WorldWideScience

Sample records for heterogeneous plume chemistry

  1. Micro-physics of aircraft-generated aerosols and their potential impact on heterogeneous plume chemistry

    Energy Technology Data Exchange (ETDEWEB)

    Kaercher, B.; Luo, B.P. [Muenchen Univ., Freising (Germany). Lehrstuhl fuer Bioklimatologie und Immissionsforschung

    1997-12-31

    Answers are attempted to give to open questions concerning physico-chemical processes in near-field aircraft plumes, with emphasis on their potential impact on subsequent heterogeneous chemistry. Research issues concerning the nucleation of aerosols and their interactions among themselves and with exhaust gases are summarized. Microphysical properties of contrail ice particles, formation of liquid ternary mixtures, and nucleation of nitric acid trihydrate particles in contrails are examined and possible implications for heterogeneous plume chemistry are discussed. (author) 19 refs.

  2. Hydrogen chloride heterogeneous chemistry on frozen water particles in subsonic aircraft plume. Laboratory studies and modelling

    Energy Technology Data Exchange (ETDEWEB)

    Persiantseva, N.V.; Popovitcheva, O.B.; Rakhimova, T.V. [Moscow State Univ. (Russian Federation)

    1997-12-31

    Heterogeneous chemistry of HCl, as a main reservoir of chlorine content gases, has been considered after plume cooling and ice particle formation. The HCl, HNO{sub 3}, N{sub 2}O{sub 5} uptake efficiencies by frozen water were obtained in a Knudsen-cell flow reactor at the subsonic cruise conditions. The formation of ice particles in the plume of subsonic aircraft is simulated to describe the kinetics of gaseous HCl loss due to heterogeneous processes. It is shown that the HCl uptake by frozen water particles may play an important role in the gaseous HCl depletion in the aircraft plume. (author) 14 refs.

  3. Chemistry in aircraft plumes

    Energy Technology Data Exchange (ETDEWEB)

    Kraabol, A.G.; Stordal, F.; Knudsen, S. [Norwegian Inst. for Air Research, Kjeller (Norway); Konopka, P. [Deutsche Forschungsanstalt fuer Luft- und Raumfahrt e.V. (DLR), Wessling (Germany). Inst. fuer Physik der Atmosphaere

    1997-12-31

    An expanding plume model with chemistry has been used to study the chemical conversion of NO{sub x} to reservoir species in aircraft plumes. The heterogeneous conversion of N{sub 2}O{sub 5} to HNO{sub 3}(s) has been investigated when the emissions take place during night-time. The plume from an B747 has been simulated. During a ten-hour calculation the most important reservoir species was HNO{sub 3} for emissions at noon. The heterogeneous reactions had little impact on the chemical loss of NO{sub x} to reservoir species for emissions at night. (author) 4 refs.

  4. Microphysics and heterogeneous chemistry in aircraft plumes - high sensitivity on local meteorology and atmospheric composition

    Directory of Open Access Journals (Sweden)

    S. K. Meilinger

    2005-01-01

    Full Text Available An aircraft plume model has been developed on the basis of two coupled trajectory box models. Two boxes, one for plume and one for background conditions, are coupled by means of a mixing parameterization based on turbulence theory. The model considers comprehensive gas phase chemistry for the tropopause region including acetone, ethane and their oxidation products. Heterogeneous halogen, N2O5 and HOx chemistry on various types of background and aircraft-induced aerosols (liquid and ice is considered, using state-of-the-art solubility dependent uptake coefficients for liquid phase reactions. The microphysical scheme allows for coagulation, gas-diffusive particle growth and evaporation, so that the particle development from 1s after emission to several days can be simulated. Model results are shown, studying emissions into the upper troposphere as well as into the lowermost stratosphere for contrail and non-contrail conditions. We show the microphysical and chemical evolution of spreading plumes and use the concept of mean plume encounter time, tl, to define effective emission and perturbation indices (EEIs and EPIs for the North Atlantic Flight Corridor (NAFC showing EEI(NOy and EPI(O3 for various background conditions, such as relative humidity, local time of emission, and seasonal variations. Our results show a high sensitivity of EEI and EPIs on the exact conditions under which emissions take place. The difference of EEIs with and without considering plume processes indicates that these processes cannot be neglected.

  5. Halogen Chemistry in Volcanic Plumes (Invited)

    Science.gov (United States)

    Roberts, Tjarda

    2017-04-01

    Volcanoes release vast amounts of gases and particles in the atmosphere. Volcanic halogens (HF, HCl, HBr, HI) are co-emitted alongside SO2, and observations show rapid formation of BrO and OClO in the plume as it disperses into the troposphere. The development of 1D and Box models (e.g. PlumeChem) that simulate volcanic plume halogen chemistry aims to characterise how volcanic reactive halogens form and quantify their atmospheric impacts. Following recent advances, these models can broadly reproduce the observed downwind BrO/SO2 ratios using "bromine-explosion" chemistry schemes, provided they use a "high-temperature initialisation" to inject radicals (OH, Cl, Br and possibly NOx) which "kick-start" the low-temperature chemistry cycles that convert HBr into reactive bromine (initially as Br2). The modelled rise in BrO/SO2 and subsequent plateau/decline as the plume disperses downwind reflects cycling between reactive bromine, particularly Br-BrO, and BrO-HOBr-BrONO2. BrCl is produced when aerosol becomes HBr-depleted. Recent model simulations suggest this mechanism for reactive chlorine formation can broadly account for OClO/SO2 reported at Mt Etna. Predicted impacts of volcanic reactive halogen chemistry include the formation of HNO3 from NOx and depletion of ozone. This concurs with HNO3 widely reported in volcanic plumes (although the source of NOx remains under question), as well as observations of ozone depletion reported in plumes from several volcanoes (Mt Redoubt, Mt Etna, Eyjafjallajokull). The plume chemistry can transform mercury into more easily deposited and potentially toxic forms, for which observations are limited. Recent incorporation of volcanic halogen chemistry in a 3D regional model of degassing from Ambrym (Vanuatu) also predicts how halogen chemistry causes depletion of OH to lengthen the SO2 lifetime, and highlights the potential for halogen transport from the troposphere to the stratosphere. However, the model parameter-space is vast and

  6. Plume dynamics in heterogeneous porous media

    Science.gov (United States)

    Neufeld, Jerome A.; Huppert, Herbert E.

    2008-11-01

    Buoyancy driven flows in layered porous media are present in many geological settings and play an important role in the mixing of fluids, from the dispersal of pollutants in underground aquifers to enhanced oil recovery techniques and, of more recent importance, the sequestration of carbon dioxide (CO2). Seismic images of the rise of a buoyant CO2 plume at Sleipner in the North Sea indicate that these plumes are greatly influenced by a vertical array of thin lenses of relatively low permeability material. We model propagation of CO2 at each layer as a gravity current in a porous medium which propagates along, and drains through, a thin, low permeability seal. Drainage, driven both by hydrostatic pressure and the body force on the draining fluid, leads to an initial rapid advance followed by a gradual retreat of the current to a steady-state. By incorporating a vertical array of these single layer models we are able to capture the rise of the buoyant plume in layered reservoirs. We find that the plume is characterized by a broad head with a tail given by the steady state extent.

  7. Global volcanic emissions: budgets, plume chemistry and impacts

    Science.gov (United States)

    Mather, T. A.

    2012-12-01

    Over the past few decades our understanding of global volcanic degassing budgets, plume chemistry and the impacts of volcanic emissions on our atmosphere and environment has been revolutionized. Global volcanic emissions budgets are needed if we are to make effective use of regional and global atmospheric models in order to understand the consequences of volcanic degassing on global environmental evolution. Traditionally volcanic SO2 budgets have been the best constrained but recent efforts have seen improvements in the quantification of the budgets of other environmentally important chemical species such as CO2, the halogens (including Br and I) and trace metals (including measurements relevant to trace metal atmospheric lifetimes and bioavailability). Recent measurements of reactive trace gas species in volcanic plumes have offered intriguing hints at the chemistry occurring in the hot environment at volcanic vents and during electrical discharges in ash-rich volcanic plumes. These reactive trace species have important consequences for gas plume chemistry and impacts, for example, in terms of the global fixed nitrogen budget, volcanically induced ozone destruction and particle fluxes to the atmosphere. Volcanically initiated atmospheric chemistry was likely to have been particularly important before biological (and latterly anthropogenic) processes started to dominate many geochemical cycles, with important consequences in terms of the evolution of the nitrogen cycle and the role of particles in modulating the Earth's climate. There are still many challenges and open questions to be addressed in this fascinating area of science.

  8. Heterogeneous chemistry in aircraft wakes: Constraints for uptake coefficients

    Science.gov (United States)

    KäRcher, B.

    1997-08-01

    Recent in situ measurements in subsonic and supersonic aircraft plumes show the presence of high aerosol abundances. Given the large initial surface areas of the exhaust particles (volatile aerosols, soot, and ice) of 103-105 μm2 cm-3 or more, heterogeneous processing can potentially become important. Based on an analytical model to predict the temporal evolution of the surface areas, the potential for heterogeneous chemistry during the lifetime of single aircraft wakes is investigated. The model surface areas are constrained by plume observations and compared to numerical simulations of aerosol formation and growth. Efficient heterogeneous processing on volatile aerosols and soot on timescales below 1 day generally requires uptake coefficients ≳0.003-0.007, depending on the specific surface area of soot. For low available surface areas and slow reactions, the lifetime of emitted exhaust species sensitively depends on the wake mixing properties. Shutting off uptake by volatile particles inhibits heterogeneous processing unless high soot surface areas and reaction probabilities are prescribed. Depending on the lifetime of ice contrails, uptake coefficients ≳0.1 are required for rapid uptake of exhaust species on the ice particles. This lower limit becomes relaxed if contrails are long-lived or develop into persistent cirrus or polar stratospheric clouds, rendering activation of chlorine potentially important. The model is applied to investigate the uptake of gaseous HNO2 and SO2 by the observed particles in the plume of the Concorde in the lower stratosphere.

  9. Modeling Macro- and Micro-Scale Turbulent Mixing and Chemistry in Engine Exhaust Plumes

    Science.gov (United States)

    Menon, Suresh

    1998-01-01

    Simulation of turbulent mixing and chemical processes in the near-field plume and plume-vortex regimes has been successfully carried out recently using a reduced gas phase kinetics mechanism which substantially decreased the computational cost. A detailed mechanism including gas phase HOx, NOx, and SOx chemistry between the aircraft exhaust and the ambient air in near-field aircraft plumes is compiled. A reduced mechanism capturing the major chemical pathways is developed. Predictions by the reduced mechanism are found to be in good agreement with those by the detailed mechanism. With the reduced chemistry, the computer CPU time is saved by a factor of more than 3.5 for the near-field plume modeling. Distributions of major chemical species are obtained and analyzed. The computed sensitivities of major species with respect to reaction step are deduced for identification of the dominant gas phase kinetic reaction pathways in the jet plume. Both the near field plume and the plume-vortex regimes were investigated using advanced mixing models. In the near field, a stand-alone mixing model was used to investigate the impact of turbulent mixing on the micro- and macro-scale mixing processes using a reduced reaction kinetics model. The plume-vortex regime was simulated using a large-eddy simulation model. Vortex plume behind Boeing 737 and 747 aircraft was simulated along with relevant kinetics. Many features of the computed flow field show reasonable agreement with data. The entrainment of the engine plumes into the wing tip vortices and also the partial detrainment of the plume were numerically captured. The impact of fluid mechanics on the chemical processes was also studied. Results show that there are significant differences between spatial and temporal simulations especially in the predicted SO3 concentrations. This has important implications for the prediction of sulfuric acid aerosols in the wake and may partly explain the discrepancy between past numerical studies

  10. Flowfield and Radiation Analysis of Missile Exhaust Plumes Using a Turbulent-Chemistry Interaction Model

    National Research Council Canada - National Science Library

    Calhoon, W. H; Kenzakowski, D. C

    2000-01-01

    ... components and missile defense systems. Current engineering level models neglect turbulent-chemistry interactions and typically underpredict the intensity of plume afterburning and afterburning burnout...

  11. Assessment of Turbulence-Chemistry Interactions in Missile Exhaust Plume Signature Analysis

    National Research Council Canada - National Science Library

    Calhoon, W

    2002-01-01

    ... components and missile defense systems. Current engineering level models neglect turbulence chemistry interactions and typically underpredict the intensity of plume afterburning and afterburning burnout...

  12. Unveiling CO2 heterogeneous freezing plumes during champagne cork popping.

    Science.gov (United States)

    Liger-Belair, Gérard; Cordier, Daniel; Honvault, Jacques; Cilindre, Clara

    2017-09-14

    Cork popping from clear transparent bottles of champagne stored at different temperatures (namely, 6, 12, and 20 °C) was filmed through high-speed video imaging in the visible light spectrum. During the cork popping process, a plume mainly composed of gaseous CO2 with traces of water vapour freely expands out of the bottleneck through ambient air. Most interestingly, for the bottles stored at 20 °C, the characteristic grey-white cloud of fog classically observed above the bottlenecks of champagne stored at lower temperatures simply disappeared. It is replaced by a more evanescent plume, surprisingly blue, starting from the bottleneck. We suggest that heterogeneous freezing of CO2 occurs on ice water clusters homogeneously nucleated in the bottlenecks, depending on the saturation ratio experienced by gas-phase CO2 after adiabatic expansion (indeed highly bottle temperature dependent). Moreover, and as observed for the bottles stored at 20 °C, we show that the freezing of only a small portion of all the available CO2 is able to pump the energy released through adiabatic expansion, thus completely inhibiting the condensation of water vapour found in air packages adjacent to the gas volume gushing out of the bottleneck.

  13. Ship plume dispersion rates in convective boundary layers for chemistry models

    Directory of Open Access Journals (Sweden)

    F. Chosson

    2008-08-01

    Full Text Available Detailed ship plume simulations in various convective boundary layer situations have been performed using a Lagrangian Dispersion Model driven by a Large Eddy Simulation Model. The simulations focus on the early stage (1–2 h of plume dispersion regime and take into account the effects of plume rise on dispersion. Results are presented in an attempt to provide to atmospheric chemistry modellers a realistic description of characteristic dispersion impact on exhaust ship plume chemistry. Plume dispersion simulations are used to derive analytical dilution rate functions. Even though results exhibit striking effects of plume rise parameter on dispersion patterns, it is shown that initial buoyancy fluxes at ship stack have a minor effect on plume dilution rate. After initial high dispersion regimes a simple characteristic dilution time scale can be used to parameterize the subgrid plume dilution effect in large-scale chemistry models. The results show that this parameter is directly related to the typical turn-over time scale of the convective boundary layer.

  14. Unveiling CO2 heterogeneous freezing plumes during champagne cork popping

    OpenAIRE

    Liger-Belair, G?rard; Cordier, Daniel; Honvault, Jacques; Cilindre, Clara

    2017-01-01

    Cork popping from clear transparent bottles of champagne stored at different temperatures (namely, 6, 12, and 20??C) was filmed through high-speed video imaging in the visible light spectrum. During the cork popping process, a plume mainly composed of gaseous CO2 with traces of water vapour freely expands out of the bottleneck through ambient air. Most interestingly, for the bottles stored at 20??C, the characteristic grey-white cloud of fog classically observed above the bottlenecks of champ...

  15. Do mantle plumes preserve the heterogeneous structure of their deep-mantle source?

    Science.gov (United States)

    Jones, T. D.; Davies, D. R.; Campbell, I. H.; Wilson, C. R.; Kramer, S. C.

    2016-01-01

    It has been proposed that the spatial variations recorded in the geochemistry of hotspot lavas, such as the bilateral asymmetry recorded at Hawaii, can be directly mapped as the heterogeneous structure and composition of their deep-mantle source. This would imply that source-region heterogeneities are transported into, and preserved within, a plume conduit, as the plume rises from the deep-mantle to Earth's surface. Previous laboratory and numerical studies, which neglect density and rheological variations between different chemical components, support this view. However, in this paper, we demonstrate that this interpretation cannot be extended to distinct chemical domains that differ from surrounding mantle in their density and viscosity. By numerically simulating thermo-chemical mantle plumes across a broad parameter space, in 2-D and 3-D, we identify two conduit structures: (i) bilaterally asymmetric conduits, which occur exclusively for cases where the chemical effect on buoyancy is negligible, in which the spatial distribution of deep-mantle heterogeneities is preserved during plume ascent; and (ii) concentric conduits, which occur for all other cases, with dense material preferentially sampled within the conduit's centre. In the latter regime, the spatial distribution of geochemical domains in the lowermost mantle is not preserved during plume ascent. Our results imply that the heterogeneous structure and composition of Earth's lowermost mantle can only be mapped from geochemical observations at Earth's surface if chemical heterogeneity is a passive component of lowermost mantle dynamics (i.e. its effect on density is outweighed by, or is secondary to, the effect of temperature). The implications of our results for: (i) why oceanic crust should be the prevalent component of ocean island basalts; and (ii) how we interpret the geochemical evolution of Earth's deep-mantle are also discussed.

  16. Shock Wave Mediated Plume Chemistry for Molecular Formation in Laser Ablation Plasmas.

    Science.gov (United States)

    Harilal, Sivanandan S; Brumfield, Brian E; Cannon, Bret D; Phillips, Mark C

    2016-02-16

    Although it is relatively straightforward to measure the ionic, atomic, molecular, and particle emission features from laser ablation plumes, the associated kinetic and thermodynamic development leading to molecular and nanocluster formation remain one of the most important topics of analytical chemistry and material science. Very little is known, for instance, about the evolutionary paths of molecular and nanocluster formation and its relation to laser plume hydrodynamics. This is, to a large extent; due to the complexity of numerous physical processes that coexist in a transient laser-plasma system. Here, we report the formation mechanisms of molecules during complex interactions of a laser-produced plasma plume expanding from a high purity aluminum metal target into ambient air. It is found that the plume hydrodynamics plays a great role in redefining the plasma thermodynamics and molecular formation. Early in the plasma expansion, the generated shock wave at the plume edge acts as a barrier for the combustion process and molecular formation is prevalent after the shock wave collapse. The temporally and spatially resolved contour mapping of atoms and molecules in laser ablation plumes highlight the formation routes and persistence of species in the plasma and their relation to plume hydrodynamics.

  17. Shock wave mediated plume chemistry for molecular formation in laser ablation plasmas

    Energy Technology Data Exchange (ETDEWEB)

    Harilal, Sivanandan S.; Brumfield, Brian E.; Cannon, Bret D.; Phillips, Mark C.

    2016-02-16

    Laser ablation is used in a variety of applications albeit formation mechanisms of molecules and nanoclusters are not well understood. We investigated the formation mechanisms of AlO molecules during complex interactions between an Al laser plume expanding into ambient air at atmospheric pressure levels. To produce the plasma a high-purity Al target was ablated using 1064 nm, 6 ns laser pulses. Our results show that the plasma chemistry leading to the formation of AlO is mediated by shock waves. During the early times of plasma expansion, the generated shock waves at the plume edges act as a barrier for the combustion process and the molecular formation is prevalent after the shockwave collapse. The temporally and spatially resolved contour mapping of Al and AlO highlight the formation routes and persistence of species in the plasma and its relation to plume hydrodynamics.

  18. Higher Order Chemistry Models in the CFD Simulation of Laser-Ablated Carbon Plumes

    Science.gov (United States)

    Scott, C. D.; Greendyke, R. B.; Creel, J. R.; Payne, B. T.

    2005-01-01

    oven facility is heated to a temperature of 1473 K prior to nanotube production runs. Upon laser irradiation, part of the carbon target ablates immediately and forms a carbon vapor plume that penetrates into the argon base flow towards the laser initially at supersonic velocities. In the previous studies either a single carbon species, C3, was used to model the plume development, or a simplified 11 species carbon model reduced down from the Krestinin and Moravsky model for full fullerene chemistry was used. While both of these options yielded significant results, it was felt that the actual chemistry occ&g in the carbon plume might have a greater affect on the plume than assumed. Indeed, in the earlier attempts at modeling the carbon plume, several thermophysical characteristics could never be matched to experimental observations of plume development - mainly the propagation distance of the plume itself. In the present study, two additional chemistry models will be used to duplicate the previous studies simulations of the carbon plume. The first chemistry model used in this study is again a reduced form of the Krestinin and Moravsky rates. However the highest order carbon species allowed has been increased from C6 to C30 - therefore allowing the simulation of up to a half of the standard C60 fullerene. The second chemistry model investigated is a reduced form of a full carbon nanotube model developed at NASA-JSC. The C30 studies have already been accomplished at the present time, and the reduced SWNT model studies are currently underway. To pursue the current study, one sacrifice had to be made in that the simulation grid spacing had to be increased from 0.5 mm spacing to 1 mm spacing for the sake of computational efficiency since computational effort is proportional to the square of the number of grid points multiplied by the number of species considered. propagation that is far more in line with the experimental results observed by Puretzky et al as shown in Fig. 2

  19. Heterogeneous Chemistry: Understanding Aerosol/Oxidant Interactions

    Energy Technology Data Exchange (ETDEWEB)

    Joyce E. Penner

    2005-03-14

    Global radiative forcing of nitrate and ammonium aerosols has mostly been estimated from aerosol concentrations calculated at thermodynamic equilibrium or using approximate treatments for their uptake by aerosols. In this study, a more accurate hybrid dynamical approach (DYN) was used to simulate the uptake of nitrate and ammonium by aerosols and the interaction with tropospheric reactive nitrogen chemistry in a three-dimensional global aerosol and chemistry model, IMPACT, which also treats sulfate, sea salt and mineral dust aerosol. 43% of the global annual average nitrate aerosol burden, 0.16 TgN, and 92% of the global annual average ammonium aerosol burden, 0.29 TgN, exist in the fine mode (D<1.25 {micro}m) that scatters most efficiently. Results from an equilibrium calculation differ significantly from those of DYN since the fraction of fine-mode nitrate to total nitrate (gas plus aerosol) is 9.8%, compared to 13% in DYN. Our results suggest that the estimates of aerosol forcing from equilibrium concentrations will be underestimated. We also show that two common approaches used to treat nitrate and ammonium in aerosol in global models, including the first-order gas-to-particle approximation based on uptake coefficients (UPTAKE) and a hybrid method that combines the former with an equilibrium model (HYB), significantly overpredict the nitrate uptake by aerosols especially that by coarse particles, resulting in total nitrate aerosol burdens higher than that in DYN by +106% and +47%, respectively. Thus, nitrate aerosol in the coarse mode calculated by HYB is 0.18 Tg N, a factor of 2 more than that in DYN (0.086 Tg N). Excessive formation of the coarse-mode nitrate in HYB leads to near surface nitrate concentrations in the fine mode lower than that in DYN by up to 50% over continents. In addition, near-surface HNO{sub 3} and NO{sub x} concentrations are underpredicted by HYB by up to 90% and 5%, respectively. UPTAKE overpredicts the NO{sub x} burden by 56% and near

  20. Surface Chemistry in Heterogeneous Catalysis: An Emerging Discipline.

    Science.gov (United States)

    White, J. M.; Campbell, Charles T.

    1980-01-01

    Provides background data on surface chemistry as an emerging discipline. Highlights the important role which surfaces play in catalysis by focusing on the catalyzed oxidation of carbon monoxide. Provides a demonstration of how surfaces exert their influences in heterogeneous phenomena and illustrates how experimental problems in this field are…

  1. Coordination chemistry in the design of heterogeneous photocatalysts.

    Science.gov (United States)

    Gao, Chao; Wang, Jin; Xu, Hangxun; Xiong, Yujie

    2017-05-22

    Heterogeneous catalysts have been widely used for photocatalysis, which is a highly important process for energy conversion, owing to their merits such as easy separation of catalysts from the reaction products and applicability to continuous chemical industry and recyclability. Yet, homogenous photocatalysis receives tremendous attention as it can offer a higher activity and selectivity with atomically dispersed catalytic sites and tunable light absorption. For this reason, there is a major trend to combine the advantages of both homogeneous and heterogeneous photocatalysts, in which coordination chemistry plays a role as the bridge. In this article, we aim to provide the first systematic review to give a clear picture of the recent progress from taking advantage of coordination chemistry. We specifically summarize the role of coordination chemistry as a versatile tool to engineer catalytically active sites, tune light harvesting and maneuver charge kinetics in heterogeneous photocatalysis. We then elaborate on the common fundamentals behind various materials systems, together with key spectroscopic characterization techniques and remaining challenges in this field. The typical applications of coordination chemistry in heterogeneous photocatalysis, including proton reduction, water oxidation, carbon dioxide reduction and organic reactions, are highlighted.

  2. Determination of the smoke-plume heights with scanning lidar using alternative functions for establishing the atmospheric heterogeneity locations

    Science.gov (United States)

    Vladimir A. Kovalev; Alexander Petkov; Cyle Wold; Wei Min Hao

    2010-01-01

    Data-processing techniques for the scanning lidar data are considered that allow determining the upper and lower boundaries of the smoke plume or smoke layering in the vicinity of wildfires. The task is fulfilled by utilizing the Atmospheric Heterogeneity Height Indicator (AHHI). The AHHI is a histogram, which shows a number of heterogeneity events defined by scanning...

  3. Heterogeneous catalytic materials solid state chemistry, surface chemistry and catalytic behaviour

    CERN Document Server

    Busca, Guido

    2014-01-01

    Heterogeneous Catalytic Materials discusses experimental methods and the latest developments in three areas of research: heterogeneous catalysis; surface chemistry; and the chemistry of catalysts. Catalytic materials are those solids that allow the chemical reaction to occur efficiently and cost-effectively. This book provides you with all necessary information to synthesize, characterize, and relate the properties of a catalyst to its behavior, enabling you to select the appropriate catalyst for the process and reactor system. Oxides (used both as catalysts and as supports for cata

  4. Metal-free heterogeneous catalysis for sustainable chemistry.

    Science.gov (United States)

    Su, Dang Sheng; Zhang, Jian; Frank, Benjamin; Thomas, Arne; Wang, Xinchen; Paraknowitsch, Jens; Schlögl, Robert

    2010-02-22

    The current established catalytic processes used in chemical industries use metals, in many cases precious metals, or metal oxides as catalysts. These are often energy-consuming and not highly selective, wasting resources and producing greenhouse gases. Metal-free heterogeneous catalysis using carbon or carbon nitride is an interesting alternative to some current industrialized chemical processes. Carbon and carbon nitride combine environmental acceptability with inexhaustible resources and allow a favorable management of energy with good thermal conductivity. Owing to lower reaction temperatures and increased selectivity, these catalysts could be candidates for green chemistry with low emission and an efficient use of the chemical feedstock. This Review highlights some recent promising activities and developments in heterogeneous catalysis using only carbon and carbon nitride as catalysts. The state-of-the-art and future challenges of metal-free heterogeneous catalysis are also discussed.

  5. Monsoon Circulations and Tropical Heterogeneous Chlorine Chemistry in the Stratosphere

    Science.gov (United States)

    Kinnison, Doug; Solomon, Susan; Garcia, Rolando; Bandoro, Justin; Wilka, Catherine; Neeley, Ryan, III; Schmidt, Anja; Barnes, John; Vernier, Jean-Paul; Höpfner, Michael; Mills, Michael

    2017-04-01

    Heterogeneous chlorine chemistry on and in liquid polar stratospheric particles is thought to play a significant role in polar and subpolar ozone depletion. Previous studies have not provided evidence for heterogeneous chlorine chemistry occurring in the tropical stratosphere. Using the current best understanding of liquid stratospheric particle chemistry in a state-of-the-art numerical model, we examine whether such processes should be expected to affect tropical composition, particularly at and slightly above the cold tropical tropopause, in association with the Asian and North American summer (June-July-August) monsoons. The Specified Dynamics version of the Community Earth System Model version 1 (CESM1) Whole Atmosphere Community Climate Model (WACCM) is used in this study. This model is nudged to externally specified dynamical fields for temperature, zonal and meridional winds, and surface pressure fields from the NASA Modern Era Retrospective Analysis for Research and Applications (MERRA). Model simulations suggest that transport processes associated with the summer monsoons bring increased abundances of hydrochloric acid (HCl) into contact with liquid sulfate aerosols in the cold tropical lowermost stratosphere, leading to heterogeneous chemical activation of chlorine species. The calculations indicate that the spatial and seasonal distributions of chlorine monoxide (ClO) and chlorine nitrate (ClONO2) near the monsoon regions of the northern hemisphere tropical and subtropical lowermost stratosphere could provide indicators of heterogeneous chlorine processing. In the model, these processes impact the local ozone budget and decrease ozone abundances, implying a chemical contribution to longer-term northern tropical ozone profile changes at 16-19 km.

  6. Modeling of Lightning-Related Plumes into the Chemistry and Transport GEOS-Chem Global Model: Impact on the Upper Tropospheric Chemistry.

    Science.gov (United States)

    Gressent, A.

    2014-12-01

    This work is dedicated to the study of the lightning-related plumes in terms of origin, quantification of the plumes trace gas, and impact on the budget of ozone in particular in the upper troposphere (critical region regarding the greenhouse effect). Recently, Gressent et al., 2014, demonstrated that the majority (74%) of large scale plumes (>300km) from lightning emissions (LNOx) is related to warm conveyor belts and extra-tropical cyclones originating from North America and entering the intercontinental pathway between North America and Europe, leading to a negative (positive) west to east NOy (O3) zonal gradient with -0.4 (+18) ppb difference during spring and -0.6 (+14) ppb difference in summer. In order to better constraint lightning emissions impact in global models, a plume parameterization has been implemented in the 3D chemistry and transport GEOS-Chem global model (Harvard University). Such parameterization was successfully developed for aircraft exhausts application (Cariolle et al., 2009). It allows reproducing sub-grid processes related to lightning NOx chemistry and the chemical evolution during transport in the atmosphere. The issue is here based on the evaluation of parameters such as the plume lifetime and the effective reaction rate constant within the plume. The Dynamically Simple Model of Atmospheric Chemical Complexity (DSMACC) is used to determine such critical values and to better understand the chemical interactions between NOx and O3 species within the undiluted fraction of the plume. Additionally high-resolved simulations of the French meso-scale Meso-NH model are applied over specific case studies of thunderstorms in order to consider the dynamical conditions necessary to represent the plume dilution to the background atmosphere. Finally, sensitivity tests are carried out with the GEOS-Chem model to evaluate the impact of this plume-in-grid model on the ozone and nitrogen species budget.

  7. Californian forest fire plumes over Southwestern British Columbia: lidar, sunphotometry, and mountaintop chemistry observations

    Directory of Open Access Journals (Sweden)

    I. McKendry

    2011-01-01

    Full Text Available Forest fires in Northern California and Oregon were responsible for two significant regional scale aerosol transport events observed in southern British Columbia during summer 2008. A combination of ground based (CORALNet and satellite (CALIPSO lidar, sunphotometry and high altitude chemistry observations permitted unprecedented characterization of forest fire plume height and mixing as well as description of optical properties and physicochemistry of the aerosol. In southwestern BC, lidar observations show the smoke to be mixed through a layer extending to 5–6 km a.g.l. where the aerosol was confined by an elevated inversion in both cases. Depolarization ratios for a trans-Pacific dust event (providing a basis for comparison and the two smoke events were consistent with observations of dust and smoke events elsewhere and permit discrimination of aerosol events in the region. Based on sunphotometry, the Aerosol Optical Thicknesses (AOT reached maxima of ~0.7 and ~0.4 for the two events respectively. Dubovik-retrieval values of reff, f during both the June/July and August events varied between about 0.13 and 0.15 μm and confirm the dominance of accumulation mode size particles in the forest fire plumes. Both Whistler Peak and Mount Bachelor Observatory data show that smoke events are accompanied by elevated CO and O3 concentrations as well as elevated K+/SO4 ratios. In addition to documenting the meteorology and physic-chemical characteristics of two regional scale biomass burning plumes, this study demonstrates the positive analytical synergies arising from the suite of measurements now in place in the Pacific Northwest, and complemented by satellite borne instruments.

  8. OClO and BrO observations in the volcanic plume of Mt. Etna - implications on the chemistry of chlorine and bromine species in volcanic plumes

    Science.gov (United States)

    Gliß, J.; Bobrowski, N.; Vogel, L.; Platt, U.

    2014-10-01

    Spatial and temporal profiles of chlorine dioxide (OClO), bromine monoxide (BrO) and sulphur dioxide (SO2) were measured in the plume of Mt. Etna, Italy, in September 2012 using Multi-Axis-Differential-Optical-Absorption-Spectroscopy (MAX-DOAS). OClO (BrO) was detected in 119 (452) individual measurements covering plume ages up to 6 (23) minutes. The retrieved slant column densities (SCDs) reached values up to 2.0 × 1014 molecules cm-2 (OClO) and 1.1 × 1015 molecules cm-2 (BrO). In addition, the spectra were analysed for signatures of IO, OIO and OBrO, none of these species could be detected. The corresponding detection limits for IO / SO2, OIO / SO2 and OBrO / SO2 were 1.8 × 10-6, 2.0 × 10-5 and 1.1 × 10-5 respectively. The measurements were performed at plume ages (τ) from zero to 23 min downwind the emission source. The chemical variability of BrO and OClO in the plume was studied analysing the OClO / SO2 and BrO / SO2-ratio. A marked increase of both ratios was observed in the young plume (τ 3 min) with mean abundances of 3.17 × 10-5 (OClO / SO2), 1.55 × 10-4 (BrO / SO2) and 0.16 (OClO / BrO). Furthermore, enhanced BrO/SO2-ratios were found at the plume edges (by ~30-37%) and a strong indication of enhanced OClO / SO2-ratios as well (~10-250%). A measurement performed in the early morning (05:20-06:20 UTC, sunrise: 04:40 UTC) showed an BrO / SO2-ratio increasing with time until 05:35 UTC and a constant ratio afterwards. Observing this increase was only possible due to a correction for stratospheric BrO signals in the plume spectra. The corresponding OClO / SO2-ratio showed a similar trend stabilising around 06:13 UTC, approximately 40 min later than BrO. This is another strong indication for the photochemical nature of the reactions involved in the formation of oxidised halogens in volcanic plumes. In particular, these findings support the current understanding of the underlying chemistry, namely, that BrO is formed in an autocatalytic reaction

  9. Ship plume dispersion rates in convective boundary layers for chemistry models

    OpenAIRE

    Chosson, F.; Paoli, R.; B. Cuenot

    2008-01-01

    International audience; Detailed ship plume simulations in various convective boundary layer situations have been performed using a Lagrangian Dispersion Model driven by a Large Eddy Simulation Model. The simulations focus on early stage (1–2 h) of plume dispersion regime and take into account the effects of plume rise on dispersion. Results are presented in an attempt to provide to chemical modellers community a realistic description of the impact of characteristic dispersion on exhaust ship...

  10. Recent Advances in Modeling the Near-Source Chemistry of Biomass-Burning Plumes in Photochemical Transport Models

    Science.gov (United States)

    Lonsdale, Chantelle; Brodowski, Christopher; Alvarado, Matthew; Henderson, John; Pierce, Jeffrey; Ramnarine, Emily; Lin, John; Kochanski, Adam

    2017-04-01

    Aerosol and gases freshly emitted from biomass-burning events are a complex mixture of organic species, black carbon, and inorganic salts, with their size, number, and chemical composition dependent on the type of vegetation that is burning, the size and combustion efficiency of the fire event, and the ambient conditions. These mixtures evolve quickly in the atmosphere due to coagulation, evaporation, and chemistry, including trace gases, ozone and secondary organic aerosol formation. Understanding and simulating this complex evolution is critical to assessing and quantifying the impact of biomass-burning plumes on air quality and climate. Since 3D Eulerian models take estimates of the primary emissions from biomass burning and unphysically mix them across large-scale grid boxes, this leads to inaccurate chemical modeling and incorrect estimates of the impact of biomass burning on air quality and climate. Plume-scale process models like the newly developed System for Atmospheric Modeling integrated with AER's Aerosol Simulation Program (SAM-ASP) allow an advanced representation of the near-source biomass-burning plume evolution, with the ability to develop parameterizations for use in air quality and climate models. We present results from a model study of a shrub land fire in California, as well as the development of a parameterization that improves upon the ASP-based parameterization of Lonsdale et al. (2015) that accounted for the formation of trace gases and secondary organic aerosols in biomass burning plumes for various fire conditions and fuel types. The newly improved parameterization additionally includes the complex processes of dispersion, advection, deposition and plume concentrations. We show results of the integration of this parameterization into a plume-in-grid sub-model within a larger-scale photochemical transport model for the first time.

  11. Inverting for volcanic SO2 flux at high temporal resolution using spaceborne plume imagery and chemistry-transport modelling: the 2010 Eyjafjallajökull eruption case study

    Directory of Open Access Journals (Sweden)

    M. Boichu

    2013-09-01

    Full Text Available Depending on the magnitude of their eruptions, volcanoes impact the atmosphere at various temporal and spatial scales. The volcanic source remains a major unknown to rigorously assess these impacts. At the scale of an eruption, the limited knowledge of source parameters, including time variations of erupted mass flux and emission profile, currently represents the greatest issue that limits the reliability of volcanic cloud forecasts. Today, a growing number of satellite and remote sensing observations of distant plumes are becoming available, bringing indirect information on these source terms. Here, we develop an inverse modelling approach combining satellite observations of the volcanic plume with an Eulerian regional chemistry-transport model (CHIMERE to characterise the volcanic SO2 emissions during an eruptive crisis. The May 2010 eruption of Eyjafjallajökull is a perfect case study to apply this method as the volcano emitted substantial amounts of SO2 during more than a month. We take advantage of the SO2 column amounts provided by a vast set of IASI (Infrared Atmospheric Sounding Interferometer satellite images to reconstruct retrospectively the time series of the mid-tropospheric SO2 flux emitted by the volcano with a temporal resolution of ~2 h, spanning the period from 1 to 12 May 2010. We show that no a priori knowledge on the SO2 flux is required for this reconstruction. The initialisation of chemistry-transport modelling with this reconstructed source allows for reliable simulation of the evolution of the long-lived tropospheric SO2 cloud over thousands of kilometres. Heterogeneities within the plume, which mainly result from the temporal variability of the emissions, are correctly tracked over a timescale of a week. The robustness of our approach is also demonstrated by the broad similarities between the SO2 flux history determined by this study and the ash discharge behaviour estimated by other means during the phases of high

  12. Constraining the heterogeneous loss of O3 on soot particles with observations in jet engine exhaust plumes

    Science.gov (United States)

    Gao, R. S.; Kärcher, B.; Keim, E. R.; Fahey, D. W.

    In situ measurements in the engine exhaust of a Concorde supersonic aircraft in the lower stratosphere are used to constrain heterogeneous reaction rates on soot particles in a plume model. Upper limit values are obtained for the product of the reactive uptake coefficients of O3 and NO2 and the mean surface area of individual soot particles using the model and the well-established O3-N2O correlation in the lower stratosphere. The low reactivity value obtained for O3 implies that soot reactions cannot account for ozone trends in the lower stratosphere.

  13. Molecular dynamics study on mechanism of preformed particle gel transporting through nanopores: Surface chemistry and heterogeneity

    Science.gov (United States)

    Cui, Peng; Zhang, Heng; Ma, Ying; Hao, Qingquan; Liu, Gang; Sun, Jichao; Yuan, Shiling

    2017-10-01

    The translocation behavior of preformed particle gel (PPG) in porous media is crucial for its application in enhanced oil recovery. By means of non-equilibrium molecular dynamics simulation, the translocation mechanism of PPG confined in different silica nanopores were investigated. The influence of surface chemistry and chemical heterogeneity of silica nanopore on the translocation process was revealed. As the degree of surface hydroxylation increases and the heterogeneity decreases, the pulling force needed to drive PPG decreases. We infer that the nanopore's surface (i.e. surface chemistry and heterogeneity) affects the translocation of PPG indirectly by forming different hydration layers.

  14. Modeling of Laser Vaporization and Plume Chemistry in a Boron Nitride Nanotube Production Rig

    Science.gov (United States)

    Gnoffo, Peter A.; Fay, Catharine C.

    2012-01-01

    Flow in a pressurized, vapor condensation (PVC) boron nitride nanotube (BNNT) production rig is modeled. A laser provides a thermal energy source to the tip of a boron ber bundle in a high pressure nitrogen chamber causing a plume of boron-rich gas to rise. The buoyancy driven flow is modeled as a mixture of thermally perfect gases (B, B2, N, N2, BN) in either thermochemical equilibrium or chemical nonequilibrium assuming steady-state melt and vaporization from a 1 mm radius spot at the axis of an axisymmetric chamber. The simulation is intended to define the macroscopic thermochemical environment from which boron-rich species, including nanotubes, condense out of the plume. Simulations indicate a high temperature environment (T > 4400K) for elevated pressures within 1 mm of the surface sufficient to dissociate molecular nitrogen and form BN at the base of the plume. Modifications to Program LAURA, a finite-volume based solver for hypersonic flows including coupled radiation and ablation, are described to enable this simulation. Simulations indicate that high pressure synthesis conditions enable formation of BN vapor in the plume that may serve to enhance formation of exceptionally long nanotubes in the PVC process.

  15. Wildland fire emissions, carbon, and climate: Plume rise, atmospheric transport, and chemistry processes

    Science.gov (United States)

    Warren Heilman; Yongqiang Liu; Shawn Urbanski; Vladimir Kovalev; Robert Mickler

    2014-01-01

    This paper provides an overview and summary of the current state of knowledge regarding critical atmospheric processes that affect the distribution and concentrations of greenhouse gases and aerosols emitted from wildland fires or produced through subsequent chemical reactions in the atmosphere. These critical atmospheric processes include the dynamics of plume rise,...

  16. Eruption Conditions of Pele Volcano on Io Inferred from Chemistry of Its Volcanic Plume

    Science.gov (United States)

    Zolotov, M. Yu.; Fegley, B., Jr.

    2000-01-01

    We used thermodynamic models and HST observations of Pele plume to calculate the temperature (1430 K) and oxidation state (log fO2 = -11.7) of volcanic gases and magmas of Pele. Our estimated vent pressure is 10(exp -3) to 10(exp -5) bars.

  17. Time-series analysis of two hydrothermal plumes at 9°50'N East Pacific Rise reveals distinct, heterogeneous bacterial populations.

    Science.gov (United States)

    Sylvan, J B; Pyenson, B C; Rouxel, O; German, C R; Edwards, K J

    2012-03-01

    We deployed sediment traps adjacent to two active hydrothermal vents at 9°50'N on the East Pacific Rise (EPR) to assess the variability in bacterial community structure associated with plume particles on the timescale of weeks to months, to determine whether an endemic population of plume microbes exists, and to establish ecological relationships between bacterial populations and vent chemistry. Automated rRNA intergenic spacer analysis (ARISA) indicated that there are separate communities at the two different vents and temporal community variations between each vent. Correlation analysis between chemistry and microbiology indicated that shifts in the coarse particulate (>1 mm) Fe/(Fe+Mn+Al), Cu, V, Ca, Al, (232) Th, and Ti as well as fine-grained particulate (particle-attached plume environment is genetically distinct from the surrounding seawater. While work to date in hydrothermal environments has focused on determining the microbial communities on hydrothermal chimneys and the basaltic lavas that form the surrounding seafloor, little comparable data exist on the plume environment that physically and chemically connects them. By employing sediment traps for a time-series approach to sampling, we show that bacterial community composition on plume particles changes on timescales much shorter than previously known. © 2012 Blackwell Publishing Ltd.

  18. Explicit modeling of organic chemistry and secondary organic aerosol partitioning for Mexico City and its outflow plume

    Directory of Open Access Journals (Sweden)

    J. Lee-Taylor

    2011-12-01

    Full Text Available The evolution of organic aerosols (OA in Mexico City and its outflow is investigated with the nearly explicit gas phase photochemistry model GECKO-A (Generator of Explicit Chemistry and Kinetics of Organics in the Atmosphere, wherein precursor hydrocarbons are oxidized to numerous intermediate species for which vapor pressures are computed and used to determine gas/particle partitioning in a chemical box model. Precursor emissions included observed C3-10 alkanes, alkenes, and light aromatics, as well as larger n-alkanes (up to C25 not directly observed but estimated by scaling to particulate emissions according to their volatility. Conditions were selected for comparison with observations made in March 2006 (MILAGRO. The model successfully reproduces the magnitude and diurnal shape for both primary (POA and secondary (SOA organic aerosols, with POA peaking in the early morning at 15–20 μg m−3, and SOA peaking at 10–15 μg m−3 during mid-day. The majority (≥75% of the model SOA stems from reaction products of the large n-alkanes, used here as surrogates for all emitted hydrocarbons of similar volatility, with the remaining SOA originating mostly from the light aromatics. Simulated OA elemental composition reproduces observed H/C and O/C ratios reasonably well, although modeled ratios develop more slowly than observations suggest. SOA chemical composition is initially dominated by δ-hydroxy ketones and nitrates from the large alkanes, with contributions from peroxy acyl nitrates and, at later times when NOx is lower, organic hydroperoxides. The simulated plume-integrated OA mass continues to increase for several days downwind despite dilution-induced particle evaporation, since oxidation chemistry leading to SOA formation remains strong. In this model, the plume SOA burden several days downwind exceeds that leaving the city by a factor of >3. These results suggest significant regional radiative

  19. Explicit modeling of organic chemistry and secondary organic aerosol partitioning for Mexico City and its outflow plume

    Energy Technology Data Exchange (ETDEWEB)

    Lee-Taylor, J.; Madronich, Sasha; Aumont, B.; Baker, A.; Camredon, M.; Hodzic, Alma; Tyndall, G. S.; Apel, Eric; Zaveri, Rahul A.

    2011-12-21

    The evolution of organic aerosols (OA) in Mexico City and its outflow is investigated with the nearly explicit gas phase photochemistry model GECKO-A (Generator of Explicit Chemistry and Kinetics of Organics in the Atmosphere), wherein precursor hydrocarbons are oxidized to numerous intermediate species for which vapor pressures are computed and used to determine gas/particle partitioning in a chemical box model. Precursor emissions included observed C3-10 alkanes, alkenes, and light aromatics, as well as larger n-alkanes (up to C25) not directly observed but estimated by scaling to particulate emissions according to their volatility. Conditions were selected for comparison with observations made in March 2006 (MILAGRO). The model successfully reproduces the magnitude and diurnal shape for both primary (POA) and secondary (SOA) organic aerosols, with POA peaking in the early morning at 15-20 ug m-3, and SOA peaking at 10-15 μg m-3 during mid-day. The majority (> 75%) of the model SOA stems from the large n-alkanes, with the remainder mostly from the light aromatics. Simulated OA elemental composition reproduces observed H/C and O/C ratios reasonably well, although modeled ratios develop more slowly than observations suggest. SOA chemical composition is initially dominated by *- hydroxy ketones and nitrates from the large alkanes, with contributions from peroxy acyl nitrates and, at later times when NOx is lower, organic hydroperoxides. The simulated plume-integrated OA mass continues to increase for several days downwind despite dilution-induced particle evaporation, since oxidation chemistry leading to SOA formation remains strong. In this model, the plume SOA burden several days downwind exceeds that leaving the city by a factor of >3. These results suggest significant regional radiative impacts of SOA.

  20. Recent advances in heterogeneous selective oxidation catalysis for sustainable chemistry.

    Science.gov (United States)

    Guo, Zhen; Liu, Bin; Zhang, Qinghong; Deng, Weiping; Wang, Ye; Yang, Yanhui

    2014-05-21

    Oxidation catalysis not only plays a crucial role in the current chemical industry for the production of key intermediates such as alcohols, epoxides, aldehydes, ketones and organic acids, but also will contribute to the establishment of novel green and sustainable chemical processes. This review is devoted to dealing with selective oxidation reactions, which are important from the viewpoint of green and sustainable chemistry and still remain challenging. Actually, some well-known highly challenging chemical reactions involve selective oxidation reactions, such as the selective oxidation of methane by oxygen. On the other hand some important oxidation reactions, such as the aerobic oxidation of alcohols in the liquid phase and the preferential oxidation of carbon monoxide in hydrogen, have attracted much attention in recent years because of their high significance in green or energy chemistry. This article summarizes recent advances in the development of new catalytic materials or novel catalytic systems for these challenging oxidation reactions. A deep scientific understanding of the mechanisms, active species and active structures for these systems are also discussed. Furthermore, connections among these distinct catalytic oxidation systems are highlighted, to gain insight for the breakthrough in rational design of efficient catalytic systems for challenging oxidation reactions.

  1. Interrelation of chemistry and process design in biodiesel manufacturing by heterogeneous catalysis

    NARCIS (Netherlands)

    Dimian, A.C.; Srokol, Z.W.; Mittelmeijer-Hazeleger, M.C.; Rothenberg, G.

    2010-01-01

    The pros and cons of using heterogeneous catalysis for biodiesel manufacturing are introduced, and explained from a chemistry and engineering viewpoint. Transesterification reactions of various feed types are then compared in batch and continuous process operation modes. The results show that the

  2. EPR approaches to heterogeneous catalysis. The chemistry of titanium in heterogeneous catalysts and photocatalysts.

    Science.gov (United States)

    Morra, Elena; Giamello, Elio; Chiesa, Mario

    2017-07-01

    Paramagnetic species are often involved in catalytic or photocatalytic reactions occurring at the solid-gas interface of heterogeneous catalysts. In this contribution we will provide an overview of the wealth and breadth of information that can be obtained from EPR in the characterization of paramagnetic species in such systems, illustrating the advantages that modern pulsed EPR methodologies can offer in monitoring the elementary processes occurring within the coordination sphere of surface transition-metal ions. To do so we selected three representative systems, where titanium ions in low oxidation states act as active catalytic sites, trying to outline the methodological approaches which characterize the application of EPR techniques and the questions that can be answered and addressed relative to the characterization of heterogeneous catalytic materials. Copyright © 2017 Elsevier Inc. All rights reserved.

  3. EPR approaches to heterogeneous catalysis. The chemistry of titanium in heterogeneous catalysts and photocatalysts

    Science.gov (United States)

    Morra, Elena; Giamello, Elio; Chiesa, Mario

    2017-07-01

    Paramagnetic species are often involved in catalytic or photocatalytic reactions occurring at the solid-gas interface of heterogeneous catalysts. In this contribution we will provide an overview of the wealth and breadth of information that can be obtained from EPR in the characterization of paramagnetic species in such systems, illustrating the advantages that modern pulsed EPR methodologies can offer in monitoring the elementary processes occurring within the coordination sphere of surface transition-metal ions. To do so we selected three representative systems, where titanium ions in low oxidation states act as active catalytic sites, trying to outline the methodological approaches which characterize the application of EPR techniques and the questions that can be answered and addressed relative to the characterization of heterogeneous catalytic materials.

  4. Impact of oxygen chemistry on the emission and fluorescence spectroscopy of laser ablation plumes

    Science.gov (United States)

    Hartig, K. C.; Brumfield, B. E.; Phillips, M. C.; Harilal, S. S.

    2017-09-01

    Oxygen present in the ambient gas medium may affect both laser-induced breakdown spectroscopy (LIBS) and laser-induced fluorescence (LIF) emission through a reduction of emission intensity and persistence. In this study, an evaluation is made on the role of oxygen in the ambient environment under atmospheric pressure conditions in LIBS and laser ablation (LA)-LIF emission. To generate plasmas, 1064 nm, 10 ns pulses were focused on an aluminum alloy sample. LIF was performed by frequency scanning a CW laser over the 396.15 nm (3s24s 2S1/2 → 3s23p 2P°3/2) Al I transition. Time-resolved emission and fluorescence signals were recorded to evaluate the variation in emission intensity caused by the presence of oxygen. The oxygen partial pressure (po) in the atmospheric pressure environment using N2 as the makeup gas was varied from 0 to 400 Torr O2. 2D-fluorescence spectroscopy images were obtained for various oxygen concentrations for simultaneous evaluation of the emission and excitation spectral features. Results showed that the presence of oxygen in the ambient environment reduces the persistence of the LIBS and LIF emission through an oxidation process that depletes the density of atomic species within the resulting laser-produced plasma (LPP) plume.

  5. The primary volcanic aerosol emission from Mt Etna: Size-resolved particles with SO2 and role in plume reactive halogen chemistry

    Science.gov (United States)

    Roberts, T. J.; Vignelles, D.; Liuzzo, M.; Giudice, G.; Aiuppa, A.; Coltelli, M.; Salerno, G.; Chartier, M.; Couté, B.; Berthet, G.; Lurton, T.; Dulac, F.; Renard, J.-B.

    2018-02-01

    Volcanoes are an important source of aerosols to the troposphere. Within minutes after emission, volcanic plume aerosol catalyses conversion of co-emitted HBr, HCl into highly reactive halogens (e.g. BrO, OClO) through chemical cycles that cause substantial ozone depletion in the dispersing downwind plume. This study quantifies the sub-to-supramicron primary volcanic aerosol emission (0.2-5 μm diameter) and its role in this process. An in-situ ground-based study at Mt Etna (Italy) during passive degassing co-deployed an optical particle counter and Multi-Gas SO2 sensors at high time resolution (0.1 Hz) enabling to characterise the aerosol number, size-distribution and emission flux. A tri-modal volcanic aerosol size distribution was found, to which lognormal distributions are fitted. Total particle volume correlates to SO2 (as a plume tracer). The measured particle volume:SO2 ratio equates to a sulfate:SO2 ratio of 1-2% at the observed meteorological conditions (40% Relative Humidity). A particle mass flux of 0.7 kg s-1 is calculated for the measured Mt Etna SO2 flux of 1950 tonnes/day. A numerical plume atmospheric chemistry model is used to simulate the role of the hygroscopic primary aerosol surface area and its humidity dependence on volcanic plume BrO and OClO chemistry. As well as predicting volcanic BrO formation and O3 depletion, the model achieves OClO/SO2 in broad quantitative agreement with recently reported Mt Etna observations, with a predicted maximum a few minutes downwind. In addition to humidity - that enhances aerosols surface area for halogen cycling - background ozone is predicted to be an important control on OClO/SO2. Dependence of BrO/SO2 on ambient humidity is rather low near-to-source but increases further downwind. The model plume chemistry also exhibits strong across-plume spatial variations between plume edge and centre.

  6. Stochastic analysis of the efficiency of coupled hydraulic-physical barriers to contain solute plumes in highly heterogeneous aquifers

    Science.gov (United States)

    Pedretti, Daniele; Masetti, Marco; Beretta, Giovanni Pietro

    2017-10-01

    The expected long-term efficiency of vertical cutoff walls coupled to pump-and-treat technologies to contain solute plumes in highly heterogeneous aquifers was analyzed. A well-characterized case study in Italy, with a hydrogeological database of 471 results from hydraulic tests performed on the aquifer and the surrounding 2-km-long cement-bentonite (CB) walls, was used to build a conceptual model and assess a representative remediation site adopting coupled technologies. In the studied area, the aquifer hydraulic conductivity Ka [m/d] is log-normally distributed with mean E (Ya) = 0.32 , variance σYa2 = 6.36 (Ya = lnKa) and spatial correlation well described by an exponential isotropic variogram with integral scale less than 1/12 the domain size. The hardened CB wall's hydraulic conductivity, Kw [m/d], displayed strong scaling effects and a lognormal distribution with mean E (Yw) = - 3.43 and σYw2 = 0.53 (Yw =log10Kw). No spatial correlation of Kw was detected. Using this information, conservative transport was simulated across a CB wall in spatially correlated 1-D random Ya fields within a numerical Monte Carlo framework. Multiple scenarios representing different Kw values were tested. A continuous solute source with known concentration and deterministic drains' discharge rates were assumed. The efficiency of the confining system was measured by the probability of exceedance of concentration over a threshold (C∗) at a control section 10 years after the initial solute release. It was found that the stronger the aquifer heterogeneity, the higher the expected efficiency of the confinement system and the lower the likelihood of aquifer pollution. This behavior can be explained because, for the analyzed aquifer conditions, a lower Ka generates more pronounced drawdown in the water table in the proximity of the drain and consequently a higher advective flux towards the confined area, which counteracts diffusive fluxes across the walls. Thus, a higher σYa2 results

  7. Fast heterogeneous N2O5 uptake and ClNO2 production in power plant and industrial plumes observed in the nocturnal residual layer over the North China Plain

    Science.gov (United States)

    Wang, Zhe; Wang, Weihao; Tham, Yee Jun; Li, Qinyi; Wang, Hao; Wen, Liang; Wang, Xinfeng; Wang, Tao

    2017-10-01

    Dinitrogen pentoxide (N2O5) and nitryl chloride (ClNO2) are key species in nocturnal tropospheric chemistry and have significant effects on particulate nitrate formation and the following day's photochemistry through chlorine radical production and NOx recycling upon photolysis of ClNO2. To better understand the roles of N2O5 and ClNO2 in the high-aerosol-loading environment of northern China, an intensive field study was carried out at a high-altitude site (Mt. Tai, 1465 m a.s.l.) in the North China Plain (NCP) during the summer of 2014. Elevated ClNO2 plumes were frequently observed in the nocturnal residual layer with a maximum mixing ratio of 2.1 ppbv (1 min), whilst N2O5 was typically present at very low levels (chemical characteristics and backward trajectories indicated that the ClNO2-laden air was caused by the transport of NOx-rich plumes from the coal-fired industry and power plants in the NCP. The heterogeneous N2O5 uptake coefficient (γ) and ClNO2 yield (ϕ) were estimated from steady-state analysis and observed growth rate of ClNO2. The derived γ and ϕ exhibited high variability, with means of 0.061 ± 0.025 and 0.28 ± 0.24, respectively. These values are higher than those derived from previous laboratory and field studies in other regions and cannot be well characterized by model parameterizations. Fast heterogeneous N2O5 reactions dominated the nocturnal NOx loss in the residual layer over this region and contributed to substantial nitrate formation of up to 17 µg m-3. The estimated nocturnal nitrate formation rates ranged from 0.2 to 4.8 µg m-3 h-1 in various plumes, with a mean of 2.2 ± 1.4 µg m-3 h-1. The results demonstrate the significance of heterogeneous N2O5 reactivity and chlorine activation in the NCP, and their unique and universal roles in fine aerosol formation and NOx transformation, and thus their potential impacts on regional haze pollution in northern China.

  8. The effects of heterogeneous reactions on atmospheric chemistry and aerosol properties

    Science.gov (United States)

    Wei, Chao; Carmichael, Gregory; Su, Hang; Cheng, Yafang

    2017-04-01

    A new aerosol module is developed for the STEM model (the Sulfur Transport and dEposition Model) to better understand the chemical aging of dust during long range transport and assess the impact of heterogeneous reactions on tropospheric chemistry. The new aerosol module is verified and first applied in a box model, and then coupled into the 3-Dimentional STEM model. In the new aerosol model, a nonequilibrium (dynamic or kinetic) approach to treat gas-to-particle conversion is employed to replace the equilibrium method in STEM model. Meanwhile, a new numerical method solving the aerosol dynamics equation is introduced into the dynamic aerosol model for its improved computational efficiency and high accuracy. Compared with the equilibrium method, the new dynamic approach is found to provide better results on predicating the different hygroscopicity and chemical aging patterns as a function of size. The current modeling study also takes advantage of new findings from laboratory experiments about heterogeneous reactions on mineral oxides and dust particles, in order to consider the complexity of surface chemistry (such as surface saturation, coating and relative humidity). Modeling results show that the impacts of mineralogy and relative humidity on heterogeneous reactions are significant and should be considered in atmospheric chemistry modeling with first priority. The new dynamic approach for gas-to-particle conversion and RH-dependent heterogeneous uptake of HNO3 improve the model performance in term of aerosol predictions under different conditions. It is shown that these improvements change the modeled nitrate and sulfate concentrations, but also modify their size distributions significantly.

  9. The Development of a Combined Search for a Heterogeneous Chemistry Database

    Directory of Open Access Journals (Sweden)

    Lulu Jiang

    2015-05-01

    Full Text Available A combined search, which joins a slow molecule structure search with a fast compound property search, results in more accurate search results and has been applied in several chemistry databases. However, the problems of search speed differences and combining the two separate search results are two major challenges. In this paper, two kinds of search strategies, synchronous search and asynchronous search, are proposed to solve these problems in the heterogeneous structure database and the property database found in ChemDB, a chemistry database owned by the Institute of Process Engineering, CAS. Their advantages and disadvantages under different conditions are discussed in detail. Furthermore, we applied these two searches to ChemDB and used them to screen for potential molecules that can work as CO2 absorbents. The results reveal that this combined search discovers reasonable target molecules within an acceptable time frame.

  10. Evaluated kinetic and photochemical data for atmospheric chemistry: Volume V – heterogeneous reactions on solid substrates

    Directory of Open Access Journals (Sweden)

    J. N. Crowley

    2010-09-01

    Full Text Available This article, the fifth in the ACP journal series, presents data evaluated by the IUPAC Subcommittee on Gas Kinetic Data Evaluation for Atmospheric Chemistry. It covers the heterogeneous processes on surfaces of solid particles present in the atmosphere, for which uptake coefficients and adsorption parameters have been presented on the IUPAC website in 2010. The article consists of an introduction and guide to the evaluation, giving a unifying framework for parameterisation of atmospheric heterogeneous processes. We provide summary sheets containing the recommended uptake parameters for the evaluated processes. Four substantial appendices contain detailed data sheets for each process considered for ice, mineral dust, sulfuric acid hydrate and nitric acid hydrate surfaces, which provide information upon which the recommendations are made.

  11. Single-Site Heterogeneous Catalysts: Innovations, Advantages, and Future Potential in Green Chemistry and Sustainable Technology

    Science.gov (United States)

    Raja, Robert; Thomas, John Meurig

    The advantages that flow from the availability of single-site heterogeneous catalysts are many. They facilitate the determination of the kinetics and mechanism of catalytic turnover and render accessible the energetics of various intermediates. More importantly, it is possible to prepare soluble molecular fragments that circumscribe the single site, thus enabling a direct comparison to be made between the catalytic performance of the same active site when functioning as a heterogeneous or a homogeneous catalyst. Our approach adopts the principles and practices of solid-state chemistry, augmented by lessons derived from enzymology, as well as computational chemistry. We have succeeded in designing a range of new catalysts to effect, inter alia, shape-selective, regioselective, bifunctional, and enantioselective catalytic conversions. In particular, large fractions of these catalysts are ideally suited for the era of clean technology in which single-step and/or solvent-free processes abound, and in which benign oxidants such as air or oxygen and inexpensive nanoporous materials are employed.

  12. Investigating the links between ozone and organic aerosol chemistry in a biomass burning plume from a prescribed fire in California chaparral

    Science.gov (United States)

    Alvarado, M. J.; Lonsdale, C. R.; Yokelson, R. J.; Akagi, S. K.; Coe, H.; Craven, J. S.; Fischer, E. V.; McMeeking, G. R.; Seinfeld, J. H.; Soni, T.; Taylor, J. W.; Weise, D. R.; Wold, C. E.

    2015-06-01

    Within minutes after emission, complex photochemistry in biomass burning smoke plumes can cause large changes in the concentrations of ozone (O3) and organic aerosol (OA). Being able to understand and simulate this rapid chemical evolution under a wide variety of conditions is a critical part of forecasting the impact of these fires on air quality, atmospheric composition, and climate. Here we use version 2.1 of the Aerosol Simulation Program (ASP) to simulate the evolution of O3 and secondary organic aerosol (SOA) within a young biomass burning smoke plume from the Williams prescribed fire in chaparral, which was sampled over California in November 2009. We demonstrate the use of a method for simultaneously accounting for the impact of the unidentified intermediate volatility, semi-volatile, and extremely low volatility organic compounds (here collectively called "SVOCs") on the formation of OA (using the Volatility Basis Set - VBS) and O3 (using the concept of mechanistic reactivity). We show that this method can successfully simulate the observations of O3, OA, NOx, ethylene (C2H4), and OH to within measurement uncertainty using reasonable assumptions about the average chemistry of the unidentified SVOCs. These assumptions were (1) a reaction rate constant with OH of ~ 10-11 cm3 s-1; (2) a significant fraction (up to ~ 50 %) of the RO2 + NO reaction resulted in fragmentation, rather than functionalization, of the parent SVOC; (3) ~ 1.1 molecules of O3 were formed for every molecule of SVOC that reacted; (4) ~ 60 % of the OH that reacted with the unidentified non-methane organic compounds (NMOC) was regenerated as HO2; and (5) that ~ 50 % of the NO that reacted with the SVOC peroxy radicals was lost, presumably to organic nitrate formation. Additional evidence for the fragmentation pathway is provided by the observed rate of formation of acetic acid (CH3COOH), which is consistent with our assumed fragmentation rate. However, the model overestimates peroxyacetyl

  13. Hydrogeophysical imaging of deposit heterogeneity and groundwater chemistry changes during DNAPL source zone bioremediation

    Science.gov (United States)

    Chambers, J. E.; Wilkinson, P. B.; Wealthall, G. P.; Loke, M. H.; Dearden, R.; Wilson, R.; Allen, D.; Ogilvy, R. D.

    2010-10-01

    Robust characterization and monitoring of dense nonaqueous phase liquid (DNAPL) source zones is essential for designing effective remediation strategies, and for assessing the efficacy of treatment. In this study high-resolution cross-hole electrical resistivity tomography (ERT) was evaluated as a means of monitoring a field-scale in-situ bioremediation experiment, in which emulsified vegetable oil (EVO) electron donor was injected into a trichloroethene source zone. Baseline ERT scans delineated the geometry of the interface between the contaminated alluvial aquifer and the underlying mudstone bedrock, and also the extent of drilling-induced physical heterogeneity. Time-lapse ERT images revealed major preferential flow pathways in the source and plume zones, which were corroborated by multiple lines of evidence, including geochemical monitoring and hydraulic testing using high density multilevel sampler arrays within the geophysical imaging planes. These pathways were shown to control the spatial distribution of the injected EVO, and a bicarbonate buffer introduced into the cell for pH control. Resistivity signatures were observed within the preferential flow pathways that were consistent with elevated chloride levels, providing tentative evidence from ERT of the biodegradation of chlorinated solvents.

  14. Heterogeneous chemistry and reaction dynamics of the atmospheric oxidants, O3, NO3, and OH, on organic surfaces

    OpenAIRE

    Chapleski, Robert C.; Zhang, Yafen; Troya, Diego; Morris, John R.

    2015-01-01

    Heterogeneous chemistry of the most important atmospheric oxidants, O3, NO3, and OH, plays a central role in regulating atmospheric gas concentrations, processing aerosols, and aging materials. Recent experimental and computational studies have begun to reveal the detailed reaction mechanisms and kinetics for gas-phase O3, NO3, and OH when they impinge on organic surfaces. Through new research approaches that merge the fields of traditional surface science with atmospheric chemistry, research...

  15. Investigating the links between ozone and organic aerosol chemistry in a biomass burning plume from a California chaparral fire

    Science.gov (United States)

    M. J. Alvarado; C. R. Lonsdale; R. J. Yokelson; S. K. Akagi; I. R. Burling; H. Coe; J. S. Craven; E. Fischer; G. R. McMeeking; J. H. Seinfeld; T. Soni; J. W. Taylor; D. R. Weise; C. E. Wold

    2014-01-01

    Within minutes after emission, rapid, complex photochemistry within a biomass burning smoke plume can cause large changes in the concentrations of ozone (O3) and organic aerosol (OA). Being able to understand and simulate this rapid chemical evolution under 5 a wide variety of conditions is a critical part of forecasting the impact of these fires...

