plane strain conditions, cylindrical rings of gravel in axial symmetry conditions, equivalent homogeneous soil with improved properties and three-dimensional models, either a full three-dimensional model or just a three-dimensional row or slice of columns. Some guidelines for obtaining these simplified geometrical models are provided and the particular case of groups of columns under footings is also analyzed. For the latter case, there is a column critical length that is around twice the footing width for non-encased columns in a homogeneous soft soil. In the literature, the column critical length is sometimes given as a function of the column length, which leads to some disparities in its value. Here it is shown that the column critical length mainly depends on the footing dimensions. Some other features related with column modeling are also briefly presented, such as the influence of column installation. Finally, some guidance and recommendations are provided on parameter selection for the study of stone columns.

  11. Modeling Stone Columns

    Science.gov (United States)

    2017-01-01

    This paper reviews the main modeling techniques for stone columns, both ordinary stone columns and geosynthetic-encased stone columns. The paper tries to encompass the more recent advances and recommendations in the topic. Regarding the geometrical model, the main options are the “unit cell”, longitudinal gravel trenches in plane strain conditions, cylindrical rings of gravel in axial symmetry conditions, equivalent homogeneous soil with improved properties and three-dimensional models, either a full three-dimensional model or just a three-dimensional row or slice of columns. Some guidelines for obtaining these simplified geometrical models are provided and the particular case of groups of columns under footings is also analyzed. For the latter case, there is a column critical length that is around twice the footing width for non-encased columns in a homogeneous soft soil. In the literature, the column critical length is sometimes given as a function of the column length, which leads to some disparities in its value. Here it is shown that the column critical length mainly depends on the footing dimensions. Some other features related with column modeling are also briefly presented, such as the influence of column installation. Finally, some guidance and recommendations are provided on parameter selection for the study of stone columns. PMID:28773146

  12. Distribution of p-process 174Hf in early solar system materials and the origin of nucleosynthetic Hf and W isotope anomalies in Ca-Al rich inclusions

    Science.gov (United States)

    Peters, Stefan T. M.; Münker, Carsten; Pfeifer, Markus; Elfers, Bo-Magnus; Sprung, Peter

    2017-02-01

    Some nuclides that were produced in supernovae are heterogeneously distributed between different meteoritic materials. In some cases these heterogeneities have been interpreted as the result of interaction between ejecta from a nearby supernova and the nascent solar system. Particularly in the case of the oldest objects that formed in the solar system - Ca-Al rich inclusions (CAIs) - this view is confirm the hypothesis that a nearby supernova event facilitated or even triggered solar system formation. We present Hf isotope data for bulk meteorites, terrestrial materials and CAIs, for the first time including the low-abundance isotope 174Hf (∼0.16%). This rare isotope was likely produced during explosive O/Ne shell burning in massive stars (i.e., the classical "p-process"), and therefore its abundance potentially provides a sensitive tracer for putative heterogeneities within the solar system that were introduced by supernova ejecta. For CAIs and one LL chondrite, also complementary W isotope data are reported for the same sample cuts. Once corrected for small neutron capture effects, different chondrite groups, eucrites, a silicate inclusion of a IAB iron meteorite, and terrestrial materials display homogeneous Hf isotope compositions including 174Hf. Hafnium-174 was thus uniformly distributed in the inner solar system when planetesimals formed at the system composition, and also variable r-process (or s-process) Hf and W contributions. Based on combined Hf and W isotope compositions, we show that CAIs sampled at least one component in which the proportion of r- and s-process derived Hf and W deviates from that of supernova ejecta. The Hf and W isotope anomalies in CAIs are therefore best explained by selective processing of presolar carrier phases prior to CAI formation, and not by a late injection of supernova materials. Likewise, other isotope anomalies in additional elements in CAIs relative to the bulk solar system may reflect the same process. The isotopic

  13. Column Liquid Chromatography.

    Science.gov (United States)

    Majors, Ronald E.; And Others

    1984-01-01

    Reviews literature covering developments of column liquid chromatography during 1982-83. Areas considered include: books and reviews; general theory; columns; instrumentation; detectors; automation and data handling; multidimensional chromatographic and column switching techniques; liquid-solid chromatography; normal bonded-phase, reversed-phase,…

  14. Environmentally friendly HF (DF) lasers

    Science.gov (United States)

    Apollonov, V. V.

    2016-08-01

    Dedicated to the 100th anniversary of the birth of Academician A M Prokhorov, this paper reviews the physics of self-sustained volume discharge without preionization—self-initiated volume discharge (SIVD)—in the working mixtures of non-chain hydrofluoride HF (deuterofluoride (DF)) lasers. The dynamics of SIVD in discharge gaps with different geometries is thoroughly described. The mechanisms for the restriction of current density in a diffuse channel in electric discharges in SF6 and SF6 based mixtures (which determines whether SIVD is possible) are proposed and analyzed using simple models. The most probable mechanisms are the electron impact dissociation of SF6 and other mixture components, electron-ion recombination and electron attachment to vibrationally excited SF6 molecules. Starting from a comparative analysis of the rate coefficients of these processes, it is shown that electron-ion recombination is capable of compensating for electron detachment from negative ions via electron impact. It is also established that SIVD is not only observed in SF6, but also in other strongly electronegative gases. The factors that determine the uniformity of the active medium in non-chain HF (DF) lasers are analyzed. Some special features of non-chain HF (DF) lasers with different apertures operating are carefully examined. Consideration is given to the problem of increasing the aperture and discharge volume of non-chain HF (DF) lasers. Based on our experimental results, the possibility of increasing the energy of such lasers to ~1 kJ and above is shown.

  15. Spiral multicapillary columns

    Science.gov (United States)

    Efimenko, A. P.; Naumenko, I. I.; Soboleva, V. K.

    2008-08-01

    It was shown in a theoretical study and confirmed by experiment that a spiral multicapillary column had maximum efficiency if the bunch of capillaries was additionally coiled around its longitudinal axis to produce an integral number of coils. This technique made it possible to manufacture gas-chromatographic columns with performance as high as 12 to 16 thousand theoretical plates. These columns can find various applications, especially if quick separation is required.

  16. A thirty second isomer in Hf-171

    NARCIS (Netherlands)

    Campbell, P; Billowes, J; Cochrane, ECA; Cooke, JL; Cooper, TG; Dendooven, P; Evans, DE; Grant, IS; Griffith, JAR; Honkanen, A; Huhta, M; Oinonen, M; Pearson, MR; Penttila, H; Persson, B.L.; Richardson, DS; Tungate, G; Wheeler, PD; Zybert, L; Aysto, J

    1997-01-01

    An isomer has been detected in Hf-171 with a half-life of T-1/2 = 29.5(9) s. The state was populated in the Yb-170(alpha,3n)Hf-171m reaction at a beam energy of E-alpha = 50 MeV in an on-line ion guide isotope separator. The isomeric Hf-17lm(+) beam was extracted from the ion guide, mass-analysed an

  17. The study of multilayers Fe/Hf and Ni/Hf by slow positron beam technique

    Science.gov (United States)

    Tashiro, Mutsumi; Nakajyo, Terunobu; Murashige, Yusuke; Koizumi, Tomoya; Kanazawa, Ikuzo; Komori, Fumio; Soe, We-Hyo; Yamamoto, Ryoichi; Ito, Yasuo

    1997-05-01

    The S-parameters versus the incident positron energy are measured in the Ni/Hf multilayer, thin Hf film, thin Fe film and the bilayer Fe/Hf. We have analyzed the change in vacancy-type defects in these multilayers and thin films with the deposition temperature in the MBE system.

  18. JCE Feature Columns

    Science.gov (United States)

    Holmes, Jon L.

    1999-05-01

    The Features area of JCE Online is now readily accessible through a single click from our home page. In the Features area each column is linked to its own home page. These column home pages also have links to them from the online Journal Table of Contents pages or from any article published as part of that feature column. Using these links you can easily find abstracts of additional articles that are related by topic. Of course, JCE Online+ subscribers are then just one click away from the entire article. Finding related articles is easy because each feature column "site" contains links to the online abstracts of all the articles that have appeared in the column. In addition, you can find the mission statement for the column and the email link to the column editor that I mentioned above. At the discretion of its editor, a feature column site may contain additional resources. As an example, the Chemical Information Instructor column edited by Arleen Somerville will have a periodically updated bibliography of resources for teaching and using chemical information. Due to the increase in the number of these resources available on the WWW, it only makes sense to publish this information online so that you can get to these resources with a simple click of the mouse. We expect that there will soon be additional information and resources at several other feature column sites. Following in the footsteps of the Chemical Information Instructor, up-to-date bibliographies and links to related online resources can be made available. We hope to extend the online component of our feature columns with moderated online discussion forums. If you have a suggestion for an online resource you would like to see included, let the feature editor or JCE Online (jceonline@chem.wisc.edu) know about it. JCE Internet Features JCE Internet also has several feature columns: Chemical Education Resource Shelf, Conceptual Questions and Challenge Problems, Equipment Buyers Guide, Hal's Picks, Mathcad

  19. Glass-silicon column

    Energy Technology Data Exchange (ETDEWEB)

    Yu, Conrad M.

    2003-12-30

    A glass-silicon column that can operate in temperature variations between room temperature and about 450.degree. C. The glass-silicon column includes large area glass, such as a thin Corning 7740 boron-silicate glass bonded to a silicon wafer, with an electrode embedded in or mounted on glass of the column, and with a self alignment silicon post/glass hole structure. The glass/silicon components are bonded, for example be anodic bonding. In one embodiment, the column includes two outer layers of silicon each bonded to an inner layer of glass, with an electrode imbedded between the layers of glass, and with at least one self alignment hole and post arrangement. The electrode functions as a column heater, and one glass/silicon component is provided with a number of flow channels adjacent the bonded surfaces.

  20. HF radiation emitted by chaotic leader processes

    Science.gov (United States)

    Mäkelä, J. S.; Edirisinghe, M.; Fernando, M.; Montaño, R.; Cooray, V.

    2007-04-01

    This paper presents direct measurements of narrowband 10 MHz HF radiation from so-called “chaotic leaders” associated with subsequent return strokes. Although the term is controversial and poorly defined, we find that more than 30% of subsequent strokes in close lightning flashes contain electric field characteristics that are best described as “chaotic”. In earlier studies, return strokes have consistently been observed to be the strongest sources of HF radiation, but the results for leader processes are less consistent. We also observe return strokes to be the main HF emitter, and the leaders before the first return stroke in a flash sequence also emit HF though somewhat less intensely. The leaders preceding subsequent strokes typically emit little or no HF radiation, whether they are dart or dart-stepped leaders. However, it was observed that the presence of a chaotic component increases the leader HF intensity dramatically Defining the HF intensity unequivocally can be problematic for processes like chaotic leaders which have a combination of continuous and impulsive phenomena. Two time-domain methods were used to measure the HF intensity, the peak energy and the RMS energy. In the frequency domain these correspond to the energy spectral density (ESD) and power spectral density (PSD), respectively. It was found that the methods are not necessarily compatible. Thus, it is suggested that to clarify future work, leader processes should be characterized by the PSD rather than the ESD.

  1. Mixing and melt sources in the Miocene Aztec Wash pluton (Nevada, USA) as revealed by zircon Hf and O and whole rock Sr, Nd, and Hf isotopes

    Science.gov (United States)

    Ryan, M.; Miller, J. S.; Miller, C. F.; Bromley, S.; Davies, G. R.; Schmitt, A. K.

    2011-12-01

    The 15.6 Ma Aztec Wash Pluton (AWP) is one of several Miocene intrusions located within the northern Colorado River extensional corridor. Extensive E-W tilting of fault blocks has exposed the pluton from the roof to 5 km structural depth. Earlier field and petrologic studies subdivided the AWP into two distinct zones: (1) a Granite Zone (GZ) comprised of relatively homogeneous granite with subtle differences in textures and mineralogy; (2) a Heterogeneous Zone (HZ), which interfingers the GZ, contains evidence for mafic and felsic magma input with a wide compositional range (42-78 wt% SiO2), and abundant field evidence for hybridization. Previous whole rock geochemistry and zircon trace element analyses indicated that compositional variation was produced by multi-component mixing between mafic and felsic melts within the HZ. New whole rock Sr, Nd, and Hf isotope data from the HZ show that all rocks (including high-silica granites) formed by mixing Precambrian crust and enriched mantle, with mixtures having a large mantle fraction (≥50%). New Hf (n=189) and O (n=241) isotope analyses of zircon from samples in the HZ confirm these melt sources and provide a broader perspective on hybridization processes within the AWP. Zircon grains from all samples show heterogeneous Hf and O isotopic compositions (-5 to -18 ɛHf; 4.5-7.5% δ18O), but despite the clear signature of Precambrian crust in the whole rock data, obvious Precambrian zircons (or cores) were mostly absent; only one zircon was clearly Precambrian (ɛHf = -25). Resolvable intragrain variability is relatively limited (including the Precambrian grain, which is unzoned). Zircons from hand samples and from compositional groups also show heterogeneous ɛHf and δ18O values, although the spreads are more restricted than in the whole data set (6-10 ɛHf in granites, 5-7 ɛHf in intermediate "hybrids", 5-6 ɛHf in gabbro/diorite sheets). Oxygen isotope values for the zircons also show intra-handsample heterogeneity

  2. STRATOSPHERIC HCL, HF, AND N_2O IN ANTARCTICA OBSERVED WITH SOLAR INFRARED ABSORPTION METHOD

    OpenAIRE

    ムラタ, イサオ; キタ, カズユキ; イワガミ, ナオモト; オガワ, トシヒロ; Isao, MURATA; Kazuyuki, KITA; Naomoto, IWAGAMI; Toshihiro, OGAWA

    1995-01-01

    Vertical column densities of HCl, HF, and N_2O were observed using solar infrared absorption technique at Syowa Station (69.006°S, 39.590°E), to study the chemistry and dynamics of Antarctic ozone depletion. The solar spectra were taken by using a 1.5m double-pass grating monochromator with wavenumber resolution of 0.075(cm)^-0.137(cm)^, and the measurements were carried out from July to December 1991. HCl vertical column densities were observed to be (1.65±0.43)×(10)^(cm)^ in winter and to i...

  3. Distillation Column Flooding Predictor

    Energy Technology Data Exchange (ETDEWEB)

    George E. Dzyacky

    2010-11-23

    The Flooding Predictor™ is a patented advanced control technology proven in research at the Separations Research Program, University of Texas at Austin, to increase distillation column throughput by over 6%, while also increasing energy efficiency by 10%. The research was conducted under a U. S. Department of Energy Cooperative Agreement awarded to George Dzyacky of 2ndpoint, LLC. The Flooding Predictor™ works by detecting the incipient flood point and controlling the column closer to its actual hydraulic limit than historical practices have allowed. Further, the technology uses existing column instrumentation, meaning no additional refining infrastructure is required. Refiners often push distillation columns to maximize throughput, improve separation, or simply to achieve day-to-day optimization. Attempting to achieve such operating objectives is a tricky undertaking that can result in flooding. Operators and advanced control strategies alike rely on the conventional use of delta-pressure instrumentation to approximate the column’s approach to flood. But column delta-pressure is more an inference of the column’s approach to flood than it is an actual measurement of it. As a consequence, delta pressure limits are established conservatively in order to operate in a regime where the column is never expected to flood. As a result, there is much “left on the table” when operating in such a regime, i.e. the capacity difference between controlling the column to an upper delta-pressure limit and controlling it to the actual hydraulic limit. The Flooding Predictor™, an innovative pattern recognition technology, controls columns at their actual hydraulic limit, which research shows leads to a throughput increase of over 6%. Controlling closer to the hydraulic limit also permits operation in a sweet spot of increased energy-efficiency. In this region of increased column loading, the Flooding Predictor is able to exploit the benefits of higher liquid

  4. Aspects of HF radio propagation

    Directory of Open Access Journals (Sweden)

    Stephane Saillant

    2009-06-01

    Full Text Available

    radio systems. From the point of view Working Group 2 of the COST 296 Action, interest lies with effects associated

    with propagation via the ionosphere of signals within the HF band. Several aspects are covered in this paper:

    a The directions of arrival and times of flight of signals received over a path oriented along the trough have

    been examined and several types of propagation effects identified. Of particular note, combining the HF observations

    with satellite measurements has identified the presence of irregularities within the floor of the trough that

    result in propagation displaced from the great circle direction. An understanding of the propagation effects that

    result in deviations of the signal path from the great circle direction are of particular relevance to the operation

    of HF radiolocation systems.

    b Inclusion of the results from the above mentioned measurements into a propagation model of the northerly

    ionosphere (i.e. those regions of the ionosphere located poleward of, and including, the mid-latitude trough

    and the use of this model to predict the coverage expected from transmitters where the signals impinge on the

    northerly ionosphere

  5. Subduction Controls of Hf and Nd Isotopes in Lavas of the Aleutian Island Arc

    Energy Technology Data Exchange (ETDEWEB)

    Yogodzinski, Gene; Vervoort, Jeffery; Brown, Shaun Tyler; Gerseny, Megan

    2010-08-29

    The Hf and Nd isotopic compositions of 71 Quaternary lavas collected from locations along the full length of the Aleutian island arc are used to constrain the sources of Aleutian magmas and to provide insight into the geochemical behavior of Nd and Hf and related elements in the Aleutian subduction-magmatic system. Isotopic compositions of Aleutian lavas fall approximately at the center of, and form a trend parallel to, the terrestrial Hf-Nd isotopic array with {var_epsilon}{sub Hf} of +12.0 to +15.5 and {var_epsilon}{sub Nd} of +6.5 to +10.5. Basalts, andesites, and dacites within volcanic centers or in nearby volcanoes generally all have similar isotopic compositions, indicating that there is little measurable effect of crustal or other lithospheric assimilation within the volcanic plumbing systems of Aleutian volcanoes. Hafnium isotopic compositions have a clear pattern of along-arc increase that is continuous from the eastern-most locations near Cold Bay to Piip Seamount in the western-most part of the arc. This pattern is interpreted to reflect a westward decrease in the subducted sediment component present in Aleutian lavas, reflecting progressively lower rates of subduction westward as well as decreasing availability of trench sediment. Binary bulk mixing models (sediment + peridotite) demonstrate that 1-2% of the Hf in Aleutian lavas is derived from subducted sediment, indicating that Hf is mobilized out of the subducted sediment with an efficiency that is similar to that of Sr, Pb and Nd. Low published solubility for Hf and Nd in aqueous subduction fluids lead us to conclude that these elements are mobilized out of the subducted component and transferred to the mantle wedge as bulk sediment or as a silicate melt. Neodymium isotopes also generally increase from east to west, but the pattern is absent in the eastern third of the arc, where the sediment flux is high and increases from east to west, due to the presence of abundant terrigenous sediment in the

  6. HERSCHEL OBSERVATIONS REVEAL ANOMALOUS MOLECULAR ABUNDANCES TOWARD THE GALACTIC CENTER

    Energy Technology Data Exchange (ETDEWEB)

    Sonnentrucker, P. [Space Telescope Science Institute, Baltimore, MD 21218 (United States); Neufeld, D. A.; Indriolo, N. [Physics and Astronomy Department, Johns Hopkins University, Baltimore, MD 21218 (United States); Gerin, M.; De Luca, M. [LERMA-LRA, UMR 8112 du CNRS, Observatoire de Paris, Ecole Normale Superieure, UPMC and UCP, 24 rue Lhomond, F-75231, Paris Cedex 05 (France); Lis, D. C. [Astronomy Department, California Institute of Technology, Pasadena, CA 91125 (United States); Goicoechea, J. R., E-mail: sonnentr@stsci.edu [Centro de Astrobiologia, CSIC/INTA, E-28850, Madrid (Spain)

    2013-01-20

    We report the Herschel detections of hydrogen fluoride (HF) and para-water (p-H{sub 2}O) in gas intercepting the sight lines to two well-studied molecular clouds in the vicinity of the Sgr A complex: G-0.02-0.07 (the {sup +}50 km s{sup -1} cloud{sup )} and G-0.13-0.08 (the {sup +}20 km s{sup -1} cloud{sup )}. Toward both sight lines, HF and water absorption components are detected over a wide range of velocities covering {approx}250 km s{sup -1}. For all velocity components with V{sub LSR} > -85 km s{sup -1}, we find that the HF and water abundances are consistent with those measured toward other sight lines probing the Galactic disk gas. The velocity components with V{sub LSR} {<=} -85 km s{sup -1}, which are known to trace gas residing within {approx}200 pc of the Galactic center, however, exhibit water vapor abundances with respect to HF at least a factor three higher than those found in the Galactic disk gas. Comparison with CH data indicates that our observations are consistent with a picture where HF and a fraction of the H{sub 2}O absorption arise in diffuse molecular clouds showing Galactic disk-like abundances while the bulk of the water absorption arises in warmer (T {>=} 400 K) diffuse molecular gas for V{sub LSR} {<=} -85 km s{sup -1}. This diffuse Interstellar Medium (ISM) phase has also been recently revealed through observations of CO, HF, H{sup +}{sub 3}, and H{sub 3}O{sup +} absorption toward other sight lines probing the Galactic center inner region.

  7. HF Transverse Segmentation and Tagging Jet Capability

    CERN Document Server

    Doroshkevich, E A; Kuleshov, Sergey

    1998-01-01

    So called tagging jets and pile-up were simulated for the optimisation of the HF segmentation. The energy resolution, angular resolution and efficiency of jet reconstruction are defined for different calorimeter segmentation.

  8. Collisional quenching of highly rotationally excited HF

    CERN Document Server

    Yang, Benhui; Forrey, R C; Stancil, P C; Balakrishnan, N

    2015-01-01

    Collisional excitation rate coefficients play an important role in the dynamics of energy transfer in the interstellar medium. In particular, accurate rotational excitation rates are needed to interpret microwave and infrared observations of the interstellar gas for nonlocal thermodynamic equilibrium line formation. Theoretical cross sections and rate coefficients for collisional deexcitation of rotationally excited HF in the vibrational ground state are reported. The quantum-mechanical close-coupling approach implemented in the nonreactive scattering code MOLSCAT was applied in the cross section and rate coefficient calculations on an accurate 2D HF-He potential energy surface. Estimates of rate coefficients for H and H$_2$ colliders were obtained from the HF-He collisional data with a reduced-potential scaling approach. The calculation of state-to-state rotational quenching cross sections for HF due to He with initial rotational levels up to $j=20$ were performed for kinetic energies from 10$^{-5}$ to 15000...

  9. Microhardness evaluation alloys Hf-Si-B; Avaliacao de microdureza de ligas Hf-Si-B

    Energy Technology Data Exchange (ETDEWEB)

    Gigolotti, Joao Carlos Janio; Costa, Eliane Fernandes Brasil [Centro Universitario de Volta Redonda (UNIFOA), Volta Redonda, RJ (Brazil); Nunes, Carlos Angelo; Rocha, Elisa Gombio; Coelho, Gilberto Carvalho, E-mail: carlosjanio@uol.com.br, E-mail: eliane-costabrasi@hotmail.com, E-mail: cnunes@demar.eel.usp.br, E-mail: elisarocha@alunos.eel.usp.br, E-mail: coelho@demar.eel.usp.br [Universidade de Sao Paulo (USP), Lorena, SP (Brazil)

    2014-08-15

    The technological advance has generated increasing demand for materials that can be used under high temperature, what includes intermetallic MR-Si-B (MR = refractory metal) alloys with multiphase structures, that can also be applied in oxide environments. Thus, this work had for objective the micro hardness study of the Hf-Si-B system alloys, heat treated at 1600 deg C, in the Hf rich region. Hf-Si-B alloys had been produced with blades of Hf (min. 99.8%), Si (min. 99.998%) and B (min. 99.5%), in the voltaic arc furnace and heat treated at 1600 deg C under argon atmosphere. The relationship of the phases had been previously identified by X-ray diffraction and contrast in backscattered electron imaging mode. The alloys had their hardness analyzed by method Vickers (micro hardness) with load of 0.05 kgf and 0.2 kgf and application time of 20 s. The results, obtained from the arithmetic mean of measurements for each alloy on the heterogeneous region, showed a mean hardness of 11.08 GPA, with small coefficient of variation of 3.8%. The borides HfB2 (19.34 GPa) e HfB - 11.76 GPa, showed the hardness higher than the silicides Hf2Si (8.57 GPa), Hf5Si3 (9.63 GPa), Hf3Si2 (11.66 GPa), Hf5Si4 (10.00 GPa), HfSi (10.02 GPa) e HfSi2 (8.61 GPa). (author)

  10. Eruption column physics

    Energy Technology Data Exchange (ETDEWEB)

    Valentine, G.A.

    1997-03-01

    In this paper the author focuses on the fluid dynamics of large-scale eruption columns. The dynamics of these columns are rooted in multiphase flow phenomena, so a major part of the paper sets up a foundation on that topic that allows one to quickly assess the inherent assumptions made in various theoretical and experimental approaches. The first part is centered on a set of complex differential equations that describe eruption columns, but the focus is on a general understanding of important physical processes rather than on the mathematics. The author discusses briefly the relative merits and weaknesses of different approaches, emphasizing that the largest advances in understanding are made by combining them. He then focuses on dynamics of steady eruption columns and then on transient phenomena. Finally he briefly reviews the effects of varying behavior of the ambient medium through which an eruption column moves. These final sections will emphasize concepts and a qualitative understanding of eruption dynamics. This paper relies on principles of continuum mechanics and transport processes but does not go into detail on the development of those principles. 36 refs., 36 figs., 3 tabs.

  11. VizieR Online Data Catalog: Line list for abundance determination in Sun siblings (Liu+, 2015)

    Science.gov (United States)

    Liu, C.; Ruchti, G.; Feltzing, S.; Martinez-Barbosa, A. C.; Bensby, T.; Brown, G. A. A.; Portegies Zwart, F. S.

    2015-01-01

    On table 2 we list all spectral lines that have been used to determine elemental abundances. Columns 1 gives the element with a degree of ionization. The wavelength, excitation potential and adopted loggf values are listed in the Columns 2, 3, and 4, respectively. References to the adopted log gf values are given in Column 5. (2 data files).

  12. Columns in Clay

    Science.gov (United States)

    Leenhouts, Robin

    2010-01-01

    This article describes a clay project for students studying Greece and Rome. It provides a wonderful way to learn slab construction techniques by making small clay column capitols. With this lesson, students learn architectural vocabulary and history, understand the importance of classical architectural forms and their influence on today's…

  13. Slender CRC Columns

    DEFF Research Database (Denmark)

    Aarup, Bendt; Jensen, Lars Rom; Ellegaard, Peter

    2005-01-01

    CRC is a high-performance steel fibre reinforced concrete with a typical compressive strength of 150 MPa. Design methods for a number of structural elements have been developed since CRC was invented in 1986, but the current project set out to further investigate the range of columns for which...

  14. Raccoon abundance inventory report

    Data.gov (United States)

    US Fish and Wildlife Service, Department of the Interior — This report summarizes the results of a raccoon abundance inventory on Clarence Cannon National Wildlife Refuge in 2012. Determining raccoon abundance allows for...

  15. Abundances and Depletions of Interstellar Oxygen

    Science.gov (United States)

    Jensen, A. G.; Rachford, B. L.; Snow, T. P.

    2003-12-01

    We extend previous work on interstellar oxygen abundances with the addition of data from the Far Ultraviolet Spectroscopic Explorer (FUSE). We report on the abundance of interstellar neutral oxygen (OI) for several sightlines, using data from FUSE, the International Spectroscopic Explorer (IUE), and the Hubble Space Telescope (HST). OI column densities are derived by measuring the equivalent widths of several ultraviolet absorption lines, and subsequently fitting those to a curve of growth. The column densities of our best-constrained sightlines show a ratio of O/H that agrees with the current best solar value if dust is considered. We do not see evidence of enhanced depletion of gas-phase oxygen that is systematically variable with respect to the physical parameters of different environments (e.g., reddening or molecular fraction). The column densities of our less well-constrained sightlines show some scatter in O/H, but many agree with the solar value to within errors. We discuss these results in the context of deriving the best methods for determining interstellar abundances, the unresolved question of the best value for O/H in the interstellar medium (ISM), the O/H ratio observed in Galactic stars, and the depletion of gas-phase oxygen onto dust grains. Financial support for this research has been provided by the National Science Foundation GK-12 Program and NASA contract NAS 5-32985.

  16. Slurry bubble column hydrodynamics

    Science.gov (United States)

    Rados, Novica

    Slurry bubble column reactors are presently used for a wide range of reactions in both chemical and biochemical industry. The successful design and scale up of slurry bubble column reactors require a complete understanding of multiphase fluid dynamics, i.e. phase mixing, heat and mass transport characteristics. The primary objective of this thesis is to improve presently limited understanding of the gas-liquid-solid slurry bubble column hydrodynamics. The effect of superficial gas velocity (8 to 45 cm/s), pressure (0.1 to 1.0 MPa) and solids loading (20 and 35 wt.%) on the time-averaged solids velocity and turbulent parameter profiles has been studied using Computer Automated Radioactive Particle Tracking (CARPT). To accomplish this, CARPT technique has been significantly improved for the measurements in highly attenuating systems, such as high pressure, high solids loading stainless steel slurry bubble column. At a similar set of operational conditions time-averaged gas and solids holdup profiles have been evaluated using the developed Computed Tomography (CT)/Overall gas holdup procedure. This procedure is based on the combination of the CT scans and the overall gas holdup measurements. The procedure assumes constant solids loading in the radial direction and axially invariant cross-sectionally averaged gas holdup. The obtained experimental holdup, velocity and turbulent parameters data are correlated and compared with the existing low superficial gas velocities and atmospheric pressure CARPT/CT gas-liquid and gas-liquid-solid slurry data. The obtained solids axial velocity radial profiles are compared with the predictions of the one dimensional (1-D) liquid/slurry recirculation phenomenological model. The obtained solids loading axial profiles are compared with the predictions of the Sedimentation and Dispersion Model (SDM). The overall gas holdup values, gas holdup radial profiles, solids loading axial profiles, solids axial velocity radial profiles and solids

  17. General concepts of modern HF communications

    Science.gov (United States)

    Aarons, Jules

    Both conceptual and hardware advancements have led to substantial systems developments in military HF communications; the former encompass coding and error correction techniques for security, in order to minimize propagation and interference, while the latter prominently include digital equipment permitting the selection of a frequency for a particular path and propagation mode, as well as modulation selection. Propagation-related advancements involve better statistical models as well as advancements in short-term forecasting methods responsive to changes in solar-geophysical parameters. Adaptive HF systems have been developed for meteor-scatter radio communications.

  18. Research on Multi-Layer Distributed HF Radio Network Structure

    Institute of Scientific and Technical Information of China (English)

    Hui Dai; Chun-Jiang Wang; Quan Yu

    2008-01-01

    High frequency (HF) transmission is an important communication techniques. However, conventional point-to-point transmission can be easily destroyed, which limits its utilization in practice. HF networking communication has the capability against demolishment. The network structure is one of the key factors for HF networking communication. In this paper, a novel analysis method of the network connectedness based on the eigenvalue is derived, and a multi-layer distributed HF radio network structure is proposed. Both the theore tical analysis and the computer simulation results verify that the application of the proposed network structure in the HF radio communication can improve the anti demolishment ability of the HF network efficiently.

  19. Behavior of Columns During Earthquakes

    Data.gov (United States)

    National Oceanic and Atmospheric Administration, Department of Commerce — The behavior of columns during earthquakes is very important since column failures may lead to additional structural failures and result in total building collapses....

  20. Determination of Two Columns Performance

    Institute of Scientific and Technical Information of China (English)

    2011-01-01

    When protein is analyzed by high performance liquid chromatography (HPLC), the selection of column is one of the most important factors. There are four quality control parameters for the column, which are theoretical plates n, capacity facto

  1. NMFS Water Column Sonar Database

    Data.gov (United States)

    National Oceanic and Atmospheric Administration, Department of Commerce — Water column sonar data are an important component of fishery independent surveys, habitat studies and other research. NMFS water column sonar data are archived here.

  2. The Origin of Fluorine: Abundances in AGB Carbon Stars Revisited

    CERN Document Server

    Abia, C; Cristallo, S; de Laverny, P

    2015-01-01

    Revised spectroscopic parameters for the HF molecule and a new CN line list in the 2.3 mu region have been recently available, allowing a revision of the F content in AGB stars. AGB carbon stars are the only observationally confirmed sources of fluorine. Nowadays there is not a consensus on the relevance of AGB stars in its Galactic chemical evolution. The aim of this article is to better constrain the contribution of these stars with a more accurate estimate of their fluorine abundances. Using new spectroscopic tools and LTE spectral synthesis, we redetermine fluorine abundances from several HF lines in the K-band in a sample of Galactic and extragalactic AGB carbon stars of spectral types N, J and SC spanning a wide range of metallicities. On average, the new derived fluorine abundances are systematically lower by 0.33 dex with respect to previous determinations. This may derive from a combination of the lower excitation energies of the HF lines and the larger macroturbulence parameters used here as well as...

  3. Precision Chemical Abundance Measurements

    DEFF Research Database (Denmark)

    Yong, David; Grundahl, Frank; Meléndez, Jorge;

    2012-01-01

    This talk covers preliminary work in which we apply a strictly differential line-by-line chemical abundance analysis to high quality UVES spectra of the globular cluster NGC 6752. We achieve extremely high precision in the measurement of relative abundance ratios. Our results indicate that the ob......This talk covers preliminary work in which we apply a strictly differential line-by-line chemical abundance analysis to high quality UVES spectra of the globular cluster NGC 6752. We achieve extremely high precision in the measurement of relative abundance ratios. Our results indicate...... that the observed abundance dispersion exceeds the measurement uncertainties and that many pairs of elements show significant correlations when plotting [X1/H] vs. [X2/H]. Our tentative conclusions are that either NGC 6752 is not chemically homogeneous at the ~=0.03 dex level or the abundance variations...

  4. Systematic Comparison of HF CMOS Transconductors

    NARCIS (Netherlands)

    Klumperink, Eric A.M.; Nauta, Bram

    2003-01-01

    Transconductors are commonly used as active elements in high-frequency (HF) filters, amplifiers, mixers, and oscillators. This paper reviews transconductor design by focusing on the V-I kernel that determines the key transconductor properties. Based on bandwidth considerations, simple V-I kernels wi

  5. Electron impact on vibrationally cold {{HF}}^{+}

    Science.gov (United States)

    Cristian Stroe, Marius; Fifirig, Magda

    2016-12-01

    The dissociative recombination and vibrational excitation processes induced by electron impact on vibrationally cold {{HF}}+ are investigated in the framework of the multichannel quantum defect theory for electron energies below 1 eV. The thermal rate coefficients for the electron temperature range from 10 to 5000 K are reported.

  6. ORIGIN OF EXCESS (176)Hf IN METEORITES

    DEFF Research Database (Denmark)

    Thrane, Kristine; Connelly, James Norman; Bizzarro, Martin

    2010-01-01

    After considerable controversy regarding the (176)Lu decay constant (lambda(176)Lu), there is now widespread agreement that (1.867 +/- 0.008) x 10(-11) yr(-1) as confirmed by various terrestrial objects and a 4557 Myr meteorite is correct. This leaves the (176)Hf excesses that are correlated with...

  7. Column: Every Last Byte

    Directory of Open Access Journals (Sweden)

    Simson Garfinkel

    2011-06-01

    Full Text Available Inheritance powder is the name that was given to poisons, especially arsenic, that were commonly used in the 17th and early 18th centuries to hasten the death of the elderly. For most of the 17th century, arsenic was deadly but undetectable, making it nearly impossible to prove that someone had been poisoned. The first arsenic test produced a gas—hardly something that a scientist could show to a judge. Faced with a growing epidemic of poisonings, doctors and chemists spent decades searching for something better.(see PDF for full column

  8. HIFI detection of HF in the carbon star envelope IRC +10216

    CERN Document Server

    Agundez, M; Waters, L B F M; Decin, L; Encrenaz, P; Neufeld, D; Teyssier, D; Daniel, F

    2011-01-01

    We report the detection of emission in the J=1-0 rotational transition of hydrogen fluoride (HF), together with observations of the J=1-0 to J=3-2 rotational lines of H35Cl and H37Cl, towards the envelope of the carbon star IRC +10216. High-sensitivity, high-spectral resolution observations have been carried out with the HIFI instrument on board Herschel, allowing us to resolve the line profiles and providing insights into the spatial distribution of the emission. Our interpretation of the observations, with the use of radiative transfer calculations, indicates that both HF and HCl are formed in the inner regions of the envelope close to the AGB star. Thermochemical equilibrium calculations predict HF and HCl to be the major reservoirs of fluorine and chlorine in the atmospheres of AGB stars. The abundances relative to H2 derived for HF and HCl, 8e-9 and 1e-7 respectively, are substantially lower than those predicted by thermochemical equilibrium, indicating that F and Cl are likely affected by significant de...

  9. Calibration of TCCON column-averaged CO2 : the first aircraft campaign over European TCCON sites

    NARCIS (Netherlands)

    Messerschmidt, J.; Geibel, M. C.; Blumenstock, T.; Chen, H.; Deutscher, N. M.; Engel, A.; Feist, D. G.; Gerbig, C.; Gisi, M.; Hase, F.; Katrynski, K.; Kolle, O.; Lavric, J. V.; Notholt, J.; Palm, M.; Ramonet, M.; Rettinger, M.; Schmidt, M.; Sussmann, R.; Toon, G. C.; Truong, F.; Warneke, T.; Wennberg, P. O.; Wunch, D.; Xueref-Remy, I.

    2011-01-01

    The Total Carbon Column Observing Network (TCCON) is a ground-based network of Fourier Transform Spectrometer (FTS) sites around the globe, where the column abundances of CO2, CH4, N2O, CO and O-2 are measured. CO2 is constrained with a precision better than 0.25% (1-sigma). To achieve a similarly h

  10. Why Hexagonal Basalt Columns?

    Science.gov (United States)

    Hofmann, Martin; Anderssohn, Robert; Bahr, Hans-Achim; Weiß, Hans-Jürgen; Nellesen, Jens

    2015-10-09

    Basalt columns with their preferably hexagonal cross sections are a fascinating example of pattern formation by crack propagation. Junctions of three propagating crack faces rearrange such that the initial right angles between them tend to approach 120°, which enables the cracks to form a pattern of regular hexagons. To promote understanding of the path on which the ideal configuration can be reached, two periodically repeatable models are presented here involving linear elastic fracture mechanics and applying the principle of maximum energy release rate. They describe the evolution of the crack pattern as a transition from rectangular start configuration to the hexagonal pattern. This is done analytically and by means of three-dimensional finite element simulation. The latter technique reproduces the curved crack path involved in this transition.

  11. Column: File Cabinet Forensics

    Directory of Open Access Journals (Sweden)

    Simson Garfinkel

    2011-12-01

    Full Text Available Researchers can spend their time reverse engineering, performing reverse analysis, or making substantive contributions to digital forensics science. Although work in all of these areas is important, it is the scientific breakthroughs that are the most critical for addressing the challenges that we face.Reverse Engineering is the traditional bread-and-butter of digital forensics research. Companies like Microsoft and Apple deliver computational artifacts (operating systems, applications and phones to the commercial market. These artifacts are bought and used by billions. Some have evil intent, and (if society is lucky, the computers end up in the hands of law enforcement. Unfortunately the original vendors rarely provide digital forensics tools that make their systems amenable to analysis by law enforcement. Hence the need for reverse engineering.(see PDF for full column

  12. European Analytical Column

    DEFF Research Database (Denmark)

    Karlberg, B.; Grasserbauer, M.; Andersen, Jens Enevold Thaulov

    2009-01-01

    The European Analytical Column has once more invited a guest columnist to give his views on various matters related to analytical chemistry in Europe. This year, we have invited Professor Manfred Grasserbauer of the Vienna University of Technology to present some of the current challenges...... for European analytical chemistry. During the period 2002–07, Professor Grasserbauer was Director of the Institute for Environment and Sustainability, Joint Research Centre of the European Commission (EC), Ispra, Italy. There is no doubt that many challenges exist at the present time for all of us representing...... a major branch of chemistry, namely analytical chemistry. The global financial crisis is affecting all branches of chemistry, but analytical chemistry, in particular, since our discipline by tradition has many close links to industry. We have already noticed decreased industrial commitment with respect...

  13. SPIRAL CONTACTOR FOR SOLVENT EXTRACTION COLUMN

    Science.gov (United States)

    Cooley, C.R.

    1961-06-13

    The patented extraction apparatus includes a column, perforated plates extending across the column, liquid pulse means connected to the column, and an imperforate spiral ribbon along the length of the column.

  14. REMPI Spectroscopy of HfF

    CERN Document Server

    Loh, Huanqian; Yahn, Tyler S; Looser, Herbert; Field, Robert W; Cornell, Eric A

    2012-01-01

    The spectrum of electronic states at 30000--33000 cm$^{-1}$ in hafnium fluoride has been studied using (1+1) resonance-enhanced multi-photon ionization (REMPI) and (1+1$'$) REMPI. Six $\\Omega' = 3/2$ and ten $\\Pi_{1/2}$ vibronic bands have been characterized. We report the molecular constants for these bands and estimate the electronic energies of the excited states using a correction derived from the observed isotope shifts. When either of two closely spaced $\\Pi_{1/2}$ electronic states is used as an intermediate state to access autoionizing Rydberg levels, qualitatively distinct autoionization spectra are observed. The intermediate state-specificity of the autoionization spectra bodes well for the possibility of using a selected $\\Pi_{1/2}$ state as an intermediate state to create ionic HfF$^+$ in various selected quantum states, an important requirement for our electron electric dipole moment (eEDM) search in HfF$^+$.

  15. Digitally Driven Antenna for HF Transmission

    Science.gov (United States)

    2010-09-01

    the 1-MHz carrier signal. This signal is then fed into the base terminals of an NPN/ PNP transistor pair arranged in a push–pull configura- tion. A dual...negative voltage connected to the collector terminal of the PNP transistor . Since it was not possible to explicitly simulate the radia- tion of the time...complementary pair of switching transistors is driven with a pulsewidth modulated HF signal, eliminating the requirement for a frequency-dependent

  16. RFID UHF i HF w bibliotekach

    Directory of Open Access Journals (Sweden)

    Gładysz Bartłomiej

    2015-06-01

    Full Text Available The potential of the innovative Radio Frequency Identification (RFID technology to be applied for support, acceleration and automation of the circulation process of library collection is presented. Technology basics, and hardware and software components are described. Two different radio standards used in libraries are compared. The goal is to present the potential of RFID technology for libraries, to highlight the differences and to build a basis for further consideration of UHF and HF alternatives.

  17. Compact electron beam focusing column

    Energy Technology Data Exchange (ETDEWEB)

    Persaud, Arun; Leung, Ka-Ngo; Reijonen, Jani

    2001-07-13

    A novel design for an electron beam focusing column has been developed at LBNL. The design is based on a low-energy spread multicusp plasma source which is used as a cathode for electron beam production. The focusing column is 10 mm in length. The electron beam is focused by means of electrostatic fields. The column is designed for a maximum voltage of 50 kV. Simulations of the electron trajectories have been performed by using the 2-D simulation code IGUN and EGUN. The electron temperature has also been incorporated into the simulations. The electron beam simulations, column design and fabrication will be discussed in this presentation.

  18. Multipath Separation-Direction of Arrival (MS-DOA) with Genetic Search Algorithm for HF channels

    Science.gov (United States)

    Arikan, Feza; Koroglu, Ozan; Fidan, Serdar; Arikan, Orhan; Guldogan, Mehmet B.

    2009-09-01

    Direction-of-Arrival (DOA) defines the estimation of arrival angles of an electromagnetic wave impinging on a set of sensors. For dispersive and time-varying HF channels, where the propagating wave also suffers from the multipath phenomena, estimation of DOA is a very challenging problem. Multipath Separation-Direction of Arrival (MS-DOA), that is developed to estimate both the arrival angles in elevation and azimuth and the incoming signals at the output of the reference antenna with very high accuracy, proves itself as a strong alternative in DOA estimation for HF channels. In MS-DOA, a linear system of equations is formed using the coefficients of the basis vector for the array output vector, the incoming signal vector and the array manifold. The angles of arrival in elevation and azimuth are obtained as the maximizers of the sum of the magnitude squares of the projection of the signal coefficients on the column space of the array manifold. In this study, alternative Genetic Search Algorithms (GA) for the maximizers of the projection sum are investigated using simulated and experimental ionospheric channel data. It is observed that GA combined with MS-DOA is a powerful alternative in online DOA estimation and can be further developed according to the channel characteristics of a specific HF link.

  19. OXYGEN ABUNDANCES IN CEPHEIDS

    Energy Technology Data Exchange (ETDEWEB)

    Luck, R. E.; Andrievsky, S. M. [Department of Astronomy, Case Western Reserve University, 10900 Euclid Avenue, Cleveland, OH 44106-7215 (United States); Korotin, S. N.; Kovtyukh, V. V., E-mail: luck@fafnir.astr.cwru.edu, E-mail: serkor@skyline.od.ua, E-mail: val@deneb1.odessa.ua, E-mail: scan@deneb1.odessa.ua [Department of Astronomy and Astronomical Observatory, Odessa National University, Isaac Newton Institute of Chile, Odessa Branch, Shevchenko Park, 65014 Odessa (Ukraine)

    2013-07-01

    Oxygen abundances in later-type stars, and intermediate-mass stars in particular, are usually determined from the [O I] line at 630.0 nm, and to a lesser extent, from the O I triplet at 615.7 nm. The near-IR triplets at 777.4 nm and 844.6 nm are strong in these stars and generally do not suffer from severe blending with other species. However, these latter two triplets suffer from strong non-local thermodynamic equilibrium (NLTE) effects and thus see limited use in abundance analyses. In this paper, we derive oxygen abundances in a large sample of Cepheids using the near-IR triplets from an NLTE analysis, and compare those abundances to values derived from a local thermodynamic equilibrium (LTE) analysis of the [O I] 630.0 nm line and the O I 615.7 nm triplet as well as LTE abundances for the 777.4 nm triplet. All of these lines suffer from line strength problems making them sensitive to either measurement complications (weak lines) or to line saturation difficulties (strong lines). Upon this realization, the LTE results for the [O I] lines and the O I 615.7 nm triplet are in adequate agreement with the abundance from the NLTE analysis of the near-IR triplets.

  20. Investigating an Inverted Soil Column in Northern Tanzania: Could Intense Groundwater Weathering be the Culprit?

    Science.gov (United States)

    Little, M. G.; Lee, C. A.

    2004-12-01

    Weathering of silicate rocks permanently sequesters a significant amount CO2 on our planet (Berner et al., 1983; Dessert et al., 2003; Gaillardet et al., 1999). Therefore, the investigation of soils and their conjugate protoliths have implications for a wide range of disciplines from soil to atmospheric sciences. This study investigates soil formed in Northern Tanzania on the southern slope of the dormant volcano Mt. Kilimanjaro. Our sample site is in the Machame region at an elevation of ~1640 m where the phonotephrite to basaltic bedrock has been dated at 0.4 to 0.5 million years (Evernden and Curtis, 1965). We determined bulk elemental concentrations of soil and bedrock samples from this region using an ICP-MS and XRF. From initial investigations into the bulk soil and bedrock chemistry using a novel mass balance method, we were able to investigate the relative mobility of a suite of elements. Relative abundances of Ta, Nb, Hf, and Zr are constant and therefore these elements are immobile. In contrast, Ti, an element commonly thought to be immobile, is clearly not immobile in our samples. The entire soil column appears to be highly depleted in Si and Ca but enriched in Al. These features indicate extensive weathering and indeed some samples approach bauxite compositions. Surprisingly, however, weathering versus depth is reversed. Si and Ca have been removed by 60 and 70 % respectively from the upper 2 meters, but below 2 m, they have been removed by 95 and 99 %. This means that the soil is more weathered at depth than in the shallowest 2 meters. We believe that ground water weathering is responsible for this inverted soil profile and may increase CO2 consumption estimates by 10-30 % for similarly affected basalts.

  1. Abundance of thraustochytridsand bacteria in the equatorial Indian Ocean, in relation totransparent exopolymeric particles (TEPs)

    Digital Repository Service at National Institute of Oceanography (India)

    Damare, V.; Raghukumar, S.

    as abundance, suggested that they were particle dependent. Raghukumar et al. (2001) had earlier noticed dense populations of thraustochytrids in association with diatom mucus particles in the water column at the end of the southwest monsoon in the Arabian Sea...

  2. Practical design of stepped columns

    NARCIS (Netherlands)

    Girao Coelho, A.M.; Simao, P.D.; Bijlaard, F.S.K.

    2012-01-01

    This paper deals with buckling aspects of the design of stepped columns in heavy mill buildings. In these structures, columns have to carry significant axial loads that usually act eccentrically and strength reducing bending moments due to lateral loads. A simple physical model for buckling behaviou

  3. An Undergraduate Column Chromatography Experiment.

    Science.gov (United States)

    Danot, M.; And Others

    1984-01-01

    Background information, list of materials needed, and procedures used are provided for an experiment designed to introduce undergraduate students to the theoretical and technical aspects of column chromatography. The experiment can also be shortened to serve as a demonstration of the column chromatography technique. (JN)

  4. Mush Column Magma Chambers

    Science.gov (United States)

    Marsh, B. D.

    2002-12-01

    Magma chambers are a necessary concept in understanding the chemical and physical evolution of magma. The concept may well be similar to a transfer function in circuit or time series analysis. It does what needs to be done to transform source magma into eruptible magma. In gravity and geodetic interpretations the causative body is (usually of necessity) geometrically simple and of limited vertical extent; it is clearly difficult to `see' through the uppermost manifestation of the concentrated magma. The presence of plutons in the upper crust has reinforced the view that magma chambers are large pots of magma, but as in the physical representation of a transfer function, actual magma chambers are clearly distinct from virtual magma chambers. Two key features to understanding magmatic systems are that they are vertically integrated over large distances (e.g., 30-100 km), and that all local magmatic processes are controlled by solidification fronts. Heat transfer considerations show that any viable volcanic system must be supported by a vertically extensive plumbing system. Field and geophysical studies point to a common theme of an interconnected stack of sill-like structures extending to great depth. This is a magmatic Mush Column. The large-scale (10s of km) structure resembles the vertical structure inferred at large volcanic centers like Hawaii (e.g., Ryan et al.), and the fine scale (10s to 100s of m) structure is exemplified by ophiolites and deeply eroded sill complexes like the Ferrar dolerites of the McMurdo Dry Valleys, Antarctica. The local length scales of the sill reservoirs and interconnecting conduits produce a rich spectrum of crystallization environments with distinct solidification time scales. Extensive horizontal and vertical mushy walls provide conditions conducive to specific processes of differentiation from solidification front instability to sidewall porous flow and wall rock slumping. The size, strength, and time series of eruptive behavior

  5. New Rare Earth Element Abundance Distributions for the Sun and Five r-Process-Rich Very Metal-Poor Stars

    CERN Document Server

    Sneden, Christopher; Cowan, John J; Ivans, Inese I; Hartog, Elizabeth A Den

    2009-01-01

    We have derived new abundances of the rare-earth elements Pr, Dy, Tm, Yb, and Lu for the solar photosphere and for five very metal-poor, neutron-capture r-process-rich giant stars. The photospheric values for all five elements are in good agreement with meteoritic abundances. For the low metallicity sample, these abundances have been combined with new Ce abundances from a companion paper, and reconsideration of a few other elements in individual stars, to produce internally-consistent Ba, rare-earth, and Hf (56<= Z <= 72) element distributions. These have been used in a critical comparison between stellar and solar r-process abundance mixes.

  6. Improvements on Signal Processing for HF Radar

    Institute of Scientific and Technical Information of China (English)

    LIU Yongtan; SHEN Yiying

    2001-01-01

    In this paper improvements on signalprocessing are achieved to enhance the performancesof H-F radar system, being unobtainable by the con-ventional signal processing. Using the improved sig-nal processing both high range resolution and longcoherent integration time may be obtained for goodbenefit to the target resolution and weak signal de-tection. Modification to the unmatched correspon-dence between range delay samples and range resolu-tion ceils saves an additional accumulation loss in therange processing. Finally, comparisons between theimproved and the conventional signal processing aregiven by numerical simulation.

  7. Abundance of atomic carbon /C I/ in dense interstellar clouds

    Science.gov (United States)

    Phillips, T. G.; Huggins, P. J.

    1981-01-01

    The abundance of interstellar neutral atomic carbon is investigated by means of its ground state fine-structure line emission at 492 GHz using the 91.5 cm telescope of NASAs Kuiper Airborne Observatory. Atomic carbon is found to be very abundant in dense interstellar molecular clouds with column densities of about 10 to the 19th per sq cm. Because the observations have considerably greater column densities than current theories of carbon chemistry, it is suggested that the physical conditions of these clouds are not as simple as assumed in the models. Various situations are discussed which would lead to large C I abundances, including the possibility that the chemical lifetimes of the clouds are relatively short.

  8. Systematic Study on Triaxial Superdeformed Bands of Hf Isotopes

    Institute of Scientific and Technical Information of China (English)

    ZHANG Da-Li; DING Bin-Gang

    2009-01-01

    Properties of the triaxial superdeformed (TSD) bands of Hf isotopes are investigated systematically within the supersymmetry scheme including many-body interactions and a perturbation possessing the SO(5) (or SU(5)) symmetry on the rotational symmetry. Quantitatively good results of the γ-ray energies, the dynamical moments of inertia,and the spin of the TSD bands in Hf isotopes are obtained. It shows that this approach is quite powerful in describing the properties of the triaxial superdeformation in Hf isotopes.

  9. Determining Energy Distributions of HF-Accelerated Electrons at HAARP

    Science.gov (United States)

    2015-11-18

    AFRL-AFOSR-VA-TR-2015-0383 Determining energy distributions of HF-accelerated electrons at HAARP Christopher Fallen University of Alaska Fairbanks...2012 - 11/14/2015 4. TITLE AND SUBTITLE Determining energy distributions of HF-accelerated electrons at HAARP 5a. CONTRACT NUMBER FA9550-12-1-0424...transmitted from the High-frequency Active Auroral Research Program ( HAARP ) transmitter in Alaska. For a given fixed HF-plasma interaction altitude

  10. Physics of the Geospace Response to Powerful HF Radio Waves

    Science.gov (United States)

    2012-10-31

    studies of the response of the Earth’s space plasma to high-power HF radio waves from the High-frequency Active Auroral Research Program ( HAARP ...of HF heating and explored to simulate artificial ducts. DMSP- HAARP experiments revealed that HF-created ion outflows and artificial density ducts...in the topside ionosphere appeared faster than predicted by the models, pointing to kinetic (suprathermal) effects. CHAMP/GRACE- HAARP experiments

  11. Deuterium abundance and cosmology

    CERN Document Server

    Vidal-Madjar, A; Lemoine, M

    1996-01-01

    We review the status of the measurements of the deuterium abundance from the local interstellar medium to the solar system and high redshifts absorbers toward quasars. We present preliminary results toward a white dwarf and a QSO. We conclude that the deuterium evolution from the Big-Bang to now is still not properly understood.

  12. PEMISAHAN Zr – Hf SECARA SINAMBUNG MENGGUNAKAN MIXER SETTLER

    Directory of Open Access Journals (Sweden)

    Dwi Biyantoro

    2017-01-01

    Full Text Available ABSTRAK PEMISAHAN Zr – Hf SECARA SINAMBUNG MENGGUNAKANMIXER SETTLER. Telah dilakukan pemisahanZr – Hf secara sinambung menggunakan pengaduk pengenap (mixer settler 16 stage. Larutan umpan adalah zirkon nitrat dengan kadar Zr = 30786 ppm dan Hf = 499 ppm. Ekstraktan dipakai adalah solven 60 % TBP dalam kerosen dan larutan scrubbingyang dipakai adalah asam nitrat 1 M. Umpan masuk pada stageke 5 dikontakkan secara berlawanan arah dengan solven masuk pada stage ke 16 dan larutan scrubbing masuk pada stage ke 1. Tujuan penelitian ini adalah memisahkan unsur Zr dan Hf dari hasil olah pasir zirkon menggunakan solven TBP dengan alat mixer settler16 stage. Analisis umpan dan hasil proses pemisahan untuk zirkonium (Zr dilakukan dengan menggunakan alat pendar sinar-X, sedangkananalisis unsur hafnium (Hf menggunakan Analisis Pengaktifan Neutron (APN. Parameter penelitian dilakukan dengan variasi keasaman asam nitrat dalam umpan dan variasi waktu pada berbagai laju pengadukan. Hasil penelitian pemisahan unsur Zr dengan Hf diperolehkondisi optimum pada keasaman umpan 4 N HNO3, keseimbangan dicapai setelah 3jam dan laju pengadukan 3300 rpm. Hasil ekstrak  unsur zirkon (Zr diperoleh kadar sebesar 28577 ppm dengan efisiensi 92,76 % serta kadar pengotor hafnium (Hf sebesar 95 ppm. Kata Kunci: pemisahan Zr, Hf, ekstraksi, mixer settler, alat pendar sinar-X, APN. ABSTRACT SEPARATION of Zr - Hf CONTINUOUSLY USE THE MIXER SETTLER. Separation of Zr - Hf continuously using mixer settler 16 stage has been done. The feed solution is zircon nitrate concentration of Zr = 30786 ppm  and Hf = 499 ppm. As the solvent used extractant 60 % TBP in 40 % kerosene. Nitric acid solution used srubbing 1 M. The feed entered into stage to 5 is contacted with solvents direction on the stage to 16 and the scrubbing solution enter the stage to 1. The purpose of this study is to separate Zr and Hf of the results from the process of zircon sand using solvent TBP using 16 stage

  13. Mitigating Doppler shift effect in HF multitone data modem

    Science.gov (United States)

    Sonlu, Yasar

    1989-09-01

    Digital communications over High Frequency (HF) radio channels are getting important in recent years. Current HF requirements are for data transmission at rates 2.4 kbps or more to accommodate computer data links and digital secure voice. HF modems which were produced to meet these speeds are, serial modems and parallel modems. On the other hand, the HF sky-wave communication medium, the ionosphere, has some propagation problems such as multipath and Doppler shift. The effect of Doppler shift in a parallel modem which employs Differential Quadrature Phase Shift Keying (DQPSK) modulation is considered and a correction method to mitigate the Doppler Shift effect is introduced.

  14. Epitaxial Thin Films of Y doped HfO2

    Science.gov (United States)

    Serrao, Claudy; Khan, Asif; Ramamoorthy, Ramesh; Salahuddin, Sayeef

    Hafnium oxide (HfO2) is one of a few metal oxides that is thermodynamically stable on silicon and silicon oxide. There has been renewed interest in HfO2 due to the recent discovery of ferroelectricity and antiferroelectricity in doped HfO2. Typical ferroelectrics - such as strontium bismuth tantalate (SBT) and lead zirconium titanate (PZT) - contain elements that easily react with silicon and silicon oxide at elevated temperatures; therefore, such ferroelectrics are not suited for device applications. Meanwhile, ferroelectric HfO2 offers promise regarding integration with silicon. The stable phase of HfO2 at room temperature is monoclinic, but HfO2 can be stabilized in the tetragonal, orthorhombic or even cubic phase by suitable doping. We stabilized Y-doped HfO2 thin films using pulsed laser deposition. The strain state can be controlled using various perovskite substrates and controlled growth conditions. We report on Y-doped HfO2 domain structures from piezo-response force microscopy (PFM) and structural parameters via X-ray reciprocal space maps (RSM). We hope this work spurs further interest in strain-tuned ferroelectricity in doped HfO2.

  15. Microstructural characterization of as-cast hf-b alloys

    Directory of Open Access Journals (Sweden)

    João Carlos Jânio Gigolotti

    2012-04-01

    Full Text Available An accurate knowledge of several metal-boron phase diagrams is important to evaluation of higher order systems such as metal-silicon-boron ternaries. The refinement and reassessment of phase diagram data is a continuous work, thus the reevaluation of metal-boron systems provides the possibility to confirm previous data from an investigation using higher purity materials and better analytical techniques. This work presents results of rigorous microstructural characterization of as-cast hafnium-boron alloys which are significant to assess the liquid composition associated to most of the invariant reactions of this system. Alloys were prepared by arc melting high purity hafnium (minimum 99.8% and boron (minimum 99.5% slices under argon atmosphere in water-cooled copper crucible with non consumable tungsten electrode and titanium getter. The phases were identified by scanning electron microscopy, using back-scattered electron image mode and X-ray diffraction. In general, a good agreement was found between our data and those from the currently accepted Hafnium-Boron phase diagram. The phases identified are αHfSS and B-RhomSS, the intermediate compounds HfB and HfB2 and the liquide L. The reactions are the eutectic L ⇔ αHfSS + HfB and L ⇔ HfB2 + B-Rhom, the peritectic L + HfB2 ⇔ HfB and the congruent formation of HfB2.

  16. A DFT study of temperature dependent dissociation mechanism of HF in HF(H2O)7 cluster

    Indian Academy of Sciences (India)

    Swatantra K Yadav; Hirdyesh Mishra; Ashwani K Tiwari

    2015-10-01

    We report a Density Functional Theoretical (DFT) study of dissociation of Hydrogen Fluoride (HF) in HF(H2O)7 cluster, using B3LYP functional and empirical exchange correlation functional M06-2X along with 6-31+G(d,p) basis set. Dissociation constant, KRP, of HF dissociation and pKa values of HF in cluster at various temperatures have been reported. It has been found that both KRP and pKa are highly dependent on temperature. The variation of pKa with temperature suggests that HF is strong acid at lower temperatures. Our study also reveals that HF is a stronger acid in water cluster than in bulk water. Further, the results obtained by DFT calculations have been compared with the earlier reported results obtained from Monte Carlo (MC) simulation. It is found that DFT results are qualitatively consistent with the results of MC simulation but quantitatively different.

  17. Hf-W chronometry of primitive achondrites

    Science.gov (United States)

    Schulz, T.; Münker, C.; Mezger, K.; Palme, H.