  16. Impacts of heterogeneous chemistry on heavy pollution in the JJJ (Beijing-Tianjin-Hebei) region

    Science.gov (United States)

    Tang, Yu Jia; Xian Liu, Bao; Sun, Feng; Wang, Li Hua; Zhang, Da Wei; Yin, Wen Jun; Zhang, Meng; Ma, Junwen

    2017-04-01

    The NO2 heterogeneous reaction on soot surfaces was incorporated into the WRF-Chem model to assess the impacts of the heterogeneous chemistry on the concentrations of HONO, HOx, O3, NO3-, and NH4+ in the JJJ (Beijing-Tianjin-Hebei) region. Results showed that the soot redox process with a γ value of 10-4 at night and the soot heterogeneous photochemistry with the γ formula of JNO2/10 in the daytime yielded a nighttime HONO increase of 0.4-1.8 ppb and a percentage enhancement of 10%-50% for HOx, 2%-6% for O3, 5%-21% for NO3-, and 6%-17% for NH4+ in the major cities of the JJJ region. The HONO simulations in this case were reasonable compared with observations in Beijing. Minor enhancements were found for HONO, HOx, O3, NO3-, and NH4+, with a maximum increase of 0.2 ppb for HONO and ≤ 6% for HOx, O3, NO3-, and NH4+ when γ was ≤ 10-5. When γ was increased to 10-3, produced are a nighttime maximum enhancement of 8.6 ppb for HONO, and a maximum percentage enhancement of 79% for HOx, 17% for O3, 211% for NO3-, and 152% for NH4+. This case considerably overestimated HONO and NO3- concentrations in Beijing in most cases. The soot surface area per unit volume of air (As) was another key parameter for the NO2 heterogeneous reaction on soot. The As values showed a sharp decrease from 3×103 μm2 cm-3 near the ground to 6×102 μm2 cm-3 at 200 m at night. Although the surface areas of major aerosol components at nighttime were  three times larger than that of those in the daytime, the surface area fractions of the major aerosol components showed minor variations between day and night. The surface area fractions of NO3-, SO42-, and soot were 32%-36%, 25%-28%, and 25%-26%, respectively.

  17. Recycled crust and the secular cooling of mantle plumes

    Science.gov (United States)

    Gazel Dondi, E.; Herzberg, C. T.; Vidito, C. A.

    2012-12-01

    Current models suggest that the massive basaltic production responsible for the emplacement of Large Igneous Provinces (LIPS) during the Permian-Paleocene may represent the initial phases of some of the mantle plumes that feed the current ocean island basalts (OIB). In some cases this magmatism was so voluminous that it produced global environmental impacts. Recent petrological, geochemical and geophysical studies of some of these localities like Samoa, Hawaii, Galapagos provide evidence that melting is related to a true mantle plume that originates from a boundary layer beneath the upper mantle. Thus, plume-related magmas produced in OIB and LIPS and their connecting plume tracks provide evidence on mantle temperature, size and composition of heterogeneities, and deep geochemical cycles. Although a lot of work has been done on LIPS and OIB, no complete record of the evolution of a mantle plume is available to this point. Galapagos-related lavas provide a complete record of the evolution of a mantle plume since the plume's initial stages in the Cretaceous. In the case of the Galapagos, our work suggests a decrease from TP(max) of 1650 °C in the Cretaceous to 1500 °C in the present day. Our recent work on the Galapagos Islands and the preliminary work on older Galapagos-related terranes suggest that this secular cooling is related with increasing amounts of recycled crust in the plume. Detailed olivine chemistry shows that although peridotite is the dominant source lithology of the Galapagos Plume, a recycled pyroxenite component is also significant in both isotopically enriched and depleted domains of the archipelago. We suggest that this possibly represents two separate bodies of recycled crust within the Galapagos mantle plume.

  18. Heterogeneous chemistry and reaction dynamics of the atmospheric oxidants, O3, NO3, and OH, on organic surfaces.

    Science.gov (United States)

    Chapleski, Robert C; Zhang, Yafen; Troya, Diego; Morris, John R

    2016-07-07

    Heterogeneous chemistry of the most important atmospheric oxidants, O3, NO3, and OH, plays a central role in regulating atmospheric gas concentrations, processing aerosols, and aging materials. Recent experimental and computational studies have begun to reveal the detailed reaction mechanisms and kinetics for gas-phase O3, NO3, and OH when they impinge on organic surfaces. Through new research approaches that merge the fields of traditional surface science with atmospheric chemistry, researchers are developing an understanding for how surface structure and functionality affect interfacial chemistry with this class of highly oxidizing pollutants. Together with future research initiatives, these studies will provide a more complete description of atmospheric chemistry and help others more accurately predict the properties of aerosols, the environmental impact of interfacial oxidation, and the concentrations of tropospheric gases.

  19. Controls of Polysaccharide Chemistry on the Kinetics and Thermodynamics of Heterogeneous Calcium Carbonate Nucleation

    Science.gov (United States)

    Giuffre, A. J.; Han, N.; Dove, P. M.

    2011-12-01

    Polysaccharide fibrils control the orientation of calcium carbonate (CaCO3) biominerals. Good examples are found in the multilayered extracellular mucilaginous sheath of green algae and cyanobacteria and in specialized vesicles inside coccolithophorids. More complex organisms such as arthropods and mollusks form biomineralized exoskeletons and shells that consist of insoluble polysaccharides and soluble acid-rich proteins. In these structures, CaCO3 mineral orientation occurs along fibers of the polysaccharide chitin. This raises the question of whether polysaccharide chemistry has specific roles in directing biomineralization. The last three decades of research show that acidic proteins influence CaCO3 polymorph selection, crystallographic orientation, and nucleation and growth rates but little is known about the function of polysaccharides. In fact, polysaccharides are long considered an inert component of organic frameworks. In this experimental investigation, we test the hypothesis that polysaccharides have chemistry-specific influences on calcification by measuring the kinetics of calcite nucleation onto three types of polysaccharide films under controlled solution compositions. Characterized polysaccharides of simple repeating monomer sequences were chosen as model compounds to represent the major carbohydrates seen in microbial and calcifying environments: 1) alginic acid with carboxyl groups, 2) hyaluronic acid with alternating carboxyl and acetylamine groups, and 3) chitosan with amine and acetylamine groups. Biosubstrates were prepared by electrodeposition of these compounds as thin gel-like films onto gold-coated silicon wafers. Using a flow-through cell, heterogeneous nucleation rates of calcite were measured for a suite of supersaturation conditions. These rate data were compared to similar measurements for carboxyl- and hydroxyl-terminated self-assembled monolayers. Calcite nucleation rates onto the three polysaccharides vary by a factor of 400x

  20. Modeling atmospheric mineral aerosol chemistry to predict heterogeneous photooxidation of SO2

    Directory of Open Access Journals (Sweden)

    Z. Yu

    2017-08-01

    Full Text Available The photocatalytic ability of airborne mineral dust particles is known to heterogeneously promote SO2 oxidation, but prediction of this phenomenon is not fully taken into account by current models. In this study, the Atmospheric Mineral Aerosol Reaction (AMAR model was developed to capture the influence of air-suspended mineral dust particles on sulfate formation in various environments. In the model, SO2 oxidation proceeds in three phases including the gas phase, the inorganic-salted aqueous phase (non-dust phase, and the dust phase. Dust chemistry is described as the absorption–desorption kinetics of SO2 and NOx (partitioning between the gas phase and the multilayer coated dust. The reaction of absorbed SO2 on dust particles occurs via two major paths: autoxidation of SO2 in open air and photocatalytic mechanisms under UV light. The kinetic mechanism of autoxidation was first leveraged using controlled indoor chamber data in the presence of Arizona Test Dust (ATD particles without UV light, and then extended to photochemistry. With UV light, SO2 photooxidation was promoted by surface oxidants (OH radicals that are generated via the photocatalysis of semiconducting metal oxides (electron–hole theory of ATD particles. This photocatalytic rate constant was derived from the integration of the combinational product of the dust absorbance spectrum and wave-dependent actinic flux for the full range of wavelengths of the light source. The predicted concentrations of sulfate and nitrate using the AMAR model agreed well with outdoor chamber data that were produced under natural sunlight. For seven consecutive hours of photooxidation of SO2 in an outdoor chamber, dust chemistry at the low NOx level was attributed to 55 % of total sulfate (56 ppb SO2, 290 µg m−3 ATD, and NOx less than 5 ppb. At high NOx ( >  50 ppb of NOx with low hydrocarbons, sulfate formation was also greatly promoted by dust chemistry, but it was suppressed by

  1. Modeling atmospheric mineral aerosol chemistry to predict heterogeneous photooxidation of SO2

    Science.gov (United States)

    Yu, Zechen; Jang, Myoseon; Park, Jiyeon

    2017-08-01

    The photocatalytic ability of airborne mineral dust particles is known to heterogeneously promote SO2 oxidation, but prediction of this phenomenon is not fully taken into account by current models. In this study, the Atmospheric Mineral Aerosol Reaction (AMAR) model was developed to capture the influence of air-suspended mineral dust particles on sulfate formation in various environments. In the model, SO2 oxidation proceeds in three phases including the gas phase, the inorganic-salted aqueous phase (non-dust phase), and the dust phase. Dust chemistry is described as the absorption-desorption kinetics of SO2 and NOx (partitioning between the gas phase and the multilayer coated dust). The reaction of absorbed SO2 on dust particles occurs via two major paths: autoxidation of SO2 in open air and photocatalytic mechanisms under UV light. The kinetic mechanism of autoxidation was first leveraged using controlled indoor chamber data in the presence of Arizona Test Dust (ATD) particles without UV light, and then extended to photochemistry. With UV light, SO2 photooxidation was promoted by surface oxidants (OH radicals) that are generated via the photocatalysis of semiconducting metal oxides (electron-hole theory) of ATD particles. This photocatalytic rate constant was derived from the integration of the combinational product of the dust absorbance spectrum and wave-dependent actinic flux for the full range of wavelengths of the light source. The predicted concentrations of sulfate and nitrate using the AMAR model agreed well with outdoor chamber data that were produced under natural sunlight. For seven consecutive hours of photooxidation of SO2 in an outdoor chamber, dust chemistry at the low NOx level was attributed to 55 % of total sulfate (56 ppb SO2, 290 µg m-3 ATD, and NOx less than 5 ppb). At high NOx ( > 50 ppb of NOx with low hydrocarbons), sulfate formation was also greatly promoted by dust chemistry, but it was suppressed by the competition between NO2 and SO2

  2. Aging of Refractory Black Carbon in Power Plant Plumes by Sulfate-Driven Chemistry during the Southeast Nexus (SENEX) study

    Science.gov (United States)

    Markovic, M. Z.; Perring, A. E.; Schwarz, J. P.; Gao, R. S.; Holloway, J. S.; Liao, J.; Middlebrook, A. M.; Brock, C. A.; Welti, A.; Pollack, I. B.; Ryerson, T. B.; Trainer, M.; De Gouw, J. A.; Wagner, N. L.; Fahey, D. W.

    2014-12-01

    Refractory black carbon (rBC) aerosol is mostly emitted into the atmosphere from biomass burning and incomplete combustion of fossil and biofuel. Emissions of rBC are strongly linked to anthropogenic activity, with potential for short-term mitigation strategies. rBC aerosol is currently the second largest anthropogenic climate forcing agent after CO2(g) with the total radiative forcing of 0.64 W m-2. Its climate impacts, which depend in part on vertical distribution and internal mixing state, are not fully understood. Internal mixing of rBC with sulfate was previously predicted by the aerosol-climate model, ECHAM5-HAM, to increase the aerosol absorption optical depth by 10 - 30 % despite decreasing the atmospheric burden of rBC by 10 - 20 % in the Southeastern U.S. The measurements of rBC from Single Particle Soot Photometer (SP2) instruments onboard the NOAA WP-3D research aircraft during the SENEX study constrain chemical aging of rBC by sulfate in coal-fired power plant plumes, and hence, constrain the model predictions. The number fraction of rBC-containing particles that can be identified as coated (CF) and the estimated coating thickness (CT) of non-rBC material internally mixed in them were in many cases higher (1 - 5 %, 1 - 12 nm) in power plant plume intercepts downwind of the power plants than in the background air. However, there was a lack of a clear pattern of increase in CT and CF with an age of a power plant plume, and the respective growth rates were only 3.5 ± 0.8 nm hr-1 and 1.1 ± 0.5 % hr-1 at maxima. This is likely the consequence of the condensation of sulfate on non-rBC particles, which are present in higher concentrations in the power plant plumes. The impacts of the observed CT and CF growth rates on the lifetime and radiative properties of rBC in the Southeast U.S. will be further discussed and compared to the model predictions.

  3. Pb, Nd, and Sr isotopic evidence for a multicomponent source for rocks of Cook-Austral Islands and heterogeneities of mantle plumes

    Energy Technology Data Exchange (ETDEWEB)

    Nakamura, Yoichi; Tatsumoto, Mitsunobu (Geological Survey, Denver, CO (USA))

    1988-12-01

    Sr, Nd, and Pb isotopic compositions were measured in alkane volcanic rocks from the South Cook Islands and the Austral Islands. The results show that the Cook-Austral rocks have an extremely wide range in isotopic compositions of Pb: {sup 206}Pb/{sup 204}Pb from 18.25 to 21.76, {sup 207}Pb/{sup 204}Pb from 15.48 to 15.83, and {sup 208}Pb/{sup 204}Pb from 38.37 to 40.62, whereas isotopic compositions of Sr and Nd are less variable. Isotopically, Mangaia, Rimatara, and Rurutu form one group, which shows extremely ratiogenic Pb isotopic compositions but near-MORB (mid-ocean ridge basalts) values for Sr and Nd isotopic ratios. In contrast, samples from Aitutaki, Rarotonga, Mauke, and Atiu (Aitutaki group) have high {sup 207}Pb/{sup 204}Pb and {sup 208}Pb/{sup 204}Pb and moderately high {sup 87}Sr/{sup 86}Sr (Dupal anomaly). The Aitutaki group could have been derived from heterogeneous mantle plumes, which rose from the enriched deep mantle (the almost primitive lower mantle or recycled continental and oceanic slabs). On the other hand, the Mangaia component could have been derived from the depleted upper mantle which may have been metasomatized with a Co{sub 2}-rich fluid, as indicated by the near-MORB values of Sr and Nd isotopes. Although Pb isotopic data of the two groups cannot be distinguished from each other statistically, the end components of the Pb-Pb system do not match with those of the Nd-Sr system. Thus, the data must be explained by a multi-, at least three, component mixing model: the mantle plumes, metasomatized upper mantle, and lithosphere. The K-Ar ages and isotopic characteristics of the Cook-Austral rocks indicate that if one mantle plume rises from the deep mantle in this region, it has separated into at least two segments on the way to the surface.

  4. Pb, Nd, and Sr isotopic evidence for a multicomponent source for rocks of Cook-Austral Islands and heterogeneities of mantle plumes

    Science.gov (United States)

    Nakamura, Y.; Tatsumoto, M.

    1988-01-01

    Sr, Nd, and Pb isotopic compositions were measured in alkaline volcanic rocks (alkali basalt, ankaramite, nephelinite, phonolite, and trachyte) from the South Cook Islands (Aitutaki, Mauke, Rarotonga, Atiu, and Mangaia) and the Austral Islands (Rimatara and Rurutu). The results show that the Cook-Austral rocks have an extremely wide range in isotopic compositions of Pb: 206Pb 204Pb from 18.25 to 21.76, 207pb 204pb from 15.48 to 15.83, and sol208pb 204Pb from 38.37 to 40.62, whereas isotopic compositions of Sr and Nd are less variable. Isotopically, Mangaia, Rimatara, and Rurutu form one group (Mangaia group), which shows extremely radiogenic Pb isotopic compositions but near-MORB (mid-oceanic ridge basalts) values for Sr and Nd isotopic ratios. In contrast, samples from Aitutaki, Rarotonga, Mauke, and Atiu (Aitutaki group) have high 207Pb 204Pb and 208Pb 204Pb and moderately high 87Sr 86Sr (Dupal anomaly). The Aitutaki group could have been derived from heterogeneous mantle plumes, which rose from the enriched deep mantle (the almost primitive lower mantle or recycled continental and oceanic slabs). On the other hand, the Mangaia component could have been derived from the depleted upper mantle which may have been metasomatized with a CO2-rich fluid, as indicated by the near-MORB values of Sr and Nd isotopes. Although Pb isotopic data of the two groups cannot be distinguished from each other statistically, the end components of the Pb-Pb system do not match with those of the Nd-Sr system. Thus, the data must be explained by a multi-, at least three, component mixing model: the mantle plumes (Dupal component and a recycled oceanic slab), metasomatized upper mantle, and lithosphere. The K-Ar ages and isotopic characteristics of the Cook-Austral rocks indicate that if one mantle plume rises from the deep mantle in this region, it has separated into at least two segments on the way to the surface. ?? 1988.

  5. Heterogeneous chemistry of NO{sub 3} in clouds and fogs

    Energy Technology Data Exchange (ETDEWEB)

    Rudich, Y.; Talukdar, R.K.; Fox, R. [NOAA, Aeronomy Lab., Boulder (United States)] [and others

    1996-10-01

    The heterogeneous reactions of the nitrate free radical (NO{sub 3}) an important nighttime oxidant in the lower troposphere, in clouds and fogs are unexplored. Therefore, the uptake coefficients ({gamma}) of NO{sub 3} onto pure water and other dilute solutions were measured. The product of Henry`s law constant, H, and diffusion coefficient D{sub {ell}}, for NO{sub 3} in water was calculated to be H{radical}D{sub {ell}} = (1.9{plus_minus}0.2)x10{sup -3} M atm{sup -1} cm s-{sup 1/2} and H , was determined to be 0.6{plus_minus}0.3 M atm{sup -1}. Uptake of NO{sub 3} on pure water is interpreted as due to reaction of NO{sub 3(aq)} with H{sub 2}O{sub ({ell})} to produce HNO{sub 3} and OH in the liquid phase. Details of these measurements and the implications of these findings to the chemistry of NO{sub 3} in the troposphere will discussed.

  6. Heterogeneous chemistry of glyoxal on acidic solutions. An oligomerization pathway for secondary organic aerosol formation.

    Science.gov (United States)

    Gomez, Mario E; Lin, Yun; Guo, Song; Zhang, Renyi

    2015-05-14

    The heterogeneous chemistry of glyoxal on sulfuric acid surfaces has been investigated at various acid concentrations and temperatures, utilizing a low-pressure fast flow laminar reactor coupled to an ion drift-chemical ionization mass spectrometer (ID-CIMS). The uptake coefficient (γ) of glyoxal ranges from (1.2 ± 0.06) × 10(-2) to (2.5 ± 0.01) × 10(-3) for 60-93 wt % H2SO4 at 253-273 K. The effective Henry's Law constant (H*) ranges from (98.9 ± 4.9) × 10(5) to (1.6 ± 0.1) × 10(5) M atm(-1) for 60-93 wt % at 263-273 K. Both the uptake coefficient and Henry's Law constant increase with decreasing acid concentration and temperature. Our results reveal a reaction mechanism of hydration followed by oligomerization for glyoxal on acidic media, indicating an efficient aqueous reaction of glyoxal on hygroscopic particles leading to secondary organic aerosol formation.

  7. Laboratory Investigations of Heterogeneous Chemistry Important to Ozone Depletion in the Stratosphere

    Science.gov (United States)

    Zhang, Renyi

    Results of laboratory investigations of heterogeneous chemistry important to ozone depletion in the stratosphere are presented. Thermodynamic properties (such as melting points, enthalpies of fusion, etc.) for acids which are present in the stratosphere (HCl, HNO_3 , and H_2SO_4 ) are studied using laboratory-assembled apparatus of electrical conductivity and differential thermal analysis and using a commercial differential scanning calorimeter (DSC). Vapor pressures and infrared spectra of liquid and supercooled solutions, and of liquid-solid and solid -solid coexistence mixtures for the HCl/H_2 O and H_2SO_4 /H_2O binary systems are investigated. Equilibrium constants and standard enthalpies of formation for the pure crystalline hydrates of those acids as well as their corresponding liquid compositions are determined from the vapor pressure and calorimetric data. A theoretical approach, which allows determination of vapor pressures for two adjacent hydrates in thermodynamic equilibrium and for the coexistence systems involving a hydrate and ice in a binary system, is presented in terms of chemical equilibrium principles and compared with the experimental data for thermodynamic consistence. Vapor pressures of HNO_3 and HCl over H_2SO_4 /HNO_3/H_2 O and H_2SO_4 /HCl/H_2O solutions as well as over H_2SO_4/HNO _3/HCl/H_2O solutions are also measured in order to predict incorporation of stratospheric acids into the background sulfate aerosols. From the data, the Henry's law solubility constants for those systems are determined and the equilibrium compositions of aqueous stratospheric aerosols are predicted as a function of ambient temperature and mixing ratios of H_2 O and HNO_3. The results indicate that at the low temperatures characteristic of the stratosphere at high latitudes in the winter and spring, the HNO_3 content reaches levels of the order of 10% wt in the background sulfate aerosols. The results also reveal that the amount of dissolved HCl in the

  8. The Impact of DNAPL Source-Zone Architecture on Contaminant Mass Flux and Plume Evolution in Heterogeneous Porous Media

    Science.gov (United States)

    2013-08-01

    M.D.; Jawitz, J.W. 2008. Laboratory investigation of flux reduction from dense non-aqueous phase liquid (DNAPL) partial source zone remediation by...project was designed to accomplish a systematic study of the mass-transfer behavior of chlorinated-solvent immiscible liquids in heterogeneous porous...5.1.3-1b Summary of experimental conditions……………………………………… 43 Tables 5.3.1-1 Summary of miscible -displacement experiments…………………………… 63 Table 5.3.1

  9. Impact of volcanic plume emissions on rain water chemistry during the January 2010 Nyamuragira eruptive event: implications for essential potable water resources.

    Science.gov (United States)

    Cuoco, Emilio; Tedesco, Dario; Poreda, Robert J; Williams, Jeremy C; De Francesco, Stefano; Balagizi, Charles; Darrah, Thomas H

    2013-01-15

    On January 2, 2010 the Nyamuragira volcano erupted lava fountains extending up to 300 m vertically along an ~1.5 km segment of its southern flank cascading ash and gas on nearby villages and cities along the western side of the rift valley. Because rain water is the only available potable water resource within this region, volcanic impacts on drinking water constitutes a major potential hazard to public health within the region. During the 2010 eruption, concerns were expressed by local inhabitants about water quality and feelings of physical discomfort (e.g. nausea, bloating, indigestion, etc.) after consuming rain water collected after the eruption began. We present the elemental and ionic chemistry of drinking water samples collected within the region on the third day of the eruption (January 5, 2010). We identify a significant impact on water quality associated with the eruption including lower pH (i.e. acidification) and increases in acidic halogens (e.g. F(-) and Cl(-)), major ions (e.g. SO(4)(2-), NH(4)(+), Na(+), Ca(2+)), potentially toxic metals (e.g. Al(3+), Mn(2+), Cd(2+), Pb(2+), Hf(4+)), and particulate load. In many cases, the water's composition significantly exceeds World Health Organization (WHO) drinking water standards. The degree of pollution depends upon: (1) ash plume direction and (2) ash plume density. The potential negative health impacts are a function of the water's pH, which regulates the elements and their chemical form that are released into drinking water. Copyright © 2012 Elsevier B.V. All rights reserved.

  10. Three-D Simulation of the Origin of the Pollutant Ozone Maxima in the Great African Plume: New Meteorology, New Chemistry for TRACE-A

    Science.gov (United States)

    Chatfeild, Robert; Vastano, John; Singh, Hanwant; Chan, K. Roland (Technical Monitor)

    1996-01-01

    Burning in South Central Africa is primarily responsible for the vast buildup of ozone in the mid-Atlantic noticeable in the Belem, Brazil, ozonesondes, and also visible in analyses using the Total Ozone Mapping Spectrometer (TOMS). We report on full-scale chemistry simulations for the SAFARI/TRACE-A field period of September-October, 1992. These observational programs provided a wealth of comparison data, including spectacular depictions of the vertical structure of ozone and particulate pollution over Africa, South America, and the Equatorial Atlantic [Browell JGR, 1996, submitted] above and below the NASA DC-8 airplane path. These depictions provide strict tests on the ability of a 3-d simulation and its controlling input parameters, most notably the biomass burning emissions strength. We use meteorology from MM5 used as a synoptic assimilation model and our own GRACES Global Regional Air Chemistry Event Simulator. This report will focus on the unique meteorology of the Equatorial Atmosphere around the Gulf of Guinea during the TRACE-A period, which we describe as "the opening of the gate," "the Great African Plume," and the "African Recirculatory System." We expect to assess whether the ozone observed is primarily "transported African smog," the standard view, or whether "re-$NO_[x)$-ification" of the Central Atlantic troposphere (reduction of nitric acid to active nitrogen oxides in clouds or aerosol) may be required for "extended intercontinental ozone production." A status report on a second nitrogen problem, "lower-tropospheric missing NO(y)," in which we find a serious imbalance in the $NO_ {x }$ and $NO_{y}$ budgets when compared with similar atmospheric tracers, will be given. An elaboration of the concepts set off by quotation marks in this abstract will be given in the talk.

  11. Insights from 2D numerical models on two-branch continental break-up: a single mantle plume's effect on a laterally heterogeneous lithosphere

    Science.gov (United States)

    Beniest, Anouk; Koptev, Alexander; Leroy, Sylvie

    2017-04-01

    We use 2D numerical models to investigate the impact of the location of one single mantle plume on the break-up evolution of realistic rheologically stratified continental lithosphere. The lithosphere is characterized by a laterally non-homogeneous rheology: a "weak" crust for the left half of the model box and a "strong" crust for the right one. We tested different experimental settings by varying three controlling parameters: the initial location of the mantle anomaly, Moho temperature and extension velocities. The results of our experiments are two-folded. Firstly, in most of the models, break-up occurs within the central part of the model domain at the boundary between weak and strong crust. This "structurally inherited" mode of continental break-up persists even when the mantle plume has been initially seeded underneath the stronger lithosphere segment with considerable (up to 300 km) shift from the central position. When the initial plume is positioned at a significant distant from this structure (>=400 km), lithospheric rupture may also develop in the "strong" half of the lithosphere directly above the upwelled plume head ("plume-centered" mode). Secondly, when the plume anomaly is seeded between 300 km and 400 km away from the boundary between the "weak" and "strong" crust, the model cultivates a two-branch rift system when both "structurally inherited" and "plume-centered" break-up develop consecutively, under the influence of one single plume. The opening of the Labrador Sea and the North Atlantic can be a natural example of a two-branch system due to one single Iceland plume. Additional experiments show that hotter crustal geotherm favors "plume-centered" mode of lithospheric rupture whereas slower far-field extension always results in "structurally inherited" break-up regardless of initial plume location. These results show that the "classical" model, where one plume anomaly produces a single break-up center situated directly overhead, is only one way

  12. Nano-sized metabolic precursors for heterogeneous tumor-targeting strategy using bioorthogonal click chemistry in vivo.

    Science.gov (United States)

    Lee, Sangmin; Jung, Seulhee; Koo, Heebeom; Na, Jin Hee; Yoon, Hong Yeol; Shim, Man Kyu; Park, Jooho; Kim, Jong-Ho; Lee, Seulki; Pomper, Martin G; Kwon, Ick Chan; Ahn, Cheol-Hee; Kim, Kwangmeyung

    2017-12-01

    Herein, we developed nano-sized metabolic precursors (Nano-MPs) for new tumor-targeting strategy to overcome the intrinsic limitations of biological ligands such as the limited number of biological receptors and the heterogeneity in tumor tissues. We conjugated the azide group-containing metabolic precursors, triacetylated N-azidoacetyl-d-mannosamine to generation 4 poly(amidoamine) dendrimer backbone. The nano-sized dendrimer of Nano-MPs could generate azide groups on the surface of tumor cells homogeneously regardless of cell types via metabolic glycoengineering. Importantly, these exogenously generated 'artificial chemical receptors' containing azide groups could be used for bioorthogonal click chemistry, regardless of phenotypes of different tumor cells. Furthermore, in tumor-bearing mice models, Nano-MPs could be mainly localized at the target tumor tissues by the enhanced permeation and retention (EPR) effect, and they successfully generated azide groups on tumor cells in vivo after an intravenous injection. Finally, we showed that these azide groups on tumor tissues could be used as 'artificial chemical receptors' that were conjugated to bioorthogonal chemical group-containing liposomes via in vivo click chemistry in heterogeneous tumor-bearing mice. Therefore, overall results demonstrated that our nano-sized metabolic precursors could be extensively applied to new alternative tumor-targeting technique for molecular imaging and drug delivery system, regardless of the phenotype of heterogeneous tumor cells. Copyright © 2017 Elsevier Ltd. All rights reserved.

  13. The Development of a Combined Search for a Heterogeneous Chemistry Database

    National Research Council Canada - National Science Library

    Lulu Jiang; Yuehong Zhao; Bojun Xu; Hao Wen

    2015-01-01

    .... In this paper, two kinds of search strategies, synchronous search and asynchronous search, are proposed to solve these problems in the heterogeneous structure database and the property database found...

  14. Heterogeneous chemistry: a mechanism missing in current models to explain secondary inorganic aerosol formation during the January 2013 haze episode in North China

    Science.gov (United States)

    Zheng, B.; Zhang, Q.; Zhang, Y.; He, K. B.; Wang, K.; Zheng, G. J.; Duan, F. K.; Ma, Y. L.; Kimoto, T.

    2015-02-01

    Severe regional haze pollution events occurred in eastern and central China in January 2013, which had adverse effects on the environment and public health. Extremely high levels of particulate matter with aerodynamic diameter of 2.5 μm or less (PM2.5) with dominant components of sulfate and nitrate are responsible for the haze pollution. Although heterogeneous chemistry is thought to play an important role in the production of sulfate and nitrate during haze episodes, few studies have comprehensively evaluated the effect of heterogeneous chemistry on haze formation in China by using the 3-D models due to of a lack of treatments for heterogeneous reactions in most climate and chemical transport models. In this work, the WRF-CMAQ model with newly added heterogeneous reactions is applied to East Asia to evaluate the impacts of heterogeneous chemistry and the meteorological anomaly during January 2013 on regional haze formation. As the parameterization of heterogeneous reactions on different types of particles is not well established yet, we arbitrarily selected the uptake coefficients from reactions on dust particles and then conducted several sensitivity runs to find the value that can best match observations. The revised CMAQ with heterogeneous chemistry not only captures the magnitude and temporal variation of sulfate and nitrate, but also reproduces the enhancement of relative contribution of sulfate and nitrate to PM2.5 mass from clean days to polluted haze days. These results indicate the significant role of heterogeneous chemistry in regional haze formation and improve the understanding of the haze formation mechanisms during the January 2013 episode.

  15. Chemistry, spectroscopy and the role of supported vanadium oxides in heterogeneous catalysis

    NARCIS (Netherlands)

    Weckhuysen, B.M.; Keller, D.E.

    2003-01-01

    Supported vanadium oxide catalysts are active in a wide range of applications. In this review, an overview is given of the current knowledge available about vanadium oxide-based catalysts. The review starts with the importance of vanadium in heterogeneous catalysis, a discussion of the molecular

  16. Importance of sulfate radical anion formation and chemistry in heterogeneous OH oxidation of sodium methyl sulfate, the smallest organosulfate

    Directory of Open Access Journals (Sweden)

    K. C. Kwong

    2018-02-01

    Full Text Available Organosulfates are important organosulfur compounds present in atmospheric particles. While the abundance, composition, and formation mechanisms of organosulfates have been extensively investigated, it remains unclear how they transform and evolve throughout their atmospheric lifetime. To acquire a fundamental understanding of how organosulfates chemically transform in the atmosphere, this work investigates the heterogeneous OH radical-initiated oxidation of sodium methyl sulfate (CH3SO4Na droplets, the smallest organosulfate detected in atmospheric particles, using an aerosol flow tube reactor at a high relative humidity (RH of 85 %. Aerosol mass spectra measured by a soft atmospheric pressure ionization source (direct analysis in real time, DART coupled with a high-resolution mass spectrometer showed that neither functionalization nor fragmentation products are detected. Instead, the ion signal intensity of the bisulfate ion (HSO4− has been found to increase significantly after OH oxidation. We postulate that sodium methyl sulfate tends to fragment into a formaldehyde (CH2O and a sulfate radical anion (SO4 ⋅ − upon OH oxidation. The formaldehyde is likely partitioned back to the gas phase due to its high volatility. The sulfate radical anion, similar to OH radical, can abstract a hydrogen atom from neighboring sodium methyl sulfate to form the bisulfate ion, contributing to the secondary chemistry. Kinetic measurements show that the heterogeneous OH reaction rate constant, k, is (3.79 ± 0.19  ×  10−13 cm3 molecule−1 s−1 with an effective OH uptake coefficient, γeff, of 0.17 ± 0.03. While about 40 % of sodium methyl sulfate is being oxidized at the maximum OH exposure (1.27  ×  1012 molecule cm−3 s, only a 3 % decrease in particle diameter is observed. This can be attributed to a small fraction of particle mass lost via the formation and volatilization of formaldehyde. Overall, we

  17. Evaluated kinetic and photochemical data for atmospheric chemistry: Volume VI – heterogeneous reactions with liquid substrates

    Directory of Open Access Journals (Sweden)

    M. Ammann

    2013-08-01

    Full Text Available This article, the sixth in the ACP journal series, presents data evaluated by the IUPAC Task Group on Atmospheric Chemical Kinetic Data Evaluation. It covers the heterogeneous processes involving liquid particles present in the atmosphere with an emphasis on those relevant for the upper troposphere/lower stratosphere and the marine boundary layer, for which uptake coefficients and adsorption parameters have been presented on the IUPAC website since 2009. The article consists of an introduction and guide to the evaluation, giving a unifying framework for parameterisation of atmospheric heterogeneous processes. We provide summary sheets containing the recommended uptake parameters for the evaluated processes. The experimental data on which the recommendations are based are provided in data sheets in separate appendices for the four surfaces considered: liquid water, deliquesced halide salts, other aqueous electrolytes and sulfuric acid.

  18. "Click Chemistry" Mediated Functional Microporous Organic Nanotube Networks for Heterogeneous Catalysis.

    Science.gov (United States)

    Yu, Wei; Zhou, Minghong; Wang, Tianqi; He, Zidong; Shi, Buyin; Xu, Yang; Huang, Kun

    2017-10-26

    The synthesis of azide functional microporous organic nanotube networks (N3-MONNs) via a Friedel-Crafts hyper-cross-linking reaction is reported. Subsequently, a general method for obtaining heterogeneous catalysts through a Cu-catalyzed alkyne-azide reaction is presented. The small-molecule catalysts such as 2,2,6,6,-tetramethylpiperidine-1-oyl and 4-(N,N-dimethylamino)pyridine can be anchored into the MONNs. Owing to the hierarchically porous structure and high surface area, these catalysts show high activity in selective oxidation of alcohols and acylation reaction, respectively.

  19. A heterogeneous chemistry model for acid rain`s effect on ozone

    Energy Technology Data Exchange (ETDEWEB)

    Ye, Tao [Univ. of New York, Stonybrook, NY (United States)

    1995-11-01

    A computer model for simulating heterogeneous reactions in cloud is developed to determine the S(IV) species` effect on ozone. Crutzen claims that NO{sub x}, HO{sub x} families and H{sub 2}CO in the troposphere can decrease ozone by 5 to 10%. However, is this claim valid for a SO{sub x} polluted atmosphere? The SO{sub x} family reacts with the ozone destroyers. These reactions seem to be significant enough to reduce the H{sub 2}CO`s destructive effect on ozone.

  20. Major Successes of Theory-and-Experiment-Combined Studies in Surface Chemistry and Heterogeneous Catalysis.

    Energy Technology Data Exchange (ETDEWEB)

    Somorjai, Gabor A.; Li, Yimin

    2009-11-21

    Experimental discoveries followed by theoretical interpretations that pave the way of further advances by experimentalists is a developing pattern in modern surface chemistry and catalysis. The revolution of modern surface science started with the development of surface-sensitive techniques such as LEED, XPS, AES, ISS and SIMS, in which the close collaboration between experimentalists and theorists led to the quantitative determination of surface structure and composition. The experimental discovery of the chemical activity of surface defects and the trends in the reactivity of transitional metals followed by the explanations from the theoretical studies led to the molecular level understanding of active sites in catalysis. The molecular level knowledge, in turn, provided a guide for experiments to search for new generation of catalysts. These and many other examples of successes in experiment-and-theory-combined studies demonstrate the importance of the collaboration between experimentalists and theorists in the development of modern surface science.

  1. Uncertainties in modelling heterogeneous chemistry and Arctic ozone depletion in the winter 2009/2010

    Directory of Open Access Journals (Sweden)

    I. Wohltmann

    2013-04-01

    Full Text Available Stratospheric chemistry and denitrification are simulated for the Arctic winter 2009/2010 with the Lagrangian Chemistry and Transport Model ATLAS. A number of sensitivity runs is used to explore the impact of uncertainties in chlorine activation and denitrification on the model results. In particular, the efficiency of chlorine activation on different types of liquid aerosol versus activation on nitric acid trihydrate clouds is examined. Additionally, the impact of changes in reaction rate coefficients, in the particle number density of polar stratospheric clouds, in supersaturation, temperature or the extent of denitrification is investigated. Results are compared to satellite measurements of MLS and ACE-FTS and to in-situ measurements onboard the Geophysica aircraft during the RECONCILE measurement campaign. It is shown that even large changes in the underlying assumptions have only a small impact on the modelled ozone loss, even though they can cause considerable differences in chemical evolution of other species and in denitrification. Differences in column ozone between the sensitivity runs stay below 10% at the end of the winter. Chlorine activation on liquid aerosols alone is able to explain the observed magnitude and morphology of the mixing ratios of active chlorine, reservoir gases and ozone. This is even true for binary aerosols (no uptake of HNO3 from the gas-phase allowed in the model. Differences in chlorine activation between sensitivity runs are within 30%. Current estimates of nitric acid trihydrate (NAT number density and supersaturation imply that, at least for this winter, NAT clouds play a relatively small role compared to liquid clouds in chlorine activation. The change between different reaction rate coefficients for liquid or solid clouds has only a minor impact on ozone loss and chlorine activation in our sensitivity runs.

  2. Application of physical adsorption thermodynamics to heterogeneous chemistry on polar stratospheric clouds

    Science.gov (United States)

    Elliott, Scott; Turco, Richard P.; Toon, Owen B.; Hamill, Patrick

    1991-01-01

    Laboratory isotherms for the binding of several nonheterogeneously active atmospheric gases and for HCl to water ice are translated into adsorptive equilibrium constants and surface enthalpies. Extrapolation to polar conditions through the Clausius Clapeyron relation yields coverage estimates below the percent level for N2, Ar, CO2, and CO, suggesting that the crystal faces of type II stratospheric cloud particles may be regarded as clean with respect to these species. For HCl, and perhaps HF and HNO3, estimates rise to several percent, and the adsorbed layer may offer acid or proton sources alternate to the bulk solid for heterogeneous reactions with stratospheric nitrates. Measurements are lacking for many key atmospheric molecules on water ice, and almost entirely for nitric acid trihydrate as substrate. Adsorptive equilibria enter into gas to particle mass flux descriptions, and the binding energy determines rates for desorption of, and encounter between, potential surface reactants.

  3. Gas-surface interactions and heterogeneous chemistry on interstellar grains analogues

    Directory of Open Access Journals (Sweden)

    Cazaux S.

    2012-01-01

    Full Text Available Detailed laboratory studies and progress in surface science technique, have allowed in recent years the first experimental confirmation of surface reaction schemes, as introduced by Tielens, Hagen and Charnley [1,2]. In this paper, we review few heterogeneous processes which give routes to form elementary molecules considered as precursors for explaining the variety and richness of molecular species in the interstellar medium. Adsorption, diffusion and reaction processes are discussed. With emphasis on the experimental approaches, but also supported by theoretical developments, progresses in the understanding of the “catalytic role” of a dust grain surface in various physical conditions are described. Recent advances made on few important species (H2, H2O, CH3OH are used to illustrate basic properties and raise open questions.

  4. Importance of heterogeneous processes to tropospheric chemistry - Studies with a one-dimensional model

    Science.gov (United States)

    Turco, R. P.; Toon, O. B.; Whitten, R. C.; Keesee, R. G.; Hamill, P.

    1982-01-01

    A one-dimensional, time-dependent model of tropospheric air composition is developed which incorporates several heterogeneous physical and chemical processes. The model includes the interaction of gases, aerosols, and hydrometeors through the physical mechanisms of nucleation, condensation, evaporation, coagulation, coalescence, and deliquescence. Precipitation, sedimentation, and dry deposition act to remove material from the atmosphere, while chemical transformations occur both in the vapor and the condensed phases. The model also incorporates the sources and vertical diffusion of gases and particles, as well as changes in the solar intensity caused by light-scattering from aerosols and clouds. Preliminary simulations made using this model indicate that rainout and washout processes strongly influence the distributions of tropospheric gases and aerosols under certain conditions.

  5. Chemistry?!

    Indian Academy of Sciences (India)

    Chemistry is the science of matter and of its transformations, and life is its highest expression. It provides structures endowed with properties and develops processes for the synthesis of structures. It plays a primordial role in our understanding of material phe- nomena, in our capability to act upon them, to modify them, to.

  6. Modeling and experimental validation of CO heterogeneous chemistry and electrochemistry in solid oxide fuel cells

    Energy Technology Data Exchange (ETDEWEB)

    Yurkiv, Vitaly

    2010-12-17

    In the present work experimental and numerical modeling studies of the heterogeneously catalyzed and electrochemical oxidation of CO at Nickel/yttria-stabilized zirconia (YSZ) solid oxide fuel cell (SOFC) anode systems were performed to evaluate elementary charge-transfer reaction mechanisms taking place at the three-phase boundary of CO/CO{sub 2} gas-phase, Ni electrode, and YSZ electrolyte. Temperature-programmed desorption and reaction experiments along with density functional theory calculations were performed to determine adsorption/desorption and surface diffusion kinetics as well as thermodynamic data for the CO/CO{sub 2}/Ni and CO/CO{sub 2}/YSZ systems. Based on these data elementary reaction based models with four different charge transfer mechanisms for the electrochemical CO oxidation were developed and applied in numerical simulations of literature experimental electrochemical data such as polarization curves and impedance spectra. Comparison between simulation and experiment demonstrated that only one of the four charge transfer mechanisms can consistently reproduce the electrochemical data over a wide range of operating temperatures and CO/CO{sub 2} gas compositions. (orig.) [German] In der vorliegenden Arbeit wurden experimentelle und numerische Untersuchungen zur heterogen katalysierten und elektrochemischen Oxidation von CO an Anodensystemen (bestehend aus Nickel und yttriumdotiertem Zirkoniumdioxid, YSZ) von Festoxidbrennstoffzellen (engl. Solid Oxide Fuel Cells, SOFCs) ausgefuehrt, um den mikroskopischen Mechanismus der an der CO/CO{sub 2}-Gasphase/Ni-Elektrode/YSZ-Elektrolyt- Dreiphasen-Grenzflaeche ablaufenden Ladungsuebertragungsreaktion aufzuklaeren. Temperaturprogrammierte Desorptionsmessungen (TPD) und Temperaturprogrammierte Reaktionsmessungen (TPR) sowie Dichtefunktionaltheorierechnungen wurden ausgefuehrt, um adsorptions-, desorptions- und reaktionskinetische sowie thermodynamische Daten fuer die CO/CO{sub 2}/Ni- und CO/CO{sub 2}/YSZ

  7. Investigating the links between ozone and organic aerosol chemistry in a biomass burning plume from a prescribed fire in California chaparral

    Science.gov (United States)

    M.J. Alvarado; C.R. Lonsdale; R.J. Yokelson; S.K. Akagi; I.R. Burling; H. Coe; J.S. Craven; E. Fischer; G.R. McMeeking; J.H. Seinfeld; T. Soni; J.W. Taylor; D.R. Weise; C.E. Wold

    2015-01-01

    Within minutes after emission, complex photochemistry in biomass burning smoke plumes can cause large changes in the concentrations of ozone (O3) and organic aerosol (OA). Being able to understand and simulate this rapid chemical evolution under a wide variety of conditions is a critical part of forecasting the impact of these fires on air...

  8. Organocatalysis: Key Trends in Green Synthetic Chemistry, Challenges, Scope towards Heterogenization, and Importance from Research and Industrial Point of View

    Directory of Open Access Journals (Sweden)

    Isak Rajjak Shaikh

    2014-01-01

    Full Text Available This paper purports to review catalysis, particularly the organocatalysis and its origin, key trends, challenges, examples, scope, and importance. The definition of organocatalyst corresponds to a low molecular weight organic molecule which in stoichiometric amounts catalyzes a chemical reaction. In this review, the use of the term heterogenized organocatalyst will be exclusively confined to a catalytic system containing an organic molecule immobilized onto some sort of support material and is responsible for accelerating a chemical reaction. Firstly, a brief description of the field is provided putting it in a green and sustainable perspective of chemistry. Next, research findings on the use of organocatalysts on various inorganic supports including nano(porousmaterials, nanoparticles, silica, and zeolite/zeolitic materials are scrutinized in brief. Then future scope, research directions, and academic and industrial applications will be outlined. A succinct account will summarize some of the research and developments in the field. This review tries to bring many outstanding researches together and shows the vitality of the organocatalysis through several aspects.

  9. Heterogeneous Catalysis.

    Science.gov (United States)

    Miranda, R.

    1989-01-01

    Described is a heterogeneous catalysis course which has elements of materials processing embedded in the classical format of catalytic mechanisms and surface chemistry. A course outline and list of examples of recent review papers written by students are provided. (MVL)

  10. Development of a fluidized bed agglomeration modeling methodology to include particle-level heterogeneities in ash chemistry and granular physics

    Science.gov (United States)

    Khadilkar, Aditi B.

    The utility of fluidized bed reactors for combustion and gasification can be enhanced if operational issues such as agglomeration are mitigated. The monetary and efficiency losses could be avoided through a mechanistic understanding of the agglomeration process and prediction of operational conditions that promote agglomeration. Pilot-scale experimentation prior to operation for each specific condition can be cumbersome and expensive. So the development of a mathematical model would aid predictions. With this motivation, the study comprised of the following model development stages- 1) development of an agglomeration modeling methodology based on binary particle collisions, 2) study of heterogeneities in ash chemical composition and gaseous atmosphere, 3) computation of a distribution of particle collision frequencies based on granular physics for a poly-disperse particle size distribution, 4) combining the ash chemistry and granular physics inputs to obtain agglomerate growth probabilities and 5) validation of the modeling methodology. The modeling methodology comprised of testing every binary particle collision in the system for sticking, based on the extent of dissipation of the particles' kinetic energy through viscous dissipation by slag-liquid (molten ash) covering the particles. In the modeling methodology developed in this study, thermodynamic equilibrium calculations are used to estimate the amount of slag-liquid in the system, and the changes in particle collision frequencies are accounted for by continuously tracking the number density of the various particle sizes. In this study, the heterogeneities in chemical composition of fuel ash were studied by separating the bulk fuel into particle classes that are rich in specific minerals. FactSage simulations were performed on two bituminous coals and an anthracite to understand the effect of particle-level heterogeneities on agglomeration. The mineral matter behavior of these constituent classes was studied

  11. Observations and model calculations of trace gas scavenging in a dense Saharan dust plume during MINATROC

    Directory of Open Access Journals (Sweden)

    M. de Reus

    2005-01-01

    Full Text Available An intensive field measurement campaign was performed in July/August 2002 at the Global Atmospheric Watch station Izaña on Tenerife to study the interaction of mineral dust aerosol and tropospheric chemistry (MINATROC. A dense Saharan dust plume, with aerosol masses exceeding 500 µg m-3, persisted for three days. During this dust event strongly reduced mixing ratios of ROx (HO2, CH3O2 and higher organic peroxy radicals, H2O2, NOx (NO and NO2 and O3 were observed. A chemistry boxmodel, constrained by the measurements, has been used to study gas phase and heterogeneous chemistry. It appeared to be difficult to reproduce the observed HCHO mixing ratios with the model, possibly related to the representation of precursor gas concentrations or the absence of dry deposition. The model calculations indicate that the reduced H2O2 mixing ratios in the dust plume can be explained by including the heterogeneous removal reaction of HO2 with an uptake coefficient of 0.2, or by assuming heterogeneous removal of H2O2 with an accommodation coefficient of 5x10-4. However, these heterogeneous reactions cannot explain the low ROx mixing ratios observed during the dust event. Whereas a mean daytime net ozone production rate (NOP of 1.06 ppbv/hr occurred throughout the campaign, the reduced ROx and NOx mixing ratios in the Saharan dust plume contributed to a reduced NOP of 0.14-0.33 ppbv/hr, which likely explains the relatively low ozone mixing ratios observed during this event.

  12. Particle Size Distributions Measured in the Stratospheric Plumes of Three Rockets During the ACCENT Missions

    Science.gov (United States)

    Wiedinmyer, C.; Brock, C. A.; Reeves, J. M.; Ross, M. N.; Schmid, O.; Toohey, D.; Wilson, J. C.

    2001-12-01

    The global impact of particles emitted by rocket engines on stratospheric ozone is not well understood, mainly due to the lack of comprehensive in situ measurements of the size distributions of these emitted particles. During the Atmospheric Chemistry of Combustion Emissions Near the Tropopause (ACCENT) missions in 1999, the NASA WB-57F aircraft carried the University of Denver N-MASS and FCAS instruments into the stratospheric plumes from three rockets. Size distributions of particles with diameters from 4 to approximately 2000 nm were calculated from the instrument measurements using numerical inversion techniques. The data have been averaged over 30-second intervals. The particle size distributions observed in all of the rocket plumes included a dominant mode near 60 nm diameter, probably composed of alumina particles. A smaller mode at approximately 25 nm, possibly composed of soot particles, was seen in only the plumes of rockets that used liquid oxygen and kerosene as a propellant. Aircraft exhaust emitted by the WB-57F was also sampled; the size distributions within these plumes are consistent with prior measurements in aircraft plumes. The size distributions for all rocket intercepts have been fitted to bimodal, lognormal distributions to provide input for global models of the stratosphere. Our data suggest that previous estimates of the solid rocket motor alumina size distributions may underestimate the alumina surface area emission index, and so underestimate the particle surface area available for heterogeneous chlorine activation reactions in the global stratosphere.

  13. WRF-Chem model predictions of the regional impacts of N2O5 heterogeneous processes on night-time chemistry over north-western Europe

    Science.gov (United States)

    Lowe, D.; Archer-Nicholls, S.; Morgan, W.; Allan, J.; Utembe, S.; Ouyang, B.; Aruffo, E.; Le Breton, M.; Zaveri, R. A.; Di Carlo, P.; Percival, C.; Coe, H.; Jones, R.; McFiggans, G.

    2015-02-01

    Chemical modelling studies have been conducted over north-western Europe in summer conditions, showing that night-time dinitrogen pentoxide (N2O5) heterogeneous reactive uptake is important regionally in modulating particulate nitrate and has a~modest influence on oxidative chemistry. Results from Weather Research and Forecasting model with Chemistry (WRF-Chem) model simulations, run with a detailed volatile organic compound (VOC) gas-phase chemistry scheme and the Model for Simulating Aerosol Interactions and Chemistry (MOSAIC) sectional aerosol scheme, were compared with a series of airborne gas and particulate measurements made over the UK in July 2010. Modelled mixing ratios of key gas-phase species were reasonably accurate (correlations with measurements of 0.7-0.9 for NO2 and O3). However modelled loadings of particulate species were less accurate (correlation with measurements for particulate sulfate and ammonium were between 0.0 and 0.6). Sulfate mass loadings were particularly low (modelled means of 0.5-0.7 μg kg-1air, compared with measurements of 1.0-1.5 μg kg-1air). Two flights from the campaign were used as test cases - one with low relative humidity (RH) (60-70%), the other with high RH (80-90%). N2O5 heterogeneous chemistry was found to not be important in the low-RH test case; but in the high-RH test case it had a strong effect and significantly improved the agreement between modelled and measured NO3 and N2O5. When the model failed to capture atmospheric RH correctly, the modelled NO3 and N2O5 mixing ratios for these flights differed significantly from the measurements. This demonstrates that, for regional modelling which involves heterogeneous processes, it is essential to capture the ambient temperature and water vapour profiles. The night-time NO3 oxidation of VOCs across the whole region was found to be 100-300 times slower than the daytime OH oxidation of these compounds. The difference in contribution was less for alkenes (× 80) and

  14. WRF-Chem model predictions of the regional impacts of N2O5 heterogeneous processes on night-time chemistry over north-western Europe

    Directory of Open Access Journals (Sweden)

    D. Lowe

    2015-02-01

    Full Text Available Chemical modelling studies have been conducted over north-western Europe in summer conditions, showing that night-time dinitrogen pentoxide (N2O5 heterogeneous reactive uptake is important regionally in modulating particulate nitrate and has a~modest influence on oxidative chemistry. Results from Weather Research and Forecasting model with Chemistry (WRF-Chem model simulations, run with a detailed volatile organic compound (VOC gas-phase chemistry scheme and the Model for Simulating Aerosol Interactions and Chemistry (MOSAIC sectional aerosol scheme, were compared with a series of airborne gas and particulate measurements made over the UK in July 2010. Modelled mixing ratios of key gas-phase species were reasonably accurate (correlations with measurements of 0.7–0.9 for NO2 and O3. However modelled loadings of particulate species were less accurate (correlation with measurements for particulate sulfate and ammonium were between 0.0 and 0.6. Sulfate mass loadings were particularly low (modelled means of 0.5–0.7 μg kg−1air, compared with measurements of 1.0–1.5 μg kg−1air. Two flights from the campaign were used as test cases – one with low relative humidity (RH (60–70%, the other with high RH (80–90%. N2O5 heterogeneous chemistry was found to not be important in the low-RH test case; but in the high-RH test case it had a strong effect and significantly improved the agreement between modelled and measured NO3 and N2O5. When the model failed to capture atmospheric RH correctly, the modelled NO3 and N2O5 mixing ratios for these flights differed significantly from the measurements. This demonstrates that, for regional modelling which involves heterogeneous processes, it is essential to capture the ambient temperature and water vapour profiles. The night-time NO3 oxidation of VOCs across the whole region was found to be 100–300 times slower than the daytime OH oxidation of these compounds. The difference in contribution was less

  15. ASSESSMENT OF PLUME DIVING

    Science.gov (United States)

    This presentation presents an assessment of plume diving. Observations included: vertical plume delineation at East Patchogue, NY showed BTEX and MTBE plumes sinking on either side of a gravel pit; Lake Druid TCE plume sank beneath unlined drainage ditch; and aquifer recharge/dis...

  16. A Transition from a Traditional to a Project-Like Physical Chemistry Laboratory via a Heterogeneous Catalysis Study.

    Science.gov (United States)

    Goldwasser, M. R.; Leal, O.

    1979-01-01

    Outlines an approach for instruction in a physical chemistry laboratory which combines traditional and project-like experiments. An outline of laboratory experiments and examples of project-like experiments are included. (BT)

  17. Measuring Heterogeneous Reaction Rates with ATR-FTIR Spectroscopy to Evaluate Chemical Fates in an Atmospheric Environment: A Physical Chemistry and Environmental Chemistry Laboratory Experiment

    Science.gov (United States)

    Roberts, Jason E.; Zeng, Guang; Maron, Marta K.; Mach, Mindy; Dwebi, Iman; Liu, Yong

    2016-01-01

    This paper reports an undergraduate laboratory experiment to measure heterogeneous liquid/gas reaction kinetics (ozone-oleic acid and ozone-phenothrin) using a flow reactor coupled to an attenuated total reflectance-Fourier transform infrared (ATR-FTIR) spectrometer. The experiment is specially designed for an upper-level undergraduate Physical…

  18. Dynamics and Deposits of Coignimbrite Plumes

    Science.gov (United States)

    Engwell, Samantha; de'Michieli Vitturi, Mattia; Esposti Ongaro, Tomaso; Neri, Augusto

    2014-05-01

    Fine ash in the atmosphere poses a significant hazard, with potentially disastrous consequences for aviation and, on deposition, health and infrastructure. Fine-grained particles form a large proportion of ejecta in Plinian volcanic clouds. However, another common, but poorly studied phenomena exists whereby large amounts of fine ash are injected into the atmosphere. Coignimbrite plumes form as material is elutriated from the top of pyroclastic density currents. The ash in these plumes is considerably finer grained than that in Plinian plumes and can be distributed over thousands of kilometres in the atmosphere. Despite their significance, very little is known regarding coignimbrite plume formation and dispersion, predominantly due to the poor preservation of resultant deposits. As a result, consequences of coignimbrite plume formation are usually overlooked when conducting hazard and risk analysis. In this study, deposit characteristics and numerical models of plumes are combined to investigate the conditions required for coignimbrite plume formation. Coignimbrite deposits from the Campanian Ignimbrite eruption (Magnitude 7.7, 39 ka) are well sorted and very fine, with a mode of between 30 and 50 microns, and a significant component of respirable ash (less than 10 microns). Analogous distributions are found for coignimbrite deposits from Tungurahua 2006 and Volcan de Colima (2004-2006), amongst others, regardless of magnitude, type or chemistry of eruption. These results indicate that elutriation processes are the dominant control on coignimbrite grainsize distribution. To further investigate elutriation and coignimbrite plume dynamics, the numerical plume model of Bursik (2001) is applied. Model sensitivity analysis demonstrates that neutral buoyancy conditions (required for the formation of the plume) are controlled by a balance between temperature and gas mass flux in the upper most parts of the pyroclastic density current. In addition, results emphasize the

  19. Organocatalysis: Key Trends in Green Synthetic Chemistry, Challenges, Scope towards Heterogenization, and Importance from Research and Industrial Point of View

    OpenAIRE

    Isak Rajjak Shaikh

    2014-01-01

    This paper purports to review catalysis, particularly the organocatalysis and its origin, key trends, challenges, examples, scope, and importance. The definition of organocatalyst corresponds to a low molecular weight organic molecule which in stoichiometric amounts catalyzes a chemical reaction. In this review, the use of the term heterogenized organocatalyst will be exclusively confined to a catalytic system containing an organic molecule immobilized onto some sort of support material and i...

  20. A kinetics study of the homogeneous and heterogeneous components of the HCl + ClONO2 reaction. [and its relevance to stratospheric chemistry

    Science.gov (United States)

    Friedl, Randall R.; Goble, James H.; Sander, Stanley P.

    1986-01-01

    The kinetics of the reaction HCl + ClONO2 to Cl2 + HNO3 were investigated at 298 K using a flow reactor with FTIR analysis to assess the importance of this reaction for stratospheric chemistry. The observed reaction was characteristic of a heterogeneous process; an upper limit of 5 x 10 to the -18th cu cm/molecule per s was obtained for the homogeneous gas phase rate constant. From calculations of the first order wall rate constant, estimates were made of the reaction rate on stratospheric aerosols. Because both HCl and ClONO2 need to be adsorbed on the particle surface, the reaction will be of negligible importance under most stratospheric conditions.

  1. Model development of dust emission and heterogeneous chemistry within the Community Multiscale Air Quality modeling system and its application over East Asia

    Science.gov (United States)

    Dong, Xinyi; Fu, Joshua S.; Huang, Kan; Tong, Daniel; Zhuang, Guoshun

    2016-07-01

    The Community Multiscale Air Quality (CMAQ) model has been further developed in terms of simulating natural wind-blown dust in this study, with a series of modifications aimed at improving the model's capability to predict the emission, transport, and chemical reactions of dust. The default parameterization of initial threshold friction velocity constants are revised to correct the double counting of the impact of soil moisture in CMAQ by the reanalysis of field experiment data; source-dependent speciation profiles for dust emission are derived based on local measurements for the Gobi and Taklamakan deserts in East Asia; and dust heterogeneous chemistry is also implemented. The improved dust module in the CMAQ is applied over East Asia for March and April from 2006 to 2010. The model evaluation result shows that the simulation bias of PM10 and aerosol optical depth (AOD) is reduced, respectively, from -55.42 and -31.97 % by the original CMAQ to -16.05 and -22.1 % by the revised CMAQ. Comparison with observations at the nearby Gobi stations of Duolun and Yulin indicates that applying a source-dependent profile helps reduce simulation bias for trace metals. Implementing heterogeneous chemistry also results in better agreement with observations for sulfur dioxide (SO2), sulfate (SO42-), nitric acid (HNO3), nitrous oxides (NOx), and nitrate (NO3-). The investigation of a severe dust storm episode from 19 to 21 March 2010 suggests that the revised CMAQ is capable of capturing the spatial distribution and temporal variation of dust. The model evaluation also indicates potential uncertainty within the excessive soil moisture used by meteorological simulation. The mass contribution of fine-mode particles in dust emission may be underestimated by 50 %. The revised CMAQ model provides a useful tool for future studies to investigate the emission, transport, and impact of wind-blown dust over East Asia and elsewhere.

  2. Does Everyone's Motivational Beliefs about Physical Science Decline in Secondary School?: Heterogeneity of Adolescents' Achievement Motivation Trajectories in Physics and Chemistry.

    Science.gov (United States)

    Wang, Ming-Te; Chow, Angela; Degol, Jessica Lauren; Eccles, Jacquelynne Sue

    2017-08-01

    Students' motivational beliefs about learning physical science are critical for achieving positive educational outcomes. In this study, we incorporated expectancy-value theory to capture the heterogeneity of adolescents' motivational trajectories in physics and chemistry from seventh to twelfth grade and linked these trajectories to science-related outcomes. We used a cross-sequential design based on three different cohorts of adolescents (N = 699; 51.5 % female; 95 % European American; M ages for youngest, middle, and oldest cohorts at the first wave = 13.2, 14.1, and 15.3 years) coming from ten public secondary schools. Although many studies claim that physical science motivation declines on average over time, we identified seven differential motivational trajectories of ability self-concept and task values, and found associations of these trajectories with science achievement, advanced science course taking, and science career aspirations. Adolescents' ability self-concept and task values in physics and chemistry were also positively related and interlinked over time. Examining how students' motivational beliefs about physical science develop in secondary school offers insight into the capacity of different groups of students to successfully adapt to their changing educational environments.

  3. Untangling the Chemical Evolution of Titan's Atmosphere and Surface -- From Homogeneous to Heterogeneous Chemistry

    Energy Technology Data Exchange (ETDEWEB)

    Kaiser, Ralf I.; Maksyutenko, Pavlo; Ennis, Courtney; Zhang, Fangtong; Gu, Xibin; Krishtal, Sergey P.; Mebel, Alexander M.; Kostko, Oleg; Ahmed, Musahid

    2010-03-16

    The arrival of the Cassini-Huygens probe at Saturn's moon Titan - the only Solar System body besides Earth and Venus with a solid surface and a thick atmosphere with a pressure of 1.4 atm at surface level - in 2004 opened up a new chapter in the history of Solar System exploration. The mission revealed Titan as a world with striking Earth-like landscapes involving hydrocarbon lakes and seas as well as sand dunes and lava-like features interspersed with craters and icy mountains of hitherto unknown chemical composition. The discovery of a dynamic atmosphere and active weather system illustrates further the similarities between Titan and Earth. The aerosol-based haze layers, which give Titan its orange-brownish color, are not only Titan's most prominent optically visible features, but also play a crucial role in determining Titan's thermal structure and chemistry. These smog-like haze layers are thought to be very similar to those that were present in Earth's atmosphere before life developed more than 3.8 billion years ago, absorbing the destructive ultraviolet radiation from the Sun, thus acting as 'prebiotic ozone' to preserve astrobiologically important molecules on Titan. Compared to Earth, Titan's low surface temperature of 94 K and the absence of liquid water preclude the evolution of biological chemistry as we know it. Exactly because of these low temperatures, Titan provides us with a unique prebiotic 'atmospheric laboratory' yielding vital clues - at the frozen stage - on the likely chemical composition of the atmosphere of the primitive Earth. However, the underlying chemical processes, which initiate the haze formation from simple molecules, have been not understood well to date.

  4. Aerosol Fragmentation Driven by Coupling of Acid-Base and Free-Radical Chemistry in the Heterogeneous Oxidation of Aqueous Citric Acid by OH Radicals.

    Science.gov (United States)

    Liu, Matthew J; Wiegel, Aaron A; Wilson, Kevin R; Houle, Frances A

    2017-08-10

    A key uncertainty in the heterogeneous oxidation of carboxylic acids by hydroxyl radicals (OH) in aqueous-phase aerosol is how the free-radical reaction pathways might be altered by acid-base chemistry. In particular, if acid-base reactions occur concurrently with acyloxy radical formation and unimolecular decomposition of alkoxy radicals, there is a possibility that differences in reaction pathways impact the partitioning of organic carbon between the gas and aqueous phases. To examine these questions, a kinetic model is developed for the OH-initiated oxidation of citric acid aerosol at high relative humidity. The reaction scheme, containing both free-radical and acid-base elementary reaction steps with physically validated rate coefficients, accurately predicts the experimentally observed molecular composition, particle size, and average elemental composition of the aerosol upon oxidation. The difference between the two reaction channels centers on the reactivity of carboxylic acid groups. Free-radical reactions mainly add functional groups to the carbon skeleton of neutral citric acid, because carboxylic acid moieties deactivate the unimolecular fragmentation of alkoxy radicals. In contrast, the conjugate carboxylate groups originating from acid-base equilibria activate both acyloxy radical formation and carbon-carbon bond scission of alkoxy radicals, leading to the formation of low molecular weight, highly oxidized products such as oxalic and mesoxalic acid. Subsequent hydration of carbonyl groups in the oxidized products increases the aerosol hygroscopicity and accelerates the substantial water uptake and volume growth that accompany oxidation. These results frame the oxidative lifecycle of atmospheric aerosol: it is governed by feedbacks between reactions that first increase the particle oxidation state, then eventually promote water uptake and acid-base chemistry. When coupled to free-radical reactions, acid-base channels lead to formation of low molecular

  5. The oleic acid-ozone heterogeneous reaction system: products, kinetics, secondary chemistry, and atmospheric implications of a model system – a review

    Directory of Open Access Journals (Sweden)

    J. Zahardis

    2007-01-01

    Full Text Available The heterogeneous processing of organic aerosols by trace oxidants has many implications to atmospheric chemistry and climate regulation. This review covers a model heterogeneous reaction system (HRS: the oleic acid-ozone HRS and other reaction systems featuring fatty acids, and their derivatives. The analysis of the commonly observed aldehyde and organic acid products of ozonolysis (azelaic acid, nonanoic acid, 9-oxononanoic acid, nonanal is described. The relative product yields are noted and explained by the observation of secondary chemical reactions. The secondary reaction products arising from reactive Criegee intermediates are mainly peroxidic, notably secondary ozonides and α-acyloxyalkyl hydroperoxide oligomers and polymers, and their formation is in accord with solution and liquid-phase ozonolysis. These highly oxygenated products are of low volatility and hydrophilic which may enhance the ability of particles to act as cloud condensation nuclei (CCN. The kinetic description of this HRS is critically reviewed. Most kinetic studies suggest this oxidative processing is either a near surface reaction that is limited by the diffusion of ozone or a surface based reaction. Internally mixed particles and coatings represent the next stage in the progression towards more realistic proxies of tropospheric organic aerosols and a description of the products and the kinetics resulting from the ozonolysis of these proxies, which are based on fatty acids or their derivatives, is presented. Finally, the main atmospheric implications of oxidative processing of particulate containing fatty acids are presented. These implications include the extended lifetime of unsaturated species in the troposphere facilitated by the presence of solids, semi-solids or viscous phases, and an enhanced rate of ozone uptake by particulate unsaturates compared to corresponding gas-phase organics. Ozonolysis of oleic acid enhances its CCN activity, which implies that

  6. Modeling the Effects of Aircraft Emissions on Atmospheric Photochemistry Using Layered Plume Dynamics

    Science.gov (United States)

    Cameron, M. A.; Jacobson, M. Z.; Naiman, A. D.; Lele, S. K.

    2012-12-01

    Aviation is an expanding industry, experiencing continued growth and playing an increasingly noticed role in upper tropospheric/lower stratospheric composition. Nitrogen oxides and other gas-phase emissions from aircraft react to affect ozone photochemistry. This research investigates the effects of treating aircraft gas-phase chemistry within an expanding layered plume versus at the grid scale. SMVGEAR II, a sparse-matrix, vectorized Gear-type solver for ordinary differential equations, is used to solve chemical equations at both the grid scale and subgrid scale. A Subgrid Plume Model (SPM) is used to advance the expanding plume, accounting for wind shear and diffusion. Simulations suggest that using a layered plume approach results in noticeably different final NOx concentrations, demonstrating the importance of these plume dynamics in predicting the effects of aircraft on ozone concentrations. Results showing the effects of a layered plume, single plume, and no plume on ozone after several hours will be presented.

  7. Polar Stratospheric Clouds and heterogeneous chemistry: Comparison between a 3D-CTM with detailed online PSC microphysics and CALIPSO observations

    Science.gov (United States)

    Viscardy, Sébastien; Errera, Quentin; Pitts, Michael C.; Poole, Lamont R.; Chabrillat, Simon; Daerden, Frank

    2013-04-01

    A 3-D Chemical Transport Model (CTM), with full stratospheric chemistry and driven by the ECMWF temperature and wind fields, has been coupled to a detailed PSC microphysical model to simulate polar winters. The formation and evolution of four types of PSC particles (STS, SAT, NAT, and ice) are described through relevant microphysical processes which alter interactively the nitric acid and water vapor concentrations of the atmosphere. Each particle type is described by a binned size distribution for the number density and chemical composition. This set-up allows for detailed calculation of optical properties and surface area densities used to compute the heterogeneous reaction rates. After comparing the evolution of the stratospheric chemical structure to satellite observations, we will investigate how the model reproduces the PSC coverage detected by CALIPSO. A comparison between the model and CALIPSO optical properties will be used to discuss the PSC composition. Finally, we aim at estimating the contribution of each PSC particle type to the chlorine activation.

  8. Química organometálica de superfície aplicada à preparação de catalisadores heterogêneos bem definidos Surface organometallic chemistry applied to the preparation of well defined heterogeneous catalysts

    Directory of Open Access Journals (Sweden)

    Silvana I. Wolke

    2002-11-01

    Full Text Available The study of the reactions of organometallic complexes with the surfaces of inorganic oxides, zeolites and metals constitutes the basis of Surface Organometallic Chemistry (SOMC. The basic rules of organometallic chemistry are often valid when applied to surfaces and well-defined surface organometallic complexes can be obtained. These complexes can be used as heterogeneous catalysts or, by controlled reactions, can be transformed in other species useful for a given catalytic reaction. In some cases, these catalysts exhibit higher activity and/or selectivity than their analogous molecular complexes.

  9. Solar Coronal Plumes

    Directory of Open Access Journals (Sweden)

    Giannina Poletto

    2015-12-01

    Full Text Available Polar plumes are thin long ray-like structures that project beyond the limb of the Sun polar regions, maintaining their identity over distances of several solar radii. Plumes have been first observed in white-light (WL images of the Sun, but, with the advent of the space era, they have been identified also in X-ray and UV wavelengths (XUV and, possibly, even in in situ data. This review traces the history of plumes, from the time they have been first imaged, to the complex means by which nowadays we attempt to reconstruct their 3-D structure. Spectroscopic techniques allowed us also to infer the physical parameters of plumes and estimate their electron and kinetic temperatures and their densities. However, perhaps the most interesting problem we need to solve is the role they cover in the solar wind origin and acceleration: Does the solar wind emanate from plumes or from the ambient coronal hole wherein they are embedded? Do plumes have a role in solar wind acceleration and mass loading? Answers to these questions are still somewhat ambiguous and theoretical modeling does not provide definite answers either. Recent data, with an unprecedented high spatial and temporal resolution, provide new information on the fine structure of plumes, their temporal evolution and relationship with other transient phenomena that may shed further light on these elusive features.

  10. Mineral Formation and Trace Element Uptake in Rising Hydrothermal Plumes of the Lau Basin

    Science.gov (United States)

    Breier, J. A.; Osicki, O.; Jiang, H.; Anantharaman, K.; Dick, G.; Wendt, K.; Sorensen, J. V.; Toner, B.

    2011-12-01

    Hydrothermal plumes are enriched in a variety of trace elements (e.g., V, As, and the rare earths) and micronutrients (e.g., Fe, Mn, Cu, Zn, and P) that are (i) extracted from the lithosphere and (ii) scavenged from seawater. Mineral particles are the transport vector for these trace elements. The relative importance of these sources and their net effect on sedimentary and marine element cycles depends on the mechanisms of trace element sequestration within plume mineral particles, the stability of the mineral phases that sequester them, and potentially the modification of plume chemistry by microbial processes. Lau Basin vents span a range of endmember chemistries and temperatures and are thus a useful setting for investigating the relationship between plume trace element composition and mineralogy. Our investigation of the rising plume chemistry of Lau Basin vents addresses these questions by comparing particulate trace element covariations through the rising plume with measured and modeled mineral formation for samples collected from three distinct hydrothermal fields: Kilo Moana, ABE, and Mariner. These rising plume samples span the initial particle formation process through sulfide formation to initial oxide formation, in addition to spanning a range of endmember vent chemistries. The trends between trace elements and Fe are nonlinear, for several elements (e.g., P, V) this contrasts with previous findings of linear trends in the neutrally buoyant plume. These trends are explained in the context of the transition from rising plume mineral mixtures dominated by sulfides to those with an increasing oxide component, upon which geochemical differences related to inter-field variations in endmember vent chemistry are superimposed. These results indicate that the sources and mechanisms of trace element enrichment vary significantly over the plume mixing path and suggest the apparent mechanisms that control plume trace element composition in neutrally buoyant plumes

  11. Wireless Sensor Network Based Subsurface Contaminant Plume Monitoring

    Science.gov (United States)

    2012-04-16

    conventional WSN . VSN enabled closed loop system consumes more energy than the VSN only system, because of the commands that are send to the nodes. Energy ...predict future plume behavior. This proof-of-concept research aimed at demonstrating the use of an intelligent Wireless Sensor Network ( WSN ) to...Network ( WSN ) to monitor contaminant plume movement in naturally heterogeneous subsurface formations to advance the sensor networking based monitoring

  12. Do Plumes Suck?

    Science.gov (United States)

    Braun, M. G.; Sohn, R. A.; Ribe, N. M.

    2001-12-01

    Geophysical observations at plumes, ridges, and arcs indicate that the the volcanic accretionary zone is much narrower than the inferred melt production region in the upwelling mantle. For ridges and arcs, lateral pressure gradients induced by advection of viscous asthenospheric mantle have been proposed as a potential mechanism for focusing melts to the accretionary center [Phipps Morgan, 1987; Spiegelman and McKenzie, 1987]. For ridges and arcs with asthenospheric viscosities >=1021 Paṡs, the magnitude of the lateral pressure gradients associated with viscous corner flow are comparable to vertical melt buoyancy (Δ ρ g). Plumes, however, differ from ridges and arcs in that mantle flow is driven primarily by buoyancy of the upwelling solid as opposed to viscous drag induced by surface plate motions. This difference in driving forces changes the relationship between the solid flow field and the resulting pressure gradients. We use numerical models to examine the influence of lateral pressure gradients from solid advection in plumes. We calculate the stream function and pressure field in the solid induced by a buoyant cylinder beneath a stationary lithosphere using the method of Ribe and Christensen [1999] after Pozrikidis [1997]. Initial results suggest that lateral pressure gradients may draw melt into the top of the plume towards the flow stagnation point. However, the largest flow-induced pressure gradients are oriented vertically within the buoyant plume. Compression where the plume impinges on the lithospheric lid has the potential to impede the vertical migration of melt within the plume. The magnitude of the flow-induced pressure gradients scales with the strength of the buoyant upwelling. However, unlike ridges and arcs, asthenospheric viscosity has little effect on the pressure gradients, because velocity and viscosity of plume material are interdependent. We explore the possible role of these pressure gradients in melt migration at plume and ridge-plume

  13. Plume-induced subduction

    Science.gov (United States)

    Gerya, T.; Stern, R. J.; Baes, M.; Sobolev, S. V.; Whattam, S. A.

    2016-12-01

    Dominant present-day subduction initiation mechanisms require acting plate forces and/or pre-existing zones of lithospheric weakness, which are themselves consequences of plate tectonics. In contrast, recently discovered plume-induced subduction initiation could have started the first subduction zone without pre-existing plate tectonics. Here, we investigate this new mechanism with high-resolution 3D numerical thermomechanical modeling experiments. We show that typical plume-induced subduction dynamics is subdivided into five different stages: (1) oceanic plateau formation by arrival of a mantle plume head; (2) formation of an incipient trench and a descending nearly-circular slab at the plateau margins; (3) tearing of the circular slab; (4) formation of several self-sustained retreating subduction zones and (5) cooling and spreading of the new lithosphere formed between the retreating subduction zones. At the final stage of plume-induced subduction initiation, a mosaic of independently moving, growing and cooling small oceanic plates heading toward individual retreating subduction zones forms. The plates are separated by spreading centers, triple junctions and transform faults and thus the newly formed multi-slab subduction system operates as an embryonic plate tectonic cell. We demonstrate that three key physical factors combine to trigger self-sustained plume-induced subduction: (1) old negatively buoyant oceanic lithosphere; (2) intense weakening of the lithosphere by plume-derived magmas; and (3) lubrication of the forming subduction interface by hydrated oceanic crust. We furthermore discuss that plume-induced subduction, which is rare at present day conditions, may have been common in the Precambrian time and likely started global plate tectonics on Earth.

  14. The effects of physical and geochemical heterogeneities on hydro-geochemical transport and effective reaction rates

    Science.gov (United States)

    Atchley, Adam L.; Navarre-Sitchler, Alexis K.; Maxwell, Reed M.

    2014-09-01

    The role of coupled physical and geochemical heterogeneities in hydro-geochemical transport is investigated by simulating three-dimensional transport in a heterogeneous system with kinetic mineral reactions. Ensembles of 100 physically heterogeneous realizations were simulated for three geochemical conditions: 1) spatially homogeneous reactive mineral surface area, 2) reactive surface area positively correlated to hydraulic heterogeneity, and 3) reactive surface area negatively correlated to hydraulic heterogeneity. Groundwater chemistry and the corresponding effective reaction rates were calculated at three transverse planes to quantify differences in plume evolution due to heterogeneity in mineral reaction rates and solute residence time (τ). The model is based on a hypothetical CO2 intrusion into groundwater from a carbon capture utilization and storage (CCUS) operation where CO2 dissolution and formation of carbonic acid created geochemical dis-equilibrium between fluids and the mineral galena that resulted in increased aqueous lead (Pb2 +) concentrations. Calcite dissolution buffered the pH change and created conditions of galena oversaturation, which then reduced lead concentrations along the flow path. Near the leak kinetic geochemical reactions control the release of solutes into the fluid, but further along the flow path mineral solubility controls solute concentrations. Simulation results demonstrate the impact of heterogeneous distribution of geochemical reactive surface area in coordination with physical heterogeneity on the effective reaction rate (Krxn,eff) and Pb2 + concentrations within the plume. Dissimilarities between ensemble Pb2 + concentration and Krxn,eff are attributed to how geochemical heterogeneity affects the time (τeq) and therefore advection distance (Leq) required for the system to re-establish geochemical equilibrium. Only after geochemical equilibrium is re-established, Krxn,eff and Pb2 + concentrations are the same for all three

  15. The effects of physical and geochemical heterogeneities on hydro-geochemical transport and effective reaction rates.

    Science.gov (United States)

    Atchley, Adam L; Navarre-Sitchler, Alexis K; Maxwell, Reed M

    2014-09-01

    The role of coupled physical and geochemical heterogeneities in hydro-geochemical transport is investigated by simulating three-dimensional transport in a heterogeneous system with kinetic mineral reactions. Ensembles of 100 physically heterogeneous realizations were simulated for three geochemical conditions: 1) spatially homogeneous reactive mineral surface area, 2) reactive surface area positively correlated to hydraulic heterogeneity, and 3) reactive surface area negatively correlated to hydraulic heterogeneity. Groundwater chemistry and the corresponding effective reaction rates were calculated at three transverse planes to quantify differences in plume evolution due to heterogeneity in mineral reaction rates and solute residence time (τ). The model is based on a hypothetical CO2 intrusion into groundwater from a carbon capture utilization and storage (CCUS) operation where CO2 dissolution and formation of carbonic acid created geochemical dis-equilibrium between fluids and the mineral galena that resulted in increased aqueous lead (Pb(2+)) concentrations. Calcite dissolution buffered the pH change and created conditions of galena oversaturation, which then reduced lead concentrations along the flow path. Near the leak kinetic geochemical reactions control the release of solutes into the fluid, but further along the flow path mineral solubility controls solute concentrations. Simulation results demonstrate the impact of heterogeneous distribution of geochemical reactive surface area in coordination with physical heterogeneity on the effective reaction rate (Krxn,eff) and Pb(2+) concentrations within the plume. Dissimilarities between ensemble Pb(2+) concentration and Krxn,eff are attributed to how geochemical heterogeneity affects the time (τeq) and therefore advection distance (Leq) required for the system to re-establish geochemical equilibrium. Only after geochemical equilibrium is re-established, Krxn,eff and Pb(2+) concentrations are the same for all

  16. Experiments on Plume Spreading by Engineered Injection and Extraction

    Science.gov (United States)

    Mays, D. C.; Jones, M.; Tigera, R. G.; Neupauer, R.

    2014-12-01

    The notion that groundwater remediation is transport-limited emphasizes the coupling between physical (i.e., hydrodynamic), geochemical, and microbiological processes in the subsurface. Here we leverage this coupling to promote groundwater remediation using the approach of engineered injection and extraction. In this approach, inspired by the literature on chaotic advection, uncontaminated groundwater is injected and extracted through a manifold of wells surrounding the contaminated plume. The potential of this approach lies in its ability to actively manipulate the velocity field near the contaminated plume, generating plume spreading above and beyond that resulting from aquifer heterogeneity. Plume spreading, in turn, promotes mixing and reaction by chemical and biological processes. Simulations have predicted that engineered injection and extraction generates (1) chaotic advection whose characteristics depend on aquifer heterogeneity, and (2) faster rates and increased extent of groundwater remediation. This presentation focuses on a complimentary effort to experimentally demonstrate these predictions experimentally. In preparation for future work using refractive index matched (RIM) porous media, the experiments reported here use a Hele-Shaw apparatus containing silicone oil. Engineered injection and extraction is used to manipulate the geometry of an initially circular plume of black pigment, and photographs record the plume geometry after each step of injection of extraction. Image analysis, using complimentary Eulerian and Lagrangian approaches, reveals the thickness and variability of the dispersion zone surrounding the deformed plume of black pigment. The size, shape, and evolution of this dispersion zone provides insight into the interplay between engineered injection and extraction, which generates plume structure, and dispersion (here Taylor dispersion), which destroys plume structure. These experiments lay the groundwork for application of engineered

  17. Dilution in Transition Zone between Rising Plumes and Surface Plumes

    DEFF Research Database (Denmark)

    Larsen, Torben

    2004-01-01

    The papers presents some physical experiments with the dilution of sea outfall plumes with emphasize on the transition zone where the relative fast flowing vertical plume turns to a horizontal surface plume following the slow sea surface currents. The experiments show that a considerable dilution...

  18. Sub-Grid Scale Plume Modeling

    Directory of Open Access Journals (Sweden)

    Greg Yarwood

    2011-08-01

    Full Text Available Multi-pollutant chemical transport models (CTMs are being routinely used to predict the impacts of emission controls on the concentrations and deposition of primary and secondary pollutants. While these models have a fairly comprehensive treatment of the governing atmospheric processes, they are unable to correctly represent processes that occur at very fine scales, such as the near-source transport and chemistry of emissions from elevated point sources, because of their relatively coarse horizontal resolution. Several different approaches have been used to address this limitation, such as using fine grids, adaptive grids, hybrid modeling, or an embedded sub-grid scale plume model, i.e., plume-in-grid (PinG modeling. In this paper, we first discuss the relative merits of these various approaches used to resolve sub-grid scale effects in grid models, and then focus on PinG modeling which has been very effective in addressing the problems listed above. We start with a history and review of PinG modeling from its initial applications for ozone modeling in the Urban Airshed Model (UAM in the early 1980s using a relatively simple plume model, to more sophisticated and state-of-the-science plume models, that include a full treatment of gas-phase, aerosol, and cloud chemistry, embedded in contemporary models such as CMAQ, CAMx, and WRF-Chem. We present examples of some typical results from PinG modeling for a variety of applications, discuss the implications of PinG on model predictions of source attribution, and discuss possible future developments and applications for PinG modeling.

  19. Turbulent buoyant jets and plumes

    CERN Document Server

    Rodi, Wolfgang

    The Science & Applications of Heat and Mass Transfer: Reports, Reviews, & Computer Programs, Volume 6: Turbulent Buoyant Jets and Plumes focuses on the formation, properties, characteristics, and reactions of turbulent jets and plumes. The selection first offers information on the mechanics of turbulent buoyant jets and plumes and turbulent buoyant jets in shallow fluid layers. Discussions focus on submerged buoyant jets into shallow fluid, horizontal surface or interface jets into shallow layers, fundamental considerations, and turbulent buoyant jets (forced plumes). The manuscript then exami

  20. On predicting mantle mushroom plumes

    Directory of Open Access Journals (Sweden)

    Ka-Kheng Tan

    2011-04-01

    Top cooling may produce plunging plumes of diameter of 585 km and at least 195 Myr old. The number of cold plumes is estimated to be 569, which has not been observed by seismic tomography or as cold spots. The cold plunging plumes may overwhelm and entrap some of the hot rising plumes from CMB, so that together they may settle in the transition zone.

  1. Evaluation of Visible Plumes.

    Science.gov (United States)

    Brennan, Thomas

    Developed for presentation at the 12th Conference on Methods in Air Pollution and Industrial Hygiene Studies, University of Southern California, April, 1971, this outline discusses plumes with contaminants that are visible to the naked eye. Information covers: (1) history of air pollution control regulations, (2) need for methods of evaluating…

  2. Thermal plumes in ventilated rooms

    DEFF Research Database (Denmark)

    Kofoed, Peter; Nielsen, Peter V.

    1990-01-01

    The design of a displacement ventilation system involves determination of the flow rate in the thermal plumes. The flow rate in the plumes and the vertical temperature gradient influence each other, and they are influenced by many factors. This paper shows some descriptions of these effects. Free...... to be the only possible approach to obtain the volume flow in: thermal plumes in ventilated rooms....

  3. A computer model for one-dimensional mass and energy transport in and around chemically reacting particles, including complex gas-phase chemistry, multicomponent molecular diffusion, surface evaporation, and heterogeneous reaction

    Science.gov (United States)

    Cho, S. Y.; Yetter, R. A.; Dryer, F. L.

    1992-01-01

    Various chemically reacting flow problems highlighting chemical and physical fundamentals rather than flow geometry are presently investigated by means of a comprehensive mathematical model that incorporates multicomponent molecular diffusion, complex chemistry, and heterogeneous processes, in the interest of obtaining sensitivity-related information. The sensitivity equations were decoupled from those of the model, and then integrated one time-step behind the integration of the model equations, and analytical Jacobian matrices were applied to improve the accuracy of sensitivity coefficients that are calculated together with model solutions.

  4. The effect of recycled oceanic crust in the thermal evolution of the Galapagos Plume

    Science.gov (United States)

    Gazel, E.; Herzberg, C. T.; Vidito, C. A.

    2011-12-01

    Current models suggest that the massive basaltic production responsible for the emplacement of Large Igneous Provinces (LIPS) during the Permian-Paleocene may represent the initial phases (plume heads) of some of the mantle plumes that feed the current ocean island basalts (OIB). In many cases, magmatism associated with the initiation of mantle plumes was so voluminous that produced global environmental impacts. The origin of these intra-plate magmatism is still debated but recent petrological, geochemical and geophysical studies of some of these localities like Samoa, Hawaii, Galapagos, provide evidence that melting is related to a true mantle plume, representing a geochemically heterogeneous, hot-buoyant domain that originates from a boundary layer beneath the upper mantle. Thus, plume-related magmas produced in OIB and LIPS and their connecting plume tracks are windows into the Earth's mantle, providing evidence on mantle temperature, size and composition of heterogeneities, and the deep earth geochemical cycles. Our preliminary petrological modeling suggests that mantle plumes for LIPS with Permian-Paleocene ages were generally hotter and melted more extensively than plumes of more modern oceanic islands. Although a lot of work has been done on LIPS and OIB, no complete record of the evolution of a mantle plume is available to this point, mostly due to the inaccessibility of the submerged sections of almost all plume tracks. Galapagos-related lavas provide a complete record of the evolution of a mantle plume since the plume's initial stages in the Cretaceous. In the case of the Galapagos, our work suggests a decrease from TP(max) of1650 C in the Cretaceous to 1500 C in the present day. Our recent work on the Galapagos Islands and the preliminary work on older Galapagos-related terranes suggest that this secular cooling is directly related with increasing amounts of recycled crust in the plume.

  5. The Thermal Evolution of the Galapagos Mantle Plume: Insights from Al-in-Olivine Thermometry

    Science.gov (United States)

    Trela, J.; Gazel, E.; Sobolev, A. V.; Class, C.; Bizimis, M.; Jicha, B. R.; Batanova, V. G.; Denyer, P.

    2016-12-01

    The mantle plume hypothesis is widely accepted for the formation of large igneous provinces (LIP) and many ocean island basalts (OIB). Petrologic models support a mantle plume origin by indicating high mantle temperatures (>1500 °C) for some plume-melts relative to melts generated at ambient mid ocean ridge conditions (1350 °C). Mantle plumes forming LIPs and OIBs provide our primary source of information on the geochemical and lithological heterogeneity of the lower mantle. The Galapagos hotspot represents one of the most thermally and geochemically heterogeneous plumes on the planet, sustaining long-lived isotopic and lithological heterogeneity over its 90 Ma evolution. Previous petrologic studies showed that the Galapagos plume secularly cooled over time and that the decrease in the plume's temperature correlates with an increase in a recycled (pyroxenite) component. We used Al-in-olivine thermometry to show that maximum olivine crystallization temperatures confirm secular cooling of the Galapagos plume. Olivines from the early melting stages of the plume at 90 Ma (Caribbean LIP) record the highest crystallization temperatures (1600 °C). Olivines from the current archipelago record the lowest temperatures of only 1300 °C. The largest decrease in temperature occurred between 90 and 70 Ma ( 200 °C decrease) and coincides with the plume head-tail transition. Olivines from the 60-90 Ma-old accreted Galapagos-tracks in Costa Rica and Panama record higher Ni, Fe/Mn, and lower Ca contents than those from the present-day archipelago, indicating a higher abundance of pyroxenite (recycled oceanic crust) entrained in parts of the plume head that melted to form the Caribbean LIP. However, the Galapagos plume was pyroxenite-rich for 40 Ma thus pyroxenite-entrainment goes beyond the plume-tail transition. Our results suggest that hotter regions of the Galapagos plume entrained larger amounts of dense, recycled components due to their greater buoyancy; however, this

  6. Investigation on balcony plume entrainment

    Institute of Scientific and Technical Information of China (English)

    刘方; NIELSEN; P; V; HEILSELBERG; P; BROHUS; H

    2009-01-01

    An investigation on the scenarios of the spill plume and its equation was presented,including two aspects,i.e.,the small-scale experiment and the numerical simulation. Two balcony spill plume models are assessed by comparing with the fire dynamic simulation (FDS) and small scale model experiment results. Besides validating the spill model by experiments,the effect of different fire locations on balcony plume is also discussed. The results show that the balcony equation in NFPA gives good predictions on the mass flow rate. And the balcony plume entrainment coefficient is independent of the fire location. This investigation is useful for the fire engineers in designing smoke control systems.

  7. Terrestrial Plume Impingement Testbed Project

    Data.gov (United States)

    National Aeronautics and Space Administration — Masten Space Systems proposes to create a terrestrial plume impingement testbed for generating novel datasets for extraterrestrial robotic missions. This testbed...

  8. Ozone production efficiency of a ship-plume: ITCT 2K2 case study.

    Science.gov (United States)

    Kim, Hyun S; Kim, Yong H; Han, Kyung M; Kim, Jhoon; Song, Chul H

    2016-01-01

    Ozone production efficiency (OPE) of ship plume was first evaluated in this study, based on ship-plume photochemical/dynamic model simulations and the ship-plume composition data measured during the ITCT 2K2 (Intercontinental Transport and Chemical Transformation 2002) aircraft campaign. The averaged instantaneous OPEs (OPE(i)‾) estimated via the ship-plume photochemical/dynamic modeling for the ITCT 2K2 ship-plume ranged between 4.61 and 18.92, showing that the values vary with the extent of chemical evolution (or chemical stage) of the ship plume and the stability classes of the marine boundary layer (MBL). Together with OPE(i)‾, the equivalent OPEs (OPE(e)‾) for the entire ITCT 2K2 ship-plume were also estimated. The OPE(e)‾ values varied between 9.73 (for the stable MBL) and 12.73 (for the moderately stable MBL), which agreed well with the OPE(e)‾ of 12.85 estimated based on the ITCT 2K2 ship-plume observations. It was also found that both the model-simulated and observation-based OPE(e)‾ inside the ship-plume were 0.29-0.38 times smaller than the OPE(e)‾ calculated/measured outside the ITCT 2K2 ship-plume. Such low OPEs insides the ship plume were due to the high levels of NO and non-liner ship-plume photochemistry. Possible implications of this ship-plume OPE study in the global chemistry-transport modeling are also discussed. Copyright © 2015 The Authors. Published by Elsevier Ltd.. All rights reserved.

  9. Life Cycle of Mantle Plumes: A perspective from the Galapagos Plume (Invited)

    Science.gov (United States)

    Gazel, E.; Herzberg, C. T.

    2009-12-01

    plume model of the CLIP. The exact form of the secular cooling curve depends on whether the Gorgona komatiites were produced by the Galapagos or another plume. Iceland also exhibits secular cooling, in agreement with previous studies. In general, mantle plumes for LIPS with Paleocene-Permian ages were hotter and melted more extensively than plumes of more modern oceanic islands. This is interpreted to reflect episodic flow from lower mantle domains that are lithologically and geochemically heterogeneous. The majority of lavas from the present-day Galapagos plume formed in a column where melting ended at pressures less than 2 GPa, and this pressure is highly variable. Melting ended at much lower pressures for lavas from the Cocos and Carnegie Ridges, consistent with the channeling of the Galapagos plume to locations of thinner lithosphere. Low pressures of final melting are also inferred for older CLIP lavas, which suggest that the plume head impacted a mid-ocean ridge system.

  10. Thermal Plumes in Ventilated Rooms

    DEFF Research Database (Denmark)

    Kofoed, Peter; Nielsen, Peter V.

    The design of a displacement ventilation system involves determination of the flow rate in the thermal plumes. The flow rate in the plumes and the vertical temperature gradient influence each other, and they are influenced by many factors. This paper shows some descriptions of these effects....

  11. Dilution of Buoyant Surface Plumes

    DEFF Research Database (Denmark)

    Larsen, Torben; Petersen, Ole

    The purpose of present work is to establish a quantitative description of a surface plume which is valid for the range of density differences occurring in relation to sewage outfalls.......The purpose of present work is to establish a quantitative description of a surface plume which is valid for the range of density differences occurring in relation to sewage outfalls....

  12. The interplay between acid-base and free radical chemistry in the heterogeneous oxidation and fragmentation of citric acid in aqueous aerosol by OH radicals

    Science.gov (United States)

    Liu, M.; Wiegel, A. A.; Wilson, K. R.; Houle, F. A.

    2016-12-01

    A key uncertainty in the oxidation of organic compounds such as carboxylic acids in aqueous phase aerosol is how β-scission of alkoxy radicals is altered by acid-base chemistry. In particular, the differences between the unimolecular fragmentation rates of radical anions and their neutral forms may impact the partitioning of organic carbon between the gas and aqueous phase. To investigate the fragmentation reactions that occur during the oxidation of highly oxygenated organic aqueous aerosol, a kinetics model is developed for the OH initiated oxidation of citric acid aerosol at high relative humidities. The reaction scheme includes both free radical and acid-base reactions, uses physically validated rate coefficients, and thus accurately predicts the experimentally observed molecular composition, particle size, and average elemental composition of the aerosol upon oxidation. Free radical reactions functionalize the carbon skeleton while carboxylate groups from acid-base chemistry activate the carbon-carbon bond fragmentation of alkoxy radicals, leading to the formation of low molecular weight, highly oxidized products such as oxaloacetic and mesoxalic acid. Subsequent hydration of carbonyl groups in the oxidized products increases the aerosol hygroscopicity and causes the substantial water uptake and volume growth observed to accompany oxidation. These results highlight the significant role of water in controlling not only changes in physical properties but also the mechanisms of oxidation and fragmentation of aerosol in the atmosphere.

  13. Magmatic plumbing system from lower mantle of Hainan plume

    Science.gov (United States)

    Xia, Shaohong; Sun, Jinlong; Xu, Huilong; Huang, Haibo; Cao, Jinghe

    2017-04-01

    Intraplate volcanism during Late Cenozoic in the Leiqiong area of southernmost South China, with basaltic lava flows covering a total of more than 7000 km2, has been attributed to an underlying Hainan plume. However, detailed features of Hainan plume, such as morphology of magmatic conduits, depth of magmatic pool in the upper mantle and pattern of mantle upwelling, are still enigmatic. Here we present seismic tomographic images of the upper 1100 km of the mantle beneath the southern South China. Our results show a mushroom-like continuous low-velocity anomaly characterized by a columnar tail with diameter of about 200-300 km that tilts downward to lower mantle beneath north of Hainan hotspot and a head that spreads laterally near the mantle transition zone, indicating a magmatic pool in the upper mantle. Further upward, this head is decomposed into small patches, but when encountering the base of the lithosphere, a pancake-like anomaly is shaped again to feed the Hainan volcanism. Our results challenge the classical model of a fixed thermal plume that rises vertically to the surface, and propose the new layering-style pattern of magmatic upwelling of Hainan plume. This work indicates the spatial complexities and differences of global mantle plumes probably due to heterogeneous compositions and changefully thermochemical structures of deep mantle.

  14. Evaluation of phase chemistry and petrochemical aspects of ...

    Indian Academy of Sciences (India)

    petrographic and petrochemical evidences. Tectonic discrimination diagrams involving clinopyroxene chemistry strongly suggest within plate alkaline affinity for the parental magma which is in conformity with the regional plume tectonics.

  15. Phase relations and mineral chemistry in pyrolitic mantle at 1600-2200 °C under pressures up to the uppermost lower mantle: Phase transitions around the 660-km discontinuity and dynamics of upwelling hot plumes

    Science.gov (United States)

    Ishii, Takayuki; Kojitani, Hiroshi; Akaogi, Masaki

    2018-01-01

    We determined phase relations of pyrolite at 12-28 GPa and 1600-2200 °C using a 6-8 Kawai-type multianvil apparatus. A large number of high pressure and high temperature experiments were conducted to constrain the phase relations especially around 660-km depth, compared with previous studies. The phase relations drastically change between 19 and 23 GPa with temperature as follows. At 19-22 GPa, a phase transition of ringwoodite (Rw) to garnet (Gt) + magnesiowüstite (Mw) occurs at 1800 °C, and no Rw is observed at 2200 °C. The mineral proportion of Gt increases with increasing temperature due to this decomposition reaction and becomes larger than that of Rw above 1800 °C. At 23 GPa, pyrolite crystallizes to a mineral assemblage of bridgmanite (Bm) + Mw + Gt + calcium perovskite by the post-spinel (pSp) transition at 1600-2000 °C and the post-garnet (pGt) transition at 2100-2200 °C, the latter of which is defined as a phase transition of a part of Gt to Bm. Clapeyron slopes of the pSp transition and the pGt transition are determined to be -1 and 5 MPa/°C, respectively, in this study. Gt is stable at any temperatures around the 660-km discontinuity (D660), and Gt-disappearance reaction occurs at 25 GPa with no temperature dependence. Densities of pyrolite were calculated in various pressure and temperature conditions by using the mineral proportions and available data of equations of state. The density at 1600 °C is higher than that at 1800-2200 °C at any pressure-temperature conditions in this study. In particular, the drastic density drop occurs at 19-24 GPa between 1600 and 1800-2200 °C because of increase of Gt proportion with increasing temperature. These suggest that upwelling hot plumes composed of pyrolite from the lower mantle do not stagnate and their ascent is promoted across D660. The mineral proportions and the density changes also suggest that the phase transition which causes D660 changes around 1800 °C from the pSp to the pGt transitions

  16. Lagrangian computations of radiating fire plumes

    Science.gov (United States)

    Lakkis, Issam Adnan

    2000-09-01

    Modeling and simulation of fires are useful in determining their impact on nearby and distant objects, quantifying their environmental impact, improving fire suppression techniques, etc. Fires, essentially naturally aspirated combustion phenomena, are buoyancy driven diffusion flames in which the fuel supply rate is governed by the burn rate itself. It has been observed experimentally that the complex interaction between the flow, transport process and chemistry in a fire leads to large scale ``puffing'' an unsteady phenomenon manifested in the periodic ejection of bellowing smoke. The complexity of the phenomenon defies analytical treatment except at the very coarse grain level essentially using similarity principles. Numerical solutions based on ensemble averaging/closure and flow- combustion interaction models are encumbered by uncertainty and unproven hypotheses. A viable alternative is a numerical simulation of the unsteady governing equations with sufficient resolution to capture the important scales. In this work, contributions to a grid- free Lagrangian approach to simulate numerically fire plumes are suggested. The physical model incorporates unsteady buoyancy dynamics, transport of heat and mass by diffusion and convection, radiative transport of heat, and a single-step, infinite-rate chemical reaction with exothermic heat release. The numerical approach is based on the vortex method in which the unsteady conservation equations of vorticity, chemical species and energy are solved using a set of moving computational elements carrying time dependent quantities. A compatible approach is proposed to solve the radiative transport equations. Simulations of an axisymmetric plume are used to identify the dynamic mechanisms leading to ``puffing'', the processes which govern entrainment into the rising unsteady plume, burn rate, and overall observable quantities such as the flame height, radiation flux, etc. (Copies available exclusively from MIT Libraries, Rm. 14

  17. Intercontinental transport of nitrogen oxide pollution plumes

    Directory of Open Access Journals (Sweden)

    M. Wenig

    2003-01-01

    Full Text Available We describe the first satellite observation of intercontinental transport of nitrogen oxides emitted by power plants, verified by simulations with a particle tracer model. The analysis of such episodes shows that anthropogenic NOx plumes may influence the atmospheric chemistry thousands of kilometers away from its origin, as well as the ocean they traverse due to nitrogen fertilization. This kind of monitoring became possible by applying an improved algorithm to extract the tropospheric fraction of NO2 from the spectral data coming from the GOME instrument. As an example we show the observation of NO2 in the time period 4--14 May, 1998, from the South African Plateau to Australia which was possible due to favourable weather conditions during that time period which availed the satellite measurement. This episode was also simulated with the Lagrangian particle dispersion model FLEXPART which uses NOx emissions taken from an inventory for industrial emissions in South Africa and is driven with analyses from the European Centre for Medium-Range Weather Forecasts. Additionally lightning emissions were taken into account by utilizing Lightning Imaging Sensor data. Lightning was found to contribute probably not more than 25% of the resulting concentrations. Both, the measured and simulated emission plume show matching patterns while traversing the Indian Ocean to Australia and show great resemblance to the aerosol and CO2 transport observed by Piketh et al. (2000.

  18. Direct Measurement of Mercury Reactions In Coal Power Plant Plumes

    Energy Technology Data Exchange (ETDEWEB)

    Leonard Levin

    2005-12-31

    Recent field and pilot-scale results indicate that divalent mercury emitted from power plants may rapidly transform to elemental mercury within the power plant plumes. Simulations of mercury chemistry in plumes based on measured rates to date have improved regional model fits to Mercury Deposition Network wet deposition data for particular years, while not degrading model verification fits for remaining years of the ensemble. The years with improved fit are those with simulated deposition in grid cells in the State of Pennsylvania that have matching MDN station data significantly less than the model values. This project seeks to establish a full-scale data basis for whether or not significant reduction or oxidation reactions occur to mercury emitted from coal-fired power plants, and what numerical redox rate should apply for extension to other sources and for modeling of power plant mercury plumes locally, regionally, and nationally. Although in-stack mercury (Hg) speciation measurements are essential to the development of control technologies and to provide data for input into atmospheric fate and transport models, the determination of speciation in a cooling coal combustion plume is more relevant for use in estimating Hg fate and effects through the atmosphere. It is mercury transformations that may occur in the plume that determine the eventual rate and patterns of mercury deposited to the earth's surface. A necessary first step in developing a supportable approach to modeling any such transformations is to directly measure the forms and concentrations of mercury from the stack exit downwind to full dispersion in the atmosphere. As a result, a study was sponsored by EPRI and jointly funded by EPRI, the U.S Department of Energy (DOE), and the Wisconsin Department of Administration. The study was designed to further our understanding of plume chemistry. The study was carried out at the We Energies Pleasant Prairie Power Plant, Pleasant Prairie, Wisconsin

  19. Heterogeneous chemistry related to Antarctic ozone depletion: Reaction of ClONO2 and N2O5 on ice surfaces

    Science.gov (United States)

    Tolbert, Margaret A.; Rossi, Michel J.; Golden, David M.

    1988-01-01

    Laboratory studies of heterogeneous reactions of possible importance for Antarctic ozone depletion were performed. In particular, the reactions of chlorine nitrate (ClONO2) and dinitrogen pentoxide (N2O5) were investigated on ice and HCl/ice surfaces. These reactions occur on the surfaces of polar stratospheric clouds (PSCs) over Antarctica. One reaction transforms the stable chlorine reservoir species (ClONO2 and HCl) into photochemically active chlorine in the form of HOCl and Cl2. Condensation of HNO3 in the reactions removes odd nitrogen from the stratosphere, a requirement in nearly all models of Antarctic ozone depletion. Other reactions may also be important for Antarctic ozone depletion. Like the reactions of chlorine nitrate, these reactions deplete odd nitrogen through HNO3 condensation. In addition, one reaction converts a stable chlorine reservior species (HCl) into photochemically active chlorine (ClNO2). These reactions were studied with a modified version of a Knudsen cell flow reactor.

  20. Impact of surface chemistry

    Science.gov (United States)

    Somorjai, Gabor A.; Li, Yimin

    2011-01-01

    The applications of molecular surface chemistry in heterogeneous catalyst technology, semiconductor-based technology, medical technology, anticorrosion and lubricant technology, and nanotechnology are highlighted in this perspective. The evolution of surface chemistry at the molecular level is reviewed, and the key roles of surface instrumentation developments for in situ studies of the gas–solid, liquid–solid, and solid–solid interfaces under reaction conditions are emphasized. PMID:20880833

  1. A global model for prediction of the stratospheric ozone layer including climate feedback and heterogeneous chemistry. Final report; Globales Modell zur Vorhersage der Entwicklung der stratosphaerischen Ozonschicht mit Beruecksichtigung von Klimaeffekten und heterogener Chemie. Abschlussbericht

    Energy Technology Data Exchange (ETDEWEB)

    Bruehl, C.; Steil, B. [Max-Planck-Institut fuer Chemie (Otto-Hahn-Institut), Mainz (Germany). Abt. Luftchemie; Manzini, E. [Max-Planck-Institut fuer Meteorologie, Hamburg (Germany); Dameris, M.; Grewe, V. [DLR Deutsches Zentrum fuer Luft- und Raumfahrt e.V., Oberpfaffenhofen (Germany)

    2000-08-01

    The circulation model with interactive chemistry MA-ECHAM-CHEM is able to simulate temperatures and trace gas distributions in the stratosphere in good agreement with satellite observations, including seasonal cycle and interannual variability, and also polar stratospheric clouds in Arctic and Antarctic, as well as filament-like structures in midlatitudes observed by CHRISTA. The model is stable and driftfree in the considered scenarios. The computed differences in temperature patterns, ozone and water vapor distributions between sixties and nineties agree well with observations, increasing confidence of the prediction capability of the model. For the conditions of 2030 the model predicts a partial recovery of the Antarctic ozone hole because of decreasing chlorine. In the Arctic spring the variability increases especially towards midlatitudes, in contradiction to other studies there is no tendency for stabilization of the polar vortex or a northern ozone hole. On average the effect of the chlorine decrease dominates. The greenhouse effect has, however, complex implications on dynamics in the middle atmosphere. (orig.) [German] Das Zirkulationsmodell mit interaktiver Chemie MA-ECHAM-CHEM ist in der Lage, Temperaturen und Spurenstoffverteilungen in der Stratosphaere einschliesslich von Jahresgang und Variabilitaet zwischen einzelnen Jahren in guter Uebereinstimmung mit Satellitenbeobachtungen zu simulieren. Dies schliesst polare Stratosphaerenwolken in Arktis und Antarktis sowie von CHRISTA beobachtete Filamenstrukturen in mittleren Breiten ein. Das Modell ist stabil und in der Lage, vorgegebene Szenarien driftfrei einzuhalten. Die berechneten Unterschiede in Temperaturmustern, Ozon- und Wasserdampfverteilungen zwischen den Sechzigern und den Neunzigern passen zu den Beobachtungen, was das Vertrauen in die Prognosefaehigkeit des Modells erhoeht. Fuer die Bedingungen des Jahres 2030 sagt das Modell eine teilweise Auffuellung des antarktischen Ozonlochs durch

  2. Microphysical, chemical, and dynamical processes in aircraft plumes

    Energy Technology Data Exchange (ETDEWEB)

    Kaercher, B. [Deutsche Forschungsanstalt fuer Luft- und Raumfahrt e.V. (DLR), Wessling (Germany). Inst. fuer Physik der Atmosphaere]|[Muenchen Univ., Freising (Germany). Lehrstuhl fuer Bioklimatologie und Immissionsforschung; Hirschberg, M.; Fabian, P. [Muenchen Univ., Freising (Germany). Lehrstuhl fuer Bioklimatologie und Immissionsforschung

    1997-12-01

    This project investigated theoretically microphysical and chemical processes in aircraft exhaust plumes during the first stages of wake dispersion. A suitable computational model has been developed, describing the two-dimensional (2D) turbulent mixing of a single jet of exhaust gas from aircraft engines with the atmosphere. The model has been used to work out general features of transport and conversion of exhaust effluents. It has also been employed to study the conditions in the jet that lead to the formation of ice contrails. The model has then been extended to include a set of all relevant chemical reactions in the gas phase and to study the chemical conversion of exhaust species with regard to the specific fluid dynamical conditions of the jet regime. A trajectory box model has been developed that is driven by turbulent mixing rates from the 2D jet model, and by parameterized mixing rates at later stages of wake dispersion. Further, a microphysical module has been designed and coupled to the box model, with which detailed investigations of adsorption, binary homogeneous and heterogeneous nucleation, heteromolecular condensation and evaporation, scavenging and coagulation, and homogeneous and heterogeneous freezing in diluting aircraft exhaust plumes and contrails have been performed. The potential for heterogeneous chemical processing on/in plume and contrail aerosols has been investigated. The results have supported the analyses of in situ observations. Vice versa, model development took great advantages form the close collaborations with several experimental groups. (orig.) 144 figs., 42 tabs., 497 refs.

  3. Smoke plumes: Emissions and effects

    Science.gov (United States)

    Susan O' Neill; Shawn Urbanski; Scott Goodrick; Sim Larkin

    2017-01-01

    Smoke can manifest itself as a towering plume rising against the clear blue sky-or as a vast swath of thick haze, with fingers that settle into valleys overnight. It comes in many forms and colors, from fluffy and white to thick and black. Smoke plumes can rise high into the atmosphere and travel great distances across oceans and continents. Or smoke can remain close...

  4. Investigation of Balcony Plume Entrainment

    DEFF Research Database (Denmark)

    Liu, F.; Nielsen, Peter V.; Heiselberg, Per

    2009-01-01

    An investigation on the scenarios of the spill plume and its equation was presented in this paper. The study includes two aspects, i.e., the small-scale experiment and the numerical simulation. Two balcony spill plume models are assessed by comparing with the FDS (Fire Dynamic Simulation) and sma...... is independent of the fire location. The Investigations in this paper are useful for the fire engineers in designing smoke control systems.......An investigation on the scenarios of the spill plume and its equation was presented in this paper. The study includes two aspects, i.e., the small-scale experiment and the numerical simulation. Two balcony spill plume models are assessed by comparing with the FDS (Fire Dynamic Simulation) and small...... scale model experiment results. Besides validating the spill model by experiments, the effect of different fire location on balcony plume is also discussed. The results show that the balcony equation in NFPA would give good predictions on the mass flow rate. And the balcony plume entrainment coefficient...

  5. Plume Aerosol Size Distribution Modeling and Comparisons to PrAIRie2005 Field Study Data

    Science.gov (United States)

    Cho, S.; Liggio, J.; Makar, P.; Li, S.; Racinthe, J.

    2006-12-01

    As part of the analysis phase of the PrAIRie2005 field study, the effects of different Edmonton-area emission sources on local air-quality are being examined. Four large coal-fired power-plants are located to the West of the city. Here, the effects of these power-plants on urban and regional air-quality will be examined, using both plume and regional air-quality models. During the last few decades, coal-fired power plants have been found to be as a major source of pollution, affecting public-health. According to NACEC (North American Commission for Environmental Corporation, 2001)'s report, 46 of the top 50 air polluters in North America were power plants. The importance of such sources has resulted in several attempts to improve understanding of the basic formation mechanisms of plume particulate matter. Sulphur dioxide contributes to acidifying emissions and to the production of secondary acidic aerosols that have been linked to a number of serious human health problems, acid rain and visibility (Seinfeld and Pandis, 1998; Hidy, 1984; Wilson and McMurray, 1981). Primary particulate matter originating directly from coal-fired power plants may also increase secondary particulate mass by providing a surface for sulphuric acid absorption . Environment Canada's PrAIRie2005 field study between August 12th and September 7th, 2005 included overflights and downwind measurements near the Edmonton powerplants (Wabamun, Sundance, Keephills and Genesee). The data collected consisted of particle size distributions, ozone, NOX, total mass and the chemical composition of fine particles. In order to investigate and improve our understanding of the formation mechanisms and physical properties of power-plant-generated aerosols in the Edmonton area, the Plume Aerosol Microphysical (PAM) model has been employed. This model accounts for gas-phase chemistry, aerosol microphysical processes (i.e. homogeneous/heterogeneous nucleation, condensation/evaporation and coagulation) and

  6. Taming Prebiotic Chemistry: The Role of Heterogeneous and Interfacial Catalysis in the Emergence of a Prebiotic Catalytic/Information Polymer System.

    Science.gov (United States)

    Monnard, Pierre-Alain

    2016-11-04

    Cellular life is based on interacting polymer networks that serve as catalysts, genetic information and structural molecules. The complexity of the DNA, RNA and protein biochemistry suggests that it must have been preceded by simpler systems. The RNA world hypothesis proposes RNA as the prime candidate for such a primal system. Even though this proposition has gained currency, its investigations have highlighted several challenges with respect to bulk aqueous media: (1) the synthesis of RNA monomers is difficult; (2) efficient pathways for monomer polymerization into functional RNAs and their subsequent, sequence-specific replication remain elusive; and (3) the evolution of the RNA function towards cellular metabolism in isolation is questionable in view of the chemical mixtures expected on the early Earth. This review will address the question of the possible roles of heterogeneous media and catalysis as drivers for the emergence of RNA-based polymer networks. We will show that this approach to non-enzymatic polymerizations of RNA from monomers and RNA evolution cannot only solve some issues encountered during reactions in bulk aqueous solutions, but may also explain the co-emergence of the various polymers indispensable for life in complex mixtures and their organization into primitive networks.

  7. Active Volcanic Plumes on Io

    Science.gov (United States)

    1997-01-01

    This color image, acquired during Galileo's ninth orbit around Jupiter, shows two volcanic plumes on Io. One plume was captured on the bright limb or edge of the moon (see inset at upper right), erupting over a caldera (volcanic depression) named Pillan Patera after a South American god of thunder, fire and volcanoes. The plume seen by Galileo is 140 kilometers (86 miles) high and was also detected by the Hubble Space Telescope. The Galileo spacecraft will pass almost directly over Pillan Patera in 1999 at a range of only 600 kilometers (373 miles).The second plume, seen near the terminator (boundary between day and night), is called Prometheus after the Greek fire god (see inset at lower right). The shadow of the 75-kilometer (45- mile) high airborne plume can be seen extending to the right of the eruption vent. The vent is near the center of the bright and dark rings. Plumes on Io have a blue color, so the plume shadow is reddish. The Prometheus plume can be seen in every Galileo image with the appropriate geometry, as well as every such Voyager image acquired in 1979. It is possible that this plume has been continuously active for more than 18 years. In contrast, a plume has never been seen at Pillan Patera prior to the recent Galileo and Hubble Space Telescope images.North is toward the top of the picture. The resolution is about 6 kilometers (3.7 miles) per picture element. This composite uses images taken with the green, violet and near infrared filters of the solid state imaging (CCD) system on NASA's Galileo spacecraft. The images were obtained on June 28, 1997, at a range of more than 600,000 kilometers (372,000 miles).The Jet Propulsion Laboratory, Pasadena, CA manages the Galileo mission for NASA's Office of Space Science, Washington, DC. JPL is an operating division of California Institute of Technology (Caltech).This image and other images and data received from Galileo are posted on the World Wide Web, on the Galileo mission home page at URL http

  8. Development and Evaluation of a Reactive-Dispersive Plume Model: TexAQS II 2006 Case Study

    Science.gov (United States)

    Kim, Yong Hoon; Kim, Hyun Soo; Song, Chul Han

    2015-04-01

    We describe the development and evaluation of a reactive-dispersive plume model (RDPM) that combines a photo-chemistry model with a plume dilution driven by turbulent dispersion of a power-plant plume. The plume transport and turbulent dispersion are derived from a Gaussian plume model and the plume chemistry model uses 71 HxOy-NxOy-CH4 chemistry-related reactions and 184 NMHC-related reactions. Emissions from large-scale point sources have continuously increased due to the rapid industrial growth. To extensively understand and assess atmospheric impacts of the power-plant emissions, a general RDPM was applied to simultaneously simulate the dynamics and photo-chemistry of the Texas power-plant plumes. During the second Texas Air Quality Study 2006 (TexAQS II 2006) on 16 September 2006, pollutant concentrations were measured by NOAA WP-3D aircraft with successive transects across power-plant plumes in Texas, USA. The simulation performances of the RDPM were evaluated by a comparison study, using the observation data obtained from the measurements of a NOAA WP-3D flight during TexAQS II 2006 airborne field campaign. On 16 September, the WP-3D aircraft observed mainly meteorological parameters and particulate species concentrations, traversing the Monticello and Welsh power-plant plumes four times from transects A to D. In addition, some meteorological variables in an initial condition for model simulation were obtained from the Weather Research and Forecasting (WRF) model output for the specific objects. These power-plant plume cases were selected in this study, because a large number of nitrogen oxides and sulfur dioxide concentrations inside the power-plant plumes were measured without any interruption of other emission sources. For the Monticello and Welsh power-plant plumes, the model-predicted concentrations showed good agreements with the observed concentrations of ambient species (e.g., nitrogen oxides, ozone, sulfur dioxide, etc.) at the four transects. Based

  9. Recycled crust in the Galápagos Plume source at 70 Ma: Implications for plume evolution

    Science.gov (United States)

    Trela, Jarek; Vidito, Christopher; Gazel, Esteban; Herzberg, Claude; Class, Cornelia; Whalen, William; Jicha, Brian; Bizimis, Michael; Alvarado, Guillermo E.

    2015-09-01

    Galápagos plume-related lavas in the accreted terranes of the Caribbean and along the west coast of Costa Rica and Panama provide evidence on the evolution of the Galápagos mantle plume, specifically its mantle temperature, size and composition of heterogeneities, and dynamics. Here we provide new 40Ar/39Ar ages, major and trace element data, Sr-Nd-Pb isotopic compositions, and high-precision olivine analyses for samples from the Quepos terrane (Costa Rica) to closely examine the transitional phase of the Galápagos Plume from Large Igneous Province (LIP) to ocean island basalt (OIB) forming stages. The new ages indicate that the record of Quepos volcanism began at 70 Ma and persisted for 10 Ma. Petrological evidence suggests that the maximum mantle potential temperature (Tp) of the plume changed from ∼1650° to ∼1550 °C between 90-70 Ma. This change correlates with a dominant pyroxenite component in the Galapagos source as indicated by high Ni and Fe/Mn and low Ca olivines relative to those that crystallized in normal peridotite derived melts. The decrease in Tp also correlates with an increase in high-field strength element enrichments, e.g., Nb/Nb*, of the erupted lavas. Radiogenic isotope ratios (Nd-Pb) suggest that the Quepos terrane samples have intermediate (Central Domain) radiogenic signatures. The Galápagos plume at 70 Ma represents elevated pyroxenite melt productivity relative to peridotite in a cooling lithologically heterogeneous mantle.

  10. Mass discharge in a tracer plume: evaluation of the Theissen Polygon Method.

    Science.gov (United States)

    Mackay, Douglas M; Einarson, Murray D; Kaiser, Phil M; Nozawa-Inoue, Mamie; Goyal, Sham; Chakraborty, Irina; Rasa, Ehsan; Scow, Kate M

    2012-01-01

    A tracer plume was created within a thin aquifer by injection for 299 d of two adjacent "sub-plumes" to represent one type of plume heterogeneity encountered in practice. The plume was monitored by snapshot sampling of transects of fully screened wells. The mass injection rate and total mass injected were known. Using all wells in each transect (0.77 m well spacing, 1.4 points/m(2) sampling density), the Theissen Polygon Method (TPM) yielded apparently accurate mass discharge (M(d) ) estimates at three transects for 12 snapshots. When applied to hypothetical sparser transects using subsets of the wells with average spacing and sampling density from 1.55 to 5.39 m and 0.70 to 0.20 points/m(2) , respectively, the TPM accuracy depended on well spacing and location of the wells in the hypothesized transect with respect to the sub-plumes. Potential error was relatively low when the well spacing was less than the widths of the sub-plumes (>0.35 points/m(2) ). Potential error increased for well spacing similar to or greater than the sub-plume widths, or when less than 1% of the plume area was sampled. For low density sampling of laterally heterogeneous plumes, small changes in groundwater flow direction can lead to wide fluctuations in M(d) estimates by the TPM. However, sampling conducted when flow is known or likely to be in a preferred direction can potentially allow more useful comparisons of M(d) over multiyear time frames, such as required for performance evaluation of natural attenuation or engineered remediation systems. © 2012, The Author(s). Ground Water © 2012, National Ground Water Association.

  11. The Biogeochemistry of Contaminant Groundwater Plumes Arising from Waste Disposal Facilities

    DEFF Research Database (Denmark)

    Bjerg, Poul Løgstrup; Albrechtsen, Hans-Jørgen; Kjeldsen, Peter

    2014-01-01

    Landfills with solid waste are abundant sources of groundwater pollution all over the world. Old uncontrolled municipal landfills are often large, heterogeneous sources with demolition waste, minor fractions of commercial or industrial waste, and organic waste from households. Strongly anaerobic ...... at landfill sites. Finally, the potential chemical or ecological impact from landfills located in former wetlands or near surface water bodies may deserve attention in future studies....... and the heterogeneity of the source may create a variable leaching pattern and maybe also multiple plumes; and (4) significant natural attenuation of xenobiotic organic compounds occurs, but the complexity of leachate plumes with respect to compounds (inorganic and xenobiotic organic compounds) and biogeochemical...

  12. The LIP-OIB transitional phase in the Galapagos mantle plume

    Science.gov (United States)

    Trela, J.; Gazel, E.; Vidito, C. A.; Class, C.; Jicha, B. R.; Bizimis, M.; Herzberg, C. T.; Alvarado-Induni, G.

    2014-12-01

    Although significant work has been done on LIPS and OIB, no complete record of the evolution of a mantle plume is available at this point. Galapagos-related lavas provide a complete record of the evolution of a mantle plume since the plume's initial stages in the Cretaceous. Our petrological models (PRIMELT2) suggest that the Galapagos plume head that formed the Caribbean Large Igneous Province (CLIP) at ~95 Ma melted at hotter temperatures than the ocean island basalt (OIB) equivalents of the modern archipelago. While this work suggests a significant decrease in mantle potential temperatures (Tp) over time, the exact mechanism responsible for secular cooling of the Galapagos plume remains unclear. One viable explanation is that plumes entraining recycled oceanic crust (pyroxenite) will be cooler than purely peridotite plumes, due to the effect of dense pyroxenite on the plume's buoyancy. High-precision electron microprobe analyses on olivine cores from the ~70 Ma Galapagos-related Quepos terrane in Costa Rica indicate a mixed peridotite-pyroxenite source lithology, not evident during the LIP stage. The appearance of this pyroxenitic component correlates with the first record of an EMII isotopic signature (Northern Galapagos Domain), and significant high-field strength enrichments in the Galapagos plume related lavas. This dense pyroxenite component may explain the marked decrease in Tp observed at ~70 Ma due to its effect on the plume's buoyancy. Otherwise, the pyroxenite component may have been diluted during voluminous basalt production of the CLIP by high peridotite melt fractions. Future research will incorporate further petrological modeling, olivine chemistry, and radiogenic isotope work of accreted Galapagos terranes in Central America to test whether or not a decrease in Tp correlates with increasing pyroxenite content in source melts.

  13. Investigation of Heterogeneous Atmospheric Chlorine Chemistry: Modeling and Environmental Chamber Studies Authors: Cameron B. Faxon, Lea Hildebrandt Ruiz, and David Allen University of Texas at Austin, McKetta Department of Chemical Engineering

    Science.gov (United States)

    Faxon, C. B.; Hildebrandt Ruiz, L.; Allen, D.

    2013-12-01

    Previous work has shown that gas phase atomic chlorine radicals (Cl*) can influence tropospheric photochemistry, including concentrations of volatile organic compound (VOC) and ozone. These radicals are produced through both gas phase and heterogeneous pathways. This work presents computational and experimental investigation into the heterogeneous reactions of chloride aerosols. An overview of a sensitivity analysis of the physical parameters involved in the heterogeneous production of nitryl chloride (ClNO2) (R1-R5) will comprise the computational work presented. NO2(g) + NO3(g) ↔ N2O5(g) (R1) N2O5(aq) ↔ N2O5(aq) (R2) N2O5(aq) ↔ NO2+(aq) + NO3-(aq) (R3) NO2+(aq) + H2O(aq) → H3O+(aq) + HNO3(aq) (R4a) NO2+(aq) + Cl- → ClNO2 + H2O(aq) (R4b) NO3-(aq) + H+ ↔ HNO3+(aq) (R5) Relative parameters include the reactive uptake coefficient, ClNO2 yield, particle surface area, and gas phase concentrations of VOCs and NOx. The sensitivity analysis results were generated through photochemical box modeling and focus on the production of ClNO2 and impacts to ozone production. Results were compared to a base case scenario in which all heterogeneous reactions were absent. Parameter values reaching the upper limits reported in the literature were tested, and results indicate that ClNO2 chemistry can potentially change peak O3 concentrations by -10.5% to 27%. NOx availability was also found to play an important role. Experimental results of the heterogeneous reaction between OH* and particulate chloride (R6-R7) will also be discussed. The mechanism is shown below, and OH***Cl- represents an intermediate species forming at the particle surface. OH(g) + Cl-(aq) → OH***Cl-(aq) (R6) 2OH***Cl-(aq) → Cl2,g + 2OH-(aq) (R7) Environmental chamber experiments involving the exposure of NaCl aerosol particles to typical atmospheric conditions (HOx, NOx, O3 and UV radiation) were performed. A 10 cubic meter teflon reaction chamber equipped with UV lights was used to contain the

  14. Coastal river plumes: Collisions and coalescence

    Science.gov (United States)

    Warrick, Jonathan A.; Farnsworth, Katherine L.

    2017-02-01

    Plumes of buoyant river water spread in the ocean from river mouths, and these plumes influence water quality, sediment dispersal, primary productivity, and circulation along the world's coasts. Most investigations of river plumes have focused on large rivers in a coastal region, for which the physical spreading of the plume is assumed to be independent from the influence of other buoyant plumes. Here we provide new understanding of the spreading patterns of multiple plumes interacting along simplified coastal settings by investigating: (i) the relative likelihood of plume-to-plume interactions at different settings using geophysical scaling, (ii) the diversity of plume frontal collision types and the effects of these collisions on spreading patterns of plume waters using a two-dimensional hydrodynamic model, and (iii) the fundamental differences in plume spreading patterns between coasts with single and multiple rivers using a three-dimensional hydrodynamic model. Geophysical scaling suggests that coastal margins with numerous small rivers (watershed areas 100,000 km2). When two plume fronts meet, several types of collision attributes were found, including refection, subduction and occlusion. We found that the relative differences in pre-collision plume densities and thicknesses strongly influenced the resulting collision types. The three-dimensional spreading of buoyant plumes was found to be influenced by the presence of additional rivers for all modeled scenarios, including those with and without Coriolis and wind. Combined, these results suggest that plume-to-plume interactions are common phenomena for coastal regions offshore of the world's smaller rivers and for coastal settings with multiple river mouths in close proximity, and that the spreading and fate of river waters in these settings will be strongly influenced by these interactions. We conclude that new investigations are needed to characterize how plumes interact offshore of river mouths to better

  15. Beyond the vent: New perspectives on hydrothermal plumes and pelagic biology

    Science.gov (United States)

    Phillips, Brennan T.

    2017-03-01

    Submarine hydrothermal vent fields introduce buoyant plumes of chemically altered seawater to the deep-sea water column. Chemoautotrophic microbes exploit this energy source, facilitating seafloor-based primary production that evidence suggests may transfer to pelagic consumers. While most hydrothermal plumes have relatively small volumes, there are recent examples of large-scale plume events associated with periods of eruptive activity, which have had a pronounced effect on water-column biology. This correlation suggests that hydrothermal plumes may have influenced basin-scale ocean chemistry during periods of increased submarine volcanism during the Phanerozoic eon. This paper synthesizes a growing body of scientific evidence supporting the hypothesis that hydrothermal plumes are the energetic basis of unique deep-sea pelagic food webs. While many important questions remain concerning the biology of hydrothermal plumes, this discussion is not present in ongoing management efforts related to seafloor massive sulfide (SMS) mining. Increased research efforts, focused on high-resolution surveys of midwater biology relative to plume structures, are recommended to establish baseline conditions and monitor the impact of future mining-based disturbances to the pelagic biosphere.

  16. Space Shuttle main engine OPAD: The search for a hardware enhanced plume

    Science.gov (United States)

    Powers, W. T.; Cooper, A. E.; Wallace, Tim L.; Buntine, W. L.; Whitaker, K. W.

    1993-01-01

    The process of applying spectroscopy to the Space Shuttle Main Engine (SSME) for plume diagnostics, as it exists today, originated at Marshall Space Flight Center in Huntsville, Alabama, and its implementation was assured largely through the efforts of Sverdrup AEDC, in Tullahoma, Tennessee. This team continues to lead and guide efforts in the plume diagnostics arena. The process, Optical Plume Anomaly Detection (OPAD), formed the basis for various activities in the development of ground-based systems as well as the development of in-flight plume spectroscopy. OPAD currently provides and will continue to provide valuable information relative to future systems definitions, instrumentation development, code validation, and data diagnostic processing. OPAD is based on the detection of anomalous atomic and molecular species in the SSME plume using two complete, stand-alone optical spectrometers. To-date OPAD has acquired data on 44 test firings of the SSME at the Technology Test Bed (TTB) at MSFC. The purpose of this paper will be to provide an introduction to the OPAD system by discussing the process of obtaining data as well as the methods of examining and interpreting the data. It will encompass such issues as selection of instrumentation correlation of data to nominal engine operation, investigation of SSME component erosion via OPAD spectral data, necessity and benefits of plume seeding, application of artificial intelligence (AI) techniques to data analysis, and the present status of efforts to quantify specie erosion utilizing standard plume and chemistry codes as well as radiative models currently under development.

  17. Tracking stormwater discharge plumes and water quality of the Tijuana River with multispectral aerial imagery

    Science.gov (United States)

    Svejkovsky, Jan; Nezlin, Nikolay P.; Mustain, Neomi M.; Kum, Jamie B.

    2010-04-01

    Spatial-temporal characteristics and environmental factors regulating the behavior of stormwater runoff from the Tijuana River in southern California were analyzed utilizing very high resolution aerial imagery, and time-coincident environmental and bacterial sampling data. Thirty nine multispectral aerial images with 2.1-m spatial resolution were collected after major rainstorms during 2003-2008. Utilizing differences in color reflectance characteristics, the ocean surface was classified into non-plume waters and three components of the runoff plume reflecting differences in age and suspended sediment concentrations. Tijuana River discharge rate was the primary factor regulating the size of the freshest plume component and its shorelong extensions to the north and south. Wave direction was found to affect the shorelong distribution of the shoreline-connected fresh plume components much more strongly than wind direction. Wave-driven sediment resuspension also significantly contributed to the size of the oldest plume component. Surf zone bacterial samples collected near the time of each image acquisition were used to evaluate the contamination characteristics of each plume component. The bacterial contamination of the freshest plume waters was very high (100% of surf zone samples exceeded California standards), but the oldest plume areas were heterogeneous, including both polluted and clean waters. The aerial imagery archive allowed study of river runoff characteristics on a plume component level, not previously done with coarser satellite images. Our findings suggest that high resolution imaging can quickly identify the spatial extents of the most polluted runoff but cannot be relied upon to always identify the entire polluted area. Our results also indicate that wave-driven transport is important in distributing the most contaminated plume areas along the shoreline.

  18. Bad chemistry

    OpenAIRE

    Petsko, Gregory A

    2004-01-01

    General chemistry courses haven't changed significantly in forty years. Because most basic chemistry students are premedical students, medical schools have enormous influence and could help us start all over again to create undergraduate chemistry education that works.

  19. Exhaust Nozzle Plume and Shock Wave Interaction

    Science.gov (United States)

    Castner, Raymond S.; Elmiligui, Alaa; Cliff, Susan

    2013-01-01

    Fundamental research for sonic boom reduction is needed to quantify the interaction of shock waves generated from the aircraft wing or tail surfaces with the exhaust plume. Both the nozzle exhaust plume shape and the tail shock shape may be affected by an interaction that may alter the vehicle sonic boom signature. The plume and shock interaction was studied using Computational Fluid Dynamics simulation on two types of convergent-divergent nozzles and a simple wedge shock generator. The nozzle plume effects on the lower wedge compression region are evaluated for two- and three-dimensional nozzle plumes. Results show that the compression from the wedge deflects the nozzle plume and shocks form on the deflected lower plume boundary. The sonic boom pressure signature of the wedge is modified by the presence of the plume, and the computational predictions show significant (8 to 15 percent) changes in shock amplitude.

  20. Ship exhaust gas plume cooling

    NARCIS (Netherlands)

    Schleijpen, H.M.A.; Neele, P.P.

    2004-01-01

    The exhaust gas plume is an important and sometimes dominating contributor to the infrared signature of ships. Suppression of the infrared ship signatures has been studied by TNO for the Royal Netherlands Navy over considerable time. This study deals with the suppression effects, which can be

  1. Characterization of redox conditions in pollution plumes

    DEFF Research Database (Denmark)

    Christensen, Thomas Højlund; Bjerg, Poul Løgstrup; Banwart, Steven A.

    2000-01-01

    Evalution of redox conditions in groundwater pollution plumes is often a prerequisite for understanding the behviour of the pollutants in the plume and for selecting remediation approaches. Measuring of redox conditions in pollution plumes is, however, a fairly recent issue and yet relative few...