    2010-03-01

    Metal segregation and silicate melting on asteroids are the most incisive differentiation events in the early evolution of planetary bodies. The timing of these events can be constrained using the short-lived 182Hf- 182W radionuclide system. Here we present new 182Hf- 182W data for major types of primitive achondrites including acapulcoites, winonaites and one lodranite. These meteorites are of particular interest because they show only limited evidence for partial melting of silicates and are therefore intermediate between chondrites and achondrites. For acapulcoites we derived a 182Hf- 182W age of Δ tCAI = 4.1 +1.2/ -1.1 Ma. A model age for winonaite separates calculated from the intercept of the isochron defines an age of Δ tCAI = 4.8 +3.1/ -2.6 Ma (assuming a bulk Hf/W ratio of ˜1.2). Both ages most likely define primary magmatic events on the respective parent bodies, such as melting of metal, although metal stayed in place and did not segregate to form a core. A later thermal event is responsible for resetting of the winonaite isochron, yielding an age of Δ tCAI = 14.3 +2.7/ -2.2 Ma, significantly younger than the model age. Assuming a co-genetic relationship between winonaites and silicates present in IAB iron meteorites (based on oxygen isotope composition) and including data by Schulz et al. (2009), a common parent body chronology can be established. Magmatic activity occurred between ˜1.5 and 5 Ma after CAIs. More than 5 Ma later, intensive thermal metamorphism has redistributed Hf-W. Average cooling rates calculated for the winonaite/IAB parent asteroid range between ˜35 and ˜4 K/Ma, most likely reflecting different burial depths. Cooling rates obtained for acapulcoites were ˜40 K/Ma to ˜720 K and then ˜3 K/Ma to ˜550 K. Accretion and subsequent magmatism on the acapulcoite parent body occurred slightly later if compared to most achondrite parent bodies (e.g., angrites, ureilites and eucrites), in this case supporting the concept of an inverse

  18. Observations of iodine monoxide columns from satellite

    Directory of Open Access Journals (Sweden)

    A. Schönhardt

    2008-02-01

    Full Text Available Iodine species in the troposphere are linked to ozone depletion and new particle formation. In this study, a full year of iodine monoxide (IO columns retrieved from measurements of the SCIAMACHY satellite instrument is presented, coupled with a discussion of their uncertainties and the detection limits. The largest amounts of IO are found near springtime in the Antarctic. A seasonal variation of iodine monoxide in Antarctica is revealed with high values in springtime, slightly less IO in the summer period and again larger amounts in autumn. In winter, no elevated IO levels are found in the areas accessible to satellite measurements. This seasonal cycle is in good agreement with recent ground-based measurements in Antarctica. In the Arctic region, no elevated IO levels were found in the period analysed. This implies that different conditions with respect to iodine release exist in the two Polar Regions. To investigate possible release mechanisms, comparisons of IO columns with those of tropospheric BrO, and ice coverage are described and discussed. Some parallels and interesting differences between IO and BrO temporal and spatial distributions are identified. Overall, the large spatial coverage of satellite retrieved IO data and the availability of a long-term dataset provide new insight about the abundances and distributions of iodine compounds in the troposphere.

  19. Pressure induced novel compounds in the Hf-O system from first-principles calculations

    OpenAIRE

    2015-01-01

    Using first-principles evolutionary simulations, we have systematically investigated phase stability in the Hf-O system at pressure up to 120 GPa. New compounds Hf5O2, Hf3O2, HfO and HfO3 are discovered to be thermodynamically stable at certain pressure ranges and a new stable high-pressure phase is found for Hf2O with space group Pnnm and anti-CaCl2-type structure. Both P62m-HfO and P4m2-Hf2O3 show semimetallic character. Pnnm-HfO3 shows interesting structure, simultaneously containing oxide...

  20. Water Column Sonar Data Collection

    Data.gov (United States)

    National Oceanic and Atmospheric Administration, Department of Commerce — The collection and analysis of water column sonar data is a relatively new avenue of research into the marine environment. Primary uses include assessing biological...

  1. Ferroelectricity of nondoped thin HfO2 films in TiN/HfO2/TiN stacks

    Science.gov (United States)

    Nishimura, Tomonori; Xu, Lun; Shibayama, Shigehisa; Yajima, Takeaki; Migita, Shinji; Toriumi, Akira

    2016-08-01

    We report on the impact of TiN interfaces on the ferroelectricity of nondoped HfO2. Ferroelectric properties of nondoped HfO2 in TiN/HfO2/TiN stacks are shown in capacitance-voltage and polarization-voltage characteristics. The Curie temperature is also estimated to be around 500 °C. The ferroelectricity of nondoped HfO2 clearly appears by thinning HfO2 film down to ˜35 nm. We directly revealed in thermal treatments that the ferroelectric HfO2 film on TiN was maintained by covering the top surface of HfO2 with TiN, while it was followed by a phase transition to the paraelectric phase in the case of the open surface of HfO2. Thus, it is concluded that the ferroelectricity in nondoped HfO2 in this study was mainly driven by both of top and bottom TiN interfaces.

  2. Water mass circulation and weathering inputs in the Labrador Sea based on coupled Hf-Nd isotope compositions and rare earth element distributions

    Science.gov (United States)

    Filippova, Alexandra; Frank, Martin; Kienast, Markus; Rickli, Jörg; Hathorne, Ed; Yashayaev, Igor M.; Pahnke, Katharina

    2017-02-01

    The Labrador Sea is one of the key areas for deep water formation driving the Atlantic thermohaline circulation and thus plays an important role in Northern Hemisphere climatic fluctuations. In order to better constrain the overturning processes and the origins of the distinct water masses, combined dissolved Hf-Nd isotopic compositions and rare earth element (REE) distribution patterns were obtained from four water depth profiles along a section across the Labrador Sea. These were complemented by one surface sample off the southern tip of Greenland, three shallow water samples off the coast of Newfoundland, and two deep water samples off Nova Scotia. Although light REEs are markedly enriched in the surface waters off the coast of Newfoundland compared to north Atlantic waters, the REE concentration profiles are essentially invariant throughout the water column across the Labrador Sea. The hafnium concentrations of surface waters exhibit a narrow range between 0.6 and 1 pmol/kg but are not significantly higher than at depth. Neodymium isotope signatures (ɛNd) vary from unradiogenic values between -16.8 and -14.9 at the surface to more radiogenic values near -11.0 at the bottom of the Labrador Sea mainly reflecting the advection of the Denmark Strait Overflow Water and North East Atlantic Deep Water, the signatures of which are influenced by weathering contributions from Icelandic basalts. Unlike Nd, water column radiogenic Hf isotope signatures (ɛHf) are more variable representing diverse weathering inputs from the surrounding landmasses. The least radiogenic seawater ɛHf signatures (up to -11.7) are found in surface waters close to Greenland and near the Canadian margin. This reflects the influence of recirculating Irminger Current Waters, which are affected by highly unradiogenic inputs from Greenland. A three to four ɛHf unit difference is observed between Denmark Strait Overflow Water (ɛHf ∼ -4) and North East Atlantic Deep Water (ɛHf ∼ -0

  3. Synthesis of Freestanding HfO2 Nanostructures

    Science.gov (United States)

    2011-04-05

    Tang J, Fabbri J, Robinson RD, Zhu Y, Herman IP, Steigerwald ML, Brus LE: Solid-solution nanoparticles:use of a nonhydrolytic sol-gel synthesis to...colloidal HfO2 nanorods. Adv Mater 2007, 19:2608-2612. Page 21 5. Qiu X, Howe JY, Cardoso MB, Polat O, Heller W: Size control of highly ordered HfO2

  4. Parametric excitation of whistler waves by HF heater

    Science.gov (United States)

    Kuo, S. P.; Lee, M. C.

    1989-01-01

    Possible generation of whistler waves by Tromso HF heater is investigated. It is shown that the HF heater wave can parametrically decay into a whistler wave and a Langmuir wave. Since whistler waves may have a broad range of frequency, the simultaneously excited Langmuir waves can have a much broader frequency bandwidth than those excited by the parametric decay instability.

  5. Study of {sup 179}Hf{sup m2} excitation

    Energy Technology Data Exchange (ETDEWEB)

    Vishnevsky, I. N.; Zheltonozhsky, V. A., E-mail: zhelton@kinr.kiev.ua; Savrasov, A. N. [National Academy of Sciences of Ukraine, Institute for Nuclear Research (Ukraine); Mazur, V. M. [National Academy of Sciences of Ukraine, Institute of Electronic Physics (Ukraine)

    2016-12-15

    Isomeric ratios of {sup 179}Hf{sup m2,g} yields in the (γ, n) reaction and the cross section for the {sup 179}Hf{sup m2} population in the (α, p) reaction are measured for the first time at the end-point energies of 15.1 and 17.5 MeV for bremsstrahlung photons and 26 MeV for alpha particles. The results are σ = (1.1 ± 0.11) × 10{sup −27} cm{sup 2} for the {sup 176}Lu(α, p){sup 179}Hf{sup m2} reaction and Y{sub m2}/Y{sub g} = (6.1 ± 0.3) × 10{sup −6} and (3.7 ± 0.2) × 10{sup −6} for the {sup 180}Hf(γ, n){sup 179}Hf{sup m22} reaction at E{sub ep} =15.1 and 17.5 MeV, respectively. The experimental data on the relative {sup 179}Hf{sup m2} yield indicate a single-humped shape of the excitation function for the {sup 180}Hf(γ, n){sup 179}Hf{sup m2} reaction. Simulation is performed using the TALYS-1.4 and EMPIRE-3.2 codes.

  6. Diffusion of Hf and Nb in Zr-19%Nb

    Energy Technology Data Exchange (ETDEWEB)

    Zou, H. [Atomic Energy of Canada Ltd., Chalk River, ON (Canada). Chalk River Nuclear Labs.; Hood, G.M. [Atomic Energy of Canada Ltd., Chalk River, ON (Canada). Chalk River Nuclear Labs.; Schultz, R.J. [Atomic Energy of Canada Ltd., Chalk River, ON (Canada). Chalk River Nuclear Labs.; Matsuura, N. [Atomic Energy of Canada Ltd., Chalk River, ON (Canada). Chalk River Nuclear Labs.; Roy, J.A. [Atomic Energy of Canada Ltd., Chalk River, ON (Canada). Chalk River Nuclear Labs.; Jackman, J.A. [CANMET, Ottawa, Ont. (Canada). Met. Sci. and Technol.

    1996-05-01

    Diffusion of Hf and Nb in large-grained bcc Zr-19%Nb has been studied. Diffusion coefficients of Hf, D(Hf), were measured in the range 620-1173 K and D(Nb) was measured at 920 and 1167 K. The Hf diffusion profiles were determined by SIMS and the Nb profiles by microtome sectioning and radio-tracer counting. The Hf data show a smooth, temperature-dependent behaviour through the monotectoid temperature, 875 K, and may be characterised by D{approx}10{sup -9}.exp-1.4 (eV/kT) m{sup 2}/s. D(Nb) tends to be lower than the corresponding values for D(Hf). Overall, diffusion of Hf and Nb are characteristic of diffusion in bcc Zr. Surface hold-up (oxide film) at low temperatures was overcome by using ion-implanted Hf diffusion sources. The results are compared with earlier work and discussed in terms of diffusion mechanisms and the {beta}-phase transformation of commercial Zr-2.5Nb. (orig.).

  7. Radiotracer Imaging of Sediment Columns

    Science.gov (United States)

    Moses, W. W.; O'Neil, J. P.; Boutchko, R.; Nico, P. S.; Druhan, J. L.; Vandehey, N. T.

    2010-12-01

    Nuclear medical PET and SPECT cameras routinely image radioactivity concentration of gamma ray emitting isotopes (PET - 511 keV; SPECT - 75-300 keV). We have used nuclear medical imaging technology to study contaminant transport in sediment columns. Specifically, we use Tc-99m (T1/2 = 6 h, Eγ = 140 keV) and a SPECT camera to image the bacteria mediated reduction of pertechnetate, [Tc(VII)O4]- + Fe(II) → Tc(IV)O2 + Fe(III). A 45 mL bolus of Tc-99m (32 mCi) labeled sodium pertechnetate was infused into a column (35cm x 10cm Ø) containing uranium-contaminated subsurface sediment from the Rifle, CO site. A flow rate of 1.25 ml/min of artificial groundwater was maintained in the column. Using a GE Millennium VG camera, we imaged the column for 12 hours, acquiring 44 frames. As the microbes in the sediment were inactive, we expected most of the iron to be Fe(III). The images were consistent with this hypothesis, and the Tc-99m pertechnetate acted like a conservative tracer. Virtually no binding of the Tc-99m was observed, and while the bolus of activity propagated fairly uniformly through the column, some inhomogeneity attributed to sediment packing was observed. We expect that after augmentation by acetate, the bacteria will metabolically reduce Fe(III) to Fe(II), leading to significant Tc-99m binding. Imaging sediment columns using nuclear medicine techniques has many attractive features. Trace quantities of the radiolabeled compounds are used (micro- to nano- molar) and the half-lives of many of these tracers are short (Image of Tc-99m distribution in a column containing Rifle sediment at four times.

  8. Oxygen Recovery in Hf Oxide Films Fabricated by Sputtering

    Institute of Scientific and Technical Information of China (English)

    JIANG Ran; LI Zi-Feng

    2009-01-01

    The chemical structure of ultrathin Hf oxide films (< 10 nm) fabricated by a standard sputtering method is investigated using x-ray spectroscopy and Rutherford backscattering spectroscopy. According to the experiments,oxygen species are impacted to the HfO2/Si interface during the initial sputtering, and then released back to the upper Hf02 region driven by the oxygen concentration grads. A vacuum annealing can greatly enhance this recovery process. Additionally, significant SiO2 reduction in the interface is observed after the vacuum annealing for the thick HfO2 films in our experiment. It might be an effective method to confine the interracial layer thickness by sputtering thick HfO2 in no-oxygen ambient.

  9. Crystal structure of Si-doped HfO2

    Science.gov (United States)

    Zhao, Lili; Nelson, Matthew; Aldridge, Henry; Iamsasri, Thanakorn; Fancher, Chris M.; Forrester, Jennifer S.; Nishida, Toshikazu; Moghaddam, Saeed; Jones, Jacob L.

    2014-01-01

    Si-doped HfO2 was prepared by solid state synthesis of the starting oxides. Using Rietveld refinement of high resolution X-ray diffraction patterns, a substitutional limit of Si in HfO2 was determined as less than 9 at. %. A second phase was identified as Cristobalite (SiO2) rather than HfSiO4, the latter of which would be expected from existing SiO2-HfO2 phase diagrams. Crystallographic refinement with increased Si-dopant concentration in monoclinic HfO2 shows that c/b increases, while β decreases. The spontaneous strain, which characterizes the ferroelastic distortion of the unit cell, was calculated and shown to decrease with increasing Si substitution.

  10. The (178m2)Hf Controversy

    Energy Technology Data Exchange (ETDEWEB)

    Becker, J A; Gemmell, D S; Schiffer, J P; Wilhelmy, J B

    2003-07-24

    Since its discovery in the 1960's the {sup 178m2}Hf isomer has garnered high attention from both the basic and applied communities in nuclear science. It's combination of high spin (16+), long half life (31 yrs), and high excitation energy (2.446 MeV) offer unique possibilities as an energy storage medium. Interest in the isomer was rekindled beginning in 1999 when a series of publications began to appear from a group (referred to here as the ''Texas collaboration'') primarily based at the University of Texas, Dallas [1]. They reported observations that some of the stored energy could be released (''triggered'') when the isomer was exposed to a fluence of photons in the energy range {approx}10 to {approx}60 keV. The implications of this observation are profound. Even though the claimed cross section for the process was {approx}7 orders of magnitude greater than would be predicted from the known systematics of photon absorption by nuclei in this mass range [2], such a highly efficient method for triggering the isomeric deexcitation immediately suggested applications utilizing the explosive or the controlled gradual energy release from a very compact source. The prospect of such applications has focused considerable interest on realizing the promise that is implicit in the reported observations. However, two experiments performed by a group from ANL/LANL/LLNL at the Advanced Photon Source at Argonne (the ''APS collaboration'') reported negative results for the observation of any photon-triggered deexcitation of the {sup 178m2}Hf isomer [3]. This has led to a continued controversy, where both sides have adamantly defended their observations. At this point an outsider has difficulty determining whether there is indeed a triggering effect that should be pursued energetically with substantial resources, or whether the phenomenon consists of overly optimistic interpretation of data.

  11. Decoupling of whole-rock Nd-Hf and zircon Hf-O isotopic compositions of a 284 Ma mafic-ultramafic intrusion in the Beishan Terrane, NW China

    Science.gov (United States)

    Su, Ben-Xun; Qin, Ke-Zhang; Lu, Ying-Huai; Sun, He; Sakyi, Patrick Asamoah

    2015-10-01

    Abundant Permian mafic-ultramafic intrusions in the Beishan Terrane, NW China, are parts of the Tarim large igneous province. Among these intrusions, Luodong intrusion is composed of dunite, wehrlite and gabbro. These rocks have whole-rock Sr-Nd-Hf and zircon Hf-O isotope compositions that display significant decoupling. The decoupling of these generally well-correlated systems demonstrates contrasting evolving trends. Systematic compositional and mineralogical controls on decoupling have been investigated. Wehrlites and gabbros show MORB-like trace element patterns with negligible crustal contamination. They have high initial 143Nd/144Nd [ɛNd(t) = +6.6 to +11.2] and 176Hf/177HfHf(t) = +12.2 to +16.9] and low initial 87Sr/86Sr [(87Sr/86Sr)i = 0.702949-0.704098] ratios and plot within the MORB field, indicating that their parental magmas were derived from a depleted mantle source. The enrichment features are present in the zircon crystals separated from the gabbro. These homogeneously unzoned zircon crystals have high U concentrations, low Th/U ratios and a U-Pb age of 284.0 ± 2.3 Ma. They are therefore interpreted as having formed rapidly in a highly fractionated/evolved magma. Their ɛHf(t) and δ18O values range from -9.3 to -6.7 and +10.25 ‰ to +11.42 ‰, respectively. The decoupling is linked with crustal contamination by ancient crust (probably Proterozoic schist in the Beishan Terrane) that occurred during zircon crystallization. However, the contamination signature in the whole-rock composition was soon overprinted by magma mixing process. The inference is evidenced by zoning textures preserved in plagioclase, clinopyroxene, spinel and particularly olivine, and the presence of coeval diabase dykes cutting through the intrusion. The isotope decoupling observed in this mantle-plume-related mafic-ultramafic intrusion supports the idea that Nd-Hf decoupling and Lu/Hf and Sm/Nd parent/daughter variations exist only on a small hand-size scale in a

  12. Ferroelectricity-modulated resistive switching in Pt/Si:HfO2/HfO2-x /Pt memory

    Science.gov (United States)

    Ran, Jiang; Xianghao, Du; Zuyin, Han

    2016-08-01

    It is investigated for the effect of a ferroelectric Si:HfO2 thin film on the resistive switching in a stacked Pt/Si:HfO2/highly-oxygen-deficient HfO2-x /Pt structure. Improved resistance performance was observed. It was concluded that the observed resistive switching behavior was related to the modulation of the width and height of a depletion barrier in the HfO2-x layer, which was caused by the Si:HfO2 ferroelectric polarization field effect. Reliable switching reproducibility and long data retention were observed in these memory cells, suggesting their great potential in non-volatile memories applications with full compatibility and simplicity. Project supported by the National Natural Science Foundation of China (No. 11374182), the Natural Science Foundation of Shandong Province (No. ZR2012FQ012), and the Jinan Independent Innovation Projects of Universities (No. 201303019).

  13. Flare Plasma Iron Abundance

    Science.gov (United States)

    Dennis, Brian R.; Dan, Chau; Jain, Rajmal; Schwartz, Richard A.; Tolbert, Anne K.

    2008-01-01

    The equivalent width of the iron-line complex at 6.7 keV seen in flare X-ray spectra suggests that the iron abundance of the hottest plasma at temperatures >approx.10 MK may sometimes be significantly lower than the nominal coronal abundance of four times the photospheric value that is commonly assumed. This conclusion is based on X-ray spectral observations of several flares seen in common with the Ramaty High Energy Solar Spectroscopic Imager (RHESSI) and the Solar X-ray Spectrometer (SOXS) on the second Indian geostationary satellite, GSAT-2. The implications of this will be discussed as it relates to the origin of the hot flare plasma - either plasma already in the corona that is directly heated during the flare energy release process or chromospheric plasma that is heated by flare-accelerated particles and driven up into the corona. Other possible explanations of lower-than-expected equivalent widths of the iron-line complex will also be discussed.

  14. Source components and magmatic processes in the genesis of Miocene to Quaternary lavas in western Turkey: constraints from HSE distribution and Hf-Pb-Os isotopes

    Science.gov (United States)

    Aldanmaz, Ercan; Pickard, Megan; Meisel, Thomas; Altunkaynak, Şafak; Sayıt, Kaan; Şen, Pınar; Hanan, Barry B.; Furman, Tanya

    2015-08-01

    Hf-Pb-Os isotope compositions and highly siderophile element (HSE) abundance variations are used to evaluate the mantle source characteristics and possible effects of differentiation processes in lavas from western Turkey, where the eruption of Late Miocene to Quaternary OIB-type intraplate mafic alkaline lavas followed pre-Middle Miocene convergent margin-type volcanism. Concentrations of Os, Ir, and Ru (IPGE) in the OIB-type intraplate lavas decrease with fractionation for primitive melts (MgO > 10 wt%), suggesting that these elements reside predominantly in olivine and associated HSE retaining trace phases and behave compatibly during olivine-dominated fractionation. Fractional crystallization trends indicate distinctly lower bulk partition coefficients for IPGE in more evolved lavas, possibly reflecting a change in the fractionating assemblages. Pd and Re in the primitive melts display negative correlations with MgO, demonstrating moderately incompatible behavior of these elements during fractionation, while the significantly scattered variation in Pt against MgO may indicate the effects of micronuggets of a Pt-rich alloy. Os-rich alkaline primary lavas (>50 ppt Os) exhibit a limited range of 187Os/188Os (0.1361-0.1404), with some xenolith-bearing lavas displaying depletions in 187Os/188Os (0.1131-0.1232), suggesting slight compositional modification of primitive melts through contamination with highly depleted, Os-rich mantle lithosphere. More radiogenic Os isotope ratios (187Os/188Os > 0.1954) in the evolved lavas reflect contamination of the magmas by high187Os/188Os crustal material during shallow differentiation. The OIB-type lavas show limited variations in Hf and Pb isotopes with 176Hf/177Hf = 0.282941-0.283051, 206Pb/204Pb = 18.683-19.091, 207Pb/204Pb = 15.579-15.646, 208Pb/204Pb = 38.550-38.993; 176Hf/177Hf ratios correlate negatively with 208Pb*/206Pb*, suggesting the effects of similar mantle processes on the evolution of time-integrated Th/U and Lu/Hf

  15. Power-Stepped HF Cross Modulation Experiments at HAARP

    Science.gov (United States)

    Greene, S.; Moore, R. C.; Langston, J. S.

    2013-12-01

    High frequency (HF) cross modulation experiments are a well established means for probing the HF-modified characteristics of the D-region ionosphere. In this paper, we apply experimental observations of HF cross-modulation to the related problem of ELF/VLF wave generation. HF cross-modulation measurements are used to evaluate the efficiency of ionospheric conductivity modulation during power-stepped modulated HF heating experiments. The results are compared to previously published dependencies of ELF/VLF wave amplitude on HF peak power. The experiments were performed during the March 2013 campaign at the High Frequency Active Auroral Research Program (HAARP) Observatory. HAARP was operated in a dual-beam transmission format: the first beam heated the ionosphere using sinusoidal amplitude modulation while the second beam broadcast a series of low-power probe pulses. The peak power of the modulating beam was incremented in 1-dB steps. We compare the minimum and maximum cross-modulation effect and the amplitude of the resulting cross-modulation waveform to the expected power-law dependence of ELF/VLF wave amplitude on HF power.

  16. Molecular abundances in the Sagittarius A molecular cloud

    Science.gov (United States)

    Minh, Y. C.; Irvine, W. M.; Friberg, P.

    1992-01-01

    We have obtained column densities for HCO(+), HCO, HCS(+), C3H2, HC5N, SiO, OCS, HCOOH, CH3CH2OH, and CH3CCH toward Sgr A. The fractional abundance of SiO relative to molecular hydrogen in Sgr A is comparable to that for the Orion plateau, about 10 exp-7 to 10 exp -8, which may be a typical value for hot clouds. The abundances of HCO, CH3CH2OH, and CH3CCH all appear to be enhanced relative to other molecular clouds such as Sgr B2.

  17. Abundance, Excess, Waste

    Directory of Open Access Journals (Sweden)

    Rox De Luca

    2016-02-01

    Her recent work focuses on the concepts of abundance, excess and waste. These concerns translate directly into vibrant and colourful garlands that she constructs from discarded plastics collected on Bondi Beach where she lives. The process of collecting is fastidious, as is the process of sorting and grading the plastics by colour and size. This initial gathering and sorting process is followed by threading the components onto strings of wire. When completed, these assemblages stand in stark contrast to the ease of disposability associated with the materials that arrive on the shoreline as evidence of our collective human neglect and destruction of the environment around us. The contrast is heightened by the fact that the constructed garlands embody the paradoxical beauty of our plastic waste byproducts, while also evoking the ways by which those byproducts similarly accumulate in randomly assorted patterns across the oceans and beaches of the planet.

  18. Column Holdup Formula of Soil Solute Transport

    Institute of Scientific and Technical Information of China (English)

    2000-01-01

    The shortcomings of the present two formulae for describing column holdup are analyzed and deductions are made to find a new formula. The column holdup, Hw, described by the new formula is dimensional,and related to soil solute transport kinesis and column physical properties. Compared with the other two column holdups, Hw is feasible to describe dimensional column holdup during solute transport process. The relationships between Hw and retardation factor, R, in different solute transport boundary conditions are established.

  19. The solar photospheric abundance of hafnium and thorium. Results from CO5BOLD 3D hydrodynamic model atmospheres

    CERN Document Server

    Caffau, Elisabetta; Ludwig, H -G; Bonifacio, P; Steffen, M; Behara, N T

    2008-01-01

    Context: The stable element hafnium (Hf) and the radioactive element thorium (Th) were recently suggested as a suitable pair for radioactive dating of stars. The applicability of this elemental pair needs to be established for stellar spectroscopy. Aims: We aim at a spectroscopic determination of the abundance of Hf and Th in the solar photosphere based on a \\cobold 3D hydrodynamical model atmosphere. We put this into a wider context by investigating 3D abundance corrections for a set of G- and F-type dwarfs. Method: High-resolution, high signal-to-noise solar spectra were compared to line synthesis calculations performed on a solar CO5BOLD model. For the other atmospheres, we compared synthetic spectra of CO5BOLD 3D and associated 1D models. Results: For Hf we find a photospheric abundance A(Hf)=0.87+-0.04, in good agreement with a previous analysis, based on 1D model atmospheres. The weak Th ii 401.9 nm line constitutes the only Th abundance indicator available in the solar spectrum. It lies in the red wing...

  20. Partially saturated granular column collapse

    Science.gov (United States)

    Turnbull, Barbara; Johnson, Chris

    2017-04-01

    Debris flows are gravity-driven sub-aerial mass movements containing water, sediments, soil and rocks. These elements lead to characteristics common to dry granular media (e.g. levee formation) and viscous gravity currents (viscous fingering and surge instabilities). The importance of pore fluid in these flows is widely recognised, but there is significant debate over the mechanisms of build up and dissipation of pore fluid pressure within debris flows, and the resultant effect this has on dilation and mobility of the grains. Here we specifically consider the effects of the liquid surface in the flow. We start with a simple experiment constituting a classical axisymmetric granular column collapse, but with fluid filling the column up to a depth comparable to the depth of grains. Thus, as the column collapses, capillary forces may be generated between the grains that prevent dilation. We explore a parameter space to uncover the effects of fluid viscosity, particle size, column size, aspect ratio, grain shape, saturation level, initial packing fraction and significantly, the effects of fine sediments in suspension which can alter the capillary interaction between wetted macroscopic grains. This work presents an initial scaling analysis and attempts to relate the findings to current debris flow modelling approaches.

  1. HF dissociation in water clusters by computer simulations

    OpenAIRE

    Elena, Alin Marin

    2013-01-01

    We perform Restrained hybrid Monte Carlo simulations to compute the equilibrium constant of the dissociation reaction of HF in HF(H2O)7. We find that, like in the bulk, hydrofluoric acid, is a weak acid also in the cubic HF(H2O)7 cluster, and that its acidity is higher at lower T. This latter phenomenon has a (vibrational) entropic origin, namely it is due to the reduction of the (negative) T∆S contribution to the variation of free energy between the reactant and product. We found also ...

  2. Ionospheric heating with oblique HF waves

    Science.gov (United States)

    Field, Edward C., Jr.; Bloom, Ron M.

    1990-10-01

    Calculations of ionospheric electron density perturbations and ground-level signal changes produce by intense oblique high frequency (HF) transmitters are presented. This analysis considers radio field focusing at caustics, the consequent joule-heating of the surrounding plasma, heat conduction, diffusion, and recombination processes: these being the effects of a powerful oblique 'modifying' wave. It neglects whatever plasma instabilities might occur. Then effects on a secondary 'test' wave that is propagated along the same path as the first are investigated. Calculations predict ground-level field-strength reductions of several dB in the test wave for modifying waves having ERP in the 85 to 90 dBW range. These field-strength changes are similar in sign, magnitude, and location to ones measured in Soviet experiments. The results are sensitive to the model ionosphere assumed, so future experiments should employ the widest possible range of frequencies and propagation conditions. An effective power of 90 dBW seems to be a sort of threshold that, if exceeded, results in substantial rather than small signal changes. The conclusions are based solely on joule-heating and subsequent defocusing of waves passing through caustic regions.

  3. The (178m2) Hf Controversy

    CERN Document Server

    Becker, J A; Schiffer, J P; Wilhelmy, J

    2003-01-01

    Since its discovery in the 1960's the sup 1 sup 7 sup 8 sup m sup 2 Hf isomer has garnered high attention from both the basic and applied communities in nuclear science. It's combination of high spin (16+), long half life (31 yrs), and high excitation energy (2.446 MeV) offer unique possibilities as an energy storage medium. Interest in the isomer was rekindled beginning in 1999 when a series of publications began to appear from a group (referred to here as the ''Texas collaboration'') primarily based at the University of Texas, Dallas [1]. They reported observations that some of the stored energy could be released (''triggered'') when the isomer was exposed to a fluence of photons in the energy range approx 10 to approx 60 keV. The implications of this observation are profound. Even though the claimed cross section for the process was approx 7 orders of magnitude greater than would be predicted from the known systematics of photon absorption by nuclei in this mass range [2], such a highly efficient method fo...

  4. Grindability of cast Ti-Hf alloys.

    Science.gov (United States)

    Kikuchi, Masafumi; Takahashi, Masatoshi; Sato, Hideki; Okuno, Osamu; Nunn, Martha E; Okabe, Toru

    2006-04-01

    As part of our systematic studies characterizing the properties of titanium alloys, we investigated the grindability of a series of cast Ti-Hf alloys. Alloy buttons with hafnium concentrations up to 40 mass% were made using an argon-arc melting furnace. Each button was cast into a magnesia-based mold using a dental titanium casting machine; three specimens were made for each metal. Prior to testing, the hardened surface layer was removed. The specimens were ground at five different speeds for 1 min at 0.98 N using a carborundum wheel on an electric dental handpiece. Grindability was evaluated as the volume of metal removed per minute (grinding rate) and the volume ratio of metal removed compared to the wheel material lost (grinding ratio). The data were analyzed using ANOVA. A trend of increasing grindability was found with increasing amounts of hafnium, although there was no statistical difference in the grindability with increasing hafnium contents. We also found that hafnium may be used to harden or strengthen titanium without deteriorating the grindability.

  5. The magnetic properties of $^{\\rm 177}$Hf and $^{\\rm 180}$Hf in the strong coupling deformed model

    OpenAIRE

    Muto, S.; Stone, N. J.; Bingham, C. R.; STONE, J.R; Walker, P. M.; Audi, G.; Gaulard, C.; Köster, U.(Institut Laue-Langevin (ILL), Grenoble, France); Nikolov, J.; Nishimura,K; Ohtsubo, T.; Podolyak, Z.; Risegari, L.; Simpson, G.S.; Veskovic, M.

    2014-01-01

    This paper reports NMR measurements of the magnetic dipole moments of two high-K isomers, the 37/2$^-$, 51.4 m, 2740 keV state in $^{\\rm 177}$Hf and the 8$^-$, 5.5 h, 1142 keV state in $^{\\rm 180}$Hf by the method of on-line nuclear orientation. Also included are results on the angular distributions of gamma transitions in the decay of the $^{\\rm 177}$Hf isotope. These yield high precision E2/M1 multipole mixing ratios for transitions in bands built on the 23/2$^+$, 1.1 s, isomer at 1315 keV ...

  6. Columns

    Institute of Scientific and Technical Information of China (English)

    于晓悠; 丁燕燕; 韩多妮; Ray; Carrie; 未冉

    2010-01-01

    <正>New York Whitney艺术双年展今年第75届纽约Whitney双年展不设题目,但以"2010"指示策展方向,继续以发掘年轻艺术家、展示创作实验为目标。参展的55位艺术家,最年轻的是23岁摄影师Tam Tran,最老资历的是75岁的概念艺术家Lorraine O’Grady。这届的另一先创性,是每位艺术家只限一件或一个系列的作品,避免了去届双年展的"小型个人回顾展"现象,而五层楼的展场各有特色,如录像及短片将独立于三楼展出,而美术馆馆藏则移师五楼。这届双年展由著名的意大利策展人Francesco Bonami联同助手Gary Carrion-Murayarn共同制作,两位策展人说明,双年展的重要性是预示未来,创新及前瞻性依然是取决原则。

  7. Columns

    Institute of Scientific and Technical Information of China (English)

    Carrie Tsang; 丁燕燕; 韩多妮; RAY

    2009-01-01

    <正>Paris承诺的展现33岁的墨西哥艺术家Mario Garcia Torres是近年国际艺坛炙手可热的新星,他以录象、摄影、幻灯及装置为创作形式,透过个人视点及独特演绎手法来重新思考历史。他是一个思考型艺术家,同时又是一个淘气的大孩子,作品往往反映了他的双重性格——嬉戏中带有深沉的历史感。这次是GarciaTorres首次在法国的国家博物馆举行展览,整合出版了他过往两年间在

  8. A thirty second isomer in {sup 171}Hf

    Energy Technology Data Exchange (ETDEWEB)

    Campbell, P.; Billowes, J.; Cooper, T.G.; Grant, I.S.; Pearson, M.R.; Wheeler, P.D. [Schuster Laboratory, University of Manchester, M13 9PL (United Kingdom); Cochrane, E.C.A.; Cooke, J.L.; Evans, D.E.; Griffith, J.A.R.; Persson, J.R.; Richardson, D.S.; Tungate, G.; Zybert, L. [School of Physics and Space Research, University of Birmingham, Edgbaston, Birmingham B15 2TT (United Kingdom); Dendooven, P.; Honkanen, A.; Huhta, M.; Oinonen, M.; Penttilae, H.; Aeystoe, J. [Accelerator Laboratory, University of Jyvaeskylae, PL 35 Jyvaeskylae SF-403 51 (Finland)

    1997-09-01

    An isomer has been detected in {sup 171}Hf with a half-life of T{sub 1/2} 29.5(9) s. The state was populated in the {sup 170}Yb({alpha},3n){sup 171m}Hf reaction at a beam energy of E{sub {alpha}} = 50 MeV in an on-line ion guide isotope separator. The isomeric {sup 171m}Hf{sup +} beam was extracted from the ion guide, mass-analysed and implanted in the surface of a microchannel-plate. The half-life of the collected activity was measured from the decay of the microchannel-plate count rate. We associate the isomer with the first excited state in {sup 171}Hf with spin 1/2{sup -} at an excitation energy of 22(2) keV. (author)

  9. HF fiber stuffing in building 186 at CERN

    CERN Multimedia

    Tiziano Camporesi

    2003-01-01

    Each of the 36 HF wedges comprise ca 12000 quartz fibers which are the active element of the calorimeter. The fibers are produced by Polymicro (USA), cleaved and bundled at KFKI, Budapest, Hungary and inserted at CERN.

  10. Low-Frequency Waves in HF Heating of the Ionosphere

    Science.gov (United States)

    Sharma, A. S.; Eliasson, B.; Milikh, G. M.; Najmi, A.; Papadopoulos, K.; Shao, X.; Vartanyan, A.

    2016-02-01

    Ionospheric heating experiments have enabled an exploration of the ionosphere as a large-scale natural laboratory for the study of many plasma processes. These experiments inject high-frequency (HF) radio waves using high-power transmitters and an array of ground- and space-based diagnostics. This chapter discusses the excitation and propagation of low-frequency waves in HF heating of the ionosphere. The theoretical aspects and the associated models and simulations, and the results from experiments, mostly from the HAARP facility, are presented together to provide a comprehensive interpretation of the relevant plasma processes. The chapter presents the plasma model of the ionosphere for describing the physical processes during HF heating, the numerical code, and the simulations of the excitation of low-frequency waves by HF heating. It then gives the simulations of the high-latitude ionosphere and mid-latitude ionosphere. The chapter also briefly discusses the role of kinetic processes associated with wave generation.

  11. Near-infrared LIF spectroscopy of HfF

    CERN Document Server

    Grau, Matt; Loh, Huanqian; Sinclair, Laura C; Stutz, Russel P; Yahn, Tylser S; Cornell, Eric A

    2012-01-01

    The molecular ion HfF$^+$ is the chosen species for a JILA experiment to measure the electron electric dipole moment (eEDM). Detailed knowledge of the spectrum of HfF is crucial to prepare HfF$^+$ in a state suitable for performing an eEDM measurement\\cite{Leanhardt}. We investigated the near-infrared electronic spectrum of HfF using laser-induced fluorescence (LIF) of a supersonic molecular beam. We discovered eight unreported bands, and assign each of them unambiguously, four to vibrational bands belonging to the transition $[13.8]0.5 \\leftarrow X1.5$, and four to vibrational bands belonging to the transition $[14.2]1.5 \\leftarrow X1.5$. Additionally, we report an improved measurement of vibrational spacing of the ground state, as well as anharmonicity $\\omega_e x_e$.

  12. Theoretical Assessment of 178m2Hf De-Excitation

    Energy Technology Data Exchange (ETDEWEB)

    Hartouni, E P; Chen, M; Descalle, M A; Escher, J E; Loshak, A; Navratil, P; Ormand, W E; Pruet, J; Thompson, I J; Wang, T F

    2008-10-06

    This document contains a comprehensive literature review in support of the theoretical assessment of the {sup 178m2}Hf de-excitation, as well as a rigorous description of controlled energy release from an isomeric nuclear state.

  13. Primordial Deuterium Abundance Measurements

    CERN Document Server

    Levshakov, S A; Takahara, F; Levshakov, Sergei A.; Kegel, Wilhelm H.; Takahara, Fumio

    1997-01-01

    Deuterium abundances measured recently from QSO absorption-line systems lie in the range from 3 10^{-5} to 3 10^{-4}, which shed some questions on standard big bang theory. We show that this discordance may simply be an artifact caused by inadequate analysis ignoring spatial correlations in the velocity field in turbulent media. The generalized procedure (accounting for such correlations) is suggested to reconcile the D/H measurements. An example is presented based on two high-resolution observations of Q1009+2956 (low D/H) [1,2] and Q1718+4807 (high D/H) [8,9]. We show that both observations are compatible with D/H = 4.1 - 4.6 10^{-5}, and thus support SBBN. The estimated mean value = 4.4 10^{-5} corresponds to the baryon-to-photon ratio during SBBN eta = 4.4 10^{-10} which yields the present-day baryon density Omega_b h^2 = 0.015.

  14. Integrated magnetics design for HF-link power converters

    DEFF Research Database (Denmark)

    Ljusev, Petar; Andersen, Michael Andreas E.

    2005-01-01

    This paper deals with the design of integrated magnetics for HF-link converters, where the integrated magnetic components do not necessarily belong to the same voltage loop. Depending on the specific HF-link converter topology, the proposed integrated magnetics can either alleviate the derivation...... of independent auxiliary supply voltages from the main transformer or integrate other magnetic structures, thus saving board space and cutting costs....

  15. Integrated magnetics design for HF-link power converters

    Energy Technology Data Exchange (ETDEWEB)

    Ljusev, P.; Andersen, Michael A.E.

    2005-07-01

    This paper deals with the design of integrated magnetics for HF-link converters, where the two integrated magnetic components on the same core do not necessarily belong to the same voltage loop. Depending on the specific HF-link converter topology, the proposed integrated magnetics can either alleviate the derivation of independent auxiliary supply voltages from the main transformer or integrate other magnetic structures, thus saving board space and cutting costs. (au)

  16. Synthesis of freestanding HfO2 nanostructures

    Directory of Open Access Journals (Sweden)

    Boyle Kayla

    2011-01-01

    Full Text Available Abstract Two new methods for synthesizing nanostructured HfO2 have been developed. The first method entails exposing HfTe2 powders to air. This simple process resulted in the formation of nanometer scale crystallites of HfO2. The second method involved a two-step heating process by which macroscopic, freestanding nanosheets of HfO2 were formed as a byproduct during the synthesis of HfTe2. These highly two-dimensional sheets had side lengths measuring up to several millimeters and were stable enough to be manipulated with tweezers and other instruments. The thickness of the sheets ranged from a few to a few hundred nanometers. The thinnest sheets appeared transparent when viewed in a scanning electron microscope. It was found that the presence of Mn enhanced the formation of HfO2 by exposure to ambient conditions and was necessary for the formation of the large scale nanosheets. These results present new routes to create freestanding nanostructured hafnium dioxide. PACS: 81.07.-b, 61.46.Hk, 68.37.Hk.

  17. The isobutylene-isobutane alkylation process in liquid HF revisited.

    Science.gov (United States)

    Esteves, P M; Araújo, C L; Horta, B A C; Alvarez, L J; Zicovich-Wilson, C M; Ramírez-Solís, A

    2005-07-07

    Details on the mechanism of HF catalyzed isobutylene-isobutane alkylation were investigated. On the basis of available experimental data and high-level quantum chemical calculations, a detailed reaction mechanism is proposed taking into account solvation effects of the medium. On the basis of our computational results, we explain why the density of the liquid media and stirring rates are the most important parameters to achieve maximum yield of alkylate, in agreement with experimental findings. The ab initio Car-Parrinello molecular dynamics calculations show that isobutylene is irreversibly protonated in the liquid HF medium at higher densities, leading to the ion pair formation, which is shown to be a minimum on the potential energy surface after optimization using periodic boundary conditions. The HF medium solvates preferentially the fluoride anion, which is found as solvated [FHF](-) or solvated F(-.)(HF)(3). On the other hand, the tert-butyl cation is weakly solvated, where the closest HF molecules appear at a distance of about 2.9 Angstrom with the fluorine termination of an HF chain.

  18. Modeling of column apparatus processes

    CERN Document Server

    Boyadjiev, Christo; Boyadjiev, Boyan; Popova-Krumova, Petya

    2016-01-01

    This book presents a new approach for the modeling of chemical and interphase mass transfer processes in industrial column apparatuses, using convection-diffusion and average-concentration models. The convection-diffusion type models are used for a qualitative analysis of the processes and to assess the main, small and slight physical effects, and then reject the slight effects. As a result, the process mechanism can be identified. It also introduces average concentration models for quantitative analysis, which use the average values of the velocity and concentration over the cross-sectional area of the column. The new models are used to analyze different processes (simple and complex chemical reactions, absorption, adsorption and catalytic reactions), and make it possible to model the processes of gas purification with sulfur dioxide, which form the basis of several patents.

  19. Comparison of drug substance impurity profiles generated with extended length columns during packed-column SFC.

    Science.gov (United States)

    Roston, D A; Ahmed, S; Williams, D; Catalano, T

    2001-10-01

    The current study assesses the effect of extending column length during gradient packed column sub/supercritical fluid chromatography (PCSFC) experiments on the detection of known and unknown impurities in a drug substance sample. Quantitative drug substance impurity profiles were generated and compared using multiple column PCSFC and HPLC conditions. Also, chromatographic figures of merit were estimated and compared for components of a standard mixture during PCSFC experiments, which used one column, four columns, and six columns in series.

  20. Hf impurity and defect interactions in helium-implanted NiHf

    Energy Technology Data Exchange (ETDEWEB)

    Govindaraj, R. E-mail: govind@igcar.ernet.in; Gopinathan, K.P.; Viswanathan, B

    2001-07-01

    TDPAC measurements on the reference and untreated sample indicate a loss in anisotropy which is attributed mainly to the association of probe atoms with defects produced by (n,{gamma}) reactions with isotopes of Ni and experiencing combined magnetic and quadrupole interactions of comparable strengths. Evolution of defect free and substitutional fraction of probe atoms experiencing Larmor frequency characteristic of Ni matrix has been studied as a function of isochronal annealing temperature in helium free {alpha}-irradiated and homogeneously helium-implanted samples. No defect associated Larmor precession frequency and/or quadrupole frequency could be deduced in these uncorrelated damage studies. Comparison of recovery stages in {alpha}-irradiated and helium-implanted samples indicates the binding of helium associated defects by Hf impurities. Segregation of Hf atoms is observed in the helium free {alpha}-irradiated sample for annealing treatment at 973 K, while no such effect is observed in the helium-implanted sample for isochronal annealing treatments up to 1273 K.

  1. HPLC determination of ibuprofen, diclofenac and salicylic acid using hollow fiber-based liquid phase microextraction (HF-LPME).

    Science.gov (United States)

    Ramos Payán, María; Bello López, Miguel Angel; Fernández-Torres, Rut; Pérez Bernal, Juan Luis; Callejón Mochón, Manuel

    2009-10-27

    This paper describes an extraction method using a polypropylene membrane supporting dihexyl ether (three-phase hollow fiber-based liquid phase microextraction (HF-LPME)) for the analysis of several pharmaceuticals (salicylic acid (SAC), ibuprofen (IBU) and diclofenac (DIC)) followed by a HPLC determination using a monolithic silica type HPLC column, that allows lower retention times than the usual packed columns with adequate resolution. Detection was realized by means of a coupled in series diode array (DAD) and fluorescence (FLD) detectors. HF-LPME is a relatively new technique employed in analytical chemistry for sample pretreatment which offers more selectivity and sensitivity than any traditional extraction technique. Detection limits by DAD are 12, 53 and 40 ng mL(-1) for salicylic acid, diclofenac and ibuprofen, respectively and by FLD 7 and 2 ng mL(-1) for salicylic acid, and ibuprofen. The method has been successfully applied to their direct determination in human urine and the results obtained demonstrated that could be also applied to the determination of the corresponding metabolites.

  2. Reconciliation of the excess 176Hf conundrum in meteorites: Recent disturbances of the Lu-Hf and Sm-Nd isotope systematics

    Science.gov (United States)

    Bast, Rebecca; Scherer, Erik E.; Sprung, Peter; Mezger, Klaus; Fischer-Gödde, Mario; Taetz, Stephan; Böhnke, Mischa; Schmid-Beurmann, Hinrich; Münker, Carsten; Kleine, Thorsten; Srinivasan, Gopalan

    2017-09-01

    The long-lived 176Lu-176Hf and 147Sm-143Nd radioisotope systems are commonly used chronometers, but when applied to meteorites, they can reveal disturbances. Specifically, Lu-Hf isochrons commonly yield dates up to ∼300 Myr older than the solar system and varying initial 176Hf/177Hf values. We investigated this problem by attempting to construct mineral and whole rock isochrons for eucrites and angrites. Meteorites from different parent bodies exhibit similar disturbance features suggesting that a common process is responsible. Minerals scatter away from isochron regressions for both meteorite classes, with low-Hf phases such as plagioclase and olivine typically being most displaced above (or left of) reference isochrons. Relatively Hf-rich pyroxene is less disturbed but still to the point of steepening Lu-Hf errorchrons. Using our Lu-Hf and Sm-Nd data, we tested various Hf and Lu redistribution scenarios and found that decoupling of Lu/Hf from 176Hf/177Hf must postdate the accumulation of significant radiogenic 176Hf. Therefore early irradiation or diffusion cannot explain the excess 176Hf. Instead, disturbed meteorite isochrons are more likely caused by terrestrial weathering, contamination, or common laboratory procedures. The partial dissolution of phosphate minerals may predominantly remove rare earth elements including Lu, leaving relatively immobile and radiogenic Hf behind. Robust Lu-Hf (and improved Sm-Nd) meteorite geochronology will require the development of chemical or physical methods for removing unsupported radiogenic Hf and silicate-hosted terrestrial contaminants without disturbing parent-daughter ratios.

  3. Beam Studies with Electron Columns

    Energy Technology Data Exchange (ETDEWEB)

    Shiltsev, V.; Valishev, A.; Kuznetsov, G.; /Fermilab; Kamerdzhiev, V.; /Julich, Forschungszentrum; Romanov, A.; /Novosibirsk, IYF

    2009-04-01

    We report preliminary results of experimental studies of 'electron columns' in the Tevatron and in a specialized test setup. In the Tevatron, a beam of 150 GeV protons ionizes residual gas and ionization electrons are stored in an electrostatic trap immersed into strong longitudinal magnetic field. Shifts of proton betatron frequencies are observed. In the test setup, we observe effects pointing to accumulation and escape of ionization electrons.

  4. Tracking magmatic processes through Zr/Hf ratios in rocks and Hf and Ti zoning in zircons: An example from the Spirit Mountain batholith, Nevada

    Science.gov (United States)

    Lowery, Claiborne L.E.; Miller, C.F.; Walker, B.A.; Wooden, J.L.; Mazdab, F.K.; Bea, F.

    2006-01-01

    Zirconium and Hf are nearly identical geochemically, and therefore most of the crust maintains near-chondritic Zr/Hf ratios of ???35-40. By contrast, many high-silica rhyolites and granites have anomalously low Zr/Hf (15-30). As zircon is the primary reservoir for both Zr and Hf and preferentially incorporates Zr, crystallization of zircon controls Zr/ Hf, imprinting low Zr/Hf on coexisting melt. Thus, low Zr/Hf is a unique fingerprint of effective magmatic fractionation in the crust. Age and compositional zonation in zircons themselves provide a record of the thermal and compositional histories of magmatic systems. High Hf (low Zr/ Hf) in zircon zones demonstrates growth from fractionated melt, and Ti provides an estimate of temperature of crystallization (TTiZ) (Watson and Harrison, 2005). Whole-rock Zr/Hf and zircon zonation in the Spirit Mountain batholith, Nevada, document repeated fractionation and thermal fluctuations. Ratios of Zr/Hf are ???30-40 for cumulates and 18-30 for high-SiO2 granites. In zircons, Hf (and U) are inversely correlated with Ti, and concentrations indicate large fluctuations in melt composition and TTiZ (>100??C) for individual zircons. Such variations are consistent with field relations and ion-probe zircon geochronology that indicate a >1 million year history of repeated replenishment, fractionation, and extraction of melt from crystal mush to form the low Zr/Hf high-SiO2 zone. ?? 2006 The Mineralogical Society.

  5. Water Column Methylation in Estuaries

    Science.gov (United States)

    Schartup, A. T.; Calder, R.; Soerensen, A. L.; Mason, R. P.; Balcom, P. H.; Sunderland, E. M.

    2014-12-01

    Methylmercury (MeHg) is a neurotoxin that bioaccumulates in aquatic food webs and affects humans and wildlife through fish consumption. Many studies have measured active methylation/demethylation in ocean margin sediments but few have reported similar rates for the marine water column. This presentation will review available evidence for water column methylation in estuaries, including new experimental measurements of methylation/demethylation rates from a deep subarctic fjord in Labrador Canada collected in Spring and Fall of 2012-2013. We used these and other data to construct a mass budget for MeHg in the estuary and show that water column methylation (with rates ranging from 1.5 to 2.8 % day-1), is the largest contributor, followed by inputs from rivers (4.9 mol year-1), to the in situ pool of MeHg available for uptake by biota. By contrast, the sediment in this system is a net sink for MeHg (-1.5 mol year-1). We discuss the relationship between observed MeHg and other ancillary environmental factors (organic carbon, sulfur and nutrients) as well as implications for the response time of fish to future changes in mercury inputs.

  6. Determination of isothermal section of Ni-Re-Hf ternary system at 1173 K

    Institute of Scientific and Technical Information of China (English)

    王日初; 柳春雷; 金展鹏

    2002-01-01

    The phase equilibriua in the Ni-Re-Hf ternary system at 1173K were investigated by means of diffusion triple technique and electron microprobe analysis(EMPA). The experimental results indicate that two ternary intermetallics (α and β) and five binary intermetallics (Ni3Hf, Ni10Hf7, Ni11Hf9, NiHf and NiHf2) exist in the Ni-Re-Hf system at 1173 K. A tentative isothermal section of this system at 1173 K was constructed on the basis of experimental results. The isothermal section consists of nine three-phase regions, five of which are supported by the experimental data.

  7. Detrital zircon evidence for Hf isotopic evolution of granitoid crust and continental growth

    Science.gov (United States)

    Iizuka, Tsuyoshi; Komiya, Tsuyoshi; Rino, Shuji; Maruyama, Shigenori; Hirata, Takafumi

    2010-04-01

    We have determined U-Pb ages, trace element abundances and Hf isotopic compositions of approximately 1000 detrital zircon grains from the Mississippi, Congo, Yangtze and Amazon Rivers. The U-Pb isotopic data reveal the lack of >3.3 Ga zircons in the river sands, and distinct peaks at 2.7-2.5, 2.2-1.9, 1.7-1.6, 1.2-1.0, 0.9-0.4, and uniformitarian secular change in Hf isotopes of granitoid crusts; Hf isotopic compositions of granitoid crusts deviate from the mantle evolution line from about 3.3 to 2.0 Ga, the deviation declines between 2.0 and 1.3 Ga and again increases afterwards. Consideration of mantle-crust mixing models for granitoid genesis suggests that the noted isotopic trends are best explained if the rate of crust generation globally increased in two stages at around (or before) 3.3 and 1.3 Ga, whereas crustal differentiation was important in the evolution of the continental crust at 2.3-2.2 Ga and after 0.6 Ga. Reconciling the isotopic secular change in granitoid crust with that in sedimentary rocks suggests that sedimentary recycling has essentially taken place in continental settings rather than active margin settings and that the sedimentary mass significantly grew through addition of first-cycle sediments from young igneous basements, until after ˜1.3 Ga when sedimentary recycling became the dominant feature of sedimentary evolution. These findings, coupled with the lack of zircons older than 3.3 Ga in river sands, imply the emergence of large-scale continents at about 3.3 Ga with further rapid growth at around 1.3 Ga. This resulted in the major growth of the sedimentary mass between 3.3 and 1.3 Ga and the predominance of its cannibalistic recycling later.

  8. 高柱容量毛细管气相色谱柱研究进展%Progress of High Column Capacity Capillary Column

    Institute of Scientific and Technical Information of China (English)

    周阳; 吴波; 高尧华; 刘磊; 牛娜

    2012-01-01

    随着分析技术和色谱技术的发展,作为气相色谱仪的核心―毛细管柱的制备改进工作取得了丰富的研究成果。本文综述了近年来毛细管气相色谱柱,主要包括大口径、厚液膜毛细管柱、微填充柱、集束毛细管柱、环形毛细管柱及纤维填充柱,在柱容量改进方面的工作及其应用进展。%With the development of analysis and chromatography technology, the preparation of capillary gas chromatography column, as the core of capillary gas chromatography, has obtained abundant research achievements. In this paper, the progress on the development of capillary gas chromatography column capacity and its applications, mainly including those on wide-bore capillary column, micro-packed column, multicapillary column, annular capillary column and fiber packed capillary column, were reviewed.

  9. Spallation and fission products in the (p+{sup 179}Hf) and (p+{sup nat}Hf) reactions

    Energy Technology Data Exchange (ETDEWEB)

    Karamian, S.A. [Joint Institute for Nuclear Research, Moscow Region, Dubna 141980 (Russian Federation); Ur, C.A. [Horia Hulubei National Institute of Physics and Nuclear Engineering, P.O. Box MG-6, Bucharest 077125 (Romania); Induced Gamma Emission Foundation, P.O. Box 34-81, Bucharest 010044 (Romania)], E-mail: ur@pd.infn.it; Adam, J. [Joint Institute for Nuclear Research, Moscow Region, Dubna 141980 (Russian Federation); Institute of Nuclear Physics, Rez, Prague CZ-25068 (Czech Republic); Kalinnikov, V.G.; Lebedev, N.A.; Vostokin, G.K. [Joint Institute for Nuclear Research, Moscow Region, Dubna 141980 (Russian Federation); Collins, C.B. [Center for Quantum Electronics, University of Texas at Dallas, Richardson, TX 75083 (United States); Popescu, I.I. [Induced Gamma Emission Foundation, P.O. Box 34-81, Bucharest 010044 (Romania)

    2009-03-01

    Production of Hf and Lu high-spin isomers has been experimentally studied in spallation reactions induced by intermediate energy protons. Targets of enriched {sup 179}Hf (91%) and {sup nat}Hf were bombarded with protons of energy in the range from 90 to 650 MeV provided by the internal beam of the Dubna Phasotron synchrocyclotron. The activation yields of the reaction products were measured by using the {gamma}-ray spectroscopy and radiochemistry methods. The production cross-sections obtained for the {sup 179m2}Hf, {sup 178m2}Hf and {sup 177m}Lu isomers are similar to the previously measured values from the spallation of Ta, Re and W targets. Therefore, the reactions involving emission of only a few nucleons, like (p,p'), (p,p'n) and (p,2pn), can transfer high enough angular momentum to the final residual nuclei with reasonable large cross-sections. A significant gain in the isomeric yields was obtained when enriched {sup 179}Hf targets were used. The mass distribution of the residual nuclei was measured over a wide range of masses and the fission-to-spallation ratio could be deduced as a function of the projectile energy. Features of the reaction mechanism are briefly discussed.

  10. Hf-Nd isotope and trace element constraints on subduction inputs at island arcs: Limitations of Hf anomalies as sediment input indicators

    Science.gov (United States)

    Handley, Heather K.; Turner, Simon; Macpherson, Colin G.; Gertisser, Ralf; Davidson, Jon P.

    2011-04-01

    New Nd-Hf isotope and trace element data for Javanese volcanoes are combined with recently published data to place constraints on subduction inputs at the Sunda arc in Indonesia and assess the value of Hf anomalies (expressed as Hf/Hf* and Sm/Hf ratios) as tracers of such inputs. Hf anomaly does not correlate with Hf isotope ratio in Javanese lavas, however, Hf/Hf* and Sm/Hf ratios do correlate with SiO 2. Contrary to previous work, we show that Hf anomaly variation may be controlled by fractionation of clinopyroxene and/or amphibole during magmatic differentiation and does not represent the magnitude or type of subduction input in some arcs. Correlation of Sm/Hf with indices of differentiation for other arcs (e.g., Vanuatu, New Britain, and Mariana) suggests that differentiation control on Sm/Hf ratios in volcanic arc rocks may be a relatively common phenomenon. This study corroborates the use of Nd-Hf isotope co-variations in arc volcanic rocks to ascertain subduction input characteristics. The trajectories of regional volcano groups (East, Central and West Java) in Nd-Hf isotope space reveal heterogeneity in the subducted sediment input along Java, which reflects present-day spatial variations in sediment compositions on the down-going plate in the Java Trench. The high Sm/Hf ratio required in the sediment end-member for some Javanese basalts suggests that partial melting of subducted sediment occurs in the presence of residual zircon, and is inconsistent with residual monazite or allanite.

  11. Investigation and Development of Data-Driven D-Region Model for HF Systems Impacts

    Science.gov (United States)

    Eccles, J. V.; Rice, D.; Sojka, J. J.; Hunsucker, R. D.

    2002-01-01

    Space Environment Corporation (SEC) and RP Consultants (RPC) are to develop and validate a weather-capable D region model for making High Frequency (HF) absorption predictions in support of the HF communications and radar communities. The weather-capable model will assimilate solar and earth space observations from NASA satellites. The model will account for solar-induced impacts on HF absorption, including X-rays, Solar Proton Events (SPE's), and auroral precipitation. The work plan includes: I . Optimize D-region model to quickly obtain ion and electron densities for proper HF absorption calculations. 2. Develop indices-driven modules for D-region ionization sources for low, mid, & high latitudes including X-rays, cosmic rays, auroral precipitation, & solar protons. (Note: solar spectrum & auroral modules already exist). 3. Setup low-cost monitors of existing HF beacons and add one single-frequency beacon. 4. Use PENEX HF-link database with HF monitor data to validate D-region/HF absorption model using climatological ionization drivers. 5. Develop algorithms to assimilate NASA satellite data of solar, interplanetary, and auroral observations into ionization source modules. 6. Use PENEX HF-link & HF-beacon data for skill score comparison of assimilation versus climatological D-region/HF absorption model. Only some satellites are available for the PENEX time period, thus, HF-beacon data is necessary. 7. Use HF beacon monitors to develop HF-link data assimilation algorithms for regional improvement to the D-region/HF absorption model.

  12. Serpentinization Changes Nd, but not Hf Isotopes of Abyssal Peridotites

    Science.gov (United States)

    Bizimis, M.; Frisby, C. P.; Mallick, S.

    2015-12-01

    Serpentinization of the oceanic lithosphere is a known sink for fluid mobile elements (B, Cl, Li, Sr, etc.), while high field strength elements (HFSE: e.g., Hf, Zr, Ti, Nb) are thought to be unaffected by it. In contrast, the fate of REE during serpentinization is equivocal. Correlations between REE and HFSE concentrations in abyssal peridotites suggest control by magmatic processes (Niu, 2004, J. Pet), while some LREE enrichments in serpentinized peridotites compared to their clinopyroxene (cpx) and Nd, Sr isotope data (Delacour et al., 2008, Chem. Geol.) imply seawater-derived REE addition to the mantle protolith (Paulick et al., 2006, Chem. Geol). To further constrain peridotite-seawater interaction during serpentinization we compare bulk rock and cpx Hf and Nd isotope data in partially (up to ~70%) serpentinized abyssal peridotites (9-16°E South West Indian Ridge). We also present a new method that improves yields in Hf, Nd and Pb separations from depleted (90% of Hf, Zr, Ti are retained in the residue. LA-ICPMS data shows that serpentine after olivine typically has higher LREE/HREE ratios than cpx, pronounced negative Ce anomalies, high U, Sr concentrations and low HFSE, unlike the coexisting cpx. These data are consistent with some seawater-derived LREE addition to peridotite during serpentinization, localized in the serpentine and other secondary phases, while cpx retains the magmatic value. This process will lower the Sm/Nd relative to Lu/Hf ratio in the peridotite and can lead to decoupled radiogenic Hf and unradiogenic Nd isotopes upon recycling and aging. Our data further testifies to the fidelity of Hf isotopes in tracing mantle processes, even in serpentinized rocks.

  13. Joint Efforts Towards European HF Radar Integration

    Science.gov (United States)

    Rubio, A.; Mader, J.; Griffa, A.; Mantovani, C.; Corgnati, L.; Novellino, A.; Schulz-Stellenfleth, J.; Quentin, C.; Wyatt, L.; Ruiz, M. I.; Lorente, P.; Hartnett, M.; Gorringe, P.

    2016-12-01

    During the past two years, significant steps have been made in Europe for achieving the needed accessibility to High Frequency Radar (HFR) data for a pan-European use. Since 2015, EuroGOOS Ocean Observing Task Teams (TT), such as HFR TT, are operational networks of observing platforms. The main goal is on the harmonization of systems requirements, systems design, data quality, improvement and proof of the readiness and standardization of HFR data access and tools. Particular attention is being paid by HFR TT to converge from different projects and programs toward those common objectives. First, JERICO-NEXT (Joint European Research Infrastructure network for Coastal Observatory - Novel European eXpertise for coastal observaTories, H2020 2015 Programme) will contribute on describing the status of the European network, on seeking harmonization through exchange of best practices and standardization, on developing and giving access to quality control procedures and new products, and finally on demonstrating the use of such technology in the general scientific strategy focused by the Coastal Observatory. Then, EMODnet (European Marine Observation and Data Network) Physics started to assemble HF radar metadata and data products within Europe in a uniform way. This long term program is providing a combined array of services and functionalities to users for obtaining free of charge data, meta-data and data products on the physical conditions of European sea basins and oceans. Additionally, the Copernicus Marine Environment Monitoring Service (CMEMS) delivers from 2015 a core information service to any user related to 4 areas of benefits: Maritime Safety, Coastal and Marine Environment, Marine Resources, and Weather, Seasonal Forecasting and Climate activities. INCREASE (Innovation and Networking for the integration of Coastal Radars into EuropeAn marine SErvices - CMEMS Service Evolution 2016) will set the necessary developments towards the integration of existing European

  14. First-principles study of the Hf-based Heusler alloys: Hf2CoGa and Hf2CoIn

    Science.gov (United States)

    Hu, Yan; Zhang, Jian-Min

    2017-01-01

    The electronic structures and magnetic properties of the new Heusler alloys Hf2CoGa and Hf2CoIn have been studied by using the first-principles projector augmented wave (PAW) potential within the generalized gradient approximation (GGA). Both Hf2CoGa and Hf2CoIn Heusler alloys have the half-metallic character and completely (100%) spin polarization at the Fermi level (EF) and the indirect band gaps of 0.733 eV and 0.654 eV, respectively, in the minority spin channel. The total magnetic moments μt are all 2μB per formula unit, linearly scaled with the total number of valence electrons (Zt) by μt=Zt-18 and the atomic magnetic moments have localized character due to less affected by deformations. The origin of the indirect band gaps for these two new Heusler alloys is well understood. These two new Heusler alloys are the ideal candidates for spintronic devices.

  15. Global abundance of planktonic heterotrophic protists in the deep ocean.

    Science.gov (United States)

    Pernice, Massimo C; Forn, Irene; Gomes, Ana; Lara, Elena; Alonso-Sáez, Laura; Arrieta, Jesus M; del Carmen Garcia, Francisca; Hernando-Morales, Victor; MacKenzie, Roy; Mestre, Mireia; Sintes, Eva; Teira, Eva; Valencia, Joaquin; Varela, Marta M; Vaqué, Dolors; Duarte, Carlos M; Gasol, Josep M; Massana, Ramon

    2015-03-01

    The dark ocean is one of the largest biomes on Earth, with critical roles in organic matter remineralization and global carbon sequestration. Despite its recognized importance, little is known about some key microbial players, such as the community of heterotrophic protists (HP), which are likely the main consumers of prokaryotic biomass. To investigate this microbial component at a global scale, we determined their abundance and biomass in deepwater column samples from the Malaspina 2010 circumnavigation using a combination of epifluorescence microscopy and flow cytometry. HP were ubiquitously found at all depths investigated down to 4000 m. HP abundances decreased with depth, from an average of 72±19 cells ml(-1) in mesopelagic waters down to 11±1 cells ml(-1) in bathypelagic waters, whereas their total biomass decreased from 280±46 to 50±14 pg C ml(-1). The parameters that better explained the variance of HP abundance were depth and prokaryote abundance, and to lesser extent oxygen concentration. The generally good correlation with prokaryotic abundance suggested active grazing of HP on prokaryotes. On a finer scale, the prokaryote:HP abundance ratio varied at a regional scale, and sites with the highest ratios exhibited a larger contribution of fungi molecular signal. Our study is a step forward towards determining the relationship between HP and their environment, unveiling their importance as players in the dark ocean's microbial food web.

  16. HF omnidirectional spectral CW auroral radar (HF-OSCAR) at very high latitude. Part 1: Technique

    Science.gov (United States)

    Olesen, J. K.; Jacobsen, K. E.; Stauning, P.; Henriksen, S.

    1983-12-01

    An HF system for studies of very high latitude ionospheric irregularities was described. Radio aurora from field-aligned E-region irregularities of the Slant E Condition type were discussed. The complete system combines an ionosonde, a 12 MHz pulse radar and a 12 MHz bistatic CW Doppler-range set-up. The two latter units use alternately a 360 deg rotating Yagi antenna. High precision oscillators secure the frequency stability of the Doppler system in which the received signal is mixed down to a center frequency of 500 Hz. The Doppler shift range is max + or - 500 Hz. The received signal is recorded in analog form on magnetic tape and may be monitored visually and audibly. Echo range of the CW Doppler signal is obtained by a 150 Hz amplitude modulation of the transmitted signal and phase comparison with the backscattered signal.

  17. Comparison of HfAlO, HfO2/Al2O3, and HfO2 on n-type GaAs using atomic layer deposition

    Science.gov (United States)

    Lu, Bin; Lv, Hongliang; Zhang, Yuming; Zhang, Yimen; Liu, Chen

    2016-11-01

    Different high-permittivity (high-k) gate dielectric structures of HfO2, HfAlO, and HfO2/Al2O3 deposited on HF-etched n-GaAs using ALD have been investigated. It has been demonstrated that the stacked structure of HfO2/Al2O3 has the lowest interface state density of 8.12 × 1012eV-1 cm-2 due to the "self-cleaning" reaction process, but the sample of HfAlO shows much better frequency dispersion and much higher dielectric permittivity extracted from the C-V curves. The investigation reveals that the electrical properties of gate dielectrics are improved by introducing alumina into HfO2.

  18. A High Resolution Fourier-Transform Spectrometer for the Measurement of Atmospheric Column Abundances

    Science.gov (United States)

    Cageao, R.; Sander, S.; Blavier, J.; Jiang, Y.; Nemtchinov, V.

    2000-01-01

    A compact, high resolution Fourier-transform spectrometer for atmospheric near ultraviolet spectroscopy has been installed at the Jet Propulsion Laboratory's Table Mountain Facility (34.4N, 117.7 W, elevation 2290m).

  19. Mechanical properties of cast Ti-Hf alloys.

    Science.gov (United States)

    Sato, Hideki; Kikuchi, Masafumi; Komatsu, Masashi; Okuno, Osamu; Okabe, Toru

    2005-02-15

    This study examined the mechanical properties of a series of Ti-Hf alloys. Titanium alloys with 10 to 40 mass % Hf were made with titanium and hafnium sponge in an argon-arc melting furnace. Specimens cast into magnesia-based investment molds were tested for yield strength, tensile strength, percentage elongation, and modulus of elasticity. Vickers microhardness was determined at 25 to 600 microm from the cast surface. X-ray diffractometry was also performed. Commercially pure Ti (CP Ti) and pure Ti prepared from titanium sponge were used as controls. The data (n = 5) were analyzed with a one-way ANOVA and the Student-Newman-Keuls test (alpha = 0.05). The diffraction peaks of all the metals matched those for alpha Ti; no beta phase peaks were found. Alloys with Hf > or = 25% had significantly (p 0.05) in elongation among all the Ti-Hf alloys and CP Ti, whereas the elongation of alloys with Hf > or = 30% was significantly (p alloys tested can be considered viable alternatives to CP Ti because they were stronger than CP Ti and had similar elongation.

  20. HfO2 Gate Dielectrics for Future Generation of CMOS Device Application

    Institute of Scientific and Technical Information of China (English)

    H.Y.Yu; J.F.Kang; Ren Chi; M.F.Li; D.L.Kwong

    2004-01-01

    The material and electrical properties of HfO2 high-k gate dielectric are reported.In the first part,the band alignment of HfO2 and (HfO2)x(Al2O3)1-x to (100)Si substrate and their thermal stability are studied by X-ray photoelectron spectroscopy and TEM.The energy gap of (HfO2)x(Al2O3)1-x,the valence band offset,and the conduction band offset between (HfO2)x(Al2O3)1-x and the Si substrate as functions of x are obtained based on the XPS results.Our XPS results also demonstrate that both the thermal stability and the resistance to oxygen diffusion of HfO2 are improved by adding Al to form Hf aluminates.In the second part,a thermally stable and high quality HfN/HfO2 gate stack is reported.Negligible changes in equivalent oxide thickness (EOT),gate leakage,and work function (close to Si mid-gap) of HfN/HfO2 gate stack are demonstrated even after 1000℃ post-metal annealing(PMA),which is attributed to the superior oxygen diffusion barrier of HfN as well as the thermal stability of the HfN/HfO2 interface.Therefore,even without surface nitridation prior to HfO2 deposition,the EOT of HfN/HfO2 gate stack has been successfully scaled down to less than 1nm after 1000℃ PMA with excellent leakage and long-term reliability.The last part demonstrates a novel replacement gate process employing a HfN dummy gate and sub-1nm EOT HfO2 gate dielectric.The excellent thermal stability of the HfN/HfO2 gate stack enables its use in high temperature CMOS processes.The replacement of HfN with other metal gate materials with work functions adequate for n- and p-MOS is facilitated by a high etch selectivity of HfN with respect to HfO2,without any degradation to the EOT,gate leakage,or TDDB characteristics of HfO2.

  1. Elastic stability of non-uniform columns

    Science.gov (United States)

    Lee, S. Y.; Kuo, Y. H.

    1991-07-01

    A simple and efficient method is proposed to investigate the elastic stability of three different tapered columns subjected to uniformly distributed follower forces. The influences of the boundary conditions and taper ratio on critical buckling loads are investigated. The critical buckling loads of columns of rectangular cross section with constant depth and linearly varied width ( T1), constant width and linearly varied depth ( T2) and double taper ( T3) are investigated. Among the three different non-uniform columns considered, taper ratio has the greatest influence on the critical buckling load of column T3 and the lowest influence on that of column T1. The types of instability mechanisms for hinged-hinged and cantilever non-uniform columns are divergence and flutter respectively. However, for clamped-hinged and clamped-clamped non-uniform columns, the type of instability mechanism for column T1 is divergence, while that for columns T2 and T3 is divergence only when the taper ratio of the columns is greater than certain critical values and flutter for the rest value of taper ratio. When the type of instability mechanism changes from divergence to flutter, there is a finite jump for the critical buckling load. The influence of taper ratio on the elastic stability of cantilever column T3 is very sensitive for small values of the taper ratio and there also exist some discontinieties in the critical buckling loads of flutter instability. For a hinged-hinged non-uniform column ( T2 or T3) with a rotational spring at the left end of the column, when the taper ratio is less than the critical value the instability mechanism changes from divergence to flutter as the rotational spring constant is increased. For a clamped-elastically supported non-uniform column, when the taper ratio is greater than the critical value the instability mechanism changes from flutter to divergence as the translational spring constant is increased.

  2. Pressure-induced novel compounds in the Hf-O system from first-principles calculations

    Science.gov (United States)

    Zhang, Jin; Oganov, Artem R.; Li, Xinfeng; Xue, Kan-Hao; Wang, Zhenhai; Dong, Huafeng

    2015-11-01

    Using first-principles evolutionary simulations, we have systematically investigated phase stability in the Hf-O system at pressure up to 120 GPa. New compounds Hf5O2,Hf3O2 , HfO, and HfO3 are discovered to be thermodynamically stable at certain pressure ranges. Two new high-pressure phases are found for Hf2O : one with space group Pnnm and anti-CaCl2-type structure, another with space group I 41/amd. Pnnm-HfO3 shows interesting structure, simultaneously containing oxide O2 - and peroxide [O-O]2 - anions. Remarkably, it is P 6 ¯2 m -HfO rather than OII-HfO2 that exhibits the highest mechanical characteristics among Hf-O compounds. Pnnm-Hf2O , Imm2-Hf5O2 ,P 3 ¯1 m -Hf2O , and P 4 ¯m 2 -Hf2O3 phases also show superior mechanical properties; theoretically these phases become metastable phases to ambient pressure and their properties can be exploited.

  3. Effect of HF leaching on 14C dates of pottery

    Science.gov (United States)

    Goslar, Tomasz; Kozłowski, Janusz; Szmyt, Marzena; Czernik, Justyna

    2013-01-01

    This paper presents the experiments with 14C dating of two potsherds, which contained carbon dispersed rather homogeneously in their clay fabric. After AAA treatment, the potsherds still appeared to be contaminated with young carbon, presumably connected with humic acids. To make removal of humic acids more effective, we treated the sherds with HF acid of different concentration. The 14C results obtained demonstrate that HF treatment indeed helps to remove humic contaminants, but it also mobilizes carbon bound to raw clay, which may make 14C dates too old. We conclude therefore, that using a simple combination of HF and AAA treatment seems insufficient in reliable 14C dating of carbon homogeneously dispersed in the volume of potsherds.

  4. Gaseous abundances in M82

    CERN Document Server

    Ranalli, P; Origlia, L; Maiolino, R; Makishima, K; Ranalli, Piero; Comastri, Andrea; Origlia, Livia; Maiolino, Roberto; Makishima, Kazuo

    2005-01-01

    We present the preliminary analysis of a deep (100ks) XMM-Newton observation of M82. The spatial distribution of the abundances of chemical elements (Fe, O, Ne, Mg, Si, S) is investigated through narrow-band imaging analisys and spatially-resolved spectroscopy. We find that the abundances of alpha-elements follow a bipolar distribution, these elements being more abundant in the gaseous outflow than in the galaxy centre. This behaviour is found to be more marked for lighter elements (O, Ne) than for heavier elements.

  5. The Status of Rotational Nonequilibrium in HF Chemical Lasers

    Science.gov (United States)

    1986-05-01

    later study from the same laboratory, Copeland et al. 5 3 used a NdYAG dye laser to pump HF into v = 2, j, and an HF pulsed laser to probe various P 2(J... Weston , Jr., J. Chem. Phys. 77, 4776 (1982). 51. J. J. Hinchen and R. H. Hobbs, Appl. Phys. 50, 628 (1979). 52. j. K. Lambert, G. M. Jursich, and F. F...Crim, Chem. Phys. Lett. 71, 258 (1980). 53. R. A. Copeland , D. J. Pearson, and F. F. Crim, Chem. Phys. Lett. 81, 541 (1981). 54. T. J. Foster and F. F

  6. New active load voltage clamp for HF-link converters

    Energy Technology Data Exchange (ETDEWEB)

    Ljusev, P.; Andersen, M.A.E.

    2005-07-01

    This paper proposes a new active clamp for HF-link converters, which features very high efficiency by returning the clamped energy back to the primary side through a small auxiliary converter. It also increases the reliability of HF-link converters by providing an alternative load current path during malfunctions of the secondary bidirectional bridge. The feasibility of the approach is shown on audio power amplifier prototype. New integrated magnetics design is presented that incorporates both the main power and auxiliary transformer on the same magnetic core. (au)

  7. HF-induced airglow at magnetic zenith: theoretical considerations

    Directory of Open Access Journals (Sweden)

    E. V. Mishin

    2005-01-01

    Full Text Available Observations of airglow at 630nm (red line and 557.7nm (green line during HF modification experiments at the High Frequency Active Auroral Research Program (HAARP heating facility are analyzed. We propose a theoretical framework for understanding the generation of Langmuir and ion acoustic waves during magnetic zenith injections. We show that observations of HF-induced airglow in an underdense ionosphere as well as a decrease in the height of the emitting volume are consistent with this scenario.

  8. HF-hash : Hash Functions Using Restricted HFE Challenge-1

    CERN Document Server

    Dey, Dhananjoy; Gupta, Indranath Sen

    2009-01-01

    Vulnerability of dedicated hash functions to various attacks has made the task of designing hash function much more challenging. This provides us a strong motivation to design a new cryptographic hash function viz. HF-hash. This is a hash function, whose compression function is designed by using first 32 polynomials of HFE Challenge-1 with 64 variables by forcing remaining 16 variables as zero. HF-hash gives 256 bits message digest and is as efficient as SHA-256. It is secure against the differential attack proposed by Chabaud and Joux as well as by Wang et. al. applied to SHA-0 and SHA-1.

  9. Hf--Co--B alloys as permanent magnet materials

    Energy Technology Data Exchange (ETDEWEB)

    McGuire, Michael Alan; Rios, Orlando; Ghimire, Nirmal Jeevi

    2017-01-24

    An alloy composition is composed essentially of Hf.sub.2-XZr.sub.XCo.sub.11B.sub.Y, wherein 0Hf.sub.2-XZr.sub.XCo.sub.11B.sub.Y, wherein 0.ltoreq.X<2 and 0

  10. First HF radar measurements of summer mesopause echoes at SURA

    Directory of Open Access Journals (Sweden)

    A. N. Karashtin

    Full Text Available HF sounding of the mesosphere was first carried out at SURA in summer 1994 at frequencies in the range 8–9 MHz using one of the sub-arrays of the SURA heating facility. The observations had a range resolution of 3 km. Almost all measurements indicated the presence of strong radar returns from altitudes between 83 and 90 km with features very similar to VHF measurements of mesopause summer echoes at mid-latitudes and polar mesopause summer echoes. In contrast to VHF observations, HF mesopause echoes are almost always present.

  11. New active load voltage clamp for HF-link converters

    DEFF Research Database (Denmark)

    Ljusev, Petar; Andersen, Michael Andreas E.

    2005-01-01

    This paper proposes a new active clamp for HF-link converters, which features very high efficiency by returning the clamped energy back to the primary side through a small auxiliary converter. It also increases the reliability of HF-link converters by providing an alternative load current path du...... during malfunctions of the secondary bidirectional bridge. The feasibility of the approach is shown on audio power amplifier prototype. New integrated magnetics design is presented that incorporates both the main power and auxiliary transformer on the same magnetic core....

  12. First HF radar measurements of summer mesopause echoes at SURA

    Science.gov (United States)

    Karashtin, A. N.; Shlyugaev, Y. V.; Abramov, V. I.; Belov, I. F.; Berezin, I. V.; Bychkov, V. V.; Eryshev, E. B.; Komrakov, G. P.

    1997-07-01

    HF sounding of the mesosphere was first carried out at SURA in summer 1994 at frequencies in the range 8-9 MHz using one of the sub-arrays of the SURA heating facility. The observations had a range resolution of 3 km. Almost all measurements indicated the presence of strong radar returns from altitudes between 83 and 90 km with features very similar to VHF measurements of mesopause summer echoes at mid-latitudes and polar mesopause summer echoes. In contrast to VHF observations, HF mesopause echoes are almost always present.

  13. European coordination for coastal HF radar data in EMODnet Physics

    Science.gov (United States)

    Mader, Julien; Novellino, Antonio; Gorringe, Patrick; Griffa, Annalisa; Schulz-Stellenfleth, Johannes; Montero, Pedro; Montovani, Carlo; Ayensa, Garbi; Vila, Begoña; Rubio, Anna; Sagarminaga, Yolanda

    2015-04-01

    Historically, joint effort has been put on observing open ocean, organizing, homogenizing, sharing and reinforcing the impact of the acquired information based on one technology: ARGO with profilers Argo floats, EuroSites, ESONET-NoE, FixO3 for deep water platforms, Ferrybox for stations in ships of opportunities, and GROOM for the more recent gliders. This kind of networking creates synergies and makes easier the implementation of this source of data in the European Data exchange services like EMODnet, ROOSs portals, or any applied services in the Blue economy. One main targeted improvement in the second phase of EMODnet projects is the assembling of data along coastline. In that sense, further coordination is recommended between platform operators around a specific technology in order to make easier the implementation of the data in the platforms (4th EuroGOOS DATAMEQ WG). HF radar is today recognized internationally as a cost-effective solution to provide high spatial and temporal resolution current maps (depending on the instrument operation frequency, covering from a few kilometres offshore up to 200 km) that are needed for many applications for issues related to ocean surface drift or sea state characterization. Significant heterogeneity still exists in Europe concerning technological configurations, data processing, quality standards and data availability. This makes more difficult the development of a significant network for achieving the needed accessibility to HF Radar data for a pan European use. EuroGOOS took the initiative to lead and coordinate activities within the various observation platforms by establishing a number of Ocean Observing Task Teams such as HF-Radars. The purpose is to coordinate and join the technological, scientific and operational HF radar communities at European level. The goal of the group is on the harmonization of systems requirements, systems design, data quality, improvement and proof of the readiness and standardization of

  14. Produced fluids separation using a coalascer column

    Energy Technology Data Exchange (ETDEWEB)

    Renouf, G.; Soveran, D.; Soveran, L. [Saskatchewan Research Council, Saskatoon, SK (Canada)

    2005-07-01

    This paper reports the results of a laboratory study in which a coalescer column was used to successfully remove water from produced heavy oil emulsions. The coalescer column is a simple, inexpensive, and environmentally friendly technology that can improve basic sediment and water values after 4 hours of settling time by about 38 per cent. The laboratory study tested the use of the column, and the effects of column length, column packing size, temperature, flow rate, demulsifier concentration, and water addition. More than 100 tests were conducted and 24 pairs of tests compared the treating effects with and without the column. The use of the coalescer column in the treatment facility resulted in a a reduction of demulsifier concentration from 250 ppm to 70 ppm, translating to an annual cost savings of $320,000 to $1,100,000 per battery. Incorporating the coalescer column also allowed operators to reduce both temperatures and demulsifier concentrations. The column also promoted faster treating. Water droplets grew by as much as 34 per cent, suggesting that treating time could be faster by 21 to 80 per cent. It was concluded that the coalescer column was very successful at improving water removal from heavy oil battery emulsions. 22 refs., 9 tabs., 7 figs.

  15. 182Hf-182W age dating of a 26Al-poor inclusion and implications for the origin of short-lived radioisotopes in the early Solar System.

    Science.gov (United States)

    Holst, Jesper C; Olsen, Mia B; Paton, Chad; Nagashima, Kazuhide; Schiller, Martin; Wielandt, Daniel; Larsen, Kirsten K; Connelly, James N; Jørgensen, Jes K; Krot, Alexander N; Nordlund, Ake; Bizzarro, Martin

    2013-05-28

    Refractory inclusions [calcium-aluminum-rich inclusions, (CAIs)] represent the oldest Solar System solids and provide information regarding the formation of the Sun and its protoplanetary disk. CAIs contain evidence of now extinct short-lived radioisotopes (e.g., (26)Al, (41)Ca, and (182)Hf) synthesized in one or multiple stars and added to the protosolar molecular cloud before or during its collapse. Understanding how and when short-lived radioisotopes were added to the Solar System is necessary to assess their validity as chronometers and constrain the birthplace of the Sun. Whereas most CAIs formed with the canonical abundance of (26)Al corresponding to (26)Al/(27)Al of ∼5 × 10(-5), rare CAIs with fractionation and unidentified nuclear isotope effects (FUN CAIs) record nucleosynthetic isotopic heterogeneity and (26)Al/(27)Al of Solar System, including the origin of short-lived radioisotopes. However, their chronology is unknown. Using the (182)Hf-(182)W chronometer, we show that a FUN CAI recording a condensation origin from a solar gas formed coevally with canonical CAIs, but with (26)Al/(27)Al of ∼3 × 10(-6). The decoupling between (182)Hf and (26)Al requires distinct stellar origins: steady-state galactic stellar nucleosynthesis for (182)Hf and late-stage contamination of the protosolar molecular cloud by a massive star(s) for (26)Al. Admixing of stellar-derived (26)Al to the protoplanetary disk occurred during the epoch of CAI formation and, therefore, the (26)Al-(26)Mg systematics of CAIs cannot be used to define their formation interval. In contrast, our results support (182)Hf homogeneity and chronological significance of the (182)Hf-(182)W clock.

  16. Column flotation testing at Suncor Energy Inc.

    Energy Technology Data Exchange (ETDEWEB)

    Cleyle, P.; Lee, L. [Suncor Energy Inc. Oil Sands, Fort McMurray, AB (Canada)

    2006-07-01

    The operations at Suncor's primary extraction plant were reviewed with reference to the column flotation process and the history of column flotation testing at Suncor. Tertiary bitumen recovery processes were also reviewed. In March and August 2005, an in-plant pilot scale column flotation test was conducted at Suncor's Millennium Primary Extraction plant near Fort McMurray, Alberta. The purpose was to evaluate the feasibility of using column flotation for tertiary bitumen recovery from cyclone overflow. The test was performed in a 4 ft diameter by 25 ft high column to determine the effects of column feed flow rate, froth wash water supply, and froth depth. The feed ranged from 0.14 to 3.79 wt per cent bitumen. Feed flow rate ranged from 59 to 237 USGPM. The test results indicated that wash water reduced froth mineral content. Increasing the wash water did not make any difference in mineral rejection. Although bitumen upgrading improved when the test column was operated at a deeper froth depth, the mineral content was not reduced. Both mechanical cell and flotation column tailings samples were collected in the flotation column tests. The average tailings composition for the last cell in the tertiary mechanical bank was 0.22 per cent bitumen, 12.10 per cent mineral, and 87.66 per cent water. At an average test column feed rate of 158 USGPM, the average tailings composition was 0.23 per cent bitumen, 12.13 per cent mineral, and 87.62 per cent water. It was concluded that flotation columns are capable of producing a tailings product similar to that of the tertiary mechanical bank. Therefore, it is feasible to use flotation columns as an alternative to mechanical cells. In fact, since there are no rotating parts requiring off-line maintenance work, flotation columns may be a better alternative from a maintenance and operations perspective. tabs., figs.

  17. Oscillating water column structural model

    Energy Technology Data Exchange (ETDEWEB)

    Copeland, Guild [Sandia National Lab. (SNL-NM), Albuquerque, NM (United States); Bull, Diana L [Sandia National Lab. (SNL-NM), Albuquerque, NM (United States); Jepsen, Richard Alan [Sandia National Lab. (SNL-NM), Albuquerque, NM (United States); Gordon, Margaret Ellen [Sandia National Lab. (SNL-NM), Albuquerque, NM (United States)

    2014-09-01

    An oscillating water column (OWC) wave energy converter is a structure with an opening to the ocean below the free surface, i.e. a structure with a moonpool. Two structural models for a non-axisymmetric terminator design OWC, the Backward Bent Duct Buoy (BBDB) are discussed in this report. The results of this structural model design study are intended to inform experiments and modeling underway in support of the U.S. Department of Energy (DOE) initiated Reference Model Project (RMP). A detailed design developed by Re Vision Consulting used stiffeners and girders to stabilize the structure against the hydrostatic loads experienced by a BBDB device. Additional support plates were added to this structure to account for loads arising from the mooring line attachment points. A simplified structure was designed in a modular fashion. This simplified design allows easy alterations to the buoyancy chambers and uncomplicated analysis of resulting changes in buoyancy.

  18. Chlorine Abundances in Cool Stars

    CERN Document Server

    Maas, Z G; Hinkle, K

    2016-01-01

    Chlorine abundances are reported in 15 evolved giants and one M dwarf in the solar neighborhood. The Cl abundance was measured using the vibration-rotation 1-0 P8 line of H$^{35}$Cl at 3.69851 $\\mu$m. The high resolution L-band spectra were observed using the Phoenix infrared spectrometer on the Kitt Peak Mayall 4m telescope. The average [$^{35}$Cl/Fe] abundance in stars with --0.72$<$[Fe/H]$<$0.20 is [$^{35}$Cl/Fe]=(--0.10$\\pm$0.15) dex. The mean difference between the [$^{35}$Cl/Fe] ratios measured in our stars and chemical evolution model values is (0.16$\\pm$0.15) dex. The [$^{35}$Cl/Ca] ratio has an offset of $\\sim$0.35 dex above model predictions suggesting chemical evolution models are under producing Cl at the high metallicity range. Abundances of C, N, O, Si, and Ca were also measured in our spectral region and are consistent with F and G dwarfs. The Cl versus O abundances from our sample match Cl abundances measured in planetary nebula and \\ion{H}{2} regions. In one star where both H$^{35}$Cl a...

  19. Study on a continuous heat integrated distillation column

    Energy Technology Data Exchange (ETDEWEB)

    Glenchur, T.; Govind, R.

    1987-12-01

    A novel continuous heat integrated distillation column called a concentric column has been studied using computer simulation. It is shown that a concentric column is a novel implementation of a thermodynamically reversible distillation column and has a lower energy loss than an ordinary distillation column. Their studies show that a concentric column has reduced column height, since the stripping section is configured concentrically around the rectifying section, and uses less utilities than a conventional column.

  20. The jet flotation column control system

    Energy Technology Data Exchange (ETDEWEB)

    Xu Zhiqiang; Ming Shangzhi; Liu Lijian; Huangfu Jinghua; Huo Sen; Zhang Rongzeng [China Univ. of Mining and Technology, Beijing (China). Mineral Processing Dept.; Yang Hongjun [Hebi Coal Mine Administrative (China)

    1998-12-31

    Compared with the conventional mechanical flotation column, the jet flotation column has the advantages of high selectivity of separation, low investment and production cost, low floor space requirement, low dosage of reagent, easy control; it is more suitable to process fine particles. Recently, many new types of flotation columns have been developed with new methods. Mineral Processing Dept., China University of Mining and Technology (Beijing) designed an aerated, double-jet flotation column in the lab and the industrial trial will be put into operation. One of the significant characteristics of the new type of flotation column is high selectivity of separation, fast bubble mineralization speed. As it is sensitive to various factors, a control system for flotation column has been developed to stabilize the working condition, and this set of control system has been operated in the lab experiment.

  1. Evolution of E2 transition strength in deformed hafnium isotopes from new measurements on $^{172}$Hf, $^{174}$Hf, and $^{176}$Hf

    CERN Document Server

    Rudigier, M; Dannhoff, M; Gerst, R-B; Jolie, J; Saed-Samii, N; Stegemann, S; Régis, J-M; Robledo, L M; Rodríguez-Guzmán, R; Blazhev, A; Fransen, Ch; Warr, N; Zell, K O

    2015-01-01

    The available data for E2 transition strengths in the region between neutron-deficient Hf and Pt isotopes are far from complete. More and precise data are needed to enhance the picture of structure evolution in this region and to test state-of-the-art nuclear models. In a simple model, the maximum collectivity is expected at the middle of the major shell. However, for actual nuclei, this picture may no longer be the case, and one should use a more realistic nuclear-structure model. We address this point by studying the spectroscopy of Hf. We remeasure the 2^+_1 half-lives of 172,174,176Hf, for which there is some disagreement in the literature. The main goal is to measure, for the first time, the half-lives of higher-lying states of the rotational band. The new results are compared to a theoretical calculation for absolute transition strengths. The half-lives were measured using \\gamma-\\gamma and conversion-electron-\\gamma delayed coincidences with the fast timing method. For the determination of half-lives i...

  2. Distribution Coefficients of Elements on TODGA Resin in HNO3, HCl and HF: Application to Determination of Lu/Hf Ratio and Hf Isotopic Composition in Meteorites

    Science.gov (United States)

    Pourmand, A.; Dauphas, N.

    2008-03-01

    Distribution coefficients for 60 elements on TODGA resin are presented along with a robust single-column protocol for separation of HSFE, lanthanides and actinides in meteorites and terrestrial rocks for high-precision isotope analysis.

  3. SNAP-TITE Composite Column Reinforcement

    OpenAIRE

    ECT Team, Purdue

    2007-01-01

    Recent earthquakes throughout the world have demonstrated the vulnerabilities of older reinforced concrete columns to seismic deformation demands. The Snap Tite Composite Column Reinforcement strengthens a concrete column by confining it in an external composite jacket, which prevents the concrete from expanding during seismic activity or prolonged freeze-thaw cycles. The pre-manufactured fiberglass jacket is comprised of glass fibers and corrosion resistant isopolyester resins.

  4. Parametric resonance in concrete beam-columns

    OpenAIRE

    Sharma,Mamta R.; Singh,Arbind K; Benipal,Gurmail S

    2014-01-01

    A dynamic instability, called parametric resonance, is exhibited by undampedelastic beam-columns when under the action of pulsating axial force. The scope of the existing theory of parametric resonance is restricted to physically linear beam-columns undergoing finite lateral displacements. In this Paper, the dynamic behaviour of physically nonlinear elastic cracked concrete beam-columns under pulsating axial force and constant lateral force is investigated. The constitutive equations derived ...

  5. Comparative study of atomic-layer-deposited HfO2/Al2O3, Hf0.8Al0.2Ox and Hf0.5Al0.5Ox on N-GaAs

    Science.gov (United States)

    Yu, Xinjiang; Lv, Hongliang; Zhang, Yuming; Zhang, Yimen; Qin, Zaiyang

    2016-11-01

    Interfacial properties of n-GaAs metal-oxide-semiconductor (MOSCAPs) with the gate dielectrics of HfO2/Al2O3, Hf0.8Al0.2Ox and Hf0.5Al0.5Ox are investigated. The results reveal that Hf0.5Al0.5Ox has larger permittivity and lower interface trap density than that of HfO2/Al2O3. In order to explain the result from the physical perspective, the XPS tests of all three samples are performed. It is found that the main reason to form interface trap of three samples treated with 500 °C post-deposition annealing, is attributed to the interfacial component of Ga2O3 and The Hf0.5Al0.5Ox dielectric is beneficial to reducing the formation of Ga2O3.

  6. Design of an Extractive Distillation Column for the Environmentally Benign Separation of Zirconium and Hafnium Tetrachloride for Nuclear Power Reactor Applications

    Directory of Open Access Journals (Sweden)

    Le Quang Minh

    2015-09-01

    Full Text Available Nuclear power with strengthened safety regulations continues to be used as an important resource in the world for managing atmospheric greenhouse gases and associated climate change. This study examined the environmentally benign separation of zirconium tetrachloride (ZrCl4 and hafnium tetrachloride (HfCl4 for nuclear power reactor applications through extractive distillation using a NaCl-KCl molten salt mixture. The vapor–liquid equilibrium behavior of ZrCl4 and HfCl4 over the molten salt system was correlated with Raoult’s law. The molten salt-based extractive distillation column was designed optimally using a rigorous commercial simulator for the feasible separation of ZrCl4 and HfCl4. The molten salt-based extractive distillation approach has many potential advantages for the commercial separation of ZrCl4 and HfCl4 compared to the conventional distillation because of its milder temperatures and pressure conditions, smaller number of required separation trays in the column, and lower energy requirement for separation, while still taking the advantage of environmentally benign feature by distillation. A heat-pump-assisted configuration was also explored to improve the energy efficiency of the extractive distillation process. The proposed enhanced configuration reduced the energy requirement drastically. Extractive distillation can be a promising option competing with the existing extraction-based separation process for zirconium purification for nuclear power reactor applications.

  7. Abundance, biomass and composition of spring ice algal and phytoplankton communities of the Laptev Sea (Arctic)

    Institute of Scientific and Technical Information of China (English)

    2005-01-01

    Abundance, biomass and composition of the ice algal and phytoplankton communities were investigated in the southeastern Laptev Sea in spring 1999.Diatoms dominated the algal communities and pennate diatoms dominated the diatom population. 12 dominant algal species occurred within sea ice and underlying water column, including Fragilariopsis oceanica, F. cylindrus, Nitzschia frigida , N. promare, Achnanthes taeniata , Nitzschia neofrigida , Navicula pelagica , N. vanhoef fenii, N. septentrionalis, Melosira arctica , Clindrotheca closterium and Pyramimonas sp. The algal abundance of bottom 10 cm sea ice varied between 14.6 and 1562.2 × 104 cells l-1 with an average of 639.0 × 104cells l-1 , and the algal biomass ranged from 7.89 to 2093.5 μg C l-1 with an average of 886.9 μg C l-1 , which were generally one order of magnitude higher than those of sub-bottom ice and two orders of magnitude higher than those of underlying surface water. The integrated algal abundance and biomass of lowermost 20 cm ice column were averagely 7.7 and 12.2 times as those of upper 20 m water column, respectively, suggesting that the ice algae might play an important role in maintaining the coastal marine ecosystem before the thawing of sea ice. Ice algae influenced the phytoplankton community of the underlying water column.However, the "seeding" of ice algae for phytoplankton bloom was negligible because of the low phytoplankton biomass within the underlying water column.

  8. Retrieval of tropospheric column-averaged CH4 mole fraction by solar absorption FTIR-spectrometry using N2O as a proxy

    Directory of Open Access Journals (Sweden)

    Z. Wang

    2014-02-01

    Full Text Available Tropospheric column-averaged CH4 mole fractions were derived from ground-based absorption columns measurements. The method used stratospheric N2O columns to correct for the stratospheric contribution to the CH4 total column. The method was applied to four TCCON sites covering locations from the Northern Arctic to the tropics. It performs well for all sites. The derived tropospheric CH4 concentrations were compared with profiles measured by aircraft at three sites. The results indicate an inter-site consistency within 6 ppb (~ 0.3%. With aircraft profiles up to 3 km, the seasonal behavior of the derived tropospheric CH4 concentration was also checked. It reveals a difference of 20 ppb around. The mean relative uncertainty of the four sites is 0.23%. Comparing with the method using HF the proposed method shows a smaller relative uncertainty and less H2O dependence.

  9. First 100 ms of HF modification at Tromso, Norway

    Science.gov (United States)

    Djuth, F. T.; Isham, B.; Rietveld, M. T.; Hagfors, T.; La Hoz, C.

    Experiments were performed with the high-power high-frequency HF facility at Troms o Norway to test theoretical predictions for the excitation of ion and Langmuir oscillations in the ionosphere The principal diagnostic of wave-plasma interactions was the VHF radar at the European Incoherent Scatter EISCAT facility High resolution radar techniques were used to monitor the temporal development of the ion and Langmuir oscillations HF pulses 100 ms in duration were periodically transmitted into a smooth background F region plasma Measurements of the radar backscatter spectra show that all key spectral features predicted by strong Langmuir turbulence SLT theory modified Zakharov model are simultaneously present in the plasma and that their evolution is in agreement with theoretical expectations However several new features have been observed that cannot be anticipated by current theory because of limitations in the electric field strength within the simulations The experimental results reinforce the notion that new theoretical developments are needed to accommodate the large HF electric fields produced at Troms o and HAARP Gakona Alaska and to treat the electron acceleration process in a self-consistent fashion The F region response to two HF effective radiated power levels sim 58 MW and sim 125 MW was investigated at Troms o These ERP values include absorptive losses resulting from the sunlit D region In general the results at 58 MW ERP and 125 MW ERP are consistent with many of the SLT

  10. The multilayer Fe/Hf studied with slow positron beam

    Science.gov (United States)

    Murashige, Y.; Tashiro, M.; Nakajyo, T.; Koizumi, T.; Kanazawa, I.; Komori, F.; Ito, Y.

    1997-04-01

    The positron annihilation parameter versus the incident positron energy is measured in the thin Fe films and the Fe/Hf bilayer on silica substrate, by means of the variable energetic slow-positron beam technique. We have analyzed the change in open-volume spaces and vacancy-type defects among the Fe microcrystals in these thin films with the deposition temperature.

  11. A CMOS OTA for HF filters with programmable transfer function

    NARCIS (Netherlands)

    van de Zwan, Eric J.; Klumperink, Eric A.M.; Seevinck, E.; Seevinck, Evert

    1991-01-01

    A CMOS operational transconductance amplifier (OTA) for programmable HF filters is presented. When used in an OTA-C integrator, the unity-gain frequency phase error remains less than 0.3° for frequencies up to more than one tenth of the OTA bandwidth. The OTA has built-in phase compensation, which

  12. Hf isotope evidence for a hidden mantle reservoir

    DEFF Research Database (Denmark)

    Bizzarro, Martin; Simonetti, A.; Stevenson, R.K.

    2002-01-01

    High-precision Hf isotopic analyses and U-Pb ages of carbonatites and kimberlites from Greenland and eastern North America, including Earth's oldest known carbonatite (3 Ga), indicate derivation from an enriched mantle source. This previously unidentified mantle reservoir-marked by an unradiogeni...

  13. Origin of excess 176Hf in meteorites

    DEFF Research Database (Denmark)

    Thrane, Kristine; Connelly, James; Bizzarro, Martin

    2010-01-01

    After considerable controversy regarding the (176)Lu decay constant (lambda(176)Lu), there is now widespread agreement that (1.867 +/- 0.008) x 10(-11) yr(-1) as confirmed by various terrestrial objects and a 4557 Myr meteorite is correct. This leaves the (176)Hf excesses that are correlated with...

  14. Self-diffusion of Er and Hf inpure and HfO/sub 2/-doped polycrystalline Er/sub 2/O/sub 3/. [Hf-175 and Er-169

    Energy Technology Data Exchange (ETDEWEB)

    Scheidecker, R.W.

    1979-01-01

    Using a tracer technique, self-diffusion of Er and Hf was measured over the approximate temperature interval of 1600 to 1970/sup 0/C in pure and HfO/sub 2/-doped polycryatalline Er/sub 2/O/sub 3/. Up to about 10 m/o HfO/sub 2/ dopant level, the Er self-diffusion coefficients followed a relationship based on cation vacancies. Above 10 m/o HfO/sub 2/, deviation from this relationship occurred, apparently due to clustering of cation vacancies and oxygen interstitials around the dopant hafnia ion. The activation energy for the self-diffusion of Er in pure Er/sub 2/O/sub 3/ was 82.2 Kcal/mole and increased with the HfO/sub 2/ dopant level present. Self-diffusion of Hf was measured in pure Er/sub 2/O/sub 3/ having two impurity levels, and a separation of the grain boundary. The volume diffusion of Hf showed both extrinsic and intrinsic behavior with the transition temperature increasing with the impurity level present in Er/sub 2/O/sub 3/. The activation energy for Hf volume diffusion in the intrinsic region was high, i.e. 235 -+ 9.5 Kcal/mole. The grain boundary diffusion was apparently extrinsic over the entire temperature interval Very low Hf self diffusion rates were found in both pure and HfO/sub 2/ doped Er/sub 2/O/sub 3/ compositions. Despite a clustering effect, the HfO/sub 2/ dopant increased the Hf volume diffusion coefficients.

  15. Helium implanted $\\rm\\underline{Al}$Hf as studied by 181Ta TDPAC

    Indian Academy of Sciences (India)

    R Govindaraj; K P Gopinathan; B Viswanathan

    2000-06-01

    Time differential perturbed angular correlation (TDPAC) measurement on $\\rm\\underline{Al}$Hf reference sample has shown that a fraction 0.88 of probe nuclei are defect free and are occupying the substitutional sites in fcc Al matrix, and the remaining are associated with Hf solute clusters. Measurements on helium implanted sample indicate the binding of helium associated defects by Hf solute clusters. Isochronal annealing measurements indicate the dissociation of the helium implantation induced defects from Hf solute clusters for annealing treatments beyond 650 K. On comparison of the present results with that reported in $\\rm\\underline{Cu}$Hf subjected to identical helium implantation, it is inferred that the Hf solute clusters in $\\rm\\underline{Al}$Hf bind less strongly the helium associated defects than in $\\rm\\underline{Cu}$Hf.

  16. Processing and crystallographic structure of non-equilibrium Si-doped HfO{sub 2}

    Energy Technology Data Exchange (ETDEWEB)

    Hou, Dong; Fancher, Chris M.; Esteves, Giovanni; Jones, Jacob L., E-mail: jacobjones@ncsu.edu [Department of Materials Science and Engineering, North Carolina State University, Raleigh, North Carolina 27695 (United States); Zhao, Lili [School of Information Science and Technology, Northwest University, Xi' an 710127 (China)

    2015-06-28

    Si-doped HfO{sub 2} was confirmed to exist as a non-equilibrium state. The crystallographic structures of Si-doped HfO{sub 2} were studied using high-resolution synchrotron X-ray diffraction and the Rietveld refinement method. Incorporation of Si into HfO{sub 2} and diffusion of Si out of (Hf,Si)O{sub 2} were determined as a function of calcination temperature. Higher thermal energy input at elevated calcination temperatures resulted in the formation of HfSiO{sub 4}, which is the expected major secondary phase in Si-doped HfO{sub 2}. The effect of SiO{sub 2} particle size (nano- and micron-sized) on the formation of Si-doped HfO{sub 2} was also determined. Nano-crystalline SiO{sub 2} was found to incorporate into HfO{sub 2} more readily.

  17. Data of evolutionary structure change: 1CLMA-2HF5A [Confc[Archive

    Lifescience Database Archive (English)

    Full Text Available 1CLMA-2HF5A 1CLM 2HF5 A A LTEEQIAEFKEAFALFDKDGDGTITTKELGTVMRSLGQN...PTEAELQDMINEVDADGNGTIDFPEFLSLMARKMKEQDSEEELIEAFKVFDRDGNGLISAAELRHVMTNLGEKL--TDDEVDEMIREADIDGDGHINYEEFVRMMVS-...ntryChain> 1CLM A 1CLMA LGEKL--TD...ne> 1CLM A 1CLMA

  18. Distribution, abundance and ecological relevance of pelagic fishes in the Lazarev Sea, Southern Ocean

    NARCIS (Netherlands)

    Florentino De Souza Silva, A.P.; Putte, van de A.P.; Siegel, V.; Pakhomov, E.A.; Franeker, van J.A.; Meesters, H.W.G.; Colckaert, F.A.M.

    2008-01-01

    The distribution and abundance of larval and postlarval fishes was investigated in the Lazarev Sea, Southern Ocean, in March and April 2004. The upper 200 m of the water column were sampled with an 8 m2 rectangular midwater trawl at 93 stations. The larval species community clustered in a diverse co

  19. Distribution, abundance and ecological relevance of pelagic fishes in the Lazarev Sea, Southern Ocean

    NARCIS (Netherlands)

    Flores, Hauke; de Putte, Anton P. Van; Siegel, Volker; Pakhomov, Evgeny A.; Van Franeker, Jan A.; Meesters, Hugo W. G.; Volckaert, Filip A. M.

    2008-01-01

    The distribution and abundance of larval and postlarval fishes was investigated in the Lazarev Sea, Southern Ocean, in March and April 2004. The upper 200 m of the water column were sampled with an 8 m(2) rectangular midwater trawl at 93 stations. The larval species community clustered in a diverse

  20. Abundance of dissolved polysaccharides in the oxygen minimum layer of the northern Indian Ocean

    Digital Repository Service at National Institute of Oceanography (India)

    Bhosle, N.B.; Bhaskar, P.V.; Ramachandran, S.

    ) were the most abundant form of total dissolved carbohydrates (TCHO) throughout the water column sampled and accounted for 75 plus or minus and 11% of the TCHO. Hydrolysis-resistant PCHO (HR-PCHO) contributed 48 plus or minusand 16% to the PCHO...

  1. Geographic variations in the PARADIGM-HF heart failure trial.

    Science.gov (United States)

    Kristensen, Søren Lund; Martinez, Felipe; Jhund, Pardeep S; Arango, Juan Luis; Bĕlohlávek, Jan; Boytsov, Sergey; Cabrera, Walter; Gomez, Efrain; Hagège, Albert A; Huang, Jun; Kiatchoosakun, Songsak; Kim, Kee-Sik; Mendoza, Iván; Senni, Michele; Squire, Iain B; Vinereanu, Dragos; Wong, Raymond Ching-Chiew; Gong, Jianjian; Lefkowitz, Martin P; Rizkala, Adel R; Rouleau, Jean L; Shi, Victor C; Solomon, Scott D; Swedberg, Karl; Zile, Michael R; Packer, Milton; McMurray, John J V

    2016-11-01

    The globalization of clinical trials has highlighted geographic variations in patient characteristics, event rates, and treatment effects. We investigated these further in PARADIGM-HF, the largest and most globally representative trial in heart failure (HF) to date. We looked at five regions: North America (NA) 602 (8%), Western Europe (WE) 1680 (20%), Central/Eastern Europe/Russia (CEER) 2762 (33%), Latin America (LA) 1433 (17%), and Asia-Pacific (AP) 1487 (18%). Notable differences included: WE patients (mean age 68 years) and NA (65 years) were older than AP (58 years) and LA (63 years) and had more coronary disease; NA and CEER patients had the worst signs, symptoms, and functional status. North American patients were the most likely to have a defibrillating-device (54 vs. 2% AP) and least likely prescribed a mineralocorticoid receptor antagonist (36 vs. 65% LA). Other evidence-based therapies were used most frequently in NA and WE. Rates of the primary composite outcome of cardiovascular (CV) death or HF hospitalization (per 100 patient-years) varied among regions: NA 13.6 (95% CI 11.7-15.7) WE 9.6 (8.6-10.6), CEER 12.3 (11.4-13.2), LA 11.2 (10.0-12.5), and AP 12.5 (11.3-13.8). After adjustment for prognostic variables, relative to NA, the risk of CV death was higher in LA and AP and the risk of HF hospitalization lower in WE. The benefit of sacubitril/valsartan was consistent across regions. There were many regional differences in PARADIGM-HF, including in age, symptoms, comorbidity, background therapy, and event-rates, although these did not modify the benefit of sacubitril/valsartan. CLINICAL TRIAL REGISTRATION URL: http://www.clinicaltrials.gov. Unique identifier: NCT01035255. © The Author 2016. Published by Oxford University Press on behalf of the European Society of Cardiology.

  2. Ready-made chromatography columns for extracellular vesicle isolation from plasma

    Directory of Open Access Journals (Sweden)

    Joanne Louise Welton

    2015-03-01

    Full Text Available Proteomic studies of circulating vesicles are hampered by difficulties in purifying vesicles from plasma and serum. Isolations are contaminated with high-abundance blood proteins that may mask genuine vesicular-associated proteins and/or simply provide misleading data. In this brief report, we explored the potential utility of a commercially available size exclusion chromatography column for rapid vesicle purification. We evaluated the performance of the column, with cancer cell line conditioned medium or healthy donor plasma, in terms of removing non-vesicular protein and enriching for vesicles exhibiting exosome characteristics. Serial fractions revealed a peak for typical exosomal proteins (CD9, CD81 etc. that preceded the peak for highly abundant proteins, including albumin, for either sample type, and harvesting only this peak would represent elimination of >95% of protein from the sample. The columns showed good reproducibility, and streamlining the workflow would allow the exosome-relevant material to be collected in less than 10 minutes. Surprisingly, however, subsequent post-column vesicle concentration steps whilst resulting in some protein loss also lead to low vesicle recoveries, with a net effect of reducing sample purity (assessed by the particle-to-protein ratio. The columns provide a convenient, reproducible and highly effective means of eliminating >95% of non-vesicular protein from biological fluid samples such as plasma.

  3. Mid-Latitude Mobile Wideband HF- NVIS Channel Analysis: Part 1

    Science.gov (United States)

    2017-09-14

    communications (SATCOM) for beyond line-of- sight (LOS) links. However, standard HF systems operating over a 3-kHz bandwidth do not provide sufficient...wideband mid-latitude HF channel soundings and three-dimensional (3-D) ray-tracing simulations to develop a statistical model of a particular nearly...46 5 THE HF-NVIS CHANNEL SOUNDING SYSTEM ...................................................................... 47 5.1 TRANSMIT AND RECEIVE HF

  4. HF Radar observations of the Dardanelles outflow current in North Eastern Aegean using validated WERA HF radar data

    Directory of Open Access Journals (Sweden)

    Z. KOKKINI

    2015-01-01

    Full Text Available A two-site WERA HF radar station was installed in November 2009 at the eastern coast of Lemnos Island in North Aegean Sea, aiming to monitor the surface inflow of Black Sea waters exiting from the Dardanelles Strait, as well as to constitute a coastal management tool for incidents of oil-pollution or save-and-rescue operations. Strong interference by foreign transmissions is a source of noise deteriorating the quality of the backscattered signal, thus significantly reducing the HF radar’s effective data return rate. In order to ameliorate this problem, further quality-control and data gap interpolating procedures have been developed and applied, to be used in addition to the procedures incorporated and used by the manufacturer’s signal processing software. The second-level processing involves traditional despiking in the temporal domain, preceding Empirical Orthogonal Function analysis. The latter is used not only to filter high-frequency noise but also to fill data gaps in time and space. The data reconstruction procedure has been assessed via comparison of (a HF radial with CODE-type drifter radial velocities as well as (b HF-derived virtual drifter tracks with actual drifter tracks. The main circulation features and their variability, as revealed by the reconstructed fields, are presented.

  5. HF Radar observations of the Dardanelles outflow current in North Eastern Aegean using validated WERA HF radar data

    Directory of Open Access Journals (Sweden)

    Z. KOKKINI

    2014-12-01

    Full Text Available A two-site WERA HF radar station was installed in November 2009 at the eastern coast of Lemnos Island in North Aegean Sea, aiming to monitor the surface inflow of Black Sea waters exiting from the Dardanelles Strait, as well as to constitute a coastal management tool for incidents of oil-pollution or save-and-rescue operations. Strong interference by foreign transmissions is a source of noise deteriorating the quality of the backscattered signal, thus significantly reducing the HF radar’s effective data return rate. In order to ameliorate this problem, further quality-control and data gap interpolating procedures have been developed and applied, to be used in addition to the procedures incorporated and used by the manufacturer’s signal processing software. The second-level processing involves traditional despiking in the temporal domain, preceding Empirical Orthogonal Function analysis. The latter is used not only to filter high-frequency noise but also to fill data gaps in time and space. The data reconstruction procedure has been assessed via comparison of (a HF radial with CODE-type drifter radial velocities as well as (b HF-derived virtual drifter tracks with actual drifter tracks. The main circulation features and their variability, as revealed by the reconstructed fields, are presented.

  6. Column: Factors Affecting Data Decay

    Directory of Open Access Journals (Sweden)

    Kevin Fairbanks

    2012-06-01

    Full Text Available In nuclear physics, the phrase decay rate is used to denote the rate that atoms and other particles spontaneously decompose. Uranium-235 famously decays into a variety of daughter isotopes including Thorium and Neptunium, which themselves decay to others. Decay rates are widely observed and wildly different depending on many factors, both internal and external. U-235 has a half-life of 703,800,000 years, for example, while free neutrons have a half-life of 611 seconds and neutrons in an atomic nucleus are stable.We posit that data in computer systems also experiences some kind of statistical decay process and thus also has a discernible decay rate. Like atomic decay, data decay fluctuates wildly. But unlike atomic decay, data decay rates are the result of so many different interplaying processes that we currently do not understand them well enough to come up with quantifiable numbers. Nevertheless, we believe that it is useful to discuss some of the factors that impact the data decay rate, for these factors frequently determine whether useful data about a subject can be recovered by forensic investigation.(see PDF for full column

  7. The stability of the bifluoride ion (HF - 2) in the gas phase

    Science.gov (United States)

    Heni, Martin; Illenberger, Eugen

    1985-12-01

    The bifluoride ion (HF-2) has been generated by dissociative electron attachment to trans-1,2-difluorethylene and cis-1,2-difluoroethylene. Evaluation of the energetics for these reactions leads to ΔH0f (HF-2) ≤-6.9 eV and E. A. (HF2)≥4.8 eV.

  8. Photon strength function in the Hf-181 nucleus by method of two-step cascade

    CERN Document Server

    Le Hong Khiem

    2003-01-01

    The applicability of sum-coincidence measurements of two-step cascade gamma ray spectra determining Photon Strength Function (PSF) of Hf-181 induced from Hf-180 (n,2 gamma) Hf-181 reaction is presented. Up to 80% intensity of the primary gamma ray transitions in a wide energy range have been deduced and compared to model calculation.

  9. Suppression Factor of ~(182)W for ~(182)Hf AMS at CIAE

    Institute of Scientific and Technical Information of China (English)

    2011-01-01

    Suppression factor of 182W is an important index in the measurement of 182Hf with AMS method. This factor is defined as the value of 182W/180Hf in blank samples divised by the measured value of 182 W/180Hf with AMS method. In order to satisfy a

  10. 40 CFR 180.1273 - Beauveria bassiana HF23; exemption from the requirement of a tolerance.

    Science.gov (United States)

    2010-07-01

    ... 40 Protection of Environment 23 2010-07-01 2010-07-01 false Beauveria bassiana HF23; exemption... FOOD Exemptions From Tolerances § 180.1273 Beauveria bassiana HF23; exemption from the requirement of a tolerance. Residues of Beauveria bassiana HF23 are exempt from the requirement of a tolerance on all...

  11. Sunspots, Starspots, and Elemental Abundances

    Science.gov (United States)

    Doschek, George A.; Warren, Harry P.

    2017-08-01

    The composition of plasma in solar and stellar atmospheres is not fixed, but varies from feature to feature. These variations are organized by the First Ionization Potential (FIP) of the element. Solar measurements often indicate that low FIP elements (10 eV, such as C, N, O, Ar, He) compared to abundances in the photosphere. Stellar observations have also shown similar enrichments. An inverse FIP effect, where the low FIP elements are depleted, has been observed in stellar coronae of stars believed to have large starspots in their photospheres. The abundances are important for determining radiative loss rates in models, tracing the origin of the slow solar wind, and for understanding wave propagation in the chromosphere and corona. Recently, inverse FIP effects have been discovered in the Sun (Doschek, Warren, & Feldman 2015, ApJ, 808, L7) from spectra obtained by the Extreme-ultraviolet Imaging Spectrometer (EIS) on the Hinode spacecraft. The inverse FIP regions seem always to be near sunspots and cover only a very small area (characteristic length = a few arcseconds). However, in pursuing the search for inverse FIP regions, we have found that in some sunspot groups the coronal abundance at a temperature of 3-4 MK can be near photospheric over much larger areas of the sun near the sunspots (e.g., 6,000 arcsec2). Also, sometimes the abundances at 3-4 MK are in between coronal and photospheric values. This can occur in small areas of an active region. It is predicted (Laming 2015, Sol. Phys., 12, 2) that the FIP effect should be highly variable in the corona. Several examples of coronal abundance variations are presented. Our work indicates that a comprehensive re-investigation of solar abundances is highly desirable. This work is supported by a NASA Hinode grant.

  12. Anthropogenic noise changes arthropod abundances.

    Science.gov (United States)

    Bunkley, Jessie P; McClure, Christopher J W; Kawahara, Akito Y; Francis, Clinton D; Barber, Jesse R

    2017-05-01

    Anthropogenic noise is a widespread and growing form of sensory pollution associated with the expansion of human infrastructure. One specific source of constant and intense noise is that produced by compressors used for the extraction and transportation of natural gas. Terrestrial arthropods play a central role in many ecosystems, and given that numerous species rely upon airborne sounds and substrate-borne vibrations in their life histories, we predicted that increased background sound levels or the presence of compressor noise would influence their distributions. In the second largest natural gas field in the United States (San Juan Basin, New Mexico, USA), we assessed differences in the abundances of terrestrial arthropod families and community structure as a function of compressor noise and background sound level. Using pitfall traps, we simultaneously sampled five sites adjacent to well pads that possessed operating compressors, and five alternate, quieter well pad sites that lacked compressors, but were otherwise similar. We found a negative association between sites with compressor noise or higher levels of background sound and the abundance of five arthropod families and one genus, a positive relationship between loud sites and the abundance of one family, and no relationship between noise level or compressor presence and abundance for six families and two genera. Despite these changes, we found no evidence of community turnover as a function of background sound level or site type (compressor and noncompressor). Our results indicate that anthropogenic noise differentially affects the abundances of some arthropod families. These preliminary findings point to a need to determine the direct and indirect mechanisms driving these observed responses. Given the diverse and important ecological functions provided by arthropods, changes in abundances could have ecological implications. Therefore, we recommend the consideration of arthropods in the environmental

  13. Two-dimensional semiconductor HfSe{sub 2} and MoSe{sub 2}/HfSe{sub 2} van der Waals heterostructures by molecular beam epitaxy

    Energy Technology Data Exchange (ETDEWEB)

    Aretouli, K. E.; Tsipas, P.; Tsoutsou, D.; Marquez-Velasco, J.; Xenogiannopoulou, E.; Giamini, S. A.; Vassalou, E.; Kelaidis, N.; Dimoulas, A., E-mail: a.dimoulas@inn.demokritos.gr [Institute of Nanoscience and Nanotechnology, National Center for Scientific Research “Demokritos,” 15310, Aghia Paraskevi, Athens (Greece)

    2015-04-06

    Using molecular beam epitaxy, atomically thin 2D semiconductor HfSe{sub 2} and MoSe{sub 2}/HfSe{sub 2} van der Waals heterostructures are grown on AlN(0001)/Si(111) substrates. Details of the electronic band structure of HfSe{sub 2} are imaged by in-situ angle resolved photoelectron spectroscopy indicating a high quality epitaxial layer. High-resolution surface tunneling microscopy supported by first principles calculations provides evidence of an ordered Se adlayer, which may be responsible for a reduction of the measured workfunction of HfSe{sub 2} compared to theoretical predictions. The latter reduction minimizes the workfunction difference between the HfSe{sub 2} and MoSe{sub 2} layers resulting in a small valence band offset of only 0.13 eV at the MoSe{sub 2}/HfSe{sub 2} heterointerface and a weak type II band alignment.

  14. Rasch models with exchangeable rows and columns

    DEFF Research Database (Denmark)

    Lauritzen, Steffen Lilholt

    The article studies distributions of doubly infinite binary matrices with exchangeable rows and columns which satify the further property that the probability of any $m \\times n$ submatrix is a function of the row- and column sums of that matrix. We show that any such distribution is a (unique...... of existence of measures with given marginals....

  15. Circulation in gas-slurry column reactors

    Energy Technology Data Exchange (ETDEWEB)

    Clark, N.; Kuhlman, J.; Celik, I.; Gross, R.; Nebiolo, E.; Wang, Yi-Zun.