  2. Plasma plume MHD power generator and method

    Science.gov (United States)

    Hammer, J.H.

    1993-08-10

    A method is described of generating power at a situs exposed to the solar wind which comprises creating at separate sources at the situs discrete plasma plumes extending in opposed directions, providing electrical communication between the plumes at their source and interposing a desired electrical load in the said electrical communication between the plumes.

  3. Water adsorption on aircraft-combustor soot under young plume conditions

    Energy Technology Data Exchange (ETDEWEB)

    Popovitcheva, O.B.; Trukhin, M.E.; Persiantseva, N.M.; Shonija, N.K. [Moscow State Univ. (Russian Federation)

    2001-03-01

    Laboratory studies of water adsorption and initial water uptake on aircraft-combustor soot, produced by combustion of sulphur-free hydrocarbon fuel, are presented. Due to the specific microporous structure and surface heterogeneity, the soot particles can acquire a substantial fraction of a water monolayer, even in the youngest plume. This sulphur-independent heterogeneous mode, driven by presence of water on soot surface, may be the cause for a visible contrail formation at low sulphur content in the jet fuel. (Author)

  4. A modeling study of SO x-NO x-Hydrocarbon plumes and their transport to the background troposphere

    Science.gov (United States)

    Balko, James A.; Peters, Leonard K.

    A model which emulates the behavior of urban-industrial plumes has been developed and used to analyze the chemical reaction processes occurring as a polluted air mass is transported from an urban area. A 73-step reaction mechanism describing hydrocarbon/NO xSO x chemistry was used, with photolytic rate constants depending on the latitude, time of day and time of year. The model includes the physical processes of plume dilution, entrainment and dry deposition, and is simulated under a diurnally varying mixing layer or neutral atmospheric stability conditions. Simulation results are compared with reported field measurements for plumes from St. Louis, Milwaukee, and a power plant plume entrained in the Milwaukee urban plume. The agreement with field concentrations and SO 2 transformation rate data is good, the latter ranging from 1 to 12 % h -1. The study was extended to hypothetical plumes for parametric analysis. In every case considered, the classic O 3 peak occurred at about 3:30 p.m., essentially independent of initial concentrations and plume departure time. The analysis also indicated that substantial SO 2 oxidation via homogeneous gas phase chemistry can occur at night-time, the prerequisite being a high HG/NO x ratio.

  5. Determination of smoke plume and layer heights using scanning lidar data

    Science.gov (United States)

    Vladimir A. Kovalev; Alexander Petkov; Cyle Wold; Shawn Urbanski; Wei Min Hao

    2009-01-01

    The methodology of using mobile scanning lidar data for investigation of smoke plume rise and high-resolution smoke dispersion is considered. The methodology is based on the lidar-signal transformation proposed recently [Appl. Opt. 48, 2559 (2009)]. In this study, similar methodology is used to create the atmospheric heterogeneity height indicator (HHI...

  6. Teaching the Mantle Plumes Debate

    Science.gov (United States)

    Foulger, G. R.

    2010-12-01

    There is an ongoing debate regarding whether or not mantle plumes exist. This debate has highlighted a number of issues regarding how Earth science is currently practised, and how this feeds into approaches toward teaching students. The plume model is an hypothesis, not a proven fact. And yet many researchers assume a priori that plumes exist. This assumption feeds into teaching. That the plume model is unproven, and that many practising researchers are skeptical, may be at best only mentioned in passing to students, with most teachers assuming that plumes are proven to exist. There is typically little emphasis, in particular in undergraduate teaching, that the origin of melting anomalies is currently uncertain and that scientists do not know all the answers. Little encouragement is given to students to become involved in the debate and to consider the pros and cons for themselves. Typically teachers take the approach that “an answer” (or even “the answer”) must be taught to students. Such a pedagogic approach misses an excellent opportunity to allow students to participate in an important ongoing debate in Earth sciences. It also misses the opportunity to illustrate to students several critical aspects regarding correct application of the scientific method. The scientific method involves attempting to disprove hypotheses, not to prove them. A priori assumptions should be kept uppermost in mind and reconsidered at all stages. Multiple working hypotheses should be entertained. The predictions of a hypothesis should be tested, and unpredicted observations taken as weakening the original hypothesis. Hypotheses should not be endlessly adapted to fit unexpected observations. The difficulty with pedagogic treatment of the mantle plumes debate highlights a general uncertainty about how to teach issues in Earth science that are not yet resolved with certainty. It also represents a missed opportunity to let students experience how scientific theories evolve, warts

  7. Compositional differentiation of Enceladus' plume

    Science.gov (United States)

    Khawaja, N.; Postberg, F.; Schmidt, J.

    2014-04-01

    The Cosmic Dust Analyser (CDA) on board the Cassini spacecraft sampled Enceladus' plume ice particles emanated directly from Enceladus' fractured south polar terrain (SPT), the so-called "Tiger Stripes", during two consecutive flybys (E17 and E18) in 2012. The spacecraft passed through the dense plume with a moderate velocity of ~7.5km/s, horizontally to the SPT with a closest approach (CA) at an altitude of ~75km almost directly over the south pole. In both flybys, spectra were recorded during a time interval of ~ ±3 minutes with respect to the closest approach achieving an average sampling rate of about 0.6 sec-1. We assume that the spacecraft passed through the plume during an interval of about ±60(sec) from the CA. Particles encountered before and after this period are predominately from the E-ring background in which Enceladus is embedded. Most CDA TOF-mass spectra are identified as one of three compositional types: (i) almost pure water (ii) organic rich and (iii) salt rich [2]. A Boxcar Analysis (BCA) is performed from a count database for compositional mapping of the plume along the space-craft trajectory. In BCA, counts of each spectrum type are integrated for a certain interval of time (box size). The integral of counts represents frequencies of compositional types in absolute abundances, which are converted later into proportions. This technique has been proven to be a suitable for inferring the compositional profiles from an earlier flyby (E5) [1]. The inferred compositional profiles show similar trends on E17 and E18. The abundances of different compositional types in the plume clearly differ from the Ering background and imply a compositional differentiation inside the plume. Following up the work of Schmidt et al, 2008 and Postberg et al, 2011 we can link different compositional types to different origins. The E17/E18 results are compared with the E5 flyby in 2008, which yielded the currently best compositional profile [2] but was executed at much

  8. The EtnaPlumeLab (EPL research cluster: advance the understanding of Mt. Etna plume, from source characterisation to downwind impact

    Directory of Open Access Journals (Sweden)

    Pasquale Sellitto

    2017-01-01

    Full Text Available In 2013, a multidisciplinary research cluster named EtnaPlumeLab (EPL was established, gathering experts from volcanology and atmospheric science communities. Target of EPL is to advance the understanding of Mt. Etna's gas and aerosol emissions and the related processes, from source to its regional climatic impact in the Mediterranean area. Here, we present the cluster and its three interacting modules: EPL-RADIO (Radioactive Aerosols and other source parameters for better atmospheric Dispersion and Impact estimatiOns, SMED (Sulfur MEditerranean Dispersion and Med-SuV (MEDiterranean SUpersite Volcanoes Work Package 5. Preliminary results have for the first time highlighted the relevance of Mt. Etna's plume impact at the Mediterranean regional scale. These results underline that further efforts need to be made to get insight into a synoptic volcanogenic-atmospheric chemistry/climatic understanding of volcanic plumes impact.

  9. Molecular Mechanism of Heterogeneous Catalysis

    Indian Academy of Sciences (India)

    Home; Journals; Resonance – Journal of Science Education; Volume 13; Issue 6. Molecular Mechanism of Heterogeneous Catalysis - The 2007 Nobel Prize in Chemistry. R S Swathi K L Sebastian. General Article Volume 13 Issue 6 June 2008 pp 548-560 ...

  10. Biogeochemistry of landfill leachate plumes

    DEFF Research Database (Denmark)

    Christensen, Thomas Højlund; Kjeldsen, Peter; Bjerg, Poul Løgstrup

    2001-01-01

    the behavior of the contaminants in the plume as the leachate migrates away from the landfill. Diverse microbial communities have been identified in leachate plumes and are believed to be responsible for the redox processes. Dissolved organic C in the leachate, although it appears to be only slowly degradable...... when the volatile organic acids are gone, apparently acts as substrate for the microbial. redox processes. Several xenobiotic organic compounds have been found to be degradable in leachate contaminated groundwater, but degradation rates under anaerobic redox conditions have only been determined...... natural remediation, limiting the effects of the leachate on the groundwater to an area usually not exceeding 1000 m from the landfill. (C) 2001 Elsevier Science Ltd. All rights reserved....

  11. Injection Heights from MISR of Grassland Fire Smoke Plumes in Australia, and Possible Role of Pyroconvection

    Science.gov (United States)

    Mims, S. R.; Kahn, R. A.; Moroney, C. M.; Gaitley, B. J.

    2009-12-01

    Atmospheric models use smoke plume injection heights from wildfires to forecast transport of aerosols and their consequent impact on atmospheric chemistry and climate. We used stereo-height algorithms from the Multi-angle Imaging SpectroRadiometer (MISR) to examine injection heights of grassland fires in the desert regions of western and central Australia. We found that, in about 10 to 30% of the cases studied, the plumes rose above the planetary boundary layer (PBL). These results were unexpected as many climate models assume that smoke from grassfires stays within the PBL. Smoke that gets above the PBL can travel farther and have a greater impact on human health and the climate. Subsequently, we observed smoke plumes in about 60 of nearly 400 MISR orbits above grassland regions in Australia searched during the austral summers in select years between 2000 and 2009. Pyrocumulus clouds were associated with plumes in about 15% of the MISR orbits where grassland fire smoke plumes were observed. In our analyses, we quantified the heights and size of the pyrocumuli and compared them to the heights of the adjacent smoke plumes. In a few instances, smoke alone appeared to rise above the PBL and sometimes as high as nearby pyrocumulus. Pyroconvection could play a role in pushing the smoke from grassfires above the PBL within the free troposphere, and could be an important consideration for climate modelers.

  12. Lead isotope signatures of Kerguelen plume-derived olivine-hosted melt inclusions: Constraints on the ocean island basalt petrogenesis

    Science.gov (United States)

    Borisova, Anastassia Y.; Faure, François; Deloule, Etienne; Grégoire, Michel; Béjina, Frédéric; de Parseval, Philippe; Devidal, Jean-Luc

    2014-06-01

    The nature of magmatic sources reflected by isotopic composition of the ocean island basalt (OIB) remains an on-going question in igneous geochemistry. To constrain the magmatic sources for OIB related to the Kerguelen plume activity, we performed detailed microanalytical investigation of the 21.4 Ma picritic basalt (MD109-D6-87) dredged during the “Marion Dufresne” cruise on a seamount between Kerguelen Archipelago and Heard Island. Lead isotope compositions of olivine-hosted melt inclusions and matrix glasses were measured by Laser Ablation Multiple Collector Inductively Coupled Plasma Mass Spectrometry (LA-MC-ICP-MS) and Secondary Ion Mass Spectrometry (SIMS). We also performed major and trace element microanalyses and mapping of the inclusions and the host olivine phenocrysts by electron microprobe (wavelength-dispersive X-ray spectroscopy, WDS). The observed significant major element (K2O/P2O5, Al2O3/TiO2) and Pb isotope (207Pb/206Pb and 208Pb/206Pb) heterogeneities of parental melts (MgO = 7-10 wt.%) during early high pressure crystallisation stage (200-300 MPa, Fo82-86 mol%), and relative homogeneity at later lower-pressure crystallisation stage (Assimilant” melts during magma residence and transport. Lead isotope composition of the parental basaltic melts was inherited from both heterogeneous mantle and the Kerguelen Plateau crust. High K2O/P2O5 (> 4), Al2O3/TiO2 (> 4) ratios are attributed to assimilation of the plateau basaltic crust (≥ 50 wt.%) by the melts in the magma chamber at palaeodepths from 6 to 9 km. The crustal assimilation may have happened through plagioclase dissolution. The large chemical and isotopic heterogeneity of the parental OIB melts found by in situ microanalyses in this study suggests that the bulk rock chemistry alone cannot provide enough information to constrain the nature of the magmatic sources.

  13. IR sensor design insight from missile-plume prediction models

    Science.gov (United States)

    Rapanotti, John L.; Gilbert, Bruno; Richer, Guy; Stowe, Robert

    2002-08-01

    Modern anti-tank missiles and the requirement of rapid deployment have significantly reduced the use of passive armour in protecting land vehicles. Vehicle survivability is becoming more dependent on sensors, computers and countermeasures to detect and avoid threats. An analysis of missile propellants suggests that missile detection based on plume characteristics alone may be more difficult than anticipated. Currently, the passive detection of missiles depends on signatures with a significant ultraviolet component. This approach is effective in detecting anti-aircraft missiles that rely on powerful motors to pursue high-speed aircraft. The high temperature exhaust from these missiles contains significant levels of carbon dioxide, water and, often, metal oxides such as alumina. The plumes emits strongest in the infrared, 1 to 5micrometers , regions with a significant component of the signature extending into the ultraviolet domain. Many anti-tank missiles do not need the same level of propulsion and radiate significantly less. These low velocity missiles, relying on the destructive force of shaped-charge warhead, are more difficult to detect. There is virtually no ultraviolet component and detection based on UV sensors is impractical. The transition in missile detection from UV to IR is reasonable, based on trends in imaging technology, but from the analysis presented in this paper even IR imagers may have difficulty in detecting missile plumes. This suggests that the emphasis should be placed in the detection of the missile hard body in the longer wavelengths of 8 to 12micrometers . The analysis described in this paper is based on solution of the governing equations of plume physics and chemistry. These models will be used to develop better sensors and threat detection algorithms.

  14. Chemistry Dashboard

    Science.gov (United States)

    The Chemistry Dashboard is part of a suite of dashboards developed by EPA to help evaluate the safety of chemicals. The Chemistry Dashboard provides access to a variety of information on over 700,000 chemicals currently in use.

  15. Combinatorial chemistry

    DEFF Research Database (Denmark)

    Nielsen, John

    1994-01-01

    An overview of combinatorial chemistry is presented. Combinatorial chemistry, sometimes referred to as `irrational drug design,' involves the generation of molecular diversity. The resulting chemical library is then screened for biologically active compounds.......An overview of combinatorial chemistry is presented. Combinatorial chemistry, sometimes referred to as `irrational drug design,' involves the generation of molecular diversity. The resulting chemical library is then screened for biologically active compounds....

  16. Magnetohydrodynamic waves in coronal polar plumes.

    Science.gov (United States)

    Nakariakov, Valery M

    2006-02-15

    Polar plumes are cool, dense, linear, magnetically open structures that arise from predominantly unipolar magnetic footpoints in the solar polar coronal holes. As the Alfvén speed is decreased in plumes in comparison with the surrounding medium, these structures are natural waveguides for fast and slow magnetoacoustic waves. The simplicity of the geometry of polar plumes makes them an ideal test ground for the study of magnetohydrodynamic (MHD) wave interaction with solar coronal structures. The review covers recent observational findings of compressible and incompressible waves in polar plumes with imaging and spectral instruments, and interpretation of the waves in terms of MHD theory.

  17. Propagation of light through ship exhaust plumes

    Science.gov (United States)

    van Iersel, M.; Mack, A.; van Eijk, A. M. J.; Schleijpen, H. M. A.

    2014-10-01

    Looking through the atmosphere, it is sometimes difficult to see the details of an object. Effects like scintillation and blur are the cause of these difficulties. Exhaust plumes of e.g. a ship can cause extreme scintillation and blur, making it even harder to see the details of what lies behind the plume. Exhaust plumes come in different shapes, sizes, and opaqueness and depending on atmospheric parameters like wind speed and direction, as well as engine settings (power, gas or diesel, etc.). A CFD model is used to determine the plume's flow field outside the stack on the basis of exhaust flow properties, the interaction with the superstructure of the ship, the meteorological conditions and the interaction of ship's motion and atmospheric wind fields. A modified version of the NIRATAM code performs the gas radiation calculations and provides the radiant intensity of the (hot) exhaust gases and the transmission of the atmosphere around the plume is modeled with MODTRAN. This allows assessing the irradiance of a sensor positioned at some distance from the ship and its plume, as function of the conditions that influence the spatial distribution and thermal properties of the plume. Furthermore, an assessment can be made of the probability of detecting objects behind the plume. This plume module will be incorporated in the TNO EOSTAR-model, which provides estimates of detection range and image quality of EO-sensors under varying meteorological conditions.

  18. Halogen speciation in volcanic plumes - Development of compact denuder sampling techniques with in-situ derivatization followed by gas chromatography-mass spectrometry and their application at Mt. Etna, Mt. Nyiragongo and Mt. Nyamulagira in 2015.

    Science.gov (United States)

    Rüdiger, Julian; Bobrowski, Nicole; Hoffmann, Thorsten

    2016-04-01

    Volcanoes are a large source for several reactive atmospheric trace gases including sulfur and halogen containing species. The detailed knowledge of volcanic plume chemistry can give insights into subsurface processes and can be considered as a useful geochemical tool for monitoring of volcanic activity, especially halogen to sulfur ratios (e.g. Bobrowski and Giuffrida, 2012; Donovan et al., 2014). The reactive bromine species bromine monoxide (BrO) is of particular interest, because BrO as well as SO2 are readily measurable by UV spectrometer at a safe distance. Furthermore it is formed in the plume by a multiphase reaction mechanism under depletion of ozone in the plume. The abundance of BrO changes as a function of the reaction time and therefore distance from the vent as well as the spatial position in the plume. The precursor substance for the formation of BrO is HBr with Br2as an intermediate product. The reaction of HBr to BrO involves heterogeneous reactions involving aerosol particles, while Br2 reacts directly with O3 to form BrO in a UV radiation induced mechanism. Due to the lack of analytical approaches for the species analysis of halogens (HBr, Br2, Br, BrCl, HOBr) there are still uncertainties about the magnitude of volcanic halogen emissions and in particular their speciation and therefore also in the understanding of the bromine chemistry in volcanic plumes (Bobrowski et al., 2007). In this study a gas diffusion denuder sampling method using a 1,3,5-trimethoxybenzene (1,3,5-TMB) coating for the derivatization of reactive halogen species (Rüdiger et al., 2015) was characterized by reaction chamber experiments. The coating proved to be suitable to collect selectively gaseous bromine species with oxidation states of +1 or 0 (such as Br2, BrCl, BrO(H) and BrONO2), while being ignorant to HBr (OS -1). The reaction of 1,3,5-TMB with reactive bromine species gives 1-bromo-2,4,6-trimethoxybenzene (1-bromo-2,4,6-TMB) - other halogens give corresponding

  19. Is the track of the Yellowstone hotspot driven by a deep mantle plume? -- Review of volcanism, faulting, and uplift in light of new data

    Science.gov (United States)

    Pierce, Kenneth L.; Morgan, Lisa A.

    2009-01-01

    Geophysical imaging of a tilted mantle plume extending at least 500 km beneath the Yellowstone caldera provides compelling support for a plume origin of the entire Yellowstone hotspot track back to its inception at 17 Ma with eruptions of flood basalts and rhyolite. The widespread volcanism, combined with a large volume of buoyant asthenosphere, supports a plume head as an initial phase. Estimates of the diameter of the plume head suggest it completely spanned the upper mantle and was fed from sources beneath the transition zone, We consider a mantle–plume depth to at least 1,000 km to best explain the large scale of features associated with the hotspot track. The Columbia River–Steens flood basalts form a northward-migrating succession consistent with the outward spreading of a plume head beneath the lithosphere. The northern part of the inferred plume head spread (pancaked) upward beneath Mesozoic oceanic crust to produce flood basalts, whereas basalt melt from the southern part intercepted and melted Paleozoic and older crust to produce rhyolite from 17 to 14 Ma. The plume head overlapped the craton margin as defined by strontium isotopes; westward motion of the North American plate has likely "scraped off" the head from the plume tail. Flood basalt chemistries are explained by delamination of the lithosphere where the plume head intersected this cratonic margin. Before reaching the lithosphere, the rising plume head apparently intercepted the east-dipping Juan de Fuca slab and was deflected ~ 250 km to the west; the plume head eventually broke through the slab, leaving an abruptly truncated slab. Westward deflection of the plume head can explain the anomalously rapid hotspot movement of 62 km/m.y. from 17 to 10 Ma, compared to the rate of ~ 25 km/m.y. from 10 to 2 Ma.

  20. Lidar measurements of plume statistics

    DEFF Research Database (Denmark)

    Ejsing Jørgensen, Hans; Mikkelsen, T.

    1993-01-01

    of measured crosswind concentration profiles, the following statistics were obtained: 1) Mean profile, 2) Root mean square profile, 3) Fluctuation intensities,and 4)Intermittency factors. Furthermore, some experimentally determined probability density functions (pdf's) of the fluctuations are presented. All...... the measured statistics are referred to a fixed and a 'moving' frame of reference, the latter being defined as a frame of reference from which the (low frequency) plume meander is removed. Finally, the measured statistics are compared with statistics on concentration fluctuations obtained with a simple puff...

  1. Plume spread and atmospheric stability

    Energy Technology Data Exchange (ETDEWEB)

    Weber, R.O. [Paul Scherrer Inst. (PSI), Villigen (Switzerland)

    1999-08-01

    The horizontal spread of a plume in atmospheric dispersion can be described by the standard deviation of horizontal direction. The widely used Pasquill-Gifford classes of atmospheric stability have assigned typical values of the standard deviation of horizontal wind direction and of the lapse rate. A measured lapse rate can thus be used to estimate the standard deviation of wind direction. It is examined by means of a large dataset of fast wind measurements how good these estimates are. (author) 1 fig., 2 refs.

  2. Characteristics of bubble plumes, bubble-plume bubbles and waves from wind-steepened wave breaking

    NARCIS (Netherlands)

    Leifer, I.; Caulliez, G.; Leeuw, G. de

    2007-01-01

    Observations of breaking waves, associated bubble plumes and bubble-plume size distributions were used to explore the coupled evolution of wave-breaking, wave properties and bubble-plume characteristics. Experiments were made in a large, freshwater, wind-wave channel with mechanical wind-steepened

  3. In situ measurements of HO{sub x} in super- and subsonic aircraft exhaust plumes

    Energy Technology Data Exchange (ETDEWEB)

    Hanisco, T.F.; Wennberg, P.O.; Cohen, R.C.; Anderson, J.G. [Harvard Univ., Cambridge, MA (United States). Dept. of Chemistry; Fahey, D.W.; Keim, E.R.; Gao, R.S.; Wamsley, R.C.; Donnelly, S.G.; Del Negro, L.A. [National Oceanic and Atmospheric Administration, Boulder, CO (United States). Aeronomy Lab.; and others

    1997-12-31

    Concentrations of HO{sub x} (OH and HO{sub 2}) have been obtained in the exhaust plumes of an Air France Concorde and a NASA ER-2 in the lower stratosphere and the NASA DC-8 in the upper troposphere using instruments aboard the NASA ER-2. These fast-time response in situ measurements are used in conjunction with simultaneous in situ measurements of other key exhaust species (NO, NO{sub 2}, NO{sub y}, H{sub 2}O, and CO) to analyze the emissions of HO{sub x} from each aircraft under a variety of conditions. The data are used to establish a general description of gas phase plume chemistry that is easily implemented in a photochemical model. This model is used to determine the amount of HO{sub x} emitted from the engines and the gas phase oxidation rates of nitrogen and sulfur species in the exhaust plumes. (author) 10 refs.

  4. Simulation of plume rise: Study the effect of stably stratified turbulence layer on the rise of a buoyant plume from a continuous source by observing the plume centroid

    Science.gov (United States)

    Bhimireddy, Sudheer Reddy; Bhaganagar, Kiran

    2016-11-01

    Buoyant plumes are common in atmosphere when there exists a difference in temperature or density between the source and its ambience. In a stratified environment, plume rise happens until the buoyancy variation exists between the plume and ambience. In a calm no wind ambience, this plume rise is purely vertical and the entrainment happens because of the relative motion of the plume with ambience and also ambient turbulence. In this study, a plume centroid is defined as the plume mass center and is calculated from the kinematic equation which relates the rate of change of centroids position to the plume rise velocity. Parameters needed to describe the plume are considered as the plume radius, plumes vertical velocity and local buoyancy of the plume. The plume rise velocity is calculated by the mass, momentum and heat conservation equations in their differential form. Our study focuses on the entrainment velocity, as it depicts the extent of plume growth. This entrainment velocity is made up as sum of fractions of plume's relative velocity and ambient turbulence. From the results, we studied the effect of turbulence on the plume growth by observing the variation in the plume radius at different heights and the centroid height reached before loosing its buoyancy.

  5. Advances in electron transfer chemistry

    CERN Document Server

    Mariano, Patrick S

    1993-01-01

    Advances in Electron Transfer Chemistry, Volume 3 presents studies that discuss findings in the various aspects of electron chemistry. The book is comprised of four chapters; each chapter reviews a work that tackles an issue in electron transfer chemistry. Chapter 1 discusses the photoinduced electron transfer in flexible biaryl donor-acceptor molecules. Chapter 2 tackles light-induced electron transfer in inorganic systems in homogeneous and heterogeneous phases. The book also covers internal geometry relaxation effects on electron transfer rates of amino-centered systems. The sequential elec

  6. Skylon Aerodynamics and SABRE Plumes

    Science.gov (United States)

    Mehta, Unmeel; Afosmis, Michael; Bowles, Jeffrey; Pandya, Shishir

    2015-01-01

    An independent partial assessment is provided of the technical viability of the Skylon aerospace plane concept, developed by Reaction Engines Limited (REL). The objectives are to verify REL's engineering estimates of airframe aerodynamics during powered flight and to assess the impact of Synergetic Air-Breathing Rocket Engine (SABRE) plumes on the aft fuselage. Pressure lift and drag coefficients derived from simulations conducted with Euler equations for unpowered flight compare very well with those REL computed with engineering methods. The REL coefficients for powered flight are increasingly less acceptable as the freestream Mach number is increased beyond 8.5, because the engineering estimates did not account for the increasing favorable (in terms of drag and lift coefficients) effect of underexpanded rocket engine plumes on the aft fuselage. At Mach numbers greater than 8.5, the thermal environment around the aft fuselage is a known unknown-a potential design and/or performance risk issue. The adverse effects of shock waves on the aft fuselage and plumeinduced flow separation are other potential risks. The development of an operational reusable launcher from the Skylon concept necessitates the judicious use of a combination of engineering methods, advanced methods based on required physics or analytical fidelity, test data, and independent assessments.

  7. Proceedings of plumes, plates and mineralisation symposium: an introduction

    CSIR Research Space (South Africa)

    Hatton, CJ

    1997-12-01

    Full Text Available of plume-theory. Mechanisms of magma formation are identified and plume positions and distances to their surface expression considered. Mantle plumes are considered as a heat and fluid source for the Witwatersrand gold deposits....

  8. The Alberta smoke plume observation study

    Directory of Open Access Journals (Sweden)

    K. Anderson

    2018-02-01

    Full Text Available A field project was conducted to observe and measure smoke plumes from wildland fires in Alberta. This study used handheld inclinometer measurements and photos taken at lookout towers in the province. Observations of 222 plumes were collected from 21 lookout towers over a 6-year period from 2010 to 2015. Observers reported the equilibrium and maximum plume heights based on the plumes' final levelling heights and the maximum lofting heights, respectively. Observations were tabulated at the end of each year and matched to reported fires. Fire sizes at assessment times and forest fuel types were reported by the province. Fire weather conditions were obtained from the Canadian Wildland Fire Information System (CWFIS. Assessed fire sizes were adjusted to the appropriate size at plume observation time using elliptical fire-growth projections. Though a logical method to collect plume observations in principle, many unanticipated issues were uncovered as the project developed. Instrument limitations and environmental conditions presented challenges to the investigators, whereas human error and the subjectivity of observations affected data quality. Despite these problems, the data set showed that responses to fire behaviour conditions were consistent with the physical processes leading to plume rise. The Alberta smoke plume observation study data can be found on the Canadian Wildland Fire Information System datamart (Natural Resources Canada, 2018 at http://cwfis.cfs.nrcan.gc.ca/datamart.

  9. Ablation plume dynamics in a background gas

    DEFF Research Database (Denmark)

    Amoruso, Salvatore; Schou, Jørgen; Lunney, James G.

    2010-01-01

    the expansion. The model also leads to an insightful treatment of the stopping behavior in dimensionless units for plumes and background gases of different atomic/molecular masses. The energetics of the plume dynamics can also be treated with this model. Experimental time-of-flight data of silver ions in a neon...

  10. Dynamics of fire plumes in verticle shear

    Science.gov (United States)

    Philip Cunningham; Scott L. Goodrick; Hussaini M. Yousuff; Rodman R. Linn; Chunmei Xia

    2003-01-01

    Plumes from wildfires and prescribed fires represent a critical aspect of smoke mangement and aire quality assessment, as as such it is important to understand the structure and dynamics of these plumes, both with respect to a basic understanding of the phenomena and with respect to an assessment of the validity of plumerise parameterizations over a wide variety of...

  11. Infrared Sensing of Buoyant Surface Plumes

    DEFF Research Database (Denmark)

    Petersen, Ole; Larsen, Torben

    1988-01-01

    This paper is concerned with laboratory experiments on buoyant surface plumes where heat is the source of buoyancy. Temperature distributions were measured at the water surface using infra-red sensing, and inside the waterbody a computer based measurement system was applied. The plume is described...

  12. Resolving Heterogeneity

    DEFF Research Database (Denmark)

    Hölzenspies, Jurriaan; Dela Cruz, Gelo Victoriano; M Brickman, Joshua

    2016-01-01

    sets of pluripotency and differentiation markers. It has become increasingly apparent that this transcriptional heterogeneity is an important characteristic of ESC culture. By sorting for specific populations of ESCs it is possible to enrich for cells with a capacity to colonize the embryo proper...

  13. Modelling oil plumes from subsurface spills.

    Science.gov (United States)

    Lardner, Robin; Zodiatis, George

    2017-11-15

    An oil plume model to simulate the behavior of oil from spills located at any given depth below the sea surface is presented, following major modifications to a plume model developed earlier by Malačič (2001) and drawing on ideas in a paper by Yapa and Zheng (1997). The paper presents improvements in those models and numerical testing of the various parameters in the plume model. The plume model described in this paper is one of the numerous modules of the well-established MEDSLIK oil spill model. The deep blowout scenario of the MEDEXPOL 2013 oil spill modelling exercise, organized by REMPEC, has been applied using the improved oil plume module of the MEDSLIK model and inter-comparison with results having the oil spill source at the sea surface are discussed. Copyright © 2017 Elsevier Ltd. All rights reserved.

  14. Galileo observations of volcanic plumes on Io

    Science.gov (United States)

    Geissler, P.E.; McMillan, M.T.

    2008-01-01

    Io's volcanic plumes erupt in a dazzling variety of sizes, shapes, colors and opacities. In general, the plumes fall into two classes, representing distinct source gas temperatures. Most of the Galileo imaging observations were of the smaller, more numerous Prometheus-type plumes that are produced when hot flows of silicate lava impinge on volatile surface ices of SO2. Few detections were made of the giant, Pele-type plumes that vent high temperature, sulfur-rich gases from the interior of Io; this was partly because of the insensitivity of Galileo's camera to ultraviolet wavelengths. Both gas and dust spout from plumes of each class. Favorably located gas plumes were detected during eclipse, when Io was in Jupiter's shadow. Dense dust columns were imaged in daylight above several Prometheus-type eruptions, reaching heights typically less than 100 km. Comparisons between eclipse observations, sunlit images, and the record of surface changes show that these optically thick dust columns are much smaller in stature than the corresponding gas plumes but are adequate to produce the observed surface deposits. Mie scattering calculations suggest that these conspicuous dust plumes are made up of coarse grained “ash” particles with radii on the order of 100 nm, and total masses on the order of 106 kg per plume. Long exposure images of Thor in sunlight show a faint outer envelope apparently populated by particles small enough to be carried along with the gas flow, perhaps formed by condensation of sulfurous “snowflakes” as suggested by the plasma instrumentation aboard Galileo as it flew through Thor's plume [Frank, L.A., Paterson, W.R., 2002. J. Geophys. Res. (Space Phys.) 107, doi:10.1029/2002JA009240. 31-1]. If so, the total mass of these fine, nearly invisible particles may be comparable to the mass of the gas, and could account for much of Io's rapid resurfacing.

  15. Chemistry Technology

    Data.gov (United States)

    Federal Laboratory Consortium — Chemistry technology experts at NCATS engage in a variety of innovative translational research activities, including:Design of bioactive small molecules.Development...

  16. Remote Sensing of Volcanic Clouds: Sulfur Gases and Plume Top Topography

    Science.gov (United States)

    Crisp, Joy A.

    1999-01-01

    New absorption line parameters for H2S were published and submitted to the Gestion et Etude des Informations Spectroscopiques Atmospheriques (GEISA) and high resolution transmission molecular absorption (HITRAN) databases. These new absorption line parameters will make it possible to use observations from the future Tropospheric Emission Spectrometer (TES) instrument [Earth Observing System (EOS) Chemistry Mission (CHEM) platform] to make more accurate H2S measurements if it observes an H2S-rich volcanic cloud. H2S is the second most abundant volcanic sulfur gas, and like SO2, it also converts to H2SO4 aerosols and can have a climate impact. A paper on the Moderate-resolution Imaging-Spectroradiometer (MODIS) SO2 alert is being revised. New aspects in the revision include verification of the SO2 alert during the EOS mission; factors affecting SO2 detection at thermal infrared, ultraviolet, and microwave wavelengths; radiative transfer tests; more description of satellite instruments; and thermal surface alert installed for MODIS. Her research involves the use of remote sensing to generate maps of plume top altitude. This parameter is important for models of volcanic eruption, aircraft hazards, and climate impact. The topographic shape of the top surface of a volcanic plume can provide information necessary to understand the physics controlling the injection and dispersal of a volcanic plume in the atmosphere. Glaze et al. describe the application of a photoclinometric technique to volcanic plumes. The software algorithm has been improved to account for more general plume and illumination geometries and for easily extracting position information directly from Advanced Very High-Resolution Radiometer (AVHRR) level 1B data. Testing of the algorithm has focused on acquiring AVHRR data for a variety of volcanic plumes in an effort to identify problems with the software as well as model sensitivities. The plumes chosen were erupted from volcanoes at a variety of

  17. Combining Deterministic structures and stochastic heterogeneity for transport modeling

    Science.gov (United States)

    Zech, Alraune; Attinger, Sabine; Dietrich, Peter; Teutsch, Georg

    2017-04-01

    Contaminant transport in highly heterogeneous aquifers is extremely challenging and subject of current scientific debate. Tracer plumes often show non-symmetric but highly skewed plume shapes. Predicting such transport behavior using the classical advection-dispersion-equation (ADE) in combination with a stochastic description of aquifer properties requires a dense measurement network. This is in contrast to the available information for most aquifers. A new conceptual aquifer structure model is presented which combines large-scale deterministic information and the stochastic approach for incorporating sub-scale heterogeneity. The conceptual model is designed to allow for a goal-oriented, site specific transport analysis making use of as few data as possible. Thereby the basic idea is to reproduce highly skewed tracer plumes in heterogeneous media by incorporating deterministic contrasts and effects of connectivity instead of using unimodal heterogeneous models with high variances. The conceptual model consists of deterministic blocks of mean hydraulic conductivity which might be measured by pumping tests indicating values differing in orders of magnitudes. A sub-scale heterogeneity is introduced within every block. This heterogeneity can be modeled as bimodal or log-normal distributed. The impact of input parameters, structure and conductivity contrasts is investigated in a systematic manor. Furthermore, some first successful implementation of the model was achieved for the well known MADE site.

  18. Heterogeneous Gossip

    Science.gov (United States)

    Frey, Davide; Guerraoui, Rachid; Kermarrec, Anne-Marie; Koldehofe, Boris; Mogensen, Martin; Monod, Maxime; Quéma, Vivien

    Gossip-based information dissemination protocols are considered easy to deploy, scalable and resilient to network dynamics. Load-balancing is inherent in these protocols as the dissemination work is evenly spread among all nodes. Yet, large-scale distributed systems are usually heterogeneous with respect to network capabilities such as bandwidth. In practice, a blind load-balancing strategy might significantly hamper the performance of the gossip dissemination.

  19. Current organic chemistry

    National Research Council Canada - National Science Library

    1997-01-01

    Provides in depth reviews on current progress in the fields of asymmetric synthesis, organometallic chemistry, bioorganic chemistry, heterocyclic chemistry, natural product chemistry, and analytical...

  20. Area 2: Inexpensive Monitoring and Uncertainty Assessment of CO2 Plume Migration using Injection Data

    Energy Technology Data Exchange (ETDEWEB)

    Srinivasan, Sanjay [Univ. of Texas, Austin, TX (United States)

    2014-09-30

    In-depth understanding of the long-term fate of CO₂ in the subsurface requires study and analysis of the reservoir formation, the overlaying caprock formation, and adjacent faults. Because there is significant uncertainty in predicting the location and extent of geologic heterogeneity that can impact the future migration of CO₂ in the subsurface, there is a need to develop algorithms that can reliably quantify this uncertainty in plume migration. This project is focused on the development of a model selection algorithm that refines an initial suite of subsurface models representing the prior uncertainty to create a posterior set of subsurface models that reflect injection performance consistent with that observed. Such posterior models can be used to represent uncertainty in the future migration of the CO₂ plume. Because only injection data is required, the method provides a very inexpensive method to map the migration of the plume and the associated uncertainty in migration paths. The model selection method developed as part of this project mainly consists of assessing the connectivity/dynamic characteristics of a large prior ensemble of models, grouping the models on the basis of their expected dynamic response, selecting the subgroup of models that most closely yield dynamic response closest to the observed dynamic data, and finally quantifying the uncertainty in plume migration using the selected subset of models. The main accomplishment of the project is the development of a software module within the SGEMS earth modeling software package that implements the model selection methodology. This software module was subsequently applied to analyze CO₂ plume migration in two field projects – the In Salah CO₂ Injection project in Algeria and CO₂ injection into the Utsira formation in Norway. These applications of the software revealed that the proxies developed in this project for quickly assessing the dynamic characteristics of the reservoir were

  1. On the statistical significance of correlations between synthetic mantle plumes and tomographic models

    Science.gov (United States)

    Boschi, L.; Becker, Thorsten W.; Steinberger, Bernhard

    2008-04-01

    In a recent article, [Boschi, L., Becker, T.W., Steinberger, B., 2007. Mantle plumes: dynamic models and seismic images. Geochem. Geophys. Geosyst. 8, Q10006. doi:10.1029/2007GC001733] (BBS07) have re-evaluated the degree to which slow seismic tomography anomalies correlate with the possible locations of plume-like mantle upwellings connected to surface hotspots. They showed that several, but not all, hotspots are likely to have a deep mantle origin. Importantly, they found that when advection of plume conduits in mantle flow is considered, such correlations are significantly higher than when conduits are assumed to be vertical under hotspots. The validity of these statements depends, however, on the definition of statistical significance. BBS07 evaluated the significance of correlation through simple Student's t tests. Anderson (personal communication, July 2007) questioned this approach, given that the true information content of published tomography models is generally unknown, and proposed, instead, to evaluate the significance of correlation by comparing tomographic results with Monte Carlo simulations of randomly located plumes. Following this approach, we show here that the correlation found by BBS07 between advected plumes and slow anomalies in S-velocity tomography is less significant than previously stated, but still significant (at the 99.7% confidence level). We also find an indication that the seismic/geodynamic correlation observed by BBS07 does not only reflect the natural tendency of plumes to cluster in slow/hot regions of the mantle: although realistically advected, and thereby biased towards such regions, our random plumes correlate with slow tomographic anomalies significantly less than the plume models of BBS07. A less significant correlation with plume models characterizes P-velocity tomography; the correlation is, however, enhanced, if flow is computed from tomographic models with amplified heterogeneity, possibly accounting for the known

  2. Radiation from advanced solid rocket motor plumes

    Science.gov (United States)

    Farmer, Richard C.; Smith, Sheldon D.; Myruski, Brian L.

    1994-12-01

    The overall objective of this study was to develop an understanding of solid rocket motor (SRM) plumes in sufficient detail to accurately explain the majority of plume radiation test data. Improved flowfield and radiation analysis codes were developed to accurately and efficiently account for all the factors which effect radiation heating from rocket plumes. These codes were verified by comparing predicted plume behavior with measured NASA/MSFC ASRM test data. Upon conducting a thorough review of the current state-of-the-art of SRM plume flowfield and radiation prediction methodology and the pertinent data base, the following analyses were developed for future design use. The NOZZRAD code was developed for preliminary base heating design and Al2O3 particle optical property data evaluation using a generalized two-flux solution to the radiative transfer equation. The IDARAD code was developed for rapid evaluation of plume radiation effects using the spherical harmonics method of differential approximation to the radiative transfer equation. The FDNS CFD code with fully coupled Euler-Lagrange particle tracking was validated by comparison to predictions made with the industry standard RAMP code for SRM nozzle flowfield analysis. The FDNS code provides the ability to analyze not only rocket nozzle flow, but also axisymmetric and three-dimensional plume flowfields with state-of-the-art CFD methodology. Procedures for conducting meaningful thermo-vision camera studies were developed.

  3. A numerical study of the Magellan Plume

    Science.gov (United States)

    Palma, Elbio D.; Matano, Ricardo P.

    2012-05-01

    In this modeling study we investigate the dynamical mechanisms controlling the spreading of the Magellan Plume, which is a low-salinity tongue that extends along the Patagonian Shelf. Our results indicate that the overall characteristics of the plume (width, depth, spreading rate, etc.) are primarily influenced by tidal forcing, which manifests through tidal mixing and tidal residual currents. Tidal forcing produces a homogenization of the plume's waters and an offshore displacement of its salinity front. The interaction between tidal and wind-forcing reinforces the downstream and upstream buoyancy transports of the plume. The influence of the Malvinas Current on the Magellan Plume is more dominant north of 50°S, where it increases the along-shelf velocities and generates intrusions of saltier waters from the outer shelf, thus causing a reduction of the downstream buoyancy transport. Our experiments also indicate that the northern limit of the Magellan Plume is set by a high salinity discharge from the San Matias Gulf. Sensitivity experiments show that increments of the wind stress cause a decrease of the downstream buoyancy transport and an increase of the upstream buoyancy transport. Variations of the magnitude of the discharge produce substantial modifications in the downstream penetration of the plume and buoyancy transport. The Magellan discharge generates a northeastward current in the middle shelf, a recirculation gyre south of the inlet and a region of weak currents father north.

  4. Sensitivity of air quality simulation to smoke plume rise

    Science.gov (United States)

    Yongqiang Liu; Gary Achtemeier; Scott Goodrick

    2008-01-01

    Plume rise is the height smoke plumes can reach. This information is needed by air quality models such as the Community Multiscale Air Quality (CMAQ) model to simulate physical and chemical processes of point-source fire emissions. This study seeks to understand the importance of plume rise to CMAQ air quality simulation of prescribed burning to plume rise. CMAQ...

  5. Bibliography of Work on the Heterogeneous Photocatalytic Removal of Hazardous Compounds from Water

    Energy Technology Data Exchange (ETDEWEB)

    Blake, D. M.

    1999-07-29

    The subject of this report is chemistry and engineering for the application of heterogeneous photocatalysts. The state of the art in catalysts are forms of titanium dioxide or modifications thereof, but work on other heterogeneous catalysts is included.

  6. Hydroxyl Tagging Velocimetry for Rocket Plumes Project

    Data.gov (United States)

    National Aeronautics and Space Administration — To address the need for non-intrusive sensors for rocket plume properties, we propose a laser-based velocity diagnostic that does not require seeding, works in high...

  7. Plume Diagnostics for Combustion Stability Project

    Data.gov (United States)

    National Aeronautics and Space Administration — Sierra Engineering Inc. and Purdue University propose to develop a non-intrusive plume instrument capable of detecting and diagnosing combustion instability. This...

  8. Novel plume deflection concept testing Project

    Data.gov (United States)

    National Aeronautics and Space Administration — The proposed effort will explore the feasibility and effectiveness of utilizing an electrically driven thermal shield for use as part of rocket plume deflectors. To...

  9. Application of NIR Laser Spectroscopy to the Monitoring of Volcanic Plumes: Principles and Practicalities

    Science.gov (United States)

    Hamish, A.; Christenson, B. W.; Mazot, A.

    2014-12-01

    have solved this problem, and yielded maximum CO2 concentrations along the 730 m pathway in excess of 500 ppm.This approach holds promise for continuous, real-time monitoring of volcanic plume chemistry, and we will now turn our focus to the detection of SO2, HCl and HF plume species.

  10. Near-glacier surveying of a subglacial discharge plume: Implications for plume parameterizations

    Science.gov (United States)

    Jackson, R. H.; Shroyer, E. L.; Nash, J. D.; Sutherland, D. A.; Carroll, D.; Fried, M. J.; Catania, G. A.; Bartholomaus, T. C.; Stearns, L. A.

    2017-07-01

    At tidewater glaciers, plume dynamics affect submarine melting, fjord circulation, and the mixing of meltwater. Models often rely on buoyant plume theory to parameterize plumes and submarine melting; however, these parameterizations are largely untested due to a dearth of near-glacier measurements. Here we present a high-resolution ocean survey by ship and remotely operated boat near the terminus of Kangerlussuup Sermia in west Greenland. These novel observations reveal the 3-D structure and transport of a near-surface plume, originating at a large undercut conduit in the glacier terminus, that is inconsistent with axisymmetric plume theory, the most common representation of plumes in ocean-glacier models. Instead, the observations suggest a wider upwelling plume—a "truncated" line plume of ˜200 m width—with higher entrainment and plume-driven melt compared to the typical axisymmetric representation. Our results highlight the importance of a subglacial outlet's geometry in controlling plume dynamics, with implications for parameterizing the exchange flow and submarine melt in glacial fjord models.

  11. Fire analog: a comparison between fire plumes and energy center cooling tower plumes

    Energy Technology Data Exchange (ETDEWEB)

    Orgill, M.M.

    1977-10-01

    Thermal plumes or convection columns associated with large fires are compared to thermal plumes from cooling towers and proposed energy centers to evaluate the fire analog concept. Energy release rates of mass fires are generally larger than for single or small groups of cooling towers but are comparable to proposed large energy centers. However, significant physical differences exist between cooling tower plumes and fire plumes. Cooling tower plumes are generally dominated by ambient wind, stability and turbulence conditions. Fire plumes, depending on burning rates and other factors, can transform into convective columns which may cause the fire behavior to become more violent. This transformation can cause strong inflow winds and updrafts, turbulence and concentrated vortices. Intense convective columns may interact with ambient winds to create significant downwind effects such as wakes and Karman vortex streets. These characteristics have not been observed with cooling tower plumes to date. The differences in physical characteristics between cooling tower and fire plumes makes the fire analog concept very questionable even though the approximate energy requirements appear to be satisfied in case of large energy centers. Additional research is suggested in studying the upper-level plume characteristics of small experimental fires so this information can be correlated with similar data from cooling towers. Numerical simulation of fires and proposed multiple cooling tower systems could also provide comparative data.

  12. Quantum chemistry

    CERN Document Server

    Lowe, John P

    1993-01-01

    Praised for its appealing writing style and clear pedagogy, Lowe's Quantum Chemistry is now available in its Second Edition as a text for senior undergraduate- and graduate-level chemistry students. The book assumes little mathematical or physical sophistication and emphasizes an understanding of the techniques and results of quantum chemistry, thus enabling students to comprehend much of the current chemical literature in which quantum chemical methods or concepts are used as tools. The book begins with a six-chapter introduction of standard one-dimensional systems, the hydrogen atom,

  13. Diagnostics of laser ablated plasma plumes

    DEFF Research Database (Denmark)

    Amoruso, S.; Toftmann, B.; Schou, Jørgen

    2004-01-01

    The effect of an ambient gas on the expansion dynamics of laser ablated plasmas has been studied for two systems by exploiting different diagnostic techniques. First, the dynamics of a MgB2 laser produced plasma plume in an Ar atmosphere has been investigated by space-and time-resolved optical...... of the laser ablated plasma plume propagation in a background gas. (C) 2003 Elsevier B.V All rights reserved....

  14. Density - Velocity Relationships in Explosive Volcanic Plumes

    Science.gov (United States)

    Fisher, M. A.; Kobs-Nawotniak, S. E.

    2015-12-01

    Positively buoyant volcanic plumes rise until the bulk density of the plume is equal to the density of the ambient atmosphere. As ambient air mixes with the plume, it lowers the plume bulk density; thus, the plume is diluted enough to reach neutral density in a naturally stratified atmospheric environment. We produced scaled plumes in analogue laboratory experiments by injecting a saline solution with a tracer dye into distilled water, using a high-pressure injection system. We recorded each eruption with a CASIO HD digital camera and used ImageJ's FeatureJ Edge toolbox to identify individual eddies. We used an optical flow software based off the ImageJ toolbox FlowJ to determine the velocities along the edge of each eddy. Eddy densities were calculated by mapping the dye concentration to the RGB digital color value. We overlaid the eddy velocities over the densities in order to track the behavioral relationship between the two variables with regard to plume motion. As an eddy's bulk density decreases, the vertical velocity decreases; this is a result of decreased mass, and therefore momentum, in the eddy. Furthermore as the density rate of change increases, the eddy deceleration increases. Eddies are most dense at their top and least dense at their bottom. The less dense sections of the eddies have lower vertical velocities than the sections of the eddies with the higher densities, relating to the expanding radial size of an eddy as it rises and the preferential ingestion of ambient air at the base of eddies. Thus the mixing rate in volcanic plumes fluctuates not only as a function of height as described by the classic 1D entrainment hypothesis, but also as a function of position in an eddy itself.

  15. OPAD data analysis. [Optical Plumes Anomaly Detection

    Science.gov (United States)

    Buntine, Wray L.; Kraft, Richard; Whitaker, Kevin; Cooper, Anita E.; Powers, W. T.; Wallace, Tim L.

    1993-01-01

    Data obtained in the framework of an Optical Plume Anomaly Detection (OPAD) program intended to create a rocket engine health monitor based on spectrometric detections of anomalous atomic and molecular species in the exhaust plume are analyzed. The major results include techniques for handling data noise, methods for registration of spectra to wavelength, and a simple automatic process for estimating the metallic component of a spectrum.

  16. A modeling of buoyant gas plume migration

    Energy Technology Data Exchange (ETDEWEB)

    Silin, D.; Patzek, T.; Benson, S.M.

    2008-12-01

    This work is motivated by the growing interest in injecting carbon dioxide into deep geological formations as a means of avoiding its atmospheric emissions and consequent global warming. Ideally, the injected greenhouse gas stays in the injection zone for a geologic time, eventually dissolves in the formation brine and remains trapped by mineralization. However, one of the potential problems associated with the geologic method of sequestration is that naturally present or inadvertently created conduits in the cap rock may result in a gas leakage from primary storage. Even in a supercritical state, the carbon dioxide viscosity and density are lower than those of the formation brine. Buoyancy tends to drive the leaked CO{sub 2} plume upward. Theoretical and experimental studies of buoyancy-driven supercritical CO{sub 2} flow, including estimation of time scales associated with plume evolution and migration, are critical for developing technology, monitoring policy, and regulations for safe carbon dioxide geologic sequestration. In this study, we obtain simple estimates of vertical plume propagation velocity taking into account the density and viscosity contrast between CO{sub 2} and brine. We describe buoyancy-driven countercurrent flow of two immiscible phases by a Buckley-Leverett type model. The model predicts that a plume of supercritical carbon dioxide in a homogeneous water-saturated porous medium does not migrate upward like a bubble in bulk water. Rather, it spreads upward until it reaches a seal or until it becomes immobile. A simple formula requiring no complex numerical calculations describes the velocity of plume propagation. This solution is a simplification of a more comprehensive theory of countercurrent plume migration (Silin et al., 2007). In a layered reservoir, the simplified solution predicts a slower plume front propagation relative to a homogeneous formation with the same harmonic mean permeability. In contrast, the model yields much higher

  17. Effects of plume afterburning on infrared spectroscopy

    Science.gov (United States)

    Zhu, Xijuan; Xu, Ying; Ma, Jing; Duan, Ran; Wu, Jie

    2017-10-01

    Contains H2, CO and unburned components of high-temperature plume of rocket engine, then injected into the atmosphere, continue to carry out the oxidation reaction in the plume near field region with the volume in the plume of oxygen in the air, two times burning. The afterburning is an important cause of infrared radiation intensification of propellant plume, which increases the temperature of the flame and changes the components of the gas, thus enhancing the infrared radiation intensity of the flame. [1]. Two the combustion numerical using chemical reaction mechanism involving HO2 intermediate reaction, the study confirmed that HO2 is a key intermediate, plays a decisive role to trigger early response, on afterburning temperature and flow concentration distribution effect. A finite rate chemical reaction model is used to describe the two burning phenomenon in high temperature plume[2]. In this paper, a numerical simulation of the flame flow field and radiative transfer is carried out for the afterburning phenomenon. The effects of afterburning on the composition, temperature and infrared radiation of the plume are obtained by comparison.

  18. Plume tectonics – myth or reality?

    Directory of Open Access Journals (Sweden)

    Ю. И. Дараган-Сущов

    2017-03-01

    Full Text Available The paper is dedicated to the role of mantle plumes in the formation of large igneous provinces. From different regions of the world facts are mentioned that contradict key points of plume tectonics. Closer attention is paid to classical volcanic provinces on Hawaiian islands and in Iceland, as well as to Siberian and Deccan Traps, oceanic plateau Ontong Java, Central Atlantic magmatic province, Alfa and Mendeleev Ridges in the Arctic Ocean. A conclusion is drawn that plumes are a special case of mantle-lithospheric flows, which according to deep geophysics are often located horizontally which leaves out their plume origin. Heated masses of mantle substance under young volcanic regions or rift zones of mid-ocean ridges do not emerge from the depth in the form of a straight column, but rather have arbitrary shapes, skewing to the sides and having outgrowths, offshoots, spherical bulges. Vertically rising flows of hot magma (plumes are not a cause, but an effect of a lithospheric split and rise of magmatic substance due to decompression. A conclusion is made that it is unproductive to exaggerate the shapes and sizes of plumes and use them to explain all the diversity of endogenous processes.

  19. Materials Chemistry

    CERN Document Server

    Fahlman, Bradley D

    2011-01-01

    The 2nd edition of Materials Chemistry builds on the strengths that were recognized by a 2008 Textbook Excellence Award from the Text and Academic Authors Association (TAA). Materials Chemistry addresses inorganic-, organic-, and nano-based materials from a structure vs. property treatment, providing a suitable breadth and depth coverage of the rapidly evolving materials field. The 2nd edition continues to offer innovative coverage and practical perspective throughout. After briefly defining materials chemistry and its history, seven chapters discuss solid-state chemistry, metals, semiconducting materials, organic "soft" materials, nanomaterials, and materials characterization. All chapters have been thoroughly updated and expanded with, for example, new sections on ‘soft lithographic’ patterning, ‘click chemistry’ polymerization, nanotoxicity, graphene, as well as many biomaterials applications. The polymer and ‘soft’ materials chapter represents the largest expansion for the 2nd edition. Each ch...

  20. Nuclear Chemistry.

    Science.gov (United States)

    Chemical and Engineering News, 1979

    1979-01-01

    Provides a brief review of the latest developments in nuclear chemistry. Nuclear research today is directed toward increased activity in radiopharmaceuticals and formation of new isotopes by high-energy, heavy-ion collisions. (Author/BB)

  1. Green Chemistry

    Energy Technology Data Exchange (ETDEWEB)

    Collison, Melanie

    2011-05-15

    Green chemistry is the science of chemistry used in a way that will not use or create hazardous substances. Dr. Rui Resendes is working in this field at GreenCentre Canada, an offshoot of PARTEQ Innovations in Kingston, Ontario. GreenCentre's preliminary findings suggest their licensed product {sup S}witchable Solutions{sup ,} featuring 3 classes of solvents and a surfactant, may be useful in bitumen oil sands extraction.

  2. Transverse mixing in three-dimensional nonstationary anisotropic heterogeneous porous media

    DEFF Research Database (Denmark)

    Cirpka, Olaf; Chiogna, Gabriele; Rolle, Massimo

    2015-01-01

    that nonstationary anisotropy in the correlation structure has a significant impact on transverse plume deformation and mixing. In natural sediments, contaminant plumes most likely mix more effectively in the transverse directions than predicted by models that neglect the nonstationarity of anisotropy.......Groundwater plumes originating from continuously emitting sources are typically controlled by transverse mixing between the plume and reactants in the ambient solution. In two-dimensional domains, heterogeneity causes only weak enhancement of transverse mixing in steady-state flows. In three......-dimensional domains, more complex flow patterns are possible because streamlines can twist. In particular, spatially varying orientation of anisotropy can cause steady-state groundwater whirls. We analyze steady-state solute transport in three-dimensional locally isotropic heterogeneous porous media with blockwise...

  3. Selective Oxidation and Ammoxidation of Olefins by Heterogeneous Catalysis.

    Science.gov (United States)

    Grasselli, Robert K.

    1986-01-01

    Shows how the ammoxidation of olefins can be understood in terms of free radicals and surface bound organometallic intermediates. Also illustrates the close intellectual relationships between heterogeneous catalysis and organometallic chemistry. (JN)

  4. Chemistry Division: Annual progress report for period ending March 31, 1987

    Energy Technology Data Exchange (ETDEWEB)

    1987-08-01

    This report is divided into the following sections: coal chemistry; aqueous chemistry at high temperatures and pressures; geochemistry of crustal processes to high temperatures and pressures; chemistry of advanced inorganic materials; structure and dynamics of advanced polymeric materials; chemistry of transuranium elements and compounds; separations chemistry; reactions and catalysis in molten salts; surface science related to heterogeneous catalysis; electron spectroscopy; chemistry related to nuclear waste disposal; computational modeling of security document printing; and special topics. (DLC)

  5. Hubble Captures Volcanic Eruption Plume From Io

    Science.gov (United States)

    1997-01-01

    The Hubble Space Telescope has snapped a picture of a 400-km-high (250-mile-high) plume of gas and dust from a volcanic eruption on Io, Jupiter's large innermost moon.Io was passing in front of Jupiter when this image was taken by the Wide Field and Planetary Camera 2 in July 1996. The plume appears as an orange patch just off the edge of Io in the eight o'clock position, against the blue background of Jupiter's clouds. Io's volcanic eruptions blasts material hundreds of kilometers into space in giant plumes of gas and dust. In this image, material must have been blown out of the volcano at more than 2,000 mph to form a plume of this size, which is the largest yet seen on Io.Until now, these plumes have only been seen by spacecraft near Jupiter, and their detection from the Earth-orbiting Hubble Space Telescope opens up new opportunities for long-term studies of these remarkable phenomena.The plume seen here is from Pele, one of Io's most powerful volcanos. Pele's eruptions have been seen before. In March 1979, the Voyager 1 spacecraft recorded a 300-km-high eruption cloud from Pele. But the volcano was inactive when the Voyager 2 spacecraft flew by Jupiter in July 1979. This Hubble observation is the first glimpse of a Pele eruption plume since the Voyager expeditions.Io's volcanic plumes are much taller than those produced by terrestrial volcanos because of a combination of factors. The moon's thin atmosphere offers no resistance to the expanding volcanic gases; its weak gravity (one-sixth that of Earth) allows material to climb higher before falling; and its biggest volcanos are more powerful than most of Earth's volcanos.This image is a contrast-enhanced composite of an ultraviolet image (2600 Angstrom wavelength), shown in blue, and a violet image (4100 Angstrom wavelength), shown in orange. The orange color probably occurs because of the absorption and/or scattering of ultraviolet light in the plume. This light from Jupiter passes through the plume and is

  6. Pele Plume Deposit on Io

    Science.gov (United States)

    1997-01-01

    The varied effects of Ionian volcanism can be seen in this false color infrared composite image of Io's trailing hemisphere. Low resolution color data from Galileo's first orbit (June, 1996) have been combined with a higher resolution clear filter picture taken on the third orbit (November, 1996) of the spacecraft around Jupiter.A diffuse ring of bright red material encircles Pele, the site of an ongoing, high velocity volcanic eruption. Pele's plume is nearly invisible, except in back-lit photographs, but its deposits indicate energetic ejection of sulfurous materials out to distances more than 600 kilometers from the central vent. Another bright red deposit lies adjacent to Marduk, also a currently active ediface. High temperature hot spots have been detected at both these locations, due to the eruption of molten material in lava flows or lava lakes. Bright red deposits on Io darken and disappear within years or decades of deposition, so the presence of bright red materials marks the sites of recent volcanism.This composite was created from data obtained by the Solid State Imaging (CCD) system aboard NASA's Galileo spacecraft. The region imaged is centered on 15 degrees South, 224 degrees West, and is almost 2400 kilometers across. The finest details that can be discerned in this picture are about 3 kilometers across. North is towards the top of the picture and the sun illuminates the surface from the west.The Jet Propulsion Laboratory, Pasadena, CA manages the mission for NASA's Office of Space Science, Washington, DC.This image and other images and data received from Galileo are posted on the World Wide Web, on the Galileo mission home page at URL http://galileo.jpl.nasa.gov. Background information and educational context for the images can be found at URL http://www.jpl.nasa.gov/galileo/sepo

  7. Microbial populations in contaminant plumes

    Science.gov (United States)

    Haack, Sheridan K.; Bekins, Barbara A.

    Efficient biodegradation of subsurface contaminants requires two elements: (1) microbial populations with the necessary degradative capabilities, and (2) favorable subsurface geochemical and hydrological conditions. Practical constraints on experimental design and interpretation in both the hydrogeological and microbiological sciences have resulted in limited knowledge of the interaction between hydrogeological and microbiological features of subsurface environments. These practical constraints include: (1) inconsistencies between the scales of investigation in the hydrogeological and microbiological sciences, and (2) practical limitations on the ability to accurately define microbial populations in environmental samples. However, advances in application of small-scale sampling methods and interdisciplinary approaches to site investigations are beginning to significantly improve understanding of hydrogeological and microbiological interactions. Likewise, culture-based and molecular analyses of microbial populations in subsurface contaminant plumes have revealed significant adaptation of microbial populations to plume environmental conditions. Results of recent studies suggest that variability in subsurface geochemical and hydrological conditions significantly influences subsurface microbial-community structure. Combined investigations of site conditions and microbial-community structure provide the knowledge needed to understand interactions between subsurface microbial populations, plume geochemistry, and contaminant biodegradation. La biodégradation efficace des polluants souterrains requiert deux éléments: des populations microbiennes possédant les aptitudes nécessaires à la dégradation, et des conditions géochimiques et hydrologiques souterraines favorables. Des contraintes pratiques sur la conception et l'interprétation des expériences à la fois en microbiologie et en hydrogéologie ont conduit à une connaissance limitée des interactions entre les

  8. PlumeSat: A Micro-Satellite Based Plume Imagery Collection Experiment

    Energy Technology Data Exchange (ETDEWEB)

    Ledebuhr, A.G.; Ng, L.C.

    2002-06-30

    This paper describes a technical approach to cost-effectively collect plume imagery of boosting targets using a novel micro-satellite based platform operating in low earth orbit (LEO). The plume collection Micro-satellite or PlueSat for short, will be capable of carrying an array of multi-spectral (UV through LWIR) passive and active (Imaging LADAR) sensors and maneuvering with a lateral divert propulsion system to different observation altitudes (100 to 300 km) and different closing geometries to achieve a range of aspect angles (15 to 60 degrees) in order to simulate a variety of boost phase intercept missions. The PlumeSat will be a cost effective platform to collect boost phase plume imagery from within 1 to 10 km ranges, resulting in 0.1 to 1 meter resolution imagery of a variety of potential target missiles with a goal of demonstrating reliable plume-to-hardbody handover algorithms for future boost phase intercept missions. Once deployed on orbit, the PlumeSat would perform a series phenomenology collection experiments until expends its on-board propellants. The baseline PlumeSat concept is sized to provide from 5 to 7 separate fly by data collects of boosting targets. The total number of data collects will depend on the orbital basing altitude and the accuracy in delivering the boosting target vehicle to the nominal PlumeSat fly-by volume.

  9. Resolving the Mantle Plume Heat Transfer Discrepancy

    Science.gov (United States)

    Hoggard, M.; Parnell-Turner, R. E.; White, N.

    2016-12-01

    Estimates of the buoyancy and heat flux of upwelling mantle plumes are important for understanding many aspects of convection within the Earth. These fluxes influence melt productivity and geochemistry at mid-oceanic spreading centres and hotspots, dynamic topography, mantle mixing timescales and Earth's bulk heat budget. The majority of existing plume flux estimates are calculated from the cross-sectional area of swells multiplied by either plate velocities or spreading rates. Hawaii and the other Pacific hotspots dominate these estimates, which indicate a total heat flux carried by plumes to the base of plates at ˜ 2 TW. Here, we use an alternative approach that calculates buoyancy flux using the swell volume constrained from a new map of dynamic topography, scaled by a characteristic swell decay time. This method avoids the assumption that plume material moves at or below the velocity of the overriding plate. Our results indicate that the Icelandic plume has a buoyancy flux of ˜ 27 ± 4 Mg/s , which is significantly larger than the Hawaiian plume and an order of magnitude greater than some previous estimates. These new values match independent geophysical constraints from Hawaii and the North Atlantic Ocean. All magmatic and amagmatic swells have been included in our global analysis, which reveals a total heat flux carried to the base of the plates of ˜ 10 ± 2 TW. This increased global heat flux is consistent with recent global seismic tomographic images of large upwelling plumes in the mid-mantle and predictions of heat flux through the core-mantle boundary.

  10. Heterogeneous oxidation of pesticides on aerosol condensed phase

    Science.gov (United States)

    Socorro, Joanna; Durand, Amandine; Temime-Roussel, Brice; Ravier, Sylvain; Gligorovski, Sasho; Wortham, Henri; Quivet, Etienne

    2015-04-01

    Pesticides are widely used all over the world. It is known that they exhibit adverse health effects and environmental risks due to their physico-chemical properties and their extensive use which is growing every year. They are distributed in the atmosphere, an important vector of dissemination, over long distances away from the target area. The partitioning of pesticides between the gas and particulate phases influences their atmospheric fate. Most of the pesticides are semi-volatile compounds, emphasizing the importance of assessing their heterogeneous reactivity towards atmospheric oxidants. These reactions are important because they are involved in, among others, direct and indirect climate changes, adverse health effects from inhaled particles, effects on cloud chemistry and ozone production. In this work, the importance of atmospheric degradation of pesticides is evaluated on the surface of aerosol deliquescent particles. The photolysis processing and heterogeneous reactivity towards O3 and OH, was evaluated of eight commonly used pesticides (cyprodinil, deltamethrin, difenoconazole, fipronil, oxadiazon, pendimethalin, permethrin, tetraconazole) adsorbed on silica particles. Silicate particles are present in air-borne mineral dust in atmospheric aerosols, and heterogeneous reactions can be different in the presence of these mineral particles. Depending on their origin and conditioning, aerosol particles containing pesticides can have complex and highly porous microstructures, which are influenced by electric charge effects and interaction with water vapour. Therefore, the kinetic experiments and consecutive product studies were performed at atmospherically relevant relative humidity (RH) of 55 %. The identification of surface bound products was performed using GC-(QqQ)-MS/MS and LC-(Q-ToF)-MS/MS and the gas-phase products were on-line monitored by PTR-ToF-MS. Based on the detected and identified reaction products, it was observed that water plays a crucial

  11. Radiation Chemistry

    Science.gov (United States)

    Wojnárovits, L.