    1990-08-15

    Circulation in bubble columns, such as those used in fischer-tropsch synthesis, detracts from their performance in that gas is carried on average more rapidly through the column, and the residence time distribution of the gas in the column is widened. Both of these factors influence mass-transfer operations in bubble columns. Circulation prediction and measurement has been undertaken using probes, one-dimensional models, laser Doppler velocimetry, and numerical modeling. Local void fraction was measured using resistance probes and a newly developed approach to determining air/water threshold voltage for the probe. A tall column of eight inch diameter was constructed of Plexiglas and the distributor plate was manufactured to distribute air evenly through the base of the column. Data were gathered throughout the volume at three different gas throughputs. Bubble velocities proved difficult to measure using twin probes with cross-correlation because of radial bubble movement. A series of three-dimensional mean and RMS bubble and liquid velocity measurements were also obtained for a turbulent flow in a laboratory model of a bubble column. These measurements have been made using a three-component laser Doppler velocimeter (LDV), to determine velocity distributions non-intrusively. Finally, the gas-liquid flow inside a vertically situated circular isothermal column reactor was simulated numerically. 74 refs., 170 figs., 5 tabs.

  16. Influence of tray hydraulics on tray column

    NARCIS (Netherlands)

    Betlem, Bernardus H.L.; Rijnsdorp, J.E.; Rijnsdorp, J.E.; Azink, R.F.

    1998-01-01

    To column control, in contrast to column design, tray hold-up and dependencies of tray hold-up on the operating conditions play an important role. The essence of this article is the development of an improved model of tray hydraulics over a broad operating range and its experimental validation by

  17. Discovery of interstellar ketenyl (HCCO), a surprisingly abundant radical

    Science.gov (United States)

    Agúndez, Marcelino; Cernicharo, José; Guélin, Michel

    2015-05-01

    We conducted radioastronomical observations of 9 dark clouds with the IRAM 30 m telescope. We present the first identification in space of the ketenyl radical (HCCO) toward the starless core Lupus-1A and the molecular cloud L483 and the detection of the related molecules ketene (H2CCO) and acetaldehyde (CH3CHO) in these two sources and 3 additional dark clouds. We also report the detection of the formyl radical (HCO) in the 9 targeted sources and of propylene (CH2CHCH3) in 4 of the observed sources, which significantly extends the number of dark clouds where these molecules are known to be present. We have derived a beam-averaged column density of HCCO of ~5 × 1011 cm-2 in both Lupus-1A and L483, which means that the ketenyl radical is just ~10 times less abundant than ketene in these sources. The non-negligible abundance of HCCO found implies that there must be a powerful formation mechanism able to counterbalance the efficient destruction of this radical through reactions with neutral atoms. The column densities derived for HCO, (0.5-2.7) ×1012 cm-2, and CH2CHCH3, (1.9-4-2) ×1013 cm-2, are remarkably uniform across the sources where these species are detected, confirming their ubiquity in dark clouds. Gas phase chemical models of cold dark clouds can reproduce the observed abundances of HCO, but cannot explain the presence of HCCO in Lupus-1A and L483 and the high abundances derived for propylene. The chemistry of cold dark clouds needs to be revised in light of these new observational results. Based on observations carried out with the IRAM 30 m Telescope. IRAM is supported by INSU/CNRS (France), MPG (Germany) and IGN (Spain).Tables 3-6 are available in electronic form at http://www.aanda.org

  18. Discovery of interstellar ketenyl (HCCO), a surprisingly abundant radical★

    Science.gov (United States)

    Agúndez, Marcelino; Cernicharo, José; Guélin, Michel

    2015-01-01

    We have conducted radioastronomical observations of 9 dark clouds with the IRAM 30m telescope. We present the first identification in space of the ketenyl radical (HCCO) toward the starless core Lupus-1A and the molecular cloud L483, and the detection of the related molecules ketene (H2CCO) and acetaldehyde (CH3CHO) in these two sources and 3 additional dark clouds. We also report the detection of the formyl radical (HCO) in the 9 targeted sources and of propylene (CH2CHCH3) in 4 of the observed sources, which extends significantly the number of dark clouds where these molecules are known to be present. We derive a beam-averaged column density of HCCO of ~ 5 × 1011 cm−2 in both Lupus-1A and L483, which means that the ketenyl radical is just ~10 times less abundant than ketene in these sources. The non-negligible abundance of HCCO found implies that there must be a powerful formation mechanism able to counterbalance the efficient destruction of this radical through reactions with neutral atoms. The column densities derived for HCO, (0.5-2.7) ×1012 cm−2, and CH2CHCH3, (1.9-4-2) ×1013 cm−2, are remarkably uniform across the sources where these species are detected, confirming their ubiquity in dark clouds. Gas phase chemical models of cold dark clouds can reproduce the observed abundances of HCO, but cannot explain the presence of HCCO in Lupus-1A and L483 and the high abundances derived for propylene. The chemistry of cold dark clouds needs to be revised in the light of these new observational results. PMID:26722130

  19. GASEOUS CO ABUNDANCE-AN EVOLUTIONARY TRACER FOR MOLECULAR CLOUDS

    Energy Technology Data Exchange (ETDEWEB)

    Liu Tie; Wu Yuefang; Zhang Huawei, E-mail: liutiepku@gmail.com, E-mail: ywu@pku.edu.cn [Department of Astronomy, Peking University, Beijing 100871 (China)

    2013-09-20

    Planck cold clumps are among the most promising objects to investigate the initial conditions of the evolution of molecular clouds. In this work, by combing the dust emission data from the survey of the Planck satellite with the molecular data of {sup 12}CO/{sup 13}CO/C{sup 18}O (1-0) lines from observations with the Purple Mountain Observatory 13.7 m telescope, we investigate the CO abundance, CO depletion, and CO-to-H{sub 2} conversion factor of 674 clumps in the early cold cores sample. The median and mean values of the CO abundance are 0.89 Multiplication-Sign 10{sup -4} and 1.28 Multiplication-Sign 10{sup -4}, respectively. The mean and median of CO depletion factor are 1.7 and 0.9, respectively. The median value of X{sub CO-to-H{sub 2}} for the whole sample is 2.8 Multiplication-Sign 10{sup 20} cm{sup -2} K{sup -1} km{sup -1} s. The CO abundance, CO depletion factor, and CO-to-H{sub 2} conversion factor are strongly (anti-)correlated to other physical parameters (e.g., dust temperature, dust emissivity spectral index, column density, volume density, and luminosity-to-mass ratio). To conclude, the gaseous CO abundance can be used as an evolutionary tracer for molecular clouds.

  20. Gd Transition Probabilities and Abundances

    CERN Document Server

    Den Hartog, E A; Sneden, C; Cowan, J J

    2006-01-01

    Radiative lifetimes, accurate to +/- 5%, have been measured for 49 even-parity and 14 odd-parity levels of Gd II using laser-induced fluorescence. The lifetimes are combined with branching fractions measured using Fourier transform spectrometry to determine transition probabilities for 611 lines of Gd II. This work is the largest-scale laboratory study to date of Gd II transition probabilities and the first using a high performance Fourier transform spectrometer. This improved data set has been used to determine a new solar photospheric Gd abundance, log epsilon = 1.11 +/- 0.03. Revised Gd abundances have also been derived for the r-process-rich metal-poor giant stars CS 22892-052, BD+17 3248, and HD 115444. The resulting Gd/Eu abundance ratios are in very good agreement with the solar-system r-process ratio. We have employed the increasingly accurate stellar abundance determinations, resulting in large part from the more precise laboratory atomic data, to predict directly the Solar System r-process elemental...

  1. A Comparative Study of Pollutant Removal Stability in Hybrid Wetland Columns

    Institute of Scientific and Technical Information of China (English)

    Tanveer Ferdous Saeed; Guang zhi Sun

    2012-01-01

    This study investigated the effects of two alternative substrates (wood mulch and zeolite) on the performance of three laboratory-scale hybrid wetland systems that had identical system components and configurations.Each system consisted of a vertical flow (VF) wetland column,followed by a horizontal flow (HF) column and a vertical flow column.The substrates employed were wood mulch,gravel and zeolite,and Phragmites australis were planted in each column.The systems received synthetic wastewater,with pollutant loadings in the range of 8.5-38.0g/(m2· d) total nitrogen (TN) and 4.0-46.4 g/(m2· d) biological oxygen demand (BOD5).Wood mulch and zeolite substrates showed higher efficiencies in terms of removing nitrogenous compounds and biodegradable organics.The supply of organic carbon from the organic mulch substrates enhanced denitrification,while adsorption of influent ammoniacal nitrogen (NH4—N) in zeolite played a major role in the removal of nitrogenous species in the wetland columns.Overall,the average percentage removals of TN and BOD5 reached>66% and >96% respectively,indicating stable performances by the hybrid wetland systems under the experimental loading ranges.Mathematical models were developed,based on the combination of Monod kinetics and continuously-stirred tank reactor (CSTR) flow patterns to describe the degradation of nitrogenous compounds.Predictions by the models closely matched the experimental data,indicating the validity and potential application of Monod kinetics in the modelling and design of treatment wetlands.

  2. Charge storage characteristics and tunneling mechanism of amorphous Ge-doped HfOx films

    Science.gov (United States)

    Qiu, X. Y.; Zhang, S. Y.; Zhang, T.; Wang, R. X.; Li, L. T.; Zhang, Y.; Dai, J. Y.

    2016-09-01

    Amorphous Ge-doped HfOx films have been deposited on p-Si(100) substrates by means of RF magnetron sputtering. Microstructural investigations reveal the partial oxidation of doped Ge atoms in the amorphous HfOx matrix and the existence of HfSiOx interfacial layer. Capacitance-voltage hysteresis of the Ag-/Ge-doped HfOx/Si/Ag memory capacitor exhibits a memory window of 3.15 V which can maintain for >5 × 104 cycles. Current-voltage characteristics reveal that Poole-Frenkel tunneling is responsible for electron transport in the Ge-doped HfOx film.

  3. Biogeochemical gradients and microbial communities in Winogradsky columns established with polluted wetland sediments.

    Science.gov (United States)

    Babcsányi, Izabella; Meite, Fatima; Imfeld, Gwenaël

    2017-08-01

    A Winogradsky column is a miniature ecosystem established with enriched sediments that can be used to study the relationship between biogeochemical gradients, microbial diversity and pollutant transformation. Biogeochemical processes and microbial communities changed with time and depth in Winogradsky columns incubated with heavy-metal-polluted wetland sediments for 520 days. 16S rRNA surveys were complemented by geochemical analyses, including heavy metal proportioning, to evaluate gradients in the mostly anoxic columns. Oxygen was depleted below the water-sediment interface (WSI), while NH4+, Fe2+, S2- and acetate increased by one order of magnitude at the bottom. Microbial niche differentiation occurred mainly by depth and from the light-exposed surface to the interior of the columns. Chemical gradients resulting from nutrient uptake by algae, and from iron and sulphate reduction mainly drove diversification. Heavy-metal proportioning did not significantly influence microbial diversity as Cu and Zn were immobilised at all depths. Proteobacteria were abundant in the top water and the WSI layers, whereas Firmicutes and Bacteroida dominated down-core. Together with low diversity and richness of communities at the WSI and column bottom, changes in the bacterial community coincided with algal-derived carbon sources and cellulose fermentation, respectively. We expect this study to be the starting point for the use Winogradsky columns to study microbial and geochemical dynamics in polluted sediments. © FEMS 2017. All rights reserved. For permissions, please e-mail: journals.permissions@oup.com.

  4. Coho Abundance - Linear Features [ds183

    Data.gov (United States)

    California Department of Resources — The CalFish Abundance Database contains a comprehensive collection of anadromous fisheries abundance information. Beginning in 1998, the Pacific States Marine...

  5. Steelhead Abundance - Point Features [ds184

    Data.gov (United States)

    California Department of Resources — The CalFish Abundance Database contains a comprehensive collection of anadromous fisheries abundance information. Beginning in 1998, the Pacific States Marine...

  6. Steelhead Abundance - Linear Features [ds185

    Data.gov (United States)

    California Department of Resources — The CalFish Abundance Database contains a comprehensive collection of anadromous fisheries abundance information. Beginning in 1998, the Pacific States Marine...

  7. Coho Abundance - Point Features [ds182

    Data.gov (United States)

    California Department of Resources — The CalFish Abundance Database contains a comprehensive collection of anadromous fisheries abundance information. Beginning in 1998, the Pacific States Marine...

  8. Chinook Abundance - Point Features [ds180

    Data.gov (United States)

    California Department of Resources — The CalFish Abundance Database contains a comprehensive collection of anadromous fisheries abundance information. Beginning in 1998, the Pacific States Marine...

  9. Abundance estimation and Conservation Biology

    Directory of Open Access Journals (Sweden)

    Nichols, J. D.

    2004-06-01

    Full Text Available Abundance is the state variable of interest in most population–level ecological research and in most programs involving management and conservation of animal populations. Abundance is the single parameter of interest in capture–recapture models for closed populations (e.g., Darroch, 1958; Otis et al., 1978; Chao, 2001. The initial capture–recapture models developed for partially (Darroch, 1959 and completely (Jolly, 1965; Seber, 1965 open populations represented efforts to relax the restrictive assumption of population closure for the purpose of estimating abundance. Subsequent emphases in capture–recapture work were on survival rate estimation in the 1970’s and 1980’s (e.g., Burnham et al., 1987; Lebreton et al.,1992, and on movement estimation in the 1990’s (Brownie et al., 1993; Schwarz et al., 1993. However, from the mid–1990’s until the present time, capture–recapture investigators have expressed a renewed interest in abundance and related parameters (Pradel, 1996; Schwarz & Arnason, 1996; Schwarz, 2001. The focus of this session was abundance, and presentations covered topics ranging from estimation of abundance and rate of change in abundance, to inferences about the demographic processes underlying changes in abundance, to occupancy as a surrogate of abundance. The plenary paper by Link & Barker (2004 is provocative and very interesting, and it contains a number of important messages and suggestions. Link & Barker (2004 emphasize that the increasing complexity of capture–recapture models has resulted in large numbers of parameters and that a challenge to ecologists is to extract ecological signals from this complexity. They offer hierarchical models as a natural approach to inference in which traditional parameters are viewed as realizations of stochastic processes. These processes are governed by hyperparameters, and the inferential approach focuses on these hyperparameters. Link & Barker (2004 also suggest that

  10. Abundance estimation and conservation biology

    Science.gov (United States)

    Nichols, J.D.; MacKenzie, D.I.

    2004-01-01

    Abundance is the state variable of interest in most population–level ecological research and in most programs involving management and conservation of animal populations. Abundance is the single parameter of interest in capture–recapture models for closed populations (e.g., Darroch, 1958; Otis et al., 1978; Chao, 2001). The initial capture–recapture models developed for partially (Darroch, 1959) and completely (Jolly, 1965; Seber, 1965) open populations represented efforts to relax the restrictive assumption of population closure for the purpose of estimating abundance. Subsequent emphases in capture–recapture work were on survival rate estimation in the 1970’s and 1980’s (e.g., Burnham et al., 1987; Lebreton et al.,1992), and on movement estimation in the 1990’s (Brownie et al., 1993; Schwarz et al., 1993). However, from the mid–1990’s until the present time, capture–recapture investigators have expressed a renewed interest in abundance and related parameters (Pradel, 1996; Schwarz & Arnason, 1996; Schwarz, 2001). The focus of this session was abundance, and presentations covered topics ranging from estimation of abundance and rate of change in abundance, to inferences about the demographic processes underlying changes in abundance, to occupancy as a surrogate of abundance. The plenary paper by Link & Barker (2004) is provocative and very interesting, and it contains a number of important messages and suggestions. Link & Barker (2004) emphasize that the increasing complexity of capture–recapture models has resulted in large numbers of parameters and that a challenge to ecologists is to extract ecological signals from this complexity. They offer hierarchical models as a natural approach to inference in which traditional parameters are viewed as realizations of stochastic processes. These processes are governed by hyperparameters, and the inferential approach focuses on these hyperparameters. Link & Barker (2004) also suggest that our attention

  11. Clinical trials update from the Heart Failure Society of America Meeting 2009: FAST, IMPROVE-HF, COACH galectin-3 substudy, HF-ACTION nuclear substudy, DAD-HF, and MARVEL-1.

    Science.gov (United States)

    Lainscak, Mitja; Coletta, Alison P; Sherwi, Nasser; Cleland, John G F

    2010-02-01

    This article presents findings and a commentary on late-breaking trials presented during the meeting of the Heart Failure Society of America in September 2009. Unpublished reports should be considered as preliminary, since analyses may change in the final publication. The FAST trial showed somewhat better performance of intrathoracic impedance for prediction of deterioration in patients with heart failure (HF) when compared with daily weighing. The IMPROVE-HF study reported the benefits of education on the management of patients with systolic HF. Galectin-3 appeared a useful method for improving risk stratification of patients with chronic HF in a substudy of the COACH trial. A nuclear substudy of the HF-ACTION trial failed to demonstrate that resting myocardial perfusion imaging, a measure of myocardial scar and viability, was clinically useful. A small randomized controlled trial (DAD-HF) suggested that the use of low-dose dopamine in patients with acutely decompensated HF was associated with less deterioration in renal function and less hypokalaemia. The MARVEL-1 trial raises further concerns about the safety of myoblast transplantation in ischaemic HF.

  12. Distribution and Abundance of Human Specific Bacteroides and Relation to Traditional Indicators in an Urban Tropical Catchment

    Science.gov (United States)

    Nshimyimana, J.; Shanahan, P.; Thompson, J. R.; Ekklesia, E.; Chua Hock Chye, L.

    2012-12-01

    The Singapore government through its Public Utilities Board is interested in opening Kranji Reservoir to recreational use. However, water courses within the Kranji Reservoir catchment contain human fecal indicator bacteria above recreational water quality criteria; their sources and distribution are unknown. The primary goals of this study were to determine the distribution of fecal indicator bacteria in drainages and water bodies in the Kranji reservoir catchment area. Total coliforms, E. coli, and the DNA-based HF marker (targeting a human specific strain of Bacteroides) were quantified in 27 samples collected in January 2009 and 54 samples collected in July 2009. Correlation of HF marker cell equivalents (CE) and E. coli abundance (colony forming units (CFU) or Most Probable Number (MPN)) to different land-use categories revealed potential sources of fecal contamination to the Kranji reservoir. Notably, areas designated as farming/agricultural were associated with the highest levels of E. coli (geometric mean 30,500 CFU/100 ml) and HF marker (1.23±1.13x106 CE/100 ml ± S.D.) while in general lower HF marker and E. coli levels were observed in residential areas, undeveloped areas, and within the Kranji reservoir (i.e. Kranji Reservoir had 2 to 17 MPN/100 ml of E. coli and 103 to 105 HF marker CE/100 ml). A partial survey of potential point sources for fecal contamination within the farming area revealed a wastewater effluent stream with HF marker levels exceeding 107 CE/100ml. As observed in previous studies, total coliforms and E. coli levels were weakly (RBacteroides dorei, an obligate anaerobe that is not expected to grow in aerated surface waters. In contrast, numerous studies have demonstrated that total coliforms, including E. coli, are able to grow well under some tropical conditions, limiting their utility as neutral tracers of fecal contamination in tropical environments. Phylogenetic analysis of cloned HF marker sequences from Kranji reservoir and

  13. Highly efficient capillary columns packed with superficially porous particles via sequential column packing.

    Science.gov (United States)

    Treadway, James W; Wyndham, Kevin D; Jorgenson, James W

    2015-11-27

    Highly efficient capillary columns packed with superficially porous particles were created for use in ultrahigh pressure liquid chromatography. Superficially porous particles around 1.5μm in diameter were packed into fused silica capillary columns with 30, 50, and 75μm internal diameters. To create the columns, several capillary columns were serially packed from the same slurry, with packing progress plots being generated to follow the packing of each column. Characterization of these columns using hydroquinone yielded calculated minimum reduced plate heights as low as 1.24 for the most efficient 30μm internal diameter column, corresponding to over 500,000plates/m. At least one highly efficient column (minimum reduced plate height less than 2) was created for all three of the investigated column inner diameters, with the smallest diameter columns having the highest efficiency. This study proves that highly efficient capillary columns can be created using superficially porous particles and shows the efficiency potential of these particles.

  14. The anisotropy of Hf diffusion in {alpha}-Zr

    Energy Technology Data Exchange (ETDEWEB)

    Hood, G.M. [Atomic Energy of Canada Ltd., Chalk River, ON (Canada). Chalk River Nuclear Labs.]|[Metals Technology Laboratory, CANMET, Ottawa, Ontario (Canada); Zou, H. [Atomic Energy of Canada Ltd., Chalk River, ON (Canada). Chalk River Nuclear Labs.]|[Metals Technology Laboratory, CANMET, Ottawa, Ontario (Canada); Roy, J.A. [Atomic Energy of Canada Ltd., Chalk River, ON (Canada). Chalk River Nuclear Labs.]|[Metals Technology Laboratory, CANMET, Ottawa, Ontario (Canada); Schultz, R.J. [Atomic Energy of Canada Ltd., Chalk River, ON (Canada). Chalk River Nuclear Labs.]|[Metals Technology Laboratory, CANMET, Ottawa, Ontario (Canada); Matsuura, N. [Atomic Energy of Canada Ltd., Chalk River, ON (Canada). Chalk River Nuclear Labs.]|[Metals Technology Laboratory, CANMET, Ottawa, Ontario (Canada); Jackman, J.A. [Atomic Energy of Canada Ltd., Chalk River, ON (Canada). Chalk River Nuclear Labs.]|[Metals Technology Laboratory, CANMET, Ottawa, Ontario (Canada)

    1996-02-01

    Hf diffusion coefficients (D) have been measured ({proportional_to}870-1100 K) in directions parallel (D{sub pa}) and perpendicular (D{sub pe}) to the c-axis of double-faced, single-crystal specimens of both high purity (HP) and nominally pure (NP) {alpha}-Zr. The diffusion profiles were measured by secondary ion mass spectrometry. Hf diffusion in HP {alpha}-Zr is characterised by an activation energy of about 3.0 eV and a pre-exponential factor of about 10{sup -5} m{sup 2}/s. The anisotropy ratio, D{sub pa}/D{sub pe}, is {proportional_to}<1.0 for the HP specimens and mostly >1.0 for the NP specimens. A dependence of D on diffusion time/depth is indicated for some experiments on NP Zr. (orig.).

  15. Photodetachment of HF-in an Electric Field

    Institute of Scientific and Technical Information of China (English)

    WANG De-Hua

    2008-01-01

    @@ Photdetachment of a negative HF-ion in an electric field is studied by using the two-centre model and the closed orbit theory.An analytic formula is presented for the electron flux of HF- in the presence of an electric field.The results show that the oscillation in the electron flux distribution is caused by the rescattering effect of the molecular ion core and the interference betweed the two nuclei.In addition,the interference between the orbits passing through the given spatial point also plays an important role in the electron flux distribution.This study provides a new understanding of the photodetachment of polar molecules in the presence of external field.

  16. Generation of ionospheric ducts by the HAARP HF heater

    Energy Technology Data Exchange (ETDEWEB)

    Cohen, J A; Pradipta, R; Burton, L M; Labno, A; Lee, M C [Massachusetts Institute of Technology, Cambridge, MA 02139 (United States); Watkins, B J; Fallen, C [University of Alaska Fairbanks, Fairbanks, AK 99775 (United States); Kuo, S P [New York University, Brooklyn, NY 11201 (United States); Burke, W J [Air Force Research Laboratory, Hanscom AFB, MA 01731 (United States); Mabius, D; See, B Z, E-mail: mclee@mit.edu [Boston University, Boston, MA 02215 (United States)

    2010-12-15

    We report an investigation of ionospheric ducts having the shape of large plasma sheets, generated by vertically transmitted HAARP HF heater waves in several experiments conducted in Gakona, Alaska. Theory predicts that O-mode heater wave-created ionospheric ducts form parallel-plate waveguides within the meridional plane, and those generated by the X-mode heater waves are orthogonal to the meridional plane. Our theoretical prediction is supported by measurements of ionosonde data (namely ionograms), range-time-intensity (RTI) plots of UHF and HF backscatter radars, as well as magnetometer data analyses. When these plasma sheets experienced ExB drifts, they were intercepted by the HAARP UHF radar and seen as slanted stripes in the RTI plots. This striking feature was also observed in our earlier experiments using the Arecibo UHF radar.

  17. Use of GPS network data for HF Doppler measurements interpretation

    CERN Document Server

    Petrova, Inna R; Latypov, Ruslan R

    2014-01-01

    The method of measurement of Doppler frequency shift of ionospheric signal - HF Doppler technique - is one of well-known and widely used methods of ionosphere research. It allows to research various disturbances in the ionosphere. There are some sources of disturbances in the ionosphere. These are geomagnetic storms, solar flashes, metrological effects, atmospheric waves. This method allows to find out the influence of earthquakes, explosions and other processes on the ionosphere, which occur near to the Earth. HF Doppler technique has the high sensitivity to small frequency variations and the high time resolution, but interpretation of results is difficult. In this work we make an attempt to use GPS data for Doppler measurements interpretation. Modeling of Doppler frequency shift variations with use of TEC allows to separate ionosphere disturbances of medium scale.

  18. Imaging HF-induced large-scale irregularities above HAARP

    Science.gov (United States)

    Djuth, Frank T.; Reinisch, Bodo W.; Kitrosser, David F.; Elder, John H.; Snyder, A. Lee; Sales, Gary S.

    2006-02-01

    The University of Massachusetts-Lowell digisonde is used with the HAARP high-frequency (HF), ionospheric modification facility to obtain radio images of artificially-produced, large-scale, geomagnetic field-aligned irregularities. F region irregularities generated with the HAARP beam pointed in the vertical and geomagnetic field-aligned directions are examined in a smooth background plasma. It is found that limited large-scale irregularity production takes place with vertical transmissions, whereas there is a dramatic increase in the number of source irregularities with the beam pointed parallel to the geomagnetic field. Strong irregularity production appears to be confined to within ~5° of the geomagnetic zenith and does not fill the volume occupied by the HF beam. A similar effect is observed in optical images of artificial airglow.

  19. Performance Analysis of HF Band FB-MC-SS

    Energy Technology Data Exchange (ETDEWEB)

    Hussein Moradi; Stephen Andrew Laraway; Behrouz Farhang-Boroujeny

    2016-01-01

    Abstract—In a recent paper [1] the filter bank multicarrier spread spectrum (FB-MC-SS) waveform was proposed for wideband spread spectrum HF communications. A significant benefit of this waveform is robustness against narrow and partial band interference. Simulation results in [1] demonstrated good performance in a wideband HF channel over a wide range of conditions. In this paper we present a theoretical analysis of the bit error probably for this system. Our analysis tailors the results from [2] where BER performance was analyzed for maximum ration combining systems that accounted for correlation between subcarriers and channel estimation error. Equations are give for BER that closely match the simulated performance in most situations.

  20. The abundances of atomic carbon and carbon monoxide compared with visual extinction in the Ophiuchus molecular cloud complex

    Science.gov (United States)

    Frerking, Margaret A.; Keene, Jocelyn; Blake, Geoffrey A.; Phillips, T. G.

    1989-01-01

    Emission from the 492 GHz lines of C I have been observed toward six positions in the Ophiuchus molecular cloud complex for which accurate visual extinctions are available. The column density of C I increases with A(V) to greater than 2 x 10 to the 17th/sq cm at 100 mag, the column-averaged fractional abundance reaches a peak of about 2.2 x 10 to the -5th for A(V) in the range 4-11 mag and the column-averaged abundance ratio of C I to CO decreases with A(V) from about 1 at 2 mag to greater that about 0.03 at 100 mag. These results imply that, while C I is not the primary reservoir of gaseous carbon even at cloud edges, its fractional abundance remains high for at least 10 mag into the cloud and may be significant at even greater depths.

  1. Early solar system. Stellar origin of the ¹⁸²Hf cosmochronometer and the presolar history of solar system matter.

    Science.gov (United States)

    Lugaro, Maria; Heger, Alexander; Osrin, Dean; Goriely, Stephane; Zuber, Kai; Karakas, Amanda I; Gibson, Brad K; Doherty, Carolyn L; Lattanzio, John C; Ott, Ulrich

    2014-08-08

    Among the short-lived radioactive nuclei inferred to be present in the early solar system via meteoritic analyses, there are several heavier than iron whose stellar origin has been poorly understood. In particular, the abundances inferred for (182)Hf (half-life = 8.9 million years) and (129)I (half-life = 15.7 million years) are in disagreement with each other if both nuclei are produced by the rapid neutron-capture process. Here, we demonstrate that contrary to previous assumption, the slow neutron-capture process in asymptotic giant branch stars produces (182)Hf. This has allowed us to date the last rapid and slow neutron-capture events that contaminated the solar system material at ~100 million years and ~30 million years, respectively, before the formation of the Sun.

  2. Discovery of interstellar ketenyl (HCCO), a surprisingly abundant radical

    CERN Document Server

    Agundez, Marcelino; Guelin, Michel

    2015-01-01

    We have conducted radioastronomical observations of 9 dark clouds with the IRAM 30m telescope. We present the first identification in space of the ketenyl radical (HCCO) toward the starless core Lupus-1A and the molecular cloud L483, and the detection of the related molecules ketene (H2CCO) and acetaldehyde (CH3CHO) in these two sources and 3 additional dark clouds. We also report the detection of the formyl radical (HCO) in the 9 targeted sources and of propylene (CH2CHCH3) in 4 of the observed sources, which extends significantly the number of dark clouds where these molecules are known to be present. We derive a beam-averaged column density of HCCO of 5e11 cm-2 in both Lupus-1A and L483, which means that the ketenyl radical is just 10 times less abundant than ketene in these sources. The non-negligible abundance of HCCO found implies that there must be a powerful formation mechanism able to counterbalance the efficient destruction of this radical through reactions with neutral atoms. The column densities d...

  3. Investigation of new type Cu-Hf-Al bulk glassy alloys

    Science.gov (United States)

    Nagy, E.; Rontó, V.; Sólyom, J.; Roósz, A.

    2009-01-01

    In the last years new type Cu-Hf-Al ternary alloys were developed with high glass forming ability and ductility. The addition of Al to Cu-Hf alloys results in improvements in glass formation, thermal stability and mechanical properties of these alloys. We have investigated new Cu-based bulk amorphous alloys in Cu-Hf-Al ternary system. The alloys with Cu49Hf42Al9, Cu46Hf45Al9, Cu50Hf42.5Al7.5 and Cu50Hf45Al5 compositions were prepared by arc melting. The samples were made by centrifugal casting and were investigated by X-ray diffraction method. Thermodynamic properties were examined by differential scanning calorimetry and the structure of the crystallising phases by scanning electron microscopy. The determination of liquidus temperatures of alloys were measured by differential thermal analysis.

  4. First-principles studies of HF molecule adsorption on intrinsic graphene and Al-doped graphene

    Science.gov (United States)

    Sun, Yuanyuan; Chen, Li; Zhang, Feiwu; Li, Daoyong; Pan, Hongzhe; Ye, Jun

    2010-10-01

    In the search for a high-sensitivity sensor for HF gas, the adsorption of HF molecules on both intrinsic and Al-doped graphene sheets is studied by first-principles calculations. We find that the adsorption mechanisms of HF molecules are different for intrinsic graphene and Al-doped graphene. Al-doped graphene has higher adsorption energy and shorter connecting distance to the HF molecule than intrinsic graphene. The calculated net electron transfers, electronic density difference images and densities of states give evidence that the adsorption of HF molecules on Al-doped graphene is by chemisorption, while there is weak physisorption on intrinsic graphene. Therefore, Al-doped graphene can be expected to have applications as a novel sensor for the detection of HF gas. The HF molecules adsorbed on Al-doped graphene material can be reactivated by applying an external electric field of 0.013 a.u.

  5. Ferroelectric HfO2 for Emerging Ferroelectric Semiconductor Devices

    Science.gov (United States)

    Florent, Karine

    The spontaneous polarization in ferroelectrics (FE) makes them particularly attractive for non-volatile memory and logic applications. Non-volatile FRAM memories using perovskite structure materials, such as Lead Zirconate Titanate (PZT) and Strontium Bismuth Tantalate (SBT) have been studied for many years. However, because of their scaling limit and incompatibility with CMOS beyond 130 nm node, floating gate Flash memory technology has been preferred for manufacturing. The recent discovery of ferroelectricity in doped HfO2 in 2011 has opened the door for new ferroelectric based devices compatible with CMOS technology, such as Ferroelectric Field Effect Transistor (FeFET) and Ferroelectric Tunnel Junctions (FTJ). This work began with developing ferroelectric hysteresis characterization capabilities at RIT. Initially reactively sputtered aluminum doped HfO 2 films were investigated. It was observed that the composition control using co-sputtering was not achievable within the existing capabilities. During the course of this study, collaboration was established with the NaMLab group in Germany to investigate Si doped HfO2 deposited by Atomic Layer Deposition (ALD). Metal Ferroelectric Metal (MFM) devices were fabricated using TiN as the top and bottom electrode with Si:HfO2 thickness ranging from 6.4 nm to 22.9 nm. The devices were electrically tested for P-E, C-V and I-V characteristics. Structural characterizations included TEM, EELS, XRR, XRD and XPS/Auger spectroscopy. Higher remanant polarization (Pr) was observed for films of 9.3 nm and 13.1 nm thickness. Thicker film (22.9 nm) showed smaller Pr. Devices with 6.4 nm thick films exhibit tunneling behavior showing a memristor like I-V characteristics. The tunnel current and ferroelectricity showed decrease with cycling indicating a possible change in either the structure or the domain configurations. Theoretical simulations using the improved FE model were carried out to model the ferroelectric behavior of

  6. Centrifugal stretching of 170Hf in the interacting boson model

    Directory of Open Access Journals (Sweden)

    Werner V.

    2014-03-01

    Full Text Available We present the results of a recent experiment to deduce lifetimes of members of the ground state rotational band of 170Hf, which show the effect of centrifugal stretching in this deformed isotope. Results are compared to the geometrical confined beta-soft(CBS rotor model, as well as to the interacting boson model (IBM. Two methods to correct for effects due to the finite valence space within the IBM are proposed.

  7. Electrochemical characterization of cast Ti-Hf binary alloys.

    Science.gov (United States)

    Cai, Z; Koike, M; Sato, H; Brezner, M; Guo, Q; Komatsu, M; Okuno, O; Okabe, T

    2005-05-01

    This study characterized the electrochemical behavior of Ti-Hf binary alloys in a simulated oral environment. Ti-Hf alloys (10, 20, 25, 30, 35 and 40 mass% Hf) were prepared by arc-melting titanium sponge and hafnium sponge. Specimens of each alloy (n = 4) were prepared using a dental titanium casting system with a MgO-based investment. Specimens were inspected with X-ray radiography to ensure minimal internal porosity. Castings (n = 4) made from pure titanium and commercially pure titanium were used as controls. The ground flat surface (10 mm x 10 mm) on each specimen where approximately 30 microm was removed was used for the characterization. Sixteen-hour open-circuit potential (OCP) measurement, linear polarization and potentiodynamic cathodic polarization were performed sequentially in aerated (air + 10% CO2) MTZ synthetic saliva at 37 degrees C. Potentiodynamic anodic polarization was conducted in the same medium but deaerated (N2 + 10% CO2) 2 h before and during testing. Polarization resistance (R(P)) and Tafel slopes were determined, as were corrosion current density (I(CORR)) and passive current density (I(PASS)). Results were subjected to nonparametric statistical analysis (alpha = 0.05). The OCP stabilized (mean values -229 mV to -470 mV vs. SCE) for all specimens after the 16-h immersion. Similar passivation was observed for all the metals on their anodic polarization diagrams. The Kruskal-Wallis test showed significant differences in OCP among the test groups (p = 0.006). No significant differences were found in R(P), I(CORR) or I(PASS) among all the metals (p>0.3). Results indicate that the electrochemical behavior of the Ti-Hf alloys examined resembles that of pure titanium.

  8. Self-healing structural properties of thermoplastics in HF field

    Directory of Open Access Journals (Sweden)

    N. G. Filippenko

    2014-01-01

    Full Text Available The article concerns one of the possible ways for safe operation of polymer products with initiating a process of their self-healing. This is especially true for products from polymer materials, used in hard-to-reach areas and units of machines and mechanisms. In this regard, the aim of this study was to develop techniques for a self-healing process of the mechanical properties of products from polymer materials.To achieve this goal, the author has solved problems to define a complex method of HF self-healing of polymer material: damage detection in products from polymer materials, determination of signal initiating the recovery process, determining the efficiency of material regeneration. The present study uses proposed and developed by the author methods for the determination of necessary and sufficient indicators of the strength characteristics of products under realmeteorological and climatic conditions of their operation.To determine the practical results of the developed algorithm for self-healing the polymer products in the HF field, a series of experimental studies has been conducted to regenerate the polyamide cage fatigue destruction of the rolling stock axle equipment of Russian Railways JSC.The obtained results of the strength characteristics of the material under investigation prove the self-healing process of polymer materials in HF field.According to research results, the conclusion is drawn that it is required to provide a technological HF self-healing process of products from polymer materials. The created algorithm of regeneration enables a new approach to study the effects of electromagnetic fields on polymer and polymer-based composite materials when solving the practical tasks to improve the quality of repairing parts from thermoplastics.

  9. Hf--Co--B alloys as permanent magnet materials

    Science.gov (United States)

    McGuire, Michael Alan; Rios, Orlando; Ghimire, Nirmal Jeevi

    2017-01-24

    An alloy composition is composed essentially of Hf.sub.2-XZr.sub.XCo.sub.11B.sub.Y, wherein 0B.sub.Y, wherein 0.ltoreq.X<2 and 0

  10. Ionizing wave via high-power HF acceleration

    CERN Document Server

    Mishin, Evgeny

    2010-01-01

    Recent ionospheric modification experiments with the 3.6 MW transmitter at the High Frequency Active Auroral Research Program (HAARP) facility in Alaska led to discovery of artificial ionization descending from the nominal interaction altitude in the background F-region ionosphere by ~60 km. This paper presents a physical model of an ionizing wavefront created by suprathermal electrons accelerated by the HF-excited plasma turbulence.

  11. Study on Preparation of 182Hf AMS Standards

    Institute of Scientific and Technical Information of China (English)

    YINXin-yi; JIANGShan; HEMing; ZHANGChun-hua; ZHANGSheng-dong

    2003-01-01

    The neutron-rich isotope 182Hf with its half-life of (9±2)×106 a produced by neutron activation can be used to determine the neutron flux of some places, in order to study the transport of radioactive nuclides and the safe disposal of nuclear waste. AMS is a kind of relative measurement method with high sensitivity (10-15), it requires corresponding standard samples.

  12. Ionizing wave via high-power HF acceleration

    OpenAIRE

    Mishin, Evgeny; Pedersen, Todd

    2010-01-01

    Recent ionospheric modification experiments with the 3.6 MW transmitter at the High Frequency Active Auroral Research Program (HAARP) facility in Alaska led to discovery of artificial ionization descending from the nominal interaction altitude in the background F-region ionosphere by ~60 km. This paper presents a physical model of an ionizing wavefront created by suprathermal electrons accelerated by the HF-excited plasma turbulence.

  13. On the Onset of HF-Induced Airglow at HAARP

    Science.gov (United States)

    2007-11-02

    AFRL-VS-HA-TR-2005-1061 JOURNAL OF GEOPHYSICAL RESEARCH, VOL. 109, A02305, doi:10.1029/2003JA010205, 2004 On the onset of HF-induced airglow at HAARP ...line) during the February 2002 campaign at the High Frequency Active Auroral Research Program ( HAARP ) heating facility are analyzed. We find that... HAARP , J. Geophys. Res., 109, A02305, doi: 10.1029/2003JA010205. 1. Introduction known as the parametric decay (PDI) or oscillating two- [2] A

  14. HF Over-the-Horizon Radar System Performance Analysis

    Science.gov (United States)

    2007-09-01

    target detection technique and radar equations are applied. Chapter V uses PROPLAB model simulation to bring in the principle of raytracing and... RADAR SYSTEM PERFORMANCE ANALYSIS by Bin-Yi Liu September 2007 Thesis Co-Advisors: Phillip E. Pace Jeffrey B. Knorr THIS PAGE...Thesis 4. TITLE AND SUBTITLE HF Over-the-Horizon Radar System Performance Analysis 6. AUTHOR(S) Bin-Yi Liu 5. FUNDING NUMBERS 7. PERFORMING

  15. Wideband high frequency (HF) skywave channel parameters from narrowband measurements

    Science.gov (United States)

    Hausman, Cynthia L.; Uffelman, Donald R.; Walton, Thomas L.

    The HF wideband channel allow the use of spread-spectrum techniques to provide covert communications with low probability of intercept (LPI) and antijam protection. The objective of this work is to determine the extent to which oblique narrowband channel measurements can be used to infer effects in the wideband skywave channel. If oblique narrowband channel measurements can be used as a basis for developing wideband channel models, a large number of existing narrowband measurements can be made available for this task.

  16. Column measurements of stratospheric trace species over Are, Sweden in the winter of 1991-1992

    Science.gov (United States)

    Bell, W.; Martin, N. A.; Gardiner, T. D.; Swann, N. R.; Woods, P. T.; Fogal, P. F.; Waters, J. W.

    1994-01-01

    Total vertical column amounts of stratospheric HCl, HF, ClONO2 and HNO3 are reported from high resolution infrared solar absorption spectra taken during the European Arctic Stratospheric Ozone Experiment (EASOE) in the winter of 1991-1992. These ground based measurements were made near Are in North Sweden (63.4 deg N, 13.1 deg E) at an altitude of 800 m using a Fourier transform spectrometer and tunable diode laser heterodyne spectrometer. On 9th January 1992 the HCl vertical column dropped to 1.2 x 10(exp 15) molecules/sq cm from a November average of 3.6 x 10(exp 15) molecules/sq cm. The HCl drop occurred at a time when Are was below the polar vortex and the lower stratospheric ClO column above Are was elevated to approximately 2 x 10(exp 15) molecules/sq cm as measured by the Microwave Limb Sounder experiment on the Upper Atmosphere Research Satellite. These measurements indicate conversion of lower stratospheric chlorine from reservoir to chemically active forms.

  17. Response of Atmospheric-Methane Oxidation to Methane-Flux Manipulation in a Laboratory Soil-Column Experiment

    Science.gov (United States)

    Schroth, M. H.; Mignola, I.; Henneberger, R.

    2015-12-01

    Upland soils are an important sink for atmospheric methane (CH4). Uptake of atmospheric CH4 in soils is generally diffusion limited, and is mediated by aerobic CH4 oxidizing bacteria (MOB) that possess a high-affinity form of a key enzyme, allowing CH4 consumption at near-atmospheric concentrations (≤ 1.9 µL/L). As cultivation attempts for these high-affinity MOB have shown little success, there remains much speculation regarding their functioning in different environments. For example, it is frequently assumed that they are highly sensitive to physical disturbance, but their response in activity and abundance to changes in substrate availability remains largely unknown. We present results of a laboratory column experiment conducted to investigate the response in activity and abundance of high-affinity MOB to an increase in CH4 flux. Intact soil cores, collected at a field site where atmospheric CH4 oxidation activity is frequently quantified, were transferred into two 1-m-long, 12-cm-dia. columns. The columns were operated at constant temperature in the dark, their headspace being continuously flushed with air. Diffusive gas-transport conditions were maintained in the reference column, whereas CH4 flux was increased in several steps in the treatment column by inducing advective gas flow using a diaphragm pump. Soil-gas samples periodically collected from ports installed along the length of the columns were analyzed for CH4 content. Together with measurements of soil-water content, atmospheric CH4 oxidation was quantified using the soil-profile method. First results indicate that atmospheric CH4 oxidation activity comparable with the field was maintained in the reference column throughout the experiment. Moreover, high-affinity MOB quickly adjusted to an increase in CH4 flux in the treatment column, efficiently consuming CH4. Quantification of MOB abundance is currently ongoing. Our data provide new insights into controls on atmospheric CH4 oxidation in soils.

  18. Detection of HCl and HF by TTFMS and WMS.

    Science.gov (United States)

    De Luca, Anna Chiara; Pesce, Giuseppe; Rusciano, Giulia; Sasso, Antonio

    2006-04-01

    In this work we discuss on a compact spectrometer based on DFB diode lasers for detection of chloridric and fluoridric acids. HCl and HF concentrations are determined through optical absorption of the P(4) line (lambda=1.7 microm) and the R(3) line (lambda=1.3 microm), respectively. Both lines belong to first overtone vibrational bands and their line strengths are 7.8 x 10(-21)cm/molecule for HCl and 2.8 x 10(-20)cm/molecule for HF. We chose these lines for their relative high intensities and because they are quite far from water vapour lines which represent the main interfering gas for trace-gases analysis. To detect these species we used two different high frequency modulation techniques: two-tone frequency modulation spectroscopy (f(1)=800 MHz and f(2)=804 MHz) was used for HCl while for HF we followed a simpler approach based on wavelength modulation spectroscopy (f=600 kHz). We demonstrate that the two techniques provide comparable detection limit of about 80 ppbV at atmospheric pressure. Positive testing of our spectrometer makes it suitable for in situ measurements of exhaust gases coming from waste incinerators.

  19. Multiple excitation modes in 163Hf

    DEFF Research Database (Denmark)

    Yadav, Rachita; Ma, J.C.; Marsh, J.C.

    2014-01-01

    Excited states of Hf163 were populated using the Zr94(Ge74,5n) reaction and the decay γ rays were measured with the Gammasphere spectrometer. Two previously known bands were extended to higher spins, and nine new bands were identified. In addition to bands associated with three- and five-quasipar......Excited states of Hf163 were populated using the Zr94(Ge74,5n) reaction and the decay γ rays were measured with the Gammasphere spectrometer. Two previously known bands were extended to higher spins, and nine new bands were identified. In addition to bands associated with three- and five......-quasiparticle configurations, two γ−vibrational bands coupled to the i13/2 excitation were also observed. The lowest level of a newly identified, negative-parity band is proposed to be the ground state of the nucleus. A systematic delay of the high-spin proton crossing frequency with increasing quadrupole deformation from Hf...

  20. Electronic structures and properties of Ti, Zr and Hf metals

    Institute of Scientific and Technical Information of China (English)

    2001-01-01

    The electronic structures of pure Ti, Zr and Hf metals with hcp structure were determined by one-atom (OA) theory. According to the electronic structures of these metals,their potential curves, cohesive energies, lattice constants, elasticities and the temperature dependence of linear thermal expansion coefficients were calculated. The electronic structures and characteristic properties of these metals with bcc and fcc structures and liquids were also studied. The results show that the electronic structures of Ti, Zr and Hf metals are respectively [Ar](3dn)0.481 0(3dc)2.085 7(4sc)1.000 0(4sf)0.433 3, [Kr](4dn)0.396 8(4dc)2.142 8(5sc)1.262 0(5sf)0.198 4, [Xe](5dn)0.368 0(5dc)2.041 4(6sc)1.406 6(6sf)0.184 0. It is explained why the pure Ti, Zr and Hf metals with hcp and bcc structures can exist naturally, while those with fcc structure can not.

  1. Lu-Hf and Sm-Nd garnet geochronology

    DEFF Research Database (Denmark)

    Smit, Matthijs Arjen; Scherer, Erik E.; Mezger, Klaus

    2013-01-01

    are similar among grains having radii larger than 1.3 mm (weighted mean: 2714±6 Ma2714±6 Ma; 2 s.d.) and up to 20 Myr younger for finer fractions. In contrast, Sm–Nd dates are equal to or younger than the 2641–2637 Ma age of peak metamorphism. The roles of concurrently digested inclusions and core–rim Lu......To investigate the systematics of the 176Lu–176Hf and 147Sm–143Nd garnet chronometers, we performed REE and isotope analyses on garnet crystals of different size (0.55–3.1 mm radius) from a single granulite specimen (Archean Pikwitonei Granulite Domain, Manitoba, Canada). The Lu–Hf dates....../Sm fractionation are quantitatively evaluated and excluded as causes for the observed age heterogeneity. Instead, the isotope dates are interpreted to reflect partial loss of radiogenic 176Hf and 143Nd, and are used to constrain the systematics of the garnet chronometers at high temperature. The data constrain...

  2. TID measurement using oblique transmissions of HF pulses

    Science.gov (United States)

    Galkin, Ivan; Reinisch, Bodo; Huang, Xueqin; Paznukhov, Vadym; Hamel, Ryan; Kozlov, Alexander; Belehaki, Anna

    2017-04-01

    The Traveling Ionospheric Disturbance (TID), a wave-like signature of moving plasma density modulation in the ionosphere, is widely acknowledged for its utility in backtracking the anomalous events responsible for the TID generation, and as a major inconvenience to high-frequency (HF) operational systems because of its deleterious impact on the accuracy of navigation and geolocation. The pilot project "Net-TIDE" for the real-time detection and evaluation of TIDs began its operation in 2016 based on the remote-sensing data from synchronized, network-coordinated HF sounding between pairs of DPS4D ionosondes at five participating observatories in Europe. Measurement of all signal properties (Doppler frequency, angle of arrival, and time-of-flight from transmitter to receiver) proved to be instrumental in detecting the TID and deducing the TID parameters: amplitude, wavelength, phase velocity, and direction of propagation. Processing of the measured HF signal data required a specialized signal processing technique that is capable of consistently extracting different signals that have propagated along different ionospheric paths. The multi-path signal environment proved to be the greatest challenge for the reliable TID specification by Net-TIDE, demanding the development of an intelligent system for "signal tracking". The intelligent system is based on a neural network model of a pre-attentive vision capable of extracting continuous signal tracks from the multi-path signal ensemble. Specific examples of the Net-TIDE algorithm suite operation and its suitability for a fully automated TID warning service are discussed.

  3. Dynamic Effects of Diabatization in Distillation Columns

    DEFF Research Database (Denmark)

    Bisgaard, Thomas; Huusom, Jakob Kjøbsted; Abildskov, Jens

    2012-01-01

    The dynamic eects of diabatization in distillation columns are investigated in simulation with primary focus on the heat-integrated distillation column (HIDiC). A generic, dynamic, rst-principle model has been formulated, which is exible to describe various diabatic distillation congurations....... Dynamic Relative Gain Array and Singular Value Analysis have been applied in a comparative study of a conventional distillation column and a HIDiC. The study showed increased input-output coupling due to diabatization. Feasible SISO control structures for the HIDiC were also found. Control...

  4. Dynamic effects of diabatization in distillation columns

    DEFF Research Database (Denmark)

    Bisgaard, Thomas; Huusom, Jakob Kjøbsted; Abildskov, Jens

    2013-01-01

    The dynamic effects of diabatization in distillation columns are investigated in simulation emphasizing the heat-integrated distillation column (HIDiC). A generic, dynamic, first-principle model has been formulated, which is flexible enough to describe various diabatic distillation configurations....... Dynamic Relative Gain Array and Singular Value Analysis have been applied in a comparative study of a conventional distillation column and a HIDiC. The study showed increased input-output coupling due to diabatization. Feasible SISO control structures for the HIDiC were also found and control...

  5. 29 CFR 1926.756 - Beams and columns.

    Science.gov (United States)

    2010-07-01

    ... (.46 m) from the extreme outer face of the column in each direction at the top of the column shaft. (e) Perimeter columns. Perimeter columns shall not be erected unless: (1) The perimeter columns extend a minimum of 48 inches (1.2 m) above the finished floor to permit installation of perimeter safety cables prior...

  6. High-spin positive-parity states in 179Hf studied by the 180Hf(τ, α) 179Hf reaction AT 32 MeV

    Science.gov (United States)

    Thorsteinsen, T. F.; Løvhøiden, G.; Vaagen, J. S.; Bjørnberg, A.; Burke, D. G.

    1981-06-01

    Full angular distributions are presented for states populated in the reaction 180Hf(τ, α) 179Hf at 32 MeV beam energy. Positive-parity states associated with the i {13}/{2} unique parity intruder orbital are given special attention. Thus, angular distributions for the five first members of the [624 {9}/{2}] groundstate sequence are given, as well as for a number of more highly excited states, some being new assignments. The distribution of l = 6 transfer strength is quite characteristic, two {13}/{2}+ states being substantially more populated than the rest. The characteristic features of the data are explained by a quasiparticle-rotor calculation employing deformed Woods-Saxon orbitals, but only if the hexadecapole shape parameter of the nuclear potential is β 4 ˜ -0.08. The often anomalous differential cross sections for I π ≠ {13}/{2}+ band members are well accounted for by a rotor model CCBA calculation employing transfer form factors extracted from the orbitals of the deformed Woods-Saxon field, and including non-adiabatic Coriolis mixing effects.

  7. Revisited fluorine abundances in the globular cluster M22 (NGC 6656)

    CERN Document Server

    de Laverny, P

    2013-01-01

    Fluorine is a fairly good tracer of formation histories of multiple stellar populations in globular clusters as already revealed by several studies. Large variations in fluorine abundance in red giant stars of the globular cluster M22 have been recently reported by two different groups. Futhermore, one of these studies claims that the abundance of fluorine is anti-correlated with sodium abundances in this cluster, leading to strong conclusions on the chemical history of M22. To validate this important finding, we re-examine the F abundance determinations of some of the previously studied stars. We have thus reanalysed some high-resolution VLT/CRIRES spectra of RGB stars found in M22 in order to re-estimate their fluorine abundance from the spectral synthesis of the HF line at 2.336microns. Unlike what has been previously estimated, we show that only upper limits or doubtful fluorine abundances with large uncertainties in M22 RGB stars can be derived. This is probably caused by an incorrect identification of c...

  8. The Abundance of Fluorine in Normal G and K Stars of the Galactic Thin Disk

    CERN Document Server

    Pilachowski, Catherine A

    2015-01-01

    The abundance of fluorine is determined from the (2-0) R9 2.3358 micron feature of the molecule HF for several dozen normal G and K stars in the Galactic thin disk from spectra obtained with the Phoenix IR spectrometer on the 2.1-m telescope at Kitt Peak. The abundances are analyzed in the context of Galactic chemical evolution to explore the contributions of supernovae and asymptotic giant branch (AGB) stars to the abundance of fluorine in the thin disk. The average abundance of fluorine in the thin disk is found to be [F/Fe] = +0.23 +/- 0.03, and the [F/Fe] ratio is flat or declines slowly with metallicity in the range from -0.6 < [Fe/H] < +0.3, within the limits of our estimated uncertainty. The measured abundance of fluorine and lack of variation with metallicity in Galactic thin disk stars suggest neutrino spallation in Type II supernovae contributes significantly to the Galactic fluorine abundance, although contributions from AGB stars may also be important.

  9. Retrieval of tropospheric NO2 columns from SCIAMACHY combining measurements from limb and nadir geometries

    Directory of Open Access Journals (Sweden)

    F. Stordal

    2012-07-01

    Full Text Available Satellite measurements of atmospheric trace gases have proved to be an invaluable tool for monitoring the Earth system. When these measurements are to be used for assessing tropospheric emissions and pollution, as for example in the case of nadir measurements of nitrogen dioxide (NO2, it is necessary to separate the stratospheric from the tropospheric signal. The SCIAMACHY instrument offers the unique opportunity to combine its measurements in limb and nadir viewing geometries into a tropospheric data product, using the limb measurements of the stratospheric NO2 abundances to correct the nadir measurements' total columns. In this manuscript, we present a novel approach to limb/nadir matching, calculating one stratospheric NO2 value from limb measurements for every single nadir measurement, abandoning global coverage for the sake of spatial accuracy. As a comparison, modelled stratospheric NO2 columns from the Oslo CTM2 are evaluated as stratospheric correction, and both datasets are confronted with the originally used reference sector method. Our study shows that stratospheric NO2 columns from SCIAMACHY limb measurements very well reflect stratospheric conditions. The zonal variability of stratospheric NO2 is captured by our matching algorithm, and the quality of the resulting tropospheric NO2 columns improves considerably. Modelled stratospheric NO2 columns from the Oslo CTM2 agree remarkably well with the measurements. Both datasets need to be matched to the level of the nadir measurements, however, because a time and latitude dependent bias between both stratospheric datasets and the measured nadir columns can be observed over clean regions. After accounting for this systematic bias between SCIAMACHY nadir observations and the stratospheric columns, both new stratospheric correction methods provide a significant improvement to the retrieval of tropospheric NO2 columns from the SCIAMACHY instrument.

  10. CO abundance variations in the Orion Molecular Cloud

    Science.gov (United States)

    Ripple, F.; Heyer, M. H.; Gutermuth, R.; Snell, R. L.; Brunt, C. M.

    2013-05-01

    Infrared stellar photometry from the Two Micron All-Sky Survey (2MASS) and spectral line imaging observations of 12CO and 13CO J = 1-0 line emission from the Five College Radio Astronomy Observatory (FCRAO) 14-m telescope are analysed to assess the variation of the CO abundance with physical conditions throughout the Orion A and Orion B molecular clouds. Three distinct Av regimes are identified in which the ratio between the 13CO column density and visual extinction changes corresponding to the photon-dominated envelope, the strongly self-shielded interior, and the cold, dense volumes of the clouds. Within the strongly self-shielded interior of the Orion A cloud, the 13CO abundance varies by 100 per cent with a peak value located near regions of enhanced star formation activity. The effect of CO depletion on to the ice mantles of dust grains is limited to regions with Av > 10 mag and gas temperatures less than ˜20 K as predicted by chemical models that consider thermal evaporation to desorb molecules from grain surfaces. Values of the molecular mass of each cloud are independently derived from the distributions of Av and 13CO column densities with a constant 13CO-to-H2 abundance over various extinction ranges. Within the strongly self-shielded interior of the cloud (Av> 3 mag), 13CO provides a reliable tracer of H2 mass with the exception of the cold, dense volumes where depletion is important. However, owing to its reduced abundance, 13CO does not trace the H2 mass that resides in the extended cloud envelope, which comprises 40-50 per cent of the molecular mass of each cloud. The implied CO luminosity to mass ratios, M/LCO, are 3.2 and 2.9 for Orion A and Orion B, respectively, which are comparable to the value (2.9), derived from γ-ray observations of the Orion region. Our results emphasize the need to consider local conditions when applying CO observations to derive H2 column densities.

  11. Electrical characteristics of MOS capacitor with HfTiON gate dielectric and HfTiSiON interlayer

    Institute of Scientific and Technical Information of China (English)

    Chen Wei-Bing; Xu Jing-Ping; Lai Pui-To; Li Yan-Ping; Xu Sheng-Guo; Chan Chu-Lok

    2006-01-01

    The paper reports that HfTiO dielectric is deposited by reactive co-sputtering of Hf and Ti targets in an Ar/O2 ambience, followed by an annealing in different gas ambiences of N2, NO and NHa at 600°C for 2 min. Capacitance-voltage and gate-leakage properties are characterized and compared. The results indicate that the NO-annealed sample exhibits the lowest interface-state and dielectric-charge densities and best device reliability. This is attributed to the fact that nitridation can create strong Si≡N bonds to passivate dangling Si bonds and replace strained Si- O bonds, thus the sample forms a hardened dielectric/Si interface with high reliability.

  12. Sm Transition Probabilities and Abundances

    CERN Document Server

    Lawler, J E; Sneden, C; Cowan, J J

    2005-01-01

    Radiative lifetimes, accurate to +/- 5%, have been measured for 212 odd-parity levels of Sm II using laser-induced fluorescence. The lifetimes are combined with branching fractions measured using Fourier-transform spectrometry to determine transition probabilities for more than 900 lines of Sm II. This work is the largest-scale laboratory study to date of Sm II transition probabilities using modern methods. This improved data set has been used to determine a new solar photospheric Sm abundance, log epsilon = 1.00 +/- 0.03, from 26 lines. The spectra of three very metal-poor, neutron-capture-rich stars also have been analyzed, employing between 55 and 72 Sm II lines per star. The abundance ratios of Sm relative to other rare earth elements in these stars are in agreement, and are consistent with ratios expected from rapid neutron-capture nucleosynthesis (the r-process).

  13. Element abundances at high redshift

    Energy Technology Data Exchange (ETDEWEB)

    Meyer, D.M.; Welty, D.E.; York, D.G. (Northwestern Univ., Evanston, IL (USA); Chicago Univ., IL (USA))

    1989-08-01

    Abundances of Si(+), S(+), Cr(+), Mn(+), Fe( ), and Zn(+) are considered for two absorption-line systems in the spectrum of the QSO PKS 0528 - 250. Zinc and sulfur are underabundant, relative to H, by a factor of 10 compared to their solar and Galactic interstellar abundances. The silicon-, chromium-, iron-, and nickel-to-hydrogen ratios are less than the solar values and comparable to the local interstellar ratios. A straightforward interpretation is that nucleosynthesis in these high-redshift systems has led to only about one-tenth as much heavy production as in the gas clouds around the sun, and that the amount of the observed underabundances attributable to grain depletion is small. The dust-to-gas ratio in these clouds is less than 8 percent of the Galactic value. 25 refs.

  14. Element abundances at high redshift

    Science.gov (United States)

    Meyer, David M.; Welty, D. E.; York, D. G.

    1989-01-01

    Abundances of Si(+), S(+), Cr(+), Mn(+), Fe(_), and Zn(+) are considered for two absorption-line systems in the spectrum of the QSO PKS 0528 - 250. Zinc and sulfur are underabundant, relative to H, by a factor of 10 compared to their solar and Galactic interstellar abundances. The silicon-, chromium-, iron-, and nickel-to-hydrogen ratios are less than the solar values and comparable to the local interstellar ratios. A straightforward interpretation is that nucleosynthesis in these high-redshift systems has led to only about one-tenth as much heavy production as in the gas clouds around the sun, and that the amount of the observed underabundances attributable to grain depletion is small. The dust-to-gas ratio in these clouds is less than 8 percent of the Galactic value.

  15. Nightside studies of coherent HF Radar spectral width behaviour

    Directory of Open Access Journals (Sweden)

    E. E. Woodfield

    Full Text Available A previous case study found a relationship between high spectral width measured by the CUTLASS Finland HF radar and elevated electron temperatures observed by the EISCAT and ESR incoherent scatter radars in the post-midnight sector of magnetic local time. This paper expands that work by briefly re-examining that interval and looking in depth at two further case studies. In all three cases a region of high HF spectral width (>200 ms-1 exists poleward of a region of low HF spectral width (<200 ms-1. Each case, however, occurs under quite different geomagnetic conditions. The original case study occurred during an interval with no observed electrojet activity, the second study during a transition from quiet to active conditions with a clear band of ion frictional heating indicating the location of the flow reversal boundary, and the third during an isolated sub-storm. These case studies indicate that the relationship between elevated electron temperature and high HF radar spectral width appears on closed field lines after 03:00 magnetic local time (MLT on the nightside. It is not clear whether the same relationship would hold on open field lines, since our analysis of this relationship is restricted in latitude. We find two important properties of high spectral width data on the nightside. Firstly the high spectral width values occur on both open and closed field lines, and secondly that the power spectra which exhibit high widths are both single-peak and multiple-peak. In general the regions of high spectral width (>200 ms-1 have more multiple-peak spectra than the regions of low spectral widths whilst still maintaining a majority of single-peak spectra. We also find that the region of ion frictional heating is collocated with many multiple-peak HF spectra. Several mechanisms for the generation of high spectral width have been proposed which would produce multiple-peak spectra, these are discussed in relation to

  16. Mechanical behavior of confined self-compacting reinforced concrete circular columns under concentric axial loading

    Directory of Open Access Journals (Sweden)

    Fouad Khairallah

    2013-12-01

    Full Text Available While there is abundant research information on ordinary confined concrete, there are little data on the behavior of Self-Compacting Concrete (SCC under such condition. Due to higher shrinkage and lower coarse aggregate content of SCC compared to that of Normal Concrete (NC, its composite performance under confined conditions needs more investigation. This paper has been devoted to investigate and compare the mechanical behavior of confined concrete circular columns cast with SCC and NC under concentric axial loading. The parameters affecting are including concrete compressive strength and confinement configuration. Twenty column specimens were casted and confined using four confinement techniques, CFRP wrap, FRP tube, GFRP wrap, and spiral steel hoops. The performance of the tested column specimens is evaluated based on mode of failure, load–displacement curve, stress–strain characteristics, ultimate strength, ductility, and degree of confinement.

  17. Carbon monoxide total column retrievals from TROPOMI shortwave infrared measurements

    Science.gov (United States)

    Landgraf, Jochen; aan de Brugh, Joost; Scheepmaker, Remco; Borsdorff, Tobias; Hu, Haili; Houweling, Sander; Butz, Andre; Aben, Ilse; Hasekamp, Otto

    2016-10-01

    The Tropospheric Monitoring Instrument (TROPOMI) spectrometer is the single payload of the Copernicus Sentinel 5 Precursor (S5P) mission. It measures Earth radiance spectra in the shortwave infrared spectral range around 2.3 µm with a dedicated instrument module. These measurements provide carbon monoxide (CO) total column densities over land, which for clear sky conditions are highly sensitive to the tropospheric boundary layer. For cloudy atmospheres over land and ocean, the column sensitivity changes according to the light path through the atmosphere. In this study, we present the physics-based operational S5P algorithm to infer atmospheric CO columns satisfying the envisaged accuracy ( information on atmospheric scattering. For efficient processing, we deploy a linearized two-stream radiative transfer model as forward model and a profile scaling approach to adjust the CO abundance in the inversion. Based on generic measurement ensembles, including clear sky and cloudy observations, we estimated the CO retrieval precision to be ≤ 11 % for surface albedo ≥ 0.03 and solar zenith angle ≤ 70°. CO biases of ≤ 3 % are introduced by inaccuracies in the methane a priori knowledge. For strongly enhanced CO concentrations in the tropospheric boundary layer and for cloudy conditions, CO errors in the order of 8 % can be introduced by the retrieval of cloud parameters of our algorithm. Moreover, we estimated the effect of a distorted spectral instrument response due to the inhomogeneous illumination of the instrument entrance slit in the flight direction to be < 2 % with pseudo-random characteristics when averaging over space and time. Finally, the CO data exploitation is demonstrated for a TROPOMI orbit of simulated shortwave infrared measurements. Overall, the study demonstrates that for an instrument that performs in compliance with the pre-flight specifications, the CO product will meet the required product performance well.

  18. Abundance analysis of Barium stars

    Institute of Scientific and Technical Information of China (English)

    Guo-Qing Liu; Yan-Chun Liang; Li-Cai Deng

    2009-01-01

    We obtain the chemical abundances of six barium stars and two CH subgiant stars based on the high signal-to-noise ratio and high resolution Echelle spectra. The neu- tron capture process elements Y, Zr, Ba, La and Eu show obvious overabundances relative to the Sun, for example, their [Ba/Fe] values are from 0.45 to 1.27. Other elements, in- cluding Na, Mg, A1, Si, Ca, Sc, Ti, V, Cr, Mn and Ni, show comparable abundances to the Solar ones, and their [Fe/H] covers a range from -0.40 to 0.21, which means they belong to the Galactic disk. The predictions of the theoretical model of wind accretion for bi- nary systems can explain the observed abundance patterns of the neutron capture process elements in these stars, which means that their overabundant heavy-elements could be caused by accreting the ejecta of AGB stars, the progenitors of present-day white dwarf companions in binary systems.

  19. Zircon U-Pb Age, Trace Element, and Hf Isotope Evidence for Paleoproterozoic Granulite-Facies Metamorphism and Archean Crustal Remnant in the Dabie Orogen

    Institute of Scientific and Technical Information of China (English)

    Lei Nengzhong; Wu Yuanbao

    2008-01-01

    Zircon U-Pb age, trace elements, and Hf isotopes were determined for granulite and gneiss at Huaugtuling (黄土岭), which is hosted by ultrahigh-pressure metamorphic rocks in the Dabie(大别) orogen, east-central China. Cathodolumineseence (CL) images reveal core-rim structure for most zircons in the granulite. The cores show oscillatory zoning, relatively high Th/U and 176 Lu/177 Hf ratios, and high rare earth element (HREE)-enriched pattern, consistent with magmatic origin. They gave a weighted mean 207 Pb/206 Pb age of (2 766±9) Ma, dating magma emplacement of protolith. The rims are characterized by sector ur planar zoning, low Th/U and 176 Lu/177 Hf ratios, negative Euanomalies and flat HREE patterns, consistent with their formation under granulite-facies metamorphicconditions. Zircon U-Pb dating yields an age of (2 029±13) Ma, which is interpreted as a record ofmetamorphic event during the assembly of the supercontinent Columbia. The gneiss has a protolith ageof (1982±14) Ma, which is similar to the zircon U-Pb age for the granulite-facies metamorphism,suggesting complementary processes to granulite-facies metamorphism and partial melting. A fewinherited cores with igneous characteristics have 207 pb/206 Pb ages of approximately 3.53, 3.24, and 2.90Ga, respectively, suggesting the presence of Mesoarchean to Paleoarchean crustal remnants. A fewTriassic and Cretaceous metamorphic ages were obtained, suggesting the influences by the Triassiccontinental collision and postcollisional collapse in response to the Cretaceous extension. Comparingwith abundant occurrence of Triassic metamorphic zircons in ultrahigh-pressure eclogite and granitehydrous melt is evident for zircon growth in theHuangtuling granulite and gneiss during thecontinental collision. The magmatic protolithzircons from the granulite show a large variationin 176 Hf/177 Hf ratios from 0.280 809 to 0.281 289,corresponding to era(t) values of-7.3 to 6.3 andHf model ages of 2.74 to 3.34 Ga. The 2

  20. Electroosmotic Driving Liquid Using Nanosilica Packed Column

    Institute of Scientific and Technical Information of China (English)

    Ling Xin CHEN; Guo An LUO; Tao WEN

    2005-01-01

    The electroosmotic pump (EOP) using nanosilica particles packed-bed column was experimentally studied. The relationship between flowrate, pressure and applied voltage of the pump, and pressure-flowrate (P-Q) characteristic were investigated.

  1. Early development of the vertebral column.

    Science.gov (United States)

    Scaal, Martin

    2016-01-01

    The segmental organization of the vertebrate body is most obviously visible in the vertebral column, which consists of a series of vertebral bones and interconnecting joints and ligaments. During embryogenesis, the vertebral column derives from the somites, which are the primary segments of the embryonic paraxial mesoderm. Anatomical, cellular and molecular aspects of vertebral column development have been of interest to developmental biologists for more than 150 years. This review briefly summarizes the present knowledge on early steps of vertebral column development in amniotes, starting from sclerotome formation and leading to the establishment of the anatomical bauplan of the spine composed of vertebral bodies, vertebral arches, intervertebral discs and ribs, and their specific axial identities along the body axis.

  2. The magnetic properties of $^{\\rm 177}$Hf and $^{\\rm 180}$Hf in the strong coupling deformed model

    CERN Document Server

    Muto, S; Bingham, C R; Stone, J R; Walker, P M; Audi, G; Gaulard, C; Köster, U; Nikolov, J; Nishimura, K; Ohtsubo, T; Podolyak, Z; Risegari, L; Simpson, G S; Veskovic, M; Walters, W B

    2014-01-01

    This paper reports NMR measurements of the magnetic dipole moments of two high-K isomers, the 37/2$^-$, 51.4 m, 2740 keV state in $^{\\rm 177}$Hf and the 8$^-$, 5.5 h, 1142 keV state in $^{\\rm 180}$Hf by the method of on-line nuclear orientation. Also included are results on the angular distributions of gamma transitions in the decay of the $^{\\rm 177}$Hf isotope. These yield high precision E2/M1 multipole mixing ratios for transitions in bands built on the 23/2$^+$, 1.1 s, isomer at 1315 keV and on the 9/2$^+$, 0.663 ns, isomer at 321 keV. The new results are discussed in the light of the recently reported finding of systematic dependence of the behavior of the g$_{\\rm R}$ parameter upon the quasi-proton and quasi-neutron make up of high-K isomeric states in this region.

  3. An in situ zircon Hf isotopic,U-Pb age and trace element study of banded granulite xenolith from Hannuoba basalt:Tracking the early evolution of the lower crust in the North China craton

    Institute of Scientific and Technical Information of China (English)

    ZHENG Jianping; LU Fengxiang; YU Chunmei; TANG Huayun

    2004-01-01

    Backscattered electron images, in situ Hf isotopes, U-Pb ages and trace elements of zircons in a banded granulite xenolith from Hannuoba basalt have been studied. The results show that the banded granulite is a sample derived from the early lower crust of the North China craton. It is difficult to explain the petrogenesis of the xenolith with a single process. Abundant information on several processes, however, is contained in the granulite. These processes include the addition of mantle material, crustal remelting, metamorphic differentiation and the delamination of early lower crust. About 80% of zircons studied yield ages of 1842±40 Ma, except few ages of 3097-2824 Ma and 2489-2447 Ma. The zircons with ages older than 2447 Ma have high εHf (up to +18.3) and high Hf model age (2.5-2.6 Ga), indicating that the primitive materials of the granulite were derived mainly from a depleted mantle source in late Archean. Most εHf of the zircons with early Proterozoic U-Pb age vary around zero, but two have high εHf up to +9.2-+10.2, indicating mantle contribution during the collision and assembly between the Eastern and Western blocks in the early Proterozoic that resulted in the amalgamation of the North China craton.

  4. Modeling Tropical Precipitation in a Single Column.

    Science.gov (United States)

    Sobel, Adam H.; Bretherton, Christopher S.

    2000-12-01

    A modified formulation of the traditional single column model for representing a limited area near the equator is proposed. This formulation can also be considered a two-column model in the limit as the area represented by one of the columns becomes very large compared to the other. Only a single column is explicitly modeled, but its free tropospheric temperature, rather than its mean vertical velocity, is prescribed. This allows the precipitation and vertical velocity to be true prognostic variables, as in prior analytical theories of tropical precipitation. Two models developed by other authors are modified according to the proposed formulation. The first is the intermediate atmospheric model of J. D. Neelin and N. Zeng, but with the horizontal connections between columns broken, rendering it a set of disconnected column models. The second is the column model of N. O. Rennó, K. A. Emanuel, and P. H. Stone. In the first model, the set of disconnected column models is run with a fixed temperature that is uniform in the Tropics, and insolation, SST, and surface wind speed taken from a control run of the original model. The column models produce a climatological precipitation field that is grossly similar to that of the control run, despite that the circulation implied by the column models is not required to conserve mass. The addition of horizontal moisture advection by the wind from the control run substantially improves the simulation in dry regions. In the second model the sensitivity of the modeled steady-state precipitation and relative humidity to varying SST and wind speed is examined. The transition from shallow to deep convection is simulated in a `Lagrangian' calculation in which the column model is subjected to an SST that increases in time. In this simulation, the onset of deep convection is delayed to a higher SST than in the steady-state case, due to the effect of horizontal moisture advection (viewed in a Lagrangian reference frame). In both of the

  5. Temporal and Spatial Distribution of the Microbial Community of Winogradsky Columns.

    Directory of Open Access Journals (Sweden)

    David J Esteban

    Full Text Available Winogradsky columns are model microbial ecosystems prepared by adding pond sediment to a clear cylinder with additional supplements and incubated with light. Environmental gradients develop within the column creating diverse niches that allow enrichment of specific bacteria. The enrichment culture can be used to study soil and sediment microbial community structure and function. In this study we used a 16S rRNA gene survey to characterize the microbial community dynamics during Winogradsky column development to determine the rate and extent of change from the source sediment community. Over a period of 60 days, the microbial community changed from the founding pond sediment population: Cyanobacteria, Chloroflexi, Nitrospirae, and Planctomycetes increased in relative abundance over time, while most Proteobacteria decreased in relative abundance. A unique, light-dependent surface biofilm community formed by 60 days that was less diverse and dominated by a few highly abundant bacteria. 67-72% of the surface community was comprised of highly enriched taxa that were rare in the source pond sediment, including the Cyanobacteria Anabaena, a member of the Gemmatimonadetes phylum, and a member of the Chloroflexi class Anaerolinea. This indicates that rare taxa can become abundant under appropriate environmental conditions and supports the hypothesis that rare taxa serve as a microbial seed bank. We also present preliminary findings that suggest that bacteriophages may be active in the Winogradsky community. The dynamics of certain taxa, most notably the Cyanobacteria, showed a bloom-and-decline pattern, consistent with bacteriophage predation as predicted in the kill-the-winner hypothesis. Time-lapse photography also supported the possibility of bacteriophage activity, revealing a pattern of colony clearance similar to formation of viral plaques. The Winogradsky column, a technique developed early in the history of microbial ecology to enrich soil

  6. Temporal and Spatial Distribution of the Microbial Community of Winogradsky Columns.

    Science.gov (United States)

    Esteban, David J; Hysa, Bledi; Bartow-McKenney, Casey

    2015-01-01

    Winogradsky columns are model microbial ecosystems prepared by adding pond sediment to a clear cylinder with additional supplements and incubated with light. Environmental gradients develop within the column creating diverse niches that allow enrichment of specific bacteria. The enrichment culture can be used to study soil and sediment microbial community structure and function. In this study we used a 16S rRNA gene survey to characterize the microbial community dynamics during Winogradsky column development to determine the rate and extent of change from the source sediment community. Over a period of 60 days, the microbial community changed from the founding pond sediment population: Cyanobacteria, Chloroflexi, Nitrospirae, and Planctomycetes increased in relative abundance over time, while most Proteobacteria decreased in relative abundance. A unique, light-dependent surface biofilm community formed by 60 days that was less diverse and dominated by a few highly abundant bacteria. 67-72% of the surface community was comprised of highly enriched taxa that were rare in the source pond sediment, including the Cyanobacteria Anabaena, a member of the Gemmatimonadetes phylum, and a member of the Chloroflexi class Anaerolinea. This indicates that rare taxa can become abundant under appropriate environmental conditions and supports the hypothesis that rare taxa serve as a microbial seed bank. We also present preliminary findings that suggest that bacteriophages may be active in the Winogradsky community. The dynamics of certain taxa, most notably the Cyanobacteria, showed a bloom-and-decline pattern, consistent with bacteriophage predation as predicted in the kill-the-winner hypothesis. Time-lapse photography also supported the possibility of bacteriophage activity, revealing a pattern of colony clearance similar to formation of viral plaques. The Winogradsky column, a technique developed early in the history of microbial ecology to enrich soil microbes, may therefore be

  7. Nonlinear control of high purity distillation columns

    OpenAIRE

    Groebel, Markus; Allgöwer, Frank; Storz, Markus; Gilles, Ernst Dieter

    1994-01-01

    Two simple models of distillation columns are studied to investigate their suitability for the practical use with exact I/O-linearization. An extension of exact I/O-linearization, the asymptotically exact I/O-linearization is applied to the control of a high purity distillation column, using one of these models to derive the static state feedback law. Simulation studies demonstrate the advantage of asymptotically exact I/O-linearization versus classical exact I/O-linearization techniques. Exp...

  8. The Dissipative Column: A New Hysteretic Damper

    OpenAIRE

    Bruno Palazzo; Paolo Castaldo; Ivana Marino

    2015-01-01

    A new replaceable hysteretic damper to better control seismic building damage, consisting of two or more adjacent steel vertical elements connected to each other with continuous mild/low strength steel shear links, is proposed and investigated in this paper. New Dampers, called Dissipative Columns (DC), continuously linked with X-shaped steel plates, provide additional stiffness and damping to a lateral system by using a basic and minimally invasive construction element: the column. Working i...

  9. Fuzzy Based composition Control of Distillation Column

    Directory of Open Access Journals (Sweden)

    Guru.R

    2013-04-01

    Full Text Available This paper proposed a control scheme based on fuzzy logic for a methanol - water system of bubble cap distillation column. Fuzzy rule base and Inference System of fuzzy (FIS is planned to regulatethe reflux ratio (manipulated variable to obtain the preferred product composition (methanol for a distillation column. Comparisons are made with conventional controller and the results confirmed the potentials of the proposed strategy of fuzzy control.

  10. The handedness of historiated spiral columns.

    Science.gov (United States)

    Couzin, Robert

    2016-11-17

    Trajan's Column in Rome (AD 113) was the model for a modest number of other spiral columns decorated with figural, narrative imagery from antiquity to the present day. Most of these wind upwards to the right, often with a congruent spiral staircase within. A brief introductory consideration of antique screw direction in mechanical devices and fluted columns suggests that the former may have been affected by the handedness of designers and the latter by a preference for symmetry. However, for the historiated columns that are the main focus of this article, the determining factor was likely script direction. The manner in which this operated is considered, as well as competing mechanisms that might explain exceptions. A related phenomenon is the reversal of the spiral in a non-trivial number of reproductions of the antique columns, from Roman coinage to Renaissance and baroque drawings and engravings. Finally, the consistent inattention in academic literature to the spiral direction of historiated columns and the repeated publication of erroneous earlier reproductions warrants further consideration.

  11. Gas Chromatograph Method Optimization Trade Study for RESOLVE: 20-meter Column v. 8-meter Column

    Science.gov (United States)

    Huz, Kateryna

    2014-01-01

    RESOLVE is the payload on a Class D mission, Resource Prospector, which will prospect for water and other volatile resources at a lunar pole. The RESOLVE payload's primary scientific purpose includes determining the presence of water on the moon in the lunar regolith. In order to detect the water, a gas chromatograph (GC) will be used in conjunction with a mass spectrometer (MS). The goal of the experiment was to compare two GC column lengths and recommend which would be best for RESOLVE's purposes. Throughout the experiment, an Inficon Fusion GC and an Inficon Micro GC 3000 were used. The Fusion had a 20m long column with 0.25mm internal diameter (Id). The Micro GC 3000 had an 8m long column with a 0.32mm Id. By varying the column temperature and column pressure while holding all other parameters constant, the ideal conditions for testing with each column length in their individual instrument configurations were determined. The criteria used for determining the optimal method parameters included (in no particular order) (1) quickest run time, (2) peak sharpness, and (3) peak separation. After testing numerous combinations of temperature and pressure, the parameters for each column length that resulted in the most optimal data given my three criteria were selected. The ideal temperature and pressure for the 20m column were 95 C and 50psig. At this temperature and pressure, the peaks were separated and the retention times were shorter compared to other combinations. The Inficon Micro GC 3000 operated better at lower temperature mainly due to the shorter 8m column. The optimal column temperature and pressure were 70 C and 30psig. The Inficon Micro GC 3000 8m column had worse separation than the Inficon Fusion 20m column, but was able to separate water within a shorter run time. Therefore, the most significant tradeoff between the two column lengths was peak separation of the sample versus run time. After performing several tests, it was concluded that better

  12. Polarity reversion of the operation mode of HfO2-based resistive random access memory devices by inserting Hf metal layer.

    Science.gov (United States)

    Peng, Ching-Shiang; Chang, Wen-Yuan; Lin, Ming-Ho; Chen, Wei-Su; Chen, Frederick; Tsai, Ming-Jinn

    2013-03-01

    The reversion of polarity within bipolar resistive switching operation occurs in Pt/HfO2/TiN and Pt/Hf/HfO2/TiN resistive random access memory devices. This reversion of voltage polarity is the result of interface generation which induces a conduction mechanism transformation from Poole-Frenkel emission to space charge limited current mechanism. To prove the reversion of polarity, this study uses curve fitting of I-V relations to verify the conduction mechanism theoretically and physical analysis to verify the oxygen ion distribution practically. The proposed Pt/Hf/HfO2/TiN devices exhibit good resistive switching characteristics, such as good uniformity, low voltage operation, robust endurance (10(3) dc sweep), and long retention (3 x 10(4) s at 85 degrees C).

  13. Vertically oriented few-layered HfS2 nanosheets: growth mechanism and optical properties

    Science.gov (United States)

    Zheng, Binjie; Chen, Yuanfu; Wang, Zegao; Qi, Fei; Huang, Zhishuo; Hao, Xin; Li, Pingjian; Zhang, Wanli; Li, Yanrong

    2016-09-01

    For the first time, large-area, vertically oriented few-layered hafnium disulfide (V-{{{HfS}}}2) nanosheets have been grown by chemical vapor deposition. The individual {{{HfS}}}2 nanosheets are well [001] oriented, with highly crystalline quality. Far different from conventional van der Waals epitaxial growth mechanism for two-dimensional transition metal dichalcogenides, a novel dangling-bond-assisted self-seeding growth mechanism is proposed to describe the growth of V-{{{HfS}}}2 nanosheets: difficult migration of {{{HfS}}}2 adatoms on substrate surface results in {{{HfS}}}2 seeds growing perpendicularly to the substrate; V-{{{HfS}}}2 nanosheets inherit the growth direction of {{{HfS}}}2 seeds; V-{{{HfS}}}2 nanosheets further expand in the in-plane direction with time evolution. Moreover, the V-{{{HfS}}}2 nanosheets show strong and broadened photons absorption from near infrared to ultraviolet; the V-{{{HfS}}}2-based photodetector exhibits an ultrafast photoresponse time of 24 ms, and a high photosensitivity ca. 103 for 405 nm laser.

  14. Empirical Study of the Multiaxial, Thermomechanical Behavior of NiTiHf Shape Memory Alloys

    Science.gov (United States)

    Shukla, Dhwanil; Noebe, Ronald D.; Stebner Aaron P.

    2013-01-01

    An empirical study was conducted to characterize the multiaxial, thermomechanical responses of new high temperature NiTiHf alloys. The experimentation included loading thin walled tube Ni(sub 50.3)Ti(sub 29.7)Hf(sub 20) alloy samples along both proportional and nonproportional axial-torsion paths at different temperatures while measuring surface strains using stereo digital image correlation. A Ni(sub 50.3)Ti(sub 33.7)Hf(sub 16) alloy was also studied in tension and compression to document the effect of slightly depleting the Hf content on the constitutive responses of NiTiHf alloys. Samples of both alloys were made from nearly texture free polycrystalline material processed by hot extrusion. Analysis of the data shows that very small changes in composition significantly alter NiTiHf alloy properties, as the austenite finish (Af) temperature of the 16-at Hf alloy was found to be approximately 60 C less than the 20-at Hf alloy (approximately 120 C vs. 180 C). In addition, the 16-at Hf alloy exhibited smaller compressive transformation strains (2 vs. 2.5 percent). Multi-axial characterization of the 20-at % Hf alloy showed that while the random polycrystal transformation strains in tension (4 percent) and compression (2.5 percent) are modest in comparison with binary NiTi (6 percent, 4 percent), the torsion performance is superior (7 vs. 4 shear strain width to the pseudoelastic plateau).

  15. Studies and research concerning BNFP pilot-scale pulsed columns: column profile and holdup studies

    Energy Technology Data Exchange (ETDEWEB)

    Cermak, A. F.

    1980-11-01

    Experimental studies were conducted on pilot-scaled pulsed columns for the purpose of obtaining data for verification of contactor computer programs. This work is in support of safeguards programs related to determination of near real-time inventories in pulsed columns. Holdup tests were performed resulting in the derivation of an empirical equation for estimation of the dispersed phase holdup in a column. Uranium solvent extraction mass-transfer tests were conducted in which all four process cycles were simulated under coprocessing flowsheet conditions. Extensive data were obtained during these tests on uranium profiles and inventories within the columns. Transient profile data were also determined between selected runs under the tested operating conditions. No concentration peaks could be observed during the transient period. Based on the extensive inventory data taken, empirical equations were developed for relating uranium inventory in a column to the test parameters. These equations were found useful for predicting and estimating the column inventory under the known run conditions.

  16. Effects of HfB2 and HfN Additions on the Microstructures and Mechanical Properties of TiB2-Based Ceramic Tool Materials

    Directory of Open Access Journals (Sweden)

    Jing An

    2017-04-01

    Full Text Available The effects of HfB2 and HfN additions on the microstructures and mechanical properties of TiB2-based ceramic tool materials were investigated. The results showed that the HfB2 additive not only can inhibit the TiB2 grain growth but can also change the morphology of some TiB2 grains from bigger polygons to smaller polygons or longer ovals that are advantageous for forming a relatively fine microstructure, and that the HfN additive had a tendency toward agglomeration. The improvement of flexural strength and Vickers hardness of the TiB2-HfB2 ceramics was due to the relatively fine microstructure; the decrease of fracture toughness was ascribed to the formation of a weaker grain boundary strength due to the brittle rim phase and the poor wettability between HfB2 and Ni. The decrease of the flexural strength and Vickers hardness of the TiB2-HfN ceramics was due to the increase of defects such as TiB2 coarse grains and HfN agglomeration; the enhancement of fracture toughness was mainly attributed to the decrease of the pore number and the increase of the rim phase and TiB2 coarse grains. The toughening mechanisms of TiB2-HfB2 ceramics mainly included crack bridging and transgranular fracture, while the toughening mechanisms of TiB2-HfN ceramics mainly included crack deflection, crack bridging, transgranular fracture, and the core-rim structure.

  17. Crystallography of the NiHfSi Phase in a NiAl (0.5 Hf) Single-Crystal Alloy

    Science.gov (United States)

    Garg, A.; Noebe, R. D.; Darolia, R.

    1996-01-01

    Small additions of Hf to conventionally processed NiAl single crystals result in the precipitation of a high density of cuboidal G-phase along with a newly identified silicide phase. Both of these phases form in the presence of Si which is not an intentional alloying addition but is a contaminant resulting from contact with the ceramic shell molds during directional solidification of the single-crystal ingots. The morphology, crystal structure and Orientation Relationship (OR) of the silicide phase in a NiAl (0.5 at.%Hf) single-crystal alloy have been determined using transmission electron microscopy, electron microdiffraction and energy dispersive X-ray spectroscopy. Qualitative elemental analysis and indexing of the electron microdiffraction patterns from the new phase indicate that it is an orthorhombic NiHfSi phase with unit cell parameters, a = 0.639 nm, b = 0.389 nm and c = 0.72 nm, and space group Pnma. The NiHfSi phase forms as thin rectangular plates on NiAl/111/ planes with an OR that is given by NiHfSi(100))(parallel) NiAl(111) and NiHfSi zone axes(010) (parallel) NiAl zone axes (101). Twelve variants of the NiHfSi phase were observed in the alloy and the number of variants and rectangular morphology of NiHfSi plates are consistent with symmetry requirements. Quenching experiments indicate that nucleation of the NiHfSi phase in NiAI(Hf) alloys is aided by the formation of NiAl group of zone axes (111) vacancy loops that form on the NiAl /111/ planes.

  18. An ab initio study of the C2H2-HF, C2H(CH3)-HF and C2(CH3)2-HF hydrogen-bonded complexes.

    Science.gov (United States)

    Ramos, Mozart N; Lopes, Kelson C; Silva, Washington L V; Tavares, Alessandra M; Castriani, Fátima A; do Monte, Silmar A; Ventura, Elizete; Araújo, Regiane C M U

    2006-02-01

    MP2/6-31++G** and B3LYP/6-31++G** ab initio molecular orbital calculations have been performed in order to obtain molecular geometries, binding energies and vibrational properties of the C2H2-HF, C2H(CH3)-HF and C2(CH3)2-HF H-bonded complexes. As expected, the more pronounced effects on the structural properties of the isolated molecules due to complexation was verified for the C[triple bond]C and H-F bond lengths, which are directly involved in the H-bond formation. These bond distances increased after complexation. BSSE uncorrected B3LYP binding energies are always lower than the corresponding MP2 values. However, the opposite trend has been verified after BSSE correction by the counterpoise method since it is much lower at B3LYP than at MP2 level. The binding energies for these complexes as well as for the HF acid submolecule modes (the HF stretching and vibrational frequency modes) showed an increasing hydrogen-bonding strength with increasing methyl substitution. The splitting in the HF in-plane and out-of-plane bending modes reflects the anisotropy in the hydrogen-bonding interaction with the pi system of the C[triple bond]C bond. The H-F stretching frequency is shifted downward after complexation and it increases with the methyl substitution. The IR intensities of the HF acid submolecule fundamentals are adequately interpreted through the atomic polar tensor of the hydrogen atom using the charge-charge flux-overlap model. The skeletal stretching modes of the Alkyne submolecule are decreased in the complex. The new vibrational modes arising from complexation show several interesting features.

  19. Structural Decoupling and Disturbance Rejection in a Distillation Column

    DEFF Research Database (Denmark)

    Bahar, Mehrdad; Jantzen, Jan; Commault, C.

    1996-01-01

    Introduction, distillation column model, input-output decoupling, disturbance rejection, concluding remarks, references.......Introduction, distillation column model, input-output decoupling, disturbance rejection, concluding remarks, references....

  20. Column Selection for Biomedical Analysis Supported by Column Classification Based on Four Test Parameters.

    Science.gov (United States)

    Plenis, Alina; Rekowska, Natalia; Bączek, Tomasz

    2016-01-21

    This article focuses on correlating the column classification obtained from the method created at the Katholieke Universiteit Leuven (KUL), with the chromatographic resolution attained in biomedical separation. In the KUL system, each column is described with four parameters, which enables estimation of the FKUL value characterising similarity of those parameters to the selected reference stationary phase. Thus, a ranking list based on the FKUL value can be calculated for the chosen reference column, then correlated with the results of the column performance test. In this study, the column performance test was based on analysis of moclobemide and its two metabolites in human plasma by liquid chromatography (LC), using 18 columns. The comparative study was performed using traditional correlation of the FKUL values with the retention parameters of the analytes describing the column performance test. In order to deepen the comparative assessment of both data sets, factor analysis (FA) was also used. The obtained results indicated that the stationary phase classes, closely related according to the KUL method, yielded comparable separation for the target substances. Therefore, the column ranking system based on the FKUL-values could be considered supportive in the choice of the appropriate column for biomedical analysis.

  1. Column flotation of bitumen at Fort Hills

    Energy Technology Data Exchange (ETDEWEB)

    Lizama, H.M. [Teck Cominco, Vancouver, BC (Canada); Romero, D. [UTS Energy Corp., Calgary, AB (Canada); Armour, M. [Petro-Canada, Calgary, AB (Canada)

    2008-05-15

    Flotation columns are used by mineral processors to separate mineral species. The separation is based on the premise that different mineral particles have different surface hydrophobicities. There are 2 carrier phases, notably air bubbles moving up and aqueous pulp moving down. Hydrophobic particles predominantly adhere to rising air bubbles and form a froth, while hydrophilic particles remain in aqueous suspension and flow down and out the bottom of the column. This paper described a demonstration plant near Fort McMurray where bitumen extraction was tested. The plant included 2 columns for bitumen flotation. Oil sands material was passed through a roll sizer and fed to a countercurrent drum separator, where it was mixed with water at 75 degrees C. Column data from the demonstration plant provided the opportunity to examine the separation behaviour during flotation of bitumen. The bitumen grade was described only in terms of bitumen content and solids content in order to simplify the interpretation of the bitumen flotation data. Bitumen/solids separation in the first column was successful at 50 to 60 degrees C, with feeds having bitumen grades between 1 and 19 per cent, and where the solids had about 60 per cent fines. Bitumen/solids separation did not occur in the second column at 50 to 60 degrees C, with feeds having bitumen grades between 8 and 63 per cent, and where the solids had about 90 per cent fines. The lack of separation was probably due to high solids entrainment in the flotation froth. It was concluded that bitumen column flotation data can be analyzed and interpreted by adopting mineral processing principles. Bitumen/solids separation can be evaluated and predicted by plotting solids recovery as a function of bitumen recovery. 7 refs., 1 tab., 6 figs.

  2. Coalescence of silver clusters by immersion in diluted HF solution

    Energy Technology Data Exchange (ETDEWEB)

    Milazzo, R. G.; Mio, A. M.; D’Arrigo, G.; Spinella, C. [CNR-IMM Institute for Microelectronics and Microsystems, I-95121 Catania (Italy); Grimaldi, M. G. [Department of Physics and Astronomy, Università di Catania, I-95123 Catania (Italy); MATIS IMM-CNR, I-95123 Catania (Italy); Rimini, E. [CNR-IMM Institute for Microelectronics and Microsystems, I-95121 Catania (Italy); Department of Physics and Astronomy, Università di Catania, I-95123 Catania (Italy)

    2015-07-14

    The galvanic displacement deposition of silver on H-terminated Si (100) in the time scale of seconds is instantaneous and characterized by a cluster density of 10{sup 11}-10{sup 12} cm{sup −2}. The amount of deposited Ag follows a t{sup 1/2} dependence in agreement with a Cottrell diffusion limited mechanism. At the same time, during the deposition, the cluster density reduces by a factor 5. This behavior is in contrast with the assumption of immobile clusters. We show in the present work that coalescence and aggregation occur also in the samples immersed in the diluted hydrofluoric acid (HF) solution without the presence of Ag{sup +}. Clusters agglomerate according to a process of dynamic coalescence, typical of colloids, followed by atomic redistribution at the contact regions with the generation of multiple internal twins and stacking-faults. The normalized size distributions in terms of r/r{sub mean} follow also the prediction of the Smoluchowski ripening mechanism. No variation of the cluster density occurs for samples immersed in pure H{sub 2}O solution. The different behavior might be associated to the strong attraction of clusters to oxide-terminated Si surface in presence of water. The silver clusters are instead weakly bound to hydrophobic H-terminated Si in presence of HF. HF causes then the detachment of clusters and a random movement on the silicon surface with mobility of about 10{sup −13} cm{sup 2}/s. Attractive interaction (probably van der Waals) among particles promotes coarsening.

  3. Lead abundance in the uranium star CS 31082-001

    DEFF Research Database (Denmark)

    Plez, B.; Hill, V.; Cayrel, R.

    2004-01-01

    stars:abundances- physical data and processes: nuclear reactions, nucleosynthesis, abundances- atomic data......stars:abundances- physical data and processes: nuclear reactions, nucleosynthesis, abundances- atomic data...

  4. Synthesis and photoluminescence property of silicon carbide nanowires thin film by HF-PECVD system

    Indian Academy of Sciences (India)

    Zhang Enlei; Wang Guosheng; Long Xiaozhu; Wang Zhumin

    2014-10-01

    A sample and scalable synthetic strategy was developed for the fabrication of nanocrystalline SiC (nc-SiC) thin film. Thin sheet of nanocrystalline diamond was deposited on Si substrate by hot filamentassisted plasma-enhanced chemical vapour deposition system (HF-PECVD). Further, the resulting carbonbased sheet was heated at 1200 °C to allow a solid state reaction between C and Si substrate to form the SiC thin films. The synthesized films mainly consist of -SiC nanowires with diameters of about 50 nm and tens of micrometers long. The nanowires axes lie along the [1 1 1] direction and possess a high density of planar defects. The -SiC nanowires thin films exhibit the strong photoluminescence (PL) peak at a wavelength of 400 nm, which is significantly shifted to the blue compared with the reported PL results of SiC materials. The blue shift may be ascribed to morphology, quantum size confinement effects of the nanomaterials and abundant structure defects that existed in the nanowires.

  5. Strong photoluminescence of the porous silicon with HfO2-filled microcavities

    Science.gov (United States)

    Jiang, Ran; Wu, Zhengran; Du, Xianghao; Han, Zuyin; Sun, Weideng

    2015-06-01

    Greatly enhanced blue emission was observed at room temperature in the single-crystal silicon with HfO2 filled into its microcavities. The broad blue band light was emitted from both the HfO2 dielectric and the porous Si. The ferroelectricity of HfO2 enhances the blue emission from Si by its filling into the microcaivities. At the same time, HfO2 contributes to the light emission for the transitions of the defect levels for oxygen vacancy. The observation of greatly enhanced blue light emission of the porous Si filled with HfO2 dielectric is remarkable as both HfO2 and Si are highly compatible with Si-based electronic industry.

  6. Ozone Treatment Improved the Resistive Switching Uniformity of HfAlO2 Based RRAM Devices

    Directory of Open Access Journals (Sweden)

    Lifeng Liu

    2015-01-01

    Full Text Available HfAlO2 based resistive random access memory (RRAM devices were fabricated using atomic layer deposition by modulating deposition cycles for HfO2 and Al2O3. Effect of ozone treatment on the resistive switching uniformity of HfAlO2 based RRAM devices was investigated. Compared to the as-fabricated devices, the resistive switching uniformity of HfAlO2 based RRAM devices with the ozone treatment is significantly improved. The uniformity improvement of HfAlO2 based RRAM devices is related to changes in compositional and structural properties of the HfAlO2 resistive switching film with the ozone treatment.

  7. Medium-Range Order Structure and Fragility of Superheated Melts of Amorphous CuHf Alloys

    Institute of Scientific and Technical Information of China (English)

    BIAN Xiu-Fang; SUN Bao-An; HU Li-Na

    2006-01-01

    @@ The structural factors of amorphous CuHf alloys at different temperatures are determined by using a high temperature x-ray diffractometer. It is found that not only the short-range order structure but also the medium-range order structure exists in amorphous CuHf alloys. The dynamic viscosities of CuHf alloy melts are measured by a torsional oscillation viscometer. The fragility of superheated melts of CuHf alloys is calculated based on the viscosity data. The experimental results show that the glass-forming ability of the CuHf alloys is closely related to the fragility of their superheated melt. The relationship between the medium-range order structures and the fragility of superheated melts has also been established in amorphous CuHf alloys. In contrast to the fragility of supercooled liquids, the fragility of superheated liquids promises a better approach to reflecting the dynamics of glass forming liquids.

  8. Ionosphere research with a HF/MF cubesat radio instrument

    Science.gov (United States)

    Kallio, Esa; Aikio, Anita; Alho, Markku; Fontell, Mathias; Harri, Ari-Matti; Kauristie, Kirsti; Kestilä, Antti; Koskimaa, Petri; Mäkelä, Jakke; Mäkelä, Miika; Turunen, Esa; Vanhamäki, Heikki; Verronen, Pekka

    2017-04-01

    New technology provides new possibilities to study geospace and 3D ionosphere by using spacecraft and computer simulations. A type of nanosatellites, CubeSats, provide a cost effective possibility to provide in-situ measurements in the ionosphere. Moreover, combined CubeSat observations with ground-based observations gives a new view on auroras and associated electromagnetic phenomena. Especially joint and active CubeSat - ground based observation campaigns enable the possibility of studying the 3D structure of the ionosphere. Furthermore using several CubeSats to form satellite constellations enables much higher temporal resolution. At the same time, increasing computation capacity has made it possible to perform simulations where properties of the ionosphere, such as propagation of the electromagnetic waves in the medium frequency, MF (0.3-3 MHz) and high frequency, HF (3-30 MHz), ranges is based on a 3D ionospheric model and on first-principles modelling. Electromagnetic waves at those frequencies are strongly affected by ionospheric electrons and, consequently, those frequencies can be used for studying the plasma. On the other hand, even if the ionosphere originally enables long-range telecommunication at MF and HF frequencies, the frequent occurrence of spatiotemporal variations in the ionosphere disturbs communication channels, especially at high latitudes. Therefore, study of the MF and HF waves in the ionosphere has both a strong science and technology interests. We introduce recently developed simulation models as well as measuring principles and techniques to investigate the arctic ionosphere by a polar orbiting CubeSat whose novel AM radio instrument measures HF and MF waves. The cubesat, which contains also a white light aurora camera, is planned to be launched in late 2017 (http://www.suomi100satelliitti.fi/eng). The new models are (1) a 3D ray tracing model and (2) a 3D full kinetic electromagnetic simulation. We also introduce how combining of the

  9. HF beacon network for ionospheric specification in Peru

    Science.gov (United States)

    Hysell, D. L.; Milla, M. A.; Vierinen, J.

    2016-12-01

    A growing network of HF beacon transmitters and receivers is being deployed in Peru for specifying the F region ionosphere regionally. The effort is motivated by ionospheric disturbances associated with equatorial spread F (ESF), especially disturbances arising under inauspicious ESF conditions. The beacons use dual frequencies (2.72 and 3.64 MHz). They incorporate PRN coding to afford group-delay measurements. Scatered power, Doppler shift, bearing, and polarization are also measured. An algorithm for inverting the beacon data combined with electron density profiles from Jicamarca is described. Data and representative solutions from recent campaigns will be reviewed.

  10. A SYNCHRONIZATION ALGORITHM FOR HF (HIGH FREQUENCY) BROADBAND OFDM SYSTEM

    Institute of Scientific and Technical Information of China (English)

    Yang Lei; Zhang You'ai

    2008-01-01

    In this letter, a kind of associated synchronization algorithm which is suitable for HF (High Frequency) broadband OFDM (Orthogonal Frequency Division Multiplexing) system is presented based on describing and constructing the GMW (Gorden, Mills and Welch) sequence. The algorithm is based on the Schmidl and Minn's symbol timing principle, the constructed GMW sequence is transmitted and disposed, and the synchronization is adjudicated using the correlation of GMW sequence. The simulation result indicates that this algorithm has high performance synchronization ability under the low SNR (Signal to Noise Ratio) at two different kinds of channel models.

  11. Surface abundances of ON stars

    CERN Document Server

    Martins, F; Palacios, A; Howarth, I; Georgy, C; Walborn, N R; Bouret, J -C; Barba, R

    2015-01-01

    Massive stars burn hydrogen through the CNO cycle during most of their evolution. When mixing is efficient, or when mass transfer in binary systems happens, chemically processed material is observed at the surface of O and B stars. ON stars show stronger lines of nitrogen than morphologically normal counterparts. Whether this corresponds to the presence of material processed through the CNO cycle or not is not known. Our goal is to answer this question. We perform a spectroscopic analysis of a sample of ON stars with atmosphere models. We determine the fundamental parameters as well as the He, C, N, and O surface abundances. We also measure the projected rotational velocities. We compare the properties of the ON stars to those of normal O stars. We show that ON stars are usually helium-rich. Their CNO surface abundances are fully consistent with predictions of nucleosynthesis. ON stars are more chemically evolved and rotate - on average - faster than normal O stars. Evolutionary models including rotation cann...

  12. Post Column Derivatization Using Reaction Flow High Performance Liquid Chromatography Columns.

    Science.gov (United States)

    Jones, Andrew; Pravadali-Cekic, Sercan; Hua, Stanley; Kocic, Danijela; Camenzuli, Michelle; Dennis, Gary; Shalliker, Andrew

    2016-04-26

    A protocol for the use of reaction flow high performance liquid chromatography columns for methods employing post column derivatization (PCD) is presented. A major difficulty in adapting PCD to modern HPLC systems and columns is the need for large volume reaction coils that enable reagent mixing and then the derivatization reaction to take place. This large post column dead volume leads to band broadening, which results in a loss of observed separation efficiency and indeed detection in sensitivity. In reaction flow post column derivatization (RF-PCD) the derivatization reagent(s) are pumped against the flow of mobile phase into either one or two of the outer ports of the reaction flow column where it is mixed with column effluent inside a frit housed within the column end fitting. This technique allows for more efficient mixing of the column effluent and derivatization reagent(s) meaning that the volume of the reaction loops can be minimized or even eliminated altogether. It has been found that RF-PCD methods perform better than conventional PCD methods in terms of observed separation efficiency and signal to noise ratio. A further advantage of RF-PCD techniques is the ability to monitor effluent coming from the central port in its underivatized state. RF-PCD has currently been trialed on a relatively small range of post column reactions, however, there is currently no reason to suggest that RF-PCD could not be adapted to any existing one or two component (as long as both reagents are added at the same time) post column derivatization reaction.

  13. [A simple preparation method of an electric heating apparatus for heating capillary chromatographic columns and its application in liquid chromatography-mass spectrometry system].

    Science.gov (United States)

    Jin, Zuyao; Lü, Yayao; Zhou, Shanshan; Hao, Feiran; Fu, Bin; Ying, Wantao; Qian, Xiaohong; Zhang, Yangjun

    2015-06-01

    For deep coverage of proteome, especially in performing qualitative identification and quantitative analysis of low-abundance proteins, the most commonly used method is the application of a longer capillary chromatographic column or a capillary column packed with smaller particle sizes. However, this causes another problem, the very high back pressure which results in liquid leaks in some connection parts in a liquid chromatograph. To solve this problem, an electric heating apparatus was developed to raise the temperature of a capillary column for reducing its back pressure, which was further applied in a capillary high performance liquid chromatography-tandem mass spectrometry system (cHPLC-MS/MS), and evaluated in the terms of chromatographic column back pressure and chromatographic column efficiency using bovine serum albumin (BSA) tryptic digests and yeast tryptic digests, separately. The results showed that at the optimum current, our electric heating apparatus could reduce the column pressure of a capillary column packed with 3 µm packing materials by at least 50% during the separation of BSA tryptic digestion and yeast tryptic digestion, compared with that without electric heating. The column efficiency was also increased slightly. This suggested that the electric heating apparatus can significantly reduce the column pressure, which provides an efficient way to use capillary chromatographic columns packed with smaller sizes of particles at a lower pressure.

  14. Meteorite zircon constraints on the bulk Lu-Hf isotope composition and early differentiation of the Earth.

    Science.gov (United States)

    Iizuka, Tsuyoshi; Yamaguchi, Takao; Hibiya, Yuki; Amelin, Yuri

    2015-04-28

    Knowledge of planetary differentiation is crucial for understanding the chemical and thermal evolution of terrestrial planets. The (176)Lu-(176)Hf radioactive decay system has been widely used to constrain the timescales and mechanisms of silicate differentiation on Earth, but the data interpretation requires accurate estimation of Hf isotope evolution of the bulk Earth. Because both Lu and Hf are refractory lithophile elements, the isotope evolution can be potentially extrapolated from the present-day (176)Hf/(177)Hf and (176)Lu/(177)Hf in undifferentiated chondrite meteorites. However, these ratios in chondrites are highly variable due to the metamorphic redistribution of Lu and Hf, making it difficult to ascertain the correct reference values for the bulk Earth. In addition, it has been proposed that chondrites contain excess (176)Hf due to the accelerated decay of (176)Lu resulting from photoexcitation to a short-lived isomer. If so, the paradigm of a chondritic Earth would be invalid for the Lu-Hf system. Herein we report the first, to our knowledge, high-precision Lu-Hf isotope analysis of meteorite crystalline zircon, a mineral that is resistant to metamorphism and has low Lu/Hf. We use the meteorite zircon data to define the Solar System initial (176)Hf/(177)Hf (0.279781 ± 0.000018) and further to identify pristine chondrites that contain no excess (176)Hf and accurately represent the Lu-Hf system of the bulk Earth ((176)Hf/(177)Hf = 0.282793 ± 0.000011; (176)Lu/(177)Hf = 0.0338 ± 0.0001). Our results provide firm evidence that the most primitive Hf in terrestrial zircon reflects the development of a chemically enriched silicate reservoir on Earth as far back as 4.5 billion years ago.

  15. Thermodynamic modeling of the Co–Hf system supported by key experiments and first-principles calculations

    Energy Technology Data Exchange (ETDEWEB)

    Lu, Xingxu [School of Materials Science and Engineering, Central South University, Changsha, Hunan 410083 (China); State Key Laboratory of Powder Metallurgy, Central South University, Changsha, Hunan 410083 (China); Liu, Shuhong, E-mail: shhliu@csu.edu.cn [State Key Laboratory of Powder Metallurgy, Central South University, Changsha, Hunan 410083 (China); Sino-German Cooperation Group “Microstructure in Al alloys”, Central South University, Changsha, Hunan 410083 (China); Cheng, Kaiming; Tang, Ying [State Key Laboratory of Powder Metallurgy, Central South University, Changsha, Hunan 410083 (China); Ou, Pengfei [School of Materials Science and Engineering, Central South University, Changsha, Hunan 410083 (China); State Key Laboratory of Powder Metallurgy, Central South University, Changsha, Hunan 410083 (China); Nash, Philip [Thermal Processing Technology Center, Illinois Institute of Technology (IIT), 10 West 32nd Street, Chicago, IL 60616 (United States); Sundman, Bo [INSTN, CEA Saclay, 91191 Gif-Sur-Yvette Cedex (France); Du, Yong [State Key Laboratory of Powder Metallurgy, Central South University, Changsha, Hunan 410083 (China); Sino-German Cooperation Group “Microstructure in Al alloys”, Central South University, Changsha, Hunan 410083 (China); Zheng, Feng [School of Materials Science and Engineering, Central South University, Changsha, Hunan 410083 (China)

    2015-05-20

    Highlights: • Heat contents of Co{sub 2}Hf and CoHf{sub 2} were measured by drop calorimetry. • Enthalpy of formation for Co{sub 23}Hf{sub 6} was computed via first-principles calculations. • Co–Hf system was assessed by means of CALPHAD approach. • Order–disorder model is used to describe B2 (CoHf) and A2 (βHf). • Glass forming range of the Co–Hf amorphous alloys was predicted. - Abstract: Phase equilibria and thermodynamic properties of the Co–Hf system were investigated via calorimetric measurements, first-principles calculations and thermodynamic modeling. Heat contents of Co{sub 2}Hf and CoHf{sub 2} were measured by drop calorimetry from 300 to 1200 °C. The enthalpy of formation for Co{sub 23}Hf{sub 6} at 0 K was computed via first-principles calculations. Based on the experimental measurements and first-principles calculations from the present work and the literature, the Co–Hf system was assessed by means of CALPHAD (CALculation of PHAse Diagram) approach. The excess Gibbs energy of solution phases was modeled with Redlich–Kister polynomial. Sublattice models were employed to describe the homogeneity ranges of Co{sub 2}Hf, CoHf and CoHf{sub 2}. The order–disorder transition between B2 (CoHf) and A2 (βHf) phases was taken into account in the current optimization. Using the optimized parameters, glass forming range (GFR) of the Co–Hf amorphous alloys was predicted to be 15–75 at.% Hf, which is in satisfactory agreement with the experimental observation.

  16. Description of $^{178}$Hf$^{m2}$ in the constrained relativistic mean field theory

    CERN Document Server

    Wei, Zhang; Shuang-Quan, Zhang

    2009-01-01

    The properties of the ground state of $^{178}$Hf and the isomeric state $^{178}$Hf$^{m2}$ are studied within the adiabatic and diabatic constrained relativistic mean field (RMF) approaches. The RMF calculations reproduce well the binding energy and the deformation for the ground state of $^{178}$Hf. Using the ground state single-particle eigenvalues obtained in the present calculation, the lowest excitation configuration with $K^\\pi=16^+$ is found to be $\

  17. Assembly of the CMS HF (hadron forward) calorimeter, April 2003 to June 2005

    CERN Multimedia

    Tejinder S. Virdee, CERN

    2005-01-01

    The forward calorimeters (HF) of the CMS hadron calorimeter system are located 11.2 m from the interaction point. Each HF module is composed by 18 wedges, made of steel absorbers and radiation-hard quartz fibers. The photogallery shows the wedges (Figs. 1-3, April 2003), the assembly of one HF module (Figs. 4-9, May and June 2004) and the assembly of the other (Figs. 10-11, June 2005)

  18. Far-Field Testing Method of Spurious Emission Produced by HF RFID

    OpenAIRE

    Nikola Gvozdenovic; Ralph Prestros; Mecklenbräuker, Christoph F.

    2016-01-01

    We present measurements of spurious emission produced by high-frequency radio frequency identification (HF RFID) using carrier frequency of 13.56 MHz. HF RFID tags produce unwanted emission due to rectification and more generally due to nonlinearity of analog front end. Depending on the conducting material of an HF RFID coil and surrounding dielectric material, the coil behaves as more or less good antenna on some harmonic frequencies. Exact characterization and analysis of unwanted emission ...

  19. Robust Matrix Completion with Corrupted Columns

    CERN Document Server

    Chen, Yudong; Caramanis, Constantine; Sanghavi, Sujay

    2011-01-01

    This paper considers the problem of matrix completion, when some number of the columns are arbitrarily corrupted, potentially by a malicious adversary. It is well-known that standard algorithms for matrix completion can return arbitrarily poor results, if even a single column is corrupted. What can be done if a large number, or even a constant fraction of columns are corrupted? In this paper, we study this very problem, and develop an efficient algorithm for its solution. Our results show that with a vanishing fraction of observed entries, it is nevertheless possible to succeed in performing matrix completion, even when the number of corrupted columns grows. When the number of corruptions is as high as a constant fraction of the total number of columns, we show that again exact matrix completion is possible, but in this case our algorithm requires many more -- a constant fraction -- of observations. One direct application comes from robust collaborative filtering. Here, some number of users are so-called mani...

  20. Enhanced resistive switching and multilevel behavior in bilayered HfAlO/HfAlO{sub x} structures for non-volatile memory applications

    Energy Technology Data Exchange (ETDEWEB)

    Faita, F. L., E-mail: fabriciofaita@gmail.com [Centre of Physics, University of Minho, Campus de Gualtar, 4710-057 Braga (Portugal); Departamento de Física, Universidade Federal de Santa Catarina, Campus Trindade, 88040-900 Florianópolis, SC (Brazil); Silva, J. P. B., E-mail: josesilva@fisica.uminho.pt [Centre of Physics, University of Minho, Campus de Gualtar, 4710-057 Braga (Portugal); IFIMUP and IN-Institute of Nanoscience and Nanotechnology, Departamento de Física e Astronomia, Faculdade de Ciências da Universidade do Porto, 4169-007 Porto (Portugal); Pereira, M.; Gomes, M. J. M. [Centre of Physics, University of Minho, Campus de Gualtar, 4710-057 Braga (Portugal)

    2015-12-14

    In this work, hafnium aluminum oxide (HfAlO) thin films were deposited by ion beam sputtering deposition technique on Si substrate. The presence of oxygen vacancies in the HfAlO{sub x} layer deposited in oxygen deficient environment is evidenced from the photoluminescence spectra. Furthermore, HfAlO(oxygen rich)/HfAlO{sub x}(oxygen poor) bilayer structures exhibit multilevel resistive switching (RS), and the switching ratio becomes more prominent with increasing the HfAlO layer thickness. The bilayer structure with HfAlO/HfAlO{sub x} thickness of 30/40 nm displays the enhanced multilevel resistive switching characteristics, where the high resistance state/intermediate resistance state (IRS) and IRS/low resistance state resistance ratios are ≈10{sup 2} and ≈5 × 10{sup 5}, respectively. The switching mechanisms in the bilayer structures were investigated by the temperature dependence of the three resistance states. This study revealed that the multilevel RS is attributed to the coupling of ionic conduction and the metallic conduction, being the first associated to the formation and rupture of conductive filaments related to oxygen vacancies and the second with the formation of a metallic filament. Moreover, the bilayer structures exhibit good endurance and stability in time.

  1. Unusually low ozone, HCl, and HNO3 column measurements at Eureka, Canada during winter/spring 2011

    Directory of Open Access Journals (Sweden)

    R. L. Mittermeier

    2012-04-01

    Full Text Available As a consequence of dynamically variable meteorological conditions, springtime Arctic ozone levels exhibit significant interannual variability in the lower stratosphere. In winter 2011, the polar vortex was strong and cold for an unusually long time. Our research site, located at Eureka, Nunavut, Canada (80.05° N, 86.42° W, was mostly inside the vortex from October 2010 until late March 2011. The Bruker 125HR Fourier transform infrared spectrometer installed at the Polar Environment Atmospheric Research Laboratory at Eureka acquired measurements from 23 February to 6 April during the 2011 Canadian Arctic Atmospheric Chemistry Experiment Validation Campaign. These measurements showed unusually low ozone, HCl, and HNO3 total columns compared to the previous 14 yr. To remove dynamical effects, we normalized these total columns by the HF total column. The normalized values of the ozone, HCl, and HNO3 total columns were smaller than those from previous years, and confirmed the occurrence of chlorine activation and chemical ozone depletion. To quantify the chemical ozone loss, a three-dimensional chemical transport model, SLIMCAT, and the passive subtraction method were used. The chemical ozone depletion was calculated as the mean percentage difference between the measured ozone and the SLIMCAT passive ozone, and was found to be 35%.

  2. Unusually low ozone, HCl, and HNO3 column measurements at Eureka, Canada during winter/spring 2011

    Directory of Open Access Journals (Sweden)

    G. J. Nott

    2012-01-01

    Full Text Available As a consequence of dynamically variable meteorological conditions, springtime Arctic ozone levels exhibit significant interannual variability in the lower stratosphere. In winter 2011, the polar vortex was strong and cold for an unusually long time. Our research site, located at Eureka, Nunavut, Canada (80.05° N, 86.42° W, was mostly inside the vortex from October 2010 until late March 2011. The Bruker 125HR Fourier transform infrared spectrometer installed at the Polar Environment Atmospheric Research Laboratory at Eureka acquired measurements from 23 February to 6 April during the 2011 Canadian Arctic Atmospheric Chemistry Experiment Validation Campaign. These measurements showed unusually low ozone, HCl, and HNO3 total columns compared to the previous 14 yr. To remove dynamical effects, we normalized these total columns by the HF total column. The normalized values of the ozone, HCl, and HNO3 total columns were smaller than those from previous years, and confirmed the occurrence of chlorine activation and chemical ozone depletion. To quantify the chemical ozone loss, a three-dimensional chemical transport model, SLIMCAT, and the passive subtraction method were used. The chemical ozone depletion was calculated as the mean percentage difference between the measured ozone and the SLIMCAT passive ozone, and was found to be 35%.

  3. Ferroelectric phase stabilization of HfO2 by nitrogen doping

    Science.gov (United States)

    Xu, Lun; Nishimura, Tomonori; Shibayama, Shigehisa; Yajima, Takeaki; Migita, Shinji; Toriumi, Akira

    2016-09-01

    We report that nitrogen (N) doping can drive the ferroelectricity of HfO2. It was found that N doping can cause the transition from a monoclinic phase to a highly symmetric phase. The role of N doping is discussed from the viewpoints of charge balance and bond-constraining effects. The former is responsible for the structural transformation from a paraelectric phase to a ferroelectric phase by forming an oxygen vacancy. In addition, Hf-N and N-O bonds with covalent characteristics have strong effects on HfO2 structural and electrical properties, and thus contribute to a marked HfO2 para-/ferroelectric transition.

  4. Efficient noble metal nanocatalysts supported on HfC(001 for O2 dissociation

    Directory of Open Access Journals (Sweden)

    Shiyan Wang

    2017-03-01

    Full Text Available The adsorption and dissociation of O2 on the M4 (M=Au, Pd, Pt clusters supported on HfC(001 (Hafnium Carbide are investigated using ab initio density functional theory calculations. The geometric and electronic structures are analyzed in detail. It is found that the dissociation barriers of O2 on Au4/HfC(001 (0.26 eV, Pd4/HfC(001 (0.49 eV and Pt4/HfC(001 (0.09 eV are much smaller than those on the clean surfaces of HfC(001 (1.60 eV, Au(111 (1.37 eV, Pd(111 (1.0 and 0.91 eV and Pt(111 (0.27–0.7 eV, respectively. The low dissociation barriers imply that the Pt4/HfC(001 exhibits the highest catalytic activity for O2 dissociation, and the Au4/HfC(001 and Pd4/HfC(001 may also be possible substitutes with lower cost for the current Pt/C catalyst for O2 dissociation. The present study is conductive to designing new efficient noble metal catalyst using HfC support for efficiently promoting O2 dissociation.

  5. Efficient noble metal nanocatalysts supported on HfC(001) for O2 dissociation

    Science.gov (United States)

    Wang, Shiyan; Zhang, Xilin; Zhang, Yanxing; Mao, Jianjun; Yang, Zongxian

    2017-03-01

    The adsorption and dissociation of O2 on the M4 (M=Au, Pd, Pt) clusters supported on HfC(001) (Hafnium Carbide) are investigated using ab initio density functional theory calculations. The geometric and electronic structures are analyzed in detail. It is found that the dissociation barriers of O2 on Au4/HfC(001) (0.26 eV), Pd4/HfC(001) (0.49 eV) and Pt4/HfC(001) (0.09 eV) are much smaller than those on the clean surfaces of HfC(001) (1.60 eV), Au(111) (1.37 eV), Pd(111) (1.0 and 0.91 eV) and Pt(111) (0.27-0.7 eV), respectively. The low dissociation barriers imply that the Pt4/HfC(001) exhibits the highest catalytic activity for O2 dissociation, and the Au4/HfC(001) and Pd4/HfC(001) may also be possible substitutes with lower cost for the current Pt/C catalyst for O2 dissociation. The present study is conductive to designing new efficient noble metal catalyst using HfC support for efficiently promoting O2 dissociation.

  6. Study of Direct-Contact HfO2/Si Interfaces

    Directory of Open Access Journals (Sweden)

    Noriyuki Miyata

    2012-03-01

    Full Text Available Controlling monolayer Si oxide at the HfO2/Si interface is a challenging issue in scaling the equivalent oxide thickness of HfO2/Si gate stack structures. A concept that the author proposes to control the Si oxide interface by using ultra-high vacuum electron-beam HfO2 deposition is described in this review paper, which enables the so-called direct-contact HfO2/Si structures to be prepared. The electrical characteristics of the HfO2/Si metal-oxide-semiconductor capacitors are reviewed, which suggest a sufficiently low interface state density for the operation of metal-oxide-semiconductor field-effect-transistors (MOSFETs but reveal the formation of an unexpected strong interface dipole. Kelvin probe measurements of the HfO2/Si structures provide obvious evidence for the formation of dipoles at the HfO2/Si interfaces. The author proposes that one-monolayer Si-O bonds at the HfO2/Si interface naturally lead to a large potential difference, mainly due to the large dielectric constant of the HfO2. Dipole scattering is demonstrated to not be a major concern in the channel mobility of MOSFETs.