    Ionizing radiation causes chemical changes in the molecules of the interacting medium. The initial molecules change to new molecules, resulting in changes of the physical, chemical, and eventually biological properties of the material. For instance, water decomposes to its elements H2 and O2. In polymers, degradation and crosslinking take place. In biopolymers, e.g., DNS strand breaks and other alterations occur. Such changes are to be avoided in some cases (radiation protection), however, in other cases they are used for technological purposes (radiation processing). This chapter introduces radiation chemistry by discussing the sources of ionizing radiation (radionuclide sources, machine sources), absorption of radiation energy, techniques used in radiation chemistry research, and methods of absorbed energy (absorbed dose) measurements. Radiation chemistry of different classes of inorganic (water and aqueous solutions, inorganic solids, ionic liquids (ILs)) and organic substances (hydrocarbons, halogenated compounds, polymers, and biomolecules) is discussed in concise form together with theoretical and experimental backgrounds. An essential part of the chapter is the introduction of radiation processing technologies in the fields of polymer chemistry, food processing, and sterilization. The application of radiation chemistry to nuclear technology and to protection of environment (flue gas treatment, wastewater treatment) is also discussed.

  12. The hydrothermal outflow plume of Valles Caldera, New Mexico, and a comparison with other outflow plumes

    Science.gov (United States)

    Goff, Fraser; Shevenell, Lisa; Gardner, Jamie N.; Vuataz, Francois-D.; Grigsby, Charles O.

    1988-06-01

    Stratigraphic, temperature gradient, hydrogeochemical, and hydrologic data have been integrated with geologic data from previous studies to show the structural configuration of the Valles caldera hydrothermal ouflow plume. Hydrologic data suggest that 25-50% of the discharge of the Valles outflow is confined to the Jemez fault zone, which predates caldera formation. Thermal gradient data from bores penetrating the plume show that shallow gradients are highest in the vicinity of the Jemez fault zone (up to 190°C/km). Shallow heat flow above the hydrothermal plume is as high as 500 mW m-2 near core hole VC-1 (Jemez fault zone) to 200 mW m-2 at Fenton Hill (Jemez Plateau). Chemical and isotopic data indicate that two source reservoirs within the caldera (Redondo Creek and Sulphur Springs reservoirs) are parents to mixed fluids flowing in the hydrothermal plume. However, isotopic data, borehole data, basic geology, and inverse relations between temperature and chloride content at major hot springs indicate that no single reservoir fluid and no single diluting fluid are involved in mixing. The Valles caldera hydrothermal plume is structurally dominated by lateral flow through a belt of vertical conduits (Jemez fault zone) that strike away from the source reservoir. Stratigraphically confined flow is present but dispersed over a wide area in relatively impermeable rocks. The Valles configuration is contrasted with the configuration of the hydrothermal plume at Roosevelt Hot Springs, which is dominated by lateral flow through a near-surface, widespread, permeable aquifer. Data from 12 other representative geothermal systems show that outflow plumes occur in a variety of magmatic and tectonic settings, have varying reservoir compositions, and have different flow characteristics. Although temperature reversals are commonly observed in wells penetrating outflow plumes, reversals are not observed in all plumes. Less information is available on the absolute age of

  13. Compressible plume dynamics in the transition zone

    Science.gov (United States)

    Bossmann, A. B.; Van Keken, P. E.; Ritsema, J. E.; Goes, S. D.

    2012-12-01

    Plumes rising from the deep mantle may explain hotspot volcanism, but their occurrence in the lower mantle is not unambiguously confirmed by seismological imaging studies. Additionally, the seismologically observed flat topography of the 670 km discontinuity below hotspots disagrees with the elevation expected due to its negative Clapeyron slope and plume excess temperature. Numerical models that account for realistic rheology, compressibility and consistently implemented phase transitions may help reconciling these observations with the mantle plume hypothesis. Here we present numerical mantle plume models in an axisymmetric spherical shell geometry. The Anelastic Liquid Approximation is applied to the governing equations to account for mantle compressibility, viscous dissipation and work done against gravity. Besides this, a depth- and temperature dependent viscosity and the main phase boundaries at 400 and 670 km depth as well as latent heat effects during the phase transitions are considered. The reference state is based on the Birch-Murnaghan equation of state and considers PREM-like density jumps at 400 and 670 km depth and latent heat effects in the temperature profile. We include a dense layer above the core-mantle boundary from which the plume rises. Plume dynamics and morphology is studied for varying Clapeyron slope, especially at the endothermic phase transition, Rayleigh number and different viscosity models. We evaluate the importance of consistently implementing latent heat in the governing equations and reference state. Furthermore we vary excess density and thickness of the dense layer to study the effects on entrainment of the layer and the dynamics in the transition zone. Our models show that the seismologically observed flat topography of the 670 km phase boundary is consistent with a plume origin in the deep mantle and offer an additional explanation independent of previously proposed ones, as we observe a large plume head in the lower mantle

  14. CALIOP-derived Smoke Plume Injection Height

    Science.gov (United States)

    Soja, A. J.; Winker, D. M.; Choi, H. D.; Fairlie, T. D.; Westberg, D. J.; Roller, C. M.; Pouliot, G.; Vaughan, M.; Pierce, T. E.; Trepte, C. R.; Rao, V.

    2014-12-01

    Biomass burning is a dominant natural and anthropogenic disturbance that feeds back to the climate system. Fire regimes, ecosystem fuels, fire severity and intensity vary widely, even within the same system, largely under the control of weather and climate. These strongly influence fire plume injection height and thus the transport of related biomass burning emissions, affecting air quality, human health and the climate system. If our knowledge of plume injection height is incorrect, transport models of those emissions will likewise be incorrect, adversely affecting our ability to analyze and predict climate feedbacks (i.e. black carbon to the Arctic, precipitation, cloud-radiation relationships) and public health (air quality forecast). Historically, plume height was based on the pioneering work of G.A. Briggs [1969; 1971] and verified with limited field campaigns. However, we currently have two satellite instruments, Cloud-Aerosol LIdar with Orthogonal Polarization (CALIOP) onboard CALIPSO (afternoon overpass) and Multi-angle Imaging SpectroRadiometer (MISR) onboard TERRA (morning overpass), that can provide the statistics necessary to verify our assumptions and improve fire plume injection height estimates for use in both small- and large-scale models. We have developed a methodology to assess fire plume injection height using the Langley Trajectory Model (LaTM), CALIOP, Hazard Mapping System (HMS) smoke plume, and MODerate Resolution Imaging Spectrometer (MODIS) thermal anomaly data that is capable of generating two distinct types of verification data. A single CALIOP smoke-filled aerosol envelop can be traced back to numerous fire events, and using multiple CALIOP transects from numerous days, a daily smoke plume injection height evolution from a single fire can be defined. Additionally, we have linked the smoke plumes to ecosystems and the meteorological variables that define fire weather. In concert, CALIOP and MISR data can produce the statistical knowledge

  15. Cobalt-chitosan: Magnetic and biodegradable heterogeneous ...

    Indian Academy of Sciences (India)

    Cobalt; chitosan; heterogeneous catalyst; magnetism; aerobic oxidation; alkyl arene. 1. Introduction. The selective oxidation of alkyl arenes and alcohols into the corresponding carbonyl compounds is an impor- tant goal in synthesis of fine chemicals.1 From green chemistry point of view, improving methods for oxida-.

  16. Mapping Pollution Plumes in Areas Impacted by Hurricane Katrina With Imaging Spectroscopy

    Science.gov (United States)

    Swayze, G. A.; Furlong, E. T.; Livo, K. E.

    2007-12-01

    New Orleans endured flooding on a massive scale subsequent to Hurricane Katrina in August of 2005. Contaminant plumes were noticeable in satellite images of the city in the days following flooding. Many of these plumes were caused by oil, gasoline, and diesel that leaked from inundated vehicles, gas stations, and refineries. News reports also suggested that the flood waters were contaminated with sewage from breached pipes. Effluent plumes such as these pose a potential health hazard to humans and wildlife in the aftermath of hurricanes and potentially from other catastrophic events (e.g., earthquakes, shipping accidents, chemical spills, and terrorist attacks). While the extent of effluent plumes can be gauged with synthetic aperture radar and broad- band visible-infrared images (Rykhus, 2005) (e.g., Radarsat and Landsat ETM+) the composition of the plumes could not be determined. These instruments lack the spectral resolution necessary to do chemical identification. Imaging spectroscopy may help solve this problem. Over 60 flight lines of NASA Airborne Visible/Infrared Imaging Spectrometer (AVIRIS) data were collected over New Orleans, the Mississippi Delta, and the Gulf Coast from one to two weeks after Katrina while the contaminated water was being pumped out of flooded areas. These data provide a unique opportunity to test if imaging spectrometer data can be used to identify the chemistry of these flood-related plumes. Many chemicals have unique spectral signatures in the ultraviolet to near-infrared range (0.2 - 2.5 microns) that can be used as fingerprints for their identification. We are particularly interested in detecting thin films of oil, gasoline, diesel, and raw sewage suspended on or in water. If these materials can be successfully differentiated in the lab then we will use spectral-shape matching algorithms to look for their spectral signatures in the AVIRIS data collected over New Orleans and other areas impacted by Katrina. If imaging spectroscopy

  17. Reconnaissance of gas plumes offshore Sado Island

    Science.gov (United States)

    Fukuoka, H.; Aoyama, C.; Watanabe, H.; Komatsu, H.; Tajima, H.

    2016-12-01

    In late March 2016, an exploration of gas plume offshore Sado Island was conducted to know about their distribution, especially from shallow sea floor of 150 - 400 m. In the Japan Sea, more than thousand of gas plumes had been found in the recent 3 years. Most of them are supposed to be originated from dissolution of submarine methane hydrate on the sea floor surface and/or shallow subsurface. Comparison of the plumes and flux observed by multi-beam sonar and fish-finder record between 2016 and 2013 shows that both of the distribution and the gas flux, evaluated from intensity in echogram has changed. Sub-bottom scanner imagery suggest that the apparently sub-surface gas-chimney-like structure was observed at as many sites. Unlike large-scale seafloor surface type methane-hydrate site, those subsurface chimney did not reach the seafloor, possibly because the temperature-pressure condition was not satisfied on the surface. Authors have sampled sea water near the vent of those plume gas, depressurized to extract dissolved air bubbles, which was subjected to chemical analysis. Atmospheres around above large-scale plume which looks reaching to the sea surface was collected and analyzed. Results show that the air collected from the seafloor near the vent contains slightly higher concentration of methane (CH4) and carbon dioxide (CO2).

  18. Heterogeneous catalysis: on bathroom mirrors and boiling stones

    NARCIS (Netherlands)

    Philipse, A.P.|info:eu-repo/dai/nl/073532894

    2011-01-01

    A catalyst is defined as a substance that accelerates a process without undergoing a net change due to that process. Most chemistry students learn about catalysts in the context of chemical reactions, such as the enzymes in biochemistry or the heterogeneous metal catalysts in inorganic chemistry (1,

  19. The 2016 Case for Mantle Plumes and a Plume-Fed Asthenosphere (Augustus Love Medal Lecture)

    Science.gov (United States)

    Morgan, Jason P.

    2016-04-01

    The process of science always returns to weighing evidence and arguments for and against a given hypothesis. As hypotheses can only be falsified, never universally proved, doubt and skepticism remain essential elements of the scientific method. In the past decade, even the hypothesis that mantle plumes exist as upwelling currents in the convecting mantle has been subject to intense scrutiny; from geochemists and geochronologists concerned that idealized plume models could not fit many details of their observations, and from seismologists concerned that mantle plumes can sometimes not be 'seen' in their increasingly high-resolution tomographic images of the mantle. In the place of mantle plumes, various locally specific and largely non-predictive hypotheses have been proposed to explain the origins of non-plate boundary volcanism at Hawaii, Samoa, etc. In my opinion, this debate has now passed from what was initially an extremely useful restorative from simply 'believing' in the idealized conventional mantle plume/hotspot scenario to becoming an active impediment to our community's ability to better understand the dynamics of the solid Earth. Having no working hypothesis at all is usually worse for making progress than having an imperfect and incomplete but partially correct one. There continues to be strong arguments and strong emerging evidence for deep mantle plumes. Furthermore, deep thermal plumes should exist in a mantle that is heated at its base, and the existence of Earth's (convective) geodynamo clearly indicates that heat flows from the core to heat the mantle's base. Here I review recent seismic evidence by French, Romanowicz, and coworkers that I feel lends strong new observational support for the existence of deep mantle plumes. I also review recent evidence consistent with the idea that secular core cooling replenishes half the mantle's heat loss through its top surface, e.g. that the present-day mantle is strongly bottom heated. Causes for

  20. Background Radiance Estimation for Gas Plume Quantification for Airborne Hyperspectral Thermal Imaging

    Directory of Open Access Journals (Sweden)

    Ramzi Idoughi

    2016-01-01

    Full Text Available Hyperspectral imaging in the long-wave infrared (LWIR is a mean that is proving its worth in the characterization of gaseous effluent. Indeed the spectral and spatial resolution of acquisition instruments is steadily decreasing, making the gases characterization increasingly easy in the LWIR domain. The majority of literature algorithms exploit the plume contribution to the radiance corresponding to the difference of radiance between the plume-present and plume-absent pixels. Nevertheless, the off-plume radiance is unobservable using a single image. In this paper, we propose a new method to retrieve trace gas concentration from airborne infrared hyperspectral data. More particularly the outlined method improves the existing background radiance estimation approach to deal with heterogeneous scenes corresponding to industrial scenes. It consists in performing a classification of the scene and then applying a principal components analysis based method to estimate the background radiance on each cluster stemming from the classification. In order to determine the contribution of the classification to the background radiance estimation, we compared the two approaches on synthetic data and Telops Fourier Transform Spectrometer (FTS Imaging Hyper-Cam LW airborne acquisition above ethylene release. We finally show ethylene retrieved concentration map and estimate flow rate of the ethylene release.

  1. Solute plumes mean velocity in aquifer transport: Impact of injection and detection modes

    Science.gov (United States)

    Dagan, Gedeon

    2017-08-01

    Flow of mean velocity U takes place in a heterogeneous aquifer of random spatially variable conductivity K. A solute plume is injected instantaneously along a plane normal to U, over a large area relative to the logconductivity integral scale I (ergodic plume). Transport is by advection by the spatially variable Eulerian velocity. The study is focused on the derivation of the mean plume velocity in the four modes set forth by Kreft and Zuber [1978] for one dimensional flow in a homogeneous medium. In the resident injection mode the mass is initially distributed uniformly in space while in the flux mode it is proportional to the local velocity. In the resident detection mode the mean velocity pertains to the plume centroid, whereas in flux detection it is quantified with the aid of the BTC and the corresponding mean arrival time. In agreement with the literature, it is shown that URR and UFF, pertaining to same injection and detection modes, either resident or flux, are equal to U. In contrast, in the mixed modes the solute velocity may differ significantly from U near the injection plane, approaching it at large distances relative to I. These effects are explained qualitatively with the aid of the exact solution for stratified aquifers.

  2. Polymer Chemistry

    Science.gov (United States)

    Williams, Martha; Roberson, Luke; Caraccio, Anne

    2010-01-01

    This viewgraph presentation describes new technologies in polymer and material chemistry that benefits NASA programs and missions. The topics include: 1) What are Polymers?; 2) History of Polymer Chemistry; 3) Composites/Materials Development at KSC; 4) Why Wiring; 5) Next Generation Wiring Materials; 6) Wire System Materials and Integration; 7) Self-Healing Wire Repair; 8) Smart Wiring Summary; 9) Fire and Polymers; 10) Aerogel Technology; 11) Aerogel Composites; 12) Aerogels for Oil Remediation; 13) KSC's Solution; 14) Chemochromic Hydrogen Sensors; 15) STS-130 and 131 Operations; 16) HyperPigment; 17) Antimicrobial Materials; 18) Conductive Inks Formulations for Multiple Applications; and 19) Testing and Processing Equipment.

  3. Importance of tropospheric ClNO2 chemistry across the Northern Hemisphere

    Science.gov (United States)

    Laboratory and field experiments have revealed that the heterogeneous hydrolysis of dinitrogen pentoxide produces nitryl chloride and nitric acid in the presence of particulate chloride. We incorporate the heterogeneous chemistry of nitryl chloride into the hemispheric Community ...

  4. Food carbohydrate chemistry

    National Research Council Canada - National Science Library

    Wrolstad, R. E

    2012-01-01

    .... Now in Food Carbohydrate Chemistry, author Wrolstad emphasizes the application of carbohydrate chemistry to understanding the chemistry, physical and functional properties of food carbohydrates...

  5. A new way to detect volcanic plumes

    Science.gov (United States)

    Larson, Kristine M.

    2013-06-01

    of volcanic plumes, especially ash-laden ones, is important both for public health and aircraft safety. A variety of geophysical tools and satellite data are used to monitor volcanic eruptions and to predict the movement of ash. However, satellite-based methods are restricted by time of day and weather, while radars are often unavailable because of cost/portability. Here a method is proposed to detect volcanic plumes using GPS signal strength data. The strengths and limitations of the method are assessed using GPS data collected during the 2008 and 2009 eruptions of the Okmok and Mt. Redoubt volcanoes. Plume detections using this GPS technique are consistent with independently collected seismic and radar data.

  6. Numerical and approximate solutions for plume rise

    Science.gov (United States)

    Krishnamurthy, Ramesh; Gordon Hall, J.

    Numerical and approximate analytical solutions are compared for turbulent plume rise in a crosswind. The numerical solutions were calculated using the plume rise model of Hoult, Fay and Forney (1969, J. Air Pollut. Control Ass.19, 585-590), over a wide range of pertinent parameters. Some wind shear and elevated inversion effects are included. The numerical solutions are seen to agree with the approximate solutions over a fairly wide range of the parameters. For the conditions considered in the study, wind shear effects are seen to be quite small. A limited study was made of the penetration of elevated inversions by plumes. The results indicate the adequacy of a simple criterion proposed by Briggs (1969, AEC Critical Review Series, USAEC Division of Technical Information extension, Oak Ridge, Tennesse).

  7. Properties of industrial dense gas plumes

    Science.gov (United States)

    Shaver, E. M.; Forney, L. J.

    Hazardous gases and vapors are often discharged into the atmosphere from industrial plants during catastrophic events (e.g. Union Carbide incident in Bhopal, India). In many cases the discharged components are more dense than air and settle to the ground surface downstream from the stack exit. In the present paper, the buoyant plume model of Hoult, Fay and Forney (1969, J. Air Pollut. Control Ass. 19, 585-590.) has been altered to predict the properties of hazardous discharges. In particular, the plume impingement point, radius and concentration are predicted for typical stack exit conditions, wind speeds and temperature profiles. Asymptotic expressions for plume properties at the impingement point are also derived for a constant crosswind and neutral temperature profile. These formulae are shown to be useful for all conditions.

  8. A collisionless plasma thruster plume expansion model

    Science.gov (United States)

    Merino, Mario; Cichocki, Filippo; Ahedo, Eduardo

    2015-06-01

    A two-fluid model of the unmagnetized, collisionless far region expansion of the plasma plume for gridded ion thrusters and Hall effect thrusters is presented. The model is integrated into two semi-analytical solutions valid in the hypersonic case. These solutions are discussed and compared against the results from the (exact) method of characteristics; the relative errors in density and velocity increase slowly axially and radially and are of the order of 10-2-10-3 in the cases studied. The plasma density, ion flux and ambipolar electric field are investigated. A sensitivity analysis of the problem parameters and initial conditions is carried out in order to characterize the far plume divergence angle in the range of interest for space electric propulsion. A qualitative discussion of the physics of the secondary plasma plume is also provided.

  9. Enceladus Plumes: A Boiling Liquid Model

    Science.gov (United States)

    Nakajima, Miki; Ingersoll, A. P.

    2012-10-01

    Following the discovery of H2O vapor and particle plumes from the tiger stripes at the south pole of Enceladus (Porco et al., 2006), observational and theoretical studies have been conducted to understand the plume mechanism (e.g., Schmidt et al., 2008; Kieffer et al., 2009; Ingersoll and Pankine, 2010). Although the “Ice Chamber Model”, which assumes that ice sublimation under the stripes causes the plumes, has successfully explained the plume mass flux (e.g., Nimmo et al., 2007; Ingersoll and Pankine, 2010), it cannot explain the high salinity in the plume (Postberg et al., 2009). Ice particles condensing from a vapor are relatively salt free, but ice particles derived from a salty liquid can have high salinity. Therefore we have investigated the “Boiling Liquid Model”, which assumes that liquid H2O under the stripes causes the plumes. With conservation of mass, momentum and energy, we built a simple atmospheric model that includes controlled boiling and gas-ice wall interaction. We first assumed that the heat radiated to space comes entirely from the heat generated by condensation of the gas onto the ice wall. We varied the width (0.1-1 m) and the height (5-4000 m) of the crack as parameters. We find that the escaping vapor flux can be relatively close to the observed value (250±100 kg/s, Hansen et al., 2006, 2008) but the radiated heat flux is only 1 GW, which is much less than the observed value (15.8 GW, Howett et al., 2011). Other models (Nimmo et al., 2007; Abramov and Spencer, 2009) also have the same difficulty accounting for the observed value. We then investigated the additional heat radiated by the particles after they come out of the crack. We built a simple model to estimate the size distributions of these condensed ice particles and their radiative properties.

  10. Real-Time Monitoring of Heterogeneous Catalysis with Mass Spectrometry

    Science.gov (United States)

    Young, Mark A.

    2009-01-01

    Heterogeneous, gas-solid processes constitute an important class of catalytic reactions that play a key role in a variety of applications, such as industrial processing and environmental controls. Heterogeneous catalytic chemistry can be demonstrated in a simple heated flow reactor containing a fragment of the catalytic converter from a vehicular…

  11. Confectionary Chemistry.

    Science.gov (United States)

    Levine, Elise Hilf

    1996-01-01

    Presents activities and demonstrations that enable teachers to use various types of confections as tactile experiences to spark chemistry students' interest and generate enthusiasm for learning. Presents uses of candy in teaching about atomic structure, spontaneous nuclear decay, chemical formulas, fractoluminescence, the effect of a molecular…

  12. Chemistry Notes.

    Science.gov (United States)

    School Science Review, 1983

    1983-01-01

    Presents chemistry experiments, laboratory procedures, demonstrations, and classroom materials/activities. These include: experiments on colloids, processing of uranium ore, action of heat on carbonates; color test for phenols and aromatic amines; solvent properties of non-electrolytes; stereoscopic applications/methods; a valency balance;…

  13. Infrared measurements of launch vehicle exhaust plumes

    Science.gov (United States)

    Schweitzer, Caroline; Ohmer, Phillip; Wendelstein, Norbert; Stein, Karin

    2017-10-01

    In the fields of early warning, one is depending on reliable analytical models for the prediction of the infrared threat signature: By having this as a basis, the warning sensors can be specified as suitable as possible to give timely threat approach alerts. In this paper, we will present preliminary results of measurement trials that have been carried out in 2015, where the exhaust plume of launch vehicles has been measured under various atmospheric conditions. The gathered data will be used to validate analytical models for the prediction of the plume signature.

  14. Scaling for turbulent viscosity of buoyant plumes in stratified fluids: PIV measurement with implications for submarine hydrothermal plume turbulence

    Science.gov (United States)

    Zhang, Wei; He, Zhiguo; Jiang, Houshuo

    2017-11-01

    Time-resolved particle image velocimetry (PIV) has been used to measure instantaneous two-dimensional velocity vector fields of laboratory-generated turbulent buoyant plumes in linearly stratified saltwater over extended periods of time. From PIV-measured time-series flow data, characteristics of plume mean flow and turbulence have been quantified. To be specific, maximum plume penetration scaling and entrainment coefficient determined from the mean flow agree well with the theory based on the entrainment hypothesis for buoyant plumes in stratified fluids. Besides the well-known persistent entrainment along the plume stem (i.e., the 'plume-stem' entrainment), the mean plume velocity field shows persistent entrainment along the outer edge of the plume cap (i.e., the 'plume-cap' entrainment), thereby confirming predictions from previous numerical simulation studies. To our knowledge, the present PIV investigation provides the first measured flow field data in the plume cap region. As to measured plume turbulence, both the turbulent kinetic energy field and the turbulence dissipation rate field attain their maximum close to the source, while the turbulent viscosity field reaches its maximum within the plume cap region; the results also show that maximum turbulent viscosity scales as νt,max = 0.030(B/N)1/2, where B is source buoyancy flux and N is ambient buoyancy frequency. These PIV data combined with previously published numerical simulation results have implications for understanding the roles of hydrothermal plume turbulence, i.e. plume turbulence within the cap region causes the 'plume-cap' entrainment that plays an equally important role as the 'plume-stem' entrainment in supplying the final volume flux at the plume spreading level.

  15. In situ measurements and modeling of reactive trace gases in a small biomass burning plume

    Directory of Open Access Journals (Sweden)

    M. Müller

    2016-03-01

    Full Text Available An instrumented NASA P-3B aircraft was used for airborne sampling of trace gases in a plume that had emanated from a small forest understory fire in Georgia, USA. The plume was sampled at its origin to derive emission factors and followed  ∼ 13.6 km downwind to observe chemical changes during the first hour of atmospheric aging. The P-3B payload included a proton-transfer-reaction time-of-flight mass spectrometer (PTR-ToF-MS, which measured non-methane organic gases (NMOGs at unprecedented spatiotemporal resolution (10 m spatial/0.1 s temporal. Quantitative emission data are reported for CO2, CO, NO, NO2, HONO, NH3, and 16 NMOGs (formaldehyde, methanol, acetonitrile, propene, acetaldehyde, formic acid, acetone plus its isomer propanal, acetic acid plus its isomer glycolaldehyde, furan, isoprene plus isomeric pentadienes and cyclopentene, methyl vinyl ketone plus its isomers crotonaldehyde and methacrolein, methylglyoxal, hydroxy acetone plus its isomers methyl acetate and propionic acid, benzene, 2,3-butanedione, and 2-furfural with molar emission ratios relative to CO larger than 1 ppbV ppmV−1. Formaldehyde, acetaldehyde, 2-furfural, and methanol dominated NMOG emissions. No NMOGs with more than 10 carbon atoms were observed at mixing ratios larger than 50 pptV ppmV−1 CO. Downwind plume chemistry was investigated using the observations and a 0-D photochemical box model simulation. The model was run on a nearly explicit chemical mechanism (MCM v3.3 and initialized with measured emission data. Ozone formation during the first hour of atmospheric aging was well captured by the model, with carbonyls (formaldehyde, acetaldehyde, 2,3-butanedione, methylglyoxal, 2-furfural in addition to CO and CH4 being the main drivers of peroxy radical chemistry. The model also accurately reproduced the sequestration of NOx into peroxyacetyl nitrate (PAN and the OH-initiated degradation of furan and 2-furfural at an average OH concentration of 7.45 ± 1

  16. Tracking Iceland Plume Motion Using Trace Element Geochemistry

    Science.gov (United States)

    Fitton, J. G.; Walters, R. L.; Jones, S. M.

    2011-12-01

    The Greenland-Scotland Ridge (GSR) is a hotspot track built by interaction between the Mid Atlantic Ridge (MAR) and the Iceland mantle plume. Unlike most other hotspot tracks built by ridge-plume interaction, the GSR is 2 to 3 times wider than the plume conduit in the upper mantle. (This unusual wide morphology arises because Icelandic crust changes significantly in thickness within a few million years of accretion, probably mainly by viscous flow in the hot lower crust). The upshot is that the GSR cannot be compared directly with theoretical plume tracks from hotspot reference frame models. However, it is possible to track the position of the Iceland plume conduit using the trace element geochemistry of basaltic lavas. Away from the plume conduit, plate spreading drives upwelling of mantle through the melting region. Above the plume conduit, plume-driven flow forces mantle through the lower part of the melting region faster than the plate-driven upwelling rate. The average depth of melting is therefore greater directly above the plume conduit than away from the plume conduit, and this difference in average melting depth means that melts generated directly above the plume conduit are relatively enriched in incompatible trace elements. Joint modelling of trace element compositions and crustal thickness can also be used to establish location of melting relative to the plume conduit. To date, these concepts have been used only to explain compositional variations in modern (post-glacial) Icelandic lavas; in this study we show that the same concepts can be applied to map the location of the plume conduit throughout the onshore Icelandic geological record (since the middle Miocene, c. 16 Ma). The plume track thus determined is in reasonable agreement with theoretical tracks calculated under the assumption that the Iceland Plume has remained fixed relative to other Indo-Atlantic hotspots. This result also supports the idea that episodic relocations of the onshore part of

  17. Characterization of redox conditions in groundwater contaminant plumes

    DEFF Research Database (Denmark)

    Christensen, Thomas Højlund; Bjerg, Poul Løgstrup; Banwarth, Steven A.

    2000-01-01

    Evaluation of redox conditions in groundwater pollution plumes is often a prerequisite for understanding the behaviour of the pollutants in the plume and for selecting remediation approaches. Measuring of redox conditions in pollution plumes is, however, a fairly recent issue and yet relative few...... dubious, if not erroneous. Several other approaches have been used in addressing redox conditions in pollution plumes: redox-sensitive compounds in groundwater samples, hydrogen concentrations in groundwater, concentrations of volatile fatty acids in groundwater, sediment characteristics and microbial...

  18. Merging Thermal Plumes in the Indoor Environment

    DEFF Research Database (Denmark)

    Bjørn, Erik; Nielsen, Peter V.

    This experimental work deals with the basic problem of merging thermal plumes from heat sources situated in the vicinity of each other. No studies have been made yet of how close two heat sources must be to each other, before they can be considered as a single source with a cumulative heat effect...

  19. Near field characteristics of buoyant helium plumes

    Indian Academy of Sciences (India)

    affects the combustion. Puffing is also observed in low density gas plumes when the ratio of inlet ... generated using helium and helium–air mixtures, hot gases were used to understand the flow dynamics associated .... The glass lens acts as a filter to block any UV light and prevents fluorescence signal contamination. Since.

  20. Near field characteristics of buoyant helium plumes

    Indian Academy of Sciences (India)

    ... Lecture Workshops · Refresher Courses · Symposia · Live Streaming. Home; Journals; Sadhana; Volume 40; Issue 3. Near field characteristics of buoyant helium plumes. Kuchimanchi K Bharadwaj Debopam Das Pavan K Sharma. Section I – Fluid Mechanics and Fluid Power (FMFP) Volume 40 Issue 3 May 2015 pp 757- ...

  1. Characterization and Modeling of Plumes and Animal Plume-Tracing in Wave-Influenced Coastal Environments

    National Research Council Canada - National Science Library

    Koseff, Jeffrey

    2002-01-01

    .... ensigera in unidirectional and wave-influenced flow environments, and correlated tracing maneuvers with the simultaneously-recorded characteristics of the odor plume at the position of the animals' olfactory antennules...

  2. Representative Atmospheric Plume Development for Elevated Releases

    Energy Technology Data Exchange (ETDEWEB)

    Eslinger, Paul W. [Pacific Northwest National Lab. (PNNL), Richland, WA (United States); Lowrey, Justin D. [Pacific Northwest National Lab. (PNNL), Richland, WA (United States); McIntyre, Justin I. [Pacific Northwest National Lab. (PNNL), Richland, WA (United States); Miley, Harry S. [Pacific Northwest National Lab. (PNNL), Richland, WA (United States); Prichard, Andrew W. [Pacific Northwest National Lab. (PNNL), Richland, WA (United States)

    2014-02-01

    An atmospheric explosion of a low-yield nuclear device will produce a large number of radioactive isotopes, some of which can be measured with airborne detection systems. However, properly equipped aircraft may not arrive in the region where an explosion occurred for a number of hours after the event. Atmospheric conditions will have caused the radioactive plume to move and diffuse before the aircraft arrives. The science behind predicting atmospheric plume movement has advanced enough that the location of the maximum concentrations in the plume can be determined reasonably accurately in real time, or near real time. Given the assumption that an aircraft can follow a plume, this study addresses the amount of atmospheric dilution expected to occur in a representative plume as a function of time past the release event. The approach models atmospheric transport of hypothetical releases from a single location for every day in a year using the publically available HYSPLIT code. The effective dilution factors for the point of maximum concentration in an elevated plume based on a release of a non-decaying, non-depositing tracer can vary by orders of magnitude depending on the day of the release, even for the same number of hours after the release event. However, the median of the dilution factors based on releases for 365 consecutive days at one site follows a power law relationship in time, as shown in Figure S-1. The relationship is good enough to provide a general rule of thumb for estimating typical future dilution factors in a plume starting at the same point. However, the coefficients of the power law function may vary for different release point locations. Radioactive decay causes the effective dilution factors to decrease more quickly with the time past the release event than the dilution factors based on a non-decaying tracer. An analytical expression for the dilution factors of isotopes with different half-lives can be developed given the power law expression

  3. The thin hot plume beneath Iceland

    Science.gov (United States)

    Allen, R.M.; Nolet, G.; Morgan, W.J.; Vogfjord, K.; Bergsson, B.H.; Erlendsson, P.; Foulger, G.R.; Jakobsdottir, S.; Julian, B.R.; Pritchard, M.; Ragnarsson, S.; Stefansson, R.

    1999-01-01

    We present the results of a seismological investigation of the frequency-dependent amplitude variations across Iceland using data from the HOTSPOT array currently deployed there. The array is composed of 30 broad-band PASSCAL instruments. We use the parameter t(*), defined in the usual manner from spectral ratios (Halderman and Davis 1991), to compare observed S-wave amplitude variations with those predicted due to both anelastic attenuation and diffraction effects. Four teleseismic events at a range of azimuths are used to measure t(*). A 2-D vertical cylindrical plume model with a Gaussian-shaped velocity anomaly is used to model the variations. That part of t(*) caused by attenuation was estimated by tracing a ray through IASP91, then superimposing our plume model velocity anomaly and calculating the path integral of 1/vQ. That part of t(*) caused by diffraction was estimated using a 2-D finite difference code to generate synthetic seismograms. The same spectral ratio technique used for the data was then used to extract a predicted t(*). The t(*) variations caused by anelastic attenuation are unable to account for the variations we observe, but those caused by diffraction do. We calculate the t(*) variations caused by diffraction for different plume models and obtain our best-fit plume, which exhibits good agreement between the observed and measured t(*). The best-fit plume model has a maximum S-velocity anomaly of - 12 per cent and falls to 1/e of its maximum at 100 km from the plume centre. This is narrower than previous estimates from seismic tomography, which are broadened and damped by the methods of tomography. This velocity model would suggest greater ray theoretical traveltime delays than observed. However, we find that for such a plume, wave-front healing effects at frequencies of 0.03-0.175 Hz (the frequency range used to pick S-wave arrivals) causes a 40 per cent reduction in traveltime delay, reducing the ray theoretical delay to that observed.

  4. Kimberlites, flood basalts and mantle plumes: New insights from the Deccan Large Igneous Province

    Science.gov (United States)

    Rao, N. V. Chalapathi; Lehmann, B.

    2011-08-01

    A clear-cut temporal and spatial relationship between small-volume, volatile-rich and highly potassic continental melt fractions, such as kimberlites and related rocks, and large-volume continental flood basalts exists in several Large Igneous Provinces (LIPs). Many of these LIPs are also widely regarded as products of mantle plume-lithosphere interactions. The small-volume melts either immediately pre-date or post-date or even are co-eval with the main flood basalt event. The overlap of ages between the flood basalts and the kimberlites very likely reflects a cause and effect relationship via mantle plumes. Recently discovered end-Cretaceous diamondiferous kimberlites (orangeites) in the Bastar craton of central India which are synchronous with the flood basalts, carbonatites, lamprophyres and alkaline rocks of the Deccan LIP provide an opportunity to re-evaluate the role of mantle plume-lithosphere interactions in the generation of these disparate magmas. The geographical zonation of the kimberlite-lamprophyre-carbonatite-alkaline rock spectrum in the Deccan LIP is inferred to reflect variable thickness of the pre-Deccan Indian lithosphere with a thinner lithosphere along the known rift zones of northwestern and western India and a thickened lithosphere underlying the Bastar craton of central India. This heterogeneity is thought to have controlled the volume of melt generation and melt ascent, as well as the ultimate alkaline magma type. These findings are supported by the regional lithospheric thickness map, generated from converting seismic shear wave velocities into temperature profiles, which clearly depicts that the present-day lithosphere beneath the Bastar craton is thicker than that in western and NW India where the centre of the Deccan plume-head was located. Thermal weakening of the sub-Bastar craton due to mantle plume-lithosphere interaction at the end-Cretaceous resulting in a thin-spot is suggested to have controlled the Deccan-related mafic dyke

  5. Heterogeneously hydrated mantle beneath the late Archean Yilgarn Craton

    Science.gov (United States)

    Ivanic, T. J.; Nebel, O.; Jourdan, F.; Faure, K.; Kirkland, C. L.; Belousova, E. A.

    2015-12-01

    Archean mafic-ultramafic melts, crystallized as layered intrusions in the upper crust and extruded as komatiitic flows, are primary probes of upper mantle chemistry. However, the message from their primary chemical composition can be compromised by different modes of contamination. Contaminants are typically cryptic in terms of their geochemical and isotopic signals but may be related to metasomatised mantle sources, ambient crustal assimilation or subduction-related inputs. In this work we present critical evidence for both dry and wet Archean mantle sources for two juxtaposed layered intrusions in the Australian Yilgarn Craton. The ca. 2813 Ma Windimurra and ca. 2800 Ma Narndee Igneous Complexes in Western Australia are two adjacent layered intrusions and would be expected to derive via similar mantle sections. A key difference in their chemistry is the presence of crystal-bound water in the Narndee Igneous Complex, represented primarily by abundant hornblende. Such a primary hydrous phase is notably absent in the Windimurra Igneous Complex. New 40Ar/39Ar plateau ages for fresh Narndee hornblende (weighted mean: 2805 ± 14 Ma, MSWD = 1.8, probability = 0.18) agrees with the published U-Pb age of 2800 ± 6 Ma for the complex and is consistent with a magmatic origin for this phase. Zircon Hf and whole-rock Hf and Nd isotopes for the Narndee Igneous Complex indicate only minor crustal contamination, in agreement with H and O isotope values in amphibole and O isotope values in rare zircon crystals, plagioclase and pyroxene within both complexes. These findings illustrate a fast temporal transition, in proximal bodies, from anhydrous to hydrous mantle sources with very minor crustal contamination. These large layered mafic-ultramafic intrusions are igneous bodies with a primitive chemical bulk composition that requires large degrees of mantle melting. This has been attributed by many workers to mantle plume activity, yet not without dispute, as subduction-related flux

  6. Nitrogen oxides and PAN in plumes from boreal fires during ARCTAS-B and their impact on ozone: an integrated analysis of aircraft and satellite observations

    Directory of Open Access Journals (Sweden)

    M. J. Alvarado

    2010-10-01

    Full Text Available We determine enhancement ratios for NOx, PAN, and other NOy species from boreal biomass burning using aircraft data obtained during the ARCTAS-B campaign and examine the impact of these emissions on tropospheric ozone in the Arctic. We find an initial emission factor for NOx of 1.06 g NO per kg dry matter (DM burned, much lower than previous observations of boreal plumes, and also one third the value recommended for extratropical fires. Our analysis provides the first observational confirmation of rapid PAN formation in a boreal smoke plume, with 40% of the initial NOx emissions being converted to PAN in the first few hours after emission. We find little clear evidence for ozone formation in the boreal smoke plumes during ARCTAS-B in either aircraft or satellite observations, or in model simulations. Only a third of the smoke plumes observed by the NASA DC8 showed a correlation between ozone and CO, and ozone was depleted in the plumes as often as it was enhanced. Special observations from the Tropospheric Emission Spectrometer (TES also show little evidence for enhanced ozone in boreal smoke plumes between 15 June and 15 July 2008. Of the 22 plumes observed by TES, only 4 showed ozone increasing within the smoke plumes, and even in those cases it was unclear that the increase was caused by fire emissions. Using the GEOS-Chem atmospheric chemistry model, we show that boreal fires during ARCTAS-B had little impact on the median ozone profile measured over Canada, and had little impact on ozone within the smoke plumes observed by TES.

  7. Heterogeneous OH oxidation of organic aerosols

    Science.gov (United States)

    Smith, J.; Kroll, J.; Cappa, C.; Che, D.; Ahmed, M.; Leone, S.; Worsnop, D.; Wilson, K.

    2008-12-01

    The hydroxyl radical (OH) is the most important reactive species in both clean and polluted atmospheres, and therefore gas-phase OH chemistry has been extensively studied for decades. Due to this enormous effort the rates and mechanism of OH reactions with gas phase organics are relatively well understood. However, it unclear whether these well established gas-phase chemical mechanisms apply to the more complex heterogeneous reactions of OH radicals with organic aerosols (OA). Although recent studies have begun to examine OH oxidation of OA, numerous outstanding questions still remain regarding both the rate and chemical mechanism of these reactions. Here we present an in depth investigation of the heterogeneous oxidation of organic squalane particles by OH radicals. By combining a photochemical aerosol flow reactor with a high-resolution aerosol mass spectrometer (AMS), with both electron impact and vacuum ultraviolet photoionization, we investigate OH heterogeneous chemistry in unprecedented detail. Employing elemental composition measurements with detailed kinetics we have arrived at a simple oxidation model which accurately accounts for the evolution of squalane and its" oxidation products. In addition, by exploring a large range of OH concentrations we are able to directly measure the role of secondary particle-phase chain chemistry which can significantly accelerate the oxidation of OA in the atmosphere. Based on these measurements we have arrived at an explicit chemical mechanism for heterogeneous OH oxidation of OA which accurately accounts for our observations over a wide range of reaction conditions.

  8. Impact of aircraft emissions on the atmospheric chemistry

    Energy Technology Data Exchange (ETDEWEB)

    Dameris, M.; Sausen, R.; Grewe, V.; Koehler, I.; Ponater, M. [Deutsche Forschungs- und Versuchsanstalt fuer Luft- und Raumfahrt e.V., Oberpfaffenhofen (Germany). Inst. fuer Physik der Atmosphaere; Steil, B. [Max-Planck-Inst. fuer Meteorologie, Hamburg (Germany); Bruehl, Ch. [Max-Planck-Inst. fuer Chemie (Otto-Hahn-Institut), Mainz (Germany)

    1997-12-31

    A hierarchy of models of different complexity has been applied to estimate the impact of aircraft NO{sub x} emissions on atmospheric chemistry. The global circulation model ECHAM3 has been coupled with two types of chemistry modules. The first of these describes only a simplified (linear) NO{sub x} and HNO{sub 3} chemistry while the second one is a comprehensive chemistry module (CHEM), describing tropospheric and stratospheric chemistry including photochemical reactions and heterogeneous reactions on sulphate aerosols and PSCs. The module CHEM has been coupled either off-line or with feedback via the ozone concentration. First results of multilayer integrations (over decades) are discussed. (author) 27 refs.

  9. Analysis of gaseous SO2, CO2 and halogen species in volcanic plumes using a multirotor Unmanned Aerial Vehicle (UAV).

    Science.gov (United States)

    Rüdiger, J.; de Moor, M. J.; Tirpitz, L.; Bobrowski, N.; Gutmann, A.; Hoffmann, T.

    2016-12-01

    Volcanoes are a large source for several reactive atmospheric trace gases including sulfur and halogen containing species. The detailed understanding of volcanic plume chemistry is needed to draw information from gas measurements on subsurface processes. This knowledge is essential for using gas measurements as a monitoring tool for volcanic activity. The reactive bromine species bromine monoxide (BrO) is of particular interest, because BrO as well as SO2 are readily measurable from safe distance by spectroscopic remote sensing techniques. BrO is not directly emitted, but is formed in the plume by a multiphase reaction mechanism. The abundance of BrO changes as a function of the distance from the vent as well as the spatial position in the plume. The precursor substance for the formation of BrO is HBr with Br2 as an intermediate product. In this study we present the application of a UAV as a carrier for a remote-controlled sampling system for halogen species (Br2, HBr, BrCl, etc), based on the gas diffusion denuder technique, which allows speciation and enrichment by selective organic reactions. For the analysis of gaseous SO2 and CO2 an in-situ gas monitoring system was additionally mounted. This setup was deployed into the gas plumes of Stromboli Volcano (Italy) and Masaya Volcano (Nicaragua) in 2016, to investigate the halogen chemistry at distant locations in the plume further downwind to the emission source, which are in most cases not accessible by other approaches. The used quadrocopter (0.75 m in diameter) weighs 2.45 kg and lifts a payload of 1.3 kg. Flights into the plume were conducted with ascents of up to 900 m, starting at 500 to 800 m altitude. From telemetrically transmitted SO2 mixing ratios, areas of dense plume were localized to keep the UAV stationary for up to 10 minutes of sampling time. Herein we will present time and spatial resolved gas mixing ratio data for SO2, CO2 and halogen species for a downwind plume age of about 3 to 5 minutes.

  10. Contrasted continental rifting via plume-craton interaction: Applications to Central East African Rift

    Directory of Open Access Journals (Sweden)

    Alexander Koptev

    2016-03-01

    Full Text Available The East African Rift system (EARS provides a unique system with the juxtaposition of two contrasting yet simultaneously formed rift branches, the eastern, magma-rich, and the western, magma-poor, on either sides of the old thick Tanzanian craton embedded in a younger lithosphere. Data on the pre-rift, syn-rift and post-rift far-field volcanic and tectonic activity show that the EARS formed in the context of the interaction between a deep mantle plume and a horizontally and vertically heterogeneous lithosphere under far-field tectonic extension. We bring quantitative insights into this evolution by implementing high-resolution 3D thermo-mechanical numerical deformation models of a lithosphere of realistic rheology. The models focus on the central part of the EARS. We explore scenarios of plume-lithosphere interaction with plumes of various size and initial position rising beneath a tectonically pre-stretched lithosphere. We test the impact of the inherited rheological discontinuities (suture zones along the craton borders, of the rheological structure, of lithosphere plate thickness variations, and of physical and mechanical contrasts between the craton and the embedding lithosphere. Our experiments indicate that the ascending plume material is deflected by the cratonic keel and preferentially channeled along one of its sides, leading to the formation of a large rift zone along the eastern side of the craton, with significant magmatic activity and substantial melt amount derived from the mantle plume material. We show that the observed asymmetry of the central EARS, with coeval amagmatic (western and magmatic (eastern branches, can be explained by the splitting of warm material rising from a broad plume head whose initial position is slightly shifted to the eastern side of the craton. In that case, neither a mechanical weakness of the contact between the craton and the embedding lithosphere nor the presence of second plume are required to

  11. Segregation of acid plume pixels from background water pixels, signatures of background water and dispersed acid plumes, and implications for calculation of iron concentration in dense plumes

    Science.gov (United States)

    Bahn, G. S.

    1978-01-01

    Two files of data, obtained with a modular multiband scanner, for an acid waste dump into ocean water, were analyzed intensively. Signatures were derived for background water at different levels of effective sunlight intensity, and for different iron concentrations in the dispersed plume from the dump. The effect of increased sunlight intensity on the calculated iron concentration was found to be relatively important at low iron concentrations and relatively unimportant at high values of iron concentration in dispersed plumes. It was concluded that the basic equation for iron concentration is not applicable to dense plumes, particularly because lower values are indicated at the very core of the plume, than in the surrounding sheath, whereas radiances increase consistently from background water to dispersed plume to inner sheath to innermost core. It was likewise concluded that in the dense plume the iron concentration would probably best be measured by the higher wave length radiances, although the suitable relationship remains unknown.

  12. Selective Oxidations using Nanostructured Heterogeneous Catalysts

    DEFF Research Database (Denmark)

    Mielby, Jerrik Jørgen

    and because they produce H2O as the only by-product. Chapter 1 gives a short introduction to basic concepts in heterogeneous catalysis and green chemistry. Furthermore, the chapter gives an overview of the most important strategies to synthesise functional nanostructured materials and highlights how detailed......The aim of this thesis is to investigate and develop new efficient methods to oxidise alcohols and amines using heterogeneous catalysts and either O2 or H2O2 as oxidants. From an economic and environmental point of view, these oxidants are ideal, because they are cheap and readily available...... understanding of size, shape and structure can help in the development of new and more efficient heterogeneous catalysts. The chapter is not intended to give a complete survey, but rather to introduce some of the recent developments in the synthesis of nanostructured heterogeneous catalysts. Finally...

  13. Heterogeneous continuous-time random walks

    Science.gov (United States)

    Grebenkov, Denis S.; Tupikina, Liubov

    2018-01-01

    We introduce a heterogeneous continuous-time random walk (HCTRW) model as a versatile analytical formalism for studying and modeling diffusion processes in heterogeneous structures, such as porous or disordered media, multiscale or crowded environments, weighted graphs or networks. We derive the exact form of the propagator and investigate the effects of spatiotemporal heterogeneities onto the diffusive dynamics via the spectral properties of the generalized transition matrix. In particular, we show how the distribution of first-passage times changes due to local and global heterogeneities of the medium. The HCTRW formalism offers a unified mathematical language to address various diffusion-reaction problems, with numerous applications in material sciences, physics, chemistry, biology, and social sciences.

  14. Modeling the reactive halogen plume from Ambrym and its impact on the troposphere with the CCATT-BRAMS mesoscale model

    Directory of Open Access Journals (Sweden)

    L. Jourdain

    2016-09-01

    Full Text Available Ambrym Volcano (Vanuatu, southwest Pacific is one of the largest sources of continuous volcanic emissions worldwide. As well as releasing SO2 that is oxidized to sulfate, volcanic plumes in the troposphere are shown to undergo reactive halogen chemistry whose atmospheric impacts have been little explored to date. Here, we investigate with the regional-scale model CCATT-BRAMS (Coupled Chemistry Aerosol-Tracer Transport model, Brazilian developments on the Regional Atmospheric Modeling System, version 4.3 the chemical processing in the Ambrym plume and the impact of this volcano on the atmospheric chemistry on both local and regional scales. We focus on an episode of extreme passive degassing that occurred in early 2005 and for which airborne DOAS (differential optical absorption spectroscopy measurements of SO2 and BrO columns in the near-downwind plume between 15 and 40 km from the vents have been reported. The model was developed to include reactive halogen chemistry and a volcanic emission source specific to this extreme degassing event. In order to test our understanding of the volcanic plume chemistry, we performed very high-resolution (500 m  ×  500 m simulations using the model nesting grid capability and compared each DOAS measurement to its temporally and spatially interpolated model counterpart “point-by-point”. Simulated SO2 columns show very good quantitative agreement with the DOAS observations, suggesting that the plume direction as well as its dilution in the near-downwind plume are well captured. The model also reproduces the salient features of volcanic chemistry as reported in previous work, such as HOx and ozone depletion in the core of the plume. When a high-temperature chemistry initialization is included, the model is able to capture the observed BrO ∕ SO2 trend with distance from the vent. The main discrepancy between observations and model is the bias between the magnitudes of observed and

  15. Summertime Changjiang River plume variation during 1998-2010

    Science.gov (United States)

    Bai, Yan; He, Xianqiang; Pan, Delu; Chen, Chen-Tung Arthur; Kang, Yan; Chen, Xiaoyan; Cai, Wei-Jun

    2014-09-01

    Using an improved satellite-derived salinity algorithm in the East China Sea (ECS), we presented and examined a general view on summertime Changjiang River plume variation during 1998-2010. Three types of plume shapes were identified: (1) the commonly known northeastward transportation, (2) a case in which most of the plume water crossed the Cheju Strait into the Tsushima-Korea Straits with only a small fraction staying on the shelf of the ECS, and (3) a rare case in which the plume front moved southeastward. Satellite time-series data suggested that, during the peak river discharge time in July with favorable southwest monsoon, the plume area was highly correlated with the river discharge of the same month. Interestingly, the plume area in August was also dominated by the discharge in July. In August, as the direct effect of freshwater discharge weakening, the plume area also became positively correlated with wind speed in the 45° and 60°direction, suggesting that the plume extension was more influenced by the southwesterly wind during periods of smaller discharge. Furthermore, a few special cases with unique plume extensions were found under extreme weather conditions. Finally, we found no significant long-term trend of plume area change over 1998-2010 in summertime and concluded that the interannual variation was probably regulated by natural variation rather than anthropogenic effects, such as construction of the Three Gorges Dam. This study will have implications for biogeochemical and modeling studies in large river plume areas.

  16. Theoretical chemistry periodicities in chemistry and biology

    CERN Document Server

    Eyring, Henry

    1978-01-01

    Theoretical Chemistry: Periodicities in Chemistry and Biology, Volume 4 covers the aspects of theoretical chemistry. The book discusses the stably rotating patterns of reaction and diffusion; the chemistry of inorganic systems exhibiting nonmonotonic behavior; and population cycles. The text also describes the mathematical modeling of excitable media in neurobiology and chemistry; oscillating enzyme reactions; and oscillatory properties and excitability of the heart cell membrane. Selected topics from the theory of physico-chemical instabilities are also encompassed. Chemists, mechanical engin

  17. On possible plume-guided seismic waves

    Science.gov (United States)

    Julian, B.R.; Evans, J.R.

    2010-01-01

    Hypothetical thermal plumes in the Earth's mantle are expected to have low seismic-wave speeds and thus would support the propagation of guided elastic waves analogous to fault-zone guided seismic waves, fiber-optic waves, and acoustic waves in the oceanic SOund Fixing And Ranging channel. Plume-guided waves would be insensitive to geometric complexities in the wave guide, and their dispersion would make them distinctive on seismograms and would provide information about wave-guide structure that would complement seismic tomography. Detecting such waves would constitute strong evidence of a new kind for the existence of plumes. A cylindrical channel embedded in an infinite medium supports two classes of axially symmetric elastic-wave modes, torsional and longitudinal-radial. Torsional modes have rectilinear particle motion tangent to the cylinder surface. Longitudinal-radial modes have elliptical particle motion in planes that include the cylinder axis, with retrograde motion near the axis. The direction of elliptical particle motion reverses with distance from the axis: once for the fundamental mode, twice for the first overtone, and so on. Each mode exists only above its cut-off frequency, where the phase and group speeds equal the shear-wave speed in the infinite medium. At high frequencies, both speeds approach the shear-wave speed in the channel. All modes have minima in their group speeds, which produce Airy phases on seismograms. For shear wave-speed contrasts of a few percent, thought to be realistic for thermal plumes in the Earth, the largest signals are inversely dispersed and have dominant frequencies of about 0.1-1 Hz and durations of 15-30 sec. There are at least two possible sources of observable plume waves: (1) the intersection of mantle plumes with high-amplitude core-phase caustics in the deep mantle; and (2) ScS-like reflection at the core-mantle boundary of downward-propagating guided waves. The widespread recent deployment of broadband

  18. Across-strike and along-strike asymmetry as an intrinsic characteristic of plume-induced continental rifting: Insights from 3D numerical modeling

    Science.gov (United States)

    Koptev, Alexander; Burov, Evgueni; Gerya, Taras; Le Pourhiet, Laetitia; Leroy, Sylvie; Calais, Eric; Jolivet, Laurent

    2017-04-01

    We present a series of numerical experiments of ascending mantle plume interacting with a rheologically realistic continental lithosphere subjected to ultra-slow far-field extension. Our study focuses on the variations of plume-induced rifting style - mode of strain localization, deformation zone width, spatial location of resulting break-up and spreading axes - as a function of variations in thermo-rheological properties of the continental lithosphere. Our results illustrate that the geometry of the plume-induced rifting/break-up pattern can be strongly variable and asymmetric even in the absence of inherited crustal/lithospheric heterogeneities. This asymmetry seems to be an intrinsic characteristic of plume-induced rifting/spreading process that develops spontaneously from initially symmetrical plume-lithosphere geometry. Along-axis asymmetry is represented by non-uniform ascent of plume material along the future break-up center, which results in the development of separated magma chambers. This scenario involving faster localized uplift of the plume material at the distal point from the plume center can be compared with magmatic and tectonic evolution of the South Atlantic where seafloor spreading propagated northward up to the Tristan da Cunha hot-spot. Across-strike segmentation is shown in our models by complex asymmetric systems characterized by various velocities of plume material uplift along different localized axes leading to contrasting rifting. The final position of the continental break-up zone(s) is likely to be offset with respect to the plume impingement and, consequently, does not necessarily coincide with the area of pre-rift uplift and magmatism. Most of our 3D experiments, as well as other 3D experiments published the last 10 years, produce self-induced temporal and spatial (across-strike just like along-strike) break-up irregularities that were only produced in 2D using very strong mechanical heterogeneity. Without dismissing heterogeneities

  19. Heterogeneity and Diversity: A Growing Challenge or Enrichment for Science Education in German Schools?

    Science.gov (United States)

    Markic, Silvija; Abels, Simone

    2014-01-01

    The present paper gives an overview of research on heterogeneity and diversity in German chemistry classes. The terms "heterogeneity" and "diversity" are first explained before discussing specific studies. The different facets of heterogeneity and diversity are asserted. Finally, the focus will be placed on language and special…

  20. Interstellar chemistry

    Science.gov (United States)

    Klemperer, William

    2006-01-01

    In the past half century, radioastronomy has changed our perception and understanding of the universe. In this issue of PNAS, the molecular chemistry directly observed within the galaxy is discussed. For the most part, the description of the molecular transformations requires specific kinetic schemes rather than chemical thermodynamics. Ionization of the very abundant molecular hydrogen and atomic helium followed by their secondary reactions is discussed. The rich variety of organic species observed is a challenge for complete understanding. The role and nature of reactions involving grain surfaces as well as new spectroscopic observations of interstellar and circumstellar regions are topics presented in this special feature. PMID:16894148

  1. Electric Propulsion Plume Simulations Using Parallel Computer

    Directory of Open Access Journals (Sweden)

    Joseph Wang

    2007-01-01

    Full Text Available A parallel, three-dimensional electrostatic PIC code is developed for large-scale electric propulsion simulations using parallel supercomputers. This code uses a newly developed immersed-finite-element particle-in-cell (IFE-PIC algorithm designed to handle complex boundary conditions accurately while maintaining the computational speed of the standard PIC code. Domain decomposition is used in both field solve and particle push to divide the computation among processors. Two simulations studies are presented to demonstrate the capability of the code. The first is a full particle simulation of near-thruster plume using real ion to electron mass ratio. The second is a high-resolution simulation of multiple ion thruster plume interactions for a realistic spacecraft using a domain enclosing the entire solar array panel. Performance benchmarks show that the IFE-PIC achieves a high parallel efficiency of ≥ 90%

  2. Modeling contaminant plumes in fractured limestone aquifers

    DEFF Research Database (Denmark)

    Mosthaf, Klaus; Brauns, Bentje; Fjordbøge, Annika Sidelmann

    Determining the fate and transport of contaminant plumes from contaminated sites in limestone aquifers is important because they are a major drinking water resource. This is challenging because they are often heavily fractured and contain chert layers and nodules, resulting in a complex transport...... behavior. Improved conceptual models are needed for this type of site. Here conceptual models are developed by combining numerical models with field data. Several types of fracture flow and transport models are available for the modeling of contaminant transport in fractured media. These include...... the established approaches of the equivalent porous medium, discrete fracture and dual continuum models. However, these modeling concepts are not well tested for contaminant plume migration in limestone geologies. Our goal was to develop and evaluate approaches for modeling the transport of dissolved contaminant...

  3. Heterogeneous physicochemistry of the polar ozone hole

    Science.gov (United States)

    Turco, Richard P.; Toon, Owen B.; Hamill, Patrick

    1989-01-01

    Processes occurring in the polar winter stratosphere, which involve polar stratospheric clouds (PSCs), are investigated using observations from the Airborne Antarctic Ozone Experiment. In particular, data on the properties of PSCs and their physical chemistry, the microphysical processes and time constants for cloud processes, the heterogeneous chemical processes and their time constants, and nonlinearities in the long-term ozone trend associated with physical and chemical processes are examined. The chemical reactions leading to the depletion of the inert chlorine reservoir in a presence of type I PSCs are established, and it is shown that type II PSCs contribute to chemical processing that sustains the chemical imbalance of the polar stratosphere. It is shown that, using a simple model, the decadal evolution of the Antarctic ozone hole may be understood through nonlinearities in the heterogeneous chemistry, with possible contributing effects of variations in stratospheric temperatures and water vapor concentrations.

  4. [Review on landscape heterogeneity].

    Science.gov (United States)

    Zhao, Yutao; Yu, Xinxiao; Guang, Wenbin

    2002-04-01

    On the base of precedent studies, the occurring mechanism, classification, measurement methods, and the important role of landscape heterogeneity in landscape ecology were reviewed. The inner and outer uncertain factors result in landscape heterogeneity. Landscape heterogeneity has close relations with landscape stability, landscape design, architecture, management and disturbance, scale and ecological diversity in ecology. Complexity of landscape heterogeneity research, non-system of measurement indices and methods, difficulties and limitations of landscape heterogeneity modelling were all discussed respectively. In addition, it is suggested that the theory and methods of ecological complexity should be used to improve landscape heterogeneity research.

  5. Innovative Strategy For Long Term Monitoring Of Metal And Radionuclide Plumes

    Energy Technology Data Exchange (ETDEWEB)

    Eddy-Dilek, Carol; Millings, Margaret R.; Looney, Brian B.; Denham, Miles E.

    2014-01-08

    Many government and private industry sites that were once contaminated with radioactive and chemical wastes cannot be cleaned up enough to permit unrestricted human access. The sites will require long term management, in some cases indefinitely, leaving site owners with the challenge of protecting human health and environmental quality at these "legacy" sites. Long-term monitoring of groundwater contamination is one of the largest projected costs in the life cycle of environmental management at the Savannah River Site, the larger DOE complex, and many large federal and private sites. There is a need to optimize the performance and manage the cost of long term surveillance and monitoring at their sites. Currently, SRNL is initiating a pilot field test using alternative protocols for long term monitoring of metals and radionuclides. A key component of the approach is that monitoring efforts are focused on measurement of low cost metrics related to hydrologic and chemical conditions that control contaminant migration. The strategy combines careful monitoring of hydrologic boundary conditions with measurement of master variables such as chemical surrogates along with a smaller number of standard well analyses. In plumes contaminated with metals, master variables control the chemistry of the groundwater system, and include redox variables (ORP, DO, chemicals), pH, specific conductivity, biological community (breakdown/decay products), and temperature. Significant changes in these variables will result in conditions whereby the plume may not be stable and therefore can be used to predict possible plume migration. Conversely, concentration measurements for all types of contaminants in groundwater are a lagging indicator plume movement - major changes contaminant concentrations indicate that contamination has migrated. An approach based on measurement of master variables and explicit monitoring of hydrologic boundary conditions combined with traditional metrics should lead

  6. Combustion chemistry

    Energy Technology Data Exchange (ETDEWEB)

    Brown, N.J. [Lawrence Berkeley Laboratory, CA (United States)

    1993-12-01

    This research is concerned with the development and use of sensitivity analysis tools to probe the response of dependent variables to model input variables. Sensitivity analysis is important at all levels of combustion modeling. This group`s research continues to be focused on elucidating the interrelationship between features in the underlying potential energy surface (obtained from ab initio quantum chemistry calculations) and their responses in the quantum dynamics, e.g., reactive transition probabilities, cross sections, and thermal rate coefficients. The goals of this research are: (i) to provide feedback information to quantum chemists in their potential surface refinement efforts, and (ii) to gain a better understanding of how various regions in the potential influence the dynamics. These investigations are carried out with the methodology of quantum functional sensitivity analysis (QFSA).

  7. Immobilization chemistries.

    Science.gov (United States)

    Todt, Sascha; Blohm, Dietmar H

    2009-01-01

    Among the parameters which influence the success of a microarray experiment, the attachment of the nucleic acid captures to the support surface plays a decisive role.This article attempts to review the main concepts and ideas of the multiple variants which exist in terms of the immobilization chemistries used in nucleic acid microarray technology. Starting from the attachment of unmodified nucleic acids to modified glass slides by adsorption, further strategies for the coupling of nucleic acid capture molecules to a variety of support materials are surveyed with a focus on the reactive groups involved in the respective process.After a brief introduction, an overview is given about microarray substrates with special emphasis on the approaches used for the activation of these - usually chemically inert - materials. In the next sections strategies for the "undefined" and "defined" immobilization of captures on the substrates are described. While the latter approach tries to accomplish the coupling via a defined reactive moiety of the molecule to be immobilized, the former mentioned techniques involve multiply occurring reactive groups in the capture.The article finishes with an example for microarray manufacture, the production of aminopropyltriethoxysilane (APTES) functionalized glass substrates to which PDITC homobifunctional linker molecules are coupled; on their part providing reactive functional groups for the covalent immobilization of pre-synthesized, amino-modified oligonucleotides.This survey does not seek to be comprehensive rather it tries to present and provide key examples for the basic techniques, and to enable orientation if more detailed studies are needed. This review should not be considered as a guide to how to use the different chemistries described, but instead as a presentation of various principles and approaches applied in the still evolving field of nucleic acid microarray technology.

  8. Geodynamic modelling of low-buoyancy thermo-chemical plumes

    Science.gov (United States)

    Dannberg, Juliane; Sobolev, Stephan

    2015-04-01

    The Earth's biggest magmatic events that form Large Igneous Provinces are believed to originate from massive melting when hot mantle plumes rising from the lowermost mantle reach the base of the lithosphere. Classical models of thermal mantle plumes predict a flattening of the plume head to a disk-like structure, a kilometer-scale surface uplift just before the initiation of LIPs and thin plume tails. However, there are seismic observations and paleo-topography data that are difficult to explain with this classical approach. Here, using numerical models, we show that the issue can be resolved if major mantle plumes are thermo-chemical rather than purely thermal. It has been suggested a long time ago that subducted oceanic crust could be recycled by mantle plumes; and based on geochemical data, they may contain up to 15-20% of this recycled material in the form of dense eclogite, which drastically decreases their buoyancy and makes it depth-dependent. We perform numerical experiments in a 3D spherical shell geometry to investigate the dynamics of the plume ascent, the interaction between plume- and plate-driven flow and the dynamics of melting in a plume head. For this purpose, we use the finite-element code ASPECT, which allows for complex temperature-, pressure- and composition-dependent material properties. Moreover, our models incorporate phase transitions (including melting) with the accompanying rheological and density changes, Clapeyron slopes and latent heat effects for both peridotite and eclogite, mantle compressibility and a strong temperature- and depth-dependent viscosity. We demonstrate that despite their low buoyancy, such plumes can rise through the whole mantle causing only negligible surface uplift. Conditions for this ascent are high plume volume and moderate lower mantle subadiabaticity. While high plume buoyancy results in plumes directly advancing to the base of the lithosphere, plumes with slightly lower buoyancy pond in a depth of 300-400 km

  9. Link-Heterogeneity vs. Node-Heterogeneity in Clusters

    OpenAIRE

    Beaumont, Olivier; Rosenberg, Arnold

    2010-01-01

    International audience; Heterogeneity in resources pervades all modern computing platforms. How do the effects of heterogeneity depend on which resources differ among computers in a platform? Some answers are derived within a formal framework, by comparing heterogeneity in computing power (node-heterogeneity) with heterogeneity in communication speed (link-heterogeneity). The former genre of heterogeneity seems much easier to understand than the latter.

  10. Public perception of chemistry

    OpenAIRE

    Stražar, Alenka

    2015-01-01

    The thesis deals with the perception of chemistry among the public, which reflects the stereotypes that people have about chemistry. It presents the existing classification of stereotypes about chemistry and their upgrade. An analysis of movies that reflect the existing perception of chemistry in the public is written. Literature on selected aspects of the application of chemistry in movies is collected and analyzed. A qualification of perception of chemistry in the movies is presented based ...

  11. Anticyclonic precession of a plume in a rotating environment

    Science.gov (United States)

    Frank, D.; Landel, J. R.; Dalziel, S. B.; Linden, P. F.