  7. Structural degradation of thin HfO2 film on Ge during the postdeposition annealing

    Science.gov (United States)

    Miyata, Noriyuki; Yasuda, Tetsuji; Abe, Yasuhiro

    2010-05-01

    Securing the thermal robustness of thin hafnium oxide (HfO2) film on the semiconductor surface is an important technical issue in the fabrication of the metal-oxide-semiconductor field-effect transistor devices, as the HfO2-based high-k gate stacks usually undergo high-temperature processes. In this study, the structural development of thin HfO2 film on a Ge surface during postdeposition annealing in an ultrahigh vacuum was examined to explore the origin for the initial degradation of thin HfO2 film. Void nucleation and subsequent two-dimensional void growth take place at 780-840 °C, while the chemical composition of the remaining Hf oxide is virtually stable. Both the void nucleation and growth processes show similar larger activation energy of about 10 eV. Based on the observed manner of void growth and the estimated activation energies, the authors propose that mass transport on the HfO2 surface is responsible for void nucleation in the HfO2 films on Ge. The authors also compare the present results with the previous studies on HfO2/Si structures, and suggest that similar surface process leads to the local Hf silicidation.

  8. The effect of Cu doping concentration on resistive switching of HfO{sub 2} film

    Energy Technology Data Exchange (ETDEWEB)

    Guo, Tingting; Tan, Tingting, E-mail: tantt@nwpu.edu.cn; Liu, Zhengtang

    2015-10-01

    Graphical abstract: - Highlights: • The Cu doped and undoped HfO{sub 2} films were fabricated. • The improved RS behaviors were observed for Cu doped HfO{sub 2} film with BRS. • The 9.7% doped HfO{sub 2}:Cu film showed both BRS and URS behaviors. • The related switching mechanisms were illustrated. - Abstract: The Cu-doped and undoped HfO{sub 2} films were fabricated and the effect of Cu doping concentration on resistive switching (RS) of HfO{sub 2} film was demonstrated. The X-ray photoelectron spectroscopy (XPS) was carried out to investigate the chemical bonding states of Cu in HfO{sub 2}:Cu film. The improved RS behaviors in terms of ON/OFF ratio and switching parameters were observed for Cu-doped HfO{sub 2} film with bipolar resistive switching (BRS) behavior. With the increase of Cu doping concentration, the 9.7% Cu-doped HfO{sub 2} film showed both BRS and unipolar resistive switching (URS) behaviors with large operating voltages. The space charge limited current (SCLC) effect was proposed to interpret the switching mechanism of HfO{sub 2}:Cu films with BRS behavior and the URS behavior can be explained by the migration of Cu ions.

  9. Lu-hf total-rock isochron for the eucrite meteorites

    Science.gov (United States)

    Patchett, P.J.; Tatsumoto, M.

    1980-01-01

    The isotope 176Lu (2.6% of natural lutetium) decays by ??- to 176Hf, with a long half life. We present here the first Lu-Hf isochron. The eucrite meteorites, a suite of planetary igneous rocks of known age, 4,550 Myr, define a 10-point total-rock isochron with a slope of 0.0934 ?? 40, leading to a value of 3.53 ?? 0.14 ??1010yr for the ??--decay half life of 176Lu. The isochron intercept of 0.27973 ?? 12 gives the initial 176Hf/177Hf for the inner Solar System at the time of accretion. ?? 1980 Nature Publishing Group.

  10. Chemical stability and defect formation in CaHfO3

    KAUST Repository

    Alay-E-Abbas, Syed Muhammad

    2014-04-01

    Defects in CaHfO3 are investigated by ab initio calculations based on density functional theory. Pristine and anion-deficient CaHfO 3 are found to be insulating, whereas cation-deficient CaHfO 3 is hole-doped. The formation energies of neutral and charged cation and anion vacancies are evaluated to determine the stability in different chemical environments. Moreover, the energies of the partial and full Schottky defect reactions are computed. We show that clustering of anion vacancies in the HfO layers is energetically favorable for sufficiently high defect concentrations and results in metallicity. © 2014 EPLA.

  11. Anticooperativity of FHF hydrogen bonds in clusters of the type F- × (HF)n, RF × (HF)n and XF × (HF)n, R = alkyl and X = H, Br, Cl, F

    Science.gov (United States)

    Kucherov, S. Yu.; Bureiko, S. F.; Denisov, G. S.

    2016-02-01

    Properties of twenty five hydrogen-bonded complexes, namely, F- × (HF)n (n = 1-6), RF × (HF)n (R = t-Bu, i-Pr, Et, Me; n = 1-3), XF × (HF)n (X = H, Br, Cl; n = 1-2), and FF…HF with the hydrogen bond energy varying in a wide range have been calculated using ab initio methods at the MP2/6-31++G** level. For the first time, the energies, geometrical parameters and vibrational frequencies are obtained for the series of clusters, where the bonding character changes from covalent to van der Waals on the variation of proton-acceptor ability of the base, and the energies are in the range of 45-1 kcal/mol. The mutual influence of multiple hydrogen bonds of F…HF type in clusters, in which a fluorine anion or an atom participates in hydrogen bond formation as the acceptor, is systematically investigated. The relative changes in the values of the considered parameters on the sequential addition of an HF molecule (anticooperativity) were determined. It was shown that non-additivity of the interaction is most strongly pronounced in the energy and vibrational frequency values, geometrical parameters of hydrogen bonds are less sensitive to the mutual influence. The anticooperative effect is more pronounced on the hydrogen bridge length R(F...F) than on the geometry of proton donor r(HF). The hydrogen bond formation and the increase of the number n of ligands lead to successive lengthening of the r(XF) bond adjacent to the hydrogen bridge. The length of an XF bond changes stronger on formation of each hydrogen bond than the HF bond length.

  12. Buckling driven debonding in sandwich columns

    DEFF Research Database (Denmark)

    Østergaard, Rasmus Christian

    2008-01-01

    A compression loaded sandwich column that contains a debond is analyzed using a geometrically non-linear finite element model. The model includes a cohesive zone along one face sheet/core interface whereby the debond can extend by interface crack growth. Two geometrical imperfections are introduced......; a global imperfection of the sandwich column axis and a local imperfection of the debonded face sheet axis. The model predicts the sandwich column to be very sensitive to the initial debond length and the local face sheet imperfection. The study shows that the sensitivity to the face sheet imperfection...... results from two mechanisms: (a) interaction of local debond buckling and global buckling and (b) the development of a damaged zone at the debond crack tip. Based on the pronounced imperfection sensitivity, the author predicts that an experimental measurement of the strength of sandwich structures may...

  13. Non-planar microfabricated gas chromatography column

    Science.gov (United States)

    Lewis, Patrick R.; Wheeler, David R.

    2007-09-25

    A non-planar microfabricated gas chromatography column comprises a planar substrate having a plurality of through holes, a top lid and a bottom lid bonded to opposite surfaces of the planar substrate, and inlet and outlet ports for injection of a sample gas and elution of separated analytes. A plurality of such planar substrates can be aligned and stacked to provide a longer column length having a small footprint. Furthermore, two or more separate channels can enable multi-channel or multi-dimensional gas chromatography. The through holes preferably have a circular cross section and can be coated with a stationary phase material or packed with a porous packing material. Importantly, uniform stationary phase coatings can be obtained and band broadening can be minimized with the circular channels. A heating or cooling element can be disposed on at least one of the lids to enable temperature programming of the column.

  14. Computational analysis of ozonation in bubble columns

    Energy Technology Data Exchange (ETDEWEB)

    Quinones-Bolanos, E. [Univ. of Guelph, School of Engineering, Guelph, Ontario (Canada)]|[Univ. de Cartagena, Facultad de Ciencias e Ingenieria, Cartagena de Indias (Colombia); Zhou, H.; Otten, L. [Univ. of Guelph, School of Engineering, Guelph, Ontario (Canada)]. E-mail: hzhou@uoguelph.ca

    2002-06-15

    This paper presents a new computational ozonation model based on the principle of computational fluid dynamics along with the kinetics of ozone decay and microbial inactivation to predict the performance of ozone disinfection in fine bubble columns. The model can be represented using a mixture two-phase flow model to simulate the hydrodynamics of the water flow and using two transport equations to track the concentration profiles of ozone and microorganisms along the height of the column, respectively. The applicability of this model was then demonstrated by comparing the simulated ozone concentrations with experimental measurements obtained from a pilot scale fine bubble column. One distinct advantage of this approach is that it does not require the prerequisite assumptions such as plug flow condition, perfect mixing, tanks-in-series, uniform radial or longitudinal dispersion in predicting the performance of disinfection contactors without carrying out expensive and tedious tracer studies. (author)

  15. Methylmercury production in the marine water column

    Science.gov (United States)

    Topping, G.; Davies, I. M.

    1981-03-01

    Although the biosynthesis of methylmercury in sediments is well established1, this is not necessarily the exclusive natural source of methylmercury entering the marine food chain, particularly commercial fish and shellfish species for human consumption. An examination of mercury levels in freshwater fish2, collected from a lake with a history of industrial mercury contamination, suggested that levels in fish are controlled in part by mercury in suspension and it followed that methylation should occur in the water column. Although methylmercury is present in seawater in coastal areas receiving discharges of waste containing either inorganic mercury3 or methylmercury4 there is no evidence that methylmercury is actually formed in the water column. We now present data which demonstrate that inorganic mercury can be methylated in the water column and we compare this production with that known to occur in marine sediments.

  16. Neutron camera employing row and column summations

    Science.gov (United States)

    Clonts, Lloyd G.; Diawara, Yacouba; Donahue, Jr, Cornelius; Montcalm, Christopher A.; Riedel, Richard A.; Visscher, Theodore

    2016-06-14

    For each photomultiplier tube in an Anger camera, an R.times.S array of preamplifiers is provided to detect electrons generated within the photomultiplier tube. The outputs of the preamplifiers are digitized to measure the magnitude of the signals from each preamplifier. For each photomultiplier tube, a corresponding summation circuitry including R row summation circuits and S column summation circuits numerically add the magnitudes of the signals from preamplifiers for each row and for each column to generate histograms. For a P.times.Q array of photomultiplier tubes, P.times.Q summation circuitries generate P.times.Q row histograms including R entries and P.times.Q column histograms including S entries. The total set of histograms include P.times.Q.times.(R+S) entries, which can be analyzed by a position calculation circuit to determine the locations of events (detection of a neutron).

  17. Effects of Hf Incorporation on Negative Bias-Illumination Stress Stability in Hf-In-Zn-O Thin-Film Transistors

    Science.gov (United States)

    Kim, Sangwook; Park, Jae Chul; Kim, Dae Hwan; Lee, Jang-Sik

    2013-04-01

    In this study, highly reliable amorphous oxide semiconductor-based thin-film transistors (TFTs) were developed. The Hf concentration was systematically changed in the Hf-incorporated In-Zn-O (HIZO) TFTs, and Hf played an important role in determining the negative bias-illumination instability. The process parameters were optimized in order to obtain HIZO TFTs with an excellent stability. HIZO can be processed on a 6-in. wafer at low temperatures and is almost transparent in the visible range. Thus this material is promising for use in current TFTs as well as future transparent electronic device components with good electrical performance and excellent stability.

  18. Accelerating selected columns of the density matrix computations via approximate column selection

    CERN Document Server

    Damle, Anil; Ying, Lexing

    2016-01-01

    Localized representation of the Kohn-Sham subspace plays an important role in quantum chemistry and materials science. The recently developed selected columns of the density matrix (SCDM) method [J. Chem. Theory Comput. 11, 1463, 2015] is a simple and robust procedure for finding a localized representation of a set of Kohn-Sham orbitals from an insulating system. The SCDM method allows the direct construction of a well conditioned (or even orthonormal) and localized basis for the Kohn-Sham subspace. The SCDM procedure avoids the use of an optimization procedure and does not depend on any adjustable parameters. The most computationally expensive step of the SCDM method is a column pivoted QR factorization that identifies the important columns for constructing the localized basis set. In this paper, we develop a two stage approximate column selection strategy to find the important columns at much lower computational cost. We demonstrate the effectiveness of this process using a dissociation process of a BH$_{3}...

  19. Phase1 upgrade of the CMS-HF Calorimeter

    CERN Document Server

    Gulmez, Erhan

    2016-01-01

    In this presentation, results of the Phase I upgrade of the CMS Hadron Forward Calorimeter (HF) are discussed. The CMS-HF Calorimeter was using regular PMTs. Cherenkov light produced in the quartz fibers embedded in the iron absorber was read out with the PMTs. However, occasionally, stray muons hitting the PMT windows cause Cherenkov radiation in the PMT itself and produce large signals. These large signals mimic a very high-energy particle and are tagged as important by the trigger. To reduce this problem, PMTs had to be replaced. The four-anode PMTs that were chosen have thinner windows; thereby reducing the Cherenkov radiation in the PMT window. As part of the upgrade, the read-out electronics is to be replaced so that the PMTs are read out in two channels by connecting each pair of anodes to a single channel. Information provided by these two channels will help us reject the false signals due to the stray muons since the Cherenkov radiation in the PMT window is more likely to produce a signal only in one...

  20. Reversible spin texture in ferroelectric Hf O2

    Science.gov (United States)

    Tao, L. L.; Paudel, Tula R.; Kovalev, Alexey A.; Tsymbal, Evgeny Y.

    2017-06-01

    Spin-orbit coupling effects occurring in noncentrosymmetric materials are known to be responsible for nontrivial spin configurations and a number of emergent physical phenomena. Ferroelectric materials may be especially interesting in this regard due to reversible spontaneous polarization making possible a nonvolatile electrical control of the spin degrees of freedom. Here, we explore a technologically relevant oxide material, Hf O2 , which has been shown to exhibit robust ferroelectricity in a noncentrosymmetric orthorhombic phase. Using theoretical modelling based on density-functional theory, we investigate the spin-dependent electronic structure of the ferroelectric Hf O2 and demonstrate the appearance of chiral spin textures driven by spin-orbit coupling. We analyze these spin configurations in terms of the Rashba and Dresselhaus effects within the k .p Hamiltonian model and find that the Rashba-type spin texture dominates around the valence-band maximum, while the Dresselhaus-type spin texture prevails around the conduction band minimum. The latter is characterized by a very large Dresselhaus constant λD= 0.578 eV Å, which allows using this material as a tunnel barrier to produce tunneling anomalous and spin Hall effects that are reversible by ferroelectric polarization.

  1. Radiation effects in Zr and Hf containing garnets

    Energy Technology Data Exchange (ETDEWEB)

    Whittle, Karl R. [Institute of Materials Engineering, Australian Nuclear Science and Technology Organisation, PMB1, Menai, NSW 2234 (Australia); Department of Materials Science and Engineering, University of Sheffield, Mappin Street, Sheffield S1 3JD (United Kingdom); Blackford, Mark G.; Smith, Katherine L. [Institute of Materials Engineering, Australian Nuclear Science and Technology Organisation, PMB1, Menai, NSW 2234 (Australia); Zaluzec, Nestor J. [Argonne National Laboratory, 9700 South Cass Avenue, Argonne, IL 60439 (United States); Weyland, Matthew [Monash Centre for Electron Microscopy, Monash University, Victoria 3800 (Australia); Department of Materials Engineering, Monash University, Victoria 3800 (Australia); Lumpkin, Gregory R. [Institute of Materials Engineering, Australian Nuclear Science and Technology Organisation, PMB1, Menai, NSW 2234 (Australia)

    2015-07-15

    Garnets have been considered as host phases for the safe immobilisation of high-level nuclear waste, as they have been shown to accommodate a wide range of elements across three different cation sites, such as Ca, Y, Mn on the a-site, Fe, Al, U, Zr, and Ti on the b-site, and Si, Fe, Al on the c-site. Garnets, due to their ability to have variable composition, make ideal model materials for the examination of radiation damage and recovery in nuclear materials, including as potential waste forms. Kimzeyite, Ca{sub 3}Zr{sub 2}FeAlSiO{sub 12}, has been shown naturally to contain up to 30 wt% Zr, and has previously been examined to elucidate both the structure and ordering within the lattice. This study examines the effects of radiation damage and recovery using in-situ ion beam irradiation with 1 MeV Kr ions at the IVEM-TANDEM facility, Argonne National Laboratory. The complementary Hf containing system Ca{sub 3}Hf{sub 2}FeAlSiO{sub 12} was also examined, and found to have a different response to irradiation damage. A sample of irradiated Ca{sub 3}Zr{sub 2}FeAlSiO{sub 12}, at 1000 K, was characterised using aberration corrected (S)TEM and found to contain discreet, nano-sized, crystalline Fe rich particles, indicating a competing process during recovery is occurring.

  2. Observations of HF backscatter decay rates from HAARP generated FAI

    Science.gov (United States)

    Bristow, W. A.; Hysell, D. L.

    2016-12-01

    Suitable experiments at the High-frequency Active Auroral Research Program (HAARP) facilities in Gakona, Alaska, create a region of ionospheric Field-Aligned Irregularities (FAI) that produces strong radar backscatter observed by the SuperDARN radar on Kodiak Island, Alaska. Creation of FAI in HF ionospheric modification experiments has been studied by a number of authors who have developed a rich theoretical background. The decay of the irregularities, however, has not been so widely studied yet it has the potential for providing estimates of the parameters of natural irregularity diffusion, which are difficult measure by other means. Hysell, et al. [1996] demonstrated using the decay of radar scatter above the Sura heating facility to estimate irregularity diffusion. A large database of radar backscatter from HAARP generated FAI has been collected over the years. Experiments often cycled the heater power on and off in a way that allowed estimates of the FAI decay rate. The database has been examined to extract decay time estimates and diffusion rates over a range of ionospheric conditions. This presentation will summarize the database and the estimated diffusion rates, and will discuss the potential for targeted experiments for aeronomy measurements. Hysell, D. L., M. C. Kelley, Y. M. Yampolski, V. S. Beley, A. V. Koloskov, P. V. Ponomarenko, and O. F. Tyrnov, HF radar observations of decaying artificial field aligned irregularities, J. Geophys. Res. , 101, 26,981, 1996.

  3. Observations of HF backscatter decay rates from HAARP generated FAI

    Science.gov (United States)

    Bristow, William; Hysell, David

    2016-07-01

    Suitable experiments at the High-frequency Active Auroral Research Program (HAARP) facilities in Gakona, Alaska, create a region of ionospheric Field-Aligned Irregularities (FAI) that produces strong radar backscatter observed by the SuperDARN radar on Kodiak Island, Alaska. Creation of FAI in HF ionospheric modification experiments has been studied by a number of authors who have developed a rich theoretical background. The decay of the irregularities, however, has not been so widely studied yet it has the potential for providing estimates of the parameters of natural irregularity diffusion, which are difficult measure by other means. Hysell, et al. [1996] demonstrated using the decay of radar scatter above the Sura heating facility to estimate irregularity diffusion. A large database of radar backscatter from HAARP generated FAI has been collected over the years. Experiments often cycled the heater power on and off in a way that allowed estimates of the FAI decay rate. The database has been examined to extract decay time estimates and diffusion rates over a range of ionospheric conditions. This presentation will summarize the database and the estimated diffusion rates, and will discuss the potential for targeted experiments for aeronomy measurements. Hysell, D. L., M. C. Kelley, Y. M. Yampolski, V. S. Beley, A. V. Koloskov, P. V. Ponomarenko, and O. F. Tyrnov, HF radar observations of decaying artificial field aligned irregularities, J. Geophys. Res. , 101, 26,981, 1996.

  4. Interrogation zone determination in HF RFID systems with multiplexed antennas*

    Directory of Open Access Journals (Sweden)

    Jankowski-Mihułowicz Piotr

    2015-09-01

    Full Text Available The operation of an anti-collision RFID system is characterized by the interrogation zone which should be estimated in any direction of 3D space for a group of electronic transponders. The interrogation zone should be as large as possible. However, the many problems in this area are due to the fact that energy can be transferred to transponders only on a limited distance. The greatest flexibility in developing RFID applications and shaping the interrogation zone can be achieved using the system with an antenna multiplexer. Therefore the problem of the interrogation zone determination in HF RFID systems with two orthogonal RWD antennas is presented in the paper. The perceived issues have been effectively dealt with and the solution has been proposed on the basis of the elaborated model. Conducted studies have been used to develop the software tool JankoRFIDmuxHF in the Mathcad environment. The research results are analysed in an example system configuration. The specialized measuring stand has been used for experimental verification of the identification efficiency. The convergence of the measurements and calculations confirms a practical usefulness of the presented concept of interrogation zone determination in anti-collision systems. It also shows the practical utility of the developed model and software tools.

  5. Bubble Shuttle: A newly discovered transport mechanism, which transfers microorganisms from the sediment into the water column

    Science.gov (United States)

    Schmale, O.; Stolle, C.; Leifer, I.; Schneider von Deimling, J.; Kiesslich, K.; Krause, S.; Frahm, A.; Treude, T.

    2013-12-01

    The diversity and abundance of methanotrophic microorganisms is well studied in the aquatic environment, indicating their importance in biogeochemical cycling of methane in the sediment and the water column. However, whether methanotrophs are distinct populations in these habitats or are exchanged between benthic and pelagic environments, remains an open question. Therefore, field studies were conducted at the 'Rostocker Seep' site (Coal Oil Point seep area, California, USA) to test our hypothesis that methane-oxidizing microorganisms can be transported by gas bubbles from the sediment into the water column. The natural methane emanating location 'Rostocker Seep' showed a strong surface water oversaturation in methane with respect to the atmospheric equilibrium. Catalyzed Reporter Deposition Fluorescence In Situ Hybridization (CARD-FISH) analyzes were performed to determine the abundance of aerobic and anaerobic methanotrophic microorganisms. Aerobic methane oxidizing bacteria were detected in the sediment and the water column, whereas anaerobic methanotrophs were detected exclusively in the sediment. The key device of the project was the newly developed "Bubble Catcher" used to collect naturally emanating gas bubbles at the sea floor together with particles attached to the bubble surface rim. Bubble Catcher experiments were carried out directly above a natural bubble release spot and on a reference site at which artificially released gas bubbles were caught, which had no contact with the sediment. CARD-FISH analyzes showed that aerobic methane oxidizing bacteria were transported by gas bubbles from the sediment into the water column. In contrast anaerobic methanotrophs were not detected in the bubble catcher. Further results indicate that this newly discovered Bubble Shuttle transport mechanism might influence the distribution pattern of methanotrophic microorganisms in the water column and even at the air-sea interface. Methane seep areas are often characterized

  6. Final Report, Distillation Column Flooding Predictor

    Energy Technology Data Exchange (ETDEWEB)

    George E. Dzyacky

    2003-05-31

    The Flooding Predictor is an advanced process control strategy comprising a patented pattern-recognition methodology that identifies pre-flood patterns discovered to precede flooding events in distillation columns. The grantee holds a U.S. patent on the modeling system. The technology was validated at the Separations Research Program, The University of Texas at Austin under a grant from the U. S. Department of Energy, Inventions & Innovation Program. Distillation tower flooding occurs at abnormally high vapor and/or liquid rates. The loss in tray efficiencies is attributed to unusual behavior of liquid inventories inside the column leading to conditions of flooding of the space in between trays with liquid. Depending on the severity of the flood condition, consequences range from off spec products to equipment damage and tower shutdown. This non-intrusive pattern recognition methodology, processes signal data obtained from existing column instrumentation. Once the pattern is identified empirically, it is modeled and coded into the plant's distributed control system. The control system is programmed to briefly "unload" the tower each time the pattern appears. The unloading takes the form of a momentary reduction in column severity, e.g., decrease bottom temperature, reflux or tower throughput. Unloading the tower briefly at the pre-flood state causes long-term column operation to become significantly more stable - allowing an increase in throughput and/or product purity. The technology provides a wide range of value between optimization and flooding. When a distillation column is not running at capacity, it should be run in such a way ("pushed") that optimal product purity is achieved. Additional benefits include low implementation and maintenance costs, and a high level of console operator acceptance. The previous commercial applications experienced 98% uptime over a four-year period. Further, the technology is unique in its ability to distinguish between

  7. Retention Models on Core-Shell Columns.

    Science.gov (United States)

    Jandera, Pavel; Hájek, Tomáš; Růžičková, Marie

    2017-07-13

    A thin, active shell layer on core-shell columns provides high efficiency in HPLC at moderately high pressures. We revisited three models of mobile phase effects on retention for core-shell columns in mixed aqueous-organic mobile phases: linear solvent strength and Snyder-Soczewiński two-parameter models and a three-parameter model. For some compounds, two-parameter models show minor deviations from linearity due to neglect of possible minor retention in pure weak solvent, which is compensated for in the three-parameter model, which does not explicitly assume either the adsorption or the partition retention mechanism in normal- or reversed-phase systems. The model retention equation can be formulated as a function of solute retention factors of nonionic compounds in pure organic solvent and in pure water (or aqueous buffer) and of the volume fraction of an either aqueous or organic solvent component in a two-component mobile phase. With core-shell columns, the impervious solid core does not participate in the retention process. Hence, the thermodynamic retention factors, defined as the ratio of the mass of the analyte mass contained in the stationary phase to its mass in the mobile phase in the column, should not include the particle core volume. The values of the thermodynamic factors are lower than the retention factors determined using a convention including the inert core in the stationary phase. However, both conventions produce correct results if consistently used to predict the effects of changing mobile phase composition on retention. We compared three types of core-shell columns with C18-, phenyl-hexyl-, and biphenyl-bonded phases. The core-shell columns with phenyl-hexyl- and biphenyl-bonded ligands provided lower errors in two-parameter model predictions for alkylbenzenes, phenolic acids, and flavonoid compounds in comparison with C18-bonded ligands.

  8. The role of Upper Hybrid Turbulence on HF Artificial Ionization

    Science.gov (United States)

    Papadopoulos, Konstantinos Dennis; Najmi, Amir; Eliasson, Bengt; Milikh, Gennady

    2016-07-01

    One of the most fascinating and scientifically interesting phenomena of active space experiments is the discovery of artificial ionization by Todd Pedersen when the HAARP ERP reached the GW level. The phenomenon has been well documented experimentally. A theoretical model based on ionization by energetic electrons accelerated by 50-100 V/m localized electric fields due to Strong Langmuir Turbulence (SLT) near the reflection surface of the HF pump wave, reproduced the observed dynamics of the descending plasma layer quite accurately. A major defect of the model was that the electron temperature in the SLT region was a free parameter. When taken as the 2000 K representing the ambient electron temperature the SLT driven electron flux was insufficient to produce ionization. An equivalent electron temperature of 5000 K or higher was necessary to reproduce the observations. The needed electron heating was attributed to the interaction of the HF at the Upper Hybrid (UH) resonant layer, approximately 5 Km below the reflection region where the HF electric field is perpendicular to the ambient magnetic field. The heated electrons expanded upwards along the magnetic field line and interacted with SLT fields near the resonance region. A consequence of this defect was that the theory could not explain the puzzling double resonance effect. Namely the observation that the ionization level was much stronger when the HF frequency and the UH resonance were a multiple of the electron cyclotron frequency. To remedy this we used a series of Vlasov simulations to explore the HF-plasma interaction in the vicinity of the UH resonance. The simulations followed the evolution of the spectral density of the electric field over a 7.5 MHz frequency band and cm scale lengths and of the electron distribution function over one millisecond for both double resonant and non-resonant cases. Many new features were revealed by the analysis of the simulations such as: 1. Broadening of the wave

  9. Complex osteotomies vertebral column resection and decancellation.

    Science.gov (United States)

    Obeid, Ibrahim; Bourghli, Anouar; Boissière, Louis; Vital, Jean-Marc; Barrey, Cédric

    2014-07-01

    Pedicle subtraction osteotomy (PSO) is nowadays widely used to treat sagittal imbalance. Some complex malalignment cases cannot be treated by a PSO, whereas the imbalance is coronal or mixed or the sagittal imbalance is major and cannot be treated by a single PSO. The aim of this article was to review these complex situations--coronal imbalance, mixed imbalance, two-level PSO, vertebral column resection, and vertebral column decancellation, and to focus on their specificities. It wills also to evoke the utility of navigation in these complex cases.

  10. Abundance analysis of DAZ white dwarfs

    CERN Document Server

    Kawka, Adela; Dinnbier, Frantisek; Cibulkova, Helena; Nemeth, Peter

    2010-01-01

    We present an abundance analysis of a sample of 33 hydrogen-rich (DA) white dwarfs. We have used archival high-resolution spectra to measure abundances of calcium, magnesium and iron in a set of 30 objects. In addition, we present preliminary calcium abundances in three new white dwarfs based on low-dispersion spectra. We investigate some abundance ratios (Mg/Ca, Fe/Ca) that may help uncover the composition of the accretion source.

  11. Planetary nebulae abundances and stellar evolution

    NARCIS (Netherlands)

    Pottasch, S. R.; Bernard-Salas, J.

    2006-01-01

    A summary is given of planetary nebulae abundances from ISO measurements. It is shown that these nebulae show abundance gradients (with galactocentric distance), which in the case of neon, argon, sulfur and oxygen (with four exceptions) are the same as HII regions and early type star abundance gradi

  12. Planetary nebulae abundances and stellar evolution II

    NARCIS (Netherlands)

    Pottasch, S. R.; Bernard-Salas, J.

    2010-01-01

    Context. In recent years mid-and far infrared spectra of planetary nebulae have been analysed and lead to more accurate abundances. It may be expected that these better abundances lead to a better understanding of the evolution of these objects. Aims. The observed abundances in planetary nebulae are

  13. Column flotation in coal: does it make `cents?`

    Energy Technology Data Exchange (ETDEWEB)

    Laurila, M.J.

    1997-01-01

    Column flotation technology was introduced into the coal industry in 1986. The column can produce higher grade concentrates than conventional cells. This has created a niche market for columns in recovering ultrafine (-100 mesh) coal from waste streams. However, column flotation is much more expensive than froth flotation and columns can only process a maximum of 20 tons per hour per unit and consume more reagents than conventional cells. Researchers at Michigan Technological University have found that baffles along the axis of a column vastly improved performance. Today only two companies in the US participate in the column flotation market, ICF Kaiser and Deister.

  14. Electron Microprobe Analysis of Hf in Zircon: Suggestions for Improved Accuracy of a Difficult Measurement

    Science.gov (United States)

    Fournelle, J.; Hanchar, J. M.

    2013-12-01

    It is not commonly recognized as such, but the accurate measurement of Hf in zircon is not a trivial analytical issue. This is important to assess because Hf is often used as an internal standard for trace element analyses of zircon by LA-ICPMS. The issues pertaining to accuracy revolve around: (1) whether the Hf Ma or the La line is used; (2) what accelerating voltage is applied if Zr La is also measured, and (3) what standard for Hf is used. Weidenbach, et al.'s (2004) study of the 91500 zircon demonstrated the spread (in accuracy) of possible EPMA values for six EPMA labs, 2 of which used Hf Ma, 3 used Hf La, and one used Hf Lb, and standards ranged from HfO2, a ZrO2-HfO2 compound, Hf metal, and hafnon. Weidenbach, et al., used the ID-TIMS values as the correct value (0.695 wt.% Hf.), for which not one of the EPMA labs came close to that value (3 were low and 3 were high). Those data suggest: (1) that there is a systematic underestimation error of the 0.695 wt% Hf (ID-TIMS Hf) value if Hf Ma is used; most likely an issue with the matrix correction, as the analytical lines and absorption edges of Zr La, Si Ka and Hf Ma are rather tightly packed in the electromagnetic spectrum. Mass absorption coefficients are easily in error (e.g., Donovan's determination of the MAC of Hf by Si Ka of 5061 differs from the typically used Henke value of 5449 (Donovan et al, 2002); and (2) For utilization of the Hf La line, however, the second order Zr Ka line interferes with Hf La if the accelerating voltage is greater than 17.99 keV. If this higher keV is used and differential mode PHA is applied, only a portion of the interference is removed (e.g., removal of escape peaks), causing an overestimation of Hf content. Unfortunately, it is virtually impossible to apply an interference correction in this case, as it is impossible to locate Hf-free Zr probe standard. We have examined many of the combinations used by those six EPMA labs and concluded that the optimal EPMA is done with Hf

  15. Atomic scale engineering of HfO{sub 2}-based dielectrics for future DRAM applications

    Energy Technology Data Exchange (ETDEWEB)

    Dudek, Piotr

    2011-02-14

    Modern dielectrics in combination with appropriate metal electrodes have a great potential to solve many difficulties associated with continuing miniaturization process in the microelectronic industry. One significant branch of microelectronics incorporates dynamic random access memory (DRAM) market. The DRAM devices scaled for over 35 years starting from 4 kb density to several Gb nowadays. The scaling process led to the dielectric material thickness reduction, resulting in higher leakage current density, and as a consequence higher power consumption. As a possible solution for this problem, alternative dielectric materials with improved electrical and material science parameters were intensively studied by many research groups. The higher dielectric constant allows the use of physically thicker layers with high capacitance but strongly reduced leakage current density. This work focused on deposition and characterization of thin insulating layers. The material engineering process was based on Si cleanroom compatible HfO{sub 2} thin films deposited on TiN metal electrodes. A combined materials science and dielectric characterization study showed that Ba-added HfO{sub 2} (BaHfO{sub 3}) films and Ti-added BaHfO{sub 3} (BaHf{sub 0.5}Ti{sub 0.5}O{sub 3}) layers are promising candidates for future generation of state-of-the-art DRAMs. In especial a strong increase of the dielectric permittivity k was achieved for thin films of cubic BaHfO{sub 3} (k{proportional_to}38) and BaHf{sub 0.5}Ti{sub 0.5}O{sub 3} (k{proportional_to}90) with respect to monoclinic HfO{sub 2} (k{proportional_to}19). Meanwhile the CET values scaled down to 1 nm for BaHfO{sub 3} and {proportional_to}0.8 nm for BaHf{sub 0.5}Ti{sub 0.5}O{sub 3} with respect to HfO{sub 2} (CET=1.5 nm). The Hf{sup 4+} ions substitution in BaHfO{sub 3} by Ti{sup 4+} ions led to a significant decrease of thermal budget from 900 C for BaHfO{sub 3} to 700 C for BaHf{sub 0.5}Ti{sub 0.5}O{sub 3}. Future studies need to focus

  16. Evolution of continental crust and mantle heterogeneity: Evidence from Hf isotopes

    Science.gov (United States)

    Jonathan, Patchett P.; Kouvo, O.; Hedge, C.E.; Tatsumoto, M.

    1982-01-01

    We present initial 176Hf/177 Hf ratios for many samples of continental crust 3.7-0.3 Gy old. Results are based chiefly on zircons (1% Hf) and whole rocks: zircons are shown to be reliable carriers of essentially the initial Hf itself when properly chosen on the basis of U-Pb studies. Pre-3.0 Gy gneisses were apparently derived from an unfractionated mantle, but both depleted and undepleted mantle are evident as magma sources from 2.9 Gy to present. This mantle was sampled mainly from major crustal growth episodes 2.8, 1.8 and 0.7 Gy ago, all of which show gross heterogeneity of 176Hf/177Hf in magma sources from ??Hf=0 to +14, or about 60% of the variability of the present mantle. The approximate ??Hf=2??Nd relationship in ancient and modern igneous rocks shows that 176Lu/177Hf fractionates in general twice as much as 147Sm/144Nd in mantle melting processes. This allows an estimation of the relative value of the unknown bulk solid/liquid distribution coefficient for Hf. DLu/DHf=??? 2.3 holds for most mantle source regions. For garnet to be an important residual mantle phase, it must hold Hf strongly in order to preserve Hf-Nd isotopic relationships. The ancient Hf initials are consistent with only a small proportion of recycled older cratons in new continental crust, and with quasi-continuous, episodic growth of the continental crust with time. However, recycling of crust less than 150 My old cannot realistically be detected using Hf initials. The mantle shows clearly the general positive ??Hf resulting from a residual geochemical state at least back to 2.9 Gy ago, and seems to have repeatedly possessed a similar degree of heterogeneity, rather than a continuously-developing depletion. This is consistent with a complex dynamic disequilibrium model for the creation, maintenance and destruction of heterogeneity in the mantle. ?? 1981 Springer-Verlag.

  17. What Hf isotopes in zircon tell us about crust-mantle evolution

    Science.gov (United States)

    Iizuka, Tsuyoshi; Yamaguchi, Takao; Itano, Keita; Hibiya, Yuki; Suzuki, Kazue

    2017-03-01

    The 176Lu-176Hf radioactive decay system has been widely used to study planetary crust-mantle differentiation. Of considerable utility in this regard is zircon, a resistant mineral that can be precisely dated by the U-Pb chronometer and record its initial Hf isotope composition due to having low Lu/Hf. Here we review zircon U-Pb age and Hf isotopic data mainly obtained over the last two decades and discuss their contributions to our current understanding of crust-mantle evolution, with emphasis on the Lu-Hf isotope composition of the bulk silicate Earth (BSE), early differentiation of the silicate Earth, and the evolution of the continental crust over geologic history. Meteorite zircon encapsulates the most primitive Hf isotope composition of our solar system, which was used to identify chondritic meteorites best representative of the BSE (176Hf/177Hf = 0.282793 ± 0.000011; 176Lu/177Hf = 0.0338 ± 0.0001). Hadean-Eoarchean detrital zircons yield highly unradiogenic Hf isotope compositions relative to the BSE, providing evidence for the development of a geochemically enriched silicate reservoir as early as 4.5 Ga. By combining the Hf and O isotope systematics, we propose that the early enriched silicate reservoir has resided at depth within the Earth rather than near the surface and may represent a fractionated residuum of a magma ocean underlying the proto-crust, like urKREEP beneath the anorthositic crust on the Moon. Detrital zircons from world major rivers potentially provide the most robust Hf isotope record of the preserved granitoid crust on a continental scale, whereas mafic rocks with various emplacement ages offer an opportunity to trace the Hf isotope evolution of juvenile continental crust (from εHf[4.5 Ga] = 0 to εHf[present] = + 13). The river zircon data as compared to the juvenile crust composition highlight that the supercontinent cycle has controlled the evolution of the continental crust by regulating the rates of crustal generation and intra

  18. The industrial practice and development of flotation column in China

    Energy Technology Data Exchange (ETDEWEB)

    Liu Jiongtian; Zhang Shuangquan [China Univ. of Mining and Technology, Xuzhou (China). Dept. of Energy Utilization and Chemical Engineering

    1997-12-31

    This paper reviewed the developing course of the flotation column since the 1960`s in China. Based on the practical data from several coal preparation plants, two types of flotation columns (the pressure aerated column and the jetting-cyclone column) were compared by their operation, performance and the reasons why they succeeded in the coal industry in China. The paper points out that the flotation column has come into commercial use and has good application prospects in China.

  19. Similar crustal evolution in the western units of the Adrar Souttouf Massif (Moroccan Sahara) and the Avalonian terranes: Insights from Hf isotope data

    Science.gov (United States)

    Gärtner, Andreas; Villeneuve, Michel; Linnemann, Ulf; Gerdes, Axel; Youbi, Nasrrddine; Hofmann, Mandy

    2016-06-01

    The Adrar Souttouf Massif is located at the western margin of the West African Craton and consists of several NNE-SSW trending units. Of them, the two westernmost have been interpreted to be linked with the Avalonian terrane assemblage and Meguma, respectively. New Hf isotopic data corroborates the Avalon correlation but has no impact one way or another on the possible Meguma connection, as there is no Hf data available from the latter. The obtained pattern of εHf(t) values vs. zircon age of the likely Avalonia related Oued Togba unit is similar to published data from Avalonia. Zircons of this unit show characteristic patterns of crustal mixing at 0.7 to 1.3 Ga and 1.75 to 2.25 Ga, while juvenile crust was likely formed around 0.6 to 0.75 Ga, from 1.2 to 2.2 Ga, and between 2.5 and 3.2 Ga. The zircons of the Sebkha Gezmayet unit reveal crustal mixing for the entire Palaeozoic and Neoproterozoic, from 2.05 to 2.11 Ga, and 2.8 to 2.9 Ga. Juvenile crust formation is interpreted to have occurred from 0.5 to 0.7 Ga, at around 2.1 Ga, and at ca. 2.9 Ga. As Mesoproterozoic zircons are abundant in the likely Avalonia-like Oued Togba unit, but uncommon at the West African Craton, their origin has to be found elsewhere. A comparison of available Hf data from Amazonia and Baltica, the two potential source cratons of Avalonia, shows similarities but is hampered by the lack of available data from Amazonia. Finally, a few grains from both units have Eoarchaean model ages. Among similar grains from other peri-Gondwanan terranes, they give indication of partial recycling of Eoarchaean crust in the vicinity of the northwestern West African Craton.

  20. Influence of Hf contents on interface state properties in a-HfInZnO thin-film transistors with SiNx/SiOx gate dielectrics

    Science.gov (United States)

    Choi, Hyun-Sik; Jeon, Sanghun; Kim, Hojung; Shin, Jaikwang; Kim, Changjung; Chung, U.-In

    2011-10-01

    We evaluated the interface properties of amorphous hafnium-indium-zinc-oxide (a-HIZO) thin-film transistors (TFTs) with respect to various Hf contents. To this end, the subthreshold swing and the low-frequency noise (LFN) of the a-HIZO TFTs were measured and compared. From LFNs providing more accurate information, we quantitatively analyzed the interface trap densities and found that they decrease with increasing Hf contents. Although the acceptor-like tail state densities in bulk channel increase with Hf contents, higher Hf contents show lower threshold voltage shift under bias stress, implying that reliability characteristics of a-HIZO TFTs are more sensitive to interface quality rather than bulk property.

  1. A halo model for cosmological neutral hydrogen : abundances and clustering

    CERN Document Server

    Padmanabhan, Hamsa; Amara, Adam

    2016-01-01

    We extend the results of previous analyses towards constraining the abundance and clustering of post-reionization ($z \\sim 0-5$) neutral hydrogen (HI) systems using a halo model framework. We work with a comprehensive HI dataset including the small-scale clustering, column density and mass function of HI galaxies at low redshifts, intensity mapping measurements at intermediate redshifts and the UV/optical observations of Damped Lyman Alpha (DLA) systems at higher redshifts. We use a Markov Chain Monte Carlo (MCMC) approach to constrain the parameters of the best-fitting models, both for the HI-halo mass relation and the HI radial density profile. We find that a radial exponential profile results in a good fit to the low-redshift HI observations, including the clustering and the column density distribution. The form of the profile is also found to match the high-redshift DLA observations, when used in combination with a three-parameter HI-halo mass relation and a redshift evolution in the HI concentration. The...

  2. Reducing axial mixing in flotation columns

    Energy Technology Data Exchange (ETDEWEB)

    Al Taweel, A.M.; Ramadan, A.M. [Technical Univ. of Nova Scotia, Halifax (Canada). Chemical Engineering Dept.; Moharam, M.R.; Hassan, T.A. [Al Azhar Univ., Cairo (Egypt); El Mofty, S.M. [Cairo Univ., Giza (Egypt)

    1995-10-01

    The axial mixing characteristics of a pilot-scale flotation column were investigated with the objective of identifying means to mitigate the extent of axial mixing that adversely affects its grade/recovery performance. A wide range of design and operating conditions wa investigated and the experimental results, obtained using the dynamic response method, were analyzed using three axial mixing models. The dynamic response of the column can best be described using the axial dispersion model. The results obtained suggest that the value of the axial dispersion coefficient, E{sub L}, can be significantly reduced by judicial selection of hydrodynamic conditions and/or the use of column inserts that suppress the onset of hydrodynamic instabilities inherent to the operation of conventional flotation columns. Up to 40% reduction in the value of E{sub L} was thus obtained by using spargers that produce more uniform bubble sizes, while up to 30% reductions were obtained by controlling the residual frother concentration. 33 refs., 7 figs.

  3. On Row Rank Equal Column Rank

    Science.gov (United States)

    Khalili, Parviz

    2009-01-01

    We will prove a well-known theorem in Linear Algebra, that is, for any "m x n" matrix the dimension of row space and column space are the same. The proof is based on the subject of "elementary matrices" and "reduced row-echelon" form of a matrix.

  4. Robust Geometric Control of a Distillation Column

    DEFF Research Database (Denmark)

    Kymmel, Mogens; Andersen, Henrik Weisberg

    1987-01-01

    A frequency domain method, which makes it possible to adjust multivariable controllers with respect to both nominal performance and robustness, is presented. The basic idea in the approach is that the designer assigns objectives such as steady-state tracking, maximum resonance peaks, bandwidth, m...... is used to examine and improve geometric control of a binary distillation column....

  5. The Special Column of Primate Behavior

    Institute of Scientific and Technical Information of China (English)

    Baoguo LI; Guest Editor

    2010-01-01

    @@ It is a long-term policy to publish SPECIAL COLUMNs in Current Zoology, and I am delighted that the journal is publishing this special colunm devoted to the topic of Primate Behavior. The eight papers in this seetion present significant new data and synthesize these findings with existing information on sexual selection of human-being and behaviors of living primates.

  6. Thermal Analysis of LANL Ion Exchange Column

    Energy Technology Data Exchange (ETDEWEB)

    Laurinat, J.E.

    1999-06-16

    This document reports results from an ion exchange column heat transfer analysis requested by Los Alamos National Laboratory (LANL). The object of the analysis is to demonstrate that the decay heat from the Pu-238 will not cause resin bed temperatures to increase to a level where the resin significantly degrades.

  7. "Dry-column" chromatography of plant pigments

    Science.gov (United States)

    Woeller, F. H.; Lehwalt, M. F.; Oyama, V. I.

    1973-01-01

    Separation of plant pigments which can be accomplished on thin-layer silica plates with mixture of petroleum ether, halocarbon, acetone, and polar solvent can be readily translated into dry-column technique that yields reproducible chromatograms after elution in fashion of liquid chromatography with fluorimeter as detector. Best solvent system was found to be mixture of petroleum ether, dichloromethane, acetone, and ethyl acetate.

  8. WATER COLUMN DATA AND SPECTRAL IRRADIANCE MODEL

    Science.gov (United States)

    Water samples collected monthly, for 18 months, from six sites in the Laguna Madre were analyzed to identify and quantify phytopigments using High Performance Liquid Chromatography (HPLC). In addition, water column pigment and nutrient data were acquired at 12 stations in Upper ...

  9. Flexural buckling of fire exposed aluminium columns

    NARCIS (Netherlands)

    Maljaars, J.; Twilt, L.; Soetens, F.

    2009-01-01

    In order to study buckling of fire exposed aluminium columns, a finite element model is developed. The results of this model are verified with experiments. Based on a parametric study with the finite element model, it is concluded that the simple calculation model for flexural buckling of fire expos

  10. Contexts for Column Addition and Subtraction

    Science.gov (United States)

    Lopez Fernandez, Jorge M.; Velazquez Estrella, Aileen

    2011-01-01

    In this article, the authors discuss their approach to column addition and subtraction algorithms. Adapting an original idea of Paul Cobb and Erna Yackel's from "A Contextual Investigation of Three-Digit Addition and Subtraction" related to packing and unpacking candy in a candy factory, the authors provided an analogous context by…

  11. Contexts for Column Addition and Subtraction

    Science.gov (United States)

    Lopez Fernandez, Jorge M.; Velazquez Estrella, Aileen

    2011-01-01

    In this article, the authors discuss their approach to column addition and subtraction algorithms. Adapting an original idea of Paul Cobb and Erna Yackel's from "A Contextual Investigation of Three-Digit Addition and Subtraction" related to packing and unpacking candy in a candy factory, the authors provided an analogous context by…

  12. Air sensitivity of MoS2, MoSe2, MoTe2, HfS2, and HfSe2

    Science.gov (United States)

    Mirabelli, Gioele; McGeough, Conor; Schmidt, Michael; McCarthy, Eoin K.; Monaghan, Scott; Povey, Ian M.; McCarthy, Melissa; Gity, Farzan; Nagle, Roger; Hughes, Greg; Cafolla, Attilio; Hurley, Paul K.; Duffy, Ray

    2016-09-01

    A surface sensitivity study was performed on different transition-metal dichalcogenides (TMDs) under ambient conditions in order to understand which material is the most suitable for future device applications. Initially, Atomic Force Microscopy and Scanning Electron Microscopy studies were carried out over a period of 27 days on mechanically exfoliated flakes of 5 different TMDs, namely, MoS2, MoSe2, MoTe2, HfS2, and HfSe2. The most reactive were MoTe2 and HfSe2. HfSe2, in particular, showed surface protrusions after ambient exposure, reaching a height and width of approximately 60 nm after a single day. This study was later supplemented by Transmission Electron Microscopy (TEM) cross-sectional analysis, which showed hemispherical-shaped surface blisters that are amorphous in nature, approximately 180-240 nm tall and 420-540 nm wide, after 5 months of air exposure, as well as surface deformation in regions between these structures, related to surface oxidation. An X-ray photoelectron spectroscopy study of atmosphere exposed HfSe2 was conducted over various time scales, which indicated that the Hf undergoes a preferential reaction with oxygen as compared to the Se. Energy-Dispersive X-Ray Spectroscopy showed that the blisters are Se-rich; thus, it is theorised that HfO2 forms when the HfSe2 reacts in ambient, which in turn causes the Se atoms to be aggregated at the surface in the form of blisters. Overall, it is evident that air contact drastically affects the structural properties of TMD materials. This issue poses one of the biggest challenges for future TMD-based devices and technologies.

  13. Origin of Cosmic Chemical Abundances

    CERN Document Server

    Maio, Umberto

    2015-01-01

    Cosmological N-body hydrodynamic computations following atomic and molecular chemistry (e$^-$, H, H$^+$, H$^-$, He, He$^+$, He$^{++}$, D, D$^+$, H$_2$, H$_2^+$, HD, HeH$^+$), gas cooling, star formation and production of heavy elements (C, N, O, Ne, Mg, Si, S, Ca, Fe, etc.) from stars covering a range of mass and metallicity are used to explore the origin of several chemical abundance patterns and to study both the metal and molecular content during simulated galaxy assembly. The resulting trends show a remarkable similarity to up-to-date observations of the most metal-poor damped Lyman-$\\alpha$ absorbers at redshift $z\\gtrsim 2$. These exhibit a transient nature and represent collapsing gaseous structures captured while cooling is becoming effective in lowering the temperature below $\\sim 10^4\\,\\rm K$, before they are disrupted by episodes of star formation or tidal effects. Our theoretical results agree with the available data for typical elemental ratios, such as [C/O], [Si/Fe], [O/Fe], [Si/O], [Fe/H], [O/...

  14. EURObservational Research Programme : The Heart Failure Pilot Survey (ESC-HF Pilot)

    NARCIS (Netherlands)

    Maggioni, Aldo P.; Dahlstrom, Ulf; Filippatos, Gerasimos; Chioncel, Ovidiu; Crespo Leiro, Marisa; Drozdz, Jaroslaw; Fruhwald, Friedrich; Gullestad, Lars; Logeart, Damien; Metra, Marco; Parissis, John; Persson, Hans; Ponikowski, Piotr; Rauchhaus, Mathias; Voors, Adriaan A.; Nielsen, Olav Wendelboe; Zannad, Faiez; Tavazzi, Luigi

    2010-01-01

    The primary objective of the new ESC-HF Pilot Survey was to describe the clinical epidemiology of outpatients and inpatients with heart failure (HF) and the diagnostic/therapeutic processes applied across 12 participating European countries. This pilot study was specifically aimed at validating the

  15. EURObservational Research Programme: the Heart Failure Pilot Survey (ESC-HF Pilot)

    DEFF Research Database (Denmark)

    Maggioni, Aldo P; Dahlström, Ulf; Filippatos, Gerasimos;

    2010-01-01

    The primary objective of the new ESC-HF Pilot Survey was to describe the clinical epidemiology of outpatients and inpatients with heart failure (HF) and the diagnostic/therapeutic processes applied across 12 participating European countries. This pilot study was specifically aimed at validating...... the structure, performance, and quality of the data set, for continuing the survey into a permanent registry....

  16. Effects of sol aging on resistive switching behaviors of HfO{sub x} resistive memories

    Energy Technology Data Exchange (ETDEWEB)

    Hsu, Chih-Chieh, E-mail: cchsu@yuntech.edu.tw [Graduate School of Engineering Science and Technology, National Yunlin University of Science and Technology, Douliu 64002, Taiwan, ROC (China); Department of Electronic Engineering, National Yunlin University of Science and Technology, Douliu 64002, Taiwan, ROC (China); Graduate School of Electronic Engineering, National Yunlin University of Science and Technology, Douliu 64002, Taiwan, ROC (China); Sun, Jhen-Kai; Tsao, Che-Chang; Chen, Yu-Ting [Graduate School of Electronic Engineering, National Yunlin University of Science and Technology, Douliu 64002, Taiwan, ROC (China)

    2017-03-01

    This work investigates effects of long-term sol-aging time on sol-gel HfO{sub x} resistive random access memories (RRAMs). A nontoxic solvent of ethanol is used to replace toxic 2-methoxyethanol, which is usually used in sol-gel processes. The top electrodes are fabricated by pressing indium balls onto the HfO{sub x} surface rather than by using conventional sputtering or evaporation processes. The maximum process temperature is limited to be 100 ℃. Therefore, influences of plasma and high temperature on HfO{sub x} film can be avoided. Under this circumstance, effects of sol aging time on the HfO{sub x} films can be more clearly studied. The current conduction mechanisms in low and high electric regions of the HfO{sub x} RRAM are found to be dominated by Ohmic conduction and trap-filled space charge limited conduction (TF-SCLC), respectively. When the sol aging time increases, the resistive switching characteristic of the HfO{sub x} layer becomes unstable and the transition voltage from Ohmic conduction to TF-SCLC is also increased. This suggests that an exceedingly long aging time will give a HfO{sub x} film with more defect states. The XPS results are consistent with FTIR analysis and they can further explain the unstable HfO{sub x} resistive switching characteristic induced by sol aging.

  17. The effects of composition on mechanical properties of W-4Re-Hf-C alloys

    Science.gov (United States)

    Witzke, W. R.

    1974-01-01

    Studies were made of the effects of alloy composition on the mechanical behavior of as-worked W-4Re-Hf-C alloys containing up to about 0.8 mol % Hfc. Extracted second-phase particles were analyzed and related to alloy composition and creep strength. While strengthening is attributed to HfC particles, the presence of excess hafnium or carbon (above the calculated amounts for stoichiometric HfC) in swaged W-4Re-Hf-C alloys generally causes a reduction of the high-temperature (1930 C) tensile strength; maximum creep strength is, however, indicated for alloys with a slight (about 0.05 to 0.1 at. %) excess of hafnium. Particle strengthening is reduced by WC in solid solution with HfC for allow compositions with an excess of carbon. The low-temperature ductility of worked W-4Re-Hf-C alloys appears to be far more dependent on the amount of excess C or Hf present than on the HfC particle content in the range studies.

  18. First results on the sorption behaviour of Rutherfordium from HCl/HF containing aqueous solution

    Energy Technology Data Exchange (ETDEWEB)

    Schumann, D.; Nitsche, H. [Technische Univ. Dresden (Germany); Taut, S. [Forschungszentrum Rossendorf e.V. (FZR), Dresden (Germany); Jost, D.T.; Gaeggeler, H.W. [Paul Scherrer Inst. (PSI), Villigen (Switzerland); Yakushev, A.B.; Buklanov, G.V.; Domanov, V.P.; Lien Din Thi [Joint Inst. for Nuclear Research, Dubna (Russian Federation); Kubica, B.; Misiak, R.; Szeglowski, Z. [NINP Cracow (Poland)

    1997-09-01

    Rutherfordium shows strong sorption on the cation exchanger DOWEX 50x8 at a concentration of 0.1 M HCl/10{sup -2} M HF. This shows that Rf behaves under these conditions differently from Hf and Zr and more like Th under these conditions. (author) 1 fig., 5 refs.

  19. Effects of sol aging on resistive switching behaviors of HfOx resistive memories

    Science.gov (United States)

    Hsu, Chih-Chieh; Sun, Jhen-Kai; Tsao, Che-Chang; Chen, Yu-Ting

    2017-03-01

    This work investigates effects of long-term sol-aging time on sol-gel HfOx resistive random access memories (RRAMs). A nontoxic solvent of ethanol is used to replace toxic 2-methoxyethanol, which is usually used in sol-gel processes. The top electrodes are fabricated by pressing indium balls onto the HfOx surface rather than by using conventional sputtering or evaporation processes. The maximum process temperature is limited to be 100 ℃. Therefore, influences of plasma and high temperature on HfOx film can be avoided. Under this circumstance, effects of sol aging time on the HfOx films can be more clearly studied. The current conduction mechanisms in low and high electric regions of the HfOx RRAM are found to be dominated by Ohmic conduction and trap-filled space charge limited conduction (TF-SCLC), respectively. When the sol aging time increases, the resistive switching characteristic of the HfOx layer becomes unstable and the transition voltage from Ohmic conduction to TF-SCLC is also increased. This suggests that an exceedingly long aging time will give a HfOx film with more defect states. The XPS results are consistent with FTIR analysis and they can further explain the unstable HfOx resistive switching characteristic induced by sol aging.

  20. The Modulation of Ionospheric Alfven Resonator on Heating HF Waves and the Doppler Effect

    Institute of Scientific and Technical Information of China (English)

    NiBin-bin; ZhaoZheng-yu; XieShu-guo

    2003-01-01

    The propagation of HF waves in IAR can produce many nonlinear effects, including the modulation effect of IAR on HF waves and the Doppler effect. To start with the dependence of the ionospheric electron temperature varia-tions on the Alfven resonant field, We discuss the mechanism of the modulation effect and lucubrate possible reasons for the Doppler effect. The results show that the Alfven resonant field can have an observable modulation effect on HF waves while its mechanism is quite different from that of Schumann resonant field on HF waves. The depth of modulation of IAR on HF waves has a quasi-quadratic relation with the Alfven field, which directly inspires the formation of cross-spectrum between ULF waves and HF waves and results in spectral peaks at some gyro-frequencies of IAR. With respect to the Doppler effect during the propagation of HF waves in IAR, it is mainly caused by the motion of the high-speed flyer and the drifting electrons and the frequency shift from the phase vari-ation of the reflected waves can be neglected when the frequency of HF incident wave is high enough.

  1. New PWM method and commutation strategy for HF-link converters for fuel cells and photovoltaics

    DEFF Research Database (Denmark)

    Ljusev, Petar; Andersen, Michael Andreas E.

    2005-01-01

    This paper presents a new PWM method and commutation strategy for HF-link converters, which leads to safe commutation of the load current in the output bidirectional bridge. The proposed implementation is independent of the particular HF-link converter topology and bidirectional switch selection...

  2. The first HF table, after heat treatment and ready to be machined in HEPCO, Arak (IRAN)

    CERN Multimedia

    Tiziano Camporesi

    2003-01-01

    The first HF support table 'load' tested by the team of people who have contributed to it from design to welding. This table will support the 240 tons of 1 HF detector and will integrate the raisers which will push it up to the beam line level. It is the first Iranian contribution to an HEP experiment.

  3. 47 CFR 73.758 - System specifications for digitally modulated emissions in the HF broadcasting service.

    Science.gov (United States)

    2010-10-01

    ... emissions in the HF broadcasting service. 73.758 Section 73.758 Telecommunication FEDERAL COMMUNICATIONS... § 73.758 System specifications for digitally modulated emissions in the HF broadcasting service. (a... digital audio broadcasting and datacasting are authorized. The RF requirements for the DRM system...

  4. Computed tomographic coronary angiography for patients with heart failure (CTA-HF): a randomized controlled trial (IMAGE HF Project 1-C).

    Science.gov (United States)

    Chow, Benjamin J W; Green, Rachel E; Coyle, Doug; Laine, Mika; Hanninen, Helena; Leskinen, Hanna; Rajda, Miroslav; Larose, Eric; Hartikainen, Juha; Hedman, Marja; Mielniczuk, Lisa; O'Meara, Eileen; deKemp, Robert A; Klein, Ran; Paterson, Ian; White, James A; Yla-Herttuala, Seppo; Leber, Alex; Tandon, Vikas; Lee, Ting; Al-Hesayen, Abdul; Hessian, Renee; Dowsley, Taylor; Kass, Malek; Kelly, Cathy; Garrard, Linda; Tardif, Jean-Claude; Knuuti, Juhani; Beanlands, Rob S; Wells, George A

    2013-12-26

    The prevalence of heart failure (HF) is rising in industrialized and developing countries. Though invasive coronary angiography (ICA) remains the gold standard for anatomical assessment of coronary artery disease in HF patients, alternatives are being sought. Computed tomographic coronary angiography (CTA) has emerged as an accurate non-invasive diagnostic tool for coronary artery disease (CAD) and has been demonstrated to have prognostic value. Whether or not CTA can be used in HF patients is unknown. Acknowledging the aging population, the growing prevalence of HF and the increasing financial burden of healthcare, we need to identify non-invasive diagnostic tests that are available, safe, accurate and cost-effective. The proposed study aims to provide insight into the efficacy of CTA in HF patients. A multicenter randomized controlled trial will enroll 250 HF patients requiring coronary anatomical definition. Enrolled patients will be randomized to either CTA or ICA (n = 125 per group) as the first test to define coronary anatomy. The primary outcomes will be collected to determine downstream resource utilization. Secondary outcomes will include the composite clinical events and major adverse cardiac events. In addition, the accuracy of CTA for detecting coronary anatomy and obstruction will be assessed in patients who subsequently undergo both CTA and ICA. It is expected that CTA will be a more cost-effective strategy for diagnosis: yielding similar outcomes with fewer procedural risks and improved resource utilization. ClinicalTrials.gov, NCT01283659. Team grant #CIF 99470.

  5. Signal processing technique for randomly discontinuous spectra HF radar waveforms

    Institute of Scientific and Technical Information of China (English)

    张东坡; 刘兴钊

    2004-01-01

    A major problem with all high frequency (HF) radars is a relatively poor range resolution available due to many interference sources. To avoid the interferences in frequency domain and operate with wideband, the randomly discontinuous spectra (RDS) signal is employed. However, it results in high range sidelobes when matching the reflected echo, which is much more difficult for target detection. A new signal processing technique that is radically different from the conventional technique to lower range sidelobes is introduced. This method is based on suppressing the selfclutter of the radar range ambiguity function (AF) by mismatched filtering. An effective algorithm is adopted to solve the filter coefficients. Simulation results show that the peak sidelobe level can be reduced to -30dB and the achievable system bandwidth is about 400KHz. The technique is adaptable to practical radar systems and applicable for other realtime signal processing.