    2017-09-01

    Motivated by potential effects of the Earth's rotation on the Deepwater Horizon oil plume, we conducted laboratory experiments on saltwater point plumes in a homogeneous rotating environment across a wide range of Rossby numbers 0.02≤Ro≤1.3. We report a striking physical instability in the plume dynamics near the source: after approximately one rotation period, the plume tilts laterally and starts to precess anticyclonically. The mean precession frequency ω¯ scales linearly with the rotation rate Ω as ω¯≈0.4Ω. We find no evidence of a critical Rossby number above which precession ceases. We infer that a conventionally defined Rossby number is not an appropriate parameter when the plume is maintained over a long time: provided Ω ≠ 0, rotation is always important to the dynamics. This indicates that precession may occur in persistent oceanic or atmospheric plumes even at low latitudes.

  12. USSR Report Chemistry

    National Research Council Canada - National Science Library

    1986-01-01

    Contents: Adsorption, Chemistry,Alkaloids, Analytical Chemistry, Catalysis,Chemical Industry,,Coal Gasification, Combustion, Electrochemistry,Explosives and Explosions, Fertilizers, Free Radicals, Inorganic...

  13. Science Update: Inorganic Chemistry.

    Science.gov (United States)

    Rawls, Rebecca

    1981-01-01

    Describes areas of inorganic chemistry which have changed dramatically in the past year or two, including photochemistry, electrochemistry, organometallic complexes, inorganic reaction theory, and solid state chemistry. (DS)

  14. Dynamic Data-Driven UAV Network for Plume Characterization

    Science.gov (United States)

    2016-05-23

    AFRL-AFOSR-VA-TR-2016-0203 Dynamic Data-Driven UAV Network for Plume Characterization Kamran Mohseni UNIVERSITY OF FLORIDA Final Report 05/23/2016...AND SUBTITLE Dynamic Data-Driven UAV Network for Plume Characterization 5a.  CONTRACT NUMBER 5b.  GRANT NUMBER FA9550-13-1-0090 5c.  PROGRAM ELEMENT...toxic plume characterization, Intelligence, Surveillance and Reconnaissance (ISR), environmental monitoring, weather forecasting, and disaster

  15. New method for calculation of integral characteristics of thermal plumes

    DEFF Research Database (Denmark)

    2008-01-01

    A method for calculation of integral characteristics of thermal plumes is proposed. The method allows for determination of the integral parameters of plumes based on speed measurements performed with omnidirectional low velocity thermoanemometers. The method includes a procedure for calculation...... occupant. The improvement in calculation of the characteristics of the thermal plume achieved with the developed method, in comparison with methods used and reported in the literature, is demonstrated....

  16. Correlating Large Igneous Provinces with Lower Mantle Seismic Structure - Where Is the Plume Generation Zone?

    Science.gov (United States)

    Austermann, J.; Kaye, B. T.; Mitrovica, J. X.; Huybers, P. J.

    2014-12-01

    Deep mantle seismic structure is dominated by two large, low shear wave velocity provinces (LLSVPs) below Africa and the Pacific. While different tomography models have come to a consensus over the general geometry of these provinces, the degree of thermal versus chemical heterogeneity that defines them is contentious. The location of plumes that rise from these large structures may provide insight into this question. Large Igneous Provinces (LIPs) are thought to be the surface expression of plumes that formed in the deep mantle and subsequently rose through the mantle and erupted at the surface. When restored to their original location of eruption, these LIPs appear to lie approximately above the margins of LLSVPs. This spatial correlation has been used to argue that plumes are preferentially generated at margins of LLSVPs, a notion that would tend to favor a significant chemical gradient at this margin. We assessed the robustness of this correlation by performing a series of Monte Carlo-based statistical tests (Austermann et al., Geophys. J. Int., 2014). These tests confirm that the reconstructed locations of LIPs are spatially correlated with margins of LLSVPs, but they also show that LIPs are correlated with the full areal extent of LLSVPs (parameterized as regions of slower-than-average shear wave velocity). These two correlations cannot be statistically distinguished, which means the areal extent of LLSVPs is an equally likely zone for plume generation. Therefore, based on current tomography models and reconstructed locations of LIPs, we cannot distinguish whether LIPs originated preferentially at the margins of LLSVPs or whether this correlation is merely an outcome of their origin across the full areal extent of these large scale, deep mantle structures. We will discuss the implications of our findings on the growing debate over the relative contributions of thermal and chemical effects on the net buoyancy of the LLSVPs, a factor that ultimately controls

  17. Marine bird aggregations associated with the tidally-driven plume and plume fronts of the Columbia River

    Science.gov (United States)

    Zamon, Jeannette E.; Phillips, Elizabeth M.; Guy, Troy J.

    2014-09-01

    Freshwater discharge from large rivers into the coastal ocean creates tidally-driven frontal systems known to enhance mixing, primary production, and secondary production. Many authors suggest that tidal plume fronts increase energy flow to fish-eating predators by attracting planktivorous fishes to feed on plankton aggregated by the fronts. However, few studies of plume fronts directly examine piscivorous predator response to plume fronts. Our work examined densities of piscivorous seabirds relative to the plume region and plume fronts of the Columbia River, USA. Common murres (Uria aalge) and sooty shearwaters (Puffinus griseus) composed 83% of all birds detected on mesoscale surveys of the Washington and Oregon coasts (June 2003-2006), and 91.3% of all birds detected on fine scale surveys of the plume region less than 40 km from the river mouth (May 2003 and 2006). Mesoscale comparisons showed consistently more predators in the central plume area compared to the surrounding marine area (murres: 10.1-21.5 vs. 3.4-8.2 birds km-2; shearwaters: 24.2-75.1 vs. 11.8-25.9 birds km-2). Fine scale comparisons showed that murre density in 2003 and shearwater density in both 2003 and 2006 were significantly elevated in the tidal plume region composed of the most recently discharged river water. Murres tended to be more abundant on the north face of the plume. In May 2003, more murres and shearwaters were found within 3 km of the front on any given transect, although maximum bird density was not necessarily found in the same location as the front itself. Predator density on a given transect was not correlated with frontal strength in either year. The high bird densities we observed associated with the tidal plume demonstrate that the turbid Columbia River plume does not necessarily provide fish with refuge from visual predators. Bird predation in the plume region may therefore impact early marine survival of Pacific salmon (Oncorhynchus spp.), which must migrate through the

  18. Heterogeneous network architectures

    DEFF Research Database (Denmark)

    Christiansen, Henrik Lehrmann

    2006-01-01

    Future networks will be heterogeneous! Due to the sheer size of networks (e.g., the Internet) upgrades cannot be instantaneous and thus heterogeneity appears. This means that instead of trying to find the olution, networks hould be designed as being heterogeneous. One of the key equirements here...

  19. The tropospheric processing of acidic gases and hydrogen sulphide in volcanic gas plumes as inferred from field and model investigations

    Directory of Open Access Journals (Sweden)

    A. Aiuppa

    2007-01-01

    variations in the modelled SO2/HCl ratios were predicted under cloudy conditions, due to heterogeneous chlorine cycling in the aerosol phase. The modelled evolution of the SO2/H2S ratios is found to be substantially dependent on whether or not the interactions of H2S with halogens are included in the model. In the former case, H2S is assumed to be oxidized in the atmosphere mainly by OH, which results in minor chemical loss for H2S during plume aging and produces a fair match between modelled and measured SO2/H2S ratios. In the latter case, fast oxidation of H2S by Cl leads to H2S chemical lifetimes in the early plume of a few seconds, and thus SO2 to H2S ratios that increase sharply during plume transport. This disagreement between modelled and observed plume compositions suggests that more in-detail kinetic investigations are required for a proper evaluation of H2S chemical processing in volcanic plumes.

  20. Exceptionally Long MTBE Plumes of the Past Have Greatly Diminished.

    Science.gov (United States)

    McDade, James M; Connor, John A; Paquette, Shawn M; Small, Julia M

    2015-01-01

    Studies published in the late 1990s and early 2000s identified the presence of exceptionally long methyl tert-butyl ether (MTBE) plumes (more than 600 m or 2000 feet) in groundwater and have been cited in technical literature as characteristic of MTBE plumes. However, the scientific literature is incomplete in regard to the subsequent behavior and fate of these MTBE plumes over the past decade. To address this gap, this issue paper compiles recent groundwater monitoring records for nine exceptional plumes that were identified in prior studies. These nine sites exhibited maximum historical MTBE groundwater plume lengths ranging from 820 m (2700 feet) to 3200 m (10,500 feet) in length, exceeding the lengths of 99% of MTBE plumes, as characterized in multiple surveys at underground storage tank sites across the United States. Groundwater monitoring data compiled in our review demonstrate that these MTBE plumes have decreased in length over the past decade, with five of the nine plumes exhibiting decreases of 75% or more compared to their historical maximum lengths. MTBE concentrations within these plumes have decreased by 93% to 100%, with two of the nine sites showing significant decreases (98% and 99%) such that the regulatory authority has subsequently designated the site as requiring no further action. © 2015 The Authors. Groundwater published by Wiley Periodicals,Inc. on behalf of National Ground Water Association.

  1. Quasi-periodic compressive waves in polar plumes

    Science.gov (United States)

    DeForest, C. E.; Gurman, J. B.

    1997-01-01

    The observation of polar plumes in the south polar coronal hole, carried out on 7 March 1996 by the Solar and Heliospheric Observatory (SOHO), are analyzed. These polar plumes are cool density structures that arise from morphologically unipolar magnetic footpoints. Data from the extreme ultraviolet imaging telescope show quasi-periodic perturbations in the brightness of the Fe IX and X line emissions at 171 A from polar plumes. The perturbations have periods of 10 to 15 min, and repeat for several cycles suggesting that they are compressive waves propagating through the plume at or near the Alfven speed. Possible explanations for the observed phenomenon are proposed.

  2. Algorithms and analysis for underwater vehicle plume tracing.

    Energy Technology Data Exchange (ETDEWEB)

    Byrne, Raymond Harry; Savage, Elizabeth L. (Texas A& M University, College Station, TX); Hurtado, John Edward (Texas A& M University, College Station, TX); Eskridge, Steven E.

    2003-07-01

    The goal of this research was to develop and demonstrate cooperative 3-D plume tracing algorithms for miniature autonomous underwater vehicles. Applications for this technology include Lost Asset and Survivor Location Systems (L-SALS) and Ship-in-Port Patrol and Protection (SP3). This research was a joint effort that included Nekton Research, LLC, Sandia National Laboratories, and Texas A&M University. Nekton Research developed the miniature autonomous underwater vehicles while Sandia and Texas A&M developed the 3-D plume tracing algorithms. This report describes the plume tracing algorithm and presents test results from successful underwater testing with pseudo-plume sources.

  3. Geochemistry and geochronology of the mafic lavas from the southeastern Ethiopian rift (the East African Rift System): assessment of models on magma sources, plume-lithosphere interaction and plume evolution

    Science.gov (United States)

    Shinjo, Ryuichi; Chekol, Takele; Meshesha, Daniel; Itaya, Tetsumaru; Tatsumi, Yoshiyuki

    2011-07-01

    Major and trace element and isotopic ratios (Sr, Nd and Pb) are presented for mafic lavas (MgO > 4 wt%) from the southwestern Yabello region (southern Ethiopia) in the vicinity of the East African Rift System (EARS). New K/Ar dating results confirm three magmatic periods of activity in the region: (1) Miocene (12.3-10.5 Ma) alkali basalts and hawaiites, (2) Pliocene (4.7-3.6 Ma) tholeiitic basalts, and (3) Recent (1.9-0.3 Ma) basanite-dominant alkaline lavas. Trace element and isotopic characteristics of the Miocene and Quaternary lavas bear a close similarity to ocean island basalts that derived from HIMU-type sublithospheric source. The Pliocene basalts have higher Ba/Nb, La/Nb, Zr/Nb and 87Sr/86Sr (0.70395-0.70417) and less radiogenic Pb isotopic ratios (206Pb/204Pb = 18.12-18.27) relative to the Miocene and Quaternary lavas, indicative of significant contribution from enriched subcontinental lithospheric mantle in their sources. Intermittent upwelling of hot mantle plume in at least two cycles can explain the magmatic evolution in the southern Ethiopian region. Although plumes have been originated from a common and deeper superplume extending from the core-mantle boundary, the diversity of plume components during the Miocene and Quaternary reflects heterogeneity of secondary plumes at shallower levels connected to the African superplume, which have evolved to more homogeneous source.

  4. Operando research in heterogeneous catalysis

    CERN Document Server

    Groot, Irene

    2017-01-01

    This book is devoted to the emerging field of techniques for visualizing atomic-scale properties of active catalysts under actual working conditions, i.e. high gas pressures and high temperatures. It explains how to understand these observations in terms of the surface structures and dynamics and their detailed interplay with the gas phase. This provides an important new link between fundamental surface physics and chemistry, and applied catalysis. The book explains the motivation and the necessity of operando studies, and positions these with respect to the more traditional low-pressure investigations on the one hand and the reality of industrial catalysis on the other. The last decade has witnessed a rapid development of new experimental and theoretical tools for operando studies of heterogeneous catalysis. The book has a strong emphasis on the new techniques and illustrates how the challenges introduced by the harsh, operando conditions are faced for each of these new tools. Therefore, one can also read th...

  5. Spatially Resolving Ocean Color and Sediment Dispersion in River Plumes, Coastal Systems, and Continental Shelf Waters

    Science.gov (United States)

    Aurin, Dirk Alexander; Mannino, Antonio; Franz, Bryan

    2013-01-01

    Satellite remote sensing of ocean color in dynamic coastal, inland, and nearshorewaters is impeded by high variability in optical constituents, demands specialized atmospheric correction, and is limited by instrument sensitivity. To accurately detect dispersion of bio-optical properties, remote sensors require ample signal-to-noise ratio (SNR) to sense small variations in ocean color without saturating over bright pixels, an atmospheric correction that can accommodate significantwater-leaving radiance in the near infrared (NIR), and spatial and temporal resolution that coincides with the scales of variability in the environment. Several current and historic space-borne sensors have met these requirements with success in the open ocean, but are not optimized for highly red-reflective and heterogeneous waters such as those found near river outflows or in the presence of sediment resuspension. Here we apply analytical approaches for determining optimal spatial resolution, dominant spatial scales of variability ("patches"), and proportions of patch variability that can be resolved from four river plumes around the world between 2008 and 2011. An offshore region in the Sargasso Sea is analyzed for comparison. A method is presented for processing Moderate Resolution Imaging Spectroradiometer (MODIS) Aqua and Terra imagery including cloud detection, stray lightmasking, faulty detector avoidance, and dynamic aerosol correction using short-wave- and near-infrared wavebands in extremely turbid regions which pose distinct optical and technical challenges. Results showthat a pixel size of approx. 520 mor smaller is generally required to resolve spatial heterogeneity in ocean color and total suspended materials in river plumes. Optimal pixel size increases with distance from shore to approx. 630 m in nearshore regions, approx 750 m on the continental shelf, and approx. 1350 m in the open ocean. Greater than 90% of the optical variability within plume regions is resolvable with

  6. Geochemical characteristics of West Molokai shield- and postshield-stage lavas: Constraints on Hawaiian plume models

    Science.gov (United States)

    Xu, Guangping; Frey, Frederick A.; Clague, David A.; Abouchami, Wafa; Blichert-Toft, Janne; Cousens, Brian; Weisler, Marshall

    2007-08-01

    There are systematic geochemical differences between the Hawaiian shields forming the subparallel spatial trends, known as Loa and Kea. These spatial and temporal geochemical changes provide insight into the spatial distribution of geochemical heterogeneities within the source of Hawaiian lavas, and the processes that create the Hawaiian plume. Lavas forming the ˜1.9 Ma West Molokai volcano are important for evaluating alternative models proposed for the spatial distribution of geochemical heterogeneities because (1) the geochemical distinction between Loa and Kea trends may end at the Molokai Fracture Zone and (2) West Molokai is a Loa-trend volcano that has exposures of shield and postshield lavas. This geochemical study (major and trace element abundances and isotopic ratios of Sr, Nd, Hf, and Pb) shows that the West Molokai shield includes lavas with Loa- and Kea-like geochemical characteristics; a mixed Loa-Kea source is required. In contrast, West Molokai postshield lavas are exclusively Kea-like. This change in source geochemistry can be explained by the observed change in strike of the Pacific plate near Molokai Island so that as West Molokai volcano moved away from a mixed Loa-Kea source it sampled only the Kea side of a bilaterally zoned plume.

  7. Cooling tower plume - model and experiment

    Directory of Open Access Journals (Sweden)

    Cizek Jan

    2017-01-01

    Full Text Available The paper discusses the description of the simple model of the, so-called, steam plume, which in many cases forms during the operation of the evaporative cooling systems of the power plants, or large technological units. The model is based on semi-empirical equations that describe the behaviour of a mixture of two gases in case of the free jet stream. In the conclusion of the paper, a simple experiment is presented through which the results of the designed model shall be validated in the subsequent period.

  8. Numerical Modelling of Jets and Plumes

    DEFF Research Database (Denmark)

    Larsen, Torben

    1993-01-01

    -dimensional integral method to the general 3-dimensional solution of the Navier-Stokes equations. Also the predictive capabilities of the models are discussed. The presentation takes the perspective of civil engineering and covers issues like sewage outfalls and cooling water discharges to the sea.......An overview on numerical models for prediction of the flow and mixing processes in turbulent jets and plumes is given. The overview is structured to follow an increasing complexity in the physical and numerical principles. The various types of models are briefly mentioned, from the one...

  9. Low-buoyancy thermochemical plumes resolve controversy of classical mantle plume concept

    National Research Council Canada - National Science Library

    Dannberg, Juliane; Sobolev, Stephan V

    2015-01-01

    .... We demonstrate that, despite their low buoyancy, large enough thermochemical plumes can rise through the whole mantle causing only negligible surface uplift. Their tails are bulky (>200 km radius) and remain in the upper mantle for 100 millions of years....

  10. Heterogeneity and Microeconometrics Modelling

    DEFF Research Database (Denmark)

    Browning, Martin; Carro, Jesus

    Presented at the 2005 Econometric Society World Congress Plenary Session on "Modelling Heterogeneity". We survey the treatment of heterogeneity in applied microeconometrics analyses. There are three themes. First, there is usually much more heterogeneity than empirical researchers allow for. Second......, the inappropriate treatment of heterogeneity can lead to serious error when estimating outcomes of interest. Finally, once we move away from the traditional linear model with a single 'fixed effect', it is very difficult to account for heterogeneity and fit the data and maintain coherence with theory structures....... The latter task is one for economists: "heterogeneity is too important to be left to the statisticians". The paper concludes with a report of our own research on dynamic discrete choice models that allow for maximal heterogeneity...

  11. Modeling ozone plumes observed downwind of New York City over the North Atlantic Ocean during the ICARTT field campaign

    Directory of Open Access Journals (Sweden)

    S.-H. Lee

    2011-07-01

    Full Text Available Transport and chemical transformation of well-defined New York City (NYC urban plumes over the North Atlantic Ocean were studied using aircraft measurements collected on 20–21 July 2004 during the ICARTT (International Consortium for Atmospheric Research on Transport and Transformation field campaign and WRF-Chem (Weather Research and Forecasting-Chemistry model simulations. The strong NYC urban plumes were characterized by carbon monoxide (CO mixing ratios of 350–400 parts per billion by volume (ppbv and ozone (O3 levels of about 100 ppbv near New York City on 20 July in the WP-3D in-situ and DC-3 lidar aircraft measurements. On 21 July, the two aircraft captured strong urban plumes with about 350 ppbv CO and over 150 ppbv O3 (~160 ppbv maximum about 600 km downwind of NYC over the North Atlantic Ocean. The measured urban plumes extended vertically up to about 2 km near New York City, but shrank to 1–1.5 km over the stable marine boundary layer (MBL over the North Atlantic Ocean. The WRF-Chem model reproduced ozone formation processes, chemical characteristics, and meteorology of the measured urban plumes near New York City (20 July and in the far downwind region over the North Atlantic Ocean (21 July. The quasi-Lagrangian analysis of transport and chemical transformation of the simulated NYC urban plumes using WRF-Chem results showed that the pollutants can be efficiently transported in (isentropic layers in the lower atmosphere (<2–3 km over the North Atlantic Ocean while maintaining a dynamic vertical decoupling by cessation of turbulence in the stable MBL. The O3 mixing ratio in the NYC urban plumes remained at 80–90 ppbv during nocturnal transport over the stable MBL, then grew to over 100 ppbv by daytime oxidation of nitrogen oxides (NOx = NO + NO2 with mixing ratios on the order of 1 ppbv. Efficient transport of reactive nitrogen species (NOy, specifically nitric

  12. Chemistry in Our Life

    Indian Academy of Sciences (India)

    IAS Admin

    toothpaste, soaps and cosmetics, (7) plastics and polymers, (8) chemistry in health and disease, (9) chemistry of building, (10) fire chemistry and (11) chemistry of electricity. To write on these topics at a popular level for lay persons, without bringing in chemical for- mulas, structures or equations, is extremely difficult.

  13. SRS reactor stack plume marking tests

    Energy Technology Data Exchange (ETDEWEB)

    Petry, S.F.

    1992-03-01

    Tests performed in 105-K in 1987 and 1988 demonstrated that the stack plume can successfully be made visible (i.e., marked) by introducing smoke into the stack breech. The ultimate objective of these tests is to provide a means during an emergency evacuation so that an evacuee can readily identify the stack plume and evacuate in the opposite direction, thus minimizing the potential of severe radiation exposure. The EPA has also requested DOE to arrange for more tests to settle a technical question involving the correct calculation of stack downwash. New test canisters were received in 1988 designed to produce more smoke per unit time; however, these canisters have not been evaluated, because normal ventilation conditions have not been reestablished in K Area. Meanwhile, both the authorization and procedure to conduct the tests have expired. The tests can be performed during normal reactor operation. It is recommended that appropriate authorization and procedure approval be obtained to resume testing after K Area restart.

  14. Short-Term Variability in Enceladus' Plume

    Science.gov (United States)

    Spitale, Joseph N.; Hurford, Terry; Rhoden, Alyssa R.

    2017-10-01

    The density of solids in Enceladus' south-polar plume at altitudes above about 50 km has been observed to vary by a factor of three between Enceladus' periapse and apoapse. This variability of the combined plume on the orbital time scale supports a relation between tidal stress and combined eruptive activity, and contains information about how the fractures fail in an averaged sense, but local variability is still not understood.Here we report on a sequence of three Cassini images showing a single collimated jet transitioning from dormant to active during a period of a few minutes. In the first image, the jet is not visible; in the subsequent images, it is seen increasing to heights of order 100 km. Prior estimates of particle velocities have been based on observing the vertical brightness profiles of steady-state eruptions. The non-steady-state jet observations discussed here provide a different way of measuring velocities, as the rate of change in density at each altitude can be estimated (using appropriate photometric assumptions). Moreover, the timing and location of the eruption contain information about the failure mechanism leading to an eruption at this particular time and place.Other jets may also be observed activating at this time, but the detections are less certain.

  15. Channelization of plumes beneath ice shelves

    KAUST Repository

    Dallaston, M. C.

    2015-11-11

    © 2015 Cambridge University Press. We study a simplified model of ice-ocean interaction beneath a floating ice shelf, and investigate the possibility for channels to form in the ice shelf base due to spatial variations in conditions at the grounding line. The model combines an extensional thin-film description of viscous ice flow in the shelf, with melting at its base driven by a turbulent ocean plume. Small transverse perturbations to the one-dimensional steady state are considered, driven either by ice thickness or subglacial discharge variations across the grounding line. Either forcing leads to the growth of channels downstream, with melting driven by locally enhanced ocean velocities, and thus heat transfer. Narrow channels are smoothed out due to turbulent mixing in the ocean plume, leading to a preferred wavelength for channel growth. In the absence of perturbations at the grounding line, linear stability analysis suggests that the one-dimensional state is stable to initial perturbations, chiefly due to the background ice advection.

  16. Laboratory Study of Dispersion of Buoyant Surface Plumes

    DEFF Research Database (Denmark)

    Petersen, Ole; Larsen, Torben

    1990-01-01

    A laboratory a study on surface dispersion of buoyant plumes in open channel turbulence in made, where the buoyancy is due to both salinity and heat. The measured parameters are the downstream derivative of a plume width and height, which are integral-characteristics of the distributions of density...

  17. Snowfall observations from natural-draft cooling tower plumes.

    Science.gov (United States)

    Kramer, M L; Seymour, D E; Smith, M E; Reeves, R W; Frankenberg, T T

    1976-09-24

    During the winter of 1975-1976, snowfall from the plumes of large natural-draft cooling towers of power plants has been observed. Snow accumulations up to 2.5 centimeters have been found on the ground at extended distances from the cooling towers, and visibility has been restricted to less than 1600 meters in the tower plume near ground level.

  18. Redox zones of a landfill leachate pollution plume (Vejen, Denmark)

    DEFF Research Database (Denmark)

    Lyngkilde, John; Christensen, Thomas Højlund

    1992-01-01

    , ferrogenic, nitrate-reducing and aerobic environments overa distance of 370 m. This redox zone sequence is consistent with thermodynamical principles and is closely matched by the leachate plume determined by the chloride plume distribution. The redox zone sequence is believed to be key in controlling...... the fate of reactive pollutants leached from the landfill....

  19. Imaging mantle plumes with instantaneous phase measurements of diffracted waves

    NARCIS (Netherlands)

    Rickers, F.; Fichtner, A.; Trampert, J.

    2012-01-01

    In a synthetic tomographic experiment, we succeeded to recover an idealized narrow mantle plume reaching deep into the lower mantle by using a misfit based on the instantaneous phase difference. A misfit based on simple cross-correlation traveltime shifts leaves the lower mantle part of the plume

  20. Morphology of the Zambezi River plume in the Sofala Bank ...

    African Journals Online (AJOL)

    The sampling plan called for 73 CTD stations that were interspersed with sampling of shrimp recruitment. ... had not been explored sufficiently in previous studies and it puts the Zambezi River plume in a short list of plumes across the globe that propagates in the direction opposite to the sense of a Kelvin or a shelf wave.

  1. Validation of smoke plume rise models using ground based lidar

    Science.gov (United States)

    Cyle E. Wold; Shawn Urbanski; Vladimir Kovalev; Alexander Petkov; Wei Min Hao

    2010-01-01

    Biomass fires can significantly degrade regional air quality. Plume rise height is one of the critical factors determining the impact of fire emissions on air quality. Plume rise models are used to prescribe the vertical distribution of fire emissions which are critical input for smoke dispersion and air quality models. The poor state of model evaluation is due in...

  2. Mantle plumes - A boundary layer approach for Newtonian and non-Newtonian temperature-dependent rheologies. [modeling for island chains and oceanic aseismic ridges

    Science.gov (United States)

    Yuen, D. A.; Schubert, G.

    1976-01-01

    Stress is placed on the temperature dependence of both a linear Newtonian rheology and a nonlinear olivine rheology in accounting for narrow mantle flow structures. The boundary-layer theory developed incorporates an arbitrary temperature-dependent power-law rheology for the medium, in order to facilitate the study of mantle plume dynamics under real conditions. Thermal, kinematic, and dynamic structures of mantle plumes are modelled by a two-dimensional natural-convection boundary layer rising in a fluid with a temperature-dependent power-law relationship between shear stress and strain rate. An analytic similarity solution is arrived at for upwelling adjacent to a vertical isothermal stress-free plane. Newtonian creep as a deformation mechanism, thermal anomalies resulting from chemical heterogeneity, the behavior of plumes in non-Newtonian (olivine) mantles, and differences in the dynamics of wet and dry olivine are discussed.

  3. Determining resolvability of mantle plumes with synthetic seismic modeling

    Science.gov (United States)

    Maguire, R.; Van Keken, P. E.; Ritsema, J.; Fichtner, A.; Goes, S. D. B.

    2014-12-01

    Hotspot volcanism in locations such as Hawaii and Iceland is commonly thought to be associated with plumes rising from the deep mantle. In theory these dynamic upwellings should be visible in seismic data due to their reduced seismic velocity and their effect on mantle transition zone thickness. Numerous studies have attempted to image plumes [1,2,3], but their deep mantle origin remains unclear. In addition, a debate continues as to whether lower mantle plumes are visible in the form of body wave travel time delays, or whether such delays will be erased due to wavefront healing. Here we combine geodynamic modeling of mantle plumes with synthetic seismic waveform modeling in order to quantitatively determine under what conditions mantle plumes should be seismically visible. We model compressible plumes with phase changes at 410 km and 670 km, and a viscosity reduction in the upper mantle. These plumes thin from greater than 600 km in diameter in the lower mantle, to 200 - 400 km in the upper mantle. Plume excess potential temperature is 375 K, which maps to seismic velocity reductions of 4 - 12 % in the upper mantle, and 2 - 4 % in the lower mantle. Previous work that was limited to an axisymmetric spherical geometry suggested that these plumes would not be visible in the lower mantle [4]. Here we extend this approach to full 3D spherical wave propagation modeling. Initial results using a simplified cylindrical plume conduit suggest that mantle plumes with a diameter of 1000 km or greater will retain a deep mantle seismic signature. References[1] Wolfe, Cecily J., et al. "Seismic structure of the Iceland mantle plume." Nature 385.6613 (1997): 245-247. [2] Montelli, Raffaella, et al. "Finite-frequency tomography reveals a variety of plumes in the mantle." Science 303.5656 (2004): 338-343. [3] Schmandt, Brandon, et al. "Hot mantle upwelling across the 660 beneath Yellowstone." Earth and Planetary Science Letters 331 (2012): 224-236. [4] Hwang, Yong Keun, et al

  4. Evidences for recent plume-induced subduction, microplates and localized lateral plate motions on Venus

    Science.gov (United States)

    Davaille, Anne; Smrekar, Suzanne

    2017-04-01

    Using laboratory experiments and theoretical modeling, we recently showed that plumes could induce roll-back subduction around large coronae. When a hot plume rises under a brittle and visco-elasto-plastic skin/lithosphere, the latter undergoes a flexural deformation which puts it under tension. Radial cracks and rifting of the skin then develop, sometimes using pre-existing weaknesses. Plume material upwells through the cracks (because it is more buoyant) and spreads as a axisymmetric gravity current above the broken denser skin. The latter bends and sinks under the combined force of its own weight and that of the plume gravity current. However, due to the brittle character of the upper part of the experimental lithosphere, it cannot deform viscously to accomodate the sinking motions. Instead, the plate continues to tear, as a sheet of paper would do upon intrusion. Several slabs are therefore produced, associated with trenches localized along partial circles on the plume, and strong roll-back is always observed. Depending on the lithospheric strength, roll-back can continue and triggers a complete resurfacing, or it stops when the plume stops spreading. Two types of microplates are also observed. First, the upwelling plume material creates a set of new plates interior to the trench segments. These plates move rapidly and expand through time, but do not subduct.. In a few cases, we also observe additional microplates exterior to the trenches. This happens when the subducting plate contains preexisting heterogeneities (e.g. fractures) and the subducted slab is massive enough for slab pull to become efficient and induce horizontal plate motions. Scalings derived from the experiments suggest that Venus lithosphere is soft enough to undergo such a regime. And indeed, at least two candidates can be identified on Venus, where plume-induced subduction could have operated. (1) Artemis Coronae is the largest (2300 km across) coronae on Venus and is bounded over 270° of

  5. West Antarctic Mantle Plume Hypothesis and Basal Water Generation

    Science.gov (United States)

    Ivins, Erik; Seroussi, Helene; Wiens, Doug; Bondzio, Johannes

    2017-04-01

    The hypothesis of a deep mantle plume that manifests Pliocene and Quaternary volcanism and present-day seismicity in West Antarctica has been speculated for more than 30 years. Recent seismic images support the plume hypothesis as the cause of Marie Byrd Land (MBL) volcanism and geophysical structure [ Lloyd et al., 2015; Ramirez et al., 2016]. Mantle plumes can more that double the geothermal heat flux, qGHF, above nominal continental values at their axial peak position and raise qGHF in the surrounding plume head to 60 mW/m2 or higher. Unfortunately, there is a dearth of in-situ basal ice sheet data that sample the heat flux. Consequently, we examine a realistic distribution of heat flux associated with a late-Cenozoic mantle plume in West Antarctica and explore its impact on thermal and melt conditions near the ice sheet base. The solid Earth model assumes a parameterized deep mantle plume and head. The 3-D ice flow model includes an enthalpy framework and full-Stokes stress balance. Both the putative plume location and extent are uncertain. Therefore, we perform broadly scoped experiments to characterize plume related basal conditions. The experiments show that mantle plumes have an important local impact on the ice sheet, with basal melting rates reaching several centimeters per year directly above the hotspot. The downstream active lake system of Whillans Ice Stream suggests a rift-related source of anomalous mantle heat. However, the lack of lake and stream activity in MBL suggests a relatively weak plume: one that delivers less flux by 35% below the heat flux to the crustal surface at the site of the Yellowstone hotspot [e.g., DeNosaquo et al., 2009], with peak value no higher than about 145 mW/m2.

  6. Integrated Numerical Model for the East African Rift System: Plume-induced Rifting and Continental Break-up from Lake Malawi to Red Sea

    Science.gov (United States)

    Koptev, A.; Leroy, S. D.; Calais, E.; Gerya, T.

    2016-12-01

    We present numerical experiments that target to reveal the role of active mantle plume, far-field tectonic forces and pre-existing lithospheric heterogeneities in structural development of the East African Rift system (EARS). Starting with models capturing the essential geophysical features of the central and southern parts of the EARS (two «cratonic» bodies (Tanzanian craton and Bangweulu block) embedded into a «normal» surrounding lithosphere) we show that development of the magmatic Eastern branch, the amagmatic Western branch and its southern prolongation (Malawi rift) can be the result of non-uniform splitting of some hot plume material that has been initially seeded underneath the southern part of Tanzanian craton. The second series of experiments has been designed in order to investigate northern segment of the EARS where Afro-Arabian plate separation is supposed to be related with the impact of Afar mantle plume. These models permit us to reproduce observed orientation and relative position of two spreading axes (Red Sea, Gulf of Aden) and rifting (Main Ethiopian rift) one. All are joining at Afar triple junction. Finally, for laterally extended experiment we have used parameters of the best-fit models for the southern and northern segments of the EARS in order to define the position of Kenyan plume and the velocity boundary conditions. This model cover all rifting and spreading structure associated with both Afar and Kenyan plumes: Red Sea Rift and the Aden Ridge to the north of the Afar Triple Junction; Main Ethiopian Rift running to the south that continues as the Kenyan Rift; Western Rift and its southern prolongation corresponding to Malawi rift.We argue that main features of the EARS can be reproduced in a relatively simple context of the interaction between two mantle anomalies corresponding to Afar and Kenyan plumes and pre-stressed rheologically stratified continental lithosphere containing only first-order structural heterogeneities (such as

  7. Green chemistry: A tool in Pharmaceutical Chemistry

    OpenAIRE

    Smita Talaviya; Falguni Majumdar

    2012-01-01

    Green chemistry expresses an area of research developing from scientific discoveries about pollution awareness and it utilizes a set of principles that reduces or eliminates the use or generation of hazardous substances in all steps of particular synthesis or process. Chemists and medicinal scientists can greatly reduce the risk to human health and the environment by following all the valuable principles of green chemistry. The most simple and direct way to apply green chemistry in pharmaceut...

  8. [Tumor genetic heterogeneity].

    Science.gov (United States)

    Yang, Yi-Ling; Chu, Jia-You; Wang, Ming-Rong

    2013-01-01

    Although the majority of spontaneous tumors derive from a single cell, people have come to realize intra-tumor heterogeneity of individual tumors. Human cancers frequently display substantial difference in phenotypic features, such as the degree of differentiation, cell proliferation rate, invasion and metastatic potential, response to therapy and many other aspects. Molecular biology studies have confirmed the occurrence of new mutations during the process of tumor progression, which provide more powerful evidences to show the existence of intra-tumor genetic heterogeneity. This re-view will focus on recent major advances in the study of tumor genetic heterogeneity. Considering that genetic heterogene-ity analysis can provide important information to indicate how long normal cells transform into tumor cells and how to spread and migrate, we firstly describe experimental evidences of intra-tumor genetic heterogeneity. Then we discuss the research value of genetic diversity in the evolutionary history of human individual tumor, introduce the two modes of the genetic heterogeneity - cancer stem cell model and the clonal evolution model, and summarize the implications of in-tra-tumor heterogeneity studies in metastasis and therapy. In addition, the article presents the research methods of genetic heterogeneity, including specific gene and genome-wide level, pointing out their strengths and limitations.

  9. New directions: Mineral dust and ozone - Heterogeneous chemistry

    Science.gov (United States)

    Ramachandran, S.

    2015-04-01

    Aerosols, the tiny solid or liquid particles suspended in air and produced from natural sources and anthropogenic activities, continue to contribute the largest uncertainty to radiative forcing (IPCC, 2013). Aerosol particles give rise to radiative forcing directly through scattering and absorption of solar and infrared radiation in the atmosphere. Aerosols also give rise to indirect radiative forcing by modifying the cloud optical properties and lifetimes. Among the aerosol species mineral dust and black carbon cause a warming (positive forcing) while sulphate and sea salt cause a cooling (negative forcing) of the Earth-atmosphere system. In tropics and sub-tropics mineral dust is a major contributor to aerosol loading and optical thickness. The global source strength of dust aerosol varies significantly on spatial and temporal scales. The source regions of dust are mainly deserts, dry lake beds, and semi-arid regions, in addition to drier regions where vegetation has been reduced or soil surfaces that are disturbed by man made activities. Anthropogenic activities mainly related to agriculture such as harvesting, ploughing, overgrazing, and cement production and transport also produce mineral dust. An estimated 2500 terragram (Tg, 1012 g) of mineral dust is emitted into the atmosphere per year, and dominates the aerosol mass over continental regions in south Asia and China accounting for ∼35% of the total aerosol mass (IPCC, 2013). In India, dust is prevalent throughout the north and western India during the year and peaks during premonsoon season.

  10. Heterogeneous chemistry of trichloroacetyl chloride in the atmosphere

    Energy Technology Data Exchange (ETDEWEB)

    George, C.; Mirabel, P.; Ponche, J.L. [Laboratoire de Physico-Chimie de l`Atmosphere, Strasbourg (France); Lagrange, J.; Lagrange, P.; Pallares, C. [Laboratoire de Cinetique et Analyse, Strasbourg (France)

    1994-01-20

    This article investigates the effects of anthropogenic releases of partially and fully halogenated hydrocarbons on the stratospheric ozone layer. Experiments using direct measurements of the reaction rates of hydrolysis and direct uptake of trichloroacetyl chlorides by water droplets are described. 32 refs., 9 figs., 3 tabs.

  11. Hydraulic Conductivity Estimates from Particle Size Distributions of Sediments from the Los Alamos Chromium Plume

    Science.gov (United States)

    Harris, R.; Reimus, P. W.; Ding, M.

    2015-12-01

    Chromium used in Los Alamos National Laboratory cooling towers was released as effluent onto laboratory property between 1956 and 1972. As a result, the underlying regional aquifer is contaminated with chromium (VI), a toxin and carcinogen. The highest concentration of chromium is ~1 ppm in monitoring well R-42, exceeding the New Mexico drinking water standard of 50 ppb. The chromium plume is currently being investigated to identify an effective remediation method. Geologic heterogeneity within the aquifer causes the hydraulic conductivity within the plume to be spatially variable. This variability, particularly with depth, is crucial for predicting plume transport behavior. Though pump tests are useful for obtaining estimates of site specific hydraulic conductivity, they tend to interrogate hydraulic properties of only the most conductive strata. Variations in particle size distribution as a function of depth can complement pump test data by providing estimates of vertical variations in hydraulic conductivity. Samples were collected from five different sonically-drilled core holes within the chromium plume at depths ranging from 732'-1125' below the surface. To obtain particle size distributions, the samples were sieved into six different fractions from the fine sands to gravel range (>4 mm, 2-4 mm, 1.4-2 mm, 0.355-1.4 mm, 180-355 µm, and smaller than 180 µm). The Kozeny-Carmen equation (k=(δg/µ)(dm2/180)(Φ3/(1-Φ)2)), was used to estimate permeability from the particle size distribution data. Pump tests estimated a hydraulic conductivity varying between 1 and 50 feet per day. The Kozeny-Carmen equation narrowed this estimate down to an average value of 2.635 feet per day for the samples analyzed, with a range of 0.971 ft/day to 6.069 ft/day. The results of this study show that the Kozeny-Carmen equation provides quite specific estimates of hydraulic conductivity in the Los Alamos aquifer. More importantly, it provides pertinent information on the expected

  12. Frontiers in Atmospheric Chemistry Modelling

    Science.gov (United States)

    Colette, Augustin; Bessagnet, Bertrand; Meleux, Frederik; Rouïl, Laurence

    2013-04-01

    The first pan-European kilometre-scale atmospheric chemistry simulation is introduced. The continental-scale air pollution episode of January 2009 is modelled with the CHIMERE offline chemistry-transport model with a massive grid of 2 million horizontal points, performed on 2000 CPU of a high performance computing system hosted by the Research and Technology Computing Center at the French Alternative Energies and Atomic Energy Commission (CCRT/CEA). Besides the technical challenge, which demonstrated the robustness of the selected air quality model, we discuss the added value in terms of air pollution modelling and decision support. The comparison with in-situ observations shows that model biases are significantly improved despite some spurious added spatial variability attributed to shortcomings in the emission downscaling process and coarse resolution of the meteorological fields. The increased spatial resolution is clearly beneficial for the detection of exceedances and exposure modelling. We reveal small scale air pollution patterns that highlight the contribution of city plumes to background air pollution levels. Up to a factor 5 underestimation of the fraction of population exposed to detrimental levels of pollution can be obtained with a coarse simulation if subgrid scale correction such as urban increments are ignored. This experiment opens new perspectives for environmental decision making. After two decades of efforts to reduce air pollutant emissions across Europe, the challenge is now to find the optimal trade-off between national and local air quality management strategies. While the first approach is based on sectoral strategies and energy policies, the later builds upon new alternatives such as urban development. The strategies, the decision pathways and the involvement of individual citizen differ, and a compromise based on cost and efficiency must be found. We illustrated how high performance computing in atmospheric science can contribute to this

  13. Citizen CATE Experiment and Polar Plume Dynamics

    Science.gov (United States)

    Mitchell, Adriana; Penn, Matt; Baer, Robert; Bosh, Robert; Garrison, David; Gelderman, Richard; Hare, Honor; Isberner, Fred; Jensen, Logan; Kovac, Sarah; McKay, Myles; Pierce, Michael; Thompson, Patricia; Ursache, Andrei; Varsik, John R.; Walter, Donald; Watson, Zachary; Young, David; Citizen CATE Team

    2017-01-01

    During the summer of 2017, a total solar eclipse will pass over the continental United States, allowing millions of citizens the opportunity to experience a beautiful celestial event. The Citizen Continental-America Telescopic Eclipse (CATE) Experiment plans to harness the power of these many viewers by using volunteers from sites across the US to observe and record the total solar eclipse. The data acquired from each of these sites will be composed into a continuous 90-minute video, allowing the inner solar corona to be studied for an unprecedented length of time.Observations in Indonesia of the March 2016 total solar eclipse allowed initial testing and analysis of the inner corona polar plume dynamics. Using MATLAB, a routine was developed to identify the polar coronal threads and their angle relative to the radial direction to analyze the field line behavior at the boundary of the polar coronal holes.

  14. Identification of discontinuities in plasma plume evolution

    CERN Document Server

    Gojani, Ardian B; Obayashi, Shigeru

    2013-01-01

    The ejection of material during laser ablation gives rise to the development of discontinuities in the ambient gas. Several of these discontinuities are observed and characterized, including externally and internally propagating shock waves, contact surface, and the ionization front. Qualitative experimental observations and analysis of these discontinuities is presented. Results from shadowgraphy enabled determination of an irradiance threshold between two different ablation mechanisms, and determination of several stages of plasma plume evolution. Consideration of the refractive index as a dynamic sum of the contributions from gas and electrons led to separate identification of ionization front from the contact surface. Furthermore, ionization front was observed to lead the shock wave at the earlier stage of the ablation.

  15. Reaction front formation in contaminant plumes.

    Science.gov (United States)

    Cribbin, Laura B; Winstanley, Henry F; Mitchell, Sarah L; Fowler, Andrew C; Sander, Graham C

    2014-12-15

    The formation of successive fronts in contaminated groundwater plumes by subsoil bacterial action is a commonly accepted feature of their propagation, but it is not obviously clear from a mathematical standpoint quite how such fronts are formed or propagate. In this paper we show that these can be explained by combining classical reaction-diffusion theory involving just two reactants (oxidant and reductant), and a secondary reaction in which a reactant on one side of such a front is (re-)formed on the other side of the front via diffusion of its product across the front. We give approximate asymptotic solutions for the reactant profiles, and the propagation rate of the front. Copyright © 2014 Elsevier B.V. All rights reserved.

  16. Plume dynamics and shielding by the ablation plume during Er:YAG laser ablation.

    Science.gov (United States)

    Nahen, Kester; Vogel, Alfred

    2002-04-01

    Free-running Er:YAG lasers are used for precise tissue ablation in various clinical applications. The ablated material is ejected into the direction perpendicular to the tissue surface. We investigated the influence of shielding by the ablation plume on the energy deposition into an irradiated sample because it influences the ablation dynamics and the amount of material ablated. The investigations were performed using an Er:YAG laser with a pulse duration of 200 micros for the ablation of gelatin with different water contents, skin, and water. Laser flash photography combined with a dark field Schlieren technique was used to visualize gaseous and particulate ablation products, and to measure the distance traveled by the ablating laser beam through the ablation plume at various times after the beginning of the laser pulse. The temporal evolution of the transmission through the ablation plume was probed using a second free running Er:YAG laser beam directed parallel to the sample's surface. The ablation dynamics was found to consist of a vaporization phase followed by material ejection. The observation of droplet ejection during water ablation provided evidence that a phase explosion is the driving mechanism for material ejection. The laser light transmission was only slightly reduced by the vapor plume, but decreased by 25%-50% when the ejected material passed the probe beam. At radiant exposures approximately 10 times above the ablation threshold, the laser energy deposited into the sample amounted to only 61% of the incident energy for gelatin samples with 90% water content and to 86% for skin samples. For free-running Er:YAG laser pulses shielding must therefore be considered in modeling the ablation dynamics and determining the dosage for clinical applications.

  17. Plume propagation direction determination with SO2 cameras

    Science.gov (United States)

    Klein, Angelika; Lübcke, Peter; Bobrowski, Nicole; Kuhn, Jonas; Platt, Ulrich

    2017-03-01

    SO2 cameras are becoming an established tool for measuring sulfur dioxide (SO2) fluxes in volcanic plumes with good precision and high temporal resolution. The primary result of SO2 camera measurements are time series of two-dimensional SO2 column density distributions (i.e. SO2 column density images). However, it is frequently overlooked that, in order to determine the correct SO2 fluxes, not only the SO2 column density, but also the distance between the camera and the volcanic plume, has to be precisely known. This is because cameras only measure angular extents of objects while flux measurements require knowledge of the spatial plume extent. The distance to the plume may vary within the image array (i.e. the field of view of the SO2 camera) since the plume propagation direction (i.e. the wind direction) might not be parallel to the image plane of the SO2 camera. If the wind direction and thus the camera-plume distance are not well known, this error propagates into the determined SO2 fluxes and can cause errors exceeding 50 %. This is a source of error which is independent of the frequently quoted (approximate) compensation of apparently higher SO2 column densities and apparently lower plume propagation velocities at non-perpendicular plume observation angles.Here, we propose a new method to estimate the propagation direction of the volcanic plume directly from SO2 camera image time series by analysing apparent flux gradients along the image plane. From the plume propagation direction and the known location of the SO2 source (i.e. volcanic vent) and camera position, the camera-plume distance can be determined. Besides being able to determine the plume propagation direction and thus the wind direction in the plume region directly from SO2 camera images, we additionally found that it is possible to detect changes of the propagation direction at a time resolution of the order of minutes. In addition to theoretical studies we applied our method to SO2 flux

  18. The dominant effect of alumina on nearfield plume radiation

    Science.gov (United States)

    Laredo, David; Netzer, David W.

    1993-11-01

    Solid propellant rocket motors can achieve high specific impulse with metal fuel additives such as aluminum. Combustion of aluminum produces condensed alumina particles. Besides causing performance losses in the nozzle, the condensed Al2O3 particles are the major source of primary smoke in the exhaust plume. The particulate matter can also have major effects upon the plume i.r. signature. High number densities of particles can block gas-phase radiation from the plume. They can also be the source of radiation, especially the larger particles which exit the nozzle not in thermal equilibrium with the gas. In the past, the expected effects of particle size on the plume i.r. signature have been determined almost exclusively from predictions made with flow and radiation codes. The aim of the present work was to investigate the role of the Al/Al2O3 particles from a highly loaded solid propellant (up to 16% in weight) on the plume radiation of a small rocket motor (5 cm in diameter). The spatial variation of particle size distribution was simultaneously measured with the overall radiation of a portion of the plume in the i.r. band (3.5-5.0 microns). In micro-motors, operating with highly aluminized solid propellant, the condensed particles in the near exhaust plume were the major source of radiation in the 3.5-5 micron wavelength band. Motors with longer residence time and operating at medium chamber pressures produced more particles in the micron sized range. The role of after burning was predominately confined to reheating of the alumina particles to a higher temperature, at which the condensed Al2O3 radiated more than gaseous species. Even with 30% Al2O3 in the plume, the plume of small motors can be considered as approximately conical in shape, with volume distributed radiating sources. Motor conditions producing larger particles in the plume core were thus found to increase plume radiation from that region. The overall apparent emissivity of the plume was between 0

  19. Detecting Volcanic Ash Plumes with GNSS Signals

    Science.gov (United States)

    Rainville, N.; Larson, K. M.; Palo, S. E.; Mattia, M.; Rossi, M.; Coltelli, M.; Roesler, C.; Fee, D.

    2016-12-01

    Global Navigation Satellite Systems (GNSS) receivers are commonly placed near volcanic sites to measure ground deformation. In addition to the carrier phase data used to measure ground position, these receivers also record Signal to Noise ratio (SNR) data. Larson (2013) showed that attenuations in SNR data strongly correlate with ash emissions at a series of eruptions of Redoubt Volcano. This finding has been confirmed at eruptions for Tongariro, Mt Etna, Mt Shindake, and Sakurajima. In each of these detections, very expensive geodetic quality GNSS receivers were used. If low-cost GNSS instruments could be used instead, a networked array could be deployed and optimized for plume detection and tomography. The outputs of this sensor array could then be used by both local volcanic observatories and Volcano Ash Advisory Centers. Here we will describe progress in developing such an array. The sensors we are working with are intended for navigation use, and thus lack the supporting power and communications equipment necessary for a networked system. Reliably providing those features is major challenge for the overall sensor design. We have built prototypes of our Volcano Ash Plume Receiver (VAPR), with solar panels, lithium-ion batteries and onboard data storage for preliminary testing. We will present results of our field tests of both receivers and antennas. A second critical need for our array is a reliable detection algorithm. We have tested our algorithm on data from recent eruptions and have incorporated the noise characteristics of the low-cost GNSS receiver. We have also developed a simulation capability so that the receivers can be deployed to optimize vent crossing GNSS signals.

  20. Dust Plume off the Coast of Egypt

    Science.gov (United States)

    2007-01-01

    Dwarfing the Nile, a river of dust flowed out of the deserts of northern Egypt on May 19, 2007. As the Moderate Resolution Imaging Spectroradiometer (MODIS) on NASA's Terra satellite passed overhead at 12:05 p.m. local time in Cairo, the sensor captured this image of the dust spreading northward over the Mediterranean Sea from the sandy deserts that span the country. At the margins of the plume, ribbons and ripples of dust are translucent, allowing a glimpse of the desert and water beneath, but in the center, the cloud is opaque, revealing nothing of the surface below. The part of north-central Egypt hidden by the dust plume is the Qattara Depression, the country's lowest point. Dipping down to 133 meters below sea level (436 feet), the depression is home to sandy deserts and dry lake beds that occasionally flood. The sand and fine, lake bed sediments are easily lofted into the air by strong winds that scour the area in late winter and early spring. In the eastern (right-hand) part of the image, the Nile River is lined by narrow ribbons of dull green vegetation. The fan-shaped delta is dotted with tan-colored spots, marking the location of cities and towns. The Nile Valley and Delta make up only a small fraction of the country's total land area, yet they support almost the entire population. The large image provided above has a spatial resolution (level of detail) of 250 meters per pixel. The MODIS Rapid Response Team provides this image in additional resolutions. The Earth Observatory also provides a 250-meter-resolution KMZ file of this image for use with Google Earth.

  1. Learning to rapidly re-contact the lost plume in chemical plume tracing.

    Science.gov (United States)

    Cao, Meng-Li; Meng, Qing-Hao; Wang, Jia-Ying; Luo, Bing; Jing, Ya-Qi; Ma, Shu-Gen

    2015-03-27

    Maintaining contact between the robot and plume is significant in chemical plume tracing (CPT). In the time immediately following the loss of chemical detection during the process of CPT, Track-Out activities bias the robot heading relative to the upwind direction, expecting to rapidly re-contact the plume. To determine the bias angle used in the Track-Out activity, we propose an online instance-based reinforcement learning method, namely virtual trail following (VTF). In VTF, action-value is generalized from recently stored instances of successful Track-Out activities. We also propose a collaborative VTF (cVTF) method, in which multiple robots store their own instances, and learn from the stored instances, in the same database. The proposed VTF and cVTF methods are compared with biased upwind surge (BUS) method, in which all Track-Out activities utilize an offline optimized universal bias angle, in an indoor environment with three different airflow fields. With respect to our experimental conditions, VTF and cVTF show stronger adaptability to different airflow environments than BUS, and furthermore, cVTF yields higher success rates and time-efficiencies than VTF.

  2. Learning to Rapidly Re-Contact the Lost Plume in Chemical Plume Tracing

    Directory of Open Access Journals (Sweden)

    Meng-Li Cao

    2015-03-01

    Full Text Available Maintaining contact between the robot and plume is significant in chemical plume tracing (CPT. In the time immediately following the loss of chemical detection during the process of CPT, Track-Out activities bias the robot heading relative to the upwind direction, expecting to rapidly re-contact the plume. To determine the bias angle used in the Track-Out activity, we propose an online instance-based reinforcement learning method, namely virtual trail following (VTF. In VTF, action-value is generalized from recently stored instances of successful Track-Out activities. We also propose a collaborative VTF (cVTF method, in which multiple robots store their own instances, and learn from the stored instances, in the same database. The proposed VTF and cVTF methods are compared with biased upwind surge (BUS method, in which all Track-Out activities utilize an offline optimized universal bias angle, in an indoor environment with three different airflow fields. With respect to our experimental conditions, VTF and cVTF show stronger adaptability to different airflow environments than BUS, and furthermore, cVTF yields higher success rates and time-efficiencies than VTF.

  3. Learning to Rapidly Re-Contact the Lost Plume in Chemical Plume Tracing

    Science.gov (United States)

    Cao, Meng-Li; Meng, Qing-Hao; Wang, Jia-Ying; Luo, Bing; Jing, Ya-Qi; Ma, Shu-Gen

    2015-01-01

    Maintaining contact between the robot and plume is significant in chemical plume tracing (CPT). In the time immediately following the loss of chemical detection during the process of CPT, Track-Out activities bias the robot heading relative to the upwind direction, expecting to rapidly re-contact the plume. To determine the bias angle used in the Track-Out activity, we propose an online instance-based reinforcement learning method, namely virtual trail following (VTF). In VTF, action-value is generalized from recently stored instances of successful Track-Out activities. We also propose a collaborative VTF (cVTF) method, in which multiple robots store their own instances, and learn from the stored instances, in the same database. The proposed VTF and cVTF methods are compared with biased upwind surge (BUS) method, in which all Track-Out activities utilize an offline optimized universal bias angle, in an indoor environment with three different airflow fields. With respect to our experimental conditions, VTF and cVTF show stronger adaptability to different airflow environments than BUS, and furthermore, cVTF yields higher success rates and time-efficiencies than VTF. PMID:25825974

  4. Role of Atmospheric Chemistry in the Climate Impacts of Stratospheric Volcanic Injections

    Science.gov (United States)

    Legrande, Allegra N.; Tsigaridis, Kostas; Bauer, Susanne E.

    2016-01-01

    The climate impact of a volcanic eruption is known to be dependent on the size, location and timing of the eruption. However, the chemistry and composition of the volcanic plume also control its impact on climate. It is not just sulfur dioxide gas, but also the coincident emissions of water, halogens and ash that influence the radiative and climate forcing of an eruption. Improvements in the capability of models to capture aerosol microphysics, and the inclusion of chemistry and aerosol microphysics modules in Earth system models, allow us to evaluate the interaction of composition and chemistry within volcanic plumes in a new way. These modeling efforts also illustrate the role of water vapor in controlling the chemical evolution, and hence climate impacts, of the plume. A growing realization of the importance of the chemical composition of volcanic plumes is leading to a more sophisticated and realistic representation of volcanic forcing in climate simulations, which in turn aids in reconciling simulations and proxy reconstructions of the climate impacts of past volcanic eruptions. More sophisticated simulations are expected to help, eventually, with predictions of the impact on the Earth system of any future large volcanic eruptions.

  5. Role of atmospheric chemistry in the climate impacts of stratospheric volcanic injections

    Science.gov (United States)

    Tsigaridis, Kostas; LeGrande, Allegra; Bauer, Susanne

    2017-04-01

    The climate impact of a volcanic eruption is known to be dependent on the size, location and timing of the eruption. However, the chemistry and composition of the volcanic plume also control its impact on climate. It is not just sulfur dioxide gas, but also the coincident emissions of water, halogens and ash that influence the radiative and climate forcing of an eruption. Improvements in the capability of models to capture aerosol microphysics, and the inclusion of chemistry and aerosol microphysics modules in Earth system models, allow us to evaluate the interaction of composition and chemistry within volcanic plumes in a new way. These modeling efforts also illustrate the role of water vapor in controlling the chemical evolution - and hence climate impacts - of the plume. A growing realization of the importance of the chemical composition of volcanic plumes is leading to a more sophisticated and realistic representation of volcanic forcing in climate simulations, which in turn aids in reconciling simulations and proxy reconstructions of the climate impacts of past volcanic eruptions. More sophisticated simulations are expected to help, eventually, with predictions of the impact on the Earth system of any future large volcanic eruptions. Such simulations will be presented, and the role of water in accelerating sulfate aerosol formation in the stratosphere will be demonstrated.

  6. Constitutional dynamic chemistry: bridge from supramolecular chemistry to adaptive chemistry.

    Science.gov (United States)

    Lehn, Jean-Marie

    2012-01-01

    Supramolecular chemistry aims at implementing highly complex chemical systems from molecular components held together by non-covalent intermolecular forces and effecting molecular recognition, catalysis and transport processes. A further step consists in the investigation of chemical systems undergoing self-organization, i.e. systems capable of spontaneously generating well-defined functional supramolecular architectures by self-assembly from their components, thus behaving as programmed chemical systems. Supramolecular chemistry is intrinsically a dynamic chemistry in view of the lability of the interactions connecting the molecular components of a supramolecular entity and the resulting ability of supramolecular species to exchange their constituents. The same holds for molecular chemistry when the molecular entity contains covalent bonds that may form and break reversibility, so as to allow a continuous change in constitution by reorganization and exchange of building blocks. These features define a Constitutional Dynamic Chemistry (CDC) on both the molecular and supramolecular levels.CDC introduces a paradigm shift with respect to constitutionally static chemistry. The latter relies on design for the generation of a target entity, whereas CDC takes advantage of dynamic diversity to allow variation and selection. The implementation of selection in chemistry introduces a fundamental change in outlook. Whereas self-organization by design strives to achieve full control over the output molecular or supramolecular entity by explicit programming, self-organization with selection operates on dynamic constitutional diversity in response to either internal or external factors to achieve adaptation.The merging of the features: -information and programmability, -dynamics and reversibility, -constitution and structural diversity, points to the emergence of adaptive and evolutive chemistry, towards a chemistry of complex matter.

  7. Silica-Supported Yttrium Nitrate Hexahydrate as a Heterogeneous ...

    African Journals Online (AJOL)

    NICO

    Silica-Supported Yttrium Nitrate Hexahydrate as a. Heterogeneous Catalyst for the Synthesis of. 2-Amino-4H-Chromenes in Water. Bahador Karami*, Mahnaz Farahi, Masoomeh Bazrafshan and Saeed Khodabakhshi. Department of Chemistry, Yasouj University, Yasouj 75918-74831, Iran. Recieved 4 February 2014, ...

  8. Exploring tumor heterogeneity

    NARCIS (Netherlands)

    Fessler, E.

    2016-01-01

    Cancer is a heterogeneous disease, which is reflected both on the cellular and the population level. Advances in detection, diagnosis, and treatment of malignancies have increased survival time of cancer patients; yet, the heterogeneity observed within and between tumors complicates accurate

  9. NW Iberia Shelf Dynamics. Study of the Douro River Plume.

    Directory of Open Access Journals (Sweden)

    Isabel Iglesias

    2014-06-01

    Full Text Available River plumes are one of the most important mechanisms that transport the terrestrial materials to the coast and the ocean. Some examples of those materials are pollutants, essential nutrients, which enhance the phytoplankton productivity or sediments, which settle on the seabed producing modifications on the bathymetry affecting the navigation channels. The mixing between the riverine and the oceanic waters can induce instabilities, which might generate bulges, filaments, and buoyant currents over the continental shelf. Offshore, the buoyant riverine water could form a front with the oceanic waters often related with the occurrence of current-jets, eddies and strong mixing. The study and modelling of the river plumes is a key factor for the complete understanding of sediment transport mechanisms and patterns, and of coastal physics and dynamic processes. On this study the Douro River plume will be simulated. The Douro River is located on the north-west Iberian coast and its daily averaged freshwater discharge can range values from 0 to 13000 m3/s. This variability impacts the formation of the river plumes and its dispersion along the continental shelf. This study builds on the long-term objective of generate a Douro River plume forecasting system as part of the RAIA and RAIA.co projects. Satellite imagery was analyzed showing that the river Douro is one of the main sources of suspended particles, dissolved material and chlorophyll in the NW Iberian Shelf. The Regional Oceanic Modeling System (ROMS model was selected to reproduce scenarios of plume generation, retention and dispersion. Whit this model, three types of simulations were performed: (i schematic winds simulations with prescribed river flow, wind speed and direction; (ii multi-year climatological simulation, with river flow and temperature change for each month; (iii extreme case simulation, based on the Entre-os-Rios accident situation. The schematic wind case-studies suggest that the

  10. Analysis of plasmaspheric plumes: CLUSTER and IMAGE observations

    Directory of Open Access Journals (Sweden)

    F. Darrouzet

    2006-07-01

    Full Text Available Plasmaspheric plumes have been routinely observed by CLUSTER and IMAGE. The CLUSTER mission provides high time resolution four-point measurements of the plasmasphere near perigee. Total electron density profiles have been derived from the electron plasma frequency identified by the WHISPER sounder supplemented, in-between soundings, by relative variations of the spacecraft potential measured by the electric field instrument EFW; ion velocity is also measured onboard these satellites. The EUV imager onboard the IMAGE spacecraft provides global images of the plasmasphere with a spatial resolution of 0.1 RE every 10 min; such images acquired near apogee from high above the pole show the geometry of plasmaspheric plumes, their evolution and motion. We present coordinated observations of three plume events and compare CLUSTER in-situ data with global images of the plasmasphere obtained by IMAGE. In particular, we study the geometry and the orientation of plasmaspheric plumes by using four-point analysis methods. We compare several aspects of plume motion as determined by different methods: (i inner and outer plume boundary velocity calculated from time delays of this boundary as observed by the wave experiment WHISPER on the four spacecraft, (ii drift velocity measured by the electron drift instrument EDI onboard CLUSTER and (iii global velocity determined from successive EUV images. These different techniques consistently indicate that plasmaspheric plumes rotate around the Earth, with their foot fully co-rotating, but with their tip rotating slower and moving farther out.

  11. Nano-TiCl4/SiO2: an efficient heterogeneous solid acid catalyst for ...

    Indian Academy of Sciences (India)

    Mirjalili

    Nano-TiCl4/SiO2: an efficient heterogeneous solid acid catalyst for the one pot cascade five-component synthesis of densely functionalized tetrahydropyridines. ABDOLHAMID BAMONIRIa,*, BI BI FATEMEH MIRJALILIb and REZA TARAZIANa. aDepartment of Organic Chemistry, Faculty of Chemistry, University of Kashan, ...

  12. Coordination Chemistry of Life Processes: Bioinorganic Chemistry

    Indian Academy of Sciences (India)

    Home; Journals; Resonance – Journal of Science Education; Volume 4; Issue 9. Coordination Chemistry of Life Processes: Bioinorganic Chemistry. R N Mukherjee. General Article Volume 4 Issue 9 September 1999 pp 53-62. Fulltext. Click here to view fulltext PDF. Permanent link:

  13. Constraints on the detection of cryovolcanic plumes on Europa

    Science.gov (United States)

    Quick, Lynnae C.; Barnouin, Olivier S.; Prockter, Louise M.; Patterson, G. Wesley

    2013-09-01

    Surface venting is a common occurrence on several outer solar system satellites. Spacecraft have observed plumes erupting from the geologically young surfaces of Io, Triton and Enceladus. Europa also has a relatively young surface and previous studies have suggested that cryovolcanic eruptions may be responsible for the production of low-albedo deposits surrounding lenticulae and along triple band margins and lineae. Here, we have used the projected thicknesses of these deposits as constraints to determine the lifetimes of detectable cryovolcanic plumes that may have emplaced them. In an effort to explore the feasibility of detection of the particle component of plumes by spacecraft cameras operating at visible wavelengths, we present a conservative model to estimate plume characteristics such as height, eruption velocity, and optical depth under a variety of conditions. We find that cryovolcanic plumes on Europa are likely to be fairly small in stature with heights between 2.5 and 26 km, and eruption velocities between 81 and 261 m/s, respectively. Under these conditions and assuming that plumes are products of steady eruptions with particle radii of 0.5 μm, our model suggests that easily detectable plumes will have optical depths, τ, greater than or equal to 0.04, and that their lifetimes may be no more than 300,000 years. Plume detection may be possible if high phase angle limb observations and/or stereo imaging of the surface are undertaken in areas where eruptive activity is likely to occur. Cameras with imaging resolutions greater than 50 m/pixel should be used to make all observations. Future missions could employ the results of our model in searches for plume activity at Europa.

  14. Compositional variation in aging volcanic plumes - Analysis of gaseous SO2, CO2 and halogen species in volcanic emissions using an Unmanned Aerial Vehicle (UAV).

    Science.gov (United States)

    Rüdiger, Julian; Lukas, Tirpitz; Bobrowski, Nicole; Gutmann, Alexandra; Liotta, Marcello; de Moor, Maarten; Hoffmann, Thorsten

    2017-04-01

    Volcanoes are a large source for several reactive atmospheric trace gases including sulfur and halogen containing species. The detailed understanding of volcanic plume chemistry is needed to draw information from gas measurements on subsurface processes. This knowledge is essential for using gas measurements as a monitoring tool for volcanic activity. The reactive bromine species bromine monoxide (BrO) is of particular interest, because BrO as well as SO2 are readily measurable from safe distance by spectroscopic remote sensing techniques. BrO is not directly emitted, but is formed in the plume by a multiphase reaction mechanism. The abundance of BrO changes as a function of the distance from the vent as well as the spatial position in the plume. The precursor substance for the formation of BrO is HBr with Br2as an intermediate product. In this study we present the application of a UAV as a carrier for a remote-controlled sampling system for halogen species (Br2, HBr, BrCl, etc), based on the gas diffusion denuder technique, which allows speciation and enrichment by selective organic reactions. For the analysis of gaseous SO2 and CO2 an in-situ gas monitoring system was additionally mounted. This setup was deployed into the gas plumes of Stromboli Volcano (Italy), Masaya Volcano (Nicaragua) and Turrialba Volcano (Costa Rica) in 2016, to investigate the halogen chemistry at distant locations in the plume further downwind to the emission source, which are in most cases not accessible by other approaches. Flights into the plume were conducted with ascents of up to 1000 m. From telemetrically transmitted SO2 mixing ratios, areas of dense plume where localized to keep the UAV stationary for up to 10 minutes of sampling time. Additionally, ground based samples were taken at the crater rim (at Masaya and Turrialba) using alkaline traps, denuder and gas sensors for comparison with airborne-collected data. Herein we will present time and spatial resolved gas mixing ratio

  15. Tropospheric Halogen Chemistry

    Science.gov (United States)

    von Glasow, R.; Crutzen, P. J.

    2003-12-01

    processes. Early work by Cauer (1951) had shown that Cl/Na and Cl/Mg ratios were lower in air than in seawater, indicating loss of chlorine by "acid displacement" from sea salt by the strong acids, H2SO4 (Eriksson (1959a, b) and HNO3 (Robbins et al., 1959). Already the first measurements of bromine in aerosols by Duce et al. (1963) showed that bromine, like chlorine, was lost from the sea salt particles, whereas iodine was strongly enriched ( Duce et al., 1965). Research since the early 1980s has shown that photochemical processes are actively involved.Interest in the chemistry of atmospheric halogens took a steep upward surge after it was postulated that the release of industrially produced halocarbons, in particular the chlorofluorocarbons (CFCs), CFCl3, and CF2Cl2, could cause severe depletions in stratospheric ozone (Molina and Rowland, 1974) by the reactions involving the CFC photolytic product radicals, Cl and ClO, as catalysts. The first stratospheric measurements of ClO did indeed show its presence in significant quantities in the stratosphere so that by the end of the 1970s USA, Canada, and the Scandinavian countries issued laws against the use of CFC gases as propellants in spray cans. In the mid-1980s the springtime stratospheric ozone hole over Antarctica was discovered by Farman et al. (1985), involving heterogeneous reactions on polar stratospheric clouds that lead to chlorine activation ( Solomon et al., 1986). Ten years later, in 1996, a complete phaseout ofthe production of the CFCs and a number of other chlorine- or bromine-containing chemicals came into effect for all nations in the developed world. In this contribution we will, however, concentrate on the impact of reactive chlorine, bromine, and iodine on tropospheric ozone chemistry.Halogens have the potential to be important in many facets of tropospheric chemistry. A multitude of gas phase reactions and gas-particle interactions occur that include coupling with the sulfur cycle and reactions with

  16. Formation of secondary organic aerosol in the Paris pollution plume and its impact on surrounding regions

    Science.gov (United States)

    Zhang, Q. J.; Beekmann, M.; Freney, E.; Sellegri, K.; Pichon, J. M.; Schwarzenboeck, A.; Colomb, A.; Bourrianne, T.; Michoud, V.; Borbon, A.

    2015-12-01

    Secondary pollutants such as ozone, secondary inorganic aerosol, and secondary organic aerosol formed in the plumes of megacities can affect regional air quality. In the framework of the FP7/EU MEGAPOLI (Megacities: Emissions, urban, regional and Global Atmospheric POLlution and climate effects, and Integrated tools for assessment and mitigation) project, an intensive campaign was launched in the greater Paris region in July 2009. The major objective was to quantify different sources of organic aerosol (OA) within a megacity and in its plume. In this study, we use airborne measurements aboard the French ATR-42 aircraft to evaluate the regional chemistry-transport model CHIMERE within and downwind of the Paris region. Two mechanisms of secondary OA (SOA) formation are used, both including SOA formation from oxidation and chemical aging of primary semivolatile and intermediate volatility organic compounds (SI-SOA) in the volatility basis set (VBS) framework. As for SOA formed from traditional VOC (volatile organic compound) precursors (traditional SOA), one applies chemical aging in the VBS framework adopting different SOA yields for high- and low-NOx environments, while another applies a single-step oxidation scheme without chemical aging. Two emission inventories are used for discussion of emission uncertainties. The slopes of the airborne OA levels versus Ox (i.e., O3 + NO2) show SOA formation normalized with respect to photochemical activity and are used for specific evaluation of the OA scheme in the model. The simulated slopes were overestimated slightly by factors of 1.1, 1.7 and 1.3 with respect to those observed for the three airborne measurements, when the most realistic "high-NOx" yields for traditional SOA formation in the VBS scheme are used in the model. In addition, these slopes are relatively stable from one day to another, which suggests that they are characteristic for the given megacity plume environment. The configuration with increased primary

  17. Environmental chemistry: Volume A

    Energy Technology Data Exchange (ETDEWEB)

    Yen, T.F.

    1999-08-01

    This is an extensive introduction to environmental chemistry for engineering and chemical professionals. The contents of Volume A include a brief review of basic chemistry prior to coverage of litho, atmo, hydro, pedo, and biospheres.

  18. A dictionary of chemistry

    National Research Council Canada - National Science Library

    Daintith, John

    2008-01-01

    "Fully revised and updated, the sixth edition of this popular dictionary covers all aspects of chemistry from physical chemistry to biochemisty, and boasts broader coverage in forensics, metallurgy, and geology...

  19. Organometallic Chemistry of Molybdenum.

    Science.gov (United States)

    Lucas, C. Robert; Walsh, Kelly A.

    1987-01-01

    Suggests ways to avoid some of the problems students have learning the principles of organometallic chemistry. Provides a description of an experiment used in a third-year college chemistry laboratory on molybdenum. (TW)

  20. Advanced Chemistry Laboratory

    Data.gov (United States)

    Federal Laboratory Consortium — Description/History: Chemistry laboratoryThe Advanced Chemistry Laboratory (ACL) is a unique facility designed for working with the most super toxic compounds known...

  1. Airborne Gamma-ray Measurements in the Chernobyl Plume

    DEFF Research Database (Denmark)

    Grasty, R. L.; Hovgaard, Jens; Multala, J.

    1997-01-01

    On 29 April 1986, the Geological Survey of Finland (GSF) survey aircraft with a gamma ray spectrometer flew through a radioactive plume from the Chernobyl nuclear accident. The aircraft became contaminated and the gamma spectrometer measured radioactivity in the plume as well as radioactivity...... on the aircraft. By using simple assumptions on the build-up of contamination it has been possible to separate the signals from contamination and from plume. The analysis further showed that even a detector/spectrometer with low energy resolution is able to identify a contamination with iodine....

  2. Single thermal plume in locally heated vertical soap films.

    Science.gov (United States)

    Adami, N; Dorbolo, S; Caps, H

    2011-10-01

    A vertical soap film is maintained by injection of a soap solution from the top. The film is then locally heated. Thermal plumes may be observed to rise in the film, depending on the magnitude of the heating and injected flows. The nearly two-dimensional nature of the system allows to visualize the motion of the plumes using an infrared camera. A model is proposed to describe the growth, emergence, and stationarity of the plumes in the film by taking into account both magnitudes of the heating ΔT and injected flow Q.

  3. Capability of MODIS radiance to analyze Iberian turbid plumes

    Science.gov (United States)

    Fernandez-Novoa, Diego; deCastro, Maite; Des, Marisela; Costoya, Xurxo; Mendes, Renato; Gomez-Gesteira, Moncho

    2017-04-01

    River plumes are formed near river mouths by freshwater and riverine materials. Therefore, the area influenced by freshwater (salinity plume) is usually negatively correlated with the area occupied by suspension and dissolved material (turbid plume). Suspended material results in a strong signal detected by satellite sensors whereas ocean clear waters have negligible contributions. Thus, remote sensing data, such as radiance obtained from Moderate Resolution Imaging Spectroradiometer (MODIS), are a very useful tool to analyze turbid plumes due to the high spatial and time resolution provided. Here, MODIS capability for characterizing similarities and differences among the most important Iberian plumes was assessed under the influence of their main forcing. Daily radiance data from MODIS-Aqua and MODIS-Terra satellite sensors were processed obtaining a resolution of 500 m. Two approaches are usually used for atmospheric correction treatments: Near-Infrared (NIR) bands and a combined algorithm using NIR and Short Wave Infrared (SWIR) bands. In the particular case of Iberian Peninsula plumes both methods offered similar results, although NIR bands present a lower associated error. MODIS allows working with several bands of normalized water-leaving radiances (nLw). Focusing in the resolution provided, nLw555 and 645 were the most appropriate because both provide the best coverage and correlation with river discharge. The nLw645 band was chosen because has a lower water penetration avoiding overestimations of turbidity caused by shallow seafloor areas and/or upwelling blooms. Daily data from both satellites were merged to enhance the robustness and precision of the study by increasing the number of available pixels. Results indicate that differences between radiance data from both satellites are negligible for Iberian plumes, justifying the merging. By last, each turbid limit, to delimit the respective plume from adjacent seawater, was obtained using two alternative

  4. Aerosol and gas emissions from Holuhraun eruption 2014-2015: size-resolved chemistry at source and in exposed communities

    Science.gov (United States)

    Ilyinskaya, Evgenia; Schmidt, Anja; Mather, Tamsin A.; Pope, Francis; Witham, Claire; Baxter, Peter; Johannsson, Thorsteinn; Barsotti, Sara; Pfeffer, Melissa; Singh, Ajit; Sanderson, Paul; Bergsson, Baldur; McCormick, Brendan; Donovan, Amy; Peters, Nial; Oppenheimer, Clive; Edmonds, Marie

    2017-04-01

    The Holuhraun eruption 2014-2015 (6-month duration) was the first scientific opportunity to directly observe the emission and dispersion of a volcanic plume from a large Icelandic fissure eruption, an eruption type that can greatly impact the environment due to their prolonged high flux emissions of reactive gases and aerosol. We present a comprehensive dataset to characterise the chemistry of aerosol and gas in the Holuhraun plume. The plume was sampled at the eruptive vent, and in two populated areas in Iceland located at different distances downwind of the volcano: Reykjahlíð town (100km), and Reykjavík capital area (250km). The dataset comprises a detailed analysis of major and trace species in the volcanic plume, including size-resolved chemistry of the aerosol phase. We also present a time series of volcanic air pollutants (SO2, PM2.5 and sulphate aerosol) in the populated areas. The results show that the plume was very diverse in its chemical composition, and 75-80% of the volcanic aerosol mass was in the PM2.5 size fraction. The plume had detectable concentrations of a large number of major and trace species in the aerosol phase, even when sampled in the populated area far downwind. The plume caused repeated air pollution events in the populated areas, exceeding the EU hourly exposure standards (350 µg/m3) for SO2 on 88 occasions in Reykjahlíð town, and 34 occasions in Reykjavík capital area. The annual limit for daily exceedances (3 days) was also surpassed in both areas (10 and 7 days, respectively). Average 24-hour concentration of volcanogenic sulphate exceeded 5 µg/m3 on 30 days in Reykjavík capital area. We detected two 'types' of plume that reached the downwind populated areas at ground level. The first type, a 'young plume' had high concentrations of both SO2 and sulphate, with a high gas/aerosol ratio. The second type, an 'aged plume' had low SO2 and high sulphate, where sulphur had undergone complete or near-complete gas

  5. Chemistry is Evergreen

    Indian Academy of Sciences (India)

    Srimath

    RESONANCE ⎜ March 2009. GENERAL ⎜ ARTICLE. Keywords. Green fluorescent protein,. FRET. Chemistry is Evergreen. 2008 Nobel Prize in Chemistry. Swagata Dasgupta. Swagata Dasgupta is an. Associate Professor in the. Department of Chemistry at IIT Kharagpur. Her research interests revolve around proteins and ...

  6. Green Chemistry and Education.

    Science.gov (United States)

    Hjeresen, Dennis L.; Schutt, David L.; Boese, Janet M.

    2000-01-01

    Many students today are profoundly interested in the sustainability of their world. Introduces Green Chemistry and its principles with teaching materials. Green Chemistry is the use of chemistry for pollution prevention and the design of chemical products and processes that are environmentally benign. (ASK)

  7. American Association for Clinical Chemistry

    Science.gov (United States)

    ... Find the answer to your question IN CLINICAL CHEMISTRY Hs-cTnI as a Gatekeeper for Further Cardiac ... Online Harmonization.net Commission on Accreditation in Clinical Chemistry American Board of Clinical Chemistry Clinical Chemistry Trainee ...

  8. Vehicle NOx emission plume isotopic signatures: Spatial variability across the eastern United States

    Science.gov (United States)

    Miller, David J.; Wojtal, Paul K.; Clark, Sydney C.; Hastings, Meredith G.

    2017-04-01

    On-road vehicle nitrogen oxide (NOx) sources currently dominate the U.S. anthropogenic emission budgets, yet vehicle NOx emissions have uncertain contributions to oxidized nitrogen (N) deposition patterns. Isotopic signatures serve as a potentially valuable observational tool to trace source contributions to NOx chemistry and N deposition, yet in situ emission signatures are underconstrained. We characterize the spatiotemporal variability of vehicle NOx emission isotopic signatures (δ15N-NOx) representative of U.S. vehicle fleet-integrated emission plumes. A novel combination of on-road mobile and stationary urban measurements is performed using a field and laboratory-verified technique for actively capturing NOx in solution to quantify δ15N-NOx at hourly resolution. On-road δ15N-NOx upwind of Providence, RI, ranged from -7 to -3‰. Simultaneous urban background δ15N-NOx observations showed comparable range and variations with on-road measurements, suggesting that vehicles dominate NOx emissions in the Providence area. On-road spatial δ15N-NOx variations of -9 to -2‰ were observed under various driving conditions in six urban metropolitan areas and rural interstate highways during summer and autumn in the U.S. Northeast and Midwest. Although isotopic signatures were insensitive to on-road driving mode variations, statistically significant correlations were found between δ15N-NOx and NOx emission factor extremes associated with heavy diesel emitter contributions. Overall, these results constrain an isotopic signature of fleet-integrated roadway NOx emission plumes, which have important implications for distinguishing vehicle NOx from other sources and tracking emission contributions to NOx chemistry and N deposition.

  9. CONSEQUENCES OF NON-LINEAR DENSITY EFFECTS ON BUOYANCY AND PLUME BEHAVIOR

    Science.gov (United States)

    Aquatic plumes, as turbulent streams, grow by entraining ambient water. Buoyant plumes rise and dense ones sink, but, non-linear kinetic effects can reverse the buoyant force in mid-phenomenon. The class of nascent-density plumes begin as buoyant, upwardly accelerating plumes tha...

  10. Field testing the role of heterogeneity at the inter-well scale during two phase flow

    Science.gov (United States)

    Hovorka, S. D.; Gulf Coast Carbon Center; Geoseq

    2011-12-01

    Connectivity of rocks with different fluid flow properties (reservoir architecture) is a major source of uncertainty in predicting multi-phase fluid flow. Multi-institution research teams have completed three major DOE-funded test programs in which movement of supercritical CO2 through brine-saturated fluvial sandstones was observed with multiple tools. In each test, closely spaced wells (30 to 100 m) were drilled to reservoir depth so that the amount of reservoir complexity sampled between the wells would be reduced and higher resolution measurements of change could be obtained during time-lapse monitoring. During one test (Frio 1), an exceptionally homogeneous injection zone produced by marine reworking of a fine-grained fluvial sandstone of the Upper Frio Formation produced a classic-wedge-shaped CO2 plume. The maximum area occupied by CO2 was the result of radial expansion of the plume near the injection well; this produced plume down-building. Away from the injection well , the importance of gravity-override increased. A second test at the same well array in a deeper sandstone (Frio 2) was sited in heterogeneous (gravel to muddy sandstone) high permeability (>3 Darcy), weakly cemented fluvial sandstone. A slow injection rate over a small interval at the flow unit base was used to accentuate buoyancy effects. Measurements of plume migration through time using tracers and cross-well seismic documented interaction between near-well radial flow and vertical rise. However, because of discontinuous fast paths in gravel zones and CO2 ponding against muddy sandstone baffles, reservoir heterogeneity was a dominant influence in short-term plume evolution. The third test interval in the SECARB "Early" test documented response of amalgamated gravel and sandstone point bars in which heterogeneity was reduced by cementation. CO2 injection rate was increased incrementally and flow-rate dependent reservoir responses observed. These suggest that capillary-entry pressure and

  11. Heterogeneous cellular networks

    CERN Document Server

    Hu, Rose Qingyang

    2013-01-01

    A timely publication providing coverage of radio resource management, mobility management and standardization in heterogeneous cellular networks The topic of heterogeneous cellular networks has gained momentum in industry and the research community, attracting the attention of standardization bodies such as 3GPP LTE and IEEE 802.16j, whose objectives are looking into increasing the capacity and coverage of the cellular networks. This book focuses on recent progresses,  covering the related topics including scenarios of heterogeneous network deployment, interference management i

  12. Multiscale modelling in computational heterogeneous catalysis.

    Science.gov (United States)

    Keil, F J

    2012-01-01

    The goal of multiscale modelling of heterogeneous catalytic reactors is the prediction of all steps, starting from the reaction mechanism at the active centre, the rates of reaction, adsorption and diffusion processes inside the porous system of the catalyst support, based on first principles, quantum chemistry, force field simulations and macroscopic differential equations. The progress in these fields of research will be presented, including linking models between the various levels of description. Alkylation of benzene will be used as an example to demonstrate the various approaches from the active centre to the reactor.

  13. Project Opalinus Clay: Sorption Data Bases For Opalinus Clay Influenced By A High pH Plume

    Energy Technology Data Exchange (ETDEWEB)

    Bradbury, M.H.; Baeyens, B

    2004-11-01

    The interaction of groundwater with the large quantities of cement/concrete used in the construction and backfilling of emplacement tunnels containing long-lived intermediate level radioactive waste may give rise to the release of a pulse of hyper alkaline fluid (pH plume) into the surrounding rock. Since the pH of this plume could remain in excess of 12.5 for tens of thousands of years, many minerals in a sedimentary host rock would be unstable leading to dissolution reactions, secondary mineral precipitation and changes in groundwater chemistry. An Opalinus day formation in the Zuercher Weinland, is under consideration by Nagra as a potential host rock for a repository of spent fuel (SF), vitrified high-level waste (HLW) from reprocessing of spent fuel and long-lived intermediate-Ievel radioactive waste (ILW). The purpose of this report is to assess the effects of the interactions between a pH plume and Opalinus day on the sorption properties of the formation and to provide appropriate sorption data bases. (author)

  14. Small particles in plumes of Mount St. Helens

    Science.gov (United States)

    Rose, W. I.; Chuan, R. L.; Woods, D. C.

    1982-01-01

    Particles in the size range 0.1-25 microns were sampled by aircraft carrying a quartz crystal microcascade in the Mount St. Helens plume on three dates in August and September 1980. Two of the sampling dates represented 'typical' emissions of the volcano between plinian eruptions. One sampling flight was made 1-4 hours before the small plinian eruption of August 7, 1980 when the plume had become discontinuous and visibly darker. The plume sampled on August 7, before the eruption, contained mainly approximately 2-micron diameter silicic glass particles, fragments of the Mount St. Helens magma. The typical plumes sampled on September 22 and August 6 had much smaller concentrations of particles, trimodal size distributions with peaks at 10, 0.4, and 0.1 microns. The particles were largely nonsilicate and apparently represented Cu-Zn oxide (10 micron peak), Al sulfate, chloride, and oxide, and sulfuric acid (smallest size peak).

  15. Volcanic ash plume identification using polarization lidar: Augustine eruption, Alaska

    Science.gov (United States)

    Sassen, Kenneth; Zhu, Jiang; Webley, Peter W.; Dean, K.; Cobb, Patrick

    2007-01-01

    During mid January to early February 2006, a series of explosive eruptions occurred at the Augustine volcanic island off the southern coast of Alaska. By early February a plume of volcanic ash was transported northward into the interior of Alaska. Satellite imagery and Puff volcanic ash transport model predictions confirm that the aerosol plume passed over a polarization lidar (0.694 mm wavelength) site at the Arctic Facility for Atmospheric Remote Sensing at the University of Alaska Fairbanks. For the first time, lidar linear depolarization ratios of 0.10 – 0.15 were measured in a fresh tropospheric volcanic plume, demonstrating that the nonspherical glass and mineral particles typical of volcanic eruptions generate strong laser depolarization. Thus, polarization lidars can identify the volcanic ash plumes that pose a threat to jet air traffic from the ground, aircraft, or potentially from Earth orbit.

  16. Near-Shore Hydrodynamic Conditions and Chemical Plume Tracking

    National Research Council Canada - National Science Library

    Fong, Derek

    2004-01-01

    .... Analyzing a dye concentration data set collected by a state of the art autonomous underwater vehicle and fixed hydrodynamic measurements, we quantify the meandering and lateral dispersion of a plume...

  17. Hydrocarbon Rocket Engine Plume Imaging with Laser Induced Incandescence Project

    Data.gov (United States)

    National Aeronautics and Space Administration — NASA/ Marshall Space Flight Center (MSFC) needs sensors that can be operated on rocket engine plume environments to improve NASA/SSC rocket engine performance. In...

  18. A Thermal Plume Model for the Martian Convective Boundary Layer

    CERN Document Server

    Colaïtis, Arnaud; Hourdin, Frédéric; Rio, Catherine; Forget, François; Millour, Ehouarn

    2013-01-01

    The Martian Planetary Boundary Layer [PBL] is a crucial component of the Martian climate system. Global Climate Models [GCMs] and Mesoscale Models [MMs] lack the resolution to predict PBL mixing which is therefore parameterized. Here we propose to adapt the "thermal plume" model, recently developed for Earth climate modeling, to Martian GCMs, MMs, and single-column models. The aim of this physically-based parameterization is to represent the effect of organized turbulent structures (updrafts and downdrafts) on the daytime PBL transport, as it is resolved in Large-Eddy Simulations [LESs]. We find that the terrestrial thermal plume model needs to be modified to satisfyingly account for deep turbulent plumes found in the Martian convective PBL. Our Martian thermal plume model qualitatively and quantitatively reproduces the thermal structure of the daytime PBL on Mars: superadiabatic near-surface layer, mixing layer, and overshoot region at PBL top. This model is coupled to surface layer parameterizations taking ...

  19. AASERT: Hydrodynamic Interaction Between Olfactory Antennae and Odor Plumes

    National Research Council Canada - National Science Library

    Koehl, M

    2002-01-01

    ... other. In the turbulent water flow typical of shallow coastal habitats, odor plumes are characterized by complex swirls of narrow filaments of high concentration near the odor source, but wider filaments...

  20. Saturated Zone Plumes in Volcanic Rock: Implications for Yucca Mountain

    Energy Technology Data Exchange (ETDEWEB)

    S. Kelkar; R. Roback; B. Robinson; G. Srinivasan; C. Jones; P. Reimus

    2006-02-14

    This paper presents a literature survey of the occurrences of radionuclide plumes in saturated, fractured rocks. Three sites, Idaho National laboratory, Hanford, and Oak Ridge are discussed in detail. Results of a modeling study are also presented showing that the length to width ratio of a plume starting within the repository footprint at the Yucca Mountain Project site, decreases from about 20:1 for the base case to about 4:1 for a higher value of transverse dispersivity, indicating enhanced lateral spreading of the plume. Due to the definition of regulatory requirements, this lateral spreading does not directly impact breakthrough curves at the 18 km compliance boundary, however it increases the potential that a plume will encounter reducing conditions, thus significantly retarding the transport of sorbing radionuclides.

  1. Turbulent Boyant Jets and Plumes in Flowing Ambient Environments

    DEFF Research Database (Denmark)

    Chen, Hai-Bo

    Turbulent buoyant jets and plumes in flowing ambient environments have been studied theoretically and experimentally. The mechanics of turbulent buoyant jets and plumes in flowing ambients have been discussed. Dimensional analysis was employed to investigate the mean behaviour of the turbulent....... Comprehensive laboratory experiments were conducted to study the mean behaviour of turbulent buoyant jets and plumes in a flowing ambient by using both fresh and salt receiving waters. The experimental data on the jet trajectories and dilutions, for a horizontal jet in a coflowing ambient and for a vertical jet......, the available field observated data on the initial dilutions for a horizontal jet issuing into a perpendicular crossflowing ambient have been presented and discussed. Mathematical modelling of the turbulent buoyant jets and plumes has been carried out by using both an integral model and a turbulence model...

  2. Airborne Remote Sensing of the Plata Plume Using STARRS

    National Research Council Canada - National Science Library

    Perez, Tabare; Wesson, Joel C; Burrage, Derek

    2006-01-01

    ...s. An international project, La Plata, was undertaken within the South American Climate Change Consortium framework to assess the behavior of the La Plata and Patos Lagoon plumes and their effects...

  3. Dynamics of femtosecond laser produced tungsten nanoparticle plumes

    Energy Technology Data Exchange (ETDEWEB)

    Harilal, S. S.; Hassanein, A. [Center for Materials Under Extreme Environment, School of Nuclear Engineering, Purdue University, West Lafayette, Indiana 47907 (United States); Farid, N. [Center for Materials Under Extreme Environment, School of Nuclear Engineering, Purdue University, West Lafayette, Indiana 47907 (United States); School of Physics and Optical Engineering, Dalian University of Technology, Dalian 116024 (China); Kozhevin, V. M. [Ioffe Physics Technical Institute, Russian Academy of Sciences, St. Petersburg 194021 (Russian Federation)

    2013-11-28

    We investigated the expansion features of femtosecond laser generated tungsten nanoparticle plumes in vacuum. Fast gated images showed distinct two components expansion features, viz., plasma and nanoparticle plumes, separated by time of appearance. The persistence of plasma and nanoparticle plumes are ∼500 ns and ∼100 μs, respectively, and propagating with velocities differed by 25 times. The estimated temperature of the nanoparticles showed a decreasing trend with increasing time and space. Compared to low-Z materials (e.g., Si), ultrafast laser ablation of high-Z materials like W provides significantly higher nanoparticle yield. A comparison between the nanoparticle plumes generated by W and Si is also discussed along with other metals.

  4. Dynamics of femtosecond laser produced tungsten nanoparticle plumes

    Science.gov (United States)

    Harilal, S. S.; Farid, N.; Hassanein, A.; Kozhevin, V. M.

    2013-11-01

    We investigated the expansion features of femtosecond laser generated tungsten nanoparticle plumes in vacuum. Fast gated images showed distinct two components expansion features, viz., plasma and nanoparticle plumes, separated by time of appearance. The persistence of plasma and nanoparticle plumes are ˜500 ns and ˜100 μs, respectively, and propagating with velocities differed by 25 times. The estimated temperature of the nanoparticles showed a decreasing trend with increasing time and space. Compared to low-Z materials (e.g., Si), ultrafast laser ablation of high-Z materials like W provides significantly higher nanoparticle yield. A comparison between the nanoparticle plumes generated by W and Si is also discussed along with other metals.

  5. Directions of seismic anisotropy in laboratory models of mantle plumes

    Science.gov (United States)

    Druken, K. A.; Kincaid, C.; Griffiths, R. W.

    2013-07-01

    recent expansion in global seismic anisotropy data provides important new insights about the style of mantle convection. Interpretations of these geophysical measurements rely on complex relationships between mineral physics, seismology, and mantle dynamics. We report on 3-D laboratory experiments using finite strain markers evolving in time-dependent, viscous flow fields to quantify the range in expected anisotropy patterns within buoyant plumes surfacing in a variety of tectonic settings. A surprising result is that laboratory proxies for the olivine fast axis overwhelmingly align tangential to radial outflow in plumes well before reaching the surface. These remarkably robust, and ancient, anisotropy patterns evolve differently in stagnant, translational, and divergent plate tectonic settings and are essentially orthogonal to patterns typically referenced when prospecting for plume signals in seismic data. Results suggest a fundamental change in the mineral physics-seismology-circulation relationship used in accepting or rejecting a plume model.

  6. Plume Activity and Tidal Deformation on Enceladus Influenced by Faults and Variable Ice Shell Thickness

    Science.gov (United States)

    Běhounková, Marie; Souček, Ondřej; Hron, Jaroslav; Čadek, Ondřej

    2017-09-01

    We investigated the effect of variations in ice shell thickness and of the tiger stripe fractures crossing Enceladus' south polar terrain on the moon's tidal deformation by performing finite element calculations in three-dimensional geometry. The combination of thinning in the polar region and the presence of faults has a synergistic effect that leads to an increase of both the displacement and stress in the south polar terrain by an order of magnitude compared to that of the traditional model with a uniform shell thickness and without faults. Assuming a simplified conductive heat transfer and neglecting the heat sources below the ice shell, we computed the global heat budget of the ice shell. For the inelastic properties of the shell described by a Maxwell viscoelastic model, we show that unrealistically low average viscosity of the order of 10^{13} Pa s is necessary for preserving the volume of the ocean, suggesting the important role of the heat sources in the deep interior. Similarly, low viscosity is required to predict the observed delay of the plume activity, which hints at other delaying mechanisms than just the viscoelasticity of the ice shell. The presence of faults results in large spatial and temporal heterogeneity of geysering activity compared to the traditional models without faults. Our model contributes to understanding the physical mechanisms that control the fault activity, and it provides potentially useful information for future missions that will sample the plume for evidence of life.

  7. The New Color of Chemistry: Green Chemistry

    Directory of Open Access Journals (Sweden)

    Zuhal GERÇEK

    2012-01-01

    Full Text Available Green chemistry which is the new application of chemistry rules provides solutions to problems that mankind is faced with climate changes, sustainable agriculture, energy, toxics, depletion of natural sources e.g. designing new chemicals and processes that production and utilization of hazardous matters. So, it is the indispensible tool for sustainable development. Current and future chemists should consider the human health and ecological issues in their professional life. In order to provide a solution for this requirement, green chemistry rules and under standings should be primarily taken in the university curriculum and at all educational levels.

  8. Surface chemistry essentials

    CERN Document Server

    Birdi, K S

    2013-01-01

    Surface chemistry plays an important role in everyday life, as the basis for many phenomena as well as technological applications. Common examples range from soap bubbles, foam, and raindrops to cosmetics, paint, adhesives, and pharmaceuticals. Additional areas that rely on surface chemistry include modern nanotechnology, medical diagnostics, and drug delivery. There is extensive literature on this subject, but most chemistry books only devote one or two chapters to it. Surface Chemistry Essentials fills a need for a reference that brings together the fundamental aspects of surface chemistry w

  9. Analysis of bubble plume spacing produced by regular breaking waves

    Science.gov (United States)

    Phaksopa, J.; Haller, M. C.

    2012-12-01

    The breaking wave process in the ocean is a significant mechanism for energy dissipation, splash, and entrainment of air. The relationship between breaking waves and bubble plume characteristics is still a mystery because of the complexity of the breaking wave mechanism. This study takes a unique approach to quantitatively analyze bubble plumes produced by regular breaking waves. Various previous studies have investigated the formation and the characteristics of bubble plumes using either field observations, laboratory experiments, or numerical modeling However, in most observational work the plume characteristics have been studied from the underneath the water surface. In addition, though numerical simulations are able to include much of the important physics, the computational costs are high and bubble plume events are only simulated for short times. Hence, bubble plume evolution and generation throughout the surf zone is not yet computationally feasible. In the present work we take a unique approach to analyzing bubble plumes. These data may be of use for model/data comparisons as numerical simulations become more tractable. The remotely sensed video data from freshwater breaking waves in the OSU Large Wave Flume (Catalan and Haller, 2008) are analyzed. The data set contains six different regular wave conditions and the video intensity data are used to estimate the spacing of plume events (wavenumber spectrum), to calculate the spectral width (i.e. the range of plume spacing), and to relate these with the wave conditions. The video intensity data capture the evolution of the wave passage over a fixed bed arranged in a bar-trough morphology. Bright regions represent the moving path or trajectory coincident with bubble plume of each wave. It also shows the bubble foam were generated and released from wave crest shown in the form of bubble tails with almost regular spacing for each wave. The bubble tails show that most bubbles did not move along with wave. For the

  10. Particle resuspension in the Columbia River plume near field

    Science.gov (United States)

    Spahn, Emily Y.; Horner-Devine, Alexander R.; Nash, Jonathan D.; Jay, David A.; Kilcher, Levi

    2009-02-01

    Measurements of suspended sediment concentration, velocity, salinity, and turbulent microscale shear in the near-field region of the Columbia River plume are used to investigate the mechanisms of sediment resuspension and entrainment into the plume. An east-west transect was occupied during spring and neap tide periods in August 2005 and May 2006, corresponding to low and high river discharge conditions, respectively. During the high-discharge period the plume is decoupled from the bottom, and fine sediment resuspended from the bottom does not leave the benthic boundary layer. The primary modes of sediment transport associated with the plume are advection of sediment from the estuary and removal of sediment from the plume by gravitational settling and turbulent mixing. In contrast, the plume is much less stratified during low-discharge conditions, and large resuspension events are observed that entrained sediment through the water column and into the plume. Our measurements indicate that two factors control the magnitude and timing of sediment resuspension and entrainment: the supply of fine sediment on the seabed and the relative influence of tidal turbulence compared with buoyancy input from the river. The latter is quantified in terms of the estuary Richardson number RiE. The magnitude of vertical turbulent sediment flux is correlated with RiE during the low-flow period when there is a sufficient supply of bottom sediment in the near-field region. Such sediment resuspension may be an important mechanism for the delivery of bioavailable micronutrients to the plume during the summer.

  11. MODELING AN IRRITANT GAS PLUME FOR EPIDEMIOLOGIC STUDY

    OpenAIRE

    Jani, Dev D.; Reed, David; Feigley, Charles E.; Svendsen, Erik R.

    2015-01-01

    Plume dispersion modeling systems are often used in assessing human exposures to chemical hazards for epidemiologic study. We modeled the 2005 Graniteville, South Carolina, 54,915 kg railcar chlorine release using both the Areal Locations of Hazardous Atmospheres (ALOHA) and Hazard Prediction and Assessment Capability (HPAC) plume modeling systems. We estimated the release rate by an engineering analysis combining semi-quantitative observations and fundamental physical principles. The use of ...

  12. Chemical Plume Detection with an Iterative Background Estimation Technique

    Science.gov (United States)

    2016-05-17

    is inspired by spatial point process analysis techniques , and involves an iterative filtering process. The detection of chemical vapors is...Chemical Plume Detection with an Iterative Background Estimation Technique Eric Truslowa, Steven Golowicha, Dimitris Manolakisa aMIT-Lincoln...Laboratory, 244 Wood Street, Lexington, MA 02420, U.S.A. ABSTRACT The detection of chemical vapor plumes using passive hyperspectral sensors operating in the

  13. Numerical simulations of rotating bubble plumes in stratified environments

    Science.gov (United States)

    Fabregat Tomà s, Alexandre; Poje, Andrew C.; Ã-zgökmen, Tamay M.; Dewar, William K.

    2017-08-01

    The effects of system rotation on the turbulent dynamics of bubble plumes evolving in stratified environments are numerically investigated by considering variations in both the system rotation rate and the gas-phase slip velocity. The turbulent dispersion of a passive scalar injected at the source of a buoyant plume is strongly altered by the rotation of the system and the nature of the buoyancy at the source. When the plume is driven by the density defect associated with the presence of slipping gas bubbles, the location of the main lateral intrusion decreases with respect to the single-phase case with identical inlet volume, momentum, and buoyancy fluxes. Enhanced downdrafts of carrier phase fluid result in increased turbulent mixing and short-circuiting of detraining plume water that elevate near-field effluent concentrations. Similarly, rotation fundamentally alters dynamic balances within the plume leading to the encroachment of the trapping height on the source and an increase in turbulent dispersion in the near field. System rotation, even at modest Rossby numbers, produces a sustained, robust, anticyclonic precession of the plume core. The effects of rotation and the presence of bubbles are cumulative. The vertical encroachment of the primary intrusion and the overall dispersion of effluent are greatest at smallest Rossby numbers and largest slip velocities. The main characteristic feature in rotating single-phase plumes, namely the robust anticyclonic precession, persists in bubble plumes. Analysis of the momentum budgets reveal that the mechanism responsible for the organized precession, i.e., the establishment of an unstable vertical hydrostatic equilibrium related to radial cyclostrophic balance, does not differ from the single-phase case.

  14. Site characterization and petroleum hydrocarbon plume mapping

    Energy Technology Data Exchange (ETDEWEB)

    Ravishankar, K. [Harding Lawson Associates, Houston, TX (United States)

    1996-12-31

    This paper presents a case study of site characterization and hydrocarbon contamination plume mapping/delineation in a gas processing plant in southern Mexico. The paper describes innovative and cost-effective use of passive (non-intrusive) and active (intrusive) techniques, including the use of compound-specific analytical methods for site characterization. The techniques used, on a demonstrative basis, include geophysical, geochemical, and borehole drilling. Geochemical techniques used to delineate the horizontal extent of hydrocarbon contamination at the site include soil gas surveys. The borehole drilling technique used to assess the vertical extent of contamination and confirm geophysical and geochemical data combines conventional hollow-stem auguring with direct push-probe using Geoprobe. Compound-specific analytical methods, such as hydrocarbon fingerprinting and a modified method for gasoline range organics, demonstrate the inherent merit and need for such analyses to properly characterize a site, while revealing the limitations of noncompound-specific total petroleum hydrocarbon analysis. The results indicate that the techniques used in tandem can properly delineate the nature and extent of contamination at a site; often supplement or complement data, while reducing the risk of errors and omissions during the assessment phase; and provide data constructively to focus site-specific remediation efforts. 7 figs.

  15. Method for baghouse brown plume pollution control

    Energy Technology Data Exchange (ETDEWEB)

    Hooper, R.G.

    1990-03-13

    This patent describes an SO{sub x}/NO{sub x} air pollution control process employing a baghouse to simultaneously control particulate emissions. It comprises: introducing a sodium-based reagent into a stream of flue gas containing SO{sub x} and NO{sub x}; introducing urea as an additive into the flue gases; maintaining the reagent and the additive in contact with the flue gas to react the reagent with some of the SO{sub x} and NO{sub x} thereby reducing the concentration of the SO{sub x} and NO{sub x} in the flue gas; the additive, as compared to use of the reagent without the additive, increasing the percent SO{sub x} removal and the percent NO{sub x} removal by the reagent while suppressing conversion of NO to NO{sub 2} by the reagent to below about the visible brown plume threshold; and collecting the reacted reagent and additive in a baghouse.

  16. Ash plume top height estimation using AATSR

    Directory of Open Access Journals (Sweden)

    T. H. Virtanen

    2014-08-01

    Full Text Available An algorithm is presented for the estimation of volcanic ash plume top height using the stereo view of the Advanced Along Track Scanning Radiometer (AATSR aboard Envisat. The algorithm is based on matching top of the atmosphere (TOA reflectances and brightness temperatures of the nadir and 55° forward views, and using the resulting parallax to obtain the height estimate. Various retrieval parameters are discussed in detail, several quality parameters are introduced, and post-processing methods for screening out unreliable data have been developed. The method is compared to other satellite observations and in situ data. The proposed algorithm is designed to be fully automatic and can be implemented in operational retrieval algorithms. Combined with automated ash detection using the brightness temperature difference between the 11 and 12 μm channels, the algorithm allows efficient simultaneous retrieval of the horizontal and vertical dispersion of volcanic ash. A case study on the eruption of the Icelandic volcano Eyjafjallajökull in 2010 is presented.

  17. Improved Heterogeneous Distance Functions

    OpenAIRE

    Wilson, D. R.; Martinez, T. R.

    1996-01-01

    Instance-based learning techniques typically handle continuous and linear input values well, but often do not handle nominal input attributes appropriately. The Value Difference Metric (VDM) was designed to find reasonable distance values between nominal attribute values, but it largely ignores continuous attributes, requiring discretization to map continuous values into nominal values. This paper proposes three new heterogeneous distance functions, called the Heterogeneous Value Difference M...

  18. Updated Conceptual Model for the 300 Area Uranium Groundwater Plume

    Energy Technology Data Exchange (ETDEWEB)

    Zachara, John M.; Freshley, Mark D.; Last, George V.; Peterson, Robert E.; Bjornstad, Bruce N.

    2012-11-01

    The 300 Area uranium groundwater plume in the 300-FF-5 Operable Unit is residual from past discharge of nuclear fuel fabrication wastes to a number of liquid (and solid) disposal sites. The source zones in the disposal sites were remediated by excavation and backfilled to grade, but sorbed uranium remains in deeper, unexcavated vadose zone sediments. In spite of source term removal, the groundwater plume has shown remarkable persistence, with concentrations exceeding the drinking water standard over an area of approximately 1 km2. The plume resides within a coupled vadose zone, groundwater, river zone system of immense complexity and scale. Interactions between geologic structure, the hydrologic system driven by the Columbia River, groundwater-river exchange points, and the geochemistry of uranium contribute to persistence of the plume. The U.S. Department of Energy (DOE) recently completed a Remedial Investigation/Feasibility Study (RI/FS) to document characterization of the 300 Area uranium plume and plan for beginning to implement proposed remedial actions. As part of the RI/FS document, a conceptual model was developed that integrates knowledge of the hydrogeologic and geochemical properties of the 300 Area and controlling processes to yield an understanding of how the system behaves and the variables that control it. Recent results from the Hanford Integrated Field Research Challenge site and the Subsurface Biogeochemistry Scientific Focus Area Project funded by the DOE Office of Science were used to update the conceptual model and provide an assessment of key factors controlling plume persistence.

  19. Implementation of microwave transmissions for rocket exhaust plume diagnostics

    Science.gov (United States)

    Coutu, Nicholas George

    Rocket-launched vehicles produce a trail of exhaust that contains ions, free electrons, and soot. The exhaust plume increases the effective conductor length of the rocket. A conductor in the presence of an electric field (e.g. near the electric charge stored within a cloud) can channel an electric discharge. The electrical conductivity of the exhaust plume is related to its concentration of free electrons. The risk of a lightning strike in-flight is a function of both the conductivity of the body and its effective length. This paper presents an approach that relates the electron number density of the exhaust plume to its propagation constant. Estimated values of the collision frequency and electron number density generated from a numerical simulation of a rocket plume are used to guide the design of the experimental apparatus. Test par meters are identified for the apparatus designed to transmit a signal sweep form 4 GHz to 7 GHz through the exhaust plume of a J-class solid rocket motor. Measurements of the scattering parameters imply that the transmission does not penetrate the plume, but instead diffracts around it. The electron density 20 cm downstream from the nozzle exit is estimated to be between 2.7x1014 m--3 and 5.6x10 15 m--3.

  20. The interaction of plume heads with compositional discontinuities in the Earth's mantle

    Science.gov (United States)

    Manga, Michael; Stone, Howard A.; O'Connell, Richard J.

    1993-01-01

    The effects of compositional discontinuities of density and viscosity in the Earth's mantle on the ascent of mantle plume heads is studied using a boundary integral numerical technique. Three specific problems are considered: (1) a plume head rising away from a deformable interface, (2) a plume head passing through an interface, and (3) a plume head approaching the surface of the Earth. For the case of a plume attached to a free-surface, the calculated time-dependent plume shapesare compared with experimental results. Two principle modes of plume head deformation are observed: plume head elingation or the formation of a cavity inside the plume head. The inferred structure of mantle plumes, namely, a large plume head with a long tail, is characteristic of plumes attached to their source region, and also of buoyant material moving away from an interface and of buoyant material moving through an interface from a high- to low-viscosity region. As a rising plume head approaches the upper mantle, most of the lower mantle will quickly drain from the gap between the plume head and the upper mantle if the plume head enters the upper mantle. If the plume head moves from a high- to low-viscosity region, the plume head becomes significantly elongated and, for the viscosity contrasts thought to exist in the Earth, could extend from the 670 km discontinuity to the surface. Plume heads that are extended owing to a viscosity decrease in the upper mantle have a cylindrical geometry. The dynamic surface topography induced by plume heads is bell-shaped when the top of the plume head is at depths greater than about 0.1 plume head radii. As the plume head approaches the surface and spreads, the dynamic topography becomes plateau-shaped. The largest stresses are produced in the early stages of plume spreading when the plume head is still nearly spherical, and the surface expression of these stresses is likely to be dominated by radial extension. As the plume spreads, compressional

  1. The New Color of Chemistry: Green Chemistry

    OpenAIRE

    Zuhal GERÇEK

    2012-01-01

    Green chemistry which is the new application of chemistry rules provides solutions to problems that mankind is faced with climate changes, sustainable agriculture, energy, toxics, depletion of natural sources e.g. designing new chemicals and processes that production and utilization of hazardous matters. So, it is the indispensible tool for sustainable development. Current and future chemists should consider the human health and ecological issues in their professional life. In order to provid...

  2. Imaging Fourier transform spectroscopy of the boundary layer plume from laser irradiated polymers and carbon materials

    Science.gov (United States)

    Acosta, Roberto I.

    The high-energy laser (HEL) lethality community needs for enhanced laser weapons systems requires a better understanding of a wide variety of emerging threats. In order to reduce the dimensionality of laser-materials interaction it is necessary to develop novel predictive capabilities of these events. The objective is to better understand the fundamentals of laser lethality testing by developing empirical models from hyperspectral imagery, enabling a robust library of experiments for vulnerability assessments. Emissive plumes from laser irradiated fiberglass reinforced polymers (FRP), poly(methyl methacrylate) (PMMA) and porous graphite targets were investigated primarily using a mid-wave infrared (MWIR) imaging Fourier transform spectrometer (FTS). Polymer and graphite targets were irradiated with a continuous wave (cw) fiber lasers. Data was acquired with a spectral resolution of 2 cm-1 and spatial resolution as high as 0.52 mm2 per pixel. Strong emission from H2O, CO, CO2 and hydrocarbons were observed in the MWIR between 1900-4000 cm-1. A single-layer radiative transfer model was developed to estimate spatial maps of temperature and column densities of CO and CO2 from the hyperspectral imagery of the boundary layer plume. The spectral model was used to compute the absorption cross sections of CO and CO2, using spectral line parameters from the high temperature extension of the HITRAN. Also, spatial maps of gas-phase temperature and methyl methacrylate (MMA) concentration were developed from laser irradiated carbon black-pigmented PMMA at irradiances of 4-22 W/cm2. Global kinetics interplay between heterogeneous and homogeneous combustion kinetics are shown from experimental observations at high spatial resolutions. Overall the boundary layer profile at steady-state is consistent with CO being mainly produced at the surface by heterogeneous reactions followed by a rapid homogeneous combustion in the boundary layer towards buoyancy.

  3. Chemistry Division annual progress report for period ending April 30, 1993

    Energy Technology Data Exchange (ETDEWEB)

    Poutsma, M.L.; Ferris, L.M.; Mesmer, R.E.

    1993-08-01

    The Chemistry Division conducts basic and applied chemical research on projects important to DOE`s missions in sciences, energy technologies, advanced materials, and waste management/environmental restoration; it also conducts complementary research for other sponsors. The research are arranged according to: coal chemistry, aqueous chemistry at high temperatures and pressures, geochemistry, chemistry of advanced inorganic materials, structure and dynamics of advanced polymeric materials, chemistry of transuranium elements and compounds, chemical and structural principles in solvent extraction, surface science related to heterogeneous catalysis, photolytic transformations of hazardous organics, DNA sequencing and mapping, and special topics.

  4. Patos Lagoon Outflow Within the Rio de la Plata Plume Using an Airborne Salinity Mapper: Observing an Embedded Plume

    Science.gov (United States)

    2008-01-01

    stress forcing, the Patos plume will be subject to advection and Numerical hydrodynamic model tests are presently being con- shear associated with...changes in the effectiveness of wind and ducted to study the transient behavior of the plumes. These tests , bottom stress as a function of water depth...Brigada de Mantenimiento, Servicio Application of data from near-coincident airborne and in-situ de Sensores Remotos y Aeroespaciales, and Escuadr6n

  5. Saturn Magnetospheric Impact on Surface Molecular Chemistry and Astrobiological Potential of Enceladus

    Science.gov (United States)

    Cooper, P. D.; Cooper, J. F.; Sittler, E. C.; Burger, M. H.; Sturner, S. J.; Rymer, A. M.

    2008-12-01

    The active south polar surface of Enceladus is exposed to strong chemical processing by direct interaction with charged plasma and energetic particles in the local magnetospheric environment of this icy moon. Chemical oxidation activity is suggested by detection of H2O2 at the surface in this region and less directly by substantial presence of CO2, CO, and N2 in the plume gases. Molecular composition of the uppermost surface, including ejecta from plume activity, is radiolytically transformed mostly by penetrating energetic electrons with lesser effects from more depleted populations of energetic protons. The main sources of molecular plasma ions and E-ring dust grains in the magnetospheric environment are the cryovolcanic plume emissions from Enceladus. These molecular ions and the dust grains are chemically processed by magnetospheric interactions that further impact surface chemistry on return to Enceladus. For example, H2O neutrals dominating the emitted plume gas return to the surface mostly as H3O+ ions after magnetospheric processing. Surface oxidant loading is further increased by return of radiolytically processed ice grains from the E-ring. Plume frost deposition and micrometeoroid gardening protect some fraction of newly produced molecular species from destruction by further irradiation. The evident horizontal and vertical mobility of surface ices in the south polar region drive mixing of these processed materials into the moon interior with potential impacts on deep ice molecular chemistry and plume gas production. Similarly as suggested previously for Europa, the externally driven source of radiolytic oxidants could affect evolution of life in any subsurface liquid water environments of Enceladus.

  6. Using ASCEM Modeling and Visualization to Inform Stakeholders of Contaminant Plume Evolution and Remediation Efficacy at F-Basin Savannah River, SC – 15156

    Energy Technology Data Exchange (ETDEWEB)

    Flach, G. [Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States); Wainwright, H. [Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States); Molins, S. [Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States); Davis, J. [Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States); Arora, B. [Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States); Faybishenko, B. [Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States); Krishnan, H. [Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States); Hubbard, S. [Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States); Flach, G. [Savannah River Site (SRS), Aiken, SC (United States). Savannah River National Lab. (SRNL); Denham, M. [Savannah River Site (SRS), Aiken, SC (United States). Savannah River National Lab. (SRNL); Eddy-Dilek, C. [Savannah River Site (SRS), Aiken, SC (United States). Savannah River National Lab. (SRNL); Moulton, D. [Los Alamos National Lab. (LANL), Los Alamos, NM (United States); Lipnikov, K. [Los Alamos National Lab. (LANL), Los Alamos, NM (United States); Gable, C. [Los Alamos National Lab. (LANL), Los Alamos, NM (United States); Miller, T. [Los Alamos National Lab. (LANL), Los Alamos, NM (United States); Freshley, M. [Pacific Northwest National Lab. (PNNL), Richland, WA (United States)

    2015-01-28

    Communication with stakeholders, regulatory agencies, and the public is an essential part of implementing different remediation and monitoring activities, and developing site closure strategies at contaminated sites. Modeling of contaminant plume evolution plays a critical role in estimating the benefit, cost, and risk of particular options. At the same time, effective visualization of monitoring data and modeling results are particularly important for conveying the significance of the results and observations. In this paper, we present the results of the Advanced Simulation Capability for Environmental Management (ASCEM) project, including the discussion of the capabilities of newly developed ASCEM software package, along with its application to the F-Area Seepage Basins located in the U.S. Department of Energy Savannah River Site (SRS). ASCEM software includes state-of-the-art numerical methods for simulating complex flow and reactive transport, as well as various toolsets such as a graphical user interface (GUI), visualization, data management, uncertainty quantification, and parameter estimation. Using this software, we have developed an advanced visualization of tritium plume migration coupled with a data management system, and simulated a three-dimensional model of flow and plume evolution on a high-performance computing platform. We evaluated the effect of engineered flow barriers on a nonreactive tritium plume, through advanced plume visualization and modeling of tritium plume migration. In addition, we developed a geochemical reaction network to describe complex geochemical processes at the site, and evaluated the impact of coupled hydrological and geochemical heterogeneity. These results are expected to support SRS’s monitoring activities and operational decisions.

  7. Flow of miscible and immiscible hydrocarbons in heterogeneous porous media

    Energy Technology Data Exchange (ETDEWEB)

    Butts, M.B.

    1996-12-31

    A series of large-scale two-dimensional physical model studies has been carried out in order to better understand and predict the multiphase flow of hydrocarbon contaminants and the release of the water-soluble fraction of such contaminants into the groundwater stream. The detailed measurements of the fluid saturations within the bulk hydrocarbon plume as well as the aqueous concentrations recorded downstream should provide a useful data set for testing and improving numerical models of both multiphase flow and transport. Predictions of a numerical model of immiscible multiphase flow developed in the petroleum industry were found to compare favourably with the observed oil plume for the case of an immiscible oil spill. Nevertheless, subtle layering within the experimental flume altered the long-term development of the oil plume in a manner not predicted by the numerical model. A stochastic model for three-dimensional, two-phase incompressible flow in heterogeneous soil and rock formations is developed. Analytical solutions for the resulting stochastic differential equations are derived for asymptotic flows using a perturbation approach. These solutions were used to derive general expressions for the large-scale (effective) properties for large-scale two-phase flow in porous media. An important observation from this analysis is that general large-scale flow in heterogeneous soils cannot be predicted on the basis of simple averages of the soil hydraulic properties alone. The large-scale capillary pressure saturation relation is evaluated for imbibition into a wet soil or rock formation. (EG) 194 refs.

  8. Amazon Plume Salinity Response to Ocean Teleconnections

    Directory of Open Access Journals (Sweden)

    Pedro Tyaquiçã

    2017-08-01

    Full Text Available Pacific and Atlantic sea surface temperature (SST variability strongly influences rainfall changes in the Amazon River basin, which impacts on the river discharge and consequently the sea surface salinity (SSS in the Amazon plume. An Empirical Orthogonal Function (EOF analysis was performed using 46 years of SST, rainfall, and SSS datasets, in order to establish the relationship between these variables. The first three modes of SST/rainfall explained 87.83% of the total covariance. Pacific and Atlantic SSTs led Amazon basin rainfall events by 4 months. The resultant SSS in the western tropical North Atlantic (WTNA lagged behind basin rainfall by 3 months, with 75.04% of the total covariance corresponding to the first four EOF modes. The first EOF mode indicated a strong SSS pattern along the coast that was connected to negative rainfall anomalies covering the Amazon basin, linked to El Niño events. A second pattern also presented positive SSS anomalies, when the rainfall was predominantly over the northwestern part of the Amazon basin, with low rainfall around the Amazon River mouth. The pattern with negative SSS anomalies in the WTNA was associated with the fourth mode, when positive rainfall anomalies were concentrated in the northwest part of South America. The spatial rainfall structure of this fourth mode was associated with the spatial rainfall distribution found in the third EOF mode of SST vs. rainfall, which was a response to La Niña Modoki events. A statistical analysis for the 46 year period and monthly anomaly composites for 2008 and 2009 indicated that La Niña Modoki events can be used for the prediction of low SSS patterns in the WNTA.

  9. Rift-plume interaction reveals multiple generations of recycled oceanic crust in Azores lavas

    Science.gov (United States)

    Béguelin, Paul; Bizimis, Michael; Beier, Christoph; Turner, Simon

    2017-12-01

    We present 176Hf/177Hf isotope ratios on 41 previously well-characterized subaerial and submarine samples from the Azores islands of São Miguel, Terceira, Graciosa, Faial, Pico and the João de Castro seamount (on the Terceira Rift). In εNd-εHf isotope space all Azores lavas fall below the mantle array reference line and do not overlap the proximal Atlantic MORB. Lavas from São Miguel and João de Castro form two distinct and well defined arrays extending below the mantle array, which has not been previously documented in other oceanic magmatic provinces. The Nd-Hf isotope compositions of João de Castro overlap those of HIMU type lavas, yet they lack the characteristically radiogenic Pb isotope ratios of HIMU. The combined Nd-Hf-Pb-Sr isotope systematics of both São Miguel and João de Castro endmembers can be explained by recycling of a single package of heterogeneous oceanic crust ranging from D-MORB to E-MORB in composition, with an age between 2.5 and 3.0 Ga, with no requirement for parent-daughter ratio modification during subduction. In contrast the Nd-Hf-Pb isotope systematics of lavas from São Jorge, Terceira, Graciosa, Pico and Faial are consistent with the presence of younger (<700 Ma) recycled crust that underwent low-temperature alteration and dehydration during subduction. There is no evidence in the erupted lavas for direct mixing between these two generations of recycled material within the plume. These data suggest that old recycling age and absence of sediments along with recycled oceanic crust are both required to develop isotopic compositions below the mantle array in εNd-εHf space. Our modeling shows that the compositional variability of erupted MORB is large enough that, given enough time, they can generate a wide range of isotope compositions such as observed in OIB. Lastly, lava compositions along the Terceira rift can be explained by a westward asthenospheric flux along a tilted lithosphere/asthenosphere boundary, where fertile

  10. Persistence of uranium groundwater plumes: Contrasting mechanisms at two DOE sites in the groundwater-river interaction zone

    Energy Technology Data Exchange (ETDEWEB)

    Zachara, John M.; Long, Philip E.; Bargar, John; Davis, James A.; Fox, Patricia M.; Fredrickson, Jim K.; Freshley, Mark D.; Konopka, Allan; Liu, Chongxuan; McKinley, James P.; Rockhold, Mark L.; Williams, Kenneth H.; Yabusaki, Steven B.

    2013-04-01

    between the sites include the geochemical nature of residual, contaminant U; the rates of current kinetic processes (both biotic and abiotic) influencing U(VI) solid-liquid distribution; the presence of detrital organic matter and the resulting spatial heterogeneity in microbially-driven redox properties; and the magnitude of groundwater hydrologic dynamics controlled by river-stage fluctuations, geologic structures, and aquifer hydraulic properties. The comparative analysis of these sites provides important guidance to the characterization, understanding, modeling, and remediation of groundwater contaminant plumes influenced by surface water interaction that are common world-wide.

  11. Enceladus Plume Structure and Time Variability: Comparison of Cassini Observations.

    Science.gov (United States)

    Teolis, Ben D; Perry, Mark E; Hansen, Candice J; Waite, J Hunter; Porco, Carolyn C; Spencer, John R; Howett, Carly J A

    2017-09-01

    During three low-altitude (99, 66, 66 km) flybys through the Enceladus plume in 2010 and 2011, Cassini's ion neutral mass spectrometer (INMS) made its first high spatial resolution measurements of the plume's gas density and distribution, detecting in situ the individual gas jets within the broad plume. Since those flybys, more detailed Imaging Science Subsystem (ISS) imaging observations of the plume's icy component have been reported, which constrain the locations and orientations of the numerous gas/grain jets. In the present study, we used these ISS imaging results, together with ultraviolet imaging spectrograph stellar and solar occultation measurements and modeling of the three-dimensional structure of the vapor cloud, to constrain the magnitudes, velocities, and time variability of the plume gas sources from the INMS data. Our results confirm a mixture of both low and high Mach gas emission from Enceladus' surface tiger stripes, with gas accelerated as fast as Mach 10 before escaping the surface. The vapor source fluxes and jet intensities/densities vary dramatically and stochastically, up to a factor 10, both spatially along the tiger stripes and over time between flyby observations. This complex spatial variability and dynamics may result from time-variable tidal stress fields interacting with subsurface fissure geometry and tortuosity beyond detectability, including changing gas pathways to the surface, and fluid flow and boiling in response evolving lithostatic stress conditions. The total plume gas source has 30% uncertainty depending on the contributions assumed for adiabatic and nonadiabatic gas expansion/acceleration to the high Mach emission. The overall vapor plume source rate exhibits stochastic time variability up to a factor ∼5 between observations, reflecting that found in the individual gas sources/jets. Key Words: Cassini at Saturn-Geysers-Enceladus-Gas dynamics-Icy satellites. Astrobiology 17, 926-940.

  12. Anthropogenic plumes from metropolitan areas and biomass burning emissions in West Africa during DACCIWA - airborne measurements on board the DLR Falcon 20

    Science.gov (United States)

    Stratmann, Greta; Schlager, Hans; Sauer, Daniel; Brocchi, Vanessa; Catoire, Valery; Baumann, Robert

    2017-04-01

    The DACCIWA (Dynamics-Aerosol-Chemistry-Cloud Interactions over West Africa) airborne field campaign was conducted in Southern West Africa in June/July 2016. Three European research aircraft (DLR - Falcon 20, SAFIRE - ATR 42 and BAS - Twin Otter) were deployed from Lomé/Togo and conducted research flights across Ivory Coast, Ghana, Togo and Benin. On board the DLR Falcon O3, SO2, CO, NO2 and aerosol fine mode particle number concentration and size distribution were measured during a total of 12 scientific flights. Until now only few airborne trace gas measurements were conducted in Southern West Africa. Therefore, this field experiment contributes to the knowledge of the chemical composition of the lower troposphere between 0 - 4 km. During several flights pollution plumes from major population centers - Lomé/Togo, Accra/Ghana, Kumasi/Ghana, and Abidjan/Ivory Coast - were probed below, inside and above clouds. Here, enhanced trace gas and particle concentrations were observed. In addition, plumes from biomass burning emissions were detected which were transported to West Africa. The composition of the pollution plumes are presented as well as transport pathways using HYSPLIT (Hybrid Single-Particle Lagrangian Integrated Trajectories) trajectory calculations. Ozone enhancements in the biomass burning pollution plumes of up to 70 ppb were observed compared to background concentrations of 30-40 ppb. Furthermore, HYSPLIT atmospheric dispersion simulations are used to estimate anthropogenic SO2 city emissions.

  13. Petrogenesis of the end-Cretaceous diamondiferous Behradih orangeite pipe: implication for mantle plume-lithosphere interaction in the Bastar craton, Central India

    Science.gov (United States)

    Chalapathi Rao, N. V.; Lehmann, B.; Mainkar, D.; Belyatsky, B.

    2011-05-01

    We present mineral chemistry, geochemistry and Sr and Nd isotope data of drillcore samples from the Late Cretaceous (65 Ma), diamondiferous Behradih ultramafic pipe, Bastar craton, Central India, which is emplaced synchronous with the Deccan flood basalt eruption. The rock is affected by pervasive serpentine-talc-carbonate alteration and consists of pelletal lapilli and variously sized olivine and phlogopite macrocrysts, set in a groundmass of abundant clinopyroxene, chrome spinel, apatite, Fe-rich perovskite (Deccan flood basalt magmatism, we infer a common tectonomagmatic control vis-a-vis the Deccan-related mantle plume. Trace element ratios and the Nd isotope signatures of the Behradih pipe imply that the Deccan plume has only contributed heat, but not substantial melt, to the Behradih magma with a cause-and-consequence relationship between them. Our study highlights (a) a striking similarity in the genesis of Late Cretaceous orangeites associated with the continental flood basalts in the Kaapvaal and Bastar cratons but related to different mantle plumes and (b) the role of plume-lithosphere interaction in the generation of orangeites.

  14. Journal of Business Chemistry

    OpenAIRE

    2013-01-01

    The Journal of Business Chemistry examines issues associated with leadership and management for chemists and managers working in chemical research or industry. This journal is devoted to improving and developing the field of Business Chemistry. The Journal of Business Chemistry publishes peer-reviewed papers (including case studies) and essays. Areas for possible publication in include: leadership issues in the chemical and biochemical industry, such as teamwork, team building, mentoring, coa...

  15. Orbital interactions in chemistry

    CERN Document Server

    Albright, Thomas A; Whangbo, Myung-Hwan

    2013-01-01

    Explains the underlying structure that unites all disciplines in chemistry Now in its second edition, this book explores organic, organometallic, inorganic, solid state, and materials chemistry, demonstrating how common molecular orbital situations arise throughout the whole chemical spectrum. The authors explore the relationships that enable readers to grasp the theory that underlies and connects traditional fields of study within chemistry, thereby providing a conceptual framework with which to think about chemical structure and reactivity problems. Orbital Interactions

  16. Green heterogeneous wireless networks

    CERN Document Server

    Ismail, Muhammad; Nee, Hans-Peter; Qaraqe, Khalid A; Serpedin, Erchin

    2016-01-01

    This book focuses on the emerging research topic "green (energy efficient) wireless networks" which has drawn huge attention recently from both academia and industry. This topic is highly motivated due to important environmental, financial, and quality-of-experience (QoE) considerations. Specifically, the high energy consumption of the wireless networks manifests in approximately 2% of all CO2 emissions worldwide. This book presents the authors’ visions and solutions for deployment of energy efficient (green) heterogeneous wireless communication networks. The book consists of three major parts. The first part provides an introduction to the "green networks" concept, the second part targets the green multi-homing resource allocation problem, and the third chapter presents a novel deployment of device-to-device (D2D) communications and its successful integration in Heterogeneous Networks (HetNets). The book is novel in that it specifically targets green networking in a heterogeneous wireless medium, which re...

  17. Laminar and turbulent surgical plume characteristics generated from curved- and straight-blade laparoscopic ultrasonic dissectors.

    Science.gov (United States)

    Kim, Fernando J; Sehrt, David; Pompeo, Alexandre; Molina, Wilson R

    2014-05-01

    To characterize laparoscopic ultrasonic dissector surgical plume emission (laminar or turbulent) and investigate plume settlement time between curved and straight blades. A straight and a curved blade laparoscopic ultrasonic dissector were activated on tissue and in a liquid environment to evaluate plume emission. Plume emission was characterized as either laminar or turbulent and the plume settlement times were compared. Devices were then placed in liquid to observed consistency in the fluid disruption. Two types of plume emission were identified generating different directions of plume: laminar flow causes minimal visual obstruction by directing the aerosol downwards, while turbulent flow directs plume erratically across the cavity. Laminar plume dissipates immediately while turbulent plume reaches a second maximum obstruction approximately 0.3 s after activation and clears after 2 s. Turbulent plume was observed with the straight blade in 10 % of activations, and from the curved blade in 47 % of activations. The straight blade emitted less obstructive plume. Turbulent flow is disruptive to laparoscopic visibility with greater field obstruction and requires longer settling than laminar plume. Ultrasonic dissectors with straight blades have more consistent oscillations and generate more laminar flow compared with curved blades. Surgeons may avoid laparoscope smearing from maximum plume generation depending on blade geometry.

  18. USSR Report, Chemistry

    National Research Council Canada - National Science Library

    1986-01-01

    This USSR Report on Chemistry contains articles on Aerosols, Adsorption, Biochemistry, Catalysis, Chemical Industry, Coal Gasification, Electrochemistry, Explosives and Explosions, Fertilizers, Food...

  19. Advances in quantum chemistry

    CERN Document Server

    Sabin, John R

    2013-01-01

    Advances in Quantum Chemistry presents surveys of current topics in this rapidly developing field that has emerged at the cross section of the historically established areas of mathematics, physics, chemistry, and biology. It features detailed reviews written by leading international researchers. This volume focuses on the theory of heavy ion physics in medicine.Advances in Quantum Chemistry presents surveys of current topics in this rapidly developing field that has emerged at the cross section of the historically established areas of mathematics, physics, chemistry, and biology. It features

  20. Canopy Chemistry (OTTER)

    Data.gov (United States)

    National Aeronautics and Space Administration — Canopy characteristics: leaf chemistry, specific leaf area, LAI, PAR, IPAR, NPP, standing biomass--see also: Meteorology (OTTER) for associated meteorological...

  1. Solution phase combinatorial chemistry.

    Science.gov (United States)

    Merritt, A T

    1998-06-01

    Combinatorial chemistry and parallel array synthesis techniques are now used extensively in the drug discovery process. Although published literature has been dominated by solid phase chemistry approaches, the use of solution phase techniques has also been widely explored. This review considers the advantages and disadvantages of choosing solution phase approaches in the various stages of drug discovery and optimisation, and assesses the practical issues related to these approaches. The uses of standard solution chemistry, the related liquid phase approach, and of supported materials to enhance solution phase chemistry are all illustrated by a comprehensive review of the published literature over the past three years.

  2. Elements of environmental chemistry

    National Research Council Canada - National Science Library

    Hites, R. A; Raff, Jonathan D

    2012-01-01

    ... more. Extensively revised, updated, and expanded, this second edition includes new chapters on atmospheric chemistry, climate change, and polychlorinated biphenyls and dioxins, and brominated flame retardants...