  6. Modification of polarization filtering technique in HF ground wave radar

    Institute of Scientific and Technical Information of China (English)

    Zhang Guoyi; Tan Zhongji; Wang Jiantao

    2006-01-01

    The polarization filter using three orthogonal linear polarization antennas can suppress more disturbances than the polarization filter using two orthogonal linear polarization antennas in HF ground wave radar. But the algorithm of the threedimension filter is relatively complicated and not suitable for real-time processing. It can't use linear and nonlinear polarization vector translation technique directly. A modified polarization filter which is simple and has same suppressing ability as the three-dimension polarization filter is given. It only has half parameters of the primary one. Some problems about estimation of polarization parameters and selection of disturbances are discussed. A method of holding the phase of radar backscatter signal constantly is put forward so that unstationary disturbance signal can be processed.

  7. Toward an european Med HF-radar coastal monitoring

    Science.gov (United States)

    Molcard, A.; Fraunie, P.

    2010-12-01

    The monitoring of coastal areas through HF radar is developping in the european Mediterranean coasts, through national and international projects. Surface current maps may be used for process studies, forecast correction through assimilation, or for practical applications in transport studies (jellyfish, oil-spill, search-and-rescue operations). Results of radar campaigns in the North-western Mediterranean (evidence of mesoscale eddy in the Gulf of Lions and identification of dynamical structures by FSLE in the Ligurian Sea) are shown, as well as techniques for current reconstruction using a single site. A new inter-regional european project started in summer 2010, regrouping 5 countries for an integrated oil-spill coastal awarness network is presented.

  8. High frequency (hourly) variation in vertical distribution and abundance of meroplanktonic larvae in nearshore waters during strong internal tidal forcing

    Science.gov (United States)

    Liévana MacTavish, A.; Ladah, L. B.; Lavín, M. F.; Filonov, A.; Tapia, Fabian J.; Leichter, J.

    2016-04-01

    We related the vertical distribution and abundance of nearshore meroplankton at hourly time scales with internal tidal wave events. We proposed that significant changes in plankter abundance would occur across internal tidal fronts, and that surface and bottom strata would respond in opposite fashions. First-mode internal tidal bores propagating in the alongshore direction were detected in water-column currents and baroclinic temperature changes. Surface and bottom currents always flowed in opposite directions, and abrupt flow reversals coincided with large temperature changes during arrival of bores. Crab zoeae and barnacle cyprids were more abundant in the bottom strata, whereas barnacle nauplii showed the opposite pattern. Significant changes in vertical distribution and abundance of target meroplankters occurred across internal tidal fronts, especially for crabs at depth, with surface and bottom organisms responding in opposite fashions. Changes in plankter abundance were significantly correlated with current flows in the strata where they were most abundant. The manner in which plankters were affected (increasing or decreasing abundance) appeared to be modulated by their vertical position within the water column. The significant differences found at the high frequencies of this study, maintained across sampling days, suggest that nearshore meroplankton populations may have greater and more consistent temporal and vertical variability than previously considered.

  9. Telemonitoring Adherence to Medications in Heart Failure Patients (TEAM-HF): A Pilot Randomized Clinical Trial.

    Science.gov (United States)

    Gallagher, Benjamin D; Moise, Nathalie; Haerizadeh, Mytra; Ye, Siqin; Medina, Vivian; Kronish, Ian M

    2017-04-01

    Medication nonadherence contributes to hospitalizations in recently discharged patients with heart failure (HF). We aimed to test the feasibility of telemonitoring medication adherence in patients with HF. We randomized 40 patients (1:1) hospitalized for HF to 30 days of loop diuretic adherence monitoring with telephonic support or to passive adherence monitoring alone. Eighty-three percent of eligible patients agreed to participate. The median age of patients was 64 years, 25% were female, and 45% were Hispanic. Overall, 67% of patients were nonadherent (percentage of days that the correct number of doses were taken telemonitoring was acceptable to most patients with HF. Diuretic nonadherence was common even when patients knew they were being monitored. Future studies should assess whether adherence telemonitoring can improve adherence and reduce readmissions among patients with HF. Copyright © 2016 Elsevier Inc. All rights reserved.

  10. The electronic structure of HfF5- and WF5-

    Science.gov (United States)

    Chen, Hongshan; Andersson, Pontus; Lindahl, Anton O.; Hanstorp, Dag

    2011-08-01

    The electronic structure of HfF5-, WF5- and the related species HfF n and WF n is studied using ab initio methods. Computation reveals that the hafnium fluorides are much more stable than the corresponding tungsten fluorides. The detachment energy of HfF5- is 8.8 eV, whereas the corresponding quantity of WF5- is only 3.9 eV. These results show that WF5- can be photodetached while HfF5- is unaffected, and so it is possible by using photodetachment to suppress the interfering isobar 182W in the ion beam of 182Hf. Such information is the precondition for the successful implementation of a future photodetachment process in Accelerator Mass Spectrometry.

  11. Effect of hydrofluoric acid (HF) concentration to pores size diameter of silicon membrane.

    Science.gov (United States)

    Burham, Norhafizah; Hamzah, Azrul Azlan; Majlis, Burhanuddin Yeop

    2014-01-01

    This paper studies parameters which affect the pore size diameter of a silicon membrane. Electrochemical etching is performed in characterise the parameter involved in this process. The parameter has been studied is volume ratio of hydrofluoric acid (HF) and ethanol as an electrolyte aqueous for electrochemical etch. This electrolyte aqueous solution has been mixed between HF and ethanol with volume ratio 3:7, 5:5, 7:3 and 9:1. As a result, the higher volume of HF in this electrolyte gives the smallest pore size diameter compared to the lower volume of HF. These samples have been dipped into HF and ethanol electrolyte aqueous with supplied 25 mA/cm2 current density for 20, 30, 40, and 50 minutes. The samples will inspect under Scanning Electron Microscope (SEM) to execute the pore formations on silicon membrane surface.

  12. Suspended HfO{sub 2} photonic crystal slab on III-nitride/Si platform

    Energy Technology Data Exchange (ETDEWEB)

    Wang, Yongjin; Feng, Jiao; Cao, Ziping; Zhu, Hongbo [Nanjing University of Posts and Telecommunications, Grueenberg Research Centre, Nanjing, Jiang-Su (China)

    2014-06-15

    We present here the fabrication of suspended hafnium oxide (HfO{sub 2}) photonic crystal slab on a III-nitride/Si platform. The calculations are performed to model the suspended HfO{sub 2} photonic crystal slab. Aluminum nitride (AlN) film is employed as the sacrificial layer to form air gap. Photonic crystal patterns are defined by electron beam lithography and transferred into HfO{sub 2} film, and suspended HfO{sub 2} photonic crystal slab is achieved on a III-nitride/Si platform through wet-etching of AlN layer in the alkaline solution. The method is promising for the fabrication of suspended HfO{sub 2} nanostructures incorporating into a III-nitride/Si platform, or acting as the template for epitaxial growth of III-nitride materials. (orig.)

  13. Crystal structure of Si-doped HfO{sub 2}

    Energy Technology Data Exchange (ETDEWEB)

    Zhao, Lili [Department of Materials Science and Engineering, North Carolina State University, Raleigh, North Carolina 27695 (United States); School of Information Science and Technology, Northwest University, Xi' an 710127 (China); Department of Materials Science and Engineering, University of Florida, Gainesville, Florida 32611 (United States); Nelson, Matthew; Fancher, Chris M. [Department of Materials Science and Engineering, North Carolina State University, Raleigh, North Carolina 27695 (United States); Aldridge, Henry [Department of Materials Science and Engineering, University of Florida, Gainesville, Florida 32611 (United States); Iamsasri, Thanakorn; Forrester, Jennifer S.; Jones, Jacob L., E-mail: jacobjones@ncsu.edu [Department of Materials Science and Engineering, North Carolina State University, Raleigh, North Carolina 27695 (United States); Department of Materials Science and Engineering, University of Florida, Gainesville, Florida 32611 (United States); Nishida, Toshikazu [Department of Electrical and Computer Engineering, University of Florida, Gainesville, Florida 32611 (United States); Moghaddam, Saeed [Department of Mechanical and Aerospace Engineering, University of Florida, Gainesville, Florida 32611 (United States)

    2014-01-21

    Si-doped HfO{sub 2} was prepared by solid state synthesis of the starting oxides. Using Rietveld refinement of high resolution X-ray diffraction patterns, a substitutional limit of Si in HfO{sub 2} was determined as less than 9 at. %. A second phase was identified as Cristobalite (SiO{sub 2}) rather than HfSiO{sub 4}, the latter of which would be expected from existing SiO{sub 2}-HfO{sub 2} phase diagrams. Crystallographic refinement with increased Si-dopant concentration in monoclinic HfO{sub 2} shows that c/b increases, while β decreases. The spontaneous strain, which characterizes the ferroelastic distortion of the unit cell, was calculated and shown to decrease with increasing Si substitution.

  14. Tsunami Arrival Detection with High Frequency (HF Radar

    Directory of Open Access Journals (Sweden)

    Donald Barrick

    2012-05-01

    Full Text Available Quantitative real-time observations of a tsunami have been limited to deep-water, pressure-sensor observations of changes in the sea surface elevation and observations of sea level fluctuations at the coast, which are essentially point measurements. Constrained by these data, models have been used for predictions and warning of the arrival of a tsunami, but to date no system exists for local detection of an actual incoming wave with a significant warning capability. Networks of coastal high frequency (HF-radars are now routinely observing surface currents in many countries. We report here on an empirical method for the detection of the initial arrival of a tsunami, and demonstrate its use with results from data measured by fourteen HF radar sites in Japan and USA following the magnitude 9.0 earthquake off Sendai, Japan, on 11 March 2011. The distance offshore at which the tsunami can be detected, and hence the warning time provided, depends on the bathymetry: the wider the shallow continental shelf, the greater this time. We compare arrival times at the radars with those measured by neighboring tide gauges. Arrival times measured by the radars preceded those at neighboring tide gauges by an average of 19 min (Japan and 15 min (USA The initial water-height increase due to the tsunami as measured by the tide gauges was moderate, ranging from 0.3 to 2 m. Thus it appears possible to detect even moderate tsunamis using this method. Larger tsunamis could obviously be detected further from the coast. We find that tsunami arrival within the radar coverage area can be announced 8 min (i.e., twice the radar spectral time resolution after its first appearance. This can provide advance warning of the tsunami approach to the coastline locations.

  15. New Adaptive Data Transmission Scheme Over HF Radio

    Directory of Open Access Journals (Sweden)

    Adil H. Ahmad

    2008-01-01

    Full Text Available Acceptable Bit Error rate can be maintained by adapting some of the design parameters such as modulation, symbol rate, constellation size, and transmit power according to the channel state.An estimate of HF propagation effects can be used to design an adaptive data transmission system over HF link. The proposed system combines the well known Automatic Link Establishment (ALE together with variable rate transmission system. The standard ALE is modified to suite the required goal of selecting the best carrier frequency (channel for a given transmission. This is based on measuring SINAD (Signal plus Noise plus Distortion to Noise plus Distortion, RSL (Received Signal Level, multipath phase distortion and BER (Bit Error Rate for each channel in the frequency list. Channel condition evaluation is done by two arrangements. In the first an FFT analysis is used where a pilot signal is transmitted over the channel, while the data itself is used in the second arrangement. Passive channel assessment is used to avoid bad channels hence limiting the frequency pool size to be used in the point to point communication and the time required for scanning and linking. An exchange of channel information between the transmitting and receiving stations is considered to select the modulation scheme for transmission. Mainly MPSK and MFSK are considered with different levels giving different data rate according to the channel condition. The results of the computer simulation have shown that when transmitting at a fixed channel symbol rate of 1200 symbol/sec, the information rate ranges from 2400 bps using 4FSK up to 3600 bps using 8PSK for SNR ranges from 11dB up to 26dB.

  16. Effect of sulfate fertilization on soil biota in grassland columns

    Science.gov (United States)

    Ikoyi, Israel; Donohue, John; Fowler, Andrew; Schmalenberger, Achim

    2017-04-01

    Sulfur (S) is an important macronutrient element in plant nutrition as a component of protein, enzymes, enzyme cofactors as well as being the major constituent of the amino acids cysteine and methionine. Organically bound S is the predominant form of S in the soil constituting up to 95% of S in agricultural soils. The most important form of S in terms of plant nutrition is inorganic sulfate which forms only about 5% of the total soil S content. Air pollution was the major source of S (as SO2) for plants, with up to 80% of the S obtained from this source. However, common effects of S limitation on crops such as chlorosis, yield reduction, and decrease in crop quality are becoming increasingly evident as atmospheric S supply has decreased in recent years. Recent research has shown that organically-bound S in soils is also plant-bioavailable, likely due to interconversion of organic S forms to inorganic sulfate by soil microbes. In this study, soil columns were setup in a greenhouse using moderate S (equivalent to Wisconsin S soil availability index of below 30) soils. The columns were planted with Lolium perenne and fertilized with 0 (control), 5 (low), 10 (medium) and 20 (high) kg/ha sulfate S alongside a full complement of other nutrients. Results after 14 weeks of management show a significant decrease (Pfertilization. In addition, soil from the top 20 cm of the column had significantly higher sulfatase activity compared to the bottom 20 cm. The medium and high S treatments had significantly higher grass dry matter yield compared to the control and low S treatments. All S treatments significantly shifted the bacterial community structure compared to the control. Overall, our preliminary results suggest that applying 5 kg/ ha S had similar effects on the soil biota as the control while the application of medium and high S had similar effects on most parameters. Moreover, this study has shown that S should not be overlooked in grassland nutrition as is often the

  17. Composite support column assembly for offshore drilling and production platforms

    Energy Technology Data Exchange (ETDEWEB)

    Pierce, R.H.

    1989-04-18

    This patent describes a support column assembly for an offshore drilling and/or production comprising: means for anchoring the column assembly on the seabed; an elongated cylindrical support column including at least one generally cylindrical column member having a cylindrical wall formed of a composite of elongated filaments of at least one of carbon and boron bonded in a resin matrix, the support column including a plurality of the column members coupled end to end by coupling means at opposite ends of the column members, the coupling means including a plurality of radially project pins for coupling the composite wall to a coupling member interposed between the column members, respectively; and means for connecting the column to a platform for transmitting platform loads between the platform and the anchor means.

  18. The Thermodynamic Characterization of ZrCo–H, HfCo−H, HfNi−H and Zr{sub 1–x}HfxNi(Co) Alloy–H Systems

    Energy Technology Data Exchange (ETDEWEB)

    Flanagan, Ted B., E-mail: ted.flanagan@uvm.edu; Noh, Hak; Luo, Suifang

    2016-08-25

    ZrCo and HfCo intermetallic compounds have the same cubic (CsCl-type) structure and their ternary (Zr{sub 1−x}Hf{sub x})Co alloys are also cubic. ZrNi and HfNi intermetallic compounds have the orthorhombic structure (CrB-type) and the ternary (Zr{sub 1−x}Hf{sub x})Ni alloys also have this structure. Thermodynamic data for hydride formation and decomposition in ZrCo, HfCo and HfNi intermetallic compounds have been determined from reaction calorimetry and from pressure-composition isotherms. Thermodynamic data have been determined for the three ternary alloys: (Zr{sub 0.75}Hf{sub 0.25})Co, (Zr{sub 0.50}Hf{sub 0.50})Co, and (Zr{sub 0.25}Hf{sub 0.75})Co and the four ternary alloys: (Zr{sub 0.875}Hf{sub 0.125})Ni, (Zr{sub 0.75}Hf{sub 0.25})Ni, (Zr{sub 0.50}Hf{sub 0.50})Ni, and (Zr{sub 0.25}Hf{sub 0.75})Ni. This offers the opportunity to learn how the thermodynamic properties of the ternary alloy-H systems change with the stoichiometry of alloys with the same structure. - Highlights: • Calorimetric enthalpies determined for H absorption by ZrCo, HfCo, HfNi are determined. • Ternary alloys, e.g., Zr{sub 1−x}Hf{sub x}Ni, prepared and characterized by x-ray diffraction. • Isotherms for the ternary alloys give thermodynamic parameters for H solution.

  19. Hydrocarbon Reserves: Abundance or Scarcity

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    2005-07-01

    IFP and the OAPEC jointly organize a regular international seminar dealing with world oil-related problems appearing in the news. For the first time, this seminar has been opened to oil and gas company specialists, service companies, research centers and independents. This year's theme concerns oil and gas reserves: are they abundant or are we headed towards the shortages announced by some experts? This theme is especially topical in that: oil and gas currently meet two thirds of world energy needs and almost completely dominate the transport sector; the reserves declared by the OAPEC countries account for nearly half of world reserves; the price of a barrel of oil went through the roof in 2004; world energy demand is growing fast and alternative sources of energy are far from ready to take over from oil and gas in the next few decades. Since the reserves correspond to the volume it is technically and economically viable to produce, the seminar has, of course, dealt with the technical and economic questions that arise in connection with exploration and production, but it has also considered changes in the geopolitical context. Presentations by the leading companies of the OAPEC countries and by the IFP group were completed by presentation from the International Energy Agency (IEA), the United States Geological Survey (USGS), the IHS Energy Group, Total and Gaz de France. This document gathers the transparencies of the following presentations: Hydrocarbon reserves in OAPEC members countries: current and future (M. Al-Lababidi); Non OAPEC liquid reserves and production forecasts (Y. Mathieu); World oil and gas resources and production outlook (K. Chew); Global investments in the upstream (F. Birol); Total's policy in the oil and gas sector (C. de Margerie); Gaz de France's policy in the oil and gas sector (J. Abiteboul); NOC/IOC's opportunities in OPEC countries (I. Sandrea); Relationships between companies, countries and investors: How they may

  20. Single layer of Ge quantum dots in HfO2 for floating gate memory capacitors.

    Science.gov (United States)

    Lepadatu, A M; Palade, C; Slav, A; Maraloiu, A V; Lazanu, S; Stoica, T; Logofatu, C; Teodorescu, V S; Ciurea, M L

    2017-04-28

    High performance trilayer memory capacitors with a floating gate of a single layer of Ge quantum dots (QDs) in HfO2 were fabricated using magnetron sputtering followed by rapid thermal annealing (RTA). The layer sequence of the capacitors is gate HfO 2/floating gate of single layer of Ge QDs in HfO 2/tunnel HfO 2/p-Si wafers. Both Ge and HfO2 are nanostructured by RTA at moderate temperatures of 600-700 °C. By nanostructuring at 600 °C, the formation of a single layer of well separated Ge QDs with diameters of 2-3 nm at a density of 4-5 × 10(15) m(-2) is achieved in the floating gate (intermediate layer). The Ge QDs inside the intermediate layer are arranged in a single layer and are separated from each other by HfO2 nanocrystals (NCs) about 8 nm in diameter with a tetragonal/orthorhombic structure. The Ge QDs in the single layer are located at the crossing of the HfO2 NCs boundaries. In the intermediate layer, besides Ge QDs, a part of the Ge atoms is segregated by RTA at the HfO2 NCs boundaries, while another part of the Ge atoms is present inside the HfO2 lattice stabilizing the tetragonal/orthorhombic structure. The fabricated capacitors show a memory window of 3.8 ± 0.5 V and a capacitance-time characteristic with 14% capacitance decay in the first 3000-4000 s followed by a very slow capacitance decrease extrapolated to 50% after 10 years. This high performance is mainly due to the floating gate of a single layer of well separated Ge QDs in HfO2, distanced from the Si substrate by the tunnel oxide layer with a precise thickness.

  1. Garnet effect on Nd-Hf isotope decoupling: Evidence from the Jinfosi batholith, Northern Tibetan Plateau

    Science.gov (United States)

    Huang, Hui; Niu, Yaoling; Mo, Xuanxue

    2017-03-01

    The initial Nd and Hf isotope ratios of a 420 Ma post-collisional dioritic-granitic batholith from the Northern Tibetan plateau define a negative trend above and orthogonal to the ԐHf(t)-ԐNd(t) terrestrial array. This uncommon trend offers an insight into the origin of the puzzling Nd-Hf isotope decoupling in the crustal rocks. On this trend, samples depleted in heavy rare earth elements (HREEs, i.e., [Dy/Yb]N ≫ 1) deviate most from the terrestrial array whereas samples with flat HREEs (i.e., [Dy/Yb]N ≥ 1) deviate less or plot within the terrestrial array, pointing to the controlling effect of garnet in the magma source. Ancient garnet-bearing residues after melt extraction will have elevated Lu/Hf ratios and can evolve with time to produce high ԐHf(t) at a low ԐNd(t) value. Mixing of melts derived from such source lithologies (high Lu/Hf) with melts possessing a within-terrestrial array Nd-Hf isotopic composition (low Lu/Hf) best explains the observed trend orthogonal to the terrestrial array. The samples from the Jinfosi batholith with the most decoupled Nd-Hf isotope compositions require a larger degree (> 40%) and ancient (i.e., ≥ 1.8 Gyr) previous melt extraction from their source. It follows that the ancient melts with depleted HREEs complementary to those garnet-bearing residues should have low ԐHf values and plot below the terrestrial array, which is indeed shown by some Archean/Paleoproterozic TTGs.

  2. Sediment composition influences spatial variation in the abundance of human pathogen indicator bacteria within an estuarine environment.

    Directory of Open Access Journals (Sweden)

    Tracy L Perkins

    Full Text Available Faecal contamination of estuarine and coastal waters can pose a risk to human health, particularly in areas used for shellfish production or recreation. Routine microbiological water quality testing highlights areas of faecal indicator bacteria (FIB contamination within the water column, but fails to consider the abundance of FIB in sediments, which under certain hydrodynamic conditions can become resuspended. Sediments can enhance the survival of FIB in estuarine environments, but the influence of sediment composition on the ecology and abundance of FIB is poorly understood. To determine the relationship between sediment composition (grain size and organic matter and the abundance of pathogen indicator bacteria (PIB, sediments were collected from four transverse transects of the Conwy estuary, UK. The abundance of culturable Escherichia coli, total coliforms, enterococci, Campylobacter, Salmonella and Vibrio spp. in sediments was determined in relation to sediment grain size, organic matter content, salinity, depth and temperature. Sediments that contained higher proportions of silt and/or clay and associated organic matter content showed significant positive correlations with the abundance of PIB. Furthermore, the abundance of each bacterial group was positively correlated with the presence of all other groups enumerated. Campylobacter spp. were not isolated from estuarine sediments. Comparisons of the number of culturable E. coli, total coliforms and Vibrio spp. in sediments and the water column revealed that their abundance was 281, 433 and 58-fold greater in sediments (colony forming units (CFU/100g when compared with the water column (CFU/100ml, respectively. These data provide important insights into sediment compositions that promote the abundance of PIB in estuarine environments, with important implications for the modelling and prediction of public health risk based on sediment resuspension and transport.

  3. Hardness and Second Phase Percentage of Ni-Ti-Hf Compounds After Heat Treatment at 700C

    Science.gov (United States)

    Stanford, Malcolm K.

    2017-01-01

    The Vickers hardness and second phase precipitation of three ternary intermetallic Ni-Ti-Hf compounds containing either 1, 3 or 5 at.% Hf were compared to 60-Nitinol (55 at.% Ni - 45 at.% Ti). Heat treatment either at 700 C or with a subsequent aging step, hardened the 3 and 5 at.% Hf-containing ternaries to approximately 620 HV (56 HRC). Heat treatment increased the hardness of the 1 at.% Hf compound by more than 25 percent. Average hardness of the 3 and 5 at.% Hf ternaries, though higher than that of the binary Ni-Ti or the Ni-Ti-Hf compound containing 1 at.% Hf, appeared to be fairly insensitive to the different heat treatments. There was a drastic reduction of fatigue-enhancing second phase precipitates for the 5 at.% Hf ternaries compared to the other compounds. These results should guide materials selection for development of aerospace componentry.

  4. Do column frits contribute to the on-column, flow-induced degradation of macromolecules?

    Science.gov (United States)

    Striegel, André M

    2014-09-12

    Flow-induced, on-column degradation is a major hindrance to the accurate characterization of ultra-high molar mass macromolecules and colloids. This degradation is a direct result of the large shear rates which are generated within the column, which cause chain scission to occur both in the interstitial medium and, it has been postulated, at the packing particle pore boundary. An additional putative source of degradation has been the column frits, though little experimental evidence exists to either support or refute this claim. To this effect, the present experiments examine the role of the frits in the degradation of high molar mass macromolecules. Two narrow dispersity polystyrene standards, the molar mass of which differs by a factor of two, were analyzed on three different size-exclusion chromatography (SEC) columns, each with frits of different pore size, at various flow rates. In the smallest pore size column, which also contained the smallest frits and which was packed with the smallest diameter particles, the larger standard was forced to degrade by increasing the flow rate of the mobile phase. During the course of the latter portion of the study, the inlet and the outlet frits were removed from the column, in stepwise fashion. It was concluded that neither frit played any appreciable role in the degradation. Results of our studies were applied to explain previously observed degradation in ultra-high pressure liquid chromatography of polymers. The general conclusion arrived at herein is that the column frits are likely to have a secondary role (as compared to interstitial and pore boundary stresses), or no role at all, in polymer degradation for cases where the frit radius is larger than or equal to the hydraulic radius rcof the column.

  5. Seasonal Variation in Abundance and Species Composition of a Planktonic Diatom Assemblage Including Viable Cells on the Bottom in Matsushima Bay, Northeastern Japan

    Institute of Scientific and Technical Information of China (English)

    ICHINOMIYA Mutsuo; TANIGUCHI Akira

    2003-01-01

    Seasonal variation in abundance and species composition of a planktonic diatom assemblage distributed in the water column and also settled on the bottom was investigated for the shallow coastal water in Matsushima Bay on the Pacific coast of northeastern Japan during the period from October 1999 to September 2000. A spring bloom of diatoms began in April when nutrient concentrations started to increase, indicating the importance of nutrients. Viable cells of Skeletonema costatum and Thalassiosira spp., which were the dominant species in the water column throughout the year, were also always abundant in the bottom sediment. Both populations in the water column and on the bottom fluctuated essentially in parallel.For the planktonic diatoms in shallow coastal waters to maintain their vegetative populations in the water column, it would be advantageous for them to have a seeding population of viable cells on the bottom that are easily resuspended into the upper photic layer.

  6. How accurately can the deuterium abundance be determined?

    CERN Document Server

    Levshakov, S A; Takahara, F

    1997-01-01

    By using a Reverse Monte Carlo technique aimed at the inverse problem in the analysis of the H+D Ly-a absorption from QSO spectra we have estimated the physical parameters of the gas and the large-scale line of sight velocity structure towards Q1009+2956 at z = 2.504 (observations by Burles and Tytler, astro-ph/9603070). We show that for a precise evaluation of the column densities, the detailed velocity field structure is to be determined simultaneously. Our study of the z = 2.504 system yields D/H = (3.75 +/- 0.85)*10^{-5} (2sigma) which gives good agreement between the standard BBN predictions and observational constraints on extra-galactic 4He mass fraction and 7Li abundances in the atmospheres of population II (halo) starts. We conclude that the discordance of D/H with the light element abundances discussed in the literature is a consequence of the assumption of microturbulence (i.e. completely uncorrelated bulk motions) in the analysis of line profiles. The generalized model accounting for a finite corr...

  7. CO Abundance Variations in the Orion Molecular Cloud

    CERN Document Server

    Ripple, F; Gutermuth, R; Snell, R L; Brunt, C M

    2013-01-01

    Infrared stellar photometry from 2MASS and spectral line imaging observations of 12CO and 13CO J = 1-0 line emission from the FCRAO 14m telescope are analysed to assess the variation of the CO abundance with physical conditions throughout the Orion A and Orion B molecular clouds. Three distinct Av regimes are identified in which the ratio between the 13CO column density and visual extinction changes corresponding to the photon dominated envelope, the strongly self-shielded interior, and the cold, dense volumes of the clouds. Within the strongly self-shielded interior of the Orion A cloud, the 13CO abundance varies by 100% with a peak value located near regions of enhanced star formation activity. The effect of CO depletion onto the ice mantles of dust grains is limited to regions with AV > 10 mag and gas temperatures less than 20 K as predicted by chemical models that consider thermal-evaporation to desorb molecules from grain surfaces. Values of the molecular mass of each cloud are independently derived from...

  8. Fourier transform spectrometer measurements of column CO2 at Sodankylä, Finland

    Science.gov (United States)

    Kivi, Rigel; Heikkinen, Pauli

    2016-07-01

    Fourier transform spectrometer (FTS) observations at Sodankylä, Finland (67.4° N, 26.6° E) have been performed since early 2009. The FTS instrument is participating in the Total Carbon Column Observing Network (TCCON) and has been optimized to measure abundances of the key greenhouse gases in the atmosphere. Sodankylä is the only TCCON station in the Fennoscandia region. Here we report the measured CO2 time series over a 7-year period (2009-2015) and provide a description of the FTS system and data processing at Sodankylä. We find the lowest monthly column CO2 values in August and the highest monthly values during the February-May season. Inter-annual variability is the highest in the June-September period, which correlates with the growing season. During the time period of FTS measurements from 2009 to 2015, we have observed a 2.2 ± 0.2 ppm increase per year in column CO2. The monthly mean column CO2 values have exceeded 400 ppm level for the first time in February 2014.

  9. Calibration of TCCON column-averaged CO2: the first aircraft campaign over European TCCON sites

    Directory of Open Access Journals (Sweden)

    G. C. Toon

    2011-11-01

    Full Text Available The Total Carbon Column Observing Network (TCCON is a ground-based network of Fourier Transform Spectrometer (FTS sites around the globe, where the column abundances of CO2, CH4, N2O, CO and O2 are measured. CO2 is constrained with a precision better than 0.25% (1-σ. To achieve a similarly high accuracy, calibration to World Meteorological Organization (WMO standards is required. This paper introduces the first aircraft calibration campaign of five European TCCON sites and a mobile FTS instrument. A series of WMO standards in-situ profiles were obtained over European TCCON sites via aircraft and compared with retrievals of CO2 column amounts from the TCCON instruments. The results of the campaign show that the FTS measurements are consistently biased 1.1% ± 0.2% low with respect to WMO standards, in agreement with previous TCCON calibration campaigns. The standard a priori profile for the TCCON FTS retrievals is shown to not add a bias. The same calibration factor is generated using aircraft profiles as a priori and with the TCCON standard a priori. With a calibration to WMO standards, the highly precise TCCON CO2 measurements of total column concentrations provide a suitable database for the calibration and validation of nadir-viewing satellites.

  10. Separation of Oil from Wastewater by Column Flotation

    Institute of Scientific and Technical Information of China (English)

    2007-01-01

    A new type of device, a dissolved-air flotation column, was developed for separation of oily wastewater.The unique design idea of the dissolved-air flotation column is the combined use of dissolved-air flotation and column flotation.The dissolved air release occurred within the column separation system.As a potential application the column was investigated for its performance in separating emulsified oil droplets in oily wastewater.A high separation efficiency was obtained in a series of tests.The aeration performance of the bubble generator used in the dissolved-air flotation column was also studied in particular.

  11. Synchronized oscillation in a modular neural network composed of columns

    Institute of Scientific and Technical Information of China (English)

    LI; Su; QI; Xianglin; HU; Hong; WANG; Yunjiu

    2005-01-01

    The columnar organization is a ubiquitous feature in the cerebral cortex. In this study, a neural network model simulating the cortical columns has been constructed. When fed with random pulse input with constant rate, a column generates synchronized oscillations, with a frequency varying from 3 to 43 Hz depending on parameter values. The behavior of the model under periodic stimulation was studied and the input-output relationship was non-linear. When identical columns were sparsely interconnected, the column oscillator could be locked in synchrony. In a network composed of heterogeneous columns, the columns were organized by intrinsic properties and formed partially synchronized assemblies.

  12. Computational-Experimental Processing of Boride/Carbide Composites by Reactive Infusion of Hf Alloy Melts into B4C

    Science.gov (United States)

    2015-09-16

    elements from the Hf family (i.e., Hf, Ti and Zr ) into a capillary to understand the effects of surface tension and viscosity during processing of melts...project primarily investigated computationally the infusion of liquid elements from the Hf family (i.e., Hf, Ti and Zr ) into a capillary to understand the... effects of surface tension and viscosity during processing of melts with a packed bed of B4C to form boride-carbide precipitates. Although the

  13. Structure, optical properties and thermal stability of HfErO films deposited by simultaneous RF and VHF magnetron sputtering

    Energy Technology Data Exchange (ETDEWEB)

    Zhang, H.Y. [Soochow University, College of Physics, Optoelectronics and Energy and Collaborative Innovation Center of Suzhou Nano Science and Technology, Suzhou (China); Nanjing University of Posts and Telecommunications, School of Tongda, Nanjing (China); Soochow University, Key Lab of Advanced Optical Manufacturing Technologies of Jiangsu Province and Key Lab of Modern Optical Technologies of Education Ministry of China, Suzhou (China); He, H.J.; Zhang, Z.; Jin, C.G.; Yang, Y.; Wang, Y.Y.; Ye, C. [Soochow University, College of Physics, Optoelectronics and Energy and Collaborative Innovation Center of Suzhou Nano Science and Technology, Suzhou (China); Soochow University, Key Lab of Advanced Optical Manufacturing Technologies of Jiangsu Province and Key Lab of Modern Optical Technologies of Education Ministry of China, Suzhou (China); Zhuge, L.J. [Soochow University, Key Lab of Advanced Optical Manufacturing Technologies of Jiangsu Province and Key Lab of Modern Optical Technologies of Education Ministry of China, Suzhou (China); Soochow University, Analysis and Testing Center, Suzhou (China); Wu, X.M. [Soochow University, College of Physics, Optoelectronics and Energy and Collaborative Innovation Center of Suzhou Nano Science and Technology, Suzhou (China); Soochow University, Key Lab of Advanced Optical Manufacturing Technologies of Jiangsu Province and Key Lab of Modern Optical Technologies of Education Ministry of China, Suzhou (China); Chinese Academy of Sciences, State Key Laboratory of Functional Materials for Informatics, Shanghai Institute of Microsystem and Information Technology, Shanghai (China)

    2015-01-23

    HfErO films are deposited on Si substrates by simultaneous radio frequency (RF) and very high frequency (VHF) magnetron sputtering technique. The content of the doped ingredient of Er and the body composition of HfO{sub x} are, respectively, controlled through the VHF and RF powers. Low content of Er doping in the HfErO films can be achieved, because the VHF source of 27.12 MHz has higher ion energy and lower ion flux than the RF source resulting in low sputtering rate in the magnetron sputtering system. The structure, optical properties and thermal stability of the HfErO films are investigated in this work. Results show that the doped content of Er is independently controlled by the VHF power. The oxygen vacancies are created by the Er incorporation. The hafnium in the HfErO films forms mixed valence of Hf{sup 2+} and Hf{sup 4+}. The HfErO films are composed with the structures of HfO{sub 2}, HfO and ErO{sub x}, which can be optimized through the VHF power. At high VHF power, the Hf-Er-O bonds are formed, which demonstrates that the Er atoms are doped into the lattice of HfO{sub 2} in the HfErO films. The HfErO films have bad thermal stability as the crystallization temperature decreases from 900 to 800 C. After thermal annealing, cubic phase of HfO{sub 2} are stabilized, which is ascribed to the oxygen vacancies creation by the Er incorporation. The optical properties such as the refractive index and the optical band gap of the HfErO films are optimized by the VHF power. (orig.)

  14. Marine Group II Dominates Planktonic Archaea in Water Column of the Northeastern South China Sea

    Directory of Open Access Journals (Sweden)

    Haodong Liu

    2017-06-01

    Full Text Available Temperature, nutrients, and salinity are among the important factors constraining the distribution and abundance of microorganisms in the ocean. Marine Group II (MGII belonging to Euryarchaeota commonly dominates the planktonic archaeal community in shallow water and Marine Group I (MGI, now is called Thaumarchaeota in deeper water in global oceans. Results of quantitative PCR (qPCR and 454 sequencing in our study, however, showed the dominance of MGII in planktonic archaea throughout the water column of the northeastern South China Sea (SCS that is characterized by strong water mixing. The abundance of ammonia-oxidizing archaea (AOA representing the main group of Thaumarchaeota in deeper water in the northeastern SCS was significantly lower than in other oceanic regions. Phylogenetic analysis showed that the top operational taxonomic units (OTUs of the MGII occurring predominantly below 200 m depth may be unique in the northeastern SCS based on the observation that they are distantly related to known sequences (identity ranging from 90–94%. The abundance of MGII was also significantly correlated with total bacteria in the whole column, which may indicate that MGII and bacteria may have similar physiological or biochemical properties or responses to environmental variation. This study provides valuable information about the dominance of MGII over AOA in both shallow and deep water in the northeastern SCS and highlights the need for comprehensive studies integrating physical, chemical, and microbial oceanography.

  15. Methane and microbial dynamics in the Gulf of Mexico water column

    Directory of Open Access Journals (Sweden)

    Chrisoulla eRakowski

    2015-09-01

    Full Text Available In contrast to other oligotrophic water bodies the Gulf of Mexico (GOM hosts an abundance of hydrocarbon seeps, which likely influences the microbial assemblages it hosts particularly regarding the availability of labile carbon in the aphotic GOM. The aphotic zone receives direct injection of seep methane (CH4, but CH4 from an unknown source has been reported at supersaturated concentrations relative to the atmosphere in the GOM photic zone. Here we used iTag sequencing of 16S rRNA genes to characterize GOM microbial communities and to relate changes in microbial community structure to the properties inherent to their oceanic province-seafloor to the photic zone, seep and non-seep. Along this trajectory water column communities were distinct in the euphotic zone compared to the mesopelagic and deep-sea. In the euphotic zone the relative abundance of a cyanobacterial species (Prochlorococcus was significantly correlated with both CH4 and chlorophyll a concentrations and was abundant in some deep-chlorophyll maximum (DCM samples. The relative abundance of microorganisms related to known hydrocarbon degraders were also significantly correlated with CH4 in the euphotic zone, but no canonical methanotrophs were observed. In the mesopelagic to the seafloor canonical methanotrophs were identified, but only a Marine Group II Euryarchaeota was significantly correlated with CH4. Overall, depth and the associated environmental conditions were the primary drivers in structuring microbial communities over the GOM water column. Further, CH4 concentrations and relative microbial abundances covaried significantly from the seafloor to the photic zone in the GOM. The lack of a significant relationship between canonical methanotrophs and CH4 in the aphotic zone, even when sampling at seep sites, may suggest methane-oxidation by unknown microorganisms. Similarly their absence in the CH4 maximum and DCM suggested that CH4 is either oxidized by unrecognized

  16. Operation of a Batch Stripping Distillation Column

    Institute of Scientific and Technical Information of China (English)

    2001-01-01

    A stripping batch distillation column is preferred when the amount of the light component in the feed is small and the products are to be recovered at high purity. The operation modes of a batch stripping are believed to be the same as those of a rectifier. However, the control system of a stripper is different. In this paper, we explore three different control methods with Hysys (Hyprotech Ltd. 1997) for a batch stripper. The main difference is the control scheme for reboiler liquid level: (a) controlled by reflux flow; (b) controlled by reboiler heat duty; (c) controlled by bottom product flow. The main characteristics of operating a batch stripper with different control scheme are presented in this paper. Guidelines are provided for the startup of a batch stripper, the effects of somecontrol tuning parameters on the column performance are discussed.

  17. The Dissipative Column: A New Hysteretic Damper

    Directory of Open Access Journals (Sweden)

    Bruno Palazzo

    2015-02-01

    Full Text Available A new replaceable hysteretic damper to better control seismic building damage, consisting of two or more adjacent steel vertical elements connected to each other with continuous mild/low strength steel shear links, is proposed and investigated in this paper. New Dampers, called Dissipative Columns (DC, continuously linked with X-shaped steel plates, provide additional stiffness and damping to a lateral system by using a basic and minimally invasive construction element: the column. Working in a way similar to coupled shear walls, the proposed element behavior is theoretically analyzed at linear and non-linear ranges. In fact, considering different restrained cases, a parametric analysis is developed in order both to evaluate the effect of the main geometrical and structural parameters and to provide the design capacity curves of this new damper. The DC can be considered a new damping device, easy to install in new as well as existing buildings in order to protect them from seismic damage.

  18. Pressure drop in CIM disk monolithic columns.

    Science.gov (United States)

    Mihelic, Igor; Nemec, Damjan; Podgornik, Ales; Koloini, Tine

    2005-02-11

    Pressure drop analysis in commercial CIM disk monolithic columns is presented. Experimental measurements of pressure drop are compared to hydrodynamic models usually employed for prediction of pressure drop in packed beds, e.g. free surface model and capillary model applying hydraulic radius concept. However, the comparison between pressure drop in monolith and adequate packed bed give unexpected results. Pressure drop in a CIM disk monolithic column is approximately 50% lower than in an adequate packed bed of spheres having the same hydraulic radius as CIM disk monolith; meaning they both have the same porosity and the same specific surface area. This phenomenon seems to be a consequence of the monolithic porous structure which is quite different in terms of the pore size distribution and parallel pore nonuniformity compared to the one in conventional packed beds. The number of self-similar levels for the CIM monoliths was estimated to be between 1.03 and 2.75.

  19. Modeling of Crystalline Silicotitanate Ion Exchange Columns

    Energy Technology Data Exchange (ETDEWEB)

    Walker, D.D.

    1999-03-09

    Non-elutable ion exchange is being considered as a potential replacement for the In-Tank Precipitation process for removing cesium from Savannah River Site (SRS) radioactive waste. Crystalline silicotitanate (CST) particles are the reference ion exchange medium for the process. A major factor in the construction cost of this process is the size of the ion exchange column required to meet product specifications for decontaminated waste. To validate SRS column sizing calculations, SRS subcontracted two reknowned experts in this field to perform similar calculations: Professor R. G. Anthony, Department of Chemical Engineering, Texas A&038;M University, and Professor S. W. Wang, Department of Chemical Engineering, Purdue University. The appendices of this document contain reports from the two subcontractors. Definition of the design problem came through several meetings and conference calls between the participants and SRS personnel over the past few months. This document summarizes the problem definition and results from the two reports.

  20. Climate and local abundance in freshwater fishes

    OpenAIRE

    Knouft, Jason H.; Anthony, Melissa M.

    2016-01-01

    Identifying factors regulating variation in numbers of individuals among populations across a species' distribution is a fundamental goal in ecology. A common prediction, often referred to as the abundant-centre hypothesis, suggests that abundance is highest near the centre of a species' range. However, because of the primary focus on the geographical position of a population, this framework provides little insight into the environmental factors regulating local abundance. While range-wide va...

  1. Water Column Variability in Coastal Regions

    Science.gov (United States)

    2016-06-07

    offshore waters of energy, mass, and biota. OBJECTIVES Our objective is to determine the processes that cause water column variations in coastal regions...meteorological conditions (solar radiation, wind velocity, and heat fluxes), (iv) tidal mixing, stratification, water mass variations, (v) runoff from land...air-sea gas exchange and biological activity in these offshore waters. Two papers are being submitted to Limnology and Oceanography on the annual

  2. COLLISIONS OF ROAD VEHICLES WITH BRIDGE COLUMNS

    OpenAIRE

    2015-01-01

    As speed limits and traffic on city roads continue to increase, collisions between road vehicles and bridge columns are becoming more common. Current regulations analyze collision with one major simplification: replacing dynamic action with the equivalent static force. In the present paper, we develop a numerical model of a typical Croatian overpass and loaded it with an equivalent static load according to the EN1991-7 and ASSHTO LRFD provisions, analyzing the differences in overpass behavior...

  3. Using Dividing Wall Columns (DWC) in LNG Production: deviding wall column, double dividing wall column, prefractionator arrangement, Petlyuk column, NGL recovery, distillation

    OpenAIRE

    Ashrafian, Roohollah

    2014-01-01

    The Dividing Wall Columns (DWC) distillation has attracted growing interest for fractionation of multicomponent mixture due to reduction of energy consumption, auxiliary equipment and space within fractionation process. Recent developments of the process show considerable energy saving, up to 30%-40%, compared to conventional fractionation schemes. The objective of this thesis is to introduce DWC configurations, governing equations and applications in LNG and gas processing as well as explana...

  4. [Cervical vertebral column--anatomy, fractures, treatment].

    Science.gov (United States)

    Kłosiński, Michał; Sienkiewicz-Zawilińska, Justyna; Lipski, Marcin; Zawiliński, Jarosław; Matyja, Andrzej; Walocha, Jerzy

    2009-01-01

    The paper deals with anatomy of human cervical spine. It shows close relation between knowledge on the normal structure and methods of treatment of different kinds of spine injuries. It describes detailed anatomy and mechanical features of cervical vertebral column, including the structure of distinct vertebrae, their joints and arrangement of muscles. It reviews also historical methods of treatment of fractures in this region considering current methods.

  5. SVD row or column symmetric matrix

    Institute of Scientific and Technical Information of China (English)

    2000-01-01

    A new architecture for row or column symmetric matrix called extended matrix is defined, and a precise correspondence of the singular values and singular vectors between the extended matrix and its original (namely, the mother matrix) is derived. As an illustration of potential, we show that, for a class of extended matrices, the singular value decomposition using the mother matrix rather than the extended matrix per se can save the CPU time and memory without loss of numerical precision.

  6. Archean Lithosphere Beneath Arctic Canada: Lu-Hf Isotope Systematics for Kimberlite-Hosted Garnet-Peridotites From Somerset Island

    Science.gov (United States)

    Schmidberger, S. S.; Simonetti, A.; Francis, D.; Gariepy, C.

    2001-05-01

    Knowledge of the age of lithospheric mantle underlying the continents provides valuable constraints for the timing of formation and stabilization of Archean cratons. This study reports Lu-Hf isotopic data for garnet-peridotites, and their constituent garnets, from the Nikos kimberlite (100 Ma) on Somerset Island in the Canadian Arctic obtained using a Micromass IsoProbe multicollector inductively coupled plasma mass spectrometer (MC-ICP-MS) at GEOTOP-UQAM. The low temperature peridotites (1100 C; 160-190 km) and their 176Hf/177Hf(0.1Ga) isotopic compositions (0.28265-0.28333; \\epsilonHf(0.1Ga)=-2 to +22) are less radiogenic than those of the shallow xenoliths. A Lu-Hf isochron for six peridotites yields a mid Archean age of 3.4\\pm0.3 Ga and an initial 176Hf/177Hf ratio of 0.28101\\pm24. The remaining peridotites (n=9), in contrast, are characterized by extremely high (+35) initial \\epsilonHf(3.4Ga) values, which correlate negatively with their 176Lu/177Hf ratios, suggesting addition of Hf as a result of metasomatic interaction with the host kimberlite. The garnets from the low temperature (3.4 Ga old) peridotites are characterized by high 176Lu/177Hf ratios and define an errorchron age of 1.4\\pm0.2 Ga, which may reflect re-equilibration of Hf during kimberlite magmatism.

  7. Design for human factors (DfHF): a grounded theory for integrating human factors into production design processes.

    Science.gov (United States)

    Village, Judy; Searcy, Cory; Salustri, Filipo; Patrick Neumann, W

    2015-01-01

    The 'design for human factors' grounded theory explains 'how' human factors (HF) went from a reactive, after-injury programme in safety, to being proactively integrated into each step of the production design process. In this longitudinal case study collaboration with engineers and HF Specialists in a large electronics manufacturer, qualitative data (e.g. meetings, interviews, observations and reflections) were analysed using a grounded theory methodology. The central tenet in the theory is that when HF Specialists acclimated to the engineering process, language and tools, and strategically aligned HF to the design and business goals of the organisation, HF became a means to improve business performance. This led to engineers 'pulling' HF Specialists onto their team. HF targets were adopted into engineering tools to communicate HF concerns quantitatively, drive continuous improvement, visibly demonstrate change and lead to benchmarking. Senior management held engineers accountable for HF as a key performance indicator, thus integrating HF into the production design process. Practitioner Summary: Research and practice lack explanations about how HF can be integrated early in design of production systems. This three-year case study and the theory derived demonstrate how ergonomists changed their focus to align with design and business goals to integrate HF into the design process.

  8. Plant practices in fine coal column flotation

    Energy Technology Data Exchange (ETDEWEB)

    Davis, V.L. Jr.; Bethell, P.J.; Stanley, F.L. [Pittston Coal Management Co., Lebanon, VA (United States); Luttrell, G.H. [Virginia Polytechnic Institute and State Univ., Blacksburg, VA (United States). Dept. of Mining and Minerals Engineering

    1995-10-01

    Five 3 m (10 ft) diameter Microcel{trademark} flotation columns were installed at Clinchfield Coal Company`s Middle Fork preparation facility in order to reduce product ash and increase recovery and plant capacity. The Middle Fork facility is utilized for the recovery of fine coal from a feed stream that consists primarily of 1.5 mm x 0 material. The columns replaced conventional flotation cells for the treatment of the minus 150 {micro}m fraction while spirals are used to upgrade the plus 150 {micro}m material in the plant feed. The addition of the column flotation circuit resulted in an increase in plant capacity in excess of 20 percent while reducing the flotation product ash content by approximately 7 percentage points. Flotation circuit combustible recovery wa increased by 17 percentage points. This paper discusses circuit design, commissioning, and sparging system design. Circuit instrumentation, level control, reagent system control, performance comparisons with conventional flotation, and general operating procedures are also discussed.

  9. Seepage characteristics of collapse column fillings

    Institute of Scientific and Technical Information of China (English)

    Zhang Boyang; Bai Haibo; Zhang Kai

    2016-01-01

    With concealment and hysteresis, water-inrush from Karst collapse column has become an important security hazard of lower group coal mining in North China. Based on the MTS815.02 seepage test system, we analyzed the impact of consolidation pressure, initial moisture content and confining pressure on the permeability of fillings in order to study the seepage characteristics of collapse column fillings. The results show that:(1) The permeability of collapse column fillings is of the order of 10?16–10?15 magni-tude and decreases with an increase in consolidation pressure and decrease in initial moisture content. (2) The essence of filling seepage law change is the change in porosity, and a power function relationship exists between the permeability ratio and porosity ratio. (3) With increasing confining pressure, the per-meability of fillings decreases. However, under low confining pressure (1.2–4 MPa), the change of confin-ing pressure has no obvious influence on the permeability.

  10. SPEEDUP{trademark} ion exchange column model

    Energy Technology Data Exchange (ETDEWEB)

    Hang, T.

    2000-03-06

    A transient model to describe the process of loading a solute onto the granular fixed bed in an ion exchange (IX) column has been developed using the SpeedUp{trademark} software package. SpeedUp offers the advantage of smooth integration into other existing SpeedUp flowsheet models. The mathematical algorithm of a porous particle diffusion model was adopted to account for convection, axial dispersion, film mass transfer, and pore diffusion. The method of orthogonal collocation on finite elements was employed to solve the governing transport equations. The model allows the use of a non-linear Langmuir isotherm based on an effective binary ionic exchange process. The SpeedUp column model was tested by comparing to the analytical solutions of three transport problems from the ion exchange literature. In addition, a sample calculation of a train of three crystalline silicotitanate (CST) IX columns in series was made using both the SpeedUp model and Purdue University's VERSE-LC code. All test cases showed excellent agreement between the SpeedUp model results and the test data. The model can be readily used for SuperLig{trademark} ion exchange resins, once the experimental data are complete.

  11. Modular evolution of the Cetacean vertebral column.

    Science.gov (United States)

    Buchholtz, Emily A

    2007-01-01

    Modular theory predicts that hierarchical developmental processes generate hierarchical phenotypic units that are capable of independent modification. The vertebral column is an overtly modular structure, and its rapid phenotypic transformation in cetacean evolution provides a case study for modularity. Terrestrial mammals have five morphologically discrete vertebral series that are now known to be coincident with Hox gene expression patterns. Here, I present the hypothesis that in living Carnivora and Artiodactyla, and by inference in the terrestrial ancestors of whales, the series are themselves components of larger precaudal and caudal modular units. Column morphology in a series of fossil and living whales is used to predict the type and sequence of developmental changes responsible for modification of that ancestral pattern. Developmental innovations inferred include independent meristic additions to the precaudal column in basal archaeocetes and basilosaurids, stepwise homeotic reduction of the sacral series in protocetids, and dissociation of the caudal series into anterior tail and fluke subunits in basilosaurids. The most dramatic change was the novel association of lumbar and anterior caudal vertebrae in a module that crosses the precaudal/caudal boundary. This large unit is defined by shared patterns of vertebral morphology, count, and size in all living whales (Neoceti).

  12. Dynamics of a Tapped Granular Column

    Science.gov (United States)

    Rosato, Anthony; Blackmore, Denis; Zuo, Luo; Hao, Wu; Horntrop, David

    2015-11-01

    We consider the behavior of a column of spheres subjected to a time-dependent vertical taps. Of interest are various dynamical properties, such as the motion of its mass center, its response to taps of different intensities and forms, and the effect of system size and material properties. The interplay between diverse time and length scales are the key contributors to the column's evolving dynamics. Soft sphere discrete element simulations were conducted over a very wide parameter space to obtain a portrait of column behavior as embodied by the collective dynamics of the mass center motion. Results compared favorably with a derived reduced-order paradigm of the mass center motion (surprisingly analogous to that for a single bouncing ball on an oscillating plate) with respect to dynamical regimes and their transitions. A continuum model obtained from a system of Newtonian equations, as a locally averaged limit in the transport mode along trajectories is described, and a numerical solution protocol for a one-dimensional system is outlined. Typical trajectories and density evolution profiles are shown. We conclude with a discussion of our investigations to relate predictions of the continuum and reduced dynamical systems models with discrete simulations.

  13. Employing anatomical knowledge in vertebral column labeling

    Science.gov (United States)

    Yao, Jianhua; Summers, Ronald M.

    2009-02-01

    The spinal column constitutes the central axis of human torso and is often used by radiologists to reference the location of organs in the chest and abdomen. However, visually identifying and labeling vertebrae is not trivial and can be timeconsuming. This paper presents an approach to automatically label vertebrae based on two pieces of anatomical knowledge: one vertebra has at most two attached ribs, and ribs are attached only to thoracic vertebrae. The spinal column is first extracted by a hybrid method using the watershed algorithm, directed acyclic graph search and a four-part vertebra model. Then curved reformations in sagittal and coronal directions are computed and aggregated intensity profiles along the spinal cord are analyzed to partition the spinal column into vertebrae. After that, candidates for rib bones are detected using features such as location, orientation, shape, size and density. Then a correspondence matrix is established to match ribs and vertebrae. The last vertebra (from thoracic to lumbar) with attached ribs is identified and labeled as T12. The rest of vertebrae are labeled accordingly. The method was tested on 50 CT scans and successfully labeled 48 of them. The two failed cases were mainly due to rudimentary ribs.

  14. Behavior of high strength concrete columns under eccentric loads

    Directory of Open Access Journals (Sweden)

    Hany A. Kottb

    2015-04-01

    Full Text Available In recent decades, high strength concrete (HSC has been widely accepted by designers and contractors to be used in concrete structures, especially in high compressive stress elements. The research aims to study the behavior of high strength concrete columns under eccentric compression using experimental and analytical programs. The research is divided into two main parts; the first part is an experimental investigation for ten square columns tested at the Cairo University Concrete Research Laboratory. The main studied parameters were eccentricity of the applied load, column slenderness ratio; and ratios of longitudinal and transverse reinforcement. The second part is analytical analysis using nonlinear finite element program ANSYS11 on nineteen columns (ten tested square columns and nine rectangular section columns to study the effect of the previous parameters on the column ultimate load, mid-height displacement, and column cracking patterns. The analyzed columns revealed a good agreement with the experimental results with an average difference of 16% and 17% for column ultimate load and mid-height displacement respectively. Results showed an excellent agreement for cracking patterns. Predictions of columns capacities using the interaction diagrams based on ACI 318-08 stress block parameters indicated a safe design procedure of HSC columns under eccentric compression, with ACI 318-08 being more conservative for moderate reinforced HSC columns.

  15. Fingerprinting of traditional Chinese medicines on the C18-Diol mixed-mode column in online or offline two-dimensional liquid chromatography on the single column modes.

    Science.gov (United States)

    Wang, Qing; Tong, Ling; Yao, Lin; Zhang, Peng; Xu, Li

    2016-06-01

    In the present study, a mixed-mode stationary phase, C18-Diol, was applied for fingerprint analysis of traditional Chinese medicines. Hydrophobic, hydrogen bonding and electrostatic interactions were demonstrated to contribute the retention separately or jointly, which endowed the C18-Diol stationary phase with distinct selectivity compared to the bare C18 one. The separation of total alkaloids extracted from Fritillaria hupehensis was compared on the C18-Diol and conventional C18 column with the greater resolving power and better symmetry responses on the former one. Besides, a novel two-dimensional liquid chromatography on the single column (2D-LC-1C) was realized on C18-Diol with the offline mode for the alcohol extract of Fritillaria hupehensis and online mode for Ligusticum chuanxiong Hort. The early co-eluted extracted components with great polarity on the first dimension were reinjected on the same column and well separated on the second dimension. The results exhibited that the two complementary RPLC and HILIC modes on C18-Diol stationary phase enhanced the separation capacity and revealed more abundant chemical information of the sample, which was a powerful tool in analyzing complex herbal medicines.

  16. Abundance of introduced species at home predicts abundance away in herbaceous communities

    Science.gov (United States)

    Firn, Jennifer; Moore, Joslin L.; MacDougall, Andrew S.; Borer, Elizabeth T.; Seabloom, Eric W.; HilleRisLambers, Janneke; Harpole, W. Stanley; Cleland, Elsa E.; Brown, Cynthia S.; Knops, Johannes M.H.; Prober, Suzanne M.; Pyke, David A.; Farrell, Kelly A.; Bakker, John D.; O'Halloran, Lydia R.; Adler, Peter B.; Collins, Scott L.; D'Antonio, Carla M.; Crawley, Michael J.; Wolkovich, Elizabeth M.; La Pierre, Kimberly J.; Melbourne, Brett A.; Hautier, Yann; Morgan, John W.; Leakey, Andrew D.B.; Kay, Adam; McCulley, Rebecca; Davies, Kendi F.; Stevens, Carly J.; Chu, Cheng-Jin; Holl, Karen D.; Klein, Julia A.; Fay, Phillip A.; Hagenah, Nicole; Kirkman, Kevin P.; Buckley, Yvonne M.

    2011-01-01

    Many ecosystems worldwide are dominated by introduced plant species, leading to loss of biodiversity and ecosystem function. A common but rarely tested assumption is that these plants are more abundant in introduced vs. native communities, because ecological or evolutionary-based shifts in populations underlie invasion success. Here, data for 26 herbaceous species at 39 sites, within eight countries, revealed that species abundances were similar at native (home) and introduced (away) sites - grass species were generally abundant home and away, while forbs were low in abundance, but more abundant at home. Sites with six or more of these species had similar community abundance hierarchies, suggesting that suites of introduced species are assembling similarly on different continents. Overall, we found that substantial changes to populations are not necessarily a pre-condition for invasion success and that increases in species abundance are unusual. Instead, abundance at home predicts abundance away, a potentially useful additional criterion for biosecurity programmes.

  17. A DIRECT MEASUREMENT OF THE TOTAL GAS COLUMN DENSITY IN ORION KL

    Energy Technology Data Exchange (ETDEWEB)

    Plume, R. [Department of Physics and Astronomy and the Institute for Space Imaging Sciences, University of Calgary, Calgary, AB T2N 1N4 (Canada); Bergin, E. A.; Wang, S.; Crockett, N. R. [Department of Astronomy, University of Michigan, 500 Church Street, Ann Arbor, MI 48109 (United States); Phillips, T. G.; Lis, D. C. [California Institute of Technology, Cahill Center for Astronomy and Astrophysics 301-17, Pasadena, CA 91125 (United States); Caux, E. [Universite de Toulouse, UPS-OMP, IRAP, Toulouse (France); Comito, C.; Schilke, P. [Max-Planck-Institut fuer Radioastronomie, Auf dem Huegel 69, 53121 Bonn (Germany); Goldsmith, P. F., E-mail: plume@ras.ucalgary.ca [Jet Propulsion Laboratory, Caltech, Pasadena, CA 91109 (United States)

    2012-01-01

    The large number of high-J lines of C{sup 18}O available via the Herschel Space Observatory provide an unprecedented ability to model the total CO column density in hot cores. Using the emission from all the observed lines (up to J = 15-14), we sum the column densities in each individual level to obtain the total column after correcting for the population in the unobserved states. With additional knowledge of source size, V{sub LSR}, and line width, and both local thermodynamic equilibrium (LTE) and non-LTE modeling, we have determined the total C{sup 18}O column densities in the Extended Ridge, Outflow/Plateau, Compact Ridge, and Hot Core components of Orion KL to be 1.4 Multiplication-Sign 10{sup 16} cm{sup -2}, 3.5 Multiplication-Sign 10{sup 16} cm{sup -2}, 2.2 Multiplication-Sign 10{sup 16} cm{sup -2}, and 6.2 Multiplication-Sign 10{sup 16} cm{sup -2}, respectively. We also find that the C{sup 18}O/C{sup 17}O abundance ratio varies from 1.7 in the Outflow/Plateau, 2.3 in the Extended Ridge, 3.0 in the Hot Core, and to 4.1 in the Compact Ridge. This is in agreement with models in which regions with higher ultraviolet radiation fields selectively dissociate C{sup 17}O, although care must be taken when interpreting these numbers due to the size of the uncertainties in the C{sup 18}O/C{sup 17}O abundance ratio.

  18. Photocurrent generation in carbon nanotube/cubic-phase HfO2 nanoparticle hybrid nanocomposites

    Directory of Open Access Journals (Sweden)

    Protima Rauwel

    2016-07-01

    Full Text Available A hybrid material consisting of nonfunctionalized multiwall carbon nanotubes (MWCNTs and cubic-phase HfO2 nanoparticles (NPs with an average diameter of 2.6 nm has been synthesized. Free standing HfO2 NPs present unusual optical properties and a strong photoluminescence emission in the visible region, originating from surface defects. Transmission electron microscopy studies show that these NPs decorate the MWCNTs on topological defect sites. The electronic structure of the C K-edge in the nanocomposites was probed by electron energy loss spectroscopy, highlighting the key role of the MWCNT growth defects in anchoring HfO2 NPs. A combined optical emission and absorption spectroscopy approach illustrated that, in contrast to HfO2 NPs, the metallic MWCNTs do not emit light but instead expose their discrete electronic structure in the absorption spectra. The hybrid material manifests characteristic absorption features with a gradual merger of the MWCNT π-plasmon resonance band with the intrinsic defect band and fundamental edge of HfO2. The photoluminescence of the nanocomposites indicates features attributed to combined effects of charge desaturation of HfO2 surface states and charge transfer to the MWCNTs with an overall reduction of radiative recombination. Finally, photocurrent generation under UV–vis illumination suggests that a HfO2 NP/MWCNT hybrid system can be used as a flexible nanodevice for light harvesting applications.