  3. Computational Chemistry for Kids

    National Research Council Canada - National Science Library

    Naef, Olivier

    2000-01-01

    This article aims to show that computational chemistry is not exclusively restricted to molecular energy and structure calculations but also includes chemical process control and reaction simulation...

  4. Green Chemistry Pedagogy

    Science.gov (United States)

    Kolopajlo, Larry

    2017-02-01

    This chapter attempts to show how the practice of chemistry teaching and learning is enriched by the incorporation of green chemistry (GC) into lectures and labs. To support this viewpoint, evidence from a wide range of published papers serve as a cogent argument that GC attracts and engages both science and nonscience students, enhances chemistry content knowledge, and improves the image of the field, while preparing the world for a sustainable future. Published pedagogy associated with green and sustainable chemistry is critically reviewed and discussed.

  5. Density Functional Theory in Surface Chemistry and Catalysis

    Energy Technology Data Exchange (ETDEWEB)

    Norskov, Jens

    2011-05-19

    Recent advances in the understanding of reactivity trends for chemistry at transition metal surfaces have enabled in silico design of heterogeneous catalysts in a few cases. Current status of the field is discussed with an emphasis on the role of coupling between theory and experiment and future challenges.

  6. Density functional theory in surface chemistry and catalysis

    Science.gov (United States)

    Nørskov, Jens K.; Abild-Pedersen, Frank; Studt, Felix; Bligaard, Thomas

    2011-01-01

    Recent advances in the understanding of reactivity trends for chemistry at transition-metal surfaces have enabled in silico design of heterogeneous catalysts in a few cases. The current status of the field is discussed with an emphasis on the role of coupling theory and experiment and future challenges. PMID:21220337

  7. Evaluation of Analytical Errors in a Clinical Chemistry Laboratory: A ...

    African Journals Online (AJOL)

    literature on laboratory error indicate great heterogeneity in the. Evaluation of Analytical Errors in a Clinical Chemistry. Laboratory: A 3 Year Experience. Sakyi AS1,2, Laing EF1,2, Ephraim RK3, Asibey OF2, Sadique OK2. 1Department of Molecular Medicine, School of Medical Sciences, College of Health Sciences, Kwame ...

  8. Density functional theory in surface chemistry and catalysis

    DEFF Research Database (Denmark)

    Nørskov, Jens Kehlet; Abild-Pedersen, Frank; Studt, Felix

    2011-01-01

    Recent advances in the understanding of reactivity trends for chemistry at transition-metal surfaces have enabled in silico design of heterogeneous catalysts in a few cases. The current status of the field is discussed with an emphasis on the role of coupling theory and experiment and future...

  9. Isotopes in heterogeneous catalysis

    CERN Document Server

    Hargreaves, Justin SJ

    2006-01-01

    The purpose of this book is to review the current, state-of-the-art application of isotopic methods to the field of heterogeneous catalysis. Isotopic studies are arguably the ultimate technique in in situ methods for heterogeneous catalysis. In this review volume, chapters have been contributed by experts in the field and the coverage includes both the application of specific isotopes - Deuterium, Tritium, Carbon-14, Sulfur-35 and Oxygen-18 - as well as isotopic techniques - determination of surface mobility, steady state transient isotope kinetic analysis, and positron emission profiling.

  10. Plume capture by a migrating ridge: Analog geodynamic experiments

    Science.gov (United States)

    Mendez, J. S.; Hall, P.

    2010-12-01

    Paleomagnetic data from the Hawaii-Emperor Seamount Chain (HESC) suggests that the Hawaiian hotspot moved rapidly (~40 mm/yr) between 81 - 47 Ma but has remained relatively stationary since that time. This implies that the iconic bend in the HESC may in fact reflect the transition from a period of rapid hotspot motion to a stationary state, rather than a change in motion of the Pacific plate. Tarduno et al. (2009) have suggested that this period of rapid hotspot motion might be the surface expression of a plume conduit returning to a largely vertical orientation after having been “captured” and tilted by a migrating mid-ocean ridge. We report on a series of analog fluid dynamic experiments designed to characterize the interaction between a migrating spreading center and a thermally buoyant mantle plume. Experiments were conducted in a clear acrylic tank (100 cm x 70 cm x 50 cm) filled with commercial grade high-fructose corn syrup. Plate-driven flow is modeled by dragging two sheets of Mylar film (driven by independent DC motors) in opposite directions over the surface of the fluid. Ridge migration is achieved by moving the point at which the mylar sheets diverge using a separate motor drive. Buoyant plume flow is modeled using corn syrup introduced into the bottom of the tank from an external, heated, pressurized reservoir. Small (~2 mm diameter), neutrally buoyant Delrin spheres are mixed into reservoir of plume material to aid in visualization. Plate velocities and ridge migration rate are controlled and plume temperature monitored using LabView software. Experiments are recorded using digital video which is then analyzed using digital image analysis software to track the position and shape of the plume conduit throughout the course of the experiment. The intersection of the plume conduit with the surface of the fluid is taken as an analog for the locus of hotspot volcanism and tracked as a function of time to obtain a hotspot migration rate. Experiments are

  11. Field experimental observations of highly graded sediment plumes.

    Science.gov (United States)

    Jensen, Jacob Hjelmager; Saremi, Sina; Jimenez, Carlos; Hadjioannou, Louis

    2015-06-15

    A field experiment in the waters off the south-eastern coast of Cyprus was carried out to study near-field formation of sediment plumes from dumping. Different loads of sediment were poured into calm and limpid waters one at the time from just above the sea surface. The associated plumes, gravitating towards the seafloor, were filmed simultaneously by four divers situated at different depths in the water column, and facing the plume at different angles. The processes were captured using GoPro-Hero-series cameras. The high-quality underwater footage from near-surface, mid-depth and near-bed positions gives unique insight into the dynamics of the descending plume and near-field dispersion processes, and enables good understanding of flow and sediment transport processes involved from-release-to-deposition of the load in a non-scaled environment. The high resolution images and footages are available through the link provided herein. Observations support the development of a detailed multi-fractional sediment plume model. Copyright © 2015 Elsevier Ltd. All rights reserved.

  12. Pyroxenite in the Galapagos plume source at 65 Ma

    Science.gov (United States)

    Whalen, W. T.; Gazel, E.; Vidito, C. A.; Herzberg, C. T.; Class, C.; Bizimis, M.; Alvarado-Induni, G.

    2013-12-01

    Mantle plumes originate from boundary layers below the upper mantle. Their surface expressions as hotspot tracks have been linked to voluminous outpourings of lava in the form of large igneous provinces. The Galapagos hotspot has been active since ~90 Ma and the oldest lavas of its associated submarine ridge have been dated to ~14 Ma, subducting at the Middle America Trench, off Costa Rica. The Galapagos plume head magmatic production is preserved as the Caribbean Large Igneous Province (CLIP). A series of 15-65 Ma accreted Galapagos paleo-ridges and islands/seamounts are accreted in the Pacific coast of Costa Rica and Panama. One of these accreted terranes, the Quepos block on the west coast of Costa Rica is an ancient, ~65 Ma Galapagos island. Olivine phenocrysts from Quepos picrites have elevated Ni and low Ca and Mn and Fe/Mn indicative of a dominant pyroxenite source component while CLIP samples are dominated by a peridotite source. The mantle potential temperature (max) of the plume changed from ~1650 to ~1550 C at 65 Ma. This change correlates with the first appearance of the pyroxenite component and an EMII signature (Northern Galapagos Domain) in the Galapagos plume. A relatively dense pyroxenite component may provide a mechanism for the change in Tp due to its effect on the plume's bouyancy. Alternatively, the pyroxenite component was diluted by high peridotite melt fraction during the massive production of the CLIP.

  13. Laser beam-plasma plume interaction during laser welding

    Science.gov (United States)

    Hoffman, Jacek; Moscicki, Tomasz; Szymanski, Zygmunt

    2003-10-01

    Laser welding process is unstable because the keyhole wall performs oscillations which results in the oscillations of plasma plume over the keyhole mouth. The characteristic frequencies are equal to 0.5-4 kHz. Since plasma plume absorbs and refracts laser radiation, plasma oscillations modulate the laser beam before it reaches the workpiece. In this work temporary electron densities and temperatures are determined in the peaks of plasma bursts during welding with a continuous wave CO2 laser. It has been found that during strong bursts the plasma plume over the keyhole consists of metal vapour only, being not diluted by the shielding gas. As expected the values of electron density are about two times higher in peaks than their time-averaged values. Since the plasma absorption coefficient scales as ~N2e/T3/2 (for CO2 laser radiation) the results show that the power of the laser beam reaching the metal surface is modulated by the plasma plume oscillations. The attenuation factor equals 4-6% of the laser power but it is expected that it is doubled by the refraction effect. The results, together with the analysis of the colour pictures from streak camera, allow also interpretation of the dynamics of the plasma plume.

  14. Jet plume injection and combustion system for internal combustion engines

    Science.gov (United States)

    Oppenheim, Antoni K.; Maxson, James A.; Hensinger, David M.

    1993-01-01

    An improved combustion system for an internal combustion engine is disclosed wherein a rich air/fuel mixture is furnished at high pressure to one or more jet plume generator cavities adjacent to a cylinder and then injected through one or more orifices from the cavities into the head space of the cylinder to form one or more turbulent jet plumes in the head space of the cylinder prior to ignition of the rich air/fuel mixture in the cavity of the jet plume generator. The portion of the rich air/fuel mixture remaining in the cavity of the generator is then ignited to provide a secondary jet, comprising incomplete combustion products which are injected into the cylinder to initiate combustion in the already formed turbulent jet plume. Formation of the turbulent jet plume in the head space of the cylinder prior to ignition has been found to yield a higher maximum combustion pressure in the cylinder, as well as shortening the time period to attain such a maximum pressure.

  15. Infrared signature characteristic of a microturbine engine exhaust plume

    Science.gov (United States)

    Gu, Bonchan; Baek, Seung Wook; Jegal, Hyunwook; Choi, Seong Man; Kim, Won Cheol

    2017-11-01

    This research investigates the infrared signature of the exhaust plume ejected from a microturbine engine. Circular and square nozzles are designed and tested to study their effects on the resultant infrared signature of the plume. A microturbine engine is operated under steady conditions with a kerosene added lubricant oil as a fuel. The measurements of the infrared signature are conducted using a spectroradiometer. Blackbody radiance is also measured at an arbitrary temperature and compared to theoretical values to validate the reference and to calibrate the raw spectrum. The infrared signatures emitted from the plume are measured at three measurement locations along the plume for two nozzle configurations. The results are grouped into sub-bands to examine and discuss their specific spectral characteristics. The infrared signatures are shown to decrease as the distance from the nozzle exit increases, which is attributed to the hot exhaust plume mixing with ambient air. The degree to which the signature is reduced at the different the measurement locations was dependent on the sub-band. Comparison of the results shows that the infrared signature of the square nozzle is lower than that of the circular nozzle in specific bands.

  16. Modern Trends in Inorganic Chemistry

    Indian Academy of Sciences (India)

    Unknown

    projections of research in frontier areas of inorganic chemistry, includ- ing organometallics, bio-inorganic chemistry, catalysis and materials chemistry. We do hope that the wide range of topics covered in this Issue reflect the current trends of research in inorganic chemistry in India and prac- titioners of inorganic chemistry ...

  17. Heterogeneity and option pricing

    NARCIS (Netherlands)

    Benninga, Simon; Mayshar, Joram

    2000-01-01

    An economy with agents having constant yet heterogeneous degrees of relative risk aversion prices assets as though there were a single decreasing relative risk aversion pricing representative agent. The pricing kernel has fat tails and option prices do not conform to the Black-Scholes formula.

  18. Why does heterogeneity matter?

    Science.gov (United States)

    K.B. Pierce

    2007-01-01

    This is a review of the book "Ecosystem function in heterogeneous landscapes" published in 2005. The authors are G. Lovett, C. Jones, M.G. Turner, and K.C. Weathers. It was published by Springer, New York. The book is a synthesis of the 10th Gary conference held at the Institute of Ecosystem Studies in Millbrook, New York, in 2003.

  19. Heterogeneous chromium catalysts

    NARCIS (Netherlands)

    2005-01-01

    The present invention relates to a heterogeneous chromium catalyst system for the polymerisation of ethylene and/or alpha olefins prepared by the steps of: (a) providing a silica-containing support, (b) treating the silica-containing support with a chromium compound to form a chromium-based

  20. Receiver Heterogeneity Helps

    DEFF Research Database (Denmark)

    Kovács, Erika R.; Pedersen, Morten Videbæk; Roetter, Daniel Enrique Lucani

    2014-01-01

    Heterogeneity amongst devices and desired service are commonly seen as a source of additional challenges for setting up an efficient multi-layer multicast service. In particular, devices requiring only the base layer can become a key bottleneck to the performance for other devices. This paper...

  1. Heterogeneity of Intellectual Assets

    DEFF Research Database (Denmark)

    Dahlgren, Johan Henrich; Lund Jensen, Rasmus; Valentin, Finn

    2004-01-01

    This paper deals with methodological issues of assessing the composition and level ofheterogeneity of firms' intellectual assets. It develops an original metric - referred to asthe H-index - for measuring heterogeneity using data extracted from patent documents.The main purpose is to improve...

  2. Quantifying hidden individual heterogeneity

    DEFF Research Database (Denmark)

    Steiner, Ulrich; Lenart, Adam; Vaupel, James W.

    Aging is assumed to be driven by the accumulation of damage or some other aging factor which shapes demographic patterns, including the classical late age mortality plateaus. However to date, heterogeneity in these damage stages is not observed. Here, we estimate underlying stage distributions...

  3. Heterogeneity of Dutch rainfall

    NARCIS (Netherlands)

    Witter, J.V.

    1984-01-01

    Rainfall data for the Netherlands have been used in this study to investigate aspects of heterogeneity of rainfall, in particular local differences in rainfall levels, time trends in rainfall, and local differences in rainfall trend. The possible effect of urbanization and industrialization on the

  4. Heterogeneous computing in economics

    DEFF Research Database (Denmark)

    Dziubinski, Matt P.; Grassi, Stefano

    2014-01-01

    This paper shows the potential of heterogeneous computing in solving dynamic equilibrium models in economics. We illustrate the power and simplicity of C++ Accelerated Massive Parallelism (C++ AMP) recently introduced by Microsoft. Starting from the same exercise as Aldrich et al. (J Econ Dyn...

  5. Scales of mantle heterogeneity

    Science.gov (United States)

    Moore, J. C.; Akber-Knutson, S.; Konter, J.; Kellogg, J.; Hart, S.; Kellogg, L. H.; Romanowicz, B.

    2004-12-01

    A long-standing question in mantle dynamics concerns the scale of heterogeneity in the mantle. Mantle convection tends to both destroy (through stirring) and create (through melt extraction and subduction) heterogeneity in bulk and trace element composition. Over time, these competing processes create variations in geochemical composition along mid-oceanic ridges and among oceanic islands, spanning a range of scales from extremely long wavelength (for example, the DUPAL anomaly) to very small scale (for example, variations amongst melt inclusions). While geochemical data and seismic observations can be used to constrain the length scales of mantle heterogeneity, dynamical mixing calculations can illustrate the processes and timescales involved in stirring and mixing. At the Summer 2004 CIDER workshop on Relating Geochemical and Seismological Heterogeneity in the Earth's Mantle, an interdisciplinary group evaluated scales of heterogeneity in the Earth's mantle using a combined analysis of geochemical data, seismological data and results of numerical models of mixing. We mined the PetDB database for isotopic data from glass and whole rock analyses for the Mid-Atlantic Ridge (MAR) and the East Pacific Rise (EPR), projecting them along the ridge length. We examined Sr isotope variability along the East Pacific rise by looking at the difference in Sr ratio between adjacent samples as a function of distance between the samples. The East Pacific Rise exhibits an overall bowl shape of normal MORB characteristics, with higher values in the higher latitudes (there is, however, an unfortunate gap in sampling, roughly 2000 km long). These background characteristics are punctuated with spikes in values at various locations, some, but not all of which are associated with off-axis volcanism. A Lomb-Scargle periodogram for unevenly spaced data was utilized to construct a power spectrum of the scale lengths of heterogeneity along both ridges. Using the same isotopic systems (Sr, Nd

  6. Diversity in Medicinal Chemistry.

    Science.gov (United States)

    Peralta, David

    2018-01-08

    The wide world of medicinal chemistry: We look back at our activities in 2017, particularly the expansion of the journal's scope to nanomedicine and why we need a more inclusive medicinal chemistry journal. Additionally, we look at upcoming special issues and developments for ChemPubSoc Europe in 2018. © 2018 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim.

  7. Chemistry in Microfluidic Channels

    Science.gov (United States)

    Chia, Matthew C.; Sweeney, Christina M.; Odom, Teri W.

    2011-01-01

    General chemistry introduces principles such as acid-base chemistry, mixing, and precipitation that are usually demonstrated in bulk solutions. In this laboratory experiment, we describe how chemical reactions can be performed in a microfluidic channel to show advanced concepts such as laminar fluid flow and controlled precipitation. Three sets of…

  8. Exercises in Computational Chemistry

    DEFF Research Database (Denmark)

    Spanget-Larsen, Jens

    2016-01-01

    A selection of HyperChem© PC-exercises in computational chemistry. Answers to most questions are appended (Roskilde University 2014-16).......A selection of HyperChem© PC-exercises in computational chemistry. Answers to most questions are appended (Roskilde University 2014-16)....

  9. The Breath of Chemistry

    DEFF Research Database (Denmark)

    Josephsen, Jens

    The present preliminary text is a short thematic presentation in biological inorganic chemistry meant to illustrate general and inorganic (especially coordination) chemistry in biochemistry. The emphasis is on molecular models to explain features of the complicated mechanisms essential to breathing...

  10. Movies in Chemistry Education

    Science.gov (United States)

    Pekdag, Bulent; Le Marechal, Jean-Francois

    2010-01-01

    This article reviews numerous studies on chemistry movies. Movies, or moving pictures, are important elements of multimedia and signify a privileged or motivating means of presenting knowledge. Studies on chemistry movies show that the first movie productions in this field were devoted to university lectures or documentaries. Shorter movies were…

  11. Chemistry of americium

    Energy Technology Data Exchange (ETDEWEB)

    Schulz, W.W.

    1976-01-01

    Essential features of the descriptive chemistry of americium are reviewed. Chapter titles are: discovery, atomic and nuclear properties, collateral reading, production and uses, chemistry in aqueous solution, metal, alloys, and compounds, and, recovery, separation, purification. Author and subject indexes are included. (JCB)

  12. Chemistry is Evergreen

    Indian Academy of Sciences (India)

    Home; Journals; Resonance – Journal of Science Education; Volume 14; Issue 3. Chemistry is Everygreen - 2008 Nobel Prize in Chemistry. Swagata Dasgupta. General Article Volume 14 Issue 3 March 2009 pp 248-258. Fulltext. Click here to view fulltext PDF. Permanent link:

  13. Using the GPS SNR Technique to Detect Volcanic Plumes

    Science.gov (United States)

    Naik, S. R.; Mattia, M.; Larson, K. M.; Rossi, M.; Bruno, V.; Coltelli, M.; Ohta, Y.; Schneider, D. J.

    2015-12-01

    Detection of volcanic plumes, especially ash-laden ones, is important both for public health and aircraft safety. A variety of geophysical tools and satellite data are used to monitor volcanic eruptions and to predict the movement of ash. However, satellite-based methods are restricted by time of day and weather, while radars are often unavailable because of cost/ portability. GPS instruments are frequently deployed near volcanos, but typically they have only been used to measure deformation. Here a method is proposed to detect volcanic plumes using GPS signal to noise ratio (SNR) data. The strengths and limitations of the method are assessed using GPS data collected during eruptions at Mt. Redoubt (2009) and Mt. Etna (2013). Plume detections are compared with independently collected seismic and radar data.

  14. Quantification of Asian Dust Plume Seasonal Dynamics and Regional Features

    Science.gov (United States)

    Goetz, Michael

    2011-01-01

    Dust is but one of many aerosols that are analyzed at the Jet Propulsion Laboratory in Pasadena. The purpose of this paper is to describe the process in analyzing and digitizing dust within a source region to better explain the work achieved by my internship. This paper will go over how to view collected data by Multi-angle Imaging SpectroRadiometer (MISR) [1] and the procedure of downloading data to be analyzed. With this data, one can digitize dust plumes using two methods called plume lines and plume polygons with the help of the software MISR INteractive eXplorer (MINX)[3]; thus, the theory of MINX's[3] algorithm and these methods are discussed in detail. Research was gathered from these techniques and emphasis is also focused on the obtained data and results.

  15. Observations of primary and secondary emissions in a B747 exhaust plume in the upper troposphere and inferred engine exit plane OH concentrations

    Energy Technology Data Exchange (ETDEWEB)

    Schlager, H.; Schulte, P.; Tremmel, H.G.; Ziereis, H. [Deutsche Forschungsanstalt fuer Luft- und Raumfahrt e.V. (DLR), Wessling (Germany). Inst. fuer Physik der Atmosphaere; Arnold, F.; Droste-Franke, B.; Klemm, M.; Schneider, J. [Max-Planck-Inst. fuer Kernphysik, Heidelberg (Germany)

    1997-12-31

    The speciation of NO{sub y} exhaust emissions in the near-field plume of a B747 cruising at 9.2 km was measured in situ using the DLR Falcon research aircraft instrumented with a chemical ionisation mass spectrometer of MPI-K and a chemiluminescence NO detector of DLR. In addition, CO{sub 2} was measured providing a dilution factor for the exhaust species. Observed maximum peak concentrations above background in the plume 60 s after emission were 25.4 ppmv (CO{sub 2}), 184 ppbv (NO), 2.6 ppbv (HNO{sub 2}), and 1.3 ppbv (HNO{sub 3}). The observations were used to infer the initial OH concentration (15.4 ppmv) and NO{sub 2}/NO{sub x} ratio (0.08) at the engine exit by back calculations using a chemistry box model. (author) 20 refs.

  16. Transuranic Computational Chemistry.

    Science.gov (United States)

    Kaltsoyannis, Nikolas

    2018-02-26

    Recent developments in the chemistry of the transuranic elements are surveyed, with particular emphasis on computational contributions. Examples are drawn from molecular coordination and organometallic chemistry, and from the study of extended solid systems. The role of the metal valence orbitals in covalent bonding is a particular focus, especially the consequences of the stabilization of the 5f orbitals as the actinide series is traversed. The fledgling chemistry of transuranic elements in the +II oxidation state is highlighted. Throughout, the symbiotic interplay of experimental and computational studies is emphasized; the extraordinary challenges of experimental transuranic chemistry afford computational chemistry a particularly valuable role at the frontier of the periodic table. © 2018 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim.

  17. Biosynthetic inorganic chemistry.

    Science.gov (United States)

    Lu, Yi

    2006-08-25

    Inorganic chemistry and biology can benefit greatly from each other. Although synthetic and physical inorganic chemistry have been greatly successful in clarifying the role of metal ions in biological systems, the time may now be right to utilize biological systems to advance coordination chemistry. One such example is the use of small, stable, easy-to-make, and well-characterized proteins as ligands to synthesize novel inorganic compounds. This biosynthetic inorganic chemistry is possible thanks to a number of developments in biology. This review summarizes the progress in the synthesis of close models of complex metalloproteins, followed by a description of recent advances in using the approach for making novel compounds that are unprecedented in either inorganic chemistry or biology. The focus is mainly on synthetic "tricks" learned from biology, as well as novel structures and insights obtained. The advantages and disadvantages of this biosynthetic approach are discussed.

  18. Satellite detection of wastewater diversion plumes in Southern California

    Science.gov (United States)

    Gierach, Michelle M.; Holt, Benjamin; Trinh, Rebecca; Jack Pan, B.; Rains, Christine

    2017-02-01

    Multi-sensor satellite observations proved useful in detecting surfacing wastewater plumes during the 2006 Hyperion Treatment Plant (HTP) and 2012 Orange County Sanitation District (OCSD) wastewater diversion events in Southern California. Satellite sensors were capable of detecting biophysical signatures associated with the wastewater, compared to ambient ocean waters, enabling monitoring of environmental impacts over a greater spatial extent than in situ sampling alone. Thermal satellite sensors measured decreased sea surface temperatures (SSTs) associated with the surfacing plumes. Ocean color satellite sensors did not measure a distinguishable biological response in terms of chlorophyll-a (chl-a) concentrations during the short lived, three-day long, 2006 HTP diversion. A period of decreased chl-a concentration was observed during the three-week long 2012 OCSD diversion, likely in association with enhanced chlorination of the discharged wastewater that suppressed the phytoplankton response and/or significant uptake by heterotrophic bacteria. Synthetic aperture radar (SAR) satellite data were able to identify and track the 2006 HTP wastewater plume through changes in surface roughness related to the oily components of the treated surfacing wastewater. Overall, it was found that chl-a and SST values must have differences of at least 1 mg m-3 and 0.5 °C, respectively, in comparison with adjacent waters for wastewater plumes and their biophysical impact to be detectable from satellite. For a wastewater plume to be identifiable in SAR imagery, wind speeds must range between ∼3 and 8 m s-1. The findings of this study illustrate the benefit of utilizing multiple satellite sensors to monitor the rapidly changing environmental response to surfacing wastewater plumes, and can help inform future wastewater diversions in coastal areas.

  19. Subducting Plate Breakup by Plume-Lithosphere Interaction

    Science.gov (United States)

    Koptev, A.; Gerya, T.; Jolivet, L.; Leroy, S. D.

    2016-12-01

    We use a 3D high-resolution thermo-mechanical modeling to investigate the impact of active mantle plume on a subducting lithospheric plate. Initial model setup consists of an overriding continental lithosphere and subducting lithospheric plate including oceanic and continental lithosphere. A mantle plume thermal anomaly has been initially seeded at the bottom of the model box underneath the continental segment of subducting plate. Mantle plume impingement on lithospheric bottom leads to thinning of continental lithosphere and decompressional melting of both lithospheric and sublithospheric mantle along stretched trench-parallel zone. Further continental breakup is followed by opening of an oceanic basin separating a newly formed microcontinent from the main subducting continent. Despite continuous push applied at the boundary of subducting plate, plume-induced oceanic basin opens during several Myrs reaching several hundred kilometers wide. Cooling of the mantle plume and beginning of collision between the separated microcontinent and the overriding continental plate lead to gradual closure of newly formed oceanic basin that gets further involved into subduction and collision. The final stage sees continental subduction of main body of subducting plate and simultaneous tectonic exhumation of the upper crust of the subducted microcontinent. This scenario involving a plume-induced rifting of a microcontinent away from main body of subducted plate can be compared to the Mesozoic-Cenozoic development of the African plate characterized by the consecutive separation of the Apulian microcontinent and Arabian plate (in the Jurassic and the Neogene, respectively) during subduction of Neo-Tethys oceanic lithosphere beneath the Eurasian margin.

  20. Tidally induced lateral dispersion of the Storfjorden overflow plume

    Directory of Open Access Journals (Sweden)

    F. Wobus

    2013-10-01

    Full Text Available We investigate the flow of brine-enriched shelf water from Storfjorden (Svalbard into Fram Strait and onto the western Svalbard Shelf using a regional set-up of NEMO-SHELF, a 3-D numerical ocean circulation model. The model is set up with realistic bathymetry, atmospheric forcing, open boundary conditions and tides. The model has 3 km horizontal resolution and 50 vertical levels in the sh-coordinate system which is specially designed to resolve bottom boundary layer processes. In a series of modelling experiments we focus on the influence of tides on the propagation of the dense water plume by comparing results from tidal and non-tidal model runs. Comparisons of non-tidal to tidal simulations reveal a hotspot of tidally induced horizontal diffusion leading to the lateral dispersion of the plume at the southernmost headland of Spitsbergen which is in close proximity to the plume path. As a result the lighter fractions in the diluted upper layer of the plume are drawn into the shallow coastal current that carries Storfjorden water onto the western Svalbard Shelf, while the dense bottom layer continues to sink down the slope. This bifurcation of the plume into a diluted shelf branch and a dense downslope branch is enhanced by tidally induced shear dispersion at the headland. Tidal effects at the headland are shown to cause a net reduction in the downslope flux of Storfjorden water into the deep Fram Strait. This finding contrasts previous results from observations of a dense plume on a different shelf without abrupt topography.

  1. IASI measurements of reactive trace species in biomass burning plumes

    Directory of Open Access Journals (Sweden)

    P.-F. Coheur

    2009-08-01

    Full Text Available This work presents observations of a series of short-lived species in biomass burning plumes from the Infrared Atmospheric Sounding Interferometer (IASI, launched onboard the MetOp-A platform in October 2006. The strong fires that have occurred in the Mediterranean Basin – and particularly Greece – in August 2007, and those in Southern Siberia and Eastern Mongolia in the early spring of 2008 are selected to support the analyses. We show that the IASI infrared spectra in these fire plumes contain distinctive signatures of ammonia (NH3, ethene (C2H4, methanol (CH3OH and formic acid (HCOOH in the atmospheric window between 800 and 1200 cm−1, with some noticeable differences between the plumes. Peroxyacetyl nitrate (CH3COOONO2, abbreviated as PAN was also observed with good confidence in some plumes and a tentative assignment of a broadband absorption spectral feature to acetic acid (CH3COOH is made. For several of these species these are the first reported measurements made from space in nadir geometry. The IASI measurements are analyzed for plume height and concentration distributions of NH3, C2H4 and CH3OH. The Greek fires are studied in greater detail for the days associated with the largest emissions. In addition to providing information on the spatial extent of the plume, the IASI retrievals allow an estimate of the total mass emissions for NH3, C2H4 and CH3OH. Enhancement ratios are calculated for the latter relative to carbon monoxide (CO, giving insight in the chemical processes occurring during the transport, the first day after the emission.

  2. Multi-scale Modeling of Power Plant Plume Emissions and Comparisons with Observations

    Science.gov (United States)

    Costigan, K. R.; Lee, S.; Reisner, J.; Dubey, M. K.; Love, S. P.; Henderson, B. G.; Chylek, P.

    2011-12-01

    The Remote Sensing Verification Project (RSVP) test-bed located in the Four Corners region of Arizona, Utah, Colorado, and New Mexico offers a unique opportunity to develop new approaches for estimating emissions of CO2. Two major power plants located in this area produce very large signals of co-emitted CO2 and NO2 in this rural region. In addition to the Environmental Protection Agency (EPA) maintaining Continuous Emissions Monitoring Systems (CEMS) on each of the power plant stacks, the RSVP program has deployed an array of in-situ and remote sensing instruments, which provide both point and integrated measurements. To aid in the synthesis and interpretation of the measurements, a multi-scale atmospheric modeling approach is implemented, using two atmospheric numerical models: the Weather Research and Forecasting Model with chemistry (WRF-Chem; Grell et al., 2005) and the HIGRAD model (Reisner et al., 2003). The high fidelity HIGRAD model incorporates a multi-phase Lagrangian particle based approach to track individual chemical species of stack plumes at ultra-high resolution, using an adaptive mesh. It is particularly suited to model buoyancy effects and entrainment processes at the edges of the power plant plumes. WRF-Chem is a community model that has been applied to a number of air quality problems and offers several physical and chemical schemes that can be used to model the transport and chemical transformation of the anthropogenic plumes out of the local region. Multiple nested grids employed in this study allow the model to incorporate atmospheric variability ranging from synoptic scales to micro-scales (~200 m), while including locally developed flows influenced by the nearby complex terrain of the San Juan Mountains. The simulated local atmospheric dynamics are provided to force the HIGRAD model, which links mesoscale atmospheric variability to the small-scale simulation of the power plant plumes. We will discuss how these two models are applied and

  3. Korean Kimchi Chemistry: A Multicultural Chemistry Connection

    Science.gov (United States)

    Murfin, Brian

    2009-01-01

    Connecting science with different cultures is one way to interest students in science, to relate science to their lives, and at the same time to broaden their horizons in a variety of ways. In the lesson described here, students make kimchi, a delicious and popular Korean dish that can be used to explore many important chemistry concepts,…

  4. Synchronized Lunar Pole Impact Plume Sample Return Trajectory Design

    Science.gov (United States)

    Genova, Anthony L.; Foster, Cyrus; Colaprete, Tony

    2016-01-01

    The presented trajectory design enables two maneuverable spacecraft launched onto the same trans-lunar injection trajectory to coordinate a steep impact of a lunar pole and subsequent sample return of the ejecta plume to Earth. To demonstrate this concept, the impactor is assumed to use the LCROSS missions trajectory and spacecraft architecture, thus the permanently-shadowed Cabeus crater on the lunar south pole is assumed as the impact site. The sample-return spacecraft is assumed to be a CubeSat that requires a complimentary trajectory design that avoids lunar impact after passing through the ejecta plume to enable sample-return to Earth via atmospheric entry.

  5. Temperature fluctuation of the Iceland mantle plume through time

    OpenAIRE

    Spice, Holly E.; Fitton, John; Kirstein, Linda

    2016-01-01

    The newly developed Al-in-olivine geothermometer was used to find the olivine-Cr-spinel crystallization temperatures of a suite of picrites spanning the spatial and temporal extent of the North Atlantic Igneous Province (NAIP), which is widely considered to be the result of a deep-seated mantle plume. Our data confirm that start-up plumes are associated with a pulse of anomalously hot mantle over a large spatial area before becoming focused into a narrow upwelling. We find that the thermal an...

  6. Monitoring Groundwater Contaminant Plumes Using Airborne Geophysical Data

    Science.gov (United States)

    Robinson, Martin; Oftendinger, Ulrich; Ruffell, Alastair; Cowan, Marie; Cassidy, Rachel; Comte, Jean-Christophe; Wilson, Christopher; Desissa, Mohammednur

    2013-04-01

    Under the European Union Water Framework Directive, Member States are required to assess water quality across both surface water and groundwater bodies. Subsurface pollution plumes, originating from a variety of sources, pose a significant direct risk to water quality. The monitoring and characterisation of groundwater contaminant plumes is generally invasive, time consuming and expensive. In particular, adequately capturing the contaminant plume with monitoring installations, when the extent of the feature is unknown and the presence of contamination is only evident from indirect observations, can be prohibitively expensive. This research aims to identify the extent and nature of subsurface contaminant plumes using airborne geophysical survey data. This data was collected across parts of the island of Ireland within the scope of the original Tellus and subsequent Tellus Border projects. The rapid assessment of the airborne electro-magnetic (AEM) data allowed the identification of several sites containing possible contaminant plumes. These AEM anomalies were assessed through the analysis of existing site data and field site inspections, with areas of interest being examined for metallic structures that could affect the AEM data. Electrical resistivity tomography (ERT), ground penetrating radar (GPR) and ground-based electro-magnetic (EM) surveys were performed to ground-truth existing airborne data and to confirm the extent and nature of the affected area identified using the airborne data. Groundwater and surface water quality were assessed using existing field site information. Initial results collected from a landfill site underlain by basalt have indicated that the AEM data, coupled with ERT and GPR, can successfully be used to locate possible plumes and help delineate their extent. The analysis of a range of case study sites exhibiting different geological and environmental settings will allow for the development of a consistent methodology for examining the

  7. Spatial and temporal characterization of methane plumes from mobile platforms

    Science.gov (United States)

    O'Brien, A.; Wendt, L.; Miller, D. J.; Lary, D. J.; Zondlo, M. A.

    2013-12-01

    The spatial and temporal characterization of methane plumes from hydraulic fracturing well sites are presented. Methane measurements from the Marcellus shale region obtained using a commercial instrument on a motor vehicle are discussed. Over 100 well sites in the region were sampled and the methane signature in the vicinity of these wells is presented. Additionally, measurements of methane from our open-path instrument flown aboard the UT Dallas AMR Payload Master 100 remote-controlled, electric aircraft in the Barnett shale region are presented. Using our observations of aircraft surveys near well sites and a gaussian plume dispersion model emission estimates of fugitive methane are presented.

  8. Insights into Coignimbrite Plume Dynamics from Numerical Models

    Science.gov (United States)

    Engwell, S. L.; De'Michieli Vitturi, M.; Barsotti, S.; Eychenne, J.; Esposti Ongaro, T.; Neri, A.

    2014-12-01

    Great advances have been made in recent years to better understand and model the processes that occur in Plinian plumes. However, comparatively little work has been conducted on modeling coignimbrite plumes, which form as fine-grained material is lofted from the top of pyroclastic density currents, rising into the atmosphere due to buoyancy. This fundamental difference in source condition (gas thrust vs. buoyancy) means that the parameters used to describe Plinian plumes, for example initial source radius, upwards velocity, temperature, gas mass fraction and grain-size distribution are not appropriate for modeling coignimbrite events. In this study, the ash flow model of Bursik and Woods (1996) is coupled with a plume model (Bursik 2001, Barsotti et al. 2008) to investigate the controls on coignimbrite plume formation, and once formed, the height and dynamics of the plume. Sensitivity analysis was conducted using DAKOTA software and results show that source temperature and gas mass fraction play a key role in controlling when 'lift-off' occurs. Once formed, maximum plume height is controlled by the source radius, the temperature at 'liftoff' and the entrainment assumption. Finally, we use the May 18th 1980 Mount St. Helens co-blast eruption to test the application of an ash dispersion model, specifically VOLCALPUFF (Barsotti et al., 2008), to the coignimbrite problem, with the specific aim of distinguishing differences in application for coignimbrite and Plinian events. The results highlight the importance of coignimbrite events when considering ash fall hazard and a requirement to treat such events separately to Plinian events. Andrews, B.J. and Manga, M.. JVGR , 225-226, 30-44, 2012 Barsotti, S, Neri, A, and Scire, JS. The vol-calpuff model for atmospheric ash dispersal: 1. Approach and physical formulation. JGR, 113(B03208), 2008 Bursik, M. Effect of wind on the rise height of volcanic plumes. GRL, 28(18), 3621-3624, 2001. Bursik, M and Woods, A. W. The dynamics

  9. Plume Mitigation: Soil Erosion and Lunar Prospecting Sensor Project

    Science.gov (United States)

    Metzger, Philip T.

    2014-01-01

    Demonstrate feasibility of the simplest, lowest-mass method of measuring density of a cloud of lunar soil ejected by rocket exhaust, using new math techniques with a small baseline laser/camera system. Focus is on exploring the erosion process that occurs when the exhaust plume of a lunar rocket impacts the regolith. Also, predicting the behavior of the lunar soil that would be blasted from a lunar landing/launch site shall assist in better design and protection of any future lunar settlement from scouring of structures and equipment. NASA is gathering experimental data to improve soil erosion models and understand how lunar particles enter the plume flow.

  10. Plume-rift interaction in the Deccan volcanic province

    Science.gov (United States)

    Sheth, H. C.; Chandrasekharam, D.

    1997-02-01

    It is widely accepted that the grand volcanic episode of the Deccan in India was a consequence of the passage of the northerly drifting Indian subcontinent over the Réunion starting plume in the Late Cretaceous. This plume also produced the three-rift Cambay triple junction, the three arms being the West Coast graben belt, the Narmada-Tapi rift zone and the Cambay rift. Deccan-related alkalic magmatism both preceded and followed the main tholeiitic phase of ˜ 65 Ma ago by about 3 MY. The uniformly tholeiitic thick basalt sequence of the Western Ghats was derived from direct melting of the plume head, but the tholeiitic-alkalic magmatism of the three rift belts was due to melting of the hydrous lithospheric mantle due to variable amounts of rifting. Any lithospheric loading mechanism for generating post-tholeiite alkalic lavas does not seem feasible for the Deccan; nor can it explain the pre-tholeiite alkaline magmatism in the Deccan. Similarly, conductive heating of the lithosphere by the plume cannot have generated the alkalic melts. Some amount of actual rifting did occur. Direct melt supply from the plume is not necessary for magmatism in the rifts, though it seems to have occurred in some cases. Our documentation of indigenous magmatism for the three rift belts calls into question any attempts at inferring the size of the plume head from synchroneity in geochronologic data alone, and we negate the possibility or necessity of large-distance transport of magmas from the plume through the lithosphere, to feed the rifts. Recent evidence indicates that alkalic magmatism north of the main Deccan outcrop preceded the main tholeiite phase by ˜ 3 MY. The Cambay graben was active 3.5 MY before the main tholeiite phase. As the alkalic complexes at the northern end of this graben are 68.5 Ma in age (so far the oldest well-proven Deccan-related rocks), they are the first expression of the Réunion plume, and the borehole picrites from the triple junction area, until now

  11. Mixing between a stratospheric intrusion and a biomass burning plume

    Directory of Open Access Journals (Sweden)

    J. Brioude

    2007-08-01

    Full Text Available Ozone, carbon monoxide, aerosol extinction coefficient, acetonitrile, nitric acid and relative humidity measured from the NOAA P3 aircraft during the TexAQS/GoMACCS 2006 experiment, indicate mixing between a biomass burning plume and a stratospheric intrusion in the free troposphere above eastern Texas. Lagrangian-based transport analysis and satellite imagery are used to investigate the transport mechanisms that bring together the tropopause fold and the biomass burning plume originating in southern California, which may affect the chemical budget of tropospheric trace gases.

  12. Measurements of reactive trace gases and variable O3 formation rates in some South Carolina biomass burning plumes

    Directory of Open Access Journals (Sweden)

    D. W. T. Griffith

    2013-02-01

    Full Text Available In October–November 2011 we measured trace gas emission factors from seven prescribed fires in South Carolina (SC, US, using two Fourier transform infrared spectrometer (FTIR systems and whole air sampling (WAS into canisters followed by gas-chromatographic analysis. A total of 97 trace gas species were quantified from both airborne and ground-based sampling platforms, making this one of the most detailed field studies of fire emissions to date. The measurements include the first emission factors for a suite of monoterpenes produced by heating vegetative fuels during field fires. The first quantitative FTIR observations of limonene in smoke are reported along with an expanded suite of monoterpenes measured by WAS including α-pinene, β-pinene, limonene, camphene, 4-carene, and myrcene. The known chemistry of the monoterpenes and their measured abundance of 0.4–27.9% of non-methane organic compounds (NMOCs and ~ 21% of organic aerosol (mass basis suggests that they impacted secondary formation of ozone (O3, aerosols, and small organic trace gases such as methanol and formaldehyde in the sampled plumes in the first few hours after emission. The variability in the initial terpene emissions in the SC fire plumes was high and, in general, the speciation of the initially emitted gas-phase NMOCs was 13–195% different from that observed in a similar study in nominally similar pine forests in North Carolina ~ 20 months earlier. It is likely that differences in stand structure and environmental conditions contributed to the high variability observed within and between these studies. Similar factors may explain much of the variability in initial emissions in the literature. The ΔHCN/ΔCO emission ratio, however, was found to be fairly consistent with previous airborne fire measurements in other coniferous-dominated ecosystems, with the mean for these studies being 0.90 ± 0.06%, further confirming the value of HCN as a biomass burning tracer. The

  13. Impacts of fluvial sedimentary heterogeneities on CO2 storage performance

    Science.gov (United States)

    Issautier, B. H.; Viseur, S.; Audigane, P. D.

    2011-12-01

    of some 50 scenarios. The results show that a strong compartmentalization, due to a shaly barrier, may decrease storage capacity by 11 to 25 percent. ? Flow-simulation of an 8-scenario sample extracted from the 50 possible scenarios. In contrast to the static modelling estimated capacities, the preliminary flow-simulation results indicate that capacity remains similar whichever model is applied (A or B). This is because the scale of the heterogeneity is similar to the extent of the CO2 plume, meaning that heterogeneity does not affect the amount of injected CO2 that can be stored in the sedimentary body. Nevertheless, connectivity strongly influences storage capacity, as determined by the 8 scenarios (model A) in which the total amount of CO2 injected ranges between 7 and 12 Mt over a 50-year period. Moreover, heterogeneity significantly increases pressure build-up, and may strongly disrupt the hydrodynamics in the aquifer.

  14. Mobile colloid generation induced by a cementitious plume: mineral surface-charge controls on mobilization.

    Science.gov (United States)

    Li, Dien; Kaplan, Daniel I; Roberts, Kimberly A; Seaman, John C

    2012-03-06

    Cementitious materials are increasingly used as engineered barriers and waste forms for radiological waste disposal. Yet their potential effect on mobile colloid generation is not well-known, especially as it may influence colloid-facilitated contaminant transport. Whereas previous papers have studied the introduction of cement colloids into sediments, this study examined the influence of cement leachate chemistry on the mobilization of colloids from a subsurface sediment collected from the Savannah River Site, USA. A sharp mobile colloid plume formed with the introduction of a cement leachate simulant. Colloid concentrations decreased to background concentrations even though the aqueous chemical conditions (pH and ionic strength) remained unchanged. Mobile colloids were mainly goethite and to a lesser extent kaolinite. The released colloids had negative surface charges and the mean particle sizes ranged primarily from 200 to 470 nm. Inherent mineralogical electrostatic forces appeared to be the controlling colloid removal mechanism in this system. In the background pH of ~6.0, goethite had a positive surface charge, whereas quartz (the dominant mineral in the immobile sediment) and kaolinite had negative surface charges. Goethite acted as a cementing agent, holding kaolinite and itself onto the quartz surfaces due to the electrostatic attraction. Once the pH of the system was elevated, as in the cementitious high pH plume front, the goethite reversed to a negative charge, along with quartz and kaolinite, then goethite and kaolinite colloids were mobilized and a sharp spike in turbidity was observed. Simulating conditions away from the cementitious source, essentially no colloids were mobilized at 1:1000 dilution of the cement leachate or when the leachate pH was ≤ 8. Extreme alkaline pH environments of cementitious leachate may change mineral surface charges, temporarily promoting the formation of mobile colloids.

  15. Observations of the Temperature Dependent Response of Ozone to NOx Reductions in an Urban Plume

    Energy Technology Data Exchange (ETDEWEB)

    LaFranchi, B W; Goldstein, A H; Cohen, R C

    2011-01-25

    Observations of NO{sub x} in the Sacramento, CA region show that mixing ratios decreased by 30% between 2001 and 2008. Here we use an observation-based method to quantify net ozone production rates in the outflow from the Sacramento metropolitan region and examine the O{sub 3} decrease resulting from reductions in NO{sub x} emissions. This observational method does not rely on assumptions about detailed chemistry of ozone production, rather it is an independent means to verify and test these assumptions. We use an instantaneous steady-state model as well as a detailed 1-D plume model to aid in interpretation of the ozone production inferred from observations. In agreement with the models, the observations show that early in the plume, the NO{sub x} dependence for O{sub x} (O{sub x} = O{sub 3}+NO{sub 2}) production is strongly coupled with temperature, suggesting that temperature dependent biogenic VOC emissions can drive O{sub x} production between NO{sub x}-limited and NO{sub x}-suppressed regimes. As a result, NO{sub x} reductions were found to be most effective at higher temperatures over the 7 year period. We show that violations of the California 1-hour O{sub 3} standard (90 ppb) in the region have been decreasing linearly with decreases in NO{sub x} (at a given temperature) and predict that reductions of NO{sub x} concentrations (and presumably emissions) by an additional 30% (relative to 2007 levels) will eliminate violations of the state 1 hour standard in the region. If current trends continue, a 30% decrease in NO{sub x} is expected by 2012, and an end to violations of the 1 hour standard in the Sacramento region appears to be imminent.

  16. Green chemistry by nano-catalysis

    KAUST Repository

    Polshettiwar, Vivek

    2010-01-01

    Nano-materials are important in many diverse areas, from basic research to various applications in electronics, biochemical sensors, catalysis and energy. They have emerged as sustainable alternatives to conventional materials, as robust high surface area heterogeneous catalysts and catalyst supports. The nano-sized particles increase the exposed surface area of the active component of the catalyst, thereby enhancing the contact between reactants and catalyst dramatically and mimicking the homogeneous catalysts. This review focuses on the use of nano-catalysis for green chemistry development including the strategy of using microwave heating with nano-catalysis in benign aqueous reaction media which offers an extraordinary synergistic effect with greater potential than these three components in isolation. To illustrate the proof-of-concept of this "green and sustainable" approach, representative examples are discussed in this article. © 2010 The Royal Society of Chemistry.

  17. Modeling study of biomass burning plumes and their impact on urban air quality; a case study of Santiago de Chile

    Science.gov (United States)

    Cuchiara, G. C.; Rappenglück, B.; Rubio, M. A.; Lissi, E.; Gramsch, E.; Garreaud, R. D.

    2017-10-01

    On January 4, 2014, during the summer period in South America, an intense forest and dry pasture wildfire occurred nearby the city of Santiago de Chile. On that day the biomass-burning plume was transported by low-intensity winds towards the metropolitan area of Santiago and impacted the concentration of pollutants in this region. In this study, the Weather Research and Forecasting model coupled with Chemistry (WRF/Chem) is implemented to investigate the biomass-burning plume associated with these wildfires nearby Santiago, which impacted the ground-level ozone concentration and exacerbated Santiago's air quality. Meteorological variables simulated by WRF/Chem are compared against surface and radiosonde observations, and the results show that the model reproduces fairly well the observed wind speed, wind direction air temperature and relative humidity for the case studied. Based on an analysis of the transport of an inert tracer released over the locations, and at the time the wildfires were captured by the satellite-borne Moderate Resolution Imaging Spectroradiometer (MODIS), the model reproduced reasonably well the transport of biomass burning plume towards the city of Santiago de Chile within a time delay of two hours as observed in ceilometer data. A six day air quality simulation was performed: the first three days were used to validate the anthropogenic and biogenic emissions, and the last three days (during and after the wildfire event) to analyze the performance of WRF/Chem plume-rise model within FINNv1 fire emission estimations. The model presented a satisfactory performance on the first days of the simulation when contrasted against data from the well-established air quality network over the city of Santiago de Chile. These days represent the urban air quality base case for Santiago de Chile unimpacted by fire emissions. However, for the last three simulation days, which were impacted by the fire emissions, the statistical indices showed a decrease in

  18. Annual Report 1984. Chemistry Department

    DEFF Research Database (Denmark)

    Funck, Jytte; Nielsen, Ole John

    This report contains a brief survey of the main activities in the Chemistry Department. All articles and reports published and lectures given in 1984 are presented. The facilities and equipment are mentioned briefly. The activities are divided into the following groups: radioisotope chemistry, an......, analytical- and organic chemistry, environmental chemistry, polymer chemistry, geochemistry and waste disposal, radical chemistry, positron annihilation, mineral processing, and general.......This report contains a brief survey of the main activities in the Chemistry Department. All articles and reports published and lectures given in 1984 are presented. The facilities and equipment are mentioned briefly. The activities are divided into the following groups: radioisotope chemistry...

  19. STUDIES OF TWO-PHASE PLUMES IN STRATIFIED ENVIRONMENTS

    Energy Technology Data Exchange (ETDEWEB)

    Scott A. Socolofsky; Brian C. Crounse; E. Eric Adams

    1998-11-18

    Two-phase plumes play an important role in the more practical scenarios for ocean sequestration of CO{sub 2}--i.e. dispersing CO{sub 2} as a buoyant liquid from either a bottom-mounted or ship-towed pipeline. Despite much research on related applications, such as for reservoir destratification using bubble plumes, our understanding of these flows is incomplete, especially concerning the phenomenon of plume peeling in a stratified ambient. To address this deficiency, we have built a laboratory facility in which we can make fundamental measurements of plume behavior. Although we are using air, oil and sediments as our sources of buoyancy (rather than CO{sub 2}), by using models, our results can be directly applied to field scale CO{sub 2} releases to help us design better CO{sub 2} injection systems, as well as plan and interpret the results of our up-coming international field experiment. The experimental facility designed to study two-phase plume behavior similar to that of an ocean CO{sub 2} release includes the following components: 1.22 x 1.22 x 2.44 m tall glass walled tank; Tanks and piping for the two-tank stratification method for producing step- and linearly-stratified ambient conditions; Density profiling system using a conductivity and temperature probe mounted to an automated depth profiler; Lighting systems, including a virtual point source light for shadowgraphs and a 6 W argon-ion laser for laser induced fluorescence (LIF) imaging; Imaging system, including a digital, progressive scanning CCD camera, computerized framegrabber, and image acquisition and analysis software; Buoyancy source diffusers having four different air diffusers, two oil diffusers, and a planned sediment diffuser; Dye injection method using a Mariotte bottle and a collar diffuser; and Systems integration software using the Labview graphical programming language and Windows NT. In comparison with previously reported experiments, this system allows us to extend the parameter range of

  20. Sediment plume response to surface melting and supraglacial lake drainages on the Greenland ice sheet

    DEFF Research Database (Denmark)

    Chu, Vena W.; Smith, Laurence C; Rennermalm, Asa K.

    2009-01-01

    of a downstream sediment plume in Kangerlussuaq Fjord by comparing: (1) plume area and suspended sediment concentration from Moderate Resolution Imaging Spectroradiometer (MODIS) imagery and field data; (2) ice-sheet melt extent from Special Sensor Microwave/Imager (SSM/I) passive microwave data; and (3......) supraglacial lake drainage events from MODIS. Results confirm that the origin of the sediment plume is meltwater release from the ice sheet. Interannual variations in plume area reflect interannual variations in surface melting. Plumes appear almost immediately with seasonal surface-melt onset, provided...... the estuary is free of landfast sea ice. A seasonal hysteresis between melt extent and plume area suggests late-season exhaustion in sediment supply. Analysis of plume sensitivity to supraglacial events is less conclusive, with 69% of melt pulses and 38% of lake drainage events triggering an increase in plume...

  1. The impact of glacier geometry on meltwater plume structure and submarine melt in Greenland fjords

    NARCIS (Netherlands)

    Carroll, D.; Sutherland, D. A.; Hudson, B.; Moon, T.; Catania, G. A.; Shroyer, E. L.; Nash, J. D.; Bartholomaus, T. C.; Felikson, D.; Stearns, L. A.; Noël, B. P Y; van den Broeke, M. R.

    2016-01-01

    Meltwater from the Greenland Ice Sheet often drains subglacially into fjords, driving upwelling plumes at glacier termini. Ocean models and observations of submarine termini suggest that plumes enhance melt and undercutting, leading to calving and potential glacier destabilization. Here we

  2. Stochastic Mapping for Chemical Plume Source Localization With Application to Autonomous Hydrothermal Vent Discovery

    National Research Council Canada - National Science Library

    Jakuba, Michael V

    2007-01-01

    ..., explosive ordinance removal, and hydrothermal vent prospecting. Turbulent flows make the spatial relationship between the detectable manifestation of a chemical plume source, the plume itself, and the location of its source inherently uncertain...

  3. Information and Heterogeneous Beliefs

    DEFF Research Database (Denmark)

    Christensen, Peter Ove; Qin, Zhenjiang

    2014-01-01

    In an incomplete market with heterogeneous prior beliefs, we show public information can have a substantial impact on the ex ante cost of capital, trading volume, and investor welfare. The Pareto effcient public information system is the system enjoying the maximum ex ante cost of capital...... ante risk premium is unaffected by the informativeness of the public information system. Similar results are obtained in a production economy, but the impact on the ex ante cost of capital is dampened compared to the exchange economy due to welfare improving reductions in real investments to smooth...... and the maximum expected abnormal trading volume. Imperfect public information increases the gains-to-trade based on heterogeneously updated posterior beliefs. In an exchange economy, this leads to higher growth in the investors' certainty equivalents and, thus, a higher equilibrium interest rate, whereas the ex...

  4. HETEROGENEOUS INTEGRATION TECHNOLOGY

    Science.gov (United States)

    2017-08-24

    the “product component” is a result of technology push only, it struggles to fit into a conservative system environment . If the “product component...makes the categorization difficult. In a technology push environment , the evolution of technology is easier to track since it starts evolving from a... environmental information. The role of the heterogeneous integration technology for reducing the size and the power consumption of small sensors was studied

  5. Micromechanics of heterogeneous materials

    CERN Document Server

    Buryachenko, Valeriy

    2007-01-01

    Here is an accurate and timely account of micromechanics, which spans materials science, mechanical engineering, applied mathematics, technical physics, geophysics, and biology. The book features rigorous and unified theoretical methods of applied mathematics and statistical physics in the material science of microheterogeneous media. Uniquely, it offers a useful demonstration of the systematic and fundamental research of the microstructure of the wide class of heterogeneous materials of natural and synthetic nature.

  6. Heterogeneous chromium catalysts

    OpenAIRE

    2005-01-01

    The present invention relates to a heterogeneous chromium catalyst system for the polymerisation of ethylene and/or alpha olefins prepared by the steps of: (a) providing a silica-containing support, (b) treating the silica-containing support with a chromium compound to form a chromium-based silica-containing support, (c) activating the chromium-based silica-containing support, (d) chemically reducing the activated chromium-based silica-containing support to produce a precursor catalyst, (e) r...

  7. The effects of particulates on supersonic shear layers and afterburning in fuel-rich plumes

    OpenAIRE

    Lee, Siwon R.

    1995-01-01

    An investigation was conducted to experimentally quantify the interaction of particulates with the fuel-rich plume flowfield typical for solid propellant rocket motors. This was done in order to optimize enhanced mixing devices or chemical-additive addition for afterburning suppression. Laser sheet flow visualization, sound spectra measurements, plume thermal images and particle size distribution measurements were utilized with reacting and non- reacting gaseous plumes and with the plumes fro...

  8. Channelling of Melt Above Plumes and Beneath MORs

    Science.gov (United States)

    Mueller, K.; Schmeling, H.

    2003-12-01

    We investigate melt transportation in partially molten rocks under different stress fields above the head of a mantle plume or beneath a spreading mid-oceanic ridge under hydrous and anhydrous conditions. We model such aggregates with the 2D-FD code FDCON [1] by means of a porous deformable matrix with melt under the influence of a given stress field to clarify the following key questions: Could channeling occur in a matrix containing a random melt distribution under a given stress field? Which orientation does it take? Is it possible to achieve a focusing of melt towards a MOR (dykes)? Does applying simple or pure shear to the matrix result in a difference in the formation and orientation of channels? How does the channel instability evolve during finite simple shear? In a deforming partially molten aggregate, weakening of the solid matrix due to the presence of melt creates an instability in which melt is localized by the following mechanism: regions of initially high melt fraction are areas of low viscosity and pressure, so that melt is drawn into these regions from higher pressure surroundings. This further enhances the melt weakening, producing a self-excited localization mechanism [2]. The channeling developing in models with a random melt distribution of 3.5 +/- 0.5% shows that melt is accumulated preferably in inclined channels. For both, simple as well as pure shear, the growth rate is highest for an orientation parallel to the direction of the maximum compressive stress and proportional to applied stress and the reverse of the Melt Retention Number. This also confirms the theoretical growth rate found by Stevenson [2]. In our isothermal models we found that the influence of water reduces the growth rate, in contrast to non-isothermal models of Hall [3]. Under simple shear melt channels evolve from an irregular melt distribution at angles of 45 degrees to the direction of shear. Upon further straining they rotate out of the orientation of maximum growth

  9. Plume-induced continental break-up from Red Sea to Lake Malawi: 3D numerical models of the East African Rift System

    Science.gov (United States)

    Koptev, Alexander; Burov, Evgueni; Calais, Eric; Leroy, Sylvie; Gerya, Taras; Cloetingh, Sierd; Guillou-Frottier, Laurent

    2017-04-01

    We use numerical thermo-mechanical experiments in order to analyze the role of active mantle plume, far-field tectonic stresses and pre-existing lithospheric heterogeneities in structural development of the East African Rift system (EARS). It is commonly assumed that the Cenozoic rifts have avoided the cratons and follow the mobile belts which serve as the weakest pathways within the non-uniform material structured during pre-rift stages. Structural control of the pre-existing heterogeneities within the Proterozoic belts at the scale of individual faults or rifts has been demonstrated as well. However, the results of our numerical experiments show that the formation of two rift zones on opposite sides of a thick lithosphere segment can be explained without appealing to pre-imposed heterogeneities at the crustal level. These models have provided a unified physical framework to understand the development of the Eastern branch, the Western branch and its southern prolongation by the Malawi rift around thicker lithosphere of the Tanzanian and Bangweulu cratons as a result of the interaction between pre-stressed continental lithosphere and single mantle plume anomaly corresponding to the Kenyan plume. The second series of experiments has been designed in order to investigate northern segment of the EARS where Afro-Arabian plate separation is supposed to be related with the impact of Afar mantle plume. We demonstrate that whereas relatively simple linear rift structures are preferred in case of uni-directional extension, more complex rifting patterns combining one or several ridge-ridge-ridge triple junctions can form in response to bi-directional extensional far-field stresses. In particular, our models suggest that Afar triple junction represents an end-member mode of plume-induced bi-directional rifting combining asymmetrical northward traction and symmetrical EW extension of similar magnitudes. The presence of pre-existing linear weak zones appears to be not

  10. Mathematics for physical chemistry

    CERN Document Server

    Mortimer, Robert G

    2013-01-01

    Mathematics for Physical Chemistry is the ideal supplementary text for practicing chemists and students who want to sharpen their mathematics skills while enrolled in general through physical chemistry courses. This book specifically emphasizes the use of mathematics in the context of physical chemistry, as opposed to being simply a mathematics text. This 4e includes new exercises in each chapter that provide practice in a technique immediately after discussion or example and encourage self-study. The early chapters are constructed around a sequence of mathematical topics, wit

  11. Gas phase ion chemistry

    CERN Document Server

    Bowers, Michael T

    1979-01-01

    Gas Phase Ion Chemistry, Volume 1 covers papers on the advances of gas phase ion chemistry. The book discusses the advances in flow tubes and the measurement of ion-molecule rate coefficients and product distributions; the ion chemistry of the earth's atmosphere; and the classical ion-molecule collision theory. The text also describes statistical methods in reaction dynamics; the state selection by photoion-photoelectron coincidence; and the effects of temperature and pressure in the kinetics of ion-molecule reactions. The energy distribution in the unimolecular decomposition of ions, as well

  12. Spatially Resolved Artificial Chemistry

    DEFF Research Database (Denmark)

    Fellermann, Harold

    2009-01-01

    Although spatial structures can play a crucial role in chemical systems and can drastically alter the outcome of reactions, the traditional framework of artificial chemistry is a well-stirred tank reactor with no spatial representation in mind. Advanced method development in physical chemistry has...... made a class of models accessible to the realms of artificial chemistry that represent reacting molecules in a coarse-grained fashion in continuous space. This chapter introduces the mathematical models of Brownian dynamics (BD) and dissipative particle dynamics (DPD) for molecular motion and reaction...

  13. Experiments in physical chemistry

    CERN Document Server

    Wilson, J M; Denaro, A R

    1968-01-01

    Experiments in Physical Chemistry, Second Edition provides a compilation of experiments concerning physical chemistry. This book illustrates the link between the theory and practice of physical chemistry. Organized into three parts, this edition begins with an overview of those experiments that generally have a simple theoretical background. Part II contains experiments that are associated with more advanced theory or more developed techniques, or which require a greater degree of experimental skill. Part III consists of experiments that are in the nature of investigations wherein these invest

  14. Dynamic heterogeneity in life histories

    DEFF Research Database (Denmark)

    Tuljapurkar, Shripad; Steiner, Uli; Orzack, Steven Hecht

    2009-01-01

    generate dynamic heterogeneity: life-history differences produced by stochastic stratum dynamics. We characterize dynamic heterogeneity in a range of species across taxa by properties of the Markov chain: the entropy, which describes the extent of heterogeneity, and the subdominant eigenvalue, which...... distributions of lifetime reproductive success. Dynamic heterogeneity contrasts with fixed heterogeneity: unobserved differences that generate variation between life histories. We show by an example that observed distributions of lifetime reproductive success are often consistent with the claim that little...... or no fixed heterogeneity influences this trait. We propose that dynamic heterogeneity provides a 'neutral' model for assessing the possible role of unobserved 'quality' differences between individuals. We discuss fitness for dynamic life histories, and the implications of dynamic heterogeneity...

  15. Observations of brine plumes below melting Arctic sea ice

    Directory of Open Access Journals (Sweden)

    A. K. Peterson

    2018-02-01

    Full Text Available In sea ice, interconnected pockets and channels of brine are surrounded by fresh ice. Over time, brine is lost by gravity drainage and flushing. The timing of salt release and its interaction with the underlying water can impact subsequent sea ice melt. Turbulence measurements 1 m below melting sea ice north of Svalbard reveal anticorrelated heat and salt fluxes. From the observations, 131 salty plumes descending from the warm sea ice are identified, confirming previous observations from a Svalbard fjord. The plumes are likely triggered by oceanic heat through bottom melt. Calculated over a composite plume, oceanic heat and salt fluxes during the plumes account for 6 and 9 % of the total fluxes, respectively, while only lasting in total 0.5 % of the time. The observed salt flux accumulates to 7.6 kg m−2, indicating nearly full desalination of the ice. Bulk salinity reduction between two nearby ice cores agrees with accumulated salt fluxes to within a factor of 2. The increasing fraction of younger, more saline ice in the Arctic suggests an increase in desalination processes with the transition to the new Arctic.

  16. Hydrothermal plumes over the Carlsberg Ridge, Indian Ocean

    Digital Repository Service at National Institute of Oceanography (India)

    Ray, D.; KameshRaju, K.A; Baker, E.T.; Rao, A; Mudholkar, A; Lupton, J.E.; SuryaPrakash, L.; Gawas, R.B.; VijayaKumar, T.

    Water column surveys and sampling in 2007 and 2009 was conducted to search for hydrothermal plumes over a segment of the Carlsberg Ridge. An evidence for two separate vent fields, one near 3 degrees 42′N, 63 degrees 40′E and another near 3 degrees...

  17. Solar Coronal Plumes and the Fast Solar Wind

    Indian Academy of Sciences (India)

    2016-01-27

    Jan 27, 2016 ... Before the spectroscopic peculiarities in IPRs and plumes in Polar Coronal Holes (PCHs) can be further investigated with the instrument Solar Ultraviolet Measurements of Emitted Radiation (SUMER) aboard the Solar and Heliospheric Observatory (SOHO), it is mandatory to summarize the results of the ...

  18. MODELING AN IRRITANT GAS PLUME FOR EPIDEMIOLOGIC STUDY

    Science.gov (United States)

    Jani, Dev D.; Reed, David; Feigley, Charles E.

    2015-01-01

    Plume dispersion modeling systems are often used in assessing human exposures to chemical hazards for epidemiologic study. We modeled the 2005 Graniteville, South Carolina, 54,915 kg railcar chlorine release using both the Areal Locations of Hazardous Atmospheres (ALOHA) and Hazard Prediction and Assessment Capability (HPAC) plume modeling systems. We estimated the release rate by an engineering analysis combining semi-quantitative observations and fundamental physical principles. The use of regional meteorological conditions was validated by comparing concentration estimates generated by two source-location weather data sets. The HPAC model estimated a chlorine plume with 20 ppm outdoor concentrations up to 7 km downwind and 0.25 km upwind/downgrade. A comparative analysis of our two models showed that HPAC was the best candidate for use as a model system on which epidemiologic studies could be based after further model validation. Further validation studies are needed before individual exposure estimates can be reliable and the chlorine plume more definitively modeled. PMID:25772143

  19. Multiphase CFD modeling of nearfield fate of sediment plumes

    DEFF Research Database (Denmark)

    Saremi, Sina; Hjelmager Jensen, Jacob

    2014-01-01

    . The two-phase mixture solution based on the drift-flux method is evaluated for 3D simulation of material disposal and overflow discharge from the hoppers. The model takes into account the hindrance and resistance mechanisms in the mixture and is capable of describing the flow details within the plumes...

  20. Impacts of wildfire smoke plumes on regional air quality

    Science.gov (United States)

    Background: Recent trends in increased frequency and severity of large fires necessitate an improved understanding of smoke plume impacts on regional-scale air quality and public health. Objective: We examine the impact of fire smoke on regional air quality between 2006 and 2013 ...