  19. Superelasticity and Shape Memory Behavior of NiTiHf Alloys

    Science.gov (United States)

    Sehitoglu, H.; Wu, Y.; Patriarca, L.; Li, G.; Ojha, A.; Zhang, S.; Chumlyakov, Y.; Nishida, M.

    2017-06-01

    The NiTiHf high-temperature shape memory alloys represent a significant advancement in extending the functionality of binary NiTi to elevated temperatures above 100 °C. Despite this potential, the previous results in the literature point to a disappointingly low shape memory strains with addition of Hf. On the other hand, based on theoretical analysis using the lattice constants, the transformation strains should increase substantially with increase in Hf content. The present paper addresses this discrepancy, and using atomistic simulations, determination of twinning modes in martensite with transmission electron microscopy, digital image measurements of habit plane orientation, and strains in single-crystal specimens show that the experimental transformation strains in NiTiHf indeed increase with increasing Hf to unprecedented strain levels near 20%. The Hf contents considered were in the range 6.25-25 at.%, and NiTi (0% Hf) results are provided as the baseline. The current work represents more than 60 experiments representing an extremely thorough study on single crystals and polycrystals.

  20. Isolation and Characterization of a Virulent Bacteriophage φPA-HF17 of Pseudomonas aeruginosa

    Directory of Open Access Journals (Sweden)

    Fang Han

    2014-09-01

    Full Text Available Pseudomonas aeruginosa, an important causative agent of nosocomial infection, is found throughout the hospital environment in moist reservoirs, and multidrug-resistant strains of P. aeruginosa have been increasingly reported worldwide. Bacteriophages are often considered potential therapeutic candidates in treating infectious diseases. In this study, a novel virulent bacteriophage φPA-HF17, specific infecting clinical isolates of P. aeruginosa, was isolated and characterized from environmental sewage. Transmission electron microscopy showed that phage φPA-HF17 had an icosahedral head with a very short tail, and exhibited characteristics typical of a podovirus. Restriction analysis indicated that phage φPA-HF17 was a double-stranded DNA virus, which might be digested by some restriction endonucleases. Phage φPA-HF17 was highly infectious with a rapid adsorption (>90% adsorbed in 4 min. In a one-step growth experiment, phage φPA-HF17 was shown having a latent period of 10 minute, with corresponding burst sizes of 200 PFU/cell. Furthermore, when φPA-HF17 alone was incubated at different pHs and different temperatures, the phage was stable over a wide pH range (4 to 10 and at extreme temperature (50°C. These results suggest that φPA-HF17 may be candidate therapeutic phage to control P. aeruginosa infection.

  1. In-situ atomic layer deposition growth of Hf-oxide

    Energy Technology Data Exchange (ETDEWEB)

    Karavaev, Konstantin

    2010-06-17

    We have grown HfO{sub 2} on Si(001) by atomic layer deposition (ALD) using HfCl{sub 4}, TEMAHf, TDMAHf and H{sub 2}O as precursors. The early stages of the ALD were investigated with high-resolution photoelectron spectroscopy and X-ray absorption spectroscopy. We observed the changes occurring in the Si 2p, O 1s, Hf 4f, Hf 4d, and Cl 2p (for HfCl{sub 4} experiment) core level lines after each ALD cycle up to the complete formation of two layers of HfO{sub 2}. The investigation was carried out in situ giving the possibility to determine the properties of the grown film after every ALD cycle or even after a half cycle. This work focused on the advantages in-situ approach in comparison with ex-situ experiments. The study provides to follow the evolution of the important properties of HfO{sub 2}: contamination level, density and stoichiometry, and influence of the experimental parameters to the interface layer formation during ALD. Our investigation shows that in-situ XPS approach for ALD gives much more information than ex-situ experiments. (orig.)

  2. Experimental Testing Of Partially Encased Composite Beam Columns

    Directory of Open Access Journals (Sweden)

    Ehab M. Hanna

    2016-01-01

    Full Text Available The past few decades have seen outstanding advances in the use of composite materials in structural applications. There can be little doubt that, within engineering circles, composites have revolutionized traditional design concepts and made possible an unparalleled range of new and exciting possibilities as viable materials for construction. In addition to the well-known advantages of composite columns, partially encased composite columns offered simplified beam-to-column connection as well as reduced or omitted shuttering thus achieved more cost effective construction. Some companies have patented these new types of partially encased composite column made of light welded steel shapes; moreover, the Canadian Institute of Steel construction CISC has recognized and codified this type of columns. In This paper, Partially Encased Composite Beam Columns is introduced; experimental studies are made on five partially encased beam columns to investigate the behavior of eccentrically loaded partially encased composite columns using different parameters.

  3. Composition Estimation in Dividing-Wall Columns Using Temperature Measurements

    OpenAIRE

    Ghadrdan, Maryam; Ivar J. Halvorsen; Skogestad, Sigurd

    2011-01-01

    In this work, we propose a method to estimate the product compositions in a distillation column section based on a combination of a number of temperature measurements from different locations in the column stages.

  4. Zr, Hf, U, Th and REE-Fertile Lower Proterozoic Potassic Granite from Parts of Andhra Pradesh, South India

    Institute of Scientific and Technical Information of China (English)

    Yamuna SINGH

    2004-01-01

    The medium- to coarse-grained and porphyritic granitoid of Dharmawaram, Karimnagar district, Andhra Pradesh, south India is a biotite-hornblende granite with notable contents of rare metal (Zr, Hf, Th) and rare earth (including Y) minerals like zircon, thorite, allanite, monazite and xenotime. Chemically, it is metaluminous (average A/C+N+K = 0.95)-type, potassic (ay. 5% K2O) granite, with dominantly sub-alkaline characters. It shows up to 8 times enrichment of rare metals (Zr, Hf, U, Th) and rare earths (including Y, Sc), with reference to their abundances in normal unevolved granite, and hence, fertile for some of these elements. Field, petrological, geochemical and isotopic data of potassic granite (PG) indicate involvement of silica-rich metasedimentary-basic crustal rocks (amphibole-quartzite,amphibolite, hornblende-biotite gneiss, etc.) in its genesis, at a depth range of 30 km. Further, chondrite-normalized REE patterns demonstrate that low-degree partial melting of source rocks is the major controlling factor in the genesis of PG.Mild negative Eu-anomaiy (av. Eu/Eu* = 0.48), plots of Ba-Rb-Sr in the field of anomalous granite and K/Rb ratios (av.239) in the range that is shown by normal unevolved granite together indicate less fractionated nature of the PG. Limited fractionation of metalumination-type, involving hornblende, led to occasional weak alumina saturation. Interestingly,geochemical and petrogenetic features of the studied PG broadly match with those potassic granites which are already known to host anomalously high enrichment of rare metals and rare earths in other parts of Andhra Pradesh and adjoining Kamataka.

  5. Microstructure and Phase Stability of Single Crystal NiAl Alloyed with Hf and Zr

    Science.gov (United States)

    Locci, I. E.; Dickerson, R. M.; Garg, A.; Noebe, R. D.; Whittenberger, J. D.; Nathal, M. V.; Darolia, R.

    1996-01-01

    Six near stoichiometric, NiAl single-crystal alloys, with 0.05-1.5 at.% of Hf and Zr additions plus Si impurities, were microstructurally analyzed in the as-cast, homogenized, and aged conditions. Hafnium-rich interdendritic regions, containing the Heusler phase (Ni2AlHf), were found in all the as-cast alloys containing Hf. Homogenization heat treatments partially reduced these interdendritic segregated regions. Transmission electron microscopy (TEM) observations of the as-cast and homogenized microstructures revealed the presence of a high density of fine Hf (or Zr) and Si-rich precipitates. These were identified as G-phase, Nil6X6Si7, or as an orthorhombic NiXSi phase, where X is Hf or Zr. Under these conditions the expected Heusler phase (beta') was almost completely absent. The Si responsible for the formation of the G and NiHfSi phases is the result of molten metal reacting with the Si-containing crucible used during the casting process. Varying the cooling rates after homogenization resulted in the refinement or complete suppression of the G and NiHfSi phases. In some of the alloys studied, long-term aging heat treatments resulted in the formation of Heusler precipitates, which were more stable at the aging temperature and coarsened at the expense of the G-phase. In other alloys, long-term aging resulted in the formation of the NiXSi phase. The stability of the Heusler or NiXSi phases can be traced to the reactive element (Hf or Zr) to silicon ratio. If the ratio is high, then the Heusler phase appears stable after long time aging. If the ratio is low, then the NiHfSi phase appears to be the stable phase.

  6. Vibrational relaxation of hydrogen fluoride by HF dimers in a laser excited nozzle beam

    Energy Technology Data Exchange (ETDEWEB)

    Knuth, E.L.; Rubahn, H.; Toennies, J.P.; Wanner, J.

    1986-09-01

    An HF nozzle beam and a cw HF laser beam in a coaxial and antiparallel arrangement facilitated exciting HF molecules vibrationally in v-italic = 1,J-italic up to the saturation limit. A beam consisting exclusively of monomeric HF was generated by heating the beam source to 600 K and was confirmed using a mass spectrometer. Energy-flux measurements made using a bolometer indicate that the vibrational energy distribution initiated by the laser is conserved, confirming that V--T energy transfer to monomers is slow. The maximum measured flux of HF(v-italic = 1,J-italic) molecules was 1.5 x 10/sup 17/ molecules s/sup -1/ sr/sup -1/ at 670 mbar stagnation pressure. Beams consisting of a mixture of monomeric and polymeric HF were generated using appropriate combinations of source temperature and pressure. In the presence of dimers, the excited monomers relax rapidly by a fast V--V transfer and subsequent predissociation of the metastable dimers. The loss of beam energy due to energy transport by the departing dimer fragments was detected bolometrically. The laser-induced depletion of dimers was determined over a wide source pressure range at T-italic/sub 0/ = 300 K using a mass spectrometer. From a kinetic model of these dimer-depletion data, the product of cross section and transfer probability for V--V energy transfer from HF (v-italic = 1) monomers to dimers was deduced to be 14 A-circle/sup 2/. The terminal-dimer-concentration equation for HF nozzle beams was refined. An analysis of the energy fluxes measured by the bolometer with no laser excitation of the beam revealed that, for an HF nozzle beam, the flow from the source to the detector is, in general, nonisenthalpic due to the onset of dimerization. Mach-number focusing enriches the dimer mole fractions detected by the bolometer.

  7. Properties of HfAlO film deposited by plasma enhanced atomic layer deposition

    Energy Technology Data Exchange (ETDEWEB)

    Cao, Duo [State Key Laboratory of Functional Materials for Informatics, Shanghai Institute of Micro-system and Information Technology, Chinese Academy of Sciences, Changning Road 865, Shanghai 200050 (China); Cheng, Xinhong, E-mail: xh_cheng@mail.sim.ac.cn [State Key Laboratory of Functional Materials for Informatics, Shanghai Institute of Micro-system and Information Technology, Chinese Academy of Sciences, Changning Road 865, Shanghai 200050 (China); Jia, Tingting; Zheng, Li; Xu, Dawei; Wang, Zhongjian; Xia, Chao; Yu, Yuehui [State Key Laboratory of Functional Materials for Informatics, Shanghai Institute of Micro-system and Information Technology, Chinese Academy of Sciences, Changning Road 865, Shanghai 200050 (China)

    2013-07-15

    Plasma enhanced atomic layer deposition (PEALD) method can reduce film growing temperature, and allow in situ plasma treatment. In this work, HfAlO and HfO{sub 2} films were deposited with PEALD at 160 °C. Microstructure analysis showed that both films were amorphous after rapid thermal annealing (RTA) treatment, and HfAlO sample showed better interfacial structure than HfO{sub 2}. X-ray photoelectron spectroscopy (XPS) spectra indicated that main component of the interfacial layer of HfAlO sample was Hf–Si–O and Al–Si–O bonds, the valence band offset value between the HfAlO film and Si substrate was calculated to be 2.5 eV. The dominant leakage current mechanism of the samples was Schottky emission at a low electric field (<1.4 MV/cm), and Poole–Frenkel emission mechanism at a higher electric field (>1.4 MV/cm). The equivalent oxide thicknesses (EOT) of the HfAlO samples were 1.0 nm and 1.3 nm, respectively. The density of interface states between dielectric and substrate were calculated to be 1.2 × 10{sup 12} eV{sup −1}cm{sup −2} and 1.3 × 10{sup 12} eV{sup −1}cm{sup −2}, respectively. In comparison with HfO{sub 2} film, HfAlO film has good interfacial structure and electrical performance.

  8. Ti insertion in the MTe5 (M = Zr, Hf structure type: Hf0.78Ti0.22Te5

    Directory of Open Access Journals (Sweden)

    Hoseop Yun

    2012-03-01

    Full Text Available The group 5 mixed-metal telluride, Hf0.78Ti0.22Te5 (hafnium titanium pentatelluride, is isostructural with the binary phases HfTe5 and ZrTe5 and forms a layered structure extending parallel to (010. The layers are made up from chains of bicapped metal-centered trigonal prisms and zigzag Te chains. The metal site (site symmetry m2m is occupied by statistically disordered Hf [78.1 (5%] and Ti [21.9 (5%]. In addition to the regular Te—Te pair [2.7448 (13 Å] forming the short base of the equilateral triangle of the trigonal prism, an intermediate Te...Te separation [2.9129 (9 Å] is also found. The classical charge balance of the compound can be described as [M4+][Te2−][Te22−][Te20] (M = Hf, Ti. The individual metal content can vary in different crystals, apparently forming a random substitutional solid solution (Hf1-xTixTe5, with 0.15 ≤ x ≤ 0.22.

  9. First-principles calculated spin-gapless semiconducting behavior in quaternary VCoHfGa and CrFeHfGa Heusler compounds

    Energy Technology Data Exchange (ETDEWEB)

    Yang, Xiude; Wu, Xiaolin [Institute of Theoretical Physics, Zunyi Normal College, Zunyi 563002 (China); Wu, Bo, E-mail: fqwubo@zync.edu.cn [Institute of Theoretical Physics, Zunyi Normal College, Zunyi 563002 (China); School of Marine Science and Technology, Northwestern Polytechnical University, Xian 710072 (China); Feng, Yu [School of Physical Science and Technology, Southwest University, Chongqing 400715 (China); Li, Ping [Institute for Clean Energy & Advanced Materials (ICAEM), Southwest University, Chongqing 400715 (China); Huang, Haishen [Institute of Theoretical Physics, Zunyi Normal College, Zunyi 563002 (China)

    2016-07-15

    Highlights: • Structural, electronic and magnetic properties of quaternary Heusler alloy [VCo,CrFe]HfGa were detected theoretically. • The quaternary Heusler alloy [VCo,CrFe]HfGa are (or are nearly) spin gapless semiconductors at the lowest energy state. • The ferromagnetic coupling plays an important role in magnetism. - Abstract: By using generalized gradient approximation (GGA) scheme within the density functional theory (DFT), the structural, electronic and magnetic properties of LiMgPdSn-type quaternary Heusler alloy CrFeHfGa and VCoHfGa were detected compressively. The results reveal that the two alloys are (or are nearly) potential spin gapless semiconductors with a magnetic moment of 3 μ{sub B} per primitive cell and the minority-spin gap of 0.8 eV and 0.6 eV at Fermi level (ε{sub F}) during the rate of lattice change of about −5%, respectively. We deduce that the ferromagnetic coupling among transitional metals plays an important role in magnetism of Heusler alloy [CrFe,VCo]HfGa.

  10. First-principles study of the (001) surface of cubic PbHfO3 and BaHfO3

    Institute of Scientific and Technical Information of China (English)

    Ni Guang-Xin; Wang Yuan-Xu

    2009-01-01

    Using first-principles techniques, we investigate the (001) surfaces of cubic PbHfO3 (PHO) and BaHfO3 (BHO) terminated with both AO (A=Pb and Ba) and HfO2- Surface structure, partial density of states, band structure, and surface energy are obtained. The BaO surface is found to be similar to its counterpart in BHO. For the HfO2-terminated surface of cubic PHO, the largest relaxation appears on the second-layer atoms but not on the first-layer ones. The analysis of the structure relaxation parameters reveals that the rumpling of the (001) surface for PHO is stronger than that for BHO. The surface thermodynamic stability is explored, and it is found that both the PbO- and the BaO-terminated surfaces are more stable than the HfO2-terminated surfaces for PHO and BHO, respectively. The surface energy calculations show that the (001) surface of PHO is more easily constructed than that of BHO.

  11. Numerical Simulations of Settlement of Jet Grouting Columns

    Directory of Open Access Journals (Sweden)

    Juzwa Anna

    2016-03-01

    Full Text Available The paper presents the comparison of results of numerical analyses of interaction between group of jet grouting columns and subsoil. The analyses were conducted for single column and groups of three, seven and nine columns. The simulations are based on experimental research in real scale which were carried out by authors. The final goal for the research is an estimation of an influence of interaction between columns working in a group.

  12. Anchoring FRP laminates for the seismic strengthening of RC columns

    OpenAIRE

    Sadone, Raphaëlle; Quiertant, Marc; FERRIER, Emmanuel; Chataigner, Sylvain; Mercier, Julien

    2012-01-01

    This paper aims to examine the effectiveness of seismic strengthening of reinforced concrete (RC) columns by externally bonded Fibre Reinforced Polymer (FRP). Particularly, a novel strengthening system, designed for the flexural strengthening of columns is studied. This flexural strengthening is achieved by FRP plates bonded longitudinally and anchored at the column-stub junction. The proposed system is validated through an experimental campaign carried out on full-scale RC columns. Different...

  13. Flexural strength enhancement of confined reinforced concrete columns

    OpenAIRE

    Pam, HJ; Ho, JCM

    2001-01-01

    As part of a continuing research study, this paper proposes a new design aid to calculate the actual moment capacity of confined reinforced concrete columns. Up to now the moment capacity of a reinforced concrete column is calculated based on the code's guidelines for an unconfined section. As most reinforced concrete columns contain transverse or confining reinforcement, which will enhance the column moment capacity, the actual moment capacity will be much higher than the unconfined moment c...

  14. QR factorization for row or column symmetric matrix

    Institute of Scientific and Technical Information of China (English)

    ZOU; Hongxing(邹红星); WANG; Dianjun(王殿军); DAI; Qionghai(戴琼海); LI; Yanda(李衍达)

    2003-01-01

    The problem of fast computing the QR factorization of row or column symmetric matrix isconsidered. We address two new algorithms based on a correspondence of Q and R matrices between the rowor column symmetric matrix and its mother matrix. Theoretical analysis and numerical evidence show that, fora class of row or column symmetric matrices, the QR factorization using the mother matrix rather than therow or column symmetric matrix per se can save dramatically the CPU time and memory without loss of anynumerical precision.

  15. Intermediate-mass Asymptotic Giant Branch Stars and Sources of 26Al, 60Fe, 107Pd, and 182Hf in the Solar System

    Science.gov (United States)

    Wasserburg, G. J.; Karakas, Amanda I.; Lugaro, Maria

    2017-02-01

    We explore the possibility that the short-lived radionuclides {}26{{A}}l, {}60{{F}}e, {}107{{P}}d, and {}182{{H}}f inferred to be present in the proto-solar cloud originated from 3–8 {M}ȯ asymptotic giant branch (AGB) stars. Models of AGB stars with initial mass above 5 {M}ȯ are prolific producers of {}26{{A}}l owing to hot bottom burning (HBB). In contrast, {}60{{F}}e, {}107{{P}}d, and {}182{{H}}f are produced by neutron captures: {}107{{P}}d and {}182{{H}}f in models ≲ 5 {M}ȯ , and {}60{{F}}e in models with higher mass. We mix stellar yields from solar-metallicity AGB models into a cloud of solar mass and composition to investigate whether it is possible to explain the abundances of the four radioactive nuclides at the Sun’s birth using one single value of the mixing ratio between the AGB yields and the initial cloud material. We find that AGB stars that experience efficient HBB (≥slant 6 {M}ȯ ) cannot provide a solution because they produce too little {}182{{H}}f and {}107{{P}}d relative to {}26{{A}}l and {}60{{F}}e. Lower-mass AGB stars cannot provide a solution because they produce too little {}26{{A}}l relative to {}107{{P}}d and {}182{{H}}f. A self-consistent solution may be found for AGB stars with masses in between (4–5.5 {M}ȯ ), provided that HBB is stronger than in our models and the {}13{{C}}(α, n){}16{{O}} neutron source is mildly activated. If stars of {{M}}< 5.5 {M}ȯ are the source of the radioactive nuclides, then some basis for their existence in proto-solar clouds needs to be explored, given that the stellar lifetimes are longer than the molecular cloud lifetimes.

  16. Recent progress in AMS measurement of 182Hf at the CIAE

    Institute of Scientific and Technical Information of China (English)

    LI Zhen-Yu; LI Heng; WU Shao-Yong; YUAN Jian; JIANG Shan; HE Ming; DONG Ke-Jun; HE Guo-Zhu; LI Chao-Li; HE Xian-Wen; ZHANG Wei; HU Hao; ZHENG Guo-Wen

    2012-01-01

    In order to improve the accuracy of accelerator mass spectrometry (AMS) measurement for 182Hf/180Hf,a series of measurements have been taken in the AMS laboratory at the China Institute of Atomic Energy (CIAE).The major ones include the instantaneous monitoring of 180HfF-5current,testing the stability of transmission,the alternate measurements of an unknown sample and standard,and the origin identification and minimization of background 182W.The experimental details and the improvement in the measurement accuracy,as well as some useful suggestions for better satisfying the requirements of certain practical applications,are presented in this paper.

  17. Crystal structure of Na2HfSi2O7 by Rietveld refinement

    Directory of Open Access Journals (Sweden)

    Nicolas Massoni

    2016-10-01

    Full Text Available The structure of triclinic disodium hafnium disilicate, Na2HfSi2O7, has been determined by laboratory powder X-ray diffraction and refined by the Rietveld refinement. The structure is a framework made of alternate layers of HfO6 octahedra and SiO4 tetrahedra linked by common O atoms. Sodium atoms are located in the voids of the framework, aligned into tunnels along the [010] direction. Na2HfSi2O7 is isostructural with the parakeldyshite Na2ZrSi2O7 phase.

  18. Structural and thermal properties of Cu-Hf-Ti bulk amorphous alloys

    Science.gov (United States)

    Rontó, V.; Nagy, E.; Svéda, M.; Roósz, A.; Tranta, F.

    2009-01-01

    Cu-Hf-Ti amorphous alloys are high strength and wear resistant materials. Master alloys of Cu57.5Hf27.5Ti15 and Cu57.5Hf25Ti17.5 ternary alloys have been prepared by arc melting, and wedge and rod shaped samples have been cast by centrifugal casting. Liquidus and solidus temperatures of the alloys were determined by DTA. The fully amorphous size was determined by X-ray diffraction. Thermodynamic properties of the amorphous alloys were studied by DSC measurements and Kissinger analyses were performed.

  19. Artificial Ionization and UHF Radar Response Associated with HF Frequencies near Electron Gyro-Harmonics (Invited)

    Science.gov (United States)

    Watkins, B. J.; Fallen, C. T.; Secan, J. A.

    2013-12-01

    We present new results from O-mode ionospheric heating experiments at the HAARP facility in Alaska to demonstrate that the magnitude of artificial ionization production is critically dependent on the choice of HF frequency near gyro-harmonics. For O-mode heating in the lower F-region ionosphere, typically about 200 km altitude, artificial ionization enhancements are observed in the lower ionosphere (about 150 - 220 km) and also in the topside ionosphere above about 500 km. Lower ionosphere density enhancements are inferred from HF-enhanced ion and plasma-line signals observed with UHF radar. Upper ionospheric density enhancements have been observed with TEC (total electron content) experiments by monitoring satellite radio beacons where signal paths traverse the HF-modified ionosphere. Both density enhancements and corresponding upward plasma fluxes have also been observed in the upper ionosphere via in-situ satellite observations. The data presented focus mainly on observations near the third and fourth gyro-harmonics. The specific values of the height-dependent gyro-harmonics have been computed from a magnetic model of the field line through the HF heated volume. Experiments with several closely spaced HF frequencies around the gyro-harmonic frequency region show that the magnitude of the lower-ionosphere artificial ionization production maximizes for HF frequencies about 1.0 - 1.5 MHz above the gyro-harmonic frequency. The response is progressively larger as the HF frequency is increased in the frequency region near the gyro-harmonics. For HF frequencies that are initially greater than the gyro-harmonic value the UHF radar scattering cross-section is relatively small, and non-existent or very weak signals are observed; as the signal returns drop in altitude due to density enhancements the HF interaction region passes through lower altitudes where the HF frequency is less than the gyro-harmonic value, for these conditions the radar scattering cross-section is

  20. Graphene contacts to a HfSe2/SnS2 heterostructure

    Science.gov (United States)

    Su, Shanshan; Das, Protik; Ge, Supeng; Lake, Roger K.

    2017-02-01

    Two-dimensional (2D) heterostructures and all-2D contacts are of high interest for electronic device applications, and the SnS2/HfSe2 bilayer heterostructure with graphene contacts has some unique, advantageous properties. The SnS2/HfSe2 heterostructure is interesting because of the strong intermixing of the two conduction bands and the large work function of the SnS2. The band lineup of the well separated materials indicates a type II heterostructure, but the conduction band minimum of the SnS2/HfSe2 bilayer is a coherent superposition of the orbitals from the two layers with a spectral weight of 60% on the SnS2 and 40% on the HfSe2 for AA stacking. These relative weights can be either increased or reversed by an applied vertical field. A 3 ×3 supercell of graphene and a 2 ×2 supercell of SnS2/HfSe2 have a lattice mismatch of 0.1% and both the SnS2/HfSe2 conduction band at M and the graphene Dirac point at K are zone-folded to Γ . Placing graphene on the SnS2/HfSe2 bilayer results in large n-type charge transfer doping of the SnS2/HfSe2 bilayer, on the order of 1013/cm2, and the charge transfer is accompanied by a negative Schottky barrier contact for electron injection from the graphene into the SnS2/HfSe2 bilayer conduction band. Binding energies and the anti-crossing gaps of the graphene and the SnS2/HfSe2 electronic bands both show that the coupling of graphene to the HfSe2 layer is significantly larger than its coupling to the SnS2 layer. A tunneling Hamiltonian estimate of the contact resistance of the graphene to the SnS2/HfSe2 heterostructure predicts an excellent low-resistance contact.

  1. Control of photoassociation reaction F+H→HF with ultrashort laser pulse

    Institute of Scientific and Technical Information of China (English)

    2007-01-01

    The laser-induced vibrational state-selectivity of product HF in photoassociation reaction H+F→HF is theoretically investigated by using the time-dependent quantum wave packet method. The population transfer process from the continuum state down to the bound vibrational states can be controlled by the driving laser. The effects of laser pulse parameters and the initial momentum of the two collision atoms on the vibrational population of the product HF are discussed in detail. Photodissociation accompanied with the photoassociation process is also described.

  2. [18F]Fluoride recovery via gaseous [18F]HF

    DEFF Research Database (Denmark)

    Mathiessen, Bente; Jensen, Mikael; Zhuravlev, Fedor

    2011-01-01

    Acidification of target water with H2SO4 in a specially constructed glassy carbon/polyethylene apparatus allowed for recovery of up to 82% of [18F]fluoride as [18F]HF gas. The [18F]HF distillate was found to be acid-free but moist; when passed through a solution of tBuPh2SiOTf, it yielded [18F......]tBuPh2SiF. The multivariate design of experiment showed that the key to high yield of [18F]HF was the efficient degassing of the reaction mixture....

  3. The role of phosphates for the Lu-Hf chronology of meteorites

    Science.gov (United States)

    Debaille, Vinciane; Van Orman, James; Yin, Qing-Zhu; Amelin, Yuri

    2017-09-01

    The 176Lu-176Hf isotopic system is widely used for dating and tracing cosmochemical and geological processes, but still suffers from two uncertainties. First, Lu-Hf isochrons for some early Solar System materials have excess slope of unknown origin that should not be expected for meteorites with ages precisely determined with other isotopic chronometers. This observation translates to an apparent Lu decay constant higher than the one calculated by comparing ages obtained with various dating methods on terrestrial samples. Second, unlike the well constrained Sm/Nd value (to within 2%) for the chondritic uniform reservoir (CHUR), the Lu/Hf ratios in chondrites vary up to 18% when considering all chondrites, adding uncertainty to the Lu/Hf CHUR value. In order to better understand the Lu-Hf systematics of chondrites, we analyzed mineral fractions from the Richardton H5 chondrite to construct an internal Lu-Hf isochron, and set up a numerical model to investigate the effect of preferential diffusion of Lu compared to Hf from phosphate, the phase with the highest Lu-Hf ratio in chondrites, to other minerals. The isochron yields an age of 4647 ± 210 million years (Myr) using the accepted 176Lu decay constant of 1.867 ± 0.008 ×10-11yr-1. Combining this study with the phosphate fractions measured in a previous study yields a slope of 0.08855 ± 0.00072, translating to a 176Lu decay constant of 1.862 ± 0.016 ×10-11yr-1 using the Pb-Pb age previously obtained, in agreement with the accepted value. The large variation of the Lu/Hf phosphates combined with observations in the present study identify phosphates as the key in perturbing Lu-Hf dating and generating the isochron slope discrepancy. This is critical as apatite has substantially higher diffusion rates of rare earth elements than most silicate minerals that comprise stony meteorites. Results of numerical modeling depending of temperature peak, size of the grains and duration of the metamorphic event, show that

  4. Interaction of La2O3 capping layers with HfO2 gate dielectrics

    Science.gov (United States)

    Copel, M.; Guha, S.; Bojarczuk, N.; Cartier, E.; Narayanan, V.; Paruchuri, V.

    2009-11-01

    We report the effect of La2O3 capping layers on HfO2/SiO2/Si dielectrics, proposed for use in threshold voltage tuning of field effect transistors. Depth profiling with medium energy ion scattering shows that an initial surface layer of La2O3 diffuses through the HfO2 at elevated temperatures, ultimately converting some of the thin interfacial SiO2 into a silicate. Core-level photoemission measurements indicate that the additional band-bending induced by the La2O3 only appears after diffusion, and the added charge resides between the HfO2 and the substrate.

  5. Diversity and abundance of ammonia-oxidizing

    NARCIS (Netherlands)

    Cardoso, J.F.M.F.; van Bleijswijk, J.D.L.; Witte, H.; van Duyl, F.C.

    2013-01-01

    We analysed the diversity and abundance of ammonia-oxidizing Archaea (AOA) and Bacteria (AOB) in the shallow warm-water sponge Halisarca caerulea and the deep cold-water sponges Higginsia thielei and Nodastrella nodastrella. The abundance of AOA and AOB was analysed using catalyzed reporter

  6. Climate and local abundance in freshwater fishes.

    Science.gov (United States)

    Knouft, Jason H; Anthony, Melissa M

    2016-06-01

    Identifying factors regulating variation in numbers of individuals among populations across a species' distribution is a fundamental goal in ecology. A common prediction, often referred to as the abundant-centre hypothesis, suggests that abundance is highest near the centre of a species' range. However, because of the primary focus on the geographical position of a population, this framework provides little insight into the environmental factors regulating local abundance. While range-wide variation in population abundance associated with environmental conditions has been investigated in terrestrial species, the relationship between climate and local abundance in freshwater taxa across species' distributions is not well understood. We used GIS-based temperature and precipitation data to determine the relationships between climatic conditions and range-wide variation in local abundance for 19 species of North American freshwater fishes. Climate predicted a portion of the variation in local abundance among populations for 18 species. In addition, the relationship between climatic conditions and local abundance varied among species, which is expected as lineages partition the environment across geographical space. The influence of local habitat quality on species persistence is well documented; however, our results also indicate the importance of climate in regulating population sizes across a species geographical range, even in aquatic taxa.

  7. Abundant Semigroups with a Multiplicative Adequate Transversal

    Institute of Scientific and Technical Information of China (English)

    GUO Xiao Jiang

    2002-01-01

    The aim of this paper is to investigate abundant semigroups with a multiplicative adequate transversal. Some properties and characterizations for such semigroups are obtained. In particular,we establish the structure of this class of abundant semigroups in terms of left normal bands, right normal bands and adequate semigroups with some simple compatibility conditions. Finally, we apply this structure to some special cases.

  8. Diversity and abundance of ammonia-oxidizing

    NARCIS (Netherlands)

    Cardoso, J.F.M.F.; van Bleijswijk, J.D.L.; Witte, H.; van Duyl, F.C.

    2013-01-01

    We analysed the diversity and abundance of ammonia-oxidizing Archaea (AOA) and Bacteria (AOB) in the shallow warm-water sponge Halisarca caerulea and the deep cold-water sponges Higginsia thielei and Nodastrella nodastrella. The abundance of AOA and AOB was analysed using catalyzed reporter depositi

  9. Resource Abundance and Resource Dependence in China

    NARCIS (Netherlands)

    Ji, K.; Magnus, J.R.; Wang, W.

    2010-01-01

    This paper reconsiders the ‘curse of resources’ hypothesis for the case of China, and distinguishes between resource abundance, resource rents, and resource dependence. Resource abundance and resource rents are shown to be approximately equivalent, and their association with resource dependence vari

  10. On the Solar Nickel and Oxygen Abundances

    Science.gov (United States)

    Scott, Pat; Asplund, Martin; Grevesse, Nicolas; Sauval, A. Jacques

    2009-02-01

    Determinations of the solar oxygen content relying on the neutral forbidden transition at 630 nm depend upon the nickel abundance, due to a Ni I blend. Here, we rederive the solar nickel abundance, using the same ab initio three-dimensional hydrodynamic model of the solar photosphere employed in the recent revision of the abundances of C, N, O, and other elements. Using 17 weak, unblended lines of Ni I together with the most accurate atomic and observational data available, we find log epsilonNi = 6.17 ± 0.02(statistical) ± 0.05(systematic), a downward shift of 0.06-0.08 dex relative to previous abundances based on one-dimensional model atmospheres. We investigate the implications of the new nickel abundance for studies of the solar oxygen abundance based on the [O I] 630 nm line in the quiet Sun. Furthermore, we demonstrate that the oxygen abundance implied by the recent sunspot spectropolarimetric study of Centeno & Socas-Navarro needs to be revised downward from log epsilonO = 8.86 ± 0.07 to 8.71 ± 0.10. This revision is based on the new nickel abundance, the application of the best available gf value for the 630 nm forbidden oxygen line, and a more transparent treatment of CO formation. Determinations of the solar oxygen content relying on forbidden lines now appear to converge around log epsilonO = 8.7.

  11. Diversity and abundance of ammonia-oxidizing

    NARCIS (Netherlands)

    Cardoso, J.F.M.F.; van Bleijswijk, J.D.L.; Witte, H.; van Duyl, F.C.

    2013-01-01

    We analysed the diversity and abundance of ammonia-oxidizing Archaea (AOA) and Bacteria (AOB) in the shallow warm-water sponge Halisarca caerulea and the deep cold-water sponges Higginsia thielei and Nodastrella nodastrella. The abundance of AOA and AOB was analysed using catalyzed reporter depositi

  12. Behavior of reinforced concrete columns strenghtened by partial jacketing

    Directory of Open Access Journals (Sweden)

    D. B. FERREIRA

    Full Text Available This article presents the study of reinforced concrete columns strengthened using a partial jacket consisting of a 35mm self-compacting concrete layer added to its most compressed face and tested in combined compression and uniaxial bending until rupture. Wedge bolt connectors were used to increase bond at the interface between the two concrete layers of different ages. Seven 2000 mm long columns were tested. Two columns were cast monolithically and named PO (original column e PR (reference column. The other five columns were strengthened using a new 35 mm thick self-compacting concrete layer attached to the column face subjected to highest compressive stresses. Column PO had a 120mm by 250 mm rectangular cross section and other columns had a 155 mm by 250mm cross section after the strengthening procedure. Results show that the ultimate resistance of the strengthened columns was more than three times the ultimate resistance of the original column PO, indicating the effectiveness of the strengthening procedure. Detachment of the new concrete layer with concrete crushing and steel yielding occurred in the strengthened columns.

  13. Self-organizing strategies for a column-store database

    NARCIS (Netherlands)

    Ivanova, M.G.; Kersten, M.L.; Nes, N.J.

    2008-01-01

    Column-store database systems open new vistas for improved maintenance through self-organization. Individual columns are the focal point, which simplify balancing conflicting requirements. This work presents two workload-driven self-organizing techniques in a column-store, i.e. adaptive segmentation

  14. Mechanistic model for dispersion coefficients in bubble column

    CSIR Research Space (South Africa)

    Skosana, PJ

    2015-05-01

    Full Text Available A mechanistic model describing the mass and momentum exchange in bubble columns is proposed that is based on the observations that the gas distribution in a bubble column is not uniform across the column and that as a consequence large liquid...

  15. A first-principles high-pressure study of Hf2PX (X=B, C, N)

    Science.gov (United States)

    Li, Hui; Luo, Zhili; Liu, Zhe; Sun, Guodong; Wang, Zhenjun

    2017-06-01

    New members of MAX family Hf2PX (X=B, C, N) were studied by first-principles calculations under pressure range of 0-100 GPa. Their structural, elastic and electronic properties were reported. The results show that they are energetically stable at zero pressure and mechanically stable under pressure range from 0 to 100 GPa. It reveals that Hf2PB>Hf2PC>Hf2PN for the structural parameters of a and V, and Hf2PBpressure environments.

  16. Fabrication and characteristics of high-K HfO2 gate dielectrics on n-germanium

    Institute of Scientific and Technical Information of China (English)

    Han De-Dong; Kang Jin-Feng; Liu Xiao-Yan; Sun Lei; Luo Hao; Han Ru-Qi

    2007-01-01

    This paper reports that the high-K HfO2 gate dielectrics are fabricated on n-germanium substrates by sputtering Hf on Ge and following by a furnace annealing. The impacts of sputtering ambient, annealing ambient and annealing temperature on the electrical properties of high-K HfO2 gate dielectrics on germanium substrates are investigated.Experimental results indicate that high-K HfO2 gate dielectrics on germanium substrates with good electrical characteristics are obtained, the electrical properties of high-K HfO2 gate dielectrics is strongly correlated with sputtering ambient, annealing ambient and annealing temperature.

  17. Comparison between a spray column and a sieve tray column operating as liquid-liquid heat exchangers

    Science.gov (United States)

    Keller, A. S.; Jacobs, H. R.; Boehm, R. F.

    The reported investigation was conducted in connection with research intended to improve the efficiency of direct contact devices for geothermal and solar applications. The investigation had the objective to evaluate the effect of adding sieve trays to the laboratory column used in studies concerned with the development of models for spray column heat transfer. Hot water is pumped from a supply vessel into the top of the heat exchanger column where, as the continuous phase, it flows down through the column. The dispersed phase is kerosene. Using an identical pump to that used for the water, the kerosene flows into a dispersion plate in the bottom of the column. The droplets rise through the column and coalesce at the top. It was found that the heat transfer performance of the perforated plate column was significantly improved over that in a spray column for similar operating conditions.

  18. Enhanced nitrobenzene removal and column longevity by coupled abiotic and biotic processes in zero-valent iron column

    DEFF Research Database (Denmark)

    Yin, Weizhao; Wu, Jinhua; Huang, Weilin;

    2015-01-01

    /or co-precipitation and the reduction of NB to aniline (AN) via abiotic reaction in the abiotic column and via both abiotic and biotic reactions in the biotic column. Due to the interactive effect of ZVI and microorganisms, more effective iron consumption and more reactive minerals such as green rust......In this study, abiotic zero-valent iron (ZVI) column and biotic ZVI column were employed to investigate abiotic and biotic effects between iron and microorganisms on NB removal and column longevity. Physical removal and kinetics analysis revealed that NB was largely removed through adsorption and...... and iron sulfide were found in the biotic column. This led to approximately 50% higher total NB removal and 6 times higher AN production in the biotic column as compared to the abiotic column during the entire operation. According to the NB breakthrough curves, longer stability and longer life...

  19. Abundances and excitation of interstellar methyl formate

    Science.gov (United States)

    Churchwell, E.; Nash, A.; Rahe, J.; Walmsley, C. M.; Lochner, O.; Winnewisser, G.

    1980-01-01

    The detection of methyl formate (HCOOCH3) in four transitions toward Orion KL, in two transitions toward Sagitarrius B2, and in one transition toward W51 is reported. The column densities of HCOOCH3 are found to be surprisingly large (2-5 x 10 to the 14th per sq cm) in all three clouds. Stimulated emission in the 18 cm K doublet of HCOOCH3 toward Sagittarius B2 is clearly demonstrated. The relatively large column densities of HCOOCH3 in clouds outside the galactic-center region probably imply that this molecule is widely distributed in the galaxy, but the negative results in other clouds require lower column densities than in Orion by a factor of 0.5 or less. Two unidentified lines were detected in Orion, at approx. 91 and 99 GHz.

  20. Low modulus Ti-Nb-Hf alloy for biomedical applications.

    Science.gov (United States)

    González, M; Peña, J; Gil, F J; Manero, J M

    2014-09-01

    β-Type titanium alloys with a low elastic modulus are a potential strategy to reduce stress shielding effect and to enhance bone remodeling in implants used to substitute failed hard tissue. For biomaterial application, investigation on the mechanical behavior, the corrosion resistance and the cell response is required. The new Ti25Nb16Hf alloy was studied before and after 95% cold rolling (95% C.R.). The mechanical properties were determined by tensile testing and its corrosion behavior was analyzed by potentiostatic equipment in Hank's solution at 37°C. The cell response was studied by means of cytotoxicity evaluation, cell adhesion and proliferation measurements. The stress-strain curves showed the lowest elastic modulus (42GPa) in the cold worked alloy and high tensile strength, similar to that of Ti6Al4V. The new alloy exhibited better corrosion resistance in terms of open circuit potential (EOCP), but was similar in terms of corrosion current density (iCORR) compared to Ti grade II. Cytotoxicity studies revealed that the chemical composition of the alloy does not induce cytotoxic activity. Cell studies in the new alloy showed a lower adhesion and a higher proliferation compared to Ti grade II presenting, therefore, mechanical features similar to those of human cortical bone and, simultaneously, a good cell response.

  1. Anomalous phenomena on HF radio paths during geomagnetic disturbances

    Science.gov (United States)

    Blagoveshchenskii, D. V.

    2016-07-01

    We analyze ionospheric oblique sounding data on three high-latitude and one high-latitude-midlatitude HF radio paths for February 15 and 16, 2014, when two substorms and one magnetic storm occurred. We investigate cases of anomalous propagation of signals: their reflection from sporadic layer Es, lateral reflections, type "M" or "N" modes, the presence of traveling ionospheric disturbances, and the diffusivity of signals and triplets. The most significant results are the following. In geomagnetically undisturbed times, sporadic Es-layers with reduced maximum observed frequencies (MOF Es) on three high-latitude paths were observed in both days. The values of MOF Es during disturbances are large, which leads to the screening of other oblique sounding signals reflected from the ionosphere. On all four paths, the most frequently traveling ionospheric disturbances due to the terminator were observed in quiet hours from 03:00 to 15:00 UT on the first day and from 06:00 to 13:00 UT on the second day of the experiment. In addition, both the sunset terminator and the magnetic storm on the high-latitude-mid-latitude path were found to generate traveling ionospheric disturbances jointly. No such phenomenon was found on high-latitude paths.

  2. Large ionospheric disturbances produced by the HAARP HF facility

    Science.gov (United States)

    Bernhardt, Paul A.; Siefring, Carl L.; Briczinski, Stanley J.; McCarrick, Mike; Michell, Robert G.

    2016-07-01

    The enormous transmitter power, fully programmable antenna array, and agile frequency generation of the High Frequency Active Auroral Research Program (HAARP) facility in Alaska have allowed the production of unprecedented disturbances in the ionosphere. Using both pencil beams and conical (or twisted) beam transmissions, artificial ionization clouds have been generated near the second, third, fourth, and sixth harmonics of the electron gyrofrequency. The conical beam has been used to sustain these clouds for up to 5 h as opposed to less than 30 min durations produced using pencil beams. The largest density plasma clouds have been produced at the highest harmonic transmissions. Satellite radio transmissions at 253 MHz from the National Research Laboratory TACSat4 communications experiment have been severely disturbed by propagating through artificial plasma regions. The scintillation levels for UHF waves passing through artificial ionization clouds from HAARP are typically 16 dB. This is much larger than previously reported scintillations at other HF facilities which have been limited to 3 dB or less. The goals of future HAARP experiments should be to build on these discoveries to sustain plasma densities larger than that of the background ionosphere for use as ionospheric reflectors of radio signals.

  3. Equatorial ionospheric disturbance observed through a transequatorial HF propagation experiment

    Directory of Open Access Journals (Sweden)

    T. Maruyama

    2006-07-01

    Full Text Available A transequatorial radio-wave propagation experiment at shortwave frequencies (HF-TEP was done between Shepparton, Australia, and Oarai, Japan, using the radio broadcasting signals of Radio Australia. The receiving facility at Oarai was capable of direction finding based on the MUSIC (Multiple Signal Classification algorithm. The results were plotted in azimuth-time diagrams (AT plots. During the daytime, the propagation path was close to the great circle connecting Shepparton and Oarai, thus forming a single line in the AT plots. After sunset, off-great-circle paths, or satellite traces in the AT plot, often appeared abruptly to the west and gradually returned to the great circle direction. However, there were very few signals across the great circle to the east. The off-great-circle propagation was very similar to that previously reported and was attributed to reflection by an ionospheric structure near the equator. From the rate of change in the direction, we estimated the drift velocity of the structure to range mostly from 100 to 300 m/s eastward. Multiple instances of off-great-circle propagation with a quasi-periodicity were often observed and their spatial distance in the east-west direction was within the range of large-scale traveling ionospheric disturbances (LS-TIDs. Off-great-circle propagation events were frequently observed in the equinox seasons. Because there were many morphological similarities, the events were attributed to the onset of equatorial plasma bubbles.

  4. The effect of column purification on cDNA indirect labelling for microarrays

    Directory of Open Access Journals (Sweden)

    Kiss John Z

    2007-06-01

    Full Text Available Abstract Background The success of the microarray reproducibility is dependent upon the performance of standardized procedures. Since the introduction of microarray technology for the analysis of global gene expression, reproducibility of results among different laboratories has been a major problem. Two of the main contributors to this variability are the use of different microarray platforms and different laboratory practices. In this paper, we address the latter question in terms of how variation in one of the steps of a labelling procedure affects the cDNA product prior to microarray hybridization. Results We used a standard procedure to label cDNA for microarray hybridization and employed different types of column chromatography for cDNA purification. After purifying labelled cDNA, we used the Agilent 2100 Bioanalyzer and agarose gel electrophoresis to assess the quality of the labelled cDNA before its hybridization onto a microarray platform. There were major differences in the cDNA profile (i.e. cDNA fragment lengths and abundance as a result of using four different columns for purification. In addition, different columns have different efficiencies to remove rRNA contamination. This study indicates that the appropriate column to use in this type of protocol has to be experimentally determined. Finally, we present new evidence establishing the importance of testing the method of purification used during an indirect labelling procedure. Our results confirm the importance of assessing the quality of the sample in the labelling procedure prior to hybridization onto a microarray platform. Conclusion Standardization of column purification systems to be used in labelling procedures will improve the reproducibility of microarray results among different laboratories. In addition, implementation of a quality control check point of the labelled samples prior to microarray hybridization will prevent hybridizing a poor quality sample to expensive

  5. Formation of Al2O3-HfO2 Eutectic EBC Film on Silicon Carbide Substrate

    Directory of Open Access Journals (Sweden)

    Kyosuke Seya

    2015-01-01

    Full Text Available The formation mechanism of Al2O3-HfO2 eutectic structure, the preparation method, and the formation mechanism of the eutectic EBC layer on the silicon carbide substrate are summarized. Al2O3-HfO2 eutectic EBC film is prepared by optical zone melting method on the silicon carbide substrate. At high temperature, a small amount of silicon carbide decomposed into silicon and carbon. The components of Al2O3 and HfO2 in molten phase also react with the free carbon. The Al2O3 phase reacts with free carbon and vapor species of AlO phase is formed. The composition of the molten phase becomes HfO2 rich from the eutectic composition. HfO2 phase also reacts with the free carbon and HfC phase is formed on the silicon carbide substrate; then a high density intermediate layer is formed. The adhesion between the intermediate layer and the substrate is excellent by an anchor effect. When the solidification process finished before all of HfO2 phase is reduced to HfC phase, HfC-HfO2 functionally graded layer is formed on the silicon carbide substrate and the Al2O3-HfO2 eutectic structure grows from the top of the intermediate layer.

  6. Effects of Modified Precursor Solution on Microstructure of (Y,Yb)MnO3/HfO2/Si

    Science.gov (United States)

    Suzuki, Kazuyuki; Kato, Kazumi

    2007-10-01

    Ferroelectric/insulator/silicon structures were prepared using (Y,Yb)MnO3 films as ferroelectrics and HfO2 thin films as insulators through alkoxy-derived precursor solutions. The HfO2 solution was chemically modified in order to decrease the number of heating cycles required. The HfO2 films prepared using a partially hydrolyzed alkoxide solution had a uniform structure. From the results of measurements of the roughness level and refractive index of the HfO2 films, the partial hydrolysis of the HfO2 solution was found to be effective for the formation of a uniform microstructure in a thin insulator film. (Y,Yb)MnO3/HfO2/Si structures were constructed using the resultant HfO2 thin films prepared using the modified solutions.

  7. Effects of C and Hf concentration on phase relations and microstructure of a wrought powder-metallurgy superalloy

    Science.gov (United States)

    Miner, R. V., Jr.

    1977-01-01

    NASA IIB-11, a candidate alloy for advanced temperature turbine engine disks, and four modifications with varying C and Hf concentrations were produced from prealloyed powders. Several notable effects of C and Hf concentration in the alloys were observed. Both the amount of the gamma-prime phase and its solvus temperature increased with decreasing C, but only the gamma-prime solvus was affected by Hf, increasing with increasing Hf. Hf also promoted a cellular gamma-prime precipitation. Hf was, however, about equally distributed between gamma-prime and gamma. Hf and C both affected the carbides formed. Increasing both promoted formation of an MC relative to that of an M6C.

  8. The Modulation of Ionospheric Alfvén Resonator on Heating HF Waves and the Doppler Effect

    Institute of Scientific and Technical Information of China (English)

    Ni Bin-bin; Zhao Zheng-yu; Xie Shu-guo

    2003-01-01

    Abstract: The propagation of HF waves in IAR can produce many nonlinear effects, including the modulation effect of IAR on HF waves and the Doppler effect. To start with the dependence of the ionospheric electron temperature variaof the modulation effect and lucubrate possible reasons for the field can have an observable modulation effect on HF waves while its mechanism is quite different from that of Schumann resonant field on HF waves. The depth of modulation of IAR field, which directly inspires the formation of cross-spectrum between ULF waves and HF waves and results in spectral peaks at some gyro-frequencies of IAR. With respect to the Doppler effect during the propagation of HF waves in IAR, it is mainly caused by the motion of the high-speed flyer and the drifting electrons and the frequency shift from the phase variation of the reflected waves can be neglected when the frequency of HF incident wave is high enough.

  9. From Single Droplet to Column Design

    Institute of Scientific and Technical Information of China (English)

    2006-01-01

    The technique state to design counter-current extraction columns is based on the performance of pilot plant experiments. The modelling is then either with the equilibrium or dispersion model, whereas in the latter the dispersion coefficient accounts for all hydrodynamic non-idealities. A new approach uses single droplet experiments to obtain the basic laws and functions governing droplet breakage, coalescence,relative velocity, and axial dispersion when using droplet populance balance models (DPBM). The hydrodynamics simulation results show that the mean Sauter diameter, hold-up, and concentration profiles could be well predicted, which promotes the use of DPBM models for further applications in industrial scale.

  10. Column: The Physics of Digital Information

    Directory of Open Access Journals (Sweden)

    Fred Cohen

    2011-09-01

    Full Text Available One of the interesting questions underlying creating a science of digital forensics is what form that science might take. At the end of the IEEE Oakland Conference in 2011, I presented some of the underlying questions and identified my approach and why I favored it.2 My basic position is that science is about causality and a scientific theory should require that cause(C produces effect (E via mechanism M (written C→ME. The scientific method then identifies the criteria for rejecting (refuting or accepting (for a time a scientific theory.(see PDF for full column

  11. Lattice approaches to packed column simulations

    Institute of Scientific and Technical Information of China (English)

    2008-01-01

    This work presents a review of the findings into the ability of a digitally based particle packing algorithm, called DigiPac, to predict bed structure in a variety of packed columns, for a range of generic pellet shapes frequently used in the chemical and process engineering industries.Resulting macroscopic properties are compared with experimental data derived from both invasive and non-destructive measurement techniques.Additionally, fluid velocity distributions, through samples of the resulting bed structures, are analysed using lattice Boltzmann method (LBM) simulations and are compared against experimental data from the literature.

  12. Hydrodynamic Study Of Column Bioleaching Processes

    Directory of Open Access Journals (Sweden)

    Sadowski Zygmunt

    2015-06-01

    Full Text Available The modelling of flow leaching solution through the porous media has been considered. The heap bioleaching process can be tested using the column experimental equipment. This equipment was employed to the hydrodynamic studies of copper ore bioleaching. The copper ore (black shale ore with the support, inertial materials (glass small balls and polyethylene beads was used to the bioleaching tests. The packed beds were various composition, the ore/support ratio was changed. The correlation between the bed porosity and bioleaching kinetics, and copper recovery was investigated.

  13. Preinjector for Linac 1, accelerating column

    CERN Multimedia

    1974-01-01

    For a description of the Linac 1 preinjector, please see first 7403070X. High up on the wall of the Faraday cage (7403073X) is this drum-shaped container of the ion source (7403083X). It is mounted at the HV end of the accelerating column through which the ions (usually protons; many other types of ions in the course of its long history) proceed through the Faraday cage wall to the low-energy end (at ground potential) of Linac 1. The 520 kV accelerating voltage was supplied by a SAMES generator (7403074X).

  14. Water column anoxia, enhanced productivity, and concomitant changes in δ13C and δ34S across the Frasnian-Famennian boundary (Kowala - Holy Cross Mountains/Poland)

    NARCIS (Netherlands)

    Sinninghe Damsté, J.S.; Joachimski, M.M.; Ostertag-Henning, C.; Pancost, R.D.; Strauss, H.; Freeman, K.; Littke, R.; Racki, G.

    2001-01-01

    The investigation of the trace element and organic geochemistry of the Frasnian Famennian boundary section at Kowala (Holy Cross Mountains/Poland) shows that the lower water column was oxygen-deficient during late Frasnian and early Famennian times. The abundance and carbon isotopic composition of d

  15. Palaeoproterozoic continental arc magmatism, and Neoproterozoic metamorphism in the Aravalli-Delhi orogenic belt, NW India: New constraints from in situ zircon U-Pb-Hf isotope systematics, monazite dating and whole-rock geochemistry

    Science.gov (United States)

    Kaur, Parampreet; Zeh, Armin; Chaudhri, Naveen

    2017-04-01

    Presently, the extent, origin and petrogenesis of late Palaeoproterozoic (ca. 1.85 Ga) magmatism in the north-central Aravalli-Delhi orogenic belt, NW India and subsequent metamorphic overprints are poorly constrained. Results of new in situ zircon U-Pb-Hf isotope analyses in combination with whole-rock elemental and isotopic data provide the first hard evidence that granitoid magmatism occurred in a continental magmatic arc setting between 1.86 and 1.81 Ga. The Hf-Nd model ages of 3.0-2.6 Ga and inherited zircon grains of 3.3-2.5 Ga indicate abundant reworking of Archaean crust. Flat HREE patterns with negative Eu anomalies furthermore reveal that the granitoids were generated from garnet-free and plagioclase-rich sources at shallow depths. Significant isotope variation among granitoid samples (εHft = -3.7 to -9.0; εNdt = -4.8 to -7.9) indicate that the reworked Archaean crust was not completely homogenised during the Palaeoproterozoic. This is best reflected by zircon Hf-isotope variation of ca. 9.5 epsilon units within the oldest granitoid sample. Zircon grains from this sample define three discrete Hf-isotope groups at εHf1.86Ga = -8.9, -4.8 and -1.6. These are interpreted to result from mixing of zircon-saturated magmas derived from three distinct sources within the crust prior to solidification. A monazite U-Pb isochron age of 868 ± 4 Ma from one of the granitoid samples furthermore indicates that the Aravalli fold belt was affected by an important post-magmatic overprint, perhaps related to the widespread metasomatic, granulite metamorphic and/or magmatic events during the same time span.

  16. Development of an automated batch-type solid-liquid extraction apparatus and extraction of Zr, Hf, and Th by triisooctylamine from HCl solutions for chemistry of element 104, Rf

    Energy Technology Data Exchange (ETDEWEB)

    Kasamatsu, Yoshitaka; Kino, Aiko; Yokokita, Takuya [Osaka Univ. (Japan). Graduate School of Science; and others

    2015-07-01

    Solid-liquid extraction of the group 4 elements Zr and Hf, which are homologues of Rf (Z = 104), and Th, a pseudo homologue, by triisooctylamine (TIOA) from HCl solutions was performed by batch method. After examining the time required to reach extraction equilibrium for these elements in various concentrations of TIOA and HCl, we investigated in detail variations in the distribution coefficients (K{sub d}) with TIOA and HCl concentrations. The K{sub d} values of Zr and Hf increased with increasing the HCl and TIOA concentrations, suggesting an increase in the abundance of the anionic chloride complexes of Zr and Hf. On the other hand, the K{sub d} values of Th were low in all the HCl concentrations studied, implying that Th does not form anionic species dominantly. We developed a new automated batch-type solid-liquid extraction apparatus for repetitive experiments on transactinide elements. Using this apparatus, we performed solid-liquid extraction employing the radioactive nuclides {sup 89m}Zr and {sup 175}Hf produced by nuclear reactions and transported continuously from the nuclear reaction chamber by the He/KCl gas-jet system. It was found that the distribution behaviors in 7-11 M HCl are almost constant in the time range 10-120 s, and the K{sub d} values are consistent with those obtained in the above manual experiment. This result suggests that the chemical reactions in the extraction process reach equilibrium within 10 s for Zr and Hf under the present experimental conditions. It took about 35 s for the extraction using the apparatus. These results indicate the applicability of the present extraction using the developed apparatus to {sup 261}Rf (T{sub 1/2} = 68 s) experiments.

  17. Hydrodynamics and Mass Transfer Performance in Supercritical Fluid Extraction Columns

    Institute of Scientific and Technical Information of China (English)

    石冰洁; 张泽廷; 等

    2002-01-01

    New models for describing hydrodynamics and mass transfer performance in supercritical fluid extraction columns were proposed.Those models were proved by experimental data,which were obtained in supercritical fluid extraction packed column,spray column and sieve tray column respectively.The inner diameter of those columns areΦ25mm,These experimental systems include supercritical carbon dioxideisopropanol-water and supercritical carbon dioxide-ethanol-water,in which supercritical carbon dioxide was dispersed phase,and another was continuous phase.The extraction processes were operated with continuous countercurrent flow.The predicted values are agreed well with experimental data.

  18. Ferroelectric modulation of terahertz waves with graphene/ultrathin-Si:HfO2/Si structures

    Science.gov (United States)

    Jiang, Ran; Han, Zuyin; Sun, Weideng; Du, Xianghao; Wu, Zhengran; Jung, Hyung-Suk

    2015-10-01

    Ferroelectric-field-effect-tunable modulation of terahertz waves in graphene/Si:HfO2/Si stack structure was observed. The modulation shows distinct behaviors when the samples under different gate polarities. At a negative voltage, a transmission modulation depth up to ˜74% was present without depending on the photo illumination power, whereas, at a positive voltage, the modulation of Thz wave shows dependence on the illumination power, which is ascribed to the creation/elimination of an extra barrier in Si layer in response to the polarization in the ferroelectric Si:HfO2 layer. Considering the good compatibility of HfO2 on Si-based semiconductor process, the ferroelectricity layer of Si:HfO2 may open up an avenue for the tunable modulation of Thz wave.

  19. Modulation of auroral electrojet currents using dual HF beams with ELF phase offset

    Science.gov (United States)

    Golkowski, M.; Cohen, M.; Moore, R. C.

    2012-12-01

    The modulation of naturally occuring ionospheric currents with high power radio waves in the high frequency (HF, 3-10 MHz) band is a well known technique for generation of extremely low frequency (ELF, 3-3000 Hz) and very low frequency (VLF, 3-30 kHz) waves. We use the heating facility of the High Frequency Active Auroral Research Program (HAARP) to investigate the effect of using dual HF beams with an ELF/VLF phase offset between the modulation waveforms. Experiments with offset HF beams confirm the model of independent ELF/VLF sources. Experiments with co-located HF beams exhibit interaction between the first and second harmonics of the modulated tones when square and sine wave modulation waveforms are employed. Using ELF/VLF phase offsets for co-loacted beams is also shown to be a potential diagnostic for the D-region ionospheric profile.

  20. Hf diffusion in dilute Fe-free Zr(Nb) alloys

    Energy Technology Data Exchange (ETDEWEB)

    Zou, H.; Hood, G.M.; Roy, J.A.; Schultz, R.J. [Atomic Energy of Canada Ltd., Chalk River, ON (Canada). Chalk River Nuclear Labs.; Jackman, J.A. [Canada Centre for Mineral and Energy Technology, Ottawa, ON (Canada)

    1995-04-01

    Hf diffusion coefficients D have been measured in the {alpha}-phase of the Fe-free binary alloys Zr-1.0 at.% Nb and Zr-2.5 at.% Nb in the temperature range 830-1100 K. The D values for the two alloys are essentially indistinguishable and little different from extant Hf diffusion coefficients measured in Fe-free polycrystalline {alpha}-Zr. The temperature dependence of D in the alloys is characteristic of intrinsic {alpha}-Zr bulk behaviour. The present hf D values are much lower than corresponding values measured in commercial Zr-2.5 Nb. The difference is attributable to the influence of solid-solution Fe. In addition, the absence of a strong enhancement of Hf diffusion in {alpha}-Zr by Nb suggests that intrinsic Nb diffusion in {alpha}-Zr may not be controlled by a normal vacancy mechanism. (author).